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Sample records for hydrothermally treated coals

  1. Hydrothermal dewatering of lower rank coals. 3. High-concentration slurries from hydrothermally treated lower rank coals

    Energy Technology Data Exchange (ETDEWEB)

    Favas, G.; Jackson, W.R.; Marshall, M. [Monash University, Vic. (Australia). School of Chemistry

    2003-01-01

    A novel method of producing a product of low intra-particle porosity ({lt}1 {mu}m pore radius) from highly porous Latrobe Valley raw brown coals uses a combination of hydrothermal and evaporative drying. Low porosity coal was made in three different batch autoclave systems at 320{sup o}C for residence times as low as 10 min. Higher temperatures (up to 350{sup o}C) increased porosity slightly but the water vapour pressure and the loss of organic material were significantly increased. Although the low and high porosity products differed dramatically in appearance and hardness, other chemical and spectroscopic properties were similar with the exception of pyrolysis gas chromatography mass spectrometry patterns. The relationship between intra-particle porosity and the maximum wt% dry solids concentration of aqueous slurries (for a viscosity of less than 1000 mPa s), {phi}{sub max}, established by earlier workers for hydrothermally treated brown coals was found to hold for the new products and was extended to a wider range of porosities and a range of mean particle sizes (mps) (20 100 {mu}m). A range of surfactants (anionic, cationic and neutral), which led to an increase of up to 7% in {phi}{sub max} for a bituminous, Blair Athol coal, increased {phi}{sub max} for products of hydrothermal or the new treatment by only 2 4%. This small increase resulted, however, in the formation of slurries of the low porosity products with {phi}{sub max} of up to 64%, similar to those obtained with high rank coals, and considered to be of commercial interest. 20 refs., 3 figs., 6 tabs.

  2. Prevention of trace and major element leaching from coal combustion products by hydrothermally-treated coal ash

    Energy Technology Data Exchange (ETDEWEB)

    Adnadjevic, B.; Popovic, A.; Mikasinovic, B. [University of Belgrade, Belgrade (Serbia). Dept. of Chemistry

    2009-07-01

    The most important structural components of coal ash obtained by coal combustion in 'Nikola Tesla A' power plant located near Belgrade (Serbia) are amorphous alumosilicate, alpha-quartz, and mullite. The phase composition of coal ash can be altered to obtain zeolite type NaA that crystallizes in a narrow crystallization field (SiO{sub 2}/Al{sub 2}O{sub 3}; Na{sub 2}O/SiO{sub 2}; H{sub 2}O/Na{sub 2}O ratios). Basic properties (crystallization degree, chemical composition, the energy of activation) of obtained zeolites were established. Coal ash extracts treated with obtained ion-exchange material showed that zeolites obtained from coal ash were able to reduce the amounts of iron, chromium, nickel, zinc, copper, lead, and manganese in ash extracts, thus proving its potential in preventing pollution from dump effluent waters.

  3. Hydrothermal pretreatment of coal

    Energy Technology Data Exchange (ETDEWEB)

    Ross, D.S.

    1989-12-21

    We have examined changes in Argonne Premium samples of Wyodak coal following 30 min treatment in liquid water at autogenous pressures at 150{degrees}, 250{degrees}, and 350{degrees}C. In most runs the coal was initially dried at 60{degrees}C/1 torr/20 hr. The changes were monitored by pyrolysis field ionization mass spectrometry (py-FIMS) operating at 2.5{degrees}C/min from ambient to 500{degrees}C. We recorded the volatility patterns of the coal tars evolved over that temperature range, and in all cases the tar yields were 25%--30% of the starting coal on mass basis. There was essentially no change after the 150{degrees}C treatment. Small increases in volatility were seen following the 250{degrees}C treatment, but major effects were seen in the 350{degrees} work. The tar quantity remained unchanged; however, the volatility increased so the temperature of half volatility for the as-received coal of 400{degrees}C was reduced to 340{degrees}C. Control runs with no water showed some thermal effect, but the net effect from the presence of liquid water was clearly evident. The composition was unchanged after the 150{degrees} and 250{degrees}C treatments, but the 350{degrees} treatment brought about a 30% loss of oxygen. The change corresponded to loss of the elements of water, although loss of OH'' seemed to fit the analysis data somewhat better. The water loss takes place both in the presence and in the absence of added water, but it is noteworthy that the loss in the hydrothermal runs occurs at p(H{sub 2}O) = 160 atm. We conclude that the process must involve the dehydration solely of chemically bound elements of water, the dehydration of catechol is a specific, likely candidate.

  4. Effect of hydrothermal treatment of coal on its associative structure

    Energy Technology Data Exchange (ETDEWEB)

    Shui Heng-fu; Wang Zhi-cai; Wang Gao-qiang; Niu Min-feng [Anhui University of Technology, Maanshan (China). School of Chemistry & Chemical Engineering

    2006-10-15

    4 bituminous coals with different ranks were thermally and hydrothermally treated under different conditions, and the raw and treated coals were extracted with carbon disulfide/N-2-pyrrolidinone (CS{sub 2}/NMP) mixed solvent (1:1 by volume). It is found that the extraction yields of the thermal or hydrothermal treated coals at proper conditions increase in different extent. The increments of extraction yields for hydrothermal treated coals are higher than those of thermal treated coals. FT-IR shows that the adsorption peaks at 3410 cm{sup -1} attributed to OH group for the hydrothermal treated coals decrease, suggesting the dissociation of the coal aggregation structure due to the breakage of hydrogen bonds, resulting in the increase of extraction yields for the treated coals. For higher rank coal, the removal of minerals and the dissociation of {pi}-cation association after hydrothermal treatment of coal may be responsible for the increase of extraction yield. In addition, the mechanism of hydrothermal treatment of coal was discussed. 15 refs., 2 figs., 5 tabs.

  5. An Investigation on Cocombustion Behaviors of Hydrothermally Treated Municipal Solid Waste with Coal Using a Drop-Tube Reactor

    Directory of Open Access Journals (Sweden)

    Liang Lu

    2012-01-01

    Full Text Available This work aims at demonstrating the feasibility of replacing Indonesian coal (INC with hydrothermally treated municipal solid waste (MSWH in cocombustion with high ash Indian coal (IC. The combustion efficiencies and emissions (CO, NO of MSWH, INC and their blends with IC for a series of tests performed under a range of temperatures and air conditions were tested in a drop-tube reactor (DTR. The results showed the following. The combustion efficiency of IC was increased by blending both MSWH and INC and CO emission was reduced with increasing temperature. For NO emission, the blending of MSWH led to the increase of NO concentration whereas the effects of INC depended on the temperature. The combustion behaviors of IC-MSWH blend were comparable to those of the IC-INC blend indicating it is possible for MSWH to become a good substitute for INC supporting IC combustion. Moreover, the CO emission fell while the NO emission rose with increasing excess air for IC-MSWH blend at 900°C and the highest combustion efficiency was obtained at the excess air of 1.9. The existence of moisture in the cocombustion system of IC-MSWH blend could slightly improve the combustion efficiency, reduce CO, and increase NO.

  6. Nitrogen evolution during the co-combustion of hydrothermally treated municipal solid waste and coal in a bubbling fluidized bed.

    Science.gov (United States)

    Lu, Liang; Jin, Yuqi; Liu, Hongmei; Ma, Xiaojun; Yoshikawa, Kunio

    2014-01-01

    Nitrogen evolution was studied during the co-combustion of hydrothermally treated municipal solid wastes (HT MSW) and coal in a bubbling fluidized bed (BFB). HT MSW blending ratios as 10%, 20% and 30% (wt.%) were selected and tested at 700, 800, 900 °C. Emissions of NO and N2O from blends were measured and compared with the results of mono-combustion trials. Moreover, concentrations of precursors like NH3 and HCN were also quantified. The results are summarized as follows: NO emissions were predominant in all the cases, which rose with increasing temperature. The blending of HT MSW contributed to the NO reduction. N2O emissions decreased with temperature rising and the blending of HT MSW also presented positive effects. At 30% HT MSW addition, both NO and N2O emissions showed the lowest values (391.85 ppm and 55.33 ppm, respectively at 900 °C). For the precursors, more HCN was detected than NH3 and both played important roles on the gas side nitrogen evolution.

  7. A comparison of co-combustion characteristics of coal with wood and hydrothermally treated municipal solid waste.

    Science.gov (United States)

    Muthuraman, Marisamy; Namioka, Tomoaki; Yoshikawa, Kunio

    2010-04-01

    In this work, thermogravimetric analysis was used to investigate the co-combustion characteristics of wood and municipal solid waste (MSW) with Indian coal. Combustion characteristics like volatile release, ignition were studied. Wood presented an enhanced reaction rate reflecting its high volatile and low ash contents, while MSW enhanced ignition behavior of Indian coal. The results indicate that blending of both, wood and MSW improves devolatization properties of coal. Significant interaction was detected between wood and Indian coal, and reactivity of coal has improved upon blending with wood. On the other hand, MSW shows a good interaction with Indian coal leading to significant reduction in ignition temperature of coal and this effect was more pronounced with higher blending ratio of MSW. Hence MSW blending could more positively support the combustion of low quality Indian coal as compared to wood, due to its property of enhancement of ignition characteristics.

  8. Hydrothermal conversion of South African coal fly ash into pure phase Zeolite Na-P1

    CSIR Research Space (South Africa)

    Gitari, MW

    2016-08-01

    Full Text Available from selected South African coal fly ashes. The hydrothermal treatment time, temperature, and molar quantities of water during the hydrothermal treatment step were successfully optimized. The optimum hydrothermal treatment time and temperature were 48 h...

  9. Hydrothermal synthesis of zeolites from coal fly ash

    OpenAIRE

    Kotova, OB; Shabalin, Igor L; Shushkov, DA; Kocheva, LS

    2015-01-01

    The fly ash, from the combustion of coal to produce energy and heat, is an industrial waste, in which large accumulations represent a serious environmental threat. To reduce the environmental burden and improve the economic benefits of energy production, the science and industry focus on the transformation of coal combustion byproducts into new functional materials. The fly ash was studied by modern analytical methods. As a result of the hydrothermal reaction, several types of zeolites were s...

  10. Collapsibility and Wettability of Hydrothermally Treated Wood

    Directory of Open Access Journals (Sweden)

    Ghane Mirzaee

    2012-06-01

    Full Text Available Study on collapsibility of oriental beech (Fagus orientalis and paulownia (Paulownia fortune woods due to their hydrothermal modification as well as the wettability and the water absorption were the main concerns of this research work. Out of these species, blocks of sizes 50×6×6cm were prepared and treated at temperatures of 130 and 150°C with a holding time of 30min in a stainless steel reactor containing the water. Oven dried weights and dimensions of the blocks were measured before and after the hydrothermal treatment to determine the density, collapsibility and mass loss due to applied treatment. Furthermore, small blocks of the treated wood were prepared and soaked in water for 1000-hr to determine their water absorption. The wettability of the woods were also measured to determine the water repellency. Results revealed that any raise of treatment temperature up to 150°C increases the density and the collapsibility. Treated wood collapsed in all directions; however, tangential collapse was much worse than the other directions. The contact angle was increased by rise of the treatment temperature. Hydrothermal treatment has reduced water absorption and increased the hydrophobicity of the woods.

  11. Reduction of sulfur content of brown coals and lignites by hydrothermal treatment

    Energy Technology Data Exchange (ETDEWEB)

    Takacs, P.; Wolf, G.; Bognar, T.

    1987-01-01

    The hydrothermal experiments were carried out in acid-proof autoclaves. The experimental conditions are described and the results are summarized for different coal types. The heat treatment reduces the organic sulfur content and increases the calorific value. From 300 degrees C the pyritic sulfur can be separated from the other forms of sulfur. By the hydrothermal treatment the bitumen content to be extracted by benzene-alcohol mixture also increased in thermo-coals.

  12. Production of a high quality coal product from a low quality coal using a modified hydrothermal dewatering technique

    Energy Technology Data Exchange (ETDEWEB)

    Favas, G.; Jackson, W.R. [Monash University, Vic. (Australia). Dept. of Chemistry

    2000-07-01

    A novel method of producing a very low porosity coal material from a wide range of highly porous Latrobe Valley raw brown coals has been developed using a combination of hydrothermal and evaporative drying. The conditions for the production of low-porosity coal in two different batch autoclave systems are discussed. The mixing regime and heat-up times of the two autoclaves had little effect on the porosity of the final product; however the lithotype of the coal did have an effect. A pale lithotype coal gave a significantly lower porosity, higher maximum solids concentrations and was more susceptible to the effect of slurry stabilising agents. For brown coals the effects on maximum solids concentration of hydrothermal drying (HTD) itself and of changing from high-porosity to low-porosity HTD conditions were much greater than the effects of chemical additives. The influence of the chemical additives increased in going from raw coal to high-porosity HTD product, and from high to low porosity product. Thus the maximum solids concentration of a low-porosity HTD product with suitable chemical additives was as high as 64 %wt.dry solids (db), compared to 50 %wt.db for the corresponding high porosity HTD product and only 60 %wt.dry solids for a bituminous coal, Blair Athol.

  13. Co-pyrolysis of hydrothermally upgraded brown coal and wax prepared from waste plastics

    Energy Technology Data Exchange (ETDEWEB)

    Kouichi Miura; Susan A. Roces; Monthicha Pattatapanusak; Hiroyuki Nakagawa; Ryuichi Ashida; Masato Morimoto [Kyoto University, Kyoto (Japan). Department of Chemical Engineering

    2007-07-01

    We have recently presented a hydrothermal extraction method that not only removes water from brown coal but also upgrades the coal and extracts low molecular mass compounds simultaneously. The upgraded coal contained much less oxygen than the raw coal. However, it still needs to be further upgraded to be utilized as a substitute for bituminous coal. In this study co-pyrolysis of the upgraded coals and waxes formed from waste plastics was investigated for this purpose. Waxes were prepared through pyrolysis of polyethylene, polypropylene, and polyethylene terephtalate. Upgraded coals were then impregnated with the waxes in an autoclave at 200{sup o}C under pressure. The mixtures of coal and wax were rapidly heated up to 1040{sup o}C at about 3000{sup o}C/s using a Curie point pyrolyzer in an inert atmosphere. The char yield was greatly enhanced by a factor of 1.1 to 1.3 compared to the char yield obtained when the upgraded coals and waxes were pyrolyzed independently. Even under a slower heating rate (0.17{sup o}C/s) the char yields increased by a factor of 1.2 for the all mixtures of the upgraded coal and waxes. Since no such effect was found when the raw brown coal was impregnated with waxes, it was suggested that the modification of the structure of brown coal by the hydrothermal extraction could enhance interactions between the coal and the wax when co-pyrolyzed. Effect of wax mixing ratio on co-pyrolysis behavior was also examined. The char yield dramatically increased when the ratio exceeded about 0.3 g/g for the pyrolysis of both under slow and rapid heating rates. This trend coincided with that of the swelling ratio of the upgraded coal impregnated with wax, indicating that some physical change by wax-impregnation affected the co-pyrolysis behavior. 5 refs., 14 figs., 3 tabs.

  14. Physicochemical properties and digestibility of hydrothermally treated waxy rice starch.

    Science.gov (United States)

    Zeng, Feng; Ma, Fei; Kong, Fansheng; Gao, Qunyu; Yu, Shujuan

    2015-04-01

    Waxy rice starch was subjected to annealing (ANN) and heat-moisture treatment (HMT). These starches were also treated by a combination of ANN and HMT. The impact of single and dual modifications (ANN-HMT and HMT-ANN) on the molecular weight (M(w)), crystalline structure, thermal properties, and the digestibility were investigated. The relative crystallinity and short-range order on the granule surface increased on ANN, whereas decreased on HMT. All treated starches showed lower M(w) than that of the native starch. Gelatinization onset temperature, peak temperature and conclusion temperature increased for both single and dual treatments. Increased slowly digestible starch content was found on HMT and ANN-HMT. However, resistant starch levels decreased in all treated starches as compared with native starch. The results would imply that hydrothermal treatment induced structural changes in waxy rice starch significantly affected its digestibility.

  15. Chlorine behavior during co-hydrothermal treatment of high alkali coal and PVC

    Science.gov (United States)

    Huang, N.; Zhao, P. T.; Li, Z. Z.; Li, T.

    2016-08-01

    The hydrothermal treatment (HT) is an effective method to remove chlorine from chlorinated wastes under mild conditions. However, the alkali was required to improve the dechlorination efficiency. Meanwhile, the alkalis contents removed was necessary to realize the clean and highly efficient utilization of coal. This work was trying to investigate the feasibility of simultaneously removal alkalis and chlorine by co-hydrothermal treatment of PVC and high-alkali coal. The effect of operating conditions including the HT temperature, the holding time and particle sizes of coal on the dechlorination efficiency (DE) of PVC during the HT process was experimentally studied in this work. The results show that the DE increased with the rise of: 1) particle sizes (0.054~0.22mm), 2) holding time (30~90 min) and 3) temperature (240~300 °C). In detail, under 300 °C and 60min of holding time, the 85.18% of DE with first PS was lower than the 93.93% of DE with second PS and 100% of DE with third PS. The organic chlorine mainly transferred into chloridion in aqueous solution in HT process. All the results indicate that it is a prospective way to simultaneously removal alkalis and chlorine by co-hydrothermal treatment of chlorinated wastes and high-alkali coal.

  16. Hydrothermal Synthesis of SBA-15 Using Sodium Silicate Derived from Coal Gangue

    Directory of Open Access Journals (Sweden)

    Jing Wang

    2013-01-01

    Full Text Available Well-ordered SBA-15 was prepared with a hydrothermal route by sodium silicate derived from coal gangue. The as-prepared sample was analyzed by SAXRD, BET, TEM, and SEM, respectively. The results indicate that at a low hydrothermal temperature of 100∘C the well-ordered mesoporous SBA-15 could be synthesized. The surface area, pore volume, and pore size of the sample are 552 m2/g, 0.54 cm3/g, and 7.0 nm, respectively. It is suggested that coal gangue could be used in obtaining an Si source to prepare mesoporous materials, such as SBA-15.

  17. Process for treating moisture laden coal fines

    Science.gov (United States)

    Davis, Burl E.; Henry, Raymond M.; Trivett, Gordon S.; Albaugh, Edgar W.

    1993-01-01

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  18. Hydrothermal pretreatment of coal. Quarterly report No. 1, September 21--December 15, 1989

    Energy Technology Data Exchange (ETDEWEB)

    Ross, D.S.

    1989-12-21

    We have examined changes in Argonne Premium samples of Wyodak coal following 30 min treatment in liquid water at autogenous pressures at 150{degrees}, 250{degrees}, and 350{degrees}C. In most runs the coal was initially dried at 60{degrees}C/1 torr/20 hr. The changes were monitored by pyrolysis field ionization mass spectrometry (py-FIMS) operating at 2.5{degrees}C/min from ambient to 500{degrees}C. We recorded the volatility patterns of the coal tars evolved over that temperature range, and in all cases the tar yields were 25%--30% of the starting coal on mass basis. There was essentially no change after the 150{degrees}C treatment. Small increases in volatility were seen following the 250{degrees}C treatment, but major effects were seen in the 350{degrees} work. The tar quantity remained unchanged; however, the volatility increased so the temperature of half volatility for the as-received coal of 400{degrees}C was reduced to 340{degrees}C. Control runs with no water showed some thermal effect, but the net effect from the presence of liquid water was clearly evident. The composition was unchanged after the 150{degrees} and 250{degrees}C treatments, but the 350{degrees} treatment brought about a 30% loss of oxygen. The change corresponded to loss of the elements of water, although loss of ``OH`` seemed to fit the analysis data somewhat better. The water loss takes place both in the presence and in the absence of added water, but it is noteworthy that the loss in the hydrothermal runs occurs at p(H{sub 2}O) = 160 atm. We conclude that the process must involve the dehydration solely of chemically bound elements of water, the dehydration of catechol is a specific, likely candidate.

  19. Ethanol Production from Hydrothermally-Treated Biomass from West Africa

    DEFF Research Database (Denmark)

    Bensah, Edem C.; Kádár, Zsófia; Mensah, Moses Y.

    2015-01-01

    Despite the abundance of diverse biomass resources in Africa, they have received little research and development focus. This study presents compositional analysis, sugar, and ethanol yields of hydrothermal pretreated (195 degrees C, 10 min) biomass from West Africa, including bamboo wood, rubber...... wood, elephant grass, Siam weed, and coconut husk, benchmarked against those of wheat straw. The elephant grass exhibited the highest glucose and ethanol yields at 57.8% and 65.1% of the theoretical maximums, respectively. The results show that the glucose yield of pretreated elephant grass was 3.......5 times that of the untreated material, while the ethanol yield was nearly 2 times higher. Moreover, the sugar released by the elephant grass (30.8 g/100 g TS) was only slightly lower than by the wheat straw (33.1 g/100 g TS), while the ethanol yield (16.1 g/100 g TS) was higher than that of the straw (15...

  20. Drying grain using a hydrothermally treated liquid lignite fuel

    Energy Technology Data Exchange (ETDEWEB)

    Bukurov, Z.; Cvijanovic, P.; Bukurov, M. [Univ. of Novi Sad (Yugoslavia); Ljubicic, B.R. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-01

    A shortage of domestic oil and natural gas resources in Yugoslavia, particularly for agricultural and industrial purposes, has motivated the authors to explore the possibility of using liquid lignite as an alternate fuel for drying grain. This paper presents a technical and economic assessment of the possibility of retrofitting grain-drying plants currently fueled by oil or natural gas to liquid lignite fuel. All estimates are based on lignite taken from the Kovin deposit. Proposed technology includes underwater mining techniques, aqueous ash removal, hydrothermal processing, solids concentration, pipeline transport up to 120 km, and liquid lignite direct combustion. For the characterization of Kovin lignite, standard ASTM procedures were used: proximate, ultimate, ash, heating value, and Theological analyses were performed. Results from an extensive economic analysis indicate a delivered cost of US$20/ton for the liquid lignite. For the 70 of the grain-drying plants in the province of Vojvodina, this would mean a total yearly saving of about US $2,500,000. The advantages of this concept are obvious: easy to transport and store, nonflammable, nonexplosive, nontoxic, 30%-40% cheaper than imported oil and gas, domestic fuel is at hand. The authors believe that liquid lignite, rather than an alternative, is becoming more and more an imperative.

  1. Optimization of hydrothermal synthesis of pure phase zeolite Na-P1 from South African coal fly ashes.

    Science.gov (United States)

    Musyoka, Nicholas M; Petrik, Leslie F; Gitari, Wilson M; Balfour, Gillian; Hums, Eric

    2012-01-01

    This study was aimed at optimizing the synthesis conditions for pure phase zeolite Na-P1 from three coal fly ashes obtained from power stations in the Mpumalanga province of South Africa. Synthesis variables evaluated were: hydrothermal treatment time (12-48 hours), temperature (100-160°C) and varying molar quantities of water during the hydrothermal treatment step (H(2)O:SiO(2) molar ratio ranged between 0-0.49). The optimum synthesis conditions for preparing pure phase zeolite Na-P1 were achieved when the molar regime was 1 SiO(2): 0.36 Al(2)O(3): 0.59 NaOH: 0.49 H(2)O and ageing was done at 47°C for 48 hours. The optimum hydrothermal treatment time and temperature was 48 hours and 140°C, respectively. Fly ashes sourced from two coal-fired power plants (A, B) were found to produce nearly same high purity zeolite Na-P1 under identical conditions whereas the third fly ash (C) lead to a low quality zeolite Na-P1 under these conditions. The cation exchange capacity for the high pure phase was found to be 4.11 meq/g. These results highlight the fact that adjustment of reactant composition and presynthesis or synthesis parameters, improved quality of zeolite Na-P1 can be achieved and hence an improved potential for application of zeolites prepared from coal fly ash.

  2. Uptake of pyrene in a breast-fed child of a mother treated with coal tar.

    NARCIS (Netherlands)

    Scheepers, P.T.J.; Houtum, J.L.M. van; Anzion, R.B.M.; Harder, R.; Bos, R.P.; Valk, P.G.M. van der

    2009-01-01

    A woman was treated for atopic dermatitis with coal tar containing ointments. Coal tar containing ointments contain genotoxic polycyclic aromatic hydrocarbons. Over a period of 50 days the accumulated dose of different coal tar containing ointments treatments corresponded to 993 mg of pyrene and 464

  3. Treating coal mine drainage with an artificial wetland. [USA - Ohio

    Energy Technology Data Exchange (ETDEWEB)

    Fennessy, M.S.; Mitsch, W.J. (Ohio State University Columbus, OH (USA). School of Natural Resources)

    A 0.22-ha constructed wetland dominated by Typha latofolia was evaluated for its ability to treat approximately 340 L/min of coal mine drainage from an underground seep in eastern Ohio. Loading of mine drainage to the wetland ranged from 15 to 35 cm/d. Conductivity, pH, manganese, and sulfate were little changed by the wetland. Iron decreased by 50 to 60%, with slightly higher decreases during the growing season. Comparisons are made to a volunteer Typha marsh receiving mine drainage where iron was found to decrease by approximately 89%. Design considerations of loading rates of created wetlands suggest that improved treatment of mine drainage is correlated with longer retention times and lower iron loading rates. Preliminary design criteria for construction of these types of Typha wetlands for removal of iron are suggested as 5 cm/d hydrologic loading and 2 to 40 g Fe/m{sup 2}.d for iron loading, depending on the treatment desired. 34 refs., 8 figs., 5 tabs.

  4. Hydrothermal Synthesis of Zeolite from Coal Class F Fly Ash. Influence of Temperature

    Directory of Open Access Journals (Sweden)

    Goñi, S.

    2010-06-01

    Full Text Available The influence of temperature of alkaline hydrothermal treatment on the conversion in zeolite of Spanish coal low calcium-fly ash (ASTM class F is presented in this work. Zeolite Na-P1 gismondine type (Na6Al6Si10O32.12H2O was formed at the temperature of 100ºC, which transformed in zeolite; analcime-C type (Na(Si2AlO6H2O and sodalite (1.08 Na2O.Al2O3.1.68SiO2.1.8H2O at 200ºC together with traces of tobermorite-11Å (Ca5(OH2Si6O16.4H2O. At this temperature the 100% of the fly ash reaction was allowed. An equivalent study was carried out in water as reference. The zeolite conversion of the fly ash was characterized by X ray diffraction (XRD, FT infrared (FTIR spectroscopy, surface area (BET-N2 and thermal analyses.

    En este trabajo se presenta el papel que juega la temperatura durante el tratamiento hidrotermal en medio alcalino para convertir una ceniza volante de bajo contenido en cal (clase F, según la norma ASTM en zeolita. Durante este tratamiento a la temperatura de 100ºC se forma Zeolita Na-P1 tipo gismondina (Na6Al6Si10O32.12H2O; al elevar la temperatura a 200ºC, dicha zeolita se transforma en zeolita Analcima C (Na(Si2AlO6H2O y en fase sodalita (1.08 Na2O.Al2O3.1.68SiO2.1.8H2O junto con trazas de tobermorita-11Å (Ca5(OH2Si6O16.4H2O. A esta temperatura y en estas condiciones se ha conseguido un 100% de reacción. Un estudio equivalente se ha llevado a cabo empleando agua como medio de referencia. La conversión de ceniza volante en zeolita se ha caracterizado mediante técnicas, como difracción de Rayos X (DRX, espectroscopia

  5. Influences of Low-Temperature Hydrothermal Fluids on the Re-distributions and Occurrences of Associated Elements in Coal--A Case Study from the Late Permian Coals in the Zhijin Coalfield, Guizhou Province, Southern China

    Institute of Scientific and Technical Information of China (English)

    代世峰; 任德贻; 唐跃刚; 邵龙义; 郝黎明

    2002-01-01

    The occurrences of associated elements and their genetic factors in the No. 30 coal seam in theZhijin Coalfield were studied using instrumental neutron activation analysis, inductively coupled plasma-atomicemission spectroscopy, and a scanning electron microscope equipped with an energy-dispersive X-ray analyzer.And, a microscope photometer system (Leitz MPV-Ⅲ) was used to observe the characteristics of coal petrology.According to the influence degree by the siliceous low-temperature hydrothermal fluids, the organic matter isdivided into four types: A, B, C, and D of the hydrothermally-altered organic matter (HAOM). The study showsthat the high content of Fe (2.31%) is not from pyrite, but mostly from the siliceous low-temperaturehydrothermal fluids. The occurrences of the associated elements in the four organic matter types are different.The contents of Fe, Si, and Al are decreasing, but S and Cu are increasing in the order of the HAOM-A,HAOM-B, HAOM-C, and HAOM-D. The losing rate of sulfur in organic matter is 0.35% and the content of Fetaken from the low-temperature hydrothermal fluids into the organic matter is 0.794% during the siliceouslow-temperature hydrothermal fluids invading the coal seam. The above facts indicate that the low-temperaturehydrothermal fluids play a crucial role in the re-distributions and occurrences of associated elements in coal.

  6. REMEDIATION OF POLLUTED SOILS BY UTILIZING HYDROTHERMALLY TREATED CALCAREOUS FLY ASHES

    Institute of Scientific and Technical Information of China (English)

    A. Moutsatsou; V. Protonotarios

    2006-01-01

    This paper investigates a treated fly ash to act as a synthetic zeolite to remediate soils polluted with heavy metals and metalloids (As, Pb, Cu, Zn, Fe, Cd and Mn). Four types of such 'zeolites' were synthesized by hydrothermal treatment of a calcareous fly ash derived from Greek lignite-fired power plants: two with excess of sodium hydroxide in a a former mining site at Lavrion, Greece. Mobilization and transfer of metals to the retention agents was effected by using HCl aq 1M, with satisfactory results with respect to As, Pb, Cu, Mn and Cd. The great variety of metal complexes in soil was found to be of major importance for the effectiveness of the overall process. The final products were solidified either on their own, or by using additives such as lime and cement.

  7. Continental hydrothermal sedimentary siliceous rock and genesis of superlarge germanium (Ge) deposit hosted in coal:A study from the Lincang Ge deposit, Yunnan, China

    Institute of Scientific and Technical Information of China (English)

    QI Huawen; HU Ruizhong; SU Wenchao; QI Liang; FENG Jiayi

    2004-01-01

    There are abundant hydrothermal sedimentary structures and plant fragment fossils in the siliceous rocks from the Lincang Ge deposit. The major element compositions of these siliceous rocks are characterized by high content SiO2, low TiO2 and Al2O3 concentrations, and low Al/(Al+Fe+Mn) ratios (0.010 on average). The siliceous rocks are distinctly enriched in Ge,Sb, As, W, and secondly enriched in Cs, U, Mo and TI. Their total REE content are generally less than 1μg/g, LREE relatively concentrated, and the values of Eu anomaly and Ce anomaly vary from 0.452 to 5.141 and 0.997 to 1.174, respectively. Their NAS-normalized REE patterns are plain or left-inclined. The Oxygen isotope compositions of these siliceous rocks are similar to those of the hydrothermal siliceous sinter. The above characteristics, as well as the geological setting of the deposit, indicate these siliceous rocks formed in continental hydrothermal environment. As the interlayer or cliff of the Ge-rich coal seams, siliceous rocks tightly contacted with ore-body, and the contents of Ge in siliceous rocks vary from 5.6 to 360 μg/g (78 μg/g on aver-age). The Ge content increased in coal which close to the siliceous rocks. With the increase of Ge content, the typical trace element ratios (i.e., Ge/Ga, Nb/Ta and U/Th) and REE patterns of Ge-rich coal are more close to those of the siliceous rocks. The Ge concentrated in coal seams of the Lincang Ge deposit might be transported by the hydrothermal water, which demonstrated by the siliceous rocks, during the coal-forming processes.

  8. Continental hydrothermal sedimentary siliceous rock and genesis of superlarge germanium (Ge) deposit hosted in coal: A study from the Lincang Ge deposit, Yunnan, China

    Institute of Scientific and Technical Information of China (English)

    QI; Huawen; HU; Ruizhong; SU; Wenchao; QI; Liang; FENG; Jia

    2004-01-01

    There are abundant hydrothermal sedimentary structures and plant fragment fossils in the siliceous rocks from the Lincang Ge deposit. The major element compositions of these siliceous rocks are characterized by high content SiO2, low TiO2 and Al2O3 concentrations, and low Al/(Al+Fe+Mn) ratios (0.010 on average). The siliceous rocks are distinctly enriched in Ge,Sb, As, W, and secondly enriched in Cs, U, Mo and TI. Their total REE content are generally less than 1μg/g, LREE relatively concentrated, and the values of Eu anomaly and Ce anomaly vary from 0.452 to 5.141 and 0.997 to 1.174, respectively. Their NAS-normalized REE patterns are plain or left-inclined. The Oxygen isotope compositions of these siliceous rocks are similar to those of the hydrothermal siliceous sinter. The above characteristics, as well as the geological setting of the deposit, indicate these siliceous rocks formed in continental hydrothermal environment. As the interlayer or cliff of the Ge-rich coal seams, siliceous rocks tightly contacted with ore-body, and the contents of Ge in siliceous rocks vary from 5.6 to 360 μg/g (78 μg/g on aver-age). The Ge content increased in coal which close to the siliceous rocks. With the increase of Ge content, the typical trace element ratios (i.e., Ge/Ga, Nb/Ta and U/Th) and REE patterns of Ge-rich coal are more close to those of the siliceous rocks. The Ge concentrated in coal seams of the Lincang Ge deposit might be transported by the hydrothermal water, which demonstrated by the siliceous rocks, during the coal-forming processes.

  9. Water Absorption and Thickness Swelling behavior of Medium Density Fiberboard Manufactured by Hydrothermally Treated Fibers

    Directory of Open Access Journals (Sweden)

    Peyman Fallah

    2011-01-01

    Full Text Available In this research, water absorption and thickness swelling behavior of hydrothermally modified fiberboard (MDF. Were evaluated Fibers were treated in a stainless steel reactor at temperatures of 120, 150 and 180°C for holding times of 0, 30 and 90 min. Test boards were prepared based on the target density of 0.7g/cm3 at the press temperature of 175°C as well as the pressure of 30 bar and the press time of 5 min. Urea formaldehyde (UF resin was applied at 10% based on the fibers dry weight. Test samples (10×20×20mm were cut from the boards, dried in an oven and soaked in the water. Water absorption, thickness swelling and their rates were measured in the soaked samples. Results revealed that increase of the treatment temperature caused decrease of water absorption and thickness swelling in the treated boards except in samples treated at 120°C. It was also indicated that increase of the holding time did not significantly affect water absorption and thickness swelling.

  10. Effect of Surfactant/Silica and Hydrothermal Time on the Specific Surface Area of Mesoporous Materials from Coal-Measure Kaolin

    Institute of Scientific and Technical Information of China (English)

    WU Qisheng; LI Shuiping

    2011-01-01

    Mesoporous materials with the highest surface area were synthesized by hydrothermal treatment from coal-measure kaolin using cetyltrimethylammonium bromide (CTAB) as template. The effect of several factors on surface area of products also had been discussed. The products were characterized by FTIR, HRTEM and N2 adsorption and desorption isotherm plot methods. There was typical structure as Si-O, Si-OH and Si-O-Si of mesoporous materials in the framework of synthesized materials; the pore size distributions of the products showed a sharp peak at 3.82 nm. The effect of hydrothermal treatment time and the amount of template on the specific surface area of mesoporous materials was important, when the Surf/Si = 0.135, and hydrothermal time = 12 h, and the surface area of the product reached up to 1 070 m2/g, which was higher than other products.

  11. Greater osteoblast and mesenchymal stem cell adhesion and proliferation on titanium with hydrothermally treated nanocrystalline hydroxyapatite/magnetically treated carbon nanotubes.

    Science.gov (United States)

    Wang, Mian; Castro, Nathan J; Li, Jian; Keidar, Michael; Zhang, Lijie Grace

    2012-10-01

    With an increasingly active and aging population, a growing number of orthopedic procedures are performed annually. However, traditional orthopedic implants face many complications such as infection, implant loosening, and poor host tissue integration leading to implant failure. Metal implant materials such as titanium and its alloys are widely used in orthopedic applications mainly based on their excellent mechanical properties and biological inertness. Since human bone extracellular matrix is nanometer in dimension comprised of rich nanostructured hydroxyapatite particles and collagen nanofibers, it is highly desirable to design a biologically-inspired nanostructured coating which renders the biocompatible titanium surface into a biomimetic and bioactive interface, thus enhancing osteoblast adhesion and promoting osseointegration. For this purpose, a biomimetic nanostructured coating based on nanocrystalline hydroxyapatite and single wall carbon nanotubes was designed. Specifically, nano hydroxyapatites with good crystallinity and biomimetic dimensions were prepared via a wet chemistry method and hydrothermal treatment. Microcrystalline hydroxyapatite with larger grain sizes can be obtained without hydrothermal treatment. The carbon nanotubes with different diameter and length were synthesized via an arc plasma method in the presence or absence of a magnetic field. Transmission electron microscopy images illustrate the regular, rod-like nanocrystalline and biomimetic nanostructure of hydrothermally treated nano hydroxyapatite. In addition, the length of carbon nanotubes can be significantly increased under external magnetic fields when compared to nanotubes produced without a magnetic field. More importantly, the in vitro study demonstrated for the first time that osteoblast and mesenchymal stem cell adhesion and proliferation were greater on titanium with hydrothermally treated nanocrystalline hydroxyapatites/magnetically treated carbon nanotubes, which suggests

  12. Hydrothermally treated xylan rich by-products yield different classes of xylo-oligosaccharides

    NARCIS (Netherlands)

    Kabel, M.A.; Carvalheiro, F.; Garrote, G.; Avgerinos, E.; Koukios, E.; Parajo, J.C.; Girio, M.

    2002-01-01

    Four xylan rich by-products, namely wheat bran, brewery's spent grain, corn cobs and Eucalyptus wood, were characterised and subjected to a mild hydrothermal treatment in order to release and degrade the xylan from the starting materials. The chemical characterisation of the feedstock materials, wit

  13. Hydrothermal extraction and gasification of low rank coal with catalyst Al2O3 and Pd/Al2O3

    Science.gov (United States)

    Fachruzzaki, Handayani, Ismi; Mursito, Anggoro Tri

    2017-01-01

    Increasing coal quality is very important in order to utilize low-rank coal. This research is attempted to increase the quality of low-rank coal using hydrothermal process with hot compressed water (HCW) at 200 °C and 3 MPa. The product from this process were solid residue and liquid filtrate with organic component. Product from gasification of the filtrate was synthetic gas. The result showed that higher water flow rate could increase organic component in the filtrate. When a catalyst was used, the extraction process was faster, the organic component in the filtrate was increased while its content was decreased in the residue. Fourier transform infrared spectroscopy (FTIR) analysis indicated that coal extraction using HCW was more effective with catalyst Pd/Al2O3. Increasing the process temperature will increase the amounts CO and H2 gas. In this research, highest net heating value at 800°C using K2CO3 solution and Pd/Al2O3 catalyst was 17,774.36 kJ/kg. The highest cold gas efficiency was 91.29% and the best carbon conversion was 34.78%.

  14. Solvent refined coal studies: effects and characterization of treated solvent refined coal effluent. Progress report, FY 1977

    Energy Technology Data Exchange (ETDEWEB)

    Becker, C.D.; Woodfield, W.G.; Strand, J.A.

    1978-07-01

    The Freshwater Sciences Section of PNL has initiated biologically oriented studies at the P and M solvent refined coal (SRC) pilot plant on the Fort Lewis Reservation in western Washington. Essentially, the study objectives are to identify residual components in the treated SRC process and assess potential for adverse impact on water quality and aquatic biota. Since inception of research in mid-1976, six static toxicity tests with treated SRC process effluent have been conducted. Toxic components, not yet specifically identified, sometimes occur in the effluent. It is believed these components involve organic hydrocarbons of the phenol and cresol groups. Analyses have been obtained on inorganic and organic constituents in partially-treated and treated process effluent. Concentrations of inorganics identified in the effluent did not differ greatly from their concentrations in Lake Sequalitchew or SRC plant tap water, but the low concentrations may be due primarily to dilution with freshwater before discharge. Organics identified in the effluent are similar to those found in samples contaminated with petroleum, and involve many complex hydrocarbons.

  15. Hydrothermally treated oil palm empty fruit bunch cellulose with urea and its dissolution in NaOH-Urea solvent system

    Science.gov (United States)

    Baharin, Khairunnisa Waznah; Zakaria, Sarani; Gan, Sinyee; Jaafar, Sharifah Nabihah Syed; Chia, Chin Hua

    2016-11-01

    Cellulose from Oil Palm Empty fruit bunch (OPEFB) fiber was hydrothermally treated by using autoclave which is immersed in an oil bath at 160 °C for 6 h. OPEFB cellulose was mixed with aqueous urea and stirred for 30 min to obtain a homogenous mixture before transferred into the autoclave. The effect of different cellulose to urea mass ratio (1:4, 1:6 and 1:8) on the molecular weight, degree of polymerization and solubility of the treated cellulose dissolved in NaOH and urea solvent system was studied. The result shows that the solubility of cellulose from OPEFB fiber increased while the molecular weight of cellulose decreased due to the pretreatment done on the OPEFB fiber.

  16. Skin cancer in patients with psoriasis treated with coal tar. A 25-year follow-up study

    Energy Technology Data Exchange (ETDEWEB)

    Pittelkow, M.R.; Perry, H.O.; Muller, S.A.; Maughan, W.Z.; O' Brien, P.C.

    1981-08-01

    For many years, crude coal tar has been used for the treatment of psoriasis. The possible carcinogenic effect of crude coal tar and ultraviolet (UV) radiation (Goeckerman regimen), considered individually or in combination, has been of some concern to physicians. A 25-year follow-up study was completed on 280 patients with psoriasis who were hospitalized and treated with crude coal tar and UV radiation at the Mayo Clinic, Rochester, Minn, during the years 1950 through 1954. The results of this study suggest that the incidence of skin cancer is not appreciably increased above the expected incidence for the general population when patients are treated with coal tar ointments. It seems that the Goeckerman regimen (topical crude coal tar combined with UV radiation) can be used with minimal risk for skin cancer in the treatment of psoriasis.

  17. Nature of Surface Layer and Electrochemical Behavior of NaOH Hydrothermally Treated NiTi Alloy

    Institute of Scientific and Technical Information of China (English)

    P. Shi; F.T. Cheng; H.C. Man

    2004-01-01

    NiTi samples were hydrothermally treated in NaOH at 200℃ with different soaking times. The morphology of the surface layer formed was studied by scanning electron microscopy (SEM). The composition of the layer and the major phases present were determined by energy-dispersive spectroscopy (EDS) and X-ray diffractometry (XRD), respectively. In contrast to the results reported by some authors, the surface layer was essentially Ni(OH)2 instead of being TiO2. The electrochemical behavior of the samples was studied by electrochemical impedance spectroscopy (EIS) in 3.5% NaCI solution at 23℃, and analyzed using a simplified Randle circuit consisting of a resistance R and a capacitance C in parallel. After hydrothermal treatment, R was increased by a factor ranging from 1.5 to 5.0 times, depending on the treatment time. The value of R of all the samples became steady within a period of less than 15 h. Results of the present study indicate that alkaline treatment leads to the growth of an insulating layer on NiTi, but the method is not suitable for surface modification of NiTi implants due to the enhanced Ni content in the surface layer.

  18. Influence of pH on the antioxidant phenols solubilised from hydrothermally treated olive oil by-product (alperujo).

    Science.gov (United States)

    Rubio-Senent, Fátima; Fernández-Bolaños, Juan; García-Borrego, Aránzazu; Lama-Muñoz, Antonio; Rodríguez-Gutiérrez, Guillermo

    2017-03-15

    The application of a novel industrial process based on the hydrothermal treatment of olive oil waste (alperujo) led to a final liquid phase that contained a high concentration of simple phenolic compounds. In this study the effect of pH on phenol extraction with ethyl acetate from the aqueous phase of hydrothermally treated alperujo at 160°C/60min (without modification, pH 4.5, and adjusted to pH 2.5) was evaluated, beside the increase of hydroxytyrosol during the storage. The variation of the concentration of phenolic compounds in each extract was analyzed by HPLC. The phenolic extract obtained at pH 4.5 presented a higher proportion of total and individual phenols and better antioxidant capacity in vitro than the extract obtained at pH 2.5. The use of lower pH values enhances the concentration of hydroxytyrosol in the liquid diminishing the storage times. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Iron oxide nanoparticles embedded in activated carbons prepared from hydrothermally treated waste biomass.

    Science.gov (United States)

    Hao, Wenming; Björkman, Eva; Yun, Yifeng; Lilliestråle, Malte; Hedin, Niklas

    2014-03-01

    Particles of iron oxide (Fe3O4 ; 20–40 nm) were embedded within activated carbons during the activation of hydrothermally carbonized (HTC) biomasses in a flow of CO2. Four different HTC biomass samples (horse manure, grass cuttings, beer production waste, and biosludge) were used as precursors for the activated carbons. Nanoparticles of iron oxide formed from iron catalyst included in the HTC biomasses. After systematic optimization, the activated carbons had specific surface areas of about 800 m2g1. The pore size distributions of the activated carbons depended strongly on the degree of carbonization of the precursors. Activated carbons prepared from highly carbonized precursors had mainly micropores, whereas those prepared from less carbonized precursors contained mainly mesopores. Given the strong magnetism of the activated carbon–nano-Fe3O4 composites, they could be particularly useful for water purification.

  20. Behavior of polymer-based electroactive actuator incorporated with mild hydrothermally treated CNTs

    Science.gov (United States)

    Melvin, Gan Jet Hong; Ni, Qing-Qing; Natsuki, Toshiaki

    2014-12-01

    We fabricated an actuator that was made from polyurethane (PU) with carbon nanotubes (CNTs) as the filler. To improve the dispersion of the CNTs, a mild hydrothermal treatment was carried out. Carboxyl and hydroxyl groups were introduced to the surface of the CNTs, and they were found to be highly dispersed in polar solvents such as dimethylformamide. To evaluate these films, we mainly focused on electrical properties, such as dielectric spectroscopy, space charge measurements, and actuator behavior. We found that the PU/CNTs film bents toward the cathode when an electric field was applied, and it reverted to its original position when the electric field was removed. Upon the inclusion of the CNTs as the filler for the polymer, the electrical properties of the films improved significantly. The highly polarized films had a high relative permittivity, and this produced a higher Maxwell pressure, which assisted the actuation. A high accumulated charge density was observed from space charge measurements in some of the films, and this explains the bending direction and the actuation mechanism.

  1. Isolation and Structural Characterization of Lignin from Cotton Stalk Treated in an Ammonia Hydrothermal System

    Science.gov (United States)

    Kang, Sumin; Xiao, Lingping; Meng, Lingyan; Zhang, Xueming; Sun, Runcang

    2012-01-01

    To investigate the potential for the utilization of cotton stalk, ammonia hydrothermal treatment was applied to fractionate the samples into aqueous ammonia-soluble and ammonia-insoluble portions. The ammonia-soluble portion was purified to yield lignin fractions. The lignin fractions obtained were characterized by wet chemistry (carbohydrate analysis) and spectroscopy methods (FT-IR, 13C and 1H-13C HSQC NMR spectroscopy) as well as gel permeation chromatography (GPC). The results showed that the cotton stalk lignin fractions were almost absent of neutral sugars (0.43%–1.29%) and had relatively low average molecular weights (1255–1746 g/mol). The lignin fractions belonged to typical G-S lignin, which was composed predominately of G-type units (59%) and noticeable amounts of S-type units (40%) together with a small amount of H-type units (~1%). Furthermore, the ammonia-extractable lignin fractions were mainly composed of β-O-4′ inter-unit linkages (75.6%), and small quantities of β-β′ (12.2%), together with lower amounts of β-5′ carbon-carbon linkages (7.4%) and p-hydroxycinnamyl alcohol end groups. PMID:23203120

  2. Sorption phenomena of methanol on heat treated coal; Netsushori wo hodokoshita sekitan no methanol kyuchaku tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Yasuda, H.; Kaiho, M.; Yamada, O.; Soneda, Y.; Kobayashi, M.; Makino, M. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    Experiments were carried out to learn methanol sorption characteristics of heat-treated coal. When Taiheiyo coal is heat-treated at 125{degree}C, performed with a first methanol adsorption at 25{degree}C, and then desorption at 25{degree}C, a site with strong interaction with methanol and a site with relatively weak interaction are generated in test samples. A small amount of methanol remains in both sites. Then, when the methanol is desorbed at as low temperature as 70{degree}C, the methanol in the site with strong interaction remains as it has existed therein, but the methanol in the site with relatively weak interaction desorbs partially, hence the adsorption amount in a second adsorption at 25{degree}C increases. However, when desorption is performed at as high temperature as 125{degree}C, the methanol in the site with strong interaction also desorbs, resulting in increased adsorption heat in the second adsorption. The adsorption velocity drops, however. Existence of methanol in a site with strong interaction affects the adsorption velocity, but no effect is given by methanol in a site with weak interaction. 3 refs., 4 figs.

  3. Priority pollutants and associated constituents in untreated and treated discharges from coal mining or processing facilities in Pennsylvania, USA

    Science.gov (United States)

    Cravotta, III, Charles A.; Keith B.C. Brady,

    2015-01-01

    Clean sampling and analysis procedures were used to quantify more than 70 inorganic constituents, including 35 potentially toxic or hazardous constituents, organic carbon, and other characteristics of untreated (influent) and treated (effluent) coal-mine discharges (CMD) at 38 permitted coal-mining or coal-processing facilities in the bituminous coalfield and 4 facilities in the anthracite coalfield of Pennsylvania. Of the 42 facilities sampled during 2011, 26 were surface mines, 11 were underground mines, and 5 were coal refuse disposal operations. Treatment of CMD with caustic soda (NaOH), lime (CaO or Ca(OH)2), flocculent, or limestone was ongoing at 21%, 40%, 6%, and 4% of the facilities, respectively; no chemicals were added at the remaining facilities. All facilities with CMD treatment incorporated structures for active or passive aeration and settling of metal-rich precipitate.

  4. Inhibition and recovery of nitrification in treating real coal gasification wastewater with moving bed biofilm reactor

    Institute of Scientific and Technical Information of China (English)

    Huiqiang Li; Hongjun Han; Maoan Du; Wei Wang

    2011-01-01

    Moving bed biofilm reactor (MBBR) was used to treat real coal gasification wastewater.Nitrification of the MBBR was inhibited almost completely during start-up period.Sudden increase of influent total NH3 concentration was the main factor inducing nitrification inhibition.Increasing DO concentration in the bulk liquid (from 2 to 3 mg/L) had little effect on nitrification recovery.Nitrification of the MBBR recovered partially by the addition of nitrifying sludge into the reactor and almost ceased within 5 days.Nitrification ratio of the MBBR achieved 65% within 12 days by increasing dilute ratio of the influent wastewater with tap water.The ratio of nitrification decreased to 25% when infiuent COD concentration increased from 650 to 1000 mg/L after nitrification recovery and recovered 70%for another 4 days.

  5. Inhibition and recovery of nitrification in treating real coal gasification wastewater with moving bed biofilm reactor.

    Science.gov (United States)

    Li, Huiqiang; Han, Hongjun; Du, Maoan; Wang, Wei

    2011-01-01

    Moving bed biofilm reactor (MBBR) was used to treat real coal gasification wastewater. Nitrification of the MBBR was inhibited almost completely during start-up period. Sudden increase of influent total NH3 concentration was the main factor inducing nitrification inhibition. Increasing DO concentration in the bulk liquid (from 2 to 3 mg/L) had little effect on nitrification recovery. Nitrification of the MBBR recovered partially by the addition of nitrifying sludge into the reactor and almost ceased within 5 days. Nitrification ratio of the MBBR achieved 65% within 12 days by increasing dilute ratio of the influent wastewater with tap water. The ratio of nitrification decreased to 25% when influent COD concentration increased from 650 to 1000 mg/L after nitrification recovery and recovered 70% for another 4 days.

  6. Hydrothermally treated chitosan hydrogel loaded with copper and zinc particles as a potential micro-nutrient based antimicrobial feed additive

    Directory of Open Access Journals (Sweden)

    Parthiban eRajasekaran

    2015-11-01

    Full Text Available Large-scale use of antibiotics in food animal farms as growth promoters is considered as one of the driving factors behind increasing incidence of microbial resistance. Several alternatives are under investigation to reduce the amount of total antibiotics used in order to avoid any potential transmission of drug resistant microbes to humans through food chain. Copper sulfate and zinc oxide salts are used as feed supplement as they exhibit antimicrobial properties in addition to being micronutrients. However, higher dosage of copper and zinc (often needed for growth promoting effect to animals is not advisable because of potential environmental toxicity arising from excreta. Innovative strategies are needed to utilize the complete potential of trace minerals as growth promoting feed supplements. To this end, we describe here the development and preliminary characterization of hydrothermally treated chitosan as a delivery vehicle for copper and zinc nanoparticles that could act as a micronutrient based antimicrobial feed supplement. Material characterization studies showed that hydrothermal treatment makes a chitosan hydrogel that re-arranged to capture the copper and zinc metal particles. Systemic antimicrobial assays showed that this chitosan biopolymer matrix embedded with copper (57.6 μg/ml and zinc (800 μg/ml reduced the load of model gut-bacteria (target organisms of growth promoting antibiotics such as Escherichia coli, Enterococcus faecalis, Staphylococcus aureus and Lactobacillus fermentum under in vitro conditions. Particularly, the chitosan/copper/zinc hydrogel exhibited significantly higher antimicrobial effect against L. fermentum, one of the primary targets of antibiotic growth promoters. Additionally, the chitosan matrix ameliorated the cytotoxicity levels of metal supplements when screened against a murine macrophage cell line RAW 264.7 and in TE-71, a murine thymic epithelial cell line. In this proof of concept study, we show

  7. Bacterial phylogenetic diversity in a constructed wetland system treating acid coal mine drainage

    Energy Technology Data Exchange (ETDEWEB)

    Nicorarat, D.; Dick, W.A.; Dopson, M.; Tuovinen, O.H. [Ohio State University, Columbus, OH (USA)

    2008-02-15

    Microorganisms in acid mine drainage are typically acidophiles that mediate the oxidation of reduced compounds of iron and sulfur. However, microbial populations in wetland systems constructed to treat acid mine drainage are not well characterized. This study was to analyze bacterial diversity, using cultivation-independent molecular ecological techniques, in a constructed wetland that received acid drainage from an abandoned underground coal mine. DNA was purified from Fe(III)-precipitates from the oxidized surface zone of wetland sediments and 16S rRNA gene sequences were amplified and cloned. A total of 200 clones were analyzed by restriction fragment length polymorphism (RFLP) and 77 unique RFLP patterns were obtained with four restriction enzymes. Of these patterns, 30 most dominant unique clones were selected for sequencing of their 16S rRNA genes. Half of these 30 clones could be matched with autotrophic iron- and sulfur-oxidizing bacteria (Acidithiohacillus ferrooxidans and Acidithiobacillus thiooxidans). Several clones also formed a clade with heterotrophic iron-oxidizing bacteria (TRA2-10, TRA3-20, and TRA5-3) and heterotrophic bacteria (Stenotrophomas maltophilia, Bordetella spp., Alcalgenes sp., Alcaligenesfaecalis, and Alcaligenes xylosoxidans). Approximately 40% and 35% of the analyzed RFLP restriction patterns were consistent with A. ferrooxidans and A. thiooxidans, respectively. The relatively high frequency of acidithiobacilli is consistent with the chemical and physical characteristics of this site i.e., continuous, abundant supply of reduced iron and sulfur compounds, pH 3-4, ambient temperature, and limited organics originating from the coal seam and from vegetation or soil surrounding the inlet channel to the wetland.

  8. Prospects for co-firing of clean coal and creosote-treated waste wood at small-scale power stations

    Directory of Open Access Journals (Sweden)

    Zandersons Janis

    2006-01-01

    Full Text Available If a small-scale clean coal fueled power plant is co-fueled with 5% of creosote-treated used-up sleeper wood, the decontamination by carbonisation at 500 °C in an indirectly heated rotary kiln with the diameter 1.7 m and effective length 10 m can be realized. It should be included in the "3R Clean Coal Carbonisation Plant" system, which processes coal. It will improve the heat balance of the system, since the carbonisation of wood will deliver a lot of high caloricity pyroligneous vapour to the joint furnace of the "3R Clean Coal Carbonisation Plant". Pine wood sleeper sapwood contains 0.25% of sulphur, but the average pine sleeper wood (sapwood and heartwood 0.05% of sulphur. Most of the sulphur is lost with the pyroligneous vapour and burned in the furnace. Since the "3R Clean Coal Carbonisation Plant" is equipped with a flue gases cleaning system, the SO2 emission level will not exceed 5 mg/m3. The charcoal of the sapwood portion of sleepers and that of the average sleeper wood will contain 0.22% and 0.035% of sulphur, respectively. The increase of the carbonisation temperature does not substantially decrease the sulphur content in charcoal, although it is sufficiently low, and the charcoal can be co-fired with clean coal. The considered process is suitable for small power plants, if the biomass input in the common energy balance is 5 to 10%. If the mean distance of sleepers transportation for Central and Eastern Europe is estimated not to exceed 200 km, the co-combustion of clean coal and carbonized sleepers would be an acceptable option from the environmental and economic points of view.

  9. Myeloperoxidase - 463A variant reduces benzo(a)pyrene diol epoxide DNA adducts in skin of coal tar treated patients

    Energy Technology Data Exchange (ETDEWEB)

    Rojas, M.; Godschalk, R.; Alexandrov, K.; Cascorbi, I.; Kriek, E.; Ostertag, J.; Van Schooten, F.J.; Bartsch, H. [German Cancer Research Center, Heidelberg (Germany). Div. of Toxicology & Cancer Risk Factors

    2001-07-01

    The skin of atopic dermatitis patients provides an excellent model to study the role of inflammation in benzo(a)pyrene (BaP) activation, since these individuals are often topically treated with ointments containing high concentrations of BaP. The authors determined, by HPLC with fluorescence detection, the BaP diol epoxide (BPDE)-DNA adduct levels in human skin after topical treatment with coal tar and their modulation by the -453G into A myeloperoxidase (MPO) polymorphism, which reduces MPO mRNA expression. The data show for the first time: (i) the in vivo formation of BPDE-DNA adducts in human skin treated with coal tar; (ii) that the MPO-463AA/AG genotype reduced BPDE-DNA adduct levels in human skin.

  10. An assessment of acid wash and bioleaching pre-treating options to remove mercury from coal

    Energy Technology Data Exchange (ETDEWEB)

    Laura C. Dronen; April E. Moore; Evguenii I. Kozliak; Wayne S. Seames [University of North Dakota, Grand Forks, ND (USA). Department of Chemical Engineering

    2004-01-01

    The United States Environmental Protection Agency is expected to begin regulating the release of vapor-phase mercury from coal-fired power plants in the year 2007. Chemical pre-treatment methods were investigated for mercury removal effectiveness from pulverized low-sulfur North Dakota lignite coal. More limited results were obtained for a pulverized high-sulfur Blacksville bituminous coal. A two-step acid wash treatment showed removal rates of 60 90%, compared to one-step treatments with concentrated HCl, which yielded removals of 30 38%. Removal effectiveness is similar for first step solvents of water, pH 5.0 acid, or pH 2.0 acid followed by concentrated HCl as the second step solvent, and is independent of first step incubation time. Neither of two bacterial strains, Thiobacillus ferrooxidans and T. thiooxidans, was found effective for mercury removal. 23 refs., 5 tabs.

  11. Effect of coal rank and mineral matter on gasification reactivity of coal char treated at high temperature; Netsushorishita sekitan char no gas ka tokusei ni taisuru tanshu oyobi kobutsushitsu no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Morishita, K.; Takei, H.; Harano, A.; Takarada, T. [Gunma University, Gunma (Japan). Faculty of Engineering

    1996-10-28

    In the wide range from brown coal to anthracite, an investigation was made of effects of heat treatment on physical/chemical properties and of coal rank dependence. For the experiment, 12 kinds of coal samples were used, and for heat treatment, the fluidized bed heated by the electric furnace and the infrared-ray gold image furnace were used. To examine characteristics of the heat-treated coal char, conducted were oxygen gasification, TPD measurement, XRD measurement, alkali metal measurement, and pore distribution measurement. The following were obtained from the experiment. The gasification reaction rate of the char heat-treated in the temperature range between 900{degree}C to 1700{degree}C decreases with a rise of the temperature of heat treatment, and the degree of decrease in the rate depends on coal rank. The order of gasification rate between coal ranks depends on the temperature of heat treatment, and the lower the heat treatment temperature is, the more largely the gasification rate is influenced by catalysis of mineral matters included in the coal. As causes of the decrease in gasification rate associated with the rise in temperature of heat treatment, indicated were release of alkali metal having catalysis and decrease of active sites by carbonaceous crystallinity. 6 figs.

  12. Performance study of vegetated sequencing batch coal slag bed treating domestic wastewater in suburban area

    Energy Technology Data Exchange (ETDEWEB)

    Chan, S.Y.; Tsang, Y.F.; Chua, H.; Sin, S.N.; Cui, L.H. [Hong Kong Polytechnic University, Hong Kong (China)

    2008-06-15

    A practical and affordable wastewater treatment system serving small community in suburban areas was studied. The system was a vegetated sequencing batch coal slag bed integrated with the rhythmical movement of wastewater and air like that of a sequencing batch reactor. The removal mechanisms capitalized on the pollutant removal process in conventional constructed wetland. Cyperus alternifolius was planted into the coal slag bed to form a novel plant-soil-microbial interactive system. Nutrients in the domestic wastewater, which cause environmental nuisance like eutrophication, were targeted to be eliminated by the process design. Operated with the contact time of 18 h, the treatment systems achieved around 60% removal efficiency for carbonaceous matters. The removals of ammonia nitrogen and phosphorus were about 50% and 40%, respectively, while the removal of total suspended solids was approaching 80%. From the current study.. the construction cost of the vegetated sequencing batch coal slag bed was 256 RMB/m{sup 3} and the operation cost was 0.13 RMB/m{sup 3}. With the advantages of ease of operation, low costs, desirable treatment efficiency and aesthetic value, the vegetated sequencing batch coal slag bed is proposed to be an alternative for onsite domestic wastewater treatment in suburban areas.

  13. Dye Sensitized Solar Cell with Conventionally Annealed and Post-Hydrothermally Treated Nanocrystalline Semiconductor Oxide TiO2 Derived from Sol-Gel Process

    Directory of Open Access Journals (Sweden)

    Akhmad Yuwono

    2011-05-01

    Full Text Available Dye-sensitized solar cell (DSSC is one of the very promising alternative renewable energy sources to anticipate the declination in the fossil fuel reserves in the next few decades and to make use of the abundance of intensive sunlight energy in tropical countries like Indonesia. In the present study, TiO2 nanoparticles of different nanocrystallinity was synthesized via sol−gel process with various water to inorganic precursor ratio (Rw of 0.85, 2.00 and 3.50 upon sol preparation, followed with subsequent drying, conventional annealing and post-hydrothermal treatments. The resulting nanoparticles were integrated into the DSSC prototype and sensitized with an organic dye made of the extract of red onion. The basic performance of the fabricated DSSC has been examined and correlated to the crystallite size and band gap energy of TiO2 nanoparticles. It was found that post-hydrothermally treated TiO2 nanoparticles derived from sol of 2.00 Rw, with the most enhanced nanocrystalline size of 12.46 nm and the lowest band gap energy of 3.48 eV, showed the highest open circuit voltage (Voc of 69.33 mV.

