Sample records for in-situ u-pb analyses

  1. In-situ U-Pb, Hf and Re-Os isotopic analyses of the Xiangshan Ni-Cu-Co deposit in Eastern Tianshan (Xinjiang), Central Asia Orogenic Belt: Constraints on the timing and genesis of the mineralization (United States)

    Han, Chunming; Xiao, Wenjiao; Zhao, Guochun; Ao, Songjian; Zhang, Jien; Qu, Wenjun; Du, Andao


    The timing and genesis of the major Ni-Cu-Co sulfide deposit in the Xiangshan intrusion have been studied based on newly obtained in-situ U-Pb, Hf and Re-Os isotopic analyses. The SIMS U-Pb zircon ages of the gabbro hosting the Ni-Cu-Co sulfide deposit indicate that the Xiangshan intrusion was emplaced at 279.6 ± 1.1 Ma (95% confidence level, MSWD = 1.30, n = 15). On the basis of combined geological and geochronological evidence, we suggest that the Xiangshan and other adjacent Ni-Cu deposits were formed in the same period. Sulphides have low common Os concentrations and high Re/Os ratios, similar to sulphide ores from the Duluth, Sally Malay and Voisey Bay complexes. The Re-Os isotopic data from the disseminated and massive ores from the Xiangshan intrusion do not form a single isochron, as they have different initial Os ratios. The Hf and Os isotopic data suggest that the Xiangshan intrusion and associated Ni-Cu-Co mineralization were derived from crustally contaminated mantle melts. The geochemical data show a tholeiitic affinity and a strong suprasubduction zone signature with negative Nb, Sr, and Ti anomalies similar to N-MORB and E-MORB. We suggest that the mafic-ultramafic rocks and associated Ni-Cu mineralization of the Eastern Tianshan orogen formed in an Alaska-type subduction zone-arc setting. Some diagnostic features of ridge-trench interaction are present in the Chinese East Tianshan orogen (e.g. granites, adakites, high-Mg andesites, near-trench magmatism, Alaskan-type mafic-ultramafic complexes, high-temperature metamorphic belts that prograde rapidly from low-grade belts, and orogenic gold deposits). The above distinctive rock groups are probably related to the same thermal event, ridge subduction, as in the Cenozoic orogen of Alaska. We suggest that ridge subduction is the most plausible mechanism to provide the necessary heat. Ridge subduction provides an important promising model for understanding many aspects of the evolution of the Chinese

  2. Statistical analyses of Global U-Pb Database 2017

    Directory of Open Access Journals (Sweden)

    Stephen J. Puetz


    Full Text Available The method of obtaining zircon samples affects estimation of the global U-Pb age distribution. Researchers typically collect zircons via convenience sampling and cluster sampling. When using these techniques, weight adjustments proportional to the areas of the sampled regions improve upon unweighted estimates. Here, grid-area and modern sediment methods are used to weight the samples from a new database of 418,967 U-Pb ages. Preliminary tests involve two age models. Model-1 uses the most precise U-Pb ages as the best ages. Model-2 uses the 206Pb/238U age as the best age if it is less than a 1000 Ma cutoff, otherwise it uses the 207Pb/206Pb age as the best age. A correlation analysis between the Model-1 and Model-2 ages indicates nearly identical distributions for both models. However, after applying acceptance criteria to include only the most precise analyses with minimal discordance, a histogram of the rejected samples shows excessive rejection of the Model-2 analyses around the 1000 Ma cutoff point. Because of the excessive rejection rate for Model-2, we select Model-1 as the preferred model. After eliminating all rejected samples, the remaining analyses use only Model-1 ages for five rock-type subsets of the database: igneous, meta-igneous, sedimentary, meta-sedimentary, and modern sediments. Next, time-series plots, cross-correlation analyses, and spectral analyses determine the degree of alignment among the time-series and their periodicity. For all rock types, the U-Pb age distributions are similar for ages older than 500 Ma, but align poorly for ages younger than 500 Ma. The similarities (>500 Ma and differences (<500 Ma highlight how reductionism from a detailed database enhances understanding of time-dependent sequences, such as erosion, detrital transport mechanisms, lithification, and metamorphism. Time-series analyses and spectral analyses of the age distributions predominantly indicate a synchronous period-tripling sequence

  3. In-Situ U-Pb Dating of Apatite by Hiroshima-SHRIMP: Contributions to Earth and Planetary Science. (United States)

    Terada, Kentaro; Sano, Yuji


    The Sensitive High Resolution Ion MicroProbe (SHRIMP) is the first ion microprobe dedicated to geological isotopic analyses, especially in-situ analyses related to the geochronology of zircon. Such a sophisticated ion probe, which can attain a high sensitivity at a high mass resolution, based on a double focusing high mass-resolution spectrometer, designed by Matsuda (1974), was constructed at the Australian National University. In 1996, such an instrument was installed at Hiroshima University and was the first SHRIMP to be installed in Japan. Since its installation, our focus has been on the in-situ U-Pb dating of the mineral apatite, as well as zircon, which is a more common U-bearing mineral. This provides the possibility for extending the use of in-situ U-Pb dating from determining the age of formation of volcanic, granitic, sedimentary and metamorphic minerals to the direct determination of the diagenetic age of fossils and/or the crystallization age of various meteorites, which can provide new insights into the thermal history on the Earth and/or the Solar System. In this paper, we review the methodology associated with in-situ apatite dating and our contribution to Earth and Planetary Science over the past 16 years.

  4. Combined U-Pb and Lu-Hf isotope analyses by laser ablation MC-ICP-MS: methodology and applications

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    Matteini, Massimo; Dantas, Elton L.; Pimentel, Marcio M.; Bühn, Bernhard, E-mail: [Universidade de Brasilia (UnB), DF (Brazil). Instituto de Geociencias


    The Lutetium-Hafnium isotopic system represents one of the most innovative and powerful tools for geochronology and isotopic studies. Combined U-Pb and Lu-Hf in situ analyses on zircon by LA-MC-ICP-MS permit to characterize isotopically the host magma from which it crystallized furnishing significant information for sediment provenance and crustal evolution studies. In this paper e describe the Lu-Hf systematic by LA-MC-ICP-MS developed in the laboratory of Geochronology of the University of Brasilia and report the results obtained by repeated analyses of {sup 176}Hf/{sup 177}Hf isotopic ratio of three zircon standards: GJ-1 = 0.282022 ± 11 (n=56), Temora 2 = 0.282693 ± 14 (n=25) and UQZ = 0.282127 ± 33 (n=11). The {sup 176}Hf/{sup 177}Hf ratio (0.282352 ± 22, n=14) of gem quality zircon used as in-house standard have been also characterized. As a geological application, we analyzed two complex zircons selected from a migmatitic rocks from the Borborema Province, NE Brazil. On the basis of U-Pb and Lu-Hf data, two main crystallization events have been identified in both studied zircons. An older event at ca. 2.05 Ga recognized in the inherited cores represents a well-characterized paleoproterozoic magmatic event that affected the whole Borborema Province. A second crystallization event at ∼ 575 Ma, recognized at the rims, represents a Neoproterozoic (Brazilian) high grade metamorphic-magmatic event. (author)

  5. Combined U-Pb and Lu-Hf isotope analyses by laser ablation MC-ICP-MS: methodology and applications

    Directory of Open Access Journals (Sweden)

    Massimo Matteini


    Full Text Available The Lutetium-Hafnium isotopic system represents one of the most innovative and powerful tools for geochronology and isotopic studies. Combined U-Pb and Lu-Hf in situ analyses on zircon by LA-MC-ICP-MS permit to characterize isotopically the host magma from which it crystallized furnishing significant information for sediment provenance and crustal evolution studies. In this paper e describe the Lu-Hf systematic by LA-MC-ICP-MS developed in the laboratory of Geochronology of the University of Brasilia and report the results obtained by repeated analyses of 176Hf/177Hf isotopic ratio of three zircon standards: GJ-1 = 0.282022 ± 11 (n=56, Temora 2 = 0.282693 ± 14 (n=25 and UQZ = 0.282127 ± 33 (n=11. The 176Hf/177Hf ratio (0.282352 ± 22, n=14 of gem quality zircon used as in-house standard have been also characterized. As a geological application, we analyzed two complex zircons selected from a migmatitic rocks from the Borborema Province, NE Brazil. On the basis of U-Pb and Lu-Hf data, two main crystallization events have been identified in both studied zircons. An older event at ca. 2.05 Ga recognized in the inherited cores represents a well-characterized paleoproterozoic magmatic event that affected the whole Borborema Province. A second crystallization event at ~ 575 Ma, recognized at the rims, represents a Neoproterozoic (Brazilian high grade metamorphic-magmatic event.O sistema isotópico Lutécio-Hafnio representa uma das ferramentas mais recentes e poderosas para estudos isotópicos e geocronológicos. Análises combinadas in situ de U-Pb e Lu-Hf sobre zircão pelo LA-MC-ICP-MS permitem caracterizar iso-topicamente o magma onde ele cristalizou, fornecendo valiosas informações para estudos de proveniência de sedimento e de evolução crustal. Nesse trabalho descrevemos a sistemática de Lu-Hf pelo LA-MC-ICP-MS implantada no laboratório de Geocronologia da Universidade de Brasília e reportamos os resultados obtidos de repetidas an

  6. U-Pb zircon in situ dating with LA-MC-ICP-MS using a mixed detector configuration

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    Chemale Junior, Farid, E-mail: [Universidade de Brasilia (UnB), DF (Brazil). Inst. de Geociencias; Kawashita, Koji; Dussin, Ivo A. [Universidade de Sao Paulo (USP), SP (Brazil). Centro de Pesquisas Geocronologicas; Avila, Janaina N. [Australian National University, Canberra, (Australia). Research School of Earth Sciences; Justino, Dayvisson; Bertotti, Anelise [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Curso de Pos-Graduacao em Geociencias


    The LA-MC-ICP-MS method applied to U-Pb in situ dating is still rapidly evolving due to improvements in both lasers and ICP-MS. To test the validity and reproducibility of the method, 5 different zircon samples, including the standard Temora-2, ranging in age between 2.2 Ga and 246 Ma, were dated using both LA-MC-ICP-MS and SHRIMP. The selected zircons were dated by SHRIMP and, after gentle polishing, the laser spot was driven to the same site or on the same zircon phase with a 213 nm laser microprobe coupled to a multi-collector mixed system. The data were collected with a routine spot size of 25 {mu}m and, in some cases, of 15 and 40 {mu}m. A careful cross-calibration using a diluted U-Th-Pb solution to calculate the Faraday reading to counting rate conversion factors and the highly suitable GJ-1 standard zircon for external calibrations were of paramount importance for obtaining reliable results. All age results were concordant within the experimental errors. The assigned age errors using the LA-MC-ICP-MS technique were, in most cases, higher than those obtained by SHRIMP, but if we are not faced with a high resolution stratigraphy, the laser technique has certain advantages. (author)

  7. Advantages of conducting in-situ U-Pb age dating of multiple U-bearing minerals from a single complex: Case in point - the Oka Carbonatite Complex (United States)

    Chen, W.; Simonetti, A.


    A detailed radiometric investigation is currently underway focusing on U-bearing accessory minerals apatite, perovskite, and niocalite from the Oka Carbonatite Complex (Canada). One of the main objectives is to obtain a comparative chronology of melt crystallization for the complex. Unlike other commonly adopted U-bearing minerals (e.g., zircon, monazite) for in-situ dating investigations, apatite, perovskite, and niocalite contain relatively high contents of common Pb. Hence, careful assessment of the proportion and composition of the common Pb, and usage of appropriate matrix-matched external standards are imperative. The Madagascar apatite was utilized as the external standard for apatite dating, and the Emerald Lake and Durango apatites were adopted as secondary standards; the latter yield ages of 92.6 ±1.8 and 32.2 ±1.1 Ma, respectively, and these are identical to their accepted ages. Pb/U ages for apatite from Oka were obtained for different rock types, including 8 carbonatites, 4 okaites, 3 ijolites and 3 alnoites, and these define a range of ages between ~105 and ~135 Ma; this result suggests a protracted crystallization history. In total, 266 individual analyses define two peaks at ~115 and ~125Ma. For perovskite dating, the Ice River perovskite standard was utilized as the external standard. The perovskites from one okaite sample yield an age of 112.2 ±1.9 Ma, and is much younger than the previously reported U-Pb perovskite age of 131 ±7 Ma. Hence, the combined U-Pb perovskite ages also suggest a rather prolonged time of melt crystallization. Niocalite is a rare, accessory silicate mineral that occurs within the carbonatites at Oka. The international zircon standard BR266 was selected for use as the external standard and rastering was employed to minimize the Pb-U fractionation. Two niocalite samples give young ages at 110.6 ±1.2 and 115.0 ±1.9 Ma, and are identical to their respective apatite ages (given associated uncertainties) from the same

  8. In situ SIMS U-Pb dating of hydrothermal rutile: reliable age for the Zhesang Carlin-type gold deposit in the golden triangle region, SW China (United States)

    Pi, Qiaohui; Hu, Ruizhong; Xiong, Bin; Li, Qiuli; Zhong, Richen


    The contiguous region between Guangxi, Guizhou, and Yunnan, commonly referred to as the Golden Triangle region in SW China, hosts many Carlin-type gold deposits. Previously, the ages of the gold mineralization in this region have not been well constrained due to the lack of suitable minerals for radiometric dating. This paper reports the first SIMS U-Pb age of hydrothermal rutile crystals for the Zhesang Carlin-type gold deposit in the region. The hydrothermal U-bearing rutile associated with gold-bearing sulfides in the deposit yields an U-Pb age of 213.6 ± 5.4 Ma, which is within the range of the previously reported arsenopyrite Re-Os isochron ages (204 ± 19 to 235 ± 33 Ma) for three other Carlin-type gold deposits in the region. Our new and more precise rutile U-Pb age confirms that the gold mineralization was contemporaneous with the Triassic W-Sn mineralization and associated granitic magmatism in the surrounding regions. Based on the temporal correlation, we postulate that coeval granitic plutons may be present at greater depths in the Golden Triangle region and that the formation of the Carlin-type gold deposits is probably linked to the coeval granitic magmatism in the region. This study clearly demonstrates that in situ rutile U-Pb dating is a robust tool for the geochronogical study of hydrothermal deposits that contain hydrothermal rutile.

  9. Petrology of the L-Melt Rock NWA 7251 and In Situ U-Pb Dating of Phosphates (United States)

    Li, Y.; Hsu, W.


    NWA 7251 mainly consists of three parts: chondrite host (L5), impact-melt portion and impact melt vein. Phosphate U-Pb dating results show it recoded two collisional events at 4402 ± 62 Ma and 466 ± 120 Ma, respectively.

  10. Provenance of sediments from Sumatra, Indonesia - Insights from detrital U-Pb zircon geochronology, heavy mineral analyses and Raman spectroscopy (United States)

    Liebermann, C.; Hall, R.; Gough, A.


    The island of Sumatra is situated at the southwestern margin of the Indonesian archipelago. Although it is the sixth largest island in the world, the geology of the Sumatra sedimentary basins and their underlying basement is relatively poorly understood in terms of their provenance. This work is a multi-proxy provenance study utilizing U-Pb detrital zircon dating by LA-ICP-MS combined with optical and Raman spectroscopy-based heavy mineral analysis. It will help to unravel the stratigraphy of Sumatra, contribute to paleogeographic reconstruction of western SE Asia, and aid a wider understanding of Sumatran petroleum plays. Thin section analyses, heavy mineral assemblages, and >3500 concordant U-Pb zircon ages, from samples acquired during two fieldwork seasons indicate a mixed provenance for Cenozoic sedimentary formations, including both local igneous sources and mature basement rocks. Characteristic Precambrian zircon age spectra are found in all analysed Cenozoic sedimentary strata. These can be correlated with zircon age populations found in Sumatran basement rocks; Neoproterozoic and Mesoproterozoic age groups are dominant (c. 500-600 Ma, c. 850-1000 Ma, c. 1050-1200 Ma). Paleoproterozoic to Archaean zircons occur as minor populations. The Phanerozoic age spectra of the Cenozoic formations are characterised by distinct Carboniferous, Permo-Triassic, and Jurassic-Cretaceous zircon populations. Permo-Triassic zircons are interpreted to come from granitoids in the Malay peninsula or Sumatra itself. Eocene to Lower Miocene strata are characterised by ultrastable heavy minerals such as zircon, tourmaline, and rutile, which together with garnet, suggest the principal sources were igneous and metamorphic basement rocks. Cenozoic zircons appear only from the Middle Miocene onwards. This change is interpreted to indicate a new contribution from a local volcanic arc, and is supported by the occurrence of unstable heavy minerals such as apatite and clinopyroxene, and the

  11. Geodynamics of rift-plume interaction in Iceland as constrained by new 40Ar/ 39Ar and in situ U-Pb zircon ages (United States)

    Martin, E.; Paquette, J. L.; Bosse, V.; Ruffet, G.; Tiepolo, M.; Sigmarsson, O.


    The interaction between a rift zone and a mantle plume leads to exceptional situations in Iceland where the island is 1.5 wider than expected, given the North-Atlantic spreading rate. In order to give a better idea of the timeframe of this evolution, we present 32 new 40Ar/ 39Ar and in-situ U-Pb dating on zircon from 16 volcanic systems located from the west to east coasts of Iceland. The North Iceland Rift Zone (NIRZ) was initiated at least 12 Ma ago. Furthermore, during these last 12 Ma, the NIRZ half spreading rate was between 0.7 and 1.2 cm/yr and it propagated to the south at a rate of 1.0-1.2 cm/yr. The excess width of Iceland can thus not be explained by faster spreading rate in the past. Here we discuss a model that explains the ~ 200 km 'excess' of crust, taking into account the eastward relocation of the rift zone and corresponding older crustal capture over the course of Iceland's geological history. The most recent rift relocation is dated at approximately 6 Ma at Snæfellsnes Peninsula in the west, whereas the oldest volcanic systems (15-13 Ma) from the extreme north east of Iceland were most likely generated at the Kolbeinsey ridge north of Iceland rather than in the NIRZ itself. The need for rift relocations and crustal capture to explain the width of Iceland strongly suggests that during rift-plume interaction the mantle plume plays an active role. It forces the active rift zone to be frequently relocated by rift jumps above its center leaving inactive rift zones as older synclines in the geological record. This result in an eastward position of the rift zone in Iceland relative to the North Atlantic ridge, and it can be predicted that in a few tens of millions of years the Mid-Atlantic ridge and the Icelandic plume may become decoupled.

  12. Birth and demise of the Rheic Ocean magmatic arc(s): Combined U-Pb and Hf isotope analyses in detrital zircon from SW Iberia siliciclastic strata (United States)

    Pereira, M. F.; Gutíerrez-Alonso, G.; Murphy, J. B.; Drost, K.; Gama, C.; Silva, J. B.


    Paleozoic continental reconstructions indicate that subduction of Rheic oceanic lithosphere led to collision between Laurussia and Gondwana which was a major event in the formation of the Ouachita-Appalachian-Variscan orogenic belt and the amalgamation of Pangea. However, arc systems which record Rheic Ocean subduction are poorly preserved. The preservation of Devonian detrital zircon in Late Devonian-Early Carboniferous siliciclastic rocks of SW Iberia, rather than arc-related igneous rocks indicates that direct evidence of the arc system may have been largely destroyed by erosion. Here we report in-situ detrital zircon U-Pb isotopic analyses of Late Devonian-Early Carboniferous siliciclastic rocks from the Pulo do Lobo Zone, which is a reworked Late Paleozoic suture zone located between Laurussia and Gondwana. Detrital zircon age spectra from the Pulo do Lobo Zone Frasnian formations show striking similarities, revealing a wide range of ages dominated by Neoproterozoic and Paleoproterozoic grains sourced from rocks typical of peri-Gondwanan terranes, such as Avalonia, the Meguma terrane and the Ossa-Morena Zone. Pulo do Lobo rocks also include representative populations of Mesoproterozoic and Early Silurian zircons that are typical of Avalonia and the Meguma terrane which are absent in the Ossa-Morena Zone. The Famennian-Tournaisian formations from the Pulo do Lobo Zone, however, contain more abundant Middle-Late Devonian zircon indicating the contribution from a previously unrecognized source probably related to the Rheic Ocean magmatic arc(s). The Middle-Late Devonian to Early Carboniferous zircon ages from the siliciclastic rocks of SW Iberia (South Portuguese, Pulo do Lobo and Ossa-Morena zones) have a wide range in εHfT values (- 8.2 to + 8.3) indicating the likely crystallization from magmas formed in a convergent setting. The missing Rheic Ocean arc was probably built on a Meguma/Avalonia type basement. We propose for the Pulo do Lobo Zone that the

  13. Data Reduction of Laser Ablation Split-Stream (LASS) Analyses Using Newly Developed Features Within Iolite: With Applications to Lu-Hf + U-Pb in Detrital Zircon and Sm-Nd +U-Pb in Igneous Monazite (United States)

    Fisher, Christopher M.; Paton, Chad; Pearson, D. Graham; Sarkar, Chiranjeeb; Luo, Yan; Tersmette, Daniel B.; Chacko, Thomas


    A robust platform to view and integrate multiple data sets collected simultaneously is required to realize the utility and potential of the Laser Ablation Split-Stream (LASS) method. This capability, until now, has been unavailable and practitioners have had to laboriously process each data set separately, making it challenging to take full advantage of the benefits of LASS. We describe a new program for handling multiple mass spectrometric data sets collected simultaneously, designed specifically for the LASS technique, by which a laser aerosol is been split into two or more separate "streams" to be measured on separate mass spectrometers. New features within Iolite ( enable the capability of loading, synchronizing, viewing, and reducing two or more data sets acquired simultaneously, as multiple DRSs (data reduction schemes) can be run concurrently. While this version of Iolite accommodates any combination of simultaneously collected mass spectrometer data, we demonstrate the utility using case studies where U-Pb and Lu-Hf isotope composition of zircon, and U-Pb and Sm-Nd isotope composition of monazite were analyzed simultaneously, in crystals showing complex isotopic zonation. These studies demonstrate the importance of being able to view and integrate simultaneously acquired data sets, especially for samples with complicated zoning and decoupled isotope systematics, in order to extract accurate and geologically meaningful isotopic and compositional data. This contribution provides instructions and examples for handling simultaneously collected laser ablation data. An instructional video is also provided. The updated Iolite software will help to fully develop the applications of both LASS and multi-instrument mass spectrometric measurement capabilities.

  14. Engineering cyber infrastructure for U-Pb geochronology: Tripoli and U-Pb_Redux (United States)

    Bowring, J. F.; McLean, N. M.; Bowring, S. A.


    In the past decade, major advancements in precision and accuracy of U-Pb geochronology, which stem from improved sample pretreatment and refined measurement techniques, have revealed previously unresolvable discrepancies among analyses from different laboratories. One solution to evaluating and resolving many of these discrepancies is the adoption of a common software platform that standardizes data-processing protocols, enabling robust interlaboratory comparisons. We present the results of a collaboration to develop cyber infrastructure for high-precision U-Pb geochronology based on analyzing accessory minerals by isotope dilution-thermal ionization mass spectrometry. This cyber infrastructure implements an architecture specifying the workflows of data acquisition, statistical filtering, analysis and interpretation, publication, community-based archiving, and the compilation and comparison of data from different laboratories. The backbone of the cyber infrastructure consists of two open-source software programs: Tripoli and U-Pb_Redux. Tripoli interfaces with commercially available mass spectrometers using standardized protocols, statistical filtering, and interactive visualizations to aid the analyst in preparing raw data for analysis in U-Pb_Redux. U-Pb_Redux implements the architecture by orchestrating the analyst's workflow with interactive visualizations and provides data reduction and uncertainty propagation that support data interpretations. Finally, U-Pb_Redux enables production of publication-ready graphics and data tables, the archiving of results, and the comparative compilation of archived results to support cooperative science.

  15. U-Pb dating by zircon dissolution method using chemical abrasion

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    Takehara, Lucy, E-mail: [Servico Geologico do Brasil (CPRM), Brasilia, DF (Brazil); Chemale Junior, Farid [Universidade de Brasilia (UnB), Brasilia, DF (Brazil). Inst. de Geociencias. Lab. de Geocronologia; Hartmann, Leo A. [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil). Inst. de Geociencias; Dussin, Ivo A.; Kawashita, Koji [Universidade de Sao Paulo (USP), SP, (Brazil). Centro de Pesquisa Geocronologicas


    Chemical abrasion was carried out on zircons grains of the Temora II standard for U-Pb dating prior to analyses using in situ Laser Ablation-Multi Collector Ion Coupled Plasma Mass Spectrometer (LA-ICPMS) followed by the Isotope Dissolution Thermal Ionization Mass Spectrometer (ID-TIMS) method. The proposed methodology was herein applied in order to reduce primarily the effects of secondary Pb loss, the presence of common lead and/or silicate impurities. Nine Temora II zircon grains were analyzed by the laser ablation method yielding an age of 418.3 +- 4.3 Ma. Zircon grains of a same population were separated for chemical abrasion before dissolution and mass spectrometry analyses. Six fractions of them were separated for isotope dissolution using {sup 235}U-{sup 205}Pb mixed spike after we have checked and assured the laboratory conditions of low blank values for total Pb of less than 2 pg/g. The obtained U-Pb zircon age by the ID-TIMS method was 415.7 +- 1.8 Ma (error 0.43 %) based on four successful determinations. The results are consistent with the published ages for the Temora diorite (Temora I - 416.75 +- 1.3 Ma; Temora II - 416.78 +- 0.33 Ma) and established as 416 +- 0.33 Ma. The technique is thus recommended for high precision U-Pb zircon analyses (error < 1 %), mainly for high resolution stratigraphic studies of Phanerozoic sequences. (author)

  16. Tracing the Cambro-Ordovician ferrosilicic to calc-alkaline magmatic association in Iberia by in situ U-Pb SHRIMP zircon geochronology (Gredos massif, Spanish Central System batholith) (United States)

    Díaz-Alvarado, Juan; Fernández, Carlos; Chichorro, Martim; Castro, Antonio; Pereira, Manuel Francisco


    U-Pb geochronological study of zircons from nodular granites and Qtz-diorites comprising part of Variscan high-grade metamorphic complexes in Gredos massif (Spanish Central System batholith) points out the significant presence of Cambro-Ordovician protoliths among the Variscan migmatitic rocks that host the Late Carboniferous intrusive granitoids. Indeed, the studied zone was affected by two contrasted tectono-magmatic episodes, Carboniferous (Variscan) and Cambro-Ordovician. Three main characteristics denote a close relation between the Cambro-Ordovician protholiths of the Prado de las Pozas high-grade metamorphic complex, strongly reworked during the Variscan Orogeny, and other Cambro-Ordovician igneous domains in the Central Iberian Zone of the Iberian Massif: (1) geochemical features show the ferrosilicic signature of nodular granites. They plot very close to the average analysis of the metavolcanic rocks of the Ollo de Sapo formation (Iberia). Qtz-diorites present typical calc-alkaline signatures and are geochemically similar to intermediate cordilleran granitoids. (2) Both Qtz-diorite and nodular granite samples yield a significant population of Cambro-Ordovician ages, ranging between 483 and 473 Ma and between 487 and 457 Ma, respectively. Besides, (3) the abundance of zircon inheritance observed on nodular granites matches the significant component of inheritance reported on Cambro-Ordovician metagranites and metavolcanic rocks of central and NW Iberia. The spatial and temporal coincidence of both peraluminous and intermediate granitoids, and specifically in nodular granites and Qtz-diorite enclaves of the Prado de las Pozas high-grade complex, is conducive to a common petrogenetic context for the formation of both magmatic types. Tectonic and geochemical characteristics describe the activity of a Cambro-Ordovician arc-back-arc tectonic setting associated with the subduction of the Iapetus-Tornquist Ocean and the birth of the Rheic Ocean. The extensional

  17. In situ analyses of gallstone inner layers by external PIXE

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    Rautray, Tapash R., E-mail: [Department of Dental Biomaterials, School of Dentistry, Kyungpook National University, 2-188-1 Samduk-dong, Jung-gu, Daegu (Korea, Republic of); Institute of Physics, Sachivalaya Marg, Bhubaneswar 751005 (India); ARASMIN, G. Udayagiri, Kandhamal, Orissa 762100 (India); Dutta, Koushik; Das, Saubhagya L. [Institute of Physics, Sachivalaya Marg, Bhubaneswar 751005 (India); Rautray, Alekh C. [ARASMIN, G. Udayagiri, Kandhamal, Orissa 762100 (India)


    External proton induced X-ray emission analyses were carried out to study the elemental profile at different points of two mixed gallstones inner layers. It was observed that ten minor/trace elements namely P, S, Ca, Mn, Fe, Cu, Zn, Br, Rb and Sr were present in the mixed gallstone layers. Among the elements detected, Ca shows the highest concentration whereas Br, Rb and Sr were found only at some points in trace level. Concentrations of Ca and P were observed to be the highest in the core of the gallstones. The presence of high amount of Cu and Zn on the surface of the gallstones, as compared to other layers, may be due to contamination with bile.

  18. Magmatic age of rare-earth element and zirconium mineralisation at the Norra Kärr alkaline complex, southern Sweden, determined by U-Pb and Lu-Hf isotope analyses of metasomatic zircon and eudialyte (United States)

    Sjöqvist, Axel S. L.; Cornell, David H.; Andersen, Tom; Christensson, Ulf I.; Berg, Johan T.


    The agpaitic Norra Kärr alkaline complex in southern Sweden is rich in heavy rare-earth elements and zirconium. Despite generally containing high concentrations of Zr, agpaitic rocks sensu stricto are devoid of igneous zircon. During the late stages of magmatic activity at Norra Kärr, metasomatic Na- and F-rich fluids transporting Zr complexes caused fenitisation (syn-magmatic alkali metasomatism) of the granitic wall rocks, which formed new metasomatic zircon. Fenite zircon was dated by LA-MC-ICP-MS with the U-Pb method at 1.49 ± 0.01 Ga, while the unaltered country rock granite was dated at 1.79 ± 0.01 Ga. Zircon in the fenites exhibits εHf + 6.58 ± 0.36 at 1.49 Ga; significantly above the expected value for Svecofennian crust at that time (ca. - 5 ± 2), but identical, within error, of that measured in eudialyte from Norra Kärr. This suggests a common source of Hf for fenite zircon and eudialyte from Norra Kärr, which isotopically strengthens the genetic link between fenite and nepheline syenite. The 1.49 Ga age dates not only the fenitisation, but also the relatively small agpaitic intrusion, which caused the fenitisation. This also dates the origin of the rare-earth element and Zr ore within the agpaitic nepheline syenite, which probably formed from an evolved magma derived from the mantle. A few zircon xenocrysts, which survived in the agpaitic nepheline syenite magma, may indicate the presence of an Archaean component in the basement.

  19. From opening to subduction of an oceanic domain constrained by LA-ICP-MS U-Pb zircon dating (Variscan belt, Southern Armorican Massif, France) (United States)

    Paquette, J.-L.; Ballèvre, M.; Peucat, J.-J.; Cornen, G.


    In the Variscan belt of Western Europe, the lifetime and evolution of the oceanic domain is poorly constrained by sparse, outdated and unreliable multigrain ID-TIMS U-Pb zircon dating. In this article, we present a complete in situ LA-ICP-MS dataset of about 300 U-Pb zircon analyses obtained on most of the ophiolitic and eclogitic outcrops of Southern Brittany, comprising new dating of previously published zircon populations and newly discovered rock samples. In situ dating and cathodo-luminescence imaging of each zircon grain yields new absolute time-constraints on the evolution of the Galicia-Moldanubian Ocean. The new results confirm that the opening of this oceanic domain is well defined at about 490 Ma. In contrast, the generally-quoted 400-410 Ma-age for the high-pressure event related to the subduction of the oceanic crust is definitely not recorded in the zircons of the eclogites. In light of these new data, we propose that the obduction of oceanic rocks occurred at about 370-380 Ma while the high-pressure event is recorded at 355 Ma in only a few zircon grains of some eclogite samples. Additionally, this large scale dating project demonstrates that the zircons from eclogites do not systematically recrystallise during the high pressure event and consequently their U-Pb systems do not record that metamorphism systematically. These zircons rather preserve the isotopic memory of the magmatic crystallization of their igneous protolith. Another example of an eclogite sample from the French Massif Central illustrates the frequent mistake in the interpretation of the ages of the early hydrothermal alteration of zircons in the oceanic crust versus partial or complete recrystallization during eclogite facies metamorphism.

  20. Conventional U-Pb dating versus SHRIMP of the Santa Barbara Granite Massif, Rondonia, Brazil (United States)

    Sparrenberger, I.; Bettencourt, Jorge S.; Tosdal, R.M.; Wooden, J.L.


    The Santa Ba??rbara Granite Massif is part of the Younger Granites of Rondo??nia (998 - 974 Ma) and is included in the Rondo??nia Tin Province (SW Amazonian Craton). It comprises three highly fractionated metaluminous to peraluminous within-plate A-type granite units emplaced in older medium-grade metamorphic rocks. Sn-mineralization is closely associated with the late-stage unit. U-Pb monazite conventional dating of the early-stage Serra do Cicero facies and late-stage Serra Azul facies yielded ages of 993 ?? 5 Ma and 989 ?? 13 Ma, respectively. Conventional multigrain U-Pb isotope analyses of zircon demonstrate isotopic disturbance (discordance) and the preservation of inherited older zircons of several different ages and thus yield little about the ages of Sn-granite magmatism. SHRIMP U-Pb ages for the Santa Ba??rbara facies association yielded a 207Pb/206Pb weighted-mean age of 978 ?? 13 Ma. The textural complexity of the zircon crystals of the Santa Ba??rbara facies association, the variable concentrations of U, Th and Pb, as well as the mixed inheritance of zircon populations are major obstacles to using conventional multigrain U-Pb isotopic analyses. Sm-Nd model ages and ??Nd (T) values reveal anomalous isotopic data, attesting to the complex isotopic behaviour within these highly fractionated granites. Thus, SHRIMP U-Pb zircon and conventional U-Pb monazite dating methods are the most appropriate to constrain the crystallization age of the Sn-bearing granite systems in the Rondo??nia Tin Province.

  1. Detrital zircon U-Pb geochronology, Lu-Hf isotopes and REE geochemistry constrains on the provenance and tectonic setting of Indochina Block in the Paleozoic (United States)

    Wang, Ce; Liang, Xinquan; Foster, David A.; Fu, Jiangang; Jiang, Ying; Dong, Chaoge; Zhou, Yun; Wen, Shunv; Van Quynh, Phan


    In situ U-Pb geochronology, Lu-Hf isotopes and REE geochemical analyses of detrital zircons from Cambrian-Devonian sandstones in the Truong Son Belt, central Vietnam, are used to provide the information of provenance and tectonic evolution of the Indochina Block. The combined detrital zircon age spectra of all of the samples ranges from 3699 Ma to 443 Ma and shows with dominant age peaks at ca. 445 Ma and 964 Ma, along with a number of age populations at 618-532 Ma, 1160-1076 Ma, 1454 Ma, 1728 Ma and 2516 Ma. The zircon age populations are similar to those from time equivalent sedimentary sequences in continental blocks disintegrated from the East Gondwana during the Phanerozoic. The younger zircon grains with age peaks at ca. 445 Ma were apparently derived from middle Ordovician-Silurian igneous and metamorphic rocks in Indochina. Zircons with ages older than about 600 Ma were derived from other Gondwana terrains or recycled from the Precambrian basement of the Indochina Block. Similarities in the detrital zircon U-Pb ages suggest that Paleozoic strata in the Indochina, Yangtze, Cathaysia and Tethyan Himalayas has similar provenance. This is consistent with other geological constrains indicating that the Indochina Block was located close to Tethyan Himalaya, northern margin of the India, and northwestern Australia in Gondwana.

  2. Ion Microprobe U-Pb Dating of Zagami Phosphates (United States)

    Sano, Y.; Koike, M.; Takahata, N.; Terada, K.


    We report U-Pb dating of Zagami phosphates using SHRIMP and NanoSIMS. A least-squares fit gives 238U-206Pb isochron age of 363 ± 120 Ma and total Pb/U age of 300 ± 84 Ma, which are older than 180 ± 7 Ma of baddeleyite of Zagami in literature.

  3. Coordinated In Situ Analyses of Organic Nanoglobules in the Sutter's Mill Meteorite (United States)

    Nakamura--Messenger, K.; Messenger, S.; Keller, L. P.; Clemett, S. J.; Nguyen, A. N.; Gibson, E. K.


    The Sutter s Mill meteorite is a newly fallen carbonaceous chondrite that was collected and curated quickly after its fall [1]. Preliminary petrographic and isotopic investigations suggest affinities to the CM2 carbonaceous chondrites. The primitive nature of this meteorite and its rapid recovery provide an opportunity to investigate primordial solar system organic matter in a unique new sample. Organic matter in primitive meteorites and chondritic porous interplanetary dust particles (CP IDPs) is commonly enriched in D/H and N-15/N-14 relative to terrestrial values [2-4]. These anomalies are ascribed to the partial preservation of presolar cold molecular cloud material [2]. Some meteorites and IDPs contain gm-size inclusions with extreme H and N isotopic anomalies [3-5], possibly due to preserved primordial organic grains. The abundance and isotopic composition of C in Sutter's Mill were found to be similar to the Tagish Lake meteorite [6]. In the Tagish Lake meteorite, the principle carriers of large H and N isotopic anomalies are sub-micron hollow organic spherules known as organic nanoglobules [7]. Organic nanoglobules are commonly distributed among primitive meteorites [8, 9] and cometary samples [10]. Here we report in-situ analyses of organic nano-globules in the Sutter's Mill meteorite using UV fluorescence imaging, Fourier-transform infrared spectroscopy (FTIR), scanning transmission electron microscopy (STEM), NanoSIMS, and ultrafast two-step laser mass spectrometry (ultra-L2MS).

  4. Apatite U-Pb thermochronolgy applied to complex geological settings - insights from geo/thermochronology and geochemistry (United States)

    Paul, Andre; Spikings, Richard; Ulyanov, Alexey; Chew, David


    Application of high temperature (>350oC) thermochronology is limited to the U-Pb system of accessory minerals, such as apatite, under the assumption that radiogenic lead is lost to thermally activated volume diffusion into an infinite reservoir. Cochrane et al. (2015) have demonstrated a working example from the northern Andes of South America. Predictions from volume diffusion theory were compared with measured single grain U-Pb date correlated to shortest diffusion radius and in-situ profiles measured by LA-ICP-MS. Results from both techniques were found to be in agreement with predictions from thermally activated, volume diffusion. However, outliers from the ID-TIMS data suggested some complexity, as grains were found to be too young relative to their diffusion radius. Interaction of multiple processes can be responsible for the alteration of apatite U-Pb dates such as: (1) metamorphic (over)growth, (2) fluid aided alteration/recrystallization and (3) metamictization and fracturing of the grain. Further, predictions from volume diffusion rely on the input parameters: (a) diffusivity, (b) activation energy and (c) shortest diffusion radius. Diffusivity and activation energy are potentially influenced by the chemical composition and subsequent changes in crystal structure. Currently there is one value for diffusion parameter and activation energy established for (Durango) apatite (Cherniak et al., 1991). Correlation between diffusivity/activation energy and composition has not been established. We investigate if correlations exist between diffusivity/activation energy and composition by obtaining single grain apatite U-Pb date and chemical compostion and correlating these to their diffusion radius. We test the consistency of apatite closure temperature, by comparing the apatite U-Pb dates with lower temperature thermochronometers such as white mica and K-feldspar Ar/Ar and by petrographic observations. We test if chemical information can be a proxy to identify

  5. A Zircon U-Pb Study of the Evolution of Lunar KREEP (United States)

    Meyer, Charles; Nemchin, A.; Pidgeon, R.; Whitehouse, M.; Vaughan, J.


    SIMS U-Pb analyses show that zircons from breccias from Apollo 14 and Apollo 17 have essentially identical age distributions in the range 4350 to 4200 Ma but, whereas Apollo 14 zircons additionally show ages from 4200 to 3900 Ma, the Apollo 17 samples have no zircons with ages zircon results also show an uneven distribution with distinct peaks of magmatic activity. In explaining these observations we propose that periodic episodes of KREEP magmatism were generated from a primary reservoir of KREEP magma, which contracted over time towards the centre of Procellarum KREEP terrane.

  6. Detrital zircon U-Pb and Hf isotopic data for meta-sedimentary rocks from the Heilongjiang Complex, northeastern China and tectonic implications (United States)

    Zhu, Chloe Yanlin; Zhao, Guochun; Sun, Min; Han, Yigui; Liu, Qian; Eizenhöfer, Paul R.; Zhang, Xiaoran; Hou, Wenzhu


    The Heilongjiang Complex is a blueschist facies metamorphic belt located within the Zhangguangcailing Orogen between the Jiamusi and Songliao blocks in Northeast China. This complex has been regarded as an accretionary belt related to the subduction of an intervening oceanic domain between the two blocks. However, the timing of ocean closure and final amalgamation has not been well constrained, with different models arguing for a period of 210-180 Ma or sometime after 140 Ma. This work reports in-situ detrital zircon U-Pb and Hf isotopic analyses of meta-sedimentary rocks from the Heilongjiang Complex. Detrital zircons from seven meta-sedimentary rocks samples yield U-Pb ages spanning from 1690 to 167 Ma, with main populations matching those of multi-phase magmatism in the Jiamusi and Songliao blocks. Several Precambrian age groups (600 Ma, 700 Ma, 900 Ma, 960 Ma, 1200 Ma, and 1300 Ma) are consistent with the inherited zircons from the mafic rocks in the Heilongjiang Complex. A comparison with compiled data of magmatic rocks suggests that the two blocks may have been connected to each other during Permian time. Detrital zircon dating of all siliciclastic rocks yielded the youngest age component of 170 Ma, suggesting that the latest deposition of the mica schists happened at some time after 170 Ma. We propose that the Jiamusi and Songliao blocks once existed as a single block around Late Permian, which underwent a rifting event in the Permian to form a rifting basin that was subsequently evolved into an oceanic domain (Heilongjiang Ocean). The closure of the Heilongjiang Ocean occurred after 170 Ma.

  7. U-Pb age and Hf-O isotopes of detrital zircons from Hainan Island: Implications for Mesozoic subduction models (United States)

    Jiang, Xiao-Yan; Li, Xian-Hua; Collins, W. J.; Huang, Hui-Qing


    A compilation of magmatic ages from the Mesozoic South China Block suggests a number of "magmatic quiescence" periods at ca. 205-195 Ma, ca. 150-140 Ma and ca. 125-115 Ma, casting doubt on tectonic models that suggest ongoing Andean-type subduction along the South China continental margin. However, SIMS U-Pb analyses on two detrital zircon samples from the Cretaceous Lumuwan Formation on Hainan Island, southeast China, reveal three major age peaks at ca. 120 Ma, ca. 155 Ma and ca. 235 Ma. Zircons of these ages are mostly euhedral and show typical magmatic oscillatory zoning, suggesting short-distance transport from nearby magmatic sources. The extremely rare occurrence of ca. 120 Ma magmatic records onshore suggests that detrital zircons of this age population may be derived from a source proximal to Hainan Island but presently missing. Therefore, our data provide new evidence for ongoing magmatic activity in late Mesozoic South China. In situ Hf and O isotope analyses of the Mesozoic detrital zircons reveal large variations in both εHf(t) (- 21.2 to 10.5) and δ18O (4.4‰ to 13.6‰) values. A general negative correlation between them suggests the reworking of old supracrustal materials (average crustal residence age of ca. 2.0 Ga) by juvenile mantle-derived magmas. The progression of increasing εHf(t) and decreasing δ18O values of zircons from the Triassic to the Cretaceous suggests progressive crustal growth during the Mesozoic. The results are consistent with hybridization at an active continental margin. We briefly review tectonic models for the Indosinian orogeny and suggest that the petrologic evidence indicates that Mesozoic magmatism was part of the circum-Pacific accretionary orogens that formed along the continental margin of East Asia no later than ca. 250 Ma and continued at least to the late Cretaceous.

  8. Impact of spectral resolution of in situ ocean color radiometric data in satellite matchups analyses. (United States)

    Zibordi, Giuseppe; Talone, Marco; Voss, Kenneth J; Johnson, B Carol


    The spectral resolution requirements for in situ remote sensing reflectanceR RS measurements aiming at supporting satellite ocean color validation and System Vicarious Calibration (SVC) were investigated. The study, conducted using sample hyperspectral R RS from different water types, focused on the visible spectral bands of the ocean land color imager (OLCI) and of the Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) satellite sensors. Allowing for a ±0.5% maximum difference between in situ and satellite derived R RS solely due to the spectral band characteristics of the in situ radiometer, a spectral resolution of 1 nm for SVC of PACE is needed in oligotrophic waters. Requirements decrease to 3 nm for SVC of OLCI. In the case of validation activities, which exhibit less stringent uncertainty requirements with respect to SVC, a maximum difference of ±1% between in situ and satellite derived data indicates the need for a spectral resolution of 3 nm for both OLCI and PACE in oligotrophic waters. Conversely, spectral resolutions of 6 nm for PACE and 9 nm for OLCI appear to satisfy validation activities in optically complex waters.

  9. Soft nanomaterials analysed by in situ liquid TEM: Towards high resolution characterisation of nanoparticles in motion

    Directory of Open Access Journals (Sweden)

    Joseph P. Patterson


    Full Text Available In this article we present in situ transmission electron microscopy (TEM of soft, synthetic nanoparticles with a comparative analysis using conventional TEM methods. This comparison is made with the simple aim of describing what is an unprecedented example of in situ imaging by TEM. However, we contend the technique will quickly become essential in the characterisation of analogous systems, especially where dynamics are of interest in the solvated state. In this case, particles were studied which were obtained from the direct polymerisation of an oxaliplatin analogue, designed for an ongoing programme in novel chemotherapeutic delivery systems. The resulting nanoparticles provided sufficient contrast for facile imaging in situ, and point towards key design parameters that enable this new characterisation approach for organic nanomaterials. We describe the preparation of the synthetic nanoparticles together with their characterisation in liquid water. Finally, we provide a future perspective of this technique for the analysis of soft and dynamic nanomaterials and discussion the progress which needs to be made in order to bring in situ liquid TEM to its full potential.

  10. Late cenozoic magmatism in the South Patagonian batholith: SHRIMP U-Pb zircon age evidence

    International Nuclear Information System (INIS)

    Fanning, C.M; Herve, F; Pankhurst, R.J; Thomson, S; Faundez, V


    The North Patagonian Batholith (NPB) has a zonal age pattern which includes a well defined belt of Miocene and Mio-Pliocene plutons in its central portion (Pankhurst et al., 1999) which are spatially, and probably genetically related to the Liquine-Ofqui Fault Zone. Previous geochronological studies in the Southern Patagonian Batholith (SPB), as summarized by Bruce et al. (1991), have yielded 9 late Cenozoic K-Ar or Ar-Ar ages out of a total of 116 age determinations. None of these young ages correspond to U-Pb determinations on zircons, and some of the young ages correspond to satellite plutons east of the SPB proper, such as the Torres del Paine intrusion. In this paper we present the first late Cenozoic SHRIMP U-Pb zircon ages in the area of the SPB. The morphology of the analysed zircon crystals is described and leads to some inferences on the methodology and on the geological interpretation of the obtained ages (au)

  11. The U Pb systematics of angrite Sahara 99555 (United States)

    Amelin, Yuri


    Angrite Sahara 99555 (hereafter SAH), precisely dated by Baker et al. (Baker J., Bizzarro M., Wittig N., Connelly J. and Haack H. (2005) Early planetesimal melting from an age of 4.5662 Gyr for differentiated meteorites. Nature436, 1127-1131), has been proposed as a new reference point for the early Solar System timescale and for calculation of the revised minimum age of our Solar System. The Pb-Pb age of SAH of 4566.18 ± 0.14 Ma, reported by Baker et al., differs from the Pb-Pb age of D'Orbigny, another basaltic angrite, of 4564.42 ± 0.12 Ma (Amelin Y. (2008) U-Pb ages of angrites. Geochim. Cosmochim. Acta72, 221-232), despite the fact that the relative 53Mn- 53Cr and 182Hf- 182W ages of these meteorites are identical. Here I report U-Pb data for 21 whole rock and pyroxene fractions from SAH, analyzed using the same approach as D'Orbigny (Amelin, 2008). These fractions contain between 1.3 and 8.9 pg of total common Pb, slightly more than analytical blank. Measured 206Pb/ 204Pb ratios are between 625 and 2817 for D'Orbigny, blank-corrected 206Pb/ 204Pb ratios are between 1173 and 6675. Eight acid-washed whole rock fractions yielded an isochron age of 4564.86 ± 0.38 Ma, MSWD = 1.5. Data for pyroxene fractions plot mostly above the whole rock isochron, and do not form a linear array in 207Pb/ 206Pb vs. 204Pb/ 206Pb isochron coordinates. The 207Pb ∗/ 206Pb ∗ model dates of the pyroxene fractions vary from 4563.8 ± 0.3 to 4567.1 ± 0.5 Ma. The difference between whole rock and pyroxene U-Pb systematics may be a result of re-distribution of radiogenic Pb at a mineral grain scale several million years after crystallization. Complexities of Sm-Nd, Lu-Hf, and possibly 26Al- 26Mg mineral systematics of SAH, described previously, may be related to the same process that caused the re-distribution of radiogenic Pb. Disturbance of isotopic chronometers renders SAH an imperfect anchor for the early Solar System timescale. The problems with age determination revealed by

  12. Confocal X-ray fluorescence spectrometer for in-situ analyses of paintings (United States)

    Trojek, Tomáš; Prokeš, Radek; Šefců, Radka; Bilavčíková, Hana; Čechák, Tomáš


    This paper describes the properties of the newly constructed device for confocal X-ray fluorescence analysis that was tested with a sample plate consisting of 19 combinations of two single pigment layers. The preparation of this experimental wooden board with layered systems was based on knowledge of the panel painting techniques of Bohemian collections from the National Gallery in Prague dating back to the 14th and 15th centuries. The design of the confocal setup allows its transport and the in-situ measurement of paintings in depositories or even in exhibition areas. The advantages of our confocal setup with movable collimating optics are also described.

  13. Miniaturised 'lab-on-a-chip' nitrate analyser applied to high resolution in situ analysis of glacial meltwater (United States)

    Beaton, A.; Mowlem, M.; Wadham, J. L.


    In situ chemical measurements of glacial meltwater can provide high temporal and spatial resolution data that allow us to infer biogeochemical processes and calculate export from glacial systems. Despite this, in situ measurements of single chemical parameters in glacial meltwater have so far largely been restricted to pH and dissolved oxygen. The lack of high performance ruggedized in situ sensors for other analytes means that the laboratory-based analysis of manually collected samples is still routine. Microfluidics (through lab-on-a-chip technology) permits the miniaturisation of established chemical analysis techniques so that they can be performed in situ. The advantages of decreased size and low power and reagent consumption make these systems suitable for deployment in extreme and inaccessible environments where regular manual sample collection is logistically difficult. We present data from a novel stand-alone microfluidic wet chemical nitrate analyser that has been deployed to monitor a proglacial meltwater river draining from the Greenland ice sheet. By performing a measurement every 20 minutes, the analyser was able to reveal diurnal fluctuations and short term trends in nitrate concentrations that would not discernible using standard daily sampling. High resolution in situ measurements such as these can allow a more accurate determination of nutrient export fluxes from glacial systems into the polar oceans, and allow enhanced interpretation of water quality datasets. Steps have been taken to ruggedize the system so that it can survive the freeze-thaw conditions, dilute concentrations and high sediment loads that can be associated with cryospheric environments. The system is small, has low power consumption and detects nitrate and nitrite with a limit of detection (LOD) of 0.025 μM, which is sufficient for low nutrient glacial environments. On-going work looks to deploy similar nutrient analysers more widely, not only in glacial systems, but also in

  14. Fungal-Induced Deterioration of Mural Paintings: In Situ and Mock-Model Microscopy Analyses. (United States)

    Unković, Nikola; Grbić, Milica Ljaljević; Stupar, Miloš; Savković, Željko; Jelikić, Aleksa; Stanojević, Dragan; Vukojević, Jelena


    Fungal deterioration of frescoes was studied in situ on a selected Serbian church, and on a laboratory model, utilizing standard and newly implemented microscopy techniques. Scanning electron microscopy (SEM) with energy-dispersive X-ray confirmed the limestone components of the plaster. Pigments used were identified as carbon black, green earth, iron oxide, ocher, and an ocher/cinnabar mixture. In situ microscopy, applied via a portable microscope ShuttlePix P-400R, proved very useful for detection of invisible micro-impairments and hidden, symptomless, microbial growth. SEM and optical microscopy established that observed deterioration symptoms, predominantly discoloration and pulverization of painted layers, were due to bacterial filaments and fungal hyphal penetration, and formation of a wide range of fungal structures (i.e., melanized hyphae, chlamydospores, microcolonial clusters, Cladosporium-like conidia, and Chaetomium perithecia and ascospores). The all year-round monitoring of spontaneous and induced fungal colonization of a "mock painting" in controlled laboratory conditions confirmed the decisive role of humidity level (70.18±6.91% RH) in efficient colonization of painted surfaces, as well as demonstrated increased bioreceptivity of painted surfaces to fungal colonization when plant-based adhesives (ilinocopie, murdent), compared with organic adhesives of animal origin (bone glue, egg white), are used for pigment sizing.

  15. A compact μ-XRF spectrometer for (in situ) analyses of cultural heritage and forensic materials

    International Nuclear Information System (INIS)

    Vittiglio, G.; Bichlmeier, S.; Klinger, P.; Heckel, J.; Fuzhong, W.; Vincze, L.; Janssens, K.; Engstroem, P.; Rindby, A.; Dietrich, K.; Jembrih-Simbuerger, D.; Schreiner, M.; Denis, D.; Lakdar, A.; Lamotte, A.


    A compact, light weight and relatively inexpensive μ-XRF instrument that allows for non-destructive and local analysis of sub-mm samples with minor/trace level sensitivity was developed. Two versions of this prototype instrument exist: a table-top version that can be used in a laboratory environment while for in situ measurements a readily transportable version was constructed. Polycapillary lenses are used to focus the primary X-ray beam down to the level of 70-100 μm in diameter. Relative detection limits of transition elements in biological and glass matrices are situated at the 10-100 ppm level. These instruments are useful for characterization of various materials from the cultural heritage and forensic sector

  16. In situ mid-infrared analyses of reactive gas-phase intermediates in TEOS/Ozone SAPCVD

    International Nuclear Information System (INIS)

    Whidden, Thomas K.; Doiron, Sarah


    In this report, we present in situ characterizations of chemical vapour deposition (CVD) reactors used in silicon dioxide thin film depositions. The characterizations are based on Fourier transform infrared spectroscopy. The infrared absorption data are interpreted within the context of process and thin film properties and the bearing of the spectroscopic data upon the chemical mechanisms extant in the deposition reaction. The relevance of the interpretations to real-time process control is discussed. The process under study in this work is TEOS/ozone-based deposition of silicon dioxide thin films at subatmospheric pressures. This process exhibits many desirable properties but has fundamental problems that may be solvable by reaction control based on in situ analyses and the real-time manipulation of reagent concentrations and process conditions. Herein we discuss our preliminary data on characterizations of TEOS/ozone chemistries in commercial reactor configurations. Reaction products and reactive intermediate species are detected and identified. Quantitative in situ measurements of the reagent materials are demonstrated. Preliminary correlations of these data with process and thin film properties are discussed

  17. The challenge of multi-parameter hydrochemical, gas-physical, and isotopic analyses of in-situ clay pore water and samples from in-situ clay experiments

    International Nuclear Information System (INIS)

    Eichinger, L.; Lorenz, G.D.; Eichinger, F.; Wechner, S.; Voropaev, A.


    Document available in extended abstract form only. Within the research framework of natural clay rocks used as barriers for radioactive waste confinement comprehensive analyses are mandatory to determine the chemical and isotopic composition of natural pore water and therein dissolved gases as well as samples from distinct in-situ and lab experiments. Based on the natural conditions pore waters from low permeable argillaceous rocks can be sampled only in small amounts over long time periods. Often those samples are primarily influenced by processes of the exploration and exploitation such as the contamination by drilling fluid and disinfection fluid or cement-water interactions. Sophisticated equipment for circulation experiments allows the sampling of gas and water in the original state in steel and peek cells. The challenge though is to optimise the lab equipment and measurement techniques in a way that the physical-chemical conditions of the water can be analysed in the original state. The development of special micro measuring cells enables the analyses of physical parameters like redox potential under very slow through-flow conditions. Additional analyses can follow subsequently without wasting any drop of the precious pore water. The gas composition is measured in equilibrated gas phases above water phases after emptying a defined volume by inert gas or through manual pressure. The analytical challenge is to obtain an extensive set of parameters which is considered representative for the in-situ conditions using only a few millilitres of water. The parameter analysis includes the determination of the composition of the water, the isotopic compositions of the water and the dissolved constituents as well as their gas concentrations and isotopic signatures. So far the smallest sample volume needed for an analysis of a full set of parameters including the gas composition was 9 ml of water. Obviously, the analysis requires a highly sophisticated infrastructure and

  18. High-precision Temporal Calibration of the Early Cambrian Biotic and Paleoenvironmental Records: New U-Pb Geochronology from Eastern Yunnan, China. (United States)

    Tsukui, K.; Ramezani, J.; Zhu, M.; Maloof, A. C.; Porter, S.; Moore, J.; Eddy, M. P.; Bowring, S. A.


    The Terreneuvian Epoch of the early Cambrian marks the global diversification of early animal life, as well as major perturbations to Earth's geochemical cycles. Understanding possible links between biotic evolution (e.g., emergence of skeletal animals) and the recognized changes in ocean chemistry requires a high fidelity chronostratigraphic framework for the early Cambrian records. One such chronostratigraphy was built by mapping local early Cambrian carbon isotope profiles onto a U-Pb age-calibrated marine carbonate δ13C record from Morocco, assuming global synchroneity of the observed δ13C trends. Here we present a direct test of this assumption using high-precision U-Pb geochronology (CA-ID-TIMS method) of ash beds from key lower Cambrian horizons throughout eastern Yunnan Province in South China. Preliminary age results from ash beds near the top of the Dengying Formation (Fm.) and the basal Daibu Member (Mb.) of the Zhujiaqing Fm. in multiple sections place the basal Cambrian negative δ13C excursion (BACE) in China at ca. 540.7-539.6 Ma. Our new U-Pb dates from the overlying Zhongyicun Mb. at the Meishucun and nearby sections improve significantly upon previous in situ U-Pb geochronology and constrain the onset of high-frequency δ13C oscillations in some sections to between 533.5 and 532.9 Ma. Most importantly, a new U-Pb date of ca. 526 Ma from the basal Shiyantou Fm. in the Xiaotan Section marks the termination of a >1 million year-long period of consistently positive (≥+4‰) δ13C values (ZHUCE) that is characteristic of many early Cambrian records worldwide. This date establishes a robust time correlation between ZHUCE in South China and its equivalent 5p excursion in Morocco and Siberia, and constrains the timing and duration of the largest positive δ13C anomalies in the Cambrian.

  19. U-Pb age of zircons from rocks of Keret granite-greenstone system in the junction zone of Karelian and Belomorian structure of the Baltic Shield

    International Nuclear Information System (INIS)

    Bibikova, E.V.; Slabunov, A.I.; Kirnozova, T.I.; Makarov, V.A.; Kevlich, V.I.


    The U-Pb isotope analyses on accessory zircons from the three rock samples, reflecting various stages of the evolution structure, are carried out with the purpose of determining the time of the green-stone system formation and its tectonic-thermal retreatment in the junction zone of the Karelian granite-greenstone area and Belomorian traversing belt

  20. U-Pb zircon ages and structural development of metagranitoids of the Teplá crystalline complex: evidence for pervasive Cambrian plutonism within the Bohemian massif (Czech Republic)

    Czech Academy of Sciences Publication Activity Database

    Dörr, W.; Fiala, Jiří; Vejnar, Zdeněk; Zulauf, G.


    Roč. 87, č. 1 (1998), s. 135-149 ISSN 0016-7835 R&D Projects: GA AV ČR KSK1012601 Grant - others:DFG(DE) Zu73/1-3 Keywords : Cambrian plutonism * U-Pb analyses * Bohemian massif Subject RIV: DB - Geology ; Mineralogy Impact factor: 0.841, year: 1998

  1. In situ analyses of Ag speciation in tissues of cucumber and wheat using synchrotron-based X-ray absorption spectroscopy (United States)

    U.S. Environmental Protection Agency — In situ analyses of Ag speciation in tissues of cucumber and wheat using synchrotron-based X-ray absorption spectroscopy showing spectral fitting and linear...

  2. U-Pb geochronology of Gangdese (Transhimalaya) plutonism in the Lhasa-Xigaze region, Tibet

    International Nuclear Information System (INIS)

    Schaerer, U.; Allegre, C.J.; Paris-6 Univ., 75; Paris-7 Univ., 75; Xu, R.H.


    A series of different plutons from the Lhasa-Xigaze segment of the Gangdese (Transhimalaya) belt has been studied by high-resolution U-Pb analyses of zircon (using zircon fractions of 5-100 grains each, selected upon specific grain characteristics). For two diorites, located east of Xigaze (Dazhuka), the zircons yield concordant ages of 93.4 +- 1.0 and 94.2 +- 1.0 m.y., respectively. Also concordant ages of 41.1 +- 0.4 and 41.7 +- 0.4 m.y. have been obtained for two granodiorites, collected southwest of Lhasa (Qushui). The precision on the ages of two granites from the Xigaze and Lhasa area, is limited by two factors: the presence of inherited radiogenic lead and the occurrence of subsequent lead loss. However, some concordant zircons, detected in both granites, define approximate ages of about 67 and 53 m.y., respectively. The inherited lead components show the melting of Precambrian material was involved in magma genesis. The U-Pb ages substantiate a magmatic activity lasting from mid-Cretaceous (Cenomanian) to Eocene (Lutetian) time. Such a period of plutonism at the southern margin of Eurasia, as well as the occurrence of magma generation from continental crust, suggest that the Gangdese range results from the subduction of Tethys oceanic lithosphere (Indian plate) underneath Eurasia (Eurasian plate). If this model is true, the collision of India with Eurasia (Along the Lhasa-Xigaze sector) postdates the emplacement of the 41 m.y. old Gangdese granodiorites, i.e. the collision occurred after Lutetian time. (orig.)

  3. Evolution of the African continental crust as recorded by U-Pb, Lu-Hf and O isotopes in detrital zircons from modern rivers (United States)

    Iizuka, Tsuyoshi; Campbell, Ian H.; Allen, Charlotte M.; Gill, James B.; Maruyama, Shigenori; Makoka, Frédéric


    To better understand the evolutionary history of the African continental crust, a combined U-Pb, Lu-Hf and O isotopic study has been carried out by in situ analyses of approximately 450 detrital zircon grains from the Niger, Nile, Congo, Zambezi and Orange Rivers. The U-Pb isotopic data show age peaks at ca. 2.7, 2.1-1.8, 1.2-1.0, ca. 0.8, 0.7-0.5 and ca. 0.3 Ga. These peaks, with the exception of the one at ca. 0.8 Ga, correspond with the assembly of supercontinents. Furthermore, the detrital zircons that crystallized during these periods of supercontinent assembly have dominantly non-mantle-like O and Hf isotopic signatures, in contrast to the ca. 0.8 Ga detrital zircons which have juvenile characteristics. These data can be interpreted as showing that continental collisions during supercontinent assembly resulted in supermountain building accompanied by remelting of older continental crust, which in turn led to significant erosion of young igneous rocks with non-mantle-like isotopic signatures. Alternatively, the data may indicate that the major mode of crustal development changed during the supercontinent cycle: the generation of juvenile crust in extensional settings was dominant during supercontinent fragmentation, whereas the stabilization of the generated crust via crustal accretion and reworking was important during supercontinent assembly. The Lu-Hf and O isotope systematics indicate that terreigneous sediments could attain elevated 18O/16O via prolonged sediment-sediment recycling over long crustal residence time, and also that reworking of carbonate and chert which generally have elevated 18O/16O and low Hf contents is minor in granitoid magmatism. The highest 18O/16O in detrital zircon abruptly increased at ca. 2.1 Ga and became nearly constant thereafter. This indicates that reworking of mature sediments increased abruptly at that time, probably as a result of a transition in the dynamics of either granitoid crust formation or sedimentary evolution

  4. Polymetamorphic history of the Crixas-Acu gneiss, central Brazil: SHRIMP U-Pb evidence from titanite and zircon

    International Nuclear Information System (INIS)

    Queiroz, Claudia Lima; Jost, Hardy; McNaughton, Neil J.; Fletcher, I.R.; Barley, Mark E.


    A sample of the Crixas-Acu gneiss in Central Brazil contains protolith and metamorphic zircons, and two generations of metamorphic titanite. SHRIMP U-Pb data of these different mineral generations indicate the following temporal sequence: tonalitic magmatism at 2817 ± 9 M.y derived from an older source region (3050 to 2930 M.y zircon cores); Archaen metamorphic at 2772±6 M.y (from zircon)with cooling to the blocking temperature of titanite (at 2711 ±34 Ma); followed by Paleoproterozoic metamorphism and weak fabric development at 2011 ±+ 15 Ma, and a possible Neoproterozoic metamorphism. The field relations and these age data indicate the polymetamorphic history of the area and demonstrate the value of in situ age determinations on well-characterized rocks. (author)

  5. Ion microprobe U-Pb dating of a dinosaur tooth

    International Nuclear Information System (INIS)

    Sano, Yuji; Terada, Kentaro; Ly, Chi V.; Park, Eun Ju


    Ion microprobe U-Pb dating of apatite is applied to a fossil tooth of a Allosaurid derived from the Hasandong Formation in the Gyeongsang basin, southeastern Korea. Twelve spots on a single fragment of the fossil dentine yield a Tera-Wasserburg concordia intercept age of 115±10 Ma (2σ, MSWD=0.59) on a 238 U/ 206 Pb- 207 Pb/ 206 Pb- 204 Pb/ 206 Pb diagram. The age provides a constraint on the depositional age of the fossil in its host Hassandong Formation as Early Aptian. The success of the ion microprobe dating depends on the heterogeneities of diagenetically incorporated U and Pb at the few hundred μm scale, the consequent variations in Pb isotopic compositions due to radioactive decay and the closed-system behavior of U and Pb. There are at least three end-members to explain the variations of minor chemical components such as FeO, SiO 2 and Al 2 O 3 , and trace elements as Th, U and rare earth elements (REE) in the sample by a simple mixing model. They are (1) very low minor and REE, very high common Pb with variable U abundances, (2) low common Pb, high minor, REE, and U abundances, and (3) low minor, common Pb, and U with intermediate REE abundances, even though groups (2) and (3) may consist of a larger group. Various contributions of the three (and/or two) end-members during diagenetic processes may cause the elemental fractionation of U and Pb in a fossil tooth. (author)

  6. High spatial resolution U-Pb geochronology and Pb isotope geochemistry of magnetite-apatite ore from the Pea Ridge iron oxide-apatite deposit, St. Francois Mountains, southeast Missouri, USA (United States)

    Neymark, Leonid; Holm-Denoma, Christopher S.; Pietruszka, Aaron; Aleinikoff, John N.; Fanning, C. Mark; Pillers, Renee M.; Moscati, Richard J.


    The Pea Ridge iron oxide-apatite (IOA) deposit is one of the major rhyolite-hosted magnetite deposits of the St. Francois Mountains terrane, which is located within the Mesoproterozoic (1.5–1.3 Ga) Granite-Rhyolite province in the U.S. Midcontinent. Precise and accurate determination of the timing and duration of oreforming processes in this deposit is crucial for understanding its origin and placing it within a deposit-scale and regional geologic context. Apatite and monazite, well-established U-Pb mineral geochronometers, are abundant in the Pea Ridge orebody. However, the potential presence of multiple generations of dateable minerals, processes of dissolution-reprecipitation, and occurrence of micrometer-sized intergrowths and inclusions complicate measurements and interpretations of the geochronological results. Here, we employ a combination of several techniques, including ID-TIMS and high spatial resolution geochronology of apatite and monazite using LA-SC-ICPMS and SHRIMP, and Pb isotope geochemistry of pyrite and magnetite to obtain the first direct age constraints on the formation and alteration history of the Pea Ridge IOA deposit. The oldest apatite TIMS 207Pb*/206Pb* dates are 1471 ± 1 and 1468 ± 1 Ma, slightly younger than (but within error of) the ~1474 to ~1473 Ma U-Pb zircon ages of the host rhyolites. Dating of apatite and monazite inclusions within apatite provides evidence for at least one younger metasomatic event at ~1.44 Ga, and possibly multiple superimposed metasomatic events between 1.47 and 1.44 Ga. Lead isotop analyses of pyrite show extremely radiogenic 206Pb/204Pb ratios up to ~80 unsupported by in situ U decay. This excess radiogenic Pb in pyrite may have been derived from the spatially associated apatite as apatite recrystallized several tens of million years after its formation. The low initial 206Pb/204Pb ratio of ~16.5 and 207Pb/204Pb ratio of ~15.4 for individual magnetite grains indicate closed U-Pb system behavior in

  7. In situ LA-ICPMS U–Pb dating of cassiterite without a known-age matrix-matched reference material: Examples from worldwide tin deposits spanning the Proterozoic to the Tertiary (United States)

    Neymark, Leonid; Holm-Denoma, Christopher S.; Moscati, Richard J.


    Cassiterite (SnO2), a main ore mineral in tin deposits, is suitable for U–Pb isotopic dating because of its relatively high U/Pb ratios and typically low common Pb. We report a LA-ICPMS analytical procedure for U–Pb dating of this mineral with no need for an independently dated matrix-matched cassiterite standard. LA-ICPMS U-Th-Pb data were acquired while using NIST 612 glass as a primary non-matrix-matched standard. Raw data are reduced using a combination of Iolite™ and other off-line data reduction methods. Cassiterite is extremely difficult to digest, so traditional approaches in LA-ICPMS U-Pb geochronology that utilize well-characterized matrix-matched reference materials (e.g., age values determined by ID-TIMS) cannot be easily implemented. We propose a new approach for in situ LA-ICPMS dating of cassiterite, which benefits from the unique chemistry of cassiterite with extremely low Th concentrations (Th/U ratio of 10−4 or lower) in some cassiterite samples. Accordingly, it is assumed that 208Pb measured in cassiterite is mostly of non-radiogenic origin—it was initially incorporated in cassiterite during mineral formation, and can be used as a proxy for common Pb. Using 208Pb as a common Pb proxy instead of 204Pb is preferred as 204Pb is much less abundant and is also compromised by 204Hg interference during the LA-ICPMS analyses.Our procedure relies on 208Pb/206Pb vs 207Pb/206Pb (Pb-Pb) and Tera-Wasserburg 207Pb/206Pb vs 238U/206Pb (U-Pb) isochron dates that are calculated for a ~1.54 Ga low-Th cassiterite reference material with varying amounts of common Pb that we assume remained a closed U-Pb system. The difference between the NIST 612 glass normalized biased U-Pb date and the Pb-Pb age of the reference material is used to calculate a correction factor (F) for instrumental U-Pb fractionation. The correction factor (F) is then applied to measured U/Pb ratios and Tera-Wasserburg isochron dates are obtained for the unknown

  8. U-Pb Dating of Zircons and Phosphates in Lunar Meteorites, Acapulcoites and Angrites (United States)

    Zhou, Q.; Zeigler, R. A.; Yin, Q. Z.; Korotev, R. L.; Joliff, B. L.; Amelin, Y.; Marti, K.; Wu, F. Y.; Li, X. H.; Li, Q. L.; hide


    Zircon U-Pb geochronology has made a great contribution to the timing of magmatism in the early Solar System [1-3]. Ca phosphates are another group of common accessory minerals in meteorites with great potential for U-Pb geochronology. Compared to zircons, the lower closure temperatures of the U-Pb system for apatite and merrillite (the most common phosphates in achondrites) makes them susceptible to resetting during thermal metamorphism. The different closure temperatures of the U-Pb system for zircon and apatite provide us an opportunity to discover the evolutionary history of meteoritic parent bodies, such as the crystallization ages of magmatism, as well as later impact events and thermal metamorphism. We have developed techniques using the Cameca IMS-1280 ion microprobe to date both zircon and phosphate grains in meteorites. Here we report U-Pb dating results for zircons and phosphates from lunar meteorites Dhofar 1442 and SaU 169. To test and verify the reliability of the newly developed phosphate dating technique, two additional meteorites, Acapulco, obtained from Acapulco consortium, and angrite NWA 4590 were also selected for this study as both have precisely known phosphate U-Pb ages by TIMS [4,5]. Both meteorites are from very fast cooled parent bodies with no sign of resetting [4,5], satisfying a necessity for precise dating.

  9. The White Nile as a source for Nile sediments: Assessment using U-Pb geochronology of detrital rutile and monazite (United States)

    Be'eri-Shlevin, Yaron; Avigad, Dov; Gerdes, Axel


    Basement terranes exposed at the headwaters of the White Nile include Archean-Paleoproterozoic rocks of the Congo Craton, whose northern sectors were severely reworked during Neoproterozoic orogeny. New U-Pb analyses of detrital rutile and monazite from early Quaternary to Recent coastal quartz sands of Israel, at the northeast extension of the Nile sedimentary system, yield mostly late Neoproterozoic ages, with a dominant peak at ca. 600 Ma. While derivation from the reworked sectors of the Craton cannot be negated, the absence of pre-Neoproterozoic rutile and monazite indicates that the detrital contribution from the Congo cratonic nuclei into the main Nile was insignificant. The near absence of White Nile basement-derived heavy minerals from the Nile sands arriving at the Eastern Mediterranean may be explained by a number of factors such as relatively minor erosion of the Cratonic basement nuclei during the Quaternary, late connection of the White Nile to the main Nile system with a possibility that northern segments connected prior to more southerly ones, and a long-term effective sediment blockage mechanism at the mouth of White Nile. Likewise, our previous study demonstrated that Nile sands display a detrital zircon U-Pb-Hf pattern consistent with significant recycling of NE African Paleozoic sediments. It is thus plausible that any detrital contribution from White Nile basement rocks was thoroughly diluted by eroded Paleozoic sediments, or their recycled products, which were likely the greatest sand reservoir in the region. This study adds to previous studies showing the advantage of a multi mineral U-Pb geochronology strategy in constraining sediment provenance patterns.

  10. Work function shifts and variations of ionization probabilities occurring during SIMS analyses using an in situ deposition of Cs 0 (United States)

    Wirtz, T.; Migeon, H.-N.


    To optimize the advantageous quantification technique consisting in analyzing MCs x+ clusters, the Laboratoire d'Analyse des Matériaux (LAM) has developed the Cation Mass Spectrometer (CMS), a new instrument specially dedicated to performing this kind of analysis. To further enhance the potential of this instrument, we have developed a column that delivers a collimated and adjustable stream of neutral Cs atoms to be deposited on the surface of the sample while this one is being analyzed by SIMS. As this configuration permits a successful decoupling of the sputtering and Cs introduction processes by avoiding the constraints imposed by an energetic Cs + ion bombardment, it becomes possible to optimize simultaneously the sensitivity of the analysis, by carefully adjusting the Cs concentration to its optimum value, and the depth resolution of the analysis, by choosing adequate primary bombardment conditions. For the present paper, we have performed in situ measurements of the produced variations of the sample's work function, which are a typical concomitant of alkali metal deposition, by recording successive energy distributions of secondary Cs + ions sputtered from three different samples (Al, Si, Ni). The work function shifts detected by using this method can subsequently be used to explain the variations of the ionization probability of secondary Cs found in a previous study of MCs x+ cluster analysis based upon the described technique. In this respect, we find curves which are typical for what one would expect considering the electron-tunneling model and this theoretical prediction is thus corroborated by our experimental results.

  11. Pre-Variscan evolution of the Western Tatra Mountains: new insights from U-Pb zircon dating. (United States)

    Burda, Jolanta; Klötzli, Urs

    In situ LA-MC-ICP-MS U-Pb zircon geochronology combined with cathodoluminescence imaging were carried out to determine protolith and metamorphic ages of orthogneisses from the Western Tatra Mountains (Central Western Carpathians). The metamorphic complex is subdivided into two units (the Lower Unit and the Upper Unit). Orthogneisses of the Lower Unit are mostly banded, fine- to medium-grained rocks while in the Upper Unit varieties with augen structures predominate. Orthogneisses show a dynamically recrystallised mineral assemblage of Qz + Pl + Bt ± Grt with accessory zircon and apatite. They are peraluminous (ASI = 1.20-1.27) and interpreted to belong to a high-K calc-alkaline suite of a VAG-type tectonic setting. LA-MC-ICP-MS U-Pb zircon data from samples from both units, from crystals with oscillatory zoning and Th/U > 0.1, yield similar concordia ages of ca. 534 Ma. This is interpreted to reflect the magmatic crystallization age of igneous precursors. These oldest meta-magmatics so far dated in the Western Tatra Mountains could be linked to the fragmentation of the northern margin of Gondwana. In zircons from a gneiss from the Upper Unit, cores with well-developed oscillatory zoning are surrounded by weakly luminescent, low contrast rims (Th/U < 0.1). These yield a concordia age of ca. 387 Ma corresponding to a subsequent, Eo-Variscan, high-grade metamorphic event, connected with the formation of crustal-scale nappe structures and collision-related magmatism.

  12. New zircon U-Pb LA-ICP-MS ages and Hf isotope data from the Central Pontides (Turkey): Geological and geodynamic constraints (United States)

    Çimen, Okay; Göncüoğlu, M. Cemal; Simonetti, Antonio; Sayit, Kaan


    The Central Pontides in northern Anatolia is located on the accretionary complex formed by the closure of Neotethyan Intra-Pontide Ocean between the southern Eurasian margin (Istanbul-Zonguldak Terrane) and the Cimmerian Sakarya Composite Terrane. Among other components of the oceanic lithosphere, it comprises not yet well-dated felsic igneous rocks formed in arc-basin as well as continent margin settings. In-situ U-Pb age results for zircons from the arc-basin system (öangaldağ Metamorphic Complex) and the continental arc (Devrekani Metadiorite and Granitoid) yield ages of 176 ± 6 Ma, 163 ± 9 Ma and 165 ± 3 Ma, respectively. Corresponding in-situ average (initial) 176Hf/177Hf initial ratios are 0.28261 ± 0.00003, 0.28267 ± 0.00002 and 0.28290 ± 0.00004 for these units and indicative of a subduction-modified mantle source. The new U-Pb ages and Hf isotope data from these oceanic and continental arc units together with regional geological constraints support the presence of a multiple subduction system within the Intra-Pontide Ocean during the Middle Jurassic.

  13. U-Pb rutile thermochronology: a review and status report on a vexing conundrum (Invited) (United States)

    Schmitz, M. D.; Dye, J. H.


    Among the available intermediate-temperature thermochronometers utilizing U-Pb isotopic measurements of accessory minerals, rutile stands out as among the least apparently understood in terms of diffusion kinetics and daughter-loss mechanisms. Discrepancies persist between a variety of empirical and experimental estimates of apparent closure temperature for the U-Pb rutile thermochronometer, ranging from as low as 400°C to greater than 600°C. This range in the temperature component of the thermochronometer is particularly vexing given the otherwise attractive chronologic and petrologic characteristics of rutile, and a new Zr-in-rutile thermometric calibration (Watson et al., 2006, Crystallization thermometers for zircon and rutile, Contrib. Mineral. Petrol. 151:413-433) that could complement U-Pb-based thermochronology. The crux of the U-Pb rutile conundrum lies in apparent discrepancy between nominal closure temperatures inferred on the basis of: a) empirical multiple mineral-isotope relative thermochronology for metamorphic terrains, versus b) the available experimental determination of Pb volume diffusion parameters in rutile (Cherniak et al., 2000, Pb diffusion in rutile, Contrib. Mineral. Petrol. 139:198-207). This contribution will review the state-of-the-art in U-Pb analytical measurements of rutile, and the constraints provided by empirical studies of the relative closure properties of rutile and a variety of other mineral-isotope thermochronometers. A thermochronological case study combining Rb-Sr mica and U-Pb zircon, monazite, titanite and rutile ages and trace element thermometry from Cretaceous-Paleogene amphibolite-facies gneisses of the northern U.S. Cordillera will highlight the problems and potential of this valuable thermochronometer.

  14. Timing of the Permian-Triassic biotic crisis: implications from new zircon U/Pb age data (and their limitations) (United States)

    Mundil, Roland; Metcalfe, Ian; Ludwig, Kenneth R.; Renne, Paul R.; Oberli, Felix; Nicoll, Robert S.


    The most profound biotic crisis in the Earth's history, causing the near extinction of both terrestrial and marine life, occurred at the end of the Permian period about 253 Myr ago and marks the Paleozoic-Mesozoic era boundary. The cause of this event is still a matter of vigorous debate, with both brief and catastrophic as well as gradual mechanisms having been proposed. Similar to a recent landmark study, this study uses the U-Pb method on zircons from the uppermost Permian/lowermost Triassic ash fall deposits at Meishan (Zhejiang Province, SE China) in order to examine time and rate constraints for these events. The results of both this study and previous work show that for these ash layers, the effects of Pb loss are combined with varying amounts and sources of inheritance, resulting in an age scatter which prohibits the extraction of a statistically robust age in many cases. Though the effects of Pb loss on the zircons analyzed in this study were reduced by leaching the grains in hydrofluoric acid (as opposed to commonly applied air abrasion) prior to analysis, the presence within a single ash layer of multiple generations of older xenocrysts (in many cases only slightly older than the depositional age) has made quantitative interpretation even more difficult. When these combined phenomena bias individual zircon ages by less than a percent, they are extremely difficult to deconvolute, and, if multi-grain analyses are used, can become impossible to recognize (because of the resulting age averaging). Monte Carlo simulations using actual measurements of individual zircon crystals show that age excursions due to Pb loss and xenocrystic contamination for the Meishan bentonites are easily homogenized to the point of undetectability when replicate analyses of multi-grain zircon samples are compared. Thus this study uses only high-precision analyses of single crystals, whether from our work or that of previous studies. Three main conclusions have emerged. First, our


    African Journals Online (AJOL)


    Out of 131 analyses 117 yielded useful geochronological data. 67 of these gave 90-110% ... These first-ever geochronological data from rocks of Akwanga area are further evidence of the polycyclic nature of the Nigerian basement. ... composed of feldspar and quartz whilst the dark band shows parallel alignment of biotite.

  16. A study of U-Pb isotopic evolutionary system in Chanziping uranium deposit

    International Nuclear Information System (INIS)

    Xu Weichang; Huang Shijie; Xia Yuliang.


    Chanziping uranium deposit occurred in the black siliceous slate of Lower cambrian. The uranium mineralization was controlled by both interstratified fault belt and the ore-bearing beds. Based on the study of the U-Pb isotopic system of the various rocks, ores and minerals in the ore-bearing beds, the authors find out the obvious disequilibrium of U-Pb isotopic composition in most rock samples which indicates the loss of uranium form the ore-bearing beds and surrounding granite. Its counting loss ranges from 30 to 80%. The age of rich ores of the U-Pb concordance diagram and the U-Pb three stage model are t 1 = 523 ± 19M. Y. , t 2 = 22 ± 2 M.Y.. The isochronal ages for pitchblend are 75 ± 4 M.Y., 43 ± 7 M.Y., and for rock is 416 M.y.. These data shows that the uranium in ore-bearing beds was mainly derived from the ore-bearing beds itself and partly from the surrounding granite. The ore deposit can be considered to be of stratabound uranium deposit of sedimentation and late transformation type

  17. Constraints on a Late Cretaceous uplift, denudation, and incision of the Grand Canyon region, southwestern Colorado Plateau, USA, from U-Pb dating of lacustrine limestone (United States)

    Hill, Carol A.; Polyak, Victor J.; Asmerom, Yemane; P. Provencio, Paula


    The uplift and denudation of the Colorado Plateau is important in reconstructing the geomorphic and tectonic evolution of western North America. A Late Cretaceous (64 ± 2 Ma) U-Pb age for the Long Point limestone on the Coconino Plateau, which overlies a regional erosional surface developed on Permo-Triassic formations, supports unroofing of the Coconino Plateau part of Grand Canyon by that time. U-Pb analyses of three separate outcrops of this limestone gave ages of 64.0 ± 0.7, 60.5 ± 4.6, and 66.3 ± 3.9 Ma, which dates are older than a fossil-based, early Eocene age. Samples of the Long Point limestone were dated using the isotope dilution isochron method on well-preserved carbonates having high-uranium and low-lead concentrations. Our U-Pb ages on the Long Point limestone place important constraints on the (1) time of tectonic uplift of the southwestern Colorado Plateau and Kaibab arch, (2) time of denudation of the Coconino Plateau, and (3) Late Cretaceous models of paleocanyon incision west of, or across, the Kaibab arch. We propose that the age of the Long Point limestone, interbedded within the Music Mountain Formation in the Long Point area, represents a period of regional aggradation and a time of drainage blockage northward and eastward across the Kaibab arch, with possible diversion of northward drainage on the Coconino Plateau westward around the arch via a Laramide paleo-Grand Canyon.

  18. Morphology versus U-Pb systematics in zircon: A high-resolution isotopic study of a zircon population from a Variscan dike in the Central Alps

    International Nuclear Information System (INIS)

    Bossart, P.J.; Meier, M.; Oberli, F.; Steiger, R.H.


