WorldWideScience

Sample records for hydrogen fueled light

  1. Project Profile: Hydrogen Fuel Cell Mobile Lighting Tower (HFCML)

    Science.gov (United States)

    McLaughlin, Russell

    2013-01-01

    NASA is committed to finding innovative solutions that improve the operational performance of ground support equipment while providing environment and cost benefits, as well. Through the Hydrogen Fuel Cell Mobile Lighting Tower (HFCML) project, NASA gained operational exposure to a novel application of high efficiency technologies. Traditionally, outdoor lighting and auxiliary power at security gates, launch viewing sites, fallback areas, outage support, and special events is provided by diesel generators with metal halide lights. Diesel generators inherently contribute to C02, NOx, particulate emissions, and are very noisy. In 2010, engineers from NASA's Technology Evaluation for Environmental Risk Mitigation Principal Center (TEERM) introduced KSC operations to a novel technology for outdoor lighting needs. Developed by a team led by Sandia National Laboratory (SNL), the technology pairs a 5kW hydrogen fuel cell with robust high efficiency plasma lights in a towable trailer. Increased efficiency, in both the fuel cell power source and lighting load, yields longer run times between fueling operations while providing greater auxiliary power. Because of the unit's quiet operation and no exhaust fumes, it is capable of being used indoors and in emergency situations, and meets the needs of all other operational roles for metal halide/diesel generators. The only discharge is some water and warm air. Environmental benefits include elimination of diesel particulate emissions and estimated 73% greenhouse gas emissions savings when the hydrogen source is natural gas (per GREET model). As the technology matures the costs could become competitive for the fuel cell units which are approximately 5 times diesel units. Initial operational . concerns included the hydrogen storage tanks and valves, lightning safety/grounding, and required operating and refueling procedures. TEERM facilitated technical information exchange (design drawings, technical standards, and operations

  2. Development of the on-demand fuel injection system for a light truck using the hydrogen enriched compressed natural gas (HCNG) fuel

    OpenAIRE

    Sarawoot Watechagit; Ruangdet Panduang; Natthaporn Prommakorn; Peeraya Siriput; Yaowateera Achawangkul; Bunyongvut Chullabodhi

    2014-01-01

    The use of hydrogen as a fuel by mixing with a commercial fuel has recently been investigated continuously in order to solve the energy crisis and global warming. This article presents the results of the design and experimentation for the use of the hydrogen enriched compressed natural gas or HCNG as a fuel. The prototype vehicle a light truck equipped with a 1809 cc. gasoline engine. The proposed system is a mixing system where the compressed natural gas and the hydrogen are stored on-board ...

  3. Hydrogen Fuel Cell Vehicles

    OpenAIRE

    Delucchi, Mark

    1992-01-01

    Hydrogen is an especially attractive transportation fuel. It is the least polluting fuel available, and can be produced anywhere there is water and a clean source of electricity. A fuel cycle in which hydrogen is produced by solar-electrolysis of water, or by gasification of renewably grown biomass, and then used in a fuel-cell powered electric-motor vehicle (FCEV), would produce little or no local, regional, or global pollution. Hydrogen FCEVs would combine the best features of bat...

  4. Development of the on-demand fuel injection system for a light truck using the hydrogen enriched compressed natural gas (HCNG fuel

    Directory of Open Access Journals (Sweden)

    Sarawoot Watechagit

    2014-06-01

    Full Text Available The use of hydrogen as a fuel by mixing with a commercial fuel has recently been investigated continuously in order to solve the energy crisis and global warming. This article presents the results of the design and experimentation for the use of the hydrogen enriched compressed natural gas or HCNG as a fuel. The prototype vehicle a light truck equipped with a 1809 cc. gasoline engine. The proposed system is a mixing system where the compressed natural gas and the hydrogen are stored on-board and controlled separately. They are mixed as they are injected into the intake manifold right before the intake-port (Port Injection. The hydrogen supply system used in this investigation is adopted from the common system used for compressed natural gas system. The mixing ratio (%H in the total volume of HCNG ranges from 5% to 20% by volume. The performance testing is done through the Chassis Dynamometer. The results show that the power and the torque of the engine drops when using either CNG or HCNG as compared to the gasoline fuel. However, when compared to the case when using the CNG, the 10% addition of hydrogen can increase the performance by 1%. The performance, on the other hands, is reduced for other amount of hydrogen additions.

  5. Hydrogen vehicle fueling station

    Energy Technology Data Exchange (ETDEWEB)

    Daney, D.E.; Edeskuty, F.J.; Daugherty, M.A. [Los Alamos National Lab., NM (United States)] [and others

    1995-09-01

    Hydrogen fueling stations are an essential element in the practical application of hydrogen as a vehicle fuel, and a number of issues such as safety, efficiency, design, and operating procedures can only be accurately addressed by a practical demonstration. Regardless of whether the vehicle is powered by an internal combustion engine or fuel cell, or whether the vehicle has a liquid or gaseous fuel tank, the fueling station is a critical technology which is the link between the local storage facility and the vehicle. Because most merchant hydrogen delivered in the US today (and in the near future) is in liquid form due to the overall economics of production and delivery, we believe a practical refueling station should be designed to receive liquid. Systems studies confirm this assumption for stations fueling up to about 300 vehicles. Our fueling station, aimed at refueling fleet vehicles, will receive hydrogen as a liquid and dispense it as either liquid, high pressure gas, or low pressure gas. Thus, it can refuel any of the three types of tanks proposed for hydrogen-powered vehicles -- liquid, gaseous, or hydride. The paper discusses the fueling station design. Results of a numerical model of liquid hydrogen vehicle tank filling, with emphasis on no vent filling, are presented to illustrate the usefulness of the model as a design tool. Results of our vehicle performance model illustrate our thesis that it is too early to judge what the preferred method of on-board vehicle fuel storage will be in practice -- thus our decision to accommodate all three methods.

  6. Hydrogen: Fueling the Future

    Energy Technology Data Exchange (ETDEWEB)

    Leisch, Jennifer

    2007-02-27

    As our dependence on foreign oil increases and concerns about global climate change rise, the need to develop sustainable energy technologies is becoming increasingly significant. Worldwide energy consumption is expected to double by the year 2050, as will carbon emissions along with it. This increase in emissions is a product of an ever-increasing demand for energy, and a corresponding rise in the combustion of carbon containing fossil fuels such as coal, petroleum, and natural gas. Undisputable scientific evidence indicates significant changes in the global climate have occurred in recent years. Impacts of climate change and the resulting atmospheric warming are extensive, and know no political or geographic boundaries. These far-reaching effects will be manifested as environmental, economic, socioeconomic, and geopolitical issues. Offsetting the projected increase in fossil energy use with renewable energy production will require large increases in renewable energy systems, as well as the ability to store and transport clean domestic fuels. Storage and transport of electricity generated from intermittent resources such as wind and solar is central to the widespread use of renewable energy technologies. Hydrogen created from water electrolysis is an option for energy storage and transport, and represents a pollution-free source of fuel when generated using renewable electricity. The conversion of chemical to electrical energy using fuel cells provides a high efficiency, carbon-free power source. Hydrogen serves to blur the line between stationary and mobile power applications, as it can be used as both a transportation fuel and for stationary electricity generation, with the possibility of a distributed generation energy infrastructure. Hydrogen and fuel cell technologies will be presented as possible pollution-free solutions to present and future energy concerns. Recent hydrogen-related research at SLAC in hydrogen production, fuel cell catalysis, and hydrogen

  7. Effect of Light/Dark Regimens on Hydrogen Production by Tetraselmis subcordiformis Coupled with an Alkaline Fuel Cell System.

    Science.gov (United States)

    Guo, Zhen; Li, Ying; Guo, Haiyan

    2017-12-01

    To improve the photoproduction of hydrogen (H2) by a green algae-based system, the effect of light/dark regimens on H2 photoproduction regulated by carbonyl cyanide m-chlorophenylhydrazone (CCCP) was investigated. A fuel cell was integrated into a photobioreactor to allow online monitoring of the H2 evolution rate and decrease potential H2 feedback inhibition by consuming the generated H2 in situ. During the first 15 h of H2 evolution, the system was subjected to dark treatment after initial light illumination (L/D = 6/9 h, 9/6 h, and 12/3 h). After the dark period, all systems were again exposed to light illumination until H2 evolution stopped. Two peaks were observed in the H2 evolution rate under all three light/dark regimens. Additionally, a high H2 yield of 126 ± 10 mL L-1 was achieved using a light/dark regimen of L 9 h/D 6 h/L until H2 production ceased, which was 1.6 times higher than that obtained under continuous illumination. H2 production was accompanied by some physiological and morphological changes in the cells. The results indicated that light/dark regimens improved the duration and yield of H2 photoproduction by the CCCP-regulated process of Tetraselmis subcordiformis.

  8. Hydrogen-enriched fuels

    Energy Technology Data Exchange (ETDEWEB)

    Roser, R. [NRG Technologies, Inc., Reno, NV (United States)

    1998-08-01

    NRG Technologies, Inc. is attempting to develop hardware and infrastructure that will allow mixtures of hydrogen and conventional fuels to become viable alternatives to conventional fuels alone. This commercialization can be successful if the authors are able to achieve exhaust emission levels of less than 0.03 g/kw-hr NOx and CO; and 0.15 g/kw-hr NMHC at full engine power without the use of exhaust catalysts. The major barriers to achieving these goals are that the lean burn regimes required to meet exhaust emissions goals reduce engine output substantially and tend to exhibit higher-than-normal total hydrocarbon emissions. Also, hydrogen addition to conventional fuels increases fuel cost, and reduces both vehicle range and engine output power. Maintaining low emissions during transient driving cycles has not been demonstrated. A three year test plan has been developed to perform the investigations into the issues described above. During this initial year of funding research has progressed in the following areas: (a) a cost effective single-cylinder research platform was constructed; (b) exhaust gas speciation was performed to characterize the nature of hydrocarbon emissions from hydrogen-enriched natural gas fuels; (c) three H{sub 2}/CH{sub 4} fuel compositions were analyzed using spark timing and equivalence ratio sweeping procedures and finally; (d) a full size pick-up truck platform was converted to run on HCNG fuels. The testing performed in year one of the three year plan represents a baseline from which to assess options for overcoming the stated barriers to success.

  9. Hydrogen fuel dispensing station for transportation vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Singh, S.P.N.; Richmond, A.A. [Oak Ridge National Lab., TN (United States). Chemical Technology Div.

    1995-07-01

    A technical and economic assessment is being conducted of a hydrogen fuel dispensing station to develop an understanding of the infrastructure requirements for supplying hydrogen fuel for mobile applications. The study includes a process design of a conceptual small-scale, stand-alone, grassroots fuel dispensing facility (similar to the present-day gasoline stations) producing hydrogen by steam reforming of natural gas. Other hydrogen production processes (such as partial oxidation of hydrocarbons and water electrolysis) were reviewed to determine their suitability for manufacturing the hydrogen. The study includes an assessment of the environmental and other regulatory permitting requirements likely to be imposed on a hydrogen fuel dispensing station for transportation vehicles. The assessment concludes that a dispensing station designed to produce 0.75 million standard cubic feet of fuel grade (99.99%+ purity) hydrogen will meet the fuel needs of 300 light-duty vehicles per day. Preliminary economics place the total capital investment (in 1994 US dollars) for the dispensing station at $4.5 million and the annual operating costs at around $1 million. A discounted cash-flow analysis indicates that the fuel hydrogen product price (excluding taxes) to range between $1.37 to $2.31 per pound of hydrogen, depending upon the natural gas price, the plant financing scenario, and the rate of return on equity capital. A report on the assessment is due in June 1995. This paper presents a summary of the current status of the assessment.

  10. Hydrogen as aviation fuel: a comparison with hydrocarbon fuels

    Energy Technology Data Exchange (ETDEWEB)

    Contreras, A. [UNED Ciudad Universitaria, Quimica Aplicada a la Ingenieria Dept., Madrid (Spain); Yigit, S.; Ozay, K.; Veziroglu, T.N. [Miami Univ., Clean Energy Research Inst., Coral Gables, FL (United States)

    1997-12-31

    Depletion of fossil fuels and environmental considerations have led engineers and scientists to anticipate the need to develop a clean, renewable and sustainable energy system. In general, they agree that in such a system hydrogen will be used as an energy carrier. One of the areas in which hydrogen will be replacing fossil fuels is air transportation, an area that has been under research for several decades. Hydrogen as an energy carrier for use in airplanes has some unique attributes like global availability, safety, minimum pollution and light weight, making it an ideal fuel. This paper briefly reviews hydrogen as a fuel in aviation, compares it with other aviation fuels, and discusses the possible future developments and the goals in this field. (Author)

  11. Performance assessment of 700-bar compressed hydrogen storage for light duty fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Hua, Thanh Q.; Roh, Hee-Seok; Ahluwalia, Rajesh K.

    2017-10-01

    Type 4 700-bar compressed hydrogen storage tanks were modeled using ABAQUS. The finite element model was first calibrated against data for 35-L subscale test tanks to obtain the composite translation efficiency, and then applied to full sized tanks. Two variations of the baseline T700/epoxy composite were considered in which the epoxy was replaced with a low cost vinyl ester resin and low cost resin with an alternate sizing. The results showed that the reduction in composite weight was attributed primarily to the lower density of the resin and higher fiber volume fraction in the composite due to increased squeeze-out with the lower viscosity vinyl ester resin. The system gravimetric and volumetric capacities for the onboard storage system that holds 5.6 kg H-2 are 4.2 wt% (1.40 kWh/kg) and 24.4 g-H-2/L (0.81 kWh/L), respectively. The system capacities increase and carbon fiber requirement decreases if the in-tank amount of unrecoverable hydrogen is reduced by lowering the tank "empty" pressure. Models of an alternate tank design showed potential 4-7% saving in composite usage for tanks with a length-to-diameter (L/D) ratio of 2.8-3.0 but no saving for L/D of 1.7. A boss with smaller opening and longer flange does not appear to reduce the amount of helical windings.

  12. Water reactive hydrogen fuel cell power system

    Science.gov (United States)

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-11-25

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  13. Water reactive hydrogen fuel cell power system

    Science.gov (United States)

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-01-21

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  14. Hydrogen Generation Via Fuel Reforming

    Science.gov (United States)

    Krebs, John F.

    2003-07-01

    Reforming is the conversion of a hydrocarbon based fuel to a gas mixture that contains hydrogen. The H2 that is produced by reforming can then be used to produce electricity via fuel cells. The realization of H2-based power generation, via reforming, is facilitated by the existence of the liquid fuel and natural gas distribution infrastructures. Coupling these same infrastructures with more portable reforming technology facilitates the realization of fuel cell powered vehicles. The reformer is the first component in a fuel processor. Contaminants in the H2-enriched product stream, such as carbon monoxide (CO) and hydrogen sulfide (H2S), can significantly degrade the performance of current polymer electrolyte membrane fuel cells (PEMFC's). Removal of such contaminants requires extensive processing of the H2-rich product stream prior to utilization by the fuel cell to generate electricity. The remaining components of the fuel processor remove the contaminants in the H2 product stream. For transportation applications the entire fuel processing system must be as small and lightweight as possible to achieve desirable performance requirements. Current efforts at Argonne National Laboratory are focused on catalyst development and reactor engineering of the autothermal processing train for transportation applications.

  15. Hydrogen storage and fuel cells

    Science.gov (United States)

    Liu, Di-Jia

    2018-01-01

    Global warming and future energy supply are two major challenges facing American public today. To overcome such challenges, it is imperative to maximize the existing fuel utilization with new conversion technologies while exploring alternative energy sources with minimal environmental impact. Hydrogen fuel cell represents a next-generation energy-efficient technology in transportation and stationary power productions. In this presentation, a brief overview of the current technology status of on-board hydrogen storage and polymer electrolyte membrane fuel cell in transportation will be provided. The directions of the future researches in these technological fields, including a recent "big idea" of "H2@Scale" currently developed at the U. S. Department of Energy, will also be discussed.

  16. Comparing hydrogen and hydrocarbon booster fuels

    Science.gov (United States)

    Martin, James A.

    1988-01-01

    The present evaluation of the consequences of hydrogen and hydrocarbon fuels as the basis of launch vehicle booster rocket-stage performance notes that hydrocarbon fuels lead to lower vehicle dry mass, for low-velocity requirements, while hydrogen fuel furnishes lower dry mass. Vehicles employing both types of fuel attempt to take advantage of the low intercept and slope of hydrocarbon fuel at low velocity, and subsequently, of the slope of the hydrogen curves at higher velocities.

  17. Hydrogen and fuel cells; Hydrogene et piles a combustible

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-06-15

    This road-map proposes by the Group Total aims to inform the public on the hydrogen and fuel cells. It presents the hydrogen technology from the production to the distribution and storage, the issues as motor fuel and fuel cells, the challenge for vehicles applications and the Total commitments in the domain. (A.L.B.)

  18. Hydrogen and Gaseous Fuel Safety and Toxicity

    Energy Technology Data Exchange (ETDEWEB)

    Lee C. Cadwallader; J. Sephen Herring

    2007-06-01

    Non-traditional motor fuels are receiving increased attention and use. This paper examines the safety of three alternative gaseous fuels plus gasoline and the advantages and disadvantages of each. The gaseous fuels are hydrogen, methane (natural gas), and propane. Qualitatively, the overall risks of the four fuels should be close. Gasoline is the most toxic. For small leaks, hydrogen has the highest ignition probability and the gaseous fuels have the highest risk of a burning jet or cloud.

  19. National FCEV and Hydrogen Fueling Station Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Bush, Brian; Melaina, Marc

    2016-06-09

    This presentation provides a summary of the FY16 activities and accomplishments for NREL's national fuel cell electric vehicle (FCEV) and hydrogen fueling station scenarios project. It was presented at the U.S. Department of Energy Hydrogen and Fuel Cells Program 2016 Annual Merit Review and Peer Evaluation Meeting on June 9, 2016, in Washington, D.C.

  20. Hydrogen storage and integrated fuel cell assembly

    Science.gov (United States)

    Gross, Karl J.

    2010-08-24

    Hydrogen is stored in materials that absorb and desorb hydrogen with temperature dependent rates. A housing is provided that allows for the storage of one or more types of hydrogen-storage materials in close thermal proximity to a fuel cell stack. This arrangement, which includes alternating fuel cell stack and hydrogen-storage units, allows for close thermal matching of the hydrogen storage material and the fuel cell stack. Also, the present invention allows for tailoring of the hydrogen delivery by mixing different materials in one unit. Thermal insulation alternatively allows for a highly efficient unit. Individual power modules including one fuel cell stack surrounded by a pair of hydrogen-storage units allows for distribution of power throughout a vehicle or other electric power consuming devices.

  1. Maximizing Light Utilization Efficiency and Hydrogen Production in Microalgal Cultures

    Energy Technology Data Exchange (ETDEWEB)

    Melis, Anastasios [Univ. of California, Berkeley, CA (United States)

    2014-12-31

    The project addressed the following technical barrier from the Biological Hydrogen Production section of the Fuel Cell Technologies Program Multi-Year Research, Development and Demonstration Plan: Low Sunlight Utilization Efficiency in Photobiological Hydrogen Production is due to a Large Photosystem Chlorophyll Antenna Size in Photosynthetic Microorganisms (Barrier AN: Light Utilization Efficiency).

  2. Solar-Hydrogen Fuel-Cell Vehicles

    OpenAIRE

    DeLuchi, Mark A.; Ogden, Joan M.

    1993-01-01

    Hydrogen is an especially attractive transportation fuel. It is the least polluting fuel available, and can be produced anywhere there is water and a clean source of electricity. A fuel cycle in which hydrogen is produced by solar-electrolysis of water, or by gasification of renewably grown biomass, and then used in a fuel-cell powered electric-motor vehicle (FCEV), would produce little or no local, regional or global pollution. Hydrogen FCEVs would combine the best features of battery-powere...

  3. Hydrogen: The Ultimate Fuel and Energy Carrier.

    Science.gov (United States)

    Dinga, Gustav P.

    1988-01-01

    Lists 24 frequently asked questions concerning hydrogen as a fuel with several responses given to each question. Emphasized are hydrogen production, storage, transmission, and application to various energy-consuming sectors. Summarizes current findings and research on hydrogen. An extensive bibliography is included. (ML)

  4. Hydrogen Fuel Cell Engines and Related Technologies

    Science.gov (United States)

    2001-12-01

    The Hydrogen Fuel Cell Engines and Related Technologies report documents the first training course ever developed and made available to the transportation community and general public on the use hydrogen fuel cells in transportation. The course is designed to train a new generation of technicians in gaining a more complete understanding of the concepts, procedures, and technologies involved with hydrogen fuel cell use in transportation purposes. The manual contains 11 modules (chapters). The first eight modules cover (1) hydrogen properties, use and safety; and (2) fuel cell technology and its systems, fuel cell engine design and safety, and design and maintenance of a heavy duty fuel cell bus engine. The different types of fuel cells and hybrid electric vehicles are presented, however, the system descriptions and maintenance procedures focus on proton-exchange-membrane (PEM) fuel cells with respect to heavy duty transit applications. Modules 9 and 10 are intended to provide a better understanding of the acts, codes, regulations and guidelines concerning the use of hydrogen, as well as the safety guidelines for both hydrogen maintenance and fueling facilities. Module 11 presents a glossary and conversions.

  5. Hydrogen Fuel Cells: Part of the Solution

    Science.gov (United States)

    Busby, Joe R.; Altork, Linh Nguyen

    2010-01-01

    With the decreasing availability of oil and the perpetual dependence on foreign-controlled resources, many people around the world are beginning to insist on alternative fuel sources. Hydrogen fuel cell technology is one answer to this demand. Although modern fuel cell technology has existed for over a century, the technology is only now becoming…

  6. Fuel Cell Electrodes for Hydrogen-Air Fuel Cell Assemblies.

    Science.gov (United States)

    The report describes the design and evaluation of a hydrogen-air fuel cell module for use in a portable hydrid fuel cell -battery system. The fuel ... cell module consists of a stack of 20 single assemblies. Each assembly contains 2 electrically independent cells with a common electrolyte compartment

  7. Chrysler Pentastar direct hydrogen fuel cell program

    Energy Technology Data Exchange (ETDEWEB)

    Kimble, M.; Deloney, D.

    1995-08-01

    The Chrysler Pentastar Electronics, Inc. Direct Hydrogen Fueled PEM Fuel Cell Hybrid Vehicle Program (DPHV) was initiated 1 July, 1994 with the following mission, {open_quotes}Design, fabricate, and test a Direct Hydrogen Fueled Proton Exchange Membrane (PEM) Fuel Cell System including onboard hydrogen storage, an efficient lightweight fuel cell, a gas management system, peak power augmentation and a complete system controls that can be economically mass produced and comply with all safety environmental and consumer requirements for vehicle applications for the 21st century.{close_quotes} The Conceptual Design for the entire system based upon the selection of an applicable vehicle and performance requirements that are consistent with the PNGV goals will be discussed. A Hydrogen Storage system that has been selected, packaged, and partially tested in accordance with perceived Hydrogen Safety and Infrastructure requirements will be discussed in addition to our Fuel Cell approach along with design of the {open_quotes}real{close_quotes} module. The Gas Management System and the Load Leveling System have been designed and the software programs have been developed and will be discussed along with a complete fuel cell test station that has the capability to test up to a 60 kW fuel cell system.

  8. Hydrogen Storage in Nanostructured Light Metal Hydrides

    NARCIS (Netherlands)

    Singh, S.

    2009-01-01

    The global energy issues can be solved by the abundantly available hydrogen on earth. Light metals are a compact and safe medium for storing hydrogen. This makes them attractive for vehicular use. Unfortunately, hydrogen uptake and release is slow in light metals at practical temperature and

  9. Coupling hydrogen fuel and carbonless utilities

    Energy Technology Data Exchange (ETDEWEB)

    Berry, G.D. [Lawrence Livermore National Lab., CA (United States)

    1998-08-01

    A number of previous analyses have focused on comparisons of single hydrogen vehicles to petroleum and alternative fuel vehicles or of stationary hydrogen storage for utility or local power applications. LLNL`s approach is to compare combined transportation/utility storage systems using hydrogen and fossil fuels. Computer models have been constructed to test the hypothesis that combining carbonless electricity sources and vehicles fueled by electrolytic hydrogen can reduce carbon emissions more cost effectively than either approach alone. Three scenarios have been developed and compared using computer simulations, hourly utility demand data, representative data for solar and wind energy sites, and the latest available EIA projections for transportation and energy demand in the US in 2020. Cost projections were based on estimates from GRI, EIA, and a recent DOE/EPRI report on renewable energy technologies. The key question guiding this analysis was: what can be gained by combining hydrogen fuel production and renewable electricity? Bounding scenarios were chosen to analyze three carbon conscious options for the US transportation fuel and electricity supply system beyond 2020: Reference Case -- petroleum transportation and natural gas electric sector; Benchmark Case -- petroleum transportation and carbonless electric sector; and Target Case -- hydrogen transportation and carbonless electric sector.

  10. Hydrogen and Fuel Cells for IT Equipment

    Energy Technology Data Exchange (ETDEWEB)

    Kurtz, Jennifer

    2016-03-09

    With the increased push for carbon-free and sustainable data centers, data center operators are increasingly looking to renewable energy as a means to approach carbon-free status and be more sustainable. The National Renewable Energy Laboratory (NREL) is a world leader in hydrogen research and already has an elaborate hydrogen infrastructure in place at the Golden, Colorado, state-of-the-art data center and facility. This presentation will discuss hydrogen generation, storage considerations, and safety issues as they relate to hydrogen delivery to fuel cells powering IT equipment.

  11. Solar-hydrogen fuel-cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Deluchi, M.A. (California Univ., Davis, CA (United States). Inst. of Transportation Studies); Ogden, J.M. (Princeton Univ., NJ (United States). Center for Energy and Environmental Studies)

    1993-05-01

    A fuel cycle in which hydrogen is produced by solar-electrolysis of water, or by gasification of renewable grown biomass, and then used in a fuel-cell powered electric-motor vehicle (FCEV), would produce little or no local, regional or global pollution. Hydrogen FCEVs would combine the best features of battery-powered electric vehicles (BPEVS) - zero emissions, high efficiency, quiet operation and long life -with the long range and fast refueling time of internal-combustion-engine vehicles (ICEVs). If fuel-cell technology develops as hoped, then hydrogen FCEVs will be a significant advance over both hydrogen ICEVs and solar BPEVs: they will be cleaner and more efficient than hydrogen ICEVs, have a much shorter refueling time than BPEVs and have a lower life-cycle cost than both. Solar-hydrogen fuel-cell vehicles would be general-purpose zero-emission vehicles, and could be an important component of a strategy for reducing dependence on imported oil, mitigating global warming and improving urban air quality, at an acceptable cost. (author)

  12. DOE Hydrogen and Fuel Cells Program Plan (September 2011)

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2011-09-01

    The Department of Energy Hydrogen and Fuel Cells Program Plan outlines the strategy, activities, and plans of the DOE Hydrogen and Fuel Cells Program, which includes hydrogen and fuel cell activities within the EERE Fuel Cell Technologies Program and the DOE offices of Nuclear Energy, Fossil Energy, and Science.

  13. Metallic hydrogen: The most powerful rocket fuel yet to exist

    Energy Technology Data Exchange (ETDEWEB)

    Silvera, Isaac F [Lyman Laboratory of Physics, Harvard University, Cambridge MA 02138 (United States); Cole, John W, E-mail: silvera@physics.harvard.ed [NASA MSFC, Huntsville, AL 35801 (United States)

    2010-03-01

    Wigner and Huntington first predicted that pressures of order 25 GPa were required for the transition of solid molecular hydrogen to the atomic metallic phase. Later it was predicted that metallic hydrogen might be a metastable material so that it remains metallic when pressure is released. Experimental pressures achieved on hydrogen have been more than an order of magnitude higher than the predicted transition pressure and yet it remains an insulator. We discuss the applications of metastable metallic hydrogen to rocketry. Metastable metallic hydrogen would be a very light-weight, low volume, powerful rocket propellant. One of the characteristics of a propellant is its specific impulse, I{sub sp}. Liquid (molecular) hydrogen-oxygen used in modern rockets has an Isp of {approx}460s; metallic hydrogen has a theoretical I{sub sp} of 1700s. Detailed analysis shows that such a fuel would allow single-stage rockets to enter into orbit or carry economical payloads to the moon. If pure metallic hydrogen is used as a propellant, the reaction chamber temperature is calculated to be greater than 6000 K, too high for currently known rocket engine materials. By diluting metallic hydrogen with liquid hydrogen or water, the reaction temperature can be reduced, yet there is still a significant performance improvement for the diluted mixture.

  14. Hydrogen/Air Fuel Nozzle Emissions Experiments

    Science.gov (United States)

    Smith, Timothy D.

    2001-01-01

    The use of hydrogen combustion for aircraft gas turbine engines provides significant opportunities to reduce harmful exhaust emissions. Hydrogen has many advantages (no CO2 production, high reaction rates, high heating value, and future availability), along with some disadvantages (high current cost of production and storage, high volume per BTU, and an unknown safety profile when in wide use). One of the primary reasons for switching to hydrogen is the elimination of CO2 emissions. Also, with hydrogen, design challenges such as fuel coking in the fuel nozzle and particulate emissions are no longer an issue. However, because it takes place at high temperatures, hydrogen-air combustion can still produce significant levels of NOx emissions. Much of the current research into conventional hydrocarbon-fueled aircraft gas turbine combustors is focused on NOx reduction methods. The Zero CO2 Emission Technology (ZCET) hydrogen combustion project will focus on meeting the Office of Aerospace Technology goal 2 within pillar one for Global Civil Aviation reducing the emissions of future aircraft by a factor of 3 within 10 years and by a factor of 5 within 25 years. Recent advances in hydrocarbon-based gas turbine combustion components have expanded the horizons for fuel nozzle development. Both new fluid designs and manufacturing technologies have led to the development of fuel nozzles that significantly reduce aircraft emissions. The goal of the ZCET program is to mesh the current technology of Lean Direct Injection and rocket injectors to provide quick mixing, low emissions, and high-performance fuel nozzle designs. An experimental program is planned to investigate the fuel nozzle concepts in a flametube test rig. Currently, a hydrogen system is being installed in cell 23 at NASA Glenn Research Center's Research Combustion Laboratory. Testing will be conducted on a variety of fuel nozzle concepts up to combustion pressures of 350 psia and inlet air temperatures of 1200 F

  15. An Opportunity for Hydrogen Fueled Supersonic Airliners

    Directory of Open Access Journals (Sweden)

    Alex Forbes

    2011-02-01

    Full Text Available This paper takes a new look at the prospects for developing supersonic civil airliners, considering global demographics, climate change issues, fuel prices and technological advances. Dramatic changes have occurred in the demographics, economics, and market intensity of the Eastern Hemisphere since the 1990s. Carbon reduction imperatives provide a major incentive to invest in developing hydrogen-fueled airliners. The “point-to-point” air route architecture has proved viable with long range mid-size airliners. With a cruise Mach number of 1.4, a large number of destinations become viable for overland supersonic flight. A conceptual design process is used to estimate cost per seat mile for a range of hydrocarbon and hydrogen fuel costs. An argument based on the ideal shape for minimal wave drag, estimates the drag penalty from using hydrogen. Viable aircraft geometries are shown to exist, that match the theoretical ideal shape, showing that the drag estimate is achievable. Conservative design arguments and market estimates suggest that hydrogen-fueled airliners can achieve seat-mile costs low enough to open a large worldwide market and justify a viable fleet size.

  16. Combustion characteristics of hydrogen. Carbon monoxide based gaseous fuels

    Science.gov (United States)

    Notardonato, J. J.; White, D. J.; Kubasco, A. J.; Lecren, R. T.

    1981-01-01

    An experimental rig program was conducted with the objective of evaluating the combuston performance of a family of fuel gases based on a mixture of hydrogen and carbon monoxide. These gases, in addition to being members of a family, were also representative of those secondary fuels that could be produced from coal by various gasification schemes. In particular, simulated Winkler, Lurgi, and Blue-water low and medium energy content gases were used as fuels in the experimental combustor rig. The combustor used was originally designed as a low NOx rich-lean system for burning liquid fuels with high bound nitrogen levels. When used with the above gaseous fuels this combustor was operated in a lean-lean mode with ultra long residence times. The Blue-water gas was also operated in a rich-lean mode. The results of these tests indicate the possibility of the existence of an 'optimum' gas turbine hydrogen - carbon monoxide based secondary fuel. Such a fuel would exhibit NOx and high efficiency over the entire engine operating range. It would also have sufficient stability range to allow normal light-off and engine acceleration. Solar Turbines Incorporated would like to emphasize that the results presented here have been obtained with experimental rig combustors. The technologies generated could, however, be utilized in future commercial gas turbines.

  17. Hydrogen-fueled postal vehicle performance evaluation

    Science.gov (United States)

    Hall, R. A.

    1979-01-01

    Fuel consumption, range, and emissions data were obtained while operating a hydrogen-fueled postal delivery vehicle over a defined Postal Service Driving Cycle and the 1975 Urban Driving Cycle. The vehicle's fuel consumption was 0.366 pounds of hydrogen per mile over the postal driving cycle and 0.22 pounds of hydrogen per mile over the urban driving cycle. These data correspond to 6.2 and 10.6 mpg equivalent gasoline mileage for the two driving cycles, respectively. The vehicle's range was 24.2 miles while being operated on the postal driving cycle. Vehicle emissions were measured over the urban driving cycle. HC and CO emissions were quite low, as would be expected. The oxides of nitrogen were found to be 4.86 gm/mi, a value which is well above the current Federal and California standards. Vehicle limitations discussed include excessive engine flashbacks, inadequate acceleration capability the engine air/fuel ratio, the water injection systems, and the cab temperature. Other concerns are safety considerations, iron-titanium hydride observed in the fuel system, evidence of water in the engine rocker cover, and the vehicle maintenance required during the evaluation.

  18. 77 FR 50488 - Hydrogen and Fuel Cell Technical Advisory Committee

    Science.gov (United States)

    2012-08-21

    ... Hydrogen and Fuel Cell Technical Advisory Committee AGENCY: Department of Energy, Office of Energy... open meeting (Webinar) of the Hydrogen and Fuel Cell Technical Advisory Committee (HTAC). The Federal..., DC 20585. SUPPLEMENTARY INFORMATION: Purpose of the Committee: The Hydrogen and Fuel Cell Technical...

  19. Electrocatalytic water splitting to produce fuel hydrogen

    Science.gov (United States)

    Yuan, Hao

    Solar energy is regarded as a promising source for clean and sustainable energy. However, it is not a continuous energy source, thus certain strategies have to be developed to effectively convert and store it. Solar-driven electrocatalytic water splitting, which converts solar energy into chemical energy for storage as fuel hydrogen, can effectively mitigate the intermittence of solar radiation. Water splitting consists of two half reactions: water oxidation and hydrogen evolution. Both reactions rely on highly effective electrocatalysts. This dissertation is an account of four detailed studies on developing highly effective low-cost electrocatalysts for both reactions, and includes a preliminary attempt at system integration to build a functional photoanode for solar-driven water oxidation. For the water oxidation reaction, we have developed an electrochemical method to immobilize a cobalt-based (Co-OXO) water oxidation catalyst on a conductive surface to promote recyclability and reusability without affecting functionality. We have also developed a method to synthesize a manganese-based (MnOx) catalytic film in situ, generating a nanoscale fibrous morphology that provides steady and excellent water oxidation performance. The new method involves two series of cyclic voltammetry (CV) over different potential ranges, followed by calcination to increase crystallinity. The research has the potential to open avenues for synthesizing and optimizing other manganese-based water oxidation catalysts. For the hydrogen evolution reaction, we have developed a new electrodeposition method to synthesize Ni/Ni(OH)2 catalysts in situ on conductive surfaces. The new method involves only two cycles of CV over a single potential range. The resulting catalytic film has a morphology of packed walnut-shaped particles. It has superior catalytic activity and good stability over long periods. We have investigated the feasibility of incorporating manganese-based water oxidation catalysts

  20. Guidelines for use of Hydrogen Fuel in Commercial Vehicles

    Science.gov (United States)

    2008-01-01

    Over the next 50 years, hydrogen use is expected to grow dramatically as an automotive and electrical power source fuel. As hydrogen becomes commercially viable, the safety concerns associated with hydrogen systems, equipment, and operation are of co...

  1. 2016 Annual Progress Report: DOE Hydrogen and Fuel Cells Program

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2017-03-09

    The 2016 Annual Progress Report summarizes fiscal year 2016 activities and accomplishments by projects funded by the DOE Hydrogen and Fuel Cells Program. It covers the program areas of hydrogen production; hydrogen delivery; hydrogen storage; fuel cells; manufacturing R&D; technology validation; safety, codes and standards; systems analysis; market transformation; and Small Business Innovation Research projects.

  2. 2015 Annual Progress Report: DOE Hydrogen and Fuel Cells Program

    Energy Technology Data Exchange (ETDEWEB)

    None

    2015-12-23

    The 2015 Annual Progress Report summarizes fiscal year 2015 activities and accomplishments by projects funded by the DOE Hydrogen and Fuel Cells Program. It covers the program areas of hydrogen production; hydrogen delivery; hydrogen storage; fuel cells; manufacturing R&D; technology validation; safety, codes and standards; systems analysis; and market transformation.

  3. Replacement of fossil fuels by hydrogen

    Science.gov (United States)

    Dahlberg, R.

    The replacement of fossil fuels by solar hydrogen plantations is considered. A model is proposed in which ten plantation families, situated in suitable deserted zones of the world after the year 2000, would generate enough electrical energy to produce solar cells and materials for the construction of ten new plantations within a decade. The technological growth process for identical solar plantation units could be completed about 50 years after construction of the first plantation. All ten plantation families would, by using their electrical energy for the electrolysis of water, generate an amount of hydrogen per year which is four to five times the energy of the world's present annual consumption of oil. This concept envisions the global replacement of fossil fuels by hydrogen within a period consistent with the remaining time span of fossil fuel availability. Storage and transportation of hydrogen would be economical, and the energy produced would not present any environmental problems. Advantages with respect to gains in international cooperation, world peace, and world economy are also discussed.

  4. WVU Hydrogen Fuel Dispensing Station

    Energy Technology Data Exchange (ETDEWEB)

    Davis, William [West Virginia University Research Corporation, Morgantown, WV (United States)

    2015-09-01

    The scope of this project was changed during the course of the project. Phase I of the project was to construct a site similar to the site at Central West Virginia Regional Airport in Charleston, WV to show that duplication of the site was a feasible method of conducting hydrogen stations. Phase II of the project was necessitated due to a lack of funding that was planned for the development of the station in Morgantown. The US Department of Energy determined that the station in Charleston would be dismantled and moved to Morgantown and reassembled at the Morgantown site. This necessitated storage of the components of the station for almost a year at the NAFTC Headquarters which caused a number of issues with the equipment that will be discussed in later portions of this report. This report will consist of PHASE I and PHASE II with discussions on each of the tasks scheduled for each phase of the project.

  5. Commercializing light-duty plug-in/plug-out hydrogen-fuel-cell vehicles: "Mobile electricity" technologies, early California household markets, and innovation management

    Science.gov (United States)

    Williams, Brett David

    Starting from the premise that new consumer value must drive hydrogen-fuel-cell-vehicle (H2FCV) commercialization, a group of opportunities collectively called "Mobile Electricity" (Me-) is characterized. Me- redefines H2 FCVs as innovative products able to provide home recharging and mobile power, for example for tools, mobile activities, emergencies, and electric-grid-support services. To characterize such opportunities, this study first integrates and extends previous analyses of H2FCVs, plug-in hybrids, and vehicle-to-grid (V2G) power. It uses a new model to estimate zero-emission-power vs. zero-emission-driving tradeoffs, costs, and grid-support revenues for various electric-drive vehicle types and levels of infrastructure service. Next, the initial market potential for Me- enabled vehicles, such as H2FCVs and plug-in hybrids, is estimated by eliminating unlikely households from consideration for early adoption. 5.2 million of 33.9 million Californians in the 2000 Census live in households pre-adapted to Me-, 3.9 million if natural gas is required for home refueling. The possible sales base represented by this population is discussed. Several differences in demographic and other characteristics between the target market and the population as a whole are highlighted, and two issues related to the design of H2FCVs and their supporting infrastructure are discussed: vehicle range and home hydrogen refueling. These findings argue for continued investigation of this and similar target segments-which represent more efficient research populations for subsequent study by product designers and other decision-makers wishing to understand the early market dynamics facing Me- innovations. Next, Me-H2FCV commercialization issues are raised from the perspectives of innovation, product development, and strategic marketing. Starting with today's internalcombustion hybrids, this discussion suggests a way to move beyond the battery vs. fuel-cell zero-sum game and towards the

  6. Potential of hydrogen fuel for future air transportation systems.

    Science.gov (United States)

    Small, W. J.; Fetterman, D. E.; Bonner, T. F., Jr.

    1973-01-01

    Recent studies have shown that hydrogen fuel can yield spectacular improvements in aircraft performance in addition to its more widely discussed environmental advantages. The characteristics of subsonic, supersonic, and hypersonic transport aircraft using hydrogen fuel are discussed, and their performance and environmental impact are compared to that of similar aircraft using conventional fuel. The possibilities of developing hydrogen-fueled supersonic and hypersonic vehicles with sonic boom levels acceptable for overland flight are also explored.

  7. Sodium Borohydride/Hydrogen Peroxide Fuel Cells For Space Application

    Science.gov (United States)

    Valdez, T. I.; Deelo, M. E.; Narayanan, S. R.

    2006-01-01

    This viewgraph presentation examines Sodium Borohydride and Hydrogen Peroxide Fuel Cells as they are applied to space applications. The topics include: 1) Motivation; 2) The Sodium Borohydride Fuel Cell; 3) Sodium Borohydride Fuel Cell Test Stands; 4) Fuel Cell Comparisons; 5) MEA Performance; 6) Anode Polarization; and 7) Electrode Analysis. The benefits of hydrogen peroxide as an oxidant and benefits of sodium borohydride as a fuel are also addressed.

  8. Hydrogen plant module (HPM) and vehicle fueled by same.

    Science.gov (United States)

    2011-09-29

    The goal / objective of the project was to design and fabricate hydrogen plant module (HPM) that is capable of producing : hydrogen fuel onboard a vehicle and that obviates one or more of the present issues related to compressed hydrogen fuel : stora...

  9. Hydrogen as a transportation fuel: Costs and benefits

    Energy Technology Data Exchange (ETDEWEB)

    Berry, G.D.

    1996-03-01

    Hydrogen fuel and vehicles are assessed and compared to other alternative fuels and vehicles. The cost, efficiency, and emissions of hydrogen storage, delivery, and use in hybrid-electric vehicles (HEVs) are estimated. Hydrogen made thermochemically from natural gas and electrolytically from a range of electricity mixes is examined. Hydrogen produced at central plants and delivered by truck is compared to hydrogen produced on-site at filling stations, fleet refueling centers, and residences. The impacts of hydrogen HEVs, fueled using these pathways, are compared to ultra-low emissions gasoline internal-combustion-engine vehicles (ICEVs), advanced battery-powered electric vehicles (BPEVs), and HEVs using gasoline or natural gas.

  10. Hydrogen as a fuel for fuel cell vehicles: A technical and economic comparison

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, J.; Steinbugler, M.; Kreutz, T. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies

    1997-12-31

    All fuel cells currently being developed for near term use in vehicles require hydrogen as a fuel. Hydrogen can be stored directly or produced onboard the vehicle by reforming methanol, ethanol or hydrocarbon fuels derived from crude oil (e.g., Diesel, gasoline or middle distillates). The vehicle design is simpler with direct hydrogen storage, but requires developing a more complex refueling infrastructure. In this paper, the authors compare three leading options for fuel storage onboard fuel cell vehicles: compressed gas hydrogen storage; onboard steam reforming of methanol; onboard partial oxidation (POX) of hydrocarbon fuels derived from crude oil. Equilibrium, kinetic and heat integrated system (ASPEN) models have been developed to estimate the performance of onboard steam reforming and POX fuel processors. These results have been incorporated into a fuel cell vehicle model, allowing us to compare the vehicle performance, fuel economy, weight, and cost for various fuel storage choices and driving cycles. A range of technical and economic parameters were considered. The infrastructure requirements are also compared for gaseous hydrogen, methanol and hydrocarbon fuels from crude oil, including the added costs of fuel production, storage, distribution and refueling stations. Considering both vehicle and infrastructure issues, the authors compare hydrogen to other fuel cell vehicle fuels. Technical and economic goals for fuel cell vehicle and hydrogen technologies are discussed. Potential roles for hydrogen in the commercialization of fuel cell vehicles are sketched.

  11. Electrocatalysis research for fuel cells and hydrogen production

    CSIR Research Space (South Africa)

    Mathe, MK

    2012-01-01

    Full Text Available The CSIR undertakes research in the Electrocatalysis of fuel cells and for hydrogen production. The Hydrogen South Africa (HySA) strategy supports research on electrocatalysts due to their importance to the national beneficiation strategy. The work...

  12. Simulation of a hydrogen hybrid battery-fuel cell vehicle

    National Research Council Canada - National Science Library

    Víctor Alfonsín; Andrés Suárez; Rocío Maceiras; Ángeles Cancela; Ángel Sánchez

    2015-01-01

    .... Battery and hydrogen consumption, hydrogen storage tank level, battery state of charge, power consumption and fuel cell energy production, maximum range and maximum number of cycles for a real route can be determined...

  13. The use of hydrogen for aircraft propulsion in view of the fuel crisis

    Science.gov (United States)

    Weiss, S.

    1973-01-01

    Some factors influencing the technical feasibility of operating a liquid hydrogen-fueled airplane are discussed in light of the projected decrease of fossil fuels. Other sources of energy, such as wind, tidal, solar, and geothermal, are briefly mentioned. In view of projected decreases in available petroleum fuels, interest has been generated in exploiting the potential of liquid hydrogen (LH2) as an aircraft fuel. Cost studies of LH2 production show it to be more expensive than presently used fuels. Regardless of cost considerations, LH2 is viewed as an attractive aircraft fuel because of the potential performance benefits it offers. Accompanying these benefits, however, are many new problems associated with aircraft design and operations; for example, problems related to fuel system design and the handling of LH2 during ground servicing. Some of the factors influencing LH2 fuel tank design, pumping, heat exchange, and flow regulation are discussed.

  14. Hydrogen Fuel Cell development in Columbia (SC)

    Energy Technology Data Exchange (ETDEWEB)

    Reifsnider, Kenneth [Univ. of South Carolina, Columbia, SC (United States); Chen, Fanglin [Univ. of South Carolina, Columbia, SC (United States); Popov, Branko [Univ. of South Carolina, Columbia, SC (United States); Chao, Yuh [Univ. of South Carolina, Columbia, SC (United States); Xue, Xingjian [Univ. of South Carolina, Columbia, SC (United States)

    2012-09-15

    This is an update to the final report filed after the extension of this program to May of 2011. The activities of the present program contributed to the goals and objectives of the Fuel Cell element of the Hydrogen, Fuel Cells and Infrastructure Technologies Program of the Department of Energy through five sub-projects. Three of these projects have focused on PEM cells, addressing the creation of carbon-based metal-free catalysts, the development of durable seals, and an effort to understand contaminant adsorption/reaction/transport/performance relationships at low contaminant levels in PEM cells. Two programs addressed barriers in SOFCs; an effort to create a new symmetrical and direct hydrocarbon fuel SOFC designs with greatly increased durability, efficiency, and ease of manufacturing, and an effort to create a multiphysics engineering durability model based on electrochemical impedance spectroscopy interpretations that associate the micro-details of how a fuel cell is made and their history of (individual) use with specific prognosis for long term performance, resulting in attendant reductions in design, manufacturing, and maintenance costs and increases in reliability and durability.

  15. Hydrogen Fuel Cell Development in Columbia (SC)

    Energy Technology Data Exchange (ETDEWEB)

    Reifsnider, Kenneth

    2011-07-31

    This is an update to the final report filed after the extension of this program to May of 2011. The activities of the present program contributed to the goals and objectives of the Fuel Cell element of the Hydrogen, Fuel Cells and Infrastructure Technologies Program of the Department of Energy through five sub-projects. Three of these projects have focused on PEM cells, addressing the creation of carbon-based metal-free catalysts, the development of durable seals, and an effort to understand contaminant adsorption/reaction/transport/performance relationships at low contaminant levels in PEM cells. Two programs addressed barriers in SOFCs; an effort to create a new symmetrical and direct hydrocarbon fuel SOFC designs with greatly increased durability, efficiency, and ease of manufacturing, and an effort to create a multiphysics engineering durability model based on electrochemical impedance spectroscopy interpretations that associate the micro-details of how a fuel cell is made and their history of (individual) use with specific prognosis for long term performance, resulting in attendant reductions in design, manufacturing, and maintenance costs and increases in reliability and durability.

  16. Hydrogen-methane fuel control systems for turbojet engines

    Science.gov (United States)

    Goldsmith, J. S.; Bennett, G. W.

    1973-01-01

    Design, development, and test of a fuel conditioning and control system utilizing liquid methane (natural gas) and liquid hydrogen fuels for operation of a J85 jet engine were performed. The experimental program evaluated the stability and response of an engine fuel control employing liquid pumping of cryogenic fuels, gasification of the fuels at supercritical pressure, and gaseous metering and control. Acceptably stable and responsive control of the engine was demonstrated throughout the sea level power range for liquid gas fuel and up to 88 percent engine speed using liquid hydrogen fuel.

  17. Aircraft-Fuel-Tank Design for Liquid Hydrogen

    Science.gov (United States)

    Reynolds, T W

    1955-01-01

    Some of the considerations involved in the design of aircraft fuel tanks for liquid hydrogen are discussed herein. Several of the physical properties of metals and thermal insulators in the temperature range from ambient to liquid-hydrogen temperatures are assembled. Calculations based on these properties indicate that it is possible to build a large-size liquid-hydrogen fuel tank which (1) will weigh less then 15 percent of the fuel weight, (2) will have a hydrogen vaporization rate less than 30 percent of the cruise fuel-flow rate, and (3) can be held in a stand-by condition and readied for flight in a short time.

  18. Safety risks of hydrogen fuel for applications in transportation vehicles.

    Science.gov (United States)

    2009-04-01

    Combustion of hydrocarbon fuels in many practical applications produces pollutants that are harmful to human health and environment. Hydrogen fuel is considered to be a potential answer to the clean energy demands, especially with the advances in fue...

  19. Possibilities of Using Hydrogen as Motor Vehicle Fuel

    Directory of Open Access Journals (Sweden)

    Zdravko Bukljaš

    2005-03-01

    Full Text Available Hydrogen is the fuel of the future, since it is the element ofwater (H20 whichsun·ounds us and the resources of which areunlimited. First water is divided into hydrogen and oxygen. Thepaper presents the laboratory and industrial methods of obtain·ing hydrogen, types of fuel cells for various purposes, hydrogen-propelled motor vehicles, as well as advantages and drawbacksof hydrogen used as fuel under the conditions that haveto be met in order to use it as propulsion energy for motor vehicles.

  20. Optimal Design of a Fossil Fuel-Based Hydrogen Infrastructure with Carbon Capture and Sequestration: Case Study in Ohio

    OpenAIRE

    Johnson, Nils; Yang, Christopher; Ni, Jason; Johnson, Joshua; Lin, Zhenhong; Ogden, Joan M

    2005-01-01

    Presented at the National Hydrogen Association Annual Hydrogen Conference (NHA 2005), Washington, DC, March 29 - April 1, 2005 The use of hydrogen as a light-duty transportation fuel requires the development of a widespread regional hydrogen infrastructure, including production facilities, a distribution network, and refueling stations. In the case of fossil-based hydrogen production with carbon capture and sequestration, additional infrastructure is needed for CO2 disposal. If const...

  1. EVermont Renewable Hydrogen Production and Transportation Fueling System

    Energy Technology Data Exchange (ETDEWEB)

    Garabedian, Harold T.

    2008-03-30

    A great deal of research funding is being devoted to the use of hydrogen for transportation fuel, particularly in the development of fuel cell vehicles. When this research bears fruit in the form of consumer-ready vehicles, will the fueling infrastructure be ready? Will the required fueling systems work in cold climates as well as they do in warm areas? Will we be sure that production of hydrogen as the energy carrier of choice for our transit system is the most energy efficient and environmentally friendly option? Will consumers understand this fuel and how to handle it? Those are questions addressed by the EVermont Wind to Wheels Hydrogen Project: Sustainable Transportation. The hydrogen fueling infrastructure consists of three primary subcomponents: a hydrogen generator (electrolyzer), a compression and storage system, and a dispenser. The generated fuel is then used to provide transportation as a motor fuel. EVermont Inc., started in 1993 by then governor Howard Dean, is a public-private partnership of entities interested in documenting and advancing the performance of advanced technology vehicles that are sustainable and less burdensome on the environment, especially in areas of cold climates, hilly terrain and with rural settlement patterns. EVermont has developed a demonstration wind powered hydrogen fuel producing filling system that uses electrolysis, compression to 5000 psi and a hydrogen burning vehicle that functions reliably in cold climates. And that fuel is then used to meet transportation needs in a hybrid electric vehicle whose internal combustion engine has been converted to operate on hydrogen Sponsored by the DOE EERE Hydrogen, Fuel Cells & Infrastructure Technologies (HFC&IT) Program, the purpose of the project is to test the viability of sustainably produced hydrogen for use as a transportation fuel in a cold climate with hilly terrain and rural settlement patterns. Specifically, the project addresses the challenge of building a renewable

  2. Solar Hydrogen Fuel Cell Projects at Brooklyn Tech

    Science.gov (United States)

    Fedotov, Alex; Farah, Shadia; Farley, Daithi; Ghani, Naureen; Kuo, Emmy; Aponte, Cecielo; Abrescia, Leo; Kwan, Laiyee; Khan, Ussamah; Khizner, Felix; Yam, Anthony; Sakeeb, Khan; Grey, Daniel; Anika, Zarin; Issa, Fouad; Boussayoud, Chayama; Abdeldayem, Mahmoud; Zhang, Alvin; Chen, Kelin; Chan, Kameron Chuen; Roytman, Viktor; Yee, Michael

    2010-01-01

    This article describes the projects on solar hydrogen powered vehicles using water as fuel conducted by teams at Brooklyn Technical High School. Their investigations into the pure and applied chemical thermodynamics of hydrogen fuel cells and bio-inspired devices have been consolidated in a new and emerging sub-discipline that they define as solar…

  3. Installation of Ohio's First Electrolysis-Based Hydrogen Fueling Station

    Science.gov (United States)

    Scheidegger, Brianne T.; Lively, Michael L.

    2012-01-01

    This paper describes progress made towards the installation of a hydrogen fueling station in Northeast Ohio. In collaboration with several entities in the Northeast Ohio area, the NASA Glenn Research Center is installing a hydrogen fueling station that uses electrolysis to generate hydrogen on-site. The installation of this station is scheduled for the spring of 2012 at the Greater Cleveland Regional Transit Authority s Hayden bus garage in East Cleveland. This will be the first electrolysis-based hydrogen fueling station in Ohio.

  4. H2FIRST: A partnership to advance hydrogen fueling station technology driving an optimal consumer experience.

    Energy Technology Data Exchange (ETDEWEB)

    Moen, Christopher D. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Dedrick, Daniel E. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Pratt, Joseph William [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Balfour, Bruce [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Noma, Edwin Yoichi [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Somerday, Brian P. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); San Marchi, Christopher W. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Wipke, Keith [National Renewable Energy Lab. (NREL), Golden, CO (United States); Kurtz, Jennifer [National Renewable Energy Lab. (NREL), Golden, CO (United States); Terlip, Danny [National Renewable Energy Lab. (NREL), Golden, CO (United States); Harrison, Kevin [National Renewable Energy Lab. (NREL), Golden, CO (United States); Sprik, Samuel [National Renewable Energy Lab. (NREL), Golden, CO (United States); Harris, Aaron [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2014-03-01

    The US Department of Energy (DOE) Energy Efficiency and Renewable Energy (EERE) Office of Fuel Cell Technologies Office (FCTO) is establishing the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) partnership, led by the National Renewable Energy Laboratory (NREL) and Sandia National Laboratories (SNL). FCTO is establishing this partnership and the associated capabilities in support of H2USA, the public/private partnership launched in 2013. The H2FIRST partnership provides the research and technology acceleration support to enable the widespread deployment of hydrogen infrastructure for the robust fueling of light-duty fuel cell electric vehicles (FCEV). H2FIRST will focus on improving private-sector economics, safety, availability and reliability, and consumer confidence for hydrogen fueling. This whitepaper outlines the goals, scope, activities associated with the H2FIRST partnership.

  5. Influence of the Ambient Temperature, to the Hydrogen Fuel Cell Functioning

    Directory of Open Access Journals (Sweden)

    POPOVICI Ovidiu

    2012-10-01

    Full Text Available The reversible fuel cell can be used to produce hydrogen. The hydrogen is further the chemical energy source to produce electrical energy using the fuel cell. The ambient temperature will influence theparameters of the hydrogen fuel cell.

  6. Synthesis of Nano-Light Magnesium Hydride for Hydrogen Storage ...

    African Journals Online (AJOL)

    Abstract. Nano-light magnesium hydride that has the capability for hydrogen storage was synthesized from treatment of magnesium ribbon with hydrogen peroxide. The optimum time for complete hydrogenation of the magnesium hydride was 5 hours.

  7. 2014 Annual Progress Report: DOE Hydrogen and Fuel Cells Program

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2014-11-01

    The 2014 Annual Progress Report summarizes fiscal year 2014 activities and accomplishments by projects funded by the DOE Hydrogen Program. It covers the program areas of hydrogen production and delivery; hydrogen storage; fuel cells; manufacturing; technology validation; safety, codes and standards; market transformation; and systems analysis.

  8. 2011 Annual Progress Report: DOE Hydrogen and Fuel Cells Program

    Energy Technology Data Exchange (ETDEWEB)

    Satyapal, Sunita [Office of Energy Efficiency and Renewable Energy (EERE), Washington, DC (United States)

    2011-11-01

    The 2011 Annual Progress Report summarizes fiscal year 2011 activities and accomplishments by projects funded by the DOE Hydrogen Program. It covers the program areas of hydrogen production and delivery; hydrogen storage; fuel cells; manufacturing; technology validation; safety, codes and standards; education; market transformation; and systems analysis.

  9. 2013 Annual Progress Report: DOE Hydrogen and Fuel Cells Program

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2013-12-01

    The 2013 Annual Progress Report summarizes fiscal year 2013 activities and accomplishments by projects funded by the DOE Hydrogen Program. It covers the program areas of hydrogen production and delivery; hydrogen storage; fuel cells; manufacturing; technology validation; safety, codes and standards; market transformation; and systems analysis.

  10. Hydrogen as fuel carrier in PEM fuelcell for automobile applications

    Science.gov (United States)

    Sk, Mudassir Ali; Venkateswara Rao, K.; Ramana Rao, Jagirdar V.

    2015-02-01

    The present work focuses the application of nanostructured materials for storing of hydrogen in different carbon materials by physisorption method. To market a hydrogen-fuel cell vehicle as competitively as the present internal combustion engine vehicles, there is a need for materials that can store a minimum of 6.5wt% of hydrogen. Carbon materials are being heavily investigated because of their promise to offer an economical solution to the challenge of safe storage of large hydrogen quantities. Hydrogen is important as a new source of energy for automotive applications. It is clear that the key challenge in developing this technology is hydrogen storage. Combustion of fossil fuels and their overuse is at present a serious concern as it is creates severe air pollution and global environmental problems; like global warming, acid rains, ozone depletion in stratosphere etc. This necessitated the search for possible alternative sources of energy. Though there are a number of primary energy sources available, such as thermonuclear energy, solar energy, wind energy, hydropower, geothermal energy etc, in contrast to the fossil fuels in most cases, these new primary energy sources cannot be used directly and thus they must be converted into fuels, that is to say, a new energy carrier is needed. Hydrogen fuel cells are two to three times more efficient than combustion engines. As they become more widely available, they will reduce dependence on fossil fuels. In a fuel cell, hydrogen and oxygen are combined in an electrochemical reaction that produces electricity and, as a byproduct, water.

  11. Deployment of Fuel Cell Electric Buses in Transit Agencies: Allocation of Hydrogen Demand and Rollout of Preferable Infrastructure Scenarios

    OpenAIRE

    Castillo Munoz, Analy

    2016-01-01

    Initiatives to improve air quality in urban areas and to mitigate climate change through the reduction of greenhouse gas emissions have resulted in new mandates and legislation to implement zero emissions vehicles (ZEV). While several studies have focused on fueling infrastructure for light-duty fuel cell electric vehicles, there is a lack of knowledge regarding the nature of hydrogen supply chains for fuel cell electric buses. This thesis presents an analysis of hydrogen infrastructures to g...

  12. City of Chula Vista hydrogen fuel cell bus demonstration project

    Energy Technology Data Exchange (ETDEWEB)

    Gustafson, B.; Bamberger, B.

