WorldWideScience

Sample records for hydrogen energy potential

  1. The potential impact of hydrogen energy use on the atmosphere

    Science.gov (United States)

    van Ruijven, B. J.; Lamarque, J. F.; van Vuuren, D. P.; Kram, T.; Eerens, H.

    2009-04-01

    Energy models show very different trajectories for future energy systems (partly as function of future climate policy). One possible option is a transition towards a hydrogen-based energy system. The potential impact of such hydrogen economy on atmospheric emissions is highly uncertain. On the one hand, application of hydrogen in clean fuel cells reduces emissions of local air pollutants, like SOx and NOx. On the other hand, emissions of hydrogen from system leakages are expected to change the atmospheric concentrations and behaviour (see also Price et al., 2007; Sanderson et al., 2003; Schultz et al., 2003; Tromp et al., 2003). The uncertainty arises from several sources: the expected use of hydrogen, the intensity of leakages and emissions, and the atmospheric chemical behaviour of hydrogen. Existing studies to the potential impacts of a hydrogen economy on the atmosphere mostly use hydrogen emission scenarios that are based on simple assumptions. This research combines two different modelling efforts to explore the range of impacts of hydrogen on atmospheric chemistry. First, the potential role of hydrogen in the global energy system and the related emissions of hydrogen and other air pollutants are derived from the global energy system simulation model TIMER (van Vuuren, 2007). A set of dedicated scenarios on hydrogen technology development explores the most pessimistic and optimistic cases for hydrogen deployment (van Ruijven et al., 2008; van Ruijven et al., 2007). These scenarios are combined with different assumptions on hydrogen emission factors. Second, the emissions from the TIMER model are linked to the NCAR atmospheric model (Lamarque et al., 2005; Lamarque et al., 2008), in order to determine the impacts on atmospheric chemistry. By combining an energy system model and an atmospheric model, we are able to consistently explore the boundaries of both hydrogen use, emissions and impacts on atmospheric chemistry. References: Lamarque, J.-F., Kiehl, J. T

  2. Resource Assessment for Hydrogen Production: Hydrogen Production Potential from Fossil and Renewable Energy Resources

    Energy Technology Data Exchange (ETDEWEB)

    Melaina, M. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Penev, M. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Heimiller, D. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2013-09-01

    This study examines the energy resources required to produce 4-10 million metric tonnes of domestic, low-carbon hydrogen in order to fuel approximately 20-50 million fuel cell electric vehicles. These projected energy resource requirements are compared to current consumption levels, projected 2040 business as usual consumptions levels, and projected 2040 consumption levels within a carbonconstrained future for the following energy resources: coal (assuming carbon capture and storage), natural gas, nuclear (uranium), biomass, wind (on- and offshore), and solar (photovoltaics and concentrating solar power). The analysis framework builds upon previous analysis results estimating hydrogen production potentials and drawing comparisons with economy-wide resource production projections

  3. The potential role of hydrogen energy in India and Western Europe

    NARCIS (Netherlands)

    van Ruijven, B.J.; Lakshmikanth, H.D.; van Vuuren, D.P.; de Vries, B.

    2008-01-01

    We used the TIMER energy model to explore the potential role of hydrogen in the energy systems of India and Western Europe, looking at the impacts on its main incentives: climate policy, energy security and urban air pollution. We found that hydrogen will not play a major role in both regions withou

  4. Metallic Hydrogen - Potentially a High Energy Rocket Propellant

    Science.gov (United States)

    Cole, John; Silvera, Ike

    2007-01-01

    Pure metallic hydrogen is predicted to have a specific impulse (Isp) of 1700 seconds, but the reaction temperature is too high for current engine materials. Diluting metallic hydrogen with liquid hydrogen can reduce the reaction temperature to levels compatible with current material limits and still provide an Isp greater than 900 s. Metallic hydrogen has not yet been produced on earth, but experimental techniques exist that may change this situation. This paper will provide a brief description of metallic hydrogen and the status of experiments that may soon produce detectable quantities of this material in the lab. Also provided are some characteristics for diluted metallic hydrogen engines and launch vehicles.

  5. REVIEW OF THE POTENTIAL OF NUCLEAR HYDROGEN FOR ADDRESSING ENERGY SECURITY AND CLIMATE CHANGE

    Energy Technology Data Exchange (ETDEWEB)

    James E. O' Brien

    2010-06-01

    Nuclear energy has the potential to exert a major positive impact on energy security and climate change by coupling it to the transportation sector, primarily through hydrogen production. In the short term, this coupling will provide carbon-free hydrogen for upgrading increasingly lower quality petroleum resources such as oil sands, offsetting carbon emissions associated with steam methane reforming. In the intermediate term, nuclear hydrogen will be needed for large-scale production of infrastructure-compatible synthetic liquid fuels. In the long term, there is great potential for the use of hydrogen as a direct vehicle fuel, most likely in the form of light-duty pluggable hybrid hydrogen fuel cell vehicles. This paper presents a review of the potential benefits of large-scale nuclear hydrogen production for energy security (i.e. displacing imported petroleum) and reduction of greenhouse gas emissions. Lifecycle benefits of nuclear energy in this context are presented, with reference to recent major publications on this topic. The status of US and international nuclear hydrogen research programs are discussed. Industry progress toward consumer-grade hydrogen fuel cell vehicles are also be examined.

  6. Hydrogen energy systems studies

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, J.M.; Steinbugler, M.; Kreutz, T. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies

    1998-08-01

    In this progress report (covering the period May 1997--May 1998), the authors summarize results from ongoing technical and economic assessments of hydrogen energy systems. Generally, the goal of their research is to illuminate possible pathways leading from present hydrogen markets and technologies toward wide scale use of hydrogen as an energy carrier, highlighting important technologies for RD and D. Over the past year they worked on three projects. From May 1997--November 1997, the authors completed an assessment of hydrogen as a fuel for fuel cell vehicles, as compared to methanol and gasoline. Two other studies were begun in November 1997 and are scheduled for completion in September 1998. The authors are carrying out an assessment of potential supplies and demands for hydrogen energy in the New York City/New Jersey area. The goal of this study is to provide useful data and suggest possible implementation strategies for the New York City/ New Jersey area, as the Hydrogen Program plans demonstrations of hydrogen vehicles and refueling infrastructure. The authors are assessing the implications of CO{sub 2} sequestration for hydrogen energy systems. The goals of this work are (a) to understand the implications of CO{sub 2} sequestration for hydrogen energy system design; (b) to understand the conditions under which CO{sub 2} sequestration might become economically viable; and (c) to understand design issues for future low-CO{sub 2} emitting hydrogen energy systems based on fossil fuels.

  7. The Economic Potential of Nuclear-Renewable Hybrid Energy Systems Producing Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Ruth, Mark; Cutler, Dylan; Flores-Espino, Francisco; Stark, Greg

    2017-04-07

    This report is one in a series of reports that Idaho National Laboratory and the Joint Institute for Strategic Energy Analysis are publishing that address the technical and economic aspects of nuclear-renewable hybrid energy systems (N-R HESs). This report discusses an analysis of the economic potential of a tightly coupled N-R HES that produces electricity and hydrogen. Both low and high temperature electrolysis options are considered in the analysis. Low-temperature electrolysis requires only electricity to convert water to hydrogen. High temperature electrolysis requires less electricity because it uses both electricity and heat to provide the energy necessary to electrolyze water. The study finds that, to be profitable, the examined high-temperature electrosis and low-temperature electrosis N-R HES configurations that produce hydrogen require higher electricity prices, more electricity price volatility, higher natural gas prices, or higher capacity payments than the reference case values of these parameters considered in this analysis.

  8. Hydrogen energy assessment

    Energy Technology Data Exchange (ETDEWEB)

    Salzano, F J; Braun, C [eds.

    1977-09-01

    The purpose of this assessment is to define the near term and long term prospects for the use of hydrogen as an energy delivery medium. Possible applications of hydrogen are defined along with the associated technologies required for implementation. A major focus in the near term is on industrial uses of hydrogen for special applications. The major source of hydrogen in the near term is expected to be from coal, with hydrogen from electric sources supplying a smaller fraction. A number of potential applications for hydrogen in the long term are identified and the level of demand estimated. The results of a cost benefit study for R and D work on coal gasification to hydrogen and electrolytic production of hydrogen are presented in order to aid in defining approximate levels of R and D funding. A considerable amount of data is presented on the cost of producing hydrogen from various energy resources. A key conclusion of the study is that in time hydrogen is likely to play a role in the energy system; however, hydrogen is not yet competitive for most applications when compared to the cost of energy from petroleum and natural gas.

  9. Hydrogen energy systems studies

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, J.M.; Steinbugler, M.; Dennis, E. [Princeton Univ., NJ (United States)] [and others

    1995-09-01

    For several years, researchers at Princeton University`s Center for Energy and Environmental Studies have carried out technical and economic assessments of hydrogen energy systems. Initially, we focussed on the long term potential of renewable hydrogen. More recently we have explored how a transition to renewable hydrogen might begin. The goal of our current work is to identify promising strategies leading from near term hydrogen markets and technologies toward eventual large scale use of renewable hydrogen as an energy carrier. Our approach has been to assess the entire hydrogen energy system from production through end-use considering technical performance, economics, infrastructure and environmental issues. This work is part of the systems analysis activity of the DOE Hydrogen Program. In this paper we first summarize the results of three tasks which were completed during the past year under NREL Contract No. XR-11265-2: in Task 1, we carried out assessments of near term options for supplying hydrogen transportation fuel from natural gas; in Task 2, we assessed the feasibility of using the existing natural gas system with hydrogen and hydrogen blends; and in Task 3, we carried out a study of PEM fuel cells for residential cogeneration applications, a market which might have less stringent cost requirements than transportation. We then give preliminary results for two other tasks which are ongoing under DOE Contract No. DE-FG04-94AL85803: In Task 1 we are assessing the technical options for low cost small scale production of hydrogen from natural gas, considering (a) steam reforming, (b) partial oxidation and (c) autothermal reforming, and in Task 2 we are assessing potential markets for hydrogen in Southern California.