    U/Pb isotopic measurements on individual zircon crystals combined with morphological analyses permit the identification of three distinct components within the zircon population of the Saedelhorn diorite, a Variscan dike from the western Gotthard (Central Alps, Switzerland): (i) 94% of the grains in the zircon population are elongate crystals with pronounced skeletal morphology indicative of rapid growth from a supercooled melt. (ii) 5% of the population consist of turbid, mostly subhedral zircons frequently showing D-type morphology and elevated uranium contents compared to the skeletal variety. Single-crystal and multi-grain U-Pb isotopic data of group (i) and (ii) zircons define an intrusion age of 293 + 5/ -4 m.y. for the dike. (iii) Rare, transparent zircon crystals (< 1% of the zircons population) yield apparent U-Pb ages in the range of 370-490 m.y. and display morphological and isotopic characteristics closely resembling those of a Caledonian orthogneiss intruded by the dike. This implies presence of assimilated wall-rock components in the macroscopically homogeneous dike sample. (orig./WB)

  19. Precise U-Pb Zircon Constraints on the Earliest Magmatic History of the Carolina Terrane. (United States)

    Wortman; Samson; Hibbard


    The early magmatic and tectonic history of the Carolina terrane and its possible affinities with other Neoproterozoic circum-Atlantic arc terranes have been poorly understood, in large part because of a lack of reliable geochronological data. Precise U-Pb zircon dates for the Virgilina sequence, the oldest exposed part, constrain the timing of the earliest known stage of magmatism in the terrane and of the Virgilina orogeny. A flow-banded rhyolite sampled from a metavolcanic sequence near Chapel Hill, North Carolina, yielded a U-Pb zircon date of 632.9 +2.6/-1.9 Ma. A granitic unit of the Chapel Hill pluton, which intrudes the metavolcanic sequence, yielded a nearly identical U-Pb zircon date of 633 +2/-1.5 Ma, interpreted as its crystallization age. A felsic gneiss and a dacitic tuff from the Hyco Formation yielded U-Pb zircon dates of 619.9 +4.5/-3 Ma and 615.7 +3.7/-1.9 Ma, respectively. Diorite and granite of the Flat River complex have indistinguishable U-Pb upper-intercept dates of 613.9 +1.6/-1.5 Ma and 613.4 +2.8/-2 Ma. The Osmond biotite-granite gneiss, which intruded the Hyco Formation before the Virgilina orogeny, crystallized at 612.4 +5.2/-1.7 Ma. Granite of the Roxboro pluton, an intrusion that postdated the Virgilina orogeny, yielded a U-Pb upper intercept date of 546.5 +3.0/-2.4 Ma, interpreted as the time of its crystallization. These new dates both provide the first reliable estimates of the age of the Virgilina sequence and document that the earliest known stage of magmatism in the Carolina terrane had begun by 633 +2/-1.5 Ma and continued at least until 612.4 +5.2/-1.7 Ma, an interval of approximately 25 m.yr. Timing of the Virgilina orogeny is bracketed between 612.4 +5.2/-1.7 Ma and 586+/-10 Ma (reported age of the upper Uwharrie Formation). The U-Pb systematics of all units studied in the Virgilina sequence are simple and lack any evidence of an older xenocrystic zircon component, which would indicate the presence of a continental

  20. Cenozoic foreland basins of Central Andes: a preliminary provenance U-Pb zircon analysis of sedimentary sequences of Calchaqui Valley

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Alisson Lopes; Hauser, Natalia; Pimentel, Marcio Martins; Matteini, Massimo, E-mail: [Universidade de Brasilia (UnB), DF (Brazil). Laboratorio de Geocronologia; Galli, Claudia Ines [Faculdad de Ingenieria, Universidad Nacional de Jujuy (Argentina); Coira, Beatriz [CIT Jujuy, CONICET. Instituto de Geologia y Mineria (Argentina); Alonso, Ricardo; Barrientos, Andrea [Instituto CEGA, CONICET. Universidad Nacional de Salta (Argentina)


    The Eocene of northwestern Argentina records complex basin and structural evolution, including continental sedimentation of the post-rift Salta Basin and the beginning of the Andean uplift and foreland system evolution. This illuminates a significant period of evolutionary history of this and surrounding basins in northwestern Argentina. U-Pb zircon analyses by LA-ICP-MS for three formations representing post-rift to foreland stages allowed interpretation about provenance terrains. The Lumbrera Formation, representing the post-rift stage, shows bimodal sources with a main zircon population around 462 Ma, and a second population around 1023 Ma. The Los Colorados and Angastaco Formations representing the sedimentation in a foreland basin, show a unimodal source around 490 Ma, and 517 Ma respectively. Zircons younger than 50 Ma were not identified during this study. (author)

  1. Cenozoic foreland basins of Central Andes: a preliminary provenance U-Pb zircon analysis of sedimentary sequences of Calchaqui Valley

    International Nuclear Information System (INIS)

    Oliveira, Alisson Lopes; Hauser, Natalia; Pimentel, Marcio Martins; Matteini, Massimo; Coira, Beatriz; Alonso, Ricardo; Barrientos, Andrea


    The Eocene of northwestern Argentina records complex basin and structural evolution, including continental sedimentation of the post-rift Salta Basin and the beginning of the Andean uplift and foreland system evolution. This illuminates a significant period of evolutionary history of this and surrounding basins in northwestern Argentina. U-Pb zircon analyses by LA-ICP-MS for three formations representing post-rift to foreland stages allowed interpretation about provenance terrains. The Lumbrera Formation, representing the post-rift stage, shows bimodal sources with a main zircon population around 462 Ma, and a second population around 1023 Ma. The Los Colorados and Angastaco Formations representing the sedimentation in a foreland basin, show a unimodal source around 490 Ma, and 517 Ma respectively. Zircons younger than 50 Ma were not identified during this study. (author)

  2. U-Pb isotopic systematics of zircons from prograde and retrograde transition zones in high-grade orthogneisses, Sri Lanka

    Energy Technology Data Exchange (ETDEWEB)

    Baur, N.; Liew, T.C.; Todt, W.; Hofmann, A.W. (Max-Planck-Institut fuer Chemie, Mainz (West Germany)); Kroener, A. (Univ. Mainz (West Germany)); Williams, I.S. (Australian National Univ., Canberra (Australia))


    The authors present U-Pb zircon isotopic data from locally restricted prograde (arrested in situ charnockitization) and retrograde metamorphic transition zones, which are well exposed in Proterozoic orthogneisses tectonically interbanded with granulite facies supracrustal rocks of the Highland Group in Sri Lanka. These granitoid rocks yield apparent ages of 1942 {plus minus} 22 Ma, {approximately} 770 Ma, {approximately} 660 Ma, and {approximately} 560 Ma. All samples show severe Pb-loss some 550-560 Ma ago. The main phase of granulite-formation could not be dated unambiguously but is bracketed between {approximately} 660 Ma and {approximately} 550 Ma. The pervasive Pb-loss event around 550-560 Ma reflects the end of this period of high-grade metamorphism and was associated with widespread igneous activity and retrogression. This is constrained by the 550 {plus minus} 3 Ma intrusion age for a post-tectonic granite. They relate this late phase of thermal activity to crustal uplift of the Sri Lankan granulites. This data unambiguously prove the high-grade history of the Sri Lanka gneisses to be a late Precambrian event that may be related to the Pan-African evolution along the eastern part of Africa.

  3. Allogenic and Autogenic Signals in the Detrital Zircon U-Pb Record of the Deep-Sea Bengal Fan (United States)

    Blum, M. D.; Rogers, K. G.; Gleason, J. D.; Najman, Y.


    The Himalayan-sourced Ganges-Brahmaputra river system and the deep-sea Bengal Fan represent Earth's largest sediment-dispersal system. This presentation summarizes a new detrital zircon U-Pb (DZ) provenance record from the Bengal Fan from cores collected during IODP Expedition 354, with coring sites located 1350 km downdip from the shelf margin. Each of our 15 samples were collected from medium- to fine-grained turbidite sand and, based on shipboard biostratigraphic analyses, our samples are late Miocene to late Pleistocene in age. Each sample was analyzed by LA-ICPMS at the Arizona Laserchron facility, with an average of n=270 concordant U-Pb ages per sample. Our goals are to use these data to evaluate the influence of allogenic controls vs. autogenic processes on signal propagation from source-to-sink. At the first order, large-scale sediment transfer to the Bengal Fan clearly records the strong tectonic and climatic forcing associated with the Himalayas and Ganges-Brahmaputra system: after up to 2500 km of river transport, and 1350 km of transport in turbidity currents, the DZ record faithfully represents Himalayan source terrains. The sand-rich turbidite part of the record is nevertheless biased towards glacial periods when rivers extended across the shelf in response to climate-forced sea-level fall, and discharged directly to slope canyons. However, only part of the Bengal Fan DZ record represents either the Ganges or the Brahmaputra, with most samples representing varying degrees of mixing of sediments from the two systems: this mixing, or the lack thereof, represents the signal of autogenic avulsions on the delta plain that result in the two river systems delivering sediment separately to the shelf margin, or together as they do today. Within the allogenic framework established by tectonic processes, the climatic system, and global climate-forced sea-level change, the DZ U-Pb record of sediment mixing or the lack thereof provides a fingerprint of autogenic

  4. Enhanced provenance interpretation using combined U-Pb and (U-Th)/He double dating of detrital zircon grains from lower Miocene strata, proximal Gulf of Mexico Basin, North America (United States)

    Xu, Jie; Stockli, Daniel F.; Snedden, John W.


    Detrital zircon U-Pb analysis is an effective approach for investigating sediment provenance by relating crystallization age to potential crystalline source terranes. Studies of large passive margin basins, such as the Gulf of Mexico Basin, that have received sediment from multiple terranes with non-unique crystallization ages or sedimentary strata, benefit from additional constraints to better elucidate provenance interpretation. In this study, U-Pb and (U-Th)/He double dating analyses on single zircons from the lower Miocene sandstones in the northern Gulf of Mexico Basin reveal a detailed history of sediment source evolution. U-Pb age data indicate that most zircon originated from five major crystalline provinces, including the Western Cordillera Arc (Pan-African (700-500 Ma) and Canadian Shield (>1800 Ma) terranes. Zircon (U-Th)/He ages record tectonic cooling and exhumation in the U.S. since the Mesoproterozoic related to the Grenville to Laramide Orogenies. The combined crystallization and cooling information from single zircon double dating can differentiate volcanic and plutonic zircons. Importantly, the U-Pb-He double dating approach allows for the differentiation between multiple possible crystallization-age sources on the basis of their subsequent tectonic evolution. In particular, for Grenville zircons that are present in all of lower Miocene samples, four distinct zircon U-Pb-He age combinations are recognizable that can be traced back to four different possible sources. The integrated U-Pb and (U-Th)/He data eliminate some ambiguities and improves the provenance interpretation for the lower Miocene strata in the northern Gulf of Mexico Basin and illustrate the applicability of this approach for other large-scale basins to reconstruct sediment provenance and dispersal patterns.

  5. Relict zircon U-Pb age and O isotope evidence for reworking of Neoproterozoic crustal rocks in the origin of Triassic S-type granites in South China (United States)

    Gao, Peng; Zheng, Yong-Fei; Chen, Yi-Xiang; Zhao, Zi-Fu; Xia, Xiao-Ping


    Granites derived from partial melting of sedimentary rocks are generally characterized by high δ18O values and abundant relict zircons. Such relict zircons are valuable in tracing the source rocks of granites and the history of crustal anatexis. Here we report in-situ U-Pb ages, O isotopes and trace elements in zircons from Triassic granites in the Zhuguangshan and Jiuzhou regions, which are located in the Nanling Range and the Darongshan area, respectively, in South China. Zircon U-Pb dating yields magma crystallization ages of 236 ± 2 Ma for the Zhuguangshan granites and 246 ± 2 Ma to 252 ± 3 Ma for the Jiuzhou granites. The Triassic syn-magmatic zircons are characterized by high δ18O values of 10.1-11.9‰ in Zhuguangshan and 8.5-13.5‰ in Jiuzhou. The relict zircons show a wide range of U-Pb ages from 315 to 2185 Ma in Zhuguangshan and from 304 to 3121 Ma in Jiuzhou. Nevertheless, a dominant age peak of 700-1000 Ma is prominent in both occurrences, demonstrating that their source rocks were dominated by detrital sediments weathered from Neoproterozoic magmatic rocks. Taking previous results for regional granites together, Neoproterozoic relict zircons show δ18O values in a small range from 5 to 8‰ for the Nanling granites but a large range from 5 to 11‰ for the Darongshan granites. In addition, relict zircons of Paleozoic U-Pb age occur in the two granitic plutons. They exhibit consistently high δ18O values similar to the Triassic syn-magmatic zircons in the host granites. These Paleozoic relict zircons are interpreted as the peritectic product during transient melting of the metasedimentary rocks in response to the intracontinental orogenesis in South China. Therefore, the relict zircons of Neoproterozoic age are directly inherited from the source rocks of S-type granites, and those of Paleozoic age record the transient melting of metasedimentary rocks before intensive melting for granitic magmatism in the Triassic.

  6. Pb-Pb and U-Pb zircon ages of archean syntetocnic granites of the Carajas metallogenic province, northern Brazil

    International Nuclear Information System (INIS)

    Barros, Carlos Eduardo de Mesquita; Sardinha, Alex Souza; Barbosa, Jaime dos Passos de Oliveira; Krimski, Robert; Macambira, Moacir Jose Buenano


    The Carajas Metallogenic Province is located in the southeastern Amazonian Craton. It has been divided in two domains, the southernmost comprises the Rio Maria region and the northernmost corresponds to Caraj region (Souza et al. 1996). The former domain is made up of Archean greenstone sequences (2,97 Ga), TTG (2,9 Ga) and calc-alkaline granitoids (2,87 Ga) (Macambira and Lafon 1995, Leite et al. 1999, Althoff et al. 2000). The Carajas block is constituted of minor mafic granulites (3,00 Ga) and quartzofeldspathic gneisses (2,81 Ga), metavolcanosedimentary sequences (2,76 Ga) and granites (2,76 to 2,56 Ga) (Machado et al. 1991; Huhn et al. 1999, Pidgeon et al. 2000). Widespread anorogenic A-type granites are found in both areas (Docegeo 1988; Dall'Agnol et al. 1994). In the last two decades several authors (Lindenamyer et al. 1994, Barros and Barbey 1998, Huhn et al. 1999 and others) have emphasized the role of the Archean granite magmatism in the tectonicthermal evolution in the Carajas Province. In this paper we discuss the tectonic significance of the Pb- Pb and U-Pb ages obtained in some granitoids from the Carajas region. The Estrela Granite Complex and the granitoids located to the north of Parauapebas were dated by Pb- Pb evaporation zircon method (cf. Kober 1987). Data are presented considering 2σ ∼ . The Pb corrections have been done in the basis of the evolution model of Pb in double stage (cf. Stacey and Kramers 1975). U-Pb zircon method (cf. Krogh 1973, Stacey and Kramers 1975, Parrish 1987, Ludwuig 1999), recently put on routine in the Para-Iso laboratories, was employed to date the granite from the Serra do Rabo area. Analyses were carried on the Finnigan Mat 262 spectrometer (au)

  7. Chemostratigraphic and U-Pb geochronologic constraints on carbon cycling across the Silurian-Devonian boundary (United States)

    Husson, Jon M.; Schoene, Blair; Bluher, Sarah; Maloof, Adam C.


    The Devonian Period hosts extraordinary changes to Earth's biosphere. Land plants began their rise to prominence, with early vascular vegetation beginning its colonization of near-shore environments in the latest Silurian. Across the Silurian-Devonian (Pridoli-Lochkovian) transition, carbon isotope analyses of bulk marine carbonates (δC13carb) from Laurentian and Baltic successions reveal a positive δC13carb shift. Known as the Klonk Event, values reach + 5.8 ‰, making it one of the largest carbon isotope excursions in the Phanerozoic. Assigning rates and durations to these significant events requires a robust, precise Devonian time scale. Here we present 675 micritic matrix and 357 fossil-specific δC13carb analyses from the lower Devonian Helderberg Group of New York and West Virginia that exhibit the very positive δC13carb values observed in other Silurian-Devonian basins. This chemostratigraphic dataset is coupled with 66 ID-TIMS U-Pb dates on single zircons from six ash falls intercalated within Helderberg sediments, including dates on the stratigraphically lowest Devonian ashes yet developed. In this work, we (a) demonstrate that matrix and fossil-specific δC13carb values track one another closely in the Helderberg Group, (b) estimate the Silurian-Devonian boundary age in New York to be 421.3 ± 1.2 Ma (2σ; including decay constant uncertainties), and (c) calculate the time required to evolve from baseline to peak δC13carb values at the onset of the Klonk event to be 1.00 ± 0.25 Myr. Under these constraints, a steady-state perturbation to the global carbon cycle can explain the observed excursion with modern fluxes, as long as DIC concentration in the Devonian ocean remained below ∼2× the modern value. Therefore, potential drivers, such as enhanced burial of organic carbon, need not rely on anomalously high total fluxes of carbon to explain the Klonk Event.

  8. Isotopic geochemistry, zircon U-Pb ages and Hf isotopes of A-type granites from the Xitian W-Sn deposit, SE China: Constraints on petrogenesis and tectonic significance (United States)

    Zhou, Yun; Liang, Xinquan; Wu, Shichong; Cai, Yongfeng; Liang, Xirong; Shao, Tongbin; Wang, Ce; Fu, Jiangang; Jiang, Ying


    Zircon U-Pb geochronological, geochemical and petrological analyses have been carried out on the Xitian granite emplaced in the middle part of Shi-Hang zone, which is closely related to the economically important Xitian tungsten-tin deposit in Hunan Province, Southeast China. LA-ICP-MS zircon U-Pb dating of two representative samples yielded weighted means 206Pb/238U age of 151.7 ± 1.2 Ma and 151.8 ± 1.4 Ma. These granites are comprised mainly of K-feldspar, quartz, plagioclase, Fe-rich biotite and minor fluorite, and are characterized by enrichments in Rb, Th, REEs (total REE = 159-351 ppm), and HFSEs (e.g., Zr and Y) but depletions in Ba, Sr, P, Eu and Ti. They are metaluminous to weakly peraluminous and show a clear A-type granite geochemical signature with high SiO2 (73.44-78.45 wt.%), total alkalis (Na2O + K2O = 2.89-8.98 wt.%), Fe2O3∗/MgO ratios and low P2O5, CaO, MgO and TiO2 contents. In-situ zircon Hf isotope analysis suggests their εHf(t) values ranging from -7.43 to -14.69. Sr-Nd isotope data show their εNd(t) values in the range of -9.2 to -7.3, with corresponding TDM2 ages of 1.72-1.56 Ga. These characteristics indicate that the Xitian granite originated from partial melting of metamorphic basement rocks with a certain amount of mantle-derived materials. Combined with previous geochemical and isotopic data, it is derived that mantle-crust interaction was gradually enhanced from the early to late stages of magmatism. The ore-forming materials and fluids of the Xitian W-Sn deposit are mainly produced by the Early Yanshanian granitic magmatism, which is also responsible for the Late Jurassic (ca. 152 Ma) A-type granitic rocks that host the W-Sn polymetallic deposits distributed along the Shi-Hang zone, implying a significant Mesozoic extensional event in Southeast China likely caused by the subduction of the Paleo-Pacific plate.

  9. Precise U-Pb Zircon Dating of the Syenite Phase from the Ditrau Alkaline Igneous Complex

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    Pană Dinu


    Full Text Available The Ditrău igneous complex represents the largest alkaline intrusion in the Carpathian-Pannonian region consisting of a plethora of rock types formed by complicated magmatic and metasomatic processes. A detailed U-Pb zircon age study is currently underway and the results for the syenite intrusion phase is reported herein. The U-Pb zircon emplacement age of the syenite of 229.6 +1.7/-1.2 Ma documents the quasi-contemporaneous production and emplacement of the gabbro and syenite magmas. We suggest that the syenite and associated granite formed by crustal melting during the emplacement of the mantle derived gabbroic magma around 230 Ma. The thermal contact aureole produced by the Ditrău alkaline igneous complex constrains the main tectonism recorded by surrounding metamorphic lithotectonic assemblages to be pre-Ladinian.

  10. Critical evaluation and thermodynamic optimization of the U-Pb and U-Sb binary systems

    International Nuclear Information System (INIS)

    Wang, Jian; Jin, Liling; Chen, Chuchu; Rao, Weifeng; Wang, Cuiping; Liu, Xingjun


    A complete literature review, critical evaluation and thermodynamic optimization of the phase diagrams and thermodynamic properties of U-Pb and U-Sb binary systems are presented. The CALculation of PHAse Diagrams (CALPHAD) method was used for the thermodynamic optimization, the results of which can reproduce all available reliable experimental phase equilibria and thermodynamic data. The modified quasi-chemical model in the pair approximation (MQMPA) was used for modeling the liquid solution. The Gibbs energies of all terminal solid solutions and intermetallic compounds were described by the compound energy formalism (CEF) model. All reliable experimental data of the U-Pb and U-Sb systems have been reproduced. A self-consistent thermodynamic database has been constructed for these binary systems; this database can be used in liquid-metal fuel reactor (LMFR) research.

  11. NanoSIMS U-Pb dating of hydrothermally altered monazite: Constraints on the Timing of LaoZaiWan Carlin-type gold deposit in the golden triangle region, SW China (United States)

    PI, Q.


    Abstract: Direct dating of Carlin-type Au deposits was restricted due to the absence of a geochronometer. Back-scattered electron (BSE) imaging and X-ray element mapping of monazite in gold-rich ore samples from the LaoZaiWan Au deposit in SW China, reveal the presence of distinct, high-Th cores surrounded by low-Th, inclusion-rich rims. The monazite grain is considered to be the product of fluid-aided coupled dissolution-reprecipitation during Au mineralization via prograde metamorphic reactions. We present results of in situ NonSIMS U-Pb dating applied to the rims of monazite . NonSIMS U-Pb age of hydrothermal monazite gave ages of 228 ± 9 Ma(2σ) and 230 ± 16 Ma(2σ) for LaoZaiWan Au deposit. These ages are interpreted as Au mineralization ages, which consistent with the Re-Os age of arsenopyite for JinYa Au deposit, the U-Pb age of rutile for and 40Ar-39Ar age of sericite for Zhesang Au deposit. We postulate that the formation of the Carlin-type Au deposits in the Golden Triangle region was triggered by the Indosinian Orogen, related to collision of the Indochina Block with South China Block.

  12. IRE (Institut National des Radioelements) site in Belgium. Report of in situ measurements and analyses performed for the RTBF

    International Nuclear Information System (INIS)


    This document reports various analyses performed within the frame of the preparation and filming of a TV documentary on the Belgium National Institute of Radio-elements. It reports gamma radiation measurements performed at the vicinity of the institute, discusses the possible origin of its increase at the vicinity of the institute, analyses of sludge samples coming from a wastewater treatment works, and analyses of milk, cabbage, mosses and sediments collected by residents

  13. In situ assembly states of (Na+,K+)-pump ATPase in human erythrocytes. Radiation target size analyses

    International Nuclear Information System (INIS)

    Hah, J.; Goldinger, J.M.; Jung, C.Y.


    The in situ assembly state of the (Na+,K+)-pump ATPase of human erythrocytes was studied by applying the classical target theory to radiation inactivation data of the ouabain-sensitive sodium efflux and ATP hydrolysis. Erythrocytes and their extensively washed white ghosts were irradiated at -45 to -50 degrees C with an increasing dose of 1.5-MeV electron beam, and after thawing, the Na+-pump flux and/or enzyme activities were assayed. Each activity measured was reduced as a simple exponential function of radiation dose, from which a radiation sensitive mass (target size) was calculated. When intact cells were used, the target sizes for the pump and for the ATPase activities were equal and approximately 620,000 daltons. The target size for the ATPase activity was reduced to approximately 320,000 daltons if the cells were pretreated with digitoxigenin. When ghosts were used, the target size for the ATPase activity was again approximately 320,000 daltons. Our target size measurements together with other information available in literature suggest that (Na+,K+)-pump ATPase may exist in human erythrocytes either as a tetramer of alpha beta or as a dimer of alpha beta in tight association with other protein mass, probably certain glycolytic enzymes, and that this tetrameric or heterocomplex association is dissociable by digitoxigenin treatment or by extensive wash during ghost preparation

  14. A comparison of zircon U-Pb age results of the Red Clay sequence on the central Chinese Loess Plateau. (United States)

    Gong, Hujun; Nie, Junsheng; Wang, Zhao; Peng, Wenbin; Zhang, Rui; Zhang, Yunxiang


    Single grain zircon U-Pb geochronology has demonstrated great potentials in extracting tectonic and atmospheric circulation signal carried by aeolian, fluvial, and fluviolacustrine sediments. A routine in this sort of studies is analyzing 100-150 grains and then compares zircon U-Pb age spectra between the measured sample and the potential sources. Here we compared the zircon U-Pb age results of the late Miocene-Pliocene Red Clay sequence of two neighboring sites from the Chinese Loess Plateau where similar provenance signal is expected. Although the results from the 5.5 Ma sediment support this prediction, the results from the 3 Ma sediment at these two sites differ from each other significantly. These results emphasize the importance of increasing analysis number per sample and combining the zircon U-Pb geochronology with other provenance tools in order to get reliable provenance information.

  15. U-Pb zircon age data for selected sedimentary, metasedimentary, and igneous rocks from northern and central Alaska (United States)

    Moore, Thomas E.


    This publication contains the complete results of U-Pb zircon age dating studies of sedimentary and metasedimentary units from northern and central Alaska that are discussed and interpreted in other reports by the author. Most of the U-Pb ages are of detrital zircons from sandstones, although U-Pb ages from igneous and sedimentary clasts from conglomerates in some of those same units are also included. In addition to the data presented in the interpretive reports, this publication includes data that were excluded due to discordance, analytical problems, and publication space limitations. The U-Pb age data are reported in Excel-file format so that they can be easily downloaded and referenced or reinterpreted by future workers.

  16. The U-Pb System in Schorlomite from Calcite-Amphobole-Pyroxene Pegmatite of the Afrikanda Complex (Kola Peninsula) (United States)

    Salnikova, E. B.; Stifeeva, M. V.; Chakhmouradian, A. R.; Glebovitsky, V. A.; Reguir, E. P.


    The geochronological U-Pb study of shorlomite from igneous rocks of the alkali-ultramafic Afrikanda massif (Kola Peninsula) was performed. The results demonstrate the reliability of calcium garnet as a mineral for the U-Pb geochronology of a wide range of igneous rocks, i.e., carbonatite, syenite, foidolite, foidite, melilitolite, melilitite, lamprophyres, micaceous kimberlites, etc., and associated rare earth and trace elements (REE, Nb, Zr) mineralization.

  17. Whole-rock U-Pb dating of the Shuijingtuo formation sedimentary rocks in the Yangtze Gorge

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Y.F. (Goettingen Univ. (Germany, F.R.). Geochemisches Inst.); Zhou, H.F. (Tianjing Inst. of Geology and Mineral Resources, TJ (China)); Huang, B. (Guilin Inst. of Mineral Resources and Geology, GX (China))


    Black shale and enclosed limestone lenticule from Lower Cambrian Shuijingtuo Formation in the Yangtze Gorge is successfully dated by whole-rock U-Pb method. The results yield a concordant age of about 573+-14 Ma, in excellent agreement with both stratigraphic and palaeontologic evidence. The whole-rock U-Pb method can provide a reliable approach for age determination of sedimentary stratum. (orig.).

  18. Crystal Cargo Characterization: Unravelling Granite Petrogenesis through Combined MicroXRF Imaging and In-situ Analyses. (United States)

    McLeod, C. L.; Brown, K.; Brydon, R.; Haley, M.; Hill, T.; Shaulis, B.; Tronnes, R. G.


    Advances in the capabilities of microanalysis over the past several decades have promoted a redefinition of traditional petrological terminology. This has allowed a more accurate evaluation of a samples petrogenetic history. For example, the term "phenocryst", specifically describes crystals that grew from the liquid that solidified into the groundmass. Evolving from this idea is the term xenocryst, referring to crystals that did not originate in the magma but were gathered by it, and antecrysts, which crystallized from a progenitor of the magma that solidified into the groundmass. Through identification of a magmas different, and distinct, crystal populations, the petrogenetic history of a magmatic rock can therefore be unraveled. This approach has been widely applied to terrestrial volcanic systems throughout the past several decades. This study presents results from a combined microimaging and in-situ microanalytical investigation of granitic magmas crystal cargoes in order to unravel how granitic batholiths are constructed. 27 lithological units from two granite batholiths in the Oslo Rift, Norway form the basis of this investigation. Micro X-Ray Fluorescence (µXRF) mapping of major elements and selected trace elements is used in order to chemically map each granitic unit, identify any characteristic growth zoning, and compare the crystal cargoes of the different units. Major and trace elemental abundances of the major phases (feldspars, biotite, amphibole) and minor phases (apatite and titanite) are to be quantified through electron microprobe analysis (EPMA) and laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) respectively. Through chemically fingerprinting the crystal cargoes of these Oslo Rift granitic magmas, the open vs. closed nature of granitic, intrusive, magmatic systems will be investigated. Within the context of the Oslo Rift, this study also offers an opportunity to evaluate the processes inherent to granitoid magmatism

  19. The Mars Organic Molecule Analyser : in situ analysis of organic compounds on Mars by Gas Chromatography-Mass Spectrometry. (United States)

    Buch, Arnaud; Sternberg, Robert; Freissinet, Caroline; Pinnick, Veronika; Szopa, Cyril; Coll, Patrice; Geffroy-Rodier, Claude; Raulin, Francois; Goesmann, Fred

    The search for signs of past or present life is one of the primary goals of the future Mars exploratory missions. With this aim the Mars Organic Molecule Analyzer (MOMA) experiment of the ExoMars 2016-2018 next coming joint ESA/NASA mission is designed to perform the in situ analysis of exobiological organic molecules of exobiological interest in the Martian soil such as amino acids, carboxylic acids, nucleobases or polycyclic aromatic hydrocarbons (PAHs). With the aim to separate and detect organic compounds from Martian soil, US and European teams have respectively built an ion trap mass spectrometer and a gas chromatograph. The mass spectrometer prototype has been coupled with the gas chromatograph prototype which is able to work in standalone mode by using a TCD detector. A GC-MS compatible sample processing system (SPS) allowing the extraction and the chemical transformation of the organic compounds from the soil, within space compatible operating conditions, has also been devel-oped. The sample processing is performed in an oven, dedicated to the MOMA experiment containing the solid sample (50-100mg). The internal temperature of which can be ranged from 20 to 1000 C. The extraction step is achieved by using thermodesorption in the range of 100 to 300C for 5 to 20 min. Then, the chemical derivatization and/or thermochemolysis of the extracted compounds is performed directly on the soil with a mixture of MTBSTFA-DMF, TMAH or DMF-DMA solution when enantiomeric separation is required. By decreasing the polarity of the target molecules, this step allows their volatilization at a temperature below 250C without any chemical degradation. Once derivatized, the volatile target molecules are trapped in a cold and chemical trap and promptly desorbed into the gas chromatograph coupled with a mass spectrometer. Preliminary tests, performed on Martian analogue soils (Atacama), with the MOMA SPS-GC/MS experiment, allowed the detection of organic compounds such as amino and

  20. U-Pb SHRIMP ages of granitoides from the main batholith belt (North East Asia) (United States)

    Akinin, V. V.; Prokopiev, A. V.; Toro, J.; Miller, E. L.; Wooden, J.; Goryachev, N. A.; Alshevsky, A. V.; Bakharev, A. G.; Trunilina, V. A.


    U-Pb SHRIMP-dating of zircons from twenty five intrusions representative of the Main granitoid batholith belt and associated dike swarms (Yano-Kolyma gold bearing province, North East of Asia) are mostly ˜150 ± 3 Ma (Kimmeridgian-Tithonian). Two less widespread impulses of magmatism dated at 160-155 Ma and 146-143 Ma representing the full range of ages present in the Main belt. Paleoproterozoic (˜1.8 Ga) inherited zircons were found in three intrusions from the south-western part of the belt where Precambrian crust of the North-Asia craton is inferred to underlie it.

  1. Tithonian age of dinosaur fossils in central Patagonian, Chile: U-Pb SHRIMP geochronology (United States)

    Suárez, Manuel; De La Cruz, Rita; Fanning, Mark; Novas, Fernando; Salgado, Leonardo


    Three Tithonian concordant U-Pb SHRIMP zircon ages of 148.7 ± 1.4, 147.9 ± 1.5 and 147.0 ± 1.0 from tuffs intercalated in a clastic sedimentary succession with exceptional dinosaur bones including the new taxon Chilesaurus diegosuarezi gen. et sp. nov. exposed in central Chilean Patagonia (ca. 46°30'S) are reported herein. The fossiliferous beds accumulated in a synvolcanic fan delta reaching a shallow marine basin as indicated by glauconite present in some of the beds, and coeval with the beginning of the transgression of the Aysén Basin.

  2. Maintenance: organizational modes, activities and health and safety. Use of a French national survey and in-situ analyses. (United States)

    Grusenmeyer, Corinne


    Maintenance activities are identified as critical both to operator safety and to systems safety and reliability. However, it is still difficult to identify maintenance workers in French occupational accident and disease statistics. Moreover, few analyses of these activities and of organizational changes in this field have been conducted. This paper presents two different approaches to this same issue. Analyses were aimed firstly at identifying the occupational exposures of these operators and at comparing them with occupational exposures of production staff and, secondly at developing understanding of normal real maintenance activities, i.e. maintenance activities that are normally actually carried out, while taking into account the socio-technical system and maintenance organization within which they lie. The use of the French SUMER 2003 survey shows that occupational exposures of maintenance staff to various constraints are more frequent than occupational exposures of their production colleagues. However, maintenance staff appear to have greater independence. Analyses were also conducted in a subcontracting urban public transport company, who outsources some maintenance work. Those analyses highlight a complex network of companies involved in maintenance activities, a substantial number of work interruptions and a significant fragmentation of the internal technicians' activities that can be cognitively costly, reduce anticipation possibilities and lead to incidents or accidents. Above all they underline internal technicians' contributions to the completion of outsourced interventions and interdependent relationships between the activities of the internal and the external technicians. Outsourcing maintenance interventions thus raises the question of risks associated with the interdependence of actual work activities undertaken by the different types of staff, since they contribute to the same maintenance intervention. This study therefore pinpoints the need to

  3. Zircon U-Pb ages and Hf isotopic compositions indicate multiple sources for Grenvillian detrital zircon deposited in western Laurentia (United States)

    Howard, Amanda L.; Farmer, G. Lang; Amato, Jeffrey M.; Fedo, Christopher M.


    Combined U-Pb ages and Hf isotopic data from 1.0 Ga to 1.3 Ga (Grenvillian) detrital zircon in Neoproterozoic and Cambrian siliciclastic sedimentary rocks in southwest North America, and from igneous zircon in potential Mesoproterozoic source rocks, are used to better assess the provenance of detrital zircon potentially transported across Laurentia in major river systems originating in the Grenville orogenic highlands. High-precision hafnium isotopic analyses of individual ∼1.1 Ga detrital zircon from Neoproterozoic siliciclastic sedimentary rocks in Sonora, northern Mexico, reveal that these zircons have low εHf (0) (-22 to -26) and were most likely derived from ∼1.1 Ga granitic rocks embedded in local Mojave Province Paleoproterozoic crust. In contrast, Grenvillian detrital zircons in Cambrian sedimentary rocks in Sonora, the Great Basin, and the Mojave Desert, have generally higher εHf (0) (-15 to -21) as demonstrated both by high precision solution-based, and by lower precision laser ablation, ICPMS data and were likely derived from more distal sources further to the east/southeast in Laurentia. Comparison to new and existing zircon U-Pb geochronology and Hf isotopic data from Grenvillian crystalline rocks from the Appalachian Mountains, central and west Texas, and from Paleoproterozoic terranes throughout southwest North America reveals that zircon in Cambrian sandstones need not entirely represent detritus transported across the continent from Grenville province rocks in the vicinity of the present-day southern Appalachian Mountains. Instead, these zircons could have been derived from more proximal, high εHf (0), ∼1.1 Ga, crystalline rocks such as those exposed today in the Llano Uplift in central Texas and in the Franklin Mountains of west Texas. Regardless of the exact source(s) of the Grenvillian detrital zircon, new and existing whole-rock Nd isotopic data from Neoproterozoic to Cambrian siliciclastic sedimentary rocks in the Mojave Desert

  4. In situ multi-element analyses by energy-dispersive X-ray fluorescence on varnishes of historical violins

    International Nuclear Information System (INIS)

    Echard, Jean-Philippe


    Varnishes of Italian violins and other historical stringed instruments have been analyzed by energy-dispersive X-ray fluorescence (EDXRF). The instruments whose varnishes were to be analyzed were chosen from the collection kept in Musee de la Musique in Paris. Direct analyses were performed on instrument varnishes, without any sampling and non-destructively, showing inorganic elements such as lead, mercury and iron that could be related to siccatives or pigments. Analytical results and their comparison with old formulae or traditional recipes of violin varnishes, as with the few previous analytical results, will be discussed

  5. In situ multi-element analyses by energy-dispersive X-ray fluorescence on varnishes of historical violins

    Energy Technology Data Exchange (ETDEWEB)

    Echard, Jean-Philippe [Laboratoire de recherche et de restauration, Musee de la musique, Cite de la musique, 221, avenue Jean-Jaures, 75019 Paris (France)]. E-mail:


    Varnishes of Italian violins and other historical stringed instruments have been analyzed by energy-dispersive X-ray fluorescence (EDXRF). The instruments whose varnishes were to be analyzed were chosen from the collection kept in Musee de la Musique in Paris. Direct analyses were performed on instrument varnishes, without any sampling and non-destructively, showing inorganic elements such as lead, mercury and iron that could be related to siccatives or pigments. Analytical results and their comparison with old formulae or traditional recipes of violin varnishes, as with the few previous analytical results, will be discussed.

  6. In situ multi-element analyses by energy-dispersive X-ray fluorescence on varnishes of historical violins (United States)

    Echard, Jean-Philippe


    Varnishes of Italian violins and other historical stringed instruments have been analyzed by energy-dispersive X-ray fluorescence (EDXRF). The instruments whose varnishes were to be analyzed were chosen from the collection kept in Musée de la Musique in Paris. Direct analyses were performed on instrument varnishes, without any sampling and non-destructively, showing inorganic elements such as lead, mercury and iron that could be related to siccatives or pigments. Analytical results and their comparison with old formulae or traditional recipes of violin varnishes, as with the few previous analytical results, will be discussed.

  7. Evidence of early Archean crust in northwest Gondwana, from U-Pb and Hf isotope analysis of detrital zircon, in Ediacaran surpacrustal rocks of northern Spain (United States)

    Naidoo, Thanusha; Zimmermann, Udo; Vervoort, Jeff; Tait, Jenny


    The Mora Formation (Narcea Group) is one of the oldest Precambrian supracrustal successions in northern Spain. Here, we use U-Pb and in situ Hf isotope analysis on detrital zircon to determine its age and provenance. The youngest U-Pb dates constrain the maximum depositional age of the Mora Formation at 565 ± 11 Ma. Results indicate: (1) a dominant Ediacaran zircon population (33%; 565-633 Ma, Cadomian) within a spectrum of Neoproterozoic ages (40%; 636-996 Ma); and (2) smaller Mesoproterozoic (5%; 1004-1240 Ma), Palaeoproterozoic (11%; 1890-2476 Ma) and Archean (11%; 2519-3550 Ma) populations. Results here do not point to one specific cratonic source area; instead, detritus may have been derived from the West African craton and Amazonia, or even the concealed Iberian basement. The lack of 1.3-1.8 Ga grains suggests exclusion of the Sahara Craton as a major source, but this is not certain. This mixed composition favours a complex source history with reworking of detritus across terrane/craton boundaries. Hafnium isotope compositions indicate a range of crustal and juvenile sources, with initial ɛHf values between -15.8 and 11.1, and Hf model ages from 0.8 to 3.7 Ga. For Neoproterozoic zircons (80%), juvenile components (ɛHf(i) +10) may be related to Rodinia fragmentation and the onset of an active margin setting leading to the Cadomian orogeny. Palaeoproterozoic to Paleoarchean grains (20%) all have negative ɛHf values and Meso- to Eoarchean Hf model ages. This indicates an early (Archean) sialic crustal component for northwestern Gondwana.

  8. Geology and U-Pb geochronology of the Banabuiu granite, Northeastern Ceara, Brazil; Geologia y geocronologia U-Pb del granito de Banabuiu, Noreste de Ceara, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Lima, M. N.; Nogueira Neto, J. A.; Azevedo, M. R.; Valle Aguado,


    The Banabuiu massif crops out in the Central Ceara Domain (DCC) of the Borborema Province (NE Brasil), as an N-S elongate granite intrusion, concordant with the regional structures. It was emplaced into basement rocks of Paleoproterozoic age, extensively transformed into gneisses and migmatites during the Brasilian orogeny ({approx}600 Ma). Using U-Pb zircon dating, the crystallization age of the Banabuiu syn-kinematic two-mica granite was estimated at 578.6 {+-} 6.5 Ma. The granite is strongly peraluminous (A/CNK 1,098 - 1,134) and shows a typical S-type geochemical signature. The {epsilon}Nd{sub 5}80 values are strongly negative ({epsilon}Nd{sub 5}80 = -19 a - 23) and partially overlap with those of the Paleoproterozoic gneissmigmatite complex ({epsilon}Nd{sub 5}80 = -12 to -26), suggesting that the parental magmas of the Banabuiu granite could have been produced by partial melting of similar crustal materials. (Author) 21 refs.

  9. Provenance analysis of the Late Triassic Yichuan Basin: constraints from zircon U-Pb geochronology

    Directory of Open Access Journals (Sweden)

    Meng Xianghong


    Full Text Available Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS U-Pb dating has been performed on detrital zircons from the Chunshuyao Formation sandstone of Yichuan Basin. The ages of 85 detrital zircon grains are divided into three groups: 252-290 Ma, 1740-2000 Ma, and 2400-2600 Ma. The lack of Early Paleozoic and Neoproterozoic U-Pb ages indicates that there is no input from the Qinling Orogen, because the Qinling Orogen is characterized by Paleozoic and Neoproterozoic material. In combination with previous research, we suggest that the source of the Chunshuyao Formation is most likely recycled from previous sedimentary rocks from the North China Craton. In the Late Triassic, the Funiu ancient land was uplifted which prevented source material from the Qinling Orogen. Owing to the Indosinian orogeny, the strata to the east of the North China Craton were uplifted and eroded. The Yichuan Basin received detrital material from the North China Craton.

  10. Magmatic tempo of Earth's youngest exposed plutons as revealed by detrital zircon U-Pb geochronology. (United States)

    Ito, Hisatoshi; Spencer, Christopher J; Danišík, Martin; Hoiland, Carl W


    Plutons are formed by protracted crystallization of magma bodies several kilometers deep within the crust. The temporal frequency (i.e. episodicity or 'tempo') of pluton formation is often poorly constrained as timescales of pluton formation are largely variable and may be difficult to resolve by traditional dating methods. The Hida Mountain Range of central Japan hosts the youngest exposed plutons on Earth and provides a unique opportunity to assess the temporal and spatial characteristics of pluton emplacement at high temporal resolution. Here we apply U-Pb geochronology to zircon from the Quaternary Kurobegawa Granite and Takidani Granodiorite in the Hida Mountain Range, and from modern river sediments whose fluvial catchments include these plutons in order to reconstruct their formation. The U-Pb data demonstrate that the Kurobegawa pluton experienced two magmatic pulses at ~2.3 Ma and ~0.9 Ma; whereas, to the south, the Takidani pluton experienced only one magmatic pulse at ~1.6 Ma. These data imply that each of these magmatic systems were both spatially and temporally distinct. The apparent ~0.7 Myr age gap between each of the three magmatic pulses potentially constrains the recharge duration of a single pluton within a larger arc plutonic complex.

  11. U-Pb ages in zircon of some classic granites from the Borborema province

    International Nuclear Information System (INIS)

    Neves, Benjamin Bley de Brito; Basei, Miguel Angelo Stipp; Passarelli, Claudia Regina; Santos, Edilton Jose dos


    The Neoproterozoic evolution of the Borborema Province in the east-northeast part of the South American platform exhibits remarkable, much studied granitic plutonism. In 1967 F. F. Almeida and co-workers discriminated a series of granitic typologies as 'Conceicao type', 'Itaporanga type' etc, mostly based upon general geological features and petrographic grounds. This preliminary classification has somehow been maintained in all subsequent papers up to now, despite all the newly observed plutons and the newly generated tectonic, geochemical and isotopic data since then. Samples of these classical types of granites from their type-localities were analyzed geo chronologically using the U-Pb method in zircons in response to the felt needs of the geological community, because previous age-determinations involved less accurate methods. The new data have been added to all other preexisting U-Pb data (from other granitic bodies) obtained over the last decade, making it possible to recognize three main stages of granitic magmatism for the Borborema Province: 650-625 Ma, 580-570 Ma and 545-520 Ma. The last group of dates is closely association with the escape tectonics of the Brasiliano-Pan African collage, which preceded the assembly of the super continental landmass of Western Gondwana. (author)

  12. TEMORA 1: A new zircon standard for Phanerozoic U-Pb geochronology (United States)

    Black, L.P.; Kamo, S.L.; Allen, C.M.; Aleinikoff, J.N.; Davis, D.W.; Korsch, R.J.; Foudoulis, C.


    The role of the standard is critical to the derivation of reliable U-Pb zircon ages by micro-beam analysis. For maximum reliability, it is critically important that the utilised standard be homogeneous at all scales of analysis. It is equally important that the standard has been precisely and accurately dated by an independent technique. This study reports the emergence of a new zircon standard that meets those criteria, as demonstrated by Sensitive High Resolution Ion MicroProbe (SHRIMP), isotope dilution thermal ionisation mass-spectrometry (IDTIMS) and excimer laser ablation- inductively coupled plasma-mass-spectrometry (ELA-ICP-MS) documentation. The TEMORA 1 zircon standard derives from the Middledale Gabbroic Diorite, a high-level mafic stock within the Palaeozoic Lachlan Orogen of eastern Australia. Its 206Pb/238U IDTIMS age has been determined to be 416.75??0.24 Ma (95% confidence limits), based on measurement errors alone. Spike-calibration uncertainty limits the accuracy to 416.8??1.1 Ma for U-Pb intercomparisons between different laboratories that do not use a common spike. ?? 2003 Published by Elsevier Science B.V. All rights reserved.

  13. An Early Permian epithermal gold system in the Tulasu Basin in North Xinjiang, NW China: Constraints from in situ oxygen-sulfur isotopes and geochronology (United States)

    Dong, Leilei; Wan, Bo; Deng, Chen; Cai, Keda; Xiao, Wenjiao


    The Axi and Jingxi-Yelmand gold deposits, being the largest gold deposits in the Chinese North Tianshan, NW China, are located ca. l0 km apart in the Tulasu Basin, and are hosted by the Late Devonian - Early Carboniferous Dahalajunshan Formation. In situ LA-ICP-MS titanium analyses on quartz from the Axi and Jingxi-Yelmand deposits are broadly identical. Accordingly, the calculated ore-forming temperatures by Ti-in-quartz thermometer give average temperatures of 279 °C and 294 °C, respectively. Results of in situ SIMS analyses of oxygen and sulfur isotopes on quartz and pyrite from these two deposits are similar. Temperature-corrected fluids of the Axi deposit have δ18O values of 2.6-8.1‰ and δ34S values of 0.8-2.4‰, whereas the fluids of the Jingxi-Yelmand deposit have δ18O of 6.4-8.9‰ and δ34S of -0.4 to 4.0‰. The oxygen and sulfur isotopes from the two deposits indicate a magmatic origin. LA-ICP-MS zircon U-Pb ages of Aqialehe Formation sandstone provided a lower limit for the mineralization timing of the Axi deposit (288 Ma). In situ SIMS U-Pb analyses on entrapped zircon (297 Ma) and newly recognized 284.5 Ma columnar rhyolite implies that the Jingxi-Yelmand deposit formed in the Early Permian. Based on the magmatic affinity of the ore fluids, similar age and ore-formation temperatures, we propose that the Axi and Jingxi-Yelmand deposits comprise an epithermal gold system, which was driven by the same Permian magma in the Tulasu Basin. The ore geological features together with our new results indicate that the Axi and Jingxi-Yelmand deposits are intermediate and high sulfidation type epithermal deposits, respectively.

  14. U-Pb SHRIMP ages of detrital zircons from Hiriyur formation in Chitradurga Greenstone belt and its implication to the Neoarchean evolution of Dharwar craton, South India

    International Nuclear Information System (INIS)

    Nasheeth, A.; Okudaira, T.; Horie, K.; Hokada, T.; Satish Kumar, M.


    We report newly obtained U-Pb SHRIMP ages of detrital zircons from metagreywackes in the Hiriyur Formation (Chitradurga Group, Dharwar Supergroup) from the central eastern part of the Chitradurga greenstone belt. U-Pb analyses yield three major Neoarchean age populations ranging from 2.70 - 2.54 Ga with some minor age population of Mesoarchean. The maximum age of deposition is constrained by the youngest detrital zircon population at 2546 Ma. This is the first report of the occurrence of supracrustal rocks less than 2.58 Ga in the central part of Chitradurga greenstone belt. Close evaluation of detrital ages with the published ages of surrounding igneous rocks suggest that the youngest detrital zircons might be derived from rocks of the Eastern Dharwar craton and the inferred docking of the western and eastern Dharwar cratons happened prior to the deposition of the Hiriyur Formation. The Chitradurga shear zone, dividing the Dharwar craton into western and eastern blocks, probably developed after the deposition. Furthermore, the lower intercept is interpreted as evidence for the Pan-African overprints in the study area. (author)

  15. U-Pb zircon constraints on the age of the Cretaceous Mata Amarilla Formation, Southern Patagonia, Argentina: Its relationship with the evolution of the Austral Basin

    International Nuclear Information System (INIS)

    Varela, Augusto N; Poire, Daniel G; Martin, Thomas; Gerdes, Axel; Goin, Francisco J; Gelfo, Javier N; Hoffmann, Simone


    Despite the abundant fossil content of the Mata Amarilla Formation (Southern Patagonia, Santa Cruz Province, Argentina), its age has always generated a considerable number of questions and debates. The chronological data provided by invertebrates, dinosaurs, fish, turtles, plesiosaurs and fossil flora are contradictory. In this work, twenty U-Pb spot analyses by laser ablation were carried out on the outer parts of the zoned zircon crystals from a tuff layer of the middle section of the Mata Amarilla Formation, yielding a U-Pb concordia age of 96.23±0.71 Ma, which corresponds to the middle Cenomanian. The deposition of the lower section of the Mata Amarilla Formation marks the onset of the foreland stage of the Austral Basin (also known as Magallanes Basin); this transition is characterized by the west-east shift of the depositional systems, which is consistent with the progradation of the Cretaceous fold-and-thrust belt. Thus, the onset of the foreland stage could have occurred between the upper Albian and lower Cenomanian, as the underlying Piedra Clavada Formation is lower Albian in age. On comparing the data obtained with information from the Ultima Esperanza Province in Chile, it can be suggested that the initiation of the closure of the Rocas Verdes Marginal Basin occurred simultaneously

  16. U-Pb ages of detrital zircon from Pegasus Group, Stewart Island

    International Nuclear Information System (INIS)

    Walker, N.; Tulloch, A.J.; Allibone, A.


    Stewart Island (New Zealand) is relatively unaffected by Cenozoic deformation related to the present-day plate boundary and has thus been a locale of investigations that focus on the relationship between Mesozoic continental margin magmatic rocks and the Western Province (WP) of NZ. Pegasus Group metasedimentary rocks represent the only candidate for WP equivalents on Stewart Island. We measured U-Pb and 207 Pb / 206 Pb ages of detrital zircons from the Pegasus Group in an effort to validate the correlation with the WP. On SI, Pegasus Group is exposed over a small area in the southern Tin Range where it forms amphibolite facies roof pendants and screens among plutons of mid Paleozoic to mid Cretaceous age. Mica schists predominate, with lesser amounts of psammite and metaquartzite and rare calcareous schist and amphibolite. Zircons were extracted from metaquarzite and 24 grains were chosen on the basis of morphology for geochronologic investigation. Sixteen single crystals were dated by U-Pb TIMS; 8 additional grains were studied by the total evaporation method described by Kober. Despite vigorous air abrasion prior to processing, the 16 grains measured by conventional U-Pb TIMS yielded slightly normally discordant ages that we interpret to reflect minor Pb-loss. The 8 grains studied by the total evaporation method yielded more than four analytically identical /sup 207 Pb / 206 Pb ages within each grain at progressively higher temperatures (1515-1580 degrees C) of evaporation. The results permit the following general conclusions: 1) the age range of 420-2700 Ma is grossly similar to that reported from the Greenland Group/Victoria Paragneiss (Ireland 1992) of the Buller Terrane, WP; 2) the zircon population is dominantly 530-680 Ma but a subsidiary population is 900-1100 Ma; 3) no zircons with ages that match the timing of the Ross Orogen (530-480 Ma) were identified; 4) two grains of 420 Ma and a 453 Ma are probably too young for the paleontogically

  17. Th-U-PbT dating by Electron Probe Microanalysis, Part I. Monazite: analytical procedures and data treatment;Datacao Th-U-Pb{sub T} com microssonda eletronica, Parte I. Monazita: procedimentos analiticos e tratamento de dados

    Energy Technology Data Exchange (ETDEWEB)

    Vlach, Silvio Roberto Farias, E-mail: srfvlach@usp.b [Universidade de Sao Paulo (IG/USP), SP (Brazil). Inst. de Geociencias. Dept. de Mineralogia e Geotectonica


    Dating methodology by the electron probe microanalyser (EPMA) of (Th, U)-bearing minerals, highlighting monazite, acquired greater than ever importance in literature, particularly due to its superior spatial resolution, as well as versatility, which allow correlating petrological processes at times registered only in micro-scales in minerals and rocks with absolute ages. Although the accuracy is inferior to the one achieved with conventional isotopic methods in up to an order of magnitude, EPMA is the instrument that allows the best spatial resolution, reaching a few {mu}m{sup 3} in some conditions. Quantification of minor and trace elements with suitable precision and accuracy involves the own instrumental and analytical set-ups and data treatment strategies, significantly more rigorous when compared with those applied in conventional analyses. Th-U-Pb{sub T} dating is an example of these cases. Each EPMA is a unique machine as for its instrumental characteristics and respective automation system. In such a way, analytical procedures ought to be adjusted for laboratory specificities. The analytical strategies and data treatment adopted in the Electronic Microprobe Laboratory from Instituto de Geociencias of Universidade de Sao Paulo, Brazil, with a JEOL JXA8600S EPMA, and a ThermoNoran-Voyager 4.3 automation system, are presented and compared with the ones used in other laboratories. The influence of instrumental factors and spectral overlaps on Th, U, and Pb quantification is discussed. Applied procedures to interference correction, error propagation, data treatment, and fi nal chemical age presentation as well as to sampling and analyses are emphasized. Some typical applications are discussed, drawing attention to the most relevant aspects of electron microprobe dating. (author)

  18. SHRIMP U-Pb zircon dating of Pedras Grandes Suite, southern Santa Catarina State, Brazil

    Directory of Open Access Journals (Sweden)

    Andréa R. Jelinek


    Full Text Available Two major magmatic pulses of the granitic Florianópolis Batholith in Santa Catarina State, southern Brazil, occurred between 613±5Ma and 595±5 Ma, during the Neoproterozoic Brasiliano Cycle. These ages were obtained by U-Pb isotopic determinations with the sensitive high mass-resolution ion microprobe on igneous zircons from Pedras Grandes Suite in Santa Catarina State. Euhedral zircons remained unaltered close to a fluorite vein deposited at 180?C or more. These ages suggest a northern limit for the Pedras Grandes Suite, explaining the spatial relationship between the fluorite veins and the source rock.Dois dos principais pulsos da atividade granítica no Batólito Florianópolis em Santa Catarina ocorreram entre 613 ±5 Ma e 595 ±5 Ma, durante o Neoproterozóico do Ciclo Brasiliano. Estas idades foram obtidas a partir dedeterminações isotópicas U-Pb em cristais de zircão da Suite Pedras Grandes por "Sensitive high-resolution íon microprobe" - SHRIMP II. Os cristais de zircão permaneceram inalterados mesmo mediante condições hidrotermais com temperaturas iguais e, até mesmo, superiores a 180ºC. Estas idades sugerem a delimitação norte do Maciço Pedras Grandes, explicando a relação espacial existente entre os filões de fluorita e a rocha fonte destas mineralizações.

  19. Th-U-Pb{sub T} dating by electron probe microanalysis, Part I. Monazite: analytical procedures and data treatment

    Energy Technology Data Exchange (ETDEWEB)

    Vlach, Silvio Roberto Farias [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil). Inst. de Geociencias. Dept. de Mineralogia e Geotectonica], e-mail:


    Dating methodology by the electron probe microanalyser (EPMA) of (Th, U)-bearing minerals, highlighting monazite, acquired greater than ever importance in literature, particularly due to its superior spatial resolution, as well as versatility, which allow correlating petrological processes at times registered only in micro-scales in minerals and rocks with absolute ages. Although the accuracy is inferior to the one achieved with conventional isotopic methods in up to an order of magnitude, EPMA is the instrument that allows the best spatial resolution, reaching a few {mu}m{sup 3} in some conditions. Quantification of minor and trace elements with suitable precision and accuracy involves the own instrumental and analytical set-ups and data treatment strategies, significantly more rigorous when compared with those applied in conventional analyses. Th-U-Pb{sub T} dating is an example of these cases. Each EPMA is a unique machine as for its instrumental characteristics and respective automation system. In such a way, analytical procedures ought to be adjusted for laboratory specific cities. The analytical strategies and data treatment adopted in the Electronic Microprobe Laboratory from Instituto de Geociencias of Universidade de Sao Paulo, Brazil, with a JEOL JXA8600S EPMA, and a ThermoNoran-Voyager 4.3 automation system, are presented and compared with the ones used in other laboratories. The influence of instrumental factors and spectral overlaps on Th, U, and Pb quantification is discussed. Applied procedures to interference correction, error propagation, data treatment, and final chemical age presentation as well as to sampling and analyses are emphasized. Some typical applications are discussed, drawing attention to the most relevant aspects of electron microprobe dating. (author)

  20. Unraveling the tectonic evolution of a Neoproterozoic-Cambrian active margin in the Ribeira Orogen (Se Brazil): U-Pb and Lu-Hf provenance data

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, Gabriel Lamounier de F. [Servico Geologico do Estado do Rio de Janeiro (DRM-RJ), Niteroi, RJ (Brazil); Schmitt, Renata; Bongiolo, Everton M.; Mendes, Julio [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil); Basei, Miguel S. [Universidade de Sao Paulo (USP), SP (Brazil)


    Full text: The Neoproterozoic-Ordovician Central Ribeira Orogen, in SE Brazil, presents two contrasting tectonic domains in its southern portion: (a) The Arc Domain constituted of Neoproterozoic to Paleozoic magmatic rocks and low P-high T metamorphic para (Sao Fidelis Group) - and ortho- derived units (in Oriental Terrane); and (b) The Basement Domain, constituted of a Paleoproterozoic and Neoproterozoic medium P-high T metamorphic para (Palmital-Buzios Succession)- and ortho-derived units (in Cabo Frio Tectonic Domain). Our work focuses on paraderived rocks sequences from both domains. The provenance analysis using U-Pb and Lu-Hf in zircon grains is presented here as an effective tool to unravel the paleogeography and nature of the pre-collisional sedimentary basins. We performed 505 analyses (U-Pb) on detrital zircon grains and some metamorphic overgrowths from six paragneiss samples. Besides, 141 analyses (Lu-Hf) in six samples only on the detrital zircon grains domains. All samples present a main peak from Neoproterozoic sources (750-570 Ma) and the other minor peak in the Stenian/Tonian periods (1200-850Ma), this indicate an orogenic contribution for this basin. Scarce register from the Mesoproterozoic and two peaks in the Archean/Paleoproterozoic (2.6 and 1.9 Ga) are recognized as a contribution from an ancient continent. The Lu-Hf data reveals a juvenile source for the detrital zircon grains from Buzios Succession while Palmital and Sao Fidelis Group units show a main crustal signature for their detrital zircon population. Based on the U-Pb and Lu-Hf data presented here, plus petrological data, geological correlations, and compilation of data from literature, we propose a tectonic model for the origin of para-derived rocks from the eastern part of the Ribeira Orogen. Starting with an extensional environment of ca. 600 Ma in a back-arc basin (Buzios succession deposition) and continuing as an active margin between 570 and 550 Ma in the fore-arc and prism

  1. Pan-African U-Pb zircon age from apatite-magnetite veins of eastern ghats granulite belt, India

    International Nuclear Information System (INIS)

    Kovach, V.P.; Salnikova, E.B.; Kotov, A.B.; Yakovleva, S.Z.; Rao, A.T.


    206 Pb/ 238 U ages of zircon correspond to 502±3 Ma and 207 Pb/ 206 Pb ages are equal to 508±14 Ma. U-Pb isotopic study of the Kasipatnam zircon has led to the recognition of pan-African thermal event in the eastern ghats granulite belt, India. (author)

  2. U-Pb ages and Nd isotope characteristics of the lateorogenic, migmatizing microcline granites in southwestern Finland

    Directory of Open Access Journals (Sweden)

    Matti Kurhila


    Full Text Available U-Pb ages and whole-rock Nd isotope data have been obtained from the Paleoproterozoic lateorogenic migmatizing microcline granites of southwestern Finland. Isotope dilution and ion microprobe U-Pb data on zircons and monazites show that the age spectrum of these granites is at least 1.85-1.82 Ga. Commonly, zircons and monazites record the same ages. The age variation in the Veikkola granite area is of the order of 25 Ma and indicates that this seemingly homogeneous granite consists of two separate intrusions. The zircons of the lateorogenic granites are pervasively altered and conventional U-Pb results are commonly discordant. The ion microprobe studies reveal that the granites contain very few inherited zircons with preserved original U-Pb isotope ratios, with the exception of the Oripää granite. Initial εNd values, mostly in the range of ‑0.5 to ‑1.0, imply a moderate input of older crustal material into most of the lateorogenic granites. A shift from more juvenile to less radiogenic Nd isotope composition is observed from north to south, and the variation pattern of εNd values of the lateorogenic granites is thus similar to that of the surrounding synorogenic granitoid rocks.

  3. Evidence for prolonged mid-Paleozoic plutonism and ages of crustal sources in east-central Alaska from SHRIMP U-Pb dating of syn-magmatic, inherited, and detrital zircon (United States)

    Dusel-Bacon, C.; Williams, I.S.


    Sensitive high-resolution ion microprobe (SHRIMP) U-Pb analyses of igneous zircons from the Lake George assemblage in the eastern Yukon-Tanana Upland (Tanacross quadrangle) indicate both Late Devonian (???370 Ma) and Early Mississippian (???350 Ma) magmatic pulses. The zircons occur in four textural variants of granitic orthogneiss from a large area of muscovite-biotite augen gneiss. Granitic orthogneiss from the nearby Fiftymile batholith, which straddles the Alaska-Yukon border, yielded a similar range in zircon U-Pb ages, suggesting that both the Fiftymile batholith and the Tanacross orthogneiss body consist of multiple intrusions. We interpret the overall tectonic setting for the Late Devonian and Early Mississippian magmatism as an extending continental margin (broad back-arc region) inboard of a northeast-dipping (present coordinates) subduction zone. New SHRIMP U-Pb ages of inherited zircon cores in the Tanacross orthogneisses and of detrital zircons from quartzite from the Jarvis belt in the Alaska Range (Mount Hayes quadrangle) include major 2.0-1.7 Ga clusters and lesser 2.7-2.3 Ga clusters, with subordinate 3.2, 1.4, and 1.1 Ga clusters in some orthogneiss samples. For the most part, these inherited and core U-Pb ages match those of basement provinces of the western Canadian Shield and indicate widespread potential sources within western Laurentia for most grain populations; these ages also match the detrital zircon reference for the northern North American miogeocline and support a correlation between the two areas.

  4. Zircon U-Pb age and Hf-O isotopes of felsic rocks from the Atlantis Bank, Southwest Indian Ridge (United States)

    Liu, C. Z.; Zhang, W. Q.


    Hole U1473A was drilled to 790 meters below seafloor on the Atlantis Bank, an oceanic core complex in the Southwest Indian Ridge, where the upper crust has been removed by detachment faulting. The recovered core consists dominantly of olivine gabbro, with subordinate gabbro, gabbro with varying Fe-Ti oxide concentrations. Felsic veins intermittently occur throughout the whole core section. Zircons separated from twenty-four felsic samples have been conducted for U-Pb dating and O isotope analyses on the Cameca 1280 and Lu-Hf isotopes by laser ablation coupled with a MC-ICPMS. The zircons have highly variable contents of U (12-2078 ppm) and Th (5-801 ppm), yielding Th/U ratios of 0.33-0.81. They are typical oceanic zircons as defined by the trace element discrimination plots of Grimes et al. (2015). The weighted mean 206Pb/238U ages of the analyzed zircons vary from 11.29 to 12.57 Ma. Age differences between felsic veins throughout the whole core are not resolved within analytical uncertainty of the SIMS measurements. All felsic samples have similar zircon Hf isotope compositions, with initial 176Hf/177Hf ratios of 0.283126-0.283197 and ɛHf values of 12.76-15.27. Zircons from all felsic samples but one have mantle-like δ18O values of 5.14-5.50‰. Zircons from one sample show partial resorption or total recrystallization; in comparison, they have lower δ18O values of 4.81±0.21‰. Such characteristics provide clear evidence for hydrothermal alteration after magmatic intrusion.

  5. Tectono-magmatic evolution of the Chihuahua-Sinaloa border region in northern Mexico: Insights from zircon-apatite U-Pb geochronology, zircon Hf isotope composition and geochemistry of granodiorite intrusions (United States)

    Mahar, Munazzam Ali; Goodell, Philip C.; Feinstein, Michael Nicholas


    We present the whole-rock geochemistry, LA-ICP-MS zircon-apatite U-Pb ages and zircon Hf isotope composition of the granodioritic plutons at the southwestern boundary of Chihuahua with the states of Sinaloa and Sonora. These granodiorites are exposed in the north and south of the Rio El Fuerte in southwest Chihuahua and northern Sinaloa. The magmatism spans over a time period of 37 Ma from 90 to 53 Ma. Zircons are exclusively magmatic with strong oscillatory zoning. No inheritance of any age has been observed. Our new U-Pb dating ( 250 analyses) does not support the involvement of older basement lithologies in the generation of the granitic magmas. The U-Pb apatite ages from granodiorites in southwest Chihuahua vary from 52 to 70 Ma. These apatite ages are 1 to 20 Ma younger than the corresponding zircon U-Pb crystallization ages, suggesting variable cooling rates from very fast to 15 °C/Ma ( 800 °C to 500 °C) and shallow to moderate emplacement depths. In contrast, U-Pb apatite ages from the Sinaloa batholith are restricted from 64 to 61 Ma and are indistinguishable from the zircon U-Pb ages range from 67 to 60 Ma within the error, indicating rapid cooling and very shallow emplacement. However, one sample from El Realito showed a larger difference of 20 Ma in zircon-apatite age pair: zircon 80 ± 0.8 Ma and apatite 60.6 ± 4 Ma, suggesting a slower cooling rate of 15 °C/Ma. The weighted mean initial εHf (t) isotope composition (2σ) of granodiorites varies from + 1.8 to + 5.2. The radiogenic Hf isotope composition coupled with previous Sr-Nd isotope data demonstrates a significant shift from multiple crustal sources in the Sonoran batholithic belt to the predominant contribution of the mantle-derived magmas in the southwest Chihuahua and northern Sinaloa. Based on U-Pb ages, the absence of inheritance, typical high Th/U ratio and radiogenic Hf isotope composition, we suggest that the Late Cretaceous-Paleogene magmatic rocks in this region are not derived from

  6. Using the U-Pb system of calcretes to date the time of sedimentation of clastic sedimentary rocks

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Z.S.; Rasbury, E.T.; Hanson, G.N.; Meyers, W.J. [State Univ. of New York, Stony Brook, NY (United States). Dept. of Geosciences


    The time of sedimentation of rapidly deposited clastic sedimentary rocks in fluvial environments may be directly dated with an uncertainty of less than three million years using U-Pb dating of pure micritic calcite from calcretes developed in overbank deposits. This conclusion is based on results obtained for calcretes (soil calcite, caliche) formed in the late Triassic New Haven Arkose, Hartford Basin, Connecticut, USA. The paragenesis of calcrete samples from the New Haven Arkose was determined using plane-polarized light and cathodoluminescence petrography, uranium fission track analysis, as well as trace element and stable isotope geochemistry. These calcretes contain an abundance of paleosol microfabrics and diagenetic calcite. The first-generation micritic calcite and second-generation blocky calcite have characteristics consistent with soil calcite. The third generation blocky calcite is a later diagenetic calcite (post-soil calcite). The U-Pb data for pure micritic calcite (first generation) in a horizontal sheet calcrete in sedimentary rocks of Norian age gives a {sup 238}U/{sup 207}Pb-{sup 206}Pb/{sub 207}Pb isochron age of 211.9 {+-} 2.1 Ma (2-sigma, and used hereafter for all ages). The U-Pb data for two samples of first generation micrite in rhizoliths with about 15% insoluble residues give ages of 7 {+-} 66 Ma and 20 {+-} 36 Ma. These results suggest that relatively recent events disturbed the U-Pb system of these detrital rich samples, perhaps due to redistribution of U during weathering or during chemical dissolution for analysis. The U-Pb data for a sample of pure third generation blocky calcite cement in a rhizolith yields a {sup 206}Pb/{sup 238}U-{sup 207}Pb/{sup 235}U isochron age of 81 {+-} 11 Ma. This age suggests that this sample of third generation blocky calcite precipitated during the late Cretaceous perhaps over an extended period.

  7. Mesozoic to Cenozoic U-Pb zircon ages from Graham Land, West Antarctica: the magmatic evolution of the Antarctic Peninsula batholith (United States)

    Bastias, Joaquin; Spikings, Richard; Ulianov, Alex; Schaltegger, Urs; Grunow, Anne; Hervé, Francisco


    The plutonic rocks of the Antarctic Peninsula form one of the major intrusive bodies located along the circum-Pacific rim. Spanning ages of ˜240 to 9 Ma and emplaced over 1300 km long and 200 km wide along Graham and Palmer Land, these rocks represents a key unit to understand the magmatic and tectonic evolution of the Antarctic Peninsula. In the north, the plutons intrude Paleozoic- Mesozoic low-grade meta-sedimentary rocks, and intrudes schists and ortho- and paragneisses with Triassic to Carboniferous metamorphic ages, further south. The origin of the arc of Antarctic Peninsula has been in dispute since the interpretation of Vaughan and Storey (2000) who suggested that these plutonic rocks are part of an allochthonous arc, contradicting the traditional interpretation that these rocks are autochthonous and are part of the continental arc which formed along the southern margin of Gondwana (Suarez, 1976). We will address the magmatic and tectonic evolution of the Antarctic Peninsula by providing crystallization ages (zircon U-Pb and hornblende 40Ar/39Ar) of the main plutonic units, together with the characterization of the tectonic environment within which magmatism was occurring (geochemical studies and isotopic tracing). We present 45 LA-ICP-MS U-Pb (zircon) and 4 40Ar/39Ar (hornblende) dates of plutons and dikes from the west coast of the northern Antarctic Peninsula and the South Shetland Islands. Their geochemical composition shows affinities with calc-alkaline, supra-subduction zone rocks (Pearce et al., 1984). The U-Pb zircon ages range between ˜160 Ma (Stonington Island) to ˜9 Ma (Cornwallis Island), with a peak in the Early Cretaceous (Albian and Aptian). Upper Jurassic to Eocene intrusions were emplaced in a constant, approximately stationary position. Magmatism displaced ˜50km westwards during the Miocene, which is currently exposed on Watkin Island (˜22 Ma), Snodgrass Island (˜19 Ma), Litchfield Island (˜19 Ma) and Cornwallis Island (˜26 Ma

  8. Zircon U-Pb Geochronology, Hf Isotopic Composition and Geological Implications of the Neoproterozoic Huashan Group in the Jingshan Area, Northern Yangtze Block, China (United States)

    Yang, Z.; Yang, K.


    In the northern Yangtze Block, a clear angular unconformity between the Mesoproterozoic sequences (e.g. Dagushi Group) and the overlying Neoproterozoic strata (e.g. Huashan Group) marks the the Jinning orogeny. A combined study of Lu-Hf isotopes and U-Pb ages for detrital zircons from Huashan Group can provide information on the crustal evolution of sedimentary provenances and the timing of the Jinning orogeny. Detrital zircons from Huashan Group have two major U-Pb age populations of about 2.0Ga, 2.65Ga, and three subordinate age groups of about 0.82Ga, 2.5Ga, 2.9Ga with minor >3.0Ga ages. The youngest five analyses yield a weighted average age of 816±9Ma, which is consistent with that of interlayered basalt (824±9Ma, Deng et al., 2013) and roughly defines the minimum depositional age of Huashan Group. Detrital zircons of Huashan Group mostly have two stage Hf isotope model ages (TDM2) between 3.0 to 3.3Ga, indicating that the northern Yangtze Block experienced significant continental crustal growth during the Paleo- to Meso-archean. Similar U-Pb ages of detrital zircons have been obtained from Precambrian sedimentary rocks in the northern Yangtze Block from previous studies (Liu et al., 2008; Guo et al., 2014 and references therein). Recently, ca. 2.65Ga A-type granites had been reported from the Kongling and Huji area, which likely record the thermally stable lithosphere (Chen et al., 2013; Zhou et al., 2015). In combination with this study, it documents the widespread 2.6-2.7Ga magmatic rocks in the northern Yangtze Block. Zhao et al. (2013) demonstrated both the ca. 850Ma tonalite and trondhjemite of the Huangling igneous complex were formed in a continental arc setting. This suggests the Miaowan-Huashan oceanic basin proposed by Bader et al. (2013) has not been closed at ca. 850Ma. This evidence, together with the depositional age of the Huashan Group, indicates the Jinning orogeny took place at 850-820 Ma. [1] Bader et al., 2013 Tectonics [2] Deng et al

  9. Geochemistry and zircon U-Pb geochronology of the Pulang complex, Yunnan province, China

    International Nuclear Information System (INIS)

    Pang, Zhenshan; Du, Yangsong; Cao, Yi; Gao, Fuping; Wang, Gongwen; Dong, Qian


    The Pulang complex is located tectonically at the southern margin of the Yidun-Zhongdian island arc belt in Yunnan province, China, and is closely related to formation of the Pulang copper deposit, which is the largest copper deposit in Asia. The Pulang complex can be divided into three intrusion stages based on contact relationships and petrological characteristics: (1) a first stage of quartz dioritic porphyry; (2) a second stage of quartz monzonitic porphyry; and (3) a third stage of granodioritic porphyry. The crystallization ages of these intrusion stages were determined by single-zircon U-Pb dating, yielding ages of 221.0 ± 1.0, 211.8 ± 0.5, and 206.3 ± 0.7 Ma for the first, second, and third stages, respectively. These dates, integrated with previous geochronological data and field investigations, indicate that the second-stage quartz monzonitic porphyry has a close spatial and temporal relationship with the large Pulang porphyry copper deposit. These age data, geochemical and Sr-Nd isotopic results suggest that the Pulang complex formed in the Indo-Chinese epoch (257∼ 205 Ma) by multiphase intrusion of a mixture of mantle- and crust-derived magmas. (author)

  10. U-Pb dating of uranium deposits in collapse breccia pipes of the Grand Canyon region (United States)

    Ludwig, K. R.; Simmons, K.R.


    Two major periods of uranium mineralization are indicated by U-Pb isotope dating of uranium ores from collapse breccia pipes in the Grand Canyon region, northern Arizona. The Hack 2 and 3, Kanab North, and EZ 1 and 2 orebodies apparently formed in the interval of 200 ?? 20 Ma, similar to ages inferred for strata-bound, Late Triassic-hosted uranium deposits in southern Utah and northern Arizona. Samples from the Grand Canyon and Pine Nut pipes, however, indicate a distinctly older age of about 260 Ma. The clustering in ages for a variety of uranium deposits at about the age of the lower part of the Chinle Formation (Late Triassic) suggests that uranium in these deposits may have been derived by leaching from volcanic ash in the Chinle and mobilized by ground-water movement. Pb isotope ratios of galenas in mineralized pipes are more radiogenic than those of sulfides from either uranium-poor pipes or occurrences away from pipes. Fluids which passed through the pipes had interacted with the Proterozoic basement, possibly through the vertical fractures which influenced the location and evolution of the pipes themselves. -from Authors

  11. U-Pb zircon geochronology and evolution of some Adirondack meta-igneous rocks (United States)

    Mclelland, J. M.


    An update was presented of the recent U-Pb isotope geochronology and models for evolution of some of the meta-igneous rocks of the Adirondacks, New York. Uranium-lead zircon data from charnockites and mangerites and on baddeleyite from anorthosite suggest that the emplacement of these rocks into a stable crust took place in the range 1160 to 1130 Ma. Granulite facies metamorphism was approximately 1050 Ma as indicated by metamorphic zircon and sphene ages of the anorthosite and by development of magmatitic alaskitic gneiss. The concentric isotherms that are observed in this area are due to later doming. However, an older contact metamorphic aureole associated with anorthosite intrusion is observed where wollastonite develops in metacarbonates. Zenoliths found in the anorthosite indicate a metamorphic event prior to anorthosite emplacement. The most probable mechanism for anorthosite genesis is thought to be ponding of gabbroic magmas at the Moho. The emplacement of the anorogenic anorthosite-mangerite-charnockite suite was apparently bracketed by compressional orogenies.

  12. U-Pb systematics in iron meteorites: uniformity of primordial lead

    International Nuclear Information System (INIS)

    Goepel, C.; Manhes, G.; Allegre, C.J.


    Pb isotopic compositions and U-Pb abundances were determined in the metal phase of six iron meteorites: Canyon Diablo IA, Toluca IA, Odessa IA, Youndegin IA, Deport IA and Mundrabilla An. Prior to complete dissolution, samples were subjected to a series of leachings and partial dissolutions. Isotopic compositions and abundances of the etched Pb indicate a contamination by terrestrial Pb which is attributable to previous cutting of the meteorite. Pb isotopic compositions measured in the decontaminated samples are identical within 0.2% and essentially confirm the primordial Pb value defined by Tatsumoto et al. (1973). These data invalidate more radiogenic Pb isotopic compositions published for iron meteorites, which are the result of terrestrial Pb contamination introduced mainly by analytical procedure. Our results support the idea of a solar nebula which was isotopically homogeneous for Pb 4.55 Ga ago. The new upper limit for U-abundance in iron meteorites, 0.001 ppb, is in agreement with its expected thermodynamic solubility in the metal phase. (author)

  13. U-Pb zircon geochronology in the western part of the Rayner Complex, East Antarctica

    International Nuclear Information System (INIS)

    Horie, Kenji; Hokada, Tomokazu; Motoyoshi, Yoichi; Shiraishi, Kazuyuki; Takehara, Mami; Hiroi, Yoshikuni


    U-Pb zircon geochronology was applied to nine metasedimentary samples collected from Mt. Yuzhnaya, Condon Hills, and Mt. Lira in the inland region of the Rayner Complex of western Enderby Land, East Antarctica, in order to define the eastern limits of the western Rayner Complex that underwent the Pan-African metamorphism and to evaluate potential source areas of metasedimentary rocks. Condon Hills and Mt. Lira revealed metamorphic ages of ∼ 894 and ∼ 934 Ma, respectively, which are consistent with previously reported metamorphism in association with Rayner Structural Episode (RSE). Mt. Yuzhnaya samples affected by the RSE contain zircon grains rejuvenated during 590-570 Ma, which indicates that the Pan-African reworking can be extended up to Mt. Yuzhnaya. On the other hand, the Condon Hills samples include Archean detritus, and the age peaks from 3850 to 2491 Ma are the oldest components in the Rayner Complex of western Enderby Land. There is no evidence of reworked Napier Complex rocks in the studied Rayner samples. (author)

  14. U-Pb systematics in iron meteorites - Uniformity of primordial lead (United States)

    Gopel, C.; Manhes, G.; Allegre, C. J.


    Pb isotopic compositions and U-Pb abundances were determined in the metal phase of six iron meteorites: Canyon Diablo IA, Toluca IA, Odessa IA, Youndegin IA, Deport IA, and Mundrabilla An. Prior to complete dissolution, samples were subjected to a series of leachings and partial dissolutions. Isotopic compositions and abundances of the etched Pb indicate a contamination by terrestrial Pb which is attributable to previous cutting of the meteorite. Pb isotopic compositions measured in the decontaminated samples are identical within 0.2 percent and essentially confirm the primordial Pb value defined by Tatsumoto et al. (1973). These data invalidate more radiogenic Pb isotopic compositions published for iron meteorites, which are the result of terrestrial Pb contamination introduced mainly by analytical procedure. The results of this study support the idea of a solar nebula which was isotopically homogeneous for Pb 4.55 Ga ago. The new upper limit for U-abundance in iron meteorites, 0.001 ppb, is in agreement with its expected thermodynamic solubility in the metal phase.

  15. The history of a continent from U-Pb ages of zircons from Orinoco River sand and Sm-Nd isotopes in Orinoco basin river sediments (United States)

    Goldstein, S.L.; Arndt, N.T.; Stallard, R.F.


    We report SHRIMP U-Pb ages of 49 zircons from a sand sample from the lower Orinoco River, Venezuela, and Nd model ages of the fine sediment load from the main river and tributaries. The U-Pb ages reflect individual magmatic or metamorphic events, the Sm-Nd model ages reflect average crustal-residence ages of the sediment sources. Together they allow delineation of the crust-formation history of the basement precursors of the sediments. The U-Pb ages range from 2.83 to 0.15 Ga, and most are concordant or nearly so. Discrete age groupings occur at ??? 2.8, ??? 2.1, and ??? 1.1 Ga. The oldest group contains only three samples but is isolated from its closest neighbors by a ??? 600 Ma age gap. Larger age groupings at ??? 2.1 and ??? 1.1 Ga make up about a third and a quarter of the total number of analyses, respectively. The remaining analyses scatter along concordia, and most are younger than 1.6 Ga. The ??? 2.8 and ??? 2.1 Ga ages correspond to periods of crust formation of the Imataca and Trans-Amazonian provinces of the Guyana Shield, respectively, and record intervals of short but intensive continental growth. These ages coincide with ??? 2.9 and ??? 2.1 Ga Nd model ages of sediments from tributaries draining the Archean and Proterozoic provinces of the Guyana Shield, respectively, indicating that the U-Pb ages record the geological history of the crystalline basement of the Orinoco basin. Zircons with ages corresponding to the major orogenies of the North Atlantic continents (the Superior at ??? 2.7 Ga and Hudsonian at 1.7-1.9 Ga) were not found in the Orinoco sample. The age distribution may indicate that South and North America were separated throughout their history. Nd model ages of sediments from the lower Orinoco River and Andean tributaries are ??? 1.9 Ga, broadly within the range displayed by major rivers and dusts. This age does not coincide with known thermal events in the region and reflects mixing of sources with different crust-formation ages. The

  16. U-Pb detrital zircon ages from the Paleozoic Marbella Conglomerate of the Malaguide Complex (Betic Cordilleras, Spain). Implications on Paleotethyan evolution (United States)

    Esteban, J. J.; Cuevas, J.; Tubía, J. M.; Gutiérrez-Alonso, G.; Larionov, A.; Sergeev, S.; Hofmann, M.


    The Marbella Conglomerate (Betic Cordilleras, SW Spain) is a poorly sorted and polymictic rock of vaguely constrained Late Carboniferous age interlayered within a sandy sequence. It contains variable amounts of pebbles of quartzite, gneiss, deformed granitoid, schist, aplite, dacite and other volcanic rocks among others, which makes it a potential target for detrital zircon provenance studies. In order to decipher provenance we combined U-Pb SHRIMP and LA-ICP-MS analyses on zircons obtained from single pebbles of deformed rocks (schist, granitoids) and detrital zircons from the sandy sequence, respectively. The age spectra of the detrital zircons indicates that at least the sedimentation took place soon after the start of the Permian according to the youngest detrital zircon age (≈ 286 Ma), and it involved the denudation of terranes with rocks bearing Paleoproterozoic, Neoproterozoic, Cambro-Ordovician, Devonian and Carboniferous zircon age clusters. In contrast with the Permian age of the detrital zircons from the sandstones, igneous (ca. 532 and 516 Ma) and metamorphic (ca. 356 Ma) U-Pb SHRIMP Concordia ages were obtained from the pebbles. The different age clusters observed could be correlated to igneous, metamorphic and detrital rocks from an already eroded terrane similar to the Ossa-Morena Zone of the Iberian Variscan Belt. Therefore, we propose that most of the sedimentation of the Marbella Conglomerate took place along the western border of the Paleotethys at the north margin of Gondwana during the dismantling of the Variscan orogenic edifice and/or the Neotethys ocean opening and the birth of the Cimmerian ribbon continent.

  17. Using the U-Pb system of calcretes to date the time of sedimentation of clastic sedimentary rocks (United States)

    Wang, Z. S.; Rasbury, E. T.; Hanson, G. N.; Meyers, W. J.


    The time of sedimentation of rapidly deposited clastic sedimentary rocks in fluvial environments may be directly dated with an uncertainty of less than three million years using U-Pb dating of pure micritic calcite from calcretes developed in overbank deposits. This conclusion is based on results obtained for calcretes (soil calcite, caliche) formed in the late Triassic New Haven Arkose, Hartford Basin, Connecticut, USA. The paragenesis of calcrete samples from the New Haven Arkose was determined using plane-polarized light and cathodoluminesence petrography, uranium fission track analysis, as well as trace element and stable isotope geochemistry. These calcretes contain an abundance of paleosol microfabrics and diagenetic calcite. The first-generation micritic calcite and second-generation blocky calcite have characteristics consistent with soil calcite. The third generation blocky calcite is a later diagenetic calcite (post-soil calcite). The U-Pb data for pure micritic calcite (first generation) in a horizontal sheet calcrete in sedimentary rocks of Norian age gives a 238U/ 207Pb- 206Pb/ 207Pb isochron age of 211.9 ± 2.1 Ma (2-sigma, and used hereafter for all ages). This age and the stratigraphic position for this sample are in excellent agreement with the ages proposed by Gradstein et al. (1994) for the Norian/Rhaetian boundary of 209.6 ± 4.1 Ma and the Carnian/Norian boundary of 220.7 ± 4.4 Ma. The U-Pb data for two samples of first generation micrite in rhizoliths with about 15% insoluble residues give "ages" of 7 ± 66 Ma and 20 ± 36 Ma. These results suggest that relatively recent events disturbed the U-Pb system of these detrital rich samples, perhaps due to redistribution of U during weathering or during chemical dissolution for analysis. The U-Pb data for a sample of pure third generation blocky calcite cement in a rhizolith yields a 206Pb/ 238U- 207Pb/ 235U isochron age of 81 ± 11 Ma. This age suggests that this sample of third generation blocky

  18. Coupled in situ Ammonium and Nitrate analyses of a tidally dominated estuary: New developments from the Elkhorn Slough Land/Ocean Biogeochemical Observatory network (United States)

    Gibson, P. J.; Plant, J.; Johnson, K. S.