    1996-10-01

    Hydrogen as an energy carrier and fuel has potential for various uses including electricity, commercial, residential, transportation, and industrial. It is an energy carrier that can be produced from a variety of primary sources and potentially can accomplish these various uses while significantly reducing pollution by substituting for or reducing the use of fossil fuels. One of the most immediate and potentially viable roles for hydrogen as an energy carrier will be its use as a transportation fuel, especially in densely populated urban areas where automotive emissions contribute significantly to air pollution. The Department of Energy`s commitment to research and development of hydrogen as an alternative fuel, and California`s Zero Emission Vehicle (ZEV) requirements, both provide the impetus and favorable circumstance for demonstrating hydrogen as a transportation fuel on an urban bus system. The purpose of this project is to demonstrate the feasibility of using solid polymer fuel cells in a hydrogen-powered electric drive system for an urban transit bus application. Fuel cell buses use hydrogen fuel and oxygen from the air to produce electrical power with the only byproduct being pure water. Proton Exchange Membrane (PEM) fuel cells are proposed for this project. Current evidence suggests that fuel cells, which rely on hydrogen and a process known as proton exchange to generate their power, appear to have an infinite life span. All exhaust pollution is completely eliminated, resulting in a Zero Emission Vehicle (ZEV). An urban bus system offers the potential for developing a market for the production of hydrogen propulsion technology due to extensive vehicular use in densely populated areas experiencing pollution from numerous sources, and because the central garaging facilities or the bus system facilitates fueling and maintenance functions.

  13. Pathways to a hydrogen fuel infrastructure in Norway

    Energy Technology Data Exchange (ETDEWEB)

    Stiller, Christoph; Buenger, Ulrich [Department of Energy and Process Engineering, The Norwegian University of Science and Technology, Kolbjoern Hejes vei 1B, NO-7491 Trondheim (Norway); Moeller-Holst, Steffen; Svensson, Ann Mari [SINTEF Materials and Chemistry, Sem Saelandsvei 12, NO-7465 Trondheim (Norway); Espegren, Kari A. [Institute for Energy Technology, Instituttveien 18, NO-2027 Kjeller (Norway); Nowak, Matthias [Department of Industrial Economics and Technology Management, The Norwegian University of Science and Technology, Alfred Getz vei 3, NO-7491 Trondheim (Norway)

    2010-04-15

    Hydrogen is expected to become an integral part of the Norwegian energy system in the future, primarily as transportation fuel. The NorWays project aims at providing decision support for introduction of hydrogen in the Norwegian energy system by modelling of energy system and hydrogen infrastructure at various spatial levels. GIS-based regional hydrogen demand scenarios and fuelling station networks have been generated, considering organic growth of regional hydrogen coverage and increasing density of hydrogen users over time. A regional model optimised supply scenarios for these fuelling station networks, including choice of production technology (biomass gasification, NG SMR, electrolysis, by-product hydrogen) and delivery (pipeline, truck, and onsite schemes), including integrated hydrogen delivery networks by truck and pipeline. The impact of energy price and GHG emission constraint scenarios on hydrogen production and delivery mix and average hydrogen costs is analysed, and conclusions on the effectiveness of policy measures are drawn. (author)

  14. Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell.

    Science.gov (United States)

    Fukuzumi, Shunichi; Yamada, Yusuke; Karlin, Kenneth D

    2012-11-01

    This review describes homogeneous and heterogeneous catalytic reduction of dioxygen with metal complexes focusing on the catalytic two-electron reduction of dioxygen to produce hydrogen peroxide. Whether two-electron reduction of dioxygen to produce hydrogen peroxide or four-electron O2-reduction to produce water occurs depends on the types of metals and ligands that are utilized. Those factors controlling the two processes are discussed in terms of metal-oxygen intermediates involved in the catalysis. Metal complexes acting as catalysts for selective two-electron reduction of oxygen can be utilized as metal complex-modified electrodes in the electrocatalytic reduction to produce hydrogen peroxide. Hydrogen peroxide thus produced can be used as a fuel in a hydrogen peroxide fuel cell. A hydrogen peroxide fuel cell can be operated with a one-compartment structure without a membrane, which is certainly more promising for the development of low-cost fuel cells as compared with two compartment hydrogen fuel cells that require membranes. Hydrogen peroxide is regarded as an environmentally benign energy carrier because it can be produced by the electrocatalytic two-electron reduction of O2, which is abundant in air, using solar cells; the hydrogen peroxide thus produced could then be readily stored and then used as needed to generate electricity through the use of hydrogen peroxide fuel cells.

  15. Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell

    Science.gov (United States)

    Fukuzumi, Shunichi; Yamada, Yusuke; Karlin, Kenneth D.

    2012-01-01

    This review describes homogeneous and heterogeneous catalytic reduction of dioxygen with metal complexes focusing on the catalytic two-electron reduction of dioxygen to produce hydrogen peroxide. Whether two-electron reduction of dioxygen to produce hydrogen peroxide or four-electron O2-reduction to produce water occurs depends on the types of metals and ligands that are utilized. Those factors controlling the two processes are discussed in terms of metal-oxygen intermediates involved in the catalysis. Metal complexes acting as catalysts for selective two-electron reduction of oxygen can be utilized as metal complex-modified electrodes in the electrocatalytic reduction to produce hydrogen peroxide. Hydrogen peroxide thus produced can be used as a fuel in a hydrogen peroxide fuel cell. A hydrogen peroxide fuel cell can be operated with a one-compartment structure without a membrane, which is certainly more promising for the development of low-cost fuel cells as compared with two compartment hydrogen fuel cells that require membranes. Hydrogen peroxide is regarded as an environmentally benign energy carrier because it can be produced by the electrocatalytic two-electron reduction of O2, which is abundant in air, using solar cells; the hydrogen peroxide thus produced could then be readily stored and then used as needed to generate electricity through the use of hydrogen peroxide fuel cells. PMID:23457415

  16. Fuel from water: the photochemical generation of hydrogen from water.

    Science.gov (United States)

    Han, Zhiji; Eisenberg, Richard

    2014-08-19

    Hydrogen has been labeled the fuel of the future since it contains no carbon, has the highest specific enthalpy of combustion of any chemical fuel, yields only water upon complete oxidation, and is not limited by Carnot considerations in the amount of work obtained when used in a fuel cell. To be used on the scale needed for sustainable growth on a global scale, hydrogen must be produced by the light-driven splitting of water into its elements, as opposed to reforming of methane, as is currently done. The photochemical generation of H2, which is the reductive side of the water splitting reaction, is the focus of this Account, particularly with regard to work done in the senior author's laboratory over the last 5 years. Despite seminal work done more than 30 years ago and the extensive research conducted since then on all aspects of the process, no viable system has been developed for the efficient and robust photogeneration of H2 from water using only earth abundant elements. For the photogeneration of H2 from water, a system must contain a light absorber, a catalyst, and a source of electrons. In this Account, the discovery and study of new Co and Ni catalysts are described that suggest H2 forms via a heterocoupling mechanism from a metal-hydride and a ligand-bound proton. Several complexes with redox active dithiolene ligands are newly recognized to be effective in promoting the reaction. A major new development in the work described is the use of water-soluble CdSe quantum dots (QDs) as light absorbers for H2 generation in water. Both activity and robustness of the most successful systems are impressive with turnover numbers (TONs) approaching 10(6), activity maintained over 15 days, and a quantum yield for H2 of 36% with 520 nm light. The water solubilizing capping agent for the first system examined was dihydrolipoic acid (DHLA) anion, and the catalyst was determined to be a DHLA complex of Ni(II) formed in situ. Dissociation of DHLA from the QD surface proved

  17. Hydrogen and fuel cells emerging technologies and applications

    CERN Document Server

    Sorensen (Sorensen), Bent

    2011-01-01

    A hydrogen economy, in which this one gas provides the source of all energy needs, is often touted as the long-term solution to the environmental and security problems associated with fossil fuels. However, before hydrogen can be used as fuel on a global scale we must establish cost effective means of producing, storing, and distributing the gas, develop cost efficient technologies for converting hydrogen to electricity (e.g. fuel cells), and creating the infrastructure to support all this. Sorensen is the only text available that provides up to date coverage of all these issues at a level

  18. Hydrogen Fueling Station in Honolulu, Hawaii Feasibility Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Porter Hill; Michael Penev

    2014-08-01

    The Department of Energy Hydrogen & Fuel Cells Program Plan (September 2011) identifies the use of hydrogen for government and fleet electric vehicles as a key step for achieving “reduced greenhouse gas emissions; reduced oil consumption; expanded use of renewable power …; highly efficient energy conversion; fuel flexibility …; reduced air pollution; and highly reliable grid-support.” This report synthesizes several pieces of existing information that can inform a decision regarding the viability of deploying a hydrogen (H2) fueling station at the Fort Armstrong site in Honolulu, Hawaii.

  19. Liquid Hydrogen Fuel System for Small Unmanned Air Vehicles

    Science.gov (United States)

    2013-01-07

    the Office of Naval Research for support of this research. VII. References 1 R. Stroman, J.C. Kellogg, K. Swider-Lyons, “Testing of a PEM Fuel Cell ...energy storage system. The Naval Research Laboratory has been extending the duration of electric UAVs through the use of hydrogen fuel cells , which...take advantage of both the high energy of H2 fuel in combination with the high efficiency (~50%) of polymer fuel cells . In this paper, we describe

  20. Hydrogen-bromine fuel cell advance component development

    Science.gov (United States)

    Charleston, Joann; Reed, James

    1988-01-01

    Advanced cell component development is performed by NASA Lewis to achieve improved performance and longer life for the hydrogen-bromine fuel cells system. The state-of-the-art hydrogen-bromine system utilizes the solid polymer electrolyte (SPE) technology, similar to the SPE technology developed for the hydrogen-oxygen fuel cell system. These studies are directed at exploring the potential for this system by assessing and evaluating various types of materials for cell parts and electrode materials for Bromine-hydrogen bromine environment and fabricating experimental membrane/electrode-catalysts by chemical deposition.

  1. Hydrogen engines based on liquid fuels, a review

    Science.gov (United States)

    Houseman, J.; Voecks, G. E.

    1981-01-01

    The concept of storing hydrogen as part of a liquid fuel, such as gasoline or methanol, and subsequent onboard generation of the hydrogen from such liquids, is reviewed. Hydrogen generation processes, such as steam reforming, partial oxidation, and thermal decomposition are evaluated in terms of theoretical potential and practical limitations, and a summary is presented on the major experimental work on conversion of gasoline and methanol. Results of experiments indicate that onboard hydrogen generation from methanol is technically feasible and will yield substantial improvements in fuel economy and emissions, especially if methanol decomposition is brought about by the use of engine exhaust heat; e.g., a methanol decomposition reactor of 3.8 provides hydrogen-rich gas for a 4 cylinder engine (1.952), and 80% of the methanol is converted, engine exhaust gas being the only heat supply. A preliminary outline of the development of a methanol-based hydrogen engine and a straight hydrogen engine is presented.

  2. Fuel Manifold Resists Embrittlement by Hydrogen

    Science.gov (United States)

    Adams, T.

    1986-01-01

    Completely-cast hydrogen-compatible alloy preferable to protective plating. Complexity of plating, welding, and brazing unnecessary if hydrogen-compatible alloy used for entire casting instead of protective overlay. Parts exposed to high-pressure hydrogen made immune to hydrogen embrittlement if fabricated from new alloy, Incoly 903 (or equivalent). Material strong and compatible with hydrogen at all temperatures and adapted for outlet manifold of Space Shuttle main combustion chamber.

  3. Ohio's First Electrolysis-Based Hydrogen Fueling Station

    Science.gov (United States)

    Demattia, Brianne

    2014-01-01

    Presentation to the earth day coalition describing efforts with NASA GRC and Cleveland RTA on Ohio's hydrogen fueling station and bus demonstration. Project background and goals, challenges and successes, and current status.

  4. 2010 Hydrogen and Fuel Cell Global Commercialization & Development Update

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2010-11-01

    This report offers examples of real-world applications and technical progress of hydrogen and fuel cell technologies, including policies adopted by countries to increase technology development and commercialization.

  5. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2004-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

  6. Polymers for hydrogen infrastructure and vehicle fuel systems :

    Energy Technology Data Exchange (ETDEWEB)

    Barth, Rachel Reina; Simmons, Kevin L.; San Marchi, Christopher W.

    2013-10-01

    This document addresses polymer materials for use in hydrogen service. Section 1 summarizes the applications of polymers in hydrogen infrastructure and vehicle fuel systems and identifies polymers used in these applications. Section 2 reviews the properties of polymer materials exposed to hydrogen and/or high-pressure environments, using information obtained from published, peer-reviewed literature. The effect of high pressure on physical and mechanical properties of polymers is emphasized in this section along with a summary of hydrogen transport through polymers. Section 3 identifies areas in which fuller characterization is needed in order to assess material suitability for hydrogen service.

  7. Hydrogen, Fuel Cells & Infrastructure Technologies Program

    Energy Technology Data Exchange (ETDEWEB)

    2005-03-01

    This plan details the goals, objectives, technical targets, tasks and schedule for EERE's contribution to the DOE Hydrogen Program. Similar detailed plans exist for the other DOE offices that make up the Hydrogen Program.

  8. Hydrogen as an activating fuel for a tidal power plant

    Science.gov (United States)

    Gorlov, A. M.

    Tidal projects, offering a clean, inexhaustible, and fairly predictable energy source, require a system for accumulating energy for off-peak periods. Hydrogen produced by electrolysis during off-peak power plant operation can be used as an activating fuel to furnish the plant during peak load demands. Tidal energy is converted into compressed air energy by special chambers on the ocean bed. This compressed air can be heated by combustion of the stored hydrogen and expanded through high speed gas turbine generators. For off-peak periods, the energy of non-heated compressed air is used for the production of hydrogen fuel. The amount of fuel produced at this time is enough for power plant operation during two peak hours, with three times greater plant capacity. The hydrogen fuel storage method does have energy losses and requires extra capital investment for electrolysis and hydrogen storage equipment. It does not, however, require a gas turbine oil fuel, as does the air compressed storage method, nor a low-speed heavy hydro-turbine, as does the hydro-pumped method. Moreover, the gas turbine can be used for both production and consumption of hydrogen fuel.

  9. Liquid hydrogen as a propulsion fuel, 1945-1959

    Science.gov (United States)

    Sloop, J. L.

    1978-01-01

    A historical review is presented on the research and development of liquid hydrogen for use as a propulsion fuel. The document is divided into three parts: Part 1 (1945-1950); Part 2 (1950-1957); and Part 3 (1957-1958), encompassing eleven topics. Two appendixes are included. Hydrogen Technology Through World War 2; and Propulsion Primer, Performance Parameters and Units.

  10. Novel sugar-to-hydrogen technology promises transportation fuel independence

    OpenAIRE

    Trulove, Susan

    2007-01-01

    The hydrogen economy is not a futuristic concept. The U.S. Department of Energy's 2006 Advance Energy Initiative calls for competitive ethanol from plant sources by 2012 and a good selection of hydrogen-powered fuel cell vehicles by 2020.

  11. SPE (tm) regenerative hydrogen/oxygen fuel cells for extraterrestrial surface and microgravity applications

    Science.gov (United States)

    Mcelroy, J. F.

    1990-01-01

    Viewgraphs on SPE regenerative hydrogen/oxygen fuel cells for extraterrestrial surface and microgravity applications are presented. Topics covered include: hydrogen-oxygen regenerative fuel cell energy storage system; electrochemical cell reactions; SPE cell voltage stability; passive water removal SPE fuel cell; fuel cell performance; SPE water electrolyzers; hydrophobic oxygen phase separator; hydrophilic/electrochemical hydrogen phase separator; and unitized regenerative fuel cell.

  12. Premixer Design for High Hydrogen Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Benjamin P. Lacy; Keith R. McManus; Balachandar Varatharajan; Biswadip Shome

    2005-12-16

    This 21-month project translated DLN technology to the unique properties of high hydrogen content IGCC fuels, and yielded designs in preparation for a future testing and validation phase. Fundamental flame characterization, mixing, and flame property measurement experiments were conducted to tailor computational design tools and criteria to create a framework for predicting nozzle operability (e.g., flame stabilization, emissions, resistance to flashback/flame-holding and auto-ignition). This framework was then used to establish, rank, and evaluate potential solutions to the operability challenges of IGCC combustion. The leading contenders were studied and developed with the most promising concepts evaluated via computational fluid dynamics (CFD) modeling and using the design rules generated by the fundamental experiments, as well as using GE's combustion design tools and practices. Finally, the project scoped the necessary steps required to carry the design through mechanical and durability review, testing, and validation, towards full demonstration of this revolutionary technology. This project was carried out in three linked tasks with the following results. (1) Develop conceptual designs of premixer and down-select the promising options. This task defined the ''gap'' between existing design capabilities and the targeted range of IGCC fuel compositions and evaluated the current capability of DLN pre-mixer designs when operated at similar conditions. Two concepts (1) swirl based and (2) multiple point lean direct injection based premixers were selected via a QFD from 13 potential design concepts. (2) Carry out CFD on chosen options (1 or 2) to evaluate operability risks. This task developed the leading options down-selected in Task 1. Both a GE15 swozzle based premixer and a lean direct injection concept were examined by performing a detailed CFD study wherein the aerodynamics of the design, together with the chemical kinetics of the

  13. Hydrogen-Fuel Engine Component Tests Near Completion

    Science.gov (United States)

    2003-01-01

    Gaseous hydrogen is burned off at the E1 Test Stand the night of Oct. 7 during a cold-flow test of the fuel turbopump of the Integrated Powerhead Demonstrator (IPD) at NASA Stennis Space Center (SSC). The gaseous hydrogen spins the pump's turbine during the test, which was conducted to verify the pump's performance. Engineers plan one more test before sending the pump to The Boeing Co. for inspection. It will then be returned to SSC for engine system assembly. The IPD is the first reusable hydrogen-fueled advanced engine in development since the Space Shuttle Main Engine.

  14. Elimination of abnormal combustion in a hydrogen-fueled engine

    Energy Technology Data Exchange (ETDEWEB)

    Swain, M.R.; Swain, M.N. [Analytical Technologies, Inc., Miami, FL (United States)

    1995-11-01

    This report covers the design, construction, and testing of a dedicated hydrogen-fueled engine. Both part-load and full-load data were taken under laboratory conditions. The engine design included a billet aluminum single combustion chamber cylinder-head with one intake valve, two sodium coiled exhaust valves, and two spark plugs. The cylinder-head design also included drilled cooling passages. The fuel-delivery system employed two modified Siemens electrically actuated fuel injectors, The exhaust system included two separate headers, one for each exhaust port. The piston/ring combination was designed specifically for hydrogen operation.

  15. Hydrogen.

    Science.gov (United States)

    Bockris, John O'M

    2011-11-30

    The idea of a "Hydrogen Economy" is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO₂ in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H₂ from the electrolyzer. Methanol made with CO₂ from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan). Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs) by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech.

  16. Arizona Public Service - Alternative Fuel (Hydrogen) Pilot Plant Design Report

    Energy Technology Data Exchange (ETDEWEB)

    James E. Francfort

    2003-12-01

    Hydrogen has promise to be the fuel of the future. Its use as a chemical reagent and as a rocket propellant has grown to over eight million metric tons per year in the United States. Although use of hydrogen is abundant, it has not been used extensively as a transportation fuel. To assess the viability of hydrogen as a transportation fuel and the viability of producing hydrogen using off-peak electric energy, Pinnacle West Capital Corporation (PNW) and its electric utility subsidiary, Arizona Public Service (APS) designed, constructed, and operates a hydrogen and compressed natural gas fueling station—the APS Alternative Fuel Pilot Plant. This report summarizes the design of the APS Alternative Fuel Pilot Plant and presents lessons learned from its design and construction. Electric Transportation Applications prepared this report under contract to the U.S. Department of Energy’s Advanced Vehicle Testing Activity. The Idaho National Engineering and Environmental Laboratory manages these activities for the Advanced Vehicle Testing Activity.

  17. Light Absorbers and Catalysts for Solar to Fuel Conversion

    Science.gov (United States)

    Kornienko, Nikolay I.

    Increasing fossil fuel consumption and the resulting consequences to the environment has propelled research into means of utilizing alternative, clean energy sources. Solar power is among the most promising of renewable energy sources but must be converted into an energy dense medium such as chemical bonds to render it useful for transport and energy storage. Photoelectrochemistry (PEC), the splitting of water into oxygen and hydrogen fuel or reducing CO 2 to hydrocarbon fuels via sunlight is a promising approach towards this goal. Photoelectrochemical systems are comprised of several components, including light absorbers and catalysts. These parts must all synergistically function in a working device. Therefore, the continual development of each component is crucial for the overall goal. For PEC systems to be practical for large scale use, the must be efficient, stable, and composed of cost effective components. To this end, my work focused on the development of light absorbing and catalyst components of PEC solar to fuel converting systems. In the direction of light absorbers, I focused of utilizing Indium Phosphide (InP) nanowires (NWs) as photocathodes. I first developed synthetic techniques for InP NW solution phase and vapor phase growth. Next, I developed light absorbing photocathodes from my InP NWs towards PEC water splitting cells. I studied cobalt sulfide (CoSx) as an earth abundant catalyst for the reductive hydrogen evolution half reaction. Using in situ spectroscopic techniques, I elucidated the active structure of this catalyst and offered clues to its high activity. In addition to hydrogen evolution catalysts, I established a new generation of earth abundant catalysts for CO2 reduction to CO fuel/chemical feedstock. I first worked with molecularly tunable homogeneous catalysts that exhibited high selectivity for CO2 reduction in non-aqueous media. Next, in order to retain molecular tunability while achieving stability and efficiency in aqueous

  18. Logistic Fuel Processor Development

    National Research Council Canada - National Science Library

    Salavani, Reza

    2004-01-01

    ... to light gases then steam reform the light gases into hydrogen rich stream. This report documents the efforts in developing a fuel processor capable of providing hydrogen to a 3kW fuel cell stack...

  19. Safety Issues with Hydrogen as a Vehicle Fuel

    Energy Technology Data Exchange (ETDEWEB)

    L. C. Cadwallader; J. S. Herring

    1999-09-01

    This report is an initial effort to identify and evaluate safety issues associated with the use of hydrogen as a vehicle fuel in automobiles. Several forms of hydrogen have been considered: gas, liquid, slush, and hydrides. The safety issues have been discussed, beginning with properties of hydrogen and the phenomenology of hydrogen combustion. Safety-related operating experiences with hydrogen vehicles have been summarized to identify concerns that must be addressed in future design activities and to support probabilistic risk assessment. Also, applicable codes, standards, and regulations pertaining to hydrogen usage and refueling have been identified and are briefly discussed. This report serves as a safety foundation for any future hydrogen safety work, such as a safety analysis or a probabilistic risk assessment.

  20. Safety Issues with Hydrogen as a Vehicle Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Cadwallader, Lee Charles; Herring, James Stephen

    1999-10-01

    This report is an initial effort to identify and evaluate safety issues associated with the use of hydrogen as a vehicle fuel in automobiles. Several forms of hydrogen have been considered: gas, liquid, slush, and hydrides. The safety issues have been discussed, beginning with properties of hydrogen and the phenomenology of hydrogen combustion. Safety-related operating experiences with hydrogen vehicles have been summarized to identify concerns that must be addressed in future design activities and to support probabilistic risk assessment. Also, applicable codes, standards, and regulations pertaining to hydrogen usage and refueling have been identified and are briefly discussed. This report serves as a safety foundation for any future hydrogen safety work, such as a safety analysis or a probabilistic risk assessment.

  1. Development of a Turnkey Hydrogen Fueling Station Final Report

    Energy Technology Data Exchange (ETDEWEB)

    David E. Guro; Edward Kiczek; Kendral Gill; Othniel Brown

    2010-07-29

    The transition to hydrogen as a fuel source presents several challenges. One of the major hurdles is the cost-effective production of hydrogen in small quantities (less than 1MMscf/month). In the early demonstration phase, hydrogen can be provided by bulk distribution of liquid or compressed gas from central production plants; however, the next phase to fostering the hydrogen economy will likely include onsite generation and extensive pipeline networks to help effect a pervasive infrastructure. Providing inexpensive hydrogen at a fleet operator’s garage or local fueling station is a key enabling technology for direct hydrogen Fuel Cell Vehicles (FCVs). The objective of this project was to develop a comprehensive, turnkey, stand-alone, commercial hydrogen fueling station for FCVs with state-of-the-art technology that is cost-competitive with current hydrocarbon fuels. Such a station would promote the advent of the hydrogen fuel economy for buses, fleet vehicles, and ultimately personal vehicles. Air Products, partnering with the U.S. Department of Energy (DOE), The Pennsylvania State University, Harvest Energy Technology, and QuestAir, developed a turnkey hydrogen fueling station on the Penn State campus. Air Products aimed at designing a station that would have 65% overall station efficiency, 82% PSA (pressure swing adsorption) efficiency, and the capability of producing hydrogen at $3.00/kg (gge) H2 at mass production rates. Air Products designed a fueling station at Penn State from the ground up. This project was implemented in three phases. The first phase evaluated the various technologies available in hydrogen generation, compression, storage, and gas dispensing. In the second phase, Air Products designed the components chosen from the technologies examined. Finally, phase three entailed a several-month period of data collection, full-scale operation, maintenance of the station, and optimization of system reliability and performance. Based on field data

  2. Analysis of hydrogen as a Transportation Fuel FY17 Report

    Energy Technology Data Exchange (ETDEWEB)

    Pratt, Richard M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Luzi, Francesco [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wilcox Freeburg, Eric D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2017-09-30

    This report summarizes the results of literature reviews, surveys and analyses performed to evaluate the potential of hydrogen-fueled vehicles to be an economically viable transportation alternative. Five existing and important drivers of expanding hydrogen-fueled transportation adoption are multi-billion dollar sales reservations of Nikola Class 8 trucks, CALSTART viability analysis of hybrid-hydrogen drayage trucks in the shipyard cargo application, analysis showing economic advantages of Fuel Cell Electric Vehicles (FCEV)s over Battery Electric Vehicles (BEV)s beginning at 150-mile ranges, the announcement of a commercial 5kg electrolyzer, and commercial plans or vehicle availability by nine vehicle manufacturers of FCEV passenger vehicles. But hydrogen infrastructure availability needed to support broad adoption of hydrogen-fueled vehicles is limited to less than 50 publicly-available refueling stations, primarily in California. The demand side (consumer) economics associated with FCEV adoption showed strong economic sensitivity to the original vehicle’s fuel economy (mpg), distance traveled, and hydrogen (H2) generation costs. Seven use cases were used to evaluate the broad range of potential FCEV purchasers, including autonomous vehicle applications. Each consumer use case analysis resulted in a different hydrogen fuel cost that would be equivalent to the current fuel cost being paid by the consumer. The H2 generation costs (supply side) were sensitive to the volume of H2 supplied and H2 production costs needed to repay H2 supply facility capital costs and produce competitively-priced energy. H2FAST was used to more accurately incorporate capital, maintenance and production costs into a viable H2 supply cost to the consumer. When the H2 generation and consumer economics were combined, several applications with positive economics became clear. The availability of low-cost hydrogen pipeline connections, and therefore low-cost hydrogen, greatly benefits the

  3. Direct-hydrogen-fueled proton-exchange-membrane fuel cell system for transportation applications. Hydrogen vehicle safety report

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, C.E. [Directed Technologies, Inc., Arlington, VA (United States)

    1997-05-01

    This report reviews the safety characteristics of hydrogen as an energy carrier for a fuel cell vehicle (FCV), with emphasis on high pressure gaseous hydrogen onboard storage. The authors consider normal operation of the vehicle in addition to refueling, collisions, operation in tunnels, and storage in garages. They identify the most likely risks and failure modes leading to hazardous conditions, and provide potential countermeasures in the vehicle design to prevent or substantially reduce the consequences of each plausible failure mode. They then compare the risks of hydrogen with those of more common motor vehicle fuels including gasoline, propane, and natural gas.

  4. Light irradiance and spectral distribution effects on cyanobacterial hydrogen production

    Science.gov (United States)

    Fatihah Salleh, Siti; Kamaruddin, Azlina; Hekarl Uzir, Mohamad; Rahman Mohamed, Abdul; Halim Shamsuddin, Abdul

    2016-03-01

    Light is an essential energy source for photosynthetic cyanobacteria. Changes in both light irradiance and spectral distribution will affect their photosynthetic productivity. Compared to the light irradiance, little investigations have been carried out on the effect of light spectra towards cyanobacterial hydrogen production. Hence, this work aims to investigate the effects of both light quantity and quality on biohydrogen productivity of heterocystous cyanobacterium, A.variabilis. Under white light condition, the highest hydrogen production rate of 31 µmol H2 mg chl a -1 h-1 was achieved at 70 µE m-2 s-1. When the experiment was repeated at the same light irradiance but different light spectra of blue, red and green, the accumulations of hydrogen were significantly lower than the white light except for blue light. As the light irradiance was increased to 350 µE m-2 s-1, the accumulated hydrogen under the blue light doubled that of the white light. Besides that, an unusual prolongation of the hydrogen production up to 120 h was observed. The results obtained suggest that blue light could be the most desirable light spectrum for cyanobacterial hydrogen production.

  5. Hydrogen production econometric studies. [hydrogen and fossil fuels

    Science.gov (United States)

    Howell, J. R.; Bannerot, R. B.

    1975-01-01

    The current assessments of fossil fuel resources in the United States were examined, and predictions of the maximum and minimum lifetimes of recoverable resources according to these assessments are presented. In addition, current rates of production in quads/year for the fossil fuels were determined from the literature. Where possible, costs of energy, location of reserves, and remaining time before these reserves are exhausted are given. Limitations that appear to hinder complete development of each energy source are outlined.

  6. HYDROGEN COMMERCIALIZATION: TRANSPORTATION FUEL FOR THE 21ST CENTURY

    Energy Technology Data Exchange (ETDEWEB)

    APOLONIO DEL TORO

    2008-05-27

    Since 1999, SunLine Transit Agency has worked with the U.S. Department of Energy (DOE), U.S. Department of Defense (DOD), and the U.S. Department of Transportation (DOT) to develop and test hydrogen infrastructure, fuel cell buses, a heavy-duty fuel cell truck, a fuel cell neighborhood electric vehicle, fuel cell golf carts and internal combustion engine buses operating on a mixture of hydrogen and compressed natural gas (CNG). SunLine has cultivated a rich history of testing and demonstrating equipment for leading industry manufacturers in a pre-commercial environment. Visitors to SunLine's "Clean Fuels Mall" from around the world have included government delegations and agencies, international journalists and media, industry leaders and experts and environmental and educational groups.

  7. Options for refuelling hydrogen fuel cell vehicles in Italy

    Science.gov (United States)

    Mercuri, R.; Bauen, A.; Hart, D.

    Hydrogen fuel cell vehicle (H 2 FCV) trials are taking place in a number of cities around the world. In Italy, Milan and Turin are the first to have demonstration projects involving hydrogen-fuelled vehicles, in part to satisfy increasing consumer demand for improved environmental performance. The Italian transport plan specifically highlights the potential for FCVs to enter into the marketplace from around 2005. A scenario for FCV penetration into Italy, developed using projected costs for FCV and hydrogen fuel, suggests that by 2015, 2 million Italian cars could be powered by fuel cells. By 2030, 60% of the parc could be FCVs. To develop an infrastructure to supply these vehicles, a variety of options is considered. Large-scale steam reforming, on-site reforming and electrolysis options are analysed, with hydrogen delivered both in liquid and gaseous form. Assuming mature technologies, with over 10,000 units produced, on-site steam reforming provides the most economic hydrogen supply to the consumer, at US 2.6/kg. However, in the early stages of the infrastructure development there is a clear opportunity for on-site electrolysis and for production of hydrogen at centralised facilities, with delivery in the form of liquid hydrogen. This enables additional flexibility, as the hydrogen may also be used for fuel refining or for local power generation. In the current Italian context, energy companies could have a significant role to play in developing a hydrogen infrastructure. The use of hydrogen FCVs can substantially reduce emissions of regulated pollutants and greenhouse gases. Using externality costs for regulated pollutants, it is estimated that the use of hydrogen fuel cell buses in place of 5% of diesel buses in Milan could avoid US 2 million per year in health costs. The addition of even very low externality costs to fuel prices makes the use of untaxed hydrogen in buses and cars, which is slightly more expensive for the motorist than untaxed gasoline or

  8. Demonstrating hydrogen production from ammonia using lithium imide - Powering a small proton exchange membrane fuel cell

    Science.gov (United States)

    Hunter, Hazel M. A.; Makepeace, Joshua W.; Wood, Thomas J.; Mylius, O. Simon; Kibble, Mark G.; Nutter, Jamie B.; Jones, Martin O.; David, William I. F.

    2016-10-01

    Accessing the intrinsic hydrogen content within ammonia, NH3, has the potential to play a very significant role in the future of a CO2-free sustainable energy supply. Inexpensive light metal imides and amides are effective at decomposing ammonia to hydrogen and nitrogen (2NH3 → 3H2 + N2), at modest temperatures, and thus represent a low-cost approach to on-demand hydrogen production. Building upon this discovery, this paper describes the integration of an ammonia cracking unit with a post-reactor gas purification system and a small-scale PEM fuel cell to create a first bench-top demonstrator for the production of hydrogen using light metal imides.

  9. A fuel conservation study for transport aircraft utilizing advanced technology and hydrogen fuel

    Science.gov (United States)

    Berry, W.; Calleson, R.; Espil, J.; Quartero, C.; Swanson, E.

    1972-01-01

    The conservation of fossil fuels in commercial aviation was investigated. Four categories of aircraft were selected for investigation: (1) conventional, medium range, low take-off gross weight; (2) conventional, long range, high take-off gross weights; (3) large take-off gross weight aircraft that might find future applications using both conventional and advanced technology; and (4) advanced technology aircraft of the future powered with liquid hydrogen fuel. It is concluded that the hydrogen fueled aircraft can perform at reduced size and gross weight the same payload/range mission as conventionally fueled aircraft.

  10. Economics of Direct Hydrogen Polymer Electrolyte Membrane Fuel Cell Systems

    Energy Technology Data Exchange (ETDEWEB)

    Mahadevan, Kathyayani

    2011-10-04

    Battelle's Economic Analysis of PEM Fuel Cell Systems project was initiated in 2003 to evaluate the technology and markets that are near-term and potentially could support the transition to fuel cells in automotive markets. The objective of Battelle?s project was to assist the DOE in developing fuel cell systems for pre-automotive applications by analyzing the technical, economic, and market drivers of direct hydrogen PEM fuel cell adoption. The project was executed over a 6-year period (2003 to 2010) and a variety of analyses were completed in that period. The analyses presented in the final report include: Commercialization scenarios for stationary generation through 2015 (2004); Stakeholder feedback on technology status and performance status of fuel cell systems (2004); Development of manufacturing costs of stationary PEM fuel cell systems for backup power markets (2004); Identification of near-term and mid-term markets for PEM fuel cells (2006); Development of the value proposition and market opportunity of PEM fuel cells in near-term markets by assessing the lifecycle cost of PEM fuel cells as compared to conventional alternatives used in the marketplace and modeling market penetration (2006); Development of the value proposition of PEM fuel cells in government markets (2007); Development of the value proposition and opportunity for large fuel cell system application at data centers and wastewater treatment plants (2008); Update of the manufacturing costs of PEM fuel cells for backup power applications (2009).

  11. Diesel fuel processor for hydrogen production for 5 kW fuel cell application

    Energy Technology Data Exchange (ETDEWEB)

    Sopena, D.; Melgar, A.; Briceno, Y. [Fundacion CIDAUT. Parque Tecnologico de Boecillo, P. 209, 47151 Boecillo (Valladolid) (Spain); Navarro, R.M.; Alvarez-Galvan, M.C. [Instituto de Catalisis y Petroquimica (CSIC), C/ Marie Curie 2, Cantoblanco (Madrid) (Spain); Rosa, F. [Instituto Nacional de Tecnica Aeroespacial, Carretera San Juan del Puerto-Matalascanas, km 33, 21130 Mazagon-Moguer (Huelva) (Spain)

    2007-07-15

    The present paper describes a diesel fuel processor designed to produce hydrogen to feed a PEM fuel cell of 5 kW. The fuel processor includes three reactors in series: (1) oxidative steam reforming reactor; (2) one-step water gas shift reactor; and (3) a preferential oxidation reactor. The design of the system was accomplished by means of a one-dimensional model. A specific study of the fuel-air mixing chamber was carried out with Fluent by taking into account fuel evaporation and cool flame processes. The assembly of the installation allowed the characterisation of each component and the control of each working parameter. The first experimental results obtained in the reformer system using decaline and diesel fuels demonstrate the feasibility of the design to produce hydrogen suitable to feed a PEM fuel cell. (author)

  12. Exploration of hydrogen odorants for fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Imamura, Daichi; Akai, Motoaki; Watanabe, Shogo [Japan Automobile Research Institute, 2530 Karima, Tsukuba, Ibaraki 305-0822 (Japan)

    2005-12-01

    The suitability of sulfur compounds (e.g., mercaptan and sulfide) and various sulfur-free smelling compounds for hydrogen odorants were evaluated. The influence of each smelling compound on fuel cell performance was evaluated through the measurement of I-V curves and voltage decline under constant current density, and their condensation properties under high-pressure condition were evaluated by measuring their vapor pressures. The results indicated that all the sulfur compounds evaluated in this study were not suitable as hydrogen odorants since their addition to the hydrogen caused serious degradation of fuel cell performance. Among the sulfur-free compounds, however, some oxygen-containing compounds (2,3-butanedione, ethyl isobutyrate and ethyl sugar lactone) and an unsaturated hydrocarbon (5-ethylidene-2-norbornene) proved to be promising candidates since their adverse effects on the fuel cell performance were minimal and their vapor pressures were adequate. (author)

  13. Exploration of hydrogen odorants for fuel cell vehicles

    Science.gov (United States)

    Imamura, Daichi; Akai, Motoaki; Watanabe, Shogo

    The suitability of sulfur compounds (e.g., mercaptan and sulfide) and various sulfur-free smelling compounds for hydrogen odorants were evaluated. The influence of each smelling compound on fuel cell performance was evaluated through the measurement of I- V curves and voltage decline under constant current density, and their condensation properties under high-pressure condition were evaluated by measuring their vapor pressures. The results indicated that all the sulfur compounds evaluated in this study were not suitable as hydrogen odorants since their addition to the hydrogen caused serious degradation of fuel cell performance. Among the sulfur-free compounds, however, some oxygen-containing compounds (2,3-butanedione, ethyl isobutyrate and ethyl sugar lactone) and an unsaturated hydrocarbon (5-ethylidene-2-norbornene) proved to be promising candidates since their adverse effects on the fuel cell performance were minimal and their vapor pressures were adequate.

  14. Hydrogen release properties of lithium alanate for application to fuel cell propulsion systems

    Science.gov (United States)

    Corbo, P.; Migliardini, F.; Veneri, O.

    In this paper the results of an experimental study on LiAlH 4 (lithium alanate) as hydrogen source for fuel cell propulsion systems are reported. The compound examined in this work was selected as reference material for light metal hydrides, because of its high hydrogen content (10.5 wt.%) and interesting desorption kinetic properties at moderate temperatures. Thermal dynamic and kinetic of hydrogen release from this hydride were investigated using a fixed bed reactor to evaluate the effect of heating procedure, carrier gas flow rate and sample form. The aim of this study was to characterize the lithium alanate decomposition through the reaction steps leading to the formation of Li 3AlH 6 and LiH. A hydrogen tank was designed and realized to contain pellets of lithium alanate as feeding for a fuel cell propulsion system based on a 2-kW Polymeric Electrolyte Fuel Cell (PEFC) stack. The fuel cell system was integrated into the power train comprising DC-DC converter, energy storage systems and electric drive for moped applications (3 kW). The experiments on the power train were conducted on a test bench able to simulate the vehicle behaviour and road characteristics on specific driving cycles. In particular the efficiencies of individual components and overall power train were analyzed evidencing the energy requirements of the hydrogen storage material.

  15. Steam and partial oxidation reforming options for hydrogen production from fossil fuels for PEM fuel cells

    Directory of Open Access Journals (Sweden)

    Yousri M.A. Welaya

    2012-06-01

    Full Text Available Proton exchange membrane fuel cell (PEM generates electrical power from air and from hydrogen or hydrogen rich gas mixtures. Therefore, there is an increasing interest in converting current hydrocarbon based marine fuels such as natural gas, gasoline, and diesel into hydrogen rich gases acceptable to the PEM fuel cells on board ships. Using chemical flow sheeting software, the total system efficiency has been calculated. Natural gas appears to be the best fuel for hydrogen rich gas production due to its favorable composition of lower molecular weight compounds. This paper presents a study for a 250 kW net electrical power PEM fuel cell system utilizing a partial oxidation in one case study and steam reformers in the second. This study has shown that steam-reforming process is the most competitive fuel processing option in terms of fuel processing efficiency. Partial oxidation process has proved to posses the lowest fuel processing efficiency. Among the options studied, the highest fuel processing efficiency is achieved with natural gas steam reforming system.

  16. Hydrogen as an Auxiliary Fuel in Compression-Ignition Engines

    Science.gov (United States)

    Gerrish, Harold C; Foster, H

    1936-01-01

    An investigation was made to determine whether a sufficient amount of hydrogen could be efficiently burned in a compression-ignition engine to compensate for the increase of lift of an airship due to the consumption of the fuel oil. The performance of a single-cylinder four-stroke-cycle compression-ignition engine operating on fuel oil alone was compared with its performance when various quantities of hydrogen were inducted with the inlet air. Engine-performance data, indicator cards, and exhaust-gas samples were obtained for each change in engine-operating conditions.

  17. Near-surface alloys for hydrogen fuel cell applications

    DEFF Research Database (Denmark)

    Greeley, Jeffrey Philip; Mavrikakis, Manos

    2006-01-01

    facile H-2 activation. These NSAs could, potentially, facilitate highly selective hydrogenation reactions at low temperatures. In the present work, the suitability of NSAs for use as hydrogen fuel cell anodes has been evaluated: the combination of properties, possessed by selected NSAs, of weak binding...... of such materials for use in fuel cells and in an ever. increasing range of catalytic applications. Furthermore, we introduce a new concept for NSA-defect sites, which could be responsible for the promotional catalytic effects of a second metal added. even in minute quantities, to a host metal catalyst....

  18. Direct hydrogen fuel cell systems for hybrid vehicles

    Science.gov (United States)

    Ahluwalia, Rajesh K.; Wang, X.

    Hybridizing a fuel cell system with an energy storage system offers an opportunity to improve the fuel economy of the vehicle through regenerative braking and possibly to increase the specific power and decrease the cost of the combined energy conversion and storage systems. Even in a hybrid configuration it is advantageous to operate the fuel cell system in a load-following mode and use the power from the energy storage system when the fuel cell alone cannot meet the power demand. This paper discusses an approach for designing load-following fuel cell systems for hybrid vehicles and illustrates it by applying it to pressurized, direct hydrogen, polymer-electrolyte fuel cell (PEFC) systems for a mid-size family sedan. The vehicle level requirements relative to traction power, response time, start-up time and energy conversion efficiency are used to select the important parameters for the PEFC stack, air management system, heat rejection system and the water management system.

  19. Hydrogen Fuel Cells and Storage Technology: Fundamental Research for Optimization of Hydrogen Storage and Utilization

    Energy Technology Data Exchange (ETDEWEB)

    Perret, Bob; Heske, Clemens; Nadavalath, Balakrishnan; Cornelius, Andrew; Hatchett, David; Bae, Chusung; Pang, Tao; Kim, Eunja; Hemmers, Oliver

    2011-03-28

    Design and development of improved low-cost hydrogen fuel cell catalytic materials and high-capacity hydrogenn storage media are paramount to enabling the hydrogen economy. Presently, effective and durable catalysts are mostly precious metals in pure or alloyed form and their high cost inhibits fuel cell applications. Similarly, materials that meet on-board hydrogen storage targets within total mass and volumetric constraints are yet to be found. Both hydrogen storage performance and cost-effective fuel cell designs are intimately linked to the electronic structure, morphology and cost of the chosen materials. The FCAST Project combined theoretical and experimental studies of electronic structure, chemical bonding, and hydrogen adsorption/desorption characteristics of a number of different nanomaterials and metal clusters to develop better fundamental understanding of hydrogen storage in solid state matrices. Additional experimental studies quantified the hydrogen storage properties of synthesized polyaniline(PANI)/Pd composites. Such conducting polymers are especially interesting because of their high intrinsic electron density and the ability to dope the materials with protons, anions, and metal species. Earlier work produced contradictory results: one study reported 7% to 8% hydrogen uptake while a second study reported zero hydrogen uptake. Cost and durability of fuel cell systems are crucial factors in their affordability. Limits on operating temperature, loss of catalytic reactivity and degradation of proton exchange membranes are factors that affect system durability and contribute to operational costs. More cost effective fuel cell components were sought through studies of the physical and chemical nature of catalyst performance, characterization of oxidation and reduction processes on system surfaces. Additional development effort resulted in a new hydrocarbon-based high-performance sulfonated proton exchange membrane (PEM) that can be manufactured at low

  20. Proceedings of the 5th International workshop on hydrogen and fuel cells WICaC 2010

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    The 5th International Workshop on Hydrogen and Fuel Cells - WICaC 2010 aims to bring the most recent advances on fuel cell and hydrogen technologies. The conference will address the trends on hydrogen production, distribution, delivery, storage and infrastructure as well as fuel cell research, development, demonstration and commercialization. Some of the issues addressed at WICaC 2010 are: the official Brazilian hydrogen and fuel cell programs and its participation in the international programs and partnerships such as the IPHE (The International Partnership for Hydrogen and Fuel Cells in the Economy); the integration of renewable energy sources with hydrogen and fuel cell systems; the challenges to deploy the commercialization and use of fuel cells and hydrogen; distributed generation of energy; fuel cell uses in portable devices and in vehicles; life-cycle assessment of fuel cells and hydrogen technologies; environmental aspects; energy efficiency.

  1. Design and Control of a Hydrogen Fuel Cell Vehicle

    OpenAIRE

    Bell, Joseph

    2016-01-01

    Starting with the chassis of a 1969 Volkswagen Beetle, the goal of this project was to design and build a Proton Exchange Membrane Fuel Cell (PEMFC) hybrid vehicle that is powered by hydrogen. This thesis highlights the design process, modeling, and control of a Proton Exchange Membrane Fuel Cell hybrid drive train. Finally, the vehicle was built with many of the components assembled, fabricated, and functioning.

  2. Solid Hydrogen Particles and Flow Rates Analyzed for Atomic Fuels

    Science.gov (United States)

    Palaszewski, Bryan A.

    2003-01-01

    The experiments were conducted at Glenn's Small Multipurpose Research Facility (SMIRF, ref. 5). The experimental setup was placed in the facility's vacuum tank to prevent heat leaks and subsequent boiloff of the liquid helium. Supporting systems maintained the temperature and pressure of the liquid helium bath where the solid particles were created. Solid hydrogen particle formation was tested from February 23 to April 2, 2001. Millimeter-sized solid-hydrogen particles were formed in a Dewar of liquid helium as a prelude to creating atomic fuels and propellants for aerospace vehicles. Atomic fuels or propellants are created when atomic boron, carbon, or hydrogen is stored in solid hydrogen particles. The current testing characterized the solid hydrogen particles without the atomic species, as a first step to creating a feed system for the atomic fuels and propellants. This testing did not create atomic species, but only sought to understand the solid hydrogen particle formation and behavior in the liquid helium. In these tests, video images of the solid particle formation were recorded, and the total mass flow rate of the hydrogen was measured. The mass of hydrogen that went into the gaseous phase was also recorded using a commercially available residual gas analyzer. The temperatures, pressures, and flow rates of the liquids and gases in the test apparatus were recorded as well. Testing conducted in 1999 recorded particles as small as 2 to 5 mm in diameter. The current testing extended the testing conditions to a very cold Dewar ullage gas of about 20 to 90 K above the 4 K liquid helium. With the very cold Dewar gas, the hydrogen freezing process took on new dimensions, in some cases creating particles so small that they seemed to be microscopic, appearing as infinitesimally small scintillations on the videotaped images.

  3. A new high strength alloy for hydrogen fueled propulsion systems

    Science.gov (United States)

    Mcpherson, W. B.

    1986-01-01

    This paper describes the development of a high-strength alloy (1241 MPa ultimate and 1103 MPa yield, with little or no degradation in hydrogen) for application in advanced hydrogen-fueled rocket engines. Various compositions of the Fe-Ni-Co-Cr system with elemental additions of Cb, Ti and Al are discussed. After processing, notched tensile specimens were tested in 34.5-MPa hydrogen at room temperature, as the main screening test. The H2/air notch tensile ratio was used as the selection/rejection criterion. The most promising alloys are discussed.

  4. Fuel cell commercialization: The key to a hydrogen economy

    Science.gov (United States)

    Zegers, P.

    With the current level of global oil production, oil reserves will be sufficient for 40 years. However, due to the fact that the global GDP will have increased by a factor seven in 2050, oil reserves are likely to be exhausted in a much shorter time period. The EU and car industry aim at a reduction of the consumption of oil, at energy savings (with a key role for fuel cells) and an increased use of hydrogen from natural gas and, possibly, coal, in the medium term. The discovery of huge methane resources as methane hydrates (20 times those of oil, gas and coal together) in oceans at 1000-3000 m depth could be of major importance. In the long term, the EU aims at a renewable energy-based energy supply. The European Hydrogen and Fuel Cell Technology Platform is expected to play a major role in bringing about a hydrogen economy. The availability of commercial fuel cells is here a prerequisite. However, after many years of research, fuel cells have not yet been commercialized. If they will not succeed to enter the market within 5 years there is a real danger that activities aiming at a hydrogen society will peter out. In a hydrogen strategy, high priority should therefore be given to actions which will bring about fuel cell commercialization within 5 years. They should include the identification of fuel cell types and (niche) markets which are most favorable for a rapid market introduction. These actions should include focused short-term RTD aiming at cost reduction and increased reliability.

  5. Spanish R and D programs on hydrogen and fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez Garcia-Conde, A.; Ben Pendones, R. [Instituto Nacional de Tecnica Aeroespacial (INTA), Departamento de Aerodinamica y Propulsion, Madrid (Spain)

    2003-09-01

    Since 1988 INTA (the National Institute for Aerospace Technology in Spain) has been running hydrogen and fuel cells activities supported by own funds. Up to 1996, subsidies from the regional government of Andalucia (south of Spain), were provided for building a solar hydrogen production pilot plant based on photovoltaic powered water electrolysis. At present there is not a specific programme devoted to hydrogen energy and fuel cells in Spain, however, the Spanish Plan for Scientific Research, Technological Development and Innovation (2004-2007) in the energy area, will consider these topics as separate items included in the priority devoted to renewable energies and emerging technologies. This means that part of the R and D budget will be allocated for hydrogen and fuel cells projects but competing with the rest of renewable energies projects. Nevertheless the possibilities to approve projects for national funding are considered in a very wide and detailed way in the rationale of the national R and D programme, as mentioned in the following paragraphs: Hydrogen, by means of fuel cells technological evolution, presents a potential to become in the long term an energy carrier that changes the energetic sector configuration, making it safer, more efficient and more respectful with environment. For achieving this goal, a number of technological barriers must be overcome within production, storage, distribution and final supply, both for its utilization in transport and stationary applications. Fuel Cells are gaining in Spain increasing importance both for stationary and transport utilization, as a consequence of its different types, modular characteristics and the possibility for utilization in different applications, as domestic use, distributed and centralized generation. Due to its wide variety of possibilities and its characteristics of low environmental impact and reduced noise production, fuel cells become themselves a energetic objective. (O.M.)

  6. Solid Hydrogen Particles Analyzed for Atomic Fuels

    Science.gov (United States)

    Palaszewski, Bryan A.

    2001-01-01

    Solid hydrogen particles have been selected as a means of storing atomic propellants in future launch vehicles (refs. 1 to 2). In preparation for this, hydrogen particle formation in liquid helium was tested experimentally. These experiments were conducted to visually characterize the particles and to observe their formation and molecular transformations (aging) while in liquid helium. The particle sizes, molecular transformations, and agglomeration times were estimated from video image analyses. The experiments were conducted at the NASA Glenn Research Center in the Supplemental Multilayer Insulation Research Facility (SMIRF, ref. 3). The facility has a vacuum tank, into which the experimental setup was placed. The vacuum tank prevented heat leaks and subsequent boiloff of the liquid helium, and the supporting systems maintained the temperature and pressure of the liquid helium bath where the solid particles were created. As the operation of the apparatus was developed, the hydrogen particles were easily visualized. The figures (ref. 1) show images from the experimental runs. The first image shows the initial particle freezing, and the second image shows the particles after the small particles have agglomerated. The particles finally all clump, but stick together loosely. The solid particles tended to agglomerate within a maximum of 11 min, and the agglomerate was very weak. Because the hydrogen particles are buoyant in the helium, the agglomerate tends to compact itself into a flat pancake on the surface of the helium. This pancake agglomerate is easily broken apart by reducing the pressure above the liquid. The weak agglomerate implies that the particles can be used as a gelling agent for the liquid helium, as well as a storage medium for atomic boron, carbon, or hydrogen. The smallest particle sizes that resulted from the initial freezing experiments were about 1.8 mm. About 50 percent of the particles formed were between 1.8 to 4.6 mm in diameter. These very

  7. Electrogenerated hydrogen peroxide and fuel cells

    OpenAIRE

    McDonnell-Worth, Ciaran James

    2017-01-01

    This thesis focuses on the electrochemical production of H₂O₂ via water oxidation and its subsequent use as a fuel in direct H₂O₂ fuel cells. H₂O₂ is a useful chemical both in industrial and scientific applications as it is not only a strong oxidant but also produces no harmful by-products when it is used as such. Shortly prior to the commencement of this thesis it was found that H₂O₂ may be produced electrochemically via water oxidation. This process only occurred in a specific electroly...

  8. Fuel processor for fuel cell power system. [Conversion of methanol into hydrogen

    Science.gov (United States)

    Vanderborgh, N.E.; Springer, T.E.; Huff, J.R.

    1986-01-28

    A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

  9. Biorefinery and Hydrogen Fuel Cell Research

    Energy Technology Data Exchange (ETDEWEB)

    K.C. Das; Thomas T. Adams; Mark A. Eiteman; John Stickney; Joy Doran Peterson; James R. Kastner; Sudhagar Mani; Ryan Adolphson

    2012-06-12

    In this project we focused on several aspects of technology development that advances the formation of an integrated biorefinery. These focus areas include: [1] establishment of pyrolysis processing systems and characterization of the product oils for fuel applications, including engine testing of a preferred product and its pro forma economic analysis; [2] extraction of sugars through a novel hotwater extaction process, and the development of levoglucosan (a pyrolysis BioOil intermediate); [3] identification and testing of the use of biochar, the coproduct from pyrolysis, for soil applications; [4] developments in methods of atomic layer epitaxy (for efficient development of coatings as in fuel cells); [5] advancement in fermentation of lignocellulosics, [6] development of algal biomass as a potential substrate for the biorefinery, and [7] development of catalysts from coproducts. These advancements are intended to provide a diverse set of product choices within the biorefinery, thus improving the cost effectiveness of the system. Technical effectiveness was demonstrated in the pyrolysis biooil based diesel fuel supplement, sugar extraction from lignocelluose, use of biochar, production of algal biomass in wastewaters, and the development of catalysts. Economic feasibility of algal biomass production systems seems attractive, relative to the other options. However, further optimization in all paths, and testing/demonstration at larger scales are required to fully understand the economic viabilities. The various coproducts provide a clear picture that multiple streams of value can be generated within an integrated biorefinery, and these include fuels and products.

  10. Hydrogen peroxide oxidant fuel cell systems for ultra-portable applications

    Science.gov (United States)

    Valdez, T. I.; Narayanan, S. R.

    2001-01-01

    This paper will address the issues of using hydrogen peroxide as an oxidant fuel in a miniature DMFC system. Cell performance for DMFC based fuel cells operating on hydrogen peroxide will be presented and discussed.

  11. Air-cooled, hydrogen-air fuel cell

    Science.gov (United States)

    Shelekhin, Alexander B. (Inventor); Bushnell, Calvin L. (Inventor); Pien, Michael S. (Inventor)

    1999-01-01

    An air-cooled, hydrogen-air solid polymer electrolyte (SPE) fuel cell with a membrane electrode assembly operatively associated with a fluid flow plate having at least one plate cooling channel extending through the plate and at least one air distribution hole extending from a surface of the cathode flow field into the plate cooling channel.

  12. Energizing Engineering Students with Hydrogen Fuel Cell Project

    Science.gov (United States)

    Cannell, Nori; Zavaleta, Dan

    2010-01-01

    At Desert Vista High School, near Phoenix, Arizona, Perkins Innovation Grant funding is being used to fund a program that is helping to prepare students for careers in engineering by giving them hands-on experience in areas like hydrogen generation and fuel cell utilization. As one enters Dan Zavaleta's automotive and engineering classroom and lab…

  13. Integrating Wind And Solar With Hydrogen Producing Fuel Cells

    NARCIS (Netherlands)

    Hemmes, K.

    2007-01-01

    The often proposed solution for the fluctuating wind energy supply is the conversion of the surplus of wind energy into hydrogen by means of electrolysis. In this paper a patented alternative is proposed consisting of the integration of wind turbines with internal reforming fuel-cells, capable of

  14. Hydrogen as energy-storage-medium and fuel

    Directory of Open Access Journals (Sweden)

    Töpler Johannes

    2016-01-01

    Full Text Available This contribution addresses the future energy situation with the expected reduction of fossil primary energy supply and increasing market segments by renewable energies within the next decades. The potential of renewable energies to cover the energy demand is described as well as the necessity of energy storage systems (especially hydrogen to compensate the fluctuations of primary energy sources. Furthermore the increasing use of renewable vehicle fuels is investigated with special focus on hydrogen in short and long-term considerations. As a result the paper will show an energy supply gap between decreasing fossil energies and increasing renewable energies which can only be bridged by a more efficient general use of energy. Hydrogen will be proven as best synthetic fuel by “well-to-wheel analysis” both with respect to energy efficiency, to environmental analysis as well as to customer satisfaction.

  15. Fuel processor and method for generating hydrogen for fuel cells

    Science.gov (United States)

    Ahmed, Shabbir [Naperville, IL; Lee, Sheldon H. D. [Willowbrook, IL; Carter, John David [Bolingbrook, IL; Krumpelt, Michael [Naperville, IL; Myers, Deborah J [Lisle, IL

    2009-07-21

    A method of producing a H.sub.2 rich gas stream includes supplying an O.sub.2 rich gas, steam, and fuel to an inner reforming zone of a fuel processor that includes a partial oxidation catalyst and a steam reforming catalyst or a combined partial oxidation and stream reforming catalyst. The method also includes contacting the O.sub.2 rich gas, steam, and fuel with the partial oxidation catalyst and the steam reforming catalyst or the combined partial oxidation and stream reforming catalyst in the inner reforming zone to generate a hot reformate stream. The method still further includes cooling the hot reformate stream in a cooling zone to produce a cooled reformate stream. Additionally, the method includes removing sulfur-containing compounds from the cooled reformate stream by contacting the cooled reformate stream with a sulfur removal agent. The method still further includes contacting the cooled reformate stream with a catalyst that converts water and carbon monoxide to carbon dioxide and H.sub.2 in a water-gas-shift zone to produce a final reformate stream in the fuel processor.

  16. Performance optimization of a PEM hydrogen-oxygen fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Sadiq Al-Baghdadi, Maher A.R. [Fuel Cell Research Center, International Energy and Environment Foundation, Al-Najaf, P.O.Box 39 (Iraq)

    2013-07-01

    The objective was to develop a semi-empirical model that would simulate the performance of proton exchange membrane (PEM) fuel cells without extensive calculations. A fuel cell mathematical module has been designed and constructed to determine the performance of a PEM fuel cell. The influence of some operating parameters on the performance of PEM fuel cell has been investigated using pure hydrogen on the anode side and oxygen on the cathode side. The present model can be used to investigate the influence of process variables for design optimization of fuel cells, stacks, and complete fuel cell power system. The possible mechanisms of the parameter effects and their interrelationships are discussed. In order to assess the validity of the developed model a real PEM fuel cell system has been used to generate experimental data. The comparison shows good agreements between the modelling results and the experimental data. The model is shown a very useful for estimating the performance of PEM fuel cell stacks and optimization of fuel cell system integration and operation.

