WorldWideScience

Sample records for hydrogen hybrid internal

  1. Public perception related to a hydrogen hybrid internal combustion engine transit bus demonstration and hydrogen fuel

    International Nuclear Information System (INIS)

    Hickson, Allister; Phillips, Al; Morales, Gene

    2007-01-01

    Hydrogen has been widely considered as a potentially viable alternative to fossil fuels for use in transportation. In addition to price competitiveness with fossil fuels, a key to its adoption will be public perceptions of hydrogen technologies and hydrogen fuel. This paper examines public perceptions of riders of a hydrogen hybrid internal combustion engine bus and hydrogen as a fuel source

  2. Development of Premacy Hydrogen RE Hybrid

    Energy Technology Data Exchange (ETDEWEB)

    Wakayama, N. [Mazda Motor Corporation, Hiroshima (Japan)

    2010-07-01

    Hydrogen powered ICE (internal combustion engine) vehicles can play an important role as an automotive power source in the future, because of its higher reliability and cost performance than those of fuel cell vehicles. Combined with hydrogen, Mazda's unique rotary engine (RE) has merits such as a prevention of hydrogen pre-ignition. Mazda has been developing hydrogen vehicles with the hydrogen RE from the early 1990s. Premacy (Mazda5) Hydrogen RE Hybrid was developed and launched in 2009, following RX-8 Hydrogen RE delivered in 2006. A series hybrid system was adopted in Premacy Hydrogen RE Hybrid. A traction motor switches its windings while the vehicle is moving. This switching technology allows the motor to be small and high-efficient. The lithium-ion high voltage battery, which has excellent input-output characteristics, was installed. These features extend the hydrogen fuel driving range to 200 km and obtain excellent acceleration performance. The hydrogen RE can be also operated by gasoline (Dual Fuel System). The additional gasoline operation makes hydrogen vehicles possible to drive in non-hydrogen station area. With approval from the Japanese Ministry of Land Infrastructure and Transport, Mazda Premacy Hydrogen RE Hybrid was delivered successfully to the Japanese market in the form of leasing. (orig.)

  3. Hydrogen hybrid vehicle engine development: Experimental program

    Energy Technology Data Exchange (ETDEWEB)

    Van Blarigan, P. [Sandia National Lab., Livermore, CA (United States)

    1995-09-01

    A hydrogen fueled engine is being developed specifically for the auxiliary power unit (APU) in a series type hybrid vehicle. Hydrogen is different from other internal combustion (IC) engine fuels, and hybrid vehicle IC engine requirements are different from those of other IC vehicle engines. Together these differences will allow a new engine design based on first principles that will maximize thermal efficiency while minimizing principal emissions. The experimental program is proceeding in four steps: (1) Demonstration of the emissions and the indicated thermal efficiency capability of a standard CLR research engine modified for higher compression ratios and hydrogen fueled operation. (2) Design and test a new combustion chamber geometry for an existing single cylinder research engine, in an attempt to improve on the baseline indicated thermal efficiency of the CLR engine. (3) Design and build, in conjunction with an industrial collaborator, a new full scale research engine designed to maximize brake thermal efficiency. Include a full complement of combustion diagnostics. (4) Incorporate all of the knowledge thus obtained in the design and fabrication, by an industrial collaborator, of the hydrogen fueled engine for the hybrid vehicle power train illustrator. Results of the CLR baseline engine testing are presented, as well as preliminary data from the new combustion chamber engine. The CLR data confirm the low NOx produced by lean operation. The preliminary indicated thermal efficiency data from the new combustion chamber design engine show an improvement relative to the CLR engine. Comparison with previous high compression engine results shows reasonable agreement.

  4. Analysis of Hybrid Hydrogen Systems: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Dean, J.; Braun, R.; Munoz, D.; Penev, M.; Kinchin, C.

    2010-01-01

    Report on biomass pathways for hydrogen production and how they can be hybridized to support renewable electricity generation. Two hybrid systems were studied in detail for process feasibility and economic performance. The best-performing system was estimated to produce hydrogen at costs ($1.67/kg) within Department of Energy targets ($2.10/kg) for central biomass-derived hydrogen production while also providing value-added energy services to the electric grid.

  5. Solar hydrogen hybrid system with carbon storage

    International Nuclear Information System (INIS)

    Zini, G.; Marazzi, R.; Pedrazzi, S.; Tartarini, P.

    2009-01-01

    A complete solar hydrogen hybrid system has been developed to convert, store and use energy from renewable energy sources. The theoretical model has been implemented in a dynamic model-based software environment and applied to real data to simulate its functioning over a one-year period. Results are used to study system design and performance. A photovoltaic sub-system directly drives a residential load and, if a surplus of energy is available, an electrolyzer to produce hydrogen which is stored in a cluster of nitrogen-cooled tanks filled with AX-21 activated carbons. When the power converted from the sun is not sufficient to cover load needs, hydrogen is desorbed from activated carbon tanks and sent to the fuel-cell sub-system so to obtain electrical energy. A set of sub-systems (bus-bar, buck- and boost-converters, inverter, control circuits), handle the electrical power according to a Programmable Logic Control unit so that the load can be driven with adequate Quality of Service. Hydrogen storage is achieved through physisorption (weak van der Waals interactions) between carbon atoms and hydrogen molecules occurring at low temperature (77 K) in carbon porous solids at relatively low pressures. Storage modeling has been developed using a Langmuir-Freundlich 1st type isotherm and experimental data available in literature. Physisorption storage provides safer operations along with good gravimetric (10.8% at 6 MPa) and volumetric (32.5 g/l at 6 MPa) storage capacities at costs that can be comparable to, or smaller than, ordinary storage techniques (compression or liquefaction). Several test runs have been performed on residential user data-sets: the system is capable of providing grid independence and can be designed to yield a surplus production of hydrogen which can be used to recharge electric car batteries or fill tanks for non-stationary uses. (author)

  6. Importance of international standards on hydrogen technologies

    International Nuclear Information System (INIS)

    Bose, T.K.; Gingras, S.

    2001-01-01

    This presentation provided some basic information regarding standards and the International Organization for Standardization (ISO). It also explained the importance of standardization activities, particularly ISO/TC 197 which applies to hydrogen technologies. Standards are established by consensus. They define the minimum requirements that will ensure that products and services are reliable and effective. Standards contribute to the elimination of technical barriers to trade (TBT). The harmonization of standards around the world is desirable in a free trade environment. The influence of the TBT on international standardization was discussed with particular reference to the objectives of ISO/TC 197 hydrogen technologies. One of the priorities for ISO/TC 197 is a hydrogen fuel infrastructure which includes refuelling stations, fuelling connectors, and storage technologies for gaseous and liquid hydrogen. Other priorities include an agreement between the International Electrotechnical Commission (IEC) and the ISO, in particular the IEC/TC 105 and ISO/TC 197 for the development of fuel cell standards. The international standards that have been published thus far include ISO 13984:1999 for liquid hydrogen, land vehicle fuelling system interface, and ISO 14687:1999 for hydrogen fuel product specification. Standards are currently under development for: liquid hydrogen; airport hydrogen fuelling facilities; gaseous hydrogen blends; basic considerations for the safety of hydrogen systems; gaseous hydrogen and hydrogen blends; and gaseous hydrogen for land vehicle filling connectors. It was concluded that the widespread use of hydrogen is dependent on international standardization

  7. Hybrid Hydrogen and Mechanical Distributed Energy Storage

    Directory of Open Access Journals (Sweden)

    Stefano Ubertini

    2017-12-01

    Full Text Available Effective energy storage technologies represent one of the key elements to solving the growing challenges of electrical energy supply of the 21st century. Several energy storage systems are available, from ones that are technologically mature to others still at a research stage. Each technology has its inherent limitations that make its use economically or practically feasible only for specific applications. The present paper aims at integrating hydrogen generation into compressed air energy storage systems to avoid natural gas combustion or thermal energy storage. A proper design of such a hybrid storage system could provide high roundtrip efficiencies together with enhanced flexibility thanks to the possibility of providing additional energy outputs (heat, cooling, and hydrogen as a fuel, in a distributed energy storage framework. Such a system could be directly connected to the power grid at the distribution level to reduce power and energy intermittence problems related to renewable energy generation. Similarly, it could be located close to the user (e.g., office buildings, commercial centers, industrial plants, hospitals, etc.. Finally, it could be integrated in decentralized energy generation systems to reduce the peak electricity demand charges and energy costs, to increase power generation efficiency, to enhance the security of electrical energy supply, and to facilitate the market penetration of small renewable energy systems. Different configurations have been investigated (simple hybrid storage system, regenerate system, multistage system demonstrating the compressed air and hydrogen storage systems effectiveness in improving energy source flexibility and efficiency, and possibly in reducing the costs of energy supply. Round-trip efficiency up to 65% can be easily reached. The analysis is conducted through a mixed theoretical-numerical approach, which allows the definition of the most relevant physical parameters affecting the system

  8. Transit experience with hydrogen fueled hybrid electric buses

    Energy Technology Data Exchange (ETDEWEB)

    Scott, P.B.; Mazaika, D.M. [ISE Corp., Poway, CA (United States)

    2006-07-01

    Mass transit buses are ideal candidates for hydrogen implementation due to their capability of carrying 30 to 60 kg of hydrogen. ISE Corporation is a supplier of hydrogen fueled buses, including the first hybrid electric fuel cell bus which was commercialized in 2002, the hybrid electric fuel cell bus, and the hybrid hydrogen internal combustion engine (HHICE) bus which was commercialized in 2004. The configuration of a HHICE bus was illustrated with reference to its engine, control system, energy storage, generator, drive motor, inverter and accessories. Although these vehicles are expensive, the cost is amortized over a large base of hours used and passengers carried. The buses are operated primarily in urban areas where quiet and clean operation is needed the most. ISE has established a joint venture with Thor industries to develop a series of fuel cell buses equipped with a 60 kW PEM fuel cell. A schematic illustrating the energy flow in HHICE bus was also presented. It was shown that regenerative braking recovers the energy of motion. When using regenerative braking, most of the braking energy is saved in the battery. ISE drive systems convert 30 per cent or more of the bus energy to electrical energy to be used in later acceleration. Reduced fuel consumption also reduces the vehicle emissions. Testing of HHICE buses in both summer and winter operating conditions have shown that the range needs to be improved along with engine component reliability and durability. Fuel supply is also a major issue. A comparison with a fuel cell hybrid system was also presented. In the United States, more than 100,000 miles have been logged for the use of hydrogen hybrid buses, fuel cell buses and HHICE buses. The HHICE bus offers low capital cost, familiar technologies, but some NOx. CAT absorber technology offers the possibility of near zero emission capability. The fuel cell bus was found to be more fuel efficient, and can travel nearly twice as far per unit energy as

  9. Transit experience with hydrogen fueled hybrid electric buses

    International Nuclear Information System (INIS)

    Scott, P.B.; Mazaika, D.M.; Levin, J.; Edwards, T.

    2006-01-01

    Both AC Transit and SunLine Transit operate hybrid electric hydrogen fueled buses in their transit service. ACT presently operates three fuel cell buses in daily revenue service, and SunLine operates a fuel cell bus and a HHICE (Hybrid Hydrogen Internal Combustion Engine) bus. All these buses use similar electric drive train and electric accessories, although the detailed design differs notably between the fuel cell and the hybrid ICE buses. The fuel cell buses use a 120kW UTC fuel cell and a Van Hool Chassis, whereas the HHICE bus uses a turbocharged Ford engine which is capable of 140kW generator output in a New Flyer Chassis. The HHICE bus was the first in service, and has been subjected to both winter testing in Manitoba, Canada and summer testing in the Palm Springs, CA region. The winter testing included passenger sampling using questionnaires to ascertain passenger response. The fuel cell buses were introduced to service at the start of 2006. All five buses are in daily revenue service use. The paper will describe the buses and the experience of the transit properties in operating the buses. (author)

  10. Borazine-boron nitride hybrid hydrogen storage system

    Science.gov (United States)

    Narula, Chaitanya K [Knoxville, TN; Simonson, J Michael [Knoxville, TN; Maya, Leon [Knoxville, TN; Paine, Robert T [Albuquerque, NM

    2008-04-22

    A hybrid hydrogen storage composition includes a first phase and a second phase adsorbed on the first phase, the first phase including BN for storing hydrogen by physisorption and the second phase including a borazane-borazine system for storing hydrogen in combined form as a hydride.

  11. Internal combustion engines in hybrid vehicles

    NARCIS (Netherlands)

    Mourad, S.; Weijer, C.J.T. van de; Beckman, D.E.

    1998-01-01

    In this paper the use of internal combustion engines in hybrid powertrains is investigated. The substantial difference between the use of internal combustion engines in conventional and in hybrid vehicles mean that engines for hybrid vehicles should be designed specifically for the purpose. At the

  12. Hydrogenation properties and microstructure of Ti-Mn-based alloys for hybrid hydrogen storage vessel

    International Nuclear Information System (INIS)

    Shibuya, Masachika; Nakamura, Jin; Akiba, Etsuo

    2008-01-01

    Ti-Mn-based AB 2 -type alloys which are suitable for a hybrid hydrogen storage vessel have been synthesized and evaluated hydrogenation properties. As the third element V was added to Ti-Mn binary alloys. All the alloys synthesized in this work mainly consist of the C14 Laves and BCC phase. In the case of Ti0.5V0.5Mn alloy, the amounts of hydrogen absorption was 1.8 wt.% at 243 K under the atmosphere of 7 MPa H 2 , and the hydrogen desorption pressure was in the range of 0.2-0.4 MPa at 243 K. The hydrogen capacity of this alloy did not saturate under 7 MPa H 2 and seems to increase with hydrogen pressure up to 35 MPa that is estimated working pressure of the hybrid hydrogen storage vessel

  13. HYDROGEN USE IN INTERNAL COMBUSTION ENGINE:

    OpenAIRE

    Ciniviz, Murat

    2012-01-01

    Fast depletion of fossil fuels is urgently demanding a carry out work for research to find out the viable alternative fuels for meeting sustainable energy demand with minimum environmental impact. In the future, our energy systems will need to be renewable and sustainable, efficient and cost-effective, convenient and safe. Hydrogen is expected to be one of the most important fuels in the near future to meet the stringent emission norms. The use of the hydrogen as fuel in the internal combusti...

  14. Development of a solar-hydrogen hybrid energy system

    International Nuclear Information System (INIS)

    Sebastian, P.J.; Gamboa, S.A.; Vejar, Set; Campos, J.

    2009-01-01

    Full text: The details of the development of a PV-hydrogen hybrid energy system is presented. An arrangement of photovoltaic modules (125 W/module) was established to provide 9 kW installed power in a three-phase configuration at 127 Vrms/phase. A 5 kW fuel cell system (hydrogen/oxygen) operate as a dynamic backup of the photovoltaic system. The autonomous operation of the hybrid power system implies the production of hydrogen by electrolysis. The hydrogen is produced by water electrolysis using an electrolyzer of 1 kW power. The electrical energy used to produce hydrogen is supplied from solar panels by using 1kW of photovoltaic modules. The photovoltaic modules are installed in a sun-tracker arrangement for increasing the energy conversion efficiency. The hydrogen is stored in solar to electric commercial metal hydride based containers and supplied to the fuel cell. The hybrid system is monitored by internet and some dynamic characteristics such as demanding power, energy and power factor could be analyzed independently from the system. Some energy saving recommendations has been implemented as a pilot program at CIE-UNAM to improve the efficient use of clean energy in normal operating conditions in offices and laboratories. (author)

  15. Storing in carbon nano structures for hybrid systems solar hydrogen

    International Nuclear Information System (INIS)

    Marazzi, R.; Zini, G.; Tartarini, P.

    2009-01-01

    We have developed a hybrid energy system for converting energy from renewable sources and its storage in the form of hydrogen. The storage uses activated carbon and the methodology was modelled mathematically and simulated in numerical software. The results show that storage compression is cheaper storage for liquefaction. [it

  16. Benchmarking the internal combustion engine and hydrogen

    International Nuclear Information System (INIS)

    Wallace, J.S.

    2006-01-01

    The internal combustion engine is a cost-effective and highly reliable energy conversion technology. Exhaust emission regulations introduced in the 1970's triggered extensive research and development that has significantly improved in-use fuel efficiency and dramatically reduced exhaust emissions. The current level of gasoline vehicle engine development is highlighted and representative emissions and efficiency data are presented as benchmarks. The use of hydrogen fueling for IC engines has been investigated over many decades and the benefits and challenges arising are well-known. The current state of hydrogen-fueled engine development will be reviewed and evaluated against gasoline-fueled benchmarks. The prospects for further improvements to hydrogen-fueled IC engines will be examined. While fuel cells are projected to offer greater energy efficiency than IC engines and zero emissions, the availability of fuel cells in quantity at reasonable cost is a barrier to their widespread adaptation for the near future. In their current state of development, hydrogen fueled IC engines are an effective technology to create demand for hydrogen fueling infrastructure until fuel cells become available in commercial quantities. During this transition period, hydrogen fueled IC engines can achieve PZEV/ULSLEV emissions. (author)

  17. Hydrogen atom as a quantum-classical hybrid system

    International Nuclear Information System (INIS)

    Zhan, Fei; Wu, Biao

    2013-01-01

    Hydrogen atom is studied as a quantum-classical hybrid system, where the proton is treated as a classical object while the electron is regarded as a quantum object. We use a well known mean-field approach to describe this hybrid hydrogen atom; the resulting dynamics for the electron and the proton is compared to their full quantum dynamics. The electron dynamics in the hybrid description is found to be only marginally different from its full quantum counterpart. The situation is very different for the proton: in the hybrid description, the proton behaves like a free particle; in the fully quantum description, the wave packet center of the proton orbits around the center of mass. Furthermore, we find that the failure to describe the proton dynamics properly can be regarded as a manifestation of the fact that there is no conservation of momentum in the mean-field hybrid approach. We expect that such a failure is a common feature for all existing approaches for quantum-classical hybrid systems of Born-Oppenheimer type.

  18. UC Davis Fuel Cell, Hydrogen, and Hybrid Vehicle (FCH2V) GATE Center of Excellence

    Energy Technology Data Exchange (ETDEWEB)

    Erickson, Paul

    2012-05-31

    This is the final report of the UC Davis Fuel Cell, Hydrogen, and Hybrid Vehicle (FCH2V) GATE Center of Excellence which spanned from 2005-2012. The U.S. Department of Energy (DOE) established the Graduate Automotive Technology Education (GATE) Program, to provide a new generation of engineers and scientists with knowledge and skills to create advanced automotive technologies. The UC Davis Fuel Cell, Hydrogen, and Hybrid Vehicle (FCH2V) GATE Center of Excellence established in 2005 is focused on research, education, industrial collaboration and outreach within automotive technology. UC Davis has had two independent GATE centers with separate well-defined objectives and research programs from 1998. The Fuel Cell Center, administered by ITS-Davis, has focused on fuel cell technology. The Hybrid-Electric Vehicle Design Center (HEV Center), administered by the Department of Mechanical and Aeronautical Engineering, has focused on the development of plug-in hybrid technology using internal combustion engines. The merger of these two centers in 2005 has broadened the scope of research and lead to higher visibility of the activity. UC Davis's existing GATE centers have become the campus's research focal points on fuel cells and hybrid-electric vehicles, and the home for graduate students who are studying advanced automotive technologies. The centers have been highly successful in attracting, training, and placing top-notch students into fuel cell and hybrid programs in both industry and government.

  19. Direct hydrogen fuel cell systems for hybrid vehicles

    Science.gov (United States)

    Ahluwalia, Rajesh K.; Wang, X.

    Hybridizing a fuel cell system with an energy storage system offers an opportunity to improve the fuel economy of the vehicle through regenerative braking and possibly to increase the specific power and decrease the cost of the combined energy conversion and storage systems. Even in a hybrid configuration it is advantageous to operate the fuel cell system in a load-following mode and use the power from the energy storage system when the fuel cell alone cannot meet the power demand. This paper discusses an approach for designing load-following fuel cell systems for hybrid vehicles and illustrates it by applying it to pressurized, direct hydrogen, polymer-electrolyte fuel cell (PEFC) systems for a mid-size family sedan. The vehicle level requirements relative to traction power, response time, start-up time and energy conversion efficiency are used to select the important parameters for the PEFC stack, air management system, heat rejection system and the water management system.

  20. Once-through hybrid sulfur process for nuclear hydrogen production

    International Nuclear Information System (INIS)

    Jeong, Y. H.

    2008-01-01

    Increasing concern about the global climate change spurs the development of low- or zero-carbon energy system. Nuclear hydrogen production by water electrolysis would be the one of the short-term solutions, but low efficiency and high production cost (high energy consumption) is the technical hurdle to be removed. In this paper the once-through sulfur process composed of the desulfurization and the water electrolysis systems is proposed. Electrode potential for the conventional water electrolysis (∼2.0 V) can be reduced significantly by the anode depolarization using sulfur dioxide: down to 0.6 V depending on the current density This depolarized electrolysis is the electrolysis step of the hybrid sulfur process originally proposed by the Westinghouse. However; recycling of sulfur dioxide requires a high temperature heat source and thus put another technical hurdle on the way to nuclear hydrogen production: the development of high temperature nuclear reactors and corresponding sulfuric acid decomposition system. By the once-through use of sulfur dioxide rather than the closed recycle, the hurdle can be removed. For the sulfur feed, the desulfurization system is integrated into the water electrolysis system. Fossil fuels include a few percent of sulfur by weight. During the refinement or energy conversion, most of the sulfur should be separated The separated sulfur can be fed to the water electrolysis system and the final product would be hydrogen and sulfuric acid, which is number one chemical in the world by volume. Lowered electrode potential and additional byproduct, the sulfuric acid, can provide economically affordable hydrogen. In this study, the once-through hybrid sulfur process for hydrogen production was proposed and the process was optimized considering energy consumption in electrolysis and sulfuric acid concentration. Economic feasibility of the proposed process was also discussed. Based on currently available experimental data for the electrode

  1. Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications

    CSIR Research Space (South Africa)

    Musyoka, Nicholas M

    2016-06-01

    Full Text Available Metal–organic frameworks (MOFs) hybrid composites have recently attracted considerable attention in hydrogen storage applications. In this study a hybrid composite of zeolite templated carbon (ZTC) and Cr-based MOF (MIL-101) was synthesised...

  2. Hydrogen Bonding and Stability of Hybrid Organic-Inorganic Perovskites

    KAUST Repository

    El-Mellouhi, Fedwa

    2016-09-08

    In the past few years, the efficiency of solar cells based on hybrid organic–inorganic perovskites has exceeded the level needed for commercialization. However, existing perovskites solar cells (PSCs) suffer from several intrinsic instabilities, which prevent them from reaching industrial maturity, and stabilizing PSCs has become a critically important problem. Here we propose to stabilize PSCs chemically by strengthening the interactions between the organic cation and inorganic anion of the perovskite framework. In particular, we show that replacing the methylammonium cation with alternative protonated cations allows an increase in the stability of the perovskite by forming strong hydrogen bonds with the halide anions. This interaction also provides opportunities for tuning the electronic states near the bandgap. These mechanisms should have a universal character in different hybrid organic–inorganic framework materials that are widely used.

  3. Hydrogen Bonding and Stability of Hybrid Organic-Inorganic Perovskites

    KAUST Repository

    El-Mellouhi, Fedwa; Marzouk, Asma; Bentria, El Tayeb; Rashkeev, Sergey N.; Kais, Sabre; Alharbi, Fahhad H.

    2016-01-01

    In the past few years, the efficiency of solar cells based on hybrid organic–inorganic perovskites has exceeded the level needed for commercialization. However, existing perovskites solar cells (PSCs) suffer from several intrinsic instabilities, which prevent them from reaching industrial maturity, and stabilizing PSCs has become a critically important problem. Here we propose to stabilize PSCs chemically by strengthening the interactions between the organic cation and inorganic anion of the perovskite framework. In particular, we show that replacing the methylammonium cation with alternative protonated cations allows an increase in the stability of the perovskite by forming strong hydrogen bonds with the halide anions. This interaction also provides opportunities for tuning the electronic states near the bandgap. These mechanisms should have a universal character in different hybrid organic–inorganic framework materials that are widely used.

  4. Wind energy-hydrogen storage hybrid power generation

    Energy Technology Data Exchange (ETDEWEB)

    Wenjei Yang; Orhan Aydin [University of Michigan, Ann Arbor, MI (United States). Dept. of Mechanical Engineering and Applied Mechanics

    2001-07-01

    In this theoretical investigation, a hybrid power generation system utilizing wind energy and hydrogen storage is presented. Firstly, the available wind energy is determined, which is followed by evaluating the efficiency of the wind energy conversion system. A revised model of windmill is proposed from which wind power density and electric power output are determined. When the load demand is less than the output of the generation, the excess electric power is relayed to the electrolytic cell where it is used to electrolyse the de-ionized water. Hydrogen thus produced can be stored as hydrogen compressed gas or liquid. Once the hydrogen is stored in an appropriate high-pressure vessel, it can be used in a combustion engine, fuel cell, or burned in a water-cooled burner to produce a very high-quality steam for space heating, or to drive a turbine to generate electric power. It can also be combined with organic materials to produce synthetic fuels. The conclusion is that the system produces no harmful waste and depletes no resources. Note that this system also works well with a solar collector instead of a windmill. (author)

  5. Hybrid vehicle system studies and optimized hydrogen engine design

    Science.gov (United States)

    Smith, J. R.; Aceves, S.

    1995-04-01

    We have done system studies of series hydrogen hybrid automobiles that approach the PNGV design goal of 34 km/liter (80 mpg), for 384 km (240 mi) and 608 km (380 mi) ranges. Our results indicate that such a vehicle appears feasible using an optimized hydrogen engine. We have evaluated the impact of various on-board storage options on fuel economy. Experiments in an available engine at the Sandia CRF demonstrated NO(x) emissions of 10 to 20 ppM at an equivalence ratio of 0.4, rising to about 500 ppm at 0.5 equivalence ratio using neat hydrogen. Hybrid simulation studies indicate that exhaust NO(x) concentrations must be less than 180 ppM to meet the 0.2 g/mile ULEV or Federal Tier II emissions regulations. LLNL has designed and fabricated a first generation optimized hydrogen engine head for use on an existing Onan engine. This head features 15:1 compression ratio, dual ignition, water cooling, two valves and open quiescent combustion chamber to minimize heat transfer losses. Initial testing shows promise of achieving an indicated efficiency of nearly 50% and emissions of less than 100 ppM NO(x). Hydrocarbons and CO are to be measured, but are expected to be very low since their only source is engine lubricating oil. A successful friction reduction program on the Onan engine should result in a brake thermal efficiency of about 42% compared to today's gasoline engines of 32%. Based on system studies requirements, the next generation engine will be about 2 liter displacement and is projected to achieve 46% brake thermal efficiency with outputs of 15 kW for cruise and 40 kW for hill climb.

  6. Modeling the reaction kinetics of a hydrogen generator onboard a fuel cell -- Electric hybrid motorcycle

    Science.gov (United States)

    Ganesh, Karthik

    Owing to the perceived decline of the fossil fuel reserves in the world and environmental issues like pollution, conventional fuels may be replaced by cleaner alternative fuels. The potential of hydrogen as a fuel in vehicular applications is being explored. Hydrogen as an energy carrier potentially finds applications in internal combustion engines and fuel cells because it is considered a clean fuel and has high specific energy. However, at 6 to 8 per kilogram, not only is hydrogen produced from conventional methods like steam reforming expensive, but also there are storage and handling issues, safety concerns and lack of hydrogen refilling stations across the country. The purpose of this research is to suggest a cheap and viable system that generates hydrogen on demand through a chemical reaction between an aluminum-water slurry and an aqueous sodium hydroxide solution to power a 2 kW fuel cell on a fuel cell hybrid motorcycle. This reaction is essentially an aluminum-water reaction where sodium hydroxide acts as a reaction promoter or catalyst. The Horizon 2000 fuel cell used for this purpose has a maximum hydrogen intake rate of 28 lpm. The study focuses on studying the exothermic reaction between the reactants and proposes a rate law that best describes the rate of generation of hydrogen in connection to the surface area of aluminum available for the certain reaction and the concentration of the sodium hydroxide solution. Further, the proposed rate law is used in the simulation model of the chemical reactor onboard the hybrid motorcycle to determine the hydrogen flow rate to the fuel cell with time. Based on the simulated rate of production of hydrogen from the chemical system, its feasibility of use on different drive cycles is analyzed. The rate of production of hydrogen with a higher concentration of sodium hydroxide and smaller aluminum powder size was found to enable the installation of the chemical reactor on urban cycles with frequent stops and starts

  7. Hydrogen-oxygen powered internal combustion engine

    Science.gov (United States)

    Cameron, H.; Morgan, N.

    1970-01-01

    Hydrogen at 300 psi and oxygen at 800 psi are injected sequentially into the combustion chamber to form hydrogen-rich mixture. This mode of injection eliminates difficulties of preignition, detonation, etc., encountered with carburated, spark-ignited, hydrogen-air mixtures. Ignition at startup is by means of a palladium catalyst.

  8. An internal friction peak caused by hydrogen in maraging steel

    International Nuclear Information System (INIS)

    Usui, Makoto; Asano, Shigeru

    1996-01-01

    Internal friction in hydrogen-charged iron and steel has so far been studied by a large number of investigators. For pure iron, a well-defined peak of internal friction has been observed under the cold-worked and hydrogen-charged conditions. This is called the hydrogen cold-work peak, or the Snoek-Koester relaxation, which originates from the hydrogen-dislocation interaction. In the present study, a high-strength maraging steel (Fe-18Ni-9Co-5Mo) was chosen as another high-alloy steel which is known to be very susceptible to hydrogen embrittlement. The purpose of this paper is to show a new internal friction peak caused by hydrogen in the maraging steel and to compare it with those found in stainless steels which have so far been studied as typical engineering high-alloy materials

  9. Hybrid hydrogen-battery systems for renewable off-grid telecom power

    OpenAIRE

    Scamman, D.; Newborough, M.; Bustamante, H.

    2015-01-01

    Off-grid hybrid systems, based on the integration of hydrogen technologies (electrolysers, hydrogen stores and fuel cells) with battery and wind/solar power technologies, are proposed for satisfying the continuous power demands of telecom remote base stations. A model was developed to investigate the preferred role for electrolytic hydrogen within a hybrid system; the analysis focused on powering a 1 kW telecom load in three locations of distinct wind and solar resource availability. When com...

  10. On battery-less autonomous polygeneration microgrids: Investigation of the combined hybrid capacitors/hydrogen alternative

    International Nuclear Information System (INIS)

    Kyriakarakos, George; Piromalis, Dimitrios D.; Arvanitis, Konstantinos G.; Dounis, Anastasios I.; Papadakis, George

    2015-01-01

    Highlights: • A battery-less autonomous polygeneration microgrid is technically feasible. • Laboratory testing of hybrid capacitors. • Investigation of hybrid capacitors utilization along with hydrogen subsystem. - Abstract: The autonomous polygeneration microgrid topology aims to cover holistically the needs in remote areas as far as electrical power, potable water through desalination, fuel for transportation in the form of hydrogen, heating and cooling are concerned. Deep discharge lead acid batteries are mostly used in such systems, associated with specific disadvantages, both technical and environmental. This paper investigated the possibility of replacing the battery bank from a polygeneration microgrid with a hybrid capacitor bank and more intensive utilization of a hydrogen subsystem. Initially commercial hybrid capacitors were tested under laboratory conditions and based on the respective results a case study was performed. The optimized combination of hybrid capacitors and higher hydrogen usage was then investigated through simulations and compared to a polygeneration microgrid featuring deep discharge lead acid batteries. From the results it was clear that it is technically possible to exchange the battery bank with a hybrid capacitor bank and higher hydrogen utilization. From the economic point of view, the current cost of the hybrid capacitors and the hydrogen components is high which leads to higher overall cost in comparison with deep discharge lead acid batteries. Taking into account, though, the decreasing cost prospects and trends of both the hybrid capacitors and the hydrogen components it is expected that this approach will become economically competitive in a few years

  11. Internal dosimetry of tritiated hydrogen gas

    International Nuclear Information System (INIS)

    Peterman, B.F.; Johnson, J.R.; Dunford, D.W.; McElroy, R.G.C.

    1985-02-01

    This document is a report on experiments to quantify the doses that may occur from the tritium gas that is converted 'in vivo' to tritiated water following the exposure to tritiated hydrogen gas contaminated air. This report also includes theoretical evaluation of the radiological hazards from the uptake through skin of tritium from tritiated hydrogen adsorbed on surfaces

  12. Noncatalytic hydrogenation of decene-1 with hydrogen accumulated in a hybrid carbon nanostructure in nanosized membrane reactors

    Science.gov (United States)

    Soldatov, A. P.

    2014-08-01

    Studies on the creation of nanosized membrane reactors (NMRs) of a new generation with accumulated hydrogen and a regulated volume of reaction zone were continued at the next stage. Hydrogenation was performed in the pores of ceramic membranes with hydrogen preliminarily adsorbed in mono- and multilayered orientated carbon nanotubes with graphene walls (OCNTGs)—a new hybrid carbon nanostructure formed on the inner pore surface. Quantitative determination of hydrogen adsorption in OCNTGs was performed using TRUMEM ultrafiltration membranes with D av = 50 and 90 nm and showed that hydrogen adsorption was up to ˜1.5% of the mass of OCNTG. The instrumentation and procedure for noncatalytic hydrogenation of decene-1 at 250-350°C using hydrogen accumulated and stored in OCNTG were developed. The conversion of decene-1 into decane was ˜0.2-1.8% at hydrogenation temperatures of 250 and 350°C, respectively. The rate constants and activation energy of hydrogenation were determined. The latter was found to be 94.5 kJ/mol, which is much smaller than the values typical for noncatalytic hydrogenations and very close to the values characteristic for catalytic reactions. The quantitative distribution of the reacting compounds in each pore regarded as a nanosized membrane reactor was determined. The activity of hydrogen adsorbed in a 2D carbon nanostructure was evaluated. Possible mechanisms of noncatalytic hydrogenation were discussed.

  13. Effects of Internal and External Hydrogen on Inconel 718

    Science.gov (United States)

    Walter, R. J.; Frandsen, J. D.

    1999-01-01

    Internal hydrogen embrittlement (IHE) and hydrogen environment embrittlement (HEE) tensile and bend crack growth tests were performed on Inconel 718. For the IHE tests, the specimens were precharged to approximately 90 ppm hydrogen by exposure to 34.5 MPa H2 at 650 C. The HEE tests were performed in 34.5 MPa H2. Parameters evaluated were test temperature, strain rate for smooth and notch specimen geometries. The strain rate effect was very significant at ambient temperature for both IHE and HEE and decreased with increasing temperatures. For IHE, the strain rate effect was neglible at 260'C, and for HEE the strain rate effect was neglible at 400 C. At low temperatures, IHE was more severe than HEE, and at high temperatures HEE was more severe than IHE with a cross over temperature about 350 C. At 350 C, the equilibrium hydrogen concentration in Inconel 718 is about 50% lower than the hydrogen content of the precharged IHE specimens. Dislocation hydrogen sweeping of surface absorbed hydrogen was the likely transport mechanism for increasing the hydrogen concentration in the HEE tests sufficiently to produce the same degree of embrittlement as that of the more highly hydrogen charged IHE specimens. The main IHE fracture characteristic was formation of large, brittle flat facets, which decreased with increasing test temperature. The IHE fracture matrix surrounding the large facets ranged between brittle fine faceted to microvoid ductility depending upon strain rate, specimen geometry as well as temperature. The HEE fractures were characteristically fine featured, transgranular and brittle with a significant portion forming a "saw tooth" crystallographic pattern. Both IHE and HEE fractures were predominantly along the {1 1 1) slip and twin boundaries. With respect to embrittlement mechanism, it was postulated that dislocation hydrogen sweeping and hydrogen enhanced localized plasticity were active in HEE and IHE for concentrating hydrogen along (1 1 1) slip and twin

  14. Relative efficiency of hydrogen technologies for the hydrogen economy : a fuzzy AHP/DEA hybrid model approach

    International Nuclear Information System (INIS)

    Lee, S.

    2009-01-01

    As a provider of national energy security, the Korean Institute of Energy Research is seeking to establish a long term strategic technology roadmap for a hydrogen-based economy. This paper addressed 5 criteria regarding the strategy, notably economic impact, commercial potential, inner capacity, technical spinoff, and development cost. The fuzzy AHP and DEA hybrid model were used in a two-stage multi-criteria decision making approach to evaluate the relative efficiency of hydrogen technologies for the hydrogen economy. The fuzzy analytic hierarchy process reflects the uncertainty of human thoughts with interval values instead of clear-cut numbers. It therefore allocates the relative importance of 4 criteria, notably economic impact, commercial potential, inner capacity and technical spin-off. The relative efficiency of hydrogen technologies for the hydrogen economy can be measured via data envelopment analysis. It was concluded that the scientific decision making approach can be used effectively to allocate research and development resources and activities

  15. Relative efficiency of hydrogen technologies for the hydrogen economy : a fuzzy AHP/DEA hybrid model approach

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S. [Korea Inst. of Energy Research, Daejeon (Korea, Republic of). Energy Policy Research Division; Mogi, G. [Tokyo Univ., (Japan). Dept. of Technology Management for Innovation, Graduate School of Engineering; Kim, J. [Korea Inst. of Energy Research, Daejeon (Korea, Republic of)

    2009-07-01

    As a provider of national energy security, the Korean Institute of Energy Research is seeking to establish a long term strategic technology roadmap for a hydrogen-based economy. This paper addressed 5 criteria regarding the strategy, notably economic impact, commercial potential, inner capacity, technical spinoff, and development cost. The fuzzy AHP and DEA hybrid model were used in a two-stage multi-criteria decision making approach to evaluate the relative efficiency of hydrogen technologies for the hydrogen economy. The fuzzy analytic hierarchy process reflects the uncertainty of human thoughts with interval values instead of clear-cut numbers. It therefore allocates the relative importance of 4 criteria, notably economic impact, commercial potential, inner capacity and technical spin-off. The relative efficiency of hydrogen technologies for the hydrogen economy can be measured via data envelopment analysis. It was concluded that the scientific decision making approach can be used effectively to allocate research and development resources and activities.

  16. Hydrogen storage in hybrid of layered double hydroxides/reduced graphene oxide using spillover mechanism

    International Nuclear Information System (INIS)

    Ensafi, Ali A.; Jafari-Asl, Mehdi; Nabiyan, Afshin; Rezaei, Behzad; Dinari, Mohammad

    2016-01-01

    New efficient hydrogen storage hybrids were fabricated based on hydrogen spillover mechanism, including chemisorptions and dissociation of H_2 on the surface of LDH (layered double hydroxides) and diffusion of H to rGO (reduced graphene oxide). The structures and compositions of all of the hybrids (LDHs/rGO) have been verified using different methods including transmission electron microscopy, X ray diffraction spectroscopy, infrared spectroscopy and Brunauer–Emmett–Teller analysis. Then, the abilities of the LDHs/rGOs, as hydrogen spillover, were investigated by electrochemical methods. In addition, the LDHs/rGOs were decorated with palladium, using redox replacement process, and their hydrogen spillover properties were studied. The results showed that the hydrogen adsorption/desorption kinetics, hydrogen storage capacities and stabilities of Pd"#LDH/rGOs are better than Pd/rGO. Finally presence of different polymers (synthesis with monomers, 4–aminophenol, 4–aminothiophenol, o-phenylenediamine and p-phenylenediamine) at the surface of the Pd#LDH/rGOs on hydrogen storage were studied. The results showed that presence of o-phenylenediamine and p-phenylenediamine improves the kinetics of the hydrogen adsorption/desorption and increase the capacity of the hydrogen storage. - Highlights: • Efficient hydrogen storage sorbents are introduced. • The sorbents are synthesized based on hybrids of layered double hydroxide. • The compositions of all of the hybrids are verified using different methods. • Pd nanoparticles modified nanohybrids are investigated for hydrogen storage. • Presence of different polymers beside the hydrogen sorbents are investigated.

  17. Thermodynamics of the hybrid interaction of hydrogen with palladium nanoparticles

    NARCIS (Netherlands)

    Griessen, R.P.; Strohfeldt, N.; Giessen, H.

    2015-01-01

    Palladium-hydrogen is a prototypical metal-hydrogen system. It is therefore not at all surprising that a lot of attention has been devoted to the absorption and desorption of hydrogen in nanosized palladium particles. Several seminal articles on the interaction of H with Pd nanocubes and

  18. A nanostructured Ni/graphene hybrid for enhanced electrochemical hydrogen storage

    International Nuclear Information System (INIS)

    Choi, Moon-Hyung; Min, Young-Je; Gwak, Gyeong-Hyeon; Paek, Seung-Min; Oh, Jae-Min

    2014-01-01

    Highlights: • Graphene oxide(GO) was hybridized with the Ni(OH) 2 . • The Ni(OH) 2 /GO was reduced to Ni/graphene. • XRD, TEM, and X-ray absorption spectroscopy were examined. • The hydrogen storage property of Ni/graphene was significantly enhanced. - Abstract: To fabricate electrochemical hydrogen storage materials with delaminated structure, the graphene oxide (GO) in the ethylene glycol solution was reassembled in the presence of the precursor of Ni nanoparticles, and then, the reassembled hybrid was reduced under hydrogen atmosphere to obtain Ni/graphene hybrid. X-ray diffraction patterns and X-ray absorption spectscopic (XAS) analysis clearly show that Ni nanoparticles in Ni/graphene hybrid maintain its nanosized nature even after hybridization with graphene nanosheet (GNS). According to the TEM analysis, the Ni nanoparticles with an average size of 5.2 nm are homogeneously distributed onto the GNS in such a way that the nanoporous structure with much amount of void spaces could be fabricated. The obtained Ni/GNS exhibits a hydrogen storage capacity of 160 mA h/g, while the specific capacity of the graphene nanosheet was only 21 mA h/g. A flexible delaminated structure of Ni/GNS nanocomposite could provide additional intercalation sites for accommodation of hydrogen, leading to the enhancement of hydrogen storage capacity

  19. Internal hydrogen embrittlement of gamma-stabilized uranium alloys

    International Nuclear Information System (INIS)

    Powell, G.L.; Koger, J.W.; Bennett, R.K.; Williamson, A.L.; Hemperly, V.C.

    1976-01-01

    Relationships between the tensile ductility and fracture characteristics of as-quenched, gamma-stabilized uranium alloys (uranium--10 wt percent molybdenum, uranium--8.5 wt percent niobium, uranium--10 wt percent niobium, and uranium--7.5 wt percent niobium--2.5 wt percent zirconium), the hydrogen content of the tensile specimens, and the hydrogen gas pressure during the annealing at 850 0 C of the tensile test blanks prior to quenching were established. For these alloys, the tensile ductility decreases only slightly with increasing hydrogen content up to a critical hydrogen concentration above which the tensile ductility drops to nearly zero. The only alloy not displaying this sharp drop in tensile ductility was U--7.5 Nb--2.5 Zr, probably because sufficiently high hydrogen contents could not be achieved under our experimental arrangements. The critical hydrogen content for ductility loss increased with increasing hydrogen solubility in the alloy. Fracture surfaces produced by internal hydrogen embrittlement do not resemble those produced by stress corrosion cracking (SCC) in aqueous environments containing chloride ions. 8 figs

  20. Hydrogen Sensors Boost Hybrids; Today's Models Losing Gas?

    Science.gov (United States)

    2005-01-01

    Advanced chemical sensors are used in aeronautic and space applications to provide safety monitoring, emission monitoring, and fire detection. In order to fully do their jobs, these sensors must be able to operate in a range of environments. NASA has developed sensor technologies addressing these needs with the intent of improving safety, optimizing combustion efficiencies, and controlling emissions. On the ground, the chemical sensors were developed by NASA engineers to detect potential hydrogen leaks during Space Shuttle launch operations. The Space Shuttle uses a combination of hydrogen and oxygen as fuel for its main engines. Liquid hydrogen is pumped to the external tank from a storage tank located several hundred feet away. Any hydrogen leak could potentially result in a hydrogen fire, which is invisible to the naked eye. It is important to detect the presence of a hydrogen fire in order to prevent a major accident. In the air, the same hydrogen-leak dangers are present. Stress and temperature changes can cause tiny cracks or holes to form in the tubes that line the Space Shuttle s main engine nozzle. Such defects could allow the hydrogen that is pumped through the nozzle during firing to escape. Responding to the challenges associated with pinpointing hydrogen leaks, NASA endeavored to improve propellant leak-detection capabilities during assembly, pre-launch operations, and flight. The objective was to reduce the operational cost of assembling and maintaining hydrogen delivery systems with automated detection systems. In particular, efforts have been focused on developing an automated hydrogen leak-detection system using multiple, networked hydrogen sensors that are operable in harsh conditions.

  1. A dynamic simulation tool for the battery-hybrid hydrogen fuel cell vehicle

    Energy Technology Data Exchange (ETDEWEB)

    Moore, R.M. [Hawaii Natural Energy Institute, University of Hawaii, Manoa (United States); Ramaswamy, S.; Cunningham, J.M. [California Univ., Berkeley, CA (United States); Hauer, K.H. [xcellvision, Major-Hirst-Strasse 11, 38422 Wolfsburg (Germany)

    2006-10-15

    This paper describes a dynamic fuel cell vehicle simulation tool for the battery-hybrid direct-hydrogen fuel cell vehicle. The emphasis is on simulation of the hybridized hydrogen fuel cell system within an existing fuel cell vehicle simulation tool. The discussion is focused on the simulation of the sub-systems that are unique to the hybridized direct-hydrogen vehicle, and builds on a previous paper that described a simulation tool for the load-following direct-hydrogen vehicle. The configuration of the general fuel cell vehicle simulation tool has been previously presented in detail, and is only briefly reviewed in the introduction to this paper. Strictly speaking, the results provided in this paper only serve as an example that is valid for the specific fuel cell vehicle design configuration analyzed. Different design choices may lead to different results, depending strongly on the parameters used and choices taken during the detailed design process required for this highly non-linear and n-dimensional system. The primary purpose of this paper is not to provide a dynamic simulation tool that is the ''final word'' for the ''optimal'' hybrid fuel cell vehicle design. The primary purpose is to provide an explanation of a simulation method for analyzing the energetic aspects of a hybrid fuel cell vehicle. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

  2. Continuous flow hydrogenation using polysilane-supported palladium/alumina hybrid catalysts

    Directory of Open Access Journals (Sweden)

    Shū Kobayashi

    2011-05-01

    Full Text Available Continuous flow systems for hydrogenation using polysilane-supported palladium/alumina (Pd/(PSi–Al2O3 hybrid catalysts were developed. Our original Pd/(PSi–Al2O3 catalysts were used successfully in these systems and the hydrogenation of unsaturated C–C bonds and a nitro group, deprotection of a carbobenzyloxy (Cbz group, and a dehalogenation reaction proceeded smoothly. The catalyst retained high activity for at least 8 h under neat conditions.

  3. Experimental results with hydrogen fueled internal combustion engines

    Science.gov (United States)

    De Boer, P. C. T.; Mclean, W. J.; Homan, H. S.

    1975-01-01

    The paper focuses on the most important experimental findings for hydrogen-fueled internal combustion engines, with particular reference to the application of these findings to the assessment of the potential of hydrogen engines. Emphasis is on the various tradeoffs that can be made, such as between maximum efficiency, maximum power, and minimum NO emissions. The various possibilities for induction and ignition are described. Some projections are made about areas in which hydrogen engines may find their initial application and about optimum ways to design such engines. It is shown that hydrogen-fueled reciprocal internal combustion engines offer important advantages with respect to thermal efficiency and exhaust emissions. Problems arising from preignition can suitably be avoided by restricting the fuel-air equivalence ratio to values below about 0.5. The direct cylinder injection appears to be a very attractive way to operate the engine, because it combines a wide range of possible power outputs with a high thermal efficiency and very low NO emissions at part loads.

  4. Oxygen- and Lithium-Doped Hybrid Boron-Nitride/Carbon Networks for Hydrogen Storage.

    Science.gov (United States)

    Shayeganfar, Farzaneh; Shahsavari, Rouzbeh

    2016-12-20

    Hydrogen storage capacities have been studied on newly designed three-dimensional pillared boron nitride (PBN) and pillared graphene boron nitride (PGBN). We propose these novel materials based on the covalent connection of BNNTs and graphene sheets, which enhance the surface and free volume for storage within the nanomaterial and increase the gravimetric and volumetric hydrogen uptake capacities. Density functional theory and molecular dynamics simulations show that these lithium- and oxygen-doped pillared structures have improved gravimetric and volumetric hydrogen capacities at room temperature, with values on the order of 9.1-11.6 wt % and 40-60 g/L. Our findings demonstrate that the gravimetric uptake of oxygen- and lithium-doped PBN and PGBN has significantly enhanced the hydrogen sorption and desorption. Calculations for O-doped PGBN yield gravimetric hydrogen uptake capacities greater than 11.6 wt % at room temperature. This increased value is attributed to the pillared morphology, which improves the mechanical properties and increases porosity, as well as the high binding energy between oxygen and GBN. Our results suggest that hybrid carbon/BNNT nanostructures are an excellent candidate for hydrogen storage, owing to the combination of the electron mobility of graphene and the polarized nature of BN at heterojunctions, which enhances the uptake capacity, providing ample opportunities to further tune this hybrid material for efficient hydrogen storage.

  5. Hybrid Theory of Electron-Hydrogenic Systems Elastic Scattering

    Science.gov (United States)

    Bhatia, A. K.

    2007-01-01

    Accurate electron-hydrogen and electron-hydrogenic cross sections are required to interpret fusion experiments, laboratory plasma physics and properties of the solar and astrophysical plasmas. We have developed a method in which the short-range and long-range correlations can be included at the same time in the scattering equations. The phase shifts have rigorous lower bounds and the scattering lengths have rigorous upper bounds. The phase shifts in the resonance region can be used to calculate very accurately the resonance parameters.

  6. A hybrid HTGR system producing electricity, hydrogen and such other products as water demanded in the Middle East

    Energy Technology Data Exchange (ETDEWEB)

    Yan, X., E-mail: yan.xing@jaea.go.jp; Noguchi, H.; Sato, H.; Tachibana, Y.; Kunitomi, K.; Hino, R.

    2014-05-01

    Alternative energy products are being considered by the Middle East countries for both consumption and export. Electricity, water, and hydrogen produced not from oil and gas are amongst those desirable. A hybrid nuclear production system, GTHTR300C, under development in JAEA can achieve this regional strategic goal. The system is based on a 600 MWt HTGR and equipped to cogenerate electricity by gas turbine and seawater desalination by using only the nuclear plant waste heat. Hydrogen is produced via a thermochemical water-splitting process driven by the reactor's 950 °C heat. Additionally process steam may be produced for industrial uses. An example is shown of manufacturing soda ash, an internationally traded commodity, from using the steam produced and the brine discharged from desalination. The nuclear reactor satisfies nearly all energy requirements for the hybrid generations without emitting CO{sub 2}. The passive safety of the reactor as described in the paper permits proximity of siting the reactor with the production facilities to enhance energy transmission. Production flowsheet of the GTHTR300C is given for up to 300 MWe electricity, 58 t/day hydrogen, 56,000 m{sup 3}/day potable water, 3500 t/day steam, and 1000 t/day soda ash. The production thermal efficiency reaches 88%.

  7. Pd Nanoparticles and MOFs Synergistically Hybridized Halloysite Nanotubes for Hydrogen Storage

    Science.gov (United States)

    Jin, Jiao; Ouyang, Jing; Yang, Huaming

    2017-03-01

    Natural halloysite nanotubes (HNTs) were hybridized with metal-organic frameworks (MOFs) to prepare novel composites. MOFs were transformed into carbon by carbonization calcination, and palladium (Pd) nanoparticles were introduced to build an emerging ternary compound system for hydrogen adsorption. The hydrogen adsorption capacities of HNT-MOF composites were 0.23 and 0.24 wt%, while those of carbonized products were 0.24 and 0.27 wt% at 25 °C and 2.65 MPa, respectively. Al-based samples showed higher hydrogen adsorption capacities than Zn-based samples on account of different selectivity between metal and hydrogen and approximate porous characteristics. More pore structures are generated by the carbonization reaction from metal-organic frameworks into carbon; high specific surface area, uniform pore size, and large pore volume benefited the hydrogen adsorption ability of composites. Moreover, it was also possible to promote hydrogen adsorption capacity by incorporating Pd. The hydrogen adsorption capacity of ternary compound, Pd-C-H3-MOFs(Al), reached 0.32 wt% at 25 °C and 2.65 MPa. Dissociation was assumed to take place on the Pd particles, then atomic and molecule hydrogen spilled over to the structure of carboxylated HNTs, MOFs, and the carbon products for enhancing the hydrogen adsorption capacity.

  8. Pd Nanoparticles and MOFs Synergistically Hybridized Halloysite Nanotubes for Hydrogen Storage.

    Science.gov (United States)

    Jin, Jiao; Ouyang, Jing; Yang, Huaming

    2017-12-01

    Natural halloysite nanotubes (HNTs) were hybridized with metal-organic frameworks (MOFs) to prepare novel composites. MOFs were transformed into carbon by carbonization calcination, and palladium (Pd) nanoparticles were introduced to build an emerging ternary compound system for hydrogen adsorption. The hydrogen adsorption capacities of HNT-MOF composites were 0.23 and 0.24 wt%, while those of carbonized products were 0.24 and 0.27 wt% at 25 °C and 2.65 MPa, respectively. Al-based samples showed higher hydrogen adsorption capacities than Zn-based samples on account of different selectivity between metal and hydrogen and approximate porous characteristics. More pore structures are generated by the carbonization reaction from metal-organic frameworks into carbon; high specific surface area, uniform pore size, and large pore volume benefited the hydrogen adsorption ability of composites. Moreover, it was also possible to promote hydrogen adsorption capacity by incorporating Pd. The hydrogen adsorption capacity of ternary compound, Pd-C-H3-MOFs(Al), reached 0.32 wt% at 25 °C and 2.65 MPa. Dissociation was assumed to take place on the Pd particles, then atomic and molecule hydrogen spilled over to the structure of carboxylated HNTs, MOFs, and the carbon products for enhancing the hydrogen adsorption capacity.

  9. Graphene oxide – molybdenum disulfide hybrid membranes for hydrogen separation

    KAUST Repository

    Ostwal, Mayur

    2017-12-24

    Graphene oxide – molybdenum disulfide hybrid membranes were prepared using vacuum filtration technique. The thickness and the MoS2 content in the membranes were varied and their H2 permeance and H2/CO2 selectivity are reported. A 60nm hybrid membrane containing ~75% by weight of MoS2 exhibited the highest H2 permeance of 804×10−9mol/m2·s·Pa with corresponding H2/CO2 selectivity of 26.7; while a 150nm hybrid membrane with ~29% MoS2 showed the highest H2/CO2 selectivity of 44.2 with corresponding H2 permeance of 287×10−9mol/m2·s·Pa. The hybrid membranes exhibited much higher H2 permeance compared to graphene oxide membranes and higher selectivity compared to MoS2 membranes, which fully demonstrated the synergistic effect of both nanomaterials. The membranes also displayed excellent operational long-term stability.

  10. Graphene oxide – molybdenum disulfide hybrid membranes for hydrogen separation

    KAUST Repository

    Ostwal, Mayur; Shinde, Digambar B.; Wang, Xinbo; Gadwal, Ikhlas; Lai, Zhiping

    2017-01-01

    Graphene oxide – molybdenum disulfide hybrid membranes were prepared using vacuum filtration technique. The thickness and the MoS2 content in the membranes were varied and their H2 permeance and H2/CO2 selectivity are reported. A 60nm hybrid membrane containing ~75% by weight of MoS2 exhibited the highest H2 permeance of 804×10−9mol/m2·s·Pa with corresponding H2/CO2 selectivity of 26.7; while a 150nm hybrid membrane with ~29% MoS2 showed the highest H2/CO2 selectivity of 44.2 with corresponding H2 permeance of 287×10−9mol/m2·s·Pa. The hybrid membranes exhibited much higher H2 permeance compared to graphene oxide membranes and higher selectivity compared to MoS2 membranes, which fully demonstrated the synergistic effect of both nanomaterials. The membranes also displayed excellent operational long-term stability.

  11. Hydrogen storage behaviors of Ni-doped graphene Oxide/MIL-101 hybrid composites.

    Science.gov (United States)

    Lee, Seul-Yi; Park, Soo-Jin

    2013-01-01

    In this work, Ni-doped graphene oxide/MIL-101 hybrid composites (Ni--GO/MIL) were prepared to investigate their hydrogen storage behaviors. Ni--GO/MIL was synthesized by adding Ni--GO in situ during the synthesis of MIL-101 using a hydrothermal process, which was conducted by conventional convection heating with Cr(III) ion as a metal center and telephthalic acid as organic ligands. The crystalline structures and morphologies were measured by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The specific surface area and micropore volume were investigated by N2/77 K adsorption isotherms using the Brunauer-Emmett-Teller (BET) method and Dubinin-Radushkevic (D-R) equation, respectively. The hydrogen storage capacity was investigated by BEL-HP at 77 K and 1 bar. The obtained results show that Ni--GO/MIL presents new directions for achieving novel hybrid materials with higher hydrogen storage capacity.

  12. Laser-driven nuclear-polarized hydrogen internal gas target

    International Nuclear Information System (INIS)

    Seely, J.; Crawford, C.; Clasie, B.; Xu, W.; Dutta, D.; Gao, H.

    2006-01-01

    We report the performance of a laser-driven polarized internal hydrogen gas target (LDT) in a configuration similar to that used in scattering experiments. This target used the technique of spin-exchange optical pumping to produce nuclear spin polarized hydrogen gas that was fed into a cylindrical storage (target) cell. We present in this paper the performance of the target, methods that were tried to improve the figure-of-merit (FOM) of the target, and a Monte Carlo simulation of spin-exchange optical pumping. The dimensions of the apparatus were optimized using the simulation and the experimental results were in good agreement with the results from the simulation. The best experimental result achieved was at a hydrogen flow rate of 1.1x10 18 atoms/s, where the sample beam exiting the storage cell had 58.2% degree of dissociation and 50.5% polarization. Based on this measurement, the atomic fraction in the storage cell was 49.6% and the density averaged nuclear polarization was 25.0%. This represents the highest FOM for hydrogen from an LDT and is higher than the best FOM reported by atomic beam sources that used storage cells

  13. 15th International conference on Hybrid Intelligent Systems

    CERN Document Server

    Han, Sang; Al-Sharhan, Salah; Liu, Hongbo

    2016-01-01

    This book is devoted to the hybridization of intelligent systems which is a promising research field of modern computational intelligence concerned with the development of the next generation of intelligent systems. This Volume contains the papers presented in the Fifteenth International conference on Hybrid Intelligent Systems (HIS 2015) held in Seoul, South Korea during November 16-18, 2015. The 26 papers presented in this Volume were carefully reviewed and selected from 90 paper submissions. The Volume will be a valuable reference to researchers, students and practitioners in the computational intelligence field.

  14. Internal combustion engines fueled by natural gas-hydrogen mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Akansu, S.O.; Kahraman, N. [Erciyes University, Kayseri (Turkey). Engineering Faculty; Dulger, Z. [Kocaeli University (Turkey). Engineering Faculty; Veziroglu, T.N. [University of Miami, Coral Gables, FL (United States). College of Engineering

    2004-11-01

    In this study, a survey of research papers on utilization of natural gas-hydrogen mixtures in internal combustion engines is carried out. In general, HC, CO{sub 2}, and CO emissions decrease with increasing H{sub 2}, but NO{sub x} emissions generally increase. If a catalytic converter is used, NO{sub x} emission values can be decreased to extremely low levels. Consequently, equivalence zero emission vehicles (EZEV) standards may be reached. Efficiency values vary with H{sub 2} amount, spark timing, compression ratio, equivalence ratio, etc. Under certain conditions, efficiency values can be increased. In terms of BSFC, emissions and BTE, a mixture of low hydrogen percentage is suitable for using. (author)

  15. Reconfiguration of photovoltaic panels for reducing the hydrogen consumption in fuel cells of hybrid systems

    Directory of Open Access Journals (Sweden)

    Daniel González-Montoya

    2017-05-01

    Full Text Available Hybrid generation combines advantages from fuel cell systems with non-predictable generation approaches, such as photovoltaic and wind generators. In such hybrid systems, it is desirable to minimize as much as possible the fuel consumption, for the sake of reducing costs and increasing the system autonomy. This paper proposes an optimization algorithm, referred to as population-based incremental learning, in order to maximize the produced power of a photovoltaic generator. This maximization reduces the fuel consumption in the hybrid aggregation. Moreover, the algorithm's speed enables the real-time computation of the best configuration for the photovoltaic system, which also optimizes the fuel consumption in the complementary fuel cell system. Finally, a system experimental validation is presented considering 6 photovoltaic modules and a NEXA 1.2KW fuel cell. Such a validation demonstrates the effectiveness of the proposed algorithm to reduce the hydrogen consumption in these hybrid systems.

  16. Hybrid fiber gratings coated with a catalytic sensitive layer for hydrogen sensing in air.

    Science.gov (United States)

    Caucheteur, Christophe; Debliquy, Marc; Lahem, Driss; Megret, Patrice

    2008-10-13

    Using hydrogen as fuel presents a potential risk of explosion and requires low cost and efficient leak sensors. We present here a hybrid sensor configuration consisting of a long period fiber grating (LPFG) and a superimposed uniform fiber Bragg grating (FBG). Both gratings are covered with a sensitive layer made of WO(3) doped with Pt on which H(2) undergoes an exothermic reaction. The released heat increases the temperature around the gratings. In this configuration, the LPFG favors the exothermic reaction thanks to a light coupling to the sensitive layer while the FBG reflects the temperature change linked to the hydrogen concentration. Our sensor is very fast and suitable to detect low hydrogen concentrations in air whatever the relative humidity level and for temperatures down to -50 degrees C, which is without equivalent for other hydrogen optical sensors reported so far.

  17. Numerical and experimental analysis of heat transfer in injector plate of hydrogen peroxide hybrid rocket motor

    Science.gov (United States)

    Cai, Guobiao; Li, Chengen; Tian, Hui

    2016-11-01

    This paper is aimed to analyze heat transfer in injector plate of hydrogen peroxide hybrid rocket motor by two-dimensional axisymmetric numerical simulations and full-scale firing tests. Long-time working, which is an advantage of hybrid rocket motor over conventional solid rocket motor, puts forward new challenges for thermal protection. Thermal environments of full-scale hybrid rocket motors designed for long-time firing tests are studied through steady-state coupled numerical simulations of flow field and heat transfer in chamber head. The motor adopts 98% hydrogen peroxide (98HP) oxidizer and hydroxyl-terminated poly-butadiene (HTPB) based fuel as the propellants. Simulation results reveal that flowing liquid 98HP in head oxidizer chamber could cool the injector plate of the motor. The cooling of 98HP is similar to the regenerative cooling in liquid rocket engines. However, the temperature of the 98HP in periphery portion of the head oxidizer chamber is higher than its boiling point. In order to prevent the liquid 98HP from unexpected decomposition, a thermal protection method for chamber head utilizing silica-phenolics annular insulating board is proposed. The simulation results show that the annular insulating board could effectively decrease the temperature of the 98HP in head oxidizer chamber. Besides, the thermal protection method for long-time working hydrogen peroxide hybrid rocket motor is verified through full-scale firing tests. The ablation of the insulating board in oxygen-rich environment is also analyzed.

  18. Energy Management and Simulation of Photovoltaic/Hydrogen /Battery Hybrid Power System

    Directory of Open Access Journals (Sweden)

    Tariq Kamal

    2016-06-01

    Full Text Available This manuscript focuses on a hybrid power system combining a solar photovoltaic array and energy storage system based on hydrogen technology (fuel cell, hydrogen tank and electrolyzer and battery. The complete architecture is connected to the national grid through power converters to increase the continuity of power. The proposed a hybrid power system is designed to work under classical-based energy management algorithm. According to the proposed algorithm, the PV has the priority in meeting the load demands. The hydrogen technology is utilized to ensure long-term energy balance. The battery is used as a backup and/or high power device to take care of the load following problems of hydrogen technology during transient. The dynamic performance of a hybrid power system is tested under different solar radiation, temperature and load conditions for the simulation of 24 Hrs. The effectiveness of the proposed system in terms of power sharing, grid stability, power quality and voltage regulation is verified by Matlab simulation results.

  19. Tetra-n-butylammonium borohydride semiclathrate: a hybrid material for hydrogen storage.

    Science.gov (United States)

    Shin, Kyuchul; Kim, Yongkwan; Strobel, Timothy A; Prasad, P S R; Sugahara, Takeshi; Lee, Huen; Sloan, E Dendy; Sum, Amadeu K; Koh, Carolyn A

    2009-06-11

    In this study, we demonstrate that tetra-n-butylammonium borohydride [(n-C(4)H(9))(4)NBH(4)] can be used to form a hybrid hydrogen storage material. Powder X-ray diffraction measurements verify the formation of tetra-n-butylammonium borohydride semiclathrate, while Raman spectroscopic and direct gas release measurements confirm the storage of molecular hydrogen within the vacant cavities. Subsequent to clathrate decomposition and the release of physically bound H(2), additional hydrogen was produced from the hybrid system via a hydrolysis reaction between the water host molecules and the incorporated BH(4)(-) anions. The additional hydrogen produced from the hydrolysis reaction resulted in a 170% increase in the gravimetric hydrogen storage capacity, or 27% greater storage than fully occupied THF + H(2) hydrate. The decomposition temperature of tetra-n-butylammonium borohydride semiclathrate was measured at 5.7 degrees C, which is higher than that for pure THF hydrate (4.4 degrees C). The present results reveal that the BH(4)(-) anion is capable of stabilizing tetraalkylammonium hydrates.

  20. Comprehensive Understanding of Ductility Loss Mechanisms in Various Steels with External and Internal Hydrogen

    Science.gov (United States)

    Takakuwa, Osamu; Yamabe, Junichiro; Matsunaga, Hisao; Furuya, Yoshiyuki; Matsuoka, Saburo

    2017-11-01

    Hydrogen-induced ductility loss and related fracture morphologies are comprehensively discussed in consideration of the hydrogen distribution in a specimen with external and internal hydrogen by using 300-series austenitic stainless steels (Types 304, 316, 316L), high-strength austenitic stainless steels (HP160, XM-19), precipitation-hardened iron-based super alloy (A286), low-alloy Cr-Mo steel (JIS-SCM435), and low-carbon steel (JIS-SM490B). External hydrogen is realized by a non-charged specimen tested in high-pressure gaseous hydrogen, and internal hydrogen is realized by a hydrogen-charged specimen tested in air or inert gas. Fracture morphologies obtained by slow-strain-rate tensile tests (SSRT) of the materials with external or internal hydrogen could be comprehensively categorized into five types: hydrogen-induced successive crack growth, ordinary void formation, small-sized void formation related to the void sheet, large-sized void formation, and facet formation. The mechanisms of hydrogen embrittlement are broadly classified into hydrogen-enhanced decohesion (HEDE) and hydrogen-enhanced localized plasticity (HELP). In the HEDE model, hydrogen weakens interatomic bonds, whereas in the HELP model, hydrogen enhances localized slip deformations. Although various fracture morphologies are produced by external or internal hydrogen, these morphologies can be explained by the HELP model rather than by the HEDE model.

  1. Study of hydrogen engine for a hybrid electric vehicle. 1; Hybrid denki jidoshayo suiso engine ni kansuru kenkyu. 1

    Energy Technology Data Exchange (ETDEWEB)

    Iguchi, T.; Numata, T. Hiruma, M.; Yamane, K.; Nakajima, Y.; Furuhama, S. [Musashi Institute of Technology, Tokyo (Japan); Takagi, Y. [Nissan Motor Co. Ltd., Tokyo (Japan)

    1998-10-15

    Study was made on application of a hydrogen engine to series hybrid electric vehicle (SHEV). Power of 20kW (for steady driving of a vehicle of 1t in total weight on flat road surface at 100km/h), and NOx emission concentration equivalent to that of EZEV (equivalent zero emission vehicle) were used as target performance. One of the merits of using a hydrogen engine for HEV is that conventional high-reliability gasoline engines can be used as hydrogen engines only by a bit of modification. A modified conventional 4-cylinder 4-cycle gasoline engine was used for this study. Hydrogen gas was continuously supplied through an intake manifold for premixed combustion by spark ignition. Brake thermal efficiency was improved from 30.5% to 35.5% by use of a high compression ratio and reduction of friction loss. NOx emission concentration could be controlled within 10ppm by ultra-lean combustion even at excess air ratios over 2.5. Both high efficiency and low emission were achieved at the same time around 3000rpm in engine revolution. 4 refs., 12 figs., 1 tab.

  2. The developments of international hydrogen and fuel cell technology standards and the response strategies in Taiwan

    International Nuclear Information System (INIS)

    Tso, C.

    2009-01-01

    The application of hydrogen and fuel cells has expanded as the technology in international markets has improved. Leading countries have focused on establishing hydrogen and fuel cell technology standards. Both the International Organization for Standardization (ISO) and the International Electrotechnical Commission (IEC) continuously release new hydrogen and fuel cell related standards. Although the government of Taiwan is promoting the development of a hydrogen and fuel cell industry, it may delay the commercialized schedule if there are no hydrogen and fuel cell related standards and regulations in place. Standards and regulations must be established as quickly as possible in order to accelerate the progress of the hydrogen and fuel cell industry. This presentation reviewed the international progress in hydrogen and fuel cell development and explained Taiwan's response strategies regarding the adoption of hydrogen and fuel cell products in niche Taiwanese markets

  3. Complete modeling and software implementation of a virtual solar hydrogen hybrid system

    International Nuclear Information System (INIS)

    Pedrazzi, S.; Zini, G.; Tartarini, P.

    2010-01-01

    A complete mathematical model and software implementation of a solar hydrogen hybrid system has been developed and applied to real data. The mathematical model has been derived from sub-models taken from literature with appropriate modifications and improvements. The model has been implemented as a stand-alone virtual energy system in a model-based, multi-domain software environment. A test run has then been performed on typical residential user data-sets over a year-long period. Results show that the virtual hybrid system can bring about complete grid independence; in particular, hydrogen production balance is positive (+1.25 kg) after a year's operation with a system efficiency of 7%.