    For nearly nine years the Elkhorn Slough Land/Ocean Biogeochemical Observatory (LOBO) network of moorings has been delivering freely available hourly data to the web in near real time. Each mooring hosts a suite of instruments including an ISUS nitrate sensor. In addition to providing valuable information on ecosystem scale processes, the moorings serve as ideal test platforms for novel in situ chemical sensors & analyzers developed by the Monterey Bay Aquarium Research Institute. The recent addition of a newly developed in situ NH4+ analyzer, the DigiScan-II, has provided additional insights into N cycling mechanisms within the slough. The analysis method estimates NH4+ concentration via base conversion to NH3 gas and diffusion across a membrane into an acid carrier stream with subsequent conductivity detection. Although this new NH4+ analyzer is reagent based, it was developed to be relatively cheap, robust, and configurable for a range of deployment options and requires minimal, infrequent maintenance that is ultimately governed by battery life. The fundamental DigiScan-II platform can also be used for other analyses of interest, such as PO4 or CT (total inorganic carbon), by swapping the necessary reagents and components and by making minor code modifications. For deployment in Elkhorn Slough, the NH4+ DigiScan-II was configured for mid-scale concentration detection with a linear calibration range of 30.0 μM NH4+. The flux of different forms of bioavailable DIN through the system is driven by runoff inputs, tidal exchange, and biological processing. Large inputs of NO3- are sourced from the agriculturally influenced Old Salinas River (OSR), which enters the Slough near the estuary mouth and confluence with Monterey Bay. Rising ocean tides force this eutrophied water mass up into the slough where it is accessed by various biological communities during the course of the tidal period. Mass balance estimates suggest there is an imbalance between the amount of NO3

  19. New Sm/Nd and U/Pb geochronological constraints of the Archean to neoproterozoic evolution of the Amparo basement complex of the Central Ribeira Belt, Southeastern Brazil

    International Nuclear Information System (INIS)

    Fetter, A.H.; Hackspacher, P.C.; Ebbert, H.D; Dantas, E.L; Costa, A.C.D. da


    genesis. U/Pb zircon results obtained from other tonalitic to granodioritic orthogneisses collected to the east and south of this Archean core (Figure 1) suggest that subsequent growth around it may have occurred in two additional phases during the Paleoproterozoic; at around 2.23 and 2.14 Ga. The Nd data from these younger gneisses yield T(DM) ages ranging from 2.25 to 3.28 Ga indicating that the two events involved both significant contributions from Archean sources as well as juvenile, presumably accretionary, growth. The entire basement complex later suffered intense deformation during the Neoproterozoic assembly of West Gondwana, as a strong NE-SW tectonic fabric can be observed in the Archean as well as the younger lithologies that constitute the Ribeira Belt. Analyses of metamorphic monazite obtained from the basement rocks, dated at 609 +/- 2 Ma, provide a precise age as to the timing of this final tectonothermal event (au)

  20. Reassessment of the geologic evolution of selected precambrian terranes in Brazil, based on SHRIMP U-Pb data, part 2: mineiro and Aracuai orogens and Southern Sao Francisco craton; Reavaliacao da evolucao geologica em terrenos pre-cambrianos brasileiros com base em novos dados U-Pb SHRIMP, parte 2: orogeno Aracuai, cinturao mineiro e craton Sao Francisco Meridional

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Luiz Carlos da; Pimentel, Marcio [Brasilia Univ., DF (Brazil). Inst. de Geociencias]. E-mail:; Leite, Carlos Augusto; Vieira, Valter Salino; Silva, Marcio Antonio da; Paes, Vinicius Jose de Castro; Cardoso Filho, Joao Moraes [Companhia de Pesquisas de Recursos Minerais (CPRM), Belo Horizonte, MG (Brazil); Armstrong, Richard [Australian National Univ., Canberra (Australia). Research School of Earth Sciences; Noce, Carlos Mauricio; Pedrosa-Soares, Antonio Carlos [Minas Gerais Univ., Belo Horizonte (Brazil). Inst. de Geociencias. Centro de Pesquisa Manuel Teixeira da Costa; Carneiro, Mauricio Antonio [Ouro Preto Univ., MG (Brazil). Dept. de Geologia


    This paper discusses new zircon SHRIMP (Sensitive High Resolution Ion Microprobe) U-Pb geochronological data for 19 key-exposures of several geological units exposed at the eastern border of the Southern Sao Francisco Craton and at the adjacent Proterozoic Mineiro and Aracuai orogens. Samples were collected along several E-W tran sects, aiming at tracing the precise limit of the Sao Francisco Craton Archean basement, as well as assessing the extension of the successive proterozoic orogenic collages. Due to the complex geologic history and/or high grade metamorphism which most of the rock units investigated have undergone, zircon morphology and the U-Pb analytical data exhibit very complex patterns. These are characterized by a combination of inheritance, partial resetting and new zircon growth during high-grade metamorphism. As a consequence, very careful and detailed analyses of cathodoluminescence imagery were required to allow distinction between inheritance, newly melt-precipitated zircon and partially reset zircons, as well as between the ages of magmatic and metamorphic events. In the southeastern border of the craton 5 units yielded Archean crystallization ages ranging from ca. 3000-2700 Ma, with poorly constrained metamorphic ages ranging from ca. 2850 to 550 Ma. The TTG gneissic complex exposed to the east and south of the Quadrilatero Ferrifero, formerly ascribed to the Archean basement, have crystallization ages from ca. 2210 Ma to 2050 Ma, and can now be interpreted as representing pre- to syn-collisional magmatic phases of the Mineiro Belt. Metamorphic ages of ca. 2100 Ma and 560 Ma are also well constrained in zircon populations from these gneisses. The crystallization age of ca 1740 Ma observed for an alkaline granite of the Borrachudos Suite (intrusive into the Archean basement east of the Southern Espinhaco Range) confirmed previous conventional U-Pb data for this Paleoproterozoic rift-related magmatism. One of the major basement inliers within the

  1. Coordinated U-Pb geochronology, trace element, Ti-in-zircon thermometry and microstructural analysis of Apollo zircons (United States)

    Crow, Carolyn A.; McKeegan, Kevin D.; Moser, Desmond E.


    We present the results of a coordinated SIMS U-Pb, trace element, Ti-in-zircon thermometry, and microstructural study of 155 lunar zircons separated from Apollo 14, 15, and 17 breccia and soil samples that help resolve discrepancies between the zircon data, the lunar whole rock history and lunar magma ocean crystallization models. The majority of lunar grains are detrital fragments, some nearly 1 mm in length, of large parent crystals suggesting that they crystallized in highly enriched KREEP magmas. The zircon age distributions for all three landing sites exhibit an abundance of ages at ∼4.33 Ga, however they differ in that only Apollo 14 samples have a population of zircons with ages between 4.1 and 3.9 Ga. These younger grains comprise only 10% of all dated lunar zircons and are usually small and highly shocked making them more susceptible to Pb-loss. These observations suggest that the majority of zircons crystallized before 4.1 Ga and that KREEP magmatism had predominantly ceased by this time. We also observed that trace element analyses are easily affected by contributions from inclusions (typically injected impact melt) within SIMS analyses spots. After filtering for these effects, rare-earth element (REE) abundances of pristine zircon are consistent with one pattern characterized by a negative Eu anomaly and no positive Ce anomaly, implying that the zircons formed in a reducing environment. This inference is consistent with crystallization temperatures based on measured Ti concentrations and new estimates of oxide activities which imply temperatures ranging between 958 ± 57 and 1321 ± 100 °C, suggesting that zircon parent magmas were anhydrous. Together, the lunar zircon ages and trace elements are consistent with a ⩽300 My duration of KREEP magmatism under anhydrous, reducing conditions. We also report two granular texture zircons that contain baddeleyite cores, which both yield 207Pb-206Pb ages of 4.33 Ga. These grains are our best constraints on

  2. Direct U-Pb dating of Cretaceous and Paleocene dinosaur bones, San Juan Basin, New Mexico: COMMENT (United States)

    Koenig, Alan E.; Lucas, Spencer G.; Neymark, Leonid A.; Heckert, Andrew B.; Sullivan, Robert M.; Jasinski, Steven E.; Fowler, Denver W.


    Based on U-Pb dating of two dinosaur bones from the San Juan Basin of New Mexico (United States), Fassett et al. (2011) claim to provide the first successful direct dating of fossil bones and to establish the presence of Paleocene dinosaurs. Fassett et al. ignore previously published work that directly questions their stratigraphic interpretations (Lucas et al., 2009), and fail to provide sufficient descriptions of instrumental, geochronological, and statistical treatments of the data to allow evaluation of the potentially complex diagenetic and recrystallization history of bone. These shortcomings lead us to question the validity of the U-Pb dates published by Fassett et al. and their conclusions regarding the existence of Paleocene dinosaurs.

  3. In situ (United States)

    Tremsin, Anton S; Makowska, Małgorzata G; Perrodin, Didier; Shalapska, Tetiana; Khodyuk, Ivan V; Trtik, Pavel; Boillat, Pierre; Vogel, Sven C; Losko, Adrian S; Strobl, Markus; Kuhn, L Theil; Bizarri, Gregory A; Bourret-Courchesne, Edith D


    Neutrons are known to be unique probes in situations where other types of radiation fail to penetrate samples and their surrounding structures. In this paper it is demonstrated how thermal and cold neutron radiography can provide time-resolved imaging of materials while they are being processed ( e.g. while growing single crystals). The processing equipment, in this case furnaces, and the scintillator materials are opaque to conventional X-ray interrogation techniques. The distribution of the europium activator within a BaBrCl:Eu scintillator (0.1 and 0.5% nominal doping concentrations per mole) is studied in situ during the melting and solidification processes with a temporal resolution of 5-7 s. The strong tendency of the Eu dopant to segregate during the solidification process is observed in repeated cycles, with Eu forming clusters on multiple length scales (only for clusters larger than ∼50 µm, as limited by the resolution of the present experiments). It is also demonstrated that the dopant concentration can be quantified even for very low concentration levels (∼0.1%) in 10 mm thick samples. The interface between the solid and liquid phases can also be imaged, provided there is a sufficient change in concentration of one of the elements with a sufficient neutron attenuation cross section. Tomographic imaging of the BaBrCl:0.1%Eu sample reveals a strong correlation between crystal fractures and Eu-deficient clusters. The results of these experiments demonstrate the unique capabilities of neutron imaging for in situ diagnostics and the optimization of crystal-growth procedures.

  4. Methods Development for In Situ Laser-Ablation Pb and Sr Isotopic Analyses Using a Double-Focusing Single-Collector ICPMS (United States)

    Pietruszka, A. J.; Neymark, L. A.


    Laser-ablation (LA) ICPMS isotopic analyses of Pb and Sr in geological materials have mostly used multi-collector instruments equipped with Faraday-type detectors (e.g., [1-3]). The main limitation of this approach is that samples with relatively high concentrations of Pb and Sr are typically required. Here we present the development of analytical methods for the accurate and precise in situ measurement of Pb and Sr isotope ratios in relatively low-concentration samples using a laser ablation system (193-nm excimer laser) with a double-focusing single-collector (SC) ICPMS (Nu AttoMTM). Our methods build on published techniques [4-6] that used different LA-SC-ICPMS instrumentation to demonstrate the benefits of fast-scanning ion-counting measurements combined with flat-top peaks. We have paid special attention to the characterization and correction of instrumental artifacts using solutions of the NIST SRM981 Pb and SRM987 Sr standards in "wet plasma" mode. For Pb, this includes correcting for the interference of 204Hg on 204Pb, characterizing the effects of tails from thallium (at masses 203 and 205) on the Pb peaks, evaluating the stability of the instrumental mass bias, and maintaining linearity of the detector response over the full dynamic range. For Sr, this includes correcting for the interference of 86Kr on 86Sr and 87Rb on 87Sr, verifying the accuracy of an internal correction for instrumental mass bias, and calibrating the ion optics scanning parameters. LA-SC-ICPMS results for Pb and Sr isotopic measurements of international glass standards and newly developed in-house mineral and glass reference materials will be presented. [1] Davidson et al. (2001) EPSL 184, 427-442. [2] Ramos et al. (2004) Chem. Geol. 211, 135-158. [3] Simon et al. (2007) GCA 71, 2014-2035. [4] Jochum et al. (2005) IJMS 242, 281-289. [5] Jochum et al. (2006) JAAS 21, 666-675. [6] Jochum et al. (2009) JAAS 24, 1237-1243.

  5. Clinical benefit, complication patterns and cost effectiveness of laser in situ keratomileusis (LASIK) in moderate myopia: results of independent meta analyses on clinical outcome and postoperative complication profiles. (United States)

    Lamparter, J; Dick, H B; Krummenauer, Frank


    Laser in situ keratomileusis (LASIK) means a patient investment of 2426 Euro per eye, which usually cannot be funded by European health care insurers. In the context of recent resource allocation discussions, however, the cost effectiveness of LASIK could become an important indication of allocation decisions. Therefore an evidence based estimation of its incremental cost effectiveness was intended. Three independent meta analyses were implemented to estimate the refractive gain (dpt) due to conventional LASIK procedures as well as the predictability of the latter (%) (fraction of eyes achieving a postoperative refraction with maximum deviation of +/- 0.5 dpt from the target refraction). Study reports of 1995 - 2004 (English or German language) were screened for appropriate key words. Meta effects in refractive gain and predictability were estimated by means and standard deviations of reported effect measures. Cost data were estimated by German DRG rates and individual clinical pathway calculations; cost effectiveness was then computed in terms of the incremental cost effectiveness ratio (ICER) for both clinical benefit endpoints. A sensitivity analysis comprised cost variations of +/- 10 % and utility variations alongside the meta effects' 95% confidence intervals. Total direct costs from the patients' perspective were estimated at 2426 Euro per eye, associated with a refractive meta benefit of 5.93 dpt (95% meta confidence interval 5.32 - 6.54 dpt) and a meta predictability of 67% (43% - 91%). In terms of incremental costs, the unilateral LASIK implied a patient investion of 409 Euro (sensitivity range 351 - 473 Euro) per gained refractive unit or 36 Euro (27 - 56 Euro) per gained percentage point in predictability. When LASIK associated complication patterns were considered, the total direct costs amounted up to 3075 Euro, resulting in incremental costs of 519 Euro / dpt (sensitivity range 445 - 600 Euro / dpt) or 46 Euro / % (34 - 72 Euro / %). Most frequently

  6. Plešovice zircon -- a new natural reference material for U-Pb and Hf isotopic microanalysis

    Czech Academy of Sciences Publication Activity Database

    Sláma, Jiří; Košler, J.; Condon, D. J.; Crowley, J. L.; Gerdes, A.; Hanchar, J. M.; Horstwood, M. S. A.; Morris, G. A.; Nasdala, L.; Norberg, N.; Schaltegger, U.; Schoene, B.; Tubrett, M. N.; Whitehouse, M. J.


    Roč. 249, 1-2 (2008), s. 1-35 ISSN 0009-2541 Grant - others:GA ČR(CZ) GA205/05/0381 Institutional research plan: CEZ:AV0Z30130516 Keywords : zircon reference material * lase ablation ICP-MS * U-Pb dating * Hf isotopes * Plešovice, Bohemian Massif Subject RIV: DD - Geochemistry Impact factor: 3.531, year: 2008

  7. Detrital zircon U-Pb reconnaissance of the Franciscan subduction complex in northwestern California (United States)

    Dimitru, Trevor; Ernst, W. Gary; Hourigan, Jeremy K.; McLaughlin, Robert J.


    In northwestern California, the Franciscan subduction complex has been subdivided into seven major tectonostratigraphic units. We report U-Pb ages of ≈2400 detrital zircon grains from 26 sandstone samples from 5 of these units. Here, we tabulate each unit's interpreted predominant sediment source areas and depositional age range, ordered from the oldest to the youngest unit. (1) Yolla Bolly terrane: nearby Sierra Nevada batholith (SNB); ca. 118 to 98 Ma. Rare fossils had indicated that this unit was mostly 151-137 Ma, but it is mostly much younger. (2) Central Belt: SND; ca. 103 too 53 Ma (but poorly constrained), again mostly younger than previously thought. (3) Yager terrane: distant Idaho batholith (IB); ca. 52 to 50 Ma. Much of the Yager's detritus was shed during major core complex extension and erosion in Idaho that started 53 Ma. An eocene Princeton River-Princeton submarine canyon system transported this detritus to the Great Valley forearc basin and thence to the Franciscan trench. (4) Coastal terrane: mostly IB, ±SNB, ±nearby Cascade arc, ±Nevada Cenozoic ignimbrite belt; 52 to zircons; parts 16-14 Ma based on microfossils. Overall, some Franciscan units are younger than previously thought, making them more compatible with models for the growth of subduction complexes by positive accretion. From ca. 118 to 70 Ma, Franciscan sediments were sourced mainly from the nearby Sierra Nevada region and were isolated from southwestern US and Mexican sources. From 53 to 49 Ma, the Franciscan was sourced from both Idaho and the Sierra Nevada. By 37-32 Ma, input from Idaho had ceased. The influx from Idaho probably reflects major tectonism in Idaho, Oregon, and Washington, plus development of a through-going Princeton River to California, rather than radical changes in the subduction system at the Franciscan trench itself.

  8. Thermal and exhumation history of Sakhalin Island (Russia) constrained by apatite U-Pb and fission track thermochronology (United States)

    Glorie, Stijn; Alexandrov, Igor; Nixon, Angus; Jepson, Gilby; Gillespie, Jack; Jahn, Bor-Ming


    Sakhalin Island represents a key locality to study the tectonic evolution of the western Pacific. The island is located at the Amur-Okhotsk plate margin and records a complex thermotectonic history. Apatite double dating (U-Pb and fission track) and thermal history modelling were applied to three late Eocene granitoid massifs within central and southern Sakhalin: the Aniva, Okhotsk and Langeri complexes. Apatite U-Pb results yield consistent late Eocene (∼40-37 Ma) ages, suggesting rapid post-magmatic cooling. Apatite fission track results reveal bimodal age distributions with late Eocene - early Oligocene (∼38-33 Ma) and early Miocene (∼20-17 Ma) age populations that can be correlated with variations in Uranium and Chlorine concentrations. Thermal history modelling translates the AFT age bimodality into two-phase cooling histories. The timing of the early cooling phase (∼38-33 Ma) corresponds with the apatite U-Pb ages, indicating rapid cooling to at least ∼100 °C during the late Oligocene. The second cooling phase at ∼20-17 Ma cooled the samples to near-surface temperatures. Both cooling phases correspond with regional unconformities and subsequent accelerations in sedimentation rate, suggesting that cooling was a response to rapid exhumation. In addition, our data suggests that the studied terranes record differential exhumation with respect to the structural architecture. The Miocene exhumation pulse is coeval with the timing of transpressional fault displacement and the subsequent opening of the Kuril Basin.

  9. Constraints on the timing of Co-Cu ± Au mineralization in the Blackbird district, Idaho, using SHRIMP U-Pb ages of monazite and xenotime plus zircon ages of related Mesoproterozoic orthogneisses and metasedimentary rocks (United States)

    Aleinikoff, John N.; Slack, John F.; Lund, Karen; Evans, Karl V.; Fanning, C. Mark; Mazdab, Frank K.; Wooden, Joseph L.; Pillers, Renee M.


    The Blackbird district, east-central Idaho, contains the largest known Co reserves in the United States. The origin of strata-hosted Co-Cu ± Au mineralization at Blackbird has been a matter of controversy for decades. In order to differentiate among possible genetic models for the deposits, including various combinations of volcanic, sedimentary, magmatic, and metamorphic processes, we used U-Pb geochronology of xenotime, monazite, and zircon to establish time constraints for ore formation. New age data reported here were obtained using sensitive high resolution ion microprobe (SHRIMP) microanalysis of (1) detrital zircons from a sample of Mesoproterozoic siliciclastic metasedimentary country rock in the Blackbird district, (2) igneous zircons from Mesoproterozoic intrusions, and (3) xenotime and monazite from the Merle and Sunshine prospects at Blackbird. Detrital zircon from metasandstone of the biotite phyllite-schist unit has ages mostly in the range of 1900 to 1600 Ma, plus a few Neoarchean and Paleoproterozoic grains. Age data for the six youngest grains form a coherent group at 1409 ± 10 Ma, regarded as the maximum age of deposition of metasedimentary country rocks of the central structural domain. Igneous zircons from nine samples of megacrystic granite, granite augen gneiss, and granodiorite augen gneiss that crop out north and east of the Blackbird district yield ages between 1383 ± 4 and 1359 ± 7 Ma. Emplacement of the Big Deer Creek megacrystic granite (1377 ± 4 Ma), structurally juxtaposed with host rocks in the Late Cretaceous ca. 5 km north of Blackbird, may have been involved in initial deposition of rare earth elements (REE) minerals and, possibly, sulfides. In situ SHRIMP ages of xenotime and monazite in Co-rich samples from the Merle and Sunshine prospects, plus backscattered electron imagery and SHRIMP analyses of trace elements, indicate a complex sequence of Mesoproterozoic and Cretaceous events. On the basis of textural relationships

  10. Did the Kiruna iron ores form as a result of a metasomatic or igneous process? New U-Pb and Nd data for the iron oxide apatite ores and their host rocks in the Norrbotten region of northern Sweden (United States)

    Westhues, A.; Hanchar, J. M.; Whitehouse, M. J.; Fisher, C. M.


    A number of iron deposits near Kiruna in the Norrbotten region of northern Sweden are of the iron oxide apatite (IOA) type of deposits; also referred to as Kiruna-type deposits. They are commonly considered a subgroup or end-member of iron oxide copper gold (IOCG) deposits, containing no economic grades of copper or gold. Both IOCG and IOA deposits are characterized by abundant low-Ti Fe oxides, an enrichment in REE, and intense sodium and potassium wall-rock alteration adjacent to the ores. Deposits of these types are of a great economic importance, not only for iron, but also for other elements such as rare earth elements (REE) or uranium. Kiruna, the type locality of the IOA type of mineral deposits, is the focus of this study. Despite a century-long mining history and 2500 Mt of iron ore produced in the region to date (with grades of 30 to 70 wt.% Fe), the genesis of these deposits is poorly understood: theories of a magmatic vs. a hydrothermal or metasomatic origin have been debated, and the timing of mineralization of the ores in the Norbotten region has never been directly dated. The results anticipated from this study will provide a better understanding of the nature of the IOA type of mineral deposits and their relation to IOCG deposits such as Olympic Dam in Australia. An array of geochemical methods is used in order to gain insights on the emplacement history of the host rocks, their subsequent alteration, and the ore genesis of these deposits. This includes in situ U/Pb geochronology of zircon, monazite, and titanite to constrain the timing between host rock emplacement, alteration and mineralization. Isotopic data from whole rocks and in situ at mineral scale will provide constraints on the involvement of hydrothermal fluids and their possible sources, as well as on the sources of Fe, U, and the REE. Newly obtained Sm-Nd isotopic data points to distinct source differences between host rocks, ore and alteration related samples. Preliminary in situ U-Pb

  11. Petrogenesis of Malaysian tin granites: geochemistry, fractional crystallization, U-Pb zircon geochronology and tectonic setting (United States)

    Wai-Pan Ng, Samuel; Searle, Mike; Whitehouse, Martin; Chung, Sun-Lin; Ghani, Azman; Robb, Laurence; Sone, Masatoshi; Oliver, Grahame; Gardiner, Nick; Roselee, Mohammad


    The Malaysian tin granites forming the backbone of the Thai-Malay Peninsula has been long recognized with two distinct granitic provinces:- 1. Early Permian to Late Triassic Eastern Province with mainly "I-type" (Hbl)-Bt granites with associated Cu-Au deposits, with subordinate Bt granites hosting limited Sn-W deposits, and 2. Late Triassic Main Range Province with mainly "S-type" Bt granites with associated Sn-W deposits, and subordinate (Hbl)-Bt granites. New geochemical data show that Chappell and White's (1974) I-S granite classification adopted in the existing model does not adequately distinguish the granites from one another as previously implied. Trace element geochemistry and Sr-Nd isotopic compositions show that the Malaysian tin granites in both provinces have transitional I-S characteristics. In addition, they inherited within-plate signature from Cambro-Ordovician Gondwana-related source rocks. Previous ages were obtained by whole rock Rb-Sr and biotite K-Ar geochronology in the 70s and 80s, dating methods that may not accurately represent the crystallization age of granites. We re-sampled the entire Malaysian Peninsula and 40 samples were collected for high-precision U-Pb SIMS dating on extracted zircon grains in order to better constrain the magmatic and tectonic evolution of Southeast Asia. The crystallization ages of the Eastern Province granitoids have been constrained ranging from 220 to 290 Ma, while the Main Range (Western) Province granitoids have ages ranging from 200 to 230 Ma. A progressive westward younging trend is apparent across the Eastern Province, but becomes less obvious in the Main Range Province. Our model suggests two east dipping subduction zones. We suggest that subduction roll-back along the Bentong-Raub suture might account for the westward younging trend, in the Eastern province. A second Late Triassic east-dipping subduction zone beneath western Malaysia is proposed in order to explain the "I-type" components to the Main

  12. In situ (United States)

    Chamlagain, Bhawani; Sugito, Tessa A; Deptula, Paulina; Edelmann, Minnamari; Kariluoto, Susanna; Varmanen, Pekka; Piironen, Vieno


    The in situ production of active vitamin B12 was investigated in aqueous cereal-based matrices with three strains of food-grade Propionibacterium freudenreichii . Matrices prepared from malted barley flour (33% w/v; BM), barley flour (6%; BF), and wheat aleurone (15%; AM) were fermented. The effect of cobalt and the lower ligand 5,6-dimethylbenzimidazole (DMBI) or its natural precursors (riboflavin and nicotinamide) on active B12 production was evaluated. Active B12 production was confirmed by UHPLC-UV-MS analysis. A B12 content of 12-37 μg·kg -1 was produced in BM; this content increased 10-fold with cobalt and reached 940-1,480 μg·kg -1 with both cobalt and DMBI. With riboflavin and nicotinamide, B12 production in cobalt-supplemented BM increased to 712 μg·kg -1 . Approximately, 10 μg·kg -1 was achieved in BF and AM and was increased to 80 μg·kg -1 in BF and 260 μg·kg -1 in AM with cobalt and DMBI. The UHPLC and microbiological assay (MBA) results agreed when both cobalt and DMBI or riboflavin and nicotinamide were supplemented. However, MBA gave ca. 20%-40% higher results in BM and AM supplemented with cobalt, indicating the presence of human inactive analogues, such as pseudovitamin B12. This study demonstrates that cereal products can be naturally fortified with active B12 to a nutritionally relevant level by fermenting with P. freudenreichii .

  13. Differential response of U-Pb systems in coexisting accessory minerals, Winnipeg River Subprovince, Canadian Shield: Implications for Archeal crustal growth and stabilization

    International Nuclear Information System (INIS)

    Corfu, F.


    The U-Pb isotopic systems of zircon, monazite, titanite and some apatite and the Pb isotopic composition of K-feldspar have been investigated in three areas of the Winnipeg River Subprovince (WRS) of the Superior Province, Canada, in order to define the timing of magmatic and metamorphic processes in this Archean gneissic-granitoid terrain. U-Pb systematics in the WRS record a complex sequence of igneous, metamorphic and tectonic processes spanning some 700 Ma. (orig.)

  14. Thermomagmatic evolution of Mesoproterozoic crust in the Blue Ridge of SW Virginia and NW North Carolina: Evidence from U-Pb geochronology and zircon geothermometry (United States)

    Tollo, Richard P.; Aleinikoff, John N.; Wooden, Joseph L.; Mazdab, Frank K.; Southworth, Scott; Fanning, Mark C.


    New geologic mapping, petrology, and U-Pb geochronology indicate that Mesoproterozoic crust near Mount Rogers consists of felsic to mafic meta-igneous rocks emplaced over 260 m.y. The oldest rocks are compositionally diverse and migmatitic, whereas younger granitoids are porphyritic to porphyroclastic. Cathodoluminescence imaging indicates that zircon from four representative units preserves textural evidence of multiple episodes of growth, including domains of igneous, metamorphic, and inherited origin. Sensitive high-resolution ion microprobe (SHRIMP) trace-element analyses indicate that metamorphic zircon is characterized by lower Th/U, higher Yb/Gd, and lower overall rare earth element (REE) concentrations than igneous zircon. SHRIMP U-Pb isotopic analyses of zircon define three episodes of magmatism: 1327 ± 7 Ma, 1180–1155 Ma, and 1061 ± 5 Ma. Crustal recycling is recorded by inherited igneous cores of 1.33–1.29 Ga age in 1161 ± 7 Ma meta-monzogranite. Overlapping ages of igneous and metamorphic crystallization indicate that plutons of ca. 1170 and 1060 Ma age were emplaced during episodes of regional heating. Local development of hornblende + plagioclase + quartz ± clinopyroxene indicates that prograde metamorphism at 1170–1145 Ma and 1060–1020 Ma reached upper-amphibolite-facies conditions, with temperatures estimated using Ti-in-zircon geothermometry at ~740 ± 40 °C during both episodes. The chemical composition of 1327 ± 7 Ma orthogranofels from migmatite preserves the first evidence of arc-generated rocks in the Blue Ridge, indicating a subduction-related environment that may have been comparable to similar-age systems in inliers of the Northern Appalachians and the Composite Arc belt of Canada. Granitic magmatism at 1180–1155 Ma and ca. 1060 Ma near Mount Rogers was contemporaneous with anorthosite-mangerite-charnockite-granite (AMCG) plutonism in the Northern Appalachian inliers and Canadian Grenville Province. Metamorphism at ca. 1160

  15. Brittle-ductile deformation effects on zircon crystal-chemistry and U-Pb ages: an example from the Finero Mafic Complex (Ivrea-Verbano Zone, western Alps) (United States)

    Langone, Antonio; José Alberto, Padrón-Navarta; Zanetti, Alberto; Mazzucchelli, Maurizio; Tiepolo, Massimo; Giovanardi, Tommaso; Bonazzi, Mattia


    A detailed structural, geochemical and geochronological survey was performed on zircon grains from a leucocratic dioritic dyke discordantly intruded within meta-diorites/gabbros forming the External Gabbro unit of the Finero Mafic Complex. This latter is nowadays exposed as part of a near complete crustal section spanning from mantle rocks to upper crustal metasediments (Val Cannobina, Ivrea-Verbano Zone, Italy). The leucocratic dyke consists mainly of plagioclase (An18-24Ab79-82Or0.3-0.7) with subordinate amounts of biotite, spinel, zircon and corundum. Both the leucocratic dyke and the surrounding meta-diorites show evidence of ductile deformation occurred under amphibolite-facies conditions. Zircon grains (up to 2 mm in length) occur mainly as euhedral grains surrounded by fine grained plagioclase-dominated matrix and pressure shadows, typically filled by oxides. Fractures and cracks within zircon are common and can be associated with grain displacement or they can be filled by secondary minerals (oxides and chlorite). Cathodoluminescence (CL) images show that zircon grains have internal features typical of magmatic growth, but with local disturbances. However EBSD maps on two selected zircon grains revealed a profuse mosaic texture resulting in an internal misorientation of ca. 10o. The majority of the domains of the mosaic texture are related to parting and fractures, but some domains show no clear relation with brittle features. Rotation angles related to the mosaic texture are not crystallographically controlled. In addition, one of the analysed zircons shows clear evidence of plastic deformation at one of its corners due to indentation. Plastic deformation results in gradual misorientations of up to 12o, which are crystallographically controlled. Trace elements and U-Pb analyses were carried out by LA-ICP-MS directly on petrographic thin sections and designed to cover the entire exposed surface of selected grains. Such investigations revealed a strong

  16. SHRIMP zircon U-Pb age, litho- and biostratigraphic analyses of the Huaiyu Domain in South China.


    Shu , Liangshu S.; Faure , Michel; Jiang , Shaoyong; Yang , Qun; Wang , Yujing


    In the last few decades, the Late Paleozoic–Early Mesozoic tectonic evolution of South China has been quite controversial. The focus of debate is on both the age of ophiolites and the Late Paleozoic–Early Mesozoic geological and geodynamic environment. The Huaiyu Domain is located in the NE part of South China and exposes numerous significant geological features that are keys to understand the tectonics of South China. In this paper, we present some new evidence on stratigraphy, petrology and...

  17. Chemical abrasion-SIMS (CA-SIMS) U-Pb dating of zircon from the late Eocene Caetano caldera, Nevada (United States)

    Watts, Kathryn E.; Coble, Matthew A.; Vazquez, Jorge A.; Henry, Christopher D.; Colgan, Joseph P.; John, David A.


    Zircon geochronology is a critical tool for establishing geologic ages and time scales of processes in the Earth's crust. However, for zircons compromised by open system behavior, achieving robust dates can be difficult. Chemical abrasion (CA) is a routine step prior to thermal ionization mass spectrometry (TIMS) dating of zircon to remove radiation-damaged parts of grains that may have experienced open system behavior and loss of radiogenic Pb. While this technique has been shown to improve the accuracy and precision of TIMS dating, its application to high-spatial resolution dating methods, such as secondary ion mass spectrometry (SIMS), is relatively uncommon. In our efforts to U-Pb date zircons from the late Eocene Caetano caldera by SIMS (SHRIMP-RG: sensitive high resolution ion microprobe, reverse geometry), some grains yielded anomalously young U-Pb ages that implicated Pb-loss and motivated us to investigate with a comparative CA and non-CA dating study. We present CA and non-CA 206Pb/238U ages and trace elements determined by SHRIMP-RG for zircons from three Caetano samples (Caetano Tuff, Redrock Canyon porphyry, and a silicic ring-fracture intrusion) and for R33 and TEMORA-2 reference zircons. We find that non-CA Caetano zircons have weighted mean or bimodal U-Pb ages that are 2–4% younger than CA zircons for the same samples. CA Caetano zircons have mean U-Pb ages that are 0.4–0.6 Myr older than the 40Ar/39Ar sanidine eruption age (34.00 ± 0.03 Ma; error-weighted mean, 2σ), whereas non-CA zircons have ages that are 0.7–1.3 Myr younger. U-Pb ages do not correlate with U (~ 100–800 ppm), Th (~ 50–300 ppm) or any other measured zircon trace elements (Y, Hf, REE), and CA and non-CA Caetano zircons define identical trace element ranges. No statistically significant difference in U-Pb age is observed for CA versus non-CA R33 or TEMORA-2 zircons. Optical profiler measurements of ion microprobe pits demonstrate consistent depths of ~ 1.6

  18. Geochemistry and U-Pb geochronology of detrital zircons in the Brujas beach sands, Campeche, Southwestern Gulf of Mexico, Mexico (United States)

    Tapia-Fernandez, Hector J.; Armstrong-Altrin, John S.; Selvaraj, Kandasamy


    This study investigated the bulk sediment geochemistry, U-Pb ages and rare earth element (REE) geochemistry of one hundred detrital zircons recovered from the Brujas beach sands in southwestern Gulf of Mexico to understand the provenance and age spectra. The bulk sediments are high in Zr and Hf contents (∼1400-3773 ppm and ∼33-90 ppm, respectively) suggested the abundance of resistant mineral zircon. The chondrite normalized REE patterns of the bulk sediments are less fractionated with enriched low REE (LREE; LaCN/SmCN = ∼491-693), depleted heavy REE (HREE; GdCN/YbCN = ∼44-69) and a negative Eu anomaly (Eu/Eu∗ = ∼0.44-0.67) suggested that the source rock is felsic type. The results of this study revealed highly varied contents of Th (∼4.2-321 ppm), U (∼20.7-1680 ppm), and Hf (∼6970-14,200 ppm) in detrital zircons compared to bulk sands. The total REE content (∼75 and 1600 ppm) and its chondrite-normalized pattern with positive Ce and negative Eu anomalies as well as low Th/U ratio of zircon grains indicated that they were dominantly of magmatic origin. U-Pb data of zircons indicated two age populations, with predominance of Permian-Triassic (∼216-286 Ma) and Neoproterozoic (∼551-996 Ma). The Permian-Triassic zircons were contributed by the granitoids and recycled metasedimentary rocks of the Chiapas Massif Complex. The major contribution of Neoproterozoic zircons was from the Chaucus, Oaxacan, and Chiapas Massif Complexes in Grenville Province, southern Mexico. U-Pb ages of zircons from the Brujas beach are consistent to the reported zircon ages from the drainage basins of Usumacinta, Coatzacoalcos, and Grijalva Rivers in southern Mexico, suggesting that the sediments delivered by the rivers to the beach area are vital in defining the provenance of placers.

  19. Significance of zircon U-Pb ages from the Pescadero felsite, west-central California coast ranges (United States)

    McLaughlin, Robert J.; Moore, Diane E.; ,; Martens, UWE C.; Clark, J.C.


    Weathered felsite is associated with the late Campanian–Maastrichtian Pigeon Point Formation near Pescadero, California. Poorly exposed, its age and correlation are uncertain. Is it part of the Pigeon Point section west of the San Gregorio–Hosgri fault? Does it rest on Nacimiento block basement? Is it dextrally offset from the Oligocene Cambria Felsite, ∼185 km to the southeast? Why is a calc-alkaline hypabyssal igneous rock intrusive into the outboard accretionary prism? To address these questions, we analyzed 43 oscillatory-zoned zircon crystals from three incipiently recrystallized pumpellyite ± prehnite ± laumontite-bearing Pescadero felsite samples by sensitive high-resolution ion microprobe–reverse geometry (SHRIMP-RG) and laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) techniques. Thirty-three zircons gave late Mesozoic U-Pb ages, with single-grain values ranging from 81 to 167 Ma; ten have pre-Mesozoic, chiefly Proterozoic ages. A group of the four youngest Pescadero zircons yielded an apparent maximum igneous age of ca. 86–90 Ma. Reflecting broad age scatter and presence of partly digested sandstone inclusions, we interpret the rest of the zircons (perhaps all) as xenocrysts. Twenty-three zircons were separated and analyzed from two samples of the similar Cambria Felsite, yielding a unimodal 27 Ma U-Pb age. Clearly, the origin of the Upper Oligocene Cambria Felsite is different from that of the Upper Cretaceous Pescadero felsite; these rocks are not correlated, and do not constrain displacement along the San Gregorio–Hosgri fault. Peak ages differ slightly, but relative probability curves for Mesozoic and pre-Mesozoic Pescadero zircons compare well, for example, with abundant U-Pb age data for detrital zircons from Franciscan metaclastic strata ∼100 km to the east in the Diablo Range–San Francisco Bay area, San Joaquin Great Valley Group turbidites, Upper Cretaceous Nacimiento block Franciscan strata, and Upper

  20. U-Pb isotopic evidence pertaining to the age and genesis of uranium mineralisation in Karoo sediments

    International Nuclear Information System (INIS)

    Allsopp, H.L.; Welke, H.J.; Armstrong, R.A.; Clough, W.; Evans, I.B.


    Preliminary investigations have been carried out, using the uranium-lead isotopic method, on the uranium mineralisation that occurs within the Karoo sediments. Two occurences were studied, namely the lower Beaufort sediments (Adelaide Subgroup) in the Beaufort West area and the Molteno Formation sediments in the Ficksburg area. The objective were to determine the age of the mineralisation and to study the mode of formation of the ores. The pattern of U-Pb apparent ages for all the Karoo samples is 207 Pb/ 206 Pb age >> 207 Pb* 235 U age > 206 Pb* 238 U age

  1. Detrital zircon U-Pb and (U-Th)/He double-dating of Upper Cretaceous-Cenozoic Zagros foreland basin strata in the Kurdistan Region of northern Iraq (United States)

    Barber, D. E.; Stockli, D. F.; Koshnaw, R. I.; Horton, B. K.; Tamar-Agha, M. Y.; Kendall, J. J.


    The NW Zagros orogen is the result of the multistage collisional history associated with Late Cretaceous-Cenozoic convergence of the Arabian and Eurasian continents and final closure of Neotethys. Siliciclastic strata preserved within a ~400 km segment of the NW Zagros fold-thrust belt and foreland basin in the Iraqi Kurdistan Region (IKR) provide a widespread record of exhumation and sedimentation. As a means of assessing NW Zagros foreland basin evolution and chronostratigraphy, we present coupled detrital zircon (DZ) U-Pb and (U-Th)/He geo-thermochronometric data of Upper Cretaceous to Pliocene siliciclastic strata from the Duhok, Erbil, and Suleimaniyah provinces of IKR. LA-ICP-MS U-Pb age analyses reveal that the foreland basin fill in IKR in general was dominantly derived from Pan-African/Arabian-Nubian, Peri-Gondwandan, Eurasian, and Cretaceous volcanic arc terrenes. However, the provenance of these strata varies systematically along strike and through time, with an overall increase in complexity upsection. DZ age distribution of Paleocene-Eocene strata is dominated by a ~95 Ma grain age population, likely sourced from the Late Cretaceous Hassanbag-Bitlis volcanic arc complex along the northern margin of Arabia. In contrast, DZ U-Pb age distributions of Neogene strata show a major contribution derived from various Eurasian (e.g., Iranian, Tauride, Pontide; ~45, 150, 300 Ma) and Pan-African (~550, 950 Ma) sources. The introduction of Eurasian DZ ages at the Paleogene-Neogene transition likely records the onset of Arabian-Eurasian collision. Along strike to the southeast, the DZ U-Pb spectra of Neogene strata show a decreased percentage of Pan-African, Peri-Gondwandan, Tauride, and Ordovician ages, coupled with a dramatic increase in 40-50 Ma DZ ages that correspond to Urumieh-Dokhtar magmatic rocks in Iran. Combined with paleocurrent data, this suggests that Neogene sediments were transported longitudinally southeastward through an unbroken foreland basin

  2. U-Pb Geochronology of non-marine Upper Triassic strata of the Colorado Plateau (western North America): implications for stratigraphic correlation and paleoenvironmental reconstruction (United States)

    Rasmussen, C.; Mundil, R.; Irmis, R. B.; Keller, C. B.; Giesler, D.; Gehrels, G. E.


    The Triassic is a critical period in Earth history that witnessed the origin of modern ecosystems and frequent climate fluctuations, as well as major environmental events such as flood basalt volcanism and bolide impacts. The Chinle Formation contains a primary non-marine archive for past ecosystems in North America due to its fossil richness and well-studied sedimentology. Moreover, within these highly fossiliferous strata, a biotic turnover has been reported that has been hypothesized to coincide with one or more of the aforementioned environmental events. Unfortunately, few radioisotopic ages have been published for the Late Triassic, limiting our ability for lithological and paleoenvironmental correlations. In addition, the superposition of the Chinle Formation remains illusive due to frequent lateral facies changes and discontinuous outcrops across the Colorado Plateau. The 520 m long core 1A of the Colorado Plateau Coring Project from Petrified Forest National Park (PFNP) (Arizona) provides, for the first time, a continuous section of these early Mesozoic sedimentary strata. Many of the sand- and siltstones from this continuous succession throughout most of the Upper Triassic Chinle Formation contain euhedral zircons suitable for U-Pb analyses. We analyzed >300 crystals each from 10 samples using LA-ICPMS; these results indicated abundant Late Triassic crystals that appear to be closely associated with the depositional age of the host rock. We then selected the youngest grains from these samples to obtain precise CA-TIMS U-Pb single zircon ages in order to constrain the maximum depositional ages (using quantitative methods) of these formations. We are able to revise the proposed time scale (based on outcrop samples) for Upper Triassic strata at PFNP and evaluate whether the biotic turnover observed within the Sonsela Member of these strata coincides with the Manicouagan bolide impact event. This revised chronostratigraphic framework allows intercalibration

  3. Arc-continent collision of the Coastal Range in Taiwan: Geochronological constraints from U-Pb ages of zircons (United States)

    Geng, Wei; Zhang, Xun-Hua; Huang, Long


    The oblique arc-continent collision between the Luzon arc and the southeastern margin of the Eurasian continent caused the uplift of Taiwan. The Coastal Range in eastern Taiwan is the northern section of the Luzon arc in the collision zone and thus records important information about the arc-continent collision. In this paper, we determine and analyze the U-Pb ages of magmatic zircons from the volcanic arc and clastic zircons from the fore-arc basin in the Coastal Range. For the volcanic arc in the Coastal Range, the eruption ages range from 16.8-5 Ma. Given that the initial subduction of the South China Sea oceanic crust (17 Ma) occurred before the Luzon arc formed, we conclude that the volcanic activity of the Coastal Range began at 16.8 ± 1.3 Ma; it was most active from 14 to 8 Ma and continued until approximately 5 Ma. The U-Pb chronology also indicates that the initial stage of arc-continent collision of the Coastal Range started at approximately 5 Ma, when the northern section of the Luzon arc moved away from the magmatic chamber because of the kinematics of the Philippine Sea Plate.

  4. U-Pb ages of detrital zircon and provenances of Red Clay in the Chinese Loess Plateau (United States)

    Gong, Hujun; Xie, Wenbin; Zhang, Rui; Zhang, Yunxiang


    The Chinese Loess Plateau (CLP), which is located in the central part of China, mainly contains two sequences: the Quaternary loess-paleosol sequence and the late Miocene-Pliocene Red Clay sequence. U-Pb ages of detrital zircon from the Quaternary loess-paleosol sequences indicate that the current spatial pattern of central Asian aridification was largely established during the early Quaternary. U-Pb ages of detrital zircon from the underlying Red Clay sequences demonstrate that the northern source regions were important contributors for the dust since the late Miocene, except for the periods of ∼8 Ma and ∼5.5 to ∼4 Ma. These two periods correspond to increased and decreased dust deposition in the North Pacific, respectively, ascribed to the late Miocene aridification of the Qaidam Basin (in the west of the CLP) and the early Pliocene aridification of the Tarim Basin (in the west of the CLP). We attribute the increase of the Qaidam Basin-derived North Pacific dust fluxes to the uplift of the NE Tibetan Plateau. Such uplift also controlled the climatic and environmental changes in central Asian during the late Miocene. This study highlights the dynamical process of the central Asian aridification during the late Miocene-Pliocene.

  5. Petrogenesis and U-Pb and Sm-Nd geochronology of the Taquaral granite: record of an orosirian continental magmatic arc in the region of Corumba - MS

    Directory of Open Access Journals (Sweden)

    Letícia Alexandre Redes

    Full Text Available The Taquaral Granite is located on southern Amazon Craton in the region of Corumbá, westernmost part of the Brazilian state of Mato Grosso do Sul (MS, near Brazil-Bolivia frontier. This intrusion of batholitic dimensions is partially covered by sedimentary rocks of the Urucum, Tamengo Bocaina and Pantanal formations and Alluvial Deposits. The rock types are classified as quartz-monzodiorites, granodiorites, quartz-monzonites, monzo and syenogranites. There are two groups of enclaves genetically and compositionally different: one corresponds to mafic xenoliths and the second is identified as felsic microgranular enclave. Two deformation phases are observed: one ductile (F1 and the other brittle (F2. Geochemical data indicate intermediate to acidic composition for these rocks and a medium to high-K, metaluminous to peraluminous calk-alkaline magmatism, suggesting also their emplacement into magmatic arc settings. SHRIMP zircon U-Pb geochronological data of these granites reveals a crystallization age of 1861 ± 5.3 Ma. Whole rock Sm-Nd analyses provided εNd(1,86 Ga values of -1.48 and -1.28 and TDM model ages of 2.32 and 2.25 Ga, likely indicating a Ryacian crustal source. Here we conclude that Taquaral Granite represents a magmatic episode generated at the end of the Orosirian, as a part of the Amoguija Magmatic Arc.

  6. Geochemistry and zircon U-Pb geochronology of the rhyolitic tuff on Port Island, Hong Kong: Implications for early Cretaceous tectonic setting

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    Longlong Zhao


    Full Text Available Early Cretaceous rhyolitic tuffs, widely distributed on Port Island, provide insights into the volcanism and tectonic setting of Hong Kong. In this paper we present petrological, geochronological and geochemical data of the rhyolitic tuff to constrain the diagenesis age and petrogenesis of the rocks, tectonic setting and early Cretaceous volcanism of Hong Kong. The first geochronological data show that the zircons in the volcanic rocks have U-Pb age of 141.1–139.5 Ma, which reveals that the rhyolitic tuff on Port Island was formed in the early Cretaceous (K1. Geochemically, these acid rocks, which are enriched in large ion lithophile elements (LILEs and light rare earth elements (LREEs, and depleted in high field strength elements (HFSEs, belong to the high K calc-alkaline to shoshonite series with strongly-peraluminous characteristic. The geochemical analyses suggest that the volcanic rocks were derived from deep melting in the continental crust caused by basaltic magma underplating. Based on the geochemical analysis and previous studies, we concluded that the rhyolitic tuffs on Port Island were formed in a back-arc extension setting in response to the subduction of the Paleo-Pacific Plate beneath the Eurasian Plate.

  7. U-Pb Ages of Secondary Silica at Yucca Mountain, Nevada: Implications for the Paleohydrology of the Unsaturated Zone

    International Nuclear Information System (INIS)

    L.A. Neymark; Y. Amelin; J.B. Paces; Z.E. Peterman


    U, Th, and Pb isotopes were analyzed in layers of opal and chalcedony from individual millimeter- to centimeter-thick calcite and silica coatings at Yucca Mountain, Nevada, USA, a site that is being evaluated for a potential high-level nuclear waste repository. These calcite and silica coatings on fractures and in lithophysal cavities in Miocene-age tuffs in the unsaturated zone (UZ) precipitated from descending water and record a long history of percolation through the UZ. Opal and chalcedony have high concentrations of U (10 to 780 ppm) and low concentrations of common Pb as indicated by large values of 206 Pb/ 204 Pb (up to 53,806), thus making them suitable for U-Pb age determinations. Interpretations of U-Pb isotopes in opal samples at Yucca Mountain are complicated by the incorporation of excess 234 U at the time of mineral formation, resulting in reverse discordance of U-Pb ages. However, the 207 Pb/ 235 U ages are much less affected by deviation from initial secular equilibrium and provide reliable ages of most silica deposits between 0.6 and 9.8 Ma. For chalcedony subsamples showing normal age discordance, these ages may represent minimum times of deposition. Typically, 207 Pb/ 235 U ages are consistent with the microstratigraphy in the mineral coating samples, such that the youngest ages are for subsamples from outer layers, intermediate ages are from inner layers, and oldest ages are from innermost layers. 234 U and 230 Th in most silica layers deeper in the coatings are in secular equilibrium with 238 U, which is consistent with their old age and closed system behavior during the past 0.5 m.y. U-Pb ages for subsamples of silica layers from different microstratigraphic positions in individual calcite and silica coating samples collected from lithophysal cavities in the welded part of the Topopah Spring Tuff yield slow long-term average depositional rates of 1 to 5 mm/m.y. These data imply that the deeper parts of the UZ at Yucca Mountain maintained long

  8. Zircon Lu-Hf isotope systematics and U-Pb geochronology, whole-rock Sr-Nd isotopes and geochemistry of the early Jurassic Gokcedere pluton, Sakarya Zone-NE Turkey: a magmatic response to roll-back of the Paleo-Tethyan oceanic lithosphere (United States)

    Karsli, Orhan; Dokuz, Abdurrahman; Kandemir, Raif


    The early Mesozoic was a critical era for the geodynamic evolution of the Sakarya Zone as transition from accretion to collision events in the region. However, its complex evolutionary history is still debated. To address this issue, we present new in situ zircon U-Pb ages and Lu-Hf isotope data, whole-rock Sr-Nd isotopes, and mineral chemistry and geochemistry data of plutonic rocks to better understand the magmatic processes. The Gokcedere pluton is mainly composed of gabbro and gabbroic diorite. LA-ICP-MS zircon U-Pb dating reveals that the pluton was emplaced in the early Jurassic (177 Ma). These gabbros and gabbroic diorites are characterized by relatively low SiO2 content of 47.09 to 57.15 wt% and high Mg# values varying from 46 to 75. The samples belong to the calc-alkaline series and exhibit a metaluminous I-type character. Moreover, they are slightly enriched in large ion lithophile elements (Rb, Ba, Th and K) and light rare earth elements and depleted in high field strength elements (Nb and Ti). Gabbroic rocks of the pluton have a depleted Sr-Nd isotopic composition, including low initial 87Sr/86Sr ranging from 0.705124 to 0.705599, relatively high ɛ Nd ( t) values varying from 0.1 to 3.5 and single-stage Nd model ages ( T DM1 = 0.65-0.95 Ga). In situ zircon analyses show that the rocks have variable and positive ɛ Hf ( t) values (4.6 to 13.5) and single-stage Hf model ages ( T DM1 = 0.30 to 0.65 Ga). Both the geochemical signature and Sr-Nd-Hf isotopic composition of the gabbroic rocks reveal that the magma of the studied rocks was formed by the partial melting of a depleted mantle wedge metasomatized by slab-derived fluids. The influence of slab fluids is mirrored by their trace-element characteristics. Trace-element modeling suggests that the primary magma was generated by a low and variable degree of partial melting ( 5-15%) of a depleted and young lithospheric mantle wedge consisting of phlogopite- and spinel-bearing lherzolite. Heat to melt the

  9. Crystallization and Disturbance Histories of Single Zircon Crystals From Hadean-Eoarchean Acasta Gneisses Examined by LA-ICP-MS U-Pb Traverses (United States)

    Guitreau, Martin; Mora, Nicolas; Paquette, Jean-Louis


    Zircon U-Pb geochronology is a very robust dating method but the accuracy of determined ages can sometimes be compromised. This is because, as commonly observed, the U-Pb isotope system can be reopened during the post-crystallization evolution of a zircon. The present manuscript investigates the capability of traverses by LA-ICP-MS to identify zones of well-preserved U-Pb isotope systematics within zircon crystals. The data for the different zones can be used to construct internal Discordia lines that provide age information about crystallization and metamorphism of single zircon crystals. To test our approach, we analyzed zircons from three ca. 3.96 Ga Acasta gneisses. Results demonstrate that such a method allows retrieval of original crystallization age in most of the studied zircons, even in those that experienced ancient U-Pb disturbances resulting in discordant U-Pb data. It was also possible to estimate disturbance ages, though not as precisely as for the igneous crystallization, in many of the studied crystals.

  10. Petrology and zircon U-Pb geochronology of metamorphic massifs around the middle segment of the Tan-Lu fault to define the boundary between the North and South China blocks (United States)

    Shi, Yonghong


    The Tan-Lu fault (TLF) is a significant linear structure of eastern China. The middle segment of the TLF in the northern Anhui Province separates the North China Block (NCB) and South China Block (SCB). Lack of geological work makes the plate boundary here ambiguous. Detailed field survey and laboratory analyses have been conducted to constrain the formation and evolution of the TLF. To the west of the TLF, the Wuhe massif underwent a granulite facies metamorphism with T = 778-836 °C, P = 1.0-1.2 GPa during 2.41-2.43 Ga according to LA-ICP-MS U-Pb zircon dating. On the contrary, to the east of the TLF, the Zhangbaling massif suffered a greenschist to lower amphibolite facies metamorphism with the average metamorphic temperature at around 340-440 °C, with the protolith igneous ages of ca. 750 Ma. These differences indicate that the two massifs belong to the different blocks. Furthermore, the granitic gneiss in the central part of TLF gives three populations of zircon U-Pb age at 667-504 Ma, 228 ± 2 Ma and 211 ± 2 Ma, respectively. The later two groups of spectra correspond to the periods of subduction and exhumation of the Dabie massif (245-200 Ma). Combined with previous study, the precise plate boundary between NCB and SCB has been delineated as the Zhuding-Shimenshan fault, and the initial time of the motion for the TLF is also discussed.

  11. Mercury anomalies as a proxy for large igneous province volicanism and effects on the carbon cycle in a U-Pb age-constrained section spanning the end-Triassic mass extinction, Levanto, Peru (United States)

    Yager, J. A.; West, A. J.; Bergquist, B. A.; Thibodeau, A. M.; Corsetti, F. A.; Berelson, W.; Rosas, S.; Bottjer, D. J.


    Understanding the causes of the end-Triassic extinction and their potential relationship to Central Atlantic Magmatic Province (CAMP) volcanism necessitates careful correlation of carbon cycle records (largely from marine sections) and volcanism (largely from terrestrial successions) in a robust chronological framework. Here, we report stable carbon isotopes and mercury concentrations and isotopes from the Levanto section in Northern Peru as a putative proxy for CAMP (a large igneous province) in a marine section. Levanto represents deposition well below storm wave base and is lithologically homogenous before, during, and after the end-Triassic extinction interval, making it ideal for detailed chemostratigraphy. Furthermore, abundant intercalated ash beds allow us to correlate mercury concentrations in the marine record directly with CAMP basalt ages, providing a test of the correspondence of mercury anomalies with the eruption of CAMP volcanics. Age dating and C isotope analyses provide an opportunity to explore orbital tuning of the carbon isotope record and ground truth it with existing U-Pb ages from the section, a feature not available in any other marine sections examined to date. The abundance of U-Pb dated ashes in the Levanto section allows us to correlate orbital tuning with other basins, which lack absolute age control, providing a better understanding for the C cycle changes associated with the Triassic-Jurassic boundary.

  12. Palaeozoic polymetamorphism in the North Qinling orogenic belt, Central China: Insights from petrology and in situ titanite and zircon U-Pb geochronology

    NARCIS (Netherlands)

    Li, Y.; Zhou, H.; Li, Q.L.; Xiang, H.; Zhong, Z.Q.; Brouwer, F.M.


    The Qinling orogenic belt experienced multiple phases of orogenesis during the Palaeozoic. Unraveling the timing and P- T conditions of these events is the key to understanding the convergence processes between the South China and the North China Blocks. The Songshugou Complex, located in the

  13. Geochemistry and geochronology U-Pb and Sm/Nd data of the orthogneiss from Pontalina region (GO), Brazil; Geoquimica e geocronologia U-Pb e Sm-Nd dos ortognaisses da regiao de Pontalina (GO), Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Navarro, Guillermo Rafael Beltran, E-mail: [Universidade Estadual Paulista Julio de Mesquisa Filho (UNESP), Rio Claro, SP (Brazil). Inst. de Geociencias e Ciencias Exatas. Programa de Pos-Graduacao em Geologia Regional; Zanardo, Antenor, E-mail: [Universidade Estadual Paulista Julio de Mesquisa Filho (UNESP), Rio Claro, SP (Brazil). Dept. de Petrologia e Metalogenia; Conceicao, Fabiano Tomazini da, E-mail: [Universidade Estadual Paulista Julio de Mesquisa Filho (UNESP), Rio Claro, SP (Brazil). Dept. de Planejamento Territorial e Geoprocessamento; Montibeller, Cibele Carolina, E-mail: [Universidade Estadual Paulista Julio de Mesquisa Filho (UNESP), Rio Claro, SP (Brazil). Curso de Geologia


    Orthogneisses of tonalitic to granodioritic composition with calc-alkaline, metaluminous to peraluminous characteristics crop out at the region of Pontalina. The orthogneisses exhibit negative anomalies of Nb, Ta, P and Ti relative to rare earth elements (REE) and litophile elements, besides low contents of Nb, Ta, Y and Yb, similar to the rocks formed in subduction environments. U-Pb geochronological data show a neoproterozoic (681.5 {+-} 7.7 Ma) crystallization for the orthogneisses. The Nd isotope data yielded weakly negative to positive {epsilon}{sub Nd}(T) (+3.2 up to -0.1), with T{sub DM} model ages of {approx} 1.2 Ga. The combined geochemical and isotopic data suggest that the protolith of these orthogneisses are representative of neoproterozoic juvenile magmas, probably developed in an island arc system, generated during a ca.700 and 600 Ma event of crustal accretion in the western edge of the Sao Francisco Craton. (author)

  14. U-Pb geochronology by La-CIP-MS and petrography of Sao Carlos massif - stanniferous province of Rondonia; Geocronologia U-Pb por La-ICP-MS e petrografia do macico Sao Carlos - Provincia Estanifera de Rondonia

    Energy Technology Data Exchange (ETDEWEB)

    Debowski, Beatriz P.; Geraldes, Mauro Cesar; Nogueira, Camila; Almeida, Bruna Saar de [Universidade do Estado do Rio de Janeiro, (UERJ), RJ (Brazil)


    U-Pb dating by ICP-MS-LA were performed in four samples of the Massif Sao Carlos massif, representative of the younger Granites of Rondonia belonging to the stanniferous province of the same State. Dated samples are granites of pink in colour and coarse-grained to porphyry with main mineralogy consisting of feldspar pertitic to mesopertitic, quartz, plagioclase in lower proportion, biotite and amphibole in some cases. Ages obtained were 986 ± 14 Ma, 974 ± 10 Ma, ± 8 Ma 992.7 and 996 ± 8 Ma and represent the age of crystallization of the Massif. Such ages are concordant with others reported on the bibliography ratifying the inclusion of the massif in the younger Granites of Rondonia, which are directly associated with the most significant mineralization of cassiterite in the State.

  15. Community-based Approaches to Improving Accuracy, Precision, and Reproducibility in U-Pb and U-Th Geochronology (United States)

    McLean, N. M.; Condon, D. J.; Bowring, S. A.; Schoene, B.; Dutton, A.; Rubin, K. H.


    The last two decades have seen a grassroots effort by the international geochronology community to "calibrate Earth history through teamwork and cooperation," both as part of the EARTHTIME initiative and though several daughter projects with similar goals. Its mission originally challenged laboratories "to produce temporal constraints with uncertainties approaching 0.1% of the radioisotopic ages," but EARTHTIME has since exceeded its charge in many ways. Both the U-Pb and Ar-Ar chronometers first considered for high-precision timescale calibration now regularly produce dates at the sub-per mil level thanks to instrumentation, laboratory, and software advances. At the same time new isotope systems, including U-Th dating of carbonates, have developed comparable precision. But the larger, inter-related scientific challenges envisioned at EARTHTIME's inception remain - for instance, precisely calibrating the global geologic timescale, estimating rates of change around major climatic perturbations, and understanding evolutionary rates through time - and increasingly require that data from multiple geochronometers be combined. To solve these problems, the next two decades of uranium-daughter geochronology will require further advances in accuracy, precision, and reproducibility. The U-Th system has much in common with U-Pb, in that both parent and daughter isotopes are solids that can easily be weighed and dissolved in acid, and have well-characterized reference materials certified for isotopic composition and/or purity. For U-Pb, improving lab-to-lab reproducibility has entailed dissolving precisely weighed U and Pb metals of known purity and isotopic composition together to make gravimetric solutions, then using these to calibrate widely distributed tracers composed of artificial U and Pb isotopes. To mimic laboratory measurements, naturally occurring U and Pb isotopes were also mixed in proportions to mimic samples of three different ages, to be run as internal

  16. New U-Pb age constraints on the upper Banxi Group and synchrony of the Sturtian glaciation in South China

    Directory of Open Access Journals (Sweden)

    Gaoyuan Song


    Full Text Available The Nanhua basin in South China hosts well-preserved middle–late Neoproterozoic sedimentary and volcanic rocks that are critical for studying the basin evolution, the breakup of the supercontinent Rodinia, the nature and dynamics of the “snowball” Earth and diversification of metazoans. Establishing a stratigraphic framework is crucial for better understanding the interactions between tectonic, paleoclimatic and biotic events recorded in the Nanhua basin, but existing stratigraphic correlations remain debated, particularly for pre-Ediacaran strata. Here we report new Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICPMS U-Pb zircon ages from the middle and topmost Wuqiangxi Formation (the upper stratigraphic unit of the Banxi Group in Siduping, Hunan Province, South China. Two samples show similar age distribution, with two major peaks at ca. 820 Ma and 780 Ma and one minor peak at ca. 910 Ma, suggesting that the Wuqiangxi sandstone was mainly sourced from Neoproterozoic rocks. Two major age peaks correspond to two phases of magmatic events associated with the rifting of the Nanhua basin, and the minor peak at ca. 910 Ma may correspond to the Shuangxiwu volcanic arc magmatism, which represents pre-collision/amalgamation subduction on the southeastern margin of the Yangtze Block. The youngest zircon group from the topmost Wuqiangxi Formation has a weighted mean age of 714.6 ± 5.2 Ma, which is likely close to the depositional age of the uppermost Banxi Group. This age, along with the ages reported from other sections, constrains that the Banxi Group was deposited between ca. 820 Ma and ca. 715 Ma. The age of 714.6 ± 5.2 Ma from the top of the Wuqiangxi Formation is indistinguishable with the SIMS U-Pb age of 715.9 ± 2.8 Ma from the upper Gongdong Formation in the Sibao village section of northern Guangxi, South China. It is also, within uncertainties, overlapped with two TIMS U-Pb ages from pre

  17. New zircon (U-Th)/He and U/Pb eruption age for the Rockland tephra, western USA (United States)

    Coble, Matthew A.; Burgess, Seth; Klemetti, Erik W.


    Eruption ages of a number of prominent Quaternary volcanic deposits remain inaccurately and/or imprecisely constrained, despite their importance as regional stratigraphic markers in paleo-environment reconstruction and as evidence of climate-altering eruptions. Accurately dating volcanic deposits presents challenging analytical considerations, including poor radiogenic yield, scarcity of datable minerals, and contamination of crystal populations by magma, eruption, and transport processes. One prominent example is the Rockland tephra, which erupted from the Lassen Volcanic Center in the southern Cascade arc. Despite a range in published eruption ages from 0.40 to 0.63 Ma, the Rockland tephra is extensively used as a marker bed across the western United States. To more accurately and precisely constrain the age of the Rockland tephra-producing eruption, we report U/Pb crystallization dates from the outermost ∼2 μm of zircon crystal faces (surfaces) using secondary ion mass spectrometry (SIMS). Our new weighted mean 238U/206Pb age for Rockland tephra zircon surfaces is 0.598 ± 0.013 Ma (2σ) and MSWD = 1.11 (mean square weighted deviation). As an independent test of the accuracy of this age, we obtained new (U-Th)/He dates from individual zircon grains from the Rockland tephra, which yielded a weighted mean age of 0.599 ± 0.012 Ma (2σ, MSWD = 5.13). We also obtained a (U-Th)/He age of 0.628 ± 0.014 Ma (MSWD = 1.19) for the Lava Creek Tuff member B, which was analyzed as a secondary standard to test the accuracy of the (U-Th)/He technique for Quaternary tephras, and to evaluate assumptions made in the model-age calculation. Concordance of new U/Pb and (U-Th)/He zircon ages reinforces the accuracy of our preferred Rockland tephra eruption age, and confirms that zircon surface dates sample zircon growth up to the time of eruption. We demonstrate the broad applicability of coupled U/Pb zircon-surface and single-grain zircon (U-Th)/He geochronology to

  18. New zircon (U-Th)/He and U/Pb eruption age for the Rockland tephra, western USA (United States)

    Coble, Matthew A.; Burgess, Seth D.; Klemetti, Erik W.


    Eruption ages of a number of prominent Quaternary volcanic deposits remain inaccurately and/or imprecisely constrained, despite their importance as regional stratigraphic markers in paleo-environment reconstruction and as evidence of climate-altering eruptions. Accurately dating volcanic deposits presents challenging analytical considerations, including poor radiogenic yield, scarcity of datable minerals, and contamination of crystal populations by magma, eruption, and transport processes. One prominent example is the Rockland tephra, which erupted from the Lassen Volcanic Center in the southern Cascade arc. Despite a range in published eruption ages from 0.40 to 0.63 Ma, the Rockland tephra is extensively used as a marker bed across the western United States. To more accurately and precisely constrain the age of the Rockland tephra-producing eruption, we report U/Pb crystallization dates from the outermost ∼2 μm of zircon crystal faces (surfaces) using secondary ion mass spectrometry (SIMS). Our new weighted mean 238U/206Pb age for Rockland tephra zircon surfaces is 0.598 ± 0.013 Ma (2σ) and MSWD = 1.11 (mean square weighted deviation). As an independent test of the accuracy of this age, we obtained new (U-Th)/He dates from individual zircon grains from the Rockland tephra, which yielded a weighted mean age of 0.599 ± 0.012 Ma (2σ, MSWD = 5.13). We also obtained a (U-Th)/He age of 0.628 ± 0.014 Ma (MSWD = 1.19) for the Lava Creek Tuff member B, which was analyzed as a secondary standard to test the accuracy of the (U-Th)/He technique for Quaternary tephras, and to evaluate assumptions made in the model-age calculation. Concordance of new U/Pb and (U-Th)/He zircon ages reinforces the accuracy of our preferred Rockland tephra eruption age, and confirms that zircon surface dates sample zircon growth up to the time of eruption. We demonstrate the broad applicability of coupled U/Pb zircon-surface and single-grain zircon (U-Th)/He geochronology to accurate

  19. Tectonic implications of U-Pb (zircon) Geochronology of Chor Granitoids of the Lesser Himalaya, Himachal Pradesh, NW Himalaya (United States)

    Singh, P.; Bhakuni, S. S.


    Granitoids of various ages ranging from Proterozoic to Tertiary occur throughout the Himalayan fold-thrust belt. The occurrence of the Neoproterozoic granitoids are very less in the Himalayan orogen. One of the best example of Neoproterozoic granitoids is Chor granitoids, which are the intrusive granite bodies in the Paleoproterozoic of the Lesser Himalayan Crystallines of the Jutogh Group. In the central part these granites are non-foliated homogeneous that are porphyritic and peraluminous in nature (Singh et al., 2002; Bhargava et al., 2014, 2016), whereas in the peripheral part these are foliated showing south directed shear sense of movement. In this work we present the U-Pb (zircon) geochronology of two different granites samples of the Chor granitoids of Himachal Pradesh, NW Himalaya. The Jutogh Group of rocks is thrust over the Lesser Himalayan Sequence along the Jutogh Thrust or MCT. The geochronology of the Chor Granitoids and Lesser Himalayan Crystallines and their relationship with each other, including with the Indian shield are sparsely obscure. U-Pb zircon geochrnological age populations from these granitoids yield ages between 780 and 980 Ma. One sample gives the prominent age spectra for 206Pb/238U with weighted mean age of 908.3 ± 6.7 Ma (2σ) MSWD = 2.4 (n = 18). Similarly another sample gives the age of crystallization with weight mean age of 917 ± 17 Ma (2σ) MSWD = 3 (n = 11) and Th/U ratios of both samples are >0.1, indicating their magmatic origin. As a result of ductile shearing of granites along the MCT during the Cenozoic Himalayan Orogeny, the age has reduced to 780 Ma. The Neoproterozoic age of Chor granite matches with the Neoproterozoic detrital zircon age (800 to 1000 Ma by Parrish and Hodges 1996, Decelles et al., 2000) of the HHC. On the basis of U-Pb (zircon) geochronological ages, it is revealed that the source of zircons of the Chor granite and HHC rocks was the northern margin of the Pan-African orogen. The Chor granitoids was

  20. Toward the bioremediation of dioxin-polluted soil: structural and functional analyses of in situ microbial populations by quinone profiling and culture-dependent methods. (United States)

    Hiraishi, A; Miyakoda, H; Lim, B R; Hu, H Y; Fujie, K; Suzuki, J


    In order to obtain basic information toward the bioremediation of dioxin-polluted soil, microbial communities in farmland soils polluted with high concentrations of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were studied by quinone profiling as well as conventional microbiological methods. The concentration of PCDD/Fs in the polluted soils ranged from 36 to 4,980 pg toxicity equivalent quality (TEQ) g(-1) dry weight of soil. There was an inverse relationship between the levels of PCDD/Fs and microbial biomass as measured by direct cell counting and quinone profiling. The most abundant quinone type detected was either MK-6 or Q-10. In addition, MK-8, MK-8(H2), and MK-9(H8) were detected in significant amounts. Numerical analysis of quinone profiles showed that the heavily polluted soils (> or = 1,430 pg TEQ g(-1)) contained different community structures from lightly polluted soils (polluted soils with dibenzofuran or 2-chlorodibenzofuran resulted in enrichment of Q-10-containing bacteria. When the heavily polluted soil was incubated in static bottles with autoclaved compost as an organic nutrient additive, the concentrations of PCDD/Fs in the soil were decreased by 22% after 3 months of incubation. These results indicate that dioxin pollution exerted a significant effect on microbial populations in soil in terms of quantity, quality, and activity. The in situ microbial populations in the dioxin-polluted soil were suggested to have a potential for the transformation of PCDD/Fs and oxidative degradation of the lower chlorinated ones thus produced.

  1. Archean and proterozoic in the West-European Hercynian chain: isotopic geochemistry (Sr-Nd-Pb) and U-Pb geochronology on zircons

    International Nuclear Information System (INIS)

    Guerrot, C.


    The first part of this research thesis reports the study of isotopic (Sr-Nd-Pb) geochemistry and U-Pb geochronology on zircons in the immersed granulites of the Bay of Biscay: U-Pb geochronology on zircons, Nd isotopic geochemistry, Sr isotopic geochemistry, common Pb, Rb-Sr, Sm-Nd and rare earth data on minerals, comparison with other European granulites, comparison with West-Africa, study of Archean and proterozoic in the Hercynian chain. The second part reports the study of the U-Pb geochronology on zircon in the Cadomian, and the third part addresses the Sr-Nd isotopic geochemistry of some Cadomian granitoid, and the crust contamination in different regions [fr

  2. Geologic evolution of the Paraiba do Sul complex, in the central part of the Ribeira belt, based on the geochemistry and U-Pb geochronology studies

    International Nuclear Information System (INIS)

    Valladares, Claudia Sayao


    Aiming the definition of the Complexo Paraiba do Sul evolution, the work presents a geochronological approach by the U-Pb method, considered appropriate to study polideformed terrains. The minerals used to the U-Pb dating (zircon, titanite and monazite) provides information about the ages of rock generation and the successive geological events the rocks were submitted. The U-Pb geochronological approach is pioneer in the investigated area and two questions referent to the Complexo Paraiba do Sul evolution in the central part of the Ribeira belt, were the aim of this approach. The first of them refers to the crystallization epoch and the gneisses metamorphism, interpreted here like orthogneisses, called Unidade Quirino of the Complexo Paraiba do Sul. The second refers to the metamorphism ages and meta sedimentary unit deformation. Looking for the contribution to the Complexo Paraiba do Sul evolution understanding, this work presents the data based on the geologic map of this area, comprising part of the Folha Volta Redonda (1:50.000), including petrographic, structural and microtectonic studies. It also presents and discusses the results of: 17 U-Pb analysis in zircon and titanite of the Complexo Paraiba do Sul orthogneisses collection; 24 geochemical analysis of major, minor, trace elements and ETR of the same collection; an U-Pb analysis in titanite of the Unidade Sao Joao, 5 U-Pb analysis in titanites and/or monazites of granites and granitoids; 12 geochemical analysis including major, minor and trace elements and ETR, in granites and sills of leucogranites. Finally, the data achieved were integrated with the objective to elaborate an evolutive view of the Complexo Paraiba do Sul

  3. U-Pb geochronology by La-CIP-MS and petrography of Sao Carlos massif - stanniferous province of Rondonia

    International Nuclear Information System (INIS)

    Debowski, Beatriz P.; Geraldes, Mauro Cesar; Nogueira, Camila; Almeida, Bruna Saar de


    U-Pb dating by ICP-MS-LA were performed in four samples of the Massif Sao Carlos massif, representative of the younger Granites of Rondonia belonging to the stanniferous province of the same State. Dated samples are granites of pink in colour and coarse-grained to porphyry with main mineralogy consisting of feldspar pertitic to mesopertitic, quartz, plagioclase in lower proportion, biotite and amphibole in some cases. Ages obtained were 986 ± 14 Ma, 974 ± 10 Ma, ± 8 Ma 992.7 and 996 ± 8 Ma and represent the age of crystallization of the Massif. Such ages are concordant with others reported on the bibliography ratifying the inclusion of the massif in the younger Granites of Rondonia, which are directly associated with the most significant mineralization of cassiterite in the State

  4. Zircon U-Pb geochronology links the end-Triassic extinction with the Central Atlantic Magmatic Province. (United States)

    Blackburn, Terrence J; Olsen, Paul E; Bowring, Samuel A; McLean, Noah M; Kent, Dennis V; Puffer, John; McHone, Greg; Rasbury, E Troy; Et-Touhami, Mohammed


    The end-Triassic extinction is characterized by major losses in both terrestrial and marine diversity, setting the stage for dinosaurs to dominate Earth for the next 136 million years. Despite the approximate coincidence between this extinction and flood basalt volcanism, existing geochronologic dates have insufficient resolution to confirm eruptive rates required to induce major climate perturbations. Here, we present new zircon uranium-lead (U-Pb) geochronologic constraints on the age and duration of flood basalt volcanism within the Central Atlantic Magmatic Province. This chronology demonstrates synchroneity between the earliest volcanism and extinction, tests and corroborates the existing astrochronologic time scale, and shows that the release of magma and associated atmospheric flux occurred in four pulses over about 600,000 years, indicating expansive volcanism even as the biologic recovery was under way.

  5. Permian depositional age of metaturbidites of the Duque de York Complex, southern Chile: U-Pb SHRIMP data and palynology

    International Nuclear Information System (INIS)

    Sepulveda, Fernando A; Palma-Heldt, Sylvia; Herve, Francisco; Fanning, Mark


    The Duque de York Complex (DYC) is part of the low grade metamorphic accretionary complexes of the pre-Andean Patagonian 'basement'. It is a sedimentary succession exposed along the western margin of southernmost South America. New U-Pb zircon ages and palynological data restrict the maximum depositional age of the DYC to the limit between the early Permian (Kungurian) and the middle Permian (Roadian). The palynological association recorded in the DYC, characterized mainly by Gymnospermopsida pollen, indicates a humid environment of forest with an under-growth of ferns. Regional paleogeographic correlations point out that an interpretation of DYC as an autochthonous terrane cannot be discarded, contrasting with previous hypotheses which suggest an allochthonous character for this complex

  6. Earth history. U-Pb geochronology of the Deccan Traps and relation to the end-Cretaceous mass extinction. (United States)

    Schoene, Blair; Samperton, Kyle M; Eddy, Michael P; Keller, Gerta; Adatte, Thierry; Bowring, Samuel A; Khadri, Syed F R; Gertsch, Brian


    The Chicxulub asteroid impact (Mexico) and the eruption of the massive Deccan volcanic province (India) are two proposed causes of the end-Cretaceous mass extinction, which includes the demise of nonavian dinosaurs. Despite widespread acceptance of the impact hypothesis, the lack of a high-resolution eruption timeline for the Deccan basalts has prevented full assessment of their relationship to the mass extinction. Here we apply uranium-lead (U-Pb) zircon geochronology to Deccan rocks and show that the main phase of eruptions initiated ~250,000 years before the Cretaceous-Paleogene boundary and that >1.1 million cubic kilometers of basalt erupted in ~750,000 years. Our results are consistent with the hypothesis that the Deccan Traps contributed to the latest Cretaceous environmental change and biologic turnover that culminated in the marine and terrestrial mass extinctions. Copyright © 2015, American Association for the Advancement of Science.

  7. In situ calibration using univariate analyses based on the onboard ChemCam targets: first prediction of Martian rock and soil compositions

    Energy Technology Data Exchange (ETDEWEB)

    Fabre, C. [GeoRessources lab, Université de Lorraine, Nancy (France); Cousin, A.; Wiens, R.C. [Los Alamos National Laboratory, Los Alamos, NM (United States); Ollila, A. [University of NM, Albuquerque (United States); Gasnault, O.; Maurice, S. [IRAP, Toulouse (France); Sautter, V. [Museum National d' Histoire Naturelle, Paris (France); Forni, O.; Lasue, J. [IRAP, Toulouse (France); Tokar, R.; Vaniman, D. [Planetary Science Institute, Tucson, AZ (United States); Melikechi, N. [Delaware State University (United States)


    Curiosity rover landed on August 6th, 2012 in Gale Crater, Mars and it possesses unique analytical capabilities to investigate the chemistry and mineralogy of the Martian soil. In particular, the LIBS technique is being used for the first time on another planet with the ChemCam instrument, and more than 75,000 spectra have been returned in the first year on Mars. Curiosity carries body-mounted calibration targets specially designed for the ChemCam instrument, some of which are homgeneous glasses and others that are fine-grained glass-ceramics. We present direct calibrations, using these onboard standards to infer elements and element ratios by ratioing relative peak areas. As the laser spot size is around 300 μm, the LIBS technique provides measurements of the silicate glass compositions representing homogeneous material and measurements of the ceramic targets that are comparable to fine-grained rock or soil. The laser energy and the auto-focus are controlled for all sequences used for calibration. The univariate calibration curves present relatively to very good correlation coefficients with low RSDs for major and ratio calibrations. Trace element calibration curves (Li, Sr, and Mn), down to several ppm, can be used as a rapid tool to draw attention to remarkable rocks and soils along the traverse. First comparisons to alpha-particle X-ray spectroscopy (APXS) data, on selected targets, show good agreement for most elements and for Mg# and Al/Si estimates. SiO{sub 2} estimates using univariate cannot be yet used. Na{sub 2}O and K{sub 2}O estimates are relevant for high alkali contents, but probably under estimated due to the CCCT initial compositions. Very good results for CaO and Al{sub 2}O{sub 3} estimates and satisfactory results for FeO are obtained. - Highlights: • In situ LIBS univariate calibrations are done using the Curiosity onboard standards. • Major and minor element contents can be rapidly obtained. • Trace element contents can be used as a

  8. Electron microprobe Th-U-Pb monazite dating and metamorphic evolution of the Acaiaca Granulite Complex, Minas Gerais, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Medeiros Junior, Edgar Batista; Marques, Rodson Abreu, E-mail:, E-mail: [Universidade Federal do Espirito Santo (UFES), Alegre, ES (Brazil). Departamento de Geologia; Jordt-Evangelista, Hanna; Queiroga, Glaucia Nascimento, E-mail:, E-mail: [Universidade Federal de Ouro Preto (UFOP), Ouro Preto, MG (Brazil). Escola de Minas. Departamento de Geologia; Schulz, Bernhard, E-mail: [TU Bergakademie - Institute of Mineralogy, Freiberg - Saxony (Germany)


    The Acaiaca Complex (AC) is located in southeastern Minas Gerais state, and comprises felsic, mafic, ultramafic, and aluminous granulite as well as lower grade gneisses and mylonite. The complex is distributed over an area of ca. 36 km by 6 km, surrounded by amphibolite facies gneisses of the Mantiqueira Complex (MC). The discrepancy in the metamorphic grade between both complexes led to the present study aiming to understand the metamorphic history of the AC by means of geothermobarometry calculations and electron microprobe Th-U-Pb monazite dating. Estimates of the metamorphic conditions of the granulite based on conventional geothermobarometry and THERMOCALC resulted in temperatures around 800 deg C and pressures between of 5.0 and 9.9 kbar and a retro metamorphic path characterized by near-isobaric cooling. Part of the granulite was affected by anatexis. The melting of felsic granulite resulted in the generation of pegmatites and two aluminous lithotypes. These are: 1) garnet-sillimanite granulite with euhedral plagioclase and cordierite that show straight faces against quartz, and is the crystallization product of an anatectic melt, and 2) garnet-kyanite-cordierite granulite, which is probably the restite of anatexis, as indicated by textures and high magnesium contents. Th-U-Pb monazite geochronology of two granulite samples resulted in a metamorphic age around 2060 Ma, which is similar to the age of the MC registered in the literature. The similar Paleoproterozoic metamorphic ages of both complexes lead to the conclusion that the Acaiaca Complex may be the high grade metamorphic unit geochronological related to the lower grade Mantiqueira Complex. (author)

  9. North Qinling Terrain as a provenance of Kuanping Group: LA-ICP-MS U-Pb Geochronology of detrital zircons (United States)

    Hu, B.; Li, S.; Zhai, M.; Wu, J.; Jia, X.


    Though some Neoproterozoic S-type granites in the North Qinling Terrain (NQT), China indicate the collision between the NQT and an unknown block, there are still controversial. The LA-ICP-MS U-Pb ages of detrital zircons of meta-sandstones from the Kuanping Group in Luonan area, NQT, provide sedimentology evidence to prove that the NQT and an unknown block from Rodinia supercontinent have been collided during Meso-Neoproterozoic. The U-Pb ages of detrital zircons from the Kuanping Group show that the main age peaks are at 2.58 Ga, 2.46 Ga, 2.0 Ga, 1.78 Ga, 1.6 Ga, 1.45 Ga and 1.27 Ga. The youngest age of 880 Ma indicates that the sedimentary age of the Kuanping Group is less than 880 Ma. The provenances, which provide 1.45 - 0.88 Ga sediments may come from NQT, which magmatic and metamorphic rocks during this period outcropped. Whereas provenances providing 2.6- 1.6 Ga sediments may come from an unknown block. This indicates that the Kuangping Group received both NQT and the unknown block materials. Therefore, the NQT and the unknown block may have collided before 880 Ma. 889 - 848 Ma A-type granites distributing the NQT was considered forming under a post-collisional tectonics. According the youngest detrital zircon ages of 880 Ma, it is inferred that the Kuanping Basin may also form in the same tectonic environments. Neoproterozoic Kuanping basin and 889 - 848 Ma A-type granites may be a result which NQT broken off a block of Rodinia supercontinent. Acknowledgments: This research is supported by National Key Research and Development Plan of China (2016YFC0601002), Special Fund for Basic Scientific Research of Central Colleges, Chang'an University (310827172201, 0009-2014G1271067) and National Nature Science Foundation of China (41402042).

  10. Geology and U-Pb Zircon ages of the Kavacik Leucogranite in the Bornova Flysch Zone (Western Anatolia, Turkey) (United States)

    Güngör, Talip; Hasözbek, Altuǧ; Akal, Cüneyt; Mertz-Kraus, Regina; Peştemalci Üregel, Reyhan


    The Bornova Flysch Zone comprises an olistostrome-melange situated NE-SW direction between the Izmir Ankara Suture Zone and the Menderes Massif. The Bornova Flysch Zone is mainly composed of slightly deformed Late Cretaceous to Paleocene sandstone and shale with Mesozoic limestone and oceanic crustal associations. These large-scale blocks in the matrix of the Bornova Flysch Zone are mostly defined as limestone, basalt, serpentinite and radiolarian cherts. In this study, granitic bodies, situated in the Bornova Flysch Zone, named as Kavacik leucogranite is examined for the first time, in terms its geological features and its U-Pb zircon crystallization ages. Kavacik leucogranite displays a typical granitic texture and its composition indicates ranging between granitic to granodioritic in composition with lack of mafic minerals. The geochemical features of the granite indicate the I-type and subalkaline nature of the granitic body. The geochemical signatures of the Kavacik granite points out Volcanic Arc Granitoids as similarly seen in Karaburun granite. U-Pb zircon LA ages were also obtained from the Kavacik granite ranging between 224.5 ± 2.0 Ma and 230.0 ± 2.8 Ma. Early Triassic zircon ages are also previously observed in the Karaburun Peninsula (Karaburun Granite) and the Menderes Massif (Odemis-Kiraz Submassif). The initial geological boundary relation of the Kavacik Leucogranite is not clear in the field and likely displays tectonic boundary features in the matrix of the Bornova Flysch Zone. Overall, the geochemical features of the Kavacik leucogranite and similar leucomagmatic bodies in the Western Anatolia points out the subduction-related tectonic setting is favorable during the Triassic time.

  11. Variscan Collisional Magmatism and Deformation In The Viseu Area (northern Central Portugal) - Constraints From U-pb Geochronology of Granitoids (United States)

    Azevedo, M. R.; Aguado, B. V.; Scaltegger, U.; Nolan, J.; Martins, M. R.; Medina, J.