  17. Possibility of hydrogen supply by shared residential fuel cell systems for fuel cell vehicles

    Directory of Open Access Journals (Sweden)

    Ono Yusuke

    2017-01-01

    Full Text Available Residential polymer electrolyte fuel cells cogeneration systems (residential PEFC systems produce hydrogen from city gas by internal gas-reformer, and generate electricity, the hot water at the same time. From the viewpoint of the operation, it is known that residential PEFC systems do not continuously work but stop for long time, because the systems generate enough hot water for short operation time. In other words, currently residential PEFC systems are dominated by the amount of hot water demand. This study focuses on the idle time of residential PEFC systems. Since their gas-reformers are free, the systems have potential to produce hydrogen during the partial load operations. The authors expect that residential PEFC systems can take a role to supply hydrogen for fuel cell vehicles (FCVs before hydrogen fueling stations are distributed enough. From this perspective, the objective of this study is to evaluate the hydrogen production potential of residential PEFC systems. A residential PEFC system was modeled by the mixed integer linear programming to optimize the operation including hydrogen supply for FCV. The objective function represents annual system cost to be minimized with the constraints of energy balance. It should be noted that the partial load characteristics of the gas-reformer and the fuel cell stack are taken into account to derive the optimal operation. The model was employed to estimate the possible amount of hydrogen supply by a residential PEFC system. The results indicated that the system could satisfy at least hydrogen demand for transportation of 8000 km which is as far as the average annual mileage of a passenger car in Japan. Furthermore, hydrogen production by sharing a residential PEFC system with two households is more effective to reduce primary energy consumption with hydrogen supply for FCV than the case of introducing PEFC in each household.

  18. HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER

    Energy Technology Data Exchange (ETDEWEB)

    BROWN,LC; BESENBRUCH,GE; LENTSCH,RD; SCHULTZ,KR; FUNK,JF; PICKARD,PS; MARSHALL,AC; SHOWALTER,SK

    2003-06-01

    OAK B202 HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER. Combustion of fossil fuels, used to power transportation, generate electricity, heat homes and fuel industry provides 86% of the world's energy. Drawbacks to fossil fuel utilization include limited supply, pollution, and carbon dioxide emissions. Carbon dioxide emissions, thought to be responsible for global warming, are now the subject of international treaties. Together, these drawbacks argue for the replacement of fossil fuels with a less-polluting potentially renewable primary energy such as nuclear energy. Conventional nuclear plants readily generate electric power but fossil fuels are firmly entrenched in the transportation sector. Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. Hydrogen will be particularly advantageous when coupled with fuel cells. Fuel cells have higher efficiency than conventional battery/internal combustion engine combinations and do not produce nitrogen oxides during low-temperature operation. Contemporary hydrogen production is primarily based on fossil fuels and most specifically on natural gas. When hydrogen is produced using energy derived from fossil fuels, there is little or no environmental advantage. There is currently no large scale, cost-effective, environmentally attractive hydrogen production process available for commercialization, nor has such a process been identified. The objective of this work is to find an economically feasible process for the production of hydrogen, by nuclear means, using an advanced high-temperature nuclear reactor as the primary energy source. Hydrogen production by thermochemical water-splitting (Appendix A), a chemical process that accomplishes the decomposition of water into hydrogen and oxygen using only heat or, in the case of a hybrid thermochemical process, by a combination of heat and electrolysis, could meet these goals. Hydrogen produced from

  19. British Columbia hydrogen and fuel cell strategy : an industry vision for our hydrogen future

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-05-15

    British Columbia's strategy for global leadership in hydrogen fuel cell technology was outlined. It was suggested that hydrogen and fuel cells will power a significant portion of the province by 2020, and will be used in homes, businesses, industry and transportation. The following 3 streams of activity were identified as leading to the achievement of this vision: (1) a hydrogen highway of technology demonstrations in vehicles, refuelling facilities and stationary power systems in time for and building on the 2010 Winter Olympic and Paralympic Games, (2) the development of a globally leading sustainable energy technology cluster that delivers products and services as well as securing high-value jobs, and (3) the renewal of the province's resource heartlands to supply the fuel and knowledge base for hydrogen-based communities and industries, and clean hydrogen production and distribution. It was suggested that in order to achieve the aforementioned goals, the government should promote the hydrogen highway and obtain $135 million in funding from various sources. It was recommended that the BC government and members of industry should also work with the federal government and other provinces to make Canada an early adopter market. Creative markets for BC products and services both in Canada and abroad will be accomplished by global partnerships, collaboration with Alberta and the United States. It was suggested that in order to deploy clean energy technologies, BC must integrate their strategy into the province's long-term sustainable energy plan. It was concluded that the hydrogen and fuel cell cluster has already contributed to the economy through jobs, private sector investment and federal and provincial tax revenues. The technology cluster's revenues have been projected at $3 billion with a workforce of 10,000 people by 2010. The hydrogen economy will reduce provincial air emissions, improve public health, and support sustainable tourism

  20. 78 FR 60866 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC)

    Science.gov (United States)

    2013-10-02

    ... Hydrogen and Fuel Cell Technical Advisory Committee (HTAC) AGENCY: Office of Energy Efficiency and... open meeting of the Hydrogen and Fuel Cell Technical Advisory Committee (HTAC). The Federal Advisory... Avenue, Washington, DC 20585. SUPPLEMENTARY INFORMATION: Purpose of the Committee: The Hydrogen and Fuel...

  1. 77 FR 65542 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC)

    Science.gov (United States)

    2012-10-29

    ... of Energy Efficiency and Renewable Energy Hydrogen and Fuel Cell Technical Advisory Committee (HTAC... Meeting. SUMMARY: The Hydrogen and Fuel Cell Technical Advisory Committee (HTAC) was established under... web at: http://hydrogen.energy.gov ). Public Comment DOE Program Updates Congressional Fuel Cell...

  2. 78 FR 6086 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC)

    Science.gov (United States)

    2013-01-29

    ... Hydrogen and Fuel Cell Technical Advisory Committee (HTAC) AGENCY: Office of Energy Efficiency and... announces an open meeting (Webinar) of the Hydrogen and Fuel Cell Technical Advisory Committee (HTAC). The..., DC 20585. SUPPLEMENTARY INFORMATION: Purpose of the Committee: The Hydrogen and Fuel Cell Technical...

  3. 78 FR 18578 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC)

    Science.gov (United States)

    2013-03-27

    ... of Energy Efficiency and Renewable Energy Hydrogen and Fuel Cell Technical Advisory Committee (HTAC... Meeting. SUMMARY: This notice announces an open meeting of the Hydrogen and Fuel Cell Technical Advisory.... SUPPLEMENTARY INFORMATION: Purpose of the Committee: The Hydrogen and Fuel Cell Technical Advisory Committee...

  4. 77 FR 18243 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC); Notice of Open Meeting

    Science.gov (United States)

    2012-03-27

    ... Hydrogen and Fuel Cell Technical Advisory Committee (HTAC); Notice of Open Meeting AGENCY: Office of Energy... announces a meeting of the Hydrogen and Fuel Cell Technical Advisory Committee (HTAC). The Federal Advisory...., Washington, DC 20585. SUPPLEMENTARY INFORMATION: Purpose of the Committee: The Hydrogen and Fuel Cell...

  5. A study of spin isomer conversion kinetics in supercritical fluid hydrogen for cyrogenic fuel storage technologies

    Science.gov (United States)

    Matthews, Manyalibo J.; Petitpas, Guillaume; Aceves, Salvador M.

    2011-08-01

    A detailed kinetic study of para-ortho hydrogen conversion under supercritical conditions using rotational Raman scattering is presented. Isochoric measurements of initially low ortho concentrations over temperatures 32 hydrogen fuel tank dormancy performance for hydrogen-power vehicles.

  6. Hydrogen storage performance of functionalized hexagonal boron nitride for fuel cell applications

    Science.gov (United States)

    Muthu, R. Naresh; Rajashabala, S.; Kannan, R.

    2017-05-01

    Developing light weight, safe, efficient and compact hydrogen storage medium are still the major concerns for the blooming of hydrogen based energy economy. In the present article, activated hexagonal boron nitride (ABN) and ABN functionalized with lithium borohydride (ABN-LiBH4) nanocomposite based hydrogen storage medium are synthesized. where a facile solvent-assistant technique was adopted for the preparation of ABN-LiBH4 nanocomposite. The prepared hydrogen storage medium was subjected to various characterization techniques such as XRD, FTIR, SEM, EDX, CHNS - elemental analysis and TGA. Sievert's-like hydrogenation setup has been utilized for hydrogenation studies. It is noticed that the ABN-LiBH4 nanocomposite exhibits an attractive high gravimetric density of 1.67 wt% at 100 °C than pristine ABN. Moreover the stored hydrogen is released in the temperature range of 115 - 150 °C and possesses an average binding energy of 0.31 eV. These results indicate that the prepared ABN-LiBH4 nanocomposite paves a way to potential solid state hydrogen storage medium towards fuel cell technology as per the targets set by US Department of Energy (DOE).

  7. Hydrogen Fuel Capability Added to Combustor Flametube Rig

    Science.gov (United States)

    Frankenfield, Bruce J.

    2003-01-01

    Facility capabilities have been expanded at Test Cell 23, Research Combustor Lab (RCL23) at the NASA Glenn Research Center, with a new gaseous hydrogen fuel system. The purpose of this facility is to test a variety of fuel nozzle and flameholder hardware configurations for use in aircraft combustors. Previously, this facility only had jet fuel available to perform these various combustor flametube tests. The new hydrogen fuel system will support the testing and development of aircraft combustors with zero carbon dioxide (CO2) emissions. Research information generated from this test rig includes combustor emissions and performance data via gas sampling probes and emissions measuring equipment. The new gaseous hydrogen system is being supplied from a 70 000-standard-ft3 tube trailer at flow rates up to 0.05 lb/s (maximum). The hydrogen supply pressure is regulated, and the flow is controlled with a -in. remotely operated globe valve. Both a calibrated subsonic venturi and a coriolis mass flowmeter are used to measure flow. Safety concerns required the placement of all hydrogen connections within purge boxes, each of which contains a small nitrogen flow that is vented past a hydrogen detector. If any hydrogen leaks occur, the hydrogen detectors alert the operators and automatically safe the facility. Facility upgrades and modifications were also performed on other fluids systems, including the nitrogen gas, cooling water, and air systems. RCL23 can provide nonvitiated heated air to the research combustor, up to 350 psig at 1200 F and 3.0 lb/s. Significant modernization of the facility control systems and the data acquisition systems was completed. A flexible control architecture was installed that allows quick changes of research configurations. The labor-intensive hardware interface has been removed and changed to a software-based system. In addition, the operation of this facility has been greatly enhanced with new software programming and graphic operator interface

  8. A polymer electrolyte fuel cell stack for stationary power generation from hydrogen fuel

    Energy Technology Data Exchange (ETDEWEB)

    Zawodzinski, C.; Wilson, M.; Gottesfeld, S. [Los Alamos National Lab., NM (United States)

    1996-10-01

    The fuel cell is the most efficient device for the conversion of hydrogen fuel to electric power. As such, the fuel cell represents a key element in efforts to demonstrate and implement hydrogen fuel utilization for electric power generation. A central objective of a LANL/Industry collaborative effort supported by the Hydrogen Program is to integrate PEM fuel cell and novel stack designs at LANL with stack technology of H-Power Corporation (H-Power) in order to develop a manufacturable, low-cost/high-performance hydrogen/air fuel cell stack for stationary generation of electric power. A LANL/H-Power CRADA includes Tasks ranging from exchange, testing and optimization of membrane-electrode assemblies of large areas, development and demonstration of manufacturable flow field, backing and bipolar plate components, and testing of stacks at the 3-5 cell level and, finally, at the 4-5 kW level. The stack should demonstrate the basic features of manufacturability, overall low cost and high energy conversion efficiency. Plans for future work are to continue the CRADA work along the time line defined in a two-year program, to continue the LANL activities of developing and testing stainless steel hardware for longer term stability including testing in a stack, and to further enhance air cathode performance to achieve higher energy conversion efficiencies as required for stationary power application.

  9. Experimental results with hydrogen fueled internal combustion engines

    Science.gov (United States)

    De Boer, P. C. T.; Mclean, W. J.; Homan, H. S.

    1975-01-01

    The paper focuses on the most important experimental findings for hydrogen-fueled internal combustion engines, with particular reference to the application of these findings to the assessment of the potential of hydrogen engines. Emphasis is on the various tradeoffs that can be made, such as between maximum efficiency, maximum power, and minimum NO emissions. The various possibilities for induction and ignition are described. Some projections are made about areas in which hydrogen engines may find their initial application and about optimum ways to design such engines. It is shown that hydrogen-fueled reciprocal internal combustion engines offer important advantages with respect to thermal efficiency and exhaust emissions. Problems arising from preignition can suitably be avoided by restricting the fuel-air equivalence ratio to values below about 0.5. The direct cylinder injection appears to be a very attractive way to operate the engine, because it combines a wide range of possible power outputs with a high thermal efficiency and very low NO emissions at part loads.

  10. A polymer electrolyte fuel cell stack for stationary power generation from hydrogen fuel

    Energy Technology Data Exchange (ETDEWEB)

    Gottesfeld, S. [Los Alamos National Lab., NM (United States)

    1995-09-01

    The fuel cell is the most efficient device for the conversion of hydrogen fuel to electric power. As such, the fuel cell represents a key element in efforts to demonstrate and implement hydrogen fuel utilization for electric power generation. The low temperature, polymer electrolyte membrane fuel cell (PEMFC) has recently been identified as an attractive option for stationary power generation, based on the relatively simple and benign materials employed, the zero-emission character of the device, and the expected high power density, high reliability and low cost. However, a PEMFC stack fueled by hydrogen with the combined properties of low cost, high performance and high reliability has not yet been demonstrated. Demonstration of such a stack will remove a significant barrier to implementation of this advanced technology for electric power generation from hydrogen. Work done in the past at LANL on the development of components and materials, particularly on advanced membrane/electrode assemblies (MEAs), has contributed significantly to the capability to demonstrate in the foreseeable future a PEMFC stack with the combined characteristics described above. A joint effort between LANL and an industrial stack manufacturer will result in the demonstration of such a fuel cell stack for stationary power generation. The stack could operate on hydrogen fuel derived from either natural gas or from renewable sources. The technical plan includes collaboration with a stack manufacturer (CRADA). It stresses the special requirements from a PEMFC in stationary power generation, particularly maximization of the energy conversion efficiency, extension of useful life to the 10 hours time scale and tolerance to impurities from the reforming of natural gas.

  11. Safety evaluation of a hydrogen fueled transit bus

    Energy Technology Data Exchange (ETDEWEB)

    Coutts, D.A.; Thomas, J.K.; Hovis, G.L.; Wu, T.T. [Westinghouse Savannah River Co., Aiken, SC (United States)

    1997-12-31

    Hydrogen fueled vehicle demonstration projects must satisfy management and regulator safety expectations. This is often accomplished using hazard and safety analyses. Such an analysis has been completed to evaluate the safety of the H2Fuel bus to be operated in Augusta, Georgia. The evaluation methods and criteria used reflect the Department of Energy`s graded approach for qualifying and documenting nuclear and chemical facility safety. The work focused on the storage and distribution of hydrogen as the bus motor fuel with emphases on the technical and operational aspects of using metal hydride beds to store hydrogen. The safety evaluation demonstrated that the operation of the H2Fuel bus represents a moderate risk. This is the same risk level determined for operation of conventionally powered transit buses in the United States. By the same criteria, private passenger automobile travel in the United States is considered a high risk. The evaluation also identified several design and operational modifications that resulted in improved safety, operability, and reliability. The hazard assessment methodology used in this project has widespread applicability to other innovative operations and systems, and the techniques can serve as a template for other similar projects.

  12. A new approach to utilize Hydrogen as a safe fuel

    Energy Technology Data Exchange (ETDEWEB)

    Abdel-Aal, H.K.; Sadik, M.; Bassyouni, M. [Department of Chemical Engineering, Higher Technical Institute, Tenth of Ramadan, Cairo (Egypt); Shalabi, M. [Department of Chemical Engineering, KFUPM (Saudi Arabia)

    2005-11-01

    Fundamental to the creation of a hydrogen economy is a viable, safe and affordable hydrogen-energy-system. Examining carefully some of the key properties of hydrogen that are related to fire and explosion, it is found that hydrogen is combustible over a wide range of concentrations. At atmospheric pressure, it is combustible at concentrations from 4% to 74.2% by volume. It has the highest flame velocity of any gas and its ignition energy is very low, which is 32% less than methane gas. In this paper, the problem of 'safe hydrogen' is tackled using a new theoretical approach. Hydrogen is mixed with predetermined amounts of methane gas and to be sold as 'Hydrothane'. The properties of this mixture-most important are the flame speed, lower explosion limit (LEL) and upper explosion limit (UEL) are to be developed as a function of the ratio of the hydrogen-methane. The maximum flame speed, cm/s, for a selected number of hydrocarbons along with the corresponding volume percentage of combustible mixture (fuel in air) are used in the proposed analysis. In addition, Le Chatelier's law is used to predict limits of flammability of the Hydrothane. (author)

  13. The Australian Hydrogen and Fuel Cells Education Program

    Energy Technology Data Exchange (ETDEWEB)

    Luigi Bonadio [Senior Consultant Luigi Bonadio and Associates (Australia)

    2006-07-01

    The next generation of engineers and scientists will face great technical, economic and political challenges to satisfy increasing demands for a secure, reliable and affordable global energy system that maintains and enhances current standards of living. The Australian Hydrogen and Fuel Cells Education Program aims to bolster the quality and relevance of primary and secondary school teaching in emerging areas of science, technology and environmental/sustainability studies using hydrogen, in its capacity as a versatile energy carrier, as the educational basis for teacher and student learning. Critical advances in specific areas of hydrogen production, distribution, storage and end-use technologies arise when students are engaged to develop and apply a broad range of disciplinary and interdisciplinary knowledge and practical skills. A comprehensive hydrogen and fuel cell technology teaching module will be developed to complement existing fuels and energy curricula across Australian schools. The pilot program will be delivered via the collaboration of nine trial schools, a broad range of technical and pedagogy experts and representatives of professional bodies and industry. The program features essential and extensive teacher consultation, a professional learning and development course, industry site visits and a dedicated research and evaluation study. This initiative aims to bolster teacher literacy and student participation in the design, construction and operation of various hydrogen and fuel cell devices and extended activities. Students will reflect on and formally present their learning experiences via several dedicated fora including an awards ceremony where outstanding performance of leading schools, teachers and student groups within the cluster will be acknowledged. (authors)

  14. Realistic costs of wind-hydrogen vehicle fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Linnemann, J.; Steinberger-Wilckens, R. [PLANET - Planungsgruppe Energie und Technik GbR, P.O. Box 4003, D-26030 Oldenburg (Germany)

    2007-07-15

    Electricity grids with a high penetration of fluctuating energy production from wind and solar energy sources bear a risk of electricity over-production. A surplus of renewable energy can arise at times of high production when the energy volume cannot be absorbed by the electricity grid. Furthermore, the control of the stochastic power fluctuations has to be addressed since these will result in changes to grid stability. Producing hydrogen from excess electricity is one approach to solve these problems. This hydrogen can either be sold outside the electricity market, for instance as vehicle fuel, or re-converted into electricity, for instance as a means of controlling wind power output. This paper describes two different wind-hydrogen systems and analyses the ensuing costs of hydrogen per unit of energy service (i.e. kWh and Nm{sup 3}). If hydrogen is to represent a practical fuel alternative, it has to compete with conventional energy carriers. If this is not possible on strictly (micro-) economic terms, at least a macro-economic calculation, in this case including all external costs of energy services, needs to show competitiveness. (author)

  15. Hydrogen Separation Membranes for Vision 21 Fossil Fuel Plants

    Energy Technology Data Exchange (ETDEWEB)

    Roark, Shane E.; Mackay, Richard; Sammells, Anthony F.

    2001-11-06

    Eltron Research and team members CoorsTek, McDermott Technology, Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the Department of Energy (DOE) National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. By appropriately changing the catalysts coupled with the membrane, essentially the same system can be used to facilitate alkane dehydrogenation and coupling, aromatics processing, and hydrogen sulfide decomposition.

  16. Hydrogen

    Directory of Open Access Journals (Sweden)

    John O’M. Bockris

    2011-11-01

    Full Text Available The idea of a “Hydrogen Economy” is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO2 in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H2 from the electrolyzer. Methanol made with CO2 from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan. Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech.

  17. 2016 Annual Progress Report: DOE Hydrogen and Fuel Cells Program

    Energy Technology Data Exchange (ETDEWEB)

    Satyapal, Sunita [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2017-02-01

    In the past year, the DOE Hydrogen Program (the Program) made substantial progress toward its goals and objectives. The Program has conducted comprehensive and focused efforts to enable the widespread commercialization of hydrogen and fuel cell technologies in diverse sectors of the economy. With emphasis on applications that will effectively strengthen our nation's energy security and improve our stewardship of the environment, the Program engages in research, development, and demonstration of critical improvements in the technologies. Highlights of the Program's accomplishments can be found in the sub-program chapters of this report.

  18. 2015 Annual Progress Report: DOE Hydrogen and Fuel Cells Program

    Energy Technology Data Exchange (ETDEWEB)

    Popovich, Neil

    2015-12-01

    In the past year, the DOE Hydrogen Program (the Program) made substantial progress toward its goals and objectives. The Program has conducted comprehensive and focused efforts to enable the widespread commercialization of hydrogen and fuel cell technologies in diverse sectors of the economy. With emphasis on applications that will effectively strengthen our nation's energy security and improve our stewardship of the environment, the Program engages in research, development, and demonstration of critical improvements in the technologies. Highlights of the Program's accomplishments can be found in the sub-program chapters of this report.

  19. 2012 Annual Progress Report: DOE Hydrogen and Fuel Cells Program

    Energy Technology Data Exchange (ETDEWEB)

    2012-12-01

    In the past year, the DOE Hydrogen Program (the Program) made substantial progress toward its goals and objectives. The Program has conducted comprehensive and focused efforts to enable the widespread commercialization of hydrogen and fuel cell technologies in diverse sectors of the economy. With emphasis on applications that will effectively strengthen our nation's energy security and improve our stewardship of the environment, the Program engages in research, development, and demonstration of critical improvements in the technologies. Highlights of the Program's accomplishments can be found in the sub-program chapters of this report.

  20. Novel Hydrogen Purification Device Integrated with PEM Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Joseph Schwartz; Hankwon Lim; Raymond Drnevich

    2010-12-31

    A prototype device containing twelve membrane tubes was designed, built, and demonstrated. The device produced almost 300 scfh of purified hydrogen at 200 psig feed pressure. The extent of purification met the program target of selectively removing enough impurities to enable industrial-grade hydrogen to meet purity specifications for PEM fuel cells. An extrusion process was developed to produce substrate tubes. Membranes met several test objectives, including completing 20 thermal cycles, exceeding 250 hours of operating life, and demonstrating a flux of 965 scfh/ft2 at 200 psid and 400 C.

  1. Investigating fuel-cell transport limitations using hydrogen limiting current

    OpenAIRE

    Spingler, FB; Phillips, A; Schuler, T; Tucker, MC; Weber, AZ

    2017-01-01

    © 2017 Hydrogen Energy Publications LLC Reducing mass-transport losses in polymer-electrolyte fuel cells (PEFCs) is essential to increase their power density and reduce overall stack cost. At the same time, cost also motivates the reduction in expensive precious-metal catalysts, which results in higher local transport losses in the catalyst layers. In this paper, we use a hydrogen-pump limiting-current setup to explore the gas-phase transport losses through PEFC catalyst layers and various ga...

  2. Hydrogen Storage Experiments for an Undergraduate Laboratory Course--Clean Energy: Hydrogen/Fuel Cells

    Science.gov (United States)

    Bailey, Alla; Andrews, Lisa; Khot, Ameya; Rubin, Lea; Young, Jun; Allston, Thomas D.; Takacs, Gerald A.

    2015-01-01

    Global interest in both renewable energies and reduction in emission levels has placed increasing attention on hydrogen-based fuel cells that avoid harm to the environment by releasing only water as a byproduct. Therefore, there is a critical need for education and workforce development in clean energy technologies. A new undergraduate laboratory…

  3. Porous silicon-based direct hydrogen sulphide fuel cells.

    Science.gov (United States)

    Dzhafarov, T D; Yuksel, S Aydin

    2011-10-01

    In this paper, the use of Au/porous silicon/Silicon Schottky type structure, as a direct hydrogen sulphide fuel cell is demonstrated. The porous silicon filled with hydrochlorid acid was developed as a proton conduction membrane. The Au/Porous Silicon/Silicon cells were fabricated by first creating the porous silicon layer in single-crystalline Si using the anodic etching under illumination and then deposition Au catalyst layer onto the porous silicon. Using 80 mM H2S solution as fuel the open circuit voltage of 0.4 V was obtained and maximum power density of 30 W/m2 at room temperature was achieved. These results demonstrate that the Au/Porous Silicon/Silicon direct hydrogen sulphide fuel cell which uses H2S:dH2O solution as fuel and operates at room temperature can be considered as the most promising type of low cost fuel cell for small power-supply units.

  4. Theoretical performance of hydrogen-bromine rechargeable SPE fuel cell

    Science.gov (United States)

    Savinell, Robert F.; Fritts, S. D.

    1987-01-01

    A mathematical model was formulated to describe the performance of a hydrogen-bromine fuel cell. Porous electrode theory was applied to the carbon felt flow-by electrode and was coupled to theory describing the solid polymer electrolyte (SPE) system. Parametric studies using the numerical solution to this model were performed to determine the effect of kinetic, mass transfer, and design parameters on the performance of the fuel cell. The results indicate that the cell performance is most sensitive to the transport properties of the SPE membrane. The model was also shown to be a useful tool for scale-up studies.

  5. Hydrogen Storage Needs for Early Motive Fuel Cell Markets

    Energy Technology Data Exchange (ETDEWEB)

    Kurtz, J.; Ainscough, C.; Simpson, L.; Caton, M.

    2012-11-01

    The National Renewable Energy Laboratory's (NREL) objective for this project is to identify performance needs for onboard energy storage of early motive fuel cell markets by working with end users, manufacturers, and experts. The performance needs analysis is combined with a hydrogen storage technology gap analysis to provide the U.S. Department of Energy (DOE) Fuel Cell Technologies Program with information about the needs and gaps that can be used to focus research and development activities that are capable of supporting market growth.

  6. A Renewably Powered Hydrogen Generation and Fueling Station Community Project

    Science.gov (United States)

    Lyons, Valerie J.; Sekura, Linda S.; Prokopius, Paul; Theirl, Susan

    2009-01-01

    The proposed project goal is to encourage the use of renewable energy and clean fuel technologies for transportation and other applications while generating economic development. This can be done by creating an incubator for collaborators, and creating a manufacturing hub for the energy economy of the future by training both white- and blue-collar workers for the new energy economy. Hydrogen electrolyzer fueling stations could be mass-produced, shipped and installed in collaboration with renewable energy power stations, or installed connected to the grid with renewable power added later.

  7. Hydrogen powered fuel cell systems : different designs for variable specifications

    Energy Technology Data Exchange (ETDEWEB)

    Beckhaus, P.; Goessling, S.; Notthoff, T.; Souzani, S.; Schoemaker, M.; Heinzel, A. [ZBT GmbH, Duisburg (Germany). Fuel Cells and Systems

    2009-07-01

    This paper discussed system designs for hydrogen-powered fuel cell systems in the sub-kilowatt range. Designs were presented for the following 3 different types of applications: (1) supplying electrical power for high efficiency drives of 60 per cent, (2) supplying power for small uninterruptible power supply (UPS) devices with high power densities and minimum start-up times in a variety of environmental conditions, and (3) providing the supply of oxygen-reduced breathing air for the high altitude training of athletes. Different control strategies and approaches to system design were discussed. The results of experimental studies conducted to test the fuel cell stack systems were also provided.

  8. On Cherenkov light production by irradiated nuclear fuel rods

    Science.gov (United States)

    Branger, E.; Grape, S.; Jacobsson Svärd, S.; Jansson, P.; Andersson Sundén, E.

    2017-06-01

    Safeguards verification of irradiated nuclear fuel assemblies in wet storage is frequently done by measuring the Cherenkov light in the surrounding water produced due to radioactive decays of fission products in the fuel. This paper accounts for the physical processes behind the Cherenkov light production caused by a single fuel rod in wet storage, and simulations are presented that investigate to what extent various properties of the rod affect the Cherenkov light production. The results show that the fuel properties have a noticeable effect on the Cherenkov light production, and thus that the prediction models for Cherenkov light production which are used in the safeguards verifications could potentially be improved by considering these properties. It is concluded that the dominating source of the Cherenkov light is gamma-ray interactions with electrons in the surrounding water. Electrons created from beta decay may also exit the fuel and produce Cherenkov light, and e.g. Y-90 was identified as a possible contributor to significant levels of the measurable Cherenkov light in long-cooled fuel. The results also show that the cylindrical, elongated fuel rod geometry results in a non-isotropic Cherenkov light production, and the light component parallel to the rod's axis exhibits a dependence on gamma-ray energy that differs from the total intensity, which is of importance since the typical safeguards measurement situation observes the vertical light component. It is also concluded that the radial distributions of the radiation sources in a fuel rod will affect the Cherenkov light production.

  9. A polymer electrolyte fuel cell stack for stationary power generation from hydrogen fuel

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, M.S.; Moeller-Holst, S.; Webb, D.M.; Zawodzinski, C.; Gottesfeld, S. [Los Alamos National Lab., NM (United States). Materials Science and Technology Div.

    1998-08-01

    The objective is to develop and demonstrate a 4 kW, hydrogen-fueled polymer electrolyte fuel cell (PEFC) stack, based on non-machined stainless steel hardware and on membrane/electrode assemblies (MEAs) of low catalyst loadings. The stack is designed to operate at ambient pressure on the air-side and can accommodate operation at higher fuel pressures, if so required. This is to be accomplished by working jointly with a fuel cell stack manufacturer, based on a CRADA. The performance goals are 57% energy conversion efficiency hydrogen-to-electricity (DC) at a power density of 0.9 kW/liter for a stack operating at ambient inlet pressures. The cost goal is $600/kW, based on present materials costs.

  10. Spent nuclear fuel project detonation phenomena of hydrogen/oxygen in spent fuel containers

    Energy Technology Data Exchange (ETDEWEB)

    Cooper, T.D.

    1996-09-30

    Movement of Spent N Reactor fuels from the Hanford K Basins near the Columbia River to Dry interim storage facility on the Hanford plateau will require repackaging the fuel in the basins into multi-canister overpacks (MCOs), drying of the fuel, transporting the contained fuel, hot conditioning, and finally interim storage. Each of these functions will be accomplished while the fuel is contained in the MCOs by several mechanisms. The principal source of hydrogenand oxygen within the MCOs is residual water from the vacuum drying and hot conditioning operations. This document assesses the detonation phenomena of hydrogen and oxygen in the spent fuel containers. Several process scenarios have been identified that could generate detonation pressures that exceed the nominal 10 atmosphere design limit ofthe MCOS. Only 42 grams of radiolized water are required to establish this condition.

  11. Thermal Cracking of Jatropha Oil with Hydrogen to Produce Bio-Fuel Oil

    Directory of Open Access Journals (Sweden)

    Yi-Yu Wang

    2016-11-01

    Full Text Available This study used thermal cracking with hydrogen (HTC to produce bio-fuel oil (BFO from jatropha oil (JO and to improve its quality. We conducted HTC with different hydrogen pressures (PH2; 0–2.07 MPa or 0–300 psig, retention times (tr; 40–780 min, and set temperatures (TC; 623–683 K. By applying HTC, the oil molecules can be hydrogenated and broken down into smaller molecules. The acid value (AV, iodine value, kinematic viscosity (KV, density, and heating value (HV of the BFO produced were measured and compared with the prevailing standards for oil to assess its suitability as a substitute for fossil fuels or biofuels. The results indicate that an increase in PH2 tends to increase the AV and KV while decreasing the HV of the BFO. The BFO yield (YBFO increases with PH2 and tr. The above properties decrease with increasing TC. Upon HTC at 0.69 MPa (100 psig H2 pressure, 60 min time, and 683 K temperature, the YBFO was found to be 86 wt%. The resulting BFO possesses simulated distillation characteristics superior to those of boat oil and heavy oil while being similar to those of diesel oil. The BFO contains 15.48% light naphtha, 35.73% heavy naphtha, 21.79% light gas oil, and 27% heavy gas oil and vacuum residue. These constituents can be further refined to produce gasoline, diesel, lubricants, and other fuel products.

  12. European hydrogen and fuel cell technology platform. Strategic overview

    Energy Technology Data Exchange (ETDEWEB)

    Alleau, Th

    2005-07-01

    In January 2004, following the recommendation of the High Level Group, the European Commission set up the European Hydrogen and Fuel Cell Technology Platform (HFP) a partnership of over 300 stakeholders. Its brief? To prepare and direct an effective strategy for bringing hydrogen and fuel cells to market in order to exploit their outstanding environmental and economic potential. An Advisory Council of 35 representatives from a broad range of industry, EC, public authority, academic and NGO stakeholders was set up to guide the activity, together with a number of subsidiary bodies. Two steering panels were then charged with defining a Strategic Research Agenda (SRA) and Deployment Strategy (DS) respectively in order to drive the transition forward. This report gives a work in progress strategic overview, with further details provided in the Executive Summaries of the Strategic Research Agenda and Deployment Strategy foundation documents. (authors)

  13. Hydrogen-Oxygen PEM Regenerative Fuel Cell Energy Storage System

    Science.gov (United States)

    Bents, David J.; Scullin, Vincent J.; Chang, Bei-Jiann; Johnson, Donald W.; Garcia, Christopher P.

    2005-01-01

    An introduction to the closed cycle hydrogen-oxygen polymer electrolyte membrane (PEM) regenerative fuel cell (RFC), recently constructed at NASA Glenn Research Center, is presented. Illustrated with explanatory graphics and figures, this report outlines the engineering motivations for the RFC as a solar energy storage device, the system requirements, layout and hardware detail of the RFC unit at NASA Glenn, the construction history, and test experience accumulated to date with this unit.

  14. Hydrogen as energy-storage-medium and fuel

    OpenAIRE

    Töpler Johannes

    2016-01-01

    This contribution addresses the future energy situation with the expected reduction of fossil primary energy supply and increasing market segments by renewable energies within the next decades. The potential of renewable energies to cover the energy demand is described as well as the necessity of energy storage systems (especially hydrogen) to compensate the fluctuations of primary energy sources. Furthermore the increasing use of renewable vehicle fuels is investigated with special focus on ...

  15. Light-Promoted Hydrogenation of Carbon Dioxide¿An Overview

    OpenAIRE

    Puga Vaca, Alberto

    2016-01-01

    [EN] Hydrogenation of carbon dioxide is considered as a viable strategy to generate fuels while closing the carbon cycle (heavily disrupted by the abuse in the exploitation of fossil resources) and reducing greenhouse gas emissions. The process can be performed by heat-powered catalytic processes, albeit conversion and selectivity tend to be reduced at increasing temperatures owing to thermodynamic constraints. Recent investigations, as summarised in this overview, have proven that light acti...

  16. Global Assessment of Hydrogen Technologies - Task 1 Report Technology Evaluation of Hydrogen Light Duty Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan Andrew J.; Rousseau, Aymeric

    2007-12-01

    This task analyzes the candidate hydrogen-fueled vehicles for near-term use in the Southeastern U.S. The purpose of this work is to assess their potential in terms of efficiency and performance. This report compares conventional, hybrid electric vehicles (HEV) with gasoline and hydrogen-fueled internal combustion engines (ICEs) as well as fuel cell and fuel cell hybrids from a technology as well as fuel economy point of view. All the vehicles have been simulated using the Powertrain System Analysis Toolkit (PSAT). First, some background information is provided on recent American automotive market trends and consequences. Moreover, available options are presented for introducing cleaner and more economical vehicles in the market in the future. In this study, analysis of various candidate hydrogen-fueled vehicles is performed using PSAT and, thus, a brief description of PSAT features and capabilities are provided. Detailed information on the simulation analysis performed is also offered, including methodology assumptions, fuel economic results, and conclusions from the findings.

  17. Production of JET fuel containing molecules of high hydrogen content

    Directory of Open Access Journals (Sweden)

    Tomasek Sz.

    2017-12-01

    Full Text Available The harmful effects of aviation can only be reduced by using alternative fuels with excellent burning properties and a high hydrogen content in the constituent molecules. Due to increasing plastic consumption the amount of the plastic waste is also higher. Despite the fact that landfill plastic waste has been steadily reduced, the present scenario is not satisfactory. Therefore, the aim of this study is to produce JET fuel containing an alternative component made from straight-run kerosene and the waste polyethylene cracking fraction. We carried out our experiments on a commercial NiMo/Al2O3/P catalyst at the following process parameters: T=200-300°C, P=40 bar, LHSV=1.0-3.0 h-1, hydrogen/hydrocarbon ratio= 400 Nm3/m3. We investigated the effects of the feedstocks and the process parameters on the product yields, the hydrodesulfurization and hydrodearomatization efficiencies, and the main product properties. The liquid product yields varied between 99.7-99.8%. As a result of the hydrogenation the sulfur (1-1780 mg/kg and the aromatic contents (9.0-20.5% of the obtained products and the values of their smoke points (26.0-34.7 mm fulfilled the requirements of JET fuel standard. Additionally, the concentration of paraffins increased in the products and the burning properties were also improved. The freezing points of the products were higher than -47°C, therefore product blending is needed.

  18. Hydrogen generation at ambient conditions: application in fuel cells.

    Science.gov (United States)

    Boddien, Albert; Loges, Björn; Junge, Henrik; Beller, Matthias

    2008-01-01

    The efficient generation of hydrogen from formic acid/amine adducts at ambient temperature is demonstrated. The highest catalytic activity (TOF up to 3630 h(-1) after 20 min) was observed in the presence of in situ generated ruthenium phosphine catalysts. Compared to the previously known methods to generate hydrogen from liquid feedstocks, the systems presented here can be operated at room temperature without the need for any high-temperature reforming processes, and the hydrogen produced can then be directly used in fuel cells. A variety of Ru precursors and phosphine ligands were investigated for the decomposition of formic acid/amine adducts. These catalytic systems are particularly interesting for the generation of H2 for new applications in portable electric devices.

  19. Compact fuel cell system utilizing a combination of hydrogen storage materials for optimized performance.

    Energy Technology Data Exchange (ETDEWEB)

    Chan, Jennifer P.; Dedrick, Daniel E.; Gross, Karl J.; Ng, Greg L.

    2004-12-01

    An entirely new class of light-weight reversible hydrides was recently discovered (the Ti-doped alanates)[1]. These NaAIH{sub 4}-based materials have demonstrated reversible hydrogen storage capacities of up to 5 wt%, nearly 4 times the gravimetrically density of commercial metal hydrides. For this reason, they have been considered a breakthrough for hydrogen storage in fuel cell vehicles. This project is the first to publish the use of alanates for the generation of electrical power and the first demonstration of a hydride-fueled elevated-temperature PEM Fuel Cell. Because the kinetics of hydrogen uptake and release by the alanate improves with elevated temperatures, novel concepts were tested for the purpose of developing a highly efficient stand-alone power system. A major focus of this work was on the modeling, design, construction and testing of an integrated fuel cell stack and hydrogen storage system that eliminates the need of complicated heat transfer systems and media. After extensive modeling efforts, a proof-of-concept system was built that employs an integrated fuel cell stack and hydride beds that balancing the generation of fuel cell waste heat with the endothermic release of hydrogen from the alanates. Our demonstration unit was capable of greater than one hour of operation on a single charge of hydrogen from the integrated 173 gram alanate bed. In addition, composite hydride materials with synergistic reaction heats were evaluated and tested to enhance the operational performance of the alanates. The composites provide a unique opportunity to utilize the heat produced from hydriding classic metal hydrides to improve both absorption and desorption rates of the alanates. A particular focus of the mixed storage materials work was to balance the thermodynamics and kinetics of the hydrides for start-up conditions. Modeling of the sorption properties proved invaluable in evaluating the optimum composition of hydrides. The modeling efforts were followed

  20. Effect of ramp-cavity on hydrogen fueled scramjet combustor

    Directory of Open Access Journals (Sweden)

    J.V.S. Moorthy

    2014-03-01

    Full Text Available Sustained combustion and optimization of combustor are the two challenges being faced by combustion scientists working in the area of supersonic combustion. Thorough mixing, lower stagnation pressure losses, positive thrust and sustained combustion are the key issues in the field of supersonic combustion. Special fluid mechanism is required to achieve good mixing. To induce such mechanisms in supersonic inflows, the fuel injectors should be critically shaped incurring less flow losses. Present investigations are focused on the effect of fuel injection scheme on a model scramjet combustor performance. Ramps at supersonic flow generate axial vortices that help in macro-mixing of fuel with air. Interaction of shocks generated by ramps with the fuel stream generates boro-clinic torque at the air & liquid fuel interface, enhancing micro-mixing. Recirculation zones present in cavities increase the residence time of the combustible mixture. Making use of the advantageous features of both, a ramp-cavity combustor is designed. The combustor has two sections. First, constant height section consists of a backward facing step followed by ramps and cavities on both the top and bottom walls. The ramps are located alternately on top and bottom walls. The complete combustor width is utilized for the cavities. The second section of the combustor is diverging area section. This is provided to avoid thermal choking. In the present work gaseous hydrogen is considered as fuel. This study was mainly focused on the mixing characteristics of four different fuel injection locations. It was found that injecting fuel upstream of the ramp was beneficial from fuel spread point of view.

  1. Slurry-Based Chemical Hydrogen Storage Systems for Automotive Fuel Cell Applications

    Energy Technology Data Exchange (ETDEWEB)

    Brooks, Kriston P.; Semelsberger, Troy; Simmons, Kevin L.; Van Hassel, Bart A.

    2014-05-30

    In this paper, the system designs for hydrogen storage using chemical hydrogen materials in an 80 kWe fuel cell, light-duty vehicle are described. Ammonia borane and alane are used for these designs to represent the general classes of exothermic and endothermic materials. The designs are then compared to the USDRIVE/DOE developed set of system level targets for on-board storage. While most of the DOE targets are predicted to be achieved based on the modeling, the system gravimetric and volumetric densities were more challenging and became the focus of this work. The resulting system evaluation determined that the slurry is majority of the system mass. Only modest reductions in the system mass can be expected with improvements in the balance of plant components. Most of the gravimetric improvements will require developing materials with higher inherent storage capacity or by increasing the solids loading of the chemical hydrogen storage material in the slurry.

  2. Turbulent Flame Propagation Characteristics of High Hydrogen Content Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Seitzman, Jerry [Georgia Inst. of Technology, Atlanta, GA (United States); Lieuwen, Timothy [Georgia Inst. of Technology, Atlanta, GA (United States)

    2014-09-30

    This final report describes the results of an effort to better understand turbulent flame propagation, especially at conditions relevant to gas turbines employing fuels with syngas or hydrogen mixtures. Turbulent flame speeds were measured for a variety of hydrogen/carbon monoxide (H2/CO) and hydrogen/methane (H2/CH4) fuel mixtures with air as the oxidizer. The measurements include global consumption speeds (ST,GC) acquired in a turbulent jet flame at pressures of 1-10 atm and local displacement speeds (ST,LD) acquired in a low-swirl burner at atmospheric pressure. The results verify the importance of fuel composition in determining turbulent flame speeds. For example, different fuel-air mixtures having the same unstretched laminar flame speed (SL,0) but different fuel compositions resulted in significantly different ST,GC for the same turbulence levels (u'). This demonstrates the weakness of turbulent flame speed correlations based simply on u'/SL,0. The results were analyzed using a steady-steady leading points concept to explain the sensitivity of turbulent burning rates to fuel (and oxidizer) composition. Leading point theories suggest that the premixed turbulent flame speed is controlled by the flame front characteristics at the flame brush leading edge, or, in other words, by the flamelets that advance farthest into the unburned mixture (the so-called leading points). For negative Markstein length mixtures, this is assumed to be close to the maximum stretched laminar flame speed (SL,max) for the given fuel-oxidizer mixture. For the ST,GC measurements, the data at a given pressure were well-correlated with an SL,max scaling. However the variation with pressure was not captured, which may be due to non-quasi-steady effects that are not included in the current model. For the ST,LD data, the leading points model again faithfully captured the variation of turbulent flame speed over a wide range of fuel-compositions and turbulence intensities. These

  3. Uniform hydrogen fuel layers for inertial fusion targets by microgravity

    Science.gov (United States)

    Parks, P. B.; Fagaly, Robert L.

    1994-01-01

    A critical concern in the fabrication of targets for inertial confinement fusion (ICF) is ensuring that the hydrogenic (D(sub 2) or DT) fuel layer maintains spherical symmetry. Solid layered targets have structural integrity, but lack the needed surface smoothness. Liquid targets are inherently smooth, but suffer from gravitationally induced sagging. One method to reduce the effective gravitational field environment is freefall insertion into the target chamber. Another method to counterbalance field gravitational force is to use an applied magnetic field combined with a gradient field to induce a magnetic dipole force on the liquid fuel layer. Based on time dependent calculations of the dynamics of the liquid fuel layer in microgravity environments, we show that it may be possible to produce a liquid layered ICF target that satisfies both smoothness and symmetry requirements.

  4. Design of a reconfigurable liquid hydrogen fuel tank for use in the Genii unmanned aerial vehicle

    Science.gov (United States)

    Adam, Patrick; Leachman, Jacob

    2014-01-01

    Long endurance flight, on the order of days, is a leading flight performance characteristic for Unmanned Aerial Vehicles (UAVs). Liquid hydrogen (LH2) is well suited to providing multi-day flight times with a specific energy 2.8 times that of conventional kerosene based fuels. However, no such system of LH2 storage, delivery, and use is currently available for commercial UAVs. In this paper, we develop a light weight LH2 dewar for integration and testing in the proton exchange membrane (PEM) fuel cell powered, student designed and constructed, Genii UAV. The fuel tank design is general for scaling to suit various UAV platforms. A cylindrical vacuum-jacketed design with removable end caps was chosen to incorporate various fuel level gauging, pressurizing, and slosh mitigation systems. Heat and mechanical loadings were modeled to compare with experimental results. Mass performance of the fuel tank is characterized by the fraction of liquid hydrogen to full tank mass, and the insulation performance was characterized by effective thermal conductivity and boil-off rate.

  5. Renewable hydrogen production for fossil fuel processing

    Energy Technology Data Exchange (ETDEWEB)

    Greenbaum, E.; Lee, J.W.; Tevault, C.V.; Blankinship, S.L.

    1996-06-01

    In the current and prevailing concept of photosynthesis, the Z-scheme, first proposed by Hill and Bendall, PSII can split water, but is not thought to be able to perform one of PSI`s assigned functions-the reduction of ferredoxin/NADP{sup +} essential for CO{sub 2} assimilation. The Z-scheme therefore requires both PSII and PSI working in sequence for complete photosynthesis using water as the source of electrons and CO{sub 2} as the terminal electron acceptor. Despite disagreement from several investigators, the Z-scheme has become the textbook model of photosynthesis. Recently, we have demonstrated that sustained photoassimilation of CO{sub 2} and evolution of H{sub 2} and O{sub 2} in minimal medium can be achieved by the PSII light reaction without involvement of PSI in a PSI-deficient mutant of Chlamydomonas grown photoheterotrophically using an organic nutrient (acetate). In this paper, we report a more exciting discovery that PSI-deficient mutants of Chlamydomonas were capable of growing photoautotrophically with CO{sub 2} as the sole source of carbon. Since the Z-scheme requires both PSI and PSII working together in series for complete photosynthesis, it predicts that PSI-deficient mutants of green algae will not grow photoautotrophically. The discovery of photoautotrophic growth of PSI-deficient green algae without any organic nutrients, therefore, provides clear and solid evidence for the existence of a new type of photosynthesis-{open_quotes}PSII photosynthesis{close_quotes} that is an alternative to the Z-scheme. Our discovery may also provide an explanation for many {open_quotes}anomalous{close_quotes} quantum requirements that have been reported over the last 50 years, but failed to be explained by the Z-scheme.

  6. Hydrogen Monitoring Requirements in the Global Technical Regulation on Hydrogen and Fuel Cell Vehicles: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Buttner, William; Rivkin, Carl; Burgess, Robert; Hartmann, Kevin; Bubar, Max; Post, Matthew; Boon-Brett, Lois; Weidner, Eveline; Moretto, Pietro

    2016-07-01

    The United Nations Global Technical Regulation (GTR) Number 13 (Global Technical Regulation on Hydrogen and Fuel Cell Vehicles) is the defining document regulating safety requirements in hydrogen vehicles, and in particular fuel cell electric vehicles (FCEV). GTR Number 13 has been formally implemented and will serve as the basis for the national regulatory standards for FCEV safety in North America (Canada, United States), Japan, Korea, and the European Union. The GTR defines safety requirement for these vehicles, including specifications on the allowable hydrogen levels in vehicle enclosures during in-use and post-crash conditions and on the allowable hydrogen emissions levels in vehicle exhaust during certain modes of normal operation. However, in order to be incorporated into national regulations, that is, in order to be binding, methods to verify compliance to the specific requirements must exist. In a collaborative program, the Sensor Laboratories at the National Renewable Energy Laboratory in the United States and the Joint Research Centre, Institute for Energy and Transport in the Netherlands have been evaluating and developing analytical methods that can be used to verify compliance to the hydrogen release requirement as specified in the GTR.

  7. Direct-hydrogen-fueled proton-exchange-membrane fuel cell system for transportation applications

    Energy Technology Data Exchange (ETDEWEB)

    Oei, D.; Adams, J.A.; Kinnelly, A.A. [and others

    1997-07-01

    In partial fulfillment of the U.S. Department of Energy Contract No. DE-ACO2-94CE50389, {open_quotes}Direct Hydrogen-Fueled Proton-Exchange-Membrane (PEM) Fuel Cell System for Transportation Applications{close_quotes}, this conceptual vehicle design report addresses the design and packaging of battery augmented fuel cell powertrain vehicles. This report supplements the {open_quotes}Conceptual Vehicle Design Report - Pure Fuel Cell Powertrain Vehicle{close_quotes} and includes a cost study of the fuel cell power system. The three classes of vehicles considered in this design and packaging exercise are the same vehicle classes that were studied in the previous report: the Aspire, representing the small vehicle class; the AIV (Aluminum Intensive Vehicle) Sable, representing the mid-size vehicle; and the E-150 Econoline, representing the van-size class. A preliminary PEM fuel cell power system manufacturing cost study is also presented. As in the case of the previous report concerning the {open_quotes}Pure Fuel Cell Powertrain Vehicle{close_quotes}, the same assumptions are made for the fuel cell power system. These assumptions are fuel cell system power densities of 0.33 kW/ka and 0.33 kW/l, platinum catalyst loading of less than or equal to 0.25 mg/cm{sup 2} total, and hydrogen tanks containing compressed gaseous hydrogen under 340 atm (5000 psia) pressure. The batteries considered for power augmentation of the fuel cell vehicle are based on the Ford Hybrid Electric Vehicle (HEV) program. These are state-of-the-art high power lead acid batteries with power densities ranging from 0.8 kW/kg to 2 kW/kg. The results reported here show that battery augmentation provides the fuel cell vehicle with a power source to meet instant high power demand for acceleration and start-up. Based on the assumptions made in this report, the packaging of the battery augmented fuel cell vehicle appears to be as feasible as the packaging of the pure fuel cell powered vehicle.

  8. 2011 DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Report

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2011-09-01

    This report summarizes comments from the Peer Review Panel at the 2011 DOE Hydrogen and Fuel Cells Program Annual Merit Review, held on May 9-13, 2011, in Arlington, Virginia. It covers the program areas of hydrogen production and delivery; hydrogen storage; fuel cells; manufacturing R&D; technology validation; safety, codes, and standards; education; market transformation; and systems analysis.

  9. 2013 DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Report

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2013-10-01

    This report summarizes comments from the Peer Review Panel at the 2013 DOE Hydrogen and Fuel Cells Program Annual Merit Review, held on May 13-17, 2013, in Arlington, Virginia. It covers the program areas of hydrogen production and delivery; hydrogen storage; fuel cells; manufacturing R&D; technology validation; safety, codes, and standards; market transformation; and systems analysis.

  10. 2014 DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Report

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2014-10-01

    This report summarizes comments from the Peer Review Panel at the 2014 DOE Hydrogen and Fuel Cells Program Annual Merit Review, held on June 16-20, 2014, in Washington, DC. It covers the program areas of hydrogen production and delivery; hydrogen storage; fuel cells; manufacturing R&D; technology validation; safety, codes, and standards; market transformation; and systems analysis.

  11. 2015 DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Report

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2015-10-01

    This report summarizes comments from the Peer Review Panel at the 2015 DOE Hydrogen and Fuel Cells Program Annual Merit Review, held on June 8-12, 2015, in Arlington, Virginia. It covers the program areas of hydrogen production and delivery; hydrogen storage; fuel cells; manufacturing R&D; technology validation; safety, codes, and standards; market transformation; and systems analysis.

  12. 75 FR 59705 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC)

    Science.gov (United States)

    2010-09-28

    ... Hydrogen and Fuel Cell Technical Advisory Committee (HTAC) AGENCY: Department of Energy, Office of Energy Efficiency and Renewable Energy. ACTION: Notice of open meeting. SUMMARY: The Hydrogen and Fuel Cell... will be posted on the web at http://hydrogen.energy.gov and copies of the final agenda will be...

  13. 75 FR 2860 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC)

    Science.gov (United States)

    2010-01-19

    ... of Energy Efficiency and Renewable Energy Hydrogen and Fuel Cell Technical Advisory Committee (HTAC... Meeting. SUMMARY: The Hydrogen and Fuel Cell Technical Advisory Committee (HTAC) was established under... posted on http://hydrogen.energy.gov and copies of the final agenda will available the date of the...

  14. 76 FR 60478 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC)

    Science.gov (United States)

    2011-09-29

    ... Hydrogen and Fuel Cell Technical Advisory Committee (HTAC) AGENCY: Department of Energy, Office of Energy Efficiency and Renewable Energy. ACTION: Notice of open meeting. SUMMARY: The Hydrogen and Fuel Cell... Agenda: (Subject to change; updates will be posted on the website at: http://hydrogen.energy.gov and...

  15. 77 FR 2714 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC)

    Science.gov (United States)

    2012-01-19

    ... Hydrogen and Fuel Cell Technical Advisory Committee (HTAC) AGENCY: Department of Energy, Office of Energy... open meeting of the Hydrogen and Fuel Cell Technical Advisory Committee (HTAC). The HTAC was... EPACT. Tentative Agenda: (Subject to change; updates will be posted on http://hydrogen.energy.gov...

  16. 76 FR 4645 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC)

    Science.gov (United States)

    2011-01-26

    ... Hydrogen and Fuel Cell Technical Advisory Committee (HTAC) AGENCY: Department of Energy, Office of Energy... the Hydrogen and Fuel Cell Technical Advisory Committee (HTAC). HTAC was established under section 807... posted on http://hydrogen.energy.gov and copies of the final agenda will available the date of the...

  17. 76 FR 28759 - Hydrogen and Fuel Cell Technical Advisory Committee (HTAC)

    Science.gov (United States)

    2011-05-18

    ... of Energy Efficiency and Renewable Energy Hydrogen and Fuel Cell Technical Advisory Committee (HTAC... meeting. SUMMARY: The Hydrogen and Fuel Cell Technical Advisory Committee (HTAC) was established under... address: [email protected] or check the Web site at: hydrogen.energy.gov . SUPPLEMENTARY INFORMATION: Purpose...

  18. 2012 DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Report

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2012-09-01

    This report summarizes comments from the Peer Review Panel at the 2012 DOE Hydrogen and Fuel Cells Program Annual Merit Review, held on May 14-18, 2012, in Arlington, Virginia. It covers the program areas of hydrogen production and delivery; hydrogen storage; fuel cells; manufacturing R&D; technology validation; safety, codes, and standards; education; market transformation; and systems analysis.

  19. Investigation and Mitigation of Degradation in Hydrogen Fuel Cells

    Science.gov (United States)

    Mandal, Pratiti

    The ever increasing demand of petroleum in the transport sector has led to depletion of low cost/low risk reserves, increased level of pollution, and greenhouse gas emissions that take a heavy toll on the environment as well as the national economy. There is an urgent need to utilize alternative energy resources along with an efficient and affordable energy conversion system to arrest environmental degradation. Polymer electrolyte fuel cells (PEFCs) show great promise in this regard, they use hydrogen gas as a fuel that electrochemically reacts with air to produce electrical energy and water as the by product. In a fuel cell electric vehicle (FCEV), these zero tail pipe emission systems offer high efficiency and power density for medium-heavy duty and long range transportation. However, PEFC technology is currently challenged by its limited durability when subjected to harsh and adverse operating conditions and transients that arises during the normal course of vehicle operation. The hydrogen-based fuel cell power train for electric vehicles must achieve high durability while maintaining high power efficiency and fuel economy in order to equal the range and lifetime of an internal-combustion engine vehicle. The technology also needs to meet the cost targets to make FCEVs a commercial success. In this dissertation, one of the degradation phenomena that severely impede the durability of the system has been investigated. In scenarios where the cell becomes locally starved of hydrogen fuel, "cell reversal" occurs, which causes the cell to consume itself through carbon corrosion and eventually fail. Carbon corrosion in the anode disrupts the original structure of the electrode and can cause undesirable outcomes like catalyst particle migration, aggregation, loss of structural and chemical integrity. Through a comprehensive study using advanced electrochemical diagnostics and high resolution 3D imaging, a new understanding to extend PEFC life time and robustness by

  20. Storage and production of hydrogen for fuel cell applications

    Science.gov (United States)

    Aiello, Rita

    The increased utilization of proton-exchange membrane (PEM) fuel cells as an alternative to internal combustion engines is expected to increase the demand for hydrogen, which is used as the energy source in these systems. The objective of this work is to develop and test new methods for the storage and production of hydrogen for fuel cells. Six ligand-stabilized hydrides were synthesized and tested as hydrogen storage media for use in portable fuel cells. These novel compounds are more stable than classical hydrides (e.g., NaBH4, LiAlH4) and react to release hydrogen less exothermically upon hydrolysis with water. Three of the compounds produced hydrogen in high yield (88 to 100 percent of the theoretical) and at significantly lower temperatures than those required for the hydrolysis of NaBH4 and LiAlH4. However, a large excess of water and acid were required to completely wet the hydride and keep the pH of the reaction medium neutral. The hydrolysis of the classical hydrides with steam can overcome these limitations. This reaction was studied in a flow reactor and the results indicate that classical hydrides can be hydrolyzed with steam in high yields at low temperatures (110 to 123°C) and in the absence of acid. Although excess steam was required, the pH of the condensed steam was neutral. Consequently, steam could be recycled back to the reactor. Production of hydrogen for large-scale transportation fuel cells is primarily achieved via the steam reforming, partial oxidation or autothermal reforming of natural gas or the steam reforming of methanol. However, in all of these processes CO is a by-product that must be subsequently removed because the Pt-based electrocatalyst used in the fuel cells is poisoned by its presence. The direct cracking of methane over a Ni/SiO2 catalyst can produce CO-free hydrogen. In addition to hydrogen, filamentous carbon is also produced. This material accumulates on the catalyst and eventually deactivates it. The Ni/SiO2 catalyst

  1. Hydrogen peroxide as sustainable fuel: electrocatalysts for production with a solar cell and decomposition with a fuel cell.

    Science.gov (United States)

    Yamada, Yusuke; Fukunishi, Yurie; Yamazaki, Shin-ichi; Fukuzumi, Shunichi

    2010-10-21

    Hydrogen peroxide was electrochemically produced by reducing oxygen in an aqueous solution with [Co(TCPP)] as a catalyst and photovoltaic solar cell operating at 0.5 V. Hydrogen peroxide thus produced is utilized as a fuel for a one-compartment fuel cell with Ag-Pb alloy nanoparticles as the cathode.

  2. Hydrogen in Vans and Light Duty Trucks in Denmark

    DEFF Research Database (Denmark)

    Jørgensen, Kaj

    1996-01-01

    The potential for application of hydrogen in light goods vehicles(i.e. freight vehicles with a gross vehicle weight of less than 6 tonnes) for local goods distribution, and the resulting energy and environmental consequences are evaluated. Local distribution of goods by road transport...... is characterised by very poor energy efficiency and by considerable negative environmental impacts compared to the transport demand covered. Based on an investigation of the Danish stock of LGVs and its application for local freight transportation the article outlines and assesses different designs for hydrogen...... operation, all based on hydrogen generated by electrolysis. For each combination of design and weight category, hydrogen consumption and emissions are calculated for typical driving patterns, and the potential for emission reduction is assessed. In addition, the longer-term application of hydrogen as energy...