  4. Enhanced hydrogen storage in sandwich-structured rGO/Co1-xS/rGO hybrid papers through hydrogen spillover

    Science.gov (United States)

    Han, Lu; Qin, Wei; Jian, Jiahuang; Liu, Jiawei; Wu, Xiaohong; Gao, Peng; Hultman, Benjamin; Wu, Gang

    2017-08-01

    Reduced graphene oxide (rGO) based two-dimensional (2D) structures have been fabricated for electrochemical hydrogen storage. However, the effective transfer of atomic hydrogen to adjacent rGO surfaces is suppressed by binders, which are widely used in conventional electrochemical hydrogen storage electrodes, leading to a confining of the performance of rGO for hydrogen storage. As a proof of concept experiment, a novel strategy is developed to fabricate the binder-free sandwich-structured rGO/Co1-xS/rGO hybrid paper via facile ball milling and filtration process. Based on the structure investigation, Co1-xS is immobilized in the space between the individual rGO sheets by the creation of chemical "bridges" (Csbnd S bonds). Through the Csbnd S bonds, the atomic hydrogen is transferred from Co1-xS to rGO accompanying a Csbnd H chemical bond formation. When used as an electrode, the hybrid paper exhibits an improved hydrogen storage capacity of 3.82 wt% and, most importantly, significant cycling stability for up to 50 cycles. Excluding the direct hydrogen storage contribution from the Co1-xS in the hybrid paper, the hydrogen storage ability of rGO is enhanced by 10× through the spillover effects caused by the Co1-xS modifier.

  5. IEA hydrogen agreement, task 15: photobiological hydrogen production - an international collaboration

    International Nuclear Information System (INIS)

    Lindblad, P.; Asada, Y.; Benemann, J.; Hallenbeck, P.; Melis, A.; Miyake, J.; Seibert, M.; Skulberg, O.

    2000-01-01

    Biological hydrogen production, the production of H 2 by microorganisms, has been an active field of basic and applied research for many years. Realization of practical processes for photobiological hydrogen production from water using solar energy would result in a major, novel source of sustainable and renewable energy, without greenhouse gas emissions or environmental pollution. However, development of such processes requires significant scientific and technological advances, and long-term basic and applied R and D. This International Energy Agency (lEA) Task covers research areas and needs at the interface of basic and applied R and D which are of mutual interest to the countries and researchers participating in the lEA Hydrogen Agreement. The overall objective is to sufficiently advance the basic and early-stage applied science in this area of research over the next five years to allow an evaluation of the potential of such a technology to be developed as a practical renewable energy source for the 21st Century. (author)

  6. A lignite-geothermal hybrid power and hydrogen production plant for green cities and sustainable buildings

    Energy Technology Data Exchange (ETDEWEB)

    Kilkis, B. [Baskent University, Ankara (Turkey). Dept. of Mechanical Engineering

    2011-02-15

    Turkey is rich in both geothermal energy and lignite reserves, which in many cases, are co-located. This condition makes it feasible to utilize both lignite and geothermal energy in a hybrid form for combined power heat, and cold generation, which may lead to optimally energy and exergy efficient, environmentally benign, and economically sound applications. This paper presents a novel concept of hybrid lignite-geothermal plant for a district energy system and hydrogen production facility in Aydin with special emphasis on high performance, green buildings and green districts. In this concept, lignite is first introduced to a partially fluidized-bed gasifier and then to a fluidized-bed gas cleaning unit, which produces synthetic gas and finally hydrogen. The by-products, namely char and ash are used in a fluidized-bed combustor to produce power. Waste heat from all these steps are utilized in a district heating system along with heat received from geothermal production wells after power is generated there. H{sub 2}S gas obtained from the separator system is coupled with hydrogen production process at the lignite plant. Absorption cooling systems and thermal storage tanks complement the hybrid system for the tri-generation district energy system. On the demand side, the new, green OSTIM OSB administration building in Ankara is exemplified for greener, low-exergy buildings that will compound the environmental benefits.

  7. Combustion characteristics of natural gas-hydrogen hybrid fuel turbulent diffusion flame

    Energy Technology Data Exchange (ETDEWEB)

    El-Ghafour, S.A.A.; El-dein, A.H.E.; Aref, A.A.R. [Mechanical Power Engineering Department, Faculty of Engineering, Suez Canal University, Port-Said (Egypt)

    2010-03-15

    Combustion characteristics of natural gas - hydrogen hybrid fuel were investigated experimentally in a free jet turbulent diffusion flame flowing into a slow co-flowing air stream. Experiments were carried out at a constant jet exit Reynolds number of 4000 and with a wide range of NG-H{sub 2} mixture concentrations, varied from 100%NG to 50%NG-50% H{sub 2} by volume. The effect of hydrogen addition on flame stability, flame length, flame structure, exhaust species concentration and pollutant emissions was conducted. Results showed that, hydrogen addition sustains a progressive improvement in flame stability and reduction in flame length, especially for relatively high hydrogen concentrations. Hydrogen-enriched flames found to have a higher combustion temperatures and reactivity than natural gas flame. Also, it was found that hydrogen addition to natural gas is an ineffective strategy for NO and CO reduction in the studied range, while a significant reduction in the %CO{sub 2} molar concentration by about 30% was achieved. (author)

  8. A hydrogen production experiment by the thermo-chemical and electrolytic hybrid hydrogen production in lower temperature range. System viability and preliminary thermal efficiency estimation

    International Nuclear Information System (INIS)

    Takai, Toshihide; Nakagiri, Toshio; Inagaki, Yoshiyuki

    2008-10-01

    A new experimental apparatus by the thermo-chemical and electrolytic Hybrid-Hydrogen production in Lower Temperature range (HHLT) was developed and hydrogen production experiment was performed to confirm the system operability. Hydrogen production efficiency was estimated and technical problems were clarified through the experimental results. Stable operation of the SO 3 electrolysis cell and the sulfur dioxide solution electrolysis cell were confirmed during experimental operation and any damage which would be affected solid operation was not detected under post operation inspection. To improve hydrogen production efficiency, it was found that the reduction of sulfuric acid circulation and the decrease in the cell voltage were key issues. (author)

  9. The Economic Potential of Nuclear-Renewable Hybrid Energy Systems Producing Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Ruth, Mark [National Renewable Energy Lab. (NREL), Golden, CO (United States); Cutler, Dylan [National Renewable Energy Lab. (NREL), Golden, CO (United States); Flores-Espino, Francisco [National Renewable Energy Lab. (NREL), Golden, CO (United States); Stark, Greg [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2017-04-01

    This report is one in a series of reports that Idaho National Laboratory and the Joint Institute for Strategic Energy Analysis are publishing that address the technical and economic aspects of nuclear-renewable hybrid energy systems (N-R HESs). This report discusses an analysis of the economic potential of a tightly coupled N-R HES that produces electricity and hydrogen. Both low and high temperature electrolysis options are considered in the analysis. Low-temperature electrolysis requires only electricity to convert water to hydrogen. High temperature electrolysis requires less electricity because it uses both electricity and heat to provide the energy necessary to electrolyze water. The study finds that, to be profitable, the examined high-temperature electrosis and low-temperature electrosis N-R HES configurations that produce hydrogen require higher electricity prices, more electricity price volatility, higher natural gas prices, or higher capacity payments than the reference case values of these parameters considered in this analysis.

  10. Hybrid Molten Bed Gasifier for High Hydrogen Syngas Production

    Energy Technology Data Exchange (ETDEWEB)

    Rue, David [Gas Technology Institute, Des Plaines, IL (United States)

    2017-05-23

    The techno-economic analyses of the hybrid molten bed gasification technology and laboratory testing of the HMB process were carried out in this project by the Gas Technology Institute and partner Nexant, Inc. under contract with the US Department of Energy’s National Energy Technology Laboratory. This report includes the results of two complete IGCC and Fischer-Tropsch TEA analyses comparing HMB gasification with the Shell slagging gasification process as a base case. Also included are the results of the laboratory simulation tests of the HMB process using Illinois #6 coal fed along with natural gas, two different syngases, and steam. Work in this 18-month project was carried out in three main Tasks. Task 2 was completed first and involved modeling, mass and energy balances, and gasification process design. The results of this work were provided to Nexant as input to the TEA IGCC and FT configurations studied in detail in Task 3. The results of Task 2 were also used to guide the design of the laboratory-scale testing of the HMB concept in the submerged combustion melting test facility in GTI’s industrial combustion laboratory. All project work was completed on time and budget. A project close-out meeting reviewing project results was conducted on April 1, 2015 at GTI in Des Plaines, IL. The hybrid molten bed gasification process techno-economic analyses found that the HMB process is both technically and economically attractive compared with the Shell entrained flow gasification process. In IGCC configuration, HMB gasification provides both efficiency and cost benefits. In Fischer-Tropsch configuration, HMB shows small benefits, primarily because even at current low natural gas prices, natural gas is more expensive than coal on an energy cost basis. HMB gasification was found in the TEA to improve the overall IGCC economics as compared to the coal only Shell gasification process. Operationally, the HMB process proved to be robust and easy to operate. The burner

  11. Comparative analysis of battery electric, hydrogen fuel cell and hybrid vehicles in a future sustainable road transport system

    International Nuclear Information System (INIS)

    Offer, G.J.; Howey, D.; Contestabile, M.; Clague, R.; Brandon, N.P.

    2010-01-01

    This paper compares battery electric vehicles (BEV) to hydrogen fuel cell electric vehicles (FCEV) and hydrogen fuel cell plug-in hybrid vehicles (FCHEV). Qualitative comparisons of technologies and infrastructural requirements, and quantitative comparisons of the lifecycle cost of the powertrain over 100,000 mile are undertaken, accounting for capital and fuel costs. A common vehicle platform is assumed. The 2030 scenario is discussed and compared to a conventional gasoline-fuelled internal combustion engine (ICE) powertrain. A comprehensive sensitivity analysis shows that in 2030 FCEVs could achieve lifecycle cost parity with conventional gasoline vehicles. However, both the BEV and FCHEV have significantly lower lifecycle costs. In the 2030 scenario, powertrain lifecycle costs of FCEVs range from $7360 to $22,580, whereas those for BEVs range from $6460 to $11,420 and FCHEVs, from $4310 to $12,540. All vehicle platforms exhibit significant cost sensitivity to powertrain capital cost. The BEV and FCHEV are relatively insensitive to electricity costs but the FCHEV and FCV are sensitive to hydrogen cost. The BEV and FCHEV are reasonably similar in lifecycle cost and one may offer an advantage over the other depending on driving patterns. A key conclusion is that the best path for future development of FCEVs is the FCHEV.

  12. Comparative analysis of battery electric, hydrogen fuel cell and hybrid vehicles in a future sustainable road transport system

    Energy Technology Data Exchange (ETDEWEB)

    Offer, G.J.; Brandon, N.P. [Department Earth Science Engineering, Imperial College London, SW7 2AZ (United Kingdom); Howey, D. [Department of Electrical and Electronic Engineering, Imperial College London, SW7 2AZ (United Kingdom); Contestabile, M. [Centre for Environmental Policy, Imperial College London, SW7 2AZ (United Kingdom); Clague, R. [Energy Futures Lab, Imperial College London, SW7 2AZ (United Kingdom)

    2010-01-15

    This paper compares battery electric vehicles (BEV) to hydrogen fuel cell electric vehicles (FCEV) and hydrogen fuel cell plug-in hybrid vehicles (FCHEV). Qualitative comparisons of technologies and infrastructural requirements, and quantitative comparisons of the lifecycle cost of the powertrain over 100,000 mile are undertaken, accounting for capital and fuel costs. A common vehicle platform is assumed. The 2030 scenario is discussed and compared to a conventional gasoline-fuelled internal combustion engine (ICE) powertrain. A comprehensive sensitivity analysis shows that in 2030 FCEVs could achieve lifecycle cost parity with conventional gasoline vehicles. However, both the BEV and FCHEV have significantly lower lifecycle costs. In the 2030 scenario, powertrain lifecycle costs of FCEVs range from $7360 to $22,580, whereas those for BEVs range from $6460 to $11,420 and FCHEVs, from $4310 to $12,540. All vehicle platforms exhibit significant cost sensitivity to powertrain capital cost. The BEV and FCHEV are relatively insensitive to electricity costs but the FCHEV and FCV are sensitive to hydrogen cost. The BEV and FCHEV are reasonably similar in lifecycle cost and one may offer an advantage over the other depending on driving patterns. A key conclusion is that the best path for future development of FCEVs is the FCHEV. (author)

  13. Carbon hybridized halloysite nanotubes for high-performance hydrogen storage capacities

    Science.gov (United States)

    Jin, Jiao; Fu, Liangjie; Yang, Huaming; Ouyang, Jing

    2015-01-01

    Hybrid nanotubes of carbon and halloysite nanotubes (HNTs) with different carbon:HNTs ratio were hydrothermally synthesized from natural halloysite and sucrose. The samples display uniformly cylindrical hollow tubular structure with different morphologies. These hybrid nanotubes were concluded to be promising medium for physisorption-based hydrogen storage. The hydrogen adsorption capacity of pristine HNTs was 0.35% at 2.65 MPa and 298 K, while that of carbon coated HNTs with the pre-set carbon:HNTs ratio of 3:1 (3C-HNTs) was 0.48% under the same condition. This carbon coated method could offer a new pattern for increasing the hydrogen adsorption capacity. It was also possible to enhance the hydrogen adsorption capacity through the spillover mechanism by incorporating palladium (Pd) in the samples of HNTs (Pd-HNTs) and 3C-HNTs (Pd-3C-HNTs and 3C-Pd-HNTs are the samples with different location of Pd nanoparticles). The hydrogen adsorption capacity of the Pd-HNTs was 0.50% at 2.65 MPa and 298 K, while those of Pd-3C-HNTs and 3C-Pd-HNTs were 0.58% and 0.63%, respectively. In particular, for this spillover mechanism of Pd-carbon-HNTs ternary system, the bidirectional transmission of atomic and molecular hydrogen (3C-Pd-HNTs) was concluded to be more effective than the unidirectional transmission (Pd-3C-HNTs) in this work for the first time. PMID:26201827

  14. Proceedings of the 5th International workshop on hydrogen and fuel cells WICaC 2010

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    The 5th International Workshop on Hydrogen and Fuel Cells - WICaC 2010 aims to bring the most recent advances on fuel cell and hydrogen technologies. The conference will address the trends on hydrogen production, distribution, delivery, storage and infrastructure as well as fuel cell research, development, demonstration and commercialization. Some of the issues addressed at WICaC 2010 are: the official Brazilian hydrogen and fuel cell programs and its participation in the international programs and partnerships such as the IPHE (The International Partnership for Hydrogen and Fuel Cells in the Economy); the integration of renewable energy sources with hydrogen and fuel cell systems; the challenges to deploy the commercialization and use of fuel cells and hydrogen; distributed generation of energy; fuel cell uses in portable devices and in vehicles; life-cycle assessment of fuel cells and hydrogen technologies; environmental aspects; energy efficiency.

  15. Laser-driven polarized hydrogen and deuterium internal targets

    International Nuclear Information System (INIS)

    Jones, C.E.; Fedchak, J.A.; Kowalczyk, R.S.

    1995-01-01

    After completing comprehensive tests of the performance of the source with both hydrogen and deuterium gas, we began tests of a realistic polarized deuterium internal target. These tests involve characterizing the atomic polarization and dissociation fraction of atoms in a storage cell as a function of flow and magnetic field, and making direct measurements of the average nuclear tensor polarization of deuterium atoms in the storage cell. Transfer of polarization from the atomic electron to the nucleus as a result of D-D spin-exchange collisions was observed in deuterium, verifying calculations suggesting that high vector polarization in both hydrogen and deuterium can be obtained in a gas in spin temperature equilibrium without inducing RF transitions between the magnetic substates. In order to improve the durability of the system, the source glassware was redesigned to simplify construction and installation and eliminate stress points that led to frequent breakage. Improvements made to the nuclear polarimeter, which used the low energy 3 H(d,n) 4 He reaction to analyze the tensor polarization of the deuterium, included installing acceleration lenses constructed of wire mesh to improve pumping conductance, construction of a new holding field coil, and elimination of the Wien filter from the setup. These changes substantially simplified operation of the polarimeter and should have reduced depolarization in collisions with the wall. However, when a number of tests failed to show an improvement of the nuclear polarization, it was discovered that extended operation of the system with a section of teflon as a getter for potassium caused the dissociation fraction to decline with time under realistic operating conditions, suggesting that teflon may not be a suitable material to eliminate potassium from the target. We are replacing the teflon surfaces with drifilm-coated ones and plan to continue tests of the polarized internal target in this configuration

  16. Hydrogen enrichment of an internal combustion engine via closed loop thermochemical recuperation

    NARCIS (Netherlands)

    Zwitserlood, J.G.; Hofman, T.; Erickson, P.A.

    2013-01-01

    Hydrogen enrichment in an internal combustion engine can greatly improve efficiency and at the same time reduce emissions without the need for extensive engine modifications. One option for a hydrogen source for the enrichment is actively producing hydrogen on-board the vehicle through steam

  17. Design of Hydrogen Storage Alloys/Nanoporous Metals Hybrid Electrodes for Nickel-Metal Hydride Batteries

    Science.gov (United States)

    Li, M. M.; Yang, C. C.; Wang, C. C.; Wen, Z.; Zhu, Y. F.; Zhao, M.; Li, J. C.; Zheng, W. T.; Lian, J. S.; Jiang, Q.

    2016-06-01

    Nickel metal hydride (Ni-MH) batteries have demonstrated key technology advantages for applications in new-energy vehicles, which play an important role in reducing greenhouse gas emissions and the world’s dependence on fossil fuels. However, the poor high-rate dischargeability of the negative electrode materials—hydrogen storage alloys (HSAs) limits applications of Ni-MH batteries in high-power fields due to large polarization. Here we design a hybrid electrode by integrating HSAs with a current collector of three-dimensional bicontinuous nanoporous Ni. The electrode shows enhanced high-rate dischargeability with the capacity retention rate reaching 44.6% at a discharge current density of 3000 mA g-1, which is 2.4 times that of bare HSAs (18.8%). Such a unique hybrid architecture not only enhances charge transfer between nanoporous Ni and HSAs, but also facilitates rapid diffusion of hydrogen atoms in HSAs. The developed HSAs/nanoporous metals hybrid structures exhibit great potential to be candidates as electrodes in high-performance Ni-MH batteries towards applications in new-energy vehicles.

  18. DNA hybridization kinetics: zippering, internal displacement and sequence dependence.

    Science.gov (United States)

    Ouldridge, Thomas E; Sulc, Petr; Romano, Flavio; Doye, Jonathan P K; Louis, Ard A

    2013-10-01

    Although the thermodynamics of DNA hybridization is generally well established, the kinetics of this classic transition is less well understood. Providing such understanding has new urgency because DNA nanotechnology often depends critically on binding rates. Here, we explore DNA oligomer hybridization kinetics using a coarse-grained model. Strand association proceeds through a complex set of intermediate states, with successful binding events initiated by a few metastable base-pairing interactions, followed by zippering of the remaining bonds. But despite reasonably strong interstrand interactions, initial contacts frequently dissociate because typical configurations in which they form differ from typical states of similar enthalpy in the double-stranded equilibrium ensemble. Initial contacts must be stabilized by two or three base pairs before full zippering is likely, resulting in negative effective activation enthalpies. Non-Arrhenius behavior arises because the number of base pairs required for nucleation increases with temperature. In addition, we observe two alternative pathways-pseudoknot and inchworm internal displacement-through which misaligned duplexes can rearrange to form duplexes. These pathways accelerate hybridization. Our results explain why experimentally observed association rates of GC-rich oligomers are higher than rates of AT- rich equivalents, and more generally demonstrate how association rates can be modulated by sequence choice.

  19. FY 2000 Project of international clean energy network using hydrogen conversion (WE-NET)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the FY 2000 results of the research and development project aimed at construction of the international clean energy network using hydrogen conversion (WE-NET). The projects include 12 tasks; system evaluation for, e.g., optimum scenario for introduction of hydrogen energy; experiments for hydrogen safety; study on the international cooperation for WE-NET; development of power generation technology using a 100kW cogeneration system including hydrogen-firing diesel engine; developmental research on vehicles driven by a hydrogen fuel cell system; developmental research on the basic technologies for PEFC utilizing pure hydrogen; developmental research on a 30Nm{sup 3}/hour hydrogen refueling station for vehicles; developmental research on hydrogen production technology; developmental research on hydrogen transportation and storage technology, e.g., liquid hydrogen pump; research and development of the databases of and processing technology for cryogenic materials exposed to liquid hydrogen; developmental research on hydrogen absorbing alloys for small-scale hydrogen transportation and storage systems; and study on innovative and leading technologies. (NEDO)

  20. Computational hybrid anthropometric paediatric phantom library for internal radiation dosimetry

    Science.gov (United States)

    Xie, Tianwu; Kuster, Niels; Zaidi, Habib

    2017-04-01

    Hybrid computational phantoms combine voxel-based and simplified equation-based modelling approaches to provide unique advantages and more realism for the construction of anthropomorphic models. In this work, a methodology and C++ code are developed to generate hybrid computational phantoms covering statistical distributions of body morphometry in the paediatric population. The paediatric phantoms of the Virtual Population Series (IT’IS Foundation, Switzerland) were modified to match target anthropometric parameters, including body mass, body length, standing height and sitting height/stature ratio, determined from reference databases of the National Centre for Health Statistics and the National Health and Nutrition Examination Survey. The phantoms were selected as representative anchor phantoms for the newborn, 1, 2, 5, 10 and 15 years-old children, and were subsequently remodelled to create 1100 female and male phantoms with 10th, 25th, 50th, 75th and 90th body morphometries. Evaluation was performed qualitatively using 3D visualization and quantitatively by analysing internal organ masses. Overall, the newly generated phantoms appear very reasonable and representative of the main characteristics of the paediatric population at various ages and for different genders, body sizes and sitting stature ratios. The mass of internal organs increases with height and body mass. The comparison of organ masses of the heart, kidney, liver, lung and spleen with published autopsy and ICRP reference data for children demonstrated that they follow the same trend when correlated with age. The constructed hybrid computational phantom library opens up the prospect of comprehensive radiation dosimetry calculations and risk assessment for the paediatric population of different age groups and diverse anthropometric parameters.

  1. Reversible transient hydrogen storage in a fuel cell-supercapacitor hybrid device.

    Science.gov (United States)

    Unda, Jesus E Zerpa; Roduner, Emil

    2012-03-21

    A new concept is investigated for hydrogen storage in a supercapacitor based on large-surface-area carbon material (Black Pearls 2000). Protons and electrons of hydrogen are separated on a fuel cell-type electrode and then stored separately in the electrical double layer, the electrons on the carbon and the protons in the aqueous electrolyte of the supercapacitor electrode. The merit of this concept is that it works spontaneously and reversibly near ambient pressure and temperature. This is in pronounced contrast to what has been known as electrochemical hydrogen storage, which does not involve hydrogen gas and where electrical work has to be spent in the loading process. With the present hybrid device, a H(2) storage capacity of 0.13 wt% was obtained, one order of magnitude more than what can be stored by conventional physisorption on large-surface-area carbons at the same pressure and temperature. Raising the pressure from 1.5 to 3.5 bar increased the capacity by less than 20%, indicating saturation. A capacitance of 11 μF cm(-2), comparable with that of a commercial double layer supercapacitor, was found using H(2)SO(4) as electrolyte. The chemical energy of the stored H(2) is almost a factor of 3 larger than the electrical energy stored in the supercapacitor. Further developments of this concept relate to a hydrogen buffer integrated inside a proton exchange membrane fuel cell to be used in case of peak power demand. This serial setup takes advantage of the suggested novel concept of hydrogen storage. It is fundamentally different from previous ways of operating a conventional supercapacitor hooked up in parallel to a fuel cell.

  2. Hydrogen Peroxide and Ozone Formation in Hybrid Gas-Liquid Electrical Discharge Reactors

    Czech Academy of Sciences Publication Activity Database

    Lukeš, Petr; Appleton, A. T.; Locke, B. R.

    2004-01-01

    Roč. 40, č. 1 (2004), s. 60-67 ISSN 0093-9994. [IEEE Industry Applications Society Annual Meeting 2002/37th./. Pittsburgh, Pennsylvania , 13.10.2002-18.10.2002] R&D Projects: GA ČR GA202/02/1026; GA MŠk ME 472 Grant - others:NSF(US) INT0086351 Keywords : hydrogen peroxide, ozone, corona discharge, water treatment, hybrid reactor Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 0.987, year: 2004

  3. Polyaniline nanowires-gold nanoparticles hybrid network based chemiresistive hydrogen sulfide sensor

    Science.gov (United States)

    Shirsat, Mahendra D.; Bangar, Mangesh A.; Deshusses, Marc A.; Myung, Nosang V.; Mulchandani, Ashok

    2009-02-01

    We report a sensitive, selective, and fast responding room temperature chemiresistive sensor for hydrogen sulfide detection and quantification using polyaniline nanowires-gold nanoparticles hybrid network. The sensor was fabricated by facile electrochemical technique. Initially, polyaniline nanowires with a diameter of 250-320 nm bridging the gap between a pair of microfabricated gold electrodes were synthesized using templateless electrochemical polymerization using a two step galvanostatic technique. Polyaniline nanowires were then electrochemically functionalized with gold nanoparticles using cyclic voltammetry technique. These chemiresistive sensors show an excellent limit of detection (0.1 ppb), wide dynamic range (0.1-100 ppb), and very good selectivity and reproducibility.

  4. Technical feasibility and financial analysis of hybrid wind-photovoltaic system with hydrogen storage for Cooma

    Energy Technology Data Exchange (ETDEWEB)

    Shakya, B.D.; Aye, L. [Melbourne Univ., Victoria (Australia). Dept. of Civil and Environmental Engineering; Musgrave, P. [Snowy Hydro Ltd., Cooma, NSW (Australia)

    2005-01-01

    The feasibility of a stand-alone hybrid wind-photovoltaic (PV) system incorporating compressed hydrogen gas storage was studied for Cooma (Australia). Cooma has an average annual solar and wind energy availability of 1784 and 932 kWh/m{sup 2}, respectively. A system with 69 kWh{sub e}/day (load) and 483 kWh{sub e}(storage) was studied. Hydrogen is generated in electrolysers using excess electricity from the system. The system components were selected according to their availability and cost. The 'discounted cash flow' method, with the 'levelized energy cost' (LEC) as a financial indicator was used for analysis. Configurations with PV% of 100, 60, 12 and zero were analysed. The lowest LEC of AU $2.52/kWh{sub e} was found for 100% PV. The cost of hydrogen generation from 100% PV was AU $692/GJ of hydrogen. Fifty-two percent of the total project costs were due to the electrolyser. Hence, a reduction in the electrolyser cost would reduce the cost of the overall system. (Author)

  5. Nano-porous inorganic-organic hybrid solids: some new materials for hydrogen storage?

    International Nuclear Information System (INIS)

    Serre, Ch.; Loiseau, Th.; Devic, T.; Ferey, G.; Latroche, M.; Llewellyn, Ph.; Chang, J.S.

    2007-01-01

    Recently have been studied chromium and aluminium carboxylates MIL-53(Cr, Al), formed from an assembly of octahedrons chains and for hybrid solids formed with octahedrons trimers (MIL-100 and MIL-101). The compounds MIL-53(Cr, Al) are microporous (φ ∼ 8 Angstroms, while the solids MIL-100 and MIL-101 have very large porous volumes (V ∼ 380-700000 (Angstroms) 3 ), meso-pores (φ ∼ 25-34 Angstroms) and a zeolitic architecture. The resulting specific surface areas are important (between 1000 m 2 .g -1 for the MIL-53 solids, until 4000 m 2 .g -1 for the MIL-101 compound. Here is presented their hydrogen adsorption properties, at 77 K and 298 K. The hydrogen adsorption kinetics has been tested on the MIL-53(Cr) solid at 77 K. Hydrogen adsorption micro-calorimetry experiments have been carried out on these solids between 0 and 1 bar in order to obtain data on the strongest interactions between hydrogen and the porous basic structure. (O.M.)

  6. Evaluation of Hybrid Power Plants using Biomass, Photovoltaics and Steam Electrolysis for Hydrogen and Power Generation

    Science.gov (United States)

    Petrakopoulou, F.; Sanz, J.

    2014-12-01

    Steam electrolysis is a promising process of large-scale centralized hydrogen production, while it is also considered an excellent option for the efficient use of renewable solar and geothermal energy resources. This work studies the operation of an intermediate temperature steam electrolyzer (ITSE) and its incorporation into hybrid power plants that include biomass combustion and photovoltaic panels (PV). The plants generate both electricity and hydrogen. The reference -biomass- power plant and four variations of a hybrid biomass-PV incorporating the reference biomass plant and the ITSE are simulated and evaluated using exergetic analysis. The variations of the hybrid power plants are associated with (1) the air recirculation from the electrolyzer to the biomass power plant, (2) the elimination of the sweep gas of the electrolyzer, (3) the replacement of two electric heaters with gas/gas heat exchangers, and (4) the replacement two heat exchangers of the reference electrolyzer unit with one heat exchanger that uses steam from the biomass power plant. In all cases, 60% of the electricity required in the electrolyzer is covered by the biomass plant and 40% by the photovoltaic panels. When comparing the hybrid plants with the reference biomass power plant that has identical operation and structure as that incorporated in the hybrid plants, we observe an efficiency decrease that varies depending on the scenario. The efficiency decrease stems mainly from the low effectiveness of the photovoltaic panels (14.4%). When comparing the hybrid scenarios, we see that the elimination of the sweep gas decreases the power consumption due to the elimination of the compressor used to cover the pressure losses of the filter, the heat exchangers and the electrolyzer. Nevertheless, if the sweep gas is used to preheat the air entering the boiler of the biomass power plant, the efficiency of the plant increases. When replacing the electric heaters with gas-gas heat exchangers, the

  7. Analysis of the hybrid copper oxide-copper sulfate cycle for the thermochemical splitting of water for hydrogen production

    International Nuclear Information System (INIS)

    Gonzales, Ross B.; Law, Victor J.; Prindle, John C.

    2009-01-01

    The hybrid copper oxide-copper sulfate water-splitting thermochemical cycle involves two principal steps: (1) hydrogen production from the electrolysis of water, SO 2 (g) and CuO(s) at room temperature and (2) the thermal decomposition of the CuSO 4 product to form oxygen and SO 2 , which is recycled to the first step. A four-reaction version of the cycle (known in the literature as Cycle H-5) was used as the basis of the present work. For several of the four reactions, a rotating batch reactor sequence is proposed in order to overcome equilibrium limitations. Pinch technology was used to optimize heat integration. Sensitivity analyses revealed it to be economically more attractive to use a 10 C approach to minimize heat loss (rather than 20 C). Using standard Aspen Plus features and the Peng-Robinson equation of state for separations involving oxygen and sulfur oxides, a proposed flowsheet for the cycle was generated to yield ''Level 3'' results. A cost analysis of the designed plant (producing 100 million kmol/yr hydrogen) indicates a total major equipment cost of approximately $45 million. This translates to a turnkey plant price (excluding the cost of the high-temperature heat source or electrolyzer internals) of approximately $360 million. Based on a $2.50/kg selling price for hydrogen, gross annual revenue could be on the order of $500 million, resulting in a reasonable payback period when all capital and operating costs are considered. Previous efficiency estimates using Level 1 and Level 2 methods gave the process efficiency in the neighborhood of 47-48%. The Level 3 efficiency computation was 24-25% depending on the approach temperature used for recuperation. If the low quality heat rejected by the process can be recovered and used elsewhere, the Level 3 analysis could be as high as 51-53%. (author)

  8. Symmetrical synergy of hybrid CoS2-WS2 electrocatalysts for hydrogen evolution reaction

    KAUST Repository

    Zhou, Xiaofeng; Yang, Xiulin; Li, Henan; Hedhili, Mohamed N.; Huang, Kuo-Wei; Li, Lain-Jong; Zhang, Wenjing

    2017-01-01

    A highly active and stable hybrid electrocatalyst 3D hierarchical CoS2 nanosheets incorporated with WS2 (CoS2@WS2) has been developed via a one-step sulfurization method for the first time, where the contents of WS2 can be adjusted easily. We first prove the addition of small amounts of WS2 enhances the hydrogen evolution reaction (HER) performance of CoS2, and vise versa. In other words, we validated the symmetric synergy for HER between the Co- and W-based sulfide hybrid catalysts. In addition, we confirmed that the formation of nanointerfaces of Co-S-W between CoS2 and WS2 was responsible for the excellent HER activity (an overpotential of -97.2 mV at -10 mA/cm2, a small Tafel slope of 66.0 mV/dec, and prominent electrochemical stability) of hybrid electrocatalyst CoS2@WS2.

  9. A breeding strategy to harness flavor diversity of Saccharomyces interspecific hybrids and minimize hydrogen sulfide production.

    Science.gov (United States)

    Bizaj, Etjen; Cordente, Antonio G; Bellon, Jennifer R; Raspor, Peter; Curtin, Chris D; Pretorius, Isak S

    2012-06-01

    Industrial food-grade yeast strains are selected for traits that enhance their application in quality production processes. Wine yeasts are required to survive in the harsh environment of fermenting grape must, while at the same time contributing to wine quality by producing desirable aromas and flavors. For this reason, there are hundreds of wine yeasts available, exhibiting characteristics that make them suitable for different fermentation conditions and winemaking practices. As wine styles evolve and technical winemaking requirements change, however, it becomes necessary to improve existing strains. This becomes a laborious and costly process when the targets for improvement involve flavor compound production. Here, we demonstrate a new approach harnessing preexisting industrial yeast strains that carry desirable flavor phenotypes - low hydrogen sulfide (H(2) S) production and high ester production. A low-H(2) S Saccharomyces cerevisiae strain previously generated by chemical mutagenesis was hybridized independently with two ester-producing natural interspecies hybrids of S. cerevisiae and Saccharomyces kudriavzevii. Deficiencies in sporulation frequency and spore viability were overcome through use of complementary selectable traits, allowing successful isolation of several novel hybrids exhibiting both desired traits in a single round of selection. © 2012 Federation of European Microbiological Societies. Published by Blackwell Publishing Ltd. All rights reserved.

  10. Solar Hybrid Hydrogen Production in Sunbelt and Shipping to Japan as a Liquid fuel of Methanol

    International Nuclear Information System (INIS)

    Tamaura, Y.; Hasegawa, N.; Kaneko, H.; Utamura, M.; Katayama, Y.; Onozaki, M.; Hasuike, H.

    2006-01-01

    Solar hybrid methanol (SH-methanol) production (6000 t/day) from natural gas and coal using H 2 and O 2 gases, which are produced by electrolysis with solar thermal power (Tokyo Tech Beam-down concentration solar power generation with molten salt heat-storage system) at Sunbelt in Australia was studied from the economical view point. This system is the combined system of O 2 -burning coal gasification (C+1/2O 2 =CO), natural gas reforming by O 2 -partial oxidation (CH 4 + 1/2O 2 = CO + 2H 2 ), and water decomposition by electrolysis with solar thermal power (H 2 O = H 2 + 1/2O 2 ). In this production system, the SH-methanol is produced with zero CO 2 emission, shipped to Japan by oil tanker, and can be used as solar hybrid hydrogen in Japan for fuel cell. The solar hybrid methanol production cost of 24 yen/kg (58 US dollars bbl crude oil equivalent, April, 2006) is obtained with the solar power cost of the Tokyo Tech Beam-down solar concentration solar power generation with molten salt heat-storage. This cost is lower than the crude oil (67 US dollars bbl crude oil equivalent, April, 2006) and LPG (72 US dollars/ bbl crude oil equivalent, January, 2006). (authors)

  11. Symmetrical synergy of hybrid CoS2-WS2 electrocatalysts for hydrogen evolution reaction

    KAUST Repository

    Zhou, Xiaofeng

    2017-06-05

    A highly active and stable hybrid electrocatalyst 3D hierarchical CoS2 nanosheets incorporated with WS2 (CoS2@WS2) has been developed via a one-step sulfurization method for the first time, where the contents of WS2 can be adjusted easily. We first prove the addition of small amounts of WS2 enhances the hydrogen evolution reaction (HER) performance of CoS2, and vise versa. In other words, we validated the symmetric synergy for HER between the Co- and W-based sulfide hybrid catalysts. In addition, we confirmed that the formation of nanointerfaces of Co-S-W between CoS2 and WS2 was responsible for the excellent HER activity (an overpotential of -97.2 mV at -10 mA/cm2, a small Tafel slope of 66.0 mV/dec, and prominent electrochemical stability) of hybrid electrocatalyst CoS2@WS2.

  12. The United Kingdom Hydrogen Association Forms with International Collaboration in Mind

    International Nuclear Information System (INIS)

    Karen Hall; John Carolin; Ian Williamson

    2006-01-01

    In April 2006, the United Kingdom Hydrogen Association was launched. This paper will describe the context under which the need was established, and address the challenges and opportunities faced in creating the association. A UK Hydrogen Association can encourage information sharing among regional hydrogen efforts, and provide a mechanism for a larger, single voice on the national level. In addition, a UK Hydrogen Association can serve as a focal point for UK participation in EU activities such as the European Hydrogen and Fuel Cell Technology Platform (HFP), and other international activities such as IPHE and IEA. The results of the stake holder briefing and progress of a UK Hydrogen Association will be presented, with a focus on international collaboration. (authors)

  13. The United Kingdom Hydrogen Association Forms with International Collaboration in Mind

    International Nuclear Information System (INIS)

    Karen Hall; John Carolin; Ian Williamson

    2006-01-01

    In April 2006, the United Kingdom Hydrogen Association was launched. This paper will describe the context under which the need was established, and address the challenges and opportunities faced in creating the association. A UK Hydrogen Association can encourage information sharing among regional hydrogen efforts, and provide a mechanism for a larger, single voice on the national level. In addition, a UK Hydrogen Association can serve as a focal point for UK participation in EU activities such as the European Hydrogen and Fuel Cell Technology Platform (HFP), and other international activities such as IPHE and IEA. The results of the stakeholder briefing and progress of a UK Hydrogen Association will be presented, with a focus on international collaboration. (authors)

  14. 1999 annual summary report on results. International clean energy network using hydrogen conversion (WE-NET)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The R and D were conducted on the international clean network (WE-NET) which aims at producing hydrogen by using renewable energy, converting it in a form suitable for transportation and supplying the hydrogen to places of quantity consumption of energy. The FY 1999 results were summed up. In the system evaluation, study was made on sodium carbonate electrolysis by-producing hydrogen, the supply amount by coke oven by-producing hydrogen and the economical efficiency, etc. As to the safety, study was made on the design of hydrogen supply stand model. Concerning the power generation technology, study was conducted on element technologies of injection valve, exhaust gas condenser, gas/liquid separator, etc. Relating to the hydrogen fueled vehicle system, the shock destructive testing, etc. were conducted on the hydrogen tank and hydrogen storage alloys. Besides, a lot of R and D were carried out of pure water use solid polymer fuel cells, hydrogen stand, hydrogen production technology, hydrogen transportation/storage technology, low temperature materials, transportation/storage using hydrogen storage alloys, innovative advanced technology, etc. (NEDO)

  15. Cross-border Intra-group Hybrid Finance and International Taxation

    OpenAIRE

    Eberhartinger, Eva; Pummerer, Erich; Göritzer, Andreas

    2010-01-01

    In intra-group finance hybrid instruments allow for tailor-made form of finance. Hence hybrid finance is often used for international tax planning in multinational groups. Due to a lack of international tax harmonization or tax coordination qualification conflict can arise. A specific hybrid instrument is classified as debt in one country, and as equity in the other country. This may lead to double taxation. In the reverse case, double non-taxation can arise. Against this legal background one...

  16. The effect of internal hydrogen on surface slip localisation on polycrystalline AISI 316L stainless steel

    International Nuclear Information System (INIS)

    Aubert, Isabelle; Olive, Jean-Marc; Saintier, Nicolas

    2010-01-01

    A statistical analysis of the effect of internal hydrogen on the surface slip morphology of relatively high nickel content AISI 316L type austenitic stainless steel was carried out on high resolution data obtained by atomic force microscopy. Surface plastic strain localisation was studied for different hydrogen contents, two grain sizes, and two plastic strain levels. The height and spacing of approximately 8000 slip bands, observed on 12 specimens, are shown to follow log-normal distributions. Hydrogen increased the mean slip-band height and the mean slip-band spacing for the two macroscopic plastic strain levels considered, and for the two hydrogen concentrations in coarse-grained specimens. The hydrogen effect was also observed for fine-grained specimens, but only for the highest hydrogen concentration. In addition, the emerging dislocation velocity increased by a factor 3 for high hydrogen content.

  17. Developing a Model Using Homer for a Hybrid Hydrogen Fuel Cell System

    Directory of Open Access Journals (Sweden)

    Fera Annisa

    2013-04-01

    Full Text Available ABSTRACT. Hydrogen is widely considered be the fuel of the near future. Combined wind/PV energy hybrid systems can be used to sources energy to hydrogen production. This paper describes design, simulation and feasibility study of a hybrid energy system for a household in Malaysia. One year recorded wind speed and solar radiation are used for the design of a hybrid energy system. In 2000 was average annual wind speed in Johor Bahru is 3.76 m/s and annual average solar energy resource available is 5.08 kWh/m2/day. National Renewable Energy Laboratory’s HOMER software was used to select an optimum hybrid energy system. In the optimization process, HOMER simulates every system configuration in the search space and displays the feasible ones in a table, sorted by total net present cost (TNPC. The optimization study indicates that sensitivity analysis of the HOMER is shown in the overall winner which shows that the most least cost and optimize hybrid system is combination of 10 kW of PV array, 1 unit of wind turbine, 2 kW of fuel cell, 120 units of batteries and 6 kW converter as well as 1 kW of electrolyzer so as to generate the minimum COE, $2.423 kWh- 1. Although renewable sources (wind and PV involved in the power generation, 1 kg of hydrogen was produced in this system. Pengembangan Model Dengan Menggunakan Homer Untuk Sistem Sel Berbahan bakar Hidrogen Hibrida ABSTRAK. Hidrogen secara luas dianggap sebagai bahan bakar masa depan. Gabungan sistem hibrida energi angin/fotovoltaik dapat digunakan untuk sumber energi produksi hidrogen. Makalah ini menjelaskan desain, simulasi dan studi kelayakan dari sistem energi hibrida untuk rumah tangga di Malaysia. Satu tahun kecepatan angin tercatat dan radiasi matahari digunakan untuk desain sistem energi hibrida. Pada tahun 2000 adalah kecepatan angin rata-rata tahunan di Johor Bahru 3.76 m/det dan rata-rata sumber daya energi surya tahunan yang tersedia adalah 5.08 kWjam/m2/ hari. Software HOMER digunakan

  18. Hybrid continuum–molecular modelling of multiscale internal gas flows

    International Nuclear Information System (INIS)

    Patronis, Alexander; Lockerby, Duncan A.; Borg, Matthew K.; Reese, Jason M.

    2013-01-01

    We develop and apply an efficient multiscale method for simulating a large class of low-speed internal rarefied gas flows. The method is an extension of the hybrid atomistic–continuum approach proposed by Borg et al. (2013) [28] for the simulation of micro/nano flows of high-aspect ratio. The major new extensions are: (1) incorporation of fluid compressibility; (2) implementation using the direct simulation Monte Carlo (DSMC) method for dilute rarefied gas flows, and (3) application to a broader range of geometries, including periodic, non-periodic, pressure-driven, gravity-driven and shear-driven internal flows. The multiscale method is applied to micro-scale gas flows through a periodic converging–diverging channel (driven by an external acceleration) and a non-periodic channel with a bend (driven by a pressure difference), as well as the flow between two eccentric cylinders (with the inner rotating relative to the outer). In all these cases there exists a wide variation of Knudsen number within the geometries, as well as substantial compressibility despite the Mach number being very low. For validation purposes, our multiscale simulation results are compared to those obtained from full-scale DSMC simulations: very close agreement is obtained in all cases for all flow variables considered. Our multiscale simulation is an order of magnitude more computationally efficient than the full-scale DSMC for the first and second test cases, and two orders of magnitude more efficient for the third case

  19. Hydrogen enriched compressed natural gas (HCNG: A futuristic fuel for internal combustion engines

    Directory of Open Access Journals (Sweden)

    Nanthagopal Kasianantham

    2011-01-01

    Full Text Available Air pollution is fast becoming a serious global problem with increasing population and its subsequent demands. This has resulted in increased usage of hydrogen as fuel for internal combustion engines. Hydrogen resources are vast and it is considered as one of the most promising fuel for automotive sector. As the required hydrogen infrastructure and refueling stations are not meeting the demand, widespread introduction of hydrogen vehicles is not possible in the near future. One of the solutions for this hurdle is to blend hydrogen with methane. Such types of blends take benefit of the unique combustion properties of hydrogen and at the same time reduce the demand for pure hydrogen. Enriching natural gas with hydrogen could be a potential alternative to common hydrocarbon fuels for internal combustion engine applications. Many researchers are working on this for the last few years and work is now focused on how to use this kind of fuel to its maximum extent. This technical note is an assessment of HCNG usage in case of internal combustion engines. Several examples and their salient features have been discussed. Finally, overall effects of hydrogen addition on an engine fueled with HCNG under various conditions are illustrated. In addition, the scope and challenges being faced in this area of research are clearly described.

  20. Hydrogen applications for Lambert-St. Louis International Airport

    Science.gov (United States)

    2009-01-01

    Today, major airports are facing challenges related to pollution, energy efficiency, and safety and security. Hydrogen and fuel cell technologies, regarded as one of the key energy solutions of the 21st century are more energy efficient and reliable ...

  1. Non-traditional Process of Hydrogen Containing Fuel Mixtures Production for Internal-combustion Engines

    Directory of Open Access Journals (Sweden)

    Gennady G. Kuvshinov

    2012-12-01

    Full Text Available The article justifies the perspectives of development of the environmentally sound technology of hydrogen containing fuel mixtures for internal-combustion engines based on the catalytic process of low-temperature decomposition of hydrocarbons into hydrogen and nanofibrous carbon.

  2. On the use of hydrogen in confined spaces: Results from the internal project InsHyde

    NARCIS (Netherlands)

    Venetsanos, A.G.; Adams, P.; Azkarate, I.; Bengaouer, A.; Brett, L.; Carcassi, M.N.; Engebø, A.; Gallego, E.; Gavrikov, A.I.; Hansen, O.R.; Hawksworth, S.; Jordan, T.; Kessler, A.; Kumar, S.; Molkov, V.; Nilsen, S.; Reinecke, E.; Stöcklin, M.; Schmidtchen, U.; Teodorczyk, A.; Tigreat, D.; Versloot, N.H.A.

    2011-01-01

    The paper presents an overview of the main achievements of the internal project InsHyde of the HySafe NoE. The scope of InsHyde was to investigate realistic small-medium indoor hydrogen leaks and provide recommendations for the safe use/storage of indoor hydrogen systems. Additionally, InsHyde

  3. Development of once-through hybrid sulfur process for nuclear hydrogen production

    International Nuclear Information System (INIS)

    Jung, Yong Hun

    2010-02-01

    Humanity has been facing major energy challenges such as the severe climate change, threat of energy security and global energy shortage especially for the developing world. Particularly, growing awareness of the global warming has led to efforts to develop the sustainable energy technologies for the harmony of the economy, social welfare and environment. Water-splitting nuclear hydrogen production is expected to help to resolve those challenges, when high energy efficiency and low cost for hydrogen production become possible. Once-through Hybrid Sulfur process (Ot-HyS), proposed in this work, produces hydrogen using the same SO 2 Depolarized water Electrolysis (SDE) process found in the original Hybrid Sulfur cycle (HyS) proposed by Westinghouse, which has the sulfuric acid decomposition (SAD) process using high temperature heat source in order to recover sulfur dioxide for the SDE process. But Ot-HyS eliminated this technical hurdle by replacing it with well-established sulfur combustion process to feed sulfur dioxide to the SDE process. Because Ot-HyS has less technical challenges, Ot-HyS is expected to advance the realization of the large-scale nuclear hydrogen production by feeding an initial nuclear hydrogen stock. Most of the elemental sulfur, at present, is supplied by desulfurization process for environmental reasons during the processing of natural gas and petroleum refining and expected to increase significantly. This recovered sulfur will be burned with oxygen in the sulfur combustion process so that produced sulfur dioxide could be supplied to the SDE process to produce hydrogen. Because the sulfur combustion is a highly exothermic reaction releasing 297 kJ/mol of combustion heat resulting in a large temperature rise, efficiency of the Ot-HyS is expected to be high by recovering this great amount of high grade excess heat with nuclear energy. Sulfuric acid, which is a byproduct of the SDE process, could be sent to the neighboring consumers with or even

  4. Non-noble metal graphene oxide-copper (II) ions hybrid electrodes for electrocatalytic hydrogen evolution reaction

    KAUST Repository

    Muralikrishna, S.; Ravishankar, T.N.; Ramakrishnappa, T.; Nagaraju, Doddahalli H.; Krishna Pai, Ranjith

    2015-01-01

    Non-noble metal and inexpensive graphene oxide-copper (II) ions (GO-Cu2+) hybrid catalysts have been explored for the hydrogen evolution reaction (HER). We were able to tune the binding abilities of GO toward the Cu2+ ions and hence their catalytic

  5. Hydrogen storage as a hydride. Citations from the International Aerospace Abstracts data base

    Science.gov (United States)

    Zollars, G. F.

    1980-01-01

    These citations from the international literature concern the storage of hydrogen in various metal hydrides. Binary and intermetallic hydrides are considered. Specific alloys discussed are iron titanium, lanthanium nickel, magnesium copper and magnesium nickel among others.

  6. Techno-economical Analysis of Hybrid PV-WT-Hydrogen FC System for a Residential Building with Low Power Consumption

    Directory of Open Access Journals (Sweden)

    Badea G.

    2016-12-01

    Full Text Available This paper shows a techno-economical analysis on performance indicators of hybrid solar-wind-hydrogen power generation system which supply with electricity a low - energy building, located in Cluj-Napoca. The case study had the main objectives, as follows: cost estimation, evaluation of energy and environmental performance for a fuel cell integrated into a small-scale hybrid system power generation and estimation of electrolytic hydrogen production based on renewable energy resources available on the proposed site. The results presented in this paper illustrate a case study for location Cluj-Napoca. The wind and solar resource can play an important role in energy needs for periods with "peak load" or intermittent energy supply. However, hydrogen production is dependent directly proportional to the availability of renewable energy resources, but the hydrogen can be considered as a storage medium for these renewable resources. It can be said that this study is a small-scale model analysis, a starting point for a detailed analysis of Romania's potential electrolytic production of hydrogen from renewable resources and supply electricity using fuel cells integrated into hybrid energy systems.

  7. Operating Point Optimization of a Hydrogen Fueled Hybrid Solid Oxide Fuel Cell-Steam Turbine (SOFC-ST Plant

    Directory of Open Access Journals (Sweden)

    Juanjo Ugartemendia

    2013-09-01

    Full Text Available This paper presents a hydrogen powered hybrid solid oxide fuel cell-steam turbine (SOFC-ST system and studies its optimal operating conditions. This type of installation can be very appropriate to complement the intermittent generation of renewable energies, such as wind generation. A dynamic model of an alternative hybrid SOFC-ST configuration that is especially suited to work with hydrogen is developed. The proposed system recuperates the waste heat of the high temperature fuel cell, to feed a bottoming cycle (BC based on a steam turbine (ST. In order to optimize the behavior and performance of the system, a two-level control structure is proposed. Two controllers have been implemented for the stack temperature and fuel utilization factor. An upper supervisor generates optimal set-points in order to reach a maximal hydrogen efficiency. The simulation results obtained show that the proposed system allows one to reach high efficiencies at rated power levels.

  8. A feasibility study of conceptual design for international clean energy network using hydrogen conversion technology

    International Nuclear Information System (INIS)

    Sato, Takashi; Hamada, Akiyoshi; Kitamura, Kazuhiro

    1998-01-01

    Clean energy is more and more required worldwide in proportion to actualization of global environmental issues including global warming. Therefore, it is an urgent task to realize promotion of worldwide introduction of clean energy which exists abundantly and is widely distributed in the world, such as hydropower and solar energy, while reducing the dependence on fossil fuel. However, since the renewable energy, differing from so called fossil fuel, is impossible to transport for long distance and store as it is, its utilization is subject to be limited. As one possible resolution of this kind of issues, 'International clean energy network using hydrogen conversion technology' which enables conversion of renewable energy from low cost hydropower into hydrogen energy and also into the transportable and storable form, is a meaningful concept. This system technology enables dealing of this hydrogen energy in international market as in the same manner as fossil fuel. It is considered to enable promotion of international and large scale introduction of such clean energy, along with the contribution to diversified and stabilized international energy supply. In this study, based upon the above-mentioned point of view and assumption of two sites, one on supply side and another on demand side of hydrogen energy, three systems are presumed. One of the systems consists of liquid hydrogen as transportation and storage medium of hydrogen, and the others intermediately convert hydrogen into methanol or ammonia as an energy carrier. A overall conceptual design of each system spanning from hydrogen production to its utilization, is conducted in practical way in order to review the general technical aspects and economical aspects through cost analysis. This study is administrated through the New Energy and Industrial Technology Development Organization (NEDO) as a part of the International Clean Energy Network Using Hydrogen Conversion (so-called WE-NET) Program with funding from

  9. Internal hydrogen-induced subcritical crack growth in austenitic stainless steels

    Science.gov (United States)

    Huang, J. H.; Altstetter, C. J.

    1991-11-01

    The effects of small amounts of dissolved hydrogen on crack propagation were determined for two austenitic stainless steel alloys, AISI 301 and 310S. In order to have a uniform distribution of hydrogen in the alloys, they were cathodically charged at high temperature in a molten salt electrolyte. Sustained load tests were performed on fatigue precracked specimens in air at 0 ‡C, 25 ‡C, and 50 ‡C with hydrogen contents up to 41 wt ppm. The electrical potential drop method with optical calibration was used to continuously monitor the crack position. Log crack velocity vs stress intensity curves had definite thresholds for subcritical crack growth (SCG), but stage II was not always clearly delineated. In the unstable austenitic steel, AISI 301, the threshold stress intensity decreased with increasing hydrogen content or increasing temperature, but beyond about 10 wt ppm, it became insensitive to hydrogen concentration. At higher concentrations, stage II became less distinct. In the stable stainless steel, subcritical crack growth was observed only for a specimen containing 41 wt ppm hydrogen. Fractographic features were correlated with stress intensity, hydrogen content, and temperature. The fracture mode changed with temperature and hydrogen content. For unstable austenitic steel, low temperature and high hydrogen content favored intergranular fracture while microvoid coalescence dominated at a low hydrogen content. The interpretation of these phenomena is based on the tendency for stress-induced phase transformation, the different hydrogen diffusivity and solubility in ferrite and austenite, and outgassing from the crack tip. After comparing the embrittlement due to internal hydrogen with that in external hydrogen, it is concluded that the critical hydrogen distribution for the onset of subcritical crack growth is reached at a location that is very near the crack tip.

  10. Fiscal 1995 achievement report. International Clean Energy Network Using Hydrogen Conversion (WE-NET) technology

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Research and development was performed for the WE-NET (World Energy Network) project which aims to carry out hydrogen production, transportation, and supply to consumers, by the use of renewable energy. Under subtask 1, besides investigation of a pilot plant of phase 2, the WE-NET image as a whole was studied. Under subtask 2, technical information was exchanged at an international symposium and a long-term vision of the international network was discussed. Under subtask 3, for the evaluation of the effect of hydrogen energy introduction on the global level, national level, and city level, simulation models were discussed and improved. Under subtask 4, tests and studies were made concerning electrode bonding methods. Under subtask 5, the Neon Brayton cycle process was surveyed and studied as a hydrogen liquefaction cycle. Under subtasks 6-9, furthermore, surveys and studies were made about techniques relating to low-temperature substances, hydrogen energy, hydrogen combustion turbines, and so forth. (NEDO)

  11. Symmetrical synergy of hybrid Co9S8-MoSx electrocatalysts for hydrogen evolution reaction

    KAUST Repository

    Zhou, Xiaofeng

    2017-01-07

    There exists a strong demand to replace expensive noble metal catalysts with efficient and earth-abundant catalysts for hydrogen evolution reaction (HER). Recently the Co- and Mo-based sulfides such as CoS2, Co9S8, and MoSx have been considered as several promising HER candidates. Here, a highly active and stable hybrid electrocatalyst 3D flower-like hierarchical Co9S8 nanosheets incorporated with MoSx has been developed via a one-step sulfurization method. Since the amounts of Co9S8 and MoSx are easily adjustable, we verify that small amounts of MoSx promotes the HER activity of Co9S8, and vise versa. In other words, we validate that symmetric synergy for HER in the Co- and Mo-based sulfide hybrid catalysts, a long-standing question requiring clear experimental proofs. Meanwhile, the best electrocatalyst Co9S8-30@MoSx/CC in this study exhibits excellent HER performance with an overpotential of −98 mV at −10 mA/cm2, a small Tafel slope of 64.8 mV/dec, and prominent electrochemical stability.

  12. NATO International Symposium on the Electronic Structure and Properties of Hydrogen in Metals

    CERN Document Server

    Satterthwaite, C

    1983-01-01

    Hydrogen is the smallest impurity atom that can be implanted in a metallic host. Its small mass and strong interaction with the host electrons and nuclei are responsible for many anomalous and interesting solid state effects. In addition, hydrogen in metals gives rise to a number of technological problems such as hydrogen embrittlement, hydrogen storage, radiation hardening, first wall problems associated with nuclear fusion reactors, and degradation of the fuel cladding in fission reactors. Both the fundamental effects and applied problems have stimulated a great deal of inter­ est in the study of metal hydrogen systems in recent years. This is evident from a growing list of publications as well as several international conferences held in this field during the past decade. It is clear that a fundamental understanding of these problems re­ quires a firm knowledge of the basic interactions between hydrogen, host metal atoms, intrinsic lattice defects and electrons. This understanding is made particularly di...

  13. Nuclear-Renewable Hybrid System Economic Basis for Electricity, Fuel, and Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Charles Forsberg; Steven Aumeier

    2014-04-01

    Concerns about climate change and altering the ocean chemistry are likely to limit the use of fossil fuels. That implies a transition to a low-carbon nuclear-renewable electricity grid. Historically variable electricity demand was met using fossil plants with low capital costs, high operating costs, and substantial greenhouse gas emissions. However, the most easily scalable very-low-emissions generating options, nuclear and non-dispatchable renewables (solar and wind), are capital-intensive technologies with low operating costs that should operate at full capacities to minimize costs. No combination of fully-utilized nuclear and renewables can meet the variable electricity demand. This implies large quantities of expensive excess generating capacity much of the time. In a free market this results in near-zero electricity prices at times of high nuclear renewables output and low electricity demand with electricity revenue collapse. Capital deployment efficiency—the economic benefit derived from energy systems capital investment at a societal level—strongly favors high utilization of these capital-intensive systems, especially if low-carbon nuclear renewables are to replace fossil fuels. Hybrid energy systems are one option for better utilization of these systems that consumes excess energy at times of low prices to make some useful product.The economic basis for development of hybrid energy systems is described for a low-carbon nuclear renewable world where much of the time there are massivequantities of excess energy available from the electric sector.Examples include (1) high-temperature electrolysis to generate hydrogen for non-fossil liquid fuels, direct use as a transport fuel, metal reduction, etc. and (2) biorefineries.Nuclear energy with its concentrated constant heat output may become the enabling technology for economically-viable low-carbon electricity grids because hybrid nuclear systems may provide an economic way to produce dispatachable variable

  14. Control Scheme Formulation for the Production of Hydrogen on Demand to Feed an Internal Combustion Engine

    Directory of Open Access Journals (Sweden)

    Jarniel García Morales

    2016-12-01

    Full Text Available In this work, a control strategy is presented to produce hydrogen on demand to feed an internal combustion (IC engine. For this purpose, the modeling of the IC engine fueled by gasoline blended with 10 % v/v of anhydrous ethanol (E10 and hydrogen as an additive is developed. It is considered that the hydrogen gas is produced according to the IC engine demand, and that the hydrogen gas is obtained by an alkaline electrolyzer. The gasoline–ethanol blend added into the combustion chamber is determined according to the stoichiometric ratio and the production of hydrogen gas is regulated by a proportional and integral controller (P.I.. The controller reference is varying according to the mass flow air induced into the cylinder, in order to ensure an adequate production of hydrogen gas for any operating condition of the IC engine. The main contribution of this work is the control scheme developed, through simulation, in order to produce hydrogen on demand for any operating point of an internal combustion engine fueled by an E10 blend. The simulation results showed that the use of hydrogen gas as an additive in an E10 blend decreases the E10 fuel consumption 23 % on average, and the thermal efficiency is increased approximately 2.13 % , without brake power loss in the IC engine.

  15. Effects of internal hydrogen on the vacancy loop formation probability in Al

    International Nuclear Information System (INIS)

    Bui, T.X.; Sirois, E.; Robertson, I.M.

    1990-04-01

    The effect of internal hydrogen on the formation of vacancy dislocation loops from heavy-ion generated displacement cascades in Al has been investigated. Samples of high-purity aluminum and aluminum containing 900 and 1300 appM of hydrogen were irradiated at room temperature with 50 keV Kr+ ions. The ion dose rate was typically 2 x 10 10 ions cm -2 sec -1 and the ion dose was between 10 11 and 10 13 ion cm -2 . Under these irradiation conditions, dislocation loops were observed in all compositions, although the formation probability was relatively low (less than 10 percent of the displacement cascades produced a vacancy loop). The loop formation probability was further reduced by the presence of hydrogen. No difference in the geometry or the size of the loops created in the hydrogen free and hydrogen charged samples was found. These results are difficult to interpret, and the explanation may lie in the distribution and form of the hydrogen. To account for the large hydrogen concentrations and from calculations of the energy associated with hydrogen entry into aluminum, it has been suggested that the hydrogen enters the aluminum lattice with an accompanying vacancy. This will create hydrogen-vacancy complexes in the material; two dimensional complexes have been detected in the hydrogen-charged, but unirradiated, samples by the small-angle x-ray scattering technique. The possibility of these complexes trapping the vacancies produced by the cascade process exists thus lowering the formation probability. However, such a mechanism must occur within the lifetime of the cascade. Alternatively, if a displacement cascade overlaps with the hydrogen-vacancy complexes, the lower atomic density of the region will result in an increase in the cascade volume (decrease in the local vacancy concentration) which will also reduce the loop formation probability

  16. Energy–exergy and economic analyses of a hybrid solar–hydrogen renewable energy system in Ankara, Turkey

    International Nuclear Information System (INIS)

    Ozden, Ender; Tari, Ilker

    2016-01-01

    Highlights: • Uninterrupted energy in an emergency blackout situation. • System modeling of a solar–hydrogen based hybrid renewable energy system. • A comprehensive thermodynamical analysis. • Levelized cost of electricity analysis for a project lifetime of 25 years. - Abstract: A hybrid (Solar–Hydrogen) stand-alone renewable energy system that consists of photovoltaic panels (PV), Proton Exchange Membrane (PEM) fuel cells, PEM based electrolyzers and hydrogen storage is investigated by developing a complete model of the system using TRNSYS. The PV panels are mounted on a tiltable platform to improve the performance of the system by monthly adjustments of the tilt angle. The total area of the PV panels is 300 m 2 , the PEM fuel cell capacity is 5 kW, and the hydrogen storage is at 55 bars pressure and with 45 m 3 capacity. The main goal of this study is to verify that the system meets the electrical power demand of the emergency room without experiencing a shortage for a complete year in an emergency blackout situation. For this purpose, after modeling the system, energy and exergy analyses for the hydrogen cycle of the system for a complete year are performed, and the energy and exergy efficiencies are found as 4.06% and 4.25%, respectively. Furthermore, an economic analysis is performed for a project lifetime of 25 years based on Levelized Cost of Electricity (LCE), and the LCE is calculated as 0.626 $/kWh.

  17. Design and economical analysis of hybrid PV-wind systems connected to the grid for the intermittent production of hydrogen

    International Nuclear Information System (INIS)

    Dufo-Lopez, Rodolfo; Bernal-Agustin, Jose L.; Mendoza, Franklin

    2009-01-01

    In this paper, several designs of hybrid PV-wind (photovoltaic-wind) systems connected to the electrical grid, including the intermittent production of hydrogen, are shown. The objective considered in the design is economical to maximise the net present value (NPV) of the system. A control strategy has been applied so that hydrogen is only produced by the electrolyser when there is an excess of electrical energy that cannot be exported to the grid (intermittent production of hydrogen). Several optimisation studies based on different scenarios have been carried out. After studying the results - for systems with which the produced hydrogen would be sold for external consumption - it can be stated that the selling price of hydrogen should be about 10 Euro /kg in areas with strong wind, in order to get economically viable systems. For the hydrogen-producing systems in which hydrogen is produced when there is an excess of electricity and then stored and later used in a fuel cell to produce electricity to be sold to the grid, even in areas with high wind speed rate, the price of electrical energy produced by the fuel cell should be very high for the system to be profitable.

  18. Relation of Hydrogen and Methane to Carbon Monoxide in Exhaust Gases from Internal-Combustion Engines

    Science.gov (United States)

    Gerrish, Harold C; Tessmann, Arthur M

    1935-01-01

    The relation of hydrogen and methane to carbon monoxide in the exhaust gases from internal-combustion engines operating on standard-grade aviation gasoline, fighting-grade aviation gasoline, hydrogenated safety fuel, laboratory diesel fuel, and auto diesel fuel was determined by analysis of the exhaust gases. Two liquid-cooled single-cylinder spark-ignition, one 9-cylinder radial air-cooled spark-ignition, and two liquid-cooled single-cylinder compression-ignition engines were used.

  19. A Novel Synthesis of Gold Nanoparticles Supported on Hybrid Polymer/Metal Oxide as Catalysts for p-Chloronitrobenzene Hydrogenation

    Directory of Open Access Journals (Sweden)

    Cristian H. Campos

    2017-01-01

    Full Text Available This contribution reports a novel preparation of gold nanoparticles on polymer/metal oxide hybrid materials (Au/P[VBTACl]-M metal: Al, Ti or Zr and their use as heterogeneous catalysts in liquid phase hydrogenation of p-chloronitrobenzene. The support was prepared by in situ radical polymerization/sol gel process of (4-vinyl-benzyltrimethylammonium chloride and 3-(trimethoxysilylpropyl methacrylate in conjunction with metal-alkoxides as metal oxide precursors. The supported catalyst was prepared by an ion exchange process using chloroauric acid (HAuCl4 as gold precursor. The support provided the appropriate environment to induce the spontaneous reduction and deposition of gold nanoparticles. The hybrid material was characterized. TEM and DRUV-vis results indicated that the gold forms spherical metallic nanoparticles and that their mean diameter increases in the sequence, Au/P[VBTACl]-Zr > Au/P[VBTACl]-Al > Au/P[VBTACl]-Ti. The reactivity of the Au catalysts toward the p-CNB hydrogenation reaction is attributed to the different particle size distributions of gold nanoparticles in the hybrid supports. The kinetic pseudo-first-order constant values for the catalysts in the hydrogenation reaction increases in the order, Au/P[VBTACl]-Al > Au/P[VBTACl]-Zr > Au/P[VBTACl]-Ti. The selectivity for all the catalytic systems was greater than 99% toward the chloroaniline target product. Finally the catalyst supported on the hybrid with Al as metal oxide could be reused at least four times without loss in activity or selectivity for the hydrogenation of p-CNB in ethanol as solvent.

  20. Techno-economic evaluation of hybrid systems for hydrogen production from biomass and natural gas

    Energy Technology Data Exchange (ETDEWEB)

    Kassem, N. [Royal Institute of Technology, Stockholm (Sweden). Dept. of Energy Processes

    2001-07-01

    Hydrogen (H{sub 2}) is an alternative energy carrier, which is expected to significantly contribute to globally sustainable energy systems. It is environmentally friendly with high-energy density that makes it an excellent integrating fuel in transportation and power generation systems. This paper presents an assessment of the techno-economic viability of H{sub 2} production technologies based on hybrid systems using gasified biomass and natural gas combined with high temperature electrochemical shift. Assessment of the well-established thermal processes, high-temperature steam electrolysis (HTEL), and the plasma catalytic reforming (PCR) of light hydrocarbons developed at MIT are included for comparison. The results show that the PCR and HTEL processes are as cost-effective as the thermal steam reforming for H{sub 2} production when deployed on a commercial scale. The natural gas steam reforming (NGSR) is still the most favorable choice in energy and financial terms, while gasified biomass (GB) provides the highest production costs due to the intensive capital cost investments. The cost of H{sub 2} storage in the form of compressed gas or liquefied H{sub 2} also contributes significantly to total cost per kg produced H{sub 2}. 9 refs., 7 figs., 2 tabs.

  1. Hybrid Theory of P-Wave Electron-Hydrogen Elastic Scattering

    Science.gov (United States)

    Bhatia, Anand

    2012-01-01

    We report on a study of electron-hydrogen scattering, using a combination of a modified method of polarized orbitals and the optical potential formalism. The calculation is restricted to P waves in the elastic region, where the correlation functions are of Hylleraas type. It is found that the phase shifts are not significantly affected by the modification of the target function by a method similar to the method of polarized orbitals and they are close to the phase shifts calculated earlier by Bhatia. This indicates that the correlation function is general enough to include the target distortion (polarization) in the presence of the incident electron. The important fact is that in the present calculation, to obtain similar results only 35-term correlation function is needed in the wave function compared to the 220-term wave function required in the above-mentioned previous calculation. Results for the phase shifts, obtained in the present hybrid formalism, are rigorous lower bounds to the exact phase shifts.

  2. A first-principles study of lithium-decorated hybrid boron nitride and graphene domains for hydrogen storage

    International Nuclear Information System (INIS)

    Hu, Zi-Yu; Shao, Xiaohong; Wang, Da; Liu, Li-Min; Johnson, J. Karl

    2014-01-01

    First-principles calculations are performed to investigate the adsorption of hydrogen onto Li-decorated hybrid boron nitride and graphene domains of (BN) x C 1−x complexes with x = 1, 0.25, 0.5, 0.75, 0, and B 0.125 C 0.875 . The most stable adsorption sites for the nth hydrogen molecule in the lithium-decorated (BN) x C 1−x complexes are systematically discussed. The most stable adsorption sites were affected by the charge localization, and the hydrogen molecules were favorably located above the C-C bonds beside the Li atom. The results show that the nitrogen atoms in the substrate planes could increase the hybridization between the 2p orbitals of Li and the orbitals of H 2 . The results revealed that the (BN) x C 1−x complexes not only have good thermal stability but they also exhibit a high hydrogen storage of 8.7% because of their dehydrogenation ability

  3. Expanding the peptide beta-turn in alphagamma hybrid sequences: 12 atom hydrogen bonded helical and hairpin turns.

    Science.gov (United States)

    Chatterjee, Sunanda; Vasudev, Prema G; Raghothama, Srinivasarao; Ramakrishnan, Chandrasekharan; Shamala, Narayanaswamy; Balaram, Padmanabhan

    2009-04-29

    Hybrid peptide segments containing contiguous alpha and gamma amino acid residues can form C(12) hydrogen bonded turns which may be considered as backbone expanded analogues of C(10) (beta-turns) found in alphaalpha segments. Exploration of the regular hydrogen bonded conformations accessible for hybrid alphagamma sequences is facilitated by the use of a stereochemically constrained gamma amino acid residue gabapentin (1-aminomethylcyclohexaneacetic acid, Gpn), in which the two torsion angles about C(gamma)-C(beta) (theta(1)) and C(beta)-C(alpha) (theta(2)) are predominantly restricted to gauche conformations. The crystal structures of the octapeptides Boc-Gpn-Aib-Gpn-Aib-Gpn-Aib-Gpn-Aib-OMe (1) and Boc-Leu-Phe-Val-Aib-Gpn-Leu-Phe-Val-OMe (2) reveal two distinct conformations for the Aib-Gpn segment. Peptide 1 forms a continuous helix over the Aib(2)-Aib(6) segment, while the peptide 2 forms a beta-hairpin structure stabilized by four cross-strand hydrogen bonds with the Aib-Gpn segment forming a nonhelical C(12) turn. The robustness of the helix in peptide 1 in solution is demonstrated by NMR methods. Peptide 2 is conformationally fragile in solution with evidence of beta-hairpin conformations being obtained in methanol. Theoretical calculations permit delineation of the various C(12) hydrogen bonded structures which are energetically feasible in alphagamma and gammaalpha sequences.