  14. Treating dye wastewater by TiO2 coated on coal cinder

    Institute of Scientific and Technical Information of China (English)

    LIU Jian-hua; WANG Hai-jun

    2009-01-01

    We investigated the photocatalytic degradation of dye wastewater by using titanium dioxide (TiO2) coated on a coal cinder. The coal cinder was used as the carrier, with a thin film of TiO2 coated on it by using the sol-gel method. Using the Congo red as the model pollutant for dye wastewater, we studied the decolorization efficiency, and effects of TiO2 film thickness and roasting temperature on the efficiency. We also evaluated the recycling and regeneration of the immobilized TiO2 (TiO2/cinder). Results show that the decolorization rate of Congo red solution was more than 98% after 2 h treatment when we used TiO2/cinder calcined at 500 °C for 2 h and coated four times as the photocatalyst. At the same time, the TiO2/cinder remained high catalytic activity after being reused and regenerated for many times.

  15. Coal demineralization with Ca(OH)2. Hydrothermal reaction between Ca(OH)2 and quartz; Ca(OH)2 wo mochiita sekitan no kagakuteki dakkai. Ca(OH)2 to sekitan no suinetsu hanno

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J.; Tomita, A. [Tohoku University, Sendai (Japan). Institute for Chemical Reaction Science

    1996-10-28

    Coal demineralization mechanism and its optimum condition were studied by hydrothermal reaction between Ca(OH)2 and quartz as a coal demineralization model. In experiment, the mixture of powder quartz and Ca(OH)2 water slurry was subjected to reaction in an autoclave under spontaneous pressure at 175-340{degree}C. After dried in N2 gas atmosphere at 105{degree}C, the reaction product was analyzed by X-ray diffraction, thermo-balance and differential thermal analysis. In measurement of quartz conversion, the specimen was analyzed by X-ray diffraction after removal of bound water by heat treatment at 850{degree}C. The mixture of clean coal deashed by NaOH and a fixed amount of quartz was also used as specimen for experiment. As the experimental result, dicalcium silicate hydrate was mainly produced at 175{degree}C, and the product changed into xonotlite through tobermorite by longer treatment at higher temperature. For complete reaction of quartz, heat treatments for 7 and 5 hours at 300 and 400{degree}C were necessary, respectively. 2 refs., 2 figs., 2 tabs.

  16. Coal cinder filtration as pretreatment with biological processes to treat pharmaceutical wastewater.

    Science.gov (United States)

    Zheng, Wei; Li, Xiao-ming; Hao, Zhi-ming; Wang, Dong-bo; Yang, Qi; Zeng, Guang-ming

    2010-01-01

    This study aims at coupling coal cinder filter with biological process to improve pharmaceutical wastewater quality and reduce the disposal cost. In the coal cinder filter, the removal efficiencies of COD, BOD(5), SS and color were 90+/-2%, 72+/-2%, 95+/-2% and 80+/-2%, respectively. The results attribute to the big specific surface area and strong adsorption ability. Coal cinder filter removes a large portion of the pollutants in the influent wastewater, which would strongly stable the effluent waste water quality, and reduce the load of follow-up biological treatment process. The average removal efficiencies for COD, BOD(5), SS and color of the combined process were about 99.7+/-3%, 98.2+/-4%, 98.5+/-3% and 96.3+/-2%, respectively, with the average effluent quality of COD 16+/-1 mg/L, BOD(5) 11+/-1 mg/L, SS 10+/-0.6 mg/L and color 22+/-1 (multiple), which are consistent with the national requirements of the waste pollutants for pharmaceutical industry of chinese traditional medicine discharge standard (GB 21906-2008). The results indicated that the combined procedure could offer an attractive solution for pharmaceutical wastewater treatment with considerable low cost.

  17. Toxicity of granular activated carbon treated coal gasification water as determined by the Microtox test and Escherichia coli.

    Science.gov (United States)

    Makino, Y; Adams, J C; McTernan, W F

    1986-01-01

    The Microtox assay and various parameters (growth, ATP concentration and electrochemical detection) of Escherichia coli were used to assess the toxicity of various levels of granular activated carbon treated coal gasification process water. The generation time of E. coli was statistically significantly slower at the level of 50 percent treatment than any other level of treatment. No differences were seen for ATP concentration per cell or in the electrochemical detection methods for any level treatment. There was a very high correlation between total organic carbon removal by GAC treatment and reduction in toxicity as measured by the Microtox system. However, even the treated water which had 91 percent of the TOC removed was still highly toxic.

  18. Strong bonding strength between HA and (NH4)2S2O8-treated carbon/carbon composite by hydrothermal treatment and induction heating.

    Science.gov (United States)

    Xiong, Xin-bo; Zeng, Xie-rong; Zou, Chun-li; Zhou, Ji-Zhao

    2009-06-01

    Carbon/carbon composite with hydroxyapatite (HA) coating is an attractive material in the dental and orthopedic fields, but the reported bonding strength between them was very poor. In this study, a compact crystalline HA coating on (NH(4))(2)S(2)O(8)-treated C/C substrate about 10 microm in width was obtained by hydrothermal treatment and induction heating. The microstructure, composition and morphologies of the as-prepared coatings were identified by X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. A strong shear strength averaging 74.2 MPa between C/C substrate and HA was achieved and adhesion failures were observed more frequently than cohesion failures. The coating adhesion measured using a scratch test was 23 N and the reasons for this are discussed.

  19. Recovery strategies for tackling the impact of phenolic compounds in a UASB reactor treating coal gasification wastewater.

    Science.gov (United States)

    Wang, Wei; Han, Hongjun

    2012-01-01

    The impact of phenolic compounds (around 3.2 g/L) resulted in a completely failed performance in a mesophilic UASB reactor treating coal gasification wastewater. The recovery strategies, including extension of HRT, dilution, oxygen-limited aeration, and addition of powdered activated carbon were evaluated in batch tests, in order to obtain the most appropriate way for the quick recovery of the failed reactor performance. Results indicated that addition of powdered activated carbon and oxygen-limited aeration were the best recovery strategies in the batch tests. In the UASB reactor, addition of powdered activated carbon of 1 g/L shortened the recovery time from 25 to 9 days and oxygen-limited aeration of 0-0.5 mgO2/L reduced the recovery time to 17 days. Reduction of bioavailable concentration of phenolic compounds and recovery of sludge activity were the decisive factors for the recovery strategies to tackle the impact of phenolic compounds in anaerobic treatment of coal gasification wastewater.

  20. Impact of high external circulation ratio on the performance of anaerobic reactor treating coal gasification wastewater under thermophilic condition.

    Science.gov (United States)

    Jia, Shengyong; Han, Hongjun; Zhuang, Haifeng; Hou, Baolin; Li, Kun

    2015-09-01

    A laboratory-scale external circulation anaerobic reactor (ECAR) was developed to treat actual coal gasification wastewater. The external circulation ratio (R) was selected as the main operating variable for analysis. From the results, with the hydraulic retention time of 50h, pH > 8.0 and R of 3, the COD, total phenols, volatile phenol and NH4(+)-N removal efficiencies were remarkably increased to 10 ± 2%, 22 ± 5%, 18 ± 1%, and -1 ± 2%, respectively. Besides, increasing R resulted in more transformation from bound extracellular polymeric substances (EPS) to free EPS in the liquid and the particle size distribution of anaerobic granular sludge accumulated in the middle size range of 1.0-2.5mm. Results showed the genus Saccharofermentans dominanted in the ECAR and the bacterial community shift was observed at different external circulation ratio, influencing the pollutants removal profoundly.

  1. Hydrothermal pretreatment of biomass for pellet production

    Energy Technology Data Exchange (ETDEWEB)

    Tooyserkani, Z. [British Columbia Univ., Vancouver, BC (Canada). Clean Energy Research Centre, Biomass and Bioenergy Research Group

    2010-07-01

    This presentation discussed innovative technologies for the production of wood pellets using the hydrothermal pre-treatment of biomass. Conventional techniques use low-cost mill residues, such as saw dust and shavings, as feedstock to produce durable, low-ash pellets. However, mill residues are becoming less available as a result of fewer saw mills, increased pellet production, and increased competition for saw dust. Advanced techniques use mixed biomass such as logging residue as feedstock, creating pellets that are durable for handling and long-term storage, of a higher energy density for transport and mixing with coal for co-firing, and a choice feedstock for biofuels. Advanced pellet production uses steam explosion/pre-treatment in which biomass receives a short-term high-pressure steam treatment followed by sudden decompression. Mild torrefaction seems to have positive feedback, and steam-treated pellets are durable with superior hydrophobicity. 3 figs., 3 tabs.

  2. Research development of zeolites preparation from coal fly ash by microwave-hydrothermal synthesis%粉煤灰微波-水热合成法制备分子筛的研究进展

    Institute of Scientific and Technical Information of China (English)

    陈彦广; 徐婷婷; 韩洪晶; 王新惠; 王琦旗; 韩洪伟; 宋军; 宋华

    2015-01-01

    煤炭燃烧与转化过程产生大量的固体废弃物粉煤灰,其大量排放与堆积造成的环境污染已引起人们的广泛重视,以粉煤灰为原料制备分子筛是粉煤灰资源化利用的重要途径。传统水热合成加热方式所需合成时间较长,能量消耗量大;微波加热可极大地缩短反应时间,并对产物晶粒大小、纯度和分子筛产品性能有明显改善。本文介绍了微波-水热合成法将粉煤灰转化为不同类型分子筛的反应机理及其所制备的分子筛产品的应用,分析了粉煤灰制备分子筛过程中阴离子和阳离子、前驱液的碱度、晶种、加热方式等关键因素的影响,讨论了粉煤灰经过分级处理和除杂后,用微波-水热相结合替代传统加热对分子筛产品纯度、晶粒尺寸、孔径分布的调控和优化规律,为粉煤灰合成不同种类分子筛提供了重要的理论指导与发展方向。同时提出了将煤粉炉粉煤灰经除杂和分级处理获取其中的硅铝组分、通过调控硅铝比以微波-水热合成制备方沸石的新工艺,为粉煤灰资源化利用开辟了新途径。%Coal fly ash(CFA),a solid waste formed in the process of coal combustion and conversion has caused serious environmental pollution by large-scale emission and accumulation,and has attracted extensive attention. Preparation of zeolite from CFA is an important way for resource utilization of CFA. It takes longer crystallization time and more energy in the hydrothermal synthesis process by traditional heating method than by the microwave heating method. Moreover,it is easier to obtain zeolite with fine grain size and high performance by the microwave-hydrothermal synthesis method. The mechanism and application of different types of zeolite from CFA by the microwave hydrothermal synthesis method were introduced. The effects of cations and anions,alkalinity of liquid precursor, seeding and heating manner were analyzed

  3. Study on Hydrothermal Synthesis Technique of Spinel CoAl2O4 Nanocolorants%尖晶石型纳米CoAl2O4色料水热合成工艺研究

    Institute of Scientific and Technical Information of China (English)

    卢希龙; 胡琪; 洪琛; 陈云霞; 沈华荣; 曹春娥

    2012-01-01

    分别以钴、铝的氯化物、硝酸盐和硫酸盐为起始原料,NaOH为沉淀剂,用水热法合成了纳米尖晶石型钴蓝色料.分别研究了填充度、pH值、nCo/nAl、起始原料种类以及浓度等对合成色料物相组成、颗粒大小与形貌和呈色的影响.用XRD、TEM和色度分析对样品进行了表征.结果表明:以浓度分别为0.15 mol/L和0.3 mol/L的CoCl2·6H20和AlCl3为起始原料,在填充度为70%、pH值为13、nCo/nAl为1/2的条件下,245℃水热培育20h制得呈色良好的尖晶石型钴蓝色料,颗粒为八面体型,晶型完整,粒径多为100 nm以下.相同条件下,以钴、铝的硫酸盐为起始原料,产物中除COAl204外,还有Co-Al LDHs、γ-AlO(OH)和β-Al(OH)3;以钴、铝的硝酸盐为起始原料,样品呈绿色,颗粒为八面体型Co-Al204,粒径多为100 nm以上.%Spinel CoAl2O4 nanocolorants were synthesized by hydrothermal method using chloride, nitrate and sulfate salts of cobalt and aluminum as raw materials, NaOH as precipitating agent. Hie influence of filling factors, pH values, nCo/nAl ratios and the species of starting materials and their concentration on the phase composition, particle size and morphology and coloration of the pigments was systematically examined. X-ray diffraction, transmission electron microscope and colorimetric analysis were employed to characterize the as-prepared samples. Results indicate that spinel type cobalt blue pigments were achieved by hydrothermal treatment at 245 ℃ for 20 h, using CoCl2 o 6H2O and A1C13 with concentration of 0.15 mol/L and 0.3 mol/L, filling factor of 70%, pH value of 13 and nCo/nAl of 1/2, respectively. The crystals are of octahedral shape with high perfection and most of the sizes are below 100 tun. Under the same processing conditions, besides CoAl2O4, there are also Co-Al LDHs, γ-A10(0H) and β-Al(OH)3 phases present in the resulting pigments prepared when the starting materials is sulfate salts of cobalt and aluminum

  4. Nitrite accumulation performance of aerobic MBBR treating Lurgi coal gasification waste water by adjusting pollutant load and DO concentration.

    Science.gov (United States)

    Li, Hui-Qiang; Han, Hong-Jun

    2015-01-01

    An aerobic moving bed biofilm reactor (MBBR) was adopted to treat Lurgi coal gasification waste water (LCGW) in about 10 months. The pollutant load and dissolve oxygen (DO) concentration were adjusted by trying to maximize the accumulation of [Formula: see text] in the MBBR for LCGW treatment. The highest [Formula: see text] accumulation proportion [Formula: see text] was 73.9%, but was not stable with influent chemical oxygen demand (COD) and DO concentrations of around 1000 and 1.5 mg/L, respectively. Around 1500 mg/L of influent COD concentration and 1.5 mg/L of DO concentration were proper operation conditions for the aerobic MBBR to achieve relatively stable [Formula: see text] accumulation, with [Formula: see text] ratio at 53% and [Formula: see text] ratio at just 4.3% in the effluent. More specifically, free ammonia concentration and DO concentration affected [Formula: see text] accumulation much more obvious than phenols concentration. The activity and quantity of nitrifying bacteria growth in suspended sludge and biofilm of the MBBR were monitored simultaneously to explain the variations of [Formula: see text] accumulation performance under different operation conditions. An aerobic moving bed biofilm reactor (MBBR) was adopted to treat Lurgi coal gasification waste water (LCGW)in about 10 months. The pollutant load and dissolve oxygen (DO) concentration were adjusted by trying to maximize the accumulation of NO(−)(2)−N in the MBBR for LCGW treatment. The highest NO(−)(2)−N accumulation proportion(NO(−)(2)−Neffluent/TN effluent) was 73.9%, but was not stable with influent chemical oxygen demand (COD) and DO concentrations of around 1000 and 1.5 mg/L, respectively. Around 1500 mg/L of influent COD concentration and 1.5 mg/L of DO concentration were proper operation conditions for the aerobic MBBR to achieve relatively stable NO(−)(2)−N accumulation,with NO(−)(2)−N/TN ratio at 53% and NO(-)(3)−N/TN ratio at just 4.3% in the

  5. Catalytic Hydrothermal Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.

    2015-05-31

    The term “hydrothermal” used here refers to the processing of biomass in water slurries at elevated temperature and pressure to facilitate the chemical conversion of the organic structures in biomass into useful fuels. The process is meant to provide a means for treating wet biomass materials without drying and to access ionic reaction conditions by maintaining a liquid water processing medium. Typical hydrothermal processing conditions are 523-647K of temperature and operating pressures from 4-22 MPa of pressure. The temperature is sufficient to initiate pyrolytic mechanisms in the biopolymers while the pressure is sufficient to maintain a liquid water processing phase. Hydrothermal gasification is accomplished at the upper end of the process temperature range. It can be considered an extension of the hydrothermal liquefaction mechanisms that begin at the lowest hydrothermal conditions with subsequent decomposition of biopolymer fragments formed in liquefaction to smaller molecules and eventually to gas. Typically, hydrothermal gasification requires an active catalyst to accomplish reasonable rates of gas formation from biomass.

  6. Performance of double-layer biofilter packed with coal fly ash ceramic granules in treating highly polluted river water.

    Science.gov (United States)

    Jing, Zhaoqian; Li, Yu-You; Cao, Shiwei; Liu, Yuyu

    2012-09-01

    To improve trickling filters' denitrification efficiency, a biofilter with a trickling upper layer and a submerged lower layer was developed and applied in treating highly polluted river water. It was packed with porous coal fly ash ceramic granules. Its start-up characteristics, influence of hydraulic loading rates (HLR), carbon/nitrogen (C/N) ratio and filter depth on pollutants removal were investigated. The results indicated this biofilter was started quickly in 16 days with river sediment as inoculum. Alternating nitrification and denitrification were achieved when water flowed downwards. COD and nitrogen were mainly removed in the upper layer and the lower layer, respectively. With HLR of 4.0-5.0m(3)/(m(2)d), chemical oxygen demand (COD), ammonium (NH(4)(+)-N) and total nitrogen (TN) in the effluent were below 50, 5 and 15 mg/L, respectively. This biofilter removed more than 80% of COD, 85% of NH(4)(+)-N and 60% of TN with C/N ratios ranging from 6 to 10.

  7. Performance of the Full-scale Loop Hybrid Reactor Treating Coal Gasification Wastewater under Different Recirculation Modes

    Institute of Scientific and Technical Information of China (English)

    Qian Zhao; Hongjun Han; Fang Fang; Wang Bing

    2015-01-01

    This paper aims to investigate the simultaneous removal efficiencies of both COD and nitrogen in a single reactor treating coal gasification wastewater ( CGW ) . A novel loop hybrid reactor was developed and operated under different recirculation modes in order to achieve simultaneous removal of refractory compounds and total nitrogen ( TN) in a full⁃scale CGW treatment plant. Mid⁃ditch recirculation was superior to other operational modes in terms of the NH3⁃N and TN removal, resulting in a TN removal efficiency of 52. 3%. Although the system achieved equal COD removal rates under different recirculation modes, hydrophobic acid ( HPO⁃A) fraction of effluent dissolved organic matter ( DOMef) in mid⁃ditch recirculation mode accounted for 35.7%, compared to the proportions of 59. 2%, 45. 3% and 39. 4% for the other modes. The ultraviolet absorbance to dissolved organic carbon ratio test revealed that effluent under mid⁃ditch recirculation mode contained more non⁃aromatic hydrophilic components. Furthermore, appropriate recirculation and anoxic/oxic ( A/O) partitions were also demonstrated to remove some refractory metabolites ( phenols, alkanes, aniline, etc.), which reduced the chromaticity and improved the biodegradability.

  8. Influence of phenol on ammonia removal in an intermittent aeration bioreactor treating biologically pretreated coal gasification wastewater.

    Science.gov (United States)

    Xu, Chunyan; Han, Hongjun; Jia, Shengyong; Zhao, Qian

    2016-05-01

    A laboratory-scale intermittent aeration bioreactor was investigated to treat biologically pretreated coal gasification wastewater that was mainly composed of NH3-N and phenol. The results showed that increasing phenol loading had an adverse effect on NH3-N removal; the concentration in effluent at phenol loading of 40mgphenol/(L·day) was 7.3mg/L, 36.3% of that at 200mg phenol/(L·day). The enzyme ammonia monooxygenase showed more sensitivity than hydroxylamine oxidoreductase to the inhibitory effect of phenol, with 32.2% and 10.5% activity inhibition, respectively at 200mg phenol/(L·day). Owing to intermittent aeration conditions, nitritation-type nitrification and simultaneous nitrification and denitrification (SND) were observed, giving a maximum SND efficiency of 30.5%. Additionally, ammonia oxidizing bacteria (AOB) and denitrifying bacteria were the main group identified by fluorescent in situ hybridization. However, their relative abundance represented opposite variations as phenol loading increased, ranging from 30.1% to 17.5% and 7.6% to 18.2% for AOB and denitrifying bacteria, respectively.

  9. 微波辅助加热粉煤灰水热合成沸石的最佳条件%The Better Condition for Hydrothermal Synthesizing Zeolite from Coal Fly Ash under the Microwave

    Institute of Scientific and Technical Information of China (English)

    崔红梅; 柯灵非; 李芳; 齐晗兵; 康媞

    2012-01-01

    The zeolite was synthesized by hydrothermal method under the microwave using the coal fly ash as the material. The synthesis effect of zeolite was detected with cation exchange capacity. The synthesis technologies of zeolite under the microwave were compared with conventional synthesis under the same conditions. The impact factor and the best condition of this method was discussed. The main factor which influences the category of synthesized zeolite and rate were chemical compositions of coal fly ash, temperature, time, activator, concentration of alkali, ratio of solution and solid, microwave, etc. The best conditions were 120 ℃ ,40 min,2 mol/L NaOH,ratio of solution and solid 2.5.%以火力发电厂粉煤灰为原料,微波辅助加热水热合成沸石,并用阳离子交换容量(CEC)检测粉煤灰沸石合成效果.将微波辅助加热合成与同等条件下的常规水热合成进行比较,探讨微波辅助合成沸石中的影响因素及最佳条件.微波条件下影响粉煤灰合成沸石的种类及合成效果的主要因素有:粉煤灰的组分、温度、时间、活化剂种类、碱浓度、液固比、微波催化等;微波合成最佳条件为:120℃、40 min、NaOH浓度2 mol/L、液固比2.5.

  10. Geochemistry of vanadium (V) in Chinese coals.

    Science.gov (United States)

    Liu, Yuan; Liu, Guijian; Qu, Qinyuan; Qi, Cuicui; Sun, Ruoyu; Liu, Houqi

    2016-10-11

    Vanadium in coals may have potential environmental and economic impacts. However, comprehensive knowledge of the geochemistry of V in coals is lacking. In this study, abundances, distribution and modes of occurrence of V are reviewed by compiling >2900 reported Chinese coal samples. With coal reserves in individual provinces as the weighting factors, V in Chinese coals is estimated to have an average abundance of 35.81 μg/g. Large variation of V concentration is observed in Chinese coals of different regions, coal-forming periods, and maturation ranks. According to the concentration coefficient of V in coals from individual provinces, three regions are divided across Chinese coal deposits. Vanadium in Chinese coals is probably influenced by sediment source and sedimentary environment, supplemented by late-stage hydrothermal fluids. Specifically, hydrothermal fluids have relatively more significant effect on the enrichment of V in local coal seams. Vanadium in coals is commonly associated with aluminosilicate minerals and organic matter, and the modes of V occurrence in coal depend on coal-forming environment and coal rank. The Chinese V emission inventory during coal combustion is estimated to be 4906 mt in 2014, accounting for 50.55 % of global emission. Vanadium emissions by electric power plants are the largest contributor.

  11. Removal of mineral matter from some Australian coals by Ca(OH){sub 2}/HCl leaching

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J.; Tomita, A. [Tohoku University, Sendai (Japan). Inst. for Chemical Reaction Science

    1998-12-01

    Four Australian coals, Blair Athol, Ebenezer, Newlands and Warkworth coals, were demineralized by Ca(OH){sub 2} digestion at 300{degree}C, followed by washing with dilute HCl. Ash contents decreased from 8.8-15.4% to 1% for Blair Athol, Newlands and Warkworth coals, and from 14.9% to 2.8% for Ebenezer coal. The CaO/ash ratio is an important factor affecting coal demineralization; the maximum ash removals were achieved at CaO/ash ratios in the range 0.6-1 g/g for all the coals. The major minerals in the original coals were kaolinite and quartz, with some montmorillonite and carbonates. Kaolinite and quartz hydrothermally reacted with Ca(OH){sub 2} to form calcium-bearing hydrated silicates and aluminosilicates, such as tobermorite and hibschites, that could be dissolved in acid. With increasing CaO/ash ratio in excess of the optimum value, the removal of quartz significantly decreased; there also remains some calcium in treated coal, depending on digestion conditions and coal type. A lower ash removal from Ebenezer is due to a lower quartz removal and more remaining calcium. 16 refs., 8 figs., 4 tabs.

  12. 粉煤灰水热法合成沸石的研究进展%On the research advances in hydrothermal synthesis of zeolite from the coal fly ash

    Institute of Scientific and Technical Information of China (English)

    石德智; 张金露; 张超; 李鹏飞; 袁荣焕

    2016-01-01

    The given paper is devoted to making a review over the research advances on the successful ways to deal with the coal fly ash (CFA) as one of the main industrial solid wastes from the power-generating plants.In the paper,we have made a brief introduction to the reaction mechanism and the crystal formation steps through the hydrothermal synthesis of the zeolite from CFA,which depends on the formation of the aluminosilicate gel from the reaction system,for the aluminosilicate crystal can be formed during the following three periods:the induced period,the nucleation poriod and the crystal growth period step by step.In so doing,the zeolite can be made crystallized through a serf-catalytic process,with the crystals growing during the said process.Furthermore,we would like to recommend the respective advances in the different hydrothermal processing methods including the conventional hydrothermal synthesis (one-step method),the two-step method,the microwave-supporting method,the alkaline fusion method,the seedling-inducing method,the gradually heated method and the dialysis hydrothermal method,respectively,with the differences of each method being briefly analyzed.Then,the seedling methods can be chosen according to the types of the target products of zeolite types and the different crystal seeds as the seedling to be induced.It is just by taking all the aforementioned induced methods that it would be possible to reach high-degree idealistic crystallized zeolites of highly possible purity.On the other hand,the simple operation,the mild reaction conditions,the promptly effective reaction time and all the other favorable seedling factors,may all contribute to the advantages of the method.Therefore,as compared with the conventional hydrothermal synthesis the above said methods can help to gain more by-products but less lower purity zeolite,which makes them enjoy brighter prospects for future developments and more worthy popularization.It is just for better popularization

  13. Study of green quartz of hydrothermal origin treated by gamma radiation; Estudo do quartzo verde de origem hidrotermal tratado com radiacao gama

    Energy Technology Data Exchange (ETDEWEB)

    Enokihara, Cyro Teiti

    2013-07-01

    A specific variety of quartz showing a green color in nature or induced artificially by radiation is quite rare. This can be explained by the fact that the mechanism of formation of this color is very different from the ones widely discussed in the literature and responsible for the formation of the fumee, citrine and amethyst types of quartz, including the prasiolite (leak green quartz) formed by heating amethyst from Montezuma, Brazil. Only two occurrences are known today, where this type of quartz can be found: Canada, at the Thunder Bay Amethyst Mine, Ontario, a small district, and Brazil, at widely scattered geode occurrences along a 600 km stretch from Quarai at Brazils southernmost tip to Uberlandia in Minas Gerais. These two occurrences have been formed by strong hydrothermal activities, at Thunder Bay due to tectonics and in Brazil by meteoric and hydrothermal waters of the Guarani aquifer. That way much quartz crystals showed a very fast growth history facilitating the formation of growth defects (twinning, small angle tilting, mosaic growth, striations) and the uptake of water in form of micro inclusions, molecular water, silanol (Si-OH) and OH. This type of quartz can be considered 'wet quartz', similar to synthetic quartz. The water content with up to 3200 ppm by weight exceeds the amount of charge balancing cations (Fe, Al, Li). There is no correlation between water content and cations as in other color varieties. Instead, silanol complexes are formed, which by radiation due to gamma rays form the color center NBOHC (non-bonding oxygen hole defect), showing absorption between 590 to 620 nm and leaving a transmission window at about 550nm, responsible for the green color. To characterize samples which will be colored green by gamma rays analyses by ICP, NAA, Electron microscopy, water loss techniques and UV-VIS and NIR-FTIR spectroscopic have been made. The spectroscopic water determination showed less water (up to 2300 ppm by weight

  14. Unique nature of the coal mining industry-are the labor law rules determining when two employers should be treated as one different for the coal industry?

    Energy Technology Data Exchange (ETDEWEB)

    Roles, F.J. [Smith, Heenan, & Althen, Charleston, WV (United States)

    1995-11-01

    Modern United States labor law dates from the 1935 enactment of the Wagner Act. Its definition of {open_quotes}employer{close_quotes} has remained the same over the the nearly sixty years of its application. The Courts and the Board have developed detailed criteria deciding when two or more employers should be considered one under that definition. Since the 1984 decision in B.F.I., those criteria have been uniformly accepted and applied. There is nothing unique about the coal industry warranting a change or a different application of the criteria.

  15. Hydrothermal synthesis of hydroxyapatite

    Science.gov (United States)

    Earl, J. S.; Wood, D. J.; Milne, S. J.

    2006-02-01

    A hydrothermal method of synthesizing hydroxyapatite by heating a precipitate, formed by mixing Ca(NO3)2bold dot4H2O and (NH4)2HPO4 with distilled water, in a hydrothermal reactor at 200 °C for 24-72 hrs is described. A treatment time of 24 hrs produced single phase (as shown by XRD) hydroxyapatite powder, however for longer treatment times XRD patterns were indicative of the presence of a secondary phase, monetite (CaHPO4). SEM examination of the treated powders displayed particles of rod-like morphology with dimensions 100-500 nm in length and 10-60 nm in diameter. Preliminary results on the use of the particles for the infiltration of dentine tubules are presented.

  16. Hydrothermal synthesis of hydroxyapatite

    Energy Technology Data Exchange (ETDEWEB)

    Earl, J S; Wood, D J; Milne, S J [Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (United Kingdom)

    2006-02-22

    A hydrothermal method of synthesizing hydroxyapatite by heating a precipitate, formed by mixing Ca(NO{sub 3}){sub 2}{center_dot}4H{sub 2}O and (NH{sub 4}){sub 2}HPO{sub 4} with distilled water, in a hydrothermal reactor at 200 deg. C for 24-72 hrs is described. A treatment time of 24 hrs produced single phase (as shown by XRD) hydroxyapatite powder, however for longer treatment times XRD patterns were indicative of the presence of a secondary phase, monetite (CaHPO{sub 4}). SEM examination of the treated powders displayed particles of rod-like morphology with dimensions 100-500 nm in length and 10-60 nm in diameter. Preliminary results on the use of the particles for the infiltration of dentine tubules are presented.

  17. Hydrothermal minerals

    Digital Repository Service at National Institute of Oceanography (India)

    Nath, B.N.

    -floor hydrothermal processes involving free circulation of seawater through ocean crust as convection. Heat flow, seafloor fracturing, permeability and fluid composition are the parameters governing the type and extent of mineralization. The chimney like... stream_size 23365 stream_content_type text/plain stream_name Refresher_Course_Mar_Geol_Geophys_2007_Lecture_Notes_78.pdf.txt stream_source_info Refresher_Course_Mar_Geol_Geophys_2007_Lecture_Notes_78.pdf.txt Content-Encoding UTF-8...

  18. 高铝粉煤灰中Al2O3与SiO2在碱溶液中的反应行为%Reaction behaviour of Al2O3 and SiO2 in high alumina coal fly ash during alkali hydrothermal process

    Institute of Scientific and Technical Information of China (English)

    蒋周青; 杨静; 马鸿文; 王乐; 马玺

    2015-01-01

    The reaction behaviours of Al2O3 and SiO2 in high alumina coal fly ash under various alkali hydrothermal conditions were studied. The means of XRD, XRF, FTIR and SEM were used to measure the mineral phase and morphology of the solid samples obtained by different alkali hydrothermal treatments as well as the leaching ratio of SiO2 to Al2O3 in alkali solution. The results showed that with the increase of the hydrothermal treating temperature from 75 to 160 °C, phillipsite-Na, zeolite A, zeolite P, and hydroxysodalite were produced sequentially while the mullite and corundum phase still remained. Zeolite P was massively formed at low-alkali concentration and the hydroxysodalite was predominantly obtained at high-alkali concentration. By the dissolution of aluminosilicate glass and the formation of zeolites together, the leaching efficiency of SiO2 can reach 42.13% with the mass ratio of Al2O3/SiO2 up to 2.19:1.%研究高铝粉煤灰中Al2O3与SiO2组分在NaOH碱液中不同水热条件下的反应行为。采用XRD、XRF、SEM、FTIR等测试方法对高铝粉煤灰碱溶液处理前后的物相组成和形貌变化进行表征,得到粉煤灰Al2O3和SiO2组分的溶出率变化规律。结果表明,高铝粉煤灰经75°C到160°C不同温度碱溶液处理后,颗粒表面硅铝玻璃相消失,依次生成钠型沸石、A型沸石、P型沸石及羟基方钠石,所含刚玉及莫来石相未被完全溶解。在低碱浓度溶液中P型沸石为主要生成相,高碱浓度下羟基方钠石为稳定的相。在铝硅玻璃体溶解和沸石相生成两种反应的共同作用下,粉煤灰中SiO2的溶出率可达42.13%,滤渣中Al2O3/SiO2质量比提高到2.19:1.

  19. Converting ultrasonic induction heating deposited monetite coating to Na-doped HA coating on H 2O 2-treated C/C composites by a two-step hydrothermal method

    Science.gov (United States)

    Xin-bo, Xiong; Jian-feng, Hung; Xie-rong, Zeng; Cen-cen, Chu

    2011-10-01

    a monetite coating on H 2O 2-treated C/C composites was prepared by ultrasonic induction heating (UIH) technology. Subsequently, this coating was subjected to an ammonia hydrothermal treatment to form a undoped hydroxyapatite (U-HA) coating. Finally, the as-prepared U-HA coating was placed in a NaOH solution and hydrothermally treated to produce the other hydroxyapatite (Na-HA) coating. The structure, morphology and chemical composition of the two HA coatings were characterized by XRD, FTIR, SEM and EDS, the adhesiveness and local mechanical properties, e.g. nanohardness and Young's modulus of the two HA coatings to C/C composites was evaluated by a scratch test and nanoindentation technique respectively. The results showed that the two HA coatings had the alike morphology and crystallization. But, compared with the U-HA coating, the Na-HA coating was doped with Na ions, and gave a Ca/P ratio close to a stoichiometric hydroxyapatite, and thus showed a higher nano-indentation value, Young's modulus, and larger bonding strength. These results verified the strengthened effect of Na ion in hydroxyapatite coating on carbon/carbon (C/C) composities.

  20. Characteristics of Telemagmatic Metamorphism of the Ceshui Formation Coal in Lianyuan Coal Basin

    Institute of Scientific and Technical Information of China (English)

    毕华; 彭格林

    1998-01-01

    The Ceshui Formation coal is mostly anthracite and its metamorphism has been less documented.By analyzing systematically the reflectance of vitrinite and the results of X-ray diffraction of the Ceshui Formation cola in the Lianyuan coal basin,the spatial variation characteristics of coal ranks,coal metamorphic regions,the extension of coal metamorphic belts.coal metamorphic gradients,coal chemical structure and the effect on the degree of metamorphism of heat-production and -storge conditions,buried depth of the Indosinian-Yenshanian granites at the margins of the Lianyuan coal basin are discussed.The research results in conjunction of the features of regional hydrothermal alterations,endogenetic deposits with the Ceshui Formation coal measures,and the development of secondary vesicles indicate that the telemagmatic metamorphism is the main factor leading to the metamorphism of the Ceshui Formation coal in the region studied.

  1. Photosynthetic pigment concentrations, gas exchange and vegetative growth for selected monocots and dicots treated with two contrasting coal fly ashes

    Energy Technology Data Exchange (ETDEWEB)

    Yunusa, I.A.M.; Burchett, M.D.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Skilbeck, C.G. [University of Technology Sydney, Sydney, NSW (Australia). Dept. of Environmental Science

    2009-07-15

    There is uncertainty as to the rates of coal fly ash needed for optimum physiological processes and growth. In the current study we tested the hyothesis that photosynthetic pigments concentrations and CO{sub 2} assimilation (A) are more sensitive than dry weights in plants grown on media amended with coal fly ash. We applied the Terrestrial Plant Growth Test (Guideline 208) protocols of the Organization for Economic Cooperation and Development (OECD) to monocots (barley (Hordeum vulgare) and ryegrass (Secale cereale)) and dicots (canola (Brasica napus), radish (Raphanus sativus), field peas (Pisum sativum), and lucerne (Medicago sativa)) on media amended with fly ashes derived from semi-bituminous (gray ash) or lignite (red ash) coals at rates of 0, 2.5, 5.0, 10, or 20 Mg ha(-1). The red ash had higher elemental concentrations and salinity than the gray ash. Fly ash addition had no significant effect on germination by any of the six species. At moderate rates ({<=}10 Mg ha{sup -1}) both ashes increased (P < 0.05) growth rates and concentrations of chlorophylls a and b, but reduced carotenoid concentrations. Addition of either ash increased A in radish and transpiration in barley. Growth rates and final dry weights were reduced for all of the six test species when addition rates exceeded 10 Mg ha{sup -1} for gray ash and 5 Mg ha{sup -1} for red ash. We concluded that plant dry weights, rather than pigment concentrations and/or instantaneous rates of photosynthesis, are more consistent for assessing subsequent growth in plants supplied with fly ash.

  2. Coal; Le charbon

    Energy Technology Data Exchange (ETDEWEB)

    Teissie, J.; Bourgogne, D. de; Bautin, F. [TotalFinaElf, La Defense, 92 - Courbevoie (France)

    2001-12-15

    Coal world production represents 3.5 billions of tons, plus 900 millions of tons of lignite. 50% of coal is used for power generation, 16% by steel making industry, 5% by cement plants, and 29% for space heating and by other industries like carbo-chemistry. Coal reserves are enormous, about 1000 billions of tons (i.e. 250 years of consumption with the present day rate) but their exploitation will be in competition with less costly and less polluting energy sources. This documents treats of all aspects of coal: origin, composition, calorific value, classification, resources, reserves, production, international trade, sectoral consumption, cost, retail price, safety aspects of coal mining, environmental impacts (solid and gaseous effluents), different technologies of coal-fired power plants and their relative efficiency, alternative solutions for the recovery of coal energy (fuel cells, liquefaction). (J.S.)

  3. Radiocesium Adsorption By Zeolitic Materials Synthesized From Coal Fly Ash

    Directory of Open Access Journals (Sweden)

    Remenárová Lucia

    2014-06-01

    Full Text Available Brown coal fly ash derived from the combustion of brown-coal in power plant ENO Nováky (Slovak Republic was used as raw material for synthesis of zeolitic materials ZM1 and ZM3 by hydrothermal alternation with 1M NaOH and 3M NaOH, respectively. Fly ash and synthesized products were characterized using XRF and SEM-EDX analysis. Subsequently, zeolitic materials were tested as sorbents to remove Cs+ ions from aqueous solutions using radiotracer technique. Sorption of cesium by both types of zeolitic materials obeys Langmuir adsorption isotherm model. The maximum sorption capacities Qmax at pH 6.0 calculated from Langmuir isotherm were 1203 ± 65 μmol Cs+/ g for ZM1 and 1341 ± 66 μmol Cs+/ g for ZM3. The results showed that alkali treated fly ash can be used as effective sorbent for radiocesium removal from contaminated solutions

  4. Cation exchange for mercury and cadmium of xanthated, sulfonated, activated and non-treated subbituminous coal, commercial activated carbon and commercial synthetic resin:effect of pre-oxidation on xanthation of subbituminous coal

    Institute of Scientific and Technical Information of China (English)

    Lewis M. Gomez; Fredy Colpas-Castillo; Roberto Fernandez-Maestre

    2014-01-01

    A subbituminous coal was oxidized with air at 150 ?C on a fixed bed for 4 h and xanthated with carbon disulfide in a basic solution, at 30 or 5–10 ?C. This xanthated coal was evaluated for the removal of Hg2? and Cd2? from 7,000 mg/L aqueous solutions; metal concentrations were determined by atomic absorption spectrometry. The ion exchange of the xanthated coal was compared against those of the original subbituminous coal, a sulfonated subbituminous coal, activated carbon, commercial activated carbon, and commercial synthetic resin. The commercial synthetic resin showed the highest exchange capacity (concentration factor 98%) followed by the xanthated coal (concentration factor 96%). The retention of cadmium on the sulfonated subbituminous coal was lower (exchange capacity 0.56 meq/g) than that of xanthated coals (1.85 ± 0.09 meq/g). Our xanthated coal showed a better Cd2? removal (81%against 15%) than a non preoxidized 40-h-xanthated coal, which shows that oxidation of coal increased the amount of oxygenated groups which enhanced xanthation.

  5. Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction. Final technical report, Volume 2 - hydrogenative and hydrothermal pretreatments and spectroscopic characterization using pyrolysis-GC-MS, CPMAS {sup 13}C NMR and FT-IR

    Energy Technology Data Exchange (ETDEWEB)

    Chunshan Song; Hatcher, P.G.; Saini, A.K.; Wenzel, K.A.

    1998-01-01

    It has been indicated by DOE COLIRN panel that low-temperature catalytic pretreatment is a promising approach to the development of an improved liquefaction process. This work is a fundamental study on effects of pretreatments on coal structure and reactivity in liquefaction. The main objectives of this project are to study the coal structural changes induced by low-temperature catalytic and thermal pretreatments by using spectroscopic techniques; and to clarify the pretreatment-induced changes in reactivity or convertibility of coals. As the second volume of the final report, here we summarize our work on spectroscopic characterization of four raw coals including two subbituminous coals and two bituminous coals, tetrahydrofuran (THF)-extracted but unreacted coals, the coals (THF-insoluble parts) that have been thermally pretreated. in the absence of any solvents and in the presence of either a hydrogen-donor solvent or a non-donor solvent, and the coals (THF-insoluble parts) that have been catalytically pretreated in the presence of a dispersed Mo sulfide catalyst in the absence of any solvents and in the presence of either a hydrogen-donor solvent or a non-donor solvent.

  6. Hydrothermal Biogeochemistry

    Science.gov (United States)

    Shock, E.; Havig, J.; Windman, T.; Meyer-Dombard, D.; Michaud, A.; Hartnett, H.

    2006-12-01

    Life in hot spring ecosystems is confronted with diverse challenges, and the responses to those challenges have dynamic biogeochemical consequences over narrow spatial and temporal scales. Within meters along hot spring outflow channels at Yellowstone, temperatures drop from boiling, and the near-boiling conditions of hot chemolithotrophic communities, to those that permit photosynthesis and on down to conditions where nematodes and insects graze on the edges of photosynthetic mats. Many major and trace element concentrations change only mildly in the water that flows through the entire ecosystem, while concentrations of other dissolved constituents (oxygen, sulfide, ammonia, total organic carbon) increase or decrease dramatically. Concentrations of metals and micronutrients range from toxic to inadequate for enzyme synthesis depending on the choice of hot spring. Precipitation of minerals may provide continuous growth of microbial niches, while dissolution and turbulent flow sweeps them away. Consequently, microbial communities change at the meter scale, and even more abruptly at the photosynthetic fringe. Isotopic compositions of carbon and nitrogen in microbial biomass reflect dramatic and continuous changes in metabolic strategies throughout the system. Chemical energy sources that support chemolithotrophic communities can persist at abundant or useless levels, or change dramatically owing to microbial activity. The rate of temporal change depends on the selection of hot spring systems for study. Some have changed little since our studies began in 1999. Others have shifted by two or more units in pH over several years, with corresponding changes in other chemical constituents. Some go through daily or seasonal desiccation cycles, and still others exhibit pulses of changing temperature (up to 40°C) within minutes. Taken together, hydrothermal ecosystems provide highly manageable opportunities for testing how biogeochemical processes respond to the scale of

  7. Relationship between the fluidity of heat-treated coals and molecular weight distributions of their solvent-soluble component; Netsushoritan no yobai kayo seibun no bunshiryo bunpu to ryudosei no kanren

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, T.; Takanohashi, T.; Iino, M. [Tohoku University, Sendai (Japan). Institute for Chemical Reaction Science; Kato, K. [Nippon Steel Co. Ltd., Tokyo (Japan); Fukada, K. [NKK Corp., Tokyo (Japan)

    1996-10-28

    In order to improve the coke manufacturing process, considerations were given on fluidity manifestation mechanism of heat-treated coals from molecular weight distributions of extracts of a solvent mixed with CS2-N-methyl-2-pyrrolidinone (CS2-NMP). The heat treatment was performed in an autoclave under nitrogen atmosphere at a rate of 3{degree}C/min to settings of 200 to 550{degree}C. The resultant heat-treated coal was quenched, and then extracted by using the CS2-NMP mixed solvent. The fluidity was measured by using a Gieseler plastometer. Maximum extraction rate and the highest fluidity are in linear relationship, which suggests that the extracts govern the fluidity. Since heavy caking coal has no difference in the extraction rates due to heat treatment temperature, and its molecular weight distribution trend does not change, the extracted components which have existed primarily in the original coal govern the fluidity. In semi-caking coals, polymer molecular components are extracted in a large quantity at the softening starting temperature, but the quantity decreases as the temperature rises. However, low-molecular components present no quantitative change, while polymer molecular components decompose, decrease in molecular weight, get solubilized with rising temperature, and act as a binder to cause a flow. 7 figs., 1 tab.

  8. Reuse of Treated Internal or External Wastewaters in the Cooling Systems of Coal-Based Thermoelectric Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Radisav Vidic; David Dzombak; Ming-Kai Hsieh; Heng Li; Shih-Hsiang Chien; Yinghua Feng; Indranil Chowdhury; Jason Monnell

    2009-06-30

    This study evaluated the feasibility of using three impaired waters - secondary treated municipal wastewater, passively treated abandoned mine drainage (AMD), and effluent from ash sedimentation ponds at power plants - for use as makeup water in recirculating cooling water systems at thermoelectric power plants. The evaluation included assessment of water availability based on proximity and relevant regulations as well as feasibility of managing cooling water quality with traditional chemical management schemes. Options for chemical treatment to prevent corrosion, scaling, and biofouling were identified through review of current practices, and were tested at bench and pilot-scale. Secondary treated wastewater is the most widely available impaired water that can serve as a reliable source of cooling water makeup. There are no federal regulations specifically related to impaired water reuse but a number of states have introduced regulations with primary focus on water aerosol 'drift' emitted from cooling towers, which has the potential to contain elevated concentrations of chemicals and microorganisms and may pose health risk to the public. It was determined that corrosion, scaling, and biofouling can be controlled adequately in cooling systems using secondary treated municipal wastewater at 4-6 cycles of concentration. The high concentration of dissolved solids in treated AMD rendered difficulties in scaling inhibition and requires more comprehensive pretreatment and scaling controls. Addition of appropriate chemicals can adequately control corrosion, scaling and biological growth in ash transport water, which typically has the best water quality among the three waters evaluated in this study. The high TDS in the blowdown from pilot-scale testing units with both passively treated mine drainage and secondary treated municipal wastewater and the high sulfate concentration in the mine drainage blowdown water were identified as the main challenges for blowdown

  9. Chemical, structural and combustion characteristics of carbonaceous products obtained by hydrothermal carbonization of palm empty fruit bunches.

    Science.gov (United States)

    Parshetti, Ganesh K; Kent Hoekman, S; Balasubramanian, Rajasekhar

    2013-05-01

    A carbon-rich solid product, denoted as hydrochar, was synthesized by hydrothermal carbonization (HTC) of palm oil empty fruit bunch (EFB), at different pre-treatment temperatures of 150, 250 and 350 °C. The conversion of the raw biomass to its hydrochar occurred via dehydration and decarboxylation processes. The hydrochar produced at 350 °C had the maximum energy-density (>27 MJ kg(-1)) with 68.52% of raw EFB energy retained in the char. To gain a detailed insight into the chemical and structural properties, carbonaceous hydrochar materials were characterized by FE-SEM, FT-IR, XRD and Brunauer-Emmett-Teller (BET) analyses. This work also investigated the influence of hydrothermally treated hydrochars on the co-combustion characteristics of low rank Indonesian coal. Conventional thermal gravimetric analysis (TGA) parameters, kinetics and activation energy of different hydrochar and coal blends were estimated. Our results show that solid hydrochars improve the combustion of low rank coals for energy generation.

  10. Effect of pure oxygen fine bubbles on the organic matter removal and bacterial community evolution treating coal gasification wastewater by membrane bioreactor.

    Science.gov (United States)

    Zhuang, Haifeng; Hong, Xiaoting; Han, Hongjun; Shan, Shengdao

    2016-12-01

    A lab-scale study was investigated to evaluate the effect of pure oxygen fine bubbles on membrane bioreactor (O2-MBR) performance of treating coal gasification wastewater. Compared with conventional MBR using aeration source of air (CMBR), the removal efficiencies of COD and total phenols increased by 28% and 36%, and the organic compositions of treated effluent represented significant difference that was mainly attributed to the controlled the foam expansion and enhanced the enzymatic activities in O2-MBR. Moreover, membrane fouling mitigation was observed in O2-MBR, probably owing to the less EPS amount and larger PSD. It was notable that the pure oxygen with fine bubbles promoted marked evolution of bacterial community from CMBR to O2-MBR, particularly, the bacterial community richness and diversity in O2-MBR was lower than CMBR, and the genera Phycisphaera, Comamonas, Thauera and Ohtaekwangia composed the top four most relative abundance genera in O2-MBR, giving the total relative abundance of 26.7%.

  11. Effects of process parameters on hydrothermal carbonization

    Science.gov (United States)

    Uddin, Md. Helal

    In recent years there has been increased research activity in renewable energy, especially upgrading widely available lignicellulosic biomass, in a bid to counter the increasing environmental concerns related with the use of fossil fuels. Hydrothermal carbonization (HTC), also known as wet torrefaction or hot water pretreatment, is a process for pretreatment of diverse lignocellulosic biomass feedstocks, where biomass is treated under subcritical water conditions in short contact time to produce high-value products. The products of this process are: a solid mass characterized as biochar/biocoal/biocarbon, which is homogeneous, energy dense, and hydrophobic; a liquid stream composed of five and six carbon sugars, various organic acids, and 5-HMF; and a gaseous stream, mainly CO2. A number of process parameters are considered important for the extensive application of the HTC process. Primarily, reaction temperature determines the characteristics of the products. In the solid product, the oxygen carbon ratio decreases with increasing reaction temperature and as a result, HTC biochar has the similar characteristics to low rank coal. However, liquid and gaseous stream compositions are largely correlated with the residence time. Biomass particle size can also limit the reaction kinetics due to the mass transfer effect. Recycling of process water can help to minimize the utility consumption and reduce the waste treatment cost as a result of less environmental impact. Loblolly pine was treated in hot compressed water at 200 °C, 230 °C, and 260 °C with 5:1 water:biomass mass ratio to investigate the effects of process parameters on HTC. The solid product were characterized by their mass yields, higher heating values (HHV), and equilibrium moisture content (EMC), while the liquid were characterized by their total organic carbon content and pH value.

  12. Evaluation of adsorbents for treating stable oil/water/mineral emulsions produced during in-situ bitumen/heavy oil recovery operations. Phase 2. Final report. [Fly ash, red mud and Minuto coal

    Energy Technology Data Exchange (ETDEWEB)

    1985-03-29

    The objective was to make a preliminary assessment of the technical and economic feasibility of treating emulsions from in-situ bitumen/heavy oil recovery operations for recovery of the oil and preparation of suitable water for boiler feed utilizing adsorbents developed within the Separation and Characterization laboratory of Energy Mines and Resources Canada. This project was completed in two phases. In the first phase, a report was prepared which focussed on the characterization of the adsorption behaviour of the novel adsorbents, determination of an appropriate mode of operation and of the approximate cost for producing water for boiler feed. Three adsorbents (fly ash, red mud, Minto coal) were evaluated with respect to their potential for the treatment produced water. Fly ash and Minto coal were determined to have the best potential based on isotherms for total suspended oil (TSO) removal at two pH levels. The most appropriate mode of operation for these two adsorbents was slurry contact followed by precipitation clarification. During the second phase, work was focussed on the development and characterization of the slurry contact and clarification process for the treatment of produced water utilizing the novel adsorbents Minto coal and fly ash and the development of methods that could be used for the recovery of the adsorbed oil and regeneration of the spent adsorbents. The mechanism of oil removal by Minto coal was determined to be emulsion destabilization and precipitation caused by a coagulation type reaction with iron released from the coal, rather than an adsorbtion of oil on organics on the coal surface as originally believed. This study has shown that virgin Minto coal can effectively destabilize wellhead emulsions and that the oil can be separated from the destabilized emulsion by either precipitation or filtration. 3 figs., 15 tabs.

  13. Hydrothermal organic synthesis experiments

    Science.gov (United States)

    Shock, Everett L.

    1992-01-01

    Ways in which heat is useful in organic synthesis experiments are described, and experiments on the hydrothermal destruction and synthesis of organic compounds are discussed. It is pointed out that, if heat can overcome kinetic barriers to the formation of metastable states from reduced or oxidized starting materials, abiotic synthesis under hydrothermal conditions is a distinct possibility. However, carefully controlled experiments which replicate the descriptive variables of natural hydrothermal systems have not yet been conducted with the aim of testing the hypothesis of hydrothermal organic systems.

  14. Hydrothermal pretreatment of palm oil empty fruit bunch

    Science.gov (United States)

    Simanungkalit, Sabar Pangihutan; Mansur, Dieni; Nurhakim, Boby; Agustin, Astrid; Rinaldi, Nino; Muryanto, Fitriady, Muhammad Ariffudin

    2017-01-01

    Hydrothermal pretreatment methods in 2nd generation bioethanol production more profitable to be developed, since the conventional pretreatment, by using acids or alkalis, is associated with the serious economic and environmental constraints. The current studies investigate hydrothermal pretreatment of palm oil empty fruit bunch (EFB) in a batch tube reactor system with temperature and time range from 160 to 240 C and 15 to 30 min, respectively. The EFB were grinded and separated into 3 different particles sizes i.e. 10 mesh, 18 mesh and 40 mesh, prior to hydrothermal pretreatment. Solid yield and pH of the treated EFB slurries changed over treatment severities. The chemical composition of EFB was greatly affected by the hydrothermal pretreatment especially hemicellulose which decreased at higher severity factor as determined by HPLC. Both partial removal of hemicellulose and migration of lignin during hydrothermal pretreatment caused negatively affect for enzymatic hydrolysis. This studies provided important factors for maximizing hydrothermal pretreatment of EFB.

  15. Key technology for treating slack coal blockage in CBM recovery: A case study from multi-lateral horizontal wells in the Qinshui Basin

    Directory of Open Access Journals (Sweden)

    Yong Yang

    2016-01-01

    Full Text Available Due to the nature of coal bed, slack coal production is inevitable in gas recovery sby water drainage. When coalbed methane (CBM wells are reentered after low energy exploitation and shut-in, the negative effect of slack coal production on productivity of CBM is irreversible. In this paper, the CBM occurrence characteristics and multi-lateral horizontal well trajectory in the Qinshui Basin, Shanxi Province, were analyzed. In the multi-lateral horizontal wells, the expected gas production rate could not be reached and the production rate after shut-in maintenance could not restore to the level before shut-in. The reason for these issues is that migration pathways in the reservoirs are blocked by slack coal deposits, while formation water and slack coal deposit accumulated at the troughs of horizontal sections enlarge the resistance for gas to flow into the bottom hole. Furthermore, three key technologies to deal with slack coal blockage were proposed. Firstly, CBM horizontal well trajectory should follow the principle of keeping the wellbores smooth and updip instead of being “wavy”, on the premise of guaranteeing CBM drilling rate. Secondly, the cavities of production wells, as an important part of multi-lateral horizontal wells, are capable of settling sand, and can be used for gas–liquid–solid separation. And thirdly, a tree-like horizontal well with its main hole set on stable seam top or floor, provides a stable well flushing passage for coal powder. This research provides a useful attempt in solving the problem of slack coal production in gas recovery by water drainage.

  16. Slurry sampling of sediments and coals for the determination of Sn by HG-GF AAS with retention in the graphite tube treated with Th or W as permanent modifiers

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, Mariana Antunes; Ribeiro, Anderson Schwingel; Curtius, Adilson Jose [Departamento de Quimica da Universidade Federal de Santa Catarina, Florianopolis, SC (Brazil)

    2004-10-01

    A method for the determination of Sn in slurry samples of sediment and coal by hydride generation graphite furnace electrothermal atomic absorption spectrometry (HG-GF AAS) is proposed. The slurries were prepared by mixing the ground sample (particle size {<=}50 {mu}m) with 2.0 mol L{sup -1} HCl for the sediment samples or with 2.0 mol L{sup -1} HCl+1.0% v/v HF in a saturated boric acid medium for the coal samples. The slurry was placed in an ultrasonic bath for 30 min, before and after standing for 24 h, with occasional manual stirring. The graphite tube was treated with 0.5 mg of Th or W as a permanent modifier. Sn determination was carried out by electrothermal atomic absorption spectrometry at the optimized retention temperatures of 450 and 300 C for Th and W treatment, respectively. With this coupling, kinetic interference in the formation of the hydrides is avoided, and excellent detection limits can be obtained by using peak height. For the chemical vapor generation device, an optimized volume of 2 mL of sample slurry and an optimized NaBH{sub 4} concentration of 5% m/v were employed. The vapor produced was transported and retained on the graphite tube surface, which was further heated for Sn atomization. The accuracy of the method was verified by analyzing five certified sediments and three coals. By using the external calibration against aqueous standard solutions, the results obtained were in agreement with the certified values only for the sediment samples. For the coal samples, an addition calibration curve, obtained for one certified coal, was necessary to achieve accurate results. The obtained limits of detection were 0.03 {mu}g g{sup -1} for sediment and 0.09 {mu}g g{sup -1} for coal with Th as permanent modifier. The relative standard deviations were lower than 15%, demonstrating an adequate precision for slurry analysis. Sediment and coal samples from Santa Catarina, Brazil, were also analyzed. (orig.)

  17. Tuning photoluminescence of organic rubrene nanoparticles through a hydrothermal process

    Directory of Open Access Journals (Sweden)

    Jung Hyunjung

    2011-01-01

    Full Text Available Abstract Light-emitting 5,6,11,12-tetraphenylnaphthacene (rubrene nanoparticles (NPs prepared by a reprecipitation method were treated hydrothermally. The diameters of hydrothermally treated rubrene NPs were changed from 100 nm to 2 μm, depending on hydrothermal temperature. Photoluminescence (PL characteristics of rubrene NPs varied with hydrothermal temperatures. Luminescence of pristine rubrene NPs was yellow-orange, and it changed to blue as the hydrothermal temperature increased to 180°C. The light-emitting color distribution of the NPs was confirmed using confocal laser spectrum microscope. As the hydrothermal temperature increased from 110°C to 160°C, the blue light emission at 464 to approximately 516 nm from filtered-down NPs was enhanced by H-type aggregation. Filtered-up rubrene NPs treated at 170°C and 180°C exhibited blue luminescence due to the decrease of intermolecular excimer densities with the rapid increase in size. Variations in PL of hydrothermally treated rubrene NPs resulted from different size distributions of the NPs.

  18. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Rudolf, Andreas

    2011-01-01

    This article reviews the hydrothermal liquefaction of biomass with the aim of describing the current status of the technology. Hydrothermal liquefaction is a medium-temperature, high-pressure thermochemical process, which produces a liquid product, often called bio-oil or bi-crude. During...... the hydrothermal liquefaction process, the macromolecules of the biomass are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive and can recombine into larger ones. During this process, a substantial part of the oxygen in the biomass is removed...... by dehydration or decarboxylation. The chemical properties of bio-oil are highly dependent of the biomass substrate composition. Biomass constitutes of various components such as protein; carbohydrates, lignin and fat, and each of them produce distinct spectra of compounds during hydrothermal liquefaction...

  19. Mercury in coal. A review. Part 1

    Energy Technology Data Exchange (ETDEWEB)

    Yudovich, Ya. E.; Ketris, M.P. [Institute of Geology, Komi Scientific Center, Ural Division of the Russian Academy of Sciences, Morozova St., 100, ap. 49, 167023 Syktyvkar (Russian Federation)

    2005-05-11

    coal. Until the recent discovery of syngenetic volcanic Hg accumulations in Canadian coals, such Hg accumulations in coal were unknown. The most important type of Hg enrichment in coals is an epigenetic, low-temperature hydrothermal process; the Nikitovka (Ukraine), Warrior (USA), and Guizhou (China) basins are good examples. In the two latter coal basins, the paragenetic association Hg-As-Au-Tl is similar to Carlin-type Au deposits. The most notably Hg-rich basin is the Donbas-Donetsk coal basin situated in the Ukraine and Russia. Numerous coalfields in the Donbas are enriched in Hg by one order of magnitude above the coal Clarke level. The Hg in the Donbas was due to hydrothermal mineralization passing through sheared zones. The extraction and use of Hg-bearing Donbas coals have created very difficult environmental problems for the Ukrainian people.

  20. Coal washing scenario in India and future prospects

    Institute of Scientific and Technical Information of China (English)

    R.Venugopal; J.P.Patel; C.Bhar

    2016-01-01

    Coal Washing Exploration in India dates back to 1900s;though,first coking coal washeries in India were installed after independence.At present,most of the coking coal washeries are owned by Public Sector Companies;whereas,most of the non-coking coal washeries are owned by Private Sector.Even after six decades of coal washing practices,there has not been significant development in the coal washing intelligentsia.Indian Coal Washing industry is still dependent on imported equipment,which has been designed to treat coal that is significantly different from Indian coal of drift origin.In this paper,authors have ventured into evolution of Indian Coal Washing Industry (with a focus on coking coal washing sector),its present condition and future prospect for growth.The paper emphasizes need for developing indigenous solutions to industrial challenges and highlights importance of increased coordination among academia-research institutions and coal industry.

  1. Hydrothermal carbonization and torrefaction of grape pomace: a comparative evaluation.

    Science.gov (United States)

    Pala, Mehmet; Kantarli, Ismail Cem; Buyukisik, Hasan Baha; Yanik, Jale

    2014-06-01

    Grape pomace was treated by hydrothermal carbonization (sub-critical water, 175-275°C) and torrefaction (nitrogen atmosphere, 250 and 300°C), with mass yield of solid product (char) ranging between 47% and 78%, and energy densification ratio to 1.42-1.15 of the original feedstock. The chars were characterised with respect to their fuel properties, morphological and structural properties and combustion characteristics. The hydrothermal carbonization produced the char with greater energy density than torrefaction. The chars from torrefaction were found to be more aromatic in nature than that from hydrothermal carbonization. Hydrothermal carbonization process produced the char having high combustion reactivity. Most interesting was the finding that aqueous phase from hydrothermal carbonization had antioxidant activity. The results obtained in this study showed that HTC appears to be promising process for a winery waste having high moisture content.

