WorldWideScience

Sample records for illegaalne reiv kalinini

  1. Kunst elab Kalinini tehases

    Index Scriptorium Estoniae

    2002-01-01

    Šveitsi ja prantsuse kunstnike Delphine Reisti, Laurent Fauloni ja Sebastien Perroud' installatsioonide näitus "For Songs for Siivi" endises Kalinini tehases Tallinnas. Näitusega kaasnevad viiuldaja Mathieu Werchowski kontserdid. Squat art on kunst, mis tekib ühisolemise produktina ja jääb tegevuskohta näitamiseks

  2. Kalinini tehas hõivatud

    Index Scriptorium Estoniae

    2002-01-01

    Prantsuse kunstnike Delphine Reisti, Laurent Fauloni, Sebastien Perroud' ja viiuldaja Mathieu Werchowsky ühisnäitus "Four songs for Siivi" Tallinna endises Kalinini tehases. Kunstnikud esitlevad igaüks üht installatsiooni, M. Werchowsky annab mitu kontserti

  3. Partei illegaalne nuumamine viis Chiraci kohtuniku ette / Krister Paris

    Index Scriptorium Estoniae

    Paris, Krister

    2007-01-01

    Prantsusmaa endine president Jacques Chirac kuulati üle seoses mitmele tema asutatud partei RPD töötajale ametikoha jagamisega munitsipaalametis ajal, kui Chirac oli veel Pariisi linnapea. Lisa: Villepin mustamise eest kohtu all

  4. Pranglis liiva kaevandamine oli illegaalne / Küllike Rooväli

    Index Scriptorium Estoniae

    Rooväli, Küllike, 1969-

    2004-01-01

    Keskkonnainspektsiooni Harju osakond tuvastas, et AS-i Tallinna Sadam tellimusel Muuga sadama söekai ehituseks liiva kaevandanud süvenduslaeva Coastway ebaseaduslik kaevandamine tõi riigile suurt kahju. Peatöövõtja AS Merko trahvimisest

  5. Illegaalne relvaäri on kui ämblikuvõrk / Toomas Sildam, Toomas Mattson

    Index Scriptorium Estoniae

    Sildam, Toomas, 1961-

    1995-01-01

    Venemaa süüdistused. Kaitseliit. Politsei. Ilmunud ka: Vetshernije Vesti, 13. nov. 1995, lk. 1; 14. nov. 1995, lk. 5; 16. nov. 1995, lk. 5; 18. nov. 1995, lk. 7; Pühapäevaleht, 11. nov. 1995, lk. 10-12; Molodjozh Estonii : Kupetsheskaja Gavan, 17. nov. 1995, lk. 8-9

  6. The Effect of Crystal Packing and Re(IV) Ions on the Magnetisation Relaxation of [Mn6 ]-Based Molecular Magnets

    OpenAIRE

    Martínez-Lillo, José; Cano, Joan; Wernsdorfer, Wolfgang; Brechin, Euan K

    2015-01-01

    The energy barrier to magnetisation relaxation in single-molecule magnets (SMMs) proffers potential technological applications in high-density information storage and quantum computation. Leading candidates amongst complexes of 3d metals ions are the hexametallic family of complexes of formula [Mn6 O2 (R-sao)6 (X)2 (solvent)y ] (saoH2 =salicylaldoxime; X=mono-anion; y=4-6; R=H, Me, Et, and Ph). The recent synthesis of cationic [Mn6 ][ClO4 ]2 family members, in which the coordinating X ions we...

  7. Conceptualizing declarations of independence in international law / Jure Vidmar

    Index Scriptorium Estoniae

    Vidmar, Jure

    2012-01-01

    Autor arutleb, millistel asjaoludel võib iseseisvuse deklaratsioon rahvusvahelise õiguse reguleerimisalas illegaalne olla. Näiteid Rahvusvahelise Kohtu nõuandvast otsusest Kosovo iseseisvuse kohta

  8. Prantsuse kunstnikud asustasid vana tehase / Johannes Saar

    Index Scriptorium Estoniae

    Saar, Johannes, 1965-

    2002-01-01

    Prantsuse kunstnike (Delphine Reist, Laurent Faulon, Sebastien Perroud) ja viiuldaja Mathieu Werchowsky Tallinnas valminud installatsiooninäitus "Neli laulu Siivile" vanas Kalinini tehasehoones 7.-12. juunini

  9. One-dimensional coordination polymers of [Co3(dpa)4]2+ and [MF6]2- (M = ReIV, ZrIV and SnIV)

    DEFF Research Database (Denmark)

    Bulicanu, Vladimir; Pedersen, Kasper Steen; Rouzières, Mathieu

    2015-01-01

    One-dimensional coordination polymers of alternating metal-metal bonded trinuclear [Co3(dpa)4]2+ (dpa = the anion of 2,2'-dipyridylamine) building blocks and [ReF6]2- (1), [ZrF6]2- (2) or [SnF6]2- (3) linkers have been self-assembled and crystallographically characterized. Magnetic measurements...