  4. Conversion of a gasoline internal combustion engine to operate on hydrogen fuel

    International Nuclear Information System (INIS)

    Bates, M.; Dincer, I.

    2009-01-01

    This study deals with the conversion of a gasoline spark ignition internal combustion engine to operate on hydrogen fuel while producing similar power, economy and reliability as gasoline. The conversion engine will have the fuel system redesigned and ignition and fuel timing changed. Engine construction material is of great importance due to the low ignition energy of hydrogen, making aluminum a desirable material in the intake manifold and combustion chamber. The engine selected to convert is a 3400 SFI dual over head cam General Motors engine. Hydrogen reacts with metals causing hydrogen embrittlement which leads to failure due to cracking. There are standards published by American Society of Mechanical Engineers (ASME) to avoid such a problem. Tuning of the hydrogen engine proved to be challenging due to the basic tuning tools of a gasoline engine such as a wide band oxygen sensor that could not measure the 34:1 fuel air mixture needed for the hydrogen engine. Once the conversion was complete the engine was tested on a chassis dynamometer to compare the hydrogen horsepower and torque produced to that of a gasoline engine. Results showed that the engine is not operating correctly. The engine is not getting the proper amount of fuel needed for complete combustion when operated in a loaded state over 3000 rpm. The problem was found to be the use of the stock injector driver that could not deliver enough power for the proper operation of the larger CM4980 injectors. (author)

  5. Computational hybrid anthropometric paediatric phantom library for internal radiation dosimetry

    DEFF Research Database (Denmark)

    Xie, Tianwu; Kuster, Niels; Zaidi, Habib

    2017-01-01

    for children demonstrated that they follow the same trend when correlated with age. The constructed hybrid computational phantom library opens up the prospect of comprehensive radiation dosimetry calculations and risk assessment for the paediatric population of different age groups and diverse anthropometric...

  6. Hydrogen energy

    International Nuclear Information System (INIS)

    2005-03-01

    This book consists of seven chapters, which deals with hydrogen energy with discover and using of hydrogen, Korean plan for hydrogen economy and background, manufacturing technique on hydrogen like classification and hydrogen manufacture by water splitting, hydrogen storage technique with need and method, hydrogen using technique like fuel cell, hydrogen engine, international trend on involving hydrogen economy, technical current for infrastructure such as hydrogen station and price, regulation, standard, prospect and education for hydrogen safety and system. It has an appendix on related organization with hydrogen and fuel cell.

  7. Non-noble metal graphene oxide-copper (II) ions hybrid electrodes for electrocatalytic hydrogen evolution reaction

    KAUST Repository

    Muralikrishna, S.

    2015-08-25

    Non-noble metal and inexpensive graphene oxide-copper (II) ions (GO-Cu2+) hybrid catalysts have been explored for the hydrogen evolution reaction (HER). We were able to tune the binding abilities of GO toward the Cu2+ ions and hence their catalytic properties by altering the pH. We have utilized the oxygen functional moieties such as carboxylate, epoxide, and hydroxyl groups on the edge and basal planes of the GO for binding the Cu2+ ions through dative bonds. The GO-Cu2+ hybrid materials were characterized by cyclic voltammetry in sodium acetate buffer solution. The morphology of the hybrid GO-Cu2+ was characterized by atomic force microscopy. The GO-Cu2+ hybrid electrodes show good electrocatalytic activity for HER with low overpotential in acidic solution. The Tafel slope for the GO-Cu2+ hybrid electrode implies that the primary discharge step is the rate determining step and HER proceed with Volmer step. © 2015 American Institute of Chemical Engineers Environ Prog.

  8. United States Energy Association Final Report International Partnership for the Hydrogen Economy Ministerial Conference

    Energy Technology Data Exchange (ETDEWEB)

    William L. Polen

    2006-04-05

    This report summarizes the activities of the United States Energy Association as it conducted the initial Ministerial Meeting of the International Partnership for the Hydrogen Economy in Washington, DC on November 18-21, 2003. The report summarizes the results of the meeting and subsequent support to the Office of Energy Efficiency and Renewable Energy in its role as IPHE Secretariat.

  9. International Conference on Solar Concentrators for the Generation of Electricity or Hydrogen: Book of Abstracts

    Energy Technology Data Exchange (ETDEWEB)

    McConnell, R.; Symko-Davies, M.; Hayden, H.

    2005-05-01

    The International Conference on Solar Concentrators for the Generation of Electricity or Hydrogen provides an opportunity to learn about current significant research on solar concentrators for generating electricity or hydrogen. The conference will emphasize in-depth technical discussions of recent achievements in technologies that convert concentrated solar radiation to electricity or hydrogen, with primary emphasis on photovoltaic (PV) technologies. Very high-efficiency solar cells--above 37%--were recently developed, and are now widely used for powering satellites. This development demands that we take a fresh look at the potential of solar concentrators for generating low-cost electricity or hydrogen. Solar electric concentrators could dramatically overtake other PV technologies in the electric utility marketplace because of the low capital cost of concentrator manufacturing facilities and the larger module size of concentrators. Concentrating solar energy also has advantages for th e solar generation of hydrogen. Around the world, researchers and engineers are developing solar concentrator technologies for entry into the electricity generation market and several have explored the use of concentrators for hydrogen production. The last conference on the subject of solar electric concentrators was held in November of 2003 and proved to be an important opportunity for researchers and developers to share new and crucial information that is helping to stimulate projects in their countries.

  10. Fiscal 1994 achievement report. International Clean Energy Network Using Hydrogen Conversion (WE-NET) technology

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    Research and development was made for the WE-NET (World Energy Network) project which aims to carry out hydrogen production, transportation, and supply to consumers, by the use of renewable energy. In this fiscal year, surveys were conducted of the status of research and development in each of the fields, and research was started on element technologies in some of the fields. Under subtask 1, surveys and studies were started for pilot plant phase 2. Under subtask 2, an international symposium was held for the enhancement of technical information exchange. Under subtask 3, a liquid hydrogen system conceptual design was prepared for the estimation of facility cost, etc. Under subtask 4, small experimental cells were fabricated for evaluating electrode bonding methods. Under subtask 5, studies were made about the processes of the helium Brayton cycle and hydrogen Claude cycle for the development of a large-scale hydrogen liquefaction plant. Under subtasks 6-9, furthermore, surveys and studies were conducted about low-temperature substance technology, hydrogen energy, hydrogen combustion turbines, and so forth. (NEDO)

  11. Definition, analysis and experimental investigation of operation modes in hydrogen-renewable-based power plants incorporating hybrid energy storage

    International Nuclear Information System (INIS)

    Valverde, L.; Pino, F.J.; Guerra, J.; Rosa, F.

    2016-01-01

    Highlights: • A conceptual analysis of operation modes in energy storage plants is presented. • Key Performance Indicators to select operation modes are provided. • The approach has been applied to a laboratory hybrid power plant. • The methodology provides guidance for the operation of hybrid power plants. - Abstract: This paper is concerned with Operating Modes in hybrid renewable energy-based power plants with hydrogen as the intermediate energy storage medium. Six operation modes are defined according to plant topology and the possibility of operating electrolyzer and fuel cell at steady-power or partial load. A methodology for the evaluation of plant performance is presented throughout this paper. The approach includes a set of simulations over a fully validated model, which are run in order to compare the proposed operation modes in various weather conditions. Conclusions are drawn from the simulation stage using a set of Key Performance Indicators defined in this paper. This analysis yields the conclusion that certain modes are more appropriate from technical and practical standpoints when they are implemented in a real plant. From the results of the simulation assessment, selected operating modes are applied to an experimental hydrogen-based pilot plant to illustrate and validate the performance of the proposed operation modes. Experimental results confirmed the simulation study, pointing out the advantages and disadvantages of each operation mode in terms of performance and equipment durability.

  12. Modeling and control design of hydrogen production process for an active hydrogen/wind hybrid power system

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Tao; Francois, Bruno [L2EP, Ecole Centrale de Lille, Cite Scientifique, BP48, 59651, Villeneuve d' Ascq (France)

    2009-01-15

    This paper gives a control oriented modeling of an electrolyzer, as well as the ancillary system for the hydrogen production process. A Causal Ordering Graph of all necessary equations has been used to illustrate the global scheme for an easy understanding. The model is capable of characterizing the relations among the different physical quantities and can be used to determine the control system ensuring efficient and reliable operation of the electrolyzer. The proposed control method can manage the power flow and the hydrogen flow. The simulation results have highlighted the variation domains and the relations among the different physical quantities. The model has also been experimentally tested in real time with a Hardware-In-the-Loop Simulation before being integrated in the test bench of the active wind energy conversion system. (author)

  13. Nano-porous inorganic-organic hybrid solids: some new materials for hydrogen storage?; Les solides hybrides inorganiques-organiques nanoporeux: de nouveaux materiaux pour le stockage de l'hydrogene?

    Energy Technology Data Exchange (ETDEWEB)

    Serre, Ch.; Loiseau, Th.; Devic, T.; Ferey, G. [Institut Lavoisier, UMR CNRS 8180, 78 - Versailles (France); Latroche, M. [Laboratoire de Chimie Metallurgique des Terres Rares (LCMTR), UPR 209, 94 - Thiais (France); Llewellyn, Ph. [Universite de Provence, Madirel, 13 - Marseille (France); Chang, J.S. [KRICT, Daejon (Korea, Republic of)

    2007-07-01

    Recently have been studied chromium and aluminium carboxylates MIL-53(Cr, Al), formed from an assembly of octahedrons chains and for hybrid solids formed with octahedrons trimers (MIL-100 and MIL-101). The compounds MIL-53(Cr, Al) are microporous ({phi} {approx} 8 Angstroms, while the solids MIL-100 and MIL-101 have very large porous volumes (V {approx} 380-700000 (Angstroms){sup 3}), meso-pores ({phi} {approx} 25-34 Angstroms) and a zeolitic architecture. The resulting specific surface areas are important (between 1000 m{sup 2}.g{sup -1} for the MIL-53 solids, until 4000 m{sup 2}.g{sup -1} for the MIL-101 compound. Here is presented their hydrogen adsorption properties, at 77 K and 298 K. The hydrogen adsorption kinetics has been tested on the MIL-53(Cr) solid at 77 K. Hydrogen adsorption micro-calorimetry experiments have been carried out on these solids between 0 and 1 bar in order to obtain data on the strongest interactions between hydrogen and the porous basic structure. (O.M.)

  14. Concept for lowest emissions of a hydrogen internal combustion engine; Niedrigstemissionskonzept fuer einen wasserstoffbetriebenen Verbrennungsmotor

    Energy Technology Data Exchange (ETDEWEB)

    Fouquet, Marcel Christian Thomas

    2012-03-15

    This paper describes a concept with lowest emissions for a hydrogen internal combustion engine for passenger cars. With optimisation of the combustion concept the level of nitrogen oxide is below 90%, hydrocarbon and carbon monoxide below 99% of the SULEV target (CARB). This concept enables a potential in power density that is comparable to current supercharged combustion engines at lowest emission level without catalytic aftertreatment. Additionally with a catalytic aftertreatment system, the emission level of a current hydrogen combustion engine (mono-fuel) is lowered to a level, that this car can be labeled as air cleaning vehicle for hydrocarbons and carbon monoxide.

  15. Chemical-clathrate hybrid hydrogen storage: storage in both guest and host.

    Science.gov (United States)

    Strobel, Timothy A; Kim, Yongkwan; Andrews, Gary S; Ferrell, Jack R; Koh, Carolyn A; Herring, Andrew M; Sloan, E Dendy

    2008-11-12

    Hydrogen storage from two independent sources of the same material represents a novel approach to the hydrogen storage problem, yielding storage capacities greater than either of the individual constituents. Here we report a novel hydrogen storage scheme in which recoverable hydrogen is stored molecularly within clathrate cavities as well as chemically in the clathrate host material. X-ray diffraction and Raman spectroscopic measurements confirm the formation of beta-hydroquinone (beta-HQ) clathrate with molecular hydrogen. Hydrogen within the beta-HQ clathrate vibrates at considerably lower frequency than hydrogen in the free gaseous phase and rotates nondegenerately with splitting comparable to the rotational constant. Compared with water-based clathrate hydrate phases, the beta-HQ+H2 clathrate shows remarkable stability over a range of p-T conditions. Subsequent to clathrate decomposition, the host HQ was used to directly power a PEM fuel cell. With one H2 molecule per cavity, 0.61 wt % hydrogen may be stored in the beta-HQ clathrate cavities. When this amount is combined with complete dehydrogenation of the host hydroxyl hydrogens, the maximum hydrogen storage capacity increases nearly 300% to 2.43 wt %.

  16. Texas Hydrogen Highway Fuel Cell Hybrid Bus and Fueling Infrastructure Technology Showcase - Final Scientific/Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Hitchcock, David

    2012-06-29

    The Texas Hydrogen Highway project has showcased a hydrogen fuel cell transit bus and hydrogen fueling infrastructure that was designed and built through previous support from various public and private sector entities. The aim of this project has been to increase awareness among transit agencies and other public entities on these transportation technologies, and to place such technologies into commercial applications, such as a public transit agency. The initial project concept developed in 2004 was to show that a skid-mounted, fully-integrated, factory-built and tested hydrogen fueling station could be used to simplify the design, and lower the cost of fueling infrastructure for fuel cell vehicles. The approach was to design, engineer, build, and test the integrated fueling station at the factory then install it at a site that offered educational and technical resources and provide an opportunity to showcase both the fueling station and advanced hydrogen vehicles. The two primary technology components include: Hydrogen Fueling Station: The hydrogen fueling infrastructure was designed and built by Gas Technology Institute primarily through a funding grant from the Texas Commission on Environmental Quality. It includes hydrogen production, clean-up, compression, storage, and dispensing. The station consists of a steam methane reformer, gas clean-up system, gas compressor and 48 kilograms of hydrogen storage capacity for dispensing at 5000 psig. The station is skid-mounted for easy installation and can be relocated if needed. It includes a dispenser that is designed to provide temperaturecompensated fills using a control algorithm. The total station daily capacity is approximately 50 kilograms. Fuel Cell Bus: The transit passenger bus built by Ebus, a company located in Downey, CA, was commissioned and acquired by GTI prior to this project. It is a fuel cell plug-in hybrid electric vehicle which is ADA compliant, has air conditioning sufficient for Texas operations

  17. Bigger hybrid loader on the drawing board : Mining Technologies International hybrid gets rave reviews for power and comfort

    Energy Technology Data Exchange (ETDEWEB)

    Tollinsky, N.

    2010-12-01

    This article presented a hybrid loader that reduces diesel emissions in underground mining. Sudbury-based Mining Technologies International (MTI) plans to build a 4 cubic yard loader in 2011, following the successful trial of a smaller 1.5 cubic yard machine at the CANMET experimental mine in Val d'Or, Quebec. The prototype hybrid loader was equipped with a metal hydride battery pack and a 2-cylinder, 35 hp Deutz engine. Performance testing revealed that the machine is capable of providing much more torque than originally expected and that it has more power compared to a mechanical drive machine. Operators at the CANMET mine also gave the hybrid loader high marks for comfort. The MTI loaders are equipped with a load sensing hydraulics system to eliminate jarring movement. The prototype experienced some premature failures in the flex coupling, which was subsequently replaced at the MTI shop in Sudbury. The primary reason for building the hybrid loader was to reduce diesel emissions underground in anticipation of stricter emission standards planned by the Mine Safety and Health Administration, the United States Environmental Protection Agency and CANMET for 2014. Compared to a conventional machine, there is virtually no exhaust from the hybrid loader. It is an ideal machine for a mine with very limited ventilation. Since the loader runs off the battery, MTI is currently looking at battery technologies other than metal hydrides to obtain a much higher energy density. Diesel is used to recharge the loader, and eliminates the need to plug in the unit between shifts. 1 ref., 2 figs.

  18. A hybrid tandem solar cell based on hydrogenated amorphous silicon and dye-sensitized TiO{sub 2} film

    Energy Technology Data Exchange (ETDEWEB)

    Hao Sancun [Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, 362021 (China); Institute of Photo-Electronics of Nankai University, Tianjin 300071 (China); Jiangsu Shuangdeng Group Co. Ltd, Thaizhou, Jiangsu, 225526 (China); Wu Jihuai, E-mail: jhwu@hqu.edu.cn [Institute of Materials Physical Chemistry, Huaqiao University, Quanzhou, 362021 (China); Sun Zhonglin [Institute of Photo-Electronics of Nankai University, Tianjin 300071 (China)

    2012-01-01

    Hydrogenated amorphous silicon film (a-Si:H) as top cell is introduced to dye-sensitized titanium dioxide nanocrystalline solar cell (DSSC) as bottom cell to assemble a hybrid tandem solar cell. The hybrid tandem solar cell fabricated with the thicknesses a-Si:H layer of 235 nm, ZnO/Pt interlayer of 100 nm and DSSC layer of 8.5 {mu}m achieves a photo-to-electric energy conversion efficiency of 8.31%, a short circuit current density of 10.61 mA{center_dot}cm{sup -2} and an open-circuit voltage of 1.45 V under a simulated solar light irradiation of 100 mW{center_dot}cm{sup -2}.

  19. Air-steam hybrid engine : an alternative to internal combustion.

    Science.gov (United States)

    2011-03-01

    In this Small Business Innovation Research (SBIR) Phase 1 project, an energy-efficient air-steam propulsion system has been developed and patented, and key performance attributes have been demonstrated to be superior to those of internal combustion e...

  20. NREL Showcases Hydrogen Internal Combustion Engine Bus, Helps DOE Set Standards for Outreach (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2010-11-01

    This fact sheet describes the National Renewable Energy Laboratory's (NREL's) accomplishments in showcasing a Ford hydrogen-powered internal combustion engine (H2ICE) bus at The Taste of Colorado festival in Denver. NREL started using its U.S. Department of Energy-funded H2ICE bus in May 2010 as the primary shuttle vehicle for VIP visitors, members of the media, and new employees. In September 2010, NREL featured the bus at The Taste of Colorado. This was the first major outreach event for the bus. NREL's educational brochure, vehicle wrap designs, and outreach efforts serve as a model for other organizations with DOE-funded H2ICE buses. Work was performed by the Hydrogen Education Group and Market Transformation Group in the Hydrogen Technologies and Systems Center.

  1. Start up system for hydrogen generator used with an internal combustion engine

    Science.gov (United States)

    Houseman, J.; Cerini, D. J. (Inventor)

    1977-01-01

    A hydrogen generator provides hydrogen rich product gases which are mixed with the fuel being supplied to an internal combustion engine for the purpose of enabling a very lean mixture of that fuel to be used, whereby nitrous oxides emitted by the engine are minimized. The hydrogen generator contains a catalyst which must be heated to a pre-determined temperature before it can react properly. To simplify the process of heating up the catalyst at start-up time, either some of the energy produced by the engine such as engine exhaust gas, or electrical energy produced by the engine, or the engine exhaust gas may be used to heat up air which is then used to heat the catalyst.

  2. Ultrapure hydrogen thermal compressor based on metal hydrides for fuel cells and hybrid vehicles

    International Nuclear Information System (INIS)

    Almasan, V.; Biris, A.; Coldea, I.; Lupu, D.; Misan, I.; Popeneciu, G.; Ardelean, O.

    2007-01-01

    Full text: In hydrogen economy, efficient compressors are indispensable elements in the storage, transport and distribution of the produced hydrogen. Energetic efficient technologies can contribute to H 2 pipelines transport to the point of use and to distribute H 2 by refuelling stations. Characteristic for metal hydrides systems is the wide area of possibilities to absorb hydrogen at low pressure from any source of hydrogen, to store and deliver it hydrogen at high pressure (compression ratio more than 30). On the basis of innovative concepts and advanced materials for H 2 storage/compression (and fast thermal transfer), a fast mass (H 2 ) and heat transfer unit will be developed suitable to be integrated in a 3 stage thermal compressor. Metal hydrides used for a three stage hydrogen compression system must have different equilibrium pressures, namely: for stage 1, low pressure H 2 absorption and resistant to poisoning with impurities of hydrogen, for stage 2, medium pressure H 2 absorption and for stage 3, high pressure hydrogen delivery (120 bar). In the case of compression device based on metallic hydrides the most important properties are the hydrogen absorption/desorption rate, a smaller process enthalpy and a great structural stability on long term hydrogen absorption/desorption cycling. These properties require metal hydrides with large differences between the hydrogen absorption and desorption pressures at equilibrium, within a rather small temperature range. The main goal of this work is to search and develop metal hydride integrated systems for hydrogen purification, storage and compression. After a careful screening three hydrogen absorbing alloys will be selected. After selection, the work up of the alloys composition on the bases of detailed solid state studies, new multi-component alloys will be developed, with suitable thermodynamic and kinetic properties for a hydrogen compressor. The results of the study are the following: new types of hydrogen

  3. Cost of generating tritium internal and external to a tokamak hybrid reactor

    International Nuclear Information System (INIS)

    Crotzer, M.E.; Heck, F.M.; Steinke, K.C.

    1981-01-01

    The costs associated with producing tritium internal and external to a thorium-based tokamak hybrid are estimated for a number of scenarios and the resulting impact on the symbiotic system cost of electricity calculated. For tritium generation within the hybrid, both continuous and batch production is analyzed. For external production, the lithium-bearing blanket is replaced with thorium and the tritium is generated in the client fission reactors. Continuous tritium production within the hybrid is found to increase the cost of electricity from 1.4 to 4.0 mills/kW-h. Batch tritium production can increase the cost of electricity by 10 mills/kW-h. Producing tritium outside the hybrid, and thereby enhancing client support, increases the cost of electricity from 1.8 to 4.1 mills/kW-h

  4. THE HYDROGEN-FUELLED INTERNAL COMBUSTION ENGINES FOR MARINE APPLICATIONS WITH A CASE STUDY

    Directory of Open Access Journals (Sweden)

    Ibrahim S. Seddiek

    2015-03-01

    Full Text Available Modern marine power plants have been designed to improve the overall ship’s efficiency. This pushed the designers of marine machinery to search for unconventional fuels for these plants. During the previous years, diesel oil has been extensively used on-board ships. Due to the high price of light diesel oil and the environmental problems resulting from the use of heavy fuel oil, it has become necessary to search for an alternative to traditional fuels. As a result, natural gas fuel has been used on-board some types of ships, especially short-voyage cruise ships. Unfortunately, there are still some technical and logistic problems related to the use of natural gas as a fuel, especially as it is considered a non-renewable energy source. The use of hydrogen fuel on-board ships, particularly in modern power plants may contribute to overcoming the above problems. The present paper considers the possibility of the use of hydrogen fuel for marine applications and discusses different stages of hydrogen gas cycle beginning with hydrogen generation process from clean energy until using it as fuel for internal combustion engines on-board one RO/RO ship, named Taba, operating in the Mediterranean Sea. Compared to the diesel engine, the hydrogen fuelled engine is found to be lower in thermal efficiency and fuel consumption, however, some adjustments are needed.

  5. Hydrogen.

    Science.gov (United States)

    Bockris, John O'M

    2011-11-30

    The idea of a "Hydrogen Economy" is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO₂ in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H₂ from the electrolyzer. Methanol made with CO₂ from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan). Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs) by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech.

  6. Numerical Study on the Performance Characteristics of Hydrogen Fueled Port Injection Internal Combustion Engine

    OpenAIRE

    Rosli A. Bakar; Mohammed K. Mohammed; M. M. Rahman

    2009-01-01

    This study was focused on the engine performance of single cylinder hydrogen fueled port injection internal combustion engine. GT-Power was utilized to develop the model for port injection engine. One dimensional gas dynamics was represented the flow and heat transfer in the components of the engine model. The governing equations were introduced first, followed by the performance parameters and model description. Air-fuel ratio was varied from stoichiometric limit to a lean limit and the rota...

  7. Case Studies of integrated hydrogen systems. International Energy Agency Hydrogen Implementing Agreement, Final report for Subtask A of task 11 - Integrated Systems

    Energy Technology Data Exchange (ETDEWEB)

    Schucan, T. [Paul Scherrer Inst., Villigen PSI (Switzerland)

    1999-12-31

    Within the framework of the International Energy Agency Hydrogen Implementing Agreement, Task 11 was undertaken to develop tools to assist in the design and evaluation of existing and potential hydrogen demonstration projects. Emphasis was placed on integrated systems, from input energy to hydrogen end use. Included in the PDF document are the Executive Summary of the final report and the various case studies. The activities of task 11 were focused on near- and mid-term applications, with consideration for the transition from fossil-based systems to sustainable hydrogen energy systems. The participating countries were Canada, Italy, Japan, the Netherlands, Spain, Switzerland and the United States. In order for hydrogen to become a competitive energy carrier, experience and operating data need to be generated and collected through demonstration projects. A framework of scientific principles, technical expertise, and analytical evaluation and assessment needed to be developed to aid in the design and optimization of hydrogen demonstration projects to promote implementation. The task participants undertook research within the framework of three highly coordinated subtasks that focused on the collection and critical evaluation of data from existing demonstration projects around the world, the development and testing of computer models of hydrogen components and integrated systems, and the evaluation and comparison of hydrogen systems. While the Executive Summary reflects work on all three subtasks, this collection of chapters refers only to the work performed under Subtask A. Ten projects were analyzed and evaluated in detail as part of Subtask A, Case Studies. The projects and the project partners were: Solar Hydrogen Demonstration Project, Solar-Wasserstoff-Bayern, Bayernwerk, BMW, Linde, Siemens (Germany); Solar Hydrogen Plant on Residential House, M. Friedli (Switzerland); A.T. Stuart Renewable Energy Test Site; Stuart Energy Systems (Canada); PHOEBUS Juelich

  8. Progress in hydrogen fueled busses

    International Nuclear Information System (INIS)

    Scott, P.B.; Mazaika, D.M.; Tyler, T.

    2004-01-01

    'Full text:' The Thor/ISE fuel cell bus has been in demonstration and revenue service during 2002-2003 at sites including SunLine Transit, Chula Vista Transit, Los Angeles County Metropolitan Transit Authority, and AC Transit in Oakland. By taking advantage of ISE's advanced hybrid-electric drive technology, this 30-foot bus operates with a much smaller fuel cell than those used in other buses of this class. Further, stress on the fuel cell is diminished. Based on the exceptional performance of this prototype bus, the transit agencies listed above have concluded that hybrid electric hydrogen fueled buses are attractive. Two types of hydrogen fueled hybrid electric buses will be described: - fuel cell powered, and - HICE (Hydrogen Internal Combustion Engine) This progress report will include: 1. Experience with the Thor/ISE fuel cell bus, including results from revenue service at two transit locations, 2. Design and fabrication status of the advanced fuel cell buses being built for AC Transit and SunLine Transit, 3. Design and fabrication status of the prototype HHICE (Hybrid electric Hydrogen fueled Internal Combustion Engine) bus that uses a Ford hydrogen burning engine, mated to a generator, rather than a fuel cell. Other than the engine, the drive train in the HHICE bus is nearly identical to that of a fuel cell hybrid-electric bus. Canadian participation in the HHICE bus is extensive, it is a New Flyer platform and will be winter tested in Winnipeg. (author)

  9. Hydrogen

    Directory of Open Access Journals (Sweden)

    John O’M. Bockris

    2011-11-01

    Full Text Available The idea of a “Hydrogen Economy” is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO2 in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H2 from the electrolyzer. Methanol made with CO2 from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan. Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech.

  10. Environmental mitigation for SCC initiation of BWR core internals by hydrogen injection during start-up

    International Nuclear Information System (INIS)

    Dozaki, K.; Abe, A.; Nagata, N.; Takiguchi, H.

    2004-01-01

    Hydrogen injection into the reactor water has been applied to many BWR power stations. Since hydrogen injected accelerates recombination of oxidant generated by water radiolysis, oxidant concentration, such as dissolved oxygen concentration in reactor water can be reduced. As the result of the reduction of oxidant concentration, Electrochemical Corrosion Potential (ECP) at the surface of structural material can be lowered. Lowered ECP moderates Stress Corrosion Cracking (SCC) sensitivity of structural materials, such as stainless steels. As usual, hydrogen injection system begins to work after the plant start-up is finished, when the condition of normal operation is established. Accordingly, Hydrogen Water Chemistry (HWC) does not cover all the period of plant operation. As far as SCC crack growth is considered, loss of HWC during plant start-up does not result in significant crack growth, because of duration of plant start-up is much shorter than that of plant normal operation, when HWC condition is being satisfied. However, the reactor water environment and load conditions during a plant start-up may contribute to the initiation of SCC. It is estimated that the core internals are subjected to the strain rate that may cause susceptibility to SCC initiation during start-up. Dissolved oxygen (DO) and hydrogen peroxide (H 2 O 2 ) has a peak, and ECP is in high levels during start-up. Therefore it is beneficial to perform hydrogen injection during start-up as well in order to suppress SCC initiation. We call it HWC During Start-up (HDS) here. (orig.)

  11. A nano-engineered graphene/carbon nitride hybrid for photocatalytic hydrogen evolution

    Institute of Scientific and Technical Information of China (English)

    Xiaobo Li; Yao Zheng; Anthony F.Masters; Thomas Maschmeyer

    2016-01-01

    A metal-free photocatalytic hydrogen evolution system was successfully fabricated using heteroatom doped graphene materials as electron-transfer co-catalysts and carbon nitride as a semiconductor.The catalytic role of graphene is significantly dependent on the heteroatom dopant of the graphene,such as O,S,B,N doped/undoped graphene co-catalysts,and N-graphene shows the best catalytic hydrogen evolution rate.

  12. Effect of using hydrogen in the power and performance of an internal combustion engine

    Directory of Open Access Journals (Sweden)

    Edwin Tamayo

    2016-12-01

    Full Text Available This study analyzed the real working parameters of an Otto cycle internal combustion engine, using as fuel hydrogen plus gasoline. Two stoichiometric equations were determined. In the first equation, the reagents are octane and air, in the second equation was added the quantity of 3.86 H2 moles obtained from a hydrogen cell. Two sets of equations, for consumption and power, were determined from the chemical equations, working at the conditions of Quito: altitude 2850 msnm, 72.794 kPa of atmospheric pressure and 300 K of temperature. A single cylinder engine powered with hydrogen plus gasoline was used for getting real data of engine power, using mixtures of air-gasoline and hydrogen; the theoretical power without H2 was 3.91 HP and with H2 5.41 HP, it increased 27.1%, the real power is 3.78 HP without H2 and 4.66 HP with H2, it increased 16.7%. Theoretical fuel consumption is 401.61 g/kWh and addition of H2 is less to 373.52 g/kWh, the actual consumption that indicates the manufacturer is 395 g/kWh.

  13. Experimental study of hydrogen as a fuel additive in internal combustion engines

    Energy Technology Data Exchange (ETDEWEB)

    Saanum, Inge

    2008-07-01

    Combustion of hydrocarbons in internal combustion engines results in emissions that can be harmful both to human health and to the environment. Although the engine technology is improving, the emissions of NO{sub x}, PM and UHC are still challenging. Besides, the overall consumption of fossil fuel and hence the emissions of CO{sub 2} are increasing because of the increasing number of vehicles. This has lead to a focus on finding alternative fuels and alternative technologies that may result in lower emissions of harmful gases and lower CO{sub 2} emissions. This thesis treats various topics that are relevant when using blends of fuels in different internal combustion engine technologies, with a particular focus on using hydrogen as a fuel additive. The topics addressed are especially the ones that impact the environment, such as emissions of harmful gases and thermal efficiency (fuel consumption). The thesis is based on experimental work performed at four different test rigs: 1. A dynamic combustion rig with optical access to the combustion chamber where spark ignited premixed combustion could be studied by means of a Schlieren optical setup and a high speed video camera. 2. A spark ignition natural gas engine rig with an optional exhaust gas recycling system. 3. A 1-cylinder diesel engine prepared for homogeneous charge compression ignition combustion. 4. A 6-cylinder standard diesel engine The engine rigs were equipped with cylinder pressure sensors, engine dynamometers, exhaust gas analyzers etc. to enable analyses of the effects of different fuels. The effect of hydrogen blended with methane and natural gas in spark ignited premixed combustion was investigated in the dynamic combustion rig and in a natural gas engine. In the dynamic combustion rig, the effect of hydrogen added to methane on the flame speed and the flame structure was investigated at elevated pressure and temperature. A considerable increase in the flame speed was observed when adding 30 vol

  14. Book of abstracts of the 3rd International conference and the 3rd International School for young scientists Interaction of hydrogen isotopes with structural materials. IHISM-07

    International Nuclear Information System (INIS)

    2007-01-01

    The book involves abstracts of presentations at the 3rd International Conference and the 3rd International School for Young Scientists Interaction of Hydrogen Isotopes with Structural Materials (IHISM-07). The activities of Russian and foreign scientific centers associated with the use of hydrogen isotopes in power engineering, national economy and basic research are considered. The presentations cover the following areas: kinetics and interaction between hydrogen isotopes and solids including effects of radiogenic helium accumulation, hydrides and hydride transformations; structural transformations and mechanical properties; equipment and research techniques [ru

  15. Effect of the Miller cycle on the performance of turbocharged hydrogen internal combustion engines

    International Nuclear Information System (INIS)

    Luo, Qing-he; Sun, Bai-gang

    2016-01-01

    Highlights: • The Miller cycle can increase power density for turbocharged hydrogen engines. • The boundaries is limited by the turbocharged system and valve lift. • Broke power and BSFC of using Miller cycle is the best in three technical methods. - Abstract: Hydrogen is a promising energy carrier, and the port fuel injection (PFI) is a fuel-flexible, durable, and relatively cheap method of energy conversion. However, the contradiction of increasing the power density and controlling NOx emissions limits the wide application of PFI hydrogen internal combustion engines. To address this issue, two typical thermodynamic cycles—the Miller and Otto cycles—are studied based on the calculation model proposed in this study. The thermodynamic cycle analyses of the two cycles are compared and results show that the thermal efficiency of the Miller cycle (η_M_i_l_l_e_r) is higher than η_O_t_t_o, when the multiplied result of the inlet pressure and Miller cycle coefficient (δ_Mγ_M) is larger than that of the Otto cycle (i.e., the value of the inlet pressure ratio multiplied by the Miller cycle coefficient is larger than the value of the inlet pressure ratio of the Otto cycle). The results also show that the intake valve closure (IVC) of the Miller cycle is limited by the inlet pressure and valve lift. The two factors show the boundaries of the Miller cycle in increasing the power density of the turbocharged PFI hydrogen engine. The ways of lean burn + Otto cycle (LO), stoichiometric equivalence ratio burn + EGR + Otto cycle (SEO) and Miller cycle in turbocharged hydrogen engine are compared, the results show that the Miller cycle has the highest power density and the lowest BSFC among the three methods at an engine speed of 2800 rpm and NOx emissions below 100 ppm. The brake power of the Miller cycle increases by 37.7% higher than that of the LO and 26.3% higher than that of SEO, when γ_M is 0.7. The BSFC of the Miller cycle decreases by 16% lower than that of

  16. A Hydrogen-Evolving Hybrid-Electrolyte Battery with Electrochemical/Photoelectrochemical Charging from Water Oxidation.

    Science.gov (United States)

    Jin, Zhaoyu; Li, Panpan; Xiao, Dan

    2017-02-08

    Decoupled hydrogen and oxygen production were successfully embedded into an aqueous dual-electrolyte (acid-base) battery for simultaneous energy storage and conversion. A three-electrode configuration was adopted, involving an electrocatalytic hydrogen-evolving electrode as cathode, an alkaline battery-type or capacitor-type anode as shuttle, and a charging-assisting electrode for electro-/photoelectrochemically catalyzing water oxidation. The conceptual battery not only synergistically outputs electricity and chemical fuels with tremendous specific energy and power densities, but also supports various approaches to be charged by pure or solar-assisted electricity. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Palladium-Catalyzed Atom-Transfer Radical Cyclization at Remote Unactivated C(sp3 )-H Sites: Hydrogen-Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates.

    Science.gov (United States)

    Ratushnyy, Maxim; Parasram, Marvin; Wang, Yang; Gevorgyan, Vladimir

    2018-03-01

    A novel mild, visible-light-induced palladium-catalyzed hydrogen atom translocation/atom-transfer radical cyclization (HAT/ATRC) cascade has been developed. This protocol involves a 1,5-HAT process of previously unknown hybrid vinyl palladium radical intermediates, thus leading to iodomethyl carbo- and heterocyclic structures. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Consumption and efficiency of a passenger car with a hydrogen/oxygen PEFC based hybrid electric drivetrain

    Energy Technology Data Exchange (ETDEWEB)

    Buechi, F.N.; Dietrich, P.; Tsukada, A.; Koetz, R.; Freunberger, S.A. [Paul Scherrer Institut, Electrochemistry Laboratory, CH-5232 Villigen PSI (Switzerland); Paganelli, G.; Laurent, D.; Varenne, P.; Delfino, A.; Magne, P.A.; Walser, D.; Olsommer, D. [Conception et Developpement Michelin, Route Andre-Piller 30, CH-1762 Givisiez (Switzerland)

    2007-08-15

    The main factors for reducing the consumption of a vehicle are reduction of curb weight, air drag and increase in the drivetrain efficiency. Highly efficient drivetrains can be developed based on PEFC technology and curb weight may be limited by an innovative vehicle construction. In this paper, data on consumption and efficiency of a four-place passenger vehicle with a curb weight of 850 kg and an H{sub 2}/O{sub 2} fed PEFC/Supercap hybrid electric powertrain are presented. Hydrogen consumption in the New European Driving Cycle is 0.67 kg H{sub 2}/100 km, which corresponds to a gasoline equivalent consumption of 2.5 l/100 km. When including the energy needed to supply pure oxygen, the calculated consumption increases from 0.67 to 0.69-0.79 kg H{sub 2}/100 km, depending on the method of oxygen production. (Abstract Copyright [2007], Wiley Periodicals, Inc.)

  19. Hydrogen , Hybrid and Electric Propulsion in a Strategy for Sustainable Transport

    DEFF Research Database (Denmark)

    Jørgensen, Kaj

    1998-01-01

    Analysis of the scope for application of hydrogen and electric propulsion for improvement of the fuel cycle efficiency and introduction of renewable energy in the transport sector. The paper compares these fuels with each other as well as with other fuels (especially bio fuels) and outlines...... their individual roles in a strategy for sustainable transport. Finally, the fuels are compared to the present fuels....

  20. Symmetrical synergy of hybrid Co9S8-MoSx electrocatalysts for hydrogen evolution reaction

    KAUST Repository

    Zhou, Xiaofeng; Yang, Xiulin; Hedhili, Mohamed N.; Li, Henan; Min, Shixiong; Ming, Jun; Huang, Kuo-Wei; Zhang, Wenjing; Li, Lain-Jong

    2017-01-01

    There exists a strong demand to replace expensive noble metal catalysts with efficient and earth-abundant catalysts for hydrogen evolution reaction (HER). Recently the Co- and Mo-based sulfides such as CoS2, Co9S8, and MoSx have been considered

  1. Hybrid functional calculations of potential hydrogen storage material: Complex dimagnesium iron hydride

    KAUST Repository

    Ul Haq, Bakhtiar

    2014-06-01

    By employing the state of art first principles approaches, comprehensive investigations of a very promising hydrogen storage material, Mg 2FeH6 hydride, is presented. To expose its hydrogen storage capabilities, detailed structural, elastic, electronic, optical and dielectric aspects have been deeply analysed. The electronic band structure calculations demonstrate that Mg2FeH6 is semiconducting material. The obtained results of the optical bandgap (4.19 eV) also indicate that it is a transparent material for ultraviolet light, thus demonstrating its potential for optoelectronics application. The calculated elastic properties reveal that Mg2FeH6 is highly stiff and stable hydride. Finally, the calculated hydrogen (H2) storage capacity (5.47 wt.%) within a reasonable formation energy of -78 kJ mol-1, at room temperature, can be easily achievable, thus making Mg2FeH6 as potential material for practical H2 storage applications. Copyright © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

  2. Hybrid functional calculations of potential hydrogen storage material: Complex dimagnesium iron hydride

    KAUST Repository

    Ul Haq, Bakhtiar; Kanoun, Mohammed; Ahmed, Rashid; Bououdina, M.; Goumri-Said, Souraya

    2014-01-01

    .%) within a reasonable formation energy of -78 kJ mol-1, at room temperature, can be easily achievable, thus making Mg2FeH6 as potential material for practical H2 storage applications. Copyright © 2014, Hydrogen Energy Publications, LLC. Published

  3. Comprehensive physicochemical studies of a new hybrid material: 2-Amino-4-methyl-3-nitropyridinium hydrogen oxalate

    Science.gov (United States)

    Bryndal, I.; Kucharska, E.; Wandas, M.; Lorenc, J.; Hermanowicz, K.; Mączka, M.; Lis, T.; Marchewka, M.; Hanuza, J.

    2014-01-01

    A new organic-organic salt, 2-amino-4-methyl-3-nitropyridinium hydrogen oxalate (AMNPO), and its deuterium analogue have been synthesized and characterized by means of FT-IR, FT-Raman, DSC and single crystal X-ray studies. The DSC measurements and temperature dependence of the IR and Raman spectra in the range 4-295 K show that it undergoes a reversible phase transition at ∼240 K. At room temperature it crystallizes in noncentrosymmetric space group P21. The unit-cell is built of the 2-amino-4-methyl-3-nitropyridinium cations and oxalate monoanions which are connected via the Nsbnd H⋯O and Osbnd H⋯O hydrogen bonds. The geometrical and hydrogen bond parameters are similar for non-deuterated (at 120 and 293 K) and deuterated compounds (at 90 K). The phase transition is probably a consequence of order-disorder transition inside of hydrogen network. The 6-311G(2d,2p) basis set with B3LYP functional have been used to discuss the structure and vibrational spectra of the studied compound.

  4. Di-ureasil hybrids doped with LiBF{sub 4}: Spectroscopic study of the ionic interactions and hydrogen bonding

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, Mariana [Departamento de Quimica/CQ-VR, Universidade de Tras-os-Montes e Alto Douro, 5001-801 Vila Real (Portugal); Barbosa, Paula C.; Manuela Silva, M.; Smith, Michael J. [Departamento de Quimica/Centro de Quimica, Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Zea Bermudez, Veronica de, E-mail: vbermude@utad.pt [Departamento de Quimica/CQ-VR, Universidade de Tras-os-Montes e Alto Douro, 5001-801 Vila Real (Portugal)

    2011-09-15

    Highlights: {yields} FT-IR and FT-Raman spectroscopy were used to characterize cation interactions in two LiBF{sub 4}-doped di-ureasil networks incorporating POE chains with different length. {yields} Over the range of salt content analyzed the cations bond to amorphous POE chains and form ion contact pairs with BF{sub 4}{sup -}. {yields} A crystalline POE/LiBF{sub 4} complex of unknown stoichiometry emerges at high salt concentration. - Abstract: In the present work Fourier transform infrared and Raman spectroscopy were used to characterize the cation/polymer, cation/cross-link, cation/anion and hydrogen bonding interactions in hybrid electrolytes composed of lithium tetrafluoroborate (LiBF{sub 4}) and di-urea cross-linked poly(oxyethylene) (POE)/siloxane hybrid networks (di-ureasils) designated as d-U(2000) and d-U(600) and incorporating polyether chains with ca. 40.5 and 8.5 oxyethylene repeat units, respectively. Samples with {infinity} > n {>=} 2.5 (where n, composition, is the molar ratio of CH{sub 2}CH{sub 2}O units per Li{sup +} ion) were analyzed. In both di-ureasil systems over the whole range of salt content examined the Li{sup +} ions bond to the ether oxygen atoms of amorphous POE chains and to BF{sub 4}{sup -} ions forming ion contact pairs. Spectroscopic evidences and SEM images confirm the presence of a crystalline POE/LiBF{sub 4} complex of unknown stoichiometry at n < 20 and 25, respectively. Ionic association is particularly important in the case of the d-U(600)-based materials, as a result of the presence of strong hydrogen-bonded aggregates that prevent the establishment of Li{sup +}/urea carbonyl oxygen atom interactions.

  5. Internal friction and Young's modulus measurements in Zr-2.5Nb alloy doped with hydrogen

    International Nuclear Information System (INIS)

    Ritchie, I.G.; Pan, Z.-L.

    1992-01-01

    The presence of hydrides is an important factor in assessing the potential for delayed hydride cracking in Zr-2.5Nb alloys, and consequently, the terminal solid solubility (TSS) of hydrogen in the material is an important parameter. In pure zirconium doped with hydrogen, the TSS is marked by a dissolution peak of internal friction on heating and a truncated precipitation peak associated with hydride nucleation on cooling. These phenomena occur only at low frequencies and are accompanied in torsion pendulum studies by autotwisting of the sample (or zero-point drift) that stops abruptly at the TSS. Neither the dissolution/precipitation peaks nor the autotwisting phenomena are observed in Zr-2.5Nb. However, the TSS is also marked by an abrupt change in the slope of Young's modulus as a function of temperature. This phenomenon is observed regardless of the frequency (in the range 1 Hz to 120 kHz) and in both pure zirconium and Zr-2.5Nb alloys. The reasons for the absence of the dissolution/precipitation peak in Zr-2.5Nb alloys are discussed and the use of Young's modulus changes to investigate the TSS of hydrogen and the hysteresis between heat-up and cool-down TSS curves is demonstrated. (author)

  6. Control of internal combustion engines and hybrid engines; Regelung von Verbrennungsmotoren und Hybridantrieben

    Energy Technology Data Exchange (ETDEWEB)

    Isermann, R. [TU Darmstadt (Germany). Forschungsgruppe Regelungstechnik und Prozessautomatisierung

    2007-07-15

    In the development of internal combustion engines, there are increasingly rigid specifications for further reduction of consumption, exhaust and noise emissions, better specific performance, lower weight, and good driving characteristics. The contributions in this special issue provide an insight into the many aspects of internal combustion engine and hybrid engine control. The editors of at journal took care to select interesting papers presented at the 3. VDI/VDE-GMA conference AUTOREG 2006. They show how control and mechatronics support the high demands on functionality in motor car engineering. (orig.)

  7. Ti-doped hydrogenated diamond like carbon coating deposited by hybrid physical vapor deposition and plasma enhanced chemical vapor deposition

    Science.gov (United States)

    Lee, Na Rae; Sle Jun, Yee; Moon, Kyoung Il; Sunyong Lee, Caroline

    2017-03-01

    Diamond-like carbon films containing titanium and hydrogen (Ti-doped DLC:H) were synthesized using a hybrid technique based on physical vapor deposition (PVD) and plasma enhanced chemical vapor deposition (PECVD). The film was deposited under a mixture of argon (Ar) and acetylene gas (C2H2). The amount of Ti in the Ti-doped DLC:H film was controlled by varying the DC power of the Ti sputtering target ranging from 0 to 240 W. The composition, microstructure, mechanical and chemical properties of Ti-doped DLC:H films with varying Ti concentrations, were investigated using Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), nano indentation, a ball-on-disk tribometer, a four-point probe system and dynamic anodic testing. As a result, the optimum composition of Ti in Ti-doped DLC:H film using our hybrid method was found to be a Ti content of 18 at. %, having superior electrical conductivity and high corrosion resistance, suitable for bipolar plates. Its hardness value was measured to be 25.6 GPa with a low friction factor.

  8. Techno-economic feasibility analysis of hydrogen fuel cell and solar photovoltaic hybrid renewable energy system for academic research building

    International Nuclear Information System (INIS)

    Singh, Anand; Baredar, Prashant; Gupta, Bhupendra

    2017-01-01

    Highlights: • A HFC and SPV HRES for stand-alone applications is proposed. • The FC program computes the optimum cost of HRES components. • HOMER pro software to calculate the optimum performance of HRES. - Abstract: A hydrogen fuel cell (HFC) and solar photovoltaic (SPV) hybrid renewable energy system (HRES) for stand-alone applications is proposed. This system arrangement of a hydrogen tank, battery, and an electrolyzer are used as like the energy storage. The economic viability of using HRES power to supply the electrical load demand of academic research building located at 23°12′N latitude and 77°24′E longitudes, India is examined. The fuzzy logic program computes the optimum value of capital and replacement cost of the components, which is then utilized in HOMER pro software to calculate the optimum performance of HRES. The results shows the HFC and battery bank are the most significant modules of the HRES to meet load demand at late night and early morning hours. The AC primary load consuming 20712.63 kWh/year out of total power generation of HRES which is 24570.72 kWh/year. The excess of electricity produced by HRES is 791.7709 kWh/year with the optimized cost of energy, unmet electrical load and capacity shortage of 0%.

  9. Carbon-Nanotube-Supported Bio-Inspired Nickel Catalyst and Its Integration in Hybrid Hydrogen/Air Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Gentil, Solène [Univ. Grenoble Alpes, CNRS, DCM UMR 5250, 38000 Grenoble France; Laboratoire de Chimie et Biologie des Métaux, Univ. Grenoble Alpes, CNRS UMR5249, CEA, 38000 Grenoble France; Lalaoui, Noémie [Univ. Grenoble Alpes, CNRS, DCM UMR 5250, 38000 Grenoble France; Dutta, Arnab [Pacific Northwest National Laboratory, Richland WA 99532 USA; Current address: Chemistry Department, IIT Gandhinagar, Gujarat 382355 India; Nedellec, Yannig [Univ. Grenoble Alpes, CNRS, DCM UMR 5250, 38000 Grenoble France; Cosnier, Serge [Univ. Grenoble Alpes, CNRS, DCM UMR 5250, 38000 Grenoble France; Shaw, Wendy J. [Pacific Northwest National Laboratory, Richland WA 99532 USA; Artero, Vincent [Laboratoire de Chimie et Biologie des Métaux, Univ. Grenoble Alpes, CNRS UMR5249, CEA, 38000 Grenoble France; Le Goff, Alan [Univ. Grenoble Alpes, CNRS, DCM UMR 5250, 38000 Grenoble France

    2017-01-12

    A biomimetic nickel bis-diphosphine complex incorporating the amino-acid arginine in the outer coordination sphere, was immobilized on modified single-wall carbon nanotubes (SWCNTs) through electrostatic interactions. The sur-face-confined catalyst is characterized by a reversible 2-electron/2-proton redox process at potentials close to the equibrium potential of the H+/H2 couple. Consequently, the functionalized redox nanomaterial exhibits reversible electrocatalytic activity for the H2/2H+ interconversion over a broad range of pH. This system exhibits catalytic bias, analogous to hydrogenases, resulting in high turnover frequencies at low overpotentials for electrocatalytic H2 oxida-tion between pH 0 and 7. This allowed integrating such bio-inspired nanomaterial together with a multicopper oxi-dase at the cathode side in a hybrid bioinspired/enzymatic hydrogen fuel cell. This device delivers ~2 mW cm–2 with an open-circuit voltage of 1.0 V at room temperature and pH 5, which sets a new efficiency record for a bio-related hydrogen fuel cell with base metal catalysts.

  10. Hydrogen system (hydrogen fuels feasibility)

    International Nuclear Information System (INIS)

    Guarna, S.

    1991-07-01

    This feasibility study on the production and use of hydrogen fuels for industry and domestic purposes includes the following aspects: physical and chemical properties of hydrogen; production methods steam reforming of natural gas, hydrolysis of water; liquid and gaseous hydrogen transportation and storage (hydrogen-hydride technology); environmental impacts, safety and economics of hydrogen fuel cells for power generation and hydrogen automotive fuels; relevant international research programs

  11. A Cultural Hybridization Perspective: Emerging Academic Subculture among International Students from East Asia in U.S.

    Science.gov (United States)

    Li, Jian

    2016-01-01

    This research examines the emerging academic subculture of international students from East Asia in U.S. academics from the cultural hybridization perspective. In a knowledge-based economy, international education plays a pivotal role in the global educational environment. Advocacy of international student mobility is essential; international…

  12. A highly polarized hydrogen/deuterium internal gas target embedded in a toroidal magnetic spectrometer

    International Nuclear Information System (INIS)

    Cheever, D.; Ihloff, E.; Kelsey, J.; Kolster, H.; Meitanis, N.; Milner, R.; Shinozaki, A.; Tsentalovich, E.; Zwart, T.; Ziskin, V.; Xiao, Y.; Zhang, C.

    2006-01-01

    A polarized hydrogen/deuterium internal gas target has been constructed and operated at the internal target region of the South Hall Ring (SHR) of the MIT-Bates Linear Accelerator Center to carry out measurements of spin-dependent electron scattering at 850MeV. The target used an Atomic Beam Source (ABS) to inject a flux of highly polarized atoms into a thin-walled, coated storage cell. The polarization of the electron beam was determined using a Compton laser backscattering polarimeter. The target polarization was determined using well-known nuclear reactions. The ABS and storage cell were embedded in the Bates Large Acceptance Toroidal Spectrometer (BLAST), which was used to detect scattered particles from the electron-target interactions. The target has been designed to rapidly (∼8h) switch operation from hydrogen to deuterium. Further, this target was the first to be operated inside a magnetic spectrometer in the presence of a magnetic field exceeding 2kG. An ABS intensity 2.5x10 16 at/s and a high polarization (∼70%) inside the storage cell have been achieved. The details of the target design and construction are described here and the performance over an 18 month period is reported

  13. On the development of an International Curriculum on Hydrogen Safety Engineering and its Implementation into Educational Programmes

    International Nuclear Information System (INIS)

    Dahoe, A.E.; Molkov, V.V.

    2006-01-01

    The present paper provides an overview of the development of an International Curriculum on Hydrogen Safety Engineering and its implementation into new educational programmes. The curriculum has a modular structure, and consists of five basic, six fundamental and four applied modules. The reasons for this particular structure are explained. To accelerate the development of teaching materials and their implementation in training/educational programmes, an annual European Summer School on Hydrogen Safety will be held (the first Summer School is from 15-24 Aug 2006, Belfast, UK), where leading experts deliver keynote lectures to an audience of researchers on topics covering the state-of-the-art in Hydrogen Safety Science and Engineering. The establishment of a Postgraduate Certificate course in Hydrogen Safety Engineering at the University of Ulster (starting in September 2006) as a first step in the development of a worldwide system of Hydrogen Safety education and training is described. (authors)

  14. An efficient route for catalytic activity promotion via hybrid electro-depositional modification on commercial nickel foam for hydrogen evolution reaction in alkaline water electrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Guanshui; He, Yongwei; Wang, Mei; Zhu, Fuchun; Tang, Bin [Research Institute of Surface Engineering, Taiyuan University of Technology, Yingze West Road 79, Taiyuan 030024 (China); Wang, Xiaoguang, E-mail: wangxiaog1982@163.com [Research Institute of Surface Engineering, Taiyuan University of Technology, Yingze West Road 79, Taiyuan 030024 (China); International Iberian Nanotechnology Laboratory (INL), 4715-330 Braga (Portugal)

    2014-09-15

    Highlights: • Mono-Cu surface modification depress the HER activity of Ni-foam. • Hybrid Ni-foam/Cu0.01/Co0.05 exhibits superior HER performance. • Layer-by-layer structure may contribute to a synergistic promoting effect. - Abstract: In this paper, the single- and hybrid-layered Cu, Ni and Co thin films were electrochemically deposited onto the three-dimensional nickel foam as composite cathode catalyst for hydrogen evolution reaction in alkaline water electrolysis. The morphology, structure and chemical composition of the electrodeposited composite catalysts were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX). Electrochemical measurement depicted that, for the case of the monometallic layered samples, the general activity for hydrogen evolution reaction followed the sequence: Ni-foam/Ni > Ni-foam/Co > bare Ni-foam > Ni-foam/Cu. It is noteworthy that, the hybrid-layered Ni-foam/Cu0.01/Co0.05 exhibited the highest catalytic activity towards hydrogen evolution reaction with the current density as high as 2.82 times that of the bare Ni-foam. Moreover, both excellent electrochemical and physical stabilities can also be acquired on the Ni-foam/Cu0.01/Co0.05, making this hybrid-layered composite structure as a promising HER electro-catalyst.

  15. Techno-economic and behavioural analysis of battery electric, hydrogen fuel cell and hybrid vehicles in a future sustainable road transport system in the UK

    International Nuclear Information System (INIS)

    Offer, G.J.; Contestabile, M.; Howey, D.A.; Clague, R.; Brandon, N.P.

    2011-01-01

    This paper conducts a techno-economic study on hydrogen Fuel Cell Electric Vehicles (FCV), Battery Electric Vehicles (BEV) and hydrogen Fuel Cell plug-in Hybrid Electric Vehicles (FCHEV) in the UK using cost predictions for 2030. The study includes an analysis of data on distance currently travelled by private car users daily in the UK. Results show that there may be diminishing economic returns for Plug-in Hybrid Electric Vehicles (PHEV) with battery sizes above 20 kWh, and the optimum size for a PHEV battery is between 5 and 15 kWh. Differences in behaviour as a function of vehicle size are demonstrated, which decreases the percentage of miles that can be economically driven using electricity for a larger vehicle. Decreasing carbon dioxide emissions from electricity generation by 80% favours larger optimum battery sizes as long as carbon is priced, and will reduce emissions considerably. However, the model does not take into account reductions in carbon dioxide emissions from hydrogen generation, assuming hydrogen will still be produced from steam reforming methane in 2030. - Research highlights: → Report diminishing returns for plug-in hybrids with battery sizes above 20 kWh. → The optimum size for a PHEV battery is between 5 and 15 kWh. → Current behaviour decreases percentage electric only miles for larger vehicles. → Low carbon electricity favours larger battery sizes as long as carbon is priced. → Reinforces that the FCHEV is a cheaper option than conventional ICE vehicles in 2030.

  16. Techno-economic and behavioural analysis of battery electric, hydrogen fuel cell and hybrid vehicles in a future sustainable road transport system in the UK

    Energy Technology Data Exchange (ETDEWEB)

    Offer, G.J., E-mail: gregory.offer@imperial.ac.u [Department Earth Science Engineering, Imperial College London, SW7 2AZ London (United Kingdom); Contestabile, M. [Centre for Environmental Policy, Imperial College London, SW7 2AZ (United Kingdom); Howey, D.A. [Department of Electrical and Electronic Engineering, Imperial College London, SW7 2AZ (United Kingdom); Clague, R. [Energy Futures Lab, Imperial College London, SW7 2AZ (United Kingdom); Brandon, N.P. [Department Earth Science Engineering, Imperial College London, SW7 2AZ London (United Kingdom)

    2011-04-15

    This paper conducts a techno-economic study on hydrogen Fuel Cell Electric Vehicles (FCV), Battery Electric Vehicles (BEV) and hydrogen Fuel Cell plug-in Hybrid Electric Vehicles (FCHEV) in the UK using cost predictions for 2030. The study includes an analysis of data on distance currently travelled by private car users daily in the UK. Results show that there may be diminishing economic returns for Plug-in Hybrid Electric Vehicles (PHEV) with battery sizes above 20 kWh, and the optimum size for a PHEV battery is between 5 and 15 kWh. Differences in behaviour as a function of vehicle size are demonstrated, which decreases the percentage of miles that can be economically driven using electricity for a larger vehicle. Decreasing carbon dioxide emissions from electricity generation by 80% favours larger optimum battery sizes as long as carbon is priced, and will reduce emissions considerably. However, the model does not take into account reductions in carbon dioxide emissions from hydrogen generation, assuming hydrogen will still be produced from steam reforming methane in 2030. - Research highlights: {yields} Report diminishing returns for plug-in hybrids with battery sizes above 20 kWh. {yields} The optimum size for a PHEV battery is between 5 and 15 kWh. {yields} Current behaviour decreases percentage electric only miles for larger vehicles. {yields} Low carbon electricity favours larger battery sizes as long as carbon is priced. {yields} Reinforces that the FCHEV is a cheaper option than conventional ICE vehicles in 2030.

  17. Numerical study of hydrogen absorption in a LM-Ni5 hybride reactor

    International Nuclear Information System (INIS)

    Altinisik, K.; Tekin, M.; Mat, M. D.; Altinisik, A.; Veziroglu, T. N.

    2007-01-01

    Metal hydride formation in an Lm-Ni5 storage tank is numerically studied with a continuum mathematical model. The model considers complex heat, and mass transfer and chemical reaction in the reaction bed. It is found that hydride formation enhances at regions with lower equilibrium pressure. Absorbed hydrogen mass increases exponentially at earlier times of hydriding process and slow down after temperature of reaction bed increases due to the heat of reaction. Numerical results agree satisfactorily with the experimental data in the literature

  18. Optimal Hybrid Renewable Airport Power System: Empirical Study on Incheon International Airport, South Korea

    Directory of Open Access Journals (Sweden)

    Seoin Baek

    2016-06-01

    Full Text Available In response to global energy problems (e.g., the oil crisis, the Fukushima accident, the Paris Agreement, the South Korean government has executed a strict renewable energy plan to decrease the country’s dependence on fossil fuel. Public facilities, such as international airports, which use substantial amounts of electricity, are the most in need of government regulation. In this study, we attempt to determine the optimal hybrid electricity generation system for South Korea’s largest airport: Incheon International Airport. In the analysis, we use three scenarios: the current load, 120% of the current load, and 140% of the current load, according to the plan to expand Incheon International Airport. According to the COE (cost of electricity and the NPC (net present cost of the result, it is economically feasible to completely cover the potential increase in the electric load with PV power. Government policy implications and limitations are discussed.

  19. Engineering MoSx/Ti/InP Hybrid Photocathode for Improved Solar Hydrogen Production.

    Science.gov (United States)

    Li, Qiang; Zheng, Maojun; Zhong, Miao; Ma, Liguo; Wang, Faze; Ma, Li; Shen, Wenzhong

    2016-07-19

    Due to its direct band gap of ~1.35 eV, appropriate energy band-edge positions, and low surface-recombination velocity, p-type InP has attracted considerable attention as a promising photocathode material for solar hydrogen generation. However, challenges remain with p-type InP for achieving high and stable photoelectrochemical (PEC) performances. Here, we demonstrate that surface modifications of InP photocathodes with Ti thin layers and amorphous MoSx nanoparticles can remarkably improve their PEC performances. A high photocurrent density with an improved PEC onset potential is obtained. Electrochemical impedance analyses reveal that the largely improved PEC performance of MoSx/Ti/InP is attributed to the reduced charge-transfer resistance and the increased band bending at the MoSx/Ti/InP/electrolyte interface. In addition, the MoSx/Ti/InP photocathodes function stably for PEC water reduction under continuous light illumination over 2 h. Our study demonstrates an effective approach to develop high-PEC-performance InP photocathodes towards stable solar hydrogen production.

  20. A dynamic model of a 100 kW micro gas turbine fuelled with natural gas and hydrogen blends and its application in a hybrid energy grid

    International Nuclear Information System (INIS)

    Di Gaeta, Alessandro; Reale, Fabrizio; Chiariello, Fabio; Massoli, Patrizio

    2017-01-01

    The paper deals with the development of a dynamic model of a commercial 100 kW Micro Gas Turbine (MGT) fuelled with mixtures of standard (i.e. natural gas or methane) and alternative fuels (i.e. hydrogen). The model consists of a first-order differential equation (ODE) describing the dominant dynamics of the MGT imposed by its own control system during production electrical power. The differential equation is coupled to a set of nonlinear maps derived numerically from a detailed 0D thermodynamic matching model of the MGT evaluated over a wide range of operating conditions (i.e. mechanical power, fraction of hydrogen and ambient temperature). The efficiency of the electrical machine with power inverter and power absorbed by auxiliary devices is also taken into account. The resulting model is experimentally validated for a sequence of power step responses of the MGT at different ambient conditions and with different fuel mixtures. The model is suited for simulation and control of hybrid energy grids (HEGs) which rely on advanced use of MGT and hydrogen as energy carrier. In this regard, the MGT model is used in the simulation of an HEG based on an appropriate mix of renewable (non-programmable) and non-renewable (programmable) energy sources with hydrogen storage and its reuse in the MGT. Here, the MGT is used as a programmable energy vector for compensating the deficits of renewable energies (such as solar and wind) with respect to user demand, while excess renewable energy is used to produce hydrogen via electrolysis of water. The simulated HEG comprises a solar PhotoVoltaic (PV) plant (300 kW), an MGT (100 kW) fuelled with natural gas and hydrogen blends, a water electrolyzer (WE) system (8 bar, 56 Nm 3 /h), a hydrogen tank (54 m 3 ), and an Energy Management Control System (EMCS). - Highlights: • A dynamic model of a commercial 100 kW MGT fuelled with natural gas and hydrogen blends is developed. • The model reproduces the electrical power generated by

  1. Development of a Novel Efficient Solid-Oxide Hybrid for Co-generation of Hydrogen and Electricity Using Nearby Resources for Local Application

    Energy Technology Data Exchange (ETDEWEB)

    Tao, Greg, G.; Virkar, Anil, V.; Bandopadhyay, Sukumar; Thangamani, Nithyanantham; Anderson, Harlan, U.; Brow, Richard, K.

    2009-06-30

    Developing safe, reliable, cost-effective, and efficient hydrogen-electricity co-generation systems is an important step in the quest for national energy security and minimized reliance on foreign oil. This project aimed to, through materials research, develop a cost-effective advanced technology cogenerating hydrogen and electricity directly from distributed natural gas and/or coal-derived fuels. This advanced technology was built upon a novel hybrid module composed of solid-oxide fuel-assisted electrolysis cells (SOFECs) and solid-oxide fuel cells (SOFCs), both of which were in planar, anode-supported designs. A SOFEC is an electrochemical device, in which an oxidizable fuel and steam are fed to the anode and cathode, respectively. Steam on the cathode is split into oxygen ions that are transported through an oxygen ion-conducting electrolyte (i.e. YSZ) to oxidize the anode fuel. The dissociated hydrogen and residual steam are exhausted from the SOFEC cathode and then separated by condensation of the steam to produce pure hydrogen. The rationale was that in such an approach fuel provides a chemical potential replacing the external power conventionally used to drive electrolysis cells (i.e. solid oxide electrolysis cells). A SOFC is similar to the SOFEC by replacing cathode steam with air for power generation. To fulfill the cogeneration objective, a hybrid module comprising reversible SOFEC stacks and SOFC stacks was designed that planar SOFECs and SOFCs were manifolded in such a way that the anodes of both the SOFCs and the SOFECs were fed the same fuel, (i.e. natural gas or coal-derived fuel). Hydrogen was produced by SOFECs and electricity was generated by SOFCs within the same hybrid system. A stand-alone 5 kW system comprising three SOFEC-SOFC hybrid modules and three dedicated SOFC stacks, balance-of-plant components (including a tailgas-fired steam generator and tailgas-fired process heaters), and electronic controls was designed, though an overall

  2. Ni-polymer nanogel hybrid particles: A new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride

    International Nuclear Information System (INIS)

    Cai, Haokun; Liu, Liping; Chen, Qiang; Lu, Ping; Dong, Jian

    2016-01-01

    Efficient non-precious metal catalysts are crucial for hydrogen production from borohydride compounds in aqueous media via hydrogen atoms in water. A method for preparing magnetic polymer nanoparticles is developed in this study based on the chemical deposition of nickel onto hydrophilic polymer nanogels. High-resolution transmission electron microscopic and XPS analyses show that Ni exists mainly in the form of NiO in nanogels. Excellent catalytic activities of the nanoparticles are demonstrated for hydrogen generation from the hydrolysis of dimethylamine-borane and sodium borohydride in which the initial TOF (turn-over frequencies) are 376 and 1919 h"−"1, respectively. Kinetic studies also reveal an Arrhenius activation energy of 50.96 kJ mol"−"1 for the hydrolysis of dimethylamine-borane and 47.82 kJ mol"−"1 for the hydrolysis of sodium borohydride, which are lower than those catalyzed by Ru metal. Excellent reusability and the use of water for hydrogen production from dimethylamine-borane provide the additional benefit of using a hybrid catalyst. The principle illustrated in the present study offers a new strategy to explore polymer-transition metal hybrid particles for hydrogen energy technology. - Highlights: • Electroless Ni plating on polymer nanogels generated recyclable catalysts. • The Ni particles proved efficient for H_2 production from borohydride compounds. • The catalysts have lower activation energies than Ru for the hydrolysis. • Borohydride hydrolysis is more beneficial than dehydrogenation in organic solvent.

  3. The production of hydrogen through the uncatalyzed partial oxidation of methane in an internal combustion engine

    Energy Technology Data Exchange (ETDEWEB)

    Karim, Ghazi A.; Wierzba, I. [Department of Mechanical and Manufacturing Engineering, Schulich School of Engineering, University of Calgary, Calgary (Canada)

    2008-04-15

    The thermodynamic and kinetic limitations of the uncatalyzed partial oxidation of methane for the production of synthesis gas, which is made up of mostly hydrogen and carbon monoxide in a variety of proportions, are reviewed. It is suggested that such processes can be made to proceed successfully in a conventional internal combustion engine when operated on excessively rich mixtures of methane and oxygenated air. This is achieved while simultaneously producing power and regenerative exhaust gas heating. Experimental results are described that show a dual fuel engine of the compression ignition type with pilot liquid fuel injection can be operated on excessively rich mixtures of methane and air supplemented with oxygen gas to produce hydrogen rich gas with high methane conversion rates. Similarly, a spark ignition engine was reported to be equally capable of such production and performance. It is shown that there are viable prospects for the simultaneous production of synthesis gas in engines with efficient useful mechanical power and exhaust gas regenerative heating. (author)

  4. A polarized hydrogen/deuterium atomic beam source for internal target experiments

    International Nuclear Information System (INIS)

    Szczerba, D.; Buuren, L.D. van; Brand, J.F.J. van den; Bulten, H.J.; Ferro-Luzzi, M.; Klous, S.; Kolster, H.; Lang, J.; Mul, F.; Poolman, H.R.; Simani, M.C.