  2. CERAMIC MEMBRANES FOR HYDROGEN PRODUCTION FROM COAL

    Energy Technology Data Exchange (ETDEWEB)

    George R. Gavalas

    2004-04-01

    The preparation and performance of membranes for application to hydrogen separation from coal-derived gas is described. The membrane material investigated was dense amorphous silica deposited on a suitable support by chemical vapor deposition (CVD). Two types of support materials were pursued. One type consisted of a two-layer composite, zeolite silicalite/{alpha}-Al{sub 2}O{sub 3}, in the form of tubes approximately 0.7 cm in diameter. The other type was porous glass tubes of diameter below 0.2 cm. The first type of support was prepared starting from {alpha}-Al{sub 2}O{sub 3} tubes of 1{micro}m mean pore diameter and growing by hydrothermal reaction a zeolite silicalite layer inside the pores of the alumina at the OD side. After calcination to remove the organic template used in the hydrothermal reaction, CVD was carried out to deposit the final silica layer. CVD was carried out by alternating exposure of the surface with silicon tetrachloride and water vapor. SEM and N2 adsorption measurements were employed to characterize the membranes at several stages during their preparation. Permeation measurements of several gases yielded H{sub 2}:N{sub 2} ideal selectivity of 150-200 at room temperature declining to 110 at 250 C. The second type of support pursued was porous glass tubes prepared by a novel extrusion technique. A thick suspension of borosilicate glass powder in a polyethersulfone solution was extruded through a spinneret and after gelation the glass-polymer tube was heat treated to obtain a gas-tight glass tube. Leaching of the glass tube in hot water yielded connected pores with diameter on the order of 100 nm. CVD of the final silica layer was not carried out on these tubes on account of their large pore size.

  3. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>20141574 Chen Hao(Exploration and Development Research Institute,Daqing Oilfield Company,Daqing 163712,China)High-Resolution Sequences and Coal Accumulating Laws in Nantun Formation of Huhe Lake Sag(Petroleum Geology&Oilfield Development in Daqing,ISSN1000-3754,CN23-1286/TQ,32(4),2013,p.15-19,5 illus.,15 refs.)Key words:coal accumulation regularity,coal

  4. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091159 Gao Yan(No.3 Prospecting Team of Anhui Bureau of Coal Geology,Suzhou 234000,China) Effect of Depositional Environment of Coal-Bearing Stratum on Major Coal Seams in Suntan Coalmine,Anhui Province(Geology of Anhui,ISSN 1005- 6157,CN34-1111/P,18(2),2008,p.114 -117,5 illus.,1 ref.,with English abstract)

  5. The Lassen hydrothermal system

    Science.gov (United States)

    Ingebritsen, Steven E.; Bergfeld, Deborah; Clor, Laura; Evans, William C.

    2016-01-01

    The active Lassen hydrothermal system includes a central vapor-dominated zone or zones beneath the Lassen highlands underlain by ~240 °C high-chloride waters that discharge at lower elevations. It is the best-exposed and largest hydrothermal system in the Cascade Range, discharging 41 ± 10 kg/s of steam (~115 MW) and 23 ± 2 kg/s of high-chloride waters (~27 MW). The Lassen system accounts for a full 1/3 of the total high-temperature hydrothermal heat discharge in the U.S. Cascades (140/400 MW). Hydrothermal heat discharge of ~140 MW can be supported by crystallization and cooling of silicic magma at a rate of ~2400 km3/Ma, and the ongoing rates of heat and magmatic CO2 discharge are broadly consistent with a petrologic model for basalt-driven magmatic evolution. The clustering of observed seismicity at ~4–5 km depth may define zones of thermal cracking where the hydrothermal system mines heat from near-plastic rock. If so, the combined areal extent of the primary heat-transfer zones is ~5 km2, the average conductive heat flux over that area is >25 W/m2, and the conductive-boundary length system or owe to various geologic events such as the eruption of Lassen Peak at 27 ka, deglaciation beginning ~18 ka, the eruptions of Chaos Crags at 1.1 ka, or the minor 1914–1917 eruption at the summit of Lassen Peak. However, there is a rich record of intermittent hydrothermal measurement over the past several decades and more-frequent measurement 2009–present. These data reveal sensitivity to climate and weather conditions, seasonal variability that owes to interaction with the shallow hydrologic system, and a transient 1.5- to twofold increase in high-chloride discharge in response to an earthquake swarm in mid-November 2014.

  6. Complexing and hydrothermal ore deposition

    CERN Document Server

    Helgeson, Harold C

    1964-01-01

    Complexing and Hydrothermal Ore Deposition provides a synthesis of fact, theory, and interpretative speculation on hydrothermal ore-forming solutions. This book summarizes information and theory of the internal chemistry of aqueous electrolyte solutions accumulated in previous years. The scope of the discussion is limited to those aspects of particular interest to the geologist working on the problem of hydrothermal ore genesis. Wherever feasible, fundamental principles are reviewed. Portions of this text are devoted to calculations of specific hydrothermal equilibriums in multicompone

  7. Hydrothermal conversion of biomass

    NARCIS (Netherlands)

    Knezevic, Dragan

    2009-01-01

    This thesis presents research of hydrothermal conversion of biomass (HTC). In this process, hot compressed water (subcritical water) is used as the reaction medium. Therefore this technique is suitable for conversion of wet biomass/ waste streams. By working at high pressures, the evaporation of wat

  8. Hydrothermal Reactivity of Amines

    Science.gov (United States)

    Robinson, K.; Shock, E.; Hartnett, H. E.; Williams, L. B.; Gould, I.

    2013-12-01

    The reactivity of aqueous amines depends on temperature, pH, and redox state [1], all of which are highly variable in hydrothermal systems. Temperature and pH affect the ratio of protonated to unprotonated amines (R-NH2 + H+ = R-NH3+), which act as nucleophiles and electrophiles, respectively. We hypothesize that this dual nature can explain the pH dependence of reaction rates, and predict that rates will approach a maximum at pH = pKa where the ratio of protonated and unprotonated amines approaches one and the two compounds are poised to react with one another. Higher temperatures in hydrothermal systems allow for more rapid reaction rates, readily reversible reactions, and unique carbon-nitrogen chemistry in which water acts as a reagent in addition to being the solvent. In this study, aqueous benzylamine was used as a model compound to explore the reaction mechanisms, kinetics, and equilibria of amines under hydrothermal conditions. Experiments were carried out in anoxic silica glass tubes at 250°C (Psat) using phosphate-buffered solutions to observe changes in reaction rates and product distributions as a function of pH. The rate of decomposition of benzylamine was much faster at pH 4 than at pH 9, consistent with the prediction that benzylamine acts as both nucleophile and an electrophile, and our estimate that the pKa of benzylamine is ~5 at 250°C and Psat. Accordingly, dibenzylamine is the primary product of the reaction of two benzylamine molecules, and this reaction is readily reversible under hydrothermal conditions. Extremely acidic or basic pH can be used to suppress dibenzylamine production, which also suppresses the formation of all other major products, including toluene, benzyl alcohol, dibenzylimine, and tribenzylamine. This suggests that dibenzylamine is the lone primary product that then itself reacts as a precursor to produce the above compounds. Analog experiments performed with ring-substituted benzylamine derivatives and chiral

  9. Cytotoxicity and genotoxicity induced by coal and coal fly ash particles samples in V79 cells.

    Science.gov (United States)

    León-Mejía, Grethel; Silva, Luis F O; Civeira, Matheus S; Oliveira, Marcos L S; Machado, Miriana; Villela, Izabel Vianna; Hartmann, Andreas; Premoli, Suziane; Corrêa, Dione Silva; Da Silva, Juliana; Henriques, João Antônio Pêgas

    2016-12-01

    Exposure to coal and coal ashes can cause harmful effects in in vitro and in vivo systems, mainly by the induction of oxidative damage. The aim of this work was to assess cytotoxic and genotoxic effects using the V79 cell line treated with coal and coal fly ash particles derived from a coal power plant located in Santa Catarina, Brazil. Two coal samples (COAL11 and COAL16) and two coal fly ash samples (CFA11 and CFA16) were included in this study. COAL16 was co-firing with a mixture of fuel oil and diesel oil. The comet assay data showed that exposure of V79 cells to coal and coal fly ash particles induced primary DNA lesions. Application of lesion-specific endonucleases (FPG and ENDO III) demonstrated increased DNA effects indicating the presence of high amounts of oxidative DNA lesions. The cytokinesis-block micronucleus cytome assay analysis showed that exposure of V79 cells to high concentrations of coal and coal fly ash particles induced cytotoxic effects (apoptosis and necrosis) and chromosomal instability (nucleoplasmic bridges, nuclear buds, and micronucleus (MN) formation). These results may be associated with compounds contained in the surface of the particles as hazardous elements, ultrafine/nanoparticles, and polycyclic aromatic hydrocarbons (PAHs) which were detected in the samples. Graphical abstract ᅟ.

  10. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>20131668 Chang Huizhen(Key Laboratory of Coalbed Methane Resources and Reservoir Formation Process,CUMT,Ministry of Edu-cation,School of Resource and Earth Science,China University of Mining and Technology,Xuzhou 221008,China);Qin Yong Differences in of Pore Structure of Coals and Their Impact on the Permeability of Coals from the

  11. Isolation of a naphthalene-degrading strain from activated sludge and bioaugmentation with it in a MBR treating coal gasification wastewater.

    Science.gov (United States)

    Xu, Peng; Ma, Wencheng; Han, Hongjun; Jia, Shengyong; Hou, Baolin

    2015-03-01

    A highly effective naphthalene-degrading bacterial strain was isolated from acclimated activated sludge from a coal gasification wastewater plant, and identified as a Streptomyces sp., designated as strain QWE-35. The optimal pH and temperature for naphthalene degradation were 7.0 and 35°C. The presence of additional glucose and methanol significantly increased the degradation efficiency of naphthalene. The strain showed tolerance to the toxicity of naphthalene at a concentration as great as 200 mg/L. The Andrews mode could be fitted to the degradation kinetics data well over a wide range of initial naphthalene concentrations (10-200 mg/L), with kinetic values q max = 0.84 h(-1), K s = 40.39 mg/L, and K i = 193.76 mg/L. Metabolic intermediates were identified by gas chromatography and mass spectrometry, allowing a new degradation pathway for naphthalene to be proposed for the first time. Strain QWE-35 was added into a membrane bioreactor (MBR) to enhance the treatment of real coal gasification wastewater. The results showed that the removal of chemical oxygen demand and total nitrogen were similar between bioaugmented and non-bioaugmented MBRs, however, significant removal of naphthalene was obtained in the bioaugmented reactor. The findings suggest a potential bioremediation role of Streptomyces sp. QWE-35 in the removal of naphthalene from wastewaters.

  12. Power generation from chemically cleaned coals: do environmental benefits of firing cleaner coal outweigh environmental burden of cleaning?

    DEFF Research Database (Denmark)

    Ryberg, Morten W.; Owsianiak, Mikolaj; Laurent, Alexis;

    2015-01-01

    Power generation from high-ash coals is a niche technology for power generation, but coal cleaning is deemed necessary to avoid problems associated with low combustion efficiencies and to minimize environmental burdens associated with emissions of pollutants originating from ash. Here, chemical...... beneficiation of coals using acid and alkali–acid leaching procedures is evaluated as a potential coal cleaning technology employing life cycle assessment (LCA). Taking into account the environmental benefits from firing cleaner coal in pulverized coal power plants and the environmental burden of the cleaning....... Chemical cleaning can be optimized with regard to electricity, heat and methanol use for the hydrothermal washing step, and could have environmental impact comparable to that of physical cleaning if the overall resource intensiveness of chemical cleaning is reduced by a factor 5 to 10, depending...

  13. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111053 Chen Jian(School of Earth and Environment,Anhui University of Science and Technology,Huainan 232001,China);Liu Wenzhong Organic Affinity of Trace Elements in Coal from No.10 Coal-Bed at Western Huagou,Guoyang(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,38(4),2010,p.16-20,24,3 illus.,3 tables,19 refs.)Key words:coal,minor elements,Anhui Province In order to study the organic affinity of trace elements in coal from No.10 coal-bed at western Huagou,Guoyang,10 borehole samples were collected at exploration area of Huaibei mining area.The contents of 12 kinds of trace elements were determined by the inductively coupled plasma mass spectrometry(ICP-MS),the total organic carbon(TOC)of coal was determined by LECO carbon and sulfur analyzer,and the organic affinity of trace elements were deduced from the correlations between contents and TOCs.The results showed that the contents of V,Cr,Co,Ni,Mo,Cd,Sb,Pb and Zn were lower than

  14. Trace elements in coals of eastern Donbas

    Energy Technology Data Exchange (ETDEWEB)

    Taranushich, F.F. [All Russian Research & Geological Prospecting Institute for Coal Deposits, Rostov Na Donu (Russian Federation)

    2003-02-01

    Peculiarities of trace element (TE) distribution in coals of the eastern Donets Basin (Donbas) are discussed. The correlation of TE distribution with specific features of the geological setting of the region can testify to the hydrothermal introduction of trace elements or their redistribution in fluid-active zones. The geochemical regionalization of eastern Donbas is based on TE distribution. Strontium-gold-base metal, tungsten, and selenium geochemical belts and a rare metal geochemical block are outlined.

  15. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

    2014-01-01

    Biomass is one of the most abundant sources of renewable energy, and will be an important part of a more sustainable future energy system. In addition to direct combustion, there is growing attention on conversion of biomass into liquid en-ergy carriers. These conversion methods are divided...... into liquid biofuels, with the aim of describing the current status and development challenges of the technology. During the hydrothermal liquefaction process, the biomass macromolecules are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive...... into biochemical/biotechnical methods and thermochemical methods; such as direct combustion, pyrolysis, gasification, liquefaction etc. This chapter will focus on hydrothermal liquefaction, where high pressures and intermediate temperatures together with the presence of water are used to convert biomass...

  16. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

    2014-01-01

    Biomass is one of the most abundant sources of renewable energy, and will be an important part of a more sustainable future energy system. In addition to direct combustion, there is growing attention on conversion of biomass into liquid en-ergy carriers. These conversion methods are divided...... into biochemical/biotechnical methods and thermochemical methods; such as direct combustion, pyrolysis, gasification, liquefaction etc. This chapter will focus on hydrothermal liquefaction, where high pressures and intermediate temperatures together with the presence of water are used to convert biomass...... into liquid biofuels, with the aim of describing the current status and development challenges of the technology. During the hydrothermal liquefaction process, the biomass macromolecules are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive...

  17. British coal

    Energy Technology Data Exchange (ETDEWEB)

    Forrest, M.

    2009-03-15

    The paper describes a visit to UK's Daw Mill in north Warwickshire to find out about a planned expansion of the coal mine. Daw Mill, 10 km west of Coventry is the UK's largest underground coal mine. The coal is extracted by an Eckhoff Sl500 coal shearer that traverses the coalface. Overarching the shearer is a series of electro-hydraulically operated powered roof supports (PRS) over the roof and coalface that are advanced forward after each pass of the shearer. The void behind the PRS is then allowed to collapse. The coalface is currently 295 m long, but there are plans to extend the replacement coalface to 357 m. Under the shearer is an armored face conveyor (AFC) that receives and transports the coal along the coalface and deposits it onto the beam stage loader, which sits at 90{sup o} to the AFC. The coal is turned by a deflector plough on the AFC headframe and is transferred to the belt conveyor to begin its journey out of the mine. Last year two significant records were broken at Daw Mill - the fastest million tonnes achieved and the European record for a single face of 3.2 Mt. The 300s area of the mine has already been mapped out and development teams are constructing roadways to facilitate more mining. To maintain annual production in excess of three million tonnes will require at least 5,000 m of roadways to access the coal, and install equipment. These investments are supported by proven reserves. Seismic surveys and borehole drilling has shown approximately 20 Mt of extractable coal in the 300s area which extends over 15 km{sup 2}. These panels will be the next to be mined in a sequence that extends to 2014. 2 photos.

  18. Coal mining: coal in Spain

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Arguelles Martinez, A.; Lugue Cabal, V.

    1984-01-01

    The Survey of Spanish Coal Resources published by the Centre for Energy Studies in 1979 is without doubt the most serious and full study on this subject. The coal boom of the last few years and the important role it will play in the future, as well as the wealth of new information which has come to light in the research carried out in Spanish coalfields by both the public and private sector, prompted the General Mine Management of the Ministry of Industry and Energy to commission IGME to review and update the previous Survey of Spanish Coal Resources of November 1981.

  19. Ensiling of wheat straw decreases the required temperature in hydrothermal pretreatment

    DEFF Research Database (Denmark)

    Ambye-Jensen, Morten; Thomsen, Sune Tjalfe; Kádár, Zsófia

    2013-01-01

    .5%. When comparing hydrothermally treated wheat straw (170, 180 and 190°C) with hydrothermally treated ensiled wheat straw (same temperatures), several positive effects of ensiling were revealed. Glucan was up-concentrated in the solid fraction and the solubilisation of hemicellulose was significantly...... increased.Subsequent enzymatic hydrolysis of the solid fractions showed that ensiling significantly improved the effect of pretreatment, especially at the lower temperatures of 170 and 180°C.The overall glucose yields after pretreatments of ensiled wheat straw were higher than for non-ensiled wheat straw...... hydrothermally treated at 180°C, with overall glucose yield of 78% and overall conversion yield of xylose of 87%. CONCLUSIONS: Ensiling of wheat straw is shown to be an effective pre-step to hydrothermal treatment, and can give rise to a welcomed decrease of process temperature in hydrothermal treatments...

  20. Blended coals for improved coal water slurries

    Institute of Scientific and Technical Information of China (English)

    GU Tian-ye; WU Guo-guang; LI Qi-hui; SUN Zhi-qiang; ZENG Fang; WANG Guang-you; MENG Xian-liang

    2008-01-01

    Three coal samples of different ranks were used to study the effect of coal blending on the preparation of Coal Water Slurry (CWS). The results show that by taking advantage of two kinds of coal, the coal concentration in slurry made from hard-to-pulp coal can be effectively improved and increased by 3%-5% generally. DLT coal (DaLiuTa coal mine) is very poor in slurryability and the stability and rheology of the resulting slurry are not very good. When the amount of easily slurried coal is more than 30%, all properties of the CWS improve and the CWS meets the requirements for use as fuel. Coalification, porosity, surface oxygenic functional groups, zeta potential and grindability have a great effect on the performance of blended coal CWS. This leads to some differences in performance between the slurry made from a single coal and slurry made from blended coal.

  1. Effect of hydrothermal heat treatment on magnetic properties of copper zinc ferrite rf sputtered films

    Directory of Open Access Journals (Sweden)

    Jasmeet Kaur

    2016-05-01

    Full Text Available The hydrothermal treatment to the nano-structured films can overcome the destruction of the films. The Cu-Zn Ferrite films were fabricated by RF-sputtering on quartz substrates. Subsequently, the as deposited films were heat treated using hydrothermal process. The X-ray diffraction pattern of the as-deposited and hydrothermal treated films indicate nano-crystalline cubic spinel structure. The amorphous nature of the films is removed after hydrothermal treatment with decreased crystallite size. The field emission scanning electron micrographs showed merged columnar growth for as deposited films, which changes to well define columns after hydrothermal heating. The homogeneous cluster distribution is observed in surface view of the hydrothermal treated films. Hydrothermal treated films show merging of in-plane and out of plane magnetization plots (M(H whereas the M(H plots of as deposited films show angular dependence. The strong angular dependence is observed in the FMR spectra due to the presence of a uniaxial anisotropy in the films. The ferromagnetic interactions decrease in hydrothermal heated films due to the reduced shape anisotropy and crystallite size.

  2. Mild hydrothermal conditioning prior to torrefaction and slow pyrolysis of low-value biomass.

    Science.gov (United States)

    Van Poucke, R; Nachenius, R W; Agbo, K E; Hensgen, F; Bühle, L; Wachendorf, M; Ok, Y S; Tack, F M G; Prins, W; Ronsse, F; Meers, E

    2016-10-01

    The aim of this research was to establish whether hydrothermal conditioning and subsequent thermochemical processing via batch torrefaction or slow pyrolysis may improve the fuel quality of grass residues. A comparison in terms of fuel quality was made of the direct thermochemical processing of the feedstock versus hydrothermal conditioning as a pretreatment prior to thermochemical processing. Hydrothermal conditioning reduced ash content, and particularly nitrogen, potassium and chlorine contents in the biomass. The removal of volatile organic matter associated with thermochemical processes can increase the HHV to levels of volatile bituminous coal. However, slow pyrolysis only increased the HHV of biomass provided a low ash content (<6%) feedstock was used. In conclusion, hydrothermal conditioning can have a highly positive influence on the efficiency of thermochemical processes for upgrading low-value (high-ash) biomass to a higher quality fuel.

  3. Solubilization of coal in organic media

    Science.gov (United States)

    Lahaye, P.; Decroocq, D.

    1977-01-01

    The use of solvent extraction to solubilize coal is discussed. Simple extractions are described which are conducted at moderate temperatures to exclude extraneous chemical reactions which would lead to uncontrolled changes in the components of the treated coal. Sample preparation, extraction apparatus, and the determination of extract yield for different experiments are also described.

  4. Remediação de drenagem ácida de mina usando zeólitas sintetizadas a partir de cinzas leves de carvão Remediation of acid mine drainage using zeolites synthesized from coal fly ash

    Directory of Open Access Journals (Sweden)

    Denise Alves Fungaro

    2006-07-01

    Full Text Available Zeolitic material was synthesized from coal fly ashes (baghouse filter fly ash and cyclone filter fly ash by hydrothermal alkaline activation. The potential application of the zeolitic product for decontamination of waters from acid mine drainage was evaluated. The results showed that a dose of 30 g L-1 of zeolitic material allowed the water to reach acceptable quality levels after treatment. Both precipitation and cation-exchange processes accounted for the reduction in the pollutant concentration in the treated waters.

  5. Characterization of biochar from hydrothermal carbonization of bamboo

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, Daniel; Escala, Marina [Institute of Natural Resource Sciences, School of Life Sciences and Facility Management, Zurich University of Applied Sciences, Waedenswil (Switzerland); Supawittayayothin, Kawin; Tippayawong, Nakorn [Department of Mechanical Engineering, Chiang Mai University, Ching Mai (Thailand)

    2011-07-01

    This paper presents a preliminary investigation on producing biochar from bamboo using a technique of hydrothermal carbonization. Laboratory scale experimentation to produce carbonaceous materials was carried out. The suspended biomass samples in water were subjected to hydrothermal carbonization at 220 C, 2.2 MPa in a closed vessel for six hours. The resulting products were in solid and liquid phase. The coal-like biochar was found to have rough surface and porous structure. The aqueous solution was found to contain a high concentration of nutrients, especially nitrogen, phosphorus, and potassium. The study shows that bamboo is an interesting and adequate biomass for the production of biochar with several applications including carbon sequestration.

  6. Characterization of biochar from hydrothermal carbonization of bamboo

    Directory of Open Access Journals (Sweden)

    Daniel Schneider, Marina Escala, Kawin Supawittayayothin, Nakorn Tippayawong

    2011-07-01

    Full Text Available This paper presents a preliminary investigation on producing biochar from bamboo using a technique of hydrothermal carbonization. Laboratory scale experimentation to produce carbonaceous materials was carried out. The suspended biomass samples in water were subjected to hydrothermal carbonization at 220 C, 2.2 MPa in a closed vessel for six hours. The resulting products were in solid and liquid phase. The coal-like biochar was found to have rough surface and porous structure. The aqueous solution was found to contain a high concentration of nutrients, especially nitrogen, phosphorus, and potassium. The study shows that bamboo is an interesting and adequate biomass for the production of biochar with several applications including carbon sequestration.

  7. COAL GEOLOGY

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>20091749 Cai Hou’an(College of Energy Geology,China University of Geosciences,Beijing 100083,China);Xu Debin SHRIMP U-Pb Isotope Age of Volcanic Rocks Distributed in the Badaohao Area,Liaoning Province and Its Significance(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,36(4),2008,p.17-20,2 illus.,1 table,16 refs.)Key words:coal measures,volcanic rocks,U-Pb dating,LiaoningA set of andesite volcanic rocks distributes in the Badaohao area in Heishan County,Liaoning Province.It’s geological age and stratigraphy sequence relationship between the Lower Cretaceous Badaohao Formation and the volcanic rocks can not make sure till now and is influencing the further prospect for coals.Zircon

  8. Hydrothermal processes above the Yellowstone magma chamber: Large hydrothermal systems and large hydrothermal explosions

    Science.gov (United States)

    Morgan, L.A.; Shanks, W.C. Pat; Pierce, K.L.

    2009-01-01

    Hydrothermal explosions are violent and dramatic events resulting in the rapid ejection of boiling water, steam, mud, and rock fragments from source craters that range from a few meters up to more than 2 km in diameter; associated breccia can be emplaced as much as 3 to 4 km from the largest craters. Hydrothermal explosions occur where shallow interconnected reservoirs of steam- and liquid-saturated fluids with temperatures at or near the boiling curve underlie thermal fields. Sudden reduction in confi ning pressure causes fluids to fl ash to steam, resulting in signifi cant expansion, rock fragmentation, and debris ejection. In Yellowstone, hydrothermal explosions are a potentially signifi cant hazard for visitors and facilities and can damage or even destroy thermal features. The breccia deposits and associated craters formed from hydrothermal explosions are mapped as mostly Holocene (the Mary Bay deposit is older) units throughout Yellowstone National Park (YNP) and are spatially related to within the 0.64-Ma Yellowstone caldera and along the active Norris-Mammoth tectonic corridor. In Yellowstone, at least 20 large (>100 m in diameter) hydrothermal explosion craters have been identifi ed; the scale of the individual associated events dwarfs similar features in geothermal areas elsewhere in the world. Large hydrothermal explosions in Yellowstone have occurred over the past 16 ka averaging ??1 every 700 yr; similar events are likely in the future. Our studies of large hydrothermal explosion events indicate: (1) none are directly associated with eruptive volcanic or shallow intrusive events; (2) several historical explosions have been triggered by seismic events; (3) lithic clasts and comingled matrix material that form hydrothermal explosion deposits are extensively altered, indicating that explosions occur in areas subjected to intense hydrothermal processes; (4) many lithic clasts contained in explosion breccia deposits preserve evidence of repeated fracturing

  9. The hydrothermal reaction kinetics of aspartic acid

    Science.gov (United States)

    Cox, Jenny S.; Seward, Terry M.

    2007-02-01

    Experimental data on the hydrothermal reaction kinetics of aspartic acid were acquired using a custom-built spectrophotometric reaction cell which permits in situ observation under hydrothermal conditions. The results of this study indicate that the reaction kinetics of dilute aspartic acid solutions are significantly different depending on the presence or absence of catalytic surfaces such as standard metal alloys. The spectroscopic data presented here represent the first direct observations, in situ and in real time, of an amino acid reacting in a hydrothermal solution. Quantitative kinetic information, including rate constants, concentration versus time profiles, and calculations of the individual component spectra, was obtained from the data using a chemometric approach based on factor analysis/principle component analysis which treats the rate expressions simultaneously as a system of differential algebraic equations (DAE) of index 1. Identification of the products was confirmed where possible by high pressure anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD). The reaction kinetics of aspartic acid under hydrothermal conditions was observed to be highly complex, in contrast to previous studies which indicated almost exclusively deamination. At lower temperatures (120-170 °C), several different reaction pathways were observed, including decarboxylation and polymerization, and the catalytic effects of reactor surfaces on the aspartic acid system were clearly demonstrated. At higher temperatures (above 170 °C), aspartic acid exhibited highly complex behaviour, with evidence indicating that it can simultaneously dimerize and cyclize, deaminate (by up to two pathways), and decarboxylate (by up to two pathways). These higher temperature kinetics were not fully resolvable in a quantitative manner due to the complexity of the system and the constraints of UV spectroscopy. The results of this study provide strong evidence that the reaction

  10. Method for producing catalysis from coal

    Science.gov (United States)

    Farcasiu, Malvina; Derbyshire, Frank; Kaufman, Phillip B.; Jagtoyen, Marit

    1998-01-01

    A method for producing catalysts from coal is provided comprising mixing an aqueous alkali solution with the coal, heating the aqueous mixture to treat the coal, drying the now-heated aqueous mixture, reheating the mixture to form carbonized material, cooling the mixture, removing excess alkali from the carbonized material, and recovering the carbonized material, wherein the entire process is carried out in controlled atmospheres, and the carbonized material is a hydrocracking or hydrodehalogenation catalyst for liquid phase reactions. The invention also provides for a one-step method for producing catalysts from coal comprising mixing an aqueous alkali solution with the coal to create a mixture, heating the aqueous mixture from an ambient temperature to a predetermined temperature at a predetermined rate, cooling the mixture, and washing the mixture to remove excess alkali from the treated and carbonized material, wherein the entire process is carried out in a controlled atmosphere.

  11. PRE-FILTRATION IN BOULDER AND SLOW SAND FILTRATION WITH NON-WOVEN SYNTHETIC LAYERS AND GRANULATED VEGETAL COAL TO IMPROVE QUALITY IN WASTEWATER TREATED BY CONSTRUCTED WETLANDS

    OpenAIRE

    Paterniani, JES; da Silva, MJM; Ribeiro, TAP; Barbosa, M.

    2011-01-01

    The objective of this study was the comparison between two filtration systems, being one composed of a boulder pre-filter followed by a slow filter with sand as filtration media and a non-woven synthetic fabric in the upper part, and the other one composed of a boulder pre-filter followed by a slow filter with sand as filtration media and granular activated charcoal and a non-woven synthetic fabric in the upper part, for the purification of household effluents treated in cultivated beds, to b...

  12. Coal industry annual 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  13. Coal Industry Annual 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  14. Coal industry annual 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  15. Leeuwpan fine coal dense medium plant

    CSIR Research Space (South Africa)

    Lundt, M

    2010-11-01

    Full Text Available availability to treat the higher grade coal (the bottom layer of coal) from the no. 2 Seam for a local and export metallurgical market. Following the path of evolution, in 2007, Leeuwpan commissioned the first double stage ultra-fines dense medium cyclone... plant in the coal industry, to form part of its overall DMS plant. It replaced the spirals to treat the -1 mm material. Spirals are still the most commonly and accepted method used by the industry, but it seems as if the pioneering cyclone process...

  16. Effect of carrier fill ratio on biofilm properties and performance of a hybrid fixed-film bioreactor treating coal gasification wastewater for the removal of COD, phenols and ammonia-nitrogen.

    Science.gov (United States)

    Rava, E; Chirwa, E

    2016-01-01

    The purpose of this study was to determine the effect different biofilm carrier filling ratios would have on biofilm morphology and activity and bacterial diversity in a hybrid fixed-film bioreactor treating high strength coal gasification wastewater (CGWW) for the removal of chemical oxygen demand (COD), phenols and ammonia-nitrogen. Results showed that a carrier fill of 70% formed a 'compact' biofilm, a 50% fill formed a 'rippling' biofilm and a 30% fill formed a 'porous' biofilm. The highest microbial activity was obtained with a 50% carrier fill supporting a relatively thin biofilm. The highest level of biofilm bound metals were aluminium, silicon, calcium and iron in the 'compact' biofilm; nitrogen, magnesium, chloride, sodium and potassium in the 'rippling' biofilm, and copper in the 'porous' biofilm. The bioreactor improved the quality of the CGWW by removing 49% and 78% of the COD and phenols, respectively. However, no significant amount of ammonia-nitrogen was removed since nitrification did not take place due to heterotrophic bacteria out-competing autotrophic nitrifying bacteria in the biofilm. The dominant heterotrophic genera identified for all three carrier filling ratios were Thauera, Pseudaminobacter, Pseudomonas and Diaphorobacter.

  17. Coal industry annual 1993

    Energy Technology Data Exchange (ETDEWEB)

    1994-12-06

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  18. Coal - proximate analysis

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-06-14

    This Standard establishes a practice for the proximate analysis of coal, that is, the coal is analysed for the content of moisture, ash and volatile matter; fixed carbon is calculated. The standard provides a basis for the comparison of coals.

  19. Efeito da aplicação do cloreto de cálcio nos frutos da manga 'Tommy Atkins' tratados hidrotermicamente Effect of calcium chloride application on mango fruit cv. Tommy Atkins hydrothermally treated

    Directory of Open Access Journals (Sweden)

    Murillo Freire Júnior

    1999-05-01

    Full Text Available O objetivo do trabalho foi estudar os efeitos da aplicação de cloreto de cálcio, associado ao tratamento hidrotérmico em frutos de manga (Mangifera indica L.. Verificou-se que a associação do tratamento hidrotérmico à aplicação de cloreto de cálcio é viável, e que existe uma correlação positiva entre o Ca aplicado e a quantidade deste elemento na casca, porém com pouca penetração para a polpa do fruto, o que demonstra que o Ca age positivamente na diminuição dos sintomas da antracnose. Pelo contraste apresentado na aparência externa dos frutos, a aplicação de cloreto de cálcio a 4% mostrou melhores resultados, porém sem garantir a qualidade final exigida para a exportação dos frutos. A aplicação de cloreto de cálcio não se mostrou efetiva no aumento do período de conservação dos frutos.The aim of this work was to study the effects of the application of calcium chloride associated with hydrothermal treatment on post-harvest preservation of mango fruit (Mangifera indica L.. The Ca absorption by mango peel and flesh was investigated using the same conditions usually employed for the fruit exportation to the american market. It was verified that the association of heat treatment to Ca application was viable. There was a positive correlation between the amount of Ca applied and the amount of this element presented in the peel, although low penetration toward the flesh was observed. It was demonstrated that Ca reduces anthracnose symptoms. It was also verified, by observing the external appearance of the fruits, that the best results were obtained when 4% of calcium chloride was used, although such concentration did not guarantee the required quality for the fruit exportation. The calcium chloride application was not effective to increase the shelf-life of the fruits.

  20. Duration of hydrothermal treatment and peeling of 'Murcott' tangor

    Directory of Open Access Journals (Sweden)

    Ana Luiza Pinheiro

    2011-12-01

    Full Text Available Hydrothermal treatment facilitates the peeling of 'Pera' sweet orange fruit and does not alter its quality. The aim of this work was to adapt the technology of peeling for the use of hydrothermal treatment in 'Murcott' tangor and to evaluate its influence in the CO2 production and the physicochemical, microbiologic and sensorial characteristics of fruits. The peeling time, the yield of marketable fruits and the internal temperature of fruits during the treatment were also evaluated. The hydrothermal treatment consisted of placing the fruits in a water-bath at 50 ºC for 5, 10, 15, 20, 25 and 30 min. Fruits were peeled by first opening a gap in the peduncle region with a knife and then manually removing the flavedo and albedo. Fruits were stored at 5 ºC for six days. Hydrothermal treatment caused changes in the fruits' CO2 production for only the first few hours after processing. Internal fruit temperature after 30 min of treatment reached 35 ºC. There were no changes in the physicochemical and microbiologic characteristics of the fruits. The treatment did not change the flavor, improved the fruits' appearance, decreased the peeling time of the treated fruits by 57 % and increased the yield of marketable fruits. In conclusion, the hydrothermal treatment accomplished from 5 to 30 min at 50 ºC can be used as part of the peeling process for 'Murcott' tangor.

  1. Hydrothermal carbonization of anaerobically digested maize silage.

    Science.gov (United States)

    Mumme, Jan; Eckervogt, Lion; Pielert, Judith; Diakité, Mamadou; Rupp, Fabian; Kern, Jürgen

    2011-10-01

    Hydrochars were prepared by hydrothermal carbonization (HTC) of maize silage previously treated at 55 °C in a two-stage solid-state reactor system. The HTC was carried out in a 1-L stirred pressure reactor with pH regulation by citric acid. The treated silage carbonized at relatively mild conditions (190 °C, 2 h), and the hydrochars showed mainly amorphous macro-size features with a carbon content of 59-79% (ash-free, dry) and a higher heating value of 25-36 MJ kg⁻¹. Temperature was the main influencing factor. The surface area according to Brunauer-Emmett-Teller (BET) analysis was highest at 190 °C (12.3 m²) g⁻¹). Based on these results, the hydrochars are potentially interesting for applications such as an alternative fuel or a soil conditioner.

  2. Queensland coal inventory

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-04-01

    Australia's black coal resources rank in the top five globally, around 50% of which are located in the sedimentary basins of Queensland. The Bowen Basin is the most prolific coal repository, hosting over 60% of the currently established resource inventory. Large volumes of thermal coal are present in the Surat and Galilee basins as well as small extensional and pull apart basins such as Blair Athol and Tarong. The article examines Queensland's coal industry from a government perspective. It first discusses the current coal market, then introduces the concept of inventory coal and explains the Australia Joint Ore Reserves Committee (JORC) code - a resource evaluation system. The stratigraphy of each of Queensland's coal basins is then discussed in sections headed Permian coals, Triassic coals, Jurassic and Cretaceous coals, and Tertiary coals. 3 figs.

  3. Performance of cemented coal gangue backfill

    Institute of Scientific and Technical Information of China (English)

    ZHANG Qin-li; WANG Xin-min

    2007-01-01

    Possibility of cemented gangue backfill was studied with gangue of Suncun Coal Mine, Xinwen Coal Group, Shandong,and fly ash of nearby thermal power plant, in order to treat enormous coal gangue on a large scale and to recovery safety coal pillars.The results indicate that coal gangue is not an ideal aggregate for pipeline gravity flow backfill, but such disadvantages of gangue as bad fluidity and serious pipe wear can be overcome by addition of fly ash. It is approved that quality indexes such as strength and dewatering ratio and piping feature of slurry can satisfy requirement of cemented backfill if mass ratio of cement to fly ash to gangue higher middle and long term comprehensive strength.

  4. Power generation from chemically cleaned coals: do environmental benefits of firing cleaner coal outweigh environmental burden of cleaning?

    DEFF Research Database (Denmark)

    Ryberg, Morten W.; Owsianiak, Mikolaj; Laurent, Alexis;

    2015-01-01

    Power generation from high-ash coals is a niche technology for power generation, but coal cleaning is deemed necessary to avoid problems associated with low combustion efficiencies and to minimize environmental burdens associated with emissions of pollutants originating from ash. Here, chemical...... itself, it is demonstrated that for a wide range of cleaning procedures and types of coal, chemical cleaning generally performs worse than combustion of the raw coals and physical cleaning using dense medium separation. These findings apply for many relevant impact categories, including climate change....... Chemical cleaning can be optimized with regard to electricity, heat and methanol use for the hydrothermal washing step, and could have environmental impact comparable to that of physical cleaning if the overall resource intensiveness of chemical cleaning is reduced by a factor 5 to 10, depending...

  5. Application of Hydrothermal Treatment to High Concentrated Sewage Sludge for Anaerobic Digestion Process

    Directory of Open Access Journals (Sweden)

    M. Orikawa

    2013-10-01

    Full Text Available Tomato and seaweed were produced by utilizing CO2 and heat discharged from power generation using biogas in Toyogawa biomass park, Japan. The biogas was obtained by anaerobic digestion with hydrothermal treatment. The hydrothermal treatment was applied to the high concentrated sewage sludge (22 % total solids (TS dewatered sludge. The purpose of this study is to clarify the effect of hydrothermal treatment on the qualities of high concentrated sewage sludge, by analyzing particulate organic carbon (POC and dissolved organic carbon (DOC. The hydrothermal treatment was investigated under 10-60 min of treatment time, 180-200 °C of temperature, 10-22 %-TS of sewage sludge concentration. The results showed that the DOC in each conditions increased through hydrothermal treatment. The highest DOC obtained was 67 % of total carbon concentration, when the temperature was 180 °C, treatment time was 60 min and sewage sludge concentration was 10 %-TS. Furthermore, the viscosity of treated sewage sludge was decreased by hydrothermal treatment. In batch anaerobic digestion test, methane gas production was confirmed. In addition, this study evaluated the energy balance of this system. Thus, the results of this study indicated that the possibility of application of hydrothermal treatment to high concentrated sewage sludge for anaerobic digestion process. Keywords: anaerobic reaction, hydrothermal treatment, sewage sludge, solubilization

  6. Applied coal petrology: the role of petrology in coal utilization

    Energy Technology Data Exchange (ETDEWEB)

    Isabel Suarez-Ruiz; John Crelling [Instituto Nacional del Carbon (INCAR-CSIC), Oviedo (Spain)

    2008-08-15

    This book is an integrated approach towards the applications of coal (organic) petrology and discusses the role of this science in the field of coal and coal-related topics. Contents are: Introduction 2. Basic factors controlling coal quality and technological behaviour of coal 3. Mining and benefication 4. Coal combustion 5. Coal gasification 6. Coal liquefaction 7. Coal carbonisation 8. Coal-derived carbons 9. Coal as a Petroleum source rock and reservoir rock 10. Environmental and health aspects 11. Other applications of coal petrology.

  7. Enhancement of valve metal osteoconductivity by one-step hydrothermal treatment

    Energy Technology Data Exchange (ETDEWEB)

    Zuldesmi, Mansjur, E-mail: mzuldesmi@yahoo.com [Department of Materials Science and Engineering, Graduate School of Engineering, Nagoya University, Nagoya (Japan); Department of Mechanical Engineering, Manado State University (UNIMA) (Indonesia); Waki, Atsushi [Department of Materials Science and Engineering, Graduate School of Engineering, Nagoya University, Nagoya (Japan); Kuroda, Kensuke; Okido, Masazumi [EcoTopia Science Institute, Nagoya University, Nagoya (Japan)

    2014-09-01

    In this study, we produced super-hydrophilic surfaces of valve metals (Ti, Nb, Ta and Zr) by one-step hydrothermal treatment. Their surface characteristics and osteoconductivity using an in vivo test were then assessed. These data were compared with that of as-polished, as-anodized and both anodized + hydrothermally treated samples. Changes in surface chemistry, surface morphology and structure were investigated by X-ray photoelectron spectroscopy, scanning electron microscopy, and X-ray diffractometry. The results revealed that the water contact angles of valve metals were decreased by hydrothermal treatment and continued to reduce dramatically until lower than 10° after being immersed in phosphate buffered solution. By producing super-hydrophilic surfaces, the osteoconductivity of these hydrothermally treated valve metals was enhanced by up to 55%. - Highlights: • Hydrothermal treatment in distilled water was applied to valve metals. • Surface characteristics and osteoconductivity by in vivo test were evaluated. • Water contact angles of valve metals were decreased by hydrothermal treatment. • Osteoconductivity of valve metals improved notably by hydrothermal treatment.

  8. Hydrothermal Synthesis of Metal Silicates

    Institute of Scientific and Technical Information of China (English)

    Lii Kwang-Hwa

    2004-01-01

    Organically templated metal phosphates have been extensively studied because of interesting structural chemistry and potential applications in catalysis. However, in most cases the organic templates cannot be removed without collapse of the frameworks. This is in contrast to the high thermal stability and extensive applications of zeolites in refinery and petrochemical processes.Therefore, studies have been directed to the synthesis of transition metal silicates to produce more stable frameworks. Our synthetic methods are twofold, namely mild hydrothermal reactions in Teflon-lined autoclaves at 100-200 ℃ using organic amines as templates and high-temperature,high-pressure hydrothermal reactions in gold ampoules contained in a high-pressure reaction vessel at ca. 550 ℃ and 150 Mpa using alkali metal cations as templates. In this presentation I will report the high-temperature, high-pressure hydrothermal synthesis, crystal structures, and solid-state NMR spectroscopy of a number of new silicates of indium, uranium, and transition metals.

  9. Geochemical characteristics of Guizhou Permian coal measure strata and analysis of the control factors

    Institute of Scientific and Technical Information of China (English)

    YANG Rui-dong; LIU Ling; WEI Huai-rui; CUI Yu-chao; CHENG Wei

    2011-01-01

    Based on element geochemical studies of the main Permian exploitable coal measure strata in Western Guizhou, the element geochemical distribution characteristics of the main exploitable coal measures were revealed in the regions of Dafang,Qianxi, Weining, Hezhang, Zhijin, etc., of Guizhou Province, and the results show that their element contents are mainly affected by terrestrial material supply. Coal measures formed in the delta plain environment where sufficient terrestrial materials are supplied contain relatively abundant trace elements and rare-earth elements, whereas those formed in the tidal-flat environment influenced greatly by seawater have relatively low contents of trace elements and rare-earth elements, mainly controlled by the geological fact that basalts the parent rocks from source regions contain high trace elements and rare-earth elements. In addition, coal measures affected by later hydrothermal activities and fault tectonics contain a large amount of harmful elements. According to the rules of distribution of elements in coal measures, a new idea was put forward to classify coal-forming environments by using the geochemical composition characteristics, which is of great significance in dissolving the problem of whether coal measures were formed either in delta environments or in tidal-flat environments in Western Guizhou. At the same time, the rules of distribution of elements in the main exploitable coal measures in Western Guizhou were fully understood, which is of direct significance in utilizing coal resources on the basis of classification of coals, as well as in developing the coal chemical industry.

  10. Hydrothermalism in the Mediterranean Sea

    Science.gov (United States)

    Dando, P. R.; Stüben, D.; Varnavas, S. P.

    1999-08-01

    Hydrothermalism in the Mediterranean Sea results from the collision of the African and European plates, with the subduction of the oceanic part of the African plate below Europe. High heat flows in the resulting volcanic arcs and back-arc extensional areas have set-up hydrothermal convection systems. Most of the known hydrothermal sites are in shallow coastal waters, <200 m depth, so that much of the reported fluid venting is of the gasohydrothermal type. The hydrothermal liquids are of varying salinities, both because of phase separation as a result of seawater boiling at the low pressures and because of significant inputs of rainfall into the hydrothermal reservoirs at some sites. The major component of the vented gas is carbon dioxide, with significant quantities of sulphur dioxide, hydrogen sulphide, methane and hydrogen also being released. Acid leaching of the underlying rocks leads to the mobilisation of heavy metals, many of which are deposited sub-surface although there is a conspicuous enrichment of metals in surficial sediments in venting areas. Massive polymetalic sulphides have been reported from some sites. No extant vent-specific fauna have been described from Mediterranean sites. There is a reduced diversity of fauna within the sediments at the vents. In contrast, a high diversity of epifauna has been reported and the vent sites are areas of settlement for exotic thermophilic species. Large numbers of novel prokaryotes, especially hyperthermophilic crenarchaeota, have been isolated from Mediterranean hydrothermal vents. However, their distribution in the subsurface biosphere and their role in the biogeochemistry of the sites has yet to be studied.

  11. Assessing coal burnout

    Energy Technology Data Exchange (ETDEWEB)

    Lowe, A. [Pacific Power, Sydney, NSW (Australia)

    1999-11-01

    Recent research has allowed a quantitative description of the basic process of burnout for pulverized coals to be made. The Cooperative Research Centre for Black Coal Utilization has built on this work to develop a coal combustion model which will allow plant engineers and coal company representatives to assess their coals for combustion performance. The paper describes the model and its validation and outlines how it is run. 2 figs.

  12. Colombian coal focus

    Energy Technology Data Exchange (ETDEWEB)

    Warden-Fernandez, J.; Rodriguez, L.E. [University of Dundee, Dundee (United Kingdom)

    2003-03-01

    The paper reviews the development of Colombia's coal industry over recent years. Colombia has recently modernised its mining code, Law 685 of 2001 concerning mineral rights and including the concept of sustainable development. The article discusses the legislation, analyses trends in Columbia's income from the coal and mineral industries (nickel, gold, emerald), and briefly discusses coal reserves, mining projects, coal exports and markets for Colombian coal. 7 refs., 7 figs., 4 tabs.

  13. Coal markets in transition

    Energy Technology Data Exchange (ETDEWEB)

    Romer, R.

    1990-01-01

    Describes Colorado's coal industry, and the implementation of a nine point mining plan announced in 1988. This plan includes an environmental regulatory review, coal royalty reform, production and marketing incentives, clean coal and clean air issues, and promotion of the coal industry. Other issues to be addressed are abandoned mine reclamation, abandoned mine safety and land reclamation after surface mining. International markets for Colorado coal are also discussed.

  14. Coal combustion products

    Science.gov (United States)

    Kalyoncu, R.S.; Olson, D.W.

    2001-01-01

    Coal-burning powerplants, which supply more than half of U.S. electricity, also generate coal combustion products, which can be both a resource and a disposal problem. The U.S. Geological Survey collaborates with the American Coal Ash Association in preparing its annual report on coal combustion products. This Fact Sheet answers questions about present and potential uses of coal combustion products.

  15. Kinetic comparison of biological and conventional flotation of coal

    Energy Technology Data Exchange (ETDEWEB)

    Amini, E.; Oliazadeh, M.; Kolahdoozan, M. [University of Queensland, Brisbane, Qld. (Australia)

    2009-03-15

    Froth flotation is commonly used in coal processing to selectively recover the organic material (coal) from inorganic waste material. Tabas coal, located in east Iran, contains fine disseminated pyrite which is floated with coal during flotation, and hence decreasing the quality of the final concentrate. Reagents, such as sodium cyanide, are typically added to depress pyrite. Due to the toxicity of cyanide, alternative strategies for depressing pyrite flotation are being investigated. In this paper the metallurgical performance of Tabas coal treated with sodium cyanide is compared to that of Tabas coal which has undergone bacterial treatment using Acidithiobacillus ferrooxidans. Results indicate that bacterial treatment decreases the flotation rate of pyrite and improves the selectivity between coal and gangue. The possibility of using bacteria in place of toxic chemicals such as cyanide has significant environmental benefit.

  16. Coal data: A reference

    Energy Technology Data Exchange (ETDEWEB)

    1995-02-01

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  17. Microwave Hydrothermal Synthesis PZT of Nanometer Crystal

    Institute of Scientific and Technical Information of China (English)

    Hongxing LIU; Hong DENG; Yan LI; Yanrong LI

    2004-01-01

    It was focused on the applications and developments of microwave hydrothermal synthesis piezoelectric ceramic powder. The microwave hydrothermal vessel was designed and manufactured. The microwave hydrothermal synthesis system was established and the PZT piezoelectric ceramic powder was synthesized. XRD and TEM have been used to characterize the products in detail. The diameter of the PZT powder particle is from 40 to 60 nm.

  18. Mobilization of iron from coal fly ash was dependent upon the particle size and the source of coal.

    Science.gov (United States)

    Smith, K R; Veranth, J M; Lighty, J S; Aust, A E

    1998-12-01

    Particulate air pollution, including coal fly ash, contains iron, and some of the pathological effects after inhalation may be due to reactive oxygen species produced by iron-catalyzed reactions. The objective of this study was to determine whether iron, present in coal fly ash, was mobilized, leading to ferritin induction in human airway epithelial cells, and whether the size of the particles affected the amount of iron mobilized. Three types of coal were used to generate the three size fractions of fly ash collected. The Utah coal fly ash was generated from a bituminous b coal, the Illinois coal fly ash from a bituminous c coal, and the North Dakota coal fly ash from a lignite a coal. Three size fractions were studied to compare the amount of iron mobilized in human airway epithelial (A549) cells and by citrate in cell-free suspensions. The size fractions selected were fine (airborne particulate matter fraction greater than 10 microm. Coal fly ash samples were incubated with 1 mM citrate to determine if iron associated with coal fly ash could be mobilized. Iron was mobilized by citrate from all three size fractions of all three coal types to levels as high as 56.7 nmol of Fe/mg of coal fly ash after 24 h. With all three coal types, more iron was mobilized by citrate from the fraction than from the >2.5 microm fractions. Further, the mobilized iron was in the Fe(III) form. To determine if iron associated with the coal fly ash could be mobilized by A549 cells, cells were treated with coal fly ash, and the amount of the iron storage protein ferritin was determined after 24 h. Ferritin levels were increased by as much as 11.9-fold in cells treated with coal fly ash. With two of the three types of coal studied, more ferritin was induced in cells treated with the fraction than with the >2.5 microm fractions. Further, inhibition of the endocytosis of the coal fly ash by the cells resulted in ferritin levels that were near that of the untreated cells, suggesting that

  19. Hydrothermal precipitation of artificial violarite

    DEFF Research Database (Denmark)

    Jørgensen, W. H.; Toftlund, H.; Warner, T. E.

    2012-01-01

    The nonstoichiometric nickel-ore mineral, violarite, (Ni,Fe)3S4 was prepared as a phase-pure fine powder by a comparatively quick hydrothermal method from an aqueous solution of iron(II) acetate, nickel(II) acetate and DL-penicillamine in an autoclave at 130 °C for 45 h. Powder-XRD showed...

  20. Electricity generation from hydrothermal vents

    Science.gov (United States)

    Aryadi, Y.; Rizal, I. S.; Fadhli, M. N.

    2016-09-01

    Hydrothermal vent is a kind of manifestation of geothermal energy on seabed. It produces high temperature fluid through a hole which has a diameter in various range between several inches to tens of meters. Hydrothermal vent is mostly found over ocean ridges. There are some 67000 km of ocean ridges, 13000 of them have been already studied discovering more than 280 sites with geothermal vents. Some of them have a thermal power of up to 60 MWt. These big potential resources of energy, which are located over subsea, have a constraint related to environmental impact to the biotas live around when it becomes an object of exploitation. Organic Rankine Cycle (ORC) is a method of exploiting heat energy to become electricity using organic fluid. This paper presents a model of exploitation technology of hydrothermal vent using ORC method. With conservative calculation, it can give result of 15 MWe by exploiting a middle range diameter of hydrothermal vent in deep of 2000 meters below sea level. The technology provided here really has small impact to the environment. With an output energy as huge as mentioned before, the price of constructing this technology is low considering the empty of cost for drilling as what it should be in conventional exploitation. This paper also presents the comparison in several equipment which is more suitable to be installed over subsea.

  1. Hydrothermal precipitation of artificial violarite

    DEFF Research Database (Denmark)

    Jørgensen, W. H.; Toftlund, H.; Warner, T. E.

    2012-01-01

    The nonstoichiometric nickel-ore mineral, violarite, (Ni,Fe)3S4 was prepared as a phase-pure fine powder by a comparatively quick hydrothermal method from an aqueous solution of iron(II) acetate, nickel(II) acetate and DL-penicillamine in an autoclave at 130 °C for 45 h. Powder-XRD showed that th...

  2. HYDROTHERMAL CRACKING OF RESIDUAL OILS

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The hydrothermal cracking of heavy oils, such as Canadian oil sand bitumen and Arabian heavy vacuum residue, as well as their model compound were performed over sulfided Ni/Al2O3 and NiMo/Al2O3 catalysts under 663~703 K and 6.0~8.0 MPa of hydrogen pressure in a batch autoclave reactor. According to the reaction mechanism of hydrothermal cracking, a small amount of free redical initiators, such as di-tert-peroxide, sulfur, etc., was added into the feed to generate free redicals at lower temperature, and obviously showed promotional effect on the conversion of hydrocarbons. The reaction mechanisms of hydrothermal cracking as well as the enhancing effect of initiators were studied by a probe reaction with 1-phenyldodecane as a model compound. The hydrothermal cracking of hydrocarbon proceeded via free redical mechanism and hydrogenating quench. The initiators might easily generate free redicals under reaction temperature, these redicals might abstract H from hydrocarbon molecule and reasonably initiate the chain reactions, therefore, promote the conversion of hydrocarbon even at lower reaction temperature.

  3. Hydrothermal preparation and crystal habit of X-zeolite powder

    Institute of Scientific and Technical Information of China (English)

    SHEN Shao-hua; ZHANG Shu-gen; WANG Da-wei; FANG Ke-ming

    2005-01-01

    The preparation of X-zeolite powder was investigatedin hydrothermal system, the crystal growth process of X-zeolite in hydrothermal condition was characterized by means of X-ray diffraction, scanning electron microscope and infrared ray. The results show that X-zeolite powder with uniform granularity and intact crystal shape can be obtained in hydrothermal system of acid-treated stellerite-NaOH-NaAl(OH)4-H2O; the crystallite size is in the range of 2 - 3μm. The best reaction time of hydrothermal preparation is 6 h. The formation phases of X-zeolite crystal are as follows: dissolution of feedstocks → formation of [SiO4]4- and [AlO4]5- tetrahedron, many-membered ring,β cage → formation of crystal nucleus and nano-particle → aggregation growth of nano-particle → coalescence growth of crystallite. The crystal habits of X-zeolite are intimately related with crystallization orientation ofβ cage in crystal and with its coupling stability on every crystal face family.

  4. Coal char fragmentation during pulverized coal combustion

    Energy Technology Data Exchange (ETDEWEB)

    Baxter, L.L.

    1995-07-01

    A series of investigations of coal and char fragmentation during pulverized coal combustion is reported for a suite of coals ranging in rank from lignite to low-volatile (lv) bituminous coal under combustion conditions similar to those found in commercial-scale boilers. Experimental measurements are described that utilize identical particle sizing characteristics to determine initial and final size distributions. Mechanistic interpretation of the data suggest that coal fragmentation is an insignificant event and that char fragmentation is controlled by char structure. Chars forming cenospheres fragment more extensively than solid chars. Among the chars that fragment, large particles produce more fine material than small particles. In all cases, coal and char fragmentation are seen to be sufficiently minor as to be relatively insignificant factors influencing fly ash size distribution, particle loading, and char burnout.

  5. Upgraded Coal Interest Group

    Energy Technology Data Exchange (ETDEWEB)

    Evan Hughes

    2009-01-08

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  6. International perspectives on coal preparation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  7. Underground Coal Thermal Treatment: Task 6 Topical Report, Utah Clean Coal Program

    Energy Technology Data Exchange (ETDEWEB)

    Smith, P.J.; Deo, M.; Edding, E.G.; Hradisky, M.; Kelly, K.E.; Krumm, R.; Sarofim, Adel; Wang, D.

    2014-08-15

    The long-term objective of this task is to develop a transformational energy production technology by in- situ thermal treatment of a coal seam for the production of substitute natural gas and/or liquid transportation fuels while leaving much of the coal’s carbon in the ground. This process converts coal to a high-efficiency, low-greenhouse gas (GHG) emitting fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This task focused on three areas: Experimental. The Underground Coal Thermal Treatment (UCTT) team focused on experiments at two scales, bench-top and slightly larger, to develop data to understand the feasibility of a UCTT process as well as to develop validation/uncertainty quantification (V/UQ) data for the simulation team. Simulation. The investigators completed development of High Performance Computing (HPC) simulations of UCTT. This built on our simulation developments over the course of the task and included the application of Computational Fluid Dynamics (CFD)- based tools to perform HPC simulations of a realistically sized domain representative of an actual coal field located in Utah. CO2 storage. In order to help determine the amount of CO2 that can be sequestered in a coal formation that has undergone UCTT, adsorption isotherms were performed on coals treated to 325, 450, and 600°C with slow heating rates. Raw material was sourced from the Sufco (Utah), Carlinville (Illinois), and North Antelope (Wyoming) mines. The study indicated that adsorptive capacity for the coals increased with treatment temperature and that coals treated to 325°C showed less or similar capacity to the untreated coals.

  8. Coal Combustion Science

    Energy Technology Data Exchange (ETDEWEB)

    Hardesty, D.R. (ed.); Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. (Sandia National Labs., Livermore, CA (United States))

    1991-08-01

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

  9. The prospects of hard and brown coal in Poland and in the European Union

    Energy Technology Data Exchange (ETDEWEB)

    Gawlik, Lidia; Majchrzak, Henryk; Mokrzycki, Eugeniusz; Uliasz-Bochenczyk, Alicja

    2010-09-15

    Poland possess significant reserves of hard and brown coal and is an important producer of these fuels, for that reason coal has a dominant position in Polish energy balance. The government document describing energy policy of Poland up to the year 2030 treats Polish coal as an stabilizer of national energy safety. The progress in clean coal technologies development is a key element to determine the role of Polish coal both in Polish and EU economy. The possibilities of prospective use of coal pointing at the main direction of clean technology development has also been discussed in the paper.

  10. Hydrothermal commercialization baseline for state of Wyoming

    Energy Technology Data Exchange (ETDEWEB)

    Hanny, J.A.; Lunis, B.C. [eds.

    1979-06-01

    Wyoming does have numerous hot springs; but there has been little development effort in geothermal energy, since the state's primary interests are in coal, gas and oil. The hot springs of Thermopolis are among the largest in the world. Recent data from the central portion of the state indicate the potential for electric power generation from geothermal energy. Oil and gas wells (about 70,000) have been drilled in the state and some have geothermal waters that can be utilized for direct applications. The Madison Aquifer extends into the northeastern quadrant of the state and offers considerable potential for geothermal energy. Leasing activity is very limited. Geothermal legislation is basically non-existent, but the State Engineer has the responsibility for protecting the thermal springs. This handbook provides a synopsis of various aspects of the geothermal program in Wyoming. The section on Basic State Data (Section 2) lists government personnel (both legislative and executive branches) who are most directly involved with geothermal development. Some basic demographic data are also included. The various hydrothermal resources and the pertinent geology are summarized in Section 3. Activities (ranging from leases to operational systems) that lead to commercialization are described in Section 4. Plans for various developments are summarized in Section 5, while government assistance to Wyoming projects is list4ed in Section 6. The section on energy use patterns (Section 7) summarizes existing energy use and identifies counties and industries likely to be impacted most by geothermal energy. The section on leasing and permitting policies (Section 8) deals with legal and institutional considerations and includes a time table of institutional procedures for a typical resource to show the interrelationships among various organizations involved in development and regulation of the resource.

  11. Coal fires in China

    Institute of Scientific and Technical Information of China (English)

    CHE Yao(车遥); HUANG Wen-hui(黄文辉); ZHANG Ai-yun(张爱云)

    2004-01-01

    Coal fires have a very long history in China; the oldest coal fires have being burning for many million years. Up to now more than 56 coal fires spots were distinguished. They mainly locate in West-North of China, North of China and East-North of China. About millions of tons of coal have been burned in fires every year. Xinjiang Autonomy is the most serious region in coal fires as it has 38 coal fires spots and about 6.85 million tons of coal was burned every year. Coal fires in China ignited by wildfires, spontaneous combustion and human being during mining activities. These fires have released about 0.9 million tons of gasses (including CO, CO2, SO2, NO2 CH4, CO2, H2S etc.) into the atmosphere every year, most of which are brought to the east by wind and resulting more heavier air pollution in northern China.

  12. Continuous coal processing method

    Science.gov (United States)

    Ryason, P. R.

    1980-06-01

    A coal pump is provided in which solid coal is heated in the barrel of an extruder under pressure to a temperature at which the coal assumes plastic properties. The coal is continuously extruded, without static zones, using, for example, screw extrusion preferably without venting through a reduced diameter die to form a dispersed spray. As a result, the dispersed coal may be continuously injected into vessels or combustors at any pressure up to the maximum pressure developed in the extrusion device. The coal may be premixed with other materials such as desulfurization aids or reducible metal ores so that reactions occur, during or after conversion to its plastic state. Alternatively, the coal may be processed and caused to react after extrusion, through the die, with, for example, liquid oxidizers, whereby a coal reactor is provided.

  13. Nitrogen in Chinese coals

    Science.gov (United States)

    Wu, D.; Lei, J.; Zheng, B.; Tang, X.; Wang, M.; Hu, Jiawen; Li, S.; Wang, B.; Finkelman, R.B.

    2011-01-01

    Three hundred and six coal samples were taken from main coal mines of twenty-six provinces, autonomous regions, and municipalities in China, according to the resource distribution and coal-forming periods as well as the coal ranks and coal yields. Nitrogen was determined by using the Kjeldahl method at U. S. Geological Survey (USGS), which exhibit a normal frequency distribution. The nitrogen contents of over 90% Chinese coal vary from 0.52% to 1.41% and the average nitrogen content is recommended to be 0.98%. Nitrogen in coal exists primarily in organic form. There is a slight positive relationship between nitrogen content and coal ranking. ?? 2011 Science Press, Institute of Geochemistry, CAS and Springer Berlin Heidelberg.

