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Sample records for hydrothermal system prior

  1. Early Archaean hydrothermal systems

    Science.gov (United States)

    de Vries, S. T.; Nijman, W.

    2003-04-01

    Although many people have written about hydrothermal systems in the early Earth, little real evidence is available. New data from the Barberton greenstone belt (South Africa) and greenstone belts of the East Pilbara (Western Australia), provide proof of the existence and nature of hydrothermal systems in the Early Archaean (around 3.4 Ga). Detailed field relationships between vein systems, host rock and overlying sediments are combined with data from fluid inclusions studies on quartz fills in the sediments. An intimate relationship between chert veins and the overlying sediments has been established (the veins are syn-sedimentary). The salinity and temperature of the fluids in the inclusions shows that these are of hydrothermal origin. Similar types of hydrothermal systems, of approximately the same age, have been found at different locations; in the Barberton greenstone belt and at various locations in the East Pilbara. The setting of these hydrothermal systems is not always identical however. Although a felsic substratum is more common, in the North Pole area (Pilbara) the hydrothermal systems rise from a basaltic substratum. In the Barberton greenstone belt, the systems are closely related to shallow intrusive (felsic) bodies. The study of these ancient hydrothermal systems forms an important framework for studies of early life on Earth. This study forms part of an international project on Earth's Earliest Sedimentary Basins, supported by the Foundation Dr. Schürmannfonds.

  2. The Lassen hydrothermal system

    Science.gov (United States)

    Ingebritsen, Steven E.; Bergfeld, Deborah; Clor, Laura; Evans, William C.

    2016-01-01

    The active Lassen hydrothermal system includes a central vapor-dominated zone or zones beneath the Lassen highlands underlain by ~240 °C high-chloride waters that discharge at lower elevations. It is the best-exposed and largest hydrothermal system in the Cascade Range, discharging 41 ± 10 kg/s of steam (~115 MW) and 23 ± 2 kg/s of high-chloride waters (~27 MW). The Lassen system accounts for a full 1/3 of the total high-temperature hydrothermal heat discharge in the U.S. Cascades (140/400 MW). Hydrothermal heat discharge of ~140 MW can be supported by crystallization and cooling of silicic magma at a rate of ~2400 km3/Ma, and the ongoing rates of heat and magmatic CO2 discharge are broadly consistent with a petrologic model for basalt-driven magmatic evolution. The clustering of observed seismicity at ~4–5 km depth may define zones of thermal cracking where the hydrothermal system mines heat from near-plastic rock. If so, the combined areal extent of the primary heat-transfer zones is ~5 km2, the average conductive heat flux over that area is >25 W/m2, and the conductive-boundary length summit of Lassen Peak. However, there is a rich record of intermittent hydrothermal measurement over the past several decades and more-frequent measurement 2009–present. These data reveal sensitivity to climate and weather conditions, seasonal variability that owes to interaction with the shallow hydrologic system, and a transient 1.5- to twofold increase in high-chloride discharge in response to an earthquake swarm in mid-November 2014.

  3. Hydrothermal processes above the Yellowstone magma chamber: Large hydrothermal systems and large hydrothermal explosions

    Science.gov (United States)

    Morgan, L.A.; Shanks, W.C. Pat; Pierce, K.L.

    2009-01-01

    and vein-fi lling; and (5) areal dimensions of many large hydrothermal explosion craters in Yellowstone are similar to those of its active geyser basins and thermal areas. For Yellowstone, our knowledge of hydrothermal craters and ejecta is generally limited to after the Yellowstone Plateau emerged from beneath a late Pleistocene icecap that was roughly a kilometer thick. Large hydrothermal explosions may have occurred earlier as indicated by multiple episodes of cementation and brecciation commonly observed in hydrothermal ejecta clasts. Critical components for large, explosive hydrothermal systems include a watersaturated system at or near boiling temperatures and an interconnected system of well-developed joints and fractures along which hydrothermal fluids flow. Active deformation of the Yellowstone caldera, active faulting and moderate local seismicity, high heat flow, rapid changes in climate, and regional stresses are factors that have strong infl uences on the type of hydrothermal system developed. Ascending hydrothermal fluids flow along fractures that have developed in response to active caldera deformation and along edges of low-permeability rhyolitic lava flows. Alteration of the area affected, self-sealing leading to development of a caprock for the hydrothermal system, and dissolution of silica-rich rocks are additional factors that may constrain the distribution and development of hydrothermal fields. A partial lowpermeability layer that acts as a cap to the hydrothermal system may produce some over-pressurization, thought to be small in most systems. Any abrupt drop in pressure initiates steam fl ashing and is rapidly transmitted through interconnected fractures that result in a series of multiple large-scale explosions contributing to the excavation of a larger explosion crater. Similarities between the size and dimensions of large hydrothermal explosion craters and thermal fields in Yellowstone may indicate that catastrophic events which result in l

  4. Hydrothermal system of Long Valley caldera, California

    Energy Technology Data Exchange (ETDEWEB)

    Sorey, M.L.; Lewis, R.E.; Olmsted, F.H.

    1978-01-01

    The geologic and hydrologic setting of the hydrothermal system are described. The geochemical and thermal characteristics of the system are presented. A mathematical model of the Long Valley caldera is analyzed. (MHR)

  5. Mild hydrothermal conditioning prior to torrefaction and slow pyrolysis of low-value biomass.

    Science.gov (United States)

    Van Poucke, R; Nachenius, R W; Agbo, K E; Hensgen, F; Bühle, L; Wachendorf, M; Ok, Y S; Tack, F M G; Prins, W; Ronsse, F; Meers, E

    2016-10-01

    The aim of this research was to establish whether hydrothermal conditioning and subsequent thermochemical processing via batch torrefaction or slow pyrolysis may improve the fuel quality of grass residues. A comparison in terms of fuel quality was made of the direct thermochemical processing of the feedstock versus hydrothermal conditioning as a pretreatment prior to thermochemical processing. Hydrothermal conditioning reduced ash content, and particularly nitrogen, potassium and chlorine contents in the biomass. The removal of volatile organic matter associated with thermochemical processes can increase the HHV to levels of volatile bituminous coal. However, slow pyrolysis only increased the HHV of biomass provided a low ash content (biomass to a higher quality fuel. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Dynamics of the Yellowstone hydrothermal system

    Science.gov (United States)

    Hurwitz, Shaul; Lowenstern, Jacob B.

    2014-01-01

    The Yellowstone Plateau Volcanic Field is characterized by extensive seismicity, episodes of uplift and subsidence, and a hydrothermal system that comprises more than 10,000 thermal features, including geysers, fumaroles, mud pots, thermal springs, and hydrothermal explosion craters. The diverse chemical and isotopic compositions of waters and gases derive from mantle, crustal, and meteoric sources and extensive water-gas-rock interaction at variable pressures and temperatures. The thermal features are host to all domains of life that utilize diverse inorganic sources of energy for metabolism. The unique and exceptional features of the hydrothermal system have attracted numerous researchers to Yellowstone beginning with the Washburn and Hayden expeditions in the 1870s. Since a seminal review published a quarter of a century ago, research in many fields has greatly advanced our understanding of the many coupled processes operating in and on the hydrothermal system. Specific advances include more refined geophysical images of the magmatic system, better constraints on the time scale of magmatic processes, characterization of fluid sources and water-rock interactions, quantitative estimates of heat and magmatic volatile fluxes, discovering and quantifying the role of thermophile microorganisms in the geochemical cycle, defining the chronology of hydrothermal explosions and their relation to glacial cycles, defining possible links between hydrothermal activity, deformation, and seismicity; quantifying geyser dynamics; and the discovery of extensive hydrothermal activity in Yellowstone Lake. Discussion of these many advances forms the basis of this review.

  7. Chemical environments of submarine hydrothermal systems

    Science.gov (United States)

    Shock, Everett L.

    1992-01-01

    Perhaps because black-smoker chimneys make tremendous subjects for magazine covers, the proposal that submarine hydrothermal systems were involved in the origin of life has caused many investigators to focus on the eye-catching hydrothermal vents. In much the same way that tourists rush to watch the spectacular eruptions of Old Faithful geyser with little regard for the hydrology of the Yellowstone basin, attention is focused on the spectacular, high-temperature hydrothermal vents to the near exclusion of the enormous underlying hydrothermal systems. Nevertheless, the magnitude and complexity of geologic structures, heat flow, and hydrologic parameters which characterize the geyser basins at Yellowstone also characterize submarine hydrothermal systems. However, in the submarine systems the scale can be considerably more vast. Like Old Faithful, submarine hydrothermal vents have a spectacular quality, but they are only one fascinating aspect of enormous geologic systems operating at seafloor spreading centers throughout all of the ocean basins. A critical study of the possible role of hydrothermal processes in the origin of life should include the full spectrum of probable environments. The goals of this chapter are to synthesize diverse information about the inorganic geochemistry of submarine hydrothermal systems, assemble a description of the fundamental physical and chemical attributes of these systems, and consider the implications of high-temperature, fluid-driven processes for organic synthesis. Information about submarine hydrothermal systems comes from many directions. Measurements made directly on venting fluids provide useful, but remarkably limited, clues about processes operating at depth. The oceanic crust has been drilled to approximately 2.0 km depth providing many other pieces of information, but drilling technology has not allowed the bore holes and core samples to reach the maximum depths to which aqueous fluids circulate in oceanic crust. Such

  8. Peptide synthesis in early earth hydrothermal systems

    Science.gov (United States)

    Lemke, K.H.; Rosenbauer, R.J.; Bird, D.K.

    2009-01-01

    We report here results from experiments and thermodynamic calculations that demonstrate a rapid, temperature-enhanced synthesis of oligopeptides from the condensation of aqueous glycine. Experiments were conducted in custom-made hydrothermal reactors, and organic compounds were characterized with ultraviolet-visible procedures. A comparison of peptide yields at 260??C with those obtained at more moderate temperatures (160??C) gives evidence of a significant (13 kJ ?? mol-1) exergonic shift. In contrast to previous hydrothermal studies, we demonstrate that peptide synthesis is favored in hydrothermal fluids and that rates of peptide hydrolysis are controlled by the stability of the parent amino acid, with a critical dependence on reactor surface composition. From our study, we predict that rapid recycling of product peptides from cool into near-supercritical fluids in mid-ocean ridge hydrothermal systems will enhance peptide chain elongation. It is anticipated that the abundant hydrothermal systems on early Earth could have provided a substantial source of biomolecules required for the origin of life. Astrobiology 9, 141-146. ?? 2009 Mary Ann Liebert, Inc. 2009.

  9. Numerical simulation of magmatic hydrothermal systems

    Science.gov (United States)

    Ingebritsen, S.E.; Geiger, S.; Hurwitz, S.; Driesner, T.

    2010-01-01

    The dynamic behavior of magmatic hydrothermal systems entails coupled and nonlinear multiphase flow, heat and solute transport, and deformation in highly heterogeneous media. Thus, quantitative analysis of these systems depends mainly on numerical solution of coupled partial differential equations and complementary equations of state (EOS). The past 2 decades have seen steady growth of computational power and the development of numerical models that have eliminated or minimized the need for various simplifying assumptions. Considerable heuristic insight has been gained from process-oriented numerical modeling. Recent modeling efforts employing relatively complete EOS and accurate transport calculations have revealed dynamic behavior that was damped by linearized, less accurate models, including fluid property control of hydrothermal plume temperatures and three-dimensional geometries. Other recent modeling results have further elucidated the controlling role of permeability structure and revealed the potential for significant hydrothermally driven deformation. Key areas for future reSearch include incorporation of accurate EOS for the complete H2O-NaCl-CO2 system, more realistic treatment of material heterogeneity in space and time, realistic description of large-scale relative permeability behavior, and intercode benchmarking comparisons. Copyright 2010 by the American Geophysical Union.

  10. Stable light isotope biogeochemistry of hydrothermal systems.

    Science.gov (United States)

    Des Marais, D J

    1996-01-01

    The stable isotopic composition of the elements O, H, S and C in minerals and other chemical species can indicate the existence, extent, conditions and the processes (including biological activity) of hydrothermal systems. Hydrothermal alteration of the 18O/16O and D/H values of minerals can be used to detect fossil systems and delineate their areal extent. Water-rock interactions create isotopic signatures which indicate fluid composition, temperature, water-rock ratios, etc. The 18O/16O values of silica and carbonate deposits tend to increase with declining temperature and thus help to map thermal gradients. Measurements of D/H values can help to decipher the origin(s) of hydrothermal fluids. The 34S/32S and 13C/12C values of fluids and minerals reflect the origin of the S and C as well as oxygen fugacities and key redox processes. For example, a wide range of 34S/32S values which are consistent with equilibration below 100 degrees C between sulfide and sulfate can be attributed to sulfur metabolizing bacteria. Depending on its magnitude, the difference in the 13C/12C value of CO2 and carbonates versus organic carbon might be attributed either to equilibrium at hydrothermal temperatures or, if the difference exceeds 1% (10/1000), to organic biosynthesis. Along the thermal gradients of thermal spring outflows, the 13C/12C value of carbonates and 13C-depleted microbial organic carbon increases, principally due to the outgassing of relatively 13C-depleted CO2.

  11. Entropy Production in Convective Hydrothermal Systems

    Science.gov (United States)

    Boersing, Nele; Wellmann, Florian; Niederau, Jan

    2016-04-01

    Exploring hydrothermal reservoirs requires reliable estimates of subsurface temperatures to delineate favorable locations of boreholes. It is therefore of fundamental and practical importance to understand the thermodynamic behavior of the system in order to predict its performance with numerical studies. To this end, the thermodynamic measure of entropy production is considered as a useful abstraction tool to characterize the convective state of a system since it accounts for dissipative heat processes and gives insight into the system's average behavior in a statistical sense. Solving the underlying conservation principles of a convective hydrothermal system is sensitive to initial conditions and boundary conditions which in turn are prone to uncertain knowledge in subsurface parameters. There exist multiple numerical solutions to the mathematical description of a convective system and the prediction becomes even more challenging as the vigor of convection increases. Thus, the variety of possible modes contained in such highly non-linear problems needs to be quantified. A synthetic study is carried out to simulate fluid flow and heat transfer in a finite porous layer heated from below. Various two-dimensional models are created such that their corresponding Rayleigh numbers lie in a range from the sub-critical linear to the supercritical non-linear regime, that is purely conductive to convection-dominated systems. Entropy production is found to describe the transient evolution of convective processes fairly well and can be used to identify thermodynamic equilibrium. Additionally, varying the aspect ratio for each Rayleigh number shows that the variety of realized convection modes increases with both larger aspect ratio and higher Rayleigh number. This phenomenon is also reflected by an enlarged spread of entropy production for the realized modes. Consequently, the Rayleigh number can be correlated to the magnitude of entropy production. In cases of moderate

  12. Combined hydrothermal liquefaction and catalytic hydrothermal gasification system and process for conversion of biomass feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2017-09-12

    A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.

  13. Hydrothermal systems as environments for the emergence of life.

    Science.gov (United States)

    Shock, E L

    1996-01-01

    Analysis of the chemical disequilibrium provided by the mixing of hydrothermal fluids and seawater in present-day systems indicates that organic synthesis from CO2 or carbonic acid is thermodynamically favoured in the conditions in which hyperthermophilic microorganisms are known to live. These organisms lower the Gibbs free energy of the chemical mixture by synthesizing many of the components of their cells. Primary productivity is enormous in hydrothermal systems because it depends only on catalysis of thermodynamically favourable, exergonic reactions. It follows that hydrothermal systems may be the most favourable environments for life on Earth. This fact makes hydrothermal systems logical candidates for the location of the emergence of life, a speculation that is supported by genetic evidence that modern hyperthermophilic organisms are closer to a common ancestor than any other forms of life. The presence of hydrothermal systems on the early Earth would correspond to the presence of liquid water. Evidence that hydrothermal systems existed early in the history of Mars raises the possibility that life may have emerged on Mars as well. Redox reactions between water and rock establish the potential for organic synthesis in and around hydrothermal systems. Therefore, the single most important parameter for modelling the geochemical emergence of life on the early Earth or Mars is the composition of the rock which hosts the hydrothermal system.

  14. The hydrothermal system at Newberry Volcano, Oregon

    Science.gov (United States)

    Sammel, E.A.; Ingebritsen, S.E.; Mariner, R.H.

    1988-01-01

    Results of recent geological and geophysical studies at Newberry Volcano have been incorporated into conceptual and numerical models of a magma-based hydrothermal system. Numerical simulations begin with emplacement of a small magma body, the presumed source of silicic eruptions at Newberry that began about 10 000 BP, into a thermal regime representing 100 000 yr of cooling of a large underlying intrusion. Simulated flow patterns and thermal histories for three sets of hypothetical permeability values are compatible with data from four geothermal drill holes on the volcano. Meteoric recharge cools the caldera-fill deposits, but thermal water moving up a central conduit representing a permeable volcanic vent produces temperatures close to those observed in drill holes within the caldera. Meteoric recharge from the caldera moves down the flanks and creates a near-isothermal zone that extends several hundred meters below the water table, producing temperature profiles similar to those obserbed in drill holes on the flanks. The temperatures observed in drillholes on the flanks are not influenced by the postulated Holocene magma body. The elevated temperature gradients measured in the lower portions of these holes may be related to the cumulative effect of older intrusions. The models also indicate that meteoric recharge to the deep hyrothermal system probably originates within or near the caldera. Relatively low fluid velocities at depth suggest that at least a significant fraction of the thermal fluid may be very old. -Authors

  15. Fractionation of Boron Isotopes in Icelandic Hydrothermal Systems

    Energy Technology Data Exchange (ETDEWEB)

    Aggarwal, J.K.; Palmer, M.R.

    1995-01-01

    Boron isotope ratios have been determined in a variety of different geothermal waters from hydrothermal systems across Iceland. Isotope ratios from the high temperature meteoric water recharged systems reflect the isotope ratio of the host rocks without any apparent fractionation. Seawater recharged geothermal systems exhibit more positive {delta}{sup 11}B values than the meteoric water recharged geothermal systems. Water/rock ratios can be assessed from boron isotope ratios in the saline hydrothermal systems. Low temperature hydrothermal systems also exhibit more positive {delta}{sup 11}B than the high temperature systems, indicating fractionation of boron due to adsorption of the lighter isotope onto secondary minerals. Fractionation of boron in carbonate deposits may indicate the level of equilibrium attained within the systems.

  16. Molybdenum isotope behaviour in groundwaters and terrestrial hydrothermal systems, Iceland

    Science.gov (United States)

    Neely, Rebecca A.; Gislason, Sigurdur R.; Ólafsson, Magnus; McCoy-West, Alex J.; Pearce, Christopher R.; Burton, Kevin W.

    2018-03-01

    Molybdenum (Mo) isotopes have proved useful in the reconstruction of paleoredox conditions. Their application generally relies upon a simplified model of ocean inputs in which rivers dominate Mo fluxes to the oceans and hydrothermal fluids are considered to be a minor contribution. To date, however, little attention has been paid to the extent of Mo isotope variation of hydrothermal waters, or to the potential effect of direct groundwater discharge to the oceans. Here we present Mo isotope data for two Icelandic groundwater systems (Mývatn and Þeistareykir) that are both influenced by hydrothermal processes. Relative to NIST 3134 = +0.25‰, the cold (Icelandic rivers. In contrast, waters that are hydrothermally influenced (>10 °C) possess isotopically heavy δ98/95MoHYDROTHERMAL values of +0.25‰ to +2.06‰ (n = 18) with the possibility that the high temperature endmembers are even heavier. Although the mechanisms driving this fractionation remain unresolved, the incongruent dissolution of the host basalt and both the dissolution and precipitation of sulfides are considered. Regardless of the processes driving these variations, the δ98Mo data presented in this study indicate that groundwater and hydrothermal waters have the potential to modify ocean budget calculations.

  17. System and process for efficient separation of biocrudes and water in a hydrothermal liquefaction system

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Oyler, James R.; Rotness, Jr, Leslie J.; Schmidt, Andrew J.; Zacher, Alan H.

    2016-08-02

    A system and process are described for clean separation of biocrudes and water by-products from hydrothermal liquefaction (HTL) product mixtures of organic and biomass-containing feedstocks at elevated temperatures and pressures. Inorganic compound solids are removed prior to separation of biocrude and water by-product fractions to minimize formation of emulsions that impede separation. Separation may be performed at higher temperatures that reduce heat loss and need to cool product mixtures to ambient. The present invention thus achieves separation efficiencies not achieved in conventional HTL processing.

  18. The hydrothermal exploration system on the 'Qianlong2' AUV

    Science.gov (United States)

    Tao, W.; Tao, C.; Jinhui, Z.; Cai, L.; Guoyin, Z.

    2016-12-01

    ABSTRACT: Qianlong2, is a fully Autonomous Underwater Vehicle (AUV) designed for submarine resources research, especially for polymetallic sulphides, and the survey depths of is up to 4500 m. Qianlong2 had successfully explored hydrothermal vent field on the Southwest Indian Ridge (SWIR), and collected conductance, temperature and depth (CTD), turbidity, and Oxidation-Reduction Potential (ORP) data. It also had mapped precise topography by high resolution side scan sonar (HRBSSS) during every dive; and obtained photographs of sulfide deposits during some dives. Here, we detailedly described the implementation of investigation, data administration, and fast mapping of hydrothermal exploration system by Qianlong2. Giving a description of how to remove the platform magnetic interference by using magnetic data during Qianlong2 spin. Based on comprehensive hydrochemical anomalies, we get a rapid method for finding the localization of hydrothermal vents. Taking one dive as an example, we systemically showed the process about how to analyse hydrothermal survey data and acquire the location results of hydrothermal vents. Considering that this method is effective and can be used in other deep-submergence assets such as human occupied vehicles (HOVs) and remotely operated vehicles (ROVs) during further studies. Finally, we discussed how to promote and optimize the installation and application of those sensors and how to improve Qianlong2's autonomy of investigation.

  19. thermal power stations' reliability evaluation in a hydrothermal system

    African Journals Online (AJOL)

    Dr Obe

    A quantitative tool for the evaluation of thermal power stations reliability in a hydrothermal system is presented. A reliable power station is one which would supply the required power within its installed capacity at any time within the specified voltage and frequency limits. Required for this evaluation are the station's installed ...

  20. A Palaeoproterozoic multi-stage hydrothermal alteration system at Nalunaq gold deposit, South Greenland

    Science.gov (United States)

    Bell, Robin-Marie; Kolb, Jochen; Waight, Tod Earle; Bagas, Leon; Thomsen, Tonny B.

    2017-03-01

    Nalunaq is an orogenic, high gold grade deposit situated on the Nanortalik Peninsula, South Greenland. Mineralisation is hosted in shear zone-controlled quartz veins, located in fine- and medium-grained amphibolite. The deposit was the site of Greenland's only operating metalliferous mine until its closure in 2014, having produced 10.67 t of gold. This study uses a combination of field investigation, petrography and U/Pb zircon and titanite geochronology to define a multi-stage hydrothermal alteration system at Nalunaq. A clinopyroxene-plagioclase-garnet(-sulphide) alteration zone (CPGZ) developed in the Nanortalik Peninsula, close to regional peak metamorphism and prior to gold-quartz vein formation. The ca. 1783-1762-Ma gold-quartz veins are hosted in reactivated shear zones with a hydrothermal alteration halo of biotite-arsenopyrite-sericite-actinolite-pyrrhotite(-chlorite-plagioclase-löllingite-tourmaline-titanite), which is best developed in areas of exceptionally high gold grades. Aplite dykes dated to ca. 1762 Ma cross-cut the gold-quartz veins, providing a minimum age for mineralisation. A hydrothermal calcite-titanite alteration assemblage is dated to ca. 1766 Ma; however, this alteration is highly isolated, and as a result, its field relationships are poorly constrained. The hydrothermal alteration and mineralisation is cut by several generations of ca. 1745-Ma biotite granodiorite accompanied by brittle deformation. A ca. 1745-Ma lower greenschist facies hydrothermal epidote-calcite-zoisite alteration assemblage with numerous accessory minerals forms halos surrounding the late-stage fractures. The contrasting hydrothermal alteration styles at Nalunaq indicate a complex history of exhumation from amphibolite facies conditions to lower greenschist facies conditions in an orogenic belt which resembles modern Phanerozoic orogens.

  1. Catalytic Diversity in Alkaline Hydrothermal Vent Systems on Ocean Worlds

    Science.gov (United States)

    Cameron, Ryan D.; Barge, Laura; Chin, Keith B.; Doloboff, Ivria J.; Flores, Erika; Hammer, Arden C.; Sobron, Pablo; Russell, Michael J.; Kanik, Isik

    2016-10-01

    Hydrothermal systems formed by serpentinization can create moderate-temperature, alkaline systems and it is possible that this type of vent could exist on icy worlds such as Europa which have water-rock interfaces. It has been proposed that some prebiotic chemistry responsible for the emergence of life on Earth and possibly other wet and icy worlds could occur as a result ofredox potential and pH gradients in submarine alkaline hydrothermal vents (Russell et al., 2014). Hydrothermal chimneys formed in laboratory simulations of alkaline vents under early Earth conditions have precipitate membranes that contain minerals such as iron sulfides, which are hypothesized to catalyze reduction of CO2 (Yamaguchi et al. 2014, Roldan et al. 2014) leading to further organic synthesis. This CO2 reduction process may be affected by other trace components in the chimney, e.g. nickel or organic molecules. We have conducted experiments to investigate catalytic properties of iron and iron-nickel sulfides containing organic dopants in slightly acidic ocean simulants relevant to early Earth or possibly ocean worlds. We find that the electrochemical properties of the chimney as well as the morphology/chemistry of the precipitate are affected by the concentration and type of organics present. These results imply that synthesis of organics in water-rock systems on ocean worlds may lead to hydrothermal precipitates which can incorporate these organic into the mineral matrix and may affect the role of gradients in alkaline vent systems.Therefore, further understanding on the electroactive roles of various organic species within hydrothermal chimneys will have important implications for habitability as well as prebiotic chemistry. This work is funded by NASA Astrobiology Institute JPL Icy Worlds Team and a NAI Director's Discretionary Fund award.Yamaguchi A. et al. (2014) Electrochimica Acta, 141, 311-318.Russell, M. J. et al. (2014), Astrobiology, 14, 308-43.Roldan, A. (2014) Chem. Comm. 51

  2. Hydrothermal alteration and evolution of the Ohakuri hydrothermal system, Taupo volcanic zone, New Zealand

    Science.gov (United States)

    Henneberger, R. C.; Browne, P. R. L.

    1988-05-01

    Erosion and excavations at Ohakuri in the Taupo Volcanic zone have exposed the upper portion (100-150 m) of a hydrothermal system that was active sometime between 700,000 and 160,000 years ago. Extensive hydrothermal alteration occurred within a host sequence of young, relatively undeformed, chemically and lithologically similar unwelded rhyolitic ignimbrite and air-fall tuffs. Mapping and petrologic work have identified six distinct alteration types. An early event formed a concentrically zoned suite of alteration through the pervasive movement of alkaline chloride type water. In the innermost zone, primary rock components were almost entirely converted to quartz + adularia ± illite ± hematite ± leucoxene. Mineralized veins and breccias of quartz ± pyrite ± adularia ± chlorite formed here in response to episodic hydraulic fracturing. This zone grades outward and upward into a zone of less intense, lower rank alteration with a mordenite + clinoptilolite + smectite + opal ± hematite assemblage, then a zone of weak clay alteration and into fresh rock. Calcite is conspicuously absent from the entire suite. Acid-sulphate type water, formed from steam-condensate, dominated the shallow activity in a second stage of alteration that followed local erosion. Widespread but discontinuous alteration converted the ignimbrite to kaolinite + opal ± hematite, with alunite occurring in the more intense zones. This alteration locally overprints the early alkali-chloride produced suite, but the focus of the second-stage activity was north of the focus of the older event. Scattered opaline sinters and silicified surficial deposits are products of either still later activity or the waning part of the second stage. Chemical analysis shows that the various alteration types have characteristic patterns of major element addition and removal; these reflect the key hydrothermal mineral reactions that formed the new assemblages. Quartz-adularia alteration involved mainly

  3. The Benedikt hydrothermal system (north-eastern Slovenia)

    Science.gov (United States)

    Kralj, Peter; Eichinger, Lorenz; Kralj, Polona

    2009-10-01

    Deep welling in the Benedikt area has proven the existence of recently active hydrothermal system in pre-Tertiary basement composed of banded gneiss, marble and schist originating from a regionally metamorphosed sequence of clastic sediments. Two aquifers with very high fracture porosity were tapped—at depths between 1,485-1,530 and 1,848-1,857 m, where the welling stopped owing to a technical failure. The water temperature exceeds 90°C, while the yield of 100 l/s is limited only by the well performances. The Na-HCO3 dominated water is classified as a CO2-rich healing mineral water suitable for drinking, bottling and balneology. The free degassing gas is almost pure CO2 (99.9 %) and its δ13C composition indicates volcanic origin. The tapped water is relatively old, probably of Pleistocene age at least, and the planned exploitation must consider reinjection in order to protect this valuable natural resource from overexploitation. This recent hydrothermal system is characterised by dominating vertical circulation of waters and is superimposed on older, already inactive hydrothermal system(s), recognised by veins of either metal sulphides and quartz, or calcite. These vein minerals precipitated from hydrothermal fluids migrating from a deeper source towards the ancient surface through a fracture system, which is now self-sealed already. The distribution of metal sulphides indicates that the source might have been a deep-seated Neogene pluton genetically related to the tonalites and quartz diorites that outcrop in the Pohorje Mountains, or a subvolcanic-level volcanic body related to the Neogene volcanic activity in the Graz Basin.

  4. Modeling of Perturbations in Mid-Ocean Hydrothermal Systems

    Science.gov (United States)

    Singh, S.; Lowell, R. P.

    2013-12-01

    Mid-ocean ridge hydrothermal systems are complex fluid circulation systems straddling the locations of formation of oceanic crust. Due to the dynamic nature of the crust building process, these systems are episodically subject to magmatic and seismic perturbations. Magma may be emplaced deep or shallow in the oceanic crust thereby changing the thermal structure and permeability of the system. Such events would enhance hydrothermal venting resulting in an increase in vent temperature and heat output along with a decrease in vent salinity in a phase separating system. Event plumes, which may be associated with dike intrusions into the shallow crust, are an important class of such perturbations. In this case, the formation of low salinity vapor may add to the thermal buoyancy flux and allow the plume to rise rapidly to a considerable height above the seafloor. Additionally, seismic or tectonic disturbances may occur both deep and shallow in the crust, changing the fluid-flow structure in the system. Upon knowledge of a major magmatic or seismotectonic event, temporary surveillance at the respective mid ocean ridge site is often increased as a result of rapid response cruises. One of the most common observations made after such events is the temperature of vent fluids, which is then correlated to time of observed activity and used to estimate the residence time of fluids in the system. However, our numerical results indicate that for deep-seated perturbations, surface salinity may show quicker response than temperature. This result serves as our motivation to seek better understanding of propagation mechanism of perturbations through hydrothermal systems. We construct analytical models for fluid flow, heat and salt transfer in both single cracks and through porous media to investigate how perturbations affect both heat and salt transfer to the surface. Our preliminary results for simplified fluid circulation systems tend to support the results from numerical modeling

  5. Flow and permeability structure of the Beowawe, Nevada hydrothermal system

    Energy Technology Data Exchange (ETDEWEB)

    Faulder, D.D. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States); Johnson, S.D.; Benoit, W.R. [Oxbow Power Services, Inc., Reno, NV (United States)

    1997-05-01

    A review of past geologic, geochemical, hydrological, pressure transient, and reservoir engineering studies of Beowawe suggests a different picture of the reservoir than previously presented. The Beowawe hydrothermal contains buoyant thermal fluid dynamically balanced with overlying cold water, as shown by repeated temperature surveys and well test results. Thermal fluid upwells from the west of the currently developed reservoir at the intersection of the Malpais Fault and an older structural feature associated with mid-Miocene rifting. A tongue of thermal fluid rises to the east up the high permeability Malpais Fault, discharges at the Geysers area, and is in intimate contact with overlying cooler water. The permeability structure is closely related to the structural setting, with the permeability of the shallow hydrothermal system ranging from 500 to 1,000 D-ft, while the deeper system ranges from 200 to 400 D-ft.

  6. Hydrothermal Systems of Kamchatka are Models of the Prebiotic Environment

    Science.gov (United States)

    Kompanichenko, V. N.; Poturay, V. A.; Shlufman, K. V.

    2015-06-01

    The composition of organic matter and fluctuations of thermodynamic parameters were investigated in the hydrothermal systems of the Kamchatka peninsula in the context of the origin of life. Organics were analyzed by gas-chromatography/mass spectrometry, and 111 organic compounds belonging to 14 homologous series (aromatic hydrocarbons, alkanes and isoalkanes, halogenated aromatic hydrocarbons, carboxylic acids, esters, etc.) were found in hot springs inhabited by Archaeal and Bacterial thermophiles. The organics detected in the sterile condensate of water-steam mixture taken from deep boreholes (temperature 108-175 °C) consisted of 69 compounds of 11 homologous series, with aromatic hydrocarbons and alkanes being prevalent. The organic material included important prebiotic components such as nitrogen-containing compounds and lipid precursors. A separate organic phase (oil) was discovered in the Uzon Caldera. A biogenic origin is supported by the presence of sterane and hopane biomarkers and the δ13C value of the bulk oil; its age determined by 14C measurements was 1030 ± 40 years. Multilevel fluctuations of thermodynamic parameters proposed to be required for the origin of life were determined in the Mutnovsky and Pauzhetsky hydrothermal systems. The low-frequency component of the hydrothermal fluid pressure varied by up to 2 bars over periods of hours to days, while mid-frequency variations had regular micro-oscillations with periods of about 20 min; the high-frequency component displayed sharp changes of pressure and microfluctuations with periods less than 5 min. The correlation coefficient between pressure and temperature ranges from 0.89 to 0.99 (average 0.96). The natural regimes of pressure and temperature fluctuations in Kamchatka hydrothermal systems can guide future experiments on prebiotic chemistry under oscillating conditions.

  7. Lithium isotope traces magmatic fluid in a seafloor hydrothermal system.

    Science.gov (United States)

    Yang, Dan; Hou, Zengqian; Zhao, Yue; Hou, Kejun; Yang, Zhiming; Tian, Shihong; Fu, Qiang

    2015-09-08

    Lithium isotopic compositions of fluid inclusions and hosted gangue quartz from a giant volcanogenic massive sulfide deposit in China provide robust evidence for inputting of magmatic fluids into a Triassic submarine hydrothermal system. The δ(7)Li results vary from +4.5‰ to +13.8‰ for fluid inclusions and from +6.7‰ to +21.0‰ for the hosted gangue quartz(9 gangue quartz samples containing primary fluid inclusions). These data confirm the temperature-dependent Li isotopic fractionation between hydrothermal quartz and fluid (i.e., Δδ(7)Liquartz-fluid = -8.9382 × (1000/T) + 22.22(R(2) = 0.98; 175 °C-340 °C)), which suggests that the fluid inclusions are in equilibrium with their hosted quartz, thus allowing to determine the composition of the fluids by using δ(7)Liquartz data. Accordingly, we estimate that the ore-forming fluids have a δ(7)Li range from -0.7‰ to +18.4‰ at temperatures of 175-340 °C. This δ(7)Li range, together with Li-O modeling , suggest that magmatic fluid played a significant role in the ore formation. This study demonstrates that Li isotope can be effectively used to trace magmatic fluids in a seafloor hydrothermal system and has the potential to monitor fluid mixing and ore-forming process.

  8. Temperatures of Mediterranean Volcanic Hydrothermal Systems Reflected by Gas Geothermometry

    Science.gov (United States)

    Fiebig, J.; Tassi, F.; D'Alessandro, W.; Vaselli, O.; Woodland, A. B.

    2011-12-01

    We have addressed the genetic relationship between H2, H2O, CO, CO2, n-alkanes and n-alkenes in volcanic-hydrothermal gases emitted from Nisyros (Greece), Vesuvio, Campi Flegrei and Pantelleria (all Italy). Methane attains chemical and isotopic equilibrium with CO2 in the associated hydrothermal systems within the single liquid phase. Calculated aquifer temperatures at depth are ~360°C at Nisyros, 420-460°C at Vesuvio, ~450°C at Campi Flegrei and ~540°C at Pantelleria. CH4-CO2 equilibrium temperatures are in agreement with propane/propene concentration ratios. Temperatures >400°C are additionally confirmed by ethane/ethene ratios. In contrast to CH4-CO2, metastable equilibration of the alkane/alkene pairs takes place in the saturated water vapor phase. Overall agreement of vapor and liquid equilibration temperatures suggests that boiling in the investigated high-enthalpy hydrothermal systems is essentially isothermal. Our results imply that the chemical and isotopic CH4-CO2 geothermometer is least prone to re-equilibration reactions occurring in the vapor phase after vapor separation. Redox conditions during these re-equilibration reactions are homogeneously buffered by H2/H2O ratios of the vapor phase, which, in turn, are controlled by those of the parental liquid phase and by the degree of superimposed vapor separation. Amongst the redox pairs investigated, CO/CO2 is most prone to secondary vapor phase equilibration. Our results imply that the isotopic CH4-CO2 geothermometer has the potential to record temperatures of aquifers associated with dormant volcanoes. Alkene/alkane and H2/H2O concentration ratios should be measured along with CH4 and CO2 to prove independently whether isotopic equilibrium has been attained.

  9. Spatial distribution of marine crenarchaeota group I in the vicinity of deep-sea hydrothermal systems.

    Science.gov (United States)

    Takai, Ken; Oida, Hanako; Suzuki, Yohey; Hirayama, Hisako; Nakagawa, Satoshi; Nunoura, Takuro; Inagaki, Fumio; Nealson, Kenneth H; Horikoshi, Koki

    2004-04-01

    Distribution profiles of marine crenarchaeota group I in the vicinity of deep-sea hydrothermal systems were mapped with culture-independent molecular techniques. Planktonic samples were obtained from the waters surrounding two geographically and geologically distinct hydrothermal systems, and the abundance of marine crenarchaeota group I was examined by 16S ribosomal DNA clone analysis, quantitative PCR, and whole-cell fluorescence in situ hybridization. A much higher proportion of marine crenarchaeota group I within the microbial community was detected in deep-sea hydrothermal environments than in normal deep and surface seawaters. The highest proportion was always obtained from the ambient seawater adjacent to hydrothermal emissions and chimneys but not from the hydrothermal plumes. These profiles were markedly different from the profiles of epsilon-Proteobacteria, which are abundant in the low temperatures of deep-sea hydrothermal environments.

  10. Geochemical Energy for Catabolism and Anabolism in Hydrothermal Systems

    Science.gov (United States)

    Amend, J. P.; McCollom, T. M.; Bach, W.

    2008-12-01

    Chemically reduced deep-sea vent fluids mixed with oxidized seawater can generate redox disequilibria that serve as energy sources for chemolithoautotrophic (catabolism) and biomass synthesis (anabolism) reactions. Numerical models can be used to evaluate Gibbs energies of such processes on the early Earth and in present-day systems. Here, geochemical data from compositionally diverse vent fluids (Lost City, Rainbow, Logatchev, TAG, 21 °N EPR) are combined with several seawater chemistries to yield a wide range of mixed hydrothermal solutions; this is the starting point for our thermodynamic calculations. In ultramafic-hosted hydrothermal systems, such as Rainbow or Lost City, aerobic chemolithotrophic catabolisms (oxidation of H2, FeII, CH4) are the most energy-yielding at low temperatures (<25 °C); at elevated temperatures, the anaerobic counterparts (e.g., sulfate reduction, methanogenesis) dominate. In basalt-hosed systems, such as TAG and 21 °N EPR, aerobic sulfide oxidation appears to dominate over much of the microbially-relevant temperature range. Such catabolic reaction energetics can then be used to put constraints on the amount of primary biomass production. Under putative early Earth conditions, for example, the net chemoautotrophic synthesis of cellular building blocks is thermodynamically most favorable at moderate temperatures (~50°C), where the energy contributions from HCO3- and H+ in cool seawater coupled to the reducing power in hot vent fluid are optimized. At these conditions, and counter to conventional wisdom, the synthesis of amino acids may even yield small amounts of energy.

  11. Monitoring the hydrothermal system in Long Valley caldera, California

    Science.gov (United States)

    Farrar, C.D.; Sorey, M.L.

    1985-01-01

    An ongoing program to monitor the hydrothermal system in Long Valley for changes caused by volcanic or tectonic processes has produced considerable data on the water chemistry and discharge of springs and fluid temperatures and pressures in wells. Chemical and isotopic data collected under this program have greatly expanded the knowledge of chemical variability both in space and time. Although no chemical or isotopic changes in hot spring waters can be attributed directly to volcanic or tectonic processes, changes in hot spring chemistry that have been recorded probably relate to interactions between and variations in the quantity of liquid and gas discharged. Stable carbon isotope data are consistent with a carbon source either perform the mantle or from metamorphosed carbonate rocks. Continuous and periodic measurements of hot spring discharge at several sites show significant co seismic and a seismic changes since 1980.

  12. Hydrothermal minerals

    Digital Repository Service at National Institute of Oceanography (India)

    Nath, B.N.

    , radon etc. to locate active venting site 4. Seabed sampling for rocks and minerals looking for indications of hydrothermal mineralization 5. TV and still Photographic surveys with real- time imaging on board 6. Submersible/ROVs for direct... thriving in this unique environments. However, the study of hydrothermal systems is still relatively young, and there are many fundamental questions that remain to be addressed in the forthcoming years. Suggested reading 1. Seafloor hydrothermal...

  13. Geochemistry and strontium isotopic composition of mineralforming solutions of hydrothermal systems of southern Kamchatka

    Energy Technology Data Exchange (ETDEWEB)

    Pampura, V.D.; Plyusnin, G.S.; Sandimirova, G.P.

    1980-01-01

    In order to understand the genesis of hydrothermal systems in the regions of recent volcanism, the chemical composition of hydrothermal waters was studied. In addition, the behavior of strontium in the process of hydrothermal alteration of volcanic aquifers was considered. The data on strontium isotopy for thermal waters, effusives and volcanic-sedimentary rocks of the Pauzhetka hydrothermal region are given. For depth-derived sodium-chloride hydrothermal waters /sup 87/Sr//sup 86/Sr values lie within the range of 0.7033 to 0.7056. Significant differences of /sup 87/Sr//sup 86/Sr values in seawater and sodium-chloride hydrothermal waters at all levels of their geochemical metamorphism were noted. This is considered to be evidence of the absence of seawater in the chemical composition of hydrothermal waters of the Pauzhetka type. To determine the cause of low /sup 87/Sr//sup 86/Sr values of depth-derived sodium-chloride hydrothermal waters, the strontium isotopy of country rocks was studied and /sup 87/Sr//sup 86/Sr = 0.702 to 0.705 have been determined. The data indicate the possibility that recent hydrothermal waters inherited a ratio of /sup 87/Sr//sup 86/Sr = 0.703 to 0.704 at the aquifer level.

  14. The importance of shallow hydrothermal island arc systems in ocean biogeochemistry

    NARCIS (Netherlands)

    Hawkes, J.A.; Connelly, D.P.; Rijkenberg, M.J.A.; Achterberg, E.P.

    2014-01-01

    Hydrothermal venting often occurs at submarine volcanic calderas on island arc chains, typically at shallower depths than mid-ocean ridges. The effect of these systems on ocean biogeochemistry has been under-investigated to date. Here we show that hydrothermal effluent from an island arc caldera was

  15. The hydrothermal system of Long Valley Caldera, California

    Science.gov (United States)

    Sorey, M.L.; Lewis, Robert Edward; Olmsted, F.H.

    1978-01-01

    Long Valley caldera, an elliptical depression covering 450 km 2 on the eastern front of the Sierra Nevada in east-central California, contains a hot-water convection system with numerous hot springs and measured and estimated aquifer temperatures at depths of 180?C to 280?C. In this study we have synthesized the results of previous geologic, geophysical, geochemical, and hydrologic investigations of the Long Valley area to develop a generalized conceptual and mathematical model which describes the gross features of heat and fluid flow in the hydrothermal system. Cenozoic volcanism in the Long Valley region began about 3.2 m.y. (million years) ago and has continued intermittently until the present time. The major event that resulted in the formation of the Long Valley caldera took place about 0.7 m.y. ago with the eruption of 600 km 3 or more of Bishop Tuff of Pleistocene age, a rhyolitic ash flow, and subsequent collapse of the roof of the magma chamber along one or more steeply inclined ring fractures. Subsequent intracaldera volcanism and uplift of the west-central part of the caldera floor formed a subcircular resurgent dome about 10 km in diameter surrounded by a moat containing rhyolitic, rhyodacitic, and basaltic rocks ranging in age from 0.5 to 0.05 m.y. On the basis of gravity and seismic studies, we estimate an aver- age thickness of fill of 2.4 km above the precaldera granitic and metamorphic basement rocks. A continuous layer of densely welded Bishop Tuff overlies the basement rocks, with an average thickness of 1.4 km; the fill above the welded Bishop Tuff consists of intercalated volcanic flows and tuffs and fluvial and lacustrine deposits. Assuming the average grain density of the fill is between 2.45 and 2.65 g/cm 3 , we calculate the average bulk porosity of the total fill as from 0.11 to 0.21. Comparison of published values of porosity of the welded Bishop Tuff exposed southeast of the caldera with calculated values indicates average bulk porosity

  16. Temporal and Seasonal Variations of the Hot Spring Basin Hydrothermal System, Yellowstone National Park, USA

    Directory of Open Access Journals (Sweden)

    Cheryl Jaworowski

    2013-12-01

    Full Text Available Monitoring Yellowstone National Park’s hydrothermal systems and establishing hydrothermal baselines are the main goals of an ongoing collaborative effort between Yellowstone National Park’s Geology program and Utah State University’s Remote Sensing Services Laboratory. During the first years of this research effort, improvements were made in image acquisition, processing and calibration. In 2007, a broad-band, forward looking infrared (FLIR camera (8–12 microns provided reliable airborne images for a hydrothermal baseline of the Hot Spring Basin hydrothermal system. From 2008 to 2011, night-time, airborne thermal infrared image acquisitions during September yielded temperature maps that established the temporal variability of the hydrothermal system. A March 2012 airborne image acquisition provided an initial assessment of seasonal variability. The consistent, high-spatial resolution imagery (~1 m demonstrates that the technique is robust and repeatable for generating corrected (atmosphere and emissivity and calibrated temperature maps of the Hot Spring Basin hydrothermal system. Atmospheric conditions before and at flight-time determine the usefulness of the thermal infrared imagery for geohydrologic applications, such as hydrothermal monitoring. Although these ground-surface temperature maps are easily understood, quantification of radiative heat from the Hot Spring Basin hydrothermal system is an estimate of the system’s total energy output. Area is a key parameter for calculating the hydrothermal system’s heat output. Preliminary heat calculations suggest a radiative heat output of ~56 MW to 62 MW for the central Hot Spring Basin hydrothermal system. Challenges still remain in removing the latent solar component within the calibrated, atmospherically adjusted, and emissivity corrected night-time imagery.

  17. Application of Hydrothermal and Non-Hydrothermal TiO2 Nanoporous Materials as New Adsorbents for Removal of Heavy Metal Ions from Aqueous System

    Directory of Open Access Journals (Sweden)

    Mansoor Anbia

    2016-06-01

    Full Text Available Hydrothermal and non-hydrothermal spherical TiO2 nanoporous with crystalline framework were prepared by sol-gel method. The Crystalline structures, morphologies and surface texturing of materials were determined by X-ray diffraction (XRD, scanning electron microscopy (SEM and N2 adsorption-desorption isotherms. The Hydrothermal spherical TiO2 nanoporous was found to have a narrow and strong pore size distribution peaks with average of 37.8 Å and pore volume of 0.41 cm3/g and the (Brunauer–Emmett–TellerBET specific surface area of 365 m2/g. Hydrothermal and non-hydrothermal spherical TiO2 nanoporous have been used as adsorbent to study of the adsorption behavior of Pb(II, Co(II and Ni(II ions from aqueous system in a batch system. Effect of equilibrium time on adsorption Pb(II, Co(II and Ni(II ions on these adsorbent was studied The results show that the shaking time 0.5 to 10h has no serious effect on the percentage of ions removal, and the adsorption is fast in all cases. The maximum uptake capacities of Hydrothermal and non-hydrothermal spherical TiO2 nanoporous was calculated. Both hydrothermal and non-hydrothermal TiO2 nanoporous materials were found to have very good potential as new adsorbents in removal of these ions. In batch systems the maximum uptake capacities of Pb(II, Ni(II and Co(II on the hydrothermal and non-hydrothermal TiO2 nanoporous materials was Co(II > Pb(II > Ni(II and Co(II > Ni(II > Pb(II, respectively.

  18. New insights into the Kawah Ijen hydrothermal system from geophysical data

    Science.gov (United States)

    Caudron, Corentin; Mauri, G.; Williams-Jones, Glyn; Lecocq, Thomas; Syahbana, Devy Kamil; de Plaen, Raphael; Peiffer, Loic; Bernard, Alain; Saracco, Ginette

    2017-01-01

    Volcanoes with crater lakes and/or extensive hydrothermal systems pose significant challenges with respect to monitoring and forecasting eruptions, but they also provide new opportunities to enhance our understanding of magmatic–hydrothermal processes. Their lakes and hydrothermal systems serve as reservoirs for magmatic heat and fluid emissions, filtering and delaying the surface expressions of magmatic unrest and eruption, yet they also enable sampling and monitoring of geochemical tracers. Here, we describe the outcomes of a highly focused international experimental campaign and workshop carried out at Kawah Ijen volcano, Indonesia, in September 2014, designed to answer fundamental questions about how to improve monitoring and eruption forecasting at wet volcanoes.

  19. The importance of shallow hydrothermal island arc systems in ocean biogeochemistry

    OpenAIRE

    Hawkes, J.A.; Connelly, D. P.; Rijkenberg, M.J.A.; E. P. Achterberg

    2014-01-01

    Hydrothermal venting often occurs at submarine volcanic calderas on island arc chains, typically at shallower depths than mid-ocean ridges. The effect of these systems on ocean biogeochemistry has been under-investigated to date. Here we show that hydrothermal effluent from an island arc caldera was rich in Fe(III) colloids (0.02-0.2 mu m; 46% of total Fe), contributing to a fraction of hydrothermal Fe that was stable in ocean water. Iron(III) colloids from island arc calderas may be transfer...

  20. Migration of hydrothermal systems in an evolving collisional orogen, New Zealand

    Science.gov (United States)

    Craw, D.; Upton, P.; Horton, T.; Williams, J.

    2013-02-01

    The Pacific-Australian tectonic plate boundary through the South Island of New Zealand consists of the transpressional Southern Alps mountain belt and the transcurrent Marlborough Fault System, both of which have active tectonically driven hydrothermal systems, with topographically driven meteoric incursion and warm springs. The Southern Alps hydrothermal system is relatively diffuse, with little or no fault control, and is channelled through scattered extensional sites beneath the mountains, where gold mineralisation is occurring locally. The hydrothermal activity along the Marlborough Fault System is controlled by the principal faults in well-defined valleys separated by narrow high ridges. Lateral evolution of Marlborough fault strands southwestwards into the Southern Alps has caused diversion of diffuse Southern Alps hydrothermal activity into the structural superimposition zone, where fluid flow is increasingly being controlled by faults. This hydrothermal diversion was accompanied by major topographic reorientation and river drainage reversal in the late Quaternary. Vein swarms now exposed in the remnants of the Southern Alps north of the superimposition zone formed at shallow levels, with some evidence for fluid boiling, from a mixture of meteoric and deep-sourced fluid. These veins, some of which contain gold, are part of an abandoned lateral incursion of the Marlborough fault strands. Observations on this active plate boundary provide some insights into processes that controlled orogenic gold mineralisation in ancient belts, particularly with respect to relationships between hydrothermal fluid flow, structure and topography.

  1. Chaotic thermohaline convection in low-porosity hydrothermal systems

    NARCIS (Netherlands)

    Schoofs, Stan; Spera, Frank J.; Hansen, Ulrich

    1999-01-01

    Fluids circulate through the Earth's crust perhaps down to depths as great as 5^15 km, based on oxygen isotope systematics of exhumed metamorphic terrains, geothermal fields, mesozonal batholithic rocks and analysis of obducted ophiolites. Hydrothermal flows are driven by both thermal and chemical

  2. Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems.

    Directory of Open Access Journals (Sweden)

    Yao Zhang

    Full Text Available To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4 concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4 was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4 concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

  3. Bioavailability, Bioaccumulation and Biotransformation of arsenic in coral reef organisms surrounding an arsenic-rich marine shallow-water hydrothermal vent system in the coastal waters of Ambitle Island, Papua New Guinea

    Science.gov (United States)

    Pichler, T.; Wallschläger, D.; Price, R. E.

    2009-12-01

    Marine shallow-water hydrothermal systems are often enriched in biologically toxic elements, thus making them ideal natural analogs for coastal anthropogenic pollution. Here, we report our investigation of the bioavailability, bioaccumulation, and biotransformation of hydrothermally-derived arsenic into several coral reef organisms from the arsenic-rich marine shallow-water hydrothermal system of Tutum Bay, Ambitle Island, in northeastern Papua New Guinea. Hydrothermal venting provided bioavailable As by two major pathways throughout Tutum Bay: 1) easily-exchangeable As from hydrothermally influenced sediments to as far away as 200 m from focused venting, and 2) in surface seawaters, which may allow for biological uptake by phytoplankton and transfer up the food web. The soft coral Clavularia sp., the calcareous algae Halimeda sp., and the tunicate Polycarpa sp. collected from the hydrothermal area each displayed distinctly higher (up to 20 times) total arsenic compared to the control site, with increasing trends while approaching focused hydrothermal venting. Organic and inorganic arsenic species were extracted intact from the tissues of each organism, separated by anion exchange chromatography, and analyzed by inductively-coupled plasma-dynamic reaction cell-mass spectrometry. Overall, speciation patterns for Clavularia were similar for the control site versus the hydrothermal site, although the concentrations were much higher. Elevated concentrations of DMA and cationic forms of arsenic, most likely AB, in Clavularia, both from the control site and from the hydrothermal area suggest its metabolic pathway is not altered due to hydrothermal activity, and is similar to other marine organisms. Arsenic speciation patterns in Polycarpa were also similar for both sites, and suggests uptake of arsenic via food chain, containing neither As(III) nor As(V), but abundant excluded As and DMA. It is unclear if methylation is taking place within this organism or prior to

  4. Entropy production in a box: Analysis of instabilities in confined hydrothermal systems

    Science.gov (United States)

    Börsing, N.; Wellmann, J. F.; Niederau, J.; Regenauer-Lieb, K.

    2017-09-01

    We evaluate if the concept of thermal entropy production can be used as a measure to characterize hydrothermal convection in a confined porous medium as a valuable, thermodynamically motivated addition to the standard Rayleigh number analysis. Entropy production has been used widely in the field of mechanical and chemical engineering as a way to characterize the thermodynamic state and irreversibility of an investigated system. Pioneering studies have since adapted these concepts to natural systems, and we apply this measure here to investigate the specific case of hydrothermal convection in a "box-shaped" confined porous medium, as a simplified analog for, e.g., hydrothermal convection in deep geothermal aquifers. We perform various detailed numerical experiments to assess the response of the convective system to changing boundary conditions or domain aspect ratios, and then determine the resulting entropy production for each experiment. In systems close to the critical Rayleigh number, we derive results that are in accordance to the analytically derived predictions. At higher Rayleigh numbers, however, we observe multiple possible convection modes, and the analysis of the integrated entropy production reveals distinct curves of entropy production that provide an insight into the hydrothermal behavior in the system, both for cases of homogeneous materials, as well as for heterogeneous spatial material distributions. We conclude that the average thermal entropy production characterizes the internal behavior of hydrothermal systems with a meaningful thermodynamic measure, and we expect that it can be useful for the investigation of convection systems in many similar hydrogeological and geophysical settings.

  5. Microbial community structure across fluid gradients in the Juan de Fuca Ridge hydrothermal system.

    Science.gov (United States)

    Anderson, Rika E; Beltrán, Mónica Torres; Hallam, Steven J; Baross, John A

    2013-02-01

    Physical and chemical gradients are dominant factors in shaping hydrothermal vent microbial ecology, where archaeal and bacterial habitats encompass a range between hot, reduced hydrothermal fluid and cold, oxidized seawater. To determine the impact of these fluid gradients on microbial communities inhabiting these systems, we surveyed bacterial and archaeal community structure among and between hydrothermal plumes, diffuse flow fluids, and background seawater in several hydrothermal vent sites on the Juan de Fuca Ridge using 16S rRNA gene diversity screening (clone libraries and terminal restriction length polymorphisms) and quantitative polymerase chain reaction methods. Community structure was similar between hydrothermal plumes and background seawater, where a number of taxa usually associated with low-oxygen zones were observed, whereas high-temperature diffuse fluids exhibited a distinct phylogenetic profile. SUP05 and Arctic96BD-19 sulfur-oxidizing bacteria were prevalent in all three mixing regimes where they exhibited overlapping but not identical abundance patterns. Taken together, these results indicate conserved patterns of redox-driven niche partitioning between hydrothermal mixing regimes and microbial communities associated with sinking particles and oxygen-deficient waters. Moreover, the prevalence of SUP05 and Arctic96BD-19 in plume and diffuse flow fluids indicates a more cosmopolitan role for these groups in the ecology and biogeochemistry of the dark ocean. © 2012 Federation of European Microbiological Societies. Published by Blackwell Publishing Ltd. All rights reserved.

  6. An unit commitment model for hydrothermal systems; Um modelo de unit commitment para sistemas hidrotermicos

    Energy Technology Data Exchange (ETDEWEB)

    Franca, Thiago de Paula; Luciano, Edson Jose Rezende; Nepomuceno, Leonardo [Universidade Estadual Paulista (UNESP), Bauru, SP (Brazil). Dept. de Engenharia Eletrica], Emails: ra611191@feb.unesp.br, edson.joserl@uol.com.br, leo@feb.unesp.br

    2009-07-01

    A model of Unit Commitment to hydrothermal systems that includes the costs of start/stop of generators is proposed. These costs has been neglected in a good part of the programming models for operation of hydrothermal systems (pre-dispatch). The impact of the representation of costs in total production costs is evaluated. The proposed model is solved by a hybrid methodology, which involves the use of genetic algorithms (to solve the entire part of the problem) and sequential quadratic programming methods. This methodology is applied to the solution of an IEEE test system. The results emphasize the importance of representation of the start/stop in the generation schedule.

  7. The effect of prior hydrothermal alteration on the melting behaviour during rhyolite formation in Yellowstone, and its importance in the generation of low-δ18O magmas

    Science.gov (United States)

    Troch, Juliana; Ellis, Ben S.; Harris, Chris; Ulmer, Peter; Bachmann, Olivier

    2018-01-01

    Constraining the contribution of crustal lithologies to silicic magmas has important implications for understanding the dynamics of these potentially highly explosive systems. Low-δ18O rhyolite lavas erupted after caldera-forming events in Yellowstone have been interpreted as the products of bulk crustal melting of previously deposited and hydrothermally altered rhyolitic material in the down-dropped caldera roof. For lack of compositional data, the "self-cannibalisation bulk melting"-theory relies on the assumption that hydrothermally altered materials are near-cotectic and hydrous (>3 wt% H2O) and will therefore readily melt at temperatures below 850 °C. In this study, we examine the drillcores Y2, Y9 and Y13 from a USGS drilling campaign in Yellowstone in order to characterise the hydrothermally altered material in terms of major and trace elements, oxygen isotopes and water contents. Rhyolite δ18O values can decrease from "normal" (+5.8 to +6.1‰) on the surface to as low as -5‰ at depths of 100-160 m and probably lower as a function of increasing temperature with depth. While material in the drillcores is variably altered and silicified, oxygen isotope exchange in these samples is not accompanied by systematic changes in major and trace element composition and is independent of uptake of water. More than 75% of the drillcore samples have water the most limiting factor during melting. Modelled melting curves using rhyolite-MELTS suggest a maximum of 35% melt can be created at 850 °C, and that bulk melting would require extremely high temperatures >1100 °C. Therefore, large-scale bulk melting is unrealistic and low-δ18O rhyolite magmas more likely result from assimilation of <30% partially melted altered crust with low δ18O into a normal-δ18O rhyolite magma from the main reservoir. This mechanism is supported by isotopic mass-balance models as well as thermal and volumetric constraints, and may be similarly applicable to other low-δ18O settings

  8. Phase separation, brine formation, and salinity variation at Black Smoker hydrothermal systems

    NARCIS (Netherlands)

    Coumou, D.; Driesner, T.; Weis, P.; Heinrich, C. A.

    2009-01-01

    We present the first fully transient 2-D numerical simulations of black smoker hydrothermal systems using realistic fluid properties and allowing for all phase transitions possible in the system H2O-NaCl, including phase separation of convecting seawater into a low-salinity vapor and high-salinity

  9. Hydrogen, Oxygen and Silicon Isotope Systematics of Groundwater-Magma Interaction in Icelandic Hydrothermal Systems

    Science.gov (United States)

    Kleine, B. I.; Stefansson, A.; Halldorsson, S. A.; Martin, W.; Barnes, J.; Jónasson, K.; Franzson, H.

    2016-12-01

    Magma often encounters groundwater (meteoric or seawater derived) when intruded into the crust. Magma-groundwater interactions result in the formation of hydrothermal fluids which can lead to contact metamorphism and elemental transport in the country rock. In fact, magma-hydrothermal fluid interaction (rather than magma-magmatic fluid interaction) may lead to classic contact metamorphic reactions. In order to explore the importance of hydrothermal fluid during contact metamorphism we use stable isotopes (δD, δ18O, δ30Si) from both active and extinct magma chambers and hydrothermal systems from across Iceland. Quartz grains from various hydrothermal systems, from crustal xenoliths from the Askja central volcano and from the Hafnarfjall pluton, as well as quartz grains associated with low-T zeolites were analysed for δ18O and δ30Si in-situ using SIMS. Whole rock material of these samples was analysed for δD values using a TCEA coupled to an IRMS. Our results indicate that low-T quartz (300°C). Combining the results from the analyses of δ18O and δD allows further division of samples into (i) seawater and/or rock dominated and (ii) meteoric water dominated hydrothermal systems. In order to isolate the effects of fluid-rock interaction, fluid source and formation temperature at the magma-groundwater contact, δD, δ18O and δ30Si values of rocks and fluids were modeled using the PHREEQC software. Comparison of analytical and model results shows that the isotopic compositions are influenced by multiple processes. In some cases, groundwater penetrates the contact zone and causes alteration at >400°C by groundwater-magma heat interaction. Other cases document "baked" contact zones without groundwater. Our analyses and modeling demonstrates that groundwater flow and permeability are crucial in setting the style of contact metamorphism around high T intrusions.

  10. Identifying bubble collapse in a hydrothermal system using hiddden Markov models

    Science.gov (United States)

    Dawson, Phillip B.; Benitez, M.C.; Lowenstern, Jacob B.; Chouet, Bernard A.

    2012-01-01

    Beginning in July 2003 and lasting through September 2003, the Norris Geyser Basin in Yellowstone National Park exhibited an unusual increase in ground temperature and hydrothermal activity. Using hidden Markov model theory, we identify over five million high-frequency (>15 Hz) seismic events observed at a temporary seismic station deployed in the basin in response to the increase in hydrothermal activity. The source of these seismic events is constrained to within ~100 m of the station, and produced ~3500–5500 events per hour with mean durations of ~0.35–0.45 s. The seismic event rate, air temperature, hydrologic temperatures, and surficial water flow of the geyser basin exhibited a marked diurnal pattern that was closely associated with solar thermal radiance. We interpret the source of the seismicity to be due to the collapse of small steam bubbles in the hydrothermal system, with the rate of collapse being controlled by surficial temperatures and daytime evaporation rates.

  11. Basin scale permeability and thermal evolution of a magmatic hydrothermal system

    Science.gov (United States)

    Taron, J.; Hickman, S. H.; Ingebritsen, S.; Williams, C.

    2013-12-01

    Large-scale hydrothermal systems are potentially valuable energy resources and are of general scientific interest due to extreme conditions of stress, temperature, and reactive chemistry that can act to modify crustal rheology and composition. With many proposed sites for Enhanced Geothermal Systems (EGS) located on the margins of large-scale hydrothermal systems, understanding the temporal evolution of these systems contributes to site selection, characterization and design of EGS. This understanding is also needed to address the long-term sustainability of EGS once they are created. Many important insights into heat and mass transfer within natural hydrothermal systems can be obtained through hydrothermal modeling assuming that stress and permeability structure do not evolve over time. However, this is not fully representative of natural systems, where the effects of thermo-elastic stress changes, chemical fluid-rock interactions, and rock failure on fluid flow and thermal evolution can be significant. The quantitative importance of an evolving permeability field within the overall behavior of a large-scale hydrothermal system is somewhat untested, and providing such a parametric understanding is one of the goals of this study. We explore the thermal evolution of a sedimentary basin hydrothermal system following the emplacement of a magma body. The Salton Sea geothermal field and its associated magmatic system in southern California is utilized as a general backdrop to define the initial state. Working within the general framework of the open-source scientific computing initiative OpenGeoSys (www.opengeosys.org), we introduce full treatment of thermodynamic properties at the extreme conditions following magma emplacement. This treatment utilizes a combination of standard Galerkin and control-volume finite elements to balance fluid mass, mechanical deformation, and thermal energy with consideration of local thermal non-equilibrium (LTNE) between fluids and solids

  12. Assessment of operation reserves in hydrothermal electric systems with high wind generation

    NARCIS (Netherlands)

    Ramos, Andres; Rivier, Michel; García-González, Javier; Latorre, Jesus M.; Morales Espana, G.

    2016-01-01

    In this paper, we propose a method to analyze the amount of operation reserves procured in a system based on two stages. The first stage is a detailed hourly unit commitment and the second stage is a simulation model with a shorter time period. The method is applied to the Spanish hydrothermal

  13. Numerical 3D models support two distinct hydrothermal circulation systems at fast spreading ridges

    Science.gov (United States)

    Hasenclever, Jörg; Theissen-Krah, Sonja; Rüpke, Lars

    2013-04-01

    We present 3D numerical calculations of hydrothermal fluid flow at fast spreading ridges. The setup of the 3D models is based our previous 2D studies, in which we have coupled numerical models for crustal accretion and hydrothermal fluid flow. One result of these calculations is a crustal permeability field that leads to a thermal structure in the crust that matches seismic tomography data of the East Pacific Rise (EPR). The 1000°C isotherm obtained from the 2D results is now used as the lower boundary of the 3D model domain, while the upper boundary is a smoothed bathymetry of the EPR. The same permeability field as in the 2D models is used, with the highest permeability at the ridge axis and a decrease with both depth and distance to the ridge. Permeability is also reduced linearly between 600 and 1000°C. Using a newly developed parallel finite element code written in Matlab that solves for thermal evolution, fluid pressure and Darcy flow, we simulate the flow patterns of hydrothermal circulation in a segment of 5000m along-axis, 10000m across-axis and up to 5000m depth. We observe two distinct hydrothermal circulation systems: An on-axis system forming a series of vents with a spacing ranging from 100 to 500m that is recharged by nearby (100-200m) downflows on both sides of the ridge axis. Simultaneously a second system with much broader extensions both laterally and vertically exists off-axis. It is recharged by fluids intruding between 1500m to 5000m off-axis and sampling both upper and lower crust. These fluids are channeled in the deepest and hottest regions with high permeability and migrate up-slope following the 600°C isotherm until reaching the edge of the melt lens. Depending on the width of the melt lens these off-axis fluids either merge with the on-axis hydrothermal system or form separate vents. We observe separate off-axis vent fields if the magma lens half-width exceeds 1000m and confluence of both systems for half-widths smaller than 500m. For

  14. Reaction chemistry of nitrogen species in hydrothermal systems: Simple reactions, waste simulants, and actual wastes

    Energy Technology Data Exchange (ETDEWEB)

    Dell`Orco, P.; Luan, L.; Proesmans, P.; Wilmanns, E.

    1995-02-01

    Results are presented from hydrothermal reaction systems containing organic components, nitrogen components, and an oxidant. Reaction chemistry observed in simple systems and in simple waste simulants is used to develop a model which presents global nitrogen chemistry in these reactive systems. The global reaction path suggested is then compared with results obtained for the treatment of an actual waste stream containing only C-N-0-H species.

  15. Hydrothermal pretreatment of palm oil empty fruit bunch

    Science.gov (United States)

    Simanungkalit, Sabar Pangihutan; Mansur, Dieni; Nurhakim, Boby; Agustin, Astrid; Rinaldi, Nino; Muryanto, Fitriady, Muhammad Ariffudin

    2017-01-01

    Hydrothermal pretreatment methods in 2nd generation bioethanol production more profitable to be developed, since the conventional pretreatment, by using acids or alkalis, is associated with the serious economic and environmental constraints. The current studies investigate hydrothermal pretreatment of palm oil empty fruit bunch (EFB) in a batch tube reactor system with temperature and time range from 160 to 240 C and 15 to 30 min, respectively. The EFB were grinded and separated into 3 different particles sizes i.e. 10 mesh, 18 mesh and 40 mesh, prior to hydrothermal pretreatment. Solid yield and pH of the treated EFB slurries changed over treatment severities. The chemical composition of EFB was greatly affected by the hydrothermal pretreatment especially hemicellulose which decreased at higher severity factor as determined by HPLC. Both partial removal of hemicellulose and migration of lignin during hydrothermal pretreatment caused negatively affect for enzymatic hydrolysis. This studies provided important factors for maximizing hydrothermal pretreatment of EFB.

  16. Carlin-type Au Deposits in Nevada: Unique Hydrothermal Systems?

    Science.gov (United States)

    Cline, J. S.

    2006-05-01

    Carlin-type gold deposits (CTGD) in Nevada have huge Au endowments that have made Nevada one of the leading Au producers in the world. Although they form one of the three most productive Au districts in the world, the deposits were not discovered until the early 1960's owing primarily to the lack of visible Au. Numerous studies have provided a detailed geologic picture of the deposits, yet a comprehensive and widely accepted genetic model remains elusive because of 1) difficulties in identifying and analyzing the fine-grained, volumetrically minor, and common ore and gangue minerals, 2) approximately contemporaneous mineralization that overprinted or was overprinted by Carlin-type mineralization, and 3) post-ore weathering and oxidation. Geologic data from all districts indicate compelling similarities, suggesting that all deposits formed in response to similar geologic processes. Yet, stable isotope studies suggest multiple sources for ore fluids and components. Because of these inconsistencies, current models relate deposits to 1) metal leaching and transport by convecting meteoric water, 2) hydrothermal fluids exsolved from epizonal intrusions, and 3) deep metamorphic and/or magmatic fluids. Proterozoic to early Paleozoic rifting produced a passive margin sequence of reactive calcareous host rocks, and NNW- and WNW-striking basement and Paleozoic normal faults that may control the trends. Following rifting, the host rocks were subjected to compressional orogenies, developing a pre-mineral architecture of steeply dipping fluid conduits and shallow dipping traps. NNW- and WNW-striking basement and Paleozoic normal faults were inverted during these compressional events and formed structural culminations including anticlines and domes that served as depositional sites for ore fluids. Au-bearing pyrite precipitated 42-36 m.y. ago as northwesterly to westerly extension reopened favorably oriented older structures. Fluid flow and mineral deposition appear to have been

  17. The Muruntau gold deposit (Uzbekistan – A unique ancient hydrothermal system in the southern Tien Shan

    Directory of Open Access Journals (Sweden)

    Ulf Kempe

    2016-05-01

    Full Text Available The Muruntau gold deposit in the Central Kyzylkum, Uzbekistan is one of the largest single gold deposits worldwide. Data available from the literature are reviewed with the aim to (1 integrate the present knowledge on this unique deposit from Russian and English literature; (2 show the considerable progress made in the understanding of the genesis of the Muruntau deposit during the last decades; and (3 point to problems still open for future research. Deposit formation occurred through a multi-stage process involving sedimentation, regional metamorphism including thrusting, magmatism with formation of hornfels aureoles and several stages of hydrothermal activity. According to recent knowledge, synsedimentary or pure metamorphic formation of gold mineralization seems unlikely. The role of granite magmatism occurring roughly within the same time interval as the main hydrothermal gold precipitation remains uncertain. There are no signs of interaction of matter between the magma(s and the hydrothermal system(s. On the other hand, there was an intense, high-temperature (above 400 °C fluid – wall rock interaction resulting in the formation of gold-bearing, cone-like stockworks with veins, veinlets and gold-bearing metasomatites. Several chemical and isotope indicators hint at an involvement of lower-crustal or mantle-related sources as well as of surface waters in ore formation. Deposit formation through brecciation involving explosion, hydrothermal or tectonic breccias might explain these data. Further investigations on breccia formation as well as on the exact timing of relevant sedimentary, metamorphic, magmatic and hydrothermal events are recommended.

  18. Hydrothermal alteration in the Baca Geothermal System, Redondo Dome, Valles Caldera, New Mexico

    Science.gov (United States)

    Hulen, Jeffrey B.; Nielson, Dennis L.

    1986-02-01

    Thermal fluids circulating in the active hydrothermal system of the resurgent Redondo dome of the Valles caldera have interacted with their diverse host rocks to produce well-zoned alteration assemblages, which not only help locate permeable fluid channels but also provide insight into the system's thermal history. The alteration shows that fluid flow has been confined principally to steeply dipping normal faults and subsidiary fractures as well as thin stratigraphic aquifers. Permeability along many of these channels has been reduced or locally eliminated by hydrothermal self-sealing. Alteration from the surface through the base of the Miocene Paliza Canyon Formation is of three distinctive types: argillic, propylitic, and phyllic. Argillic alteration forms a blanket above the deep water table in formerly permeable nonwelded tuffs. Beneath the argillic zone, pervasive propylitic alteration is weakly developed in felsic host rocks but locally intense in deep intermediate composition volcanics. Strong phyllic alteration is commonly but not invariably associated with major active thermal fluid channels. Phyllic zones yielding no fluid were clearly once permeable but now are hydrothermally sealed. High-temperature alteration phases at Baca are presently found at much lower temperatures. We suggest either that isotherms have collapsed due to gradual cooling of the system, that they have retreated without overall heat loss due to uplift of the Redondo dome, that the system has shifted laterally, or that it has contracted due to a drop in the water table. The deepest Well (B-12, 3423 m) in the dome may have penetrated through the base of the active hydrothermal system. Below a depth of 2440 m in this well, hydrothermal veining largely disappears, and the rocks resemble those developed by isochemical thermal metamorphism. The transition is reflected by temperature logs, which show a conductive thermal gradient below 2440 m. This depth may mark the dome's neutral plane

  19. Strontium and oxygen isotopic profiles through 3km of hydrothermally altered oceanic crust in the Reykjanes Geothermal System, Iceland

    OpenAIRE

    Marks, Naomi; Zierenberg, Robert A.; Schiffman, Peter

    2015-01-01

    © 2015 Elsevier B.V. The Iceland Deep Drilling Program well RN-17 was drilled 3km into a section of hydrothermally altered basaltic crust in the Reykjanes geothermal system in Iceland. The system is located on the landward extension of the Mid-Atlantic Ridge, and the circulating hydrothermal fluid is modified seawater, making Reykjanes a useful analog for mid-oceanic ridge hydrothermal systems. We have determined whole-rock Sr and O isotope compositions, and Sr isotope compositions of epidote...

  20. Numerical Modeling of Multiphase Fluid Flow in Ore-Forming Hydrothermal Systems

    Science.gov (United States)

    Weis, P.; Driesner, T.; Coumou, D.; Heinrich, C. A.