    The Viseu area is located in the innermost zone of the Iberian Variscan Fold Belt (the Central Iberian Zone). It consists of abundant post-thickening, collision related grani- toids intruded into upper and middle crustal levels. The ascent of granite magmas took place after an extensional tectonic event (D2) and is coeval with D3 dextral and sinis- tral crustal-scale transcurrent shear zones. In the northern part of the area, the presence of a well preserved Upper Carboniferous tectonic basin filled with deformed conti- nental clastic sediments, bounded by contemporaneously exhumed deep crustal rocks and intruded by late-tectonic granites documents an episode of extension involving basin subsidence, uplift and erosion of the basement and granite magmatism in a post- thickening, but syn-convergent scenario. Convergence is manifested by strike-slip tec- tonics and basin inversion. According to structural criteria, the Variscan granitoids can be subdivided into two major groups: (1) syn-D3 granitoids including two dif- ferent petrological associations, highly peraluminous leucogranite and granodiorite- monzogranite intrusions and (2) late-D3 granitoids comprising slightly metaluminous to peraluminous granodiorites and monzogranites. Four plutons representing the syn- D3 leucogranites (Junqueira) and monzogranites (Maceira and Casal Vasco) and the late-D3 biotite granites (Cota) yielded U-Pb zircon + monazite or monazite ages of 310 Ma, 311 Ma, 311 Ma and 306 Ma, respectively. This points to a synchronous emplacement of the different syn-D3 plutons shortly followed by the intrusion of the late-D3 granites and suggests that the Upper Carboniferous plutonism occurred within a short time span of ca. 5 myr. Stratigraphic markers show that the oldest continental sediments in the Carboniferous basin are Westphalian whilst field relationships in- dicate that the deformation occurred prior to the intrusion of the late-D3 granitoids. Precise U-Pb geochronology proves that basin

  12. First evidence for Permian-Triassic boundary volcanism in the Northern Gemericum: geochemistry and U-Pb zircon geochronology

    Directory of Open Access Journals (Sweden)

    Vozárová Anna


    Full Text Available Several magmatic events based on U-Pb zircon geochronology were recognized in the Permian sedimentary succession of the Northern Gemeric Unit (NGU. The Kungurian magmatic event is dominant. The later magmatism stage was documented at the Permian-Triassic boundary. The detrital zircon assemblages from surrounding sediments documented the Sakmarian magmatic age. The post-orogenic extensional/transtensional faulting controlled the magma ascent and its emplacement. The magmatic products are represented by the calc-alkaline volcanic rocks, ranging from basaltic metaandesite to metarhyolite, associated with subordinate metabasalt. The whole group of the studied NGU Permian metavolcanics has values for the Nb/La ratio at (0.44–0.27 and for the Nb/U ratio at (9.55–4.18, which suggests that they represent mainly crustal melts. Magma derivation from continental crust or underplated crust is also indicated by high values of Y/Nb ratios, ranging from 1.63 to 4.01. The new 206U–238Pb zircon ages (concordia age at 269 ± 7 Ma confirm the dominant Kungurian volcanic event in the NGU Permian sedimentary basin. Simultaneously, the Permian-Triassic boundary volcanism at 251 ± 4 Ma has been found for the first time. The NGU Permian volcanic activity was related to a polyphase extensional tectonic regime. Based on the new and previous U-Pb zircon ages, the bulk of the NGU Permian magmatic activity occurred during the Sakmarian and Kungurian. It was linked to the post-orogenic transpression/transtension tectonic movements that reflected the consolidation of the Variscan orogenic belt. The Permian-Triassic boundary magmatism was accompanied by extension, connected with the beginning of the Alpine Wilson cycle.

  13. In situ Remediation Technologies

    NARCIS (Netherlands)

    Grotenhuis, J.T.C.; Rijnaarts, H.H.M.


    A summary of two decades of developments of In Situ remediation is presented in this chapter. The basic principles of In Situ technology application are addressed, such as equilibrium relations between contaminant phases, factors controlling biological and geochemical processes, contaminant

  14. U-Pb zircon constraints on the age of the Cretaceous Mata Amarilla Formation, Southern Patagonia, Argentina: its relationship with the evolution of the Austral Basin Edades U-Pb en circones de la Formación Mata Amarilla (Cretácico, Patagonia Austral, Argentina: su relación con la evoluci��n de la Cuenca Austral

    Directory of Open Access Journals (Sweden)

    Augusto N Varela


    Full Text Available Despite the abundant fossil content of the Mata Amarilla Formation (Southern Patagonia, Santa Cruz Province, Argentina, its age has always generated a considerable number of questions and debates. The chronological data provided by invertebrates, dinosaurs, fish, turtles, plesiosaurs and fossil flora are contradictory. In this work, twenty U-Pb spot analyses by laser ablation were carried out on the outer parts of the zoned zircon crystals from a tuff layer of the middle section of the Mata Amarilla Formation, yielding a U-Pb concordia age of 96.23±0.71 Ma, which corresponds to the middle Cenomanian. The deposition of the lower section of the Mata Amarilla Formation marks the onset of the foreland stage of the Austral Basin (also known as Magallanes Basin; this transition is characterized by the west-east shift of the depositional systems, which is consistent with the progradation of the Cretaceous fold-and-thrust belt. Thus, the onset of the foreland stage could have occurred between the upper Albian and lower Cenomanian, as the underlying Piedra Clavada Formation is lower Albian in age. On comparing the data obtained with information from the Última Esperanza Province in Chile, it can be suggested that the initiation of the closure of the Rocas Verdes Marginal Basin occurred simultaneously.A pesar del abundante contenido fosilífero de la Formación Mata Amarilla (Patagonia Austral, Provincia de Santa Cruz, Argentina, siempre se generaron abundantes dudas y debates acerca de cuál es la edad de esta formación. Los datos cronológicos aportados por los invertebrados, los dinosaurios, peces, tortugas, plesiosaurios y flora fósil son dispares. En el presente trabajo se obtuvo una edad U-Pb concordia por la metodología de ablación láser aplicada a 20 puntos de la parte externa de circones zonados provenientes de un nivel tobáceo hallado en la sección media de la Formación Mata Amarilla, lo cual arrojó una edad de 96,23±0,71 Ma, que

  15. U-Pb geochronology of metasedimentary schists in Akwanga area of ...

    African Journals Online (AJOL)

    The zircons separated from a sample of the Schists show growth zoning and a number of grains display distinct cores and rims. Out of 131 analyses 117 yielded useful geochronological data. 67 of these gave 90-110% concordant results. Most ages scatter between 600 and 1100Ma with distinct peaks at 700, 850 and ...

  16. U-Pb age of the Diana Complex and Adirondack granulite ...

    Indian Academy of Sciences (India)

    For the most concordant analyses, the 207Pb/206Pb ages range between 1115 and 1150 Ma. Detailed petrographic studies revealed that most grains contained at least two phases of zircon growth, either primary magmatic cores enclosed by variable thickness of metamorphic overgrowths or magmatic portions enclosing ...

  17. SHRIMP U-Pb zircon dating of Archean core complex formatio and pancratonic strike-slip deformation in the East Pilbara Granite-Greenstone Terrain

    NARCIS (Netherlands)

    Zegers, T.E.; Nelson, D.R.; Wijbrans, J.R.; White, S.H.


    Sensitive high-resolution ion microprobe (SHRIMP) U-Pb dating of zircons from granitic rocks in the East Pilbara Granite-Greenstone Terrain has provided time constraints for main tectonic events in the Shaw Granitoid Complex and has shown that deformation was intricately related to granitoid

  18. U-Pb detrital zircon geochronology from the basement of the Central Qilian Terrane: implications for tectonic evolution of northeastern Tibetan Plateau (United States)

    Liu, Changfeng; Wu, Chen; Zhou, Zhiguang; Yan, Zhu; Jiang, Tian; Song, Zhijie; Liu, Wencan; Yang, Xin; Zhang, Hongyuan


    The Tuolai Group dominates the Central Qilian Terrane, and there are different opinions on the age and tectonic attribute of the Tuolai Group. Based on large-scale geologic mapping and zircon dating, the Tuolai Group is divided into four parts: metamorphic supracrustal rocks, Neoproterozoic acid intrusive rocks, early-middle Ordovician acid intrusive rocks and middle Ordovician basic intrusive rocks. The metamorphic supracrustal rocks are the redefined Tuolai complex-group and include gneiss and schist assemblage by faulting contact. Zircon U-Pb LA-MC-ICP-MS dating was conducted on these samples of gneiss and migmatite from the gneiss assemblage, quartzite, two-mica schist and slate from the schist assemblage. The five detrital samples possess similar age spectra; have detrital zircon U-Pb main peak ages of 1.7 Ga with youngest U-Pb ages of 1150 Ma. They are intruded by Neoproterozoic acid intrusive rocks. Therefore, the Tuolai Group belonging to late Mesoproterozoic and early Neoproterozoic. With this caveat in mind, we believe that U-Pb detrital zircon dating, together with the geologic constraints obtained from this study and early work in the neighboring regions. We suggest that the formation age of the entire crystalline basement rocks of metasedimentary sequence from the Central Qilian Terrane should be constrained between the Late Mesoproterozoic and the Late Neoproterozoic, but not the previous Paleoproterozoic. The basement of the Central Qilian Terrane contains the typical Grenville ages, which indicates the Centre Qilian Terrane have been experienced the Grenville orogeny event.

  19. Geochemie a zirkonové U-Pb stáří derflického granodioritu z dyjského masivu

    Czech Academy of Sciences Publication Activity Database

    Svojtka, Martin; Breiter, Karel; Ďurišová, Jana; Ackerman, Lukáš; Veselovský, F.; Šmerda, J.


    Roč. 50, č. 1 (2017), s. 17-24 ISSN 0514-8057 R&D Projects: GA ČR GA13-15390S Institutional support: RVO:67985831 Keywords : Bohemian Massif * Cadomian granitoids * Thaya (Dyje) Massif * zircon U-Pb dating Subject RIV: DB - Geology ; Mineralogy OBOR OECD: Geology

  20. Genesis of granitoid batholiths of Peninsular Malaysia and implications for models of crustal evolution: evidence from a Nd-Sr isotopic and U-Pb zircon study

    International Nuclear Information System (INIS)

    Liew, T.C.; McCulloch, M.T.


    Nd, Sr and U-Pb isotopic data for the late Triassic West Coast Province batholiths and Permian to Triassic East Coast Province batholiths of Peninsular Malaysia allow estimates of the ages of the crustal fragments comprising the peninsula to be made. Initial epsilonsub(Nd) and epsilonsub(Sr) values for granitoids from the West Coast Province are presented. Nd model ages calculated based on a depleted mantle evolution model (Tsub(DM)sup(Nd)) range from 1300 Ma to 1800 Ma and are in general agreement with the mid-Proterozoic upper intersection ages of U-Pb zircon reverse discordia. Initial epsilonsub(Nd) and epsilonsub(Sr) values for granitoids from the East Coast Province are presented. Calculated Tsub(DM)sup(Nd) ages of 900 to 1400 Ma for these granitoids are comparable to two U-Pb zircon reverse discordia intercepts that yield 800 Ma and 1350 Ma. The general agreement of U-Pb zircon inheritance ages and Tsub(DM)sup(Nd) ages are interpreted to correspond to the Proterozoic 'crust formation' ages of the continental fragments represented by the West Coast and East Coast batholithic provinces. Mid-Proterozoic 'crust formation' ages are commonly shown by other Phanerozoic continental margin plutonic and volcanic belts. The results are discussed. (U.K.)

  1. U-Pb detrital zircon geochronology from the basement of the Central Qilian Terrane: implications for tectonic evolution of northeastern Tibetan Plateau (United States)

    Liu, Changfeng; Wu, Chen; Zhou, Zhiguang; Yan, Zhu; Jiang, Tian; Song, Zhijie; Liu, Wencan; Yang, Xin; Zhang, Hongyuan


    The Tuolai Group dominates the Central Qilian Terrane, and there are different opinions on the age and tectonic attribute of the Tuolai Group. Based on large-scale geologic mapping and zircon dating, the Tuolai Group is divided into four parts: metamorphic supracrustal rocks, Neoproterozoic acid intrusive rocks, early-middle Ordovician acid intrusive rocks and middle Ordovician basic intrusive rocks. The metamorphic supracrustal rocks are the redefined Tuolai complex-group and include gneiss and schist assemblage by faulting contact. Zircon U-Pb LA-MC-ICP-MS dating was conducted on these samples of gneiss and migmatite from the gneiss assemblage, quartzite, two-mica schist and slate from the schist assemblage. The five detrital samples possess similar age spectra; have detrital zircon U-Pb main peak ages of 1.7 Ga with youngest U-Pb ages of 1150 Ma. They are intruded by Neoproterozoic acid intrusive rocks. Therefore, the Tuolai Group belonging to late Mesoproterozoic and early Neoproterozoic. With this caveat in mind, we believe that U-Pb detrital zircon dating, together with the geologic constraints obtained from this study and early work in the neighboring regions. We suggest that the formation age of the entire crystalline basement rocks of metasedimentary sequence from the Central Qilian Terrane should be constrained between the Late Mesoproterozoic and the Late Neoproterozoic, but not the previous Paleoproterozoic. The basement of the Central Qilian Terrane contains the typical Grenville ages, which indicates the Centre Qilian Terrane have been experienced the Grenville orogeny event.

  2. Carboniferous-Permian volcanic evolution in Central Europe-U/Pb ages of volcanic rocks in Saxony (Germany) and northern Bohemia (Czech Republic)

    Czech Academy of Sciences Publication Activity Database

    Hoffmann, U.; Breitkreuz, Ch.; Breiter, Karel; Sergeev, S.; Stanek, K.; Tichomirowa, M.


    Roč. 102, č. 1 (2013), s. 73-99 ISSN 1437-3254 Institutional support: RVO:67985831 Keywords : pyroclastic rocks * dykes * stratigraphy * SHRIMP U/Pb ages * Pb/Pb single zircon age * Variscides Subject RIV: DB - Geology ; Mineralogy Impact factor: 2.084, year: 2013

  3. Instrumented Bit for In-Situ Spectroscopy (IBISS), Phase I (United States)

    National Aeronautics and Space Administration — We propose to build and critically test the Instrumented Bit for In-Situ Spectroscopy (IBISS), a novel system for in-situ, rapid analyses of planetary subsurface...

  4. Paleocene and Early Eocene volcanic ash layers in the Schlieren Flysch, Switzerland: U-Pb dating and Hf-isotopes of zircons, pumice geochemistry and origin (United States)

    Koch, Simone; Winkler, Wilfried; Von Quadt, Albrecht; Ulmer, Peter


    Thin mm to cm thick bentonite layers of Paleocene to Early Eocene age in the Tonsteinschichten of the Schlieren Flysch represent volcanic ash layers. Heavy mineral analysis of the layers indicates basic to acidic volcanic sources. U/Pb dating of single zircon crystals of a Paleocene layer (WW1948) by LA-ICP-MS points to an eruption at 59.87 ± 0.41 Ma, whereas ID-TIMS shows an eruption age of 60.96 ± 0.07 Ma. Taking into account the external precision of LA-ICP-MS analyses of 1-2% both ages are overlapping and indicate an apparent minimal durations of zircon crystallization of 350 ka. Hf-isotope analysis of the same zircon crystals reveals the hybrid character of the source magma. The geochemical composition of the pumice grains of all bentonite layers is strongly affected by alteration. Nevertheless, the original character of the volcanic source can be evaluated. The Paleocene ashes (Lower Tonsteinschichten, LT) show a more fractionated multi-element pattern than the ashes of Early Eocene (Upper Tonsteinschichten, UT). The LT ash series are of rhyodacite to dacite character whereas the UT ashes fall in the field of alkali basalts. Both ash series seem to originate from a within-plate volcanic setting according to their trace element concentrations. Geochemical and temporary counterparts can be found in ash layers from Anthering (Austria) and the Danish Basin. As proposed for those ashes, volcanism connected to the opening of the North Atlantic might be the source as well for the ashes in the Schlieren Flysch. By comparison of the composition of rocks from the British Paleogene Igneous Province BPIP and the Schlieren Flysch ashes many correlations can be drawn which supports the suggestion of a North Atlantic origin of the Alpine ashes.

  5. Orogenesis and Basin Development: U-Pb Detrital Zircon Age Constraints on Evolution of the Late Paleozoic St. Marys Basin, Central Mainland Nova Scotia. (United States)

    Murphy; Hamilton


    The St. Marys Basin, along the southern flank of the composite Late Paleozoic Magdalen Basin in the Canadian Appalachians and along the Avalon-Meguma terrane boundary, contains Late Devonian-Early Carboniferous continental clastic rocks of the Horton Group that were deposited in fluvial and lacustrine environments after the peak of the Acadian orogeny. SHRIMP II (Geological Survey of Canada) data on approximately 100 detrital zircons from three samples of Horton Group rocks from the St. Marys Basin show that most of the zircons have been involved in a multistage history, recycled from clastic rocks in the adjacent Meguma and Avalonian terranes. Although there is a minor contribution from Early Silurian (411 Ma) and Late Devonian suites (ca. 380-370 Ma), Neoproterozoic (ca. 700-550 Ma) and Paleoproterozoic (ca. 2.0-2.2 Ga) zircon populations predominate, with a minor contribution from ca. 1.0-, 1.2-, and 1.8-Ga zircons. Published U-Pb single-zircon analyses on clastic sedimentary rocks indicate that the Meguma and Avalon terranes have different populations of detrital zircons, sourced from discrete portions (Amazonian and West African cratons) of the ancient Gondwanan margin. Both terranes contain Neoproterozoic and Late Archean populations. The SHRIMP data, in conjunction with published sedimentological and geochemical data, indicate that the Horton Group basin-fill sediments are largely the result of rapid uplift and erosion of Meguma terrane metasedimentary and granitoid rocks immediately to the south of the St. Marys Basin during the waning stages of the Acadian orogeny. Regional syntheses indicate that this uplift occurred before and during deposition and was a consequence of dextral ramping of the Meguma terrane over the Avalon terrane along the southern flank of the Magdalen Basin.

  6. Age of the Lava Creek supereruption and magma chamber assembly at Yellowstone based on 40Ar/39Ar and U-Pb dating of sanidine and zircon crystals (United States)

    Matthews, Naomi E.; Vazquez, Jorge A.; Calvert, Andrew T.


    The last supereruption from the Yellowstone Plateau formed Yellowstone caldera and ejected the >1000 km3 of rhyolite that composes the Lava Creek Tuff. Tephra from the Lava Creek eruption is a key Quaternary chronostratigraphic marker, in particular for dating the deposition of mid Pleistocene glacial and pluvial deposits in western North America. To resolve the timing of eruption and crystallization history for the Lava Creek magma, we performed (1) 40Ar/39Ar dating of single sanidine crystals to delimit eruption age and (2) ion microprobe U-Pb and trace-element analyses of the crystal faces and interiors of single zircons to date the interval of zircon crystallization and characterize magmatic evolution. Sanidines from the two informal members composing Lava Creek Tuff yield a preferred 40Ar/39Ar isochron date of 631.3 ± 4.3 ka. Crystal faces on zircons from both members yield a weighted mean 206Pb/238U date of 626.5 ± 5.8 ka, and have trace element concentrations that vary with the eruptive stratigraphy. Zircon interiors yield a mean 206Pb/238U date of 659.8 ± 5.5 ka, and reveal reverse and/or oscillatory zoning of trace element concentrations, with many crystals containing high U concentration cores that likely grew from highly evolved melt. The occurrence of distal Lava Creek tephra in stratigraphic sequences marking the Marine Isotope Stage 16–15 transition supports the apparent eruption age of ∼631 ka. The combined results reveal that Lava Creek zircons record episodic heating, renewed crystallization, and an overall up-temperature evolution for Yellowstone's subvolcanic reservoir in the 103−104 year interval before eruption.

  7. U-Pb and Sm-Nd preliminary geochronologic data on the Yaounde series, Cameroon: re-interpretation of the granulitic rocks as the suture of a collision in the ''Centrafrican'' belt

    International Nuclear Information System (INIS)

    Schmus, W.R. Van; Penaye, J.; Toteu, S.F.; Nzenti, J.P.


    U-Pb on zircons and Sm-Nd on whole-rock analyses have been applied on the schists, micaschists and granulitic gneisses of the Yaounde series. The results fix the granulitic metamorphism in the Yaounde series at 620±10 Ma and the deposition of the series during the Upper Proterozoic. In addition, another remnant of Lower Proterozoic basement, previously recognized in northern Cameroon, has been identified at Kekem northwest of the Yaounde series. The Yaounde granulitic unit is re-interpreted as the suture of a Pan-African collision between a passive margin (Archean Congo craton and its Birrimian Nyong cover) to the south and an intensive granitized active margin (dismembered eburnian basement and Upper Proterozoic series) to the north. (author). 14 refs., 4 figs

  8. U-Pb ages and Hf isotope compositions of zircons in plutonic rocks from the central Famatinian arc, Argentina (United States)

    Otamendi, Juan E.; Ducea, Mihai N.; Cristofolini, Eber A.; Tibaldi, Alina M.; Camilletti, Giuliano C.; Bergantz, George W.


    The Famatinian arc formed around the South Iapetus rim during the Ordovician, when oceanic lithosphere subducted beneath the West Gondwana margin. We present combined in situ U-Th-Pb and Lu-Hf isotope analyses for zircon to gain insights into the origin and evolution of Famatinian magmatism. Zircon crystals sampled from four intermediate and silicic plutonic rocks confirm previous observations showing that voluminous magmatism took place during a relatively short pulse between the Early and Middle Ordovician (472-465 Ma). The entire zircon population for the four plutonic rocks yields coherent εHf negative values and spreads over several ranges of initial εHf(t) units (-0.3 to -8.0). The range of εHf units in detrital zircons of Famatinian metasedimentary rocks reflects a prolonged history of the cratonic sources during the Proterozoic to the earliest Phanerozoic. Typical tonalites and granodiorites that contain zircons with evolved Hf isotopic compositions formed upon incorporating (meta)sedimentary materials into calc-alkaline metaluminous magmas. The evolved Hf isotope ratios of zircons in the subduction related plutonic rocks strongly reflect the Hf isotopic character of the metasedimentary contaminant, even though the linked differentiation and growth of the Famatinian arc crust was driven by ascending and evolving mantle magmas. Geochronology and Hf isotope systematics in plutonic zircons allow us understanding the petrogenesis of igneous series and the provenance of magma sources. However, these data could be inadequate for computing model ages and supporting models of crustal evolution.

  9. Characterization and zircon SHRIMP U-Pb geochronology of the subvolcanic rocks from Yarumalito Porphyry System, Marmato District, Colombia; Caracterizacao e geocronologia SHRIMP U-Pb em zircao das rochas subvulcanicas do sistema porfiro Yarumalito, Distrito de Marmato, Colombia

    Energy Technology Data Exchange (ETDEWEB)

    Henrichs, Isadora A.; Frantz, Jose Carlos; Marques, Juliana C.; Castoldi, Marco S., E-mail:, E-mail:, E-mail: [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil). Instituto de Geociencias; Ordonez-Carmona, Oswaldo, E-mail: [Universidad Nacional de Colombia, Medellin (Colombia). Facultad de Minas; Sato, Kei, E-mail: [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Centro de Pesquisas Geocronologicas


    The mining District of Marmato, located in the Central Cordillera, is considered one of the oldest gold districts in Colombia and its exploration dates back to the Inca’s times, being exploited regularly for more than a thousand years. Inserted in this context lies the Yarumalito porphyry system (YPS), characterized to concentrate ore in structure related veins and stockworks. The YPS is related to the Miocene magmatism of the Combia Formation. In this paper, the subvolcanic rocks directly associated with the mineralized zones were described in order to obtain U-Pb ages in zircon to the intrusions. Selected samples from two fertile intrusions, one andesitic (more abundant in the area) and other dioritic (more restricted), were carefully described and dated by SHRIMP. The results points to a very restricted interval for the ages, with weighted average {sup 206}Pb/{sup 238}U varying from 7,00 ± 0,15 Ma for the andesitic porphyry and 6.95 ± 0.16 Ma for the dioritic porphyry. These results constrain the Yarumalito system to the final stages of the Combia magmatism and suggest a brief period for the crystallization of the mineralized subvolcanic rocks in the area and in the Marmato District. (author)

  10. The Proterozoic of NW Mexico revisited: U-Pb geochronology and Hf isotopes of Sonoran rocks and their tectonic implications (United States)

    Solari, L. A.; González-León, C. M.; Ortega-Obregón, C.; Valencia-Moreno, M.; Rascón-Heimpel, M. A.


    Several Proterozoic basement units crop out in the Sonora State of NW Mexico, and the same can be correlated with crustal provinces of southern Laurentia in the neighboring southwestern USA. Zircon U-Pb and Hf isotopic determinations in more than 300 grains separated from igneous and metaigneous rocks from these units indicate that the crystalline basement in Sonora is made up of different components, which are from west to east: (1) The Caborca-Mojave province to the west, characterized by the so-called Bámori Complex, have U-Pb ages between 1696 and 1772 Ma, with moderately juvenile to slightly evolved ɛHf values, yielding T DM ages of ca. 2.1-2.4 Ga; (2) in the intermediate area, east of Hermosillo, the Palofierral and La Ramada orthogneiss units yield an age of 1640 and 1703 Ma, respectively, both having juvenile ɛHf with the Palofierral overlapping the depleted mantle curve at ca. 1.65 Ga; and (3) in the northeastern Sonora, samples from the southern extension of the Mazatzal province, represented by the Pinal Schist, yielded ages between 1674 and 1694 Ma, with moderately juvenile to juvenile ɛHf values and a T DM age of ca. 1.9 Ga. In addition, a suite of post-tectonic granites was also studied in Caborca (San Luis granite) as well as in northeastern Sonora (Cananea granite), both yielding ages of ca. 1.44 Ga with moderately juvenile ɛHf values ranging from -1 to +8 and T DM dates of ca. 1.8-1.9 Ga and 1.6-1.7 Ga, respectively. These two isotopically contrasting provinces may imply the existence of a Proterozoic paleo-suture. However, if the Palofierral gneiss, of which the Hf signature straddles the depleted mantle array, is taken as the source for the 1.44 Ga Cananea granite, then the location of such a suture zone should lay farther south than the proposed trace of the Mojave-Sonora megashear.

  11. U-Pb SHRIMP geochronology and trace-element geochemistry of coesite-bearing zircons, North-East Greenland Caledonides (United States)

    McClelland, W.C.; Power, S.E.; Gilotti, J.A.; Mazdab, F.K.; Wopenka, B.


    Obtaining reliable estimates for the timing of eclogite-facies metamorphism is critical to establishing models for the formation and exhumation of high-pressure and ultrahigh-pressure (UHP) metamorphic terranes in collisional orogens. The presence of pressure-dependent phases, such as coesite, included in metamorphic zircon is generally regarded as evidence that zircon growth occurred at UHP conditions and, ifdated, should provide the necessary timing information. We report U-Pb sensitive high-resolution ion microprobe (SHRIMP) ages and trace-element SHRIMP data from coesite-bearing zircon suites formed during UHP metamorphism in the North- East Greenland Caledonides. Kyanite eclogite and quartzofeldspathic host gneiss samples from an island in J??kelbugt (78??00'N, 18??04'W) contained subspherical zircons with well-defined domains in cathodoluminescence (CL) images. The presence of coesite is confirmed by Raman spectroscopy in six zircons from four samples. Additional components of the eclogite-facies inclusion suite include kyanite, omphacite, garnet, and rutile. The trace-element signatures in core domains reflect modification of igneous protolith zircon. Rim signatures show flat heavy rare earth element (HREE) patterns that are characteristic of eclogite-facies zircon. The kyanite eclogites generally lack a Eu anomaly, whereas a negative Eu anomaly persists in all domains of the host gneiss. The 207Pb- corrected 206Pb/238U ages range from 330 to 390 Ma for the host gneiss and 330-370 Ma for the kyanite eclogite. Weighted mean 206Pb/238U ages for coesite-bearing domains vary from 364 ?? 8 Ma for the host gneiss to 350 ?? 4 Ma for kyanite eclogite. The combined U-Pb and REE data interpreted in conjunction with observed CL domains and inclusion suites suggest that (1) Caledonian metamorphic zircon formed by both new zircon growth and recrystallization, (2) UHP metamorphism occurred near the end of the Caledonian collision, and (3) the 30-50m.y. span of ages

  12. Mineral equilibria and zircon, garnet and titanite U-Pb ages constraining the PTt path of granite-related hydrothermal systems at the Big Bell gold deposit, Western Australia (United States)

    Mueller, Andreas G.; McNaughton, Neal J.


    The Big Bell deposit (75 t gold) is located in a narrow spur of the Meekatharra greenstone belt, Yilgarn Craton, Western Australia. Two ore bodies are located in a calcic-potassic contact alteration zone overprinting lineated granodiorite dykes and amphibolite: almandine-cummingtonite-hornblende skarn (1-3 g/t Au, 1700 g/t As, 330 g/t W) and the muscovite-microcline gneiss (3-5 g/t Au, 580 g/t Sb, 620 g/t W) of the Main Lode. Genetic models vary from pre- to post-metamorphic replacement. Hornblende-plagioclase pairs in amphibolite constrain peak metamorphic temperature to 670 ± 50 °C. In contrast, garnet-biotite thermometry provides estimates of 578 ± 50 and 608 ± 50 °C for garnet-cordierite-biotite schist bordering the skarn and enveloping the Main Lode. Garnet-cordierite and garnet-hornblende pairs extend the range of fluid temperature to 540 ± 65 °C, well below peak metamorphic temperature. At 540-600 °C, the alteration assemblage andalusite + sillimanite constrains pressure to 300-400 MPa corresponding to 11-14 km crustal depth. Published U-Pb ages indicate that metamorphism took place in the aureole of the southeast granodiorite-tonalite batholith (2740-2700 Ma), followed by gold mineralization at 2662 ± 5 Ma and by the emplacement of biotite granite and Sn-Ta-Nb granite-pegmatite dykes at 2625-2610 Ma. Amphibolite xenoliths in granite northwest of the deposit record the lowest temperature (628 ± 50 °C), suggesting it lacks a metamorphic aureole. The rare metal dykes are spatially associated with epidote-albite and andradite-diopside skarns (≤1.5 g/t Au), mined where enriched in the weathered zone. We analysed hydrothermal zircon intergrown with andradite. Concordant U-Pb ages of 2612 ± 7 and 2609 ± 10 Ma confirm the presence of a second granite-related system. The zircons display oscillatory zoning and have low Th/U ratios (0.05-0.08). Low-Th titanite from an albite granite dyke has a concordant but reset U-Pb age of 2577 ± 7 Ma.

  13. New P-T and U-Pb constraints on Alpine Schist metamorphism in south Westland, New Zealand

    International Nuclear Information System (INIS)

    Scott, J.M.; Auer, A.; Muhling, J.R.; Czertowicz, T.A.; Cooper, A.F.; Billia, M.A.; Kennedy, A.K.


    Metamorphic mineral compositions of a staurolite-bearing greyschist from the middle reaches of the Moeraki River valley in south Westland reveal peak equilibration at c. 558±50 degrees C and c. 6.1±1.2 kbar. Two c. 83 Ma U-Pb monazite age populations from the cores of monazite-apatite-allanite-epidote corona structures in mylonitised schists from near Fox Glacier confirm that Alpine Schist metamorphism occurred during the Late Cretaceous. The published spread in Late Cretaceous metamorphic ages indicates that metamorphism was diachronous or was a protracted event. Further dating is required to pin down the cryptic transition into the Jurassic-Early Cretaceous metamorphosed Otago Schist, but the Alpine Schist must extend at least 11 km east of the Alpine Fault in south Westland and overprint the suture between the Pounamu and Rakaia terranes. The P-T-t results imply that the Late Cretaceous crust represented by portions of the Alpine Schist was probably of similar thickness to that beneath the Southern Alps today, but with dehydration and partial melting occurring near the base. The crust under Westland and Otago may be dry and therefore strong. (author).

  14. Zircon U-Pb dating of early Palaeozoic monzonitic intrusives from the Goonumbla area, New South Wales

    International Nuclear Information System (INIS)

    Butera, K.M.; Williams, I.S.; Blevin, P.L.; Simpson, C.J.


    Zircon U-Pb ages measured on four small intrusions into the succession of Ordovician volcanic rocks that hosts North Parkes Cu-Au mine northwest of Parkes. New South Wales. place limits on the age of the volcanic sequence. The basal Nelungaloo Volcanics are constrained by a cross-cutting monzodiorite to be ≥484.3 ± 2.9Ma (Early Ordovician). Similarly. the overlying basal Goonumbla Volcanics are constrained by another cross-cutting monzodiorite to be ≥450.8 ± 4.2Ma (Middle Ordovician). A later generation of monzonites intruded into the middle and upper Goonumbla Volcanics yield ages of 439.1 ± 4.5 and 438.9 ± 4.7 Ma (Siluro-Ordovician). These various ages are consistent with the ages of fossiliferous sediments within the volcanic sequence. and indicate that both the intrusive and volcanic rocks span an appreciable period of time-neither are the product of a single magmatic episode. Intrusion of the youngest monzonites and mineralisation was virtually contemporaneous. Copyright (2001) Geological Society of Australia

  15. Early cretaceous zircon SHRIMP U-Pb age of the trachyte and its significances of the Gan-Hang belt

    International Nuclear Information System (INIS)

    Liu Feiyu; Wu Jianhua; Liu Shuai


    The Shixi basin was located at Gan-Hang tectonic volcanic uranium deposit of rock-magma belt which belong to a part of the Mesozoic volcanic rocks in the northeastern of China. The appearance of the trachyte in Shixi basin have the majoy elements characteristic of the shoshonite series volcanic rocks. To determine the geological age of trachyte have very important significance on the geodynamics research and the study on the cause of uranium mineralization. The zircons of the trachyte have clear ring and high Th/U ratio which belong to the typical magmatic zircons. The zircon SHRIMP U-Pb dating resules show that 14points' age range is very smaller is 132-144 Ma and the weighted average age is (137.00±0.94)Ma which represents the diagenetic age of volcanic rocks. Accronding to the latest International Stratigraphic Chart the boundary of Jurassic and Cretaceous is (145.4±4.0)Ma. So the trachyte of Shixi Group belong to early Cretaceous. The large-scale acidic volcanic activity occurred in the Early Cretaceous in Southeastern China, and the Volcanic uranium deposit of Gan-Hang tectonic belt relate to Alkali metasomatism Uranium mineralization also occurred in the Early Cretaceous (120-130 Ma). The determined of trachyte in Shixi Group in the Early Cretaceous show that the acidic volcanic activity have connection with magma activity and the early Uranium mineralization consistent with the Alkali magma activity. (authors)

  16. Age of hydrothermal processes in the central iberian zone (Spain according TO U-Pb dating of cassiterite and apatite

    Directory of Open Access Journals (Sweden)

    Н. Г. Ризванова


    Full Text Available Results of isotope-geochemical studies by PbLS step-leaching method of cassiterite from greisens located in Logrosán granite massif (Central Iberian Zone, Spain and apatite from hydrothermal quartz-apatite vein on its exocontact indicate that in both cases a hydrothermal event is recorded in the interval of 114-126 Ma, which has been accompanied by lead supply. Within the limits of estimation error, the same age around 120 Ma corresponds to crystallization of hydrothermal apatite, formation of sticks and micro-inclusions in cassiterite from greisens and is suggested for Au-As-Sb-Pb ore mineralization, which calls for further confirmation. Xenogenous zircon from quartz-apatite vein does not react to this relatively low-temperature hydrothermal event either with building up new generations (sticks, areas of recrystallization or with rebalancing of U-Pb isotope system. The age of greisen formation has been confirmed to be around 305 Ma by PbLS method on final phases of cassiterite leaching. Earlier it was estimated with 40Ar/39Ar method on muscovite.

  17. Isotopic (U-Pb, Nd) and geochemical constraints on the origins of the Aileu and Gondwana sequences of Timor (United States)

    Boger, S. D.; Spelbrink, L. G.; Lee, R. I.; Sandiford, M.; Maas, R.; Woodhead, J. D.


    Detrital zircon U-Pb age data collected from the argillitic sedimentary rocks of the Timorese Aileu Complex and Gondwana Sequence indicate that both units were derived from a common source containing 200-600 Ma, 900-1250 Ma and 1450-1900 Ma zircon. The modally most significant age population within this range of ages dates to c. 260 Ma. The observed spectrum of ages can be traced to the eastern active margin of Pangaea and its immediate foreland, which today is best exposed along the northeast coast of Australia. Compared to the relative homogeneity of the detrital zircon age data, geochemical and Nd isotopic data show that the mudstones of the Aileu Complex are on average more siliceous, have higher K2O/Na2O, Rb/Sr, Th/Sc and yield notably older Nd TDM model ages when compared to those from the Gondwana Sequence. These data are interpreted to suggest that, although both sequences share a common east Pangaea provenance, they were eroded from different sections of this active margin and deposited in spatially separated basins. The present proximity of these units is a result of their tectonic juxtaposition during the Pliocene to Recent collision between the northern edge of the Indo-Australia plate and the Banda Arc.

  18. SHRIMP zircon U-Pb ages and tectonic implications of igneous events in the Ereendavaa metamorphic terrane in NE Mongolia (United States)

    Miao, Laicheng; Zhang, Fochin; Baatar, Munkhtsengel; Zhu, Mingshuai; Anaad, Chimedtseren


    The Ereendavaa metamorphic terrane in NE Mongolia has long been considered as a Pre-Altaid block or a Precambrian cratonic terrane with a Paleoproterozoic basement overlain by Neoproterozoic-Cambrian rocks, but the idea has not been supported by any isotopic dating. Sensitive high resolution ion microprobe (SHRIMP) zircon U-Pb dating on gneisses, amphibolite and schists (mylonites) of the Ereendavaa terrane suggests that the terrane mainly formed during Early Paleozoic (495-464 Ma) and Late Paleozoic-Early Mesozoic (295-172 Ma). A minor amount of Precambrian rocks might have been involved in the formation of the protoliths of these rocks, as shown by Precambrian inherited zircons (1796-794 Ma). The new age data also suggest that the Ereendavaa terrane experienced at least two periods of magmatism: (1) Early Paleozoic (495-464 Ma) and (2) Late Paleozoic-Early Mesozoic (295-172 Ma), which are probably produced by the subduction of the Paleo Asian Ocean in the south and the subduction of the Mongol-Okhotsk Ocean in the north, respectively. The mylonitized granite (172 Ma) and undeformed pegmatite (163 Ma) are interpreted to be syn- and post-kinematic products. The new age data constrain the closure of the Mongol-Okhotsk Ocean at mid-Jurassic.

  19. U Pb zircon and monazite geochronology of Variscan magmatism related to syn-convergence extension in Central Northern Portugal (United States)

    Valle Aguado, B.; Azevedo, M. R.; Schaltegger, U.; Martínez Catalán, J. R.; Nolan, J.


    The Viseu area is located in the Central Iberian Zone of the Iberian Variscan Belt and hosts numerous post-thickening, collision-related granitoids intruded into upper and middle crustal levels. The present paper reports high precision U-Pb zircon and monazite ages for four plutons of the Viseu area: the syn-kinematic granitoids of Maceira (314±5 Ma), Casal Vasco (311±1 Ma) and Junqueira (307.8±0.7 Ma) and the late-kinematic biotite monzogranites of Cota (306±9 Ma). This points to a synchronous emplacement of the different syn-kinematic plutons shortly followed by the intrusion of the late-kinematic granites and shows that the Upper Carboniferous plutonism occurred within a short time span of ca. 10 million years. The ascent of granite magmas took place after an extensional tectonic event (D 2) and is coeval with dextral and sinistral crustal-scale transcurrent shearing (D 3). Field and petrographical evidence suggest a narrow time-span between peak T metamorphic conditions and the intrusion of granitic melts which implies very fast uplift rates accommodated through active tectonic exhumation. Magma compositions evolve through time, reflecting an increasing involvement of mid-crustal sources and the underplating effect of an upwelling asthenospheric mantle at the base of a thinning and stretching continental crust.

  20. Scanning ion imaging - a potent tool in SIMS U -Pb zircon geochronology (United States)

    Whitehouse, M. J.; Fedo, C.; Kusiak, M.; Nemchin, A.


    The application of high spatial resolution (spot analyses may yield uninterpretable and/or meaningless mixed ages by inadvertent sampling across regions with real age differences. Scanning ion imaging (SII) has the potential to generate accurate and precise geochrono-logical data with a spatial resolution down to ca. 2 μm, much higher than that of a normal spot analysis. SII acquisition utilises a rastered primary beam to image an area of the sample with a spatial resolution dependent on the selected primary beam diameter. On the Cameca ims1270/80 instruments, the primary beam scanning is coupled with the dynamic transfer optical system (DTOS) which deflects the secondary ions back on to the ion optical axis of the instrument regardless of where in the raster illuminated area the ions originated. This feature allows retention of a high field magnification (= high transmission) mode and the ability to operate the mass spectrometer at high mass resolution without any compromise in the quality of the peak shape. Secondary ions may be detected either in a sequential (peak hopping) mono-collection mode or simultaneous multicollection mode using low-noise pulse counting electron multipliers. Regardless of the detection mode, data are acquired over sufficient cycles to generate usable counting statistics from selected sub-areas of the image. In two case studies from southern west Greenland and Antarctica, Pb-isotope maps gen-erated using SII reveal considerable complexities of internal structure, age and isotope systematics that were not predictable from CL imaging of the grains (Fig. 1). Fig. 1. Scanning ion images of the 207Pb/206Pb ratio in zircons from (a) W. Greenland and (b) Antarctica (inset shows rastered area of grain corresponding to the image).

  1. U-Pb zircon, geochemical and Sr-Nd-Hf-O isotopic constraints on age and origin of the ore-bearing intrusions from the Nurkazgan porphyry Cu-Au deposit in Kazakhstan (United States)

    Shen, Ping; Pan, Hongdi; Seitmuratova, Eleonora; Jakupova, Sholpan


    Nurkazgan, located in northeastern Kazakhstan, is a super-large porphyry Cu-Au deposit with 3.9 Mt metal copper and 229 tonnage gold. We report in situ zircon U-Pb age and Hf-O isotope data, whole rock geochemical and Sr-Nd isotopic data for the ore-bearing intrusions from the Nurkazgan deposit. The ore-bearing intrusions include the granodiorite porphyry, quartz diorite porphyry, quartz diorite, and diorite. Secondary ion mass spectrometry (SIMS) zircon U-Pb dating indicates that the granodiorite porphyry and quartz diorite porphyry emplaced at 440 ± 3 Ma and 437 ± 3 Ma, respectively. All host rocks have low initial 87Sr/86Sr ratios (0.70338-0.70439), high whole-rock εNd(t) values (+5.9 to +6.3) and very high zircon εHf(t) values (+13.4 to +16.5), young whole-rock Nd and zircon Hf model ages, and consistent and slightly high zircon O values (+5.7 to +6.7), indicating that the ore-bearing magmas derived from the mantle without old continental crust involvement and without marked sediment contamination during magma emplacement. The granodiorite porphyry and quartz diorite porphyry are enriched in large ion lithophile elements (LILE) and light rare earth elements (LREE) and depleted in high-field strength elements (HFSE), Eu, Ba, Nb, Sr, P and Ti. The diorite and quartz diorite have also LILE and LREE enrichment and HFSE, Nb and Ti depletion, but have not negative Eu, Ba, Sr, and P anomalies. These features suggest that the parental magma of the granodiorite porphyry and quartz diorite porphyry originated from melting of a lithospheric mantle and experienced fractional crystallization, whereas the diorite and quartz diorite has a relatively deeper lithospheric mantle source region and has not experienced strong fractional crystallization. Based on these, together with the coeval ophiolites in the area, we propose that a subduction of the Balkhash-Junggar oceanic plate took place during the Early Silurian and the ore-bearing intrusions and associated Nurkazgan

  2. Petrogenesis of Jurassic tungsten-bearing granites in the Nanling Range, South China: Evidence from whole-rock geochemistry and zircon U-Pb and Hf-O isotopes (United States)

    Zhang, Yang; Yang, Jin-Hui; Chen, Jing-Yuan; Wang, Hao; Xiang, Yuan-Xin


    The Nanling Range (NLR) is the largest tungsten metallogenic province in China and perhaps in the world. The tungsten mineralization is believed to be related to Jurassic granitic magmatism. However, the petrogenesis of these granites and their relation to the tungsten mineralization are still debated. Whole-rock geochemical and Sr-Nd-Hf isotopic data and zircon in situ U-Pb ages and Hf-O isotopes are reported for W-bearing granitic intrusions from the southern Jiangxi Province in the NLR, in order to constrain their magmatic sources and petrogenesis. The NLR granites include biotite granites, two-mica granites and garnet muscovite granites. SIMS and LA-ICPMS U-Pb dating of zircons and monazites give emplacement ages of 161-154 Ma for these rocks. The granites are metaluminous to strongly peraluminous with high SiO2 (> 72.3 wt.%) and high K2O (> 3.7 wt.%). Petrographic and geochemical features show that they are highly fractionated I-type granites. The biotite granites are enriched in light rare earth elements (LREEs) relative to heavy REEs, have weakly negative Eu anomalies and are depleted in Nb, Ba, P and Ti. In contrast, the two-mica and garnet-bearing muscovite granites have tetrad-type REE patterns with strongly negative Eu anomalies and are extremely depleted in Ba, Nb, Sr, P and Ti. Magmatic garnets are mainly almandine and spessartine, and have low-Mn cores and high-Mn rims. Their (Y + HREE) contents are high and generally decrease from core (1.2 wt.%) to rim (average = 4955 ppm). All of these granites are characterized by variable whole-rock initial 87Sr/86Sr (0.7053-0.8000), εNd(t) (- 12.6 to - 9.4) and εHf(t) (- 12.3 to - 8.5), as well as variable zircon εHf(t) and δ18O, with values of - 16.3 to - 7.4 and 7.6 to 10.0‰, respectively. They contain abundant zircon xenocrysts and xenoliths of micaceous schist. All of these features are consistent with a process of crystal fractionation of crustally-derived magmas coupled with strong assimilation of

  3. Geologic evolution of the Paraiba do Sul complex, in the central part of the Ribeira belt, based on the geochemistry and U-Pb geochronology studies; Evolucao geologica do complexo Paraiba do Sul, no segmento central da faixa Ribeira, com base em estudos de geoquimica e geocronologia U-Pb

    Energy Technology Data Exchange (ETDEWEB)

    Valladares, Claudia Sayao


    Aiming the definition of the Complexo Paraiba do Sul evolution, the work presents a geochronological approach by the U-Pb method, considered appropriate to study polideformed terrains. The minerals used to the U-Pb dating (zircon, titanite and monazite) provides information about the ages of rock generation and the successive geological events the rocks were submitted. The U-Pb geochronological approach is pioneer in the investigated area and two questions referent to the Complexo Paraiba do Sul evolution in the central part of the Ribeira belt, were the aim of this approach. The first of them refers to the crystallization epoch and the gneisses metamorphism, interpreted here like orthogneisses, called Unidade Quirino of the Complexo Paraiba do Sul. The second refers to the metamorphism ages and meta sedimentary unit deformation. Looking for the contribution to the Complexo Paraiba do Sul evolution understanding, this work presents the data based on the geologic map of this area, comprising part of the Folha Volta Redonda (1:50.000), including petrographic, structural and microtectonic studies. It also presents and discusses the results of: 17 U-Pb analysis in zircon and titanite of the Complexo Paraiba do Sul orthogneisses collection; 24 geochemical analysis of major, minor, trace elements and ETR of the same collection; an U-Pb analysis in titanite of the Unidade Sao Joao, 5 U-Pb analysis in titanites and/or monazites of granites and granitoids; 12 geochemical analysis including major, minor and trace elements and ETR, in granites and sills of leucogranites. Finally, the data achieved were integrated with the objective to elaborate an evolutive view of the Complexo Paraiba do Sul 157 refs., 54 figs., 17 tabs.

  4. In situ sulfur isotopes (δ{sup 34}S and δ{sup 33}S) analyses in sulfides and elemental sulfur using high sensitivity cones combined with the addition of nitrogen by laser ablation MC-ICP-MS

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Jiali [State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074 (China); Hu, Zhaochu, E-mail: [State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074 (China); The Beijing SHRIMP Center, Institute of Geology, Chinese Academy of Geological Sciences, Beijing 102206 (China); Zhang, Wen [State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074 (China); Yang, Lu [State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074 (China); National Research Council Canada, 1200 Montreal Rd., Ottawa, Ontario K1A 0R6 (Canada); Liu, Yongsheng; Li, Ming; Zong, Keqing; Gao, Shan; Hu, Shenghong [State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074 (China)


    The sulfur isotope is an important geochemical tracer in diverse fields of geosciences. In this study, the effects of three different cone combinations with the addition of N{sub 2} on the performance of in situ S isotope analyses were investigated in detail. The signal intensities of S isotopes were improved by a factor of 2.3 and 3.6 using the X skimmer cone combined with the standard sample cone or the Jet sample cone, respectively, compared with the standard arrangement (H skimmer cone combined with the standard sample cone). This signal enhancement is important for the improvement of the precision and accuracy of in situ S isotope analysis at high spatial resolution. Different cone combinations have a significant effect on the mass bias and mass bias stability for S isotopes. Poor precisions of S isotope ratios were obtained using the Jet and X cones combination at their corresponding optimum makeup gas flow when using Ar plasma only. The addition of 4–8 ml min{sup −1} nitrogen to the central gas flow in laser ablation MC-ICP-MS was found to significantly enlarge the mass bias stability zone at their corresponding optimum makeup gas flow in these three different cone combinations. The polyatomic interferences of OO, SH, OOH were also significantly reduced, and the interference free plateaus of sulfur isotopes became broader and flatter in the nitrogen mode (N{sub 2} = 4 ml min{sup −1}). However, the signal intensity of S was not increased by the addition of nitrogen in this study. The laser fluence and ablation mode had significant effects on sulfur isotope fractionation during the analysis of sulfides and elemental sulfur by laser ablation MC-ICP-MS. The matrix effect among different sulfides and elemental sulfur was observed, but could be significantly reduced by line scan ablation in preference to single spot ablation under the optimized fluence. It is recommended that the d{sub 90} values of the particles in pressed powder pellets for accurate

  5. In situ sulfur isotopes (δ34S and δ33S) analyses in sulfides and elemental sulfur using high sensitivity cones combined with the addition of nitrogen by laser ablation MC-ICP-MS

    International Nuclear Information System (INIS)

    Fu, Jiali; Hu, Zhaochu; Zhang, Wen; Yang, Lu; Liu, Yongsheng; Li, Ming; Zong, Keqing; Gao, Shan; Hu, Shenghong


    The sulfur isotope is an important geochemical tracer in diverse fields of geosciences. In this study, the effects of three different cone combinations with the addition of N 2 on the performance of in situ S isotope analyses were investigated in detail. The signal intensities of S isotopes were improved by a factor of 2.3 and 3.6 using the X skimmer cone combined with the standard sample cone or the Jet sample cone, respectively, compared with the standard arrangement (H skimmer cone combined with the standard sample cone). This signal enhancement is important for the improvement of the precision and accuracy of in situ S isotope analysis at high spatial resolution. Different cone combinations have a significant effect on the mass bias and mass bias stability for S isotopes. Poor precisions of S isotope ratios were obtained using the Jet and X cones combination at their corresponding optimum makeup gas flow when using Ar plasma only. The addition of 4–8 ml min −1 nitrogen to the central gas flow in laser ablation MC-ICP-MS was found to significantly enlarge the mass bias stability zone at their corresponding optimum makeup gas flow in these three different cone combinations. The polyatomic interferences of OO, SH, OOH were also significantly reduced, and the interference free plateaus of sulfur isotopes became broader and flatter in the nitrogen mode (N 2  = 4 ml min −1 ). However, the signal intensity of S was not increased by the addition of nitrogen in this study. The laser fluence and ablation mode had significant effects on sulfur isotope fractionation during the analysis of sulfides and elemental sulfur by laser ablation MC-ICP-MS. The matrix effect among different sulfides and elemental sulfur was observed, but could be significantly reduced by line scan ablation in preference to single spot ablation under the optimized fluence. It is recommended that the d 90 values of the particles in pressed powder pellets for accurate and precise S isotope

  6. Testing the age calibration of the Newark-Hartford APTS by magnetostratigraphic correlation of U-Pb zircon-dated tuffaceous beds in the Late Traissic Chinle Formation in core PFNP-1A from the Petrified Forest National Park (Arizona, USA) (United States)

    Kent, D. V.; Olsen, P. E.; Mundil, R.; Lepre, C. J.


    endemic taxa in continental deposits are more likely a reflection of demonstrated continental drift across climate belts and the misinterpretation of ecostratigraphy as chronostratigraphy. A suite of new U-Pb dates in conjunction with paleomagnetic analyses in PFNP-1A is expected to calibrate much of Triassic succession of the Colorado Plateau.

  7. Geochemistry and Geochronology U-Pb SHRIMP of granites from Peixoto de Azevedo: Alta Floresta Gold Province; Geoquimica e geocronologia U-Pb (SHRIMP) de granitos da regiao de Peixoto de Azevedo: Provincia Aurifera Alta Floresta, MT

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Fernanda Rodrigues da; Barros, Marcia Aparecida Sant' Ana; Pierosan, Ronaldo; Pinho, Francisco Edigio Cavalcante; Tavares, Carla; Rocha, Jhonattan, E-mail:, E-mail:, E-mail:, E-mail:, E-mail:, E-mail: [Universidade Federal de Mato Grosso (UFMT), Cuiaba, MT (Brazil). Inst. de Ciencias Exatas e da Terra; Rocha, Mara Luiza Barros Pita; Vasconcelos, Bruno Rodrigo; Dezula, Samantha Evelyn Max, E-mail:, E-mail:, E-mail: [Universidade de Brasilia (UNB), Brasilia, DF (Brazil). Programa de Pos-Graduacao em Geologia


    The analysis of petrographic, geochemical and geochronological data of granites in the Peixoto de Azevedo region, Mato Grosso, Brazil, in the eastern portion of the Alta Floresta Gold Province, led to the recognition of two granitic bodies bounded by regional major faults and shear zones. In the northwestern portion a body with featured as biotite granodiorite, coarse-grained, with porphyritic to inequigranular texture, metaluminous to peraluminous, high-K calc-alkaline and magnesium character. In the southeastern portion of the area, a biotite monzogranite coarse-grained, with equigranular to porphyritic texture, slightly peraluminous, high-K calc-alkaline and dominantly of ferrous character. U- Pb dating (SHRIMP) showed that the biotite monzogranite has an age of 1869 ± 10 Ma, similar to the Matupa Intrusive Suite, while the biotite granodiorite has an age of 1781 ± 10 Ma, that is the age expected to Peixoto Granite. Both units show patterns of rare earth elements with enrichment of light over heavy and negative Eu anomaly (La{sub N}/Yb{sub N} » 7.6 to 17.31 and ratios Eu/EU{sup ⁎} between 0.46 – 0.72 for biotite monzogranite and La{sub N}/Yb{sub N} » 7.13 to 29.09 with ratios Eu/Eu{sup ⁎} between 0.25 - 0.40 for the biotite granodiorite). Trace elements pattern for both present negative anomalies of Ba, P, Ti and Nb indicating an evolution from mineral fractionation and subduction related sources. In this paper, it is suggested that the monzogranite Matupa was developed in mature arc tectonic environment. For the Peixoto Granite, two hypotheses are suggested: (a) it was developed in younger magmatic arc environment associated with the Colider Magmatism or (b) it was generated in extensional tectonic environment during the Columbia Super continent break up. (author)

  8. Geochronology of the Archaean Kolmozero-Voron'ya Greenstone Belt: U-Pb dating of zircon, titanite, tourmaline and tantalite (Kola Region, North-Eastern BAltic Shield) (United States)

    Kudryashov, N.; Gavrilenko, B.; Apanasevich, E.


    The Archaean Kolmozero-Voron’ya greenstone belt is one of the most ancient geological structures of the Kola Peninsula. It is located between Upper Archaean terrains: Murmansk, Central Kola and Keivy. Within the Kolmozero-Voron'ya greenstone belt there are rare metal (Li, Cs with accessory Nb, Ta, and Be), Cu, Mo, and Au deposits. All rocks were metamorphosed under amphibolite facies conditions and intruded by granodiorites, plagiomicrocline and tourmaline granites and pegmatite veins. Four suites are distinguished within the belt: lower terrigenous formation, komatiite-tholeite, basalt-andesite-dacite and upper terrigenous formation. The U-Pb age of 2925±6 Ma on magmatic zircon was obtained for leucogabbro of differentiated gabbro-anorthosite massif Patchemvarak, situated at the boundary between volcanic-sedimentary units and granitoids of the Murmansk block. This age is the oldest for gabbro-anorthosites of the Kola Peninsula. Sm-Nd age of komatiites is ca. 2.87 Ga (Vrevsky, 1996). U-Pb age of zircon from biotite schist, which belongs to acid volcanites is 2865+/-5 Ma. Quartz porphyries, which are considered to be an intrusive vein analogous of acid volcanites has an age of 2828+/-8 Ma, that marks the final stage of the belt development. Dating of titanite from ovoid plagioamphibolites yielded an U-Pb age of 2595+/-20 Ma that probably is connected with the closure of the U-Pb isotopic titanite system during the regional metamorphism. The Porosozero granodioritic complex with an age of 2733+/-6 Ma is located between granites of the Murmansk domain, migmatites and gneisses of the Central Kola terrain and the Keivy alkaline granites. Tourmaline granites are found all over the Kolmozero-Voron’ya belt occurring among volcanogenic-sedimentary rocks of the belt. Their Pb-Pb age of 2520+/-70 Ma appears to denote the tourmaline crystallization at a post-magmatic stage of the complex formation. U-Pb zircon age from rare metal pegmatites is 1.9-1.8 Ga. Zircons from

  9. U-Pb and Lu-Hf systematics of zircons from Sargur metasediments, Dharwar Craton, Southern India: new insights on the provenance and crustal evolution

    International Nuclear Information System (INIS)

    Maibam, Bidyananda; Gerdes, Axel; Srinivasan, R.; Goswami, J.N.


    A study of U-Pb and Lu-Hf-Yb isotope data in zircons from metamorphosed psammopelite and quartzite from the type area of Archaean Sargur Group, Dharwar Craton, India is carried out. Two age populations are observed: an older population with concordant U-Pb ages between 2.7 and 2.8 Ga, and a younger population with ages in the 2.4 - 2.6 Ga age range. The εHf values of 0 to + 2.0 for the older zircon population suggest that they were derived from juvenile crust formed at 2.7- 2.8 Ga. Sub-chondritic εHf values for the younger population indicate metamorphism and/or crustal reworking at ∼2.5 Ga. Meta-sedimentary enclaves in the Sargur type area are therefore part of the gneiss-supracrustal complex of different antiquities and may not have an independent stratigraphic status. (author)

  10. New U-Pb ages from dykes cross-cutting the Demirci metamorphics, NW Turkey: Implications for multiple orogenic events (United States)

    Sen, Fatih; Koral, Hayrettin; Peytcheva, Irena


    A high-grade metamorphic sequence in the Sünnice Mountains, Bolu, NW Turkey, is represented by migmatitic quartzo-feldspathic gneisses in amphibolite facies called the Demirci metamorphics/paragneisses, and a sequence of low-grade meta-volcanics containing meta-andesites with minor meta-rhyolites and meta-sedimentary rocks called the Yellice meta-volcanics. They are intruded by the Dirgine granite with an age of Upper Ediacaran (576-565 Ma) and are considered a part of the İstanbul-Zonguldak Tectonic Unit. The Demirci paragneisses are also intruded by a number of dykes in various directions, traditionally considered without radiometric dating to have been emplaced in a single magmatic phase in the Eocene related to post-collision regime of the Anatolide-Tauride platform. Mafic-intermediate-felsic dykes cross-cutting the Demirci paragneisses have been investigated in maps of 1/1000 scale, and their U-Pb zircon age, major-trace element and kinematic data have been obtained. The mafics dykes cross-cutting the Yellice meta-volcanics, equivalents of those in the Demirci paragneisses, occur in N400-500E orientations and have calc-alkaline basalt compositions with a subduction signature. The intermediate dykes occur in N650W, N800W orientations and have calc-alkaline basaltic andesite to andesitic compositions with a subduction signature. Some felsics occur in N150W and N800E orientations and have calc-alkaline dacitic compositions with a collisional tectonic setting. Other calc-alkaline granitic dykes occur in N750E orientation and calc-alkaline granitic compositions with a subduction signature. U-Pb LA-ICP-MS dating of zircons yield ages from 485.7±3.6 Ma (i.e. Cambro-Ordovician) for N800E trending dacite dykes; 443.0±5.4 Ma (i.e. Ordovician-Silurian) for N150W trending dacite dykes; 301.0±1.6 Ma (i.e. Upper Pennsylvanian-Carboniferous) for N650W trending basaltic andesite dykes; 268.2±2.4 Ma (i.e. Guadalupian-Permian) for N40-500E trending basalt dykes; 262.9±3

  11. 1,100,000 year history of Siberian permafrost based on U-Pb chronology of speleothems (United States)

    Vaks, Anton; Mason, Andrew J.; Breitenbach, Sebastian F. M.; Kononov, Alexander M.; Osintcev, Alexander V.; Henderson, Gideon M.


    We have used U-Pb dating of the speleothems from Siberian Ledyanaya Lenskaya Cave for tracing of permafrost thawing events during the last 1.1 million years. Rain and snowmelt waters can penetrate into caves only when the soil and subsoil temperatures are above 0° C and permafrost above the cave is discontinuous or absent. Therefore, speleothems in regions currently affected by permafrost provide a tracer of past permafrost thawing events. Ledyanaya Lenskaya Cave is located at 60° 22'N-116° 57'E, on the southern boundary of continuous permafrost zone, with no present-day water seepage in the cave. Temperatures in the region range from -32° C (January) to +18° C (July), with mean annual temperature of ~-6° C. U-Th dating of speleothems from this cave in a previous study [1] showed that the youngest speleothem growth period occurred at 427±23 thousand years ago (ka), during the early Marine Isotope Stage (MIS) 11. During this episode global temperature was 1.5° C higher than pre-industrial levels, and ~0.7° C above the present. In the current study two horizons at the base of a stalagmite were dated using U-Pb chronology [2]. Isochron ages of 1074.1 +7.9/-6.9 ka and 951.4 +3.6/-4.4 ka were obtained. Timing of these permafrost thawing events correlates with events of exceptionally high Pacific Warm Pool sea surface temperature (~+30° C)[3]. During these warm episodes the average global temperature was 1.2-1.3° C higher than pre-industrial temperatures. These findings put the threshold of thawing of the continuous permafrost near its southern boundary slightly lower than it was found previously. The dating work is still in process and is now focusing on growth periods older than MIS-11 but younger than 950 ka. The oldest horizon of the stalagmite grew on the bedrock. This layer was probably amongst the first vadose speleothems that formed after the cave was uplifted above the groundwater table (associated with the nearby Lena River). Today the cave is ~50

  12. U-Pb aging of the sodalite-syenite (Blue-Bahia) mineralization in the Lichfield stock of Itaju do Colonia, southern Bahia, Brazil

    International Nuclear Information System (INIS)

    Rosa, Maria de Lourdes da Silva; Marinho, Moacyr Moura


    The Litchfieldite Stock of Itaju do Colonia is one of the intrusions from the Alkaline Province of the South Bahia State, which host the blue coloured sodalite-syenite ore. The U-Pb isotopic results for titanite from the sodalite-syenites of this complex yield an age of 732 ± 8 Ma, which is interpreted as the crystallization age for the blue-sodalite-ore. (author)

  13. A Modern Analog to the Depositional Age Problem: Zircon and Apatite Fission Track and U-Pb Age Distributions by LA-ICP-MS (United States)

    Donelick, H. M.; Donelick, M. B.; Donelick, R. A.


    Sand from three river systems in North Idaho (Snake River near Lewiston, Clearwater River near Lewiston and the Salmon River near White Bird) and two regional ash fall events (Mt. Mazama and Mt. St. Helens) were collected for zircon U-Pb detrital age analysis. Up to 120 grains of zircon per sample were ablated using a Resonetics M-50 193 nm ArF Excimer laser ablation (LA) system and the Pb, Th, and U isotopic signals were quantified using an Agilent 7700x quadrupole inductively coupled plasma-mass spectrometer (ICP-MS). Isotopic signals for major, minor, and trace elements, including all REEs, were also monitored. The youngest zircon U-Pb ages from the river samples were approximately 44 Ma; Cenozoic Idaho Batholith and Precambrian Belt Supergroup ages were well represented. Significant common Pb contamination of the Clearwater River sample (e.g., placer native Cu was observed in the sample) precluded detailed analysis of the zircon U-Pb ages but no interpretable ages Mazama 7,700 years ago, and no doubt other events during the Quaternary. Work currently in progress seeks to address bias against near 0 Ma ages in the catchment areas due to: a) small, local ash fall grain sizes and b) overwhelming number of older grains relative to the ash fall grains. Data from Mt. St. Helens ash from several localities near the mountain (Toutle River and Maple Flats, WA) and several far from the mountain (Spokane, WA; Princeton, ID; Kalispell, MT) and Mt. Mazama ash fall deposits near Lewiston, ID and Spokane, WA will be presented to address these possibilities. Additionally, fission track and U-Pb ages from apatites collected from these river and ash fall samples will also be shown to help constrain the problem.

  14. Fossil pollen analysis of U-Pb-dated speleothems: a new approach to understanding Pliocene terrestrial climate evolution (United States)

    Sniderman, K.; Woodhead, J. D.; Porch, N.


    The nature of terrestrial environments in the Southern Hemisphere during the warm Pliocene is poorly known. This is not only because there are few published fossil records, but also because many of the existing records have very limited age control. For example, in Australia, the ages of most putative 'mid-Pliocene' fossil pollen records are based solely on biostratigraphic correlation. These correlations for the most part do not have the resolution to differentiate late Miocene from early Pliocene environments, let alone to pinpoint a Myrtaceae, with no sign of extensive cheonopod shrubland. Climate reconstructions based on presence of taxa now absent from the Nullarbor suggest that mean annual rainfall and/or summer rainfall were 50-100% higher than today. Second, vegetation near the Miocene/Pliocene boundary (at c. 5.5 Ma) was dominated by Gyrostemonaceae and Casuarinaceae. We interpret this transition from earliest Pliocene to mid-late Pliocene vegetation as an increase in biological productivity, from possibly very sparse woodland to forest, presumably in response to increased effective moisture in the mid-late Pliocene. Hence climate evolution within the Pliocene was substantial enough to drive complete biome turnover. Explanations of the mechanisms that drove Pliocene warmth thus need to explain not only why the Pliocene warm interval was terminated by Pleistocene cooling, but also why the mid-late Pliocene differed substantially from the earliest Pliocene. Our novel use of U/Pb dating of speleothem pollen records demonstrates that previous syntheses of 'mid-Pliocene' vegetation may, in regions with poor age control, have conflated biomes growing within different climatic regimes during different stages within the Pliocene.

  15. U-Pb zircon geochronology, Sr-Nd isotope geochemistry, and petrogenesis of oxidant granitoids at Keybarkuh, southwest of Khaf

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    Ehsan Salati


    Full Text Available Keybarkuh area is located 70 km southwest of Khaf, Khorasan Razavi province. The study area is situated in northeastern Lut block. The rock units in the area are Paleozoic metamorphic rocks and Cretaceous to Tertiary subvolcanic intrusions intruded as dike, stock and batholith; their composition varies from granite to diorite. Based on magnetic susceptibility, the intrusive rocks are divided into oxidant and reduced series. In this study, the oxidant intrusions are discussed. These intrusions are mostly high-K to shoshonitic and also meta-aluminous type. Their magma formed in subduction magmatic arc and they belong to I-type granitoid series. Enrichment of Large Ion Lithophile Elements (LILE such as Rb, Cs, K, Ba, and Th relative to High Field Stength Elements (HFSE such as Nb, Zr, and Ti supported the idea. Enrichment of Light Rare Earth Elements (LREE and depletion of Heavy Rare Earth Elements (HREE are also typical of subduction magmatism. Negative anomalies of Eu/Eu* can be attributed to the presence of residual plagioclase in a mantle source and contamination of magma by reduced continental crust. The amount of Nb > 11 ppm, lower ratio of Zr/Nb 0.706, initial 143Nd/144Nd (> 0.512 and εNd (< -3.5 indicate that magma contaminated by reduced continental crust. Hornblende biotite granodiorite porphyry dated using U-Pb zircon geochronology at 43.44 Ma (Middle Eocene. Based on calculated TDM, magma derived from ancient slab with 820 Ma age in the Keybarkuh area, was affected by the highest continental crust contamination during its ascent.

  16. Zircon U-Pb geochronology and emplacement history of intrusive rocks in the Ardestan section, central Iran

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    Sarjoughian, F.; Kananian, A.


    The Urumieh-Dokhtar Magmatic Arc (UDMA) is part of the Alpine–Himalayan orogenic belt and interpreted to be a subduction-related Andean-type magmatic arc. Along this belt, Eocene volcanics and some gabbroic to granitic bodies crop out. The main rock types of the studied intrusion are granite, granodiorite, and diorite. They have geochemical features typical of magnesian, calc-alkaline, metaluminous to slightly peraluminous granites and I-type intrusive rock that have a strong enrichment in Large-Ion Lithophile (LIL) elements (e.g. Rb, Ba, Sr), and a depletion in High Field Strength (HFS) elements (e.g. Nb, Ti, P), typical of subduction-related magmas. Zircon U-Pb dating was applied to determine the emplacement ages of the different intrusions in the Ardestan area. Among them the Kuh-e Dom diorite is 53.9±0.4Ma old; the Kuh-e Dom granodiorite is 51.10±0.4Ma old; the Mehrabad granodiorite is 36.8±0.5Ma old, the Nasrand granodiorite is 36.5±0.5Ma old, the Zafarghand granodiorite is 24.6±1.0Ma old, and the Feshark granodiorite is 20.5±0.8Ma old. These results delineate more accurately the magmatic evolution related to the Neotethyan subduction from the Lower Eocene to Lower Miocene, and the subsequent Zagros orogeny that resulted from the Arabia-Eurasia collision. The emplacement of these intrusive rocks inside the UDMA, which has a close relationship with the collisional orogeny, is transitional from a subduction-related setting to post-collisional setting in the Ardestan area.

  17. Coronitic metagabbro and eclogite from the Grenville Province of western Quebec: interpretation of U-Pb geochronology and metamorphism

    International Nuclear Information System (INIS)

    Indares, A.; Dunning, G.


    We present new U-Pb and metamorphic data on high-pressure coronitic metagabbros from three distinct structural settings in the Parautochthonous belt of the Grenville Province in western Quebec. Intrusive ages are (i) 1217 -10 +15 Ma, for metagabbro close to the Grenville Front, correlative with the Sudbury dykes, defined in Ontario; (ii) 1403 -11 +14 Ma for an eclogitized lens at the base of the highest structural level (SL4), a new age for mafic magmatism in the western Grenville; and (iii) 1218 -34 +53 Ma for metagabbro from SL4, interpreted as correlative with metagabbros from the Algonquin and Shawanaga domains in Ontario. Metamorphism in all cases is Grenvillian, with the best constrained age of 1069 ± 3 Ma for the metagabbro of SL4. Metamorphic grade increases from the Grenville Front to the south. The mafic rocks preserve relict igneous textures overprinted by garnet + clinopyroxene that developed as coronas and (or) pseudomorphs after igneous phases. The highest grade metagabbros contain omphacite and some lack primary plagioclase, therefore being eclogites. However, interpretation of textures and mineral chemistry indicates that they were equilibrated during decompression (at 1350 MPa and 720 o C, sample 51: and at 1200 MPa and 740 o C, sample 29), so maximum depths of burial remain unconstrained. Their evolution is interpreted as follows: (i) high-pressure metamorphism by burial of the Laurentian margin under accreted terranes thrust toward the northwest between 1080 and 1060 Ma; (ii) residence at intermediate crustal levels, for a few tens of millions of years; and (iii) rapid exhumation by renewed thrusting that led to the emplacement of the high-pressure units over the northerly adjacent structural units of the Parautochthonous Belt. (author)

  18. Calibrating the Cretaceous normal superchron with high-precision U-Pb zircon geochronology from Songliao Basin, NE China (United States)

    Wang, T.; Ramezani, J.; Wang, C.


    The Cretaceous Normal Superchron (CNS) or C34n is defined as the prolonged period of normal geomagnetic polarity, which lasted for approximately 38 Myr from the Aptian to the beginning of the Campanian. Along with the Kiaman Reverse Superchron (Carboniferous-Permian), they constitute the two longest periods of stability in the Earth's magnetic field. Polarity reversals are geologically abrupt events of global extent that form the basis of the Geomagnetic Polarity Timescale. In addition, a causal relationship between the end of a superchron and global environmental change has been hypothesized by some workers. Thus, the precise timing of the onset and termination of CNS has important implications for the correlation of global tectonic, paleoclimatic and paleobiotic events, and may help us better understand the causes and consequences of superchrons. At present, the exact age and duration of CNS are poorly understood, in part due to the relative scarcity of relevant paleomagnetic and radioisotopic data. The end of CNS or the C34n/C33r chron boundary is also considered a suitable proxy for the Santonian-Campanian stage boundary in the absence of diagnostic fossils of global distribution for the latter. The early Campanian ( 84 Ma to 76 Ma) is characterized by a steady cooling of the (greenhouse) climate, preceded by an abrupt (possibly 5-6°C) drop in the global temperatures at the Santonain-Campanian boundary, based on the oxygen isotope record of benthic foraminifera. The peak of dinosaur diversity throughout vast swaths of the continents was reached during the Campanian, as well. Here we present a new age constraint for the termination of CNS based on ash bed geochronology from a near-continuous, subsurface, Cretaceous lacustrine record recovered from the Songliao Basin in Northeast China. This extraordinary record allows integration of high-precision U-Pb geochronology, magnetostratigraphy and cyclostratigraphy that enables a multi-chronometer approach to the

  19. Zircon Geochronology (U-Pb, Petrography, Geochemistry and Radioisotopes of Bornaward Metarhyolites (Central Taknar Zone-Northwest of Bardaskan

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    Reza Monazzami Bagherzadeh


    Full Text Available Introduction The Bornaward area is located in the Northeastern Iran (in the Khorasan Razavi province 28 km northwest of the city of Bardaskan at 57˚ 46΄ to 57˚ 52΄ N latitude and 35˚ 21΄ to 35˚ 24΄E longitude. The Taknar structural zone, situated in the North central Iranian micro continent, is part of the Lut block (Forster, 1978. The Taknar zone is an allochthonous block bounded by the Darouneh and Taknar major faults. Much of this zone consists of metarhyolite-rhyodacite volcanic rocks, and rhyolitic tuff with interlayers of sandstone and dolomite (Taknar Formation. Analytical Results ICP-MS analysis of REE and minor elements of samples of the Bornaward metarhyolites was carried out at the ACME Laboratory in Vancouver, Canada. U-Pb dating of the metarhyolites was performed on isolated zircons in Crohn's Laser Lab, in Arizona (Gehrels et al., 2008. Measurement of Rb, Sr, Sm and Nd isotopes and (143Nd/144Ndi and (87Sr/86Sri ratios took place in the radioisotope laboratory of the University of Aveiro in Portugal. Petrography The volcanic rocks are porphyritic, commonly containing phenocrysts of orthoclase and rarely sanidine, quartz and intermediate plagioclase in a groundmass of fine-grained quartz and feldspar. An alteration has produced oriented needles of sericite and clay minerals, clusters of fine-grained green biotite and clots of epidote and chlorite. Geochemistry The compositions of the volcanic rocks are calc alkaline and high K- calc alkaline. The obtained Shand index (Al2O3/( CaO+Na2O+K2O is above 1.1, in the peraluminous S-type granite field (Chappell and White, 2001. Plotted on the TAS diagram (Middlemost, 1994, all the metarhyolite-rhyodacite samples are located in the sub-alkaline field and the majority fall into the rhyolite group. The metarhyolite-rhyodacites show enrichment of LREE with a moderately ascending pattern ((La/YbN=2.51-10.11 and La=46.45-145.48. Europium shows a negative anomaly (Eu/Eu*=0.23-0.71. U-Pb

  20. 40 Ma of hydrothermal W mineralization during the Variscan orogenic evolution of the French Massif Central revealed by U-Pb dating of wolframite (United States)

    Harlaux, Matthieu; Romer, Rolf L.; Mercadier, Julien; Morlot, Christophe; Marignac, Christian; Cuney, Michel


    We present U-Pb thermal ionization mass spectrometer (TIMS) ages of wolframite from several granite-related hydrothermal W±Sn deposits in the French Massif Central (FMC) located in the internal zone of the Variscan belt. The studied wolframite samples are characterized by variable U and Pb contents (typically <10 ppm) and show significant variations in their radiogenic Pb isotopic compositions. The obtained U-Pb ages define three distinct geochronological groups related to three contrasting geodynamic settings: (i) Visean to Namurian mineralization (333-327 Ma) coeval with syn-orogenic compression and emplacement of large peraluminous leucogranites (ca. 335-325 Ma), (ii) Namurian to Westphalian mineralization (317-315 Ma) synchronous with the onset of late-orogenic extension and emplacement of syn-tectonic granites (ca. 315-310 Ma) and (iii) Stephanian to Permian mineralization (298-274 Ma) formed during post-orogenic extension contemporaneous with the Permian volcanism in the entire Variscan belt. The youngest ages (276-274 Ma) likely reflect the reopening of the U-Pb isotopic system after wolframite crystallization and may correspond to late hydrothermal alteration (e.g. ferberitization). Our results demonstrate that W(±Sn) mineralization in the FMC formed during at least three distinct hydrothermal events in different tectono-metamorphic settings over a time range of 40 Ma.

  1. Controls on Cenozoic exhumation of the Tethyan Himalaya from fission-track thermochronology and detrital zircon U-Pb geochronology in the Gyirong basin area, southern Tibet (United States)

    Shen, Tianyi; Wang, Guocan; Leloup, Philippe Hervé; van der Beek, Peter; Bernet, Matthias; Cao, Kai; Wang, An; Liu, Chao; Zhang, Kexin


    The Gyirong basin, southern Tibet, contains the record of Miocene-Pliocene exhumation, drainage development, and sedimentation along the northern flank of the Himalaya. The tectonic controls on basin formation and their potential link to the South Tibetan Detachment System (STDS) are not well understood. We use detrital zircon (ZFT) and apatite (AFT) fission-track analysis, together with detrital zircon U-Pb dating to decipher the provenance of Gyirong basin sediments and the exhumation history of the source areas. Results are presented for nine detrital samples of Gyirong basin sediments (AFT, ZFT, and U-Pb), two modern river-sediment samples (ZFT and AFT), and six bedrock samples (ZFT) from transect across the Gyirong fault bounding the basin to the east. The combination of detrital zircon U-Pb and fission-track data demonstrates that the Gyirong basin sediments were sourced locally from the Tethyan Sedimentary Sequence. This provenance pattern indicates that deposition was controlled by the Gyirong fault, active since 10 Ma, whose vertical throw was probably slab during the middle Miocene, inducing dynamic uplift of the Indian plate overriding its own slab.

  2. Petrogenesis and zircon U-Pb dating of skarnified pyroxene-bearing dioritic rocks in Bisheh area, south of Birjand, eastern Iran

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    Malihe Nakhaei


    Full Text Available Introduction The study area is located 196 km south of Birjand in eastern border of the Lut block Berberian and King, 1981 in eastern Iran between 59°05′35" and 59°09′12" E longitude and 31°42′29" and 31°44′13" N latitude. The magmatic activity in the Lut block began in the middle Jurassic such as Kalateh Ahani, Shah Kuh and Surkh Kuh granitoids that are among the oldest rocks exposed within the Lut block (Esmaeily et al., 2005; Tarkian et al., 1983; Moradi Noghondar et al., 2011-2012. Eastern Iran, and particularly the Lut block, has great potential for different types of mineralization as skarnification in Bisheh area which has been studied in this paper. The goal of this study is to highlight the geochronology, geochemistry of major and trace elements, Rb-Sr, Sm-Nd isotopes for skarnified pyroxene-bearing diorites. Materials and methods Major element compositions of thirteen samples were determined by wavelength-dispersive X-ray fluorescence (XRF spectrometry, using fused discs and the Phillips PW 1410 XRF spectrometer at Ferdowsi University, Mashhad, Iran. These samples were analysed for trace elements using inductively coupled plasma-mass spectrometry (ICP-MS in the Acme Analytical Laboratories, Vancouver, British Columbia, Canada. Zircon grains were separated from pyroxene diorite porphyrys using heavy liquid and magnetic techniques at the Institute of Earth Sciences, Academia Sinica, Taipei, Taiwan. Zircon U-Pb dating was performed by laser ablation-inductively-coupled plasma-mass spectrometry (LA-ICP-MS, using an Agilent 7500 s machine and a New Wave UP213 laser ablation system, equipped at the Dr Shen-Su Sun memorial laboratory in the Department of Geosciences, National Taiwan University, Taiwan. Strontium and Nd isotopic analyses were performed on a six-collector Finnigan MAT 261 thermal-ionization mass spectrometer at the University of Colorado, Boulder, Colorado, United States. 87Sr/86Sr ratios were determined using four

  3. Contributions to the petrography, geochemistry and geochronology (U-Pb and Sm-Nd) of the Paleoproterozoic effusive rocks from Iricoume Group, Amazonian Craton, Brazil

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    Marques, Suelen Nonata de Souza; Nascimento, Rielva Solimairy Campelo do, E-mail:, E-mail: [Universidade Federal do Amazonas (UFAM), Manaus, AM (Brazil). Inst. de Geociencias; Souza, Valmir da Silva; Dantas, Elton Luiz, E-mail:, E-mail: [Universidade de Brasilia (UnB), DF (Brazil). Inst. de Geociencias; Valerio, Cristovao da Silva, E-mail: [Universidade Federal de Roraima (UFRR), Boa Vista, RR (Brazil). Inst. de Geociencias


    The southernmost region of the Guyana shield, Amazonian craton, hosts large record of Paleoproterozoic effusive rocks of the Iricoume Group. They present remarkably well-preserved igneous textures and structures. The SiO{sub 2} contents reveal a bimodal association marked by a compositional gap between acid (SiO{sub 2} > 67 wt%) and intermediate (SiO{sub 2} < 57.7 wt%) rocks. The acid effusive rocks are rhyolites to rhyodacites with high SiO{sub 2}, alkali, Rb, Zr, Nb + Ta, La + Ce and 104 Ga/Al content and low Fe{sub 2}O{sub 3tot}, TiO{sub 2}, CaO, Sr and Co content. They exhibit subalkaline, metaluminous-to-peraluminous compositions, and geochemically compatible to A-type magmatism emplaced in post-collisional to within-plate tectonic settings. The intermediate rocks are andesitic/basalt to andesite relatively high contents of TiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3total}, MgO, CaO, Sr and Co; low SiO{sub 2}, K{sub 2}O, Rb, Zr, Nb + Ta, La + Ce. They have subalkaline and metaluminous geochemical composition and plot on within-plate basalt field. The acid rocks crystallized at 1882 ± 11 Ma in U-Pb analyses for LA-MC-ICPMS zircon data. The Sm-Nd isotopic data on all rocks reveal a Nd TDM model ages between 2.59 and 2.16 Ga and ε{sub Nd}(t) values between -5.78 and 0.03, indicate that the magmatic evolution was related to the reworking of older Paleoproterozoic at the Rhyacian-Siderian period, continental crust (Transamazonian crust-forming event) with some mixing with a limited amount mantle-derived magmas or with contamination by Archean crust. The petrographic, geochemical and geochronological data presented in this paper suggest a within-plate to post-collisional tectonic setting for the Iricoume volcanism, involving lower crust uplift and generation of basalt magma in an extensional regime. (author)

  4. U-Pb SHRIMP-RG zircon ages and Nd signature of lower Paleozoic rifting-related magmatism in the Variscan basement of the Eastern Pyrenees (United States)

    Martinez, F.J.; Iriondo, A.; Dietsch, C.; Aleinikoff, J.N.; Peucat, J.J.; Cires, J.; Reche, J.; Capdevila, R.


    The ages of orthogneisses exposed in massifs of the Variscan chain can determine whether they are part of a pre-Neoproterozoic basement, a Neoproterozoic, Panafrican arc, or are, in fact, lower Paleozoic, and their isotopic compositions can be used to probe the nature of their source rocks, adding to the understanding of the types, distribution, and tectonic evolution of peri-Gondwanan crystalline basement. Using SHRIMP U-Pb zircon geochronology and Nd isotopic analysis, pre-Variscan metaigneous rocks from the N??ria massif in the Eastern Pyrenean axial zone and the Guilleries massif, 70km to the south, have been dated and their Nd signatures characterized. All dated orthogneisses from the N??ria massif have the same age within error, ~457Ma, including the Ribes granophyre, interpreted as a subvolcanic unit within Caradocian sediments contemporaneous with granitic magmas intruded into Cambro-Ordovician sediments at deeper levels. Orthogneisses in the Guilleries massif record essentially continuous magmatic activity during the Ordovician, beginning at the Cambro-Ordovician boundary (488??3Ma) and reaching a peak in the volume of magma in the early Late Ordovician (~460Ma). Metavolcanic rocks in the Guilleries massif were extruded at 452??4Ma and appear to have their intrusive equivalent in thin, deformed veins of granitic gneiss (451??7Ma) within metasedimentary rocks. In orthogneisses from both massifs, the cores of some zircons yield Neoproterozoic ages between ~520 and 900Ma. The age of deposition of a pre-Late Ordovician metapelite in the Guilleries massif is bracketed by the weighted average age of the youngest detrital zircon population, 582??11Ma, and the age of cross-cutting granitic veins, 451??7Ma. Older detrital zircons populations in this metapelite include Neoproterozoic (749-610Ma; n=10), Neo- to Mesoproterozoic (1.04-0.86Ga; n=7), Paleoproterozoic (2.02-1.59Ga; n=5), and Neoarchean (2.74-2.58Ga; n=3). Nd isotopic analyses of the N??ria and Guilleries

  5. SE Vietnam U-Pb zircon ages and provenance: Correlating the Da Lat Zone on land with the Cuu Long Basin offshore (United States)

    Hennig, J.; Breitfeld, H. T.; Gough, A.; Hall, R.; Trinh, L. T.; Mai, V. K.; Dinh, S. Q.