  14. Coal worker's pneumoconiosis

    Science.gov (United States)

    ... this page: //medlineplus.gov/ency/article/000130.htm Coal worker's pneumoconiosis To use the sharing features on this page, please enable JavaScript. Coal worker's pneumoconiosis is a lung disease that results ...

  15. Fluidized coal combustion

    Science.gov (United States)

    Moynihan, P. I.; Young, D. L.

    1979-01-01

    Fluidized-bed coal combustion process, in which pulverized coal and limestone are burned in presence of forced air, may lead to efficient, reliable boilers with low sulfur dioxide and nitrogen dioxide emissions.

  16. TENORM: Coal Combustion Residuals

    Science.gov (United States)

    Burning coal in boilers to create steam for power generation and industrial applications produces a number of combustion residuals. Naturally radioactive materials that were in the coal mostly end up in fly ash, bottom ash and boiler slag.

  17. Chemicals from coal

    Energy Technology Data Exchange (ETDEWEB)

    Harold A. Wittcoff; Bryan G. Reuben; Jeffrey S. Plotkin

    2004-12-01

    This chapter contains sections titled: Chemicals from Coke Oven Distillate; The Fischer-Tropsch Reaction; Coal Hydrogenation; Substitute Natural Gas (SNG); Synthesis Gas Technology; Calcium Carbide; Coal and the Environment; and Notes and References

  18. Coal Extraction - Environmental Prediction

    Science.gov (United States)

    Cecil, C. Blaine; Tewalt, Susan J.

    2002-01-01

    Coal from the Appalachian region has supplied energy to the Nation for more than 200 years. Appalachian coal fueled America through a civil war and helped win two world wars. Appalachian coal has also provided fuel for keeping America warm in the winter and cool in the summer and has served as the basis for the steel, automobile, organic chemicals, chlorine, and aluminum industries. These benefits have not come without environmental costs, however. Coal extraction and utilization have had significant environmental impacts.

  19. Effect of Na2O/SiO2 mole ratio on the crystal type of zeolite synthesized from coal fly ash

    Directory of Open Access Journals (Sweden)

    PREDRAG LAZIC

    2003-06-01

    Full Text Available Coal fly ash was modified to zeolitic materials by hydrothermal treatment at 90ºC. The zeolite synthesis was studied as a function of the mole ratio of Na2O/SiO2 in the reaction mixtures. The results showed that NaP1 zeolite is obtained when the Na2O/SiO2 mole ratio was 0.7. Hydroxysodalite is the dominant zeolite phase in modified fly ash treated with a higher Na2O concentration solution (Na2O/SiO2 = 1.3. The IR and XRD methods were used to determine the phases present in the starting sample and in the zeolitic materials.

  20. In Situ Synthesis of NaY Zeolite with Coal-Based Kaolin

    Institute of Scientific and Technical Information of China (English)

    Xinmei Liu; Zifeng Yan; Huaiping Wang; Yantuo Luo

    2003-01-01

    NaY zeolites were in-situ synthesized from coal-based kaolin via the hydrothermal method.The effects of various factors on the structure of the samples were extensively investigated. The sampleswere characterized by N2 adsorption, XRD, IR and DTG-DTA methods, and the results show that thecrystallization temperature and amount of added water play an important role in the formation of the zeo-lite structure. The 4A and P zeolites are the competitive phase present in the resulting product. However,NaY zeolites with a higher relative crystallinity, excluding impure crystals and the well hydrothermal sta-bility, can be synthesized from coal-based kaolin. These zeolites possess a larger surface area and a narrowpore size distribution, and this means that optimization of this process might result in a commercial routeto synthesize NaY zeolites from coal-based kaolin.

  1. Tuning optical properties of poly(3-hexylthiophene) nanoparticles through hydrothermal processing

    Science.gov (United States)

    Lee, Seok Ho; Lee, Yong Baek; Park, Dong Hyuk; Kim, Mi Suk; Hei Cho, Eun; Joo, Jinsoo

    2011-03-01

    Poly(3-hexylthiophene) (P3HT) nanoparticles (NPs) were prepared by a reprecipitation method. Hydrothermal processing applied external pressure to the pristine P3HT NPs at temperatures ranging from 60 to 150 °C. Optical absorption and photoluminescence (PL) spectra for the hydrothermally treated P3HT NPs varied markedly with the processing temperature. With increasing treatment temperature, the absorption peak broadened and the peak position shifted from 510 to 623 nm; moreover, the intensity ratio of the 0-1 to 0-0 emission varied. These changes were caused by interactions between the P3HT main chains and alkyl side groups and conformational modifications induced by the high pressure during the hydrothermal process. The evolution of the optical absorption spectra of the P3HT NPs during the hydrothermal processing was strongly correlated with the variation of PL excitation spectra and with the PL emission spectra of a single NP.

  2. Zinc stannate nanostructures: hydrothermal synthesis

    Directory of Open Access Journals (Sweden)

    Sunandan Baruah and Joydeep Dutta

    2011-01-01

    Full Text Available Nanostructured binary semiconducting metal oxides have received much attention in the last decade owing to their unique properties rendering them suitable for a wide range of applications. In the quest to further improve the physical and chemical properties, an interest in ternary complex oxides has become noticeable in recent times. Zinc stannate or zinc tin oxide (ZTO is a class of ternary oxides that are known for their stable properties under extreme conditions, higher electron mobility compared to its binary counterparts and other interesting optical properties. The material is thus ideal for applications from solar cells and sensors to photocatalysts. Among the different methods of synthesizing ZTO nanostructures, the hydrothermal method is an attractive green process that is carried out at low temperatures. In this review, we summarize the conditions leading to the growth of different ZTO nanostructures using the hydrothermal method and delve into a few of its applications reported in the literature.

  3. Biological upgrading of coal liquids. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-02-01

    A large number of bacterial enrichments have been developed for their ability to utilize nitrogen and sulfur in coal liquids and the model compound naphtha. These bacteria include the original aerobic bacteria isolated from natural sources which utilize heteroatom compounds in the presence of rich media, aerobic nitrogen-utilizing bacteria and denitrifying bacteria. The most promising isolates include Mix M, a mixture of aerobic bacteria; ER15, a pyridine-utilizing isolate; ERI6, an aniline-utilizing isolate and a sewage sludge isolate. Culture optimization experiments have led to these bacteria being able to remove up to 40 percent of the sulfur and nitrogen in naphtha and coal liquids in batch culture. Continuous culture experiments showed that the coal liquid is too toxic to the bacteria to be fed without dilution or extraction. Thus either semi-batch operation must be employed with continuous gas sparging into a batch of liquid, or acid extracted coal liquid must be employed in continuous reactor studies with continuous liquid flow. Isolate EN-1, a chemical waste isolate, removed 27 percent of the sulfur and 19 percent of the nitrogen in fed batch experiments. Isolate ERI5 removed 28 percent of the nitrogen in coal liquid in 10 days in fed batch culture. The sewage sludge isolate removed 22.5 percent of the sulfur and 6.5 percent of the nitrogen from extracted coal liquid in continuous culture, and Mix M removed 17.5 percent of the nitrogen from medium containing extracted coal liquid. An economic evaluation has been prepared for the removal of nitrogen heteroatom compounds from Wilsonville coal liquid using acid extraction followed by fermentation. Similar technology can be developed for sulfur removal. The evaluation indicates that the nitrogen heteroatom compounds can be removed for $0.09/lb of coal liquid treated.

  4. Considerations on coal gasification

    Science.gov (United States)

    Franzen, J. E.

    1978-01-01

    Commercial processes for the gasification of coal with oxygen are discussed. The Koppers-Totzek process for the gasification of coal dust entrained in a stream of gasifying agents is described in particular detail. The outlook for future applications of coal gasification is presented.

  5. Prediction of coal hydrophobicity

    Energy Technology Data Exchange (ETDEWEB)

    Labuschagne, B.C.J. [Council for Scientific and Industrial Research, Pretoria (South Africa). Div. of Energy Technology; Wheelock, T.D.; Guo, R.K.; David, H.T. [Iowa State Univ. of Science and Technology, Ames, IA (United States); Markuszewski, R. [Ames Lab., IA (United States)

    1988-12-31

    Many coals exhibit a certain degree of native hydrophobicity. The more hydrophobic coals (the higher-rank coals) are easily beneficiated by froth flotation or oil agglomeration, while the more hydrophilic coals (the lower-rank coals) are floated or agglomerated with difficulty. Coals of different ranks and often even of the same rank sometimes differ greatly in hydrophobicity as measured by contact angle or natural floatability. Although the degree of hydrophobicity of a coal is related to its rank and has been correlated with other surface properties of the coal , the known information is still not sufficient to allow a good estimation to be made of the hydrophobicity of a given coal and does not explain the variation of coal hydrophobicity as a function of rank. A statistical analysis of previously published data, as well as newly acquired data, shows that coal hydrophobicity correlates better with moisture content than with carbon content, and better with the moisture/carbon molar ratio than with the hydrogen/carbon or oxygen/carbon atomic ratios. These findings indicate that there is a strong association between hydrophobicity and coal moisture content.

  6. Coal production 1989

    Energy Technology Data Exchange (ETDEWEB)

    1990-11-29

    Coal Production 1989 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, reserves, and stocks to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. 7 figs., 43 tabs.

  7. Is a renaissance of coal imminent?--challenges for catalysis.

    Science.gov (United States)

    Traa, Yvonne

    2010-04-07

    In the introduction, the reserves and resources of coal and other fossil fuels are discussed, also with regard to the regional distribution and consumption. Then, coalification and the classification of coal are described. The main part of the article is devoted to the most important processes using coal where challenges for catalysis still exist, with a focus on recent literature. First, technologies based on the production of synthesis gas, i.e., Fischer-Tropsch synthesis as well as MTO/MTP (Methanol To Olefins/Methanol To Propylene), are discussed. Secondly, direct coal liquefaction is treated. The last part of the article is devoted to "clean" coal and gives an outlook on the future of coal.

  8. Plasma-supported coal combustion in boiler furnace

    Energy Technology Data Exchange (ETDEWEB)

    Askarova, A.S.; Karpenko, E.I.; Lavrishcheva, Y.I.; Messerle, V.E.; Ustimenko, A.B. [Kazakh National University, Alma Ata (Kazakhstan). Dept. of Physics

    2007-12-15

    Plasma activation promotes more effective and environmentally friendly low-rank coal combustion. This paper presents Plasma Fuel Systems that increase the burning efficiency of coal. The systems were tested for fuel oil-free start-up of coal-fired boilers and stabilization of a pulverized-coal flame in power-generating boilers equipped with different types of burners, and burning all types of power-generating coal. Also, numerical modeling results of a plasma thermochemical preparation of pulverized coal for ignition and combustion in the furnace of a utility boiler are discussed in this paper. Two kinetic mathematical models were used in the investigation of the processes of air/fuel mixture plasma activation: ignition and combustion. A I-D kinetic code PLASMA-COAL calculates the concentrations of species, temperatures, and velocities of the treated coal/air mixture in a burner incorporating a plasma source. The I-D simulation results are initial data for the 3-D-modeling of power boiler furnaces by the code FLOREAN. A comprehensive image of plasma-activated coal combustion processes in a furnace of a pulverized-coal-fired boiler was obtained. The advantages of the plasma technology are clearly demonstrated.

  9. The economics of coal

    Energy Technology Data Exchange (ETDEWEB)

    1981-01-01

    Global aspects of the production, consumption and trade in coal are described. World reserves and resources, production (both by region and country), international trade (exporters and importers), coal consumption (by region and sector), and the demand for primary energy (1960-1979). Each of the producing and consuming countries are discussed individually. The electricity sector and its future demand for coal, and the future demand for coking coal are covered. Prices for metallurgical and steam coal are also given. Statistics are presented in tables.

  10. Radionuclides in US coals

    Energy Technology Data Exchange (ETDEWEB)

    Bisselle, C. A.; Brown, R. D.

    1984-03-01

    The current state of knowledge with respect to radionuclide concentrations in US coals is discussed. Emphasis is placed on the levels of uranium in coal (and lignite) which are considered to represent a concern resulting from coal combustion; areas of the US where such levels have been found; and possible origins of high radionuclide levels in coal. The report reviews relevant studies and presents new data derived from a computerized search of radionuclide content in about 4000 coal samples collected throughout the coterminous US. 103 references, 5 figures, 5 tables.

  11. Steam pretreatment for coal liquefaction

    Science.gov (United States)

    Ivanenko, Olga

    The objectives of this work are to test the application of steam pretreatment to direct coal liquefaction, to investigate the reaction of model compounds with water, and to explore the use of zeolites in these processes. Previous work demonstrated the effectiveness of steam pretreatment in a subsequent flash pyrolysis. Apparently, subcritical steam ruptures nearly all of the ether cross links, leaving a partially depolymerized structure. It was postulated that very rapid heating of the pretreated coal to liquefaction conditions would be required to preserve the effects of such treatment. Accordingly, a method was adopted in which coal slurry is injected into a hot autoclave containing solvent. Since oxygen is capable of destroying the pretreatment effect, precautions were taken for its rigorous exclusion. Tests were conducted with Illinois No. 6 coal steam treated at 340sp°C, 750 psia for 15 minutes. Both raw and pretreated samples were liquified in deoxygenated tetralin at high severity (400sp°C, 30 min.) and low severity (a: 350sp°C, 30 min., and b: 385sp°C, 15 min.) conditions under 1500 psia hydrogen. Substantial improvement in liquid product quality was obtained and the need for rapid heating and oxygen exclusion demonstrated. Under low severity conditions, the oil yield was more than doubled, going from 12.5 to 29 wt%. Also chemistry of the pretreatment process was studied using aromatic ethers as model compounds. alpha-Benzylnaphthyl ether (alpha-BNE), alpha-naphthylmethyl phenyl (alpha-NMPE), and 9-phenoxyphenanthrene were exposed to steam and inert gas at pretreatment conditions and in some cases to liquid water at 315sp°C. alpha-BNE and alpha-NMPE showed little difference in conversion in inert gas and in steam. Hence, these compounds are poor models for coal in steam pretreatment. Thermally stable 9-phenoxyphenanthrene, however, was completely converted in one hour by liquid water at 315sp°C. At pretreatment conditions mostly rearranged starting

  12. Sustainable carbon materials from hydrothermal processes

    CERN Document Server

    Titirici, Maria-Magdalena

    2013-01-01

    The production of low cost and environmentally friendly high performing carbon materials is crucial for a sustainable future. Sustainable Carbon Materials from Hydrothermal Processes describes a sustainable and alternative technique to produce carbon from biomass in water at low temperatures, a process known as Hydrothermal Carbonization (HTC). Sustainable Carbon Materials from Hydrothermal Processes presents an overview of this new and rapidly developing field, discussing various synthetic approaches, characterization of the final products, and modern fields of application fo

  13. Chemical coal conversion yesterday, today, and tomorrow; Der Chemierohstoff Kohle: gestern, heute und morgen

    Energy Technology Data Exchange (ETDEWEB)

    Talbiersky, J. [UCP Chemicals AG, Wien (Austria)

    2007-01-15

    Shortage in mineral oil and gas as well as a high price level have caused a renaissance in coal conversion technologies, at the end of the 70's. Today we have a similar situation. Now coal coversion technologies will be in the focus again but hopefully as a longterm strategy. The most important coal conversion technologies as liquefaction, gasification, coking and calcium carbide synthesis are discussed regarding their use for the production of chemicals. The most important source for aromatic chemicals from coal is till now coal tar with an availability of 22 Mio. t/a. The manufacturing of coal tar is discussed as an example for making aromatic products from a complex feed stock that you get by the fixed bed gasification, coal liquefaction and coking. Also the special marketing strategy that is necessary to be competitive against products from the petroindustry. It can be expected, that coal gasification as a source for synthesis gas will become more and more important. Synthesis gas is the access to aliphatic hydrocarbons by Fischer Tropsch synthesis and to methanol, a chemical with a high synthetic potential. Also the new hydrothermal carbonization of biomass to synthetic coal is mentioned. (orig.)

  14. The CIS coal summit

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The presentations (overhead/viewgraphs) include: the impacts of EU environmental legislation on Russian coal market (A. Sankovski); how Caterpillar and Cat dealers create value in the global mining industry (D. Mohr); new coal preparation technology and application in the Russian coal market (D. Morris); UK demand outlook and import growth (G. Parker); new technologies in blasting operations and services (J. Petzold and others); a global bank's view of the coal sector (M. Seleznev); ELGA coal deposit, Republic of Sakha (Yakutia), Russia (M. Tsikanov); Russia's economic outlook (P. Forrest); Renaissance Capital (investment bank) (R. Edwards); Russian coal for Korean gencos (S. Kim); and coking coal in Ukraine (V. Khilko).

  15. Influence of high-energy impact on the physical and technical characteristics of coal fuels

    Science.gov (United States)

    Mal'tsev, L. I.; Belogurova, T. P.; Kravchenko, I. V.

    2017-08-01

    Currently, in the world's large-scale coal-fired power industry, the combustion of pulverized coal is the most widely spread technology of combusting the coals. In recent years, the micropulverization technology for preparation and combustion of the coal has been developed in this field. As applied to the small-scale power industry, the method of combusting the coal in the form of a coal-water slurry has been explored for years. Fine coal powders are produced and used in the pulverized-coal gasification. Therefore, the coal preparation methods that involve high-dispersion disintegration of coals attract the greatest interest. The article deals with the problems of high-energy impact on the coal during the preparation of pulverized-coal fuels and coal-water slurries, in particular, during the milling of the coal in ball drum mills and the subsequent regrinding in disintegrators or the cavitation treatment of the coal-water slurries. The investigations were conducted using samples of anthracite and lignite from Belovskii open-pit mine (Kuznetsk Basin). It is shown that both the disintegration and the cavitation treatment are efficient methods for controlling the fuel characteristics. Both methods allow increasing the degree of dispersion of the coal. The content of the small-sized particles reground by cavitation considerably exceeds the similar figure obtained using the disintegrator. The specific surface area of the coal is increased by both cavitation and disintegration with the cavitation treatment producing a considerably greater effect. Being subjected to the cavitation treatment, most coal particles assume the form of a split characterized by the thermodynamically nonequilibrium state. Under external action, in particular, of temperature, the morphological structure of such pulverized materials changes faster and, consequently, the combustion of the treated coal should occur more efficiently. The obtained results are explained from the physical point of view.

  16. Geochemistry of arsenic and selenium in a Ge-poor coal from the Wulantuga coal-hosted Ge ore deposit, Inner Mongolia, North China

    Institute of Scientific and Technical Information of China (English)

    Panpan Xie; Qingqian Li; Jingjing Liu; Hongjian Song; Jianpeng Wei

    2014-01-01

    This paper reports new data for arsenic (As) and selenium (Se) in a total of twelve bench samples of Ge-rich and Ge-poor coals in the No. 6 coal seam from the Wulantuga ore deposit, Inner Mongolia, Northeastern China. The Ge-poor coals are characterized by low-ash (with a weighted average ash yield 10.59%). The coal samples were digested using an UltraClave microwave high pressure reactor (milestone) and trace elements were detected by inductively coupled plasma mass spectrometry—collision/reaction cell technology, a reliable method for As and Se determination in coal samples. The contents of As and Se in the Ge-poor (with a weighted average content of 9.14 and 0.30μg/g, respectively) and Ge-rich coal samples in the present study (varies from 16.88 to 17,776μg/g and from 0.26 to 14.39μg/g, respectively) are in a sharp contrast. The As in the Ge-poor coals is of both organic- and pyrite-associations, and its enrichment is attributed to the sediment source, and to a lesser extent, to hydrothermal fluids. Se is predominantly connected with organic matter in the Wulantuga Ge-poor coals.

  17. Studies of coal structure using carbene chemistry

    Energy Technology Data Exchange (ETDEWEB)

    1990-01-01

    The object of this grant was to react coal, derivatized forms of coal, and solvent swelled coal with carbenes (divalent carbon species) under mild conditions. These carbenes were to be prepared by treating the coal with several diazo compounds and then thermally decomposing them at relatively low temperatures (80--130{degree}C). The carbenes were to be chosen to show varying selectively toward aromatic rings containing heteroatom functionalities and toward polynuclear aromatic systems. In some instances, where selectivities toward aromatic and heteroaromatic ring systems were not known, model studies were to be carried out. Because of the generally mild conditions employed and the good selectivity anticipated, and actually observed with one particular system, it was expected that this methodology would provide structural information about the coal, along with data on the extent of occurrence and type of aromatic systems. After carbene reactions, treatment of the coal samples was to include extractions and thermolysis. Physical studies included thermogravimetric analysis, diffuse reflectance FT-IR spectroscopy, NMR ({sup 1}H and {sup 13}C) spectroscopy, gas chromatography, GC/MS and GC/FT-IR. 7 figs., 10 tabs.

  18. Hydrothermal conversion of chrysotile asbestos using near supercritical conditions

    Energy Technology Data Exchange (ETDEWEB)

    Anastasiadou, Kalliopi; Axiotis, Dimosthenis [Laboratory of Toxic and Hazardous Waste Management, Department of Environmental Engineering, Technical University of Crete, Chania, P.C. 73100 (Greece); Gidarakos, Evangelos, E-mail: gidarako@mred.tuc.gr [Laboratory of Toxic and Hazardous Waste Management, Department of Environmental Engineering, Technical University of Crete, Chania, P.C. 73100 (Greece)

    2010-07-15

    The present research investigates, develops and evaluates the transformation of chrysotile asbestos into a non-hazardous material, such as forsterite, using an economically viable and safe method. The aim of this study is to convert fibrous chrysotile asbestos into an anhydrous magnesium silicate with a non-hazardous lamellar morphology using supercritical steam. The treatment method is characterized as hydrothermal in a temperature and pressure range of 300-700 deg. C and 1.75-5.80 MPa, respectively. Small amounts of asbestos (2.5 g) were treated in each experiment. Deionised water was used as the treatment solution. The treatment duration varied from approximately 1-5 h. Additional experiments took place using solutions of distilled water and small amounts of acetic acid, with the aim of attaining optimal treatment conditions. Crystal phases of the samples were determined by X-ray diffraction (XRD). The main phases present in the treated samples were forsterite, enstatite, and chrysotile asbestos. Lizardite and periclase were also found. The morphology of the treated chrysotile asbestos fibers was identified by scanning electron microscope (SEM). The fibrous form of chrysotile asbestos was converted into non-fibrous form of forsterite. In fact, none of the fibrous-needle-like morphology, with length equal to or greater than 5 {mu}m and diameter less than 3 {mu}m, which was responsible for the toxicity of the original material, was visible in the solid phase. The dissolution of magnesium from chrysotile asbestos was measured using volumetric determination by titration with EDTA. Leaching of magnesium into the liquid phase was observed. Clearly, the highest concentrations of dissolved magnesium are observed after hydrothermal treatment of chrysotile asbestos using acetic acid 1% (8.4-14.6%). Lowest concentrations of dissolved magnesium are obtained after hydrothermal treatment of chrysotile asbestos without using additives. Observing the results of the hydrothermal

  19. Hydrothermal conversion of chrysotile asbestos using near supercritical conditions.

    Science.gov (United States)

    Anastasiadou, Kalliopi; Axiotis, Dimosthenis; Gidarakos, Evangelos

    2010-07-15

    The present research investigates, develops and evaluates the transformation of chrysotile asbestos into a non-hazardous material, such as forsterite, using an economically viable and safe method. The aim of this study is to convert fibrous chrysotile asbestos into an anhydrous magnesium silicate with a non-hazardous lamellar morphology using supercritical steam. The treatment method is characterized as hydrothermal in a temperature and pressure range of 300-700 degrees C and 1.75-5.80 MPa, respectively. Small amounts of asbestos (2.5 g) were treated in each experiment. Deionised water was used as the treatment solution. The treatment duration varied from approximately 1-5 h. Additional experiments took place using solutions of distilled water and small amounts of acetic acid, with the aim of attaining optimal treatment conditions. Crystal phases of the samples were determined by X-ray diffraction (XRD). The main phases present in the treated samples were forsterite, enstatite, and chrysotile asbestos. Lizardite and periclase were also found. The morphology of the treated chrysotile asbestos fibers was identified by scanning electron microscope (SEM). The fibrous form of chrysotile asbestos was converted into non-fibrous form of forsterite. In fact, none of the fibrous-needle-like morphology, with length equal to or greater than 5 microm and diameter less than 3 microm, which was responsible for the toxicity of the original material, was visible in the solid phase. The dissolution of magnesium from chrysotile asbestos was measured using volumetric determination by titration with EDTA. Leaching of magnesium into the liquid phase was observed. Clearly, the highest concentrations of dissolved magnesium are observed after hydrothermal treatment of chrysotile asbestos using acetic acid 1% (8.4-14.6%). Lowest concentrations of dissolved magnesium are obtained after hydrothermal treatment of chrysotile asbestos without using additives. Observing the results of the

  20. Correlation between coal characteristics and methane adsorption on China's coals

    Institute of Scientific and Technical Information of China (English)

    YU Hong-guan; YUAN Jian; SONG Ji-yong; LENG Shu-wei

    2007-01-01

    It is highly important to investigate relationship between coal characteristics and methane adsorption on coal in the fields of coalbed methane recovery. Based on data examination of coal quality indexes collected from the literatures, regression equations for Langmuir adsorption constants, VL or VL/PL, and coal quality indexes for selected coal samples were developed with multiple linear regression of SPSS software according to the degree of coal metamorphosis. The regression equations built were tested with data collected from some literatures, and the influences of coal quality indexes on CH4 adsorption on coals were studied with investigation of regression equations, and the reasons of low accuracy to Langmuir constants calculated with regression equation for a few coal samples were investigated. The results show that the regression equations can be employed to predict Langmuir constants for methane adsorption isotherms on coals obtained using volumetric gas adsorption experiments, which are conducted at 30 ℃ on a wet or dried coal samples with less than 30% ash content in coal. The influence of same coal quality index with various coal rank or influence of various coal quality indexes for same coal rank on CH4 adsorption is not consistent. The regression equations have different accuracy to different coal rank, in which the VL equations supply better prediction accuracy for anthracite and higher prediction error for lower metamorphosis coal, and the PL prediction error with VL and VL/PL equations is lower to bituminous coal and higher to anthracite.

  1. Anaerobic digestion of yard waste with hydrothermal pretreatment.

    Science.gov (United States)

    Li, Wangliang; Zhang, Guangyi; Zhang, Zhikai; Xu, Guangwen

    2014-03-01

    The digestibility of lignocellulosic biomass is limited by its high content of refractory components. The objective of this study is to investigate hydrothermal pretreatment and its effects on anaerobic digestion of sorted organic waste with submerged fermentation. Hydrothermal pretreatment (HT) was performed prior to anaerobic digestion, and three agents were examined for the HT: hot compressed water, alkaline solution, and acidic solution. The concentrations of glucose and xylose were the highest in the sample pretreated in acidic solution. Compared with that of the untreated sample, the biogas yields from digesting the samples pretreated in alkaline solution, acidic solution, and hot water increased by 364, 107, and 79%, respectively. The decrease of chemical oxygen demand (COD) in liquid phase followed the same order as for the biogas yield. The initial ammonia content of the treated samples followed the order sample treated in acidic solution > sample treated in alkaline solution > sample treated in hot water. The concentrations of volatile fatty acids (VFAs) were low, indicating that the anaerobic digestion process was running at continuously stable conditions.

  2. SURFACE-MODIFIED COALS FOR ENHANCED CATALYST DISPERSION AND LIQUEFACTION

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Yaw D. Yeboah

    1999-09-01

    This is the final report of the Department of Energy Sponsored project DE-FGF22-95PC95229 entitled, surface modified coals for enhanced catalyst dispersion and liquefaction. The aims of the study were to enhance catalyst loading and dispersion in coal for improved liquefaction by preadsorption of surfactants and catalysts on the coal and to train and educate minority scientists in catalysts and separation science. Illinois No. 6 Coal (DEC-24) was selected for the study. The surfactants investigated included dodecyl dimethyl ethyl ammonium bromide (DDAB), a cationic surfactant, sodium dodecyl sulfate, an anionic surfactant, and Triton x-100, a neutral surfactant. Ammonium molybdate tetrahydrate was used as the molybdenum catalyst precursor. Zeta potential, BET, FTIR, AFM, UV-Vis and luminescence intensity measurements were undertaken to assess the surface properties and the liquefaction activities of the coal. The parent coal had a net negative surface charge over the pH range 2-12. However, in the presence of DDAB the negativity of the surface charge decreased. At higher concentrations of DDAB, a positive surface charge resulted. In contrast to the effect of DDAB, the zeta potential of the coal became more negative than the parent coal in the presence of SDS. Adsorption of Triton reduced the net negative charge density of the coal samples. The measured surface area of the coal surface was about 30 m{sup 2}/g compared to 77m{sup 2}/g after being washed with deionized water. Addition of the surfactants decreased the surface area of the samples. Adsorption of the molybdenum catalyst increased the surface area of the coal sample. The adsorption of molybdenum on the coal was significantly promoted by preadsorption of DDAB and SDS. Molybdenum adsorption showed that, over a wide range of concentrations and pH values, the DDAB treated coal adsorbed a higher amount of molybdenum than the samples treated with SDS. The infrared spectroscopy (FTIR) and the atomic force

  3. SURFACE-MODIFIED COALS FOR ENHANCED CATALYST DISPERSION AND LIQUEFACTION

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Yaw D. Yeboah

    1999-09-01

    This is the final report of the Department of Energy Sponsored project DE-FGF22-95PC95229 entitled, surface modified coals for enhanced catalyst dispersion and liquefaction. The aims of the study were to enhance catalyst loading and dispersion in coal for improved liquefaction by preadsorption of surfactants and catalysts on the coal and to train and educate minority scientists in catalysts and separation science. Illinois No. 6 Coal (DEC-24) was selected for the study. The surfactants investigated included dodecyl dimethyl ethyl ammonium bromide (DDAB), a cationic surfactant, sodium dodecyl sulfate, an anionic surfactant, and Triton x-100, a neutral surfactant. Ammonium molybdate tetrahydrate was used as the molybdenum catalyst precursor. Zeta potential, BET, FTIR, AFM, UV-Vis and luminescence intensity measurements were undertaken to assess the surface properties and the liquefaction activities of the coal. The parent coal had a net negative surface charge over the pH range 2-12. However, in the presence of DDAB the negativity of the surface charge decreased. At higher concentrations of DDAB, a positive surface charge resulted. In contrast to the effect of DDAB, the zeta potential of the coal became more negative than the parent coal in the presence of SDS. Adsorption of Triton reduced the net negative charge density of the coal samples. The measured surface area of the coal surface was about 30 m{sup 2}/g compared to 77m{sup 2}/g after being washed with deionized water. Addition of the surfactants decreased the surface area of the samples. Adsorption of the molybdenum catalyst increased the surface area of the coal sample. The adsorption of molybdenum on the coal was significantly promoted by preadsorption of DDAB and SDS. Molybdenum adsorption showed that, over a wide range of concentrations and pH values, the DDAB treated coal adsorbed a higher amount of molybdenum than the samples treated with SDS. The infrared spectroscopy (FTIR) and the atomic force

  4. Changes in brown coal structure caused by coal-solubilizing microorganisms

    Energy Technology Data Exchange (ETDEWEB)

    Schmiers, H.; Koepsel, R.; Weber, A.; Winkelhoefer, M.; Grosse, S. [Technische Univ. Bergakademie Freiberg (Germany). Inst. fuer Energieverfahrenstechnik und Chemieingenieurwesen

    1997-12-31

    The phenomenon of coal solubilization caused by microorganisms has been explained by various mechanisms: extraction of non-covalently bonded polar components of the coal substance by biogenic agents (chelating agents, alkaline substances) and enzyme-catalyzed cleavage of covalent bonds by extracellular enzyme systems. For this it is assumed that bond cleavage occurs on the aliphatic carbon (methylene groups, aliphatic bridges or on ester groups). As the coal has usually been treated with oxidizing agents such as H{sub 2}O{sub 2} or HNO{sub 3} before bioconversion, there is a possibility that the result of bioconversion is overlaid with the effect of the chemical treatment. We therefore studied the structural changes in the organic coal substance during pre-oxidation with H{sub 2}O{sub 2}, treatment with MnP and conversion using the fungal strains of Trichoderma and Fusarium oxysporum. (orig.)

  5. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, M.; Davis, R.; Jones, S.

    2013-03-01

    This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

  6. Change in pore structure of coals by activation with KOH; KOH fukatsushita sekitan no saiko kozo

    Energy Technology Data Exchange (ETDEWEB)

    Maruyama, K.; Yoshizawa, N.; Ishikawa, E.; Kobayashi, M.; Toda, Y.; Yamada, Y.; Shiraishi, M. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    Three typical Japanese coals of non-coking coal, coking coal and anthracite were heat-treated with KOH, and change in their pore structure was examined by absorption of N2, X-ray diffraction and TEM observation. In addition, the relation between a coal rank and pore structure was also studied by absorption experiment of N2. In experiment, the mixture of coal and KOH in a nickel holder was heat-treated in N2 gas flow at heating rate of 2{degree}C/min, and held at a fixed temperature for one hour. To clarify the pore structure, N2 absorption isotherms were measured at -196{degree}C under nearly 76cmHg using a commercially available full-automatic absorption measurement equipment. Based on the X-ray diffraction and TEM observation results on activated coals, the relation between the N2 absorption and pore structure was studied. The results are summarized as follows: (1) The yield and absorption ability of coals increase with a coal rank, (2) The specific surface area of coals reaches its peak at 800{degree}C in activation temperature regardless of a coal rank, and (3) The activation behavior of coals is dependent on a coal rank. 5 refs., 7 figs., 1 tab.

  7. Coal, culture and community

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-11-01

    16 papers are presented with the following titles: the miners; municipalisation and the millenium - Bolton-upon-Dearne Urban District Council 1899-1914; the traditional working class community revisited; the cultural capital of coal mining communities; activities, strike-breakers and coal communities; the limits of protest - media coverage of the Orgreave picket during the miners` strike; in defence of home and hearth? Families, friendships and feminism in mining communities; young people`s attitudes to the police in mining communities; the determinants of productivity growth in the British coal mining industry, 1976-1989; strategic responses to flexibility - a case study in coal; no coal turned in Yorkshire?; the North-South divide in the Central Coalfields; the psychological effects of redundancy and worklessness - a case study from the coalfields; the Dearne Valley initiative; the future under labour: and coal, culture and the community.

  8. Beneficiated coals' char morphology

    Directory of Open Access Journals (Sweden)

    Diana Vargas

    2012-09-01

    Full Text Available This work evaluated the char morphology of beneficiated and original coal (without beneficiation from four Colombian coalmines: Cerrejón (La Guajira, La Jagua (Cesar, Guachinte (Valle del Cauca and Nechí (Antioquia. Column flotation was used to obtain beneficiated coal, whereas a drop tube reactor at 1,000°C, 104 °C/s heating rate and 100 ms residence time was used to obtain char. The chars were analysed by image analysis which determined their shape, size, porosity and wall thickness. It was found that char morphology depended on coal rank and maceral composition. Morphological characteristics like high porosity, thinner walls and network-like morphology which are beneficial in improving combustion were present in vitrinite- and liptinite-rich lowest-ranking coals. Beneficiated coals showed that their chars had better performance regarding their morphological characteristics than their original coal chars.

  9. Coal tar in dermatology

    Energy Technology Data Exchange (ETDEWEB)

    Roelofzen, J.H.J.; Aben, K.K.H.; Van Der Valk, P.G.M.; Van Houtum, J.L.M.; Van De Kerkhof, P.C.M.; Kiemeney, L.A.L.M. [Radboud University Nijmegen Medical Center, Nijmegen (Netherlands). Dept. of Dermatology

    2007-07-01

    Coal tar is one of the oldest treatments for psoriasis and eczema. It has anti-inflammatory, antibacterial, antipruritic and antimitotic effects. The short-term side effects are folliculitis, irritation and contact allergy. Coal tar contains carcinogens. The carcinogenicity of coal tar has been shown in animal studies and studies in occupational settings. There is no clear evidence of an increased risk of skin tumors or internal tumors. Until now, most studies have been fairly small and they did not investigate the risk of coal tar alone, but the risk of coal tar combined with other therapies. New, well-designed, epidemiological studies are necessary to assess the risk of skin tumors and other malignancies after dermatological use of coal tar.

  10. Coal: ditching the dirt

    Energy Technology Data Exchange (ETDEWEB)

    Russell, E.

    2006-01-01

    At the time when the British government is considering building new nuclear power plants, this article gives an overview of how the coal industry has been developing technologies to reduce greenhouse gas emissions and increase combustion efficiency which make coal a more attractive power source that should not be overlooked. Technologies mentioned include integrated gasification combined cycle, fluidized bed combustion, low NOx burners, and combustion control. Research is under way on capturing greenhouse gas emissions from fossil fuels. Use of fly ash in cement manufacture help reduce CO{sub 2} emissions. Clean coal technologies in the UK are supported by the IEA Clean Coal Centre, the World Coal Institute and the Coal Research Forum. 3 photos. 3 figs.

  11. Arthropod cuticles in coal

    Energy Technology Data Exchange (ETDEWEB)

    Bartram, K.M.; Jeram, A.J.; Selden, P.A.

    1987-05-01

    An abundance of scorpion cuticles from Westphalian (Upper Carboniferous) coals of Yorkshire is described, and other records of arthropod cuticles in coals are reviewed. The absence of cuticles assignable to arthropod groups other than scorpions is thought to be due to preferential preservation of the unique exocuticle of scorpions; it alone is preserved and appears to retain an organic nature. The cuticle is recovered from all the lithotypes of humic bituminous coals although it is most common in coals rich in inertinite macerals. From the present study it is uncertain whether the scorpions were aquatic or terrestrial. The recognition of arthropod cuticle as a coal maceral could aid environmental interpretations. The abundance of arthropod cuticle in the coals studied indicates its potential use in correlation and in determining the thermal maturity of sediments. 37 refs., 1 fig.

  12. Fungal degradation of coal as a pretreatment for methane production

    Science.gov (United States)

    Haider, Rizwan; Ghauri, Muhammad A.; SanFilipo, John R.; Jones, Elizabeth J.; Orem, William H.; Tatu, Calin A.; Akhtar, Kalsoom; Akhtar, Nasrin

    2013-01-01

    Coal conversion technologies can help in taking advantage of huge low rank coal reserves by converting those into alternative fuels like methane. In this regard, fungal degradation of coal can serve as a pretreatment step in order to make coal a suitable substrate for biological beneficiation. A fungal isolate MW1, identified as Penicillium chrysogenum on the basis of fungal ITS sequences, was isolated from a core sample of coal, taken from a well drilled by the US. Geological Survey in Montana, USA. The low rank coal samples, from major coal fields of Pakistan, were treated with MW1 for 7 days in the presence of 0.1% ammonium sulfate as nitrogen source and 0.1% glucose as a supplemental carbon source. Liquid extracts were analyzed through Excitation–Emission Matrix Spectroscopy (EEMS) to obtain qualitative estimates of solubilized coal; these analyses indicated the release of complex organic functionalities. In addition, GC–MS analysis of these extracts confirmed the presence of single ring aromatics, polyaromatic hydrocarbons (PAHs), aromatic nitrogen compounds and aliphatics. Subsequently, the released organics were subjected to a bioassay for the generation of methane which conferred the potential application of fungal degradation as pretreatment. Additionally, fungal-mediated degradation was also prospected for extracting some other chemical entities like humic acids from brown coals with high huminite content especially from Thar, the largest lignite reserve of Pakistan.

  13. Cooperative research program in coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, G.P. (ed.)

    1991-01-01

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  14. Cooperative research program in coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, G.P. (ed.)

    1992-01-01

    Research continues on coal liquefaction in the following areas: (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  15. Cooperative research program in coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, G.P. (ed.)

    1991-01-01

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  16. CLEANER ENERGY FROM COAL

    Directory of Open Access Journals (Sweden)

    Adina-MilenaTĂTAR

    2016-12-01

    Full Text Available With the ever-increasing demand for coal, particularly in the developing world, the use of low emission coal technologies becomes increasingly important if international targets on climate change are to be achieved. The two principal avenues for reducing carbon emissions from coal-fired power generation are through use of high efficiency, low emission power plantsand carbon capture, use and storage.

  17. Supercritical solvent coal extraction

    Science.gov (United States)

    Compton, L. E. (Inventor)

    1984-01-01

    Yields of soluble organic extract are increased up to about 50% by the supercritical extraction of particulate coal at a temperature below the polymerization temperature for coal extract fragments (450 C.) and a pressure from 500 psig to 5,000 psig by the conjoint use of a solvent mixture containing a low volatility, high critical temperature coal dissolution catalyst such as phenanthrene and a high volatility, low critical temperature solvent such as toluene.

  18. Fate of Organic Micropollutants during Hydrothermal Carbonization

    Science.gov (United States)

    Weiner, B.; Baskyr, I.; Pörschmann, J.; Kopinke, F.-D.

    2012-04-01

    The hydrothermal carbonization (HTC) is an exothermic process, in which biomass in an aqueous suspension is transformed into a bituminous coal-like material (hydrochar) at temperatures between 180-250°C and under moderate pressure. With these process conditions, little gas is generated (1-5%), and a fraction of the organic carbon is dissolved in the aqueous phase (10-30%) but the largest part is obtained as solid char. The respective yields and the molecular composition depend on the choice of educts and the process conditions, such as temperature, pH-value, and reaction time. Various biomass-educts have recently been studied, such as waste materials from agriculture, brewer's spent grains, sewage sludge, as well as wood and paper materials. Besides their use for energy generation, the hydrochars have also been investigated as soil amendments. Prior to addition of the chars to soil, these should be free of toxic components that could be released into the environment as harmful organic pollutants. Herein, the potential for the degradation of trace organic pollutants, such as pesticides and pharmaceuticals, under typical HTC conditions will be presented. The degradation of selected organic pollutants with different polarity and hydrophobicity was investigated. Scope and limitations of the degradation potential of the HTC are discussed on examples of micro pollutants such as hormones, residues of pharmaceuticals and personal care products including their metabolites, and pesticides. We will show that the target analytes are partially and in some cases completely degraded. The degree of degradation depends on the HTC process conditions such as reaction temperature and time, the solution pH value, the presence of catalysts or additional reagents. The biotic and abiotic degradation of chlorinated organic compounds, in particular chlorinated aromatics, has been a well-known environmental problem and remains a challenging issue for the development of a HTC process for

  19. Pyrolysis of Coal

    Directory of Open Access Journals (Sweden)

    Rađenović, A.

    2006-07-01

    Full Text Available The paper presents a review of relevant literature on coal pyrolysis.Pyrolysis, as a process technology, has received considerable attention from many researchers because it is an important intermediate stage in coal conversion.Reactions parameters as the temperature, pressure, coal particle size, heating rate, soak time, type of reactor, etc. determine the total carbon conversion and the transport of volatiles and therebythe product distribution. Part of the possible environmental pollutants could be removed by optimising the pyrolysis conditions. Therefore, this process will be subsequently interesting for coal utilization in the future

  20. Petrographers fingerprint coals

    Energy Technology Data Exchange (ETDEWEB)

    Pearson, D.E. [Pearson and Associates Ltd. (USA)

    2001-05-01

    A new system of coal fingerprinting called Digipet generates reflectance profiles by using an automated digital imaging system in which tens of millions of individual reflectance measurements are obtained. Images are conditioned to generate a detailed smooth histogram which convey information on the coal sample's provenance and history. Expert interpretation can reveal further information. The article gives details of the instrument and shows sample reflectance profiles. It discusses some applications in sampling coal charged to coke ovens of the Indiana Harbor Coke Co, and at a Midwest generating plant where it detected the presence of rogue high volatile coal. 3 figs.

  1. The NOXSO clean coal project

    Energy Technology Data Exchange (ETDEWEB)

    Black, J.B.; Woods, M.C.; Friedrich, J.J.; Browning, J.P. [NOXSO Corp., Bethel Park, PA (United States)

    1997-12-31

    The NOXSO Clean Coal Project will consist of designing, constructing, and operating a commercial-scale flue-gas cleanup system utilizing the NOXSO Process. The process is a waste-free, dry, post-combustion flue-gas treatment technology which uses a regenerable sorbent to simultaneously adsorb sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from flue gas from coal-fired boilers. The NOXSO plant will be constructed at Alcoa Generating Corporation`s (AGC) Warrick Power Plant near Evansville, Indiana and will treat all the flue gas from the 150-MW Unit 2 boiler. The NOXSO plant is being designed to remove 98% of the SO{sub 2} and 75% of the NO{sub x} when the boiler is fired with 3.4 weight percent sulfur, southern-Indiana coal. The NOXSO plant by-product will be elemental sulfur. The elemental sulfur will be shipped to Olin Corporation`s Charleston, Tennessee facility for additional processing. As part of the project, a liquid SO{sub 2} plant has been constructed at this facility to convert the sulfur into liquid SO{sub 2}. The project utilizes a unique burn-in-oxygen process in which the elemental sulfur is oxidized to SO{sub 2} in a stream of compressed oxygen. The SO{sub 2} vapor will then be cooled and condensed. The burn-in-oxygen process is simpler and more environmentally friendly than conventional technologies. The liquid SO{sub 2} plant produces 99.99% pure SO{sub 2} for use at Olin`s facilities. The $82.8 million project is co-funded by the US Department of Energy (DOE) under Round III of the Clean Coal Technology program. The DOE manages the project through the Pittsburgh Energy Technology Center (PETC).

  2. Clean coal technologies market potential

    Energy Technology Data Exchange (ETDEWEB)

    Drazga, B. (ed.)

    2007-01-30

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  3. Hydrothermal method for preparing calcium phosphate monoliths

    Directory of Open Access Journals (Sweden)

    García Carrodeguas Raúl

    2003-01-01

    Full Text Available A new hydrothermal route for preparing biphasic calcium phosphate monoliths is proposed. Firstly, a slurry of beta-tricalcium phosphate/ortho-phosphoric acid (b-TCP/H3PO4 is cast into the desired final shape and size to obtain a block composed of dicalcium phosphate dihydrate (DCPD and b-TCP. This block is then treated in 1.0 M Na2HPO4 at 60 °C in order to hydrolyze the DCPD into Ca10-x(HPO4x(PO4 6-x(OH2-x (CDHA and Ca8H2(PO46 .5H2O (OCP. The result is a monolithic piece which preserves the initial shape and size, but which is composed instead of CDHA, OCP, and b-TCP. During the initial stage, when the pH is slightly alkaline, the product of DCPD hydrolysis is CDHA. However, when a neutral or slightly acidic pH is reached OCP is formed. Test samples processed by this method showed complete conversion of DCPD into CDHA and OCP after 112 h of hydrolysis, and with a compressive strength of 16.2 MPa, similar to cancellous bone.

  4. Structural characteristics and glucose response in mice of potato starch modified by hydrothermal treatments

    Science.gov (United States)

    The structural properties and digestibility of slowly digestible The structural properties and digestibility of slowly digestible hydrothermally treated potato starch (SDS) were investigated. The potato starch with 20, 30 or 40% moisture content was heated at 100 °C for 30 min, and then kept at 30 °...

  5. Environmental performance of hydrothermal carbonization of four wet biomass waste streams at industry-relevant scales

    DEFF Research Database (Denmark)

    Owsianiak, Mikolaj; Ryberg, Morten; Renz, Michael

    2016-01-01

    Hydrothermal carbonization (HTC) of green waste, food waste, organic fraction of municipal solid waste (MSW), and digestate is assessed using life cycle assessment as a potential technology to treat biowaste. Water content of the biowaste and composition of the resulting hydrochar are important...

  6. Dynamics of the Yellowstone hydrothermal system

    Science.gov (United States)

    Hurwitz, Shaul; Lowenstern, Jacob B.

    2014-01-01

    The Yellowstone Plateau Volcanic Field is characterized by extensive seismicity, episodes of uplift and subsidence, and a hydrothermal system that comprises more than 10,000 thermal features, including geysers, fumaroles, mud pots, thermal springs, and hydrothermal explosion craters. The diverse chemical and isotopic compositions of waters and gases derive from mantle, crustal, and meteoric sources and extensive water-gas-rock interaction at variable pressures and temperatures. The thermal features are host to all domains of life that utilize diverse inorganic sources of energy for metabolism. The unique and exceptional features of the hydrothermal system have attracted numerous researchers to Yellowstone beginning with the Washburn and Hayden expeditions in the 1870s. Since a seminal review published a quarter of a century ago, research in many fields has greatly advanced our understanding of the many coupled processes operating in and on the hydrothermal system. Specific advances include more refined geophysical images of the magmatic system, better constraints on the time scale of magmatic processes, characterization of fluid sources and water-rock interactions, quantitative estimates of heat and magmatic volatile fluxes, discovering and quantifying the role of thermophile microorganisms in the geochemical cycle, defining the chronology of hydrothermal explosions and their relation to glacial cycles, defining possible links between hydrothermal activity, deformation, and seismicity; quantifying geyser dynamics; and the discovery of extensive hydrothermal activity in Yellowstone Lake. Discussion of these many advances forms the basis of this review.

  7. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

    1995-04-01

    Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

  8. State coal profiles, January 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-02-02

    The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

  9. Nitrogen-doped hydrothermal carbons

    Energy Technology Data Exchange (ETDEWEB)

    Titirici, Maria-Magdalena; White, Robin J. [Max-Planck-Institute of Colloids and Interfaces, Potsdam (Germany). Dept. of Colloid Chemistry; Zhao, Li [Max-Planck-Institute of Colloids and Interfaces, Potsdam (Germany). Dept. of Colloid Chemistry; National Center for Nanoscience and Technology, Beijing (China)

    2012-07-01

    Nitrogen doped carbon materials are now playing an important role in cutting edge innovations for energy conversion and storage technologies such as supercapacitors and proton exchange membrane fuel cells as well as in catalytic applications, adsorption and CO{sub 2} capture. The production of such materials using benign aqueous based processes, mild temperatures and renewable precursors is of great promise in addressing growing environmental concerns for cleaner power sources at a time of increasing global demand for energy. In this perspective, we show that nitrogen doped carbons prepared using sustainable processes such as ''Hydrothermal Carbonisation'' has advantages in many applications over the conventional carbons. We also summarize an array of synthetic strategies used to create such nitrogen doped carbons, and discuss the application of these novel materials. (orig.)

  10. Explosive treatment of Illinois No.6 coal with a mixed solvent of water and cyclohexanol; Mizu-cyclohexanol kongo yozai ni yoru Illinois tan no bakusai shori

    Energy Technology Data Exchange (ETDEWEB)

    Hashimoto, T.; Takada, H.; Asami, K.; Yano, M. [Osaka City University, Osaka (Japan). Faculty of Engineering

    1996-10-28

    Coal was treated at high temperature under high pressure in the binary system mixed solvent of water and organic solvent, and the solvent treated coal was liquefied. When the treated coal was treated again by the explosive method in which high temperature and pressure were released immediately, the oil yield was higher than that by the normal method in which high temperature and pressure were reduced gradually to room temperature and atmospheric pressure. In this study, an explosive treatment unit with increased scale of sample amount was newly fabricated. Illinois No.6 coal was treated by the explosive method in a mixed solvent of water and cyclohexanol using this unit. Changes in shape on the surface, specific surface area, and functional groups were analyzed. The explosively treated coal contained more amount of low boiling point components than the normally treated coal. It was suggested that the oil yield of explosively treated coal increased due to the liquefaction of these components during the successive hydrogenation process. For the explosively treated coal, micro pores were fractured by the rapid change in the volume of solvent molecules, and the specific surface area was smaller than that of the normally treated coal. When the treatment temperature was increased from 300{degree}C to 350{degree}C, specific surface areas of both the treated coals increased. 2 refs., 3 figs., 2 tabs.

  11. COAL USE REPORT

    Science.gov (United States)

    The world's coal reserves have been estimated to be about one exagram accessible with current extraction technology. The energy content has been valued at 290 zettajourles. Using a value of 15 terawatt as the current global energy consumption, the coal supply could global needs f...

  12. Coal Industry Burns Hot

    Institute of Scientific and Technical Information of China (English)

    JadaFu

    2003-01-01

    After a rapid boom last year, China's coal industry has continued to grow in 2003. The country has produced 177.27 million tons of coal in the first two months of the year, a year-on-year rise of 17.7 percent.

  13. Improving coal handling effectiveness

    Energy Technology Data Exchange (ETDEWEB)

    Walker, S.

    2003-10-01

    Appropriate coal handling systems are essential for successful coal utilisation. The paper looks at some of the options available, including crushers and hammer mills, wear-resistant liners for chutes and wagons, and dewatering systems. These are individual components within larger systems such as stockyard stacking and reclaiming installations. 5 photos.

  14. Development of coal resources

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    It is an important issue to expand stable coal supply areas for Japan, especially to assure stable supply of overseas coals. The investigations on geological structures in foreign countries perform surveys on geological structures in overseas coal producing countries and basic feasibility studies. The investigations select areas with greater business risks in coal producing countries and among private business entities. The geological structure investigations were carried out on China, Indonesia and Malaysia and the basic feasibility studies on Indonesia during fiscal 1994. The basic coal resource development investigations refer to the results of previous physical explorations and drilling tests to develop practical exploration technologies for coal resources in foreign countries. The development feasibility studies on overseas coals conduct technological consultation, surface surveys, physical explorations, and trial drilling operations, and provide fund assistance to activities related thereto. Fiscal 1994 has provided fund assistance to two projects in Indonesia and America. Fund loans are provided on investigations for development and import of overseas coals and other related activities. Liability guarantee for development fund is also described.

  15. Apparatus and method for feeding coal into a coal gasifier

    Science.gov (United States)

    Bissett, Larry A.; Friggens, Gary R.; McGee, James P.

    1979-01-01

    This invention is directed to a system for feeding coal into a gasifier operating at high pressures. A coal-water slurry is pumped to the desired pressure and then the coal is "dried" prior to feeding the coal into the gasifier by contacting the slurry with superheated steam in an entrained bed dryer for vaporizing the water in the slurry.

  16. Catastrophic volcanic collapse: relation to hydrothermal processes.

    Science.gov (United States)

    López, D L; Williams, S N

    1993-06-18

    Catastrophic volcanic collapse, without precursory magmatic activity, is characteristic of many volcanic disasters. The extent and locations of hydrothermal discharges at Nevado del Ruiz volcano, Colombia, suggest that at many volcanoes collapse may result from the interactions between hydrothermal fluids and the volcanic edifice. Rock dissolution and hydrothermal mineral alteration, combined with physical triggers such as earth-quakes, can produce volcanic collapse. Hot spring water compositions, residence times, and flow paths through faults were used to model potential collapse at Ruiz. Caldera dimensions, deposits, and alteration mineral volumes are consistent with parameters observed at other volcanoes.

  17. What Defines a Separate Hydrothermal System

    Energy Technology Data Exchange (ETDEWEB)

    Lawless, J.V.; Bogie, I.; Bignall, G.

    1995-01-01

    Separate hydrothermal systems can be defined in a variety of ways. Criteria which have been applied include separation of heat source, upflow, economic resource and geophysical anomaly. Alternatively, connections have been defined by the effects of withdrawal of economically useful fluid and subsidence, effects of reinjection, changes in thermal features, or by a hydrological connection of groundwaters. It is proposed here that: ''A separate hydrothermal system is one that is fed by a separate convective upflow of fluid, at a depth above the brittle-ductile transition for the host rocks, while acknowledging that separate hydrothermal systems can be hydrologically interconnected at shallower levels''.

  18. Coal technology program. Progress report, September 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-10-01

    A successful hydrocarbonization experiment at 300 psi of hydrogen and approximately 1050/sup 0/F was completed with Illinois No. 6 coal that had been chemically pretreated with aqueous CaO and NaOH. In pressurized carbonization, one successful experiment at approximately 1100/sup 0/F and 415 psi of methane was completed with vacuum distillation residue from the H-Coal process. In the thick section pressure vessel work, procedures are being developed with the DATA TRAK heat treating facility to allow preparation of relatively large heat treated samples of 2 /sup 1///sub 4/ Cr-1 Mo steel. In the Gas-Fired Potassium Boiler Project, the potassium system installation was completed, the fill and drain tank was filled with potassium, and the checkout of the instruments and controls was nearly completed. The Coal-Fired Alkali Metal Power System Design Study was completed and a draft report describing the design was issued. Cesium was selected as the working fluid for the topping cycle. For the reference design, the furnace operated at atmospheric pressure and the cycle conditions for the power conversion systems were 1500/sup 0/F (1089 K) to 900/sup 0/F (756 K) for the topping cycle and 2400 psi (16.5 MPa)/1000/sup 0/F (811 K)/1000/sup 0/F (811 K) to 1 /sup 1///sub 2/ in. Hg (5079 Pa) for the steam system. ORNL was requested by DOE to develop a program for testing coal feeders currently under development. Work was continued on process modeling, the preparation of a Synthetic Fuels Research Digest, a survey of industrial coal conversion equipment capabilities, and studies of flash hydropyrolysis, hot gas purification processes, processes for heat recovery, and hydrogen production by the steam/molten iron process. Process and program analysis studies were continued on low-Btu gasification, direct combustion, advanced power conversion systems, liquefaction, high-Btu gasification, in-situ gasification, and coal beneficiation.

  19. Underground Coal Thermal Treatment

    Energy Technology Data Exchange (ETDEWEB)

    Smith, P. [Univ. of Utah, Salt Lake City, UT (United States); Deo, M. [Univ. of Utah, Salt Lake City, UT (United States); Eddings, E. [Univ. of Utah, Salt Lake City, UT (United States); Sarofim, A. [Univ. of Utah, Salt Lake City, UT (United States); Gueishen, K. [Univ. of Utah, Salt Lake City, UT (United States); Hradisky, M. [Univ. of Utah, Salt Lake City, UT (United States); Kelly, K. [Univ. of Utah, Salt Lake City, UT (United States); Mandalaparty, P. [Univ. of Utah, Salt Lake City, UT (United States); Zhang, H. [Univ. of Utah, Salt Lake City, UT (United States)

    2012-01-11

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coal's carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO2 sequestration.

  20. (Coal utilization in India)

    Energy Technology Data Exchange (ETDEWEB)

    Krishnan, R.P.

    1991-01-15

    Under the Phase II, Alternative Energy Resources Development (AERD) project of the United States Agency for International Development (USAID) and the Government of India (GOI), five collaborative coal projects have been initiated in the areas of: (1) NO{sub x}/SO{sub x} control from coal-fired power plants, (2) slagging combustor development for high-ash Indian coals, (3) characterization of Indian coals for combustion and gasification, (4) diagnostic studies for prediction of power plant life expectancy, and (5) environmental and natural resource analysis of coal cycle. The Pittsburgh Energy Technology Center (PETC) has the implementation responsibility for these projects. The Indian collaborative institutions identified for these projects are the Bharat Heavy Electricals Ltd. (BHEL), Trichy, (Projects 1--4), and the Tata Energy Research Institute (TERI) for Project 5. The Oak Ridge National Laboratory (ORNL) is providing cross-cut technical coordination and support for these five projects.

  1. Enzymatic desulfurization of coal

    Energy Technology Data Exchange (ETDEWEB)

    Boyer, Y.N.; Crooker, S.C.; Kitchell, J.P.; Nochur, S.V.

    1991-05-16

    The overall objective of this program was to investigate the feasibility of an enzymatic desulfurization process specifically intended for organic sulfur removal from coal. Toward that end, a series of specific objectives were defined: (1) establish the feasibility of (bio)oxidative pretreatment followed by biochemical sulfate cleavage for representative sulfur-containing model compounds and coals using commercially-available enzymes; (2) investigate the potential for the isolation and selective use of enzyme preparations from coal-utilizing microbial systems for desulfurization of sulfur-containing model compounds and coals; and (3) develop a conceptual design and economic analysis of a process for enzymatic removal of organic sulfur from coal. Within the scope of this program, it was proposed to carry out a portion of each of these efforts concurrently. (VC)

  2. Pyrolysis of Indonesian coal

    Energy Technology Data Exchange (ETDEWEB)

    Rachimoellah; Endah [Institut Teknologi Sepuluh Nopemba, Surabaya (Indonesia). Department of Chemical Engineering; Karaman, N.; Kusuma, S.A. [UPN Surabaya, (Indonesia). Department of Chemical Engineering

    1997-04-01

    It has been estimated that there is 36 billion tons of coal resource potential in Indonesia. Over 21.4 billion tons is classified as low rank (lignitic) coal. The coal deposits are located mainly in Sumatra and Kalimantan. As an energy source, low rank coals are not widely used, because of their high moisture content, low calorific value and variable ash content. One of the key questions for utilizing low rank coal is whether lignite can be upgraded into another form which is more economically viable. In this study tests were carried out in a pilot plant fixed bed pyrolysis reactor unit provided with hopper, electric heater, coolers and product receivers. The yield of char, tar and gases was found to depend on temperature which also affected the composition of gas produced. Results also indicated the temperature and particle size giving maximum tar yield, gas concentration, and the atmosphere of inert nitrogen. 1 tab., 2 figs., 10 refs.

  3. Industrial coal utilization

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-01-01

    The effects of the National Energy Act on the use of coal in US industrial and utility power plants are considered. Innovative methods of using coal in an environmentally acceptable way are discussed: furnace types, fluidized-bed combustion, coal-oil-mixtures, coal firing in kilns and combustion of synthetic gas and liquid fuels. Fuel use in various industries is discussed with trends brought about by uncertain availability and price of natural gas and fuel oils: steel, chemical, cement, pulp and paper, glass and bricks. The symposium on Industrial Coal Utilization was sponsored by the US DOE, Pittsburgh Energy Technology Center, April 3 to 4, 1979. Twenty-one papers have been entered individually into the EDB. (LTN)

  4. Industrial coal utilization

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-01-01

    The effects of the National Energy Act on the use of coal in US industrial and utility power plants are considered. Innovative methods of using coal in an environmentally acceptable way are discussed: furnace types, fluidized-bed combustion, coal-oil-mixtures, coal firing in kilns and combustion of synthetic gas and liquid fuels. Fuel use in various industries is discussed with trends brought about by uncertain availability and price of natural gas and fuel oils: steel, chemical, cement, pulp and paper, glass and bricks. The symposium on Industrial Coal Utilization was sponsored by the US DOE, Pittsburgh Energy Technology Center, April 3 to 4, 1979. Twenty-one papers have been entered individually into the EDB. (LTN)

  5. Study on Modification of Ultra-Stable Zeolite Prepared by Hydrothermal Method

    Institute of Scientific and Technical Information of China (English)

    Zhang Weilin; Zhou Lingping; Shen Shimin; Li Zheng; Zhu Yuxia; Tian Huiping; Long Jun

    2007-01-01

    The ultra-stable zeolite DASY-0.0 was prepared by hydrothermal method in commercial scale.Its structure was further modified via the treatment for cleaning of pores(CP).The zeolite samples before and after CP treating were analyzed and characterized by XRF,XRD,NMR,IR,BET and DTA.The results showed that,in comparison with the conventional ultra-stable zeolite DASY-0.0 prepared by the hydrothermal process,the CP-modified zeolite SOY0 exhibited a higher relative crystallinity.a larger surface area and pore volume,a higher thermal stability and contained less amorphous non-framework Al.