    2007-12-01

    Two coexisting fluid phases - a variably saline liquid and a vapor phase - are ubiquitous in ore-forming and other hydrothermal systems. Understanding the dynamics of phase separation and the distinct physical and chemical evolution of the two fluids probably plays a key role in generating different ore deposit types, e.g. porphyry type, high and low sulfidation Cu-Mo-Au deposits. To this end, processes within hydrothermal systems have been studied with a refined numerical model describing fluid flow in transient porous media (CSP~5.0). The model is formulated on a mass, energy and momentum conserving finite-element-finite-volume (FEFV) scheme and is capable of simulating multiphase flow of NaCl-H20 fluids. Fluid properties are computed from an improved equation of state (SOWAT~2.0). It covers conditions with temperatures of up to 1000 degrees~C, pressures of up to 500 MPa, and fluid salinities of 0~to 100%~NaCl. In particular, the new set-up allows for a more accurate description of fluid phase separation during boiling of hydrothermal fluids into a vapor and a brine phase. The geometric flexibility of the FEFV-meshes allows for investigations of a large variety of geological settings, ranging from ore-forming processes in magmatic hydrothermal system to the dynamics of black smokers at mid-ocean ridges. Simulations demonstrated that hydrothermal convection patterns above cooling plutons are primarily controlled by the system-scale permeability structure. In porphyry systems, high fluid pressures develop in a stock rising from the magma chamber which can lead to rock failure and, eventually, an increase in permeability due to hydrofracturing. Comparisons of the thermal evolution as inferred from modeling studies with data from fluid inclusion studies of the Pb-Zn deposits of Madan, Bulgaria are in a strikingly good agreement. This indicates that cross-comparisons of field observations, analytical data and numerical simulations will become a powerful tool towards a

  1. Surficial extent and conceptual model of hydrothermal system at Mount Rainier, Washington

    Science.gov (United States)

    Frank, David

    1995-04-01

    A once massive hydrothermal system was disgorged from the summit of Mount Rainier in a highly destructive manner about 5000 years ago. Today, hydrothermal processes are depositing clayey alteration products that have the potential to reset the stage for similar events in the future. Areas of active hydrothermal alteration occur in three representative settings: (1) An extensive area (greater than 12,000 m 2) of heated ground and slightly acidic boiling-point fumaroles at 76-82 °C at East and West Craters on the volcano's summit, where alteration products include smectite, halloysite and disordered kaolinite, cristobalite, tridymite, opal, alunite, gibbsite, and calcite. (2) A small area (less than 500 m 2) of heated ground and sub-boiling-point fumaroles at 55-60 °C on the upper flank at Disappointment Cleaver with smectite alteration and chalcedony, tridymite, and opal-A encrustations. Similar areas probably occur at Willis Wall, Sunset Amphitheater, and the South Tahoma and Kautz headwalls. (3) Sulfate- and carbon dioxide-enriched thermal springs at 9-24 °C on the lower flank of the volcano in valley walls beside the Winthrop and Paradise Glaciers, where calcite, opal-A, and gypsum are being deposited. In addition, chloride- and carbon dioxide-enriched thermal springs issue from thin sediments that overlie Tertiary rocks at, or somewhat beyond, the base of the volcanic edifice in valley bottoms of the Nisqually and Ohanapecosh Rivers. Maximum spring temperatures of 19-25 °C and 38-50 °C, respectively, and extensive travertine deposits have developed in these more distant localities. The heat flow, distribution of thermal activity, and nature of alteration minerals and fluids suggest a conceptual model of a narrow, central hydrothermal system within Mount Rainier, with steam-heated snowmelt at the summit craters and localized leakage of steam-heated fluids within 2 km of the summit. The lateral extent of the hydrothermal system is marked by discharge of

  2. Flow systems exploiting in-line prior assays.

    Science.gov (United States)

    Grassi, Viviane; Dias, Ana Cristi B; Zagatto, Elias A G

    2004-12-15

    An expert sequential injection system involving a prior assay is proposed for spectrophotometric determination of phosphate and eventually zinc in soil extracts. The result of phosphate determination is the basis for a concentration-oriented decision regarding to the need or not for zinc determination. Zinc was only determined if a threshold value (peak height corresponding to 5.0mgl(-1)P) was surpassed. The methods involved formation of molybdenum blue and the Rhodamine 6G/ammonium thiocyanate/Zn(2+) ternary complex. Variations in the threshold value were < 2% during 4h operating periods, false responses were not verified, and the analytical time was reduced in about 30%. Precise results (R.S.D. <3%P and < 1% Zn) in agreement with spectrophotometry and flame atomic absorption spectrometry were obtained. The innovation permits faster information processing, as well as a reduction in the number of measurements, number of analytical steps, laboratorial time, and consumption of sample and reagents, thus waste generation.

  3. Interactions between phase separation, mineral precipitation, and permeability variations in saline magmatic-hydrothermal system

    Science.gov (United States)

    Weis, P.

    2016-12-01

    Fluid flow through permeable rocks in saline magmatic-hydrothermal systems is influenced by non-linear fluid and rock properties as well as physical and chemical fluid-rock interactions. The same processes are of critical importance to a variety of different disciplines of Earth sciences such as volcanology, geothermal energy, hydrogeology and economic geology, and progress in understanding the relative importance of the interactions between different processes requires multi-method approaches investigating both active and fossil hydrothermal systems. Observations and model results suggest that many of these systems are highly dynamic and have a potential for self-organization, optimizing heat and mass transport by fluids in the upper crust. For example, numerical simulations in combination with oxygen isotopes of vein quartz suggest that ore precipitation in porphyry copper deposits occurs at the hydrological interface between a dynamic plume of ascending magmatic fluids and meteoric water convection, which is controlled by the transition from ductile to brittle rock behavior. With increasing ductile behavior, we infer that locally host rock permeability is reduced and the regional stress state is relaxed, resulting in fluid pressure build-up to near-lithostatic values with continued fluid expulsion, which eventually leads to episodic brittle failure of otherwise nominally ductile rocks. Sharp pressure drops and phase separation at this hydrological front can lead to saturation in solid halite, which is indicated to be a ubiquitous feature in hydrothermal systems associated with upper crustal plutons both by fluid inclusion studies and numerical simulations. Precipitation of solid halite can also lead to permeability reduction and evoke pulsating fluid migration. The presentation will show analytical and numerical results describing the role of non-linear fluid properties, phase separation, salt precipitation, fluid mixing, hydraulic fracturing and the brittle

  4. Hydrothermal REE and Zr Ore Forming Processes in Peralkaline Granitic Systems

    Science.gov (United States)

    Gysi, A. P.

    2015-12-01

    Anorogenic peralkaline igneous systems display extreme enrichment of REE and Zr with a hydrothermal overprint leading to post-magmatic metal mobilization. Strange Lake in Canada, for example, is a mid-Proterozoic peralkaline granitic intrusion and host to a world-class REE-Zr deposit with >50 Mt ore (>1.5 wt.% REE and >3 wt.% Zr). In contrast to porphyry systems, peralkaline systems are poorly understood and hydrothermal metal mobilization models are only in the early stage of their development. This is partly due to the paucity of thermodynamic data for REE-bearing minerals and aqueous species, and the complexity of the hydrothermal fluids (enrichment of F, P and Cl), which make it difficult to develop thermodynamic models of metal partitioning. This study aims to show the link between alteration stages and metal mobilization using Strange Lake as a natural laboratory and combine these observations with numerical modeling. Four types of alteration were recognized at Strange Lake: i) alkali (i.e. K and Na) metasomatism related to interaction with NaCl-bearing orthomagmatic fluids, ii) acidic alteration by HCl-HF-bearing fluids originating from the pegmatites followed by iii) aegirinization of the border of the pegmatites and surrounding granites and by iv) pervasive Ca-F-metasomatism. The acidic alteration accounts for most of the hydrothermal metal mobilization in and outward from the pegmatites, whereas the Ca-F-metasomatism led to metal deposition and resulted from interaction of an acidic F-rich fluid with a Ca-bearing fluid. Numerical simulations of fluid-rock reactions with saline HCl-HF-bearing fluids at 400 °C to 250 °C indicate that temperature, availability of F/Cl and pH limit the mobility of Zr and REE. Fluids with pH peralkaline granitic systems is the formation of a fluid-buffered subsystem providing the acids and ligands required for REE and Zr mobilization.

  5. The dynamic interplay between saline fluid flow and rock permeability in magmatic-hydrothermal systems

    OpenAIRE

    Philipp Weis

    2015-01-01

    Magmatic-hydrothermal ore deposits document the interplay between saline fluid flow and rock permeability. Numerical simulations of multiphase flow of variably miscible, compressible H2O–NaCl fluids in concert with a dynamic permeability model can reproduce characteristics of porphyry copper and epithermal gold systems. This dynamic permeability model uses values between 10−22 and 10−13 m2, incorporating depth-dependent permeability profiles characteristic for tectonically active crust as wel...

  6. Comparative assessment of five potential sites for hydrothermal-magma systems: energy transport

    Energy Technology Data Exchange (ETDEWEB)

    Hardee, H.C.

    1980-09-01

    A comparative assessment of five sites is being prepared as part of a Continental Scientific Drilling Program (CSDP) review of thermal regimes for the purpose of scoping areas for future research and drilling activities. This background report: discusses the various energy transport processes likely to be encountered in a hydrothermal-magma system, reviews related literature, discusses research and field data needs, and reviews the sites from an energy transport viewpoint. At least three major zones exist in the magma-hydrothermal transport system: the magma zone, the hydrothermal zone, and the transition zone between the two. Major energy transport questions relate to the nature and existence of these zones and their evolution with time. Additional energy transport questions are concerned with the possible existence of critical state and super-critical state permeable convection in deep geothermal systems. A review of thermal transport models emphasizes the fact that present transport models and computational techniques far outweigh the scarcity and quality of deep field data.

  7. Solubility limits in Mn–Mg ferrites system under hydrothermal conditions

    Energy Technology Data Exchange (ETDEWEB)

    Hemeda, O.M., E-mail: omhemeda@yahoo.co.uk [Physics Department, Faculty of Science, Tanta University, Tanta (Egypt); Mostafa, N.Y. [Chemistry Department, Faculty of Science, Suez Canal University, Ismailia 41522 (Egypt); Faculty of Science, Taif University, PO Box 888, Al-Haweiah, Taif (Saudi Arabia); Abd Elkader, O.H. [Electron Microscope and Thin Films Department, National Research Center, Dokki 12622, Cairo (Egypt); Electron Microscope Unit, Zoology Department, King Saud University, Riyadh 11451 (Saudi Arabia); Ahmed, M.A. [Physics Department, Faculty of Science, Al Azhar University, Nasr City, Cairo (Egypt)

    2014-09-01

    In the present investigation, we successfully synthesized a pure MnFe{sub 2}O{sub 4} ferrite by the hydrothermal method. Moreover, the effect of Mg ion content on the formation of Mn{sub 1−x}Mg{sub x}Fe{sub 2}O{sub 4} particles (with x varying from 0.1 to 1.0) was also investigated using XRD, SEM, TEM and Mossbauer Spectroscopy. Phases formed in the system Mn{sub 1−x}Mg{sub x}Fe{sub 2}O{sub 4}; 0.0≤x≤1.0 were investigated under hydrothermal conditions at 453 K.The produced phases were characterized by X-ray diffraction, Scanning, transmission microscopy and Mossbauer spectroscopy. The information of composition, cation distribution in the spinel structure and the particle size of the products were obtained. The spinel ferrites; Mn{sub 1−x}Mg{sub x}Fe{sub 2}O{sub 4} were formed in the range 0.0≤x≤0.3. However, sample with x>0.3 showed semi-crystalline magnesium hydroxide (Mg(OH){sub 2}) and hematite (Fe{sub 2}O{sub 3}) beside the ferrite phase. For x=1.0, only magnesium hydroxide and hematite are formed without any ferrites. Particles of uniform size around 10–20 nm were obtained in the spinel structure of Mn{sub 1−x}Mg{sub x}Fe{sub 2}O{sub 4} with x=0.0 and 0.1. The corresponding average crystallite size for each sample was 40.3 nm and 39.2 nm respectively. In addition, the Mossbauer spectra were analyzed into two subspectra, one for the tetrahedral A-site and the other for the octahedral B-site. The Mossbauer parameters were determined and discussed for the studied system. The cation distribution was estimated from the analysis of the Mossbauer spectra as well as the X-ray diffraction patterns. The results showed that Mg ions occupy mainly B-site while both Mn and Fe ions are distributed between A- and B-sites. - Highlights: • Mossbauer characterization of Mg–Mn ferrite prepared by hydrothermal route. • X-ray powder diffraction analysis of Mg–Mn ferrite prepared by hydrothermal route. • Solubility limit of MgMn ferrite under

  8. Temperature Effects on Phase Relations in Ultramafic-Hosted Hydrothermal Systems

    Science.gov (United States)

    Seyfried, W. E.; Foustoukos, D. I.; Fu, Q.

    2005-12-01

    The effect of temperature on alteration processes in ultramafic hosted hydrothermal systems is significant and manifest by complex changes in secondary mineralization and the composition of coexisting fluids, as suggested by recent experimental and theoretical data. At relatively high temperatures (400C) olivine recrystallization reactions are sluggish, generally limiting mass transfer. In SiO2 bearing fluids, such as the case for the Rainbow hydrothermal system (36N, MAR), evidence indicates olivine recrystallization to a more fayalite-rich phase and talc, enhancing olivine stability at reaction zone conditions. These phases plus tremolite play a key role in maintaining fluid acidity, accounting for the unusually high levels of dissolved metals that characterize the high temperature Rainbow vent fluids. In contrast, hydrothermal alteration of ultramafic rocks by seawater at temperatures below 300C generally results in high pH fluids, serpentinization of olivine and coexisting pyroxene, and Ca for Mg exchange in the fluid. Data also indicate potentially high dissolved H2 and low dissolved Fe and total dissolved sulfide species. Analogous processes likely characterize subseafloor reaction zones at the Lost City Hydrothermal Field (LCHF), which lies on the Atlantis Massif at 30N, 15 km west of the Mid-Atlantic Ridge. Indeed, geochemical modeling of the Lost City vent fluid chemistry suggests subseafloor temperatures of approximately 200C, which are considerably greater than the measured vent fluid temperatures (40 to 90C), suggesting conductive cooling and seawater mixing effects; processes consistent with the reported mineralization of chimney structures. Available data also suggest moderately high fluid/rock mass ratios, which in combination with reaction zone temperature estimates make it unlikely that hydrothermal circulation can be a direct result of the exothermic nature of the conversion of olivine to serpentine. Accordingly, alternative heat sources need to

  9. Newly discovered hydrothermal system on the Alarcón Rise, Mexico

    Science.gov (United States)

    Paduan, J. B.; Clague, D. A.; Caress, D. W.; Lundsten, L.; Martin, J. F.; Nieves-Cardoso, C.

    2012-12-01

    The Alarcón Rise lies at the mouth of the Gulf of California, and is the last segment of the East Pacific Rise before the plate boundary redirects into the gulf. As part of MBARI's expedition to the gulf in 2012, the neovolcanic zone of the entire ridge segment was mapped by MBARI's mapping AUV. 110 potential hydrothermal chimneys were identified in the new high resolution maps, and 70 were visited with the ROV Doc Ricketts, after having been sought in vain without the maps on an expedition in 2003. Two active vent fields were found, and have been named Meyibó and Ja sít from local native languages. They lie 2.5km apart at ~2300m depth, and are associated with a large, young sheet flow 1/3 of the way along the ridge from the south, on the most inflated part of the ridge. The southern field, Meyibó, contains 14 active chimneys (confirmed with ROV observations) nestled in grabens of several highly fractured cones surrounded by the sheet flow, and generally aligned with its discontinuous, 8km-long fissure system. The northern field, Ja sít, is a broad cluster of 8 active chimneys (also confirmed) rising above the sheet flow's channel system, more than 150m from the fissure. The chimneys stand as tall as 18 m. The most vigorous vent "black smoke" (mineral-rich fluid) >300°C and others are bathed in "white smoke". The active chimneys are populated with bacterial mat and dense clumps of Riftia pachyptila with tubes as long as 1.5m. Abundant limpets, Bythograea thermydron and galatheid crabs, and the pink vent fish Thermarces cerberus were on and near the giant tube worms. Alvinellid worms were observed at 2 chimneys. Some cracks in nearby lava flows vented clear fluid and were populated with tubeworms or Calyptogena magnifica clams. Several chimneys exhibited signs of waning activity: dead tubeworms were still attached and only a minor portion of the edifice supported bacterial mat and live tubeworms. Inactive chimneys are more numerous (48 were confirmed with ROV

  10. Subseafloor Biosphere Linked to Hydrothermal Systems: TAIGA Concept

    National Research Council Canada - National Science Library

    Ishibashi, Jun-ichiro; Okino, Kyoko; Sunamura, Michinari

    2015-01-01

    This book is the comprehensive volume of the TAIGA (“a great river ” in Japanese) project. Supported by the Japanese government, the project examined the hypothesis that the subseafloor fluid advection system...

  11. Post-impact hydrothermal system geochemistry and mineralogy: Rochechouart impact structure, France.

    Science.gov (United States)

    Simpson, Sarah

    2014-05-01

    Hypervelocity impacts generate extreme temperatures and pressures in target rocks and may permanently alter them. The process of cratering is at the forefront of research involving the study of the evolution and origin of life, both on Mars and Earth, as conditions may be favourable for hydrothermal systems to form. Of the 170 known impact structures on Earth, over one-third are known to contain fossil hydrothermal systems [1]. The introduction of water to a system, when coupled with even small amounts of heat, has the potential to completely alter the target or host rock geochemistry. Often, the mineral assemblages produced in these environments are unique, and are useful indicators of post-impact conditions. The Rochechouart impact structure in South-Central France is dated to 201 ± 2 Ma into a primarily granitic target [2]. Much of the original morphological features have been eroded and very little of the allochthonous impactites remain. This has, however, allowed researchers to study the shock effects on the lower and central areas of the structure, as well as any subsequent hydrothermal activity. Previous work has focused on detailed classification of the target and autochthonous and allochthonous impactites [3, 4], identification of the projectile [5], and dating the structure using Ar-isotope techniques [2]. Authors have also noted geochemical evidence of K-metasomatism, which is pronounced throughout all lithologies as enrichment in K2O and depletion in CaO and Na2O [3, 4, 5]. This indicates a pervasive hydrothermal system, whose effects throughout the structure have yet to be studied in detail, particularly in those parts at and below the transient floor. The purpose of this study is to classify the mineralogical and geochemical effects of the hydrothermal system. Samples were collected via permission from the Réserve Naturelle de l'Astroblème de Rochechouart-Chassenon [6]. Sample selection was based on the presence of secondary mineralization in hand

  12. A review of numerical simulation of hydrothermal systems.

    Science.gov (United States)

    Mercer, J.W.; Faust, C.R.

    1979-01-01

    Many advances in simulating single and two-phase fluid flow and heat transport in porous media have recently been made in conjunction with geothermal energy research. These numerical models reproduce system thermal and pressure behaviour and can be used for other heat-transport problems, such as high-level radioactive waste disposal and heat-storage projects. -Authors

  13. Identifying bubble collapse in a hydrothermal system using hidden Markov models

    Science.gov (United States)

    Dawson, P.B.; Benitez, M.C.; Lowenstern, J. B.; Chouet, B.A.

    2012-01-01

    Beginning in July 2003 and lasting through September 2003, the Norris Geyser Basin in Yellowstone National Park exhibited an unusual increase in ground temperature and hydrothermal activity. Using hidden Markov model theory, we identify over five million high-frequency (>15Hz) seismic events observed at a temporary seismic station deployed in the basin in response to the increase in hydrothermal activity. The source of these seismic events is constrained to within ???100 m of the station, and produced ???3500-5500 events per hour with mean durations of ???0.35-0.45s. The seismic event rate, air temperature, hydrologic temperatures, and surficial water flow of the geyser basin exhibited a marked diurnal pattern that was closely associated with solar thermal radiance. We interpret the source of the seismicity to be due to the collapse of small steam bubbles in the hydrothermal system, with the rate of collapse being controlled by surficial temperatures and daytime evaporation rates. copyright 2012 by the American Geophysical Union.

  14. Hydrothermal system of the Papandayan Volcano from temperature, self-potential (SP) and geochemical measurements

    Science.gov (United States)

    Byrdina, Svetlana; Revil, André; Gunawan, Hendra; Saing, Ugan B.; Grandis, Hendra

    2017-07-01

    Papandayan volcano in West Java, Indonesia, is characterized by intense hydrothermal activities manifested by numerous fumaroles at three craters or kawah, i.e. Mas, Manuk and Baru. The latter was created after November 2002 phreatic eruption. Since 2011, numerous volcano-tectonic B events are encountered and the volcano was set on alert status on several occasions. The purpose of the present study is to delineate the structure of the summital hydrothermal system from Self-Potential (SP), soil temperature and gas concentrations in the soil (CO2, SO2 and H2S) data. This combination of geophysical and geochemical methods allows identification of the weak permeable zones serving as preferential pathways for hydrothermal circulation and potential candidates to future landslides or flank collapses. This study is an on-going collaborative research project and we plan to conduct electrical resistivity tomography (ERT) and also Induced-Polarization (IP) surveys. Additional data would allow the 3D imaging of the studied area. The IP parameters will be used to characterise and to quantify the degree of alteration of the volcanic rocks as has been shown very recently in the laboratory studies. There are also rocks and soil samples that will undergo laboratory analyses at ISTerre for IP and complex resistivity parameters at the sample scale that will help to interpret the survey results.

  15. Nanoparticles in the zirconia-europium niobate system via hydrothermal route.

    Science.gov (United States)

    Hirano, Masanori; Dozono, Hayato

    2013-10-01

    The effect of the composition on the hydrothermal formation, structure, and properties of nanocrystalline luminescent materials in the zirconia (ZrO2)-europium niobate 1/4(Eu3NbO7) system was investigated. In the composition range 40 particles with crystallite size 6.0-7.6 nm that were hydrothermally formed from the precursor solutions of NbCl5, ZrOCI2, and EuCl3 under weakly basic conditions at 240 degrees C showed cubic structure. The lattice parameter when estimated as a single cubic phase linearly decreased as the concentration of ZrO2 increased. The presence of zirconia component effectively promoted the formation of nanocrystals containing the niobate, Eu3NbO7 under hydrothermal condition. The nanocrystalline particles could be excited by ultraviolet light 395 nm (f-f transition) and emitted orange (590 nm) and red light (610 nm) corresponding to 5D0 --> 7F1 and 5D0 --> 7F2 transitions of Eu3+, respectively. The intensity of the electric dipole transition (5D0 --> 7F2) that was expressed in values relative to the magnetic dipole transition (5D0 --> 7F1) increased with increased heat-treatment temperature in the range from 950 to 1200 degrees C.

  16. Numerical Modeling of Brine Formation and Serpentinization at the Rainbow Hydrothermal System

    Science.gov (United States)

    Sekhar, P.; Lowell, R. P.

    2015-12-01

    The Rainbow hydrothermal field on the Mid Atlantic Ridge is a high-temperature hydrothermal system hosted in peridotite. The vent fluids are rich in methane and hydrogen suggesting that serpentinization is occurring at depth in the system. Vent temperature of ~365°C, salinity of ~4.5 wt%, and heat output of ~500 MW suggest that Rainbow field is driven by a magmatic heat source and that phase separation is occurring at depth. To understand the origin of high salinity in the Rainbow hydrothermal fluid, we construct a 2D numerical model of two-phase hydrothermal circulation using the numerical simulator FISHES. This code uses the finite volume method to solve the conservation of mass, momentum, energy, and salt equations in a NaCl-H2O fluid. We simulate convection in an open top 2D box at a surface pressure of 23 MPa and seawater temperature of 10oC. The bottom and sides of the box are insulated and impermeable, and a fixed temperature distribution is maintained at the base to ensure phase separation. We first consider a homogeneous model with a permeability of 10-13 m2 and system depths of 2 and 1 km, respectively. The brine-derived fluid from the deeper system barely exceeds seawater, whereas the shallower system produces a short pulse of 9.0 wt% for 5 years. We then consider 1 km deep systems with a high permeability discharge zone of 5x10-13 m2 that corresponds to a fault zone, surrounded by recharge zones of 10-13, 10-14 and 10-15 m2, respectively. The model with recharge permeability of 10-14 m2 yields stable plumes that vent brine-derived fluid of 4.2 wt% for 150 years. Using the quasi- steady state of this model as a base, we estimate the rate of serpentinization along the fluid flow paths, and evolution of porosity and permeability. This analysis will indicate the extent to which serpentinization will affect the dynamics of the system and will provide insight into methane flux in the Rainbow vent field.

  17. Multifractal spatial organisation in hydrothermal gold systems of the Archaean Yilgarn craton, Western Australia

    Science.gov (United States)

    Munro, Mark; Ord, Alison; Hobbs, Bruce

    2015-04-01

    A range of factors controls the location of hydrothermal alteration and gold mineralisation in the Earth's crust. These include the broad-scale lithospheric architecture, availability of fluid sources, fluid composition and pH, pressure-temperature conditions, microscopic to macroscopic structural development, the distribution of primary lithologies, and the extent of fluid-rock interactions. Consequently, the spatial distribution of alteration and mineralization in hydrothermal systems is complex and often considered highly irregular. However, despite this, do they organize themselves in a configuration that can be documented and quantified? Wavelets, mathematical functions representing wave-like oscillations, are commonly used in digital signals analysis. Wavelet-based multifractal analysis involves incrementally scanning a wavelet across the dataset multiple times (varying its scale) and recording its degree of fit to the signal at each interval. This approach (the wavelet transform modulus maxima method) highlights patterns of self-similarity present in the dataset and addresses the range of scales over which these patterns replicate themselves (expressed by their range in 'fractal dimension'). Focusing on seven gold ore bodies in the Archaean Yilgarn craton of Western Australia, this study investigates whether different aspects of hydrothermal gold systems evolve to organize themselves spatially as multifractals. Four ore bodies were selected from the Sunrise Dam deposit (situated in the Laverton tectonic zone of the Kurnalpi terrane) in addition to the Imperial, Majestic and Salt Creek gold prospects, situated in the Yindarlgooda dome of the Mount Monger goldfield (approximately 40km due east of Kalgoorlie). The Vogue, GQ, Cosmo East and Astro ore bodies at Sunrise Dam were chosen because they exhibit different structural geometries and relationships between gold and associated host-rock alteration styles. Wavelet-based analysis was conducted on 0.5m and 1m

  18. Implications of Chloride, Boron, and Lithium in Hydrothermal Systems of Jamaica, WI

    Science.gov (United States)

    Wishart, D.

    2012-12-01

    Chloride (Cl) often termed a "relatively conservative element" served as a very useful tracer (pathfinder element) in fluids from hydrothermal systems by comparing its concentration to those of select ions in solution. The concentrations of major ions of three thermal spring water samples: Bath hot springs (BTHS and BTHN), Milk River (MKR), Windsor (WS) and a cold spring water sample-Salt River spring (SR) of Jamaica were plotted against the Cl concentration. Results of chemical analyses, graphical analyses, and hydrogeochemical modeling confirmed three water types: Na-Cl-SO4, Na-Cl, and Ca-Na-Cl. Whereas chloride concentrations at MKR, WS and SR strongly indicate the influence of sea water mixing, the concentrations at MKR and SR are spatially related to a major tectonic feature, the South Coast Fault Zone (SCFZ). A principal component analysis (PCA) performed for the water samples showed a direct correlation between the concentrations of chloride and other conservative elements: boron (B), lithium (Li), bromide (Br), strontium (Sr), arsenic (As), and cesium (Cs). Isotope results (δ18O, δ2H, 3H) of the water samples implied minimal shallow mixing with deep circulating thermal fluids at the Bath site and the predominance of mixing with deep-circulating brines at the WS, MKR, and SR sites. Ionic ratios (Cl/B, Br/Cl, Li/B, have provided further interesting results for these hydrothermal systems including (1) a power series relationship between Li/B and SO4/Cl ratios; (2) the variation of B/Li versus Cl/SO4 concentrations with relatively prolonged water-rock contact time for these waters occurring at depth; and (3) low enthalpy. A discriminant analysis (DA) aided in the delineation of three independent hydrothermal systems based on processes affecting the chemical compositions of the water samples. Calculated chloride convective heat fluxes range between compared to the boron flux range of 3.41 x 104 - 1.63 x 106 Calories/second.

  19. Development of Vertical Cable Seismic System for Hydrothermal Deposit Survey (2) - Feasibility Study

    Science.gov (United States)

    Asakawa, E.; Murakami, F.; Sekino, Y.; Okamoto, T.; Mikada, H.; Takekawa, J.; Shimura, T.

    2010-12-01

    In 2009, Ministry of Education, Culture, Sports, Science and Technology(MEXT) started the survey system development for Hydrothermal deposit. We proposed the Vertical Cable Seismic (VCS), the reflection seismic survey with vertical cable above seabottom. VCS has the following advantages for hydrothermal deposit survey. . (1) VCS is an effective high-resolution 3D seismic survey within limited area. (2) It achieves high-resolution image because the sensors are closely located to the target. (3) It avoids the coupling problems between sensor and seabottom that cause serious damage of seismic data quality. (4) Various types of marine source are applicable with VCS such as sea-surface source (air gun, water gun etc.) , deep-towed or ocean bottom sources. (5) Autonomous recording system. Our first experiment of 2D/3D VCS surveys has been carried out in Lake Biwa, JAPAN. in November 2009. The 2D VCS data processing follows the walk-away VSP, including wave field separation and depth migration. The result gives clearer image than the conventional surface seismic. Prestack depth migration is applied to 3D data to obtain good quality 3D depth volume. Uncertainty of the source/receiver poisons in water causes the serious problem of the imaging. We used several transducer/transponder to estimate these positions. The VCS seismic records themselves can also provide sensor position using the first break of each trace and we calibrate the positions. We are currently developing the autonomous recording VCS system and planning the trial experiment in actual ocean to establish the way of deployment/recovery and the examine the position through the current flow in November, 2010. The second VCS survey will planned over the actual hydrothermal deposit with deep-towed source in February, 2011.

  20. Multiple objective optimization of hydro-thermal systems using Ritz's method

    Directory of Open Access Journals (Sweden)

    L. Bayón Arnáu

    2000-01-01

    Full Text Available This paper examines the applicability of the Ritz method to multi-objective optimization of hydro-thermal systems. The algorithm proposed is aimed to minimize an objective functional that incorporates the cost of energy losses, the conventional fuel cost and the production of atmospheric emissions such as NOx and SO2 caused by the operation of fossil-fueled thermal generation. The formulation includes a general layout of hydro-plants that may form multi-chains of reservoir network.

  1. Hydrothermal System of the Lastarria Volcano (Central Andes) Imaged by Magnetotellurics

    Science.gov (United States)

    Diaz, D.

    2015-12-01

    Lazufre volcanic complex, located in the central Andes, is recently undergoing an episode of uplift, conforming one of the most extensive deforming volcanic systems worldwide. Recent works have focused on the subsurface of this volcanic system at different scales, using surface deformation data, seismic noise tomography and magnetotellurics. Here we image the electrical resistivity structure of the Lastarria volcano, one of the most important features in the Lazufre area, using broadband magnetotelluric data at 30 locations around the volcanic edifice. Results from 3-D modeling show a conductive zone at 6 km depth south of the Lastarria volcano interpreted as a magmatic heat source, which is connected to a shallower conductive area beneath the volcanic edifice and its close vicinity. This shallow highly conductive zone fits with geochemical analysis results of thermal fluid discharges, related to fumaroles present in this area, in terms of depth extent and possible temperatures of fluids, and presents also a good correlation with seismic tomography results. The horizontal extension of this shallow conductive zone, related to the hydrothermal system of Lastarria, suggests that it has been draining one of the lagoons in the area (Laguna Azufrera), forming a sulfur rich area which can be observed at the southern side of this lagoon. Joint modeling of the hydrothermal system using magnetotellurics and seismic data is part of the current work.

  2. Controls on the chemistry and temporal variability of seafloor hydrothermal fluids

    Science.gov (United States)

    Von Damm, K. L.

    Hydrothermal activity at mid-ocean ridge spreading centers has an influence on all aspects of oceanography. The heat input from these systems affects the mid-depth circulation of the oceans, although the magnitude of this effect has not been rigorously quantified [Stommel, 1982]. The rising hydrothermal plumes also entrain deeper, and often saltier water, carrying it up in the water column thereby also affecting the thermohaline circulation of the oceans [Lupton et al., 1985]. The topography of the ridges may also influence deep circulation patterns. It is the inputs of heat and reduced chemical species from the hydrothermal systems that provide the energy for communities of chemosynthetic organisms, unknown prior to the discovery of venting. Hydrothermal activity also affects the chemistry of seawater by the direct addition and removal of various chemical species, and the more indirect scavenging of mid depth chemical constituents onto the Fe- and Mn-particles fanned in hydrothermal plumes. The composition of the oceanic crust is also changed by the addition and removal of chemical constituents as a result of hydrothermal alteration. Recycling of the oceanic crust into the Earth's mantle and the eventual transfer of some gases input by hydrothermal activity from the ocean to the atmosphere, extend the Influence of hydrothermal activity to beyond the oceans themselves. While the magnitude and importance of these linkages are still poorly quantified, we were unaware these linkages even existed prior to the discovery of seafloor hydrothermal systems.

  3. Development of micro-flow hydrothermal monitoring systems and their applications to the origin of life study on Earth.

    Science.gov (United States)

    Kawamura, Kunio

    2011-01-01

    Continuous extensive studies on thermophilic organisms have suggested that life emerged on hydrothermal systems on primitive Earth. Thus, it is well known that hydrothermal reactions are, therefore, very important to study fields deeply related to the origin-of-life study. Furthermore, the importance of hydrothermal and solvothermal systems is now realized in both fundamental and practical areas. Here, our recent investigations are described for the development of real-time and in situ monitoring systems for hydrothermal reactions. The systems were primarily developed for the origin-of-life study, but it was also applicable to fundamental and practical areas. The present techniques are based on the concept that a sample solution is injected to a narrow tubing flow reactor at high temperatures, where the sample is rapidly heated up in a very short time by exposure at to a high-temperature narrow tubing flow reactor with a very short time scale. This enables millisecond to second time-scale monitoring in real time and/or in situ at temperatures of up to 400°C. By using these techniques, a series of studies on the hydrothermal origin-of-life have been successfully carried out.

  4. Resistivity structure of the Furnas hydrothermal system (Azores archipelago, Portugal) from AMT and ERT imaging.

    Science.gov (United States)

    Byrdina, Svetlana; Vandemeulebrouck, Jean; Rath, Volker; Silva, Catarina; Hogg, Colin; Kiyan, Duygu; Viveiros, Fatima; Eleuterio, Joana; Gresse, Marceau

    2016-04-01

    The Furnas volcanic complex is located in the eastern part of the São Miguel Island and comprises a 5 km × 8 km summit depression filled by two nested calderas with several craters and a lake. Present-day volcanic activity of Furnas volcano is mostly located in the northern part of the caldera, within the Furnas village and north to Furnas Lake, where hydrothermal manifestations are mainly fumarolic fields, steam vents, thermal springs, and intense soil diffuse degassing. Considering the Furnas volcano as a whole, the total integrated CO2 efflux is extremely high, with a total amount of CO2 close to 1000 ton per day (Viveiros et al., 2009). We present the first results of an electrical resistivity tomography (ERT), combined with audio-magneto-telluric (AMT) measurements aligned along two profiles inside the caldera. The purpose of this survey is to delimit the extent, the geometry, and the depth of the hydrothermal system and to correlate the deep resistivity structure with high resolution cartography of diffuse CO2 flux (Viveiros et al, 2015). The ERT and AMT methods are complementary in terms of resolution and penetration depth: ERT can image the structural details of shallow hydrothermal system (down to 100 m in our study) while AMT can image at lower resolution deeper structures at the roots of a volcano (down to 4 km in our study). Our first independent 2D inversions of the ERT-AMT data show a good agreement between the surficial and deeper features. Below the main fumarole area we observe a low resistivity body (less than 1 Ohmm) which corresponds well to the high CO2 flux at the surface and is associated with an extended conductive body at larger depth. These results strongly suggest the presence of hydrothermal waters at depth or/and the presence of altered clay-rich material. On a larger scale however, the geometry of the conducting zones differs slightly from what was expected from earlier surface studies, and may not be directly related to fault zones

  5. Yttrium and rare earth elements in fluids from various deep-sea hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Douville, E. [Univ. Bretagne Occidentale, Brest (France). Dept. de Chimie]|[IFREMER Centre de Brest, Plouzane (France); Appriou, P. [Univ. Bretagne Occidentale, Brest (France); Bienvenu, P. [CEA Cadarache, Saint Paul Lez Durance (France). Lab. d`Analyses Radiochimiques et Chimiques; Charlou, J.L.; Donval, J.P.; Fouquet, Y. [IFREMER Centre de Brest, Plouzane (France); Gamo, Toshitaka [Univ. of Tokyo, Nakano, Tokyo (Japan). Ocean Research Inst.

    1999-03-01

    Rare earth element (REE) and yttrium (Y) concentrations were measured in fluids collected from deep-sea hydrothermal systems including the Mid-Atlantic Ridge (MAR), i.e., Menez Gwen, Lucky Strike, TAG, and Snakepit; the East Pacific Rise (EPR), i.e., 13{degree}N and 17--19{degree}S; and the Lau (Vai Lili) and Manus (Vienna Woods, PacManus, Desmos) Back-arc Basins (BAB) in the South-West Pacific. In most fluids, Y is trivalent and behaves like Ho. Chondrite normalized Y-REE (Y-REE{sub N}) concentrations of fluids from MAR, EPR, and two BAB sites, i.e., Vai Lili and Vienna Woods, showed common patterns with LREE enrichment and positive Eu anomalies. REE analysis of plagioclase collected at Lucky Strike strengthens the idea that fluid REE contents, are controlled by plagioclase phenocrysts. Other processes, however, such as REE complexation by ligands (Cl{sup {minus}}, F{sup {minus}}, So{sub 4}{sup 2{minus}}), secondary phase precipitation, and phase separation modify REE distributions in deep-sea hydrothermal fluids. REE speciation calculations suggest that aqueous REE are mainly complexed by Cl{sup {minus}} ions in hot acidic fluids from deep-sea hydrothermal systems. REE concentrations in the fluid phases are, therefore, influenced by temperature, pH, and duration of rock-fluid interaction. Unusual Y-REE{sub N} patterns found in the PacManus fluids are characterized by depleted LREE and a positive Eu anomaly. The Demos fluid sample shows a flat Y-REE{sub N} pattern, which increases regularly from LREE to HREE with no Eu anomaly. These Manus Basin fluids also have an unusual major element chemistry with relatively high Mg, So{sub 4}, H{sub 2}S, and F contents, which may be due to the incorporation of magmatic fluids into heated seawater during hydrothermal circulation. REE distribution in PacManus fluids may stem from a subseafloor barite precipitation and the REE in Demos fluids are likely influenced by the presence of sulfate ions.

  6. The eastern Tibetan Plateau geothermal belt, western China: Geology, geophysics, genesis, and hydrothermal system

    Science.gov (United States)

    Tang, Xianchun; Zhang, Jian; Pang, Zhonghe; Hu, Shengbiao; Tian, Jiao; Bao, Shujing

    2017-10-01

    The eastern Tibetan Plateau geothermal belt (ETGB), which is located in 98-102°E, 28-32°N, belongs to the eastern part of the Mediterranean-Himalayan geothermal belt. Recently, about 248 natural hot springs have been found in the ETGB. > 60% of these springs have temperatures of > 40 °C, and 11 springs have temperature above the local water boiling point. Using the helium isotopic data, gravity, magnetic and seismic data, we analyzed the thermal structure and the relationship between hydrothermal activity and geothermal dynamics of the ETGB. Results show that: (1) the 248 springs can be divided into three geothermal fields: Kangding-Luhuo geothermal field (KGF), Litang-Ganzi geothermal field (LGF) and Batang-Xiangcheng geothermal field (BGF). The BGF and LGF have hot crust and warm mantle, and are characterized by the higher heat flux (66.26 mW/m2), and higher ratios of crust-derived heat flux to total flux (47.46-60.62%). The KGF has cool crust and hot mantle, and is characterized by the higher heat flux and lower Qc/Qm; (2) there is a relatively 4-6 m higher gravimetric geoid anomaly dome which is corresponding with the ETGB. And in hydrothermal activity areas of the BGF and LGF, there is a northwest - southeast-trending tensile stress area and the upper-middle crust uplift area; (3) an abnormal layer exists in the middle-lower crust at a depth of 13-30 km beneath the ETGB, and this layer is 8-10 km thick and is characterized by lower velocity (Vp 2.5), high conductivity ( 10 Ω·m) and high temperature (850-1000 °C). Finally, based on the heat source and geological and geophysical background, we propose Kangding-type and Batang-type hydrothermal system models in the ETGB.

  7. Early Solar System hydrothermal activity in chondritic asteroids on 1-10-year timescales.

    Science.gov (United States)

    Dyl, Kathryn A; Bischoff, Addi; Ziegler, Karen; Young, Edward D; Wimmer, Karl; Bland, Phil A

    2012-11-06

    Chondritic meteorites are considered the most primitive remnants of planetesimals from the early Solar System. As undifferentiated objects, they also display widespread evidence of water-rock interaction on the parent body. Understanding this history has implications for the formation of planetary bodies, the delivery of water to the inner Solar System, and the formation of prebiotic molecules. The timescales of water-rock reactions in these early objects, however, are largely unknown. Here, we report evidence for short-lived water-rock reactions in the highly metamorphosed ordinary chondrite breccia Villalbeto de la Peña (L6). An exotic clast (d = 2cm) has coexisting variations in feldspar composition and oxygen isotope ratios that can only result from hydrothermal conditions. The profiles were modeled at T = 800 °C and P(H(2)O) = 1 bar using modified grain-boundary diffusion parameters for oxygen self-diffusion and reaction rates of NaSiCa(-1)Al(-1) exchange in a fumarole. The geochemical data are consistent with hydrothermal activity on the parent body lasting only 1-10 y. This result has wide-ranging implications for the geological history of chondritic asteroids.

  8. Early Solar System hydrothermal activity in chondritic asteroids on 1–10-year timescales

    Science.gov (United States)

    Dyl, Kathryn A.; Bischoff, Addi; Ziegler, Karen; Young, Edward D.; Wimmer, Karl; Bland, Phil A.

    2012-01-01

    Chondritic meteorites are considered the most primitive remnants of planetesimals from the early Solar System. As undifferentiated objects, they also display widespread evidence of water–rock interaction on the parent body. Understanding this history has implications for the formation of planetary bodies, the delivery of water to the inner Solar System, and the formation of prebiotic molecules. The timescales of water–rock reactions in these early objects, however, are largely unknown. Here, we report evidence for short-lived water–rock reactions in the highly metamorphosed ordinary chondrite breccia Villalbeto de la Peña (L6). An exotic clast (d = 2cm) has coexisting variations in feldspar composition and oxygen isotope ratios that can only result from hydrothermal conditions. The profiles were modeled at T = 800 °C and P(H2O) = 1 bar using modified grain-boundary diffusion parameters for oxygen self-diffusion and reaction rates of NaSiCa-1Al-1 exchange in a fumarole. The geochemical data are consistent with hydrothermal activity on the parent body lasting only 1–10 y. This result has wide-ranging implications for the geological history of chondritic asteroids. PMID:23093668

  9. Evolution of the Vesuvius magmatic-hydrothermal system before the 16 December 1631 eruption

    Science.gov (United States)

    Principe, Claudia; Marini, Luigi

    2008-04-01

    In a recently published manuscript [Guidoboni, E., Boschi, E., 2006. Vesuvius before the 1631 eruption, EOS, 87(40), 417 and 423]; [Guidoboni, E. (Ed.), 2006. Pirro Ligorio, Libro di diversi terremoti (1571), volume 28, codex Ja II 15, Archivio di Stato di Torino, Edizione Nazionale delle Opere di Pirro Ligorio, Roma, De Luca, 261 pp], Pirro Ligorio gives a detailed description of the phenomena occurring in the crater area of Vesuvius volcano, in 1570-1571 and previous years. Here, these phenomena are interpreted as the first clearly documented signals of unrest of this volcanic system caused by the shallow emplacement of a magma batch and leading to the 1631 eruption. Our interpretation is mainly based on the present understanding of the fluid geochemistry of magmatic-hydrothermal systems. In this way, it is possible to conclude that: (i) incandescent rocks were present at the surface, with temperatures > 500 °C approximately and (ii) either a magmatic-dominated or a magmatic-hydrothermal-type of conceptual geochemical model applies to Vesuvius in 1570-1571 and preceding years. The Ligorio's picture represents the first clear evidence that the magma involved in the 1631 eruption was present under the volcano more than sixty years before the eruption. Moreover, its emplacement produced a series of phenomena which were clearly observed although not understood at that time. A similar phenomenological pattern should be easily detected and correctly interpreted at present or in the future.

  10. Response of Hydrothermal System to Stress Transients at Lassen Volcanic Center, California inferred from Seismic Interferometry with Ambient Noise

    Science.gov (United States)

    Taira, T.; Brenguier, F.

    2016-12-01

    Time-lapse monitoring of seismic velocity at volcanic areas can provide unique insight into the property of hydrothermal and magmatic fluids and their temporal variability. We established a quasi real-time velocity monitoring system by using seismic interferometry with ambient noise to explore the temporal evolution of velocity in the Lassen Volcanic Center, northern California. Our monitoring system finds temporal variability of seismic velocity in response to stress changes imparted by an earthquake and by seasonal environmental changes. Dynamic stress changes from a magnitude 5.7 local earthquake induced a 0.1% velocity reduction at a depth of about 1 km. The seismic velocity susceptibility defined as ratio of seismic velocity change to dynamic stress change is estimated to be about 0.006 MPa-1, which suggests the Lassen hydrothermal system is marked by high-pressurized hydrothermal fluid. By combining geodetic measurements, our observation shows that the long-term seismic velocity fluctuation closely tracks snow-induced vertical deformation without time delay, which is most consistent with an hydrologic load model (either elastic or poroelastic response) in which surface loading drives hydrothermal fluid diffusion that leads to an increase of opening of cracks and subsequently reductions of seismic velocity. We infer that heated-hydrothermal fluid in a vapor-dominated zone at a depth of 2-4 km range is responsible for the long-term variation in seismic velocity.

  11. Hydrothermal ore-forming processes in the light of studies in rock- buffered systems: II. Some general geologic applications

    Science.gov (United States)

    Hemley, J.J.; Hunt, J.P.

    1992-01-01

    The experimental metal solubilities for rock-buffered hydrothermal systems provide important insights into the acquisition, transport, and deposition of metals in real hydrothermal systems that produced base metal ore deposits. Water-rock reactions that determine pH, together with total chloride and changes in temperature and fluid pressure, play significant roles in controlling the solubility of metals and determining where metals are fixed to form ore deposits. Deposition of metals in hydrothermal systems occurs where changes such as cooling, pH increase due to rock alteration, boiling, or fluid mixing cause the aqueous metal concentration to exceed saturation. Metal zoning results from deposition occurring at successive saturation surfaces. Zoning is not a reflection simply of relative solubility but of the manner of intersection of transport concentration paths with those surfaces. Saturation surfaces will tend to migrate outward and inward in prograde and retrograde time, respectively, controlled by either temperature or chemical variables. -from Authors

  12. Microbial heterotrophy coupled to Fe-S-As cycling in a shallow-sea hydrothermal system

    Science.gov (United States)

    Lu, G.; Amend, J.

    2013-12-01

    To date, there are only a few known heterotrophic arsenite oxidizers and arsenate reducers. They utilize organic compounds as their carbon source and/or as important electron donors in the transfer arsenic in high temperature environments. Arsenic in hydrothermal vent systems can be immobilized at low temperatures through (ad)sorption on iron oxide and other iron-bearing minerals. Interactions with sulfur species can also affect the redox state of arsenic species. A better understanding of microbially-catalyzed reactions involving carbon, arsenic, iron and sulfur would provide constraints on the mobility of arsenic in a wide variety of natural and engineered systems. The aim of this study is to establish links between microbial distribution and in situ Fe-S-As cycling processes in a shallow-sea hydrothermal vent system. We investigated three shallow-sea hydrothermal vents, Champagne Hot Spring (CHS), Soufriere Spring (SOU) and Portsmouth Spring (PM), located off the western coast of Dominica, Lesser Antilles. CHS and SOU are characterized by moderate temperatures (46oC and 55oC, respectively), and PM is substantially hotter (~90-111 oC). Two sediment cores (one close to and one far from the thermal source) were collected from CHS and from SOU. Porewaters in both background cores had low concentrations of arsenic (mostly As3+, to a lesser extent As5+, DMA, MMA) and ferrous iron. The arsenic concentrations (predominantly As3+) in the CHS high temperature core were 30-90 nM, tracking with dissolved iron. Similar to CHS, the arsenic concentration in the SOU high temperature core was dominated by As3+ and controlled by ferrous iron. However, the arsenic concentration at SOU is comparatively higher, up to 1.9 mM. At the hotter and deeper PM site, highly elevated arsenic levels (1-2.5 mM) were measured, values that are among the highest arsenic concentrations ever reported in a marine hydrothermal system. Several autotrophic and heterotrophic media at two pHs (5.5 and 8

  13. Review of Prior U.S. Attribute Measurement Systems

    Energy Technology Data Exchange (ETDEWEB)

    White, G K

    2012-07-06

    Attribute Measurement Systems have been developed and demonstrated several times in the United States over the last decade or so; under the Trilateral Initiative (1996-2002), FMTTD (Fissile Material Transparency Technology Demonstration, 2000), and NG-AMS (Next Generation Attribute Measurement System, 2005-2008). Each Attribute Measurement System has contributed to the growing body of knowledge regarding the use of such systems in warhead dismantlement and other Arms Control scenarios. The Trilateral Initiative, besides developing prototype hardware/software, introduced the topic to the international community. The 'trilateral' parties included the United States, the Russian Federation, and the International Atomic Energy Agency (IAEA). With the participation of a Russian delegation, the FMTTD demonstrated that measurements behind an information barrier are feasible while meeting host party security requirements. The NG-AMS system explored the consequences of maximizing the use of Commercial off the Shelf (COTS) equipment, which made construction easier, but authentication harder. The 3rd Generation Attribute Measurement System (3G-AMS) will further the scope of previous systems by including additional attributes and more rigor in authentication.

  14. Volcano electrical tomography unveils edifice collapse hazard linked to hydrothermal system structure and dynamics.

    Science.gov (United States)

    Rosas-Carbajal, Marina; Komorowski, Jean-Christophe; Nicollin, Florence; Gibert, Dominique

    2016-07-26

    Catastrophic collapses of the flanks of stratovolcanoes constitute a major hazard threatening numerous lives in many countries. Although many such collapses occurred following the ascent of magma to the surface, many are not associated with magmatic reawakening but are triggered by a combination of forcing agents such as pore-fluid pressurization and/or mechanical weakening of the volcanic edifice often located above a low-strength detachment plane. The volume of altered rock available for collapse, the dynamics of the hydrothermal fluid reservoir and the geometry of incipient collapse failure planes are key parameters for edifice stability analysis and modelling that remain essentially hidden to current volcano monitoring techniques. Here we derive a high-resolution, three-dimensional electrical conductivity model of the La Soufrière de Guadeloupe volcano from extensive electrical tomography data. We identify several highly conductive regions in the lava dome that are associated to fluid saturated host-rock and preferential flow of highly acid hot fluids within the dome. We interpret this model together with the existing wealth of geological and geochemical data on the volcano to demonstrate the influence of the hydrothermal system dynamics on the hazards associated to collapse-prone altered volcanic edifices.

  15. Debris flow evolution and the activation of an explosive hydrothermal system; Te Maari, Tongariro, New Zealand

    Science.gov (United States)

    Procter, J. N.; Cronin, S. J.; Zernack, A. V.; Lube, G.; Stewart, R. B.; Nemeth, K.; Keys, H.

    2014-10-01

    Analysis of the pre- and post-eruption topography, together with observations of the avalanche deposition sequence, yields a triggering mechanism for the 6 August 2012 eruption of Upper Te Maari. The avalanche was composed of a wedge of c. 683 000-774 000 m3 of coarse breccia, spatter and clay-rich tuffs and diamictons which slid from the western flanks of the Upper Te Maari Crater, the failure plane is considered to be a hydrothermally altered clay layer. This landslide led to a pressure drop of up to 0.5 MPa, enough to generate an explosive eruption from the hydrothermal system below, which had been activated over the months earlier by additional heat and gas from a shallow intrusion. The landslide transformed after c. 700 m into a clay-rich cohesive debris flow, eroding soils from steep, narrow stretches of channel, before depositing on intermediate broad flatter reaches. After each erosive reach, the debris flow contained greater clay and mud contents and became more mobile. At c. 2 km flow distance, however, the unsaturated flow stopped, due to a lack of excess pore pressure. This volume controlled flow deposited thick, steep sided lobes behind an outer levee, accreting inward and upward to form a series of curved surface ridges.

  16. An effective method and pathways of acrylonitrile degradation to acrylic acid through an alkaline hydrothermal system.

    Science.gov (United States)

    Dong, Wenjie; Peng, Boyu; Wang, Ke; Miao, Jia; Zhang, Wei; Zhang, Yalei; Shen, Zheng

    2017-07-01

    Degradation of pollution for specific chemicals represents an optimal approach to high-strength wastewater treatment. One-pot selective conversion of acrylonitrile to acrylic acid in a hydrothermal system with NaOH as a catalyst was carried out. The influence factors were evaluated, including initial acrylonitrile concentration, reaction temperature, reaction time and amount of alkali. Experimental results showed that the highest yield of acrylic acid (55%) was obtained at the initial acrylonitrile concentration of 3 × 10(3) mg/L, 300°C for 90 s with 1.0 M NaOH. To determine the reaction path, intermediates analysis and calculation of carbon and nitrogen balance were carried out by means of HPLC, GC and TOC/TN methods. Two probable reaction pathways were proposed as follows: (1) Acrylonitrile was hydrolyzed into acrylamide, and acrylic acid was obtained via further hydrolysis. (2) Acrylonitrile was converted into 3-hydroxy-propionitrile via additive reaction, and this product was readily converted to 3-hydroxy-propionic acid through two steps of hydrolysis, followed by dehydration reaction to produce acrylic acid. This study offered not only an efficient method to transfer highly toxic pollutants into valuable chemical, but also a better understanding of hydrothermal alkali catalytic reaction.

  17. 76 FR 75809 - Prior Label Approval System: Generic Label Approval

    Science.gov (United States)

    2011-12-05

    ... Analysis and Critical Control Point (HACCP) Systems (9 CFR 417.5). For example, establishments are required to maintain copies of their HACCP plan, hazard analysis, records documenting the monitoring of... similar to HACCP and Sanitation Standard Operating Procedure (SOP) records because establishments are...

  18. Diffuse flow hydrothermal manganese mineralization along the active Mariana and southern Izu-Bonin arc system, western Pacific

    Science.gov (United States)

    Hein, J.R.; Schulz, M.S.; Dunham, R.E.; Stern, R.J.; Bloomer, S.H.

    2008-01-01

    Abundant ferromanganese oxides were collected along 1200 km of the active Izu-Bonin-Mariana arc system. Chemical compositions and mineralogy show that samples were collected from two deposit types: Fe-Mn crusts of mixed hydrogenetic/hydrothermal origin and hydrothermal Mn oxide deposits; this paper addresses only the second type. Mn oxides cement volcaniclastic and biogenic sandstone and breccia layers (Mn sandstone) and form discrete dense stratabound layers along bedding planes and within beds (stratabound Mn). The Mn oxide was deposited within coarse-grained sediments from diffuse flow systems where precipitation occurred below the seafloor. Deposits were exposed at the seabed by faulting, mass wasting, and erosion. Scanning electron microscopy and microprobe analyses indicate the presence of both amorphous and crystalline 10 ?? and 7 ?? manganate minerals, the fundamental chemical difference being high water contents in the amorphous Mn oxides. Alternation of amorphous and crystalline laminae occurs in many samples, which likely resulted from initial rapid precipitation of amorphous Mn oxides from waxing pulses of hydrothermal fluids followed by precipitation of slow forming crystallites during waning stages. The chemical composition is characteristic of a hydrothermal origin including strong fractionation between Fe (mean 0.9 wt %) and Mn (mean 48 wt %) for the stratabound Mn, generally low trace metal contents, and very low rare earth element and platinum group element contents. However, Mo, Cd, Zn, Cu, Ni, and Co occur in high concentrations in some samples and may be good indicator elements for proximity to the heat source or to massive sulfide deposits. For the Mn sandstones, Fe (mean-8.4%) and Mn (12.4%) are not significantly fractionated because of high Fe contents in the volcaniclastic material. However, the proportion of hydrothermal Fe (nondetrital Fe) to total Fe is remarkably constant (49-58%) for all the sample groups, regardless of the degree of

  19. Cu-As Decoupling in Hydrothermal Systems: A Link Between Pyrite Chemistry and Fluid Composition

    Science.gov (United States)

    Reich, M.; Tardani, D.; Deditius, A.; Chryssoulis, S.; Wrage, J.; Sanchez-Alfaro, P.; Andrea, H.; Cinthia, J.

    2016-12-01

    Chemical zonations in pyrite have been recognized in most hydrothermal ore deposit types, showing in some cases marked oscillatory alternation of metals and metalloids in pyrite growth zones (e.g., of Cu-rich, As-(Au)-depleted zones and As-(Au)-rich, Cu-depleted zones). This decoupled geochemical behavior of Cu and As has been interpreted as a result of chemical changes in ore-forming fluids, although direct evidence connecting fluctuations in hydrothermal fluid composition with metal partitioning into pyrite growth zones is still lacking. Here we report a comprehensive trace element database of pyrite from an active hydrothermal system, the Tolhuaca Geothermal System (TGS) in southern Chile. We combined high-spatial resolution and X-ray mapping capabilities of electron microprobe analysis (EMPA) with low detection limits and depth-profiling capabilities of secondary-ion mass spectrometry (SIMS) in a suite of pyrite samples retrieved from a 1 km drill hole that crosses the argillic and propylitic alteration zones of the geothermal system. We show that the concentrations of precious metals (e.g., Au, Ag), metalloids (e.g., As, Sb, Se, Te), and base and heavy metals (e.g., Cu, Co, Ni, Pb) in pyrite at the TGS are significant. Among the elements analyzed, arsenic, Cu and Co are the most abundant with concentrations that vary from sub-ppm levels to a few wt. %. Pyrites from the deeper propylitic zone do not show significant zonation and high Cu-(Co)-As concentrations correlate with each other. In contrast, well-developed zonations were detected in pyrite from the shallow argillic alteration zone, where Cu(Co)-rich, As-depleted cores alternate with Cu(Co)-depleted, As-rich rims. These microanalytical data were contrasted with chemical data of fluid inclusion in quartz veins (high Cu/Na and low As/Na) and borehole fluids (low Cu/Na and high As/Na) reported at the TGS, showing a clear correspondence between Cu and As concentrations in pyrite-forming fluids and chemical

  20. Nitrogen cycling in Ophiolite-hosted and Fault-associated Hydrothermal Systems; Spacial and Temporal Variations

    Science.gov (United States)

    Meyer-Dombard, D. R.; Gulecal, Y.; Loiacono, S. T.; Cardace, D.; Uzunlar, N.; Temel, M.

    2011-12-01

    Gene-targeted analyses have revealed that microbial communities in hydrothermal environments can be surprisingly diverse. However, we know shockingly little about basic ecological functions such as carbon and nitrogen cycling, or community shifts over time or with seasons. Previous work has shown that nitrogen cycling in a Yellowstone National Park hot spring, "Bison Pool", and its associated runoff channel functions as a complex system. Analysis of nitrogen isotopes and sequencing of metagenomes from multiple locations at "Bison Pool" revealed that nitrogen fixation and denitrification varies across the chemosynthetic/photosynthetic ecotone [1-3], and high temperature activity of nifH genes has been shown for another nearby feature [4]. Other recent studies have explored the diversity of nifH and archaeal amoA genes in various terrestrial hydrothermal systems [5-8]. Despite these advances, we are still ignorant of changes in N-cycling over time in the same sample location, and in particular during seasonal climate changes. Further, the role of N-cycling in deeply-sourced fluids associated with ophiolites, which represent deep biosphere processes, is unknown. This study will compare evidence of N-cycling in terrestrial hydrothermal and ophiolite-hosted springs, focusing on the role of microbes as environmental conditions vary over space and time. Here, we explore the diversity of nifH [nitrogen fixation], amoA [ammonia oxidation], narG, nirKS, and nosZ [denitrification] genes in a variety of hydrothermal environments in Yellowstone and Turkey, representing fault-associated and deeply-sourced fluids. Environmental nucleic acids were extracted, and PCR-directed screens reveal the presence or absence of functional genes, indicating genetic capacity for N-cycling. We have examined the transition of genetic diversity and genetic capacity within sediments and biofilms at the chemosynthetic/photosynthetic ecotone in several hot springs spanning ranges of pH and

  1. Exopolysaccharides isolated from hydrothermal vent bacteria can modulate the complement system.

    Science.gov (United States)

    Courtois, Anthony; Berthou, Christian; Guézennec, Jean; Boisset, Claire; Bordron, Anne

    2014-01-01

    The complement system is involved in the defence against bacterial infection, or in the elimination of tumour cells. However, disturbances in this system contributes to the pathogenesis of various inflammatory diseases. The efficiency of therapeutic anti-tumour antibodies is enhanced when the complement system is stimulated. In contrast, cancer cells are able to inhibit the complement system and thus proliferate. Some marine molecules are currently being developed as new drugs for use in humans. Among them, known exopolyssacharides (EPSs) generally originate from fungi, but few studies have been performed on bacterial EPSs and even fewer on EPSs extracted from deep-sea hydrothermal vent microbes. For use in humans, these high molecular weight EPSs must be depolymerised. Furthermore, the over-sulphation of EPSs can modify their biological activity. The aim of this study was to investigate the immunodulation of the complement system by either native or over-sulphated low molecular weight EPSs isolated from vent bacteria in order to find pro or anti-activators of complement.

  2. Evidence of a modern deep water magmatic hydrothermal system in the Canary Basin (eastern central Atlantic Ocean)

    Science.gov (United States)

    Medialdea, T.; Somoza, L.; González, F. J.; Vázquez, J. T.; de Ignacio, C.; Sumino, H.; Sánchez-Guillamón, O.; Orihashi, Y.; León, R.; Palomino, D.

    2017-08-01

    New seismic profiles, bathymetric data, and sediment-rock sampling document for the first time the discovery of hydrothermal vent complexes and volcanic cones at 4800-5200 m depth related to recent volcanic and intrusive activity in an unexplored area of the Canary Basin (Eastern Atlantic Ocean, 500 km west of the Canary Islands). A complex of sill intrusions is imaged on seismic profiles showing saucer-shaped, parallel, or inclined geometries. Three main types of structures are related to these intrusions. Type I consists of cone-shaped depressions developed above inclined sills interpreted as hydrothermal vents. Type II is the most abundant and is represented by isolated or clustered hydrothermal domes bounded by faults rooted at the tips of saucer-shaped sills. Domes are interpreted as seabed expressions of reservoirs of CH4 and CO2-rich fluids formed by degassing and contact metamorphism of organic-rich sediments around sill intrusions. Type III are hydrothermal-volcanic complexes originated above stratified or branched inclined sills connected by a chimney to the seabed volcanic edifice. Parallel sills sourced from the magmatic chimney formed also domes surrounding the volcanic cones. Core and dredges revealed that these volcanoes, which must be among the deepest in the world, are constituted by OIB-type, basanites with an outer ring of blue-green hydrothermal Al-rich smectite muds. Magmatic activity is dated, based on lava samples, at 0.78 ± 0.05 and 1.61 ± 0.09 Ma (K/Ar methods) and on tephra layers within cores at 25-237 ky. The Subvent hydrothermal-volcanic complex constitutes the first modern system reported in deep water oceanic basins related to intraplate hotspot activity.Plain Language SummarySubmarine volcanism and associated hydrothermal systems are relevant processes for the evolution of the ocean basins, due their impact on the geochemistry of the oceans, their potential to form significant ore deposits, and their implications for global climate

  3. Revisiting the Euganean Geothermal System (NE Italy) - insights from large scale hydrothermal modelling

    Science.gov (United States)

    Pola, Marco; Cacace, Mauro; Fabbri, Paolo; Piccinini, Leonardo; Zampieri, Dario; Dalla Libera, Nico

    2017-04-01

    As one of the largest and most extensive utilized geothermal system in northern Italy, the Euganean Geothermal System (EGS, Veneto region, NE Italy) has long been the subject of still ongoing studies. Hydrothermal waters feeding the system are of meteoric origin and infiltrate in the Veneto Prealps, to the north of the main geothermal area. The waters circulate for approximately 100 km in the subsurface of the central Veneto, outflowing with temperatures from 65°C to 86°C to the southwest near the cities of Abano Terme and Montegrotto Terme. The naturally emerging waters are mainly used for balneotherapeutic purposes, forming the famous Euganean spa district. This preferential outflow is thought to have a relevant structural component producing a high secondary permeability localized within an area of limited extent (approx. 25 km2). This peculiar structure is associated with a local network of fractures resulting from transtentional tectonics of the regional Schio-Vicenza fault system (SVFS) bounding the Euganean Geothermal Field (EGF). In the present study, a revised conceptual hydrothermal model for the EGS based on the regional hydrogeology and structural geology is proposed. Particularly, this work aims to quantify: (1) the role of the regional SVFS, and (2) the impact of the high density local fractures mesh beneath the EGF on the regional-to-local groundwater flow circulation at depths and its thermal configuration. 3D coupled flow and heat transport numerical simulations inspired by the newly developed conceptual model are carried out to properly quantify the results from these interactions. Consistently with the observations, the obtained results provide indication for temperatures in the EGF reservoir being higher than in the surrounding areas, despite a uniform basal regional crustal heat inflow. In addition, they point to the presence of a structural causative process for the localized outflow, in which deep-seated groundwater is preferentially

  4. Indium: Understanding its Behavior in Magmatic-Hydrothermal Systems Today to Meet Tomorrow's Demand

    Science.gov (United States)

    Piccoli, P. M.; Kayser, S.; Candela, P. A.

    2014-12-01

    Indium is integral to modern electronic devices, and is an essential component in indium-tin oxide (ITO), an electrically conductive, and optically transparent material that forms the basis for touch screens and high-end LCDs. World-wide production of indium has increased almost seven-fold from 1990 to 2012. Continued increases in production can be aided by better models for the formation of indium-bearing ores, yet little is known about the behavior of indium in magmatic-hydrothermal systems. As a first step toward solving this problem, we performed experiments to evaluate the partitioning of indium between pyrrhotite (po) and silicate melt (m). Experiments were performed at 800 °C, 100 MPa, and fO2 ≈ NNO in a po-saturated, vapor-brine-rhyolite melt system for durations of 5 to15 days. Three separate series of experiments were conducted in which each series differed by the aqueous solution added. The first series of experiments were prepared with pure water, the second series of experiments with a 1.01 M chloride solution and the third series with a 0.35 M CuCl2-bearing starting aqueous solution. These changes in starting material produced changes in the composition of the run product po and glass. The partition coefficient D(po/m) for the pure-water series experiments is on the order of ≈ 10. The addition of chloride-bearing aqueous solution leads to a decrease in the partition coefficient to ≈ 1.5. The copper-bearing experiments yield a D ≈ 3. The lower values for D in the chloride-bearing experiments may be explained by indium-chloride interactions in the melt phase. Although the D does vary depending upon the composition of the starting aqueous solution, an order of magnitude estimate for D, for general modeling purposes, can be made by assuming a value of 4. By using reasonable estimates of the mass fraction of po that crystallizes in crustal magmatic systems, the proportion of indium sequestered by po, during fractional crystallization, can be

  5. Comparative assessment of five potential sites for hydrothermal magma systems: geochemistry

    Energy Technology Data Exchange (ETDEWEB)

    White, A.F.

    1980-08-01

    A brief discussion is given of the geochemical objectives and questions that must be addressed in such an evaluation. A summary of the currently published literature that is pertinent in answering these questions is presented for each of the five areas: The Geysers-Clear Lake region, Long Valley, Rio Grand Rift, Roosevelt Hot Springs, and the Salton Trough. The major geochemical processes associated with proposed hydrothermal sites are categorized into three groups for presentation: geochemistry of magma and associated volcanic rocks, geochemistry of hydrothermal solutions, and geochemistry of hydrothermal alteration. (MHR)

  6. The Ultramafic-Hosted Lost City Hydrothermal Field: Clues in the Search for Life Elsewhere in the Solar System?

    Science.gov (United States)

    Kelley, D. S.; Baross, J. A.; Frueh-Green, G. L.; Schrenk, M. O.; Karson, J. A.

    2002-12-01

    The recent discovery of the peridotite-hosted Lost City Hydrothermal Field (LCHF) raises the possibility that such systems are prevalent not only on Earth, but that similar systems may have existed, or currently exist, elsewhere in the solar system. The LCHF, which rests atop the Atlantis massif at 30N on the Mid-Atlantic Ridge, is unlike any previously known hydrothermal field: 1) it is located on 1.5 my-old crust, nearly 15 km west of the spreading axis; 2) it hosts at least 30 active and inactive carbonate-brucite chimneys that tower up to 60 m above the seafloor; 3) the venting pinnacles appear to be the surface expression of warm (40-75C), high pH (9-10) fluids emanating from fault zones that tap a region of active serpentinization in the underlying peridotites; and 5) hydrothermal flow is facilitated by exothermic serpentinization reactions at depth. The diffusely venting fluids support dense and diverse communities of mesophilic to hyperthermophilic organisms that may include sulfur-, methane- and hydrogen-oxidizers. The Lost City Field may represent our closest analogue to hydrothermal systems operative during early Earth where ultramafic rocks were predominant. The reducing conditions associated with serpentinization of ultramafic material may be similar to those present in the Hadean ocean (4.5-3.9 Gyr) and it has been suggested that such high-pH systems were a requirement for the emergence of life on the seafloor. Model calculations based on thermodynamic considerations and experimental studies suggest that synthesis of numerous organic compounds is favored during mixing of warm, serpentinite-derived, high-pH, reducing fluids with cool, oxygenated seawater. Dissolved hydrogen, present in hydrothermal fluids due to reaction of olivine and other iron-bearing minerals with fluids, provides the reduction potential and the thermodynamic drive for organic synthesis. Significant quantities of methane and hydrogen produced during serpentinization reactions form

  7. An enhanced artificial bee colony algorithm (EABC for solving dispatching of hydro-thermal system (DHTS problem.

    Directory of Open Access Journals (Sweden)

    Yi Yu

    Full Text Available The dispatching of hydro-thermal system is a nonlinear programming problem with multiple constraints and high dimensions and the solution techniques of the model have been a hotspot in research. Based on the advantage of that the artificial bee colony algorithm (ABC can efficiently solve the high-dimensional problem, an improved artificial bee colony algorithm has been proposed to solve DHTS problem in this paper. The improvements of the proposed algorithm include two aspects. On one hand, local search can be guided in efficiency by the information of the global optimal solution and its gradient in each generation. The global optimal solution improves the search efficiency of the algorithm but loses diversity, while the gradient can weaken the loss of diversity caused by the global optimal solution. On the other hand, inspired by genetic algorithm, the nectar resource which has not been updated in limit generation is transformed to a new one by using selection, crossover and mutation, which can ensure individual diversity and make full use of prior information for improving the global search ability of the algorithm. The two improvements of ABC algorithm are proved to be effective via a classical numeral example at last. Among which the genetic operator for the promotion of the ABC algorithm's performance is significant. The results are also compared with those of other state-of-the-art algorithms, the enhanced ABC algorithm has general advantages in minimum cost, average cost and maximum cost which shows its usability and effectiveness. The achievements in this paper provide a new method for solving the DHTS problems, and also offer a novel reference for the improvement of mechanism and the application of algorithms.

  8. An enhanced artificial bee colony algorithm (EABC) for solving dispatching of hydro-thermal system (DHTS) problem.

    Science.gov (United States)

    Yu, Yi; Wu, Yonggang; Hu, Binqi; Liu, Xinglong

    2018-01-01

    The dispatching of hydro-thermal system is a nonlinear programming problem with multiple constraints and high dimensions and the solution techniques of the model have been a hotspot in research. Based on the advantage of that the artificial bee colony algorithm (ABC) can efficiently solve the high-dimensional problem, an improved artificial bee colony algorithm has been proposed to solve DHTS problem in this paper. The improvements of the proposed algorithm include two aspects. On one hand, local search can be guided in efficiency by the information of the global optimal solution and its gradient in each generation. The global optimal solution improves the search efficiency of the algorithm but loses diversity, while the gradient can weaken the loss of diversity caused by the global optimal solution. On the other hand, inspired by genetic algorithm, the nectar resource which has not been updated in limit generation is transformed to a new one by using selection, crossover and mutation, which can ensure individual diversity and make full use of prior information for improving the global search ability of the algorithm. The two improvements of ABC algorithm are proved to be effective via a classical numeral example at last. Among which the genetic operator for the promotion of the ABC algorithm's performance is significant. The results are also compared with those of other state-of-the-art algorithms, the enhanced ABC algorithm has general advantages in minimum cost, average cost and maximum cost which shows its usability and effectiveness. The achievements in this paper provide a new method for solving the DHTS problems, and also offer a novel reference for the improvement of mechanism and the application of algorithms.

  9. Neuro-Fuzzy Computational Technique to Control Load Frequency in Hydro-Thermal Interconnected Power System

    Science.gov (United States)

    Prakash, S.; Sinha, S. K.

    2015-09-01

    In this research work, two areas hydro-thermal power system connected through tie-lines is considered. The perturbation of frequencies at the areas and resulting tie line power flows arise due to unpredictable load variations that cause mismatch between the generated and demanded powers. Due to rising and falling power demand, the real and reactive power balance is harmed; hence frequency and voltage get deviated from nominal value. This necessitates designing of an accurate and fast controller to maintain the system parameters at nominal value. The main purpose of system generation control is to balance the system generation against the load and losses so that the desired frequency and power interchange between neighboring systems are maintained. The intelligent controllers like fuzzy logic, artificial neural network (ANN) and hybrid fuzzy neural network approaches are used for automatic generation control for the two area interconnected power systems. Area 1 consists of thermal reheat power plant whereas area 2 consists of hydro power plant with electric governor. Performance evaluation is carried out by using intelligent (ANFIS, ANN and fuzzy) control and conventional PI and PID control approaches. To enhance the performance of controller sliding surface i.e. variable structure control is included. The model of interconnected power system has been developed with all five types of said controllers and simulated using MATLAB/SIMULINK package. The performance of the intelligent controllers has been compared with the conventional PI and PID controllers for the interconnected power system. A comparison of ANFIS, ANN, Fuzzy and PI, PID based approaches shows the superiority of proposed ANFIS over ANN, fuzzy and PI, PID. Thus the hybrid fuzzy neural network controller has better dynamic response i.e., quick in operation, reduced error magnitude and minimized frequency transients.

  10. Fluid geochemistry of the Mondragone hydrothermal systems (southern Italy): water and gas compositions vs. geostructural setting

    Science.gov (United States)

    Cuoco, Emilio; Minissale, Angelo; Di Leo, Antonella "Magda"; Tamburrino, Stella; Iorio, Marina; Tedesco, Dario

    2017-10-01

    The geochemistry of natural thermal fluids discharging in the Mondragone Plain has been investigated. Thermal spring emergences are located along the Tyrrhenian coast in two different areas: near Padule-S. Rocco (41°7.5'N 13°53.4'E) at the foot of Mt. Petrino, and near Levagnole (41°8.5'N 13°51.3'E) at the foot of Mt. Pizzuto. The water isotopic composition of both thermal discharges is lighter than the one of local shallow groundwater (δ18O ≅ -6.3‰ SMOW vs. ≅ -5.9‰; δD ≅ -40‰ SMOW vs. ≅ -36‰, respectively) as a consequence of inland higher altitude of recharge by rainfall, suggesting that thermal water undergoes a deep and long flow-path before emerging along the coast. The chemical composition of the highest temperature samples of two areas points that fluids in the hydrothermal reservoir(s) interact with similar lithologies, since they are both hosted in the lower sedimentary carbonate formations of the Campanian-Latial Apennine succession. However, the two spring systems are different in terms of temperature and salinity (Levagnole: ≅50 °C and 8.9 g/L vs. Padule: ≅32 °C and 7.4 g/L, respectively). The higher salinity of Levagnole springs is due to a longer interaction with evaporite material embedded in Miocene sedimentary formations and to the eventual mixing, during rising, with fresh seawater close to the seashore. The chemical and isotopic composition of the free gases associated with the springs, again suggests a different source of the two hydrothermal systems. Comparing the 3He/4He measured ratios with other gas emissions located NE and SE of Mt. Massico-Roccamonfina alignment, it is evident that the Levagnole thermal springs are related to the northern Latial mantle wedge where the 3He/4He is about 0.5 R/Ra, whereas the Padule-S. Rocco springs, although being only 3.5 km south of Levagnole, are related to the Campanian mantle wedge where R/Ra is always ≥2.0. Such a difference in 3He/4He ratio in a very short distance

  11. Production of fuel range oxygenates by supercritical hydrothermal liquefaction of lignocellulosic model systems

    DEFF Research Database (Denmark)

    Pedersen, Thomas Helmer; Rosendahl, Lasse Aistrup

    2015-01-01

    Lignocellulosic model compounds and aspen wood are processed at supercritical hydrothermal conditions to study and understand feedstock impact on biocrude formation and characteristics. Glucose and xylose demonstrate similar yield of biocrude and biochar, similar biocrude characteristics, and it ......Lignocellulosic model compounds and aspen wood are processed at supercritical hydrothermal conditions to study and understand feedstock impact on biocrude formation and characteristics. Glucose and xylose demonstrate similar yield of biocrude and biochar, similar biocrude characteristics...