  10. The Effects of Hydrogen on the Potential-Energy Surface of Amorphous Silicon

    Science.gov (United States)

    Joly, Jean-Francois; Mousseau, Normand

    2012-02-01

    Hydrogenated amorphous silicon (a-Si:H) is an important semiconducting material used in many applications from solar cells to transistors. In 2010, Houssem et al. [1], using the open-ended saddle-point search method, ART nouveau, studied the characteristics of the potential energy landscape of a-Si as a function of relaxation. Here, we extend this study and follow the impact of hydrogen doping on the same a-Si models as a function of doping level. Hydrogen atoms are first attached to dangling bonds, then are positioned to relieve strained bonds of fivefold coordinated silicon atoms. Once these sites are saturated, further doping is achieved with a Monte-Carlo bond switching method that preserves coordination and reduces stress [2]. Bonded interactions are described with a modified Stillinger-Weber potential and non-bonded Si-H and H-H interactions with an adapted Slater-Buckingham potential. Large series of ART nouveau searches are initiated on each model, resulting in an extended catalogue of events that characterize the evolution of potential energy surface as a function of H-doping. [4pt] [1] Houssem et al., Phys Rev. Lett., 105, 045503 (2010)[0pt] [2] Mousseau et al., Phys Rev. B, 41, 3702 (1990)

  11. Hydrogen Scenario Analysis Summary Report: Analysis of the Transition to Hydrogen Fuel Cell Vehicles and the Potential Hydrogen Energy Infrastructure Requirements

    Energy Technology Data Exchange (ETDEWEB)

    Greene, David L [ORNL; Leiby, Paul Newsome [ORNL; James, Brian [Directed Technologies, Inc.; Perez, Julie [Directed Technologies, Inc.; Melendez, Margo [National Renewable Energy Laboratory (NREL); Milbrandt, Anelia [National Renewable Energy Laboratory (NREL); Unnasch, Stefan [Life Cycle Associates; Rutherford, Daniel [TIAX, LLC; Hooks, Matthew [TIAX, LLC

    2008-03-01

    Achieving a successful transition to hydrogen-powered vehicles in the U.S. automotive market will require strong and sustained commitment by hydrogen producers, vehicle manufacturers, transporters and retailers, consumers, and governments. The interaction of these agents in the marketplace will determine the real costs and benefits of early market transformation policies, and ultimately the success of the transition itself. The transition to hydrogen-powered transportation faces imposing economic barriers. The challenges include developing and refining a new and different power-train technology, building a supporting fuel infrastructure, creating a market for new and unfamiliar vehicles, and achieving economies of scale in vehicle production while providing an attractive selection of vehicle makes and models for car-buyers. The upfront costs will be high and could persist for a decade or more, delaying profitability until an adequate number of vehicles can be produced and moved into consumer markets. However, the potential rewards to the economy, environment, and national security are immense. Such a profound market transformation will require careful planning and strong, consistent policy incentives. Section 811 of the Energy Policy Act (EPACT) of 2005, Public Law 109-59 (U.S. House, 2005), calls for a report from the Secretary of Energy on measures to support the transition to a hydrogen economy. The report was to specifically address production and deployment of hydrogen-fueled vehicles and the hydrogen production and delivery infrastructure needed to support those vehicles. In addition, the 2004 report of the National Academy of Sciences (NAS, 2004), The Hydrogen Economy, contained two recommendations for analyses to be conducted by the U.S. Department of Energy (DOE) to strengthen hydrogen energy transition and infrastructure planning for the hydrogen economy. In response to the EPACT requirement and NAS recommendations, DOE's Hydrogen, Fuel Cells and

  12. Hydrogen Scenario Analysis Summary Report: Analysis of the Transition to Hydrogen Fuel Cell Vehicles and the Potential Hydrogen Energy Infrastructure Requirements

    Energy Technology Data Exchange (ETDEWEB)

    Greene, David L [ORNL; Leiby, Paul Newsome [ORNL; James, Brian [Directed Technologies, Inc.; Perez, Julie [Directed Technologies, Inc.; Melendez, Margo [National Renewable Energy Laboratory (NREL); Milbrandt, Anelia [National Renewable Energy Laboratory (NREL); Unnasch, Stefan [Life Cycle Associates; Rutherford, Daniel [TIAX, LLC; Hooks, Matthew [TIAX, LLC

    2008-03-01

    Achieving a successful transition to hydrogen-powered vehicles in the U.S. automotive market will require strong and sustained commitment by hydrogen producers, vehicle manufacturers, transporters and retailers, consumers, and governments. The interaction of these agents in the marketplace will determine the real costs and benefits of early market transformation policies, and ultimately the success of the transition itself. The transition to hydrogen-powered transportation faces imposing economic barriers. The challenges include developing and refining a new and different power-train technology, building a supporting fuel infrastructure, creating a market for new and unfamiliar vehicles, and achieving economies of scale in vehicle production while providing an attractive selection of vehicle makes and models for car-buyers. The upfront costs will be high and could persist for a decade or more, delaying profitability until an adequate number of vehicles can be produced and moved into consumer markets. However, the potential rewards to the economy, environment, and national security are immense. Such a profound market transformation will require careful planning and strong, consistent policy incentives. Section 811 of the Energy Policy Act (EPACT) of 2005, Public Law 109-59 (U.S. House, 2005), calls for a report from the Secretary of Energy on measures to support the transition to a hydrogen economy. The report was to specifically address production and deployment of hydrogen-fueled vehicles and the hydrogen production and delivery infrastructure needed to support those vehicles. In addition, the 2004 report of the National Academy of Sciences (NAS, 2004), The Hydrogen Economy, contained two recommendations for analyses to be conducted by the U.S. Department of Energy (DOE) to strengthen hydrogen energy transition and infrastructure planning for the hydrogen economy. In response to the EPACT requirement and NAS recommendations, DOE's Hydrogen, Fuel Cells and

  13. Evaluation of the Potential Environmental Impacts from Large-Scale Use and Production of Hydrogen in Energy and Transportation Applications

    Energy Technology Data Exchange (ETDEWEB)

    Wuebbles, D.J.; Dubey, M.K., Edmonds, J.; Layzell, D.; Olsen, S.; Rahn, T.; Rocket, A.; Wang, D.; Jia, W.

    2010-06-01

    The purpose of this project is to systematically identify and examine possible near and long-term ecological and environmental effects from the production of hydrogen from various energy sources based on the DOE hydrogen production strategy and the use of that hydrogen in transportation applications. This project uses state-of-the-art numerical modeling tools of the environment and energy system emissions in combination with relevant new and prior measurements and other analyses to assess the understanding of the potential ecological and environmental impacts from hydrogen market penetration. H2 technology options and market penetration scenarios will be evaluated using energy-technology-economics models as well as atmospheric trace gas projections based on the IPCC SRES scenarios including the decline in halocarbons due to the Montreal Protocol. Specifically we investigate the impact of hydrogen releases on the oxidative capacity of the atmosphere, the long-term stability of the ozone layer due to changes in hydrogen emissions, the impact of hydrogen emissions and resulting concentrations on climate, the impact on microbial ecosystems involved in hydrogen uptake, and criteria pollutants emitted from distributed and centralized hydrogen production pathways and their impacts on human health, air quality, ecosystems, and structures under different penetration scenarios

  14. Assessment of the potential future market in Sweden for hydrogen as an energy carrier

    Science.gov (United States)

    Carleson, G.

    Future hydrogen markets for the period 1980-2025 are projected, the probable range of hydrogen production costs for various manufacturing methods is estimated, and expected market shares in competition with alternative energy carriers are evaluated. A general scenario for economic and industrial development in Sweden for the given period was evaluated, showing the average increase in gross national product to become 1.6% per year. Three different energy scenarios were then developed: alternatives were based on nuclear energy, renewable indigenous energy sources, and the present energy situation with free access to imported natural or synthetic fuels. An analysis was made within each scenario of the competitiveness of hydrogen on both the demand and the supply of the following sectors: chemical industry, steel industry, peak power production, residential and commercial heating, and transportation. Costs were calculated for the production, storage and transmission of hydrogen according to technically feasible methods and were compared to those of alternative energy carriers. Health, environmental and societal implications were also considered. The market penetration of hydrogen in each sector was estimated, and the required investment capital was shown to be less than 4% of the national gross investment sum.

  15. Wind, biomass, hydrogen: renewable energies; Vent, biomasse, hydrogene: energies renouvelables

    Energy Technology Data Exchange (ETDEWEB)

    Rakotosson, V.; Brousse, Th.; Guillemet, Ph.; Scudeller, Y.; Crosnier, O.; Dugas, R.; Favier, F.; Zhou, Y.; Taberna, P.M.; Simon, P.; Toupin, M.; Belanger, D.; Ngo, Ch.; Djamie, B.; Guyard, Ch.; Tamain, B.; Ruer, J.; Ungerer, Ph.; Bonal, J.; Flamant, G

    2007-06-15

    This press kit gathers a series of articles about renewable energies: the compared availabilities of renewable energy sources (comparison at a given time); offshore wind turbines (projects under development, cost optimisation); hydrogen for transports: present day situation (production, transport and storage, hydrogen conversion into mechanical energy, indirect use in biomass conversion); biomass: future carbon source (resource potential in France, pyrolysis and fermentation, development of biofuels and synthetic fuels, stakes for agriculture); beneficial standards for the heat pumps market (market organization and quality approach); collecting solar energy (solar furnaces and future solar power plants, hydrogen generation). (J.S.)

  16. Potential improvement to a citric wastewater treatment plant using bio-hydrogen and a hybrid energy system

    Science.gov (United States)

    Zhi, Xiaohua; Yang, Haijun; Berthold, Sascha; Doetsch, Christian; Shen, Jianquan

    Treatment of highly concentrated organic wastewater is characterized as cost-consuming. The conventional technology uses the anaerobic-anoxic-oxic process (A 2/O), which does not produce hydrogen. There is potential for energy saving using hydrogen utilization associated with wastewater treatment because hydrogen can be produced from organic wastewater using anaerobic fermentation. A 50 m 3 pilot bio-reactor for hydrogen production was constructed in Shandong Province, China in 2006 but to date the hydrogen produced has not been utilized. In this work, a technical-economic model based on hydrogen utilization is presented and analyzed to estimate the potential improvement to a citric wastewater plant. The model assesses the size, capital cost, annual cost, system efficiency and electricity cost under different configurations. In a stand-alone situation, the power production from hydrogen is not sufficient for the required load, thus a photovoltaic array (PV) is employed as the power supply. The simulated results show that the combination of solar and bio-hydrogen has a much higher cost compared with the A 2/O process. When the grid is connected, the system cost achieved is 0.238 US t -1 wastewater, which is lower than 0.257 US t -1 by the A 2/O process. The results reveal that a simulated improvement by using bio-hydrogen and a FC system is effective and feasible for the citric wastewater plant, even when compared to the current cost of the A 2/O process. In addition, lead acid and vanadium flow batteries were compared for energy storage service. The results show that a vanadium battery has lower cost and higher efficiency due to its long lifespan and energy efficiency. Additionally, the cost distribution of components shows that the PV dominates the cost in the stand-alone situation, while the bio-reactor is the main cost component in the parallel grid.