    The offshore Neogene Cuu Long Basin SE of Vietnam includes thick sedimentary successions that include important hydrocarbon reservoirs. Zircon U-Pb ages were obtained from these sediments, and Mesozoic igneous and sedimentary rocks exposed on land in the nearby Da Lat Zone of SE Vietnam, to study provenance, sources, stratigraphic relations and sediment pathways. Zircons from several intrusions assigned to the Dinh Quan, Deo Ca and Ankroet complexes yielded Cretaceous weighted mean ages (c. 122-76 Ma). Metasediments of the Jurassic Ban Don Group contain dominant Jurassic, Permo-Triassic and Paleoproterozoic (c. 1.8 Ga) age populations. Neogene to Pleistocene formations locally exposed in the Da Lat Zone are probable equivalents of the offshore sediments. Zircons from the Oligocene to Miocene Di Linh Formation show a dominant Cretaceous peak and minor Permo-Triassic and Paleoproterozoic ages, and are interpreted to be derived from Cretaceous magmatic complexes and subordinate Cathaysian basement of Indochina and South China. The younger Early Pliocene to Pleistocene Song Luy Formation has a different provenance with dominant Permo-Triassic and Paleoproterozoic peaks, an additional Silurian-Ordovician peak, as well as some zircons with Cambrian to Neoproterozoic ages. They are interpreted to be related to magmatism and metamorphism associated with Caledonian and Indosinian events that overprinted the basement exposed in the Kontum Massif and further north in North Vietnam and South China. The Late Pliocene to Pleistocene Ba Mieu Formation shows a very similar zircon age distribution but contains a higher proportion of Precambrian ages (c. 1.8 and 2.5 Ga) from these basement rocks. Only a few Jurassic ages were acquired, indicating the Jurassic Ban Don Group was not an important source. Oligocene samples analysed from the Cuu Long Basin show a significant component of Cretaceous and minor Permo-Triassic zircons. In contrast, Middle Miocene sandstones have a dominant

  6. Petrology and U-PB geochronology of the Robertson River Igneous Suite, Blue Ridge province, Virginia - Evidence for multistage magmatism associated witn an early episode of Laurentian rifting (United States)

    Tollo, R.P.; Aleinikoff, J.N.


    The Late Neoproterozoic (735-702 Ma) Robertson River Igneous Suite includes at least eight plutons ranging in composition from syenogranite to alkali feldspar granite to alkali feldspar syenite. These plutons intruded Mesoproterozoic (1.2-1.0 Ga) gneissic basement of the Blue Ridge anticlinorium in northern and central Virginia during an early episode of Laurentian rifting. Robertson River plutons range in composition from metaluminous to peralkaline and, relative to other granite types, exhibit compositional characteristics of A-type granitoids including (1) marked enrichment in Nb, Zr, Y, REE (except Eu), and Ga, (2) high Ga/Al and FeO(total)/MgO, and (3) depletion of Ba and Sr. High Ga/Al ratios are particularly diagnostic of the suite and serve as an effective discriminant between originally metaluminous and peralkaline bulk compositions, providing a useful proxy for widely used indicators based on major elements that are prone to remobilization. U-Pb isotopic analyses of zircons indicate that the suite was emplaced in two pulses, occurring at 735 to 722 and 706 to 702 Ma. Metaluminous magmas were emplaced during both pulses, formed most of the main batholith, and fractionated as independent, time-correlative groups. Peralkaline magmas were emplaced only during the final pulse, formed a volcanic center that erupted unknown quantities of rhyolite, and experienced a style of fractionation similar to the metaluminous types. Differences in Ce/Nb, Y/Nb, and Yb/Ta ratios suggest that the metaluminous and peralkaline magmas were derived from different sources. The Robertson River Igneous Suite is part of a regional group of Late Neoproterozoic (760-700 Ma) plutons including at least 20 other A-type granitoid bodies exposed throughout the Laurentian terrane of Virginia and northwestern North Carolina. Like the Robertson River, most of the other granitoids are metaluminous in composition, typically form multi-intrusive, elongate plutons, and are not geographically

  7. U-Pb thermochronology of rutile from Alpine Corsica: constraints on the thermal evolution of the European margin during Jurassic continental breakup (United States)

    Ewing, T. A.; Beltrando, M.; Müntener, O.


    U-Pb thermochronology of rutile can provide valuable temporal constraints on the exhumation history of the lower crust, given its moderate closure temperature and the occurrence of rutile in appropriate lithologies. We present an example from Alpine Corsica, in which we investigate the thermal evolution of the distal European margin during Jurassic continental rifting that culminated in the opening of the Alpine Tethys ocean. The Belli Piani unit of the Santa Lucia nappe (Corsica) experienced minimal Alpine overprint and bears a striking resemblance to the renowned Ivrea Zone lower crustal section (Italy). At its base, a 2-4 km thick gabbroic complex contains slivers of granulite facies metapelites that represent Permian lower crust. Zr-in-rutile temperatures and U-Pb ages were determined for rutile from three metapelitic slivers from throughout the Mafic Complex. High Zr-in-rutile temperatures of 850-950 °C corroborate textural evidence for rutile formation during Permian granulite facies metamorphism. Lower Zr-in-rutile temperatures of 750-800 °C in a few grains are partly associated with elongate strings of rutile within quartz ribbons, which record recrystallisation of some rutile during high-temperature shearing. Zr thermometry documents that both crystallisation and re-crystallisation of rutile occurred above the closure temperature of Pb in rutile, such that the U-Pb system can be expected to record cooling ages uncomplicated by re-crystallisation. Our new high-precision single-spot LA-ICPMS U-Pb dates are highly consistent between and within samples. The three samples gave ages from 160 ± 1 Ma to 161 ± 2 Ma, with no other age populations detected. The new data indicate that the Santa Lucia lower crust last cooled through 550-650 °C at 160 Ma, coeval with the first formation of oceanic crust in the Tethys. The new data are compared to previous depth profiling rutile U-Pb data for the Belli Piani unit1, and exploited to cast light on the tectonothermal

  8. New data for paleoprotherozoic PGE-bearing anorthosite of Kandalaksha massif (Baltic shield): U-Pb and Sm-Nd ages (United States)

    Steshenko, Ekaterina; Bayanova, Tamara; Serov, Pavel


    The aims of this researches were to study the isotope U-Pb age of zircon and rutile and Sm-Nd (rock forming and sulphide minerals) on Kandalaksha anorthosite massif due to study of polimetamorphic history. In marginal zone firstly have been obtained the presence of sulphide mineralization with PGE (Chashchin, Petrov , 2013). Kandalaksha massif is located in the N-E part of Baltic shield and consists of three parts. Marginal zone (mesocratic metanorite) lies at the base of the massif. Main zone is composed of leucocratic metagabbro. The upper zone is alteration of mataanorthosite and leucocratic metagabbro. All rocks were subjected to granulate polymetamorphism. Two fractions of single grains from anorthosite of the massif gave precise U-Pb age, which is equal to 2450± 3 Ma. Leucocratic gabbro-norite were dated by U-Pb method, with age up to 2230 ± 10 Ma. This age reflects the time of granulite metamorphism according to data of (Mitrofanov, Nirovich, 2003). Two fractions of rutile have been analyzed by U-Pb method and reflect age of 1700 ± 10 Ma. It is known that the closure temperature of U-Pb system rutile is 400-450 ° C (Mezger, 1989), thus cooling processes of massif rocks to these temperatures was about 1.7 Ga. These data reflect one of the stages of metamorphic alteration of the massif. Three stages of metamorphism are distinguished by Sm-Nd method. Isotope Sm-Nd dating on Cpx-WR line gives the age of 2311 Ma which suggested of high pressure granulite metamorphism. Moreover Cpx-Pl line reflect the age 1908 Ma of low pressure granulite metamorphism. Also two-points (Grt-Rt) Sm-Nd isochrone yield the age 1687 Ma of the last metamorphic alterations in Kandalaksha anorthosite massif. Model Sm-Nd age of the leucocratic gabbro-norite is 2796 Ma with positive ɛNd (+0.32). It means that the source of gabbro-norite was mantle reservoir. All investigations are devoted to memory of academician PAS F. MItrofanov which was a leader of scientific school for

  9. The Halti-Corrovarre enigma in the northern Scandes: new ID-TIMS U/Pb zircon data (United States)

    Andréasson, Per-Gunnar; Corfu, Fernando; Gee, David G.


    The Caledonides of northern Norway are dominated by the Kalak Nappe Complex (KNC), mainly composed of greenschist facies quartzo-feldspathic sandstones, variously intruded by dolerite dykes and minor granites. The highest components of the KNC, the Halti, Corrovarre, Seiland and Gjesvaer nappes (apparently the same structural level), are of higher metamorphic grade and include prominent igneous suites. The Halti and Corrovarre nappes comprise mafic dyke-swarms that intrude and partially melt the meta-sandstones and also include both ultramafites and gabbros. By contrast, the Seiland nappe is dominated by a major igneous province ranging in composition from alkaline gabbro to nepheline syenite and the Gjesvaer nappe is dominated by migmatites. The KNC overrides other thrust sheets, also dominated by siliciclastic successions, the Laksefjord and Gaissa nappes, and all these allochthons overlie a thin Cambrian-Ediacaran sedimentary veneer and the Precambrian crystalline basement of Baltica. Palinspastic reconstructions of the nappes indicate that the KNC has been emplaced at least two hundred kilometres southeastwards onto the Baltoscandian platform; attempts to balance cross-sections have suggested transport distance of the highest Kalak nappes to be in the order of three times this distance. Mapping of the Kalak nappes southwards into Sweden has established their correlation with the Särv and Seve nappes, together comprising the Middle Allochthon. Recent ID-TIMS, U/Pb dating by one of us (FC) of zircons extracted from granitic melts within the dyke-swarms of the Halti and Corrovarre nappes has confirmed the results of previous studies. In Halti, ages of 441-436 Ma compare well with previous zircon and baddeleyite studies; this dunite, troctolite, gabbro, sheeted-dyke suite is of early Llandovery age, overlapping in time with the early Scandian collision of Baltica and Laurentia. In Corrovarre, the granitic melts within the dyke-swarm yield 610 Ma ages, closely

  10. Volcano-climate interactions during the PETM and U-Pb dating from the Fur Formation, Denmark (United States)

    Jones, Morgan; Augland, Lars; Svensen, Henrik; Tegner, Christian; Planke, Sverre; Willumsen, Pi


    The Palaeocene-Eocene Thermal Maximum (PETM) at ~56 Ma is one of the most extreme global warming events in Earth's history. Vast quantities of CO2 and CH4 were released to the atmosphere, causing a rapid (within 20,000 years) 5-6 °C warming that persisted for ~170,000 years. The PETM occurred during an abnormally warm period in Earth history, and was followed by other hyperthermal events later in the Eocene. The PETM also coincided with the second and major pulse of magmatism from the North Atlantic Igneous Province (NAIP) during the break-up of Laurentia and Eurasia at 54-56 Ma. Evidence of explosive volcanism is prevalent at Fur, an island in northern Denmark, where over 180 distinct >1 cm thick ash horizons are preserved in a shallow marine succession (numbered from #-39 to #+140). These ash layers are believed to have originated from volcanic centres in east Greenland and western UK, which indicates that that they were formed during very large volcanic eruptions. Here we present the results of two key sections of the Fur Formation: a beach section at Stolleklint that includes sediment deposited syn-PETM, and a quarry section at Jenshøj that encompasses post-PETM sediments. A detailed chemostratigraphic log of δ13C (TOC) and δ15N values through the section suggests that there may be part of sequence missing, either through glaciotectonism or a depositional hiatus. The δ13C values around ash #-33 are typical of the PETM negative carbon isotope excursion (-31 to -32 ‰), yet are back to background values of ~-26 ‰ just four metres up section. The quarry section around ash #+19 displays further variations in δ13C values, suggesting a coincidence with one of the later Eocene hyperthermal events. High precision U-Pb dating of magmatic zircons from ash layer #+19 conforms to a post-PETM depositional age, giving a mean deposition rate of approximately ~5 cm kyr-1. The correlation between the largest ash layers (#-33 and #+19) and the largest perturbations to

  11. Pre-Cenozoic History of the Jalisco Block (Guerrero Terrane of West-Central Mexico) From U- Pb Geochronology (United States)

    Valencia, V. A.; Righter, K. O.; Gehrels, G.; Ruiz, J.; Ducea, M.; Rosas-Helguera, J.


    The Jalisco Block is a fault-bounded crustal fragment, located along the western edge of the Trans-Mexican Volcanic Belt of west-central Mexico, and it forms part of the Triassic-Jurassic Guerrero terrane. Because of its extensive Miocene-Quaternary volcanic cover and Early Cretaceous-Tertiary intrusions, little is known about its Pre-Tertiary history. U-Pb (LA-MC-ICPMS) zircon geochronology of metasedimentary (Quartz Feldespathic Schist), marine sedimentary and plutonic rocks from several localities of the Jalisco Block (southern Mexico) were determined to constrain the geological evolution of this region. Results for the metasedimentary rocks, which are present as roof pendants, indicate a depositional age between the Late Triassic and Middle Jurassic. The older depositional sequence (Late Triassic) shows an important continental influence with subordinate clusters from the Carboniferous (297 Ma), Ordovician (446 Ma), Late and Middle Proterozoic (760, 1041, 1200, 1500 Ma) and Archean (~~2700 Ma), whereas the youngest depositional sequence (Middle Jurassic) have mainly Jurassic zircons, indicating sedimentation in a restricted basin. Ages of turbiditic marine sediments reveal a maximum depositional age of ~~130 Ma (Early Cretaceous), comparable to zircon populations from other areas of the Guerrero Terrane, and with minor age peaks at 320, 480-560, 743, 997-1260, and ~~2750 Ma. Magmatic granitic rocks from Atenguillo, Puerto Vallarta, Mascota and Tomatlan have ages of ~~60 Ma, ~~74 Ma and 80-90 Ma. These ages overlap with previously determined ages of granites and rhyolitic ash flow tuffs from the Jalisco Block, Baja California, Sonora and Sinaloa states. On the other hand, a granitic sample of Cuale region yielded a middle Jurassic age. Metasedimentary and sedimentary rocks of the Jalisco Block have a depositional evolution similar to coeval formations in the Guerrero and Alisitos terranes. We conclude that this

  12. Petrology and SHRIMP U-Pb dating of Xitieshan eclogite, North Qaidam UHP metamorphic belt, NW China (United States)

    Zhang, Cong; Zhang, Lifei; Roermund, Herman Van; Song, Shuguang; Zhang, Guibin


    Normal bimineralic and phengite-bearing eclogites have been recognized within mafic boudins (or lenses) enclosed in granitic and pelitic gneisses in the Xitieshan terrane, NW China. Bimineralic eclogite contains the primary M1 mineral assemblage Grt + Omp + Rt + Qtz+/-Zrn. Inclusions in M1 omphacite may be coesite pseudomorphs. Phengite eclogite consists of the M1 mineral assemblage Grt + Omp + Phn + Qtz + Rt+/-Zrn. Most eclogites are retrogressed to various degrees and contain hornblende, diopside and plagioclase, which commonly form symplectitic and/or kelyphitic intergrowths. The peak M1 P-T conditions of the Xitieshan eclogite are calculated to be P = 2.71-3.17 GPa and T = 751-791 °C, consistent with the presence of coesite pseudomorphs in omphacite. In addition, we have identified two stages of retrograde metamorphism; an early isothermal decompression stage (M2) followed by a later stage (M3) that developed under decreasing temperatures and pressures. During M2 internally-derived fluids played an important role, whereas during M3 and below externally-derived fluids dominated. The composition of garnet in M1changed little during M2 isothermal decompression (ITD), although pyrope contents in garnet locally decrease from core to rim where the grains have amphibole and pargasite + plagioclase coronas. Also the jadeite content (56%) of M1 omphacite decreased in the presence of active fluids during retrograde metamorphism. M1 phengite is replaced by the M2 assemblage Ms + Bt accompanied by K-feldspar + quartz. Amphibole compositions changed from magnesio-katophorite in M2 to pargasite in M3. Zircon U-Pb SHRIMP dating shows that the bimineralic eclogite has a magmatic protolith age of 877 ± 8 Ma and a metamorphic age of 439 ± 8 to 461 ± 4 Ma. We conclude that the Xitieshan metabasic rocks formed in the late Proterozoic and were subsequently subducted to depths of about 100 km, where they were metamorphosed to UHP eclogite during the late Ordovician (440-460 Ma

  13. U-Pb dated Speleothem records of Plio-Pleistocen climate variability from South African hominin bearing caves (United States)

    Pickering, Robyn; Göktürk, Ozan; Badertscher, Seraina; Fleitmann, Dominik; Kramers, Jan


    We use stable isotopes of carbon and oxygen to investigate the potential palaeoclimate records from the caves near Johannesburg in South Africa. The sediments in these caves contain early human (hominin) fossils, as well as speleothem material, providing an ideal opportunity to investigate the palaeo-enviroments of our earliest ancestors. These sites are dated via uranium-lead to between 2.8 and 1.5 Ma and provide a window into changing climatic conditions, rare from both this period and region. We micro-drilled stalagmite and flowstone samples from Sterkfontein (2.8 -2.0 Ma), Swartkrans (2.4 -1.7 Ma) and Cooper's Cave (1.5 - 1.4 Ma) at 0.5mm spacing to provide a total of five high resolution records. Oxygen isotope values range from -6.5 to -3‰, clustering around -4.5‰. Carbon isotopes range from -8 to 2‰ and show more variation. Both a Hendy test and a C vs. O plot show that the deposits in question were deposited in equilibrium with their surroundings and the data can be used for environmental interpretations. Care was also taken to examine the petrography of all the speleothem material to access the mineralogy (calcite vs aragonite) and the extent of re-crystallisation. Oxygen isotope values are interpreted as the product of the amount and type of rainfall, with wetter periods represented by enriched excursions. The contribution of the dolomite aquifer above the cave may, however, obscure the δ18O signal. The carbon isotopes reflect changes in the vegetational communities above the cave, with varying amounts of C3 and C4 plants. At present each speleothem piece has only one U-Pb date, the distribution of suitable uranium rich layers limits the spatial resolution of dates. The Cooper's Cave flowstone pieces display visible growth layers; should these be annual layers, then these two records represent as little as 60 years climate variability - specifically in the amount of rainfall. However, this would require very fast speleothem growth rates (0.5mm

  14. U-Pb Dating of Calcite to Constrain Basinal Brine Flux Events: An Example from the Upper Midwest USA (United States)

    Rasbury, T.; Luczaj, J.


    Calcite forms in a variety of settings and can be the product of surface to deep basinal fluids. As such, this mineral can uniquely record details of the fluids responsible for its formation. The forms of calcium carbonates and their stratigraphic relationships from the thin section to the regional scale give important insights on pulses of fluids. A fundamental question is the age of such fluid pulses. While calcite excludes uranium (U) from its crystal structure, some is incorporated and depending on the U/Pb ratio, this provides an opportunity for radiometric dating. Calcite crystals of various sizes and crystal habits are found in Paleozoic carbonate rocks throughout the region from the western Michigan basin to the upper Mississippi valley. These are typically associated with Mississippi Valley-type (MVT) mineralization, including galena, sphalerite, and iron sulfides, but typically post-date the main MVT event. We have analyzed a variety of these calcites and find multiple generations of calcite, separated by tens of millions of years. The initial Pb isotope ratios are similar to the isotope ratios of nearby galena, strongly suggesting a genetic relationship. Our oldest ages are 200 Ma, and we find ages ranging into the Cenozoic. Based on the Paleozoic-hosted galena Pb-isotope isoscapes from the region, the fluids may have been sourced from both the Michigan and Illinois basins. An important and unanswered question is what would cause significant fluid movement out of the basins substantially after Appalachian orogenesis. Noble gas data from brines in the Michigan Basin have a mantle component and have been suggested to be responsible for recognized elevated temperatures across the basin (Ma et al., 2009). Multiple thermal events during the Paleozoic and Mesozoic eras may have an internal heat source related to reactivation of faults of the Keweenawan Rift system below the Michigan Basin. Perhaps a mantle heat source from below episodically fluxes into the

  15. U-Pb, Re-Os, and Ar/Ar geochronology of rare earth element (REE)-rich breccia pipes and associated host rocks from the Mesoproterozoic Pea Ridge Fe-REE-Au deposit, St. Francois Mountains, Missouri (United States)

    Aleinikoff, John N.; Selby, David; Slack, John F.; Day, Warren C.; Pillers, Renee M.; Cosca, Michael A.; Seeger, Cheryl; Fanning, C. Mark; Samson, Iain


    Rare earth element (REE)-rich breccia pipes (600,000 t @ 12% rare earth oxides) are preserved along the margins of the 136-million metric ton (Mt) Pea Ridge magnetite-apatite deposit, within Mesoproterozoic (~1.47 Ga) volcanic-plutonic rocks of the St. Francois Mountains terrane in southeastern Missouri, United States. The breccia pipes cut the rhyolite-hosted magnetite deposit and contain clasts of nearly all local bedrock and mineralized lithologies.Grains of monazite and xenotime were extracted from breccia pipe samples for SHRIMP U-Pb geochronology; both minerals were also dated in one polished thin section. Monazite forms two morphologies: (1) matrix granular grains composed of numerous small (Os on fine-grained molybdenite and 40Ar/39Ar on muscovite, biotite, and K-feldspar.Ages (±2σ errors) obtained by SHRIMP U-Pb analysis are as follows: (1) zircon from the two host rhyolite samples have ages of 1473.6 ± 8.0 and 1472.7 ± 5.6 Ma; most zircon in late felsic dikes is interpreted as xenocrystic (age range ca. 1522–1455 Ma); a population of rare spongy zircon is likely of igneous origin and yields an age of 1441 ± 9 Ma; (2) pale-yellow granular monazite—1464.9 ± 3.3 Ma (no dated xenotime); (3) reddish matrix granular monazite—1462.0 ± 3.5 Ma and associated xenotime—1453 ± 11 Ma; (4) coarse glassy-yellow monazite—1464.8 ± 2.1, 1461.7 ± 3.7 Ma, with rims at 1447.2 ± 4.7 Ma; and (5) matrix monazite (in situ)—1464.1 ± 3.6 and 1454.6 ± 9.6 Ma, and matrix xenotime (in situ)—1468.0 ± 8.0 Ma. Two slightly older ages of cores are about 1478 Ma. The young age of rims on the coarse glassy monazite coincides with an Re-Os age of 1440.6 ± 9.2 Ma determined in this study for molybdenite intergrown with quartz and allanite, and with the age of monazite inclusions in apatite from the magnetite ore (Neymark et al., 2016). A 40Ar/39Ar age of 1473 ± 1 Ma was obtained for muscovite from a breccia pipe sample.Geochronology and trace element

  16. High-precision U-Pb geochronology of the Jurassic Yanliao Biota from Jianchang (western Liaoning Province, China): Age constraints on the rise of feathered dinosaurs and eutherian mammals (United States)

    Chu, Zhuyin; He, Huaiyu; Ramezani, Jahandar; Bowring, Samuel A.; Hu, Dongyu; Zhang, Lijun; Zheng, Shaolin; Wang, Xiaolin; Zhou, Zhonghe; Deng, Chenglong; Guo, Jinghui


    The Yanliao Biota of northeastern China comprises the oldest feathered dinosaurs, transitional pterosaurs, as well as the earliest eutherian mammals, multituberculate mammals, and new euharamiyidan species that are key elements of the Mesozoic biotic record. Recent discovery of the Yanliao Biota in the Daxishan section near the town of Linglongta, Jianchang County in western Liaoning Province have greatly enhanced our knowledge of the transition from dinosaurs to birds, primitive to derived pterosaurs, and the early evolution of mammals. Nevertheless, fundamental questions regarding the correlation of fossil-bearing strata, rates of dinosaur and mammalian evolution, and their relationship to environmental change in deep time remain unresolved due to the paucity of precise and accurate temporal constraints. These limitations underscore the importance of placing the rich fossil record of Jianchang within a high-resolution chronostratigraphic framework that has thus far been hampered by the relatively low precision of in situ radioisotopic dating techniques. Here we present high-precision U-Pb zircon geochronology by the chemical abrasion isotope dilution thermal ionization mass spectrometry (CA-ID-TIMS) from three interstratified ash beds previously dated by secondary-ion mass spectrometry (SIMS) technique. The results constrain the key fossil horizons of the Daxishan section to an interval spanning 160.89 to 160.25 Ma with 2σ analytical uncertainties that range from ±46 to ±69 kyr. These data place the Yanliao Biota from Jianchang in the Oxfordian Stage of the Late Jurassic, and mark the Daxishan section as the site of Earth's oldest precisely dated feathered dinosaurs and eutherian mammals.

  17. In situ isotopic analyses of U and Pb in zircon by remotely operated SHRIMP II, and Hf by LA-ICP-MS: an example of dating and genetic evolution of zircon by {sup 176}Hf/{sup 177}Hf from the Ita Quarry in the Atuba Complex, SE, Brazil; Analises in situ de U e Pb em zircao por SRIMP II por controle remoto e de Hf por LA-ICP-MS: um exemplo de datacao e da evolucao genetica de zircao atraves da razao {sup 176}Hf/{sup 177} em amostra da Pedreira Ita no Complexo Atuba, SE, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Sato, K.; Siga Junior, Oswaldo; McReath, Ian; Sproesser, Walter; Basei, Miguel Angelo Stipp [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Geociencias. Centro de Pesquisas Geocronologicas], e-mail:, e-mail:, e-mail:, e-mail:, e-mail:; Silva, Josiane Aline da [Universidade de Sao Paulo (USP), SP (Brazil). Programa de Pos-graduacao em Geoquimica e Geotectonica; Dunyi, Liu [Institute of Geology, Beijing (China); Iizuka, Takafumi; Rino, Shuji; Hirata, Takafumi [Tokyo Institute of Technology, Tokyo (Japan)


    Remotely-operated SHRIMP dating of zircon is an interesting alternative for dating of zircon crystals. Although it does not represent any technical progress of the geochronological method using the U-Pb system in zircon it is a very useful and cheap facility. The procedure was first used for mass spectrometric analyses involving two international laboratories in Sao Paulo, Brazil and Beijing, China. It was applied to samples of three gneiss-migmatitic rocks from the Ita quarry in the Atuba Complex (located between the Luis Alves and the Apiai Domain) to test previous controversial hypotheses about its evolution. The presence of important archaean and paleo proterozoic components in the complex is confirmed by analyses of zircon found in probably neo proterozoic leucosomes. Diorite intrusion also occurred during the neo proterozoic, associated with the 0.6Ga continental collisions involved in the assembly of Gondwana. The determination of Hf isotope ratios by LA-ICP/MS represents a new option for checking the relative importance of mantle ({epsilon}{sub Hf} > 0) and crustal contributions (({epsilon}{sub Hf} < 0) during the growth of the zircon crystals. While the archaean component in the complex was derived from the mantle ({epsilon}{sub Hf} + 1.5 to + 8.7) the paleo proterozoic component had a crustal contribution ({epsilon}{sub Hf} - 9.1 to -10.1). (author)

  18. Precambrian-Cambrian provenance of Matinde Formation, Karoo Supergroup, northwestern Mozambique, constrained from detrital zircon U-Pb age and Lu-Hf isotope data (United States)

    Bicca, Marcos Müller; Jelinek, Andrea Ritter; Philipp, Ruy Paulo; de Carvalho Lana, Cristiano; Alkmim, Ana Ramalho


    The Permian-Triassic time interval was a period of high sedimentation rates in the intracontinental Karoo rift basin of northwestern Mozambique, reflecting high exhumation rates in the surrounding high ground Precambrian-Cambrian basement and juxtaposed nappes. U-Pb LA-MC-ICPMS dating and Lu-Hf isotopic analysis of detrital zircons from the Late Permian-Early Triassic Matinde Formation of the Karoo Supergroup is used as a reliable proxy to map denudation patterns of source regions. Data allow discrimination of U-Pb age populations of ca. 1250-900 Ma, a secondary population between ca. 900-700 and a major contribution of ages around ca. 700-490 Ma. Zircon grains of the Mesoproterozoic age population present Mesoproterozoic (1000-1500 Ma) to Paleoproterozoic (1800-2300 Ma) Hf TDM ages, with positive (0 to +11) and negative εHf values (-3 to -15), respectively. The younger U-Pb age population also presents two different groups of zircon grains according to Lu-Hf isotopes. The first group comprise Paleoproterozoic (1800-2300 Ma) ages, with highly negative εHf values, between -10 and -22, and the second group exhibits Mesoproterozoic ages (1200-1500 Ma), with increased juvenile εHf values (ca. 0 to -5). These Hf isotopes reinforce the presence of unexposed ancient crust in this region. The oldest U-Pb age population resembles the late stages of Grenville Orogeny and the Rodinia Supercontinent geotectonic activity mostly represented by magmatic rocks, which are widely present in the basement of northern Mozambique. The juvenile Hf-isotope signature with an older age component is associated to rocks generated from subduction processes with crust assimilation by continental arcs, which we correlate to rocks of the Nampula Complex, south and east of the Moatize-Minjova Basin. The U-Pb ages between 900 and 700 Ma were correlated to the calc-alkaline magmatism registered in the Guro Suite, related to the breakup phase of Rodinia, and mark the western limit of the Moatize

  19. In situ groundwater bioremediation

    Energy Technology Data Exchange (ETDEWEB)

    Hazen, Terry C.


    In situ groundwater bioremediation of hydrocarbons has been used for more than 40 years. Most strategies involve biostimulation; however, recently bioaugmentation have been used for dehalorespiration. Aquifer and contaminant profiles are critical to determining the feasibility and strategy for in situ groundwater bioremediation. Hydraulic conductivity and redox conditions, including concentrations of terminal electron acceptors are critical to determine the feasibility and strategy for potential bioremediation applications. Conceptual models followed by characterization and subsequent numerical models are critical for efficient and cost effective bioremediation. Critical research needs in this area include better modeling and integration of remediation strategies with natural attenuation.

  20. Using U-Pb apatite thermochronology to track the structural evolution of granitoid-orthogneiss domes from the Archean Pilbara craton (United States)

    MacLennan, S. A.; Schoene, B.


    Granitoid-orthogneiss domes are an important component of all Archean crustal terranes. The Eastern Pilbara craton contains well-preserved examples of Mesoarchean granitoid-orthogneiss domes whose formation has been interpreted by many within a non-plate tectonic paradigm that hinges upon hotter crustal geotherms that drive partial convective overturn of the crust. This model makes predictions for the temperature-time histories of the domes that can be tested by high-temperature thermochronometry. We use U-Pb thermochronmetry in apatite, which is sensitive to mid crustal temperatures ( 400°C), and thus can track exhumation of gneiss domes from the lower to upper crust. These processes are not recorded in geochronometers (e.g., U-Pb zircon) or low temperature thermochronometers (e.g., U/Th-He, apatite fission track). The convective overturn model for the development of these domes predicts that exhumation of the granitoid ( 3.25 Ga) -orthogneiss (3.45 Ga) domes into the upper crust occurred rapidly (100 Ma after emplacement, followed by exhumation. A craton-wide deformational episode occurs at 3.0 Ga, but is poorly resolved in the eastern Pilbara craton. Our ca. 3.0 Ga apatite dates indicate that this period also drove structural modification in this area. When combined, these data indicate that the eastern Pilbara craton experience a ca. 400 Myr history of intrusion, deformation, and exhumation that resulted in the present crustal architecture, and highlight the utility of U-Pb in apatite as a tool to resolve tectonic histories by constraining the timing of exhumation or emplacement of material into the upper crust, and has wide applications to cratonic or orogenic studies.

  1. Provenance and paleogeography of the Mesozoic strata in the Muang Xai Basin, northern Laos: petrology, whole-rock geochemistry, and U-Pb geochronology constraints (United States)

    Wang, Yanlu; Wang, Licheng; Wei, Yushuai; Shen, Lijian; Chen, Ke; Yu, Xiaocan; Liu, Chenglin


    The Muang Xai Basin, located in northern Laos, is associated with the Simao, Vientiane, and Khorat Basins. The paleogeographic link of these basins has not been investigated in great detail; thus, the investigation presented in this study is a comprehensive analysis of petrology, whole-rock geochemistry, and detrital zircon U-Pb chronology used to characterize the provenance of the Muang Xai Basin. Results suggest that the sedimentary source includes felsic rocks from an active continental margin or continental arc with minor amounts of recycled passive continental margin sediments. Sandstones of the Muang Xai Basin contain detrital zircons with varying U-Pb peak ages. The youngest age peak of all the zircons is 103 Ma, which limits the age of the Mesozoic strata to the Late Cretaceous. Detrital zircon U-Pb and trace element data, combined with geochemical result, reveal that the pre-Ordovician zircons were derived from recycled sediments of the Yangtze Block, which are originally sourced from the Qinling Orogenic belt. This provenance is shared with coeval sediments in the Simao and Khorat Basins, while magmatic rocks of the Ailaoshan, Truong Son Belt, and Lincang terrane are responsible for zircons of 416-466 and 219-308 Ma in age. Zircons of 101-110 and 149-175 Ma in age were sourced from magmatic rocks of the southwestern South China Block and northern Vietnam. These provenance results suggest that sediments flow into the Khorat red beds was likely from the Great Simao Basin and northern Vietnam, and not directly from the Yangtze Block.

  2. Detrital Zircon U-Pb Ages of River Sands from Taiwan: Implications for Sedimentary Provenance and Its Source Link with the East Chinese Mainland (United States)

    Deng, K.; Yang, S.; Li, C.; Bi, L.; Chang, Y. P.


    In order to investigate the provenances of sedimentary rocks in Taiwan Island, we report the U-Pb geochronology of 630 concordant detrital zircons separated from the sandy sediments of the Zhuoshui River in west Taiwan and the Lanyang River in east Taiwan. In addition, 1472 published ages of detrital zircons from different rivers draining the east Chinese mainland are compiled to reveal the source-sink relationship between Taiwanese sedimentary rocks and east mainland. Detrital zircons from the two Taiwanese Rivers show seven major age groups of 100-200 Ma, 200-300 Ma, 360-550 Ma, 700-850 Ma, 0.9-1.1 Ga, 1.8-2.0 Ga and 2.4-2.6 Ga, which correspond well with major tectonic and magmatic events in east mainland. Nevertheless, the U-Pb age distributions have significant difference between east and west Taiwan terranes, showing high proportion of Phanerozoic zircons in east Taiwan and more complex age population and more Precambrian zircons in west Taiwan. This reveals obviously different sedimentary evolution between east and west Taiwan terranes. A series of methods (kernel density estimation plot, cumulative probability plot, overlap and similarity and a simple provenance model) are carried out to compare the U-Pb age distributions between Taiwan and east Chinese mainland, hence the source-sink relationship between them can be investigated. The Eocene-late Oligocene sequences of the Hsuehshan Range and the Miocene turbidity sequences of the east Central Range in east Taiwan are mainly sourced from the west Cathaysia Block (contributing about 81% of total zircon age population). The Yangtze Block (about 43%) and the North China Block (about 34%) may be the dominant provenances of the Eocene-Pleistocene sequences in west Taiwan.

  3. The Grand St Bernard-Briançonnais Nappe System and the Paleozoic Inheritance of the Western Alps Unraveled by Zircon U-Pb Dating (United States)

    Bergomi, M. A.; Dal Piaz, G. V.; Malusà, M. G.; Monopoli, B.; Tunesi, A.


    The continental crust involved in the Alpine orogeny was largely shaped by Paleozoic tectono-metamorphic and igneous events during oblique collision between Gondwana and Laurussia. In order to shed light on the pre-Alpine basement puzzle disrupted and reamalgamated during the Tethyan rifting and the Alpine orogeny, we provide sensitive high-resolution ion microprobe U-Pb zircon and geochemical whole rock data from selected basement units of the Grand St Bernard-Briançonnais nappe system in the Western Alps and from the Penninic and Lower Austroalpine units in the Central Alps. Zircon U-Pb ages, ranging from 459.0 ± 2.3 Ma to 279.1 ± 1.1 Ma, provide evidence of a complex evolution along the northern margin of Gondwana including Ordovician transtension, Devonian subduction, and Carboniferous-to-Permian tectonic reorganization. Original zircon U-Pb ages of 371 ± 0.9 Ma and 369.3 ± 1.5 Ma, from calc-alkaline granitoids of the Grand Nomenon and Gneiss del Monte Canale units, provide the first compelling evidence of Late Devonian orogenic magmatism in the Alps. We propose that rocks belonging to these units were originally part of the Moldanubian domain and were displaced toward the SW by Late Carboniferous strike-slip faulting. The resulting assemblage of basement units was disrupted by Permian tectonics and by Mesozoic opening of the Alpine Tethys. Remnants of the Moldanubian domain became either part of the European paleomargin (Grand Nomenon unit) or part of the Adriatic paleomargin (Gneiss del Monte Canale unit), to be finally accreted into the Alpine orogenic wedge during the Cenozoic.

  4. Geology, geochemistry, and geochronology (U-Pb) of the Rio Fortuna Gneiss - Serra do Bau intrusive Suite - Paragua Terrane SW Amazonian Craton

    Energy Technology Data Exchange (ETDEWEB)

    Faria, Debora Almeida; Ruiz, Amarildo Salina; Matos, Joao Batista; Sousa, Maria Zelia Aguiar de; Lima, Gabrielle Aparecida de [Research Group on Crustal and Tectonic Evolution, Guapore, RS (Brazil); Universidade Federal de Mato Grosso (ICET/UFMT), Cuiaba, MT (Brazil). Instituto de Ciencias Exatas e da Terra; Inst. Nacional de Ciencia e Tecnologia de Geociencias da Amazonia (GEOCIAM), Belem, PA (Brazil); Moacir Jose Buenano Macambira, E-mail:, E-mail:, E-mail:, E-mail:, E-mail:, E-mail: [Research Group on Crustal and Tectonic Evolution, Guapore, RS (Brazil); Universidade Federal do Para (UFPA), Belem, PA (Brazil)


    The Rio Fortuna Gneiss crops out in the Serra Santa Barbara, near the Fortuna military headquarters, on the Brazil-Bolivia border. These orthogneisses are located in a portion of the Paragua terrain affected by the Sunsas Orogeny (1.0-0.9 Ga.). They are classified as monzo to granodiorite orthogneisses and underwent at least three episodes of deformation. The U-Pb zircon age of 1,711 ± 13 Ma obtained by laser ablation MC-ICP-MS is interpreted as the crystallization age of this orthogneiss. Geochemically, these rocks form a sequence comprising acidic subalkaline magmatism, calc-alkalic-type high-K, and metaluminous to peraluminous. (author)

  5. A combined Sm-Nd, Rb-Sr, and U-Pb isotopic study of Mg-suite norite 78238: Further evidence for early differentiation of the Moon

    Energy Technology Data Exchange (ETDEWEB)

    Edmunson, J; E.Borg, L; Nyquist, L E; Asmerom, Y


    Lunar Mg-suite norite 78238 was dated using the Sm-Nd, Rb-Sr, and U-Pb isotopic systems in order to constrain the age of lunar magma ocean solidification and the beginning of Mg-suite magmatism, as well as to provide a direct comparison between the three isotopic systems. The Sm-Nd isotopic system yields a crystallization age for 78238 of 4334 {+-} 37 Ma and an initial {var_epsilon}{sub Nd}{sup 143} value of -0.27 {+-} 0.74. The age-initial {var_epsilon}{sub Nd}{sup 143} (T-I) systematics of a variety of KREEP-rich samples, including 78238 and other Mg-suite rocks, KREEP basalts, and olivine cumulate NWA 773, suggest that lunar differentiation was completed by 4492 {+-} 61 Ma assuming a Chondritic Uniform Reservoir bulk composition for the Moon. The Rb-Sr isotopic systematics of 78238 were disturbed by post-crystallization processes. Nevertheless, selected data points yield two Rb-Sr isochrons. One is concordant with the Sm-Nd crystallization age, 4366 {+-} 53 Ma. The other is 4003 {+-} 95 Ma and is concordant with an Ar-Ar age for 78236. The {sup 207}Pb-{sup 206}Pb age of 4333 {+-} 59 Ma is concordant with the Sm-Nd age. The U-Pb isotopic systematics of 78238 yield linear arrays equivalent to younger ages than the Pb-Pb system, and may reflect fractionation of U and Pb during sample handling. Despite the disturbed nature of the U-Pb systems, a time-averaged {mu} ({sup 238}U/{sup 204}Pb) value of the source can be estimated at 27 {+-} 30 from the Pb-Pb isotopic systematics. Because KREEP-rich samples are likely to be derived from source regions with the highest U/Pb ratios, the relatively low {mu} value calculated for the 78238 source suggests the bulk Moon does not have an exceedingly high {mu} value.

  6. Chronology of fluid paleo-circulations in mesozoic formations on the site of Bure by U/Pb dating of secondary calcites

    International Nuclear Information System (INIS)

    Pisapia, C.; Deschamps, P.; Hamelin, B.; Pisapia, C.; Buschaert, S.


    The French national agency for the management of radioactive wastes (ANDRA, Agence nationale pour la gestion des dechets radioactifs) has developed an underground research laboratory in mesozoic formations of the eastern Parisian Basin in order to test the design of radioactive waste storage site in sedimentary formations. The authors report an investigation which aims at understanding the site paleo-hydrology. This investigation is based on the disintegration chain of uranium and on U/Th and U/Pb dating methods, and aims at giving a precise chronology of the different phases of precipitation of centimetric and millimetric secondary calcites sampled on this site

  7. Zircon U-Pb ages and geochemistry of migmatites and granites in the Foping dome: Evidence for Late Triassic crustal evolution in South Qinling, China (United States)

    Zhang, He; Li, Shuang-Qing; Fang, Bo-Wen; He, Jian-Feng; Xue, Ying-Yu; Siebel, Wolfgang; Chen, Fukun


    Migmatites provide a record of melt formation and crustal rheology. In this study we present zircon U-Pb ages and geochemical composition of migmatites from the Foping dome and granites from the Wulong pluton. U-Pb results from migmatite zircons indicate two episodes of partial melting. Rim domains from a leucosome in the Longcaoping area yield an age of ca. 209 Ma. Migmatites collected from the Foping dome yield U-Pb zircon ages of 2910 to 190 Ma, suggesting the involvement of meta-sedimentary source components. Rim domains of the zircons with low Th/U ratios (earth elements, which is related to crystallization of garnet. Magmatic rocks from the Wulong pluton can be subdivided into high Sr/Y and low Sr/Y granites. U-Pb zircon ages vary from 219 to 214 Ma for the high Sr/Y granites and from 214 to 192 Ma for the low Sr/Y granites. High Sr/Y granites have higher Na2O and Sr contents than the low Sr/Y granites. They also lack negative Eu anomalies and are depleted in HREE compared to the low Sr/Y granites. Initial 87Sr/86Sr ratios and εNd values of all the samples roughly overlap with those of Neoproterozoic basement rocks exposed in South Qinling. Including previous studies, we propose that the high and low Sr/Y granites formed by melting of thickened and normal crust, respectively. Close temporal-spatial relationship of the high and low Sr/Y granites with the two-stage migmatization events implies variation of crustal thickness and thermal overprints of the orogenic crust in post-collisional collapse. Following the collision of South Qinling and the Yangtze block prior to 219 Ma, partial melting of the deep crust occurred. The melts migrated upwards to form the high Sr/Y granites. This process occurred rapidly and caused collapse of the thickened crust and carried heat upwards, leading to further partial melting within the shallower crust and formation of the low Sr/Y granites.

  8. U-Pb age constraints for the La Tuna Granite and Montevideo Formation (Paleoproterozoic, Uruguay): Unravelling the structure of the Río de la Plata Craton (United States)

    Pamoukaghlián, Karina; Gaucher, Claudio; Frei, Robert; Poiré, Daniel G.; Chemale, Farid; Frei, Dirk; Will, Thomas M.


    The Río de la Plata Craton is a continental block that crops out in Uruguay, eastern Argentina, southernmost Brazil and Paraguay. It comprises in Uruguay the Piedra Alta, Tandilia and Nico Pérez terranes, separated by the Colonia and the Sarandí del Yí megashears. The La Tuna Granite, which intrudes the Araminda metasandstones in the Tandilia Terrane, was considered Cambrian in age and the intruded sandstones were assigned to the Neoproterozoic Piedras de Afilar Formation. We show that the granite is Paleoproterozoic in age and that the host metasandstones do not belong to the Piedras de Afilar Formation, but to the Paleoproterozoic Montevideo Formation. U-Pb LA ICP-MS of zircon ages for the La Tuna Granite yielded a concordant crystallization age of 2156 ± 26 Ma. Furthermore a metamorphic event at 2010 ± 9 Ma is revealed by Pb stepwise leaching dating of monazites. U-Pb detrital zircon ages of the host Araminda metasandstone yield an upper intercept discordia age of 2152 ± 29 Ma, which marks the intrusion of the La Tuna pluton, and which is in accordance with the zircon U-Pb LA ICP MS constraints. A concordant U-Pb detrital zircon age of 2465 ± 40 Ma provides a maximum depositional age constraint for the metapsammites. Comparing quartz arenites of the Ediacaran Piedras de Afilar Formation with the Araminda metaquartzites, we conclude that they are very similar regarding petrology but they differ in age and metamorphic overprint. Detrital zircons in quartz arenites of the Piedras de Afilar Formation show youngest ages of 1.0 Ga. On the other hand, detrital zircons recovered from the Araminda metasandstones and the age of the intruding granite allow interpreting a depositional age between 2465 and 2150 Ma. Nd model ages show crustal residence times in average more than 200 myr older for the Tandilia Terrane both in Uruguay and Argentina, with a significant Neoarchean component, which is lacking in the Piedra Alta Terrane. Whereas the Piedra Alta Terrane was

  9. Zircon U-Pb age of the Pescadero felsite: A late Cretaceous igneous event in the forearc, west-central California Coast Ranges (United States)

    Ernst, W.G.; Martens, U.C.; McLaughlin, R.J.; Clark, J.C.; Moore, Diane E.


    Weathered felsite is associated with the late Campanian-Maastrichtian Pigeon Point Formation near Pescadero, California. Poorly exposed, its age and correlation are uncertain. Is it part of the Pigeon Point section west of the San Gregorio-Hosgri fault? Does it rest on Nacimiento block basement? Is it dextrally offset from the Oligocene Cambria Felsite, ~185 km to the southeast? Why is a calc-alkaline hypabyssal igneous rock intrusive into the outboard accretionary prism? To address these questions, we analyzed 43 oscillatory-zoned zircon crystals from three incipiently recrystallized pumpellyite ?? prehnite ?? laumontite-bearing Pescadero felsite samples by sensitive high-resolution ion microprobe-reverse geometry (SHRIMPRG) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) techniques. Thirty-three zircons gave late Mesozoic U-Pb ages, with single-grain values ranging from 81 to 167 Ma; ten have pre-Mesozoic, chiefl y Proterozoic ages. A group of the four youngest Pescadero zircons yielded an apparent maximum igneous age of ca. 86-90 Ma. Refl ecting broad age scatter and presence of partly digested sandstone inclusions, we interpret the rest of the zircons (perhaps all) as xenocrysts. Twenty-three zircons were separated and analyzed from two samples of the similar Cambria Felsite, yielding a unimodal 27 Ma U-Pb age. Clearly, the origin of the Upper Oligocene Cambria Felsite is different from that of the Upper Cretaceous Pescadero felsite; these rocks are not correlated, and do not constrain displacement along the San Gregorio-Hosgri fault. Peak ages differ slightly, but relative probability curves for Mesozoic and pre-Mesozoic Pescadero zircons compare well, for example, with abundant U-Pb age data for detrital zircons from Franciscan metaclastic strata ~100 km to the east in the Diablo Range- San Francisco Bay area, San Joaquin Great Valley Group turbidites, Upper Cretaceous Nacimiento block Franciscan strata, and Upper Cretaceous

  10. Classification, U-Pb (TIMS) age and sources of the Kolmozero-Keivy rare-element pegmatites (NE Baltic Shield) (United States)

    Kudryashov, Nikolay; Zozulya, Dmitry; Lyalina, Ludmila; Mokrushin, Artem; Steshenko, Ekaterina; Kunakkuzin, Evgeniy


    Kolmozero-Keivy zone, NE Baltic shield, is composed mainly from basic-intermediate-acid metavolcanic suites of 2.83-2.87 Ga age and metamorphosed at amphibolitic facies during 1.8-1.7 Ga. Younger igneous events are represented by voluminous intrusions of 2.73 Ga plagio-microcline granites and of 2.65 Ga peralkaline A-type granites, and small stocks of 2.52 Ga tourmaline granites. Four pegmatite fields with total amount of more than 100 bodies are confined to Kolmozero subzone. The pegmatites intrude amphibolites and rarely associated gabbro-anorthosite and are of 50-700m long and of 10-35m thickness. The Kolmozero pegmatites are of complex type, spodumene subtype with Li, Cs, Be, Ta, Sn geochemical signature and belong to LCT family by classification of Cerny and Ercit [1]. They crystallized at relatively high pressure (3-4 kbar) with peralumunious S-type granite as the source magma. The Vasin Myl'k pegmatite field with the lepidolite-albite-microcline-spodumene-pollucite association is located among amphibolites in the northwestern part of the Kolmozero zone. The minerals of the columbite-tantalite group from Vasin Myl'k field include microlite, simpsonite, and torolite, and are the earliest within the rare-element mineral sequence. Microlite from the pegmatite taken from the dump of a prospecting drill hole was used for U-Pb (TIMS) age determination. The discordia constructed for seven measured microlite samples is characterized by upper intercept with concordia at 2454±8 Ma, which probably reflects the time of rare-element pegmatite crystallization, coeval with the age of tourmaline granites. Several tens of pegmatite bodies from Keivy subzone are confined to inner and outer apical parts of peralkaline granite intrusions. They are of few tens meters long and of several meters thickness, sometimes are of oval and irregular shape (so-called quartzolites). Keivy pegmatites are subdivided on quartz-microcline, quartz-feldspar-astrophylite and quartz

  11. New techniques applied to the U-Pb method at the Centre for Geochronological Research of the University of Sao Paulo: chemical digestions, TIMS mass spectrometry and examples of integrated application of SHRIMP; Novas tecnicas aplicadas ao metodo U-Pb no CPGeo-IGc/USP: avancos na digestao quimica, espectrometria de massa (TIMS) e exemplos de aplicacao integrada com SHRIMP

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Kei; Basei, Miguel Angelo Stipp; Siga Junior, Oswaldo; Sproesser, Walter Mauricio; Passarelli, Claudia Regina [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Geociencias. Centro de Pesquisas Geocronologicas]. E-mails:;;;;


    The present work describes new techniques of U-Pb ID-TIMS developed at the CPGeo-IGc/USP. Techniques of partial and total chemical digestions, U and Pb concentration using anion exchange in a micro column, and the utilization of a {sup 205}Pb spike are discussed. Main geochronological equations used are also discussed. Examples of the application of U-Pb data, obtained by leaching technique using a microwave oven in zircon with isotopic inheritances in the core and border, are presented. The genesis of zircon based on the initial {sup 176}Hf/{sup 177}Hf ratio is discussed. Finally complete listings of the mathematical formulations used in the PBDAT software are given in the appendix. (author)

  12. Uranium in situ leaching

    International Nuclear Information System (INIS)


    Despite the depressed situation that has affected the uranium industry during the past years, the second Technical Committee Meeting on Uranium In Situ Leaching, organized by the International Atomic Energy Agency and held in Vienna from 5 to 8 October 1992, has attracted a relatively large number of participants. A notable development since the first meeting was that the majority of the contributions came from the actual operators of in situ leaching uranium production. At the present meeting, presentations on operations in the USA were balanced by those of the eastern European and Asian countries. Contributions from Bulgaria, China, Czechoslovakia, Germany (from the operation in the former German Democratic Republic), the Russian Federation and Uzbekistan represent new information not commonly available. In situ leach mining is defined in one of the paper presented as a ''mining method where the ore mineral is preferentially leached from the host rock in place, or in situ, by the use of leach solutions, and the mineral value is recovered. Refs, figs and tabs

  13. Sex in situ

    DEFF Research Database (Denmark)

    Krøgholt, Ida


    Sex er en del af vores sociale praksis og centralt for det, vi hver især er. Men bortset fra pornoindustrien, har vi ikke mange muligheder for at få adgang til billeder af sex. Teater Nordkrafts forestilling Sex in situ vil gøre seksuelle billeder til noget, der kan deles, udveksles og tales om, og...

  14. In Situ Cometary Cosmochemistry (United States)

    Wright, I. P.; Andrews, D. J.; Barber, S. J.; Sheridan, S.; Morgan, G. H.; Morse, A. D.


    In 2014 the Rosetta space mission arrives at comet 67P. Herein we describe the ambitions of one of the instruments, Ptolemy, included on the lander. Our aim is to make in situ measurements of isotopic compositions of elements such as H, C, N and O.

  15. Evolution Of An Upper Crustal Plutonic-Volcanic Plumbing System:Insights From High Precision U-Pb Zircon Geochronology Of Intracaldera Tuff And Intrusions In Silver Creek Caldera, Arizona, USA (United States)

    Zhang, T.; Mundil, R.; Miller, C. F.; Miller, J. S.; Paterson, S. R.


    Study of both plutonic and volcanic regimes in one single magmatic system is a powerful approach towards obtaining a more complete view of the long-term evolution of magma systems. The recently discovered Silver Creek caldera is the source of the voluminous Peach Spring Tuff (PST) (Ferguson, 2008) and presents a unique opportunity to study a field laboratory of a linked plutonic-volcanic system. This relict west-facing half caldera is predominantly filled with trachytic intracaldera tuff with the caldera margin intruded by several petrologically distinct hypabyssal intrusions. These include porphyritic granite with granophyric texture, felsic leucogranite, porphyritic monzonite exposed on NE side of the caldera that is zoned from more felsic to more mafic, and quartz-phyric dikes that intrude the caldera fill. We present preliminary single zircon ages from 4 samples that have been analyzed using the CA-TIMS method after thermal annealing and chemical leaching (Mattinson 2005), including 1 sample from intracaldera tuff and 3 samples from caldera-related intrusions. 3-D total U/Pb isochron ages from all four samples fall within a range of 18.32-18.90 Ma with uncertainties between 0.09 and 0.39 Ma, although some of them lack precision and are compromised by elevated common Pb. For example, zircon from the dated porphyritic monzonite yields an age of 18.32±0.42 Ma (MSWD=2.7) where the excess scatter may result from real age dispersion and/or different compositions of the common Pb contribution. The PST had been dated to ~18.5 Ma by 40Ar/39Ar techniques (Nielson et al., 1990). In order to be compared to U/Pb ages the 40Ar/39Ar age must be adjusted for a revised age for the then used flux monitor (MMbh-1) and corrected for the now quantified systematic bias between 40Ar/39Ar and U/Pb ages (Renne et al., 2010), which results in a corrected age of 18.8 Ma. Thus, the ages for our samples match that of the PST within error. Based on current results, the age difference

  16. U-Pb ages of detrital zircon from Cenozoic sediments in the southwestern Tarim Basin, NW China: Implications for Eocene-Pliocene source-to-sink relations and new insights into Cretaceous-Paleogene magmatic sources (United States)

    Yang, Wei; Fu, Ling; Wu, Chaodong; Song, Yan; Jiang, Zhenxue; Luo, Qun; Zhang, Ziya; Zhang, Chen; Zhu, Bei


    A detailed investigation of potential provenance is still lacking in the southwestern Tarim Basin, which restricts our complete understanding of Cenozoic source-to-sink relations between the basin interior and the Pamir salient - western Kunlun Mountain Range. Debate also exists concerning the potential sources of the Paleogene and Cretaceous igneous detritus present in the Cenozoic sedimentary sequences. Here, we present U-Pb (LA-ICP-MS) ages of detrital zircons from the continuous Eocene-Pliocene sediment series in the well-exposed Aertashi section to investigate changes in sediment provenance through time. The U-Pb detrital zircon ages range widely from 45 to 3204 Ma and can be divided into seven main groups: 45-65 Ma (sub-peak at 49 Ma), 67-103 Ma (sub-peak at 95 Ma), 196-251 Ma (sub-peak at 208 Ma), 252-416 Ma (sub-peak at 296 Ma), 417-540 Ma (sub-peak at 446 Ma), 550-1429 Ma (sub-peaks at 614 Ma, 828 Ma and 942 Ma) and 1345-3204 Ma (sub-peaks at 1773 Ma and 2480 Ma). These zircons were mainly derived from the western Kunlun Mountain Range and northern Pamir salient to the west and south. The evolution of the provenance and source-to-sink relationship patterns in the southwestern Tarim Basin can be divided into three stages: (1) The Middle Eocene to Lower Oligocene sediments display a wide variety of detrital zircon ages, suggesting that the source area was extensive. (2) A major change in provenance occurred during the Late Oligocene to Early Miocene and was characterized by an abrupt increase in the proportion of Triassic and Lower Paleozoic igneous components, implying a significant adjustment in topography induced by the initial uplift and exhumation of the western Kunlun Mountain Range and northern Pamir salient. (3) In the Late Miocene, the source-to-sink system transformed again, and contributions of Triassic to Lower Paleozoic material weakened substantially due to the sufficient indentation of the Pamir salient. Our integrated analyses of zircon

  17. Integrated provenance analysis of a convergent retroarc foreland system: U-Pb ages, heavy minerals, Nd isotopes, and sandstone compositions of the Middle Magdalena Valley basin, northern Andes, Colombia (United States)

    Nie, Junsheng; Horton, Brian K.; Saylor, Joel E.; Mora, Andrés; Mange, Maria; Garzione, Carmala N.; Basu, Asish; Moreno, Christopher J.; Caballero, Victor; Parra, Mauricio


    Sediment provenance analysis remains a powerful method for testing hypotheses on the temporal and spatial evolution of uplifted source regions, but issues such as recycling, nonunique sources, and pre- and post-depositional modifications may complicate interpretation of results from individual provenance techniques. Convergent retroarc systems commonly contain sediment sources that are sufficiently diverse (continental magmatic arc, fold-thrust belt, and stable craton) to enable explicit provenance assessments. In this paper, we combine detrital zircon U-Pb geochronology, heavy mineral identification, Nd isotopic analyses, conventional sandstone petrography, and paleocurrent measurements to reconstruct the clastic provenance history of a long-lived sedimentary basin now exposed in an intermontane zone of the northern Andean hinterland of Colombia. The Middle Magdalena Valley basin, situated between the Central Cordillera and Eastern Cordillera, contains a 5-10 km-thick succession of Upper Cretaceous to Quaternary fill. The integrated techniques show a pronounced change in provenance during the Paleocene transition from the lower to upper Lisama Formation. We interpret this as a shift from an eastern cratonic source to a western Andean source composed of magmatic-arc rocks uplifted during initial shortening of the Central Cordillera. The appearance of detrital chloritoid and a shift to more negative ɛ Nd(t=0) values in middle Eocene strata of the middle La Paz Formation are attributed to shortening-related exhumation of a continental basement block (La Cira-Infantas paleohigh), now buried, along the axis of the Magdalena Valley. The diverse provenance proxies also show distinct changes during middle to late Eocene deposition of the Esmeraldas Formation that likely reflect initial rock uplift and exhumation of the fold-thrust belt defining the Eastern Cordillera. Upsection, detrital zircon U-Pb ages and heavy mineral assemblages for Oligocene and younger clastic

  18. Reassessment of the geologic evolution of selected precambrian terranes in Brazil, based on new SHRIMP U-Pb data, part 1: central-eastern border of Sao Francisco Craton in Bahia state, Brazil

    International Nuclear Information System (INIS)

    Silva, Luiz Carlos da; Pimentel, Marcio; Jost, Hardy; Armstrong, Richard


    This paper discusses new U-Pb SHRIMP zircon data for 12 key-exposures of several geological units exposed at the eastern border of the Sao Francisco Craton. The samples represent mostly Archean basement units within the Paleoproterozoic Eastern Bahia Belt (Orogen). Samples were collected along several E-W tran sects trying to more accurately assess the areal distribution of the Archean polycyclic basement of the Sao Francisco Craton and to identify the limits of Paleoproterozoic metamorphic overprint resulting from the development of the Eastern Bahia Orogen. Owing to the polycyclic evolution and/or high grade metamorphic conditions which most of the rock units investigated have undergone, zircon morphology and the U-Pb analytical data exhibit very complex patterns. These are characterized by a combination of inheritance, partial resetting and new zircon growth during high grade metamorphism. As a consequence, very careful and detailed analyses of cathodoluminescence imagery were required to allow distinction between inheritance, newly melt-precipitated zircon and partially reset zircons, as well as between the ages of magmatic and metamorphic events. Except for one unit (sample LH 44), which present crystallization age of ca 3000 Ma - interpreted, therefore, as the eastern extension of the Serrinha Craton - the others are ascribed to two major age groups at ca. 2870-2500 Ma and ca. 2200?-2030 Ma. The former group includes ortho gneisses with crystallization ages between ca. 2870-2500 Ma, which have been mapped and interpreted, in its major extension, as juvenile Paleoproterozoic arc (Itabuna and Salvador-Curaca belts/domains). The new data presented in this study, however, indicate that these ortho gneisses represent a multi-episodic collage of primitive Archean orogenic arcs, which gave rise to the Archean basement of that part of the Sao Francisco Craton. All the investigated zircon populations were extensively recrystallized at ca. 2080-2050 Ma as a result of

  19. Early paleozoic granitoids in the southern Vanoise basement: U-Pb geochronology of the Arpont meta-granite (Savoy, French Alps); Granitoides d`age paleozoique inferieur dans le socle de Vanoise meridionale: geochronologie U-Pb du metagranite de l`Arpont (Alpes de Savoir, France)

    Energy Technology Data Exchange (ETDEWEB)

    Bertrand, J.M. [Laboratoire de geodynamique des chaines alpines, LGCA-CISM, 73 - Le Bourget-du-Lac (France); Leterrier, J. [Centre de recherches petrographiques et geochimique, 54 - Vandoeuvre-les-Nancy (France)


    The U-Pb age of a meta-granite from southern Vanoise (Brianconnais` domain) at 479{+-} 4 Ma confirms hat the micaschists which dominate this pre-alpine basement are, at least, of Early Paleozoic age. The rare magmatic rocks occurring in Vanoise and showing alkaline affinities, may be compared to the orthogneisses belonging to the Cambrian-Ordovician extensional event well known in other parts of the Varican belt. (authors) 27 refs.

  20. Characterization of Pollution Transport into Texas Using OMI and TES Satellite and In Situ data, and HYSPLIT Back Trajectory Analyses: implications for TCEQ State Implementation Plans and High School/Undergraduate STEM Education (United States)

    Boxe, C.; Bella, D.; Khaimova, J.; Culpepper, J.; Ahmed, N.; Belkalai, A.; Ealy, J.; Arroyo, I.; Lahoumh, M.; Jenkins, O.; Emmanuel, S.; Andrews, J.; Fu, D.; Wu, L.; Choi, Y.; Morris, G.; Osterman, G. B.; Johnson, L. P.; Austin, S. A.


    Using an online trajectory analysis tool NASA, ArcGIS, Satellite and EPA in situ data, we assess whether high pollution events in Texas are primarily sourced locally or remotely. We focus satellite data that exemplify high O3 and NO2 over Texas's lower troposphere. Four day back trajectory analyses of all dates show that upper-, mid-, and lower-tropospheric air over Texas, containing high O3, is transported from the Gulf of Mexico, Southeast USA, Midwest USA, Northeast USA, the Atlantic Ocean, Pacific Ocean, Mexico, etc. Only day showed air at 1 km is sourced within Texas. Satellite data show O3 enhancements in the boundary layer and O3 and NO2 enhancements via tropospheric column profiles. These enhancements complement four-day trajectory analysis. This study provides a viable basis for more quantifiable and accurate information for developing effective air quality State Implementation Plans. STEM Impact: (i) D. Bella was an NSF-LSAMP undergraduate research mentee with me at Medgar Evers College-CUNY; she received a B.S. in Environmental Science (and a Chemistry Minor) and is now a Ph.D. graduate student at University at Albany's School of Public Health. (ii) J. Khaimova is an undergraduate Geology and Planetary Science B.S. major at Brooklyn College-CUNY. I have supported Jessica's summer internship in summer 2013 as a CUNY Summer Research Fellow, where she is currently an NSF-REU research mentee at Pennsylvania State University's Meteorology Department. (iii) J. Culpepper received his B.S. in Environmental Science from MEC-CUNY and will be a Ph.D. student, Fall 2014 at University of Iowa's Civil and Environmental Engineering Department. (iv) S. Gentle was a high school researcher with me within ACS's Project SEED Program for high school students. S. Gentle will start her undergraduate career Fall 2014 at Pennsylvania State University and seeks to attain a B.S. in Chemistry. (v). All parties, including high school and undergraduate researchers seek to attend

  1. Structure, petrology and U-Pb zircon age of Mesoproterozoic nepheline syenites from the Rengali Province, eastern India: Implications for their petrogenesis and geodynamic evolution (United States)

    Sheikh, Janisar M.; Champati, Anil K.; Patel, Suresh C.; Prabhakar, Naraga; Gerdes, Axel


    titanite in fracture-controlled openings in primary microcline and amphibole, respectively. Trace element analyses of the rocks show elevated concentrations of LILE and HFSE, near chondritic to superchondritic ratios of Nb/Ta(16 - 28) and Zr/Hf(31 - 78), and REE patterns with enrichment of LREE over HREE (LaN/Y bN = 4.5 - 70) and small or no Eu anomaly (Eu/Eu∗ = 0.3 - 2.0) which indicate derivation of the parental melt by low degree of partial melting of an enriched mantle source. Pyrolite-normalized spidergrams show positive Nb - Ta anomalies, and negative Sr - Ba anomalies which argue against a subduction related origin of the rocks. Igneous zircons from the intrusions have been dated at 1322±8 Ma (U -Pb concordant age, LA-ICP-MS). Electron microprobe U -Th-Pb dating of monazites from mica schists in the metasedimentary sequence yield peak metamorphic age in the range of 1283±13 Ma to 1333±11 Ma which indicates synchronism of the nepheline syenite magmatism and sillimanite grade regional metamorphism of the metasedimentary sequence. Contrary to the common belief that nepheline syenite plutons in eastern India were emplaced in intra-continental rifts and subsequently deformed by continental collision, we propose a geodynamic scenario in which the nepheline syenites of the Rengali Province have been emplaced in localised domains of extension in an overall transpressional regime.

  2. Shrimp and conventional U-Pb age, Sm-Nd isotopic characteristics and tectonic significance of the K-rich Itapuranga suite in Goias, Central Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Pimentel, Marcio M.; Dantas, Elton L.; Fuck, Reinhardt A. [Brasilia Univ., DF (Brazil). Inst. de Geociencias. Lab. de Geocronologia]. E-mail:;; Armstrong, Richard A. [Australian National Univ., Canberra (Australia). Research School of Earth Sciences


    The Itapuranga alkali granite and Uruana quartz syenite are large K-rich E W-elongated intrusions, in the central part of the Neoproterozoic Brasilia Belt, central Brazil. They are associated with Pireneus lineaments, which cut the regional NNW-SSE structures of the southern part of the belt. SHRIMP and conventional U-Pb data for the Itapuranga and Uruana intrusions indicate crystallization ages of 624 {+-} 10 Ma and 618 {+-} Ma, respectively. Three zircon cores from the Itapuranga granite yielded U-Pb ages between 1.79 and 1.49 Ga. Sm-Nd T{sub DM} ages for both intrusions are 1.44 Ga and epsilon{sub Nd}(T) values are -5.1 and -5.7, suggesting the input of material derived from older (Paleo- to Mesoproterozoic) sialic crust in the origin of the parental magmas. Magma mixing structures indicate co-existence of mafic and felsic end-members. The felsic end-member of the intrusions is dominantly represented by crust-derived melts, formed in response to the invasion of Paleo/Mesoproterozoic sialic crust by alkali-rich mafic magmas at ca. 620 Ma. These intrusions are roughly contemporaneous with, or perhaps slightly younger than, the peak of regional metamorphism in the southern Brasilia Belt. Their emplacement along the Pireneus lineament suggest a syn-tectonic origin for them, most probably in transtensional settings along these faults. (author)

  3. Zircon U-Pb geochronology and Sr-Nd-Pb-Hf isotopic constraints on the timing and origin of Mesozoic granitoids hosting the Mo deposits in northern Xilamulun district, NE China (United States)

    Shu, Qihai; Lai, Yong; Zhou, Yitao; Xu, Jiajia; Wu, Huaying


    Located in the east section of the Central Asian orogen in northeastern China, the Xilamulun district comprises several newly discovered molybdenum deposits, primarily of porphyry type and Mesozoic ages. This district is divided by the Xilamulun fault into the southern and the northern parts. In this paper, we present new zircon U-Pb dating, trace elements and Hf isotope, and/or whole rock Sr-Nd-Pb isotopic results for the host granitoids from three Mo deposits (Yangchang, Haisugou and Shabutai) in northern Xilamulun. Our aim is to constrain the age and petrogenesis of these intrusions and their implications for Mo mineralization. Zircon U-Pb LA-ICP-MS dating shows that the monzogranites from the Shabutai and Yangchang deposits formed at 138.4 ± 1.5 and 137.4 ± 2.1 Ma, respectively, which is identical to the molybdenite Re-Os ages and coeval well with the other Mo deposits in this region, thereby indicating an Early Cretaceous magmatism and Mo mineralization event. Zircon Ce/Nd ratios from the mineralized intrusions are significantly higher than the barren granites, implying that the mineralization-related magmas are characterized by higher oxygen fugacity. These mineralized intrusions share similar zircon in-situ Hf and whole rock Sr-Nd isotopic compositions, with slightly negative to positive εHf(t) ranging from - 0.8 to + 10.0, restricted εNd(t) values from - 3.7 to + 1.6 but a little variable (87Sr/86Sr)i ratios between 0.7021 and 0.7074, indicative of formation from primary magmas generated from a dominantly juvenile lower crust source derived from depleted mantle, despite diverse consequent processes (e.g., magma mixing, fractional crystallization and crustal contamination) during their evolution. The Pb isotopes (whole rock) also show a narrow range of initial compositions, with (206Pb/204Pb)i = 18.03-18.88, (207Pb/204Pb)i = 15.48-15.58 and (208Pb/204Pb)i = 37.72-38.28, in agreement with Sr-Nd-Hf isotopes reflecting the dominance of a mantle component

  4. Geology, mineralization, U-Pb dating and Sr-Nd isotope geochemistry of intrusive bodies in northeast of Kashmar

    Directory of Open Access Journals (Sweden)

    Alireza Almasi


    Full Text Available Alireza Almasi1, Mohammad Hassan Karimpour1*, Khosrow Ebrahimi Nasrabadi1, Behnam Rahimi1, Urs KlÖtzli2 and Jose Francisco Santos3 Introduction The study area is located in central part of the Khaf- Kashmar-Bardeskan belt which is volcano-plutonic belt at the north of the Dorouneh fault in the north of Lut block. The north of the Lut block is affected by tectonic rotation and subduction processes which occur in the east of Iran (Tirrul et al., 1983. The magmatism of Lut block begins in Jurassic and continues in Tertiary (Aghanabati, 1995. Karimpour (Karimpour, 2006 pointed out the Khaf-Kashmar-Bardeskan belt has significant potential for IOCG type mineralization such as Kuh-e-Zar, Tannurjeh, and Sangan (Karimpour, 2006; Mazloumi, 2009. The data gathered on the I-type intrusive rocks include their field geology, petrography, U–Pb zircon dating and Sr–Nd isotope and also alteration and mineralization in the study area. Materials and methods - Preparation of 150 thin sections of rock samples for study of petrography and alteration of the intrusive rocks. - Magnetic susceptibility measuring of intrusive rocks. - U-Pb dating in zircon of I-type intrusive rocks by Laser-Ablation Multi Collector ICP-MS method. - Sr-Nd analysis on 5 samples of I-type intrusive rocks by Multi-Collector Thermal Ionization Mass Spectrometer (TIMS VG Sector 54 instrument. - Mineralography and paragenetic studies of ore-bearing quartz veins and geochemical analysis for 28 samples. - Production of the geology, alteration and mineralization maps by scale: 1:20000 in GIS. Results Oblique subduction in southern America initiated an arc-parallel fault and shear zones in the back of continental magmatic arc (Sillitoe, 2003. Because of this event, pull-apart basins were formed and high-K to shoshonitic calc-alkalineI- and A-type magmatism occur (Sillitoe, 2003. Most important deposits accompany with this magmatism are Au-Cu deposits types and Fe-Skarns (Sillitoe, 2003. We have

  5. U-Pb SHRIMP and Sm-Nd geochronology of the Silvânia Volcanics and Jurubatuba Granite: juvenile Paleoproterozoic crust in the basement of the Neoproterozoic Brasília Belt, Goiás, central Brazil

    Directory of Open Access Journals (Sweden)



    Full Text Available U-Pb SHRIMP and Sm-Nd isotopic ages were determined for felsic metavolcanic rocks from the Silvânia Sequence and Jurubatuba Granite in the central part of the Brasília Belt. Zircon grains from a metavolcanic sample yielded 2115 ± 23 Ma and from the granite yielded 2089 ± 14 Ma, interpreted as crystallization ages of these rocks. Six metavolcanic samples of the Silvânia Sequence yielded a six-point whole-rock Sm-Nd isochron indicating a crystallization age of 2262 ± 110 Ma and positive epsilonNd(T = +3.0 interpreted as a juvenile magmatic event. Nd isotopic analyses on samples from the Jurubatuba Granite have Paleoproterozoic T DM model ages between 2.30 and 2.42 Ga and epsilonNd(T values vary between -0.22 and -0.58. The oldest T DM value refers to a sedimentary xenolith in the granite. These results suggest crystallization ages of Silvânia volcanics and Jurubatuba Granite are the first evidence of a ca. 2.14-2.08 juvenile magmatic event in the basement of the central part of the Brasília Belt that implies the presence of arc/suture hidden in reworked basement of the Brasília Belt.

  6. U-Pb SHRIMP and Sm-Nd geochronology of the Silvania Volcanics and Jurubatuba Granite: juvenile paleoproterozoic crust in the basement of the Neo proterozoic Brasilia Belt, Goias, central Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Fischel, Danielle P.; Pimentel, Marcio M.; Fuck, Reinhardt A. [Brasilia Univ., DF (Brazil). Inst. de Geociencias; Armstrong, Richard [Australian National Univ., Canberra (Australia). Research School of Earth Sciences


    U-Pb SHRIMP and Sm-Nd isotopic ages were determined for felsic meta volcanic rocks from the Silvania Sequence and Jurubatuba Granite in the central part of the Brasilia Belt. Zircon grains from a meta volcanic sample yielded 2115 {+-} 23 Ma and from the granite yielded 2089 {+-}14 Ma, interpreted as crystallization ages of these rocks. Six meta volcanic samples of the Silvania Sequence yielded a six-point whole-rock Sm-Nd isochron indicating a crystallization age of 2262 {+-}110 Ma and positive {epsilon}{sub Nd} (T) = +3.0 interpreted as a juvenile magmatic event. Nd isotopic analyses on samples from the Jurubatuba Granite have Paleoproterozoic T{sub DM} model ages between 2.30 and 2.42 Ga and {epsilon}{sub Nd} (T) values vary between -0.22 and -0.58. The oldest T{sub DM} value refers to a sedimentary xenolith in the granite. These results suggest crystallization ages of Silvania volcanics and Jurubatuba Granite are the first evidence of a ca. 2.14-2.08 juvenile magmatic event in the basement of the central part of the Brasilia Belt that implies the presence of arc/suture hidden in reworked basement of the Brasilia Belt. (author)

  7. Re-appraisal of the Santa Rita Greenstone Belt stratigraphy, central Brazil, based on new U-Pb SHRIMP age and Sm-Nd data of felsic metavolcanic rocks

    Energy Technology Data Exchange (ETDEWEB)

    Pimentel, Marcio Martins; Jost, Hardy; Fuck, Reinhardt Adolfo; Junges, Sergio Luiz [Brasilia Univ., DF (Brazil). Inst. de Geociencias]. E-mail:; Armstrong, Richard [Australian National Univ., Canberra, ACT (Australia). Research School of Earth Sciences; Resende, Marcelo Goncalves [Universidade Catolica de Brasilia, DF (Brazil). Curso de Graduacao em Engenharia Ambiental


    The Santa Rita greenstone belt represents one of the supracrustal belts of the Archaen terranes of Goias, central Brazil. The stratigraphic sequence of this greenstone belt comprises a lower of komatities and basalts and an upper metasedimentary unit made of carbonaceous schits, chert, iron formation and marble, unconformably overlain by clastic metasedimentary rocks. Felsic metavolcanics occur at the interface between the metabasalts and the upper metasedimentary pile. U-Pb SHRIMP age for zircons from the felsic metavolcanics reveal that it is not part of the Archaean sequence, but represents the product of mesoproterozoic (1580 {+-} 12 Ma) magmatic event. Sm-Nd isotopic data (initial e{sub CHUR} values between -10.5 and -14.9) and T{sub DM} values of 3.0 and 3.2 Ga, within the range of the surrounding TTG terranes, indicate that the original felsic magmas were produced by re-melting of Archaen crust. The data demonstrate that the Goias greenstone belt contains infolded and imbricated proterozoic rocks, as previously suggested by Sm-Nd isotopic analyses of some of the upper detrital metasedimentary rocks. (author)

  8. Achaean TTG and high alimunia gneisses on Baltic Shield: Precise U-Pb (ID-TIMS) and SHRIMP-II ages on single zircon (United States)

    Bayanova, Tamara; Morozova, Ludmila; Mitrofanov, Felix; Serov, Pavel; Nitkina, Elena; Fedotov, Dzorzh; Larionov, Alexander


    New U-Pb (ID-TIMS) data on single zircon from high alimunia gneisses near Murmansk in the Central-Kola domain gave 3.17 Ga. Core from these zircon population has the age 3695±5 Ma by SHRIMP-II. Time of amphibolites metamorphism was dated with 2753±3 Ma. Achaean gneisses in Monchegorsk ore region were firstly dated in the Central-Kola domain. Single zircon from gneisses in Monchegorsk region which are the basement for Paleoproterozoic PGE layered intrusions with U-Pb ages on zircon and baddeleyite from 2.4-to 2.5 Ga (Bayanova et all, 2009) has 3.16 Ga. Single zircon from gnneisses gave 2776±3 Ma and is considered as amphibolites metamorphism. Voche-Lambina international polygon lies on the boundary between Belomorian mobile block and Central -Kola domain (Morozova et al, 2011). New neoarhaean U-Pb data on single zircon from TTG of polygon yielded 3158.2±8.2. Zircon are characterized by low concentration U and Pb, low U/Th ratio with 0.2. REE diagrams of grey gneisses reflect high fractionation La/Yb>30,encriched by light REE and depleted by heavy Yb<0.6 ppm. Model Sm-Ng ages on the rocks have protolith from with the ages 3.4 to 3.2 Ga, positive ɛNd from +1.29 to +3.3, ISr equals 0.702. Precise (ID-TIMS) age of amphibolites metamorphism has been dated on single zircon with 2704.3±5.9 Ma. In the frame of the Central-Kola domain there is an Ingosersky TTG complex. Firstly U-Pb dating on single zircon from Bt-gneisses reflects 3149±49 Ma. Metamorphic alterations were in 2725.2±2.5 Ma and connected with origin of Amf-Bt gneisses and 2733.6±6.6 with Bt-Amf gneisses. (NItkina et al., 2012). Therefore based on the new data on single zircon from TTG and high alimunia gneisses from Central-Kola domain leads to the long history of continental crust origin in the Baltic or Fennoscandian Shield from 3.16 to 3.7 Ga. We thank to G. Wasserburg for 205 Pb artificial spike, J. Ludden for 91500 and Temora standards, F. Corfu, V. Todt and U. Poller for assistance in the

  9. Grenvillian age magmatism in the Southern Espinhaço Range (Minas Gerais): evidence from U-Pb zircon ages.


    Chaves, Mario Luiz de Sá Carneiro; Silva, Márcio Célio Rodrigues da; Scholz, Ricardo Augusto; Babinski, Marly


    Este trabalho descreve a primeira possível ocorrên¬cia in situ de uma rocha vulcânica datada no período Grenvilleano (~ 1,4 – 1,0 Ga) na Serra do Espinhaço Meridional, com idade máxima de deposição em ca. 1,16 Ga. A amostra Vul-1A, intrusiva no Com¬plexo Basal arqueano, possui estrutura brechoide, formada por clastos de xistos, formações ferríferas (FFs), rochas vulcânicas e granitoides, em matriz vulcânica muito fina a média, petrograficamente de natureza básica com tendência alcalina, defin...

  10. In-Situ Simulation

    DEFF Research Database (Denmark)

    Bjerregaard, Anders Thais; Slot, Susanne; Paltved, Charlotte


    offered in situ simulation faculty with a model for integrating reported critical incidents and adverse events with contextual needs analysis and short-term observations. Furthermore the research group is working on detailing the barriers of in situ simulation such as resources for team training despite...... emergencies. It contains 12 questions, which are rated using a five-point scale, and covers four categories; leadership, teamwork and task management, and an overall score on team performance. Results: 16 simulations were conducted with 16 different teams of 10 doctors and 32 nurses. First, this study took...... of handovers. The team performance varied greatly according to how well the team members knew each other professionally as confirmed by video recordings. SAQ, and TEAM observational data are being analyzed by the research group with focus on correlation with teamwork and handovers. In summary, this study...

  11. In Situ Mass Spectrometer Project (United States)

    National Aeronautics and Space Administration — The In Situ Mass Spectrometer projects focuses on a specific subsystem to leverage advanced research for laser-based in situ mass spectrometer development...

  12. Tectono-thermal evolution of the southwestern Alxa Tectonic Belt, NW China: Constrained by apatite U-Pb and fission track thermochronology (United States)

    Song, Dongfang; Glorie, Stijn; Xiao, Wenjiao; Collins, Alan S.; Gillespie, Jack; Jepson, Gilby; Li, Yongchen


    The Central Asian Orogenic Belt (CAOB) is regarded to have undergone multiple phases of intracontinental deformation during the Meso-Cenozoic. Located in a key position along the southern CAOB, the Alxa Tectonic Belt (ATB) connects the northernmost Tibetan Plateau with the Mongolian Plateau. In this paper we apply apatite U-Pb and fission track thermochronological studies on varieties of samples from the southwestern ATB, in order to constrain its thermal evolution. Precambrian bedrock samples yield late Ordovician-early Silurian ( 430-450 Ma) and late Permian ( 257 Ma) apatite U-Pb ages; the late Paleozoic magmatic-sedimentary samples yield relatively consistent early Permian ages from 276 to 290 Ma. These data reveal that the ATB experienced multiple Paleozoic tectono-thermal events, as the samples passed through the apatite U-Pb closure temperature ( 350-550 °C). We interpret these tectonic events to record the long-lived subduction-accretion processes of the Paleo-Asian Ocean during the formation of the southern CAOB, with possible thermal influence of the Permian Tarim mantle plume. Apatite fission track (AFT) data and thermal history modelling reveal discrete low-temperature thermal events for the ATB, inducing cooling/reheating through the AFT partial annealing zone ( 120-60 °C). During the Permian, the samples underwent rapid cooling via exhumation or denudation from deep crustal levels to temperatures < 200 °C. Subsequent thermal events in the Triassic were thought to be associated with the final amalgamation of the CAOB or the closure of the Paleotethys. During the Jurassic-Cretaceous the study area experienced heating by burial, followed by renewed cooling, which may be related with the construction and subsequent collapse of the Mongol-Okhotsk Orogeny, or the Lhasa-Eurasia collision and subsequent slab break-off. These results indicate that the ATB may have been stable after late Cretaceous in contrast to the Qilian Shan and Tianshan. Finally, our

  13. Is the Macquarie Arc (Lachlan Orogen) An Exotic Terrane or Formed on the Gondwanan Margin? Reappraisal by SHRIMP U-Pb Dating of Volcano-Sedimentary Rocks (United States)

    Buckman, S.; Zhang, Q.; Nutman, A. P.


    A fundamental question concerning the Ordovician Macquarie Arc rocks is did they form within the palaeo-Pacific Ocean and are entirely juvenile, or did they evolve on the periphery of Gondwana? This is a key issue to ongoing debates concerning the growth of the eastern Gondwanan margin throughout the Palaeozoic. This problem is complicated by the arc now occurs as several slices, in post-arc tectonic contact with the eastern Gondwanan Ordovician Adaminaby Group. The dispersal of the arc as tectonic slices means that the temporal correlation of lithologies across the extent of the arc's exposure needs to be verified via U-Pb zircon geochronology. Our zircon U-Pb geochronology reveals that samples with the oldest zircons of Palaeozoic volcanic origin do not contain any Gondwanan-sourced zircons (particularly Cambrian and Neoproteorzoic). These samples, particularly some ascribed to the Weemalla Formation and Mitchell Formation have unimodal zircon populations of 450.5 Ma and 479.8 Ma. On the other hand, some samples with somewhat younger volcanic populations of 415 Ma and 458 Ma contain some Gondwanan-sourced older detrital zircons as well. Some of these latter samples are derived from outcrops that have previously consigned to the Yarrimbah Formation, should be older than, or equivalent to, the samples with the unimodal volcanic zircon populations of 480 Ma. This shows clearly that the consignment of some Macquarie Arc units to particular formations needs to be revised. The geochemical and radiogenic isotopic characteristics of the Macquarie Arc indicate that it is dominated by products of an intra-oceanic island arc that developed contemporaneously but spatially separated from Adaminaby Group passive margin sedimentation along eastern Gondwana. However, because our new U-Pb zircon data reveals that only samples with the youngest volcanic zircons also contain Gondwanan zircons, it shows that before the death of the arc, it was proximal to the Gondwanan margin

  14. LA-ICP-MS zircon U-Pb and muscovite K-Ar ages of basement rocks from the south arm of Sulawesi, Indonesia (United States)

    Jaya, Asri; Nishikawa, Osamu; Hayasaka, Yasutaka


    The zircon U-Pb and muscovite K-Ar age from the Bantimala, Barru and Biru basement complexes in the South Arm of Sulawesi, Indonesia provide new information regarding the timing of magmatism, metamorphism and sedimentation in this region and have implications for the origin and evolution of the study area. The study area is at the juncture between the southeast margin of Sundaland and Bird's Head-Australia. The age of both the zircon U-Pb of detrital materials in the Bantimala Complex and the muscovite K-Ar of amphibolite in the Biru Complex fall in the Late Early Cretaceous (between 109 and 115 Ma), which is a similar age range to previous data for both the sedimentary and metamorphic rocks. The youngest detrital zircon in the schist samples from the Barru Complex fall into the Triassic in age (between 243 and 247 Ma). These age data indicate that the protolith of all three basement complexes were involved in the subduction system and metamorphosed in the late Early Cretaceous, but there are several differences in their deposition environment under and out of the influence of the late Early Cretaceous magmatism in the Bantimala and Barru Complexes, respectively. Felsic igneous activities are confirmed in the Late Cretaceous and the Eocene by the zircon U-Pb age of igneous rocks intruding or included as detrital fragments in three basement complexes. These dates are similar to those reported from the Meratus Complex of South Kalimantan. The detrital zircon age distributions of the basement rocks in the South Arm of Sulawesi display predominant Mesozoic (Cretaceous and Triassic) and Paleozoic populations with a small population of Proterozoic ages supporting the hypothesis that the West Sulawesi block originated from the region of the circum Bird's Head-Australian, namely the Inner Banda block. The absence of Jurassic zircon age population in the South Arm of Sulawesi suggests the division of the South Arm of Sulawesi from the Inner Banda block in early stage of

  15. Malignant mesothelioma in situ. (United States)

    Churg, Andrew; Hwang, Harry; Tan, Larry; Qing, Gefei; Taher, Altaf; Tong, Amy; Bilawich, Ana M; Dacic, Sanja


    The existence of malignant mesothelioma in situ (MIS) is often postulated, but there are no accepted morphological criteria for making such a diagnosis. Here we report two cases that appear to be true MIS on the basis of in-situ genomic analysis. In one case the patient had repeated unexplained pleural unilateral effusions. Two thoracoscopies 9 months apart revealed only visually normal pleura. Biopsies from both thoracoscopies showed only a single layer of mildly reactive mesothelial cells. However, these cells had lost BRCA1-associated protein 1 (BAP1) and showed loss of cyclin-dependent kinase inhibitor 2 (CDKN2A) (p16) by fluorescence in-situ hybridisation (FISH). NF2 was not deleted by FISH but 28% of the mesothelial cells showed hyperploidy. Six months after the second biopsy the patient has persisting effusions but no evidence of pleural malignancy on imaging. The second patient presented with ascites and minimal omental thickening on imaging, but no visual evidence of tumour at laparoscopy. Omental biopsy showed a single layer of minimally atypical mesothelial cells with rare tiny foci of superficial invasion of fat. BAP1 immunostain showed loss of nuclear BAP1 in all the surface mesothelial cells and the invasive cells. There was CDKN2A deletion, but no deletion of NF2 by FISH. These cases show that morphologically bland single-layered surface mesothelial proliferations with molecular alterations seen previously only in invasive malignant mesotheliomas exist, and presumably represent malignant MIS. More cases are need to understand the frequency of such changes and the time-course over which invasive tumour develops. © 2018 John Wiley & Sons Ltd.