  3. Negotiating sustainable innovation? Hydrogen and fuel cell technologies in Germany

    Directory of Open Access Journals (Sweden)

    Weert Canzler

    2013-06-01

    Full Text Available Recently, the German Federal Government made the consequential decision to change its energy program. This not only as a result of the decision to shut down the existing nuclear power plants within the next few years, but also due to vital challenges like climate change and security of energy supply. The shift in the energy-technology paradigm from fossil fuel technologies to regenerative energies might appear as a merely technical process at first glance. Yet, the road to environmental sustainability is paved with economic and social stumbling blocks. The concept of sustainable development is not a blueprint for technical progress but requires deliberations on questions about innovations and governance: How do we want to live and how do we want to get there? This paper traces the negotiations of sustainable innovation on the example of hydrogen and fuel cell technologies in Germany. The institutional set up in this field is analyzed and the new organizational actors are identified. These actors attempt to inform and persuade others of the benefits of hydrogen and fuel cells in order to establish a common view that is to guide the further development. However, while they succeeded in mobilizing enough actors to launch the largest Public Private Partnership in this sector in the EU, they could not attain the leadership in the public discourse on these technologies. It seems that an attractive guiding vision of a sustainable, post-fossil energy future and a broad acceptance in daily use would have been major prerequisites for such leadership.

  4. Thermally regenerative hydrogen/oxygen fuel cell power cycles

    Science.gov (United States)

    Morehouse, J. H.

    1986-01-01

    Two innovative thermodynamic power cycles are analytically examined for future engineering feasibility. The power cycles use a hydrogen-oxygen fuel cell for electrical energy production and use the thermal dissociation of water for regeneration of the hydrogen and oxygen. The TDS (thermal dissociation system) uses a thermal energy input at over 2000 K to thermally dissociate the water. The other cycle, the HTE (high temperature electrolyzer) system, dissociates the water using an electrolyzer operating at high temperature (1300 K) which receives its electrical energy from the fuel cell. The primary advantages of these cycles is that they are basically a no moving parts system, thus having the potential for long life and high reliability, and they have the potential for high thermal efficiency. Both cycles are shown to be classical heat engines with ideal efficiency close to Carnot cycle efficiency. The feasibility of constructing actual cycles is investigated by examining process irreversibilities and device efficiencies for the two types of cycles. The results show that while the processes and devices of the 2000 K TDS exceed current technology limits, the high temperature electrolyzer system appears to be a state-of-the-art technology development. The requirements for very high electrolyzer and fuel cell efficiencies are seen as determining the feasbility of the HTE system, and these high efficiency devices are currently being developed. It is concluded that a proof-of-concept HTE system experiment can and should be conducted.

  5. NEW MATERIAL NEEDS FOR HYDROCARBON FUEL PROCESSING: Generating Hydrogen for the PEM Fuel Cell

    Science.gov (United States)

    Farrauto, R.; Hwang, S.; Shore, L.; Ruettinger, W.; Lampert, J.; Giroux, T.; Liu, Y.; Ilinich, O.

    2003-08-01

    The hydrogen economy is fast approaching as petroleum reserves are rapidly consumed. The fuel cell promises to deliver clean and efficient power by combining hydrogen and oxygen in a simple electrochemical device that directly converts chemical energy to electrical energy. Hydrogen, the most plentiful element available, can be extracted from water by electrolysis. One can imagine capturing energy from the sun and wind and/or from the depths of the earth to provide the necessary power for electrolysis. Alternative energy sources such as these are the promise for the future, but for now they are not feasible for power needs across the globe. A transitional solution is required to convert certain hydrocarbon fuels to hydrogen. These fuels must be available through existing infrastructures such as the natural gas pipeline. The present review discusses the catalyst and adsorbent technologies under development for the extraction of hydrogen from natural gas to meet the requirements for the proton exchange membrane (PEM) fuel cell. The primary market is for residential applications, where pipeline natural gas will be the source of H2 used to power the home. Other applications including the reforming of methanol for portable power applications such as laptop computers, cellular phones, and personnel digital equipment are also discussed. Processing natural gas containing sulfur requires many materials, for example, adsorbents for desulfurization, and heterogeneous catalysts for reforming (either autothermal or steam reforming) water gas shift, preferential oxidation of CO, and anode tail gas combustion. All these technologies are discussed for natural gas and to a limited extent for reforming methanol.

  6. Electronic Safety Resource Tools -- Supporting Hydrogen and Fuel Cell Commercialization

    Energy Technology Data Exchange (ETDEWEB)

    Barilo, Nick F.

    2014-09-29

    The Pacific Northwest National Laboratory (PNNL) Hydrogen Safety Program conducted a planning session in Los Angeles, CA on April 1, 2014 to consider what electronic safety tools would benefit the next phase of hydrogen and fuel cell commercialization. A diverse, 20-person team led by an experienced facilitator considered the question as it applied to the eight most relevant user groups. The results and subsequent evaluation activities revealed several possible resource tools that could greatly benefit users. The tool identified as having the greatest potential for impact is a hydrogen safety portal, which can be the central location for integrating and disseminating safety information (including most of the tools identified in this report). Such a tool can provide credible and reliable information from a trustworthy source. Other impactful tools identified include a codes and standards wizard to guide users through a series of questions relating to application and specific features of the requirements; a scenario-based virtual reality training for first responders; peer networking tools to bring users from focused groups together to discuss and collaborate on hydrogen safety issues; and a focused tool for training inspectors. Table ES.1 provides results of the planning session, including proposed new tools and changes to existing tools.

  7. Hydrogen fuel cells in chemical industry: The assemini project

    Energy Technology Data Exchange (ETDEWEB)

    Caserza, G.; Bozzoni, T.; Porcino, G.; Pasquinucci, A. [Ansaldo CLC s.r.l., Genova (Italy)] [and others

    1996-12-31

    Chemical and petrochemical industries generate large quantities of hydrogen-rich streams, in the range 50%-100% H{sub 2} concentration by volume, as by-products of electrochemical or dehydrogenation processes, or exhausts/purging in hydrogenation processes. Due to safety aspects, and because of the low density, which makes difficult transportation and storage, such streams often constitute a problem for plant managers. In most cases recycling within the plant processes is not possible, and transportation to other sites, generally by truck after compression in cylinders, is not economical. Many of these streams arc therefore simply co-burned in plant boilers, and in some cases even wasted by venting or flaring. Their value ranges from zero (if vented), to the value of the fuel used in the boiler, where they are co-burned.

  8. In situ Gas Conditioning in Fuel Reforming for Hydrogen Generation

    Energy Technology Data Exchange (ETDEWEB)

    Bandi, A.; Specht, M.; Sichler, P.; Nicoloso, N.

    2002-09-20

    The production of hydrogen for fuel cell applications requires cost and energy efficient technologies. The Absorption Enhanced Reforming (AER), developed at ZSW with industrial partners, is aimed to simplify the process by using a high temperature in situ CO2 absorption. The in situ CO2 removal results in shifting the steam reforming reaction equilibrium towards increased hydrogen concentration (up to 95 vol%). The key part of the process is the high temperature CO2 absorbent. In this contribution results of Thermal Gravimetric Analysis (TGA) investigations on natural minerals, dolomites, silicates and synthetic absorbent materials in regard of their CO2 absorption capacity and absorption/desorption cyclic stability are presented and discussed. It has been found that the inert parts of the absorbent materials have a structure stabilizing effect, leading to an improved cyclic stability of the materials.

  9. Refueling Infrastructure for Alternative Fuel Vehicles: Lessons Learned for Hydrogen; Workshop Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Melaina, M. W.; McQueen, S.; Brinch, J.

    2008-07-01

    DOE sponsored the Refueling Infrastructure for Alternative Fuel Vehicles: Lessons Learned for Hydrogen workshop to understand how lessons from past experiences can inform future efforts to commercialize hydrogen vehicles. This report contains the proceedings from the workshop.

  10. Fiber Optic Sensors for Leak Detection and Condition Monitoring in Hydrogen Fuel Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR Phase I proposal addresses the need for explosion proof, sensitive and reliable hydrogen sensors for NASA and commercial hydrogen fuel systems. It also...

  11. Guide to Permitting Hydrogen Motor Fuel Dispensing Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Rivkin, Carl [National Renewable Energy Lab. (NREL), Golden, CO (United States); Buttner, William [National Renewable Energy Lab. (NREL), Golden, CO (United States); Burgess, Robert [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2016-03-28

    The purpose of this guide is to assist project developers, permitting officials, code enforcement officials, and other parties involved in developing permit applications and approving the implementation of hydrogen motor fuel dispensing facilities. The guide facilitates the identification of the elements to be addressed in the permitting of a project as it progresses through the approval process; the specific requirements associated with those elements; and the applicable (or potentially applicable) codes and standards by which to determine whether the specific requirements have been met. The guide attempts to identify all applicable codes and standards relevant to the permitting requirements.

  12. Energy Technology Analysis Prospects for Hydrogen and Fuel Cells

    CERN Document Server

    2005-01-01

    Energy security, economic prosperity and environmental protection are prominent challenges for all countries. The use of hydrogen as an energy carrier and fuel cells as motive devices in transportation and energy distribution systems are possible solutions. This book provides the reader with an authoritative and objective analysis of policy responses and hurdles and business opportunities. Information regarding the latest RD&D, policy initiatives and private sector plans are assessed from the perspective of the rapidly changing global energy system in the next half century. This book prov

  13. The German hydrogen and fuel cell community. Successes and failures

    Energy Technology Data Exchange (ETDEWEB)

    Canzler, Weert; Marz, Lutz [Wissenschaftszentrum Berlin fuer Sozialforschung gGmbH (WZB), Berlin (Germany); Galich, Ante [Luxembourg Univ. (Luxembourg). Faculty of Languages and Literature, Humanities, Arts and Education

    2013-11-01

    Recently, the German Federal Government made the consequential decision to change its energy program. This not only as a result of the decision to shut down the existing nuclear power plants within the next few years, but also due to vital challenges like climate change and security of energy supply. The shift in the energy-technology paradigm from fossil fuel technologies to regenerative energies constitutes a major technical process but also new economic and social constellations. This paper focuses on hydrogen and fuel cell technologies in Germany. The institutional set up in this field is analysed and the new organizational actors are identified who have actively lobbied towards a political consensus. However, the experts in this field could not attain the required leadership in the public discourse on these technologies. It seems that an attractive guiding vision of a post-fossil energy future and a broad acceptance in daily use would have been major prerequisites for such leadership. (orig.)

  14. DOE Hydrogen, Fuel Cells and Infrastructure Technologies Program Integrated Hydrogen Production, Purification and Compression System

    Energy Technology Data Exchange (ETDEWEB)

    Tamhankar, Satish; Gulamhusein, Ali; Boyd, Tony; DaCosta, David; Golben, Mark

    2011-06-30

    The project was started in April 2005 with the objective to meet the DOE target of delivered hydrogen of <$1.50/gge, which was later revised by DOE to $2-$3/gge range for hydrogen to be competitive with gasoline as a fuel for vehicles. For small, on-site hydrogen plants being evaluated at the time for refueling stations (the 'forecourt'), it was determined that capital cost is the main contributor to the high cost of delivered hydrogen. The concept of this project was to reduce the cost by combining unit operations for the entire generation, purification, and compression system (refer to Figure 1). To accomplish this, the Fluid Bed Membrane Reactor (FBMR) developed by MRT was used. The FBMR has hydrogen selective, palladium-alloy membrane modules immersed in the reformer vessel, thereby directly producing high purity hydrogen in a single step. The continuous removal of pure hydrogen from the reformer pushes the equilibrium 'forward', thereby maximizing the productivity with an associated reduction in the cost of product hydrogen. Additional gains were envisaged by the integration of the novel Metal Hydride Hydrogen Compressor (MHC) developed by Ergenics, which compresses hydrogen from 0.5 bar (7 psia) to 350 bar (5,076 psia) or higher in a single unit using thermal energy. Excess energy from the reformer provides up to 25% of the power used for driving the hydride compressor so that system integration improved efficiency. Hydrogen from the membrane reformer is of very high, fuel cell vehicle (FCV) quality (purity over 99.99%), eliminating the need for a separate purification step. The hydride compressor maintains hydrogen purity because it does not have dynamic seals or lubricating oil. The project team set out to integrate the membrane reformer developed by MRT and the hydride compression system developed by Ergenics in a single package. This was expected to result in lower cost and higher efficiency compared to conventional hydrogen production

  15. Analytic Methods for Benchmarking Hydrogen and Fuel Cell Technologies; NREL (National Renewable Energy Laboratory)

    Energy Technology Data Exchange (ETDEWEB)

    Melaina, Marc; Saur, Genevieve; Ramsden, Todd; Eichman, Joshua

    2015-05-28

    This presentation summarizes NREL's hydrogen and fuel cell analysis work in three areas: resource potential, greenhouse gas emissions and cost of delivered energy, and influence of auxiliary revenue streams. NREL's hydrogen and fuel cell analysis projects focus on low-­carbon and economic transportation and stationary fuel cell applications. Analysis tools developed by the lab provide insight into the degree to which bridging markets can strengthen the business case for fuel cell applications.

  16. Relationship between the variations of hydrogen in HCNG fuel and the oxygen in exhausted gas

    OpenAIRE

    Preecha Yaom; Sarawoot Watechagit

    2015-01-01

    The variation of the mixing ratio between hydrogen and compressed natural gas (CNG) in hydrogen enriched compressed natural gas fuel (HCNG) gives different results in terms of engine performances, fuel consumption, and emission characteristics. Therefore, the engine performance using HCNG as fuel can be optimized if the mixing ratio between the two fuels in HCNG can be adjusted in real time while the engine is being operated. In this research, the relationship between the amount of oxygen in ...

  17. Comparison of alternate fuels for aircraft. [liquid hydrogen, liquid methane, and synthetic aviation kerosene

    Science.gov (United States)

    Witcofski, R. D.

    1979-01-01

    Liquid hydrogen, liquid methane, and synthetic aviation kerosene were assessed as alternate fuels for aircraft in terms of cost, capital requirements, and energy resource utilization. Fuel transmission and airport storage and distribution facilities are considered. Environmental emissions and safety aspects of fuel selection are discussed and detailed descriptions of various fuel production and liquefaction processes are given. Technological deficiencies are identified.

  18. Control of malodorous hydrogen sulfide compounds using microbial fuel cell.

    Science.gov (United States)

    Eaktasang, Numfon; Min, Hyeong-Sik; Kang, Christina; Kim, Han S

    2013-10-01

    In this study, a microbial fuel cell (MFC) was used to control malodorous hydrogen sulfide compounds generated from domestic wastewaters. The electricity production demonstrated a distinct pattern of a two-step increase during 170 h of system run: the first maximum current density was 118.6 ± 7.2 mA m⁻² followed by a rebound of current density increase, reaching the second maximum of 176.8 ± 9.4 mA m⁻². The behaviors of the redox potential and the sulfate level in the anode compartment indicated that the microbial production of hydrogen sulfide compounds was suppressed in the first stage, and the hydrogen sulfide compounds generated from the system were removed effectively as a result of their electrochemical oxidation, which contributed to the additional electricity production in the second stage. This was also directly supported by sulfur deposits formed on the anode surface, which was confirmed by analyses on those solids using a scanning electron microscope equipped with energy dispersive X-ray spectroscopy as well as an elemental analyzer. To this end, the overall reduction efficiencies for HS⁻ and H₂S(g) were as high as 67.5 and 96.4 %, respectively. The correlations among current density, redox potential, and sulfate level supported the idea that the electricity signal generated in the MFC can be utilized as a potential indicator of malodor control for the domestic wastewater system.

  19. Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels

    Energy Technology Data Exchange (ETDEWEB)

    University of Central Florida

    2004-01-30

    The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

  20. Light Obscuration Particle Counter Fuel Contamination Limits

    Science.gov (United States)

    2015-10-08

    contamination . Based on this work the Department of Defense Tri-Service Petroleum, Oil and Lubricants Technical Steering Committee has recommended...4) (5). The Army utilizes ASTM D4176 – Standard Test Method for Free Water and Particulate Contamination in Distillate Fuels (Visual Inspection...specifies limits for free water and particulate matter in aviation fuels. Specifically, free water contamination in jet fuel cannot exceed 10 parts per

  1. The public acceptance of Hydrogen Fuel Cell applications in Europe

    Directory of Open Access Journals (Sweden)

    Christian Oltra

    2017-12-01

    Full Text Available There is increasing realisation amongst policy makers and industry that ‘social acceptance’ is a key issue in the deployment of low carbon energy technologies and infrastructures in Europe. The development of hydrogen fuel cell technologies (HFCs involves small-scale residential and transport applications, as well as large-scale infrastructures, the socio-technical embedment of which will be influenced by the public and stakeholders in various roles. Previous research on public acceptance has investigated public perceptions of HFCs in specific countries. Here we present survey data on a multi-country scale, using a multivariate, socio-psychological approach. We particularly focus on cross-country differences in self-reported awareness and familiarity, global attitude and support in relation to mobile and residential HFC applications. Our data shows that less than half of the population in the seven countries are aware of the existence of hydrogen and fuel cell technologies in the context of energy production. The level of familiarity with both applications is low, and less than 10% of respondents consider themselves familiar with these applications. In general, respondents in the seven countries have a positive initial attitude towards HFC technologies and are likely to accept and support the adoption of residential fuel cells and HFCEVs. The seven populations studied are similar in their attitudes towards HFC technologies, but there are small to moderate differences in awareness and acceptance of HFC applications across countries. We finally found that positive and negative affect, perceived benefits, preference for alternative technologies, trust, and age were significant correlates of acceptance of HFC applications. We consider the implications of these differences for the public acceptance of HFCs.

  2. Light and Heavy Tactical Wheeled Vehicle Fuel Consumption Evaluations Using Fuel Efficient Gear Oils (FEGO)

    Science.gov (United States)

    2016-05-01

    UNCLASSIFIED LIGHT AND HEAVY TACTICAL WHEELED VEHICLE FUEL CONSUMPTION EVALUATIONS USING FUEL EFFICIENT GEAR OILS (FEGO) FINAL...HEAVY TACTICAL WHEELED VEHICLE FUEL CONSUMPTION EVALUATIONS USING FUEL EFFICIENT GEAR OILS (FEGO) FINAL REPORT TFLRF No. 477 by Adam C... subject to any penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number. PLEASE DO

  3. Evaluation of Additives to Eliminate Free Water from Aviation Fuel Light Obscuration Particle Counts

    Science.gov (United States)

    2015-11-01

    SiO2 extracted the water from the fuel samples via hydrogen bonding. This absorption of the free water to the walls of the glass bottles resulted in...contamination on light obscuration particle counting data. 15. SUBJECT TERMS fuel, JP-8, diesel, contamination, particulate, free water , absorption ...ISO 12103-1 A3 medium test dust and free water evaluation in glass bottles. 1 Table 3. 1.0 mg/L ISO 12103-1 A3 medium test dust and 15 ppm free water 2

  4. Light-Duty Vehicle CO2 and Fuel Economy Trends

    Science.gov (United States)

    This report provides data on the fuel economy, carbon dioxide (CO2) emissions, and technology trends of new light-duty vehicles (cars, minivans, sport utility vehicles, and pickup trucks) for model years 1975 to present in the United States.

  5. Structure and dynamics of hydrogen in nanocomposite solid acids for fuel cell applications

    NARCIS (Netherlands)

    Mulder, F.M.; Chan, W.K.

    The transition to sustainable energy sources is inevitable. A possible future scenario could be the hydrogen economy, where the fuel cell plays an important role in the conversion of hydrogen back to electricity. The technology behind the fuel cell however, still has significant room for

  6. Conclusions and recommendations. [for problems in energy situation, air transportation, and hydrogen fuel

    Science.gov (United States)

    1973-01-01

    Conclusions and recommendations are presented for an analysis of the total energy situation; the effect of the energy problem on air transportation; and hydrogen fuel for aircraft. Properties and production costs of fuels, future prediction for energy and transportation, and economic aspects of hydrogen production are appended.

  7. Structure and dynamics of hydrogen in nanocomposite solid acids for fuel cell applications

    NARCIS (Netherlands)

    Chan, W.K.

    2011-01-01

    The transition to sustainable energy sources is inevitable. A possible future scenario could be the hydrogen economy, where the fuel cell plays an important role in the conversion of hydrogen back to electricity. The technology behind the fuel cell however, still has significant room for

  8. Fuel cell cars in a microgrid for synergies between hydrogen and electricity networks

    NARCIS (Netherlands)

    Alavi, F.; Park Lee, H.; van de Wouw, N.; De Schutter, B.H.K.; Lukszo, Z.

    2017-01-01

    Fuel cell electric vehicles convert chemical energy of hydrogen into electricity to power their motor. Since cars are used for transport only during a small part of the time, energy stored in the on-board hydrogen tanks of fuel cell vehicles can be used to provide power when cars are parked. In

  9. Hydrogen and fuel cells: the preparation is following; Hydrogene et piles a combustible: la gestation se poursuit

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The first applications of the fuel cells for the public are announced for 2007 in the portable domain (computers, phones...). Some technological locks remain to overcome in order to decrease the the hydrogen and cells production costs and to improve their longevity, especially for the automotive sector. The author discusses the static and the moving applications, the embedded applications, the platinum and the catalyzers, the hydrogen storage, the robotization and the hydrogen production. (A.L.B.)

  10. Retail Infrastructure Costs Comparison for Hydrogen and Electricity for Light-Duty Vehicles: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Melaina, M.; Sun, Y.; Bush, B.

    2014-08-01

    Both hydrogen and plug-in electric vehicles offer significant social benefits to enhance energy security and reduce criteria and greenhouse gas emissions from the transportation sector. However, the rollout of electric vehicle supply equipment (EVSE) and hydrogen retail stations (HRS) requires substantial investments with high risks due to many uncertainties. We compare retail infrastructure costs on a common basis - cost per mile, assuming fueling service to 10% of all light-duty vehicles in a typical 1.5 million person city in 2025. Our analysis considers three HRS sizes, four distinct types of EVSE and two distinct EVSE scenarios. EVSE station costs, including equipment and installation, are assumed to be 15% less than today's costs. We find that levelized retail capital costs per mile are essentially indistinguishable given the uncertainty and variability around input assumptions. Total fuel costs per mile for battery electric vehicle (BEV) and plug-in hybrid vehicle (PHEV) are, respectively, 21% lower and 13% lower than that for hydrogen fuel cell electric vehicle (FCEV) under the home-dominant scenario. Including fuel economies and vehicle costs makes FCEVs and BEVs comparable in terms of costs per mile, and PHEVs are about 10% less than FCEVs and BEVs. To account for geographic variability in energy prices and hydrogen delivery costs, we use the Scenario Evaluation, Regionalization and Analysis (SERA) model and confirm the aforementioned estimate of cost per mile, nationally averaged, but see a 15% variability in regional costs of FCEVs and a 5% variability in regional costs for BEVs.

  11. Fuel cell drive system with hydrogen generation in test

    Science.gov (United States)

    Emonts, B.; Bøgild Hansen, J.; Schmidt, H.; Grube, T.; Höhlein, B.; Peters, R.; Tschauder, A.

    In the future, drive systems for vehicles with polymer electrolyte membrane fuel cells (PEMFC) may be the environmentally more acceptable alternative to conventional drives with internal combustion engines. The energy carrier may not be gasoline or diesel, as in combustion engines today, but methanol, which is converted on-board into a hydrogen-rich synthesis gas in a reforming reaction with water. After removal of carbon monoxide in a gas-cleaning step, the conditioned synthesis gas is converted into electricity in a fuel cell using air as the oxidant. The electric energy thus generated serves to supply a vehicle's electric drive system. Based on the process design for a test drive system, a test facility was prepared and assembled at Forschungszentrum Jülich (FZJ). Final function tests with the PEMFC and the integrated compact methanol reformer (CMR) were carried out to determine the performance and the dynamic behaviour. With regard to the 50-kW(H 2)-compact methanol reformer, a special design of catalytic burner was constructed. The burner units, with a total power output of 16 kW, were built and tested under different states of constant and alternating load. If selecting a specific catalyst loading of 40 g Pt/m 2, the burner emissions are below the super ultra low emission vehicle (SULEV) standard. The stationary performance test of the CMR shows a specific hydrogen production of 6.7 m N3/(kg cat h) for a methanol conversion rate of 95% at 280°C. Measurements of the transient behaviour of the CMR clearly show a response time of about 20 s, reaching 99% of the hydrogen flow demand due to the limited performance of the test facility control system. Simulations have been carried out in order to develop a control strategy for hydrogen production by the CMR during the New European Driving Cycle (NEDC). Based on the NEDC, an optimized energy management for the total drive system was evaluated and the characteristic data for different peak load storage systems are

  12. Gaseous fuel safety assessment for light-duty automotive vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Krupka, M.C.; Peaslee, A.T.; Laquer, H.L.

    1983-11-01

    The relative safety of gaseous and liquid fuels utilized for light-duty automotive transportation was assessed. The specific fuels considered were compressed natural gas (CNG), liquefied natural gas (LNG), liquefied petroleum gas (LPG), and as reference, gasoline and diesel fuel. The assessment methodology describes and develops the relative hazards of these fuels from an integrated generic physicochemical property and accident scenario point of view. Fuel-relative safety rankings were established by eliciting expert judgment and combining that judgment with a comparative scoring methodology. Selected accident scenarios included fuel leakage in both residential and public garages; fueling line rupture at a refueling station in the presence of user vehicles or delivery vehicles; and vehicle collisions under rural, urban, and vehicular tunnel conditions. Results permit the generation of selected safe handling criteria.

  13. Fuel Summary Report: Shippingport Light Water Breeder Reactor - Rev. 2

    Energy Technology Data Exchange (ETDEWEB)

    Olson, Gail Lynn; Mc Cardell, Richard Keith; Illum, Douglas Brent

    2002-09-01

    The Shippingport Light Water Breeder Reactor (LWBR) was developed by Bettis Atomic Power Laboratory to demonstrate the potential of a water-cooled, thorium oxide fuel cycle breeder reactor. The LWBR core operated from 1977-82 without major incident. The fuel and fuel components suffered minimal damage during operation, and the reactor testing was deemed successful. Extensive destructive and nondestructive postirradiation examinations confirmed that the fuel was in good condition with minimal amounts of cladding deformities and fuel pellet cracks. Fuel was placed in wet storage upon arrival at the Expended Core Facility, then dried and sent to the Idaho Nuclear Technology and Engineering Center for underground dry storage. It is likely that the fuel remains in good condition at its current underground dry storage location at the Idaho Nuclear Technology and Engineering Center. Reports show no indication of damage to the core associated with shipping, loading, or storage.

  14. Development and validation of a slurry model for chemical hydrogen storage in fuel cell vehicle applications

    Science.gov (United States)

    Brooks, Kriston P.; Pires, Richard P.; Simmons, Kevin L.

    2014-12-01

    The U.S. Department of Energy's (DOE) Hydrogen Storage Engineering Center of Excellence (HSECoE) is developing models for hydrogen storage systems for fuel cell-based light duty vehicle applications for a variety of promising materials. These transient models simulate the performance of the storage system for comparison to the DOE's Technical Targets and a set of four drive cycles. PNNL developed models to simulate the performance and suitability of slurry-based chemical hydrogen storage materials. The storage systems of both a representative exothermic system based on ammonia borane and an endothermic system based on alane were developed and modeled in Simulink®. Once complete, the reactor and radiator components of the model were validated with experimental data. The system design parameters were adjusted to allow the model to successfully meet a highway cycle, an aggressive cycle, a cold-start cycle, and a hot drive cycle. Finally, a sensitivity analysis was performed to identify the range of material properties where these DOE targets and drive cycles could be met. Materials with a heat of reaction >11 kJ mol-1 H2 generated and a slurry hydrogen capacity of >11.4% will meet the on-board efficiency and gravimetric capacity targets, respectively.

  15. Development and Validation of a Slurry Model for Chemical Hydrogen Storage in Fuel Cell Applications

    Energy Technology Data Exchange (ETDEWEB)

    Brooks, Kriston P.; Pires, Richard P.; Simmons, Kevin L.

    2014-07-25

    The US Department of Energy's (DOE) Hydrogen Storage Engineering Center of Excellence (HSECoE) is developing models for hydrogen storage systems for fuel cell-based light duty vehicle applications for a variety of promising materials. These transient models simulate the performance of the storage system for comparison to the DOE’s Technical Targets and a set of four drive cycles. The purpose of this research is to describe the models developed for slurry-based chemical hydrogen storage materials. The storage systems of both a representative exothermic system based on ammonia borane and endothermic system based on alane were developed and modeled in Simulink®. Once complete the reactor and radiator components of the model were validated with experimental data. The model was then run using a highway cycle, an aggressive cycle, cold-start cycle and hot drive cycle. The system design was adjusted to meet these drive cycles. A sensitivity analysis was then performed to identify the range of material properties where these DOE targets and drive cycles could be met. Materials with a heat of reaction greater than 11 kJ/mol H2 generated and a slurry hydrogen capacity of greater than 11.4% will meet the on-board efficiency and gravimetric capacity targets, respectively.

  16. Financial investments in fuel cells and hydrogen projects in Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Brito de Matos, Maiana; Neves, Newton Pimenta Jr.; Silva, Ennio Peres da; Silva Pinto, Cristiano [Universidade Estadual de Campinas (UNICAMP), SP (Brazil)

    2010-07-01

    This work aims to identify, classify and account for the investments in hydrogen and fuel cells from 1999 to 2007 made by the public and private sectors in Brazil. Two methodologies were applied to obtain the data for this study. The Top-Down methodology was used to obtain the information from the sponsoring agencies, institutions and funds that promote science and technology in Brazil, such as CNPq, FINEP, P and D ANEEL and Regional Foundations for Research Support. The Bottom-Up methodology consisted in obtaining data directly from the research groups granted by those agencies. After accounting the total Brazilian investment in the period, this was compared with the investments made by the other BRIC countries (Russia, India and China). Next, BRIC countries investment was compared with those made by the European Union, Japan and the United States. The results show that in order to participate in the market share related to equipment and services for the hydrogen economy, Brazil needs to increase the efforts in research, development and innovation in the area. It will be also necessary to apply resources in other important research issues besides ethanol reforming, polymer electrolyte and solid oxide fuel cells, which are the current technologies supported by the Brazilian funding agencies. To achieve this, resources that are already available could be used more efficiently. Another important evidence is that the total annual investment made BRIC countries together is of the same order of magnitude as the investments made separately by the European Union, Japan and the United States. (orig.)

  17. Hydrogen Fuel Cell Vehicle Fuel Economy Testing at the U.S. EPA National Vehicle and Fuel Emissions Laboratory (SAE Paper 2004-01-2900)

    Science.gov (United States)

    The introduction of hydrogen fuel cell vehicles and their new technology has created the need for development of new fuel economy test procedures and safety procedures during testing. The United States Environmental Protection Agency-National Vehicle Fuels and Emissions Laborato...

  18. Spent fuel data base: commercial light water reactors. [PWR; BWR

    Energy Technology Data Exchange (ETDEWEB)

    Hauf, M.J.; Kniazewycz, B.G.

    1979-12-01

    As a consequence of this country's non-proliferation policy, the reprocessing of spent nuclear fuel has been delayed indefinitely. This has resulted in spent light water reactor (LWR) fuel being considered as a potential waste form for disposal. Since the Nuclear Regulatory Commission (NRC) is currently developing methodologies for use in the regulation of the management and disposal of high-level and transuranic wastes, a comprehensive data base describing LWR fuel technology must be compiled. This document provides that technology baseline and, as such, will support the development of those evaluation standards and criteria applicable to spent nuclear fuel.

  19. Lighting Up Enzymes for Solar Hydrogen Production (Fact Sheet)

    Energy Technology Data Exchange (ETDEWEB)

    2011-02-01

    Scientists at the National Renewable Energy Laboratory (NREL) have combined quantum dots, which are spherical nanoparticles that possess unique size-tunable photophysical properties, with the high substrate selectivity and fast turnover of hydrogenase enzymes to achieve light-driven hydrogen (H2) production. They found that quantum dots of cadmium telluride coated in carboxylic acids easily formed highly stable complexes with the hydrogenase and that these hybrid assemblies functioned to catalyze H2 production using the energy of sunlight.

  20. An analysis of hydrogen production from ammonia hydride hydrogen generators for use in military fuel cell environments

    Science.gov (United States)

    Sifer, Nicholas; Gardner, Kristopher

    In an effort to simultaneously improve upon existing power storage and generation devices while supplying America's war fighters with state-of-the-art equipment, the US military has focused on fuel cell technology for several military applications. These applications include soldier and sensor power (0-100 W) and auxiliary power units (500-3000 W). Over the past few years, the fuel cell industry has realized remarkable decreases in the size and weight of proton exchange membrane (PEM) fuel cell systems. However, a safe and affordable means of storing and generating hydrogen does not yet exist to justify their transition into the field. In order to assess the hydrogen storage capacity and hydrogen generation rates of ammonia (NH 3) based systems, the US Army Communications-Electronics Research, Development, and Engineering Center (CERDEC), tested several ammonia hydride hydrogen generator systems built by Hydrogen Components Inc. (HCI). Experimental results and analysis illustrate that while there are developments necessary at the sub-system level, the hydrogen generators are ideal energy storage devices for low power (5 W) operations over wide temperature ranges. The results show that the hydrogen generators are capable of operating autonomously for over 50+ h of operation (at a 5 W load) and producing hydrogen delivery system energy densities of 480 Wh/kg.

  1. Feasibility Studies of Vortex Flow Impact On the Proliferation of Algae in Hydrogen Production for Fuel Cell Applications

    Science.gov (United States)

    Miskon, Azizi; A/L Thanakodi, Suresh; Shiema Moh Nazar, Nazatul; Kit Chong, Marcus Wai; Sobri Takriff, Mohd; Fakir Kamarudin, Kamrul; Aziz Norzali, Abdul; Nooraya Mohd Tawil, Siti

    2016-11-01

    The instability of crude oil price in global market as well as the sensitivity towards green energy increases, more research works being carried out to find alternative energy replacing the depleting of fossil fuels. Photobiological hydrogen production system using algae is one of the promising alternative energy source. However, the yield of hydrogen utilizing the current photobioreactor (PBR) is still low for commercial application due to restricted light penetration into the deeper regions of the reactor. Therefore, this paper studies the feasibility of vortex flow impact utilizing magnetic stirring in hydrogen production for fuel cell applications. For comparison of results, a magnetic stirrer is placed under a PBR of algae to stir the algae to obtain an even distribution of sunlight to the algae while the controlled PBR of algae kept in static. The produced hydrogen level was measured using hydrogen sensor circuit and the data collected were communicated to laptop using Arduino Uno. The results showed more cell counts and hydrogen produced in the PBR under the influence of magnetic stirring compared to static PBR by an average of 8 percent in 4 days.

  2. Stability of MOF-5 in a hydrogen gas environment containing fueling station impurities

    DEFF Research Database (Denmark)

    Ming, Yang; Purewal, Justin; Yang, Jun

    2016-01-01

    Metal-organic frameworks (MOFs) are an emerging class of porous, crystalline materials with potential application as hydrogen storage media in fuel cell vehicles. Unlike lower capacity adsorbents such as zeolites and carbons, some MOFs are expected to degrade due to attack by impurities present...... in the hydrogen fuel stream. Hydrogen intended for use in fuel cell vehicles should satisfy purity standards, such as those outlined in SAE J2719. This standard limits the concentration of certain species in the fuel stream based primarily on their deleterious effects on PEM fuel cells. However, the impact...... of these contaminants on MOFs is mostly unknown. In the present study MOF-5 is adopted as a prototypical moisture-sensitive hydrogen storage material. Five “impure” gas mixtures were prepared by introducing low-to-moderate levels (i.e., up to ∼200 times greater than the J2719 limit) of selected contaminants (NH3, H2S...

  3. Hydrogen as a fuel for today and tomorrow: expectations for advanced hydrogen storage materials/systems research.

    Science.gov (United States)

    Hirose, Katsuhiko

    2011-01-01

    History shows that the evolution of vehicles is promoted by several environmental restraints very similar to the evolution of life. The latest environmental strain is sustainability. Transport vehicles are now facing again the need to advance to use sustainable fuels such as hydrogen. Hydrogen fuel cell vehicles are being prepared for commercialization in 2015. Despite intensive research by the world's scientists and engineers and recent advances in our understanding of hydrogen behavior in materials, the only engineering phase technology which will be available for 2015 is high pressure storage. Thus industry has decided to implement the high pressure tank storage system. However the necessity of smart hydrogen storage is not decreasing but rather increasing because high market penetration of hydrogen fuel cell vehicles is expected from around 2025 onward. In order to bring more vehicles onto the market, cheaper and more compact hydrogen storage is inevitable. The year 2025 seems a long way away but considering the field tests and large scale preparation required, there is little time available for research. Finding smart materials within the next 5 years is very important to the success of fuel cells towards a low carbon sustainable world.

  4. Hydrogen enriched compressed natural gas (HCNG: A futuristic fuel for internal combustion engines

    Directory of Open Access Journals (Sweden)

    Nanthagopal Kasianantham

    2011-01-01

    Full Text Available Air pollution is fast becoming a serious global problem with increasing population and its subsequent demands. This has resulted in increased usage of hydrogen as fuel for internal combustion engines. Hydrogen resources are vast and it is considered as one of the most promising fuel for automotive sector. As the required hydrogen infrastructure and refueling stations are not meeting the demand, widespread introduction of hydrogen vehicles is not possible in the near future. One of the solutions for this hurdle is to blend hydrogen with methane. Such types of blends take benefit of the unique combustion properties of hydrogen and at the same time reduce the demand for pure hydrogen. Enriching natural gas with hydrogen could be a potential alternative to common hydrocarbon fuels for internal combustion engine applications. Many researchers are working on this for the last few years and work is now focused on how to use this kind of fuel to its maximum extent. This technical note is an assessment of HCNG usage in case of internal combustion engines. Several examples and their salient features have been discussed. Finally, overall effects of hydrogen addition on an engine fueled with HCNG under various conditions are illustrated. In addition, the scope and challenges being faced in this area of research are clearly described.

  5. Texas Hydrogen Highway Fuel Cell Hybrid Bus and Fueling Infrastructure Technology Showcase - Final Scientific/Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Hitchcock, David

    2012-06-29

    The Texas Hydrogen Highway project has showcased a hydrogen fuel cell transit bus and hydrogen fueling infrastructure that was designed and built through previous support from various public and private sector entities. The aim of this project has been to increase awareness among transit agencies and other public entities on these transportation technologies, and to place such technologies into commercial applications, such as a public transit agency. The initial project concept developed in 2004 was to show that a skid-mounted, fully-integrated, factory-built and tested hydrogen fueling station could be used to simplify the design, and lower the cost of fueling infrastructure for fuel cell vehicles. The approach was to design, engineer, build, and test the integrated fueling station at the factory then install it at a site that offered educational and technical resources and provide an opportunity to showcase both the fueling station and advanced hydrogen vehicles. The two primary technology components include: Hydrogen Fueling Station: The hydrogen fueling infrastructure was designed and built by Gas Technology Institute primarily through a funding grant from the Texas Commission on Environmental Quality. It includes hydrogen production, clean-up, compression, storage, and dispensing. The station consists of a steam methane reformer, gas clean-up system, gas compressor and 48 kilograms of hydrogen storage capacity for dispensing at 5000 psig. The station is skid-mounted for easy installation and can be relocated if needed. It includes a dispenser that is designed to provide temperaturecompensated fills using a control algorithm. The total station daily capacity is approximately 50 kilograms. Fuel Cell Bus: The transit passenger bus built by Ebus, a company located in Downey, CA, was commissioned and acquired by GTI prior to this project. It is a fuel cell plug-in hybrid electric vehicle which is ADA compliant, has air conditioning sufficient for Texas operations

  6. Method of Hydrogenous Fuel Usage to Increase the Efficiency in Tandem Diverse Temperature Oxidation System

    Directory of Open Access Journals (Sweden)

    Zubkova Marina

    2016-01-01

    Full Text Available This paper presents the results of estimation energy efficiency, the collation data of thermodynamic calculations and data on material balance for an assessment of electric and thermal components in considered ways to use convention products, performance enhancement in the tandem system containing the high-temperature fuel cell and the low-temperature fuel cell with full heat regeneration for hydrogenous fuel (CH4. The overall effective efficiency (ηΣef. making full use of the recovered heat considered tandem system depends on the efficiency of its constituent fuel cells. The overall effective efficiency of the tandem installation including the fuel converter, separating system, high-temperature oxidation system, and hydrogen disposal system in case of fuel use in the low-temperature fuel cell, is higher than for each of the fuel cell elements separately.

  7. Hydrogen Research for Spaceport and Space-Based Applications: Fuel Cell Projects

    Science.gov (United States)

    Anderson, Tim; Balaban, Canan

    2008-01-01

    The activities presented are a broad based approach to advancing key hydrogen related technologies in areas such as fuel cells, hydrogen production, and distributed sensors for hydrogen-leak detection, laser instrumentation for hydrogen-leak detection, and cryogenic transport and storage. Presented are the results from research projects, education and outreach activities, system and trade studies. The work will aid in advancing the state-of-the-art for several critical technologies related to the implementation of a hydrogen infrastructure. Activities conducted are relevant to a number of propulsion and power systems for terrestrial, aeronautics and aerospace applications. Fuel cell research focused on proton exchange membranes (PEM), solid oxide fuel cells (SOFC). Specific technologies included aircraft fuel cell reformers, new and improved electrodes, electrolytes, interconnect, and seals, modeling of fuel cells including CFD coupled with impedance spectroscopy. Research was conducted on new materials and designs for fuel cells, along with using embedded sensors with power management electronics to improve the power density delivered by fuel cells. Fuel cell applications considered were in-space operations, aviation, and ground-based fuel cells such as; powering auxiliary power units (APUs) in aircraft; high power density, long duration power supplies for interplanetary missions (space science probes and planetary rovers); regenerative capabilities for high altitude aircraft; and power supplies for reusable launch vehicles.

  8. U.S. Clean Energy Hydrogen and Fuel Cell Technologies: A Competitiveness Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Fullenkamp, Patrick [Westside Industrial Retention & Expansion Network, Cleveland, OH (United States); Holody, Diane [Westside Industrial Retention & Expansion Network, Cleveland, OH (United States); James, Brian [Strategic Analysis, Inc., Arlington, VA (United States); Houchins, Cassidy [Strategic Analysis, Inc., Arlington, VA (United States); Wheeler, Douglas [DJW Technology, Dublin, OH (United States); Hart, David [E4tech, London (United Kingdom); Lehner, Franz [E4tech, London (United Kingdom)

    2017-10-10

    The objectives of this project are a 1) Global Competitiveness Analysis of hydrogen and fuel cell systems and components manufactured including 700 bar compressed hydrogen storage system in the U.S., Europe, Asia, and other key areas to be identified to determine the global cost leaders, the best current manufacturing processes, the key factors determining competitiveness, and the potential means of cost reductions; and an 2) Analysis to assess the status of global hydrogen and fuel cell markets. The analysis of units, megawatts by country and by application will focus on polymer electrolyte membrane (PEM) fuel cell systems (automotive and stationary).

  9. Role of membranes and membrane reactors in the hydrogen supply of fuel cells for transports

    Energy Technology Data Exchange (ETDEWEB)

    Julbe, A.; Guizard, Ch. [Institut Europeen des Membranes, UMII, Lab. des Materiaux et des Procedes Membranaires, CNRS UMR 5635, 34 - Montpellier (France)

    2000-07-01

    Production, storage and supply of high-purity hydrogen as a clean and efficient fuel is central to fuel cells technology, in particular in vehicle traction. Actually, technologies for handling liquefied or gaseous hydrogen in transports are not available so that a number of alternative fuels are considered with the aim of in-situ generation of hydrogen through catalytic processes. The integrated concept of membrane reactors (MRs) can greatly benefit to these technologies. Particular emphasis is put on inorganic membranes and their role in MRs performance for H{sub 2} production.

  10. Test and Approval Center for Fuel Cell and Hydrogen Technologies: Phase I. Initiation

    DEFF Research Database (Denmark)

    electricity - can be converted to power and heat. The increased use of hydrogen will decrease oil dependency, which is foreseen to have profound economic as well as political impacts. Fuel cell and hydrogen technologies play an important role in future sustainable energy system scenarios, often in combination...... fuels (natural gas) and on alternative fuels as well. They can therefore bridge the gap between availability and efficient use of fossil fuels on the short term and establishment of an energy market based on renewables on the long term. Hydrogen is a zero carbon energy carrier that– just like...... with other technologies where Denmark already holds strong positions today. This includes for example (1) using biomass for production of electricity, (2) storing of energy by using excess electricity from wind turbines to produce fuel by electrolysis and (3) using fuel cells for load balancing...

  11. Life cycle assessment of the production of hydrogen and transportation fuels from corn stover via fast pyrolysis

    Science.gov (United States)

    Zhang, Yanan; Hu, Guiping; Brown, Robert C.

    2013-06-01

    This life cycle assessment evaluates and quantifies the environmental impacts of the production of hydrogen and transportation fuels from the fast pyrolysis and upgrading of corn stover. Input data for this analysis come from Aspen Plus modeling, a GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model database and a US Life Cycle Inventory Database. SimaPro 7.3 software is employed to estimate the environmental impacts. The results indicate that the net fossil energy input is 0.25 MJ and 0.23 MJ per km traveled for a light-duty vehicle fueled by gasoline and diesel fuel, respectively. Bio-oil production requires the largest fossil energy input. The net global warming potential (GWP) is 0.037 kg CO2eq and 0.015 kg CO2eq per km traveled for a vehicle fueled by gasoline and diesel fuel, respectively. Vehicle operations contribute up to 33% of the total positive GWP, which is the largest greenhouse gas footprint of all the unit processes. The net GWPs in this study are 88% and 94% lower than for petroleum-based gasoline and diesel fuel (2005 baseline), respectively. Biomass transportation has the largest impact on ozone depletion among all of the unit processes. Sensitivity analysis shows that fuel economy, transportation fuel yield, bio-oil yield, and electricity consumption are the key factors that influence greenhouse gas emissions.

  12. Electricity Storage and the Hydrogen-Chlorine Fuel Cell

    Science.gov (United States)

    Rugolo, Jason Steven

    Electricity storage is an essential component of the transforming energy marketplace. Its absence at any significant scale requires that electricity producers sit ready to respond to every flick of a switch, constantly adjusting power production to meet demand. The dispatchable electricity production technologies that currently enable this type of market are growing unpopular because of their carbon emissions. Popular methods to move away from fossil fuels are wind and solar power. These sources also happen to be the least dispatchable. Electricity storage can solve that problem. By overproducing during sunlight to store energy for evening use, or storing during windy periods for delivery in future calm ones, electricity storage has the potential to allow intermittent renewable sources to constitute a large portion of our electricity mix. I investigate the variability of wind in Chapter 2, and show that the variability is not significantly reduced by geographically distributing power production over the entire country of the Netherlands. In Chapter 3, I calculate the required characteristics of a linear-response, constant activity storage technology to map wind and solar production scenarios onto several different supply scenarios for a range of specified system efficiencies. I show that solid electrode batteries have two orders of magnitude too little energy per unit power to be well suited for renewable balancing and emphasize the value of the modular separation between the power and energy components of regenerative fuel cell technologies. In Chapter 4 I introduce the regenerative hydrogen-chlorine fuel cell (rHCFC), which is a specific technology that shows promise for the above applications. In collaboration with Sustainable Innovations, we have made and tested 6 different rHCFCs. In order to understand the relative importance of the different inefficiencies in the rHCFC, Chapter 5 introduces a complex temperature and concentration dependent model of the r

  13. REDUCING ULTRA-CLEAN TRANSPORTATION FUEL COSTS WITH HYMELT HYDROGEN

    Energy Technology Data Exchange (ETDEWEB)

    Donald P. Malone; William R. Renner

    2003-07-31

    This report describes activities for the third quarter of work performed under this agreement. Atmospheric testing was conducted as scheduled on June 5 through June 13, 2003. The test results were encouraging, however, the rate of carbon dissolution was below expectations. Additional atmospheric testing is scheduled for the first week of September 2003. Phase I of the work to be done under this agreement consists of conducting atmospheric gasification of coal using the HyMelt technology to produce separate hydrogen rich and carbon monoxide rich product stream. In addition smaller quantities of petroleum coke and a low value refinery stream will be gasified. DOE and EnviRes will evaluate the results of this work to determine the feasibility and desirability of proceeding to Phase II of the work to be done under this agreement, which is gasification of the above-mentioned feeds at a gasifier pressure of approximately 5 bar. The results of this work will be used to evaluate the technical and economic aspects of producing ultra-clean transportation fuels using the HyMelt technology in existing and proposed refinery configurations.

  14. Study of Knocking Effect in Compression Ignition Engine with Hydrogen as a Secondary Fuel

    Directory of Open Access Journals (Sweden)

    R. Sivabalakrishnan

    2014-01-01

    Full Text Available The aim of this project is detecting knock during combustion of biodiesel-hydrogen fuel and also the knock is suppressed by timed injection of diethyl ether (DEE with biodiesel-hydrogen fuel for different loads. Hydrogen fuel is an effective alternate fuel in making a pollution-free environment with higher efficiency. The usage of hydrogen in compression ignition engine leads to production of knocking or detonation because of its lower ignition energy, wider flammability range, and shorter quenching distance. Knocking combustion causes major engine damage, and also reduces the efficiency. The method uses the measurement and analysis of cylinder pressure signal for various loads. The pressure signal is to be converted into frequency domain that shows the accurate knocking combustion of fuel mixtures. The variation of pressure signal is gradually increased and smoothly reduced to minimum during normal combustion. The rapid rise of pressure signal has occurred during knocking combustion. The experimental setup was mainly available for evaluating the feasibility of normal combustion by comparing with the signals from both fuel mixtures in compression ignition engine. This method provides better results in predicting the knocking feature of biodiesel-hydrogen fuel and the usage of DEE provides complete combustion of fuels with higher performance, and lower emission.

  15. Reactor Design for CO2 Photo-Hydrogenation toward Solar Fuels under Ambient Temperature and Pressure

    Directory of Open Access Journals (Sweden)

    Chun-Ying Chen

    2017-02-01

    Full Text Available Photo-hydrogenation of carbon dioxide (CO2 is a green and promising technology and has received much attention recently. This technique could convert solar energy under ambient temperature and pressure into desirable and sustainable solar fuels, such as methanol (CH3OH, methane (CH4, and formic acid (HCOOH. It is worthwhile to mention that this direction can not only potentially depress atmospheric CO2, but also weaken dependence on fossil fuel. Herein, 1 wt % Pt/CuAlGaO4 photocatalyst was successfully synthesized and fully characterized by ultraviolet-visible light (UV-vis spectroscopy, X-ray diffraction (XRD, Field emission scanning electron microscopy using energy dispersive spectroscopy analysis (FE-SEM/EDS, transmission electron microscopy (TEM, X-ray photoelectron spectroscopy (XPS, and Brunauer-Emmett-Teller (BET, respectively. Three kinds of experimental photo-hydrogenation of CO2 in the gas phase, liquid phase, and gas-liquid phase, correspondingly, were conducted under different H2 partial pressures. The remarkable result has been observed in the gas-liquid phase. Additionally, increasing the partial pressure of H2 would enhance the yield of product. However, when an extra amount of H2 is supplied, it might compete with CO2 for occupying the active sites, resulting in a negative effect on CO2 photo-hydrogenation. For liquid and gas-liquid phases, CH3OH is the major product. Maximum total hydrocarbons 8.302 µmol·g−1 is achieved in the gas-liquid phase.

  16. Light-induced metastable structural changes in hydrogenated amorphous silicon

    Energy Technology Data Exchange (ETDEWEB)

    Fritzsche, H. [Univ. of Chicago, IL (United States)

    1996-09-01

    Light-induced defects (LID) in hydrogenated amorphous silicon (a-Si:H) and its alloys limit the ultimate efficiency of solar panels made with these materials. This paper reviews a variety of attempts to find the origin of and to eliminate the processes that give rise to LIDs. These attempts include novel deposition processes and the reduction of impurities. Material improvements achieved over the past decade are associated more with the material`s microstructure than with eliminating LIDs. We conclude that metastable LIDs are a natural by-product of structural changes which are generally associated with non-radiative electron-hole recombination in amorphous semiconductors.

  17. Dye-Sensitized Hydrobromic Acid Splitting for Hydrogen Solar Fuel Production.

    Science.gov (United States)

    Brady, Matthew D; Sampaio, Renato N; Wang, Degao; Meyer, Thomas J; Meyer, Gerald J

    2017-11-08

    Hydrobromic acid (HBr) has significant potential as an inexpensive feedstock for hydrogen gas (H2) solar fuel production through HBr splitting. Mesoporous thin films of anatase TiO2 or SnO2/TiO2 core-shell nanoparticles were sensitized to visible light with a new Ru(II) polypyridyl complex that served as a photocatalyst for bromide oxidation. These thin films were tested as photoelectrodes in dye-sensitized photoelectrosynthesis cells. In 1 N HBr (aq), the photocatalyst undergoes excited-state electron injection and light-driven Br(-) oxidation. The injected electrons induce proton reduction at a Pt electrode. Under 100 mW cm(-2) white-light illumination, sustained photocurrents of 1.5 mA cm(-2) were measured under an applied bias. Faradaic efficiencies of 71 ± 5% for Br(-) oxidation and 94 ± 2% for H2 production were measured. A 12 μmol h(-1) sustained rate of H2 production was maintained during illumination. The results demonstrate a molecular approach to HBr splitting with a visible light absorbing complex capable of aqueous Br(-) oxidation and excited-state electron injection.

  18. Experimental hydrogen-fueled automotive engine design data-base project. Volume 1. Executive summary report

    Energy Technology Data Exchange (ETDEWEB)

    Swain, M.R.; Adt, R.R. Jr.; Pappas, J.M.

    1983-05-01

    A preliminary hydrogen-fueled automotive piston engine design data-base now exists as a result of a research project at the University of Miami. The effort, which is overviewed here, encompassed the testing of 19 different configurations of an appropriately-modified, 1.6-liter displacement, light-duty automotive piston engine. The design data base includes engine performance and exhaust emissions over the entire load range, generally at a fixed speed (1800 rpm) and best efficiency spark timing. This range was sometimes limited by intake manifold backfiring and lean-limit restrictions; however, effective measures were demonstrated for obviating these problems. High efficiency, competitive specific power, and low emissions were conclusively demonstrated.

  19. Compatibility Studies of Hydrogen Peroxide and a New Hypergolic Fuel Blend

    Science.gov (United States)

    Baldridge, Jennifer; Villegas, Yvonne

    2002-01-01

    Several preliminary materials compatibility studies have been conducted to determine the practicality of a new hypergolic fuel system. Hypergolic fuel ignites spontaneously as the oxidizer decomposes and releases energy in the presence of the fuel. The bipropellant system tested consists of high-test hydrogen peroxide (HTP) and a liquid fuel blend consisting of a hydrocarbon fuel, an ignition enhancer and a transition metal catalyst. In order for further testing of the new fuel blend to take place, some basic materials compatibility and HTP decomposition studies must be accomplished. The thermal decomposition rate of HTP was tested using gas evolution and isothermal microcalorimetry (IMC). Materials were analyzed for compatibility with hydrogen peroxide including a study of the affect welding has on stainless steel elemental composition and its relation to HTP decomposition. Compatibility studies of valve materials in the fuel blend were performed to determine the corrosion resistance of the materials.

  20. [Life cycle assessment of the infrastructure for hydrogen sources of fuel cell vehicles].

    Science.gov (United States)

    Feng, Wen; Wang, Shujuan; Ni, Weidou; Chen, Changhe

    2003-05-01

    In order to promote the application of life cycle assessment and provide references for China to make the project of infrastructure for hydrogen sources of fuel cell vehicles in the near future, 10 feasible plans of infrastructure for hydrogen sources of fuel cell vehicles were designed according to the current technologies of producing, storing and transporting hydrogen. Then life cycle assessment was used as a tool to evaluate the environmental performances of the 10 plans. The standard indexes of classified environmental impacts of every plan were gotten and sensitivity analysis for several parameters were carried out. The results showed that the best plan was that hydrogen will be produced by natural gas steam reforming in central factory, then transported to refuelling stations through pipelines, and filled to fuel cell vehicles using hydrogen gas at last.

  1. Light water reactor fuel response during reactivity initiated accident experiments

    Energy Technology Data Exchange (ETDEWEB)

    MacDonald, P. E.; McCardell, R. K.; Martinson, Z. R.; Seiffert, S. L.

    1979-01-01

    Experimental results from six recent Power Burst Facility (PBF) reactivity initiated accident (RIA) tests are compared with data from previous Special Power Excursion Reactor Test (SPERT), and Japanese Nuclear Safety Research Reactor (NSRR) tests. The RIA fuel behavior experimental program recently started in the PBF is being conducted with coolant conditions typical of hot-startup conditions in a commercial boiling water reactor. The SPERT and NSRR test programs investigated the behavior of single or small clusters of light water reactor (LWR) type fuel rods under approximate room temperature and atmospheric pressure conditions in capsules containing stagnant water. As observed in the SPERT and NSRR tests, energy deposition, and consequent enthalpy increase in the PBF test fuel, appears to be the single most important variable. However, the consequences of failure at boiling water hot-startup system conditions appear to be more severe than previously observed in either the stagnant capsule SPERT or NSRR tests. Metallographic examination of both previously unirradiated and irradiated PBF fuel rod cross sections revealed extensive variation in cladding wall thicknesses (involving considerable plastic flow) and fuel shattering along grain boundaries in both restructured and unrestructured fuel regions. Oxidation of the cladding resulted in fracture at the location of cladding thinning and disintegration of the rods during quench. In addition,swelling of the gaseous and potentially volatile fission products in previously irradiated fuel resulted in volume increases of up to 180% and blockage of the coolant channels within the flow shrouds surrounding the fuel rods.

  2. HYDROGEN PRODUCTION BY THE CYANOBACTERIUM PLECTONEMA BORYANUM: EFFECTS OF INITIAL NITRATE CONCENTRATION, LIGHT INTENSITY, AND INHIBITION OF PHOTOSYSTEM II BY DCMU

    Energy Technology Data Exchange (ETDEWEB)

    Carter, B.; Huesemann, M.

    2008-01-01

    The alarming rate at which atmospheric carbon dioxide levels are increasing due to the burning of fossil fuels will have incalculable consequences if disregarded. Fuel cells, a source of energy that does not add to carbon dioxide emissions, have become an important topic of study. Although signifi cant advances have been made related to fuel cells, the problem of cheap and renewable hydrogen production still remains. The cyanobacterium Plectonema boryanum has demonstrated potential as a resolution to this problem by producing hydrogen under nitrogen defi cient growing conditions. Plectonema boryanum cultures were tested in a series of experiments to determine the effects of light intensity, initial nitrate concentration, and photosystem II inhibitor DCMU (3-(3,4- dichlorophenyl)-1,1-dimethylurea) upon hydrogen production. Cultures were grown in sterile Chu. No. 10 medium within photobioreactors constantly illuminated by halogen lights. Because the enzyme responsible for hydrogen production is sensitive to oxygen, the medium was continuously sparged with argon/CO2 (99.7%/0.3% vol/vol) by gas dispersion tubes immersed in the culture. Hydrogen production was monitored by using a gas chromatograph equipped with a thermal conductivity detector. In the initial experiment, the effects of initial nitrate concentration were tested and results revealed cumulative hydrogen production was maximum at an initial nitrate concentration of 1 mM. A second experiment was then conducted at an initial nitrate concentration of 1 mM to determine the effects of light intensity at 50, 100, and 200 μmole m-2 s-1. Cumulative hydrogen production increased with increasing light intensity. A fi nal experiment, conducted at an initial nitrate concentration of 2 mM, tested the effects of high light intensity at 200 and 400 μmole m-2 s-1. Excessive light at 400 μmole m-2 s-1 decreased cumulative hydrogen production. Based upon all experiments, cumulative hydrogen production rates were optimal

  3. From Extended Nanofluidics to an Autonomous Solar-Light-Driven Micro Fuel-Cell Device.

    Science.gov (United States)

    Pihosh, Yuriy; Uemura, Jin; Turkevych, Ivan; Mawatari, Kazuma; Kazoe, Yutaka; Smirnova, Adelina; Kitamori, Takehiko

    2017-07-03

    Autonomous micro/nano mechanical, chemical, and biomedical sensors require persistent power sources scaled to their size. Realization of autonomous micro-power sources is a challenging task, as it requires combination of wireless energy supply, conversion, storage, and delivery to the sensor. Herein, we realized a solar-light-driven power source that consists of a micro fuel cell (μFC) and a photocatalytic micro fuel generator (μFG) integrated on a single microfluidic chip. The μFG produces hydrogen by photocatalytic water splitting under solar light. The hydrogen fuel is then consumed by the μFC to generate electricity. Importantly, the by-product water returns back to the photocatalytic μFG via recirculation loop without losses. Both devices rely on novel phenomena in extended-nano-fluidic channels that ensure ultra-fast proton transport. As a proof of concept, we demonstrate that μFG/μFC source achieves remarkable energy density of ca. 17.2 mWh cm -2 at room temperature. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. DOE Hydrogen and Fuel Cells Program 2016 Annual Merit Review and Peer Evaluation Report

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2016-11-01

    The fiscal year 2016 U.S. Department of Energy (DOE) Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting (AMR), in conjunction with DOE's Vehicle Technologies Office AMR, was held from June 6-10, 2016, in Washington, D.C. This report is a summary of comments by AMR peer reviewers about the hydrogen and fuel cell projects funded by DOE's Office of Energy Efficiency and Renewable Energy.