  17. Hydrogen energy systems studies

    Energy Technology Data Exchange (ETDEWEB)

    Ogden, J.M.; Kreutz, T.G.; Steinbugler, M. [Princeton Univ., NJ (United States)] [and others

    1996-10-01

    In this report the authors describe results from technical and economic assessments carried out during the past year with support from the USDOE Hydrogen R&D Program. (1) Assessment of technologies for small scale production of hydrogen from natural gas. Because of the cost and logistics of transporting and storing hydrogen, it may be preferable to produce hydrogen at the point of use from more readily available energy carriers such as natural gas or electricity. In this task the authors assess near term technologies for producing hydrogen from natural gas at small scale including steam reforming, partial oxidation and autothermal reforming. (2) Case study of developing a hydrogen vehicle refueling infrastructure in Southern California. Many analysts suggest that the first widespread use of hydrogen energy is likely to be in zero emission vehicles in Southern California. Several hundred thousand zero emission automobiles are projected for the Los Angeles Basin alone by 2010, if mandated levels are implemented. Assuming that hydrogen vehicles capture a significant fraction of this market, a large demand for hydrogen fuel could evolve over the next few decades. Refueling a large number of hydrogen vehicles poses significant challenges. In this task the authors assess near term options for producing and delivering gaseous hydrogen transportation fuel to users in Southern California including: (1) hydrogen produced from natural gas in a large, centralized steam reforming plant, and delivered to refueling stations via liquid hydrogen truck or small scale hydrogen gas pipeline, (2) hydrogen produced at the refueling station via small scale steam reforming of natural gas, (3) hydrogen produced via small scale electrolysis at the refueling station, and (4) hydrogen from low cost chemical industry sources (e.g. excess capacity in refineries which have recently upgraded their hydrogen production capacity, etc.).

  18. Hydrogen rich gas from oil palm biomass as a potential source of renewable energy in Malaysia

    Energy Technology Data Exchange (ETDEWEB)

    Mohammed, M.A.A.; Salmiaton, A.; Wan Azlina, W.A.K.G.; Mohammad Amran, M.S.; Fakhru' l-Razi, A. [Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia); Taufiq-Yap, Y.H. [Centre of Excellence for Catalysis Science and Technology and Department of Chemistry, Faculty of Science, University Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia)

    2011-02-15

    Oil palm is one of the major economic crops in many countries. Malaysia alone produces about 47% of the world's palm oil supply and can be considered as the world's largest producer and exporter of palm oil. Malaysia also generates huge quantity of oil palm biomass including oil palm trunks, oil palm fronds, empty fruit bunches (EFB), shells and fibers as waste from palm oil fruit harvest and oil extraction processing. At present there is a continuously increasing interest in the utilization of oil palm biomass as a source of clean energy. One of the major interests is hydrogen from oil palm biomass. Hydrogen from biomass is a clean and efficient energy source and is expected to take a significant role in future energy demand due to the raw material availability. This paper presents a review which focuses on different types of thermo-chemical processes for conversion of oil palm biomass to hydrogen rich gas. This paper offers a concise and up-to-date scenario of the present status of oil palm industry in contributing towards sustainable and renewable energy. (author)

  19. National hydrogen energy roadmap

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2002-11-01

    This report was unveiled by Energy Secretary Spencer Abraham in November 2002 and provides a blueprint for the coordinated, long-term, public and private efforts required for hydrogen energy development. Based on the results of the government-industry National Hydrogen Energy Roadmap Workshop, held in Washington, DC on April 2-3, 2002, it displays the development of a roadmap for America's clean energy future and outlines the key barriers and needs to achieve the hydrogen vision goals defined in

  20. Hydrogen energy for beginners

    CERN Document Server

    2013-01-01

    This book highlights the outstanding role of hydrogen in energy processes, where it is the most functional element due to its unique peculiarities that are highlighted and emphasized in the book. The first half of the book covers the great natural hydrogen processes in biology, chemistry, and physics, showing that hydrogen is a trend that can unite all natural sciences. The second half of the book is devoted to the technological hydrogen processes that are under research and development with the aim to create the infrastructure for hydrogen energetics. The book describes the main features of hydrogen that make it inalienable player in processes such as fusion, photosynthesis, and metabolism. It also covers the methods of hydrogen production and storage, highlighting at the same time the exclusive importance of nanotechnologies in those processes.

  1. The READY program: Building a global potential energy surface and reactive dynamic simulations for the hydrogen combustion.

    Science.gov (United States)

    Mogo, César; Brandão, João

    2014-06-30

    READY (REActive DYnamics) is a program for studying reactive dynamic systems using a global potential energy surface (PES) built from previously existing PESs corresponding to each of the most important elementary reactions present in the system. We present an application to the combustion dynamics of a mixture of hydrogen and oxygen using accurate PESs for all the systems involving up to four oxygen and hydrogen atoms. Results at the temperature of 4000 K and pressure of 2 atm are presented and compared with model based on rate constants. Drawbacks and advantages of this approach are discussed and future directions of research are pointed out.

  2. Hydrogen transfer reactions in viscous media — Potential and free energy surfaces in solvent–solute coordinates and their kinetic implications

    National Research Council Canada - National Science Library

    Wiebe, Heather; Prachnau, Melissa; Weinberg, Noham

    2013-01-01

    Two-dimensional potential energy and free energy surfaces are obtained using quantum mechanical and molecular dynamics calculations for four hydrogen transfer reactions in n-hexane solvent: the methyl–methane, n-propyl–n-propane, n-pentyl...

  3. Hydrogen and OUr Energy Future

    Energy Technology Data Exchange (ETDEWEB)

    Rick Tidball; Stu Knoke

    2009-03-01

    In 2003, President George W. Bush announced the Hydrogen Fuel Initiative to accelerate the research and development of hydrogen, fuel cell, and infrastructure technologies that would enable hydrogen fuel cell vehicles to reach the commercial market in the 2020 timeframe. The widespread use of hydrogen can reduce our dependence on imported oil and benefit the environment by reducing greenhouse gas emissions and criteria pollutant emissions that affect our air quality. The Energy Policy Act of 2005, passed by Congress and signed into law by President Bush on August 8, 2005, reinforces Federal government support for hydrogen and fuel cell technologies. Title VIII, also called the 'Spark M. Matsunaga Hydrogen Act of 2005' authorizes more than $3.2 billion for hydrogen and fuel cell activities intended to enable the commercial introduction of hydrogen fuel cell vehicles by 2020, consistent with the Hydrogen Fuel Initiative. Numerous other titles in the Act call for related tax and market incentives, new studies, collaboration with alternative fuels and renewable energy programs, and broadened demonstrations--clearly demonstrating the strong support among members of Congress for the development and use of hydrogen fuel cell technologies. In 2006, the President announced the Advanced Energy Initiative (AEI) to accelerate research on technologies with the potential to reduce near-term oil use in the transportation sector--batteries for hybrid vehicles and cellulosic ethanol--and advance activities under the Hydrogen Fuel Initiative. The AEI also supports research to reduce the cost of electricity production technologies in the stationary sector such as clean coal, nuclear energy, solar photovoltaics, and wind energy.

  4. Analysis of the Transition to Hydrogen Fuel Cell Vehicles and the Potential Hydrogen Energy Infrastructure Requirements, March 2008

    Energy Technology Data Exchange (ETDEWEB)

    Greene, David L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Leiby, Paul N. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); James, Brian [Directed Technologies, Inc., Youngstown, OH (United States); Perez, Julie [Directed Technologies, Inc., Youngstown, OH (United States); Melendez, Margo [National Renewable Energy Lab. (NREL), Golden, CO (United States); Milbrandt, Anelia [National Renewable Energy Lab. (NREL), Golden, CO (United States); Unnash, Stefan [Life Cycle Associates, Portola Valley, CA (United States); Rutherford, Daniel [Life Cycle Associates, Portola Valley, CA (United States); Hooks, Matthew [TIAX, LLC, Lexingtion, MA (United States)

    2008-03-14

    Achieving a successful transition to hydrogen-powered vehicles in the U.S. automotive market will require strong and sustained commitment by hydrogen producers, vehicle manufacturers, transporters and retailers, consumers, and governments. The interaction of these agents in the marketplace will determine the real costs and benefits of early market transformation policies, and ultimately the success of the transition itself.

  5. Effect of external fields on the energies of hydrogenic donor with the anharmonic confinement potential

    Energy Technology Data Exchange (ETDEWEB)

    Aciksoz, E.; Bayrak, O. [Department of Physics, Akdeniz University, 07058 Antalya (Turkey); Soylu, A., E-mail: asimsoylu@gmail.com [Department of Physics, Nigde University, 51240 Nigde (Turkey)

    2015-01-01

    The impurity binding energy in the GaAs−Ga{sub 1−x}Al{sub x}As system is studied with an anharmonic type confinement potential by taking into account the influence of the external electric and magnetic fields within the framework of the effective mass approximation and asymptotic iteration method (AIM). The influence of the external electromagnetic fields and anharmonicity on a donor binding energy is examined systematically. It is shown that the donor binding energy is highly dependent on the external electric and magnetic fields and the confinement potential shapes. Both the electric and magnetic fields are increased, the binding energies increase for each of them. However, the behaviors of increase in the weak and strong fields’ regimes have different character a bit. Furthermore, when the more anharmonicity is considered, the binding energy of donor slightly increases as well.