  16. In situ breast cancer

    International Nuclear Information System (INIS)

    Pacheco, Luis


    In situ breast cancer, particularly the ductal type, is increasing in frequency in the developed countries as well as in Ecuador, most probably. These lesions carry a higher risk of developing a subsequent invasive cancer. Treatment has changed recently due to results of randomized studies, from classical mastectomy to conservative surgery associated to radiotherapy. The Van Nuys Prognostic Index is currently the most usual instrument to guide diagnosis and treatment. Tamoxifen seems to decrease significantly the risk of tumor recurrence after initial treatment. (The author)

  17. Zircon U-Pb ages, Hf isotope data, and tectonic implications of Early-Middle Triassic granitoids in the Ailaoshan high-grade metamorphic belt of Southeast Tibet (United States)

    Wu, Wenbin; Liu, Junlai; Chen, Xiaoyu; Zhang, Lisheng


    The Ailaoshan tectonic belt, where the effects of the Paleo-Tethyan ocean evolution and Indian-Eurasian plate collision are superimposed, is one of the most significant geological discontinuities in western Yunnan province of southeast Tibet. An Ailaoshan micro-block within the belt is bounded by the Ailaoshan suture zone to the west and the Red River Fault to the east, and consists of low- and high-grade metamorphic belts. Late Permian-Middle Triassic granitoids that are widely distributed to the west of the Ailaoshan suture zone and within the Ailaoshan micro-block may yield significant information on the Tethyan tectonic evolution of the Ailaoshan tectonic belt. This study reports new LA-ICP-MS zircon U-Pb geochronology and Hf isotope data of four granitoids from the Ailaoshan high-grade metamorphic belt. Zircon grains from the Yinjie granitoid do not have inherited cores and yield a weighted mean U-Pb age of 247.1 ± 2.0 Ma. The zircon ɛ Hf( t) values range from 7.8 to 12.1, and Hf model ages from 775 to 546 Ma, indicating that the granitoid was derived from juvenile crust. The rims of zircons from the Majie and Yuanjiang granitoids yield weighted mean U-Pb ages of 239.5 ± 1.8 and 237.9 ± 2.6 Ma, respectively, whereas the cores yield ages of 1608-352 Ma. The ɛ Hf( t) values of zircon rims range from -20.4 to -5.3, yielding Hf model ages from 2557 to 1606 Ma and suggesting that the source magma of the Majie and Yuanjiang granitoids was derived from ancient crust. An additional granitoid located near the Majie Village yields a zircon U-Pb age of 241.2 ± 1.0 Ma. Based on our geochronological and geochemical data, combined with geological observations, we propose that the Ailaoshan micro-block was derived from the western margin of the Yangtze block, and is comparable to the Zhongzan and Nam Co micro-blocks. The presence of late Permian mafic rocks with rift-related geochemical characteristics within the Ailaoshan micro-block, together with granitoids derived

  18. U-Pb La-ICP-ms geochronology and regional correlation of middle Jurassic intrusive rocks from the Garzon Massif, Upper Magdalena Valley and central cordillera, southern Colombia

    International Nuclear Information System (INIS)

    Bustamante, Camilo; Cardona, Agustin; Bayona, German; Mora, Andres; Valencia, Victor; Gehrels, George; Vervoort, Jeff


    New U-Pb zircon geochronology from four granitic units sampled along a southeast-northwest transect between the Garzon massif and the Serrania de las Minas (central cordillera), records a middle Jurassic magmatic activity with two different spatio-temporal domains at ca. 189 ma and 180-173 ma. Reconnaissance data suggest that the four granitoids are characterized by mineralogical and geochemical characteristics akin to a continental magmatic arc setting. The new results suggest that the southern Colombian continental margin includes remnants of tectonomagmatic elements formed by the subduction of the Farallon plate under the South American continental margin. This middle Jurassic arc magmatism is part of the broader Andean scale arc province, and is significant for understanding the tectonic and paleogeographic scenario that characterized the Mesozoic tectonic evolution of the northern Andes.

  19. Possible zircon U-Pb evidence for Pan-African granulite-facies metamorphism in the Mozambique belt of southern Tanzania

    International Nuclear Information System (INIS)

    Coolen, J.J.M.M.M.


    Four zircon fractions of garnet-bearing two-pyroxene granulite, from the Furua granulite complex of southern Tanzania, plot very close to concordia. A discordia yields a lower intercept at 652 +- 10 Ma, an age slightly higher than the Rb-Sr whole-rock and mineral ages reported from the surrounding amphibolite-facies rocks. The U-Pb systematics indicate the presence of a very small amount of older (2-3 Ga) radiogenic lead. The zircon data may be interpreted as indicating an event of granulite-facies metamorphism during the Pan-African thermotectonic episode. This interpretation is at variance with current models postulating that the granulite complexes in the Mozambique belt are relicts of older, possibly Archaean events of metamorphism. (Auth.)

  20. Strong evidence for enhanced multiple electron capture from surfaces in 46 MeV/u Pb81+ collisions with thin carbon foils. (United States)

    Bräuning, H; Mokler, P H; Liesen, D; Bosch, F; Franzke, B; Krämer, A; Kozhuharov, C; Ludziejewski, T; Ma, X; Nolden, F; Steck, M; Stöhlker, T; Dunford, R W; Kanter, E P; Bednarz, G; Warczak, A; Stachura, Z; Tribedi, L; Kambara, T; Dauvergne, D; Kirsch, R; Cohen, C


    Strong evidence has been found for enhanced multiple electron capture into 46 MeV/u Pb81+ with a significant contribution from the entrance surface of thin carbon foils. Capture of up to five electrons has been observed. The multiple electron capture yield is found to increase with decreasing target thickness for thin targets. A simple model describing the data and showing the importance of capture from surfaces is discussed. Further evidence is found for a pronounced asymmetry between electron capture at the entrance and the exit surfaces. Absolute yields for multiple electron capture and projectile ionization are presented. The experimental total cross sections for single capture and ionization agree well with theory.

  1. New U-Pb SHRIMP zircon ages for pre-variscan orthogneisses from Portugal and their bearing on the evolution of the Ossa-Morena tectonic zone. (United States)

    Cordani, Umberto G; Nutman, Allen P; Andrade, Antonio S; Santos, José F; Azevedo, Maria do Rosário; Mendes, Maria Helena; Pinto, Manuel S


    New SHRIMP U-Pb zircon ages for the Portalegre and Alcáçovas orthogneisses document a complex pre- Variscan history for the Iberian basement in Portugal. The available geochemical and geochronological data for the Alcáçovas orthogneiss (ca. 540 Ma) tend to favor its involvement in a Cadomian orogenic event. This is consistent with the development of an active continental margin setting at the end of the Proterozoic and supports a Gondwanan provenance for the Iberian crust. On the other hand, the Ordovician emplacement age obtained for the magmatic precursors of the Portalegre orthogneisses (497 +/- 10 Ma) provides additional evidence for the occurrence of rift-related magmatic activity during the Lower Paleozoic.

  2. New U-Pb SHRIMP zircon ages for pre-variscan orthogneisses from Portugal and their bearing on the evolution of the Ossa-Morena tectonic zone

    Directory of Open Access Journals (Sweden)

    Cordani Umberto G.


    Full Text Available New SHRIMP U-Pb zircon ages for the Portalegre and Alcáçovas orthogneisses document a complex pre- Variscan history for the Iberian basement in Portugal. The available geochemical and geochronological data for the Alcáçovas orthogneiss (ca. 540 Ma tend to favor its involvement in a Cadomian orogenic event. This is consistent with the development of an active continental margin setting at the end of the Proterozoic and supports a Gondwanan provenance for the Iberian crust. On the other hand, the Ordovician emplacement age obtained for the magmatic precursors of the Portalegre orthogneisses (497?10 Ma provides additional evidence for the occurrence of rift-related magmatic activity during the Lower Paleozoic.

  3. Rb/Sr and U/Pb isotopic ages in basement rocks of Mina Gonzalito and Arroyo Salado, Atlantic North-Patagonian Massif, Rio Negro, Argentina

    International Nuclear Information System (INIS)

    Varela, Ricardo; Sato, Ana M.; Cingolani, Carlos A.; Basei, Miguel A.S.; Siga, Oswaldo; Sato, Kei


    Isotopic ages from metamorphic and plutonic rocks of the Atlantic area of North Patagonian basement indicate that the main crustal tectonic events occurred during the late Proterozoic to early Paleozoic times. Rb/Sr and U/Pb data in the 550-470 Ma interval suggest an old tecto-thermal activity during the upper Brazilian Cycle (Rio Doce Orogeny). At regional scale, the comparable Neo proterozoic basement of Ventania and sedimentary for eland cover of Tandilia continues to the Northeast, in the Dom Feliciano Belt. A possible correlation of the North Patagonian basement with igneous-metamorphic relics of Central Argentina (Pampean Ranges of San Luis-Cordoba and at La Pampa province) is also indicated. (author)

  4. Geochronological data from the Faxinal coal succession, southern Parana Basin, Brazil: A preliminary approach combining radiometric U-Pb dating and palynostratigraphy

    Energy Technology Data Exchange (ETDEWEB)

    Guerra-Sommer, M.; Cazzulo-Klepzig, M.; Menegat, R.; Formoso, M.L.L.; Basei, M.A.; Barboza, E.; Simas, M.W. [Universidade Federal do Rio Grande do Sul, Porto Alegre (Brazil)


    A radiometric zircon age of 285.4 {+-} 8.6 Ma (IDTIMS U-Pb) is reported from a tonstein layer interbedded with coal seams in the Faxinal coalfield, Rio Grande do Sul, Brazil. Calibration of palynostratigraphic data with the absolute age shows that the coal depositional interval in the southern Parana Basin is constrained to the Sakmarian. Consequently, the basal Gondwana sequence in the southern part of the basin should lie at the Carboniferous-Permian boundary, not within the Sakmarian as previously considered. The new results are significant for correlations between the Parana Basin and the Argentinian Paganzo Basin (302 {+-} 6 Ma and 288 {+-} 7 Ma) and with the Karoo Basin, specifically with the top of the Dwyka Tillite (302 {+-} 3 Ma and 299.2 {+-} 3.2 Ma) and the lowermost Ecca Group (288 {+-} 3 Ma and 289.6 {+-} 3.8 Ma). The evidence signifies widespread latest Carboniferous volcanic activity in western Gondwana.

  5. Application of U-Pb ID-TIMS dating to the end-Triassic global crisis: testing the limits on precision and accuracy in a multidisciplinary whodunnit (Invited) (United States)

    Schoene, B.; Schaltegger, U.; Guex, J.; Bartolini, A.


    The ca. 201.4 Ma Triassic-Jurassic boundary is characterized by one of the most devastating mass-extinctions in Earth history, subsequent biologic radiation, rapid carbon cycle disturbances and enormous flood basalt volcanism (Central Atlantic Magmatic Province - CAMP). Considerable uncertainty remains regarding the temporal and causal relationship between these events though this link is important for understanding global environmental change under extreme stresses. We present ID-TIMS U-Pb zircon geochronology on volcanic ash beds from two marine sections that span the Triassic-Jurassic boundary and from the CAMP in North America. To compare the timing of the extinction with the onset of the CAMP, we assess the precision and accuracy of ID-TIMS U-Pb zircon geochronology by exploring random and systematic uncertainties, reproducibility, open-system behavior, and pre-eruptive crystallization of zircon. We find that U-Pb ID-TIMS dates on single zircons can be internally and externally reproducible at 0.05% of the age, consistent with recent experiments coordinated through the EARTHTIME network. Increased precision combined with methods alleviating Pb-loss in zircon reveals that these ash beds contain zircon that crystallized between 10^5 and 10^6 years prior to eruption. Mineral dates older than eruption ages are prone to affect all geochronologic methods and therefore new tools exploring this form of “geologic uncertainty” will lead to better time constraints for ash bed deposition. In an effort to understand zircon dates within the framework of a magmatic system, we analyzed zircon trace elements by solution ICPMS for the same volume of zircon dated by ID-TIMS. In one example we argue that zircon trace element patterns as a function of time result from a mix of xeno-, ante-, and autocrystic zircons in the ash bed, and approximate eruption age with the youngest zircon date. In a contrasting example from a suite of Cretaceous andesites, zircon trace elements

  6. Contribution of U-Pb geochronology to characterizing the Cadomian magmatism of the southeastern French Massif Central and of the related uranium-ore at Bertholene

    International Nuclear Information System (INIS)

    Leveque, Marie-Helene


    U-Pb geochronology and whole-rock geochemistry (major, trace and rare earth elements) were applied to various ortho- and paragneiss formations of the southeastern part of the French Massif Central. The Mendic granite and the Les Palanges granite were dated at 603 ± 9 Ma and 540 ± 18 Ma, respectively. Their micaschist host-rocks show a multi-episodic evolution that matches the U-Pb data obtained on metasediments and leucogranites of the Variscan Orogen. An old zircon source was detected at 1.87 Ga in the Les Palanges micaschist, while, seemingly, this heritage was wiped out of the Mendic micaschist during the Cadomian events. In the Decazeville gneiss, where a crustal component of unknown age has been detected, the major event is the Variscan migmatization. At Bertholene, the geochronology of uranium ores associated to the Les Palanges orthogneiss evidenced two periods of emplacement: -the relicts of the first phase, of Liassic age at 173 ± 9 Ma, are restricted to an uranium oxide; -the second phase, related to coffinites, represents the economical ore emplaced from Oligocene until Recent times, generated through remobilization of the Liassic stock. A comparison between the geochronological data from the ore, and of those from its granite host, suggests a genetic relationship between the Cadomian magmatism and the U-concentrations, spatially linked to the unconformity between the Les Palanges basement and its Permo-Carboniferous cover series. Metamictization of the source minerals combined with tectonic processes would be responsible for the release of uranium. Uranium-rich minerals from Bertholene, from Lodeve and from Les Pierres-Plantees have been subjected to trial dating by the isotopic Xe-Xe method, which confirms the evolution admitted for those occurrences. This technique is demonstrably expeditious and faithful. Various phenomena were investigated, at the scale of the crystalline structure, related to the xenon energy states and to the problem of rare

  7. Subduction Initiation Existed Along the Ancient Continent Margins? Evidence of U-Pb ages of zircons from the Bonin Trench, Japan (United States)

    Li, Y. B.; Pearce, J. A.; Ryan, J. G.; Li, X. H.; Haraguchi, S.; Iizuka, T.; Kon, Y.; Yamamoto, S.; Sawaki, Y.; Ishii, T.; Maruyama, S.


    Although it is not cleanly known when and where the subduction initiation began on the Paleo-Izu-Bonin-Mariana (IBM) Trench, Jurassic and Cretaceous plutonic rocks, such as gabbroic, granitic and metamorphic rocks had been sampled from the Amami Plateau-Daito Ridge-Okidaito Ridge (ADO) in the Philippine Sea Plate. Furthermore, Mesozonic to Paleozonic ages zircons were obtained from volcaniclastic sandstones collected from northern Izu-Bonin forarc (Tani et al., 2012). We present U-Pb ages, Hf-O isotopes and trace element compositions of zircon grains separated from sediment, volcanic rock, dolerite and gabbro, collected from Chichijima Island and Bonin forearc seafloor (KH03-3, KT04-28 cruise of the University of Tokyo, IODP Leg 352). In the zircon age histogram, several age groups were identified. The age peaks are 0-3 Ma and 13 Ma (Hahajima Seamount: soft mud and volcanic tuff); 38 Ma (Oomachi Seamount: sandstone); 45 Ma (Chichijima Island: volcanic rock); 40 Ma, 48 Ma and 52 Ma (Hahajima Seamount: dolerite and gabbro); 45 Ma and 164-165 Ma (IODP Leg 352: volcanic rock), respectively. Zircon U-Pb ages ranging 0-52 Ma correspond well to the multi-stages of magmatism in the IBM. However, 164-165 Ma maybe represent the ages of zircon xenocryst including in forearc volcanic rock , which pre-existing in ancient continent crustal materials (SE China Continent Crust?) as the basement of Paleo-IBM. It seems reasonable to suppose that the subduction initiation of IBM existed along the ancient SE China Continent margins. The initiation of subduction zone is a consequence of lateral compositional buoyancy contrast within the lithosphere, that advocated by Niu et al. (2003, 2016).

  8. U-Pb ages of shocked zircon grains link distal K-Pg boundary sites in Spain and Italy with the Chicxulub impact (United States)

    Kamo, Sandra L.; Lana, Cristiano; Morgan, Joanna V.


    The U-Pb ages of shocked zircon crystals from the Chicxulub impact crater and Cretaceous-Paleogene (K-Pg) boundary sites in Haiti, the USA, and Canada, and the pattern of decreasing particle size with paleodistance from the crater, have been used as evidence of a genetic link between Chicxulub and the K-Pg boundary. Despite this, the inference that the K-Pg boundary layer formed as a direct consequence of the Chicxulub impact has been repeatedly questioned. Here we present U-Pb (ID-TIMS) ages and textural evidence of shock metamorphosed zircon grains from the K-Pg boundary at Caravaca, Spain, and Petriccio, Italy, that establish a causal connection between the impact and formation of the K-Pg boundary layer. The shocked zircon grains give data that produce a characteristic age pattern, which indicates a primary source age of 549.5 ± 5.7 Ma and a secondary event at the approximate time of impact at 66 Ma. The intensity of the shock features is proportional to the degree of isotopic resetting, and all textural features and ages are analytically identical to those of previously analyzed zircon from Chicxulub and K-Pg boundary sites in North America. Caravaca and Petriccio were > 8000 km from Chicxulub at the time of impact, and are therefore the farthest K-Pg sites identified that can be linked to Chicxulub through the dating of individual shocked zircon grains. We conclude that the combined age data and textural observations provide unambiguous evidence that ejecta from the Chicxulub impact formed the global K-Pg boundary layer. These data cannot be explained by the alternative scenario that the Chicxulub impact occurred ~ 300 ka prior to the K-Pg boundary.

  9. SHRIMP U-Pb zircon geochronology and thermal modeling of multilayer granitoid intrusions. Implications for the building and thermal evolution of the Central System batholith, Iberian Massif, Spain (United States)

    Díaz Alvarado, Juan; Fernández, Carlos; Castro, Antonio; Moreno-Ventas, Ignacio


    This work shows the results of a U-Pb SHRIMP zircon geochronological study of the central part of the Gredos massif (Spanish Central System batholith). The studied batholith is composed of several granodiorite and monzogranite tabular bodies, around 1 km thick each, intruded into partially molten pelitic metasediments. Granodiorites and monzogranites, belonging to three distinct intrusive bodies, and samples of anatectic leucogranites have been selected for SHRIMP U-Pb zircon geochronology. Distinct age groups, separated by up to 20 Ma, have been distinguished in each sample. Important age differences have also been determined among the most representative age groups of the three analyzed granitoid bodies: 312.6 ± 2.8 Ma for the Circo de Gredos Bt-granodiorites (floor intrusive layer), 306.9 ± 1.5 Ma for the Barbellido-Plataforma granitoids (top intrusive layer) and 303.5 ± 2.8 Ma for Las Pozas Crd-monzogranites (middle intrusive layer). These age differences are interpreted in terms of sequential emplacement of the three intrusive bodies, contemporary with the Late Paleozoic D3 deformation phase. The anatectic leucogranites are coeval to slightly younger than the adjacent intrusive granodiorites and monzogranites (305.4 ± 1.6 Ma for Refugio del Rey leucogranites and 303 ± 2 Ma for migmatitic hornfelses). It is suggested that these anatectic magmas were generated in response to the thermal effects of granodiorite intrusions. Thermal modeling with COMSOL Multiphysics® reveals that sequential emplacement was able to keep the thermal conditions of the batholith around the temperature of zircon crystallization in granitic melts (around 750 °C) for several million of years, favoring the partial melting of host rocks and the existence of large magma chambers composed of crystal mush prone to be rejuvenated after new intrusions.

  10. New models for Paleoproterozoic orogenesis in the Cheyenne belt region: Evidence from the geology and U-Pb geochronology of the Big Creek Gneiss, southeastern Wyoming (United States)

    Jones, D.S.; Snoke, A.W.; Premo, W.R.; Chamberlain, K.R.


    The disputed age of the deep crust of the Colorado Province is central to hypotheses for Paleoproterozoic crustal growth in the region. We studied the high-grade Big Creek Gneiss, southeastern Wyoming, as a potential exposure of pre-1780 Ma basement rocks. New geologic mapping and U-Pb geochronological data indicate that the Big Creek Gneiss exposes a deeper, but coeval, level of the Green Mountain arc relative to the predominantly supracrustal section to the west. The Big Creek Gneiss is composed of: supracrustal rocks; a ca. 1780 Ma Green Mountain arc-correlative, bimodal intrusive suite; a ca. 1763 Ma extensional(?) bimodal intrusive suite; and widespread ca. 1630 Ma pegmatitic leucogranite. The mafic member of the younger bimodal suite is documented here for the first time. U-Pb zircon ages from migmatite leucosomes indicate penetrative deformation of the Big Creek Gneiss at ca. 1750 Ma. We find that the postarc intrusive suite is mantle-involved, implying a second period of crustal growth. Shortening postdates arc magmatism by ~20 m.y., implying that termination of arc magmatism and accretion were separate events. Finally, criteria previously used to constrain the polarity of subduction for the Green Mountain arc are not reliable. We propose two competing models: (1) southward-dipping Green Mountain arc subduction (present coordinates), with slab breakoff-related magmatism following arc accretion; or (2) northward-dipping subduction, with extensional postarc magmatism. In both models, high-temperature deformation coincides with accretion along the Cheyenne belt, and extensional magmatism is an important component of crustal growth. We prefer the northward-dipping subduction model because it can be better integrated with regional tectonic events and published isotopic compositions of the igneous rocks. ?? 2010 Geological Society of America.

  11. Fingerprinting the K/T impact site and determining the time of impact by U-Pb dating of single shocked zircons from distal ejecta (United States)

    Krogh, T. E.; Kamo, S. L.; Bohor, B. F.


    U-Pb isotopic dating of single 1 - 3 micrograms zircons from K/T distal ejecta from a site in the Raton Basin, Colorado provides a powerful new tool with which to determine both the time of the impact event and the age of the basement at the impact site. Data for the least shocked zircons are slightly displaced from the 544 +/- 5 Ma primary age for a component of the target site, while those for highly shocked and granular grains are strongly displaced towards the time of impact at 65.5 +/- 3.0 Ma. Such shocked and granular zircons have never been reported from any source, including explosive volcanic rocks. Zircon is refractory and has one of the highest thermal blocking temperatures; hence, it can record both shock features and primary and secondary ages without modification by post-crystallization processes. Unlike shocked quartz, which can come from almost anywhere on the Earth's crust, shocked zircons can be shown to come from a specific site because basement ages vary on the scale of meters to kilometers. With U-Pb zircon dating, it is now possible to correlate ejecta layers derived from the same target site, test the single versus multiple impact hypothesis, and identify the target source of impact ejecta. The ages obtained in this study indicate that the Manson impact site, Iowa, which has basement rocks that are mid-Proterozoic in age, cannot be the source of K/T distal ejecta. The K/T distal ejecta probably originated from a single impact site because most grains have the same primary age.

  12. Phanerozoic polyphase orogenies recorded in the northeastern Okcheon Belt, Korea from SHRIMP U-Pb detrital zircon and K-Ar illite geochronologies (United States)

    Jang, Yirang; Kwon, Sanghoon; Song, Yungoo; Kim, Sung Won; Kwon, Yi Kyun; Yi, Keewook


    We present the SHRIMP U-Pb detrital zircon and K-Ar illite 1Md/1M and 2M1 ages, suggesting new insight into the Phanerozoic polyphase orogenies preserved in the northeastern Okcheon Belt, Korea since the initial basin formation during Neoproterozoic rifting through several successive contractional orogens. The U-Pb detrital zircon ages from the Early Paleozoic strata of the Taebaeksan Zone suggest a Cambrian maximum deposition age, and are supported by trilobite and conodont biostratigraphy. Although the age spectra from two sedimentary groups, the Yeongwol and Taebaek Groups, show similar continuous distributions from the Late Paleoproterozoic to Early Paleozoic ages, a Grenville-age hiatus (1.3-0.9 Ga) in the continuous stratigraphic sequence from the Taebaek Group suggests the existence of different peripheral clastic sources along rifted continental margin(s). In addition, we present the K-Ar illite 1Md/1M ages of the fault gouges, which confirm fault formation/reactivation during the Late Cretaceous to Early Paleogene (ca. 82-62 Ma) and the Early Miocene (ca. 20-18 Ma). The 2M1 illite ages, at least those younger than the host rock ages, provide episodes of deformation, metamorphism and hydrothermal effects related to the tectonic events during the Devonian (ca.410 Ma) and Permo-Triassic (ca. 285-240 Ma). These results indicate that the northeastern Okcheon Belt experienced polyphase orogenic events, namely the Okcheon (Middle Paleozoic), Songrim (Late Paleozoic to Early Mesozoic), Daebo (Middle Mesozoic) and Bulguksa (Late Mesozoic to Early Cenozoic) Orogenies, reflecting the Phanerozoic tectonic evolution of the Korean Peninsula along the East Asian continental margin.

  13. Determinations of rare earth element abundance and U-Pb age of zircons using multispot laser ablation-inductively coupled plasma mass spectrometry. (United States)

    Yokoyama, Takaomi D; Suzuki, Toshihiro; Kon, Yoshiaki; Hirata, Takafumi


    We have developed a new calibration technique for multielement determination and U-Pb dating of zircon samples using laser ablation-inductively coupled plasma mass spectrometry (ICPMS) coupled with galvanometric optics. With the galvanometric optics, laser ablation of two or more sample materials could be achieved in very short time intervals (~10 ms). The resulting sample aerosols released from different ablation pits or different solid samples were mixed and homogenized within the sample cell and then transported into the ICP ion source. Multiple spot laser ablation enables spiking of analytes or internal standard elements directly into the solid samples, and therefore the standard addition calibration method can be applied for the determination of trace elements in solid samples. In this study, we have measured the rare earth element (REE) abundances of two zircon samples (Nancy 91500 and Prešovice) based on the standard addition technique, using a direct spiking of analytes through a multispot laser ablation of the glass standard material (NIST SRM612). The resulting REE abundance data show good agreement with previously reported values within analytical uncertainties achieved in this study (10% for most elements). Our experiments demonstrated that nonspectroscopic interferences on 14 REEs could be significantly reduced by the standard addition technique employed here. Another advantage of galvanometric devices is the accumulation of sample aerosol released from multiple spots. In this study we have measured the U-Pb age of a zircon sample (LMR) using an accumulation of sample aerosols released from 10 separate ablation pits of low diameters (~8 μm). The resulting (238)U-(206)Pb age data for the LMR zircons was 369 ± 64 Ma, which is in good agreement with previously reported age data (367.6 ± 1.5 Ma). (1) The data obtained here clearly demonstrate that the multiple spot laser ablation-ICPMS technique can become a powerful approach for elemental and isotopic

  14. Early Paleozoic U-Pb age of zircons from meta-granophyres f the Grand-Saint-Bernard nappe (zona interna, Aosta Valley, Italy); Age paleozoique inferieur (U-Pb sur zircon) de metagranophyres de la nappe du Grand-Saint-Bernard (zona interna, Vallee d'Aoste, Italie)

    Energy Technology Data Exchange (ETDEWEB)

    Bertrand, J.M. [Laboratoire de Geodynamique des Chaines Alpines, LGCA, Campus Scientifique, 73 - Le Bourget-du-Lac (France)


    The U-Pb age of a meta-granophyre from the Val de Rhemes (Brianconnais basement of the Aosta valley) of 511{+-}9 Ma suggests that the micaschists which dominate the pre-alpine basement of the Grand-Saint-Bernard Nappe are, in part, of Early Paleozoic age. The Brianconnais domain is characterized by a Cambrian to Ordovician alkalineto sub-alkaline (monzonitic) magmatism, similar in age to orthogneisses known in other parts of the Variscan belt and generally interpreted as related to an extensional event. (authors)

  15. In situ measurement system (United States)

    Lord, D.E.


    A multipurpose in situ underground measurement system comprising a plurality of long electrical resistance elements in the form of rigid reinforcing bars, each having an open loop hairpin configuration of shorter length than the other resistance elements. The resistance elements are arranged in pairs in a unitized structure, and grouted in place in the underground volume. Measurement means are provided for obtaining for each pair the electrical resistance of each element and the difference in electrical resistance of the paired elements, which difference values may be used in analytical methods involving resistance as a function of temperature. A scanner means sequentially connects the resistance-measuring apparatus to each individual pair of elements. A source of heating current is also selectively connectable for heating the elements to an initial predetermined temperature prior to electrical resistance measurements when used as an anemometer.

  16. In situ zymography. (United States)

    George, Sarah J; Johnson, Jason L


    In situ zymography is a unique laboratory technique that enables the localisation of matrix-degrading metalloproteinase (MMP) activity in histological sections. Frozen sections are placed on glass slides coated with fluorescently labelled matrix proteins. After incubation MMP activity can be observed as black holes in the fluorescent background due to proteolysis of the matrix protein. Alternatively frozen sections can be incubated with matrix proteins conjugated to quenched fluorescein. Proteolysis of the substrate by MMPs leads to the release of fluorescence. This technique can be combined with immunohistochemistry to enable co-location of proteins such as cell type markers or other proteins of interest. Additionally, this technique can be adapted for use with cell cultures, permitting precise location of MMP activity within cells, time-lapse analysis of MMP activity and analysis of MMP activity in migrating cells.

  17. In-Situ (United States)

    Sasayama, Kohki; Hayashi, Tetsushi; Kohno, Hideo


    Flattening of a carbon nanotube with a switching of the flattening direction results in the formation of a nanotetrahedron/nanoribbon structure. In this study, behavior of individual carbon nanotetra-hedron/nanoribbon structures under a tensile load is observed by means of in-situ scanning electron microscopy using micro-manipulators. Positions of breakage caused by a tensile load are not necessarily at a nanotetrahedron/nanoribbon junction. The results indicate that the nanotetrahedron/nanoribbon junctions are not mechanical weak points under a tensile load, and the nanotetra-hedron/nanoribbon structures are as strong as simple multi-walled carbon nanotubes. In addition, the nanostructures maintain their shape and do not transformed to a tubular form.

  18. The role of trace element partitioning between garnet, zircon and orthopyroxene on the interpretation of zircon U-Pb ages: an example from high-grade basement in Calabria (Southern Italy) (United States)

    Fornelli, A.; Langone, A.; Micheletti, F.; Pascazio, A.; Piccarreta, G.


    The recognition of the coeval growth of zircon, orthopyroxene and garnet domains formed during the same metamorphic cycle has been attempted with detailed microanalyses coupled with textural analyses. A coronitic garnet-bearing granulite from the lower crust of Calabria has been considered. U-Pb zircon data and zircon, garnet and orthopyroxene chemistries, at different textural sites, on a thin section of the considered granulite have been used to test possible equilibrium and better constrain the geological significance of the U-Pb ages related to zircon separates from other rocks of the same structural level. The garnet is very rich in REE and is characterised by a decrease in HREE from core to outer core and an increase in the margin. Zircons show core-overgrowth structures showing different chemistries, likely reflecting episodic metamorphic new growth. Zircon grains in matrix, corona around garnet and within the inner rim of garnet, are decidedly poorer in HREE up to Ho than garnet interior. Orthopyroxene in matrix and corona is homogeneously poor in REE. Thus, the outer core of garnet and the analysed zircon grains grew or equilibrated in a REE depleted system due to the former growth of garnet core. Zircon ages ranging from 357 to 333 Ma have been determined in the matrix, whereas ages 327-320 Ma and around 300 Ma have been determined, respectively, on cores and overgrowths of zircons from matrix, corona and inner rim of garnet. The calculated DREEzrn/grt and DREEopx/grt are largely different from the equilibrium values of literature due to strong depletion up to Ho in zircon and orthopyroxene with respect to garnet. On the other hand, the literature data show large variability. In the case study, (1) the D zrn/grt values define positive and linear trends from Gd to Lu as many examples from literature do and the values from Er to Lu approach the experimental results at about 900 °C in the combination zircon dated from 339 to 305 Ma with garnet outer core

  19. New Zircon Shock Phenomenon for Dating and Reconstruction of Large Impact Basins Revealed by Electron Nanobeam (EBSD, CL, EDS), U-Pb, and (U-Th)/He Isotopic Analysis of the Vredefort Dome (United States)

    Moser, D. E.; Cupelli, C. L.; Barker, I. R.; Flowers, R. M.; Bowman, J. R.; Wooden, J.; Hart, R.


    We present new microstructural (EBSD, CL), U-Pb, and (U-Th)/He isotopic data on zircon microcrystals from bedrock across ~65 km radial distance of the deeply eroded collar and central uplift of the 2.020-Ga Vredefort impact basin of South Africa.

  20. Nové U-Pb datování zirkonů z bohutínského pně v příbramské rudní oblasti

    Czech Academy of Sciences Publication Activity Database

    Žák, Karel; Svojtka, Martin; Breiter, Karel; Ďurišová, Jana; Veselovský, F.; Pašava, J.


    Roč. 2014, č. 1 (2015), s. 43-49 ISSN 0514-8057 R&D Projects: GA ČR GA13-15390S Institutional support: RVO:67985831 Keywords : Bohemian Massif * Central Bohemian Pluton * Bohutím Stock * zircon U-Pb dating Subject RIV: DB - Geology ; Mineralogy

  1. Provenance variability along the Early Ordovician north Gondwana margin: Paleogeographic and tectonic implications of U-Pb detrital zircon ages from the Armorican Quartzite of the Iberian Variscan belt

    NARCIS (Netherlands)

    Shaw, J.; Gutiérrez-Alonso, G.; Johnston, S.T.; Pastor-Galán, D.


    Detrital zircon laser ablation–inductively coupled plasma–mass spectrometry U-Pb age data from the Lower Ordovician Armorican Quartzite (deformed passive margin strata of Gondwanan affinity) of the Iberian Massif are presented herein. The S-shaped coupled Iberian oroclines defined within these zones

  2. Provenance and depositional age of metavolcano-sedimentary sequences of the Santa Terezinha de Goias, based on Sm-Nd and U-Pb zircon single grain; Proveniencia e idade deposicional de sequencias metavulcano-sedimentares da regiao de Santa Terezinha de Goias, baseada em dados isotopicos Sm-Nd e U-Pb em monocristal de zircao

    Energy Technology Data Exchange (ETDEWEB)

    Dantas, Ellton Luiz; Jost, Hardy; Fuck, Reinhardt A.; Brod, Jose Afonso; Pimentel, Marcio Martins; Meneses, Paulo Roberto [Brasilia Univ., DF (Brazil). Inst. de Geociencias]. E-mail:


    Supracrustal rocks of the Santa Terezinha de Goias region, Central Brazil, presumably represent a southern extension of the Mara Rosa magmatic arc tectonically juxtaposed to Archean terrains and consist of a meta volcanic unit and a meta sedimentary unit. The aim of the paper is to present and discuss the first U-Pb and Sm-Nd data of rocks belonging to both units of that region. U-Pb data of zircons from a felsic meta volcanic rock inter layered with chlorite-rich schists (metandesites?) yield a concordant age of of 660 My, while the Sm-Nd model age of a variety of chlorite-schists indicate a juvenile age between 1.1 and 1.3 Ga. These data indicate that the meta volcanic rocks are Neo proterozoic in age and may be correlated with rocks of the Mara Rosa magmatic arc. On the other hand, the prevailing provenance of rocks belonging to the meta sedimentary unit indicate a Paleoproterozoic, or older, source. Thus, the deposition of both units are explained by means of the erosion of source-areas of variable age. (author)

  3. Implications of Late Cretaceous U-Pb zircon ages of granitic intrusions cutting ophiolitic and volcanogenic rocks for the assembly of the Tauride allochthon in SE Anatolia (Helete area, Kahramanmaraş Region, SE Turkey) (United States)

    Nurlu, Nusret; Parlak, Osman; Robertson, Alastair; von Quadt, Albrecht


    An assemblage of NE-SW-trending, imbricate thrust slices (c. 26 km E-W long × 6.3 km N-S) of granitic rocks, basic-felsic volcanogenic rocks (Helete volcanics), ophiolitic rocks (Meydan ophiolite) and melange (Meydan melange) is exposed near the Tauride thrust front in SE Anatolia. The volcanogenic rocks were previously assumed to be Eocene because of associated Nummulitic limestones. However, ion probe U-Pb dating of zircons extracted from the intrusive granitic rocks yielded ages of 92.9 ± 2.2-83.1 ± 1.5 Ma (Cenomanian-Campanian). The Helete volcanic unit and the overlying Meydan ophiolitic rocks both are intruded by granitic rocks of similar age and composition. Structurally underlying ophiolite-related melange includes similar-aged, but fragmented granitic intrusions. Major, trace element and rare earth element analyses coupled with electron microprobe analysis of the granitic rocks show that they are metaluminus to peraluminus and calc-alkaline in composition. A magmatic arc setting is inferred from a combination of tectonomagmatic discrimination, ocean ridge granite-normalized multi-element patterns and biotite geochemistry. Sr-Nd-Pb isotope data further suggest that the granitoid rocks were derived from variably mixed mantle and crustal sources. Granitic rocks cutting the intrusive rocks are inferred to have crystallized at ~5-16 km depth. The volcanogenic rocks and granitic rocks originated in a supra-subduction zone setting that was widely developed throughout SE Anatolia. Initial tectonic assembly took place during the Late Cretaceous probably related to northward subduction and accretion beneath the Tauride continent (Keban and Malatya platforms). Initial tectonic assembly was followed by exhumation and then transgression by shelf-depth Nummulitic limestones during Mid-Eocene, as documented in several key outcrops. Final emplacement onto the Arabian continental margin took place during the Early Miocene.

  4. High-spatial resolution SIMS U-Pb zircon dating on Malay tin granites: New insights to crustal evolution of the Malaysian Peninsula (United States)

    Ng, S.; Searle, M. P.; Whitehouse, M. J.; Chung, S.; Robb, L. J.; Ghani, A. A.; Sone, M.


    The Southeast Asian tin granite province has previously been recognized as comprising three distinct granitic belt (Cobbing et al., 1986): (1) Middle Permian - Late Triassic Eastern Province with mainly subduction-related I-type granites associated with Cu-Au deposits, (2) Late Permian - Early Jurassic Main Range Province with mainly S-type granites associated with Sn-W deposits, and (3) Late Triassic - Cretaceous Western Province with mixed I- and S-type granites associated with Sn-W deposits. These ages were obtained mainly using whole rock Rb-Sr and K-Ar geochronology in the 70s and 80s, methods that are no longer considered suitable for obtaining crystallization ages of granites due to unstable behaviour of these isotopes in hydrothermal systems. During 2011 we collected over 50 samples of granites across all three zones in Northern Malaysia for U-Pb dating using high-spatial resolution precision SIMS at the Swedish Museum of Natural History. The results reveal a westward younging trend across the Malay Peninsula. The Eastern Province hornblende- and biotite-granites in Eastern Malaysia formed by subduction-related processes have ages lying between 220-285 Ma. The Main Range Province dominantly S-type granites in west and central Malaysia have ages lying between 206-226 Ma. These include dominantly biotite granites with less common tourmaline+biotite leucocratic granites related to crustal thickening processes following collision of Sibumasu with Indochina and closing of the Palaeo-Tethyan Bentong-Raub suture zone. Some enigmatic young Cretaceous zircon rim ages (c. 81-80 Ma) may indicate a young hydrothermal - metasomatic origin for some tin mineralization from both the Eastern Province (Tioman Island) and the Western province (Phuket, Thailand) (Searle et al., 2012). Granites in Malaysia cannot be simply categorized as I-, S- or A-type as most of them failed to show distinctive minerals for classification and there is considerable overlap in geochemical

  5. Magmatic Activity and Crustal Melting During Orogenesis: Laser-ablation U-Pb Geochronology of Dike and Leucosome Generations in Granulites of the Gruf Complex, Central Alps (United States)

    Savage, J. A.; Oalmann, J.; Bousquet, R.; Moeller, A.


    Magmatic leucosomes and dikes in metamorphic terranes provide an opportunity to correlate accessory phase crystallization ages with the timing of deformation and metamorphic events, as well as larger scale magmatic intrusions. The Gruf Complex consists of upper amphibolite to lower granulite facies migmatitic gneisses and scarce, UHT sapphirine granulites and is bordered by the c. 31 Ma tonalite-granodiorite Bergell Intrusion and the c. 24 Ma Novate S-type leucogranite. Several mineralogically distinct types of leucosomes and dikes have been identified: 1) biotite-bearing leucosomes, which define the main foliation and are commonly folded; 2) hornblende- and biotite-bearing dikes, which are either boudinaged or crosscut the main foliation; 3) pegmatitic muscovite-, garnet-, beryll-bearing dikes, which commonly crosscut all other rock types. These field observations indicate a change in melt composition during and after the regional metamorphic event and its associated deformation. To correlate these melt types with the timing of metamorphism of the Gruf Complex, and the Bergell and Novate intrusions, U-Pb zircon ages were obtained from several dike and leucosome samples. Grains were separated, mounted in epoxy, and imaged by cathodoluminescence prior to U-Pb isotope analysis by LA-ICP-MS. The outermost zircon growth zones were targeted in order to determine the crystallization age of the host magma. All of the analyzed samples contain oscillatory-zoned domains with ages between 250 Ma and 300 Ma. A leucosome sample from within a brecciated metaperidotite enclave in the granulites contains equant, sector-zoned "soccer ball" zircon grains with an age of 32.4±1.0 Ma. Most dike samples contain unzoned or sector-zoned rims or mantles that range from 30-33 Ma. Most of the pegmatitic samples, regardless of their degree of deformation, contain zircon crystals with weakly zoned rims ranging from 24-27 Ma. However, some undeformed pegmatitic samples lack zircon domains

  6. Comparing Carbon and Strontium Isotope Chemostratigraphy against U-Pb Detrital Zircon Analysis in Dating Marbles of the Uppermost Allochthon in North Norway (United States)

    Verellen, Devon; Yaw Agyei-Dwarko, Nana; Steltenpohl, Mark; Andresen, Arild


    The basal parts of the Uppermost Allochthon between latitudes N67oN (Fauske) and N68.45oN (Ofoten) comprise a thick sequence of platformal marbles that overlie a fragmented ophiolite complex. This basement-cover package can be traced discontinuously from Ofoten more than 150 kilometers northward to connect with the Lyngen ophiolite, the largest ophiolite complex in Scandinavia. U-Pb zircon geochronology documents an Early Ordovician age (469 ±5 Ma) for magmatic crystallization of the Lyngen ophiolite and for the Ofoten mafic complex (474 ±0.7 Ma). A regional unconformity separates the Lyngen ophiolite from overlying rocks of the Balsfjord Group. Halysitid corals from the Balsfjord Group constrain an Upper Llandoverian age for the unconformity. In Ofoten, metasedimentary rocks of the Evenes Group nonconformably overlie the mafic complex and are lithologically correlated to parts of the Balsfjord Group. The basal unit of the Evenes Group, the Elvenes Conglomerate, contains clasts of plutonic igneous rocks clearly derived from the underlying mafic complex (Lillevik dike complex). Suites of multiple phases of felsic intrusions occur within overlying (Bogen/Niingen nappes) and underlying (Narvik nappe) allochthons but are absent in the Evenes Group. Carbon and strontium isotopes reported on these amphibolite-facies marbles have been interpreted to place chemostratigraphic ages that range from Neoproterozoic to Silurian, requiring the placement of hypothetical thrusts and normal faults to explain their vertical stacking although no faults are yet recognized based on field and structural studies. We present LA-ICPMS U-Pb isotope data on detrital zircons from a siliciclastic layer within one of the carbonate units of the Evenes Group that had previously been assigned a Neoproterozoic chemostratigraphic apparent age. Twenty-seven percent of the ages are younger than 600 Ma and define a prominent 470 Ma age population with the 5 youngest ones giving a concordia age of 460

  7. Modeling in situ vitrification

    International Nuclear Information System (INIS)

    Mecham, D.C.; MacKinnon, R.J.; Murray, P.E.; Johnson, R.W.


    In Situ Vitrification (ISV) process is being assessed by the Idaho National Engineering Laboratory (INEL) to determine its applicability to transuranic and mixed wastes buried at INEL'S Subsurface Disposal Area (SDA). This process uses electrical resistance heating to melt waste and contaminated soil in place to produce a durable glasslike material that encapsulates and immobilizes buried wastes. This paper outlines the requirements for the model being developed at the INEL which will provide analytical support for the ISV technology assessment program. The model includes representations of the electric potential field, thermal transport with melting, gas and particulate release, vapor migration, off-gas combustion and process chemistry. The modeling objectives are to help determine the safety of the process by assessing the air and surrounding soil radionuclides and chemical pollution hazards, the nuclear criticality hazard, and the explosion and fire hazards, help determine the suitability of the ISV process for stabilizing the buried wastes involved, and help design laboratory and field tests and interpret results. 3 refs., 2 figs., 1 tab

  8. A Precise U-Pb Zircon age for the Skaergaard Intrusion: Magmatic Cooling History Refinement and Palaeogene Igneous Correlations, East Greenland (United States)

    Hamilton, M. A.; Brooks, C. K.


    A cooling curve for the Skaergaard intrusion was first established by Norton & Taylor [1] using oxygen isotopes and transport theory. Subsequently, Hirschmann et al. [2] located a cooling curve in absolute time using 40Ar/39Ar ages on biotite and hornblende. Here, we present new, high-precision U-Pb results for zircon recovered from the Sandwich Horizon on Basistoppen. Our (concordant) age of 55.59±0.13 Ma (2σ ) is fully consistent with these earlier results, thereby confirming the validity of both the cooling model, temperatures deduced from mineral equilibria, and the standardization used in the Ar-Ar system. It is, however, at variance with a recent WR-apatite Lu-Hf age for the intrusion [3]. Furthermore, knowledge of the thickness of lava overburden at the time of intrusion also constrains the pressure in the cooling intrusion, and this is in turn consistent with existing estimates of 60±15 MPa. Andreasen et al. [4] recently demonstrated that lavas with compositions corresponding closely to deduced Skaergaard magmas are found relatively high up in the adjacent lava plateau. The new zircon age thereby allows us to precisely date this level; a result in general agreement with the 40Ar/39Ar stratigraphy of Storey et al. [5]. Moreover, the Skaergaard age reported here represents the first precise and accurate zircon age for Tertiary (Palaeogene) magmatism in Greenland, and serves as a useful reference point for assessing Ar-Ar ages determined on numerous lavas, sills, dykes and gabbros elsewhere in the North Atlantic Igneous Province. The 55.59 Ma U-Pb age reaffirms earlier conclusions that the Skaergaard intrusion was emplaced contemporaneously with continental flood basalts erupted during late Paleocene-early Eocene time, in the middle stages of Palaeogene NAIP magmatism. The timing was synchronous with incipient rifting of Greenland and northern Europe as reflected in the formation of new ocean crust (Chron 24r), but distinctly postdates basic central

  9. U-Pb ages of zircons from sites in Spain and Italy provide more evidence linking the Chicxulub impact to the global K-P boundary layer (United States)

    Morgan, J. V.; Kamo, S.; Lana, C.


    The K-P boundary layer possesses an extra-terrestrial signature and contains highly shocked terrestrial minerals. The only plausible explanation for the K-P layer is that it was formed when a large meteorite hit the Earth, causing the ejection of both meteoritic material and shocked fragments of target rock around the globe. There is now universal agreement that the Chicxulub structure is an impact crater, and dating of the impact melt rocks within the crater place it close in age to the K-P boundary. Two significant lines of evidence indicate a genetic link between Chicxulub and the global K-P layer: 1) the size of the ejected particles in the layer decreases with palaeodistance from Chicxulub, and 2) U-Pb dating of shocked zircons from the Chicxulub impact site and in several K-P sites in North America are near-identical in age, texture and lead-loss pattern. However, even with such apparently incontrovertible evidence linking Chicxulub and the K-P boundary, a minority continue to question the link and suggest that the Chicxulub impact occurred ~300 ka before the K-P boundary. Here we present the results of U-Pb isotope dilution thermal ionization mass spectrometry (ID-TIMS) for shock-metamorphosed zircon crystals from the K-P boundary layer at Caravaca, Spain, and Petriccio, Italy. We find that the determined ages form a mixing line between a primary source age of ~549 Ma and the approximate time of impact. This is analytically identical to ages obtained previously for similarly shocked zircon grains at Chicxulub and from K-P boundary sites in North America. Caravaca and Petriccio are the most distal K-P sites that can be directly linked to Chicxulub through the dating of individual shocked zircon grains. These results, along with the completeness of the K-P transition at several sites around the globe, including Caravaca, cannot be explained by the alternative scenario that the Chicxulub impact occurred ~300 ka prior to the K-P boundary.

  10. Metamorphic P-T path and zircon U-Pb dating of HP mafic granulites in the Yushugou granulite-peridotite complex, Chinese South Tianshan, NW China (United States)

    Zhang, Lu; Zhang, Lifei; Xia, Bin; Lü, Zeng


    Co-existing granulite and peridotite may represent relics of the paleo-suture zone and provides an optimal opportunity for better understanding of orogeny between two blocks. In this study, we carried out petrological and U-Pb zircon dating investigation on the HP mafic granulites associated with peridotite complex at Yushugou in Chinese South Tianshan. The studied samples include garnet-bearing high-pressure mafic granulites which can be subdivided into two types: Type I orthopyroxene-free and Type II orthopyroxene-bearing granulites and amphibolite. Type I granulite (Y21-2) has a mineral assemblage of garnet (33 vol.%), clinopyroxene (32 vol.%) and plagioclase (30 vol.%); and Type II granulite (Y18-8) has a mineral assemblage of garnet (22 vol.%), clinopyroxene (10 vol.%), orthopyroxene (14 vol.%), plagioclase (45 vol.%) and quartz. Garnet in both granulites exhibits core-rim structure characterized by increasing grossular and decreasing pyrope from core to rim. Petrographic observations and phase equilibrium modeling using THERMOCALC in the NCFMASHTO system for the mafic granulites (Y21-2 and Y18-8) show three stages of metamorphism: Stage I (granulite facies) was recognized by the large porphyroblastic garnet core, with P-T conditions of 9.8-10.4 Kbar and 860-900 °C (Y21-2) and 9.9-10.6 Kbar and 875-890 °C (Y18-8), respectively; Stage II (HP granulite facies) has peak P-T conditions of 12.1 Kbar at 755 °C (Y21-2) and 13.8 Kbar at 815 °C (Y18-8) using mineral assemblages combining with garnet rim compositions with maximum grossular and minimum pyrope contents; Stage III (amphibolite facies) was characterized by the development of calcic amphibole in granulites with temperature of 446-563 °C. Therefore, an anticlockwise P-T path characterized by simultaneous temperature-decreasing and pressure-increasing was inferred for the Yushugou HP mafic granulite. Studies of zircon morphology and inclusions, combined with zircon U-Pb dating and REE geochemistry

  11. Isotope U-Pb age on single zircon and REE distribution in rocks and zircon from paleoproterozoic Kandalaksha-Kolvitsa complex Baltic shield (United States)

    Steshenko, Ekaterina; Bayanova, Tamara; Drogobuzhskaya, Svetlana; Lyalina, Ludmila; Serov, Pavel; Chashchin, Viktor; Elizarov, Dmitriy


    Kandalaksha-Kolvitsa paleoproterozoic complex located in the N-E part of Baltic shield and consists of three zones. Marginal zone (mesocratic metanorite) lies at the base of the massif. Main zone is composed of leucocratic metagabbro. The upper zone is alteration of mataanorthosite and leucocratic metagabbro. All rocks were subjected to granulate and anorthositic metamorphism. Age of magmatic crystallization of the massif was determined for the first time, using the U-Pb isotope method for single zircon grains. Three fractions of single zircons from anorthosite of the Kandalaksha massif gave precise U-Pb age of 2435.5 ± 4.8 Ma. For the first time REE concentration (WR) was determined using a quadrupole mass spectrometer (Agilent 7500 ce ICP-MS) in the main varieties of rocks of the Kandalaksha-Kolvitsa paleoproterozoic complex. Anorthosite and leucocratic metagabbros (main zone) are characterized by a flat spectrum distribution of HREE, which were normalized by [1]. The REE pattern is characterized by significant positive anomalies of Eu ((Eu / Eu *)n = 3.72-3.91) in anorthosite and leucogabbros and 7.26 - in ortoamfibolitah. General content of individual elements that are common for this type of rocks: Cen = 5.82-8.54, Ybn = 1.54-1.58, which indicates that the process of crystallization of the rock occurred with predominant accumulation of plagioclase. According to geochemical and Nd-Sr isotopic data (ISr=0.702 - 0.706, ɛNd(T) = +1 - (-3)) Kandalaksha Kolvitsa complex, appear to have a general plume source with Paleoproterozoic layered intrusions of the Baltic Shield [2] Distribution of REE (ELAN-9000 ICP-MS) in zircon have a typical magmatic species: a positive Ce, negative Eu anomaly and HREE flat spectrum. Titanium content in zircons were measured for the calculation of their crystallization temperature with 8350C. These data are evidence of magmatic origin of zircon [3]. The scientific researches are supported by RFBR (projects № 15-35-20501, № 16

  12. Tectonic Evolution of the Izmir Ankara Suture Zone in Northwest Turkey Using Zircon U-Pb Geochronology and Zircon Lu-Hf Isotopic Tracers (United States)

    Campbell, C.; Taylor, M. H.; Licht, A.; Mueller, M.; Ocakglu, F.; Moeller, A.; Metais, G.; Beard, K. C.


    Detrital zircons from a Cretaceous forearc basin and Tertiary foreland basin located along the Sakarya Zone of the Western Pontides were analyzed to better understand the closure history of the Tethyan oceans. The Variscan Orogeny is characterized by abundant 350-300 Ma U-Pb ages and vertical ɛHf arrays, consistent with a mature magmatic arc that emplaced plutons through a southward growing accretionary margin. An ɛHf pull-up is observed from 300-250 Ma interpreted as rifting of the Intra-Pontide Ocean. The Cimmerian Orogeny is characterized by a 250-230 Ma ɛHf pull-down, followed by a 230-200 Ma magmatic gap consistent with underthrusting of the Karakaya Complex. From 200-120 Ma another magmatic lull is observed. The Alpine Orogeny is characterized by an ɛHf pull-down from 120-85 Ma within Cretaceous forearc sediments and a 100 Ma deviant ɛHf vertical array within Tertiary foreland basin sediments. Minor zircon U-Pb age peaks and contrasting inter-basinal ɛHf evolution are interpreted to represent onset of Andean-style subduction along the southern margin of the Sakarya Zone at 120 Ma followed by crustal thickening until 85 Ma. The deviant 100 Ma ɛHf vertical array within foreland basin detritus is interpreted as initiation of intra-oceanic subduction within the Izmir-Ankara Ocean. An 85-75 Ma ɛHf pull-up from forearc basin sediments is interpreted as slab roll-back along the southern margin of the Sakarya Zone, responsible for final rifting of the Western Black Sea. At 80 Ma, a vertical ɛHf array from Tertiary foreland basin deposits is interpreted to represent synchronous melting of the Tavsanli Zone and intra-oceanic slab break-off. A single 66 Myr pre-collisional grain defines a sharp ɛHf pull-down immediately prior to total arc shut-off, interpreted to represent incipient collision between the Sakarya and Tavsanli zones. A 52 Ma syn-collisional tuff yields minimally intermediate ɛHf values followed by a slight 48 Ma ɛHf pull-down, interpreted as a

  13. High-resolution U-Pb ages from the Upper Triassic Chinle Formation (New Mexico, USA) support a diachronous rise of dinosaurs (United States)

    Irmis, Randall B.; Mundil, Roland; Martz, Jeffrey W.; Parker, William G.


    Though the Late Triassic preserves major paleoenvironmental fluctuations and is key for understanding the evolution of Mesozoic and modern terrestrial ecosystems, comparisons of Late Triassic non-marine sedimentary and fossil records are difficult because global correlations lack precise radioisotopic ages, and have instead been based upon unconstrained biostratigraphic ranges of palynomorph and vertebrate fossils. The Chinle Formation in southwestern North America preserves a major Late Triassic record of paleoenvironmental and biotic change, including significant early dinosaur fossils. Previous high-resolution radioisotopic age constraints for the formation are limited to a single U-Pb zircon age from the upper third of the formation. The extraction of a geologically meaningful age is challenging from these redeposited units and preference is given to considering the youngest age of a deposit as a maximum age and closest approximation of the depositional age. Because calculating a weighted mean age (or median age) from a group of ages from such deposits is often not adequate, the precision of our two new CA-TIMS single crystal zircon U-Pb ages from the Chinle Formation of New Mexico is limited to ca 0.3% (or ± 0.7 Ma) of the youngest crystal age. Our 206Pb/ 238U age of ~ 218 Ma from the Blue Mesa Member in Six Mile Canyon, western New Mexico, demonstrates that strata, palynomorphs, and vertebrate fossils previously considered to be late Carnian in age are actually middle Norian in age. Our new age of ~ 212 Ma from the Hayden Quarry within the Petrified Forest Member at Ghost Ranch, northern New Mexico, provides the first maximum age for important vertebrate assemblages from this area that record the rise of dinosaurs, and demonstrates that basal dinosauromorphs ('dinosaur precursors') co-existed with dinosaurs for at least 18 Ma. These new radioisotopic data allow a new correlation of the Chinle Formation to the Late Triassic timescale, suggesting that most if

  14. Structural observations and U-Pb mineral ages from igneous rocks at the Archaean-Palaeoproterozoic boundary in the Salahmi Schist Belt, central Finland: constraints on tectonic evolution

    Directory of Open Access Journals (Sweden)

    Pietikäinen, K.


    Full Text Available The study area in Vieremä, central Finland, contains part of Archaean-Palaeoproterozoic boundary. In the east, the area comprises Archaean gneiss and the Salahmi Schist Belt. The rocks of the schist belt are turbiditic metagreywackes, with well-preserved depositional structures, occurring as Proterozoic wedge-shaped blocks, and staurolite schists, the latter representing higher-strained and metamorphosed equivalents of the metagreywackes. In the west of the area there is an Archaean gneiss block, containing strongly elongated structures, and deformed Svecofennian supracrustal rocks, which are cut by deformed granitoids. These are juxtaposed with the schist belt. The boundaries of these tectonometamorphic blocks are narrow, highly strained mylonites and thrust zones. The metamorphic grade of the supracrustal rocks increases from east to west, the increase being stepwise across the mylonitic block boundaries. The rocks are more deformed from east to west with younger structures overprinting. In the staurolite schists of the Salahmi Schist Belt, the most prominent structure is a lineation (L2 that overprints the bedding and axial plane foliation. In Sorronmäki quarry, at the western boundary of the schist belt, this Palaeoproterozoic lineation dominates all the structures in tonalite gneiss, which gives a U-Pb age of 2731±6 Ma. Southeast of the quarry, at the same boundary, the Salahmi schists have been overturned towards the northeast, suggesting that the Archaean gneiss at Sorronmäki has been thrust towards the northeast over these rocks. In the western part of the study area, the Leppikangas granodiorite that intrudes the Svecofennian supracrustal rocks gives a U-Pb age of 1891+6 Ma. In the granodiorite, a strong lineation formed by the intersection of two foliations, which maybe L2 is associated with thrusting towards the northeast. The monazite age of the Archaean Sorronmäki gneiss is 1817+3 Ma, and the titanite age of the Svecofennian

  15. Sediment input pathways from North American highlands to the Gulf of Mexico based on detrital zircon U-Pb and U-Th/He dating (United States)

    Xu, J.; Snedden, J.; Stockli, D. F.; Fulthorpe, C.


    The lower Miocene is a period of significant sediment input to the Gulf of Mexico (GOM) Basin that accompanied tectonic and climatic changes in North America. However, the resulting sediment pathways from continental upland sources to basinal sink remain poorly constrained. We employ detrital zircon (DZ) U-Pb and (U-Th)/He double dating to define both basement provenance and the exhumation histories of detrital source regions. We have collected samples from outcrops across the northern Gulf, from Texas to Florida, in order to discriminate sediment pathways. Most of our data show a mixture of source terranes, including Oligocene volcanic centers, Cordilleran Arc, Laramide uplifts, Grenville, Mid-Continent, Yavapai-Mazatzal, and Appalachian-Ouachita as major provinces and Wyoming and Superior regions as minor provinces. However, major DZ age peaks vary greatly between different samples, providing a means to differentia drainage systems. Five major sediment input pathways are defined: the Paleo-Rio Grande, Paleo-Red, Paleo-Mississippi and Paleo-Tennessee rivers and a local river system in Florida draining from Appalachians. The Paleo-Rio Grande and Paleo-Red rivers show a significant sediment input from Oligocene volcanic centers, Laramide uplift regions and the Cordilleran Arc, whereas the Paleo-Tennessee River received most of its sediments from Appalachian-Ouachita and Grenville basement. The Paleo-Mississippi River lies within a transitional zone between western and eastern North American drainage systems. By integrating (U-Th)/He ages we can further distinguish first order volcanic zircons from recycled zircons. This can increase the ability to discriminate different drainage systems because the recycled zircons come from source terranes that are different from the original basement in which they formed. For example, two different Grenville-age zircon sources are differentiated by our U-Pb and (U-Th)/He ages. Sediments in Texas show a mixed zircon source from

  16. U-Pb SHRIMP and Sm-Nd geochronology of the paleoproterozoic Silvania magmatic arc in the neoproproterozoic Brasilia Belt, Goias, Central Brazil

    International Nuclear Information System (INIS)

    Fischel, D.P.; Pimentel, M.M.; Fuck, R.A; Armstrong, R


    The Brasilia Belt is a large Neoproterozoic orogen formed along the western margin of the Sao Francisco/Congo Craton in central Brazil. It comprises: (i) a thick Meso-Neoproterozoic metasedimentary/sedimentary pile with eastward tectonic vergence; (ii) a large Neoproterozoic juvenile arc in the west (Goias Magmatic Arc); and (iii) a micro-continent (or exotic sialic terrain) formed by Archean rock units (the Crixas -Goias granitegreenstones) and associated Proterozoic formations (Almeida et al. 1981, Fuck et al. 1993,1994, Pimentel et al. 2000a, b). The sialic basement on which the Brasilia Belt sediments were deposited is poorly understood, despite being well exposed in some areas of Goias and Tocantins. Gneiss and volcano-sedimentary units form most of this basement. Early studies have suggested that these rock units are dominantly Archean ( Danni et al. 1982, Marini et al. 1984). However, recent Sm- Nd isotopic studies have indicated that most of them are Paleoproterozoic (Sato 1998, Pimentel et al. 1999a, 2000b). Granite gneiss to the south and east of the Barro Alto mafic-ultramafic layered complex has been dated at 2128+/- 15 Ma (Correia et al. 1997). Calc-alkaline granite gneiss from Almas-Dianopolis is dated at ca. 2.2-2.45 Ga old (U-Pb SHRIMP on zircon and titanite, Cruz et al. 2000). The latter is probably the western extension of Paleoproterozoic rocks which underlie the San Francisco Craton to the east of the northern part of the Brasilia Belt. In central Goias, a large part of the Brasilia Belt is underlain by high-grade metamorphic rocks known as the Anapolis-Itaucu Complex, together with surrounding greenschist to amphibolite facies Mesoto Neoproterozoic cover metasediments of the Araxa group. These rocks represent the main constituent of the internal zone of the Brasilia Belt (Fuck et al. 1994, Pimentel et al. 2000b). Between the Araxa Group, and the easternmost part of the Anapolis-Itaucu Complex a volcano-sedimentary association known as Silvania

  17. Accessory Mineral U-Pb Ti-Zr Thermochronology of the Deep Crust of Zealandia: Rift, Breakup and Drift from 90-20 Ma (United States)

    Beinlich, A.; Palin, J.; Cooper, A. F.


    Cenozoic alkaline mafic volcanics of eastern Otago were made famous in classic petrology and petrography texts coauthored by Francis Turner. Several locales have yielded mantle and crustal xenoliths including the Pigroot "mafic phonolite". Here, among abundant spinel lherzolite xenoliths, we discovered an undeformed cumulate gabbro composed of intermediate plagioclase and pargasitic amphibole with augite, ilmenite, magnetite, titanite (sphene) and accessory zircon and apatite. Major and trace elements indicate the rock crystallised from primitive alkaline magma, whereas the mineral assemblage indicates equilibration under amphibolite facies conditions at 5-9 kbar. Accessory mineral U-Pb Ti-Zr thermochronology by LA-ICP-MS on grain separates and in thin section reveals a T-t path that began with zircon crystallisation at 90±2 Ma (^{208}Pb-corrected 206Pb/238U, n=37, mswd=9.9) and 710±20°C (Ti-zircon geothermometer of Watson et al. 2006). Titanite dates (207Pb-corrected 206Pb/238U, n=49) and temperatures (Zr-titanite geothermometer of Hayden et al. 2006 at 7 kbar) form a linear array (r2=0.6) extending from 85 Ma, 830°C to 34 Ma, 760°C. The slope of this T-t array is inconsistent with diffusive loss of Pb and Zr from titanite (Cherniak, pers.comm.) and, together with REE data and reaction textures, indicates prolonged growth at the expense of plagioclase and ilmenite. Apatite U-Pb isotope data projected from the measured 207Pb/206Pb in plagioclase give a lower intercept age of 20±3 Ma (n=17, mswd=1.5) which overlaps the K-Ar age of the phonotephrite host lava (Coombs, pers.comm.). This remarkable xenolith records 1) crystallisation of alkaline mafic magma in the deep crust during early rifting of Zealandia from Gondwana around 90 Ma, 2) heating during continued lithospheric thinning 90-85 Ma, 3) slow cooling (≤2°C/my) for 50 my following continental breakup at 85 Ma, and 4) transport to the surface and thermal quenching at 20 Ma. Slow cooling of the deep

  18. Timing of exhumation of the Ereendavaa metamorphic core complex (north-eastern Mongolia) - U-Pb and 40Ar/39Ar constraints (United States)

    Daoudene, Yannick; Ruffet, Gilles; Cocherie, Alain; Ledru, Patrick; Gapais, Denis


    The occurrence of numerous NE-SW trending rift basins that locally bound metamorphic core complexes in Transbaikalia, northern Mongolia and north-eastern China indicates that the eastern domain of the Central Asian Orogenic Belt was affected by a large-scale NW-SE extensional tectonic event during late Jurassic to early Cretaceous times. Available geochronological information about the formation of metamorphic core complexes in the region define partly synchronous periods in Transbaikalia (134-121 Ma) and North China (136-110 Ma) suggesting dome exhumation during the early Cretaceous. In north-eastern Mongolia, the Ereendavaa Range, lined by the Onon Shear Zone, was recently interpreted as one of these metamorphic core complexes, of late Jurassic to early Cretaceous age, on the basis of U-Pb zircons data from two synkinematic pegmatite dykes. However, this wide time range remains to be discussed. The present work constrains the tectono-thermal evolution of the range by providing new MC-ICP-MS U-Pb zircons ages from pegmatite dykes and metamorphic igneous rocks, and mica and amphibole 40Ar/39Ar laser step-heating ages from metamorphic and magmatic rocks that crop out within the range. The results show that (1) the Ereendavaa range was the locus of a widespread magmatic activity prior to its exhumation from late Jurassic times, (2) cooling of the range began at least at 137.9 ± 0.3 Ma as revealed by a 40Ar/39Ar plateau ages obtained from an hornblende sampled within the range core, and (3) exhumation along the Onon Shear Zone occurred from 130.3 ± 1.9 Ma down to 124.8 ± 0.3 Ma, as shown by ages of most of micas and amphiboles from the Shear zone. These more accurate ages are consistent with metamorphic core complex ages from adjacent areas. Furthermore, they argue for an extensional dynamic paroxysm at the scale of eastern Asia during a narrow time range in the early Cretaceous between ca. 130 Ma and ca. 120 Ma.

  19. U-Pb SHRIMP zircon dating of high-grade rocks from the Upper Allochthonous Terrane of Bragança and Morais Massifs (NE Portugal); geodynamic consequences (United States)

    Mateus, A.; Munhá, J.; Ribeiro, A.; Tassinari, C. C. G.; Sato, K.; Pereira, E.; Santos, J. F.


    Bragança and Morais Massifs are part of the mega-klippen ensemble of NW Iberia, comprising a tectonic pile of four allochthonous units stacked above the Central-Iberian Zone autochthon. On top of this pile, the Upper Allochthonous Terrane (UAT) includes different high-grade metamorphic series whose age and geodynamic meaning are controversial. Mafic granulites provided U-Pb zircon ages at 399 ± 7 Ma, dating the Variscan emplacement of UAT. In contrast, U-Pb zircon ages of ky- and hb-eclogites, felsic/intermediate HP/HT-granulites and orthogneisses (ca. 500-480 Ma) are identical to those of gabbros (488 ± 10 Ma) and Grt-pyroxenites (495 ± 8 Ma) belonging to a mafic/ultramafic igneous suite that records upper mantle melting and mafic magma crustal underplating at these times. Gabbros intrude the high-grade units of UAT and did not underwent the HP metamorphic event experienced by eclogites and granulites. These features and the zircon dates resemblance among different lithologies, suggest that extensive age resetting of older events may have been correlative with the igneous suite emplacement/crystallisation. Accordingly, reconciliation of structural, petrological and geochronological evidence implies that the development and early deformation of UAT high-grade rocks should be ascribed to an orogenic cycle prior to ≈ 500 Ma. Undisputable dating of this cycle is impossible, but the sporadic vestiges of Cadomian ages cannot be disregarded. The ca. 500-480 Ma time-window harmonises well with the Lower Palaeozoic continental rifting that trace the Variscan Wilson Cycle onset and the Rheic Ocean opening. Subsequent preservation of the high heat-flow regime, possibly related to the Palaeotethys back-arc basin development (ca. 450-420 Ma), would explain the 461 ± 10 Ma age yielded by some zircon domains in felsic granulites, conceivably reflecting zircon dissolution/recrystallisation till Ordovician times, long before the Variscan paroxysm (ca. 400-390 Ma). This

  20. Zircon U-Pb chronology, geochemistry and Sr-Nd-Pb isotopic compositions of the Volcanic Rocks in the Elashan area, NW China: petrogenesis and tectonic implications (United States)

    Zhou, H.; Wei, J.; Shi, W.; Li, P.; Chen, M.; Zhao, X.


    Elashan area is located in the intersection of the East Kunlun Orogenic Belt (EKOB) and the West Qinling Orogenic (WQOB). We present petrology, zircon U-Pb ages, whole-rock geochemistry and Sr-Nd-Pb isotopic compositions from the andesite and felsic volcanic rocks (rhyolite and rhyolitic tuffs) in Elashan group volcanic rock. The LA-ICP-MS zircon U-Pb age data indicate that the volcanic rocks are emplaced at 250 247 Ma. The volcanic rocks have high -K and aluminum - peraluminous characteristics, A/CNK = 1.07 1.82, δ ranges from 1.56 2.95, the main body is calc-alkaline rock. They are enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) and depleted in some high field strength elements (HFSEs, e.g., Nb, Ta, P and Ti), while having a flat heavy REE (HREEs) pattern. The ∑REE values of 178.68 to 298.11 ppm, average 230.50 ppm. The LREE/HREE values of 4.39 to 11.78 ppm, average 6.77 ppm. REE fractionation is obvious, REE distribution curve was right smooth, and have slightly negative Eu anomalies (Eu/Eu*=0.44-0.80, average 0.60), which as similar to the island arc volcanic rocks. The volcanic rocks have initial 87Sr/86Sr ratios of 0.71028-0.71232, ɛNd(t) values of -6.7 to -7.6, with T2DM-Nd ranging from 1561 to 1640 Ma. Pb isotopic composition (206 Pb / 204 Pb)t = 18.055 18.330, (207 Pb / 204 Pb)t = 15.586 15.618, (208 Pb / 204 Pb)t = 37.677 38.332. Geochemical and Sr-Nd-Pb isotopes indicates that Elashan group volcanic magma derived mainly from the lower crust. Elashan group volcanic rocks is the productive East Kunlun block and West Qinling block collision, which makes the thicken crust caused partial melting in the study area. The source rocks is probably from metamorphic sandstone of Bayankala. But with Y-Nb and Rb-(Y+Nb), R1-R2 and Rb/10-Hf-Ta*3 diagrams showing that intermediate-acid rocks mainly formed in volcanic arc-collision environment, probably the collision event is short , therefore rocks retain the original island

  1. Improved accuracy of U-Pb zircon ages by the creation of more concordant systems using an air abrasion technique

    International Nuclear Information System (INIS)

    Krogh, T.E.


    Abrasion combined with an improved paramagnetic separation technique eliminates 90 to 100 percent of discordance so that ages of unprecedented accuracy (+-1 to 3m.y.) can be achieved for virtually all 2700m.y. old zircon populations from plutonic or volcanic rocks. The procedures work even better for younger zircons. Besides removing outer layers that may have been leached, high-U parts are preferentially removed by abrasion because they are softened by radiation damage. Altered and cracked zircons also tend to be eliminated. In most cases, the new concordant data move up the line established by previously analysed paramagnetic fractions but a number of anomalies have been found where old data give upper intersections that are in error by as much as 25m.y. Reducing or eliminating paramagnetically correlated Pb loss greatly enhances our ability to define mixing lines for igneous or metamorphic rocks when two ages of zircon are present. The abrasion technique allows detection of an inherited component if it exists by enhancing the sample in core material. Abrasion in many cases removes about 80 percent of the common lead, thus allowing a direct evaluation of this component. When the outer parts of grains are removed, the correlation between magnetic susceptibility and uranium content is maintained but the usual correlation of uranium level with lead loss is reduced or eliminated. Therefore, only near surface uranium is involved in the classic discordance versus uranium level correlation of Silver (1963). (author)

  2. Improved accuracy of U-Pb zircon ages by the creation of more concordant systems using an air abrasion technique

    International Nuclear Information System (INIS)

    Krogh, T.E.


    Abrasion combined with an improved paramagnetic separation technique eliminates 90 to 100 percent of discordance so that ages of unprecedented accuracy (+- 1 to 3 m.y.) can be achieved for virtually all 2700 m.y. old zircon populations from plutonic or volcanic rocks. The procedures work even better for younger zircons. Besides removing outer layers that may have been leached, high-U parts are preferentially removed by abrasion because they are softened by radiation damage. Altered and cracked zircons also tend to be eliminated. In most cases, the new concordant data move up the line established by previously analysed paramagnetic fractions but a number of anomalies have been found where old data give upper intersections that are in error by as much as 25 m.y. Reducing or eliminating paramagnetically correlated Pb loss greatly enhances our ability to define mixing lines for igneous or metamorphic rocks when two ages of zircon are present. The abrasion technique allows detection of an inherited component if it exists by enhancing the sample in core material. Abrasion in many cases removes about 80 percent of the common lead, thus allowing a direct evaluation of this component. (author)

  3. Integrated U-Pb zircon and palynological/palaeofloristic age determinations of a Bashkirian palaeofjord fill, Quebrada Grande (Western Argentina) (United States)

    Valdez Buso, Victoria; di Pasquo, Mercedes; Milana, Juan Pablo; Kneller, Benjamin; Fallgatter, Claus; Junior, Farid Chemale; Gomes Paim, Paulo Sérgio


    This work presents a new age framework for the main Bashkirian glacio-eustatic transgression in Argentina, including the first absolute age for the Jejenes Formation, San Juan Province, based on radiometric dating of a crystal-rich tuff, supported by palynological and palaeofloristic studies, and presented within a revised palaeogeographic setting. The Jejenes Formation represents the glacial to postglacial fill of the Quebrada Grande palaeofjord carved in the Eastern Precordillera. The succession has been subdivided into five stages, the youngest of which suggests a previously unrecognised glacial event for this locality. Six productive levels for palynology were found within proglacial strata, and in the base and top of the succeeding interglacial stage. Palynoassemblages are characterized by poorly preserved trilete spores and monosaccate pollen grains along with a large amount of terrestrial phytoclasts. Main species indicating the Raistrickia densa-Convolutispora muriornata SubZone (DMa SZ) are Vallatisporites ciliaris, Cristatisporites rollerii, C. stellatus, C. chacoparanensis, C. inconstans and monosaccates such as Circumplicatipollis plicatus. This DMa SZ is estimated as Serpukhovian/Bashkirian and characterizes the glacial-related Guandacol Formation and equivalents units of the western Paganzo Basin. A tuffaceous level in the proglacial unit, bearing platyspermic seeds, plant remains and palynomorphs, yielded first-cycle volcanic zircons that were analysed by SHRIMP. An absolute age of 321.3 ± 5.3 Ma confirms a Bashkirian age for the main postglacial transgression in the Paganzo Basin, and offers a novel calibration for the palynoassemblages of DMa SZ that occurs elsewhere in Western Argentina.

  4. Magnetic studies and U Pb geochronology of the Uruguayan dyke swarm, Rio de la Plata craton, Uruguay: paleomagnetic and economic implications (United States)

    Halls, Henry C.; Campal, Nestor; Davis, Don W.; Bossi, Jorge


    A U-Pb age on baddeleyite of 1790±5 Ma has been obtained from a single dyke of the Uruguayan tholeiitic dyke swarm from the Rio de la Plata craton. Palaeomagnetic results from this and 10 other dykes yield two components, one (A) has the following paleomagnetic parameters: declination=12°, inclination=-16°, α95=7°, latitude of paleopole=61°, longitude=-31°, dp=4°, dm=7°, paleolatitude=-8°, whereas another (B), about 20° steeper, has a direction closer to the present Earth's field direction in Uruguay. Neither magnetisation is considered primary, although the A component may represent a composite between B and a primary component. A field test for the primary nature of the remanences was inconclusive, and no primary pole positions of similar age from other South American cratons are available for comparison. The magnetic results demonstrate that darker-coloured andesite dykes that are sought for facing and monument stone (as 'black granite') can be easily differentiated from more andesi-basaltic, lighter coloured, less valuable dykes of the same swarm, using aeromagnetic data. The results suggest that a high resolution airborne magnetic survey could constitute an important exploration tool for the Uruguayan 'black granite' industry.

  5. Metamorphic evolution and U-Pb zircon SHRIMP geochronology of the Belizário ultramafic amphibolite, Encantadas Complex, southernmost Brazil

    Directory of Open Access Journals (Sweden)

    Hartmann Léo A.


    Full Text Available The integrated investigation of metamorphism and zircon U-Pb SHRIMP geochronology of the Belizário ultramafic amphibolite from southernmost Brazil leads to a better understanding of the processes involved in the generation of the Encantadas Complex. Magmatic evidence of the magnesian basalt or pyroxenite protolith is only preserved in cores of zircon crystals, which are dated at 2257 ± 12 Ma. Amphibolite facies metamorphism M1 formed voluminous hornblende in the investigated rock possibly at 1989 ± 21 Ma. This ultramafic rock was re-metamorphosed at 702±21 Ma during a greenschist facies eventM2; the assemblage actinolite + oligoclase + microcline + epidote + titanite + monazite formed by alteration of hornblende. The metamorphic events are probably related to the Encantadas Orogeny (2257±12 Ma and Camboriú Orogeny (~ 1989 Ma of the Trans-Amazonian Cycle, followed by an orogenic event (702±21 Ma of the Brasiliano Cycle. The intervening cratonic period (2000-700 Ma corresponds to the existence of the Supercontinent Atlantica, known regionally as the Rio de la Plata Craton.

  6. Geochronological U-PB zircon dating of two ore-bearing magma pulses: stratifrom and non-stratiform bodies in the Fedorov deposit (Kola Peninsula). (United States)

    Nitkina, E.


    -100-m-thick marginal zone composed of schists after mafic rocks; the zone of ore-bearing taxitic gabbronorite typical of the deposit and will be discussed below; 50-200-m-thick norite zone with norites and plagiopyroxenites; 200-800-m-thick gabbronorite zone, and the uppermost gabbro zone with the thickness of over 1000 m. The latter contains rare thin layers of leucocratic rock varieties and anorthosites (Shissel et al., 2002; Mitrofanov et al., 2005). The Fedorov deposit is characterized by the presence of mineralized taxitic gabbronorite zone with the thickness of 150 - 300 m. The zone contains great amounts of orthopyroxenite and norite xenoliths (Shissel et al., 2002; Mitrofanov et al., 2005). Besides, the stratigraphy of the Fedorov deposit includes the second-phase rocks, gabbronorites cementing the xenoliths with sulphide mineralization (Shissel et al., 2002; Mitrofanov et al., 2005). This is the non-stratiform type of ore-bearing bodies, and the previously defined age for this ore-forming stage was 2485+/-9 Ma (Nitkina, 2006). The basement of the Fedorov deposit, where sulphides (2-5 vol.per.) are spread widely, but irregularly includes several low-sulphide PGE-bearing horizons occurring conformably to the massif layering. This is the stratiform type of ore-bearing bodies. The thickness of the sulphide mineralization interval varies from 10-20 to 100 m. This zone is divided into the lower and upper ore bodies with the total PGE content of about 1 ppm (Shissel et al., 2002; Mitrofanov et al., 2005; Mitrofanov, 2005). The isotope U-Pb zircon dating was made on the core samples from the upper ore body (gabbro F10-B weighing 7,35 kg), and from the lower ore body (gabbro with olivine F10-D weighing 20,5 kg). Four zircon populations from gabbro F10-B were separated from electromagnetic and non-electromagnetic fractions for isotope U-Pb dating that yielded an age of 2518+/-9 Ma. The isotope U-Pb dating of olivine gabbro F10-D was carried out on five zircon populations

  7. Listwaenite in the Sartohay ophiolitic mélange (Xinjiang, China): A genetic model based on petrology, U-Pb chronology and trace element geochemistry (United States)

    Qiu, Tian; Zhu, Yongfeng


    Listwaenite lenses in the Sartohay ophiolitic mélange (Xinjiang, China) were formed via reactions between serpentinite and metasomatic fluids. First, serpentinite changed into talc schist via the reaction of serpentine + CO2 → talc + magnesite + H2O. Second, talc schist changed into listwaenite via the reaction of talc + CO2 → magnesite + quartz + H2O. Magnetite was progressively destroyed during transformation from serpentinite to talc schist, and completely consumed in listwaenite. Zircon crystals 30-100 μm long, disseminating in talc schist, undeformed listwaenite and mylonitized listwaenite, coexist with talc, quartz and magnesite, while micron-sized zircon grains (ages (302.9 ± 6.8 Ma, 299.7 ± 5.5 Ma and 296.5 ± 3.5 Ma), and are thought to represent the age of formation of the talc schist and listwaenite. These ages are indistinguishable within errors and suggest a rapid transformation from talc schist to listwaenite. Some zircon rims in samples of the undeformed listwaenite and mylonitized listwaenite give much younger apparent U-Pb ages (280-277 Ma), which could be interpreted as a recrystallization age reflecting late-stage shearing in the Sartohay ophiolitic mélange.

  8. U-Pb age for some base-metal sulfide deposits in Ireland: genetic implications for Mississippi Valley-type mineralization

    International Nuclear Information System (INIS)

    Duane, M.J.; Welke, H.J.; Allsopp, H.L.


    Evidence is presented that links the timing of vein-type (Cu-Ag(U)) to stratiform Mississippi Valley-type (MVT, Pb-Zn) ore events in Ireland. The rare occurrence of pitchblende, coffinite(?), and brannerite mineralization, which is regarded as a precursor component to the sulfide mineralization in the Gortdrum deposit (Ireland), provides the first direct radiometric dating tool for these carbonate-hosted deposits. The U-Pb (340 +25/-20 Ma) and Pb-Pb (359 +/- 26 Ma) whole-rock ages constrain the uranium and base-metal mineralizing events to the Early Carboniferous. The data support a model according to which MVT and earlier uranium mineralization stages of some major ore bodies resulted from fracturing coincident with large basin-dewatering events. The Pb-Pb and concordia data are consistent with an Early Carboniferous age for the mineralization at Gortdrum and agree closely with a previously published Rb-Sr age of 359 +/- 22 Ma, obtained for Missouri glauconites. Furthermore, other comparative geologic data from Ireland and from North American MVT mineral provinces support a model of Pb-Zn-Cu(U) mobilization on a regional scale that implicates the later closing stages of the proto-Atlantic. 40 references, 3 figures, 1 table

  9. Petrogenesis, detrital zircon SHRIMP U-Pb geochronology, and tectonic implications of the Upper Paleoproterozoic Seosan iron formation, western Gyeonggi Massif, Korea (United States)

    Kim, Chang Seong; Jang, Yirang; Samuel, Vinod O.; Kwon, Sanghoon; Park, Jung-Woo; Yi, Keewook; Choi, Seon-Gyu


    This study involves investigations on the Upper Paleoproterozoic iron formation (viz., Seosan iron formation) from the Seosan Group, Gyeonggi Massif of the southwestern Korean Peninsula. It occurs as thin banded layers within meta-arkosic sandstone, formed by alternating processes of chemical (hydrothermal) and detrital depositions under a shallow marine environment. It mainly consists of alternating layers of iron oxides, mostly hematite, and quartz. Minor amounts of magnetite surrounded by muscovite, clinopyroxene and amphibole indicate hydrothermal alteration since its formation. Meta-arkosic sandstone is composed of recrystallized or porphyroclastic quartz and microcline, with small amounts of hematite and pyrite clusters. The Seosan iron formation has high contents of total Fe2O3 and SiO2 with positive Eu anomalies similar to those of other Precambrian banded iron formations, and its formation is clearly related to hydrothermal alteration since its deposition. Detrital zircon SHRIMP U-Pb geochronology data from a meta-arkosic sandstone (SN-1) and an iron formation (SN-2) show mainly two age groups of ca. 2.5 Ga and ca. 1.9-1.75 Ga. This together with intrusion age of the granite gneiss (ca. 1.70-1.65 Ga) clearly indicate that the iron formations were deposited during the Upper Paleoproterozoic. The dominant Paleoproterozoic detrital zircon bimodal age peaks preserved in the Seosan iron formation compare well with those from the South China Craton sedimentary basins, reflecting global tectonic events related to the Columbia supercontinent in East Asia.