  5. DOE Hydrogen and Fuel Cells Program 2017 Annual Merit Review and Peer Evaluation Report

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2017-10-16

    The fiscal year 2017 U.S. Department of Energy (DOE) Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting (AMR), in conjunction with DOE's Vehicle Technologies Office AMR, was held from June June 5-9, 2017, in Washington, D.C. This report is a summary of comments by AMR peer reviewers about the hydrogen and fuel cell projects funded by DOE's Office of Energy Efficiency and Renewable Energy.

  6. Analysis and optimization of a tubular SOFC, using nuclear hydrogen as fuel

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, Daniel G.; Parra, Lazaro R.G.; Fernandez, Carlos R.G., E-mail: dgr@instec.cu [Instituto Superior de Tecnologias y Ciencias Aplicadas, Habana (Cuba). Dept. de Ingenieria Nuclear; Lira, Carlos A.B.O., E-mail: cabol@ufpe.br [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Dept. de Energia Nuclear

    2013-07-01

    One of the main areas of hydrogen uses as an energy carrier is in fuel cells of high standards as solid oxide fuel cells (SOFC). The SOFCs are fuel cells operate at high temperatures making them ideal for use in large power systems, suitable for distributed generation of electricity. Optimization and analysis of these electrochemical devices is an area of great current study. The computational fluid dynamics software (CFD) have unique advantages for analyzing the influence of design parameters on the efficiency of fuel cells. This paper presents a SOFC design cell which employ as fuel hydrogen produced by thermochemical water splitting cycle (I-S). There will be done the optimization of the main parameters thermodynamic and electrochemical cell operating to achieve top performance. Also will be estimate the cell efficiency and a production-consumption hydrogen system. (author)

  7. Retention property of deuterium for fuel recovery in divertor by using hydrogen storage material

    Science.gov (United States)

    Mera, Saori; Tonegawa, Akira; Matsumura, Yoshihito; Sato, Kohnosuke; Kawamura, Kazutaka

    2014-10-01

    Magnetic confinement fusion reactor by using Deuterium and Tritium of hydrogen isotope as fuels is suggested as one of the future energy source. Most fuels don't react and are exhausted out of fusion reactor. Especially, Tritium is radioisotope and rarely exists in nature, so fuels recovery is necessary. This poster presentation will explain about research new fuel recovery method by using hydrogen storage materials in divertor simulator TPD-Sheet IV. Samples are tungsten coated with titanium; tungsten of various thickness, and titanium films deposited by ion plating on tungsten substrates. The sample surface temperature is measured by radiation thermometer. Retention property of deuterium after deuterium plasma irradiation was examined with thermal desorption spectroscopy (TDS). As a result, the TDS measurement shows that deuterium is retained in titanium. Therefore, Titanium as a hydrogen storage material expects to be possible to use separating and recovering fuel particles in divertor.

  8. Making the case for direct hydrogen storage in fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    James, B.D.; Thomas, C.E.; Baum, G.N.; Lomas, F.D. Jr.; Kuhn, I.F. Jr. [Directed Technologies, Inc., Arlington, VA (United States)

    1997-12-31

    Three obstacles to the introduction of direct hydrogen fuel cell vehicles are often states: (1) inadequate onboard hydrogen storage leading to limited vehicle range; (2) lack of an hydrogen infrastructure, and (3) cost of the entire fuel cell system. This paper will address the first point with analysis of the problem/proposed solutions for the remaining two obstacles addressed in other papers. Results of a recent study conducted by Directed Technologies Inc. will be briefly presented. The study, as part of Ford Motor Company/DOE PEM Fuel Cell Program, examines multiple pure hydrogen onboard storage systems on the basis of weight, volume, cost, and complexity. Compressed gas, liquid, carbon adsorption, and metal hydride storage are all examined with compressed hydrogen storage at 5,000 psia being judged the lowest-risk, highest benefit, near-term option. These results are combined with recent fuel cell vehicle drive cycle simulations to estimate the onboard hydrogen storage requirement for full vehicle range (380 miles on the combined Federal driving schedule). The results indicate that a PNGV-like vehicle using powertrain weights and performance realistically available by the 2004 PNGV target data can achieve approximate fuel economy equivalent to 100 mpg on gasoline (100 mpg{sub eq}) and requires storage of approximately 3.6 kg hydrogen for full vehicle storage quantity allows 5,000 psia onboard storage without altering the vehicle exterior lines or appreciably encroaching on the passenger or trunk compartments.

  9. Operating Point Optimization of a Hydrogen Fueled Hybrid Solid Oxide Fuel Cell-Steam Turbine (SOFC-ST Plant

    Directory of Open Access Journals (Sweden)

    Juanjo Ugartemendia

    2013-09-01

    Full Text Available This paper presents a hydrogen powered hybrid solid oxide fuel cell-steam turbine (SOFC-ST system and studies its optimal operating conditions. This type of installation can be very appropriate to complement the intermittent generation of renewable energies, such as wind generation. A dynamic model of an alternative hybrid SOFC-ST configuration that is especially suited to work with hydrogen is developed. The proposed system recuperates the waste heat of the high temperature fuel cell, to feed a bottoming cycle (BC based on a steam turbine (ST. In order to optimize the behavior and performance of the system, a two-level control structure is proposed. Two controllers have been implemented for the stack temperature and fuel utilization factor. An upper supervisor generates optimal set-points in order to reach a maximal hydrogen efficiency. The simulation results obtained show that the proposed system allows one to reach high efficiencies at rated power levels.

  10. Numerical and Experimental Study of Mixing Processes Associated with Hydrogen and High Hydrogen Content Fuels

    Energy Technology Data Exchange (ETDEWEB)

    McDonell, Vincent; Hill, Scott; Akbari, Amin; McDonell, Vincent

    2011-09-30

    As simulation capability improves exponentially with increasingly more cost effective CPUs and hardware, it can be used ?routinely? for engineering applications. Many commercial products are available and they are marketed as increasingly powerful and easy to use. The question remains as to the overall accuracy of results obtained. To support the validation of the CFD, a hierarchical experiment was established in which the type of fuel injection (radial, axial) as well as level of swirl (non-swirling, swirling) could be systematically varied. The effort was limited to time efficient approaches (i.e., generally RANS approaches) although limited assessment of time resolved methods (i.e., unsteady RANS and LES) were considered. Careful measurements of the flowfield velocity and fuel concentration were made using both intrusive and non-intrusive methods. This database was then used as the basis for the assessment of the CFD approach. The numerical studies were carried out with a statistically based matrix. As a result, the effect of turbulence model, fuel type, axial plane, turbulent Schmidt number, and injection type could be studied using analysis of variance. The results for the non-swirling cases could be analyzed as planned, and demonstrate that turbulence model selection, turbulence Schmidt number, and the type of injection will strongly influence the agreement with measured values. Interestingly, the type of fuel used (either hydrogen or methane) has no influence on the accuracy of the simulations. For axial injection, the selection of proper turbulence Schmidt number is important, whereas for radial injection, the results are relatively insensitive to this parameter. In general, it was found that the nature of the flowfield influences the performance of the predictions. This result implies that it is difficult to establish a priori the ?best? simulation approach to use. However, the insights from the relative orientation of the jet and flow do offer some

  11. Experimental hydrogen-fueled automotive engine design data-base project. Volume 2. Main technical report

    Energy Technology Data Exchange (ETDEWEB)

    Swain, M.R.; Adt, R.R. Jr.; Pappas, J.M.

    1983-05-01

    Operational performance and emissions characteristics of hydrogen-fueled engines are reviewed. The project activities are reviewed including descriptions of the test engine and its components, the test apparatus, experimental techniques, experiments performed and the results obtained. Analyses of other hydrogen engine project data are also presented and compared with the results of the present effort.

  12. A Theme-Based Course: Hydrogen as the Fuel of the Future

    Science.gov (United States)

    Shultz, Mary Jane; Kelly, Matthew; Paritsky, Leonid; Wagner, Julia

    2009-01-01

    A theme-based course focusing on the potential role of hydrogen as a future fuel is described. Numerous topics included in typical introductory courses can be directly related to the issue of hydrogen energy. Beginning topics include Avogadro's number, the mole, atomic mass, gas laws, and the role of electrons in chemical transformations. Reaction…

  13. An Experimental Investigation of Hypergolic Ignition Delay of Hydrogen Peroxide with Fuel Mixtures

    Science.gov (United States)

    Blevins, John A.; Gostowski, Rudy; Chianese, Silvio

    2003-01-01

    An experimental evaluation of decomposition and ignition delay of hydrogen peroxide at concentrations of 80% to 98% with combinations of hydrocarbon fuels, tertiary amines and transition metal chelates will be presented in the proposed paper. The results will be compared to hydrazine ignition delays with hydrogen peroxide and nitric acid mixtures using the same test apparatus.

  14. Non-traditional Process of Hydrogen Containing Fuel Mixtures Production for Internal-combustion Engines

    Directory of Open Access Journals (Sweden)

    Gennady G. Kuvshinov

    2012-12-01

    Full Text Available The article justifies the perspectives of development of the environmentally sound technology of hydrogen containing fuel mixtures for internal-combustion engines based on the catalytic process of low-temperature decomposition of hydrocarbons into hydrogen and nanofibrous carbon.

  15. Modeling the reaction kinetics of a hydrogen generator onboard a fuel cell -- Electric hybrid motorcycle

    Science.gov (United States)

    Ganesh, Karthik

    Owing to the perceived decline of the fossil fuel reserves in the world and environmental issues like pollution, conventional fuels may be replaced by cleaner alternative fuels. The potential of hydrogen as a fuel in vehicular applications is being explored. Hydrogen as an energy carrier potentially finds applications in internal combustion engines and fuel cells because it is considered a clean fuel and has high specific energy. However, at 6 to 8 per kilogram, not only is hydrogen produced from conventional methods like steam reforming expensive, but also there are storage and handling issues, safety concerns and lack of hydrogen refilling stations across the country. The purpose of this research is to suggest a cheap and viable system that generates hydrogen on demand through a chemical reaction between an aluminum-water slurry and an aqueous sodium hydroxide solution to power a 2 kW fuel cell on a fuel cell hybrid motorcycle. This reaction is essentially an aluminum-water reaction where sodium hydroxide acts as a reaction promoter or catalyst. The Horizon 2000 fuel cell used for this purpose has a maximum hydrogen intake rate of 28 lpm. The study focuses on studying the exothermic reaction between the reactants and proposes a rate law that best describes the rate of generation of hydrogen in connection to the surface area of aluminum available for the certain reaction and the concentration of the sodium hydroxide solution. Further, the proposed rate law is used in the simulation model of the chemical reactor onboard the hybrid motorcycle to determine the hydrogen flow rate to the fuel cell with time. Based on the simulated rate of production of hydrogen from the chemical system, its feasibility of use on different drive cycles is analyzed. The rate of production of hydrogen with a higher concentration of sodium hydroxide and smaller aluminum powder size was found to enable the installation of the chemical reactor on urban cycles with frequent stops and starts

  16. Onboard Hydrogen/Helium Sensors in Support of the Global Technical Regulation: An Assessment of Performance in Fuel Cell Electric Vehicle Crash Tests

    Energy Technology Data Exchange (ETDEWEB)

    Post, M. B.; Burgess, R.; Rivkin, C.; Buttner, W.; O' Malley, K.; Ruiz, A.

    2012-09-01

    Automobile manufacturers in North America, Europe, and Asia project a 2015 release of commercial hydrogen fuel cell powered light-duty road vehicles. These vehicles will be for general consumer applications, albeit initially in select markets but with much broader market penetration expected by 2025. To assure international harmony, North American, European, and Asian regulatory representatives are striving to base respective national regulations on an international safety standard, the Global Technical Regulation (GTR), Hydrogen Fueled Vehicle, which is part of an international agreement pertaining to wheeled vehicles and equipment for wheeled vehicles.

  17. A Barrier Options Approach to Modeling Project Failure : The Case of Hydrogen Fuel Infrastructure

    NARCIS (Netherlands)

    Engelen, P.J.; Kool, C.J.M.; Li, Y.

    2016-01-01

    Hydrogen fuel cell vehicles have the potential to contribute to a sustainable transport system with zero tailpipe emissions. This requires the construction of a network of fuel stations, a long-term, expensive and highly uncertain investment. We contribute to the literature by including a knock-out

  18. Hydrogen-powered road vehicles : the health benfits and drawbacks of a new fuel

    NARCIS (Netherlands)

    Passchier, W.F.; Erisman, J.W.; Hazel, van den P.J.; Heederik, D.J.J.; Leemans, R.; Legler, J.; Sluijs, J.P.; Dogger, J.W.

    2009-01-01

    Because of the political, social and environmental problems associated with dependency on fossil fuels, there is considerable interest in alternative energy sources. Hydrogen is regarded as a promising option, particularly as a fuel for road vehicles. The Dutch Energy Research Centre (ECN) recently

  19. Turbojet Performance and Operation at High Altitudes with Hydrogen and Jp-4 Fuels

    Science.gov (United States)

    Fleming, W A; Kaufman, H R; Harp, J L , Jr; Chelko, L J

    1956-01-01

    Two current turbojet engines were operated with gaseous-hydrogen and JP-4 fuels at very high altitudes and a simulated Mach number of 0.8. With gaseous hydrogen as the fuel stable operation was obtained at altitudes up to the facility limit of about 90,000 feet and the specific fuel consumption was only 40 percent of that with JP-4 fuel. With JP-4 as the fuel combustion was unstable at altitudes above 60,000 to 65,000 feet and blowout limits were reached at 75,000 to 80,000 feet. Over-all performance, component efficiencies, and operating range were reduced considerable at very high altitudes with both fuels.

  20. The importance of safety in achieving the widespread use of hydrogen as a fuel

    Energy Technology Data Exchange (ETDEWEB)

    Edeskuty, F.J.

    1997-09-01

    The advantages of hydrogen fuel have been adequately demonstrated on numerous occasions. However, two major disadvantages have prevented any significant amount of corresponding development. These disadvantages have been in the economics of producing sufficient quantities of hydrogen and in the safety (both real and perceived) of its use. To date work has mostly been properly centered on solving the economic problems. However, a greater effort on the safety of new hydrogen systems now being proposed also deserves consideration. To achieve the greatest safety in the expansion of the use of hydrogen into its wide-spread use as a fuel, attention must be given to four considerations. These are, obtaining knowledge of all the physical principles involved in the new uses, having in place the regulations that allow the safe interfacing of the new systems, designing and constructing the new systems with safety in mind, and the training of the large number of people that will become the handlers of the hydrogen. Existing organizations that produce, transport, or use hydrogen on a large scale have an excellent safety record. This safety record comes as a consequence of dedicated attention to the above-mentioned principles. However, where these principles were not closely followed, accidents have resulted. Some examples can be cited. As the use of hydrogen becomes more widespread, there must be a mechanism for assuring the universal application of these principles. Larger and more numerous fleet operations with hydrogen fuel may be the best way to begin the indoctrination of the general public to the more general use of hydrogen fuel. Demonstrated safe operation with hydrogen is vital to its final acceptance as the fuel of choice.

  1. Fuel cell collaboration in the United States. Follow up report to the Danish Partnership for Hydrogen and Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-01-15

    Fuel cell technology continues to grow in the United States, with strong sales in stationary applications and early markets such as data centers, materials handling equipment, and telecommunications sites. New fuel cell customers include Fortune 500 companies Apple, eBay, Coca-Cola, and Walmart, who will use fuel cells to provide reliable power to data centers, stores, and facilities. Some are purchasing multi-megawatt (MW) systems, including three of the largest non-utility purchases of stationary fuel cells in the world by AT and T, Apple and eBay - 17 MW, 10 MW and 6 MW respectively. Others are replacing fleets of battery forklifts with fuel cells. Sysco, the food distributor, has more than 700 fuel cell-powered forklifts operating at seven facilities, with more on order. Mega-retailer Walmart now operates more than 500 fuel cell forklifts at three warehouses, including a freezer facility. Although federal government budget reduction efforts are impacting a wide range of departments and programs, fuel cell and hydrogen technology continues to be funded, albeit at a lower level than in past years. The Department of Energy (DOE) is currently funding fuel cell and hydrogen R and D and has nearly 300 ongoing projects at companies, national labs, and universities/institutes universities. The American Recovery and Reinvestment Act (ARRA) of 2009 and DOE's Market Transformation efforts have acted as a government ''catalyst'' for market success of emerging technologies. Early market deployments of about 1,400 fuel cells under the ARRA have led to more than 5,000 additional fuel cell purchases by industry with no DOE funding. In addition, interest in Congress remains high. Senators Richard Blumenthal (D-CT), Chris Coons (D-DE), Lindsey Graham (R-SC) and John Hoeven (R-ND) re-launched the bipartisan Senate Fuel Cell and Hydrogen Caucus in August 2012 to promote the continued development and commercialization of hydrogen and fuel cell technologies

  2. Study of the application of hydrogen fuel to long-range subsonic transport aircraft, volume 2

    Science.gov (United States)

    Brewer, G. D.; Morris, R. E.; Lange, R. H.; Moore, J. W.

    1975-01-01

    The feasibility, practicability, and potential advantages/disadvantages of using liquid hydrogen as fuel in long range, subsonic transport aircraft of advanced design were studied. Both passenger and cargo-type aircraft were investigated. To provide a valid basis for comparison, conventional hydrocarbon (Jet A) fueled aircraft were designed to perform identical missions using the same advanced technology and meeting the same operational constraints. The liquid hydrogen and Jet A fueled aircraft were compared on the basis of weight, size, energy utilization, cost, noise, emissions, safety, and operational characteristics. A program of technology development was formulated.

  3. HYDROGEN AND FUEL CELL EDUCATION AT CALIFORNIA STATE UNIVERSITY, LOS ANGELES

    Energy Technology Data Exchange (ETDEWEB)

    Blekhman, David

    2011-09-30

    California State University, Los Angeles, has partnered with the Department of Energy in addressing the workforce preparation and public education needs of the fuel cell industry and the US economy through a comprehensive set of curriculum development and training activities: * Developing and offering several courses in fuel cell technologies, hydrogen and alternative fuels production, alternative and renewable energy technologies as means of zero emissions hydrogen economy, and sustainable environment. * Establishing a zero emissions PEM fuel cell and hydrogen laboratory supporting curriculum and graduate students teaching and research experiences. * Providing engaging capstone projects for multi-disciplinary teams of senior undergraduate students. * Fostering partnerships with automotive OEMs and energy providers. * Organizing and participating in synergistic projects and activities that grow the program and assure its sustainability.

  4. Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes

    Energy Technology Data Exchange (ETDEWEB)

    Ott, Kevin; Linehan, Sue; Lipiecki, Frank; Aardahl, Christopher L.

    2008-08-24

    The DOE Hydrogen Storage Program is focused on identifying and developing viable hydrogen storage systems for onboard vehicular applications. The program funds exploratory research directed at identifying new materials and concepts for storage of hydrogen having high gravimetric and volumetric capacities that have the potential to meet long term technical targets for onboard storage. Approaches currently being examined are reversible metal hydride storage materials, reversible hydrogen sorption systems, and chemical hydrogen storage systems. The latter approach concerns materials that release hydrogen in endothermic or exothermic chemical bond-breaking processes. To regenerate the spent fuels arising from hydrogen release from such materials, chemical processes must be employed. These chemical regeneration processes are envisioned to occur offboard the vehicle.

  5. Metallic Hydrogen: The Most Powerful Rocket Fuel Yet To Exist

    OpenAIRE

    Silvera, Isaac F.; Cole, John W.

    2010-01-01

    Wigner and Huntington first predicted that pressures of order 25 GPa were required for the transition of solid molecular hydrogen to the atomic metallic phase. Later it was predicted that metallic hydrogen might be a metastable material so that it remains metallic when pressure is released. Experimental pressures achieved on hydrogen have been more than an order of magnitude higher than the predicted transition pressure and yet it remains an insulator. We discuss the applications of metast...

  6. Electro Decomposition of Ammonia into Hydrogen for Fuel Cell Use

    Science.gov (United States)

    2012-01-01

    CERL TR-12-1 vii Tables 1 Energy consumption for hydrogen production in different ammonia electrolysis systems...monia and urea electrolysis processes is the low energy consumption for the production of hydrogen from ammonia and urea. This work was undertaken... hydrogen production in different ammonia electrolysis systems. System Cell Voltage (V) Energy Consumption (Wh/g of H2) Comments 1 Pt-Rh catalyst

  7. High Strength and Compatible Aluminum Alloy for Hydrogen-Peroxide Fuel Tanks

    Science.gov (United States)

    Lee, Jonathan A.

    2004-01-01

    This paper describes the development of a new high strength and Hydrogen Peroxide (HP) propellant compatible aluminum alloy for NASA Hyper-X vehicle's fuel tanks and structures. The tensile strength of the new alloy is more than 3 times stronger than the conventional 5254 alloy while it still maintains HP compatibility similar to 5254 (Class 1 category). The alloy development strategy consists of selecting certain rare earth and transition metals, with unique electrochemical properties, that will not act as catalysts to decompose liquid HP at the atomic level. Such elements will added to the aluminum alloy and the mixture will be cast and rolled into thin sheet metals. Test coupons are machined from sheet metals for HP long-term exposure testing and mechanical properties testing. In addition, the ability to weld the new alloy using Friction Stir Welding has also been explored. Currently, aluminum alloy 5254 is the state-of-the-art material for HP storage, but its yield strength is very low (420 ksi) and may not be suitable for the development of light-weight fuel tanks for Hyper-X vehicles. The new high strength and HP compatible alloy could represent an enabling material technology for NASA's Hyper-X vehicles, where flight weight reduction is a critical requirement. These X-planes are currently under studied as air-breathing hypersonic research vehicles featuring a lifting body configuration with a Rocket Based Combined Cycle (RBCC) engine system.

  8. Hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Pier, M.

    1943-02-19

    A transcript is presented of a speech on the history of the development of hydrogenation of coal and tar. Apparently the talk had been accompanied by the showing of photographic slides, but none of the pictures were included with the report. In giving the history, Dr. Pier mentioned the dependence of much of the development of hydrogenation upon previous development in the related areas of ammonia and methanol syntheses, but he also pointed out several ways in which equipment appropriate for hydrogenation differed considerably from that used for ammonia and methanol. Dr. Pier discussed the difficulties encountered with residue processing, design of the reaction ovens, manufacture of ovens and preheaters, heating of reaction mixtures, development of steels, and development of compressor pumps. He described in some detail his own involvement in the development of the process. In addition, he discussed the development of methods of testing gasolines and other fuels. Also he listed some important byproducts of hydrogenation, such as phenols and polycyclic aromatics, and he discussed the formation of iso-octane fuel from the butanes arising from hydrogenation. In connection with several kinds of equipment used in hydrogenation (whose pictures were being shown), Dr. Pier gave some of the design and operating data.

  9. The Assessment of Hydrogen Energy Systems for Fuel Cell Vehicles Using Principal Componenet Analysis and Cluster Analysis

    DEFF Research Database (Denmark)

    Ren, Jingzheng; Tan, Shiyu; Dong, Lichun

    2012-01-01

    Hydrogen energy which has been recognized as an alternative instead of fossil fuel has been developed rapidly in fuel cell vehicles. Different hydrogen energy systems have different performances on environmental, economic, and energy aspects. A methodology for the quantitative evaluation...... to verify the correctness and accuracy of the principal components (PCs) determined by PCA in this paper. A case including 11 different hydrogen energy systems for fuel cell vehicles has been studied in this paper, and the system using steam reforming of natural gas for hydrogen production, pipeline...... for transportation of hydrogen, hydrogen gas tank for the storage of hydrogen at refueling stations, and gaseous hydrogen as power energy for fuel cell vehicles has been recognized as the best scenario. Also, the clustering results calculated by CA are consistent with those determined by PCA, denoting...

  10. Influence of fuel temperature on supersonic mixing and combustion of hydrogen

    Science.gov (United States)

    Rogers, R. C.

    1977-01-01

    Results are presented from an experimental investigation of the influence of fuel stagnation temperature on the mixing and reaction of hydrogen injected transverse to a supersonic flow in a duct. The hydrogen fuel was injected stoichiometrically at stagnation temperatures of 300 K and 800 K from a row of five circular orifices in the duct wall. Detailed measurements in the flow at the duct exit are used to determine the overall amount of mixing accomplished at each of three test conditions. Static pressure distributions are used with duct wall temperatures and heat flux in a one-dimensional analysis to deduce the fraction of fuel reacted along the duct. Results from the one-dimensional analyses of the tests with hot fuel indicated slightly more fuel reacted at the exit; however, differences in the accomplished mixing obtained from integrations of exit surveys were small.

  11. Artificial photosynthesis for production of hydrogen peroxide and its fuel cells.

    Science.gov (United States)

    Fukuzumi, Shunichi

    2016-05-01

    The reducing power released from photosystem I (PSI) via ferredoxin enables the reduction of NADP(+) to NADPH, which is essential in the Calvin-Benson cycle to make sugars in photosynthesis. Alternatively, PSI can reduce O2 to produce hydrogen peroxide as a fuel. This article describes the artificial version of the photocatalytic production of hydrogen peroxide from water and O2 using solar energy. Hydrogen peroxide is used as a fuel in hydrogen peroxide fuel cells to make electricity. The combination of the photocatalytic H2O2 production from water and O2 using solar energy with one-compartment H2O2 fuel cells provides on-site production and usage of H2O2 as a more useful and promising solar fuel than hydrogen. This article is part of a Special Issue entitled Biodesign for Bioenergetics--The design and engineering of electronc transfer cofactors, proteins and protein networks, edited by Ronald L. Koder and J.L. Ross Anderson. Copyright © 2016 Elsevier B.V. All rights reserved.

  12. Hydrogen Fuel System Design Trades for High-Altitude Long-Endurance Remotely- Operated Aircraft

    Science.gov (United States)

    Millis, Marc G.; Tornabene, Robert T.; Jurns, John M.; Guynn, Mark D.; Tomsik, Thomas M.; VanOverbeke, Thomas J.

    2009-01-01

    Preliminary design trades are presented for liquid hydrogen fuel systems for remotely-operated, high-altitude aircraft that accommodate three different propulsion options: internal combustion engines, and electric motors powered by either polymer electrolyte membrane fuel cells or solid oxide fuel cells. Mission goal is sustained cruise at 60,000 ft altitude, with duration-aloft a key parameter. The subject aircraft specifies an engine power of 143 to 148 hp, gross liftoff weight of 9270 to 9450 lb, payload of 440 lb, and a hydrogen fuel capacity of 2650 to 2755 lb stored in two spherical tanks (8.5 ft inside diameter), each with a dry mass goal of 316 lb. Hydrogen schematics for all three propulsion options are provided. Each employs vacuum-jacketed tanks with multilayer insulation, augmented with a helium pressurant system, and using electric motor driven hydrogen pumps. The most significant schematic differences involve the heat exchangers and hydrogen reclamation equipment. Heat balances indicate that mission durations of 10 to 16 days appear achievable. The dry mass for the hydrogen system is estimated to be 1900 lb, including 645 lb for each tank. This tank mass is roughly twice that of the advanced tanks assumed in the initial conceptual vehicle. Control strategies are not addressed, nor are procedures for filling and draining the tanks.

  13. Effects of hydrogen sulfide in fuel gas on SOFC stack performance with nickel containing anodes

    Energy Technology Data Exchange (ETDEWEB)

    Kavurucu Schubert, Sena

    2012-07-01

    Solid oxide fuel cells (SOFC) can use wide varieties of fuels such as hydrogen, carbon monoxide, hydrocarbons, alcohols as well as synthesis gases from natural gas, biogas and petroleum. Using such a wide range of fuels introduces the risk of unwanted impurities, which can affect the function of the SOFC. One of the known impurities is sulfur which is a well known catalyst poison. This work deals with the effect of H{sub 2}S containing fuel gas on SOFC stack performance as well as regeneration processes and their underlying mechanisms.

  14. Advances in the development of a hydrogen/oxygen PEM fuel cell stack

    Energy Technology Data Exchange (ETDEWEB)

    Tori, C.; Garaventta, G.; Visintin, A.; Triaca, W.E. [Instituto de Investigaciones Fisicoquimicas Teoricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 16, Suc. 4 (1900) La Plata (Argentina); Baleztena, M.; Peralta, C.; Calzada, R.; Jorge, E. [Grupo de Investigacion en Energias Sustentables y Eficiencia Energetica (GIESEE), Departamento de Electrotecnia, Universidad Tecnologica Nacional, Facultad Regional La Plata, Av. 60 esq. 124 (1900) La Plata (Argentina); Barsellini, D. [Instituto de Investigaciones Fisicoquimicas Teoricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, CC 16, Suc. 4 (1900) La Plata (Argentina); Grupo de Investigacion en Energias Sustentables y Eficiencia Energetica (GIESEE), Departamento de Electrotecnia, Universidad Tecnologica Nacional, Facultad Regional La Plata, Av. 60 esq. 124 (1900) La Plata (Argentina)

    2008-07-15

    Recent advances in the design and construction of a hydrogen/oxygen PEM fuel cell stack are presented. A test bench including measurement and control devices to monitor the fuel cell operating parameters was mounted. The influence of the characteristics of the membrane electrode assembly, bipolar plates, etc., on the performance of the fuel cell stack was studied. The behavior of the fuel cell stack with a different number of cells in series was evaluated. In order to identify and minimize the energy losses a critical analysis of the results was done. (author)

  15. Modeling and simulation of hydrogen behavior in Zircaloy-4 fuel cladding

    Energy Technology Data Exchange (ETDEWEB)

    Jason D. Hales; Various

    2014-09-01

    As a result of corrosion during normal operation in nuclear reactors, hydrogen can enter the zirconium-alloy fuel cladding and precipitate as brittle hydride platelets, which can severely degrade the cladding ductility. Under a heterogeneous temperature distribution, hydrides tend to accumulate in the colder areas, creating local spots of degraded cladding that can favor crack initiation. Therefore, an estimation of the local hydride distribution is necessary to help predict the risk of cladding failure. The hydride distribution is governed by three competing phenomena. Hydrogen in solid solution diffuses under a concentration gradient due to Fick’s law and under a temperature gradient due to the Soret effect. Precipitation of the hydride platelets occurs once the hydrogen solubility limit is reached. A model of these phenomena was implemented in the 3D fuel performance code BISON in order to calculate the hydrogen distribution for arbitrary geometries, such as a nuclear fuel rod, and is now available for BISON users. Simulations have been performed on simple geometries to validate the model and its implementation. The simulations predict that before precipitation occurs, hydrogen tends to accumulate in the colder spots due to the Soret effect. Once the solubility limit is reached, hydrogen precipitates and forms a rim close to the outer edge of the cladding. The simulations also predict that the reactor shut down has little effect on already precipitated hydrides but causes the remaining hydrogen to precipitate homogeneously into hydrides.

  16. Modeling and simulation of hydrogen behavior in Zircaloy-4 fuel cladding

    Energy Technology Data Exchange (ETDEWEB)

    Courty, Olivier, E-mail: o.courty@gmail.com [Pennsylvania State University, 45 Bd Gouvion Saint Cyr, 75017 Paris (France); Motta, Arthur T., E-mail: atm2@psu.edu [Department of Mechanical and Nuclear Engineering, 227 Reber Building, Penn State University, University Park, PA 16802 (United States); Hales, Jason D., E-mail: jason.hales@inl.gov [Fuels Modeling and Simulation Department, Idaho National Laboratory (United States)

    2014-09-15

    As a result of corrosion during normal operation in nuclear reactors, hydrogen can enter the zirconium-alloy fuel cladding and precipitate as brittle hydride platelets, which can severely degrade the cladding ductility. Under a heterogeneous temperature distribution, hydrides tend to accumulate in the colder areas, creating local spots of degraded cladding that can favor crack initiation. Therefore, an estimation of the local hydride distribution is necessary to help predict the risk of cladding failure. The hydride distribution is governed by three competing phenomena. Hydrogen in solid solution diffuses under a concentration gradient due to Fick’s law and under a temperature gradient due to the Soret effect. Precipitation of the hydride platelets occurs once the hydrogen solubility limit is reached. A model of these phenomena was implemented in the 3D fuel performance code BISON in order to calculate the hydrogen distribution for arbitrary geometries, such as a nuclear fuel rod, and is now available for BISON users. Simulations have been performed on simple geometries to validate the model and its implementation. The simulations predict that before precipitation occurs, hydrogen tends to accumulate in the colder spots due to the Soret effect. Once the solubility limit is reached, hydrogen precipitates and forms a rim close to the outer edge of the cladding. The simulations also predict that the reactor shut down has little effect on already precipitated hydrides but causes the remaining hydrogen to precipitate homogeneously into hydrides.

  17. The effect of temperature and light intensity on hydrogen production by Rhodobacter capsulatus

    Energy Technology Data Exchange (ETDEWEB)

    Eroglu, Inci [Middle East Technical Univ., Ankara (Turkey). Dept. of Chemical Engineering; Sevinc, Pelin [Middle East Technical Univ., Ankara (Turkey). Dept. of Biotechnology; Guenduez, Ufuk; Yucel, Meral [Middle East Technical Univ., Ankara (Turkey). Dept. of Biological Sciences

    2010-07-01

    Rhodobacter capsulatus is a purple non-sulfur photosynthetic bacterium which can produce hydrogen by photofermentation on acetate and lactate. Hydrogen productivity depends on several parameters such as medium composition, pH, light intensity and temperature. In the present study, the effects of temperature and light intensity on hydrogen production were investigated. The cell growth curve has been fitted to the logistic model and hydrogen productivity was interpreted by Modified Gompertz Equation. The maximum productivity was obtained at 30 C and light intensity of 4000 lux. (orig.)

  18. The impact of carbon materials on the hydrogen storage properties of light metal hydrides

    NARCIS (Netherlands)

    Adelhelm, P.A.|info:eu-repo/dai/nl/313907854; de Jongh, P.E.|info:eu-repo/dai/nl/186125372

    2011-01-01

    The safe and efficient storage of hydrogen is still one of the remaining challenges towards fuel cell powered cars. Metal hydrides are a promising class of materials as they allow the storage of large amounts of hydrogen in a small volume at room temperature and low pressures. However, usually the

  19. Hydrogen as clean fuel via continuous fermentation by anaerobic ...

    African Journals Online (AJOL)

    free and oxidized to water as a combustion product. Bioconversion of synthesis gas to hydrogen was demonstrated in a continuous fermentation utilizing malate as a carbon source. Rhodospirillum rubrum, an anaerobic photosynthetic bacterium ...

  20. Phase 1 feasibility study of an integrated hydrogen PEM fuel cell system. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Luczak, F.

    1998-03-01

    Evaluated in the report is the use of hydrogen fueled proton exchange membrane (PEM) fuel cells for devices requiring less than 15 kW. Metal hydrides were specifically analyzed as a method of storing hydrogen. There is a business and technical part to the study that were developed with feedback from each other. The business potential of a small PEM product is reviewed by examining the markets, projected sales, and required investment. The major technical and cost hurdles to a product are also reviewed including: the membrane and electrode assembly (M and EA), water transport plate (WTP), and the metal hydrides. It was concluded that the best potential stationary market for hydrogen PEM fuel cell less than 15 kW is for backup power use in telecommunications applications.

  1. Kinetic Studies on State of the Art Solid Oxide Cells – A Comparison between Hydrogen/Steam and Reformate Fuels

    DEFF Research Database (Denmark)

    Njodzefon, Jean-Claude; Graves, Christopher R.; Mogensen, Mogens Bjerg

    2015-01-01

    /steam and reformate fuels hydrogen/carbon-dioxide and hydrogen/methane/steam. It was found that the kinetics at the fuel electrode were exactly the same in both reformates. The hydrogen/steam fuel displayed slightly faster kinetics than the reformate fuels. Furthermore the gas conversion impedance in the hydrogen...... into a single process as the gas conversion was reduced. The SOC with finer electrode microstructure displayed improved kinetics.......Electrochemical reaction kinetics at the electrodes of Solid Oxide Cells (SOCs) were investigated at 700 °C for two cells with different fuel electrode microstructures as well as on a third cell with a reduced active electrode area. Three fuel mixtures were investigated – hydrogen...

  2. Advanced chemical hydride-based hydrogen generation/storage system for fuel cell vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Breault, R.W.; Rolfe, J. [Thermo Power Corp., Waltham, MA (United States)

    1998-08-01

    Because of the inherent advantages of high efficiency, environmental acceptability, and high modularity, fuel cells are potentially attractive power supplies. Worldwide concerns over clean environments have revitalized research efforts on developing fuel cell vehicles (FCV). As a result of intensive research efforts, most of the subsystem technology for FCV`s are currently well established. These include: high power density PEM fuel cells, control systems, thermal management technology, and secondary power sources for hybrid operation. For mobile applications, however, supply of hydrogen or fuel for fuel cell operation poses a significant logistic problem. To supply high purity hydrogen for FCV operation, Thermo Power`s Advanced Technology Group is developing an advanced hydrogen storage technology. In this approach, a metal hydride/organic slurry is used as the hydrogen carrier and storage media. At the point of use, high purity hydrogen will be produced by reacting the metal hydride/organic slurry with water. In addition, Thermo Power has conceived the paths for recovery and regeneration of the spent hydride (practically metal hydroxide). The fluid-like nature of the spent hydride/organic slurry will provide a unique opportunity for pumping, transporting, and storing these materials. The final product of the program will be a user-friendly and relatively high energy storage density hydrogen supply system for fuel cell operation. In addition, the spent hydride can relatively easily be collected at the pumping station and regenerated utilizing renewable sources, such as biomass, natural, or coal, at the central processing plants. Therefore, the entire process will be economically favorable and environmentally friendly.

  3. Fuel cell collaboration in the United States. A report to the Danish Partnership for Hydrogen and Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    2011-08-15

    The purpose of this report is to provide members of the Danish Partnership for Hydrogen and Fuel Cells with information regarding collaborative opportunities in the United States. The report is designed to provide an overview of key issues and activities and to provide guidance on strategies for finding U.S. research and commercial partners and gaining access to the U.S. market. Section 1 of this report provides an overview of the key drivers of policy at the federal and state government levels regarding hydrogen and fuel cell technologies and provides a perspective of the U.S. industry and key players. It also suggests three general pathways for accessing U.S. opportunities: enhancing visibility; developing vendor relationships; and establishing a formal presence in the U.S. The next sections summarize focus areas for commercial and research activity that currently are of the greatest interest in the U.S. Section 2 describes major programs within the federal government and national laboratories, and discusses various methods for identifying R and D funding opportunities, with an overview of federal acquisition regulations. Section 3 reviews the efforts of several state governments engaging the fuel cell industry as an economic driver and presents an overview of acquisition at the state level. Section 4 discusses university research and development (R and D) and university-industry partnerships. There are 12 appendices attached to the report. These appendices provide more detailed information regarding the key federal government agencies involved in fuel cells and hydrogen, state-specific policies and activities, national laboratories and universities, and other information regarding the fuel cell and hydrogen industry in the U.S. (Author)

  4. Hydrogen as a fuel additive to enhance combustion and reduce emissions

    Energy Technology Data Exchange (ETDEWEB)

    D' Andrea, T.; Henshaw, P.F. [Windsor Univ., ON (Canada). Dept. of Civil and Environmental Engineering; Sobiesiak, A.; Ting, D.S.-K. [Windsor Univ., ON (Canada). Dept. of Mechanical, Automotive and Materials Engineering

    2002-07-01

    This paper presents the results of a study that examined the effects of adding hydrogen to a gasoline fuelled spark ignition (SI) engine. The idea is to have the hydrogen generated on board through the electrolysis of water, thereby eliminating the need for hydrogen storage and a hydrogen infrastructure. The addition of small amounts of hydrogen to SI engines can decrease carbon monoxide as well as unburnt hydrocarbon emissions and cycle to-cycle variation. NOx emissions can potentially be reduced by operating at lean stoichiometries. In this study, a mixture of air with 2 per cent hydrogen was fed to an engine through the carburettor. This added 20 per cent by volume of the fuel as hydrogen at stoichiometric conditions. The addition of hydrogen proved to have significant effect on engine operation. Cycle-to-cycle variability decreased by a factor of 3 while the indicated mean effective pressure (IMEP) increased by 30 per cent. The engine produced at least 40 per cent more torque when hydrogen was added, and the thermal efficiency improved. However, there was no improvement in emissions. As the flame temperature increased, and the OH and O radicals increased, the NO production increased. There does not appear to be a trend in CO emissions with the addition of hydrogen. 19 refs., 5 figs.

  5. Study and development of a hydrogen/oxygen fuel cell in solid polymer electrolyte technology

    Energy Technology Data Exchange (ETDEWEB)

    Mosdale, R.

    1992-10-29

    The hydrogen/oxygen fuel cell appears today as the best candidate to the replacing of the internal combustion engine for automobile traction. This system uses the non explosive electrochemical recombination of hydrogen and oxygen. It is a clean generator whom only reactive product is water. This thesis shows a theoretical study of this system, the synthesis of different kinds of used electrodes and finally an analysis of water movements in polymer electrolyte by different original technologies. 70 refs., 73 figs., 15 tabs.

  6. Determining air quality and greenhouse gas impacts of hydrogen infrastructure and fuel cell vehicles.

    Science.gov (United States)

    Stephens-Romero, Shane; Carreras-Sospedra, Marc; Brouwer, Jacob; Dabdub, Donald; Samuelsen, Scott

    2009-12-01

    Adoption of hydrogen infrastructure and hydrogen fuel cell vehicles (HFCVs) to replace gasoline internal combustion engine (ICE) vehicles has been proposed as a strategy to reduce criteria pollutant and greenhouse gas (GHG) emissions from the transportation sector and transition to fuel independence. However, it is uncertain (1) to what degree the reduction in criteria pollutants will impact urban air quality, and (2) how the reductions in pollutant emissions and concomitant urban air quality impacts compare to ultralow emission gasoline-powered vehicles projected for a future year (e.g., 2060). To address these questions, the present study introduces a "spatially and temporally resolved energy and environment tool" (STREET) to characterize the pollutant and GHG emissions associated with a comprehensive hydrogen supply infrastructure and HFCVs at a high level of geographic and temporal resolution. To demonstrate the utility of STREET, two spatially and temporally resolved scenarios for hydrogen infrastructure are evaluated in a prototypical urban airshed (the South Coast Air Basin of California) using geographic information systems (GIS) data. The well-to-wheels (WTW) GHG emissions are quantified and the air quality is established using a detailed atmospheric chemistry and transport model followed by a comparison to a future gasoline scenario comprised of advanced ICE vehicles. One hydrogen scenario includes more renewable primary energy sources for hydrogen generation and the other includes more fossil fuel sources. The two scenarios encompass a variety of hydrogen generation, distribution, and fueling strategies. GHG emissions reductions range from 61 to 68% for both hydrogen scenarios in parallel with substantial improvements in urban air quality (e.g., reductions of 10 ppb in peak 8-h-averaged ozone and 6 mug/m(3) in 24-h-averaged particulate matter concentrations, particularly in regions of the airshed where concentrations are highest for the gasoline scenario).

  7. Fabrication and characterisation of hydrogen fuel cell membrane electrode assemblies

    CSIR Research Space (South Africa)

    Mathe

    2006-09-01

    Full Text Available Proton-exchange membrane fuel cells (PEMFC) have been receiving attention owing to their highly attractive properties as a power source for both stationary and mobile applications. Fabrication of Membrane Electrode Assemblies (MEAs) is a key...

  8. Power generation in fuel cells using liquid methanol and hydrogen peroxide

    Science.gov (United States)

    Narayanan, Sekharipuram R. (Inventor); Valdez, Thomas I. (Inventor); Chun, William (Inventor)

    2002-01-01

    The invention is directed to an encapsulated fuel cell including a methanol source that feeds liquid methanol (CH.sub.3 OH) to an anode. The anode is electrical communication with a load that provides electrical power. The fuel cell also includes a hydrogen peroxide source that feeds liquid hydrogen peroxide (H.sub.2 O.sub.2) to the cathode. The cathode is also in communication with the electrical load. The anode and cathode are in contact with and separated by a proton-conducting polymer electrolyte membrane.

  9. 2011 Annual Progress Report: DOE Hydrogen and Fuel Cells Program (Book)

    Energy Technology Data Exchange (ETDEWEB)

    2011-11-01

    In the past year, the DOE Hydrogen and Fuel Cells Program (the Program) made substantial progress toward its goals and objectives. The Program has conducted comprehensive and focused efforts to enable the widespread commercialization of hydrogen and fuel cell technologies in diverse sectors of the economy. With emphasis on applications that will effectively strengthen our nation's energy security and improve our stewardship of the environment, the Program engages in research, development, and demonstration of critical improvements in the technologies. Highlights of the Program's accomplishments can be found in the sub-program chapters of this report.

  10. Tests of the hydrogen-fueled detonation ramjet model in a wind tunnel with thrust measurements

    Science.gov (United States)

    Frolov, S. M.; Zvegintsev, V. I.; Ivanov, V. S.; Aksenov, V. S.; Shamshin, I. O.; Vnuchkov, D. A.; Nalivaichenko, D. G.; Berlin, A. A.; Fomin, V. M.

    2017-10-01

    Experimental studies of an axisymmetric hydrogen-fueled detonation ramjet model 1.05-meter long and 0.31 m in diameter with an expanding annular combustor were performed in a pulse wind tunnel under conditions of approaching air stream Mach number ranging from 4 to 8 with the stagnation temperature of 293 K. In a supersonic air flow entering the combustor, continuous and longitudinally pulsating modes of hydrogen detonation with the corresponding characteristic frequencies of 1250 and 900 Hz were obtained. The maximum measured values of the fuel-based specific impulse and total thrust were 3600 s and 2200 N.

  11. Optimization of the overall energy consumption in cascade fueling stations for hydrogen vehicles

    DEFF Research Database (Denmark)

    Rothuizen, Erasmus Damgaard; Rokni, Masoud

    2014-01-01

    Hydrogen fueling stations are emerging around and in larger cities in Europe and United States together with a number of hydrogen vehicles. The most stations comply with the refueling protocol made by society of automotive engineers and they use a cascade fueling system on-site for filling...... the vehicles. The cascade system at the station has to be refueled as the tank sizes are limited by the high pressures. The process of filling a vehicle and afterward bringing the tanks in refueling station back to same pressures, are called a complete refueling cycle. This study analyzes power consumption...

  12. Robust, Reliable Low Emission Gas Turbine Combustion of High Hydrogen Content Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Wooldridge, Margaret Stacy [Univ. of Michigan, Ann Arbor, MI (United States); Im, Hong Geum [Univ. of Michigan, Ann Arbor, MI (United States)

    2016-12-16

    The effects of high hydrogen content fuels were studied using experimental, computational and theoretical approaches to understand the effects of mixture and state conditions on the ignition behavior of the fuels. A rapid compression facility (RCF) was used to measure the ignition delay time of hydrogen and carbon monoxide mixtures. The data were combined with results of previous studies to develop ignition regime criteria. Analytical theory and direct numerical simulation were used to validate and interpret the RCF ignition data. Based on the integrated information the ignition regime criteria were extended to non-dimensional metrics which enable application of the results to practical gas turbine combustion systems.

  13. Catalytic pressurization of liquid hydrogen fuel tanks for unmanned aerial vehicles

    Science.gov (United States)

    Leachman, Jacob; Street, Melissa Jean; Graham, Teira

    2012-06-01

    As the use and applications of Unmanned Aerial Vehicles (UAV) expand, the need for a lighter weight fuel allowing for longer duration flights has become the primary limiting factor in the advancement of these vehicles. To extend the operational envelope of UAV, onboard condensed hydrogen storage for missions exceeding one week is necessary. Currently, large spherical liquid hydrogen tanks that are pressurized with external helium tanks or electronic heating elements are utilized for this purpose. However, the mass, size, and power consumption of the fuel storage tank and fuel pressurization system significantly limit the flight envelope of UAV. In an effort to alleviate these issues, this paper investigates the technological feasibility of orthohydrogen-parahydrogen catalysis as a method of fuel pressurization. Typical pressurization requirements for takeoff, cruise, and landing are reviewed. Calculations of the catalyst system mass and response time are presented.

  14. Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    Science.gov (United States)

    Clawson, Lawrence G.; Mitchell, William L.; Bentley, Jeffrey M.; Thijssen, Johannes H. J.

    2001-01-01

    A hydrocarbon fuel reformer (200) is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. The reformer (200) comprises first and second tubes (208,218). The first tube (208) includes a first catalyst (214) and receives a first mixture of steam and a first fuel. The second tube (218) is annularly disposed about the first tube (208) and receives a second mixture of an oxygen-containing gas and a second fuel. In one embodiment, a third tube (224) is annularly disposed about the second tube (218) and receives a first reaction reformate from the first tube (208) and a second reaction reformate from the second tube (218). A catalyst reforming zone (260) annularly disposed about the third tube (224) may be provided to subject reformate constituents to a shift reaction. In another embodiment, a fractionator is provided to distill first and second fuels from a fuel supply source.

  15. Reconfiguration of photovoltaic panels for reducing the hydrogen consumption in fuel cells of hybrid systems

    Directory of Open Access Journals (Sweden)

    Daniel González-Montoya

    2017-05-01

    Full Text Available Hybrid generation combines advantages from fuel cell systems with non-predictable generation approaches, such as photovoltaic and wind generators. In such hybrid systems, it is desirable to minimize as much as possible the fuel consumption, for the sake of reducing costs and increasing the system autonomy. This paper proposes an optimization algorithm, referred to as population-based incremental learning, in order to maximize the produced power of a photovoltaic generator. This maximization reduces the fuel consumption in the hybrid aggregation. Moreover, the algorithm's speed enables the real-time computation of the best configuration for the photovoltaic system, which also optimizes the fuel consumption in the complementary fuel cell system. Finally, a system experimental validation is presented considering 6 photovoltaic modules and a NEXA 1.2KW fuel cell. Such a validation demonstrates the effectiveness of the proposed algorithm to reduce the hydrogen consumption in these hybrid systems.

  16. A synergetic use of hydrogen and fuel cells in human spaceflight power systems

    Science.gov (United States)

    Belz, S.

    2016-04-01

    Hydrogen is very flexible in different fields of application of energy conversion. It can be generated by water electrolysis. Stored in tanks it is available for re-electrification by fuel cells. But it is not only the power system, which benefits from use of hydrogen, but also the life support system, which can contain hydrogen consuming technologies for recycling management (e.g. carbon dioxide removal and waste combustion processes). This paper points out various fields of hydrogen use in a human spaceflight system. Depending on mission scenarios, shadow phases, and the need of energy storage, regenerative fuel cell systems can be more efficient than secondary batteries. Here, different power storage concepts are compared by equivalent system mass calculation, thus including impact in the peripheral structure (volume, thermal management, etc.) on the space system. It is also focused on the technical integration aspect, e.g. which peripheral components have to be adapted when hydrogen is also used for life support technologies and what system mass benefit can be expected. Finally, a recommendation is given for the following development steps for a synergetic use of hydrogen and fuel cells in human spaceflight power systems.

  17. Task D: Hydrogen safety analysis

    Energy Technology Data Exchange (ETDEWEB)

    Swain, M.R.; Sievert, B.G. [Univ. of Miami, Coral Gables, FL (United States); Swain, M.N. [Analytical Technologies, Inc., Miami, FL (United States)

    1996-10-01

    This report covers two topics. The first is a review of codes, standards, regulations, recommendations, certifications, and pamphlets which address safety of gaseous fuels. The second is an experimental investigation of hydrogen flame impingement. Four areas of concern in the conversion of natural gas safety publications to hydrogen safety publications are delineated. Two suggested design criteria for hydrogen vehicle fuel systems are proposed. It is concluded from the experimental work that light weight, low cost, firewalls to resist hydrogen flame impingement are feasible.

  18. Comparison between Hydrogen, Methane and Ethylene Fuels in a 3-D Scramjet at Mach 8

    Science.gov (United States)

    2016-06-24

    shock tunnel. 15. SUBJECT TERMS Airbreathing Engines, Hypersonics , Propulsion , AOARD 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT SAR 18...Report Comparison between hydrogen, methane and ethylene fuels in a 3-D Scramjet at Mach 8 Professor Michael K. Smart Chair of Hypersonic Propulsion ... Propulsion and Power. References [1] Lewis, M. J., Significance of Fuel Selection for Hypersonic Vehicle Range, Journal of Propulsion and Power

  19. Comparison between Hydrogen and Methane Fuels in a 3-D Scramjet at Mach 8

    Science.gov (United States)

    2016-06-24

    shock tunnel. 15. SUBJECT TERMS Airbreathing Engines, Hypersonics , Propulsion , AOARD 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT SAR 18...Report Comparison between hydrogen, methane and ethylene fuels in a 3-D Scramjet at Mach 8 Professor Michael K. Smart Chair of Hypersonic Propulsion ... Propulsion and Power. References [1] Lewis, M. J., Significance of Fuel Selection for Hypersonic Vehicle Range, Journal of Propulsion and Power

  20. Fuels demand by light vehicles and motorcycles In Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Gomez, Jose Manoel Antelo [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2010-07-01

    The purpose of this paper is to analyze the consumption of gasoline, alcohol and natural gas vehicle (NGV) by light vehicles and motorcycles in Brazil. Through the estimation of fleets per consumption class, in an environment influenced by a new engine technology (flex-fuel), this exercise estimates the fleet-elasticity of cars (and motorcycles) powered by gasoline, hydrated alcohol, natural gas vehicle (NGV) and flex-fuel, in addition to the income elasticity within the period from January, 2000 to December, 2008. This paper uses an alternative variable as income proxy and estimates the five different fleets through the combination of vehicles sales and scrapping curves. This paper's conclusion is that given specific issues of the Brazilian fuel market, in special prices and technological innovations, the fleets' equations for the consumption of the three fuels represent in a more significant manner the relationships expected between supply and demand variables than the commonly used functions of prices and income. (author)

  1. Electrolytic hydrogen fuel production with solid polymer electrolyte technology.

    Science.gov (United States)

    Titterington, W. A.; Fickett, A. P.

    1973-01-01

    A water electrolysis technology based on a solid polymer electrolyte (SPE) concept is presented for applicability to large-scale hydrogen production in a future energy system. High cell current density operation is selected for the application, and supporting cell test performance data are presented. Demonstrated cell life data are included to support the adaptability of the SPE system to large-size hydrogen generation utility plants as needed for bulk energy storage or transmission. The inherent system advantages of the acid SPE electrolysis technology are explained. System performance predictions are made through the year 2000, along with plant capital and operating cost projections.

  2. Relationship between the variations of hydrogen in HCNG fuel and the oxygen in exhausted gas

    Directory of Open Access Journals (Sweden)

    Preecha Yaom

    2015-09-01

    Full Text Available The variation of the mixing ratio between hydrogen and compressed natural gas (CNG in hydrogen enriched compressed natural gas fuel (HCNG gives different results in terms of engine performances, fuel consumption, and emission characteristics. Therefore, the engine performance using HCNG as fuel can be optimized if the mixing ratio between the two fuels in HCNG can be adjusted in real time while the engine is being operated. In this research, the relationship between the amount of oxygen in the exhausted gas and the mixing composition between the hydrogen and CNG in HCNG is investigated based on the equilibrium equation of combustion. It is found that the main factors affecting the amount of oxygen in exhausted gas when using HCNG as fuel include the error from the air-fuel-ratio (AFR control, the error from the HCNG composition control, and the intended change of the HCNG composition. Theoretically, the amount of the oxygen in the exhaust should increase by 0.78% for every 5% addition of H2 at stoichiometric condition. This value can be higher or lower for lean and rich engine operation, respectively. The experimental results found that at the equivalent ratio around 0.8 the amount of O2 in the exhaust gas increases about 1.23% for every 5% H2 addition, which inclines with the proposed calculations.

  3. A new approach for bio-jet fuel generation from palm oil and limonene in the absence of hydrogen.

    Science.gov (United States)

    Zhang, Jingjing; Zhao, Chen

    2015-12-18

    The traditional methodology includes a carbon-chain shortening strategy to produce bio-jet fuel from lipids via a two-stage process with hydrogen. Here, we propose a new solution using a carbon-chain filling strategy to convert C10 terpene and lipids to jet fuel ranged hydrocarbons with aromatic hydrocarbon ingredients in the absence of hydrogen.

  4. Hydrogen Fuel Cell Analysis: Lessons Learned from Stationary Power Generation Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Scott E. Grasman; John W. Sheffield; Fatih Dogan; Sunggyu Lee; Umit O. Koylu; Angie Rolufs

    2010-04-30

    This study considered opportunities for hydrogen in stationary applications in order to make recommendations related to RD&D strategies that incorporate lessons learned and best practices from relevant national and international stationary power efforts, as well as cost and environmental modeling of pathways. The study analyzed the different strategies utilized in power generation systems and identified the different challenges and opportunities for producing and using hydrogen as an energy carrier. Specific objectives included both a synopsis/critical analysis of lessons learned from previous stationary power programs and recommendations for a strategy for hydrogen infrastructure deployment. This strategy incorporates all hydrogen pathways and a combination of distributed power generating stations, and provides an overview of stationary power markets, benefits of hydrogen-based stationary power systems, and competitive and technological challenges. The motivation for this project was to identify the lessons learned from prior stationary power programs, including the most significant obstacles, how these obstacles have been approached, outcomes of the programs, and how this information can be used by the Hydrogen, Fuel Cells & Infrastructure Technologies Program to meet program objectives primarily related to hydrogen pathway technologies (production, storage, and delivery) and implementation of fuel cell technologies for distributed stationary power. In addition, the lessons learned address environmental and safety concerns, including codes and standards, and education of key stakeholders.

  5. Modification and testing of an engine and fuel control system for a hydrogen fuelled gas turbine

    Science.gov (United States)

    Funke, H. H.-W.; Börner, S.; Hendrick, P.; Recker, E.

    2011-10-01

    The control of pollutant emissions has become more and more important by the development of new gas turbines. The use of hydrogen produced by renewable energy sources could be an alternative. Besides the reduction of NOx emissions emerged during the combustion process, another major question is how a hydrogen fuelled gas turbine including the metering unit can be controlled and operated. This paper presents a first insight in modifications on an Auxiliary Power Unit (APU) GTCP 36300 for using gaseous hydrogen as a gas turbine fuel. For safe operation with hydrogen, the metering of hydrogen has to be fast, precise, and secure. So, the quality of the metering unit's control loop has an important influence on this topic. The paper documents the empiric determination of the proportional integral derivative (PID) control parameters for the metering unit.

  6. Hydrogen Fueling Station Using Thermal Compression: a techno-economic analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kriha, Kenneth [Gas Technology Inst., Des Plaines, IL (United States); Petitpas, Guillaume [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Melchionda, Michael [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Soto, Herie [Shell, Houston TX (United States); Feng, Zhili [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Wang, Yanli [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2017-08-11

    The goal of this project was to demonstrate the technical and economic feasibility of using thermal compression to create the hydrogen pressure necessary to operate vehicle hydrogen fueling stations. The concept of utilizing the exergy within liquid hydrogen to build pressure rather than mechanical components such as compressors or cryogenic liquid pumps has several advantages. In theory, the compressor-less hydrogen station will have lower operating and maintenance costs because the compressors found in conventional stations require large amounts of electricity to run and are prone to mechanical breakdowns. The thermal compression station also utilizes some of the energy used to liquefy the hydrogen as work to build pressure, this is energy that in conventional stations is lost as heat to the environment.

  7. Conceptual design report for a Direct Hydrogen Proton Exchange Membrane Fuel Cell for transportation application

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-05

    This report presents the conceptual design for a Direct-Hydrogen-Fueled Proton Exchange Membrane (PEM) Fuel Cell System for transportation applications. The design is based on the initial selection of the Chrysler LH sedan as the target vehicle with a 50 kW (gross) PEM Fuel Cell Stack (FCS) as the primary power source, a battery-powered Load Leveling Unit (LLU) for surge power requirements, an on-board hydrogen storage subsystem containing high pressure gaseous storage, a Gas Management Subsystem (GMS) to manage the hydrogen and air supplies for the FCS, and electronic controllers to control the electrical system. The design process has been dedicated to the use of Design-to-Cost (DTC) principles. The Direct Hydrogen-Powered PEM Fuel Cell Stack Hybrid Vehicle (DPHV) system is designed to operate on the Federal Urban Driving Schedule (FUDS) and Hiway Cycles. These cycles have been used to evaluate the vehicle performance with regard to range and hydrogen usage. The major constraints for the DPHV vehicle are vehicle and battery weight, transparency of the power system and drive train to the user, equivalence of fuel and life cycle costs to conventional vehicles, and vehicle range. The energy and power requirements are derived by the capability of the DPHV system to achieve an acceleration from 0 to 60 MPH within 12 seconds, and the capability to achieve and maintain a speed of 55 MPH on a grade of seven percent. The conceptual design for the DPHV vehicle is shown in a figure. A detailed description of the Hydrogen Storage Subsystem is given in section 4. A detailed description of the FCS Subsystem and GMS is given in section 3. A detailed description of the LLU, selection of the LLU energy source, and the power controller designs is given in section 5.