    2000-01-01

    A high-brightness hydrogen/deuterium atomic beam source is presented. The apparatus, previously used in electron scattering experiments with tensor-polarized deuterium (Ferro-Luzzi et al., Phys. Rev. Lett. 77 (1996) 2630; van den Brand et al., Phys. Rev. Lett. 78 (1997) 1235; Zhou et al., Phys. Rev. Lett. 82 (1998) 687; Bouwhuis et al., Phys. Rev. Lett. 82 (1999) 3755), was configured as a source for internal target experiments to measure single- and double-polarization observables, with either polarized hydrogen or vector/tensor polarized deuterium. The atomic beam intensity was enhanced by a factor of ∼2.5 by optimizing the Stern-Gerlach focusing system using high tip-field (∼1.5 T) rare-earth permanent magnets, and by increasing the pumping speed in the beam-formation chamber. Fluxes of (5.9±0.2)x10 16 1 H/s were measured in a diameter 12 mmx122 mm compression tube with its entrance at a distance of 27 cm from the last focusing element. The total output flux amounted to (7.6±0.2)x10 16 1 H/s

  5. Hydrogen Fueled Hybrid Solid Oxide Fuel Cell-Gas Turbine (SOFC-GT) System for Long-Haul Rail Application

    Science.gov (United States)

    Chow, Justin Jeff

    Freight movement of goods is the artery for America's economic health. Long-haul rail is the premier mode of transport on a ton-mile basis. Concerns regarding greenhouse gas and criteria pollutant emissions, however, have motivated the creation of annually increasing locomotive emissions standards. Health issues from diesel particulate matter, especially near rail yards, have also been on the rise. These factors and the potential to raise conventional diesel-electric locomotive performance warrants the investigation of using future fuels in a more efficient system for locomotive application. This research evaluates the dynamic performance of a Solid Oxide Fuel Cell-Gas Turbine (SOFC-GT) Hybrid system operating on hydrogen fuel to power a locomotive over a rail path starting from the Port of Los Angeles and ending in the City of Barstow. Physical constraints, representative locomotive operation logic, and basic design are used from a previous feasibility study and simulations are performed in the MATLAB Simulink environment. In-house controls are adapted to and expanded upon. Results indicate high fuel-to-electricity efficiencies of at least 54% compared to a conventional diesel-electric locomotive efficiency of 35%. Incorporation of properly calibrated feedback and feed-forward controls enables substantial load following of difficult transients that result from train kinematics while maintaining turbomachinery operating requirements and suppressing thermal stresses in the fuel cell stack. The power split between the SOFC and gas turbine is deduced to be a deterministic factor in the balance between capital and operational costs. Using hydrogen results in no emissions if renewable and offers a potential of 24.2% fuel energy savings for the rail industry.

  6. Facile In Situ Fabrication of Nanostructured Graphene–CuO Hybrid with Hydrogen Sulfide Removal Capacity

    Institute of Scientific and Technical Information of China (English)

    Sunil P.Lonkar; Vishnu V.Pillai; Samuel Stephen; Ahmed Abdala; Vikas Mittal

    2016-01-01

    A simple and scalable synthetic approach for one-step synthesis of graphene–Cu O(TRGC) nanocomposite by an in situ thermo-annealing method has been developed.Using graphene oxide(GO) and copper hydroxide as a precursors reagent,the reduction of GO and the uniform deposition of in situ formed Cu O nanoparticles on graphene was simultaneously achieved.The method employed no solvents,toxic-reducing agents,or organic modifiers.The resulting nanostructured hybrid exhibited improved H2 S sorption capacity of 1.5 mmol H2S/g-sorbent(3 g S/100 g-sorbent).Due to its highly dispersed sub-20 nm Cu O nanoparticles and large specific surface area,TRGC nanocomposite exhibits tremendous potential for energy and environment applications.

  7. Simulation of hydrogen bubble growth in tungsten by a hybrid model

    International Nuclear Information System (INIS)

    Sang, Chaofeng; Sun, Jizhong; Bonnin, Xavier; Wang, L.; Wang, Dezhen

    2015-01-01

    A two dimensional hybrid code (HIIPC-MC) joining rate-theory and Monte Carlo (MC) methods is developed in this work. We evaluate the cascade-coalescence mechanism contribution to the bubble growth by MC. First, effects of the starting radius and solute deuterium concentration on the bubble growth are studied; then the impacts of the wall temperature and implantation ion flux on the bubble growth are assessed. The simulation indicates that the migration-coalescence of the bubbles and the high pressure inside the bubbles are the main driving forces for the bubble growth, and that neglect of the migration and coalescence would lead to an underestimation of the bubble growth or blistering

  8. Self-organizing hybrid Cartesian grid generation and application to external and internal flow problems

    Energy Technology Data Exchange (ETDEWEB)

    Deister, F.; Hirschel, E.H. [Univ. Stuttgart, IAG, Stuttgart (Germany); Waymel, F.; Monnoyer, F. [Univ. de Valenciennes, LME, Valenciennes (France)

    2003-07-01

    An automatic adaptive hybrid Cartesian grid generation and simulation system is presented together with applications. The primary computational grid is an octree Cartesian grid. A quasi-prismatic grid may be added for resolving the boundary layer region of viscous flow around the solid body. For external flow simulations the flow solver TAU from the ''deutsche zentrum fuer luft- und raumfahrt (DLR)'' is integrated in the simulation system. Coarse grids are generated automatically, which are required by the multilevel method. As an application to an internal problem the thermal and dynamic modeling of a subway station is presented. (orig.)

  9. Internal friction study of hydrides in zirconium at low hydrogen contents

    International Nuclear Information System (INIS)

    Peretti, H.A.; Corso, H.L.; Gonzalez, O.A.; Fernandez, L.; Ghilarducci, A.A.; Salva, H.R.

    1999-01-01

    Full text: Internal friction and shear modulus measurements were carried out on crystal bar zirconium in the as received and hydride conditions using an inverted forced pendulum. Hydriding was achieved in two ways: inside and out of the pendulum. The final hydrogen content determined by fusion analysis in the 'in situ' hydride sample was of 36 ppm. Another sample was hydride by the cathodic charge method with 25 ppm. The thermal solid solubility (TSS) phase boundary presents hysteresis between the precipitation (TSSP) and the dissolution (TSSD) temperatures for the zirconium hydrides. During the first thermal cycling the anelastic effects could be attributed to the δ, ε and metastable γ zirconium hydrides. After 'in situ' annealing at 490 K, these peaks completely disappear in the electrolytically charged sample, while in the 'in situ' hydride, the peaks remain with decreasing intensity. This effect can be understood in terms of the different surface conditions of the samples. (author)

  10. HYBRID SULFUR CYCLE FLOWSHEETS FOR HYDROGEN PRODUCTION USING HIGH-TEMPERATURE GAS-COOLED REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    Gorensek, M.

    2011-07-06

    Two hybrid sulfur (HyS) cycle process flowsheets intended for use with high-temperature gas-cooled reactors (HTGRs) are presented. The flowsheets were developed for the Next Generation Nuclear Plant (NGNP) program, and couple a proton exchange membrane (PEM) electrolyzer for the SO2-depolarized electrolysis step with a silicon carbide bayonet reactor for the high-temperature decomposition step. One presumes an HTGR reactor outlet temperature (ROT) of 950 C, the other 750 C. Performance was improved (over earlier flowsheets) by assuming that use of a more acid-tolerant PEM, like acid-doped poly[2,2'-(m-phenylene)-5,5'-bibenzimidazole] (PBI), instead of Nafion{reg_sign}, would allow higher anolyte acid concentrations. Lower ROT was accommodated by adding a direct contact exchange/quench column upstream from the bayonet reactor and dropping the decomposition pressure. Aspen Plus was used to develop material and energy balances. A net thermal efficiency of 44.0% to 47.6%, higher heating value basis is projected for the 950 C case, dropping to 39.9% for the 750 C case.

  11. Hybrid Endovascular Aortic Aneurysm Repair: Preservation of Pelvic Perfusion with External to Internal Iliac Artery Bypass.

    Science.gov (United States)

    Mansukhani, Neel A; Havelka, George E; Helenowski, Irene B; Rodriguez, Heron E; Hoel, Andrew W; Eskandari, Mark K

    2017-07-01

    Diminished pelvic arterial flow as a result of intentional coverage/embolization of internal iliac arteries (IIA) during isolated endovascular common iliac artery aneurysm (CIAA) repair or endovascular repair of abdominal aortic aneurysms (EVAR) may result in symptomatic pelvic ischemia. Although generally well tolerated, in severe cases, pelvic ischemia may manifest as recalcitrant buttock claudication, vasculogenic impotence, or perineal, vesicle, rectal, and/or spinal cord ischemia. Branched graft technology has recently become available; however, many patients are not candidates for endovascular repair with these devices. Therefore, techniques to preserve pelvic arterial flow are needed. We reviewed our outcomes of isolated endovascular CIAA repair or EVAR in conjunction with unilateral external-internal iliac artery bypass. Single-center, retrospective review of 10 consecutive patients who underwent hybrid endovascular abdominal aortic aneurysm (AAA) or CIAA repair with concomitant external-internal iliac artery bypass between 2006 and 2015. Demographics, index procedural details, postoperative symptoms, hospital length of stay (LOS), follow-up imaging, and bypass patency were recorded. The cohort of 10 patients was all men with a mean age of 71 years (range: 56-84). Hybrid repair consisted of contralateral IIA coil embolization followed by EVAR with external iliac artery-internal iliac artery (EIA-IIA) bypass. All EIA-IIA bypasses were performed via a standard lower quadrant retroperitoneal approach with a prosthetic bypass graft. Technical success was 100%, and there were no perioperative deaths. One patient developed transient paraplegia, 1 patient had buttock claudication on the side of his hypogastric embolization contralateral to his iliac bypass, and 1 developed postoperative impotence. 20% of patients sustained long-term complications (buttock claudication and postoperative impotence). Mean LOS was 2.8 days (range: 1-9 days). Postoperative imaging

  12. Hybrid endovascular and surgical approach for mycotic pseudoaneurysms of the extracranial internal carotid artery

    Directory of Open Access Journals (Sweden)

    Daniela Mazzaccaro

    2014-11-01

    Full Text Available Objectives: Mycotic pseudoaneurysms of the extracranial internal carotid artery are rare, and their management often represents a challenge, but treatment is necessary due to the high risk of rupture and distal brain embolization. Systemic antibiotics associated with open surgical excision of the infected tissues and carotid reconstruction using autologous grafts are the treatment of choice. The use of endovascular techniques still remains controversial in infective fields; however, it can be an attractive alternative in high-risk patients or more often as a “temporary” solution to achieve immediate bleeding control for a safe surgical reconstruction. Methods: We discuss the unusual case of an extracranial right internal carotid artery mycotic pseudoaneurysm following methicillin-resistant Staphylococcus aureus infection, in a patient with poor general conditions. Results and Conclusion: The lesion was successfully treated using a hybrid endovascular and surgical procedure.

  13. Internal stress distribution of X-ring using photoelastic experimental hybrid method

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, Alunda Ouma [Dedan Kimathi University of Technology, Nyeri (Kenya); Hawong, Jai Sug; Lim, Hyun Seok [Yeungnam University, Gyeongsan (Korea, Republic of); Shin, Dong Chul [Koje College, Geoje (Korea, Republic of)

    2014-05-15

    Sealing elements are essential parts of many machines, and are used to prevent the loss of a fluid or gas. When such fluids are not properly sealed, catastrophic failures may result. Many different types of rings have been developed to suit various industrial needs. Considerable research has been done on the O-ring. We analyze the internal stresses developed in an X-ring under a uniform squeeze rate of 20%, which is suitable for static applications, using a photoelastic experimental hybrid method. The internal pressures applied were 0.98, 1.96, 2.94, 3.92, 4.90, and 5.88 MPa. We show that sealing rings with X geometry have considerably higher internal stresses than O-ring seals. In addition, we demonstrate that after extrusion, for an internal pressure of 5.88 MPa, the two lobes on the upper contact surface merge, thereby increasing the contact length of the upper side significantly. Extrusion in the X-ring occurred when the internal pressure was 4.90 MPa.

  14. A green hydrogen economy

    Energy Technology Data Exchange (ETDEWEB)

    Clark, W.W. II [Clark Communications, Beverly Hills, CA (United States). Green Hydrogen Scientific Advisory Committee; Rifkin, J. [The Foundation on Economic Trends (United States)

    2006-11-15

    This paper is the result of over a dozen scholars and practitioners who strongly felt that a hydrogen economy and hence the future is closer than some American politicians and bureaucrats state. Moreover, when seen internationally, there is strong evidence, the most recent and obvious ones are the proliferation of hybrid vehicles, that for any nation-state to be energy independent it must seek a renewable or green hydrogen future in the near term. The State of California has once again taken the lead in this effort for both an energy-independent future and one linked strongly to the hydrogen economy. Then why a hydrogen economy in the first instance? The fact is that hydrogen most likely will not be used for refueling of vehicles in the near term. The number of vehicles to make hydrogen commercially viable will not be in the mass market by almost all estimates until 2010. However, it is less than a decade away. The time frame is NOT 30-40 years as some argue. The hydrogen economy needs trained people, new ventures and public-private partnerships now. The paper points out how the concerns of today, including higher costs and technologies under development, can be turned into opportunities for both the public and private sectors. It was not too long ago that the size of a mobile phone was that of a briefcase, and then almost 10 years ago, the size of a shoe box. Today, they are not only the size of a man's wallet but also often given away free to consumers who subscribe or contract for wireless services. While hydrogen may not follow this technological commercialization exactly, it certainly will be on a parallel path. International events and local or regional security dictate that the time for a hydrogen must be close at hand. (author)

  15. A green hydrogen economy

    International Nuclear Information System (INIS)

    Clark, Woodrow W.; Rifkin, Jeremy

    2006-01-01

    This paper is the result of over a dozen scholars and practitioners who strongly felt that a hydrogen economy and hence the future is closer than some American politicians and bureaucrats state. Moreover, when seen internationally, there is strong evidence, the most recent and obvious ones are the proliferation of hybrid vehicles, that for any nation-state to be energy independent it must seek a renewable or green hydrogen future in the near term. The State of California has once again taken the lead in this effort for both an energy-independent future and one linked strongly to the hydrogen economy. Then why a hydrogen economy in the first instance? The fact is that hydrogen most likely will not be used for refueling of vehicles in the near term. The number of vehicles to make hydrogen commercially viable will not be in the mass market by almost all estimates until 2010. However, it is less than a decade away. The time frame is NOT 30-40 years as some argue. The hydrogen economy needs trained people, new ventures and public-private partnerships now. The paper points out how the concerns of today, including higher costs and technologies under development, can be turned into opportunities for both the public and private sectors. It was not too long ago that the size of a mobile phone was that of a briefcase, and then almost 10 years ago, the size of a shoe box. Today, they are not only the size of a man's wallet but also often given away free to consumers who subscribe or contract for wireless services. While hydrogen may not follow this technological commercialization exactly, it certainly will be on a parallel path. International events and local or regional security dictate that the time for a hydrogen must be close at hand

  16. Energy, exergy and sustainability analyses of hybrid renewable energy based hydrogen and electricity production and storage systems: Modeling and case study

    International Nuclear Information System (INIS)

    Caliskan, Hakan; Dincer, Ibrahim; Hepbasli, Arif

    2013-01-01

    In this study, hybrid renewable energy based hydrogen and electricity production and storage systems are conceptually modeled and analyzed in detail through energy, exergy and sustainability approaches. Several subsystems, namely hybrid geothermal energy-wind turbine-solar photovoltaic (PV) panel, inverter, electrolyzer, hydrogen storage system, Proton Exchange Membrane Fuel Cell (PEMFC), battery and loading system are considered. Also, a case study, based on hybrid wind–solar renewable energy system, is conducted and its results are presented. In addition, the dead state temperatures are considered as 0 °C, 10 °C, 20 °C and 30 °C, while the environment temperature is 30 °C. The maximum efficiencies of the wind turbine, solar PV panel, electrolyzer, PEMFC are calculated as 26.15%, 9.06%, 53.55%, and 33.06% through energy analysis, and 71.70%, 9.74%, 53.60%, and 33.02% through exergy analysis, respectively. Also, the overall exergy efficiency, ranging from 5.838% to 5.865%, is directly proportional to the dead state temperature and becomes higher than the corresponding energy efficiency of 3.44% for the entire system. -- Highlights: ► Developing a three-hybrid renewable energy (geothermal–wind–solar)-based system. ► Undertaking a parametric study at various dead state temperatures. ► Investigating the effect of dead state temperatures on exergy efficiency

  17. New type of microengine using internal combustion of hydrogen and oxygen

    Science.gov (United States)

    Svetovoy, Vitaly B.; Sanders, Remco G. P.; Ma, Kechun; Elwenspoek, Miko C.

    2014-01-01

    Microsystems become part of everyday life but their application is restricted by lack of strong and fast motors (actuators) converting energy into motion. For example, widespread internal combustion engines cannot be scaled down because combustion reactions are quenched in a small space. Here we present an actuator with the dimensions 100 × 100 × 5 μm3 that is using internal combustion of hydrogen and oxygen as part of its working cycle. Water electrolysis driven by short voltage pulses creates an extra pressure of 0.5–4 bar for a time of 100–400 μs in a chamber closed by a flexible membrane. When the pulses are switched off this pressure is released even faster allowing production of mechanical work in short cycles. We provide arguments that this unexpectedly fast pressure decrease is due to spontaneous combustion of the gases in the chamber. This actuator is the first step to truly microscopic combustion engines. PMID:24599052

  18. New type of microengine using internal combustion of hydrogen and oxygen.

    Science.gov (United States)

    Svetovoy, Vitaly B; Sanders, Remco G P; Ma, Kechun; Elwenspoek, Miko C

    2014-03-06

    Microsystems become part of everyday life but their application is restricted by lack of strong and fast motors (actuators) converting energy into motion. For example, widespread internal combustion engines cannot be scaled down because combustion reactions are quenched in a small space. Here we present an actuator with the dimensions 100 × 100 × 5 μm(3) that is using internal combustion of hydrogen and oxygen as part of its working cycle. Water electrolysis driven by short voltage pulses creates an extra pressure of 0.5-4 bar for a time of 100-400 μs in a chamber closed by a flexible membrane. When the pulses are switched off this pressure is released even faster allowing production of mechanical work in short cycles. We provide arguments that this unexpectedly fast pressure decrease is due to spontaneous combustion of the gases in the chamber. This actuator is the first step to truly microscopic combustion engines.

  19. INCREASING THE THERMOSTABILITY OF THE NEUTRAL PROTEINASE OF BACILLUS-STEAROTHERMOPHILUS BY IMPROVEMENT OF INTERNAL HYDROGEN-BONDING

    NARCIS (Netherlands)

    EIJSINK, VGH; VRIEND, G; VANDERZEE, [No Value; VANDENBURG, B; VENEMA, G

    1992-01-01

    In an attempt to increase the thermostability of the neutral proteinase of Bacillus stearothermophilus the buried Ala-170 was replaced by serine. Molecular-dynamics simulations showed that Ser-170 stabilizes the enzyme by formation of an internal hydrogen bond. In addition, the hydroxy group of

  20. Self adaptive internal combustion engine control for hydrogen mixtures using piezoelectric transducers for dynamic cylinder pressure monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Courteau, R.; Bose, T.K. [Quebec Univ., Trois-Rivieres, PQ (Canada). Institut de recherche sur l' hydrogene

    2004-07-01

    Hydrogen internal combustion engine research at the Hydrogen Research Institute includes the following infrastructure: a 20 square metre test cell, an engine preparation room, a 150 hp dynamometer, exhaust gas analysers and a hydrogen supply. The goal of the research is to develop internal combustion engine technologies that can use hydrogen as a fuel without knocking, backfires, excessive engine wear, and with low emissions. As well as hydrogen, fuels such as biogas are also investigated. Technologies under investigation include adaptive control algorithms, as well as advanced sensors and actuators. The latter include piezolelectrics, optical fibres, nitrogen oxide detectors, and chemical composition detectors. Developments include microprocessor-controlled injection and ignition control systems for both single cylinder and multicylinder engines. Research on the influence of fuel composition on best ignition timing is presented. There is also dynamic cylinder pressure monitoring to prevent knocking make engine state assessments and perform engine calibration. Piezoelectric cylinder pressure sensors are employed, either integrated with the spark plugs, or stand-alone, inserted through separate holes through the cylinder head. tabs, figs.

  1. 9. international congress of the Mexican Hydrogen Society (MHS); 9. congreso Internacional de la Sociedad Mexicana del Hidrogeno (SMH)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-09-15

    The Mexican Hydrogen Society (MHS) and Cinvestav, Saltillo Unit, organized the IX International Congress of the MHS, held in Saltillo, Coahuila, Mexico from September 21 to 25, 2009. Important topics were discussed related to hydrogen technologies, the environment and global climate change during the congress [Spanish] La Sociedad Mexicana del Hidrogeno (SMH) y el Cinvestav, Unidad Saltillo, organizaron el IX Congreso Internacional de la SMH, que se llevo a cabo en la ciudad de Saltillo, Coahuila del 21 al 25 de septiembre de 2009. Durante el desarrollo del Congreso se cubrieron importantes topicos relacionados con las tecnologias del hidrogeno, el medio ambiente y el cambio climatico global.

  2. Nonlinear hybrid simulation of internal kink with beam ion effects in DIII-D

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Wei; Sheng, Zheng-Mao [Department of Physics, Institute for Fusion Theory and Simulation, Zhejiang University, Hangzhou 310027 (China); Fu, G. Y.; Tobias, Benjamin [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Zeeland, Michael Van [General Atomics, San Diego, California 92186-5608 (United States); Wang, Feng [School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China)

    2015-04-15

    In DIII-D sawteething plasmas, long-lived (1,1) kink modes are often observed between sawtooth crashes. The saturated kink modes have two distinct frequencies. The mode with higher frequency transits to a fishbone-like mode with sufficient on-axis neutral beam power. In this work, hybrid simulations with the global kinetic-magnetohydrodynamic (MHD) hybrid code M3D-K have been carried out to investigate the linear stability and nonlinear dynamics of the n = 1 mode with effects of energetic beam ions for a typical DIII-D discharge where both saturated kink mode and fishbone were observed. Linear simulation results show that the n = 1 internal kink mode is unstable in MHD limit. However, with kinetic effects of beam ions, a fishbone-like mode is excited with mode frequency about a few kHz depending on beam pressure profile. The mode frequency is higher at higher beam power and/or narrower radial profile consistent with the experimental observation. Nonlinear simulations have been performed to investigate mode saturation as well as energetic particle transport. The nonlinear MHD simulations show that the unstable kink mode becomes a saturated kink mode after a sawtooth crash. With beam ion effects, the fishbone-like mode can also transit to a saturated kink mode with a small but finite mode frequency. These results are consistent with the experimental observation of saturated kink mode between sawtooth crashes.

  3. Collaboration under the International Partnership for the Hydrogen Economy (IPHE) and the Carbon Sequestration Leadership Forum (CSLF)

    Energy Technology Data Exchange (ETDEWEB)

    Neff, H.J. [Forschungszentrum Juelich (Germany)

    2005-06-01

    The objectives and achievements of the International Partnership for the Hydrogen Economy (IPHE) and the Carbon Sequestration Leadership Forum (CSLF) will be described. Both are agreements between governments and aim at identifying and promoting potential areas of bilateral and multilateral collaboration on new and advanced energy technologies. The IPHE has analysed priorities for international collaboration in research, development, demonstration and utilisation of hydrogen equipment in five areas: hydrogen production, fuel cells, hydrogen storage, codes and standards, socio-economic research. A report on such options is available and a series of IPHE conferences and workshops will pave the way to concrete collaboration projects. The CSLF is focused on development of improved cost-effective technologies for the cost-efficient capture and safe, long-term storage of carbon dioxide (CO{sub 2}) for fossil power plants. The mission of the CSLF is to facilitate the development and deployment of such technologies via collaborative efforts that address key technical issues, as well as economic, and environmental challenges. The CSLF also promotes awareness and champion legal, regulatory, financial, and institutional environments conducive to such technologies. The CSLF has worked out a Technology Roadmap as a guide for the CSLF and its Members that describes possible routes to future CO2 capture, transport and storage needs. Included are modules on the current status of these technologies, ongoing activities in CO{sub 2} capture, transport and storage, and identification of technology gaps and non-technology needs that should be addressed over the next decade. The Technology Roadmap indicates areas where the CSLF can add value through international collaborative effort. Both, hydrogen technologies and CO2 sequestration, are closely connected and will serve an overall strategic framework with clean fossil fuels as a key element of a sustainable energy portfolio

  4. Nickel-Hydrogen Battery Cell Life Test Program Update for the International Space Station

    Science.gov (United States)

    Miller, Thomas B.

    2000-01-01

    NASA and Boeing North America are responsible for constructing the electrical power system for the International Space Station (ISS), which circles the Earth every 90 minutes in a low Earth orbit (LEO). For approximately 55 minutes of this orbit, the ISS is in sunlight, and for the remaining 35 minutes, the ISS is in the Earth s shadow (eclipse). The electrical power system must not only provide power during the sunlight portion by means of the solar arrays, but also store energy for use during the eclipse. Nickel-hydrogen (Ni/H2) battery cells were selected as the energy storage systems for ISS. Each battery Orbital Replacement Unit (ORU) comprises 38 individual series-connected Ni/H2 battery cells, and there are 48 battery ORU s on the ISS. On the basis of a limited Ni/H2 LEO data base on life and performance characteristics, the NASA Glenn Research Center at Lewis Field commenced testing through two test programs: one in-house and one at the Naval Surface Warfare Center in Crane, Indiana.

  5. International Space Station Nickel-Hydrogen Battery On-Orbit Performance

    Science.gov (United States)

    Dalton, Penni; Cohen, Fred

    2002-01-01

    International Space Station (ISS) Electric Power System (EPS) utilizes Nickel-Hydrogen (Ni-H2) batteries as part of its power system to store electrical energy. The batteries are charged during insolation and discharged during eclipse. The batteries are designed to operate at a 35 percent depth of discharge (DOD) maximum during normal operation. Thirty-eight individual pressure vessel (IPV) Ni-H2 battery cells are series-connected and packaged in an Orbital Replacement Unit (ORU). Two ORUs are series-connected utilizing a total of 76 cells to form one battery. The ISS is the first application for low earth orbit (LEO) cycling of this quantity of series-connected cells. The P6 (Port) Integrated Equipment Assembly (IEA) containing the initial ISS high-power components was successfully launched on November 30, 2000. The IEA contains 12 Battery Subassembly ORUs (6 batteries) that provide station power during eclipse periods. This paper will discuss the battery performance data after eighteen months of cycling.

  6. International Space Station Nickel-Hydrogen Battery Start-Up and Initial Performance

    Science.gov (United States)

    Cohen, Fred; Dalton, Penni J.

    2001-01-01

    International Space Station (ISS) Electric Power System (EPS) utilizes Nickel-Hydrogen (Ni-H2) batteries as part of its power system to store electrical energy. The batteries are charged during insolation and discharged during eclipse. The batteries are designed to operate at a 35% depth of discharge (DOD) maximum during normal operation. Thirty eight individual pressure vessel (IPV) Ni-H2 battery cells are series-connected and packaged in an Orbital Replacement Unit (ORU). Two ORUs are series-connected utilizing a total of 76 cells, to form one battery. The ISS is the first application for low earth orbit (LEO) cycling of this quantity of series-connected cells. The P6 Integrated Equipment Assembly (IEA) containing the initial ISS high-power components was successfully launched on November 30, 2000. The IEA contains 12 Battery Subassembly ORUs (6 batteries) that provide station power during eclipse periods. This paper will describe the battery hardware configuration, operation, and role in providing power to the main power system of the ISS. We will also discuss initial battery start-up and performance data.

  7. Update on International Space Station Nickel-Hydrogen Battery On-Orbit Performance

    Science.gov (United States)

    Dalton, Penni; Cohen, Fred

    2003-01-01

    International Space Station (ISS) Electric Power System (EPS) utilizes Nickel-Hydrogen (Ni-H2) batteries as part of its power system to store electrical energy. The batteries are charged during insolation and discharged during eclipse. The batteries are designed to operate at a 35% depth of discharge (DOD) maximum during normal operation. Thirty-eight individual pressure vessel (IPV) Ni-H2 battery cells are series-connected and packaged in an Orbital Replacement Unit (ORU). Two ORUs are series-connected utilizing a total of 76 cells, to form one battery. The ISS is the first application for low earth orbit (LEO) cycling of this quantity of series-connected cells. The P6 (Port) Integrated Equipment Assembly (IEA) containing the initial ISS high-power components was successfully launched on November 30, 2000. The IEA contains 12 Battery Subassembly ORUs (6 batteries) that provide station power during eclipse periods. This paper will discuss the battery performance data after two and a half years of cycling.

  8. Fiscal 1996 achievement report. International Clean Energy Network Using Hydrogen Conversion (WE-NET) technology

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Research and development was performed for the WE-NET (World Energy Network) project which aims to carry out hydrogen production, transportation, and supply to consumers, by the use of renewable energy. Under subtask 1, the whole WE-NET project was subjected to evaluation, which included coordination between the respective tasks. Under subtask 2, information exchange and research cooperation were carried out with research institutes overseas. Under subtask 3, a conceptual design was prepared of a total system using ammonia as the medium for hydrogen transportation, accident data were collected and screened, and safety measures and evaluation techniques were developed and improved. Under subtask 4, the hot press method and the electroless plating method were selected as better electrode bonding methods. Under subtask 5, hydrogen liquefaction cycle processes, liquid hydrogen tankers, storage facilities, etc., were studied. Under subtasks 6-9, furthermore, investigations were conducted about low-temperature substance technology, hydrogen energy, hydrogen combustion turbine, etc. (NEDO)

  9. 16th International Conference on Hybrid Intelligent Systems and the 8th World Congress on Nature and Biologically Inspired Computing

    CERN Document Server

    Haqiq, Abdelkrim; Alimi, Adel; Mezzour, Ghita; Rokbani, Nizar; Muda, Azah

    2017-01-01

    This book presents the latest research in hybrid intelligent systems. It includes 57 carefully selected papers from the 16th International Conference on Hybrid Intelligent Systems (HIS 2016) and the 8th World Congress on Nature and Biologically Inspired Computing (NaBIC 2016), held on November 21–23, 2016 in Marrakech, Morocco. HIS - NaBIC 2016 was jointly organized by the Machine Intelligence Research Labs (MIR Labs), USA; Hassan 1st University, Settat, Morocco and University of Sfax, Tunisia. Hybridization of intelligent systems is a promising research field in modern artificial/computational intelligence and is concerned with the development of the next generation of intelligent systems. The conference’s main aim is to inspire further exploration of the intriguing potential of hybrid intelligent systems and bio-inspired computing. As such, the book is a valuable resource for practicing engineers /scientists and researchers working in the field of computational intelligence and artificial intelligence.

  10. Low temperature internal friction in pure iron charged with hydrogen or deuterium

    International Nuclear Information System (INIS)

    Moser, P.; Dufresne, J.F.; Ritchie, I.G.

    1977-01-01

    The search for the elusive hydrogen Snoek-peak in pure iron has been continued with specimens charged with either hydrogen or deuterium. The peaks observed are attributed to deformation produced during charging and can be classified as an α-type peak and a Snoek-Koester type peak. The detailed behavior of these peaks during systematic outgassing of hydrogen or deuterium is described

  11. Optimal Sizing of a Stand-Alone Hybrid Power System Based on Battery/Hydrogen with an Improved Ant Colony Optimization

    Directory of Open Access Journals (Sweden)

    Weiqiang Dong

    2016-09-01

    Full Text Available A distributed power system with renewable energy sources is very popular in recent years due to the rapid depletion of conventional sources of energy. Reasonable sizing for such power systems could improve the power supply reliability and reduce the annual system cost. The goal of this work is to optimize the size of a stand-alone hybrid photovoltaic (PV/wind turbine (WT/battery (B/hydrogen system (a hybrid system based on battery and hydrogen (HS-BH for reliable and economic supply. Two objectives that take the minimum annual system cost and maximum system reliability described as the loss of power supply probability (LPSP have been addressed for sizing HS-BH from a more comprehensive perspective, considering the basic demand of load, the profit from hydrogen, which is produced by HS-BH, and an effective energy storage strategy. An improved ant colony optimization (ACO algorithm has been presented to solve the sizing problem of HS-BH. Finally, a simulation experiment has been done to demonstrate the developed results, in which some comparisons have been done to emphasize the advantage of HS-BH with the aid of data from an island of Zhejiang, China.

  12. Development of a hybrid multi-scale phantom for Monte-Carlo based internal dosimetry

    International Nuclear Information System (INIS)

    Marcatili, S.; Villoing, D.; Bardies, M.

    2015-01-01

    Full text of publication follows. Aim: in recent years several phantoms were developed for radiopharmaceutical dosimetry in clinical and preclinical settings. Voxel-based models (Zubal, Max/Fax, ICRP110) were developed to reach a level of realism that could not be achieved by mathematical models. In turn, 'hybrid' models (XCAT, MOBY/ROBY, Mash/Fash) allow a further degree of versatility by offering the possibility to finely tune each model according to various parameters. However, even 'hybrid' models require the generation of a voxel version for Monte-Carlo modeling of radiation transport. Since absorbed dose simulation time is strictly related to geometry spatial sampling, a compromise should be made between phantom realism and simulation speed. This trade-off leads on one side in an overestimation of the size of small radiosensitive structures such as the skin or hollow organs' walls, and on the other hand to unnecessarily detailed voxellization of large, homogeneous structures. The Aim of this work is to develop a hybrid multi-resolution phantom model for Geant4 and Gate, to better characterize energy deposition in small structures while preserving reasonable computation times. Materials and Methods: we have developed a pipeline for the conversion of preexisting phantoms into a multi-scale Geant4 model. Meshes of each organ are created from raw binary images of a phantom and then voxellized to the smallest spatial sampling required by the user. The user can then decide to re-sample the internal part of each organ, while leaving a layer of smallest voxels at the edge of the organ. In this way, the realistic shape of the organ is maintained while reducing the voxel number in the inner part. For hollow organs, the wall is always modeled using the smallest voxel sampling. This approach allows choosing different voxel resolutions for each organ according to a specific application. Results: preliminary results show that it is possible to

  13. Multi-unit Inertial Fusion Energy (IFE) plants producing hydrogen fuel

    International Nuclear Information System (INIS)

    Logan, B.G.

    1993-12-01

    A quantitative energy pathway comparison is made between a modern oil refinery and genetic fusion hydrogen plant supporting hybrid-electric cars powered by gasoline and hydrogen-optimized internal combustion engines, respectively, both meeting President Clinton's goal for advanced car goal of 80 mpg gasoline equivalent. The comparison shows that a fusion electric plant producing hydrogen by water electrolysis at 80% efficiency must have an electric capacity of 10 GWe to support as many hydrogen-powered hybrid cars as one modern 200,000 bbl/day-capacity oil refinery could support in gasoline-powered hybrid cars. A 10 GWe fusion electric plant capital cost is limited to 12.5 B$ to produce electricity at 2.3 cents/kWehr, and hydrogen production by electrolysis at 8 $/GJ, for equal consumer fuel cost per passenger mile as in the oil-gasoline-hybrid pathway

  14. The Influence of Hydrogen Gas on the Measures of Efficiency of Diesel Internal Combustion Engine

    Directory of Open Access Journals (Sweden)

    Jurgis Latakas

    2014-12-01

    Full Text Available In this research paper energy and ecological parameters of diesel engine which works under addition of hydrogen (10, 20, 30 l/ min are presented. A survey of research literature has shown that addition of hydrogen gases improve diesel combustion; increase indicated pressure; decrease concentration of carbon dioxide (CO2, hydrocarbons (HC, particles; decrease fuel consumptions. Results of the experiment revealed that hydrogen gas additive decreased pressure in cylinder in kinetic combustion phase. Concentration of CO2 and nitrous oxides (NOx decreased not significantly, HC – increased. Concentration of particles in engine exhaust gases significantly decreased. In case when hydrogen gas as additive was supplied, the fuel consumptions decreased a little. Using AVL BOOST software combustion process analysis was made. It was determined that in order to optimize engine work process under hydrogen additive usage, it is necessary to adjust diesel injection angle.

  15. Improving long-term operation of power sources in off-grid hybrid systems based on renewable energy, hydrogen and battery

    Science.gov (United States)

    García, Pablo; Torreglosa, Juan P.; Fernández, Luis M.; Jurado, Francisco

    2014-11-01

    This paper presents two novel hourly energy supervisory controls (ESC) for improving long-term operation of off-grid hybrid systems (HS) integrating renewable energy sources (wind turbine and photovoltaic solar panels), hydrogen system (fuel cell, hydrogen tank and electrolyzer) and battery. The first ESC tries to improve the power supplied by the HS and the power stored in the battery and/or in the hydrogen tank, whereas the second one tries to minimize the number of needed elements (batteries, fuel cells and electrolyzers) throughout the expected life of the HS (25 years). Moreover, in both ESC, the battery state-of-charge (SOC) and the hydrogen tank level are controlled and maintained between optimum operating margins. Finally, a comparative study between the controls is carried out by models of the commercially available components used in the HS under study in this work. These ESC are also compared with a third ESC, already published by the authors, and based on reducing the utilization costs of the energy storage devices. The comparative study proves the right performance of the ESC and their differences.

  16. Enhanced hydrogen evolution rates at high pH with a colloidal cadmium sulphide–platinum hybrid system

    International Nuclear Information System (INIS)

    Schneider, Julian; Vaneski, Aleksandar; Susha, Andrei S.; Rogach, Andrey L.; Pesch, Georg R.; Yang Teoh, Wey

    2014-01-01

    We demonstrate enhanced hydrogen generation rates at high pH using colloidal cadmium sulphide nanorods decorated with Pt nanoparticles. We introduce a simplified procedure for the decoration and subsequent hydrogen generation, reducing both the number of working steps and the materials costs. Different Pt precursor concentrations were tested to reveal the optimal conditions for the efficient hydrogen evolution. A sharp increase in hydrogen evolution rates was measured at pH 13 and above, a condition at which the surface charge transfer was efficiently mediated by the formation of hydroxyl radicals and further consumption by the sacrificial triethanolamine hole scavenger

  17. Enhanced hydrogen evolution rates at high pH with a colloidal cadmium sulphide–platinum hybrid system

    Energy Technology Data Exchange (ETDEWEB)

    Schneider, Julian; Vaneski, Aleksandar; Susha, Andrei S.; Rogach, Andrey L., E-mail: andrey.rogach@cityu.edu.hk [Department of Physics and Materials Science and Centre for Functional Photonics (CFP), City University of Hong Kong, 83 Tat Chee Avenue, Kowloon (Hong Kong); Pesch, Georg R.; Yang Teoh, Wey [Clean Energy and Nanotechnology (CLEAN) Laboratory, School of Energy and Environment, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon (Hong Kong)

    2014-12-01

    We demonstrate enhanced hydrogen generation rates at high pH using colloidal cadmium sulphide nanorods decorated with Pt nanoparticles. We introduce a simplified procedure for the decoration and subsequent hydrogen generation, reducing both the number of working steps and the materials costs. Different Pt precursor concentrations were tested to reveal the optimal conditions for the efficient hydrogen evolution. A sharp increase in hydrogen evolution rates was measured at pH 13 and above, a condition at which the surface charge transfer was efficiently mediated by the formation of hydroxyl radicals and further consumption by the sacrificial triethanolamine hole scavenger.

  18. IHCE '95. International Hydrogen and Clean Energy Symposium '95. (February 6-8, 1995)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-02-06

    This is a collection of speeches and lectures delivered at the above-named symposium that took place in Tokyo. Three speakers from Japan, Germany, and the U.S. made remarks about the future energy systems and the role of hydrogen; the hydrogen energy development status and plans in Europe; and the role of hydrogen in meeting southern California's air quality goals, respectively. Technical lectures numbering 22 in total included the photocatalytic reactions - water splitting and environmental applications; realization and operation of SWB's (Solar-Wasserstof-Bayern GmBH) development assembling major industrial-scale components of solar hydrogen technology; hydrogen production by UT-3 (University of Tokyo-3) thermochemical water decomposition cycle; energy and environmental technology in Japan - the New Sunshine Program; and research and development plans for WE-NET (World Energy Network). In the poster session, there were 45 exhibitions, which included development on solid polymer electrolyte water electrolysis in Mitsubishi Heavy Industries, Ltd.; development of environmentally friendly technology for the production of hydrogen; and recent progress of hydrogen storage and transportation technologies in North America. (NEDO)

  19. IHCE '95. International Hydrogen and Clean Energy Symposium '95. (February 6-8, 1995)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-02-06

    This is a collection of speeches and lectures delivered at the above-named symposium that took place in Tokyo. Three speakers from Japan, Germany, and the U.S. made remarks about the future energy systems and the role of hydrogen; the hydrogen energy development status and plans in Europe; and the role of hydrogen in meeting southern California's air quality goals, respectively. Technical lectures numbering 22 in total included the photocatalytic reactions - water splitting and environmental applications; realization and operation of SWB's (Solar-Wasserstof-Bayern GmBH) development assembling major industrial-scale components of solar hydrogen technology; hydrogen production by UT-3 (University of Tokyo-3) thermochemical water decomposition cycle; energy and environmental technology in Japan - the New Sunshine Program; and research and development plans for WE-NET (World Energy Network). In the poster session, there were 45 exhibitions, which included development on solid polymer electrolyte water electrolysis in Mitsubishi Heavy Industries, Ltd.; development of environmentally friendly technology for the production of hydrogen; and recent progress of hydrogen storage and transportation technologies in North America. (NEDO)

  20. Negative-ion production on carbon materials in hydrogen plasma : influence of the carbon hybridization state and the hydrogen content on H- yield

    NARCIS (Netherlands)

    Ahmad, A.; Pardanaud, C.; Carrère, M.; Layet, J.M.; Gicquel, A.; Kumar, P.; Eon, D.; Jaoul, C.; Engeln, R.A.H.; Cartry, G.

    2014-01-01

    Highly oriented polycrystalline graphite (HOPG), boron-doped diamond (BDD), nanocrystalline diamond, ultra-nanocrystalline diamond and diamond-like carbon surfaces are exposed to low-pressure hydrogen plasma in a 13.56 MHz plasma reactor. Relative yields of surface-produced H- ions due to

  1. Electric and hybrid electric vehicles. Report of the International Evaluation Committee. June 96

    Energy Technology Data Exchange (ETDEWEB)

    Kahlen, H [Univ. Kaiserslautern (Germany); Maggetto, G [Vrije Univ., Brussel (Belgium); Scrosati, B [Univ. di Roma (Italy); Srinivasan, S [Texas A and M Univ., College Station (United States)

    1996-11-01

    As requested by NUTEK our task was to evaluate the results and progress achieved in the electric and hybrid electric vehicles programme. This is a multidisciplinary research programme involving 12 projects at four universities and is planned to be extended over two three-year periods, i.e. 1993-1996 and 1997-1999 at a level of 8 MSKR (about USD 1,2M) per year. The programme has been launched to stimulate the development of electric vehicle technology in Sweden and is supporting projects to optimize the material processes, improve battery and engine components and promote of their production by the Swedish industry. In addition, the programme is directed to: 1. improve the knowledge and experience in the field at the academic level; 2. to support long time research on the subject and, 3. promote collaboration nationally and internationally. Our first comment is that the latter aspect appears to be satisfactorily accomplished. Most of the groups we have visited demonstrate an acquired experience in the field and presented their results with competence and enthusiasm. In many cases, we found valid interactions on ongoing projects in Swedish universities and established collaborations with high rank international groups. The programme has provided the material and the motivation for high-quality thesis work and, consequently, the formation of a class of well prepared and professionally competent students. Since electric vehicle technology is fast developing and is expected to have important fall-outs not only in the car industry but also in battery and electric engine manufacturing, the training of competent scientists and engineers in the field is of paramount relevance for Sweden where these types of industries are active and spread out. Therefore, we believe that as far as educational promotion is concerned, the funds distribution was worthwhile in all the projects which we evaluated

  2. Potential improvement to a citric wastewater treatment plant using bio-hydrogen and a hybrid energy system

    Science.gov (United States)

    Zhi, Xiaohua; Yang, Haijun; Berthold, Sascha; Doetsch, Christian; Shen, Jianquan

    Treatment of highly concentrated organic wastewater is characterized as cost-consuming. The conventional technology uses the anaerobic-anoxic-oxic process (A 2/O), which does not produce hydrogen. There is potential for energy saving using hydrogen utilization associated with wastewater treatment because hydrogen can be produced from organic wastewater using anaerobic fermentation. A 50 m 3 pilot bio-reactor for hydrogen production was constructed in Shandong Province, China in 2006 but to date the hydrogen produced has not been utilized. In this work, a technical-economic model based on hydrogen utilization is presented and analyzed to estimate the potential improvement to a citric wastewater plant. The model assesses the size, capital cost, annual cost, system efficiency and electricity cost under different configurations. In a stand-alone situation, the power production from hydrogen is not sufficient for the required load, thus a photovoltaic array (PV) is employed as the power supply. The simulated results show that the combination of solar and bio-hydrogen has a much higher cost compared with the A 2/O process. When the grid is connected, the system cost achieved is 0.238 US t -1 wastewater, which is lower than 0.257 US t -1 by the A 2/O process. The results reveal that a simulated improvement by using bio-hydrogen and a FC system is effective and feasible for the citric wastewater plant, even when compared to the current cost of the A 2/O process. In addition, lead acid and vanadium flow batteries were compared for energy storage service. The results show that a vanadium battery has lower cost and higher efficiency due to its long lifespan and energy efficiency. Additionally, the cost distribution of components shows that the PV dominates the cost in the stand-alone situation, while the bio-reactor is the main cost component in the parallel grid.

  3. THEN: COE-INES international workshop on 'toward hydrogen economy; what nuclear can contribute and how'. Proposal and presentations

    International Nuclear Information System (INIS)

    2005-01-01

    The workshop of the title was held on topics; hydrogen system, nuclear and non-nuclear hydrogen production, hydrogen storage and transportation, fuel-cells, hydrogen energy management, hydrogen economy and all subjects related on hydrogen system, consisted of 4 panels by 15 panelists and a comprehensive discussion session. (J.P.N.)

  4. Dynamic effects on the acceptance of hydrogen technologies - an international comparison

    International Nuclear Information System (INIS)

    Heinz, Boris; Erdmann, Georg

    2008-01-01

    Social acceptance plays an important role for the future hydrogen economy and a broad market launch of hydrogen technologies. Neglecting the aspect of public acceptance and attitude may become a serious obstacle for the establishment of a mass market infrastructure. With a standardized questionnaire and a standardized procedure, personal interviews were conducted with at least 300 persons in Amsterdam, Barcelona, Berlin, Hamburg, London, Luxembourg, Madrid and Reykjavik, in total with 3352 persons. Thus the dynamics of the public attitude toward hydrogen were analyzed, whereby the possibility of setbacks and accidents was taken into consideration. Whereas 68% of the interviewed persons would be supportive of the aforementioned technologies, an amount of 31% was determined to be volatile. An amount of 77% stated that they would use a hydrogen bus instead of a conventional one if they could choose, but an amount of 21% was indifferent. It will be shown how these amounts can affect the balance of acceptance and how stable the acceptance of hydrogen technologies can be considered in the evaluated six countries. (author)

  5. A highly sensitive hydrogen sensor with gas selectivity using a PMMA membrane-coated Pd nanoparticle/single-layer graphene hybrid.

    Science.gov (United States)

    Hong, Juree; Lee, Sanggeun; Seo, Jungmok; Pyo, Soonjae; Kim, Jongbaeg; Lee, Taeyoon

    2015-02-18

    A polymer membrane-coated palladium (Pd) nanoparticle (NP)/single-layer graphene (SLG) hybrid sensor was fabricated for highly sensitive hydrogen gas (H2) sensing with gas selectivity. Pd NPs were deposited on SLG via the galvanic displacement reaction between graphene-buffered copper (Cu) and Pd ion. During the galvanic displacement reaction, graphene was used as a buffer layer, which transports electrons from Cu for Pd to nucleate on the SLG surface. The deposited Pd NPs on the SLG surface were well-distributed with high uniformity and low defects. The Pd NP/SLG hybrid was then coated with polymer membrane layer for the selective filtration of H2. Because of the selective H2 filtration effect of the polymer membrane layer, the sensor had no responses to methane, carbon monoxide, or nitrogen dioxide gas. On the contrary, the PMMA/Pd NP/SLG hybrid sensor exhibited a good response to exposure to 2% H2: on average, 66.37% response within 1.81 min and recovery within 5.52 min. In addition, reliable and repeatable sensing behaviors were obtained when the sensor was exposed to different H2 concentrations ranging from 0.025 to 2%.

  6. PtNi Alloy Cocatalyst Modification of Eosin Y-Sensitized g-C3N4/GO Hybrid for Efficient Visible-Light Photocatalytic Hydrogen Evolution

    Science.gov (United States)

    Wang, Peng; Zong, Lanlan; Guan, Zhongjie; Li, Qiuye; Yang, Jianjun

    2018-02-01

    An economic and effective Pt-based alloy cocatalyst has attracted considerable attention due to their excellent catalytic activity and reducing Pt usage. In this study, PtNi alloy cocatalyst was successfully decorated on the g-C3N4/GO hybrid photocatalyst via a facile chemical reduction method. The Eosin Y-sensitized g-C3N4/PtNi/GO-0.5% composite photocatalyst yields about 1.54 and 1178 times higher hydrogen evolution rate than the Eosin Y-sensitized g-C3N4/Pt/GO-0.5% and g-C3N4/Ni/GO-0.5% samples, respectively. Mechanism of enhanced performance for the g-C3N4/PtNi/GO composite was also investigated by different characterization, such as photoluminescence, transient photocurrent response, and TEM. These results indicated that enhanced charge separation efficiency and more reactive sites are responsible for the improved hydrogen evolution performance due to the positive synergetic effect between Pt and Ni. This study suggests that PtNi alloy can be used as an economic and effective cocatalyst for hydrogen evolution reaction. [Figure not available: see fulltext.

  7. Preparation, characterization and evaluation of proton-conducting hybrid membranes based on sulfonated hydrogenated styrene-butadiene and polysiloxanes for fuel cell applications

    Energy Technology Data Exchange (ETDEWEB)

    Monroy-Barreto, M.; Aguilar, J.C.; Rodriguez de San Miguel, E.; de Gyves, J. [Departamento de Quimica Analitica, Facultad de Quimica, UNAM, Ciudad Universitaria, 04360 Mexico, D.F. (Mexico); Acosta, J.L.; del Rio, C.; Ojeda, M.C. [Instituto de Ciencia y Tecnologia de Polimeros (CSIC), c/Juan de la Cierva 3, 28006 Madrid (Spain); Munoz, M. [Departament de Quimica Analitica, Facultat de Ciencies, U.A.B., Bellaterra 08193 Barcelona (Spain)

    2010-12-15

    This paper describes the preparation of proton-conducting hybrid membranes (HMs) obtained by a solvent casting procedure using a solution containing sulfonated hydrogenated styrene-butadiene (HSBS-S) and an inorganic-organic mixture (polysiloxanes) previously prepared by a sol-gel route. HSBS-S copolymers with different sulfonation degrees were obtained and characterized by means of elemental analysis (EA), chemical titration and electrochemical impedance spectroscopy (EIS). HSBS-S with the best properties in terms of proton conductivity and solubility for the casting procedure was selected to prepare the HMs. The solvent casting procedure permitted the two phases to be homogeneously distributed while maintaining a relatively high proton conductivity in the membrane. HMs with different blend ratios were characterized using structural (Fourier transform infrared-attenuated total reflectance (FTIR-ATR), dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC)), electrical (EIS), physicochemical (water uptake, ion-exchange capacity) and thermal (TGA-MS) methods. Finally, the optimized HSBS-S membrane and HMs were tested in hydrogen single fuel cells to obtain the polarization and power curves at different cell temperatures and gas pressures. Results indicate that HMs show a considerable improvement in performance compared to the optimized HSBS-S membrane denoting the benefit of incorporating the inorganic-organic network in the hydrogenated styrene-butadiene matrix. A Nafion membrane was used as reference material throughout this work. (author)

  8. Metal (Ag/Ti)-Containing Hydrogenated Amorphous Carbon Nanocomposite Films with Enhanced Nanoscratch Resistance: Hybrid PECVD/PVD System and Microstructural Characteristics.

    Science.gov (United States)

    Constantinou, Marios; Nikolaou, Petros; Koutsokeras, Loukas; Avgeropoulos, Apostolos; Moschovas, Dimitrios; Varotsis, Constantinos; Patsalas, Panos; Kelires, Pantelis; Constantinides, Georgios

    2018-03-30

    This study aimed to develop hydrogenated amorphous carbon thin films with embedded metallic nanoparticles (a-C:H:Me) of controlled size and concentration. Towards this end, a novel hybrid deposition system is presented that uses a combination of Plasma Enhanced Chemical Vapor Deposition (PECVD) and Physical Vapor Deposition (PVD) technologies. The a-C:H matrix was deposited through the acceleration of carbon ions generated through a radio-frequency (RF) plasma source by cracking methane, whereas metallic nanoparticles were generated and deposited using terminated gas condensation (TGC) technology. The resulting material was a hydrogenated amorphous carbon film with controlled physical properties and evenly dispersed metallic nanoparticles (here Ag or Ti). The physical, chemical, morphological and mechanical characteristics of the films were investigated through X-ray reflectivity (XRR), Raman spectroscopy, Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), Transmission Electron Microscopy (TEM) and nanoscratch testing. The resulting amorphous carbon metal nanocomposite films (a-C:H:Ag and a-C:H:Ti) exhibited enhanced nanoscratch resistance (up to +50%) and low values of friction coefficient (<0.05), properties desirable for protective coatings and/or solid lubricant applications. The ability to form nanocomposite structures with tunable coating performance by potentially controlling the carbon bonding, hydrogen content, and the type/size/percent of metallic nanoparticles opens new avenues for a broad range of applications in which mechanical, physical, biological and/or combinatorial properties are required.

  9. Metal (Ag/Ti-Containing Hydrogenated Amorphous Carbon Nanocomposite Films with Enhanced Nanoscratch Resistance: Hybrid PECVD/PVD System and Microstructural Characteristics

    Directory of Open Access Journals (Sweden)

    Marios Constantinou

    2018-03-01

    Full Text Available This study aimed to develop hydrogenated amorphous carbon thin films with embedded metallic nanoparticles (a–C:H:Me of controlled size and concentration. Towards this end, a novel hybrid deposition system is presented that uses a combination of Plasma Enhanced Chemical Vapor Deposition (PECVD and Physical Vapor Deposition (PVD technologies. The a–C:H matrix was deposited through the acceleration of carbon ions generated through a radio-frequency (RF plasma source by cracking methane, whereas metallic nanoparticles were generated and deposited using terminated gas condensation (TGC technology. The resulting material was a hydrogenated amorphous carbon film with controlled physical properties and evenly dispersed metallic nanoparticles (here Ag or Ti. The physical, chemical, morphological and mechanical characteristics of the films were investigated through X-ray reflectivity (XRR, Raman spectroscopy, Scanning Electron Microscopy (SEM, Atomic Force Microscopy (AFM, Transmission Electron Microscopy (TEM and nanoscratch testing. The resulting amorphous carbon metal nanocomposite films (a–C:H:Ag and a–C:H:Ti exhibited enhanced nanoscratch resistance (up to +50% and low values of friction coefficient (<0.05, properties desirable for protective coatings and/or solid lubricant applications. The ability to form nanocomposite structures with tunable coating performance by potentially controlling the carbon bonding, hydrogen content, and the type/size/percent of metallic nanoparticles opens new avenues for a broad range of applications in which mechanical, physical, biological and/or combinatorial properties are required.

  10. Hydrogen, fuel of the future?

    International Nuclear Information System (INIS)

    Bello, B.

    2008-01-01

    The European project HyWays has drawn out the road map of hydrogen energy development in Europe. The impact of this new energy vector on the security of energy supplies, on the abatement of greenhouse gases and on the economy should be important in the future. This article summarizes the main conclusions of the HyWays study: CO 2 emissions, hydrogen production mix, oil saving abatement, economic analysis, contribution of hydrogen to the development of renewable energies, hydrogen uses, development of regional demand and of users' centers, transport and distribution. The proposals of the HyWays consortium are as follows: implementing a strong public/private European partnership to reach the goals, favoring market penetration, developing training, tax exemption on hydrogen in the initial phase for a partial compensation of the cost difference, inciting public fleets to purchase hydrogen-fueled vehicles, using synergies with other technologies (vehicles with internal combustion engines, hybrid vehicles, biofuels of second generation..), harmonizing hydrogen national regulations at the European scale. (J.S.)

  11. Hydrogen in air transportation. Proceedings of the international symposium, Stuttgart, West Germany, September 11-14, 1979, and supplement

    Energy Technology Data Exchange (ETDEWEB)

    1979-01-01

    The Symposium emphasizes future oil prospects, experience with gaseous hydrogen pipeline systems, hydrogen fueled turbofan engines, liquid hydrogen airport requirements, and a liquid hydrogen experimental airline project. Papers were given on the impacts of fossil fuel on the environment, alternate fuels for aircraft, production of hydrogen by coal gasification, production of hydrogen from solar energy and water, handling of hydrogen, liquid hydrogen fueled aircraft, turbofan engine and fuel system for liquid hydrogen use, liquid hydrogen engines, and design concept for LH2 airport facilities.

  12. Hybrid war”: рolitical discourse and the international practice

    OpenAIRE

    P. A. Tsygankov

    2015-01-01

    The paper analyzes the content of the term “hybrid war” and its difference from other types of modern military conflicts; stresses that combination of military and non-military methods became a priority means in conducting the U.S. foreign policy; argues that the term “hybrid war” is exploited as a tool of anti-Russian rhetoric.

  13. OPTIMIZATION OF INTERNAL HEAT EXCHANGERS FOR HYDROGEN STORAGE TANKS UTILIZING METAL HYDRIDES

    Energy Technology Data Exchange (ETDEWEB)

    Garrison, S.; Tamburello, D.; Hardy, B.; Anton, D.; Gorbounov, M.; Cognale, C.; van Hassel, B.; Mosher, D.

    2011-07-14

    Two detailed, unit-cell models, a transverse fin design and a longitudinal fin design, of a combined hydride bed and heat exchanger are developed in COMSOL{reg_sign} Multiphysics incorporating and accounting for heat transfer and reaction kinetic limitations. MatLab{reg_sign} scripts for autonomous model generation are developed and incorporated into (1) a grid-based and (2) a systematic optimization routine based on the Nelder-Mead downhill simplex method to determine the geometrical parameters that lead to the optimal structure for each fin design that maximizes the hydrogen stored within the hydride. The optimal designs for both the transverse and longitudinal fin designs point toward closely-spaced, small cooling fluid tubes. Under the hydrogen feed conditions studied (50 bar), a 25 times improvement or better in the hydrogen storage kinetics will be required to simultaneously meet the Department of Energy technical targets for gravimetric capacity and fill time. These models and methodology can be rapidly applied to other hydrogen storage materials, such as other metal hydrides or to cryoadsorbents, in future work.

  14. Proceedings of a Canadian Hydrogen Association workshop in support of the transition to the hydrogen age : Greening the fleet : the status of hydrogen-powered vehicles for fleet applications

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    The Canadian Hydrogen Association (CHA) endorses hydrogen as an energy carrier and promotes the development of a supporting hydrogen infrastructure. It promotes the research, development and commercialization of innovative ways to accelerate the application of hydrogen technologies to reduce greenhouse gas emissions. The presentations at this conference described new technologies and the companies that are developing hydrogen-powered vehicles, including hybrid-electric powered vehicles for fleet application. Some international activities were also covered, including lessons learned from the California experience and European fuel cell fleets. The benefits of fuel cell hybrids were highlighted along with methods to overcome the barriers to the introduction of new vehicle fuels. A review of current and future hydrogen supply infrastructure systems was also provided. The conference featured 14 presentations, of which 2 have been catalogued separately for inclusion in this database. refs., tabs., figs.

  15. Evaluation of marginal and internal adaptation of hybrid and nanoceramic systems with microcomputed tomography: An in vitro study.

    Science.gov (United States)

    Yildirim, Güler; Uzun, Ismail H; Keles, Ali

    2017-08-01

    The accuracy of recently introduced chairside computer-aided design and computer-aided manufacturing (CAD-CAM) blocks is not well established, and marginal integrity and internal adaptation are not known. The purpose of this in vitro study was to evaluate the marginal and internal adaptation of hybrid and nanoceramics using microcomputed tomography (μ-CT). The marginal and internal adaptation of 3 polymer-infiltrated ceramic-network (PICN) materials (Vita Enamic [VE]; Lava Ultimate [LU]; Vita Suprinity [VS]) were compared with lithium disilicate (IPS e.max.CAD, IPS). Ninety-six specimens (48 dies and 48 crowns) were prepared (n=12 each group) using a chairside CAD-CAM system. The restorations were scanned with μ-CT, with 160 measurements made for each crown, and used in 2-dimensional (2D) analysis. The marginal adaptation of marginal discrepancy (MD), absolute marginal discrepancy (AMD), internal adaptation of shoulder area (SA), axial space (AS), and occlusal space (OS) were compared using appropriate statistical analysis methods (α=.05). Cement volumes were compared using 3D analysis. The IPS blocks showed higher MD (130 μm), AMD (156 μm), SA (111 μm) (P.05). IPS had the largest cement space at 18 mm 3 (Pmarginal and internal adaptation values were within a clinically acceptable range for all 3 hybrids and nanoceramics tested. Copyright © 2016 Editorial Council for the Journal of Prosthetic Dentistry. Published by Elsevier Inc. All rights reserved.

  16. Fast ion stabilization of the ion temperature gradient driven modes in the Joint European Torus hybrid-scenario plasmas: a trigger mechanism for internal transport barrier formation

    Energy Technology Data Exchange (ETDEWEB)

    Romanelli, M; Zocco, A [Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon, Oxon, OX14 3DB (United Kingdom); Crisanti, F, E-mail: Michele.Romanelli@ccfe.ac.u [Associazione Euratom-ENEA sulla Fusione, C.R. Frascati, Frascati (Italy)

    2010-04-15

    Understanding and modelling turbulent transport in thermonuclear fusion plasmas are crucial for designing and optimizing the operational scenarios of future fusion reactors. In this context, plasmas exhibiting state transitions, such as the formation of an internal transport barrier (ITB), are particularly interesting since they can shed light on transport physics and offer the opportunity to test different turbulence suppression models. In this paper, we focus on the modelling of ITB formation in the Joint European Torus (JET) [1] hybrid-scenario plasmas, where, due to the monotonic safety factor profile, magnetic shear stabilization cannot be invoked to explain the transition. The turbulence suppression mechanism investigated here relies on the increase in the plasma pressure gradient in the presence of a minority of energetic ions. Microstability analysis of the ion temperature gradient driven modes (ITG) in the presence of a fast-hydrogen minority shows that energetic ions accelerated by the ion cyclotron resonance heating (ICRH) system (hydrogen, n{sub H,fast}/n{sub D,thermal} up to 10%, T{sub H,fast}/T{sub D,thermal} up to 30) can increase the pressure gradient enough to stabilize the ITG modes driven by the gradient of the thermal ions (deuterium). Numerical analysis shows that, by increasing the temperature of the energetic ions, electrostatic ITG modes are gradually replaced by nearly electrostatic modes with tearing parity at progressively longer wavelengths. The growth rate of the microtearing modes is found to be lower than that of the ITG modes and comparable to the local E x B-velocity shearing rate. The above mechanism is proposed as a possible trigger for the formation of ITBs in this type of discharges.

  17. Mitigation of climate change via a copper-chlorine hybrid thermochemical water splitting cycle for hydrogen production from nuclear energy

    International Nuclear Information System (INIS)

    Orhan, M.F.; Dincer, I.; Rosen, M.A.

    2009-01-01

    Concerns regarding climate change have motivated research on clean energy resources. While many energy resources have limitations, nuclear energy has the potential to supply a significant share of energy supply without contributing to climate change. Nuclear energy has been used mainly for electric power generation, but hydrogen production via thermochemical water decomposition provides another option for the utilization of nuclear thermal energy. This paper describes nuclear-based hydrogen production technologies and discusses the role of the Cu-Cl cycle for thermochemical water decomposition, potentially driven in part by waste heat from a nuclear generating station, in reducing greenhouse gas emissions. (author)

  18. Hydrogen millennium

    International Nuclear Information System (INIS)

    Bose, T.K.; Benard, P.

    2000-05-01

    The 10th Canadian Hydrogen Conference was held at the Hilton Hotel in Quebec City from May 28 to May 31, 2000. The topics discussed included current drivers for the hydrogen economy, the international response to these drivers, new initiatives, sustainable as well as biological and hydrocarbon-derived production of hydrogen, defense applications of fuel cells, hydrogen storage on metal hydrides and carbon nanostructures, stationary power and remote application, micro-fuel cells and portable applications, marketing aspects, fuel cell modeling, materials, safety, fuel cell vehicles and residential applications. (author)

  19. Fuel cell systems and high-integrated combinations of internal combustion engines and generators for hybrid drives; Brennstoffzellensysteme und hoch integrierte Verbrennungsmotor/Generator-Kombinationen fueHybridantriebe

    Energy Technology Data Exchange (ETDEWEB)

    Treffinger, P.; Graef, M. [DLR Deutsches Zentrum fuer Luft- und Raumfahrt e.V., Stuttgart (Germany). Inst. fuer Fahrzeugkonzepte

    2005-07-01

    So called fuel cell hybrid vehicles can be regarded in general as electrical driven vehicles, equipped with a fuel cell as current source, which is connected in parallel with an electrical energy storage. This power train configuration gives very high flexibility realizing the package, because the primary energy converter is not directly connected with the torque converter for propulsion. The studies 'Hy-Wire' and 'Sequel' of GM are adopting this approach as well as the modular vehicle concept of DLR Institute of Vehicle Concepts. The overall efficiency of the above described power train concept depends strongly on the efficiency of the current source. The efficiency potential of Polymer Electrolyte Fuel Cell (PEFC) systems has been successfully demonstrated by several car manufacturers. However, some technical issues are still to be solved, e.g. operation at low temperatures and power densities of the complete system. There is also no satisfying solution for the on-board storage of hydrogen. A current source based on a free piston linear generator is an alternative to the PEFC system. The free piston linear generator can be realized in several configurations. The approach of DLR, which is explained in this paper, enables the stroke to be adjusted according to the actual load. This especially improves internal efficiency significantly in partial loading conditions and also reduces heat losses. On the base of detailed simulation, underlined by first experimental studies, efficiencies above 35% in a broad operation range are estimated. (orig.)

  20. Hybrid war”: рolitical discourse and the international practice

    Directory of Open Access Journals (Sweden)

    P. A. Tsygankov

    2015-01-01

    Full Text Available The paper analyzes the content of the term “hybrid war” and its difference from other types of modern military conflicts; stresses that combination of military and non-military methods became a priority means in conducting the U.S. foreign policy; argues that the term “hybrid war” is exploited as a tool of anti-Russian rhetoric.

  1. Optimization of operating parameters in a hybrid wind–hydrogen system using energy and exergy analysis: Modeling and case study

    International Nuclear Information System (INIS)

    Fakehi, Amir Hossein; Ahmadi, Somayeh; Mirghaed, Mohammad Rezaie

    2015-01-01

    Highlights: • The exergy analysis of a hybrid system of a wind turbine and PEM electrolyzer/fuel-cell has been performed. • Effects of various operating parameters on the exergy efficiency have been investigated. • The exergy and energy efficiency in each of hybrid system’s components have been compared. - Abstract: In this study, hybrid renewable energy system based on wind/electrolyzer/PEM fuel cell are conceptually modeled, and also, exergy and energy analysis are performed. The energy and exergy flows are investigated by the proposed model for Khaf region-Iran with high average wind speed and monsoon. Exergy and energy analysis framework is made based on thermodynamic, electro-chemical and mechanical model of the different component of hybrid system. Also, the effects of various operating parameters in exergy efficiency are calculated. The results show an optimum wind speed where the exergy efficiency and power coefficient is at maximum level, and also, when the ambient temperature start to be increased in wind turbine, the efficiencies decrease by a great deal for constant wind speeds. Also, the optimum temperature is calculated by exergy analysis in electrolyzer and fuel cell as 353 and the exergy efficiency of electrolyzer decreases by increasing the membrane thickness. Furthermore, pressure changes affect exergy and energy efficiency in PEM fuel cell. Finally, the electrolyzer and fuel cell efficiencies are calculated as 68.5% and 47% respectively.

  2. Coupling of copper-chloride hybrid thermochemical water splitting cycle with a desalination plant for hydrogen production from nuclear energy

    International Nuclear Information System (INIS)

    Orhan, Mehmet F.; Dincer, Ibrahim; Naterer, Greg F.; Rosen, Marc A.

    2010-01-01

    Energy and environmental concerns have motivated research on clean energy resources. Nuclear energy has the potential to provide a significant share of energy supply without contributing to environmental emissions and climate change. Nuclear energy has been used mainly for electric power generation, but hydrogen production via thermochemical water decomposition provides another pathway for the utilization of nuclear thermal energy. One option for nuclear-based hydrogen production via thermochemical water decomposition uses a copper-chloride (Cu-Cl) cycle. Another societal concern relates to supplies of fresh water. Thus, to avoid causing one problem while solving another, hydrogen could be produced from seawater rather than limited fresh water sources. In this study we analyze a coupling of the Cu-Cl cycle with a desalination plant for hydrogen production from nuclear energy and seawater. Desalination technologies are reviewed comprehensively to determine the most appropriate option for the Cu-Cl cycle and a thermodynamic analysis and several parametric studies of this coupled system are presented for various configurations. (author)

  3. Hydrogen Delivery Technical Team Roadmap

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-06-01

    The mission of the Hydrogen Delivery Technical Team (HDTT) is to enable the development of hydrogen delivery technologies, which will allow for fuel cell competitiveness with gasoline and hybrid technologies by achieving an as-produced, delivered, and dispensed hydrogen cost of $2-$4 per gallon of gasoline equivalent of hydrogen.

  4. Tracer-based laser-induced fluorescence measurement technique for quantitative fuel/air-ratio measurements in a hydrogen internal combustion engine.

    Science.gov (United States)

    Blotevogel, Thomas; Hartmann, Matthias; Rottengruber, Hermann; Leipertz, Alfred

    2008-12-10

    A measurement technique for the quantitative investigation of mixture formation processes in hydrogen internal combustion engines (ICEs) has been developed using tracer-based laser-induced fluorescence (TLIF). This technique can be employed to fired and motored engine operation. The quantitative TLIF fuel/air-ratio results have been verified by means of linear Raman scattering measurements. Exemplary results of the simultaneous investigation of mixture formation and combustion obtained at an optical accessible hydrogen ICE are shown.