  10. Calymmian magmatism in the basement of the Jauru Terrain (Rondonian - San Ignacio Province), Amazon Craton: U-Pb and Sm-Nd geochemistry and geochronology

    Energy Technology Data Exchange (ETDEWEB)

    Fachetti, Frankie James Serrano; Costa, Ana Claudia Dantas da; Silva, Carlos Humberto da, E-mail:, E-mail:, E-mail: [Universidade Federal de Mato Grosso (UFMT), Cuiaba, MT (Brazil). Instituto de Ciencias Exatas e da Terra


    The Taquarussu Orthogneiss and the Guadalupe Granodiorite, part of the Rondonian-San Ignacio Province basement, southwest of the Amazonian Craton, correspond to oriented bodies with a NW trend. The rocks show granodiorite composition with minor occurrences of coarse grained monzogranites consisting essentially of plagioclase, quartz, microcline, orthoclase and biotite. The accessory minerals are amphibole, titanite, garnet, apatite, epidote, zircon and opaque. The geochemical data indicate that the rocks are classified as granodiorites and monzogranites, with an intermediate to acid magmatism, sub-alkaline character, from the calc-alkaline to the high-K calc-alkaline series, with alumina ratios ranging from metaluminous to lightly peraluminous. The rocks were classified as generated in volcanic islands arc environment and the U-Pb data (SHRIMP zircon) show a concord age 1575 ± 6 Ma. The Sm-Nd model age (T{sub DM}) is 1.63 Ga with εNd (t = 1.57 Ga) ranging from -1.52 to +0.78. These data indicate that these rocks are probably a juvenile crust with a possible contamination of crustal rocks. (author)

  11. U-Pb and K-Ar geochronology from the Cerro Empexa Formation, 1st and 2nd Regions, Precordillera, northern Chile

    International Nuclear Information System (INIS)

    Tomlinson, A.J; Martin, M.W; Blanco, N.; Perez de Arce, C


    The Cerro Empexa Formation (Galli, 1957) is a regionally distributed andesitic volcanic and continental sedimentary unit exposed in the Precordillera of the 1st and 2nd Regions of northern Chile. The formation has generally been considered to lie within the Lower or 'mid' Cretaceous, however, this assignment is based on scant, unreliable geochronologic data. Furthermore, there are conflicting interpretations as to whether the unit predates or postdates the first major Mesozoic shortening event affecting northern Chile. Because of the formation's presumed mid-Cretaceous age and its stratigraphic position over older back-arc sedimentary successions, the unit has been interpreted to represent products of the first eastward jump in the Andean magmatic arc from the arc's initial position in the Cordillera de la Costa (Scheuber and Reutter, 1992). In this paper we present the results of mapping and field observations that indicate exposures previously assigned to the Cerro Empexa Formation include two andesitic volcanic units separated by a major unconformity. The Cerro Empexa Formation proper lies above this unconformity. We also present U-Pb zircon and K-Ar geochronology that indicate the Cerro Empexa Formation is latest Cretaceous in its lower levels, and integrate our data with previously reported 40 Ar/ 39 Ar and fission-track data in the Cerros de Montecristo area (Maksaev, 1990; Maksaev and Zentilli, 1999) to show that 1800±600 m of rocks were deposited within ca. 2.5 m.y (au)

  12. High-precision U-Pb zircon age from the Anfiteatro de Ticó Formation: Implications for the timing of the early angiosperm diversification in Patagonia (United States)

    Perez Loinaze, Valeria S.; Vera, Ezequiel I.; Passalia, Mauro G.; Llorens, Magdalena; Friedman, Richard; Limarino, Carlos O.; Césari, Silvia N.


    The Baqueró Group is one of the most relevant units regarding the study of the early diversification of angiosperms in South America. Whereas the age of the upper part of the Group, namely the Punta del Barco Formation, has been recently dated at 114.67 ± 0.18 Ma, the rest of the unit still lacks precise dating. In this contribution a CA-TIMS U-Pb zircon age of 118.23 ± 0.09 Ma for a tuff interlayered with fossiliferous rocks of the Anfiteatro de Ticó Formation (lower part of the Baqueró Group) is reported. This age constrains the duration of deposition of the Baqueró Group to approximately 4 Ma and provides new evidence for the age interpretation of the previously described angiosperm flora and associated pollen assemblages from this unit, until now interpreted as early Aptian or possibly Barremian in age. The Aptian age of the Baqueró Group allows a better comparison between the paleofloras from this southernmost region.

  13. U-Pb zircon and monazite geochronology of the Hercynian two-mica granite composite pluton of Cabeceiras de Basto (Northern Portugal); Geochronologie U-Pb sur zircon et monazite du massif composite de granite a deux micas hercynien de Cabeceiras de Basto (Nord-Portugal)

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, A.; Noronha, F. [Universidade do Porto (Portugal). Centro de Geologia; Leterrier, J. [Centre de Recherches Petrographiques et Geochimiques, 54 - Vandoeuvre-les-Nancy (France); Bertrand, J.M. [Universite de Savoie, 73 - Le-Bourget-du-Lac (France). Laboratoire de geodynamique des Chaines alpines


    The zircon and monazite U-Pb minimum age of the Hercynian peraluminous two-mica composite granite pluton of Cabeceiras de Basto (Northern Portugal) is 311 {+-} 1 Ma (2 {sigma}). This age, well constrained by a concordant monazite of 311{+-}4 Ma (2{sigma}), is in good agreement with the age suggested for the syn-kinematic, syn-D3, Iberian granites of the Hercynian orogeny (315-305; Pinto et al., 1987). The ({sup 87}Sr/{sup 86}Sr){sub i} and {xi}{sub Nd} isotopic ratios, calculated for 311 Ma, suggest that the three granite units which constitute the massif may derive from an heterogeneous crustal source dated (upper intercept of the discordance) around 1200 Ma. (authors) 21 refs.

  14. Petrographic and geochemical characterization and isotope analysis of U-PB (SHRIMP) in tuffaceous siltstone, Salitre formation, Sao Francisco supergroup, BA, Brazil; Caracterizacao petrografica, geoquimica e analises isotopicas U-PB (SRIMP) em siltito tufaceo, formacao Salitre Supergrupo Sao Francisco, Bahia

    Energy Technology Data Exchange (ETDEWEB)

    Santana, Ana; Chemale Junior, Farid, E-mail: [Universidade de Brasilia (UnB), DF (Brazil); Sherer, Claiton Marlon dos Santos [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil)


    The Salitre Formation consists of neoproterozoic carbonate sequence overlying the Sao Francisco Craton (SFC) in Bahia. Data on the origin of such training are scarce, mainly due to their nature, essentially carbonate. In this study, from the petrographic characterization and geochemical thin levels of terrigenous, it was identified the contribution of volcanic material. Isotopic analysis of U-Pb, SHRIMP, indicate the existence of young grain, aged 669 ± 14 Ma (Cryogenian) - probable volcanism associated with the building of neoproterozoic mobile belts surrounding the SFC - and inherited zircons with the main population in the Paleoproterozoic and corresponding to the source area of the crystalline basement. Detrital zircons with ages between Statherian and Tonian have also been reported and have the source area the metasedimentary rocks of the Espinhaco Supergroup. (author)

  15. Age and sedimentary provenance of the Canastra and Vazante groups in the regions of Guarda-Mor and Unai, Minas Gerais, Sm-Nd and U-Pb methods, Brazil; Idade e proveniencia sedimentar dos grupos Canastra e Vazante nas regioes de Guarda-Mor e Unai, Minas Gerais, metodos Sm-Nd e U-Pb

    Energy Technology Data Exchange (ETDEWEB)

    Marimon, Rodrigo Schwantes; Dantas, Elton Luiz; Matteini, Massimo, E-mail:, E-mail: [Universidade de Brasilia (UnB), DF (Brazil). Instituto de Geociencias


    Sm-Nd and U-Pb isotopic data on rocks of the Canastra and Vazante groups suggest derivation from predominantly Meso to Paleoproterozoic sources for these tectonic units of the Brasilia Range. T{sub DM} model ages between 1.76 and 2.85 Ga are consistent with continuous supply of sources with long crustal residence time and / or mix between old and younger sources. Detrital zirconia around 1.0 Ga may indicate the maximum deposition age of the Canastra Group, as well as suggests an important Mesoproterozoic source in the derivation of these sediments. The analyzed samples are in different scales of push, that put side by side the diverse formations of the Canastra and Vazante. So tectonics can explain the change of origin between each one.

  16. New Constraints for Tectono-Thermal Alpine Evolution of the Pyrenees: Combining Zircon Fission-Track and (U-Th)/He Analyses with Raman Spectrometry and In-Situ K-Ar Geochronology (United States)

    Waldner, M.; Bellahsen, N.; Mouthereau, F.; Pik, R.; Bernet, M.; Scaillet, S.; Rosenberg, C.


    The pyrenean range was formed by the convergence of European and Iberian plates following the inversion of the Mesozoic rifting in the north of Pyrenees. In the Axial Zone, the collision caused an antiformal nappe-stacking of tectonic units. Recent studies pointed out the importance of pre-collision structural and thermal inheritance that may play a major role for orogeny such as: 1) Paleozoic Variscan inheritance; 2) Mesozoic rift-related high geothermal gradients, which are maintained during the onset of convergence in the North Pyrenean Zone. From a mineralogical point of view, pre-collision feldspars have been destabilized and influenced the development of alpine phyllonite in brittle-ductile conditions which suggests a weak crustal behavior during the formation of the orogenic wedge. Our aim is to get a better understanding of alpine deformation and exhumation by coupling different thermochronological, geochronological and thermometric methods. We document the thermal evolution of each tectonic unit by using low-temperature thermochronometers (Zircon Fission Tracks, U-Th/He on zircons including laser ablation profiles). Our data on vertical profiles combined to existing dataset on apatite allows to model alpine exhumation across the Axial zone. Structural observations through alpine thrusts coupled to geochronology (in situ K/Ar on phengites), Raman and chlorite-phengite thermo(baro)metry provide new key data to unravel the alpine evolution of the Pyrenees. According to preliminary ZFT results on granite massifs in the central part of Pyrenean Axial zone (near ECORS profile), exhumation ages potentially indicates a migration of exhumation towards the south. Exhumation ages of the northern massifs seems to have preserved the North Pyrenean Cretaceous rift evolution. Further south, the onset of exhumation is as old as Paleocene, which precedes the Eocene ages of the literature. The low burial estimated in the northern massifs may indicate a high thermal gradient

  17. Permian depositional age of metaturbidites of the Duque de York Complex, southern Chile: U-Pb SHRIMP data and palynology Edad pérmica de sedimentación de las metaturbiditas del Complejo Duque de York, sur de Chile: datos mediante U-Pb SHRIMP y palinología

    Directory of Open Access Journals (Sweden)

    Fernando A Sepúlveda


    Full Text Available The Duque de York Complex (DYC is part of the low grade metamorphic accretionary complexes of the pre-Andean Patagonian 'basement'. It is a sedimentary succession exposed along the western margin of southernmost South America. New U-Pb zircon ages and palynological data restrict the maximum depositional age of the DYC to the limit between the early Permian (Kungurian and the middle Permian (Roadian. The palynological association recorded in the DYC, characterized mainly by Gymnospermopsida pollen, indicates a humid environment of forest with an under-growth of ferns. Regional paleogeographic correlations point out that an interpretation of DYC as an autochthonous terrane cannot be discarded, contrasting with previous hypotheses which suggest an allochthonous character for this complex.El Complejo Duque de York (CDY forma parte de los complejos metamórficos acrecionarios del 'basamento' pre-Andino de la Patagonia, correspondiendo a una sucesión sedimentaria que añora a lo largo del margen occidental austral de Sudamérica. Nuevas edades U-Pb en circón, en combinación con información palinológica, permiten acotar la maxima edad de depósito posible del CDY al límite entre el Pérmico temprano (Kunguriano y el Pérmico medio (Roadiano. La asociación palinológica registrada en el CDY está caracterizada por Gymnospermopsida, e indica un ambiente húmedo de bosque con sotobosque de heléchos. Las correlaciones paleogeográñcas apuntan a que la condición de terreno autóctono del CDY no puede ser descartada, lo que se contrapone a hipótesis anteriores, las que sugieren un carácter alóctono para este complejo.

  18. In Situ Planetary Geochronology Technology (United States)

    National Aeronautics and Space Administration — This project's purpose was to determine whether a Pulsed Neutron Generator (PNG) could be used in an instrument that could perform in situ age dating of planetary...

  19. In Situ Activation of Microcapsules (United States)

    Morrison, Dennis R. (Inventor); Mosier, Benjamin (Inventor)


    Disclosed are microcapsules comprising a polymer shell enclosing two or more immiscible liquid phases in which a drug, or a prodrug and a drug activator are partitioned into separate phases. or prevented from diffusing out of the microcapsule by a liquid phase in which the drug is poorly soluble. Also disclosed are methods of using the microcapsules for in situ activation of drugs where upon exposure to an appropriate energy source the internal phases mix and the drug is activated in situ.

  20. Tectonic evolution of the NE section of the Pamir Plateau: New evidence from field observations and zircon U-Pb geochronology (United States)

    Zhang, Chuan-Lin; Zou, Hai-Bo; Ye, Xian-Tao; Chen, Xiang-Yan


    The Pamir Plateau at the western end of the India-Asia collision zone underwent long-term terrane drifting, accretion and collision between early Paleozoic and Mesozoic. However, the detailed evolution of this plateau, in particular, the timing of the Proto- and Palaeo-Tethys ocean subduction and closure, remains enigmatic. Here we report new field observations and zircon U-Pb ages and Hf isotopic compositions of the representative rocks from the so-called Precambrian basement in the northeastern Pamir, i.e., the Bulunkuole Group. The rock associations of the Bulunkuole Group indicate volcano-sedimentary sequences with arc affinities. Geochronological data demonstrate that the deposition age of the Bulunkuole Group in the NE section of the Pamir was Middle to Late Cambrian (530-508 Ma) rather than Paleoproterozoic. The deposition age became progressively younger from south to north. The amphibolite- to granulite facies metamorphism of the Bulunkuole Group took place at ca. 200-180 Ma. Unlike the scenario in the Southern Kunlun terrane (SKT) in the eastern section of the West Kunlun Orogenic Belt (WKOB), early Paleozoic metamorphism (ca. 440 Ma) was absent in this area. Two phases of magmatic intrusions, composed of granites and minor gabbros with arc geochemical signatures, emplaced at 510-480 Ma and 240-200 Ma. The amphibolite (meta mafic sheet? 519 Ma) and the meta-rhyolite (508 Ma) have zircon εHf(t) values of 1.6 to 5.9 and - 1.5 to 1.4, respectively. The 511 Ma gneissic granite sheet and the 486 Ma gabbro have zircon εHf(t) values of - 0.1 to 2.4 and 1.3 to 3.6, respectively. Zircon εHf(t) of the 245 Ma augen gneissic granite sheet varies from - 2.2 to 2.0 whereas the metamorphic zircons from the amphibolite (193 Ma) and high-pressure mafic granulite sample (187 Ma) have negative εHf(t) values of - 5.3 to - 2 and - 15 to - 12, respectively. In line with rock association and the deposition age of the Bulunkuole Group and the Saitula Group in the eastern

  1. Petrography and U-Pb Zircon Geochronology of Geological Units of the Mesa de Cocodite, Península de Paraguaná, Venezuela (United States)

    Mendi, D.; Baquero, M. L.; Oliveira, E. P.; Urbani, F.; Pinto, J.; Grande, S.; Valencia, V.


    Several continental crust units crop out in The Mesa de Cocodite, central Paraguaná Peninsula, Northwestern Venezuela, including a newly mapped quartz-feldspar gneiss that intruded the El Amparo Pluton, a major low-graded metamorphic unit of Permian age. It is unconformably overlying by Late Jurassic phyllites of the Pueblo Nuevo Formation. All these units are cross-cut by narrow dykes. This contribution focuses on the petrography and LA-ICP-MS U-Pb zircon dating of the igneous units, with the aim of constraining magmatism and its tectonic significance in the area. The quartz-feldspar gneiss consists of albite, bluish-smoked quartz, muscovite-chlorite, epidote and zircon. The enclosing El Amparo Pluton is typically a coarse-grained and thick-banded metagranodiorite, containing andesine, quartz, hornblende, epidote, K-feldspar, biotite, chlorite, titanite and zircon. The younger dykes consist of fine-grained, porphyritic hornblende diorites that contain numerous hornblende phenocrysts. The main minerals are andesine, hornblende, quartz, and chlorite. Accessory minerals include zircon, epidote and opaques. A felsic gneiss xenolith collected from the dykes contain quartz, K-feldspar, chlorite, epidote, albite and zircon. Zircon population in the quartz-feldspar gneiss displays a discordia trend, ranging in age from 1050-750 Ma but mostly around 950-900 Ma, which may represent a peak high-grade metamorphism in the area. The El Amparo Pluton provides a concordant Permian age (271.3±6.5 Ma), which is comparable with previous reported U-Pb ages in titanite. Because the porphyry dykes cross-cut all the units in the area, they should be post-Late Jurassic in Age; however, all dated zircons from the dykes are in the range of 1200-750 Ma. The absence of younger ages can be attributed to either formation during a relatively low temperature magmatic event, which generated very narrow younger zircon rims only and thus undetectable with the technique used, or a completely lack

  2. Primera edad U-Pb en circón usando LA-ICP-MS de un dique traquiandesítico emplazado en el granito tipo-A Los Árboles, Sierras Pampeanas Orientales


    Juan A Dahlquist; Pablo H Alasino


    La edad de cristalización de diques subvolcánicos emplazados en plutones graníticos carboníferos, Sierras Pampeanas Orientales, permanece incierta. La primera edad U-Pb en circón usando LA-ICP-MS obtenida en un dique que intruye al plutón Los Árboles (sierra de Fiambalá), revela una edad de cristalización de 311 ± 3 Ma.

  3. Aeolian dust supply from the Yellow River floodplain to the Pleistocene loess deposits of the Mangshan Plateau, central China: Evidence from zircon U-Pb age spectra (United States)

    Shang, Yuan; Prins, Maarten A.; Beets, Christiaan J.; Kaakinen, Anu; Lahaye, Yann; Dijkstra, Noortje; Rits, Daniël S.; Wang, Bin; Zheng, Hongbo; van Balen, Ronald T.


    The thick loess-palaeosol sequences in the Mangshan Loess Plateau (MLP; central China) along the south bank of the lower reach of the Yellow River provide high-resolution records of Quaternary climate change. In addition, substantial increases in grain-size and accumulation rate have been inferred in the upper part of the loess sequence, above palaeosol layer S2. This study investigates the sources of the long-term dust supply to the MLP and explores the mechanism behind the sudden increase in sediment delivery and coarsening of the loess deposits since S2 (∼240 ka) by using end member modelling of the loess grain-size dataset and single-grain zircon U-Pb dating. Our results indicate that the lower Yellow River floodplain, directly north of the MLP, served as a major dust supply for the plateau at least since the deposition of loess unit L9 and indirectly suggest that the integration of the Yellow River and the disappearance of the Sanmen palaeolake took place before L9 (∼900 ka). The sudden change in sedimentology of the Mangshan sequence above palaeosol unit S2 may result from an increased fluvial sediment flux being transported to the lower reaches of the Yellow River because of tectonic movements (initiated) in the Weihe Basin around 240 ka. Furthermore, sediment coarsening can be explained by the gradual southward migration of the lower Yellow River floodplain towards the MLP since the deposition of palaeosol S2. The migration is evidenced by the formation of an impressive scarp, and is likely caused by tectonic tilting of the floodplain area.

  4. Recognition of the Kaweka Terrane in northern South Island, New Zealand : preliminary evidence from Rb-Sr metamorphic and U-Pb detrital zircon ages

    International Nuclear Information System (INIS)

    Adams, C.J.; Mortimer, N.; Campbell, H.J.; Griffin, W.L.


    Detrital zircon U-Pb ages and Rb-Sr metamorphic ages from low-grade Torlesse Supergroup metasedimentary rocks from North Canterbury and Marlborough provide preliminary evidence for a continuation of the Kaweka Terrane of the central North Island into the Torlesse Composite Terrane of the South Island. This would extend from the south side of the Wairau Fault in the upper Wairau River valley southwards to the Lake Tennyson and Lake Sumner areas, and as far as Hawarden. Rb-Sr ages indicate Jurassic metamorphism, 170±24 Ma, with initial 87 Sr/ 86 Sr ratios at that time 0.7073 ± 0.0007 i.e. similar to their North Island counterparts. These Kaweka Terrane rocks have detrital zircon ages that follow the distinctive pattern of the Torlesse rocks in general, i.e. substantial (>30%) Permian-Triassic and Precambrian-Early Palaeozoic groupings, but they also have minor youngest age components c. 175-165 Ma which constrain a maximum Early-Middle Jurassic depositional age. In detail, significant, older zircon components are Late Permian-Early Triassic (260-240 Ma) and Late Triassic (220-210 Ma), but the Precambrian-Early Palaeozoic detrital zircon ages are more scattered. The Kaweka Terrane thus forms a linear belt (c. 500 km) along the length of the Torlesse Composite Terrane in both North and South Islands. In the South Island it coincides with the Esk Head Belt, i.e. east of the Rakaia Terrane (Triassic-Late Permian) and west of the Pahau Terrane (Early Cretaceous-Late Jurassic). (author). 61 refs., 4 figs., 2 tabs.

  5. Geology, petrology, U-Pb (SHRIMP) geochronology of the Morrinhos granite - Paragua terrane, SW Amazonian craton: implications for the magmatic evolution of the San Ignacio orogeny

    Energy Technology Data Exchange (ETDEWEB)

    Franca, Ohana; Ruiz, Amarildo Salina; Sousa, Maria Zelia Aguiar de, E-mail:, E-mail:, E-mail: [Universidade Federal de Mato Grosso (UFMT), Cuiaba, MT (Brazil). Instituto de Ciencias Exatas e da Terra. Dept. de Geologia Geral; Batata, Maria Elisa Froes, E-mail: [Universidade Federal de Mato Grosso (UFMT), Cuiaba, MT (Brazil). Grupo de Pesquisa em Evolucao Crustal e Tectonica; Lafon, Jean-Michel [Universidade Federal do Para (GEOCIAM/UFPA), Belem, PR (Brazil). Inst. Nacional de Cencia e Tecnologia de Geociencias da Amazonia


    Morrinhos granite is a batholith body that is slightly elongated in the NNW direction and approximately 1,140 km{sup 2} long; it is located in the municipality of Vila Bela da Santissima Trindade of the state of Mato Grosso, Brazil, in the Paragua Terrane, Rondonian-San Ignacio Province, in the SW portion of the Amazonian Craton. This intrusion displays a compositional variation from tonalite to monzogranite, has a medium to coarse inequigranular texture and is locally porphyritic; biotite is the predominant mafic in one of the facies, and hornblende is predominant in the other, with both metamorphosed into the green schist facies. The studied rocks characterize an intermediate to acidic sequence that was formed by a subalkaline magmatism; the series is alkali-calcic to metaluminous to slightly peraluminous, and the rocks evolved through fractioned crystallization mechanisms. The structural data show two deformation phases represented by penetrative foliation (S{sub 1}) and open folds (D{sub 2}), and both phases were most likely related to the San Ignacio Orogeny. The geochronological (U-Pb SHRIMP) and isotopic (Sm-Nd) investigations of these rocks indicated a crystallization age of 1350±12Ma, T{sub DM} of approximately 1.77 Ga and εNd{sub (1.35}) with a negative value of -2.57, suggesting that their generation was related to a partial melting process of a Paleoproterozoic (Statherian) continental crust. The results herein indicate that the Morrinhos granite was generated in a continental magmatic arc in a late- to post-orogenic stage of the San Ignacio Orogeny, and it can be recognized as belonging to the Pensamiento Intrusive Suite. (author)

  6. Early Cretaceous U-Pb zircon ages for the Copiapó plutonic complex and implications for the IOCG mineralization at Candelaria, Atacama Region, Chile (United States)

    Marschik, Robert; Söllner, Frank


    Four of the major plutons in the vicinity of the Candelaria mine (470 Mt at 0.95% Cu, 0.22 g/t Au, 3.1 g/t Ag) and a dike-sill system exposed in the Candelaria open pit have been dated with the U-Pb zircon method. The new geochronological data indicate that dacite magmatism around 123 Ma preceded the crystallization of hornblende diorite (Khd) at 118 ± 1 Ma, quartz-monzonite porphyry (Kqm) at 116.3 ± 0.4 Ma, monzodiorite (Kmd) at 115.5 ± 0.4 Ma, and tonalite (Kt) at 110.7 ± 0.4 Ma. The new ages of the plutons are consistent with field relationships regarding the relative timing of emplacement. Plutonism temporally overlaps with the iron oxide Cu-Au mineralization (Re-Os molybdenite ages at ˜115 Ma) and silicate alteration (ages mainly from 114 to 116 and 110 to 112 Ma) in the Candelaria-Punta del Cobre district. The dated dacite porphyry and hornblende diorite intrusions preceded the ore formation. A genetic link of the metallic mineralization with the quartz-monzonite porphyry and/or the monzodiorite is likely. Both of these metaluminous, shoshonitic (high-K) intrusions could have provided energy and contributed fluids, metals, and sulfur to the hydrothermal system that caused the iron oxide Cu-Au mineralization. The age of the tonalite at 110.7 Ma falls in the same range as the late alteration at 110 to 112 Ma. Tonalite emplacement may have sustained existing or driven newly developed hydrothermal cells that caused this late alteration or modified 40Ar/39Ar and K/Ar systematic in some areas.

  7. U-Pb zircon geochronology of the Paleogene - Neogene volcanism in the NW Anatolia: Its implications for the Late Mesozoic-Cenozoic geodynamic evolution of the Aegean (United States)

    Ersoy, E. Yalçın; Akal, Cüneyt; Genç, Ş. Can; Candan, Osman; Palmer, Martin R.; Prelević, Dejan; Uysal, İbrahim; Mertz-Kraus, Regina


    The northern Aegean region was shaped by subduction, obduction, collision, and post-collisional extension processes. Two areas in this region, the Rhodope-Thrace-Biga Peninsula to the west and Armutlu-Almacık-Nallıhan (the Central Sakarya) to the east, are characterized by extensive Eocene to Miocene post-collisional magmatic associations. We suggest that comparison of the Cenozoic magmatic events of these two regions may provide insights into the Late Mesozoic to Cenozoic tectonic evolution of the Aegean. With this aim, we present an improved Cenozoic stratigraphy of the Biga Peninsula derived from a new comprehensive set of U-Pb zircon age data obtained from the Eocene to Miocene volcanic units in the region. The compiled radiometric age data show that calc-alkaline volcanic activity occurred at 43-15 Ma in the Biga Peninsula, 43-17 Ma in the Rhodope and Thrace regions, and 53-38 Ma in the Armutlu-Almacık-Nallıhan region, which are slightly overlapping. We discuss the possible cause for the distinct Cenozoic geodynamic evolution of the eastern and western parts of the region, and propose that the Rhodope, Thrace and Biga regions in the north Aegean share the same Late Mesozoic to Cenozoic geodynamic evolution, which is consistent with continuous subduction, crustal accretion, southwestward trench migration and accompanying extension; all preceded by the Late Cretaceous - Paleocene collision along the Vardar suture zone. In contrast, the Armutlu-Almacık-Nallıhan region was shaped by slab break-off and related processes following the Late Cretaceous - Paleocene collision along the İzmir-Ankara suture zone. The eastern and western parts of the region are presently separated by a northeast-southwest trending transfer zone that was likely originally present as a transform fault in the subducted Tethys oceanic crust, and demonstrates that the regional geodynamic evolution can be strongly influenced by the geographical distribution of geologic features on the

  8. U-Pb zircon geochronology of plutonism in the northern Peninsular Ranges batholith, southern California: Implications for the Late Cretaceous tectonic evolution of southern California (United States)

    Premo, Wayne R.; Morton, Douglas M.; Wooden, Joseph L.; Fanning, C. Mark


    Utilizing both sensitive high-resolution ion microprobe (SHRIMP) and conventional isotope dilution–thermal ionization mass spectrometry (ID-TIMS) methods, crystallization and/or emplacement ages have been obtained for a suite of Cretaceous intermediate-composition plutonic samples collected along a roughly E-W–trending traverse through the northern Peninsular Ranges batholith. Previously noted petrologic, mineralogic, and textural differences delineated four major zonations from west to east and raised the need for detailed geochemical and isotopic work. U-Pb zircon geochronology establishes that these zonations are essentially temporally separate. Mean 206Pb/238U ages date the three older zones from west to east at 126–107 Ma, 107–98 Ma, and 98–91 Ma. Despite petrologic differences, a relatively smooth progression of magmatism is seen from west to east. A fourth zone is defined by magmatism at ca. 85 Ma, which represents emplacement of deeper-level plutons east of the Eastern Peninsular Ranges mylonite zone in an allochthonous thrust sheet in the northeastern Peninsular Ranges batholith.The age data presented here differ slightly from those presented in earlier work for similar rocks exposed across the middle and southern portions of the Peninsular Ranges batholith in that our data define a relatively smooth progression of magmatism from west to east, and that the transition from western-type to eastern-type plutonism is interpreted to have occurred at ca. 98 Ma and not at ca. 105 Ma.The progressive involvement of older crustal components in the enrichment of eastern Peninsular Ranges batholith–type magma sources is documented by the occurrence of Proterozoic zircon inheritance within samples of the eastern part of the batholith.

  9. Timing of granitic magmatism in the northern Borborema Province, Brazil: a U Pb study of granitoids from the Alto Pajeú Terrain (United States)

    Bastos Leite, P. R.; Bertrand, J.-M.; de Lima, E. S.; Leterrier, J.


    The Alto Pajeú Terrain (APT) is a SW-NE trending fold belt in the Neoproterozoic Borborema Province (NE Brazil), formed by metasedimentary sequences interlayered with metavolcanosedimentary units, both intruded by granitic rocks of different compositions and ages. The tectonic evolution of the APT involves Mesoproterozoic and Neoproterozoic transtensional and contractional tectonic events. In this study, we present U-Pb zircon ages of five granitoids selected according to a generally accepted relative chronology: (a) the Tuparetama granite and Tuparetama migmatitic granite with low angle gneissic foliation represent syn-tangential rocks presumably related to a Transamazonian event; (b) the Amparo granite with high angle gneissic foliation related to the Brazilian/Pan-African event; and (c) the Tabira and Jabitacá post-strike-slip granites. The results obtained do not confirm the generally accepted chronology of events. Granites previously classified in different groups (Tuparetama, Amparo, and Jabitacá) belong to the same orogenic cycle (Brazilian). Large batholiths, previously suspected to have been emplaced after the strike-slip deformation, represent older crustal remnants within them. In each case they consist of particular rock types — an alkaline high-temperature granite (Tabira) and a 'granulite' (Tuparetama migmatitic granite). These older ages imply that pre-Brazilian crust-forming events such as the Transamazonian Orogeny (Tuparetama migmatitic granite estimated at ca. 2050 Ma) and Cariris Velhos event (Tabira granite at ca. 972 Ma) occurred in the APT, and their records survived the intense recycling which characterizes the Brazilian/Pan-African orogeny.

  10. Timing of the Late Paleozoic Ice Age: A Review of the Status Quo and New U-Pb Zircon Ages From Southern Gondwana (United States)

    Mundil, R.; Griffis, N. P.; Keller, C. B.; Fedorchuk, N.; Montanez, I. P.; Isbell, J.; Vesely, F.; Iannuzzi, R.


    Throughout the Carboniferous and Permian Late Paleozoic Ice Age (LPIA), glaciations in southern Gondwana exerted a profound influence on global climate and environment, ocean chemistry, and the nature of sedimentary processes. The LPIA is widely regarded as an analogue for Pleistocene glaciations. Our understanding of the latter, as well as the validity of predictions for the future global climate and environment, depends therefore on our ability to reconstruct the LPIA. A robust chronostratigraphic framework built on high precision/high accuracy geochronology is crucial for the reconstruction of events and processes that occurred during the LPIA, particularly in the absence of high-resolution terrestrial biostratigraphic constraints that apply to both near- and far-field proxy records. The occurrence of volcaniclastic layers containing primary volcanic zircon at many levels throughout southern Gondwana makes such a reconstruction feasible, but complications inevitably arise due to the mixing of older age components with primary volcanic crystals, as well as the potential of unrecognized open system behavior to produce spurious younger ages. These pitfalls cause age dispersion that may be difficult to interpret, or is unrecognized if low precision geochronological techniques are used, resulting in inaccurate radioisotopic ages. Our current efforts in the Parana Basin (Southern Brazil) and the Karoo Basin (South Africa/Namibia) concentrate on building a robust and exportable chronostratigraphic framework based on U-Pb zircon CA-TIMS ages with sub-permil level precision combined with Bayesian approaches for resolving the eruption age of dispersed age spectra to facilitate the reconstruction of glaciogenic processes through the Carboniferous-Permian transition, as well as their implications for global sea level, atmospheric pCO2 and ocean chemistry. We will also review currently available geochronological data from contemporaneous Australian successions and their

  11. U-Pb ages of uraniferous opals and implications for the history of beryllium, fluorine, and uranium mineralization at Spor Mountain, Utah (United States)

    Ludwig, K. R.; Lindsey, D.A.; Zielinski, R.A.; Simmons, K.R.


    The U-Pb isotope systematics of uraniferous opals from Spor Mountain, Utah, were investigated to determine the suitability of such material for geochronologic purposes, and to estimate the timing of uranium and associated beryllium and fluorine mineralization. The results indicate that uraniferous opals can approximate a closed system for uranium and uranium daughters, so that dating samples as young as ???1 m.y. should be possible. In addition, the expected lack of initial 230Th and 231Pa in opals permits valuable information on the initial 234U/238U to be obtained on suitable samples of ???10 m.y. age. The oldest 207Pb/235U apparent age observed, 20.8 ?? 1 m.y., was that of the opal-fluorite core of a nodule from a beryllium deposit in the Spor Mountain Formation. This age is indistinguishable from that of fission-track and K-Ar ages from the host rhyolite, and links the mineralization to the first episode of alkali rhyolite magmatism and related hydrothermal activity at Spor Mountain. Successively younger ages of 13 m.y. and 8-9 m.y. on concentric outer zones of the same nodule indicate that opal formed either episodically or continuously for over 10 m.y. Several samples of both fracture-filling and massive-nodule opal associated with beryllium deposits gave 207Pb/235U apparent ages of 13-16 m.y., which may reflect a restricted period of mineralization or perhaps an averaging of 21- and <13-m.y. periods of opal growth. Several samples of fracture-filling opal in volcanic rocks as young as 6 m.y. gave 207Pb/235U ages of 3.4-4.8 m.y. These ages may reflect hot-spring activity after the last major eruption of alkali rhyolite. ?? 1980.

  12. Petrogenesis, U-Pb and Sm-Nd geochronology of the Furna Azul Migmatite: partial melting evidence during the San Ignacio Orogeny, Paragua Terrane, SW Amazon Craton

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, Newton Diego Couto do; Ruiz, Amarildo Salina; Pierosan, Ronaldo; Lima, Gabrielle Aparecida de; Matos, Joao Batista; Lafon, Jean-Michel; Moura, Candido Augusto Veloso, E-mail:, E-mail:, E-mail:, E-mail:, E-mail:, E-mail:, E-mail: [Universidade Federal do Para (GEOCIAM/UFPA), Belem, PA (Brazil). Instituto Nacional de Ciencia e Tecnologia de Geociencias da Amazonia


    The Furna Azul Migmatite is a ∼10 km{sup 2} complex located in Pontes e Lacerda city, Mato Grosso, Brazil. It belongs to Paragua Terrane, limit with Rio Alegre Terrane, southeast of San Ignacio Province, in Amazon Craton. It consists of transitional metatexites with amphibolite enclaves and dioritic injections. The rocks were divided in residuum rich and leucosome rich; both have three deformation phases marked by folded stromatic layers affected by spaced foliation and metamorphosed in amphibolite facies, represented by garnet, biotite, sillimanite, and by the clinopyroxene in the enclaves. The metamorphic retrograde to greenschist is marked by formation of chlorite, muscovite and prehnite. Residuum-rich metatexites show higher CaO and Na{sub 2}O contents, separating them from K{sub 2}O, Ba and Rb enriched transitional metatexites. U-Pb on zircon and Sm-Nd whole-rocks dating indicates that the residuum-rich metatexite crystallized at 1436 ± 11 Ma, with a T{sub DM} age of 1.90 Ga and ε{sub Nd(1.43)} of -0.54, whereas the dioritic injection crystallized at 1341,7 ± 17 Ma with a T{sub DM} age of 1.47 Ga and ε{sub Nd(1.34)} of 3.39. These results indicate that the Furna Azul Migmatite protolith was formed during the San Ignacio Orogeny and was reworked during the same orogeny, as basement for collisional to post-magmatic granites from Pensamiento Intrusive Suite. (author)

  13. Stratigraphy, tectonics and detrital zircon U-Pb (LA-ICP-MS) geochronology of the Rio Preto Belt and northern Paramirim corridor, NE, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Alcantara, Davi da Costa Bezerra Gobira de; Uhlein, Alexandre; Caxito, Fabricio de Andrade; Pedrosa-Soares, Antonio Carlos, E-mail:, E-mail:, E-mail:, E-mail: [Universidade Federal de Minas Gerais (CPMTC/UFMG), Belo Horizonte, MG (Brazil). Instituto de Geociencias. Centro de Pesquisa Professor Manoel Teixeira da Costa; Dussin, Ivo, E-mail: [Universidade Estadual do Rio de Janeiro (UERJ), Rio de Janeiro, RJ (Brazil). Faculdade de Geologia


    Two important Proterozoic metasedimentary sequences, the Rio Preto and Santo Onofre Groups, crop out along the northwestern margin of the Sao Francisco craton and in northern Paramirim corridor, respectively. The Rio Preto Group, involved in the eponymous fold-thrust belt along the northwestern cratonic boundary, comprises the Formosa (garnet schist, quartz schist, quartzite, chlorite-sericite schist and ferriferrous quartz schist) and Canabravinha (quartzite, micaceous quartzite, metarhytmite, phylite, schist and metaturbidite) formations. The Santo Onofre Group occurs exclusively in the Paramirim corridor, and is composed of quartzite and minor carbonaceous or Mn-rich phylite. These units record sedimentation in shallow to deep-water marine settings related to rift basins, and were deformed and metamorphosed under green schist facies conditions during the Brasiliano orogeny. Here we present 427 new detrital zircon U-Pb ages, which constrain the maximum depositional ages of ca. 971 Ma for the Santo Onofre Group, ca. 912 Ma for the Canabravinha Formation, and ca. 65 Ma for the Formosa Formation of the Rio Preto Group. Our data suggests that the Santo Onofre and the Rio Preto Groups accumulated in two distinct basin settings. The latter, composed mostly of sandy rocks, would represent a relatively stable, shallow-marine shelf environment. The Rio Preto Group, with metadiamictite, quartzite, pelitic and rhythmitic rocks, represents a shallow to deep marine environment influenced by gravity flows. Both groups were probably deposited in the Late Tonian, and are potential correlatives of the lower (pre-glacial) units of the Macaubas Group of the Aracuai belt. (author)

  14. Carboniferous-Permian volcanic evolution in Central Europe—U/Pb ages of volcanic rocks in Saxony (Germany) and northern Bohemia (Czech Republic) (United States)

    Hoffmann, Uwe; Breitkreuz, Christoph; Breiter, Karel; Sergeev, Sergey; Stanek, Klaus; Tichomirowa, Marion


    Nine SHRIMP U/Pb ages on zircon and two Pb/Pb single zircon ages have been determined from Late Paleozoic volcanic rocks from Saxony and northern Bohemia. Samples came from the Teplice-Altenberg Volcanic Complex, the Meissen Volcanic Complex, the Chemnitz Basin, the Döhlen Basin, the Brandov-Olbernhau Basin, and the North Saxon Volcanic Complex. The Teplice-Altenberg Volcanic Complex is subdivided into an early Namurian phase (Mikulov Ignimbrite, 326.8 ± 4.3 Ma), thus older than assumed by previous studies, and a late caldera-forming phase (Teplice Ignimbrite, 308.8 ± 4.9 Ma). The age of the latter, however, is not well constrained due to a large population of inherited zircon and possible hydrothermal overprint. The Leutewitz Ignimbrite, product of an early explosive volcanic episode of the Meissen Volcanic Complex yielded an age of 302.9 ± 2.5 Ma (Stephanian A). Volcanic rocks intercalated in the Brandov-Olbernhau Basin (BOB, 302 ± 2.8 Ma), Chemnitz Basin (CB, 296.6 ± 3.0 Ma), Döhlen Basin (DB, 296 ± 3.0 Ma), and the North Saxon Volcanic Complex (NSVC, c. 300-290 Ma) yielded well-constrained Stephanian to Sakmarian ages. The largest Late Paleozoic ignimbrite-forming eruption in Central Europe, the Rochlitz Ignimbrite, has a well-defined middle Asselian age of 294.4 ± 1.8 Ma. Ages of palingenic zircon revealed that the Namurian-Westphalian magmatism assimilated larger amounts of crystalline basement that formed during previous Paleozoic geodynamic phases. The Precambrian inherited ages support the chronostratigraphic structure assumed for the Saxo-Thuringian Zone of the Variscan Orogen. The present results help to improve the chronostratigraphic allocation of the Late Paleozoic volcanic zones in Central Europe. At the same time, the radiometric ages have implications for the interbasinal correlation and for the geodynamic evolution of the Variscan Orogeny.

  15. New U-Pb ages in the Diablillos Intrusive Complex, Southern Puna, Argentina: A long magmatic event in the Paleozoic Arc, SW Gondwana

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz, Agustin; Hauser, Natalia [Universidade de Brasilia (UnB), DF (Brazil). Instituto de Geociencias. Lab. de Geocronologia; Becchio, Raul; Nieves, Alexis; Suzano, Nestor [Universidad Nacional de Salta (UNSa)-CONICET, Salta (Argentina)


    The Puna geological region comprises Salta, Jujuy and Catamarca provinces, northwestern Argentina. This 4000 meter above sea level high-plateau region lies between the Central Argentinian Andes. The Puna basement in the central Andes consists of Proterozoic–Paleozoic metamorphic rocks and granitoids. Diverse authors, proposed different models to explain the origin of the basement, where two orogenic events are recognized: the Pampean (Upper Precambrian–Lower Cambrian) and Famatinian (Upper Cambrian–Lower Silurian) (e.g. Ramos et al., 1986; Ramos, 1988; Loewy et al., 2004; for opposite points of view see Becchio et al., 1999; Bock et al., 2000; Buttner et al., 2005). Hence, Lucassen et al. (2000) proposed for the Central Andean basement, an evolution in a mobile belt, where the Pampean and Famatinian cycles are not distinct events but, they are one single, non-differentiable event from 600 to 400 Ma. The mobile belt culminated in low-P/ high-T metamorphism at approximately 525-500 Ma. Then, these were followed by a long-lasting high-thermal gradient regime in the mid-crust until Silurian times. Becchio et al., (2011) defined the Diablillos Intrusive Complex (CID, by its Spanish name), emplaced in the Inca Viejo Range. This range splits the Salares Ratones-Centenario with the Salar Diablillos (Fig.1). This Complex is located in the Eastern Magmatic Belt, Southern Puna, Argentina. Here we present new zircons U-Pb ages by LA-MC-ICPMS in the Diablillos Intrusive Complex, contributing to understanding the magmatic event in the lower Paleozoic arc, SW Gondwana. (author)

  16. U-Pb zircon geochronology of the Paleoproterozoic Tagragra de Tata inlier and its Neoproterozoic cover, western Anti-Atlas, Morocco (United States)

    Walsh, G.J.; Aleinikoff, J.N.; Benziane, F.; Yazidi, A.; Armstrong, T.R.


    New U-Pb zircon data obtained by sensitive high resolution ion microprobe (SHRIMP) from the Tagragra de Tata inlier in the western Anti-Atlas, Morocco establish Paleoproterozoic ages for the basement schists, granites, and metadolerites, and a Neoproterozoic age for an ignimbrite of the Ouarzazate Series in the cover sequence. The age of interbedded felsic metatuff in the metasedimentary and metavolcanic sequence of the basement schists is 2072 ?? 8 Ma. This date represents: (1) the first reliable age from the metasedimentary and metavolcanic sequence; (2) the oldest reliable age for the basement of the Anti-Atlas; (3) the first date on the timing of deposition of the sediments on the northern edge of the Paleoproterozoic West African craton; (4) a lower age limit on deformation during the Eburnean orogeny; and (5) the first date obtained from the non-granitic Paleoproterozoic basement of Morocco. Ages of 2046 ?? 7 Ma (Targant granite) and 2041 ?? 6 Ma (Oudad granite) support earlier interpretations of a Paleoproterozoic Eburnean igneous event in the Anti-Atlas. The granites post-date the Eburnean D1 deformation event in the Paleoproterozoic schist sequence, and place a ???2046 Ma limit on short-lived Eburnean deformation in the area. Cross-cutting metadolerite is 2040 ?? 6 Ma; this is the first date from a metadolerite in the western Anti-Atlas. All of the dolerites in the area post-date emplacement of the two granites and the new age constrains the onset of late- or post-Eburnean extension. Ignimbrite of the Ouarzazate Series, immediately above the Paleoproterozoic basement is 565 ?? 7 Ma. This Neoproterozoic age agrees with ages of similar volcanic rocks elsewhere from the Ouarzazate Series. The date also agrees with the ages of associated hypabyssal intrusions, and marks the second and final stage of Pan-African orogenic activity in the western Anti-Atlas. ?? 2002 Elsevier Science B.V. All rights reserved.

  17. Stratigraphy, tectonics and detrital zircon U-Pb (LA-ICP-MS geochronology of the Rio Preto Belt and northern Paramirim corridor, NE, Brazil

    Directory of Open Access Journals (Sweden)

    Davi da Costa Bezerra Gobira de Alcântara

    Full Text Available ABSTRACT: Two important Proterozoic metasedimentary sequences, the Rio Preto and Santo Onofre Groups, crop out along the northwestern margin of the São Francisco craton and in northern Paramirim corridor, respectively. The Rio Preto Group, involved in the eponymous fold-thrust belt along the northwestern cratonic boundary, comprises the Formosa (garnet schist, quartz-mica schist, quartzite, chlorite-sericite schist and ferriferous quartz schist and Canabravinha (quartzite, micaceous quartzite, metarhytmite, phylite, schist and metaturbidite formations. The Santo Onofre Group occurs exclusively in the Paramirim corridor, and is composed of quartzite and minor carbonaceous or Mn-rich phylite. These units record sedimentation in shallow to deep-water marine settings related to rift basins, and were deformed and metamorphosed under greenschist facies conditions during the Brasiliano orogeny. Here we present 427 new detrital zircon U-Pb ages, which constrain the maximum depositional ages of ca. 971 Ma for the Santo Onofre Group, ca. 912 Ma for the Canabravinha Formation, and ca. 965 Ma for the Formosa Formation of the Rio Preto Group. Our data suggests that the Santo Onofre and the Rio Preto Groups accumulated in two distinct basin settings. The latter, composed mostly of sandy rocks, would represent a relatively stable, shallow-marine shelf environment. The Rio Preto Group, with metadiamictite, quartzite, pelitic and rhythmitic rocks, represents a shallow to deep marine environment influenced by gravity flows. Both groups were probably deposited in the Late Tonian, and are potential correlatives of the lower (pre-glacial units of the Macaúbas Group of the Araçuaí belt.

  18. Tracking the exhumation of a Pliocene (U)HP terrane: U-Pb and trace-element constraints from zircon, D'Entrecasteaux Islands, Papua New Guinea (United States)

    DesOrmeau, Joel W.; Gordon, Stacia M.; Little, Timothy A.; Bowring, Samuel A.


    Domal structures within the D'Entrecasteaux Islands of eastern Papua New Guinea expose ultrahigh-pressure (UHP) Pliocene (5.6-4.6 Ma) eclogites and evidence for partial melting. To better interpret the (U)HP exhumation history, U-Pb geochronology and trace-element abundances were determined in zircon from variably deformed host gneiss and crystallized melt (leucosomes, sills, dikes, and plutons) from the Goodenough and Normanby Domes by ID-TIMS (isotope-dilution thermal ionization mass spectrometry) and ICP-MS (inductively coupled plasma mass spectrometry), respectively, to constrain the timing of melt crystallization and deformation relative to UHP metamorphism. Zircons extracted from orthogneiss and deformed granodiorite sills of Normanby Dome, located ˜40 km southeast of the UHP eclogite, record HP metamorphism from 5.66 ± 0.02 to 5.04 ± 0.07 Ma, and melt crystallization at ˜4.1 Ma. Strongly deformed, layer-parallel leucosomes from Goodenough Dome, ˜20 km northwest of the UHP eclogite, began to crystallize by 3.85 ± 0.02 Ma. These dates indicate that melt crystallization began in the Goodenough and Normanby Domes within ˜0.75 m.y. of (U)HP metamorphism. The ID-TIMS dates from the orthogneiss and crystallized melt show that exhumation and cooling of the (U)HP rocks in the PNG terrane began first in the east, within Normanby Dome, then to the west, in the Goodenough Dome ˜1 m.y. later, and finally the middle dome rocks, exposed within the Mailolo Dome, cooled ˜2 m.y. after exhumation of Normanby Dome. All domes reveal synchronous crystallization of late, nondeformed melts, and final extension-driven exhumation by 1.82 ± 0.03 Ma.

  19. A Novel in situ Trigger Combination Method

    International Nuclear Information System (INIS)

    Buzatu, Adrian; Warburton, Andreas; Krumnack, Nils; Yao, Wei-Ming


    Searches for rare physics processes using particle detectors in high-luminosity colliding hadronic beam environments require the use of multi-level trigger systems to reject colossal background rates in real time. In analyses like the search for the Higgs boson, there is a need to maximize the signal acceptance by combining multiple different trigger chains when forming the offline data sample. In such statistically limited searches, datasets are often amassed over periods of several years, during which the trigger characteristics evolve and their performance can vary significantly. Reliable production cross-section measurements and upper limits must take into account a detailed understanding of the effective trigger inefficiency for every selected candidate event. We present as an example the complex situation of three trigger chains, based on missing energy and jet energy, to be combined in the context of the search for the Higgs (H) boson produced in association with a W boson at the Collider Detector at Fermilab (CDF). We briefly review the existing techniques for combining triggers, namely the inclusion, division, and exclusion methods. We introduce and describe a novel fourth in situ method whereby, for each candidate event, only the trigger chain with the highest a priori probability of selecting the event is considered. The in situ combination method has advantages of scalability to large numbers of differing trigger chains and of insensitivity to correlations between triggers. We compare the inclusion and in situ methods for signal event yields in the CDF WH search.

  20. U-Pb (LA-ICPMS) zircon ages and Nd isotopes for granitoids of the Tamboril-Santa Quiteria Complex, Ceara Central Domain: implication for neoproterozoic syncollisional magmatism in north Borborema Province, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Felipe Grandjean da; Araujo, Carlos Eduardo Ganade de; Vasconcelos, Antonio Maurilio, E-mail:, E-mail:, E-mail: [Servico Geologico do Brasil (CPRM), Fortaleza, CE (Brazil); Amaral, Wagner da Silva, E-mail: [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Departamento de Geologia; Rodrigues, Joseneusa Brilhante, E-mail: [Servico Geologico do Brasil (CPRM), Brasilia, DF (Brazil)


    The Tamboril-Santa Quiteria Complex (TSQC) is one of the largest Neoproterozoic plutonic manifestations in the north Borborema Province (NE Brazil). It represents an anatectic/igneous association characterized by a number of magmatic pulses that occurred in the 650-610 Ma interval. In this paper, we present U-Pb (LA-MC-ICP-MS) zircon ages and Nd isotopes for quartz monzonite and quartz diorites of the southern part of TSQC. The quartz monzonite belong to a hybrid granitoid association, including monzonite, syenites and quartz syenites, all with abundant mafic magmatic enclaves. A quartz monzonite sample yielded a U-Pb zircon age of 634 {+-} 10 Ma and a TDM age of 2.69 Ga. The quartz diorites are much more homogeneous in composition and yielded a U-Pb zircon age of 618 {+-} 23 Ma and a TDM age of 2.19 Ga. The presence of coeval mantle-derived magmatism and diatexites (crustal anatexis) post-dating high-pressure metamorphism (ca. 650 Ma), and together with high-temperature metamorphism (ca. 630-610 Ma), suggests that this large magmatic manifestation evolved in a collisional setting, probably related to slab break off during the Western Gondwana amalgamation. (author)

  1. Geochronology of granulite, charnockite and gneiss in the poly-metamorphosed Gaozhou Complex (Yunkai massif), South China: Emphasis on the in-situ EMP monazite dating (United States)

    Chen, Cheng-Hong; Liu, Yung-Hsin; Lee, Chi-Yu; Xiang, Hua; Zhou, Han-Wen


    The in-situ EMP (electron microprobe) monazite age dating performed directly in the polished sections, in addition to the conventional U-Pb zircon and EMP monazite age dating on grains from heavy mineral concentrates, has been applied to the granulite, charnockite and gneiss in the Gaozhou Complex of the Yunkai massif in South China. While the conventional dating systems all give Caledonian ages, the in-situ EMP monazite ages provide more information to reveal not only detailed age groups pertaining to the Caledonian orogeny but also traces of later thermal events overprinting these rocks. For granulites, although some monazites present zoning (concentric, patchy and complex) in the BSE images, no discernable age differences are observed. Resetting of the Th-U-Pb monazite dating system under the high temperature condition could be the reason. Ages of homogeneous monazite in garnet porphyroblast (ca. 440 Ma) of the garnet-cordierite granulite that match nicely with the U-Pb zircon ages are systematically older than those in the matrix (ca. 430 Ma). The same case of two age groups is also present in the orthopyroxene-biotite granulite as revealed by monazite inclusions in plagioclase and orthopyroxene and those in quartz, respectively. For charnockites, despite similar ages of ca. 430 Ma are given by monazite in biotite and zircon in the rock, significant younger ages are obtained from monazites with particular features. Relict monazites with a breakdown texture to form successive layers of apatite and allanite in the rim as well as those which are close to the biotite-chlorite microvein always show a similar age of ca. 230 Ma. Moreover, tiny monazites in close association with the garnetiferous corona mainly surrounding orthopyroxene give rise to another age group around 370 Ma. For gneissic rocks, monazites enclosed by quartz give 434 Ma and those setting in the chlorite-epidote microvein of a paragneiss yield 237 Ma, consistent with the U-Pb zircon core-rim age

  2. The Pan-African Kekem gabbro-norite (West-Cameroon), U-Pb zircon age, geochemistry and Sr-Nd isotopes: Geodynamical implication for the evolution of the Central African fold belt (United States)

    Kwékam, Maurice; Affaton, Pascal; Bruguier, Olivier; Liégeois, Jean-Paul; Hartmann, Gerald; Njonfang, Emmanuel


    The Kekem shoshonitic gabbro-norite association is part of the high-K calc-alkaline (HKCA) post-collisional magmatism, a major feature of the Pan-African Belt in Cameroon. LA-ICP-MS U-Pb zircon analyses provide an age of 576 ± 4 Ma for the Kekem complex. This age is interpreted as dating the emplacement of the massif during the waning stage of the Pan-African orogeny. The latter is related to dextral movements along the Central Cameroon Shear Zone (CCSZ). The REE patterns display enriched LREE (LaN/YbN = 14.2-23.5) while HREE present a nearly flat profile (DyN/YbN = 1.3-1.7), and the La/Sm and Sm/Yb ratios led to propose that the Kekem gabbro-norites have been derived from the partial melting of a garnet-spinel lherzolite mantle source. The negative Nb-Ta and Ti anomalies and the positive Pb anomalies indicate that this mantle source was modified by contribution of a subduction-related material. The low Ce/Pb (2.6-10.4) and Th/Yb ratios associated to high Ba/La ratios, indicate that source enrichment could be related to slab derived fluids. As a whole, the Kekem geochemical features suggest that primary gabbro-noritic magmas derived from a subduction-modified mantle source (metasomatised lithospheric mantle). Moderately high 86Sr/87Sr initial ratios (0.7068-0.7082), low ɛNd (-5 to -9) and old Nd TDM model ages (1.6-1.8 Ga) are interpreted to result from contamination of Neoproterozoic mantle by the Paleoproterozoic crust. The ca. 576 Ma movements along the CCSZ are related to a Neoproterozoic metacratonization of the northern margin of the Congo craton during the Pan-African orogeny. This metacratonization led to vertical planar lithospheric delamination along lithospheric transcurrent faults, asthenospheric uprise and partial melting of the Paleoproterozoic lithospheric mantle.

  3. In situ microbial filter used for bioremediation (United States)

    Carman, M. Leslie; Taylor, Robert T.


    An improved method for in situ microbial filter bioremediation having increasingly operational longevity of an in situ microbial filter emplaced into an aquifer. A method for generating a microbial filter of sufficient catalytic density and thickness, which has increased replenishment interval, improved bacteria attachment and detachment characteristics and the endogenous stability under in situ conditions. A system for in situ field water remediation.

  4. Aplicação de análise multivariada aos dados de espectroscopia no infravermelho obtidos na polimerização in situ de adesivo à base de cianoacrilato Multivariate analyses on FT-IR data of polymerization in situ of cyanoacrylate adhesive

    Directory of Open Access Journals (Sweden)

    Francisco A. A. Miranda


    Full Text Available A polimerização de adesivo à base de cianoacrilato foi acompanhada por FT-IR durante 30 minutos. A aplicação das técnicas de estatística multivariada (análise de agrupamento hierárquico e a análise dos componentes principais aos espectros de infravermelho, permitiram uma melhor identificação das diferenças espectrais entre monômero e polímero e possibilitou, também, inferir que a quantidade de monômero e do mero no polímero se eqüivalem com seis minutos de polimerização. A técnica de infravermelho mostrou-se uma ferramenta adequada para o acompanhamento da cinética de reação de adesivo à base de cianoacrilato, que torna-se ainda mais eficiente quando associada às técnicas de estatística multivariada.The polymerization of a cyanoacrylate adhesive was accompanied by FT-IR during 30 minutes. The application of multivariate statistics techniques (Hierarchical Clusters Analyses and Principal Components on infrared spectra allowed a better identification of spectral differences between monomer and polymer and also permitted to infer that the quantity of monomer and of mer of the polymer are equal in six minutes polymerization (half-life. The infrared technique appeared as an apropriate tool for observing the kinetics of cyanoacrylate adhesive reaction, which becomes even more efficient when associated to multivariate statistics techniques.

  5. Triplex in-situ hybridization (United States)

    Fresco, Jacques R.; Johnson, Marion D.


    Disclosed are methods for detecting in situ the presence of a target sequence in a substantially double-stranded nucleic acid segment, which comprises: a) contacting in situ under conditions suitable for hybridization a substantially double-stranded nucleic acid segment with a detectable third strand, said third strand being capable of hybridizing to at least a portion of the target sequence to form a triple-stranded structure, if said target sequence is present; and b) detecting whether hybridization between the third strand and the target sequence has occured.

  6. In situ management and domestication of plants in Mesoamerica. (United States)

    Casas, Alejandro; Otero-Arnaiz, Adriana; Pérez-Negrón, Edgar; Valiente-Banuet, Alfonso


    Ethnobotanical studies in Mexico have documented that Mesoamerican peoples practise systems of in situ management of wild and weedy vegetation directed to control availability of useful plants. In situ management includes let standing, encouraging growing and protection of individual plants of useful species during clearance of vegetation, which in some cases may involve artificial selection. The aim of this study was to review, complement and re-analyse information from three case studies which examined patterns of morphological, physiological and genetic effects of artificial selection in plant populations under in situ management in the region. Information on wild and in situ managed populations of the herbaceous weedy plants Anoda cristata and Crotalaria pumila, the tree Leucaena esculenta subsp. esculenta and the columnar cacti Escontria chiotilla, Polaskia chichipe and Stenocereus stellatus from Central Mexico was re-analysed. Analyses compared morphology and frequency of morphological variants, germination patterns, and population genetics parameters between wild and managed in situ populations of the species studied. Species of columnar cacti are under different management intensities and their populations, including cultivated stands of P. chichipe and S. stellatus, were also compared between species. Significant differences in morphology, germination patterns and genetic variation documented between wild, in situ managed and cultivated populations of the species studied are associated with higher frequencies of phenotypes favoured by humans in managed populations. Genetic diversity in managed populations of E. chiotilla and P. chichipe is slightly lower than in wild populations but in managed populations of S. stellatus variation was higher than in the wild. However, genetic distance between populations was generally small and influenced more by geographic distance than by management. Artificial selection operating on in situ managed populations of the

  7. U-Pb Detrital Zircon Geochronologic Constraints on Depositional Age and Sediment Source Terrains of the Late Paleozoic Tepuel-Genoa Basin (United States)

    Griffis, N. P.; Montanez, I. P.; Isbell, J.; Gulbranson, E. L.; Wimpenny, J.; Yin, Q. Z.; Cúneo, N. R.; Pagani, M. A.; Taboada, A. C.


    The late Paleozoic Ice Age (LPIA) is the longest-lived icehouse of the Phanerozoic and the only time a metazoan dominated and vegetated world transitioned from an icehouse climate into a greenhouse. Despite several decades of research, the timing, extent of glaciation and the location of ice centers remain unresolved, which prohibits reconstruction of ice volume. The Permo-Carboniferous sediments in the Tepuel-Genoa Basin, Patagonia contains a near complete record of sedimentation from the lower Carboniferous through lower Permian. Outsized clasts, thin pebble-rich diamictites and slumps represent the last of the late Paleozoic glacially influenced deep-water marine sediments in the Mojón de Hierro Fm. and the Paleozoic of Patagonia. U-Pb analysis of detrital zircons separated from slope sediments reveal groupings (20 myr bins, n≥5 zircons) with peak depositional ages of 420, 540 to 660 and 1040 Ma. Zircon age populations recovered from the Mojón de Hierro Fm. compare well with bedrock ages of the Deseado Massif of SE Patagonia, suggesting this may be a potential source of sediments. The maximum depositional age of the sediments is 306.05 ± 3.7 Ma (2σ) as determined by the median age of the two youngest concordant zircons that overlap in error. The youngest zircon from the analysis yields a 238U/206Pb age of 301.3 ± 4.5 Ma (2σ; MSWD = 2.3). Younger zircons from the analysis compare well with the age of granite bedrock exposed along the basin margin to the E-NE suggesting they may reflect a more proximal source. These data, which indicate a maximum age of late Carboniferous for the Mojón de Hierro Fm, provide the first geochemical constraints for the timing of final deposition of glaciomarine sediments in the Tepuel-Genoa Basin, and contributes to the biostratigraphic correlation of the late Paleozoic succession in Patagonia with other key LPIA basins that has thus far been hindered by faunal provincialism.

  8. Ordovician metamorphism in the Sierras Pampeana: New U-Pb SHRIMP ages in Central-East Valle Fertil and the Velasco batholith

    International Nuclear Information System (INIS)

    Rapela, C.W; Pankhurst, R.J; Baldo, E; Casquet, C.; Galindo, C; Fanning, C.M; Saavedra, J


    Magmatic activity, during which extensive I- and S-type granitoids were emplaced in the Famatinian belt and synchronous, though sparse, TTG plutons in the Pampean belt, preceded the accretion of the Precordillera terrane (PT) to the proto-Pacific margin of South America. These three types of granitoid were mainly emplaced in Early Ordovician times (470 90 Ma, Pankhurst et al., 2001). However, little is known about the timing and characteristics of regional metamorphism during the Famatinian orogeny. A key transect in this study is at 30 o 30 31 o 40 , where Grenvillian basement units of the PT are separated by the Bermejo valley from high-grade rocks of the Sierra de Valle Fertil. Geochronological studies have been carried out in the Sierra de Pie de Palo (PT), on the western side of the transect, by Ramos et al. (1998) and Casquet et al. (2001). We are now able to characterise metamorphism on the eastern side of the transect, i.e. the Gondwana margin. To this end we are presenting new U-Pb SHRIMP geochronological studies of western Sierra de Valle Fertil (Baldo et al., 2001), and central-eastern Sierra de Valle Fertil and Sierra de Velasco (this paper). The geology of the central and eastern sectors of the Sierra de Valle Fertil is dominated by a metaluminous sequence of hornblende-biotite tonalites/granodiorites, and suites of troctolitic, noritic and hornblende gabbros emplaced in high-grade metapelites, marbles and amphibolites. The locations of the three samples selected for the isotopic study SVF-3131 is a garnet migmatite composed of Grt + Bt + Pl + Qtz, with Zrn, Mnz, Ap as accessories (mineral symbols after Kretz, 1983). SVF-573 is a cordierite-garnet diatexitic migmatite: Crd (Mg 77-79) + Grt (Alm 57-69, Py 27-32) + Bt (TiO 2 = 3.2-4.5%) + Sil + Pl (An33-35) + Kfs + Qtz; accessories are Spl (included in Grt, ZnO 9-11%), Zrn, Mag, Ilm, Mnz. The widespread occurrence of Crd and Spl in the high-grade rocks indicates that anatexis in central-east Valle Fertil

  9. Electron Backscatter Diffraction (EBSD) Analysis and U-Pb Geochronology of the Oldest Lunar Zircon: Constraining Early Lunar Differentiation and Dating Impact-Related Deformation (United States)

    Timms, Nick; Nemchin, Alexander; Grange, Marion; Reddy, Steve; Pidgeon, Bob; Geisler, Thorsten; Meyer, Chuck


    The evolution of the early moon was dominated by two processes (i) crystallization of the Lunar Magma Ocean (LMO) and differentiation of potassium-rare earth element-phosphorous-rich residual magma reservoir referred to as KREEP, and (ii) an intense meteorite bombardment referred to as lunar cataclysm . The exact timing of these processes is disputed, and resolution relies on collection and interpretation of precise age data. This study examines the microstructure and geochronology of zircon from lunar impact breccias collected during the Apollo 17 mission. A large zircon clast within lunar breccia 72215,195 shows sector zoning in optical microscopy, cathodoluminescence (CL) imaging and Raman mapping, and indicates that it was a relict fragment of a much larger magmatic grain. Sensitive high resolution ion microprobe (SHRIMP) U-Pb analysis of the zircon shows that U and Th concentration correlate with sector zoning, with darkest CL domains corresponding with high-U and Th (approx.150 and approx.100 ppm respectively), and the brightest-CL sectors containing approx.30-50 ppm U and approx.10-20 ppm Th. This indicates that variations in optical CL and Raman properties correspond to differential accumulation of alpha-radiation damage in each sector. Electron backscatter diffraction (EBSD) mapping shows that the quality of electron backscatter patterns (band contrast) varies with sector zoning, with the poorest quality patterns obtained from high-U and Th, dark-CL zones. EBSD mapping also reveals a deformation microstructure that is cryptic in optical, CL and Raman imaging. Two orthogonal sets of straight discrete and gradational low-angle boundaries accommodate approx.12 misorientation across the grain. The deformation bands are parallel to the crystallographic {a}-planes of the zircon, have misorientation axes parallel to the c-axis, and are geometrically consistent with formation by dislocation creep associated with {010} slip. The deformation bands are unlike curved

  10. Neoproterozoic anorogenic magmatism in the Southern Bahia Alkaline Province of NE Brazil: U-Pb and Pb-Pb ages of the blue sodalite syenites (United States)

    Rosa, Maria de Lourdes da Silva; Conceição, Herbet; Macambira, Moacir José Buenano; Galarza, Marco Antonio; Cunha, Mônica Pringsheim; Menezes, Rita Cunha Leal; Marinho, Moacyr Moura; Filho, Basílio Elesbão da Cruz; Rios, Débora Correia


    Blue sodalite syenite is a rare rock, and the Southern Bahia Alkaline Province (SBAP) is the only place in Brazil where economic deposits are found. This province forms part of the Archaean to Paleoproterozoic São Francisco craton, and contains a few batholiths, a large number of stocks and hundreds of dykes. Its southern part lies close to the tectonic contact between the craton and the Neoproterozoic Araçuaí mobile melt. Blue sodalite-bearing syenites are found in almost all the igneous bodies of the SBAP as dykes or pegmatitic masses hosted by nepheline syenite. Economically viable quantities for the production of dimension stones are found only in the Floresta Azul alkaline complex, the Itaju do Colônia and Rio Pardo stocks and the Itarantim batholith.U-Pb ages obtained for titanite from Itaju do Colônia (732 ± 8 Ma) and Rio Pardo (714 ± 8) and Pb-Pb evaporation ages of zircon from Floresta Azul (696 ± 3 Ma) and Itarantim (722 ± 5 Ma). The geochronology of the SBAP shows that the anorogenic alkaline magmatism persisted for at least 58 Ma, demonstrating an extensional tectonic environment in the southern part of the São Francisco craton at this time. The data show that the rift phase which preceded the formation of the Araçuaí orogen was active until at least 700 Ma. The reported ages are similar to those found for the nepheline syenite host bodies, which supports the conclusions of the previous petrologic study demonstrating that blue sodalite is formed during the crystallization of these bodies. Two different processes are involved. In the magmatic process, sodalite occurs as disseminated and interstitial crystals among alkali feldspar crystals, and is associated with calcite and cancrinite formed by destabilization of nepheline. In the metasomatic process, discontinuous bands of sodalite are in sharp contact with nepheline syenite pegmatite, and its crystal aggregates often contain relict textures of nepheline and albite been replaced by sodalite.

  11. Formation And Exhumation Of High Pressure Metamorphic Rocks From Oman: New Constraints From U-Pb Dating Of Zircon And Rutile (United States)

    El-Shazly, A. K.; Walker, J. D.


    Basement and continental shelf units structurally underlying the Semail ophiolite in Saih Hatat, NE Oman were metamorphosed under high pressure, low temperature (high P/T) conditions, and occur in two plates. The lower plate consists of eclogite facies rocks that grade westward into garnet blueschists and crossite epidote schists. The upper plate consists of thrust sheets of lower grade metasedimentary and metavolcanic rocks formed under pumpellyite - actinolite to lawsonite albite facies conditions. The eclogite facies rocks had a clockwise P-T path, with peak conditions of 12 12 kbar to ˜ 4 kbar, and a stage of near isobaric cooling followed by cooling and decompression. High P/T rocks from the upper plate are also characterized by clockwise P-T paths with a segment of near isothermal decompression, and reached peak conditions that ranged from ˜ 310° C, P pile. A distinct pressure gap of > 3 kbar results from the juxtaposition of the lower and upper plates. U-Pb dating of zircon and rutile grains from two lower plate blueschists yield ages ranging from Proterozoic to Late Cretaceous: data cluster near a Late Creatceous age on the younger end of the array and spread to Mesoproterozoic values at the older end. A weighted mean of the 238U/206Pb ages from the youngest and most concordant fractions (one zircon and 2 rutile crystals) yields 80.1 +/- 5 Ma. These results are consistent with Rb/Sr isochron ages of 78 +/- 2 Ma obtained using phengite, clinopyroxene, and epidote from seven eclogite facies samples, and suggest that high P/T metamorphism in Saih Hatat was almost coeval with the emplacement of the Semail ophiolite. We conclude that the lower plate blueschists and eclogites formed by intracontinental thrusting and subduction of the thinned leading edge of the Oman continental margin in an east dipping subduction zone. The upper plate rocks which were part of the hanging wall of this subduction zone, were metamorphosed by tectonic loading by the ophiolite

  12. Zircon U-Pb geochronology and Hf isotopes from the Sanbagawa Metamorphic Belt, Western Shikoku, Japan: evidence for the prevalence for the Late Cretaceous protoliths (United States)

    Walia, Monika; Knittel, Ulrich; Suzuki, Shigeyuki; Nishizaka, Naoki; Kimura, Kazunari; Lee, Yuan-Hsi; Lee, Hao-Yang


    Sanbagawa Metamorphic Belt lies to the south of Median Tectonic Line and is exposed on Kyushu, Shikoku and Honshu Islands in Japan. This belt has been the focus of many studies in recent years since the discovery of young detrital zircon grains (80 - 95 Ma). Samples for this study come from a 2000 m bore hole from north-western Shikoku drilled in an area considered to be part of the Jurassic to Early Cretaceous part of the Sanbagawa Belt. Dating of single zircon grains using the LA-ICP-MS U-Pb dating method shows that all but one sample contain zircons younger than 100 Ma and thus the protoliths are younger than the previously accepted age of metamorphism of the Sanbagawa Belt at ca. 110 Ma. The single sample that contains only zircons dated at 136 ± 3 Ma, apparently is of volcanic origin and could be a clast representing the source of 130-140 Ma zircons of the sample taken about 120m above this sample. In addition, three surface samples were analyzed. Two of these also contain zircons younger than 100 Ma, whereas the third sample contains only zircons older than 159 Ma. Hf-isotope values for the younger age group 82-116 Ma, ɛHf(T) range from -2.4 to +9.6. Zircon grains of 127-146 Ma ages have more positive ɛHf(T) values of +11.5 to +19.0 indicating depleted mantle source. We envisage these zircons to have been derived from the ocean side of a magmatic arc. All grains in the range 215-250 Ma are characterized by negative ɛHf(T) ranging from -2.3 to -15.2, suggesting re-melting of already existent crust. Within the detrital zircon populations contained in the Sanbagawa meta-sediments age groups are recognized that are also known from SE China. However, compared to those from mainland China, zircons from the Sanbagawa meta-sediments are usually characterized by higher ɛHf(T) values suggesting higher input of material derived from the depleted mantle.

  13. Comparison of U-Th and U-Pb zircon ages from erupted plutonic clasts and 40Ar/39Ar eruption ages from Newberry Volcano, Oregon (United States)

    Sullivan, K. M.; Stelten, M. E.; Leech, M. L.; Donnelly-Nolan, J. M.


    The magmatic plumbing systems of Quaternary volcanoes are poorly understood due to insufficient uplift and erosion to expose their intrusive roots. These intrusive bodies remained in the plumbing system for longer timescales than the eruptive melt; therefore, plutonic rocks record a more extensive history of the entire magmatic system. Occasionally, large-scale eruptions can expose regions of the plumbing system and/or erupt plutonic clasts (EPC) to the surface. We are investigating EPCs found within Newberry ash flow tuffs and hydrothermal drill cores to understand subsurface processes occurring within the magmatic plumbing system. Newberry Volcano is a large shield-shaped composite volcano located in central Oregon that has experienced recurrent volcanism from ca. 500 ka to 1,300 ybp. This study uses the EPC ages to link the intrusive rocks inferred to be representative of the Newberry magmatic plumbing system, and to discern a systematic relationship with volcanism. SHRIMP U-Th disequilibrium and U-Pb zircon ages were analyzed from six EPCs and two hydrothermal granitoids from separate drill cuttings. We compare these new SHRIMP ages to existing 40Ar/39Ar geochronology of Newberry volcanic strata. Three EPCs have unimodal zircon ages of 140 ka, two EPCs display ages of 300 ka, and one has three distinct zircon age populations of 120 ka, 200 ka, and 300 ka. Zircons from separate drill cuttings have ages of 350 ka and 1.9 Ma. All the EPC zircon ages are less than 500 kyr, implying that these clasts are related to the Newberry magmatic system. The granitoid with 1.9 Myr zircons was penetrated by drilling at 2.6 km depth, and could be related to Newberry magmatism and represent an earlier phase of intrusive activity. The 140 kyr zircons record a single crystallization event that took place during a period of frequent volcanism, while the three remaining age populations represent multiple periods of growth that overlap with timeframes of waning activity. Combining

  14. Temporal and spatial distribution of Paleozoic metamorphism in the southern Appalachian Blue Ridge and Inner Piedmont delimited by ion microprobe U-Pb ages of metamorphic zircon (United States)

    Merschat, Arthur J.; Bream, Brendan R.; Huebner, Matthew T.; Hatcher, Robert D.; Miller, Calvin F.


    Ion microprobe U-Pb zircon rim ages from 39 samples from across the accreted terranes of the central Blue Ridge, eastward across the Inner Piedmont, delimit the timing and spatial extent of superposed metamorphism in the southern Appalachian orogen. Metamorphic zircon rims are 10–40 µm wide, mostly unzoned, and dark gray to black or bright white in cathodoluminescence, and truncate and/or embay interior oscillatory zoning. Black unzoned and rounded or ovoid-shaped metamorphic zircon morphologies also occur. Th/U values range from 0.01 to 1.4, with the majority of ratios less than 0.1. Results of 206Pb/238U ages, ±2% discordant, range from 481 to 305 Ma. Clustering within these data reveals that the Blue Ridge and Inner Piedmont terranes were affected by three tectonothermal events: (1) 462–448 Ma (Taconic); (2) 395–340 Ma (Acadian and Neoacadian); and (3) 335–322 Ma, related to the early phase of the Alleghanian orogeny. By combining zircon rim ages with metamorphic isograds and other published isotopic ages, we identify the thermal architecture of the southern Appalachian orogen: juxtaposed and superposed metamorphic domains have younger ages to the east related to the marginward addition of terranes, and these domains can serve as a proxy to delimit terrane accretion. Most 462–448 Ma ages occur in the western and central Blue Ridge and define a continuous progression from greenschist to granulite facies that identifies the intact Taconic core. The extent of 462–448 Ma metamorphism indicates that the central Blue Ridge and Tugaloo terranes were accreted to the western Blue Ridge during the Taconic orogeny. Zircon rim ages in the Inner Piedmont span almost 100 m.y., with peaks at 395–385, 376–340, and 335–322 Ma, and delimit the Acadian-Neoacadian and Alleghanian metamorphic core. The timing and distribution of metamorphism in the Inner Piedmont are consistent with the Devonian to Mississippian oblique collision of the Carolina superterrane

  15. Temporal and Spatial Fluctuations in Ancestral Northern Cascade Arc Magmatism from New LA-ICP-MS U-Pb Zircon Dating (United States)

    McCallum, I. S.; Mullen, E.; Jean-Louis, P.; Tepper, J. H.


    Mt. Baker and the adjacent Chilliwack batholith (MBC focus) in NW Washington preserve the longest magmatic record in the Cascade Arc, providing an excellent natural laboratory for examining the spatial, temporal and geochemical evolution of Cascade magmatism and links to tectonic processes. We present new U-Pb zircon LA-ICP-MS ages for 14 samples from MBC and neighboring regions of the north Cascades. The new results are up to 8 Myr different from previous K-Ar ages, illustrating the need for new age determinations in the Cascades. A maximum age of 34.74±0.24 Ma (2σ) (Post Creek stock) is consistent with 35-40 Ma ages for arc inception in the southern Cascades. The most voluminous MBC plutons cluster at 32-29 Ma, consistent with an early flare-up that also coincides with intrusion of the Index batholith farther south (2 samples at 33.26±0.19, 33.53±0.15 Ma). This flare-up is absent in the northernmost Cascades where the oldest pluton (Fall Creek stock) is 6.646±0.046 Ma, 4 Myr younger than previously cited. Earliest Cascade magmatism is progressively younger to the north of MBC, possibly tracing the northerly passage of the slab edge. MBC activity was continuous to 22.75±0.17 Ma (Whatcom Arm), marking the initiation of an 11 Myr hiatus. Magmatism resumed at 11.33±0.08 Ma (Indian Creek) and continued to the modern Mt. Baker cone, defining a pattern of southwesterly migration over ~55 km that may be attributable to slab rollback and arc rotation (e.g. Wells & McCaffrey 2013). Uniformity of the rate and direction of migration implies that rollback and rotation began at least 11 Myr ago. Post-hiatus magmas show distinct geochemical and petrologic characteristics including a major Pb isotopic shift. The 2.430±0.016 Ma Lake Ann stock contains 4.2 Ma zircon antecrysts, recording prolonged activity in that area. The 1.165±0.013 Ma Kulshan caldera ignimbrite contains ~200 Ma inherited zircons that may provide the first direct record of Wrangellian basement beneath

  16. SHRIMP U-Pb dating of recurrent Cryogenian and Late Cambrian-Early Ordovician alkalic magmatism in central Idaho: Implications for Rodinian rift tectonics (United States)

    Lund, K.; Aleinikoff, J.N.; Evans, K.V.; duBray, E.A.; deWitt, E.H.; Unruh, D.M.


    Composite alkalic plutonic suites and tuffaceous diamictite, although discontinuously exposed across central Idaho in roof pendants and inliers within the Idaho batholith and Challis volcanic-plutonic complex, define the >200-km-long northwest-aligned Big Creek-Beaverhead belt. Sensitive highresolution ion microprobe (SHRIMP) U-Pb zircon dates on these igneous rocks provide direct evidence for the orientation and location of the Neoproterozoic-Paleozoic western Laurentian rift margin in the northern U.S. Cordillera. Dating delimits two discrete magmatic pulses at ca. 665-650 Ma and 500-485 Ma at the western and eastern ends, respectively, of this belt. Together with the nearby 685 Ma volcanic rocks of the Edwardsburg Formation, there is a 200 Ma history of recurrent extensional magmatic pulses along the belt. A similar history of recurrent uplift is reflected in the stratigraphic record of the associated miogeoclinal and cratonal platform basins, suggesting that the Big Creek-Beaverhead belt originated as a border fault during continental rift events. The magmatic belt is paired with the recurrently emergent Lemhi Arch and narrow miogeoclinal facies belts and it lies inboard of a northwest-striking narrow zone of thinned continental crust. These features define a northeast-extending upper-plate extensional system between southeast Washington and southeast Idaho that formed a segment of the Neoproterozoic-Paleozoic miogeocline. This segment was flanked on the north by the St. Mary-Moyie transform zone (south of a narrow southern Canadian upper-plate margin) and on the south by the Snake River transfer zone (north of a broad Great Basin lower-plate margin). These are the central segments of a zigzagshaped Cordilleran rift system of alternating northwest-striking extensional zones offset by northeast-striking transfers and transforms. The data substantiate polyphase rift and continental separation events that included (1) pre-and syn-Windermere rifting, (2) Windermere

  17. Barren Miocene granitoids in the Central Andean metallogenic belt, Chile: Geochemistry and Nd-Hf and U-Pb isotope systematics

    International Nuclear Information System (INIS)

    Deckart, Katja; Godoy, Estanislao; Bertens, Alfredo; Jerez, Daniela; Saeed, Ayesha


    Four Middle-to-Late Miocene barren plutonic complexes that occur between the giant porphyry copper deposits of the central Chilean Andes were selected for U-Pb LA-ICPMS geochronology and Hf-isotope systematics on single zircon grains. Major and trace elements and Sr-Nd-Hf isotope whole rock geochemical studies were undertaken to compare with slightly younger or coeval barren and fertile intrusive rocks between 32 o and 34 o S. The studied granitoids yield resolvable crystallization ages of 11.3±0.1 Ma (Cerro Meson Alto massif), 10.3±0.2 Ma (La Gloria pluton), 14.9±0.2 Ma/14.9±0.1 Ma (Yerba Loca stock) and 11.2±0.1 Ma/14.7±0.1 Ma (San Francisco Batholith). Major and trace elements discard an adakitic signature as suggested for coeval porphyric intrusions at 32 o S, slightly younger mineralized porphyries at Rio Blanco-Los Bronces deposit and other Cenozoic adakites. Volcanic host rocks are less fractionated than the intrusive rock units. The same observation can be made for the unmineralized northern plutons compared to the southern ones. Initial Sr-Nd isotope data show insignificant variation (0.703761-0.704118 and 0.512758- 0.512882), plotting in the mantle array. Trace element enrichment can be explained by addition of subducted-slab fluids and/or terrigenous sediments to the mantle wedge prior to and/or slight crustal input during magma ascent. Zircon grains separated from these barren intrusives share a similar initial εHf-data variation for the younger age group (10-12 Ma; 7.04-9.54) and show a more scattered range for the older one (14-15 Ma; 8.50-15.34); both sets plot between the DM and CHUR evolution lines. There is evidence that magma evolution was slightly distinct through time from older to younger barren magmatism, compared to a few fertile porphyritic rocks from Rio Blanco-Los Bronces porphyry copper deposit. It is suggested that chronological inconsistencies within these complexes might be related to differential shortening across the NE

  18. Petrography, geochemistry, and U-Pb geochronology of pegmatites and aplites associated with the Alvand intrusive complex in the Hamedan region, Sanandaj-Sirjan zone, Zagros orogen (Iran) (United States)

    Sepahi, Ali Asghar; Salami, Sedigheh; Lentz, David; McFarlane, Christopher; Maanijou, Mohammad


    The Alvand intrusive complex in the Hamedan area in Iran is in the Sanandaj-Sirjan zone of the Zagros orogen. It consists of a wide range of plutonic rocks, mainly gabbro, diorite, granodiorite, granite, and leucogranites that were intruded by aplitic and pegmatitic dykes. At least three successive magmatic episodes generated an older gabbro-diorite-tonalite assemblage, followed by a voluminous granodiorite-granite association, which was then followed by minor leucocratic granitoids. Aplitic and pegmatitic dykes and bodies have truncated both plutonic rocks of the Alvand intrusive complex and its metamorphic aureole. Chemically they belong to peraluminous LCT (Li-, Cs-, and Ta-bearing) family of pegmatites. Mineralogically, they resemble Muscovite (MS) and Muscovite Rare Element (MSREL) classes of pegmatites. High amounts of some elements, such as Sn (up to 10,000 ppm), Rb (up to 936 ppm), Ba (up to 706 ppm), and LREE (up to 404 ppm) indicate the highly fractionated nature of some of these aplites and pegmatites. U-Pb dating of monazite, zircon, and allanite by LA-ICPMS indicate the following ages: monazite-bearing aplites of Heydareh-e-Poshteshahr and Barfejin areas, southwest of Hamedan, give an age range of 162-172 Ma; zircon in Heydareh-e-Poshteshar gives an average age of 165 Ma and for allanite-bearing pegmatites of Artiman area, north of Tuyserkan, an age of 154.1 ± 3.7 Ma was determined. These overlap with previously reported ages (ca. 167-153 Ma) for the plutonic rocks of the Alvand complex. Therefore, these data reveal that the Jurassic was a period of magmatism in the Hamedan region and adjacent areas in the Sanandaj-Sirjan zone, which was situated at the southern edge of the central Iranian micro-plate (southern Eurasian plate) at this time. Our results also suggest that advective heating in a continental arc setting has caused melting of fertile supracrustal lithologies, such as meta-pelites. These partial melts were then emplaced at much higher

  19. Petrogenesis of granodiorite in the Balong region, eastern Kunlun Orogen, China: Constraints from zircon U-Pb geochronology, geochemistry and Sr-Nd-Hf isotopes (United States)

    Huang, X.; Li, H.; Wang, Y.; Liu, Y.