  8. Performance and specific emissions contours throughout the operating range of hydrogen-fueled compression ignition engine with diesel and RME pilot fuels

    Directory of Open Access Journals (Sweden)

    Shahid Imran

    2015-09-01

    Full Text Available This paper presents the performance and emissions contours of a hydrogen dual fueled compression ignition (CI engine with two pilot fuels (diesel and rapeseed methyl ester, and compares the performance and emissions iso-contours of diesel and rapeseed methyl ester (RME single fueling with diesel and RME piloted hydrogen dual fueling throughout the engines operating speed and power range. The collected data have been used to produce iso-contours of thermal efficiency, volumetric efficiency, specific oxides of nitrogen (NOX, specific hydrocarbons (HC and specific carbon dioxide (CO2 on a power-speed plane. The performance and emission maps are experimentally investigated, compared, and critically discussed. Apart from medium loads at lower and medium speeds with diesel piloted hydrogen combustion, dual fueling produced lower thermal efficiency everywhere across the map. For diesel and RME single fueling the maximum specific NOX emissions are centered at the mid speed, mid power region. Hydrogen dual fueling produced higher specific NOX with both pilot fuels as compared to their respective single fueling operations. The range, location and trends of specific NOX varied significantly when compared to single fueling cases. The volumetric efficiency is discussed in detail with the implications of manifold injection of hydrogen analyzed with the conclusions drawn.

  9. A small portable proton exchange membrane fuel cell and hydrogen generator for medical applications.

    Science.gov (United States)

    Adlhart, O J; Rohonyi, P; Modroukas, D; Driller, J

    1997-01-01

    Small, lightweight power sources for total artificial hearts (TAH), left ventricular assist devices (LVAD), and other medical products are under development. The new power source will provide 2 to 3 times the capacity of conventional batteries. The implications of this new power source are profound. For example, for the Heartmate LVAD, 5 to 8 hours of operation are obtained with 3 lb of lead acid batteries (Personal Communication Mr. Craig Sherman, Thermo Cardiosystems, Inc TCI 11/29/96). With the same weight, as much as 14 hours of operation appear achievable with the proton exchange membrane (PEM) fuel cell power source. Energy densities near 135 watt-hour/L are achievable. These values significantly exceed those of most conventional and advanced primary and secondary batteries. The improvement is mission dependent and even applies for the short deployment cited above. The comparison to batteries becomes even more favorable if the mission length is increased. The higher capacity requires only replacement of lightweight hydride cartridges and logistically available water. Therefore, when one spare 50 L hydride cartridge weighing 115 g is added to the reactant supply the energy density of the total system increases to 230 watt-hour/kg. This new power source is comprised of a hydrogen fueled, air-breathing PEM fuel cell and a miniature hydrogen generator (US Patent No 5,514,353). The fuel cell is of novel construction and differs from conventional bipolar PEM fuel cells by the arrangement of cells on a single sheet of ion-exchange membrane. The construction avoids the weight and volume penalty of conventional bipolar stacks. The hydrogen consumed by the fuel cell is generated load-responsively in the miniature hydrogen generator, by reacting calcium hydride with water, forming in the process hydrogen and lime. The generator is cartridge rechargeable and available in capacities providing up to several hundred watt-hours of electric power.

  10. Literature Review for the Baseline Knowledge Assessment of the Hydrogen, Fuel Cells, and Infrastructure Technologies Program

    Energy Technology Data Exchange (ETDEWEB)

    Truett, L.F.

    2003-12-10

    The purpose of the Hydrogen, Fuel Cells, and Infrastructure Technologies (HFCIT) Program Baseline Knowledge Assessment is to measure the current level of awareness and understanding of hydrogen and fuel cell technologies and the hydrogen economy. This information will be an asset to the HFCIT program in formulating an overall education plan. It will also provide a baseline for comparison with future knowledge and opinion surveys. To assess the current understanding and establish the baseline, the HFCIT program plans to conduct scientific surveys of four target audience groups--the general public, the educational community, governmental agencies, and potential large users. The purpose of the literature review is to examine the literature and summarize the results of surveys that have been conducted in the recent past concerning the existing knowledge and attitudes toward hydrogen. This literature review covers both scientific and, to a lesser extent, non-scientific polls. Seven primary data sources were reviewed, two of which were studies based in Europe. Studies involved both closed-end and open-end questions; surveys varied in length from three questions to multi-page interviews. Populations involved in the studies were primarily adults, although one study involved students. The number of participants ranged from 13 to over 16,000 per study. In addition to the primary surveys, additional related studies were mined for pertinent information. The primary conclusions of the surveys reviewed are that the public knows very little about hydrogen and fuel cell technologies but is generally accepting of the potential for hydrogen use. In general, respondents consider themselves as environmentally conscious. The public considers safety as the primary issue surrounding hydrogen as a fuel. Price, performance, and convenience are also considerations that will have major impacts on purchase decisions.

  11. Hydrogen production from bio-fuels using precious metal catalysts

    Science.gov (United States)

    Pasel, Joachim; Wohlrab, Sebastian; Rotov, Mikhail; Löhken, Katrin; Peters, Ralf; Stolten, Detlef

    2017-11-01

    Fuel cell systems with integrated autothermal reforming unit require active and robust catalysts for H2 production. Thus, an experimental screening of catalysts for autothermal reforming of commercial biodiesel fuel was performed. Catalysts consisted of a monolithic cordierite substrate, an oxide support (γ-Al2O3) and Pt, Ru, Ni, PtRh and PtRu as active phase. Experiments were run by widely varying the O2/C and H2O/C molar ratios at different gas hourly space velocities. Fresh and aged catalysts were characterized by temperature programmed methods and thermogravimetry to find correlations with catalytic activity and stability.

  12. Hydrogen production from bio-fuels using precious metal catalysts

    Directory of Open Access Journals (Sweden)

    Pasel Joachim

    2017-01-01

    Full Text Available Fuel cell systems with integrated autothermal reforming unit require active and robust catalysts for H2 production. Thus, an experimental screening of catalysts for autothermal reforming of commercial biodiesel fuel was performed. Catalysts consisted of a monolithic cordierite substrate, an oxide support (γ-Al2O3 and Pt, Ru, Ni, PtRh and PtRu as active phase. Experiments were run by widely varying the O2/C and H2O/C molar ratios at different gas hourly space velocities. Fresh and aged catalysts were characterized by temperature programmed methods and thermogravimetry to find correlations with catalytic activity and stability.

  13. A Reversible Planar Solid Oxide Fuel-Fed Electrolysis Cell and Solid Oxide Fuel Cell for Hydrogen and Electricity Production Operating on Natural Gas/Biomass Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Tao, Greg, G.

    2007-03-31

    A solid oxide fuel-assisted electrolysis technique was developed to co-generate hydrogen and electricity directly from a fuel at a reduced cost of electricity. Solid oxide fuel-assisted electrolysis cells (SOFECs), which were comprised of 8YSZ electrolytes sandwiched between thick anode supports and thin cathodes, were constructed and experimentally evaluated at various operation conditions on lab-level button cells with 2 cm2 per-cell active areas as well as on bench-scale stacks with 30 cm2 and 100 cm2 per-cell active areas. To reduce the concentration overpotentials, pore former systems were developed and engineered to optimize the microstructure and morphology of the Ni+8YSZ-based anodes. Chemically stable cathode materials, which possess good electronic and ionic conductivity and exhibit good electrocatalytic properties in both oxidizing and reducing gas atmospheres, were developed and materials properties were investigated. In order to increase the specific hydrogen production rate and thereby reduce the system volume and capital cost for commercial applications, a hybrid system that integrates the technologies of the SOFEC and the solid-oxide fuel cell (SOFC), was developed and successfully demonstrated at a 1kW scale, co-generating hydrogen and electricity directly from chemical fuels.

  14. System comparison of hydrogen with other alternative fuels in terms of EPACT requirements

    Energy Technology Data Exchange (ETDEWEB)

    Barbir, F.; Oezay, K.; Veziroglu, T.N. [Univ. of Miami, Coral Gables, FL (United States)

    1996-10-01

    The feasibility of several alternative fuels, namely natural gas, methanol, ethanol, hydrogen and electricity, to replace 10% of gasoline by the year 2000 has been investigated. The analysis was divided in two parts: (i) analysis of vehicle technologies, and (ii) analysis of fuel production storage and distribution, from the primary energy sources to the refueling station. Only technologies that are developed to at least demonstration level were considered. The amount and type of the primary energy sources have been determined for each of the fuels being analyzed. A need for a common denominator for different types of energy has been identified.

  15. A Self-Supported Direct Borohydride-Hydrogen Peroxide Fuel Cell System

    Directory of Open Access Journals (Sweden)

    Ashok K. Shukla

    2009-04-01

    Full Text Available A self-supported direct borohydride-hydrogen peroxide fuel cell system with internal manifolds and an auxiliary control unit is reported. The system, while operating under ambient conditions, delivers a peak power of 40 W with about 2 W to run the auxiliary control unit. A critical cause and effect analysis, on the data for single cells and stack, suggests the optimum concentrations of fuel and oxidant to be 8 wt. % NaBH4 and 2 M H2O2, respectively in extending the operating time of the system. Such a fuel cell system is ideally suited for submersible and aerospace applications where anaerobic conditions prevail.

  16. Direct conversion of light hydrocarbon gases to liquid fuel

    Energy Technology Data Exchange (ETDEWEB)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  17. Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    Science.gov (United States)

    Clawson, Lawrence G.; Mitchell, William L.; Bentley, Jeffrey M.; Thijssen, Johannes H. J.

    2000-01-01

    A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

  18. A study of subsonic transport aircraft configurations using hydrogen (H2) and methane (CH4) as fuel

    Science.gov (United States)

    Snow, D. B.; Avery, B. D.; Bodin, L. A.; Baldasare, P.; Washburn, G. F.

    1974-01-01

    The acceptability of alternate fuels for future commercial transport aircraft are discussed. Using both liquid hydrogen and methane, several aircraft configurations are developed and energy consumption, aircraft weights, range and payload are determined and compared to a conventional Boeing 747-100 aircraft. The results show that liquid hydrogen can be used to reduce aircraft energy consumption and that methane offers no advantage over JP or hydrogen fuel.

  19. The Assessment of Hydrogen Energy Systems for Fuel Cell Vehicles Using Principal Component Analysis and Cluster Analysis

    OpenAIRE

    Ren, Jing-Zheng; Tan, Shi-yu; Dong, Li-chun

    2012-01-01

    Hydrogen energy which has been recognized as an alternative instead of fossil fuel has been developed rapidly in fuel cell vehicles. Different hydrogen energy systems have different performances on environmental, economic, and energy aspects. A methodology for the quantitative evaluation and analysis of the hydrogen systems is meaningful for decision makers to select the best scenario. principal component analysis (PCA) has been used to evaluate the integrated performance of different hydroge...

  20. Hydrogen storage for fuel cell applications: Challenges, opportunities and prospects for metal-organic frameworks

    CSIR Research Space (South Africa)

    Langmi, Henrietta W

    2013-07-01

    Full Text Available CELL APPLICATIONS: CHALLENGES, OPPORTUNITIES AND PROSPECTS FOR METAL-ORGANIC FRAMEWORKS Korea-South Africa H2 Fuel Cell Collaboration Workshop,15-18 July 2013, Hyundai Hotel, Gyeongju, Rep. of Korea Dr. Henrietta Langmi, Hy...% Russia 12% North America 5% Others 4% PGM Supply by region Slide 6 Strategic Goals  Establish a base for hydrogen production, storage technologies...

  1. Oxygen-hydrogen fuel cell with an iodine-iodide cathode - A concept

    Science.gov (United States)

    Javet, P.

    1970-01-01

    Fuel cell uses a porous cathode through which is fed a solution of iodine in aqueous iodide solution, the anode is a hydrogen electrode. No activation polarization appears on the cathode because of the high exchange-current density of the iodine-iodide electrode.

  2. Hydrogen-Oxygen PEM Regenerative Fuel Cell at NASA Glenn Research Center

    Science.gov (United States)

    Bents, David J.

    2004-01-01

    The NASA Glenn Research Center has constructed a closed-cycle hydrogen-oxygen PEM regenerative fuel cell (RFC) to explore its potential use as an energy storage device for a high altitude solar electric aircraft. Built up over the last 2 years from specialized hardware and off the shelf components the Glenn RFC is a complete "brassboard" energy storage system which includes all the equipment required to (1) absorb electrical power from an outside source and store it as pressurized hydrogen and oxygen and (2) make electrical power from the stored gases, saving the product water for re-use during the next cycle. It consists of a dedicated hydrogen-oxygen fuel cell stack and an electrolyzer stack, the interconnecting plumbing and valves, cooling pumps, water transfer pumps, gas recirculation pumps, phase separators, storage tanks for oxygen (O2) and hydrogen (H2), heat exchangers, isolation valves, pressure regulators, nitrogen purge provisions, instrumentation, and other components. It specific developmental functions include: (1) Test fuel cells and fuel cell components under repeated closed-cycle operation (nothing escapes; everything is used over and over again). (2) Simulate diurnal charge-discharge cycles (3) Observe long-term system performance and identify degradation and loss mechanisms. (4) Develop safe and convenient operation and control strategies leading to the successful development of mission-capable, flight-weight RFC's.

  3. Combustion gas properties. Part 3: Hydrogen gas fuel and dry air

    Science.gov (United States)

    Wear, J. D.; Jones, R. E.; Mcbride, B. J.; Beyerle, R. A.

    1985-01-01

    A series of computations has been made to produce the equilibrium temperature and gas composition for hydrogen gas fuel and dry air. The computed tables and figures provide combustion gas property data for pressures from 0.5 to 50 atmospheres and equivalence ratios from 0 to 2.0. Only sample tables and figures are provided in this report.

  4. Developing and Implementing a Simple, Affordable Hydrogen Fuel Cell Laboratory in Introductory Chemistry

    Science.gov (United States)

    Klara, Kristina; Hou, Ning; Lawman, Allison; Wu, Liheng; Morrill, Drew; Tente, Alfred; Wang, Li-Qiong

    2014-01-01

    A simple, affordable hydrogen proton exchange membrane (PEM) fuel cell laboratory was developed through a collaborative effort between faculty and undergraduate students at Brown University. It has been incorporated into the introductory chemistry curriculum and successfully implemented in a class of over 500 students per academic year for over 3…

  5. ASU nitrogen sweep gas in hydrogen separation membrane for production of HRSG duct burner fuel

    Science.gov (United States)

    Panuccio, Gregory J.; Raybold, Troy M.; Jamal, Agil; Drnevich, Raymond Francis

    2013-04-02

    The present invention relates to the use of low pressure N2 from an air separation unit (ASU) for use as a sweep gas in a hydrogen transport membrane (HTM) to increase syngas H2 recovery and make a near-atmospheric pressure (less than or equal to about 25 psia) fuel for supplemental firing in the heat recovery steam generator (HRSG) duct burner.

  6. Single-use paper-based hydrogen fuel cells for point-of-care diagnostic applications

    Science.gov (United States)

    Esquivel, J. P.; Buser, J. R.; Lim, C. W.; Domínguez, C.; Rojas, S.; Yager, P.; Sabaté, N.

    2017-02-01

    This work demonstrates a stand-alone power source that integrates a paper-based hydrogen fuel cell with a customized chemical heater that produces hydrogen in-situ upon the addition of a liquid. The presented approach operates by capillary action and takes advantage of the hydrogen released as a by-product of an exothermic reaction used in point-of-care diagnostics. The paper-based fuel cell produces a maximum power of 25.8 mW (103.2 mW cm-2), which is suitable for powering a diversity of electrical devices such as commercially available digital pregnancy tests and glucometers. While device shape and dimensions can be customized, here it is shown that the fuel cell can be designed in a compact form factor and footprint comparable to a lateral flow test while providing a remarkable power output. This approach holds great promise for powering portable diagnostics, as the generated electric power could enable device functionalities required for advanced assays, such as device timing, actuation, and signal quantification. Part of the same liquid sample that is to be analyzed (urine, saliva, water, etc) could be used to trigger the hydrogen generation and start the fuel cell operation.

  7. About the process improvement of adsorptive desulphurisation by adding hydrogen donators as additives in liquid fuels

    Science.gov (United States)

    van Rheinberg, Oliver; Lucka, Klaus; Köhne, Heinrich

    For the use in fuel cell system commercial fuels, like diesel or domestic heating oil, have to be desulphurised to ultra deep sulphur levels of below 1 mg kg -1. To reach this goal the adsorptive desulphurisation using a nickel-based sorbent has been identified. The evaluation of the reaction mechanism reveals in principle the same route as that of the hydrodesulphurisation (HDS) whereas the sulphur is adsorbed by the sorbent instead of being converted to hydrogen sulphide. The required hydrogen for the process is provided out of the fuel itself and not by an external supply of hydrogen. This analysis leads to an easy applicable enhancement of the process by adding a hydrogen donator as an additive to the liquid fuel. In correlation to the mass fraction of the donator the reaction rates and sorbent capacities are improved significantly. Furthermore the influence of aromatic compounds has been investigated, which exhibit similar molecular structures and chemical properties than comparable high refractory sulphur species. This leads to side reactions especially of di- and tri-aromatics which influence the sulphur adsorption. A shift of the aromatic fraction from mono- to di- and tri-aromatic compounds has been observed as well as the alkylation of di- and tri-aromatics.

  8. Design of a Fuel Processor System for Generating Hydrogen for Automotive Applications

    Science.gov (United States)

    Kolavennu, Panini K.; Telotte, John C.; Palanki, Srinivas

    2006-01-01

    The objective of this paper is to design a train of tubular reactors that use a methane feed to produce hydrogen of the desired purity so that it can be utilized by a fuel cell for automotive applications. Reaction engineering principles, which are typically covered at the undergraduate level, are utilized to design this reactor train. It is shown…

  9. Biomass & Natural Gas Based Hydrogen Fuel For Gas Turbine (Power Generation)

    Science.gov (United States)

    Significant progress has been made by major power generation equipment manufacturers in the development of market applications for hydrogen fuel use in gas turbines in recent years. Development of a new application using gas turbines for significant reduction of power plant CO2 e...

  10. Understanding the build-up of a technological innovation system around hydrogen and fuel cell technologies

    NARCIS (Netherlands)

    Suurs, R.A.A.; Hekkert, M.P.; Smits, R.E.H.M.

    2009-01-01

    This study provides insight into the development of hydrogen and fuel cell technologies in the Netherlands (1980-2007). This is done by applying a Technological Innovation System (TIS) approach. This approach takes the perspective that a technology is shaped by a surrounding network of actors,

  11. Combustion of hydrogen in a two-dimensional duct with step fuel injectors

    Science.gov (United States)

    Eggers, J. M.; Reagon, P. G.; Gooderum, P. B.

    1978-01-01

    An investigation of the combustion of hydrogen perpendicularly injected from step fuel injectors into a Mach 2.72, 2100 K vitiated test gas was conducted. The model simulated the flow between the center and side struts of an integrated scramjet module at Mach 7 flight and an altitude of 29 km. Parametric variation included equivalence ratio, fuel dynamic pressure ratio, and area distribution of the model. The overall area ratio of the model was held constant at 2.87. The data analysis indicated that no measurable improvement in mixing or combustion efficiency was obtained by varying the fuel dynamic pressure ratio from 0.79 to 2.45. Computations indicated approximately 80 percent of the fuel was mixed so that it could react; however, only approximately 50 percent of the mixed fuel actually reacted in two test configurations, and 74 percent in later tests where less area expansion of the flow occurred.

  12. Performance of a single fuel-vaporizing combustor with six injectors adapted for gaseous hydrogen

    Science.gov (United States)

    Wear, Jerrold D; Smith, Arthur L

    1955-01-01

    The combustor was operated over a range of inlet-air pressures from 5.3 to 24.0 inches of mercury absolute and inlet-air reference velocities from 60 to 100 feet per second. The combustion efficiencies obtained with the six configurations varied from about 65 to 95 percent for a combustor temperature-rise range of 200 degrees to 1400 degrees F. At a temperature rise of 1200 degrees F (near-rated engine conditions), the spread in efficiencies of the six configurations was about 5 percent. Efficiencies in the range of 65 to 85 percent were obtained at operating conditions beyond the burning range of conventional jet fuels. A fuel-injector configuration that fed only gaseous hydrogen fuel into the standard liquid-fuel-vaporizing tubes generally gave the highest efficiencies. This configuration minimizes the possibility of combustion in the fuel-vaporizing tubes and could be easily adapted to the full-scale engine combustor.

  13. Hydrogen Through Water Electrolysis and Biomass Gasification for Application in Fuel Cells

    Directory of Open Access Journals (Sweden)

    Y. Kirosa

    2017-03-01

    Full Text Available Hydrogen is considered to be one of the most promising green energy carrier in the energy storage and conversion scenario. Although it is abundant on Earth in the form of compounds, its occurrence in free form is extremely low. Thus, it has to be produced by reforming processes, steam reforming (SR, partial oxidation (POX and auto-thermal reforming (ATR mainly from fossil fuels for high throughput with high energy requirements, pyrolysis of biomass and electrolysis. Electrolysis is brought about by passing electric current though two electrodes to evolve water into its constituent parts, viz. hydrogen and oxygen, respectively. Hydrogen produced by non-noble metal catalysts for both anode and cathode is therefore cost-effective and can be integrated into fuel cells for direct chemical energy conversion into electrical energy electricity, thus meeting the sustainable and renewable use with low carbon footprint.

  14. Fast start-up of microchannel fuel processor integrated with an igniter for hydrogen combustion

    Science.gov (United States)

    Ryi, Shin Kun; Park, Jong Soo; Cho, Song Ho; Kim, Sung Hyun

    A Pt-Zr catalyst coated FeCrAlY mesh is introduced into the combustion outlet conduit of a newly designed microchannel reactor (MCR) as an igniter of hydrogen combustion to decrease the start-up time. The catalyst is coated using a wash-coating method. After installing the Pt-Zr/FeCrAlY mesh, the reactor is heated to its running temperature within 1 min with hydrogen combustion. Two plate-type heat-exchangers are introduced at the combustion outlet and reforming outlet conduits of the microchannel reactor in order to recover the heat of the combustion gas and reformed gas, respectively. Using these heat-exchangers, methane steam reforming is carried out with hydrogen combustion and the reforming capacity and energy efficiency are enhanced by up to 3.4 and 1.7 times, respectively. A compact fuel processor and fuel-cell system using this reactor concept is expected to show considerable advancement.

  15. COMPENDIUM: SURVEYS EVALUATING KNOWLEDGE AND OPINIONS CONCERNING HYDROGEN AND FUEL CELL TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Truett, Lorena Faith [ORNL; Cooper, Christy [U.S. Department of Energy; Schmoyer, Richard L [ORNL

    2008-10-01

    This compendium updates a 2003 literature review of surveys of knowledge and opinions of hydrogen and fuel cell technologies. Its purpose is to ensure that results of comparable surveys are considered in surveys conducted by the U.S. Department of Energy (DOE). Over twice as many studies related to the DOE survey have been published since 2003 than prior to that date. The fact that there have been significantly more studies implies that there have been further demonstration projects and/or increased interest in hydrogen and fuel cell technologies. The primary findings of these 15 new surveys, all of which were conducted in Europe (E) or North America (NA), to the DOE surveys are as follows: 1.Respondents who are more educated are more accepting of hydrogen technologies (NA). 2.Respondents who are more knowledgeable about hydrogen and/or fuel cells are more accepting of hydrogen technologies (E, NA). 3.When asked about issues of trust, respondents generally expressed distrust of the government or political parties but trusted scientists and environmental protection organizations (E). 4.Technical knowledge about hydrogen and fuel cell technologies is low (E, NA). 5.Respondents may express opinions about a technology even when they are lacking in knowledge of that technology (E). 6.Women and men have different priorities when deciding on an automobile purchase (E). 7.Public acceptance to hydrogen is vulnerable to perceptions of decreased safety (E, NA). 8.Public acceptance to hydrogen is vulnerable to perceptions of increased cost (E, NA). The DOE surveys are similar to surveys that examine technical knowledge of hydrogen and fuel cell technologies, although the technical questions are certainly different. The DOE surveys are also similar to the opinion surveys in that they address many of the same issues, such as safety, sources of energy information, or trust. There are many differences between the surveys reviewed in this compendium and the DOE surveys. The

  16. Exergetic Aspects of Hydrogen Energy Systems—The Case Study of a Fuel Cell Bus

    Directory of Open Access Journals (Sweden)

    Evanthia A. Nanaki

    2017-02-01

    Full Text Available Electrifying transportation is a promising approach to alleviate climate change issues arising from increased emissions. This study examines a system for the production of hydrogen using renewable energy sources as well as its use in buses. The electricity requirements for the production of hydrogen through the electrolysis of water, are covered by renewable energy sources. Fuel cells are being used to utilize hydrogen to power the bus. Exergy analysis for the system is carried out. Based on a steady-state model of the processes, exergy efficiencies are calculated for all subsystems. The subsystems with the highest proportion of irreversibility are identified and compared. It is shown that PV panel has exergetic efficiency of 12.74%, wind turbine of 45%, electrolysis of 67%, and fuel cells of 40%.

  17. The hydrogen and the fuel cells in the world. Programs and evolutions; L'hydrogene et les piles a combustibles dans le monde. Programmes et evolutions

    Energy Technology Data Exchange (ETDEWEB)

    Lucchese, P. [CEA Saclay, Dir. des Nouvelles Technologies de l' Energie CEA, 91 - Gif-sur-Yvette (France)

    2008-07-01

    HyPac is a french platform on the hydrogen and fuel cells, created in 2008. The author presents the opportunity of such a platform facing the world research programs and other existing platforms. (A.L.B.)

  18. Dynamic behaviour of Li batteries in hydrogen fuel cell power trains

    Science.gov (United States)

    Veneri, O.; Migliardini, F.; Capasso, C.; Corbo, P.

    A Li ion polymer battery pack for road vehicles (48 V, 20 Ah) was tested by charging/discharging tests at different current values, in order to evaluate its performance in comparison with a conventional Pb acid battery pack. The comparative analysis was also performed integrating the two storage systems in a hydrogen fuel cell power train for moped applications. The propulsion system comprised a fuel cell generator based on a 2.5 kW polymeric electrolyte membrane (PEM) stack, fuelled with compressed hydrogen, an electric drive of 1.8 kW as nominal power, of the same typology of that installed on commercial electric scooters (brushless electric machine and controlled bidirectional inverter). The power train was characterized making use of a test bench able to simulate the vehicle behaviour and road characteristics on driving cycles with different acceleration/deceleration rates and lengths. The power flows between fuel cell system, electric energy storage system and electric drive during the different cycles were analyzed, evidencing the effect of high battery currents on the vehicle driving range. The use of Li batteries in the fuel cell power train, adopting a range extender configuration, determined a hydrogen consumption lower than the correspondent Pb battery/fuel cell hybrid vehicle, with a major flexibility in the power management.

  19. Experimental study of hydrogen as a fuel additive in internal combustion engines

    Energy Technology Data Exchange (ETDEWEB)

    Saanum, Inge

    2008-07-01

    Combustion of hydrocarbons in internal combustion engines results in emissions that can be harmful both to human health and to the environment. Although the engine technology is improving, the emissions of NO{sub x}, PM and UHC are still challenging. Besides, the overall consumption of fossil fuel and hence the emissions of CO{sub 2} are increasing because of the increasing number of vehicles. This has lead to a focus on finding alternative fuels and alternative technologies that may result in lower emissions of harmful gases and lower CO{sub 2} emissions. This thesis treats various topics that are relevant when using blends of fuels in different internal combustion engine technologies, with a particular focus on using hydrogen as a fuel additive. The topics addressed are especially the ones that impact the environment, such as emissions of harmful gases and thermal efficiency (fuel consumption). The thesis is based on experimental work performed at four different test rigs: 1. A dynamic combustion rig with optical access to the combustion chamber where spark ignited premixed combustion could be studied by means of a Schlieren optical setup and a high speed video camera. 2. A spark ignition natural gas engine rig with an optional exhaust gas recycling system. 3. A 1-cylinder diesel engine prepared for homogeneous charge compression ignition combustion. 4. A 6-cylinder standard diesel engine The engine rigs were equipped with cylinder pressure sensors, engine dynamometers, exhaust gas analyzers etc. to enable analyses of the effects of different fuels. The effect of hydrogen blended with methane and natural gas in spark ignited premixed combustion was investigated in the dynamic combustion rig and in a natural gas engine. In the dynamic combustion rig, the effect of hydrogen added to methane on the flame speed and the flame structure was investigated at elevated pressure and temperature. A considerable increase in the flame speed was observed when adding 30 vol

  20. Synthesis and characterization of light-metal-based hydrides for hydrogen storage materials

    Science.gov (United States)

    Choi, Young Joon

    In the past few years, research and development on the use of hydrogen as a fuel for various applications have gathered momentum in response to the demand for cleaner fuels and substitutes to fossil fuels. The use of hydrogen for automobiles, one of the most important applications of hydrogen fuel, requires an on-board hydrogen storage system that can be regenerated on-board or off-board. However, one of the key obstacles to this application is that current available storage technologies do not meet the capacity and efficiency requirements for achieving the commercial viability. In this study, two solid-state hydrogen storage systems, i.e. Mg-Ti-H and Li-Al-B-H, are investigated. Among a variety of MgH2/TiH2 ratios and milling conditions, the 10MgH2/TiH2 sample milled in a dual-planetary high-energy mill for 4 hours under 15 MPa hydrogen pressure were found to be the optimal materials, displaying a substantially reduced activation energy and enthalpy change for MgH2 dehydrogenation. PCT analysis demonstrated that the system showed excellent cycle stability attributed to the inhibition of coarsening by TiH2. Lithium borohydride (LiBH4) is one of the promising candidates as a superior hydrogen storage because of its high theoretical storage capacity (18.5 wt.%). In this work, the promising hydrogen storage properties of combined systems of Li3AlH6/LiBH4 and Al/LiBH 4, exhibiting the favorable formation of AlB2 during dehydrogenation, were presented based on TGA and XRD analyses. Additionally, the characterization of the intermediate and final products of the dehydrogenation and rehydrogenation of the above systems by solid-state NMR analyses were presented. This has verified and further clarified the paths and intermediate products of the reversible hydrogen release and uptake by the mixtures.

  1. Hydrogen Fueled Hybrid Solid Oxide Fuel Cell-Gas Turbine (SOFC-GT) System for Long-Haul Rail Application

    Science.gov (United States)

    Chow, Justin Jeff

    Freight movement of goods is the artery for America's economic health. Long-haul rail is the premier mode of transport on a ton-mile basis. Concerns regarding greenhouse gas and criteria pollutant emissions, however, have motivated the creation of annually increasing locomotive emissions standards. Health issues from diesel particulate matter, especially near rail yards, have also been on the rise. These factors and the potential to raise conventional diesel-electric locomotive performance warrants the investigation of using future fuels in a more efficient system for locomotive application. This research evaluates the dynamic performance of a Solid Oxide Fuel Cell-Gas Turbine (SOFC-GT) Hybrid system operating on hydrogen fuel to power a locomotive over a rail path starting from the Port of Los Angeles and ending in the City of Barstow. Physical constraints, representative locomotive operation logic, and basic design are used from a previous feasibility study and simulations are performed in the MATLAB Simulink environment. In-house controls are adapted to and expanded upon. Results indicate high fuel-to-electricity efficiencies of at least 54% compared to a conventional diesel-electric locomotive efficiency of 35%. Incorporation of properly calibrated feedback and feed-forward controls enables substantial load following of difficult transients that result from train kinematics while maintaining turbomachinery operating requirements and suppressing thermal stresses in the fuel cell stack. The power split between the SOFC and gas turbine is deduced to be a deterministic factor in the balance between capital and operational costs. Using hydrogen results in no emissions if renewable and offers a potential of 24.2% fuel energy savings for the rail industry.

  2. Light harvesting proteins for solar fuel generation in bioengineered photoelectrochemical cells.

    Science.gov (United States)

    Ihssen, Julian; Braun, Artur; Faccio, Greta; Gajda-Schrantz, Krisztina; Thöny-Meyer, Linda

    2014-01-01

    The sun is the primary energy source of our planet and potentially can supply all societies with more than just their basic energy needs. Demand of electric energy can be satisfied with photovoltaics, however the global demand for fuels is even higher. The direct way to produce the solar fuel hydrogen is by water splitting in photoelectrochemical (PEC) cells, an artificial mimic of photosynthesis. There is currently strong resurging interest for solar fuels produced by PEC cells, but some fundamental technological problems need to be solved to make PEC water splitting an economic, competitive alternative. One of the problems is to provide a low cost, high performing water oxidizing and oxygen evolving photoanode in an environmentally benign setting. Hematite, α-Fe2O3, satisfies many requirements for a good PEC photoanode, but its efficiency is insufficient in its pristine form. A promising strategy for enhancing photocurrent density takes advantage of photosynthetic proteins. In this paper we give an overview of how electrode surfaces in general and hematite photoanodes in particular can be functionalized with light harvesting proteins. Specifically, we demonstrate how low-cost biomaterials such as cyanobacterial phycocyanin and enzymatically produced melanin increase the overall performance of virtually no-cost metal oxide photoanodes in a PEC system. The implementation of biomaterials changes the overall nature of the photoanode assembly in a way that aggressive alkaline electrolytes such as concentrated KOH are not required anymore. Rather, a more environmentally benign and pH neutral electrolyte can be used.

  3. Study of the application of hydrogen fuel to long-range subsonic transport aircraft. Volume 1: Summary

    Science.gov (United States)

    Brewer, G. D.; Morris, R. E.; Lange, R. H.; Moore, J. W.

    1975-01-01

    The feasibility of using liquid hydrogen as fuel in advanced designs of long range, subsonic transport aircraft is assessed. Both passenger and cargo type aircraft are investigated. Comparisons of physical, performance, and economic parameters of the LH2 fueled designs with conventionally fueled aircraft are presented. Design studies are conducted to determine appropriate characteristics for the hydrogen related systems required on board the aircraft. These studies included consideration of material, structural, and thermodynamic requirements of the cryogenic fuel tanks and fuel systems with the structural support and thermal protection systems.

  4. Inverted Fuel Cell: Room-Temperature Hydrogen Separation from an Exhaust Gas by Using a Commercial Short-Circuited PEM Fuel Cell without Applying any Electrical Voltage.

    Science.gov (United States)

    Friebe, Sebastian; Geppert, Benjamin; Caro, Jürgen

    2015-06-26

    A short-circuited PEM fuel cell with a Nafion membrane has been evaluated in the room-temperature separation of hydrogen from exhaust gas streams. The separated hydrogen can be recovered or consumed in an in situ olefin hydrogenation when the fuel cell is operated as catalytic membrane reactor. Without applying an outer electrical voltage, there is a continuous hydrogen flux from the higher to the lower hydrogen partial pressure side through the Nafion membrane. On the feed side of the Nafion membrane, hydrogen is catalytically split into protons and electrons by the Pt/C electrocatalyst. The protons diffuse through the Nafion membrane, the electrons follow the short-circuit between the two brass current collectors. On the cathode side, protons and electrons recombine, and hydrogen is released. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Advanced Fuels Campaign Light Water Reactor Accident Tolerant Fuel Performance Metrics

    Energy Technology Data Exchange (ETDEWEB)

    Brad Merrill; Melissa Teague; Robert Youngblood; Larry Ott; Kevin Robb; Michael Todosow; Chris Stanek; Mitchell Farmer; Michael Billone; Robert Montgomery; Nicholas Brown; Shannon Bragg-Sitton

    2014-02-01

    The safe, reliable and economic operation of the nation’s nuclear power reactor fleet has always been a top priority for the United States’ nuclear industry. As a result, continual improvement of technology, including advanced materials and nuclear fuels, remains central to industry’s success. Decades of research combined with continual operation have produced steady advancements in technology and yielded an extensive base of data, experience, and knowledge on light water reactor (LWR) fuel performance under both normal and accident conditions. In 2011, following the Great East Japan Earthquake, resulting tsunami, and subsequent damage to the Fukushima Daiichi nuclear power plant complex, enhancing the accident tolerance of LWRs became a topic of serious discussion. As a result of direction from the U.S. Congress, the U.S. Department of Energy Office of Nuclear Energy (DOE-NE) initiated an Accident Tolerant Fuel (ATF) Development program. The complex multiphysics behavior of LWR nuclear fuel makes defining specific material or design improvements difficult; as such, establishing qualitative attributes is critical to guide the design and development of fuels and cladding with enhanced accident tolerance. This report summarizes a common set of technical evaluation metrics to aid in the optimization and down selection of candidate designs. As used herein, “metrics” describe a set of technical bases by which multiple concepts can be fairly evaluated against a common baseline and against one another. Furthermore, this report describes a proposed technical evaluation methodology that can be applied to assess the ability of each concept to meet performance and safety goals relative to the current UO2 – zirconium alloy system and relative to one another. The resultant ranked evaluation can then inform concept down-selection, such that the most promising accident tolerant fuel design option(s) can continue to be developed for lead test rod or lead test assembly

  6. An unexpected negative influence of light intensity on hydrogen production by dark fermentative bacteria Clostridium beijerinckii.

    Science.gov (United States)

    Zagrodnik, R; Laniecki, M

    2016-01-01

    The role of light intensity on biohydrogen production from glucose by Clostridium beijerinckii, Clostridium acetobutylicum, and Rhodobacter sphaeroides was studied to evaluate the performance and possible application in co-culture fermentation system. The applied source of light had spectrum similar to the solar radiation. The influence of light intensity on hydrogen production in dark process by C. acetobutylicum was negligible. In contrast, dark fermentation by C. beijerinckii bacteria showed a significant decrease (83%) in produced hydrogen at light intensity of 540W/m(2). Here, the redirection of metabolism from acetic and butyric acid formation towards lactic acid was observed. This not yet reported effect was probably caused by irradiation of these bacteria by light within UVA range, which is an important component of the solar radiation. The excessive illumination with light of intensity higher than 200W/m(2) resulted in decrease in hydrogen production with photofermentative bacteria as well. Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. UC Davis Fuel Cell, Hydrogen, and Hybrid Vehicle (FCH2V) GATE Center of Excellence

    Energy Technology Data Exchange (ETDEWEB)

    Erickson, Paul

    2012-05-31

    This is the final report of the UC Davis Fuel Cell, Hydrogen, and Hybrid Vehicle (FCH2V) GATE Center of Excellence which spanned from 2005-2012. The U.S. Department of Energy (DOE) established the Graduate Automotive Technology Education (GATE) Program, to provide a new generation of engineers and scientists with knowledge and skills to create advanced automotive technologies. The UC Davis Fuel Cell, Hydrogen, and Hybrid Vehicle (FCH2V) GATE Center of Excellence established in 2005 is focused on research, education, industrial collaboration and outreach within automotive technology. UC Davis has had two independent GATE centers with separate well-defined objectives and research programs from 1998. The Fuel Cell Center, administered by ITS-Davis, has focused on fuel cell technology. The Hybrid-Electric Vehicle Design Center (HEV Center), administered by the Department of Mechanical and Aeronautical Engineering, has focused on the development of plug-in hybrid technology using internal combustion engines. The merger of these two centers in 2005 has broadened the scope of research and lead to higher visibility of the activity. UC Davis's existing GATE centers have become the campus's research focal points on fuel cells and hybrid-electric vehicles, and the home for graduate students who are studying advanced automotive technologies. The centers have been highly successful in attracting, training, and placing top-notch students into fuel cell and hybrid programs in both industry and government.

  8. Fuel Cell Development for NASA's Human Exploration Program: Benchmarking with "The Hydrogen Economy"

    Science.gov (United States)

    Scott, John H.

    2007-01-01

    The theoretically high efficiency and low temperature operation of hydrogen-oxygen fuel cells has motivated them to be the subject of much study since their invention in the 19th Century, but their relatively high life cycle costs kept them as a "solution in search of a problem" for many years. The first problem for which fuel cells presented a truly cost effective solution was that of providing a power source for NASA's human spaceflight vehicles in the 1960 s. NASA thus invested, and continues to invest, in the development of fuel cell power plants for this application. This development program continues to place its highest priorities on requirements for minimum system mass and maximum durability and reliability. These priorities drive fuel cell power plant design decisions at all levels, even that of catalyst support. However, since the mid-1990's, prospective environmental regulations have driven increased governmental and industrial interest in "green power" and the "Hydrogen Economy." This has in turn stimulated greatly increased investment in fuel cell development for a variety of commercial applications. This investment is bringing about notable advances in fuel cell technology, but, as these development efforts place their highest priority on requirements for minimum life cycle cost and field safety, these advances are yielding design solutions quite different at almost every level from those needed for spacecraft applications. This environment thus presents both opportunities and challenges for NASA's Human Exploration Program

  9. Hydrodesulphurization of Light Gas Oil using hydrogen from the Water Gas Shift Reaction

    Science.gov (United States)

    Alghamdi, Abdulaziz

    2009-12-01

    The production of clean fuel faces the challenges of high production cost and complying with stricter environmental regulations. In this research, the ability of using a novel technology of upgrading heavy oil to treat Light Gas Oil (LGO) will be investigated. The target of this project is to produce cleaner transportation fuel with much lower cost of production. Recently, a novel process for upgrading of heavy oil has been developed at University of Waterloo. It is combining the two essential processes in bitumen upgrading; emulsion breaking and hydroprocessing into one process. The water in the emulsion is used to generate in situ hydrogen from the Water Gas Shift Reaction (WGSR). This hydrogen can be used for the hydrogenation and hydrotreating reaction which includes sulfur removal instead of the expensive molecular hydrogen. This process can be carried out for the upgrading of the bitumen emulsion which would improve its quality. In this study, the hydrodesulphurization (HDS) of LGO was conducted using in situ hydrogen produced via the Water Gas Shift Reaction (WGSR). The main objective of this experimental study is to evaluate the possibility of producing clean LGO over dispersed molybdenum sulphide catalyst and to evaluate the effect of different promoters and syn-gas on the activity of the dispersed Mo catalyst. Experiments were carried out in a 300 ml Autoclave batch reactor under 600 psi (initially) at 391°C for 1 to 3 hours and different amounts of water. After the hydrotreating reaction, the gas samples were collected and the conversion of carbon monoxide to hydrogen via WGSR was determined using a refinery gas analyzer. The sulphur content in liquid sample was analyzed via X-Ray Fluorescence. Experimental results showed that using more water will enhance WGSR but at the same time inhibits the HDS reaction. It was also shown that the amount of sulfur removed depends on the reaction time. The plan is to investigate the effect of synthesis gas (syngas

  10. Coupling a PEM fuel cell and the hydrogen generation from aluminum waste cans

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, Susana Silva; Albanil Sanchez, Loyda; Alvarez Gallegos, Alberto A. [Centro de Investigacion en Ingenieria y Ciencias Aplicadas, Av. Universidad 1001, Col. Chamilpa, Cuernavaca, Mor. CP 62210 (Mexico); Sebastian, P.J. [Centro de Investigacion en Energia-UNAM, 62580 Temixco, Morelos (Mexico); Cuerpo Academico de Energia y Sustentabilidad, UPCH, Tuxtla Gutierrez, Chiapas (Mexico)

    2007-10-15

    High purity hydrogen was generated from the chemical reaction of aluminum and sodium hydroxide. The aluminum used in this study was obtained from empty soft drink cans and treated with concentrated sulfuric acid to remove the paint and plastic film. One gram of aluminum was reacted with a solution of 2moldm{sup -3} of sodium hydroxide to produce hydrogen. The hydrogen produced from aluminum cans and oxygen obtained from a proton exchange membrane electrolyzer or air, was fed to a proton exchange membrane (PEM) fuel cell to produce electricity. Yields of 44 mmol of hydrogen contained in a volume of 1.760dm{sup 3} were produced from one gram of aluminum in a time period of 20 min. (author)

  11. ENHANCED HYDROGEN ECONOMICS VIA COPRODUCTION OF FUELS AND CARBON PRODUCTS

    Energy Technology Data Exchange (ETDEWEB)

    Kennel, Elliot B; Bhagavatula, Abhijit; Dadyburjor, Dady; Dixit, Santhoshi; Garlapalli, Ravinder; Magean, Liviu; Mukkha, Mayuri; Olajide, Olufemi A; Stiller, Alfred H; Yurchick, Christopher L

    2011-03-31

    This Department of Energy National Energy Technology Laboratory sponsored research effort to develop environmentally cleaner projects as a spin-off of the FutureGen project, which seeks to reduce or eliminate emissions from plants that utilize coal for power or hydrogen production. New clean coal conversion processes were designed and tested for coproducing clean pitches and cokes used in the metals industry as well as a heavy crude oil. These new processes were based on direct liquefaction and pyrolysis techniques that liberate volatile liquids from coal without the need for high pressure or on-site gaseous hydrogen. As a result of the research, a commercial scale plant for the production of synthetic foundry coke has broken ground near Wise, Virginia under the auspices of Carbonite Inc. This plant will produce foundry coke by pyrolyzing a blend of steam coal feedstocks. A second plant is planned by Quantex Energy Inc (in Texas) which will use solvent extraction to coproduce a coke residue as well as crude oil. A third plant is being actively considered for Kingsport, Tennessee, pending a favorable resolution of regulatory issues.

  12. Electrocatalyst advances for hydrogen oxidation in phosphoric acid fuel cells

    Science.gov (United States)

    Stonehart, P.

    1984-01-01

    The important considerations that presently exist for achieving commercial acceptance of fuel cells are centered on cost (which translates to efficiency) and lifetime. This paper addresses the questions of electrocatalyst utilization within porous electrode structures and the preparation of low-cost noble metal electrocatalyst combinations with extreme dispersions of the metal. Now that electrocatalyst particles can be prepared with dimensions of 10 A, either singly or in alloy combinations, a very large percentage of the noble metal atoms in a crystallite are available for reaction. The cost savings for such electrocatalysts in the present commercially driven environment are considerable.

  13. Radiation heat transfer calculations for the uranium fuel-containment region of the nuclear light bulb engine.

    Science.gov (United States)

    Rodgers, R. J.; Latham, T. S.; Krascella, N. L.

    1971-01-01

    Calculation results are reviewed of the radiant heat transfer characteristics in the fuel and buffer gas regions of a nuclear light bulb engine based on the transfer of energy by thermal radiation from gaseous uranium fuel in a neon vortex, through an internally cooled transparent wall, to seeded hydrogen propellant. The results indicate that the fraction of UV energy incident on the transparent walls increases with increasing power level. For the reference engine power level of 4600 megw, it is necessary to employ space radiators to reject the UV radiated energy absorbed by the transparent walls. This UV energy can be blocked by employing nitric oxide and oxygen seed gases in the fuel and buffer gas regions. However, this results in increased UV absorption in the buffer gas which also requires space radiators to reject the heat load.

  14. Nano-ferrites for water splitting: Unprecedented high photocatalytic hydrogen production under visible light

    KAUST Repository

    Mangrulkar, Priti A.

    2012-01-01

    In the present investigation, hydrogen production via water splitting by nano-ferrites was studied using ethanol as the sacrificial donor and Pt as co-catalyst. Nano-ferrite is emerging as a promising photocatalyst with a hydrogen evolution rate of 8.275 μmol h -1 and a hydrogen yield of 8275 μmol h -1 g -1 under visible light compared to 0.0046 μmol h -1 for commercial iron oxide (tested under similar experimental conditions). Nano-ferrites were tested in three different photoreactor configurations. The rate of hydrogen evolution by nano-ferrite was significantly influenced by the photoreactor configuration. Altering the reactor configuration led to sevenfold (59.55 μmol h -1) increase in the hydrogen evolution rate. Nano-ferrites have shown remarkable stability in hydrogen production up to 30 h and the cumulative hydrogen evolution rate was observed to be 98.79 μmol h -1. The hydrogen yield was seen to be influenced by several factors like photocatalyst dose, illumination intensity, irradiation time, sacrificial donor and presence of co-catalyst. These were then investigated in detail. It was evident from the experimental data that nano-ferrites under optimized reaction conditions and photoreactor configuration could lead to remarkable hydrogen evolution activity under visible light. Temperature had a significant role in enhancing the hydrogen yield. © 2012 The Royal Society of Chemistry.

  15. Literature search on Light Water Reactor (LWR) fuel and absorber rod fabrication, 1960--1976

    Energy Technology Data Exchange (ETDEWEB)

    Sample, C R [comp.

    1977-02-01

    A literature search was conducted to provide information supporting the design of a conceptual Light Water Reactor (LWR) Fuel Fabrication plant. Emphasis was placed on fuel processing and pin bundle fabrication, effects of fuel impurities and microstructure on performance and densification, quality assurance, absorber and poison rod fabrication, and fuel pin welding. All data have been taken from publicly available documents, journals, and books. This work was sponsored by the Finishing Processes-Mixed Oxide (MOX) Fuel Fabrication Studies program at HEDL.

  16. Polygeneration-IGCC concepts for the production of hydrogen rich fuels based on lignite

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, Bernd; Ogriseck, Katrin

    2007-08-15

    This paper presents three IGCC-power plant concepts for central production of a hydrogen-rich fuel (methanol, hydrogen, synthetic natural gas SNG) from lignite. Each concept contains a CO{sub 2} separation, which produces a sequestration-ready CO{sub 2} rich stream. Thus, CO{sub 2} emissions caused by use of lignite are considerably reduced. Furthermore, the produced low-carbon fuels are converted in decentralised Combined Heat and Power Plants (CHPP). CHPP leads to high efficiencies of fuel utilisation between 54 and 62%, which exceed the efficiencies of single power generation. Regarding to the CO{sub 2} emissions of a natural gas fired CHPP, heat and power can be generated by lignite as clean as by natural gas. The specific CO{sub 2} emissions are even much lower in the case of hydrogen production. Costs for the centrally produced methanol and hydrogen are with 29 and 19 EUR/MWh(LHV) already within an economic range. Synthetic natural gas can be produced for 23 EUR/MWh (LHV).

  17. Hydrogen and electricity production from a food processing wastewater using fermentation and microbial fuel cell technologies.

    Science.gov (United States)

    Oh, Sang Eun; Logan, Bruce E

    2005-11-01

    Hydrogen can be produced from fermentation of sugars in wastewaters, but much of the organic matter remains in solution. We demonstrate here that hydrogen production from a food processing wastewater high in sugar can be linked to electricity generation using a microbial fuel cell (MFC) to achieve more effective wastewater treatment. Grab samples were taken from: plant effluent at two different times during the day (Effluents 1 and 2; 735+/-15 and 3250+/-90 mg-COD/L), an equalization tank (Lagoon; 1670+/-50mg-COD/L), and waste stream containing a high concentration of organic matter (Cereal; 8920+/-150 mg-COD/L). Hydrogen production from the Lagoon and effluent samples was low, with 64+/-16 mL of hydrogen per liter of wastewater (mL/L) for Effluent 1, 21+/-18 mL/L for Effluent 2, and 16+/-2 mL/L for the Lagoon sample. There was substantially greater hydrogen production using the Cereal wastewater (210+/-56 mL/L). Assuming a theoretical maximum yield of 4 mol of hydrogen per mol of glucose, hydrogen yields were 0.61-0.79 mol/mol for the Cereal wastewater, and ranged from 1 to 2.52 mol/mol for the other samples. This suggests a strategy for hydrogen recovery from wastewater based on targeting high-COD and high-sugar wastewaters, recognizing that sugar content alone is an insufficient predictor of hydrogen yields. Preliminary tests with the Cereal wastewater (diluted to 595 mg-COD/L) in a two-chambered MFC demonstrated a maximum of 81+/-7 mW/m(2) (normalized to the anode surface area), or 25+/-2 mA per liter of wastewater, and a final COD of hydrogen production and electricity producing using MFCs in order to achieve both wastewater treatment and bioenergy production.

  18. High Efficiency Generation of Hydrogen Fuels using Nuclear Power Annual Report August, 2000 - July 2001

    Energy Technology Data Exchange (ETDEWEB)

    Brown, L.C.

    2002-11-01

    OAK B188 High Efficiency Generation of Hydrogen Fuels using Nuclear Power Annual Report August 2000 - July 2001. Currently no large scale, cost-effective, environmentally attractive hydrogen production process is available for commercialization nor has such a process been identified. Hydrogen is a promising energy carrier, which potentially could replace the fossil fuels used in the transportation sector of our economy. Carbon dioxide emissions from fossil fuel combustion are thought to be responsible for global warming. The purpose of this work is to determine the potential for efficient, cost-effective, large-scale production of hydrogen utilizing high temperature heat from an advanced nuclear power station. The benefits of this work will include the generation of a low-polluting transportable energy feedstock in an efficient method that has little or no implication for greenhouse gas emissions from a primary energy source whose availability and sources are domestically controlled. This will help to ensure energy for a future transportation/energy infrastructure that is not influenced/controlled by foreign governments. This report describes work accomplished during the second year (Phase 2) of a three year project whose objective is to ''define an economically feasible concept for production of hydrogen, by nuclear means, using an advanced high temperature nuclear reactor as the energy source.'' The emphasis of the first year (Phase 1) was to evaluate thermochemical processes which offer the potential for efficient, cost-effective, large-scale production of hydrogen from water, in which the primary energy input is high temperature heat from an advanced nuclear reactor and to select one (or, at most, three) for further detailed consideration. Phase 1 met its goals and did select one process, the sulfur-iodine process, for investigation in Phases 2 and 3. The combined goals of Phases 2 and 3 were to select the advanced nuclear reactor best

  19. Vortex combustor for low NOX emissions when burning lean premixed high hydrogen content fuel

    Science.gov (United States)

    Steele, Robert C; Edmonds, Ryan G; Williams, Joseph T; Baldwin, Stephen P

    2012-11-20

    A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

  20. Separation of gaseous hydrogen from a water-hydrogen mixture in a fuel cell power system operating in a weightless environment

    Science.gov (United States)

    Romanowski, William E. (Inventor); Suljak, George T. (Inventor)

    1989-01-01

    A fuel cell power system for use in a weightless environment, such as in space, includes a device for removing water from a water-hydrogen mixture condensed from the exhaust from the fuel cell power section of the system. Water is removed from the mixture in a centrifugal separator, and is fed into a holding, pressure operated water discharge valve via a Pitot tube. Entrained nondissolved hydrogen is removed from the Pitot tube by a bleed orifice in the Pitot tube before the water reaches the water discharge valve. Water discharged from the valve thus has a substantially reduced hydrogen content.

  1. Reversible transient hydrogen storage in a fuel cell-supercapacitor hybrid device.

    Science.gov (United States)

    Unda, Jesus E Zerpa; Roduner, Emil

    2012-03-21

    A new concept is investigated for hydrogen storage in a supercapacitor based on large-surface-area carbon material (Black Pearls 2000). Protons and electrons of hydrogen are separated on a fuel cell-type electrode and then stored separately in the electrical double layer, the electrons on the carbon and the protons in the aqueous electrolyte of the supercapacitor electrode. The merit of this concept is that it works spontaneously and reversibly near ambient pressure and temperature. This is in pronounced contrast to what has been known as electrochemical hydrogen storage, which does not involve hydrogen gas and where electrical work has to be spent in the loading process. With the present hybrid device, a H(2) storage capacity of 0.13 wt% was obtained, one order of magnitude more than what can be stored by conventional physisorption on large-surface-area carbons at the same pressure and temperature. Raising the pressure from 1.5 to 3.5 bar increased the capacity by less than 20%, indicating saturation. A capacitance of 11 μF cm(-2), comparable with that of a commercial double layer supercapacitor, was found using H(2)SO(4) as electrolyte. The chemical energy of the stored H(2) is almost a factor of 3 larger than the electrical energy stored in the supercapacitor. Further developments of this concept relate to a hydrogen buffer integrated inside a proton exchange membrane fuel cell to be used in case of peak power demand. This serial setup takes advantage of the suggested novel concept of hydrogen storage. It is fundamentally different from previous ways of operating a conventional supercapacitor hooked up in parallel to a fuel cell.

  2. American Recovery & Reinvestment Act: Fuel Cell Hybrid Power Packs and Hydrogen Refueling for Lift Trucks

    Energy Technology Data Exchange (ETDEWEB)

    Block, Gus

    2011-07-31

    HEB Grocery Company, Inc. (H-E-B) is a privately-held supermarket chain with 310 stores throughout Texas and northern Mexico. H-E-B converted 14 of its lift reach trucks to fuel cell power using Nuvera Fuel Cells’ PowerEdge™ units to verify the value proposition and environmental benefits associated with the technology. Issues associated with the increasing power requirements of the distribution center operation, along with high ambient temperature in the summer and other operating conditions (such as air quality and floor surface condition), surfaced opportunities for improving Nuvera’s PowerEdge fuel cell system design in high-throughput forklift environments. The project included on-site generation of hydrogen from a steam methane reformer, called PowerTap™ manufactured by Nuvera. The hydrogen was generated, compressed and stored in equipment located outside H-E-B’s facility, and provided to the forklifts by hydrogen dispensers located in high forklift traffic areas. The PowerEdge fuel cell units logged over 25,300 operating hours over the course of the two-year project period. The PowerTap hydrogen generator produced more than 11,100 kg of hydrogen over the same period. Hydrogen availability at the pump was 99.9%. H-E-B management has determined that fuel cell forklifts help alleviate several issues in its distribution centers, including truck operator downtime associated with battery changing, truck and battery maintenance costs, and reduction of grid electricity usage. Data collected from this initial installation demonstrated a 10% productivity improvement, which enabled H-E-B to make economic decisions on expanding the fleet of PowerEdge and PowerTap units in the fleet, which it plans to undertake upon successful demonstration of the new PowerEdge reach truck product. H-E-B has also expressed interst in other uses of hydrogen produced on site in the future, such as for APUs used in tractor trailers and refrigerated transport trucks in its fleet.

  3. Hydrogen assisted catalytic biomass pyrolysis for green fuels

    DEFF Research Database (Denmark)

    Stummann, Magnus Zingler; Høj, Martin; Schandel, Christian Bækhøj

    Fast pyrolysis of biomass is a well-known technology for producing bio-oil, however in order to use the oil as transportation fuel the oxygen content must be decreased from approximately 30 wt.% to below 1 wt.%. This can be achieved by catalytic hydrodeoxygenation (HDO). Unfortunately, deactivation...... in a fluid bed reactor with a commercial CoMoS/MgAl2O4 catalyst as bed medium followed by an additional vapor phase, fixed bed HDO reactor using a commercial NiMoS/Al2O3 catalyst .The obtained bio-oil is essentially oxygen free. Oxygen specific GC-AED showed only traces of phenols, benzofurans and napthols...

  4. Evaluation of Lighting Systems, Carbon Sources, and Bacteria Cultures on Photofermentative Hydrogen Production.

    Science.gov (United States)

    Hu, Chengcheng; Choy, Sing-Ying; Giannis, Apostolos

    2017-11-10

    Fluorescent and incandescent lighting systems were applied for batch photofermentative hydrogen production by four purple non-sulfur photosynthetic bacteria (PNSB). The hydrogen production efficiency of Rhodopseudomonas palustris, Rhodobacter sphaeroides, Rhodobacter capsulatus, and Rhodospirillum rubrum was evaluated using different carbon sources (acetate, butyrate, lactate, and malate). Incandescent light was found to be more effective for bacteria cell growth and hydrogen production. It was observed that PNSB followed substrate selection criteria for hydrogen production. Only R. palustris was able to produce hydrogen using most carbon sources. Cell density was almost constant, but cell growth rate and hydrogen production were significantly varied under the different lighting systems. The kinetics study suggested that initial substrate concentration had a positive correlation with lag phase duration. Among the PNSB, R. palustris grew faster and had higher hydrogen yields of 1.58, 4.92, and 2.57 mol H2/mol using acetate, butyrate, and lactate, respectively. In the integrative approach with dark fermentation effluents rich in organic acids, R. palustris should be enriched in the phototrophic microbial consortium of the continuous hydrogen production system.

  5. Fuel Summary Report: Shippingport Light Water Breeder Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Illum, D.B.; Olson, G.L.; McCardell, R.K.

    1999-01-01

    The Shippingport Light Water Breeder Reactor (LWBR) was a small water cooled, U-233/Th-232 cycle breeder reactor developed by the Pittsburgh Naval Reactors to improve utilization of the nation's nuclear fuel resources in light water reactors. The LWBR was operated at Shippingport Atomic Power Station (APS), which was a Department of Energy (DOE) (formerly Atomic Energy Commission)-owned reactor plant. Shippingport APS was the first large-scale, central-station nuclear power plant in the United States and the first plant of such size in the world operated solely to produce electric power. The Shippingport LWBR was operated successfully from 1977 to 1982 at the APS. During the five years of operation, the LWBR generated more than 29,000 effective full power hours (EFPH) of energy. After final shutdown, the 39 core modules of the LWBR were shipped to the Expended Core Facility (ECF) at Naval Reactors Facility at the Idaho National Engineering and Environmental Laboratory (INEEL). At ECF, 12 of the 39 modules were dismantled and about 1000 of more than 17,000 rods were removed from the modules of proof-of-breeding and fuel performance testing. Some of the removed rods were kept at ECF, some were sent to Argonne National Laboratory-West (ANL-W) in Idaho and some to ANL-East in Chicago for a variety of physical, chemical and radiological examinations. All rods and rod sections remaining after the experiments were shipped back to ECF, where modules and loose rods were repackaged in liners for dry storage. In a series of shipments, the liners were transported from ECF to Idaho Nuclear Technology Engineering Center (INTEC), formerly the Idaho Chemical Processing Plant (ICPP). The 47 liners containing the fully-rodded and partially-derodded core modules, the loose rods, and the rod scraps, are now stored in underground dry wells at CPP-749.