  6. Potentialities of hydrogen production in Algeria

    Energy Technology Data Exchange (ETDEWEB)

    Boudries, R. [CDER, Route de l' Observatoire, Bouzareah Algiers (Algeria); USTHB, El Alia, Algiers (Algeria); Dizene, R. [USTHB, El Alia, Algiers (Algeria)

    2008-09-15

    The objective of the present study is to estimate the potentialities of hydrogen production in Algeria. Particular attention is paid to the clean and sustainable hydrogen production, i.e., production from renewable energy. First, the present overall energy situation in Algeria is reviewed. Trend in energy demand is analysed taking into account major parameters such as population growth, urbanization, improvement in quality of life and export opportunities. The resources available for hydrogen production are then presented. Finally, the estimation of hydrogen production potential using solar sources, the most important renewable energy sources in Algeria, is presented. This study indicates that the shift to hydrogen economy shows a promising prospect. Not only, it can meet the evergrowing local needs but it will also allow Algeria to keep its share of the energy market. Indeed, as is now the case for natural gas, hydrogen could be delivered to Western Europe through pipelines. (author)

  7. Evidence for Seismogenic Hydrogen Gas, a Potential Microbial Energy Source on Earth and Mars

    Science.gov (United States)

    McMahon, Sean; Parnell, John; Blamey, Nigel J. F.

    2016-09-01

    The oxidation of molecular hydrogen (H2) is thought to be a major source of metabolic energy for life in the deep subsurface on Earth, and it could likewise support any extant biosphere on Mars, where stable habitable environments are probably limited to the subsurface. Faulting and fracturing may stimulate the supply of H2 from several sources. We report the H2 content of fluids present in terrestrial rocks formed by brittle fracturing on fault planes (pseudotachylites and cataclasites), along with protolith control samples. The fluids are dominated by water and include H2 at abundances sufficient to support hydrogenotrophic microorganisms, with strong H2 enrichments in the pseudotachylites compared to the controls. Weaker and less consistent H2 enrichments are observed in the cataclasites, which represent less intense seismic friction than the pseudotachylites. The enrichments agree quantitatively with previous experimental measurements of frictionally driven H2 formation during rock fracturing. We find that conservative estimates of current martian global seismicity predict episodic H2 generation by Marsquakes in quantities useful to hydrogenotrophs over a range of scales and recurrence times. On both Earth and Mars, secondary release of H2 may also accompany the breakdown of ancient fault rocks, which are particularly abundant in the pervasively fractured martian crust. This study strengthens the case for the astrobiological investigation of ancient martian fracture systems.

  8. Hydrogen fuel - Universal energy

    Science.gov (United States)

    Prince, A. G.; Burg, J. A.

    The technology for the production, storage, transmission, and consumption of hydrogen as a fuel is surveyed, with the physical and chemical properties of hydrogen examined as they affect its use as a fuel. Sources of hydrogen production are described including synthesis from coal or natural gas, biomass conversion, thermochemical decomposition of water, and electrolysis of water, of these only electrolysis is considered economicially and technologically feasible in the near future. Methods of production of the large quantities of electricity required for the electrolysis of sea water are explored: fossil fuels, hydroelectric plants, nuclear fission, solar energy, wind power, geothermal energy, tidal power, wave motion, electrochemical concentration cells, and finally ocean thermal energy conversion (OTEC). The wind power and OTEC are considered in detail as the most feasible approaches. Techniques for transmission (by railcar or pipeline), storage (as liquid in underwater or underground tanks, as granular metal hydride, or as cryogenic liquid), and consumption (in fuel cells in conventional power plants, for home usage, for industrial furnaces, and for cars and aircraft) are analyzed. The safety problems of hydrogen as a universal fuel are discussed, noting that they are no greater than those for conventional fuels.

  9. Vibrational analysis on the revised potential energy curve of the low-barrier hydrogen bond in photoactive yellow protein

    Directory of Open Access Journals (Sweden)

    Yusuke Kanematsu

    2016-01-01

    Full Text Available Photoactive yellow protein (PYP has a characteristic hydrogen bond (H bond between p-coumaric acid chromophore and Glu46, whose OH bond length has been observed to be 1.21 Å by the neutron diffraction technique [Proc. Natl. Acad. Sci. 106, 440–4]. Although it has been expected that such a drastic elongation of the OH bond could be caused by the quantum effect of the hydrogen nucleus, previous theoretical computations including the nuclear quantum effect have so far underestimated the bond length by more than 0.07 Å. To elucidate the origin of the difference, we performed a vibrational analysis of the H bond on potential energy curve with O…O distance of 2.47 Å on the equilibrium structure, and that with O…O distance of 2.56 Å on the experimental crystal structure. While the vibrationally averaged OH bond length for equilibrium structure was underestimated, the corresponding value for crystal structure was in reasonable agreement with the corresponding experimental values. The elongation of the O…O distance by the quantum mechanical or thermal fluctuation would be indispensable for the formation of a low-barrier hydrogen bond in PYP.

  10. Energy conversion, storage and balancing. Great potential of hydrogen and fuel cells; Energikonvertering, lagring og balancering. Stort potentiale i brint og braendselsceller

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-12-15

    This document is the Danish strategy for hydrogen technology research, development and demonstration. Work on a new strategy was launched in early 2012 by the Partnership for hydrogen and fuel cells. The new national strategy complements the Partnership's former national strategy ''Hydrogen Technologies - strategy for research, development and demonstration in Denmark'' from June 2005. The former strategy describes the challenges and costs by the technological development of hydrogen and fuel cells until 2016 - and is valid until 2016. The Partnership's strategy anno 2012 describes the energy technology challenges for hydrogen technology development until 2016 - and in some years thereafter. The strategy provides an updated status of hydrogen and fuel cells, describes the area's future potential, and specifies future needs for technological development. The strategy's main focus is to define how electrolysis, hydrogen and fuel cells can help to meet Denmark's future energy policy objectives. In the strategy the term ''hydrogen technologies'' overall means: Electrolysis and fuel cells as conversion technologies, and hydrogen and hydrogen-containing fuels, such as methanol, as energy carriers. (LN)

  11. Chirality of weakly bound complexes: The potential energy surfaces for the hydrogen-peroxide−noble-gas interactions

    Energy Technology Data Exchange (ETDEWEB)

    Roncaratti, L. F., E-mail: lz@fis.unb.br; Leal, L. A.; Silva, G. M. de [Instituto de Física, Universidade de Brasília, 70910 Brasília (Brazil); Pirani, F. [Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, 06123 Perugia (Italy); Aquilanti, V. [Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, 06123 Perugia (Italy); Instituto de Física, Universidade Federal da Bahia, 40210 Salvador (Brazil); Gargano, R. [Instituto de Física, Universidade de Brasília, 70910 Brasília (Brazil); Departments of Chemistry and Physics, University of Florida, Quantum Theory Project, Gainesville, Florida 32611 (United States)

    2014-10-07

    We consider the analytical representation of the potential energy surfaces of relevance for the intermolecular dynamics of weakly bound complexes of chiral molecules. In this paper we study the H{sub 2}O{sub 2}−Ng (Ng=He, Ne, Ar, Kr, and Xe) systems providing the radial and the angular dependence of the potential energy surface on the relative position of the Ng atom. We accomplish this by introducing an analytical representation which is able to fit the ab initio energies of these complexes in a wide range of geometries. Our analysis sheds light on the role that the enantiomeric forms and the symmetry of the H{sub 2}O{sub 2} molecule play on the resulting barriers and equilibrium geometries. The proposed theoretical framework is useful to study the dynamics of the H{sub 2}O{sub 2} molecule, or other systems involving O–O and S–S bonds, interacting by non-covalent forces with atoms or molecules and to understand how the relative orientation of the O–H bonds changes along collisional events that may lead to a hydrogen bond formation or even to selectivity in chemical reactions.

  12. Clean energy and the hydrogen economy.

    Science.gov (United States)

    Brandon, N P; Kurban, Z

    2017-07-28

    In recent years, new-found interest in the hydrogen economy from both industry and academia has helped to shed light on its potential. Hydrogen can enable an energy revolution by providing much needed flexibility in renewable energy systems. As a clean energy carrier, hydrogen offers a range of benefits for simultaneously decarbonizing the transport, residential, commercial and industrial sectors. Hydrogen is shown here to have synergies with other low-carbon alternatives, and can enable a more cost-effective transition to de-carbonized and cleaner energy systems. This paper presents the opportunities for the use of hydrogen in key sectors of the economy and identifies the benefits and challenges within the hydrogen supply chain for power-to-gas, power-to-power and gas-to-gas supply pathways. While industry players have already started the market introduction of hydrogen fuel cell systems, including fuel cell electric vehicles and micro-combined heat and power devices, the use of hydrogen at grid scale requires the challenges of clean hydrogen production, bulk storage and distribution to be resolved. Ultimately, greater government support, in partnership with industry and academia, is still needed to realize hydrogen's potential across all economic sectors.This article is part of the themed issue 'The challenges of hydrogen and metals'. © 2017 The Author(s).

  13. Probing the global potential energy minimum of (CH2O)2: THz absorption spectrum of (CH2O)2 in solid neon and para-hydrogen

    DEFF Research Database (Denmark)

    Andersen, Jonas; Voute, A.; Mihrin, Dmytro

    2017-01-01

    . The combination of concentration dependency measurements, observed isotopic spectral shifts associated with H/D substitutions and dedicated annealing procedures, enables the unambiguous assignment of three large-amplitude infrared active hydrogen bond vibrational modes for the non-planar Cs configuration of (CH2O......The true global potential energy minimum configuration of the formaldehyde dimer (CH2O)2, including the presence of a single or a double weak intermolecular CH⋯O hydrogen bond motif, has been a long-standing subject among both experimentalists and theoreticians as two different energy minima...... conformations of Cs and C2h symmetry have almost identical energies. The present work demonstrates how the class of large-amplitude hydrogen bond vibrational motion probed in the THz region provides excellent direct spectroscopic observables for these weak intermolecular CH⋯O hydrogen bond motifs...

  14. Handbook of hydrogen energy

    CERN Document Server

    Sherif, SA; Stefanakos, EK; Steinfeld, Aldo

    2014-01-01

    ""This book provides an excellent overview of the hydrogen economy and a thorough and comprehensive presentation of hydrogen production and storage methods.""-Scott E. Grasman, Rochester Institute of Technology, New York, USA

  15. Hydrogen production from solar energy

    Science.gov (United States)

    Eisenstadt, M. M.; Cox, K. E.