  5. Greenhouse gas implications of using coal for transportation: Life cycle assessment of coal-to-liquids, plug-in hybrids, and hydrogen pathways

    International Nuclear Information System (INIS)

    Jaramillo, Paulina; Samaras, Constantine; Wakeley, Heather; Meisterling, Kyle

    2009-01-01

    Using coal to produce transportation fuels could improve the energy security of the United States by replacing some of the demand for imported petroleum. Because of concerns regarding climate change and the high greenhouse gas (GHG) emissions associated with conventional coal use, policies to encourage pathways that utilize coal for transportation should seek to reduce GHGs compared to petroleum fuels. This paper compares the GHG emissions of coal-to-liquid (CTL) fuels to the emissions of plug-in hybrid electric vehicles (PHEV) powered with coal-based electricity, and to the emissions of a fuel cell vehicle (FCV) that uses coal-based hydrogen. A life cycle approach is used to account for fuel cycle and use-phase emissions, as well as vehicle cycle and battery manufacturing emissions. This analysis allows policymakers to better identify benefits or disadvantages of an energy future that includes coal as a transportation fuel. We find that PHEVs could reduce vehicle life cycle GHG emissions by up to about one-half when coal with carbon capture and sequestration is used to generate the electricity used by the vehicles. On the other hand, CTL fuels and coal-based hydrogen would likely lead to significantly increased emissions compared to PHEVs and conventional vehicles using petroleum-based fuels.

  6. Characterization of diverse internal binding specificities of PDZ domains by yeast two-hybrid screening of a special peptide library.

    Science.gov (United States)

    Mu, Yi; Cai, Pengfei; Hu, Siqi; Ma, Sucan; Gao, Youhe

    2014-01-01

    Protein-protein interactions (PPIs) are essential events to play important roles in a series of biological processes. There are probably more ways of PPIs than we currently realized. Structural and functional investigations of weak PPIs have lagged behind those of strong PPIs due to technical difficulties. Weak PPIs are often short-lived, which may result in more dynamic signals with important biological roles within and/or between cells. For example, the characteristics of PSD-95/Dlg/ZO-1 (PDZ) domain binding to internal sequences, which are primarily weak interactions, have not yet been systematically explored. In the present study, we constructed a nearly random octapeptide yeast two-hybrid library. A total of 24 PDZ domains were used as baits for screening the library. Fourteen of these domains were able to bind internal PDZ-domain binding motifs (PBMs), and PBMs screened for nine PDZ domains exhibited strong preferences. Among 11 PDZ domains that have not been reported their internal PBM binding ability, six were confirmed to bind internal PBMs. The first PDZ domain of LNX2, which has not been reported to bind C-terminal PBMs, was found to bind internal PBMs. These results suggest that the internal PBMs binding ability of PDZ domains may have been underestimated. The data provided diverse internal binding properties for several PDZ domains that may help identify their novel binding partners.

  7. Book of abstracts of the Fifth International School for young scientists and specialists Interaction of hydrogen isotopes with structural materials. IHISM-09 JUNIOR

    International Nuclear Information System (INIS)

    2009-01-01

    The book includes abstracts of presentations at the Fifth International School for young scientists and specialists Interaction of hydrogen isotopes with structural materials (IHISM-09 JUNIOR). Abstracts of lecture faculty and reports of young scientists and specialists covering the use of hydrogen isotopes in energetics, national economy and fundamental researches are given. Papers presented on the following topics: mechanical properties and structural transformations; kinetics and thermodynamics of interaction between hydrogen isotopes and solids including effects of radiogenic helium accumulation, hydrides and hydride transformations; equipment and research techniques

  8. Book of abstracts of the fourth international school for young scientists and specialists Interaction of hydrogen isotopes with structural materials (IHISM-08)

    International Nuclear Information System (INIS)

    2008-01-01

    The book includes abstracts of presentations at the 4th International School for young scientists and specialists Interaction of hydrogen isotopes with structural materials (IHISM-08). The lectures of lecturer and presentations of young scientists associated with the use of hydrogen isotopes in power engineering, national economy and basic research are considered. The presentations cover the following areas: kinetics and thermodynamics of interaction between hydrogen isotopes and solids including effects of radiogenic helium accumulation; hydrides and hydride transformations; structural transformations and mechanical properties; equipment and research techniques [ru

  9. Disturbing effect of free hydrogen on fuel combustion in internal combustion engines

    Science.gov (United States)

    Riedler, A

    1923-01-01

    Experiments with fuel mixtures of varying composition, have recently been conducted by the Motor Vehicle and Airplane Engine Testing Laboratories of the Royal Technical High School in Berlin and at Fort Hahneberg, as well as at numerous private engine works. The behavior of hydrogen during combustion in engines and its harmful effect under certain conditions, on the combustion in the engine cylinder are of general interest. Some of the results of these experiments are given here, in order to elucidate the main facts and explain much that is already a matter of experience with chauffeurs and pilots.

  10. Photoinduced electron transfer pathways in hydrogen-evolving reduced graphene oxide-boosted hybrid nano-bio catalyst.

    Science.gov (United States)

    Wang, Peng; Dimitrijevic, Nada M; Chang, Angela Y; Schaller, Richard D; Liu, Yuzi; Rajh, Tijana; Rozhkova, Elena A

    2014-08-26

    Photocatalytic production of clean hydrogen fuels using water and sunlight has attracted remarkable attention due to the increasing global energy demand. Natural and synthetic dyes can be utilized to sensitize semiconductors for solar energy transformation using visible light. In this study, reduced graphene oxide (rGO) and a membrane protein bacteriorhodopsin (bR) were employed as building modules to harness visible light by a Pt/TiO2 nanocatalyst. Introduction of the rGO boosts the nano-bio catalyst performance that results in hydrogen production rates of approximately 11.24 mmol of H2 (μmol protein)(-1) h(-1). Photoelectrochemical measurements show a 9-fold increase in photocurrent density when TiO2 electrodes were modified with rGO and bR. Electron paramagnetic resonance and transient absorption spectroscopy demonstrate an interfacial charge transfer from the photoexcited rGO to the semiconductor under visible light.

  11. A Novel Hybrid Reformer-Electrolyzer-Purifier (REP) for Distributed Production of Low-Cost, Low Greenhouse Gas Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Jahnke, Fred C. [FuelCell Energy, Inc., Danbury, CT (United States)

    2017-03-28

    FuelCell Energy with support from the Department of Energy’s Office of Energy Efficiency and Renewable Energy (EERE) has investigated the production of low-cost, low CO2 hydrogen using a molten carbonate fuel cell operating as an electrolyzer. We confirmed the feasibility of the technology by testing a large-scale short stack. Economic analysis was done with the assistance of the National Fuel Cell Center at the University of California, Irvine and we found the technology to be attractive, especially for distributed hydrogen. We explored the performance under various operating parameters and developed an accurate model for further analysis and development calculations. We achieved the expected results, meeting all program goals. We identified additional uses of the technology such as for CO2 capture, power storage, and power load leveling.

  12. Economic efficiency simulation for optimized management of pressure electrolysers in hybrid power plant systems. Prognosis and hydrogen production

    International Nuclear Information System (INIS)

    Krueger, P.; Ziems, C.; Tannert, D.; Voigt, A.; Fischer, U.; Krautz, H.J.

    2014-01-01

    As part of the research at the H 2 Research Centre of BTU Cottbus-Senftenberg feasibility studies are carried out on the use of electrolysis technology in conjunction with fluctuating wind power fed to a pressure electrolysis apparatus. The aim of the analysis is an economically optimized operating strategy of the system consisting of wind farm, alkaline pressure electrolyser, hydrogen storage and reconversion. For this purpose, an energy economics tool was created. [de

  13. COOPERATIVE MODE OF ELECTRIC MOTOR AND INTERNAL COMBUSTION ENGINE OPERATION IN THE CONVERSION HYBRID CAR

    Directory of Open Access Journals (Sweden)

    V. Dvadnenko

    2016-12-01

    Full Text Available In the given article the authors proposed a method to control the car, which is converted into a hybrid one. The electric motor and combustion engine operate alternately in the car. They proposed a device for implementing this method and a circuit design for the device in question. They also calculated the dynamics of the vehicle under the joint acceleration.

  14. Language and learning in the international university from English uniformity to diversity and hybridity

    CERN Document Server

    Preisler, Bent; Fabricius, Anne

    2011-01-01

    Based on a series of studies from universities around the world, this book suggests that internationalization does not equate with across-the-board use of English, and instead represents a new cultural and linguistic hybridity with the potential to develop new identities unfettered by traditional 'us-and-them' binary thinking.

  15. Hydrogen storage and delivery system development: Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Handrock, J.L. [Sandia National Labs., Livermore, CA (United States)

    1996-10-01

    Hydrogen storage and delivery is an important element in effective hydrogen utilization for energy applications and is an important part of the FY1994-1998 Hydrogen Program Implementation Plan. This project is part of the Field Work Proposal entitled Hydrogen Utilization in Internal Combustion Engines (ICE). The goal of the Hydrogen Storage and Delivery System Development Project is to expand the state-of-the-art of hydrogen storage and delivery system design and development. At the foundation of this activity is the development of both analytical and experimental evaluation platforms. These tools provide the basis for an integrated approach for coupling hydrogen storage and delivery technology to the operating characteristics of potential hydrogen energy use applications. Results of the analytical model development portion of this project will be discussed. Analytical models have been developed for internal combustion engine (ICE) hybrid and fuel cell driven vehicles. The dependence of hydride storage system weight and energy use efficiency on engine brake efficiency and exhaust temperature for ICE hybrid vehicle applications is examined. Results show that while storage system weight decreases with increasing engine brake efficiency energy use efficiency remains relatively unchanged. The development, capability, and use of a recently developed fuel cell vehicle storage system model will also be discussed. As an example of model use, power distribution and control for a simulated driving cycle is presented. Model calibration results of fuel cell fluid inlet and exit temperatures at various fuel cell idle speeds, assumed fuel cell heat capacities, and ambient temperatures are presented. The model predicts general increases in temperature with fuel cell power and differences between inlet and exit temperatures, but under predicts absolute temperature values, especially at higher power levels.

  16. Hydrogen bonded supra-molecular framework in inorganic-organic hybrid compounds: Syntheses, structures, and photoluminescent properties

    Science.gov (United States)

    Yan, Li; Liu, Wei; Li, Chuanbi; Wang, Yifei; Ma, Li; Dong, Qinqin

    2013-03-01

    Two novel compounds constructed from aromatic acid and N-Heterocyclic ligands have been synthesized by hydrothermal reaction: [Cd(mip)(1,8-NDC)(H2O)]2 (1) [mip = 2-(3-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, 1,8-NDC = naphthalene-1,8-dicarboxylic acid] and Cd(mip)2(NTC)2 (2) [NTC = nicotinic acid]. Compounds 1 and 2 are characterized by elemental analysis, IR, single crystal X-ray diffraction and thermogravimetric analysis (TGA). Single-crystal X-ray investigation reveals that compounds 1-2 are 0 dimensional (0D) structures, and the existence of hydrogen bonds and π-π interactions lead the 0D to 2D novel framework. Hydrogen bonds and π-π interactions are powerful non-covalent intermolecular interactions for directing supra-molecular architectures. TG analysis shows clear courses of weight loss, which corresponds to the decomposition of different ligands. At room temperature, compound 1 exhibits emission at 449 nm upon excitation at 325 nm, and compound 2 shows a strong emission at 656 nm upon excitation at 350 nm. Fluorescent spectrum displays that compounds 1 and 2 are potential luminescent materials.

  17. First Nuclear Reaction Experiment with Stored Radioactive 56Ni Beam and Internal Hydrogen and Helium Targets

    NARCIS (Netherlands)

    Egelhof, P.; Bagchi, Soumya; Csatlós, M.; Dillmann, I.; Dimopoulou, C.; Furuno, T; Geissel, H.; Gernhauser, R.; Kalantar-Nayestanaki, Nasser; Kuilman, M.; Mahjour-Shafiei, M.; Najafi, M.A.; Rigollet, C.; Streicher, B.

    2014-01-01

    The investigation of light-ion induced direct reactions using stored and cooled radioactive beams, interacting with internal targets of storage rings, can lead to substantial advantages over external target experiments, in particular for direct reaction experiments in inverse kinematics at very low

  18. New type of microengine using internal combustion of hydrogen and oxygen

    NARCIS (Netherlands)

    Svetovoy, Vitaly; Sanders, Remco G.P.; Ma, Kechun; Elwenspoek, Michael Curt

    2014-01-01

    Microsystems become part of everyday life but their application is restricted by lack of strong and fast motors (actuators) converting energy into motion. For example, widespread internal combustion engines cannot be scaled down because combustion reactions are quenched in a small space. Here we

  19. International Clean Energy System Using Hydrogen Conversion (WE-NET). subtask 2. Research study on promotion of international cooperation (standardization of hydrogen energy technology); Suiso riyo kokusai clean energy system gijutsu (WE-NET). subtask 2. Kokusai kyoryoku suishin no tame no chosa kento (suiso energy gijutsu hyojunka ni kansuru chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This paper describes the basic study on standardization of hydrogen energy technology, and the research study on ISO/TC197 in fiscal 1996. As a part of the WE-NET project, the subtask 2 aims at preparation of standards necessary for practical use and promotion. Developmental states in every field of hydrogen energy technologies, current states of domestic/overseas related standards and laws, and needs and issues of standardization were surveyed. In particular, the needs and issues were clarified in relation to existing standards and laws from the viewpoint of specific hydrogen property. ISO/TC197 was established in 1989 for standardization of the systems and equipment for production, storage, transport, measurement and utilization of hydrogen energy. Four working groups are in action for the supply system and tank of liquid hydrogen fuel for automobiles, the container and ship for complex transport of liquid hydrogen, the specifications of hydrogen products for energy, and the hydrogen supply facility for airports. The draft international standards were proposed to the international conference in 1996. 16 refs., 21 figs., 41 tabs.

  20. A novel control and physical realization of a clean hybrid hydrogen fuel-cell/battery low-power personal electric vehicle

    Science.gov (United States)

    Watkins, Andrew N.

    With the rapid continuation of global warming, high concentrations of pollutants, and foreign oil conflicts, the green energy push has now begun to manifest into great advancements in renewable or clean energies. Fuel-cells have a promising future for mobile power such as the automotive industry, distributed generation, and portable auxiliary power supplies. The type of fuel-cell that has the most focus today is the hydrogen Proton Exchange Membrane (PEM) fuel-cell. It is widely accepted that a fuel-cell cannot effectively supply a dynamic load on its own. In order to correct this drawback and make the fuel-cell system useful for all occasions, a hybrid FC/storage device system needs to be implemented. In this type of system, a balance is created between the high-energy fuel-cell and the high-power storage devices. In this thesis, a hybrid fuel-cell system topology favorable for use in a "personal" electric vehicle such as a scooter is proposed. This topology consists of a fuel-cell connected directly to the batteries and load via a DC link converter. The converter is used to manage the flow of power within the system. In order to have this flow of power to be stable and within operational limits of the devices, a novel adaptive control algorithm implementing six transfer functions based on six major operating conditions is developed. The development of the adaptive algorithm and the implementation of hardware tests were carried out by Matlab/Simulink and dSPACE. The results of the tests showed that the control algorithm was successful at regulating power flow as well as facilitating DC link stability and accuracy at the major operating points.

  1. Does the hybrid light source (LED/laser) influence temperature variation on the enamel surface during 35% hydrogen peroxide bleaching? A randomized clinical trial.

    Science.gov (United States)

    de Freitas, Patricia Moreira; Menezes, Andressa Nery; da Mota, Ana Carolina Costa; Simões, Alyne; Mendes, Fausto Medeiros; Lago, Andrea Dias Neves; Ferreira, Leila Soares; Ramos-Oliveira, Thayanne Monteiro

    2016-01-01

    The present study investigated how a hybrid light source (LED/laser) influences temperature variation on the enamel surfaces during 35% hydrogen peroxide (HP) bleaching. Effects on the whitening effectiveness and tooth sensitivity were analyzed. Twenty-two volunteers were randomly assigned to two different treatments in a split-mouth experimental model: group 1 (control), 35% HP; group 2 (experimental), 35% HP + LED/laser. Color evaluation was performed before treatment, and 7 and 14 days after completion of bleaching, using a color shade scale. Tooth sensitivity was assessed using a visual analog scale (VAS; before, immediately, and 24 hours after bleaching). During the bleaching treatment, thermocouple channels positioned on the tooth surfaces recorded the temperature. Data on color and temperature changes were subjected to statistical analysis (α = 5%). Tooth sensitivity data were evaluated descriptively. Groups 1 and 2 showed mean temperatures (± standard deviation) of 30.7 ± 1.2 °C and 34.1 ± 1.3 °C, respectively. It was found that there were statistically significant differences between the groups, with group 2 showing higher mean variation (P enamel surface. The color change results showed no differences in bleaching between the two treatment groups (P = .177). The variation of the average temperature during the treatments was not statistically associated with color variation (P = .079). Immediately after bleaching, it was found that 36.4% of the subjects in group 2 had mild to moderate sensitivity. In group 1, 45.5% showed moderate sensitivity. In both groups, the sensitivity ceased within 24 hours. Hybrid light source (LED/ laser) influences temperature variation on the enamel surface during 35% HP bleaching and is not related to greater tooth sensitivity.

  2. Self adaptive internal combustion engine control for hydrogen mixtures based on piezoelectric dynamic cylinder pressure transducers

    Energy Technology Data Exchange (ETDEWEB)

    Courteau, R.; Bose, T. K. [Universite du Quebec a Trois-Rivieres, Hydrogen Research Institute, Trois-Rivieres, PQ (Canada)

    2004-07-01

    An algorithm for self-adaptive tuning of an internal combustion engine is proposed, based on a Kalman filter operating on a few selected metrics of the dynamic pressure curve. Piezoelectric transducers are devices to monitor dynamic cylinder pressure; spark plugs with embedded piezo elements are now available to provide diagnostic engine functions. Such transducers are also capable of providing signals to the engine controller to perform auto tuning, a function that is considered very useful particularly in vehicles using alternative fuels whose characteristics frequently show variations between fill-ups. 2 refs., 2 figs.

  3. Internal voltage control of hydrogen-oxygen fuel cells: Feasibility study

    Science.gov (United States)

    Prokopius, P. R.

    1975-01-01

    An experimental study was conducted to assess the feasibility of internal voltage regulation of fuel cell systems. Two methods were tested. In one, reactant partial pressure was used as the voltage control parameter and in the other reactant total pressure was used for control. Both techniques were breadboarded and tested on a single alkaline-electrolyte fuel cell. Both methods were found to be possible forms of regulation, however, of the two the total pressure technique would be more efficient, simpler to apply and would provide better transient characteristics.

  4. Pt Nanostructures/N-Doped Carbon hybrid, an Efficient Catalyst for Hydrogen Evolution/Oxidation Reactions: Enhancing its Base Media Activity through Bifunctionality of the Catalyst.

    Science.gov (United States)

    Barman, Sudip; Kundu, Manas; Bhowmik, Tanmay; Mishra, Ranjit

    2018-06-04

    Design and synthesis of active catalyst for HER/HOR are important for the development of hydrogen based renewable technologies. We report synthesis of Pt nanostructures-N-doped carbon hybrid (Pt-(PtO2)-NSs/C) for HER/HOR applications. The HER activity of this Pt-(PtOx)-NSs/C catalyst is 4 and 6.5 times better than commercial Pt/C in acid and base. The catalyst exhibits a current density of 10 mA/cm2 at overpotentials of 5 and 51 mV with tafel slopes of 29 and 64mV/dec in in 0.5 M H2SO4 and 0.5 M KOH. This catalyst also showed superior HOR activity at all pH values. The HER/HOR activity of Pt-(PtOx)-NSs/C and PtOx-free Pt-Nanostructures/C (PtNSs/C) catalysts are comparable in acid. The presence of PtOx in Pt-(PtOx)-NSs/C makes this Pt-catalyst more HER/HOR active in base media. The activity of Pt-(PtOx)NSs/C catalyst is 5 fold higher than that of PtNSs/C catalyst in basic medium although their activity is comparable in acid. Hydrogen binding energy and oxophilicity are the two equivalent descriptors for HER/HOR in basic media. We propose a bi-functional mechanism for the enhanced alkaline HER/HOR activity of Pt(PtOx)-NSs/C catalyst. In bi-functional Pt-(PtOx)-NSs/C catalyst, PtOx provide an active site for OH- adsorption to form OHads which reacts with hydrogen intermediate (Hads), present at neighbouring Pt sites to form H2O leading to enhancement of HOR activity in basic medium This work may provide opportunity to develop catalysts for various renewable energy technologies. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. FY 1998 summary report on the results of the R and D of the international clean energy network using hydrogen conversion (WE-NET)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For the purpose of solving the global environmental problem and relaxing the energy supply/demand, the R and D were conducted of the international energy network for hydrogen production and utilization using renewable energy, and the FY 1998 results were summarized. As to the conceptual design of the total system, the detailed study was made of the conceptual design of liquid hydrogen transportation/storage system by reviewing the data inputted into the system such as the equipment cost and by making a trial calculation of the power generation cost. Concerning the development of hydrogen production technology, the following were carried out: survey of characteristics of ion exchange membranes of each company, production technology improvement and stacking technology development of large area cell, etc. Relating to the development of hydrogen transportation/storage technology, selection of the hydrogen closed cycle as the liquefaction process, heat insulation test using panel test piece, etc. As to the development of the hydrogen combustion turbine, selection of the oxygen dilution combustion method annular combustor by the combustion experiment, verification of the plant efficiency of more than 60% by the turbine blade evaluation test, evaluation/selection of the topping regenerative cycle high-temperature heat exchanger, etc. (NEDO)

  6. Non-electric applications of nuclear power: Seawater desalination, hydrogen production and other industrial applications. Proceedings of an international conference

    International Nuclear Information System (INIS)

    2009-01-01

    Today, nuclear power plants contribute about 16% to the world's electricity generation. Because electricity represents less than one third of the primary energy uses, nuclear energy provides only about 6% of total energy consumption in the world. If nuclear energy were used for purposes other than electricity generation, it could play a more significant role in global energy supply. This could have also a significant impact on global goals for reduced greenhouse gas emissions for a cleaner environment. Nuclear power is the only large-scale carbon-free energy source that, in the near and medium term, has the potential to significantly displace limited and uncertain fossil fuels. To do this, however, nuclear power must move beyond its historical role as solely a producer of electricity to other non-electric applications. These applications include seawater desalination, district heating, heat for industrial processes, and electricity and heat for hydrogen production among others. These applications have tremendous potential in ensuring future worldwide energy and water security for sustainable development. In recent years, various agencies involved in nuclear energy development programmes have carried out studies on non-electric applications of nuclear power and useful reports have been published. The IAEA launched a programme on co-generation applications in the 1990's in which a number of Member States have been and continue to be actively involved. This programme, however is primarily concerned with seawater desalination, and district and process heating, utilizing the existing reactors as a source of heat and electricity. In recent years the scope of the Agency's programme has been widened to include other more promising applications such as nuclear hydrogen production and higher temperature process heat applications. OECD/NEA (OECD Nuclear Energy Agency), EURATOM (European Atomic Energy Community) and GIF (Generation IV International Forum) have also evinced

  7. Self adaptive internal combustion engine control for hydrogen mixtures based on piezoelectric dynamic cylinder pressure transducers

    International Nuclear Information System (INIS)

    Courteau, R.; Bose, T.K.

    2004-01-01

    Piezoelectric transducers offer an effective, non-intrusive way to monitor dynamic cylinder pressure in internal combustion engines. Devices dedicated to this purpose are appearing on the market, often in the form of spark plugs with embedded piezo elements. Dynamic cylinder pressure is typically used to provide diagnostic functions, or to help map an engine after it is designed. With the advent of powerful signal processor chips, it is now possible to embed enough computing power in the engine controller to perform auto tuning based on the signals provided by such transducers. Such functionality is very useful if the fuel characteristics vary between fill ups, as is often the case with alternative fuels. We propose here an algorithm for self-adaptive tuning based on a Kalman filter operating on a few selected metrics of the dynamic pressure curve. (author)

  8. Hybrid joining of polyamide and hydrogenated acrylonitrile butadiene rubber through heat-resistant functional layer of silane coupling agent

    Science.gov (United States)

    Sang, Jing; Sato, Riku; Aisawa, Sumio; Hirahara, Hidetoshi; Mori, Kunio

    2017-08-01

    A simple, direct adhesion method was developed to join polyamide (PA6) to hydrogenated acrylonitrile butadiene rubber (HNBR) by grafting a functional layer of a silane coupling agent on plasma functionalized PA6 surfaces. The functional layer of the silane coupling agent was prepared using a self-assembly method, which greatly improved the heat resistance of PA6 from 153 °C up to 325 °C and the resulting PA6/HNBR joints showed excellent adhesion properties with cohesive failure between PA6 and HNBR. X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and nanoscale infrared microscopy and chemical imaging (Nano-IR, AFM-IR) were employed to characterize the surfaces and interfaces. The Nano-IR analysis method was employed for the first time to analyze the chemical structures of the adhesion interfaces between different materials and to establish the interface formation mechanism. This study is of significant value for interface research and the study of adhesion between resins and rubbers. There is a promising future for heat-resistant functional layers on resin surfaces, with potential application in fuel hose composite materials for the automotive and aeronautical industries.

  9. High-energy, stable and recycled molecular solar thermal storage materials using AZO/graphene hybrids by optimizing hydrogen bonds.

    Science.gov (United States)

    Luo, Wen; Feng, Yiyu; Qin, Chengqun; Li, Man; Li, Shipei; Cao, Chen; Long, Peng; Liu, Enzuo; Hu, Wenping; Yoshino, Katsumi; Feng, Wei

    2015-10-21

    An important method for establishing a high-energy, stable and recycled molecular solar heat system is by designing and preparing novel photo-isomerizable molecules with a high enthalpy and a long thermal life by controlling molecular interactions. A meta- and ortho-bis-substituted azobenzene chromophore (AZO) is covalently grafted onto reduced graphene oxide (RGO) for solar thermal storage materials. High grafting degree and close-packed molecules enable intermolecular hydrogen bonds (H-bonds) for both trans-(E) and cis-(Z) isomers of AZO on the surface of nanosheets, resulting in a dramatic increase in enthalpy and lifetime. The metastable Z-form of AZO on RGO is thermally stabilized with a half-life of 52 days by steric hindrance and intermolecular H-bonds calculated using density functional theory (DFT). The AZO-RGO fuel shows a high storage capacity of 138 Wh kg(-1) by optimizing intermolecular H-bonds with a good cycling stability for 50 cycles induced by visible light at 520 nm. Our work opens up a new method for making advanced molecular solar thermal storage materials by tuning molecular interactions on a nano-template.

  10. Carbon-Nanotube-Supported Bio-Inspired Nickel Catalyst and Its Integration in Hybrid Hydrogen/Air Fuel Cells.

    Science.gov (United States)

    Gentil, Solène; Lalaoui, Noémie; Dutta, Arnab; Nedellec, Yannig; Cosnier, Serge; Shaw, Wendy J; Artero, Vincent; Le Goff, Alan

    2017-02-06

    A biomimetic nickel bis-diphosphine complex incorporating the amino acid arginine in the outer coordination sphere was immobilized on modified carbon nanotubes (CNTs) through electrostatic interactions. The functionalized redox nanomaterial exhibits reversible electrocatalytic activity for the H 2 /2 H + interconversion from pH 0 to 9, with catalytic preference for H 2 oxidation at all pH values. The high activity of the complex over a wide pH range allows us to integrate this bio-inspired nanomaterial either in an enzymatic fuel cell together with a multicopper oxidase at the cathode, or in a proton exchange membrane fuel cell (PEMFC) using Pt/C at the cathode. The Ni-based PEMFC reaches 14 mW cm -2 , only six-times-less as compared to full-Pt conventional PEMFC. The Pt-free enzyme-based fuel cell delivers ≈2 mW cm -2 , a new efficiency record for a hydrogen biofuel cell with base metal catalysts. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Hybrid approach to fabrication of hollow internally weighted mandibular denture: A case report

    OpenAIRE

    Hazari, Puja; Mishra, Sunil Kumar

    2015-01-01

    Preservation of ridge dimensions is critical for denture success. For long the concept of an internally weighted denture, which suggested that gravity and the additional weight to the mandibular complete denture aids in prosthetic retention is widely accepted. However, excessive weight and pressure can accelerate bone resorption. Here, we describe a unique modification of internally weighted metal denture base for the resorbed mandibular ridge with an incorporated additional hollow section ov...

  12. Hybrid joining of polyamide and hydrogenated acrylonitrile butadiene rubber through heat-resistant functional layer of silane coupling agent

    Energy Technology Data Exchange (ETDEWEB)

    Sang, Jing; Sato, Riku [Department of Frontier Materials and Function Engineering, Graduate School of Engineering, Iwate University, 4-3-5 Ueda, Morioka 020-8551 (Japan); Aisawa, Sumio, E-mail: aisawa@iwate-u.ac.jp [Department of Frontier Materials and Function Engineering, Graduate School of Engineering, Iwate University, 4-3-5 Ueda, Morioka 020-8551 (Japan); Hirahara, Hidetoshi [Department of Frontier Materials and Function Engineering, Graduate School of Engineering, Iwate University, 4-3-5 Ueda, Morioka 020-8551 (Japan); Mori, Kunio [Department of Frontier Materials and Function Engineering, Graduate School of Engineering, Iwate University, 4-3-5 Ueda, Morioka 020-8551 (Japan); Sulfur Chemical Institute, 210, Collabo MIU, 4-3-5, Ueda, Morioka 020-0066 (Japan)

    2017-08-01

    Highlights: • We modify PA6 surface using silane coupling agent layer of APTMS to link HNBR. • APTMS greatly improved heat resistance of PA6 from 153 °C up to 325 °C. • A PA6/HNBR joined body was obtained, and it exhibits high adhesion strength with cohesive failure. • Chemical structures of the adhesion interfaces of PA6/HNBR were confirmed by Nano-IR. - Abstract: A simple, direct adhesion method was developed to join polyamide (PA6) to hydrogenated acrylonitrile butadiene rubber (HNBR) by grafting a functional layer of a silane coupling agent on plasma functionalized PA6 surfaces. The functional layer of the silane coupling agent was prepared using a self-assembly method, which greatly improved the heat resistance of PA6 from 153 °C up to 325 °C and the resulting PA6/HNBR joints showed excellent adhesion properties with cohesive failure between PA6 and HNBR. X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and nanoscale infrared microscopy and chemical imaging (Nano-IR, AFM-IR) were employed to characterize the surfaces and interfaces. The Nano-IR analysis method was employed for the first time to analyze the chemical structures of the adhesion interfaces between different materials and to establish the interface formation mechanism. This study is of significant value for interface research and the study of adhesion between resins and rubbers. There is a promising future for heat-resistant functional layers on resin surfaces, with potential application in fuel hose composite materials for the automotive and aeronautical industries.

  13. Degassing of primordial hydrogen and helium as the major energy source for internal terrestrial processes

    Directory of Open Access Journals (Sweden)

    Arie Lev Gilat

    2012-11-01

    Full Text Available Examples of the mightiest energy releases by great earthquakes and volcanic eruptions and hypotheses providing explanations for them are analyzed along with the results of some recently published researches and visualizations. The emerging conclusions are that the mechanism of the strong earthquake is a chemical explosion; that volcanic eruption is a special type of earthquake wherein the hypocenter rises to the earth-surface; and that there is an association between the seismic-volcanic processes and mantle “fluids” and the lack of energy for mantle plumes. A conceptual system of hypotheses is put forward to explain the conservation of energy during Earth’s accretion, its quasi-stable release by primordial H- and He-degassing and of the crucial role of the energy of degassing-comprising-reactions in endogenic processes. Specific mechanisms and chemical processes are proposed for the gas-liquid mantle plumes melting through the solid mantle using heat-energy released in reactions of their metamorphic and chemical transformation under gradual decrease of pressure and temperature; volcanic gases are put forward as energy carriers. 3He performance as a unique measuring transformer correlative to the internal heat flow was used for calculation of energy release by degassing; it equals to 5.12 × 1020 J/yr, an amount of energy five-fold greater than the entire energy loss involved in earthquake and volcanic activity. The hypotheses proposed are objectively testable.

  14. Hybrid approach to fabrication of hollow internally weighted mandibular denture: A case report.

    Science.gov (United States)

    Hazari, Puja; Mishra, Sunil Kumar

    2015-08-01

    Preservation of ridge dimensions is critical for denture success. For long the concept of an internally weighted denture, which suggested that gravity and the additional weight to the mandibular complete denture aids in prosthetic retention is widely accepted. However, excessive weight and pressure can accelerate bone resorption. Here, we describe a unique modification of internally weighted metal denture base for the resorbed mandibular ridge with an incorporated additional hollow section over the anterior knife-edge ridge. The weight provided retention and stability while the hollow portion prevented further resorption of the bone.

  15. Role of nuclear produced hydrogen for global environment and energy

    International Nuclear Information System (INIS)

    Tashimo, M.; Kurosawa, A.; Ikeda, K.

    2004-01-01

    Sustainability on economical growth, energy supply and environment are major issues for the 21. century. Within this context, one of the promising concepts is the possibility of nuclear-produced hydrogen. In this study, the effect of nuclear-produced hydrogen on the environment is discussed, based on the output of the computer code 'Grape', which simulates the effects of the energy, environment and economy in 21. century. Five cases are assumed in this study. The first case is 'Business as usual by Internal Combustion Engine (ICE)', the second 'CO 2 limited to 550 ppm by ICE', the third 'CO 2 limited to 550 ppm by Hybrid Car', the fourth 'CO 2 limited to 550 ppm by Fuel Cell Vehicle (FCV) with Hydrogen produced by conventional Steam Methane Reforming (SMR)' and the fifth 'CO 2 limited to 550 ppm by FCV with Nuclear Produced-Hydrogen'. The energy used for transportation is at present about 25% of the total energy consumption in the world and is expected to be the same in the future, if there is no improvement of energy efficiency for transportation. On this point, the hybrid car shows the much better efficiency, about 2 times better than traditional internal combustion engines. Fuel Cell powered Vehicles are expected to be a key to resolving the combined issue of the environment and energy in this century. The nuclear-produced hydrogen is a better solution than conventional hydrogen production method using steam methane reforming. (author)

  16. Learning Effectiveness and Satisfaction of International Medical Students: Introducing a Hybrid-PBL Curriculum in Biochemistry

    Science.gov (United States)

    Yan, Qiu; Ma, Li; Zhu, Lina; Zhang, Wenli

    2017-01-01

    A biochemistry course is a fundamental but important subject in medical education in China. In recent years, the number of international medical students has increased. Curriculum reform in biochemistry teaching is needed because of the knowledge limitations of students, a close linkage of biochemical content with clinics, the shortcomings of…

  17. Hybrid Correlation Energy (HyCE): An Approach Based on Separate Evaluations of Internal and External Components.

    Science.gov (United States)

    Ivanic, Joseph; Schmidt, Michael W

    2018-06-04

    A novel hybrid correlation energy (HyCE) approach is proposed that determines the total correlation energy via distinct computation of its internal and external components. This approach evolved from two related studies. First, rigorous assessment of the accuracies and size extensivities of a number of electron correlation methods, that include perturbation theory (PT2), coupled-cluster (CC), configuration interaction (CI), and coupled electron pair approximation (CEPA), shows that the CEPA(0) variant of the latter and triples-corrected CC methods consistently perform very similarly. These findings were obtained by comparison to near full CI results for four small molecules and by charting recovered correlation energies for six steadily growing chain systems. Second, by generating valence virtual orbitals (VVOs) and utilizing the CEPA(0) method, we were able to partition total correlation energies into internal (or nondynamic) and external (or dynamic) parts for the aforementioned six chain systems and a benchmark test bed of 36 molecules. When using triple-ζ basis sets it was found that per orbital internal correlation energies were appreciably larger than per orbital external energies and that the former showed far more chemical variation than the latter. Additionally, accumulations of external correlation energies were seen to proceed smoothly, and somewhat linearly, as the virtual space is gradually increased. Combination of these two studies led to development of the HyCE approach, whereby the internal and external correlation energies are determined separately by CEPA(0)/VVO and PT2/external calculations, respectively. When applied to the six chain systems and the 36-molecule benchmark test set it was found that HyCE energies followed closely those of triples-corrected CC and CEPA(0) while easily outperforming MP2 and CCSD. The success of the HyCE approach is more notable when considering that its cost is only slightly more than MP2 and significantly cheaper

  18. General concept of a gas engine for a hybrid vehicle, operating on methanol dissociation products

    International Nuclear Information System (INIS)

    Tartakovsky, L.; Aleinikov, Y.; Fainberg, V.; Garbar, A.; Gutman, M.; Hetsroni, G.; Schindler, Y.; Zvirin, Y.

    1998-01-01

    The paper presents a general concept of a hybrid propulsion system, based on an SI internal combustion engine fueled by methanol dissociation products (MDP). The proposed hybrid propulsion scheme is a series hybrid, which allows the engine to be operated in an on-off mode at constant optimal regime. The engine is fed by gaseous products of methanol dissociation (mainly hydrogen and carbon monoxide) emerging from an on-board catalytic reformer. The general scheme and base operation features of the propulsion system are described. The benefits that may be achieved by combining the well-known idea of on-board methanol dissociation with the hybrid vehicle concept are discussed. The proposed scheme is compared with those of systems operating on gasoline, liquid methanol, hydrogen and also with the multi-regime (not hybrid) engine fed by MDP

  19. Comparative assessment of hydrogen storage and international electricity trade for a Danish energy system with wind power and hydrogen/fuel cell technologies. Final project report

    Energy Technology Data Exchange (ETDEWEB)

    Soerensen, Bent (Roskilde University, Energy, Environment and Climate Group, Dept. of Environmental, Social and Spatial Change (ENSPAC) (DK)); Meibom, P.; Nielsen, Lars Henrik; Karlsson, K. (Technical Univ. of Denmark, Risoe National Laboratory for Sustainable Energy, Systems Analysis Dept., Roskilde (DK)); Hauge Pedersen, A. (DONG Energy, Copenhagen (DK)); Lindboe, H.H.; Bregnebaek, L. (ea Energy Analysis, Copenhagen (DK))

    2008-02-15

    This report is the final outcome of a project carried out under the Danish Energy Agency's Energy Research Programme. The aims of the project can be summarized as follows: 1) Simulation of an energy system with a large share of wind power and possibly hydrogen, including economic optimization through trade at the Nordic power pool (exchange market) and/or use of hydrogen storage. The time horizon is 50 years. 2) Formulating new scenarios for situations with and without development of viable fuel cell technologies. 3) Updating software to solve the abovementioned problems. The project has identified a range of scenarios for all parts of the energy system, including most visions of possible future developments. (BA)

  20. Performance improvement of a hybrid air conditioning system using the indirect evaporative cooler with internal baffles as a pre-cooling unit

    Directory of Open Access Journals (Sweden)

    A.E. Kabeel

    2017-12-01

    Full Text Available In the present paper, the effects of the indirect evaporative cooler with internal baffle on the performance of the hybrid air conditioning system are numerically investigated. The hybrid air conditioning system contains two indirect evaporative coolers with internal baffle, one is utilized to pre-cool the air inlet to the desiccant wheel and the other is utilized to pre-cool the supply air inlet to the room. The effects of the inlet conditions of the process and reactivation air and working air ratio on the thermal performance of the hybrid air conditioning system have been analyzed. The results of this study show that in the hybrid air conditioning system for using the indirect evaporative cooler with internal baffle as a pre-cooling unit, the supply air temperature reduced by 21% and the coefficient of performance improved by 71% as compared to previous designs of the hybrid air conditioning system at the same inlet conditions. For increasing process air inlet temperature from 25 °C to 45 °C, supply air temperature increases from 12.7 °C to 14.2 °C, thermal COP increases from 1.87 to 2.84, and supply air relative humidity increases from 76.7% to 77.4%. Also, for increasing the reactivation air inlet temperature from 70 °C to 110 °C, supply air temperature dropped from 15.9 °C to 10.9 °C, supply air relative humidity dropped from 82.7% to 71.8%, and thermal COP dropped from 4.5 to 1.7. The recommended optimal air working ratio in the indirect evaporative cooler with internal baffle should be 0.15. Keywords: Desiccant material, Solar air collector, Evaporative cooler, Internal baffles, Air conditioning

  1. Internal combustion engine control for series hybrid electric vehicles by parallel and distributed genetic programming/multiobjective genetic algorithms

    Science.gov (United States)

    Gladwin, D.; Stewart, P.; Stewart, J.

    2011-02-01

    This article addresses the problem of maintaining a stable rectified DC output from the three-phase AC generator in a series-hybrid vehicle powertrain. The series-hybrid prime power source generally comprises an internal combustion (IC) engine driving a three-phase permanent magnet generator whose output is rectified to DC. A recent development has been to control the engine/generator combination by an electronically actuated throttle. This system can be represented as a nonlinear system with significant time delay. Previously, voltage control of the generator output has been achieved by model predictive methods such as the Smith Predictor. These methods rely on the incorporation of an accurate system model and time delay into the control algorithm, with a consequent increase in computational complexity in the real-time controller, and as a necessity relies to some extent on the accuracy of the models. Two complementary performance objectives exist for the control system. Firstly, to maintain the IC engine at its optimal operating point, and secondly, to supply a stable DC supply to the traction drive inverters. Achievement of these goals minimises the transient energy storage requirements at the DC link, with a consequent reduction in both weight and cost. These objectives imply constant velocity operation of the IC engine under external load disturbances and changes in both operating conditions and vehicle speed set-points. In order to achieve these objectives, and reduce the complexity of implementation, in this article a controller is designed by the use of Genetic Programming methods in the Simulink modelling environment, with the aim of obtaining a relatively simple controller for the time-delay system which does not rely on the implementation of real time system models or time delay approximations in the controller. A methodology is presented to utilise the miriad of existing control blocks in the Simulink libraries to automatically evolve optimal control

  2. Achievement report for fiscal 1993. International clean energy system technology to utilize hydrogen (WE-NET) (Sub-task 5. Development of hydrogen transportation and storage technology) (Edition 5. Development of hydrogen absorbing alloys for discrete transportation and storage); 1993 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET) . Sub tusk 5. Suiso yuso chozo gijutsu no kaihatsu - Dai 5 hen. Bunsan yuso chozo you suiso kyuzo gokin no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    Surveys and researches have been performed with an objective to accumulate knowledge required for R and D of a hydrogen transportation and storage technology. With respect to the hydrogen absorbing alloys for hydrogen transportation and storage, surveys have been carried out on the rare earth-nickel based alloy, magnesium based alloy, titanium/zirconium based alloy, vanadium based alloy, and other alloys. Regarding the hydrogen transportation and storage technology using hydrogen absorbing alloys, surveys have been made on R and D cases for hydrogen transporting containers, stationary hydrogen storing equipment, and hydrogen fuel tank for mobile equipment such as automobiles. For the R and D situation in overseas countries, site surveys have been executed on research organizations in Germany and Switzerland, the leader nations in R and D of hydrogen absorbing alloys. As a result of the surveys, the hydrogen absorbing alloys were found to have such R and D assignments as increase of effective hydrogen absorbing quantity, compliance with operating conditions, life extension, development of alloys easy in initial activation and fast in hydrogen discharge speed, and cost reduction. Items of the transportation and storage equipment have such assignments as making them compact, acceleration of heat conduction in alloy filling layers, handling of volume variation and internal stress, and long-term durability. (NEDO)

  3. Observation of Internal Photoinduced Electron and Hole Separation in Hybrid Two-Dimentional Perovskite Films.

    Science.gov (United States)

    Liu, Junxue; Leng, Jing; Wu, Kaifeng; Zhang, Jun; Jin, Shengye

    2017-02-01

    Two-dimensional (2D) organolead halide perovskites are promising for various optoelectronic applications. Here we report a unique spontaneous charge (electron/hole) separation property in multilayered (BA) 2 (MA) n-1 Pb n I 3n+1 (BA = CH 3 (CH 2 ) 3 NH 3 + , MA = CH 3 NH 3 + ) 2D perovskite films by studying the charge carrier dynamics using ultrafast transient absorption and photoluminescence spectroscopy. Surprisingly, the 2D perovskite films, although nominally prepared as "n = 4", are found to be mixture of multiple perovskite phases, with n = 2, 3, 4 and ≈ ∞, that naturally align in the order of n along the direction perpendicular to the substrate. Driven by the band alignment between 2D perovskites phases, we observe consecutive photoinduced electron transfer from small-n to large-n phases and hole transfer in the opposite direction on hundreds of picoseconds inside the 2D film of ∼358 nm thickness. This internal charge transfer efficiently separates electrons and holes to the upper and bottom surfaces of the films, which is a unique property beneficial for applications in photovoltaics and other optoelectronics devices.

  4. NOSH-NBP, a Novel Nitric Oxide and Hydrogen Sulfide- Releasing Hybrid, Attenuates Ischemic Stroke-Induced Neuroinflammatory Injury by Modulating Microglia Polarization

    Directory of Open Access Journals (Sweden)

    Jing Ji

    2017-05-01

    Full Text Available NOSH-NBP, a novel nitric oxide (NO and hydrogen sulfide (H2S-releasing hybrid, protects brain from ischemic stroke. This study mainly aimed to investigate the therapeutic effect of NOSH-NBP on ischemic stroke and the underlying mechanisms. In vivo, transient middle cerebral artery occlusion (tMCAO was performed in C57BL/6 mice, with NO-NBP and H2S-NBP as controls. NO and H2S scavengers, carboxy-PTIO and BSS, respectively, were used to quench NO and H2S of NOSH-NBP. In vitro, BV2 microglia/BMDM were induced to the M1/2 phenotype, and conditioned medium (CM experiments in BV2 microglia, neurons and b.End3 cerebral microvascular endothelial cells (ECs were performed. Microglial/macrophage activation/polarization was assessed by flow cytometry, Western blot, RT-qPCR, and ELISA. Neuronal and EC survival was measured by TUNEL, flow cytometry, MTT and LDH assays. Transmission electron microscopy, EB extravasation, brain water content, TEER measurement and Western blot were used to detect blood–brain barrier (BBB integrity and function. Interestingly, NOSH-NBP significantly reduced cerebral infarct volume and ameliorated neurological deficit, with superior effects compared with NO-NBP and/or H2S-NBP in mice after tMCAO. Both NO and H2S-releasing groups contributed to protection by NOSH-NBP. Additionally, NOSH-NBP decreased neuronal death and attenuated BBB dysfunction in tMCAO-treated mice. Furthermore, NOSH-NBP promoted microglia/macrophage switch from an inflammatory M1 phenotype to the protective M2 phenotype in vivo and in vitro. Moreover, the TLR4/MyD88/NF-κB pathway and NLRP3 inflammasome were involved in the inhibitory effects of NOSH-NBP on M1 polarization, while peroxisome proliferator activated receptor gamma signaling contributed to NOSH-NBP induced M2 polarization. These findings indicated that NOSH-NBP is a potential therapeutic agent that preferentially promotes microglial/macrophage M1–M2 switch in ischemic stroke.

  5. elsA-Hybrid: an all-in-one structured/unstructured solver for the simulation of internal and external flows. Application to turbomachinery

    Science.gov (United States)

    de la Llave Plata, M.; Couaillier, V.; Le Pape, M.-C.; Marmignon, C.; Gazaix, M.

    2013-03-01

    This paper reports recent work on the extension of the multiblock structured solver elsA to deal with hybrid grids. The new hybrid-grid solver is called elsA-H (elsA-Hybrid), is based on the investigation of a new unstructured-grid module has been built within the original elsA CFD (computational fluid dynamics) system. The implementation benefits from the flexibility of the object-oriented design. The aim of elsA-H is to take advantage of the full potential of structured solvers and unstructured mesh generation by allowing any type of grid to be used within the same simulation process. The main challenge lies in the numerical treatment of the hybrid-grid interfaces where blocks of different type meet. In particular, one must pay attention to the transfer of information across these boundaries, so that the accuracy of the numerical scheme is preserved and flux conservation is guaranteed. In this paper, the numerical approach allowing to achieve this is presented. A comparison between the hybrid and the structured-grid methods is also carried out by considering a fully hexahedral multiblock mesh for which a few blocks have been transformed into unstructured. The performance of elsA-H for the simulation of internal flows will be demonstrated on a number of turbomachinery configurations.

  6. International Clean Energy System Using Hydrogen Conversion (WE-NET). subtask 2. Research study on promotion of international cooperation; Suiso riyo kokusai clean energy system gijutsu (WE-NET). subtask 2. Kokusai kyoryoku suishin no tame no chosa kento

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This paper describes the research result on promotion of international cooperation in the WE-NET project in fiscal 1996. The WE-NET project aims at development of the total system for hydrogen production, transport, storage and utilization, and construction of the earth-friendly innovative global clean energy network integrating elemental technologies. Since the standpoint is different between latent resource supplying countries and technology supplying countries, the WE-NET project should be constantly promoted under international understanding and cooperation. The committee distributed the annual summary report prepared by NEDO to overseas organizations, and made positive PR activities in the 11th World Conference and others. The committee made the evaluation on the improvement effect of air pollution by introducing a hydrogen vehicle in combination with Stanford University, and preparation of PR video tapes for hydrogen energy. Preliminary arrangement of Internet home pages, establishment of a long-term vision for international cooperation, and proposal toward the practical WE-NET are also made. 9 figs., 13 tabs.

  7. HySDeP: a computational platform for on-board hydrogen storage systems – hybrid high-pressure solid-state and gaseous storage

    DEFF Research Database (Denmark)

    Mazzucco, Andrea; Rokni, Masoud

    2016-01-01

    A computational platform is developed in the Modelica® language within the DymolaTM environment to provide a tool for the design and performance comparison of on-board hydrogen storage systems. The platform has been coupled with an open source library for hydrogen fueling stations to investigate...

  8. Modeling of lower hybrid current drive (LHCD) and parametric instability (PI) for high performance internal transport barriers (ITBs)

    International Nuclear Information System (INIS)

    Cesario, R.; Cardinali, A.; Castaldo, C.; Paoletti, F.; Challis, C.; Mailloux, J.; Mazon, D.

    2003-01-01

    ITBs (internal transport barrier) with high performance in time duration (4 seconds) were produced at Jet in plasma discharges operating at the plasma current of 2,4 MA and toroidal magnetic field of 3,45 T using lower hybrid (LH) radiofrequency power (2,3 MW) for heating and current drive. The first results of the modeling devoted to calculate the LH power deposition and current density profiles for ITB plasmas are presented. The LH power density profile was first calculated considering the nominal LH power n / spectrum launched by the antenna, a substantially centrally deposition is obtained, many passes (> 10) are necessary for producing a significant fraction of the coupled LH power to be absorbed. In a second step some broadening (20%) of the launched n / power spectrum was considered to simulate the effect of a non-linear wave scattering. Most of the LH power is deposited at the first pass, mainly in the outer half of plasma. The simulation gives a moderate amount (60%) of non-inductive current, including 30% of LHCD fraction. The q-profiles from polarization and from MSE (motional Stark effect) at the beginning and during the main heating phase were analysed. Non-linear plasma edge phenomena allow propagation of some LH power with large n / . Such effect should be retained for a realistic LHCD modeling of ITB plasmas. The consequent enhanced off-axis LHCD is consistent with the observed large ITBs and the obtained large region with low magnetic shear. The LH power might provide a powerful tool for controlling the q-profile for ITB at high plasma current, for potential application to the advanced tokamak regimes

  9. Modeling of lower hybrid current drive (LHCD) and parametric instability (PI) for high performance internal transport barriers (ITBs)

    Energy Technology Data Exchange (ETDEWEB)

    Cesario, R.; Cardinali, A.; Castaldo, C. [Associazione Euratom-ENEA sulla Fusione, Centro Ricerche Frascadi (Italy); Paoletti, F. [PPPL Pinceton (United States); Challis, C.; Mailloux, J. [Euratom-UKAEA fusion association, Culham Science Centre, Abingdon, Oxfordshire, OX (United Kingdom); Mazon, D. [Association Euratom-CEA Cadarache, 13 - Saint-Paul-lez-Durance (France)

    2003-07-01

    ITBs (internal transport barrier) with high performance in time duration (4 seconds) were produced at Jet in plasma discharges operating at the plasma current of 2,4 MA and toroidal magnetic field of 3,45 T using lower hybrid (LH) radiofrequency power (2,3 MW) for heating and current drive. The first results of the modeling devoted to calculate the LH power deposition and current density profiles for ITB plasmas are presented. The LH power density profile was first calculated considering the nominal LH power n{sub /} spectrum launched by the antenna, a substantially centrally deposition is obtained, many passes (> 10) are necessary for producing a significant fraction of the coupled LH power to be absorbed. In a second step some broadening (20%) of the launched n{sub /} power spectrum was considered to simulate the effect of a non-linear wave scattering. Most of the LH power is deposited at the first pass, mainly in the outer half of plasma. The simulation gives a moderate amount (60%) of non-inductive current, including 30% of LHCD fraction. The q-profiles from polarization and from MSE (motional Stark effect) at the beginning and during the main heating phase were analysed. Non-linear plasma edge phenomena allow propagation of some LH power with large n{sub /}. Such effect should be retained for a realistic LHCD modeling of ITB plasmas. The consequent enhanced off-axis LHCD is consistent with the observed large ITBs and the obtained large region with low magnetic shear. The LH power might provide a powerful tool for controlling the q-profile for ITB at high plasma current, for potential application to the advanced tokamak regimes.

  10. US work on technical and economic aspects of electrolytic, thermochemical, and hybrid processes for hydrogen production at temperatures below 550 deg. C

    International Nuclear Information System (INIS)

    Petri, M.C.; Yyldyz, B.; Klickman, A.E.

    2006-01-01

    Hydrogen demand is increasing, but there are few options for affordable hydrogen production free of greenhouse gas emissions. Nuclear power is one of the most promising options. Most research is focused on high-temperature electrolytic and thermochemical processes for nuclear-generated hydrogen, but it will be many years before very high temperature reactors become commercially available. For light water reactors or supercritical reactors, low-temperature water electrolysis is a currently available technology for hydrogen production. Higher efficiencies may be gained through thermo-electrochemical hydrogen production cycles, but there are only a limited number that have heat requirements consistent with the lower temperatures of light-water reactor technology. Indeed, active research is ongoing for only three such cycles in the USA. Reductions in electricity and system costs would be needed (or the imposition of a carbon tax) for low-temperature water electrolysis to compete with today's costs for steam methane reformation. The interactions between hydrogen and electricity markets and hydrogen and electricity producers are complex and will evolve as the markets evolve. (author)

  11. Hydrogen energy applications

    International Nuclear Information System (INIS)

    Okken, P.A.

    1992-10-01

    For the Energy and Material consumption Scenarios (EMS), by which emission reduction of CO 2 and other greenhouse gases can be calculated, calculations are executed by means of the MARKAL model (MARket ALlocation, a process-oriented dynamic linear programming model to minimize the costs of the energy system) for the Netherlands energy economy in the period 2000-2040, using a variable CO 2 emission limit. The results of these calculations are published in a separate report (ECN-C--92-066). The use of hydrogen can play an important part in the above-mentioned period. An overview of several options to produce or use hydrogen is given and added to the MARKAL model. In this report techno-economical data and estimates were compiled for several H 2 -application options, which subsequently also are added to the MARKAL model. After a brief chapter on hydrogen and the impact on the reduction of CO 2 emission attention is paid to stationary and mobile applications. The stationary options concern the mixing of natural gas with 10% hydrogen, a 100% substitution of natural gas by hydrogen, the use of a direct steam generator (combustion of hydrogen by means of pure oxygen, followed by steam injection to produce steam), and the use of fuel cells. The mobile options concern the use of hydrogen in the transportation sector. In brief, attention is paid to a hydrogen passenger car with an Otto engine, and a hydrogen passenger car with a fuel cell, a hybrid (metal)-hydride car, a hydrogen truck, a truck with a methanol fuel cell, a hydrogen bus, an inland canal boat with a hydrogen fuel cell, and finally a hydrogen airplane. 2 figs., 15 tabs., 1 app., 26 refs

  12. Minimum deltaV Burn Planning for the International Space Station Using a Hybrid Optimization Technique, Level 1

    Science.gov (United States)

    Brown, Aaron J.

    2015-01-01

    The International Space Station's (ISS) trajectory is coordinated and executed by the Trajectory Operations and Planning (TOPO) group at NASA's Johnson Space Center. TOPO group personnel routinely generate look-ahead trajectories for the ISS that incorporate translation burns needed to maintain its orbit over the next three to twelve months. The burns are modeled as in-plane, horizontal burns, and must meet operational trajectory constraints imposed by both NASA and the Russian Space Agency. In generating these trajectories, TOPO personnel must determine the number of burns to model, each burn's Time of Ignition (TIG), and magnitude (i.e. deltaV) that meet these constraints. The current process for targeting these burns is manually intensive, and does not take advantage of more modern techniques that can reduce the workload needed to find feasible burn solutions, i.e. solutions that simply meet the constraints, or provide optimal burn solutions that minimize the total DeltaV while simultaneously meeting the constraints. A two-level, hybrid optimization technique is proposed to find both feasible and globally optimal burn solutions for ISS trajectory planning. For optimal solutions, the technique breaks the optimization problem into two distinct sub-problems, one for choosing the optimal number of burns and each burn's optimal TIG, and the other for computing the minimum total deltaV burn solution that satisfies the trajectory constraints. Each of the two aforementioned levels uses a different optimization algorithm to solve one of the sub-problems, giving rise to a hybrid technique. Level 2, or the outer level, uses a genetic algorithm to select the number of burns and each burn's TIG. Level 1, or the inner level, uses the burn TIGs from Level 2 in a sequential quadratic programming (SQP) algorithm to compute a minimum total deltaV burn solution subject to the trajectory constraints. The total deltaV from Level 1 is then used as a fitness function by the genetic

  13. Measuring the environmental benefits of hydrogen transportation fuel cycles under uncertainty about external costs

    International Nuclear Information System (INIS)

    Chernyavs'ka, Liliya; Gulli, Francesco

    2010-01-01

    In this paper, we attempt to measure the environmental benefits of hydrogen deployment in the transportation sector. We compare the hydrogen pathways to the conventional transportation fuel cycles in terms of external costs, estimated using the results of the most accurate methodologies available in this field. The central values of performed analysis bring us ambiguous results. The external cost of the best conventional solution ('oil to diesel hybrid internal-combustion engine') in some cases is just higher and in others just lower than that of the best fossil fuel to hydrogen solution ('natural gas to hydrogen fuel cell'). Nevertheless, by accounting for the uncertainty about external costs, we are able to remove this ambiguity highlighting that the hydrogen pathway provides significant environmental benefits ,especially in densely populated areas, assuming 100% city driving.

  14. IEA HIA Task 37 - Hydrogen Safety

    DEFF Research Database (Denmark)

    Markert, Frank

    The work plan and objectives of this task are designed to support the acceleration of safe implementation of hydrogen infrastructure through coordinated international collaborations and hydrogen safety knowledge dissemination.......The work plan and objectives of this task are designed to support the acceleration of safe implementation of hydrogen infrastructure through coordinated international collaborations and hydrogen safety knowledge dissemination....

  15. Hydrogen from nuclear energy and the impact on climate change

    International Nuclear Information System (INIS)

    Duffey, R.B.; Miller, A.I.; Poehnell, T.G.

    2001-01-01

    The two major candidates for hydrogen production include nuclear power and other renewable energy sources. However, hydrogen produced by steam reforming of natural gas offers little advantage in total cycle greenhouse gas (GHG) emissions over hybrid internal combustion engine (ICE) technology. Only nuclear power offers the possibility of cutting GHG emissions significantly and to economically provide electricity for traditional applications and by producing hydrogen for its widespread use in the transportation sector. Using nuclear energy to produce hydrogen for transportation fuel, doubles or triples nuclear's capacity to reduce GHG emissions. An analysis at the Atomic Energy of Canada shows that a combination of hydrogen fuel and nuclear energy can stabilize GHG emissions and climate change for a wide range of the latest scenarios presented by the Intergovernmental Panel on Climate Change. The technology for replacing hydrocarbon fuels with non-polluting hydrogen exists with nuclear power, electrolysis and fuel cells, using electric power grids for distribution. It was emphasized that a move toward total emissions-free transportation will be a move towards solving the negative effects of climate change. This paper illustrated the trends between global economic and atmospheric carbon dioxide concentrations. Low carbon dioxide emission energy alternatives were discussed along with the sources of hydrogen and the full cycle assessment results in reduced emissions. It was shown that deploying 20 CANDU NPPs (of 690 MW (e) net each) would fuel 13 million vehicles with the effect of levelling of carbon dioxide emissions from transportation between 2020 to 2030. 13 refs., 2 tabs., 3 figs

  16. Achievement report for fiscal 2000 on the phase II research and development for the hydrogen utilizing international clean energy system technology (WE-NET). Task 1. Investigations and researched on system assessment; 2000 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dai 2 ki kenkyu kaihatsu. Task 1. System hyoka ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This paper describes the achievements in fiscal 2000 from the WE-NET Phase II for Task-1. Technologies drawing attentions relate to fuel cell driven automobiles and hybrid automobiles in the field of utilizing hydrogen derived from reproducible energies and fossil energies, and fuel cell co-generation and micro gas turbine co-generation in the field of electric power generation. Hydrogen reformed from gasoline on board the automobile as the fuel for fuel cell driven automobiles, hydrogen as a by-product of coke furnace off-gas (COG), and reproducible energy hydrogen have the same fuel consumption performance as in the hybrid automobiles. Particularly the COG is low in cost, and has large supply potential. Liquefied hydrogen is as promising as compressed hydrogen in view of the cost for automotive hydrogen supply stations. What has high economic performance as the self-sustaining systems for islands are photovoltaic and wind power generation, and the system using hydrogen as the secondary energy. Since much of the reproducible energies is used for electric power demand in Japan, the by-product hydrogen and the reformed hydrogen in an amount of 9.3 billion Nm{sup 3}/year would take care of majority of the demand in view of the short time period. For a longer time span, hydrogen originated from the reproduced energies in the Pan-Pacific Region should be introduced. (NEDO)

  17. Fiscal 1999 hydrogen utilization international clean energy system technology (WE-NET). Phase 2 R and D (Task 3) - survey/study concerning international cooperation (Survey/study concerning standardization of hydrogen energy technology); 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu. Task 3. Kokusai kyoryoku ni kansuru kenkyu (suiso energy gijutsu hyojunka ni kansuru chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    With the aim of R and D of hydrogen energy technologies and the promotion of their practical use and proliferation, conducted were research on standardization of hydrogen energy technologies and research/study on draft international standards proposed by ISO/TC197. In the research on the standardization, legislation, rules and guidelines for Japan were compiled based on reference to the materials in the 'sourcebook for hydrogen applications' which was prepared in the U.S./Canada. The Japanese laws and regulations applicable to hydrogen are the high pressure gas safety law, fire service law, industrial safety and health law, building standard law, law on prevention of disasters in petroleum industrial complexes and other petroleum facilities, road vehicles act, road traffic law, harbor regulation law, etc., with related legislation compiled under headings classified as pressure containers, gas facilities, consumption, transportation, explosion proofing of electrical equipment, list of laws, and related documents. In reference to ISO/TC197, the 8th plenary meeting and WGs were held during April 6-8, 1999, in the U.S., where the progress status report, study contents, future schedule for newly proposed items, etc., of each WG were reviewed and discussed. (NEDO)

  18. Fiscal 1999 hydrogen utilization international clean energy system technology (WE-NET). Phase 2 R and D (Task 3) - survey/study concerning international cooperation (Survey/study concerning standardization of hydrogen energy technology); 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu. Task 3. Kokusai kyoryoku ni kansuru kenkyu (suiso energy gijutsu hyojunka ni kansuru chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    With the aim of R and D of hydrogen energy technologies and the promotion of their practical use and proliferation, conducted were research on standardization of hydrogen energy technologies and research/study on draft international standards proposed by ISO/TC197. In the research on the standardization, legislation, rules and guidelines for Japan were compiled based on reference to the materials in the 'sourcebook for hydrogen applications' which was prepared in the U.S./Canada. The Japanese laws and regulations applicable to hydrogen are the high pressure gas safety law, fire service law, industrial safety and health law, building standard law, law on prevention of disasters in petroleum industrial complexes and other petroleum facilities, road vehicles act, road traffic law, harbor regulation law, etc., with related legislation compiled under headings classified as pressure containers, gas facilities, consumption, transportation, explosion proofing of electrical equipment, list of laws, and related documents. In reference to ISO/TC197, the 8th plenary meeting and WGs were held during April 6-8, 1999, in the U.S., where the progress status report, study contents, future schedule for newly proposed items, etc., of each WG were reviewed and discussed. (NEDO)

  19. Protein Internal Dynamics Associated With Pre-System Glass Transition Temperature Endothermic Events: Investigation of Insulin and Human Growth Hormone by Solid State Hydrogen/Deuterium Exchange.

    Science.gov (United States)

    Fang, Rui; Grobelny, Pawel J; Bogner, Robin H; Pikal, Michael J

    2016-11-01

    Lyophilized proteins are generally stored below their glass transition temperature (T g ) to maintain long-term stability. Some proteins in the (pure) solid state showed a distinct endotherm at a temperature well below the glass transition, designated as a pre-T g endotherm. The pre-T g endothermic event has been linked with a transition in protein internal mobility. The aim of this study was to investigate the internal dynamics of 2 proteins, insulin and human growth hormone (hGH), both of which exhibit the pre-T g endothermic event with onsets at 50°C-60°C. Solid state hydrogen/deuterium (H/D) exchange of both proteins was characterized by Fourier transform infrared spectroscopy over a temperature range from 30°C to 80°C. A distinct sigmoidal transition in the extent of H/D exchange had a midpoint of 56.1 ± 1.2°C for insulin and 61.7 ± 0.9°C for hGH, suggesting a transition to greater mobility in the protein molecules at these temperatures. The data support the hypothesis that the pre-T g event is related to a transition in internal protein mobility associated with the protein dynamical temperature. Exceeding the protein dynamical temperature is expected to activate protein internal motion and therefore may have stability consequences. Copyright © 2016 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

  20. Book of abstracts of the 3rd International conference and the 3rd International School for young scientists Interaction of hydrogen isotopes with structural materials. IHISM-07; Tezisy dokladov Tret'ej mezhdunarodnoj konferentsii i Tret'ej mezhdunarodnoj Shkoly molodykh uchenykh i spetsialistov Vzaimodejstvie izotopov vodoroda s konstruktsionnymi materialami. IHISM-07

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    The book involves abstracts of presentations at the 3rd International Conference and the 3rd International School for Young Scientists Interaction of Hydrogen Isotopes with Structural Materials (IHISM-07). The activities of Russian and foreign scientific centers associated with the use of hydrogen isotopes in power engineering, national economy and basic research are considered. The presentations cover the following areas: kinetics and interaction between hydrogen isotopes and solids including effects of radiogenic helium accumulation, hydrides and hydride transformations; structural transformations and mechanical properties; equipment and research techniques.

  1. Hydrogen utilization international clean energy system (WE-NET). Subtask 8. Development of hydrogen combustion turbines (development of combustion control technology); Suiso riyo kokusai clean energy system (WE-NET). Subtask 8. Suiso nensho turbine no kaihatsu nensho seigyo gijutsu no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The paper described the fiscal 1996 developmental results of hydrogen burning turbine combustion technology in the hydrogen utilization international clean energy system (WE-NET) project. A test was conducted on an annular type combustor where oxygen is mixed with steam (inert gas) at burner and fired with hydrogen. Appropriate flame shape and cooling/dilution vapor distribution were attempted, and various data on combustion were measured for improvement. Mixture and flame holding were improved by developing a can type combustor (1) where oxygen is diluted with steam after firing oxygen and hydrogen around burner and by strengthening circulation in the combustor. Improvement such as appropriate steam distribution, etc. is needed. A can type combustor (2) was tested in which the premixed oxygen and hydrogen is supplied from scoop and fired with hydrogen. By supplying part of oxygen from the primary scoop, the residual hydrogen and oxygen concentration around the stoichiometric ratio can be reduced. Concentration of the residual oxygen can be measured by the absorption light method, but it is difficult to adopt the non-contact measuring method to hydrogen. An outlook for the gas temperature measuring method was obtained. 12 refs., 121 figs., 27 tabs.

  2. Magnesium mechanical alloys for hydrogen storage

    International Nuclear Information System (INIS)

    Ivanov, E.; Konstanchuk, I.; Stepanov, A.; Boldyrev, V.

    1985-01-01

    Metal hybrides are currently being used to store and handle hydrogen and its isotopes. They are also being tested in hydrogen compressors and in heat energy, refrigerators and in hydrogen and thermal storage devices. Metal hydrides have been proposed as one of the possible media for hydrogen storage to overcome the limitations of other techniques in regard to safety hydrogen weight and volume ration. The suitability of metal hybrides as a hydrogen storage media depends on a number of factors such as storage capacity, reactivity with hydrogen at various pressures and temperatures, and the cost of base materials. Magnesium based alloys are promising materials for storing hydrogen. They are generally made by argon melting and no attention has been payed to other fabrication techniques such as mechanical alloying or powder technique

  3. Fiscal 1998 research report on International Clean Energy Network using Hydrogen Conversion (WE-NET). Subtask 2. Research on promotion of international cooperation (research on standardization of hydrogen energy technologies); 1998 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) sub task. 2. Kokusai kyoryoku suishin no tame no chosa kento (suiso energy gijutsu hyojunka ni kansuru chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This report summarizes the fiscal 1998 research result on the basic research on standardization of hydrogen energy technologies, and ISO/TC197. As for the standardization, in relation to the hydrogen station in the WE-NET second phase research, the laws related to handling of gaseous hydrogen, and the basic issues on facility and safe handling were studied. As for ISO/TC197, the following draft standards were examined: Fuel supply system interface for liquid hydrogen vehicles, fuel tank for liquid hydrogen vehicles, container for liquid hydrogen transport, specification of hydrogen fuel, hydrogen fuel supply facility for air ports, gaseous hydrogen and hydrogen mixture fuel system for vehicles, gaseous hydrogen fuel connector for vehicles, gaseous hydrogen fuel tank for vehicles, and basic items for hydrogen system safety. Final examination of the fuel supply system interface for liquid hydrogen vehicles, and the specification of hydrogen fuel was finished, and these are scheduled to be registered for ISO. (NEDO)

  4. Hydrogen as automotive fuel

    International Nuclear Information System (INIS)

    Ambrosini, G.; Ciancia, A.; Pede, G.; Brighigna, M.