  6. Utilization of zeolites synthesized from coal ash for methylene blue removal from water

    Directory of Open Access Journals (Sweden)

    Denise Alves Fungaro

    2008-12-01

    Full Text Available The adsorption of methylene blue from aqueous solution was carried out using zeolites synthesized from coal ash as low-cost adsorbents. The coal ash sample was converted to zeolites by hydrothermal treatment using different synthesis parameters. The materials were characterized by physical-chemical analysis, XRD and SEM studies. The adsorption isotherms can be fitted by Freundlich model. The values of the adsorption capacity of adsorbents were similar for adsorbents. Kinetic studies indicate that the adsorption follows pseudo-second-order kinetic model.

  7. Economic Limit of Coal Mining Closedown in Restructuring Coal Industry

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    One of the key points in restructuring the coal industry is to close some deficient coal mines which haveneither economic result nor social benefit. Based on the relationship among production, cost, and profit, differenteconomic limits for closing coal mines in different cases were put forward. The relationship between the profit andclosedown cost of deficient coal mines was analyzed and an overall economic limit for closing a deficient coal minewas also proposed.

  8. Coal Activities for Secondary Students.

    Science.gov (United States)

    American Coal Foundation, Washington, DC.

    This collection of lesson plans designed for teachers of 4th- through 12th-grade students utilizes an assortment of teaching strategies for topics related to coal and the coal industry. Activities cover the following topics: coal formation; coal identification; "the geologist's dilemma" (a supply and demand activity); geologic time and the…

  9. Transportation of coal by pipeline

    Energy Technology Data Exchange (ETDEWEB)

    Round, G.F.

    1982-01-01

    Discusses Canada's coal resources, technology of long distance coal slurry pipelines, existing and planned coal slurry pipelines, their economics, liquid carbon dioxide, methanol and crude oil instead of water as carrier fluid, and coal slurry research in Canada.

  10. Mineral and inorganic chemical composition of the Pernik coal, Bulgaria

    Energy Technology Data Exchange (ETDEWEB)

    Yossifova, Mariana G. [Geological Institute, Acad. G. Bonchev Str., Bl.24, Bulgarian Academy of Sciences, 1113 Sofia (Bulgaria)

    2007-11-22

    The mineral and inorganic chemical composition of five types of samples from the Pernik subbituminous coals and their products generated from the Pernik preparation plant were studied. They include feed coal, low-grade coal, high-grade coal, coal slime, and host rock. The mineral matter of the coals contains 44 species that belong mainly to silicates, carbonates, sulphates, sulphides, and oxides/hydroxides, and to a lesser extent, chlorides, biogenic minerals, and organic minerals. The detrital minerals are quartz, kaolinite, micas, feldspars, magnetite, cristobalite, spessartine, and amphibole. The authigenic minerals include various sulphides, silicates, oxihydroxides, sulphates, and carbonates. Several stages and substages of formation were identified during the syngenetic and epigenetic mineral precipitations of these coals. The authigenic minerals show the greatest diversity of mineral species as the epigenetic mineralization (mostly sulphides, carbonates, and sulphates) dominates qualitatively and quantitatively. The epigenetic mineralization was a result of complex processes occurring mostly during the late development of the Pernik basin. These processes indicate intensive tectonic, hydrothermal and volcanic activities accompanied by a change from fresh to marine sedimentation environment. Thermally altered organic matter due to some of the above processes was also identified in the basin. Most of the trace elements in the Pernik coals (Mo, Be, S, Zr, Y, Cl, Ba, Sc, Ga, Ag, V, P, Br, Ni, Co, Pb, Ca, and Ti) show an affinity to OM and phases intimately associated with OM. Some of the trace elements (Sr, Ti, Mn, Ba, Pb, Cu, Zn, Co, Cr, Ni, As, Ag, Yb, Sn, Ga, Ge, etc.) are impurities in authigenic and accessory minerals, while other trace elements (La, Ba, Cu, Ce, Sb, Bi, Zn, Pb, Cd, Nd, etc.) occur as discrete phases. Elements such as Sc, Be, Y, Ba, V, Zr, S, Mo, Ti, and Ga exceed Clarke concentrations in all of the coal types studied. It was also found that

  11. Hydrothermal treatment of titanium alloys for the enhancement of osteoconductivity

    Energy Technology Data Exchange (ETDEWEB)

    Zuldesmi, Mansjur, E-mail: mzuldesmi@yahoo.com [Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University, Nagoya (Japan); Department of Mechanical Engineering, Manad State University (UNIMA) (Indonesia); Waki, Atsushi [Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University, Nagoya (Japan); Kuroda, Kensuke; Okido, Masazumi [EcoTopia Science Institute, Nagoya University, Nagoya (Japan)

    2015-04-01

    The surface wettability of implants is a crucial factor in their osteoconductivity because it influences the adsorption of cell-attached proteins onto the surface. In this study, a single-step hydrothermal surface treatment using distilled water at a temperature of 180 °C for 3 h was applied to titanium (Ti) and its alloys (Ti–6Al–4V, Ti–6Al–7Nb, Ti–29Nb–13Ta–4.6Zr, Ti–13Cr–1Fe–3Al; mass%) and compared with as-polished Ti implants and with implants produced by anodizing Ti in 0.1 M of H{sub 3}PO{sub 4} with applied voltages from 0 V to 150 V at a scanning rate of 0.1 V s{sup −1}. The surface-treated samples were stored in a five time phosphate buffered saline (× 5 PBS(−)) solution to prevent increasing the water contact angle (WCA) with time. The surface characteristics were evaluated using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Auger electron spectroscopy, surface roughness, and contact angle measurement using a 2 μL droplet of distilled water. The relationship between WCA and osteoconductivity at various surface modifications was examined using in vivo tests. The results showed that a superhydrophilic surface with a WCA ≤ 10° and a high osteoconductivity (R{sub B–I}) of up to 50% in the cortical bone part, about four times higher than the as-polished Ti and Ti alloys, were provided by the combination of the hydrothermal surface treatment and storage in × 5 of PBS(−). - Highlights: • Hydrothermal treatment in distilled water was applied to titanium alloys. • Surface characteristics and osteoconductivity by in vivo test were evaluated. • Water contact angles of titanium alloys were decreased by hydrothermal treatment. • Osteoconductivity of titanium alloys improved notably by hydrothermal treatment after stored in × 5 of PBS (−)

  12. Spin-mapping of Coal Structures with ESE and ENDOR

    Science.gov (United States)

    Belford, R. L.; Clarkson, R. B.

    1989-12-01

    The broad goals of this project are to determine by nondestructive magnetic resonance methods chemical and physical structural characteristics of organic parts of native and treated coals. In this project period, we have begun to explore a technique which promises to enable us to follow to course of coal cleaning processes with microscopic spatial resolution. For the past five years, our laboratory has worked on extensions of the EPR technique as applied to coal to address these analytical problems. In this report we (1) describe the world's first nuclear magnetic resonance imaging results from an Illinois {number sign}6 coal and (2) transmit a manuscript describing how organic sulfur affect the very-high-frequency EPR spectra of coals. Magnetic resonance imaging (MRI) is a non-destructive technique that has found wide medical application as a means of visualizing the interior of human bodies. We have used MRI techniques to study the diffusion of an organic solvent (DMSO) into the pores of Illinois {number sign}6 coal. Proton MRI images reveal that this solvent at room temperature does not penetrate approximately 30% of the coal volume. Regions of the coal that exclude solvent could be related to inertinite and mineral components. A multi-technique imaging program is contemplated.

  13. Hydrothermal system of Long Valley caldera, California

    Energy Technology Data Exchange (ETDEWEB)

    Sorey, M.L.; Lewis, R.E.; Olmsted, F.H.

    1978-01-01

    The geologic and hydrologic setting of the hydrothermal system are described. The geochemical and thermal characteristics of the system are presented. A mathematical model of the Long Valley caldera is analyzed. (MHR)

  14. Dissolubility of Hydroxyapatite Powder under Hydrothermal Condition

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The dissolubility of hydroxyapatite(HA) in the hydrothermal solution was investigated in Morey-type autoclave over a temperature range of 150 to 350 ℃ and the pH value range of 5 to 9. It is shown that the dissolubility of HA is determined as a function of temperature and time under a constant filling ratio of autoclave, and the temperature coefficient for the solubility of HA is positive. The equilibrium time attained in the hydrothermal solution is shortened with the increase of hydrothermal temperature, and the effect of temperature on the solubility is obviously stronger than that of pH value. The solubility data suggest that HA has higher dissolubility in the HA-H2O system under the hydrothermal condition than that under the normal temperature-pressure.

  15. Effect of hydrothermally ‘Hass” avocado about antioxidant capacity, total phenolic content and coloration

    Directory of Open Access Journals (Sweden)

    Maria Augusta Tremocoldi

    2014-06-01

    Full Text Available This study aimed to determine the antioxidant activity, total phenolic compounds and color in avocado ‘Hass’ hydrothermally treated. The fruits were hydrothermally treated at 45oC for 5, 10, 15 and 20 min. After treatment, fruit were stored at room temperature (21±1ºC and 70±5% relative humidity and cold (10°C±1 and 90±5% relative humidity. The fruits were analyzed for their antioxidant capacity by DPPH method and phenolic compounds at 0, 3, 9 and 12 days. The fruits color was measured at 0, 3, 6, 9, 12 and 15 days. The control fruits had higher antioxidant capacity and content of phenolic compounds during the storage period, compared to the fruits hydrothermally treated. The hydrothermally treatment altered the behavior as for the maintenance of the antioxidant activity in relation to the fruits control. In spite of superior values of antioxidant activity for the fruits maintained at 21±1ºC and 70±5% relative humidity, those refrigerated presented better aspect for commercialization. The refrigerated fruits presented better aspect for commercialization in relation to the maintained under room temperature. The brightness, color a * and b * values decreased with the storage days. Values color superiors were observed for the fruits control and those maintained under refrigeration. As it increased the irradiation dose reduced the fruits antioxidant activity and coloration.

  16. Hydrothermal Manganese Mineralization Near the Samoan Hotspot

    Science.gov (United States)

    Hein, J. R.; Staudigel, H.; Koppers, A.; Hart, S. R.; Dunham, R.

    2006-12-01

    The thickest beds of hydrothermal manganese oxides recovered to date from the global ocean were collected from a volcanic cone in the south Pacific. In April 2005, samples were dredged aboard the R.V. Kilo Moana from a volcanic cone on the lower flank of Tulaga seamount (about 2,700 m water depth; 14° 39.222' S; 170° 1.730' W), located 115 km SW of Vailulu'u, the volcanically and hydrothermally active center of the Samoan hotspot. Additional hydrothermal manganese samples were collected off Ofu Island (dredge Alia 107), 72 km to the WSW of Vailulu'u. Manganese-oxide beds up to 9 cm thick are composed of birnessite and 10 Å manganates. Some layers consist of Mn-oxide columnar structures 4 cm long and 1 cm wide, which have not been described previously. The mean Mn and Fe contents of 18 samples are 51 weight percent and 0.76 weight percent, respectively. Elevated concentrations of Li (mean 0.11 wt. percent) are indicators of a hydrothermal origin, and distinguishes these samples, along with the high Mn and low Fe contents, from hydrogenetic Fe-Mn crusts. Other enriched elements include Ba (mean 0.14 percent), Cu (249 ppm), Mo (451 ppm), Ni (400 ppm), Zn (394 ppm), V (214 ppm), and W (132 ppm). Chondrite-normalized REE patterns show large negative Ce anomalies and LREE enrichments, both characteristic of hydrothermal Mn deposits. Small negative Eu anomalies are not typical of hydrothermal deposits and can be explained either by the absence of leaching of plagioclase by the hydrothermal fluids or by the precipitation of Eu-rich minerals, such as barite and anhydrite, at depth. The high base-metal contents indicate that sulfides are not forming deeper in the hydrothermal system or that such deposits are being leached by the ascending fluids. Textures of the thickest Mn deposits indicate that the Mn oxides formed below the seabed from ascending fluids during multiple phases of waxing and waning hydrothermal pulses. The deposits were later exposed at the seafloor by

  17. Atmospheric fluidized bed coal combustion research, development and application

    CERN Document Server

    Valk, M

    1994-01-01

    The use of fluidized bed coal combustion technology has been developed in the past decade in The Netherlands with a view to expanding the industrial use of coal as an energy supply. Various research groups from universities, institutes for applied science and from boiler industries participated and contributed to this research area. Comprehensive results of such recent experimentation and development work on atmospheric fluidized bed combustion of coal are covered in this volume. Each chapter, written by an expert, treats one specific subject and gives both the theoretical background as well a

  18. Crystalline hydroxyapatite coatings synthesized under hydrothermal conditions on modified titanium substrates

    Energy Technology Data Exchange (ETDEWEB)

    Suchanek, Katarzyna, E-mail: Katarzyna.Suchanek@ifj.edu.pl [The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego Street 152, 31-342 Krakow (Poland); Bartkowiak, Amanda [The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego Street 152, 31-342 Krakow (Poland); Gdowik, Agnieszka [Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow (Poland); Perzanowski, Marcin [The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego Street 152, 31-342 Krakow (Poland); Kąc, Sławomir [Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, Mickiewica 30, 30-059 Krakow (Poland); Szaraniec, Barbara [Department of Biomaterials, AGH University of Science and Technology, Mickiewicza 30, 30-059 Krakow (Poland); Suchanek, Mateusz [Department of Chemistry and Physics, University of Agriculture in Krakow, Mickiewicza 21, 31-120 Krakow (Poland); Marszałek, Marta [The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego Street 152, 31-342 Krakow (Poland)

    2015-06-01

    Hydroxyapatite coatings were successfully produced on modified titanium substrates via hydrothermal synthesis in a Ca(EDTA){sup 2−} and (NH{sub 4}){sub 2}HPO{sub 4} solution. The morphology of modified titanium substrates as well as hydroxyapatite coatings was studied using scanning electron microcopy and phase identification by X-ray diffraction, and Raman and FTIR spectroscopy. The results show that the nucleation and growth of hydroxyapatite needle-like crystals with hexagonal symmetry occurred only on titanium substrates both chemically and thermally treated. No hydroxyapatite phase was detected on only acid etched Ti metal. This finding demonstrates that only a particular titanium surface treatment can effectively induce the apatite nucleation under hydrothermal conditions. - Highlights: • Bioactivation of titanium substrate by chemical and heat treatments • Precipitation of hydroxyapatite on modified titanium plates • Hydrothermal crystallization of hydroxyapatite by chelate decomposition method.

  19. One-pot hydrothermal preparation of graphene sponge for the removal of oils and organic solvents

    Science.gov (United States)

    Wu, Ruihan; Yu, Baowei; Liu, Xiaoyang; Li, Hongliang; Wang, Weixuan; Chen, Lingyun; Bai, Yitong; Ming, Zhu; Yang, Sheng-Tao

    2016-01-01

    Graphene sponge (GS) has found applications in oil removal due to the hydrophobic nature of graphene sheets. Current hydrothermal preparations of GS use toxic reducing reagents, which might cause environmental pollution. In this study, we reported that graphene oxide (GO) could be hydrothermally reduced by glucose to form GS for the adsorption of oils and various organic solvents. Graphene sheets were reduced by glucose during the hydrothermal treatment and formed 3D porous structure. GS efficiently adsorbed organic solvents and oils with competitive adsorption capacities. GS was able to treat pollutants in pure liquid form and also in the simulated seawater. GS could be easily regenerated by evaporating or burning. After 10 cycles, the adsorption capacity still retained 77% by evaporating and 87% by burning. The implication to the applications of GS in water remediation is discussed.

  20. Hydrothermal industrialization: direct heat development. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1982-05-01

    A description of hydrothermal resources suitable for direct applications, their associated temperatures, geographic distribution and developable capacity are given. An overview of the hydrothermal direct-heat development infrastructure is presented. Development activity is highlighted by examining known and planned geothermal direct-use applications. Underlying assumptions and results for three studies conducted to determine direct-use market penetration of geothermal energy are discussed.

  1. Treating Infertility

    Science.gov (United States)

    ... Education & Events Advocacy For Patients About ACOG Treating Infertility Home For Patients Search FAQs Treating Infertility Page ... Treating Infertility FAQ137, March 2015 PDF Format Treating Infertility Gynecologic Problems What is infertility? What treatment options ...

  2. Coal Mines Security System

    Directory of Open Access Journals (Sweden)

    Ankita Guhe

    2012-05-01

    Full Text Available Geological circumstances of mine seem to be extremely complicated and there are many hidden troubles. Coal is wrongly lifted by the musclemen from coal stocks, coal washeries, coal transfer and loading points and also in the transport routes by malfunctioning the weighing of trucks. CIL —Coal India Ltd is under the control of mafia and a large number of irregularities can be contributed to coal mafia. An Intelligent Coal Mine Security System using data acquisition method utilizes sensor, automatic detection, communication and microcontroller technologies, to realize the operational parameters of the mining area. The data acquisition terminal take the PIC 16F877A chip integrated circuit as a core for sensing the data, which carries on the communication through the RS232 interface with the main control machine, which has realized the intelligent monitoring. Data management system uses EEPROM chip as a Black box to store data permanently and also use CCTV camera for recording internal situation. The system implements the real-time monitoring and displaying for data undermine, query, deletion and maintenance of history data, graphic statistic, report printing, expert diagnosis and decision-making support. The Research, development and Promote Application will provide the safeguard regarding the mine pit control in accuracy, real-time capacity and has high reliability.

  3. Industrial role of coal chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Dierk, E.A.; Stadelhofer, J.W.

    1983-02-07

    The paper is concerned with the production of coal-based chemicals either from the by-products of coal carbonization, or from synthesis gas manufactured from coal. The potential of coal tar as a raw material for chemicals synthesis forms the basis of the paper. Koppers-Totzek and Lurgi gasification processes and Fischer-Tropsch synthesis are considered, and, finally, coal liquefaction processes are briefly mentioned.

  4. Clean coal technology: The new coal era

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    The Clean Coal Technology Program is a government and industry cofunded effort to demonstrate a new generation of innovative coal processes in a series of full-scale showcase`` facilities built across the country. Begun in 1986 and expanded in 1987, the program is expected to finance more than $6.8 billion of projects. Nearly two-thirds of the funding will come from the private sector, well above the 50 percent industry co-funding expected when the program began. The original recommendation for a multi-billion dollar clean coal demonstration program came from the US and Canadian Special Envoys on Acid Rain. In January 1986, Special Envoys Lewis and Davis presented their recommendations. Included was the call for a 5-year, $5-billion program in the US to demonstrate, at commercial scale, innovative clean coal technologies that were beginning to emerge from research programs both in the US and elsewhere in the world. As the Envoys said: if the menu of control options was expanded, and if the new options were significantly cheaper, yet highly efficient, it would be easier to formulate an acid rain control plan that would have broader public appeal.

  5. A Systematic Analysis of Coal Accumulation Process

    Institute of Scientific and Technical Information of China (English)

    CHENG Aiguo

    2008-01-01

    Formation of coal seam and coal-rich zone is an integrated result of a series of factors in coal accumulation process. The coal accumulation system is an architectural aggregation of coal accumulation factors. It can be classified into 4 levels: the global coal accumulation super-system, the coal accumulation domain mega.system, the coal accumulation basin system, and the coal seam or coal seam set sub-system. The coal accumulation process is an open, dynamic, and grey system, and is meanwhile a system with such natures as aggregation, relevance, entirety, purpose-orientated, hierarchy, and environment adaptability. In this paper, we take coal accumulation process as a system to study origin of coal seam and coal-rich zone; and we will discuss a methodology of the systematic analysis of coal accumulation process. As an example, the Ordos coal basin was investigated to elucidate the application of the method of the coal accumulation system analysis.

  6. Hydrothermal treatment for TiN as abrasion resistant dental implant coating and its fibroblast response

    Energy Technology Data Exchange (ETDEWEB)

    Shi, Xingling, E-mail: shixingling1985@hotmail.com [School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003 (China); Department of Biomaterials, Faculty of Dental Science, Kyushu University, Fukuoka 812-8582 (Japan); Jiangsu Provincial Key Laboratory for Interventional Medical Devices, Huaiyin Institute of Technology, Huaian 223003 (China); Xu, Lingli [School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003 (China); Munar, Melvin L.; Ishikawa, Kunio [Department of Biomaterials, Faculty of Dental Science, Kyushu University, Fukuoka 812-8582 (Japan)

    2015-04-01

    Dental implant made of pure titanium (Ti) is prone to scratch and abrasion during routine oral hygiene procedures. This results an increase in surface roughness and therefore, facilitates the adhesion of bacteria. In severe cases, this could lead to peri-implantitis. To overcome this problem, surface modification of Ti is necessary to improve its abrasion resistance. Besides, a strong implant–gingiva interface should also be guaranteed to prevent the adhesion of bacteria. In this study, titanium nitride (TiN) coating was first prepared with gas nitriding to increase surface hardness of pure the substrate. Then, the TiN was hydrothermally treated in CaCl{sub 2} solution in order to improve its soft tissue biocompatibility. The effect of hydrothermal treatment temperature on surface properties of TiN was investigated and its biocompatibility was assessed in vitro using NIH3T3 fibroblast cell. It was determined that 120 °C was the critical temperature for the hydrothermal treatment condition. Treatment below 120 °C could incorporate Ca into TiN surface, oxidize TiN surface partially and then improve the wettability while preserving its morphology and hardness. Fibroblast cell attachment and proliferation were improved and cell spreading was enhanced on hydrothermally treated specimens compared with untreated ones. Improved wettability, Ca incorporation and negative surface due to interstitial N were believed to be the main reasons. Hydrothermal treatment is expected to make TiN a promising dental implant coating with excellent abrasion resistance and good soft tissue affinity. - Highlights: • Ca was incorporated into TiN surface while not sacrificing its hardness. • Interstitial N due to oxidation promoted Ca adsorption and cell adhesion. • Hydrothermal treatment makes TiN a promising coating for dental implant.

  7. Clean coal initiatives in Indiana

    Science.gov (United States)

    Bowen, B.H.; Irwin, M.W.; Sparrow, F.T.; Mastalerz, Maria; Yu, Z.; Kramer, R.A.

    2007-01-01

    Purpose - Indiana is listed among the top ten coal states in the USA and annually mines about 35 million short tons (million tons) of coal from the vast reserves of the US Midwest Illinois Coal Basin. The implementation and commercialization of clean coal technologies is important to the economy of the state and has a significant role in the state's energy plan for increasing the use of the state's natural resources. Coal is a substantial Indiana energy resource and also has stable and relatively low costs, compared with the increasing costs of other major fuels. This indigenous energy source enables the promotion of energy independence. The purpose of this paper is to outline the significance of clean coal projects for achieving this objective. Design/methodology/approach - The paper outlines the clean coal initiatives being taken in Indiana and the research carried out at the Indiana Center for Coal Technology Research. Findings - Clean coal power generation and coal for transportation fuels (coal-to-liquids - CTL) are two major topics being investigated in Indiana. Coking coal, data compilation of the bituminous coal qualities within the Indiana coal beds, reducing dependence on coal imports, and provision of an emissions free environment are important topics to state legislators. Originality/value - Lessons learnt from these projects will be of value to other states and countries.

  8. Coal potential of Antartica

    Energy Technology Data Exchange (ETDEWEB)

    Rose, G.; McElroy, C.T.

    1987-01-01

    This report attempts to bring together available information on the coal deposits of Antarctica and discuss factors that would be involved if these deposits were to be explored and mined. Most of the reported principal coal deposits in Antarctica lie generally within the Transantarctic Mountains: the majority are of Permian age and are present in the Victoria Group of the Beacon Supergroup. Several other deposits have been recorded in East Antarctica and in the Antarctic Peninsula, including minor occurrences of Mesozoic and Tertiary coal and carbonaceous shale.

  9. Coal-fired generation

    CERN Document Server

    Breeze, Paul

    2015-01-01

    Coal-Fired Generation is a concise, up-to-date and readable guide providing an introduction to this traditional power generation technology. It includes detailed descriptions of coal fired generation systems, demystifies the coal fired technology functions in practice as well as exploring the economic and environmental risk factors. Engineers, managers, policymakers and those involved in planning and delivering energy resources will find this reference a valuable guide, to help establish a reliable power supply address social and economic objectives. Focuses on the evolution of the traditio

  10. Steam jacket dynamics in underground coal gasification

    Science.gov (United States)

    Otto, Christopher; Kempka, Thomas

    2017-04-01

    Underground coal gasification (UCG) has the potential to increase the world-wide hydrocarbon reserves by utilization of deposits not economically mineable by conventional methods. In this context, UCG involves combusting coal in-situ to produce a high-calorific synthesis gas, which can be applied for electricity generation or chemical feedstock production. Apart from high economic potentials, in-situ combustion may cause environmental impacts such as groundwater pollution by by-product leakage. In order to prevent or significantly mitigate these potential environmental concerns, UCG reactors are generally operated below hydrostatic pressure to limit the outflow of UCG process fluids into overburden aquifers. This pressure difference effects groundwater inflow into the reactor and prevents the escape of product gas. In the close reactor vicinity, fluid flow determined by the evolving high reactor temperatures, resulting in the build-up of a steam jacket. Numerical modeling is one of the key components to study coupled processes in in-situ combustion. We employed the thermo-hydraulic numerical simulator MUFITS (BINMIXT module) to address the influence of reactor pressure dynamics as well as hydro-geological coal and caprock parameters on water inflow and steam jacket dynamics. The US field trials Hanna and Hoe Creek (Wyoming) were applied for 3D model validation in terms of water inflow matching, whereby the good agreement between our modeling results and the field data indicates that our model reflects the hydrothermal physics of the process. In summary, our validated model allows a fast prediction of the steam jacket dynamics as well as water in- and outflows, required to avoid aquifer contamination during the entire life cycle of in-situ combustion operations.

  11. Variation in gas drainage rate from a coal seam during mining

    Institute of Scientific and Technical Information of China (English)

    Li; Gang; Qi; Qingxin; Li; Hongyan; Fan; Xisheng

    2012-01-01

    Gas flow patterns during draining of gas from a coal seam during mining are discussed.The coal seam is treated as a dual medium with both pores and cracks.The seepage,diffusion,and desorption processes are treated using a gas flow equation that describes flow around drill holes.MATLAB is used to solve the differential equations.The permeability tracer test results from a mined coal seam are used to study the variation in gas drainage from a coal seam during mining.The results show that mining can increase the permeability of a coal seam,which then increases the gas drainage.There are inflection points in this variation over time.A close relationship between this variation and the rate of change in coal seam permeability is observed.

  12. Coal slurry - a problem of the brown coal industry

    Energy Technology Data Exchange (ETDEWEB)

    Guenther, H.; Hielscher, R.; Mohry, J.

    1983-01-01

    Technological and economic aspects are examined for processing coal-containing waste water from brown coal preparation plants in the German Democratic Republic. In 1979, 106.8 Mm/sup 3/ of coal slurry were produced by the GDR brown coal industry, with a coal fine content ranging between 7.8 g/l and 20.4 g/l. This amounts to 2.6 Mt/y of coal which is 1% of the annual brown coal production. Technological variants of processing and utilizing coal slurry are discussed. At a number of major coal preparation plants, coal slurry is flushed into sedimentation lakes. After a 2 to 3 year drying period, a 6 to 10 m thick layer of coal is recovered. Technologies of coal slurry processing with the aim of recovering coal fines are enumerated. Equipment for these processes include, filters, centrifuges, dryers, etc. Recovered coal can be used as fuel or processed into fertilizer in combination with fly ash and other waste products. 12 references.

  13. Properties and degradability of hydrothermal carbonization products.

    Science.gov (United States)

    Eibisch, Nina; Helfrich, Mirjam; Don, Axel; Mikutta, Robert; Kruse, Andrea; Ellerbrock, Ruth; Flessa, Heinz

    2013-09-01

    Biomass carbonized via hydrothermal carbonization (HTC) yields a liquid and a carbon (C)-rich solid called hydrochar. In soil, hydrochars may act as fertilizers and promote C sequestration. We assumed that the chemical composition of the raw material (woodchips, straw, grass cuttings, or digestate) determines the properties of the liquid and solid HTC products, including their degradability. Additionally, we investigated whether easily mineralizable organic components adsorbed on the hydrochar surface influence the degradability of the hydrochars and could be removed by repetitive washing. Carbon mineralization was measured as CO production over 30 d in aerobic incubation experiments with loamy sand. Chemical analysis revealed that most nutrients were preferably enriched in the liquid phase. The C mineralization of hydrochars from woodchips (2% of total C added), straw (3%), grass (6%), and digestate (14%) were dependent on the raw material carbonized and were significantly lower (by 60-92%; < 0.05) than the mineralization of the corresponding raw materials. Washing of the hydrochars significantly decreased mineralization of digestate-hydrochar (up to 40%) but had no effect on mineralization rates of the other three hydrochars. Variations in C mineralization between different hydrochars could be explained by multiple factors, including differences in the O/C-H/C ratios, C/N ratios, lignin content, amount of oxygen-containing functional groups, and pH. In contrast to the solids, the liquid products were highly degradable, with 61 to 89% of their dissolved organic C being mineralized within 30 d. The liquids may be treated aerobically (e.g., for nutrient recovery).

  14. Powering hydrothermal activity on Enceladus

    Science.gov (United States)

    Tobie, Gabriel; Choblet, Gael; Sotin, Christophe; Behounkova, Marie; Cadek, Ondrej; Postberg, Frank; Soucek, Ondrej

    2017-04-01

    A series of evidence gathered by the Cassini spacecraft indicates that the intense activity at the South Pole of Saturn's moon Enceladus is related to a subsurface salty water reservoir associated with seafloor hydrothermal activity (Hsu et al. 2015, Waite et al. 2017). The observation of an elevated libration implies that this reservoir is global with a thin ice shell (20-25 km in average (Thomas et al. 2016) and 90 °C) mostly in the polar regions, explaining strongly localized ice shell thinning. Owing to strong dissipation in Saturn (Lainey et al. 2017), we show that circulation of hot waters in the core may last at least 20-25 million years and that 10 to 100% of the oceanic volume may be processed in the core at temperature higher than 90°C on this timescale. Whether this has been sufficient for the emergence of life can be explored by future spacecraft missions (Mitri et al., this meeting; Lunine et al. 2017).

  15. Mineralogy and geochemistry of the No. 6 Coal (Pennsylvanian) in the Junger Coalfield, Ordos Basin, China

    Science.gov (United States)

    Dai, S.; Ren, D.; Chou, C.-L.; Li, S.; Jiang, Y.

    2006-01-01

    This paper discusses the mineralogy and geochemistry of the No. 6 Coal (Pennsylvanian) in the Junger Coalfield, Ordos Basin, China. The results show that the vitrinite reflectance (0.58%) is lowest and the proportions of inertinite and liptinite (37.4% and 7.1%, respectively) in the No. 6 Coal of the Junger Coalfield are highest among all of the Late Paleozoic coals in the Ordos Basin. The No. 6 Coal may be divided vertically into four sections based on their mineral compositions and elemental concentrations. A high boehmite content (mean 6.1%) was identified in the No. 6 Coal. The minerals associated with the boehmite in the coal include goyazite, rutile, zircon, and Pb-bearing minerals (galena, clausthalite, and selenio-galena). The boehmite is derived from weathered and oxidized bauxite in the weathered crust of the underlying Benxi Formation (Pennsylvanian). A high Pb-bearing mineral content of samples ZG6-2 and ZG6-3 is likely of hydrothermal origin. The No. 6 coal is enriched in Ga (44.8 ??g/g), Se (8.2 ??g/g), Sr (423 ??g/g), Zr (234 ??g/g), REEs (193.3 ??g/g), Hg (0.35 ??g/g), Pb (35.7 ??g/ g), and Th (17.8 ??g/g). Gallium and Th in the No. 6 Coal mainly occur in boehmite, and the Pb-bearing selenide and sulfide minerals contribute not only to Se and Pb contents in the coal, but also probably to Hg content. A high Zr content is attributed to the presence of zircon, and Sr is related to goyazite. The REEs in the coal are supplied from the sediment-source region, and the REEs leached from the adjacent partings by groundwater. ?? 2005 Elsevier B.V. All rights reserved.

  16. Mineralogy and geochemistry of the No. 6 Coal (Pennsylvanian) in the Junger Coalfield, Ordos Basin, China

    Energy Technology Data Exchange (ETDEWEB)

    Dai, Shifeng [Key Laboratory of Resource Exploration Research of Hebei Province, Handan 056038 (China); Ren, Deyi; Li, Shengsheng; Jiang, Yaofa [China University of Mining and Technology, D11, Xueyuan Road, Haidian District, Beijing 100083 (China); Chou, Chen-Lin [Illinois State Geological Survey (Emeritus), 615 East Peabody Drive, Champaign, IL 61820 (United States)

    2006-04-03

    This paper discusses the mineralogy and geochemistry of the No. 6 Coal (Pennsylvanian) in the Junger Coalfield, Ordos Basin, China. The results show that the vitrinite reflectance (0.58%) is lowest and the proportions of inertinite and liptinite (37.4% and 7.1%, respectively) in the No. 6 Coal of the Junger Coalfield are highest among all of the Late Paleozoic coals in the Ordos Basin. The No. 6 Coal may be divided vertically into four sections based on their mineral compositions and elemental concentrations. A high boehmite content (mean 6.1%) was identified in the No. 6 Coal. The minerals associated with the boehmite in the coal include goyazite, rutile, zircon, and Pb-bearing minerals (galena, clausthalite, and selenio-galena). The boehmite is derived from weathered and oxidized bauxite in the weathered crust of the underlying Benxi Formation (Pennsylvanian). A high Pb-bearing mineral content of samples ZG6-2 and ZG6-3 is likely of hydrothermal origin. The No. 6 coal is enriched in Ga (44.8 {mu}g/g), Se (8.2 {mu}g/g), Sr (423 {mu}g/g), Zr (234 {mu}g/g), REEs (193.3 {mu}g/g), Hg (0.35 {mu}g/g), Pb (35.7 {mu}g/g), and Th (17.8 {mu}g/g). Gallium and Th in the No. 6 Coal mainly occur in boehmite, and the Pb-bearing selenide and sulfide minerals contribute not only to Se and Pb contents in the coal, but also probably to Hg content. A high Zr content is attributed to the presence of zircon, and Sr is related to goyazite. The REEs in the coal are supplied from the sediment-source region, and the REEs leached from the adjacent partings by groundwater. (author)

  17. Subtask 3.16 - Low-Cost Coal-Water Fuel for Entrained-Flow Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, C.M.

    1997-10-01

    The specific objective of this research project is to assess the potential process efficiency and pollution control benefits that may occur by applying the hydrothermal, or hot water-drying, process to low-rank coals as related to entrained-flow gasification systems. Project emphasis is on identifying more efficient coal dewatering and CWF formulation methods prior to gasification. A favorable estimate of incremental cost for integrated hydrothermal drying depends, in part, on increasing the particle size of the feed coal from minus 100 to minus 28 mesh for the purpose of simplifying the slurry concentration process. Two options will be reviewed for dewatering or concentrating the processed slurry: (1) repressurization and then concentration with sieve bends or (2) partial dewatering at system pressure with hydroclones. Both have their own merits, sieve bends being a low-cost alternative, while hydroclone application would not require additional pumping sections prior to gasification. Various CWF samples with different particle-size distributions and solids concentrations will be sent to equipment vendors for application review. Also, EERC cost models will be used to calculate the integral cost of adding the partial dewatering to the hydrothermal technology for a commercial-size facility.

  18. Tianjin smokeless coal project

    Energy Technology Data Exchange (ETDEWEB)

    Reuvid, J.M. [Information Services Trans Europe B.V. (Netherlands)

    1997-08-01

    A feasibility study was started to evaluate the technical barriers and the commercial possibilities of forming a joint venture between the Tianjin Coal and Building Materials Company (TCBM) and Coalite hereby coal from the Shanxi coalfields would be converted by the Coalite process to a smokeless fuel, which would reduce Taijin`s heavy level of air pollution. The project was, however, aborted in October 1996 because Tianjin had been allocated a connection to domestic natural gas fields. The project did identify the suitability of coals from the Shanxi coalfields for the Coalite process and the likely market acceptability of the product. It demonstrated the necessity of establishing good contacts in the relevant industries and Ministries in China - and highlighted the benefits of an effective collaboration between three types of organisation - an investment and consultancy company with expertise in China, a UK clean coal technology company, and a local consultant. 4 apps.

  19. Coal Mine Permit Boundaries

    Data.gov (United States)

    Earth Data Analysis Center, University of New Mexico — ESRI ArcView shapefile depicting New Mexico coal mines permitted under the Surface Mining Control and Reclamation Act of 1977 (SMCRA), by either the NM Mining these...

  20. Proximate analysis of coal

    Energy Technology Data Exchange (ETDEWEB)

    Donahue, C.J.; Rais, E.A. [University of Michigan, Dearborn, MI (USA)

    2009-02-15

    This lab experiment illustrates the use of thermogravimetric analysis (TGA) to perform proximate analysis on a series of coal samples of different rank. Peat and coke are also examined. A total of four exercises are described. These are dry exercises as students interpret previously recorded scans. The weight percent moisture, volatile matter, fixed carbon, and ash content are determined for each sample and comparisons are made. Proximate analysis is performed on a coal sample from a local electric utility. From the weight percent sulfur found in the coal (determined by a separate procedure the Eschka method) and the ash content, students calculate the quantity of sulfur dioxide emissions and ash produced annually by a large coal-fired electric power plant.

  1. Coal terminal directory

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-06-15

    The directory gives a comprehensive listing of the world's coal terminals, in a total of 50 countries including information on throughput, facilities, storage capacity, and vessel size limitation.

  2. Coal log pipeline for twenty-first century coal transportation

    Energy Technology Data Exchange (ETDEWEB)

    Marrero, T.R.; Liu, H.; Wilkinson, J.E. [Univ. of Missouri, Columbia, MO (United States)

    1998-12-31

    During the first years of the 21st century coal log pipeline (CLP) technology will be available for long-distance coal transportation. The purpose of this report is to present the state-of-the-art of coal log pipeline technology. Some recent developments are as follows: optimization of coal log compaction procedures, construction of a unique coal log prototype manufacturing machine, and its testing. Coal log abrasion while transported in water-filled pipelines is also discussed. A CLP pilot plant is currently under construction at the University of Missouri. For certain routes in the US a CLP system appears to be cost-competitive.

  3. Prospects for coal and clean coal technology in the Philippines

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-03-15

    This report examines the current energy outlook for the Philippines in regard not only to coal but also other energy resources. The history of the power sector, current state of play and future plans to meet the increasing energy demand from a growing population are discussed. There is also analysis of the trends for coal demand and production, imports and exports of coal and the types of coal-fired power stations that have been built. This includes examination of the legislation involving coal and the promotion of clean coal technologies.

  4. Research and development to prepare and characterize robust coal/biomass mixtures for direct co-feeding into gasification systems

    Energy Technology Data Exchange (ETDEWEB)

    Felix, Larry [Inst. Of Gas Technology, Des Plaines, IL (United States); Farthing, William [Inst. Of Gas Technology, Des Plaines, IL (United States); Hoekman, S. Kent [Inst. Of Gas Technology, Des Plaines, IL (United States)

    2014-12-31

    This project was initiated on October 1, 2010 and utilizes equipment and research supported by the Department of Energy, National Energy Technology Laboratory, under Award Number DE- FE0005349. It is also based upon previous work supported by the Department of Energy, National Energy Technology Laboratory, under Award Numbers DOE-DE-FG36-01GOl1082, DE-FG36-02G012011 or DE-EE0000272. The overall goal of the work performed was to demonstrate and assess the economic viability of fast hydrothermal carbonization (HTC) for transforming lignocellulosic biomass into a densified, friable fuel to gasify like coal that can be easily blended with ground coal and coal fines and then be formed into robust, weather-resistant pellets and briquettes. The specific objectives of the project include: • Demonstration of the continuous production of a uniform densified and formed feedstock from loblolly pine (a lignocellulosic, short rotation woody crop) in a hydrothermal carbonization (HTC) process development unit (PDU). • Demonstration that finely divided bituminous coal and HTC loblolly pine can be blended to form 90/10 and 70/30 weight-percent mixtures of coal and HTC biomass for further processing by pelletization and briquetting equipment to form robust weather resistant pellets and/or briquettes suitable for transportation and long term storage. • Characterization of the coal-biomass pellets and briquettes to quantify their physical properties (e.g. flow properties, homogeneity, moisture content, particle size and shape), bulk physical properties (e.g. compressibility, heat transfer and friability) and assess their suitability for use as fuels for commercially-available coal gasifiers. • Perform economic analyses using Aspen-based process simulations to determine the costs for deploying and operating HTC processing facilities for the production of robust coal/biomass fuels suitable for fueling commercially-available coal-fired gasifiers. This Final Project Scientific

  5. Contact sensitivity to newsprint: a rare manifestation of coal tar allergy

    Energy Technology Data Exchange (ETDEWEB)

    Illchyshyn, A.; Cartwright, P.H.; Smith, A.G.

    1987-07-01

    Contact dermatitis due to coal tar is infrequently reported in spite of the fact that it consists of a mixture of 10,000 constituents, and is still often used to treat both eczema and psoriasis. Discusses patient with coal tar sensitivity in whom the source of exacerbation of her dermatitis is shown to be newsprint, a common product containing coal tar-derived material. 6 refs.

  6. Coal facies studies in Canada

    Energy Technology Data Exchange (ETDEWEB)

    Kalkreuth, Wolfgang D. [Laboratorio de Carvao e de Petrologia Organica, Instituto de Geociencias, Universidade Federal do Rio Grande do Sul (UFRGS), Av. Bento Goncalves, 9500, 91501-970 Porto Alegre, RS (Brazil)

    2004-04-23

    The present study is a compilation of published data on coal facies studies in Canada based on coal petrological and other methods. The geological age of the coals range from the Devonian coal deposits in Arctic Canada to coals of Tertiary age in the Western Canada Sedimentary Basin, intermontane British Columbia and Arctic Canada. In terms of rank, the coal deposits studied range from lignite to low volatile bituminous. Coal petrological methods include maceral and microlithotype analyses, frequently integrated with data from palynological and geochemical analyses. Most recently, a number of studies have applied sequence stratigraphic concepts to the coal-bearing strata including the interpretation of coal petrological data in the context of this concept.

  7. COAL QUALITY CONTROL

    Institute of Scientific and Technical Information of China (English)

    孟祥瑞

    1998-01-01

    Coal storing and loading have much more influence on coal quality. In the paper, a goalprogramming model has been constructed to determine the ideal quantity extracting from stockpileand silos and a quality control model is inferred under the guidance of maximum theory ofdispersed number and practice methods are given to meet production demand, with which a coalmine has achieved a better tech-economic result.

  8. American coal imports 2015

    Energy Technology Data Exchange (ETDEWEB)

    Frank Kolojeski [TransGlobal Ventures Corp. (United States)

    2007-09-15

    As 2007 ends, the US coal industry passes two major milestones - the ending of the Synfuel tax break, affecting over 100M st annually, and the imposition of tighter and much more expensive safety measures, particularly in deep mines. Both of these issues, arriving at a time of wretched steam coal price levels, promise to result in a major shake up in the Central Appalachian mining sector. The report utilizes a microeconomic regional approach to determine whether either of these two schools of thought have any validity. Transport, infrastructure, competing fuels and regional issues are examined in detail and this forecasts estimates coal demand and imports on a region by region basis for the years 2010 and 2015. Some of the major highlights of the forecast are: Import growth will be driven by steam coal demand in the eastern and southern US; Transport will continue to be the key driver - we believe that inland rail rates will deter imports from being railed far inland and that the great majority of imports will be delivered directly by vessel, barge or truck to end users; Colombian coal will be the overwhelmingly dominant supply source and possesses a costs structure to enable it to compete with US-produced coal in any market conditions; Most of the growth will come from existing power plants - increasing capacity utilization at existing import facilities and other plants making investments to add imports to the supply portfolio - the growth is not dependent upon a lot of new coal fired capacity being built. Contents of the report are: Key US market dynamics; International supply dynamics; Structure of the US coal import market; and Geographic analysis.

  9. Indicators of coal metamorphism

    Energy Technology Data Exchange (ETDEWEB)

    Proskuryakov, A.E.

    1982-06-01

    Important in determining metamorphism of coal is the reliability of indicators of coalification. Both the reflection of vitrinite and emission of volatile matter have been used for this purpose. To determine which indicator more accurately characterizes metamorphism of coal, their conformity to the following demands was established: 1. uniformity in direction of change of parameters with degree of metamorphism; 2. independence of the indicator of the genetic characteristics of coal (petrographic composition, reduction and oxidation of coal); 3. sensitivity of indicator. Both indicators conform to the first requirement. Emission of volatile substance decreases and reflective capacity of vitrinite increases uniformly with degree of metamorphism. However, the reflectivity of vitrinite is not influenced by petrographic composition of coals and is less dependent on the oxidation and reduction of coal than emission of volatile matter. It is also a more sensitive indicator distinguishing more degrees of metamorphism than emission of volatile matter. Reflectivity of vitrinite is a more reliable indicator of metamorphism than emission of volatile matter. However, in many laboratories this indicator is not measured with sufficient accuracy. To correct this, measuring equipment must be standardized.

  10. Coal in Bulgaria

    Energy Technology Data Exchange (ETDEWEB)

    McConville, L.; Broadbent, J.; Rousaki, K.

    1999-01-01

    Bulgaria`s national energy strategy includes plans to restructure the energy sector by introducing competition and privatisation, to promote energy efficiency and environmental protection and to prepare the country for integration into the EU energy market. Energy prices are still under government control and coal mining is heavily subsidised. Bulgaria is a major producer of coal, all of which is consumed locally. Most of the domestic production is low quality lignite used for electricity generation. Demand for hard coal is met by imports, mainly from the former USSR and the USA. Bulgaria generates almost half of its electricity needs from coal. Total reserves of lignite are estimated at 2.5 Gt. Coal production declined between 1987 and 1991 reflecting the economic disturbance following the break up of the USSR. In 1996, production was 32 Mt. The mining industry is being restructured as Bulgaria is slowly moving from a centrally-controlled economy to a market-based economy. Environmental damage as a result of coal production has been serious in Bulgaria, due to the use of low grade high sulphur content lignite. 84 refs., 10 figs., 9 tabs.

  11. The effects of moderate coal cleaning on the microbial removal of organic sulfur. [Rhodococcuc rhodochrous

    Energy Technology Data Exchange (ETDEWEB)

    Srivastava, V.J.

    1991-01-01

    The purpose of this project is to investigate the possibilities of developing an integrated physical/chemical/microbial process for the precombustion removal of sulfur from coal. An effective pre- combustion coal desulfurization process should ideally be capable of removing both organic and inorganic sulfur. A variety of techniques exist for the removal of inorganic sulfur from coal, but there is currently no cost-effective method for the pre-combustion removal of organic sulfur. Recent developments have demonstrated that microorganisms are capable of specifically cleaving carbon-sulfur bonds and removing substantial amounts of organic sulfur from coal. However, lengthy treatment times are required. Moreover, the removal of organic sulfur form coal by microorganisms is hampered by the fact that, as a solid substrate, it is difficult to bring microorganisms in contact with the entirety of a coal sample. This study will examine the suitability of physically/chemically treated coal sample for subsequent biodesulfurization. Physical/chemical processes primarily designed for the removal of pyritic sulfur may also cause substantial increases in the porosity and surface area of the coal which may facilitate the subsequent removal of organic sulfur by microoganisms. During the current quarter, coal samples that have been chemically pretreated with methanol, ammonia, and isopropanol were examined for the removal of organic sulfur by the microbial culture IGTS8, an assay for the presence of protein in coal samples was developed, and a laboratory-scale device for the explosive comminution of coal was designed and constructed.

  12. Tandem fluidized bed elutriator-Pneumatic classification of coal particles in a fluidized conveyer

    Institute of Scientific and Technical Information of China (English)

    Zhouen Liu; Yimin Xie; Yin Wang; Jian Yu; Shiqiu Gao; Guangwen Xu

    2012-01-01

    Coal moisture control (CMC) in coking process,which reduces coal moisture before loading the coal into the coke oven,allows substantial reduction in coking energy consumption and increase in coke productivity.The technology is seeking to integrate the coal classification,thus calling it the coal classifying moisture control (CCMC),to separate the fine and coarse coal fractions in the CMC process so that the downstream coal crushing can only treat the coarse fraction.CCMC adopts a reactor that integrates a fiuidized bottom section and a pneumatic conveying top section.The present work investigates the pneumatic classification behavior in a laboratory CCMC reactor with such a configuration by removing the coal fraction below a given size (e.g.,3.0 mm) from a 0 to 20,0 mm coal feed.The results show that the coal classification were dominated by the gas velocity in the top conveying section,and the required gas velocity for ensuring the maximal degree of removing a fine coal fraction could be roughly predicted by the Richardson and Zaki equation.The effect of bottom fluidization on the performance of CCMC is also examined.

  13. Journal of Coal Science & Engineering(China)

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    @@ Guide for Authors Journal of Coal Science & Engineering(English Edition), a comprehensive academic periodical of the China Coal Society, covers the fields of coal science and technology including coal geology, exploration,mine survey, mine project assessment, mine construction, coal mining, coal mine electrical machinery,mine safety, coal processing and utilization, coal mine environmental protection, etc. It reflects the latest research results and findings.

  14. Trace elements in coal ash

    Science.gov (United States)

    Deonarine, Amrika; Kolker, Allan; Doughten, Michael W.

    2015-01-01

    Coal ash is a residual waste product primarily produced by coal combustion for electric power generation. Coal ash includes fly ash, bottom ash, and flue-gas desulfurization products (at powerplants equipped with flue-gas desulfurization systems). Fly ash, the most common form of coal ash, is used in a range of products, especially construction materials. A new Environmental Protection Agency ruling upholds designation of coal ash as a non-hazardous waste under Subtitle D of the Resource Conservation and Recovery Act, allowing for the continued beneficial use of coal ash and also designating procedures and requirements for its storage.

  15. Coal facies studies in Spain

    Energy Technology Data Exchange (ETDEWEB)

    Suarez-Ruiz, Isabel [INCAR (CSIC), Ap. Co., 73, 33080, Oviedo (Spain); Jimenez, Amalia [Geology, University of Oviedo, 33005, Oviedo (Spain)

    2004-04-23

    This work is a synthesis of the distribution of the main coal basins and sub-basins in Spain as well as the research carried out on their coal facies. The coal fields are distributed through the Paleozoic (mainly Pennsylvanian), Mesozoic (Cretaceous) and Cenozoic times. Peats also exist in the southeast Spain (Granada area), although these types of deposits are not included in this review. Spanish coal basins are both of a paralic and intramontane type and the coal rank is highly variable, from lignite in the case of the younger coal seams to anthracite for those of Carboniferous age.

  16. Coal 99; Kol 99

    Energy Technology Data Exchange (ETDEWEB)

    Sparre, C.

    2000-07-01

    The following report deals with the use of coal and coke during 1998. Some information about techniques, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used. The use of steam coal for heating purposes during 1998 was 680 000 tons and somewhat lower than in 1997. The extremely high figures of 1996 were due to twice the production of electricity because of lack of waterpower. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generating plants. During the top year 1987 coal was used in 18 hot water plants and 11 co-generation plants. During 1998 these figures are 1 and 8. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. Steel-works, however, increase their use of steam coal in order to replace the more expensive coke. The import of metallurgical coal in 1998 was 1.6 mill tons like the year before. 1.1 mill tons of coke were produced. The coke consumption in the industry was 1.4 mill tons from which 0.3 mill tons were imported. Several other plants have plans to replace the coal with forest fuels, waste fuels and NG. Even the biggest plant, Vaesteraas, has ordered a block for bio fuels. Helsingborg has started to use wood pellets. The pellets replace most of the coal for the heat production in the co-generation plant. Norrkoeping Kraft AB has put a fluid bed boiler for various fuels into operation, leading to more than half the coal consumption compared with previous years. They have also rebuilt one of their travelling grates for bio fuels. Stockholm Energi, Haesselbyverket, has invested

  17. Peptide synthesis in early earth hydrothermal systems

    Science.gov (United States)

    Lemke, K.H.; Rosenbauer, R.J.; Bird, D.K.

    2009-01-01

    We report here results from experiments and thermodynamic calculations that demonstrate a rapid, temperature-enhanced synthesis of oligopeptides from the condensation of aqueous glycine. Experiments were conducted in custom-made hydrothermal reactors, and organic compounds were characterized with ultraviolet-visible procedures. A comparison of peptide yields at 260??C with those obtained at more moderate temperatures (160??C) gives evidence of a significant (13 kJ ?? mol-1) exergonic shift. In contrast to previous hydrothermal studies, we demonstrate that peptide synthesis is favored in hydrothermal fluids and that rates of peptide hydrolysis are controlled by the stability of the parent amino acid, with a critical dependence on reactor surface composition. From our study, we predict that rapid recycling of product peptides from cool into near-supercritical fluids in mid-ocean ridge hydrothermal systems will enhance peptide chain elongation. It is anticipated that the abundant hydrothermal systems on early Earth could have provided a substantial source of biomolecules required for the origin of life. Astrobiology 9, 141-146. ?? 2009 Mary Ann Liebert, Inc. 2009.

  18. Method of extracting coal from a coal refuse pile

    Science.gov (United States)

    Yavorsky, Paul M.

    1991-01-01

    A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

  19. Underground coal gasification - the acceptable face of coal mining?

    Energy Technology Data Exchange (ETDEWEB)

    Dryburgh, P.

    2009-11-15

    There is growing interest in underground coal gasification, whereby energy is accessed from coal in a cleaner way than traditional combustion methods. The paper looks at the benefits of UCG. 1 fig., 1 photo.

  20. Raton Coal Basin boundary, 1999 Coal Resource Assessment

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This ArcView shape file contains a polygon representing the extent of the Raton Coal Basin boundary. This theme was created specifically for the National Coal...

  1. Denver Coal Basin boundary from 1999 National Coal Resource Assessment

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This ArcView shapefile contains a polygon representing the extent of the Denver coal basin boundary. This theme was created specifically for the National Coal...

  2. Coal recovery from a coal waste dump

    Directory of Open Access Journals (Sweden)

    Rozanski Zenon

    2016-01-01

    Full Text Available The possibilities and efficiency of coal recovery from the waste material located at the Central Coal Waste Dump in Poland were presented in this paper. The waste material includes significant amount of fly ash. Research conducted into determination of energetic properties of such wastes showed that the average ash content was 75.75% and the average gross calorific value was 7.81 MJ/kg. Coal was gravitationally separated from the waste material in a pulsatory jig and in a spiral washer including size fractions: 30-5 and 8-0 mm (this was crushed to a size <3.2 mm, respectively. The application of the pulsatory jig (pulse classifier allowed to obtain a high-quality energetic concentrate with the ash content lower than 12% and the gross calorific value higher than 26 MJ/kg (with average yield 7.8%. The spiral separator gave much worse results. The average gross calorific value for the concentrate was 11.6 MJ/kg, with the high ash content 56.5% and yield approximately 26%.

  3. Coal 99; Kol 99

    Energy Technology Data Exchange (ETDEWEB)

    Sparre, C.

    2000-07-01

    The following report deals with the use of coal and coke during 1998. Some information about techniques, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used. The use of steam coal for heating purposes during 1998 was 680 000 tons and somewhat lower than in 1997. The extremely high figures of 1996 were due to twice the production of electricity because of lack of waterpower. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generating plants. During the top year 1987 coal was used in 18 hot water plants and 11 co-generation plants. During 1998 these figures are 1 and 8. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. Steel-works, however, increase their use of steam coal in order to replace the more expensive coke. The import of metallurgical coal in 1998 was 1.6 mill tons like the year before. 1.1 mill tons of coke were produced. The coke consumption in the industry was 1.4 mill tons from which 0.3 mill tons were imported. Several other plants have plans to replace the coal with forest fuels, waste fuels and NG. Even the biggest plant, Vaesteraas, has ordered a block for bio fuels. Helsingborg has started to use wood pellets. The pellets replace most of the coal for the heat production in the co-generation plant. Norrkoeping Kraft AB has put a fluid bed boiler for various fuels into operation, leading to more than half the coal consumption compared with previous years. They have also rebuilt one of their travelling grates for bio fuels. Stockholm Energi, Haesselbyverket, has invested

  4. Impact of nongray multiphase radiation in pulverized coal combustion

    Science.gov (United States)

    Roy, Somesh; Wu, Bifen; Modest, Michael; Zhao, Xinyu

    2016-11-01

    Detailed modeling of radiation is important for accurate modeling of pulverized coal combustion. Because of high temperature and optical properties, radiative heat transfer from coal particles is often more dominant than convective heat transfer. In this work a multiphase photon Monte Carlo radiation solver is used to investigate and to quantify the effect of nongray radiation in a laboratory-scale pulverized coal flame. The nongray radiative properties of carrier phase (gas) is modeled using HITEMP database. Three major species - CO, CO2, and H2O - are treated as participating gases. Two optical models are used to evaluate radiative properties of coal particles: a formulation based on the large particle limit and a size-dependent correlation. Effect of scattering due to coal particle is also investigated using both isotropic scattering and anisotropic scattering using a Henyey-Greenstein function. Lastly, since the optical properties of ash is very different from that of coal, the effect of ash content on the radiative properties of coal particle is examined. This work used Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by National Science Foundation Grant Number ACI-1053575.

  5. Coal fires in Indonesia

    Energy Technology Data Exchange (ETDEWEB)

    Whitehouse, Alfred E.; Mulyana, Asep A.S. [Office of Surface Mining/Ministry of Energy and Mineral Resources Coal Fire Project, Ministry of Energy and Mineral Resources, Agency for Training and Education, Jl. Gatot Subroto, Kav. 49, Jakarta 12950 (Indonesia)

    2004-07-12

    Indonesia's fire and haze problem is increasingly being ascribed to large-scale forest conversion and land clearing activities making way for pulpwood, rubber and oil palm plantations. Fire is the cheapest tool available to small holders and plantation owners to reduce vegetation cover and prepare and fertilize extremely poor soils. Fires that escaped from agricultural burns have ravaged East Kalimantan forests on the island of Borneo during extreme drought periods in 1982-1983, 1987, 1991, 1994 and 1997-1998. Estimates based on satellite data and ground observations are that more than five million hectares were burned in East Kalimantan during the 1997/1998 dry season. Not only were the economic losses and ecological damage from these surface fires enormous, they ignited coal seams exposed at the ground surface along their outcrops.Coal fires now threaten Indonesia's shrinking ecological resources in Kutai National Park and Sungai Wain Nature Reserve. Sungai Wain has one of the last areas of unburned primary rainforest in the Balikpapan-Samarinda area with an extremely rich biodiversity. Although fires in 1997/1998 damaged nearly 50% of this Reserve and ignited 76 coal fires, it remains the most valuable water catchment area in the region and it has been used as a reintroduction site for the endangered orangutan. The Office of Surface Mining provided Indonesia with the capability to take quick action on coal fires that presented threats to public health and safety, infrastructure or the environment. The US Department of State's Southeast Asia Environmental Protection Initiative through the US Agency for International Development funded the project. Technical assistance and training transferred skills in coal fire management through the Ministry of Energy and Mineral Resource's Training Agency to the regional offices; giving the regions the long-term capability to manage coal fires. Funding was also included to extinguish coal fires as

  6. Mercury and trace element contents of Donbas coals and associated mine water in the vicinity of Donetsk, Ukraine

    Energy Technology Data Exchange (ETDEWEB)

    Kolker, Allan [U.S. Geological Survey, 956 National Center, Reston, VA 20192 (United States); Panov, Boris S.; Panov, Yuri B.; Korchemagin, Viktor A.; Shendrik, Tatiana [Department of Mineral Deposits and Ecological Geology, Donetsk National Technical University, Donetsk, 83000 (Ukraine); Landa, Edward R.; Conko, Kathryn M. [U.S. Geological Survey, 430 National Center, Reston, VA 20192 (United States); McCord, Jamey D. [U.S. Geological Survey, 973 Denver Federal Center, Denver, CO 80225 (United States)

    2009-08-01

    Mercury-rich coals in the Donets Basin (Donbas region) of Ukraine were sampled in active underground mines to assess the levels of potentially harmful elements and the potential for dispersion of metals through use of this coal. For 29 samples representing c{sub 11} to m{sub 3} Carboniferous coals, mercury contents range from 0.02 to 3.5 ppm (whole-coal dry basis). Mercury is well correlated with pyritic sulfur (0.01 to 3.2 wt.%), with an r{sup 2} of 0.614 (one outlier excluded). Sulfides in these samples show enrichment of minor constituents in late-stage pyrite formed as a result of interaction of coal with hydrothermal fluids. Mine water sampled at depth and at surface collection points does not show enrichment of trace metals at harmful levels, indicating pyrite stability at subsurface conditions. Four samples of coal exposed in the defunct open-cast Nikitovka mercury mines in Gorlovka have extreme mercury contents of 12.8 to 25.5 ppm. This coal was formerly produced as a byproduct of extracting sandstone-hosted cinnabar ore. Access to these workings is unrestricted and small amounts of extreme mercury-rich coal are collected for domestic use, posing a limited human health hazard. More widespread hazards are posed by the abandoned Nikitovka mercury processing plant, the extensive mercury mine tailings, and mercury enrichment of soils extending into residential areas of Gorlovka. (author)

  7. Mercury and trace element contents of Donbas coals and associated mine water in the vicinity of Donetsk, Ukraine

    Science.gov (United States)

    Kolker, A.; Panov, B.S.; Panov, Y.B.; Landa, E.R.; Conko, K.M.; Korchemagin, V.A.; Shendrik, T.; McCord, J.D.

    2009-01-01

    Mercury-rich coals in the Donets Basin (Donbas region) of Ukraine were sampled in active underground mines to assess the levels of potentially harmful elements and the potential for dispersion of metals through use of this coal. For 29 samples representing c11 to m3 Carboniferous coals, mercury contents range from 0.02 to 3.5 ppm (whole-coal dry basis). Mercury is well correlated with pyritic sulfur (0.01 to 3.2 wt.%), with an r2 of 0.614 (one outlier excluded). Sulfides in these samples show enrichment of minor constituents in late-stage pyrite formed as a result of interaction of coal with hydrothermal fluids. Mine water sampled at depth and at surface collection points does not show enrichment of trace metals at harmful levels, indicating pyrite stability at subsurface conditions. Four samples of coal exposed in the defunct open-cast Nikitovka mercury mines in Gorlovka have extreme mercury contents of 12.8 to 25.5 ppm. This coal was formerly produced as a byproduct of extracting sandstone-hosted cinnabar ore. Access to these workings is unrestricted and small amounts of extreme mercury-rich coal are collected for domestic use, posing a limited human health hazard. More widespread hazards are posed by the abandoned Nikitovka mercury processing plant, the extensive mercury mine tailings, and mercury enrichment of soils extending into residential areas of Gorlovka.