    1975-01-01

    Three alternatives for hydrogen production from solar energy have been analyzed on both efficiency and economic grounds. The analysis shows that the alternative using solar energy followed by thermochemical decomposition of water to produce hydrogen is the optimum one. The other schemes considered were the direct conversion of solar energy to electricity by silicon cells and water electrolysis, and the use of solar energy to power a vapor cycle followed by electrical generation and electrolysis. The capital cost of hydrogen via the thermochemical alternative was estimated at $575/kW of hydrogen output or $3.15/million Btu. Although this cost appears high when compared with hydrogen from other primary energy sources or from fossil fuel, environmental and social costs which favor solar energy may prove this scheme feasible in the future.

  16. Hydrogen - A sustainable energy carrier

    Directory of Open Access Journals (Sweden)

    Kasper T. Møller

    2017-02-01

    Full Text Available Hydrogen may play a key role in a future sustainable energy system as a carrier of renewable energy to replace hydrocarbons. This review describes the fundamental physical and chemical properties of hydrogen and basic theories of hydrogen sorption reactions, followed by the emphasis on state-of-the-art of the hydrogen storage properties of selected interstitial metallic hydrides and magnesium hydride, especially for stationary energy storage related utilizations. Finally, new perspectives for utilization of metal hydrides in other applications will be reviewed.

  17. Hydrogen Storage Technologies for Future Energy Systems.

    Science.gov (United States)

    Preuster, Patrick; Alekseev, Alexander; Wasserscheid, Peter

    2017-06-07

    Future energy systems will be determined by the increasing relevance of solar and wind energy. Crude oil and gas prices are expected to increase in the long run, and penalties for CO2 emissions will become a relevant economic factor. Solar- and wind-powered electricity will become significantly cheaper, such that hydrogen produced from electrolysis will be competitively priced against hydrogen manufactured from natural gas. However, to handle the unsteadiness of system input from fluctuating energy sources, energy storage technologies that cover the full scale of power (in megawatts) and energy storage amounts (in megawatt hours) are required. Hydrogen, in particular, is a promising secondary energy vector for storing, transporting, and distributing large and very large amounts of energy at the gigawatt-hour and terawatt-hour scales. However, we also discuss energy storage at the 120-200-kWh scale, for example, for onboard hydrogen storage in fuel cell vehicles using compressed hydrogen storage. This article focuses on the characteristics and development potential of hydrogen storage technologies in light of such a changing energy system and its related challenges. Technological factors that influence the dynamics, flexibility, and operating costs of unsteady operation are therefore highlighted in particular. Moreover, the potential for using renewable hydrogen in the mobility sector, industrial production, and the heat market is discussed, as this potential may determine to a significant extent the future economic value of hydrogen storage technology as it applies to other industries. This evaluation elucidates known and well-established options for hydrogen storage and may guide the development and direction of newer, less developed technologies.

  18. Hydrogen energy systems technology study

    Science.gov (United States)

    Kelley, J. H.

    1975-01-01

    The paper discusses the objectives of a hydrogen energy systems technology study directed toward determining future demand for hydrogen based on current trends and anticipated new uses and identifying the critical research and technology advancements required to meet this need with allowance for raw material limitations, economics, and environmental effects. Attention is focused on historic production and use of hydrogen, scenarios used as a basis for projections, projections of energy sources and uses, supply options, and technology requirements and needs. The study found more than a billion dollar annual usage of hydrogen, dominated by chemical-industry needs, supplied mostly from natural gas and petroleum feedstocks. Evaluation of the progress in developing nuclear fusion and solar energy sources relative to hydrogen production will be necessary to direct the pace and character of research and technology work in the advanced water-splitting areas.

  19. Electrocatalysts for hydrogen energy

    CERN Document Server

    Losiewicz, Bozena

    2015-01-01

    This special topic volume deals with the development of novel solid state electrocatalysts of a high performance to enhance the rates of the hydrogen or oxygen evolution. It contains a description of various types of metals, alloys and composites which have been obtained using electrodeposition in aqueous solutions that has been identified to be a technologically feasible and economically superior technique for the production of the porous electrodes. The goal was to produce papers that would be useful to both the novice and the expert in hydrogen technologies. This volume is intended to be us

  20. Hydrogen: the future energy carrier.

    Science.gov (United States)

    Züttel, Andreas; Remhof, Arndt; Borgschulte, Andreas; Friedrichs, Oliver

    2010-07-28

    Since the beginning of the twenty-first century the limitations of the fossil age with regard to the continuing growth of energy demand, the peaking mining rate of oil, the growing impact of CO2 emissions on the environment and the dependency of the economy in the industrialized world on the availability of fossil fuels became very obvious. A major change in the energy economy from fossil energy carriers to renewable energy fluxes is necessary. The main challenge is to efficiently convert renewable energy into electricity and the storage of electricity or the production of a synthetic fuel. Hydrogen is produced from water by electricity through an electrolyser. The storage of hydrogen in its molecular or atomic form is a materials challenge. Some hydrides are known to exhibit a hydrogen density comparable to oil; however, these hydrides require a sophisticated storage system. The system energy density is significantly smaller than the energy density of fossil fuels. An interesting alternative to the direct storage of hydrogen are synthetic hydrocarbons produced from hydrogen and CO2 extracted from the atmosphere. They are CO2 neutral and stored like fossil fuels. Conventional combustion engines and turbines can be used in order to convert the stored energy into work and heat.

  1. Formic Acid as a Hydrogen Energy Carrier

    KAUST Repository

    Eppinger, Jorg

    2016-12-15

    The high volumetric capacity (S3 g H-2/L) and its low toxicity and flammability under ambient conditions make formic acid a promising hydrogen energy carrier. Particularly, in the past decade, significant advancements have been achieved in catalyst development for selective hydrogen generation from formic acid. This Perspective highlights the advantages of this approach with discussions focused on potential applications in the transportation sector together with analysis of technical requirements, limitations, and costs.

  2. Fusion Energy for Hydrogen Production

    Energy Technology Data Exchange (ETDEWEB)

    Fillo, J. A.; Powell, J. R.; Steinberg, M.; Salzano, F.; Benenati, R.; Dang, V.; Fogelson, S.; Isaacs, H.; Kouts, H.; Kushner, M.; Lazareth, O.; Majeski, S.; Makowitz, H.; Sheehan, T. V.

    1978-09-01

    The decreasing availability of fossil fuels emphasizes the need to develop systems which will produce synthetic fuel to substitute for and supplement the natural supply. An important first step in the synthesis of liquid and gaseous fuels is the production of hydrogen. Thermonuclear fusion offers an inexhaustible source of energy for the production of hydrogen from water. Depending on design, electric generation efficiencies of approximately 40 to 60% and hydrogen production efficiencies by high temperature electrolysis of approximately 50 to 70% are projected for fusion reactors using high temperature blankets.

  3. Energy Accumulation by Hydrogen Technologies

    Directory of Open Access Journals (Sweden)

    Jiřina Čermáková

    2012-01-01

    Full Text Available Photovoltaic power plants as a renewable energy source have been receiving rapidly growing attention in the Czech Republic and in the other EU countries. This rapid development of photovoltaic sources is having a negative effect on the electricity power system control, because they depend on the weather conditions and provide a variable and unreliable supply of electric power. One way to reduce this effect is by accumulating electricity in hydrogen. The aim of this paper is to introduce hydrogen as a tool for regulating photovoltaic energy in island mode. A configuration has been designed for connecting households with the photovoltaic hybrid system, and a simulation model has been made in order to check the validity of this system. The simulation results provide energy flows and have been used for optimal sizing of real devices. An appropriate system can deliver energy in a stand-alone installation.

  4. Hydrogen: a clean energy for tomorrow?; L'hydrogene: une energie propre pour demain?

    Energy Technology Data Exchange (ETDEWEB)

    Artero, V. [Universite Joseph-Fourier, Grenoble I, Lab. de chimie et biologie des metaux, 38 (France); CEA Grenoble, energies alternatives, 38 (France); Guillet, N. [CEA Grenoble, Lab. d' innovation pour les technologies des energies nouvelles et les nanomateriaux, 38 (France); Fruchart, D. [Institut Neel du CNRS, 38 - Grenoble (France); Societe McPhy Energy, 26 - La Motte Fanjas (France); Fontecave, M. [College de France, 75 - Paris (France)

    2011-07-15

    Hydrogen has a strong energetic potential. In order to exploit this potential and transform this energy into electricity, two chemical reactions could be used which do not release any greenhouse effect gas: hydrogen can be produced by water electrolysis, and then hydrogen and oxygen can be combined to produce water and release heat and electricity. Hydrogen can therefore be used to store energy. In Norway, the exceeding electricity produced by wind turbines in thus stored in fuel cells, and the energy of which is used when the wind weakens. About ten dwellings are thus supplied with only renewable energy. Similar projects are being tested in Corsica and in the Reunion Island. The main challenges for this technology are its cost, its compactness and its durability. The article gives an overview of the various concepts, apparatus and systems involved in hydrogen and energy production. Some researches are inspired by bacteria which produce hydrogen with enzymes. The objective is to elaborate better catalysts. Another explored perspective is the storage of solid hydrogen

  5. Hydrogen and energy utilities

    Energy Technology Data Exchange (ETDEWEB)

    Hustadt, Daniel [Vattenfall Europe Innovation GmbH (Germany)

    2010-07-01

    Renewable electricity generation plays one major role with the biggest share being wind energy. At the end of the year 2009 a wind power plant capacity of around 26 GW was installed in Germany. Several outlooks come to the conclusion that this capacity can be doubled in ten years (compare Figure 1). Additionally the German government has set a target of 26 GW installed off-shore capacity in North and Baltic Sea until 2030. At Vattenfall only a minor percentage of the electricity production comes from wind power today. This share will be increased up to 12% until 2030 following Vattenfall's strategy 'Making Electricity Clean'. This rapid development of wind power offers several opportunities but also means some challenges to Utilities. (orig.)