    1993-01-01

    Hydrogen fueled vehicles may just be the answer to the air pollution problem in highly polluted urban environments where the innovative vehicle's air pollution abatement characteristics would justify its high operating costs as compared with those of conventional automotive alternatives. This paper examines the feasibility of hydrogen as an automotive fuel by analyzing the following aspects: the chemical-physical properties of hydrogen in relation to its use in internal combustion engines; the modifications necessary to adapt internal combustion engines to hydrogen use; hydrogen fuel injection systems; current production technologies and commercialization status of hydrogen automotive fuels; energy efficiency ratings; environmental impacts; in-vehicle storage systems - involving the use of hydrides, high pressure systems and liquid hydrogen storage systems; performance in terms of pay-load ratio; autonomous operation; and operating costs. With reference to recent trial results being obtained in the USA, an assessment is also made of the feasibility of the use of methane-hydrogen mixtures as automotive fuels. The paper concludes with a review of progress being made by ENEA (the Italian Agency for New Technology, Energy and the Environment) in the development of fuel storage and electronic fuel injection systems for hydrogen powered vehicles

  5. Hydrogen as automotive fuel

    International Nuclear Information System (INIS)

    Dini, D.; Ciancia, A.; Pede, G.; Sglavo, V.; ENEA, Rome

    1992-01-01

    An assessment of the technical/economic feasibility of the use of hydrogen as an automotive fuel is made based on analyses of the following: the chemical- physical properties of hydrogen in relation to its use in internal combustion engines; the modifications necessary to adapt internal combustion engines to hydrogen use; hydrogen fuel injection systems - with water vapour injection, cryogenic injection, and the low or high pressure injection of hydrogen directly into the combustion chamber; the current commercialization status of hydrogen automotive fuels; energy efficiency ratings; environmental impacts; in-vehicle storage systems - involving the use of hydrides, high pressure systems and liquid hydrogen storage systems; performance in terms of pay-load ratio; autonomous operation; and operating costs. The paper concludes that, considering current costs for hydrogen fuel production, distribution and use, at present, the employment of hydrogen fuelled vehicles is feasible only in highly polluted urban environments where the innovative vehicle's air pollution abatement characteristics would justify its high operating costs as compared with those of conventional automotive alternatives

  6. Three Gaseous Neurotransmitters, Nitric oxide, Carbon Monoxide, and Hydrogen Sulfide, Are Involved in the Neurogenic Relaxation Responses of the Porcine Internal Anal Sphincter.

    Science.gov (United States)

    Folasire, Oladayo; Mills, Kylie A; Sellers, Donna J; Chess-Williams, Russ

    2016-01-31

    The internal anal sphincter (IAS) plays an important role in maintaining continence and a number of neurotransmitters are known to regulate IAS tone. The aim of this study was to determine the relative importance of the neurotransmitters involved in the relaxant and contractile responses of the porcine IAS. Responses of isolated strips of IAS to electrical field stimulation (EFS) were obtained in the absence and presence of inhibitors of neurotransmitter systems. Contractile responses of the sphincter to EFS were unaffected by the muscarinic receptor antagonist, atropine (1 μM), but were almost completely abolished by the adrenergic neuron blocker guanethidine (10 μM). Contractile responses were also reduced (by 45% at 5 Hz, P 40-50% reduction), zinc protoprophyrin IX (10 μM), an inhibitor of carbon monoxide synthesis (20-40% reduction), and also propargylglycine (30 μM) and aminooxyacetic acid (30 μM), inhibitors of hydrogen sulphide synthesis (15-20% reduction). Stimulation of IAS efferent nerves releases excitatory and inhibitory neurotransmitters: noradrenaline is the predominant contractile transmitter with a smaller component from ATP, whilst 3 gases mediate relaxation responses to EFS, with the combined contributions being nitric oxide > carbon monoxide > hydrogen sulfide.

  7. Global Assessment of Hydrogen Technologies - Task 1 Report Technology Evaluation of Hydrogen Light Duty Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan Andrew J.; Rousseau, Aymeric

    2007-12-01

    This task analyzes the candidate hydrogen-fueled vehicles for near-term use in the Southeastern U.S. The purpose of this work is to assess their potential in terms of efficiency and performance. This report compares conventional, hybrid electric vehicles (HEV) with gasoline and hydrogen-fueled internal combustion engines (ICEs) as well as fuel cell and fuel cell hybrids from a technology as well as fuel economy point of view. All the vehicles have been simulated using the Powertrain System Analysis Toolkit (PSAT). First, some background information is provided on recent American automotive market trends and consequences. Moreover, available options are presented for introducing cleaner and more economical vehicles in the market in the future. In this study, analysis of various candidate hydrogen-fueled vehicles is performed using PSAT and, thus, a brief description of PSAT features and capabilities are provided. Detailed information on the simulation analysis performed is also offered, including methodology assumptions, fuel economic results, and conclusions from the findings.

  8. U.S. Department of Energy FreedomCar & Vehicle Technologies Program CARB Executive Order Exemption Process for a Hydrogen-fueled Internal Combustion engine Vehicle -- Status Report

    Energy Technology Data Exchange (ETDEWEB)

    2008-04-01

    The CARB Executive Order Exemption Process for a Hydrogen-fueled Internal Combustion Engine Vehicle was undertaken to define the requirements to achieve a California Air Resource Board Executive Order for a hydrogenfueled vehicle retrofit kit. A 2005 to 2006 General Motors Company Sierra/Chevrolet Silverado 1500HD pickup was assumed to be the build-from vehicle for the retrofit kit. The emissions demonstration was determined not to pose a significant hurdle due to the non-hydrocarbon-based fuel and lean-burn operation. However, significant work was determined to be necessary for Onboard Diagnostics Level II compliance. Therefore, it is recommended that an Experimental Permit be obtained from the California Air Resource Board to license and operate the vehicles for the durability of the demonstration in support of preparing a fully compliant and certifiable package that can be submitted.

  9. Contact behavior analysis of elastomeric x-ring under uniform squeeze rate and internal pressure before and after forcing-out using the photoelastic experimental hybrid method

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, Alunda Ouma [Dedan Kimathi University of Technology, Nyeri (Kenya); Hawong, Jai Sug; Dong, Bai [Yeungnam University, Gyeongsan (Korea, Republic of); Shin, Dong Chul [Koje College, Geoje (Korea, Republic of)

    2015-05-15

    Many different types of elastomeric rings have been developed to suit various needs in industry. The X-ring was introduced as a result of the limitations of O-rings that twist, especially during dynamic application. A better understanding of the behavior and the stress distribution of the X-ring under a uniform squeeze rate and internal pressure is needed. We analyzed the contact stresses and internal stresses developed in an X-ring before and after forcing-out by using the photoelastic experimental hybrid method, ascertained the packing ability of an X-ring, and studied the failure criterion of an X-ring under uniform squeeze rate and internal pressure. Forcing-out in the X-ring occurred when the internal pressure was 3.92 MPa. After forcing-out, at an internal pressure of 5.88 MPa, the two lobes on the upper contact surface merged one contact side of the upper side immensely. Even after extrusion of the X-ring, the X-ring can be used to effectively contain the fluid. This is because the effects of extrusion on the X-ring affected the stress distribution of only two lobes close to the assembly gap and the two lobes are merge into one lobe. In addition, our experimental results show that the maximum shear failure criterion is suitable for the prediction of failure in X-ring seals.

  10. Canadian hydrogen safety program

    International Nuclear Information System (INIS)

    MacIntyre, I.; Tchouvelev, A.V.; Hay, D.R.; Wong, J.; Grant, J.; Benard, P.

    2007-01-01

    The Canadian hydrogen safety program (CHSP) is a project initiative of the Codes and Standards Working Group of the Canadian transportation fuel cell alliance (CTFCA) that represents industry, academia, government, and regulators. The Program rationale, structure and contents contribute to acceptance of the products, services and systems of the Canadian Hydrogen Industry into the Canadian hydrogen stakeholder community. It facilitates trade through fair insurance policies and rates, effective and efficient regulatory approval procedures and accommodation of the interests of the general public. The Program integrates a consistent quantitative risk assessment methodology with experimental (destructive and non-destructive) failure rates and consequence-of-release data for key hydrogen components and systems into risk assessment of commercial application scenarios. Its current and past six projects include Intelligent Virtual Hydrogen Filling Station (IVHFS), Hydrogen clearance distances, comparative quantitative risk comparison of hydrogen and compressed natural gas (CNG) refuelling options; computational fluid dynamics (CFD) modeling validation, calibration and enhancement; enhancement of frequency and probability analysis, and Consequence analysis of key component failures of hydrogen systems; and fuel cell oxidant outlet hydrogen sensor project. The Program projects are tightly linked with the content of the International Energy Agency (IEA) Task 19 Hydrogen Safety. (author)

  11. A prototype experiment to study charmed particle production and decay using a Holographic High Resolution Hydrogen Chamber (HOLEBC) and the European Hybrid Spectrometer

    CERN Multimedia

    2002-01-01

    The high resolution hydrogen bubble chamber LEBC has already been used in experiments at the SPS to detect particles with lifetime $\\geq 5 \\times 10^{-13}$s (NA13 & NA16). \\\\\\\\For this experiment, a new version of LEBC called HOLEBC, has been constructed. This chamber and the NA26 version of the spectrometer have been used with classical optics in the NA27 experiment. A significant improvement in resolution was achieved ($\\simeq$ 20 microns compared with $\\simeq$ 40 $\\mu$m in LEBC) and hence a good sensitivity to all (known) charmed particle decays. The development of holographic recording techniques with HOLEBC is in progress. \\\\\\\\The prototype NA26 experiment is designed to evaluate the feasibility of the high sensitivity, high resolution holographic hydrogen bubble chamber technique and evaluate various possible charm selective triggers using the information from the spectrometer.

  12. Utilizing a CdTe quantum dots-enzyme hybrid system for the determination of both phenolic compounds and hydrogen peroxide.

    Science.gov (United States)

    Yuan, Jipei; Guo, Weiwei; Wang, Erkang

    2008-02-15

    In this paper, we attempt to construct a simple and sensitive detection method for both phenolic compounds and hydrogen peroxide, with the successful combination of the unique property of quantum dots and the specificity of enzymatic reactions. In the presence of H2O2 and horseradish peroxidase, phenolic compounds can quench quantum dots' photoluminescence efficiently, and the extent of quenching is severalfold to more than 100-fold increase. Quinone intermediates produced from the enzymatic catalyzed oxidation of phenolic compounds were believed to play the main role in the photoluminescence quenching. Using a quantum dots-enzyme system, the detection limits for phenolic compounds and hydrogen peroxide were detected to be approximately 10(-7) mol L(-1). The coupling of efficient quenching of quantum dot photoluminescence by quinone and the effective enzymatic reactions make this a simple and sensitive method for phenolic compound detection and great potential in the development of H2O2 biosensors for various analytes.

  13. Nuclear hydrogen production: re-examining the fusion option

    International Nuclear Information System (INIS)

    Baindur, S.

    2007-01-01

    This paper describes a scheme for nuclear hydrogen production by fusion. The basic idea is to use nuclear energy of the fuel (hydrogen plasma) to produce molecular hydrogen fro carbon-free hydrogen compounds. The hydrogen is then stored and utilized electrochemically in fuel cells or chemically as molecular hydrogen in internal combustion engines

  14. Hydrogen sensor

    Science.gov (United States)

    Duan, Yixiang; Jia, Quanxi; Cao, Wenqing

    2010-11-23

    A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

  15. A fluorogenic molecular nanoprobe with an engineered internal environment for sensitive and selective detection of biological hydrogen sulfide.

    Science.gov (United States)

    Kim, Myung; Seo, Young Hun; Kim, Youngsun; Heo, Jeongyun; Jang, Woo-Dong; Sim, Sang Jun; Kim, Sehoon

    2017-02-14

    A nanoreactor approach based on the amphiphilic assembly of various molecules offers a chance to finely engineer the internal reaction medium to enable highly selective and sensitive detection of H 2 S in biological media, being useful for microscopic imaging of cellular processes and in vitro diagnostics with blood samples.

  16. Hydrogen, energy of the future?

    International Nuclear Information System (INIS)

    Alleau, Th.

    2007-01-01

    A cheap, non-polluting energy with no greenhouse gas emissions and unlimited resources? This is towards this fantastic future that this book brings us, analyzing the complex but promising question of hydrogen. The scientific and technical aspects of production, transport, storage and distribution raised by hydrogen are thoroughly reviewed. Content: I) Energy, which solutions?: 1 - hydrogen, a future; 2 - hydrogen, a foreseeable solution?; II) Hydrogen, an energy vector: 3 - characteristics of hydrogen (physical data, quality and drawbacks); 4 - hydrogen production (from fossil fuels, from water, from biomass, bio-hydrogen generation); 5 - transport, storage and distribution of hydrogen; 6 - hydrogen cost (production, storage, transport and distribution costs); III) Fuel cells and ITER, utopias?: 7 - molecular hydrogen uses (thermal engines and fuel cells); 8 - hydrogen and fusion (hydrogen isotopes, thermonuclear reaction, ITER project, fusion and wastes); IV) Hydrogen acceptability: 9 - risk acceptability; 10 - standards and regulations; 11 - national, European and international policies about hydrogen; 12 - big demonstration projects in France and in the rest of the world; conclusion. (J.S.)

  17. HYBRID VEHICLE CONTROL SYSTEM

    Directory of Open Access Journals (Sweden)

    V. Dvadnenko

    2016-06-01

    Full Text Available The hybrid vehicle control system includes a start–stop system for an internal combustion engine. The system works in a hybrid mode and normal vehicle operation. To simplify the start–stop system, there were user new possibilities of a hybrid car, which appeared after the conversion. Results of the circuit design of the proposed system of basic blocks are analyzed.

  18. A Critical Study of Stationary Energy Storage Policies in Australia in an International Context: The Role of Hydrogen and Battery Technologies

    Directory of Open Access Journals (Sweden)

    Jason Moore

    2016-08-01

    Full Text Available This paper provides a critical study of current Australian and leading international policies aimed at supporting electrical energy storage for stationary power applications with a focus on battery and hydrogen storage technologies. It demonstrates that global leaders such as Germany and the U.S. are actively taking steps to support energy storage technologies through policy and regulatory change. This is principally to integrate increasing amounts of intermittent renewable energy (wind and solar that will be required to meet high renewable energy targets. The relevance of this to the Australian energy market is that whilst it is unique, it does have aspects in common with the energy markets of these global leaders. This includes regions of high concentrations of intermittent renewable energy (Texas and California and high penetration rates of residential solar photovoltaics (PV (Germany. Therefore, Australian policy makers have a good opportunity to observe what is working in an international context to support energy storage. These learnings can then be used to help shape future policy directions and guide Australia along the path to a sustainable energy future.

  19. THEN-2: The 2nd COE-INES international workshop on 'toward hydrogen economy; what nuclear can contribute and how'. Proposal and presentations

    International Nuclear Information System (INIS)

    2006-01-01

    The workshop of the title was held on topics; nuclear hydrogen system in cooperation with other non-nuclear energy systems related with hydrogen production, storage and transportation, and synthesized fuel productions, hydrogen energy management and economy, consisted of 3 keynote lectures and 4 topical sessions by 15 presenters and a panel discussion session. (J.P.N.)

  20. Hail hydrogen

    International Nuclear Information System (INIS)

    Hairston, D.

    1996-01-01

    After years of being scorned and maligned, hydrogen is finding favor in environmental and process applications. There is enormous demand for the industrial gas from petroleum refiners, who need in creasing amounts of hydrogen to remove sulfur and other contaminants from crude oil. In pulp and paper mills, hydrogen is turning up as hydrogen peroxide, displacing bleaching agents based on chlorine. Now, new technologies for making hydrogen have the industry abuzz. With better capabilities of being generated onsite at higher purity levels, recycled and reused, hydrogen is being prepped for a range of applications, from waste reduction to purification of Nylon 6 and hydrogenation of specialty chemicals. The paper discusses the strong market demand for hydrogen, easier routes being developed for hydrogen production, and the use of hydrogen in the future

  1. Fiscal 2000 report on the Phase II R and D of the international hydrogen utilization clean energy network system technology (WE-NET). Task 3. Survey and research on international cooperation - 1 (Promotion of international cooperation); 2000 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dai 2 ki kenkyu kaihatsu seika hokokusho. 3. Kokusai kyoryoku ni kansuru chosa kenkyu - 1 (kokusai kyoryoku suishin no tame no chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    International research cooperation was promoted and technical information was internationally exchanged for the development of the International Clean Energy Network Using Hydrogen Conversion (WE-NET) Project into a truly international cooperation project. In the promotion of international research cooperation, a collection of summarized achievement reports for fiscal 1999 translated into English, based on achievement reports on the respective tasks, was disseminated to 157 related organizations overseas. Activities related to the WE-NET Project were actively presented at international conferences. For research cooperation at IEA (International Energy Agency), engineers were dispatched to its committees and annexes specializing in hydrogen related implementation agreements. In the international exchange of technical information, overseas surveys were conducted for fulfilling the purposes of the respective WE-NET tasks. Investigations were conducted into the latest fuel cell development status across the world, not to mention the automotive fuel cell now attracting earnest attention. Moreover, surveys were conducted of hydrogen energy related research institutes abroad, and a Japanese booth was installed at Hyforum 2000 (The International Hydrogen Energy Forum 2000). (NEDO)

  2. Kicking the habit[Hydrogen fuel

    Energy Technology Data Exchange (ETDEWEB)

    Jones, N.; Lawton, G.; Pearce, F.

    2000-11-25

    This article focuses on the use of clean non-polluting hydrogen fuel as opposed to the use of fossil fuels which ties western nations to the Middle East. Details are given of Iceland's plans to use hydrogen fuelled buses, cars, trucks and trawlers, car manufacturers' options of using internal combustion engines burning hydrogen and hydrogen fuel cells, and the production of hydrogen using electrolysis of water and steam reforming of hydrocarbons. The 'Green Dream' of pollution-free hydrogen production, the use of solar energy for renewable hydrogen production in California, and problems associated with hydrogen storage are discussed.

  3. Controlled etching of internal and external structures of SiO2 nanoparticles using hydrogen bond of polyelectrolytes.

    Science.gov (United States)

    Islam, Md Shahinul; Choi, Won San; Lee, Ha-Jin

    2014-06-25

    We have demonstrated a novel strategy for the synthesis of mesoporous silica nanoparticles (MSNPs) using a surfactant-free method under ambient conditions. By the simple addition of an amine-based polymer (polyethylenimine; PEI) with a high molecular weight to a silica nanoparticle (SNP) solution, two types of MSNPs, including rambutan-like MSNPs (R-MSNPs) and hollow MSNPs (H-MSNPs), were produced. The structural changes of the MSNPs were systematically studied using various reaction conditions (reaction time, molar ratio and molecular weight of PEI, etc.) and were observed using electron microscopic techniques. The formation mechanisms of both MSNPs were carefully investigated using XPS, Raman, and IR spectroscopies. Because the synthesized MSNPs are highly porous materials that contain internal organic/inorganic networks, we investigated the removal/adsorption properties of these MSNPs with respect to pollutants toward possible future use in environmental remediation applications. The H-MSNPs exhibited better environmental remediation capabilities relative to the R-MSNPs because PEI is present between the cobweb-like internal structures of the H-MSNPs, thereby providing a significant number of reaction sites for the adsorption of pollutants. The approach presented here can also be used as a direct method for the preparation of intraconnected networks within the substructures.

  4. Photovoltaic hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Hiser, H.W.; Memory, S.B.; Veziroglu, T.N.; Padin, J. [Univ. of Miami, Coral Gables, FL (United States)

    1996-10-01

    This is a new project, which started in June 1995, and involves photovoltaic hydrogen production as a fuel production method for the future. In order to increase the hydrogen yield, it was decided to use hybrid solar collectors to generate D.C. electricity, as well as high temperature steam for input to the electrolyzer. In this way, some of the energy needed to dissociate the water is supplied in the form of heat (or low grade energy), to generate steam, which results in a reduction of electrical energy (or high grade energy) needed. As a result, solar to hydrogen conversion efficiency is increased. In the above stated system, the collector location, the collector tracking sub-system (i.e., orientation/rotation), and the steam temperature have been taken as variables. Five locations selected - in order to consider a variety of latitudes, altitudes, cloud coverage and atmospheric conditions - are Atlanta, Denver, Miami, Phoenix and Salt Lake City. Plain PV and hybrid solar collectors for a stationary south facing system and five different collector rotation systems have been analyzed. Steam temperatures have been varied between 200{degrees}C and 1200{degrees}C. During the first year, solar to hydrogen conversion efficiencies have been considered. The results show that higher steam temperatures, 2 dimensional tracking system, higher elevations and dryer climates causes higher conversion efficiencies. Cost effectiveness of the sub-systems and of the overall system will be analyzed during the second year. Also, initial studies will be made of an advanced high efficiency hybrid solar hydrogen production system.

  5. Biomimetic hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Krassen, Henning

    2009-05-15

    . To accomplish tight binding of both proteins the PS1 subunit PsaE was genetically fused to the C-terminal end of the small subunit of MBH, i.e. close to the electron acceptor site of MBH. This fusion protein spontaneously assembled with the PsaE-deletion mutant of PS1. Crucial for a high hydrogen evolution rate of the system is an efficient electron transfer between both proteins. To allow this measurement, the PsaE-deletion mutant of PS1 was immobilized on a Ni-NTAterminated monolayer via a genetically introduced His-tag. The specificity of the assembly of fusion protein and deletion mutant was verified by SEIRAS. Surface plasmon resonance, gas chromatography and electrochemistry complemented this measurement and yielded the specific activity of the functional hybrid complex: 4500 mol H{sub 2} min{sup -1} mol{sup -1}. The investigated complex allowed hydrogen evolution at potentials up to 85 mV, i.e. hydrogen production at a lower energy level than on a platinum electrode. In addition, the hydrogen production rate was higher than for hydrogenase-modified electrodes without PS1. Beyond these specific results, the experimental setup can be used to quantify the hydrogen evolution rate on a molecular level for variable hydrogenases and hybrid complexes. This information will be used to choose the most efficient catalysts for introduction into the native system for in vivo hydrogen production. (orig.)

  6. Fiscal 2000 report on the Phase II R and D of the international hydrogen utilization clean energy network system technology (WE-NET). Task 11. Distributed transportation of hydrogen/hydrogen absorbing alloy for hydrogen storage; 2000 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dai 2 ki kenkyu kaihatsu seika hokokusho. 11. Suiso bunsan yuso chozoyo suiso kyuzo gokin

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Studies were conducted to find out hydrogen absorbing alloys with an effective hydrogen absorption rate of 3 mass % or more, hydrogen discharge temperature of 100 degrees C or lower, hydrogen absorbing capacity after 5,000 cycles not less than 90% of the initial capacity, applicable to stationary and mobile systems. The V-based alloy that achieved an effective hydrogen absorption rate of 2.6 mass % in the preceding fiscal year was subjected to studies relating to safety and durability. Since V is costly, efforts were exerted to develop TiCrMo alloys to replace the V-based alloy. In the search for novel high-performance alloys, endeavors centered on novel ternary alloys, novel alloys based on Mg and Ti, and novel intermetallic compounds of the Mg-4 family. In the study of guidelines for developing next-generation high-performance alloys, methods for creating hydrides with an H/M (hydrogen/metal) ratio far higher than 2 were discussed. Mentioned as techniques to produce such hydrides were the utilization of the hole regulated lattice, novel alloys based on the ultrahigh pressure hydride phase, new substances making use of the cooperative phenomenon in the coexistent multiple-phase structure, and the like. (NEDO)

  7. Fabrication of the heterostructured CsTaWO{sub 6}/Au/g-C{sub 3}N{sub 4} hybrid photocatalyst with enhanced performance of photocatalytic hydrogen production from water

    Energy Technology Data Exchange (ETDEWEB)

    Lang, Junyu; Liu, Mengqing; Su, Yiguo; Yan, Lijuan; Wang, Xiaojing, E-mail: wang_xiao_jing@hotmail.com

    2015-12-15

    Graphical abstract: - Highlights: • A novel ternary CsTaWO{sub 6}/Au/g-C{sub 3}N{sub 4} hybrid photocatalyst was successfully fabricated. • Au particles act as an electron-conduction bridge between the heterostructure. • The photoctalytic hydrogen generation was promoted by the SPR of the Au. • CsTaWO{sub 6}/Au/g-C{sub 3}N{sub 4} shows significant photocatalytic activity in H{sub 2} generation. - Abstract: In this work, a novel CsTaWO{sub 6}/Au/g-C{sub 3}N{sub 4} hybrid photocatalyst is successfully fabricated. The photocatalytic performance of the heterostructured CsTaWO{sub 6}/Au/g-C{sub 3}N{sub 4} composite was investigated. Au nanoparticles were photo-deposited as the interlayer between g-C{sub 3}N{sub 4} and the surface of CsTaWO{sub 6}, which can facilitate the photoinduced electrons migration as an electron-conduction bridge as well as increase visible-light absorption via the surface plasmon resonance. This heterostructured interface bridging by Au particles may significantly retard the recombination of electron–holes, which is beneficial to promote the photocatalytic activity under visible-light irradiation. It is found the CsTaWO{sub 6}/Au/g-C{sub 3}N{sub 4} sample showed excellent photocatalytic activity of water splitting, even higher than the sum of g-C{sub 3}N{sub 4} and Au/CsTaWO{sub 6} samples, or the sum of CsTaWO{sub 6} and Au/g-C{sub 3}N{sub 4} samples. It indicates that the heterostructured combination of g-C{sub 3}N{sub 4} and CsTaWO{sub 6} bridging by Au particles provided the synergistic photocatalytic activity driving by solar light through an efficient electron transfer process.

  8. NOSH–aspirin (NBS-1120), a novel nitric oxide- and hydrogen sulfide-releasing hybrid is a potent inhibitor of colon cancer cell growth in vitro and in a xenograft mouse model

    International Nuclear Information System (INIS)

    Chattopadhyay, Mitali; Kodela, Ravinder; Olson, Kenneth R.; Kashfi, Khosrow

    2012-01-01

    Highlights: ► NOSH–aspirin is the first dual acting NO and H 2 S releasing hybrid. ► Its IC 50 for cell growth inhibition is in the low nano-molar range. ► Structure–activity studies show that the sum of the parts does not equal the whole. ► NOSH–aspirin reduced tumor growth by 85% in mice bearing a colon cancer xenograft. -- Abstract: Nonsteroidal anti-inflammatory drugs (NSAIDs) are prototypical anti-cancer agents. However, their long-term use is associated with adverse gastrointestinal effects. Recognition that endogenous gaseous mediators, nitric oxide (NO) and hydrogen sulfide (H 2 S) can increase mucosal defense mechanisms has led to the development of NO- and H 2 S-releasing NSAIDs with increased safety profiles. Here we report on a new hybrid, NOSH–aspirin, which is an NO- and H 2 S-releasing agent. NOSH–aspirin inhibited HT-29 colon cancer growth with IC 50 s of 45.5 ± 2.5, 19.7 ± 3.3, and 7.7 ± 2.2 nM at 24, 48, and 72 h, respectively. This is the first NSAID based agent with such high degree of potency. NOSH–aspirin inhibited cell proliferation, induced apoptosis, and caused G 0 /G 1 cell cycle block. Reconstitution and structure–activity studies representing a fairly close approximation to the intact molecule showed that NOSH–aspirin was 9000-fold more potent than the sum of its parts towards growth inhibition. NOSH–aspirin inhibited ovine COX-1 more than ovine COX-2. NOSH–ASA treatment of mice bearing a human colon cancer xenograft caused a reduction in volume of 85%. Taken together, these results demonstrate that NOSH–aspirin has strong anti-cancer potential and merits further evaluation.

  9. Highly efficient hydrogen evolution based on Ni3S4@MoS2 hybrids supported on N-doped reduced graphene oxide

    Science.gov (United States)

    Xu, Xiaobing; Zhong, Wei; Wu, Liqian; Sun, Yuan; Wang, Tingting; Wang, Yuanqi; Du, Youwei

    2018-01-01

    Hydrogen evolution reaction (HER) through water splitting at low overpotential is an appealing technology to produce renewable energy, wherein the design of stable electrocatalysts is very critical. To achieve optimal electrochemical performance, a highly efficient and stable noble-metal-free HER catalyst is synthesized by means of a facile hydrothermal co-synthesis. It consists of Ni3S4 nanosheets and MoS2 nanolayers supported on N-doped reduced graphene oxide (Ni3S4/MoS2@N-rGO). The optimized sample provides a large amount of active sites that benefit electron transfer in 3D conductive networks. Thanks to the strong synergistic effect in the catalyst network, we achieved a low overpotential of 94 mV, a small Tafel slope of 56 mV/dec and remarkable durability in an acidic medium.

  10. FY 1998 annual summary report on International Clean Energy Network Using Hydrogen Conversion (WE-NET) system technology. Subtask 2. Examination and promotion of measures to obtain international understanding and cooperation; 1998 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET) subtask 2 (kokusai kyoryoku shuishin no tame no chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Described herein are the results of examination and promotion of measures to obtain international understanding and cooperation, and examination and development of measures to promote international exchange of technical information, conducted in the FY 1998 continuously from the previous year, with the object to realize the International Clean Energy Network Using Hydrogen Conversion (WE-NET) project. In the FY 1998, the English version of the 1997 annual summary report was distributed to a total of about 150 overseas organizations. The WE-NET project activities were presented to the 12th World Hydrogen Energy Conference, International Joint Power Generation Conference held in 1998 by American Society of Mechanical Engineers, and 2nd International Symposium on Advanced Energy Conversion Systems and Related Technologies. For the examination and development of measures to promote international exchange of technical information, the contracting party of Japan for the Hydrogen Implementation Agreement with IEA has been shifted from the government of Japan to NEDO. NEDO has been representing Japan for various workshops on the tasks. The hydrogen projects conducted by Germany and USA were also surveyed. The WE-NET project homepage was opened in June, 1998. (NEDO)

  11. Hydrogen detector

    International Nuclear Information System (INIS)

    Kumagaya, Hiromichi; Yoshida, Kazuo; Sanada, Kazuo; Chigira, Sadao.

    1994-01-01

    The present invention concerns a hydrogen detector for detecting water-sodium reaction. The hydrogen detector comprises a sensor portion having coiled optical fibers and detects hydrogen on the basis of the increase of light transmission loss upon hydrogen absorption. In the hydrogen detector, optical fibers are wound around and welded to the outer circumference of a quartz rod, as well as the thickness of the clad layer of the optical fiber is reduced by etching. With such procedures, size of the hydrogen detecting sensor portion can be decreased easily. Further, since it can be used at high temperature, diffusion rate is improved to shorten the detection time. (N.H.)

  12. Hydrogen - From hydrogen to energy production

    International Nuclear Information System (INIS)

    Klotz, Gregory

    2005-01-01

    More than a century ago, Jules Verne wrote in 'The Mysterious Island' that water would one day be employed as fuel: 'Hydrogen and oxygen, which constitute it, used singly or together, will furnish an inexhaustible source of heat and light'. Today, the 'water motor' is not entirely the dream of a writer. Fiction is about to become fact thanks to hydrogen, which can be produced from water and when burned in air itself produces water. Hydrogen is now at the heart of international research. So why do we have such great expectations of hydrogen? 'Hydrogen as an energy system is now a major challenge, both scientifically and from an environmental and economic point of view'. Dominated as it is by fossil fuels (oil, gas and coal), our current energy system has left a dual threat hovering over our environment, exposing the planet to the exhaustion of its natural reserves and contributing to the greenhouse effect. If we want sustainable development for future generations, it is becoming necessary to diversify our methods of producing energy. Hydrogen is not, of course, a source of energy, because first it has to be produced. But it has the twofold advantage of being both inexhaustible and non-polluting. So in the future, it should have a very important role to play. (author)

  13. Fiscal 1999 hydrogen utilization international clean energy system technology (WE-NET). Phase 2 R and D (Task 3) -research/study concerning international cooperation (Volume 1. research/study for promoting international cooperation); 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu. Task 3. Kokusai kyoryoku ni kansuru chosa kenkyu (1. kokusai kyoryoku suishin no tame no chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Various measures were implemented with the aim of realizing the 'longterm vision for international cooperation' in connection with hydrogen utilization international clean energy system technology (WE-NET) formulated in fiscal 1996. The English version of the 1998 annual summary report on results was distributed to approximately 170 pertinent organizations overseas. To develop understanding of the WE-NET project, presentations were given in numerous international conferences. In addition, as research cooperation in IEA (International Energy Agency), specialists were dispatched to the hydrogen implementation committee, the corresponding committee to hydrogen implementation agreement, and to each annex. In international exchange of technical information, each WE-NET task exchanged information with organizations abroad through overseas survey and conducted research on European hydrogen project, for example. With the purpose of developing understanding of WE-NET project activities, a preparatory work was done for participation in HYFORUM2000 (Germany) and World Hydrogen Energy Conference (Beijing) which will be held in 2000. (NEDO)

  14. A novel usage of hydrogen treatment to improve the indium incorporation and internal quantum efficiency of green InGaN/GaN multiple quantum wells simultaneously

    International Nuclear Information System (INIS)

    Ren, Peng; Zhang, Ning; Xue, Bin; Liu, Zhe; Wang, Junxi; Li, Jinmin

    2016-01-01

    The challenge for improving the internal quantum efficiency (IQE) of InGaN-based light emitting diodes (LED) in the green light range is referred to as the ‘green gap’. However the IQE of InGaN-based LEDs often drops when the emission peak wavelength is adjusted through reducing the growth temperature. Although hydrogen (H 2 ) can improve surface morphology, it reduces the indium incorporation significantly. Here, a novel usage of H 2 treatment on the GaN barrier before the InGaN quantum well is demonstrated to enhance indium incorporation efficiency and improve the IQE simultaneously for the first time. The mechanism behind it is systematically investigated and explained in detail. The possible reason for this phenomenon is the strain relieving function by the undulant GaN barrier surface after H 2 treatment. Test measurements show that applying 0.2 min H 2 treatment on the barrier would reduce defects and enhance indium incorporation, which would improve the localization effect and finally lead to a higher IQE. Although further increasing the treatment time to 0.4 min incorporates more indium atoms, the IQE decreases at the expense of more defects and a larger polarization field than the 0.2 min sample. (paper)

  15. Treatment of nanofiltration concentrates of mature landfill leachate by a coupled process of coagulation and internal micro-electrolysis adding hydrogen peroxide.

    Science.gov (United States)

    Huang, Jingang; Chen, Jianjun; Xie, Zhengmiao; Xu, Xiaojun

    2015-01-01

    In this study, a coupled process of coagulation and aerated internal micro-electrolysis (IME) with the in situ addition of hydrogen peroxide (H2O2) was investigated for the treatment of nanofiltration (NF) concentrate from mature landfill leachate. The acceptable operating conditions were determined as follows: initial pH 4, polymeric aluminium chloride dosage of 525 mg-Al2O3/L in the coagulation process, H2O2 dosage of 0.75 mM and an hydraulic retention time of 2 h in an aerated IME reactor. As a result, the removal efficiencies for chemical oxygen demand (COD), total organic carbon, UV254 and colour were 79.2%, 79.6%, 81.8% and 90.8%, respectively. In addition, the ratio of biochemical oxygen demand (BOD5)/COD in the final effluent increased from 0.03 to 0.31, and that of E2/E4 from 12.4 to 38.5, respectively. The results indicate that the combined process is an effective and economical way to remove organic matters and to improve the biodegradability of the NF concentrate. Coagulation process reduces the adverse impact of high-molecular-weight organic matters such as humic acids, on the aerated IME process. A proper addition of H2O2 in the aerated IME can promote the corrosion of solid iron (Fe2+/Fe3+) and cause a likely domino effect in the enhancement of removal efficiencies.

  16. Production of hydrogen driven from biomass waste to power Remote areas away from the electric grid utilizing fuel cells and internal combustion engines vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Tawfik, Hazem [Farmingdale State College, NY (United States)

    2017-03-10

    Recent concerns over the security and reliability of the world’s energy supply has caused a flux towards the research and development of renewable sources. A leading renewable source has been found in the biomass gasification of biological materials derived from organic matters such as wood chips, forest debris, and farm waste that are found in abundance in the USA. Accordingly, there is a very strong interest worldwide in the development of new technologies that provide an in-depth understanding of this economically viable energy source. This work aims to allow the coupling of biomass gasification and fuel cell systems as well as Internal Combustion Engines (ICE) to produce high-energy efficiency, clean environmental performance and near-zero greenhouse gas emissions. Biomass gasification is a process, which produces synthesis gas (syngas) that contains 19% hydrogen and 20% carbon monoxide from inexpensive organic matter waste. This project main goal is to provide cost effective energy to the public utilizing remote farms’ waste and landfill recycling area.

  17. Analyses on interaction of internal and external surface cracks in a pressurized cylinder by hybrid boundary element method

    International Nuclear Information System (INIS)

    Chai Guozhong; Fang Zhimin; Jiang Xianfeng; Li Gan

    2004-01-01

    This paper presents a comprehensive range of analyses on the interaction of two identical semi-elliptical surface cracks at the internal and external surfaces of a pressurized cylinder. The considered ratios of the crack depth to crack length are b/a=0.25, 0.5, 0.75 and 1.0; the ratios of the crack depth to wall thickness of the cylinder are 2b/t=0.2, 0.4, 0.6, 0.7 and 0.8. Forty crack configurations are analyzed and the stress intensity factors along the crack front are presented. The numerical results show that for 2b/t<0.7, the interaction leads to a decrease in the stress intensity factors for both internal and external surface cracks, compared with a single internal or external surface crack. Thus for fracture analysis of a practical pressurized cylinder with two identical semi-elliptical surface cracks at its internal and external surfaces, a conservative result is obtained by ignoring the interaction

  18. Internal nitrogen removal from sediments by the hybrid system of microbial fuel cells and submerged aquatic plants.

    Directory of Open Access Journals (Sweden)

    Peng Xu

    Full Text Available Sediment internal nitrogen release is a significant pollution source in the overlying water of aquatic ecosystems. This study aims to remove internal nitrogen in sediment-water microcosms by coupling sediment microbial fuel cells (SMFCs with submerged aquatic plants. Twelve tanks including four treatments in triplicates were designed: open-circuit (SMFC-o, closed-circuit (SMFC-c, aquatic plants with open-circuit (P-SMFC-o and aquatic plants with closed-circuit (P-SMFC-c. The changes in the bio-electrochemical characteristics of the nitrogen levels in overlying water, pore water, sediments, and aquatic plants were documented to explain the migration and transformation pathways of internal nitrogen. The results showed that both electrogenesis and aquatic plants could facilitate the mineralization of organic nitrogen in sediments. In SMFC, electrogenesis promoted the release of ammonium from the pore water, followed by the accumulation of ammonium and nitrate in the overlying water. The increased redox potential of sediments due to electrogenesis also contributed to higher levels of nitrate in overlying water when nitrification in pore water was facilitated and denitrification at the sediment-water interface was inhibited. When the aquatic plants were introduced into the closed-circuit SMFC, the internal ammonium assimilation by aquatic plants was advanced by electrogenesis; nitrification in pore water and denitrification in sediments were also promoted. These processes might result in the maximum decrease of internal nitrogen with low nitrogen levels in the overlying water despite the lower power production. The P-SMFC-c reduced 8.1%, 16.2%, 24.7%, and 25.3% of internal total nitrogen compared to SMFC-o on the 55th, 82th, 136th, and 190th days, respectively. The smaller number of Nitrospira and the larger number of Bacillus and Pseudomonas on the anodes via high throughput sequencing may account for strong mineralization and denitrification in the

  19. Hydrogen highway

    International Nuclear Information System (INIS)

    Anon

    2008-01-01

    The USA Administration would like to consider the US power generating industry as a basis ensuring both the full-scale production of hydrogen and the widespread use of the hydrogen related technological processes into the economy [ru

  20. NOSH-aspirin (NBS-1120), a novel nitric oxide- and hydrogen sulfide-releasing hybrid is a potent inhibitor of colon cancer cell growth in vitro and in a xenograft mouse model.

    Science.gov (United States)

    Chattopadhyay, Mitali; Kodela, Ravinder; Olson, Kenneth R; Kashfi, Khosrow

    2012-03-16

    Nonsteroidal anti-inflammatory drugs (NSAIDs) are prototypical anti-cancer agents. However, their long-term use is associated with adverse gastrointestinal effects. Recognition that endogenous gaseous mediators, nitric oxide (NO) and hydrogen sulfide (H(2)S) can increase mucosal defense mechanisms has led to the development of NO- and H(2)S-releasing NSAIDs with increased safety profiles. Here we report on a new hybrid, NOSH-aspirin, which is an NO- and H(2)S-releasing agent. NOSH-aspirin inhibited HT-29 colon cancer growth with IC(50)s of 45.5 ± 2.5, 19.7 ± 3.3, and 7.7 ± 2.2 nM at 24, 48, and 72 h, respectively. This is the first NSAID based agent with such high degree of potency. NOSH-aspirin inhibited cell proliferation, induced apoptosis, and caused G(0)/G(1) cell cycle block. Reconstitution and structure-activity studies representing a fairly close approximation to the intact molecule showed that NOSH-aspirin was 9000-fold more potent than the sum of its parts towards growth inhibition. NOSH-aspirin inhibited ovine COX-1 more than ovine COX-2. NOSH-ASA treatment of mice bearing a human colon cancer xenograft caused a reduction in volume of 85%. Taken together, these results demonstrate that NOSH-aspirin has strong anti-cancer potential and merits further evaluation. Copyright © 2012 Elsevier Inc. All rights reserved.

  1. Fiscal 1997 survey report. Subtask 2 (hydrogen utilization worldwide clean energy system technology) (WE-NET) (survey/study for the promotion of international cooperation; survey/study on the standardization for hydrogen energy technology); 1997 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET) subtask 2 kokusai kyoryoku suishin no tame no chosa kento (suiso energy gijutsu hyojunka ni kansuru chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In relation to the basic study of the standardization for hydrogen energy technology and ISO/TC197, the results of the fiscal 1997 survey were summarized. From fiscal 1994 through 1996, in the wide-range field related to hydrogen energy technology, the survey of the present situation of the related standards/laws was made and the needs/subjects of standardization to be studied in the future were extracted. At the present stage, however, it is still early to enter into the stage of discussing the standardization. Therefore, in this fiscal year, only in the field of the storage/transportation/handling of liquid hydrogen, standards/laws abroad and in Japan were comparatively investigated for the basic study toward the standardization. Further, concerning ISO/TC197, studies were proceeded with of the liquid hydrogen land vehicle fueling system interface/fuel tanks/transportation containers/hydrogen fuel product specifications/airport hydrogen fueling facilities. Some are at the stage of drafting the international standard. Three drafts for the new standard were added such as gaseous hydrogen/hydrogen blend vehicular fuel systems, gaseous hydrogen fuel tanks, and basic requirements for safety of hydrogen systems. The standardization is indispensable to introducing the developed technology to the commercialization. 9 refs., 5 figs., 13 tabs.

  2. Fiscal 1997 survey report on a feasibility of international collaboration on bio-hydrogen R and D; 1997 nendo chosa hokokusho (bio suiso seizo gijutsu ni kakawaru kokusai kyoryoku kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    R and D of the production technology of biohydrogen is an option effective for the world energy supply technology and the world environmental preservation technology in the 21st century. At present, a project named `R and D of the environment harmony type hydrogen production technology` tackles the R and D of the hydrogen production technology using photosynthetic microorganisms, and promotes the R and D in this field from both aspects of a basis and application as seen in a workshop held including interchanges with researchers and research institutes overseas. With the recently increasing interest in bio-hydrogen production technology also overseas, search and bleeding/improvement of microorganisms related to the hydrogen production and utilization technology of biomass have been advancing. For development in this field, it is necessary to construct a widespread research network and promote the comprehensive research and development. In this survey, most of the research institutes visited recognized an importance of international cooperation in this field and agreed to make future research interchanges in a wide range. Based on the survey, a feasibility of concrete international collaboration is searched. 146 refs., 2 figs., 11 tabs.

  3. Hydrogen damage in stainless steel

    International Nuclear Information System (INIS)

    Caskey, G.R. Jr.

    1981-01-01

    Hydrogen damage has been studied in a wide variety of stainless steels. Both internal and external hydrogen damage were evaluated by ductility or J-integral under rising tensile loads and by fractography. Analysis of the data has emphasized the potential effects of strain-induced martensite on hydrogen damage. Strain-induced martensite was neither necessary nor sufficient for hydrogen damage in the alloys studied. Neither ductility loss nor fracture-mode change correlated generally with martensite formation. Alloy composition, particularly nickel and nitrogen contents, was the primary factor in resistance to hydrogen damage. Thermomechanical processing, however, could alter the degree of hydrogen damage in an alloy and was critical for optimizing resistance to hydrogen damage. 10 figures, 10 tables

  4. In-situ experimental characterization of the clamping pressure effects on low temperature polymer electrolyte membrane electrolysis International Journal of Hydrogen Energy

    DEFF Research Database (Denmark)

    Al Shakhshir, Saher; Cui, Xiaoti; Frensch, Steffen Henrik

    2017-01-01

    as a gas with the circulating water. The effects of clamping pressure (Pc) on the LT-PEME cell performance, polarization resistances, and hydrogen and water crossover through the membrane, and hydrogen and oxygen production rate are studied. A 50 cm2 active area LT-PEME cell designed and manufactured......-PEME splits water into hydrogen and oxygen when the voltage is applied between anode and cathode. Electrical current forces the positively charged ions to migrate to negatively charged cathode through PEM, where hydrogen is produced. Meanwhile, oxygen is produced at the anode side electrode and escapes...... in house is utilized in this work. Higher Pc has shown higher cell performance this refers to lower ohmic and activation resistances. Water crossover from anode to cathode is slightly decreased at higher Pc resulting in a slight decrease in hydrogen crossover from cathode to anode. Also, the percentage...

  5. Hydrogen economy

    Energy Technology Data Exchange (ETDEWEB)

    Pahwa, P.K.; Pahwa, Gulshan Kumar

    2013-10-01

    In the future, our energy systems will need to be renewable and sustainable, efficient and cost-effective, convenient and safe. Hydrogen has been proposed as the perfect fuel for this future energy system. The availability of a reliable and cost-effective supply, safe and efficient storage, and convenient end use of hydrogen will be essential for a transition to a hydrogen economy. Research is being conducted throughout the world for the development of safe, cost-effective hydrogen production, storage, and end-use technologies that support and foster this transition. This book discusses hydrogen economy vis-a-vis sustainable development. It examines the link between development and energy, prospects of sustainable development, significance of hydrogen energy economy, and provides an authoritative and up-to-date scientific account of hydrogen generation, storage, transportation, and safety.

  6. Hydrogen perspectives in Japan

    International Nuclear Information System (INIS)

    Furutani, H.

    2000-01-01

    Hydrogen energy is considered to present a potential effective options for achieving the greenhouse gas minimization. The MITI (Ministry of International Trade and Industry) of Japanese Government is promoting the WE-NET (World Energy Network System) Project which envisions (1) construction of a global energy network for effective supply, transportation, storage and utilization of renewable energy using hydrogen as an energy carrier as a long-term options of sustainable energy economy, and (2) promotion of market entry of hydrogen energy in near and/or mid future even before construction of a WE-NET system. In this paper, I would like to report how far the hydrogen energy technology development addressed under Phase I has progressed, and describe the outline of the Phase II Plan. (author)

  7. Photoelectrochemical hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Rocheleau, R.E.; Miller, E.; Misra, A. [Univ. of Hawaii, Honolulu, HI (United States)

    1996-10-01

    The large-scale production of hydrogen utilizing energy provided by a renewable source to split water is one of the most ambitious long-term goals of the U.S. Department of Energy`s Hydrogen Program. One promising option to meet this goal is direct photoelectrolysis in which light absorbed by semiconductor-based photoelectrodes produces electrical power internally to split water into hydrogen and oxygen. Under this program, direct solar-to-chemical conversion efficiencies as high as 7.8 % have been demonstrated using low-cost, amorphous-silicon-based photoelectrodes. Detailed loss analysis models indicate that solar-to-chemical conversion greater than 10% can be achieved with amorphous-silicon-based structures optimized for hydrogen production. In this report, the authors describe the continuing progress in the development of thin-film catalytic/protective coatings, results of outdoor testing, and efforts to develop high efficiency, stable prototype systems.

  8. Hydrogen safety

    International Nuclear Information System (INIS)

    Frazier, W.R.

    1991-01-01

    The NASA experience with hydrogen began in the 1950s when the National Advisory Committee on Aeronautics (NACA) research on rocket fuels was inherited by the newly formed National Aeronautics and Space Administration (NASA). Initial emphasis on the use of hydrogen as a fuel for high-altitude probes, satellites, and aircraft limited the available data on hydrogen hazards to small quantities of hydrogen. NASA began to use hydrogen as the principal liquid propellant for launch vehicles and quickly determined the need for hydrogen safety documentation to support design and operational requirements. The resulting NASA approach to hydrogen safety requires a joint effort by design and safety engineering to address hydrogen hazards and develop procedures for safe operation of equipment and facilities. NASA also determined the need for rigorous training and certification programs for personnel involved with hydrogen use. NASA's current use of hydrogen is mainly for large heavy-lift vehicle propulsion, which necessitates storage of large quantities for fueling space shots and for testing. Future use will involve new applications such as thermal imaging

  9. NOSH-aspirin (NBS-1120), a novel nitric oxide- and hydrogen sulfide-releasing hybrid is a potent inhibitor of colon cancer cell growth in vitro and in a xenograft mouse model

    Energy Technology Data Exchange (ETDEWEB)

    Chattopadhyay, Mitali; Kodela, Ravinder [Department of Physiology, Pharmacology, and Neuroscience, Sophie Davis School of Biomedical Education, City University of New York Medical School, New York, NY 10031 (United States); Olson, Kenneth R. [Department of Physiology, Indiana University School of Medicine, South Bend, IN 46617 (United States); Kashfi, Khosrow, E-mail: kashfi@med.cuny.edu [Department of Physiology, Pharmacology, and Neuroscience, Sophie Davis School of Biomedical Education, City University of New York Medical School, New York, NY 10031 (United States)

    2012-03-16

    Highlights: Black-Right-Pointing-Pointer NOSH-aspirin is the first dual acting NO and H{sub 2}S releasing hybrid. Black-Right-Pointing-Pointer Its IC{sub 50} for cell growth inhibition is in the low nano-molar range. Black-Right-Pointing-Pointer Structure-activity studies show that the sum of the parts does not equal the whole. Black-Right-Pointing-Pointer NOSH-aspirin reduced tumor growth by 85% in mice bearing a colon cancer xenograft. -- Abstract: Nonsteroidal anti-inflammatory drugs (NSAIDs) are prototypical anti-cancer agents. However, their long-term use is associated with adverse gastrointestinal effects. Recognition that endogenous gaseous mediators, nitric oxide (NO) and hydrogen sulfide (H{sub 2}S) can increase mucosal defense mechanisms has led to the development of NO- and H{sub 2}S-releasing NSAIDs with increased safety profiles. Here we report on a new hybrid, NOSH-aspirin, which is an NO- and H{sub 2}S-releasing agent. NOSH-aspirin inhibited HT-29 colon cancer growth with IC{sub 50}s of 45.5 {+-} 2.5, 19.7 {+-} 3.3, and 7.7 {+-} 2.2 nM at 24, 48, and 72 h, respectively. This is the first NSAID based agent with such high degree of potency. NOSH-aspirin inhibited cell proliferation, induced apoptosis, and caused G{sub 0}/G{sub 1} cell cycle block. Reconstitution and structure-activity studies representing a fairly close approximation to the intact molecule showed that NOSH-aspirin was 9000-fold more potent than the sum of its parts towards growth inhibition. NOSH-aspirin inhibited ovine COX-1 more than ovine COX-2. NOSH-ASA treatment of mice bearing a human colon cancer xenograft caused a reduction in volume of 85%. Taken together, these results demonstrate that NOSH-aspirin has strong anti-cancer potential and merits further evaluation.

  10. The Italian hydrogen programme

    International Nuclear Information System (INIS)

    Raffaele Vellone

    2001-01-01

    Hydrogen could become an important option in the new millennium. It provides the potential for a sustainable energy system as it can be used to meet most energy needs without harming the environment. In fact, hydrogen has the potential for contributing to the reduction of climate-changing emissions and other air pollutants as it exhibits clean combustion with no carbon or sulphur oxide emissions and very low nitrogen oxide emissions. Furthermore, it is capable of direct conversion to electricity in systems such as fuel cells without generating pollution. However, widespread use of hydrogen is not feasible today because of economic and technological barriers. In Italy, there is an ongoing national programme to facilitate the introduction of hydrogen as an energy carrier. This programme aims to promote, in an organic frame, a series of actions regarding the whole hydrogen cycle. It foresees the development of technologies in the areas of production, storage, transport and utilisation. Research addresses the development of technologies for separation and sequestration of CO 2 , The programme is shared by public organisations (research institutions and universities) and national industry (oil companies, electric and gas utilities and research institutions). Hydrogen can be used as a fuel, with significant advantages, both for electric energy generation/ co-generation (thermo-dynamic cycles and fuel cells) and transportation (internal combustion engine and fuel cells). One focus of research will be the development of fuel cell technologies. Fuel cells possess all necessary characteristics to be a key technology in a future economy based on hydrogen. During the initial phase of the project, hydrogen will be derived from fossil sources (natural gas), and in the second phase it will be generated from renewable electricity or nuclear energy. The presentation will provide a review of the hydrogen programme and highlight future goals. (author)

  11. Hydrogen Embrittlement

    Science.gov (United States)

    Woods, Stephen; Lee, Jonathan A.

    2016-01-01

    Hydrogen embrittlement (HE) is a process resulting in a decrease in the fracture toughness or ductility of a metal due to the presence of atomic hydrogen. In addition to pure hydrogen gas as a direct source for the absorption of atomic hydrogen, the damaging effect can manifest itself from other hydrogen-containing gas species such as hydrogen sulfide (H2S), hydrogen chloride (HCl), and hydrogen bromide (HBr) environments. It has been known that H2S environment may result in a much more severe condition of embrittlement than pure hydrogen gas (H2) for certain types of alloys at similar conditions of stress and gas pressure. The reduction of fracture loads can occur at levels well below the yield strength of the material. Hydrogen embrittlement is usually manifest in terms of singular sharp cracks, in contrast to the extensive branching observed for stress corrosion cracking. The initial crack openings and the local deformation associated with crack propagation may be so small that they are difficult to detect except in special nondestructive examinations. Cracks due to HE can grow rapidly with little macroscopic evidence of mechanical deformation in materials that are normally quite ductile. This Technical Memorandum presents a comprehensive review of experimental data for the effects of gaseous Hydrogen Environment Embrittlement (HEE) for several types of metallic materials. Common material screening methods are used to rate the hydrogen degradation of mechanical properties that occur while the material is under an applied stress and exposed to gaseous hydrogen as compared to air or helium, under slow strain rates (SSR) testing. Due to the simplicity and accelerated nature of these tests, the results expressed in terms of HEE index are not intended to necessarily represent true hydrogen service environment for long-term exposure, but rather to provide a practical approach for material screening, which is a useful concept to qualitatively evaluate the severity of

  12. Sustainability assessment of a hybrid energy system

    International Nuclear Information System (INIS)

    Afgan, Nain H.; Carvalho, Maria G.

    2008-01-01

    A hybrid energy system in the form of the Object structure is the pattern for the structure of options in the evaluation of a hybrid system. The Object structure is defined as: Hybrid Energy System {[production (solar, wind, biomass, natural gas)] [utilization(electricity, heat, hydrogen)]}. In the evaluation of hybrid energy systems only several options are selected to demonstrate the sustainability assessment method application in the promotion of the specific quality of the hybrid energy system. In this analysis the following options are taken into a consideration: 1.Solar photo-voltaic power plant (PV PP), wind turbine power plant (WTPP) biomass thermal power plant (ThSTPP) for electricity, heat and hydrogen production. 2.Solar PV PP and wind power plant (WPP) for electricity and hydrogen production. 3.Biomass thermal steam turbine power plant (BThSTPP) and WPP for heat and hydrogen production. 4.Combined cycle gas turbine power plant for electricity and hydrogen production. 5.Cogeneration of electricity and water by the hybrid system. The sustainability assessment method is used for the evaluation of quality of the selected hybrid systems. In this evaluation the following indicators are used: economic indicator, environment indicator and social indicator

  13. Research and development in second term of hydrogen utilizing international clean energy system technology (WE-NET) in fiscal 1999. Task 2. Hydrogen absorbing alloys for discrete hydrogen transportation and storage; 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu. Task 11. Suiso bunsan yuso chozoyo suiso kyuzo gokin

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Developmental researches have been performed on hydrogen absorbing alloys intended to be applied to stationary and moving objects. This paper summarizes the achievements in fiscal 1999. As a method for evaluating effective hydrogen absorption amount, proposals were made on definition and measuring method for effective hydrogen absorption amount assuming hydrogen absorption at 20 degrees C, and 10 and 30 atmospheric pressures, and hydrogen discharge at 100 degrees C and one atmospheric pressure. In the research of an Mg-Ni based alloy, the Mg based alloy having the Laves composition, treated by mechanical grinding was found to discharge hydrogen of 0.2 to 0.35% by mass at 423K. This discharge temperature is the lowest among the Mg based alloys having been developed to date. In the research of the V based hydrogen absorbing alloy, the V-Ti-Cr-Mn alloy was developed successfully that discharges hydrogen of 2.64% by mass when hydrogen absorbed at 273 K and 3.3 MPa is discharged at 373 K and 0.01 MPa. Furthermore, development has been made on the V-Ti-Cr-Mn-Ni alloy that shows high effective hydrogen absorption amount without being treated by heat. This alloy has as high effective hydrogen absorption amount as 2.47% by mass under the above described conditions. (NEDO)

  14. NOSH-aspirin (NBS-1120), a novel nitric oxide- and hydrogen sulfide-releasing hybrid has enhanced chemo-preventive properties compared to aspirin, is gastrointestinal safe with all the classic therapeutic indications

    Science.gov (United States)

    Kodela, Ravinder; Chattopadhyay, Mitali; Velázquez-Martínez, Carlos A.; Kashfi, Khosrow

    2015-01-01

    Aspirin is chemopreventive; however, side effects preclude its long-term use. NOSH-aspirin (NBS-1120), a novel hybrid that releases nitric oxide and hydrogen sulfide, was designed to be a safer alternative. Here we compare the gastrointestinal safety, anti-inflammatory, analgesic, antipyretic, anti-platelet, and chemopreventive properties of aspirin and NBS-1120 administered orally to rats at equimolar doses. Gastrointestinal safety: 6h post-administration, the number and size of hemorrhagic lesions in stomachs were counted; tissue samples were frozen for PGE2, SOD, and MDA determination. Anti-inflammatory: 1h after drug administration, the volume of carrageenan-induced rat paw edemas was measured for 5h. Anti-pyretic: fever was induced by LPS (ip) an hour before administration of the test drugs, core body temperature was measured hourly for 5h. Analgesic: time-dependent analgesic effects were evaluated by carrageenan-induced hyperalgesia. Antiplatelet: anti-aggregatory effects were studied on collagen-induced platelet aggregation of human platelet-rich plasma. Chemoprevention: Nude mice were gavaged daily for 25 days with vehicle, aspirin or NBS-1120. After one week, each mouse was inoculated subcutaneously in the right flank with HT-29 human colon cancer cells. Both agents reduced PGE2 levels in stomach tissue; however, NBS-1120 did not cause any stomach ulcers, whereas aspirin caused significant bleeding. Lipid peroxidation induced by aspirin was higher than that exerted by NBS-1120. SOD activity was significantly inhibited by aspirin but increased by NBS-1120. Both agents showed similar anti-inflammatory, analgesic, anti-pyretic, and anti-platelet activities. Aspirin increased plasma TNFα more than NBS-1120-treated animals. NBS-1120 was better than aspirin as a chemopreventive agent; it dose-dependently inhibited tumor growth and tumor mass. PMID:26394025

  15. Reduced Graphene Oxide-Hybridized Polymeric High-Internal Phase Emulsions for Highly Efficient Removal of Polycyclic Aromatic Hydrocarbons from Water Matrix.

    Science.gov (United States)

    Huang, Yipeng; Zhang, Wenjuan; Ruan, Guihua; Li, Xianxian; Cong, Yongzheng; Du, Fuyou; Li, Jianping

    2018-03-27

    Reduced graphene oxide (RGO)-hybridized polymeric high-internal phase emulsions (RGO/polyHIPEs) with an open-cell structure and hydrophobicity have been successfully prepared using 2-ethylhexyl acrylate and ethylene glycol dimethacrylate as the monomer and the cross-linker, respectively. The adsorption mechanism and performance of this RGO/polyHIPEs to polycyclic aromatic hydrocarbons (PAHs) were investigated. Adsorption isotherms of PAHs on RGO/polyHIPEs show that the saturated adsorption capacity is 47.5 mg/g and the equilibrium time is 8 h. Cycling tests show that the adsorption capacity of RGO/polyHIPEs remains stable in 10 adsorption-desorption cycles without observable structure change in RGO/polyHIPEs. Moreover, the PAH residues in water samples after being purified by RGO/polyHIPEs are lower than the limit values in drinking water set by the European Food Safety Authority. These results demonstrate that the RGO/polyHIPEs have great potentiality in PAH removal and water purification.

  16. Hybrid Bloch brane

    Energy Technology Data Exchange (ETDEWEB)

    Bazeia, D.; Lima, Elisama E.M.; Losano, L. [Universidade Federal da Paraiba, Departamento de Fisica, Joao Pessoa, PB (Brazil)

    2017-02-15

    This work reports on models described by two real scalar fields coupled with gravity in the five-dimensional spacetime, with a warped geometry involving one infinite extra dimension. Through a mechanism that smoothly changes a thick brane into a hybrid brane, one investigates the appearance of hybrid branes hosting internal structure, characterized by the splitting on the energy density and the volcano potential, induced by the parameter which controls interactions between the two scalar fields. In particular, we investigate distinct symmetric and asymmetric hybrid brane scenarios. (orig.)

  17. International Collaboration on bio-hydrogen R and D. Report for the Research Institute of Innovative Technology for the Earth (RITE), Tokyo, Japan

    Energy Technology Data Exchange (ETDEWEB)

    Huesing, B.

    1998-01-01

    In order to solve the problem of the foreseeable depletion of fossil energy resources and of expected global climatic changes due to the emission of greenhouse gases future energy systems are required which meet the growing world energy demand but do not depend on fossil fuels. One possible option which is discussed as a clean and environmentally friendly energy source for the 21{sup st} century is the conversion of solar energy into hydrogen. Hydrogen as an environmentally friendly energy source can also be an integral part of a zero-emission economy because it can contribute to the minimization of toxic dispersion (especially the greenhouse gas CO{sub 2}) and to the maximization of sustainable use of renewable resources. It has been known for more than 50 years that certain living organisms are able to produce hydrogen. Biological hydrogen production has several comparative advantages over competing hydrogen production technologies such as photovoltaic or solarthermic electricity generation plus water hydrolysis. These advantages are - simpler systems: hydrogen production from direct water splitting without involvement of electricity/electrolysis, - self-regenerating systems, - biologically degradable systems: disposal can be coupled to the production of additional value-added substances, - flexible systems: production organisms can adapt to changing environmental conditions, - versatile systems: production organisms which are tailor-made to special environmental conditions can be selected. (orig.)

  18. Hydrogen Village : creating hydrogen and fuel cell communities

    International Nuclear Information System (INIS)

    Smith, G.R.

    2009-01-01

    The Hydrogen Village (H2V) is a collaborative public-private partnership administered through Hydrogen and Fuel Cells Canada and funded by the Governments of Canada and Ontario. This end user-driven, market development program accelerates the commercialization of hydrogen and fuel cell (FC) technologies throughout the Greater Toronto Area (GTA). The program targets 3 specific aspects of market development, notably deployment of near market technologies in community based stationary and mobile applications; development of a coordinated hydrogen delivery and equipment service infrastructure; and societal factors involving corporate policy and public education. This presentation focused on lessons learned through outreach programs and the deployment of solid oxide fuel cell (SOFC) heat and power generation; indoor and outdoor fuel cell back up power systems; fuel cell-powered forklifts, delivery vehicles, and utility vehicles; hydrogen internal combustion engine powered shuttle buses, sedans, parade float; hydrogen production/refueling stations in the downtown core; and temporary fuel cell power systems

  19. International

    International Nuclear Information System (INIS)

    Anon.

    1997-01-01

    This rubric reports on 10 short notes about international economical facts about nuclear power: Electricite de France (EdF) and its assistance and management contracts with Eastern Europe countries (Poland, Hungary, Bulgaria); Transnuclear Inc. company (a 100% Cogema daughter company) acquired the US Vectra Technologies company; the construction of the Khumo nuclear power plant in Northern Korea plays in favour of the reconciliation between Northern and Southern Korea; the delivery of two VVER 1000 Russian reactors to China; the enforcement of the cooperation agreement between Euratom and Argentina; Japan requested for the financing of a Russian fast breeder reactor; Russia has planned to sell a floating barge-type nuclear power plant to Indonesia; the control of the Swedish reactor vessels of Sydkraft AB company committed to Tractebel (Belgium); the renewal of the nuclear cooperation agreement between Swiss and USA; the call for bids from the Turkish TEAS electric power company for the building of the Akkuyu nuclear power plant answered by three candidates: Atomic Energy of Canada Limited (AECL), Westinghouse (US) and the French-German NPI company. (J.S.)

  20. Hydrogen isotope technology

    International Nuclear Information System (INIS)

    Anon.

    1980-01-01

    Hydrogen pumping speeds on panels of molecular sieve types 5A and Na-Y were compared for a variety of sieve (and chevron) temperatures between 10 and 30 K. Although pumping speeds declined with time, probably because of the slow diffusion of hydrogen from the surface of the sieve crystals into the internal regions, the different sieve materials and operating conditions could be compared using time-averaged pump speeds. The (average) pumping speeds declined with increasing temperature. Under some conditions, the Na-Y sieve performed much better than the 5A sieve. Studies of the effect of small concentrations (approx. 4%) of hydrogen on helium pumping indicate that compound cryopumps in fusion reactors will not have to provide complete screening of hydrogen from helium panels. The concentrations of hydrogen did not lower effective helium pumping speeds or shorten the helium operating period between instabilities. Studies of tritium recovery from blankets of liquid lithium focused on design and construction of a flowing-lithium test system and on ultimate removal of tritium from yttrium sorbents. At 505 0 C, tritium release from yttrium behaves as a diffusion-controlled process, but the release rates are very low. Apparently, higher temperatures will be required for effective sorbent regeneration. An innovative technique for separating hydrogen isotopes by using bipolar electrolysis with permeable electrodes was analyzed to determine its potential usefulness in multistage separation

  1. Hybrid and plug-in hybrid electric vehicle performance testing by the US Department of Energy Advanced Vehicle Testing Activity

    Science.gov (United States)

    Karner, Donald; Francfort, James

    The Advanced Vehicle Testing Activity (AVTA), part of the U.S. Department of Energy's FreedomCAR and Vehicle Technologies Program, has conducted testing of advanced technology vehicles since August 1995 in support of the AVTA goal to provide benchmark data for technology modeling, and vehicle development programs. The AVTA has tested full size electric vehicles, urban electric vehicles, neighborhood electric vehicles, and hydrogen internal combustion engine powered vehicles. Currently, the AVTA is conducting baseline performance, battery benchmark and fleet tests of hybrid electric vehicles (HEV) and plug-in hybrid electric vehicles (PHEV). Testing has included all HEVs produced by major automotive manufacturers and spans over 2.5 million test miles. Testing is currently incorporating PHEVs from four different vehicle converters. The results of all testing are posted on the AVTA web page maintained by the Idaho National Laboratory.

  2. Internal combustion engine report: Spark ignited ICE GenSet optimization and novel concept development

    Energy Technology Data Exchange (ETDEWEB)

    Keller, J.; Blarigan, P. Van [Sandia National Labs., Livermore, CA (United States)

    1998-08-01

    In this manuscript the authors report on two projects each of which the goal is to produce cost effective hydrogen utilization technologies. These projects are: (1) the development of an electrical generation system using a conventional four-stroke spark-ignited internal combustion engine generator combination (SI-GenSet) optimized for maximum efficiency and minimum emissions, and (2) the development of a novel internal combustion engine concept. The SI-GenSet will be optimized to run on either hydrogen or hydrogen-blends. The novel concept seeks to develop an engine that optimizes the Otto cycle in a free piston configuration while minimizing all emissions. To this end the authors are developing a rapid combustion homogeneous charge compression ignition (HCCI) engine using a linear alternator for both power take-off and engine control. Targeted applications include stationary electrical power generation, stationary shaft power generation, hybrid vehicles, and nearly any other application now being accomplished with internal combustion engines.

  3. Hydrogen exchange

    DEFF Research Database (Denmark)

    Jensen, Pernille Foged; Rand, Kasper Dyrberg

    2016-01-01

    Hydrogen exchange (HX) monitored by mass spectrometry (MS) is a powerful analytical method for investigation of protein conformation and dynamics. HX-MS monitors isotopic exchange of hydrogen in protein backbone amides and thus serves as a sensitive method for probing protein conformation...... and dynamics along the entire protein backbone. This chapter describes the exchange of backbone amide hydrogen which is highly quenchable as it is strongly dependent on the pH and temperature. The HX rates of backbone amide hydrogen are sensitive and very useful probes of protein conformation......, as they are distributed along the polypeptide backbone and form the fundamental hydrogen-bonding networks of basic secondary structure. The effect of pressure on HX in unstructured polypeptides (poly-dl-lysine and oxidatively unfolded ribonuclease A) and native folded proteins (lysozyme and ribonuclease A) was evaluated...

  4. Hydrogen energy stations: along the roadside to the hydrogen economy

    International Nuclear Information System (INIS)

    Clark, W.W.; Rifkin, J.; O'Connor, T.; Swisher, J.; Lipman, T.; Rambach, G.

    2005-01-01

    Hydrogen has become more than an international topic of discussion within government and among industry. With the public announcements from the European Union and American governments and an Executive Order from the Governor of California, hydrogen has become a ''paradigm change'' targeted toward changing decades of economic and societal behaviours. The public demand for clean and green energy as well as being ''independent'' or not located in political or societal conflict areas, has become paramount. The key issues are the commitment of governments through public policies along with corporations. Above all, secondly, the advancement of hydrogen is regional as it depends upon infrastructure and fuel resources. Hence, the hydrogen economy, to which the hydrogen highway is the main component, will be regional and creative. New jobs, businesses and opportunities are already emerging. And finally, the costs for the hydrogen economy are critical. The debate as to hydrogen being 5 years away from being commercial and available in the marketplace versus needing more research and development contradicts the historical development and deployment of any new technology be it bio-science, flat panel displays, computers or mobile phones. The market drivers are government regulations and standards soon thereafter matched by market forces and mass production. Hydrogen is no different. What this paper does is describes is how the hydrogen highway is the backbone to the hydrogen economy by becoming, with the next five years, both regional and commercial through supplying stationary power to communities. Soon thereafter, within five to ten years, these same hydrogen stations will be serving hundreds and then thousands of hydrogen fuel powered vehicles. Hydrogen is the fuel for distributed energy generation and hence positively impacts the future of public and private power generators. The paradigm has already changed. (author)

  5. Gravity Modes Reveal the Internal Rotation of a Post-mass-transfer Gamma Doradus/Delta Scuti Hybrid Pulsator in Kepler Eclipsing Binary KIC 9592855

    Science.gov (United States)

    Guo, Z.; Gies, D. R.; Matson, R. A.