  12. A comparative mineralogical study of Te-rich magmatic-hydrothermal systems in northeastern Greece

    Science.gov (United States)

    Voudouris, P.

    2006-07-01

    Several magmatic-hydrothermal systems in northeastern Greece (western Thrace and Limnos Island) are highly enriched in tellurides which, in addition to native gold and electrum, represent major carriers of precious metals in the ore. Deposition near the porphyry-epithermal transition for several systems is indicated by field relations and by the presence of key minerals (Pb- and Ag-rich tellurides, Bi-sulfosalts and Bi-tellurides/tellurosulfides). Hessite, stützite, sylvanite, petzite, coloradoite, altaite, unnamed Ag-sulfotelluride, native tellurium and electrum are abundant in intermediate sulfidation quartz-carbonate veins together with zincian tetrahedrite-group minerals, chalcopyrite and galena. The presence of hessite, goldfieldite, native gold and enargite or famatinite suggests deposition at a high sulfidation state. The main stage of telluride deposition took place at ˜275 °C at log fTe2 values of -8.5 to -7.1 and log fS2 values of -10.8 to -9.0, based on the Fe-content in sphalerite and the sulfide-telluride mineralogy. The close spatial association of telluride mineralization with intrusive centers of intermediate composition, the base metal enrichment and the trace element signature involving Au, Ag, Te, Bi, Sn and Mo suggest that ore-forming components were introduced at the porphyry-epithermal transition. Potential sources of tellurium are the high-K calc-alkaline (western Thrace) to shoshonitic (Limnos) intrusive rocks.

  13. Structural Architecture of the Hydrothermal System from Geophysical Data in Hammam Bouhadjar Area (Northwest of Algeria)

    Science.gov (United States)

    Bouyahiaoui, Boualem; Abtout, Abdeslam; Hamai, Lamine; Boukerbout, Hassina; Djellit, Hamou; Bougchiche, Said Sofiane; Bendali, Mohamed; Bouabdallah, Hamza

    2017-03-01

    We determine the structural architecture of the hydrothermal system of Hammam Bouhadjar area (Northwest of Algeria) by the use of geophysical data. New gravity and electrical surveys covered an area of about 48 km2 in 2009. There were 350 gravity measurements made with a sampling of 500 m and 45 electrical soundings (Schlumberger type, AB = 1000 m). The Bouguer anomaly map shows a regression of gravity field towards the NW and SE. All of the observed anomalies are elongated in NE-SW direction. The results obtained from different processing methods (gradients, upward continuation, Euler deconvolution, wavelet transform and modelling) of gravity data were used to generate structural map of the studied area. The vertical and horizontal variations of resistivity confirm the presence of superficial and deeper faults system. Following the geophysical (gravity and electrical) analysis and modelling, we propose a model to explain the origin of the Hammam Bouhadjar thermal waters. We suggest that the hot spring water comes from an aquifer located in sandstones lenses in the Senono-Oligocene Tellian unit. Following the gravity modelling the aquifer is identified at about 800 m, the same depth where the geothermal gradient is insufficient to heat the water. In these circumstances, the aquifer is probably heated by volcanic processes connected with a hot compartment by faults and contacts affecting structures identified in depth. The presence of a conductor along of the horseshoe area suggests that the water percolates into this area and then is drained by the different accidents to invade the whole area.

  14. Microbial lipid remnants within sulfide chimneys reveal organic matter transport in seafloor hydrothermal systems

    Science.gov (United States)

    Reeves, E.; Goldenstein, N. I.; Yoshinaga, M. Y.; Pjevac, P.; Bach, W.; Hinrichs, K.

    2013-12-01

    , with presumed hyperthermophilic archaeal lipid remnants more prevalent in interior and more mesophilic lipids in outer regions of the inactive chimney. Diffuser interior samples, however, are highly unusual, in that they contain presumed mesophilic archaeal core lipids, despite uninhabitable temperatures. Thermal degradation of an in situ microbial community (e.g. due to transient fluid flow variability) is a possible explanation, but the nature of these lipids suggests they may instead reflect transport and pyrolysis of microbial material from lower temperature mixing zones within the crustal aquifer. Not only does this study broaden our understanding of lipid biomolecule distribution in the interiors of sulfide edifices, it provides an initial evaluation of possible sources and implications for carbon cycling in seafloor hydrothermal systems.

  15. The submarine hydrothermal system of Panarea (Southern Italy: biogeochemical processes at the thermal fluids - sea bottom interface

    Directory of Open Access Journals (Sweden)

    T. Maugeri

    2006-06-01

    Full Text Available Among the submarine hydrothermal systems located offshore the volcanic archipelago of the Aeolian Islands (Southern Italy, the most active is located off the coasts of Panarea island. Thermal waters, gases and sulfur deposits coexist at the sea bottom where hydrothermal fluids are released from both shallow and deep vents. The chemical and isotopic composition of the fluid phase shows the presence of a significant magmatic component and the physico-chemical conditions of the geothermal reservoir allow the release of reduced chemical species that are microbially mediated towards the production of organic carbon as a form of biochemical energy. Microorganisms inhabiting this environment possess nutritional requirements and overall metabolic pathways ideally suited to such ecosystem that represents a clear example of the close connection between geosphere and biosphere. Microscopic examination of the white mat attached to rock surfaces showed the presence of Thiothrix-like filamentous bacteria. Moderately thermophilic heterotrophic isolates were identified as strains of the genus Bacillus. Although the hydrothermal system of Panarea has to be considered a “shallow” system, it shows many characteristics that make it similar to the “deep” oceanic systems, giving a unique opportunity for improving our knowledge on such an unexplored world by working at this easily accessible site.

  16. Aqueous ZrO2 and YSZ Colloidal Systems through Microwave Assisted Hydrothermal Synthesis

    Directory of Open Access Journals (Sweden)

    Klaartje De Buysser

    2013-09-01

    Full Text Available In this paper, the formation of ZrO2 and yttria-stabilised-zirconia (YSZ aqueous colloidal systems via microwave assisted hydrothermal synthesis is studied. Microwave synthesis allows a fast screening of the influence of different parameters such as time and temperature. The temperature varied from 140 °C up to 180 °C and the used reaction time varied from 5 min up to 1 h. The synthesised zirconia nanoparticles have a particle size of 50 nm confirmed by TEM. A 1H NMR (nuclear magnetic resonance study helped to understand the stabilization mechanism of the synthesised particles. By the addition of ytrrium ions into the zirconia colloidal solution, YSZ could be formed via an additional thermal treatment. Hereby, the samples are heated up to 400 °C for 1 h. YSZ colloidal solutions are synthesised by making use of complexing agents such as nitrilotriacetic acid, ethylenediaminetetraacetic acid and citric acid to control the hydrolysis and condensation of both ions to avoid non-stoichiometric phases. The ratio of Zr/Y in the particles is quantified by XRF. The amorphous structure of those particles necessitates an additional thermal treatment up to 600 °C during 1 h in order to obtain crystalline YSZ.

  17. Geophysical imaging of a vapor dominated hydrothermal system in Yellowstone National Park, USA

    Science.gov (United States)

    Bouligand, C.; Byrdina, S.; Kass, A.; Irons, T. P.; Vandemeulebrouck, J.; Ball, J. L.; Ritzinger, B. T.; McConville, E. G.; Hurwitz, S.

    2016-12-01

    Yellowstone National Park (YNP) hosts several vapor-dominated, acid-sulfate thermal areas that are typically located in topographically high areas along the boundary of the Yellowstone caldera. In these systems, steam and heat rise from deep boiling waters and either condense beneath a low permeability cap layer and then descend down fractures (heat pipes), or discharge through fumaroles either to the atmosphere or into pools. To better understand the geometry of the ascending vapor plumes and their relation to geologic structures and hydrothermal alteration, we carried a geophysical study in the Solfatara Plateau thermal area along the northern boundary of the Yellowstone caldera. This ˜600 m × 600 m area has a small mud pool and several small fumaroles with visible native sulfur deposits. Previous studies in the thermal area have mapped the spatial distributions of heat and CO2 flux. In June 2016 we collected detailed electric resistivity, magnetic, TEM and NMR data. Rock samples were collected to measure the electric resistivity and magnetization properties of the altered and unaltered sub-surface in the laboratory. Initial results suggest that there is a strong electric resistivity contrast between the center and periphery of the thermal area, which suggests that fluid pathways are strongly focused. Magnetic anomalies are subdued in the center of the thermal area, indicating low-magnetization of the shallow subsurface.

  18. The Origin of Carbon-Bearing Volatiles in a Continental Hydrothermal System in the Great Basin: Water Chemistry and Isotope Characterizations

    Science.gov (United States)

    Fu, Qi; Socki, Richard A.; Niles, Paul B.; Romanek, Christopher; Datta, Saugata; Darnell, Mike

    2012-01-01

    Hydrothermal systems on Earth are active centers in the crust where organic molecules can be synthesized biotically or abiotically under a wide range of physical and chemical conditions [1-3]. Not only are volatile species (CO, CO2, H2, and hydrocarbons) a reflection of deep-seated hydrothermal alteration processes, but they also form an important component of biological systems. Studying carbon-bearing fluids from hydrothermal systems is of specific importance to understanding (bio-)geochemical processes within these systems. With recent detection of methane in the martian atmosphere [4-7] and the possibility of its hydrothermal origin [8, 9], understanding the formation mechanisms of methane may provide constraints on the history of the martian aqueous environments and climate.

  19. Antioxidant systems and lipid peroxidation in Bathymodiolus azoricus from Mid-Atlantic Ridge hydrothermal vent fields.

    Science.gov (United States)

    Bebianno, M J; Company, R; Serafim, A; Camus, L; Cosson, R P; Fiala-Médoni, A

    2005-11-30

    Enzymatic defenses involved in protection from oxygen radical damage were determined in gills and mantle of Bathymodiolus azoricus collected from three contrasting Mid-Atlantic Ridge (MAR) hydrothermal vent fields (Menez-Gwen, Lucky Strike and Rainbow). The activities of superoxide dismutase (SOD), catalase (CAT), glutathione peroxidases (GPx) (total and Se-dependent), and levels of total oxyradical scavenging capacity (TOSC), metallothioneins (MT) and lipid peroxidation (LPO) were determined in B. azoricus tissues and the impact of metal concentrations on these antioxidant systems and lipid peroxidation assessed. SOD, CAT, TOSC, MTs and LPO levels were higher in B. azoricus gills while glutathione peroxidases (total and Se-dependent) were higher in the mantle, and with the exception of CAT, were of the same order of magnitude as in other molluscs. TOSC levels from Menez-Gwen indicate that the vent environment at this site is less stressful and the formation of ROS in mussels is effectively counteracted by the antioxidant defense system. TOSC depletion indicates an elevated ROS production in molluscs at the other two vent sites. Cytosolic SOD, GPx and LPO were more relevant at Lucky Strike (Bairro Alto) where levels of essential (Cu and Zn) and toxic metals (Cd and Ag) were highest in the organisms. CAT activity and LPO were predominant at the Rainbow vent site, where an excess of Fe in mussel tissues and in vent fluids (the highest of all three vent sites) may have contributed to increased LPO. Therefore, three distinct pathways for antioxidant enzyme systems and LPO based on environmental metal speciation of MAR vent fields are proposed for Bathymodiolus gills. At Menez-Gwen, TOSC towards peroxyl and hydroxyl radicals and peroxynitrite are predominant, while at Lucky Strike cytosolic SOD activity and GPx are the main antioxidant mechanisms. Finally at Rainbow, catalase and lipid peroxidation are dominant, suggesting that resistance of mussels to metal toxicity at

  20. Organic compounds in hydrothermal systems on the Russian Far East: relevance to the origin of life

    Science.gov (United States)

    Kompanichenko, Vladimir

    instance, Simoneit et al. (2) established that the light oil associated with the Uzon caldera in Kamchatka was formed by pyrolysis of buried algal mats. More interesting would be to determine that the aromatics and alkanes are products of a Fischer-Tropsch type synthesis. Intermediately the possible in-put of the abiotic organics is confirmed with the availability of Cl-alkanes in the hot solution because these compounds cannot be produced in a living organism. Besides, concentrations of even and uneven carbon atoms are similar in the juvenile hot water from the central zone of Kuldur field (the intracontinental part) that indicates their probable abiotic origination, while the uneven carbon atoms much prevail over the even ones (in 5 times) in the lower-temperature meteoric water on the flank. The detected organic compounds could enter into the composi-tion of various prebiotic microsystems or aggregates existed in the changeable hydrothermal media suitable for the origin of life. It follows of the inversion approach to the origin of life (Kompanichenko, 2008) that synthesis of other biologically important molecules (sugars, ATP, nucleotides), which are not typical for hydrothermal medium, started at the moment of the in-version the ratio "free energy contribution to entropy contribution" in the network of chemical reactions. The re-organized and turned into negentropy way network might promote the syn-thesis of these molecules under higher temperature conditions than revealed for the laboratory experiments in Vitro (50-60C). References. 1. Mukhin L.M., Bondarev V.B., Vakin E.A., Iljukhina I.I., Kalinichenko V.I., Milekhina E.I., Safonova E.N., 1979. Amino acids in hydrothermal systems in Southern Kam-chatka. Doklady AN USSR 244 (4), 974-977, (In Russian). 2. Simoneit, B., Deamer, D.W. and Kompanichenko, V. 2009. Characterization of hydrothermally generated oil from the Uzon Caldera, Kamchatka. Applied Geochemistry 24: 303-309. 3. Kompanichenko V.N. 2008. Three stages of

  1. Three-dimensional electrical resistivity model of the hydrothermal system in Long Valley Caldera, California, from magnetotellurics

    Science.gov (United States)

    Peacock, Jared R.; Mangan, Margaret T.; McPhee, Darcy K.; Wannamaker, Phil E.

    2016-01-01

    Though shallow flow of hydrothermal fluids in Long Valley Caldera, California, has been well studied, neither the hydrothermal source reservoir nor heat source has been well characterized. Here a grid of magnetotelluric data were collected around the Long Valley volcanic system and modeled in 3-D. The preferred electrical resistivity model suggests that the source reservoir is a narrow east-west elongated body 4 km below the west moat. The heat source could be a zone of 2–5% partial melt 8 km below Deer Mountain. Additionally, a collection of hypersaline fluids, not connected to the shallow hydrothermal system, is found 3 km below the medial graben, which could originate from a zone of 5–10% partial melt 8 km below the south moat. Below Mammoth Mountain is a 3 km thick isolated body containing fluids and gases originating from an 8 km deep zone of 5–10% basaltic partial melt.

  2. Radon surveys and monitoring at active volcanoes: an open window on deep hydrothermal systems and their dynamics

    Science.gov (United States)

    Cigolini, Corrado; Laiolo, Marco; Coppola, Diego

    2017-04-01

    The behavior of fluids in hydrothermal systems is critical in volcano monitoring and geothermal prospecting. Analyzing the time series of radon emissions on active volcanoes is strategic for detecting and interpreting precursory signals of changes in volcanic activity, eventually leading to eruptions. Radon is a radioactive gas generated from the decay of U bearing rocks, soils and magmas. Although radon has been regarded as a potential precursor of earthquakes, radon anomalies appear to be better suited to forecast volcanic eruptions since we know where paroxysms may occur and we can follow the evolution of volcanic activity. Radon mapping at active volcanoes is also a reliable tool to assess diffuse and concentrated degassing as well as efficiently detecting earthquake-volcano interactions. Systematic radon monitoring has been shown to be a key factor for evaluating the rise of volcanic and hydrothermal fluids. In fact, the decay properties of radon, the duration of radon anomalies together with sampling rates may be cross-checked with the chemistry of hydrothermal fluids (and their transport properties) to constrain fluids ascent rates and to infer the permeability and porosity of rocks in sectors surrounding the active conduits. We hereby further discuss the data of radon surveys and monitoring at Somma-Vesuvius, Stromboli and La Soufrière (Guadeloupe, Lesser Antilles). The integrated analysis of seismic and geochemical data, including radon emissions, may be successfully used in testing temperature distributions and variations of porosity and permeability in volcanic hydrothermal systems and can be used as a proxy to analyze geothermal reservoirs.

  3. Hydrothermal conversion of FAU zeolite into RUT zeolite in TMAOH system

    OpenAIRE

    Jon, Hery; Takahashi, Shoutarou; Sasaki, Hitoshi; Oumi, Yasunori; Sano, Tsuneji

    2008-01-01

    The highly crystalline and pure RUT (RUB-10) zeolite could be obtained from the hydrothermal conversion of FAU zeolite used as a crystalline Si/Al source in tetramethylammonium hydroxide (TMAOH) media. As compared to amorphous silica/Al(OH)3 and amorphous silica/γ-Al2O3 sources, the crystallization rate for the formation of RUT zeolite was clearly faster when FAU zeolite was employed as the Si/Al source. Moreover, it was found that the hydrothermal conversion of FAU zeolite into RUT zeolite d...

  4. Mechanical behaviour of the Krafla geothermal reservoir: Insight into an active magmatic hydrothermal system

    Science.gov (United States)

    Eggertsson, Guðjón H.; Lavallée, Yan; Kendrick, Jackie E.

    2017-04-01

    Krafla volcano, located in North-East Iceland, holds an active magmatic hydrothermal system. Since 1978, this system has been exploited for geothermal energy. Today it is exploited by Landsvirkjun National Power of Iceland and the system is generating 60 MWg from 18 wells, tapping into fluids at 200-300°C. In order to meet further demands of environmentally sustainable energy, Landsvirkjun aims to drill deeper and source fluids in the super-heated, super high-enthalpy system which resides deeper (at 400-600°C). In relation to this, the first well of the Icelandic Deep Drilling Project (IDDP) was drilled in Krafla in 2009. Drilling stopped at a depth of 2.1 km, when the drill string penetrated a rhyolitic magma body, which could not be bypassed despite attempts to side-track the well. This pioneering effort demonstrated that the area close to magma had great energy potential. Here we seek a constraint on the mechanical properties of reservoir rocks overlying the magmatic systems to gain knowledge on these systems to improve energy extraction. During two field surveys in 2015 and 2016, and through information gathered from drilling of geothermal wells, five main rock types were identified and sampled [and their porosities (i.e., storage capacities) where determined with a helium-pycnometer]: basalts (5-60% porosity), hyaloclastites (geothermal reservoir. Uniaxial and triaxial compressive strength tests have been carried out, as well as indirect tensile strength tests using the Brazilian disc method, to measure the rock strengths. The results show that the rock strength is inversely proportional to the porosity and strongly affected by the abundance of microcracks; some of the rocks are unusually weak considering their porosities, especially at low effective pressure as constrained at Krafla. The results also show that the porous lithologies may undergo significant compaction at relatively low loads (i.e., depth). Integration of the observed mechanical behaviour and

  5. Patterns of Fluid Circulation and Steam Generation in Caldera-Hosted Hydrothermal Systems

    Science.gov (United States)

    Barnard, M. E.; Cook, S. J.

    2009-05-01

    Steam formation is an important mechanism powering near surface phenomena in active hydrothermal systems (e.g., Yellowstone) and an established ore deposition mechanism in ancient equivalents (e.g., Creede). To gain insights into factors controlling steam formation and distribution in these systems, a series of steady-state numerical models were run on a hypothetical caldera-hosted system based on characteristics of a representative suite of calderas (e.g., Yellowstone, Valles, Creede). Base model conditions consisted of (1) a 10 km-wide caldera with a flat floor and rim height of 800 m; (2) a 500 C intrusion 1.5 km below the caldera centre; (3) a regional conductive heat flux twice continental average (0.10 W/m2); (4) host rock thermal conductivity of 2.5 W/m C, density 2650 kg/m3 and pore fraction 0.05. An impermeable intrusion was modeled with a 500 m wide surrounding region with a permeability (k) 10-3 m2 less than the system meant to represent a ductile region produced by elevated temperature (T > 350 C). The remainder of the system was given homogenous permeability. Cylindrical coordinates were used to represent caldera geometry. For these conditions, a minimum k = 10-15 m2 was required to achieve the target thermal condition of T approximately 220 C at 300 m below ground surface observed in active systems (e.g., Yellowstone). This model also resulted in a continuous steam plume originating at the intrusive contact that reached within 300 m of the surface along the edges of the caldera ~2 km from caldera centre. Models with k caldera centre and reduced its volume, but still achieved target conditions. Increasing intrusion temperature by 10% produced a second distinct plume at the caldera centre that also achieved target conditions. Increasing the rim height for these conditions produced the base (i.e., single plume) conditions. Resurgent doming up to 300 m was also modeled for the caldera floor. Increasing dome height shifted steam towards the caldera centre

  6. Supercritical hydrothermal synthesis and in situ organic modification of indium tin oxide nanoparticles using continuous-flow reaction system.

    Science.gov (United States)

    Lu, Jinfeng; Minami, Kimitaka; Takami, Seiichi; Shibata, Masatoshi; Kaneko, Yasunobu; Adschiri, Tadafumi

    2012-01-01

    ITO nanoparticles were synthesized hydrothermally and surface modified in supercritical water using a continuous flow reaction system. The organic modification of the nanoparticles converted the surface from hydrophilic to hydrophobic, making the modified nanoparticles easily dispersible in organic solvent. The addition of a surface modifier into the reaction system impacted the crystal growth and particle size as well as dispersion. The particle size was 18 nm. Highly crystalline cubic ITO with a narrow particle size distribution was obtained. The advantages of short reaction time and the use of a continuous reaction system make this method suitable for industrial scale synthesis. © 2011 American Chemical Society

  7. The Bayesian Reliability Assessment and Prediction for Radar System Based on New Dirichlet Prior Distribution

    Science.gov (United States)

    Ming, Zhimao; Ling, Xiaodong; Bai, Xiaoshu; Zong, Bo

    2016-02-01

    This article studies on Bayesian reliability growth models of complex system based on new Dirichlet prior distribution when the sample of system is small. The model briefly describes expert experience as uniform distribution, then equivalent general Beta distribution of uniform distribution can be solved by optimization method when prior parameters are variables, mean is constraint condition, and variance is regarding as the optimization objective. The optimization method solves the problem of how to determine values of hyper-parameters of new Dirichlet distribution when these parameters have no specific physical meaning. Because the multidimensional numerical integration of posterior distribution is very difficult to calculate, WinBUGS software is employed to establish Bayesian reliability growth model based on a new Dirichlet prior distribution, and two practical cases are studied under this model in order to prove validity of model. The analysis results show that the model can improve the precision of calculation, and it is easy to use in engineering.

  8. Fluid chemistry of the low temperature hyperalkaline hydrothermal system of Prony Bay (New Caledonia)

    Science.gov (United States)

    Monnin, C.; Chavagnac, V.; Boulart, C.; Ménez, B.; Gérard, M.; Gérard, E.; Pisapia, C.; Quéméneur, M.; Erauso, G.; Postec, A.; Guentas-Dombrowski, L.; Payri, C.; Pelletier, B.

    2014-10-01

    H 11) are not significantly different from one site to the other although the sites are several kilometres away from each other and are located on different ultramafic substrata. The very low salinity of the hyperalkaline endmembers shows that seawater does not percolate through the ultramafic formation. Mixing of the hyperalkaline hydrothermal endmember with local seawater produces large ranges and very sharp gradients of pH, salinity and dissolved element concentrations. There is a major change in the composition of the water samples at a pH around 10, which delimitates the marine environment from the hyperalkaline environment. The redox potential evolves toward negative values at high pH indicative of the reducing conditions due to bubbling of the H2-rich gas. The calculation of the mineral saturation states carried out for the Na-K-Ca-Mg-Cl-SO4-DIC-SiO2-H2O system shows that this change is due to the onset of brucite formation. While the saturation state of the Ca carbonates over the whole pH range is typical of that found in a normal marine environment, Mg- and Mg-Ca carbonates (magnesite, hydromagnesite, huntite, dolomite) exhibit very large supersaturations with maximum values at a pH of around 10, very well marked for the Bain des Japonais, emphasizing the role of water mixing in mineral formation. The discharge of high-pH waters of meteoric origin into the lagoon marine environment makes the hydrothermal system of Prony Bay unique compared to other low temperature serpentinizing environments such as Oman (fully continental) or Lost City (fully marine).

  9. Experimental investigation of As, Sb and Cs behavior during olivine serpentinization in hydrothermal alkaline systems

    Science.gov (United States)

    Lafay, Romain; Montes-Hernandez, German; Janots, Emilie; Munoz, Manuel; Auzende, Anne Line; Gehin, Antoine; Chiriac, Rodica; Proux, Olivier

    2016-04-01

    While Fluid-Mobile Elements (FMEs) such as B, Sb, Li, As or Cs are particularly concentrated in serpentinites, data on FME fluid-serpentine partitioning, distribution, and sequestration mechanisms are missing. In the present experimental study, the behavior of Sb, As and Cs during San Carlos olivine serpentinization was investigated using accurate mineralogical, geochemical, and spectroscopic characterization. Static-batch experiments were conducted at 200 °C, under saturated vapor pressure (≈1.6 MPa), for initial olivine grain sizes of product content was determined as a function of reaction advancement for the different initial olivine grain sizes investigated. The results confirm that serpentinization products have a high FME uptake capacity with the partitioning coefficient increasing such as CsDp/fl = 1.5-1.6 products, especially brucite. In contrast, mineralogical characterization combined with XAS spectroscopy reveal redox sensitivity for Sb sequestration within serpentine products, depending on the progress of the reaction. When serpentinization is products is observed and is attributed to a reduction of Sb(V) into Sb(III). This stage is characterized by the precipitation of Sb-Ni-rich phases and a lower bulk partitioning coefficient compared to that of the serpentine and brucite assemblage. Antimony reduction appears linked to water reduction accompanying the bulk iron oxidation, as half the initial Fe(II) is oxidized into Fe(III) and incorporated into the serpentine products once the reaction is over. The reduction of Sb implies a decrease of its solubility, but the type of secondary Sb-rich phases identified here might not be representative of natural systems where Sb concentrations are lower. These results bring new insights into the uptake of FME by sorption on serpentine products that may form in hydrothermal environments at low temperatures. FME sequestration here appears to be sensitive to various physicochemical parameters and more particularly

  10. Hydrothermal fluids vented at shallow depths at the Aeolian islands: relationships with volcanic and geothermal systems.

    Science.gov (United States)

    Italiano, Francesco; Caracausi, Antonio; Longo, Manfredi; Maugeri, Roberto; Paonita, Antonio

    2010-05-01

    and Panarea). The explanation of such a difference is not related to the volcanic activity at all, but to the parent mantle that in the western side looks to be less contaminated compared to the eastern side. Crustal contamination has been invoked by several authors as the main factor that caused the dramatic 3He/4He decrease. Although the parent mantle produced magmas with different isotopic signature, the gas phase looks similar. To explain the results of the chemical analyses it is proposed that similar deep boundary conditions (pressure, temperature, oxidation level) act as buffers for the chemical composition of the venting gases. With the aim of investigating their origin, estimations of the deep equilibration conditions have been carried out. The reactive compounds detected in the sampled gases, largely used for geothermometric and geobarometric considerations of hydrothermal fluids were used in a system based on the CH4-CO-CO2 contents assuming the presence of a boiling aqueous solution. The equilibrium constants of the adopted reactions are a function of temperature and oxygen fugacity, being the latter buffered by the mineral assemblage of the host rocks. Due to the similarity in the chemical composition of the gases vented at all the islands, a theoretical model developed to interpret the chemical composition of the gases released at Panarea during the last volcanic crisis is here applied. The results have shown that geothermal boiling systems are detectable at all the islands with temperatures up to 350°C. The adopted geo-thermobarometric system is more sensitive to the contents of CO and CH4 than that of CO2, implying that although GWI induce modifications in the chemical composition, the estimated equilibrium temperatures do not change very much for variations of the CO2 content in the range of several volume percent, thus, whether or not the gaseous mixture underwent GWI. Moreover, the slow reaction kinetics of CO and CH4 allow them to keep the deep

  11. SI-Hydro: an information system for the Brazilian hydrothermal system; SI-Hidro: um sistema de informacao para o sistema hidrotermico brasileiro

    Energy Technology Data Exchange (ETDEWEB)

    Fontanini, Walcir

    1995-03-01

    An information system for the Brazilian hydrothermal system denominated SI-Hydro is presented. This information system supplies data on the hydroelectric and thermoelectric park and can be used in the main elements recognition and in the planning and management of the whole system. The information system uses the product INGRES in the platform UNIX/X-Windows, which supplies resources so much for access to the database as for the interface man machine through the fourth generation language denominated Windows4GL. The next main topics are presented: information systems concepts and its relation with the direction levels to an organization and implications for the hydrothermal system operation planning in the scenarios of short, medium and long terms; thermal and hydroelectric plants operation routine details; the most used technical terms definition; and mathematical physical typical plants processes modeling presentation.

  12. Correlations between Archaeal Diversity and Geochemical Parameters in an Arsenic-Rich Hydrothermal System

    Science.gov (United States)

    Franks, M.; Omelon, C.; Engel, A. S.; Bennett, P.

    2009-04-01

    Characterizing microbial communities within their geochemical environment is useful for understanding microbial distribution and microbial adaptations to extreme physical and chemical conditions. The hydrothermal waters at El Tatio geyser field (ETGF) demonstrate extreme geochemical conditions, with discharge water from springs and geysers at local boiling temperature (85oC), arsenic concentrations of 0.5 mM, and inorganic carbon concentrations (DIC) as low as 0.2mM. Yet many of El Tatio's hundred plus hydrothermal features host extensive microbial mat communities. Recent work has shown correlations between the metabolic guilds of microorganisms present and variations in water chemistry. ETGF is a high-altitude hydrothermal basin with over 100 mapped hydrothermal features, located within a 30km2 area near the Chile-Bolivia border. The Na-Cl type waters have a circumneutral pH and contain abundant dissolved metals. Shallow runoff aprons extend tens of meters from some geyser features, where silica rapidly precipitates from cooling water. Thick mats, which appear microbial but consist primarily of silica, iron and arsenic mineral deposits, containing

  13. Diversity of Archaeal Consortia in an Arsenic-Rich Hydrothermal System

    Science.gov (United States)

    Franks, M.; Bennett, P.; Omelon, C.; Engel, A.

    2008-12-01

    Characterizing microbial communities within their geochemical environment is essential to understanding microbial distribution and microbial adaptations to extreme physical and chemical conditions. The hydrothermal waters at El Tatio geyser field demonstrate extreme conditions, with water at local boiling (85°C), arsenic concentrations at 0.5 mM, and inorganic carbon concentrations as low as 0.02mM. Yet many of El Tatio's hundred plus hydrothermal features are associated with extensive microbial mat communities. Recent work has shown phylogenetic variation in the communities that correlates to variations in water chemistry between features. MPN analysis indicates variations in metabolic function between hydrothermal features, such as the ability of the community to fix nitrogen, and the presence of methanogens within the community. Methanogenic archaea, which are typical of hydrothermal environments, are found in very few of the sampled hydrothermal features at El Tatio. MPN enumeration shows that nonspecific microbial mat samples from sites with dissolved methane contain 106 cells of methanogenic archaea per gram while non-specific samples from sites lacking dissolved methane contain 100 cells per gram or less. An acetylene assay showed evidence for nitrogen fixation in a sample associated with methanogenesis, but microbial transformation of acetylene to ethylene did not occur in non-methanogenic sites. More specific sampling of microbial mats indicates that methanogenic archaea are dominated by microorganisms within the genus Methanospirillum and Methanobrevibacter. These microbes are associated with a number of unclassified archaea in the class Thermoplasmata Halobacteriales, and unclassifiec Crenarchaeota. In addition, preliminary results include an unclassified Thaumarchaeota clone, a member of the recently proposed third archaeal phylum Thaumarchaeota. Nonspecific microbial mat sample from a non- methanogenic site included only Crenarchaeal clones within the

  14. Catabolic and anabolic energy for chemolithoautotrophs in deep-sea hydrothermal systems hosted in different rock types

    Science.gov (United States)

    Amend, Jan P.; McCollom, Thomas M.; Hentscher, Michael; Bach, Wolfgang

    2011-10-01

    Active deep-sea hydrothermal vents are hosted by a range of different rock types, including basalt, peridotite, and felsic rocks. The associated hydrothermal fluids exhibit substantial chemical variability, which is largely attributable to compositional differences among the underlying host rocks. Numerical models were used to evaluate the energetics of seven inorganic redox reactions (potential catabolisms of chemolithoautotrophs) and numerous biomolecule synthesis reactions (anabolism) in a representative sampling of these systems, where chemical gradients are established by mixing hydrothermal fluid with seawater. The wide ranging fluid compositions dictate demonstrable differences in Gibbs energies (Δ G r) of these catabolic and anabolic reactions in three peridotite-hosted, six basalt-hosted, one troctolite-basalt hybrid, and two felsic rock-hosted systems. In peridotite-hosted systems at low to moderate temperatures (10), hydrogen oxidation yields the most catabolic energy, but the oxidation of methane, ferrous iron, and sulfide can also be moderately exergonic. At higher temperatures, and consequent SW:HF mixing ratios anabolism in chemolithoautotrophs—represented here by the synthesis of amino acids, nucleotides, fatty acids, saccharides, and amines—were generally most favorable at moderate temperatures (22-32 °C) and corresponding SW:HF mixing ratios (˜15). In peridotite-hosted and the troctolite-basalt hybrid systems, Δ G r for primary biomass synthesis yielded up to ˜900 J per g dry cell mass. The energetics of anabolism in basalt- and felsic rock-hosted systems were far less favorable. The results suggest that in peridotite-hosted (and troctolite-basalt hybrid) systems, compared with their basalt (and felsic rock) counterparts, microbial catabolic strategies—and consequently variations in microbial phylotypes—may be far more diverse and some biomass synthesis may yield energy rather than imposing a high energetic cost.

  15. Geology of the Early Archean Mid-Ocean Ridge Hydrothermal System in the North Pole Dome, Pilbara Craton, Western Australia

    Science.gov (United States)

    Kitajima, K.; Maruyama, S.

    2007-12-01

    An Archean hydrothermal system in the North Pole Dome, Pilbara Craton is associated with extensive fluid circulation driven by numerous extensional fracture systems and the underlying heat source. The fracture system is now occupied by abundant fine-grained quartz aggregate, hence we call this as silica dikes. Some of the fracture system extends deeper structural levels as listric normal faults down to 1000 m depth in the MORB crust. Barite-bearing fine-grained quartz predominant mineralogy indicates the extensive development of fracturing and quenching in a short time. Accompanying the fluid circulation, the extensive metasomatism proceeded to form the four different chemical courses, (1) silicification, (2) carbonation, (3) potassium-enrichment, and (4) Fe- enrichment. Silicification occurs along the silica dikes, carbonated greenstones are distributed relatively shallower level. Potassium-enriched (mica-rich) greenstones occur at the top of the greenstone sequence, and Fe-enriched (chlorite-rich) greenstones are distributed at lower part of the basaltic greenstones. The down going fluid precipitated carbonate-rich layer at shallow levels, whereas depleted in SiO2. Then, the fluid went down to more deeper level, and was dissolved SiO2 at high temperature (~350°C) and chlorite-rich greenstone was formed by water-rock interaction. The upwelling fluid precipitated dominantly SiO2 and formed silica dikes. Silica dikes cement the fractures formed by extensional faulting at earliest stage of development of oceanic crust. Therefore, the hydrothermal system must have related to normal fault system simultaneously with MORB volcanism. Particularly the greenish breccia with cherty matrix (oregano chert) was formed at positions by upwelling near ridge axis. After the horizontal removal of MORB crust from the ridge-axis with time, the propagating fracture into deeper levels, transports hydrothermal fluids into 500-1000 m depth range where metasomatic element exchange between

  16. Evaluating the Historical Importance of Impact Induced Hydrothermal Systems on Mars Using the Stable Isotopic Composition of Martian Water

    Science.gov (United States)

    Niles, Paul B.

    2010-01-01

    The importance of impact events during the early history of Mars is obvious through a simple examination of the character of the martian surface. This ancient, heavily cratered terrain has been shown to be associated with extensive phyllosilicate deposits. This geologic link could suggest that the extensive phyllosilicate-forming alteration may have occurred during early martian history through impact-induced hydrothermal alteration. However, examination of the oxygen isotopic composition of water on Mars suggests that the extensive phyllosilicate deposits were formed primarily through low temperature (Mars. The average oxygen isotopic composition of water on Earth is dictated by the nature of water-rock interactions. If these interactions occur at higher temperatures then the water will contain a higher proportion of 18O, while lower temperature interactions will result in water with a lower proportion of 18O. Water on Earth today contains a higher proportion of 18O because of plate tectonics and hydrothermal interaction at mid-ocean ridges. The oxygen isotopic composition of water on early earth, however, may have been quite different, containing a smaller proportion of 18O suggesting much less hydrothermal interaction. Because there are not yet any direct measurements of the oxygen isotopic composition of water on Mars, it needs to be inferred through examination of carbonates preserved in martian meteorites and the isotopic composition of atmospheric CO2. This can be done because the oxygen incorporated into carbonates and CO2 is easily exchanged with liquid water if it is present. Independently, both measurements provide an estimate for the (Sigma)18O of water on Mars to be near -16%. This composition is consistent with low temperature weathering of the silicate crust, and indicates that impact hydrothermal systems did not play an important role in the early alteration of the planet. However, our understanding of impact-induced hydrothermal systems remains

  17. Hydrothermal Biogeochemistry

    Science.gov (United States)

    Shock, E.; Havig, J.; Windman, T.; Meyer-Dombard, D.; Michaud, A.; Hartnett, H.

    2006-12-01

    Life in hot spring ecosystems is confronted with diverse challenges, and the responses to those challenges have dynamic biogeochemical consequences over narrow spatial and temporal scales. Within meters along hot spring outflow channels at Yellowstone, temperatures drop from boiling, and the near-boiling conditions of hot chemolithotrophic communities, to those that permit photosynthesis and on down to conditions where nematodes and insects graze on the edges of photosynthetic mats. Many major and trace element concentrations change only mildly in the water that flows through the entire ecosystem, while concentrations of other dissolved constituents (oxygen, sulfide, ammonia, total organic carbon) increase or decrease dramatically. Concentrations of metals and micronutrients range from toxic to inadequate for enzyme synthesis depending on the choice of hot spring. Precipitation of minerals may provide continuous growth of microbial niches, while dissolution and turbulent flow sweeps them away. Consequently, microbial communities change at the meter scale, and even more abruptly at the photosynthetic fringe. Isotopic compositions of carbon and nitrogen in microbial biomass reflect dramatic and continuous changes in metabolic strategies throughout the system. Chemical energy sources that support chemolithotrophic communities can persist at abundant or useless levels, or change dramatically owing to microbial activity. The rate of temporal change depends on the selection of hot spring systems for study. Some have changed little since our studies began in 1999. Others have shifted by two or more units in pH over several years, with corresponding changes in other chemical constituents. Some go through daily or seasonal desiccation cycles, and still others exhibit pulses of changing temperature (up to 40°C) within minutes. Taken together, hydrothermal ecosystems provide highly manageable opportunities for testing how biogeochemical processes respond to the scale of

  18. Field occurrence and lithology of Archean hydrothermal systems in the 3.2Ga Dixon Island Formation, Western Australia

    Science.gov (United States)

    Aihara, Y.; Kiyokawa, S.; Ito, T.; Ikehara, M.; Yamaguchi, K. E.; Horie, K.; Sakamoto, R.; Miki, T.

    2013-12-01

    Stratigraphic transition of black chert to iron-rich sedimentary rocks above volcanic sequences with hydrothermal systems is common and characteristic feature of Archean greenstone belts. The 3.2 Ga Dixon Island Formation, exposed along the northern coast of Dixon Island located in the coastal Pilbara terrane, Western Australia, is one of such units and the focus of our study. We introduce field occurrence and lithology of the Dixon Island Formation that preserves features of paleohydrohermal environment in the Mesoarchean ocean. The Dixon Island Formation is composed of the following three members (in ascending order): Komatiite-Rhyolite Tuff, Black Chert, and Varicolored Chert members (Kiyokawa and Taira, 1998). Here we focus on the Komatiite-Rholite Tuff member. It preserves two cycles of highly altered komatiite lavas and well-stratified rhyolite tuff. Komatiite lavas include dendritic crystals of chrome spinel and ghosts of spinifex, euhedral and sheet-like olivines and pyroxenes. These rocks are now composed of granular microcrystalline quartz with chromian muscovite, chrome spinel and chrorite that formed by intense silicification. Its upper part contains hydrothermal veining and alteration (i.e., many vein swarms composed of veins of quartz and organic carbon-rich black chert). Most black chert veins intrude vertically into overlying layers, and contain barite, pyrite, monazite and clay minerals which were least affected by silicificatio. Based on the cross-cutting relationship seen in the outcrops, we recognized two generations of black chert veins (type 1 and type 2 veins; Kiyokawa et al., 2006). Type 1 veins are mainly composed of carbonaceous peloids in a microcrystalline quartz matrix. Euhedral and xenocrystic tourmaline are found only in Type1 veins. Type 2 veins are organic carbon-poor and contain fragments of black chert and siliceous volcanic breccia (Kiyokawa et al., 2006). Intense silicification of komatiitic volcaniclastics and lava, enriched in

  19. Particle Geochemistry of Hydrothermal Systems and Implications for Mining Seafloor Massive Sulfides

    Science.gov (United States)

    Gartman, A.; Hein, J. R.

    2016-12-01

    Seafloor massive sulfide deposits form due to high-temperature hydrothermal venting that occurs globally, in every ocean basin, along plate boundaries and intra-plate hotspots. At these sites, the rapid mixing of hot, metal- and sulfur-rich reduced fluids into cold, oxygenated ocean water results in abundant mineral precipitation. The mining of seafloor massive sulfides is likely to occur in the near future and will generate a new class of mainly inorganic particulates, different from those formed in hydrothermal `black smoke.' While the major components of both black smoke & SMS tailings are Cu, Fe and Zn sulfides, many other minerals, including those containing technology critical elements, especially tellurium, are present. A comparison of these two classes of particulates will be presented, including chemical composition and reactivity to oxidative dissolution.

  20. Imaging hydrothermal systems at Furnas caldera (Azores, Portugal): Insights from Audio-Magnetotelluric data

    Science.gov (United States)

    Hogg, Colin; Kiyan, Duygu; Rath, Volker; Byrdina, Svetlana; Vandemeulebrouck, Jean; Silva, Catarina; Viveiros, Maria FB; Ferreira, Teresa

    2016-04-01

    The Furnas volcano is the eastern-most of the three active central volcanoes of Sao Miguel Island. The main caldera formed about 30 ka BP, followed by a younger eruption at 10-12 ka BP, which forms the steep topography of more than 200 m in the measuring area. It contains several very young eruptive centers, and a shallow caldera lake. Tectonic features of varying directions have been identified in the Caldera and its vicinity. In the northern part of the caldera, containing the fumarole field of Caldeiras das Furnas, a detailed map of surface CO2 emissions was recently made available. In 2015, a pilot survey of 13 AudioMagnetoTelluric soundings (AMT) and Electrical Resistivity Tomography (ERT) data were collected along two profiles in the eastern part of Furnas caldera in order to image the electrical conductivity of the subsurface. The data quality achieved by both techniques is extraordinary and first results indicate a general correlation between regions of elevated conductivity and the mapped surface CO2 emissions, suggesting that they may both be caused by the presence hydrothermal fluids. Tensor decomposition analysis using the Groom-Bailey approach produce a generalised geo-electric strike direction, 72deg East of North, for the AMT data compared to the surface geological strike derived from the major mapped fault crossing the profiles of 105deg. An analysis of the real induction arrows at certain frequencies (at depths greater than 350 m) infer that an extended conductor at depth does not exactly correspond to the degassing structures at the surface and extends outside the area of investigation. The geometry of the most conductive regions with electrical conductivities less then1 Ώm found at various depths differ from what was expected from earlier geologic and tectonic studies and possibly may not be directly related to the mapped fault systems at the surface. On the eastern profile, which seemed to be more appropriate for 2-D modelling with 72deg strike

  1. The interplay of evolved seawater and magmatic-hydrothermal fluids in the 3.24 Ga panorama volcanic-hosted massive sulfide hydrothermal system, North Pilbara Craton, Western Australia

    Science.gov (United States)

    Drieberg, Susan L.; Hagemann, Steffen G.; Huston, David L.; Landis, Gary; Ryan, Chris G.; Van Achterbergh, Esmé; Vennemann, Torsten

    2013-01-01

    The ~3240 Ma Panorama volcanic-hosted massive sulfide (VHMS) district is unusual for its high degree of exposure and low degree of postdepositional modification. In addition to typical seafloor VHMS deposits, this district contains greisen- and vein-hosted Mo-Cu-Zn-Sn mineral occurrences that are contemporaneous with VHMS orebodies and are hosted by the Strelley granite complex, which also drove VHMS circulation. Hence the Panorama district is a natural laboratory to investigate the role of magmatic-hydrothermal fluids in VHMS hydrothermal systems. Regional and proximal high-temperature alteration zones in volcanic rocks underlying the VHMS deposits are dominated by chlorite-quartz ± albite assemblages, with lesser low-temperature sericite-quartz ± K-feldspar assemblages. These assemblages are typical of VHMS hydrothermal systems. In contrast, the alteration assemblages associated with granite-hosted greisens and veins include quartz-topaz-muscovite-fluorite and quartz-muscovite (sericite)-chlorite-ankerite. These vein systems generally do not extend into the overlying volcanic pile. Fluid inclusion and stable isotope studies suggest that the greisens were produced by high-temperature (~590°C), high-salinity (38–56 wt % NaCl equiv) fluids with high densities (>1.3 g/cm3) and high δ18O (9.3 ± 0.6‰). These fluids are compatible with the measured characteristics of magmatic fluids evolved from the Strelley granite complex. In contrast, fluids in the volcanic pile (including the VHMS ore-forming fluids) were of lower temperature (90°–270°C), lower salinity (5.0–11.2 wt % NaCl equiv), with lower densities (0.88–1.01 g/cm3) and lower δ18O (−0.8 ± 2.6‰). These fluids are compatible with evolved Paleoarchean seawater. Fluids that formed the quartz-chalcopyrite-sphalerite-cassiterite veins, which are present within the granite complex near the contact with the volcanic pile, were intermediate in temperature and isotopic composition between the greisen

  2. S/Se ratio of pyrite from eastern Australian VHMS deposits: implication of magmatic input into volcanogenic hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Huston, D.L. [Geological Survey of Canada, Ottawa, ON (Canada); Sie, S.H.; Suter, G.F. [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience; Cooke, D.R. [Tasmania Univ., Sandy Bay, TAS (Australia)

    1993-12-31

    The proton microprobe was used to determine the concentrations of over twenty trace elements in pyrite grains from four volcanic-hosted massive sulphide (VHMS) deposits in eastern Australia. Of the elements determined, Se has the most potential in resolving important problems in the genesis of this class of ore deposits. This paper summarises analytical conditions, describes the distribution of Se in pyrite in VHMS deposits as determined in this and other studies, discusses the speciation of Se in hydrothermal fluids, and presents a genetic model on the relative contribution of magmatic versus sea water Se (and S) in VHMS systems. 2 refs., 1 fig.

  3. Quantitative analysis of the hydrothermal system in Lassen Volcanic National Park and Lassen Known Geothermal Resource Area

    Science.gov (United States)

    Sorey, M.L.; Ingebritsen, S.E.

    1984-01-01

    The conceptual model of the Lassen system is termed a liquid-dominated hydrothermal system with a parasitic vapor-dominated zone. The essential feature of this model is that steam and steam-heated discharge at relatively high elevations in Lassen Volcanic National Park (LVNP) and liquid discharge with high chloride concentrations at relatively low elevations outside LVNP are both fed by an upflow of high-enthalpy two-phase fluid within the Park. Liquid flows laterally away from the upflow area towards the areas of high-chloride discharge, and steam rises through a vapor-dominated zone to feed the steam and steam-heated features. Numerical simulations show that several conditions are necessary for the development of this type of system, including (1) large-scale topographic relief, (2) an initial period of convective heating within an upflow zone followed by some change in hydrologic or geologic conditions that initiates drainage of liquid from portions of the upflow zone, and (3) low permeability barriers that inhibit the movement of cold water into the vapor zone. Simulations of thermal fluid withdrawal south of LVNP, carried out in order to determine the effects of such withdrawal on portions of the hydrothermal system within the Park, showed decreases in pressure and liquid saturation beneath the vapor zone which result in a temporary increase and subsequent decrease in the rate of upflow of steam. (USGS)

  4. Prototype expert system to assist with the stabilization of neonates prior to transport.

    OpenAIRE

    Heermann, L. K.; Thompson, C. B.

    1997-01-01

    The transport of sick or premature newborns from community hospitals to acute care facilities is often necessary for the infants to receive the level of care required. Prior stabilization of these infants is imperative to a successful transport. The knowledge required to treat and stabilize sick and premature newborns is specialized and may not be available in community hospitals. "The S.T.A.B.L.E. Assistant" is a prototype rule based decision support system based on the educational program "...

  5. Cardiovascular events prior to or early after diagnosis of systemic lupus erythematosus in the systemic lupus international collaborating clinics cohort

    DEFF Research Database (Denmark)

    Urowitz, M B; Gladman, D D; Anderson, N M

    2016-01-01

    OBJECTIVE: To describe the frequency of myocardial infarction (MI) prior to the diagnosis of systemic lupus erythematosus (SLE) and within the first 2 years of follow-up. METHODS: The systemic lupus international collaborating clinics (SLICC) atherosclerosis inception cohort enters patients withi...

  6. The low temperature hyperalkaline hydrothermal system of the Prony bay (New Caledonia)

    Science.gov (United States)

    Monnin, C.; Chavagnac, V.; Boulart, C.; Ménez, B.; Gérard, M.; Gérard, E.; Quéméneur, M.; Erauso, G.; Postec, A.; Guentas-Dombrowski, L.; Payri, C.; Pelletier, B.

    2014-04-01

    members (at pH 11) are not significantly different from one site to the other although the sites are several km away from each other and are located on different ultramafic substrata. The very low salinity of the hyperalkaline end members shows that seawater does not percolate through the ultramafic formation. Mixing of the hyperalkaline hydrothermal end member with local seawater produces large ranges and very sharp gradients of pH, salinity and dissolved element concentrations. There is a major change in the composition of the water samples at a pH around 10, which delimitates the marine environment from the hyperalkaline environment. The redox potential evolves toward negative values at high pH indicative of the reducing conditions due to bubbling of the H2-rich gas. The calculation of the mineral saturation states carried out for the Na-K-Ca-Mg-Cl-SO4-DIC-SiO2-H2O system shows that this change is due to the onset of brucite formation. While the saturation state of the Ca-carbonates over the whole pH range is typical of that found in a normal marine environment, Mg- and Mg-Ca-carbonates (magnesite, hydromagnesite, huntite, dolomite) exhibit very large supersaturations with maximum values at pH around 10, very well marked for the Bain des Japonais, emphasizing the role of water mixing in mineral formation. The discharge of high pH waters of meteoric origin into the lagoon marine environment makes the hydrothermal system of the Prony bay unique compared to other low temperature serpentinizing environments such as Oman (fully continental) or Lost City (fully marine).

  7. Subseafloor microbial communities in hydrogen-rich vent fluids from hydrothermal systems along the Mid-Cayman Rise.

    Science.gov (United States)

    Reveillaud, Julie; Reddington, Emily; McDermott, Jill; Algar, Christopher; Meyer, Julie L; Sylva, Sean; Seewald, Jeffrey; German, Christopher R; Huber, Julie A

    2016-06-01

    Warm fluids emanating from hydrothermal vents can be used as windows into the rocky subseafloor habitat and its resident microbial community. Two new vent systems on the Mid-Cayman Rise each exhibits novel geologic settings and distinctively hydrogen-rich vent fluid compositions. We have determined and compared the chemistry, potential energy yielding reactions, abundance, community composition, diversity, and function of microbes in venting fluids from both sites: Piccard, the world's deepest vent site, hosted in mafic rocks; and Von Damm, an adjacent, ultramafic-influenced system. Von Damm hosted a wider diversity of lineages and metabolisms in comparison to Piccard, consistent with thermodynamic models that predict more numerous energy sources at ultramafic systems. There was little overlap in the phylotypes found at each site, although similar and dominant hydrogen-utilizing genera were present at both. Despite the differences in community structure, depth, geology, and fluid chemistry, energetic modelling and metagenomic analysis indicate near functional equivalence between Von Damm and Piccard, likely driven by the high hydrogen concentrations and elevated temperatures at both sites. Results are compared with hydrothermal sites worldwide to provide a global perspective on the distinctiveness of these newly discovered sites and the interplay among rocks, fluid composition and life in the subseafloor. © 2015 The Authors. Environmental Microbiology published by Society for Applied Microbiology and John Wiley & Sons Ltd.

  8. A Novel Algorithm for Optimal Operation of Hydrothermal Power Systems under Considering the Constraints in Transmission Networks

    Directory of Open Access Journals (Sweden)

    Thang Trung Nguyen

    2018-01-01

    Full Text Available This paper proposes an effective novel cuckoo search algorithm (ENCSA in order to enhance the operation capacity of hydrothermal power systems, considering the constraints in the transmission network, and especially to overcome optimal power flow (OPF problems. This proposed algorithm is developed on the basis of the conventional cuckoo search algorithm (CSA by two modified techniques: the first is the self-adaptive technique for generating the second new solutions via discovery of alien eggs, and the second is the high-quality solutions based on a selection technique to keep the best solutions among all new and old solutions. These techniques are able to expand the search zone to overcome the local optimum trap and are able to improve the optimal solution quality and convergence speed as well. Therefore, the proposed method has significant impacts on the searching performances. The efficacy of the proposed method is investigated and verified using IEEE 30 and 118 buses systems via numerical simulation. The obtained results are compared with the conventional cuckoo search algorithm (CCSA and the modified cuckoo search algorithm (MCSA. As a result, the proposed method can overcome the OPF of hydrothermal power systems better than the conventional ones in terms of the optimal solution quality, convergence speed, and high success rate.

  9. Contribution to the operating energy planning of hydrothermal power systems; Contribuicao ao planejamento da operacao energetica de sistemas hidrotermicos de potencia

    Energy Technology Data Exchange (ETDEWEB)

    Carneiro, Adriano Alber de Franca Mendes

    1991-08-01

    This work treats of the problem of the planning of the energy operation of hydrothermal power systems, gone back to those with predominance of hydraulic generation, as it is the case of the Brazilian system. The work makes an analysis of the problem of the planning of the energy operation of systems hydrothermal leaving of the concepts and nature of this problem. Their inherent difficulties are shown and they come the main approaches in operation in countries with predominance of hydroelectric generation. It still introduces the methodology in energy planning in Brazil being pointed their main limitations. Finally an alternative model for the planning of the energy operation of the system brazilian hydrothermal, based on the made studies is also presented.

  10. The value of prior knowledge in machine learning of complex network systems.

    Science.gov (United States)

    Ferranti, Dana; Krane, David; Craft, David

    2017-11-15

    Our overall goal is to develop machine-learning approaches based on genomics and other relevant accessible information for use in predicting how a patient will respond to a given proposed drug or treatment. Given the complexity of this problem, we begin by developing, testing and analyzing learning methods using data from simulated systems, which allows us access to a known ground truth. We examine the benefits of using prior system knowledge and investigate how learning accuracy depends on various system parameters as well as the amount of training data available. The simulations are based on Boolean networks-directed graphs with 0/1 node states and logical node update rules-which are the simplest computational systems that can mimic the dynamic behavior of cellular systems. Boolean networks can be generated and simulated at scale, have complex yet cyclical dynamics and as such provide a useful framework for developing machine-learning algorithms for modular and hierarchical networks such as biological systems in general and cancer in particular. We demonstrate that utilizing prior knowledge (in the form of network connectivity information), without detailed state equations, greatly increases the power of machine-learning algorithms to predict network steady-state node values ('phenotypes') and perturbation responses ('drug effects'). Links to codes and datasets here: https://gray.mgh.harvard.edu/people-directory/71-david-craft-phd. dcraft@broadinstitute.org. Supplementary data are available at Bioinformatics online.

  11. Numerical Modeling of the Hydrothermal System at East Pacific Rise 9°50'N Including Anhydrite Precipitation

    Science.gov (United States)

    Kolandaivelu, K. P.; Lowell, R. P.

    2015-12-01

    To better understand the effects of anhydrite precipitation on mid-ocean ridge hydrothermal systems, we conducted 2-D numerical simulations of two-phase hydrothermal circulation in a NaCl-H2O fluid at the East Pacific Rise 9°50'N. The simulations were constrained by key observational thermal data and seismicity that suggests the fluid flow is primarily along axis with recharge focused into a small zone near a 4th order discontinuity. The simulations considered an open-top square box with a fixed seafloor pressure of 25 MPa, and nominal seafloor temperature of 10 °C. The sides of the box were assumed to be impermeable and insulated. We considered two models: a homogeneous model with a permeability of 10-13 m2 and a heterogeneous model in which layer 2A extrusives were given a higher permeability. Both models had a fixed bottom temperature distribution and initial porosity of 0.1. Assuming that anhydrite precipitation resulted from the decrease in solubility with increasing temperature as downwelling fluid gets heated, we calculated the rate of porosity decrease and sealing times in each cell at certain time snapshots in the simulations. The results showed that sealing would occur most rapidly in limited regions near the base of the high-temperature plumes, where complete sealing could occur on decadal time scales. Though more detailed analysis is needed, it appeared that the areas of rapid sealing would likely have negligible impact on the overall circulation pattern and hydrothermal vent temperatures. The simulations also indicated that sealing due to anhydrite precipitation would occur more slowly at the margins of the ascending plumes. The sealing times in the deep recharge zone determined in these simulations were considerably greater than estimated from 1D analytical calculations, suggesting that with a 2D model, focused recharge at the EPR 9°50'N site may occur, at least on a decadal time scale.

  12. Fluid geochemistry of hydrothermal systems in the Arica-Parinacota, Tarapacá and Antofagasta regions (northern Chile)

    Science.gov (United States)

    Tassi, F.; Aguilera, F.; Darrah, T.; Vaselli, O.; Capaccioni, B.; Poreda, R. J.; Delgado Huertas, A.

    2010-04-01

    We investigate the chemical and isotopic composition of water and gas thermal discharges from six hydrothermal systems in the Tarapacà and Antofagasta regions (northern Chile): Surire, Puchuldiza-Tuja, Pampa Lirima, Pampa Apacheta, El Tatio and Torta de Tocorpuri, to determine the chemical-physical conditions at the fluid source. The chemical facies of the thermal discharges vary from Na +-Cl - (El Tatio, Puchuldiza-Tuja and part of Surire where SO 42--rich waters also occur) to Na +(Ca 2+)-Cl -(SO 42-) (Pampa Lirima), Ca 2+-SO 42-(HCO 3-) (Torta de Tocorpuri) and Ca 2+-SO 42- (Pampa Apacheta). The gas seeps are characterized by the dominance of CO 2, H 2S and CH 4 with N 2/Ar ratios that occasionally are up to 450. Significant amounts of SO 2 and HCl are present at Pampa Apacheta. Water and gas geothermometry suggests that El Tatio and Puchuldiza-Tuja fluid reservoirs have relatively high reservoir equilibrium temperature (up to 270 °C). Gases from Pampa Apacheta apparently equilibrated at unusually high temperature for hydrothermal fluids (up to 350 °C), being likely related to an active magmatic system, as testified by the presence of highly acidic gas compounds such as SO 2 and HCl. On the contrary, low equilibrium temperatures were calculated for the Surire fluids (El Tatio, Pampa Apacheta, Surire and Puchuldiza-Tuja can be regarded as the most promising areas and deserve more detailed geological investigations.

  13. Multi-Sensor Mapping of Diffuse Degassing of C-O-H Compounds in Terrestrial Hydrothermal Systems

    Science.gov (United States)

    Schwandner, F. M.; Shock, E. L.

    2004-12-01

    and partially map a previously-inferred active lineament in the Obsidian Pool area. In addition, reduced gas data are yielding areal ratio distributions of CO/CO2, H2/CH4, and CO/CH4, that may be indicative of reactions such as the catalytic hydrogenation of CO2 (Sabatier-Process) and of CO (Fischer-Tropsch-Process) within the shallow hydrothermal system. Barberi & Carapezza (1994). Bull. Volcanol. 56(5): 335-342. Brombach, et al. (2001). Geophys. Res. Lett. 28(1): 69-72. Crenshaw et al. (1982). Nature 300: 345-346. Chiodini et al. (1996). Bull. Volcanol. 58(1): 41-50. Schwandner et al. (2004). JGR D 109: D04301, doi:10.1029/2003JD003890. Werner & Brantley (2004) JGR B 105: 10,831-10,846. Werner et al. (2003). Earth Planet. Sci. Lett. 210: 561-577. Williams (1985). Science 229(4713): 551-553. Williams-Jones et al. (2000). Bull. Volcanol. 62: 130-142.

  14. A Palaeoproterozoic multi-stage hydrothermal alteration system at Nalunaq gold deposit, South Greenland

    DEFF Research Database (Denmark)

    Bell, Robin-Marie; Kolb, Jochen; Waight, Tod Earle

    2017-01-01

    Nalunaq is an orogenic, high gold grade deposit situated on the Nanortalik Peninsula, South Greenland. Mineralisation is hosted in shear zone-controlled quartz veins, located in fine- and medium-grained amphibolite. The deposit was the site of Greenland’s only operating metalliferous mine until its......-tourmaline-titanite), which is best developed in areas of exceptionally high gold grades. Aplite dykes dated to ca. 1762 Ma cross-cut the gold-quartz veins, providing a minimum age for mineralisation. A hydrothermal calcite-titanite alteration assemblage is dated to ca. 1766 Ma; however, this alteration is highly isolated...

  15. Detection of hydrothermal aging in Cured-In-Place Pipes (CIPP) based on microwave system

    OpenAIRE

    Manavipour, Maryam; Sklarczyk, Christoph; SZIELASKO, Klaus; Kurz, Jochen Horst; Boller, Christian

    2016-01-01

    Pipe rehabilitation by means of trenchless techniques has been performed for more than 40 years already. Cured-in-place pipe (CIPP) is a trenchless method to repair damaged pipelines by inserting a new liner of polymer composite inside the existing host pipe. Since these liners are exposed to water at different temperature after installation for a long time, the purpose of a study was to investigate the effect of hydrothermal aging on CIPP samples and how this effect can be assessed by means ...

  16. Towards an understanding of the high-temperature, high-salinity part of magmatic-hydrothermal systems

    Science.gov (United States)

    Driesner, T.

    2003-04-01

    In situ observations of fluid state and composition, fluid-rock interaction and flow characteristics in active magmatic-hydrothermal systems is restricted to wells in the upper, i.e. epithermal or geothermal environments. Our knowledge about the deeper parts therefore comes from exposed fossil examples. Up to very recently, the temperature, pressure and fluid evolution could only be inferred from standard petrological and fluid inclusion results. With the advent of quantitative multi-element analysis by LA-ICPMS of fluid inclusions, "hard" constraints on the fluid evolution in complex fossil systems can now be obtained and in ideal cases processes such as ore precipitation by fluid mixing or cooling can be distinguished. While such field-based results moved our understanding of the processes at given points in the systems to a new level of detail, the dynamics of the underlying hydrodynamic and chemical processes can only be inferred quite vaguely and crucial tests of these models are frequently impossible. Worse, such "geological" interpretations cannot distinguish between physically possible and impossible hydrodynamic scenarios because of the highly nonlinear and coupled nature of governing equations and physical fluid properties. A test of such a geological model and the understanding of the dynamics of such a system can only be achieved by forward modeling. This requires two essential components: (1) a simulation tool that is able to handle both flexible geometries with "geologically realistic" detail and material and flow properties with variations of several orders of magnitude, and (2) a comprehensive description of fluid properties over very wide ranges of T, P, and X. If chemical fluid-rock interactions play an important role, a versatile thermodynamic formalism for accurate solute properties even in the near-critical region is required. The Fluids and Ore Deposits Group at ETH has recently developed such a simulation tool (see S. Geiger et al., this

  17. Health Systems Reconstruction Among Remote Populations: Trends From Rural Liberia Prior to the Ebola Epidemic

    OpenAIRE

    Kentoffio, Katherine

    2015-01-01

    Background: The weak health network in post-war Liberia is likely a primary contributor to the unprecedented 2014 Ebola outbreak in West Africa. This paper seeks to assess gaps in the health system prior to the epidemic by evaluating changes in access to maternal and child health services in a remote region compared to rural averages from 2007-2013. Methods: We conducted a two-staged cluster survey in 2012 in the remote district of Konobo, Liberia. Our primary outcomes of interest ...

  18. Comparison of navigation in ROV and AUV surveys with high frequency acoustic systems in deep seafloor hydrothermal environments

    Science.gov (United States)

    Le Bas, T.; Murton, B. J.; Webber, A.

    2013-12-01

    As high frequency acoustic waves are highly attenuated over short distances it is essential that all high resolution surveys must be conducted close to the seafloor. In the deep ocean (over 2500m) this means that the location of a survey vehicle compared to a ship's well constrained position has some significant issues. This paper compares various methods and results of a ROV and AUV multibeam survey over the Mid Cayman Spreading Centre hydrothermal vent sites. The results show the difficulties encountered in processing when navigation uncertainty is considerably higher than the resolution of survey data. For example the best ROV positional accuracy in 5000m water depth is about 10m using USBL, whereas high-frequency multibeam systems used on ROVs and AUVs has a resolution of 50cm or better. AUV location has different navigational challenges. While the continuous movement of an AUV during surveying provides a constant that can be modelled and used to correct any relative locational uncertainty, absolute positioning at sufficient precision and accuracy for swath mapping remains problematic. In response to these uncertainties, we present a method of navigation correction that provides high-precision, internally consistent positioning and external accuracy. Using features identified on overlapping near-bottom multibeam bathymetry swathes, a correlation can be made between adjacent survey tracks. Internal consistency of the survey can be achieved by matching contours of these features by warping adjacent swaths to fit one another. We find that contour matching is extremely effective as the human eye is particularly good at identifying similar feature patterns, and the contours allow control points to be identified at sufficient spatial resolution to match that of the swath data, and then co-located with lower resolution shipboard swath maps. Examples of swath data from a variety of AUV and ROV systems will be presented including those from the deepest hydrothermal vent

  19. Hydrothermal synthesis of fine oxide powders

    Indian Academy of Sciences (India)

    The authors describe. hydrothermal decomposition,; hydrothermal metal oxidation,; hydrothermal reaction,; hydrothermal precipitation and hydrothermal hydrolysis,; hydrothermal electrochemical,; reactive electrode submerged arc,; hydrothermal microwave,; hydrothermal sonochemical,. etc and also ideal and real powders ...

  20. Prospecting for Modern and Ancient Hydrothermal Systems on Mars:Implications for Astrobiology and the Exploration for Past or Present Life

    Science.gov (United States)

    Farmer, J. D.

    2002-12-01

    Hydrothermal systems are regarded to be prime targets in the search for a fossil record on Mars because they provide 1) Localized environments for sustaining high rates of microbial productivity and 2) Co-existing high rates of mineralization (chemical precipitation) favorable for capturing and preserving microbial biosignatures. Hydrothermal environments may have been widespread on Mars early in the planet's history. Previous authors have described a number of potential hydrothermal sites on Mars which may be grouped into the following geologic associations: 1) Channels and chaos terranes associated with volcanic heat sources (e.g. Dao Vallis - Hadriaca Patera and chaos at the base of Apollonaris), 2) Channel networks and modified central uplifts associated with large impact craters, 3) Channels and alteration zones associated with rift fracture systems and dike swarms (e.g. Cerberus volcanic plains, Elysium), 4) Channel systems in periglacial environments related to potential subglacial volcanic heat sources 5) Mineral signatures (coarse-grained hematite) associated with ancient lacustrine basins and extensional geologic features (e.g. Terra Meridian basin, floor of Candor Chasma, central Aram chaos) and 6) modern seeps and runoff channels found on steep, northward facing slopes at high latitudes. In addition, some attribute a hydrothermal origin to the Fe-rich carbonates of Martian meteorite, ALH 84001. In this talk I will review examples of these and related hydrothermal environments that may have been present on Mars from the perspective of terrestrial analogs and what that implies about preservation potential for fossil biosignatures. I will also discuss possible ways to test hydrothermal hypotheses that could be implemented during the next decade of Mars exploration.

  1. Thermodynamics of Fe(II)Fe(III) oxide systems I. Hydrothermal Fe3O4

    Science.gov (United States)

    Bartel, J.J.; Westrum, E.F.; Haas, J.L.

    1976-01-01

    The heat capacity of a hydrothermally-prepared polycrystalline sample of Fe3O4 was measured from 53 to 350 K, primarily to study the thermophysics of the Verwey transitions. Although the bifurcation of the transition was confirmed, the sample was found to contain traces of manganese. The observed transition temperatures of 117.0 and 123.0 K are 3.7 and 4.2 K higher respectively than those found in pure Fe3O4. Ancillary analytical results are consistent and indicate a stoichiometry of Mn0.008Fe2.992O4 for this material. Characteristics in the transition region are ascribed to dopant effects. ?? 1976.

  2. Weapon System Requirements: Detailed Systems Engineering Prior to Product Development Positions Programs for Success

    Science.gov (United States)

    2016-11-01

    report on systems engineering status of each major acquisition program in the department’s annual budget request. What GAO Found GAO’s analysis of...more detailed descriptions of the system design are established in what systems engineering literature refers to as configuration baselines. Within...does not necessarily mean that problems are unavoidable. Rather, the ensuing systems engineering effort, if timely and sufficiently vigorous, can

  3. Fluid transfer and vein thickness distribution in high and low temperature hydrothermal systems at shallow crustal level in southern Tuscany (Italy

    Directory of Open Access Journals (Sweden)

    Francesco Mazzarini

    2014-06-01

    Full Text Available Geometric analysis of vein systems hosted in upper crustal rocks and developed in high and low temperature hydrothermal systems is presented. The high temperature hydrothermal system consists of tourmaline-rich veins hosted within the contact aureole of the upper Miocene Porto Azzurro pluton in the eastern Elba Island. The low temperature hydrothermal system consists of calcite-rich veins hosted within the Oligocene sandstones of the Tuscan Nappe, exposed along the coast in southern Tuscany. Vein thickness distribution is here used as proxy for inferring some hydraulic properties (transmissivity of the fluid circulation at the time of veins’ formation. We derive estimations of average thickness of veins by using the observed distributions. In the case of power law thickness distributions, the lower the scaling exponent of the distribution the higher the overall transmissivity. Indeed, power law distributions characterised by high scaling exponents have transmissivity three order of magnitude lower than negative exponential thickness distribution. Simple observations of vein thickness may thus provides some clues on the transmissivity in hydrothermal systems.

  4. Spatial and temporal geochemical trends in the hydrothermal system of Yellowstone National Park: Inferences from river solute fluxes

    Science.gov (United States)

    Hurwitz, S.; Lowenstern, J. B.; Heasler, H.

    2007-01-01

    We present and analyze a chemical dataset that includes the concentrations and fluxes of HCO3-, SO42-, Cl-, and F- in the major rivers draining Yellowstone National Park (YNP) for the 2002-2004 water years (1 October 2001 - 30 September 2004). The total (molar) flux in all rivers decreases in the following order, HCO3- > Cl- > SO42- > F-, but each river is characterized by a distinct chemical composition, implying large-scale spatial heterogeneity in the inputs of the various solutes. The data also display non-uniform temporal trends; whereas solute concentrations and fluxes are nearly constant during base-flow conditions, concentrations decrease, solute fluxes increase, and HCO3-/Cl-, and SO42-/Cl- increase during the late-spring high-flow period. HCO3-/SO42- decreases with increasing discharge in the Madison and Falls Rivers, but increases with discharge in the Yellowstone and Snake Rivers. The non-linear relations between solute concentrations and river discharge and the change in anion ratios associated with spring runoff are explained by mixing between two components: (1) a component that is discharged during base-flow conditions and (2) a component associated with snow-melt runoff characterized by higher HCO3-/Cl- and SO42-/Cl-. The fraction of the second component is greater in the Yellowstone and Snake Rivers, which host lakes in their drainage basins and where a large fraction of the solute flux follows thaw of ice cover in the spring months. Although the total river HCO3- flux is larger than the flux of other solutes (HCO3-/Cl- ??? 3), the CO2 equivalent flux is only ??? 1% of the estimated emission of magmatic CO2 soil emissions from Yellowstone. No anomalous solute flux in response to perturbations in the hydrothermal system was observed, possibly because gage locations are too distant from areas of disturbance, or because of the relatively low sampling frequency. In order to detect changes in river hydrothermal solute fluxes, sampling at higher

  5. Free energy distribution and hydrothermal mineral precipitation in Hadean submarine alkaline vent systems: Importance of iron redox reactions under anoxic conditions

    Science.gov (United States)

    Shibuya, Takazo; Russell, Michael J.; Takai, Ken

    2016-02-01

    Thermodynamic calculations of mixing between hypothetical seawater and hydrothermal fluid in the Hadean deep ocean were carried out to predict saturation states of mineral precipitates and redox reactions that could occur in Hadean submarine alkaline hydrothermal systems associated with the serpentinization of ultramafic rocks. In the calculations, the seawater was assumed to be weakly acidic (pH = 5.5) and to include carbon dioxide, ferrous iron and silica, with or without nitrate, while the Hadean hydrothermal fluid was assumed to be highly alkaline (pH = 11) and to contain abundant molecular hydrogen, methane and bisulfide, based on the Archean geologic record, the modern low-temperature alkaline hydrothermal vent fluid (Lost City field), and experimental and theoretical considerations. The modeling indicates that potential mineral precipitates in the mixing zone (hydrothermal chimney structures) could consist mainly of iron sulfides but also of ferrous serpentine and brucite, siderite, and ferric iron-bearing minerals such as goethite, hematite and/or magnetite as minor phases. The precipitation of ferric iron-bearing minerals suggests that chemical iron oxidation would be made possible by pH shift even under anoxic condition. In the mixing zone, comprising an inorganic barrier precipitated at the interface of the two contrasting solutions, various redox reactions release free energy with the potential to drive endergonic reactions, assuming the involvement of coupling inorganic protoenzymes. Hydrogenotrophic methanogenesis and acetogenesis - long considered the most ancient forms of biological energy metabolisms - are able to achieve higher maximum energy yield (>0.5 kJ/kg hydrothermal fluid) than those in the modern serpentinization-associated seafloor hydrothermal systems (e.g., Kairei field). Furthermore, the recently proposed methanotrophic acetogenesis pathway was also thermodynamically investigated. It is known that methanotrophic acetogenesis would

  6. COINTEGRATION RELATIONSHIPS TO ESTIMATE THE MARGINAL COST OF DEFICIT IN PLANNING A HYDROTHERMAL SYSTEM: THE CASE OF BRAZIL

    Directory of Open Access Journals (Sweden)

    Lucio Guido Tapia Carpio

    2014-04-01

    Full Text Available The aim of this study is to analyze the behavior of gross domestic product (GDP compared to electricity consumption in Brazil to estimate the curve of deficit marginal cost. The deficit cost is used as exogenous parameter in the chain of models for planning the operation and expansion of a hydrothermal system as part of the total cost of operation. The results show a cointegration relationship between GDP and electricity consumption; therefore, there is a long-term equilibrium relationship between GDP and electricity consumption. This relationship is used to estimate the curve of deficit marginal cost. The possible short-term imbalance can be mitigated using the vector error correction model (VEC.

  7. A multiobjective interval programming model for wind-hydrothermal power system dispatching using 2-step optimization algorithm.

    Science.gov (United States)

    Ren, Kun; Jihong, Qu

    2014-01-01

    Wind-hydrothermal power system dispatching has received intensive attention in recent years because it can help develop various reasonable plans to schedule the power generation efficiency. But future data such as wind power output and power load would not be accurately predicted and the nonlinear nature involved in the complex multiobjective scheduling model; therefore, to achieve accurate solution to such complex problem is a very difficult task. This paper presents an interval programming model with 2-step optimization algorithm to solve multiobjective dispatching. Initially, we represented the future data into interval numbers and simplified the object function to a linear programming problem to search the feasible and preliminary solutions to construct the Pareto set. Then the simulated annealing method was used to search the optimal solution of initial model. Thorough experimental results suggest that the proposed method performed reasonably well in terms of both operating efficiency and precision.