  6. Path-integral molecular dynamics simulations of hydrated hydrogen chloride cluster HCl(H{sub 2}O){sub 4} on a semiempirical potential energy surface

    Energy Technology Data Exchange (ETDEWEB)

    Takayanagi, Toshiyuki, E-mail: tako@mail.saitama-u.ac.jp [Department of Chemistry, Saitama University, 255 Shimo-Okubo, Sakura-ku, Saitama City, Saitama 338-8570 (Japan); Takahashi, Kenta; Kakizaki, Akira [Department of Chemistry, Saitama University, 255 Shimo-Okubo, Sakura-ku, Saitama City, Saitama 338-8570 (Japan); Shiga, Motoyuki [Center for Computational Science and E-systems, Japan Atomic Energy Agency, Higashi-Ueno 6-9-3, Taito-ku, Tokyo 110-0015 (Japan); Tachikawa, Masanori [Quantum Chemistry Division, International Graduate School of Arts and Sciences, Yokohama-City University, Seto 22-2, Kanazawa-ku, Yokohama 236-0027 (Japan)

    2009-04-22

    Path-integral molecular dynamics simulations for the HCl(H{sub 2}O){sub 4} cluster have been performed on the ground-state potential energy surface directly obtained on-the-fly from semiempirical PM3-MAIS molecular orbital calculations. It is found that the HCl(H{sub 2}O){sub 4} cluster has structural rearrangement above the temperature of 300 K showing a liquid-like behavior. Quantum mechanical fluctuation of hydrogen nuclei plays a significant role in structural arrangement processes in this cluster.

  7. Path-integral molecular dynamics simulations of hydrated hydrogen chloride cluster HCl(H 2O) 4 on a semiempirical potential energy surface

    Science.gov (United States)

    Takayanagi, Toshiyuki; Takahashi, Kenta; Kakizaki, Akira; Shiga, Motoyuki; Tachikawa, Masanori

    2009-04-01

    Path-integral molecular dynamics simulations for the HCl(H 2O) 4 cluster have been performed on the ground-state potential energy surface directly obtained on-the-fly from semiempirical PM3-MAIS molecular orbital calculations. It is found that the HCl(H 2O) 4 cluster has structural rearrangement above the temperature of 300 K showing a liquid-like behavior. Quantum mechanical fluctuation of hydrogen nuclei plays a significant role in structural arrangement processes in this cluster.

  8. Energy storage possibilities of atomic hydrogen

    Science.gov (United States)

    Etters, R. D.; Dugan, J. V., Jr.; Palmer, R.

    1976-01-01

    Several recent experiments designed to produce and store macroscopic quantities of atomic hydrogen are discussed. The bulk, ground state properties of atomic hydrogen, deuterium, and tritium systems are calculated assuming that all pair interactions occur via the atomic triplet potential. The conditions required to obtain this system, including inhibition of recombination through the energetically favorable singlet interaction, are discussed. The internal energy, pressure, and compressibility are calculated applying the Monte Carlo technique with a quantum mechanical variational wavefunction. The system studied consisted of 32 atoms in a box with periodic boundary conditions. Results show that atomic triplet hydrogen and deuterium remain gaseous at 0 K; i.e., the internal energy is positive at all molar volumes considered.

  9. The prospects for hydrogen as an energy carrier: an overview of hydrogen energy and hydrogen energy systems

    Energy Technology Data Exchange (ETDEWEB)

    Rosen, Marc A.; Koohi-Fayegh, Seama [Ontario Univ., Oshawa, ON (Canada). Inst. of Technology

    2016-02-15

    Hydrogen is expected to play a key role as an energy carrier in future energy systems of the world. As fossil-fuel supplies become scarcer and environmental concerns increase, hydrogen is likely to become an increasingly important chemical energy carrier and eventually may become the principal chemical energy carrier. When most of the world's energy sources become non-fossil based, hydrogen and electricity are expected to be the two dominant energy carriers for the provision of end-use services. In such a ''hydrogen economy,'' the two complementary energy carriers, hydrogen and electricity, are used to satisfy most of the requirements of energy consumers. A transition era will bridge the gap between today's fossil-fuel economy and a hydrogen economy, in which non-fossil-derived hydrogen will be used to extend the lifetime of the world's fossil fuels - by upgrading heavy oils, for instance - and the infrastructure needed to support a hydrogen economy is gradually developed. In this paper, the role of hydrogen as an energy carrier and hydrogen energy systems' technologies and their economics are described. Also, the social and political implications of hydrogen energy are examined, and the questions of when and where hydrogen is likely to become important are addressed. Examples are provided to illustrate key points. (orig.)

  10. Storing Renewable Energy in the Hydrogen Cycle.

    Science.gov (United States)

    Züttel, Andreas; Callini, Elsa; Kato, Shunsuke; Atakli, Züleyha Özlem Kocabas

    2015-01-01

    An energy economy based on renewable energy requires massive energy storage, approx. half of the annual energy consumption. Therefore, the production of a synthetic energy carrier, e.g. hydrogen, is necessary. The hydrogen cycle, i.e. production of hydrogen from water by renewable energy, storage and use of hydrogen in fuel cells, combustion engines or turbines is a closed cycle. Electrolysis splits water into hydrogen and oxygen and represents a mature technology in the power range up to 100 kW. However, the major technological challenge is to build electrolyzers in the power range of several MW producing high purity hydrogen with a high efficiency. After the production of hydrogen, large scale and safe hydrogen storage is required. Hydrogen is stored either as a molecule or as an atom in the case of hydrides. The maximum volumetric hydrogen density of a molecular hydrogen storage is limited to the density of liquid hydrogen. In a complex hydride the hydrogen density is limited to 20 mass% and 150 kg/m(3) which corresponds to twice the density of liquid hydrogen. Current research focuses on the investigation of new storage materials based on combinations of complex hydrides with amides and the understanding of the hydrogen sorption mechanism in order to better control the reaction for the hydrogen storage applications.

  11. Classical and Mexican hat-type potential energy curve for the hydrogen molecule from a confined Kratzer oscillator

    Science.gov (United States)

    van Hooydonk, G.

    2016-03-01

    We review harmonic oscillator theory for closed, stable quantum systems. The H2 potential energy curve (PEC) of Mexican hat-type, calculated with a confined Kratzer oscillator, is better than the Rydberg-Klein-Rees (RKR) H2 PEC. Compared with QM, the theory of chemical bonding is simplified, since a confined Kratzer oscillator can also lead to the long sought for universal function, once called the Holy Grail of Molecular Spectroscopy. This is validated by reducing PECs for different bonds H2, HF, I2, N2 and O2 to a single one. The equal probability for H2, originating either from HA + HB or HB + HA, is quantified with a Gauss probability density function. At the Bohr scale, a confined harmonic oscillator behaves properly at the extremes of bound two-nucleon quantum systems.

  12. Ab initio based potential energy surface and kinetics study of the OH + NH3 hydrogen abstraction reaction.

    Science.gov (United States)

    Monge-Palacios, M; Rangel, C; Espinosa-Garcia, J

    2013-02-28

    A full-dimensional analytical potential energy surface (PES) for the OH + NH3 → H2O + NH2 gas-phase reaction was developed based exclusively on high-level ab initio calculations. This reaction presents a very complicated shape with wells along the reaction path. Using a wide spectrum of properties of the reactive system (equilibrium geometries, vibrational frequencies, and relative energies of the stationary points, topology of the reaction path, and points on the reaction swath) as reference, the resulting analytical PES reproduces reasonably well the input ab initio information obtained at the coupled-cluster single double triple (CCSD(T)) = FULL/aug-cc-pVTZ//CCSD(T) = FC/cc-pVTZ single point level, which represents a severe test of the new surface. As a first application, on this analytical PES we perform an extensive kinetics study using variational transition-state theory with semiclassical transmission coefficients over a wide temperature range, 200-2000 K. The forward rate constants reproduce the experimental measurements, while the reverse ones are slightly underestimated. However, the detailed analysis of the experimental equilibrium constants (from which the reverse rate constants are obtained) permits us to conclude that the experimental reverse rate constants must be re-evaluated. Another severe test of the new surface is the analysis of the kinetic isotope effects (KIEs), which were not included in the fitting procedure. The KIEs reproduce the values obtained from ab initio calculations in the common temperature range, although unfortunately no experimental information is available for comparison.

  13. Configuration and technology implications of potential nuclear hydrogen system applications.

    Energy Technology Data Exchange (ETDEWEB)

    Conzelmann, G.; Petri, M.; Forsberg, C.; Yildiz, B.; ORNL

    2005-11-05

    Nuclear technologies have important distinctions and potential advantages for large-scale generation of hydrogen for U.S. energy services. Nuclear hydrogen requires no imported fossil fuels, results in lower greenhouse-gas emissions and other pollutants, lends itself to large-scale production, and is sustainable. The technical uncertainties in nuclear hydrogen processes and the reactor technologies needed to enable these processes, as well waste, proliferation, and economic issues must be successfully addressed before nuclear energy can be a major contributor to the nation's energy future. In order to address technical issues in the time frame needed to provide optimized hydrogen production choices, the Nuclear Hydrogen Initiative (NHI) must examine a wide range of new technologies, make the best use of research funding, and make early decisions on which technology options to pursue. For these reasons, it is important that system integration studies be performed to help guide the decisions made in the NHI. In framing the scope of system integration analyses, there is a hierarchy of questions that should be addressed: What hydrogen markets will exist and what are their characteristics? Which markets are most consistent with nuclear hydrogen? What nuclear power and production process configurations are optimal? What requirements are placed on the nuclear hydrogen system? The intent of the NHI system studies is to gain a better understanding of nuclear power's potential role in a hydrogen economy and what hydrogen production technologies show the most promise. This work couples with system studies sponsored by DOE-EE and other agencies that provide a basis for evaluating and selecting future hydrogen production technologies. This assessment includes identifying commercial hydrogen applications and their requirements, comparing the characteristics of nuclear hydrogen systems to those market requirements, evaluating nuclear hydrogen configuration options

  14. Hydrogen Energy by Means of Proton Conductors

    DEFF Research Database (Denmark)

    Jensen, Jens Oluf

    , but matching supply and demand in time as well as in form calls for new engineering solutions. Hydrogen as energy carrier and energy storage medium has often been mentioned as an option for the future. A protons is an elementary particles, but at the same time the ion of hydrogen. When hydrogen (H2......) is extracted from water (H2O) it can happen via formation of protons (hydrogen ions, H+) which must be transported away by proton conducting materials to form molecular hydrogen (H2). This process is called electrolysis and converts electrical energy into the chemical energy of a fuel. The reverse process...