  8. Geological Controls on Mineralogy and Geochemistry of an Early Permian Coal from the Songshao Mine, Yunnan Province, Southwestern China

    Directory of Open Access Journals (Sweden)

    Ruixue Wang

    2016-07-01

    Full Text Available This paper discusses the content, distribution, modes of occurrence, and enrichment mechanism of mineral matter and trace elements of an Early Permian coal from Songshao (Yunnan Province, China by means of coal-petrological, mineralogical, and geochemical techniques. The results show that the Songshao coal is characterized by high total and organic sulfur contents (3.61% and 3.87%, respectively. Lithium (170.39 μg/g and Zr (184.55 μg/g are significantly enriched in the Songshao coal, and, to a lesser extent, elements such as Hg, La, Ce, Nd, Th, Sr, Nb, Sn, Hf, V, and Cr are also enriched. In addition to Hg and Se that are enriched in the roof and floor strata of the coal seam, Li, La, Ce, Pr, Nd, Sm, Gd, Y, Cd, and Sb are slightly enriched in these host rocks. Compared to the upper continental crust, rare earth elements and yttrium in the host rocks and coal samples are characterized by a light-REE enrichment type and have negative Eu, positive Ce and Gd anomalies. Major minerals in the samples of coal, roof, and floor are boehmite, clay minerals (kaolinite, illite, and mixed layer illite-smectite, pyrite, and anatase. Geochemical and mineralogical anomalies of the Songshao coal are attributed to hydrothermal fluids, seawater, and sediment-source rocks.

  9. From in situ coal to the final coal product: A case study of the Danville Coal Member (Indiana)

    Science.gov (United States)

    Mastalerz, Maria; Padgett, P.L.

    1999-01-01

    A surface coal mine operation and preparation plant in southwestern Indiana was sampled to examine variations in coal quality and coal petrography parameters for the Danville Coal Member of the Dugger Formation (Pennsylvanian-Desmoinesian, Westphalian D). Representative samples from in situ coal, preparation plant feeds, and a final coal product were collected in order to compare coal quality, coal petrography, trace element concentrations, and ash chemistry of the coal to those of the product. Coal quality parameters of the in situ samples and various feeds, coarse refuse, and final product were variable. The quality of the final coal product was best predicted by the coal quality of the clean coal feed (from the middle portions of the seam). Some trace element contents, especially lead and arsenic, varied between the coal feeds and the product. Lead contents increased in the feeds and product compared to the channel sample of the raw coal, possibly due to contamination in the handling process.A surface coal mine operation and preparation plant in southwestern Indiana was sampled to examine variations in coal quality and coal petrography parameters for the Danville Coal Member of the Dugger Formation (Pennsylvanian-Desmoinesian, Westphalian D). Representative samples from in situ coal, preparation plant feeds, and a final coal product were collected in order to compare coal quality, coal petrography, trace element concentrations, and ash chemistry of the coal to those of the product. Coal quality parameters of the in situ samples and various feeds, coarse refuse, and final product were variable. The quality of the final coal product was best predicted by the coal quality of the clean coal feed (from the middle portions of the seam). Some trace element contents, especially lead and arsenic, varied between the coal feeds and the product. Lead contents increased in the feeds and product compared to the channel sample of the raw coal, possibly due to contamination in

  10. Coal 95; Kol - 95

    Energy Technology Data Exchange (ETDEWEB)

    Sparre, C.

    1995-12-31

    The report deals with the use of coal and coke in Sweden during 1994. Some information about technology, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used.The use of steam coal for heating purposes has been unchanged during 1994 at a level of 1 Mtons. The production in the cogeneration plants has been constant, but has increased for electricity production. The minor plants have increased their use of forest fuels. The use of steam coal will probably go down in the next years both for heat and cogeneration plants. During the top year 1987 coal was used in 18 hot water and 11 cogeneration plants. 1994 these figures are 3 and 12. Taxes and environmental reasons explain this trend. The use of steam coal in industry has been constant at the level 0.7 Mtons. The import of metallurgical coal in 1993 was 1.6 Mtons, like 1992. Import of 0.3 Mtons of coke gives the total consumption of coke in industry as 1.5 Mtons. the average price of steam coal imported to Sweden was 317 SEK/ton, 3% higher than 1993. All Swedish plants meet their emission limit of dust, SO{sub 2} and NO{sub x} as given by county administrations or concession boards. The cogeneration plants all have some SO{sub 2} removal system. The biggest cogeneration plant (Vaesteraas) has recently invested in a SCR NO{sub x} cleaning system. Most other plants use low NO{sub x} burners or SNR injection systems based on ammonia or urea. 2 figs, 13 tabs.

  11. Industrial symbiosis: corn ethanol fermentation, hydrothermal carbonization, and anaerobic digestion.

    Science.gov (United States)

    Wood, Brandon M; Jader, Lindsey R; Schendel, Frederick J; Hahn, Nicholas J; Valentas, Kenneth J; McNamara, Patrick J; Novak, Paige M; Heilmann, Steven M

    2013-10-01

    The production of dry-grind corn ethanol results in the generation of intermediate products, thin and whole stillage, which require energy-intensive downstream processing for conversion into commercial animal feed products. Hydrothermal carbonization of thin and whole stillage coupled with anaerobic digestion was investigated as alternative processing methods that could benefit the industry. By substantially eliminating evaporation of water, reductions in downstream energy consumption from 65% to 73% were achieved while generating hydrochar, fatty acids, treated process water, and biogas co-products providing new opportunities for the industry. Processing whole stillage in this manner produced the four co-products, eliminated centrifugation and evaporation, and substantially reduced drying. With thin stillage, all four co-products were again produced, as well as a high quality animal feed. Anaerobic digestion of the aqueous product stream from the hydrothermal carbonization of thin stillage reduced chemical oxygen demand (COD) by more than 90% and converted 83% of the initial COD to methane. Internal use of this biogas could entirely fuel the HTC process and reduce overall natural gas usage.

  12. Ageing of low-firing prehistoric ceramics in hydrothermal conditions

    Directory of Open Access Journals (Sweden)

    Petra Zemenová

    2012-03-01

    Full Text Available Remains of a prehistoric ceramic object, a moon-shaped idol from the Bronze Age found in archaeological site Zdiby near Prague in the Czech Republic, were studied especially in terms of the firing temperature. Archaeological ceramics was usually fired at temperatures below 1000 °C. It contained unstable non-crystalline products, residua after calcination of clay components of a ceramic material. These products as metakaolinite can undergo a reverse rehydration to a structure close to kaolinite. The aim of this work was to prove whether the identified kaolinite in archaeological ceramics is a product of rehydration. The model compound containing high amount of kaolinite was prepared in order to follow its changes during calcination and hydrothermal treatment. Archaeological ceramics and the model compound were treated by hydrothermal ageing and studied by XRF, XRD and IR analyses. It was proved that the presence of kaolinite in the border-parts of the archaeological object was not a product of rehydration, but that it originated from the raw materials.

  13. Hydrothermal treatment of electric arc furnace dust.

    Science.gov (United States)

    Yu, Bing-Sheng; Wang, Yuh-Ruey; Chang, Tien-Chin

    2011-06-15

    In this study, ZnO crystals were fabricated from electric arc furnace dust (EAFD) after alkaline leaching, purification and hydrothermal treatment. The effects of temperature, duration, pH, and solid/liquid ratio on ZnO crystal morphology and size were investigated. Results show a high reaction temperature capable of accelerating the dissolution of ZnO precursor, expediting the growth of 1D ZnO, and increasing the L/D ratio in the temperature range of 100-200°C. ZnO crystals with high purity can also be obtained, using the one-step hydrothermal treatment with a baffle that depends on the different solubility of zincite and franklinite in the hydrothermal conditions.

  14. Production of biofuels via hydrothermal conversion

    DEFF Research Database (Denmark)

    Biller, Patrick; Ross, Andrew

    2016-01-01

    Hydrothermal processing has evolved as an alternative processing technology for wet biomass and waste materials in recent years. Using hot-compressed water as a reaction medium at temperatures of 200–500°C, materials with increased energy density can be obtained. The technology is particularly......). Each of these hydrothermal routes results in energy densification by removal of oxygen to produce hydrochar (HTC), biocrude (HTL), or syngas (HTG). The process chemistry and reactions in hydrothermal media are described for each process. Suitable feedstocks and their considerations are reviewed...... as the quality of targeted biofuel is a function of feedstock and operating conditions. The quality of hydrochar influences its uses as a solid fuel while biocrude quality affects its use as a liquid fuel and feedstock for upgrading to drop-in replacement fuels, while HTG produces a syngas rich in either H2...

  15. Hydrothermal processing of radioactive combustible waste

    Energy Technology Data Exchange (ETDEWEB)

    Worl, L.A.; Buelow, S.J.; Harradine, D.; Le, L.; Padilla, D.D.; Roberts, J.H.

    1998-09-01

    Hydrothermal processing has been demonstrated for the treatment of radioactive combustible materials for the US Department of Energy. A hydrothermal processing system was designed, built and tested for operation in a plutonium glovebox. Presented here are results from the study of the hydrothermal oxidation of plutonium and americium contaminated organic wastes. Experiments show the destruction of the organic component to CO{sub 2} and H{sub 2}O, with 30 wt.% H{sub 2}O{sub 2} as an oxidant, at 540 C and 46.2 MPa. The majority of the actinide component forms insoluble products that are easily separated by filtration. A titanium liner in the reactor and heat exchanger provide corrosion resistance for the oxidation of chlorinated organics. The treatment of solid material is accomplished by particle size reduction and the addition of a viscosity enhancing agent to generate a homogeneous pumpable mixture.

  16. Characterization of advanced preprocessed materials (Hydrothermal)

    Energy Technology Data Exchange (ETDEWEB)

    Rachel Emerson; Garold Gresham

    2012-09-01

    The initial hydrothermal treatment parameters did not achieve the proposed objective of this effort; the reduction of intrinsic ash in the corn stover. However, liquid fractions from the 170°C treatments was indicative that some of the elements routinely found in the ash that negatively impact the biochemical conversion processes had been removed. After reviewing other options for facilitating ash removal, sodium-citrate (chelating agent) was included in the hydrothermal treatment process, resulting in a 69% reduction in the physiological ash. These results indicated that chelation –hydrothermal treatment is one possible approach that can be utilized to reduce the overall ash content of feedstock materials and having a positive impact on conversion performance.

  17. Hydrothermally reduced graphene oxide as a supercapacitor

    Science.gov (United States)

    Johra, Fatima Tuz; Jung, Woo-Gwang

    2015-12-01

    The supercapacitance behavior of hydrothermally reduced graphene oxide (RGO) was investigated for the first time. The capacitive behavior of RGO was characterized by using cyclic voltammetry and galvanostatic charge-discharge methods. The specific capacitance of hydrothermally reduced RGO at 1 A/g was 367 F/g in 1 M H2SO4 electrolyte, which was higher than that of RGO synthesized via the hydrazine reduction method. The RGO-modified glassy carbon electrode showed excellent stability. After 1000 cycles, the supercapacitance was 107.7% of that achieved in the 1st cycle, which suggests that RGO has excellent electrochemical stability as a supercapacitor electrode material. The energy density of hydrothermal RGO reached 44.4 W h/kg at a power density of 40 kW/kg.

  18. Depolymerization of sulfated polysaccharides under hydrothermal conditions.

    Science.gov (United States)

    Morimoto, Minoru; Takatori, Masaki; Hayashi, Tetsuya; Mori, Daiki; Takashima, Osamu; Yoshida, Shinichi; Sato, Kimihiko; Kawamoto, Hitoshi; Tamura, Jun-ichi; Izawa, Hironori; Ifuku, Shinsuke; Saimoto, Hiroyuki

    2014-01-30

    Fucoidan and chondroitin sulfate, which are well known sulfated polysaccharides, were depolymerized under hydrothermal conditions (120-180°C, 5-60min) as a method for the preparation of sulfated polysaccharides with controlled molecular weights. Fucoidan was easily depolymerized, and the change of the molecular weight values depended on the reaction temperature and time. The degree of sulfation and IR spectra of the depolymerized fucoidan did not change compared with those of untreated fucoidan at reaction temperatures below 140°C. However, fucoidan was partially degraded during depolymerization above 160°C. Nearly the same depolymerization was observed for chondroitin sulfate. These results indicate that hydrothermal treatment is applicable for the depolymerization of sulfated polysaccharides, and that low molecular weight products without desulfation and deformation of the initial glycan structures can be obtained under mild hydrothermal conditions.

  19. The BGU/CERN solar hydrothermal reactor

    CERN Document Server

    Bertolucci, Sergio; Caspers, Fritz; Garb, Yaakov; Gross, Amit; Pauletta, Stefano

    2014-01-01

    We describe a novel solar hydrothermal reactor (SHR) under development by Ben Gurion University (BGU) and the European Organization for Nuclear Research CERN. We describe in broad terms the several novel aspects of the device and, by extension, of the niche it occupies: in particular, enabling direct off-grid conversion of a range of organic feedstocks to sterile useable (solid, liquid) fuels, nutrients, products using only solar energy and water. We then provide a brief description of the high temperature high efficiency panels that provide process heat to the hydrothermal reactor, and review the basics of hydrothermal processes and conversion taking place in this. We conclude with a description of a simulation of the pilot system that will begin operation later this year.

  20. Metal flux from hydrothermal vents increased by organic complexation

    Science.gov (United States)

    Sander, Sylvia G.; Koschinsky, Andrea

    2011-03-01

    Hydrothermal vents in the sea floor release large volumes of hot, metal-rich fluids into the deep ocean. Until recently, it was assumed that most of the metal released was incorporated into sulphide or oxide minerals, and that the net flux of most hydrothermally derived metals to the open ocean was negligible. However, mounting evidence suggests that organic compounds bind to and stabilize metals in hydrothermal fluids, increasing trace-metal flux to the global ocean. In situ measurements reveal that hydrothermally derived chromium, copper and iron bind to organic molecules on mixing with sea water. Geochemical model simulations based on data from two hydrothermal vent sites suggest that complexation significantly increases metal flux from hydrothermal systems. According to these simulations, hydrothermal fluids could account for 9% and 14% of the deep-ocean dissolved iron and copper budgets respectively. A similar role for organic complexation can be inferred for the hydrothermal fluxes of other metals, such as manganese and zinc.

  1. Estimation of Moisture Content in Coal in Coal Mills

    DEFF Research Database (Denmark)

    Odgaard, Peter Fogh; Mataji, Babak

    2006-01-01

    the moisture content of the coal is proposed based on a simple dynamic energy model of a coal mill, which pulverizes and dries the coal before it is burned in the boiler. An optimal unknown input observer is designed to estimate the moisture content based on an energy balance model. The designed moisture...

  2. Estimation of Moisture Content in Coal in Coal Mills

    DEFF Research Database (Denmark)

    Odgaard, Peter Fogh; Mataji, B.

    the moisture content of the coal is proposed based on a simple dynamic energy model of a coal mill, which pulverizes and dries the coal before it is burned in the boiler. An optimal unknown input observer is designed to estimate the moisture content based on an energy balance model. The designed moisture...

  3. The Comprehensive Utilization Technology of Treating High-Concentration Wastewater with Coal-Water Slurry Technology%利用水煤浆技术处置高浓度废水资源化利用技术

    Institute of Scientific and Technical Information of China (English)

    何先标; 徐永萍; 唐量华; 李亚平; 徐皆

    2015-01-01

    For different kinds of high-concentration wastewaters (hazardous wastes),different analysis methods,standards and treatment processes have been drawn up;in connection with different kinds of hazardous wastes,experiments and studies are carried out to determine standard operating process of slurrying;based on different kinds of hazardous wastes,gasification process operation parameters are studied and adjusted,effectively made comprehensive recovery and utilization of organic matters in wastes,along with saving coal and water,the products of hydrogen,liquid carbon dioxide, liquid ammonia and ammonium bicarbonate are produced;in order to prevent secondary pollution, closed and tunable mill feeding device,multichannel gasification nozzle,gas quench unit and corresponding gasifier are adopted.Breakthrough progress is realized in standardized and systematic operation and management of wastes treatment,resource conservation and comprehensive utilization, technology research and development,pilot and promotion and application.%对不同的高浓度废水(危险废物)制订不同的分析方法、标准和处理工艺;对不同种类的危险废物进行制浆工艺的试验和研究,确定标准化的制浆操作工艺;根据不同种类的危险废物,研究并合理调整气化工艺操作参数,有效地综合回收利用了废物中的有机物,在节煤、节水的同时,生产氢气、液体二氧化碳、液氨、碳酸氢铵产品。为防止二次污染,采用了密闭可调式磨机喂料装置、多通道气化喷嘴、气体激冷装置和与之相适应的气化炉。在废物处置规范化和制度化运行管理、资源节约和综合利用、技术研发、中试和推广应用等方面取得了突破性的进展。

  4. Influence of Process Parameters on Coal Combustion Performance

    DEFF Research Database (Denmark)

    Lans, Robert Pieter Van Der

    The objective of this study is to improve the understanding of nitrogen oxide formation and carbon burnout during the combustion of pulverized coal, and to contribute to addressing the potential of chemical engineering models for the prediction of furnace temperatures, NO emissions and the amount...... of carbon in ash. To this purpose, the effect of coal quality on NO and burnout has been investigated experimentally, a radiation heat balance has been developed based on simple chemical engineering methodology, and a mixing study has been conducted in order to describe the near burner macro mixing in terms...... with self-sustaining flames, while extensions are made to full scale boilers and furnace modeling. Since coal combustion and flame aerodynamics are reviewed elsewhere, these phenomena are only treated briefly. The influence of coal type and process conditions on NO formation and carbon burnout has been...

  5. Low-rank coal research

    Energy Technology Data Exchange (ETDEWEB)

    Weber, G. F.; Laudal, D. L.

    1989-01-01

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  6. Clean coal - a national urgency

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, S.M.; Sahai, R. [Indian Bureau of Mines, Nagpur (India). Technical Consultancy Division

    2000-07-01

    India is the third largest producer and consumer of coal in the world. Coal generally has a high ash content, thereby requiring that it be cleaned for proper use. Technological advances now make it possible to reduce pollution considerably, even as energy use increases. However, to reduce environmental impacts, technologies for cleaning coal before combustion need to be developed. The paper focuses on the need for clean coal production and the benefits associated with it. Although the country is rich in coal reserves, the generally inferior quality of coal will lead to its depletion if it is not used cleanly. Increasing the proportion of prepared coal from the current level of less than 5% (i.e. 10-11 million tonnes per annum) of all coal consumed will lead to a massive saving. This can be achieved if new washeries are set up, preferably near the coalfields. 2 figs.

  7. China's post-coal growth

    Science.gov (United States)

    Qi, Ye; Stern, Nicholas; Wu, Tong; Lu, Jiaqi; Green, Fergus

    2016-08-01

    Slowing GDP growth, a structural shift away from heavy industry, and more proactive policies on air pollution and clean energy have caused China's coal use to peak. It seems that economic growth has decoupled from growth in coal consumption.

  8. Coal liquefaction processes

    Energy Technology Data Exchange (ETDEWEB)

    Baker, N.R.; Blazek, C.F.; Tison, R.R.

    1979-07-01

    Coal liquefaction is an emerging technology receiving great attention as a possible liquid fuel source. Currently, four general methods of converting coal to liquid fuel are under active development: direct hydrogenation; pyrolysis/hydrocarbonization; solvent extraction; and indirect liquefaction. This work is being conducted at the pilot plant stage, usually with a coal feed rate of several tons per day. Several conceptual design studies have been published recently for large (measured in tens of thousands of tons per day coal feed rate) commercial liquefaction plants, and these reports form the data base for this evaluation. Products from a liquefaction facility depend on the particular method and plant design selected, and these products range from synthetic crude oils up through the lighter hydrocarbon gases, and, in some cases, electricity. Various processes are evaluated with respect to product compositions, thermal efficiency, environmental effects, operating and maintenance requirements, and cost. Because of the large plant capacities of current conceptual designs, it is not clear as to how, and on what scale, coal liquefaction may be considered appropriate as an energy source for Integrated Community Energy Systems (CES). Development work, both currently under way and planned for the future, should help to clarify and quantify the question of applicability.

  9. Sustainable development with clean coal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-08-01

    This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

  10. Integrated coal gasification combined cycle

    Science.gov (United States)

    Richards, P. C.; Wijffels, J.-B.; Zuideveld, P. L.

    Features of the integrated coal gasification combined cycle power plants are described against the backdrop of the development and first commercial application of the shell coal gasification process. Focus is on the efficiency and excellent environmental performance of the integrated coal gasification combined power plants. Current IGCC projects are given together with an outline of some of the options for integrating coal gasification with combined cycles and also other applications of synthesis gas.

  11. The Decompositioning of Volatile-Matter of Tanjung Enim Coal by using Thermogravimetry Analyzer (TGA

    Directory of Open Access Journals (Sweden)

    Nukman Nukman

    2010-10-01

    Full Text Available Coal is a nature material which a kind of energy source. The decompotition of coal could analyze by heat treated using thermogravimetry analyzer. The decomposition of the volatile matter for three kinds of Tanjung Enim coal could be known. The value of activation energy that be found diference, then for Semi Anthracite, Bitumonius and Sub Bituminous Coal, the initial temperatures are 60.8 oC, 70.7 oC, 97.8oC, and the last temperatures are 893.8 oC, 832 oC, 584.6oC.

  12. Biofuel from hydrothermal carbonisation of biomass

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez Latorre, Marisa [Ingelia, Valencia (Spain)], e-mail: marisa.hernandez@ingelia.com

    2012-11-01

    Main Characteristics of biocoal HTC. Ingelia produce these coal pellets from different types of organic material, such as pruning of gardens and parks, biomass from forest cleaning and agricultural crops.

  13. Coal type and burnout performance

    Energy Technology Data Exchange (ETDEWEB)

    Lester, E.; Cloke, M. [University of Nottingham, Nottingham (United Kingdom). School of Chemical, Environmental and Mining Engineering

    1999-07-01

    A variety of coals underwent refire tests in a drop tube furnace. Characteristics of the coal fractions, the pyrolysed char fractions and the refired char fractions were compared to determine links between coal composition, intermediate char products and burnout. 9 refs., 1 fig., 2 tabs.

  14. Wanted: Clean Coal Burning Technology

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    China is intent on developing clean coal burning technology, an objective it can achieve through installing desulfurization facilities at coal-burning power plants that will control SO2 emissions and environmental pollution. According to kuo Yi, deputy director general of the Department of Science and Technology of the State Environmental Protection Agency, China is a major coal-buming country:

  15. Measuring Apparatus for Coal Powder

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The measuring apparatus for coal powder, equipped with radioactive source, is a set of device andcan be used to measure the density in the pipes and cumulative consumed amount of coal powder in apower plant, and to examine and display the status of the coal powder input system. It is sketched asFig. 1.

  16. Service Modules for Coal Extraction

    Science.gov (United States)

    Gangal, M. D.; Lewis, E. V.

    1985-01-01

    Service train follows group of mining machines, paying out utility lines as machines progress into coal face. Service train for four mining machines removes gases and coal and provides water and electricity. Flexible, coiling armored carriers protect cables and hoses. High coal production attained by arraying row of machines across face, working side by side.

  17. Coal mining in socioeconomic aspect

    OpenAIRE

    ZALOZNOVA YU. S.

    2014-01-01

    The article investigate the correlation of economic and social factors in the development of coal mining on example of vertically integrated companies with both domestic and foreign assets. The effect of socioeconomic aspects which have led to the American paradox of coal is studied to understand the essence of the coal mining industry at the present stage of the global economic management.

  18. The chemistry of hydrothermal magnetite: a review

    Science.gov (United States)

    Nadoll, Patrick; Angerer, Thomas; Mauk, Jeffrey L.; French, David; Walshe, John

    2014-01-01

    Magnetite (Fe3O4) is a well-recognized petrogenetic indicator and is a common accessory mineral in many ore deposits and their host rocks. Recent years have seen an increased interest in the use of hydrothermal magnetite for provenance studies and as a pathfinder for mineral exploration. A number of studies have investigated how specific formation conditions are reflected in the composition of the respective magnetite. Two fundamental questions underlie these efforts — (i) How can the composition of igneous and, more importantly, hydrothermal magnetite be used to discriminate mineralized areas from barren host rocks, and (ii) how can this assist exploration geologists to target ore deposits at greater and greater distances from the main mineralization? Similar to igneous magnetite, the most important factors that govern compositional variations in hydrothermal magnetite are (A) temperature, (B) fluid composition — element availability, (C) oxygen and sulfur fugacity, (D) silicate and sulfide activity, (E) host rock buffering, (F) re-equilibration processes, and (G) intrinsic crystallographic controls such as ionic radius and charge balance. We discuss how specific formation conditions are reflected in the composition of magnetite and review studies that investigate the chemistry of hydrothermal and igneous magnetite from various mineral deposits and their host rocks. Furthermore, we discuss the redox-related alteration of magnetite (martitization and mushketovitization) and mineral inclusions in magnetite and their effect on chemical analyses. Our database includes published and previously unpublished magnetite minor and trace element data for magnetite from (1) banded iron formations (BIF) and related high-grade iron ore deposits in Western Australia, India, and Brazil, (2) Ag–Pb–Zn veins of the Coeur d'Alene district, United States, (3) porphyry Cu–(Au)–(Mo) deposits and associated (4) calcic and magnesian skarn deposits in the southwestern United

  19. Pyrolysis of coal

    Science.gov (United States)

    Babu, Suresh P.; Bair, Wilford G.

    1992-01-01

    A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

  20. Understanding effect of wall structure on the hydrothermal stability of mesostructured silica SBA-15.

    Science.gov (United States)

    Zhang, Fuqiang; Yan, Yan; Yang, Haifeng; Meng, Yan; Yu, Chengzhong; Tu, Bo; Zhao, Dongyuan

    2005-05-12

    , resulting in smaller pore diameter and low surface area. A carbon-propping thermal treating method was employed to enhance the polymerization of Si-O-Si bonds and minimize the serious shrinkage of mesopores at the same time. It was demonstrated to be an effective method that can greatly improve the hydrothermal stability of SBA-15 materials in 800 degrees C steam for 12 h. Furthermore, the SBA-15 materials obtained by using the carbon-propping method possess larger pores and higher surface area after the steam treatment at 800 degrees C compared to the materials from the direct thermal treatment method after the steam treatment.

  1. Modelling of coal combustion enhanced through plasma-fuel systems in full-scale boilers

    Energy Technology Data Exchange (ETDEWEB)

    A.S. Askarova; Z. Jankoski; E.I. Karpenko; E.I. Lavrischeva; F.C. Lockwood; V.E. Messerle; A.B. Ustimenko [al-Farabi Kazakh National University, Almaty (Kazakhstan). Department of Physics

    2005-07-01

    Plasma activation promotes more effective and environmental friendly low-rank coal combustion. This work presents numerical modelling results of plasma thermochemical preparation of pulverized coal for ignition and combustion in the furnace of a utility boiler. Two kinetic mathematical models were used in the investigation of the processes of air-fuel mixture plasma activation, ignition and combustion. A 1D kinetic code, PLASMA-COAL, calculates the concentrations of species, temperatures and velocities of treated coal-air mixtures in a burner incorporating a plasma source. It gives initial data for 3D-modeling of power boilers furnaces by the code FLOREAN. A comprehensive image of plasma activated coal combustion processes in a furnace of pulverised coal fired boiler was obtained. The advantages of the plasma technology are clearly demonstrated. 15 refs., 6 figs., 4 tabs.

  2. Improving performance of direct coal liquefaction through swelling with solvent under the radiation of ultrasonic wave

    Institute of Scientific and Technical Information of China (English)

    NI Xian-zhi; LI Ke-jian; WANG Li

    2004-01-01

    Three kinds of lower rank bituminous coals from Yanzhou mine and Tengxian mine from Shandong Province were treated and hydrogenated in the study. The test results show that the performance of hydrogenation liquefaction of the pretreated coals is improved markedly. Under the test condition of H2 initial pressure 8.2 MPa, addition of the oil yield of pretreated YZ1 coal is 69.76% compared with 62.53% of oil yield of untreated YZ1. Seminally the oil yield of pretreated YZ2 coal is 55.43% compared with20.88% of untreated YZ2 coal. The results of tests also prove that the improving degree of hydrogenation liquefaction of the pretreated coals is related with radiation duration when the radiation frequency and radiation power of ultrasonic wave are fixed.

  3. Crossing point temperature of coal

    Institute of Scientific and Technical Information of China (English)

    Qi Xuyao; Deming Wang; James A. Milke; Xiaoxing Zhong

    2011-01-01

    A further understanding of the self-heating of coal was obtained by investigating the crossing point temperature (CPT) of different ranks of coal. The tests were carried out using a self-designed experimental system for coal self-heating. 50 g (±0.01 g) of coal particles ranging from 0.18 mm to 0.38 mm in size were put into a pure copper reaction vessel attached to the center of a temperature programmed enclosure. The temperature program increased the temperature at a rate of 0.8 ℃/min. Dry air was permitted to flow into the coal reaction vessel at different rates. The surrounding temperature and the coal temperature were monitored by a temperature logger. The results indicate that CPT is affected by coal rank, moisture, sulfur,and the experimental conditions. Higher ranked coals show higher CPT values. A high moisture content causes a delay phenomenon during the self-heating of the coal. Drying at 40 ℃ decreases the effects of moisture. The reactivity of sulfur components in the coal is low under dry and low-temperature conditions.These components form a film that covers the coal surface and slightly inhibits the self-heating of the coal.The flow rate of dry air, and the heating rate of the surroundings, also affect the self-heating of the coal. The most appropriate experimental conditions for coal samples of a given weight and particle size were determined through contrastive analysis. Based on this analysis we propose that CPTs be determined under the same, or nearly the same conditions, for evaluation of the spontaneous combustion of coal.

  4. Inhibition Effect of Phosphorus Flame Retardants on the Fire Disasters Induced by Spontaneous Combustion of Coal

    Directory of Open Access Journals (Sweden)

    Yibo Tang

    2017-01-01

    Full Text Available Coal spontaneous combustion (CSC generally induces fire disasters in underground mines, thus causing serious casualties, environmental pollution, and property loss around the world. By using six P-containing additives to process three typical coal samples, this study investigated the variations of the self-ignition characteristics of the coal samples before and after treatment. The analysis was performed by combining thermogravimetric analysis/differential scanning calorimetry (TG/DSC Fourier transform infrared spectrometer (FTIR and low temperature oxidation. Experimental results showed that P-containing inhibitors could effectively restrain the heat emitted in the combustion of coal samples and therefore the ignition temperature of the coal samples was delayed at varying degrees. The combustion rate of the coal samples was reduced as well. At the temperatures ranging from 50°C to 150°C, the activation energy of the coal samples after the treatment was found to increase, which indicated that the coal samples were more difficult to be oxidized. After being treated with phosphorus flame retardants (PFRs, the content of several active groups represented by the C-O structure in the three coal samples was proved to be obviously changed. This suggested that PFRs could significantly inhibit the content of CO generated by the low temperature oxidation of coal, and the flame-retardant efficiency grew with the increasing temperature. At 200°C, the maximal inhibition efficiency reached approximately 85%.

  5. Combined hydrothermal liquefaction and catalytic hydrothermal gasification system and process for conversion of biomass feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2017-09-12

    A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.

  6. Hydrothermal Liquefaction of the Microalgae Phaeodactylum tricornutum

    DEFF Research Database (Denmark)

    Sigaard Christensen, Per; Peng, Gaël; Vogel, Frédéric

    2014-01-01

    The microalgae Phaeodactylum tricornutum was processed by hydrothermal liquefaction in order to assess the influence of reaction temperature and reaction time on the product and elemental distribution. The experiments were carried out at different reaction times (5 and 15 min) and over a wide range...

  7. HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF A ...

    African Journals Online (AJOL)

    Preferred Customer

    tool for the construction of materials containing unique structures and special ... Recently, we reported hydrothermal synthesis of binuclear Co(II) complex [19] and a new .... to two neighboring ones, through four µ2-oxo bridges, to form infinite ...

  8. Hydrothermal Liquefaction of the Microalgae Phaeodactylum tricornutum

    DEFF Research Database (Denmark)

    Sigaard Christensen, Per; Peng, Gaël; Vogel, Frédéric

    2014-01-01

    The microalgae Phaeodactylum tricornutum was processed by hydrothermal liquefaction in order to assess the influence of reaction temperature and reaction time on the product and elemental distribution. The experiments were carried out at different reaction times (5 and 15 min) and over a wide range...

  9. Formation of zirconia polymorphs under hydrothermal conditions

    Institute of Scientific and Technical Information of China (English)

    ZHENG; Yanqing(郑燕青); SHl; Erwei(施尔畏); Li; Wenjun(李汶军); CHEN; Zhizhan(陈之战); ZHONG; Weizhuo(仲维卓); HUXingfang(胡行方)

    2002-01-01

    Using zirconium oxychloride solution as precursor, monoclinic zirconia crystallites withnarrow distribution of nanosize were obtained in the hydrothermal reaction. However, when thereaction was in weak acidic medium or base medium, whether directly using the colloidal precipi-tate prepared from zirconium salt solutions with base solution as precursor added, or using theprecipitate after filtrating, washing and drying treatments as precursor, the product of the hydro-thermal reaction was the mixture of both monoclinic and tetragonal polymorphs. As the pH of themedium rises, the content of tetragonal phase in the product, the morphologies and size of thecrystallites all change. There are three types of formation mechanisms under hydrothermal condi-tion, which can be called as saturation-precipitation mechanism in homogeneous solution, dissolu-tion-crystallization mechanism and in-situ crystallization mechanism, respectively. The formationmechanism of crystallites varies with different hydrothermal conditions, such as the states of theprecursor and the pH of the medium, which lead to changes in the phases, morphologies andsizes of the resulting crystallites.

  10. The 1997 Americas coal conference. Conference proceedings

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-11-01

    Papers are presented which cover the following topics: Colombian exports of coal; Colombian coal organizations; mining prospects; markets; Venezuela`s mining policy and private coal industry; security situation in Colombia and its effect on the energy industry; transportation; steam coal markets, including USA, Europe and the Eastern Mediterranean, and for high sulfur coal; and innovations in the coal market. 18 papers have been abstracted separately on the IEA Coal Research CD-ROM.

  11. Anhydrite precipitation in seafloor hydrothermal systems

    Science.gov (United States)

    Theissen-Krah, Sonja; Rüpke, Lars H.

    2016-04-01

    The composition and metal concentration of hydrothermal fluids venting at the seafloor is strongly temperature-dependent and fluids above 300°C are required to transport metals to the seafloor (Hannington et al. 2010). Ore-forming hydrothermal systems and high temperature vents in general are often associated with faults and fracture zones, i.e. zones of enhanced permeabilities that act as channels for the uprising hydrothermal fluid (Heinrich & Candela, 2014). Previous numerical models (Jupp and Schultz, 2000; Andersen et al. 2015) however have shown that high permeabilities tend to decrease fluid flow temperatures due to mixing with cold seawater and the resulting high fluid fluxes that lead to short residence times of the fluid near the heat source. A possible mechanism to reduce the permeability and thereby to focus high temperature fluid flow are mineral precipitation reactions that clog the pore space. Anhydrite for example precipitates from seawater if it is heated to temperatures above ~150°C or due to mixing of seawater with hydrothermal fluids that usually have high Calcium concentrations. We have implemented anhydrite reactions (precipitation and dissolution) in our finite element numerical models of hydrothermal circulation. The initial results show that the precipitation of anhydrite efficiently alters the permeability field, which affects the hydrothermal flow field as well as the resulting vent temperatures. C. Andersen et al. (2015), Fault geometry and permeability contrast control vent temperatures at the Logatchev 1 hydrothermal field, Mid-Atlantic Ridge, Geology, 43(1), 51-54. M. D. Hannington et al. (2010), Modern Sea-Floor Massive Sulfides and Base Metal Resources: Toward an Estimate of Global Sea-Floor Massive Sulfide Potential, in The Challenge of Finding New Mineral Resources: Global Metallogeny, Innovative Exploration, and New Discoveries, edited by R. J. Goldfarb, E. E. Marsh and T. Monecke, pp. 317-338, Society of Economic Geologists

  12. Latent methane in fossil coals

    Energy Technology Data Exchange (ETDEWEB)

    A.D. Alexeev; E.V. Ulyanova; G.P. Starikov; N.N. Kovriga [Academy of Sciences of Ukraine, Donetsk (Ukraine). Institute for Physics of Mining Processes

    2004-07-01

    It is established experimentally using 1H NMR wide line spectroscopy that methane can exist in coals not only in open or closed porosity and fracture systems but also in solid solutions in coal substance, in particular, under methane pressure 2 MPa or higher. Methane dissolved in coal minerals reversibly modifies their lattice parameters as determined from X-ray diffraction analysis. Co-existence of these methane forms in fossil coals causes multi-step desorption kinetics. It is shown experimentally that the long-term latent methane desorption is effected mainly by closed porosity, which in turn is determined by coal rank. 21 refs., 3 figs., 2 tabs.

  13. Coal facies studies in Australia

    Energy Technology Data Exchange (ETDEWEB)

    Crosdale, Peter J. [Coalseam Gas Research Institute, School of Earth Sciences, James Cook University, Townsville, Qld 4814 (Australia)

    2004-04-23

    Despite the economic importance of coal to the Australian economy, detailed studies of controls on variation in coal type are remarkably few. However, important contributions have been made in the understanding of coal facies development. Tertiary lignite deposits of the Gippsland Basin provide key insights into the development of lithotype cyclicity and its relationship to relative sea-level changes, with individual paling-up cycles being correlated to parasequences. Studies of Permian hard coals have identified relationships between coal type and surrounding sediments. Unfortunately, these relationships have been widely over-interpreted in a manner that has diminished their real value.

  14. Numerical analysis of coal-gas flow and pressure relief on the mining method of extreme short-range protective strata

    Institute of Scientific and Technical Information of China (English)

    LEI Wen-jie

    2008-01-01

    The coal-gas existing condition was ameliorated in the coal seams prone to coal-gas outburst adopting the mining method of protective strata. The gas volume and the gas pressure were reduced synchronously in the protected coal seam, and the coal seam of high permeability prone to the coal-gas outburst was changed into that of low perme-ability with no proneness to the coal-gas outburst. The D15 coal seam was treated as the protective strata, and the D16-17 coal seam was treated as the protected strata in the Fifth coal mine in the Pingdingshan Coal Mining Group. The distance between the two coal seams was 5 m averagely, clarified into the extreme short-range protective strata. The numerical analysis was based on the theory of the porous media flow with the finite ele-ment method. The gas flow process and the change mechanism of the coal-gas pressure were analyzed in the process of mining the protective strata.

  15. A thermal investigation on coals from Assam (India)

    Energy Technology Data Exchange (ETDEWEB)

    Saikia, Binoy K.; Boruah, Rajani K.; Baruah, Bimala P. [North-East Institute of Science and Technology (CSIR), Jorhat-785 006 (India); Gogoi, Pradip K. [Department of Chemistry, Dibrugarh University, Dibrugarh-786 004 (India)

    2009-02-15

    A thermal characterization of two coal samples from Ledo and Tikak collieries of Makum coalfield, Assam, India using XRD, FT-IR, and TGA was reported in this paper. The coal samples were heated for 20, 40 and 60 min in a 1000-watt heater (temperature {proportional_to} 250 C) in presence of air and characterized by XRD and FT-IR spectroscopy. Both the coals contain amorphous and crystalline phases. The raw coals also contain very small peaks due to quartz, calcite, gypsum, pyrite, and chlorite. The XRD patterns were found to change upon heating. In the coals heated for 20 and 40 min, it was observed that both amorphous and crystalline parts are common in them; crystalline part being the major one in the 40 min heated samples. The XRD patterns of the samples heated for 60 min indicate the presence of major quantities of {alpha}-quartz, hematite, and chlorite in them. They also show some new peaks, which are assigned to be kaolinite, illite, magnetite and very small in comparison to the amorphous portion in raw coals. {alpha}-quartz was found to be most stable crystalline phase of silica in the coals. The crystallinity % (X-ray) of the coals heat-treated for different times was determined and found to be increasing with time of heating. The FT-IR spectra of raw and heat-treated coal samples at 250 C were also recorded and compared. The spectra were observed to be almost similar and it was observed that few functional groups disappear on heating at 250 C. The same coal samples were also characterized by thermogravimetric analysis (TGA) and differential thermal analysis (DTA) techniques. On heat treatment in air atmosphere up to 800 C, 20-27% weight loss occurs due to removal of various volatile materials. DTA results indicate the chemical reactivity of the coal sample initially at 80-110 C due to loss of water, and two other major reactions at around 420 and 530 C due to primary and secondary volatization. (author)

  16. Structural changes in deashed coals induced by heat treatment; Kanetsu shori ni yoru dakkaitan no kozo henka

    Energy Technology Data Exchange (ETDEWEB)

    Sugano, M.; Sekita, M.; Muramatsu, Y.; Mashimo, K.; Wainai, T. [Nihon University, Tokyo (Japan). College of Science and Technology

    1996-10-28

    Change in structures of 3 kinds of coals with different coal ranks and their deashed coals was studied by heat treatment below 200{degree}C. In experiment, crushed Adaro, Taiheiyo and Huaibei coals below 200mesh and their deashed coals were used as specimens. The coal and deashed coal specimens dried in vacuum at 110{degree}C for 3 hours were filled into an autoclave, and the heat-treated coal specimens were prepared by holding them under initial nitrogen pressure of 2kg/cm{sup 2} at a fixed temperature for 30min. Extraction using pyridine as solvent, volumetric swelling using methanol or benzene as solvent, and measurement of the amount of carboxyl and phenolic hydroxyl functional groups were conducted for these coal specimens. The experimental results are as follows. Huaibei coal has developed aromatic ring structure, and its structure is hardly affected by heat treatment. The oxygen containing functional groups decrease by heat treatment over 100{degree}C in Adaro coal and 150{degree}C in Taiheiyo coal, and PS, MQ and BQ also decrease due to aggregation between molecules. 5 refs., 2 figs.

  17. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report No. 7, April 1993--June 1993

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., University Park, PA (United States); Gutterman, C.

    1994-09-01

    The overall objective of this project is to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrates coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and carrying out a technical assessment including an economic evaluation. The project is being carried out under contract to the United States Department of Energy. All three coals used in this study (Black Thunder, Burning Star bituminous, and Martin Lake lignite) are effectively swelled by a number of solvents. The most effective solvents are those having hetero-functionality. In addition, a synergistic effect has been demonstrated, in which solvent blends are more effective for coal swelling than the pure solvents alone. Therefore, it will be necessary to use only low levels of swelling agents and yet promote the impregnation of catalyst precursors. The rate of the impregnation of catalyst precursors into swollen coal increases greatly as the effectiveness of the solvent to swell the coal increases. This effect is also demonstrated by improved catalyst precursor impregnation with increased contact temperature. Laboratory- and bench-scale liquefaction experimentation is underway using swelled and catalyst impregnated coal samples. Higher coal conversions were observed for the SO{sub 2}-treated coal than the raw coal, regardless of catalyst type. Conversions of swelled coal were highest when Molyvan-L, molybdenum naphthenate, and nickel octoate, respectively, were added to the liquefaction solvent.

  18. Recrystallization of starches by hydrothermal treatment: digestibility, structural, and physicochemical properties.

    Science.gov (United States)

    Trinh, Khanh Son

    2015-12-01

    Gelatinized starches were recrystallized under hydrothermal treatment and their properties were characterized by X-ray diffractometry, solid-state (13)C cross-polarization and magic-angle spinning nuclear magnetic resonance, differential scanning calorimetry, gel-permeation chromatography, high-performance anion-exchange chromatography using pulsed amperomeric detection, high-performance size-exclusion chromatography with attached multiangle laser light scattering and refractive index detectors, and digestibility analysis. Amylopectin molecules of hylon (V, VII) and water yam starch contained long side-chains with high proportion of fb1 and fb2. Under hydrothermal treatment, the double helix proportion and relative crystallinity significantly increased and reached maxima of water yam (48.7 and 28.2 %, respectively). Except water yam starch, X-ray diffraction pattern of all starches exhibited the evidence of type 2 amylose-lipid complex. Besides, under DSC measurement, potato and hylon starches showed the endotherm of amylose-amylose interaction. The hydrothermal treatment caused the recrystallization resulting in the decrease of RDS, especially in case of hylon and water yam starch. HTT water yam contained highest SDS (48.3 %) and HTT hylon VII contained highest RS (44.5 %). The relationship between structure and digestibility was observed, in which, high amylose content and specific structures of amylopectin molecule were necessary for the production of RS and/or SDS of hydrothermally treated starches.

  19. Hydrothermal sulfidation and floatation treatment of heavy-metal-containing sludge for recovery and stabilization.

    Science.gov (United States)

    Liang, Yan-Jie; Chai, Li-Yuan; Min, Xiao-Bo; Tang, Chong-Jian; Zhang, Hai-Jing; Ke, Yong; Xie, Xian-De

    2012-05-30

    This study focuses on the application of hydrothermal sulfidation and floatation to treat the heavy-metal-containing sludge for recovery and stabilization. After the hydrothermal sulfidation, the sulfidation percentage of zinc and lead reach up to 85.0% and 75.4%, respectively. 33.3% of Zn, 58.9% of Pb and 68.8% of Cu can be recovered from the sludge by floatation. The lower recovery of ZnS attributes to its surface and structural characteristics. To compare these characteristics, three types of synthetic metal sulfide (ZnS, PbS and CuS) were prepared and examined with XRD, SEM and TEM. The poor floatability of the finely dispersed, round shape of ZnS can be improved by crystal modification in hydrothermal condition. With increasing the temperature and reaction time, the grain size of the ZnS increased from 7.95 nm to 44.28 nm and the recovery of Zn increased to from 33.3% to 72.8%. The TCLP results indicate that all the leached heavy metal concentrations of floatation tailings are under the allowable limit. No obvious increase of heavy metal concentration was observed in continuous leaching procedure. The presence of alkaline compounds after hydrothermal sulfidation might act as mineralogical scavengers of dissolved heavy metal released by sulfide oxidation to avoid the heavy metal pollution.

  20. Voltammetric Investigation Of Hydrothermal Iron Speciation

    Directory of Open Access Journals (Sweden)

    Charlotte eKleint

    2016-05-01

    Full Text Available Hydrothermal vent fluids are highly enriched in iron (Fe compared to ambient seawater, and organic ligands may play a role in facilitating the transport of some hydrothermal Fe into the open ocean. This is important since Fe is a limiting micronutrient for primary production in large parts of the world`s surface ocean. We have investigated the concentration and speciation of Fe in several vent fluid and plume samples from the Nifonea vent field, Coriolis Troughs, New Hebrides Island Arc, South Pacific Ocean using competitive ligand exchange - adsorptive cathodic stripping voltammetry (CLE - AdCSV with salicylaldoxime (SA as the artificial ligand. Our results for total dissolved Fe (dFe in the buoyant hydrothermal plume samples showed concentrations up to 3.86 µM dFe with only a small fraction between 1.1% and 11.8% being chemically labile. Iron binding ligand concentrations ([L] were found in µM level with strong conditional stability constants up to log K[L],Fe3+ of 22.9. Within the non-buoyant hydrothermal plume above the Nifonea vent field, up to 84.7% of the available Fe is chemically labile and [L] concentrations up to 97 nM were measured. [L] was consistently in excess of Felab, indicating that all available Fe is being complexed, which in combination with high Felab values in the non-buoyant plume, signifies that a high fraction of hydrothermal dFe is potentially being transported away from the plume into the surrounding waters, contributing to the global oceanic Fe budget.

  1. Hydrothermal systems in small ocean planets.

    Science.gov (United States)

    Vance, Steve; Harnmeijer, Jelte; Kimura, Jun; Hussmann, Hauke; Demartin, Brian; Brown, J Michael

    2007-12-01

    We examine means for driving hydrothermal activity in extraterrestrial oceans on planets and satellites of less than one Earth mass, with implications for sustaining a low level of biological activity over geological timescales. Assuming ocean planets have olivine-dominated lithospheres, a model for cooling-induced thermal cracking shows how variation in planet size and internal thermal energy may drive variation in the dominant type of hydrothermal system-for example, high or low temperature system or chemically driven system. As radiogenic heating diminishes over time, progressive exposure of new rock continues to the current epoch. Where fluid-rock interactions propagate slowly into a deep brittle layer, thermal energy from serpentinization may be the primary cause of hydrothermal activity in small ocean planets. We show that the time-varying hydrostatic head of a tidally forced ice shell may drive hydrothermal fluid flow through the seafloor, which can generate moderate but potentially important heat through viscous interaction with the matrix of porous seafloor rock. Considering all presently known potential ocean planets-Mars, a number of icy satellites, Pluto, and other trans-neptunian objects-and applying Earth-like material properties and cooling rates, we find depths of circulation are more than an order of magnitude greater than in Earth. In Europa and Enceladus, tidal flexing may drive hydrothermal circulation and, in Europa, may generate heat on the same order as present-day radiogenic heat flux at Earth's surface. In all objects, progressive serpentinization generates heat on a globally averaged basis at a fraction of a percent of present-day radiogenic heating and hydrogen is produced at rates between 10(9) and 10(10) molecules cm(2) s(1).

  2. National Coal Quality Inventory (NACQI)

    Energy Technology Data Exchange (ETDEWEB)

    Robert Finkelman

    2005-09-30

    The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

  3. The shell coal gasification process

    Energy Technology Data Exchange (ETDEWEB)

    Koenders, L.O.M.; Zuideveld, P.O. [Shell Internationale Petroleum Maatschappij B.V., The Hague (Netherlands)

    1995-12-01

    Future Integrated Coal Gasification Combined Cycle (ICGCC) power plants will have superior environmental performance and efficiency. The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an ICGCC plant. SCGP flexibility has been demonstrated for high-rank bituminous coals to low rank lignites and petroleum coke, and the process is well suited for combined cycle power generation, resulting in efficiencies of 42 to 46% (LHV), depending on choice of coal and gas turbine efficiency. In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology has been built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N.V. Sep). The construction of the unit was completed end 1993 and is now followed by start-up and a 3 year demonstration period, after that the plant will be part of the Dutch electricity generating system.

  4. Coal combustion research

    Energy Technology Data Exchange (ETDEWEB)

    Daw, C.S.

    1996-06-01

    This section describes research and development related to coal combustion being performed for the Fossil Energy Program under the direction of the Morgantown Energy Technology Center. The key activity involves the application of chaos theory for the diagnosis and control of fossil energy processes.

  5. Automation in coal mining

    Energy Technology Data Exchange (ETDEWEB)

    Thring, M.W.

    1983-08-01

    A study of the 21st century energy situation shows that coal must be the principal fuel, gradually followed by the renewable fuels which require fossil fuel to make and build the equipment. As oil runs out a substitute liquid fuel will have to be made from coal and from biomass because oil is uniquely suitable for road, sea and air transport and for agriculture. Coal can be mined without men going underground by directed drilling and by Telechirics - hands at a distance. In Telechiric mining, the coal would be won by conventional mining machinery but the human miners would erect, operate, maintain and repair this machinery by sitting in a control room on the surface and controlling telechirs which could move about the mine and would have mechanical hands which would respond exactly to every movement of the human master's hands. He would have touch and force feedback and three dimensional vision so good that he could use his trained craft skill of hands and eyes as though he were down the mine.

  6. Proximate Analysis of Coal

    Science.gov (United States)

    Donahue, Craig J.; Rais, Elizabeth A.

    2009-01-01

    This lab experiment illustrates the use of thermogravimetric analysis (TGA) to perform proximate analysis on a series of coal samples of different rank. Peat and coke are also examined. A total of four exercises are described. These are dry exercises as students interpret previously recorded scans. The weight percent moisture, volatile matter,…

  7. Hard coal; Steinkohle

    Energy Technology Data Exchange (ETDEWEB)

    Loo, Kai van de; Sitte, Andreas-Peter [Gesamtverband Steinkohle e.V. (GVSt), Herne (Germany)

    2015-07-01

    International the coal market in 2014 was the first time in a long time in a period of stagnation. In Germany, the coal consumption decreased even significantly, mainly due to the decrease in power generation. Here the national energy transition has now been noticable affected negative for coal use. The political guidances can expect a further significant downward movement for the future. In the present phase-out process of the German hard coal industry with still three active mines there was in 2014 no decommissioning. But the next is at the end of 2015, and the plans for the time after mining have been continued. [German] International war der Markt fuer Steinkohle 2014 erstmals seit langem wieder von einer Stagnation gekennzeichnet. In Deutschland ging der Steinkohlenverbrauch sogar deutlich zurueck, vor allem wegen des Rueckgangs in der Stromerzeugung. Hier hat sich die nationale Energiewende nun spuerbar und fuer die Steinkohlennutzung negativ ausgewirkt. Die politischen Weichenstellungen lassen fuer die Zukunft eine weitere erhebliche Abwaertsbewegung erwarten. Bei dem im Auslaufprozess befindlichen deutschen Steinkohlenbergbau mit noch drei aktiven Bergwerken gab es 2014 keine Stilllegung. Doch die naechste steht zum Jahresende 2015 an, und die Planungen fuer die Zeit nach dem Bergbau sind fortgefuehrt worden.

  8. Keeping Warm Without Coal

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Heat-pump technology offers a clean heating alternative to coal With no air conditioning or indoor heating, families in southeast Beijing’s Fangzhuang neighbor-hood still enjoy refreshing warm air all year round. The secret is in the pump technology. Heat pumps cool the homes in summer and warm them in winter just like a central air-conditioning system.

  9. Kinetics of coal pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Seery, D.J.; Freihaut, J.D.; Proscia, W.M. (United Technologies Research Center, East Hartford, CT (USA)); Howard, J.B.; Peters, W.; Hsu, J.; Hajaligol, M.; Sarofim, A. (Massachusetts Inst. of Tech., Cambridge, MA (USA)); Jenkins, R.; Mallin, J.; Espindola-Merin, B. (Pennsylvania State Univ., University Park, PA (USA)); Essenhigh, R.; Misra, M.K. (Ohio State Univ., Columbus, OH (USA))

    1989-07-01

    This report contains results of a coordinated, multi-laboratory investigation of coal devolatilization. Data is reported pertaining to the devolatilization for bituminous coals over three orders of magnitude in apparent heating rate (100 to 100,000 + {degree}C/sec), over two orders of magnitude in particle size (20 to 700 microns), final particle temperatures from 400 to 1600{degree}C, heat transfer modes ranging from convection to radiative, ambient pressure ranging from near vacuum to one atmosphere pressure. The heat transfer characteristics of the reactors are reported in detail. It is assumed the experimental results are to form the basis of a devolatilization data base. Empirical rate expressions are developed for each phase of devolatilization which, when coupled to an awareness of the heat transfer rate potential of a particular devolatilization reactor, indicate the kinetics emphasized by a particular system reactor plus coal sample. The analysis indicates the particular phase of devolatilization that will be emphasized by a particular reactor type and, thereby, the kinetic expressions appropriate to that devolatilization system. Engineering rate expressions are developed from the empirical rate expressions in the context of a fundamental understanding of coal devolatilization developed in the course of the investigation. 164 refs., 223 figs., 44 tabs.

  10. Coal surface control for advanced physical fine coal cleaning technologies

    Energy Technology Data Exchange (ETDEWEB)

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-01-01

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  11. Coal - carriage by sea; 2nd ed.

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, P.; Strange, J.; Studd, B. [SSY Consultancy and Research Ltd., London (United Kingdom)

    1997-04-01

    The book provides a guide to all aspects of the carriage of coal by sea. Part I gives an overview of coal consumption, production and trade, discussing major coal producers, major consumers, and importers and exporters. Part II has chapters on the ships employed to carry coal; problems concerned with the carriage of coal; the loading carrying and discharging of coal; and chartering. Part III covers the origins, properties and utilisation of coal; the petrographic classification of coal; the industrial utilisation of coal; and the principles and techniques of manual and mechanical sampling and analysis of coal. Part IV discusses problems and dangers coal transportation and storage (spontaneous combustion, prevention of freezing), and the role of the cargo superintendent in coal transportation. The text is well supported by tables of statistical data relating to coal production, trade and use. 11 figs., 94 tabs., 4 apps.

  12. The realization of the potential productivity of the potato under the influence of synthetic growth regulators in different hydrothermal conditions

    Directory of Open Access Journals (Sweden)

    Владимир Алексеевич Варавкин

    2015-06-01

    Full Text Available Plants Solanum tuberosum L. of Sateen variety treated by synthetic regulators of new generation with the growth of them in different hydrothermal conditions enhance the ability to form tubers, to increase their mass, the accumulation of dry matter and starch. Regulation of the intensity of the tuber formation, the growth of their mass, accumulation of dry matter and starch using biologically active substances has a dependency on the evolving hydrothermal conditions during the growing season of potato and chemical nature of agents

  13. Thermal evolution characteristics of Triassic coal in Chuxiong Basin and its geological significance

    Institute of Scientific and Technical Information of China (English)

    Wang Meng; Li Xiaoping; Dai Xuguang

    2016-01-01

    Chuxiong Basin in Yunnan is a typical Mesozoic foreland basin which is enriched in widely distributed Triassic coal resources with thick deposits and of important strategic significance. By applying vitrinite reflectance measurement, inclusion thermometry, fission track dating and EASY%Ro numerical simula-tion, the Triassic coal thermal evolution history of the Chuxiong Basin was analyzed, and the results were concluded. The vitrinite reflectance of Chuxiong Basin is higher in the west and south in general. Vertically, in the east, west, and north of the basin, the vitrinite reflectance increases with increasing depth, and in the northern part, exceptionally high values occur, and there is no significant regularity in the east. The formation of inclusions inside quartz veins in Chuxiong Basin Triassic coal are unrelated with magmatic hydrothermal fluid, and there are multi-phase inclusions formed in three or four sections of tectonic movements. The main heating period (apparent age) of the Triassic coal is concentrated in the late Cenozoic, during which the coal was subjected to repeated thermal disturbance, resulting in a mul-timodal distribution of the fission track data, which reveals mild burial features of the early stages of the Late Cenozoic. The Triassic coal of Chuxiong Basin has experienced two major temperature increasing processes, which occurred in the early-mid Yanshan and the early Himalayan, respectively. The first hydrocarbon generation period of coal organic matter occurred in the formation stage of the foreland basin, during which the south and west of the basin generated large amounts of hydrocarbon, but little was preserved. The second generation stage in the Early Himalayan had conditions suitable for high gas accumulation, especially in the western and southern regions. The upper Triassic coal is of moderate bur-ial depth and is less affected by the strike-slip effect. There are key areas of Chuxiong Basin oil and gas exploration, such as the

  14. An overview of the geological controls in underground coal gasification

    Science.gov (United States)

    Mohanty, Debadutta

    2017-07-01

    Coal’s reign will extend well into this millennium as the global demand for coal is expected to increase on average by 2-1% per year through 2019. Enhanced utilization of the domestic coal resource through clean coal technologies is necessary to meet the energy needs while achieving reduced emissions. Underground coal gasification (UCG) is one of such potential technologies. Geology of the area plays decisive role throughout the life of a UCG project and imperative for every phase of the project cycle starting from planning, site selection, design to cessation of operations and restoration of the site. Impermeable over/underlying strata with low porosity and less deformation are most suitable for UCG processes as they act as seal between the coal seam and the surrounding aquifers while limiting the degree of subsidence. Inrush of excess water into the gasification chamber reduces the efficacy of the process and may even quench the reactions in progress. Presence of fresh water aquifer in the vicinity of target coal seam should be abandoned in order to avoid groundwater contamination. UCG is not a proven technology that is still evolving and there are risks that need to be monitored and managed. Effective shutdown programme should intend at minimising the post-burn contaminant generation by flushing out potential organic and inorganic contaminants from the underground strata and treating contaminants, and to restore ground water quality to near baseline conditions.

  15. National coal utilization assessment: modeling long-term coal production with the Argonne coal market model

    Energy Technology Data Exchange (ETDEWEB)

    Dux, C.D.; Kroh, G.C.; VanKuiken, J.C.

    1977-08-01

    The Argonne Coal Market Model was developed as part of the National Coal Utilization Assessment, a comprehensive study of coal-related environmental, health, and safety impacts. The model was used to generate long-term coal market scenarios that became the basis for comparing the impacts of coal-development options. The model has a relatively high degree of regional detail concerning both supply and demand. Coal demands are forecast by a combination of trend and econometric analysis and then input exogenously into the model. Coal supply in each region is characterized by a linearly increasing function relating increments of new mine capacity to the marginal cost of extraction. Rail-transportation costs are econometrically estimated for each supply-demand link. A quadratic programming algorithm is used to calculate flow patterns that minimize consumer costs for the system.

  16. Proceedings of the 1978 coal chemistry workshop

    Energy Technology Data Exchange (ETDEWEB)

    Radding, S. B.; Peters, H. M. [eds.

    1978-11-01

    Ten papers from the proceedings have been entered individually into EDB and ERA. They deal with the structural chemical analysis of coal and the chemistry of coal gasification and coal liquefaction. DOE's Fossil Energy Program is discussed in detail and recommendations for further research in coal gasification and coal liquefaction are made. (LTN)

  17. A study on the genetic relations between Permian Longtan Formation coal series strata and Carlin-type gold deposits, southwestern Guizhou Province, China

    Institute of Scientific and Technical Information of China (English)

    NIE Aiguo; MEI Shiquan; GUAN Daiyun; WU Pan; ZHANG Zhuru

    2008-01-01

    A large number of the Carlin-type gold deposits occur in the Longtan Formation in southwestern Guizhou Province. The Longtan Formation contains abundant basalt, tuff and siliceous rocks. All rocks of the Longtan Formation are enriched in gold, which were deposited in a limited platform environment in the transition zone from marine to continental. The process of sedimentation was accompanied by the eruption of Emeishan basalt and hydrothermal deposition controlled by co-sedimentary submarine deep faults in the west, which led to the formation of a peculiar gold-bearing formation with coal series strata. This formation controlled the occurrence of the Carlin-type gold deposits in southwestern Guizhou Province. In response to the remobilization of the Emei mantle plume during the Yanshanian period, As, Au and other ore-forming materials were continuously extracted by deeply circulating waters from the Emeishan basalt and coal seams, thereafter forming ore-forming hydrothermal solutions.When these elements were transported in the coal seams, large amounts of As, Au and other elements were enriched in pyrite within the coal seams, thus forming high-As coal and Carlin-type gold deposits in the Longtan Formation coal series strata.

  18. Sasol process technology - the challenge of synfuels from coal

    Energy Technology Data Exchange (ETDEWEB)

    Marriott, J.N.

    1986-08-01

    Description is given of how the design challenges were met in commissioning the Sasol Two plant in 1980, a larger plant than Sasol One, and devoted to producing liquid fuels. The design parameters included treating South African coals of poor quality with high ash contents, and rapidity in building the plant.