  8. A Multiobjective Interval Programming Model for Wind-Hydrothermal Power System Dispatching Using 2-Step Optimization Algorithm

    Directory of Open Access Journals (Sweden)

    Kun Ren

    2014-01-01

    Full Text Available Wind-hydrothermal power system dispatching has received intensive attention in recent years because it can help develop various reasonable plans to schedule the power generation efficiency. But future data such as wind power output and power load would not be accurately predicted and the nonlinear nature involved in the complex multiobjective scheduling model; therefore, to achieve accurate solution to such complex problem is a very difficult task. This paper presents an interval programming model with 2-step optimization algorithm to solve multiobjective dispatching. Initially, we represented the future data into interval numbers and simplified the object function to a linear programming problem to search the feasible and preliminary solutions to construct the Pareto set. Then the simulated annealing method was used to search the optimal solution of initial model. Thorough experimental results suggest that the proposed method performed reasonably well in terms of both operating efficiency and precision.

  9. Selected geothermal resources data: hydrothermal convection systems in the states of Alaska, Arizona, California, Colorado, Hawaii, Idaho, Montana, Nevada, New Mexico, Oregon, Utah, Washington, and Wyoming

    Energy Technology Data Exchange (ETDEWEB)

    Renner, J.L.

    1976-02-01

    Data collected as part of the U.S. Geological Survey's research and land classification programs, from professional publications, and industry sources has been compiled in computer format. Location, surface manifestations, chemistry, physical properties, exploratory and development work, and references pertinent to 290 hydrothermal convection systems comprise the data base.

  10. Comparing Carbonate-Depositing Hydrothermal Systems Along the Mid-Atlantic Ridge at Lost City Hydrothermal Field and Along the Rio Grande rift in the Southwestern US: Geochemistry, Geomicrobiology and Mineralogy

    Science.gov (United States)

    Cron, B. R.; Crossey, L.; Hall, J.; Takacs-Vesbach, C.; Dahm, K.; Northup, D.; Karlstrom, K.

    2008-12-01

    Both continental and marine rift settings are characterized by hydrothermal vents (smokers) that include important components of mantle-derived "endogenic" fluids. These fluids ascend along extensional faults and provide unique biologic settings. We hypothesize that deep crustal processes support near-surface metabolic strategies by delivering chemically reduced constituents to partially oxidized surface environments. Lost City hydrothermal field, a marine vent system located 15 km west of the Mid-Atlantic ridge, exhibits a range of temperatures (40 to 75°C), pH (9-9.8), and mineral compositions (carbonate rather than sulfide-dominated) that were originally thought to be non-existent in marine vent systems. Travertine depositing CO2 springs within the Rio Grande rift, NM exhibit striking similarities in many respects to vents in Lost City. Previous research has already determined the importance of methanogenic and sulfur metabolizing microorganisms in carbonate structures at Lost City. Phylogenetic analysis of 16S rRNA genes from a terrestrial CO2 spring was performed. In addition, cells from bacteria and fungi were also cultured with oligotrophic media. Both archaeal phylotypes from the terrestrial spring grouped within Marine Group I of the Crenarchaeota, a clade dominated by sequences from hydrothermal marine vents, including some from Lost City. We will report comparative analyses of sequences from Lost City and both cultured and environmental clone libraries from the terrestrial spring using UniFrac. Geochemical modeling of data (water and gas chemistry from both locations) is used to rank the energy available for dozens of metabolic reactions. SEM and microprobe data are presented to compare mineral compositions. Our results will be discussed in respect to the tectonic setting, microbial community distributions, and the geochemical composition and textural properties of the carbonates that are precipitated in each of these systems.

  11. Effects of Prior Knowledge in Mathematics on Learner-Interface Interactions in a Learning-by-Teaching Intelligent Tutoring System

    Science.gov (United States)

    Bringula, Rex P.; Basa, Roselle S.; Dela Cruz, Cecilio; Rodrigo, Ma. Mercedes T.

    2016-01-01

    This study attempted to determine the influence of prior knowledge in mathematics of students on learner-interface interactions in a learning-by-teaching intelligent tutoring system. One hundred thirty-nine high school students answered a pretest (i.e., the prior knowledge in mathematics) and a posttest. In between the pretest and posttest, they…

  12. Carbon geochemistry of serpentinites in the Lost City Hydrothermal System (30°N, MAR)

    Science.gov (United States)

    Delacour, Adélie; Früh-Green, Gretchen L.; Bernasconi, Stefano M.; Schaeffer, Philippe; Kelley, Deborah S.

    2008-08-01

    The carbon geochemistry of serpentinized peridotites and gabbroic rocks recovered at the Lost City Hydrothermal Field (LCHF) and drilled at IODP Hole 1309D at the central dome of the Atlantis Massif (Mid-Atlantic Ridge, 30°N) was examined to characterize carbon sources and speciation in oceanic basement rocks affected by long-lived hydrothermal alteration. Our study presents new data on the geochemistry of organic carbon in the oceanic lithosphere and provides constraints on the fate of dissolved organic carbon in seawater during serpentinization. The basement rocks of the Atlantis Massif are characterized by total carbon (TC) contents of 59 ppm to 1.6 wt% and δ 13C TC values ranging from -28.7‰ to +2.3‰. In contrast, total organic carbon (TOC) concentrations and isotopic compositions are relatively constant (δ 13C TOC: -28.9‰ to -21.5‰) and variations in δ 13C TC reflect mixing of organic carbon with carbonates of marine origin. Saturated hydrocarbons extracted from serpentinites beneath the LCHF consist of n-alkanes ranging from C 15 to C 30. Longer-chain hydrocarbons (up to C 40) are observed in olivine-rich samples from the central dome (IODP Hole 1309D). Occurrences of isoprenoids (pristane, phytane and squalane), polycyclic compounds (hopanes and steranes) and higher relative abundances of n-C 16 to n-C 20 alkanes in the serpentinites of the southern wall suggest a marine organic input. The vent fluids are characterized by high concentrations of methane and hydrogen, with a putative abiotic origin of hydrocarbons; however, evidence for an inorganic source of n-alkanes in the basement rocks remains equivocal. We propose that high seawater fluxes in the southern part of the Atlantis Massif likely favor the transport and incorporation of marine dissolved organic carbon and overprints possible abiotic geochemical signatures. The presence of pristane, phytane and squalane biomarkers in olivine-rich samples associated with local faults at the central

  13. A multidisciplinary approach to quantify the permeability of the Whakaari/White Island volcanic hydrothermal system (Taupo Volcanic Zone, New Zealand)

    Science.gov (United States)

    Heap, Michael J.; Kennedy, Ben M.; Farquharson, Jamie I.; Ashworth, James; Mayer, Klaus; Letham-Brake, Mark; Reuschlé, Thierry; Gilg, H. Albert; Scheu, Bettina; Lavallée, Yan; Siratovich, Paul; Cole, Jim; Jolly, Arthur D.; Baud, Patrick; Dingwell, Donald B.

    2017-02-01

    Our multidisciplinary study aims to better understand the permeability of active volcanic hydrothermal systems, a vital prerequisite for modelling and understanding their behaviour and evolution. Whakaari/White Island volcano (an active stratovolcano at the north-eastern end of the Taupo Volcanic Zone of New Zealand) hosts a highly reactive hydrothermal system and represents an ideal natural laboratory to undertake such a study. We first gained an appreciation of the different lithologies at Whakaari and (where possible) their lateral and vertical extent through reconnaissance by land, sea, and air. The main crater, filled with tephra deposits, is shielded by a volcanic amphitheatre comprising interbedded lavas, lava breccias, and tuffs. We deployed field techniques to measure the permeability and density/porosity of (1) > 100 hand-sized sample blocks and (2) layered unlithified deposits in eight purpose-dug trenches. Our field measurements were then groundtruthed using traditional laboratory techniques on almost 150 samples. Our measurements highlight that the porosity of the materials at Whakaari varies from ∼ 0.01 to ∼ 0.7 and permeability varies by eight orders of magnitude (from ∼ 10-19 to ∼ 10-11 m2). The wide range in physical and hydraulic properties is the result of the numerous lithologies and their varied microstructures and alteration intensities, as exposed by a combination of macroscopic and microscopic (scanning electron microscopy) observations, quantitative mineralogical studies (X-ray powder diffraction), and mercury porosimetry. An understanding of the spatial distribution of lithology and alteration style/intensity is therefore important to decipher fluid flow within the Whakaari volcanic hydrothermal system. We align our field observations and porosity/permeability measurements to construct a schematic cross section of Whakaari that highlights the salient findings of our study. Taken together, the alteration typical of a volcanic

  14. Geology and mineralogy of the Auki Crater, Tyrrhena Terra, Mars: A possible post impact-induced hydrothermal system

    Science.gov (United States)

    Carrozzo, F. G.; Di Achille, G.; Salese, F.; Altieri, F.; Bellucci, G.

    2017-01-01

    A variety of hydrothermal environments have been documented in terrestrial impact structures. Due to both past water interactions and meteoritic bombardment on the surface of Mars, several authors have predicted various scenarios that include the formation of hydrothermal systems. Geological and mineralogical evidence of past hydrothermal activity have only recently been found on Mars. Here, we present a geological and mineralogical study of the Auki Crater using the spectral and visible imagery data acquired by the CRISM (Compact Reconnaissance Imaging Spectrometer for Mars), CTX (Context Camera) and HiRISE (High Resolution Imaging Science Experiment) instruments on board the NASA MRO mission. The Auki Crater is a complex crater that is ∼38 km in diameter located in Tyrrhena Terra (96.8°E and 15.7°S) and shows a correlation between its mineralogy and morphology. The presence of minerals, such as smectite, silica, zeolite, serpentine, carbonate and chlorite, associated with morphological structures, such as mounds, polygonal terrains, fractures and veins, suggests that the Auki Crater may have hosted a post impact-induced hydrothermal system. Although the distribution of hydrated minerals in and around the central uplift and the stratigraphic relationships of some morphological units could also be explained by the excavation and exhumation of carbonate-rich bedrock units as a consequence of crater formation, we favor the hypothesis of impact-induced hydrothermal circulation within fractures and subsequent mineral deposition. The hydrothermal system could have been active for a relatively long period of time after the impact, thus producing a potential transient habitable environment. It must be a spectrally neutral component to emphasize the spectral features; It is an average of spectra taken in the same column of the numerator spectra to correct the residual instrument artifacts and reduce detector noise that changes from column to column; It must be taken in

  15. Geocomputation over Hybrid Computer Architecture and Systems: Prior Works and On-going Initiatives at UARK

    Science.gov (United States)

    Shi, X.

    2015-12-01

    As NSF indicated - "Theory and experimentation have for centuries been regarded as two fundamental pillars of science. It is now widely recognized that computational and data-enabled science forms a critical third pillar." Geocomputation is the third pillar of GIScience and geosciences. With the exponential growth of geodata, the challenge of scalable and high performance computing for big data analytics become urgent because many research activities are constrained by the inability of software or tool that even could not complete the computation process. Heterogeneous geodata integration and analytics obviously magnify the complexity and operational time frame. Many large-scale geospatial problems may be not processable at all if the computer system does not have sufficient memory or computational power. Emerging computer architectures, such as Intel's Many Integrated Core (MIC) Architecture and Graphics Processing Unit (GPU), and advanced computing technologies provide promising solutions to employ massive parallelism and hardware resources to achieve scalability and high performance for data intensive computing over large spatiotemporal and social media data. Exploring novel algorithms and deploying the solutions in massively parallel computing environment to achieve the capability for scalable data processing and analytics over large-scale, complex, and heterogeneous geodata with consistent quality and high-performance has been the central theme of our research team in the Department of Geosciences at the University of Arkansas (UARK). New multi-core architectures combined with application accelerators hold the promise to achieve scalability and high performance by exploiting task and data levels of parallelism that are not supported by the conventional computing systems. Such a parallel or distributed computing environment is particularly suitable for large-scale geocomputation over big data as proved by our prior works, while the potential of such advanced

  16. Isolation and Structural Characterization of Lignin from Cotton Stalk Treated in an Ammonia Hydrothermal System

    Science.gov (United States)

    Kang, Sumin; Xiao, Lingping; Meng, Lingyan; Zhang, Xueming; Sun, Runcang

    2012-01-01

    To investigate the potential for the utilization of cotton stalk, ammonia hydrothermal treatment was applied to fractionate the samples into aqueous ammonia-soluble and ammonia-insoluble portions. The ammonia-soluble portion was purified to yield lignin fractions. The lignin fractions obtained were characterized by wet chemistry (carbohydrate analysis) and spectroscopy methods (FT-IR, 13C and 1H-13C HSQC NMR spectroscopy) as well as gel permeation chromatography (GPC). The results showed that the cotton stalk lignin fractions were almost absent of neutral sugars (0.43%–1.29%) and had relatively low average molecular weights (1255–1746 g/mol). The lignin fractions belonged to typical G-S lignin, which was composed predominately of G-type units (59%) and noticeable amounts of S-type units (40%) together with a small amount of H-type units (~1%). Furthermore, the ammonia-extractable lignin fractions were mainly composed of β-O-4′ inter-unit linkages (75.6%), and small quantities of β-β′ (12.2%), together with lower amounts of β-5′ carbon-carbon linkages (7.4%) and p-hydroxycinnamyl alcohol end groups. PMID:23203120

  17. Permeability of the Lucky Strike deep-sea hydrothermal system: Constraints from the poroelastic response to ocean tidal loading

    Science.gov (United States)

    Barreyre, Thibaut; Escartin, Javier; Sohn, Robert; Cannat, Mathilde

    2014-12-01

    We use the time delay between tidal loading and the induced subsurface flow response to constrain the poroelastic behavior and permeability of the Lucky Strike hydrothermal field on the Mid-Atlantic Ridge. We demonstrate that high-temperature (T > 200 °C) exit-fluid discharge records from four hydrothermal sites across the field are highly coherent with contemporaneously acquired bottom pressure records at tidal periods, with the thermal response lagging pressure by ∼155° (5.3 h) on average across all sites for the semi-diurnal (M2) frequency over a three-year observation period. In a one-dimensional poroelastic model of ocean tidal loading this phase lag corresponds to a high-permeability system where pore pressure perturbations at the seafloor rapidly propagate downward from the seafloor interface until they encounter a permeability boundary. Our results suggest that at the Lucky Strike field this tidal pumping is largely restricted to the ∼600 m thick extrusive layer (i.e., seismic layer 2A). Under a plausible set of matrix elastic parameters, the ∼5.3 h lag between pressure and exit-fluid temperature is consistent with an effective matrix permeability of ∼10-10 m2 and an average vertical flow velocity of ∼0.02 m/s within the extrusive layer. Our results argue against tidal pumping of the entire crustal section between the seafloor and the axial magma chamber (at ∼3.4 kmbsf) because this scenario requires unrealistically high effective permeabilities (∼10-9 m2) and average vertical flow velocities (∼0.15 m/s) over this depth range. Our effective permeability estimate for the extrusive layer is broadly consistent with previous results, and indicates that flow must be channeled in discrete permeable pathways (e.g., faults, fissures) that cut through the extrusive volcanic layer.

  18. Groundwater-driven temperature changes at thermal springs in response to recent glaciation: Bormio hydrothermal system, Central Italian Alps

    Science.gov (United States)

    Volpi, Giorgio; Magri, Fabien; Frattini, Paolo; Crosta, Giovanni B.; Riva, Federico

    2017-11-01

    Thermal springs are widespread in the European Alps, with hundreds of geothermal sites known and exploited. The thermal circulation and fluid outflows were examined in the area around Bormio (Central Italian Alps), where ten geothermal springs discharge from dolomite bodies located close to the regional Zebrù thrust. Water is heated in deep circulation systems and upwells vigorously at a temperature of about 40 °C. Heat and fluid transport is explored by steady and transient three-dimensional finite-element simulations taking into account the effect of the last glaciation, which in the study area was recognized to end around 11,000-12,000 years ago. The full regional model (ca. 700 km2) is discretized with a highly refined triangular finite-element planar grid. Numerical simulations suggest a reactivation of the system following the end of the Last Glacial Maximum. Results correctly simulate the observed discharge rate of ca. 2,400 L/min and the spring temperatures after ca. 13,000 years from deglaciation, and show a complete cooling of the aquifer within a period of approximately 50,000 years. Groundwater flow and temperature patterns suggest that thermal water flows through a deep system crossing both sedimentary and metamorphic lithotypes along a fracture network associated with the thrust system. This example gives insights into the influences of deep alpine structures and glaciations on groundwater circulation that control the development of many hydrothermal systems not necessarily associated with convective heat flow.

  19. Development of a Computer-Aided Diagnosis System for Early Detection of Masses Using Retrospectively Detected Cancers on Prior Mammograms

    National Research Council Canada - National Science Library

    Wei, Jun

    2006-01-01

    The goal of this project is to develop a computer-aided diagnosis (CAD) system for mass detection using advanced computer vision techniques that will be trained with retrospectively detected cancers on prior mammograms...

  20. Development of a Computer-Aided Diagnosis System for Early Detection of Masses Using Retrospectively Detected Cancers on Prior Mammograms

    National Research Council Canada - National Science Library

    Wei, Jun

    2007-01-01

    The goal of this project is to develop a computer-aided diagnosis (CAD) system for mass detection using advanced computer vision techniques that will be trained with retrospectively detected cancers on prior mammograms...

  1. Development of a Computer-Aided Diagnosis System for Early Detection of Masses Using Retrospectively Detected Cancers on Prior Mammograms

    National Research Council Canada - National Science Library

    Wei, Jun

    2005-01-01

    The goal of this project is to develop a computer-aided diagnosis (CAD) system for mass detection using advanced computer vision techniques that will be trained with retrospectively detected cancers on prior mammograms...

  2. Using virtual reality to test the regularity priors used by the human visual system

    Science.gov (United States)

    Palmer, Eric; Kwon, TaeKyu; Pizlo, Zygmunt

    2017-09-01

    Virtual reality applications provide an opportunity to test human vision in well-controlled scenarios that would be difficult to generate in real physical spaces. This paper presents a study intended to evaluate the importance of the regularity priors used by the human visual system. Using a CAVE simulation, subjects viewed virtual objects in a variety of experimental manipulations. In the first experiment, the subject was asked to count the objects in a scene that was viewed either right-side-up or upside-down for 4 seconds. The subject counted more accurately in the right-side-up condition regardless of the presence of binocular disparity or color. In the second experiment, the subject was asked to reconstruct the scene from a different viewpoint. Reconstructions were accurate, but the position and orientation error was twice as high when the scene was rotated by 45°, compared to 22.5°. Similarly to the first experiment, there was little difference between monocular and binocular viewing. In the third experiment, the subject was asked to adjust the position of one object to match the depth extent to the frontal extent among three objects. Performance was best with symmetrical objects and became poorer with asymmetrical objects and poorest with only small circular markers on the floor. Finally, in the fourth experiment, we demonstrated reliable performance in monocular and binocular recovery of 3D shapes of objects standing naturally on the simulated horizontal floor. Based on these results, we conclude that gravity, horizontal ground, and symmetry priors play an important role in veridical perception of scenes.

  3. Hydrothermal dolomitization of basinal deposits controlled by a synsedimentary fault system in Triassic extensional setting, Hungary

    Science.gov (United States)

    Hips, Kinga; Haas, János; Győri, Orsolya

    2016-06-01

    Dolomitization of relatively thick carbonate successions occurs via an effective fluid circulation mechanism, since the replacement process requires a large amount of Mg-rich fluid interacting with the CaCO3 precursor. In the western end of the Neotethys, fault-controlled extensional basins developed during the Late Triassic spreading stage. In the Buda Hills and Danube-East blocks, distinct parts of silica and organic matter-rich slope and basinal deposits are dolomitized. Petrographic, geochemical, and fluid inclusion data distinguished two dolomite types: (1) finely to medium crystalline and (2) medium to coarsely crystalline. They commonly co-occur and show a gradual transition. Both exhibit breccia fabric under microscope. Dolomite texture reveals that the breccia fabric is not inherited from the precursor carbonates but was formed during the dolomitization process and under the influence of repeated seismic shocks. Dolomitization within the slope and basinal succession as well as within the breccia zones of the underlying basement block is interpreted as being related to fluid originated from the detachment zone and channelled along synsedimentary normal faults. The proposed conceptual model of dolomitization suggests that pervasive dolomitization occurred not only within and near the fault zones. Permeable beds have channelled the fluid towards the basin centre where the fluid was capable of partial dolomitization. The fluid inclusion data, compared with vitrinite reflectance and maturation data of organic matter, suggest that the ascending fluid was likely hydrothermal which cooled down via mixing with marine-derived pore fluid. Thermal gradient is considered as a potential driving force for fluid flow.

  4. Experimental and theoretical investigation of the production of HCl and some metal chlorides in magmatic/hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    In the calculations we have assumed that all apatites are magmatic. The presence of chlorite and altered plagioclase within the granite and quartz-monzodiorite suggests that alteration may play a role in leading to erroneous estimates of initial melt Cl and F for 2 reasons: (1) the apatites may in fact not be magmatic in origin, but are hydrothermal, and (2) the halogen signature of magmatic apatite may be changed due to subsolidus exchange with a hydrothermal fluid. We are currently endeavoring to develop criteria for determining whether apatite composition represents earlier or later stages of magmatic-hydrothermal development.

  5. The origin of life near deep-sea hydrothermal systems during the Cambrian explosion: data from the Kyzyl Tashtyg sulphide deposit (Central Asia)

    Science.gov (United States)

    Simonov, Vladimir; Terleev, Alexander; Safonova, Inna; Kotlyarov, Alexey; Stupakov, Sergey; Tokarev, Dmitry

    2015-04-01

    On Earth the solar radiation and the hydrothermal circulation both affect life evolution. Recent extensive studies of the World Ocean have shown that the biodiversity of Earth is linked with hydrothermal activity on the oceanic floor. These deep-sea ecosystems use chemical energy, not solar radiation. In the last quarter of the XX century, a new type of hydrothermal systems, so-called black smokers, was discovered in mid-oceanic ridges. As black smokers form sulfide ores and are surrounded by abundant bio-oases or symbioses, identification of their analogues in ancient orogenic belts is necessary for studying life origin and evolution. Of special importance are problems of life associated with deep-sea hydrothermal systems acted at the Precambrian-Cambrian boundary - the time of Cambrian explosion (Maruyama et al., 2013). During that explosion life significantly evolved and diversified due to dramatic changes of Earth's environment. Consequently, the early Cambrian - late Precambrian Kyzyl Tashtyg sulphide deposit of East Tuva in the Central Asian Orogenic Belt is of special interest. This deposit was formed on the bottom of ancient back-arc deep-sea basin as a result of black smoker hydrothermal activity and is hosted by volcanogenic-sedimentary rocks altered by the high temperature solutions. The altered Kyzyl Tashtyg basalts have an amygdules (filled by albite, epidote and carbonates), contain brown-green microfossils, often attached to their walls. The microfossils are thin tubes 5 to 25 microns in diameter and 500 microns long. This tubes are empty and have straight, curved or branching shape. Chemically, the tube material is close to epidote. In consideration of microscopic dimensions, simple morphology and similarity with modern tubular microorganisms, the studied tube-shaped microfossils can be related to cyanobacteria. Almost the same fossils, associated with oceanic basalt complexes, were described earlier (Furnes et al., 2007; Mcloughlin et al., 2007

  6. Analysis of Boiler Operational Variables Prior to Tube Leakage Fault by Artificial Intelligent System

    Directory of Open Access Journals (Sweden)

    Al-Kayiem Hussain H.

    2014-07-01

    Full Text Available Steam boilers are considered as a core of any steam power plant. Boilers are subjected to various types of trips leading to shut down of the entire plant. The tube leakage is the worse among the common boiler faults, where the shutdown period lasts for around four to five days. This paper describes the rules of the Artificial Intelligent Systems to diagnosis the boiler variables prior to tube leakage occurrence. An Intelligent system based on Artificial Neural Network was designed and coded in MATLAB environment. The ANN was trained and validated using real site data acquired from coal fired power plant in Malaysia. Ninety three boiler operational variables were identified for the present investigation based on the plant operator experience. Various neural networks topology combinations were investigated. The results showed that the NN with two hidden layers performed better than one hidden layer using Levenberg-Maquardt training algorithm. Moreover, it was noticed that hyperbolic tangent function for input and output nodes performed better than other activation function types.

  7. Sm-Nd age of the Fazenda Brasileiro Gabbro, Bahia, Brazil: example of robust behavior of the Sm-Nd isotopic system under extreme hydrothermal alteration

    Energy Technology Data Exchange (ETDEWEB)

    Pimentel, Marcio M. [Brasilia Univ., DF (Brazil). Inst. de Geociencias]. E-mail: marcio@unb.br; mmp1103@terra.com.br; Silva, Maria da Gloria [Bahia Univ., Salvador (Brazil). Dept. de Geologia de Geofisica Aplicada]. E-mail: gloria@ufba.br

    2003-09-15

    The Fazenda Brasileiro gold mineralization is hosted by a gabbroic sill, intrusive into metavolcanic-metasedimentary rocks of the Rio Itapicuru Greenstone Belt, Sao Francisco Craton. The 2.05 Ga old mineralization is associated with intense shearing and hydrothermal alteration, and the host gabbro is altered to a series of rocks rich in sericite, chlorite, actinolite, carbonate and quartz. Twelve whole-rock samples of the gold mineralization, representing varied degrees of alteration, from rocks with preserved igneous textures to the ore (quartz-carbonate-sulfide-chlorite), were studied by the Sm-Nd method. All analytical points resulted in an isochron (MSWD = 1.9) indicating the age of 2142 {+-} 47 Ma (1s) and Epsilon Nd (T) of +1.2. Chlorite-sericite-carbonate rich hydrothermal rocks indicate the age of 2148 {+-} 57 Ma and Epsilon Nd (T) of +1.1. The positive Epsilon Nd (T) suggest limited or no contamination with older continental crust, compatible with an oceanic setting for the tholeiites. Combined with REE data, the Sm-Nd isotopic results reveal that the hydrothermal alteration, although intense, was unable to alter significantly the Sm/Nd ratios of the original igneous rocks and did not cause important scatter of the analytical points, providing a rare example of robust behavior of the isotopic system, even under intense hydrothermal alteration. (author)

  8. Seismic Reflection Imaging of the Heat Source of an Ultramafic-Hosted Hydrothermal System (Rainbow, Mid-Atlantic Ridge 36° 10-17'N)

    Science.gov (United States)

    Canales, J. P.; Dunn, R. A.; Sohn, R. A.; Horning, G.; Arai, R.; Paulatto, M.

    2015-12-01

    Most of our understanding of hydrothermal systems and the nature of their heat sources comes from models and observations at fast and intermediate spreading ridges. In these settings, hydrothermal systems are mainly located within the axial zone of a spreading segment, hosted in basaltic rock, and primarily driven by heat extracted from crystallization of crustal melt sills. In contrast, hydrothermal systems at slow-spreading ridges like the Mid-Atlantic Ridge (MAR) show a great variety of venting styles and host-rock lithology, and are located in diverse tectonic settings like axial volcanic ridges, non-transform discontinuities (NTDs), the foot of ridge valley walls, and off-axis inside corner highs. Among MAR systems, the Rainbow hydrothermal field (RHF) stands out as an end-member of this diversity: an ultramafic-hosted system emitting H2 and CH4-rich fluids at high temperatures and high flow rates, which suggests a magmatic heat source despite the lack of evidence for recent volcanism and its location within an NTD with presumably low magma budget. We present 2D multichannel seismic reflection images across the Rainbow massif from the NSF-funded MARINER multidisciplinary geophysical study that reveal, for the first time, the magmatic system driving hydrothermal circulation in an ultramafic setting. Data were acquired in 2013 onboard the RV M. Langseth with an 8-km-long hydrophone streamer. The images have been obtained from pre-stack depth migrations using a regional 3D P-wave velocity model from a coincident controlled-source seismic tomography experiment using ocean bottom seismometers. Our images show a complex magmatic system centered beneath the RHF occupying an areal extent of ~3.7x6 km2, with partially molten sills ranging in depth between ~3.4 km and ~6.9 km below the seafloor. Our data also image high-amplitude dipping reflections within the massif coincident with strong lateral velocity gradients that may arise from detachment fault planes

  9. Emergency Department Visits Prior to Suicide and Homicide: Linking Statewide Surveillance Systems.

    Science.gov (United States)

    Cerel, Julie; Singleton, Michael D; Brown, Margaret M; Brown, Sabrina V; Bush, Heather M; Brancado, Candice J

    2016-01-01

    Emergency departments (EDs) serve a wide range of patients who present at risk of impending suicide and homicide. Two statewide surveillance systems were probabilistically linked to understand who utilizes EDs and then dies violently within 6 weeks. Each identified case was matched with four randomly selected controls on sex, race, date of birth, resident zip code, and date of ED visit vs. date of death. Matched-pair odds ratios were estimated by conditional logistic regression to assess differences between cases and controls on reported diagnoses and expected payment sources. Of 1,599 suicides and 569 homicides in the 3-year study period, 10.7% of decedents who died by suicide (mean = 13.6 days) and 8.3% who died by homicide (mean = 16.3 days) were seen in a state ED within 6 weeks prior to death. ED attendees who died by suicide were more likely to have a diagnosis of injury/ poisoning diagnosis or mental disorder and more likely to have Medicare. Those who died by homicide were more likely to have a diagnosis of injury/poisoning and less likely to have commercial insurance. It is essential for research to further explore risk factors for imminent suicide and homicide in ED patients who present for psychiatric conditions and general injuries.

  10. Prototype expert system to assist with the stabilization of neonates prior to transport.

    Science.gov (United States)

    Heermann, L K; Thompson, C B

    1997-01-01

    The transport of sick or premature newborns from community hospitals to acute care facilities is often necessary for the infants to receive the level of care required. Prior stabilization of these infants is imperative to a successful transport. The knowledge required to treat and stabilize sick and premature newborns is specialized and may not be available in community hospitals. "The S.T.A.B.L.E. Assistant" is a prototype rule based decision support system based on the educational program "Transporting Newborns the S.T.A.B.L.E. Way". "The S.T.A.B.L.E. Assistant" accepts clinical information related to an infant's breathing status, blood glucose status and selected lab values and provides instructions as to what interventions are needed to stabilize and prepare the infant for transport. The computerized program was evaluated using data collected from 19 charts of newborns requiring transport from a community hospital to a tertiary care center. Patient data were entered into the computerized program and the subsequent instructions were reviewed by a group of neonatology and neonatal transport experts. Reviewers evaluated "The S.T.A.B.L.E. Assistant" for the safety of the program, the extent to which the computerized program follows the educational program guidelines and the degree to which the instructions generated are within the scope of community caregivers' practice. Results were positive, indicating "The S.T.A.B.L.E. Assistant" prototype is safe, and within the guidelines of neonatal clinical practice.

  11. Inspired by efficient cellulose-dissolving system: Facile one-pot synthesis of biomass-based hydrothermal magnetic carbonaceous materials.

    Science.gov (United States)

    Ma, Jian-Feng; Xing, Jian-Xiong; Wang, Kun; Yang, Hai-Yan; Fei, Ben-Hua; Liu, Xing-E

    2017-05-15

    The core-shell structure of carbon encapsulated magnetic nanoparticles (CEMNs) displays unique properties. Enhancing the magnetization of iron core, in parallel, improving the encapsulation of carbon shell are the two major challenges in the synthesis of CEMNs. Inspired by efficient cellulose-dissolving system, carbon encapsulated magnetic nano-Fe3O4 particles (Fe3O4@C) with ∼10.0nm Fe3O4 cores and 1.9-3.3nm carbon shell, were successfully one-pot synthesized via a novel hydrothermal carbonization (HTC) process. The dissolving process in ionic liquids ([Emim]Ac and [Amim]Cl) completely cleaved the intra- and intermolecular H-bonds in cellulose, and favored the incorporation of Fe3O4 nanoparticles into the cellulose H-bonds systems during the regeneration process. Some stable linkages were formed in Fe3O4@C, taking Fe3O4 nanoparticles as a structure guiding agent. The morphology and properties of Fe3O4@C depended strongly on the type of carbon precursors and pyrolysis temperature. Well encapsulated nanostructure was obtained at HTC temperature 280°C, when [Emim]Ac-treated holocellulose was used as the carbon source. Meanwhile, the thickness of the amorphous shell and magnetization increased with HTC temperature. More importantly, a novel elements for understanding the growth mechanism for the Fe3O4@C composite under HTC conditions was proposed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Seismicity and fluid geochemistry at Lassen Volcanic National Park, California: Evidence for two circulation cells in the hydrothermal system

    Science.gov (United States)

    Janik, Cathy J.; McLaren, Marcia K.

    2010-01-01

    Seismic analysis and geochemical interpretations provide evidence that two separate hydrothermal cells circulate within the greater Lassen hydrothermal system. One cell originates south to SW of Lassen Peak and within the Brokeoff Volcano depression where it forms a reservoir of hot fluid (235–270°C) that boils to feed steam to the high-temperature fumarolic areas, and has a plume of degassed reservoir liquid that flows southward to emerge at Growler and Morgan Hot Springs. The second cell originates SSE to SE of Lassen Peak and flows southeastward along inferred faults of the Walker Lane belt (WLB) where it forms a reservoir of hot fluid (220–240°C) that boils beneath Devils Kitchen and Boiling Springs Lake, and has an outflow plume of degassed liquid that boils again beneath Terminal Geyser. Three distinct seismogenic zones (identified as the West, Middle, and East seismic clusters) occur at shallow depths (Hot Springs Valley, and Bumpass Hell) and an area of cold, weak gas emissions (Cold Boiling Lake). The three zones are located within the inferred Rockland caldera in response to interactions between deeply circulating meteoric water and hot brittle rock that overlies residual magma associated with the Lassen Volcanic Center. Earthquake focal mechanisms and stress inversions indicate primarily N–S oriented normal faulting and E–W extension, with some oblique faulting and right lateral shear in the East cluster. The different focal mechanisms as well as spatial and temporal earthquake patterns for the East cluster indicate a greater influence by regional tectonics and inferred faults within the WLB. A fourth, deeper (5–10 km) seismogenic zone (the Devils Kitchen seismic cluster) occurs SE of the East cluster and trends NNW from Sifford Mountain toward the Devils Kitchen thermal area where fumarolic temperatures are ≤123°C. Lassen fumaroles discharge geothermal gases that indicate mixing between a N2-rich, arc-type component and gases derived

  13. Hydrothermal liquefaction of mixed-culture algal biomass from wastewater treatment system into bio-crude oil.

    Science.gov (United States)

    Chen, Wan-Ting; Zhang, Yuanhui; Zhang, Jixiang; Yu, Guo; Schideman, Lance C; Zhang, Peng; Minarick, Mitchell

    2014-01-01

    In this study, a mixed-culture algal biomass harvested from a functioning wastewater treatment system (AW) was hydrothermally converted into bio-crude oils. The highest bio-crude oil yield (49% of volatile matter) and the highest energy recovery were obtained at 300 °C with 1 h retention time. The highest heating value of the bio-crude oil was 33.3 MJ/kg, produced at 320 °C and 1h retention time. Thermogravimetric analysis showed approximately 60% of the bio-crude oils were distilled in the range of 200-550 °C; and the solid residue might be suitable for use in asphalt. GC-MS results indicated that the bio-crude oil contained hydrocarbons and fatty acids, while the aqueous product was rich in organic acids and cyclic amines. The nitrogen recovery (NR) in the bio-crude oil ranged from 8.41% to 16.8%, which was lower than the typical range of 25%-53% from previous studies. Copyright © 2013 Elsevier Ltd. All rights reserved.

  14. Relations between electrical resistivity, carbon dioxide flux, and self-potential in the shallow hydrothermal system of Solfatara (Phlegrean Fields, Italy)

    OpenAIRE

    S. Byrdina; Vandemeulebrouck, J.; Cardellini, C.; Legaz, A.; Camerlynck, C.; Chiodini, G.; Lebourg, T.; Gresse, M.; Bascou, P.; Motos, G; Carrier, A; Caliro, S.

    2014-01-01

    We present the results of an electric resistivity tomography (ERT) survey, combined with mappings of diffuse carbon dioxide flux, ground temperature and self-potential (SP) at Solfatara, the most active crater of Phlegrean Fields. Solfatara is characterized by an intense carbon dioxide degassing, fumarole activity, and ground deformation. This ensemble of methods is applied to image the hydrothermal system of Solfatara, to understand the geometry of the fluid circulation, and to define the ex...

  15. Caldera processes and magma-hydrothermal systems continental scientific drilling program: thermal regimes, Valles caldera research, scientific and management plan

    Energy Technology Data Exchange (ETDEWEB)

    Goff, F.; Nielson, D.L. (eds.)

    1986-05-01

    Long-range core-drilling operations and initial scientific investigations are described for four sites in the Valles caldera, New Mexico. The plan concentrates on the period 1986 to 1993 and has six primary objectives: (1) study the origin, evolution, physical/chemical dynamics of the vapor-dominated portion of the Valles geothermal system; (2) investigate the characteristics of caldera fill and mechanisms of caldera collapse and resurgence; (3) determine the physical/chemical conditions in the heat transfer zone between crystallizing plutons and the hydrothermal system; (4) study the mechanism of ore deposition in the caldera environment; (5) develop and test high-temperature drilling techniques and logging tools; and (6) evaluate the geothermal resource within a large silicic caldera. Core holes VC-2a (500 m) and VC-2b (2000 m) are planned in the Sulphur Springs area; these core holes will probe the vapor-dominated zone, the underlying hot-water-dominated zone, the boiling interface and probable ore deposition between the two zones, and the deep structure and stratigraphy along the western part of the Valles caldera fracture zone and resurgent dome. Core hole VC-3 will involve reopening existing well Baca number12 and deepening it from 3.2 km (present total depth) to 5.5 km, this core hole will penetrate the deep-crystallized silicic pluton, investigate conductive heat transfer in that zone, and study the evolution of the central resurgent dome. Core hole VC-4 is designed to penetrate deep into the presumably thick caldera fill in eastern Valles caldera and examine the relationship between caldera formation, sedimentation, tectonics, and volcanism. Core hole VC-5 is to test structure, stratigraphy, and magmatic evolution of pre-Valles caldera rocks, their relations to Valles caldera, and the influences of regional structure on volcanism and caldera formation.

  16. High-resolution water column survey to identify active sublacustrine hydrothermal discharge zones within Lake Rotomahana, North Island, New Zealand

    Science.gov (United States)

    Walker, Sharon L.; de Ronde, Cornel E. J.; Fornari, Daniel; Tivey, Maurice A.; Stucker, Valerie K.

    2016-03-01

    Autonomous underwater vehicles were used to conduct a high-resolution water column survey of Lake Rotomahana using temperature, pH, turbidity, and oxidation-reduction potential (ORP) to identify active hydrothermal discharge zones within the lake. Five areas with active sublacustrine venting were identified: (1) the area of the historic Pink Terraces; (2) adjacent to the western shoreline subaerial "Steaming Cliffs," boiling springs and geyser; (3) along the northern shoreline to the east of the Pink Terrace site; (4) the newly discovered Patiti hydrothermal system along the south margin of the 1886 Tarawera eruption rift zone; and (5) a location in the east basin (northeast of Patiti Island). The Pink Terrace hydrothermal system was active prior to the 1886 eruption of Mount Tarawera, but venting along the western shoreline, in the east basin, and the Patiti hydrothermal system appear to have been initiated in the aftermath of the eruption, similar to Waimangu Valley to the southwest. Different combinations of turbidity, pH anomalies (both positive and negative), and ORP responses suggest vent fluid compositions vary over short distances within the lake. The seasonal period of stratification limits vertical transport of heat to the surface layer and the hypolimnion temperature of Lake Rotomahana consequently increases with an average warming rate of ~ 0.010 °C/day due to both convective hydrothermal discharge and conductive geothermal heating. A sudden temperature increase occurred during our 2011 survey and was likely the response to an earthquake swarm just 11 days prior.

  17. Hydrothermal Liquefaction of Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.

    2010-12-10

    Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international

  18. ASSESSMENT OF HIGH-TEMPERATURE GEOTHERMAL RESOURCES IN HYDROTHERMAL CONVECTION SYSTEMS IN THE UNITED STATES.

    Science.gov (United States)

    Nathenson, Manuel

    1984-01-01

    The amount of thermal energy in high-temperature geothermal systems (>150 degree C) in the United States has been calculated by estimating the temperature, area, and thickness of each identified system. These data, along with a general model for recoverability of geothermal energy and a calculation that takes account of the conversion of thermal energy to electricity, yield a resource estimate of 23,000 MWe for 30 years. The undiscovered component was estimated based on multipliers of the identified resource as either 72,000 or 127,000 MWe for 30 years depending on the model chosen for the distribution of undiscovered energy as a function of temperature.

  19. Model for the heat source of the Cerro Prieto magma-hydrothermal system, Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Elders, W.A.; Bird, D.K.; Williams, A.E.; Schiffman, P.; Cox, B.

    1981-01-01

    Earlier studies at Cerro Prieto led to the development of a qualitative model for fluid flow in the geothermal system before it was drilled and perturbed by production. Current efforts are directed towards numerical modeling of heat and mass transfer in the system in this undisturbed state. This one-dimensional model assumes that the heat source was a single basalt/gabbro intrusion which provided heat to the system as it cooled. After compilation of various information of the physical properties of the reservoir, the enthalpy contained in two 1 cm thick sections across the reservoir orthogonal to each other was calculated. Various shapes, sizes and depths for the intrusion were considered as initial conditions and boundary conditions for the calculations of heat transfer. A family of numerical models which so far gives the best matches to the conditions observed in the field today have in common a funnel-shaped intrusion with a top 4 km wide emplaced at a depth of 5 km some 30,000 to 50,000 years ago, providing heat to the geothermal system.

  20. Continental Scientific Drilling Program thermal regimes: comparative site assessment geology of five magma-hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Goff, F.; Waters, A.C. (eds.)

    1980-10-01

    The geology and salient aspects of geophysics and hydrogeochemistry of five high-grade geothermal systems in the USA are reviewed. On the basis of this information, a target location is suggested for a deep (5- to 8-km) borehole that will maximize the amount of scientific information to be learned at each of the five geothermal areas.

  1. Use of Saliva for Assessment of Stress and Its Effect on the Immune System Prior to Gross Anatomy Practical Examinations

    Science.gov (United States)

    Lester, S. Reid; Brown, Jason R.; Aycock, Jeffrey E.; Grubbs, S. Lee; Johnson, Roger B.

    2010-01-01

    The objective of this study was to determine the longitudinal effects of a series of stressful gross anatomy tests on the immune system. Thirty-six freshman occupational therapy students completed a written stress evaluation survey, and saliva samples were obtained at baseline and prior to each of three timed-practical gross anatomy tests.…

  2. Use of uninformative priors to initialize state estimation for dynamical systems

    Science.gov (United States)

    Worthy, Johnny L.; Holzinger, Marcus J.

    2017-10-01

    The admissible region must be expressed probabilistically in order to be used in Bayesian estimation schemes. When treated as a probability density function (PDF), a uniform admissible region can be shown to have non-uniform probability density after a transformation. An alternative approach can be used to express the admissible region probabilistically according to the Principle of Transformation Groups. This paper uses a fundamental multivariate probability transformation theorem to show that regardless of which state space an admissible region is expressed in, the probability density must remain the same under the Principle of Transformation Groups. The admissible region can be shown to be analogous to an uninformative prior with a probability density that remains constant under reparameterization. This paper introduces requirements on how these uninformative priors may be transformed and used for state estimation and the difference in results when initializing an estimation scheme via a traditional transformation versus the alternative approach.

  3. Stable Isotope Geochemistry of Extremely Well-Preserved 2.45-Billion-Year-Old Hydrothermal Systems in the Vetreny Belt, Baltic Shield: Insights into Paleohydrosphere

    Science.gov (United States)

    Zakharov, D. O.; Bindeman, I. N.

    2015-12-01

    The early Paleoproterozoic was an eventful period in the Earth's history. The first portions of free oxygen emerged in the atmosphere, Snowball Earth glaciations happened several times and the first supercontinent broke up due to extensive rifting. These events should have affected the stable isotopic composition of the hydrosphere. In this study, we use rocks that were altered in underwater hydrothermal systems to investigate the stable isotopic composition of the hydrosphere 2.39-2.45 billion years ago (hereinafter, Ga). Extremely low-δ18O (down to -27.5‰ SMOW) rocks from 2.39 Ga metamorphosed subglacial hydrothermal systems of the Belomorian belt, Baltic Shield formed at near-equatorial latitudes suggesting a Snowball (or Slushball) Earth glaciation. These results motivated us to look at temporally and geographically close hydrothermal systems from the unmetamorhposed 2.45 Ga Vetreny Belt rift. The length of the rift is 250 km and it is composed of high-Mg basalts, mafic-ultramafic intrusions and sedimentary successions. We examined several localities of high-Mg basalt flows that include astonishingly fresh pillow lavas, often with preserved volcanic glass, eruptive breccias, and hydrothermal alteration zones. Collected samples serve a great textural evidence of water-rock interaction that occurred in situ while basalts were cooling. The preliminary results from coexisting quartz and epidote (T, D18O=311°C), and from coexisting calcite and quartz (T, D18O=190°C) yield values of δ18O of involved water between -1.6 and -0.9 ‰. The values of δ13C in calcites vary between -4.0 and -2.3 ‰. It is likely that hydrothermal fluids operated in the Vetreny Belt rift were derived from seawater that is no different from modern oceanic water in terms of δ18O. Apparently, the rift was a Paleoproterozoic analog of the modern Red Sea, filled with oceanic water. The result is important because the Vetreny Belt rift predates the onset of Snowball Earth glaciation at 2

  4. Microbial Diversity of Carbonate Chimneys at the Lost City Hydrothermal Field: Implications for Life-Sustaining Systems in Peridotite Seafloor Environments

    Science.gov (United States)

    Schrenk, M. O.; Cimino, P.; Kelley, D. S.; Baross, J. A.

    2002-12-01

    The Lost City Hydrothermal Field (LCHF) is a novel peridotite-hosted vent environment discovered in Dec. 2000 at 30 N near the Mid-Atlantic Ridge. This field contains multiple large (up to 60 m), carbonate chimneys venting high pH (9-10), moderate temperature (45-75 C) fluids. The LCHF is unusual in that it is located on 1.5 my-old oceanic crust, 15 km from the nearest spreading axis. Hydrothermal flow in this system is believed to be driven by exothermic serpentinization reactions involving iron-bearing minerals in the underlying seafloor. The conditions created by such reactions, which include significant quantities of dissolved methane and hydrogen, create habitats for microbial communities specifically adapted to this unusual vent environment. Ultramafic, reducing hydrothermal environments like the LCHF may be analogous to geologic settings present on the early Earth, which have been suggested to be important for the emergence of life. Additionally, the existence of hydrothermal environments far away from an active spreading center expands the range of potential life-supporting environments elsewhere in the solar system. To study the abundance and diversity of microbial communities inhabiting the environments that characterize the LCHF, carbonate chimney samples were analyzed by microscopic and molecular methods. Cell densities of between 105 and 107 cells/g were observed within various samples collected from the chimneys. Interestingly, 4-11% of the microbial population in direct contact with vent fluids fluoresced with Flavin-420, a key coenzyme involved in methanogenesis. Enrichment culturing from chimney material under aerobic and anaerobic conditions yielded microorganisms in the thermophilic and mesophilic temperature regimes in media designed for methanogenesis, methane-oxidation, and heterotrophy. PCR analysis of chimney material indicated the presence of both Archaea and Eubacteria in the carbonate samples. SSU rDNA clone libraries constructed from the

  5. Two-stage alkaline hydrothermal liquefaction of wood to biocrude in a continuous bench-scale system

    DEFF Research Database (Denmark)

    Sintamarean, Iulia-Maria; Grigoras, Ionela; Jensen, Claus Uhrenholt

    2017-01-01

    Feedstock pumpability is one of the main obstacles for continuous processing of biomass through hydrothermal liquefaction (HTL), due to their tendency to form heterogeneous slurries. In this work, a novel strategy is proposed to ensure lignocellulosic feed pumpability in HTL processing, even while...

  6. 3D Geothermal Modelling of the Mount Amiata Hydrothermal System in Italy

    Directory of Open Access Journals (Sweden)

    Paolo Fulignati

    2014-11-01

    Full Text Available In this paper we build a subsurface model that helps in visualizing and understanding the structural framework, geology and their interactions with the Mt. Amiata geothermal system. Modelling in 3D provides the possibility to interpolate the geometry of structures and is an effective way of understanding geological features. The 3D modelling approach appears to be crucial for further progress in the reconstruction of the assessment of the geothermal model of Mt. Amiata. Furthermore, this model is used as the basis of a 3D numerical thermo-fluid-dynamic model of the existing reservoir(s. The integration between borehole data and numerical modelling results allows reconstructing the temperature distribution in the subsoil of the Mt. Amiata area.

  7. Controls on the Mobilization and Transport of Hfse in Ore-Forming Magmatic-Hydrothermal Systems

    Science.gov (United States)

    Sanchez-Valle, C.; Louvel, M.

    2015-12-01

    The genesis of economical rare metals (Zr, Nb, REE) ore deposits in largegranitic complexes (e.g., Strange Lake and Thor Lake Nechalacho deposit, Canada; Galineiro complex, Spain) is related to the intrusion of alkaline halogen-rich magmatic bodies. Although the role of exolved magmatic fluids in the mobilization and transport of HFSE is widely recognized, the physico-chemical conditions and atomic-scale mechanisms that control the formation of the ore deposits remain poorly understood. We present new experimental constraints on behavior of HFSE during the exsolution of aqueous fluids from peralkaline granitic magmas at crustal conditions. In situ partitioning and speciation studies of Zr in the haplogranite-(F)-H2O systems using synchrotron X-ray spectroscopies provide evidence for large controls of fluid chemistry and temperature on the mobilization and transport of HFSE in crustal settings. At shallow crustal pressure conditions (> 800 °C and 0.3 GPa), Zr preferentially partitions into the exolved aqueous fluid in the presence of fluorine (Df/mZr = 1.40 ± 0.10) as previously reported for Nb in F- (and Cl-) bearing metaluminous granitic systems at similar conditions. The reverse partitioning of HFSE (Zr and Nb) into the aqueous phase at temperature above 800 °C contrast with the behavior observed at lower temperatures, where the Df/mZr remain lower than 1 at all pressures. The enrichment of the aqueous phase in HFSE (Zr, Nb) in the earlier stages of the magmatic evolution is likely related to the enhanced peralkalinity of low pressure ( 700 - 800 °C; 0.05 < P < 0.3 GPa) fluids in volcanic arcs may have critical implications for the interpretation of geochemical signature of arc magmas as will be discussed.

  8. Geostructural context of a hydrothermal system by geophysical methods: Case of Hammam Righa, Algeria

    Science.gov (United States)

    Hocine, Amina; Abtout, Abdesalam; Hamai, Lamine

    2017-04-01

    The presence of thermal water depends on the stratigraphic and structural conditions of the site. Indeed, hydrodynamism is directly related to the geostructural elements. In northern Algeria, thermal springs are increasing from west to east. They are mainly situated along the Tellian Atlas which has a complex geology. In this study, we are interested in the thermal site of Hammam Righa, located about 100 km west of Algiers, southwest of the neogene Basin of Mitidja (northern Algeria). This region, very rugged and subject to a developed tectonic rupture, has been discovered and exploited since roman times. The existing drilling on the site cross a superior cover of travertines and marly clay layers of Miocene and Cretaceous. Thermal waters emerge in a more or less impermeable outcrop of limestone marls of the Upper Cretaceous with elevated temperatures (44-68 °C). In order to define the structure and the nature of the top of the aquifer and to determine the faults system inducing the emergence of thermal waters, a hydrogeophysical survey by electrical prospection was undertaken in this region. The electrical soundings (VES, AB = 1000m) realized according to 10 profiles of direction E-W cover an area of 2.5 Km2. Interpretation of these VES resulted in geo-electric sections and iso-resistivity maps, to finally map the top of the Upper Cretaceous. The preliminary results of this study allowed to clarify the lithological nature of the top of the Upper Cretaceous and to demonstrate that there is a variation of depth according to the system of faults highlighted.

  9. In situ ore formation experiment: Amino acids and amino sugars trapped in artificial chimneys on deep-sea hydrothermal systems at Suiyo Seamount, Izu-Bonin Arc, Pacific Ocean

    CERN Document Server

    Takano,; Marumo,; K.,; Ebashi,; T.,; Gupta,; P., L; Kawahata,; H.,; Kobayashi,; K.,; Yamagishi,; A.,; Kuwabara,; T,

    2013-01-01

    The present study reports on the bio-organic composition of a deep-sea venting hydrothermal system originating from arc volcanism; the origin of the particulates in hydrothermal fluids from the Suiyo Seamount in the southern Izu-Bonin (Ogasawara) Arc is discussed with regard to amino compounds. Chimney samples on deep-sea hydrothermal systems and core samples at Suiyo Seamount were determined for amino acids, and occasionally amino sugars. Two types of chimney samples were obtained from active hydrothermal systems by submersible vehicles: one was natural chimney (NC) on a hydrothermal natural vent; the other was artificial chimneys (AC), mainly formed by the growth and deposition of sulfide-rich particulate components in a Kuwabara-type in situ incubator (KI incubator). Total hydrolyzed amino acids (THAA) and hydrolyzed hexosamines (HA) in AC ranged from 10.7 nmol/g to 64.0 nmol/g and from 0 nmol/g to 8.1 nmol/g, respectively, while THAA in hydrothermally altered core samples ranged from 26.0 nmol/g to 107.4 ...

  10. The Trafigura Case and the System of Prior Informed Consent Under the Basel Convention – A Broken System?

    Directory of Open Access Journals (Sweden)

    Gary Cox

    2010-12-01

    Full Text Available The much publicised Trafigura case of the illegal dumping of hazardous petrochemical waste in and around Abidjan in Côte d’Ivoire has reignited the debate about the international trade in hazardous wastes as well as issues of international corporate social responsibility. The incident, which took place in August 2006, highlights major flaws in the existing international regulatory system, particularly around the prior informed consent (PIC procedure. PIC forms the keystone of the 1989 Basel Convention on the Transboundary Movement of Hazardous Wastes. This article focuses on the effectiveness of the PIC procedures under the Basel Convention in the light of the response to the Trafigura incident. The incident exemplifies the failures of the PIC system under the Basel Convention. It reveals confusion on the part of regulatory authorities, failure to take prompt and appropriate action by the authorities involved, a lack of proactive supervisory intervention on the part of the Basel Secretariat, and a more far-reaching lack of developing country support for capacity building and technical assistance. There is a need for a more thorough-going approach to the assessment of environmentally sound management in developing countries. More fundamentally, meaningful consent encompasses the human rights dimension of hazardous wastes on local communities. Efforts aimed at increasing co-operation between the Basel, Rotterdam, Stockholm and MARPOL Conventions should be fully supported but they should be rapidly complemented by addressing deficiencies at ‘the sharp end’ around compliance and the effectiveness of the current system of PIC. A more integrated multilateral environmental regime dealing with all aspects of hazardous chemicals and wastes is warranted based on a wider focus on common concern for the global environment.

  11. Fluid inclusion petrography and microthermometry of the Cocos Ridge hydrothermal system, IODP Expedition 344 (CRISP 2), Site U1414

    Science.gov (United States)

    Brandstätter, J.; Kurz, W.; Krenn, K.; Micheuz, P.

    2015-12-01

    We present new data from microthermometric analyses of fluid inclusions entrapped in hydrothermal veins within lithified sediments and Cocos Ridge (CCR) basalt from IODP Expedition 344 site U1414 (Costa Rica) and concern on a primary task of Expedition 344, i.e. to evaluate fluid/rock interaction, the hydrologic system, and the geochemical processes (indicated by composition and volume of fluids) active within the incoming Cocos Plate. Mineralization of the veins and crosscutting relationships gives constraints for the different generation of veins. Calcium carbonate, commonly aragonite in the upper part and calcite in the lower part of the igneous basement, is usually present in veins as a late phase following the quartz precipitation and the clay minerals formation. The sequence of vein generations in the lithified sediments close to the contact within the CCR basalt is characterized by smaller veins filled by quartz, followed by massive intersecting calcite veins. A high fluid pressure can be concluded, due to wall rock fragments embedded within the filling and fractured mineral grains in the ground mass, which are close to the veins. This requires that the magmatic basement and the lithified sediments were covered by sequences of low permeability sediments forming a barrier that enabled build up elevated fluid pressure. The investigation of fluid inclusions in the lowest units of borehole 344-U1414, give clues about the source of the fluids and about the vein evolution within the incoming Cocos Plate close to Middle American Trench. The microthermometric analyses of the primary, almost aqueous, inclusions indicate a temperature range during entrapment between 200 and 420°C. The data indicate that seawater within the Cocos Ridge aquifer communicated with high-temperature fluids and/or were modified by heat advection. We consider the Galapagos hotspot and/ or the Cocos-Nazca spreading center as heat source. Fluids originated from mobilized sediment pore water

  12. Identification of Cr-magnetite in Neoproterozoic serpentinites resulting of Cr-Spinel alteration in a past hydrothermal system: Aït Ahmane ultramafic unit (Bou Azzer ophiolite, Anti Atlas, Morocco)

    Science.gov (United States)

    Hodel, Florent; Macouin, Mélina; Carlut, Julie; Triantafyllou, Antoine; Berger, Julien; Trindade, Ricardo; Ennih, Nasser; Rousse, Sonia

    2017-04-01

    If magnetite is a common serpentinization product, centimetric, massive and almost pure magnetite veins are rarely observed in serpentinites. Unique examples of these, in the Aït Ahmane ultramafic unit (Bou Azzer Neoproterozoic ophiolite, Anti-Atlas, Morocco), offer the opportunity to assess the hydrothermal processes that prevailed at the end of the Precambrian. Pseudomorphic lizardite/chrysotile texture of unaltered serpentinites suggests an oceanic-like first serpentinization stage, under static and low temperature conditions (T CrM/M ratio providing a quantification of the Cr-magnetite contribution to the magnetic susceptibility, relatively to the pure magnetite one. This CrM/M ratio increases drastically with the hydrothermal alteration of serpentinites and Cr-spinels, attesting of a change of the magnetic mineralogy. Combined with petrography, mineral and bulk chemistry, these magnetic data allow us to propose that a Cl-rich acidic hydrothermal event, involving temperatures below 350 °C, appears to have been responsible of an intense magnetite leaching in host serpentinite and an advanced Cr-spinel alteration in ferritchromite and Cr-magnetite. Iron provided by this leaching may have conducted to the unique magnetite veins formation in the Aït Ahmane ultramafic unit. Two different settings are proposed concerning the nature of the hydrothermal event: (1) a continental hydrothermal system as advanced for the Co-Ni-As ores in the Bou Azzer inliers or (2) an oceanic black smoker type hydrothermal vent field on the Neoproterozoic sea-floor.

  13. Fractionation of 238U/235U in rivers and hydrothermal systems: Constraints for the oceanic U isotope cycle

    Science.gov (United States)

    Noordmann, J.; Weyer, S.; Sharma, M.; Georg, R.; Rausch, S.; Bach, W.

    2010-12-01

    Recently, fractionation of 238U/235U has been observed between oxic and anoxic oceanic environments (Weyer et al., 2008). Sedimentary deposits that formed under oxic conditions (containing U+6) are typically enriched in 235U and anoxic or euxinic sediments (containing U+4) typically show enrichment in 238U. These findings are in agreement with theoretical modeling by Schauble (2007) predicting that U isotope fractionation is dominated by volume-dependent effects. To constrain redox evolution of the oceans (Montoya-Pino et al., 2010), we need detailed information on the U isotope mass balance. However, U isotope fractionation during continental weathering and transport to the oceans, as well as during hydrothermal alteration (the second most important sink for U) is yet unknown. To constrain the isotope composition of the dominant U source to the oceans, we investigated water samples from rivers of different climatic conditions. To obtain an estimate on the U isotope composition of the hydrothermal sink, we analyzed five different hydrothermal fluids from the Juan de Fuca Ridge and, additionally, altered oceanic crust from the Bermuda Rise, Reykjanes Ridge and Pigafetta Basin. Furthermore, δ238U has been measured for granites of different localities and ages to expand the very limited data set for samples from the continental crust. Large rivers display an average δ238U of -0.24 ‰ (relative to CRM-112A) which is very similar to the average value of granites (δ238U= -0.30 ‰) and basalts (δ238U= -0.28 ‰), indicating that in average only minor U isotope fractionation occurs during weathering and transport. Only smaller rivers display larger U isotope variations (between 0.01 and -0.28 ‰) likely monitoring U isotope variations of their bed rocks. The hydrothermal waters display a tight range of δ238U (-0.32 and -0.54 ‰) around the seawater value of δ238U= -0.41 ‰ (Weyer et al., 2008), however, at much lower U concentration levels (0.08 to 0.24 ppb

  14. Fluctuation Modes Prior to Lamellar-Double Gyroid Transition of a Nonionic Surfactant/Water System

    OpenAIRE

    川勝, 年洋

    2004-01-01

    Slow dynamics in complex systems : 3rd International Symposium on Slow Dynamics in Complex Systems, Sendai, Japan, 3-8 November 2003 / editors, Tokuyama Michio, Irwin Oppenheim ; sponsoring organizations, Institute of Fluid Science, Tohoku University Ministry of Education, Culture, Sports, Science and Technology of Japan

  15. High Resolution Imagery of Nikunau Island Coral Reef Systems Prior to and During Suspected Bleaching Events

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset is a collection of imagery of Nikunau Island coral reef systems. They are pairs of imagery where one image was acquired during a suspected bleaching...

  16. High Resolution Imagery of Keppel Island Coral Reef Systems Prior to and During Suspected Bleaching Events

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset is a collection of imagery of Keppel Island coral reef systems. They are pairs of imagery where one image was acquired during a suspected bleaching...

  17. High Resolution Imagery of Howland Island Coral Reef Systems Prior to and During Suspected Bleaching Events

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset is a collection of imagery of Howland Island coral reef systems. They are pairs of imagery where one image was acquired during a suspected bleaching...

  18. Cochin backwaters: An introduction to the system, prior studies, historical trends and future implication

    Digital Repository Service at National Institute of Oceanography (India)

    DineshKumar, P.K.; Sankaranarayanan, V.N.; Devi, K.S.

    Studies over the last 2 decades in the Cochin backwater system in India are reviewed to have an integrated profile with a point to evaluate future development projects in terms of potential consequences to the estuarine ecosystem. The trends...

  19. Behavioral Risk Factor Surveillance System (BRFSS) Prevalence Data (2010 and prior)

    Data.gov (United States)

    U.S. Department of Health & Human Services — 1995-2010. BRFSS land line only prevalence data. BRFSS is a continuous, state-based surveillance system that collects information about modifiable risk factors for...

  20. Calcite veining and feeding conduits in a hydrothermal system: Insights from a natural section across the Pleistocene Gölemezli travertine depositional system (western Anatolia, Turkey)

    Science.gov (United States)

    Capezzuoli, Enrico; Ruggieri, Giovanni; Rimondi, Valentina; Brogi, Andrea; Liotta, Domenico; Alçiçek, Mehmet Cihat; Alçiçek, Hülya; Bülbül, Ali; Gandin, Anna; Meccheri, Marco; Shen, Chuan-Chou; Baykara, Mehmet Oruç

    2018-02-01

    Linking the architecture of structural conduits with the hydrothermal fluids migrating from the reservoir up to the surface is a key-factor in geothermal research. A contribution to this achievement derives from the study of spring-related travertine deposits, but although travertine depositional systems occur widely, their feeding conduits are only rarely exposed. The integrated study carried out in the geothermal Gölemezli area, nearby the well-known Pamukkale area (Denizli Basin, western Anatolia, Turkey), focused on onyx-like calcite veins (banded travertine) and bedded travertine well exposed in a natural cross-section allowing the reconstruction of the shallower part of a geothermal system. The onyx-like veins represent the thickest vein network (> 150 m) so far known. New field mapping and structural/kinematic analyses allowed to document a partially dismantled travertine complex (bedded travertine) formed by proximal fissure ridges and distal terraced/pools depositional systems. The banded calcite veins, WNW-trending and up to 12 m thick, developed within a > 200 m thick damaged rock volume produced by parallel fault zones. Th/U dating indicates a long lasting (middle-late Pleistocene) fluids circulation in a palaeo-geothermal system that, due to its location and chemical characteristics, can be considered the analogue of the nearby, still active, Pamukkale system. The isotopic characteristics of the calcite veins together with data from fluid inclusions analyses, allow the reconstruction of some properties (i.e. temperature, salinity and isotopic composition) and processes (i.e. temperature variation and intensity of degassing) that characterized the parent fluids and the relation between degassing intensity and specific microfabric of calcite crystals (elongated/microsparite-micrite bands), controlled by changes/fluctuations of the physico-chemical fluid characteristics.

  1. Geochemistry of sericite and chlorite in well 14-2 Roosevelt Hot Springs geothermal system and in mineralized hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Ballantyne, J.M.

    1980-06-01

    Chemical compositions of chlorite and sericite from one production well in the Roosevelt geothermal system have been determined by electron probe methods and compared with compositions of chlorite and sericite from porphyry copper deposits. Modern system sericite and chlorite occur over a depth interval of 2 km and a temperature interval of 250/sup 0/C.

  2. Geophysical imaging of hydrothermal shallow degassing in Yellowstone National Park

    Science.gov (United States)

    Pasquet, S.; Holbrook, W. S.; Carr, B.; Sims, K. W. W.

    2016-12-01

    The Yellowstone Plateau Volcanic Field is the world's largest active hydrothermal system, with over 10,000 thermal features. Yet very little is known about the shallow "plumbing" system connecting hydrothermal reservoirs with the surface features. Here we present the results of geophysical investigations of shallow hydrothermal degassing in Yellowstone. In addition to electrical methods, we combined seismic refraction and surface-wave profiling to estimate pressure and shear wave velocities together with the Poisson's ratio. We find that resistivity data helps identifying hydrothermal areas and fluids flowpaths. Poisson's ratio shows a good sensitivity to saturation variations, highlighting gas saturated areas. Porosity and saturation predicted from rock physics modeling provide critical insight to estimate the depth of fluid phase separation and understand the evolution of hydrothermal systems. Finally, the consistency between Poisson's ratio and predicted saturation illustrates its ability to map shallow "plumbing" systems in hydrothermal areas and constrain gas saturation in depth.

  3. Fluid inclusion petrology and microthermometry of the Cocos Ridge hydrothermal system, IODP Expedition 344 (CRISP 2), Site U1414.

    Science.gov (United States)

    Brandstätter, Jennifer; Kurz, Walter; Krenn, Kurt; Micheuz, Peter

    2016-04-01

    In this study, we present new data from microthermometry of fluid inclusions entrapped in hydrothermal veins along the Cocos Ridge from the IODP Expedition 344 Site U1414. The results of our study concern a primary task of IODP Expedition 344 to evaluate fluid/rock interaction linked with the tectonic evolution of the incoming Cocos Plate from the Early Miocene up to recent times. Aqueous, low saline fluids are concentrated within veins from both the Cocos Ridge basalt and the overlying lithified sediments of Unit III. Mineralization and crosscutting relationships give constraints for different vein generations. Isochores from primary, reequilibrated, and secondary fluid inclusions crossed with litho/hydrostatic pressures indicate an anticlockwise PT evolution during vein precipitation and modification by isobaric heating and subsequent cooling at pressures between ∼210 and 350 bar. Internal over and underpressures in the inclusions enabled decrepitation and reequilibration of early inclusions but also modification of vein generations in the Cocos Ridge basalt and in the lithified sediments. We propose that lithification of the sediments was accompanied with a first stage of vein development (VU1 and VC1) that resulted from Galapagos hotspot activity in the Middle Miocene. Heat advection, either related to the Cocos-Nazca spreading center or to hotspot activity closer to the Middle America Trench, led to subsequent vein modification (VC2, VU2/3) related to isobaric heating. The latest mineralization (VC3, VU3) within aragonite and calcite veins and some vesicles of the Cocos Ridge basalt occurred during crustal cooling up to recent times. Fluid inclusion analyses and published isotope data show evidence for communication with deeper sourced, high-temperature hydrothermal fluids within the Cocos Plate. The fluid source of the hydrothermal veins reflects aqueous low saline pore water mixed with invaded seawater.

  4. Fluid inclusion petrology and microthermometry of the Cocos Ridge hydrothermal system, IODP Expedition 344 (CRISP 2), Site U1414

    Science.gov (United States)

    Brandstätter, Jennifer; Kurz, Walter; Krenn, Kurt; Micheuz, Peter

    2016-04-01

    In this study, we present new data from microthermometry of fluid inclusions entrapped in hydrothermal veins along the Cocos Ridge from the IODP Expedition 344 Site U1414. The results of our study concern a primary task of IODP Expedition 344 to evaluate fluid/rock interaction linked with the tectonic evolution of the incoming Cocos Plate from the Early Miocene up to recent times. Aqueous, low saline fluids are concentrated within veins from both the Cocos Ridge basalt and the overlying lithified sediments of Unit III. Mineralization and crosscutting relationships give constraints for different vein generations. Isochores from primary, reequilibrated, and secondary fluid inclusions crossed with litho/hydrostatic pressures indicate an anticlockwise PT evolution during vein precipitation and modification by isobaric heating and subsequent cooling at pressures between ˜210 and 350 bar. Internal over and underpressures in the inclusions enabled decrepitation and reequilibration of early inclusions but also modification of vein generations in the Cocos Ridge basalt and in the lithified sediments. We propose that lithification of the sediments was accompanied with a first stage of vein development (VU1 and VC1) that resulted from Galapagos hotspot activity in the Middle Miocene. Heat advection, either related to the Cocos-Nazca spreading center or to hotspot activity closer to the Middle America Trench, led to subsequent vein modification (VC2, VU2/3) related to isobaric heating. The latest mineralization (VC3, VU3) within aragonite and calcite veins and some vesicles of the Cocos Ridge basalt occurred during crustal cooling up to recent times. Fluid inclusion analyses and published isotope data show evidence for communication with deeper sourced, high-temperature hydrothermal fluids within the Cocos Plate. The fluid source of the hydrothermal veins reflects aqueous low saline pore water mixed with invaded seawater.

  5. Planning of the power hydrothermal system operation - alternatives for the modelling and uncertainties treatment; Planejamento da operacao de sistemas hidrotermicos de potencia - alternativas de modelagem e o tratamento das incertezas

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Andre Flavio Soares; Bajay, Sergio Valdir [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica]|[Universidade Estadual de Campinas, SP (Brazil). Nucleo Interdisciplinar de Planejamento Energetico (NIPE)]. E-mails: apereira@fem.unicamp.br; bajay@fem.unicamp.br; Barbosa, Paulo Sergio Franco [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Civil]|[Universidade Estadual de Campinas, SP (Brazil). Nucleo Interdisciplinar de Planejamento Energetico (NIPE)]. E-mail: franco@fec.unicamp.br

    2006-07-01

    The complexity of the operation scheduling of hydrothermal power systems lies, among other factors, in the interconnection between the operation decision in a certain stage and the future consequences of such decision. The operation of a hydrothermal power system comprises from the supervision and real time control of the generation and transport of electricity, to aspects as the modelling of the uncertainties concerning the future stream flows and the optimised management of the hydro power plant reservoirs. This work addresses a general formulation of the operation scheduling problem of hydrothermal power systems; a brief presentation of the various optimization techniques which can be used in its solution; and a discussion about the main alternatives that has been adopted to model the problem and to deal with its main uncertainties. (author)

  6. Diffuse emissions of Volatile Organic Compounds (VOCs) from soil in volcanic and hydrothermal systems: evidences for the influence of microbial activity on the carbon budget

    Science.gov (United States)

    Venturi, Stefania; Tassi, Franco; Fazi, Stefano; Vaselli, Orlando; Crognale, Simona; Rossetti, Simona; Cabassi, Jacopo; Capecchiacci, Francesco

    2017-04-01

    Soils in volcanic and hydrothermal areas are affected by anomalously high concentrations of gases released from the deep reservoirs, which consists of both inorganic (mainly CO2 and H2S) and organic (volatile organic compounds; VOCs) species. VOCs in volcanic and hydrothermal fluids are mainly composed of saturated and unsaturated hydrocarbons (alkanes, aromatics, alkenes, and cyclics), with variable concentrations of O- and S-bearing compounds and halocarbons, depending on the physicochemical conditions at depth. VOCs in interstitial soil gases and fumarolic emissions from four volcanic and hydrothermal systems in the Mediterranean area (Solfatara Crater, Poggio dell'Olivo and Cava dei Selci, in Italy, and Nisyros Island, in Greece) evidenced clear compositional differences, suggesting that their behavior is strongly affected by secondary processes occurring at shallow depths and likely controlled by microbial activity. Long-chain saturated hydrocarbons were significantly depleted in interstitial soil gases with respect to those from fumarolic discharges, whereas enrichments in O-bearing compounds (e.g. aldehydes, ketones), DMSO2 and cyclics were commonly observed. Benzene was recalcitrant to degradation processes, whereas methylated aromatics were relatively instable. The chemical and isotopic (δ13C in CO2 and CH4) composition of soil gases collected along vertical profiles down to 50 cm depth at both Solfatara Crater and Poggio dell'Olivo (Italy) showed evidences of relevant oxidation processes in the soil, confirming that microbial activity likely plays a major role in modifying the composition of deep-derived VOCs. Despite their harsh conditions, being typically characterized by high temperatures, low pH, and high toxic gases and metal contents, the variety of habitats characterizing volcanic and hydrothermal environments offers ideal biomes to extremophilic microbes, whose metabolic activity can consume and/or produce VOCs. In the Solfatara Crater, microbial

  7. A stochastic approach to long term operation planning of hydrothermal systems; Uma abordagem estocastica para o planejamento a longo prazo da operacao de sistemas hidrotermicos

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Marinho G. [Sao Paulo Univ., Sao Carlos, SP (Brazil). Inst. de Ciencias Matematicas; Soares, Secundino; Cruz Junior, Gelson da; Vinhal, Cassio D.N. [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Eletrica

    1996-01-01

    This paper is concerned with long term operation of hydro-thermal power systems. The problem is approached by a deterministic optimization technique coupled to an inflow forecasting model in open-loop feedback framework in monthly basis. The paper aims to compare the solution obtained by this approach and Stochastic Dynamic Programming (SDP), which has been accepted for over than two decades as the better solution to deal with inflow uncertainty in long term planning. The comparison was carried out in systems with a single plant, simulating the operation throughout a period of five years under the historical inflow conditions and evaluating the cost of the complementary thermal generation. Results show that the proposed approach can handle uncertainty as effectively as SDP. Furthermore, it does not require modeling simplification, such as composite reservoirs, to deal with multi hydro plant systems. 10 refs., 1 tab.

  8. Towards understanding the puzzling lack of acid geothermal springs in Tibet (China): Insight from a comparison with Yellowstone (USA) and some active volcanic hydrothermal systems

    Science.gov (United States)

    Nordstrom, D. Kirk; Guo, Qinghai; McCleskey, R. Blaine

    2014-01-01

    Explanations for the lack of acid geothermal springs in Tibet are inferred from a comprehensive hydrochemical comparison of Tibetan geothermal waters with those discharged from Yellowstone (USA) and two active volcanic areas, Nevado del Ruiz (Colombia) and Miravalles (Costa Rica) where acid springs are widely distributed and diversified in terms of geochemical characteristic and origin. For the hydrothermal areas investigated in this study, there appears to be a relationship between the depths of magma chambers and the occurrence of acid, chloride-rich springs formed via direct magmatic fluid absorption. Nevado del Ruiz and Miravalles with magma at or very close to the surface (less than 1–2 km) exhibit very acidic waters containing HCl and H2SO4. In contrast, the Tibetan hydrothermal systems, represented by Yangbajain, usually have fairly deep-seated magma chambers so that the released acid fluids are much more likely to be fully neutralized during transport to the surface. The absence of steam-heated acid waters in Tibet, however, may be primarily due to the lack of a confining layer (like young impermeable lavas at Yellowstone) to separate geothermal steam from underlying neutral chloride waters and the possible scenario that the deep geothermal fluids below Tibet carry less H2S than those below Yellowstone.