  6. Seawater usable for production and consumption of hydrogen peroxide as a solar fuel.

    Science.gov (United States)

    Mase, Kentaro; Yoneda, Masaki; Yamada, Yusuke; Fukuzumi, Shunichi

    2016-05-04

    Hydrogen peroxide (H2O2) in water has been proposed as a promising solar fuel instead of gaseous hydrogen because of advantages on easy storage and high energy density, being used as a fuel of a one-compartment H2O2 fuel cell for producing electricity on demand with emitting only dioxygen (O2) and water. It is highly desired to utilize the most earth-abundant seawater instead of precious pure water for the practical use of H2O2 as a solar fuel. Here we have achieved efficient photocatalytic production of H2O2 from the most earth-abundant seawater instead of precious pure water and O2 in a two-compartment photoelectrochemical cell using WO3 as a photocatalyst for water oxidation and a cobalt complex supported on a glassy-carbon substrate for the selective two-electron reduction of O2. The concentration of H2O2 produced in seawater reached 48 mM, which was high enough to operate an H2O2 fuel cell.

  7. High Efficiency Generation of Hydrogen Fuels Using Solar Thermochemical Splitting of Water

    Energy Technology Data Exchange (ETDEWEB)

    Heske, Clemens; Moujaes, Samir; Weimer, Alan; Wong, Bunsen; Siegal, Nathan; McFarland, Eric; Miller, Eric; Lewis, Michele; Bingham, Carl; Roth, Kurth; Sabacky, Bruce; Steinfeld, Aldo

    2011-09-29

    The objective of this work is to identify economically feasible concepts for the production of hydrogen from water using solar energy. The ultimate project objective was to select one or more competitive concepts for pilot-scale demonstration using concentrated solar energy. Results of pilot scale plant performance would be used as foundation for seeking public and private resources for full-scale plant development and testing. Economical success in this venture would afford the public with a renewable and limitless source of energy carrier for use in electric power load-leveling and as a carbon-free transportation fuel. The Solar Hydrogen Generation Research (SHGR) project embraces technologies relevant to hydrogen research under the Office of Hydrogen Fuel Cells and Infrastructure Technology (HFCIT) as well as concentrated solar power under the Office of Solar Energy Technologies (SET). Although the photoelectrochemical work is aligned with HFCIT, some of the technologies in this effort are also consistent with the skills and technologies found in concentrated solar power and photovoltaic technology under the Office of Solar Energy Technologies (SET). Hydrogen production by thermo-chemical water-splitting is a chemical process that accomplishes the decomposition of water into hydrogen and oxygen using only heat or a combination of heat and electrolysis instead of pure electrolysis and meets the goals for hydrogen production using only water and renewable solar energy as feed-stocks. Photoelectrochemical hydrogen production also meets these goals by implementing photo-electrolysis at the surface of a semiconductor in contact with an electrolyte with bias provided by a photovoltaic source. Here, water splitting is a photo-electrolytic process in which hydrogen is produced using only solar photons and water as feed-stocks. The thermochemical hydrogen task engendered formal collaborations among two universities, three national laboratories and two private sector

  8. Development and validation of purged thermal protection systems for liquid hydrogen fuel tanks of hypersonic vehicles

    Science.gov (United States)

    Helenbrook, R. D.; Colt, J. Z.

    1977-01-01

    An economical, lightweight, safe, efficient, reliable, and reusable insulation system was developed for hypersonic cruise vehicle hydrogen fuel tanks. Results indicate that, a nitrogen purged, layered insulation system with nonpermeable closed-cell insulation next to the cryogenic tank and a high service temperature fibrous insulation surrounding it, is potentially an attractive solution to the insulation problem. For the postulated hypersonic flight the average unit weight of the purged insulation system (including insulation, condensate and fuel boil off) is 6.31 kg/sq m (1.29 psf). Limited cyclic tests of large specimens of closed cell polymethacrylimide foam indicate it will withstand the expected thermal cycle.

  9. Hydrogen from reformer gas a novel fuel and bridging technology: A combustion perspective

    Energy Technology Data Exchange (ETDEWEB)

    Han, P.; Checkel, M.D.; Fleck, B.A. [Department of Mechanical Engineering, University of Alberta, Edmonton (Canada)

    2007-07-15

    Constant-volume combustion experiments measuring laminar burning velocity are presented for combinations of methane, inert diluent and H{sub 2}/CO mixtures that would result from steam reforming of methane. The experiments illustrate the very attractive prospects of on-board steam reforming in natural gas powered vehicles that would employ exhaust gas recirculation (EGR) to improve combustion performance and reduce NO{sub x} emissions. Laminar burning velocity in the partially reformed fuel stream can be maintained at levels similar to that of air/natural gas mixtures by increasing the prereforming of the fuel at increasing concentrations of EGR. Up to 40% dilution was tested, requiring that 53% of the methane fuel be reformed to maintain burning velocity. Calculations indicate NO{sub x} levels are similar to scenarios with unreformed fuel. The knowledge base from this and similar experiments is required to allow for the future adoption of on-board fuel reforming in IC engines. This is a critical intermediate step in introducing hydrogen as a fuel to the currently fossil-hydrocarbon oriented economy and fuel delivery infrastructure. (author)

  10. Mobile lighting apparatus

    Science.gov (United States)

    Roe, George Michael; Klebanoff, Leonard Elliott; Rea, Gerald W; Drake, Robert A; Johnson, Terry A; Wingert, Steven John; Damberger, Thomas A; Skradski, Thomas J; Radley, Christopher James; Oros, James M; Schuttinger, Paul G; Grupp, David J; Prey, Stephen Carl

    2013-05-14

    A mobile lighting apparatus includes a portable frame such as a moveable trailer or skid having a light tower thereon. The light tower is moveable from a stowed position to a deployed position. A hydrogen-powered fuel cell is located on the portable frame to provide electrical power to an array of the energy efficient lights located on the light tower.

  11. Hydrogen Solubility in Pr-doped and Un-doped YSZ for One Chamber Fuel Cell

    DEFF Research Database (Denmark)

    Bay, Lasse; Horita, T.; Sakai, N.

    1998-01-01

    Yttria-stabilised zirconia electrolytes (YSZ and Pr-doped YSZ) and yttria-doped strontium cerate (SYC) were tested in a one chamber fuel cell fed with a mixture of methane and air at 1223 K. The obtained performances were 4 mW cm(-2), 3 mW cm(-2), 2.5 mW cm(-2), and 0.15 mW cm(-2) for SYC, 1.8 mol...... SIMS analysis. Doping of Pr in the YSZ resulted in a higher intensity of the D ion, which indicated that hydrogen solubility was raised by the doping. The solubility of hydrogen in the electrolyte may affect the performance of one chamber fuel cells. (C) 1998 Elsevier Science B.V. All rights reserved....

  12. Performance of electric forklift with low-temperature polymer exchange membrane fuel cell power module and metal hydride hydrogen storage extension tank

    Science.gov (United States)

    Lototskyy, Mykhaylo V.; Tolj, Ivan; Parsons, Adrian; Smith, Fahmida; Sita, Cordellia; Linkov, Vladimir

    2016-06-01

    We present test results of a commercial 3-tonne electric forklift (STILL) equipped with a commercial fuel cell power module (Plug Power) and a MH hydrogen storage tank (HySA Systems and TF Design). The tests included: (i) performance evaluation of "hybrid" hydrogen storage system during refuelling at low (forklift performances during heavy-duty operation when changing the powering in the series: standard battery - fuel cell power module (alone) - power module with integrated MH tank; and (iii) performance tests of the forklift during its operation under working conditions. It was found that (a) the forklift with power module and MH tank can achieve 83% of maximum hydrogen storage capacity during 6 min refuelling (for full capacity 12-15 min); (b) heavy-duty operation of the forklift is characterised by 25% increase in energy consumption, and during system operation more uniform power distribution occurs when operating in the fuel cell powering mode with MH, in comparison to the battery powering mode; (c) use of the fully refuelled fuel cell power module with the MH extension tank allows for uninterrupted operation for 3 h 6 min and 7 h 15 min, for heavy- and light-duty operation, respectively.

  13. Large scale experiments simulating hydrogen distribution in a spent fuel pool building during a hypothetical fuel uncovery accident scenario

    Energy Technology Data Exchange (ETDEWEB)

    Mignot, Guillaume; Paranjape, Sidharth; Paladino, Domenico; Jaeckel, Bernd; Rydl, Adolf [Paul Scherrer Institute, Villigen (Switzerland)

    2016-08-15

    Following the Fukushima accident and its extended station blackout, attention was brought to the importance of the spent fuel pools' (SFPs) behavior in case of a prolonged loss of the cooling system. Since then, many analytical works have been performed to estimate the timing of hypothetical fuel uncovery for various SFP types. Experimentally, however, little was done to investigate issues related to the formation of a flammable gas mixture, distribution, and stratification in the SFP building itself and to some extent assess the capability for the code to correctly predict it. This paper presents the main outcomes of the Experiments on Spent Fuel Pool (ESFP) project carried out under the auspices of Swissnuclear (Framework 2012–2013) in the PANDA facility at the Paul Scherrer Institut in Switzerland. It consists of an experimental investigation focused on hydrogen concentration build-up into a SFP building during a predefined scaled scenario for different venting positions. Tests follow a two-phase scenario. Initially steam is released to mimic the boiling of the pool followed by a helium/steam mixture release to simulate the deterioration of the oxidizing spent fuel. Results shows that while the SFP building would mainly be inerted by the presence of a high concentration of steam, the volume located below the level of the pool in adjacent rooms would maintain a high air content. The interface of the two-gas mixture presents the highest risk of flammability. Additionally, it was observed that the gas mixture could become stagnant leading locally to high hydrogen concentration while steam condenses. Overall, the experiments provide relevant information for the potentially hazardous gas distribution formed in the SFP building and hints on accident management and on eventual retrofitting measures to be implemented in the SFP building.

  14. Performance of a short combustor at high altitudes using hydrogen fuel

    Science.gov (United States)

    Sivo, Joseph N; Fenn, David B

    1956-01-01

    Performance characteristics of a 16-inch annular-type combustor installed in a full-scale engine using gaseous-hydrogen fuel were obtained at simulated altitudes from 66,000 to 86,000 feet at a flight Mach number of 0.8. Combustion efficiencies of 86 percent were obtained at 86,000 feet (combustor pressure, 420 lb/sq ft abs). Combustor blowout was not encountered during the investigation.

  15. Effect of Hydrogen and Hydrogen Enriched Compressed Natural Gas Induction on the Performance of Rubber Seed Oil Methy Ester Fuelled Common Rail Direct Injection (CRDi Dual Fuel Engines

    Directory of Open Access Journals (Sweden)

    Mallikarjun Bhovi

    2017-06-01

    Full Text Available Renewable fuels are in biodegradable nature and they tender good energy security and foreign exchange savings. In addition they address environmental concerns and socio-economic issues. The present work presents the experimental investigations carried out on the utilization of such renewable fuel combinations for diesel engine applications. For this a single-cylinder four-stroke water cooled direct injection (DI compression ignition (CI engine provided with CMFIS (Conventional Mechanical Fuel Injection System was rightfully converted to operate with CRDi injection systems enabling high pressure injection of Rubber seed oil methyl ester (RuOME in the dual fuel mode with induction of varied gas flow rates of hydrogen and hydrogen enriched CNG (HCNG gas combinations. Experimental investigations showed a considerable improvement in dual fuel engine performance with acceptable brake thermal efficiency and reduced emissions of smoke, hydrocarbon (HC, carbon monoxide (CO and slightly increased nitric oxide (NOx emission levels for increased hydrogen and HCNG flow rates. Further CRDi facilitated dual fuel engine showed improved engine performance compared to CMFIS as the former enabled high pressure (900 bar injection of the RuOME and closer to TDC (Top Dead Centre as well. Combustion parameters such as ignition delay, combustion duration, pressure-crank angle and heat release rates were analyzed and compared with baseline data generated. Combustion analysis showed that the rapid rate of burning of hydrogen and HCNG along with air mixtures increased due to presence of hydrogen in total and in partial combination with CNG which further resulted into higher cylinder pressures and energy release rates. However, sustained research that can provide feasible engine technology operating on such fuels in dual fuel operation can pave the way for continued fossil fuel usage.

  16. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2004-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  17. A study of hydrogen isotopes fuel control by wall effect in magnetic fusion devices

    Energy Technology Data Exchange (ETDEWEB)

    Motevalli, S.M., E-mail: motavali@umz.ac.ir; Safari, M.

    2016-11-15

    Highlights: • A particle balance model for the main plasma and wall inventory in magnetic fusion device has been represented. • The dependence of incident particles energy on the wall has been considered in 10–300 eV for the sputtering yield and recycling coefficient. • The effect of fueling methods on plasma density behavior has been studied. - Abstract: Determination of plasma density behavior in magnetic confinement system needs to study the plasma materials interaction in the facing components such as first wall, limiter and divertor. Recycling of hydrogen isotope is an effective parameter in plasma density rate and plasma fueling. Recycling coefficient over the long pulse operation, gets to the unity, so it has a significant effect on steady state in magnetic fusion devices. Typically, sputtered carbon atoms from the plasma facing components form hydrocarbons and they redeposit on the wall. In this case little rate of hydrogen loss occurs. In present work a zero dimensional particle equilibrium model has been represented to determine particles density rate in main plasma and wall inventory under recycling effect and codeposition of hydrogen in case of continues and discontinues fueling methods and effective parameters on the main plasma decay has been studied.

  18. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2005-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  19. Hydrogen from biomass gas steam reforming for low temperature fuel cell: energy and exergy analysis

    Directory of Open Access Journals (Sweden)

    A. Sordi

    2009-03-01

    Full Text Available This work presents a method to analyze hydrogen production by biomass gasification, as well as electric power generation in small scale fuel cells. The proposed methodology is the thermodynamic modeling of a reaction system for the conversion of methane and carbon monoxide (steam reforming, as well as the energy balance of gaseous flow purification in PSA (Pressure Swing Adsorption is used with eight types of gasification gases in this study. The electric power is generated by electrochemical hydrogen conversion in fuel cell type PEMFC (Proton Exchange Membrane Fuel Cell. Energy and exergy analyses are applied to evaluate the performance of the system model. The simulation demonstrates that hydrogen production varies with the operation temperature of the reforming reactor and with the composition of the gas mixture. The maximum H2 mole fraction (0.6-0.64 mol.mol-1 and exergetic efficiency of 91- 92.5% for the reforming reactor are achieved when gas mixtures of higher quality such as: GGAS2, GGAS4 and GGAS5 are used. The use of those gas mixtures for electric power generation results in lower irreversibility and higher exergetic efficiency of 30-30.5%.

  20. A Methodology for Assessing the Sustainability of Hydrogen Production from Solid Fuels

    Directory of Open Access Journals (Sweden)

    Nirmal V. Gnanapragasam

    2010-05-01

    Full Text Available A methodology for assessing the sustainability of hydrogen production using solid fuels is introduced, in which three sustainability dimensions (ecological, sociological and technological are considered along with ten indicators for each dimension. Values for each indicator are assigned on a 10-point scale based on a high of 1 and a low of 0, depending on the characteristic of the criteria associated with each element or process, utilizing data reported in the literature. An illustrative example is presented to compare two solid fuels for hydrogen production: coal and biomass. The results suggest that qualitative sustainability indicators can be reasonably defined based on evaluations of system feasibility, and that adequate flexibility and comprehensiveness is provided through the use of ten indicators for each of the dimensions for every process or element involved in hydrogen production using solid fuels. Also, the assessment index values suggest that biomasses have better sustainability than coals, and that it may be advantageous to use coals in combination with biomass to increase their ecological and social sustainability. The sustainability assessment methodology can be made increasingly quantitative, and is likely extendable to other energy systems, but additional research and development is needed to lead to a more fully developed approach.

  1. Initial Screening of Thermochemical Water-Splitting Cycles for High Efficiency Generation of Hydrogen Fuels Using Nuclear Power

    Energy Technology Data Exchange (ETDEWEB)

    Brown, L.C.; Funk, J.F.; Showalter, S.K.

    1999-12-15

    OAK B188 Initial Screening of Thermochemical Water-Splitting Cycles for High Efficiency Generation of Hydrogen Fuels Using Nuclear Power There is currently no large scale, cost-effective, environmentally attractive hydrogen production process, nor is such a process available for commercialization. Hydrogen is a promising energy carrier, which potentially could replace the fossil fuels used in the transportation sector of our economy. Fossil fuels are polluting and carbon dioxide emissions from their combustion are thought to be responsible for global warming. The purpose of this work is to determine the potential for efficient, cost-effective, large-scale production of hydrogen utilizing high temperature heat from an advanced nuclear power station. Almost 800 literature references were located which pertain to thermochemical production of hydrogen from water and over 100 thermochemical watersplitting cycles were examined. Using defined criteria and quantifiable metrics, 25 cycles have been selected for more detailed study.

  2. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2006-03-30

    Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe

  3. Detection of hydrogen gas-producing anaerobes in refuse-derived fuel (RDF) pellets.

    Science.gov (United States)

    Sakka, Makiko; Kimura, Tetsuya; Ohmiya, Kunio; Sakka, Kazuo

    2005-11-01

    Recently, we reported that refuse-derived fuel (RDF) pellets contain a relatively high number of viable bacterial cells and that these bacteria generate heat and hydrogen gas during fermentation under wet conditions. In this study we analyzed bacterial cell numbers of RDF samples manufactured with different concentrations of calcium hydroxide, which is usually added to waste materials for the prevention of rotting of food wastes and the acceleration of drying of solid wastes, and determined the amount of hydrogen gas produced by them under wet conditions. Furthermore, we analyzed microflora of the RDF samples before and during fermentation by denaturing gradient gel electrophoresis of 16S rDNA followed by sequencing. We found that the RDF samples contained various kinds of clostridia capable of producing hydrogen gas.

  4. Innovative regions and industrial clusters in hydrogen and fuel cell technology

    DEFF Research Database (Denmark)

    Madsen, Anne Nygaard; Andersen, Per Dannemand

    2010-01-01

    will analyse regions that are highly engaged in H2FC activity, based on three indicators: existing hydrogen infrastructure and production sites, general innovativeness and the presence of industrial clusters with relevance for H2FC. Our finding is that regions with high activity in H2FC development are also...... innovative regions in general. Moreover, the article highlights some industrial clusters that create favourable conditions for regions to take part in H2FC development. Existing hydrogen infrastructure, however, seems to play only a minor role in a region’s engagement. The article concludes that, while......Regional governments in Europe seem to be playing an increasing role in hydrogen and fuel cell (H2FC) development. A number of regions are supporting demonstration projects and building networks among regional stakeholders to strengthen their engagement in H2FC technology. In this article, we...

  5. Cleaning the air and improving health with hydrogen fuel-cell vehicles.

    Science.gov (United States)

    Jacobson, M Z; Colella, W G; Golden, D M

    2005-06-24

    Converting all U.S. onroad vehicles to hydrogen fuel-cell vehicles (HFCVs) may improve air quality, health, and climate significantly, whether the hydrogen is produced by steam reforming of natural gas, wind electrolysis, or coal gasification. Most benefits would result from eliminating current vehicle exhaust. Wind and natural gas HFCVs offer the greatest potential health benefits and could save 3700 to 6400 U.S. lives annually. Wind HFCVs should benefit climate most. An all-HFCV fleet would hardly affect tropospheric water vapor concentrations. Conversion to coal HFCVs may improve health but would damage climate more than fossil/electric hybrids. The real cost of hydrogen from wind electrolysis may be below that of U.S. gasoline.

  6. Technology Implementation Plan. Fully Ceramic Microencapsulated Fuel for Commercial Light Water Reactor Application

    Energy Technology Data Exchange (ETDEWEB)

    Snead, Lance Lewis [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Terrani, Kurt A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Powers, Jeffrey J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Worrall, Andrew [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Robb, Kevin R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Snead, Mary A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-04-01

    This report is an overview of the implementation plan for ORNL's fully ceramic microencapsulated (FCM) light water reactor fuel. The fully ceramic microencapsulated fuel consists of tristructural isotropic (TRISO) particles embedded inside a fully dense SiC matrix and is intended for utilization in commercial light water reactor application.

  7. Development Status of Accident-tolerant Fuel for Light Water Reactors in Korea

    Directory of Open Access Journals (Sweden)

    Hyun-Gil Kim

    2016-02-01

    Full Text Available For a long time, a top priority in the nuclear industry was the safe, reliable, and economic operation of light water reactors. However, the development of accident-tolerant fuel (ATF became a hot topic in the nuclear research field after the March 2011 events at Fukushima, Japan. In Korea, innovative concepts of ATF have been developing to increase fuel safety and reliability during normal operations, operational transients, and also accident events. The microcell UO2 and high-density composite pellet concepts are being developed as ATF pellets. A microcell UO2 pellet is envisaged to have the enhanced retention capabilities of highly radioactive and corrosive fission products. High-density pellets are expected to be used in combination with the particular ATF cladding concepts. Two concepts—surface-modified Zr-based alloy and SiC composite material—are being developed as ATF cladding, as these innovative concepts can effectively suppress hydrogen explosions and the release of radionuclides into the environment.

  8. Current status of materials development of nuclear fuel cladding tubes for light water reactors

    Energy Technology Data Exchange (ETDEWEB)

    Duan, Zhengang, E-mail: duan_zg@imr.tohoku.ac.jp [Department of Quantum Science and Energy Engineering, Graduate School of Engineering, Tohoku University, Sendai, Miyagi 980-8577 (Japan); Yang, Huilong [Department of Nuclear Engineering, School of Engineering, The University of Tokyo, Nakagun, Ibaraki 319-1188 (Japan); Satoh, Yuhki [Institute for Materials Research, Tohoku University, Sendai, Miyagi 980-8577 (Japan); Murakami, Kenta; Kano, Sho; Zhao, Zishou; Shen, Jingjie [Department of Nuclear Engineering, School of Engineering, The University of Tokyo, Nakagun, Ibaraki 319-1188 (Japan); Abe, Hiroaki, E-mail: abe.hiroaki@n.t.u-tokyo.ac.jp [Department of Nuclear Engineering, School of Engineering, The University of Tokyo, Nakagun, Ibaraki 319-1188 (Japan)

    2017-05-15

    Zirconium-based (Zr-based) alloys have been widely used as materials for the key components in light water reactors (LWRs), such as fuel claddings which suffer from waterside corrosion, hydrogen uptakes and strength loss at elevated temperature, especially during accident scenarios like the lost-of-coolant accident (LOCA). For the purpose of providing a safer, nuclear leakage resistant and economically viable LWRs, three general approaches have been proposed so far to develop the accident tolerant fuel (ATF) claddings: optimization of metallurgical composition and processing of Zr-based alloys, coatings on existing Zr-based alloys and replacement of current Zr-based alloys. In this manuscript, an attempt has been made to systematically present the historic development of Zr-based cladding, including the impacts of alloying elements on the material properties. Subsequently, the research investigations on coating layer on the surface of Zr-based claddings, mainly referring coating materials and fabrication methods, have been broadly reviewed. The last section of this review provides the introduction to alternative materials (Non-Zr) to Zr-based alloys for LWRs, such as advanced steels, Mo-based, and SiC-based materials.

  9. U.S. Department of Energy Hydrogen and Fuel Cells Program: 2017 Annual Merit Review and Peer Evaluation Report

    Energy Technology Data Exchange (ETDEWEB)

    Popovich, Neil A [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-10-18

    The fiscal year 2017 U.S. Department of Energy (DOE) Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting (AMR), in conjunction with DOE's Vehicle Technologies Office AMR, was held from June June 5-9, 2017, in Washington, D.C. This report is a summary of comments by AMR peer reviewers about the hydrogen and fuel cell projects funded by DOE's Office of Energy Efficiency and Renewable Energy.

  10. Hydrogen and fuel cells: security and energy sustainability; Hidrogeno y pilas de combustible: seguridad y sostenibilidad energetica

    Energy Technology Data Exchange (ETDEWEB)

    Brey Sanchez, J. J.

    2012-11-01

    As fuel, hydrogen burns, burn like gasoline or natural gas, but with the difference that the only emission is water vapor produced without the presence of carbon dioxide. So, this is a clean fuel when its use. However, while the coal, oil or natural gas is found in nature, hydrogen must be produced from a primary energy source: it is said to be a energy vector. (Author)

  11. Description and modelling of the solar-hydrogen-biogas-fuel cell system in GlashusEtt

    Science.gov (United States)

    Hedström, L.; Wallmark, C.; Alvfors, P.; Rissanen, M.; Stridh, B.; Ekman, J.

    The need to reduce pollutant emissions and utilise the world's available energy resources more efficiently has led to increased attention towards e.g. fuel cells, but also to other alternative energy solutions. In order to further understand and evaluate the prerequisites for sustainable and energy-saving systems, ABB and Fortum have equipped an environmental information centre, located in Hammarby Sjöstad, Stockholm, Sweden, with an alternative energy system. The system is being used to demonstrate and evaluate how a system based on fuel cells and solar cells can function as a complement to existing electricity and heat production. The stationary energy system is situated on the top level of a three-floor glass building and is open to the public. The alternative energy system consists of a fuel cell system, a photovoltaic (PV) cell array, an electrolyser, hydrogen storage tanks, a biogas burner, dc/ac inverters, heat exchangers and an accumulator tank. The fuel cell system includes a reformer and a polymer electrolyte fuel cell (PEFC) with a maximum rated electrical output of 4 kW el and a maximum thermal output of 6.5 kW th. The fuel cell stack can be operated with reformed biogas, or directly using hydrogen produced by the electrolyser. The cell stack in the electrolyser consists of proton exchange membrane (PEM) cells. To evaluate different automatic control strategies for the system, a simplified dynamic model has been developed in MATLAB Simulink. The model based on measurement data taken from the actual system. The evaluation is based on demand curves, investment costs, electricity prices and irradiation. Evaluation criteria included in the model are electrical and total efficiencies as well as economic parameters.

  12. Effects of signal light on the fuel consumption and emissions under car-following model

    Science.gov (United States)

    Tang, Tie-Qiao; Yi, Zhi-Yan; Lin, Qing-Feng

    2017-03-01

    In this paper, a car-following model is utilized to study the effects of signal light on each vehicle's fuel consumption, CO, HC and NOX. The numerical results show that each vehicle's fuel consumption and emissions are influenced by the signal light and that the effects are related to the green split of the signal light and the vehicle's time headway at the origin, which can help drivers adjust their micro driving behavior on the road with a signal light to reduce their fuel consumption and emissions.

  13. U.S. Department of Energy Hydrogen and Fuel Cells Program 2011 Annual Merit Review and Peer Evaluation Report

    Energy Technology Data Exchange (ETDEWEB)

    Satypal, S.

    2011-09-01

    This document summarizes the comments provided by peer reviewers on hydrogen and fuel cell projects presented at the FY 2011 U.S. Department of Energy (DOE) Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting (AMR), held May 9-13, 2011 in Arlington, Virginia

  14. South African hydrogen infrastructure (HySA infrastructure) for fuel cells and energy storage: Overview of a projects portfolio

    CSIR Research Space (South Africa)

    Bessarabov, D

    2017-05-01

    Full Text Available The paper provides brief introduction to the National South African Program, branded HySA (Hydrogen South Africa) as well as discusses potential business cases for deployment of hydrogen and fuel cell technology in South Africa. This paper also...

  15. Production of Hydrogen for Clean and Renewable Source of Energy for Fuel Cell Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Deng, Xunming; Ingler, William B, Jr.; Abraham, Martin; Castellano, Felix; Coleman, Maria; Collins, Robert; Compaan, Alvin; Giolando, Dean; Jayatissa, Ahalapitiya. H.; Stuart, Thomas; Vonderembse, Mark

    2008-10-31

    This was a two-year project that had two major components: 1) the demonstration of a PV-electrolysis system that has separate PV system and electrolysis unit and the hydrogen generated is to be used to power a fuel cell based vehicle; 2) the development of technologies for generation of hydrogen through photoelectrochemical process and bio-mass derived resources. Development under this project could lead to the achievement of DOE technical target related to PEC hydrogen production at low cost. The PEC part of the project is focused on the development of photoelectrochemical hydrogen generation devices and systems using thin-film silicon based solar cells. Two approaches are taken for the development of efficient and durable photoelectrochemical cells; 1) An immersion-type photoelectrochemical cells (Task 3) where the photoelectrode is immersed in electrolyte, and 2) A substrate-type photoelectrochemical cell (Task 2) where the photoelectrode is not in direct contact with electrolyte. Four tasks are being carried out: Task 1: Design and analysis of DC voltage regulation system for direct PV-to-electrolyzer power feed Task 2: Development of advanced materials for substrate-type PEC cells Task 3: Development of advanced materials for immersion-type PEC cells Task 4: Hydrogen production through conversion of biomass-derived wastes

  16. Development of Criteria for Flameholding Tendencies within Premixer Passages for High Hydrogen Content Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lewis, Elliot Sullivan- [Univ. of California, Irvine, CA (United States); McDonell, Vincent G. [Univ. of California, Irvine, CA (United States)

    2014-12-01

    Due to increasingly stringent air quality requirements stationary power gas turbines have moved to lean-premixed operation, which reduces pollutant emissions but can result in flashback. Flashback can cause serious damage to the premixer hardware. Curtailing flashback can be difficult with hydrocarbon fuels and becomes even more challenging when hydrogen is used as the fuel. The two main approaches for coping with flashback are either to design a combustor that is resistant to flashback, or to design a premixer that will not anchor a flame if flashback occurs. Even with a well-designed combustor flashback can occur under certain circumstances, thus it is necessary to determine how to avoid flameholding within the premixer passageways of a gas turbine. To this end, an experiment was designed that would determine the flameholding propensities at elevated pressures and temperatures of three different classes of geometric features commonly found in gas turbine premixers, with both natural gas and hydrogen fuel. Experiments to find the equivalence ratio at blow off were conducted within an optically accessible test apparatus with four flameholders: 0.25 and 0.50 inch diameter cylinders, a reverse facing step with a height of 0.25 inches, and a symmetric airfoil with a thickness of 0.25 inches and a chord length of one inch. Tests were carried out at temperatures between 300 K and 750 K, at pressures up to 9 atmospheres. Typical bulk velocities were between 40 and 100 m/s. The effect of airfoil’s angle of rotation was also investigated. Blow off for hydrogen flames was found to occur at much lower adiabatic flame temperatures than natural gas flames. Additionally it was observed that at high pressures and high turbulence intensities, reactant velocity does not have a noticeable effect on the point of blow off due in large part to corresponding increases in turbulent flame speed. Finally a semi empirical correlation was developed that predicts flame extinction for both

  17. Convergent close-coupling approach to light and heavy projectile scattering on atomic and molecular hydrogen

    Science.gov (United States)

    Bray, I.; Abdurakhmanov, I. B.; Bailey, J. J.; Bray, A. W.; Fursa, D. V.; Kadyrov, A. S.; Rawlins, C. M.; Savage, J. S.; Stelbovics, A. T.; Zammit, M. C.

    2017-10-01

    The atomic hydrogen target has played a pivotal role in the development of quantum collision theory. The key complexities of computationally managing the countably infinite discrete states and the uncountably infinite continuum were solved by using atomic hydrogen as the prototype atomic target. In the case of positron or proton scattering the extra complexity of charge exchange was also solved using the atomic hydrogen target. Most recently, molecular hydrogen has been used successfully as a prototype molecule for developing the corresponding scattering theory. We concentrate on the convergent close-coupling computational approach to light projectiles, such as electrons and positrons, and heavy projectiles, such as protons and antiprotons, scattering on atomic and molecular hydrogen.

  18. Towards a framework for evaluation of renewable energy storage projects: A study case of hydrogen and fuel cells in Denmark

    DEFF Research Database (Denmark)

    Tambo, Torben; Enevoldsen, Peter

    2015-01-01

    ) A case study of the Danish Partnership for Hydrogen and Fuel Cells particularly with the focus on alkaline, PEM, SOEC and SOFC hydrolyzers and fuel cells. The paper discusses the complex and paradoxical catch between the necessity to research and develop energy storage technologies against the existence...

  19. Fuel-rich hydrogen-air combustion for a gas-turbine system without CO{sub 2} emission

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, Noriyuki; Namo, Takamitsu; Arai, Norio [Nagoya Univ. (Japan). Research Center for Advanced Energy Conversion

    1997-02-01

    We propose a new and innovative gas-turbine system using fuel-rich hydrogen combustion, which we call a chemical gas-turbine system. It involves a fuel-rich hydrogen-air combustor as a major component. We have focused on a coaxial diffusion flame under normal pressure. The effects of equivalence ratio and swirl number have been investigated by measuring temperature profiles, gas composition, and flame structures using direct observations of OH radical emissions. The flames were shortened and NO{sub x} emission decreased with swirling under fuel-rich conditions. (author)

  20. Methanol as a High Purity Hydrogen Source for Fuel Cells: A Brief Review of Catalysts and Rate Expressions

    Directory of Open Access Journals (Sweden)

    Madej-Lachowska Maria

    2017-03-01

    Full Text Available Hydrogen is the fuel of the future, therefore many hydrogen production methods are developed. At present, fuel cells are of great interest due to their energy efficiency and environmental benefits. A brief review of effective formation methods of hydrogen was conducted. It seems that hydrogen from steam reforming of methanol process is the best fuel source to be applied in fuel cells. In this process Cu-based complex catalysts proved to be the best. In presented work kinetic equations from available literature and catalysts are reported. However, hydrogen produced even in the presence of the most selective catalysts in this process is not pure enough for fuel cells and should be purified from CO. Currently, catalysts for hydrogen production are not sufficiently active in oxidation of carbon monoxide. A simple and effective method to lower CO level and obtain clean H2 is the preferential oxidation of monoxide carbon (CO-PROX. Over new CO-PROX catalysts the level of carbon monoxide can be lowered to a sufficient level of 10 ppm.

  1. Biodiesel of distilled hydrogenated fat and biodiesel of distilled residual oil: fuel consumption in agricultural tractor

    Energy Technology Data Exchange (ETDEWEB)

    Camara, Felipe Thomaz da; Lopes, Afonso; Silva, Rouverson Pereira da; Oliveira, Melina Cais Jejcic; Furlani, Carlos Eduardo Angeli [Universidade Estadual Paulista (UNESP), Jaboticabal, SP (Brazil); Dabdoub, Miguel Joaquim [Universidade de Sao Paulo (USP), Ribeirao Preto (Brazil)

    2008-07-01

    Great part of the world-wide oil production is used in fry process; however, after using, such product becomes an undesirable residue, and the usual methods of discarding of these residues, generally contaminate the environment, mainly the rivers. In function of this, using oil and residual fat for manufacturing biodiesel, besides preventing ambient contamination, turning up an undesirable residue in to fuel. The present work had as objective to evaluate the fuel consumption of a Valtra BM100 4x2 TDA tractor functioning with methylic biodiesel from distilled hydrogenated fat and methylic biodiesel from distilled residual oil, in seven blends into diesel. The work was conducted at the Department of Agricultural Engineering, at UNESP - Jaboticabal, in an entirely randomized block statistical design, factorial array of 2 x 7, with three repetitions. The factors combinations were two types of methylic distilled biodiesel (residual oil and hydrogenated fat) and seven blends (B{sub 0}, B{sub 5}, B{sub 1}5, B{sub 2}5, B{sub 5}0, B{sub 7}5 and B{sub 1}00). The results had evidenced that additioning 15% of biodiesel into diesel, the specific consumption was similar, and biodiesel of residual oil provided less consumption than biodiesel from hydrogenated fat. (author)

  2. The influence of hydrogen peroxide and hydrogen on the corrosion of simulated spent nuclear fuel.

    Science.gov (United States)

    Razdan, Mayuri; Shoesmith, David W

    2015-01-01

    The synergistic influence between H(2)O(2) and H(2) on the corrosion of SIMFUEL (simulated spent nuclear fuel) has been studied in solutions with and without added HCO(3)(-)/CO(3)(2-). The response of the surface to increasing concentrations of added H(2)O(2) was monitored by measuring the corrosion potential in either Ar or Ar/H(2)-purged solutions. Using X-ray photoelectron spectroscopy it was shown that the extent of surface oxidation (U(V) + U(VI) content) was directly related to the corrosion potential. Variations in corrosion potential with time, redox conditions, HCO(3)(-)/CO(3)(2-) concentration, and convective conditions showed that surface oxidation induced by H(2)O(2) could be reversed by reaction with H(2), the latter reaction occurring dominantly on the noble metal particles in the SIMFUEL. For sufficiently large H(2)O(2) concentrations, the influence of H(2) was overwhelmed and irreversible oxidation of the surface to U(VI) occurred. Subsequently, corrosion was controlled by the chemical dissolution rate of this U(VI) layer.

  3. Nanocrystalline diamond protects Zr cladding surface against oxygen and hydrogen uptake: Nuclear fuel durability enhancement.

    Science.gov (United States)

    Škarohlíd, Jan; Ashcheulov, Petr; Škoda, Radek; Taylor, Andrew; Čtvrtlík, Radim; Tomáštík, Jan; Fendrych, František; Kopeček, Jaromír; Cháb, Vladimír; Cichoň, Stanislav; Sajdl, Petr; Macák, Jan; Xu, Peng; Partezana, Jonna M; Lorinčík, Jan; Prehradná, Jana; Steinbrück, Martin; Kratochvílová, Irena

    2017-07-25

    In this work, we demonstrate and describe an effective method of protecting zirconium fuel cladding against oxygen and hydrogen uptake at both accident and working temperatures in water-cooled nuclear reactor environments. Zr alloy samples were coated with nanocrystalline diamond (NCD) layers of different thicknesses, grown in a microwave plasma chemical vapor deposition apparatus. In addition to showing that such an NCD layer prevents the Zr alloy from directly interacting with water, we show that carbon released from the NCD film enters the underlying Zr material and changes its properties, such that uptake of oxygen and hydrogen is significantly decreased. After 100-170 days of exposure to hot water at 360 °C, the oxidation of the NCD-coated Zr plates was typically decreased by 40%. Protective NCD layers may prolong the lifetime of nuclear cladding and consequently enhance nuclear fuel burnup. NCD may also serve as a passive element for nuclear safety. NCD-coated ZIRLO claddings have been selected as a candidate for Accident Tolerant Fuel in commercially operated reactors in 2020.

  4. High-energy-density hydrogen-halogen fuel cells for advanced military applications

    Science.gov (United States)

    Balko, E. N.; McElroy, J. F.

    It is pointed out that hydrogen-halogen fuel cell systems are particularly suited for an employment as ground power sources for military applications. The large cell potential and reversible characteristics of the H2/Cl2 and H2/Br2 couples permit high energy storage density and efficient energy conversion. When used as flow batteries, the fluid nature of the reactants in the hydrogen-halogen systems has several advantages over power sources which involve solid phases. Very deep discharge is possible without degradation of subsequent performance, and energy storage capacity is limited only by the external reactant storage volume. Very rapid chemical recharging is possible through replenishment of the reactant supply. A number of H2/Cl2 and H2/Br2 fuel cell systems have been studied. These systems use the same solid polymer electrolyte (SPE) cell technology originally developed for H2/O2 fuel cells. The results of the investigation are illustrated with the aid of a number of graphs.

  5. Catalytic processing of high-sulfur fuels for distributed hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Muradov, Nazim; Ramasamy, Karthik; Huang, Cunping; T-Raissi, Ali [Central Florida Univ., FL (United States)

    2010-07-01

    In this work, the development of a new on-demand hydrogen production technology is reported. In this process, a liquid hydrocarbon fuel (e.g., high-S diesel) is first catalytically pre-reformed to shorter chain gaseous hydrocarbons (predominantly, C{sub 1}-C{sub 3}) before being directed to the steam reformer, where it is converted to syngas and then to high-purity hydrogen. In the pre-reformer, most sulfurous species present in the fuel are catalytically converted to H{sub 2}S. In the desulfurization unit, H{sub 2}S is scrubbed and converted to H{sub 2} and elemental sulfur. Desulfurization of the pre-reformate gas is carried out in a special regenerative redox system, which includes Fe(II)/Fe(III)-containing aqueous phase scrubber coupled with an electrolyzer. The integrated pre-reformer/scrubber/electrolyzer unit operated successfully on high-S diesel fuel for more than 100 hours meeting the required desulfurization target of >95 % sulfur removal. (orig.)

  6. Developing RCM Strategy for Hydrogen Fuel Cells Utilizing On Line E-Condition Monitoring

    Science.gov (United States)

    Baglee, D.; Knowles, M. J.

    2012-05-01

    Fuel cell vehicles are considered to be a viable solution to problems such as carbon emissions and fuel shortages for road transport. Proton Exchange Membrane (PEM) Fuel Cells are mainly used in this purpose because they can run at low temperatures and have a simple structure. Yet high maintenance costs and the inherent dangers of maintaining equipment using hydrogen are two main issues which need to be addressed. The development of appropriate and efficient strategies is currently lacking with regard to fuel cell maintenance. A Reliability Centered Maintenance (RCM) approach offers considerable benefit to the management of fuel cell maintenance since it includes an identification and consideration of the impact of critical components. Technological developments in e-maintenance systems, radio-frequency identification (RFID) and personal digital assistants (PDAs) have proven to satisfy the increasing demand for improved reliability, efficiency and safety. RFID technology is used to store and remotely retrieve electronic maintenance data in order to provide instant access to up-to-date, accurate and detailed information. The aim is to support fuel cell maintenance decisions by developing and applying a blend of leading-edge communications and sensor technology including RFID. The purpose of this paper is to review and present the state of the art in fuel cell condition monitoring and maintenance utilizing RCM and RFID technologies. Using an RCM analysis critical components and fault modes are identified. RFID tags are used to store the critical information, possible faults and their cause and effect. The relationship between causes, faults, symptoms and long term implications of fault conditions are summarized. Finally conclusions are drawn regarding suggested maintenance strategies and the optimal structure for an integrated, cost effective condition monitoring and maintenance management system.

  7. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2003-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. These feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. Some highlights of the results obtained during the first year of the current research contract are summarized as: (1) Terminal alkynes are an effective chain initiator for Fischer-Tropsch (FT) reactions, producing normal paraffins with C numbers {ge} to that of the added alkyne. (2) Significant improvement in the product distribution towards heavier hydrocarbons (C{sub 5} to C{sub 19}) was achieved in supercritical fluid (SCF) FT reactions compared to that of gas-phase reactions. (3) Xerogel and aerogel silica supported cobalt catalysts were successfully employed for FT synthesis. Selectivity for diesel range products increased with increasing Co content. (4) Silicoaluminophosphate (SAPO) molecular sieve catalysts have been developed for methanol to olefin conversion, producing value-added products such as ethylene and propylene. (5) Hybrid Pt-promoted tungstated and sulfated zirconia catalysts are very effective in cracking n-C{sub 36} to jet and diesel fuel; these catalysts will be tested for cracking of FT wax. (6) Methane, ethane, and propane are readily decomposed to pure

  8. 41 CFR 109-38.104 - Fuel efficient passenger automobiles and light trucks.

    Science.gov (United States)

    2010-07-01

    ... automobiles and light trucks. 109-38.104 Section 109-38.104 Public Contracts and Property Management Federal... Vehicles § 109-38.104 Fuel efficient passenger automobiles and light trucks. (a) (b) All requests to... objectives listed in 41 CFR 101-38.104. (1)-(4) (5) Requests to exempt certain light trucks from the fleet...

  9. Global Assessment of Hydrogen Technologies – Task 5 Report Use of Fuel Cell Technology in Electric Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan Andrew J.; Ahluwalia, Rajesh K.

    2007-12-01

    The purpose of this work was to assess the performance of high temperature membranes and observe the impact of different parameters, such as water-to-carbon ratio, carbon formation, hydrogen formation, efficiencies, methane formation, fuel and oxidant utilization, sulfur reduction, and the thermal efficiency/electrical efficiency relationship, on fuel cell performance. A 250 KW PEM fuel cell model was simulated [in conjunction with Argonne National Laboratory (ANL) with the help of the fuel cell computer software model (GCtool)] which would be used to produce power of 250 kW and also produce steam at 120oC that can be used for industrial applications. The performance of the system was examined by estimating the various electrical and thermal efficiencies achievable, and by assessing the effect of supply water temperature, process water temperature, and pressure on thermal performance. It was concluded that increasing the fuel utilization increases the electrical efficiency but decreases the thermal efficiency. The electrical and thermal efficiencies are optimum at ~85% fuel utilization. The low temperature membrane (70oC) is unsuitable for generating high-grade heat suitable for useful cogeneration. The high temperature fuel cells are capable of producing steam through 280oC that can be utilized for industrial applications. Increasing the supply water temperature reduces the efficiency of the radiator. Increasing the supply water temperature beyond the dew point temperature decreases the thermal efficiency with the corresponding decrease in high-grade heat utilization. Increasing the steam pressure decreases the thermal efficiency. The environmental impacts of fuel cell use depend upon the source of the hydrogen rich fuel used. By using pure hydrogen, fuel cells have virtually no emissions except water. Hydrogen is rarely used due to problems with storage and transportation, but in the future, the growth of a “solar hydrogen economy” has been projected

  10. Evaluation of unthrottled combustion system options for light duty applications with future syncrude derived fuels. Alternative Fuels Utilization Program

    Energy Technology Data Exchange (ETDEWEB)

    Needham, J. R.; Cooper, B. M.; Norris-Jones, S. R.

    1982-12-01

    An experimental program examining the interaction between several fuel and light duty automotive engine combinations is detailed. Combustion systems addressed covered indirect and direct injection diesel and spark ignited stratified charge. Fuels primarily covered D2, naphtha and intermediate broadcut blends. Low ignition quality diesel fuels were also evaluated. The results indicate the baseline fuel tolerance of each combustion system and enable characteristics of the systems to be compared. Performance, gaseous and particulate emissions aspects were assessed. The data obtained assists in the selection of candidate combustion systems for potential future fuels. Performance and environmental penalties as appropriate are highlighted relative to the individual candidates. Areas of further work for increased understanding are also reviewed.

  11. Development of Advanced High Uranium Density Fuels for Light Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Blanchard, James [Univ. of Wisconsin, Madison, WI (United States); Butt, Darryl [Boise State Univ., ID (United States); Meyer, Mitchell [Idaho National Lab. (INL), Idaho Falls, ID (United States); Xu, Peng [Westinghouse Electric Corporation, Pittsburgh, PA (United States)

    2016-02-15

    This work conducts basic materials research (fabrication, radiation resistance, thermal conductivity, and corrosion response) on U3Si2 and UN, two high uranium density fuel forms that have a high potential for success as advanced light water reactor (LWR) fuels. The outcome of this proposed work will serve as the basis for the development of advance LWR fuels, and utilization of such fuel forms can lead to the optimization of the fuel performance related plant operating limits such as power density, power ramp rate and cycle length.

  12. Production of hydrogen for fuel cells by steam reforming of ethanol over supported noble metal catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Liguras, Dimitris K.; Kondarides, Dimitris I.; Verykios, Xenophon E. [Department of Chemical Engineering, University of Patras, GR-26504 Patras (Greece)

    2003-07-25

    The catalytic performance of supported noble metal catalysts for the steam reforming (SR) of ethanol has been investigated in the temperature range of 600-850C with respect to the nature of the active metallic phase (Rh, Ru, Pt, Pd), the nature of the support (Al{sub 2}O{sub 3}, MgO, TiO{sub 2}) and the metal loading (0-5wt.%). It is found that for low-loaded catalysts, Rh is significantly more active and selective toward hydrogen formation compared to Ru, Pt and Pd, which show a similar behavior. The catalytic performance of Rh and, particularly, Ru is significantly improved with increasing metal loading, leading to higher ethanol conversions and hydrogen selectivities at given reaction temperatures. The catalytic activity and selectivity of high-loaded Ru catalysts is comparable to that of Rh and, therefore, ruthenium was further investigated as a less costly alternative. It was found that, under certain reaction conditions, the 5% Ru/Al{sub 2}O{sub 3} catalyst is able to completely convert ethanol with selectivities toward hydrogen above 95%, the only byproduct being methane. Long-term tests conducted under severe conditions showed that the catalyst is acceptably stable and could be a good candidate for the production of hydrogen by steam reforming of ethanol for fuel cell applications.

  13. Production of hydrogen for fuel cells by reformation of biomass-derived ethanol

    Energy Technology Data Exchange (ETDEWEB)

    Fatsikostas, Athanasios N.; Kondarides, Dimitris I.; Verykios, Xenophon E. [Department of Chemical Engineering, University of Patras, GR-26500 Patras (Greece)

    2002-07-03

    The reformation of biomass-derived ethanol to a hydrogen-rich gas stream suitable for feeding fuel cells is investigated as an efficient and environmentally friendly process for the production of electricity for mobile and stationary applications. Steam reforming of ethanol is investigated over Ni catalysts supported on La{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, YSZ and MgO. The influence of several parameters on the catalytic activity and selectivity is examined including reaction temperature, water-to-ethanol ratio and space velocity. Results reveal that the Ni/La{sub 2}O{sub 3} catalyst exhibits high activity and selectivity toward hydrogen production and, most important, long term stability for steam reforming of ethanol. The enhanced stability of this catalyst may be due to scavenging of coke deposition on the Ni surface by lanthanum oxycarbonate species which exist on top of the Ni particles under reaction conditions.

  14. Make America Green Again: Fueling a Cleaner Future with Adsorbed Hydrogen Storage Tanks

    Science.gov (United States)

    Gillespie, Andrew; Prosniewski, Matthew; Knight, Ernest; Pfeifer, Peter

    Compressed hydrogen requires extremely high pressures or low temperatures in order to compete with the energy density of conventional fossil fuels. Adsorbent materials provide a means to increase the energy density of the gas up to 3 times that of compressed gas at the same temperature and pressure. Absorbent types are often compared based on their pore structures, surface areas, and heats of adsorption because each of these quantities directly impact storage capacity. In this talk, we compare the deliverable storage capacities of various adsorbent types and discuss the impact that high binding energies have on material performance and delivery. Carbonaceous materials were found to reversibly deliver 2-3 times the amount of hydrogen compared to compressed gas at cryogenic temperatures.

  15. Biological conversion of carbon dioxide and hydrogen into liquid fuels and industrial chemicals.

    Science.gov (United States)

    Hawkins, Aaron S; McTernan, Patrick M; Lian, Hong; Kelly, Robert M; Adams, Michael W W

    2013-06-01

    Non-photosynthetic routes for biological fixation of carbon dioxide into valuable industrial chemical precursors and fuels are moving from concept to reality. The development of 'electrofuel'-producing microorganisms leverages techniques in synthetic biology, genetic and metabolic engineering, as well as systems-level multi-omic analysis, directed evolution, and in silico modeling. Electrofuel processes are being developed for a range of microorganisms and energy sources (e.g. hydrogen, formate, electricity) to produce a variety of target molecules (e.g. alcohols, terpenes, alkenes). This review examines the current landscape of electrofuel projects with a focus on hydrogen-utilizing organisms covering the biochemistry of hydrogenases and carbonic anhydrases, kinetic and energetic analyses of the known carbon fixation pathways, and the state of genetic systems for current and prospective electrofuel-producing microorganisms. Copyright © 2013 Elsevier Ltd. All rights reserved.

  16. Uncertainty Analysis of Light Water Reactor Fuel Lattices

    Directory of Open Access Journals (Sweden)

    C. Arenas

    2013-01-01

    Full Text Available The study explored the calculation of uncertainty based on available cross-section covariance data and computational tool on fuel lattice levels, which included pin cell and the fuel assembly models. Uncertainty variations due to temperatures changes and different fuel compositions are the main focus of this analysis. Selected assemblies and unit pin cells were analyzed according to the OECD LWR UAM benchmark specifications. Criticality and uncertainty analysis were performed using TSUNAMI-2D sequence in SCALE 6.1. It was found that uncertainties increase with increasing temperature, while kinf decreases. This increase in the uncertainty is due to the increase in sensitivity of the largest contributing reaction of uncertainty, namely, the neutron capture reaction 238U(n, γ due to the Doppler broadening. In addition, three types (UOX, MOX, and UOX-Gd2O3 of fuel material compositions were analyzed. A remarkable increase in uncertainty in kinf was observed for the case of MOX fuel. The increase in uncertainty of kinf in MOX fuel was nearly twice the corresponding value in UOX fuel. The neutron-nuclide reaction of 238U, mainly inelastic scattering (n, n′, contributed the most to the uncertainties in the MOX fuel, shifting the neutron spectrum to higher energy compared to the UOX fuel.

  17. Disturbing effect of free hydrogen on fuel combustion in internal combustion engines

    Science.gov (United States)

    Riedler, A

    1923-01-01

    Experiments with fuel mixtures of varying composition, have recently been conducted by the Motor Vehicle and Airplane Engine Testing Laboratories of the Royal Technical High School in Berlin and at Fort Hahneberg, as well as at numerous private engine works. The behavior of hydrogen during combustion in engines and its harmful effect under certain conditions, on the combustion in the engine cylinder are of general interest. Some of the results of these experiments are given here, in order to elucidate the main facts and explain much that is already a matter of experience with chauffeurs and pilots.

  18. Towards Sustainable Production of Formic Acid from Biomass for Getting Hydrogen and Fuels.

    Science.gov (United States)

    Bulushev, Dmitri; Ross, Julian R H

    2018-01-06

    Formic acid is a widely used commodity chemical. It can be used as a safe, easily handled and transported source of hydrogen or CO for different reactions including those producing fuels. The review includes historical aspects of formic acid production. It shortly analyzes the production based on traditional sources such as CO, methanol and methane. However, the main emphasis is done to the sustainable production of formic acid from biomass and biomass-derived products via hydrolysis, wet and catalytic oxidation processes. New strategies of low temperature synthesis from biomass may lead to utilization of formic acid for production of fuel additives such as methanol, upgraded bio-oil, gamma-valerolactone and its derivatives, as well as synthesis gas used for Fischer-Tropsch synthesis of hydrocarbons. Some technological aspects are considered. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. A quasi-Delphi study on technological barriers to the uptake of hydrogen as a fuel for transport applications : production, storage and fuel cell drivetrain considerations

    OpenAIRE

    Hart, David; Anghel, Alexandra T.; Huijsmans, Joep; Vuille, François

    2009-01-01

    The introduction of hydrogen in transport, particularly using fuel cell vehicles, faces a number of technical and non-technical hurdles. However, their relative importance is unclear, as are the levels of concern accorded them within the expert community conducting research and development within this area. To understand what issues are considered by experts working in the field to have significant potential to slow down or prevent the introduction of hydrogen technology in transport, a study...

  20. Characterization of a swept-strut hydrogen fuel-injector for scramjet applications

    Science.gov (United States)

    Northam, G. B.; Trexler, C. A.; Anderson, G. Y.

    1978-01-01

    Results of an experimental investigation of a swept-strut hydrogen fuel-injector simulating the center strut of a three strut scramjet module at Mach 6 flight conditions are presented. Detailed wall pressure distributions from over 100 separate tests with overall fuel flow from 0.1 to 1.3 times stoichiometric and test gas stagnation temperature from 1100 to 2400 K were recorded. The distance for pressure rise from the point of injection was found to increase with increasing test stagnation temperature. This trend indicates that chemical kinetics in the immediate region of perpendicular injection are not likely to be the mechanism controlling the onset of pressure rise. A fluid dynamic mechanism is suggested involving separation of the boundary layer downstream of injection which is forced upstream from the trailing edge by pressure rise due to combustion occurring in the base region of the strut. The results obtained indicate that the swept-strut fuel-injector concept can be adapted to a wide range of flight conditions by varying the amount of perpendicular fuel injection.

  1. Cryogenic hydrogen fuel for controlled inertial confinement fusion (formation of reactor-scale cryogenic targets)

    Energy Technology Data Exchange (ETDEWEB)

    Aleksandrova, I. V.; Koresheva, E. R., E-mail: elena.koresheva@gmail.com; Krokhin, O. N. [Russian Academy of Sciences, Lebedev Physical Institute (Russian Federation); Osipov, I. E. [Power Efficiency Centre, Inter RAO UES (Russian Federation)

    2016-12-15

    In inertial fusion energy research, considerable attention has recently been focused on low-cost fabrication of a large number of targets by developing a specialized layering module of repeatable operation. The targets must be free-standing, or unmounted. Therefore, the development of a target factory for inertial confinement fusion (ICF) is based on methods that can ensure a cost-effective target production with high repeatability. Minimization of the amount of tritium (i.e., minimization of time and space at all production stages) is a necessary condition as well. Additionally, the cryogenic hydrogen fuel inside the targets must have a structure (ultrafine layers—the grain size should be scaled back to the nanometer range) that supports the fuel layer survivability under target injection and transport through the reactor chamber. To meet the above requirements, significant progress has been made at the Lebedev Physical Institute (LPI) in the technology developed on the basis of rapid fuel layering inside moving free-standing targets (FST), also referred to as the FST layering method. Owing to the research carried out at LPI, unique experience has been gained in the development of the FST-layering module for target fabrication with an ultrafine fuel layer, including a reactor- scale target design. This experience can be used for the development of the next-generation FST-layering module for construction of a prototype of a target factory for power laser facilities and inertial fusion power plants.

  2. Test of Hydrogen-Oxygen PEM Fuel Cell Stack at NASA Glenn Research Center

    Science.gov (United States)

    Bents, David J.; Scullin, Vincent J.; Chang, Bei-Jiann; Johnson, Donald W.; Garcia, Christopher P.; Jakupca, Ian J.

    2003-01-01

    This paper describes performance characterization tests of a 64 cell hydrogen oxygen PEM fuel cell stack at NASA Glenn Research Center in February 2003. The tests were part of NASA's ongoing effort to develop a regenerative fuel cell for aerospace energy storage applications. The purpose of the tests was to verify capability of this stack to operate within a regenerative fuel cell, and to compare performance with earlier test results recorded by the stack developer. Test results obtained include polarization performance of the stack at 50 and 100 psig system pressure, and a steady state endurance run at 100 psig. A maximum power output of 4.8 kWe was observed during polarization runs, and the stack sustained a steady power output of 4.0 kWe during the endurance run. The performance data obtained from these tests compare reasonably close to the stack developer's results although some additional spread between best to worst performing cell voltages was observed. Throughout the tests, the stack demonstrated the consistent performance and repeatable behavior required for regenerative fuel cell operation.

  3. Gas phase recovery of hydrogen sulfide contaminated polymer electrolyte membrane fuel cells

    Science.gov (United States)

    Kakati, Biraj Kumar; Kucernak, Anthony R. J.

    2014-04-01

    The effect of hydrogen sulfide (H2S) on the anode of a polymer electrolyte membrane fuel cell (PEMFC) and the gas phase recovery of the contaminated PEMFC using ozone (O3) were studied. Experiments were performed on fuel cell electrodes both in an aqueous electrolyte and within an operating fuel cell. The ex-situ analyses of a fresh electrode; a H2S contaminated electrode (23 μmolH2S cm-2); and the contaminated electrode cleaned with O3 shows that all sulfide can be removed within 900 s at room temperature. Online gas analysis of the recovery process confirms the recovery time required as around 720 s. Similarly, performance studies of an H2S contaminated PEMFC shows that complete rejuvenation occurs following 600-900 s O3 treatment at room temperature. The cleaning process involves both electrochemical oxidation (facilitated by the high equilibrium potential of the O3 reduction process) and direct chemical oxidation of the contaminant. The O3 cleaning process is more efficient than the external polarization of the single cell at 1.6 V. Application of O3 at room temperature limits the amount of carbon corrosion. Room temperature O3 treatment of poisoned fuel cell stacks may offer an efficient and quick remediation method to recover otherwise inoperable systems.

  4. Economic and environmental comparison of conventional, hybrid, electric and hydrogen fuel cell vehicles

    Science.gov (United States)

    Granovskii, Mikhail; Dincer, Ibrahim; Rosen, Marc A.

    Published data from various sources are used to perform economic and environmental comparisons of four types of vehicles: conventional, hybrid, electric and hydrogen fuel cell. The production and utilization stages of the vehicles are taken into consideration. The comparison is based on a mathematical procedure, which includes normalization of economic indicators (prices of vehicles and fuels during the vehicle life and driving range) and environmental indicators (greenhouse gas and air pollution emissions), and evaluation of an optimal relationship between the types of vehicles in the fleet. According to the comparison, hybrid and electric cars exhibit advantages over the other types. The economic efficiency and environmental impact of electric car use depends substantially on the source of the electricity. If the electricity comes from renewable energy sources, the electric car is advantageous compared to the hybrid. If electricity comes from fossil fuels, the electric car remains competitive only if the electricity is generated on board. It is shown that, if electricity is generated with an efficiency of about 50-60% by a gas turbine engine connected to a high-capacity battery and an electric motor, the electric car becomes advantageous. Implementation of fuel cells stacks and ion conductive membranes into gas turbine cycles permits electricity generation to increase to the above-mentioned level and air pollution emissions to decrease. It is concluded that the electric car with on-board electricity generation represents a significant and flexible advance in the development of efficient and ecologically benign vehicles.