  10. Ekspansioon / Alina Kurvitz

    Index Scriptorium Estoniae

    Kurvitz, Alina

    2002-01-01

    Prantsuse kunstnike Delphine Reisti, Laurent Fauloni ja Sebastien Perroud' installatsioonide näitus "Four songs for Siivi" Tallinnas mahajäetud Kalinini tehases. Näitusega kaasnevad viiuldaja Mathieu Werchowsky kontserdid

  11. Siim Nestor soovitab : Elektroakustiline kontsert. Supreme Võrus / Siim Nestor

    Index Scriptorium Estoniae

    Nestor, Siim, 1974-

    2002-01-01

    21. juunil Tallinnas Kalinini tehases installatsiooninäituse Four Songs For Siivi raames toimuvast elektroakustilisest eksperiment-kontserdist, kus peaosas prantslane Mathieu Werchowski. Diskost Võru rannabaaris 21. juunil

  12. Obrazõ Putina : kak jego vidjat hudozhniki / Kerstin Holm

    Index Scriptorium Estoniae

    Holm, Kerstin

    2005-01-01

    Venemaa presidenti Vladimir Putinit kujutavatest taiestest. Kunstnike Andrei Loginovi, Nikas Safronovi, Zurab Tsereteli, Sergei Kalinini ja Farid Bogdanovi, rühmituse "Sinije nosõ" ning David Ter-Oganjani töödest

  13. Kükitajate kunst ja kõrvalhoidmise strateegiad = Squat-art and strategies of choosing the edge / Karin Laansoo

    Index Scriptorium Estoniae

    Laansoo, Karin, 1976-

    2002-01-01

    Prantsuse kunstnikud Delphine Reist, Laurent Faulon, Sebastien Perroud ja Mathiue Werchowsky tegid Tallinnas Kalinini tehasehoones squart'näituse "Neli laulu Siivile". Kuraator Andres Lõo.Four songs for Siivi, kunstinäitus (2002 : Tallinn)

  14. São Paulo majad kõnelevad salakeeles / Filipp Kruusvall

    Index Scriptorium Estoniae

    Kruusvall, Filipp

    2015-01-01

    Artikkel tutvustab São Paulo tänavakunstnikke pixadoreseid, kes ronivad kõrghoonetele joonistama oma märguannet sotsiaalsest elususest. See illegaalne tegevus on ühtaegu hääl, sõnum kui ka karje ebaõigluse vastu ühes maailma ebaühtlasema varalise kihistumisega riigis Brasiilias

  15. 108aastase Liviko tooted koguvad tunnustust nii kodus kui välismaal / Tiit Reinart

    Index Scriptorium Estoniae

    Reinart, Tiit, 1964-

    2006-01-01

    Tänavu tunnustati AS-i Liviko tooteid Vana Tallinna Liköör, Üx Vodka ja Vana Tallinn Cream ühel mainekamal rahvusvahelisel konkursil International Wine & Spirit Competition (IWSC), ühtlasi tegeleb ettevõte jätkuvalt tootearenduse ja kvaliteetveinide importimisega. Vt. samas: Maksumärgita alkohol on illegaalne

  16. Skandaalid : Eesti elu deodorant / Argo Ideon, Toomas Sildam

    Index Scriptorium Estoniae

    Ideon, Argo, 1966-

    1999-01-01

    Lisa: intervjuu Daniel Vaarikuga. 8 valitud skandaali, mis vapustasid Eestit: Tartu Kommertspanga pankrot. Rublamüük. Illegaalne relvaäri. Lindiskandaal. 10 milj. dollari kadumine. Tallinna Panga ja Ühispanga konflikt. Daiwa laen. Viinaga valijate häälte ostmine

  17. Kus tondid Tallinnas pidu peavad?

    Index Scriptorium Estoniae

    2008-01-01

    Lagunevatest hoonetest Tallinnas - end. Kalinini nimeline tehas, Eesti Meremuuseumi alal asuv hoone, Volta tehase hooned Tööstuse tänaval, Keraamikatehase hooned Maleva 2, Patarei vangla, Tina tänava juugendvilla (projekteerijad Karl Burman ja Artur Perna), puitelamu Kadriorus Poska 6

  18. Kaduvusele kalduvad alternatiivid majas nr. 0 / Andreas Trossek

    Index Scriptorium Estoniae

    Trossek, Andreas, 1980-

    2002-01-01

    Prantsuse kunstnikekoloonia (Delphine Reist, Laurent Faulon, Sebastien Perroud) ja viiuldaja Mathieu Werchowsky Tallinnas valminud installatsiooninäitus "Neli laulu Siivile" vanas Kalinini tehasehoones 7.-12. juunini. Kunstnikud jätavad installatsiooni saatuse hooleks ja lähevad mujale