  9. Fault-Related Controls on Upward Hydrothermal Flow: An Integrated Geological Study of the Têt Fault System, Eastern Pyrénées (France

    Directory of Open Access Journals (Sweden)

    Audrey Taillefer

    2017-01-01

    Full Text Available The way faults control upward fluid flow in nonmagmatic hydrothermal systems in extensional context is still unclear. In the Eastern Pyrénées, an alignment of twenty-nine hot springs (29°C to 73°C, along the normal Têt fault, offers the opportunity to study this process. Using an integrated multiscale geological approach including mapping, remote sensing, and macro- and microscopic analyses of fault zones, we show that emergence is always located in crystalline rocks at gneiss-metasediments contacts, mostly in the Têt fault footwall. The hot springs distribution is related to high topographic reliefs, which are associated with fault throw and segmentation. In more detail, emergence localizes either (1 in brittle fault damage zones at the intersection between the Têt fault and subsidiary faults or (2 in ductile faults where dissolution cavities are observed along foliations, allowing juxtaposition of metasediments. Using these observations and 2D simple numerical simulation, we propose a hydrogeological model of upward hydrothermal flow. Meteoric fluids, infiltrated at high elevation in the fault footwall relief, get warmer at depth because of the geothermal gradient. Topography-related hydraulic gradient and buoyancy forces cause hot fluid rise along permeability anisotropies associated with lithological juxtapositions, fracture, and fault zone compositions.

  10. Evaluation of an adsorption system to concentrate VOC in air streams prior to catalytic incineration.

    Science.gov (United States)

    Campesi, María A; Luzi, Carlos D; Barreto, Guillermo F; Martínez, Osvaldo M

    2015-05-01

    Catalytic combustion is a well-developed process for the removal of volatile organic compounds (VOCs). In order to reduce both the amount of catalyst needed for incineration and the surface area of recuperative heat exchangers, an evaluation of the use of thermal swing adsorption as a previous step for VOC concentration is made. An air stream containing ethyl acetate and ethanol (employed as solvents in printing processes) has been taken as a case study. Based on the characteristics of the adsorption/desorption system and the properties of the stream to be treated, a monolithic rotor concentrator with activated carbon as adsorbent material is adopted. Once the temperature of the inlet desorption stream TD is chosen, the minimum possible desorption flow rate, WD,min, and the amount of adsorbent material can be properly defined according to the extent of the Mass Transfer Zone (MTZ) at the end of the adsorption stage. An approximate procedure to speed up the calculations needed for sizing the bed and predicting the operating variables is also presented. In the case studied here, the concentration of the VOC stream can reach 6 times that of the primary effluent when TD = 200 °C is chosen. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. Biogenic Iron-Rich Filaments in the Quartz Veins in the Uppermost Ediacaran Qigebulake Formation, Aksu Area, Northwestern Tarim Basin, China: Implications for Iron Oxidizers in Subseafloor Hydrothermal Systems.

    Science.gov (United States)

    Zhou, Xiqiang; Chen, Daizhao; Tang, Dongjie; Dong, Shaofeng; Guo, Chuan; Guo, Zenghui; Zhang, Yanqiu

    2015-07-01

    Fe-(oxyhydr)oxide-encrusted filamentous microstructures produced by microorganisms have been widely reported in various modern and ancient extreme environments; however, the iron-dependent microorganisms preserved in hydrothermal quartz veins have not been explored in detail because of limited materials available. In this study, abundant well-preserved filamentous microstructures were observed in the hydrothermal quartz veins of the uppermost dolostones of the terminal-Ediacaran Qigebulake Formation in the Aksu area, northwestern Tarim Basin, China. These filamentous microstructures were permineralized by goethite and hematite as revealed by Raman spectroscopy and completely entombed in chalcedony and quartz cements. Microscopically, they are characterized by biogenic filamentous morphologies (commonly 20-200 μm in length and 1-5 μm in diameter) and structures (curved, tubular sheath-like, segmented, and mat-like filaments), similar to the Fe-oxidizing bacteria (FeOB) living in modern and ancient hydrothermal vent fields. A previous study revealed that quartz-barite vein swarms were subseafloor channels of low-temperature, silica-rich, diffusive hydrothermal vents in the earliest Cambrian, which contributed silica to the deposition of the overlying bedded chert of the Yurtus Formation. In this context, this study suggests that the putative filamentous FeOB preserved in the quartz veins might have thrived in the low-temperature, silica- and Fe(II)-rich hydrothermal vent channels in subseafloor mixing zones and were rapidly fossilized by subsequent higher-temperature, silica-rich hydrothermal fluids in response to waning and waxing fluctuations of diffuse hydrothermal venting. In view of the occurrence in a relatively stable passive continental margin shelf environment in Tarim Block, the silica-rich submarine hydrothermal vent system may represent a new and important geological niche favorable for FeOB colonization, which is different from their traditional

  12. Standard Anatomic Terminologies: Comparison for Use in a Health Information Exchange–Based Prior Computed Tomography (CT) Alerting System

    Science.gov (United States)

    Lowry, Tina; Vreeman, Daniel J; Loo, George T; Delman, Bradley N; Thum, Frederick L; Slovis, Benjamin H; Shapiro, Jason S

    2017-01-01

    Background A health information exchange (HIE)–based prior computed tomography (CT) alerting system may reduce avoidable CT imaging by notifying ordering clinicians of prior relevant studies when a study is ordered. For maximal effectiveness, a system would alert not only for prior same CTs (exams mapped to the same code from an exam name terminology) but also for similar CTs (exams mapped to different exam name terminology codes but in the same anatomic region) and anatomically proximate CTs (exams in adjacent anatomic regions). Notification of previous same studies across an HIE requires mapping of local site CT codes to a standard terminology for exam names (such as Logical Observation Identifiers Names and Codes [LOINC]) to show that two studies with different local codes and descriptions are equivalent. Notifying of prior similar or proximate CTs requires an additional mapping of exam codes to anatomic regions, ideally coded by an anatomic terminology. Several anatomic terminologies exist, but no prior studies have evaluated how well they would support an alerting use case. Objective The aim of this study was to evaluate the fitness of five existing standard anatomic terminologies to support similar or proximate alerts of an HIE-based prior CT alerting system. Methods We compared five standard anatomic terminologies (Foundational Model of Anatomy, Systematized Nomenclature of Medicine Clinical Terms, RadLex, LOINC, and LOINC/Radiological Society of North America [RSNA] Radiology Playbook) to an anatomic framework created specifically for our use case (Simple ANatomic Ontology for Proximity or Similarity [SANOPS]), to determine whether the existing terminologies could support our use case without modification. On the basis of an assessment of optimal terminology features for our purpose, we developed an ordinal anatomic terminology utility classification. We mapped samples of 100 random and the 100 most frequent LOINC CT codes to anatomic regions in each

  13. Sulfur and lead isotopic compositions of massive sulfides from deep-sea hydrothermal systems : implications for ore genesis and fluid circulation.

    OpenAIRE

    Zeng, Z.; Ma, Y.; Chen, S; Selby, D.; Wang, X.; X. Yin

    2017-01-01

    Studies of sulfur and lead isotopic compositions in hydrothermal deposits are an important tool to determine the source and processes of both sulfur and lead, and to understand the origin of hydrothermal ore deposits. Here, the sulfur and lead isotopic compositions of sulfide minerals have been studied for different hydrothermal fields in the East Pacific Rise (EPR), Mid-Atlantic Ridge (MAR), Central Indian Ridge (CIR), Southwest Indian Ridge (SWIR), and North Fiji Basin (NFB). The sulfur iso...

  14. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Rudolf, Andreas

    2011-01-01

    This article reviews the hydrothermal liquefaction of biomass with the aim of describing the current status of the technology. Hydrothermal liquefaction is a medium-temperature, high-pressure thermochemical process, which produces a liquid product, often called bio-oil or bi-crude. During...... the hydrothermal liquefaction process, the macromolecules of the biomass are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive and can recombine into larger ones. During this process, a substantial part of the oxygen in the biomass is removed...... by dehydration or decarboxylation. The chemical properties of bio-oil are highly dependent of the biomass substrate composition. Biomass constitutes of various components such as protein; carbohydrates, lignin and fat, and each of them produce distinct spectra of compounds during hydrothermal liquefaction...

  15. Mode I fracture toughness behavior of hydro-thermally aged carbon fibre reinforced DGEBA-HHPA-PES systems

    Science.gov (United States)

    Alessi, Sabina; Pitarresi, Giuseppe; Spadaro, Giuseppe; Tumino, Davide

    2012-07-01

    In this work the Mode I fracture toughness behavior of unidirectional CFRP laminates is investigated by means of Double Cantilever Beam (DCB) tests. The composite samples were manufactured by thermal curing after impregnation of a Carbon fabric with a DGEBA epoxy and anhydride HHPA curing agent. One resin batch was also mixed with a PES thermoplastic monomer to enhance the matrix toughness. Two lots of samples, toughened and untoughened, were then left to soak in hot water to achieve various degrees of aging. The influence of matrix toughening and hydrothermal aging on the delamination behavior of the composite have then been assessed and correlated with characterization data from Dynamic Mechanical Thermal Analysis (DMTA) and Scanning Electron Microscopy (SEM).

  16. Hydrothermal Conditions and the Origin of Cellular Life.

    Science.gov (United States)

    Deamer, David W; Georgiou, Christos D

    2015-12-01

    The conditions and properties of hydrothermal vents and hydrothermal fields are compared in terms of their ability to support processes related to the origin of life. The two sites can be considered as alternative hypotheses, and from this comparison we propose a series of experimental tests to distinguish between them, focusing on those that involve concentration of solutes, self-assembly of membranous compartments, and synthesis of polymers. Key Word: Hydrothermal systems.

  17. NeMO-Net: A System for Near Real-Time Remote Sensing of Hydrothermal and Biological Activity in the Caldera of an Active Submarine Volcano

    Science.gov (United States)

    Hammond, S. R.; Butterfield, D.; Embley, R. W.; Meinig, C.; Stalin, S.

    2001-12-01

    In July of 2000, a camera and three temperature sensors were placed on the seafloor near a hydrothermal vent located in the caldera of an active submarine volcano. The volcano's summit lies at a depth of about 1500 m and is located at 46° N, 130° W, approximately 250 nautical miles off the Oregon coast. The volcano is the site of a long-term interdisciplinary study focused in part on discovering relationships between submarine volcanic and hydrothermal activity and a microbial biosphere which exists beneath the sea floor within the volcano's summit caldera. NeMO-Net utilizes an acoustic modem to communicate with a surface mooring anchored nearby. The mooring, in turn, is linked from the ocean surface to the Pacific Marine Environmental Laboratory by means of satellite systems. A unique feature of NeMO-Net is that it enables shore-based investigators to interrogate and command the system to perform specific tasks, the results of which are then reported back typically within several minutes . In the initial year-long deployment, photographic images, along with hourly readings from the three temperature probes, were available on a website which was updated every 24 hours. During the year, the camera documented a dynamic vent biological community as well as water temperature variations due to the influence of tides, and possibly with changing vent fluid temperatures The NeMO-Net system is under continuing development with particular emphasis on linking it to multiple sea floor instruments including near-real-time chemical and water samplers. Near-future plans also call for NeMO Net to be linked to a resident sea floor AUV.

  18. Seismic Characterization of Hypogenic Karst Systems Associated with Deep Hydrothermal Fluids in the Middle-Lower Ordovician Yingshan Formation of the Shunnan Area, Tarim Basin, NW China

    Directory of Open Access Journals (Sweden)

    Hongtao Zhu

    2017-01-01

    Full Text Available Two fundamental forms of hypogenic karst systems (lateral stratiform hypogenic and cross-formational fault-vein hypogenic karst system are distinguished mainly by differential effects of preexisting faults. In seismic cross sections, hypogenic karst systems are expressed as complex string-beads-like seismic reflections associated with faults. In this study, a new seismic characterization workflow was developed including seismic amplitude thresholding, fault interpretation, pickup, and merge display to enhance the description of the spatial distribution and coupling of hypogenic karst system and faults. The results suggest that the lateral stratiform hypogenic karst systems are predominantly developed at the top of the secondary faults, presenting an overall of “layered distribution and finger-like interaction” features. The cross-formational fault-vein hypogenic karst systems are developed around faults and characterized by dendritic distribution. Furthermore, we infer that the development pattern of hypogenic karst systems has been produced by the interplay of the faults, preexisting epigenic karst systems, and lateral carrier-beds, which together combine the complex hydrothermal migration pathways of fluids with the characteristics of vertical and horizontal combined pathways. In addition, some possible controlling factors (e.g., sequence stratigraphic boundaries, paleogeomorphology, and sedimentary facies that can influence the development of these hypogenic karst systems have been discussed in detail.

  19. Spatial Distribution of b-value of the Copahue volcano during 2012-2014 eruptive period: Relationship between magmatic and hydrothermal system

    Science.gov (United States)

    Lazo, Jonathan; Basualto, Daniel; Bengoa, Cintia; Cardona, Carlos; Franco, Luis; Gil-Cruz, Fernando; Hernández, Erasmo; Lara, Luis; Lundgren, Paul; Medina, Roxana; Morales, Sergio; Peña, Paola; Quijada, Jonathan; Samsonov, Sergey; San Martin, Juan; Valderrama, Oscar

    2015-04-01

    Temporal and spatial variations of b-value have been interpreted as regional stress changes on active tectonic zones or magma ascent and/or hydrothermal fluids mobilization that could affect to active volcanic arc. Increasing of fluids pressure, medium heterogeneities or temperature changes would be the cause of these variations. The Copahue volcano is a shield strato-volcano that has been edified on the western margin of the Caviahue Caldera, located in the international border between Chile and Argentina, which contain an important geothermic field and is located at a horse-tail structure of the Liquiñe-Ofqui Fault Zone. The pre-fracture nature of its basement, as well as an extensive geothermic field, would be producing very complex conditions to fluids movement that could be exploring to use the 'b' value of the recorded seismicity between 2012 and 2014. Based in the database of VT seismic events, we used 2.073 events to calculate the b-value to obtain the 2D and 3D distribution maps. Results showed two anomalous zones: the first one located 9 Km to NE of the active crater, 3-6 Km depth, with high b-values (>1.2) that is associated with a very high production rate of small earthquakes that could suggest a brittle zone, located in the active geothermal field. The second zone, showed a low b-values (~ 0.7), located to east of the volcano edifice at geothermal system, the b-value offers a tool to understand the distribution of the seismic sources and hence a physical constrain for the coupled magmatic/hydrothermal system.

  20. Larval cells become imaginal cells under the control of homothorax prior to metamorphosis in the Drosophila tracheal system.

    Science.gov (United States)

    Sato, Makoto; Kitada, Yusuke; Tabata, Tetsuya

    2008-06-15

    In Drosophila melanogaster, one of the most derived species among holometabolous insects, undifferentiated imaginal cells that are set-aside during larval development are thought to proliferate and replace terminally differentiated larval cells to constitute adult structures. Essentially all tissues that undergo extensive proliferation and drastic morphological changes during metamorphosis are thought to derive from these imaginal cells and not from differentiated larval cells. The results of studies on metamorphosis of the Drosophila tracheal system suggested that large larval tracheal cells that are thought to be terminally differentiated may be eliminated via apoptosis and rapidly replaced by small imaginal cells that go on to form the adult tracheal system. However, the origin of the small imaginal tracheal cells has not been clear. Here, we show that large larval cells in tracheal metamere 2 (Tr2) divide and produce small imaginal cells prior to metamorphosis. In the absence of homothorax gene activity, larval cells in Tr2 become non-proliferative and small imaginal cells are not produced, indicating that homothorax is necessary for proliferation of Tr2 larval cells. These unexpected results suggest that larval cells can become imaginal cells and directly contribute to the adult tissue in the Drosophila tracheal system. During metamorphosis of less derived species of holometabolous insects, adult structures are known to be formed via cells constituting larval structures. Thus, the Drosophila tracheal system may utilize ancestral mode of metamorphosis.

  1. The thermal and chemical evolution of hydrothermal vent fluids in shale hosted massive sulphide (SHMS) systems from the MacMillan Pass district (Yukon, Canada)

    Science.gov (United States)

    Magnall, J. M.; Gleeson, S. A.; Blamey, N. J. F.; Paradis, S.; Luo, Y.

    2016-11-01

    At Macmillan Pass (YT, Canada), the hydrothermal vent complexes beneath two shale-hosted massive sulphide (SHMS) deposits (Tom, Jason) are well preserved within Late Devonian strata. These deposits provide a unique opportunity to constrain key geochemical parameters (temperature, salinity, pH, fO2, ΣS) that are critical for metal transport and deposition in SHMS systems, and to evaluate the interaction between hydrothermal fluids and the mudstone host rock. This has been achieved using a combination of detailed petrography, isotopic techniques (δ34S, δ13C and δ18O values), carbonate rare earth element analysis (LA-ICP-MS), fluid inclusion analysis (microthermometry, gas analysis via incremental crush fast scan mass spectrometry), and thermodynamic modelling. Two main paragenetic stages are preserved in both vent complexes: Stage 1 comprises pervasive ankerite alteration of the organic-rich mudstone host rock and crosscutting stockwork ankerite veining (±pyrobitumen, pyrite and quartz) and; Stage 2 consists of main stage massive sulphide (galena-pyrrhotite-pyrite ± chalcopyrite-sphalerite) and siderite (±quartz and barytocalcite) mineralisation. Co-variation of δ18O and δ13C values in ankerite can be described by temperature dependent fractionation and fluid rock interaction. Together with fluid inclusion microthermometry, this provides evidence of a steep thermal gradient (from 300 to ∼100 °C) over approximately 15 m stratigraphic depth, temporally and spatially constrained within the paragenesis of both vent complexes and developed under shallow lithostatic (28), characteristic of diagenetic fluids, are coupled with positive europium anomalies and variable light REE depletion, which are more consistent with chloride complexation in hot (>250 °C) hydrothermal fluids. In this shallow sub-seafloor setting, thermal alteration of organic carbon in the immature, chemically reactive mudstones also had an important role in the evolution of fluid chemistry

  2. Microbial bio-mineralization processes in hydrothermal travertine: the case study of two active travertine systems (Tuscany, Italy).

    Science.gov (United States)

    Barilaro, Federica; Bontognali, Tomaso R. R.; Mc Kenzie, Judith A.; Vasconcelos, Crisogono

    2015-04-01

    Modern hydrothermal travertine deposits, occurring today at Bagni San Filippo (Radicofani Basin) and at Bagni di Saturnia (Albegna Valley) in Tuscany, Central Italy, have been investigated with the main purpose to improve the understanding of the processes that control calcium carbonate precipitation in hydrothermal-spring settings. Present-day thermal activity at Bagni di Saturnia is characterized by a 37.5°C thermal spring with a rate of about 800 l/s, with a pH of ca. 6.4. Thermal water discharges at Bagni San Filippo reach a rate of 20 litres per second at a maximum temperature of 50°C and a pH of ca. 7. The springs expel water enriched in H2S-CO2-SO42- and HCO3- and divalent cations (Ca and Mg). In the studied areas, travertine precipitation occurs in association with living microbial mats and biofilms, composed of a heterogeneous community of green algae, filamentous cyanobacteria and other types of prokaryotes, anoxygenic photosynthetic bacteria and heterotrophic heat-tolerant bacteria, with a variable amount of extracellular polymeric substances (EPS). Nine categories of fabric types, dominantly calcite and aragonite in composition, showing a wide range of macro- and micro-porosity, have been identified. High magnification analysis of dendritic and laminated boundstone, crystalline crust cementstone, raft boundstone, coated bubble boundstone, micrite mudstone and coated reed boundstone fabric types, suggests that precipitation occurs in association with organic matter. Diatoms, cyanobacteria filaments and other bacteria are then associated with the EPS and often appear totally or partially entombed (passively or actively) in it. Organic extracellular polymeric substances (EPS) and often the external surface of cyanobacterial sheaths are the location where the calcite minerals nucleate and grow. Precipitation begins with organomineral nano-globules consisting of nanometre-size, from sub-spherical to globular-like, raised structures (5 to 80 nm diameter

  3. The dynamics of a double-cell hydrothermal system in triggering seismicity at Somma-Vesuvius: results from a high-resolution radon survey (revisited)

    Science.gov (United States)

    Cigolini, Corrado

    2010-08-01

    Data collected at Somma-Vesuvius during the 1998-1999 radon surveys have been revisited and reinterpreted in light of recent geophysical and geochemical information. The duration of selected radon anomalies, together with the decay properties of radon, have been used to estimate the permeability and porosity of rocks of the deep hydrothermal system. The current local cyclic seismicity is explained by means of a double convective-cell model. Convective cells are separated by a low-permeability horizon located at about 2-2.5 km below sea level. Fluids convecting within the upper cells show temperatures ranging 300-350°C. Rock permeabilities in this sector are estimated on the order of 10-12 m2, for porosities ( ϕ) of about 10-5 typical of a brittle environment where fluid velocities may reach ˜800 m/day. Fluid temperatures within the lower cells may be as high as 400-450°C, consistent with supercritical regimes. The hydrodynamic parameters for these cells are lower, with permeability k ˜ 10-15 m2, and porosity ranging from 10-6 to 10-7. Here, fluid motion toward the surface is controlled by the fracture network within a porous medium approaching brittle-ductile behaviour, and fluid velocities may reach ˜1,800 m/day. The low-permeability horizon is a layer where upper and lower convecting cells converge. In this region, fluids (convecting both at upper and lower levels) percolate through the wallrock and release their brines. Due to self-sealing processes, permeability within this horizon reaches critical values to keep the fluid pressure near lithostatic pressure (for k ˜ 10-18 m2). Deep fluid pressure buildups precede the onset of hydrothermally induced earthquakes. Permeability distribution and rock strength do not exclude that the next eruption at Somma-Vesuvius could be preceded by a seismic crisis, eventually leading to a precursory phreatic explosion. The coupling of these mechanisms has the potential of inducing pervasive failure within rocks of the

  4. Catalytic Hydrothermal Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.

    2015-05-31

    The term “hydrothermal” used here refers to the processing of biomass in water slurries at elevated temperature and pressure to facilitate the chemical conversion of the organic structures in biomass into useful fuels. The process is meant to provide a means for treating wet biomass materials without drying and to access ionic reaction conditions by maintaining a liquid water processing medium. Typical hydrothermal processing conditions are 523-647K of temperature and operating pressures from 4-22 MPa of pressure. The temperature is sufficient to initiate pyrolytic mechanisms in the biopolymers while the pressure is sufficient to maintain a liquid water processing phase. Hydrothermal gasification is accomplished at the upper end of the process temperature range. It can be considered an extension of the hydrothermal liquefaction mechanisms that begin at the lowest hydrothermal conditions with subsequent decomposition of biopolymer fragments formed in liquefaction to smaller molecules and eventually to gas. Typically, hydrothermal gasification requires an active catalyst to accomplish reasonable rates of gas formation from biomass.

  5. Evolution of the magmatic-hydrothermal acid-sulfate system at Summitville, Colorado: Integration of geological, stable-isotope, and fluid-inclusion evidence

    Science.gov (United States)

    Bethke, P.M.; Rye, R.O.; Stoffregen, R.E.; Vikre, P.G.

    2005-01-01

    The Summitville Au-Ag-Cu deposit is a classic volcanic dome-hosted high-sulfidation deposit. It occurs in the Quartz Latite of South Mountain, a composite volcanic dome that was emplaced along the coincident margins of the Platoro and Summitville calderas at 22.5??0.5 Ma, penecontemporaneous with alteration and mineralization. A penecontemporaneous quartz monzonite porphyry intrusion underlies the district and is cut and overlain by pyrite-quartz stockwork veins with traces of chalcopyrite and molybdenite. Alteration and mineralization proceeded through three hypogene stages and a supergene stage, punctuated by at least three periods of hydrothermal brecciation. Intense acid leaching along fractures in the quartz latite produced irregular pipes and lenticular pods of vuggy silica enclosed sequentially by alteration zones of quartz-alunite, quartz-kaolinite, and clay. The acid-sulfate-altered rocks host subsequent covellite+enargite/luzonite+chalcopyrite mineralization accompanied by kaolinite, and later barite-base-metal veins, some containing high Au values and kaolinite. The presence of both liquid- and vapor-rich fluid inclusions indicates the episodic presence of a low-density fluid at all levels of the system. In the mineralized zone, liquid-rich fluid inclusions in healed fractures in quartz phenocrysts and in quartz associated with mineralization homogenize to temperatures between 160 and 390 ??C (90% between 190 and 310 ??C), consistent with the range (200-250 ??C) estimated from the fractionation of sulfur isotopes between coexisting alunite and pyrite. A deep alunite-pyrite pair yielded a sulfur-isotope temperature of 390 ??C, marking a transition from hydrostatic to lithostatic pressure at a depth of about 1.5 km. Two salinity populations dominate the liquid-rich fluid inclusions. One has salinities between 0 and 5 wt.% NaCl equivalent; the other has salinities of up to 43 wt.% NaCl equivalent. The occurrence of high-salinity fluid inclusions in vein

  6. Sm-Nd age of the fazenda brasileiro gabbro, Bahia, Brazil: example of robust behavior of the Sm-Nd isotopic system under extreme hydrothermal alteration

    Directory of Open Access Journals (Sweden)

    Márcio M. Pimentel

    2003-09-01

    Full Text Available The Fazenda Brasileiro gold mineralization is hosted by a gabbroic sill, intrusive into metavolcanicmetasedimentary rocks of the Rio Itapicuru Greenstone Belt, São Francisco Craton. The 2.05 Ga old mineralization is associated with intense shearing and hydrothermal alteration, and the host gabbro is altered to a series of rocks rich in sericite, chlorite, actinolite, carbonate and quartz. Twelve whole-rock samples of the gold mineralization, representing varied degrees of alteration, from rocks with preserved igneous textures to the ore (quartz-carbonate-sulfide-chlorite, were studied by the Sm-Nd method. All analytical points resulted in an isochron (MSWD = 1.9 indicating the age of 2142 +/- 47 Ma (1s and Epsilon Nd (T of +1.2. Chlorite-sericite-carbonate rich hydrothermal rocks indicate the age of 2148 +/- 57 Ma and Epsilon Nd (T of +1.1. The positive Epsilon Nd (T suggest limited or no contamination with older continental crust, compatible with an oceanic setting for the tholeiites. Combined withREEdata, the Sm-Nd isotopic results reveal that the hydrothermal alteration, although intense, was unable to alter significantly the Sm/Nd ratios of the original igneous rocks and did not cause important scatter of the analytical points, providing a rare example of robust behavior of the isotopic system, even under intense hydrothermal alteration.A mineralização de ouro de Fazenda Brasileiro é hospedada por um sill gabróico intrusivo em rochas metavulcânicas/metassedimentares do Greenstone Belt do Rio Itapicuru, Craton do São Francisco. A mineralização, com idade de ca. 2.05 Ga, está associada com forte cizalhamento e alteração hidrotermal, e o gabro hospedeiro está alterado para rochas ricas em clorita, actinolita, carbonato e quartzo. Doze amostras de rocha total representando graus variados de alteração hidrotermal, desde rochas com texturas ígneas reliquiares até o minério (quartzo-carbonato-sulfeto-clorita, foram estudadas pelo

  7. Oxygen isotope exchange kinetics of mineral pairs in closed and open systems: Applications to problems of hydrothermal alteration of igneous rocks and Precambrian iron formations

    Science.gov (United States)

    Gregory, R.T.; Criss, R.E.; Taylor, H.P.

    1989-01-01

    The systematics of stable-isotope exchange between minerals and fluids are examined in the context of modal mineralogical variations and mass-balance considerations, both in closed and in open systems. On mineral-pair ??18O plots, samples from terranes that have exchanged with large amounts of fluid typically map out steep positively-sloped non-equilibrium arrays. Analytical models are derived to explain these effects; these models allow for different exchange rates between the various minerals and the external fluids, as well as different fluid fluxes. The steep arrays are adequately modelled by calculated isochron lines that involve the whole family of possible exchange trajectories. These isochrons have initially-steep near-vertical positive slopes that rotate toward a 45?? equilibrium slope as the exchange process proceeds to completion. The actual data-point array is thus analogous to the hand of an "isotopic clock" that measures the duration of the hydrothermal episode. The dimensionless ratio of the volumetric fluid flux to the kinetic rate parameter ( u k) determines the shape of each individual exchange trajectory. In a fluid-buffered system ( u k ??? 1), the solutions to the equations: (1) are independent of the mole fractions of the solid phases; (2) correspond to Taylor's open-system water/rock equation; and (3) yield straight-line isochrons that have slopes that approach 1 f, where f is the fraction reacted of the more sluggishly exchanging mineral. The isochrons for this simple exchange model are closely congruent with the isochrons calculated for all of the more complex models, thereby simplifying the application of theory to actual hydrothermal systems in nature. In all of the models an order of magnitude of time (in units of kt) separates steep non-equilibrium arrays (e.g., slope ??? 10) from arrays approaching an equilibrium slope of unity on a ??-?? diagram. Because we know the approximate lifetimes of many hydrothermal systems from geologic and

  8. Selected data for hydrothermal-convection systems in the United States with estimated temperatures greater than or equal to 90/sup 0/C: back-up data for US Geological Survey Circular 790

    Energy Technology Data Exchange (ETDEWEB)

    Mariner, R.H.; Brook, C.A.; Swanson, J.R.; Mabey, D.R.

    1978-12-01

    A compilation of data used in determining the accessible resource base for identified hydrothermal convection systems greater than or equal to 90/sup 0/C in the United States are presented. Geographic, geologic, chemical, isotopic, volumetric, and bibliographic data and calculated thermal energy contents are listed for all vapor-dominated and hot-water systems with estimated reservoir temperatures greater than or equal to 90/sup 0/C and reservoir depths less than 3 km known to the authors in mid 1978. Data presented here is stored in the US Geological Survey's geothermal computer file GEOTHERM. Data for individual hydrothermal convection systems in each state are arranged geographically from north to south and west to east without regard to the type or temperature of the system. Locations of the systems and corresponding reference numbers are shown on map 1 accompanying US Geological Survey Circular 790.

  9. Mapping hydrothermal altered mineral deposits using Landsat 7 ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Earth System Science; Volume 121; Issue 4. Mapping hydrothermal altered mineral ... To evaluate the conventional methods for mapping hydrothermal altered deposits by using Landsat 7 ETM+ image in and around Kuju volcano is the prime target of our study. The Kuju volcano is a mountainous ...

  10. Simultaneous-Fault Diagnosis of Automotive Engine Ignition Systems Using Prior Domain Knowledge and Relevance Vector Machine

    Directory of Open Access Journals (Sweden)

    Chi-Man Vong

    2013-01-01

    Full Text Available Engine ignition patterns can be analyzed to identify the engine fault according to both the specific prior domain knowledge and the shape features of the patterns. One of the challenges in ignition system diagnosis is that more than one fault may appear at a time. This kind of problem refers to simultaneous-fault diagnosis. Another challenge is the acquisition of a large amount of costly simultaneous-fault ignition patterns for constructing the diagnostic system because the number of the training patterns depends on the combination of different single faults. The above problems could be resolved by the proposed framework combining feature extraction, probabilistic classification, and decision threshold optimization. With the proposed framework, the features of the single faults in a simultaneous-fault pattern are extracted and then detected using a new probabilistic classifier, namely, pairwise coupling relevance vector machine, which is trained with single-fault patterns only. Therefore, the training dataset of simultaneous-fault patterns is not necessary. Experimental results show that the proposed framework performs well for both single-fault and simultaneous-fault diagnoses and is superior to the existing approach.

  11. Physical, chemical and mineralogical evolution of the Tolhuaca geothermal system, southern Andes, Chile: Insights into the interplay between hydrothermal alteration and brittle deformation

    Science.gov (United States)

    Sanchez-Alfaro, Pablo; Reich, Martin; Arancibia, Gloria; Pérez-Flores, Pamela; Cembrano, José; Driesner, Thomas; Lizama, Martin; Rowland, Julie; Morata, Diego; Heinrich, Christoph A.; Tardani, Daniele; Campos, Eduardo

    2016-09-01

    In this study, we unravel the physical, chemical and mineralogical evolution of the active Tolhuaca geothermal system in the Andes of southern Chile. We used temperature measurements in the deep wells and geochemical analyses of borehole fluid samples to constrain present-day fluid conditions. In addition, we reconstructed the paleo-fluid temperatures and chemistry from microthermometry and LA-ICP-MS analysis of fluid inclusions taken from well-constrained parageneses in vein samples retrieved from a ~ 1000 m borehole core. Based on core logging, mineralogical observations and fluid inclusions data we identify four stages (S1-S4) of progressive hydrothermal alteration. An early heating event (S1) was followed by the formation of a clay-rich cap in the upper zone (Tolhuaca has produced a mineralogical, hydrological and structural vertical segmentation of the system through the development of a low-permeability, low-cohesion clay-rich cap at shallow depth. The quantitative chemical analyses of fluid inclusions and borehole fluids reveal a significant change in chemical conditions during the evolution of Tolhuaca. Whereas borehole (present-day) fluids are rich in Au, B and As, but Cu-poor (B/Na ~ 100.5, As/Na ~ 10- 1.1, Cu/Na ~ 10- 4.2), the paleofluids trapped in fluid inclusions are Cu-rich but poor in B and As (B/Na ~ 10- 1, As/Na ~ 10- 2.5, Cu/Na ~ 10- 2.5 in average). We interpret the fluctuations in fluid chemistry at Tolhuaca as the result of transient supply of metal-rich, magmatically derived fluids where As, Au and Cu are geochemically decoupled. Since these fluctuating physical and chemical conditions at the reservoir produced a mineralogical vertical segmentation of the system that affects the mechanical and hydrological properties of host rock, we explored the effect of the development of a low-cohesion low-permeability clay cap on the conditions of fault rupture and on the long-term thermal structure of the system. These analyses were performed by using

  12. Geomicrobiological exploration and characterization of a novel deep-sea hydrothermal system at the TOTO caldera in the Mariana Volcanic Arc.

    Science.gov (United States)

    Nakagawa, Tatsunori; Takai, Ken; Suzuki, Yohey; Hirayama, Hisako; Konno, Uta; Tsunogai, Urumu; Horikoshi, Koki

    2006-01-01

    Novel hydrothermal activities accompanying effluent white smokers and elemental sulfur chimney structures at the north-east lava dome of the TOTO caldera depression in the Mariana Volcanic Arc have been explored and characterized by geochemical and microbiological surveys. White smoker hydrothermal fluids were observed in the potential hydrothermal activity centre of the field and represented the maximal temperature of 170 degrees C and the lowest pH of 1.6. The chimney structures, all consisting of elemental sulfur (sulfur chimney), were also unique to the TOTO caldera hydrothermal field. Microbial community structures in a sulfur chimney and its formation hydrothermal fluid with a high concentration of hydrogen sulfide (15 mM) have been investigated by culture-dependent and -independent analyses. 16S rRNA gene clone analysis and fluorescence in situ hybridization (FISH) analysis revealed that epsilon-Proteobacteria dominated the microbial communities in the sulfur chimney structure and formed a dense microbial mat covering the sulfur chimney surface. Archaeal phylotypes were consistently minor components in the communities and related to the genera Thermococcus, Pyrodictium, Aeropyrum, and the uncultivated archaeal group of 'deep-sea hydrothermal vent euryarchaeotal group'. Cultivation analysis suggested that the chemolithoautotrophs might play a significant ecological role as primary producers utilizing gas and sulfur compounds provided from hydrothermal fluids.

  13. Reducing scan angle using adaptive prior knowledge for a limited-angle intrafraction verification (LIVE) system for conformal arc radiotherapy

    Science.gov (United States)

    Zhang, Yawei; Yin, Fang-Fang; Zhang, You; Ren, Lei

    2017-05-01

    The purpose of this study is to develop an adaptive prior knowledge guided image estimation technique to reduce the scan angle needed in the limited-angle intrafraction verification (LIVE) system for 4D-CBCT reconstruction. The LIVE system has been previously developed to reconstruct 4D volumetric images on-the-fly during arc treatment for intrafraction target verification and dose calculation. In this study, we developed an adaptive constrained free-form deformation reconstruction technique in LIVE to further reduce the scanning angle needed to reconstruct the 4D-CBCT images for faster intrafraction verification. This technique uses free form deformation with energy minimization to deform prior images to estimate 4D-CBCT based on kV-MV projections acquired in extremely limited angle (orthogonal 3°) during the treatment. Note that the prior images are adaptively updated using the latest CBCT images reconstructed by LIVE during treatment to utilize the continuity of the respiratory motion. The 4D digital extended-cardiac-torso (XCAT) phantom and a CIRS 008A dynamic thoracic phantom were used to evaluate the effectiveness of this technique. The reconstruction accuracy of the technique was evaluated by calculating both the center-of-mass-shift (COMS) and 3D volume-percentage-difference (VPD) of the tumor in reconstructed images and the true on-board images. The performance of the technique was also assessed with varied breathing signals against scanning angle, lesion size, lesion location, projection sampling interval, and scanning direction. In the XCAT study, using orthogonal-view of 3° kV and portal MV projections, this technique achieved an average tumor COMS/VPD of 0.4  ±  0.1 mm/5.5  ±  2.2%, 0.6  ±  0.3 mm/7.2  ±  2.8%, 0.5  ±  0.2 mm/7.1  ±  2.6%, 0.6  ±  0.2 mm/8.3  ±  2.4%, for baseline drift, amplitude variation, phase shift, and patient breathing signal variation

  14. Hydrothermal energy development projects

    Science.gov (United States)

    Dibello, E. G.

    The development of hydrothermal energy for direct heat applications is being accelerated by twenty-two demonstration projects that are funded on a cost sharing basis by the US Department of Energy, Division of Geothermal Energy. These projects are designed to demonstrate the technical and economic feasibility of the direct use of hydrothermal resources in the United States. Engineering and economic data for the projects are summarized. The data and experience being generated by these projects will serve as an important basis for future direct heat development.

  15. Complexing and hydrothermal ore deposition

    CERN Document Server

    Helgeson, Harold C

    1964-01-01

    Complexing and Hydrothermal Ore Deposition provides a synthesis of fact, theory, and interpretative speculation on hydrothermal ore-forming solutions. This book summarizes information and theory of the internal chemistry of aqueous electrolyte solutions accumulated in previous years. The scope of the discussion is limited to those aspects of particular interest to the geologist working on the problem of hydrothermal ore genesis. Wherever feasible, fundamental principles are reviewed. Portions of this text are devoted to calculations of specific hydrothermal equilibriums in multicompone

  16. Microbial community in a sediment-hosted CO2 lake of the southern Okinawa Trough hydrothermal system.

    Science.gov (United States)

    Inagaki, Fumio; Kuypers, Marcel M M; Tsunogai, Urumu; Ishibashi, Jun-Ichiro; Nakamura, Ko-Ichi; Treude, Tina; Ohkubo, Satoru; Nakaseama, Miwako; Gena, Kaul; Chiba, Hitoshi; Hirayama, Hisako; Nunoura, Takuro; Takai, Ken; Jørgensen, Bo B; Horikoshi, Koki; Boetius, Antje

    2006-09-19

    Increasing levels of CO2 in the atmosphere are expected to cause climatic change with negative effects on the earth's ecosystems and human society. Consequently, a variety of CO2 disposal options are discussed, including injection into the deep ocean. Because the dissolution of CO2 in seawater will decrease ambient pH considerably, negative consequences for deep-water ecosystems have been predicted. Hence, ecosystems associated with natural CO2 reservoirs in the deep sea, and the dynamics of gaseous, liquid, and solid CO2 in such environments, are of great interest to science and society. We report here a biogeochemical and microbiological characterization of a microbial community inhabiting deep-sea sediments overlying a natural CO2 lake at the Yonaguni Knoll IV hydrothermal field, southern Okinawa Trough. We found high abundances (>10(9) cm(-3)) of microbial cells in sediment pavements above the CO2 lake, decreasing to strikingly low cell numbers (10(7) cm(-3)) at the liquid CO2/CO2-hydrate interface. The key groups in these sediments were as follows: (i) the anaerobic methanotrophic archaea ANME-2c and the Eel-2 group of Deltaproteobacteria and (ii) sulfur-metabolizing chemolithotrophs within the Gamma- and Epsilonproteobacteria. The detection of functional genes related to one-carbon assimilation and the presence of highly 13C-depleted archaeal and bacterial lipid biomarkers suggest that microorganisms assimilating CO2 and/or CH4 dominate the liquid CO2 and CO2-hydrate-bearing sediments. Clearly, the Yonaguni Knoll is an exceptional natural laboratory for the study of consequences of CO2 disposal as well as of natural CO2 reservoirs as potential microbial habitats on early Earth and other celestial bodies.

  17. Burkholderia insulsa sp. nov., a facultatively chemolithotrophic bacterium isolated from an arsenic-rich shallow marine hydrothermal system.

    Science.gov (United States)

    Rusch, Antje; Islam, Shaer; Savalia, Pratixa; Amend, Jan P

    2015-01-01

    Enrichment cultures inoculated with hydrothermally influenced nearshore sediment from Papua New Guinea led to the isolation of an arsenic-tolerant, acidophilic, facultatively aerobic bacterial strain designated PNG-April(T). Cells of this strain were Gram-stain-negative, rod-shaped, motile and did not form spores. Strain PNG-April(T) grew at temperatures between 4 °C and 40 °C (optimum 30-37 °C), at pH 3.5 to 8.3 (optimum pH 5-6) and in the presence of up to 2.7% NaCl (optimum 0-1.0%). Both arsenate and arsenite were tolerated up to concentrations of at least 0.5 mM. Metabolism in strain PNG-April(T) was strictly respiratory. Heterotrophic growth occurred with O2 or nitrate as electron acceptors, and aerobic lithoautotrophic growth was observed with thiosulfate or nitrite as electron donors. The novel isolate was capable of N2-fixation. The respiratory quinones were Q-8 and Q-7. Phylogenetically, strain PNG-April(T) belongs to the genus Burkholderia and shares the highest 16S rRNA gene sequence similarity with the type strains of Burkholderia fungorum (99.8%), Burkholderia phytofirmans (98.8%), Burkholderia caledonica (98.4%) and Burkholderia sediminicola (98.4%). Differences from these related species in several physiological characteristics (lipid composition, carbohydrate utilization, enzyme profiles) and DNA-DNA hybridization suggested the isolate represents a novel species of the genus Burkholderia, for which we propose the name Burkholderia insulsa sp. nov. The type strain is PNG-April(T) ( = DSM 28142(T) = LMG 28183(T)). © 2015 IUMS.

  18. Late-stage anhydrite-gypsum-siderite-dolomite-calcite assemblages record the transition from a deep to a shallow hydrothermal system in the Schwarzwald mining district, SW Germany

    Science.gov (United States)

    Burisch, Mathias; Walter, Benjamin F.; Gerdes, Axel; Lanz, Maximilian; Markl, Gregor

    2018-02-01

    The majority of hydrothermal vein systems of economic interest occur at relatively shallow crustal levels, although many of them formed at significantly greater depths. Their present position is a consequence of uplift and erosion. Although, many aspects of their formation are well constrained, the temporal chemical evolution of such systems during uplift and erosion is still poorly understood. These vein minerals comprise calcite, dolomite-ankerite, siderite-magnesite, anhydrite and gypsum forming the last gangue assemblages in Jurassic and Tertiary sulphide-fluorite-quartz-barite veins of the Schwarzwald mining district, SW Germany. Mineral textures of samples from nine localities reveal that in these sequences, mineral precipitation follows a recurring pattern: early calcite is followed by anhydrite or gypsum, siderite and/or dolomite. This succession may repeat up to three times. In-situ (LA-ICP-MS) U-Pb age dating of 15 carbonates from three subsequent generations of the late-stage vein assemblage yield robust ages between 20 and 0.6 Ma. Each mineral sequence forms in a distinctive period of about 2-5 Ma. These ages clearly relate these late-stage mineral phases to the youngest geological episode of the Schwarzwald, which is associated with the Cenozoic Rhine Graben rifting and basement uplift. Based on thermodynamic modelling, the formation of the observed mineral assemblages required an deeply sourced Mg-, Fe- and SO4-rich fluid (b), which was episodically mixed with a shallow crustal HCO3-rich fluid (a). As a consequence of fluid mixing, concentrations of Mg, Fe and SO4 temporarily increased and initiated the formation of the observed sulphate-carbonate mineral sequences. This discontinuous large-scale vertical fluid mixing was presumably directly related to episodes of active tectonics associated with the Cenozoic strike-slip regime of the Upper Rhine Graben. Analogously, episodic fluid mixing is a major key in the formation of older (Jurassic to early

  19. Experimental and theoretical investigation of the production of HCl and some metal chlorides in magmatic/hydrothermal systems. Annual report, 1991--1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-31

    In the calculations we have assumed that all apatites are magmatic. The presence of chlorite and altered plagioclase within the granite and quartz-monzodiorite suggests that alteration may play a role in leading to erroneous estimates of initial melt Cl and F for 2 reasons: (1) the apatites may in fact not be magmatic in origin, but are hydrothermal, and (2) the halogen signature of magmatic apatite may be changed due to subsolidus exchange with a hydrothermal fluid. We are currently endeavoring to develop criteria for determining whether apatite composition represents earlier or later stages of magmatic-hydrothermal development.

  20. Systemic administration of antiretrovirals prior to exposure prevents rectal and intravenous HIV-1 transmission in humanized BLT mice.

    Directory of Open Access Journals (Sweden)

    Paul W Denton

    2010-01-01

    Full Text Available Successful antiretroviral pre-exposure prophylaxis (PrEP for mucosal and intravenous HIV-1 transmission could reduce new infections among targeted high-risk populations including discordant couples, injection drug users, high-risk women and men who have sex with men. Targeted antiretroviral PrEP could be particularly effective at slowing the spread of HIV-1 if a single antiretroviral combination were found to be broadly protective across multiple routes of transmission. Therefore, we designed our in vivo preclinical study to systematically investigate whether rectal and intravenous HIV-1 transmission can be blocked by antiretrovirals administered systemically prior to HIV-1 exposure. We performed these studies using a highly relevant in vivo model of mucosal HIV-1 transmission, humanized Bone marrow/Liver/Thymus mice (BLT. BLT mice are susceptible to HIV-1 infection via three major physiological routes of viral transmission: vaginal, rectal and intravenous. Our results show that BLT mice given systemic antiretroviral PrEP are efficiently protected from HIV-1 infection regardless of the route of exposure. Specifically, systemic antiretroviral PrEP with emtricitabine and tenofovir disoproxil fumarate prevented both rectal (Chi square = 8.6, df = 1, p = 0.003 and intravenous (Chi square = 13, df = 1, p = 0.0003 HIV-1 transmission. Our results indicate that antiretroviral PrEP has the potential to be broadly effective at preventing new rectal or intravenous HIV transmissions in targeted high risk individuals. These in vivo preclinical findings provide strong experimental evidence supporting the potential clinical implementation of antiretroviral based pre-exposure prophylactic measures to prevent the spread of HIV/AIDS.

  1. Seismo-acoustic evidence for an avalanche driven phreatic eruption through a beheaded hydrothermal system: An example from the 2012 Tongariro eruption

    Science.gov (United States)

    Jolly, A.D.; Jousset, P.; Lyons, J.J.; Carniel, R.; Fournier, R.; Fry, B.; Miller, C.

    2016-01-01

    The 6 August 2012 Te Maari eruption comprises a complex eruption sequence including multiple eruption pulses, a debris avalanche that propagated ~ 2 km from the vent, and the formation of a 500 m long, arcuate chasm, located ~ 300 m from the main eruption vent. The eruption included 6 distinct impulses that were coherent across a local infrasound network marking the eruption onset at 11:52:18 (all times UTC). An eruption energy release of ~ 3 × 1012 J was calculated using a body wave equation for radiated seismic energy. A similar calculation based on the infrasound record, shows that ~ 90% of the acoustic energy was released from three impulses at onset times 11:52:20 (~ 20% of total eruption energy), 11:52:27 (~ 50%), and 11:52:31 (~ 20%). These energy impulses may coincide with eyewitness accounts describing an initial eastward directed blast, followed by a westward directed blast, and a final vertical blast. Pre-eruption seismic activity includes numerous small unlocatable micro-earthquakes that began at 11:46:50. Two larger high frequency earthquakes were recorded at 11:49:06 and 11:49:21 followed directly by a third earthquake at 11:50:17. The first event was located within the scarp based on an arrival time location from good first P arrival times and probably represents the onset of the debris avalanche. The third event was a tornillo, characterised by a 0.8 Hz single frequency resonance, and has a resonator attenuation factor of Q ~ 40, consistent with a bubbly fluid filled resonator. This contrasts with a similar tornillo event occurring 2.5 weeks earlier having Q ~ 250–1000, consistent with a dusty gas charged resonator. We surmise from pre-eruption seismicity, and the observed attenuation change, that the debris avalanche resulted from the influx of fluids into the hydrothermal system, causing destabilisation and failure. The beheaded hydrothermal system may have then caused depressurisation frothing of the remaining gas charged system leading to the

  2. Hydrothermal conversion of biomass

    NARCIS (Netherlands)

    Knezevic, D.

    2009-01-01

    This thesis presents research of hydrothermal conversion of biomass (HTC). In this process, hot compressed water (subcritical water) is used as the reaction medium. Therefore this technique is suitable for conversion of wet biomass/ waste streams. By working at high pressures, the evaporation of

  3. Post-Drilling Changes in Seabed Landscape and Megabenthos in a Deep-Sea Hydrothermal System, the Iheya North Field, Okinawa Trough: e0123095

    National Research Council Canada - National Science Library

    Ryota Nakajima; Hiroyuki Yamamoto; Shinsuke Kawagucci; Yutaro Takaya; Tatsuo Nozaki; Chong Chen; Katsunori Fujikura; Tetsuya Miwa; Ken Takai

    2015-01-01

      There has been an increasing interest in seafloor exploitation such as mineral mining in deep-sea hydrothermal fields, but the environmental impact of anthropogenic disturbance to the seafloor is poorly known...

  4. The BGU/CERN solar hydrothermal reactor

    CERN Document Server

    Bertolucci, Sergio; Caspers, Fritz; Garb, Yaakov; Gross, Amit; Pauletta, Stefano

    2014-01-01

    We describe a novel solar hydrothermal reactor (SHR) under development by Ben Gurion University (BGU) and the European Organization for Nuclear Research CERN. We describe in broad terms the several novel aspects of the device and, by extension, of the niche it occupies: in particular, enabling direct off-grid conversion of a range of organic feedstocks to sterile useable (solid, liquid) fuels, nutrients, products using only solar energy and water. We then provide a brief description of the high temperature high efficiency panels that provide process heat to the hydrothermal reactor, and review the basics of hydrothermal processes and conversion taking place in this. We conclude with a description of a simulation of the pilot system that will begin operation later this year.

  5. Geochemical variability of hydrothermal emissions between three Pacific volcanic arc systems: Alaskan-Aleutian and Cascadian, North America and Taupo Volcanic Zone, New Zealand

    Science.gov (United States)

    Blackstock, J. M.; Horton, T. W.; Gravley, D. M.; Deering, C. D.

    2013-12-01

    Knowledge of the source, transport, and fate of hydrothermal fluids in the upper crust informs our understanding and interpretation of ore-forming processes, volcanogenic hazards, geothermal resources, and volatile cycling. Co-variation between fluid inclusion CO2/CH4 and N2/Ar ratios is an established tracer of magmatic, meteoric, and crustal fluid end-members. Yet, this tracer has had limited application to macroscopic fluid reservoirs accessible via geothermal wells and hydrothermal features (e.g. pools). In this study, we compared the covariance CO2/CH4 and N2/Ar ratios of gases collected throughout the Taupo Volcanic Zone, New Zealand (TVZ), the Alaska-Aleutian Volcanic Arc, USA (AAVA), and the Cascadian Volcanic Arc, USA (CVA) with corresponding δ13C and 3He/4He values. Our findings show that there is good agreement between these proxies for different end-member contributions at coarse scales. However, some samples classified as meteoric water according to the CO2/CH4 and N2/Ar ratios also show more positive δ13C values (~ -7.0 per mil) and relatively higher 3He/4He ratios indicative of magmatic input from primarily mantle sources. This unexpected result may be related to magmatic fluids, CO2 in particular, mixing with predominantly meteoric derived waters. The potential to identify magmatic CO2 in groundwater samples overlying geothermal systems in differing volcanic arc settings using simple and cost-effective gas ratios is a promising step forward in the search for ';surface blind' but developable geothermal systems and volcanic monitoring. 3He/4He anomalies also support this inference and underscore the potential decoupling of thermal anomalies and magmatic-derived fluids in the Earth's crust. The general agreement between the co-variation of CO2/CH4 and N2/Ar ratios with other isotope and geochemical proxies for magmatic, meteoric, and crustal end-members is encouraging to employ expanded use of these ratios for both the exploration and monitoring of

  6. Arthur Prior and 'Now'

    DEFF Research Database (Denmark)

    Blackburn, Patrick Rowan; Jørgensen, Klaus Frovin

    2016-01-01

    ’s search led him through the work of Castañeda, and back to his own work on hybrid logic: the first made temporal reference philosophically respectable, the second made it technically feasible in a modal framework. With the aid of hybrid logic, Prior built a bridge from a two-dimensional UT calculus......On the 4th of December 1967, Hans Kamp sent his UCLA seminar notes on the logic of ‘now’ to Arthur N. Prior. Kamp’s two-dimensional analysis stimulated Prior to an intense burst of creativity in which he sought to integrate Kamp’s work into tense logic using a one-dimensional approach. Prior...... to a one-dimensional tense logic containing the ‘now’ operator J. Drawing on material from the Prior archive, and the paper “‘Now”’ that detailed Prior’s findings, we retell this story. We focus on Prior’s completeness conjecture for the hybrid system and the role played by temporal reference....

  7. Thickness distributions and evolution of growth mechanisms of NH4-illite from the fossil hydrothermal system of Harghita Bai, Eastern Carpathians, Romania

    Science.gov (United States)

    Bobos, Iuliu; Eberl, D.D.

    2013-01-01

    The crystal growth of NH4-illite (NH4-I) from the hydrothermal system of Harghita Bãi (Eastern Carpathians) was deduced from the shapes of crystal thickness distributions (CTDs). The 4-illite-smectite (I-S) interstratified structures (R1, R2, and R3-type ordering) with a variable smectite-layer content. The NH4-I-S (40–5% S) structures were identified underground in a hydrothermal breccia structure, whereas the K-I/NH4-I mixtures were found at the deepest level sampled (−110 m). The percentage of smectite interlayers generally decreases with increasing depth in the deposit. This decrease in smectite content is related to the increase in degree of fracturing in the breccia structure and corresponds to a general increase in mean illite crystal thickness. In order to determine the thickness distributions of NH4-I crystals (fundamental illite particles) which make up the NH4-I-S interstratified structures and the NH4,-I/K-I mixtures, 27 samples were saturated with Li+ and aqueous solutions of PVP-10 to remove swelling and then were analyzed by X-ray diffraction. The profiles for the mean crystallite thickness (Tmean) and crystallite thickness distribution (CTD) of NH4-I crystallites were determined by the Bertaut-Warren-Averbach method using the MudMaster computer code. The Tmean of NH4-I from NH4-I-S samples ranges from 3.4 to 7.8 nm. The Tmean measured for the NH4-I/K-I mixture phase ranges from 7.8 nm to 11.7 nm (NH4-I) and from 12.1 to 24.7 nm (K-I). The CTD shapes of NH4-I fundamental particles are asymptotic and lognormal, whereas illites from NH4-I/K-I mixtures have bimodal shapes related to the presence of two lognormal-like CTDs corresponding to NH4-I and K-I. The crystal-growth mechanism for NH4-I samples was simulated using the Galoper code. Reaction pathways for NH4-I crystal nucleation and growth could be determined for each sample by plotting their CTD parameters on an α–β2 diagram constructed using Galoper. This analysis shows that NH4-I

  8. Stable carbon and nitrogen isotopic signatures of fauna associated with the deep-sea hydrothermal vent system of Guaymas Basin, Gulf of California

    Science.gov (United States)

    Soto, Luis A.

    2009-09-01

    Potential food sources and the trophic position of some of the most conspicuous faunal components (vent and non-vent) were examined in the deep-hydrothermal vent system of Guaymas Basin, in the Gulf of California using carbon and nitrogen stable isotope analyses. The isotopic signatures of 13 species collected by the DSRV Alvin and Nautile mostly from sulfide-influenced habitats were analyzed. The δ 13C of nine vent species had a wide range (-36.0‰ to -12.7‰), whereas the δ 15N values varied from -5.0‰ to+9.4‰. The dual isotopic approach allowed the recognition of two main groups containing vent-endemic fauna. One was represented by an assemblage of eight species associated with sulfide deposits, visually dominated by the siboglinid worm Riftia pachyptila and characterized by enriched δ 13C values (means -13.7‰ to -21.0‰). The second group included a single species, the bivalve Vesicomya gigas, an inhabitant of soft sediments, which had depleted δ 13C and δ 15N signatures (means -35.7‰ and -1.5‰). The galatheid Munidopsis alvisca is an exception among the species in the R. pachyptila aggregation, due to its depleted δ 13C (-26.4‰) and an intermediate δ 15N value (+5.5‰). Isotopic δ 13C and δ 15N signatures of four non-vent species exhibited mostly enriched δ 15N values (means δ 13C -27.8‰ to -13.6‰; δ 15N +14.5‰ to +17.9‰), expected for higher consumers and detritivores in a deep-sea food web. They may benefit from the vent production via microbial matter or decaying vent organisms. Vent and non-vent fauna were assigned to five feeding guilds: symbiont-containing fauna, bacterivores, detritivores, predator-scavengers, and suspension-feeders. Based on isotopic values of vent and non-vent fauna, as well as that of surficial sediments, it is inferred that the hydrothermal ecosystem in the Guaymas Basin is self-supported with high-energy efficiency and with low exporting capacity to the background deep-sea food web.

  9. Hydrothermal Synthesis, Photocatalytic Performance, and Phase Evolution from BiOCl to Bi2Ti2O7 in the Bi-Ti-Cl-O System

    Science.gov (United States)

    Pham, Khac Vu; Nguyen, Van Hung; Nguyen, Dang Phu; Do, Danh Bich; Le, Mai Oanh; Luc, Huy Hoang

    2017-12-01

    In this work, the influence of annealing treatment on the phase evolution and photocatalytic behavior in a Bi-Ti-Cl-O system prepared by a hydrothermal method was investigated. The crystal structure, particle surface morphology, and absorption properties of the samples were characterized by x-ray diffraction, field emission scanning electron microscopy, and UV-Vis diffuse-reflectance spectroscopy, respectively. The transformation process was found to occur in three stages, involving BiOCl, Bi2Ti2O7/BiOCl composite, and Bi2Ti2O7 phases, with increasing annealing temperature. The photocatalytic activity of the samples was evaluated through photodegradation of Rhodamine B under simulated sunlight irradiation. It was found that the photocatalytic activity of Bi2Ti2O7/BiOCl nanocomposites is greater than that of BiOCl or Bi2Ti2O7. The enhanced photocatalytic activity of the Bi2Ti2O7/BiOCl nanocomposite could be attributed to the effective separation of electron-hole pairs.

  10. Post-drilling changes in seabed landscape and megabenthos in a deep-sea hydrothermal system, the Iheya North field, Okinawa Trough.

    Directory of Open Access Journals (Sweden)

    Ryota Nakajima

    Full Text Available There has been an increasing interest in seafloor exploitation such as mineral mining in deep-sea hydrothermal fields, but the environmental impact of anthropogenic disturbance to the seafloor is poorly known. In this study, the effect of such anthropogenic disturbance by scientific drilling operations (IODP Expedition 331 on seabed landscape and megafaunal habitation was surveyed for over 3 years using remotely operated vehicle video observation in a deep-sea hydrothermal field, the Iheya North field, in the Okinawa Trough. We focused on observations from a particular drilling site (Site C0014 where the most dynamic change of landscape and megafaunal habitation was observed among the drilling sites of IODP Exp. 331. No visible hydrothermal fluid discharge had been observed at the sedimentary seafloor at Site C0014, where Calyptogena clam colonies were known for more than 10 years, before the drilling event. After drilling commenced, the original Calyptogena colonies were completely buried by the drilling deposits. Several months after the drilling, diffusing high-temperature hydrothermal fluid began to discharge from the sedimentary subseafloor in the area of over 20 m from the drill holes, 'artificially' creating a new hydrothermal vent habitat. Widespread microbial mats developed on the seafloor with the diffusing hydrothermal fluids and the galatheid crab Shinkaia crosnieri endemic to vents dominated the new vent community. The previously soft, sedimentary seafloor was hardened probably due to barite/gypsum mineralization or silicification, becoming rough and undulated with many fissures after the drilling operation. Although the effects of the drilling operation on seabed landscape and megafaunal composition are probably confined to an area of maximally 30 m from the drill holes, the newly established hydrothermal vent ecosystem has already lasted 2 years and is like to continue to exist until the fluid discharge ceases and thus the

  11. Sulfate brines in fluid inclusions of hydrothermal veins: Compositional determinations in the system H2O-Na-Ca-Cl-SO4

    Science.gov (United States)

    Walter, Benjamin F.; Steele-MacInnis, Matthew; Markl, Gregor

    2017-07-01

    Sulfate is among the most abundant ions in seawater and sulfate-bearing brines are common in sedimentary basins, among other environments. However, the properties of sulfate-bearing fluid inclusions during microthermometry are as yet poorly constrained, restricting the interpretation of fluid-inclusion compositions where sulfate is a major ion. The Schwarzwald mining district on the eastern shoulder of the Upper Rhinegraben rift is an example of a geologic system characterized by sulfate-bearing brines, and constraints on the anion abundances (chloride versus sulfate) would be desirable as a potential means to differentiate fluid sources in hydrothermal veins in these regions. Here, we use the Pitzer-type formalism to calculate equilibrium conditions along the vapor-saturated liquidus of the system H2O-Na-Ca-Cl-SO4, and construct phase diagrams displaying the predicted phase equilibria. We combine these predicted phase relations with microthermometric and crush-leach analyses of fluid inclusions from veins in the Schwarzwald and Upper Rhinegraben, to estimate the compositions of these brines in terms of bulk salinity as well as cation and anion loads (sodium versus calcium, and chloride versus sulfate). These data indicate systematic differences in fluid compositions recorded by fluid inclusions, and demonstrate the application of detailed low-temperature microthermometry to determine compositions of sulfate-bearing brines. Thus, these data provide new constraints on fluid sources and paleo-hydrology of these classic basin-hosted ore-forming systems. Moreover, the phase diagrams presented herein can be applied directly to compositional determinations in other systems.

  12. Hydrothermal conversion of biomass

    OpenAIRE

    Knezevic, D.

    2009-01-01

    This thesis presents research of hydrothermal conversion of biomass (HTC). In this process, hot compressed water (subcritical water) is used as the reaction medium. Therefore this technique is suitable for conversion of wet biomass/ waste streams. By working at high pressures, the evaporation of water and high energy consumption that it requires can be avoided. The main focus of this work was HTC process aiming at production of transportation fuel intermediates. For this study, a new experime...

  13. Prior data for non-normal priors.

    Science.gov (United States)

    Greenland, Sander

    2007-08-30

    Data augmentation priors facilitate contextual evaluation of prior distributions and the generation of Bayesian outputs from frequentist software. Previous papers have presented approximate Bayesian methods using 2x2 tables of 'prior data' to represent lognormal relative-risk priors in stratified and regression analyses. The present paper describes extensions that use the tables to represent generalized-F prior distributions for relative risks, which subsume lognormal priors as a limiting case. The method provides a means to increase tail-weight or skew the prior distribution for the log relative risk away from normality, while retaining the simple 2x2 table form of the prior data. When prior normality is preferred, it also provides a more accurate lognormal relative-risk prior in for the 2x2 table format. For more compact representation in regression analyses, the prior data can be compressed into a single data record. The method is illustrated with historical data from a study of electronic foetal monitoring and neonatal death.

  14. Identification of Microorganisms by FilmArray and Matrix-Assisted Laser Desorption Ionization–Time of Flight Mass Spectrometry Prior to Positivity in the Blood Culture System

    Science.gov (United States)

    Almuhayawi, Mohammed; Altun, Osman; Strålin, Kristoffer

    2014-01-01

    In this study, we investigated the performance of the FilmArray and matrix-assisted laser desorption ionization–time of flight mass spectrometry (MALDI-TOF MS) in identifying microorganisms from blood culture (BC) bottles prior to positivity. First, we used simulated BacT/Alert FA Plus BC bottles with five each for Escherichia coli and Staphylococcus aureus isolates. The FilmArray identified all 10 isolates before BC positivity with 9/10 at 5 h and 1 at 7.5 h after incubation in the BC system. MALDI-TOF MS failed to identify the isolates prior to positivity. When the bottles were incubated for 2.5 h at room temperature (RT) before we put them into the BC system, the FilmArray identified 6/10 at 2.5 h and the remaining 4 at 5 h. Finally, we tested simulated BC bottles after incubation at RT. Interestingly, 9/10 isolates were identified with the FilmArray after 8 h of incubation at RT. Second, we studied clinical BC bottles in quadruplicate. When three-fourths of the parallel bottles signaled positive, the FilmArray was run on the fourth nonsignaled bottle and was found to be positive in 14/15 such cases. Third, we analyzed the performance of the FilmArray in the identification of microorganisms from clinical BC bottles before incubation in the system. Two milliliters of broth from 400 BC bottles was collected after arrival at the laboratory and stored at −70°C. Sixteen bottles later signaled positive in the system. When the frozen broth from these bottles was analyzed, the FilmArray identified all the microorganisms in 8/16 bottles prior to incubation in the BC system. This study shows that the FilmArray can identify microorganisms from BC bottles prior to positivity and in some cases even prior to incubation in the BC system. PMID:24951811

  15. Ozone Induced Impairment of Systemic Metabolic Processes: Influence of Prior Ozone Exposure and Metformin Pre-treatment on Aged Wistar Kyoto (WKY) Rats.

    Science.gov (United States)

    SOT2014 Abstract for presentation: March 23-27, 2014; Phoenix, AZ Ozone Induced Impairment of Systemic Metabolic Processes: Influence of Prior Ozone Exposure and Metformin Pre-treatment on Aged Wistar Kyoto (WKY) Rats. V. Bass, D. Andrews, J. Richards, M. Schladweiler, A. Ledb...

  16. Extraction of valuable compounds from mangosteen pericarps by hydrothermal assisted sonication

    Science.gov (United States)

    Machmudah, Siti; Lestari, Sarah Duta; Shiddiqi, Qifni Yasa'Ash; Widiyastuti, Winardi, Sugeng; Wahyudiono, Kanda, Hideki; Goto, Motonobu

    2015-12-01

    Valuable compounds, such as xanthone and phenolic compounds, from mangosteen pericarps was extracted by hydrothermal treatment at temperatures of 120-160 °C and pressures of 5 MPa using batch and semi-batch extractor. This method is a simple and environmentally friendly extraction method requiring no chemicals other than water. Under these conditions, there is possibility for the formation of phenolic compounds from mangosteen pericarps from decomposition of bounds between lignin, cellulose, and hemicellulose via autohydrolysis. In order to increase the amount of extracted valuable compounds, sonication pre-treament was performed prior to the hydrothermal extraction process. 30 min of sonication pre-treatment could increase significantly the amount of xanthone and phenolic compounds mangosteen pericarps extraction. In batch-system, the xanthone recovery approach to 100 % at 160 °C with 30 min sonication pre-treatment for 150 min extraction time. Under semi-batch process, the total phenolic compounds in the extract was 217 mg/g sample at 160 °C with 30 min sonication pre-treatment for 150 min total extraction time. The results revealed that hydrothermal extraction assisted sonication pre-treatment is applicable method for the isolation of polyphenolic compounds from other types of biomass and may lead to an advanced plant biomass components extraction technology.

  17. Prior indigenous technological species

    Science.gov (United States)

    Wright, Jason T.

    2018-01-01

    One of the primary open questions of astrobiology is whether there is extant or extinct life elsewhere the solar system. Implicit in much of this work is that we are looking for microbial or, at best, unintelligent life, even though technological artefacts might be much easier to find. Search for Extraterrestrial Intelligence (SETI) work on searches for alien artefacts in the solar system typically presumes that such artefacts would be of extrasolar origin, even though life is known to have existed in the solar system, on Earth, for eons. But if a prior technological, perhaps spacefaring, species ever arose in the solar system, it might have produced artefacts or other technosignatures that have survived to present day, meaning solar system artefact SETI provides a potential path to resolving astrobiology's question. Here, I discuss the origins and possible locations for technosignatures of such a prior indigenous technological species, which might have arisen on ancient Earth or another body, such as a pre-greenhouse Venus or a wet Mars. In the case of Venus, the arrival of its global greenhouse and potential resurfacing might have erased all evidence of its existence on the Venusian surface. In the case of Earth, erosion and, ultimately, plate tectonics may have erased most such evidence if the species lived Gyr ago. Remaining indigenous technosignatures might be expected to be extremely old, limiting the places they might still be found to beneath the surfaces of Mars and the Moon, or in the outer solar system.

  18. Magmatic-hydrothermal fluids and volatile metals in the Spirit Lake pluton and Margaret Cu-Mo porphyry system, SW Washington, USA

    Science.gov (United States)

    Iveson, Alexander A.; Webster, James D.; Rowe, Michael C.; Neill, Owen K.

    2016-03-01

    metasomatism by halogen-bearing exsolved fluid(s) is provided by the high Mg# (>70) secondary amphiboles and biotites from within the Spirit Lake pluton, where the amphiboles are clear replacement products of primary pyroxenes. Fluid halogen fugacity ratios calculated from the biotite compositions overlap with other global mineralised porphyry systems, despite not being immediately associated with sulphide ores. The evidence suggests complex fluid processes and the coincidental development of the mineralised porphyry system within the pluton. Heat, fluids, and metals were therefore likely supplied by a later phase of magmatism, unrelated to the consolidation of the main Spirit Lake granitoid. These new constraints on magmatic-hydrothermal fluid signatures have wider applicability to potentially tracing proximal barren and mineralised processes, and for distinguishing between formation mechanisms for primary and secondary halogen-bearing minerals.

  19. Regional setting and characteristics of the Neoproterozoic Wadi Hamama Zn-Cu-Ag-Au prospect: evidence for an intra-oceanic island arc-hosted volcanogenic hydrothermal system

    Science.gov (United States)

    Abd El-Rahman, Yasser; Surour, Adel A.; El-Manawi, Abdel Hamid W.; El-Dougdoug, Abdel-Monem A.; Omar, Sayed

    2015-04-01

    The Wadi Hamama area is a volcanogenic Zn-Cu-Au-Ag prospect. It is hosted by a Neoproterozoic bimodal-mafic sequence, which comprises basalt, dacite and rhyolite along with volcaniclastic rocks. The rocks have a low-K tholeiitic affinity and are enriched in large ion lithophile elements over high field strength elements, which indicated their formation in an intra-oceanic island arc tectonic setting. The area was intruded by a tonalite-trondhjemite body, which has an intra-oceanic island arc affinity and later by diorite, which has a cordilleran-margin geochemical affinity. These rock units were intruded by post-tectonic granite dykes, which have a within-plate geochemical signature. There is a quartz-carbonate horizon extending along the contact between the basalt and the volcaniclastic rocks, mainly banded and lapilli tuffs. This horizon is of exhalative origin and is underlain by a mushroom-shaped alteration zone extending from the horizon down to the massive basalt. The footwall alteration is characterized by a silica-rich core surrounded by a thick chlorite sheath. Both the quartz-carbonate horizon and the footwall-altered rocks enclose historical trenches and pits. Sulfide-rich core samples are enriched in Zn, relative to Cu, and in Ag, which indicates the low-temperature nature of the hydrothermal system. The prospect was affected by supergene processes, which led to the widespread occurrence of secondary copper minerals and gold enrichment relative to the leached base metals, especially Zn. The prospect formed through a limited rifting of an intra-oceanic island arc which resulted in the formation of a small-scale volcanogenic Zn-Cu-Ag-Au prospect.

  20. Hydrothermal system of the Papandayan Volcano, West Java, Indonesia and its geochemistry evolution of thermal water after the November 2002 eruption

    Directory of Open Access Journals (Sweden)

    Agnes Mazot

    2014-06-01

    Full Text Available http://dx.doi.org/10.17014/ijog.vol2no1.20072Papandayan is a strato volcano situated in West Java, Indonesia. After the last magmatic eruptionin 1772, only few phreatic explosions have been occurring. At the present time, the activity is centeredin the northeast crater manifested by the presence of fumaroles and hot springs. In November 2002an explosive eruption occurred and ejected ash and altered rocks. Study of the altered rocks revealedthat an advanced argillic alteration took place in the hydrothermal system by an interaction betweenacid fl uids and rocks. Four zones of alteration have been formed as a limited extension along faults oracross permeable structures at different levels beneath the active crater of the volcano.Two types of acid fl uids are distinguished in the crater of the Papandayan Volcano: (1 acidsulphate-chloride water with pH values between 1.6 and 4.6, and (2 acid sulphate water with pHvalues between 1.2 and 2.5. The samples collected after the eruption revealed an increase in the SO4/Cl and Mg / Cl ratios. This evolution is likely explained by an increase in the neutralization of acidfl uids which tends to show that water-rock interactions were more signifi cant after the eruption. Thechanges in chemistry observed in 2003 were the consequence of the opening of new fractures whereunaltered or less altered volcanic rocks were in contact with the ascending acid water. The high δ34Svalues (9-17‰ observed in the acid sulphate-chloride water before the November 2002 eruptionsuggest that dissolved sulphates were mainly formed by the disproportionation of magmatic SO2. Onthe other hand, the low δ34S values (-0.3-7 ‰ observed in acid sulphate-chloride water sampled afterthe eruption suggest that the origin of dissolved sulphates for these waters is the surfi cial oxidation ofhydrogen sulphide.

  1. Lutibacter profundi sp. nov., isolated from a deep-sea hydrothermal system on the Arctic Mid-Ocean Ridge and emended description of the genus Lutibacter.

    Science.gov (United States)

    Le Moine Bauer, Sven; Roalkvam, Irene; Steen, Ida Helene; Dahle, Håkon

    2016-07-01

    A bacterial strain designated LP1T was isolated from a microbial mat growing on the surface of a black smoker chimney at the Loki's Castle hydrothermal system, which is located on the Arctic Mid-Ocean Ridge. Phylogenetic analyses based on 16S rRNA gene sequences positioned strain LP1T within the family Flavobacteriaceae with Lutibacterholmesii as the closest relative (97.5 % 16S rRNA gene sequence similarity). Strain LP1T was rod-shaped, Gram-reaction-negative and non-motile. It grew in a modified artificial seawater medium supplemented with tryptone and vitamins at pH 5.5-7.5 (optimum pH 6.0-6.5), within a temperature range of 13-34 °C (optimum 23 °C), and under microaerobic conditions. The most abundant fatty acids (>10 %) were iso-C15 : 0 (25.2 %) and iso-C15 : 0 3-OH (14.5 %). The genome of strain LP1T has a DNA G+C content of 29.8 mol%. Based on the results of the polyphasic characterization presented here, strain LP1T is considered to represent a novel species of the genus Lutibacter, for which the name Lutibacter profundi sp. nov. is proposed. The type strain is LP1T (=DSM 100437T =JCM 30585T). An emended description of the genus Lutibacter is also provided to fit the description of strain LP1T.

  2. Spontaneous and Widespread Electricity Generation in Natural Deep-Sea Hydrothermal Fields.

    Science.gov (United States)

    Yamamoto, Masahiro; Nakamura, Ryuhei; Kasaya, Takafumi; Kumagai, Hidenori; Suzuki, Katsuhiko; Takai, Ken

    2017-05-15

    Deep-sea hydrothermal vents discharge abundant reductive energy into oxidative seawater. Herein, we demonstrated that in situ measurements of redox potentials on the surfaces of active hydrothermal mineral deposits were more negative than the surrounding seawater potential, driving electrical current generation. We also demonstrated that negative potentials in the surface of minerals were widespread in the hydrothermal fields, regardless of the proximity to hydrothermal fluid discharges. Lab experiments verified that the negative potential of the mineral surface was induced by a distant electron transfer from the hydrothermal fluid through the metallic and catalytic properties of minerals. These results indicate that electric current is spontaneously and widely generated in natural mineral deposits in deep-sea hydrothermal fields. Our discovery provides important insights into the microbial communities that are supported by extracellular electron transfer and the prebiotic chemical and metabolic evolution of the ocean hydrothermal systems. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. A New Deep-Sea Hydrothermal Vent Species of Ostracoda (Crustacea) from the Western Pacific: Implications for Adaptation, Endemism, and Dispersal of Ostracodes in Chemosynthetic Systems.