  15. The Energy Efficiency of Onboard Hydrogen Storage

    DEFF Research Database (Denmark)

    Jensen, Jens Oluf; Vestbø, Andreas Peter; Li, Qingfeng

    2007-01-01

    A number of the most common ways of storing hydrogen are reviewed in terms of energy efficiency. Distinction is made between energy losses during regeneration and during hydrogen liberation. In the latter case, the energy might have to be provided by part of the released hydrogen, and the true st...... storage density is then equivalently smaller. Systems covered include compressed and liquid hydrogen, reversible and irreversible metal hydrides, and methanol and ammonia.......A number of the most common ways of storing hydrogen are reviewed in terms of energy efficiency. Distinction is made between energy losses during regeneration and during hydrogen liberation. In the latter case, the energy might have to be provided by part of the released hydrogen, and the true...

  16. Validation of an Integrated Hydrogen Energy Station

    Energy Technology Data Exchange (ETDEWEB)

    Heydorn, Edward C

    2012-10-26

    This report presents the results of a 10-year project conducted by Air Products and Chemicals, Inc. (Air Products) to determine the feasibility of coproducing hydrogen with electricity. The primary objective was to demonstrate the technical and economic viability of a hydrogen energy station using a high-temperature fuel cell designed to produce power and hydrogen. This four-phase project had intermediate go/no-go decisions and the following specific goals: Complete a technical assessment and economic analysis of the use of high-temperature fuel cells, including solid oxide and molten carbonate, for the co-production of power and hydrogen (energy park concept). Build on the experience gained at the Las Vegas H2 Energy Station and compare/contrast the two approaches for co-production. Determine the applicability of co-production from a high-temperature fuel cell for the existing merchant hydrogen market and for the emerging hydrogen economy. Demonstrate the concept on natural gas for six months at a suitable site with demand for both hydrogen and electricity. Maintain safety as the top priority in the system design and operation. Obtain adequate operational data to provide the basis for future commercial activities, including hydrogen fueling stations. Work began with the execution of the cooperative agreement with DOE on 30 September 2001. During Phase 1, Air Products identified high-temperature fuel cells as having the potential to meet the coproduction targets, and the molten carbonate fuel cell system from FuelCell Energy, Inc. (FuelCell Energy) was selected by Air Products and DOE following the feasibility assessment performed during Phase 2. Detailed design, construction and shop validation testing of a system to produce 250 kW of electricity and 100 kilograms per day of hydrogen, along with site selection to include a renewable feedstock for the fuel cell, were completed in Phase 3. The system also completed six months of demonstration operation at the

  17. Kinetics study of the CN + CH4 hydrogen abstraction reaction based on a new ab initio analytical full-dimensional potential energy surface.

    Science.gov (United States)

    Espinosa-Garcia, Joaquin; Rangel, Cipriano; Suleimanov, Yury V

    2017-07-26

    We have developed an analytical full-dimensional potential energy surface, named PES-2017, for the gas-phase hydrogen abstraction reaction between the cyano radical and methane. This surface is fitted using high-level ab initio information as input. Using the PES-2017 surface, a kinetics study was performed via two theoretical approaches: variational transition-state theory with multidimensional tunnelling (VTST-MT) and ring polymer molecular dynamics (RPMD). The results are compared with the experimental data. In the whole temperature range analysed, 300-1500 K, both theories agree within a factor of kinetic isotope effects are important, reproducing the scarce experimental evidence. The good agreement with the ab initio information used in the fitting process (self-consistency test) and with the kinetic behaviour in a wide temperature range gives confidence and strength to the new surface.

  18. Potential energy savings

    DEFF Research Database (Denmark)

    Schultz, Jørgen Munthe

    1996-01-01

    This chapter describes the chosen methods for estimating the potential energy savings if ordinary window glazing is exchanged with aerogel glazing as well as commercial low-energy glazings.......This chapter describes the chosen methods for estimating the potential energy savings if ordinary window glazing is exchanged with aerogel glazing as well as commercial low-energy glazings....

  19. The hydrogen energy in Japan; La filiere hydrogene au Japon

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-07-01

    The Japan needs to import feel fossil fuels. In order to develop other energy sources, the Government supports many research programs on the hydrogen production, storage and distribution. This report takes stock on these programs. (A.L.B.)

  20. Thermochemical water decomposition. [hydrogen separation for energy applications

    Science.gov (United States)

    Funk, J. E.

    1977-01-01

    At present, nearly all of the hydrogen consumed in the world is produced by reacting hydrocarbons with water. As the supply of hydrocarbons diminishes, the problem of producing hydrogen from water alone will become increasingly important. Furthermore, producing hydrogen from water is a means of energy conversion by which thermal energy from a primary source, such as solar or nuclear fusion of fission, can be changed into an easily transportable and ecologically acceptable fuel. The attraction of thermochemical processes is that they offer the potential for converting thermal energy to hydrogen more efficiently than by water electrolysis. A thermochemical hydrogen-production process is one which requires only water as material input and mainly thermal energy, or heat, as an energy input. Attention is given to a definition of process thermal efficiency, the thermodynamics of the overall process, the single-stage process, the two-stage process, multistage processes, the work of separation and a process evaluation.

  1. a Theoretical Investigation on 10-12 Potential of Hydrogen-Hydrogen Covalent Bond

    Science.gov (United States)

    Taneri, Sencer

    2013-05-01

    This is an analytical investigation of well-known 10-12 potential of hydrogen-hydrogen covalent bond. In this research, we will make an elaboration of the well-known 6-12 Lennard-Jones potential in case of this type of bond. Though the results are illustrated in many text books and literature, an analytical analysis for these potentials is missing almost everywhere. The power laws are valid for small radial distances, which are calculated to some extent. The internuclear separation as well as the binding energy of the hydrogen molecule are evaluated with success.

  2. Exactly Solvable Hydrogen-like Potentials and Factorization Method

    CERN Document Server

    Rosas-Ortiz, J O

    1998-01-01

    It is introduced a set of factorization energies giving place to a generalization of the Schrödinger and Infeld-Hull factorization for the radial Hydrogen-like Hamiltonian. An algebraic intertwinning technique involving such factorization energies leads us to derive $n$-parametric families of potentials in general almost-isospectral to the Hydrogen-like radial Hamiltonians. The construction of a SUSY partner Hamiltonian using a factorization energy $\\epsilon_l^{(k)}$ greater than the ground state energy of the departure Hamiltonian is explicitely performed.

  3. Economics and market potential of hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Swisher, Dr., James; Berger, Dr., Beverly; Fickett, Dr., A.; Dickson, Dr., E.

    1978-09-01

    A study was undertaken to evaluate the economics of producing hydrogen from coal and from water and to assess the market potential for this hydrogen in chemical and fuel applications. Results of this study are summarized. Current chemical applications of hydrogen in manufacturing ammonia and methanol, in refining petroleum and in specialty uses provide a base market for penetration by new hydrogen production technologies, although prospects for the use of hydrogen in fuel applications remain unclear. Electrolysis and coal gasification will be complementary, not competitive, technologies for producing hydrogen. Coal gasification plants are better suited to production of large quantities of hydrogen, while electrolyzers are better suited to the production of hydrogen for small-scale uses. Hydrogen produced through coal gasification may be economical in chemical applications (e.g., ammonia production) by the late 1990's. Development programs now underway are expected to provide new coal gasification technologies with lower first costs and higher efficiencies than current technologies. An on-site coal gasification plant supplying hydrogen in the quantities usually required in chemical applications (from 10 to 100 million cubic feet per day) will be smaller than is generally proposed for syngas plants. Growth in smaller scale specialty uses of hydrogen and improvements in the technology for electrolysis will create conditions favorable to expanded use of hydrogen produced through water electrolysis. The major constraint on use of electrolysis will be the availability of low cost electricity. Shortages of natural gas caused by declining domestic production could induce shifts to producing hydrogen through electrolysis or through coal gasification earlier in time (i.e., the late 1980's or early 1990's) than is suggested by comparative cost calculations alone.

  4. New perspectives on potential hydrogen storage materials using high pressure.

    Science.gov (United States)

    Song, Yang

    2013-09-21

    In addressing the global demand for clean and renewable energy, hydrogen stands out as the most suitable candidate for many fuel applications that require practical and efficient storage of hydrogen. Supplementary to the traditional hydrogen storage methods and materials, the high-pressure technique has emerged as a novel and unique approach to developing new potential hydrogen storage materials. Static compression of materials may result in significant changes in the structures, properties and performance that are important for hydrogen storage applications, and often lead to the formation of unprecedented phases or complexes that have profound implications for hydrogen storage. In this perspective article, 22 types of representative potential hydrogen storage materials that belong to four major classes--simple hydride, complex hydride, chemical hydride and hydrogen containing materials--were reviewed. In particular, their structures, stabilities, and pressure-induced transformations, which were reported in recent experimental works together with supporting theoretical studies, were provided. The important contextual aspects pertinent to hydrogen storage associated with novel structures and transitions were discussed. Finally, the summary of the recent advances reviewed and the insight into the future research in this direction were given.