  19. Relativistic DFT calculations of hyperfine coupling constants in the 5d hexafluorido complexes

    DEFF Research Database (Denmark)

    Haase, Pi Ariane Bresling; Repisky, Michal; Komorovsky, Stanislav

    2017-01-01

    We have investigated the performance of the most popular relativistic density functional theory methods, zeroth order regular approximation (ZORA) and 4-component Dirac-Kohn-Sham (DKS), in the calculation of the recently measured hyperfine coupling constants of ReIV and IrIV in their hexafluorido...

  20. X-ray photoelectron spectroscopy (XPS) studies of rhenium catalyst

    International Nuclear Information System (INIS)

    Mohd Ambar Yarmo; Che Seman Mahmood

    2000-01-01

    Rhenium oxide on alumina (Re 2 O 7 /Al 2 O 3 ) is a very active catalyst system for olefin metathesis reaction. The catalyst can be prepared by wet impregnation of ammonium perrhenate (NH 4 ReO 4 ) solution onto alumina (γ-AI 2 O 3 ) support followed by drying and calcination in air. In this study, rhenium catalysts at different treatment conditions namely active, non-active and during propylene metathesis reaction were investigated using X-ray photoelectron spectroscopy (XPS) technique. Analysis of O 1s , photoelectron peak shows that some chemical interaction between rhenium oxides and the support have been established through Re-O-Al linkage. Analysis of Re 4f7/2 photoelectron peak by using a systematic deconvolution procedure, shows that the metal was in a mixed and varied oxidation states from Re(IV) to Re(VII) depending on their treatment condition. The presence of the metal-carbene complex, the reaction intermediate, could possibly be observed by analysing the C 1s , photoelectron peak. However, a much higher vacuum (i.e. 10 -10 - 10 -11 torr) is needed in the spectroscopy system in order to have the improved detection sensitivity. (Author)

  1. The study of various rhenium compounds by capillary electrophoresis

    International Nuclear Information System (INIS)

    Kohlickova, M.; Jedinakova-Krizova, V.

    2000-01-01

    The conditions for the synthesis of rhenium compounds (pH, reaction time, concentration of reducing agent) have been determined previously by thin-layer chromatography. A Britton-Robinson buffer solution has been selected as a carrier electrolyte due to its possible use in a wide interval of pH, mainly at optimal pH for the formation of the complexes studied. The same electrolyte has been previously applied also in case of the study of rhenium and technetium complexes by polarography. The electrophoretic experiments have been carried out under both standard and reverse polarities with direct UV detection at the wavelength 214 nm and 20 deg C. The signal of perrhenate has been observed at the reverse polarity (outlet+, inlet-), of reduced rhenium [probably Re(IV)] under normal polarity. The formation of rhenium complexes with EDTA has been shown by lowering of the cationic rhenium signal due to the addition of the ligand. The rhenium complexes with EDTA are observable at reverse mode of CE. The formation of rhenium complexes with HEDP (hydroxyethylidenediphosphonic acid) has been studied in two different carrier electrolytes -40 mM Britton-Robinson buffer solution and 50 mM phosphate buffer with 20 mM HEDP. The mechanism of perrhenate reduction by stannous chloride and of the formation of rhenium complexes with EDTA has been determined. The necessity of the presence of ascorbic acid as an antioxidant in the reaction mixture at different pH values has been described as well. (author)

  2. Mixed chloride/phosphine complexes of the dirhenium core. 10. Redox reactions of an edge-sharing dirhenium(III) non-metal-metal-bonded complex, Re(2)(mu-Cl)(2)Cl(4)(PMe(3))(4).

    Science.gov (United States)