    Science.gov (United States)

    Tanaka, Hayato; Yasuhara, Moriaki

    2016-10-01

    Deep-sea hydrothermal vent fields are among the most extreme habitats on Earth. Major research interests in these ecosystems have focused on the anomalous macrofauna, which are nourished by chemoautotrophic bacterial endosymbionts. In contrast, the meiofauna is largely overlooked in this chemosynthetic environment. The present study describes a new species, Thomontocypris shimanagai sp. nov. (Crustacea: Ostracoda), which was collected from the surface of colonies of neoverrucid barnacles and paralvinellid worms on the chimneys at the Myojin-sho submarine caldera. This is the first discovery of an ostracode from deep-sea hydrothermal vent environments in the western Pacific region. In addition to the species description, we discuss three aspects: 1) adaptation, 2) endemism, and 3) dispersal strategy of the hydrothermal vent ostracodes. Regarding these aspects, we conclude the following: 1) the new species may feed on sloughed-off tissues, mucus secretions, or fecal pellets of sessile organisms, rather than depend on chemoautotrophic bacteria as symbionts for energy; 2) as has been pointed out by other studies, Thomontocypris does not likely represent a vent-specific genus; however, this new species is considered to be endemic at the species level, as it has not been found outside of the type locality; and 3) this new species may have migrated from adjacent deep-sea chemosynthesis-based habitats, such as hydrothermal vents, with wood falls potentially having acted as stepping stones.

  4. Tracing thermal aquifers of El Chichón volcano-hydrothermal system (México) with 87Sr/ 86Sr, Ca/Sr and REE

    Science.gov (United States)

    Peiffer, L.; Taran, Y. A.; Lounejeva, E.; Solís-Pichardo, G.; Rouwet, D.; Bernard-Romero, R. A.

    2011-08-01

    The volcano-hydrothermal system of El Chichón volcano, Chiapas, Mexico, is characterized by numerous thermal manifestations including an acid lake, steam vents and boiling springs in the crater and acid and neutral hot springs and steaming ground on the flanks. Previous research on major element chemistry reveals that thermal waters of El Chichón can be divided in two groups: (1) neutral waters discharging in the crater and southern slopes of the volcano with chloride content ranging from 1500 to 2200 mg/l and (2) acid-to-neutral waters with Cl up to 12,000 mg/l discharging at the western slopes. Our work supports the concept that each group of waters is derived from a separate aquifer (Aq. 1 and Aq. 2). In this study we apply Sr isotopes, Ca/Sr ratios and REE abundances along with the major and trace element water chemistry in order to discriminate and characterize these two aquifers. Waters derived from Aq. 1 are characterized by 87Sr/ 86Sr ratios ranging from 0.70407 to 0.70419, while Sr concentrations range from 0.1 to 4 mg/l and Ca/Sr weight ratios from 90 to 180, close to average values for the erupted rocks. Waters derived from Aq. 2 have 87Sr/ 86Sr between 0.70531 and 0.70542, high Sr concentrations up to 80 mg/l, and Ca/Sr ratio of 17-28. Aquifer 1 is most probably shallow, composed of volcanic rocks and situated beneath the crater, within the volcano edifice. Aquifer 2 may be situated at greater depth in sedimentary rocks and by some way connected to the regional oil-gas field brines. The relative water output (l/s) from both aquifers can be estimated as Aq. 1/Aq. 2-30. Both aquifers are not distinguishable by their REE patterns. The total concentration of REE, however, strongly depends on the acidity. All neutral waters including high-salinity waters from Aq. 2 have very low total REE concentrations (< 0.6 μg/l) and are characterized by a depletion in LREE relative to El Chichón volcanic rock, while acid waters from the crater lake (Aq. 1) and acid

  5. Interactions Between Serpentinization, Hydrothermal Activity and Microbial Community at the Lost City Hydrothermal Field

    Science.gov (United States)

    Delacour, A.; Frueh-Green, G. L.; Bernasconi, S. M.; Schaeffer, P.; Frank, M.; Gutjahr, M.; Kelley, D. S.

    2008-12-01

    Seafloor investigations of slow- and ultraslow-spreading ridges have reported many occurrences of exposed mantle peridotites and gabbroic rocks on the ocean floor. Along the Mid-Atlantic Ridge, these uplifted portions of oceanic crust host high-temperature black smoker-type hydrothermal systems (e.g., Rainbow, Logatchev, Saldanha), and the more distinct low-temperature Lost City Hydrothermal Field (LCHF). Built on a southern terrace of the Atlantis Massif, the LCHF is composed of carbonate-brucite chimneys that vent alkaline and low-temperature (40-90°C) hydrothermal fluids. These fluids are related to serpentinization of mantle peridotites, which together with minor gabbroic intrusions form the basement of the LCHF. Long-lived hydrothermal activity at Lost City led to extensive seawater-rock interaction in the basement rocks, as indicated by seawater-like Sr- and mantle to unradiogenic Nd-isotope compositions of the serpentinites. These high fluid fluxes in the southern part of the massif influenced the conditions of serpentinization and have obliterated the early chemical signatures in the serpentinites, especially those of carbon and sulfur. Compared to reducing conditions commonly formed during the first stages of serpentinization, serpentinization at Lost City is characterized by relatively oxidizing conditions resulting in a predominance of magnetite, the mobilization/dissolution and oxidation of igneous sulfides to secondary pyrite, and the incorporation of seawater sulfate, all leading to high bulk-rock S-isotope compositions. The Lost City hydrothermal fluids contain high concentrations in methane, hydrogen, and low-molecular weight hydrocarbons considered as being produced abiotically. In contrast, organic compounds in the serpentinites are dominated by the occurrences of isoprenoids (pristane, phytane, and squalane), polycyclic compounds (hopanes and steranes), and higher abundances of C16 to C20 n-alkanes indicative of a marine organic input. We

  6. Metal-rich Scales in the Reykjanes Geothermal System, SW Iceland: Sulfide Minerals in a Seawater-dominated Hydrothermal Environment

    Science.gov (United States)

    Hardardottir, Vigdis

    Downhole sampling of unboiled liquid at 1350 and 1500 m depth in the seawater-dominated Reykjanes high-temperature geothermal system in Iceland shows that metal concentrations measured at surface are minimum values due to mineral precipitation in the wells; by analogy of similar tectonic setting, host rocks and fluid composition, the metal concentrations measured in many black smoker vents at the seafloor are also minima. Fluids in the Reykjanes geothermal system react with mid-ocean ridge basalt at temperatures as high as 346°C and contain Fe 9-140 ppm, Cu 14-17 ppm, Zn 5-27 ppm, Pb 120-290 ppb, 1-6 ppb Au, and 28-107 ppb Ag. Fluids discharged at surface from the same wells have orders of magnitude lower metal concentrations due to precipitation caused by boiling and vapor loss during depressurization. Upstream of the orifice plate at high pressure (40 bar, 252°C) the precipitates consist mainly of sphalerite and chalcopyrite with a trace of galena and bornite. At the orifice plate of old wells, the pressure decreased sharply to 11 bar (188°C), resulting in abundant deposition of amorphous silica together with minor sphalerite and traces of chalcopyrite. In new wells the pressure at the orifice plate decreases to 22 bar (220°C); this pressure decrease and concomitant boiling causes deposition of fine-grained bornite-digenite solid solution together with sphalerite and galena on the fluid flow control valve. In high-pressure wells (average wellhead pressure 45-35 bar) most metals (mainly as sphalerite) are deposited downstream of the orifice plate, with up to 950 ppm Au and 2.5 wt.% Ag. Bulk concentrations in the scales vary between 15-60 wt.% upstream and downstream of the orifice plate and diminish from there. Iron increases up well from 8 to ˜20 wt.% and decreases downstream of the orifice plate from 6 to 2 wt.% at the separation station; Cu downhole is ˜3 wt.% but increases to 25 wt.% on the fluid flow control valve and then decreases; Pb downhole 100s

  7. An efficient linear approach towards the planning of the energetic operation in hydrothermal power systems; Uma eficiente abordagem linear para o planejamento da operacao energetica de sistemas hidrotermicos de potencia

    Energy Technology Data Exchange (ETDEWEB)

    Carneiro, Adriano A.F.M.; Zambon, Katia L. [Sao Paulo Univ., Sao Carlos, SP (Brazil). Escola de Engenharia. Dept. de Engenharia Eletrica

    1997-12-31

    In this paper the the operation planning of hydrothermal systems is formulated with a simplified hydroelectric generation function, resulting in an quadratic objective function. In this function were applied linearization techniques, with separable methods, and the quadratic programming technique. In the obtained models were possible to apply the Simplex, a simple, quick and efficient method. The most important features were the preservation of the system physic characteristics. (author) 6 refs., 10 figs., 2 tabs.; e-mail: adriano at sel.eesc.sc.usp.br

  8. Hydrothermal phase transformation of hematite to magnetite.

    Science.gov (United States)

    Lu, Jie-Feng; Tsai, Cho-Jen

    2014-01-01

    Different phases of iron oxide were obtained by hydrothermal treatment of ferric solution at 200°C with the addition of either KOH, ethylenediamine (EDA), or KOH and EDA into the reaction system. As usually observed, the α-Fe2O3 hexagonal plates and hexagonal bipyramids were obtained for reaction with KOH and EDA, respectively. When both KOH and EDA were added into the reaction system, we observed an interesting phase transformation from α-Fe2O3 to Fe3O4 at low-temperature hydrothermal conditions. The phase transformation involves the formation of α-Fe2O3 hexagonal plates, the dissolution of the α-Fe2O3 hexagonal plates, the reduction of Fe(3+) to Fe(2+), and the nucleation and growth of new Fe3O4 polyhedral particles.

  9. Physiological and isotopic characteristics of nitrogen fixation by hyperthermophilic methanogens: Key insights into nitrogen anabolism of the microbial communities in Archean hydrothermal systems

    Science.gov (United States)

    Nishizawa, Manabu; Miyazaki, Junichi; Makabe, Akiko; Koba, Keisuke; Takai, Ken

    2014-08-01

    Hyperthermophilic hydrogenotrophic methanogens are considered to be one of the most predominant primary producers in hydrogen (H2)-abundant hydrothermal environments in the present-day ocean and throughout the history of the Earth. However, the nitrogen sources supporting the development of microbial communities in hydrothermal environments remain poorly understood. We have investigated, for the first time, methanogenic archaea commonly found in deep-sea hydrothermal environments to understand their physiological properties (growth kinetics, energetics, and metal requirements) and isotopic characteristics during the fixation of dinitrogen (N2), which is an abundant but less-bioavailable compound in hydrothermal fluids. Culture experiments showed that Methanocaldococcus strain (Mc 1-85N) (Topt = 85 °C) and Methanothermococcus strain (Mt 5-55N) (Topt = 55 °C) assimilated N2 and ammonium, but not nitrate. Previous phylogenetic studies have predicted that the Methanocaldococcus and Methanothermococcus lineages have nitrogenases, key enzymes for N2 fixation, with biochemically uncharacterised active site metal cofactors. We showed that Mt 5-55N required molybdenum for the nitrogenase to function, implying a molybdenum-bearing cofactor in the strain. Molybdenum also stimulated diazotrophic (i.e., N2-fixing) growth of Mc 1-85N, though further experiments are required to test whether the strain contains a molybdenum-dependent nitrogenase. Importantly, Mc 1-85N exhibited an apparently lower requirement of and higher tolerance to molybdenum and iron than Mt 5-55N. Furthermore, both strains produced more 15N-depleted biomass (-4‰ relative to N2) than that previously reported for diazotrophic photosynthetic prokaryotes. These results demonstrate that diazotrophic hyperthermophilic methanogens can be broadly distributed in seafloor and subseafloor hydrothermal environments, where the availability of transition metals is variable and where organic carbon, organic nitrogen

  10. Identification of microorganisms by FilmArray and matrix-assisted laser desorption ionization-time of flight mass spectrometry prior to positivity in the blood culture system.

    Science.gov (United States)

    Almuhayawi, Mohammed; Altun, Osman; Strålin, Kristoffer; Ozenci, Volkan

    2014-09-01

    In this study, we investigated the performance of the FilmArray and matrix-assisted laser desorption ionization-time of flight mass spectrometry (MALDI-TOF MS) in identifying microorganisms from blood culture (BC) bottles prior to positivity. First, we used simulated BacT/Alert FA Plus BC bottles with five each for Escherichia coli and Staphylococcus aureus isolates. The FilmArray identified all 10 isolates before BC positivity with 9/10 at 5 h and 1 at 7.5 h after incubation in the BC system. MALDI-TOF MS failed to identify the isolates prior to positivity. When the bottles were incubated for 2.5 h at room temperature (RT) before we put them into the BC system, the FilmArray identified 6/10 at 2.5 h and the remaining 4 at 5 h. Finally, we tested simulated BC bottles after incubation at RT. Interestingly, 9/10 isolates were identified with the FilmArray after 8 h of incubation at RT. Second, we studied clinical BC bottles in quadruplicate. When three-fourths of the parallel bottles signaled positive, the FilmArray was run on the fourth nonsignaled bottle and was found to be positive in 14/15 such cases. Third, we analyzed the performance of the FilmArray in the identification of microorganisms from clinical BC bottles before incubation in the system. Two milliliters of broth from 400 BC bottles was collected after arrival at the laboratory and stored at -70°C. Sixteen bottles later signaled positive in the system. When the frozen broth from these bottles was analyzed, the FilmArray identified all the microorganisms in 8/16 bottles prior to incubation in the BC system. This study shows that the FilmArray can identify microorganisms from BC bottles prior to positivity and in some cases even prior to incubation in the BC system. Copyright © 2014, American Society for Microbiology. All Rights Reserved.

  11. Solute fluxes from Tacaná volcano-hydrothermal system, Mexico-Guatemala. Implications for estimation of geothermal potential of the deep aquifer.

    Science.gov (United States)

    Collard, N.; Taran, Y.; Jácome Paz, M. P.; Campion, R.

    2014-12-01

    Tacaná (4100 m asl) is the northernmost volcano of the Central America Volcanic Arc. The volcano hosts a volcano-hydrothermal system that is manifested as a low-temperature fumarolic field at 3600 m asl and several groups of thermal springs principally located at the northwestern slopes of the volcanic edifice, at altitudes 1500 - 2000 m asl. These thermal springs discharge SO4-HCO3-enriched water (up to 1 g/kg of each one) with temperatures in the 25-63°C range. There are two distinct groups of springs with a different chloride-temperature and chloride-sulfate correlations but with the same 87Sr/86Sr ratio (~0.7046±0.0002) indicating the same wall rock composition for different aquifers. On April 2014, we found a cold spring (Manantial Nuevo), located at an elevation ~500 m lower than the others and with a different chemical composition, that discharges Na-Cl-type water with Cl concentration of 1.4 g/l and Na+K concentration up to 1.5 g/l. This new spring forms a fourth group, representing a stratified geothermal aquifer. Each thermal spring feeds a thermal stream that flows into the main drainage of the area, Río Coatán. Solute and heat fluxes from thermal springs of Tacaná volcano are estimated by the chloride-inventory method. The total observed chloride discharge from the thermal springs is estimated as 14.8 g/s and the total measured heat output of ~9.5 MW. Considering a deep fluid temperature of 250°C, the corresponding advective heat transport from the deep reservoirs that feed these springs may be estimate as 26 MW. However, the total chloride output measured in the main drainage (Coatán river) is 4 times higher (~59 g/s) than the measured Cl output of all known thermal springs. This means that other, undiscovered, thermal discharges exist in the area and that the natural heat output through thermal springs at Tacaná is significantly higher and depends on the Cl content and temperatures of the unknown thermal water discharges. If chloride

  12. Study of growth of gadolinium-doped ceria nanobelts by a hydrothermal microwave system; Estudo do crescimento de nanofitas de ceria dopada com gadolinio por sistema de aquecimento por micro-ondas

    Energy Technology Data Exchange (ETDEWEB)

    Goncalves, R.F.; Castro, D.A.; Santos, M.R.C.; Figueiredo, A.T.; Godinho Junior, M. [Universidade Federal de Goias (UFG), Catalao, GO (Brazil). Dept. de Quimica; Barrado, C.M. [Universidade Federal do Para (UFPA), Belem, PA (Brazil). Inst. de Ciencias Exatas e Naturais; Leite, E.R. [Universidade Federal de Sao Carlos (INCTMN/UFSCar), SP (Brazil). Dept. de Qumica

    2013-07-15

    Cerium oxide (ceria) has attracted attention because of its important applications such as solid oxide fuel cells, catalysts for automobile exhaust gas, catalysts to obtain hydrogen, UV blockers, biomaterials, etc.. Control methods for synthesis of ceria are of great importance to explain or predict these properties. Thus, the objective of this work was to study the growth of cerium oxide nanobelts in a microwave-assisted hydrothermal system, where in 8 min 330 nm nanobelts were obtained at 130 deg C and 3 atm. The results collaborate to the research on reformers for ethanol and/or solid oxide fuel cells anode. (author)

  13. Development of acoustic observation method for seafloor hydrothermal flows

    Science.gov (United States)

    Mochizuki, M.; Tamura, H.; Asada, A.; Kinoshita, M.; Tamaki, K.

    2012-12-01

    In October 2009, we conducted seafloor reconnaissance using a manned deep-sea submersible Shinkai6500 in Central Indian Ridge 18-20deg.S, where hydrothermal plume signatures were previously perceived. Acoustic video camera "DIDSON" was equipped on the top of Shinkai6500 in order to get acoustic video images of hydrothermal plumes. The acoustic video images of the hydrothermal plumes had been captured in three of seven dives. We could identify shadings inside the acoustic video images of the hydrothermal plumes. Silhouettes of the hydrothermal plumes varied from second to second, and the shadings inside them also varied. These variations corresponded to internal structures and flows of the plumes. DIDSON (Dual-Frequency IDentification SONar) is acoustic lens-based sonar. It has sufficiently high resolution and rapid refresh rate that it can substitute for optical system in turbid or dark water where optical systems fail. Ins. of Industrial Science, University of Tokyo has understood DIDSON's superior performance and tried to develop a new observation method based on DIDSON for hydrothermal discharging from seafloor vent. We expected DIDSON to reveal whole image of hydrothermal plume as well as detail inside the plume. The proposed method to observe and measure hydrothermal flow is the one to utilize a sheet-like acoustic beam. Scanning with concentrated acoustic beam gives distances to the edges of the hydrothermal flows. And then, the shapes of the flows can be identified even in low and zero visibility conditions. Tank experiment was conducted. The purposes of this experiment were to make an attempt at proposed method to delineate underwater hydrothermal flows and to understand relationships among acoustic video image, flow rate and water temperature. Water was heated in the hot tub and pumped to the water tank through the silicon tube. We observed water flows discharging from the tip of the tube with DIDSON. Flow rate had been controlled and temperatures of the

  14. Hydrothermal alteration in oceanic ridge volcanics: A detailed study at the Galapagos Fossil Hydrothermal Field

    Science.gov (United States)

    Ridley, W.I.; Perfit, M.R.; Josnasson, I.R.; Smith, M.F.

    1994-01-01

    The Galapagos Fossil Hydrothermal Field is composed of altered oceanic crust and extinct hydrothermal vents within the eastern Galapagos Rift between 85??49???W and 85??55???W. The discharge zone of the hydrothermal system is revealed along scarps, thus providing an opportunity to examine the uppermost mineralized, and highly altered interior parts of the crust. Altered rocks collected in situ by the submersible ALVIN show complex concentric alteration zones. Microsamples of individual zones have been analysed for major/minor, trace elements, and strontium isotopes in order to describe the complex compositional details of the hydrothermal alteration. Interlayered chlorite-smectite and chlorite with disequilibrium compositions dominate the secondary mineralogy as replacement phases of primary glass and acicular pyroxene. Phenocrysts and matrix grains of plagioclase are unaffected during alteration. Using a modification of the Gresens' equation we demonstrate that the trivalent rare earth elements (REEs) are relatively immobile, and calculate degrees of enrichment and depletion in other elements. Strontium isotopic ratios increase as Sr concentrations decrease from least-altered cores to most-altered rims and cross-cutting veins in individual samples, and can be modeled by open system behaviour under low fluid-rock ratio (< 10) conditions following a period of lower-temperature weathering of volcanics within the rift zone. The complex patterns of element enrichment and depletion and strontium isotope variations indicate mixing between pristine seawater and ascending hot fluids to produce a compositional spectrum of fluids. The precipitation of base-metal sulfides beneath the seafloor is probably a result of fluid mixing and cooling. If, as suggested here, the discharge zone alteration occurred under relatively low fluid-rock ratios, then this shallow region must play an important role in determining the exit composition of vent fluids in marine hydrothermal systems

  15. Full System Decontamination (FSD) with the CORD{sup R} Family prior to Decommissioning - Experiences at the German NPP Obrigheim 2007

    Energy Technology Data Exchange (ETDEWEB)

    Topf, Christian [Department STC-G, AREVA NP GmbH, P.O. Box 1109, 91001 Erlangen (Germany)

    2008-07-01

    Minimizing personal radiation exposure and obtaining material free for release are the highest priorities for the decommissioning of a NPP. This calls for a FSD as the first and most effective measure. AREVA NP has a long experience with FSDs, not only for operating plants but also for decommissioning in particular. Starting 1986 with the first decontamination for decommissioning at the NPP FR2, a German research reactor, AREVA NP has performed more than 10 FSDs worldwide prior to NPP dismantling. Based on these long term decontamination experiences including the successful performance of the FSD at the German PWR in Stade 2005, AREVA NP received the contract for the FSD prior to decommissioning at the German PWR in Obrigheim (357 MWe). The NPP Obrigheim was permanently shut down in May 2005 after 36 years of operation. The decontamination of the complete primary circuit and the auxiliary systems RHR and CVCS was performed in the first quarter of 2007. The total system volume was 160 m{sup 3}, total system surface approximately 8100 m{sup 2}. Decontamination was carried out with the worldwide approved decontamination process HP/CORD D UV, using NPP own systems and the AREVA NP AMDA decontamination equipment. In the paper detailed results of the decontamination will be outlined. An important value for further decommissioning activities was the remarkable dose rate reduction at the heavy components, especially the steam generators. The average decontamination factor achieved at the systems exceeded the value of 600. (author)

  16. Strengths, challenges, and opportunities for hydrothermal pretreatment in lignocellulosic biorefineries: Hydrothermal Pretreatment

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Bin [Bioproducts, Sciences, and Engineering Laboratory, Department of Biological Systems Engineering, Washington State University, Richland WA USA; Tao, Ling [National Bioenergy Center, National Renewable Energy Laboratory, Golden CO USA; Wyman, Charles E. [Chemical and Environmental Engineering Department and Center for Environmental Research and Technology, Bourns College of Engineering, University of California at Riverside, CA, USA, BioEnergy Science Center (BESC), Oak Ridge National Laboratory, TN USA

    2017-10-11

    Pretreatment prior to or during biological conversion is required to achieve high sugar yields essential to economic production of fuels and chemicals from low cost, abundant lignocellulosic biomass. Aqueous thermochemical pretreatments achieve this performance objective from pretreatment coupled with subsequent enzymatic hydrolysis, but chemical pretreatment can also suffer from additional costs for exotic materials of construction, the need to recover or neutralize the chemicals, introduction of compounds that inhibit downstream operations, and waste disposal, as well as for the chemicals themselves. The simplicity of hydrothermal pretreatment with just hot water offers the potential to greatly improve the cost of the entire conversion process if sugar degradation during pretreatment, production of un-fermentable oligomers, and the amount of expensive enzymes needed to obtain satisfactory yields from hydrothermally pretreated solids can be reduced. Biorefinery economics would also benefit if value could be generated from lignin and other components that are currently fated to be burned for power. However, achieving these goals will no doubt require development of advanced hydrothermal pretreatment configurations. For example, passing water through a stationary bed of lignocellulosic biomass in a flowthrough configuration achieves very high yields of hemicellulose sugars, removes more than 75% of the lignin for potential valorization, and improves sugar release from the pretreated solids with lower enzyme loadings. Unfortunately, the large quantities of water needed to achieve this performance result in very dilute sugars, high energy costs for pretreatment and product recover, and large amounts of oligomers. Thus, improving our understanding of hydrothermal pretreatment fundamentals is needed to gain insights into R&D opportunities to improve performance, and help identify novel configurations that lower capital and operating costs and achieve higher yields.

  17. Expected fluid residence times, thermal breakthrough, and tracer test design for characterizing a hydrothermal system in the Upper Rhine Rift Valley

    Science.gov (United States)

    Ghergut, I.; Meixner, J.; Rettenmaier, D.; Maier, F.; Nottebohm, M.; Ptak, T.; Sauter, M.

    2012-04-01

    Relying on the structural-hydrogeological model proposed by J. Meixner (2009) for a particular hydrothermal system in South-West Germany (on the East side of the Upper Rhine Rift, this reservoir being used to demonstrate electricity production by means of a well doublet), we set up a distributed-parameter model (using Feflow) enabling to numerically simulate fluid ages, temperature evolutions and tracer test signals for a number of contrasting assumptions w. r. to (a) the nature of boundary conditions and hydrogeological characteristics of remotely situated, large-scale natural faults, (b) the degree of permeability contrast between different system compartments, (c) the hydrogeological characteristics of a naturally-occurring fault, located between injection and production wells. It appears that a spike dimensioning allowing for tracer signals to become detectable during the first three years after tracer injection in all of the contrasting a/b/c scenarios is not feasible in practice. In some of the a/b/c cases considered, the system will act like a very large reservoir, with fluid residence times in the order of decades, and extreme dilution of injected tracers. Even using preparative-scale cleaning of samples, brine separation, sample enrichment by solid phase extraction, evaporative concentrating etc. followed by state-of-the-art chromatography techniques to separate between tracer and natural background, it will not be possible to lower tracer detection limits below a certain threshold, which is mainly dictated by the amount of certain naturally-occurring aromatics in the reservoir fluids. On practical reasons, the spike dimensioning will be limited to some hundred kilogram of one or two organic tracers. This implies that part of the above-mentioned, contrasting a/b/c scenarios will remain indistinguishable during the first three years after tracer injection. However, for this reservoir structure, there is not a bijective correspondence between early

  18. Boiling vapour-type fluids from the Nifonea vent field (New Hebrides Back-Arc, Vanuatu, SW Pacific): Geochemistry of an early-stage, post-eruptive hydrothermal system

    Science.gov (United States)

    Schmidt, Katja; Garbe-Schönberg, Dieter; Hannington, Mark D.; Anderson, Melissa O.; Bühring, Benjamin; Haase, Karsten; Haruel, Christy; Lupton, John; Koschinsky, Andrea

    2017-06-01

    In 2013, high-temperature vent fluids were sampled in the Nifonea vent field. This field is located within the caldera of a large shield-type volcano of the Vate Trough, a young extensional rift in the New Hebrides back-arc. Hydrothermal venting occurs as clear and black smoker fluids with temperatures up to 368 °C, the hottest temperatures measured so far in the western Pacific. The physico-chemical conditions place the fluids within the two-phase field of NaCl-H2O, and venting is dominated by vapour phase fluids with Cl concentrations as low as 25 mM. The fluid composition, which differs between the individual vent sites, is interpreted to reflect the specific geochemical fluid signature of a hydrothermal system in its initial, post-eruptive stage. The strong Cl depletion is accompanied by low alkali/Cl ratios compared to more evolved hydrothermal systems, and very high Fe/Cl ratios. The concentrations of REY (180 nM) and As (21 μM) in the most Cl-depleted fluid are among the highest reported so far for submarine hydrothermal fluids, whereas the inter-element REY fractionation is only minor. The fluid signature, which has been described here for the first time in a back-arc setting, is controlled by fast fluid passage through basaltic volcanic rocks, with extremely high water-rock ratios and only limited water-rock exchange, phase separation and segregation, and (at least) two-component fluid mixing. Metals and metalloids are unexpectedly mobile in the vapour phase fluids, and the strong enrichments of Fe, REY, and As highlight the metal transport capacity of low-salinity, low-density vapours at the specific physico-chemical conditions at Nifonea. One possible scenario is that the fluids boiled before the separated vapour phase continued to react with fresh glassy lavas. The mobilization of metals is likely to occur by leaching from fresh glass and grain boundaries and is supported by the high water/rock ratios. The enrichment of B and As is further controlled

  19. Pre-Service and In-Service Teachers' Perceptions toward White Board System Prior to Actual Experience

    Science.gov (United States)

    Park, Ju

    2014-01-01

    Using sample of survey data by pre-service and in-service teachers attending at a regional campus, this study examined how undergraduate and graduate students, in education major, perceived interactive white boards (IWB), and described implications of how the system can be used effectively, based on student-centered pedagogy. Although the…

  20. Impact-generated Hydrothermal Activity at the Chicxulub Crater

    Science.gov (United States)

    Kring, D. A.; Zurcher, L.; Abramov, O.

    2007-05-01

    Borehole samples recovered from PEMEX exploration boreholes and an ICDP scientific borehole indicate the Chicxulub impact event generated hydrothermal alteration throughout a large volume of the Maya Block beneath the crater floor and extending across the bulk of the ~180 km diameter crater. The first indications of hydrothermal alteration were observed in the crater discovery samples from the Yucatan-6 borehole and manifest itself in the form of anhydrite and quartz veins. Continuous core from the Yaxcopoil-1 borehole reveal a more complex and temporally extensive alteration sequence: following a brief period at high temperatures, impact- melt-bearing polymict breccias and a thin, underlying unit of impact melt were subjected to metasomatism, producing alkali feldspar, sphene, apatite, and magnetite. As the system continued to cool, smectite-series phyllosilicates appeared. A saline solution was involved. Stable isotopes suggest the fluid was dominated by a basinal brine created mostly from existing groundwater of the Yucatan Peninsula, although contributions from down-welling water also occurred in some parts of the system. Numerical modeling of the hydrothermal system suggests circulation occurred for 1.5 to 2.3 Myr, depending on the permeability of the system. Our understanding of the hydrothermal system, however, is still crude. Additional core recovery projects, particularly into the central melt sheet, are needed to better evaluate the extent and duration of hydrothermal alteration.

  1. Impacts of post-mortem ageing prior to freezing on technological and oxidative properties of coarse ground lamb sausage in a model system

    Directory of Open Access Journals (Sweden)

    Juhui Choe

    2017-07-01

    Full Text Available Objective The objective of this study was to evaluate the effects of ageing time of lamb loins prior to freezing on technological characteristics and oxidation stability of coarse ground lamb loin sausage using in a model system. Methods Lamb loins (M. longissimus lumborum, n = 25 were aged at −1.5°C for 0, 1, 2, 3, and 8 wk and then frozen for the remaining days (a total of 30 wk. The aged/frozen/thawed lamb loins were ground, and model sausages were formulated with 75% aged/frozen/thawed lamb loin, 25% water, 1.5% sodium chloride (NaCl and 0.3% sodium tripolyphosphate. The pH and thaw/purge loss of aged/frozen/thawed lamb loins were evaluated, and protein functionality (protein solubility and emulsifying capacity, water-holding capacity and textural properties of model sausages were determined. Cooked model sausages were vacuum-packaged in a plastic bag and displayed under continuous fluorescent natural white light (3°C±1°C. Colour and lipid oxidation of the cooked model sausages were evaluated on 0 and 21 d of display storage. Results Ageing prior to freezing had no impact on pH and purge/thaw loss of lamb loins and the colour of cooked sausages (p>0.05 made from the loins. Lamb loins aged for at least 3 wk prior to freezing numerically improved total and myofibrillar protein solubilities (p>0.05 and emulsion activity index (p = 0.009 of meat batter, but decreased cooking loss (p = 0.003 and lipid oxidation (p<0.05 of model sausages. Conclusion This study suggests that post-mortem ageing of raw meat prior to freezing could improve water-holding capacity and lipid oxidative stability of sausage made from the meat.

  2. Identification of Microorganisms by FilmArray and Matrix-Assisted Laser Desorption Ionization–Time of Flight Mass Spectrometry Prior to Positivity in the Blood Culture System

    OpenAIRE

    Almuhayawi, Mohammed; Altun, Osman; Strålin, Kristoffer; Özenci, Volkan

    2014-01-01

    In this study, we investigated the performance of the FilmArray and matrix-assisted laser desorption ionization–time of flight mass spectrometry (MALDI-TOF MS) in identifying microorganisms from blood culture (BC) bottles prior to positivity. First, we used simulated BacT/Alert FA Plus BC bottles with five each for Escherichia coli and Staphylococcus aureus isolates. The FilmArray identified all 10 isolates before BC positivity with 9/10 at 5 h and 1 at 7.5 h after incubation in the BC system...

  3. Catalytic Hydrothermal Conversion of Wet Biomass Feedstocks and Upgrading – Process Design and Optimization

    DEFF Research Database (Denmark)

    Hoffmann, Jessica; Toor, Saqib; Rosendahl, Lasse

    Liquid biofuels will play a major role for a more sustainable energy system of the future. The CatLiq® process is a 2nd generation biomass conversion process that is based on hydrothermal liquefaction. Hydrothermal liquefaction offers a very efficient and feedstock flexible way of converting...... biomass to bio-oil. Bio-oils from hydrothermal liquefaction are characterised by their high feedstock flexibility. Upgrading of complete bio-oils derived from hydrothermal conversion has not yet been extensively studied. Purpose of this work is to reduce the oxygen content of the bio-oil to improve...

  4. Geothermal hydrothermal direct heat use: US market size and market penetration estimates

    Energy Technology Data Exchange (ETDEWEB)

    El Sawy, A.H.; Entingh, D.J.

    1980-09-01

    This study estimates the future regional and national market penetration path of hydrothermal geothermal direct heat applications in the United States. A Technology Substitution Model (MARPEN) is developed and used to estimate the energy market shares captured by low-temperature (50 to 150/sup 0/C) hydrothermal geothermal energy systems over the period 1985 to 2020. The sensitivity of hydrothermal direct heat market shares to various government hydrothermal commercialization policies is examined. Several substantive recommendations to help accelerate commercialization of geothermal direct heat utilization in the United States are indicated and possible additional analyses are discussed.

  5. Microbial diversity in a submarine carbonate edifice from the serpentinizing hydrothermal system of the Prony Bay (New Caledonia over a 6-year period.

    Directory of Open Access Journals (Sweden)

    Anne ePostec

    2015-08-01

    Full Text Available Active carbonate chimneys from the shallow marine serpentinizing Prony Hydrothermal Field were sampled 3 times over a 6 years period at site ST09. Archaeal and bacterial communities composition was investigated using PCR-based methods (clone libraries, Denaturating Gel Gradient Electrophoresis, quantitative PCR targeting 16S rRNA genes, methyl coenzyme M reductase A and dissimilatory sulfite reductase subunit B genes. Methanosarcinales (Euryarchaeota and Thaumarchaea were the main archaeal members. The Methanosarcinales, also observed by epifluorescent microscopy and FISH, consisted of two phyotypes that were previously solely detected in two other serpentinitzing ecosystems (The Cedars and Lost City Hydrothermal Field. Surprisingly, members of the hyperthermophilic order Thermococcales were also found which may indicate the presence of a hot subsurface biosphere. The bacterial community mainly consisted of Firmicutes, Chloroflexi, Alpha-, Gamma-, Beta- and Delta-proteobacteria and of the candidate division NPL-UPA2. Members of these taxa were consistently found each year and may therefore represent a stable core of the indigenous bacterial community of the PHF chimneys. Firmicutes isolates representing new bacterial taxa were obtained by cultivation under anaerobic conditions. Our study revealed diverse microbial communities in PHF ST09 related to methane and sulfur compounds that share common populations with other terrestrial or submarine serpentinizing ecosystems.

  6. Microbial diversity in a submarine carbonate edifice from the serpentinizing hydrothermal system of the Prony Bay (New Caledonia) over a 6-year period.

    Science.gov (United States)

    Postec, Anne; Quéméneur, Marianne; Bes, Méline; Mei, Nan; Benaïssa, Fatma; Payri, Claude; Pelletier, Bernard; Monnin, Christophe; Guentas-Dombrowsky, Linda; Ollivier, Bernard; Gérard, Emmanuelle; Pisapia, Céline; Gérard, Martine; Ménez, Bénédicte; Erauso, Gaël

    2015-01-01

    Active carbonate chimneys from the shallow marine serpentinizing Prony Hydrothermal Field were sampled 3 times over a 6 years period at site ST09. Archaeal and bacterial communities composition was investigated using PCR-based methods (clone libraries, Denaturating Gel Gradient Electrophoresis, quantitative PCR) targeting 16S rRNA genes, methyl coenzyme M reductase A and dissimilatory sulfite reductase subunit B genes. Methanosarcinales (Euryarchaeota) and Thaumarchaea were the main archaeal members. The Methanosarcinales, also observed by epifluorescent microscopy and FISH, consisted of two phylotypes that were previously solely detected in two other serpentinitzing ecosystems (The Cedars and Lost City Hydrothermal Field). Surprisingly, members of the hyperthermophilic order Thermococcales were also found which may indicate the presence of a hot subsurface biosphere. The bacterial community mainly consisted of Firmicutes, Chloroflexi, Alpha-, Gamma-, Beta-, and Delta-proteobacteria and of the candidate division NPL-UPA2. Members of these taxa were consistently found each year and may therefore represent a stable core of the indigenous bacterial community of the PHF chimneys. Firmicutes isolates representing new bacterial taxa were obtained by cultivation under anaerobic conditions. Our study revealed diverse microbial communities in PHF ST09 related to methane and sulfur compounds that share common populations with other terrestrial or submarine serpentinizing ecosystems.

  7. Hydrothermal pretreatment of coal

    Energy Technology Data Exchange (ETDEWEB)

    Ross, D.S.

    1989-12-21

    We have examined changes in Argonne Premium samples of Wyodak coal following 30 min treatment in liquid water at autogenous pressures at 150{degrees}, 250{degrees}, and 350{degrees}C. In most runs the coal was initially dried at 60{degrees}C/1 torr/20 hr. The changes were monitored by pyrolysis field ionization mass spectrometry (py-FIMS) operating at 2.5{degrees}C/min from ambient to 500{degrees}C. We recorded the volatility patterns of the coal tars evolved over that temperature range, and in all cases the tar yields were 25%--30% of the starting coal on mass basis. There was essentially no change after the 150{degrees}C treatment. Small increases in volatility were seen following the 250{degrees}C treatment, but major effects were seen in the 350{degrees} work. The tar quantity remained unchanged; however, the volatility increased so the temperature of half volatility for the as-received coal of 400{degrees}C was reduced to 340{degrees}C. Control runs with no water showed some thermal effect, but the net effect from the presence of liquid water was clearly evident. The composition was unchanged after the 150{degrees} and 250{degrees}C treatments, but the 350{degrees} treatment brought about a 30% loss of oxygen. The change corresponded to loss of the elements of water, although loss of OH'' seemed to fit the analysis data somewhat better. The water loss takes place both in the presence and in the absence of added water, but it is noteworthy that the loss in the hydrothermal runs occurs at p(H{sub 2}O) = 160 atm. We conclude that the process must involve the dehydration solely of chemically bound elements of water, the dehydration of catechol is a specific, likely candidate.

  8. Orchestrating an Effective Formulation to Investigate the Impact of EMSs (Energy Management Systems for Residential Units Prior to Installation

    Directory of Open Access Journals (Sweden)

    Danish Mahmood

    2017-03-01

    Full Text Available Demand Response (DR programs under the umbrella of Demand Side Management (DSM tend to involve end users in optimizing their Power Consumption (PC patterns and offer financial incentives to shift the load at “low-priced” hours. However, users have their own preferences of anticipating the amount of consumed electricity. While installing an Energy Management System (EMS, the user must be assured that this investment gives optimum comfort of bill savings, as well as appliance utility considering Time of Use (ToU. Moreover, there is a difference between desired load distribution and optimally-scheduled load across a 24-h time frame for lowering electricity bills. This difference in load usage timings, if it is beyond the tolerance level of a user, increases frustration. The comfort level is a highly variable phenomenon. An EMS giving optimum comfort to one user may not be able to provide the same level of satisfaction to another who has different preferences regarding electricity bill savings or appliance utility. Under such a diversity of human behaviors, it is difficult to select an EMS for an individual user. In this work, a numeric performance metric,“User Comfort Level (UCL”isformulatedonthebasisofuserpreferencesoncostsaving,toleranceindelayregardinguse of an appliance and return of investment. The proposed framework (UCL allows the user to select an EMS optimally that suits his.her preferences well by anticipating electricity bill reduction, tolerable delay in ToU of the appliance and return on investment. Furthermore, an extended literature analysis is conducted demonstrating generic strategies of EMSs. Five major building blocks are discussed and a comparative analysis is presented on the basis of the proposed performance metric.

  9. The Prior Internet Resources 2017

    DEFF Research Database (Denmark)

    Engerer, Volkmar Paul; Albretsen, Jørgen

    2017-01-01

    The Prior Internet Resources (PIR) are presented. Prior’s unpublished scientific manuscripts and his wast letter correspondence with fellow researchers at the time, his Nachlass, is now subject to transcription by Prior-researchers worldwide, and form an integral part of PIR. It is demonstrated...... that the PIR, defined as the virtual space delimited by the three content areas and Internet domains: 1) Priorstudies, 2) Prior Virtual Lab, and 3) Nachlass), contains six information systems of five distinct types. The informations systems are grouped into a “Transcriber Loop” to illustrate how unpublished...... material from the archive boxes goes through a transcription process to end in the Nachlass. A box taxonomy defines the transcription project’s hub. Together with the “Transcriber Loop” this setup makes it possible to use the boxlists in conjunction with a Priorbibliography also in PIR as a showcase...

  10. Shallow vs. Deep Fluid Sources In Hydrothermal Systems: New Insights From VOC Composition In Fumarolic Discharges And Soil Gases Of Yellowstone National Park (USA)

    Science.gov (United States)

    Tassi, F.; Capecchiacci, F.; Montegrossi, G.; Caliro, S.; Chiodini, G.; Vaselli, O.

    2008-12-01

    The origin of non-methane volatile organic compounds (VOCs) in hydrothermal fluids is related to two distinct mechanisms regulated by different thermodynamic conditions (e.g. Des Marais et al., 1981; Mango, 2000; Capaccioni and Mangani, 2001): i) thermogenic reactions, such as catalytic reforming and/or thermal cracking, which proceed within the main reservoir at medium-to-high temperature (150-350°C) and reduced conditions; ii) biodegradation processes, occurring at relatively shallow depth, where uprising fluids have Food Chem., 56, 789- 795. Capaccioni, B., Mangani, F., 2001. Earth Planet. Sci. Lett., 188, 543-555. Des Marais, D.J., Donchin, J.H., Truesdell, A.H., Nehring, N.L., 1981. Nature, 292, 826-828. Mango, F.D., 2000. Geochim. Cosmochim. Acta, 64, 1265-1277.

  11. The boron isotope geochemistry of tourmaline-rich alteration in the IOCG systems of northern Chile: implications for a magmatic-hydrothermal origin

    Science.gov (United States)

    Tornos, Fernando; Wiedenbeck, Michael; Velasco, Francisco

    2012-06-01

    Hydrothermal tourmaline is common in the iron oxide-copper-gold (IOCG) deposits of the Coastal Cordillera of Chile where it occurs as large crystals in the groundmass of magmatic-hydrothermal breccias, such as in the Silvita or Tropezón ore bodies, or as small grains in replacive bodies or breccia cement in the ore-bearing andesite, as seen at the Candelaria or Carola deposits. Tourmaline shows strong chemical zoning and has a composition of schorl-dravite with significant povondraite and uvite components. The observed boron isotope composition is fairly variable, between -10.4‰ and +6.0‰ with no major differences among the different deposits, suggesting a common genetic mechanism. The δ11B values are significantly lower than those of seawater or marine evaporites and very similar to those of younger porphyry copper deposits and volcanic rocks in the region, indicating that the boron has a common, likely magmatic, origin. The predominant boron source was ultimately dewatering of the subducting slab with a significant contribution derived from the overlying continental basement. The range of δ11B values is between those of the porphyry copper deposits and the porphyry tin deposits of the Andes, suggesting that the IOCG mineralization might be genetically related to fluids having more crustal contamination than the porphyry copper deposits; such an interpretation is at odds with current models that propose that the Andean IOCG deposits are related to juvenile melts or to the circulation of basinal brines. Furthermore, the obtained δ11B data are markedly different from those of the tourmaline in the Carajás IOCG district (Brazil), suggesting that IOCGs do not form by a unique mechanism involving only one type of fluids.

  12. The Hydrothermal System at Home Plate in Gusev Crater, Mars: Formation of High Silica Material by Acid-Sulfate Alteration of Basalt

    Science.gov (United States)

    Morris, R. V.; Ming, D. W.; Gellert, R.; Yen, A.; Clark, B. C.; Gnaff, T. G.; Arvidson, R. E.; Squyres, S. W.

    2008-01-01

    The Alpha Particle X-ray Spectrometer (APXS) instrument on the Mars Exploration Rover (MER) Spirit measured three targets on or adjacent to Home Plate in Gusev Crater that have unusually high SiO2 concentrations (68% to 91%), unusually low FeO concentrations (1% to 7%, with total Fe as FeO), and unusually high TiO2/FeO ratios (0.2 to 1.2 by weight) [1]. Two targets (Kenosha Comets and Lefty Ganote) are located on high albedo soil (Gertrude Weise) that was exposed by the rover wheels, and one target is a float rock called Fuzzy Smith. Kenosha Comets has the highest SiO2 concentration, lowest FeO concentration, and highest TiO2/FeO ratio. Mineralogical evidence from the MER Miniature Thermal Emission Spectrometer (Mini-TES) suggests that the SiO2 is present as amorphous (noncrystalline) SiO2 at Gertrude Weise and nearby targets [2,3]. Mini-TES data were not acquired for Fuzzy Smith. Home Plate is considered to have an explosive volcanic origin, resulting when basaltic magma came into contact with ground water or ice [4]. Within 50 m to 1 km of Home Plate are sulfate rich soil deposits (Paso Robles class soils with 22-35% SO3) which are considered to be probable fumarolic and/or hydrothermal deposits associated with the volcanism [5]. We develop the model here, suggested by [5], that the high-silica materials are another manifestation of acid-sulfate processes associated with fumarolic and hydrothermal activity at Home Plate. This is done by analogy with basaltic materials altered by acid sulfate processes on the Island of Hawaii.

  13. Hydrothermal Liquefaction Treatment Preliminary Hazard Analysis Report

    Energy Technology Data Exchange (ETDEWEB)

    Lowry, Peter P.; Wagner, Katie A.

    2015-08-31

    A preliminary hazard assessment was completed during February 2015 to evaluate the conceptual design of the modular hydrothermal liquefaction treatment system. The hazard assessment was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. This analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public.

  14. Lead recovery from scrap cathode ray tube funnel glass by hydrothermal sulphidisation.

    Science.gov (United States)

    Yuan, Wenyi; Meng, Wen; Li, Jinhui; Zhang, Chenglong; Song, Qingbin; Bai, Jianfeng; Wang, Jingwei; Li, Yingshun

    2015-10-01

    This research focused on the application of the hydrothermal sulphidisation method to separate lead from scrap cathode ray tube funnel glass. Prior to hydrothermal treatment, the cathode ray tube funnel glass was pretreated by mechanical activation. Under hydrothermal conditions, hydroxyl ions (OH(-)) were generated through an ion exchange reaction between metal ions in mechanically activated funnel glass and water, to accelerate sulphur disproportionation; no additional alkaline compound was needed. Lead contained in funnel glass was converted to lead sulphide with high efficiency. Temperature had a significant effect on the sulphidisation rate of lead in funnel glass, which increased from 25% to 90% as the temperature increased from 100 °C to 300 °C. A sulphidisation rate of 100% was achieved at a duration of 8 h at 300 °C. This process of mechanical activation and hydrothermal sulphidisation is efficient and promising for the treatment of leaded glass. © The Author(s) 2015.

  15. Crystallization Experiments in the MgO-CO2-H2O system: Role of Amorphous Magnesium Carbonate Precursors in Magnesium Carbonate Hydrated Phases and Morphologies in Low Temperature Hydrothermal Fluids

    Science.gov (United States)

    Giampouras, Manolis; Garcia-Ruiz, Juan Manuel; Garrido, Carlos J.

    2017-04-01

    Numerous forms of hydrated or basic magnesium carbonates occur in the complex MgO-CO2-H2O system. Mineral saturation states from low temperature hydrothermal fluids in Semail Ophiolite (Oman), Prony Bay (New Caledonia) and Lost City hydrothermal field (mid-Atlantic ridge) strongly indicate the presence of magnesium hydroxy-carbonate hydrates (e.g. hydromagnesite) and magnesium hydroxides (brucite). Study of formation mechanisms and morphological features of minerals forming in the MgO-CO2-H2O system could give insights into serpentinization-driven, hydrothermal, alkaline environments, which are related to early Earth conditions. Temperature, hydration degree, pH and fluid composition are crucial factors regarding the formation, coexistence and transformation of such mineral phases. The rate of supersaturation, on the other hand, is a fundamental parameter to understand nucleation and crystal growth processes. All these parameters can be examined in a solution using different crystallization techniques. In the present study, we applied different crystallization techniques to synthesize and monitor the crystallization of Mg-bearing carbonates and hydroxides under abiotic conditions. Various crystallization techniques (counter-diffusion, vapor diffusion and unseeded solution mixing) were used to screen the formation conditions of each phase, transformation processes and structural development. Mineral and textural characterization of the different synthesized phases were carried out by X-ray diffraction (XRD), Raman spectroscopy and scanning electron microscopy coupled to dispersive energy spectroscopy (FE-SEM-EDS). Experimental investigation of the effect of pH level and silica content under variable reactant concentrations revealed the importance of Amorphous Magnesium Carbonate (AMC) in the formation of hydroxy-carbonate phases (hydromagnesite and dypingite). Micro-structural resemblance between AMC precursors and later stage crystalline phases highlights the

  16. Rapid, low-cost MR imaging protocol to document central nervous system and sinus abnormalities prior to pediatric hematopoietic stem cell transplantation

    Energy Technology Data Exchange (ETDEWEB)

    Leite, Eliane D.; Barbosa, Felipe G. de; Szarf, Gilberto; Lederman, Henrique M. [Universidade Federal de Sao Paulo, Department of Diagnostic Imaging, Sao Paulo (Brazil); Seber, Adriana; Ginani, Valeria C.; Carlesse, Fabianne C.; Gouvea, Roseane V.; Zecchin, Victor G.; Carvalho, Cinthya R. [Universidade Federal de Sao Paulo, Division of Pediatric Oncology, Department of Pediatrics, Sao Paulo (Brazil)

    2011-06-15

    Patients undergoing bone marrow transplant (BMT) are at risk for infectious complications, including those of the sinus. Central nervous system (CNS) abnormalities related to the chemotherapy or radiation that the patient received for the treatment of underlying malignancy or to transplant-related effects are also commonly seen. The only effective way to differentiate pre- and post-transplant causes is to have a baseline evaluation prior to the admission for transplant. The current method used to evaluate these patients is head CT. However, CT is not accurate to demonstrate CNS abnormalities and exposes the patient to radiation. MRI, despite better sensitivity for white matter abnormalities, has not been routinely used because of the higher cost and longer duration of the exam. Therefore, we designed a fast, low-cost and radiation-free MRI-based protocol to simultaneously evaluate sinus and brain abnormalities. (orig.)

  17. Hydrothermal precipitation of artificial violarite

    DEFF Research Database (Denmark)

    Jørgensen, W. H.; Toftlund, H.; Warner, T. E.

    2012-01-01

    The nonstoichiometric nickel-ore mineral, violarite, (Ni,Fe)3S4 was prepared as a phase-pure fine powder by a comparatively quick hydrothermal method from an aqueous solution of iron(II) acetate, nickel(II) acetate and DL-penicillamine in an autoclave at 130 °C for 45 h. Powder-XRD showed that th...

  18. Hydrothermal synthesis, characterization and luminescent ...

    Indian Academy of Sciences (India)

    methods, hydrothermal synthesis allows excellent control over particle size, shape, distribution and crystallinity of the material. Synthesis is conducted in a ... terns were recorded on Tecnai G2 S-twin transmission elec- tron microscope with field emission gun operating at 200 kV. Samples for TEM measurements were ...

  19. Constructing priors in synesthesia.

    Science.gov (United States)

    van Leeuwen, Tessa M

    2014-01-01

    A new theoretical framework (PPSMC) applicable to synesthesia has been proposed, in which the discrepancy between the perceptual reality of (some) synesthetic concurrents and their subjective non-veridicality is being explained. The PPSMC framework stresses the relevance of the phenomenology of synesthesia for synesthesia research-and beyond. When describing the emergence and persistence of synesthetic concurrents under PPSMC, it is proposed that precise, high-confidence priors are crucial in synesthesia. I discuss the construction of priors in synesthesia.

  20. Composite polymer nanoarchitectures from a one-pot hydrothermal route.

    Science.gov (United States)

    Yu, Shirong; Chang, Ying; Yuan, Conghui; Wang, Shuang; Mao, Jie; Chen, Guorong; Luo, Weiang; Xu, Yiting; Dai, Lizong

    2015-11-13

    Exploitation of facile and versatile synthetic approaches to polymeric nanoarchitectures is of great interest in polymer science and engineering. Herein, we show that a simple hydrothermal route using double-solvents as reaction media has the ability to generate polymer nanospheres with tunable morphologies and components. In this one-pot approach, condensation polymerization of a resol precursor and radical polymerization of styrene are allowed to occur simultaneously under hydrothermal treatment. The synergistic self-organization of phenol-formaldehyde crosslinked networks and polystyrene chains leads to the formation of well-defined hollow nanospheres with adjustable shell thickness or even Janus particles comprising a solid hemisphere and a hollow hemisphere. Furthermore, control over the composition of the hollow polymer nanospheres can be easily achieved by introducing a third monomer into the hydrothermal system.

  1. Hydrothermal contamination of public supply wells in Napa and Sonoma Valleys, California

    Science.gov (United States)

    Forrest, Matthew J.; Kulongoski, Justin T.; Edwards, Matthew S.; Farrar, Christopher D.; Belitz, Kenneth; Norris, Richard D.

    2013-01-01

    Groundwater chemistry and isotope data from 44 public supply wells in the Napa and Sonoma Valleys, California were determined to investigate mixing of relatively shallow groundwater with deeper hydrothermal fluids. Multivariate analyses including Cluster Analyses, Multidimensional Scaling (MDS), Principal Components Analyses (PCA), Analysis of Similarities (ANOSIM), and Similarity Percentage Analyses (SIMPER) were used to elucidate constituent distribution patterns, determine which constituents are significantly associated with these hydrothermal systems, and investigate hydrothermal contamination of local groundwater used for drinking water. Multivariate statistical analyses were essential to this study because traditional methods, such as mixing tests involving single species (e.g. Cl or SiO2) were incapable of quantifying component proportions due to mixing of multiple water types. Based on these analyses, water samples collected from the wells were broadly classified as fresh groundwater, saline waters, hydrothermal fluids, or mixed hydrothermal fluids/meteoric water wells. The Multivariate Mixing and Mass-balance (M3) model was applied in order to determine the proportion of hydrothermal fluids, saline water, and fresh groundwater in each sample. Major ions, isotopes, and physical parameters of the waters were used to characterize the hydrothermal fluids as Na–Cl type, with significant enrichment in the trace elements As, B, F and Li. Five of the wells from this study were classified as hydrothermal, 28 as fresh groundwater, two as saline water, and nine as mixed hydrothermal fluids/meteoric water wells. The M3 mixing-model results indicated that the nine mixed wells contained between 14% and 30% hydrothermal fluids. Further, the chemical analyses show that several of these mixed-water wells have concentrations of As, F and B that exceed drinking-water standards or notification levels due to contamination by hydrothermal fluids.

  2. Hydrothermal mixing: Fuel for life in the deep-sea

    Science.gov (United States)

    Hentscher, M.; Bach, W.; Amend, J.; McCollom, T.

    2009-04-01

    Deep-sea hydrothermal vent systems show a wide range of fluid compositions and temperatures. They reach from highly alkaline and reducing, like the Lost City hydrothermal field, to acidic and reducing conditions, (e. g., the Logatchev hydrothermal field) to acidic and oxidizing conditions (e. g., island arc hosted systems). These apparently hostile vent systems are generally accompanied by high microbial activity forming the base of a food-web that often includes higher organisms like mussels, snails, or shrimp. The primary production is boosted by mixing of chemically reduced hydrothermal vent fluids with ambient seawater, which generates redox disequilibria that serve as energy source for chemolithoautotrophic microbial life. We used geochemical reaction path models to compute the affinities of catabolic (energy-harvesting) and anabolic (biosynthesis) reactions along trajectories of batch mixing between vent fluids and 2 °C seawater. Geochemical data of endmember hydrothermal fluids from 12 different vent fields (Lost City, Rainbow, Logatchev, TAG, EPR 21 °N, Manus Basin, Mariana Arc, etc.) were included in this reconnaissance study of the variability in metabolic energetics in global submarine vent systems. The results show a distinction between ultramafic-hosted and basalt-hosted hydrothermal systems. The highest energy yield for chemolithotrophic catabolism in ultramafic-hosted hydrothermal systems is reached at low temperature and under slightly aerobic to aerobic conditions. The dominant reactions, for example at Rainbow or Lost City, are the oxidation of H2, Fe2+ and methane. At temperatures >60 °C, anaerobic metabolic reactions, e. g., sulphate reduction and methanogenesis, become more profitable. In contrast, basalt-hosted systems, such as TAG and 21 °N EPR uniformly indicate H2S oxidation to be the catabolically dominant reaction over the entire microbial-relevant temperature range. Affinities were calculated for the formation of individual cellular

  3. Borehole plugging by hydrothermal transport. A feasibility report

    Energy Technology Data Exchange (ETDEWEB)

    Roy, D.M.; White, W.B.

    1975-05-30

    The possibility of forming borehole plugs by hydrothermal transport was examined with respect to five systems, utilizing available literature data. In general, it would appear possible to create plugs with hydrothermal cements, with hydrothermally transported quartz, and with carbonates precipitated in-situ using carbon dioxide or carbon dioxide and water as reacting fluids. Hydrothermal cements appear to be most feasible from an engineering and economic point of view using a slurry with a lime-alumina-silica composition carried into the hole in a single pipe at temperatures in the range of 200/sup 0/C and requiring only enough pressure to drive the mixture into the hole. Quartz or chalcedony plugs would be the most impervious, have the lowest chemical reactivity with groundwater, the lowest thermal expansion, and be most compatible with the wall rock. Deposition is likely to be slow, and there are severe engineering problems associated with a single pipe system carrying silica-rich solutions at temperatures in excess of 500/sup 0/C at pressure of 2000 bars (30,000 psi). Calcite plugs could be formed as compatible plug materials in contact with a limestone or dolomite wall rock. It is not known whether non-porous plugs can be readily formed and there is also a problem of chemical reaction with percolating groundwater. The clay-water and sulfur-water systems do not appear to be viable plug systems. In-situ reconstitution of the wall rock does not appear to be an economically feasible possibility.

  4. Co-hydrolysis of hydrothermal and dilute acid pretreated populus slurries to support development of a high-throughput pretreatment system

    Directory of Open Access Journals (Sweden)

    DeMartini Jaclyn D

    2011-07-01

    Full Text Available Abstract Background The BioEnergy Science Center (BESC developed a high-throughput screening method to rapidly identify low-recalcitrance biomass variants. Because the customary separation and analysis of liquid and solids between pretreatment and enzymatic hydrolysis used in conventional analyses is slow, labor-intensive and very difficult to automate, a streamlined approach we term 'co-hydrolysis' was developed. In this method, the solids and liquid in the pretreated biomass slurry are not separated, but instead hydrolysis is performed by adding enzymes to the whole pretreated slurry. The effects of pretreatment method, severity and solids loading on co-hydrolysis performance were investigated. Results For hydrothermal pretreatment at solids concentrations of 0.5 to 2%, high enzyme protein loadings of about 100 mg/g of substrate (glucan plus xylan in the original poplar wood achieved glucose and xylose yields for co-hydrolysis that were comparable with those for washed solids. In addition, although poplar wood sugar yields from co-hydrolysis at 2% solids concentrations fell short of those from hydrolysis of washed solids after dilute sulfuric acid pretreatment even at high enzyme loadings, pretreatment at 0.5% solids concentrations resulted in similar yields for all but the lowest enzyme loading. Conclusions Overall, the influence of severity on susceptibility of pretreated substrates to enzymatic hydrolysis was clearly discernable, showing co-hydrolysis to be a viable approach for identifying plant-pretreatment-enzyme combinations with substantial advantages for sugar production.

  5. Application of Hydrothermal Treatment to High Concentrated Sewage Sludge for Anaerobic Digestion Process

    Directory of Open Access Journals (Sweden)

    M. Orikawa

    2013-10-01

    Full Text Available Tomato and seaweed were produced by utilizing CO2 and heat discharged from power generation using biogas in Toyogawa biomass park, Japan. The biogas was obtained by anaerobic digestion with hydrothermal treatment. The hydrothermal treatment was applied to the high concentrated sewage sludge (22 % total solids (TS dewatered sludge. The purpose of this study is to clarify the effect of hydrothermal treatment on the qualities of high concentrated sewage sludge, by analyzing particulate organic carbon (POC and dissolved organic carbon (DOC. The hydrothermal treatment was investigated under 10-60 min of treatment time, 180-200 °C of temperature, 10-22 %-TS of sewage sludge concentration. The results showed that the DOC in each conditions increased through hydrothermal treatment. The highest DOC obtained was 67 % of total carbon concentration, when the temperature was 180 °C, treatment time was 60 min and sewage sludge concentration was 10 %-TS. Furthermore, the viscosity of treated sewage sludge was decreased by hydrothermal treatment. In batch anaerobic digestion test, methane gas production was confirmed. In addition, this study evaluated the energy balance of this system. Thus, the results of this study indicated that the possibility of application of hydrothermal treatment to high concentrated sewage sludge for anaerobic digestion process. Keywords: anaerobic reaction, hydrothermal treatment, sewage sludge, solubilization

  6. Distribution of buried hydrothermal alteration deduced from high-resolution magnetic surveys in Yellowstone National Park

    Science.gov (United States)

    Bouligand, Claire; Glen, Jonathan M. G.; Blakely, Richard J.

    2014-04-01

    Yellowstone National Park (YNP) displays numerous and extensive hydrothermal features. Although hydrothermal alteration in YNP has been extensively studied, the volume, geometry, and type of rock alteration at depth remain poorly constrained. In this study, we use high-resolution airborne and ground magnetic surveys and measurements of remanent and induced magnetization of field and drill core samples to provide constraints on the geometry of hydrothermal alteration within the subsurface of three thermal areas in YNP (Firehole River, Smoke Jumper Hot Springs, and Norris Geyser Basin). We observe that hydrothermal zones from both liquid- and vapor-dominated systems coincide with magnetic lows observed in aeromagnetic surveys and with a decrease of the amplitude of short-wavelength anomalies seen in ground magnetic surveys. This suggests a strong demagnetization of both the shallow and deep substratum within these areas associated with the removal of magnetic minerals by hydrothermal alteration processes. Such demagnetization is confirmed by measurements of rock samples from hydrothermal areas which display significantly decreased total magnetization. A pronounced negative anomaly is observed over the Lone Star Geyser and suggests a significant demagnetization of the substratum associated with areas displaying large-scale fluid flow. The ground and airborne magnetic surveys are used to evaluate the distribution of magnetization in the subsurface. This study shows that significant demagnetization occurs over a thickness of at least a few hundred meters in hydrothermal areas at YNP and that the maximum degree or maximum thickness of demagnetization correlates closely with the location of hydrothermal activity and mapped alteration.

  7. Hydrothermal deposition on the Juan de Fuca Ridge over multiple glacial-interglacial cycles

    Science.gov (United States)

    Costa, Kassandra M.; McManus, Jerry F.; Middleton, Jennifer L.; Langmuir, Charles H.; Huybers, Peter J.; Winckler, Gisela; Mukhopadhyay, Sujoy

    2017-12-01

    Hydrothermal systems play an important role in modern marine chemistry, but little is known about how they may have varied on 100,000 year timescales. Here we present high-resolution records of non-lithogenic metal fluxes within sediment cores covering the last 500,000 years of hydrothermal deposition on the flanks of the Juan de Fuca Ridge. Six adjacent, gridded cores were analyzed by x-ray fluorescence for Fe, Mn, and Cu concentrations, corrected for lithogenic inputs with Ti, and normalized to excess initial 230Th to generate non-lithogenic metal flux records that provide the longest orbitally resolved reconstructions of hydrothermal activity currently available. Fe fluxes vary with global sea level over the last two glacial cycles, suggesting higher hydrothermal deposition during interglacial periods. The observed negative relationship between Fe and Mn indicates variable sediment redox conditions and diagenetic remobilization of sedimentary Mn over time. Thus, Mn fluxes may not be a reliable indicator for hydrothermal activity in the Juan de Fuca Ridge sediment cores. Cu fluxes show substantial high-frequency variability that may be linked to changes in vent temperature related to increased magmatic production during glacial periods. Deglacial hydrothermal peaks on the Juan de Fuca Ridge are consistent with previously published records from the Mid-Atlantic Ridge and the East Pacific Rise. Moreover, on the Juan de Fuca Ridge, the deglacial peaks in hydrothermal activity are followed by relatively high hydrothermal fluxes throughout the ensuing interglacial periods relative to the previous glacial period.

  8. Marine shallow-water hydrothermal activity and mineralization at the Wakamiko crater in Kagoshima bay, south Kyushu, Japan

    Science.gov (United States)

    Ishibashi, Jun-ichiro; Nakaseama, Miwako; Seguchi, Mariko; Yamashita, Toru; Doi, Shinsuke; Sakamoto, Takeaki; Shimada, Kazuhiko; Shimada, Nobutaka; Noguchi, Takuroh; Oomori, Tamotsu; Kusakabe, Minoru; Yamanaka, Toshiro

    2008-06-01

    Submarine hydrothermal fluid emanation from a small sediment mound associated with bubbling gas was observed in the Wakamiko crater that is located 5 km offshore at 200 m depth in Kagoshima bay, southern Kyushu, Japan. In 2003 and 2005, surface sediments (up to 30 cm) from inside and outside of the hydrothermal mound were sampled using the submersible ROV Hyper-Dolphine (JAMSTEC). Chemistry of pore fluids inside the mound showed a clear difference from those collected from outside the mound, which is explained by mixing of the ascending hydrothermal component and seawater. Estimated chemical composition of the hydrothermal end member suggests that the fluid experienced hydrothermal interaction at a temperature range of about 175 to 200 °C. This is consistent with the observed mound temperature of 137 °C. Hydrothermal minerals such as barite, stibnite, and realgar were identified in the mound sediment, suggesting their precipitation due to mixing of the ascending hydrothermal fluid with seawater. Isotopic composition of the hydrothermal endmember can be explained by mixing product of seawater, magmatic water and meteoric water. The marine shallow-water hydrothermal system in the Wakamiko crater is considered to be driven by a magmatic heat source beneath the crater, which also contributes elements such as arsenic, antimony, mercury and magmatic water to the hydrothermal fluid.

  9. Reactive Hydrothermal Flow Model for Mid-Oceanic Ridges

    Science.gov (United States)

    Starger, J. L.; Garven, G.; Tivey, M. K.

    2016-12-01

    A two-dimensional finite-element code known as RST2D [1] is being used to study the geothermal energy, geohydrology, and geochemistry of fluid convection in seafloor hydrothermal systems such as the Juan de Fuca Ridge, East Pacific Rise, and TAG hydrothermal fields. Relative to black smoker vents and other discharge features, submarine recharge zones are understudied. We are attempting to model both the recharge and discharge limbs of these flow fields as a coupled system by mathematically and physically linking the fluid dynamics, heat flow, and geochemical reactions. Numerical simulations have been made to quantify likely flow rates and relevant geochemical water-rock reactions including mineral precipitation and dissolution using a fully-coupled reactive flow modeling approach. In particular, the reactive flow model is being used to predict the formation, likely spatial-temporal distribution, and preservation of anhydrite in the hydrothermal recharge zone and its feedback influence on permeability, fluid flow, and heat transport in the discharge zone. We are focusing on the geochemical effects and controls of on- and off-ridge geology and geometry, permeability-porosity, vent width and geometry, and thermal boundary conditions on the predicted size and extent of the recharge and discharge zones, and whether hydrothermal recharge is focused along extensional faults or diffused across broad areas of the seafloor. Hydrothermal flow systems of this type are known to represent modern analogs for ancient systems such as those being studied for understanding the origin of life on the planet, but also as modern analogs for the formation of volcanogenic massive sulfide ore deposits. Reactive flow modeling provides a useful tool for developing a better understanding of the physiobiochemistry of these episodic flow systems, and could potentially guide exploration for modern and ancient ore deposits. [1] Raffensperger, J.P.,1996, Advances in Porous Media 3, 185 - 305.

  10. Learning about hydrothermal volcanic activity by modeling induced geophysical changes

    Science.gov (United States)

    Currenti, Gilda M.; Napoli, Rosalba

    2017-05-01

    Motivated by ongoing efforts to understand the nature and the energy potential of geothermal resources, we devise a coupled numerical model (hydrological, thermal, mechanical), which may help in the characterization and monitoring of hydrothermal systems through computational experiments. Hydrothermal areas in volcanic regions arise from a unique combination of geological and hydrological features which regulate the movement of fluids in the vicinity of magmatic sources capable of generating large quantities of steam and hot water. Numerical simulations help in understanding and characterizing rock-fluid interaction processes and the geophysical observations associated with them. Our aim is the quantification of the response of different geophysical observables (i.e. deformation, gravity and magnetic field) to hydrothermal activity on the basis of a sound geological framework (e.g. distribution and pathways of the flows, the presence of fractured zones, caprock). A detailed comprehension and quantification of the evolution and dynamics of the geothermal systems and the definition of their internal state through a geophysical modeling approach are essential to identify the key parameters for which the geothermal system may fulfill the requirements to be exploited as a source of energy. For the sake of illustration only, the numerical computations are focused on a conceptual model of the hydrothermal system of Vulcano Island by simulating a generic 1-year unrest and estimating different geophysical changes. We solved (i) the mass and energy balance equations of flow in porous media for temperature, pressure and density changes, (ii) the elastostatic equation for the deformation field and (iii) the Poisson’s equations for gravity and magnetic potential fields. Under the model assumptions, a generic unrest of 1-year engenders on the ground surface low amplitude changes in the investigated geophysical observables, that are, however, above the accuracies of the modern

  11. Zinc stannate nanostructures: hydrothermal synthesis

    Directory of Open Access Journals (Sweden)

    Sunandan Baruah and Joydeep Dutta

    2011-01-01

    Full Text Available Nanostructured binary semiconducting metal oxides have received much attention in the last decade owing to their unique properties rendering them suitable for a wide range of applications. In the quest to further improve the physical and chemical properties, an interest in ternary complex oxides has become noticeable in recent times. Zinc stannate or zinc tin oxide (ZTO is a class of ternary oxides that are known for their stable properties under extreme conditions, higher electron mobility compared to its binary counterparts and other interesting optical properties. The material is thus ideal for applications from solar cells and sensors to photocatalysts. Among the different methods of synthesizing ZTO nanostructures, the hydrothermal method is an attractive green process that is carried out at low temperatures. In this review, we summarize the conditions leading to the growth of different ZTO nanostructures using the hydrothermal method and delve into a few of its applications reported in the literature.

  12. Hydrothermal stability of zirconia ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Lee, D.Y. [Daelim College of Technology, Anyang (Korea); Gogotsi, G.A. [National Academy of Sciences of Ukraine, Kiev (Uzbekistan); Kim, D.J. [Korea Institute of Science and Technology, Seoul (Korea); Park, N.J. [Kumho National University of Technology, Kumi (Korea)

    2002-02-01

    3 mol% Y{sub 2}O{sub 3} partially-Stabilized Zirconia single Crystals (PSZCs) containing a small quantity (<0.5%) of rare-earth oxides (CeO{sub 2}, Tb{sub 2}O{sub 3}) were prepared by using a direct high-frequency skull melting technique to evaluate hydrothermal stability in an autoclave. Pole figure measurements indicate that both CeO{sub 2} and Tb{sub 2}O{sub 3} containing specimens prepared by the skull melting are single crystals. PSZCs exhibited no t{yields}m phase transformation during aging for 5 h at temperatures from 150 to 250 deg. C and 4 MPa water vapor pressure in an autoclave, resulting in excellent hydrothermal stability. (author). 19 refs., 1 tab., 4 figs.

  13. Revisiting current “barefoot doctors” in border areas of China: system of services, financial issue and clinical practice prior to introducing integrated management of childhood illness (IMCI

    Directory of Open Access Journals (Sweden)

    Li Xiuyun

    2012-08-01

    Full Text Available Abstract Background Under-5-years child mortality remains high in rural China. Integrated management of childhood illness (IMCI was introduced to China in 1998, but only a few rural areas have been included. This study aimed at assessing the current situation of the health system of rural health care and evaluating the clinical competency of village doctors in management of childhood illnesses prior to implementing IMCI programme in remote border rural areas. Methods The study was carried out in the border areas of Puer prefecture of Yunnan province. There were 182 village doctors in the list of the health bureau in these border areas. Of these, 154 (84.6% were recruited into the study. The local health system components were investigated using a qualitative approach and analyzed with triangulation of information from different sources. The clinical component was assessed objectively and quantitatively presented using descriptive statistics. Results The study found that the New Rural Cooperative Medical Scheme (NRCMS coordinated the health insurance system and the provider service through 3 tiers: village doctor, township and county hospitals. The 30 RMB per person per year premium did not cover the referral cost, and thereby decreased the number of referrals. In contrast to available treatment facilities and drug supply, the level of basic medical education of village doctors and township doctors was low. Discontent among village doctors was common, especially concerning low rates of return from the service, exceptions being procedures such as injections, which in fact may create moral hazards to the patients. Direct observation on the assessment and management of paediatric patients by village doctors revealed inadequate history taking and physical examination, inability to detect potentially serious complications, overprescription of injection and antibiotics, and underprescription of oral rehydration salts and poor quality of counseling

  14. Deep-Sea Hydrothermal-Vent Sampler

    Science.gov (United States)

    Behar, Alberto E.; Venkateswaran, Kasthur; Matthews, Jaret B.

    2008-01-01

    An apparatus is being developed for sampling water for signs of microbial life in an ocean hydrothermal vent at a depth of as much as 6.5 km. Heretofore, evidence of microbial life in deep-sea hydrothermal vents has been elusive and difficult to validate. Because of the extreme conditions in these environments (high pressures and temperatures often in excess of 300 C), deep-sea hydrothermal- vent samplers must be robust. Because of the presumed low density of biomass of these environments, samplers must be capable of collecting water samples of significant volume. It is also essential to prevent contamination of samples by microbes entrained from surrounding waters. Prior to the development of the present apparatus, no sampling device was capable of satisfying these requirements. The apparatus (see figure) includes an intake equipped with a temperature probe, plus several other temperature probes located away from the intake. The readings from the temperature probes are utilized in conjunction with readings from flowmeters to determine the position of the intake relative to the hydrothermal plume and, thereby, to position the intake to sample directly from the plume. Because it is necessary to collect large samples of water in order to obtain sufficient microbial biomass but it is not practical to retain all the water from the samples, four filter arrays are used to concentrate the microbial biomass (which is assumed to consist of particles larger than 0.2 m) into smaller volumes. The apparatus can collect multiple samples per dive and is designed to process a total volume of 10 L of vent fluid, of which most passes through the filters, leaving a total possibly-microbe-containing sample volume of 200 mL remaining in filters. A rigid titanium nose at the intake is used for cooling the sample water before it enters a flexible inlet hose connected to a pump. As the water passes through the titanium nose, it must be cooled to a temperature that is above a mineral

  15. Effects of attrition, prior acid-etching, and cyclic loading on the bond strength of a self-etching adhesive system to dentin.

    Science.gov (United States)

    Shinkai, Koichi; Ebihara, Takashi; Shirono, Manabu; Seki, Hideaki; Wakaki, Suguru; Suzuki, Masaya; Suzuki, Shiro; Katoh, Yoshiroh

    2009-03-01

    The purpose of this study was to evaluate the effects of dentin attrition, phosphoric acid etching, and cyclic loading on the microtensile bond strength (microTBS) of a self-etching adhesive system to dentin. Flat dentin surfaces of human molars were assigned to eight experimental groups based on those with or without attrition, prior acid-etching, and cyclic loading. Resin composite paste was placed and polymerized after the bonding procedure according to manufacturer's instructions. The specimens were subjected to microTBS testing at a crosshead speed of 0.5 mm/min. Results showed that the minimum mean value of microTBS was 14.9 MPa in the group without attrition and acid-etching but with loading, while the maximum mean value of microTBS was 40.0 MPa in the group without attrition and loading but with acid etching. Therefore, the value of microTBS to dentin without attrition was significantly decreased by cyclic loading but that to dentin with attrition was not affected.