    Numerous granitoid intrusions that close to the Balong region have great scientific significance to reveal tectonic evolution and geodynamic background of eastern Kunlun Orogen (EKO). Balong granodiorite (BLG) is located at the northern of the EKO. It generally emplaced into the Proterozoic to Lower Palaeozoic rocks and contains abundant mafic microgranular enclaves. LA-ICP-MS zircon U-Pb dating of the BLG gives a 206Pb/238U age of 230.7±1.9 Ma, indicating that it was emplaced in the Late Triassic. The BLG is high-K calc-alkaline series and metaluminous, with SiO2 of 59.86 61.83%, K2O+Na2O of 5.98 6.40%, CaO of 4.95 5.77% and P2O5 of 0.14% 0.18%. The granodioritic rocks are enriched in LILE (Ba, Rb, Sr), but depleted in HFSE (Nb, Ta, P, Ti), with weak negative Eu anomalies (δEu=0.70 0.82). Mineralogy and geochemistry of the rocks show an affinity to I-type granite. The BLG, having (87Sr/86Sr)i ratios of 0.70819 to 0.70832, ɛNd(t) values of -5.27 to -5.75, and zircon ɛHf(t) values ranging from -3.86 to -1.34. The whole-rock Nd isotopic model ages (1432 1471 Ma) and zircon Hf isotopic model ages (1205 1357 Ma) indicate that the BLG is generated by partial melting of lower crust (Precambrian metabasaltic basement rocks) with different degree of involvement of mantle material. Combined with regional geological data, the granodiorite was derived from dehydration melting of mafic lower crustal rocks during the subduction of the Anyemaqen ocean lithosphere at Late Permian-Triassic in a subduction setting. Basaltic magma underplating and crust-mantle mixing are main mechanisms for the origin of large-scale I-type granitoid in Balong.

  20. High Resolution Tephra and U/Pb Chronology of the 3.33-3.26 Ga Mendon Formation, Barberton Greenstone Belt, South Africa (United States)

    Decker, N. B.; Stefurak, E. J.; Thompson, M. E.; Lowe, D. R.; Byerly, G. R.


    Stratigraphic and geologic interpretations of komatiitic flows and tuffs in the Barberton greenstone belt (BGB) are complicated by structural complexity, facies changes, and temporal repetition of lithofacies. Here we describe new data on the compositions of flows and tuffs and U/Pb ages that correlate existing and proposed new members of the Mendon Formation across the BGB. The Mendon Formation includes from 300 to >1000 m of komatiite, komatiitic tuff, and carbonaceous-to-ferruginous chert that represent the uppermost Onverwacht Group south of the Inyoka Fault. Our new data confirm that the Weltevreden Formation, the uppermost Onverwacht Group north of the Inyoka Fault, is correlative with the upper members of the Mendon Formation. The conformably overlying Fig Tree Group is composed largely of lithic sandstones and dacitic volcaniclastic rocks likely representing uplift and volcanism within a magmatic arc. Thus the Onverwacht to Fig Tree Group transition may represent a profound change from plume to plate tectonics. Recent studies have also demonstrated the importance of large asteroidal impacts near the Onverwacht-Fig Tree contact, two in the Mendon Formation and two in the lower Fig Tree Group spanning a 50 myr interval, suggesting a possible link between impacts and this tectonic transition. The compositional change from komatiitic to dacitic ash is moderately abrupt and near the S2 impact layer. However, at least five felsic ash layers are recognized in the Mendon Formation, and several komatiitic ash layers occur above S2 in the lowest Fig Tree Group. A preliminary compilation of the new data with that of previous studies suggests: 1) the Mendon Formation has an extreme diversity of primary komatiitic compositions, but also includes thin felsic ash layers, 2) no komatiitic flows have been identified in the Fig Tree Group but several komatiitic ash layers occur associated with spherule bed S2, 3) major faults in the south-central BGB isolate sections of the

  1. Precise Crystallization Age of the Bushveld Complex, South Africa: Direct Dating of the Platiniferous Merensky Reef Using the Zircon U-Pb Chemical Abrasion ID-TIMS Technique (United States)

    Scoates, J. S.; Friedman, R. M.


    Determining the age of the Bushveld Complex, the world's largest layered intrusion and host to the majority of the known resources of platinum group elements, chromium and vanadium, has been difficult given the very low abundance of U-bearing minerals in the ultramafic-mafic cumulate rocks that comprise the body. This study provides a precise crystallization age for this giant layered intrusion and associated PGE mineralization, and allows for a re-evaluation of the duration and areal extent of Bushveld-related magmatic activity. Abundant, clear and colorless, anhedral zircon grains were separated from a sample of pegmatoidal feldspathic orthopyroxenite collected from the Merensky Reef in the West Mine (Townlands Shaft), Rustenburg Section. Low-U (21-105 ppm) zircon occurs with interstitial biotite and is locally directly in contact with sulfide. The zircon grains were subjected to different pre-treatment methods (no pre-treatment, air abrasion, and chemical abrasion [CA]) and isotope ratios for individual grains were analyzed by ID-TIMS. U-Pb data for the unabraded and air-abraded grains, and leachates from the CA procedure, are slightly discordant (0.1-1.6%) and yield overlapping 207Pb/206Pb dates ranging from 2052.5 to 2058.9 Ma. For the CA zircon grains (n=6), all data are concordant and give a Concordia age of 2054.3 ± 2.5 Ma (2sd, decay-constant errors included), which is interpreted as the age of crystallization of the Merensky Reef. This age is within error of published ages for the overlying, and locally cross-cutting, Bushveld or Lebowa granite suite, which implies that the entire Bushveld Complex was emplaced within a 2-3 myr interval. Comparison with ages from satellite intrusions (e.g. Moshaneng, Botswana; Uitkomst, South Africa) indicates that the Bushveld magmatic event at ca. 2054 Ma was regionally extensive across the northern Kaapvaal Craton and is consistent with relatively rapid emplacement of mantle-derived magmas along the Thabazimbi

  2. Repeated granitoid intrusions during the Neoproterozoic along the western boundary of the Saharan metacraton, Eastern Hoggar, Tuareg shield, Algeria: An AMS and U-Pb zircon age study (United States)

    Henry, B.; Liégeois, J. P.; Nouar, O.; Derder, M. E. M.; Bayou, B.; Bruguier, O.; Ouabadi, A.; Belhai, D.; Amenna, M.; Hemmi, A.; Ayache, M.


    The N-S oriented Raghane shear zone (8°30') delineates the western boundary of the Saharan metacraton and is, with the 4°50' shear zone, the most important shear zone in the Tuareg shield. It can be followed on 1000 km in the basement from southern Aïr, Niger to NE Hoggar, Algeria. Large subhorizontal movements have occurred during the Pan-African orogeny and several groups of granitoids intruded during the Neoproterozoic. We report U-Pb zircon datings (laser ICP-MS) showing that three magmatic suites of granitoids emplaced close to the Raghane shear zone at c. 790 Ma, c. 590 and c. 550 Ma. A comprehensive and detailed (158 sites, more than 1000 cores) magnetic fabric study was performed on 8 plutons belonging to the three magmatic suites and distributed on 200 km along the Raghane shear zone. The main minerals in all the target plutons do not show visible preferential magmatic orientation except in narrow shear zones. The AMS study shows that all plutons have a magnetic lineation and foliation compatible with the deformed zones that are zones deformed lately in post-solidus conditions. These structures are related to the nearby mega-shear zones, the Raghane shear zone for most of them. The old c. 793 Ma Touffok granite preserved locally its original structures. The magnetic structures of the c. 593 Ma Ohergehem pluton, intruded in the Aouzegueur terrane, are related to thrust structures generated by the Raghane shear zone while it is not the case of the contemporaneous plutons in the Assodé-Issalane terrane whose structures are only related to the subvertical shear zones. Finally, the c. 550 Ma granite group has magnetic structure related to the N-S oriented Raghane shear zone and its associated NNE-SSW structures when close to them, but NW-SE oriented when further. These NW-SE oriented structures appear to be characteristic of the late Neoproterozoic evolution of the Saharan metacraton and are in relation to the convergence with the Murzuq craton. This

  3. In Situ TEM Electrical Measurements

    DEFF Research Database (Denmark)

    Canepa, Silvia; Alam, Sardar Bilal; Ngo, Duc-The


    influence the sample by external stimuli, e.g. through electrical connections, the TEM becomes a powerful laboratory for performing quantitative real time in situ experiments. Such TEM setups enable the characterization of nanostructures and nanodevices under working conditions, thereby providing a deeper...

  4. In Situ Wetland Restoration Demonstration (United States)


    applied to the soil (see Figure 5-3). iv. The benthic community was sampled for abundance, taxa richness, Biotic Index, functional feeding groups ...1 Figure 1-2 Freshwater Tidal Wetland...process (Chadwick, 2008). Figure 1-2 Freshwater Tidal Wetland ESTCP Project ER-200825 In Situ Wetland Restoration Demonstration ER-200825 Final

  5. In Situ Cardiovascular Tissue Engineering

    NARCIS (Netherlands)

    Talacua, H


    In this thesis, the feasibility of in situ TE for vascular and valvular purposes were tested with the use of different materials, and animal models. First, the feasibility of a decellularized biological scaffold (pSIS-ECM) as pulmonary heart valve prosthesis is examined in sheep (Chapter 2). Next,

  6. Chroni - an Android Application for Geochronologists to Access Archived Sample Analyses from the NSF-Funded Geochron.Org Data Repository. (United States)

    Nettles, J. J.; Bowring, J. F.


    NSF requires data management plans as part of funding proposals and geochronologists, among other scientists, are archiving their data and results to the public cloud archives managed by the NSF-funded Integrated Earth Data Applications, or IEDA. GeoChron is a database for geochronology housed within IEDA. The software application U-Pb_Redux developed at the Cyber Infrastructure Research and Development Lab for the Earth Sciences ( at the College of Charleston provides seamless connectivity to GeoChron for uranium-lead (U-Pb) geochronologists to automatically upload and retrieve their data and results. U-Pb_Redux also manages publication-quality documents including report tables and graphs. CHRONI is a lightweight mobile application for Android devices that provides easy access to these archived data and results. With CHRONI, U-Pb geochronologists can view archived data and analyses downloaded from the Geochron database, or any other location, in a customizable format. CHRONI uses the same extensible markup language (XML) schema and documents used by U-Pb_Redux and GeoChron. Report Settings are special XML files that can be customized in U-Pb_Redux, stored in the cloud, and then accessed and used in CHRONI to create the same customized data display on the mobile device. In addition to providing geologists effortless and mobile access to archived data and analyses, CHRONI allows users to manage their GeoChron credentials, quickly download private and public files via a specified IEDA International Geo Sample Number (IGSN) or URL, and view specialized graphics associated with particular IGSNs. Future versions of CHRONI will be developed to support iOS compatible devices. CHRONI is an open source project under the Apache 2 license and is hosted at We encourage community participation in its continued development.

  7. U-Pb detrital zircon ages of the upper metasedimentary sequences in the region of the Guarinos Greenstone Belt, Goiás, Brazil; Idades U-Pb de zircão detrítico da sequência metassedimentar superior na região do Greenstone Belt de Guarinos, Goiás

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Alex Joaquim Choupina Andrade; Simões, Luiz Sérgio Amarante, E-mail:, E-mail: [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Rio Claro, SP (Brazil). Programa de Pós-Graduação em Geociências e Meio Ambiente


    At the north portion of the Archean Block of Goiás occur two greenstone belts (Guarinos and Pilar de Goiás) covered by a younger meta sedimentary sequence, attributed by different authors to the Araxá Group and by other to the Serra da Mesa/Serra Dourada and, by other writers, simply as Mesoproterozoic Sequence. Although there are lithostratigraphic similarities between the Araxá and Serra da Mesa groups, most recent studies have shown that the evolution of basins and their sedimentation ages have peculiarities that differentiate one from the other. This work presents geochronological data of U-Pb on detrital zircon grains obtained by laser ablation method (LA-MC-ICP-MS) in quartzite samples. The youngest zircon has the age of 1405 ± 10 Ma, marking the maximum depositional age and indicating source area. The samples have a higher frequency of Paleoproterozoic zircons, between 1796 and 2472 Ma and the oldest populations of mesoneoarchean age between 2672 and 3112 Ma. Whereas the Paleoproterozoic to Archean zircons can be derived from the rocks that form the Archean Block of Goiás, the mesoproterozoic source is still uncertain, perhaps this source can be related to the Goiás Tin Province rocks. (author)

  8. Micro-analysis by U-Pb method using LAM-ICPMS and its applications for the evolution of sedimentary basins: the example from Brasilia Belt; Micro-analise pelo metodo U-Pb usando LAM-CIPMS e suas aplicacoes para a evolucao de bacias sedimentares: o exemplo da faixa Brasilia

    Energy Technology Data Exchange (ETDEWEB)

    Pimentel, Marcio Martins; Matteini, Massimo; Junges, Sergio Luiz; Giustina, Maria Emilia Schutesky Della; Dantas, Elton Luiz; Buhn, Bernhard, E-mail: [Universidade de Brasilia (UnB), DF (Brazil). Instituto de Geociencias; Rodrigues, Joseneusa Brilhante [Servico Geologico do Brasil (CPRM), Brasilia, DF (Brazil)


    The U-Pb geochronological method using LAM-MC-ICPMS represents an important tool to investigate the geological evolution of sedimentary basins, as well as its geochronology, through the determination of upper limits for the depositional ages of detrital sedimentary rocks. The method has been applied in the Geochronology Laboratory of the Universidade de Brasilia, and in this study, a brief review of the provenance data for the sediments of the Neoproterozoic Brasilia Belt is presented and their significance for the evolution of the orogen is discussed. The results indicate that the Paranoa and Canastra Groups represent passive margin sequences formed along the western margin of the Sao Francisco-Congo continent. The Vazante Group presents similar provenance patterns, although Sm-Nd isotopic results suggest that its upper portions had contributions from younger (Neoproterozoic) sources, possibly from the Neoproterozoic Goias Magmatic Arc. On the other hand, metasediments of the Araxa and Ibia groups contain an important proportion of material derived from Neoproterozoic sources, demonstrating that they represent syn-orogenic basins. The provenance pattern of the Bambui Group is marked by an important Neoproterozoic component, showing that it constitutes a sedimentary sequence which is younger than 600 Ma, representing a foreland basin to the Brasilia Belt. (author)

  9. Microstructure analysis of laboratory and in-situ compacted silts

    Directory of Open Access Journals (Sweden)

    Russo Giacomo


    Full Text Available The paper presents and discusses some results of an experimental research aimed at analysing the influence of compaction variables (w and energy and method on the resulting microstructure of a compacted silty soil. In particular, the experimental data here discussed allow to compare the microstructure induced by different dynamic compaction techniques, comparing that characterising specimens obtained by two laboratory methods (Proctor standard and Harvard and that of samples compacted in-situ during the construction of an embankment built for river regimentation purposes. Both undisturbed and disturbed samples have been retrieved from the embankment, the latter one with the purpose of collecting the soil subsequently used for laboratory compaction. Microstructural analyses (SEM, MIP performed on laboratory and in-situ compacted samples evidenced a substantial similarity of the texture induced by the various compaction techniques, highlighting that laboratory compaction is suitable to provide soil samples representative of earth in-situ compacted soil.

  10. Timing of the magmatism of the paleo-Pacific border of Gondwana: U-Pb geochronology of Late Paleozoic to Early Mesozoic igneous rocks of the north Chilean Andes between 20o and 31oS

    International Nuclear Information System (INIS)

    Maksaev, Victor; Munizaga, Francisco; Tassinari, Colombo


    U-Pb zircon geochronological data provide record of about 130 Ma of igneous activity in the Andes of northern Chile, which extended episodically from the latest Early Carboniferous to Early Jurassic (328-194 Ma). The overall U-Pb data show that volcanism and plutonism were essentially synchronous and major episodes of igneous activity developed during the Late Carboniferous to Mid-Permian (310 to 260 Ma) and from Late Permian to Late Triassic (255-205 Ma), with less prominent episodes in the mid-Carboniferous (330 to 320 Ma), and Early Jurassic (200-190 Ma). Thus, from the Carboniferous to the Early Triassic dominantly silicic magmatism developed along the Chilean segment of the southwestern border of Gondwana supercontinent. Further magmatism developed during the Mid-Late Triassic (250-194 Ma) was bimodal and synchronous with rift-related, continental and/or marine sedimentary strata related to the early stages of break-up of Gondwana. Most of the silicic volcanic rocks of the Precordillera and Domeyko Cordillera of northern Chile (21 o 30 o to 25 o 30 o S) are older than the silicic rocks assigned to the Choiyoi succession in Argentina, being instead equivalent in age to Carboniferous to Early Permian marine sedimentary sequences present in the eastern Argentinean foreland. On the other hand, silicic volcanic successions exposed in the easternmost part of northern Chile are equivalent in age to the Choiyoi succession of the San Rafael Block of Argentina. An eastward expansion or migration of the volcanism during the Mid-Permian to Early Triassic is inferred, interpretation that is consistent with expansion of the volcanism at that time in Argentina. The timing of the Late Paleozoic to Early Jurassic magmatism is coincident with that of the Andes of Peru and of western Argentina according to the available U-Pb data, revealing a rather consistent evolution in time of the magmatism along the southwestern, paleo-Pacific border of Gondwana

  11. Mesozoic magmatism and timing of epigenetic Pb-Zn-Ag mineralization in the western Fortymile mining district, east-central Alaska: Zircon U-Pb geochronology, whole-rock geochemistry, and Pb isotopes (United States)

    Dusel-Bacon, Cynthia; Aleinkoff, J.N.; Day, W.C.; Mortensen, J.K.


    The Mesozoic magmatic history of the North American margin records the evolution from a more segmented assemblage of parautochthonous and allochthonous terranes to the more cohesive northern Cordilleran orogenic belt. We characterize the setting of magmatism, tectonism, and epigenetic mineralization in the western Fortymile mining district, east-central Alaska, where parautochthonous and allochthonous Paleozoic tectonic assemblages are juxtaposed, using sensitive high-resolution ion microprobe (SHRIMP) U-Pb zircon geochronology, whole-rock geochemistry, and feldspar Pb isotopes of Mesozoic intrusions and spatially associated mineral prospects. New SHRIMP U-Pb zircon ages and published U-Pb and 40Ar/39Ar ages indicate four episodes of plutonism in the western Fortymile district: Late Triassic (216-208 Ma), Early Jurassic (199-181 Ma), mid-Cretaceous (112-94 Ma), and Late Cretaceous (70-66 Ma). All age groups have calc-alkalic arc compositions that became more evolved through time. Pb isotope compositions of feldspars from Late Triassic, Early Jurassic, and Late Cretaceous igneous rocks similarly became more radiogenic with time and are consistent with the magmas being mantle derived but extensively contaminated by upper crustal components with evolving Pb isotopic compositions. Feldspar Pb isotopes from mid-Cretaceous rocks have isotopic ratios that indicate magma derivation from upper crustal sources, probably thickened mid-Paleozoic basement. The origin of the mantle component in Late Cretaceous granitoids suggested by Pb isotopic ratios is uncertain, but we propose that it reflects asthenospheric upwelling following slab breakoff and sinking of an inactive inner subduction zone that delivered the previously accreted Wrangellia composite terrane to the North American continental margin, after the outer Farallon subduction zone was established.

  12. Polyolefin nanocomposites in situ polymerization

    International Nuclear Information System (INIS)

    Galland, Griselda Barrera; Fim, Fabiana de C.; Milani, Marceo A.; Silva, Silene P. da; Forest, Tadeu; Radaelli, Gislaine; Basso, Nara R.S.; Quijada, Raul


    Polyethylene and polypropylene nanocomposites using grapheme nanosheets and treated chrysotile have been synthesized by in situ polymerization using metallocene catalysts. The fillers have been submitted to acid, thermal and/ou ultrasound treatments before to introduce them into the polymerization reactor. A complete characterization of the fillers has been done. The nanocomposites have been characterized by SEM, TEM, DRX and AFM. The thermal, mechanic -dynamic, mechanical and electrical properties of the nanocomposites are discussed. (author)

  13. Lifetime of an ocean island volcano feeder zone: constraints from U-Pb dating on coexisting zircon and baddeleyite, and 40/39Ar age determinations, Fuerteventura, Canary Islands (United States)

    Allibon, James; Ovtcharova, Maria; Bussy, Francois; Cosca, Michael; Schaltegger, Urs; Bussien, Denise; Lewin, Eric


    High-precision isotope dilution - thermal ionization mass spectrometry (ID-TIMS) U-Pb zircon and baddeleyite ages from the PX1 vertically layered mafic intrusion Fuerteventura, Canary Islands, indicate initiation of magma crystallization at 22.10 ± 0.07 Ma. The magmatic activity lasted a minimum of 0.52 Ma. 40Ar/39Ar amphibole dating yielded ages from 21.9 ± 0.6 to 21.8 ± 0.3, identical within errors to the U-Pb ages, despite the expected 1% theoretical bias between 40Ar/39Ar and U-Pb dates. This overlap could result from (i) rapid cooling of the intrusion (i.e., less than the 0.3 to 0.6 Ma 40Ar/39Ar age uncertainties) from closure temperatures (Tc) of zircon (699-988 °C) to amphibole (500-600 °C); (ii) lead loss affecting the youngest zircons; or (iii) excess argon shifting the plateau ages towards older values. The combination of the 40Ar/39Ar and U/Pb datasets implies that the maximum amount of time PX1 intrusion took to cool below amphibole Tc is 0.8 Ma, suggesting PX1 lifetime of 520,000 to 800,000 Ma. Age disparities among coexisting baddeleyite and zircon (22.10 ± 0.07/0.08/0.15 Ma and 21.58 ± 0.15/0.16/0.31 Ma) in a gabbro sample from the pluton margin suggest complex genetic relationships between phases. Baddeleyite is found preserved in plagioclase cores and crystallized early from low silica activity magma. Zircon crystallized later in a higher silica activity environment and is found in secondary scapolite and is found close to calcite veins, in secondary scapolite that recrystallised from plagioclase. close to calcite veins. Oxygen isotope δ18O values of altered plagioclase are high (+7.7), indicating interaction with fluids derived from host-rock carbonatites. The coexistence of baddeleyite and zircon is ascribed to interaction of the PX1 gabbro with CO2-rich carbonatite-derived fluids released during contact metamorphism.

  14. Cryogenian alkaline magmatism in the Southern Granulite Terrane, India: Petrology, geochemistry, zircon U-Pb ages and Lu-Hf isotopes (United States)

    Santosh, M.; Yang, Qiong-Yan; Ram Mohan, M.; Tsunogae, T.; Shaji, E.; Satyanarayanan, M.


    The Southern Granulite Terrane (SGT) in India preserves the records of the formation and recycling of continental crust from Mesoarchean through Paleoproterozoic to Neoproterozoic and Cambrian, involving multiple subduction-accretion-collision associated with major orogenic cycles. A chain of unmetamorphosed and undeformed alkaline magmatic intrusions occurs along the northern margin of the SGT aligned along paleo-suture zones. Here we investigate two representative plutons from this suite, the Angadimogar syenite (AM) and the Peralimala alkali granite (PM) through field, petrological, geochemical, zircon U-Pb and Lu-Hf studies. Magma mixing and mingling textures and mineral assemblages typical of alkaline rocks are displayed by these plutons. The whole-rock major and trace element data characterize their alkaline nature. In trace element discrimination diagrams, the AM rocks straddle between the VAG (volcanic-arc granites) and WPG (within plate granites) fields with most of the samples confined to the VAG field, whereas the PM rocks are essentially confined to the WPG field. The diversity in some of the geochemical features between the two plutons is interpreted to be the reflection of source heterogeneities. Most zircon grains from the AM and PM plutons display oscillatory zoning typical of magmatic crystallization although some grains, particularly those from the PM pluton, show core-rim structures with dark patchy zoned cores surrounded by irregular thin rims resulting from fluid alteration. The weighted mean 206Pb/238U ages of the magmatic zircons from three samples of the AM syenite are in the range of 781.8 ± 3.8 Ma to 798 ± 3.6 Ma and those from two samples of the PM alkali granite yield ages of 797.5 ± 3.7 Ma and 799 ± 6.2 Ma. A mafic magmatic enclave from the AM pluton shows weighted mean 206Pb/238U age of 795 ± 3.3 Ma. The AM and PM plutons also carry rare xeneocrystic zircons which define upper intercept concordia ages of 3293 ± 13 Ma and 2530

  15. The Pobei Cu-Ni and Fe ore deposits in NW China are comagmatic evolution products: evidence from ore microscopy, zircon U-Pb chronology and geochemistry

    International Nuclear Information System (INIS)

    Liu, G.I.; Li, W.Y.; Lu, X.B.; Huo, Y.H.; Zhang, B.


    The Pobei mafic-ultramafic complex in northwestern China comprises magmatic Cu-Ni sulfide ore deposits coexisting with Fe-Ti oxide deposits. The Poshi, Poyi, and Podong ultramafic intrusions host the Cu-Ni ore. The ultramafic intrusions experienced four stages during its formation. The intrusion sequence was as follows: dunite, hornblende-peridotite, wehrlite and pyroxenite. The wall rock of the ultramafic intrusions is the gabbro intrusion in the southwestern of the Pobei complex. The Xiaochangshan magmatic deposit outcrops in the magnetitemineralized gabbro in the northeastern part of the Pobei complex. The main emplacement events related to the mineralization in the Pobei complex, are the magnetite-mineralized gabbro related to the Xiaochangshan Fe deposit, the gabbro intrusion associated to the Poyi, Poshi and Podong Cu-Ni deposits, and the ultramafic intrusions that host Cu-Ni deposits (Poyi and Poshi). The U-Pb age of the magnetite-mineralized gabbro is 276±1.7Ma, which is similar to that of the Pobei mafic intrusions. The εHf(t) value of zircon in the magnetite-mineralized gabbro is almost the same as that of the gabbro around the Poyi and Poshi Cu-Ni deposits, indicating that the rocks related to Cu-Ni and magnetite deposits probably originated from the same parental magma. There is a trend of crystallization differentiation evolution in the Harker diagram from the dunite in the Cu-Ni deposit to the magnetite-mineralized gabbro. The monosulfide solid solution fractional crystallization was weak in Pobei; thus, the Pd/Ir values were only influenced by the crystallization of silicate minerals. The more complete the magma evolution is, the greater is the Pd/Ir ratio. The Pd/Ir values of dunite, the lithofacies containing sulfide (including hornblende peridotite, wehrlite, and pyroxenite) in the Poyi Cu-Ni deposit, magnetite-mineralized gabbro, and massive magnetite, are 8.55, 12.18, 12.26, and 18.14, respectively. Thus, the massive magnetite was probably the

  16. A new chronostratigraphy (40Ar-39Ar and U-Pb Dating) for the Middle Section of the Burdur-Fethiye Shear Zone, SW Turkey (United States)

    Elitez, İrem; Yaltırak, Cenk; Sunal, Gürsel


    There are few basins containing younger rocks along the Burdur-Fethiye Shear Zone, such as the Burdur, Tefenni, Eşen and Acı göl basins. The middle section of the Burdur-Fethiye Shear Zone, where Neogene sediments predominate, includes three modern basins: the Acı payam, Çameli and Gölhisar basins. All these basins represent portions of larger carbonate lakes. A considerable number of studies suggested controversial Neogene stratigraphy of these basins and environs. In most cases, the local river and alluvial fan deposits were mapped together with the lacustrine sediments. According to most studies, the lacustrine deposits are of Pliocene age, except in small areas north and east of Acı payam Basin. Our field observations revealed two distinct young sedimentary sequences that unconformably overlies the pre-Neogene basement in the middle section of the Burdur-Fethiye Shear Zone. The first sequence begins with meandering- and braided-river sediments, which transition upward into lacustrine sediments. The uppermost part of the lacustrine sediments consists mostly of red-wine-coloured claystones and silty carbonates including caliche. This sequence is overlain by alluvial fan conglomerates, mudstones and claystones. In the northern part of Acı payam Basin at elevations of ˜1500-1600 m, the lamproites cut or overlie both fluvial conglomerates and lacustrine marls, claystones and limestones. In addition, a tuff level was found in the lacustrine sediments south-west of Çameli Basin. We provide new geochronological data from these volcanic rocks. Zircon U-Pb results from tuff level yielded age of 6.933±0.041 Ma. The lamproites are dated at 5.06±1.44, 5.69±2.34, 6.08±0.48, 6.43±0.29, 6.94±0.35, 6.98±0.31 and 6.88±0.22 Ma by 39Ar/40Ar dating method. Consequently, a Messinian age is suggested for the uppermost part of the river deposits. Field relations show that the lacustrine sediments are upper Miocene-lower Pliocene in age and the widespread exposures of

  17. The Pobei Cu-Ni and Fe ore deposits in NW China are comagmatic evolution products: evidence from ore microscopy, zircon U-Pb chronology and geochemistry

    Energy Technology Data Exchange (ETDEWEB)

    Liu, G.I.; Li, W.Y.; Lu, X.B.; Huo, Y.H.; Zhang, B.


    The Pobei mafic-ultramafic complex in northwestern China comprises magmatic Cu-Ni sulfide ore deposits coexisting with Fe-Ti oxide deposits. The Poshi, Poyi, and Podong ultramafic intrusions host the Cu-Ni ore. The ultramafic intrusions experienced four stages during its formation. The intrusion sequence was as follows: dunite, hornblende-peridotite, wehrlite and pyroxenite. The wall rock of the ultramafic intrusions is the gabbro intrusion in the southwestern of the Pobei complex. The Xiaochangshan magmatic deposit outcrops in the magnetitemineralized gabbro in the northeastern part of the Pobei complex. The main emplacement events related to the mineralization in the Pobei complex, are the magnetite-mineralized gabbro related to the Xiaochangshan Fe deposit, the gabbro intrusion associated to the Poyi, Poshi and Podong Cu-Ni deposits, and the ultramafic intrusions that host Cu-Ni deposits (Poyi and Poshi). The U-Pb age of the magnetite-mineralized gabbro is 276±1.7Ma, which is similar to that of the Pobei mafic intrusions. The εHf(t) value of zircon in the magnetite-mineralized gabbro is almost the same as that of the gabbro around the Poyi and Poshi Cu-Ni deposits, indicating that the rocks related to Cu-Ni and magnetite deposits probably originated from the same parental magma. There is a trend of crystallization differentiation evolution in the Harker diagram from the dunite in the Cu-Ni deposit to the magnetite-mineralized gabbro. The monosulfide solid solution fractional crystallization was weak in Pobei; thus, the Pd/Ir values were only influenced by the crystallization of silicate minerals. The more complete the magma evolution is, the greater is the Pd/Ir ratio. The Pd/Ir values of dunite, the lithofacies containing sulfide (including hornblende peridotite, wehrlite, and pyroxenite) in the Poyi Cu-Ni deposit, magnetite-mineralized gabbro, and massive magnetite, are 8.55, 12.18, 12.26, and 18.14, respectively. Thus, the massive magnetite was probably the

  18. U-Pb zircon geochronology of the Tioga ash layers within the Marcellus Shale, Appalachian Basin: Implications for basin evolution during the Middle Devonian (United States)

    Parrish, C. B.; Hayward, J.; Toro, J.; Weislogel, A. L.; Wooden, J. L.


    Numerous thin volcanic ash layers are found interbedded within the upper Onondaga Formation and lower Marcellus Shale of the Appalachian basin. These ashes are believed to have been sourced from continental arc magmatism along the Acadian orogen during the Middle Devonian and form key stratigraphic markers, allow for geochemical analysis of parent magma, and most importantly, provide geochronologic dates used in determining depositional rates and chronostratigraphic relations. Zircons were extracted from ashes found in 6 well cores in Pennsylvania and West Virginia. The ashes range in thickness from 0.5-14 cm and are recognized by their buff color, abundant mica and pyrite, and high U/Th ratios in spectral gamma ray logs. The U-Pb age of each ash layer was determined by analyzing 12-18 spots on individual zircon crystals at the USGS-Stanford SHRIMP-RG laboratory. Recycled or reworked older zircon crystals are absent from the samples suggesting a primary origin as air-fall deposits. Concordant 206Pb/238U ages from zircon crystals within a single ash vary over a range of as much as 23 My which could represent the residence time of the zircon crystals within the Acadian magmatic system. Typically there is a cluster of younger ages that we interpret as the best estimate of the age of eruption and coeval with depositional age in the basin. This indicates that either the basal Marcellus Shale was deposited diachronously or that ashes were not preserved uniformly across the study area. Wells on the western-most side of the study area in northern West Virginia yield consistently older ages than the rest of the wells. However, this age distribution is inconsistent with the simplistic model of Appalachian basin fill where the oldest sediments are expected closer to the eastern margin. Some wells also showed stratigraphically younger ashes yielding older ages than underlying ashes, although most overlap within age error, possibly due to complexity in basin structure and

  19. U-Pb geochronology, geochemistry, and H-O-S-Pb isotopic compositions of the Leqingla and Xin'gaguo skarn Pb-Zn polymetallic deposits, Tibet, China (United States)

    Wang, Liqiang; Cheng, Wenbin; Tang, Juxing; Kang, Haoran; Zhang, Yan; Li, Zhuang


    The Leqingla and Xin'gaguo deposits are two representative skarn Pb-Zn polymetallic deposits of the Gangdese Pb-Zn polymetallic belt, Tibet, China. LA-ICP-MS zircon U-Pb dating of the mineralization-related biotite granites from both the Leqingla and Xin'gaguo deposits yielded weighted mean ages of 60.8 Ma and 56.5 Ma, respectively, which can be inferred as their mineralization ages. The Leqingla biotite granite is characterized by high Al2O3, total Fe, Na2O, and low K2O. In comparison, the Xin'gaguo biotite granite is characterized by relative higher K2O but lower Al2O3, total Fe, and Na2O. Geochemical and mineralogical characteristics indicate that the Leqingla and Xin'gaguo biotite granites are calc-alkaline I-type granite and High K calc-alkaline I-type granite, respectively. Both the Leqingla and Xin'gaguo biotite granites are enrichment in LREE and LILEs and depletion in HFSEs, and they were formed at the India-Asia collision stage. δ18O and δD values for the Leqingla and Xin'gaguo deposits are -8.8‰ to 5.3‰ and -140.4‰ to -90.1‰, -4.5‰ to 7.0‰ and -117.3‰ to -81.0‰, respectively, indicating magma fluids mixed with meteoric water in ore-forming fluids. δ34S values (-11.6‰ to -0.3‰) of ore sulfides from the Leqingla deposit show characteristics of biogenetic sulfur isotope compositions, suggesting sulfur for the Leqingla deposit were sourced from wall rocks of the Mengla and Luobadui Formation, which are rich in organic materials. δ34S values of ore sulfides from the Xin'gaguo deposits show bimodal distribution (-5.0‰ to -1.6‰ and 1.6-2.1‰), indicating sulfur in the Xin'gaguo deposit were derived from both wall rocks and magma. In the Leqingla deposit, most ore sulfides have the similar Pb isotopic compositions with that of the mineralization-related biotite granite, suggesting the biotite granite supplied most of the ore-forming metals. Pb isotopic compositions of ore sulfides and Hf isotopic compositions of biotite granite show

  20. Oldest biliary endoprosthesis in situ. (United States)

    Consolo, Pierluigi; Scalisi, Giuseppe; Crinò, Stefano F; Tortora, Andrea; Giacobbe, Giuseppa; Cintolo, Marcello; Familiari, Luigi; Pallio, Socrate


    The advantages of endoscopic retrograde cholangiopancreatography over open surgery have made it the predominant method of treating patients with choledocholithiasis. After sphincterotomy, however, 10%-15% of common bile duct stones cannot be removed with a basket or balloon. The methods for managing "irretrievable stones" include surgery, mechanical lithotripsy, intraductal or extracorporeal shock wave lithotripsy and biliary stenting. The case presented was a referred 82-year-old Caucasian woman with a 7-year-old plastic biliary endoprosthesis in situ. To the best of our knowledge the examined endoprosthesis is the oldest endoprosthesis in situ reported in the literature. Endoscopic biliary endoprosthesis placement remains a simple and safe procedure for patients with stones that are difficult to manage by conventional endoscopic methods and for patients who are unfit for surgery or who are high surgical risks. To date no consensus has been reached regarding how long a biliary prosthesis should remain in situ. Long-term biliary stenting may have a role in selected elderly patients if stones extraction has failed because the procedure may prevent stones impaction and cholangitis.

  1. Oldest biliary endoprosthesis in situ (United States)

    Consolo, Pierluigi; Scalisi, Giuseppe; Crinò, Stefano F; Tortora, Andrea; Giacobbe, Giuseppa; Cintolo, Marcello; Familiari, Luigi; Pallio, Socrate


    The advantages of endoscopic retrograde cholangiopancreatography over open surgery have made it the predominant method of treating patients with choledocholithiasis. After sphincterotomy, however, 10%-15% of common bile duct stones cannot be removed with a basket or balloon. The methods for managing “irretrievable stones” include surgery, mechanical lithotripsy, intraductal or extracorporeal shock wave lithotripsy and biliary stenting. The case presented was a referred 82-year-old Caucasian woman with a 7-year-old plastic biliary endoprosthesis in situ. To the best of our knowledge the examined endoprosthesis is the oldest endoprosthesis in situ reported in the literature. Endoscopic biliary endoprosthesis placement remains a simple and safe procedure for patients with stones that are difficult to manage by conventional endoscopic methods and for patients who are unfit for surgery or who are high surgical risks. To date no consensus has been reached regarding how long a biliary prosthesis should remain in situ. Long-term biliary stenting may have a role in selected elderly patients if stones extraction has failed because the procedure may prevent stones impaction and cholangitis. PMID:23858381

  2. In-situ measurements in Vesivehmaa air field - STUK team

    Energy Technology Data Exchange (ETDEWEB)

    Markkanen, M.; Honkamaa, T.; Niskala, P. [Finnish Centre for Radiation and Nuclear Safety, Helsinki (Finland)


    Nineteen in-situ gamma-ray spectrometric measurements were performed in Vesivehmaa air field on 17th August 1995. The results for {sup 137}Cs and natural radionuclides are in good agreement with the results from soil sampling and laboratory analyses. (au).

  3. Unintended and in situ amorphisation of pharmaceuticals

    DEFF Research Database (Denmark)

    Priemel, P A; Grohganz, H; Rades, T


    by which in situ amorphisation occurs are often not fully understood. In situ amorphisation can be exploited and performed before administration of the drug or possibly even within the gastrointestinal tract, as can be inferred from in situ amorphisation observed during in vitro lipolysis. The use...... of in situ amorphisation can thus confer the advantages of the amorphous form, such as higher apparent solubility and faster dissolution rate, without the disadvantage of its physical instability....

  4. Noise canceling in-situ detection (United States)

    Walsh, David O.


    Technologies applicable to noise canceling in-situ NMR detection and imaging are disclosed. An example noise canceling in-situ NMR detection apparatus may comprise one or more of a static magnetic field generator, an alternating magnetic field generator, an in-situ NMR detection device, an auxiliary noise detection device, and a computer.

  5. U-Pb zircon geochronology of intrusive and basement rocks in the Jacurici Valley region, Sao Francisco Craton, BA, Brazil; Geocronologia U-Pb em zircao de rochas intrusivas e de embasamento na regiao do Vale do Jacurici, Craton do Sao Francisco, BA

    Energy Technology Data Exchange (ETDEWEB)

    Silveira, Carlos Jose Sobrinho da; Frantz, Jose Carlos; Marques, Juliana Charao; Roos, Siegbert; Peixoto, Vinicius Medina, E-mail:, E-mail:, E-mail:, E-mail:, E-mail: [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Laboratorio de Geologia Isotopica; Queiroz, Waldemir Jose Alves de, E-mail: [Companhia de Ferro Ligas da Bahia (FERBASA), Pojuca, BA (Brazil)


    The Jacurici Complex, located in the NE of the Sao Francisco Craton, is constituted by several Cr-mineralized mafic-ultramafic N-S bodies, possible fragments of a single sill disrupted during deformation. Some works suggest it is intruded on the Serrinha Block while others consider it in the Salvador-Curaca Belt. The basement on this region is informally divided into paragneisses and orthogneisses; the latter is supposed to be younger considering it is less deformed. Petrography revealed that some of the paragneisses are alkali-feldspar granite strongly milonitized. The orthogneisses occur at the north and consist, at least in part, of monzogranites with heterogeneous deformation, locally of low temperature. U-Pb zircon dating were performed for five representative samples. Just three provided good concordia ages. A mafic rock produced a 2102 ± 5 Ma age and it is petrographically similar to the metanorites described in the Jacurici Complex, being interpreted as the record of the first pulses of the mafic magmatism. A monzogranite yielded a 2995 ± 15 Ma age, older than expected, related to the Serrinha Block. The alkali-feldspar granite yielded a 2081 ± 3 Ma age. The Itiuba Syenite and the pegmatites that crosscut the Jacurici Complex have similar ages. Considering the lack of information about the supracrustal sequence that hosts the intrusive alkaline and mafic-ultramafic rocks at the Ipueira and the Medrado areas, it is possible that part of the terrain belongs to the Salvador-Curaca Belt. We suggest that the Jacurici Complex could be intruded after the tectonic amalgamation between the Serrinha Block and the older part of the Salvador-Curaca Belt and, therefore, could be hosted by both terrains. (author)

  6. Upper Urinary Tract Carcinoma In Situ: Current Knowledge, Future Direction. (United States)

    Redrow, Grant P; Guo, Charles C; Brausi, Maurizio A; Coleman, Jonathan A; Fernandez, Mario I; Kassouf, Wassim; Keeley, Francis X; Margulis, Vitaly; Raman, Jay D; Roupret, Morgan; Shariat, Shahrokh F; Spiess, Philippe E; Thalmann, George N; Matin, Surena F


    Carcinoma in situ of the urinary tract is a high grade form of nonmuscle invasive urothelial cancer. Our understanding of this entity in the upper tract is poor, and case management remains challenging due to knowledge gaps regarding the definition, diagnosis, treatment options and followup of the disease. We reviewed the available literature for similarities and differences between bladder and upper tract carcinoma in situ, and herein summarize the best available data. We reviewed PubMed® and MEDLINE™ databases from January 1976 through September 2014. The PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) statement was used to screen publications. All authors participated in the development of a consensus definition of disease. A total of 61 publications were found suitable for this review. All studies were retrospective. Compared to bladder carcinoma in situ, upper tract carcinoma in situ appears to have lower progression rates and improved survival. All available studies demonstrate topical therapy to be effective in treating upper tract carcinoma in situ, with decreased recurrence rates compared to bladder carcinoma in situ. Highlighted areas of current knowledge gaps include variable definitions of disease, methods of drug delivery and ideal treatment course. Improving methods for detection may allow easier diagnosis and more effective treatment. Based on the available data, organ preserving therapy with topical agents is an alternative to radical surgery in select patients with upper tract carcinoma in situ, although this method has not been evaluated in prospective trials. A paradigm shift regarding detection and treatment is needed to improve care and allow better renal preservation. A consensus definition of the disease is offered, and several areas of major knowledge gaps and opportunities for future research are identified. Copyright © 2017 American Urological Association Education and Research, Inc. Published by Elsevier

  7. Molybdenite Re/Os dating, zircon U-Pb age and geochemistry of granitoids in the Yangchuling porphyry W-Mo deposit (Jiangnan tungsten ore belt), China: Implications for petrogenesis, mineralization and geodynamic setting (United States)

    Mao, Jingwen; Xiong, Bikang; Liu, Jun; Pirajno, Franco; Cheng, Yanbo; Ye, Huishou; Song, Shiwei; Dai, Pan


    The Yangchuling W-Mo deposit, located in the Jiangnan porphyry-skarn (JNB) tungsten ore belt, is the first recognized typical porphyry W-Mo deposit in China in the 1980's. Stockworks and disseminated W-Mo mineralization occur in the roof pendant of a 0.3 km2 monzogranitic porphyry stock that intruded into a granodiorite stock, hosted by Neoproterozoic phyllite and slate. LA-ICPMS zircon U-Pb analyses suggest that of the monzogranitic porphyry and granodiorite were formed at 143.8 ± 0.5 Ma and 149.8 ± 0.6 Ma, respectively. Six molybdenite samples yielded a Re-Os weighted mean age of 146.4 ± 1.0 Ma. Geochemical data show that both granodiorite and monzogranitic porphyry are characterized by enrichment of large ion lithophile elements (LILE) relative to high field strength elements (HFSE), indicating a peraluminous nature (A/CNK = 1.01-1.08). Two granitoids are characterized by a negative slope with significant light REE/heavy REE fractionation [(La/Yb)N = 8.38-23.20] and negative Eu anomalies (Eu/Eu* = 0.69-0.76). The P2O5 contents of the Yangchuling granitoids range from 0.12% to 0.17% and exhibit a negative correlation with SiO2, reflecting that they are highly fractionated I-type. They have high initial 87Sr/86Sr ratios (0.7104-0.7116), low negative εNd(t) (- 5.05 to - 5.67), and homogeneous εHf(t) between - 1.39 and - 2.17, indicating similar sources. Additionally, two-stage Nd model ages (TDM2) of 1.3-1.4 Ga and two-stage Hf model ages (TDM2) of 1.2-1.3 Ga are consistent, indicating that Neoproterozoic crustal rocks of the Shuangqiaoshan Group could have contributed to form the Yangchuling magmas. Considering the two groups of parallel Late Mesozoic ore belts, namely the Jiangnan porphyry-skarn tungsten belt (JNB) in the south and the Middle-Lower Yangtze River porphyry-skarn Cu-Au-Mo-Fe ore belt (YRB) in the north, the Nanling granite-related W-Sn ore belt (NLB) in the south, the neighboring Qin-Hang porphyry-skarn Cu-Mo-hydrothermal Pb-Zn-Ag ore belt (QHB

  8. Multiple Stage Ore Formation in the Chadormalu Iron Deposit, Bafq Metallogenic Province, Central Iran: Evidence from BSE Imaging and Apatite EPMA and LA-ICP-MS U-Pb Geochronology

    Directory of Open Access Journals (Sweden)

    Hassan Heidarian


    Full Text Available The Chadormalu magnetite-apatite deposit in Bafq metallogenic province, Central Iran, is hosted in the late Precambrian-lower Cambrian volcano-sedimentary rocks with sodic, calcic, and potassic alterations characteristic of iron oxide copper-gold (IOCG and iron oxide-apatite (IOA ore systems. Apatite occurs as scattered irregular veinlets and disseminated grains, respectively, within and in the marginal parts of the main ore-body, as well as apatite-magnetite veins in altered wall rocks. Textural evidence (SEM-BSE images of these apatites shows primary bright, and secondary dark areas with inclusions of monazite/xenotime. The primary, monazite-free fluorapatite contains higher concentrations of Na, Si, S, and light rare earth elements (LREE. The apatite was altered by hydrothermal events that led to leaching of Na, Si, and REE + Y, and development of the dark apatite. The bright apatite yielded two U-Pb age populations, an older dominant age of 490 ± 21 Ma, similar to other iron deposits in the Bafq district and associated intrusions, and a younger age of 246 ± 17 Ma. The dark apatite yielded a U-Pb age of 437 ± 12 Ma. Our data suggest that hydrothermal magmatic fluids contributed to formation of the primary fluorapatite, and sodic and calcic alterations. The primary apatite reequilibrated with basinal brines in at least two regional extensions and basin developments in Silurian and Triassic in Central Iran.

  9. Titanite chronology, thermometry, and speedometry of ultrahigh-temperature (UHT) calc-silicates from south Madagascar: U-Pb dates, Zr temperatures, and lengthscales of trace-element diffusion (United States)

    Holder, R. M.; Hacker, B. R.


    Calc-silicate rocks are often overlooked as sources of pressure-temperature-time data in granulite-UHT metamorphic terranes due to the strong dependence of calc-silicate mineral assemblages on complex fluid compositions and a lack of thermodynamic data on common high-temperature calc-silicate minerals such as scapolite. In the Ediacaran-Cambrian UHT rocks of southern Madagascar, clinopyroxene-scapolite-feldspar-quartz-zircon-titanite calc-silicate rocks are wide-spread. U-Pb dates of 540-520 Ma from unaltered portions of titanite correspond to cooling of the rocks through upper-amphibolite facies and indicate UHT metamorphism occurred before 540 Ma. Zr concentrations in these domains preserve growth temperatures of 900-950 °C, consistent with peak temperatures calculated by pseudosection modeling of nearby osumilite-bearing gneisses. Younger U-Pb dates (510-490 Ma) correspond to fluid-mediated Pb loss from titanite grains, which occurred below their diffusive Pb-closure temperature, along fractures. The extent of fluid alteration is seen clearly in back-scattered electron images and Zr-, Al-, Fe-, Ce-, and Nb-concentration maps. Laser-ablation depth profiling of idioblastic titanite grains shows preserved Pb diffusion profiles at grain rims, but there is no evidence for Zr diffusion, indicating that it was effectively immobile even at UHT.

  10. Geotectonic structural interpretation of the basement complex at the eastern border of the Espinhaco ridge, in Guanhaes and Gouveia region, based on an integration of their U/Pb and K/Ar geochronology united

    International Nuclear Information System (INIS)

    Teixeira, W.; Salvador, E.D.; Siga Junior, O.; Sato, K.; Dossin, I.A.; Dossin, T.M.


    The basement complex at the eastern border of the Espinhaco ridge is composed of predominantly gneissic rocks which were subjected to migmatization and granitization. Overall the area shows complex tectonic evolution with recurrence of tectonomagmatic and metamorphic events as supported by geological, geochronological and structural studies. The Rb/Sr geochronology carried out on the basement rocks and metavolcanics from the Espinhaco interpreted together with the published U-Pb, Rb-Sr and K-Ar data defines the following scenario for the Precambrian crustal evolution. 1. Primary origin of a sialic crust at 2.97-2.84 Ga. ago as supported by U-Pb zircon ages. 2. Crustal reworking of the Archean crust and subordinate juvenile accretion from upper mantle during the 2.2-2.OGa. period, as suggested by the isochrons. 3. Recurrence of Middle Proterozoic events over the basement rocks (gneisses and charnockites) and metavolcanics of the Espinhaco as showed by isochrons. 4. Development of Late Proterozoic migmatization over the basement rocks (0.75 Ga., R.I.= 0.787) is association with Collisional tectonics and resetting of K-Ar mineral systems. (author)

  11. The ongoing search for the oldest rock on the Danish island of Bornholm: new U-Pb zircon ages for a quartz-rich xenolith and country rock from the Svaneke Granite

    DEFF Research Database (Denmark)

    Waight, Tod Earle; Serre, Simon H.; Næsby, Sebastian H.


    Previous geochronological studies on the Danish island of Bornholm have not identified any rocks older than c. 1.46 Ga. New LA-ICP-MS U-Pb zircon ages are presented for a xenolith within, and the country rock gneiss adjacent to, the Svaneke Granite on Bornholm. The xenolith is fine-grained and qu......Previous geochronological studies on the Danish island of Bornholm have not identified any rocks older than c. 1.46 Ga. New LA-ICP-MS U-Pb zircon ages are presented for a xenolith within, and the country rock gneiss adjacent to, the Svaneke Granite on Bornholm. The xenolith is fine...... been a felsic volcanic or shallow intrusive rock. A skarn-like inclusion from a nearby locality likely represents an originally carbonate sediment and is consistent with supracrustal rocks being present at least locally. Zircon data from the xenolith define an upper intercept age of 1483 ± 12 Ma (2σ......, MSWD = 2.5) with a poorly defined lower intercept age of 474 ± 250 Ma, and a weighted average 207Pb/206Pb age of 1477.9 ± 4.6 Ma; both these ages are older than the host Svaneke Granite (weighted average 207Pb/206Pb age of 1465.0 ± 4.8 Ma). Zircons from the gneiss define an upper intercept age of 1477...

  12. Isotopegeochemical investigations and dating on minerals and fossils from sedimentary rocks: 1. Glauconites from Jura, Molasse and Helveticum (K-Ar, Rb-Sr), 2. 87Sr/86Sr-Isotope stratigraphy on marine and limnetic micro- and macro-fossils, 3. Primary minerals from tertiary bentonites and tuffs (U-Pb, K-Ar)

    International Nuclear Information System (INIS)

    Fischer, H.


    Glauconite investigations: the main problem in dating glauconites lies in the identification of authigenic minerals which have not been influenced by post-sedimentary processes. The age determination on glauconites from the three different tectonic units: the Jura mountains, the molasse basin and the Helvetic nappes, yield inconsistent results. Up to 35% too young K-Ar ''ages'' of glauconites from limestones from the Helvetic nappes can be traced to partial Ar loss caused by sediment-lithification and tectonic events. Sr-isotope stratigraphy: multiple analyses of recent samples from the Mediterranean Sea and from the North Atlantic show that the 87 Sr/ 86 Sr isotope ratios correspond well. In a stratigraphic ideal section from the Upper marine molasse a resolution of 206 Pb/ 238 U method zircons from the Fish Canyon Tuff were measured and yielded ages of 28.49±0.10, 24.46±0.11 and 28.46±0.13 Ma. These values correspond well with the published mean value of zircon and apatite fission track age of 28.4±0.7 Ma. Thus, the U-Pb method for dating young volcanic minerals seems to be suitable. However, the published mean value (''solid state age'') of Naeser et al. (1981) is higher than the published (''gas age'') mean value of 27.2±0.7 Ma based on biotite, sanidine, hornblende and plagioclase. (author) figs., tabs., refs

  13. In-situ dating of the Earth's oldest trace fossil at 3.34 Ga (United States)

    Fliegel, D.; Kosler, J.; McLoughlin, N.; Simonetti, A.; de Wit, M. J.; Wirth, R.; Furnes, H.


    Microbial activity in volcanic glass within the oceanic crust can produce micron sized pits and tunnels. Such biogenic textures have been described from the recent oceanic crust and mineralized equivalents in pillow lavas as old as 3.47-3.45 Ga from the Barberton Greenstone Belt (BGB) of South Africa. In meta-volcanic glasses these microbial traces are preserved by titanite mineralization (CaTiSiO 5) and on the basis of morphological, textural and geochemical evidence have been argued to represent Earth's oldest trace fossils. Here we report the results of in-situ U-Pb dating of titanite that infills trace fossils from the Hooggenoeg Complex of the BGB using laser ablation MC-ICP-MS (multi-collector inductively coupled, plasma mass spectrometry). This yields a titanite age of 3.342 ± 0.068 Ga demonstrating the antiquity of the BGB trace fossils. This radiometric age confirms that a sub-seafloor biosphere was already established in the PaleoArchean and that it likely represented an important habitat for the emergence and evolution of early microbial life on the Earth.

  14. In Situ Field Testing of Processes

    International Nuclear Information System (INIS)

    Wang, J.


    The purpose of this Analysis/Model Report (AMR) is to update and document the data and subsequent analyses from ambient field-testing activities performed in underground drifts of the Yucca Mountain Site Characterization Project (YMP). This revision updates data and analyses presented in the initial issue of this AMR. This AMR was developed in accordance with the ''Technical Work Plan for Unsaturated Zone (UZ) Flow and Transport Process Model Report'' and ''Technical Work Plan for UZ Flow, Transport, and Coupled Processes Process Model Report. These activities were performed to investigate in situ flow and transport processes. The evaluations provide the necessary framework to: (1) refine and confirm the conceptual model of matrix and fracture processes in the unsaturated zone (UZ) and (2) analyze the impact of excavation (including use of construction water and effect of ventilation) on the UZ flow and transport processes. This AMR is intended to support revisions to ''Conceptual and Numerical Models for UZ Flow and Transport'' and ''Unsaturated Zone Flow and Transport Model Process Model Report''. In general, the results discussed in this AMR are from studies conducted using a combination or a subset of the following three approaches: (1) air-injection tests, (2) liquid-release tests, and (3) moisture monitoring using in-drift sensors or in-borehole sensors, to evaluate the impact of excavation, ventilation, and construction-water usage on the surrounding rocks. The liquid-release tests and air-injection tests provide an evaluation of in situ fracture flow and the competing processes of matrix imbibition. Only the findings from testing and data not covered in the ''Seepage Calibration Model and Seepage Testing Data'' are analyzed in detail in the AMR

  15. In Situ Field Testing of Processes

    Energy Technology Data Exchange (ETDEWEB)

    J. Wang


    The purpose of this Analysis/Model Report (AMR) is to update and document the data and subsequent analyses from ambient field-testing activities performed in underground drifts of the Yucca Mountain Site Characterization Project (YMP). This revision updates data and analyses presented in the initial issue of this AMR. This AMR was developed in accordance with the ''Technical Work Plan for Unsaturated Zone (UZ) Flow and Transport Process Model Report'' and ''Technical Work Plan for UZ Flow, Transport, and Coupled Processes Process Model Report. These activities were performed to investigate in situ flow and transport processes. The evaluations provide the necessary framework to: (1) refine and confirm the conceptual model of matrix and fracture processes in the unsaturated zone (UZ) and (2) analyze the impact of excavation (including use of construction water and effect of ventilation) on the UZ flow and transport processes. This AMR is intended to support revisions to ''Conceptual and Numerical Models for UZ Flow and Transport'' and ''Unsaturated Zone Flow and Transport Model Process Model Report''. In general, the results discussed in this AMR are from studies conducted using a combination or a subset of the following three approaches: (1) air-injection tests, (2) liquid-release tests, and (3) moisture monitoring using in-drift sensors or in-borehole sensors, to evaluate the impact of excavation, ventilation, and construction-water usage on the surrounding rocks. The liquid-release tests and air-injection tests provide an evaluation of in situ fracture flow and the competing processes of matrix imbibition. Only the findings from testing and data not covered in the ''Seepage Calibration Model and Seepage Testing Data'' are analyzed in detail in the AMR.

  16. Late Palaeozoic magmatism in the northern New England Orogen - evidence from U-Pb SHRIMP dating in the Yarrol and Connors provinces, central Queensland

    International Nuclear Information System (INIS)

    Withnall, I.W.; Hutton, L.J.; Hayward, M.A.; Blake, P.; Fanning, C.M.; Burch, G.


    Full text: The northern part of the New England Orogen in central Queensland has been divided into three provinces, which are from east to west, the Wandilla, Yarrol and Connors Provinces. Previous workers suggested that the provinces are elements in an Early Carboniferous west-dipping subduction system with the Wandilla Province representing the accretionary wedge, the Yarrol Province a forearc basin and the Connors Province the volcanic arc. Farther west, a fourth province, the Drummond Basin, is interpreted as a back-arc basin. The Connors Province crops out in two areas, the Auburn Arch in the south and Connors Arch in the north. Prior to the present study, some workers recognised two superimposed volcanic arcs, one in the Late Devonian and a second in the Early Permian. Other workers have challenged this model suggesting that the rocks in the Connors Province were mainly Late Carboniferous to Early Permian and that they recorded a period of continental extension. U-Pb SHRIMP dating in the Connors Province has confirmed the existence of at least episodic Early Carboniferous magmatism from the Tournaisian to Namurian in both the Auburn and Connors Arches. We suggest that the Tournaisian rocks are vestiges of the Early Carboniferous volcanic arc suggested by earlier workers. Ages of ∼350Ma and ∼349Ma in the Connors Province are similar to ages for volcanics in Cycle 1 in the Drummond Basin and to volcanics in the lower part of the Rockhampton Group in the Yarrol Province. Magmatism in the Drummond Basin and Yarrol Province continued into the Visean although no early Visean rocks have yet been recognised in the Connors Province. The mid-Carboniferous (late Visean) may represent an important change in the evolution of the region. East of the Auburn Arch, in the Yarrol Province, this time corresponds to the boundary between the Rockhampton Group and Lorray Formation, and is marked by a sudden increase in regional radiometric response. It represents the start of

  17. Precise U-Pb dating of Cenozoic tropical reef carbonates: Linking the evolution of Cenozoic Caribbean reef carbonates to climatic and environmental changes. (United States)

    Silva-Tamayo, J. C.; Ducea, M.; Cardona, A.; Montes, C.; Rincon, D.; Machado, A.; Flores, A.; Sial, A.; Pardo, A.; Niño, H.; Ramirez, V.; Jaramillo, C.; Zapata, P.; Barrios, L.; Rosero, S.; Bayona, G.; Zapata, V.


    rapid anthropogenic CO2 release to the atmosphere on reef areas. Here we report precise U-Pb ages of several Cenozoic Caribbean-tropical reef carbonate successions along the SE Circum-Caribbean Region from which major temporal variations in the reef carbonate factories, structure and ecology are related to major climate/environmental changes. Calcareous algae are the principal calcifying reef builders along the SE Circum-Caribbean during the Paleocene-middle Oligocene interval, a period of predominant high atmospheric pCO2 and OA. Calcareous algae persisted as the main calcifying reef builders until the late Oligocene when atmospheric pCO2 levels dropped, allowing the onset of global icehouse conditions and the appearance of corals as the main calcifying reef builders along the SE Circum-Caribbean. Coral reefs would have dominated until the middle Miocene, when a new period of calcareous algae reefs occurred along the Caribbean, coinciding with the Miocene thermal optimum in mid-latitude areas (i.e. the Mediterranean). Coral reef carbonates dominated since the Pliocene. From the data presented here we suggest that calcareous algae dominated were the main calcifying reef builders during periods of warm temperatures and pronounced environmental change in the tropical seas (i.e. OA). Corals would have conversely dominated as main calcifying reef builders during periods of optimal tropical climatic/environmental conditions. Comparisons between this geologic conditions and data for the period 1984-2006 in the Caribbean11 suggest that the transition from corals towards calcareous algae is repeating again. 1.Zachos et al., Science Mag. 292 (2001) 2.Zachos et al., Science Mag. 308 (2005) 3.Haug et al., Geology 29 (2001) 4.Jain and Collins, Marine Micropaleo. 62 (2007) 5.Merinco et al., Nature 452 (2008) 6.O'Dea et al., Proc. Nat. Acad. Sci. 104 (2007) 7.Jhonson et al., Palaios 24(2009) 8.Pagani et al., Nature 460 (2007) 9.Cohen et al., Journ. Geolog. Society 164 (2009) 10

  18. Four Models of In Situ Simulation

    DEFF Research Database (Denmark)

    Musaeus, Peter; Krogh, Kristian; Paltved, Charlotte


    Introduction In situ simulation is characterized by being situated in the clinical environment as opposed to the simulation laboratory. But in situ simulation bears a family resemblance to other types of on the job training. We explore a typology of in situ simulation and suggest that there are f...... to team intervention and philosophies informing what good situated learning research is. This study generates system knowledge that might inform scenario development for in situ simulation.......Introduction In situ simulation is characterized by being situated in the clinical environment as opposed to the simulation laboratory. But in situ simulation bears a family resemblance to other types of on the job training. We explore a typology of in situ simulation and suggest...... that there are four fruitful approaches to in situ simulation: (1) In situ simulation informed by reported critical incidents and adverse events from emergency departments (ED) in which team training is about to be conducted to write scenarios. (2) In situ simulation through ethnographic studies at the ED. (3) Using...

  19. Geology, petrology and U-Pb geochronology of Serra da Rajada Granitic Pluton: implications about ediacaran magmatic evolution in NE portion of the Rio Piranhas-Serido Domain (NE of Borborema Province); Geologia, petrologia e geocronologia U-Pb do Pluton Granitico Serra da Rajada: implicacoes sobre a evolucao magmatica ediacarana na porcao do Dominio Rio Piranhas-Serido (NE da Provincia Borborema)

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Alan Pereira da; Dantas, Alexandre Ranier, E-mail:, E-mail: [Servico Geologico do Brasil (CPRM), Natal, RN (Brazil). Nucleo de Apoio de Natal/Superintendencia Regional de Recife; Nascimento, Marcos Antonio Leite do; Galindo, Antonio Carlos, E-mail:, E-mail: [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Departamento de Geologia


    The Ediacaran plutonic activity, related to the Brazilian/Pan-African orogeny, is one of the most important geological features in the Borborema Province, formed by batholiths, stocks and dikes. The Serra da Rajada Granitic Pluton (SRGP), located in the central portion of the Rio Piranhas-Serido Domain, is an example of these bodies. This site is the target of cartographic, petrographic, lithochemical and geochronological studies. Its rocks are described as monzogranites consisting of K-feldspar, plagioclase (oligoclase-An{sub 23-24%}), quartz and biotite (main mafic), having as accessory minerals opaque, titanite, allanite, apatite and zircon. Chlorite, white mica and carbonate are alteration minerals. Lithochemical data from 15 samples show quite evolved rocks (SiO{sub 2} , 69% to 75%), rich in alkalis (Na{sub 2}O + K{sub 2}O ≥ 8.0%), depleted in MgO (≤ 0.45%), CaO (≤ 1.42%) and TiO{sub 2} (≤ 0.36%), and displaying moderate levels of Fe{sub 2}O{sub 3} t (2.16 to 3.53%). These rocks present a transitional nature between metaluminous and peraluminous (predominance of the latter) and have subalkaline/monzonitic affinity (high-K Calc-alkaline). Harker diagrams represent negative correlations in Fe{sub 2}O{sub 3}t, MgO and CaO, indicating fractionation of mafic and plagioclase. The REE spectrum show enrichment of light in relation to heavy REE (LaN/YbN = 23.70 to 10.13), with negative anomaly in Eu (Eu/ Eu* = 0.70 to 10.13) suggesting fractionation or accumulation in the feldspars source (plagioclase). Data integration allows correlating the SRGP rocks with those described as Equigranular high-K Calc-alkaline Suite. The U-Pb geochronology and Sm-Nd isotope dating indicate that the biotite monzogranite have a crystallization age of 557 ± 13 Ma and TDM model age of 2.36 Ga, respectively, and ε{sub Nd} value of - 20.10 for the crystallization age, allowing to infer a crustal source for the magma generated in the Paleoproterozoic age. (author)

  20. In situ dating of the oldest morphological traces of life on Earth (United States)

    Fliegel, D.; McLoughlin, N.; Simonetti, A.; de Wit, M.; Furnes, H.


    Sea floor pillow basalts contain tubular and granular bioalteration micro textures in their glassy margins1,2 created by microbes etching the rock3,4, hypothetically to get access to nutrients and electrons donors5. The etched pits in the rock can be regarded as trace fossils6 that later become mineralized by titanite (CaTiSiO5). Such trace fossils are known from recent oceanic crust to some of the oldest preserved Archean ocean floor, in the Barberton greenstone belt (BGB), in S-Africa7. However, the antiquity of BGB trace fossils has been questioned by some since only the host rock was dated until now8. Here, we report for the first time in situ U-Pb radiometric dating of titanite mineralizing the BGB trace fossils using LA-MC-ICPMS. An U-Pb date of of approx. 3.15 ± 0.05 Ga (95.4 % confidence) for the titanite demonstrates the antiquity of the BGB trace fossils. This result confirms the BGB trace fossils as the oldest directly dated morphological trace of life on Earth. We will present addition data to reveal the mineralization of trace fossils by titanite, comparing the BGB trace fossils to other similar tubular titanite mineralized textures from different locations and younger ages. Our data confirms that a sub-oceanic biosphere was already established in the early Archean by at least 3.2 Ga. Further the results highlight the importance of the sub-ocean habitats for the development and possibly refuge for life on (early) Earth. 1. Furnes, H. et al. Bioalteration of basaltic glass in the oceanic crust. Geochemistry Geophysics Geosystems 2, (2001). 2. Staudigel, H. et al. 3.5 billion years of glass bioalteration: vulcanic rocks as a basis for microbial life. Earth-Science Reviews 89, 156-176 (2008). 3. Furnes, H. et al. Links Between Geological Processes, Microbial Activeties and Evolution of Life. Dilek, Y., Furnes, H. and Muehlenbachs, K. (eds.), pp. 1-68 (Springer,2008). 4. McLoughlin, N. et al. Current Developments in Bioerosion (Erlangen Earth Conference

  1. In situ bypass og diabetes

    DEFF Research Database (Denmark)

    Jensen, Leif Panduro; Schroeder, T V; Lorentzen, J E


    decreased survival rate was found in diabetics (p treatment of critical ischaemia of the lower limb in diabetic patients. The overall results in diabetic patients, whether insulin-dependent or not, were equal to those in non-diabetic......From 1986 through to 1990 a total of 483 in situ bypass procedures were performed in 444 patients. Preoperative risk-factors were equally distributed among diabetic (DM) and non-diabetic (NDM) patients, except for smoking habits (DM:48%, NDM:64%, p = 0.002) and cardiac disease (DM:45%, NDM:29%, p...... = 0.005). Critical limb-ischaemia was more often present in diabetic than non-diabetic patients (DM:57%, NDM:36%, p = 0.0002). Diabetic patients had a significantly lower distal anastomosis than non-diabetic patients (p = 0.00001). There were no differences among diabetic and non-diabetic patients...

  2. In-situ measurement system (United States)

    Lord, David E.


    A multipurpose in situ underground measurement system comprising a plurality of long electrical resistance elements in the form of rigid reinforcing bars, each having an open loop "hairpin" configuration of shorter length than the other resistance elements. The resistance elements are arranged in pairs in a unitized structure, and grouted in place in the underground volume. The electrical resistance of each element and the difference in electrical resistance of the paired elements are obtained, which difference values may be used in analytical methods involving resistance as a function of temperature. A scanner sequentially connects the resistance-measuring apparatus to each individual pair of elements. A source of heating current is also selectively connectable for heating the elements to an initial predetermined temperature prior to electrical resistance measurements when used as an anemometer.

  3. DOE In Situ Remediation Integrated Program

    International Nuclear Information System (INIS)

    Yow, J.L. Jr.


    The In Situ Remediation Integrated Program (ISRP) supports and manages a balanced portfolio of applied research and development activities in support of DOE environmental restoration and waste management needs. ISRP technologies are being developed in four areas: containment, chemical and physical treatment, in situ bioremediation, and in situ manipulation (including electrokinetics). the focus of containment is to provide mechanisms to stop contaminant migration through the subsurface. In situ bioremediation and chemical and physical treatment both aim to destroy or eliminate contaminants in groundwater and soils. In situ manipulation (ISM) provides mechanisms to access contaminants or introduce treatment agents into the soil, and includes other technologies necessary to support the implementation of ISR methods. Descriptions of each major program area are provided to set the technical context of the ISM subprogram. Typical ISM needs for major areas of in situ remediation research and development are identified

  4. In Situ Transmission Electron Microscopy for Electronics


    Arita, Masashi; Hamada, Kouichi; Takahashi, Yasuo; Sueoka, Kazuhisa; Shibayama, Tamaki


    Electronic devices are strongly influenced by their microstructures. In situ transmission electron microscopy (in situ TEM) with capability to measure electrical properties is an effective method to dynamically correlate electric properties with microstructures. We have developed tools and in situ TEM experimental procedures for measuring electronic devices, including TEM sample holders and sample preparation methods. The method was used to study metallic nanowire by electromigration, magn...

  5. In Situ Hybridization Pada Kanker Payudara


    Diah Witari, Ni Putu


    Kesulitan yang dijumpai pada penanganan kanker payudara adalah terjadinya kekambuhan atau relaps. Deteksi status HER2 pada pasien merupakan salah satu upaya untuk mendeteksi terjadinya relaps dan juga untuk menentukan jenis terapi yang ada diberikan. Ekspresi protein HER2 dapat dideteksi dengan immunohistochemistry (IHC), sedangkan mutasi gen HER2 dapat dideteksi dengan teknik in situ hybridization baik berupa fluorescence in situ hybridization (FISH) ataupun chromogenic in situ hy...

  6. Training for teamwork through in situ simulations (United States)

    Sorensen, Asta; Poehlman, Jon; Bollenbacher, John; Riggan, Scott; Davis, Stan; Miller, Kristi; Ivester, Thomas; Kahwati, Leila


    In situ simulations allow healthcare teams to practice teamwork and communication as well as clinical management skills in a team's usual work setting with typically available resources and equipment. The purpose of this video is to demonstrate how to plan and conduct in situ simulation training sessions, with particular emphasis on how such training can be used to improve communication and teamwork. The video features an in situ simulation conducted at a labour and delivery unit in response to postpartum hemorrhage. PMID:26294962

  7. Linking zircon age to metamorphic stage using U-Pb/REE depth-profiling of zircon combined with Lu-Hf garnet geochronology (United States)

    Briggs, Sophie; Cottle, John; Smit, Matthijs; Arnush, Nicole


    The relatively novel approach of LASS-ICP-MS depth-profiling in zircon has enabled the analysis of sub-micrometer, isotopically/geochemically distinct zircon domains which are too thin to be analyzed by other in situ methods. The depth-profiling approach has proven to be particularly useful in targeting thin and discontinuous metamorphic zircon overgrowths, which are evidently capable of recording multiple short-duration tectonothermal events. Based on our knowledge of rare earth element (REE) partitioning between equilibrium zircon and garnet, it is possible to link LASS depth-profile data to specific metamorphic events, and discern the timing of garnet growth versus garnet breakdown. Here we test the potential of this approach by applying LASS-ICP-MS depth profiling in zircon to samples from the Alpine Schist (New Zealand) that have been dated previously by Lu-Hf garnet geochronology. Our results show that thin (Zealandia microcontinent from East Gondwana during 83 - 52 Ma. These results provide constraints on the P-T-t conditions recorded in the Alpine Schist during this period, with implications for the geodynamic processes involved in microcontinent formation.

  8. The SENSEI Generic In Situ Interface

    Energy Technology Data Exchange (ETDEWEB)

    Ayachit, Utkarsh [Kitware, Inc., Clifton Park, NY (United States); Whitlock, Brad [Intelligent Light, Rutherford, NJ (United States); Wolf, Matthew [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Loring, Burlen [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Geveci, Berk [Kitware, Inc., Clifton Park, NY (United States); Lonie, David [Kitware, Inc., Clifton Park, NY (United States); Bethel, E. Wes [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)


    The SENSEI generic in situ interface is an API that promotes code portability and reusability. From the simulation view, a developer can instrument their code with the SENSEI API and then make make use of any number of in situ infrastructures. From the method view, a developer can write an in situ method using the SENSEI API, then expect it to run in any number of in situ infrastructures, or be invoked directly from a simulation code, with little or no modification. This paper presents the design principles underlying the SENSEI generic interface, along with some simplified coding examples.

  9. Geocronologia U/PB em zircões detríticos e a evolução tectônica e estratigráfica da bacia espinhaço no setor meridional


    Santos, Marcelo Nascimento dos


    O Supergrupo Espinhaço em Minas Gerais representa um importante registro de bacias sedimentares intracontinentais desenvolvidas no Orógeno Araçuaí e no Cráton do São Francisco durante o Proterozoico. A presente tese tem o objetivo de esclarecer aspectos relacionados à proveniência sedimentar da Bacia Espinhaço e propor um modelo de evolução paleogeográfica para o Grupo Conselheiro Mata com base na integração de dados sedimentológicos e estratigráficos, geoquímica em rocha total, datação U-Pb ...

  10. Idades SHRIMP U-Pb do Complexo Sertânia: Implicações Sobre a Evolução Tectônica da Zona Transversal, Província Borborema


    Benjamim Bley de Brito Neves; Allen P. Nutman; Edilton José dos Santos


    O Complexo Sertânia é uma seqüência metassedimentar com pequena contribuição metavulcânica, de facies anfibolitoalto, que ocorre no Terreno Alto Moxotó, Zona Transversal da Província Borborema. Vários levantamentos geológicos têmincluído esta unidade num complexo gnáissico-migmatítico indiviso, questionando, por decorrência, a subdivisão de terrenosproposta para esse domínio litotectônico. O presente trabalho apresenta as primeiras idades geocronológicas U-Pb SHRIMPem zircão e dados isotópico...

  11. Middle Neoproterozoic (ca. 705-716 Ma) arc to rift transitional magmatism in the northern margin of the Yangtze Block: Constraints from geochemistry, zircon U-Pb geochronology and Hf isotopes (United States)

    Wang, Ruirui; Xu, Zhiqin; Santosh, M.; Xu, Xianbing; Deng, Qi; Fu, Xuehai


    The South Qinling Belt in Central China is an important window to investigate the Neoproterozoic tectono-magmatic processes along the northern margin of the Yangtze Block. Here we present whole-rock geochemistry, zircon U-Pb geochronology and Lu-Hf isotopes of a suite of Middle Neoproterozoic intrusion from the Wudang Uplift in South Qinling. Zircon LA-ICP-MS U-Pb ages reveal that these rocks were formed at ca. 705-716 Ma. Geochemical features indicate that the felsic magmatic rocks are I-type granitoids, belong to calcic- to calc-alkaline series, and display marked negative Nb, Ta and Ti anomalies. Moreover, the enrichment of light rare earth elements (LREEs) and large ion lithophile elements (LILEs), combined with depletion of heavy rare earth elements (HREEs) support that these rocks have affinity to typical arc magmatic rocks formed in Andean-type active continental margins. The REE patterns are highly to moderately fractionated, with (La/Yb)N = 5.13-8.10 in meta-granites, and 2.32-2.35 in granodiorite. The granitoids have a wide range of zircon εHf(t) values (-29.91 to 14.76) and zircon Hf two-stage model ages (696-3482 Ma). We suggest that the ca. 705-716 Ma granitoids were sourced from different degrees of magma mixing between partial melting of the overlying mantle wedge triggered by hydrous fluids released from subducted materials and crustal melting. The hybrid magmas were emplaced in the shallow crust accompanied by assimilation and fractional crystallization (AFC). Both isotopic and geochemical data suggest that the ca. 705-716 Ma felsic magmatic rocks were formed along a continental arc. These rocks as well as the contemporary A-type granite may mark a transitional tectonic regime from continental arc to rifting, probably related to slab rollback during the oceanic subduction beneath the northern margin of Yangtze Block.

  12. The Eocene Thermal Maximum 2 (ETM-2) in a terrestrial section of the High Arctic: identification by U-Pb zircon ages of volcanic ashes and carbon isotope records of coal and amber (Stenkul Fiord, Ellesmere Island, Canada) (United States)

    Reinhardt, Lutz; von Gosen, Werner; Piepjohn, Karsten; Lückge, Andreas; Schmitz, Mark


    The Stenkul Fiord section on southern Ellesmere Island reveals largely fluvial clastic sediments with intercalated coal seams of the Margaret Formation of Late Paleocene/Early Eocene age according to palynology and vertebrate remains. Field studies in recent years and interpretative mapping of a high-resolution satellite image of the area southeast of Stenkul Fiord revealed that the clastic deposits consist of at least four sedimentary units (Units 1 to 4) separated by unconformities. Several centimeter-thin volcanic ash layers, recognized within coal layers and preserved as crandallite group minerals (Ca-bearing goyazite), suggest an intense volcanic ash fall activity. Based on new U-Pb zircon ages (ID-TIMS) of three ash layers, the volcanic ash fall took place at 53.7 Ma in the Early Eocene, i.e. within the Eocene Thermal Maximum 2 (ETM-2) hyperthermal. The ETM-2 is bracketed further by discrete negative excursions of carbon isotope records of both bulk coal and amber droplets collected from individual coal layers of the section. The identification of the ETM-2 hyperthermal provides a stratigraphic tie-point in the terrestrial Margaret Formation sediments enabling assignment of the lowermost sedimentary Unit 1 to the Late Paleocene-earliest Eocene, Unit 2 to the Early Eocene, whereas Unit 3 and 4 might be Early to Middle Eocene in age. Thus the timing of syn-sedimentary movements of the Eurekan deformation causal for the observed unconformities in the section can be studied and the positions of further hyperthermals like the PETM or the ETM-3 in the section can be identified in the future. The integration of structural studies, new U-Pb zircon ages, and different carbon isotope records provides a new stratigraphic framework for further examination of the unique Early Eocene flora and fauna preserved in this high-latitude outcrop.

  13. Neoproterozoic-Early Paleozoic Peri-Pacific Accretionary Evolution of the Mongolian Collage System: Insights From Geochemical and U-Pb Zircon Data From the Ordovician Sedimentary Wedge in the Mongolian Altai (United States)

    Jiang, Y. D.; Schulmann, K.; Kröner, A.; Sun, M.; Lexa, O.; Janoušek, V.; Buriánek, D.; Yuan, C.; Hanžl, P.


    Neoproterozoic to early Paleozoic accretionary processes of the Central Asian Orogenic Belt have been evaluated so far mainly using the geology of ophiolites and/or magmatic arcs. Thus, the knowledge of the nature and evolution of associated sedimentary prisms remains fragmentary. We carried out an integrated geological, geochemical, and zircon U-Pb geochronological study on a giant Ordovician metasedimentary succession of the Mongolian Altai Mountains. This succession is characterized by dominant terrigenous components mixed with volcanogenic material. It is chemically immature, compositionally analogous to graywacke, and marked by significant input of felsic to intermediate arc components, pointing to an active continental margin depositional setting. Detrital zircon U-Pb ages suggest a source dominated by products of early Paleozoic magmatism prevailing during the Cambrian-Ordovician and culminating at circa 500 Ma. We propose that the Ordovician succession forms an "Altai sedimentary wedge," the evolution of which can be linked to the geodynamics of the margins of the Mongolian Precambrian Zavhan-Baydrag blocks. This involved subduction reversal from southward subduction of a passive continental margin (Early Cambrian) to the development of the "Ikh-Mongol Magmatic Arc System" and the giant Altai sedimentary wedge above a north dipping subduction zone (Late Cambrian-Ordovician). Such a dynamic process resembles the tectonic evolution of the peri-Pacific accretionary Terra Australis Orogen. A new model reconciling the Baikalian metamorphic belt along the southern Siberian Craton with peri-Pacific Altai accretionary systems fringing the Mongolian microcontinents is proposed to explain the Cambro-Ordovician geodynamic evolution of the Mongolian collage system.

  14. U-Pb zircon and 40Ar/39Ar geochronology of sericite from hydrothermal alteration zones: new constraints for the timing of Ediacaran gold mineralization in the Sukhaybarat area, western Afif terrane, Saudi Arabia (United States)

    Harbi, Hesham M.; Ali, Kamal A.; McNaughton, Neal J.; Andresen, Arild


    The Sukhaybarat East and Red Hill deposits, in the northeastern part of the Arabian Shield, are mesothermal vein-type gold deposits hosted by late Cryogenian-Ediacaran intrusive rocks of the Idah suites (diorite, tonalite, granodiorite) and, at Sukhaybarat East, also by Ediacaran metasedimentary rocks. Gold mineralization comprises quartz-arsenopyrite veins (Sukhaybarat East), quartz-carbonate-pyrite veins (Red Hill), and subordinate gold-base metal sulfide veins. In the Red Hill deposit, alteration is complicated due to multiple overprinting hydrothermal events and is characteristically affected by pervasive, pink quartz-K-feldspar-hematite alteration which is overprinted by potassic alteration characterized by a quartz-biotite-carbonate-muscovite/sericite-rutile-apatite assemblage. This assemblage is associated with molybdenite veins which appear to form late in the paragenetic sequence and may represent either evolution of the ore fluid composition, or a later, unrelated mineralized fluids. Hydrothermal alteration at the Sukhaybarat East deposit is dominated by quartz-carbonate-sericite-arsenopyrite assemblages. Zircon from ore-hosting tonalite at Sukhaybarat East yields a U-Pb age of 629 ± 6 Ma, and biotite from the same rock gives an 40Ar/39Ar age of 622 ± 23 Ma. The 40Ar/39Ar age is within the uncertainty range for the U-Pb age of the host intrusion and is interpreted as a minimally disturbed cooling age for the tonalite. In the Red Hill area, granodiorite was emplaced at 615 ± 5 Ma, whereas muscovite/sericite separated from a mineralized sample of a quartz-carbonate-pyrite vein, that was overprinted by molybdenite-bearing veinlets, yields an 40Ar/39Ar age of 597 ± 8 Ma. We interpreted this age to represent the maximum age of the molybdenite mineralization and the probable minimum age of gold mineralization in the Red Hill deposit.

  15. U-Pb SHRIMP geochronology of zircon in garnet peridotite from the Sulu UHP terrane, China: Implications for mantle metasomatism and subduction-zone UHP metamorphism (United States)

    Zhang, R.Y.; Yang, J.S.; Wooden, J.L.; Liou, J.G.; Li, T.F.


    We studied the Zhimafang ultrahigh-pressure metamorphic (UHP) peridotite from pre-pilot drill hole PP-1 of Chinese Continental Scientific Drilling project in the Sulu UHP terrane, eastern China. The peridotite occurs as lens within quartofeldspathic gneiss, and has an assemblage of Ol + Opx + Cpx + Phl + Ti-clinohumite (Ti-Chu) + Grt (or chromite) ?? magnesite (Mgs). Zircons were separated from cores at depths of 152 m (C24, garnet lhezolite), 160 m (C27, strongly retrograded phlogopite-rich peridotite) and 225 m (C50, banded peridotite), and were dated by SHRIMP mass spectrometer. Isometric zircons without inherited cores contain inclusions of olivine (Fo91-92), enstatite (En91-92), Ti-clinohumite, diopside, phlogopite and apatite. The enstatite inclusions have low Al2O3 contents of only 0.04-0.13 wt.%, indicating a UHP metamorphic origin. The weighted mean 206Pb/238U zircon age for garnet lherzolite (C24) is 221 ?? 3 Ma, and a discordia lower intercept age for peridotite (C50) is 220 ?? 2 Ma. These ages are within error and represent the time of subduction-zone UHP metamorphism. A younger lower intercept age of 212 ?? 3 Ma for a foliated wehrlite (C27) was probably caused by Pb loss during retrograde metamorphism. The source of zirconium may be partially attributed to melt/fluid metasomatism within the mantle wedge. Geochronological and geochemical data confirm that the mantle-derived Zhimafang garnet peridotites (probably the most representative type of Sulu garnet peridotites) were tectonically inserted into a subducting crustal slab and subjected to in situ Triassic subduction-zone UHP metamorphism. ?? 2005 Elsevier B.V. All rights reserved.

  16. Technology assessment of in situ uranium mining

    International Nuclear Information System (INIS)

    Cowan, C.E.


    The objective of the PNL portion of the Technology Assessment project is to provide a description of the current in situ uranium mining technology; to evaluate, based on available data, the environmental impacts and, in a limited fashion, the health effects; and to explore the impediments to development and deployment of the in situ uranium mining technology

  17. PRINS and in situ PCR protocols

    National Research Council Canada - National Science Library

    Gosden, John R