    Cotton, F A; Dikarev, E V; Petrukhina, M A

    2001-12-17

    Reduction and oxidation reactions of the dirhenium(III) non-metal-metal-bonded edge-sharing complex, Re(2)(mu-Cl)(2)Cl(4)(PMe(3))(4) (1), have been studied. Several new mono- and dinuclear rhenium compounds have been isolated and structurally characterized in the course of this study. Reductions of 1 with 1 and 2 equiv of KC(8) result in an unusual face-sharing complex having an Re(2)(5+) core, Re(2)(mu-Cl)(3)Cl(2)(PMe(3))(4) (2), and a triply bonded Re(II) compound, 1,2,7,8-Re(2)Cl(4)(PMe(3))(4) (3), respectively. Two-electron reduction of 1 in the presence of tetrabutylammonium chloride affords a new triply bonded complex of the Re(2)(4+) core, [Bu(n)()(4)N][1,2,7-Re(2)Cl(5)(PMe(3))(3)] (4). Oxidation of 1 with NOBF(4) yields a Re(IV) mononuclear compound, trans-ReCl(4)(PMe(3))(2) (5). Two isomers of the monomeric Re(III) anion, [ReCl(4)(PMe(3))(2)](-) (6, 7), have been isolated as side products. The crystal structures of compounds 2 and 4-7 have been determined by X-ray crystallography. The Re-Re distance in the face-sharing complex 2 of 2.686(1) A is relatively short. The metal-metal bond length in anion 4 of 2.2354(7) A is consistent with the usual values for the triply bonded Re(2)(4+) core compounds. In addition, a cis arrangement of trimethylphosphine ligands in the starting material 1 is retained upon reduction in the dinuclear products 2-4.

  3. Dissimilar behavior of technetium and rhenium in borosilicatewaste glass as determined by X-ray absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Lukens, Wayne W.; McKeown, David A.; Buechele, Andrew C.; Muller,Isabelle S.; Shuh, David K.; Pegg, Ian L.

    2006-11-09

    Technetium-99 is an abundant, long-lived (t1/2 = 213,000 yr)fission product that creates challenges for the safe, long-term disposalof nuclear waste. While 99Tc receives attention largely due to its highenvironmental mobility, it also causes problems during its incorporationinto nuclear waste glass due to the volatility of Tc(VII) compounds. Thisvolatility decreases the amount of 99Tc stabilized in the waste glass andcauses contamination of the waste glass melter and off-gas system. Theapproach to decrease the volatility of 99Tc that has received the mostattention is reduction of the volatile Tc(VII) species to less volatileTc(IV) species in the glass melt. On engineering scale experiments,rhenium is often used as a non-radioactive surrogate for 99Tc to avoidthe radioactive contamination problems caused by volatile 99Tc compounds.However, Re(VII) is more stable towards reduction than Tc(VII), so morereducing conditions would be required in the glass melt to produceRe(IV). To better understand the redox behavior of Tc and Re in nuclearwaste glass, a series of glasses were prepared under different redoxconditions. The speciation of Tc and Re in the resulting glasses wasdetermined by X-ray absorption fine structure spectroscopy. Surprisingly,Re and Tc do not behave similarly in the glass melt. Although Tc(0),Tc(IV), and Tc(VII) were observed in these samples, only Re(0) andRe(VII) were found. In no case was Re(IV) (or Re(VI))observed.

  4. Technetium (VII) Co-precipitation with Framework Aluminosilicates

    Energy Technology Data Exchange (ETDEWEB)

    Harsh, James B. [Washington State Univ., Pullman, WA (United States); Dickson, Johnbull Otah [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Pierce, Eric M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Bargar, John [SLAC National Accelerator Lab., Menlo Park, CA (United States)

    2015-07-13

    Technetium-99 (99Tc), a long-lived radionuclide, is one of the most widespread contaminants within the Hanford subsurface. At some depths, it is only extractable with strong acids, suggesting incorporation into a solid phase. We hypothesized that Tc may have coprecipitated with feldspathoid aluminosilicates under waste tanks that had leaked caustic solutions into the vadose zone. Our objectives were to determine if Tc could be incorporated into the feldspathoids cancrinite and sodalite and under what conditions coprecipitation could occur. Our hypothesis was that sodalite was more likely to incorporate and retain Tc. Our approach was to use known methods of feldspathoid formation in solutions resembling those in Hanford waste tanks contacting sediments in terms of major ion (Na, NO3, OH, Al(OH)4, and Si(OH)4 concentrations. In some cases, Al and Si were supplied from zeolite. We used perrhenate (ReO4) as a surrogate for pertechnetate (TcO4) to avoid the radioactivity. The major findings of this study were 1) ReO4 could be incorporated into either sodalite or cancrinite but the concentration in the solid was < 1% of the competing ion Cl, NO3, or NO2. 2) The small amount of ReO4 incorporated was not exchangeable with NO3 or NO2. 3) In sodalite, NO3 was highly preferred over ReO4 but significant Re-sodalite was formed when the mole fraction in solution (Re/Re+N) exceeded 0.8. 4) A nonlinear relation between the unit cell parameter and amount of Re incorporated suggested that a separate Re-sodalite phase was formed rather than a solid solution. 5) We determined that sodalite preference for sodalite in the presence of different anions increased with the ionic size of the competing anion: Cl < CO3 < NO3 < SO4 < MnO4 < WO4 and significant incorporation did not occur unless the difference in anion radii was less than 12%. 6) Re(VII) was not significantly reduced to Re(IV) under the conditions of this experiment and Re appeared to be a good surrogate for Tc under oxidizing