  16. Activity and abundance of denitrifying bacteria in the subsurface biosphere of diffuse hydrothermal vents of the Juan de Fuca Ridge

    Directory of Open Access Journals (Sweden)

    A. Bourbonnais

    2012-11-01

    Full Text Available Little is known about fixed nitrogen (N transformation and elimination at diffuse hydrothermal vents where anoxic fluids are mixed with oxygenated crustal seawater prior to discharge. Oceanic N sinks that remove bio-available N ultimately affect chemosynthetic primary productivity in these ecosystems. Using 15N paired isotope techniques, we determined potential rates of fixed N loss pathways (denitrification, anammox and dissimilatory nitrate reduction to ammonium (DNRA in sulfidic hydrothermal vent fluids discharging from the subsurface at several sites at Axial Volcano and the Endeavour Segment on the Juan de Fuca Ridge. We also measured physico-chemical parameters (i.e., temperature, pH, nutrients, H2S and N2O concentrations as well as the biodiversity and abundance of chemolithoautotrophic nitrate-reducing, sulfur-oxidizing γ-proteobacteria (SUP05 cluster using sequence analysis of amplified small subunit ribosomal RNA (16S rRNA genes in combination with taxon-specific quantitative polymerase chain reaction (qPCR assays. Denitrification was the dominant N loss pathway in the subsurface biosphere of the Juan de Fuca Ridge, with rates of up to ~1000 nmol N l−1 day−1. In comparison, anammox rates were always < 5 nmol N l−1 day−1 and below the detection limit at most of the sites. DNRA rates were up to ~150 nmol N l−1 day−1. These results suggest that bacterial denitrification out-competes anammox in sulfidic hydrothermal vent waters. Taxon-specific qPCR revealed that γ-proteobacteria of the SUP05 cluster sometimes dominated the microbial community (SUP05/total bacteria up to 38%. Significant correlations were found between fixed N loss (i.e., denitrification, anammox rates and in situ nitrate and dissolved inorganic nitrogen (DIN deficits in the fluids, indicating that DIN availability may ultimately regulate N loss in the subsurface

  17. Energetics of Amino Acid Synthesis in Alkaline Hydrothermal Environments.

    Science.gov (United States)

    Kitadai, Norio

    2015-12-01

    Alkaline hydrothermal systems have received considerable attention as candidates for the origin and evolution of life on the primitive Earth. Nevertheless, sufficient information has not yet been obtained for the thermodynamic properties of amino acids, which are necessary components for life, at high temperatures and alkaline pH. These properties were estimated using experimental high-temperature volume and heat capacity data reported in the literature for several amino acids, together with correlation algorithms and the revised Helgeson-Kirkham-Flowers (HKF) equations of state. This approach enabled determination of a complete set of the standard molal thermodynamic data and the revised HKF parameters for the 20 protein amino acids in their zwitterionic and ionization states. The obtained dataset was then used to evaluate the energetics of amino acid syntheses from simple inorganic precursors (CO2, H2, NH3 and H2S) in a simulated alkaline hydrothermal system on the Hadean Earth. Results show that mixing between CO2-rich seawater and the H2-rich hydrothermal fluid can produce energetically favorable conditions for amino acid syntheses, particularly in the lower-temperature region of such systems. Together with data related to the pH and temperature dependences of the energetics of amino acid polymerizations presented in earlier reports, these results suggest the following. Hadean alkaline hydrothermal settings, where steep pH and temperature gradients may have existed between cool, slightly acidic Hadean ocean water and hot, alkaline hydrothermal fluids at the vent-ocean interface, may be energetically the most suitable environment for the synthesis and polymerization of amino acids.

  18. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

    2014-01-01

    Biomass is one of the most abundant sources of renewable energy, and will be an important part of a more sustainable future energy system. In addition to direct combustion, there is growing attention on conversion of biomass into liquid en-ergy carriers. These conversion methods are divided......-ponents such as carbohydrates; lignin, protein and fat, and each of them produce distinct groups of compounds when processed individually. When processed to-gether in different ratios, they will most likely cross-influence each other and thus the composition of the product. Processing conditions including temperature, pres......-sure, residence time, catalyst, and type of solvent are important for the bio-oil yield and product quality....

  19. Antarctic marine biodiversity and deep-sea hydrothermal vents.

    Science.gov (United States)

    Chown, Steven L

    2012-01-01

    The diversity of many marine benthic groups is unlike that of most other taxa. Rather than declining from the tropics to the poles, much of the benthos shows high diversity in the Southern Ocean. Moreover, many species are unique to the Antarctic region. Recent work has shown that this is also true of the communities of Antarctic deep-sea hydrothermal vents. Vent ecosystems have been documented from many sites across the globe, associated with the thermally and chemically variable habitats found around these, typically high temperature, streams that are rich in reduced compounds and polymetallic sulphides. The animal communities of the East Scotia Ridge vent ecosystems are very different to those elsewhere, though the microbiota, which form the basis of vent food webs, show less differentiation. Much of the biological significance of deep-sea hydrothermal vents lies in their biodiversity, the diverse biochemistry of their bacteria, the remarkable symbioses among many of the marine animals and these bacteria, and the prospects that investigations of these systems hold for understanding the conditions that may have led to the first appearance of life. The discovery of diverse and unusual Antarctic hydrothermal vent ecosystems provides opportunities for new understanding in these fields. Moreover, the Antarctic vents south of 60°S benefit from automatic conservation under the Convention on the Conservation of Antarctic Marine Living Resources and the Antarctic Treaty. Other deep-sea hydrothermal vents located in international waters are not protected and may be threatened by growing interests in deep-sea mining.

  20. The Hydrothermal Chemistry of Gold, Arsenic, Antimony, Mercury and Silver

    Energy Technology Data Exchange (ETDEWEB)

    Bessinger, Brad; Apps, John A.

    2003-03-23

    A comprehensive thermodynamic database based on the Helgeson-Kirkham-Flowers (HKF) equation of state was developed for metal complexes in hydrothermal systems. Because this equation of state has been shown to accurately predict standard partial molal thermodynamic properties of aqueous species at elevated temperatures and pressures, this study provides the necessary foundation for future exploration into transport and depositional processes in polymetallic ore deposits. The HKF equation of state parameters for gold, arsenic, antimony, mercury, and silver sulfide and hydroxide complexes were derived from experimental equilibrium constants using nonlinear regression calculations. In order to ensure that the resulting parameters were internally consistent, those experiments utilizing incompatible thermodynamic data were re-speciated prior to regression. Because new experimental studies were used to revise the HKF parameters for H2S0 and HS-1, those metal complexes for which HKF parameters had been previously derived were also updated. It was found that predicted thermodynamic properties of metal complexes are consistent with linear correlations between standard partial molal thermodynamic properties. This result allowed assessment of several complexes for which experimental data necessary to perform regression calculations was limited. Oxygen fugacity-temperature diagrams were calculated to illustrate how thermodynamic data improves our understanding of depositional processes. Predicted thermodynamic properties were used to investigate metal transport in Carlin-type gold deposits. Assuming a linear relationship between temperature and pressure, metals are predicted to predominantly be transported as sulfide complexes at a total aqueous sulfur concentration of 0.05 m. Also, the presence of arsenic and antimony mineral phases in the deposits are shown to restrict mineralization within a limited range of chemical conditions. Finally, at a lesser aqueous sulfur

  1. The radiogenic and stable Sr isotope geochemistry of basalt weathering in Iceland: Role of hydrothermal calcite and implications for long-term climate regulation

    Science.gov (United States)

    Andrews, M. Grace; Jacobson, Andrew D.

    2017-10-01

    volcanic C flux introduced to the atmosphere-ocean system as HCO3- after subsurface silicate weathering does not regulate long-term climate. Because hydrothermal calcite simply sequesters some of this HCO3- and delays its transmission to the atmosphere-ocean system until it dissolves at the surface later in time, it can be concluded the weathering of hydrothermal calcite bearing non-atmospheric C also has no effect on long-term climate regulation. Icelandic riverine HCO3- fluxes should be corrected for the hydrothermal calcite weathering contribution prior to quantifying atmospheric CO2 consumption rates by basalt weathering at the Earth's surface.

  2. Primary granulomatous angiitis of the central nervous system: findings of magnetic resonance spectroscopy and fractional anisotropy in diffusion tensor imaging prior to surgery. Case report.

    Science.gov (United States)

    Beppu, Takaaki; Inoue, Takashi; Nishimoto, Hideaki; Nakamura, Shinichi; Nakazato, Yoichi; Ogasawara, Kuniaki; Ogawa, Akira

    2007-10-01

    Primary granulomatous angiitis of the central nervous system (CNS) is extremely rare. Its preoperative diagnosis is difficult as the condition displays nonspecific features on routine neuroimaging investigations. In this paper, the authors report findings of magnetic resonance (MR) spectroscopy and fractional anisotropy (FA) with diffusion tensor MR imaging in a case of granulomatous angiitis of the CNS. A 30-year-old man presented with morning headaches and grand mal seizures. An MR image revealed a mass resembling glioblastoma in the right temporal lobe. Magnetic resonance spectroscopy showed a high choline/creatine (Cho/Cr) ratio indicative of a malignant neoplasm, accompanied by a slight elevation of glutamate and glutamine. The FA value was very low, which is inconsistent with malignant glioma. The mass was totally removed surgically. Histologically, the peripheral lesion of the mass consisted of a rough accumulation of fat granule cells, infiltration of inflammatory cells, and distribution of capillary vessels. Some vessels within the lesion were replaced by granulomas. The histological diagnosis was granulomatous angiitis of the CNS. The MIB-1-positive rate of the granuloma was approximately 5%. Both MR spectroscopy and FA were unable to accurately diagnose granulomatous angiitis of the CNS prior to surgery; however, elevated Cho/Cr and glutamate and glutamine shown by MR spectroscopy may indicate the moderate proliferation potential of the granuloma and the inflammatory process, respectively, in this condition. Although the low FA value in the present case enabled the authors to rule out a diagnosis of glioblastoma, FA values in inflammatory lesions require careful interpretation.

  3. Submarine hydrothermal environments as sites for the origin and evolution of life

    Science.gov (United States)

    Hoffman, S.; Baross, J.

    1985-01-01

    That life formed and evolved in hydrothermal environments is proposed. This hypothesis is plausible in terms of the tectonic, paleontological, and degassing history of the Earth. Submarine hydrothermal vents are the only contemporary geological environment which may truly be called primeval and which today continue to be a major source of gases and dissolved elements to the ocean. The microbial assemblages in present day hydrothermal systems therefore could be living analogues of the earliest microbial communities to develop on Earth. The evidence for the hypothesis is reviewed.

  4. Quantification of porosity evolution from unaltered to propylitic-altered granites: the 14C-PMMA method applied on the hydrothermal system of Lavras do Sul, Brazil

    Directory of Open Access Journals (Sweden)

    Everton M. Bongiolo

    2007-09-01

    Full Text Available This work is an application of the 14C-Polymethylmethacrylate method to compare the porosity evolution between unaltered and propylitic-altered granites, using samples from Lavras do Sul region, Brazil. This method, when coupled with optical and electronic petrography has the advantage over other methods to provide the quantification and identification of total and local porosity of rocks. From petrographic observations, different kinds of porous zones were identified and quantified (microfractures, grain boundaries, alteration of minerals, etc. Results show that unaltered granites have 0.5 to 0.6% porosity and propylitic-altered ones have 1.7 to 1.8% porosity, even between samples with different textures. Porosity of altered rocks increases mainly due to higher porosity of neoformed chlorite, calcite, sericite and microfractures. Field observations show that later phyllic alteration halos are wider in equigranular than in porphyritic granites, which could not be explained by different original porosity between those rocks. The observed differences of phyllic halos diffusion were controlled by structural and fluid/rock ratio variations between the equigranular and porphyritic granitic facies during the later hydrothermal stage.Este trabalho é uma aplicação do método 14C-polimetilmetacrilato na comparação da evolução da porosidade entre granitos não alterados e propilitizados, utilizando amostras da região de Lavras do Sul, Brasil. Este método, quando associado a análises por petrografia ótica, eletrônica e processamento digital de imagens tem a vantagem de fornecer, além da porosidade total, a quantificação e identificação da porosidade em locais específicos das rochas. A partir da petrografia foi possível identificar e quantificar os diferentes tipos de poros presentes nas rochas (microfraturas, limites de grãos, alteração de minerais, etc. Os resultados mostram que granitos não alterados têm porosidade de 0,5 a 0,6% e

  5. Strata-bound Fe-Co-Cu-Au-Bi-Y-REE deposits of the Idaho Cobalt Belt: Multistage hydrothermal mineralization in a magmatic-related iron oxide copper-gold system

    Science.gov (United States)

    Slack, John F.

    2012-01-01

    Mineralogical and geochemical studies of strata-bound Fe-Co-Cu-Au-Bi-Y-rare-earth element (REE) deposits of the Idaho cobalt belt in east-central Idaho provide evidence of multistage epigenetic mineralization by magmatic-hydrothermal processes in an iron oxide copper-gold (IOCG) system. Deposits of the Idaho cobalt belt comprise three types: (1) strata-bound sulfide lenses in the Blackbird district, which are cobaltite and, less commonly, chalcopyrite rich with locally abundant gold, native bismuth, bismuthinite, xenotime, allanite, monazite, and the Be-rich silicate gadolinite-(Y), with sparse uraninite, stannite, and Bi tellurides, in a gangue of quartz, chlorite, biotite, muscovite, garnet, tourmaline, chloritoid, and/or siderite, with locally abundant fluorapatite or magnetite; (2) discordant tourmalinized breccias in the Blackbird district that in places have concentrations of cobaltite, chalcopyrite, gold, and xenotime; and (3) strata-bound magnetite-rich lenses in the Iron Creek area, which contain cobaltiferous pyrite and locally sparse chalcopyrite or xenotime. Most sulfide-rich deposits in the Blackbird district are enclosed by strata-bound lenses composed mainly of Cl-rich Fe biotite; some deposits have quartz-rich envelopes.Whole-rock analyses of 48 Co- and/or Cu-rich samples show high concentrations of Au (up to 26.8 ppm), Bi (up to 9.16 wt %), Y (up to 0.83 wt %), ∑REEs (up to 2.56 wt %), Ni (up to 6,780 ppm), and Be (up to 1,180 ppm), with locally elevated U (up to 124 ppm) and Sn (up to 133 ppm); Zn and Pb contents are uniformly low (≤821 and ≤61 ppm, respectively). Varimax factor analysis of bulk compositions of these samples reveals geochemically distinct element groupings that reflect statistical associations of monazite, allanite, and xenotime; biotite and gold; detrital minerals; chalcopyrite and sparse stannite; quartz; and cobaltite with sparse selenides and tellurides. Significantly, Cu is statistically separate from Co and As

  6. Hydrothermal Gasification for Waste to Energy

    Science.gov (United States)

    Epps, Brenden; Laser, Mark; Choo, Yeunun

    2014-11-01

    Hydrothermal gasification is a promising technology for harvesting energy from waste streams. Applications range from straightforward waste-to-energy conversion (e.g. municipal waste processing, industrial waste processing), to water purification (e.g. oil spill cleanup, wastewater treatment), to biofuel energy systems (e.g. using algae as feedstock). Products of the gasification process are electricity, bottled syngas (H2 + CO), sequestered CO2, clean water, and inorganic solids; further chemical reactions can be used to create biofuels such as ethanol and biodiesel. We present a comparison of gasification system architectures, focusing on efficiency and economic performance metrics. Various system architectures are modeled computationally, using a model developed by the coauthors. The physical model tracks the mass of each chemical species, as well as energy conversions and transfers throughout the gasification process. The generic system model includes the feedstock, gasification reactor, heat recovery system, pressure reducing mechanical expanders, and electricity generation system. Sensitivity analysis of system performance to various process parameters is presented. A discussion of the key technological barriers and necessary innovations is also presented.

  7. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, M.; Davis, R.; Jones, S.

    2013-03-01

    This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

  8. From Geochemistry to Biochemistry: Simulating Prebiotic Chemistry Driven by Geochemical Gradients in Alkaline Hydrothermal Vents

    Science.gov (United States)

    Barge, Laurie

    2016-07-01

    Planetary water-rock interfaces generate energy in the form of redox, pH, and thermal gradients, and these disequilibria are particularly focused in hydrothermal vent systems where the reducing, heated hydrothermal fluid feeds back into the more oxidizing ocean. Alkaline hydrothermal vents have been proposed as a likely location for the origin of life on the early Earth due to various factors: including the hydrothermal pH / Eh gradients that resemble the ubiquitous electrical / proton gradients in biology, the catalytic hydrothermal precipitates that resemble inorganic catalysts in enzymes, and the presence of electron donors and acceptors in hydrothermal systems (e.g. H2 + CH4 and CO2) that are thought to have been utilized in the earliest metabolisms. Of particular importance for the emergence of metabolism are the mineral "chimneys" that precipitate at the vent fluid / seawater interface. Hydrothermal chimneys are flow-through chemical reactors that form porous and permeable inorganic membranes transecting geochemical gradients; in some ways similar to biological membranes that transect proton / ion gradients and harness these disequilibria to drive metabolism. These emergent chimney structures in the far-from-equilibrium system of the alkaline vent have many properties of interest to the origin of life that can be simulated in the laboratory: for example, they can generate electrical energy and drive redox reactions, and produce catalytic minerals (in particular the metal sulfides and iron oxyhydroxides - "green rust") that can facilitate chemical reactions towards proto-metabolic cycles and biosynthesis. Many of the factors prompting interest in alkaline hydrothermal vents on Earth may also have been present on early Mars, or even presently within icy worlds such as Europa or Enceladus - thus, understanding the disequilibria and resulting prebiotic chemistry in these systems can be of great use in assessing the potential for other environments in the Solar

  9. Ongoing hydrothermal activities within Enceladus.

    Science.gov (United States)

    Hsu, Hsiang-Wen; Postberg, Frank; Sekine, Yasuhito; Shibuya, Takazo; Kempf, Sascha; Horányi, Mihály; Juhász, Antal; Altobelli, Nicolas; Suzuki, Katsuhiko; Masaki, Yuka; Kuwatani, Tatsu; Tachibana, Shogo; Sirono, Sin-iti; Moragas-Klostermeyer, Georg; Srama, Ralf

    2015-03-12

    Detection of sodium-salt-rich ice grains emitted from the plume of the Saturnian moon Enceladus suggests that the grains formed as frozen droplets from a liquid water reservoir that is, or has been, in contact with rock. Gravitational field measurements suggest a regional south polar subsurface ocean of about 10 kilometres thickness located beneath an ice crust 30 to 40 kilometres thick. These findings imply rock-water interactions in regions surrounding the core of Enceladus. The resulting chemical 'footprints' are expected to be preserved in the liquid and subsequently transported upwards to the near-surface plume sources, where they eventually would be ejected and could be measured by a spacecraft. Here we report an analysis of silicon-rich, nanometre-sized dust particles (so-called stream particles) that stand out from the water-ice-dominated objects characteristic of Saturn. We interpret these grains as nanometre-sized SiO2 (silica) particles, initially embedded in icy grains emitted from Enceladus' subsurface waters and released by sputter erosion in Saturn's E ring. The composition and the limited size range (2 to 8 nanometres in radius) of stream particles indicate ongoing high-temperature (>90 °C) hydrothermal reactions associated with global-scale geothermal activity that quickly transports hydrothermal products from the ocean floor at a depth of at least 40 kilometres up to the plume of Enceladus.

  10. Utilization of strategical model of hydro-thermal generation in equivalents sub-systems - NEWAVE - in the evaluation of the interchange explicitly representation; Uso do modelo estrategico de geracao hidrotermica a subsistemas equivalentes - Newave - na avaliacao da representacao explicita do intercambio

    Energy Technology Data Exchange (ETDEWEB)

    Macieira, M. Elvira; Costa, Joari; Gorenstin, Boris [Centro de Pesquisas de Energia Eletrica (CEPEL), Rio de Janeiro, RJ (Brazil); Suanno, Claudia [FURNAS Centrais Eletricas S.A., Rio de Janeiro, RJ (Brazil); Kligerman, Alberto [ELETROBRAS, Rio de Janeiro, RJ (Brazil); Pereira, Mario

    1995-12-31

    The basic objective of the long term hydrothermal system operational planning is to determine optimum strategies to thermal generation and optimal interchange among electrical regions, aiming to minimize the expected value of the operation cost. This work presents, thorough a case study, the NEWAVE model, presently being developed by CEPEL, the research center of the Brazilian electric power holding company, based in dual stochastic dynamic programing 7 figs., 14 refs.

  11. Hydrothermal fluoride and chloride complexation of indium: an EXAFS study

    Science.gov (United States)

    Loges, Anselm; Testemale, Denis; Huotari, Simo; Honkanen, Ari-Pekka; Potapkin, Vasily; Wagner, Thomas

    2017-04-01

    Indium (In) is one of the geochemically lesser studied ore metals, and the factors that control the hydrothermal transport and deposition are largely unknown. It has no ore deposits of its own and is commonly mined as a by-product of Zn ores, and there are very few minerals that contain In as an essential structural component. Recently, industrial application of In in touch screen devices has drastically increased demand, which is projected to exceed supply from the current sources in the near future. Since the most relevant In sources are hydrothermal sphalerite ores and to a lesser extent hydrothermal greisen-type deposits in evolved granitic plutons, the aqueous geochemistry of In is of particular interest for understanding its ore forming processes. As a first step towards a comprehensive model for hydrothermal In solubility and speciation, we have studied In speciation in fluoride and chloride bearing solutions at 30-400˚ C and 500 bar using X-Ray Absorption Spectroscopy (XAS) measurements. The experiments were conducted in a unique hydrothermal autoclave setup at beamline BM30B-FAME at the European Synchrotron Radiation Facility (ESRF) in Grenoble, France. Our results show that the complexation of In changes dramatically between 30 and 400˚ C. Below ca. 200˚ C, fluoride complexes are the most stable ones, but they break down at higher temperatures. Chloride complexes on the other hand become increasingly stable with increasing temperature. This behavior has interesting consequences for natural ore forming systems. In Cl-rich systems (e.g. massive sulfide ores formed in sea floor environments), cooling can be an effective precipitating mechanism. In F-rich systems, fluoride complexation can extend In mobility to low temperatures and In will only precipitate when F is effectively removed from the fluid, e.g. by mixing with a Ca-rich fluid and precipitation of fluorite (CaF2) as is commonly observed in skarn or greisen-type deposits. Due to In complexing with

  12. Combining experimental petrology with InSAR deformation constraints on the magmatic system prior to recent eruptions at Kelud volcano, Indonesia

    Science.gov (United States)

    Cassidy, Mike; Castro, Jonathan; Helo, Christoph; Ebmeier, Susanna; Watt, Sebastian

    2017-04-01

    The parameters that govern the eruptive style at volcanoes are critical to understand, since the volcanic hazards posed to the nearby populations are directly related on whether an eruption is explosive or effusive. Eruptions from Kelud volcano located in East Java, Indonesia are difficult to forecast in that sense, because the eruptive style varies considerably, from effusive eruptions e.g. 1920 & 2007 to explosive eruptions in 1990 and 2014. Experiments were undertaken to constrain the magma storage conditions such as pressure, temperature and volatile contents prior to both explosive and effusive eruptions at Kelud. A gas-pressurized TZM cold-seal pressure vessel was used, whereby the sample (coarsely-crushed aliquots of the 2014 Kelud pumice contained in a AgPd capsule) were held at upper crustal conditions for several days to equilibrate, and then rapidly quenched using a water-cooled coupling system to prevent further crystallisation. The experiments were held near the NNO oxygen buffer using a double-capsule method. A range of pressures (25-200 MPa), temperatures (950-1100 °C), H2O-saturated and mixed H2O-CO2 conditions were explored in this study. Experimental matrix glass and mineral rim compositions, as well as crystal contents were measured and compared to the natural mineral and groundmass characteristics erupted in explosive (1990, 2014) and effusive (2007) eruptions. The experiments were conducted on crystal-rich basaltic andesite pumice from the 2014 eruption, as this has a near identical bulk composition to the other effusively and explosively erupted products. The 2014 pumice therefore represents an ideal experimental starting material which can be applied to other Kelud eruption types investigated. This presentation will discuss the results from these experiments, which are the first to be conducted on Kelud volcanics, with the aim of elucidating magma storage conditions that precede Kelud's different eruption styles. These constraints will be

  13. Petrology and Geochemistry of Hydrothermally Altered Volcanic Rocks in the Iheya North Hydrothermal Field, Middle Okinawa Trough

    Science.gov (United States)

    Yamasaki, T.

    2015-12-01

    The Iheya North hydrothermal field is located in the middle Okinawa Trough, a young and actively spreading back-arc basin extending behind the Ryukyu arc-trench system in the southeastern margin of the East China Sea. In this hydrothermal field, two scientific drilling expeditions (IODP Exp 331 and SIP CK14-04) were conducted using a deep-sea drilling vessel "Chikyu," and samples from a total of 27 holes were taken. Through these expeditions, Kuroko-type volcanogenic massive sulfide deposits (VMS), hydrothermally altered volcanic rocks, and pumiceous and pelagic sediments were recovered. The recovered core provided important information about the relationship between hydrothermal activity, alteration, and ore mineralization. Whole-rock major element composition and trace element (TE) patterns of pumices were very similar to those of rhyolites in the middle Okinawa Trough (RMO). However, pumices were relatively enriched in chalcophile elements Sr and Nb, which suggest incipient mineralization. Volcanic rock generally demonstrated strong silicification and was greenish pale gray in color. Regardless of severe alteration, some rock displayed major element composition broadly similar to the RMO. Alteration was evidenced by an increase in the content of SiO2 and MgO, and decrease in Al2O3, Na2O, and K2O content. The most striking geochemical feature of altered volcanic rock was the discordance between texture and the degree of modification of TEs. Some samples showed decussate texture occupied by petal-like quartz with severe silicification, but no prominent disturbance of concentration and patterns of TEs were observed. In contrast, samples with well-preserved igneous porphyritic texture showed very low TE content and modification of TE patterns. These results suggest that the modification of texture and composition of TEs, as well as silicification, do not occur by a uniform process, but several processes. This may reflect the differences in temperature and the

  14. Seismic Characterization of Hypogenic Karst Systems Associated with Deep Hydrothermal Fluids in the Middle-Lower Ordovician Yingshan Formation of the Shunnan Area, Tarim Basin, NW China

    OpenAIRE

    Zhu, Hongtao; Zhu, Xiu; Chen, Honghan

    2017-01-01

    Two fundamental forms of hypogenic karst systems (lateral stratiform hypogenic and cross-formational fault-vein hypogenic karst system) are distinguished mainly by differential effects of preexisting faults. In seismic cross sections, hypogenic karst systems are expressed as complex string-beads-like seismic reflections associated with faults. In this study, a new seismic characterization workflow was developed including seismic amplitude thresholding, fault interpretation, pickup, and merge ...

  15. Colorado's hydrothermal resource base: an assessment

    Energy Technology Data Exchange (ETDEWEB)

    Pearl, R.H.

    1981-01-01

    As part of its effort to more accurately describe the nations geothrmal resource potential, the US Department of Energy/Division of Geothermal Energy contracted with the Colorado Geological survey to appraise the hydrothermal (hot water) geothermal resources of Colorado. Part of this effort required that the amount of energy that could possibly be contained in the various hydrothermal systems in Colorado be estimated. The findings of that assessment are presented. To make these estimates the geothermometer reservoir temperatures estimated by Barrett and Pearl (1978) were used. In addition, the possible reservoir size and extent were estimated and used. This assessment shows that the total energy content of the thermal systems in Colorado could range from 4.872 x 10{sup 15} BTU's to 13.2386 x 10{sup 15} BTU's.

  16. Experimental Investigation of Organic Synthesis in Hydrothermal Environments

    Science.gov (United States)

    Shock, Everett L.

    1998-01-01

    The results of the investigation were presented at a Astrobiology Institute General Meeting. Seafloor hydrothermal systems may be the most likely locations on the early Earth for the emergence of life. Because of the disequilibrium inherent in such dynamic, mixing environments, abundant chemical energy would have been available for formation of the building blocks of life. In addition, theoretical studies suggest that organic compounds in these conditions would reach metastable states, due to kinetic barriers to the formation of stable equilibrium products (CO2 and methane). The speciation of organic carbon in metastable states is highly dependent on the oxidation state, pH, temperature, pressure and bulk composition of the system. The goal of our research is to investigate the effects of a number external variables on the formation, transformation, and stability of organic compounds at hydrothermal conditions. We have begun experimental work to attempt to control the oxidation state of simulated hydrothermal systems by using buffers composed of mineral powders and gas mixtures. We are also beginning to test the stability of organic compounds under these conditions.

  17. Powering hydrothermal activity on Enceladus

    Science.gov (United States)

    Tobie, Gabriel; Choblet, Gael; Sotin, Christophe; Behounkova, Marie; Cadek, Ondrej; Postberg, Frank; Soucek, Ondrej

    2017-04-01

    A series of evidence gathered by the Cassini spacecraft indicates that the intense activity at the South Pole of Saturn's moon Enceladus is related to a subsurface salty water reservoir associated with seafloor hydrothermal activity (Hsu et al. 2015, Waite et al. 2017). The observation of an elevated libration implies that this reservoir is global with a thin ice shell (20-25 km in average (Thomas et al. 2016) and power and a mechanism to focus the release of heat in the SPT, unexplained by previous models. Here we investigate heat generation by tidal friction in the porous core and simulate heat transport by water flow for core porosities consistent with Cassini gravity data (Iess et al. 2014). We demonstrate that, for effective viscosity and permeability values typical of water-saturated terrestrial rock analogues, more than 20 GW can be generated in the core, which can maintain a global liquid ocean and power hydrothermal activity at the seafloor. By performing 3D simulations of water flow in a tidally-heated porous rock matrix, we show that heat is extracted from the core in the form of focused outflows of hot water (> 90 °C) mostly in the polar regions, explaining strongly localized ice shell thinning. Owing to strong dissipation in Saturn (Lainey et al. 2017), we show that circulation of hot waters in the core may last at least 20-25 million years and that 10 to 100% of the oceanic volume may be processed in the core at temperature higher than 90°C on this timescale. Whether this has been sufficient for the emergence of life can be explored by future spacecraft missions (Mitri et al., this meeting; Lunine et al. 2017).

  18. Prior Elicitation, Assessment and Inference with a Dirichlet Prior

    Directory of Open Access Journals (Sweden)

    Michael Evans

    2017-10-01

    Full Text Available Methods are developed for eliciting a Dirichlet prior based upon stating bounds on the individual probabilities that hold with high prior probability. This approach to selecting a prior is applied to a contingency table problem where it is demonstrated how to assess the prior with respect to the bias it induces as well as how to check for prior-data conflict. It is shown that the assessment of a hypothesis via relative belief can easily take into account what it means for the falsity of the hypothesis to correspond to a difference of practical importance and provide evidence in favor of a hypothesis.

  19. Relationship between enhanced dewaterability and structural properties of hydrothermal sludge after hydrothermal treatment of excess sludge.

    Science.gov (United States)

    Wang, Liping; Li, Aimin; Chang, Yuzhi

    2017-04-01

    Hydrothermal treatment is an effective method to enhance the deep dewaterability of excess sludge with low energy consumption. In this study, an insight into the relationship between enhanced dewaterability and structural properties of the produced hydrothermal sludge was presented, aiming at better understanding the effect of hydrothermal process on excess sludge dewatering performance. The results indicated that hydrothermal effect induced the transformation of surface water to interstitial and free water by lowering the binding strength between adjacent water and solid particles and that free water became the main form for moisture existence in hydrothermal sludge as temperature was higher than 180 °C. Increase in temperature of hydrothermal treatment generated a significant size reduction of sludge flocs but treated sludge with a higher rigidity, which not only strengthened the network of hydrothermal sludge but also destroyed the binding of EPS with water. Hydrothermal process caused crevice and pore structures of excess sludge to disappear gradually, which was a main driving force of water removal as temperature was below 150 °C. With the temperature of hydrothermal treatment exceeding 180 °C, the morphology of hydrothermal sludge became rough which linked closely to the solid precipitation of condensation polymerization, and further became smooth at higher temperature (210 °C) due to the coal-like structures with higher aromaticities, indicating that hydrothermal reaction pathways began to play a main role in enhanced dewaterability. Hydrothermal treatment led to more alkyl and aromatic carbon, but lower O-alkyl, carboxyl and carbonyl carbon. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Learning about Hydrothermal Volcanic Activity by Modeling Induced Geophysical Changes

    Directory of Open Access Journals (Sweden)

    Gilda M. Currenti

    2017-05-01

    Full Text Available Motivated by ongoing efforts to understand the nature and the energy potential of geothermal resources, we devise a coupled numerical model (hydrological, thermal, mechanical, which may help in the characterization and monitoring of hydrothermal systems through computational experiments. Hydrothermal areas in volcanic regions arise from a unique combination of geological and hydrological features which regulate the movement of fluids in the vicinity of magmatic sources capable of generating large quantities of steam and hot water. Numerical simulations help in understanding and characterizing rock-fluid interaction processes and the geophysical observations associated with them. Our aim is the quantification of the response of different geophysical observables (i.e., deformation, gravity, and magnetic fields to hydrothermal activity on the basis of a sound geological framework (e.g., distribution and pathways of the flows, the presence of fractured zones, caprock. A detailed comprehension and quantification of the evolution and dynamics of the geothermal systems and the definition of their internal state through a geophysical modeling approach are essential to identify the key parameters for which the geothermal system may fulfill the requirements to be exploited as a source of energy. For the sake of illustration only, the numerical computations are focused on a conceptual model of the hydrothermal system of Vulcano Island by simulating a generic 1-year unrest and estimating different geophysical changes. We solved (i the mass and energy balance equations of flow in porous media for temperature, pressure and density changes, (ii the elastostatic equation for the deformation field and (iii the Poisson's equations for gravity and magnetic potential fields. Under the model assumptions, a generic unrest of 1-year engenders on the ground surface low amplitude changes in the investigated geophysical observables, that, being above the accuracies of

  1. Hydrothermal synthesis and characterisation of new ...

    Indian Academy of Sciences (India)

    PCH2PO3H)] (A = Rb (1), NH4 (2) and Tl (3)) have been synthesized by hydrothermal method and structurally characterised by X-ray diffraction and spectroscopic techniques. These compounds crystallize in monoclinic space group, 21/ ...

  2. Hydrothermal syntheses and single crystal structural ...

    Indian Academy of Sciences (India)

    ), and Zn(II); OPTA = 1-oxopyridinium-2-thioacetato) was prepared from the appropriate metal acetates, 1-oxopyridinium-2-thioacetic acid (OPTAH), and potassium hydroxide in hydrothermal media and structurally characterized. The structure ...

  3. Effect of hydrothermal processing on ginseng extract

    Directory of Open Access Journals (Sweden)

    Jebin Ryu

    2017-10-01

    Conclusion: Therefore, hydrothermal processing offers significant improvements over the conventional steaming process. In particular, at temperatures over 140°C, high yields of the transformed ginsenosides and increased antioxidant activities were obtained in tens of minutes.

  4. Hydrothermal alteration in basalts from Vargeão impact structure, south Brazil, and implications for recognition of impact-induced hydrothermalism on Mars

    Science.gov (United States)

    Yokoyama, Elder; Nédélec, Anne; Baratoux, David; Trindade, Ricardo I. F.; Fabre, Sébastien; Berger, Gilles

    2015-05-01

    The 12-km-wide Vargeão impact structure was formed 123 Myr ago in the Paraná basaltic province (southern Brazil). At this time the province region had a dry climate, although a large brackish aquifer had been formed in the underlying sandstones. It is therefore one of the best terrestrial analogs for studying impact-related products on a dry martian surface environment with preserved ice-rich ground. The basalts within the impact structure display cm-sized breccia veins filled with lithic clasts, glassy remnants, newly formed Fe-oxyhydroxides and secondary phases, such as calcite, phyllosilicates and, subordinately quartz and zeolite. The textural and mineralogical study of these phases demonstrate their hydrothermal origin. Although the very center of the structure has experienced the highest pressures and temperatures, the most developed hydrothermal changes are recognized in an inner collar surrounding the central depression. This inner collar is also the location of major modifications of the rock magnetic properties. These magnetic signatures are related to the distribution of impact-related faults and to the formation of new iron oxides. Geochemical modeling indicate that hydrothermal phases formation required low water/rock ratios. Our observations therefore suggest that hydrothermal alteration took place following the perturbation of the aquifer by the impact, but evidence for hydrothermal circulation is limited in comparison with other impact-related hydrothermal systems. This situation may be explained by the presence of the aquifer below the heat source, such a setting being exceptional for the Earth, but common on Mars. However, the spectroscopic signatures in visible/near infrared images suggest that this kind of impact-related hydrothermal alteration may be still indentified in large impact craters on Mars by orbital instruments. These results does not exclude the possibility that more developed alteration took place in breccias that are today

  5. Hydrothermal industrialization: direct heat development. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1982-05-01

    A description of hydrothermal resources suitable for direct applications, their associated temperatures, geographic distribution and developable capacity are given. An overview of the hydrothermal direct-heat development infrastructure is presented. Development activity is highlighted by examining known and planned geothermal direct-use applications. Underlying assumptions and results for three studies conducted to determine direct-use market penetration of geothermal energy are discussed.

  6. Effects of iron-containing minerals on hydrothermal reactions of ketones

    Science.gov (United States)

    Yang, Ziming; Gould, Ian R.; Williams, Lynda B.; Hartnett, Hilairy E.; Shock, Everett L.

    2018-02-01

    Hydrothermal organic transformations occurring in geochemical processes are influenced by the surrounding environments including rocks and minerals. This work is focused on the effects of five common minerals on reactions of a model ketone substrate, dibenzylketone (DBK), in an experimental hydrothermal system. Ketones play a central role in many hydrothermal organic functional group transformations, such as those converting hydrocarbons to oxygenated compounds; however, how these minerals control the hydrothermal chemistry of ketones is poorly understood. Under the hydrothermal conditions of 300 °C and 70 MPa for up to 168 h, we observed that, while quartz (SiO2) and corundum (Al2O3) had no detectable effect on the hydrothermal reactions of DBK, iron-containing minerals, such as hematite (Fe2O3), magnetite (Fe3O4), and troilite (synthetic FeS), accelerated the reaction of DBK by up to an order of magnitude. We observed that fragmentation products, such as toluene and bibenzyl, dominated in the presence of hematite or magnetite, while use of troilite gave primarily the reduction products, e.g., 1, 3-diphenyl-propane and 1, 3-diphenyl-2-propanol. The roles of the three iron minerals in these transformations were further explored by (1) control experiments with various mineral surface areas, (2) measuring H2 in hydrothermal solutions, and (3) determining hydrogen balance among the organic products. These results suggest the reactions catalyzed by iron oxides (hematite and magnetite) are promoted mainly by the mineral surfaces, whereas the sulfide mineral (troilite) facilitated the reduction of ketone in the reaction solution. Therefore, this work not only provides a useful chemical approach to study and uncover complicated hydrothermal organic-mineral interactions, but also fosters a mechanistic understanding of ketone reactions in the deep carbon cycle.

  7. Anaerobic digestion of yard waste with hydrothermal pretreatment.

    Science.gov (United States)

    Li, Wangliang; Zhang, Guangyi; Zhang, Zhikai; Xu, Guangwen

    2014-03-01

    The digestibility of lignocellulosic biomass is limited by its high content of refractory components. The objective of this study is to investigate hydrothermal pretreatment and its effects on anaerobic digestion of sorted organic waste with submerged fermentation. Hydrothermal pretreatment (HT) was performed prior to anaerobic digestion, and three agents were examined for the HT: hot compressed water, alkaline solution, and acidic solution. The concentrations of glucose and xylose were the highest in the sample pretreated in acidic solution. Compared with that of the untreated sample, the biogas yields from digesting the samples pretreated in alkaline solution, acidic solution, and hot water increased by 364, 107, and 79%, respectively. The decrease of chemical oxygen demand (COD) in liquid phase followed the same order as for the biogas yield. The initial ammonia content of the treated samples followed the order sample treated in acidic solution > sample treated in alkaline solution > sample treated in hot water. The concentrations of volatile fatty acids (VFAs) were low, indicating that the anaerobic digestion process was running at continuously stable conditions.

  8. Subcritical water as reaction environment: fundamentals of hydrothermal biomass transformation.

    Science.gov (United States)

    Möller, Maria; Nilges, Peter; Harnisch, Falk; Schröder, Uwe

    2011-05-23

    Subcritical water, that is, water above the boiling and below critical point, is a unique and sustainable reaction medium. Based on its solvent properties, in combination with the often considerable intrinsic water content of natural biomass, it is often considered as a potential solvent for biomass processing. Current knowledge on biomass transformation in subcritical water is, however, still rather scattered without providing a consistent picture. Concentrating on fundamental physical and chemical aspects, this review summarizes the current state of knowledge of hydrothermal biomass conversion in subcritical water. After briefly introducing subcritical water as a reaction medium, its advantages for biomass processing compared to other thermal processes are highlighted. Subsequently, the physical-chemical properties of subcritical water are discussed in the light of their impact on the occurring chemical reactions. The influence of major operational parameters, including temperature, pressure, and reactant concentration on hydrothermal biomass transformation processes are illustrated for selected carbohydrates. Major emphasis is put on the nature of the carbohydrate monomers, since the conversion of the respective polymers is analogous with the additional prior step of hydrolytic depolymerization. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Prior low- or high-intensity exercise alters pacing strategy, energy system contribution and performance during a 4-km cycling time trial.

    Science.gov (United States)

    Correia-Oliveira, Carlos Rafaell; Santos, Ralmony Alcantara; Silva-Cavalcante, Marcos David; Bertuzzi, Romulo; Kiss, Maria Augusta Peduti Dal'Molin; Bishop, David John; Lima-Silva, Adriano Eduardo

    2014-01-01

    We analyzed the influence of prior exercise designed to reduce predominantly muscle glycogen in either type I or II fibers on pacing and performance during a 4-km cycling time trial (TT). After preliminary and familiarization trials, in a randomized, repeated-measures crossover design, ten amateur cyclists performed: 1) an exercise designed to reduce glycogen of type I muscle fibers, followed by a 4-km TT (EX-FIB I); 2) an exercise designed to reduce glycogen of type II muscle fibers, followed by a 4-km TT (EX-FIB II) and; 3) a 4-km TT, without the prior exercise (CONT). The muscle-glycogen-reducing exercise in both EX-FIB I and EX-FIB II was performed in the evening, ∼12 h before the 4-km TT. Performance time was increased and power output (PO) was reduced in EX-FIB I (432.8±8.3 s and 204.9±10.9 W) and EX-FIB II (428.7±6.7 s and 207.5±9.1 W) compared to CONT (420.8±6.4 s and 218.4±9.3 W; P0.05). The PO was lower in EX-FIB I than in CONT at the beginning and middle of the trial (P0.05). The integrated electromyography was unchanged between conditions (P>0.05). Performance may have been impaired in EX-FIB I due a more conservative pacing at the beginning and middle, which was associated with a reduced aerobic contribution. In turn, the PO profile adopted in EX-FIB II was also reduced throughout the trial, but the impairment in performance may be attributed to a reduced glycolytic contribution (i.e. reduced lactate accumulation).

  10. Prior low- or high-intensity exercise alters pacing strategy, energy system contribution and performance during a 4-km cycling time trial.

    Directory of Open Access Journals (Sweden)

    Carlos Rafaell Correia-Oliveira

    Full Text Available We analyzed the influence of prior exercise designed to reduce predominantly muscle glycogen in either type I or II fibers on pacing and performance during a 4-km cycling time trial (TT. After preliminary and familiarization trials, in a randomized, repeated-measures crossover design, ten amateur cyclists performed: 1 an exercise designed to reduce glycogen of type I muscle fibers, followed by a 4-km TT (EX-FIB I; 2 an exercise designed to reduce glycogen of type II muscle fibers, followed by a 4-km TT (EX-FIB II and; 3 a 4-km TT, without the prior exercise (CONT. The muscle-glycogen-reducing exercise in both EX-FIB I and EX-FIB II was performed in the evening, ∼12 h before the 4-km TT. Performance time was increased and power output (PO was reduced in EX-FIB I (432.8±8.3 s and 204.9±10.9 W and EX-FIB II (428.7±6.7 s and 207.5±9.1 W compared to CONT (420.8±6.4 s and 218.4±9.3 W; P0.05. The PO was lower in EX-FIB I than in CONT at the beginning and middle of the trial (P0.05. The integrated electromyography was unchanged between conditions (P>0.05. Performance may have been impaired in EX-FIB I due a more conservative pacing at the beginning and middle, which was associated with a reduced aerobic contribution. In turn, the PO profile adopted in EX-FIB II was also reduced throughout the trial, but the impairment in performance may be attributed to a reduced glycolytic contribution (i.e. reduced lactate accumulation.

  11. Antarctic marine biodiversity and deep-sea hydrothermal vents.

    Directory of Open Access Journals (Sweden)

    Steven L Chown

    2012-01-01

    Full Text Available The diversity of many marine benthic groups is unlike that of most other taxa. Rather than declining from the tropics to the poles, much of the benthos shows high diversity in the Southern Ocean. Moreover, many species are unique to the Antarctic region. Recent work has shown that this is also true of the communities of Antarctic deep-sea hydrothermal vents. Vent ecosystems have been documented from many sites across the globe, associated with the thermally and chemically variable habitats found around these, typically high temperature, streams that are rich in reduced compounds and polymetallic sulphides. The animal communities of the East Scotia Ridge vent ecosystems are very different to those elsewhere, though the microbiota, which form the basis of vent food webs, show less differentiation. Much of the biological significance of deep-sea hydrothermal vents lies in their biodiversity, the diverse biochemistry of their bacteria, the remarkable symbioses among many of the marine animals and these bacteria, and the prospects that investigations of these systems hold for understanding the conditions that may have led to the first appearance of life. The discovery of diverse and unusual Antarctic hydrothermal vent ecosystems provides opportunities for new understanding in these fields. Moreover, the Antarctic vents south of 60°S benefit from automatic conservation under the Convention on the Conservation of Antarctic Marine Living Resources and the Antarctic Treaty. Other deep-sea hydrothermal vents located in international waters are not protected and may be threatened by growing interests in deep-sea mining.

  12. Student Models for Prior Knowledge Estimation

    Science.gov (United States)

    Nižnan, Juraj; Pelánek, Radek; Rihák, Jirí

    2015-01-01

    Intelligent behavior of adaptive educational systems is based on student models. Most research in student modeling focuses on student learning (acquisition of skills). We focus on prior knowledge, which gets much less attention in modeling and yet can be highly varied and have important consequences for the use of educational systems. We describe…

  13. Surface and subsurface hydrothermal flow pathways at Norris Geyser Basin, Yellowstone National Park

    Science.gov (United States)

    Graham Wall, B. R.

    2005-12-01

    During summer 2003 at Yellowstone's Norris Geyser Basin notable changes were observed in the discharge of heat and steam, creating new thermal features, dying vegetation, and the consequent closure of trails to protect public safety. In order to interpret data collected from GPS, seismic, and temperature instruments deployed in response to the increased hydrothermal activity, a study has been undertaken to provide a more complete knowledge of the spatial distribution of subsurface fluid conduits. Geologic data, including mapped outcrops, aerial imagery, thermal infrared imagery, and subsurface core, indicate that fracture pathways in the Lava Creek Tuff (LCT) channel flow in the hydrothermal system. These data show clear evidence that NE-SW and NW-SE trending structures provide major flow pathways at Norris. By mapping fracture sets in outcrops of LCT with varied degrees of hydrothermal alteration, one can consistently identify fractures that localize hydrothermal fluid flow, alteration, and the geometry of surface thermal features. Alteration is characterized by acid leaching that quickly alters LCT mafic minerals and glassy groundmass, which in outcrop is recognized by corroded and disaggregated LCT with local secondary mineral deposition. Mapping the sequence from unaltered to altered LCT has identified vertical cooling joints as primary conduits for hydrothermal fluids. These vertical joints correlate with the NE-SW trending geomorphic expression of the LCT in this area, and parallel the adjacent caldera boundary. Horizontal fractures parallel depositional stratigraphy, and in core from drill holes Y-9 (248 m) and Y-12 (332 m) appear to initiate at collapsed vapor-phase cavities or regions of altered fiamme. Vertical fractures in the core show sequences of hydrothermal minerals locally derived from water-rock interaction that line fracture walls, characteristic of mineral deposition associated with repeat reactivation. Although the hydrothermal system is

  14. Hydrothermal speleogenesis in carbonates and metasomatic silicites induced by subvolcanic intrusions: a case study from the Štiavnické vrchy Mountains, Slovakia

    Directory of Open Access Journals (Sweden)

    Pavel Bella

    2016-01-01

    Full Text Available Several caves of hydrothermal origin in crystalline limestones and metasomatic silicites were investigated in the central zone of the Štiavnica stratovolcano, Štiavnické vrchy Mountains, central Slovakia. Evidence of hydrothermal origin includes irregular spherical cave morphology sculptured by ascending thermal water, occurrence of large calcite crystals and hydrothermal alteration of host rocks, including hydrothermal clays. The early phases of speleogenesis in the crystalline limestone near Sklené Teplice Spa were caused by post-magmatic dissolution linked either to the emplacement of subvolcanic granodiorite intrusions during Late Badenian time or to the spatially associated Late Sarmatian epithermal system. Speleogenesis in metasomatic silicites in the Šobov area is related to hydrothermal processes associated with the pre-caldera stage of the Štiavnica stratovolcano in Late Badenian. Both localities are remarkable examples of hydrothermal speleogenesis associated with Miocene volcanic and magmatic activity in the Western Carpathians.

  15. Hydrothermal alteration maps of the central and southern Basin and Range province of the United States compiled from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data

    Science.gov (United States)

    Mars, John L.

    2013-01-01

    Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data and Interactive Data Language (IDL) logical operator algorithms were used to map hydrothermally altered rocks in the central and southern parts of the Basin and Range province of the United States. The hydrothermally altered rocks mapped in this study include (1) hydrothermal silica-rich rocks (hydrous quartz, chalcedony, opal, and amorphous silica), (2) propylitic rocks (calcite-dolomite and epidote-chlorite mapped as separate mineral groups), (3) argillic rocks (alunite-pyrophyllite-kaolinite), and (4) phyllic rocks (sericite-muscovite). A series of hydrothermal alteration maps, which identify the potential locations of hydrothermal silica-rich, propylitic, argillic, and phyllic rocks on Landsat Thematic Mapper (TM) band 7 orthorectified images, and geographic information systems shape files of hydrothermal alteration units are provided in this study.

  16. Presence and diversity of anammox bacteria in cold hydrocarbon-rich seeps and hydrothermal vent sediments of the Guaymas Basin

    NARCIS (Netherlands)

    Russ, L.; Kartal, B.; Op den Camp, H.J.M.; Sollai, M.; Le Bruchec, J.; Caprais, J.-C.; Godfroy, A.; Sinninghe Damsté, J.S.; Jetten, M.S.M.

    2013-01-01

    Hydrothermally active sediments are highly productive, chemosynthetic areas which are characterized by the rapid turnover of particulate organic matter under extreme conditions in which ammonia is liberated. These systems might be suitable habitats for anaerobic ammonium oxidizing (anammox) bacteria

  17. Using a Large N Geophone Array to Identify Hydrothermal Seismic Sources in the Upper Geyser Basin of Yellowstone National Park

    Science.gov (United States)

    Farrell, J.; Lin, F. C.; Allam, A. A.; Smith, R. B.; Karplus, M. S.

    2016-12-01

    The recent availability of large N seismic arrays provides a unique capability for recording environmental seismic signals that can be monitored in detail. In November 2015, the University of Utah, in collaboration with Yellowstone National Park and the University of Texas El Paso, installed a seismic array in the Upper Geyser Basin of Yellowstone National Park centered on Old Faithful geyser. The array consisted of 133 three-component 5 Hz geophones recording continuously at 1000Hz for two weeks, with an average station spacing of 50 m and an aperture of 1 km. The array recorded numerous hydrothermal seismic sources including distinct seismic signals that could be attributed to surficial hydrothermal features as well as those that do not appear to be related to any individual surface feature. Old Faithful geyser eruptions themselves are largely aseismic. However, hydrothermal tremor, likely due to collapsing bubbles within the subsurface plumbing system, starts building about 45 minutes prior to an Old Faithful eruption. Tremor amplitudes slowly increase with time until they reach a peak about 25 minutes prior to the eruption and then slowly decrease until the eruption begins. The seismic signal related to the buildup of the Old Faithful subsurface reservoir is recorded at stations north, south and to the east of Old Faithful but is missing on stations to the northwest. This suggests a shallow subsurface feature that strongly attenuates the seismic signal immediately NW of the cone of Old Faithful. Another of the more interesting signals is observed regularly about every 38 minutes and may come from Doublet Pool on Geyser Hill. This signal has large seismic wave amplitudes and is recorded across much of the seismic array. The Geyser Hill signal may also be affected by the aforementioned subsurface attenuating feature NW of the Old Faithful cone. Interestingly, there is a persistent 20-25 Hz signal at several stations that seems to be affected by variations air

  18. Accommodating Uncertainty in Prior Distributions

    Energy Technology Data Exchange (ETDEWEB)

    Picard, Richard Roy [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Vander Wiel, Scott Alan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-01-19

    A fundamental premise of Bayesian methodology is that a priori information is accurately summarized by a single, precisely de ned prior distribution. In many cases, especially involving informative priors, this premise is false, and the (mis)application of Bayes methods produces posterior quantities whose apparent precisions are highly misleading. We examine the implications of uncertainty in prior distributions, and present graphical methods for dealing with them.

  19. Tidal Evolution and Hydrothermal Activity in IcyWorlds

    Science.gov (United States)

    Vance, S.; Hussmann, H.

    2008-09-01

    The tidal heating that sustains a subsurface ocean in Europa likely varied in intensity through the moons history due to the exchange of orbital angular momentum with the innermost Galilean satellite, Io [1]. Tidal interactions elsewhere in the solar system — e.g. in Neptunes moon Triton, and in Kuiper belt systems such as Pluto-Charon and the 2003 EL61 system (Santa-Rudolph-Blitzen) — highlight the potential for vigorously heated subsurface oceans and thus the existence of hydrothermal systems in icy worlds. Understanding the extent and nature of hydrothermal activity in such systems is important for assessing the availability of essential elements and organic compounds necessary sustain and, possibly, originate life [2, 3, 4, 5, 6, 7]. During periods of low tidal heating in such systems, hydrothermalism driven by serpentinization (reaction of water with ultramafic rock) may be extensive, with implications for seafloor production of hydrogen, methane and other potential nutrients, and elements necessary to originate and support life in icy world oceans. For Enceladus, an anomalously dense satellite for its size, radiogenic heating and overburden pressure in the mantle are sufficiently low to permit fracturing of the entirety of the moons rocky interior on long time scales [8]. Estimates of methane production from serpentinization of Enceladus interior, based on measured fluxes from the Lost City Hydrothermal Field [9], are an order of magnitude greater than fluxes observed at Enceladuss south polar plume by the Cassini Ion Neutral Mass Spectrometer [10]. For the largest icy worlds in the Solar System — Titan, Ganymede and Callisto—pressures at and below the H2Orock interface are likely too high to permit the formation of microfractures, so an alternative explanation is required if methane is endogenous. Aqueous alteration may be augmented from the above estimates if altered crust is rejuvenated during periods of increased tidal dissipation. Crustal

  20. Are there significant hydrothermal resources in the US part of the Cascade Range?

    Energy Technology Data Exchange (ETDEWEB)

    Muffler, L.J. Patrick; Guffanti, Marianne

    1995-01-26

    The Cascade Range is a geothermal dichotomy. On the one hand, it is an active volcanic arc above a subducting plate and is demonstrably an area of high heat flow. On the other hand, the distribution of hydrothermal manifestations compared to other volcanic arcs is sparse, and the hydrothermal outflow calculated from stream chemistry is low. Several large estimates of undiscovered geothermal resources in the U.S. part of the Cascade Range prepared in the 1970s and early 1980s were based fundamentally on two models of the upper crust. One model assumed that large, partly molten, intrusive bodies exist in the upper 10 km beneath major volcanic centers and serve as the thermal engines driving overlying hydrothermal systems. The other model interpreted the coincident heat-flow and gravity gradients west of the Cascade crest in central Oregon to indicate a partly molten heat source at 10 {+-} 2 km depth extending {approx}30 km west from the axis of the range. Investigations of the past ten years have called both models into question. Large long-lived high-temperature hydrothermal systems at depths <3 km in the U.S. part of the Cascade Range appear to be restricted to silicic domefields at the Lassen volcanic center, Medicine Lake volcano, Newberry volcano, and possibly the Three Sisters. Federal land-use restrictions further reduce this list to Medicine Lake and Newberry. Dominantly andesitic stratocones appear to support only small transitory hydrothermal systems related to small intrusive bodies along the volcanic conduits. The only young caldera, at Crater Lake, supports only low- to intermediate-temperature hydrothermal systems. Most of the Cascade Range comprises basaltic andesites and has little likelihood for high-level silicic intrusions and virtually no potential for resultant large high-temperature hydrothermal systems. Undiscovered hydrothermal resources of the Cascade Range of the United States are substantially lower than previous estimates. The range does

  1. Hydrothermal Liquefaction Treatment Hazard Analysis Report

    Energy Technology Data Exchange (ETDEWEB)

    Lowry, Peter P. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wagner, Katie A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-09-12

    Hazard analyses were performed to evaluate the modular hydrothermal liquefaction treatment system. The hazard assessment process was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. The analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public. The following selected hazardous scenarios received increased attention: •Scenarios involving a release of hazardous material or energy, controls were identified in the What-If analysis table that prevent the occurrence or mitigate the effects of the release. •Scenarios with significant consequences that could impact personnel outside the immediate operations area, quantitative analyses were performed to determine the potential magnitude of the scenario. The set of “critical controls” were identified for these scenarios (see Section 4) which prevent the occurrence or mitigate the effects of the release of events with significant consequences.

  2. Reconnaissance of the hydrothermal resources of Utah

    Energy Technology Data Exchange (ETDEWEB)

    Rush, F.E.

    1983-01-01

    Geologic factors in the Basin and Range province in Utah are more favorable for the occurrence of geothermal resources than in other areas on the Colorado Plateaus or in the Middle Rocky Mountains. These geologic factors are principally crustal extension and crustal thinning during the last 17 million years. Basalts as young as 10,000 years have been mapped in the area. High-silica volcanic and intrusive rocks of Quaternary age can be used to locate hydrothermal convection systems. Drilling for hot, high-silica, buried rock bodies is most promising in the areas of recent volcanic activity. Southwestern Utah has more geothermal potential than other parts of the Basin and Range province in Utah. The Roosevelt Hot Springs area, the Cove Fort-Sulphurdale area, and the area to the north as far as 60 kilometers from them probably have the best potential for geothermal development for generation of electricity. Other areas with estimated reservoir temperatures greater than 150/sup 0/C are Thermo, Monroe, Red Hill (in the Monroe-Joseph Known Geothermal Resource Area), Joseph Hot Springs, and the Newcastle area. The rates of heat and water discharge are high at Crater, Meadow, and Hatton Hot Springs, but estimated reservoir temperatures there are less than 150/sup 0/C. Additional exploration is needed to define the potential in three additional areas in the Escalante Desert. 28 figs., 18 tabs.

  3. Hydrothermal Vents of Juan de Fuca Ridge

    Science.gov (United States)

    Stark, Joyce

    As a member of REVEL (Research and Education: Volcanoes, Exploration and Life), I had an opportunity to participant in a scientific research cruise focused on the active volcanoes along the Juan de Fuca Ridge, the submarine spreading center off the Washington- Oregon-Canada coast. REVEL was sponsored by the National Science Foundation, University of Washington, Pennsylvania State University and the American Museum of Natural History. We studied the geological, chemical and biological processes associated with active hydrothermal systems and my research focused on the biological communities of the sulfide structures. We worked on board the Woods Hole Oceanographic Institution Vessel, R/V Atlantis and the submersible ALVIN was used to sample the "Black Smokers". As a member of the scientific party, I participated in collection and sorting of biological specimens from the vent communities, attended lectures by scientists, contributed to the cruise log website, maintained a journal and developed my own research project. It was my responsibility to bring this cutting-edge research back to the classroom.

  4. Health Promoting Life-Style Behaviors and Systemic Inflamma-tion in African American and Caucasian Women Prior to Chemo-therapy for Breast Cancer.

    Science.gov (United States)

    E Lyon, Debra; Mohanraj, Lathika; Kelly, Debra Lynch; Elswick, Rk

    2014-01-01

    Racial disparities in breast cancer outcomes persist, with differential adverse outcomes in African American women. Although research has ex-amined possible genetic differences, there has been little research on potentially modifiable characteristics such as health promoting behaviors. The purpose of this article is to describe the characteristics and to compare the differences by race in lifestyle factors and inflammatory biomarkers in African American and Caucasian women with breast cancer. This is a baseline descriptive analysis from an ongoing randomized controlled trial that includes 124 women diagnosed with early stage breast cancer prior to chemotherapy. Data sources included medical records, self-re-port questionnaires and a blood sample for measures of inflammation. The sta-tistical analysis included descriptive statistics and ANOVA models to determine differences between the two groups. Overall, both groups had low levels of health promoting behaviors. African Americans had a significantly higher body mass index. Caucasian women consumed more alcohol. Levels of C-reactive protein and MIP-1β were significantly higher in African Americans. Potentially modifiable factors such as nutrition, physical activity and levels of inflammation warrant further attention.

  5. High-resolution Topography of PACMANUS and DESMOS Hydrothermal Fields in the Manus Basin through ROV "FAXIAN"

    Science.gov (United States)

    Luan, Z.; Ma, X.; Yan, J.; Zhang, X.; Zheng, C.; Sun, D.

    2016-12-01

    High-resolution topography can help us deeply understand the seabed and related geological processes (e.g. hydrothermal/cold spring systems) in the deep sea areas. However, such studies are rare in China due to the limit of deep-sea detection technology. Here, we report the advances of the application of ROV in China and the newly measured high-resolution topographical data in PACMANUS and DESMOS hydrothermal fields. In June 2015, the ROV "FAXIAN" with a multibeam system (Kongsberg EM2040) was deployed to measure the topography of PACMANUS and DESMOS hydrothermal fields in the Manus basin. A composite positioning system on the ROV provided long baseline (LBL) navigation and positioning during measurements, giving a high positioning accuracy (better than 0.5m). The raw bathymetric data obtained were processed using CARIS HIPS (version 8.1). Based on the high-resolution data, we can describe the topographical details of the PACMANUS and DESMOS hydrothermal fields. High-resolution terrain clearly shows the detailed characters of the topography in the PACMANUS hydrothermal field, and some cones are corresponding to the pre discovered hydrothermal points and volcanic area. Most hydrothermal points in the PACMANUS hydrothermal field mainly developed on the steep slopes with a gradient exceeding 30 °. In contrast, the DESMOS field is a caldera that is approximately 250 m deep in the center with an E-W diameter of approximately1 km and a N-S diameter of approximately 2 km. The seafloor is much steeper on the inner side of the circular fracture. Two highlands occur in the northern and the southern flanks of the caldera. Video record indicated that pillow lava, sulfide talus, breccia, anhydrite, outcrops, and sediment all appeared in the DESMOS field. This is the first time for the ROV "FAXIAN" to be used in near-bottom topography measurements in the hydrothermal fields, opening a window of deep-sea researches in China.

  6. Microbiological and chemical characterization of hydrothermal fluids at Tortugas Mountain Geothermal Area, southern New Mexico, USA

    Science.gov (United States)

    Schulze-Makuch, Dirk; Kennedy, John F.

    2000-06-01

    The Tortugas Mountain Geothermal Area is part of the larger hydrothermal system of the Rio Grande Rift, southern New Mexico, USA. Chemical and microbial parameters indicate that the sampled hydrothermal water derives from a mixture zone of deep, anaerobic water with meteoric water from an adjacent alluvial, non-thermal groundwater flow system. A microbial phospholipid fatty acid (PLFA) analysis indicates that biomass and diversity of hydrothermal groundwater are very low, whereas hydrothermal surface water is diverse and bacteria are in a rapid growth phase. A nucleic acid (DNA) analysis of the hydrothermal groundwater resulted in the identification of one eubacterium and two Archaea (archaebacteria); the eubacterium and one Archaea were previously unknown. The one Archaea that could be related to a known species is an extreme halophilic methanomicrobacterium. The presence of the halophilic Archaea and the other Archaea species supports the hypothesis of the Tortugas Mountain Geothermal Area being the discharge area of deep circulating groundwater within a bedrock-hosted regional groundwater flow system.

  7. Identification of Hydrothermal Aquifer Zone using Geo-Electrical Method in Kaloling Sinjai District

    Directory of Open Access Journals (Sweden)

    Lantu L

    2015-12-01

    Full Text Available Geothermal energy is one of the natural resources which  emerged on the subsurface ofthe earth can be in a gaseous form (the vapor heat or in the form of hydrothermal. The geothermal Panggo that located at watersheds of Kalamisu river, was one of the three sources of hydrothermal system  existing in district Sinjai East. The existence of the geothermal system in this area will much give many advantagest if managed optimally. This research aims to map the spread of the hydrothermal aquifer zone at the subsurface and it potentials in Panggo village base on electrical properties. Methods used in this research were geo-electrical using Wenner and Schlumberger configurations.At all these research area, it is found the presence of zones which has low resistivity (< 20 Ωm, and it is interpreted as the spread of hydrothermal zones. The hydrothermal system appears at subsurface allegedly caused by the geological fault of Kalamisu across this region.

  8. Mineral equilibria and zircon, garnet and titanite U-Pb ages constraining the PTt path of granite-related hydrothermal systems at the Big Bell gold deposit, Western Australia

    Science.gov (United States)

    Mueller, Andreas G.; McNaughton, Neal J.

    2018-01-01

    The Big Bell deposit (75 t gold) is located in a narrow spur of the Meekatharra greenstone belt, Yilgarn Craton, Western Australia. Two ore bodies are located in a calcic-potassic contact alteration zone overprinting lineated granodiorite dykes and amphibolite: almandine-cummingtonite-hornblende skarn (1-3 g/t Au, 1700 g/t As, 330 g/t W) and the muscovite-microcline gneiss (3-5 g/t Au, 580 g/t Sb, 620 g/t W) of the Main Lode. Genetic models vary from pre- to post-metamorphic replacement. Hornblende-plagioclase pairs in amphibolite constrain peak metamorphic temperature to 670 ± 50 °C. In contrast, garnet-biotite thermometry provides estimates of 578 ± 50 and 608 ± 50 °C for garnet-cordierite-biotite schist bordering the skarn and enveloping the Main Lode. Garnet-cordierite and garnet-hornblende pairs extend the range of fluid temperature to 540 ± 65 °C, well below peak metamorphic temperature. At 540-600 °C, the alteration assemblage andalusite + sillimanite constrains pressure to 300-400 MPa corresponding to 11-14 km crustal depth. Published U-Pb ages indicate that metamorphism took place in the aureole of the southeast granodiorite-tonalite batholith (2740-2700 Ma), followed by gold mineralization at 2662 ± 5 Ma and by the emplacement of biotite granite and Sn-Ta-Nb granite-pegmatite dykes at 2625-2610 Ma. Amphibolite xenoliths in granite northwest of the deposit record the lowest temperature (628 ± 50 °C), suggesting it lacks a metamorphic aureole. The rare metal dykes are spatially associated with epidote-albite and andradite-diopside skarns (≤1.5 g/t Au), mined where enriched in the weathered zone. We analysed hydrothermal zircon intergrown with andradite. Concordant U-Pb ages of 2612 ± 7 and 2609 ± 10 Ma confirm the presence of a second granite-related system. The zircons display oscillatory zoning and have low Th/U ratios (0.05-0.08). Low-Th titanite from an albite granite dyke has a concordant but reset U-Pb age of 2577 ± 7 Ma.

  9. [Interactions between larvae of the hoverfly Eristalinus sepulchralis and microorganisms in the hydrothermal springs of the Uzon caldera, Kamchatka].

    Science.gov (United States)

    Lobkova, L E; Barinova, E S; Dulov, L E; Gal'chenko, V F

    2007-01-01

    The physicochemical and microbial characteristics of some medium-temperature hydrotherms of Kamchatka Peninsula (Uzon caldera), habitats of the hoverfly Eristalinus sepulchralis larvae, were studied. In these hydrothermal vents, the larvae were found to use various prokaryotic and eukaryotic microorganisms as a nutrient substrate. The rates of chemo- and photosynthetic activity of the suspended microbial communities inhabiting the hydrotherms and supporting the existence of larvae were measured. By light and electron microscopy, exo- and endosymbiotic prokaryotic microorganisms were revealed in the digestive and respiratory systems of larvae.

  10. Phreatic activity and hydrothermal alteration in the Valley of Desolation, Dominica, Lesser Antilles

    Science.gov (United States)

    Mayer, Klaus; Scheu, Bettina; Yilmaz, Tim I.; Montanaro, Cristian; Albert Gilg, H.; Rott, Stefanie; Joseph, Erouscilla P.; Dingwell, Donald B.

    2017-12-01

    potential for pressurization in the subsurface and thus lead to phreatic eruptions. Rapid decompression experiments, together with ballistic trajectory calculations, constrain estimates of the conditions prior to the 1997 small-scale phreatic event in the VoD. The results presented here may serve as a contribution to the understanding of the hazard potential of ongoing hydrothermal activity within the VoD. On a broader perspective, our results will help evaluate hydrothermal activity in similar areas worldwide which might also have the potential for phreatic eruptions, for instance Poas (Costa Rica) or Tongariro and Waimangu (New Zealand).

  11. Ultrasonic transducer for the hydrothermal method

    Energy Technology Data Exchange (ETDEWEB)

    Bornmann, Peter; Hemsel, Tobias [University of Paderborn, Paderborn (Germany); Littmann, Walter [ATHENA Technologie Beratung GmbH, Paderborn (Germany); Ageba, Ryo; Kadota, Yoishi; Morita, Takeshi [University of Tokyo, Kashiwa (Japan)

    2010-10-15

    Direct ultrasound irradiation is advantageous for increasing the efficiency of the hydrothermal method, which can be used to produce piezoelectric thin films and lead-free piezoelectric ceramics. To apply ultrasound directly to the process, transducer prototypes were developed regarding the boundary conditions of the hydrothermal method. LiNbO{sub 3} and PIC 181 were proven to be feasible materials for high-temperature-resistant transducers ({>=} 200 .deg. C). The resistance of the transducer's horn against a corrosive mineralizer was achieved by using Hastelloy C-22. The efficiency of the ultrasound-assisted hydrothermal method depends on the generated sound field.The impedance and the sound field measurements have shown that the sound field depends on the filling level and on the position and design of the transducer.

  12. Characterization of advanced preprocessed materials (Hydrothermal)

    Energy Technology Data Exchange (ETDEWEB)

    Rachel Emerson; Garold Gresham

    2012-09-01

    The initial hydrothermal treatment parameters did not achieve the proposed objective of this effort; the reduction of intrinsic ash in the corn stover. However, liquid fractions from the 170°C treatments was indicative that some of the elements routinely found in the ash that negatively impact the biochemical conversion processes had been removed. After reviewing other options for facilitating ash removal, sodium-citrate (chelating agent) was included in the hydrothermal treatment process, resulting in a 69% reduction in the physiological ash. These results indicated that chelation –hydrothermal treatment is one possible approach that can be utilized to reduce the overall ash content of feedstock materials and having a positive impact on conversion performance.

  13. Prebiotic Synthesis of Glycine from Ethanolamine in Simulated Archean Alkaline Hydrothermal Vents

    Science.gov (United States)

    Zhang, Xianlong; Tian, Ge; Gao, Jing; Han, Mei; Su, Rui; Wang, Yanxiang; Feng, Shouhua

    2017-12-01

    Submarine hydrothermal vents are generally considered as the likely habitats for the origin and evolution of early life on Earth. In recent years, a novel hydrothermal system in Archean subseafloor has been proposed. In this model, highly alkaline and high temperature hydrothermal fluids were generated in basalt-hosted hydrothermal vents, where H2 and CO2 could be abundantly provided. These extreme conditions could have played an irreplaceable role in the early evolution of life. Nevertheless, sufficient information has not yet been obtained for the abiotic synthesis of amino acids, which are indispensable components of life, at high temperature and alkaline condition. This study aims to propose a new method for the synthesis of glycine in simulated Archean submarine alkaline vent systems. We investigated the formation of glycine from ethanolamine under conditions of high temperature (80-160 °C) and highly alkaline solutions (pH = 9.70). Experiments were performed in an anaerobic environment under mild pressure (0.1-8.0 MPa) at the same time. The results suggested that the formation of glycine from ethanolamine occurred rapidly and efficiently in the presence of metal powders, and was favored by high temperatures and high pressures. The experiment provides a new pathway for prebiotic glycine formation and points out the phenomenal influence of high-temperature alkaline hydrothermal vents in origin of life in the early ocean.

  14. Hydrothermal monitoring in a quiescent volcanic arc: Cascade Range, northwestern United States

    Science.gov (United States)

    Ingebritsen, S.E.; Randolph-Flagg, N. G.; Gelwick, K.D.; Lundstrom, E.A.; Crankshaw, I.M.; Murveit, A.M.; Schmidt, M.E.; Bergfeld, D.; Spicer, K.R.; Tucker, D.S.; Mariner, R.H.; Evans, William C.

    2014-01-01

    Ongoing (1996–present) volcanic unrest near South Sister, Oregon, is accompanied by a striking set of hydrothermal anomalies, including elevated temperatures, elevated major ion concentrations, and 3He/4He ratios as large as 8.6 RA in slightly thermal springs. These observations prompted the US Geological Survey to begin a systematic hydrothermal-monitoring effort encompassing 25 sites and 10 of the highest-risk volcanoes in the Cascade volcanic arc, from Mount Baker near the Canadian border to Lassen Peak in northern California. A concerted effort was made to develop hourly, multiyear records of temperature and/or hydrothermal solute flux, suitable for retrospective comparison with other continuous geophysical monitoring data. Targets included summit fumarole groups and springs/streams that show clear evidence of magmatic influence in the form of high 3He/4He ratios and/or anomalous fluxes of magmatic CO2 or heat. As of 2009–2012, summit fumarole temperatures in the Cascade Range were generally near or below the local pure water boiling point; the maximum observed superheat was 3 during periods of hourly record. Hydrothermal responses to these small seismic stimuli were generally undetectable or ambiguous. Evaluation of multiyear to multidecadal trends indicates that whereas the hydrothermal system at Mount St. Helens is still fast-evolving in response to the 1980–present eruptive cycle, there is no clear evidence of ongoing long-term trends in hydrothermal activity at other Cascade Range volcanoes that have been active or restless during the past century (Baker, South Sister, and Lassen). Experience gained during the Cascade Range hydrothermal-monitoring experiment informs ongoing efforts to capture entire unrest cycles at more active but generally less accessible volcanoes such as those in the Aleutian arc.

  15. Recognition of Prior Learning: The Participants' Perspective

    Science.gov (United States)

    Miguel, Marta C.; Ornelas, José H.; Maroco, João P.

    2016-01-01

    The current narrative on lifelong learning goes beyond formal education and training, including learning at work, in the family and in the community. Recognition of prior learning is a process of evaluation of those skills and knowledge acquired through life experience, allowing them to be formally recognized by the qualification systems. It is a…

  16. The prior statistics of object colors

    NARCIS (Netherlands)

    Koenderink, J.J.

    2010-01-01

    The prior statistics of object colors is of much interest because extensive statistical investigations of reflectance spectra reveal highly non-uniform structure in color space common to several very different databases. This common structure is due to the visual system rather than to the statistics

  17. Hydrothermal Synthesis of Nanostructured Vanadium Oxides

    Directory of Open Access Journals (Sweden)

    Jacques Livage

    2010-08-01

    Full Text Available A wide range of vanadium oxides have been obtained via the hydrothermal treatment of aqueous V(V solutions. They exhibit a large variety of nanostructures ranging from molecular clusters to 1D and 2D layered compounds. Nanotubes are obtained via a self-rolling process while amazing morphologies such as nano-spheres, nano-flowers and even nano-urchins are formed via the self-assembling of nano-particles. This paper provides some correlation between the molecular structure of precursors in the solution and the nanostructure of the solid phases obtained by hydrothermal treatment.

  18. Forecasting Electricity Prices in an Optimization Hydrothermal Problem

    Science.gov (United States)

    Matías, J. M.; Bayón, L.; Suárez, P.; Argüelles, A.; Taboada, J.