    2017-12-01

    We report the discovery of a post-mass-transfer Gamma Doradus/Delta Scuti hybrid pulsator in the eclipsing binary KIC 9592855. This binary has a circular orbit, an orbital period of 1.2 days, and contains two stars of almost identical masses ({M}1=1.72 {M}⊙ ,{M}2=1.71 {M}⊙ ). However, the cooler secondary star is more evolved ({R}2=1.96 {R}⊙ ), while the hotter primary is still on the zero-age-main-sequence ({R}1=1.53 {R}⊙ ). Coeval models from single-star evolution cannot explain the observed masses and radii, and binary evolution with mass-transfer needs to be invoked. After subtracting the binary light curve, the Fourier spectrum shows low-order pressure-mode pulsations, and more dominantly, a cluster of low-frequency gravity modes at about 2 day-1. These g-modes are nearly equally spaced in period, and the period spacing pattern has a negative slope. We identify these g-modes as prograde dipole modes and find that they stem from the secondary star. The frequency range of unstable p-modes also agrees with that of the secondary. We derive the internal rotation rate of the convective core and the asymptotic period spacing from the observed g-modes. The resulting values suggest that the core and envelope rotate nearly uniformly, i.e., their rotation rates are both similar to the orbital frequency of this synchronized binary.

  6. Hydrogen utilization international clean energy system technology (WE-NET). Subtask 8. Research and development of hydrogen combustion turbines (development of ultra-high temperature materials); Suiso riyo kokusai clean energy system (WE-NET). Subtask 8. Suiso nensho turbine no kenkyu kaihatsu chokoon zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The paper described the result of the fiscal 1996 development of ultra-high temperature materials for parts of hydrogen combustion turbines, as part of the hydrogen utilization technology, which have excellent environmental protectivity and remarkably high efficiency. By the optimized solution heat treatment of monocrystal alloy developed in the previous fiscal year, obtained was strength property the same as the existing super alloys. As to FRC, pore size and strength property of SiC organic hybrid were made clear. ODS alloy cooling blades and heat insulation coating were studied, and YSZ was found to be most excellent as coating material. Concerning intermetallic compounds, the applicability to ultra-high temperatures up to 1700degC was not obtained. For improvement of heat resistance and environment resistance, adopted were highly compacting SiC matrix and BN coatings. Al2O3 was excellent in long-time stability. In the 1600degC steam corrosion test on multiplex structural materials with Al2O3 as surface material, chemical stability was confirmed. Three-dimensional woven fiber reinforced composite materials of C/C{center_dot}CMC were trially produced by changing the fiber orientation, and improvement in ultra-high temperature thermal shock resistance was confirmed. A study was made of spot observation of the specimen surface by laser microscope, and development was conducted of a temperature measuring method with no influence of radiant heat. 44 refs., 250 figs., 40 tabs.

  7. Hydrogen utilization international clean energy system technology (WE-NET). Subtask 8. Development of hydrogen combustion turbines (development of the main component devices such as turbine blades and rotors); Suiso riyo kokusai clean energy system gijutsu (WE-NET). Subtask 8. Suiso nensho turbine no kaihatsu (turbine yoku, rotor nado shuyo kosei kiki no kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The paper described the result of the fiscal 1996 development relating to hydrogen combustion turbines, as one of the hydrogen utilization technologies, which have excellent environmentality and are expected of remarkably high efficiency. In the film cooling system of first-stage moving/stationary blades, the smaller the pitch of film pore is, the higher the mean cooling efficiency becomes, indicating 0.7 at maximum. As compared with the conventional shower head type, the metal temperature can be reduced 30-40degC. In the recovery type inner (convection) cooling system, by reducing the blade number, the consumption amount of coolant can be reduced 6% in stationary blade and 13% in moving blade, as compared with the result of the preceding year. In the element test of the hybrid cooling system, film cooling efficiency was actually measured by the porous module test equipment, and the result well agreed with the calculation result. In the water cooling system, studied were water (stationary blade) and vapor (moving blade) of the closed cooling structure for realization of a cycle efficiency of 60%. In rotor/disk cooling, analyses were made of seal characteristic grasp tests and characteristics of the rotor. The effect of deflection in the mainstream was small. Besides, proper value of the seal overlapping amount could be obtained. 6 refs., 368 figs., 55 tabs.

  8. Hydrogen in energy transition

    International Nuclear Information System (INIS)

    2016-02-01

    This publication proposes a rather brief overview of challenges related to the use of hydrogen as an energy vector in the fields of transports and of energy storage to valorise renewable energies. Processes (steam reforming of natural gas or bio-gas, alkaline or membrane electrolysis, biological production), installation types (centralised or decentralised), raw materials and/or energy (natural gas, water, bio-gas, electricity, light), and their respective industrial maturity are indicated. The role of hydrogen to de-carbonate different types of transports is described (complementary energy for internal combustion as well as electrical vehicles) as well as its role in the valorisation and integration of renewable energies. The main challenges faced by the hydrogen sector are identified and discussed, and actions undertaken by the ADEME are indicated

  9. Surveys and researches on trends of technologies related to hydrogen; Suiso ni kansuru gijutsu doko chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1983-03-01

    This report covers surveys of the latest technological trends in relation to the production, storage, and transportation of hydrogen as energy. Also included in the report are surveys of hydrogen, fuel cells, and wind energy centering about Europe. At the 4th World Hydrogen Energy Conference (Pasadena, U.S., June 1982), a number of essays were presented concerning the utilization of hydrogen, production of hydrogen, thermochemical processes, hybrid processes, photochemical processes, photo/thermochemical processes, other processes, fuel cells, metallic hydrides, etc. This report particularly describes in detail the trends of technologies involving the production of hydrogen by the electrolysis of water and by thermochemical processes. As for the recent trend of the metallic hydride technology, reports are made on the International Symposium on the Properties and Applications of Metal Hydrides (Toba, Japan, June 1982) and on Japan's research on the application of metallic hydrides. Concerning the trends in Europe of technologies relative to hydrogen, fuel cells, and wind energy, the results of the research group's on-site investigations are reported. (NEDO)

  10. Surveys and researches on trends of technologies related to hydrogen; Suiso ni kansuru gijutsu doko chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1983-03-01

    This report covers surveys of the latest technological trends in relation to the production, storage, and transportation of hydrogen as energy. Also included in the report are surveys of hydrogen, fuel cells, and wind energy centering about Europe. At the 4th World Hydrogen Energy Conference (Pasadena, U.S., June 1982), a number of essays were presented concerning the utilization of hydrogen, production of hydrogen, thermochemical processes, hybrid processes, photochemical processes, photo/thermochemical processes, other processes, fuel cells, metallic hydrides, etc. This report particularly describes in detail the trends of technologies involving the production of hydrogen by the electrolysis of water and by thermochemical processes. As for the recent trend of the metallic hydride technology, reports are made on the International Symposium on the Properties and Applications of Metal Hydrides (Toba, Japan, June 1982) and on Japan's research on the application of metallic hydrides. Concerning the trends in Europe of technologies relative to hydrogen, fuel cells, and wind energy, the results of the research group's on-site investigations are reported. (NEDO)

  11. Questioning hydrogen

    International Nuclear Information System (INIS)

    Hammerschlag, Roel; Mazza, Patrick

    2005-01-01

    As an energy carrier, hydrogen is to be compared to electricity, the only widespread and viable alternative. When hydrogen is used to transmit renewable electricity, only 51% can reach the end user due to losses in electrolysis, hydrogen compression, and the fuel cell. In contrast, conventional electric storage technologies allow between 75% and 85% of the original electricity to be delivered. Even when hydrogen is extracted from gasified coal (with carbon sequestration) or from water cracked in high-temperature nuclear reactors, more of the primary energy reaches the end user if a conventional electric process is used instead. Hydrogen performs no better in mobile applications, where electric vehicles that are far closer to commercialization exceed fuel cell vehicles in efficiency, cost and performance. New, carbon-neutral energy can prevent twice the quantity of GHG's by displacing fossil electricity than it can by powering fuel cell vehicles. The same is true for new, natural gas energy. New energy resources should be used to displace high-GHG electric generation, not to manufacture hydrogen

  12. Hybrid-Vehicle Transmission System

    Science.gov (United States)

    Lupo, G.; Dotti, G.

    1985-01-01

    Continuously-variable transmission system for hybrid vehicles couples internal-combustion engine and electric motor section, either individually or in parallel, to power vehicle wheels during steering and braking.

  13. The Hybrid Automobile and the Atkinson Cycle

    Science.gov (United States)

    Feldman, Bernard J.

    2008-01-01

    The hybrid automobile is a strikingly new automobile technology with a number of new technological features that dramatically improve energy efficiency. This paper will briefly describe how hybrid automobiles work; what are these new technological features; why the Toyota Prius hybrid internal combustion engine operates on the Atkinson cycle…

  14. Optimal Design of a Hydrogen Community by Genetic Algorithms

    International Nuclear Information System (INIS)

    Rodolfo Dufo Lopez; Jose Luis Bernal Agustin; Luis Correas Uson; Ismael Aso Aguarta

    2006-01-01

    A study was conducted for the implementation of two Hydrogen Communities, following the recommendations of the HY-COM initiative of the European Commission. The proposed communities find their place in the municipality of Sabinanigo (Aragon, Spain). Two cases are analyzed, one off-grid village house near Sabinanigo, and a house situated in the town proper. The study was carried out with the HOGA program, Hybrid Optimization by Genetic Algorithms. A description is provided for the algorithms. The off-grid study deals with a hybrid pv-wind system with hydrogen storage for AC supply to an isolated house. The urban study is related to hydrogen production by means of hybrid renewable sources available locally (photovoltaic, wind and hydro). These complement the existing industrial electrolysis processes, in order to cater for the energy requirements of a small fleet of municipal hydrogen-powered vehicles. HOGA was used to optimize both hybrid systems. Dimensioning and deployment estimations are also provided. (authors)

  15. Optimal Design of a Hydrogen Community by Genetic Algorithms

    International Nuclear Information System (INIS)

    Rodolfo Dufo Lopeza; Jose Luis Bernal Agustin; Luis Correas Uson; Ismael Aso Aguarta

    2006-01-01

    A study was conducted for the implementation of two Hydrogen Communities, following the recommendations of the HY-COM initiative of the European Commission. The proposed communities find their place in the municipality of Sabinanigo (Aragon, Spain). Two cases are analyzed, one off-grid village house near Sabinanigo, and a house situated in the town proper. The study was carried out with the HOGA program, Hybrid Optimization by Genetic Algorithms. A description is provided for the algorithms. The off-grid study deals with a hybrid PV-wind system with hydrogen storage for AC supply to an isolated house. The urban study is related to hydrogen production by means of hybrid renewable sources available locally (photovoltaic, wind and hydro). These complement the existing industrial electrolysis processes, in order to cater for the energy requirements of a small fleet of municipal hydrogen-powered vehicles. HOGA was used to optimize both hybrid systems. Dimensioning and deployment estimations are also provided. (authors)

  16. Saga of hydrogen civilization

    Energy Technology Data Exchange (ETDEWEB)

    Veziroglu, T.N. [Univ. of Miami, Coral Gables, FL (United States). Clean Energy Research Institute

    2008-09-30

    the problem, it became clear that it would be necessary to manufacture a synthetic fuel using the new primary energy sources. Hydrogen is the lightest, the most efficient, the cleanest, and the best fuel for transportation. The resulting energy system was called 'Hydrogen Energy System' or 'Hydrogen Economy', since energy is the locomotive of economy. The author was quite sure this was the best solution to the depletion of fossil fuels and the global environmental problems they are causing, such as global warming, climate change, ozone layer depletion, acid rain, air pollution, oil spills, etc. In order to inform the scientific community about the proposed solution and get their reaction and input, the author organized an international conference named The Hydrogen Economy Miami Energy (THEME) Conference which opened on March 18, 1974 with the participation of more than 700 scientists from some eighty countries. By the end of 1974, the International Association for Hydrogen Energy (IAHE) was established. As a result of the research and development activities around the world, World Hydrogen Energy Conferences, and the publication and dissemination of the research and development results through the International Journal of Hydrogen Energy, foundations of the Hydrogen Energy System were established during the quarter century from 1974 to 2000. Starting with the twenty-first century, the implementation of the Hydrogen Energy System began. Some hydrogen fuel cells became commercially available. All major car companies came up with various models of experimental hydrogen-fuelled cars. In several major cities of the world, hydrogen-fuelled buses started being operated on a trial basis. Airbus and Boeing Companies started programs for building hydrogen fuelled subsonic, supersonic and hypersonic passenger planes. Home appliances running on hydrogen have been built and tested. Hydrogen electric batteries have been commercialized. At CERI, a model study

  17. HNEI wind-hydrogen program

    International Nuclear Information System (INIS)

    Neill, D.; Holst, B.; Yu, C.; Huang, N.; Wei, J.

    1990-01-01

    This paper reports on wind powered hydrogen production which is promising for Hawaii because Hawaii's wind energy potential exceeds the state's current electrical energy requirements by more than twenty-fold. Wind energy costs are now approaching $0.06 to $0.08/kWh, and the U.S. Department of Energy has set a goal of $0.04/kWh. These conditions make wind power a good source for electrolytic production of hydrogen. HNEI's wind-hydrogen program, at the HNEI-Kahua Wind Energy Storage Test facility on the island of Hawaii, is developing energy storage and power electronic systems for intermittent wind and solar devices to provide firm power to the utility or to a stand-alone hybrid system. In mid 1990, the first wind-hydrogen production/storage/ generation system is scheduled for installation. HNEI's wind- hydrogen program will provide research, development, demonstration, and education on the great potential and benefits of hydrogen

  18. Fuel economy and life-cycle cost analysis of a fuel cell hybrid vehicle

    Science.gov (United States)

    Jeong, Kwi Seong; Oh, Byeong Soo

    The most promising vehicle engine that can overcome the problem of present internal combustion is the hydrogen fuel cell. Fuel cells are devices that change chemical energy directly into electrical energy without combustion. Pure fuel cell vehicles and fuel cell hybrid vehicles (i.e. a combination of fuel cell and battery) as energy sources are studied. Considerations of efficiency, fuel economy, and the characteristics of power output in hybridization of fuel cell vehicle are necessary. In the case of Federal Urban Driving Schedule (FUDS) cycle simulation, hybridization is more efficient than a pure fuel cell vehicle. The reason is that it is possible to capture regenerative braking energy and to operate the fuel cell system within a more efficient range by using battery. Life-cycle cost is largely affected by the fuel cell size, fuel cell cost, and hydrogen cost. When the cost of fuel cell is high, hybridization is profitable, but when the cost of fuel cell is less than 400 US$/kW, a pure fuel cell vehicle is more profitable.

  19. Hydrogen program overview

    Energy Technology Data Exchange (ETDEWEB)

    Gronich, S. [Dept. of Energy, Washington, DC (United States). Office of Utility Technologies

    1997-12-31

    This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

  20. Hydrogen vehicle fueling station

    Energy Technology Data Exchange (ETDEWEB)

    Daney, D.E.; Edeskuty, F.J.; Daugherty, M.A. [Los Alamos National Lab., NM (United States)] [and others

    1995-09-01

    Hydrogen fueling stations are an essential element in the practical application of hydrogen as a vehicle fuel, and a number of issues such as safety, efficiency, design, and operating procedures can only be accurately addressed by a practical demonstration. Regardless of whether the vehicle is powered by an internal combustion engine or fuel cell, or whether the vehicle has a liquid or gaseous fuel tank, the fueling station is a critical technology which is the link between the local storage facility and the vehicle. Because most merchant hydrogen delivered in the US today (and in the near future) is in liquid form due to the overall economics of production and delivery, we believe a practical refueling station should be designed to receive liquid. Systems studies confirm this assumption for stations fueling up to about 300 vehicles. Our fueling station, aimed at refueling fleet vehicles, will receive hydrogen as a liquid and dispense it as either liquid, high pressure gas, or low pressure gas. Thus, it can refuel any of the three types of tanks proposed for hydrogen-powered vehicles -- liquid, gaseous, or hydride. The paper discusses the fueling station design. Results of a numerical model of liquid hydrogen vehicle tank filling, with emphasis on no vent filling, are presented to illustrate the usefulness of the model as a design tool. Results of our vehicle performance model illustrate our thesis that it is too early to judge what the preferred method of on-board vehicle fuel storage will be in practice -- thus our decision to accommodate all three methods.

  1. Systems for hybrid cars

    Science.gov (United States)

    Bitsche, Otmar; Gutmann, Guenter

    Not only sharp competition but also legislation are pushing development of hybrid drive trains. Based on conventional internal combustion engine (ICE) vehicles, these drive trains offer a wide range of benefits from reduced fuel consumption and emission to multifaceted performance improvements. Hybrid electric drive trains may also facilitate the introduction of fuel cells (FC). The battery is the key component for all hybrid drive trains, as it dominates cost and performance issues. The selection of the right battery technology for the specific automotive application is an important task with an impact on costs of development and use. Safety, power, and high cycle life are a must for all hybrid applications. The greatest pressure to reduce cost is in soft hybrids, where lead-acid embedded in a considerate management presents the cheapest solution, with a considerable improvement in performance needed. From mild to full hybridization, an improvement in specific power makes higher costs more acceptable, provided that the battery's service life is equivalent to the vehicle's lifetime. Today, this is proven for the nickel-metal hydride system. Lithium ion batteries, which make use of a multiple safety concept, and with some development anticipated, provide even better prospects in terms of performance and costs. Also, their scalability permits their application in battery electric vehicles—the basis for better performance and enhanced user acceptance. Development targets for the batteries are discussed with a focus on system aspects such as electrical and thermal management and safety.

  2. Hybrid bearings for LH2 and LO2 turbopumps

    Science.gov (United States)

    Butner, M. F.; Lee, F. C.

    1985-01-01

    Hybrid combinations of hydrostatic and ball bearings can improve bearing performance for liquid hydrogen and liquid oxygen turbopumps. Analytic studies were conducted to optimize hybrid bearing designs for the SSME-type turbopump conditions. A method to empirically determine damping coefficients was devised. Four hybrid bearing configurations were designed, and three were fabricated. Six hybrid and hydrostatic-only bearing configurations will be tested for steady-state and transient performance, and quantification of damping coefficients. The initial tests were conducted with the liquid hydrogen bearing.

  3. International Clean Energy System Using Hydrogen Conversion (WE-NET). subtask 4. Development of hydrogen production technology; Suiso riyo kokusai clean energy system gijutsu (WE-NET). subtask 4. Suiso seizo gijutsu no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This paper describes development of hydrogen production technology as a part of the WE-NET project. For the solid polymer water electrolysis method higher in efficiency and lower in cost than the previous methods, 5 companies have developed element technologies for improving electrolysis cells and synthesis technologies of hot solid polymer electrolyte based on each proper catalyst electrode production method. In fiscal 1996, the initial study on large-scale systems by middle laboratory cells was made as well as improvement of electrolysis performance by small laboratory cells and endurance tests. Among the previous methods such as a hot press method (bonding of an ion exchange membrane to an electrode), an electroless plating method (preparation of porous surface onto a membrane electrode assembly), a zero gap method (preparation of high-efficiency high-current density cells), and a sintered porous electrode method (carrying of the mixture of catalytic powder and ion exchange resin-dissipated solution onto sintered metallic porous electrode surface), the former two methods were adopted for development of bench-scale cells as effective promising methods. 192 refs., 183 figs., 108 tabs.

  4. Metastable hydrogen

    International Nuclear Information System (INIS)

    Dose, V.

    1982-01-01

    This paper deals with the basic physical properties of the metastable 2 2 sub(1/2) state of atomic hydrogen. Applications relying on its special properties, including measurement of the Lamb shift, production of spin-polarized protons and the measurement of molecular electric moments, are discussed. (author)

  5. Oral Communication Skills Assessment in a Synchronous Hybrid MBA Programme: Does Attending Face-to-Face Matter for US and International Students?

    Science.gov (United States)

    Butz, Nikolaus T.; Askim-Lovseth, Mary K.

    2015-01-01

    The ability to communicate effectively is an essential skill for graduates of Masters of Business Administration (MBA) programmes; however, as synchronous hybrid learning becomes more common, business schools may find it challenging to assess students' proficiency in this core area. An additional layer of complexity is added by the burgeoning…

  6. Industrial implications of hydrogen

    International Nuclear Information System (INIS)

    Pressouyre, G.M.

    1982-01-01

    Two major industrial implications of hydrogen are examined: problems related to the effect of hydrogen on materials properties (hydrogen embrittlement), and problems related to the use and production of hydrogen as a future energy vector [fr

  7. Synfuel (hydrogen) production from fusion power

    International Nuclear Information System (INIS)

    Krakowski, R.A.; Cox, K.E.; Pendergrass, J.H.; Booth, L.A.

    1979-01-01

    A potential use of fusion energy for the production of synthetic fuel (hydrogen) is described. The hybrid-thermochemical bismuth-sulfate cycle is used as a vehicle to assess the technological and economic merits of this potential nonelectric application of fusion power

  8. Hybrid reactors

    International Nuclear Information System (INIS)

    Moir, R.W.

    1980-01-01

    The rationale for hybrid fusion-fission reactors is the production of fissile fuel for fission reactors. A new class of reactor, the fission-suppressed hybrid promises unusually good safety features as well as the ability to support 25 light-water reactors of the same nuclear power rating, or even more high-conversion-ratio reactors such as the heavy-water type. One 4000-MW nuclear hybrid can produce 7200 kg of 233 U per year. To obtain good economics, injector efficiency times plasma gain (eta/sub i/Q) should be greater than 2, the wall load should be greater than 1 MW.m -2 , and the hybrid should cost less than 6 times the cost of a light-water reactor. Introduction rates for the fission-suppressed hybrid are usually rapid

  9. Battery-operated, argon-hydrogen microplasma on hybrid, postage stamp-sized plastic-quartz chips for elemental analysis of liquid microsamples using a portable optical emission spectrometer.

    Science.gov (United States)

    Weagant, Scott; Chen, Vivian; Karanassios, Vassili

    2011-11-01

    A battery-operated, atmospheric pressure, self-igniting, planar geometry Ar-H(2) microplasma for elemental analysis of liquid microsamples is described. The inexpensive microplasma device (MPD) fabricated for this work was a hybrid plastic-quartz structure that was formed on chips with an area (roughly) equal to that of a small-sized postage stamp (MPD footprint, 12.5-mm width by 38-mm length). Plastic substrates were chosen due to their low cost, for rapid prototyping purposes, and for a speedy microplasma device evaluation. To enhance portability, the microplasma was operated from an 18-V rechargeable battery. To facilitate portability even further, it was demonstrated that the battery can be recharged by a portable solar panel. The battery-supplied dc voltage was converted to a high-voltage ac. The ~750-μm (diameter) and 12-mm (long) Ar-H(2) (3% H(2)) microplasma was formed by applying the high-voltage ac between two needle electrodes. Spectral interference from the electrode materials or from the plastic substrate was not observed. Operating conditions were found to be key to igniting and sustaining a microplasma that was simply "warm" to the touch (thus alleviating the need for cooling or other thermal management) and that had a stable background emission. A small-sized (900 μL internal volume) electrothermal vaporization system (40-W max power) was used for microsample introduction. Microplasma background emission in the spectral region between 200 and 850 nm obtained using a portable fiber-optic spectrometer is reported and the effect of the operating conditions is described. Analyte emission from microliter volumes of dilute single-element standard solutions of Cd, Cu, K, Li, Mg, Mn, Na, Pb, and Zn is documented. The majority of spectral lines observed for the elements tested were from neutral atoms. The relative lack of emission from ion lines simplified the spectra, thus facilitating the use of a portable spectrometer. Despite the relative spectral

  10. FY 1998 annual summary report on International Clean Energy Network Using Hydrogen Conversion (WE-NET) system technology. Subtask 8. Development of hydrogen combustion turbine and ultrahigh-temperature materials; 1998 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET) subtask 8 (suiro nensho turbine no kaihatsu/chokoon zairyo no kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Summarized herein are the materials designs/production and tests/evaluation results of heat-resistant materials, i.e., alloys, ceramic composites and carbon-based composites, which are expected to be applicable to the hydrogen combustion turbines. These have been studied since 1993, and this paper summarizes the overall evaluation results of the phase I program. The intermetallic compound as one of the candidate materials has a high-temperature strength in a range from 1200 to 1400 degrees C by optimizing elements added. However, no prospect is obtained for heat resistance at 1700 degrees C or more for the material not coated or cooled moderately. Each of the other candidate materials tested shows a bright prospect of applicability at the base material and specimen levels. The single-crystal superalloy for hybrid cooling structures has novelty in that it is free of Cr but incorporated with Si and Hf, showing approximately 10 degrees C higher heat-resistant temperature than CMSX-4. CMC and C/C are inherently excellent heat-resistant materials, and are attractive advanced composites, because they are expected to realize no-cooled blades at 1700 degrees C. (NEDO)

  11. Hydrogen from nuclear power

    International Nuclear Information System (INIS)

    Miller, A.I.

    2006-01-01

    A few years ago, one frequently heard the view that LNG would cap the price of natural gas in North America at around 5 or 6 US$/GJ just as soon as sufficient terminal capacity could be installed. Recent experience with international LNG prices suggests that this is unlikely. While oil and gas prices have proven almost impossible to predict it seems likely that the price of gas will in future broadly track its energy equivalent in oil. Consequently, planning for natural gas at 10 $/GJ would seem prudent. Using steam-methane reforming, this produces hydrogen at 1500 $/t. If CO 2 has to be sequestered, adding another 500 $/t H 2 is a likely additional cost. So is water electrolysis now competitive? Electrolysis would deliver hydrogen at 2000$/t if electricity costs 3.7 US cents/kWh. This is lower than the Alberta Pool average supply price but very close to AECL's estimated cost for power from a new reactor. However, electricity prices in deregulated markets vary hugely and there would be large leverage on the hydrogen price in delivering a mix of electricity (when the Pool price is high) and hydrogen (when it is low). The key to that possibility - as well as other issues of interruptibility - is low-cost cavern storage, similar to that used for natural gas. One long-standing example for hydrogen storage exists in the UK. The nuclear-electrolysis route offers long-term price stability. It also has co-product possibilities if a use can be found for oxygen (equivalent to about 300 $/t H 2 ) and to produce heavy water (provided the scale is at least 100 MW)

  12. A Novel Type of Battery-Supercapacitor Hybrid Device with Highly Switchable Dual Performances Based on a Carbon Skeleton/Mg2Ni Free-Standing Hydrogen Storage Electrode.

    Science.gov (United States)

    Li, Na; Du, Yi; Feng, Qing-Ping; Huang, Gui-Wen; Xiao, Hong-Mei; Fu, Shao-Yun

    2017-12-27

    The sharp proliferation of high power electronics and electrical vehicles has promoted growing demands for power sources with both high energy and power densities. Under these circumstances, battery-supercapacitor hybrid devices are attracting considerable attention as they combine the advantages of both batteries and supercapacitors. Here, a novel type of hybrid device based on a carbon skeleton/Mg 2 Ni free-standing electrode without the traditional nickel foam current collector is reported, which has been designed and fabricated through a dispersing-freeze-drying method by employing reduced graphene oxide (rGO) and multiwalled carbon nanotubes (MWCNTs) as a hybrid skeleton. As a result, the Mg 2 Ni alloy is able to deliver a high discharge capacity of 644 mAh g -1 and, more importantly, a high cycling stability with a retention of over 78% after 50 charge/discharge cycles have been achieved, which exceeds almost all the results ever reported on the Mg 2 Ni alloy. Simultaneously, the electrode could also exhibit excellent supercapacitor performances including high specific capacities (296 F g -1 ) and outstanding cycling stability (100% retention after 100 cycles). Moreover, the hybrid device can switch between battery and supercapacitor modes immediately as needed during application. These features make the C skeleton/alloy electrode a highly promising candidate for battery-supercapacitor hybrid devices with high power/energy density and favorable cycling stability.

  13. Hydrogen at the Rooftop: Compact CPV-Hydrogen system to Convert Sunlight to Hydrogen

    KAUST Repository

    Burhan, Muhammad

    2017-12-27

    Despite being highest potential energy source, solar intermittency and low power density make it difficult for solar energy to compete with the conventional power plants. Highly efficient concentrated photovoltaic (CPV) system provides best technology to be paired with the electrolytic hydrogen production, as a sustainable energy source with long term energy storage. However, the conventional gigantic design of CPV system limits its market and application to the open desert fields without any rooftop installation scope, unlike conventional PV. This makes CPV less popular among solar energy customers. This paper discusses the development of compact CPV-Hydrogen system for the rooftop application in the urban region. The in-house built compact CPV system works with hybrid solar tracking of 0.1° accuracy, ensured through proposed double lens collimator based solar tracking sensor. With PEM based electrolyser, the compact CPV-hydrogen system showed 28% CPV efficiency and 18% sunlight to hydrogen (STH) efficiency, for rooftop operation in tropical region of Singapore. For plant designers, the solar to hydrogen production rating of 217 kWh/kg has been presented with 15% STH daily average efficiency, recorded from the long term field operation of the system.

  14. Hydrogen at the Rooftop: Compact CPV-Hydrogen system to Convert Sunlight to Hydrogen

    KAUST Repository

    Burhan, Muhammad; Wakil Shahzad, Muhammad; Ng, Kim Choon

    2017-01-01

    Despite being highest potential energy source, solar intermittency and low power density make it difficult for solar energy to compete with the conventional power plants. Highly efficient concentrated photovoltaic (CPV) system provides best technology to be paired with the electrolytic hydrogen production, as a sustainable energy source with long term energy storage. However, the conventional gigantic design of CPV system limits its market and application to the open desert fields without any rooftop installation scope, unlike conventional PV. This makes CPV less popular among solar energy customers. This paper discusses the development of compact CPV-Hydrogen system for the rooftop application in the urban region. The in-house built compact CPV system works with hybrid solar tracking of 0.1° accuracy, ensured through proposed double lens collimator based solar tracking sensor. With PEM based electrolyser, the compact CPV-hydrogen system showed 28% CPV efficiency and 18% sunlight to hydrogen (STH) efficiency, for rooftop operation in tropical region of Singapore. For plant designers, the solar to hydrogen production rating of 217 kWh/kg has been presented with 15% STH daily average efficiency, recorded from the long term field operation of the system.

  15. Science review of internal combustion engines

    International Nuclear Information System (INIS)

    Taylor, Alex M.K.P.

    2008-01-01

    Internal combustion engines used in transportation produce about 23% of the UK's carbon dioxide emission, up from 14% in 1980. The current science described in this paper suggests that there could be 6-15% improvements in internal combustion fuel efficiency in the coming decade, although filters to meet emission legislation reduce these gains. Using these engines as hybrids with electric motors produces a reduction in energy requirements in the order of 21-28%. Developments beyond the next decade are likely to be dominated by four topics: emission legislation and emission control, new fuels, improved combustion and a range of advanced concepts for energy saving. Emission control is important because current methods for limiting nitrogen oxides and particulate emissions imply extra energy consumption. Of the new fuels, non-conventional fossil-derived fuels are associated with larger greenhouse gas emissions than conventional petroleum-based fuels, while a vehicle propelled by fuel cells consuming non-renewable hydrogen does not necessarily offer an improvement in emissions over the best hybrid internal combustion engines. Improved combustion may be developed for both gasoline and diesel fuels and promises better efficiency as well as lower noxious emissions without the need for filtering. Finally, four advanced concepts are considered: new thermodynamic cycles, a Rankine bottoming cycle, electric turbo-compounding and the use of thermoelectric devices. The latter three all have the common theme of trying to extract energy from waste heat, which represents about 30% of the energy input to an internal combustion engine

  16. Report on the results of the FY 1998 hydrogen utilization international clean energy system technology (WE-NET). Subtask 5. Survey on the R and D of technologies for hydrogen transport and storage by hydrogen absorbing alloys (V. Development of the distributed transport/storage use hydrogen absorbing alloys); 1998 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET). 5. Suiso yuso chozo gijutsu no kaihatsu (V. bunsan yuso chozoyo suiso kyuzo gokin no kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The paper described the FY 1998 results of the development of hydrogen distributed transport/storage use absorbing alloys in the WE-NET project. Study was made of improvement of hydrogen desorption characteristics by substituting Ca for part of Mg of Mg-Ni alloys and substituting Cr for part of Ni. It is necessary to shift the state of atomic bond by H atom and metal atom in alloys from the ionic bond to the metallic bond, and to change from the amorphous state to the BCC type crystal structure. It was found out that it was possible to do it by improving the composition and heat treatment. The addition of Cu to LaMg{sub 2} alloys shifts the bond with hydrogen to the bond with metal. Easy hydrogen desorption and large absorbing capacity can be expected. It was found out that LaMg{sub 2}Cu{sub 2} synthesized by the reaction sintering method has reversible hydrogen absorbing desorption characteristics. The absorbing amount is 2.4 wt%, the desorption amount 1.2 wt%, and the desorption temperature 190 degrees C. Those are still far from WE-NET targeted values, but a clue to the search was obtained. It was found out that by applying doping technology by Ti, etc. to NaAlH{sub 4}, characteristics can be expected of the desorption amount, 4.5 wt%, of the hydrogen desorption starting temperature from 100 degrees C to 200 degrees C. (NEDO)

  17. Hydrogen production using plasma processing

    International Nuclear Information System (INIS)

    Wagner, D.; Whidden, T.K.

    2006-01-01

    Plasma processing is a promising method of extracting hydrogen from natural gas while avoiding the greenhouse gas (GHG) production typical of other methods such as steam methane reforming. This presentation describes a plasma discharge process based that, in a single reactor pass, can yield hydrogen concentrations of up to 50 % by volume in the product gas mixture. The process is free of GHG's, does not require catalysts and is easily scalable. Chemical and morphological analyses of the gaseous and solid products of the process by gas-chromatography/mass-spectrometry, microscopic Raman analyses and electron microscopy respectively are reviewed. The direct production of hydrogen-enriched natural gas (HENG) as a fuel for low pollution internal combustion engines and its purification to high-purity hydrogen (99.99%) from the product gas by pressure swing adsorption (PSA) purifier beds are reviewed. The presentation reviews potential commercial applications for the technology

  18. Trends in Hydrogen Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Hoevenaars, A.J.; Weeda, M. [ECN Hydrogen and Clean Fossil Fuels, Petten (Netherlands)

    2009-09-15

    This report intends to provide an update of the latest developments that have recently occurred within car industry within the field of Hydrogen powered fuel cell vehicles (FCVs) to date, October 2009. In attempts to provide a clear and logical overview, the report starts with an overview of the OEMs (Original Equipment Manufacturers) that are actually active within the Hydrogen vehicle business, and provides an overview of the intensity of FCV activity per OEM. This overview shows that there is a pool of distinctively most active OEMs, and that others have tried to create exposure for themselves, but have not seriously been involved in in-house technology development in support of FCV manufacturing. Furthermore, some manufacturers chose a different path when it comes to using hydrogen for vehicle propulsion and use Hydrogen gas as a fuel for a conventional Internal Combustion Engine (ICE). In the field of FCVs, Most FCV activities are displayed by Honda, Daimler, Opel/GM, Hyundai/Kia, Toyota, Nissan and Ford. Volkswagen has given less priority to FCV development and has not been profiling itself as a very Hydrogen-prone OEM. Mazda and BMW chose to put their efforts in the development of Hydrogen fuelled ICE vehicles. Also Ford has put efforts in Hydrogen fuelled ICE vehicles. After the active OEMs are mapped, an overview is given on how active they have been in terms of cars produced. It appeared difficult to come up with reliable estimations on the basis of numbers available for public. The sum of vehicles produced by all OEMs together was estimated on about 515 vehicles. This estimation however was much lower than the figures published by Fuel Cell Today (FCT). FCT projects accumulated vehicles shipped in 2009 around 1100 units, the double of the numbers found for this study. Communication with FCT learned us that FCT has access to confidential information from the OEMs. Especially the Asian OEMs do not provide transparency when it comes to FCVs shipped, however

  19. Trends in Hydrogen Vehicles

    International Nuclear Information System (INIS)

    Hoevenaars, A.J.; Weeda, M.

    2009-09-01

    This report intends to provide an update of the latest developments that have recently occurred within car industry within the field of Hydrogen powered fuel cell vehicles (FCVs) to date, October 2009. In attempts to provide a clear and logical overview, the report starts with an overview of the OEMs (Original Equipment Manufacturers) that are actually active within the Hydrogen vehicle business, and provides an overview of the intensity of FCV activity per OEM. This overview shows that there is a pool of distinctively most active OEMs, and that others have tried to create exposure for themselves, but have not seriously been involved in in-house technology development in support of FCV manufacturing. Furthermore, some manufacturers chose a different path when it comes to using hydrogen for vehicle propulsion and use Hydrogen gas as a fuel for a conventional Internal Combustion Engine (ICE). In the field of FCVs, Most FCV activities are displayed by Honda, Daimler, Opel/GM, Hyundai/Kia, Toyota, Nissan and Ford. Volkswagen has given less priority to FCV development and has not been profiling itself as a very Hydrogen-prone OEM. Mazda and BMW chose to put their efforts in the development of Hydrogen fuelled ICE vehicles. Also Ford has put efforts in Hydrogen fuelled ICE vehicles. After the active OEMs are mapped, an overview is given on how active they have been in terms of cars produced. It appeared difficult to come up with reliable estimations on the basis of numbers available for public. The sum of vehicles produced by all OEMs together was estimated on about 515 vehicles. This estimation however was much lower than the figures published by Fuel Cell Today (FCT). FCT projects accumulated vehicles shipped in 2009 around 1100 units, the double of the numbers found for this study. Communication with FCT learned us that FCT has access to confidential information from the OEMs. Especially the Asian OEMs do not provide transparency when it comes to FCVs shipped, however

  20. The hybrid electric vehicle revolution, off road

    Energy Technology Data Exchange (ETDEWEB)

    Wood, B.E. [ePower Technologies (United States)

    2004-07-01

    In this presentation the author presents concepts and details of hybrid vehicles in general, including their benefits, then describes off-road hybrid vehicles. Hybrid vehicles have been experimented with for over a century. Demonstrator vehicles include a diesel-electric tractor, an electric lawn tractor, a hybrid snow thrower, and a hybrid wheel loader. A duty cycle for the loader is shown with battery-assisted acceleration, and regenerative braking. Both of these keep the size of the engine small, the loads on it less variable, thus improving fuel economy. A hybrid excavator and its duty cycle is shown. A fuel cell lift truck that is currently in design is illustrated. The author then describes the possibilities of the hydrogen economy where sourcing and infrastructure are yet to be demonstrated on a commercial scale. The author predicts that off-road hydrogen fuel cell vehicles will be commercially viable five years before on-road applications. The author predicts hydrogen sourced from biogas, photovoltaics, and wind power. tabs, figs.

  1. Hybrid laser-arc welding

    DEFF Research Database (Denmark)

    Hybrid laser-arc welding (HLAW) is a combination of laser welding with arc welding that overcomes many of the shortfalls of both processes. This important book gives a comprehensive account of hybrid laser-arc welding technology and applications. The first part of the book reviews...... the characteristics of the process, including the properties of joints produced by hybrid laser-arc welding and ways of assessing weld quality. Part II discusses applications of the process to such metals as magnesium alloys, aluminium and steel as well as the use of hybrid laser-arc welding in such sectors as ship...... building and the automotive industry. With its distinguished editor and international team of contributors, Hybrid laser-arc welding, will be a valuable source of reference for all those using this important welding technology. Professor Flemming Ove Olsen works in the Department of Manufacturing...

  2. Integrated waste hydrogen utilization project

    International Nuclear Information System (INIS)

    Armstrong, C.

    2004-01-01

    'Full text:' The BC Hydrogen Highway's, Integrated Waste Hydrogen Utilization Project (IWHUP) is a multi-faceted, synergistic collaboration that will capture waste hydrogen and promote its use through the demonstration of 'Hydrogen Economy' enabling technologies developed by Canadian companies. IWHUP involves capturing and purifying a small portion of the 600 kg/hr of by-product hydrogen vented to the atmosphere at the ERCO's electrochemical sodium chlorate plant in North Vancouver, BC. The captured hydrogen will then be compressed so it is suitable for transportation on roadways and can be used as a fuel in transportation and stationary fuel cell demonstrations. In summary, IWHUP invests in the following; Facilities to produce up to 20kg/hr of 99.999% pure 6250psig hydrogen using QuestAir's leading edge Pressure Swing Absorption technology; Ultra high-pressure transportable hydrogen storage systems developed by Dynetek Industries, Powertech Labs and Sacre-Davey Engineering; A Mobile Hydrogen Fuelling Station to create Instant Hydrogen Infrastructure for light-duty vehicles; Natural gas and hydrogen (H-CNG) blending and compression facilities by Clean Energy for fueling heavy-duty vehicles; Ten hydrogen, internal combustion engine (H-ICE), powered light duty pick-up vehicles and a specialized vehicle training, maintenance, and emissions monitoring program with BC Hydro, GVRD and the District of North Vancouver; The demonstration of Westport's H-CNG technology for heavy-duty vehicles in conjunction with local transit properties and a specialized vehicle training, maintenance, and emissions monitoring program; The demonstration of stationary fuel cell systems that will provide clean power for reducing peak-load power demands (peak shaving), grid independence and water heating; A comprehensive communications and outreach program designed to educate stakeholders, the public, regulatory bodies and emergency response teams in the local community, Supported by industry

  3. The hydrogen; L'hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    The hydrogen as an energy system represents nowadays a main challenge (in a scientific, economical and environmental point of view). The physical and chemical characteristics of hydrogen are at first given. Then, the challenges of an hydrogen economy are explained. The different possibilities of hydrogen production are described as well as the distribution systems and the different possibilities of hydrogen storage. Several fuel cells are at last presented: PEMFC, DMFC and SOFC. (O.M.)

  4. Solar hydrogen for urban trucks

    Energy Technology Data Exchange (ETDEWEB)

    Provenzano, J.: Scott, P.B.; Zweig, R. [Clean Air Now, Northridge, CA (United States)

    1997-12-31

    The Clean Air Now (CAN) Solar Hydrogen Project, located at Xerox Corp., El Segundo, California, includes solar photovoltaic powered hydrogen generation, compression, storage and end use. Three modified Ford Ranger trucks use the hydrogen fuel. The stand-alone electrolyzer and hydrogen dispensing system are solely powered by a photovoltaic array. A variable frequency DC-AC converter steps up the voltage to drive the 15 horsepower compressor motor. On site storage is available for up to 14,000 standard cubic feet (SCF) of solar hydrogen, and up to 80,000 SCF of commercial hydrogen. The project is 3 miles from Los Angeles International airport. The engine conversions are bored to 2.9 liter displacement and are supercharged. Performance is similar to that of the Ranger gasoline powered truck. Fuel is stored in carbon composite tanks (just behind the driver`s cab) at pressures up to 3600 psi. Truck range is 144 miles, given 3600 psi of hydrogen. The engine operates in lean burn mode, with nil CO and HC emissions. NO{sub x} emissions vary with load and rpm in the range from 10 to 100 ppm, yielding total emissions at a small fraction of the ULEV standard. Two trucks have been converted for the Xerox fleet, and one for the City of West Hollywood. A public outreach program, done in conjunction with the local public schools and the Department of Energy, introduces the local public to the advantages of hydrogen fuel technologies. The Clean Air Now program demonstrates that hydrogen powered fleet development is an appropriate, safe, and effective strategy for improvement of urban air quality, energy security and avoidance of global warming impact. Continued technology development and cost reduction promises to make such implementation market competitive.

  5. Hydrogen energy based on nuclear energy

    International Nuclear Information System (INIS)

    2002-06-01

    A concept to produce hydrogen of an energy carrier using nuclear energy was proposed since 1970s, and a number of process based on thermochemical method has been investigated after petroleum shock. As this method is used high temperature based on nuclear reactors, these researches are mainly carried out as a part of application of high temperature reactors, which has been carried out at an aim of the high temperature reactor application in the Japan Atomic Energy Research Institute. On October, 2000, the 'First International Conference for Information Exchange on Hydrogen Production based on Nuclear Energy' was held by auspice of OECD/NEA, where hydrogen energy at energy view in the 21st Century, technology on hydrogen production using nuclear energy, and so on, were published. This commentary was summarized surveys and researches on hydrogen production using nuclear energy carried out by the Nuclear Hydrogen Research Group established on January, 2001 for one year. They contains, views on energy and hydrogen/nuclear energy, hydrogen production using nuclear energy and already finished researches, methods of hydrogen production using nuclear energy and their present conditions, concepts on production plants of nuclear hydrogen, resources on nuclear hydrogen production and effect on global environment, requests from market and acceptability of society, and its future process. (G.K.)

  6. Hybrid composites

    CSIR Research Space (South Africa)

    Jacob John, Maya

    2009-04-01

    Full Text Available mixed short sisal/glass hybrid fibre reinforced low density polyethylene composites was investigated by Kalaprasad et al [25].Chemical surface modifications such as alkali, acetic anhydride, stearic acid, permanganate, maleic anhydride, silane...

  7. Hybrid intermediaries

    OpenAIRE

    Cetorelli, Nicola

    2014-01-01

    I introduce the concept of hybrid intermediaries: financial conglomerates that control a multiplicity of entity types active in the "assembly line" process of modern financial intermediation, a system that has become known as shadow banking. The complex bank holding companies of today are the best example of hybrid intermediaries, but I argue that financial firms from the "nonbank" space can just as easily evolve into conglomerates with similar organizational structure, thus acquiring the cap...

  8. Energy Accumulation by Hydrogen Technologies

    Directory of Open Access Journals (Sweden)

    Jiřina Čermáková

    2012-01-01

    Full Text Available Photovoltaic power plants as a renewable energy source have been receiving rapidly growing attention in the Czech Republic and in the other EU countries. This rapid development of photovoltaic sources is having a negative effect on the electricity power system control, because they depend on the weather conditions and provide a variable and unreliable supply of electric power. One way to reduce this effect is by accumulating electricity in hydrogen. The aim of this paper is to introduce hydrogen as a tool for regulating photovoltaic energy in island mode. A configuration has been designed for connecting households with the photovoltaic hybrid system, and a simulation model has been made in order to check the validity of this system. The simulation results provide energy flows and have been used for optimal sizing of real devices. An appropriate system can deliver energy in a stand-alone installation.

  9. Comparative costs and benefits of hydrogen vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Berry, G.D. [Lawrence Livermore National Lab., CA (United States)

    1996-10-01

    The costs and benefits of hydrogen as a vehicle fuel are compared to gasoline, natural gas, and battery-powered vehicles. Costs, energy, efficiency, and tail-pipe and full fuel cycle emissions of air pollutants and greenhouse gases were estimated for hydrogen from a broad range of delivery pathways and scales: from individual vehicle refueling systems to large stations refueling 300 cars/day. Hydrogen production from natural gas, methanol, and ammonia, as well as water electrolysis based on alkaline or polymer electrolytes and steam electrolysis using solid oxide electrolytes are considered. These estimates were compared to estimates for competing fuels and vehicles, and used to construct oil use, air pollutant, and greenhouse gas emission scenarios for the U.S. passenger car fleet from 2005-2050. Fuel costs need not be an overriding concern in evaluating the suitability of hydrogen as a fuel for passenger vehicles. The combined emissions and oil import reduction benefits of hydrogen cars are estimated to be significant, valued at up to {approximately}$400/yr for each hydrogen car when primarily clean energy sources are used for hydrogen production. These benefits alone, however, become tenuous as the basis supporting a compelling rationale for hydrogen fueled vehicles, if efficient, advanced fossil-fuel hybrid electric vehicles (HEV`s) can achieve actual on-road emissions at or below ULEV standards in the 2005-2015 timeframe. It appears a robust rationale for hydrogen fuel and vehicles will need to also consider unique, strategic, and long-range benefits of hydrogen vehicles which can be achieved through the use of production, storage, delivery, and utilization methods for hydrogen which are unique among fuels: efficient use of intermittent renewable energy sources, (e,g, wind, solar), small-scale feasibility, fuel production at or near the point of use, electrolytic production, diverse storage technologies, and electrochemical conversion to electricity.

  10. Hydrogen Storage using Physisorption : Modified Carbon Nanofibers and Related Materials

    NARCIS (Netherlands)

    Nijkamp, Marije Gessien

    2002-01-01

    This thesis describes our research on adsorbent systems for hydrogen storage for small scale, mobile application. Hydrogen storage is a key element in the change-over from the less efficient and polluting internal combustion engine to the pollution-free operating hydrogen fuel cell. In general,

  11. The hydrogen value chain: applying the automotive role model of the hydrogen economy in the aerospace sector to increase performance and reduce costs

    Science.gov (United States)

    Frischauf, Norbert; Acosta-Iborra, Beatriz; Harskamp, Frederik; Moretto, Pietro; Malkow, Thomas; Honselaar, Michel; Steen, Marc; Hovland, Scott; Hufenbach, Bernhard; Schautz, Max; Wittig, Manfred; Soucek, Alexander

    2013-07-01

    Hydrogen will assume a key role in Europe's effort to adopt its energy dependent society to satisfy its needs without releasing vast amounts of greenhouse gases. The paradigm shift is so paramount that one speaks of the "Hydrogen Economy", as the energy in this new and ecological type of economy is to be distributed by hydrogen. However, H2 is not a primary energy source but rather an energy carrier, a means of storing, transporting and distributing energy, which has to be generated by other means. Various H2 storage methods are possible; however industries' favourite is the storage of gaseous hydrogen in high pressure tanks. The biggest promoter of this storage methodology is the automotive industry, which is currently preparing for the generation change from the fossil fuel internal combustion engines to hydrogen based fuel cells. The current roadmaps foresee a market roll-out by 2015, when the hydrogen supply infrastructure is expected to have reached a critical mass. The hydrogen economy is about to take off as being demonstrated by various national mobility strategies, which foresee several millions of electric cars driving on the road in 2020. Fuel cell cars are only one type of "electric car", battery electric as well as hybrid cars - all featuring electric drive trains - are the others. Which type of technology is chosen for a specific application depends primarily on the involved energy storage and power requirements. These considerations are very similar to the ones in the aerospace sector, which had introduced the fuel cell already in the 1960s. The automotive sector followed only recently, but has succeeded in moving forward the technology to a level, where the aerospace sector is starting considering to spin-in terrestrial hydrogen technologies into its technology portfolio. Target areas are again high power/high energy applications like aviation, manned spaceflight and exploration missions, as well as future generation high power telecommunication

  12. Industrial view of Hydrogen Energy

    International Nuclear Information System (INIS)

    Francois Jackow

    2006-01-01

    Industrial Gases Companies have been mastering Hydrogen production, distribution, safe handling and applications for several decades for a wide range of gas applications. This unique industrial background positioned these companies to play a key role in the emerging Hydrogen Energy market, which can rely, at early stage of development, on already existing infrastructure, logistics and technical know-how. Nevertheless, it is important to acknowledge that Hydrogen Energy raised specific challenges which are not totally addressed by industrial gas activities. The main difference is obviously in the final customer profile, which differs significantly from the qualified professional our industry is used to serve. A non professional end-user, operating with Hydrogen at home or on board of his family car, has to be served with intrinsically safe and user-friendly solutions that exceed by far the industrial specifications already in place. Another significant challenge is that we will need breakthroughs both in terms of products and infrastructure, with development time frame that may require several decades. The aim of this presentation is to review how a company like Air Liquide, worldwide leader already operating more than 200 large hydrogen production sites, is approaching this new Hydrogen Energy market, all along the complete supply chain from production to end-users. Our contributions to the analysis, understanding and deployment of this new Energy market, will be illustrated by the presentation of Air Liquide internal development's as well as our participation in several national and European projects. (author)

  13. Hydrogen energy for the transportation sector in China

    International Nuclear Information System (INIS)

    Zong Qiangmao

    2006-01-01

    Hydrogen is a promising energy carrier for providing a clean, reliable and affordable energy supply. This paper provides a blueprint for the hydrogen energy in the transportation sector in the future of China. This paper is divided into three parts. The first part answers this question: why is China interested in hydrogen energy? The second part describes the possibility of a hydrogen fuel cell engine and a hydrogen internal-combustion engine in the transportation in China in the near future. The final part describes the production of hydrogen in China. (author)

  14. Towards a hydrogen-driven society? Calculations and neutron scattering on potential hydrogen storage materials

    OpenAIRE

    Schimmel, H.G.

    2005-01-01

    For sustainable development, the resources of the earth need to be maintained and carbon dioxide emission should be avoided. In particular, we need to find an alternative for the use of fossil fuels in vehicles. Since long, hydrogen has been recognised as the fuel of the future because it exhausts only water when used in fuel cells and hardly any pollutants when used in conventional internal combustion engines. However, the storage of hydrogen onboard vehicles is a major concern. Hydrogen is ...

  15. Method and apparatus for controlling hybrid powertrain system in response to engine temperature

    Science.gov (United States)

    Martini, Ryan D; Spohn, Brian L; Lehmen, Allen J; Cerbolles, Teresa L

    2014-10-07

    A method for controlling a hybrid powertrain system including an internal combustion engine includes controlling operation of the hybrid powertrain system in response to a preferred minimum coolant temperature trajectory for the internal combustion engine.

  16. Destructive hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Terrisse, H; Dufour, L

    1929-01-21

    Oils of high boiling point, e.g. gas oil, lamp oil, schist oil, brown coal tar etc., are converted into motor benzine by heating them at 200 to 500/sup 0/C under pressure of 5 to 40 kilograms/cm/sup 2/ in the presence of ferrous chloride and gases such as hydrogen, or water gas, the desulfurization of the oils proceeding simultaneously. One kilogram of lamp oil and 100 g. ferrous chloride are heated in an autoclave in the presence of water gas under a pressure of 18 kg/cm/sup 2/ to 380 to 400/sup 0/C. The gaseous products are allowed to escape intermittently and are replaced by fresh water gas. A product distilling between 35 and 270/sup 0/C is obtained.

  17. PENGADILAN HIBRIDA (HYBRID COURT SEBAGAI ALTERNATIF PENANGANAN KEJAHATAN INTERNASIONAL

    Directory of Open Access Journals (Sweden)

    Arie Siswanto

    2016-10-01

    Since the end of World War II, the international community witnessed the increasingly serious efforts to deal with the international crimes. Besides the domestic criminal courts and purely international tribunals, the forum that is also recently used to handle international crimes is the hybrid courts that have been established in several places such as in Cambodia, Sierra Leone and Timor-Leste. Hybrid courts are established from different political backgrounds, but as a legal institution, its establishment was necessarily based on legal instruments. This paper identifies that there are three patterns in the formation of hybrid court, which are: the establishment of a hybrid court based on an agreement between the UN and the relevant state, the establishment of a hybrid court by the UN or international administration and the establishment of a hybrid court by a country which later gains greater international support.

  18. Towards sustainable urban transportation: Test, demonstration and development of fuel cell and hybrid-electric buses

    International Nuclear Information System (INIS)

    Folkesson, Anders

    2008-05-01

    Several aspects make today's transport system non-sustainable: - Production, transport and combustion of fossil fuels lead to global and local environmental problems. - Oil dependency in the transport sector may lead to economical and political instability. - Air pollution, noise, congestion and land-use may jeopardise public health and quality of life, especially in urban areas. In a sustainable urban transport system most trips are made with public transport because high convenience and comfort makes travelling with public transport attractive. In terms of emissions, including noise, the vehicles are environmentally sustainable, locally as well as globally. Vehicles are energy-efficient and the primary energy stems from renewable sources. Costs are reasonable for all involved, from passengers, bus operators and transport authorities to vehicle manufacturers. The system is thus commercially viable on its own merits. This thesis presents the results from three projects involving different concept buses, all with different powertrains. The first two projects included technical evaluations, including tests, of two different fuel cell buses. The third project focussed on development of a series hybrid-bus with internal combustion engine intended for production around 2010. The research on the fuel cell buses included evaluations of the energy efficiency improvement potential using energy mapping and vehicle simulations. Attitudes to hydrogen fuel cell buses among passengers, bus drivers and bus operators were investigated. Safety aspects of hydrogen as a vehicle fuel were analysed and the use of hydrogen compared to electrical energy storage were also investigated. One main conclusion is that a city bus should be considered as one energy system, because auxiliaries contribute largely to the energy use. Focussing only on the powertrain is not sufficient. The importance of mitigating losses far down an energy conversion chain is emphasised. The Scania hybrid fuel cell

  19. Cloud cover over the equatorial eastern Pacific derived from July 1983 International Satellite Cloud Climatology Project data using a hybrid bispectral threshold method

    Science.gov (United States)

    Minnis, Patrick; Harrison, Edwin F.; Gibson, Gary G.

    1987-01-01

    A set of visible and IR data obtained with GOES from July 17-31, 1983 is analyzed using a modified version of the hybrid bispectral threshold method developed by Minnis and Harrison (1984). This methodology can be divided into a set of procedures or optional techniques to determine the proper contaminate clear-sky temperature or IR threshold. The various optional techniques are described; the options are: standard, low-temperature limit, high-reflectance limit, low-reflectance limit, coldest pixel and thermal adjustment limit, IR-only low-cloud temperature limit, IR clear-sky limit, and IR overcast limit. Variations in the cloud parameters and the characteristics and diurnal cycles of trade cumulus and stratocumulus clouds over the eastern equatorial Pacific are examined. It is noted that the new method produces substantial changes in about one third of the cloud amount retrieval; and low cloud retrievals are affected most by the new constraints.

  20. The effect of atomic hydrogen adsorption on single-walled carbon nano tubes properties

    International Nuclear Information System (INIS)

    Jalili, S.; Majidi, R.

    2007-01-01

    We investigated the adsorption of hydrogen atoms on metallic single-walled carbon nano tubes using ab initio molecular dynamics method. It was found that the geometric structures and the electronic properties of hydrogenated SWNTs can be strongly changed by varying hydrogen coverage. The circular cross sections of the CNTs were changed with different hydrogen coverage. When hydrogen is chemisorbed on the surface of the carbon nano tube, the energy gap will be appeared. This is due to the degree of the Sp 3 hybridization, and the hydrogen coverage can control the band gap of the carbon nano tube

  1. Hybrid stars

    Indian Academy of Sciences (India)

    Hybrid stars. AsHOK GOYAL. Department of Physics and Astrophysics, University of Delhi, Delhi 110 007, India. Abstract. Recently there have been important developments in the determination of neutron ... number and the electric charge. ... available to the system to rearrange concentration of charges for a given fraction of.

  2. Energy: the solar hydrogen alternative

    Energy Technology Data Exchange (ETDEWEB)

    Bocheris, J O.M.

    1977-01-01

    The author argues that nuclear and solar energy should begin replacing conventional fossil sources as soon as possible because oil, gas and even coal supplies will be depleted within decades. A hydrogen economy would introduce major technical problems but its chief benefits are that it permits energy storage in a post fossil fuel era when electricity is expected to play a major role. It can be converted to electricity, cleanly and efficiently with fuel cells and in liquid form can be burnt as jet fuel. Hydrogen can also be burnt in internal combustion engines although less efficiently in fuel cells. However, although hydrogen is clean and efficient, technical development is still needed to reduce its cost and to cope with safety problems. The book contains a wealth of technical information and is a valuable reference on a topic of growing importance.

  3. Hydrogen converters

    International Nuclear Information System (INIS)

    Mondino, Angel V.

    2003-01-01

    The National Atomic Energy Commission of Argentina developed a process of 99 Mo production from fission, based on irradiation of uranium aluminide targets with thermal neutrons in the RA-3 reactor of the Ezeiza Atomic Centre. These targets are afterwards dissolved in an alkaline solution, with the consequent liberation of hydrogen as the main gaseous residue. This work deals with the use of a first model of metallic converter and a later prototype of glass converter at laboratory scale, adjusted to the requirements and conditions of the specific redox process. Oxidized copper wires were used, which were reduced to elementary copper at 400 C degrees and then regenerated by oxidation with hot air. Details of the bed structure and the operation conditions are also provided. The equipment required for the assembling in cells is minimal and, taking into account the operation final temperature and the purge with nitrogen, the procedure is totally safe. Finally, the results are extrapolated for the design of a converter to be used in a hot cell. (author)

  4. HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER

    Energy Technology Data Exchange (ETDEWEB)

    BROWN,LC; BESENBRUCH,GE; LENTSCH,RD; SCHULTZ,KR; FUNK,JF; PICKARD,PS; MARSHALL,AC; SHOWALTER,SK

    2003-06-01

    OAK B202 HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER. Combustion of fossil fuels, used to power transportation, generate electricity, heat homes and fuel industry provides 86% of the world's energy. Drawbacks to fossil fuel utilization include limited supply, pollution, and carbon dioxide emissions. Carbon dioxide emissions, thought to be responsible for global warming, are now the subject of international treaties. Together, these drawbacks argue for the replacement of fossil fuels with a less-polluting potentially renewable primary energy such as nuclear energy. Conventional nuclear plants readily generate electric power but fossil fuels are firmly entrenched in the transportation sector. Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. Hydrogen will be particularly advantageous when coupled with fuel cells. Fuel cells have higher efficiency than conventional battery/internal combustion engine combinations and do not produce nitrogen oxides during low-temperature operation. Contemporary hydrogen production is primarily based on fossil fuels and most specifically on natural gas. When hydrogen is produced using energy derived from fossil fuels, there is little or no environmental advantage. There is currently no large scale, cost-effective, environmentally attractive hydrogen production process available for commercialization, nor has such a process been identified. The objective of this work is to find an economically feasible process for the production of hydrogen, by nuclear means, using an advanced high-temperature nuclear reactor as the primary energy source. Hydrogen production by thermochemical water-splitting (Appendix A), a chemical process that accomplishes the decomposition of water into hydrogen and oxygen using only heat or, in the case of a hybrid thermochemical process, by a combination of heat and electrolysis, could meet these goals. Hydrogen produced from

  5. Hybrid keyword search auctions

    KAUST Repository

    Goel, Ashish; Munagala, Kamesh

    2009-01-01

    auction easily extends to multiple slots, and is also applicable to scenarios where the hybrid bidding is per-impression and per-action (i.e. CPM and CPA), or per-click and per-action (i.e. CPC and CPA). Copyright is held by the International World Wide Web Conference Committee (IW3C2).

  6. Hybrid keyword search auctions

    KAUST Repository

    Goel, Ashish

    2009-01-01

    hybrid auction easily extends to multiple slots, and is also applicable to scenarios where the hybrid bidding is per-impression and per-action (i.e. CPM and CPA), or per-click and per-action (i.e. CPC and CPA). Copyright is held by the International World Wide Web Conference Committee (IW3C2).

  7. Fiscal 1999 phase 2 R and D report of WE-NET (International Clean Energy Network Using Hydrogen Conversion). Task 7. Development of hydrogen supply station; 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu seika hokokusho. Task 7. Suiso kyokyu station no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This report summarizes the fiscal 1999 research result on element technologies and system technology for hydrogen supply stations. In 1999, study was made on the total system of hydrogen supply stations, and basic specifications and total designs were studied for such main component systems of hydrogen supply stations as hydrogen production equipment with a reformer of natural gas, polymer electrolyte water electrolyzer hydrogen supply system, hydrogen absorbing alloy tank, and hydrogen dispenser unit. From the study result on the optimum operation condition of the hydrogen production equipment, a S/C (ratio of steam/mol of material carbon) of 2.5, reforming temperature of 700 degrees C, recycling gas ratio of 0.21, and air-fuel ratio of 1.3-2.0 were obtained. In the study on optimum hydrogen absorbing alloy, LaNi{sub 5} alloy system with Mn as additive were selected. For the polymer electrolyte water electrolyzer hydrogen supply station, the basic specification of a total system, and the remote control system of the station were studied and established. R and D themes in the future were also presented. (NEDO)

  8. Photoelectrochemical Hydrogen Production

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Jian

    2013-12-23

    The objectives of this project, covering two phases and an additional extension phase, were the development of thin film-based hybrid photovoltaic (PV)/photoelectrochemical (PEC) devices for solar-powered water splitting. The hybrid device, comprising a low-cost photoactive material integrated with amorphous silicon (a-Si:H or a-Si in short)-based solar cells as a driver, should be able to produce hydrogen with a 5% solar-to-hydrogen conversion efficiency (STH) and be durable for at least 500 hours. Three thin film material classes were studied and developed under this program: silicon-based compounds, copper chalcopyrite-based compounds, and metal oxides. With the silicon-based compounds, more specifically the amorphous silicon carbide (a-SiC), we achieved a STH efficiency of 3.7% when the photoelectrode was coupled to an a-Si tandem solar cell, and a STH efficiency of 6.1% when using a crystalline Si PV driver. The hybrid PV/a-SiC device tested under a current bias of -3~4 mA/cm{sup 2}, exhibited a durability of up to ~800 hours in 0.25 M H{sub 2}SO{sub 4} electrolyte. Other than the PV driver, the most critical element affecting the photocurrent (and hence the STH efficiency) of the hybrid PV/a-SiC device was the surface energetics at the a-SiC/electrolyte interface. Without surface modification, the photocurrent of the hybrid PEC device was ~1 mA/cm{sup 2} or lower due to a surface barrier that limits the extraction of photogenerated carriers. We conducted an extensive search for suitable surface modification techniques/materials, of which the deposition of low work function metal nanoparticles was the most successful. Metal nanoparticles of ruthenium (Ru), tungsten (W) or titanium (Ti) led to an anodic shift in the onset potential. We have also been able to develop hybrid devices of various configurations in a monolithic fashion and optimized the current matching via altering the energy bandgap and thickness of each constituent cell. As a result, the short

  9. Hydrogen production processes

    International Nuclear Information System (INIS)

    2003-01-01

    The goals of this first Gedepeon workshop on hydrogen production processes are: to stimulate the information exchange about research programs and research advances in the domain of hydrogen production processes, to indicate the domains of interest of these processes and the potentialities linked with the coupling of a nuclear reactor, to establish the actions of common interest for the CEA, the CNRS, and eventually EDF, that can be funded in the framework of the Gedepeon research group. This document gathers the slides of the 17 presentations given at this workshop and dealing with: the H 2 question and the international research programs (Lucchese P.); the CEA's research program (Lucchese P., Anzieu P.); processes based on the iodine/sulfur cycle: efficiency of a facility - flow-sheets, efficiencies, hard points (Borgard J.M.), R and D about the I/S cycle: Bunsen reaction (Colette S.), R and D about the I/S cycle: the HI/I 2 /H 2 O system (Doizi D.), demonstration loop/chemical engineering (Duhamet J.), materials and corrosion (Terlain A.); other processes under study: the Westinghouse cycle (Eysseric C.), other processes under study at the CEA (UT3, plasma,...) (Lemort F.), database about thermochemical cycles (Abanades S.), Zn/ZnO cycle (Broust F.), H 2 production by cracking, high temperature reforming with carbon trapping (Flamant G.), membrane technology (De Lamare J.); high-temperature electrolysis: SOFC used as electrolyzers (Grastien R.); generic aspects linked with hydrogen production: technical-economical evaluation of processes (Werkoff F.), thermodynamic tools (Neveu P.), the reactor-process coupling (Aujollet P.). (J.S.)

  10. Advanced radiation detector development mercuric iodide, silicon with internal gain, hybrid scintillator/semiconductor detectors. Comprehensive summary report, 1976-1985

    International Nuclear Information System (INIS)

    Huth, G.C.; Dabrowski, A.J.

    1985-01-01

    Accomplishments are reported in the development of a compound semi-insulator mercuric iodide (HgI 2 ) for nuclear radiation detection and spectroscopy, early lung cancer detection and localization in the uranium miner/worker population, computer digital image processing and image reconstruction research, and a concept for multiple, filtered x-ray computed tomography scanning to reveal chemical compositional information. Another area of interest is the study of new advances in the area of silicon detectors with internal gain (''avalanche'')

  11. Hydrogen fuel cell power system

    International Nuclear Information System (INIS)

    Lam, A.W.

    2004-01-01

    'Full text:' Batteries are typically a necessary and prime component of any DC power system, providing a source of on-demand stored energy with proven reliability. The integration of batteries and basic fuel cells for mobile and stationary utility applications poses a new challenge. For high value applications, the specification and operating requirements for this hybrid module differ from conventional requirements as the module must withstand extreme weather conditions and provide extreme reliability. As an electric utility company, BCHydro has embarked in the development and application of a Hydrogen Fuel Cell Power Supply (HFCPS) for field trial. A Proton Exchange Membrane (PEM)- type fuel cell including power electronic modules are mounted in a standard 19-inch rack that provides 48V, 24V, 12V DC and 120V AC outputs. The hydrogen supply consists of hydrogen bottles and regulating devices to provide a continuous fuel source to the power modules. Many tests and evaluations have been done to ensure the HFCPS package is robust and suitable for electric utility grade operation. A field trial demonstrating this standalone system addressed reliability, durability, and installation concerns as well as developed the overall system operating procedures. (author)

  12. Electric arc hydrogen heaters

    International Nuclear Information System (INIS)

    Zasypin, I.M.

    2000-01-01

    The experimental data on the electric arc burning in hydrogen are presented. Empirical and semiempirical dependences for calculating the arc characteristics are derived. An engineering method of calculating plasma torches for hydrogen heating is proposed. A model of interaction of a hydrogen arc with a gas flow is outlined. The characteristics of plasma torches for heating hydrogen and hydrogen-bearing gases are described. (author)

  13. Fiscal 1997 survey report. Subtask 2 (hydrogen utilization worldwide clean energy system technology) (WE-NET) (survey/study for the promotion of international cooperation); 1997 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET) subtask 2 (kokusai kyoryoku suishin no tame no choa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The survey was aimed at developing the WE-NET as a joint project worldwide by taking concrete measures such PR activities to obtain international understanding and cooperation of WE-NET based on the survey/grasp of researches of research institutes in each country and the developmental trend of hydrogen energy in each of the main countries. Implementing a `long-term vision for the WE-NET international cooperation,` the following measures were taken in fiscal 1997. PR activities were positively developed which coped with the worldwide increasing interest in WE-NET such as delivery to overseas institutions of the fiscal 1996 survey report in English summarized by NEDO and information exchanges, and participation in international conferences and presentation of the research results. From a standpoint of positively proceeding with the international technical information exchange, the following were conducted following fiscal 1996: 1) the evaluation study jointly made with Stanford University of effects of reducing air pollution by introducing hydrogen cars, 2) survey on the U.S. hydrogen project, and 3) preparation for opening of the WE-NET internet home pages. 17 figs., 18 tabs.