  19. Geomorphology of coal seam fires

    Science.gov (United States)

    Kuenzer, Claudia; Stracher, Glenn B.

    2012-02-01

    Coal fires occur in underground natural coal seams, in exposed surface seams, and in coal storage or waste piles. The fires ignite through spontaneous combustion or natural or anthropogenic causes. They are reported from China, India, USA, South Africa, Australia, and Russia, as well as many other countries. Coal fires lead to loss of a valuable resource (coal), the emission of greenhouse-relevant and toxic gases, and vegetation deterioration. A dangerous aspect of the fires is the threat to local mines, industries, and settlements through the volume loss underground. Surface collapse in coal fire areas is common. Thus, coal fires are significantly affecting the evolution of the landscape. Based on more than a decade of experience with in situ mapping of coal fire areas worldwide, a general classification system for coal fires is presented. Furthermore, coal seam fire geomorphology is explained in detail. The major landforms associated with, and induced by, these fires are presented. The landforms include manifestations resulting from bedrock surface fracturing, such as fissures, cracks, funnels, vents, and sponges. Further manifestations resulting from surface bedrock subsidence include sinkholes, trenches, depressions, partial surface subsidence, large surface subsidence, and slides. Additional geomorphologic coal fire manifestations include exposed ash layers, pyrometamorphic rocks, and fumarolic minerals. The origin, evolution, and possible future development of these features are explained, and examples from in situ surveys, as well as from high-resolution satellite data analyses, are presented. The geomorphology of coal fires has not been presented in a systematic manner. Knowledge of coal fire geomorphology enables the detection of underground coal fires based on distinct surface manifestations. Furthermore, it allows judgments about the safety of coal fire-affected terrain. Additionally, geomorphologic features are indicators of the burning stage of fires

  20. Hydrothermal Carbonization: a feasible solution to convert biomass to soil?

    Science.gov (United States)

    Tesch, Walter; Tesch, Petra; Pfeifer, Christoph

    2013-04-01

    The erosion of fertile soil is a severe problem arising right after peak oil (Myers 1996). That this issue is not only a problem of arid countries is shown by the fact that even the European Commission defined certain milestones to address the problem of soil erosion in Europe (European Commission 2011). The application of bio-char produced by torrefaction or pyrolysis for the remediation, revegetation and restoration of depleted soils started to gain momentum recently (Rillig 2010, Lehmann 2011, Beesley 2011). Hydrothermal carbonization (HTC) is a promising thermo-chemical process that can be applied to convert organic feedstock into fertile soil and water, two resources which are of high value in regions being vulnerable to erosion. The great advantage of HTC is that organic feedstock (e.g. organic waste) can be used without any special pretreatment (e.g. drying) and so far no restrictions have been found regarding the composition of the organic matter. By applying HTC the organic material is processed along a defined pathway in the Van Krevelen plot (Behrendt 2006). By stopping the process at an early stage a nutritious rich material can be obtained, which is known to be similar to terra preta. Considering that HTC-coal is rich in functional groups and can be derived from the process under "wet" conditions, it can be expected that it shall allow soil bacteria to settle more easily compared to the bio-char derived by torrefaction or pyrolysis. In addition, up to 10 tons process water per ton organic waste can be gained (Vorlop 2009). Thus, as organic waste, loss of fertile soil and water scarcity becomes a serious issue within the European Union, hydrothermal carbonization can provide a feasible solution to address these issues of our near future. The presentation reviews the different types of feedstock investigated for the HTC-Process so far and gives an overview on the current stage of development of this technology. References Beesley L., Moreno-Jiménez E

  1. Studies on the effect of coal particle size on biodepyritization of high sulfur coal in batch bioreactor

    Directory of Open Access Journals (Sweden)

    Singh Sradhanjali

    2015-03-01

    Full Text Available The moderate thermophilic mix culture bacteria were used to depyritize the Illinois coal of varying particle sizes (-100 μm, 100-200 μm, +200 μm. Mineral libration analysis showed the presence of pyrite along with other minerals in coal. Microbial depyritization of coal was carried out in stirred tank batch reactors in presence of an iron-free 9K medium. The results indicate that microbial depyritization of coal using moderate thermophiles is an efficient process. Moreover, particle size of coal is an important parameter which affects the efficiency of microbial depyritization process. At the end of the experiment, a maximum of 75% pyrite and 66% of pyritic sulphur were removed from the median particle size. The XRD analysis showed the absence of pyrite mineral in the treated coal sample. A good mass balance was also obtained with net loss of mass ranging from 5-9% showing the feasibility of the process for large scale applications.

  2. Role of coal water mixture in utility coal conversion

    Energy Technology Data Exchange (ETDEWEB)

    Bhagat, N.; Butcher, T.

    1984-05-01

    To indicate the role of coal water mixtures (CWM) in utility coal conversions, the pertinent technical, economic, environmental, and regulatory factors involved in CWM conversion are reviewed. CWM technology provides an attractive option for utility companies to convert to coal. There appear to be no major technical problems in CWM production and use that cannot be overcome. Environmental considerations, however, play an important role in utilities' decisions to convert to coal. In general, coal conversions would be seriously impeded if the installation of flue gas desulfurization units cannot be avoided, as it now can because of the DOE program, and they are also inhibited by present uncertainties regarding impending acid rain regulations. Preliminary estimates of the economics of conversion seem attractive; however, site-specific evaluation is needed to justify conversion in a given situation. Although conversion to pulverized coal appears competitive with that to CWM, some non-economic factors tend to favor CWM over PC.

  3. Fine coal circuitry using advanced physical cleaning processes

    Energy Technology Data Exchange (ETDEWEB)

    Honaker, R.Q.; Mohanty, M.K.; Wang, D. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering; Ho, K. [Illinois Clean Coal Inst., Carterville, IL (United States)

    1996-12-31

    Recent investigations have found that enhanced gravity separators (EGS) and flotation columns are highly efficient for cleaning fine coal. The test results presented in this publication show that a circuit comprised of two advanced gravity separators, i.e., a hindered-bed classifier and an EGS, and a flotation column provides an enhanced cleaning efficiency for the treatment of {minus}16 mesh coal. From in-plant experiments, the hindered-bed classifier was found to be a more efficient separation device (E{sub p} = 0.12) than coal spirals (E{sub p} = 0.18) for the treatment of a nominally 16 x 100 mesh coal. Since its efficiency declines for particle sizes less than 48 mesh, the hindered-bed classifier overflow was screened to produce a final +48 mesh concentrate and a {minus}48 mesh fraction that was subsequently treated by circuits incorporating the EGS and flotation column in combination and separately. The best overall circuits in terms of both ash and total sulfur reductions for treating the -16 mesh coal was found to be the Hindered Bed-EGS-EGS and Hindered Bed-EGS-Column circuits. Both circuits rejected over 70% of the ash and over 60% of the pyritic sulfur while recovering over 85% of the combustible material.

  4. Hydrothermal Detoxization of Slate Containing Asbestos and the Possibility of Application for Fertilizer of its Products

    Science.gov (United States)

    Myojin, Sachi; Kuroki, Toshihiro; Manabe, Wataru; Yamasaki, Chizuko; Yamasaki, Nakamichi

    2010-11-01

    Hydrothermal decomposition of slate (building materials) containing asbestos has been attempted by using a NH4H2PO4 solution. Firstly, the alteration of chrysotile as a starting material was investigated under hydrothermal conditions of 200° C, 12 hrs of reaction time and with a phosphate solution. It was confirmed that the original fibrous form of chrysotile had been perfectly collapsed by the SEM observation. The chrysotile (asbestos) disappeared to form Mg-Ca-Silicate (Ca7Mg2P6O24) estimated by XRD. The composition and chemical form of reaction products (Mg-Ca-Silicate) was predicted to application as a fertilizer. Fertilizer effect of these resulted product on cultivations of Japanese radish (leaves), soybeans and tomatoes, was examined by using a special medium of mixed soil with a low content of N, P, K and a thermal-treated zeolite one. The fertilizer effects of the product were compared to commercial fertilizers such as N, N-K-P and P types. In order to estimate the fertilizer effect, the size of crops, number of fruits and number of leaves were measured everyday. As a result, these hydrothermal products of slate containing asbestos were as good as commercial fertilizers on the market. Fruits groups especially had a good crop using the hydrothermal slate product. These results show that the main components of hydrothermal treatments slate are calcium silicate and magnesium phosphate. Its decomposition reaction products may have the possibility of application for fertilization of crops which require nucleic acid—phosphorus.

  5. Computerized estimation of coal reserves of underground coal mines

    Energy Technology Data Exchange (ETDEWEB)

    Solymosi, F.; Kiss, J.

    1988-01-01

    No standardized methodology for long term planning exists in Hungary in the coal industry. A computerized method of coal reserve estimation based on normatives is described. The method has been applied in the Maza-South-Varalja-South region (Transdanubia, South Hungary). The applicability of the method is outlined and the error limit that was missing in coal reserve estimations is suggested to be introduced.

  6. High-temperature synthesis of highly hydrothermal stable mesoporous silica and Fe-SiO 2 using ionic liquid as a template

    Science.gov (United States)

    Liu, Hong; Wang, Mengyang; Hu, Hongjiu; Liang, Yuguang; Wang, Yong; Cao, Weiran; Wang, Xiaohong

    2011-03-01

    Mesoporous silicas and Fe-SiO 2 with worm-like structures have been synthesized using a room temperature ionic liquid, 1-hexadecane-3-methylimidazolium bromide, as a template at a high aging temperature (150-190 °C) with the assistance of NaF. The hydrothermal stability of mesoporous silica was effectively improved by increasing the aging temperature and adding NaF to the synthesis gel. High hydrothermally stable mesoporous silica was obtained after being aged at 190 °C in the presence of NaF, which endured the hydrothermal treatment in boiling water at least for 10 d or steam treatment at 600 °C for 6 h. The ultra hydrothermal stability could be attributed to its high degree of polymerization of silicate. Furthermore, highly hydrothermal stable mesoporous Fe-SiO 2 has been synthesized, which still remained its mesostructure after being hydrothermally treated at 100 °C for 12 d or steam-treated at 600 °C for 6 h.

  7. Evolving patterns of the fluids within the TAG hydrothermal field

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The mixing of seawater/hydrothermal fluid within the large seafloor hydrothermal sulfide deposits plays a key role in the formation processes of the sulfide deposits.Some issues attract considerable attentions in the study of seafloor hydrothermal system in recent years,such as the relationships among different types of vent fluids,the characteristics of chemical compositions and mineral assemblages of the hydrothermal deposits and their governing factors.Combined with the measured data of hydrothermal fluid in the TAG field,the thermodynamic model of mixing processes of the heated seawater at different temperatures and the hydrothermal fluid is calculated to understand the precipitation mechanism of anhydrite and the genetic relationships between the black and white smoker fluids within the TAG mound.The results indicate that the heating of seawater and the mixing of hydrothermal fluid/seawater are largely responsible for anhydrite precipitation and the temperature of the heated seawater is not higher than 150 ℃ and the temperature of the end-member hydrothermal fluid is not lower than 400℃.Based on the simulated results,the evolving patterns of fluids within the TAG deposit are discussed.The mixed fluid of the end-member hydrothermal fluid and the seawater heated by wall rock undergoes conductive cooling during upflowing within the deposit and forms "White Smoker" eventually.In addition,the end-member hydrothermal fluid without mixed with seawater,but undergoing conductive cooling,vents out of the deposit and forms "Black Smoker".

  8. Super eruption environments make for "super" hydrothermal explosions: Extreme hydrothermal explosions in Yellowstone National Park

    Science.gov (United States)

    Morgan, L. A.; Shanks, W. P.; Pierce, K. L.

    2006-12-01

    Hydrothermal explosions are violent events resulting in the rapid ejection of boiling water, steam, mud, and rock fragments over areas that range from a few meters in diameter up to several kilometers in diameter. Hydrothermal explosions occur where shallow interconnected reservoirs of steam-saturated fluids underlie thermal fields. Sudden reduction in pressure causes the fluids to flash to steam resulting in significant expansion, rock fragmentation, and debris ejection. In Yellowstone, at least 20 large (>100 meters in diameter) hydrothermal explosions have been identified, and the scale of the individual events dwarfs similar features in other hydrothermal and geothermal areas of the world. Large explosions in Yellowstone have occurred over the past 16 ka at an interval of ~1 per every 700 yrs and similar events are likely to occur in the future. Our studies of hydrothermal explosive events indicate: 1) none are associated with magmatic or volcanic events; 2) several have been triggered by seismic events coupled with other processes; 3) lithic clasts and matrix from explosion deposits are extensively altered, indicating long-term, extensive hydrothermal mineralization in areas that were incorporated into the explosion deposit; 4) many lithic clasts in explosion breccia deposits contain evidence of repeated fracturing and cementation; and 4) dimensions of many documented large hydrothermal explosion craters in Yellowstone are similar to the dimensions of currently active geyser basins or thermal areas in Yellowstone. The vast majority of active thermal areas in Yellowstone are characterized by 1) high-temperature hot-water systems in areas of high heat-flow, 2) extensive systems of hot springs, fumaroles, geysers, sinter terraces, mud pots, and, in places, small hydrothermal explosion craters, 3) widespread alteration of host rocks, 4) large areal dimensions (>several 100 m) and 5) intermittent but long-lived activity (40,000 to 300,000 years). Critical

  9. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, Mary J.; Davis, Ryan; Jones, Susanne B.; Zhu, Yunhua

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  10. Hydrothermal alteration in oceanic ridge volcanics: A detailed study at the Galapagos Fossil Hydrothermal Field

    Science.gov (United States)

    Ridley, W.I.; Perfit, M.R.; Josnasson, I.R.; Smith, M.F.

    1994-01-01

    The Galapagos Fossil Hydrothermal Field is composed of altered oceanic crust and extinct hydrothermal vents within the eastern Galapagos Rift between 85??49???W and 85??55???W. The discharge zone of the hydrothermal system is revealed along scarps, thus providing an opportunity to examine the uppermost mineralized, and highly altered interior parts of the crust. Altered rocks collected in situ by the submersible ALVIN show complex concentric alteration zones. Microsamples of individual zones have been analysed for major/minor, trace elements, and strontium isotopes in order to describe the complex compositional details of the hydrothermal alteration. Interlayered chlorite-smectite and chlorite with disequilibrium compositions dominate the secondary mineralogy as replacement phases of primary glass and acicular pyroxene. Phenocrysts and matrix grains of plagioclase are unaffected during alteration. Using a modification of the Gresens' equation we demonstrate that the trivalent rare earth elements (REEs) are relatively immobile, and calculate degrees of enrichment and depletion in other elements. Strontium isotopic ratios increase as Sr concentrations decrease from least-altered cores to most-altered rims and cross-cutting veins in individual samples, and can be modeled by open system behaviour under low fluid-rock ratio (metal sulfides beneath the seafloor is probably a result of fluid mixing and cooling. If, as suggested here, the discharge zone alteration occurred under relatively low fluid-rock ratios, then this shallow region must play an important role in determining the exit composition of vent fluids in marine hydrothermal systems. ?? 1994.

  11. 230Th/238U dating of hydrothermal sulfides from Duanqiao hydrothermal field, Southwest Indian Ridge

    Science.gov (United States)

    Yang, Weifang; Tao, Chunhui; Li, Huaiming; Liang, Jin; Liao, Shili; Long, Jiangping; Ma, Zhibang; Wang, Lisheng

    2016-11-01

    Duanqiao hydrothermal field is located between the Indomed and Gallieni fracture zones at the central volcano, at 50°28'E in the ultraslow-spreading Southwest Indian Ridge (SWIR). Twenty-eight subsamples from a relict chimney and massive sulfides were dated using the 230Th/238U method. Four main episodes of hydrothermal activity were determined according to the restricted results: 68.9-84.3, 43.9-48.4, 25.3-34.8, and 0.7-17.3 kyrs. Hydrothermal activity of Duanqiao probably started about 84.3 (±0.5) kyrs ago and ceased about 0.737 (±0.023) kyrs ago. The periodic character of hydrothermal activity may be related to the heat source provided by the interaction of local magmatism and tectonism. The estimated mean growth rate of the sulfide chimney is Dragon Flag field is much more recent than that of Duanqiao or Mt. Jourdanne fields. The massive sulfides are younger than the sulfides from other hydrothermal fields such as Rainbow, Sonne and Ashadze-2. The preliminarily estimated reserves of sulfide ores of Duanqiao are approximately 0.5-2.9 million tons.

  12. Health impacts of coal and coal use: Possible solutions

    Science.gov (United States)

    Finkelman, R.B.; Orem, W.; Castranova, V.; Tatu, C.A.; Belkin, H.E.; Zheng, B.; Lerch, H.E.; Maharaj, S.V.; Bates, A.L.

    2002-01-01

    Coal will be a dominant energy source in both developed and developing countries for at least the first half of the 21st century. Environmental problems associated with coal, before mining, during mining, in storage, during combustion, and postcombustion waste products are well known and are being addressed by ongoing research. The connection between potential environmental problems with human health is a fairly new field and requires the cooperation of both the geoscience and medical disciplines. Three research programs that illustrate this collaboration are described and used to present a range of human health problems that are potentially caused by coal. Domestic combustion of coal in China has, in some cases, severely affected human health. Both on a local and regional scale, human health has been adversely affected by coals containing arsenic, fluorine, selenium, and possibly, mercury. Balkan endemic nephropathy (BEN), an irreversible kidney disease of unknown origin, has been related to the proximity of Pliocene lignite deposits. The working hypothesis is that groundwater is leaching toxic organic compounds as it passes through the lignites and that these organics are then ingested by the local population contributing to this health problem. Human disease associated with coal mining mainly results from inhalation of particulate matter during the mining process. The disease is Coal Worker's Pneumoconiosis characterized by coal dust-induced lesions in the gas exchange regions of the lung; the coal worker's "black lung disease". ?? 2002 Elsevier Science B.V. All rights reserved.

  13. Flotation and flocculation chemistry of coal and oxidized coals

    Energy Technology Data Exchange (ETDEWEB)

    Somasundaran, P.

    1990-01-01

    The objective of this research project is to understand the fundamentals involved in the flotation and flocculation of coal and oxidized coals and elucidate mechanisms by which surface interactions between coal and various reagents enhance coal beneficiation. An understanding of the nature of the heterogeneity of coal surfaces arising from the intrinsic distribution of chemical moieties is fundamental to the elucidation of mechanism of coal surface modification and its role in interfacial processes such as flotation, flocculation and agglomeration. A new approach for determining the distribution in surface properties of coal particles was developed in this study and various techniques capable of providing such information were identified. Distributions in surface energy, contact angle and wettability were obtained using novel techniques such as centrifugal immersion and film flotation. Changes in these distributions upon oxidation and surface modifications were monitored and discussed. An approach to the modelling of coal surface site distributions based on thermodynamic information obtained from gas adsorption and immersion calorimetry is proposed. Polyacrylamide and dodecane was used to alter the coal surface. Methanol adsorption was also studied. 62 figs.

  14. Kinetics of hydrothermal crystallization under saturated steam pressure and the self-healing effect by nanocrystallite for hydroxyapatite coatings.

    Science.gov (United States)

    Yang, Chung-Wei; Lui, Truan-Sheng

    2009-09-01

    Hydroxyapatite coatings (HACs) with a low crystalline state were prepared using the plasma spraying process followed by hermetic autoclaving hydrothermal treatment at 100, 150 and 200 degrees C. Experimental evidence confirmed that the HACs became significantly crystallized and the content of amorphous calcium phosphate decreased by performing the autoclaving hydrothermal treatment in an ambient saturated steam pressure system. The obvious chemisorbed hydroxy groups (OH) peak in the X-ray photoelectron spectra detected from the hydrothermally crystallized HAC specimens means that the hydroxyl-deficient state of plasma-sprayed HACs is significantly improved by the abundant replenished OH groups. The HA nanocrystallite observed from scanning electron microscopy and transmission electron microscopy images within hydrothermally treated HACs is the result of nucleation and grain growth through the replenishment of OH groups into the hydroxyl-deficient HA crystal structure. The microstructural self-healing effect is a result of reduction in defects (pores, microcracks and lamellar boundaries) due to new-growth HA nanocrystallite. According to the systematic derivation of the Arrhenius equation, the HA crystallization is a second-order Arrhenius reaction kinetics. Besides the effects of heating temperature and an atmosphere with abundant water molecules, the saturated steam pressure is a crucial factor which significantly improves the crystallization rate constant and further reduces the activation energy for the hydrothermal HA crystallization.

  15. Assessing the environmental impact of energy production from hydrochar generated via hydrothermal carbonization of food wastes.

    Science.gov (United States)

    Berge, Nicole D; Li, Liang; Flora, Joseph R V; Ro, Kyoung S

    2015-09-01

    Although there are numerous studies suggesting hydrothermal carbonization is an environmentally advantageous process for transformation of wastes to value-added products, a systems level evaluation of the environmental impacts associated with hydrothermal carbonization and subsequent hydrochar combustion has not been conducted. The specific objectives of this work are to use a life cycle assessment approach to evaluate the environmental impacts associated with the HTC of food wastes and the subsequent combustion of the generated solid product (hydrochar) for energy production, and to understand how parameters and/or components associated with food waste carbonization and subsequent hydrochar combustion influence system environmental impact. Results from this analysis indicate that HTC process water emissions and hydrochar combustion most significantly influence system environmental impact, with a net negative GWP impact resulting for all evaluated substituted energy-sources except biomass. These results illustrate the importance of electricity production from hydrochar particularly when it is used to offset coal-based energy sources. HTC process water emissions result in a net impact to the environment, indicating a need for developing appropriate management strategies. Results from this analysis also highlight a need for additional exploration of liquid and gas-phase composition, a better understanding of how changes in carbonization conditions (e.g., reaction time and temperature) influence metal and nutrient fate, and the exploration of liquid-phase treatment. Copyright © 2015 Elsevier Ltd. All rights reserved.

  16. Removal of residual chlorine from Indiana 5 coal by supercritical carbon dioxide extraction

    Energy Technology Data Exchange (ETDEWEB)

    Kocher, B.S.; Azzam, F.O.; Lee, S. (University of Akron, Akron, OH (United States). Dept. of Chemical Engineering)

    1994-01-01

    The perchloroethylene coal desulfurization process has unique advantages as a precombustion coal cleaning process, that include high cleaning efficiencies, mild process conditions, minimal output of undesirable byproducts, and cost effectiveness. However, the use of perchloroethylene in the process renders an important process engineering problem of complete recovery and reuse of perchloroethylene, thus requiring a 'zero discharge' condition of the solvent. Therefore, the treated coal must be stripped of any residual perchloroethylene. Carbon dioxide (CO[sub 2]) in its supercritical state has been investigated for its ability to remove chlorine from Indiana 5 coal, that has been desulfurized by the perchloroethylene (PCE) process. The reduction of Cl content from a PCE treated and filtered coal has been as high as 78% by mass. The experiments have been carried out following a statistical experimental design and the discerning characteristics of the process have been identified. The solvent density and extraction conditions can be tailored in such a way as to optimally remove C from the coal without any detrimental effects on the coal matrix. The supercritical CO[sub 2] extraction process can be successfully implemented to the PCE coal cleaning process by replacing energy intensive steps of steam stripping and vacuum drying. 6 refs., 3 figs., 3 tabs.

  17. Analysis and Processing about Spontaneous Combustion of Coal in Enclosed Circular Coal Yard with Large Coal Reserves%封闭式大储量圆形煤场储煤自燃分析及处理

    Institute of Scientific and Technical Information of China (English)

    金建华; 沈建军; 龚福; 黄健

    2014-01-01

    Due to many spontaneous combustions of coal in enclosed circular coal yard with large coal reserves, it is imminent to know how to prevent and control coal spontaneous combustion.As analysised,the main rea-sons of coal spontaneous combustion are Coal stocks,high coal volatile,increase of coal oxidation layer and water catalytic.So,the keys to prevent and control coal spontaneous combustion are reduce of the contact area of the air and coal,control of moisture content in coal,good ventilation cooling measures and so on.There-fore,,putting forward the establishment of a sound quality management files,“first in first out,burn the old new,regular replacement”,control of the oxygen supply for spontaneous combustion of coal,timely treatment once finding the signs,strict control of time of spontaneous combustion of coal entry storage and measures on how to treat the spontaneous combustion of coal strategy measures can greatly improve the safety factor of the coal yard and the economic benefits of the power plant.%针对燃煤电厂发生多起封闭式大储量圆形煤场储煤自燃问题,如何防止和治理煤炭自燃迫在眉睫。分析认为,煤炭自燃的主要原因是煤场库存量大、煤炭挥发分高、堆煤氧化层增大和水分催化,而减少空气与煤的接触面,控制煤中的水分含量,做好通风散热等措施,是预防和治理圆形煤场储煤自燃的关键。为此,提出建立健全煤质管理档案、“先进先出,烧旧存新,定期置换”、控制煤炭自燃的供氧量、发现自燃征兆及时处理、严控自燃煤的入场堆存时间和处理煤炭自燃的策略等措施,提高煤场的安全运行和电厂的经济效益。

  18. Coal Mining-Related Respiratory Diseases

    Science.gov (United States)

    ... Topics Publications and Products Programs Contact NIOSH NIOSH COAL WORKERS' HEALTH SURVEILLANCE PROGRAM Recommend on Facebook Tweet Share Compartir Coal Mining-Related Respiratory Diseases Coal mining-related respiratory ...

  19. Hydrotreating of coal-derived liquids

    Energy Technology Data Exchange (ETDEWEB)

    Lott, S.E.; Stohl, F.V.; Diegert, K.V. [Sandia National Lab., Albuquerque, NM (United States)] [and others

    1995-12-31

    To develop a database relating hydrotreating parameters to feed and product quality by experimentally evaluating options for hydrotreating whole coal liquids, distillate cuts of coal liquids, petroleum, and blends of coal liquids with petroleum.

  20. A review of state-of-the-art processing operations in coal preparation

    Institute of Scientific and Technical Information of China (English)

    Noble Aaron; Luttrell Gerald H.

    2015-01-01

    Coal preparation is an integral part of the coal commodity supply chain. This stage of post-mining, pre-utilization beneficiation uses low-cost separation technologies to remove unwanted mineral matter and moisture which hinder the value of the coal product. Coal preparation plants typically employ several parallel circuits of cleaning and dewatering operations, with each circuit designed to optimally treat a specific size range of coal. Recent innovations in coal preparation have increased the efficiency and capac-ity of individual unit operations while reinforcing the standard parallel cleaning approach. This article, which describes the historical influences and state-of-the-art design for the various coal preparation unit operations, is organized to distinguish between coarse/intermediate coal cleaning and fine/ultrafine coal cleaning. Size reduction, screening, classification, cleaning, dewatering, waste disposal unit operations are particularly highlighted, with a special focus on the U.S. design philosophy. Notable differences between the U.S. and international operations are described as appropriate.

  1. Numerical simulation of magmatic hydrothermal systems

    Science.gov (United States)

    Ingebritsen, S.E.; Geiger, S.; Hurwitz, S.; Driesner, T.

    2010-01-01

    The dynamic behavior of magmatic hydrothermal systems entails coupled and nonlinear multiphase flow, heat and solute transport, and deformation in highly heterogeneous media. Thus, quantitative analysis of these systems depends mainly on numerical solution of coupled partial differential equations and complementary equations of state (EOS). The past 2 decades have seen steady growth of computational power and the development of numerical models that have eliminated or minimized the need for various simplifying assumptions. Considerable heuristic insight has been gained from process-oriented numerical modeling. Recent modeling efforts employing relatively complete EOS and accurate transport calculations have revealed dynamic behavior that was damped by linearized, less accurate models, including fluid property control of hydrothermal plume temperatures and three-dimensional geometries. Other recent modeling results have further elucidated the controlling role of permeability structure and revealed the potential for significant hydrothermally driven deformation. Key areas for future reSearch include incorporation of accurate EOS for the complete H2O-NaCl-CO2 system, more realistic treatment of material heterogeneity in space and time, realistic description of large-scale relative permeability behavior, and intercode benchmarking comparisons. Copyright 2010 by the American Geophysical Union.

  2. Hydrothermal synthesis of zeolites from natural stellerite

    Institute of Scientific and Technical Information of China (English)

    李酽; 汪信; 董元彩; 朱俊武

    2002-01-01

    Y and P zeolites were synthesized hydrothermally from natural stellerite under different conditions and were characterized via XRD and FT-IR.The results show that the higher crystallinity of Y zeolite can be obtained in hydrothermal system with low alkalinity,low Ca2+/Na+ ratio,and high SiO2/Al2O3 ratio.The lattice space of the samples decreases as crystallization time increases.P Zeolite is prompted under condition of higher alkalinity and higher Ca2+/Na+ ratio.The intensity and number of bands in the range of 400 cm-1~900 cm-1 increases with reaction time.Bands at 680 cm-1,760 cm-1 and 860 cm-1 corresponding to Y zeolite appear during the crystallization stage.Most of these bands shift to higher wavenumbers when SiO2/Al2O3 ratio increases generally.In the hydrothermal system with reverse condition above,bands at 600 cm-1,420 cm-1~470 cm-1 hardly change as the crystallization time increases and the main crystal phase of P zeolite is obtained.

  3. Surface roughened zirconia: towards hydrothermal stability.

    Science.gov (United States)

    Camposilvan, Erik; Flamant, Quentin; Anglada, Marc

    2015-07-01

    Surface roughness is needed in several yttria-stabilized zirconia components used in restorative dentistry for osseointegration or adhesion purposes. This can be achieved by different treatments, which may also modify the microstructure of the surface. Among them, sandblasting and chemical etching are widely used, but their effect on hydrothermal aging of zirconia is not fully understood. In the present work, the zirconia long-term stability of rough surfaces prepared by these techniques is analyzed and a method is proposed for preventing hydrothermal aging while maintaining the original surface appearance and mechanical properties. The method involves pressure infiltration of a Cerium salt solution on the roughened surfaces followed by a thermal treatment. The solution, trapped by surface defects and small pores, is decomposed during thermal treatment into Cerium oxide, which is diffused at high temperature, obtaining Ce co-doping in the near-surface region. In addition, the microstructural changes induced in the near-surface by sandblasting or chemical etching are removed by the thermal treatment together with surface defects. No color modification was observed and the final roughness parameters were in the range of existing implants of proved good osseointegration. The aging resistance of Ce co-doped materials was strongly enhanced, showing the absence of aging after artificial degradation, increasing in this way the surface mechanical integrity. The proposed treatment is easily applicable to the current manufacturing procedures of zirconia dental posts, abutments, crowns and dentures, representing a solution to hydrothermal aging in these and other biomedical applications.

  4. Hydrothermal Formation of Calcium Copper Tetrasilicate.

    Science.gov (United States)

    Johnson-McDaniel, Darrah; Comer, Sara; Kolis, Joseph W; Salguero, Tina T

    2015-12-01

    We describe the first hydrothermal synthesis of CaCuSi4 O10 as micron-scale clusters of thin platelets, distinct from morphologies generated under salt-flux or solid-state conditions. The hydrothermal reaction conditions are surprisingly specific: too cold, and instead of CaCuSi4 O10 , a porous calcium copper silicate forms; too hot, and calcium silicate (CaSiO3 ) forms. The precursors also strongly impact the course of the reaction, with the most common side product being sodium copper silicate (Na2 CuSi4 O10 ). Optimized conditions for hydrothermal CaCuSi4 O10 formation from calcium chloride, copper(II) nitrate, sodium silicate, and ammonium hydroxide are 350 °C at 3000 psi for 72 h; at longer reaction times, competitive delamination and exfoliation causes crystal fragmentation. These results illustrate that CaCuSi4 O10 is an even more unique material than previously appreciated.

  5. Hydrothermal synthesis of xonotlite from carbide slag

    Institute of Scientific and Technical Information of China (English)

    Jianxin Cao; Fei Liu; Qian Lin; Yu Zhang

    2008-01-01

    Carbide slag was used as the calcareous materials for the first time to prepare xonotlite via dynamic hydrothermal synthesis.The effects of influential factors including different calcination temperatures,pretreatment methods of the carbide slag and process param-eters of hydrothermal synthesis on the microstructure and morphology of xonotlite were explored using XRD and SEM techniques.The results indicate that the carbide slag after proper calcination could be used to prepare pure xonotlite;and different calcination tern-peratures have little effect on the crystallinity of synthesized xonotlitc,but have great impact on the morphology of secondary particles.The different pretreatment methods of the carbide slag pose great impact on the crystallinity and morphology of secondary particles of xonotlite.Xonotlite was also synthesized from pure CaO under the salne experimental conditions as that prepared from calcined carbide slag for comparison.Little amount of impurities in carbide slag has no effect on the mechanism of hydrothermal synthesizing xonotlite from carbide slag.

  6. The effects of moderate coal cleaning on the microbial removal of organic sulfur. Technical report, September 1--November 30, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Srivastava, V.J.

    1991-12-31

    The purpose of this project is to investigate the possibilities of developing an integrated physical/chemical/microbial process for the precombustion removal of sulfur from coal. An effective pre- combustion coal desulfurization process should ideally be capable of removing both organic and inorganic sulfur. A variety of techniques exist for the removal of inorganic sulfur from coal, but there is currently no cost-effective method for the pre-combustion removal of organic sulfur. Recent developments have demonstrated that microorganisms are capable of specifically cleaving carbon-sulfur bonds and removing substantial amounts of organic sulfur from coal. However, lengthy treatment times are required. Moreover, the removal of organic sulfur form coal by microorganisms is hampered by the fact that, as a solid substrate, it is difficult to bring microorganisms in contact with the entirety of a coal sample. This study will examine the suitability of physically/chemically treated coal sample for subsequent biodesulfurization. Physical/chemical processes primarily designed for the removal of pyritic sulfur may also cause substantial increases in the porosity and surface area of the coal which may facilitate the subsequent removal of organic sulfur by microoganisms. During the current quarter, coal samples that have been chemically pretreated with methanol, ammonia, and isopropanol were examined for the removal of organic sulfur by the microbial culture IGTS8, an assay for the presence of protein in coal samples was developed, and a laboratory-scale device for the explosive comminution of coal was designed and constructed.

  7. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 1, Final technical report, October 1, 1991--September 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., (United States); Gutterman, C. [Foster Wheeler Development Corp., Livingston, NJ (United States); Chander, S. [Pennsylvania State Univ., (United States)

    1994-12-31

    The overall objective of this project was to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrated coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. Heterofunctional solvents were the most effective in swelling coals. Also solvent blends such as isopropanol/water were more effective than pure solvents alone. Impregnating slurry catalysts simultaneously during coal swelling showed that better uptake was achieved with nonswelling solvent and higher impregnation temperature. Some enhancement in initial coal conversion was seen liquefying SO{sub 2}-treated Black Thunder coal with slurry catalysts, and also when hydrogen donor liquefaction solvents were used. Noncatalytic reactions showed no benefit from SO{sub 2} treatment. Coupling coal swelling and SO{sub 2} treatment with slurry catalysts was also not beneficial, although high conversion was seen with continuous operation and long residence time, however, similar high conversion was observed with untreated coal. SO{sub 2} treatment is not economically attractive unless it provides about 17% increase in coal reactivity. In most cases, the best results were obtained when the coal was untreated and the slurry catalyst was added directly into the reactor. Foster Wheeler`s ASCOT process had better average liquid yields than either Wilsonville`s vacuum tower/ROSE combination or delayed coking process. This liquid product also had good quality.

  8. Development of low rank coals upgrading and their CWM producing technology; Teihin`itan kaishitsu ni yoru CWM seizo gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Sugiyama, T. [Center for Coal Utilization, Japan, Tokyo (Japan); Tsurui, M.; Suto, Y.; Asakura, M. [JGC Corp., Tokyo (Japan); Ogawa, J.; Yui, M.; Takano, S. [Japan COM Co. Ltd., Japan, Tokyo (Japan)

    1996-09-01

    A CWM manufacturing technology was developed by means of upgrading low rank coals. Even though some low rank coals have such advantages as low ash, low sulfur and high volatile matter content, many of them are merely used on a small scale in areas near the mine-mouths because of high moisture content, low calorification and high ignitability. Therefore, discussions were given on a coal fuel manufacturing technology by which coal will be irreversibly dehydrated with as much volatile matters as possible remaining in the coal, and the coal is made high-concentration CWM, thus the coal can be safely transported and stored. The technology uses a method to treat coal with hot water under high pressure and dry it with hot water. The method performs not only removal of water, but also irreversible dehydration without losing volatile matters by decomposing hydrophilic groups on surface and blocking micro pores with volatile matters in the coal (wax and tar). The upgrading effect was verified by processing coals in a pilot plant, which derived greater calorification and higher concentration CWM than with the conventional processes. A CWM combustion test proved lower NOx, lower SOx and higher combustion rate than for bituminous coal. The ash content was also found lower. This process suits a Texaco-type gasification furnace. For a production scale of three million tons a year, the production cost is lower by 2 yen per 10 {sup 3} kcal than for heavy oil with the same sulfur content. 11 figs., 15 tabs.

  9. Effects of MAPP Compatibilization and Acetylation Treatment Followed by Hydrothermal Aging on Polypropylene Alfa Fiber Composites

    Directory of Open Access Journals (Sweden)

    Noura Hamour

    2015-01-01

    Full Text Available This work investigates the effect of hydrothermal aging on the properties of polypropylene/alfa fiber composites. Hydrothermal aging was induced in an environmental testing chamber at 65°C and 75% relative humidity (RH over a 1000 h period. At the beginning (t=0 h, the results showed that Young’s moduli of the untreated alfa fibers and the acetylation-treated fibers increased by 21% and 36%, respectively, compared with the virgin polypropylene (PP. Additionally, Young’s moduli decreased by 7% for the compatibilized composites composed of maleic anhydride grafted polypropylene (MAPP. After 1000 h of aging, Young’s moduli decreased by 36% for untreated alfa fibers and 29% for the acetylation-treated alfa fibers and the compatibilized composites. Significant degradation was observed in the untreated alfa fiber samples. The Fourier transformed infrared (FTIR allows us to distinguish the characteristic absorption bands of the main chemical functions present in the composite material before and after aging. The thermal properties showed that the thermal stability and the degree of crystallinity of the composites decreased after hydrothermal aging; this result was corroborated by the dynamical mechanical analysis (DMA results.

  10. Photocatalytic degradation of rhodamine B dye using hydrothermally synthesized ZnO

    Indian Academy of Sciences (India)

    K Byrappa; A K Subramani; S Ananda; K M Lokanatha Rai; R Dinesh; M Yoshimura

    2006-10-01

    The sunlight mediated photocatalytic degradation of rhodamine B (RB) dye was studied using hydrothermally prepared ZnO ( = 150°C and ∼ 20–30 bars). Zinc chloride was used as the starting material along with sodium hydroxide as a solvent in the hydrothermal synthesis of ZnO. Different durations were tried to obtain pure ZnO phase, which was later confirmed through powder X-ray diffraction. The photocatalytic behaviour of the prepared ZnO was tested through the degradation of RB. The disappearance of organic molecules follows first-order kinetics. The effect of various parameters such as initial dye concentration, catalyst loading, pH of the medium, temperature of the dye solution, on the photo degradation of RB were investigated. The thermodynamic parameters of the photodegradation of RB, like energy of activation, enthalpy of activation, entropy of activation and free energy of activation revealed the efficiency of the process. An actual textile effluent containing RB as a major constituent along with other dyes and dyeing auxiliaries was treated using hydrothermally synthesized ZnO and the reduction in the chemical oxygen demand (COD) of the treated effluent revealed a complete destruction of the organic molecules along with colour removal.

  11. Hydrothermal Formation of Lath-Shaped Trioctahedral Smectite with High Crystallinity

    Institute of Scientific and Technical Information of China (English)

    Hirohisa YAMADA; Kenji TAMURA; Shingo YOKOYAMA; Yujiro WATANABE

    2006-01-01

    Lath-shaped and highly crystalline trioctahedral smectites were synthesized under hydrothermal conditions. The quenched glasses with stoichiometrically dehydrated Na-smectite compositions were treated at (a) 500℃ and 100 MPa for 1 and 11 days; and (b) 300℃ and 100 MPa for 7 days. The crystallinity and particle size of products were dependent on the chemical composition of the starting glass, synthetic temperature and duration of hydrothermal treatment. The high structural ordering and large dimensions of the products were confirmed from the sharpness of XRD peaks; and hydration behavior under controlled relative humidity. Transmission electron microscopy was also performed for the characterization of the particle size of product. Particle sizes vary from ca. 10 nm to a few μm by changing the chemical compositions of the starting materials. The product with the highest structural ordering and largest dimension was obtained from Na0.33(Mg1.83Al0.67)Si4O11 glass treated at 500℃ and 100 MPa for 1 day. The obtained results also confirmed the metastability and compositional dependency in the formation of highly crystalline trioctahedral smectite at hydrothermal conditions.

  12. Hydrothermal processing of MSWI fly ash--towards new stable minerals and fixation of heavy metals.

    Science.gov (United States)

    Bayuseno, A P; Schmahl, W W; Müllejans, Th

    2009-08-15

    A hydrothermal processing strategy of MSWI fly ash is presented for obtaining stable minerals with low toxic potential. Different hydrothermal conditions were tested to obtain high yields of new stable minerals. Experimental parameters including temperature, nature and molarity of alkali reagents, and reaction time were evaluated. The chemical stability of hydrothermal products was examined by the toxicity characteristic leaching procedure (TCLP) test and subsequent XRD for the leached residue. The significant amounts of Al-substituted 11A tobermorite and katoite in addition to minor amounts of zeolites were formed under experimental conditions at 0.5M NaOH, 180 degrees C for 48 h, however KOH treatment in a similar regime resulted in smaller amounts of Al-substituted 11A tobermorite and katoite. Similarly, a product of mixed Al-substituted 11A tobermorite and katoite could be formed from the washed fly ash treated in 0.5M NaOH at 180 degrees C for 48 h. Under the acidic condition, the treated fly ash exhibited an excellent stability of the mineral assemblage and less release of heavy metals relative to the untreated parent materials.

  13. Hydrothermal treatment of titanium alloys for the enhancement of osteoconductivity.

    Science.gov (United States)

    Zuldesmi, Mansjur; Waki, Atsushi; Kuroda, Kensuke; Okido, Masazumi

    2015-04-01

    The surface wettability of implants is a crucial factor in their osteoconductivity because it influences the adsorption of cell-attached proteins onto the surface. In this study, a single-step hydrothermal surface treatment using distilled water at a temperature of 180°C for 3h was applied to titanium (Ti) and its alloys (Ti-6Al-4V, Ti-6Al-7Nb, Ti-29Nb-13Ta-4.6Zr, Ti-13Cr-1Fe-3Al; mass%) and compared with as-polished Ti implants and with implants produced by anodizing Ti in 0.1M of H3PO4 with applied voltages from 0V to 150V at a scanning rate of 0.1Vs(-1). The surface-treated samples were stored in a five time phosphate buffered saline (×5 PBS(-)) solution to prevent increasing the water contact angle (WCA) with time. The surface characteristics were evaluated using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Auger electron spectroscopy, surface roughness, and contact angle measurement using a 2μL droplet of distilled water. The relationship between WCA and osteoconductivity at various surface modifications was examined using in vivo tests. The results showed that a superhydrophilic surface with a WCA≤10° and a high osteoconductivity (RB-I) of up to 50% in the cortical bone part, about four times higher than the as-polished Ti and Ti alloys, were provided by the combination of the hydrothermal surface treatment and storage in ×5 of PBS(-).

  14. Enzymatic desulfurization of coal

    Energy Technology Data Exchange (ETDEWEB)

    Marquis, J.K. (Boston Univ., MA (United States). School of Medicine); Kitchell, J.P. (Holometrix, Inc., Cambridge, MA (United States))

    1988-12-15

    Our current efforts to develop clean coal technology emphasize the advantages of enzymatic desulfurization techniques and have specifically addressed the potential of using partially-purified extracellular microbial enzymes or commercially available enzymes. Our work is focused on the treatment of model'' organic sulfur compounds such as dibenzothiophene (DBT) and ethylphenylsulfide (EPS). Furthermore, we are designing experiments to facilitate the enzymatic process by means of a hydrated organic solvent matrix.

  15. Coal Bed Methane Primer

    Energy Technology Data Exchange (ETDEWEB)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of

  16. Microbial desulfurization of coal

    Energy Technology Data Exchange (ETDEWEB)

    Danzet, C.; Buonfiglio, V.; Polidoro, M.; Valenti, P. (Rome Univ. La Sapienza (Italy). Ist. di Microbiologia)

    This paper reviews the biochemical and economics aspects of coal desulfurization processes involving the use of thermophile microorganisms such as sulfolobus, currently believed to be the the only type of microorganism capable of degrading both inorganic (pyrite-containing) and organic sulfur compounds. Comments are also made on the feasibility of the development of an in-lab, microbial based method for the transformation of the lignin component, obtained in the processing, by anaerobic fermentation, of lignocellulosic biomass, into humic acid.

  17. Spectrum of underground coal gasification in Tianjin

    Energy Technology Data Exchange (ETDEWEB)

    Xu Yongsheng; Bai Xiaohong [Tianjin Urban Construction Inst. (China)

    1997-12-31

    A feasibility study on underground coal gasification in Tianjin is conducted and a program for exploitation of these coal reserves with UCG techniques is suggested. Some issues, such as the coal resources in Tianjin, the geological features of the selected for UCG trial, the characteristics of local coal deposits and the coal quality are discussed. A proposal for a combination of the production of coalbed methane and underground coal gas was summarized.

  18. Mode I fracture toughness of coal

    Energy Technology Data Exchange (ETDEWEB)

    Bhagat, R.B.

    1985-10-01

    This investigation was undertaken to determine the fracture toughness and tensile strength of coal and to correlate these with the grindability of the coals in order to understand the fracture mechanics behaviour of coal. Results showed statistical relationships for the dependence of fracture toughness on the tensile strength of coal and between the fracture toughness and the Hardgrove Grindability Index. Softer coals have a lower fracture toughness value as coal is a brittle material. 16 references.

  19. (Bioprocessing of lignite coals using reductive microorganisms)

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, D.L.

    1990-01-01

    The objectives of this report are to: (1) characterize selected aerobic bacterial strains for their abilities to depolymerize lignite coal polymers, and isolate and identify the extracellular enzymes responsible for depolymerization of the coal; (2) characterize selected strictly anaerobic bacteria, that were previously shown to reductively transform coal substructure model compounds, for the ability to similarly transform polymeric coal; and (3) isolate more strains of anaerobic bacteria by enrichment using additional coal substructure model compounds and coal as substrates.

  20. The Coal Reserves Database Program

    Energy Technology Data Exchange (ETDEWEB)

    Bonskowski, R. (Energy Information Administration, Washington, DC (United States))

    1993-01-01

    The Energy Information Administration (EIA) initiated the Coal Reserves Data Base (CRDB) Program in October, 1990 in order to update and improve the inherent applicability of EIA's national coal reserves database. Currently, EIA's database is derived from the demonstrated reserve base (DRB) of coal, a compilation of data from published sources, unified by adherence to standardized physical criteria of minability, but never intended for the detailed coal supply and policy analyses demanded today. The CRDB Program is designed to engage the expertise available at State geological surveys in compiling best current State-level estimates of both quantities and quality of available coal reserves through cooperative agreements with EIA. The CRDB emphasizes integration of more data on coal quality, use of data from unpublished sources, cooperation with industry and other government sources, and flexibility of criteria to take into account local accessibility and mining conditions and utilize computerized geographic information systems or coal resource software. The results of pilot projects in Ohio and Wyoming are summarized. Areas nominated for support in the program include 15 additional priority coal regions in 14 States, which comprise 95 percent of the current reserve estimates and most of the coal-bearing areas of low sulfur potential. 8 refs., 3 figs., 3 tabs.

  1. The Global Value of Coal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    Coal plays an essential role in our global energy mix, particularly for power generation; and through that to the alleviation of energy poverty. The use of coal continues to grow rapidly and will continue, together with other fuels, to support world economic and social development particularly in rapidly developing world economies such as China and India. The purpose of this paper is to highlight for policy makers the value of coal to world economic and social development and so encourage development of a policy environment that will allow the coal and electricity industries to make the necessary investments in production capacity and CO2 emissions reduction technologies.

  2. Chemical analyses of coal, coal-associated rocks and coal combustion products collected for the National Coal Quality Inventory

    Science.gov (United States)

    Hatch, Joseph R.; Bullock, John H.; Finkelman, Robert B.

    2006-01-01

    In 1999, the USGS initiated the National Coal Quality Inventory (NaCQI) project to address a need for quality information on coals that will be mined during the next 20-30 years. At the time this project was initiated, the publicly available USGS coal quality data was based on samples primarily collected and analyzed between 1973 and 1985. The primary objective of NaCQI was to create a database containing comprehensive, accurate and accessible chemical information on the quality of mined and prepared United States coals and their combustion byproducts. This objective was to be accomplished through maintaining the existing publicly available coal quality database, expanding the database through the acquisition of new samples from priority areas, and analysis of the samples using updated coal analytical chemistry procedures. Priorities for sampling include those areas where future sources of compliance coal are federally owned. This project was a cooperative effort between the U.S. Geological Survey (USGS), State geological surveys, universities, coal burning utilities, and the coal mining industry. Funding support came from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE).

  3. Coal Discovery Trail officially opens

    Energy Technology Data Exchange (ETDEWEB)

    Gallinger, C. [Elk Valley Coal Corporation, Sparwood, BC (Canada)

    2004-09-01

    The opening of the 30-kilometre Coal Discovery Trail in August is described. The trail, through a pine, spruce, and larch forest, extends from Sparwood to Fernie and passes through Hosmer, a historic mining site. The trail, part of the Elk Valley Coal Discovery Centre, will be used for hiking, bicycling, horseback riding, and cross-country skiing. The Coal Discovery Centre will provide an interpretive centre that concentrates on history of coal mining and miners, preservation of mining artifacts and sites, and existing technology. 3 figs.

  4. Geophysical imaging of shallow degassing in a Yellowstone hydrothermal system

    Science.gov (United States)

    Pasquet, S.; Holbrook, W. S.; Carr, B. J.; Sims, K. W. W.

    2016-12-01

    The Yellowstone Plateau Volcanic Field, which hosts over 10,000 thermal features, is the world's largest active continental hydrothermal system, yet very little is known about the shallow "plumbing" system connecting hydrothermal reservoirs to surface features. Here we present the results of geophysical investigations of shallow hydrothermal degassing in Yellowstone. We measured electrical resistivity, compressional-wave velocity from refraction data, and shear wave velocity from surface-wave analysis to image shallow hydrothermal degassing to depths of 15-30 m. We find that resistivity helps identify fluid pathways and that Poisson's ratio shows good sensitivity to saturation variations, highlighting gas-saturated areas and the local water table. Porosity and saturation predicted from rock physics modeling provide critical insight to estimate the fluid phase separation depth and understand the structure of hydrothermal systems. Finally, our results show that Poisson's ratio can effectively discriminate gas- from water-saturated zones in hydrothermal systems.

  5. Hydrothermal Treatment of Tannin: A Route to Porous Metal Oxides and Metal/Carbon Hybrid Materials

    Directory of Open Access Journals (Sweden)

    Flavia L. Braghiroli

    2017-01-01

    Full Text Available In the present paper, porous materials were prepared from the hydrothermal treatment of aqueous solutions of tannin, a renewable phenolic resource extracted from tree barks, containing dissolved salts of transition metals: V, Cr, Ni and Fe. Hydrothermal treatment produced carbonaceous particles doped with the aforementioned metals, and such materials were treated according to two different routes: (i calcination in air in order to burn the carbon and to recover porous oxides; (ii pyrolysis in inert atmosphere so as to recover porous metal/carbon hybrid materials. The nature of the metal salt was found to have a dramatic impact on the structure of the materials recovered by the first route, leading either to nano-powders (V, Cr or to hollow microspheres (Ni, Fe. The second route was only investigated with iron, leading to magnetic Fe-loaded micro/mesoporous carbons whose texture, pore volumes and surface areas gradually changed with the iron content.

  6. Hydrothermal synthesis of nanostructured titania; Sintese hidrotermica de ceramicas de titania nanoestruturada

    Energy Technology Data Exchange (ETDEWEB)

    Yoshito, W.K.; Ferreira, N.A.M.; Lazar, D.R.R.; Ussui, V., E-mail: wkyoshito@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Rumbao, A.C.S. [Universidade Presbiteriana Mackenzie (UPM), Sao Paulo, SP (Brazil)

    2011-07-01

    Titania ceramics have many applications due to its surface properties and, recently, its nanostructured compounds, prepared by hydrothermal treatments, have been described to improve these properties. In this work, commercial titanium dioxide was treated with 10% sodium hydroxide solution in a pressurized reactor at 150 deg C for 24 hours under vigorous stirring and then washed following two different procedures. The first one consisted of washing with water and ethanol and the second with water and hydrochloric acid solution (1%). Resulting powders were characterized by X-ray diffraction, N{sub 2} gas adsorption and field emission gun scanning and transmission electronic microscopy. Results showed that from an original starting material with mainly rutile phase, both anatase and H{sub 2}Ti{sub 3}O{sub 7} phase could be identified after the hydrothermal treatment. Surface area of powders presented a notable increase of one order of magnitude and micrographs showed a rearrangement on the microstructure of powders. (author)

  7. U and Th Concentration and Isotopic Composition of Hydrothermal Fluids at the Lost City Hydrothermal Field

    Science.gov (United States)

    Ludwig, K. A.; Shen, C.; Cheng, H.; Edwards, R.; Kelley, D. S.; Butterfield, D. A.

    2006-12-01

    Uranium and Th concentration and isotopic composition of hydrothermal fluids at the Lost City Hydrothermal Field (LCHF) were determined using multi-collector inductively coupled plasma mass spectrometry (MC-ICP- MS). The LCHF is an off-axis, serpentinite-hosted hydrothermal system located at 30°N near the Mid- Atlantic Ridge. Carbonate chimneys reaching 60 m in height vent alkaline (pH~10), calcium-rich fluids at 40- 91°C and the towers are home to dense microbial communities. Vent fluid and seawater U and Th concentration and isotopic composition data provide critical information for constraining U-Th chimney ages. The increased sensitivity (1-2%) of MC-ICP-MS combined with an Aridus nebulization system allows the precise measurement of small quantities of sample (~150 ml) with low concentrations (ICP-MS techniques to measure the U and Th concentration and isotopic composition (234U, 238U, 230Th, and 232Th) of eight hydrothermal fluid samples. Endmember fluids with ~1mmol/kg Mg have ~0.02 ng/g U, confirming that end-member fluids contain near-zero values of both Mg and U. Thorium concentrations of fluids are close to deep seawater values. U and Th isotopic compositions are reported at the permil level. These data may provide new insights into the role of serpentinite-hosted hydrothermal systems in the budgets of U and Th in the ocean. Techniques presented in this study may be applied to other hydrothermal and seep environments.

  8. Belite cement clinker from coal fly ash of high Ca content. Optimization of synthesis parameters

    Energy Technology Data Exchange (ETDEWEB)

    A. Guerrero; S. Goni; I. Campillo; A. Moragues [Instituto de Ciencias de la Construccion ' Eduardo Torroja' (CSIC), Madrid (Spain)

    2004-06-01

    The optimization of parameters of synthesis of belite cement clinker from Spanish coal fly ash of high Ca content is presented in this paper. The investigations were prompted by a need to reduce the CO{sub 2} emissions produced by the cement industry. Belite Ca{sub 2}SiO{sub 4} synthesis produces less CO{sub 2} than alite, the main component of Portland cement clinker. The synthesis process is based on the hydrothermal-calcination-route of the fly ash without extra additions. The hydrothermal treatment was carried out in demineralized water and a 1 M NaOH solution for 4 h at the temperatures of 100, 150, and 200{sup o} C. The precursors obtained during the hydrothermal treatment were heated at temperatures of 700, 800, 900, and 1000{sup o}C. The changes of fly ash composition after the different treatments were characterized by X-ray diffraction (XRD), FT infrared (FTIR) spectroscopy, surface area (BET-N{sub 2}), and thermal analyses. From the results obtained it was concluded that the optimum temperature of the hydrothermal treatment was 200{sup o}C, and the optimum temperature for obtaining the belite cement clinker was 800{sup o}C. 12 refs., 11 figs., 2 tabs.

  9. Hydrothermal Conditions and the Origin of Cellular Life.

    Science.gov (United States)

    Deamer, David W; Georgiou, Christos D

    2015-12-01

    The conditions and properties of hydrothermal vents and hydrothermal fields are compared in terms of their ability to support processes related to the origin of life. The two sites can be considered as alternative hypotheses, and from this comparison we propose a series of experimental tests to distinguish between them, focusing on those that involve concentration of solutes, self-assembly of membranous compartments, and synthesis of polymers. Key Word: Hydrothermal systems.

  10. Minor element distribution in iron disulfides in coal: a geochemical review

    Science.gov (United States)

    Kolker, Allan

    2012-01-01

    Electron beam microanalysis of coal samples in U.S. Geological Survey (USGS) labs confirms that As is the most abundant minor constituent in Fe disulfides in coal and that Se, Ni, and other minor constituents are present less commonly and at lower concentrations than those for As. In nearly all cases, Hg occurs in Fe disulfides in coal at concentrations below detection by electron beam instruments. Its presence is shown by laser ablation ICP-MS, by selective leaching studies of bulk coal, and by correlation with Fe disulfide proxies such as total Fe and pyritic sulfur. Multiple generations of Fe disulfides are present in coal. These commonly show grain-to-grain and within-grain minor- or trace element compositional variation that is a function of the early diagenetic, coalification, and post-coalification history of the coal. Framboidal pyrite is almost always the earliest Fe disulfide generation, as shown by overgrowths of later Fe disulfides which may include pyrite or marcasite. Cleat- (or vein) pyrite (or marcasite) is typically the latest Fe disulfide generation, as shown by cross-cutting relations. Cleat pyrite forms by fluid migration within a coal basin and consequently may be enriched in elements such as As by deposition from compaction-driven fluids, metal enriched basinal brines or hydrothermal fluids. In some cases, framboidal pyrite shows preferential Ni enrichment with respect to co-occurring pyrite forms. This is consistent with bacterial complexing of metals in anoxic sediments and derivation of framboidal pyrite from greigite (Fe3S4), an Fe monosulfide precursor to framboidal pyrite having the thio-spinel structure which accommodates transition metals. Elements such as As, Se, and Sb substitute for S in the pyrite structure whereas metals, including transition metals, Hg and Pb, are thought to substitute for Fe. Understanding the distribution of minor and trace elements in Fe disulfides in coal has important implications for their availability to

  11. Interactions Between Serpentinization, Hydrothermal Activity and Microbial Community at the Lost City Hydrothermal Field

    Science.gov (United States)

    Delacour, A.; Frueh-Green, G. L.; Bernasconi, S. M.; Schaeffer, P.; Frank, M.; Gutjahr, M.; Kelley, D. S.

    2008-12-01

    Seafloor investigations of slow- and ultraslow-spreading ridges have reported many occurrences of exposed mantle peridotites and gabbroic rocks on the ocean floor. Along the Mid-Atlantic Ridge, these uplifted portions of oceanic crust host high-temperature black smoker-type hydrothermal systems (e.g., Rainbow, Logatchev, Saldanha), and the more distinct low-temperature Lost City Hydrothermal Field (LCHF). Built on a southern terrace of the Atlantis Massif, the LCHF is composed of carbonate-brucite chimneys that vent alkaline and low-temperature (40-90°C) hydrothermal fluids. These fluids are related to serpentinization of mantle peridotites, which together with minor gabbroic intrusions form the basement of the LCHF. Long-lived hydrothermal activity at Lost City led to extensive seawater-rock interaction in the basement rocks, as indicated by seawater-like Sr- and mantle to unradiogenic Nd-isotope compositions of the serpentinites. These high fluid fluxes in the southern part of the massif influenced the conditions of serpentinization and have obliterated the early chemical signatures in the serpentinites, especially those of carbon and sulfur. Compared to reducing conditions commonly formed during the first stages of serpentinization, serpentinization at Lost City is characterized by relatively oxidizing conditions resulting in a predominance of magnetite, the mobilization/dissolution and oxidation of igneous sulfides to secondary pyrite, and the incorporation of seawater sulfate, all leading to high bulk-rock S-isotope compositions. The Lost City hydrothermal fluids contain high concentrations in methane, hydrogen, and low-molecular weight hydrocarbons considered as being produced abiotically. In contrast, organic compounds in the serpentinites are dominated by the occurrences of isoprenoids (pristane, phytane, and squalane), polycyclic compounds (hopanes and steranes), and higher abundances of C16 to C20 n-alkanes indicative of a marine organic input. We

  12. Theoretical constraints of physical and chemical properties of hydrothermal fluids on variations in chemolithotrophic microbial communities in seafloor hydrothermal systems

    Science.gov (United States)

    Nakamura, Kentaro; Takai, Ken

    2014-12-01

    In the past few decades, chemosynthetic ecosystems at deep-sea hydrothermal vents have received attention as plausible analogues to the early ecosystems of Earth, as well as to extraterrestrial ecosystems. These ecosystems are sustained by chemical energy obtained from inorganic redox substances (e.g., H2S, CO2, H2, CH4, and O2) in hydrothermal fluids and ambient seawater. The chemical and isotope compositions of the hydrothermal fluid are, in turn, controlled by subseafloor physical and chemical processes, including fluid-rock interactions, phase separation and partitioning of fluids, and precipitation of minerals. We hypothesized that specific physicochemical principles describe the linkages among the living ecosystems, hydrothermal fluids, and geological background in deep-sea hydrothermal systems. We estimated the metabolic energy potentially available for productivity by chemolithotrophic microorganisms at various hydrothermal vent fields. We used a geochemical model based on hydrothermal fluid chemistry data compiled from 89 globally distributed hydrothermal vent sites. The model estimates were compared to the observed variability in extant microbial communities in seafloor hydrothermal environments. Our calculations clearly show that representative chemolithotrophic metabolisms (e.g., thiotrophic, hydrogenotrophic, and methanotrophic) respond differently to geological and geochemical variations in the hydrothermal systems. Nearly all of the deep-sea hydrothermal systems provide abundant energy for organisms with aerobic thiotrophic metabolisms; observed variations in the H2S concentrations among the hydrothermal fluids had little effect on the energetics of thiotrophic metabolism. Thus, these organisms form the base of the chemosynthetic microbial community in global deep-sea hydrothermal environments. In contrast, variations in H2 concentrations in hydrothermal fluids significantly impact organisms with aerobic and anaerobic hydrogenotrophic metabolisms

  13. Coal resources of Indiana

    Science.gov (United States)

    Spencer, Frank Darwyn

    1953-01-01

    The Indiana coal field forms the eastern edge of the eastern interior coal basin, which is near some of the most densely populated and highly productive manufacturing areas of the United States. (See fig. 1. ) For this reason Indiana coal reserves are an important State and National asset. In dollar value the coal mining industry is the largest of Indiana's natural-resource-producing industries. The total value of coil production for the year 1950 was more than 100 million dollars, or more than that of all other natural-resource industries in the State combined. As estimated herein, the original coal reserves of Indiana total 37,293 million tons, of which 27,320 million tons is contained in beds more than 42 inches thick; 7,632 million tons in beds 28 to 49. inches thick; and 2,341 million tons in beds 14 to 28 inches thick. The remaining reserves as of January 1951, total 35,806 million tons, of which 18,779 million tons is believed to be recoverable. The distribution of the reserves in these several categories is summarized by counties in table 1. Of the total original reserves of 37,293 million tons, 6,355 million tons can be classified as measured; 8,657 million tons as indicated; and 22,281 million tons as inferred. Strippable reserves constitute 3,524 million tons, or 9.5 percent of the total original reserves. The distribution of the strippable and nonstrippable original reserves is summarized in tables 2 and 3 by counties and by several categories, according to the thickness of the beds and the relative abundance and reliability of the information available for preparing the estimates. The distribution of the estimated 18,779 million tons of recoverable strippable and nonstrippable reserves in Indiana is further summarized by counties in table 4, and the information is presented graphically in figures 2 and 3. The tables i to 4 and figures 2 and 3 include beds in the 14- to 28-inch category, because thin beds have been mined in many places. However, many

  14. Simple model for fault-charged hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Bodvarsson, G.S.; Miller, C.W.; Benson, S.M.