  5. Photocatalytic generation of hydrogen under visible light on La2CuO4

    Indian Academy of Sciences (India)

    Bull. Mater. Sci., Vol. 38, No. 4, August 2015, pp. 1043–1048. c Indian Academy of Sciences. Photocatalytic generation of hydrogen under visible light on La2CuO4. H LAHMAR and M TRARI. ∗. Laboratory of Storage and Valorization of Renewable Energies, Faculty of Chemistry (USTHB),. B.P. 32, 16111 Algiers, Algeria.

  6. Early-time photodynamics of ruthenium-based photocatalysts for light-induced hydrogen generation

    NARCIS (Netherlands)

    Pan, Qing

    2016-01-01

    This thesis aims to provide a fundamental understanding of the early-time photodynamics of a series of Ru/M (M = Pd or Pt) bimetallic photocatalysts for light-induced hydrogen generation. This class of complexes adopts a general structure involving a Ru(II) center coordinated to two peripheral

  7. CHOOSING OF PERFORMANCE PARAMETERS OF LIGHT-DUTY ENGINE RUNNING ON NATURAL GAS AND HYDROGEN MIXTURE

    Directory of Open Access Journals (Sweden)

    Y. Dube

    2011-01-01

    Full Text Available The results of investigation of light-duty gas engine running on natural gas and hydrogen mixture has been given. The mathematical model of combustion process with variable Vibe combus-tion factor for this engine type has been specified.

  8. Characterizing the V-band light-curves of hydrogen-rich type II supernovae

    DEFF Research Database (Denmark)

    Anderson, Joseph P.; González-Gaitán, Santiago; Hamuy, Mario

    2014-01-01

    We present an analysis of the diversity of V-band light-curves of hydrogen-rich type II supernovae. Analyzing a sample of 116 supernovae, several magnitude measurements are defined, together with decline rates at different epochs, and time durations of different phases. It is found that magnitude...

  9. Comparison of different mixed cultures for bio-hydrogen production from ground wheat starch by combined dark and light fermentation.

    Science.gov (United States)

    Ozmihci, Serpil; Kargi, Fikret

    2010-04-01

    Composition of the mixed culture was varied in combined dark-light fermentation of wheat powder starch in order to improve hydrogen gas formation rate and yield. Heat-treated anaerobic sludge and pure culture of Clostridium beijerinckii (DSMZ 791T) were combined with two different light fermentation bacteria of Rhodobacter sphaeroides (RS-NRRL and RS-RV) in order to select a more suitable mixture resulting in high hydrogen yield and formation rate. A combination of the anaerobic sludge and RS-NRRL yielded the highest cumulative hydrogen (CHF = 140 ml), the highest yield (0.36 mol H2 mol(-1) glucose) and specific hydrogen formation rate (2.5 ml H2 g(-1) biomass h(-1)). During dark fermentation (70 h) hydrogen was produced simultaneously by the dark and light fermentation bacteria using glucose from hydrolyzed starch. However, only light fermentation bacteria produced hydrogen from VFA's derived from dark fermentation after a long adaptation period.

  10. Surface modification of a proton exchange membrane and hydrogen storage in a metal hydride for fuel cells

    Science.gov (United States)

    Andrews, Lisa

    Interest in fuel cell technology is rising as a result of the need for more affordable and available fuel sources. Proton exchange membrane fuel cells involve the catalysis of a fuel to release protons and electrons. It requires the use of a polymer electrolyte membrane to transfer protons through the cell, while the electrons pass through an external circuit, producing electricity. The surface modification of the polymer, NafionRTM, commonly researched as a proton exchange membrane, may improve efficiency of a fuel cell. Surface modification can change the chemistry of the surface of a polymer while maintaining bulk properties. Plasma modification techniques such as microwave discharge of an argon and oxygen gas mixture as well as vacuum-ultraviolet (VUV) photolysis may cause favorable chemical and physical changes on the surface of Nafion for improved fuel cell function. A possible increase in hydrophilicity as a result of microwave discharge experiments may increase proton conductivity. Grafting of acrylic acid from the surface of modified Nafion may decrease the permeation of methanol in a direct methanol fuel cell, a process which can decrease efficiency. Modification of the surface of Nafion samples were carried out using: 1) An indirect Ar/O2 gas mixture plasma investigating the reaction of oxygen radicals with the surface, 2) A direct Ar/O2 gas mixture plasma investigating the reaction of oxygen radicals and VUV radiation with the surface and, 3) VUV photolysis investigating exclusively the interaction of VUV radiation with the surface and any possible oxidation upon exposure to air. Acrylic acid was grafted from the VUV photolysed Nafion samples. All treated surfaces were analyzed using X-ray photoelectron spectroscopy (XPS). Fourier transform infrared spectroscopy (FTIR) was used to analyze the grafted Nafion samples. Scanning electron microscopy (SEM) and contact angle measurements were used to analyze experiments 2 and 3. Using hydrogen as fuel is a

  11. Study on the Use of Hydride Fuel in High-Performance Light Water Reactor Concept

    OpenAIRE

    Haileyesus Tsige-Tamirat; Luca Ammirabile

    2015-01-01

    Hydride fuels have features which could make their use attractive in future advanced power reactors. The potential benefit of use of hydride fuel in HPLWR without introducing significant modification in the current core design concept of the high-performance light water reactor (HPLWR) has been evaluated. Neutronics and thermal hydraulic analyses were performed for a single assembly model of HPLWR with oxide and hydride fuels. The hydride assembly shows higher moderation with softer neutron s...

  12. Light-Duty Automotive Technology, Carbon Dioxide Emissions, and Fuel Economy Trends Data

    Data.gov (United States)

    U.S. Environmental Protection Agency — The Light-Duty Automotive Technology, Carbon Dioxide Emissions, and Fuel Economy Trends report is the authoritative reference for carbon dioxide (CO2) emissions,...

  13. Technology of the light water reactor fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Wymer, R. G.

    1979-01-01

    This essay presents elements of the processes used in the fuel cycle steps and gives an indication of the types of equipment used. The amounts of radioactivity released in normal operation of the processes are indicated and related to radiation doses. Types and costs of equipment or processes required to lower these radioactivity releases are in some cases suggested. Mining and milling, conversion of uranium concentrate to UF/sub 6/, uranium isotope separation, LWR fuel fabrication, fuel reprocessing, transportation, and waste management are covered in this essay. 40 figures, 34 tables. (DLC)

  14. A proposed model of factors influencing hydrogen fuel cell vehicle acceptance

    Science.gov (United States)

    Imanina, N. H. Noor; Kwe Lu, Tan; Fadhilah, A. R.

    2016-03-01

    Issues such as environmental problem and energy insecurity keep worsening as a result of energy use from household to huge industries including automotive industry. Recently, a new type of zero emission vehicle, hydrogen fuel cell vehicle (HFCV) has received attention. Although there are argues on the feasibility of hydrogen as the future fuel, there is another important issue, which is the acceptance of HFCV. The study of technology acceptance in the early stage is a vital key for a successful introduction and penetration of a technology. This paper proposes a model of factors influencing green vehicle acceptance, specifically HFCV. This model is built base on two technology acceptance theories and other empirical studies of vehicle acceptance. It aims to provide a base for finding the key factors influencing new sustainable energy fuelled vehicle, HFCV acceptance which is achieved by explaining intention to accept HFCV. Intention is influenced by attitude, subjective norm and perceived behavioural control from Theory of Planned Behaviour and personal norm from Norm Activation Theory. In the framework, attitude is influenced by perceptions of benefits and risks, and social trust. Perceived behavioural control is influenced by government interventions. Personal norm is influenced by outcome efficacy and problem awareness.

  15. Nitrogen-doped fullerene as a potential catalyst for hydrogen fuel cells.

    Science.gov (United States)

    Gao, Feng; Zhao, Guang-Lin; Yang, Shizhong; Spivey, James J

    2013-03-06

    We examine the possibility of nitrogen-doped C60 fullerene (N-C60) as a cathode catalyst for hydrogen fuel cells. We use first-principles spin-polarized density functional theory calculations to simulate the electrocatalytic reactions on N-C60. The first-principles results show that an O2 molecule can be adsorbed and partially reduced on the N-C complex sites (Pauling sites) of N-C60 without any activation barrier. Through a direct pathway, the partially reduced O2 can further react with H(+) and additional electrons and complete the water formation reaction (WFR) with no activation energy barrier. In the indirect pathway, reduced O2 reacts with H(+) and additional electrons to form H2O molecules through a transition state (TS) with a small activation barrier (0.22-0.37 eV). From an intermediate state to a TS, H(+) can obtain a kinetic energy of ∼0.95-3.68 eV, due to the Coulomb electric interaction, and easily overcome the activation energy barrier during the WFR. The full catalytic reaction cycles can be completed energetically, and N-C60 fullerene recovers to its original structure for the next catalytic reaction cycle. N-C60 fullerene is a potential cathode catalyst for hydrogen fuel cells.

  16. Lithium polymer batteries and proton exchange membrane fuel cells as energy sources in hydrogen electric vehicles

    Science.gov (United States)

    Corbo, P.; Migliardini, F.; Veneri, O.

    This paper deals with the application of lithium ion polymer batteries as electric energy storage systems for hydrogen fuel cell power trains. The experimental study was firstly effected in steady state conditions, to evidence the basic features of these systems in view of their application in the automotive field, in particular charge-discharge experiments were carried at different rates (varying the current between 8 and 100 A). A comparison with conventional lead acid batteries evidenced the superior features of lithium systems in terms of both higher discharge rate capability and minor resistance in charge mode. Dynamic experiments were carried out on the overall power train equipped with PEM fuel cell stack (2 kW) and lithium batteries (47.5 V, 40 Ah) on the European R47 driving cycle. The usage of lithium ion polymer batteries permitted to follow the high dynamic requirement of this cycle in hard hybrid configuration, with a hydrogen consumption reduction of about 6% with respect to the same power train equipped with lead acid batteries.

  17. A quasi-Delphi study on technological barriers to the uptake of hydrogen as a fuel for transport applications-Production, storage and fuel cell drivetrain considerations

    Science.gov (United States)

    Hart, David; Anghel, Alexandra T.; Huijsmans, Joep; Vuille, François

    The introduction of hydrogen in transport, particularly using fuel cell vehicles, faces a number of technical and non-technical hurdles. However, their relative importance is unclear, as are the levels of concern accorded them within the expert community conducting research and development within this area. To understand what issues are considered by experts working in the field to have significant potential to slow down or prevent the introduction of hydrogen technology in transport, a study was undertaken, primarily during 2007. Three key technology areas within hydrogen transport were selected - hydrogen storage, fuel cell drivetrains, and small-scale hydrogen production - and interviews with selected experts conducted. Forty-nine experts from 34 organisations within the fuel cell, automotive, industrial gas and other related industries participated, in addition to some key academic and government figures. The survey was conducted in China, Japan, North America and Europe, and analysed using conventional mathematical techniques to provide weighted and averaged rankings of issues viewed as important by the experts. It became clear both from the interviews and the subsequent analysis that while a primary concern in China was fundamental technical performance, in the other regions cost and policy were rated more highly. Although a few individual experts identified possible technical showstoppers, the overall message was that pre-commercial hydrogen fuel cell vehicles could realistically be on the road in tens of thousands within 5 years, and that full commercialisation could take place within 10-15 years, without the need for radical technical breakthroughs. Perhaps surprisingly, the performance of hydrogen storage technologies was not viewed as a showstopper, though cost was seen as a significant challenge. Overall, however, coherent policy development was more frequently identified as a major issue to address.

  18. Final Project Closeout Report for Sprint Hydrogen Fuel Cell (HFC) Deployment Project in California, Gulf Coast and Eastern Seaboard Markets

    Energy Technology Data Exchange (ETDEWEB)

    Kenny, Kevin [Sprint, Reston, VA (United States); Bradley, Dwayne [Burns & McDonnell, Kansas City, MO (United States)

    2015-09-01

    Sprint is one of the telecommunications industry leaders in the deployment of hydrogen fuel cell (HFC) systems to provide backup power for their mission critical wireless network facilities. With several hundred fuel cells commissioned in California, states in the gulf coast region, and along the upper eastern seaboard. A strong incentive for advancing the integration of fuel cells into the Sprint network came through the award of a Department of Energy (DOE) grant focused on Market Transformation activities for project (EE0000486). This grant was funded by the 2009 American Recovery and Reinvestment Act (ARRA). The funding provided by DOE ($7.295M) was allocated to support the installation of 260 new HFC systems, equipped with an on-site refillable Medium Pressure Hydrogen Storage Solution (MPHSS), as well as for the conversion of 21 low pressure hydrogen systems to the MPHSS, in hopes of reducing barriers to market acceptance.

  19. Ohio's first ethanol-fueled light-duty fleet

    Science.gov (United States)

    1998-12-31

    In 1996, the State of Ohio established a : project to demonstrate the effectiveness of : ethanol as an alternative to gasoline in : fleet operations. The state purchased and : incorporated a number of flexible-fuel : vehicles (FFVs) into its fleet. F...

  20. Fuel Cell Power Model Version 2: Startup Guide, System Designs, and Case Studies. Modeling Electricity, Heat, and Hydrogen Generation from Fuel Cell-Based Distributed Energy Systems

    Energy Technology Data Exchange (ETDEWEB)

    Steward, D.; Penev, M.; Saur, G.; Becker, W.; Zuboy, J.

    2013-06-01

    This guide helps users get started with the U.S. Department of Energy/National Renewable Energy Laboratory Fuel Cell Power (FCPower) Model Version 2, which is a Microsoft Excel workbook that analyzes the technical and economic aspects of high-temperature fuel cell-based distributed energy systems with the aim of providing consistent, transparent, comparable results. This type of energy system would provide onsite-generated heat and electricity to large end users such as hospitals and office complexes. The hydrogen produced could be used for fueling vehicles or stored for later conversion to electricity.

  1. Study on Doppler coefficient for metallic fuel fast reactor added hydrogeneous moderator

    Energy Technology Data Exchange (ETDEWEB)

    Hirakawa, Naohiro; Iwasaki, Tomohiko; Tsujimoto, Kazuhumi [Tohoku Univ., Sendai (Japan). Faculty of Engineering; Osugi, Toshitaka; Okajima, Shigeaki; Andoh, Masaki; Nemoto, Tatsuo; Mukaiyama, Takehiko

    1998-01-01

    A series of mock-up experiments for moderator added metallic fast reactor core was carried out at FCA to obtain the experimental verification for improvement of reactivity coefficients. Softened neutron spectrum increases Doppler effect by a factor of 2, and flatter adjoint neutron spectrum decreases Na void effect by a factor of 0.6 when hydrogen to heavy metal atomic number ratio is increased from 0.02 to 0.13. The experimental results are analyzed with SLALOM and CITATION-FBR, which is the standard design code system for a fast reactor at JAERI, and SRAC95 and CITATION-FBR. The present code system gives generally good agreement with the experimental results, especially by the use of the latter, the dependence of the Doppler effect to the hydrogen to fuel element atomic number density ratio is disappeared. Therefore, it looks possible to use the present code system for the conceptual design of a fast reactor system with hydrogeneous materials. (author)

  2. The production of hydrogen fuel from renewable sources and its role in grid operations

    Energy Technology Data Exchange (ETDEWEB)

    Barton, John [Centre for Renewable Energy Systems Technology (CREST), Holywell Park, Loughborough University, Loughborough, Leicestershire (United Kingdom); Gammon, Rupert [Bryte Energy Limited, Loughborough Innovation Centre, Epinal Way, Loughborough, Leicestershire (United Kingdom)

    2010-12-15

    Understanding the scale and nature of hydrogen's potential role in the development of low carbon energy systems requires an examination of the operation of the whole energy system, including heat, power, industrial and transport sectors, on an hour-by-hour basis. The Future Energy Scenario Assessment (FESA) software model used for this study is unique in providing a holistic, high resolution, functional analysis, which incorporates variations in supply resulting from weather-dependent renewable energy generators. The outputs of this model, arising from any given user-definable scenario, are year round supply and demand profiles that can be used to assess the market size and operational regime of energy technologies. FESA was used in this case to assess what - if anything - might be the role for hydrogen in a low carbon economy future for the UK. In this study, three UK energy supply pathways were considered, all of which reduce greenhouse gas emissions by 80% by 2050, and substantially reduce reliance on oil and gas while maintaining a stable electricity grid and meeting the energy needs of a modern economy. All use more nuclear power and renewable energy of all kinds than today's system. The first of these scenarios relies on substantial amounts of 'clean coal' in combination with intermittent renewable energy sources by year the 2050. The second uses twice as much intermittent renewable energy as the first and virtually no coal. The third uses 2.5 times as much nuclear power as the first and virtually no coal. All scenarios clearly indicate that the use of hydrogen in the transport sector is important in reducing distributed carbon emissions that cannot easily be mitigated by Carbon Capture and Storage (CCS). In the first scenario, this hydrogen derives mainly from steam reformation of fossil fuels (principally coal), whereas in the second and third scenarios, hydrogen is made mainly by electrolysis using variable surpluses of low

  3. The burnup dependence of light water reactor spent fuel oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Hanson, B.D.

    1998-07-01

    Over the temperature range of interest for dry storage or for placement of spent fuel in a permanent repository under the conditions now being considered, UO{sub 2} is thermodynamically unstable with respect to oxidation to higher oxides. The multiple valence states of uranium allow for the accommodation of interstitial oxygen atoms in the fuel matrix. A variety of stoichiometric and nonstoichiometric phases is therefore possible as the fuel oxidizers from UO{sub 2} to higher oxides. The oxidation of UO{sub 2} has been studied extensively for over 40 years. It has been shown that spent fuel and unirradiated UO{sub 2} oxidize via different mechanisms and at different rates. The oxidation of LWR spent fuel from UO{sub 2} to UO{sub 2.4} was studied previously and is reasonably well understood. The study presented here was initiated to determine the mechanism and rate of oxidation from UO{sub 2.4} to higher oxides. During the early stages of this work, a large variability in the oxidation behavior of samples oxidized under nearly identical conditions was found. Based on previous work on the effect of dopants on UO{sub 2} oxidation and this initial variability, it was hypothesized that the substitution of fission product and actinide impurities for uranium atoms in the spent fuel matrix was the cause of the variable oxidation behavior. Since the impurity concentration is roughly proportional to the burnup of a specimen, the oxidation behavior of spent fuel was expected to be a function of both temperature and burnup. This report (1) summarizes the previous oxidation work for both unirradiated UO{sub 2} and spent fuel (Section 2.2) and presents the theoretical basis for the burnup (i.e., impurity concentration) dependence of the rate of oxidation (Sections 2.3, 2.4, and 2.5), (2) describes the experimental approach (Section 3) and results (Section 4) for the current oxidation tests on spent fuel, and (3) establishes a simple model to determine the activation energies

  4. Gold nanoparticles produced in situ mediate bioelectricity and hydrogen production in a microbial fuel cell by quantized capacitance charging.

    Science.gov (United States)

    Kalathil, Shafeer; Lee, Jintae; Cho, Moo Hwan

    2013-02-01

    Oppan quantized style: By adding a gold precursor at its cathode, a microbial fuel cell (MFC) is demonstrated to form gold nanoparticles that can be used to simultaneously produce bioelectricity and hydrogen. By exploiting the quantized capacitance charging effect, the gold nanoparticles mediate the production of hydrogen without requiring an external power supply, while the MFC produces a stable power density. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Modeling, Control, and Simulation of a Solar Hydrogen/Fuel Cell Hybrid Energy System for Grid-Connected Applications

    OpenAIRE

    Tourkia Lajnef; Slim Abid; Anis Ammous

    2013-01-01

    Different energy sources and converters need to be integrated with each other for extended usage of alternative energy, in order to meet sustained load demands during various weather conditions. The objective of this paper is to associate photovoltaic generators, fuel cells, and electrolysers. Here, to sustain the power demand and solve the energy storage problem, electrical energy can be stored in the form of hydrogen. By using an electrolyser, hydrogen can be generated and stored for future...

  6. U.S. Department of Energy Hydrogen and Fuel Cells Program, 2013 Annual Merit Review and Peer Evaluation Report (Book)

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2013-10-01

    The fiscal year (FY) 2013 U.S. Department of Energy (DOE) Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting (AMR), in conjunction with DOE's Vehicle Technologies Office AMR, was held from May 13-16, 2013, at the Crystal City Marriott and Crystal Gateway Marriott in Arlington, Virginia. This report is a summary of comments by AMR peer reviewers about the hydrogen and fuel cell projects funded by DOE's Office of Energy Efficiency and Renewable Energy (EERE).

  7. Clean Cities Strategic Planning White Paper: Light Duty Vehicle Fuel Economy

    Energy Technology Data Exchange (ETDEWEB)

    Saulsbury, Bo [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Hopson, Dr Janet L [Univ. of Tennessee, Knoxville, TN (United States); Greene, David [Univ. of Tennessee, Knoxville, TN (United States); Gibson, Robert [Univ. of Tennessee, Knoxville, TN (United States)

    2015-04-01

    Increasing the energy efficiency of motor vehicles is critical to achieving national energy goals of reduced petroleum dependence, protecting the global climate, and promoting continued economic prosperity. Even with fuel economy and greenhouse gas emissions standards and various economic incentives for clean and efficient vehicles, providing reliable and accurate fuel economy information to the public is important to achieving these goals. This white paper reviews the current status of light-duty vehicle fuel economy in the United States and the role of the Department of Energy (DOE) Clean Cities Program in disseminating fuel economy information to the public.

  8. Hydrogen-Oxygen PEM Regenerative Fuel Cell Development at NASA Glenn Research Center

    Science.gov (United States)

    Bents, David J.; Scullin, Vincent J.; Chang, B. J.; Johnson, Donald W.; Garcia, Christopher P.; Jakupca, Ian J.

    2006-01-01

    The closed-cycle hydrogen-oxygen PEM regenerative fuel cell (RFC) at NASA Glenn Research Center has demonstrated multiple back to back contiguous cycles at rated power, and round trip efficiencies up to 52 percent. It is the first fully closed cycle regenerative fuel cell ever demonstrated (entire system is sealed: nothing enters or escapes the system other than electrical power and heat). During FY2006 the system has undergone numerous modifications and internal improvements aimed at reducing parasitic power, heat loss and noise signature, increasing its functionality as an unattended automated energy storage device, and in-service reliability. It also serves as testbed towards development of a 600 W-hr/kg flight configuration, through the successful demonstration of lightweight fuel cell and electrolyser stacks and supporting components. The RFC has demonstrated its potential as an energy storage device for aerospace solar power systems such as solar electric aircraft, lunar and planetary surface installations; any airless environment where minimum system weight is critical. Its development process continues on a path of risk reduction for the flight system NASA will eventually need for the manned lunar outpost.

  9. NanoCapillary Network Proton Conducting Membranes for High Temperature Hydrogen/Air Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Pintauro, Peter [Vanderbilt Univ., Nashville, TN (United States)

    2012-07-09

    The objective of this proposal is to fabricate and characterize a new class of NanoCapillary Network (NCN) proton conducting membranes for hydrogen/air fuel cells that operate under high temperature, low humidity conditions. The membranes will be intelligently designed, where a high density interconnecting 3-D network of nm-diameter electrospun proton conducting polymer fibers is embedded in an inert (uncharged) water/gas impermeable polymer matrix. The high density of fibers in the resulting mat and the high ion-exchange capacity of the fiber polymer will ensure high proton conductivity. To further enhance water retention, molecular silica will be added to the sulfonated polymer fibers. The uncharged matrix material will control water swelling of the high ion-exchange capacity proton conducting polymer fibers and will impart toughness to the final nanocapillary composite membrane. Thus, unlike other fuel cell membranes, the role of the polymer support matrix will be decoupled from that of the proton-conducting channels. The expected final outcome of this 5-year project is the fabrication of fuel cell membranes with properties that exceed the DOE’s technical targets, in particular a proton conductivity of 0.1 S/cm at a temperature less than or equal to120°C and 25-50% relative humidity.

  10. Study of Systems and Technology for Liquid Hydrogen Production Independent of Fossil Fuels

    Science.gov (United States)

    Sprafka, R. J.; Escher, W. J. D.; Foster, R. W.; Tison, R. R.; Shingleton, J.; Moore, J. S.; Baker, C. R.

    1983-01-01

    Based on Kennedy Space Center siting and logistics requirements and the nonfossil energy resources at the Center, a number of applicable technologies and system candidates for hydrogen production were identified and characterized. A two stage screening of these technologies in the light of specific criteria identified two leading candidates as nonfossil system approaches. Conceptual design and costing of two solar-operated, stand alone systems, one photovoltaic based on and the other involving the power tower approach reveals their technical feasibility as sited as KSC, and the potential for product cost competitiveness with conventional supply approaches in the 1990 to 1210 time period. Conventional water hydrolysis and hydrogen liquefaction subsystems are integrated with the solar subsystems.

  11. Application of Hydrogen Assisted Lean Operation to Natural Gas-Fueled Reciprocating Engines (HALO)

    Energy Technology Data Exchange (ETDEWEB)

    Chad Smutzer

    2006-01-01

    Two key challenges facing Natural Gas Engines used for cogeneration purposes are spark plug life and high NOx emissions. Using Hydrogen Assisted Lean Operation (HALO), these two keys issues are simultaneously addressed. HALO operation, as demonstrated in this project, allows stable engine operation to be achieved at ultra-lean (relative air/fuel ratios of 2) conditions, which virtually eliminates NOx production. NOx values of 10 ppm (0.07 g/bhp-hr NO) for 8% (LHV H2/LHV CH4) supplementation at an exhaust O2 level of 10% were demonstrated, which is a 98% NOx emissions reduction compared to the leanest unsupplemented operating condition. Spark ignition energy reduction (which will increase ignition system life) was carried out at an oxygen level of 9%, leading to a NOx emission level of 28 ppm (0.13 g/bhp-hr NO). The spark ignition energy reduction testing found that spark energy could be reduced 22% (from 151 mJ supplied to the coil) with 13% (LHV H2/LHV CH4) hydrogen supplementation, and even further reduced 27% with 17% hydrogen supplementation, with no reportable effect on NOx emissions for these conditions and with stable engine torque output. Another important result is that the combustion duration was shown to be only a function of hydrogen supplementation, not a function of ignition energy (until the ignitability limit was reached). The next logical step leading from these promising results is to see how much the spark energy reduction translates into increase in spark plug life, which may be accomplished by durability testing.

  12. The electrification of the powertrain system. Is the battery the death of the hydrogen fuel cell?; Die Elektrifizierung des Antriebsstranges. Ist die Batterie der Tod der Brennstoffzelle?

    Energy Technology Data Exchange (ETDEWEB)

    Steiger, W.; Scholz, I.; Riemann, A. [Volkswagen AG, Wolfsburg (Germany)

    2007-07-01

    Within this paper the strategies to realize a holistic steel lightweight concept were explained. The overview about the relevant basic principles starts with the right choice of suitable steel materials and the utilization of appropriate manufacturing technologies and ends up in conceptual light weight design with regard to geometry and construction principle. For explanation possibilities for the design of a body in white structure were discussed, e.g. the application of tailored products, the realization of straight members and the evolution to complex frame structures and the reduction of doubled layers and intersections. With the use of examples the additional benefits of these conceptual ideas will be shown in detail. Furthermore a short outlook concerning the development of steel products will be given, which enlarges continuously the light weight potential of the material steel in future. The question then arises as to the production of hydrogen. When making hydrogen using natural gas steam reforming, a similarly good CO2 balance is achieved for the fuel cells as for the all electric traction based on the European power mix. This result allows both types of powertrains to coexist. Batteries will show sufficient energy density for a maximum mileage of 200 km enough for today and future Mega- Cities. In the city's surroundings, with distances of up to 400 km, a market for the fuel cells may develop, primarily as a range extender. For longer mobility with distances of more than 400 km, there is no real alternative to the combustion engine with liquid hydrocarbons. It can be seen that the maximum distance for local emission-free mobility cannot be optimally provided by electrical storage technology alone. In fact, it is the combination of electrical energy storage and fuel cells which ensures short and medium range mobility. So, future focal points for research and development must be in the area of electrical storage, as well as fuel cell technology. (orig.)

  13. Integration and dynamics of a renewable regenerative hydrogen fuel cell system

    Science.gov (United States)

    Bergen, Alvin Peter

    2008-10-01

    This thesis explores the integration and dynamics of residential scale renewable-regenerative energy systems which employ hydrogen for energy buffering. The development of the Integrated Renewable Energy Experiment (IRENE) test-bed is presented. IRENE is a laboratory-scale distributed energy system with a modular structure which can be readily re-configured to test newly developed components for generic regenerative systems. Key aspects include renewable energy conversion, electrolysis, hydrogen and electricity storage, and fuel cells. A special design feature of this test bed is the ability to accept dynamic inputs from and provide dynamic loads to real devices as well as from simulated energy sources/sinks. The integration issues encountered while developing IRENE and innovative solutions devised to overcome these barriers are discussed. Renewable energy systems that employ a regenerative approach to enable intermittent energy sources to service time varying loads rely on the efficient transfer of energy through the storage media. Experiments were conducted to evaluate the performance of the hydrogen energy buffer under a range of dynamic operating conditions. Results indicate that the operating characteristics of the electrolyser under transient conditions limit the production of hydrogen from excess renewable input power. These characteristics must be considered when designing or modeling a renewable-regenerative system. Strategies to mitigate performance degradation due to interruptions in the renewable power supply are discussed. Experiments were conducted to determine the response of the IRENE system to operating conditions that are representative of a residential scale, solar based, renewable-regenerative system. A control algorithm, employing bus voltage constraints and device current limitations, was developed to guide system operation. Results for a two week operating period that indicate that the system response is very dynamic but repeatable are

  14. Development of a Low NOx Medium sized Industrial Gas Turbine Operating on Hydrogen-Rich Renewable and Opportunity Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Srinivasan, Ram

    2013-07-31

    This report presents the accomplishments at the completion of the DOE sponsored project (Contract # DE-FC26-09NT05873) undertaken by Solar Turbines Incorporated. The objective of this 54-month project was to develop a low NOx combustion system for a medium sized industrial gas turbine engine operating on Hydrogen-rich renewable and opportunity Fuels. The work in this project was focused on development of a combustion system sized for 15MW Titan 130 gas turbine engine based on design analysis and rig test results. Although detailed engine evaluation of the complete system is required prior to commercial application, those tasks were beyond the scope of this DOE sponsored project. The project tasks were organized in three stages, Stages 2 through 4. In Stage 2 of this project, Solar Turbines Incorporated characterized the low emission capability of current Titan 130 SoLoNOx fuel injector while operating on a matrix of fuel blends with varying Hydrogen concentration. The mapping in this phase was performed on a fuel injector designed for natural gas operation. Favorable test results were obtained in this phase on emissions and operability. However, the resulting fuel supply pressure needed to operate the engine with the lower Wobbe Index opportunity fuels would require additional gas compression, resulting in parasitic load and reduced thermal efficiency. In Stage 3, Solar characterized the pressure loss in the fuel injector and developed modifications to the fuel injection system through detailed network analysis. In this modification, only the fuel delivery flowpath was modified and the air-side of the injector and the premixing passages were not altered. The modified injector was fabricated and tested and verified to produce similar operability and emissions as the Stage 2 results. In parallel, Solar also fabricated a dual fuel capable injector with the same air-side flowpath to improve commercialization potential. This injector was also test verified to produce 15

  15. Mechanism of soft x-ray continuum radiation from low-energy pinch discharges of hydrogen and ultra-low field ignition of solid fuels

    Science.gov (United States)

    Mills, R.; Lotoski, J.; Lu, Y.

    2017-09-01

    EUV continuum radiation (10-30 nm) arising only from very low energy pulsed pinch gas discharges comprising some hydrogen was first observed at BlackLight Power, Inc. and reproduced at the Harvard Center for Astrophysics (CfA). The source was determined to be due to the transition of H to the lower-energy hydrogen or hydrino state H(1/4) whose emission matches that observed wherein alternative sources were eliminated. The identity of the catalyst that accepts 3 · 27.2 eV from the H to cause the H to H(1/4) transition was determined to HOH versus 3H. The mechanism was elucidated using different oxide-coated electrodes that were selective in forming HOH versus plasma forming metal atoms as well as from the intensity profile that was a mismatch for the multi-body reaction required during 3H catalysis. The HOH catalyst was further shown to give EUV radiation of the same nature by igniting a solid fuel comprising a source of H and HOH catalyst by passing a low voltage, high current through the fuel to produce explosive plasma. No chemical reaction can release such high-energy light. No high field existed to form highly ionized ions that could give radiation in this EUV region that persisted even without power input. This plasma source serves as strong evidence for the existence of the transition of H to hydrino H(1/4) by HOH as the catalyst and a corresponding new power source wherein initial extraordinarily brilliant light-emitting prototypes are already producing photovoltaic generated electrical power. The hydrino product of a catalyst reaction of atomic hydrogen was analyzed by multiple spectroscopic techniques. Moreover, the mH catalyst was identified to be active in astronomical sources such as the Sun, stars and interstellar medium wherein the characteristics of hydrino match those of the dark matter of the Universe.

  16. Visible light-induced enzymatic hydrogen production from oligosaccharides using Mg chlorophyll-a and platinum colloid conjugate system

    Energy Technology Data Exchange (ETDEWEB)

    Saiki, Yoshinobu; Amao, Yutaka [Oita Univ. (Japan). Dept. of Applied Chemistry

    2004-07-01

    Visible light-induced enzymatic hydrogen production coupling the enzymatic oligosaccharide degradation and hydrogen production with platinum colloid using the photosensitization of Mg chlorophyll-a (Mg Chl-a) has been developed. The continuous hydrogen gas production was observed when the reaction mixture containing oligosaccharide (sucrose or maltose), invertase, glucose dehydrogenase, nicotinamide adenine dinucleotide (NAD{sup +}), Mg Chl-a, methylviologen (MV{sup 2+}, an electron relay reagent) and platinum colloid was irradiated by visible light. After 420 min irradiation, the amounts of hydrogen production from sucrose and from maltose were estimated to be 4.3 and 0.40 {mu}mol, respectively. (Author)

  17. U.S. Department of Energy Hydrogen and Fuel Cells Program 2012 Annual Merit Review and Peer Evaluation Report: May 14-18, 2012, Arlington, VA

    Energy Technology Data Exchange (ETDEWEB)

    2012-09-01

    This document summarizes the comments provided by peer reviewers on hydrogen and fuel cell projects presented at the fiscal year (FY) 2012 U.S. Department of Energy (DOE) Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting (AMR), held May 14-18, 2012, in Arlington, VA.

  18. Nuclear-Renewable Hybrid System Economic Basis for Electricity, Fuel, and Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Charles Forsberg; Steven Aumeier

    2014-04-01

    Concerns about climate change and altering the ocean chemistry are likely to limit the use of fossil fuels. That implies a transition to a low-carbon nuclear-renewable electricity grid. Historically variable electricity demand was met using fossil plants with low capital costs, high operating costs, and substantial greenhouse gas emissions. However, the most easily scalable very-low-emissions generating options, nuclear and non-dispatchable renewables (solar and wind), are capital-intensive technologies with low operating costs that should operate at full capacities to minimize costs. No combination of fully-utilized nuclear and renewables can meet the variable electricity demand. This implies large quantities of expensive excess generating capacity much of the time. In a free market this results in near-zero electricity prices at times of high nuclear renewables output and low electricity demand with electricity revenue collapse. Capital deployment efficiency—the economic benefit derived from energy systems capital investment at a societal level—strongly favors high utilization of these capital-intensive systems, especially if low-carbon nuclear renewables are to replace fossil fuels. Hybrid energy systems are one option for better utilization of these systems that consumes excess energy at times of low prices to make some useful product.The economic basis for development of hybrid energy systems is described for a low-carbon nuclear renewable world where much of the time there are massivequantities of excess energy available from the electric sector.Examples include (1) high-temperature electrolysis to generate hydrogen for non-fossil liquid fuels, direct use as a transport fuel, metal reduction, etc. and (2) biorefineries.Nuclear energy with its concentrated constant heat output may become the enabling technology for economically-viable low-carbon electricity grids because hybrid nuclear systems may provide an economic way to produce dispatachable variable

  19. Drinking water purification by electrosynthesis of hydrogen peroxide in a power-producing PEM fuel cell.

    Science.gov (United States)

    Li, Winton; Bonakdarpour, Arman; Gyenge, Előd; Wilkinson, David P

    2013-11-01

    The industrial anthraquinone auto-oxidation process produces most of the world's supply of hydrogen peroxide. For applications that require small amounts of H2 O2 or have economically difficult transportation means, an alternate, on-site H2 O2 production method is needed. Advanced drinking water purification technologies use neutral-pH H2 O2 in combination with UV treatment to reach the desired water purity targets. To produce neutral H2 O2 on-site and on-demand for drinking water purification, the electroreduction of oxygen at the cathode of a proton exchange membrane (PEM) fuel cell operated in either electrolysis (power consuming) or fuel cell (power generating) mode could be a possible solution. The work presented here focuses on the H2 /O2 fuel cell mode to produce H2 O2 . The fuel cell reactor is operated with a continuous flow of carrier water through the cathode to remove the product H2 O2 . The impact of the cobalt-carbon composite cathode catalyst loading, Teflon content in the cathode gas diffusion layer, and cathode carrier water flowrate on the production of H2 O2 are examined. H2 O2 production rates of up to 200 μmol h(-1)  cmgeometric (-2) are achieved using a continuous flow of carrier water operating at 30 % current efficiency. Operation times of more than 24 h have shown consistent H2 O2 and power production, with no degradation of the cobalt catalyst. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Energy conversion, storage and balancing. Great potential of hydrogen and fuel cells; Energikonvertering, lagring og balancering. Stort potentiale i brint og braendselsceller

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-12-15

    This document is the Danish strategy for hydrogen technology research, development and demonstration. Work on a new strategy was launched in early 2012 by the Partnership for hydrogen and fuel cells. The new national strategy complements the Partnership's former national strategy ''Hydrogen Technologies - strategy for research, development and demonstration in Denmark'' from June 2005. The former strategy describes the challenges and costs by the technological development of hydrogen and fuel cells until 2016 - and is valid until 2016. The Partnership's strategy anno 2012 describes the energy technology challenges for hydrogen technology development until 2016 - and in some years thereafter. The strategy provides an updated status of hydrogen and fuel cells, describes the area's future potential, and specifies future needs for technological development. The strategy's main focus is to define how electrolysis, hydrogen and fuel cells can help to meet Denmark's future energy policy objectives. In the strategy the term ''hydrogen technologies'' overall means: Electrolysis and fuel cells as conversion technologies, and hydrogen and hydrogen-containing fuels, such as methanol, as energy carriers. (LN)

  1. Three-dimensional fuel pin model validation by prediction of hydrogen distribution in cladding and comparison with experiment

    Energy Technology Data Exchange (ETDEWEB)

    Aly, A. [North Carolina State Univ., Raleigh, NC (United States); Avramova, Maria [North Carolina State Univ., Raleigh, NC (United States); Ivanov, Kostadin [Pennsylvania State Univ., University Park, PA (United States); Motta, Arthur [Pennsylvania State Univ., University Park, PA (United States); Lacroix, E. [Pennsylvania State Univ., University Park, PA (United States); Manera, Annalisa [Univ. of Michigan, Ann Arbor, MI (United States); Walter, D. [Univ. of Michigan, Ann Arbor, MI (United States); Williamson, R. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Gamble, K. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2017-10-29

    To correctly describe and predict this hydrogen distribution there is a need for multi-physics coupling to provide accurate three-dimensional azimuthal, radial, and axial temperature distributions in the cladding. Coupled high-fidelity reactor-physics codes with a sub-channel code as well as with a computational fluid dynamics (CFD) tool have been used to calculate detailed temperature distributions. These high-fidelity coupled neutronics/thermal-hydraulics code systems are coupled further with the fuel-performance BISON code with a kernel (module) for hydrogen. Both hydrogen migration and precipitation/dissolution are included in the model. Results from this multi-physics analysis is validated utilizing calculations of hydrogen distribution using models informed by data from hydrogen experiments and PIE data.

  2. Molecular Beam-Thermal Desorption Spectrometry (MB-TDS) Monitoring of Hydrogen Desorbed from Storage Fuel Cell Anodes.

    Science.gov (United States)

    Lobo, Rui F M; Santos, Diogo M F; Sequeira, Cesar A C; Ribeiro, Jorge H F

    2012-02-06

    Different types of experimental studies are performed using the hydrogen storage alloy (HSA) MlNi3.6Co0.85Al0.3Mn0.3 (Ml: La-rich mischmetal), chemically surface treated, as the anode active material for application in a proton exchange membrane fuel cell (PEMFC). The recently developed molecular beam-thermal desorption spectrometry (MB-TDS) technique is here reported for detecting the electrochemical hydrogen uptake and release by the treated HSA. The MB-TDS allows an accurate determination of the hydrogen mass absorbed into the hydrogen storage alloy (HSA), and has significant advantages in comparison with the conventional TDS method. Experimental data has revealed that the membrane electrode assembly (MEA) using such chemically treated alloy presents an enhanced surface capability for hydrogen adsorption.

  3. Molecular Beam-Thermal Desorption Spectrometry (MB-TDS Monitoring of Hydrogen Desorbed from Storage Fuel Cell Anodes

    Directory of Open Access Journals (Sweden)

    Jorge H. F. Ribeiro

    2012-02-01

    Full Text Available Different types of experimental studies are performed using the hydrogen storage alloy (HSA MlNi3.6Co0.85Al0.3Mn0.3 (Ml: La-rich mischmetal, chemically surface treated, as the anode active material for application in a proton exchange membrane fuel cell (PEMFC. The recently developed molecular beam—thermal desorption spectrometry (MB-TDS technique is here reported for detecting the electrochemical hydrogen uptake and release by the treated HSA. The MB-TDS allows an accurate determination of the hydrogen mass absorbed into the hydrogen storage alloy (HSA, and has significant advantages in comparison with the conventional TDS method. Experimental data has revealed that the membrane electrode assembly (MEA using such chemically treated alloy presents an enhanced surface capability for hydrogen adsorption.

  4. Molecular Beam-Thermal Desorption Spectrometry (MB-TDS) Monitoring of Hydrogen Desorbed from Storage Fuel Cell Anodes

    Science.gov (United States)

    Lobo, Rui F. M.; Santos, Diogo M. F.; Sequeira, Cesar A. C.; Ribeiro, Jorge H. F.

    2012-01-01

    Different types of experimental studies are performed using the hydrogen storage alloy (HSA) MlNi3.6Co0.85Al0.3Mn0.3 (Ml: La-rich mischmetal), chemically surface treated, as the anode active material for application in a proton exchange membrane fuel cell (PEMFC). The recently developed molecular beam—thermal desorption spectrometry (MB-TDS) technique is here reported for detecting the electrochemical hydrogen uptake and release by the treated HSA. The MB-TDS allows an accurate determination of the hydrogen mass absorbed into the hydrogen storage alloy (HSA), and has significant advantages in comparison with the conventional TDS method. Experimental data has revealed that the membrane electrode assembly (MEA) using such chemically treated alloy presents an enhanced surface capability for hydrogen adsorption. PMID:28817043

  5. Micropower chemical fuel-to-electric conversion : a "regenerative flip" hydrogen concentration cell promising near carnot efficiency.

    Energy Technology Data Exchange (ETDEWEB)

    Wally, Karl

    2006-05-01

    Although battery technology is relatively mature, power sources continue to impose serious limitations for small, portable, mobile, or remote applications. A potentially attractive alternative to batteries is chemical fuel-to-electric conversion. Chemical fuels have volumetric energy densities 4 to 10 times those of batteries. However, realizing this advantage requires efficient chemical fuel-to-electric conversion. Direct electrochemical conversion would be the ideal, but, for most fuels, is generally not within the state-of-the-science. Next best, chemical-to-thermal-to-electric conversion can be attractive if efficiencies can be kept high. This small investigative project was an exploration into the feasibility of a novel hybrid (i.e., thermal-electrochemical) micropower converter of high theoretical performance whose demonstration was thought to be within near-term reach. The system is comprised of a hydrogen concentration electrochemical cell with physically identical hydrogen electrodes as anode and cathode, with each electrode connected to physically identical hydride beds each containing the same low-enthalpy-of-formation metal hydride. In operation, electrical power is generated by a hydrogen concentration differential across the electrochemical cell. This differential is established via coordinated heating and passive cooling of the corresponding hydride source and sink. Heating is provided by the exothermic combustion (i.e., either flame combustion or catalytic combustion) of a chemical fuel. Upon hydride source depletion, the role of source and sink are reversed, heating and cooling reversed, electrodes commutatively reversed, cell operation reversed, while power delivery continues unchanged. This 'regenerative flip' of source and sink hydride beds can be cycled continuously until all available heating fuel is consumed. Electricity is efficiently generated electrochemically, but hydrogen is not consumed, rather the hydrogen is regeneratively

  6. Conference on researches and industrial outlooks on fuel cell and hydrogen; Recherches et perspectives industrielles sur la pile a combustible et l'hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    This conference aimed at presenting a panorama concerning the research and development of fuel cells and hydrogen and the associated regulation landscape. The first sessions concerned the industrial offer: the strategic advantages as a vehicle fuel, the equipment and the technology, the micro-cell. The second part of the conference concerned the society demand, the difficulties and the research and development programs: the parliamentary offer for the scientific and technological choices evaluation, the energy vector choice, the experiments in particular in Germany, the regulations. (A.L.B.)

  7. Characterizing the V-band light-curves of hydrogen-rich type II supernovae

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Joseph P.; González-Gaitán, Santiago; Hamuy, Mario; Gutiérrez, Claudia P.; Antezana, Roberto; De Jaeger, Thomas; Förster, Francisco; González, Luis [Departamento de Astronomía, Universidad de Chile, Casilla 36-D, Santiago (Chile); Stritzinger, Maximilian D.; Contreras, Carlos [Department of Physics and Astronomy, Aarhus University, Ny Munkegade 120, DK-8000 Aarhus C (Denmark); Olivares E, Felipe [Departamento de Ciencias Fisicas, Universidad Andres Bello, Avda. Republica 252, Santiago (Chile); Phillips, Mark M.; Campillay, Abdo; Castellón, Sergio; Hsiao, Eric [Carnegie Observatories, Las Campanas Observatory, Casilla 601, La Serena (Chile); Schulze, Steve [Instituto de Astrofísica, Facultad de Física, Pontifícia Universidad Católica de Chile, Casilla 306, Santiago 22 (Chile); Bolt, Luis [Argelander Institut für Astronomie, Universität Bonn, Auf dem Hügel 71, D-53111 Bonn (Germany); Folatelli, Gastón [Institute for the Physics and Mathematics of the Universe (IPMU), University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8583 (Japan); Freedman, Wendy L. [Observatories of the Carnegie Institution for Science, Pasadena, CA 91101 (United States); Krzemiński, Wojtek, E-mail: janderso@eso.org [N. Copernicus Astronomical Center, ul. Bartycka 18, 00-716 Warszawa (Poland); and others

    2014-05-01

    We present an analysis of the diversity of V-band light-curves of hydrogen-rich type II supernovae. Analyzing a sample of 116 supernovae, several magnitude measurements are defined, together with decline rates at different epochs, and time durations of different phases. It is found that magnitudes measured at maximum light correlate more strongly with decline rates than those measured at other epochs: brighter supernovae at maximum generally have faster declining light-curves at all epochs. We find a relation between the decline rate during the 'plateau' phase and peak magnitudes, which has a dispersion of 0.56 mag, offering the prospect of using type II supernovae as purely photometric distance indicators. Our analysis suggests that the type II population spans a continuum from low-luminosity events which have flat light-curves during the 'plateau' stage, through to the brightest events which decline much faster. A large range in optically thick phase durations is observed, implying a range in progenitor envelope masses at the epoch of explosion. During the radioactive tails, we find many supernovae with faster declining light-curves than expected from full trapping of radioactive emission, implying low mass ejecta. It is suggested that the main driver of light-curve diversity is the extent of hydrogen envelopes retained before explosion. Finally, a new classification scheme is introduced where hydrogen-rich events are typed as simply 'SN II' with an 's {sub 2}' value giving the decline rate during the 'plateau' phase, indicating its morphological type.

  8. Comparison of prediction models for Cherenkov light emissions from nuclear fuel assemblies

    Science.gov (United States)

    Branger, E.; Grape, S.; Jacobsson Svärd, S.; Jansson, P.; Andersson Sundén, E.

    2017-06-01

    The Digital Cherenkov Viewing Device (DCVD) [1] is a tool used by nuclear safeguards inspectors to verify irradiated nuclear fuel assemblies in wet storage based on the Cherenkov light produced by the assembly. Verifying that no rods have been substituted in the fuel, so-called partial-defect verification, is done by comparing the intensity measured with a DCVD with a predicted intensity, based on operator fuel declaration. The prediction model currently used by inspectors is based on simulations of Cherenkov light production in a BWR 8x8 geometry. This work investigates prediction models based on simulated Cherenkov light production in a BWR 8x8 and a PWR 17x17 assembly, as well as a simplified model based on a single rod in water. Cherenkov light caused by both fission product gamma and beta decays was considered. The simulations reveal that there are systematic differences between the model used by safeguards inspectors and the models described in this publication, most noticeably with respect to the fuel assembly cooling time. Consequently, if the intensity predictions are based on another fuel type than the fuel type being measured, a systematic bias in intensity with respect to burnup and cooling time is introduced. While a simplified model may be accurate enough for a set of fuel assemblies with nearly identical cooling times, the prediction models may differ systematically by up to 18 % for fuels with more varied cooling times. Accordingly, these investigations indicate that the currently used model may need to be exchanged with a set of more detailed, fuel-type specific models, in order minimize the model dependent systematic deviations.

  9. Computed tomography measurement of gaseous fuel concentration by infrared laser light absorption

    Science.gov (United States)

    Kawazoe, Hiromitsu; Inagaki, Kazuhisa; Emi, Y.; Yoshino, Fumio

    1997-11-01

    A system to measure gaseous hydrocarbon distributions was devised, which is based on IR light absorption by C-H stretch mode of vibration and computed tomography method. It is called IR-CT method in the paper. Affection of laser light power fluctuation was diminished by monitoring source light intensity by the second IR light detector. Calibration test for methane fuel was carried out to convert spatial data of line absorption coefficient into quantitative methane concentration. This system was applied to three flow fields. The first is methane flow with lifted flame which is generated by a gourd-shaped fuel nozzle. Feasibility of the IR-CT method was confirmed through the measurement. The second application is combustion field with diffusion flame. Calibration to determine absorptivity was undertaken, and measured line absorption coefficient was converted spatial fuel concentration using corresponding temperature data. The last case is modeled in cylinder gas flow of internal combustion engine, where gaseous methane was led to the intake valve in steady flow state. The fuel gas flow simulates behavior of gaseous gasoline which is evaporated at intake valve tulip. Computed tomography measurement of inner flow is essentially difficult because of existence of surrounding wall. In this experiment, IR laser beam was led to planed portion by IR light fiber. It is found that fuel convection by airflow takes great part in air-fuel mixture formation and the developed IR-CT system to measure fuel concentration is useful to analyze air-fuel mixture formation process and to develop new combustors.

  10. The effect of dissolved hydrogen on the dissolution of {sup 233}U doped UO{sub 2}(s) high burn-up spent fuel and MOX fuel

    Energy Technology Data Exchange (ETDEWEB)

    Carbol, P. [Inst. for Transuranium Elements, Karlsruhe (Germany); Spahiu, K. (ed.) [and others

    2005-03-01

    In this report the results of the experimental work carried out in a large EU-research project (SFS, 2001-2004) on spent fuel stability in the presence of various amounts of near field hydrogen are presented. Studies of the dissolution of {sup 233}U doped UO{sub 2}(s) simulating 'old' spent fuel were carried out as static leaching tests, autoclave tests with various hydrogen concentrations and electrochemical tests. The results of the leaching behaviour of a high burn-up spent fuel pellet in 5 M NaCl solutions in the presence of 3.2 bar H{sub 2} pressure and of MOX fuel in dilute synthetic groundwater under 53 bar H{sub 2} pressure are also presented. In all the experimental studies carried out in this project, a considerable effect of hydrogen in the dissolution rates of radioactive materials was observed. The experimental results obtained in this project with a-doped UO{sub 2}, high burn-up spent fuel and MOX fuel together with literature data give a reliable background to use fractional alteration/dissolution rates for spent fuel of the order of 10{sup -6}/yr - 10{sup -8}/yr with a recommended value of 4x10{sup -7}/yr for dissolved hydrogen concentrations above 10{sup -3} M and Fe(II) concentrations typical for European repository concepts. Finally, based on a review of the experimental data and available literature data, potential mechanisms of the hydrogen effect are also discussed. The work reported in this document was performed as part of the Project SFS of the European Commission 5th Framework Programme under contract no FIKW-CT-2001-20192 SFS. It represents the deliverable D10 of the experimental work package 'Key experiments using a-doped UO{sub 2} and real spent fuel', coordinated by SKB with the participation of ITU, FZK-INE, ENRESA, CIEMAT, ARMINES-SUBATECH and SKB.

  11. An in vitro thermal analysis during different light-activated hydrogen peroxide bleaching

    Science.gov (United States)

    Kabbach, W.; Zezell, D. M.; Bandéca, M. C.; Pereira, T. M.; Andrade, M. F.

    2010-09-01

    This study measured the critical temperature reaching time and also the variation of temperature in the surface of the cervical region and within the pulp chamber of human teeth submitted to dental bleaching using 35% hydrogen peroxide gel activated by three different light sources. The samples were randomly divided into 3 groups ( n = 15), according to the catalyst light source: Halogen Light (HL), High Intensity Diode Laser (DL), and Light Emmited Diode (LED). The results of temperature variation were submitted to the analysis of variance and Tukey test with p bleaching for a short period of time. The LED source did not heat the target tissues significantly within the parameters used in this study.

  12. A green lead hydrometallurgical process based on a hydrogen-lead oxide fuel cell.

    Science.gov (United States)

    Pan, Junqing; Sun, Yanzhi; Li, Wei; Knight, James; Manthiram, Arumugam

    2013-01-01

    The automobile industry consumed 9 million metric tons of lead in 2012 for lead-acid batteries. Recycling lead from spent lead-acid batteries is not only related to the sustainable development of the lead industry, but also to the reduction of lead pollution in the environment. The existing lead pyrometallurgical processes have two main issues, toxic lead emission into the environment and high energy consumption; the developing hydrometallurgical processes have the disadvantages of high electricity consumption, use of toxic chemicals and severe corrosion of metallic components. Here we demonstrate a new green hydrometallurgical process to recover lead based on a hydrogen-lead oxide fuel cell. High-purity lead, along with electricity, is produced with only water as the by-product. It has a >99.5% lead yield, which is higher than that of the existing pyrometallurgical processes (95-97%). This greatly reduces lead pollution to the environment.

  13. Fail-safe system for activity cooled supersonic and hypersonic aircraft. [using liquid hydrogen fuel

    Science.gov (United States)

    Jones, R. A.; Braswell, D. O.; Richie, C. B.

    1975-01-01

    A fail-safe-system concept was studied as an alternative to a redundant active cooling system for supersonic and hypersonic aircraft which use the heat sink of liquid-hydrogen fuel for cooling the aircraft structure. This concept consists of an abort maneuver by the aircraft and a passive thermal protection system (TPS) for the aircraft skin. The abort manuever provides a low-heat-load descent from normal cruise speed to a lower speed at which cooling is unnecessary, and the passive TPS allows the aircraft skin to absorb the abort heat load without exceeding critical skin temperature. On the basis of results obtained, it appears that this fail-safe-system concept warrants further consideration, inasmuch as a fail-safe system could possibly replace a redundant active cooling system with no increase in weight and would offer other potential advantages.

  14. Hydrogen-Oxygen PEM Regenerative Fuel Cell Development at the NASA Glenn Research Center

    Science.gov (United States)

    Bents, David J.; Scullin, Vincent J.; Chang, Bei-Jiann; Johnson, Donald W.; Garcia, Christoher P.; Jakupca, Ian J.

    2005-01-01

    The closed-cycle hydrogen-oxygen PEM regenerative fuel cell (RFC) at the NASA Glenn Research Center has successfully demonstrated closed cycle operation at rated power for multiple charge-discharge cycles. During charge cycle the RFC has absorbed input electrical power simulating a solar day cycle ranging from zero to 15 kWe peak, and delivered steady 5 kWe output power for periods exceeding 8 hr. Orderly transitions from charge to discharge mode, and return to charging after full discharge, have been accomplished without incident. Continuing test operations focus on: (1) Increasing the number of contiguous uninterrupted charge discharge cycles; (2) Increasing the performance envelope boundaries; (3) Operating the RFC as an energy storage device on a regular basis; (4) Gaining operational experience leading to development of fully automated operation; and (5) Developing instrumentation and in situ fluid sampling strategies to monitor health and anticipate breakdowns.

  15. Prediction of Combustion Stability and Flashback in Turbines with High-Hydrogen Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Lieuwen, Tim [Georgia Inst. of Technology, Atlanta, GA (United States); Santavicca, Dom [Georgia Inst. of Technology, Atlanta, GA (United States); Yang, Vigor [Georgia Inst. of Technology, Atlanta, GA (United States)

    2012-03-31

    During the duration of this sponsorship, we broadened our understanding of combustion instabilities through both analytical and experimental work. Predictive models were developed for flame response to transverse acoustic instabilities and for quantifying how a turbulent flame responds to velocity and fuel/air ratio forcing. Analysis was performed on the key instability mechanisms controlling heat release response for flames over a wide range of instability frequencies. Importantly, work was done closely with industrial partners to transition existing models into internal instability prediction codes. Experimentally, the forced response of hydrogen-enriched natural gas/air premixed and partially premixed flames were measured. The response of a lean premixed flame was investigated, subjected to velocity, equivalence ratio, and both forcing mechanisms simultaneously. In addition, important physical mechanisms controlling the response of partially premixed flames to inlet velocity and equivalence ratio oscillations were analyzed. This final technical report summarizes our findings and major publications stemming from this program.

  16. Coordinated Control of a Wind-Methanol-Fuel Cell System with Hydrogen Storage

    Directory of Open Access Journals (Sweden)

    Tiejiang Yuan

    2017-12-01

    Full Text Available This paper presents a wind-methanol-fuel cell system with hydrogen storage. It can manage various energy flow to provide stable wind power supply, produce constant methanol, and reduce CO2 emissions. Firstly, this study establishes the theoretical basis and formulation algorithms. And then, computational experiments are developed with MATLAB/Simulink (R2016a, MathWorks, Natick, MA, USA. Real data are used to fit the developed models in the study. From the test results, the developed system can generate maximum electricity whilst maintaining a stable production of methanol with the aid of a hybrid energy storage system (HESS. A sophisticated control scheme is also developed to coordinate these actions to achieve satisfactory system performance.

  17. System and method for integration of renewable energy and fuel cell for the production of electricity and hydrogen

    NARCIS (Netherlands)

    Hemmes, K.

    The invention relates to a system and method for integrating renewable energy and a fuel cell for the production of electricity and hydrogen, wherein this comprises the use of renewable energy as fluctuating energy source for the production of electricity and also comprises the use of at least one

  18. Environmental accounting of eco-innovations through environmental input-output analysis : The case of hydrogen and fuel cells buses

    NARCIS (Netherlands)

    Cantono, Simona; Heijungs, Reinout; Kleijn, Réne

    The introduction of environmentally friendly innovations in both transport and energy sectors are included in the list of priorities of the European Union political agenda. This paper investigates the environmental consequences of the introduction of hydrogen and fuel cells technology in the

  19. Symposium on hydrogen technology and fuel cells - opportunities for the economy; Symposium Wassertechnologie und Brennstoffzellen - Chancen fuer die Wirtschaft

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    This volume contains 17 contributions on fuel cell technology and on the infrastructure required for hydrogen production and supply, in the form of abstracts and short reports. [German] Dieser Band enthaelt 17 Beitraege zum Themenkreis Brennstoffzellentechnologie und die dazu erforderliche Infrastruktur fuer die Wasserstofferzeugung und -versorgung in Form von Kurzfassungen und Vortragsfolien.

  20. System and method for integration of renewable energy and fuel cell for the production of electricity and hydrogen

    NARCIS (Netherlands)

    Hemmes, K.

    2007-01-01

    The invention relates to a system and method for integrating renewable energy and a fuel cell for the production of electricity and hydrogen, wherein this comprises the use of renewable energy as fluctuating energy source for the production of electricity and also comprises the use of at least one