    2007-12-01

    This paper presents an economic dispatch algorithm in a hydrothermal system within the framework of a competitive and deregulated electricity market. The optimization problem of one firm is described, whose objective function can be defined as its profit maximization. Since next-day price forecasting is an aspect crucial, this paper proposes an efficient yet highly accurate next-day price new forecasting method using a functional time series approach trying to exploit the daily seasonal structure of the series of prices. For the optimization problem, an optimal control technique is applied and Pontryagin's theorem is employed.

  19. Hydrothermal analysis in engineering using control volume finite element method

    CERN Document Server

    Sheikholeslami, Mohsen

    2015-01-01

    Control volume finite element methods (CVFEM) bridge the gap between finite difference and finite element methods, using the advantages of both methods for simulation of multi-physics problems in complex geometries. In Hydrothermal Analysis in Engineering Using Control Volume Finite Element Method, CVFEM is covered in detail and applied to key areas of thermal engineering. Examples, exercises, and extensive references are used to show the use of the technique to model key engineering problems such as heat transfer in nanofluids (to enhance performance and compactness of energy systems),

  20. Multiperiod hydrothermal economic dispatch by an interior point method

    Directory of Open Access Journals (Sweden)

    Kimball L. M.

    2002-01-01

    Full Text Available This paper presents an interior point algorithm to solve the multiperiod hydrothermal economic dispatch (HTED. The multiperiod HTED is a large scale nonlinear programming problem. Various optimization methods have been applied to the multiperiod HTED, but most neglect important network characteristics or require decomposition into thermal and hydro subproblems. The algorithm described here exploits the special bordered block diagonal structure and sparsity of the Newton system for the first order necessary conditions to result in a fast efficient algorithm that can account for all network aspects. Applying this new algorithm challenges a conventional method for the use of available hydro resources known as the peak shaving heuristic.

  1. Dissolved gases in hydrothermal plumes from Artic vent fields

    OpenAIRE

    Stensland, Anne

    2013-01-01

    Recent discoveries of active vent fields on slow and ultraslow spreading ridges have revealed that hydrothermal activity is more common than previously assumed. In the Norwegian-Greenland Sea, two such vent fields are found; the Jan Mayen vent fields (71°N and 6°E) and Loki`s Castle (73°30′N and 8°E). Both these systems are located on the ultraslow spreading Mohns Ridge, but they differ profoundly in the geochemical fluid and gas composition. This study presen...

  2. Diffuse flow environments within basalt- and sediment-based hydrothermal vent ecosystems harbor specialized microbial communities

    Directory of Open Access Journals (Sweden)

    Barbara J Campbell

    2013-07-01

    Full Text Available Hydrothermal vents differ both in surface input and subsurface geochemistry. The effects of these differences on their microbial communities are not clear. Here, we investigated both alpha and beta diversity of diffuse flow-associated microbial communities emanating from vents at a basalt-based hydrothermal system along the East Pacific Rise (EPR and a sediment-based hydrothermal system, Guaymas Basin. Both Bacteria and Archaea were targeted using high throughput 16S rRNA gene pyrosequencing analyses. A novel aspect of this study was the use of a universal set of 16S rRNA gene primers to characterize total and diffuse flow-specific microbial communities from varied deep-sea hydrothermal environments. Both surrounding seawater and diffuse flow water samples contained large numbers of Marine Group I (MGI Thaumarchaea and Gammaproteobacteria taxa previously observed in deep sea systems. However, these taxa were geographically distinct and segregated according to type of spreading center. Diffuse flow microbial community profiles were highly differentiated. In particular, EPR dominant diffuse-flow taxa were most closely associated with chemolithoautotrophs and off axis water were dominated by heterotrophic-related taxa, where the opposite was true for Guaymas basin. The diversity and richness of diffuse flow specific microbial communities were strongly correlated to the relative abundance of Epsilonproteobacteria, proximity to macrofauna, and hydrothermal system type. Archaeal diversity was higher than or equivalent to bacterial diversity in about one third of the samples. Most diffuse flow-specific communities were dominated by OTUs associated with Epsilonproteobacteria, but many of the Guaymas Basin diffuse flow samples were dominated by either OTUs within the Planctomycetes or hyperthermophilic Archaea. This study emphasizes the unique microbial communities associated with geochemically and geographically distinct hydrothermal diffuse flow

  3. A hydrogeological conceptual model of the Suio hydrothermal area (central Italy)

    Science.gov (United States)

    Saroli, Michele; Lancia, Michele; Albano, Matteo; Casale, Anna; Giovinco, Gaspare; Petitta, Marco; Zarlenga, Francesco; dell'Isola, Marco

    2017-09-01

    A hydrogeological conceptual model has been developed that describes the hydrothermal system of Suio Terme (central Italy). The studied area is located along the peri-Tyrrhenian zone of the central Apennines, between the Mesozoic and Cenozoic carbonate platform sequences of the Aurunci Mountains and the volcanic sequences of the Roccamonfina. A multi-disciplinary approach was followed, using new hydrogeological surveys, the interpretation of stratigraphic logs of boreholes and water wells, and geophysical data—seismic sections, shear-wave velocity (Vs) crustal model and gravimetric model. The collected information allowed for construction of a conceptual hydrogeological model and characterization of the hydrothermal system. The Suio hydrothermal system is strongly influenced by the Eastern Aurunci hydrostructure. Along the southeastern side, the top of the hydrostructure sinks to -1,000 m relative to sea level via a series of normal faults which give origin to the Garigliano graben. Geological and hydrogeological data strongly suggest the propagation and mixing of hot fluids, with cold waters coming from the shallow karst circuit. The aquitard distribution, the normal tectonic displacements and the fracturing of the karst hydrostructure strongly influence the hydrothermal basin. Carbon dioxide and other gasses play a key role in the whole circuit, facilitating the development of the hydrothermal system. The current level of knowledge suggests that the origin of the Suio hydrothermalism is the result of interaction between the carbonate reservoir of the Eastern Aurunci Mountains and the hot and deep crust of this peri-Tyrrhenian sector, where the Roccamonfina volcano represents the shallowest expression.

  4. ESR dating of submarine hydrothermal activities using barite in sulfide deposition

    Science.gov (United States)

    Toyoda, S.; Fujiwara, T.; Ishibashi, J.; Isono, Y.; Uchida, A.; Takamasa, A.; Nakai, S.

    2012-12-01

    The temporal change of submarine hydrothermal activities has been an important issue in the aspect of the evolution of hydrothermal systems which is related with ore formation (Urabe, 1995) and biological systems sustained by the chemical species arising from hydrothermal activities (Macdonald et al., 1980). Determining the ages of the hydrothermal deposit will provide essential information on such studies. Dating methods using disequilibrium between radioisotopes such as U-Th method (e.g. You and Bickle, 1998), 226}Ra-{210Pb and 228}Ra-{228Th method (e.g. Noguchi et al., 2011) have been applied to date submarine hydrothermal deposits. ESR (electron spin resonance) dating method is commonly applied to fossil teeth, shells, and quartz of Quaternay period where the natural accumulated dose is obtained from the intensities of the ESR signals which are created by natural radiation. The natural dose is divided by the dose rate to the mineral/sample to deduce the age. Okumura et al., (2010) made the first practical application of ESR (electron spin resonance) dating technique to a sample of submarine hydrothermal barite (BaSO4) to obtain preliminary ages, where Kasuya et al. (1991) first pointed out that barite can be used for ESR dating. Knowing that ESR dating of barite is promising, in this paper, we will present how we have investigated each factor that contributes ESR dating of barite in submarine hydrothermal sulfide deposition. (1) The best ESR condition for measuring the SO3- signal in barite is with the microwave power of 1mW and modulation amplitude of 0.1mT. (2) As results of heating experiments, the signal was found to be stable for the dating age range of several thousands. (3) 226Ra replacing Ba in barite is the source of the radiation. The amount of radioactive elements in sulfide mineral surrounding barite is negligible. (4) The external radiation from the sea water is negligible even in the submarine hydrothermal area where the radiation level is much

  5. The chemistry of hydrothermal magnetite: a review

    Science.gov (United States)

    Nadoll, Patrick; Angerer, Thomas; Mauk, Jeffrey L.; French, David; Walshe, John

    2014-01-01

    Magnetite (Fe3O4) is a well-recognized petrogenetic indicator and is a common accessory mineral in many ore deposits and their host rocks. Recent years have seen an increased interest in the use of hydrothermal magnetite for provenance studies and as a pathfinder for mineral exploration. A number of studies have investigated how specific formation conditions are reflected in the composition of the respective magnetite. Two fundamental questions underlie these efforts — (i) How can the composition of igneous and, more importantly, hydrothermal magnetite be used to discriminate mineralized areas from barren host rocks, and (ii) how can this assist exploration geologists to target ore deposits at greater and greater distances from the main mineralization? Similar to igneous magnetite, the most important factors that govern compositional variations in hydrothermal magnetite are (A) temperature, (B) fluid composition — element availability, (C) oxygen and sulfur fugacity, (D) silicate and sulfide activity, (E) host rock buffering, (F) re-equilibration processes, and (G) intrinsic crystallographic controls such as ionic radius and charge balance. We discuss how specific formation conditions are reflected in the composition of magnetite and review studies that investigate the chemistry of hydrothermal and igneous magnetite from various mineral deposits and their host rocks. Furthermore, we discuss the redox-related alteration of magnetite (martitization and mushketovitization) and mineral inclusions in magnetite and their effect on chemical analyses. Our database includes published and previously unpublished magnetite minor and trace element data for magnetite from (1) banded iron formations (BIF) and related high-grade iron ore deposits in Western Australia, India, and Brazil, (2) Ag–Pb–Zn veins of the Coeur d'Alene district, United States, (3) porphyry Cu–(Au)–(Mo) deposits and associated (4) calcic and magnesian skarn deposits in the southwestern United

  6. Catalytic hydrothermal gasification of biomass for the production of synthetic natural gas[Dissertation 17100

    Energy Technology Data Exchange (ETDEWEB)

    Waldner, M. H.

    2007-07-01

    Energy from biomass is a CO{sub 2} neutral, sustainable form of energy. Anaerobic digestion is an established technology for converting biomass to biogas, which contains around 60% methane, besides CO{sub 2} and various contaminants. Most types of biomass contain material that cannot be digested; in woody biomass, this portion is particularly high. Therefore, conventional anaerobic digestion is not suited for the production of biogas from woody biomass. While wood is already being converted to energy by conventional thermal methods (gasification with subsequent methanation), dung, manure, and sewage sludge represent types of biomass whose energy potential remains largely untapped (present energetic use of manure in Switzerland: 0.4%). Conventional gas phase processes suffer from a low efficiency due to the high water content of the feed (enthalpy of vaporization). An alternative technology is the hydrothermal gasification: the water contained within the biomass serves as reaction medium, which at high pressures of around 30 MPa turns into a supercritical fluid that exhibits apolar properties. Under these conditions, tar precursors, which cause significant problems in conventional gasification, can be solubilized and gasified. The need to dry the biomass prior to gasification is obsolete, and as a consequence high thermal process efficiencies (65 - 70%) are possible. Due to their low solubility in supercritical water, the inorganics that are present in the biomass (up to 20 wt % of the dry matter of manure) can be separated and further used as fertilizer. The biomass is thus not only converted into an energy carrier, but it allows valuable substances contained in the biomass to be extracted and re-used. Furthermore, the process can be used for aqueous waste stream destruction. The aim of this project at the Paul Scherrer Institute was to develop a catalytic process that demonstrates the gasification of wet biomass to synthetic natural gas (SNG) in a continuously

  7. Hydrothermal commercialization baseline for state of Wyoming

    Energy Technology Data Exchange (ETDEWEB)

    Hanny, J.A.; Lunis, B.C. [eds.

    1979-06-01

    Wyoming does have numerous hot springs; but there has been little development effort in geothermal energy, since the state's primary interests are in coal, gas and oil. The hot springs of Thermopolis are among the largest in the world. Recent data from the central portion of the state indicate the potential for electric power generation from geothermal energy. Oil and gas wells (about 70,000) have been drilled in the state and some have geothermal waters that can be utilized for direct applications. The Madison Aquifer extends into the northeastern quadrant of the state and offers considerable potential for geothermal energy. Leasing activity is very limited. Geothermal legislation is basically non-existent, but the State Engineer has the responsibility for protecting the thermal springs. This handbook provides a synopsis of various aspects of the geothermal program in Wyoming. The section on Basic State Data (Section 2) lists government personnel (both legislative and executive branches) who are most directly involved with geothermal development. Some basic demographic data are also included. The various hydrothermal resources and the pertinent geology are summarized in Section 3. Activities (ranging from leases to operational systems) that lead to commercialization are described in Section 4. Plans for various developments are summarized in Section 5, while government assistance to Wyoming projects is list4ed in Section 6. The section on energy use patterns (Section 7) summarizes existing energy use and identifies counties and industries likely to be impacted most by geothermal energy. The section on leasing and permitting policies (Section 8) deals with legal and institutional considerations and includes a time table of institutional procedures for a typical resource to show the interrelationships among various organizations involved in development and regulation of the resource.

  8. Mobility of rare earth element in hydrothermal process and weathering product: a review

    Science.gov (United States)

    Lintjewas, L.; Setiawan, I.

    2018-02-01

    The Rare Earth Element (REE), consists of La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Lu, Ho, Er, Tm, Yb, are important elements to be used as raw materials of advanced technology such as semiconductors, magnets, and lasers. The research of REE in Indonesia has not been done. Several researches were conducted on granitic rocks and weathering product such as Bangka, Sibolga, West Kalimantan, West Sulawesi and Papua. REE can be formed by hydrothermal processes such as Bayan Obo, South China. The REE study on active hydrothermal system (geothermal) in this case also has the potential to produce mineral deposits. The purpose of this review paper is to know the mobility of REE on hydrothermal process and weathering products. Mobility of REE in the hydrothermal process can change the distribution patterns and REE content such as Ce, Eu, La, Lu, Nd, Sm, and Y. Another process besides the hydrothermal is weathering process. REE mobility is influenced by weathering products, where the REE will experience residual and secondary enrichment processes in heavier minerals.

  9. Hydrothermal Liquefaction of the Microalgae Phaeodactylum tricornutum

    DEFF Research Database (Denmark)

    Sigaard Christensen, Per; Peng, Gaël; Vogel, Frédéric

    2014-01-01

    The microalgae Phaeodactylum tricornutum was processed by hydrothermal liquefaction in order to assess the influence of reaction temperature and reaction time on the product and elemental distribution. The experiments were carried out at different reaction times (5 and 15 min) and over a wide range...

  10. Hydrothermal synthesis, crystal structure and luminescence property ...

    Indian Academy of Sciences (India)

    Hydrothermal synthesis, crystal structure and luminescence property of a three dimensional Sm(III) coordination polymer with. 2,5-pyridinedicarboxylic acid. KRANTHI KUMAR GANGU, ANIMA S DADHICH and. SARATCHANDRA BABU MUKKAMALA. ∗. Department of Chemistry, GITAM University, Visakhapatnam 530 045, ...

  11. Hydrothermal synthesis, crystal structure and luminescence property ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 127; Issue 12. Hydrothermal synthesis, crystal structure and luminescence property of a three dimensional Sm(III) coordination polymer with 2,5-pyridinedicarboxylic acid. Kranthi Kumar Gangu Anima S Dadhich Saratchandra Babu Mukkamala. Volume 127 Issue 12 ...

  12. Hydroprocessing Microalgae Derived Hydrothermal Liquefaction Bio ...

    African Journals Online (AJOL)

    Bio-crude, a biomass derived oil similar to petroleum crude in properties, can be produced from microalgae via hydrothermal liquefaction (HTL) and upgraded to ... for hydroprocessing the bio-crude; the products obtainable, their compositions & properties; as well as the inputs required for modelling and simulation of the ...

  13. Valorization of Furfural Residue by Hydrothermal Carbonization

    DEFF Research Database (Denmark)

    Yue, Fen; Zhang, Jia; Pedersen, Christian Marcus

    2017-01-01

    Furfural residue (FR) is a low-cost by-product generated in the furfural production from corncobs, which is mainly composed of cellulose and lignin. In this report, hydrothermal carbonization (HTC) of deashed FR was conducted at various reaction temperatures (200, 220 and 240 °C) and reaction tim...

  14. Hydrothermal synthesis and characterisation of BIS (4 ...

    African Journals Online (AJOL)

    ... of Infrared and UV- visible spectroscopy. The complexes show broad band absorption in the region 3760 – 3765.71 cm-1 due to the symmetric stretching vibration of the co-ordinated water molecule. Keywords: Hydrothermal reaction, metalloligand, parahydroxybenzaldehyde, para-phenylenediamine, zinc phosphate.

  15. Phase Transformation of Hydrothermally Synthesized Nanoparticle ...

    African Journals Online (AJOL)

    Mild hydrothermal hydrolysis of TiCl4 produces nanorods of the rutile phase of titanium dioxide in high yield, while in the presence of organic acids (citric, acetic, D-tartaric and benzoic acids) anatase is the only product. The effect of these organic acids on the products of the hydrolysis reaction as well as the reaction kinetics ...

  16. Hydrothermal synthesis, structure and characterization of new ...

    Indian Academy of Sciences (India)

    Unknown

    The structure has tunnel-type cavities and are congenial for ion transportation through them. The compound exhibits moderate thermal stability. Keywords. Hydrothermal; crystal structure; solid electrolyte; iron (III) pyrophosphate. 1. Introduction. NASICON and related compounds belong to the well known family of solid ...

  17. HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF A ...

    African Journals Online (AJOL)

    Preferred Customer

    HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF A BINUCLEAR. COMPLEX AND A COORDINATION POLYMER OF COPPER(II). Masoumeh Tabatabaee1*, Reza Mohamadinasab1, Kazem Ghaini1 and Hamid Reza Khavasi2. 1Department of Chemistry, Islamic Azad University, Yazd Branch, Yazd, Iran.

  18. Direct hydrothermal synthesis of metal intercalated hexagonal ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 115; Issue 5-6. Direct hydrothermal synthesis of metal intercalated hexagonal molybdates, M x + Mo 6 − x / 3 O 18 − x (OH) x . y H2O (M = Li, Rb, Cs, NH4). S Upreti A Ramanan. Volume 115 Issue 5-6 October-December 2003 pp 411-417 ...

  19. Hydrothermal synthesis and electrochemical properties of a ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 128; Issue 5. Hydrothermal synthesis and electrochemical properties of a coordination polymer based on dinuclear (Pyrazinyl tetrazolate) Copper(II) cations and βOctamolybdate Anions. SHAOBIN LI LI ZHANG HUIYUAN MA HAIJUN PANG. Regular Article Volume ...

  20. Inclusion of environmental costs on a long-term expansion model of hydrothermal generation systems; Insercao dos custos ambientais em um modelo de expansao da geracao a longo prazo

    Energy Technology Data Exchange (ETDEWEB)

    Santos Henrique Luz

    2008-02-15

    This dissertation presents the development of a mathematical model to be used in the hydrothermal generation expansion planning taking into account uncertainties, the guarantee of energy supply and issues related to the social and environmental problems caused by the power sector. Named 'MELP Ambiental', it is a version of MELP, a model developed by Machado Junior (2000). The environmental valuation was based on results of previous studies. The analysis of the environmental costs scenarios showed that the inclusion of a variable linked to externalities implies in changes on the investment schedule. These changes decrease the total cost (economic and environmental) related to long-term power supply expansion. (author)

  1. Weathering of post-impact hydrothermal deposits from the Haughton impact structure: implications for microbial colonization and biosignature preservation.

    Science.gov (United States)

    Izawa, M R M; Banerjee, Neil R; Osinski, G R; Flemming, R L; Parnell, J; Cockell, C S

    2011-01-01

    Meteorite impacts are among the very few processes common to all planetary bodies with solid surfaces. Among the effects of impact on water-bearing targets is the formation of post-impact hydrothermal systems and associated mineral deposits. The Haughton impact structure (Devon Island, Nunavut, Canada, 75.2 °N, 89.5 °W) hosts a variety of hydrothermal mineral deposits that preserve assemblages of primary hydrothermal minerals commonly associated with secondary oxidative/hydrous weathering products. Hydrothermal mineral deposits at Haughton include intra-breccia calcite-marcasite vugs, small intra-breccia calcite or quartz vugs, intra-breccia gypsum megacryst vugs, hydrothermal pipe structures and associated surface "gossans," banded Fe-oxyhydroxide deposits, and calcite and quartz veins and coatings in shattered target rocks. Of particular importance are sulfide-rich deposits and their associated assemblage of weathering products. Hydrothermal mineral assemblages were characterized structurally, texturally, and geochemically with X-ray diffraction, micro X-ray diffraction, optical and electron microscopy, and inductively coupled plasma atomic emission spectroscopy. Primary sulfides (marcasite and pyrite) are commonly associated with alteration minerals, including jarosite (K,Na,H(3)O)Fe(3)(SO(4))(2)(OH)(6), rozenite FeSO(4)·4(H(2)O), copiapite (Fe,Mg)Fe(4)(SO(4))(6)(OH)(2)·20(H(2)O), fibroferrite Fe(SO(4))(OH)·5(H(2)O), melanterite FeSO(4)·7(H(2)O), szomolnokite FeSO(4)·H(2)O, goethite α-FeO(OH), lepidocrocite γ-FeO(OH) and ferrihydrite Fe(2)O(3)·0.5(H(2)O). These alteration assemblages are consistent with geochemical conditions that were locally very different from the predominantly circumneutral, carbonate-buffered environment at Haughton. Mineral assemblages associated with primary hydrothermal activity, and the weathering products of such deposits, provide constraints on possible microbial activity in the post-impact environment. The initial period of

  2. Geomicrobiology of Hydrothermal Vents in Yellowstone Lake: Phylogenetic and Functional Analysis suggest Importance of Geochemistry (Invited)

    Science.gov (United States)

    Inskeep, W. P.; Macur, R.; Jay, Z.; Clingenpeel, S.; Tenney, A.; Lavalvo, D.; Shanks, W. C.; McDermott, T.; Kan, J.; Gorby, Y.; Morgan, L. A.; Yooseph, S.; Varley, J.; Nealson, K.

    2010-12-01

    Yellowstone Lake (Yellowstone National Park, WY, USA) is a large, high-altitude, fresh-water lake that straddles the most recent Yellowstone caldera, and is situated on top of significant hydrothermal activity. An interdisciplinary study is underway to evaluate the geochemical and geomicrobiological characteristics of several hydrothermal vent environments sampled using a remotely operated vehicle, and to determine the degree to which these vents may influence the biology of this young freshwater ecosystem. Approximately six different vent systems (locations) were sampled during 2007 and 2008, and included water obtained directly from the hydrothermal vents as well as biomass and sediment associated with these high-temperature environments. Thorough geochemical analysis of these hydrothermal environments reveals variation in pH, sulfide, hydrogen and other potential electron donors that may drive primary productivity. The concentrations of dissolved hydrogen and sulfide were extremely high in numerous vents sampled, especially the deeper (30-50 m) vents located in the Inflated Plain, West Thumb, and Mary Bay. Significant dilution of hydrothermal fluids occurs due to mixing with surrounding lake water. Despite this, the temperatures observed in many of these hydrothermal vents range from 50-90 C, and elevated concentrations of constituents typically associated with geothermal activity in Yellowstone are observed in waters sampled directly from vent discharge. Microorganisms associated with elemental sulfur mats and filamentous ‘streamer’ communities of Inflated Plain and West Thumb (pH range 5-6) were dominated by members of the deeply-rooted bacterial Order Aquificales, but also contain thermophilic members of the domain Archaea. Assembly of metagenome sequence from the Inflated Plain vent biomass and to a lesser extent, West Thumb vent biomass reveal the importance of Sulfurihydrogenibium-like organisms, also important in numerous terrestrial geothermal

  3. Characteristics of hydrothermal eruptions, with examples from New Zealand and elsewhere

    Science.gov (United States)

    Browne, P. R. L.; Lawless, J. V.

    2001-02-01

    Hydrothermal eruptions have occurred in many hot water geothermal fields. This paper concentrates on examples from New Zealand but also mentions others elsewhere, which demonstrate points of particular interest. Numerous small eruptions (maximum focal depths of about 90 m) have occurred in historic times (past 150 years) at Wairakei/Tauhara, Rotorua, Tikitere, Ngatamariki, Mokai and Waimangu. The presence of breccia deposits shows that much larger (with estimated maximum focal depths of about 450 m), prehistoric hydrothermal eruptions have also occurred at Kawerau, Wairakei, Tikitere, Orakeikorako, Te Kopia, Rotokawa and Waiotapu. One of the largest known hydrothermal eruptions in New Zealand took place at Rotokawa 6060±60 years ago; this produced a deposit that extended over an area with a diameter of 4 km, and has a maximum thickness of 11 m. Deposits from hydrothermal eruptions are typically very poorly sorted, matrix-supported, and may contain hydrothermally altered clasts that derive from within the geothermal reservoir. Their lithologies and alteration mineralogies are useful guides to subsurface conditions. Hydrothermal eruptions do not require any direct input of either mass or energy derived directly from a magma and, thus, differ from both phreatic and phreatomagmatic eruptions. Many hydrothermal eruptions in a hot water field start very close to the ground surface and result from the rapid formation of steam due to a sudden pressure reduction. This steam provides the energy necessary to brecciate, lift and eject fragments of the host rocks as a flashing front descends and water nearby in the reservoir boils. A rock brecciation zone accompanies this front, and both precede the descent of the eruption surface. A hydrothermal eruption continues until the steam is produced too slowly to lift the brecciated rocks. There is no genetic difference between the small eruptions induced by exploitation and those which occur as a geothermal system evolves naturally

  4. Novel molecular fossils of bacteria: insights into hydrothermal origin of life.

    Science.gov (United States)

    Dai, Jianghong

    2012-10-07

    Hydrothermal vents, in particular, alkaline submarine vents, are potential systems for the origin of life. Early hydrothermal vents may have imprinted on biochemical processes and housekeeping proteins of life and have hallmarked key molecules. This essay introduces new information to this discussion by focusing on newly identified sulfur-modified DNA and a heretofore ignored anhydro bond of the cell wall peptidoglycan in bacteria. It is suggested that they are novel molecular fossils that are relevant to the settings of alkaline submarine vents and harbor clues of early life. As DNA and the cell wall are bound up with genetic information and the integrity of cell, respectively, these two molecular fossils may provide insights into hydrothermal origin of life from a new angle. Copyright © 2012 Elsevier Ltd. All rights reserved.

  5. Layered double hydroxide using hydrothermal treatment: morphology evolution, intercalation and release kinetics of diclofenac sodium

    Science.gov (United States)

    Joy, Mathew; Iyengar, Srividhya J.; Chakraborty, Jui; Ghosh, Swapankumar

    2017-11-01

    The present work demonstrates the possibilities of hydrothermal transformation of Zn-Al layered double hydroxide (LDH) nanostructure by varying the synthetic conditions. The manipulation in washing step before hydrothermal treatment allows control over crystal morphologies, size and stability of their aqueous solutions. We examined the crystal growth process in the presence and the absence of extra ions during hydrothermal treatment and its dependence on the drug (diclofenac sodium (Dic-Na)) loading and release processes. Hexagonal plate-like crystals show sustained release with ˜90% of the drug from the matrix in a week, suggesting the applicability of LDH nanohybrids in sustained drug delivery systems. The fits to the release kinetics data indicated the drug release as a diffusion-controlled release process. LDH with rod-like morphology shows excellent colloidal stability in aqueous suspension, as studied by photon correlation spectroscopy.

  6. The Outer Planets and their Moons Comparative Studies of the Outer Planets prior to the Exploration of the Saturn System by Cassini-Huygens

    CERN Document Server

    Encrenaz, T; Owen, T. C; Sotin, C

    2005-01-01

    This volume gives an integrated summary of the science related to the four giant planets in our solar system. It is the result of an ISSI workshop on «A comparative study of the outer planets before the exploration of Saturn by Cassini-Huygens» which was held at ISSI in Bern on January 12-16, 2004. Representatives of several scientific communities, such as planetary scientists, astronomers, space physicists, chemists and astrobiologists have met with the aim to review the knowledge on four major themes: (1) the study of the formation and evolution processes of the outer planets and their satellites, beginning with the formation of compounds and planetesimals in the solar nebula, and the subsequent evolution of the interiors of the outer planets, (2) a comparative study of the atmospheres of the outer planets and Titan, (3) the study of the planetary magnetospheres and their interactions with the solar wind, and (4) the formation and properties of satellites and rings, including their interiors, surfaces, an...

  7. Poultry blood from slaughterhouses: development of a biopreservation system to improve microbiological quality prior to transforming blood into by-products.

    Science.gov (United States)

    Zbrun, M V; Frizzo, L S; Soto, L P; Rosmini, M R; Sequeira, G J; Astesana, D M; Blajman, J E; Rossler, E; Berisvil, A; Romero Scharpen, A; Signorini, M L

    2016-10-01

    The aim of this study was to investigate the use of indigenous lactic acid bacteria (LAB) with specific additives as a Biopreservation System (BS) for poultry blood during its storage in slaughterhouses. The BS consisted of two LAB (Enterococcus faecalis DSPV 008SA or Lactobacillus salivarius DSPV 032SA) with 4 additives (lactose 2 g/l, yeast extract 0.4 g/l, ammonium citrate 0.4 g/l and NaCl 1 g/l). After 24 h storage at 30ºC, lower counts of enterobacteria, coliforms, Pseudomonas spp. and Staphylococcus aureus were evident in blood treated with the BS than in untreated blood. The ability of LAB to prevent haemolysis was evident. A decrease in pH was associated with control of spoilage microorganisms but it needed to be regulated to prevent coagulation of proteins. On the basis of these results it is recommended to supplement blood with a BS to avoid undesirable changes during blood storage before processing.

  8. Using noble gases measured in spring discharge to trace hydrothermal processes in the Norris Geyser Basin, Yellowstone National Park, U.S.A.

    Science.gov (United States)

    Gardner, W.P.; Susong, D.D.; Solomon, D.K.; Heasler, H.P.

    2010-01-01

    Dissolved noble gas concentrations in springs are used to investigate boiling of hydrothermal water and mixing of hydrothermal and shallow cool water in the Norris Geyser Basin area. Noble gas concentrations in water are modeled for single stage and continuous steam removal. Limitations on boiling using noble gas concentrations are then used to estimate the isotopic effect of boiling on hydrothermal water, allowing the isotopic composition of the parent hydrothermal water to be determined from that measured in spring. In neutral chloride springs of the Norris Geyser Basin, steam loss since the last addition of noble gas charged water is less than 30% of the total hydrothermal discharge, which results in an isotopic shift due to boiling of ?? 2.5% ??D. Noble gas concentrations in water rapidly and predictably change in dual phase systems, making them invaluable tracers of gas-liquid interaction in hydrothermal systems. By combining traditional tracers of hydrothermal flow such as deuterium with dissolved noble gas measurements, more complex hydrothermal processes can be interpreted. ?? 2010 Elsevier B.V.

  9. Application of Algae as Cosubstrate To Enhance the Processability of Willow Wood for Continuous Hydrothermal Liquefaction

    DEFF Research Database (Denmark)

    Sintamarean, Iulia-Maria; Pedersen, Thomas Helmer; Zhao, Xueli

    2017-01-01

    This work proposes a novel strategy to improve the continuous processing of wood slurries in hydrothermal liquefaction systems by coprocessing with algae. Of all algae tested, brown seaweeds and microalgae perform best in preventing slurries dewatering, the main reason for pumpability issues...... with wood slurries. Rheological tests (viscosity–shear rate profile) indicate that the addition of these two algae to the wood slurry causes the highest increase in viscosity, which coincides with improved wood slurries stability and pumpability. Hydrothermal liquefaction of wood-algae slurries at 400 °C...

  10. Constraints on mineralisation and hydrothermal alteration in the Nalunaq gold deposit, South Greenland

    DEFF Research Database (Denmark)

    Bell, Robin-Marie Fairbairn

    Summary: Nalunaq is located in South Greenland and is a small high gold-grade deposit, which for the majority of its operational life was Greenland's only metalliferous mine. Gold is hosted in narrow quartz veins which are cross-cut by late-stage faults. Gold-quartz veins are hosted by fine......-and - medium grained amphibolite of the Nanortalik Nappe. Detailed petrographic and geochronological studies have revealed a multi-stage hydrothermal alteration system, with alteration pre-and post-dating gold mineralisation. The hydrothermal alteration records a transition from upper-amphibolite facies...

  11. Coupled Iron and Sulfur Transformations in Hydrothermal Springs

    Science.gov (United States)

    Boyd, E. S.; Amenabar, M.; Roden, E. E.

    2014-12-01

    Iron (Fe) and sulfur (S) compounds are common constituents of terrestrial hydrothermal systems. The transformation of Fe and S compounds is inferred to be an ancient mechanism of energy conservation that is still represented in extant life inhabiting contemporary hydrothermal environments. While substantial research has been conducted to uncover the ability of microorganisms to couple Fe and S transformations with other biogeochemical cycles (e.g., H, O, C cycles) in hydrothermal environments, few studies have focused on the interplay between the Fe and S cycles. In particular, a paucity of studies has been conducted on this phenomenon in acidic high temperature ecosystems despite the common co-occurrence of Fe and S in these environments. Here, we report the isolation and physiological characterization of a metabolically diverse thermoacidiphilic and autotrophic archaeon from an acidic hot spring environment in Yellowstone National Park (YNP) that is capable of both direct and indirect coupling of the Fe and S cycles. Growth experiments indicate differential attachment requirements depending on the mode of growth and imply the importance of intermediate sulfur species in supporting its metabolism. Genomic analyses confirm the metabolic plasticity of this strain and suggest numerous other mechanisms by which this organism may exploit other geochemical cycles during Fe or S dependent growth. Cultivation and cultivation independent approaches suggest that the distribution of this archaeon is widespread in Fe and S rich hot spring environments in YNP and is likely a keystone population in these environments, responsible for a large proportion of primary productivity. These results underscore the utility of integrating geochemical, cultivation, physiological, and genomic approaches in understanding biogeochemical cycling in volcanic environments.

  12. Climate change in a hydrothermal-thermohaline framework

    Science.gov (United States)

    Aldama Campino, Aitor; Döös, Kristofer

    2017-04-01

    In this study, the response of the oceanic thermohaline circulation and the atmospheric hydrothermal circulation to a future climate change scenario are compared to the present climate. We will use stream functions based on purely thermodynamic coordinates to represent the atmospheric and oceanic circulation in one single representation. The oceanic thermohaline stream function makes it possible to analyse and quantify the entire world-ocean conversion rate between cold/warm and fresh/saline waters. The hydrothermal stream function, the analogous circulation in the atmosphere, captures the conversion rate between cold/warm and dry/humid air. The two stream functions have been computed from data from the Earth System Model EC-Earth. For the future climate change scenario the Representative Concentration Pathway (RCP) 8.5 was selected. The effects of the anthropogenic climate change is analysed in this study comparing the difference between the last 10 years of the historical simulation (1996-2005) to the RCP 8.5 simulation (2090-2100). Both circulations are compared on the same diagram by scaling the axes. The salinity axis of the ocean circulation is scaled by the equivalent latent heat energy required to move an air parcel on the moisture axis in the atmospheric circulation. In the future scenario, the atmospheric and oceanic circulation show a weakening and widening a of the stream function. The circulation expands both in the temperature space and in the humidity space for the atmosphere (salinity for the ocean). These results leads us to propose that the Clausius-Clapeyron relationship guides not only the moist branch of the hydrothermal circulation but also the warming branches of the thermohaline circulation both in the present climate and in a future scenario.

  13. Hydrothermal Processing of Macroalgal Feedstocks in Continuous-Flow Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Roesijadi, Guri; Zacher, Alan H.; Magnuson, Jon K.

    2014-02-03

    Wet macroalgal slurries have been converted into a biocrude by hydrothermal liquefaction (HTL) in a bench-scale continuous-flow reactor system. Carbon conversion to a gravity-separable oil product of 58.8% was accomplished at relatively low temperature (350 °C) in a pressurized (subcritical liquid water) environment (20 MPa) when using feedstock slurries with a 21.7% concentration of dry solids. As opposed to earlier work in batch reactors reported by others, direct oil recovery was achieved without the use of a solvent, and biomass trace mineral components were removed by processing steps so that they did not cause processing difficulties. In addition, catalytic hydrothermal gasification (CHG) was effectively applied for HTL byproduct water cleanup and fuel gas production from water-soluble organics. Conversion of 99.2% of the carbon left in the aqueous phase was demonstrated. Finally, as a result, high conversion of macroalgae to liquid and gas fuel products was found with low levels of residual organic contamination in byproduct water. Both process steps were accomplished in continuous-flow reactor systems such that design data for process scale-up was generated.

  14. Cool seafloor hydrothermal springs reveal global geochemical fluxes

    Science.gov (United States)

    Wheat, C. Geoffrey; Fisher, Andrew T.; McManus, James; Hulme, Samuel M.; Orcutt, Beth N.

    2017-10-01

    We present geochemical data from the first samples of spring fluids from Dorado Outcrop, a basaltic edifice on 23 M.y. old seafloor of the Cocos Plate, eastern Pacific Ocean. These samples were collected from the discharge of a cool hydrothermal system (CHS) on a ridge flank, where typical reaction temperatures in the volcanic crust are low (2-20 °C) and fluid residence times are short. Ridge-flank hydrothermal systems extract 25% of Earth's lithospheric heat, with a global discharge rate equivalent to that of Earth's river discharge to the ocean; CHSs comprise a significant fraction of this global flow. Upper crustal temperatures around Dorado Outcrop are ∼15 °C, the calculated residence time is concentrations in spring fluids are indistinguishable from those of bottom seawater; however, concentrations of Rb, Mo, V, U, Mg, phosphate, Si and Li are different. Applying these observed differences to calculated global CHS fluxes results in chemical fluxes for these ions that are ≥15% of riverine fluxes. Fluxes of K and B also may be significant, but better analytical resolution is required to confirm this result. Spring fluids also have ∼50% less dissolved oxygen (DO) than bottom seawater. Calculations of an analytical model suggest that the loss of DO occurs primarily (>80%) within the upper basaltic crust by biotic and/or abiotic consumption. This calculation demonstrates that permeable pathways within the upper crust can support oxic water-rock interactions for millions of years.

  15. Hydrothermal Liquefaction of Dried Distillers Grains with solubles: A reaction temperature study

    DEFF Research Database (Denmark)

    Mørup, Anders; Christensen, Per Runge; Aarup, David Friis

    2012-01-01

    The effect of the reaction temperature on hydrothermal liquefaction of dried distillers grains with solubles (DDGS) was investigated using a novel stop-flow reactor system at varying temperatures (300–400 °C), fixed pressure (250 bar), and fixed reaction time (15 min). The stop-flow reactor...

  16. Production of Advanced Biofuels via Liquefaction - Hydrothermal Liquefaction Reactor Design: April 5, 2013

    Energy Technology Data Exchange (ETDEWEB)

    Knorr, D.; Lukas, J.; Schoen, P.

    2013-11-01

    This report provides detailed reactor designs and capital costs, and operating cost estimates for the hydrothermal liquefaction reactor system, used for biomass-to-biofuels conversion, under development at Pacific Northwest National Laboratory. Five cases were developed and the costs associated with all cases ranged from $22 MM/year - $47 MM/year.

  17. Modeling mid-ocean ridge hydrothermal response to earthquakes, tides, and ocean currents: a case study at the Grotto mound, Endeavour Segment, Juan de Fuca Ridge

    Science.gov (United States)

    Xu, G.; Bemis, K. G.

    2014-12-01

    Seafloor hydrothermal systems feature intricate interconnections among oceanic, geological, hydrothermal, and biological processes. The advent of the NEPTUNE observatory operated by Ocean Networks Canada at the Endeavour Segment, Juan de Fuca Ridge enables scientists to study these interconnections through multidisciplinary, continuous, real-time observations. The multidisciplinary observatory instruments deployed at the Grotto Mound, a major study site of the NEPTUNE observatory, makes it a perfect place to study the response of a seafloor hydrothermal system to geological and oceanic processes. In this study, we use the multidisciplinary datasets recorded by the NEPTUNE Observatory instruments as observational tools to demonstrate two different aspects of the response of hydrothermal activity at the Grotto Mound to geological and oceanic processes. First, we investigate a recent increase in venting temperature and heat flux at Grotto observed by the Benthic and Resistivity Sensors (BARS) and the Cabled Observatory Vent Imaging Sonar (COVIS) respectively. This event started in Mar 2014 and is still evolving by the time of writing this abstract. An initial interpretation in light of the seismic data recorded by a neighboring ocean bottom seismometer on the NEPTUNE observatory suggests the temperature and heat flux increase is probably triggered by local seismic activities. Comparison of the observations with the results of a 1-D mathematical model simulation of hydrothermal sub-seafloor circulation elucidates the potential mechanisms underlying hydrothermal response to local earthquakes. Second, we observe significant tidal oscillations in the venting temperature time series recorded by BARS and the acoustic imaging of hydrothermal plumes by COVIS, which is evidence for hydrothermal response to ocean tides and currents. We interpret the tidal oscillations of venting temperature as a result of tidal loading on a poroelastic medium. We then invoke poroelastic

  18. The origin of life in alkaline hydrothermal vents

    Science.gov (United States)

    Sojo, V.; Herschy, B.; Whicher, A.; Camprubí, E.; Lane, N.

    2016-12-01

    The origin of life remains one of Science's greatest unresolved questions. The answer will no doubt involve almost all the basic disciplines, including Physics, Chemistry, Astronomy, Geology, and Biology. Chiefly, it is the link between the latter two that must be elucidated: how geochemistry gave rise to biochemistry. Serpentinizing systems such as alkaline hydrothermal vents offer the most robust combination of conditions to have hosted the origin of life on the early Earth, while bearing many parallels to modern living cells. Stark gradients of concentration, pH, oxidation/reduction, and temperature provided the ability to synthesise and concentrate organic products, drive polymerisation reactions, and develop an autotrophic lifestyle independent of foreign sources of organics. In the oxygen-depleted waters of the Hadean, alkaline vents would have acted as electrochemical flow reactors, in which alkaline fluids saturated in H2 mixed with the relatively acidic CO2-rich waters of the ocean, through interconnected micropores made of thin inorganic walls containing catalytic Fe(Ni)S minerals. Perhaps not coincidentally, the unit cells of these Fe(Ni)S minerals closely resemble the active sites of crucial ancestral bioenergetic enzymes. Meanwhile, differences in pH across the thin barriers produced natural proton gradients similar to those used for carbon fixation in modern archaea and bacteria. At the earliest stages, the problem of the origin of life is the problem of the origin of carbon fixation. I will discuss work over the last decade that suggests several possible hypotheses for how simple one-carbon molecules could have given rise to more complex organics, particularly within a serpentinizing alkaline hydrothermal vent. I will discuss the perplexing differences in carbon and energy metabolism in methanogenic archaea and acetogenic bacteria, thought to be the earliest representatives of each domain, to propose a possible ancestral mechanism of CO2 reduction in

  19. Integrated analysis of hydrothermal flow through pretreatment

    Directory of Open Access Journals (Sweden)

    Archambault-Leger Veronique

    2012-07-01

    Full Text Available Abstract Background The impact of hydrothermal flowthrough (FT pretreatment severity on pretreatment and solubilization performance metrics was evaluated for three milled feedstocks (corn stover, bagasse, and poplar and two conversion systems (simultaneous saccharification and fermentation using yeast and fungal cellulase, and fermentation by Clostridium thermocellum. Results Compared to batch pretreatment, FT pretreatment consistently resulted in higher XMG recovery, higher removal of non-carbohydrate carbon and higher glucan solubilization by simultaneous saccharification and fermentation (SSF. XMG recovery was above 90% for FT pretreatment below 4.1 severity but decreased at higher severities, particularly for bagasse. Removal of non-carbohydrate carbon during FT pretreatment increased from 65% at low severity to 80% at high severity for corn stover, and from 40% to 70% for bagasse and poplar. Solids obtained by FT pretreatment were amenable to high conversion for all of the feedstocks and conversion systems examined. The optimal time and temperature for FT pretreatment on poplar were found to be 16 min and 210°C. At these conditions, SSF glucan conversion was about 85%, 94% of the XMG was removed, and 62% of the non carbohydrate mass was solubilized. Solubilization of FT-pretreated poplar was compared for C. thermocellum fermentation (10% inoculum, and for yeast-fungal cellulase SSF (5% inoculum, cellulase loading of 5 and 10 FPU/g glucan supplemented with β-glucosidase at 15 and 30 U/g glucan. Under the conditions tested, which featured low solids concentration, C. thermocellum fermentation achieved faster rates and more complete conversion of FT-pretreated poplar than did SSF. Compared to SSF, solubilization by C. thermocellum was 30% higher after 4 days, and was over twice as fast on ball-milled FT-pretreated poplar. Conclusions XMG removal trends were similar between feedstocks whereas glucan conversion trends were significantly

  20. The hydrothermal outflow plume of Valles Caldera, New Mexico, and a comparison with other outflow plumes

    Science.gov (United States)

    Goff, Fraser; Shevenell, Lisa; Gardner, Jamie N.; Vuataz, Francois-D.; Grigsby, Charles O.

    1988-06-01

    Stratigraphic, temperature gradient, hydrogeochemical, and hydrologic data have been integrated with geologic data from previous studies to show the structural configuration of the Valles caldera hydrothermal ouflow plume. Hydrologic data suggest that 25-50% of the discharge of the Valles outflow is confined to the Jemez fault zone, which predates caldera formation. Thermal gradient data from bores penetrating the plume show that shallow gradients are highest in the vicinity of the Jemez fault zone (up to 190°C/km). Shallow heat flow above the hydrothermal plume is as high as 500 mW m-2 near core hole VC-1 (Jemez fault zone) to 200 mW m-2 at Fenton Hill (Jemez Plateau). Chemical and isotopic data indicate that two source reservoirs within the caldera (Redondo Creek and Sulphur Springs reservoirs) are parents to mixed fluids flowing in the hydrothermal plume. However, isotopic data, borehole data, basic geology, and inverse relations between temperature and chloride content at major hot springs indicate that no single reservoir fluid and no single diluting fluid are involved in mixing. The Valles caldera hydrothermal plume is structurally dominated by lateral flow through a belt of vertical conduits (Jemez fault zone) that strike away from the source reservoir. Stratigraphically confined flow is present but dispersed over a wide area in relatively impermeable rocks. The Valles configuration is contrasted with the configuration of the hydrothermal plume at Roosevelt Hot Springs, which is dominated by lateral flow through a near-surface, widespread, permeable aquifer. Data from 12 other representative geothermal systems show that outflow plumes occur in a variety of magmatic and tectonic settings, have varying reservoir compositions, and have different flow characteristics. Although temperature reversals are commonly observed in wells penetrating outflow plumes, reversals are not observed in all plumes. Less information is available on the absolute age of

  1. Volcanic and Hydrothermal Activity of the North Su Volcano: New Insights from Repeated Bathymetric Surveys and ROV Observations

    Science.gov (United States)

    Thal, J.; Bach, W.; Tivey, M.; Yoerger, D.

    2013-12-01

    Bathymetric data from cruises in 2002, 2006, and 2011 were combined and compared to determine the evolution of volcanic activity, seafloor structures, erosional features and to identify and document the distribution of hydrothermal vents on North Su volcano, SuSu Knolls, eastern Manus Basin (Papua New Guinea). Geologic mapping based on ROV observations from 2006 (WHOI Jason-2) and 2011 (MARUM Quest-4000) combined with repeated bathymetric surveys from 2002 and 2011 are used to identify morphologic features on the slopes of North Su and to track temporal changes. ROV MARUM Quest-4000 bathymetry was used to develop a 10 m grid of the top of North Su to precisely depict recent changes. In 2006, the south slope of North Su was steeply sloped and featured numerous white smoker vents discharging acid sulfate waters. These vents were covered by several tens of meters of sand- to gravel-sized volcanic material in 2011. The growth of this new cone changed the bathymetry of the south flank of North Su up to ~50 m and emplaced ~0.014 km3 of clastic volcanic material. This material is primarily comprised of fractured altered dacite and massive fresh dacite as well as crystals of opx, cpx, olivine and plagioclase. There is no evidence for pyroclastic fragmentation, so we hypothesize that the fragmentation is likely related to hydrothermal explosions. Hydrothermal activity varies over a short (~50 m) lateral distance from 'flashing' black smokers to acidic white smoker vents. Within 2 weeks of observation time in 2011, the white smoker vents varied markedly in activity suggesting a highly episodic hydrothermal system. Based on ROV video recordings, we identified steeply sloping (up to 30°) slopes exposing pillars and walls of hydrothermal cemented volcaniclastic material representing former fluid upflow zones. These features show that hydrothermal activity has increased slope stability as hydrothermal cementation has prevented slope collapse. Additionally, in some places

  2. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, Mary J.; Davis, Ryan; Jones, Susanne B.; Zhu, Yunhua

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  3. Resistivity methods in exploration for hydrothermal resources

    Energy Technology Data Exchange (ETDEWEB)

    Jiracek, G.R.; Ruscetta, C.A.; Foley, D. (eds.)

    1981-05-01

    The practical aspects of using dc resistivity in the exploration for hydrothermal resources are discussed. There are several reasons why low electrical resistivity is expected in hydrothermal aquifers but the association is not without pit falls. Besides outlining the reasons why resistivity has proven a successful geothermal exploration tool, a section on how resistivity is practiced is included. Here, the common electrode arrays are considered with their major advantages and disadvantages pointed out. The current status in resistivity interpretation schemes is touched upon with emphasis on computer modeling. Finally, a successful resistivity case history of a low-temperature resource at Las Alturas Estates, New Mexico is included to illustrate a specific resistivity exploration philosophy. The case history concludes with drilling results which are, of course, the ultimate test.

  4. On the early fate of hydrothermal iron at deep-sea vents: A reassessment after in situ filtration

    Science.gov (United States)

    Waeles, M.; Cotte, L.; Pernet-Coudrier, B.; Chavagnac, V.; Cathalot, C.; Leleu, T.; Laës-Huon, A.; Perhirin, A.; Riso, R. D.; Sarradin, P.-M.

    2017-05-01

    Deep-sea hydrothermal venting is now recognized as a major source of iron (Fe), an essential trace element that controls marine productivity. However, the reactions occurring during dispersal from buoyant plumes to neutrally buoyant hydrothermal plumes are still poorly constrained. Here we report for the first time on the dissolved-particulate partition of Fe after in situ filtration at the early stage of mixing at different hydrothermal discharges, i.e., Lucky Strike (37°N), TAG (26°N), and Snakepit (23°N) on the Mid-Atlantic Ridge. We found that hydrothermal iron is almost completely preserved (>90%) in the dissolved fraction, arguing for low iron-bearing sulfide precipitation of iron in basalt-hosted systems with low Fe:H2S ratios. This result can only be explained by a kinetically limited formation of pyrite. The small part of Fe being precipitated as sulfides in the mixing gradient (<10%) is restricted to the inclusion of Fe in minerals of high Cu and Zn content. We also show that secondary venting is a source of Fe-depleted hydrothermal solutions. These results provide new constrains on Fe fluxes from hydrothermal venting.

  5. Quantum steganography using prior entanglement

    Energy Technology Data Exchange (ETDEWEB)

    Mihara, Takashi, E-mail: mihara@toyo.jp

    2015-06-05

    Steganography is the hiding of secret information within innocent-looking information (e.g., text, audio, image, video, etc.). A quantum version of steganography is a method based on quantum physics. In this paper, we propose quantum steganography by combining quantum error-correcting codes with prior entanglement. In many steganographic techniques, embedding secret messages in error-correcting codes may cause damage to them if the embedded part is corrupted. However, our proposed steganography can separately create secret messages and the content of cover messages. The intrinsic form of the cover message does not have to be modified for embedding secret messages. - Highlights: • Our steganography combines quantum error-correcting codes with prior entanglement. • Our steganography can separately create secret messages and the content of cover messages. • Errors in cover messages do not have affect the recovery of secret messages. • We embed a secret message in the Steane code as an example of our steganography.

  6. Migration depth and residence time of juvenile salmonids in the forebays of hydropower dams prior to passage through turbines or juvenile bypass systems: implications for turbine-passage survival.

    Science.gov (United States)

    Li, Xinya; Deng, Zhiqun D; Brown, Richard S; Fu, Tao; Martinez, Jayson J; McMichael, Geoffrey A; Skalski, John R; Townsend, Richard L; Trumbo, Bradly A; Ahmann, Martin L; Renholds, Jon F

    2015-01-01

    Little is known about the three-dimensional depth distributions in rivers of individually marked fish that are in close proximity to hydropower facilities. Knowledge of the depth distributions of fish approaching dams can be used to understand how vulnerable fish are to injuries such as barotrauma as they pass through dams. To predict the possibility of barotrauma injury caused by pressure changes during turbine passage, it is necessary to understand fish behaviour relative to acclimation depth in dam forebays as they approach turbines. A guiding study was conducted using high-resolution three-dimensional tracking results of salmonids implanted with Juvenile Salmon Acoustic Telemetry System transmitters to investigate the depth distributions of subyearling and yearling Chinook salmon (Oncorhynchus tshawytscha) and juvenile steelhead (Oncorhynchus mykiss) passing two dams on the Snake River in Washington State. Multiple approaches were evaluated to describe the depth at which fish were acclimated, and statistical analyses were performed on large data sets extracted from ∼28 000 individually tagged fish during 2012 and 2013. Our study identified patterns of depth distributions of juvenile salmonids in forebays prior to passage through turbines or juvenile bypass systems. This research indicates that the median depth at which juvenile salmonids approached turbines ranged from 2.8 to 12.2 m, with the depths varying by species/life history, year, location (which dam) and diel period (between day and night). One of the most enlightening findings was the difference in dam passage associated with the diel period. The amount of time that turbine-passed fish spent in the immediate forebay prior to entering the powerhouse was much lower during the night than during the day. This research will allow scientists to understand turbine-passage survival better and enable them to assess more accurately the effects of dam passage on juvenile salmon survival.

  7. Rare Earth Element Compositions of Chlorite-rich Hydrothermal Sediments in the middle Okinawa Trough, East China Sea

    Science.gov (United States)

    Shao, H.; Yang, S.; Humphris, S. E.; Cai, D.; Wang, Q.

    2015-12-01

    Rare earth elements (REEs) have been used as powerful tracers in the study of hot fluid-rock reaction in hydrothermal system. However, the behavior of the REEs during interaction of hydrothermal solution with rocks remains to be clarified more quantitatively. The Okinawa Trough (OT), located in the East Asian continental margin, is characterized by thick terrigenous sediment and ubiquitous volcanic-hydrothermal activities. In this study, the sediments collected during IODP Expedition 331 to the mid-OT were determined for mineralogical and REEs as well as Nd isotopic compositions, aiming to investigate the geochemical behavior of REEs during hydrothermal processes. All samples were separated into bulk and clay-size (˂ 2 μm) fractions and pretreated by 1N HCl to remove carbonate and other unstable components. The hydrothermal sediments in the mid-OT is dominated by Mg-rich chlorite based on the XRD analysis, especially the clay-size fraction comprising pure chlorite. The clay-size samples bear different mineralogical and geochemical compositions between the upper and lower parts in this hydrothermal area. All hydrothermal samples are relatively enriched in HREEs in the residues. The upper clays have higher values of δEu and (La/Yb)N as well as LREEs concentration than the lower part, while the bulk samples have weak REE differentiation. In the 1N HCl leachates, the concentrations of REEs in the bulk samples are higher than in the clays in the lower part but LREEs are obviously enriched in the upper clays. We infer that the grain size may be an important factor controlling the behavior of REEs in the mid-OT hydrothermal system. Both bulk and clay samples show negative Eu anomalies relative to chondrite, similar as the detrital sediments and volcanic rocks. This study confirms the hypothesis that HREEs patterns are constant throughout the system compatible with higher LREEs mobility as chlorine ion complexes in acidic solutions (Mills and Elderfield 1995; Douville

  8. Experimentally Testing Hydrothermal Vent Origin of Life on Enceladus and Other Icy/Ocean Worlds.

    Science.gov (United States)

    Barge, Laura M; White, Lauren M

    2017-09-01

    We review various laboratory strategies and methods that can be utilized to simulate prebiotic processes and origin of life in hydrothermal vent systems on icy/ocean worlds. Crucial steps that could be simulated in the laboratory include simulations of water-rock chemistry (e.g., serpentinization) to produce hydrothermal fluids, the types of mineral catalysts and energy gradients produced in vent interfaces where hydrothermal fluids interface with the surrounding seawater, and simulations of biologically relevant chemistry in flow-through gradient systems (i.e., far-from-equilibrium experiments). We describe some examples of experimental designs in detail, which are adaptable and could be used to test particular hypotheses about ocean world energetics or mineral/organic chemistry. Enceladus among the ocean worlds provides an ideal test case, since the pressure at the ocean floor is more easily simulated in the lab. Results for Enceladus could be extrapolated with further experiments and modeling to understand other ocean worlds. Key Words: Enceladus-Ocean worlds-Icy worlds-Hydrothermal vent-Iron sulfide-Gradient. Astrobiology 17, 820-833.

  9. Evolutionary strategies of viruses, bacteria and archaea in hydrothermal vent ecosystems revealed through metagenomics.

    Directory of Open Access Journals (Sweden)

    Rika E Anderson

    Full Text Available The deep-sea hydrothermal vent habitat hosts a diverse community of archaea and bacteria that withstand extreme fluctuations in environmental conditions. Abundant viruses in these systems, a high proportion of which are lysogenic, must also withstand these environmental extremes. Here, we explore the evolutionary strategies of both microorganisms and viruses in hydrothermal systems through comparative analysis of a cellular and viral metagenome, collected by size fractionation of high temperature fluids from a diffuse flow hydrothermal vent. We detected a high enrichment of mobile elements and proviruses in the cellular fraction relative to microorganisms in other environments. We observed a relatively high abundance of genes related to energy metabolism as well as cofactors and vitamins in the viral fraction compared to the cellular fraction, which suggest encoding of auxiliary metabolic genes on viral genomes. Moreover, the observation of stronger purifying selection in the viral versus cellular gene pool suggests viral strategies that promote prolonged host integration. Our results demonstrate that there is great potential for hydrothermal vent viruses to integrate into hosts, facilitate horizontal gene transfer, and express or transfer genes that manipulate the hosts' functional capabilities.

  10. Partitioning of F-Cl-OH between minerals and hydrothermal fluids

    Energy Technology Data Exchange (ETDEWEB)

    Chen Zhu; Sverjensky, D.A. (Johns Hopkins Univ., Baltimore, MD (United States))

    1991-07-01

    A thermodynamic analysis of F-Cl-OH partitioning between minerals and hydrothermal fluids has resulted in the retrieval of standard-state Gibbs free energies for fluormuscovite, fluorphlogopite, fluorannite, fluortremolite, fluortalc, hydroxyapatite, fluorapatite, chlorapatite, and chlorannite from hydrothermal experimental studies. Standard-state entropies, heat capacities, and volumes are either derived from experimental studies or estimated following HELGESON et al. (1978). The derived thermodynamic properties are internally consistent and consistent with the thermodynamic properties of minerals and aqueous species from BERMAN (1988,1990), SVERJENSKY et al. (1991a), SHOCK and HELGESON (1988), and SHOCK et al. (1989), and therefore can be extrapolated over a wide range of temperatures and pressures for application to geochemistry, igneous and metamorphic petrology, and ore deposits. The derived standard-state thermodynamic properties for F and Cl endmember phases provide a basis for predicting the fluoride and chloride concentrations of former aqueous fluids from the measured F and Cl concentrations in minerals. Speciation and solubility calculations simulating F and Cl partitioning between minerals and hydrothermal fluids, and systems containing apatites, show that the partitioning is a strong function of temperature, pressure, and fluid composition. The decrease of both pressure and pH of fluids favors partitioning of Cl into annite with respect to fluids. In addition to predicting fluoride and chloride concentrations in hydrothermal fluids, the results of this study enable mass transfer calculations including both F-Cl-OH partitioning and metal complexing of halides during water-rock interactions in a variety of geological systems.

  11. Macrofaunal ecology of sedimented hydrothermal vents in the Bransfield Strait, Antarctica

    Directory of Open Access Journals (Sweden)

    James Benjamin Bell

    2016-03-01

    Full Text Available Sedimented hydrothermal vents, where hot, mineral-rich water flows through sediment, are poorly understood globally, both in their distribution and the ecology of individual vent fields. We explored macrofaunal community ecology at a sediment-hosted hydrothermal vent in the Southern Ocean. This is the first such study of these ecosystems outside of the Pacific and the furthest south (62˚S of any vent system studied. Sedimentary fauna were sampled in four areas of the Bransfield Strait (Southern Ocean, with the aim of contrasting community structure between vent and non-vent sites. Macrofaunal assemblages were clearly distinct between vent and non-vent sites, and diversity, richness and density declined towards maximum hydrothermal activity. This variation is in contrast to observations from similar systems in the Pacific and demonstrates the influence of factors other than chemosynthetic primary productivity in structuring infauna at deep-sea vent communities. Vent endemic fauna had limited abundance and were represented by a single siboglinid species at hydrothermally active areas, meaning that that the majority of local biota were those also found in other areas. Several taxa occupied all sampling stations but there were large differences in their relative abundances, suggesting communities were structured by niche variation rather than dispersal ability.

  12. Characteristics and source of inorganic and organic compounds in the sediments from two hydrothermal fields of the Central Indian and Mid-Atlantic Ridges

    Science.gov (United States)

    Peng, Xiaotong; Li, Jiwei; Zhou, Huaiyang; Wu, Zijun; Li, Jiangtao; Chen, Shun; Yao, Huiqiang

    2011-05-01

    A combined inorganic and organic geochemical study was carried out on sediments collected from the Kairei hydrothermal field on the Central Indian Ridge (CIR) and the Logatchev hydrothermal field on the Mid Atlantic Ridge (MAR). Analysis of the major and trace elements as well as the minerals shows that the Kairei hydrothermal sediments are formed by the mixing of silica-rich hydrothermal fluids with Mg-rich seawaters, but the Logatchev sediments are associated with pelagic carbonate oozes containing some precipitates derived from hydrothermal plume fall-out. The rare earth element (REE) patterns of Kairei sediments show a character of light REE (LREE) enrichment and positive Eu anomaly, whereas two of the three Logatchev sediment samples lack positive Eu anomaly and have negative Ce anomaly. Patterns of aliphatic hydrocarbon fractions in the sediments from both hydrothermal fields exhibit high relative concentrations of volatile resolved components, smooth n-alkane distributions and high concentrations of the isoprenoids pristane and phytane. The composition of organic matter and C isotope composition of individual n-alkanes indicate that they come from marine photosynthetic autotrophs and hydrothermal organisms, as well as terrestrial inputs in the Kairei and the Logatchev hydrothermal fields. Several parameters of organic geochemistry, used for assessing the maturity of bitumen, are well correlated with one another. In general, these parameters indicate that the Kairei sediments are more mature than the Logatchev sediments. The relationship between the inorganic parameters (REE/Fe and Eu/Eu ∗) and the organic parameter (bitumen maturity) might reflect changes of the hydrothermal influence on the sediments. The results of this study provide an insight into the variation of inorganic and organic geochemistry in deep-sea hydrothermal systems.

  13. Cuprous oxide thin films grown by hydrothermal electrochemical deposition technique

    Energy Technology Data Exchange (ETDEWEB)

    Majumder, M., E-mail: mousumi@cgcri.res.in; Biswas, I.; Pujaru, S.; Chakraborty, A.K.

    2015-08-31

    Semiconducting cuprous oxide films were grown by a hydrothermal electro-deposition technique on metal (Cu) and glass (ITO) substrates between 60 °C and 100 °C. X-ray diffraction studies reveal the formation of cubic cuprous oxide films in different preferred orientations depending upon the deposition technique used. Film growth, uniformity, grain size, optical band gap and photoelectrochemical response were found to improve in the hydrothermal electrochemical deposition technique. - Highlights: • Cu{sub 2}O thin films were grown on Cu and glass substrates. • Conventional and hydrothermal electrochemical deposition techniques were used. • Hydrothermal electrochemical growth showed improved morphology, thickness and optical band gap.

  14. Information Propagation in Prior-Image-Based Reconstruction.

    Science.gov (United States)

    Stayman, J Webster; Prince, Jerry L; Siewerdsen, Jeffrey H

    Advanced reconstruction methods for computed tomography include sophisticated forward models of the imaging system that capture the pertinent physical processes affecting the signal and noise in projection measurements. However, most do little to integrate prior knowledge of the subject - often relying only on very general notions of local smoothness or edges. In many cases, as in longitudinal surveillance or interventional imaging, a patient has undergone a sequence of studies prior to the current image acquisition that hold a wealth of prior information on patient-specific anatomy. While traditional techniques tend to treat each data acquisition as an isolated event and disregard such valuable patient-specific prior information, some reconstruction methods, such as PICCS[1] and PIR-PLE[2], can incorporate prior images into a reconstruction objective function. Inclusion of such information allows for dramatic reduction in the data fidelity requirements and more robustly accommodate substantial undersampling and exposure reduction with consequent benefits to imaging speed and reduced radiation dose. While such prior-image-based methods offer tremendous promise, the introduction of prior information in the reconstruction raises significant concern regarding the accurate representation of features in the image and whether those features arise from the current data acquisition or from the prior images. In this work we propose a novel framework to analyze the propagation of information in prior-image-based reconstruction by decomposing the estimation into distinct components supported by the current data acquisition and by the prior image. This decomposition quantifies the contributions from prior and current data as a spatial map and can trace specific features in the image to their source. Such "information source maps" can potentially be used as a check on confidence that a given image feature arises from the current data or from the prior and to more quantitatively

  15. Laboratory simulated hydrothermal alteration of sedimentary organic matter from Guaymas Basin, Gulf of California. Ph.D. Thesis

    Science.gov (United States)

    Leif, Roald N.

    1993-01-01

    High temperature alteration of sedimentary organic matter associated with marine hydrothermal systems involves complex physical and chemical processes that are not easily measured in most natural systems. Many of these processes can be evaluated indirectly by examining the geochemistry of the hydrothermal system in the laboratory. In this investigation, an experimental organic geochemical approach to studying pyrolysis of sedimentary organic matter is applied to the hydrothermal system in the Guaymas Basin, Gulf of California. A general survey of hydrothermal oils and extractable organic matter (bitumen) in hydrothermally altered sediments identified several homologous series of alkanones associated with a high temperature hydrothermal origin. The alkanones range in carbon number from C11 to C30 with no carbon number preference. Alkan-2-ones are in highest concentrations, with lower amounts of 3-, 4-, 5- (and higher) homologs. The alkanones appear to be pyrolysis products synthesized under extreme hydrothermal conditions. Hydrous pyrolysis and confinement pyrolysis experiments were performed to simulate thermally enhanced diagenetic and catagenetic changes in the immature sedimentary organic matter. The extent of alteration was measured by monitoring the n-alkanes, acyclic isoprenoids, steroid and triterpenoid biomarkers, polycyclic aromatic hydrocarbons and alkanones. The results were compared to bitumen extracts from sediments which have been naturally altered by a sill intrusion and accompanied hydrothermal fluid flow. These pyrolysis experiments duplicated many of the organic matter transformations observed in the natural system. Full hopane and sterane maturation occurred after 48 hr in experiments at 330 deg C with low water/rock mass ratios (0.29). A variety of radical and ionic reactions are responsible for the organic compound conversions which occur under extreme hydrothermal conditions. Short duration pyrolysis experiments revealed that a portion of the

  16. Hydrothermal circulation in fast spread ocean crust - where and how much? Insight from ODP Hole 1256D

    Science.gov (United States)

    Harris, M.; Coggon, R. M.; Smith-Duque, C. E.; Teagle, D. A. H.

    2014-12-01

    Understanding and quantifying hydrothermal circulation is critical to testing models of the accretion of lower ocean crust and quantifying global geochemical cycles. However, our understanding is principally limited by a lack of direct observations from intact ocean crust. Key questions remain about the magnitude of hydrothermal fluid fluxes, the nature and distribution of fluid pathways and their global variability. ODP Hole 1256D in the eastern equatorial Pacific samples a complete section of 15 Myr old upper ocean crust down to the dike/gabbro transition zone. A high spatial resolution Sr isotope profile is integrated with wireline studies, volcanostratigraphy, petrography and mineral geochemistry to document fluid pathways and develop a model for the evolving hydrothermal system during volcanic construction of the crust. Major off-axis fluid conduits in the volcanic sequence are restricted to the flow margins of two anomalously thick (>25 m) massive flows, indicating that massive flows act as a permeability barrier for fluid flow. Dike margins are pathways for both recharge and discharge hydrothermal fluids. Sub-horizontal channeling of high temperature fluids at the dike/gabbro boundary is a common attribute of most cartoons of mid ocean ridge hydrothermal systems. Hole 1256D provides the first in situ observations of the dike/gabbro transition zone and records lateral fluid transport along intrusive boundaries. The time-integrated fluid flux in the sheeted dikes of Hole 1256D calculated using Sr isotope mass balance is ~1.8 x 106 kg/m2. This is similar to fluid fluxes from other studies (Hole 504B, Pito Deep, Hess Deep) despite large variations in the thickness and Sr isotope profiles of the sheeted dike complexes, suggesting that hydrothermal fluid fluxes are remarkably uniform and independent of the local structure of the crust. This fluid flux is not large enough to completely remove the heat flux from crystallizing and cooling the lower crust and requires

  17. IODP Expedition 331: Strong and Expansive Subseafloor Hydrothermal Activities in the Okinawa Trough

    Directory of Open Access Journals (Sweden)

    the IODP Expedition 331 Scientists

    2012-04-01

    Full Text Available Integrated Ocean Drilling Program (IODP Expedition 331 drilled into the Iheya North hydrothermal system in the middle Okinawa Trough in order to investigate active subseafloor microbial ecosystems and their physical and chemical settings. We drilled five sites during Expedition 331 using special guide bases at three holes for reentry, casing, and capping, including installation of a steel mesh platformwith valve controls for postcruise sampling of fluids. At Site C0016, drilling at the base of the North Big Chimney (NBCmound yielded low recovery, but core included the first Kuroko-type black ore ever recovered from the modern subseafloor. The other four sites yielded interbedded hemipelagic and strongly pumiceous volcaniclastic sediment, along with volcanogenic breccias that are variably hydrothermally altered and mineralized. At most sites, analyses of interstitial water and headspace gas yielded complex patterns withdepth and lateral distance of only a few meters. Documented processes included formation of brines and vapor-rich fluids by phase separation and segregation, uptake of Mg and Na by alteration minerals in exchange for Ca, leaching of K at high temperature and uptake at low temperature, anhydrite precipitation, potential microbial oxidation of organic matter and anaerobic oxidation of methane utilizing sulfate, and methanogenesis. Shipboard analyses have found evidence for microbial activity in sediments within the upper 10–30 m below seafloor (mbsf where temperatures were relativelylow, but little evidence in the deeper hydrothermally altered zones and hydrothermal fluid regime.

  18. Geologic field-trip guide to the volcanic and hydrothermal landscape of the Yellowstone Plateau

    Science.gov (United States)

    Morgan Morzel, Lisa Ann; Shanks, W. C. Pat; Lowenstern, Jacob B.; Farrell, Jamie M.; Robinson, Joel E.

    2017-11-20

    Yellowstone National Park, a nearly 9,000 km2 (~3,468 mi2) area, was preserved in 1872 as the world’s first national park for its unique, extraordinary, and magnificent natural features. Rimmed by a crescent of older mountainous terrain, Yellowstone National Park has at its core the Quaternary Yellowstone Plateau, an undulating landscape shaped by forces of late Cenozoic explosive and effusive volcanism, on-going tectonism, glaciation, and hydrothermal activity. The Yellowstone Caldera is the centerpiece of the Yellowstone Plateau. The Yellowstone Plateau lies at the most northeastern front of the 17-Ma Yellowstone hot spot track, one of the few places on Earth where time-transgressive processes on continental crust can be observed in the volcanic and tectonic (faulting and uplift) record at the rate and direction predicted by plate motion. Over six days, this field trip presents an intensive overview into volcanism, tectonism, and hydrothermal activity on the Yellowstone Plateau (fig. 1). Field stops are linked directly to conceptual models related to monitoring of the various volcanic, geochemical, hydrothermal, and tectonic aspects of the greater Yellowstone system. Recent interest in young and possible future volcanism at Yellowstone as well as new discoveries and synthesis of previous studies, (for example, tomographic, deformation, gas, aeromagnetic, bathymetric, and seismic surveys), provide a framework in which to discuss volcanic, hydrothermal, and seismic activity in this dynamic region.

  19. VentDB: A Global Online Synthesis Database of Seafloor Hydrothermal Spring Geochemistry

    Science.gov (United States)

    Mottl, M. J.; Lehnert, K. A.; Johansson, A. K.; Hsu, L.

    2011-12-01

    Chemical data for seafloor hydrothermal springs are fundamental to the study of mid-ocean ridge and seafloor processes, ocean water chemistry, and global geochemical cycles, as well as vent ecosystems and the sub-seafloor biosphere. So far, these data have been accessible only in the scientific literature or in online data catalogs where they are widely dispersed in individual data tables, and are often insufficiently documented for re-use. We have developed VentDB as an online data system for geochemical data for hydrothermal springs that will facilitate access and analysis of these data. VentDB uses the concept and architecture of the popular PetDB database for seafloor igneous and metamorphic rock geochemistry (www.petdb.org) to provide easy and fast access to a global synthesis of seafloor hydrothermal spring geochemical data. The VentDB database contains concentrations of major and trace species, dissolved gases, and radiogenic and isotopic ratios for hydrothermal vents on the seafloor. Further chemical or physical properties of hydrothermal springs can be included in the future if desired. The database comprises both the calculated hydrothermal end-member solution compositions as estimated by extrapolation of the concentrations of individual chemical species to a Mg concentration of zero, and the raw data for hydrothermal solution samples as collected, where available. Data quality is documented by including information for the raw analytical data about the analytical method, precision, and reference material measurements, and quality control parameters for end-member compositions including the lowest Mg measured in any sample, the number of samples and correlation coefficient of the linear regression, and the charge balance for the extrapolated zero-Mg composition. The database also includes information about the sampled locations (geospatial coordinates, vent or vent field names, names of other physiographic features), temperature, flow and vent type

  20. Mixing from below in hydrothermal ore deposits

    Science.gov (United States)

    Bons, Paul D.; Gomez-Rivas, Enrique; Markl, Gregor; Walter, Bejamin

    2014-05-01

    Unconformity-related hydrothermal ore deposits typically show indications of mixing of two end-member fluids: (a) hot, deep, rock-buffered basement brines and (b) colder fluids derived from the surface or overlying sediments. The hydromechanics of bringing these fluids together from above and below remain unclear. Classical percolative Darcy-flow models are inconsistent with (1) fluid overpressure indicated by fracturing and brecciation, (2) fast fluid flow indicated by thermal disequilibrium, and (3) strong fluid composition variations on the mm-scale, indicated by fluid inclusion analyses (Bons et al. 2012; Fusswinkel et al. 2013). We propose that fluids first descend, sucked down by desiccation reactions in exhumed basement. Oldest fluids reach greatest depths, where long residence times and elevated temperatures allow them the extensively equilibrate with their host rock, reach high salinity and scavenge metals, if present. Youngest fluids can only penetrate to shallower depths and can (partially) retain signatures from their origin, for example high Cl/Br ratios from the dissolution of evaporitic halite horizons. When fluids are released from all levels of the crustal column, these fluids mix during rapid ascent to form hydrothermal ore deposits. Mixing from below provides a viable hydromechanical mechanism to explain the common phenomenon of mixed shallow and deep fluids in hydrothermal ore deposits. Bons, P.D., Elburg, M.A., Gomez-Rivas, E. 2012. A review of the formation of tectonic veins and their microstructures. J. Struct. Geol. doi:10.1016/j.jsg.2012.07.005 Fusswinkel, T., Wagner, T., Wälle, M., Wenzel, T., Heinrich, C.A., Markl, M. 2013. Fluid mixing forms basement-hosted Pb-Zn deposits: Insight from metal and halogen geochemistry of individual fluid inclusions. Geology. doi:10.1130/G34092.1

  1. Hydrothermal corrosion of silicon carbide joints without radiation

    Science.gov (United States)

    Koyanagi, Takaaki; Katoh, Yutai; Terrani, Kurt A.; Kim, Young-Jin; Kiggans, James O.; Hinoki, Tatsuya

    2016-12-01

    Hydrothermal corrosion of four types of the silicon carbi