    1981-06-01

    A two-dimensional transient model of fault-charged hydrothermal systems has been developed. The model can be used to analyze temperature data from fault-charged hydrothermal systems, estimate the recharge rate from the fault, and determine how long the system has been under natural development. The model can also be used for theoretical studies of the development of fault-controlled hydrothermal systems. The model has been tentatively applied to the low-temperature hydrothermal system at Susanville, California. A resonable match was obtained with the observed temperature data, and a hot water recharge rate of 9 x 10{sup -6} m{sup 3}s/m was calculated.

  15. Heat and mass flux estimation of modern seafloor hydrothermal activity

    Institute of Scientific and Technical Information of China (English)

    ZHAI Shikui; WANG Xingtao; YU Zenghui

    2006-01-01

    Research on heat and mass flux yielded by modern seafloor hydrothermal activity is very important, because it is involved not only in the base of ocean environment research, but also in the historical evolution of seawater properties. Currently, estimating heat flux is based on the observation data of hydrothermal smokers, low-temperature diffusive flow and mid-ocean ridge mainly. But there are some faults, for example, there is lack of a concurrent conductive item in estimating the heat flux by smokers and the error between the half-space cooling model and the observation data is too large. So, three kinds of methods are applied to re-estimating the heat flux of hydrothermal activity resepectively, corresponding estimation is 97.359 GW by hydrothermal smoker and diffusive flow, 84.895 GW by hydrothermal plume, and 4.11 TW by exponential attenuation method put forward by this paper. Research on mass flux estimation is relatively rare, the main reason for this is insufficient field observation data. Mass fluxes of different elements are calculated using hydrothermal vent fluid data from the TAG hydrothermal area on the Mid-Atlantic Ridge for the first time. Difference of estimations by different methods reflects the researching extent of hydrothermal activity, and systematically in-situ observation will help to estimate the contribution of hydrothermal activity to ocean chemical environment, ocean circulation and global climate precisely.

  16. Recovery of clean coal from polymer flocculated raw coal slurry

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, B.K.; Chen, Z. [Center for Applied Energy Research, Lexington, KY (US)

    2004-11-01

    The recovery of fine clean coal from waste streams using column flotation is recognized as an efficient and economical technique. However, due to the low percent solids (around 3% by weight) found in these fine waste slurries, the flotation columns have low capacities and are, thus, underutilized. In this study, a 3% (by weight) solids suspension of Upper Freeport coal was flocculated with polymers and concentrated to 10% (by weight) solids. The flocculated slurry was then floated using 250 g/t No. 2 fuel oil and 250 g/t MIBC, which provided a clean coal with 12% ash at an 80% yield. The results showed that flocculated coal could be floated effectively. Zeta potential and contact-angle data showed that the presence of polymer on the surface of the coal did not affect its hydrophobicity, and in some cases it improved the hydrophobicity as indicated by larger contact angles.

  17. Prospects for coal and clean coal technologies in Malaysia

    Energy Technology Data Exchange (ETDEWEB)

    Paul Baruya [IEA Clean Coal Centre, London (United Kingdom)

    2010-07-15

    Malaysia is a regular participant in world coal trade. Coal production is a modest 1 Mt/y but, as an importer, the country trades some 30 Mt/y. As one of ASEAN's most prosperous economies, the expected growth in electricity demand is inevitable. For many years the country has been dependent on gas-fired power, much of which is in the form of expensive single cycle gas turbines. However, coal-fired power has emerged as an important provider of power in a country desperate to improve its energy security. This report looks at how coal-fired power has developed, and examines the current technologies deployed in the country. It is the fourth in a series of reports by the lEA Clean Coal Centre on ASEAN countries, following Indonesia, Thailand and Vietnam. 35 refs., 14 figs., 4 tabs.

  18. CoalVal-A coal resource valuation program

    Science.gov (United States)

    Rohrbacher, Timothy J.; McIntosh, Gary E.

    2010-01-01

    CoalVal is a menu-driven Windows program that produces cost-of-mining analyses of mine-modeled coal resources. Geological modeling of the coal beds and some degree of mine planning, from basic prefeasibility to advanced, must already have been performed before this program can be used. United States Geological Survey mine planning is done from a very basic, prefeasibility standpoint, but the accuracy of CoalVal's output is a reflection of the accuracy of the data entered, both for mine costs and mine planning. The mining cost analysis is done by using mine cost models designed for the commonly employed, surface and underground mining methods utilized in the United States. CoalVal requires a Microsoft Windows? 98 or Windows? XP operating system and a minimum of 1 gigabyte of random access memory to perform operations. It will not operate on Microsoft Vista?, Windows? 7, or Macintosh? operating systems. The program will summarize the evaluation of an unlimited number of coal seams, haulage zones, tax entities, or other area delineations for a given coal property, coalfield, or basin. When the reader opens the CoalVal publication from the USGS website, options are provided to download the CoalVal publication manual and the CoalVal Program. The CoalVal report is divided into five specific areas relevant to the development and use of the CoalVal program: 1. Introduction to CoalVal Assumptions and Concepts. 2. Mine Model Assumption Details (appendix A). 3. CoalVal Project Tutorial (appendix B). 4. Program Description (appendix C). 5. Mine Model and Discounted Cash Flow Formulas (appendix D). The tutorial explains how to enter coal resource and quality data by mining method; program default values for production, operating, and cost variables; and ones own operating and cost variables into the program. Generated summary reports list the volume of resource in short tons available for mining, recoverable short tons by mining method; the seam or property being mined

  19. Evaluating the risk of coal bursts in underground coal mines

    Institute of Scientific and Technical Information of China (English)

    Mark Christopher⇑; Gauna Michael

    2016-01-01

    Coal bursts involve the sudden, violent ejection of coal or rock into the mine workings. They are almost always accompanied by a loud noise, like an explosion, and ground vibration. Bursts are a particular haz-ard for miners because they typically occur without warning. Despite decades of research, the sources and mechanics of these events are not well understood, and therefore they are difficult to predict and control. Experience has shown, however, that certain geologic and mining factors are associated with an increased likelihood of a coal burst. A coal burst risk assessment consists of evaluating the degree to which these risk factors are present, and then identifying appropriate control measures to mitigate the hazard. This paper summarizes the U.S. and international experience with coal bursts, and describes the known risk factors in detail. It includes a framework that can be used to guide the risk assessment process.

  20. Physicochemical properties of Mecsek coal. 2. Coal-gas interactions

    Energy Technology Data Exchange (ETDEWEB)

    Toth, J.; Lakatos, J. [MTA Banyaszati Kemiai Kutatolab, Miskolc (Hungary)

    1995-02-01

    There are two models for interpretation of the internal structure of coals. One of them supposes that the coal structure is similar to the active carbons having macro- and micropores. The second model supposes that the molecules sorbed in the coal are present in a molecular lattice structure. The authors have measured the sorption isotherms and isobars of different gases (nitrogen, methane, carbon dioxide) in coals. They have calculated the equivalent specific surface areas and their temperature dependences. The results have been compared to similar data calculated from methanol-water and methanol-benzene excess isotherms. It was found that the surface areas calculated from gas sorption isotherms and methanol water excess isotherms are comparable. From the methanol-benzene excess isotherms approximately one order of magnitude higher surface areas were obtained. This finding was attributed to the lamellar structure of Mecsek coal and to the intercalated clay minerals.

  1. Progress in developments of dry coal beneficiation

    Institute of Scientific and Technical Information of China (English)

    Yuemin Zhao; Xuliang Yang; Zhenfu Luo; Chenlong Duan; Shulei Song

    2014-01-01

    China’s energy supply heavily relies on coal and China’s coal resource and water resource has a reverse distribution. The problem of water shortages restricts the applications of wet coal beneficiation technologies in drought regions. The present situation highlights the significance and urgency of developing dry beneficiation technologies of coal. Besides, other countries that produce large amounts of coal also encounter serious problem of lack of water for coal beneficiation, such as American, Australia, Canada, South Africa, Turkey and India. Thus, dry coal beneficiation becomes the research hot-points in the field of coal cleaning worldwide in recent years. This paper systematically reviewed the promising research efforts on dry coal beneficiation reported in literature in last 5 years and discussed the progress in developments of dry coal beneficiation worldwide. Finally, we also elaborated the prospects and the challenges of the development of dry coal beneficiation.

  2. Research and development to prepare and characterize robust coal/biomass mixtures for direct co-feeding into gasification systems

    Energy Technology Data Exchange (ETDEWEB)

    Felix, Larry [Inst. Of Gas Technology, Des Plaines, IL (United States); Farthing, William [Inst. Of Gas Technology, Des Plaines, IL (United States); Hoekman, S. Kent [Inst. Of Gas Technology, Des Plaines, IL (United States)

    2014-12-31

    This project was initiated on October 1, 2010 and utilizes equipment and research supported by the Department of Energy, National Energy Technology Laboratory, under Award Number DE- FE0005349. It is also based upon previous work supported by the Department of Energy, National Energy Technology Laboratory, under Award Numbers DOE-DE-FG36-01GOl1082, DE-FG36-02G012011 or DE-EE0000272. The overall goal of the work performed was to demonstrate and assess the economic viability of fast hydrothermal carbonization (HTC) for transforming lignocellulosic biomass into a densified, friable fuel to gasify like coal that can be easily blended with ground coal and coal fines and then be formed into robust, weather-resistant pellets and briquettes.

  3. Hydrothermal calcium modification of 316L stainless steel and its apatite forming ability in simulated body fluid.

    Science.gov (United States)

    Valanezahad, Alireza; Ishikawa, Kunio; Tsuru, Kanji; Maruta, Michito; Matsuya, Shigeki

    2011-01-01

    To understand the feasibility of calcium (Ca) modification of type 316L stainless steel (316L SS) surface using hydrothermal treatment, 316L SS plates were treated hydrothermally in calcium chloride (CaCl(2)) solution. X-ray photoelectron spectroscopic analysis revealed that the surface of 316L SS plate was modified with Ca after hydrothermal treatment at 200°C. And the immobilized Ca increased with CaCl(2) concentration. However no Ca-modification was occurred for 316L SS plates treated at 100°C. When Ca-modified 316L SS plate was immersed in simulated body fluid (SBF) with ion concentrations nearly equal to those of human blood plasma, low crystalline apatite was precipitated on its surface whereas no precipitate was observed on non Ca-modified 316L SS. The results obtained in the present study indicated that hydrothermal treatment at 200°C in CaCl(2) solution is useful for Ca-modification of 316L SS, and Ca-modification plays important role for apatite precipitation in SBF.

  4. Expedient utilization of wastes from the 'Tverditza' coal preparation plant

    Energy Technology Data Exchange (ETDEWEB)

    Kalchev, B.; Kamburova, G.; Terziev, S.

    1982-08-01

    The paper treats the problem of waste utilization at the Tverditza coal preparation plant in the Balkan coal basin, where, due to low coal quality (77.22% ash), more than 60% of the total run-of-mine coal is disposed of as waste on nearby spoil banks. The results of chemical analysis of waste material are given, showing that this material may be used for production of ceramic products and bricks. Results of industrial utilization of prepared waste material (crushed to under 3 mm) at the Demir Slavov ceramic factory are described. Annually more than 230,000 tons of waste material containing 77-80% or 60-65% of carbon may be used for production of ceramic products and bricks in ceramic factories of the Balkan coal basin, bringing about an annual savings of 300,000 BLevs. (4 refs.)

  5. Study of oxidative desulphurization process of coal with different metamorphism degrees

    Institute of Scientific and Technical Information of China (English)

    SPYSH'YEV; V GUNKA; YPRYSIAZHNYI; K SHEVCHUK; A PATTEK-JANCZYK

    2012-01-01

    The oxidative desulphurization process of coal with different metamorphism degrees treated by an air-steam mixture has been studied.It has been shown that the pyrite present in black coal and anthracite is oxidized with the sulphur dioxide formation,and the process chemical mechanism does not depend on the quality of organic matter.The medium-metamorphized coal,capable of turning into a plastic state and cake in the range of investigated temperatures ( 350 ~ 450 ℃ ),is desulphurized with the greatest difficulty.The chemical mechanism dealing with the transformations of pyritic sulphur present in brown coal differs from similar processes taking place in black coal and anthracite,because FeS2 is converted with hydrogen sulphide formation at desulphurization.

  6. Treating Meningitis

    Science.gov (United States)

    ... David C. Spencer, MD Steven Karceski, MD Treating meningitis Steven Karceski, MD WHAT DID THE AUTHORS STUDY? ... study, “ Dexamethasone and long-term survival in bacterial meningitis, ” Dr. Fritz and his colleagues carefully evaluated 2 ...

  7. Treating Vomiting

    Science.gov (United States)

    ... hours. Your pediatrician usually won’t prescribe a drug to treat the vomiting, but some doctors will prescribe antinausea medications to children. If your child also has diarrhea, ask your pediatrician for instructions on giving liquids ...

  8. Alteration of MX-80 by hydrothermal treatment under high salt content conditions

    Energy Technology Data Exchange (ETDEWEB)

    Pusch, R. [Geodevelopment AB, Lund (Sweden); Kasbohm, J. [Greifswald Univ. (Germany). Geological Dep.

    2002-02-01

    If brammalit, i.e. sodium illite, is formed from smectite in Na-rich salt water at high temperature such conversion can also take place in the buffer clay that surrounds the canisters in a KBS-3 repository. The present study comprised two laboratory test series with MX-80 clay, one with compacted clay powder with a dry density of 1200 to 1300 kg/m{sup 3} and saturation with 10% and 20% NaCl solutions followed by heating to 110 deg C under closed conditions for 30 days. In the second series air-dry compacted clay powder in a cell was heated at 110 deg C for the same period of time and connected to vessels with 10% and 20% NaCl solutions. The first series represents the conditions in the buffer clay after saturation with Na-rich salt water while the second one corresponds to the conditions in the course of saturation with such water. All laboratory tests were made after short-term percolation with distilled water for making sure that the hydro-thermally treated samples were fully fluid-saturated. The results from the physical testing showed that the hydraulic conductivity and swelling pressure of the hydrothermally treated clay samples were on the same order of magnitude as for untreated clay. Comparison with illitic clays shows that the latter are at least a hundred times more permeable than the hydrothermally treated salt clays in the present study, which hence indicates that conversion to illite was insignificant. This is obvious also from the fact that while illitic clays have very low swelling pressures the hydrothermally treated clays exhibited swelling pressures on the same order of magnitude as untreated MX-80. XRD analysis showed a clear difference in mineral constitution between the two test series. Thus, while no significant change from the typical mineralogy of untreated MX-80 was found for hydrothermal treatment of clay saturated with 10 and 20% NaCl solution, except for some very slight neoformation of illite-smectite mixed layers or irreversible

  9. Alteration of MX-80 by hydrothermal treatment under high salt content conditions

    Energy Technology Data Exchange (ETDEWEB)

    Pusch, R. [Geodevelopment AB, Lund (Sweden); Kasbohm, J. [Greifswald Univ. (Germany). Geological Dep.

    2002-02-01

    If brammalit, i.e. sodium illite, is formed from smectite in Na-rich salt water at high temperature such conversion can also take place in the buffer clay that surrounds the canisters in a KBS-3 repository. The present study comprised two laboratory test series with MX-80 clay, one with compacted clay powder with a dry density of 1200 to 1300 kg/m{sup 3} and saturation with 10% and 20% NaCl solutions followed by heating to 110 deg C under closed conditions for 30 days. In the second series air-dry compacted clay powder in a cell was heated at 110 deg C for the same period of time and connected to vessels with 10% and 20% NaCl solutions. The first series represents the conditions in the buffer clay after saturation with Na-rich salt water while the second one corresponds to the conditions in the course of saturation with such water. All laboratory tests were made after short-term percolation with distilled water for making sure that the hydro-thermally treated samples were fully fluid-saturated. The results from the physical testing showed that the hydraulic conductivity and swelling pressure of the hydrothermally treated clay samples were on the same order of magnitude as for untreated clay. Comparison with illitic clays shows that the latter are at least a hundred times more permeable than the hydrothermally treated salt clays in the present study, which hence indicates that conversion to illite was insignificant. This is obvious also from the fact that while illitic clays have very low swelling pressures the hydrothermally treated clays exhibited swelling pressures on the same order of magnitude as untreated MX-80. XRD analysis showed a clear difference in mineral constitution between the two test series. Thus, while no significant change from the typical mineralogy of untreated MX-80 was found for hydrothermal treatment of clay saturated with 10 and 20% NaCl solution, except for some very slight neoformation of illite-smectite mixed layers or irreversible

  10. Targeting organic molecules in hydrothermal environments on Mars

    Science.gov (United States)

    Parnell, J.; Bowden, S. A.; Lindgren, P.; Wilson, R.; Cooper, J. M.

    2008-09-01

    Hydrothermal deposits on Mars Hydrothermal systems are proposed as environments that could support organic synthesis, the evolution of life or the maintenance of life [1,2,3]. They have therefore been suggested as primary targets for exploration on Mars [1,2,4,].There is now confidence that hydrothermal deposits occur at the martian surface. This is based on a range of criteria that could point towards hydrothermal activity, including volcanic activity, magmatic-driven tectonism, impact cratering in icy terrains, hydrous alteration of minerals and typical hydrothermal mineralogies [4]. The proposals to search for evidence of life at martian hydrothermal sites have been focussed on seeking morphological evidence of microbial activity [5]. Here we discuss the potential to seek a chemical signature of organic matter in hydrothermal systems. Organics in terrestrial hydrothermal systems Terrestrial hydrothermal systems can have large quantities of organic matter because they intersect organic-rich sedimentary rocks or oil reservoirs. Thus the signatures that they contain reflect some preexisting concentration of fossil organic compounds, rather than life which was active in the hydrothermal system. If any extant life was incorporated in these hydrothermal systems, it is swamped by the fossil molecules. Examples of environments where organic materials may become entrained include subsurface hydrothermal mineral deposits, generation of hydrothermal systems by igneous intrusions, and hot fluid venting at the seafloor. Nevertheless, there is value in studying the interactions of hydrothermal systems with fossil organic matter, for information about the survivability of organic compounds, phase relationships between carbonaceous and noncarbonaceous materials, and where in hydrothermal deposits to find evidence of organic matter. Microbial colonization of hot spring systems is feasible at depth within the systems and at the surface where the hydrothermal waters discharge

  11. Thermography in the coal industry

    Energy Technology Data Exchange (ETDEWEB)

    Van De Ven, H., E-mail: hvandeven@thesnellgroup.com [The Snell Group, Barre, VT (United States)

    2013-03-15

    In the past, maintenance in the coal industry was using the 'run-to-failure' philosophy. This mindset is not only costly; it can also be dangerous. Today, some of the more progressive coal companies are trying to find ways to be more cost effective in their maintenance practices including adding infrared thermography for to their maintenance process. (author)

  12. Coal preparation. Energy program report

    Energy Technology Data Exchange (ETDEWEB)

    Anastas, M.Y.

    1975-06-01

    This is one of several special reports prepared in conjunction with a broad state-of-the-art study on underground coal mining. This report is essentially a review of the current technology of coal preparation and future research needs in this field. (GRA)

  13. Coal: Energy for the future

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-01

    This report was prepared in response to a request by the US Department of energy (DOE). The principal objectives of the study were to assess the current DOE coal program vis-a-vis the provisions of the Energy Policy Act of 1992 (EPACT), and to recommend the emphasis and priorities that DOE should consider in updating its strategic plan for coal. A strategic plan for research, development, demonstration, and commercialization (RDD and C) activities for coal should be based on assumptions regarding the future supply and price of competing energy sources, the demand for products manufactured from these sources, technological opportunities, and the need to control the environmental impact of waste streams. These factors change with time. Accordingly, the committee generated strategic planning scenarios for three time periods: near-term, 1995--2005; mid-term, 2006--2020; and, long-term, 2021--2040. The report is divided into the following chapters: executive summary; introduction and scope of the study; overview of US DOE programs and planning; trends and issues for future coal use; the strategic planning framework; coal preparation, coal liquid mixtures, and coal bed methane recovery; clean fuels and specialty products from coal; electric power generation; technology demonstration and commercialization; advanced research programs; conclusions and recommendations; appendices; and glossary. 174 refs.

  14. Power Generation from Coal 2011

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    This report focuses mainly on developments to improve the performance of coal-based power generation technologies, which should be a priority -- particularly if carbon capture and storage takes longer to become established than currently projected. A close look is taken of the major ongoing developments in process technology, plant equipment, instrumentation and control. Coal is an important source of energy for the world, particularly for power generation. To meet the growth in demand for energy over the past decade, the contribution from coal has exceeded that of any other energy source. Additionally, coal has contributed almost half of total growth in electricity over the past decade. As a result, CO2 emissions from coal-fired power generation have increased markedly and continue to rise. More than 70% of CO2 emissions that arise from power generation are attributed to coal. To play its role in a sustainable energy future, its environmental footprint must be reduced; using coal more efficiently is an important first step. Beyond efficiency improvement, carbon capture and storage (CCS) must be deployed to make deep cuts in CO2 emissions. The need for energy and the economics of producing and supplying it to the end-user are central considerations in power plant construction and operation. Economic and regulatory conditions must be made consistent with the ambition to achieve higher efficiencies and lower emissions. In essence, clean coal technologies must be more widely deployed.

  15. Supercritical multicomponent solvent coal extraction

    Science.gov (United States)

    Corcoran, W. H.; Fong, W. S.; Pichaichanarong, P.; Chan, P. C. F.; Lawson, D. D. (Inventor)

    1983-01-01

    The yield of organic extract from the supercritical extraction of coal with larger diameter organic solvents such as toluene is increased by use of a minor amount of from 0.1 to 10% by weight of a second solvent such as methanol having a molecular diameter significantly smaller than the average pore diameter of the coal.

  16. Major Changes in Coal Industry

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ In recent years, facing the unprecedented difficulties and challenges such as fuel price increase, supply tension of power coal and increasing pressure of environmental protection, the survival of power enterprises is subjected to certain squeeze. The impact of coal industry on the power industry is increasing.

  17. Coal Mine Methane in Russia

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    This paper discusses coal mine methane emissions (CMM) in the Russian Federation and the potential for their productive utilisation. It highlights specific opportunities for cost-effective reductions of CMM from oil and natural gas facilities, coal mines and landfills, with the aim of improving knowledge about effective policy approaches.

  18. Impacts of Coal Seam Gas (Coal Bed Methane) and Coal Mining on Water Resources in Australia

    Science.gov (United States)

    Post, D. A.

    2013-12-01

    Mining of coal bed methane deposits (termed ';coal seam gas' in Australia) is a rapidly growing source of natural gas in Australia. Indeed, expansion of the industry is occurring so quickly that in some cases, legislation is struggling to keep up with this expansion. Perhaps because of this, community concern about the impacts of coal seam gas development is very strong. Responding to these concerns, the Australian Government has recently established an Independent Expert Scientific Committee (IESC) to provide advice to the Commonwealth and state regulators on potential water-related impacts of coal seam gas and large coal mining developments. In order to provide the underlying science to the IESC, a program of ';bioregional assessments' has been implemented. One aim of these bioregional assessments is to improve our understanding of the connectivity between the impacts of coal seam gas extraction and groundwater aquifers, as well as their connection to surface water. A bioregional assessment can be defined as a scientific analysis of the ecology, hydrology, geology and hydrogeology of a bioregion, with explicit assessment of the potential direct, indirect and cumulative impacts of coal seam gas and large coal mining development on water resources. These bioregional assessments are now being carried out across large portions of eastern Australia which are underlain by coal reserves. This presentation will provide an overview of the issues related to the impacts of coal seam gas and coal mining on water resources in Australia. The methodology of undertaking bioregional assessments will be described, and the application of this methodology to six priority bioregions in eastern Australia will be detailed. Preliminary results of the program of research to date will be assessed in light of the requirements of the IESC to provide independent advice to the Commonwealth and State governments. Finally, parallels between the expansion of the industry in Australia with that

  19. The new face of coal

    Energy Technology Data Exchange (ETDEWEB)

    White, G. [Coal Association of Canada, Calgary, AB (Canada)

    2007-09-15

    Coal is particularly abundant in western Canada. The expected increase in coal consumption is at variance with the worldwide demand to reduce greenhouse gas (GHG) emissions. At the current global consumption of 5 billion tonnes per year, 10 billion tonnes of carbon dioxide (CO{sub 2}) are emitted per year from coal alone. Almost none of this coal is captured and ultimately ends up in the earth's atmosphere. Much of the world's coal is used directly for electricity production. This article presented solutions to reduce the CO{sub 2} footprint of coal while expanding consumption at a rate of 74 per cent over 25 years. Nearly every coal-fired power plant in the world is becoming more efficient. Less fuel is being burned to make the same amount of energy, resulting in fewer CO{sub 2} emissions. The newest plants can be as much as 90 per cent more efficient than the oldest. In Canada, many coal-fired plants have heat rate efficiencies of 10,200 KJ/kWh, each producing 0.90 tonnes of CO{sub 2} per kWh. A potential 20 per cent reduction in CO{sub 2} emissions will result if Canada's oldest plants are replaced with best available new coal combustion technology. It is expected that within the next 30 years, almost all of Canada's aging coal-fired plants will require replacement. Interest in the coal gasification process is growing worldwide. Rather than converting coal-fired electricity production to gas, the coal can be converted to form synthesis gas that can readily be used in natural gas-fired power plants to make electricity. The coal gasification process also produces a pure stream of CO{sub 2}, which can be captured as a by-product and sequestered in the earth. CO{sub 2} sequestration is a proven technology and is currently being done with large quantities of CO{sub 2} from an operating gasification plant in North Dakota. The CO{sub 2} is being piped from North Dakota to the Weyburn oil field in Saskatchewan where it is being stored and used to

  20. Concentrations and modes of occurrence of trace elements in the Late Permian coals from the Puan Coalfield, southwestern Guizhou, China

    Energy Technology Data Exchange (ETDEWEB)

    Yang, J.Y. [Xian University of Science & Technology, Xian (China)

    2006-12-15

    The concentration, mode of occurrence, and origin of trace elements in the Late Permian coals from the Puan Coalfield, southwestern Guizhou, China, were examined using inductively coupled plasma-mass spectrometry (ICP-MS), X-ray fluorescence (XRF), cold-vapor atomic absorption spectrometry (CV-AAS), ion-selective electrode method (ISE), sequential chemical extraction procedure (SCEP), scanning electron microscopy equipped with energy-dispersive X-ray (SEM-EDX), and optical microscope. Results show that minerals in the No. 2 Coal from the Puan Coalfield were mainly made up of epigenetic pyrite of low-temperature hydrothermal fluid origin and kaolinite of detrital terrigenous origin. Elements including As (36.9 {mu} g/g), Cd (10.2 {mu} g/g), Cr (167.3 {mu} g/g), Cu (365.4 {mu} g/g), Hg (2.82 {mu} g/g), Mo (92.6 {mu} g/g), Ni (82.6 {mu} g/g), Pb (184.6 {mu} g/g), Se (6.23 {mu} g/g), Zn (242.3 {mu} g/g), and U (132.7 {mu} g/g) are significantly enriched in the No. 2 Coal from the Puan Coalfield. However, concentrations of trace elements in the other four coals, the No. 1, No. 8, No. 11, and No. 18 Coals, were close to the usual ranges found for Guizhou of China, China, and USA. Results of SEM-EDX and SCEP showed that As, Cd, Hg, Mo, Ni, Pb, and Zn occur mainly in veined pyrite, while Cr, Cu, and U distribute mainly in kaolinite, indicating that the low-temperature hydrothermal fluid and detrital materials of terrigenous origin are the main contributors to the enrichment of these trace elements in the No. 2 Coal.

  1. Surfactant-Assisted Coal Liquefaction

    Science.gov (United States)

    Hickey, Gregory S.; Sharma, Pramod K.

    1993-01-01

    Obtaining liquid fuels from coal which are economically competitive with those obtained from petroleum based sources is a significant challenge for the researcher as well as the chemical industry. Presently, the economics of coal liquefaction are not favorable because of relatively intense processing conditions (temperatures of 430 degrees C and pressures of 2200 psig), use of a costly catalyst, and a low quality product slate of relatively high boiling fractions. The economics could be made more favorable by achieving adequate coal conversions at less intense processing conditions and improving the product slate. A study has been carried out to examine the effect of a surfactant in reducing particle agglomeration and improving hydrodynamics in the coal liquefaction reactor to increase coal conversions...

  2. Development coal tippler facility. [Japan

    Energy Technology Data Exchange (ETDEWEB)

    Hanzawa, F.

    1985-01-01

    Development coal at Mitsui Coal Mining's Ashibetsu mine was previously hauled in tubs through horizontal and inclined roadways to a tippler installed at the -410 m level, where it was transferred to a trunk belt conveyor which took it to the surface. However, when working faces began operating at depths in excess of -600 m, the main inclined shaft winding machine was found to be of insufficient capacity. Accordingly, a tippler for development coal has recently been installed in an unused coal storage pocket at the -600 m level, in conjunction with an extension to the trunk conveyor. The effect of this addition has been to reduce by 75% the amount of development coal handled by tubs in the main inclined shaft, and to reduce the number of operators required, by six.

  3. Removal of pollutants from wastewater by coal bottom ash.

    Science.gov (United States)

    Lin, Chiu-Yue; Yang, Dong-Hao

    2002-09-01

    Coal bottom ash produced from a thermal power plant was used in a batch experiment to investigate the adsorption characteristic of this bottom ash. The adsorbate solutions were synthetic wastewaters contained copper (Cu2+) or COD and a sanitary landfill leachate. The influences of various factors, such as contact time, pH, initial adsorbate concentration and temperature on the sorption have been studied. Experimental results show that coal bottom ash had a good adsorption capacity for copper and COD and could reduce the concentrations of various pollutants in the leachate. The adsorption capacities of each gram of coal bottom ash were 0.48 mg Cu (at pH 4 and temperature 25 degrees C) and 7.5 mg COD (at pH 5 and temperature 25 degrees C); their adsorption behaviors conformed to Freundlich's adsorption model. In treating leachate, the removal efficiencies of COD, NH3--N, total Kjeldah nitrogen, phosphorus, Fe3+, Mn2+ and Zn2+ were 47, 39.4, 31.1, 92.9, 96.5, 94.3 and 82.2%, respectively. Based on these results we can conclude that it is possible to use coal bottom ash for removing pollutants from wastewaters. The adsorption capacities of coal bottom ash for pollutants were also determined.

  4. Research on coal structure indices to coal and gas outbursts in Pingdingshan Mine Area, China

    Institute of Scientific and Technical Information of China (English)

    郭德勇; 宋广太; 库明欣

    2002-01-01

    According to the feature that coal and gas outbursts is controlled by coal structure in Pingdingshan mine area, based on the study of the distribution law of disturbed coal in Mine Area and the macroscopic characteristics of coal structure, the characteristics and genesis to micro-pore of disturbed coal, the relationship between the type of coal structure and gas parameter, and the structural feature of coal at outbursts sites are mainly explored in this paper. Further, the steps and methods are put forward that coal structure indices applied to forecast coal and gas outbursts.

  5. Porosity evolution in Icelandic hydrothermal systems

    Science.gov (United States)

    Thien, B.; Kosakowski, G.; Kulik, D. A.

    2014-12-01

    Mineralogical alteration of reservoir rocks, driven by fluid circulation in natural or enhanced hydrothermal systems, is likely to influence the long-term performance of geothermal power generation. A key factor is the change of porosity due to dissolution of primary minerals and precipitation of secondary phases. Porosity changes will affect fluid circulation and solute transport, which, in turn, influence mineralogical alteration. This study is part of the Sinergia COTHERM project (COmbined hydrological, geochemical and geophysical modeling of geotTHERMal systems, grant number CRSII2_141843/1) that is an integrative research project aimed at improving our understanding of the sub-surface processes in magmatically-driven natural geothermal systems. These are typically high enthalphy systems where a magmatic pluton is located at a few kilometers depth. These shallow plutons increase the geothermal gradient and trigger the circulation of hydrothermal waters with a steam cap forming at shallow depth. Field observations suggest that active and fossil Icelandic hydrothermal systems are built from a superposition of completely altered and completely unaltered layers. With help of 1D and 2D reactive transport models (OpenGeoSys-GEM code), we investigate the reasons for this finding, by studying the mineralogical evolution of protoliths with different initial porosities at different temperatures and pressures, different leaching water composition and gas content, and different porosity geometries (i.e. porous medium versus fractured medium). From this study, we believe that the initial porosity of protoliths and volume changes due to their transformation into secondary minerals are key factors to explain the different alteration extents observed in field studies. We also discuss how precipitation and dissolution kinetics can influence the alteration time scales.

  6. Hydrothermal processes at Mount Rainier, Washington

    Energy Technology Data Exchange (ETDEWEB)

    Frank, D.G.

    1985-01-01

    Field studies and thermal-infrared mapping at Mount Rainier indicate areas of active hydrothermal alteration where excess surface heat flux is about 9 megawatts. Three representative settings include: (1) An extensive area (greater than 12,000 m/sup 2/) of heated ground and slightly acidic boiling-point fumaroles at 76-82/sup 0/C at East and West Craters on the volcano's summit; (2) A small area (less than 500 m/sup 2/) of heated ground and sub-boiling-point fumaroles at 55-60/sup 0/C on the upper flank at Disappointment Cleaver, and other probably similar areas at Willis Wall, Sunset Amphitheater, and the South Tahoma and Kautz headwalls; (3) Sulfate and carbon dioxide enriched thermal springs at 9-24/sup 0/C on the lower flank of the volcano in valley walls beside the Winthrop and Paradise Glaciers. In addition, chloride- and carbon dioxide-enriched thermal springs issue from thin sediments that overlie Tertiary rocks at, or somewhat beyond, the base of the volcanic edifice in valley bottoms of the Nisqually and Ohanapecosh Rivers where maximum spring temperatures are 19-25/sup 0/C, respectively, and where extensive travertine deposits have developed. The heat flow, distribution of thermal activity, and nature of alteration products indicate that a narrow, central hydrothermal system exists within Mount Rainier forming steam-heated snowmelt at the summit craters and localized leakage of steam-heated fluids within 2 kilometers of the summit. The lateral extent of the hydrothermal system is limited in that only sparse, neutral sulfate-enriched thermal water issues from the lower flank of the cone. Simulations of geochemical mass transfer suggest that the thermal springs may be derived from an acid sulfate-chloride parent fluid which has been neutralized by reaction with andesite and highly diluted with shallow ground water.

  7. Hydrothermal Liquefaction Treatment Preliminary Hazard Analysis Report

    Energy Technology Data Exchange (ETDEWEB)

    Lowry, Peter P.; Wagner, Katie A.

    2015-08-31

    A preliminary hazard assessment was completed during February 2015 to evaluate the conceptual design of the modular hydrothermal liquefaction treatment system. The hazard assessment was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. This analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public.

  8. Hydrothermal synthesis of bismuth germanium oxide

    Energy Technology Data Exchange (ETDEWEB)

    Boyle, Timothy J.

    2016-12-13

    A method for the hydrothermal synthesis of bismuth germanium oxide comprises dissolving a bismuth precursor (e.g., bismuth nitrate pentahydrate) and a germanium precursor (e.g., germanium dioxide) in water and heating the aqueous solution to an elevated reaction temperature for a length of time sufficient to produce the eulytite phase of bismuth germanium oxide (E-BGO) with high yield. The E-BGO produced can be used as a scintillator material. For example, the air stability and radioluminescence response suggest that the E-BGO can be employed for medical applications.

  9. Synthesis of hydroxy sodalite from coal fly ash using waste industrial brine solution.

    Science.gov (United States)

    Musyoka, Nicholas M; Petrik, Leslie F; Balfour, Gillian; Gitari, Wilson M; Hums, Eric

    2011-01-01

    The effect of using industrial waste brine solution instead of ultra pure water was investigated during the synthesis of zeolites using three South African coal fly ashes as Si feedstock. The high halide brine was obtained from the retentate effluent of a reverse osmosis mine water treatment plant. Synthesis conditions applied were; ageing of fly ash was at 47 ° C for 48 hours, and while the hydrothermal treatment temperature was set at 140 ° C for 48 hours. The use of brine as a solvent resulted in the formation of hydroxy sodalite zeolite although unconverted mullite and hematite from the fly ash feedstock was also found in the synthesis product.

  10. Modelling the coal chain

    Energy Technology Data Exchange (ETDEWEB)

    Gertenbach, J.-D.; Varendorff, R. von [Knowledge Based Engineering, Sandton (South Africa)

    1999-03-01

    Managing the supply chain in an integrated coal operation involves many operation and control options often too complex for the human mind to comprehend and react to. By integrating all the knowledge of a supply chain into an expert system, both off-line and on-line real time decisions are possible. Knowledge Based Engineering based in South Africa, has gained valuable experience in modelling such mining operations. The article discusses the methodologies that the company has implemented. KBE uses Gensym`s G2 Real Time Expert System as the foundation of the system and the knowledge base is developed modularly.

  11. Coal, oil and cancer

    Energy Technology Data Exchange (ETDEWEB)

    Steingraber, Sandra

    2011-09-15

    The author believes contaminants in our external environment play a significant role in causing cancer in humans and the cumulative impact of exposure to chemical carcinogens over a lifetime has also to be considered. An efficient method to prevent cancer is to restrict the presence of chemical carcinogens not only indoor, but also in outdoor, environments. Due to collective efforts to reduce tobacco use, lung cancer rates are falling in the USA. Most chemical carcinogens are derived from coal and petroleum, so finding substitutes for these two substances is the right way to proceed in cancer prevention efforts, the author states.

  12. COAL OF THE FUTURE (Supply Prospects for Thermal Coal by 2030-2050)

    OpenAIRE

    2007-01-01

    The report, produced by Messrs. Energy Edge Ltd. (the U.K.) for the JRC Institute for Energy, aims at making a techno-economic analysis of novel extraction technologies for coal and their potential contribution to the global coal supply. These novel extraction technologies include: advanced coal mapping techniques, improved underground coal mining, underground coal gasification and utilisation of coalmine methane gas.

  13. Coal resources, production, and quality in the Eastern kentucky coal field: Perspectives on the future of steam coal production

    Science.gov (United States)

    Hower, J.C.; Hiett, J.K.; Wild, G.D.; Eble, C.F.

    1994-01-01

    The Eastern Kentucky coal field, along with adjacent portions of Virginia and southern West Virginia, is part of the greatest production concentration of high-heating-value, low-sulfur coal in the United States, accounting for over 27% of the 1993 U.S. production of coal of all ranks. Eastern Kentucky's production is spread among many coal beds but is particularly concentrated in a limited number of highquality coals, notably the Pond Creek coal bed and its correlatives, and the Fire Clay coal bed and its correlatives. Both coals are relatively low ash and low sulfur through the areas of the heaviest concentration of mining activity. We discuss production trends, resources, and the quality of in-place and clean coal for those and other major coals in the region. ?? 1994 Oxford University Press.

  14. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Quarterly technical progress report, July--September 1992

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Gutterman, C. [Foster Wheeler Development Corp., Livingston, NJ (United States); Chander, S. [Pennsylvania State Univ., University Park, PA (United States)

    1992-12-31

    The experimental study of coal swelling ratios have been determined with a wide variety of solvents. Only marginal levels of coal swelling were observed for the hydrocarbon solvents, but high levels were found with solvents having heteroatom functionality. Blends were superior to pure solvents. The activity of various catalyst precursors for pyrene hydrogenation and coal conversion was measured. Higher coal conversions were observed for the S0{sub 2}-treated coal than the raw coal, regardless of catalyst type. Coal conversions were highest for Molyvan-L, molybdenum naphthenate, and nickel octoate, respectively. Bottoms processing consists of a combination of the ASCOT process coupling solvent deasphalting with delayed coking. Initial results indicate that a blend of butane and pentane used near the critical temperature of butane is the best solvent blend for producing a yield/temperature relationship of proper sensitivity and yet retaining an asphalt phase of reasonable viscosity. The literature concerning coal swelling, both alone and in combination with coal liquefaction, and the use of dispersed or unsupported catalysts in coal liquefaction has been updated.

  15. Effect of heat treatment changes on swelling treatment of coal; Sekitan no bojun shori sayo ni oyobosu netsushori henka no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Satsuka, T.; Mashimo, K.; Wainai, T. [Nihon University, Tokyo (Japan). College of Science and Technology

    1996-10-28

    Discussions were given on effects of heat treatment at relatively low temperatures as a pretreatment for coal liquefaction on coal swelling and hydrogenolysis reaction. Taiheiyo coal was heated to 200{degree}C for one hour as a pretreatment. The attempted heating methods consisted of four steps of rapid heating (6.7{degree}C/min)quenching (20{degree}C/min), rapid heating/natural cooling (0.7{degree}C/min), heating (1.0{degree}C/min)/quenching, and heating/natural cooling. The swelling treatment was composed of adding methanol benzene into heat treated coal, and leaving it at room temperature for 24 hours. The hydrogenolysis was carried out by using a tetralin solvent and at an initial hydrogen pressure of 20 kg/cm{sup 2} and a temperature of 350{degree}C and for a time of one hour. Hydrogenolysis conversion in the heat treated coal was found lower than that of the original coal because of generation of liquefaction inactive components due to thermal polymerization. When the heat treated coal is swollen by using the solvent, gas yield from the hydrogenolysis reaction decreased due to gas suppression effect, and the conversion was lower than that of the original coal. Heat treatment suggests densification of the coal structure. Swollen coal shows no conspicuous difference in the heat treatment methods against the hydrogenolysis due to the swelling effect. 3 refs., 5 figs., 1 tab.

  16. Coal surface control for advanced fine coal flotation

    Energy Technology Data Exchange (ETDEWEB)

    Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Harris, G.; Sotillo, F.; Diao, J. (California Univ., Berkeley, CA (USA)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (USA)); Hu, Weibai; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (USA)); Choudhry, V.; Sehgal, R.; Ghosh, A. (Praxis Engineers, Inc., Milpitas, CA (USA))

    1990-08-15

    The primary objective of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from six major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Work this quarter concentrated on the following: washability studies, which included particle size distribution of the washability samples, and chemical analysis of washability test samples; characterization studies of induction time measurements, correlation between yield, combustible-material recovery (CMR), and heating-value recovery (HVR), and QA/QC for standard flotation tests and coal analyses; surface modification and control including testing of surface-modifying reagents, restoration of hydrophobicity to lab-oxidized coals, pH effects on coal flotation, and depression of pyritic sulfur in which pyrite depression with calcium cyanide and pyrite depression with xanthated reagents was investigated; flotation optimization and circuitry included staged reagent addition, cleaning and scavenging, and scavenging and middling recycling. Weathering studies are also discussed. 19 figs., 28 tabs.

  17. Characterization of coal water slurry prepared for PRB coal

    Institute of Scientific and Technical Information of China (English)

    Fei Yi; Akshay Gopan; Richard L. Axelbaum

    2014-01-01

    Powder River Basin (PRB) coal, which accounts for over 40% of the coal consumed for power generation in the United States, was investigated for preparation of coal water slurry ( CWS). The static stability and rheology of the CWS were characterized as a function of loading. The coal loading was varied from 30% to 50% and both ionic ( sodium polystyrene sulphonate (PSS)) and nonionic (Triton X-100) surfactants were employed as additives. The addition of PSS to PRB slurries was found to yield poor static stability. On the other hand, Triton X-100 was found to be an effective surfactant, reducing the sedimentation by more than 50% compared to the one without surfactant in 45% CWS. Adding Triton X-100 reduces the viscosity of the CWS for coal loadings of 30% and 40% . Although the viscosities for coal loading of 42. 5% and 45% are higher when Triton X-100 is added, the static stability is significantly better than for samples without surfactant. The highest coal loading for PRB slurry with acceptable viscosity for pumping is 42. 5% .

  18. Formation and retention of methane in coal

    Energy Technology Data Exchange (ETDEWEB)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  19. STUDY ON CLASSIFICATION SYSTEM FOR CHINESE COAL

    Institute of Scientific and Technical Information of China (English)

    陈鹏

    1998-01-01

    An integrated coal classification system-technical/commercial and scientific/geneticclassification in China is discussed in this paper. This system shall enable producers, sellers andpurchasers to communicate unambiguously with regard to the quality of coal complying with therequirements of the respective application. The determination of perfect coal classification systemis an important measure for rational utilization of coal resources.

  20. Oxy Coal Combustion at the US EPA

    Science.gov (United States)

    Oxygen enriched coal (oxy-coal) combustion is a developing, and potentially a strategically key technology intended to accommodate direct CO2 recovery and sequestration. Oxy-coal combustion is also intended for retrofit application to existing power plants. During oxy-coal comb...

  1. Hydrothermal Processes in the Archean - New Insights from Imaging Spectroscopy

    NARCIS (Netherlands)

    Ruitenbeek, F.J.A. van

    2007-01-01

    The aim of this research was to gain new insights in fossil hydrothermal systems using airborne imaging spectroscopy. Fossil submarine hydrothermal systems in Archean greenstone belts and other geologic terranes are important because of their relationship with volcanic massive sulfide (VMS) mineral

  2. Hydrothermal stability of microporous silica and niobia-silica membranes

    NARCIS (Netherlands)

    Boffa, V.; Blank, David H.A.; ten Elshof, Johan E.

    2008-01-01

    The hydrothermal stability of microporous niobia–silica membranes was investigated and compared with silica membranes. The membranes were exposed to hydrothermal conditions at 150 and 200 °C for 70 h. The change of pore structure before and after exposure to steam was probed by single-gas permeation

  3. Levulinic acid from orange peel waste by hydrothermal carbonization (HTC)

    NARCIS (Netherlands)

    Puccini, Monica; Licursi, Domenico; Stefanelli, Eleonora; Vitolo, Sandra; Galletti, Anna Maria Raspolli; Heeres, Hero Jan

    2016-01-01

    With the awareness of the need for optimal and sustainable use of natural resources, hydrothermal treatment of biomass and biomass waste for energy and resource recovery has received increasing attention. The hydrothermal carbonization (HTC) of a biomass is achieved using water as the reaction

  4. Hydrothermal Processes in the Archean - New Insights from Imaging Spectroscopy

    NARCIS (Netherlands)

    Ruitenbeek, F.J.A. van

    2007-01-01

    The aim of this research was to gain new insights in fossil hydrothermal systems using airborne imaging spectroscopy. Fossil submarine hydrothermal systems in Archean greenstone belts and other geologic terranes are important because of their relationship with volcanic massive sulfide (VMS) mineral

  5. PRACTICAL AND PREDICTIVE MODELLING OF ORE DEPOSITS IN HYDROTHERMAL SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    ZHAO Chong-bin; B.E.Hobbs; H.B.Muhlhaus; A.Ord

    2001-01-01

    @@ Over the past five years,we have been making efforts to develop a practical and predictive tool to explore for giant ore deposits in hydrothermal systems.Towards this goal,a significant progress has been made towards a better understanding of the basic physical and chemical processes behind ore body formation and mineralization in hydrothermal systems.

  6. PRACTICAL AND PREDICTIVE MODELLING OF ORE DEPOSITS IN HYDROTHERMAL SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    ZHAO; Chong-bin; B.E.Hobbs; H.B.Muhlhaus; A.Ord

    2001-01-01

    Over the past five years,we have been making efforts to develop a practical and predictive tool to explore for giant ore deposits in hydrothermal systems.Towards this goal,a significant progress has been made towards a better understanding of the basic physical and chemical processes behind ore body formation and mineralization in hydrothermal systems.……

  7. Characterization of Coal Porosity for Naturally Tectonically Stressed Coals in Huaibei Coal Field, China

    Directory of Open Access Journals (Sweden)

    Xiaoshi Li

    2014-01-01

    Full Text Available The enrichment of coalbed methane (CBM and the outburst of gas in a coal mine are closely related to the nanopore structure of coal. The evolutionary characteristics of 12 coal nanopore structures under different natural deformational mechanisms (brittle and ductile deformation are studied using a scanning electron microscope (SEM and low-temperature nitrogen adsorption. The results indicate that there are mainly submicropores (2~5 nm and supermicropores (4 m2/g, with pore sizes <5 nm in ductile deformed coal. The nanopore structure (<100 nm and its distribution could be affected by macromolecular structure in two ways. Interconversion will occur among the different size nanopores especially in ductile deformed coal.

  8. Bioprocessing of lignite coals using reductive microorganisms

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, D.L.

    1992-03-29

    In order to convert lignite coals into liquid fuels, gases or chemical feedstock, the macromolecular structure of the coal must be broken down into low molecular weight fractions prior to further modification. Our research focused on this aspect of coal bioprocessing. We isolated, characterized and studied the lignite coal-depolymerizing organisms Streptomyces viridosporus T7A, Pseudomonas sp. DLC-62, unidentified bacterial strain DLC-BB2 and Gram-positive Bacillus megaterium strain DLC-21. In this research we showed that these bacteria are able to solubilize and depolymerize lignite coals using a combination of biological mechanisms including the excretion of coal solublizing basic chemical metabolites and extracellular coal depolymerizing enzymes.

  9. Study on combustion characteristics of blended coals

    Energy Technology Data Exchange (ETDEWEB)

    Li Yonghua; Wang Chunbo; Chen Hongwei [North China Electric Power University, Baoding (China)

    2007-02-15

    Power plants in China have to burn blended coal instead of one specific coal for a variety of reasons. So it is of great necessity to investigate the combustion of blended coals. Using a test rig with a capacity of 640 MJ/h with an absolute milling system and flue gas online analysis system, characteristics such as burnout, slag, and pollution of some blended coals were investigated. The ratio of coke and slag as a method of distinguishing coal slagging characteristic was introduced. The results show that the blending of coal has some effect on NOx but there is no obvious rule. SOx emission can be reduced by blending low sulfur coal.

  10. Hydrothermal synthesis of highly nitrogen-doped few-layer graphene via solid–gas reaction

    Energy Technology Data Exchange (ETDEWEB)

    Liang, Xianqing, E-mail: lxq@gxu.edu.cn [College of Physics Science and Technology, Guangxi University, Nanning 530004 (China); Zhong, Jun [Jiangsu Key Laboratory for Carbon-Based Functional Material and Devices, Institute of Functional Nano and Soft Materials Laboratory (FUNSOM), Soochow University, Suzhou 215123 (China); Shi, Yalin; Guo, Jin; Huang, Guolong [College of Physics Science and Technology, Guangxi University, Nanning 530004 (China); Hong, Caihao; Zhao, Yidong [Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)

    2015-01-15

    Highlights: • A novel approach to synthesis of N-doped few-layer graphene has been developed. • The high doping levels of N in products are achieved. • XPS and XANES results reveal a thermal transformation of N bonding configurations. • The developed method is cost-effective and eco-friendly. - Abstract: Nitrogen-doped (N-doped) graphene sheets with high doping concentration were facilely synthesized through solid–gas reaction of graphene oxide (GO) with ammonia vapor in a self-designed hydrothermal system. The morphology, surface chemistry and electronic structure of N-doped graphene sheets were investigated by TEM, AFM, XRD, XPS, XANES and Raman characterizations. Upon hydrothermal treatment, up to 13.22 at% of nitrogen could be introduced into the crumpled few-layer graphene sheets. Both XPS and XANES analysis reveal that the reaction between oxygen functional groups in GO and ammonia vapor produces amide and amine species in hydrothermally treated GO (HTGO). Subsequent thermal annealing of the resultant HTGO introduces a gradual transformation of nitrogen bonding configurations in graphene sheets from amine N to pyridinic and graphitic N with the increase of annealing temperature. This study provides a simple but cost-effective and eco-friendly method to prepare N-doped graphene materials in large-scale for potential applications.

  11. Hydration Characteristics and Immobilization of Cr (VI) in Slag Cement-CKD Pastes under Hydrothermal Treatment

    Institute of Scientific and Technical Information of China (English)

    M R Shatat; Gomaa A M Ali; M A Tantawy

    2015-01-01

    The effect of hydrothermal curing regimes on the hydration characteristics of slag cement containing different ratios of cement kiln dust has been studied. The samples for this study were combination of slag cement and cement kiln dust (5%-25%) without and with immobilization of 5% Cr (VI) by mass. Pastes were hydrothermally treated at 180℃ for different periods (2-24 h) in well closed stainless steel capsule. The hydration characteristics of these pastes were studied by measuring the compressive strength, bulk density, total porosity and combined water content. The findings were further supported by XRD and SEM analysis. The results indicated that the hydration characteristics of slag cement paste containing cement kiln dust 10% by mass were enhanced, especially at later ages (24 h) of hydration. That is due to the hydrothermal curing regimes of immobilized pastes accelerating hydration reactions and precipitation of CaCrO4, indicating that Cr (VI) can be solidiifed in the cement paste. This precipitation leads to pore formation in hydrated slag cement pastes.

  12. Production of monosaccharides from napier grass by hydrothermal process with phosphoric acid.

    Science.gov (United States)

    Takata, Eri; Tsutsumi, Ken; Tsutsumi, Yuji; Tabata, Kenji

    2013-09-01

    The production of monosaccharides from napier grass was investigated in the presence of acid catalysts using the hydrothermal process. When the napier grass was treated with 3 wt.% phosphoric acid at 160°C for 15min, the xylose yield reached 10.3 wt.%, corresponding to 72.0% of the xylan in it, whereas glucose was hardly obtained. A combined process was then conducted using an 85 wt.% phosphoric acid treatment at 60 °C for 1h followed by a hydrothermal treatment with 3 wt.% phosphoric acid. In the initial treatment with concentrated phosphoric acid the most of xylan was hydrolyzed to xylose, and the crystalline cellulose was converted to its amorphous form. The hydrolysis of cellulose to glucose was significantly enhanced during the following hydrothermal process with 3 wt.% phosphoric acid at 200 °C for 8 min. Consequently, 77.2% yield of xylose and 50.0% yield of glucose were obtained from the combined process.

  13. Tricky Treats

    Centers for Disease Control (CDC) Podcasts

    2008-08-04

    The Eagle Books are a series of four books that are brought to life by wise animal characters - Mr. Eagle, Miss Rabbit, and Coyote - who engage Rain That Dances and his young friends in the joy of physical activity, eating healthy foods, and learning from their elders about health and diabetes prevention. Tricky Treats shows children the difference between healthy snacks and sweet treats.  Created: 8/4/2008 by National Center for Chronic Disease Prevention and Health Promotion (NCCDPHP).   Date Released: 8/5/2008.

  14. Coal surface control for advanced fine coal flotation

    Energy Technology Data Exchange (ETDEWEB)

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. (California Univ., Berkeley, CA (United States)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (United States)); Hu, W.; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (United States)); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. (Praxis Engineers, Inc., Milpitas, CA (United States))

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal's emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  15. Hydrothermal Liquefaction of Wastewater Treatment Plant Solids

    Energy Technology Data Exchange (ETDEWEB)

    Billing, Justin M.

    2016-10-16

    Feedstock cost is the greatest barrier to the commercial production of biofuels. The merits of any thermochemical or biological conversion process are constrained by their applicability to the lowest cost feedstocks. At PNNL, a recent resource assessment of wet waste feedstocks led to the identification of waste water treatment plant (WWTP) solids as a cost-negative source of biomass. WWTP solids disposal is a growing environmental concern [1, 2] and can account for up to half of WWTP operating costs. The high moisture content is well-suited for hydrothermal liquefaction (HTL), avoiding the costs and parasitic energy losses associated with drying the feedstock for incineration. The yield and quality of biocrude and upgraded biocrude from WWTP solids is comparable to that obtained from algae feedstocks but the feedstock cost is $500-1200 less per dry ton. A collaborative project was initiated and directed by the Water Environment & Reuse Foundation (WERF) and included feedstock identification, dewatering, shipping to PNNL, conversion to biocrude by HTL, and catalytic hydrothermal gasification of the aqueous byproduct. Additional testing at PNNL included biocrude upgrading by catalytic hydrotreatment, characterization of the hydrotreated product, and a preliminary techno-economic analysis (TEA) based on empirical results. This short article will cover HTL conversion and biocrude upgrading. The WERF project report with complete HTL results is now available through the WERF website [3]. The preliminary TEA is available as a PNNL report [4].

  16. Nutritional strategies of the hydrothermal ecosystem bivalves

    Science.gov (United States)

    Le Pennec, Marcel; Donval, Anne; Herry, Angèle

    Studies of deep-sea hydrothermal bivalves have revealed that the species, which are strictly dependent upon the interstitial fluid emissions, derive their food indirectly via symbiotic relationships with chemosynthetic bacteria present in their gill tissues. As the gill plays the main trophic role, structural and ultrastructural modifications occur in the digestive tract. Scanning and transmission electron microscope studies reveal that the digestive system of species belonging to the genera Calyptogena, Bathymodiolus and Bathypecten have anatomical differences. In Calyptogena, the reduction of several parts of the digestive tract and the stomach content which is either empty or full, according to the various species examined indicate that the digestive system is hardly if at all functional. In Bathymodiolus, the labial palps are well developed, the stomach is always full with particles and the two cellular types, digestive and secretory, are present in the digestive gland. All these characteristics indicate that the digestive system is functional. In Bathypecten, the digestive tract is well developed and it seems that it plays the main trophic role. We conclude that the nutritional strategies of the hydrothermal vents bivalves are quite varied. They range from a normal trophic process, through a mixotrophic diet, to one based purely on chemoautotrophic bacteria. The strategy of each species is adapted to and influences its distribution.

  17. Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction. Final technical report, Volume 1 - effects of solvents, catalysts and temperature conditions on conversion and structural changes of low-rank coals

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Lili [Pennsylvania State Univ., University Park, PA (United States); Schobert, Harold H. [Pennsylvania State Univ., University Park, PA (United States); Song, Chunshan [Pennsylvania State Univ., University Park, PA (United States)

    1998-01-01

    The main objectives of this project were to study the effects of low-temperature pretreatments on coal structure and their impacts on subsequent liquefaction. The effects of pretreatment temperatures, catalyst type, coal rank, and influence of solvent were examined. Specific objectives were to identify the basic changes in coal structure induced by catalytic and thermal pretreatments, and to determine the reactivity of the catalytically and thermally treated coals for liquefaction. In the original project management plan it was indicated that six coals would be used for the study. These were to include two each of bituminous, subbituminous, and lignite rank. For convenience in executing the experimental work, two parallel efforts were conducted. The first involved the two lignites and one subbituminous coal; and the second, the two bituminous coals and the remaining subbituminous coal. This Volume presents the results of the first portion of the work, studies on two lignites and one subbituminous coal. The remaining work accomplished under this project will be described and discussed in Volume 2 of this report. The objective of this portion of the project was to determine and compare the effects of solvents, catalysts and reaction conditions on coal liquefaction. Specifically, the improvements of reaction conversion, product distribution, as well as the structural changes in the coals and coal-derived products were examined. This study targeted at promoting hydrogenation of the coal-derived radicals, generated during thermal cleavage of chemical bonds, by using a good hydrogen donor-solvent and an effective catalyst. Attempts were also made in efforts to match the formation and hydrogenation of the free radicals and thus to prevent retrogressive reaction.

  18. Clean Coal Initiatives in India

    Directory of Open Access Journals (Sweden)

    Sribas Goswami

    2014-08-01

    Full Text Available Availability of, and access to, coal is a crucial element of modern economies and it helps pave the way for human development. Accordingly, the thermal power sector and steel industries have been given a high priority in the national planning processes in India and a concerted focus on enhancing these sectors have resulted in significant gain in generation and availability of electricity and steel in the years since independence. To meet the need of huge demand of power coal is excavated. The process of excavation to the use of coal is potential enough to degrade the environment. Coal Mining is a development activity, which is bound to damage the natural ecosystem by all its activities directly and ancillary, starting from land acquisition to coal beneficiation and use of the products. Huge areas in the Raniganj and Jharia coal field in India have become derelict due to abandoned and active opencast and underground mines. The study is pursued to illustrate the facts which show the urgent need to clean coal mining in India.

  19. Appalachian clean coal technology consortium

    Energy Technology Data Exchange (ETDEWEB)

    Kutz, K.; Yoon, Roe-Hoan [Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States)

    1995-11-01

    The Appalachian Clean Coal Technology Consortium (ACCTC) has been established to help U.S. coal producers, particularly those in the Appalachian region, increase the production of lower-sulfur coal. The cooperative research conducted as part of the consortium activities will help utilities meet the emissions standards established by the 1990 Clean Air Act Amendments, enhance the competitiveness of U.S. coals in the world market, create jobs in economically-depressed coal producing regions, and reduce U.S. dependence on foreign energy supplies. The research activities will be conducted in cooperation with coal companies, equipment manufacturers, and A&E firms working in the Appalachian coal fields. This approach is consistent with President Clinton`s initiative in establishing Regional Technology Alliances to meet regional needs through technology development in cooperation with industry. The consortium activities are complementary to the High-Efficiency Preparation program of the Pittsburgh Energy Technology Center, but are broader in scope as they are inclusive of technology developments for both near-term and long-term applications, technology transfer, and training a highly-skilled work force.

  20. Gaseous phase coal surface modification

    Energy Technology Data Exchange (ETDEWEB)

    Okoh, J.M.; Pinion, J.; Thiensatit, S.

    1992-05-07

    In this report, we present an improved, feasible and potentially cost effective method of cleaning and beneficiating ultrafine coal. Increased mechanization of mining methods and the need towards depyritization, and demineralization have led to an increase in the quantity of coal fines generated in recent times. For example, the amount of {minus}100 mesh coal occurring in coal preparation plant feeds now typically varies from 5 to 25% of the total feed. Environmental constraints coupled with the greatly increased cost of coal have made it increasingly important to recover more of these fines. Our method chemically modifies the surface of such coals by a series of gaseous phase treatments employing Friedel-Crafts reactions. By using olefins (ethene, propene and butene) and hydrogen chloride catalyst at elevated temperature, the surface hydrophobicity of coal is enhanced. This increased hydrophobicity is manifest in surface phenomena which reflect conditions at the solid/liquid interphase (zeta potential) and those which reflect conditions at the solid/liquid/gas interphases (contact angle, wettability and floatability).