  14. Hydrogen energy technology

    International Nuclear Information System (INIS)

    Morovic, T.; Pilhar, R.; Witt, B.

    1988-01-01

    A comprehensive assessment of different energy systems from the economic point of view has to be based on data showing all relevant costs incurred and benefits drawn by the society from the use of such energy systems, i.e. internal costs and benefits visible to the energy consumer as prices paid for power supplied, as well as external costs and benefits. External costs or benefits of energy systems cover among other items employment or wage standard effects, energy-induced environmental impacts, public expenditure for pollution abatement and mitigation of risks and effects of accidents, and the user costs connected with the exploitation of reserves, which are not rated high enough to really reflect and demonstrate the factor of depletion of non-renewable energy sources, as e.g. fossil reserves. Damage to the natural and social environment induced by anthropogenous air pollutants up to about 90% counts among external costs of energy conversion and utilisation. Such damage is considered to be the main factor of external energy costs, while the external benefits of energy systems currently are rated to be relatively unsignificant. This means that an internalisation of external costs would drive up current prices of non-renewable energy sources, which in turn would boost up the economics of renewable energy sources, and the hydrogen produced with their energy. Other advantages attributed to most of the renewable energy sources and to hydrogen energy systems are better environmental compatibility, and no user costs. (orig.) [de

  15. Hybrid fuel cells technologies for electrical microgrids

    Energy Technology Data Exchange (ETDEWEB)

    San Martin, Jose Ignacio; Zamora, Inmaculada; San Martin, Jose Javier; Aperribay, Victor; Eguia, Pablo [Department of Electrical Engineering, University of the Basque Country, Alda. de Urquijo, s/n, 48013 Bilbao (Spain)

    2010-09-15

    Hybrid systems are characterized by containing two or more electrical generation technologies, in order to optimize the global efficiency of the processes involved. These systems can present different operating modes. Besides, they take into account aspects that not only concern the electrical and thermal efficiencies, but also the reduction of pollutant emissions. There is a wide range of possible configurations to form hybrid systems, including hydrogen, renewable energies, gas cycles, vapour cycles or both. Nowadays, these technologies are mainly used for energy production in electrical microgrids. Some examples of these technologies are: hybridization processes of fuel cells with wind turbines and photovoltaic plants, cogeneration and trigeneration processes that can be configured with fuel cell technologies, etc. This paper reviews and analyses the main characteristics of electrical microgrids and the systems based on fuel cells for polygeneration and hybridization processes. (author)

  16. Storage, transmission and distribution of hydrogen

    Science.gov (United States)

    Kelley, J. H.; Hagler, R., Jr.

    1979-01-01

    Current practices and future requirements for the storage, transmission and distribution of hydrogen are reviewed in order to identify inadequacies to be corrected before hydrogen can achieve its full potential as a substitute for fossil fuels. Consideration is given to the storage of hydrogen in underground solution-mined salt caverns, portable high-pressure containers and dewars, pressure vessels and aquifers and as metal hydrides, hydrogen transmission in evacuated double-walled insulated containers and by pipeline, and distribution by truck and internal distribution networks. Areas for the improvement of these techniques are indicated, and these technological deficiencies, including materials development, low-cost storage and transmission methods, low-cost, long-life metal hydrides and novel methods for hydrogen storage, are presented as challenges for research and development.

  17. Nuclear power reactors and hydrogen storage systems

    International Nuclear Information System (INIS)

    Ibrahim Aly Mahmoud El Osery.

    1980-01-01

    Among conclusions and results come by, a nuclear-electric-hydrogen integrated power system was suggested as a way to prevent the energy crisis. It was shown that the hydrogen power system using nuclear power as a leading energy resource would hold an advantage in the current international situation as well as for the long-term future. Results reported provide designers of integrated nuclear-electric-hydrogen systems with computation models and routines which will allow them to explore the optimal solution in coupling power reactors to hydrogen producing systems, taking into account the specific characters of hydrogen storage systems. The models were meant for average computers of a type easily available in developing countries. (author)

  18. Economic efficiency simulation for optimized management of pressure electrolysers in hybrid power plant systems. Prognosis and hydrogen production; Wirtschaftlichkeitssimulation zur optimierten Betriebsfuehrung von Druckelektrolyseuren in hybriden Kraftwerksystemen. Prognose und Wasserstoffproduktion

    Energy Technology Data Exchange (ETDEWEB)

    Krueger, P.; Ziems, C.; Tannert, D.; Voigt, A.; Fischer, U.; Krautz, H.J. [Brandenburgische Technische Univ. Cottbus-Senftenberg, Cottbus (Germany)

    2014-07-01

    As part of the research at the H{sub 2} Research Centre of BTU Cottbus-Senftenberg feasibility studies are carried out on the use of electrolysis technology in conjunction with fluctuating wind power fed to a pressure electrolysis apparatus. The aim of the analysis is an economically optimized operating strategy of the system consisting of wind farm, alkaline pressure electrolyser, hydrogen storage and reconversion. For this purpose, an energy economics tool was created. [German] Im Rahmen der Forschungsarbeiten am H{sub 2}-Forschungszentrum der BTU Cottbus-Senftenberg werden an einer Druckelektrolyseanlage Wirtschaftlichkeitsbetrachtungen zum Einsatz der Elektrolysetechnik in Verbindung mit fluktuierender Windenergieeinspeisung durchgefuehrt. Ziel der Analysen ist eine wirtschaftlich optimierte Betriebsstrategie des Systems, bestehend aus Windpark, alkalischem druckaufgeladenem Elektrolyseur, Wasserstoff-Speicher und Rueckverstromung. Hierzu wurde ein Wirtschaftlichkeits-Tool erstellt.

  19. FY 1998 annual summary report on International Clean Energy Network Using Hydrogen Conversion (WE-NET) system technology. Subtask 6. Development of cryogenic temperature materials technologies; 1998 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET) subtask 6 (teion zairyo gijutsu no kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Summarized herein are the cryogenic temperature materials technologies for the International Clean Energy Network Using Hydrogen Conversion (WE-NET) project, developed in FY 1998. The R and D programs have been implemented continuously since 1994. For stainless steel, the base and TIG weld metals were evaluated for their material characteristics in liquid hydrogen. The items investigated included the influences of hydrogen charge, 20% of stretch working on the base metal, welding methods, and ?-ferrite content on the characteristics. Fatigue strength of the base metal was found to increases as temperature decreases, but remain unchanged in a range from 20 to 77K. No significant difference was observed between 304L and 316L. For aluminum alloy, mechanical characteristics, centered by fatigue characteristics, were investigated for the base and weld metals. The sample of higher tensile strength showed a higher fatigue strength, at room temperature, 77 and 4K. The other tested items investigated included embrittlement characteristics in a hydrogen atmosphere, phase transformation, hydrogen diffusion and fracture toughness, for establishing the databases of cryogenic temperature materials. (NEDO)

  20. Development of hydrogen production technology using FBR

    International Nuclear Information System (INIS)

    Ono, Kiyoshi; Otaki, Akira; Chikazawa, Yoshitaka; Nakagiri, Toshio; Sato, Hiroyuki; Sekine, Takashi; Ooka, Makoto

    2004-06-01

    This report describes the features of technology, the schedule and the organization for the research and development regarding the hydrogen production technology using FBR thermal energy. Now, the hydrogen production system is proposed as one of new business models for FBR deployment. This system is the production of hydrogen either thermal energy at approximately from 500degC to 550degC or electricity produced by a sodium cooled FBR. Hydrogen is expected to be one of the future clean secondary energies without carbon-dioxide emission. Meanwhile the global energy demand will increase, especially in Asian countries, and the energy supply by fossil fuels is not the best choice considering the green house effect and the stability of energy supply. The development of the hydrogen technology using FBR that satisfies 'sustainable energy development' and 'utilization of energies free from environmental pollution' will be one of the promising options. Based on the above mentioned recognition, we propose the direction of the development, the issues to be solved, the time schedule, the budget, and the organization for R and D of three hydrogen production technologies, the thermochemical hybrid process, the low temperature steam reforming process, and the high temperature steam electrolysis process in JNC. (author)

  1. The hydrogen village in the Greater Toronto Area (GTA)

    International Nuclear Information System (INIS)

    Kimmel, T.B.; Smith, R.

    2004-01-01

    'Full text:' A Hydrogen Village (H2V) is a public/private partnership with an objective to accelerate the commercialization of hydrogen and fuel cell technology in Canada and firmly position Canada as the international leader in this sector. The first Hydrogen Village is planned for the Greater Toronto Area (GTA) and will make use of existing hydrogen and fuel cell deployments to assist in its creation. This five year GTA Hydrogen Village program is planned to begin operations in 2004. The Hydrogen Village will demonstrate and deploy various hydrogen production and delivery techniques as well as fuel cells for stationary, transportation (mobile) and portable applications. This paper will provide an overview of the Hydrogen Village and identify the missions, objectives, members and progress within the H2V. (author)

  2. International Clean Energy System Using Hydrogen Conversion (WE-NET). subtask 5. Development of hydrogen transport/storage technology (development of tanker for liquid hydrogen); Suiso riyo kokusai clean energy system gijutsu (WE-NET). subtask 5. Suiso yuso chozo gijutsu no kaihatsu (ekitai suiso yuso tanker no kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    As a part of the WE-NET project, the tanker for liquid hydrogen transport was studied. In fiscal 1996, some experiments and numerical analyses were proposed which are necessary to solve technological issues extracted in fiscal 1995 for heat insulation structure. The issue was roughly classified into vacuum and non-vacuum insulation, and their basic functions and required performance were arranged. Boil-off rate of 0.2-0.4%/d was targeted. The insulation system which applies polyurethane form (PUF) to tank surfaces and injects atmospheric N2 gas into the surrounding hold space, could achieve the targeted insulation performance by PUF of 1m in thickness. The system of vacuum panel insulation and atmospheric N2 gas injection into a hold space required the panel of 500mm in thickness because of the large effect of metallic outer panel material. The system of vacuum hold and PUF panels was faced with the essential issue for realizing and maintaining vacuum hold. The super insulation system featured by layered insulation materials and vacuum layer spaces was also strongly affected by degree of vacuum. 23 figs., 8 tabs.

  3. International Clean Energy System Using Hydrogen Conversion (WE-NET). subtask 5. Development of hydrogen transport/storage technology (development of storage facility for liquid hydrogen); Suiso riyo kokusai clean energy system gijutsu (WE-NET). subtask 5. Suiso yuso chozo gijutsu no kaihatsu (ekitai suiso chozo setsubi no kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    As a part of the WE-NET project, the storage facility for a large amount of liquid hydrogen (LH) was studied. Gasification loss caused by heat input of LH delivery pumps was studied for liquefaction and power generation bases assuming an pump efficiency of 70%, and the total heat and mass balance such as interface conditions for calculating the amount of boil-off gas was reviewed. The target storage capacity of 50,000m{sup 3} was reasonable, however, the performance of loading arms should be examined. The capacity around 5,000m{sup 3} of coastal localized bases was reasonable for control delivery loss caused by coastal tanker or LH container system to 2.6%. The capacity of 500m{sup 3} was suitable for inland bases, resulting in the loss of 1.2%. The concept design of the storage tank of 50,000m{sup 3} extracted confirmation of low-temperature characteristics of adiabatic materials and structures, and development of leakage inspection technology and vacuum holding technology as issues. The concept design of the underground storage tank showed that the material specifications for LNG ones are applicable to it by using proper adiabatic structures. 4 refs., 72 figs., 27 tabs.

  4. Why hydrogen; Pourquoi l'hydrogene?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-02-01

    The energy consumption increase and the associated environmental risks, led to develop new energy sources. The authors present the potentialities of the hydrogen in this context of energy supply safety. They detail the today market and the perspectives, the energy sources for the hydrogen production (fossils, nuclear and renewable), the hydrogen transport, storage, distribution and conversion, the application domains, the associated risks. (A.L.B.)

  5. Development and characterization of a solar-hydrogen energy system

    International Nuclear Information System (INIS)

    Sebastian, P.J.; Vejar, S.; Gonzalez, E.; Perez, M.; Gamboa, S.A.

    2009-01-01

    'Full text': The details of the development of a PV-hydrogen hybrid energy system are presented. An arrangement of photovoltaic modules (125 W/module) was established to provide 9 kW installed power in a three-phase configuration at 127 Vrms/phase. A 5 kW fuel cell system (hydrogen/oxygen) operates as a dynamic backup of the photovoltaic system. The autonomous operation of the hybrid power system implies the production of hydrogen by electrolysis. The hydrogen is produced by water electrolysis using an electrolyzer of 1 kW of power. The electrical energy used to produce hydrogen is supplied from solar panels by using 1 kW of photovoltaic modules. The photovoltaic modules are installed in a sun-tracker arrangement for increasing the energy conversion efficiency. The hydrogen is stored in solar to electric commercial metal hydride based containers and supplied to the fuel cell. The hybrid system is monitored by internet, and some dynamic characteristics such as demanding power, energy and power factor could be analyzed independently from the system. Some energy saving recommendations have been implemented as a pilot program at CIE-UNAM to improve the efficient use of clean energy in normal operating conditions in offices and laboratories. (author)

  6. Hydrogen fuel. Uses

    International Nuclear Information System (INIS)

    Darkrim-Lamari, F.; Malbrunot, P.

    2006-01-01

    Hydrogen is a very energetic fuel which can be used in combustion to generate heat and mechanical energy or which can be used to generate electricity and heat through an electrochemical reaction with oxygen. This article deals with the energy conversion, the availability and safety problems linked with the use of hydrogen, and with the socio-economical consequences of a generalized use of hydrogen: 1 - hydrogen energy conversion: hydrogen engines, aerospace applications, fuel cells (principle, different types, domains of application); 2 - hydrogen energy availability: transport and storage (gas pipelines, liquid hydrogen, adsorbed and absorbed hydrogen in solid materials), service stations; 3 - hazards and safety: flammability, explosibility, storage and transport safety, standards and regulations; 4 - hydrogen economy; 5 - conclusion. (J.S.)

  7. Hydrogen utilization international clean energy system technology (WE-NET). Subtask 5. Development of technology of hydrogen transportation/storage (3rd edition, development of liquid hydrogen storage equipment, report on results of Air Liquide); Suiso riyo kokusai clean energy system gijutsu (WE-NET). Subtask 5. Suiso yuso chozo gijutsu no kaihatsu (daisanpen ekitai suiso chozo setsubi no kaihatsu Air Liquide sha seika hokoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    In the fiscal 1995 study, items were searched which are keys to the design of a liquid hydrogen tanker of a capacity of 200,000m{sup 3}. Among those, the basic concepts were summarized which are necessary for the design of a liquid hydrogen tanker in terms of safety, and the extraporation of the existing low temperature technology into the large liquid hydrogen tank was studied. When adopting safety conditions of IGC Code applied to LNG to the liquid hydrogen tanker, it is necessary to limit the discharge amount of hydrogen to 3 kg/s. When considering safety at fire, for keeping safety of the same level as that of the LNG tanker, it is not appropriate to adopt the conventional vacuum insulation liquid hydrogen tank. In the fiscal 1995 study, 7 kinds of concept of the insulation structure were assumed, and it was concluded that BOR of 0.04-0.23/d was obtained. Also in fiscal 1996, the large liquid hydrogen tank was studied. For insulation of the large liquid hydrogen tank, the structure is most promising where AEROSIL bag or homogeneous AEROSIL is substituted for a forming heat insulating material of 4 design, but further study is needed for selection of the optimum heat insulating structure. 9 figs., 6 tabs.

  8. Market Penetration Simulation of Hydrogen Powered Vehicles in Korea

    International Nuclear Information System (INIS)

    Eunju Jun; Yong Hoon, Jeong; Soon Heung, Chang

    2006-01-01

    As oil price being boosted, hydrogen has been considered to be a strong candidate for the future energy carrier along with electricity. Although hydrogen can be produced by many energy sources, carbon-free sources such as nuclear and renewable energy may be ideal ones due to their environmental friendliness. For the analysis of hydrogen economy, the cost and market penetration of various end-use technologies are the most important factors in production and consumer side, respectively. Particularly, hydrogen powered vehicle is getting more interests as fuel cell technologies are developed. In this paper, the hydrogen powered vehicle penetration into the transportation market is simulated. A system dynamic code, Vensim, was utilized to simulate the dynamics in the transportation, assuming various types of vehicle such as gasoline, hybrid electricity and hydrogen powered. Market shares of each vehicle are predicted by using currently available data. The result showed that hydrogen era will not be bright as we think. To reach the era of hydrogen fuel cell cost should be reduced dramatically. And if the hydrogen cost which includes both operating and capital cost reaches to a $0.16 per kilometer, hydrogen portion can be a 50 percent in the transportation sector. However, if strong policy or subsidy can be given, the result will be changed. [1] (authors)

  9. DEVELOPMENT OF DOPED NANOPOROUS CARBONS FOR HYDROGEN STORAGE

    Energy Technology Data Exchange (ETDEWEB)

    Lueking, Angela D.; Li, Qixiu; Badding, John V.; Fonseca, Dania; Gutierrez, Humerto; Sakti, Apurba; Adu, Kofi; Schimmel, Michael

    2010-03-31

    Hydrogen storage materials based on the hydrogen spillover mechanism onto metal-doped nanoporous carbons are studied, in an effort to develop materials that store appreciable hydrogen at ambient temperatures and moderate pressures. We demonstrate that oxidation of the carbon surface can significantly increase the hydrogen uptake of these materials, primarily at low pressure. Trace water present in the system plays a role in the development of active sites, and may further be used as a strategy to increase uptake. Increased surface density of oxygen groups led to a significant enhancement of hydrogen spillover at pressures less than 100 milibar. At 300K, the hydrogen uptake was up to 1.1 wt. % at 100 mbar and increased to 1.4 wt. % at 20 bar. However, only 0.4 wt% of this was desorbable via a pressure reduction at room temperature, and the high lowpressure hydrogen uptake was found only when trace water was present during pretreatment. Although far from DOE hydrogen storage targets, storage at ambient temperature has significant practical advantages oner cryogenic physical adsorbents. The role of trace water in surface modification has significant implications for reproducibility in the field. High-pressure in situ characterization of ideal carbon surfaces in hydrogen suggests re-hybridization is not likely under conditions of practical interest. Advanced characterization is used to probe carbon-hydrogen-metal interactions in a number of systems and new carbon materials have been developed.

  10. IEA Hydrogen Implementing Agreement's Second Generation R and D and the Hydrogen Economy

    Energy Technology Data Exchange (ETDEWEB)

    Beck, N.; Garcia-Conde, A. G.; Riis, T. U.; Luzzi, A.; Valladares, M. R. de

    2005-07-01

    Since its creation by the International Energy Agency in the late 1970's, the IEA Hydrogen Implementing Agreement (HIA) has been at the forefront of collaborative international hydrogen research and development (R and D) (http://www.ieahia.org. ) The collective body of HIA hydrogen R and D will contribute to definition of the hydrogen economy. The five-year [2004-2009) mission of the IEA HIA is to advance the adoption of a Hydrogen Economy through strategic implementation of collaborative R and D and outreach programs that address key issues and barriers. The three goals for the Second Generation HIA are: Advancement of science and technology via pre-commercial collaborative RD and D programs; Assessment of market environment, including the non-energy sector; and Implementation of outreach program, aimed at community acceptance and support. The HIA launched its Second Generation of hydrogen R and D in the latter part of 2004. The HIA's anniversary report: In Pursuit of the Future: 25 Years of IEA Research towards the realization of Hydrogen Energy Systems (http://ieahia.org/pdfs/IEA_AnniversaryReport_HIA.pdf) chronicles its contributions to hydrogen R and D. As the hydrogen economy takes shape, the HIA is pleased to share highlights of its R and D history together with progress on planned activities and its six current annexes, listed below: Task 15 Photobiological Production of Hydrogen Task 16 Hydrogen from Carbon-Containing Materials Task 17 Solid and Liquid Storage Task 18 Integrated Systems Evaluation Task 19 Safety Task 20 Hydrogen from Waterphotolysis Planned successor annexes in storage and photobiological hydrogen production will also be discussed, along with a task on high temperature hydrogen production that is now in the definition phase. Over 250 experts from the sixteen member HIA countries and the European Union contribute to this portfolio of cutting edge hydrogen R and D and analysis activities. Several other countries are expected to

  11. Hydrogen energy systems studies

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, J.M.; Kreutz, T.G.; Steinbugler, M. [Princeton Univ., NJ (United States)] [and others

    1996-10-01

    In this report the authors describe results from technical and economic assessments carried out during the past year with support from the USDOE Hydrogen R&D Program. (1) Assessment of technologies for small scale production of hydrogen from natural gas. Because of the cost and logistics of transporting and storing hydrogen, it may be preferable to produce hydrogen at the point of use from more readily available energy carriers such as natural gas or electricity. In this task the authors assess near term technologies for producing hydrogen from natural gas at small scale including steam reforming, partial oxidation and autothermal reforming. (2) Case study of developing a hydrogen vehicle refueling infrastructure in Southern California. Many analysts suggest that the first widespread use of hydrogen energy is likely to be in zero emission vehicles in Southern California. Several hundred thousand zero emission automobiles are projected for the Los Angeles Basin alone by 2010, if mandated levels are implemented. Assuming that hydrogen vehicles capture a significant fraction of this market, a large demand for hydrogen fuel could evolve over the next few decades. Refueling a large number of hydrogen vehicles poses significant challenges. In this task the authors assess near term options for producing and delivering gaseous hydrogen transportation fuel to users in Southern California including: (1) hydrogen produced from natural gas in a large, centralized steam reforming plant, and delivered to refueling stations via liquid hydrogen truck or small scale hydrogen gas pipeline, (2) hydrogen produced at the refueling station via small scale steam reforming of natural gas, (3) hydrogen produced via small scale electrolysis at the refueling station, and (4) hydrogen from low cost chemical industry sources (e.g. excess capacity in refineries which have recently upgraded their hydrogen production capacity, etc.).

  12. Fiscal 1999 phase 2 R and D report of WE-NET (International Clean Energy Network Using Hydrogen Conversion). Task 5. Development of hydrogen vehicle system; 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu. Task 5. Suiso jidosha system no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This report summarizes the fiscal 1999 research result on the safety of hydrogen absorbing alloy tanks for hydrogen vehicle systems and the measuring method of a fuel consumption rate of hydrogen fuel cell powered vehicles. In the impact rupture test of (mini-scale) hydrogen absorbing alloy tanks, the impact 3-point bending test result by drop weight showed no ignition caused by impact and friction energy acting on hydrogen released by rupture of tanks, and the necessity for taking spontaneous ignition of alloys due to fuel leakage into account. The experiment result on deformation and rupture of alloy tanks caused by expansion and contraction of crystal lattices due to hydrogen absorption and desorption showed relatively large deformation due to grain fining only within earlier 10 cycles, and no cracks nor other defects even after 1000 cycles. In the measurement of a fuel consumption rate of hydrogen fuel cell powered vehicles, the study result on flow rate measurement method, full tank method, electric current method, hydrogen balance method and oxygen balance method showed that the electric current method is most simple, accurate and practical. (NEDO)

  13. Hydrogen in metals

    CSIR Research Space (South Africa)

    Carter, TJ

    2001-04-01

    Full Text Available .J. Cartera,*, L.A. Cornishb aAdvanced Engineering & Testing Services, MATTEK, CSIR, Private Bag X28, Auckland Park 2006, South Africa bSchool of Process and Materials Engineering, University of the Witwatersrand, Private Bag 3, P.O. WITS 2050, South Africa... are contrasted, and an unusual case study of hydrogen embrittlement of an alloy steel is presented. 7 2001 Published by Elsevier Science Ltd. Keywords: Hydrogen; Hydrogen-assisted cracking; Hydrogen damage; Hydrogen embrittlement 1. Introduction Hydrogen suC128...

  14. Development of Advanced Small Hydrogen Engines

    Energy Technology Data Exchange (ETDEWEB)

    Sapru, Krishna; Tan, Zhaosheng; Chao, Ben

    2010-09-30

    The main objective of the project is to develop advanced, low cost conversions of small (< 25 hp) gasoline internal combustion engines (ICEs) to run on hydrogen fuel while maintaining the same performance and durability. This final technical report summarizes the results of i) the details of the conversion of several small gasoline ICEs to run on hydrogen, ii) the durability test of a converted hydrogen engine and iii) the demonstration of a prototype bundled canister solid hydrogen storage system. Peak power of the hydrogen engine achieves 60% of the power output of the gasoline counterpart. The efforts to boost the engine power with various options including installing the over-sized turbocharger, retrofit of custom-made pistons with high compression ratio, an advanced ignition system, and various types of fuel injection systems are not realized. A converted Honda GC160 engine with ACS system to run with hydrogen fuel is successful. Total accumulative runtime is 785 hours. A prototype bundled canister solid hydrogen storage system having nominal capacity of 1.2 kg is designed, constructed and demonstrated. It is capable of supporting a wide range of output load of a hydrogen generator.

  15. Fiscal 2000 report on the Phase II R and D of the international hydrogen utilization clean energy network system technology (WE-NET). Task 3. Survey and research on international cooperation (Hydrogen energy technology standardization); 2000 nendo suiro riyo kokusai clean energy sytem gijutsu (WE-NET) dai 2 ki kenkyu kaihatsu. 3. Kokusai kyoryoku ni kansuru chosa kenkyu (suiso energy gijutsu hyojunka ni kansuru chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Efforts were made to establish standards necessary to promote the research and development of hydrogen energy technology and the practical application and popularization of the technology. In the study of the base of hydrogen energy technology standardization, research was conducted about Japan's difference from other countries and tasks to discharge and problems to solve in this country, relative to laws and regulations governing the construction of 'hydrogen supply stations' constituting the core of studies in the above-mentioned phase II research and development efforts. Studies conducted toward diffusion into the general public included rules and regulations over the size of hydrogen storage and the distance between dangerous matters and fire. ISO/TC197 (hydrogen technology) was established with the aim of achieving standardization of the system and equipment pertaining to the production, storage, transportation, measurement, and utilization of hydrogen for energy purposes. In fiscal 2000, Working Group 1 registered an 'interface for automated liquid hydrogen fuel delivery system' and 'hydrogen product specifications.' Moreover, Working Groups 2 through 7 were also engaged in their activities, respectively. (NEDO)

  16. Fiscal 2000 report on the Phase II R and D of the international hydrogen utilization clean energy network system technology (WE-NET). Task 3. Survey and research on international cooperation (Hydrogen energy technology standardization); 2000 nendo suiro riyo kokusai clean energy sytem gijutsu (WE-NET) dai 2 ki kenkyu kaihatsu. 3. Kokusai kyoryoku ni kansuru chosa kenkyu (suiso energy gijutsu hyojunka ni kansuru chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Efforts were made to establish standards necessary to promote the research and development of hydrogen energy technology and the practical application and popularization of the technology. In the study of the base of hydrogen energy technology standardization, research was conducted about Japan's difference from other countries and tasks to discharge and problems to solve in this country, relative to laws and regulations governing the construction of 'hydrogen supply stations' constituting the core of studies in the above-mentioned phase II research and development efforts. Studies conducted toward diffusion into the general public included rules and regulations over the size of hydrogen storage and the distance between dangerous matters and fire. ISO/TC197 (hydrogen technology) was established with the aim of achieving standardization of the system and equipment pertaining to the production, storage, transportation, measurement, and utilization of hydrogen for energy purposes. In fiscal 2000, Working Group 1 registered an 'interface for automated liquid hydrogen fuel delivery system' and 'hydrogen product specifications.' Moreover, Working Groups 2 through 7 were also engaged in their activities, respectively. (NEDO)

  17. Hybrid Qualifications

    DEFF Research Database (Denmark)

    Against the background of increasing qualification needs there is a growing awareness of the challenge to widen participation in processes of skill formation and competence development. At the same time, the issue of permeability between vocational education and training (VET) and general education...... has turned out as a major focus of European education and training policies and certainly is a crucial principle underlying the European Qualifications Framework (EQF). In this context, «hybrid qualifications» (HQ) may be seen as an interesting approach to tackle these challenges as they serve «two...

  18. Hybrid Gear

    Science.gov (United States)

    Handschuh, Robert F. (Inventor); Roberts, Gary D. (Inventor)

    2016-01-01

    A hybrid gear consisting of metallic outer rim with gear teeth and metallic hub in combination with a composite lay up between the shaft interface (hub) and gear tooth rim is described. The composite lay-up lightens the gear member while having similar torque carrying capability and it attenuates the impact loading driven noise/vibration that is typical in gear systems. The gear has the same operational capability with respect to shaft speed, torque, and temperature as an all-metallic gear as used in aerospace gear design.

  19. Two dimensional simulation of hydrogen iodide decomposition reaction using fluent code for hydrogen production using nuclear technology

    Energy Technology Data Exchange (ETDEWEB)

    Chi, Jung Sik [The Institute of Machinery and Electronic Technology, Mokpo National Maritime University, Mokpo (Korea, Republic of); Shin, Young Joon; Lee, Ki Young [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Choi, Jae Hyuk [Division of Marine Engineering System, Korea Maritime and Ocean University, Busan (Korea, Republic of)

    2015-06-15

    The operating characteristics of hydrogen iodide (HI) decomposition for hydrogen production were investigated using the commercial computational fluid dynamics code, and various factors, such as hydrogen production, heat of reaction, and temperature distribution, were studied to compare device performance with that expected for device development. Hydrogen production increased with an increase of the surface-to-volume (STV) ratio. With an increase of hydrogen production, the reaction heat increased. The internal pressure and velocity of the HI decomposer were estimated through pressure drop and reducing velocity from the preheating zone. The mass of H2O was independent of the STV ratio, whereas that of HI decreased with increasing STV ratio.

  20. Analysis of hydrogen operation in the Danish Traffic System

    DEFF Research Database (Denmark)

    Jørgensen, Kaj

    1996-01-01

    The main report of a study of the utilisation of hydrogen in the Danish energy and traffic system.The report contains an overview and assessment of the potential hydrogen technologies as well as analyses of the energy and environmental effects of different applications in the Danish transport sec...... sector (passenger car, bus, van, truck). The report concludes that hydrogen along with electric and hybrid propulsion can be a very interesting element in a strategy for sustainable transport, but only if based mainly on renewable energy....

  1. Economic assessment of a waste hydrogen utilization project

    International Nuclear Information System (INIS)

    Wang, L.; Zhou, H.; Zhou, W.; Wu, J.; Wang, Q.

    1993-01-01

    This paper reports the economic assessment on an hybrid hydrogen recovery, purification, storage, transportation and application project (HRPSTA) set for a system including a nitrogenous fertilizer plant and a float glass factory. A pretreatment unit and metal hydride containers are used to recover and purify the hydrogen from the purge gas of the ammonia fertilizer plant and to transport and use the hydrogen on the tin bath in the float glass factory. Cost analysis and cash flow statements are presented, and financial value and rate of return are calculated. The project is shown to be technologically and financially feasible. 1 fig., 4 tabs., 4 refs

  2. Thermodynamic modelling and kinetics of hydrogen absorption associated with phase transformations

    International Nuclear Information System (INIS)

    Gondor, G.; Lexcellent, Ch.

    2007-01-01

    The intermetallic are used for hydrogen pressure containers in order to avoid leaks in the case of an hybrid container. The hydrogen atoms are absorbed by the intermetallic which act as a hydrogen sponge. This hydrogen absorption must be modelled for the container design. The Pressure-composition isotherms describe the equilibrium. Out of this equilibrium the kinetics are controlled by different processes, without taking into account the phase transformations. The author presents a new model of the p-c isotherms with the hydrogen absorption kinetics. (A.L.B.)

  3. Fuel Cell and Hydrogen Technologies Program | Hydrogen and Fuel Cells |

    Science.gov (United States)

    NREL Fuel Cell and Hydrogen Technologies Program Fuel Cell and Hydrogen Technologies Program Through its Fuel Cell and Hydrogen Technologies Program, NREL researches, develops, analyzes, and validates fuel cell and hydrogen production, delivery, and storage technologies for transportation

  4. Comparative study of fuel cell, battery and hybrid buses for renewable energy constrained areas

    Science.gov (United States)

    Stempien, J. P.; Chan, S. H.

    2017-02-01

    Fuel cell- and battery-based public bus technologies are reviewed and compared for application in tropical urban areas. This paper scrutinizes the reported literature on fuel cell bus, fuel cell electric bus, battery electric bus, hybrid electric bus, internal combustion diesel bus and compressed natural gas bus. The comparison includes the capital and operating costs, fuel consumption and fuel cycle emissions. To the best of authors knowledge, this is the first study to holistically compare hydrogen and battery powered buses, which is the original contribution of this paper. Moreover, this is the first study to focus on supplying hydrogen and electricity from fossil resources, while including the associated emissions. The study shows that compressed natural gas and hybrid electric buses appear to be the cheapest options in terms of total cost of ownership, but they are unable to meet the EURO VI emissions' standard requirement. Only fuel cell based buses have the potential to achieve the emissions' standard when the fuel cycle based on fossil energy was considered. Fuel cell electric buses are identified as a technology allowing for the largest CO2 emission reduction, making ∼61% decrease in annual emissions possible.

  5. Dynamics of hydrogen in hydrogenated amorphous silicon

    Indian Academy of Sciences (India)

    is mobile and can easily move through the material). Hydrogen diffuses ... The determination of the relationship of light-enhanced hydrogen motion to ... term is negligible, and using the thermodynamic relation given below f(c) = kBT .... device-applications problematic but the normal state can be recovered by a thermal an-.

  6. Basic tuning of hydrogen powered car and artificial intelligent prediction of hydrogen engine characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Ho, Tien [School of Engineering, University of Tasmania, GPO Box 252-65, Hobart, Tasmania, 7001 (Australia); Karri, Vishy [Australian College of Kuwait, P.O. Box 1411, Safat 13015 (Kuwait)

    2010-09-15

    Many studies of renewable energy have shown hydrogen is one of the major green energy in the future. This has lead to the development of many automotive application of using hydrogen as a fuel especially in internal combustion engine. Nonetheless, there has been a slow growth and less knowledge details in building up the prototype and control methodology of the hydrogen internal combustion engine. In this paper, The Toyota Corolla 4 cylinder, 1.8l engine running on petrol was systematically modified in such a way that it could be operated on either gasoline or hydrogen at the choice of the driver. Within the scope of this project, several ancillary instruments such as a new inlet manifold, hydrogen fuel injection, storage system and leak detection safety system were implemented. Attention is directed towards special characteristics related to the basic tuning of hydrogen engine such as: air to fuel ratio operating conditions, ignition timing and injection timing in terms of different engine speed and throttle position. Based on the experimental data, a suite of neural network models were tested to accurately predict the effect of different engine operating conditions (speed and throttle position) on the hydrogen powered car engine characteristics. Predictions were found to be {+-}3% to the experimental values for all of case studies. This work provided better understanding of the effect of hydrogen engine characteristic parameters on different engine operating conditions. (author)

  7. Hydrogen Production Using Nuclear Energy

    Energy Technology Data Exchange (ETDEWEB)

    Verfondern, K. [Research Centre Juelich (Germany)

    2013-03-15

    One of the IAEA's statutory objectives is to 'seek to accelerate and enlarge the contribution of atomic energy to peace, health and prosperity throughout the world.' One way this objective is achieved is through the publication of a range of technical series. Two of these are the IAEA Nuclear Energy Series and the IAEA Safety Standards Series. According to Article III.A.6 of the IAEA Statute, the safety standards establish 'standards of safety for protection of health and minimization of danger to life and property'. The safety standards include the Safety Fundamentals, Safety Requirements and Safety Guides. These standards are written primarily in a regulatory style, and are binding on the IAEA for its own programmes. The principal users are the regulatory bodies in Member States and other national authorities. The IAEA Nuclear Energy Series comprises reports designed to encourage and assist R and D on, and application of, nuclear energy for peaceful uses. This includes practical examples to be used by owners and operators of utilities in Member States, implementing organizations, academia, and government officials, among others. This information is presented in guides, reports on technology status and advances, and best practices for peaceful uses of nuclear energy based on inputs from international experts. The IAEA Nuclear Energy Series complements the IAEA Safety Standards Series. Nuclear generated hydrogen has important potential advantages over other sources that will be considered for a growing hydrogen share in a future world energy economy. Still, there are technical uncertainties in nuclear hydrogen processes that need to be addressed through a vigorous research and development effort. Safety issues as well as hydrogen storage and distribution are important areas of research to be undertaken to support a successful hydrogen economy in the future. The hydrogen economy is gaining higher visibility and stronger political support in several parts of the

  8. Intuitionistic hybrid logic

    DEFF Research Database (Denmark)

    Braüner, Torben

    2011-01-01

    Intuitionistic hybrid logic is hybrid modal logic over an intuitionistic logic basis instead of a classical logical basis. In this short paper we introduce intuitionistic hybrid logic and we give a survey of work in the area.......Intuitionistic hybrid logic is hybrid modal logic over an intuitionistic logic basis instead of a classical logical basis. In this short paper we introduce intuitionistic hybrid logic and we give a survey of work in the area....

  9. Handbook of hydrogen energy

    CERN Document Server

    Sherif, SA; Stefanakos, EK; Steinfeld, Aldo

    2014-01-01

    ""This book provides an excellent overview of the hydrogen economy and a thorough and comprehensive presentation of hydrogen production and storage methods.""-Scott E. Grasman, Rochester Institute of Technology, New York, USA

  10. Hydrogen production by Cyanobacteria

    Directory of Open Access Journals (Sweden)

    Chaudhuri Surabhi

    2005-12-01

    Full Text Available Abstract The limited fossil fuel prompts the prospecting of various unconventional energy sources to take over the traditional fossil fuel energy source. In this respect the use of hydrogen gas is an attractive alternate source. Attributed by its numerous advantages including those of environmentally clean, efficiency and renew ability, hydrogen gas is considered to be one of the most desired alternate. Cyanobacteria are highly promising microorganism for hydrogen production. In comparison to the traditional ways of hydrogen production (chemical, photoelectrical, Cyanobacterial hydrogen production is commercially viable. This review highlights the basic biology of cynobacterial hydrogen production, strains involved, large-scale hydrogen production and its future prospects. While integrating the existing knowledge and technology, much future improvement and progress is to be done before hydrogen is accepted as a commercial primary energy source.

  11. Center for Hydrogen Storage.

    Science.gov (United States)

    2013-06-01

    The main goals of this project were to (1) Establish a Center for Hydrogen Storage Research at Delaware State University for the preparation and characterization of selected complex metal hydrides and the determination their suitability for hydrogen ...

  12. Assessment of MHR-based hydrogen energy systems

    International Nuclear Information System (INIS)

    Richards, Matthew; Shenoy, Arkal; Schultz, Kenneth; Brown, Lloyd; Besenbruch, Gottfried; Handa, Norihiko; Das, Jadu

    2004-01-01

    Process heat from a high-temperature nuclear reactor can be used to drive a set of chemical reactions, with the net result of splitting water into hydrogen and oxygen. For example, process heat at temperatures in the range 850degC to 950degC can drive the sulfur-iodine (SI) thermochemical process to produce hydrogen with high efficiency. The SI process produces highly pure hydrogen and oxygen, with formation, decomposition, regeneration, and recycle of the intermediate chemical reagents and low-temperature heat as the only waste product. Electricity can also be used directly to split water, using conventional, low-temperature electrolysis (LTE). Hydrogen can also be produced with hybrid processes that use both process heat and electricity to generate hydrogen. An example of a hybrid process is high-temperature electrolysis (HTE), in which process heat is used to generate steam, which is then supplied to an electrolyzer to generate hydrogen. This process is of interest because the efficiency of electrolysis increases with temperature. Because of its high-temperature capability, advanced of development relative to other high-temperature reactor concepts, and passive-safety features, the Modular Helium Reactor (MHR) is well suited for producing hydrogen using nuclear energy. In this paper we investigate concepts for coupling the MHR to the SI process, LTE, and HTE. These concepts are referred to as the H2-MHR. (author)

  13. Nuclear electrolytic hydrogen

    International Nuclear Information System (INIS)

    Barnstaple, A.G.; Petrella, A.J.

    1982-05-01

    An extensive study of hydrogen supply has recently been carried out by Ontario Hydro which indicates that electrolytic hydrogen produced from nuclear electricity could offer the lowest cost option for any future large scale hydrogen supply in the Province of Ontario, Canada. This paper provides a synopsis of the Ontario Hydro study, a brief overview of the economic factors supporting the study conclusion and discussion of a number of issues concerning the supply of electrolytic hydrogen by electric power utilities

  14. Hydrogen Technologies Safety Guide

    Energy Technology Data Exchange (ETDEWEB)

    Rivkin, C. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Burgess, R. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Buttner, W. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2015-01-01

    The purpose of this guide is to provide basic background information on hydrogen technologies. It is intended to provide project developers, code officials, and other interested parties the background information to be able to put hydrogen safety in context. For example, code officials reviewing permit applications for hydrogen projects will get an understanding of the industrial history of hydrogen, basic safety concerns, and safety requirements.

  15. Hydrogen-metal systems

    International Nuclear Information System (INIS)

    Wenzl, H.; Springer, T.

    1976-01-01

    A survey is given on the alloys of metal crystals with hydrogen. The system niobium-hydrogen and its properties are especially dealt with: diffusion and heat of solution of hydrogen in the host crystal, phase diagram, coherent and incoherent phase separation, application of metal-hydrogen systems in technology. Furthermore, examples from research work in IFF (Institut fuer Festkoerperforschung) of the Nuclear Research Plant, Juelich, in the field of metal-H systems are given in summary form. (GSC) [de

  16. Trace hydrogen extraction from liquid lithium tin alloy

    International Nuclear Information System (INIS)

    Xie Bo; Hu Rui; Xie Shuxian; Weng Kuiping

    2010-01-01

    In order to finish the design of tritium extraction system (TES) of fusion fission hybrid reactor (FFHR) tritium blanket, involving the dynamic mathematical model of liquid metal in contact with a gaseous atmosphere, approximate mathematical equation of tritium in lithium tin alloy was deduced. Moreover, carrying process used for trace hydrogen extraction from liquid lithium tin alloy was investigated with hydrogen being used to simulate tritium in the study. The study results indicate that carrying process is effective way for hydrogen extraction from liquid lithium tin alloy, and the best flow velocity of carrier gas is about 4 L/min under 1 kg alloy temperatures and carrying numbers are the main influencing factors of hydrogen number. Hydrogen extraction efficiency can reach 85% while the alloy sample is treated 6 times at 823 K. (authors)

  17. Achievement report for fiscal 2000 on the phase II research and development for hydrogen utilizing international clean energy system technology (WE-NET). Task 7. Development of hydrogen refueling station; 2000 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dai 2 ki kenkyu kaihatsu. Task 7. Suiso kyokyu station no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This paper describes the achievements in fiscal 2000 from the development of hydrogen refueling stand-alone stations for hydrogen fueled automobiles in the WE-NET. Supply capacity of practical size of 1/10, 30 Nm{sup 3} was selected as the object. For the natural gas reformed type hydrogen generator, discussions were given on design and manufacture of a reforming unit and a PSA device. The PCT diagram method was discussed to estimate the capacity of a hydrogen absorbing alloy type storing facility. Interface between fuel cell driven automobiles and the station was adjusted. For the solid polymer electrolyte water decomposition type, safety measures were discussed with a high-pressure filling system kept in mind. Detailed design was made on a water decomposing hydrogen generator. Fabrication was completed on the hydrogen absorbing alloy type storing facility, and verifications were given on the storage amount, hydrogen absorbing speed, and discharge capability. In the high-pressure refueling system, temperature rise was simulated at a pressure of 35 MPa. Refueling for ten minutes raised the gas temperature by 75 degrees C, and the container surface by 65 degrees C. Local temperature rise was forecasted in the actual work, which is a future discussion assignment. An outline method was discussed for the verification test. (NEDO)

  18. Hydrogenation of passivated contacts

    Energy Technology Data Exchange (ETDEWEB)

    Nemeth, William; Yuan, Hao-Chih; LaSalvia, Vincenzo; Stradins, Pauls; Page, Matthew R.

    2018-03-06

    Methods of hydrogenation of passivated contacts using materials having hydrogen impurities are provided. An example method includes applying, to a passivated contact, a layer of a material, the material containing hydrogen impurities. The method further includes subsequently annealing the material and subsequently removing the material from the passivated contact.

  19. Hydrogen storage in metal-organic frameworks: A review

    CSIR Research Space (South Africa)

    Langmi, Henrietta W

    2014-05-01

    Full Text Available Metal-organic frameworks (MOFs) for hydrogen storage have continued to receive intense interest over the past decade. MOFs are a class of organic-inorganic hybrid crystalline materials consisting of metallic moieties that are linked by strong...

  20. IAHE Hydrogen Civilization Conception for the Humankind Sustainable Future

    International Nuclear Information System (INIS)

    Victor A Goltsov; Lyudmila F Goltsova; T Nejat Veziroglu

    2006-01-01

    There are generalized of a novel Hydrogen Civilization (HyCi-) conception of the International Association for Hydrogen Energy. The HyCi-Conception states that at this rigorous, severe historical period the humankind still has a real possibility to save the biosphere and makes living out of humanity be possible and real process. The above objective can be achieved by the only way, the way of advantageous all-planetary work along the direction of ecologically clean vector 'Hydrogen energy → Hydrogen economy → Hydrogen civilization'. The HyCi-Conception includes three constituent, mutually conditioned parts: industrially-ecological, humanitarian-cultural and geopolitical-internationally legislative ones. Legislative-economical mechanism of transition to hydrogen civilization is formulated, and the most important possible stages of HyCi-transition are indicated and discussed. (authors)

  1. HER2 Gene Amplification Testing by Fluorescent In Situ Hybridization (FISH): Comparison of the ASCO-College of American Pathologists Guidelines With FISH Scores Used for Enrollment in Breast Cancer International Research Group Clinical Trials.

    Science.gov (United States)

    Press, Michael F; Sauter, Guido; Buyse, Marc; Fourmanoir, Hélène; Quinaux, Emmanuel; Tsao-Wei, Denice D; Eiermann, Wolfgang; Robert, Nicholas; Pienkowski, Tadeusz; Crown, John; Martin, Miguel; Valero, Vicente; Mackey, John R; Bee, Valerie; Ma, Yanling; Villalobos, Ivonne; Campeau, Anaamika; Mirlacher, Martina; Lindsay, Mary-Ann; Slamon, Dennis J

    2016-10-10

    Purpose ASCO and the College of American Pathologists (ASCO-CAP) recently recommended further changes to the evaluation of human epidermal growth factor receptor 2 gene (HER2) amplification by fluorescent in situ hybridization (FISH). We retrospectively assessed the impact of these new guidelines by using annotated Breast Cancer International Research Group (BCIRG) -005, BCIRG-006, and BCIRG-007 clinical trials data for which we have detailed outcomes. Patients and Methods The HER2 FISH status of BCIRG-005/006/007 patients with breast cancers was re-evaluated according to current ASCO-CAP guidelines, which designates five different groups according to HER2 FISH ratio and average HER2 gene copy number per tumor cell: group 1 (in situ hybridization [ISH]-positive): HER2-to-chromosome 17 centromere ratio ≥ 2.0, average HER2 copies ≥ 4.0; group 2 (ISH-positive): ratio ≥ 2.0, copies < 4.0; group 3 (ISH-positive): ratio < 2.0, copies ≥ 6.0; group 4 (ISH-equivocal): ratio < 2.0, copies ≥ 4.0 and < 6.0; and group 5 (ISH-negative): ratio < 2.0, copies < 4.0. We assessed correlations with HER2 protein, clinical outcomes by disease-free survival (DFS) and overall survival (OS) and benefit from trastuzumab therapy (hazard ratio [HR]). Results Among 10,468 patients with breast cancers who were successfully screened for trial entry, 40.8% were in ASCO-CAP ISH group 1, 0.7% in group 2; 0.5% in group 3, 4.1% in group 4, and 53.9% in group 5. Distributions were similar in screened compared with accrued subpopulations. Among accrued patients, FISH group 1 breast cancers were strongly correlated with immunohistochemistry 3+ status (P < .0001), whereas groups 2, 3, 4, and 5 were not; however, groups 2, 4 and, 5 were strongly correlated with immunohistochemistry 0/1+ status (all P < .0001), whereas group 3 was not. Among patients accrued to BCIRG-005, group 4 was not associated with significantly worse DFS or OS compared with group 5. Among patients accrued to BCIRG-006, only

  2. Hydrogen in portable devices

    Energy Technology Data Exchange (ETDEWEB)

    Garche, J. [ZSW - Electrochemical Energy storage and energy Conversion Division, Baden Wuerttemberg (Germany); Stimmer, U. [Technische Universitaet, Muenchen (Germany); Friedrich, A.K. [ZAE Bayern (Germany); Fiedenhans' l, R. [Risoe National Lab., Materials Res. Dept., Roskilde (Denmark)

    2004-10-01

    Fuel cells were originally intended for use in power plants and vehicles. More recently, developers realised the possibility for building much smaller units and for lower prices per kilowatt than their larger relatives. This has led to a strong interest in developing small fuel cells. Small fuel cells could replace batteries in portable electronic equipment and internal combustion engines in portable generators. The upper limit for portable generators is about 5kW, mainly because of the weight of the fuel cell. The main applications for low-power fuel cells are mobile phones, personal digital assistants, laptop and notebook computers, cameras, medical equipment, military applications and other portable electronic devices. In comparison to batteries, fuel cells can supply much more power per unit volume or weight, though they have lower output voltages and are slower to respond to transients. Fuel cell types that are suitable for portable applications include: proton exchange membrane fuel cells (PEMFCs) using pure hydrogen, PEMFCs using hydrogen-rich gases from hydrocarbon or alcohol reforming, direct methanol fuel cells and, high-temperature fuel cells such as solid oxide fuel cells (SOFCs) and molten carbonate fuel cells (MCFCs) using hydrocarbons directly. Fuel cells for portable devices is becoming a niche, high-value market area which has good opportunities for a fast introduction of fuel cell technology and for the first consumer products in the electronic market can be expected within the coming year and is believed to grow rapidly thereafter. Danish industry is involved in the development of SOFC, PEMFC and DMFC fuel cells and the industry has in particular a strong position in system components and complete systems. An important area for Danish industry is system integration, where fuel cells and hydrogen technologies are implemented in electrical powered products. This is an area that is particular suited for small and medium sized enterprises and for

  3. Hydrogen in portable devices

    International Nuclear Information System (INIS)

    Garche, J.; Stimmer, U.; Friedrich, A.K.; Fiedenhans'l, R.

    2004-01-01

    Fuel cells were originally intended for use in power plants and vehicles. More recently, developers realised the possibility for building much smaller units and for lower prices per kilowatt than their larger relatives. This has led to a strong interest in developing small fuel cells. Small fuel cells could replace batteries in portable electronic equipment and internal combustion engines in portable generators. The upper limit for portable generators is about 5kW, mainly because of the weight of the fuel cell. The main applications for low-power fuel cells are mobile phones, personal digital assistants, laptop and notebook computers, cameras, medical equipment, military applications and other portable electronic devices. In comparison to batteries, fuel cells can supply much more power per unit volume or weight, though they have lower output voltages and are slower to respond to transients. Fuel cell types that are suitable for portable applications include: proton exchange membrane fuel cells (PEMFCs) using pure hydrogen, PEMFCs using hydrogen-rich gases from hydrocarbon or alcohol reforming, direct methanol fuel cells and, high-temperature fuel cells such as solid oxide fuel cells (SOFCs) and molten carbonate fuel cells (MCFCs) using hydrocarbons directly. Fuel cells for portable devices is becoming a niche, high-value market area which has good opportunities for a fast introduction of fuel cell technology and for the first consumer products in the electronic market can be expected within the coming year and is believed to grow rapidly thereafter. Danish industry is involved in the development of SOFC, PEMFC and DMFC fuel cells and the industry has in particular a strong position in system components and complete systems. An important area for Danish industry is system integration, where fuel cells and hydrogen technologies are implemented in electrical powered products. This is an area that is particular suited for small and medium sized enterprises and for

  4. A Study of Ion-Ion Hybrid Instability in the Mixed Plasma

    Directory of Open Access Journals (Sweden)

    Soo-Yong Kim

    1987-12-01

    Full Text Available There are more oxygen ions than hydrogen ions in the auroral field zone. We consider both analytic and numerical simulation study of the heating of hydrogen and oxygen ions by auroral electrons. With the low drift speed of electron beams, the ion-ion hybrid wave becomes unstable instead of the lower hybrid wave so that a preferential heating of oxygen ions occurs.

  5. Hydrogen separation process

    Science.gov (United States)

    Mundschau, Michael [Longmont, CO; Xie, Xiaobing [Foster City, CA; Evenson, IV, Carl; Grimmer, Paul [Longmont, CO; Wright, Harold [Longmont, CO

    2011-05-24

    A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

  6. Parametric analysis of an irreversible proton exchange membrane fuel cell/absorption refrigerator hybrid system

    International Nuclear Information System (INIS)

    Yang, Puqing; Zhang, Houcheng

    2015-01-01

    A hybrid system mainly consisting of a PEMFC (proton exchange membrane fuel cell) and an absorption refrigerator is proposed, where the PEMFC directly converts the chemical energy contained in the hydrogen into electrical and thermal energies, and the thermal energy is transferred to drive the bottoming absorption refrigerator for cooling purpose. By considering the existing irreversible losses in the hybrid system, the operating current density region of the PEMFC permits the absorption refrigerator to exert its function is determined and the analytical expressions for the equivalent power output and efficiency of the hybrid system under different operating conditions are specified. Numerical calculations show that the equivalent maximum power density and the corresponding efficiency of the hybrid system can be respectively increased by 5.3% and 6.8% compared to that of the stand-alone PEMFC. Comprehensive parametric analyses are conducted to reveal the effects of the internal irreversibility of the absorption refrigerator, operating current density, operating temperature and operating pressure of the PEMFC, and some integrated parameters related to the thermodynamic losses on the performance of the hybrid system. The model presented in the paper is more general than previous study, and the results for some special cases can be directly derived from this paper. - Highlights: • A CHP system composed of a PEMFC and an absorption refrigerator is proposed. • Current density region enables the absorption refrigerator to work is determined. • Multiple irreversible losses in the system are analytically characterized. • Maximum power density and corresponding efficiency can be increased by 5.3% and 6.8%. • Effects of some designing and operating parameters on the performance are discussed

  7. Comparison of the performance of a spark-ignited gasoline engine blended with hydrogen and hydrogen-oxygen mixtures

    International Nuclear Information System (INIS)

    Wang, Shuofeng; Ji, Changwei; Zhang, Jian; Zhang, Bo

    2011-01-01

    This paper compared the effects of hydrogen and hydrogen-oxygen blends (hydroxygen) additions on the performance of a gasoline engine at 1400 rpm and a manifolds absolute pressure of 61.5 kPa. The tests were carried out on a 1.6 L gasoline engine equipped with a hydrogen and oxygen injection system. A hybrid electronic control unit was applied to adjust the hydrogen and hydroxygen volume fractions in the intake increasing from 0% to about 3% and keep the hydrogen-to-oxygen mole ratio at 2:1 in hydroxygen tests. For each testing condition, the gasoline flow rate was adjusted to maintain the mixture global excess air ratio at 1.00. The test results confirmed that engine fuel energy flow rate was decreased after hydrogen addition but increased with hydroxygen blending. When hydrogen or hydroxygen volume fraction in the intake was lower than 2%, the hydroxygen-blended gasoline engine produced a higher thermal efficiency than the hydrogen-blended gasoline engine. Both the additions of hydrogen and hydroxygen help reduce flame development and propagation periods of the gasoline engine. HC emissions were reduced whereas NOx emissions were raised with the increase of hydrogen and hydroxygen addition levels. CO was slightly increased after hydrogen blending, but reduced with hydroxygen addition. -- Highlights: → We compared the effects of hydrogen and hydroxygen additions on the gasoline engine performance. → The hydroxygen should be added into the engine only at low blending levels. → CO is decreased with hydroxygen addition whereas increased with hydrogen blending.

  8. FY 1999 project on the development of new industry support type international standards. Standardization of a measuring method of fuel consumption of hybrid electric vehicles; 1999 nendo shinki sangyo shiengata kokusai hyojun kaihatsu jigyo seika hokokusho. Hybrid denki jidosha no nenpi sokutei hoho no hyojunka

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of proposing a measuring method of fuel consumption of hybrid electric vehicle (HEV) to ISO and internationally standardizing it, test/study were made. The FY 1999 results were summarized. In this fiscal year, the following were conducted using one new vehicle in addition to the two HEVs used in the previous fiscal year: assessment of generative energy at braking, and verification of the results obtained in FY 1998 such as changes in the remaining battery capacity before/after the test. Further, study was made on 'the concretely described contents of each element of the standards' and 'the method to correct changes in battery capacity and improvement in measuring accuracy.' Moreover, the items to be considered at the time of measuring current were made clear. Based on these studies, the making of a draft on the standards was finished. In addition, the measurement by overseas mode was also made, and it was confirmed that this is an effective measuring method also for overseas mode. In the investigational study, standards/papers overseas were surveyed. Exchanges of opinion on the technical background, etc. were also made with persons who are making the same studies overseas for mutual understanding. (NEDO)

  9. Hybrid anode for semiconductor radiation detectors

    Science.gov (United States)

    Yang, Ge; Bolotnikov, Aleksey E; Camarda, Guiseppe; Cui, Yonggang; Hossain, Anwar; Kim, Ki Hyun; James, Ralph B

    2013-11-19

    The present invention relates to a novel hybrid anode configuration for a radiation detector that effectively reduces the edge effect of surface defects on the internal electric field in compound semiconductor detectors by focusing the internal electric field of the detector and redirecting drifting carriers away from the side surfaces of the semiconductor toward the collection electrode(s).

  10. Hybridized Tetraquarks

    CERN Document Server

    Esposito, A.; Polosa, A.D.

    2016-01-01

    We propose a new interpretation of the neutral and charged X, Z exotic hadron resonances. Hybridized-tetraquarks are neither purely compact tetraquark states nor bound or loosely bound molecules. The latter would require a negative or zero binding energy whose counterpart in h-tetraquarks is a positive quantity. The formation mechanism of this new class of hadrons is inspired by that of Feshbach metastable states in atomic physics. The recent claim of an exotic resonance in the Bs pi+- channel by the D0 collaboration and the negative result presented subsequently by the LHCb collaboration are understood in this scheme, together with a considerable portion of available data on X, Z particles. Considerations on a state with the same quantum numbers as the X(5568) are also made.

  11. FY 1998 annual summary report on International Clean Energy Network Using Hydrogen Conversion (WE-NET) system technology. Subtask 9. Research and evaluation of innovative and leading technologies; 1998 nendo seika hokokusho. Suiso riyo kokusai clean energy system gijutsu (WE-NET) subtask 9 (kakushinteki, sendoteki gijutsu ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    In order to make useful suggestions and proposals for the International Clean Energy Network Using Hydrogen Conversion (WE-NET) project and thereby to promote the research and development activities, the innovative and leading technologies have been studied, investigated and evaluated. In FY 1998, a total of 6 proposals were collected, and evaluated to prioritize for the conceptual studies. These are related to methanol-fueled power generation turbine system, conceptual design of high-efficiency production system for high-efficiency solar cell by the 10 GW/y scale production process, investigation of potential of wind power, CO2 recycling methanol fuel cell, investigation of catalysis materials for hydrogen combustion and catalytic combustion systems, development of reversible high-temperature steam electrolysis cell/solid oxide fuel cell by the synthesis from aqueous solutions, and mobile heat recovery hydrogen production system. Promising technologies to be reflected on the WE-NET project were examined, based on the new technologies acquired from the research and investigation so far. As a result, two candidates were selected; hydrogen liquefaction by magnetic refrigeration technology, and catalytic combustion gas turbine. (NEDO)

  12. Large eddy simulation of turbulent diffusion flame with hybrid fuel of CH4/H2 in various background conditions

    Science.gov (United States)

    Hong, Sungmin; Lee, Wook; Song, Han Ho; Kang, Seongwon

    2014-11-01

    A turbulent diffusion flame with hybrid fuel of methane and hydrogen is analyzed to investigate the effects of operating conditions on flame shape, rate of fuel consumption and pollutant formation. Various combinations of operating parameter, i.e. hydrogen concentration, background pressure and temperature, are examined in relatively high pressure and temperature conditions that can be found at the end of compression stroke in an internal combustion engine. A flamelet-progress variable approach (FPVA) and a dynamic subgrid scale (SGS) model are used for large eddy simulation (LES). A comparison with previous experiments and simulations in the standard condition shows a good agreement in the statistics of flow fields and chemical compositions, as well as in the resultant trends by similar parametric studies. As a result, the effects of added hydrogen are found to be consistent for most of the chemical species in the range of background pressure and temperature conditions. However, the flow fields of some species such as OH, NO, CO at a higher pressure and temperature state show a behavior different from the standard condition. Finally, hydrogen addition is shown to improve flame stability which is measured by the pressure fluctuations in all the tested conditions.

  13. Fiscal 1999 phase 2 R and D report of WE-NET (International Clean Energy Network Using Hydrogen Conversion). Task 9. Development of liquid hydrogen transport and storage technology Part 3 (Concept design of hydrogen liquefaction facility); 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu seika hokokusho. Task 9. Ekika suiso yuso chozo gijutsu no kaihatsu 3 (suiso ekika setsubi no gainen sekkei)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This report summarizes the fiscal 1999 research result on the aerodynamic design and seal design necessary for development of advanced hydrogen compressors for large-scale hydrogen liquefiers in the WE-NET plan. In the study on aerodynamic performance of impellers, 3-D viscous flow analysis of 2 types of new impeller forms (20 and 15 degrees) was carried out based on the study result on backward angle. The 2-D viscous flow analysis result on diffuser suitable for hydrogen compressors showed that improvement of the performance of a NACA65 type profile diffuser is possible. The study result on scale effect by using Casy's evaluation formula showed the efficiency difference of nearly 2.6% between impeller diameters of 1000mm and 300mm at 0.08 in exit width ratio. Study was made on hydrogen gas leak for spiral groove sealing selected as hydrogen gas sealing. The study on small capacity hydrogen liquefiers was conducted on the same process cycle as the 11t/d liquefier which has been commercially available. (NEDO)

  14. Solar Hydrogen Reaching Maturity

    Directory of Open Access Journals (Sweden)

    Rongé Jan

    2015-09-01

    Full Text Available Increasingly vast research efforts are devoted to the development of materials and processes for solar hydrogen production by light-driven dissociation of water into oxygen and hydrogen. Storage of solar energy in chemical bonds resolves the issues associated with the intermittent nature of sunlight, by decoupling energy generation and consumption. This paper investigates recent advances and prospects in solar hydrogen processes that are reaching market readiness. Future energy scenarios involving solar hydrogen are proposed and a case is made for systems producing hydrogen from water vapor present in air, supported by advanced modeling.

  15. Canada's hydrogen energy sector

    International Nuclear Information System (INIS)

    Kimmel, T.B.

    2009-01-01

    Canada produces the most hydrogen per capita of any Organization of Economic Cooperation and Development (OECD) country. The majority of this hydrogen is produced by steam methane reforming for industrial use (predominantly oil upgrading and fertilizer production). Canada also has a world leading hydrogen and fuel cell sector. This sector is seeking new methods for making hydrogen for its future energy needs. The paper will discuss Canada's hydrogen and fuel cell sector in the context of its capabilities, its demonstration and commercialization activities and its stature on the world stage. (author)

  16. Neurotoxic injury pathways in differentiated mouse motor neuron–neuroblastoma hybrid (NSC-34D) cells in vitro—Limited effect of riluzole on thapsigargin, but not staurosporine, hydrogen peroxide and homocysteine neurotoxicity

    Energy Technology Data Exchange (ETDEWEB)

    Hemendinger, Richelle A., E-mail: richelle.hemendinger@carolinashealthcare.org [ALS Translational Neuroscience Laboratory, Carolinas Medical Center, Charlotte, NC 28203 (United States); Carolinas Neuromuscular/ALS-MDA Center, Department of Neurology, Carolinas Medical Center, Charlotte, NC 28203 (United States); Armstrong, Edward J. [ALS Translational Neuroscience Laboratory, Carolinas Medical Center, Charlotte, NC 28203 (United States); Carolinas Neuromuscular/ALS-MDA Center, Department of Neurology, Carolinas Medical Center, Charlotte, NC 28203 (United States); Radio, Nick [ThermoScientific, Pittsburgh, PA (United States); Brooks, Benjamin Rix [ALS Translational Neuroscience Laboratory, Carolinas Medical Center, Charlotte, NC 28203 (United States); Carolinas Neuromuscular/ALS-MDA Center, Department of Neurology, Carolinas Medical Center, Charlotte, NC 28203 (United States); University of North Carolina School of Medicine-Charlotte Campus (United States)

    2012-01-15

    The neuroblastoma–spinal motor neuron fusion cell line, NSC-34, in its differentiated form, NSC-34D, permits examining the effects of riluzole, a proven treatment for amyotrophic lateral sclerosis (ALS) on cell death induction by staurosporine (STS), thapsigargin (Thaps), hydrogen peroxide (H{sub 2}O{sub 2}) and homocysteine (HCy). These neurotoxins, applied exogenously, have mechanisms of action related to the various proposed molecular pathogenetic pathways in ALS and are differentiated from endogenous cell death that is associated with cytoplasmic aggregate formation in motor neurons. Nuclear morphology, caspase-3/7 activation and high content imaging were used to assess toxicity of these neurotoxins with and without co-treatment with riluzole, a benzothiazole compound with multiple pharmacological actions. STS was the most potent neurotoxin at killing NSC-34D cells with a toxic concentration at which 50% of maximal cell death is achieved (TC{sub 50} = 0.01 μM), followed by Thaps (TC{sub 50} = 0.9 μM) and H{sub 2}O{sub 2} (TC{sub 50} = 15 μM) with HCy requiring higher concentrations to kill at the same level (TC{sub 50} = 2200 μM). Riluzole provided neurorescue with a 20% absolute reduction (47.6% relative reduction) in apoptotic cell death against Thaps-induced NSC-34D cell (p ≤ 0.05), but had no effect on STS-, H{sub 2}O{sub 2}- and HCy-induced NSC-34D cell death. This effect of riluzole on Thaps induction of cell death was independent of caspase-3/7 activation. Riluzole mitigated a toxin that can cause intracellular calcium dysregulation associated with endoplasmic reticulum (ER) stress but not toxins associated with other cell death mechanisms. -- Highlights: ► Calcium-dependent neurotoxins are potent cell death inducers in NSC-34D cells. ► Riluzole provides neurorescue against Thaps-induced NSC-34D cell death. ► Riluzole had no effect on neurotoxicity by STS, H{sub 2}O{sub 2} and Hcy. ► Riluzole reduces NSC-34D cell death independent of

  17. The cost analysis of hydrogen life cycle in China

    International Nuclear Information System (INIS)

    Yao, Fei; Jia, Yuan; Mao, Zongqiang

    2010-01-01

    Currently, the increasing price of oil and the possibility of global energy crisis demand for substitutive energy to replace fossil energy. Many kinds of renewable energy have been considered, such as hydrogen, solar energy, and wind energy. Many countries including China have their own plan to support the research of hydrogen, because of its premier features. But, at present, the cost of hydrogen energy production, storage and transportation process is higher than that of fossil energy and its commercialization progress is slow. Life cycle cost analysis (LCCA) was used in this paper to evaluate the cost of hydrogen energy throughout the life cycle focused on the stratagem selection, to demonstrate the costs of every step and to discuss their relationship. Finally, the minimum cost program is as follows: natural gas steam reforming - high-pressure hydrogen bottles transported by car to hydrogen filling stations - hydrogen internal-combustion engines. (author)

  18. Hydrogen transport behavior of beryllium

    Energy Technology Data Exchange (ETDEWEB)

    Anderl, R.A.; Hankins, M.R.; Longhurst, G.R.; Pawelko, R.J. (Idaho National Engineering Lab., EG and G Idaho, Inc., Idaho Falls, ID (United States)); Macaulay-Newcombe, R.G. (Dept. of Engineering Physics, Univ. Hamilton, ON (Canada))

    1992-12-01

    Beryllium is being evaluated for use as a plasma-facing material in the International Thermonuclear Experimental Reactor (ITER). One concern in the evaluation is the retention and permeation of tritium implanted into the plasma-facing surface. We performed laboratory-scale studies to investigate mechanisms that influence hydrogen transport and retention in beryllium foil specimens of rolled powder metallurgy product and rolled ingot cast beryllium. Specimen characterization was accomplished using scanning electron microscopy. Auger electron spectroscopy, and Rutherford backscattering spectrometry (RBS) techniques. Hydrogen transport was investigated using ion-beam permeation experiments and nuclear reaction analysis (NRA). Results indicate that trapping plays a significant role in permeation, re-emission, and retention, and that surface processes at both upstream and downstream surfaces are also important. (orig.).

  19. Hydrogen axion star: metallic hydrogen bound to a QCD axion BEC

    Energy Technology Data Exchange (ETDEWEB)

    Bai, Yang; Barger, Vernon; Berger, Joshua [Department of Physics, University of Wisconsin-Madison,1150 University Ave, Madison, WI 53706 (United States)

    2016-12-23

    As a cold dark matter candidate, the QCD axion may form Bose-Einstein condensates, called axion stars, with masses around 10{sup −11} M{sub ⊙}. In this paper, we point out that a brand new astrophysical object, a Hydrogen Axion Star (HAS), may well be formed by ordinary baryonic matter becoming gravitationally bound to an axion star. We study the properties of the HAS and find that the hydrogen cloud has a high pressure and temperature in the center and is likely in the liquid metallic hydrogen state. Because of the high particle number densities for both the axion star and the hydrogen cloud, the feeble interaction between axion and hydrogen can still generate enough internal power, around 10{sup 13} W×(m{sub a}/5 meV){sup 4}, to make these objects luminous point sources. High resolution ultraviolet, optical and infrared telescopes can discover HAS via black-body radiation.

  20. About connection between atomic and hydrogen energy power

    International Nuclear Information System (INIS)

    Avdeeva, M.Zh.; Vecher, A.A.; Pan'kov, V.V.

    2008-01-01

    Possible interaction between atomic and hydrogen energy power has been discussed. The analysis of the result held shows that the electrical energy produced by the atomic reactor during the of-load hours can be involved into the process of obtaining hydrogen by electrolysis. In order to optimize the transportation and storage of hydrogen it is proposed to convert it into ammonia. The direct uses of ammonia as a fuel into the internal combustion engine and fuel cells are examined. (authors)