  5. Energy Policy is Technology Politics The Hydrogen Energy Case

    Energy Technology Data Exchange (ETDEWEB)

    Carl-Jochen Winter [ENERGON, Obere St. Leonhardstr. 9, 88662 Uberlingen, T 07551 944 5940, F 07551 944 5941 (Germany)

    2006-07-01

    Germany's energy supply status shows both an accumulation of unsatisfactory sustainabilities putting the nation's energy security at risk, and a hopeful sign: The nation's supply dependency on foreign sources and the accordingly unavoidable price dictate the nation suffers under is almost life risking; the technological skill, however, of the nation's researchers, engineers, and industry materializes in a good percentage of the indigenous and the world's energy conversion technology market. Exemplified with the up and coming hydrogen energy economy this paper tries to advocate the 21. century energy credo: energy policy is energy technology politics{exclamation_point} Energy source thinking and acting is 19. and 20. century, energy efficient conversion technology thinking and acting is 21. century. Hydrogen energy is on the verge of becoming the centre-field of world energy interest. Hydrogen energy is key for the de-carbonization and, thus, sustainabilization of fossil fuels, and as a storage and transport means for the introduction of so far un-operational huge renewable sources into the world energy market. - What is most important is hydrogen's thermodynamic ability to exergize the energy scheme: hydrogen makes more technical work (exergy) out of less primary energy{exclamation_point} Hydrogen adds value. Hydrogen energy and, in particular, hydrogen energy technologies, are to become part of Germany's national energy identity; accordingly, national energy policy as energy technology politics needs to grow in the nation's awareness as common sense{exclamation_point} Otherwise Germany seems ill-equipped energetically, and its well-being hangs in the balance. (author)

  6. Hydrogen-based electrochemical energy storage

    Science.gov (United States)

    Simpson, Lin Jay

    2013-08-06

    An energy storage device (100) providing high storage densities via hydrogen storage. The device (100) includes a counter electrode (110), a storage electrode (130), and an ion conducting membrane (120) positioned between the counter electrode (110) and the storage electrode (130). The counter electrode (110) is formed of one or more materials with an affinity for hydrogen and includes an exchange matrix for elements/materials selected from the non-noble materials that have an affinity for hydrogen. The storage electrode (130) is loaded with hydrogen such as atomic or mono-hydrogen that is adsorbed by a hydrogen storage material such that the hydrogen (132, 134) may be stored with low chemical bonding. The hydrogen storage material is typically formed of a lightweight material such as carbon or boron with a network of passage-ways or intercalants for storing and conducting mono-hydrogen, protons, or the like. The hydrogen storage material may store at least ten percent by weight hydrogen (132, 134) at ambient temperature and pressure.

  7. Energy Levels of Hydrogen and Deuterium

    Science.gov (United States)

    SRD 142 Energy Levels of Hydrogen and Deuterium (Web, free access)   This database provides theoretical values of energy levels of hydrogen and deuterium for principle quantum numbers n = 1 to 200 and all allowed orbital angular momenta l and total angular momenta j. The values are based on current knowledge of the revelant theoretical contributions including relativistic, quantum electrodynamic, recoil, and nuclear size effects.

  8. How HE (Hydrogen Energy) Knowledge and Innovativeness Affect Potential Innovators' Acceptance and Opinions Regarding HE An example from UNIDO-ICHET Web-site Users

    Energy Technology Data Exchange (ETDEWEB)

    Mavis Tsai; Scott Warren; Reide Song; JingYi Gao [Shih Hsin University, 1, Lane 17, Mu-Cha Road, Sec. 1, Taiwan (China)

    2006-07-01

    According to innovation diffusion research, the innovators, opinion leaders, and diffusion agents play vital roles in promoting the acceptance of innovation. The purpose of this research is to investigate how HE innovators' knowledge affects their acceptance and opinions about HE and related products. The research method is an on-line survey and the sample is a voluntary sample. This survey successfully collected 1126 HE innovators' information. The researchers used SPSS statistics software to analyze the data and found the relationship between HE innovators' demographics, their knowledge about hydrogen energy, their innovativeness, and their familiarity with new energy technology with their acceptance and opinions about HE, and how they use the UNIDO-ICHET web-site. The researchers found HE knowledge could be used to predict new energy innovators' information resource usage, innovativeness, new energy product adoption and their opinions about HE. (authors)

  9. Hydrogen utilization potential in subsurface sediments

    Directory of Open Access Journals (Sweden)

    Rishi Ram Adhikari

    2016-01-01

    Full Text Available Subsurface microbial communities undertake many terminal electron-accepting processes, often simultaneously. Using a tritium-based assay, we measured the potential hydrogen oxidation catalyzed by hydrogenase enzymes in several subsurface sedimentary environments (Lake Van, Barents Sea, Equatorial Pacific and Gulf of Mexico with different predominant electron-acceptors. Hydrogenases constitute a diverse family of enzymes expressed by microorganisms that utilize molecular hydrogen as a metabolic substrate, product or intermediate. The assay reveals the potential for utilizing molecular hydrogen and allows qualitative detection of microbial activity irrespective of the predominant electron-accepting process. Because the method only requires samples frozen immediately after recovery, the assay can be used for identifying microbial activity in subsurface ecosystems without the need to preserve live material.We measured potential hydrogen oxidation rates in all samples from multiple depths at several sites that collectively span a wide range of environmental conditions and biogeochemical zones. Potential activity normalized to total cell abundance ranges over five orders of magnitude and varies, dependent upon the predominant terminal electron acceptor. Lowest per-cell potential rates characterize the zone of nitrate reduction and highest per-cell potential rates occur in the methanogenic zone. Possible reasons for this relationship to predominant electron acceptor include (i increasing importance of fermentation in successively deeper biogeochemical zones and (ii adaptation of H2ases to successively higher concentrations of H2 in successively deeper zones.

  10. Genetic algorithm approach to global optimization of the full-dimensional potential energy surface for hydrogen atom at fcc-metal surfaces

    Science.gov (United States)

    Kammler, Marvin; Janke, Svenja M.; Kandratsenka, Alexander; Wodtke, Alec M.

    2017-09-01

    We have developed a genetic algorithm approach for the parametrization of a multi-dimensional potential energy surface based on the analytical expression for energy derived from Effective Medium Theory by fitting it to DFT data. This approach yields consistent results for the H-atom interaction energy with a number of fcc-metal surfaces (Al, Ag, Au, Cu, Ni, Pd, Pt and Rh) and provides reasonable energy values for virtually any system geometry including various facets.

  11. Rating hydrogen as a potential aviation fuel

    Science.gov (United States)

    Witcofski, R. D.

    1980-01-01

    The viability of liquid hydrogen, liquid methane, and synthetic aviation kerosene as future alternate fuels for transport aircraft is analyzed, and the results of a comparative assessment are given in terms of cost, energy resource utilization, areas of fuel production, transmission airport facilities, and ultimate use in the aircraft. Important safety (fires) and some environmental aspects (CO2 balance) are also described. It is concluded that fuel price estimates indicate the price of synthetic aviation kerosene (synjet) would be approximately half of the price calculated for liquid hydrogen and somewhat less than that of liquid methane, with synjet from oil shale reported to be the least expensive.

  12. The hydrogen: a clean and durable energy; L'hydrogene: une energie propre et durable

    Energy Technology Data Exchange (ETDEWEB)

    Alleau, Th. [Association Francaise de l' Hydrogene (France); Nejat Veziroglu, T. [Clean Energy Research Institute, University of Miami (United States); Lequeux, G. [Commission europeenne, DG de la Recherche, Bruxelles (Belgium)

    2000-07-01

    All the scientific experts agree, the hydrogen will be the energy vector of the future. During this conference day on the hydrogen, the authors recalled the actual economic context of the energy policy with the importance of the environmental policy and the decrease of the fossil fuels. The research programs and the attitudes of the France and the other countries facing the hydrogen are also discussed, showing the great interest for this clean and durable energy. They underline the importance of an appropriate government policy, necessary to develop the technology of the hydrogen production, storage and use. (A.L.B.)

  13. Wind-To-Hydrogen Energy Pilot Project

    Energy Technology Data Exchange (ETDEWEB)

    Ron Rebenitsch; Randall Bush; Allen Boushee; Brad G. Stevens; Kirk D. Williams; Jeremy Woeste; Ronda Peters; Keith Bennett

    2009-04-24

    WIND-TO-HYDROGEN ENERGY PILOT PROJECT: BASIN ELECTRIC POWER COOPERATIVE In an effort to address the hurdles of wind-generated electricity (specifically wind's intermittency and transmission capacity limitations) and support development of electrolysis technology, Basin Electric Power Cooperative (BEPC) conducted a research project involving a wind-to-hydrogen system. Through this effort, BEPC, with the support of the Energy & Environmental Research Center at the University of North Dakota, evaluated the feasibility of dynamically scheduling wind energy to power an electrolysis-based hydrogen production system. The goal of this project was to research the application of hydrogen production from wind energy, allowing for continued wind energy development in remote wind-rich areas and mitigating the necessity for electrical transmission expansion. Prior to expending significant funding on equipment and site development, a feasibility study was performed. The primary objective of the feasibility study was to provide BEPC and The U.S. Department of Energy (DOE) with sufficient information to make a determination whether or not to proceed with Phase II of the project, which was equipment procurement, installation, and operation. Four modes of operation were considered in the feasibility report to evaluate technical and economic merits. Mode 1 - scaled wind, Mode 2 - scaled wind with off-peak, Mode 3 - full wind, and Mode 4 - full wind with off-peak In summary, the feasibility report, completed on August 11, 2005, found that the proposed hydrogen production system would produce between 8000 and 20,000 kg of hydrogen annually depending on the mode of operation. This estimate was based on actual wind energy production from one of the North Dakota (ND) wind farms of which BEPC is the electrical off-taker. The cost of the hydrogen produced ranged from $20 to $10 per kg (depending on the mode of operation). The economic sensitivity analysis performed as part of the

  14. Hydrogen: an energy vector for the future?

    Energy Technology Data Exchange (ETDEWEB)

    His, St

    2004-07-01

    Used today in various industrial sectors including refining and chemicals, hydrogen is often presented as a promising energy vector for the transport sector. However, its balance sheet presents disadvantages as well as advantages. For instance, some of its physical characteristics are not very well adapted to transport use and hydrogen does not exist in pure form. Hydrogen technologies can offer satisfactory environmental performance in certain respects, but remain handicapped by costs too high for large-scale development. A great deal of research will be required to develop mass transport application. (author)

  15. Hydrogen utilization potential in subsurface sediments

    DEFF Research Database (Denmark)

    Adhikari, Rishi Ram; Glombitza, Clemens; Nickel, Julia

    2016-01-01

    Pacific, and Gulf of Mexico) with different predominant electron-acceptors. Hydrogenases constitute a diverse family of enzymes expressed by microorganisms that utilize molecular hydrogen as a metabolic substrate, product, or intermediate. The assay reveals the potential for utilizing molecular hydrogen...... and allows qualitative detection of microbial activity irrespective of the predominant electron-accepting process. Because the method only requires samples frozen immediately after recovery, the assay can be used for identifying microbial activity in subsurface ecosystems without the need to preserve live...

  16. Characterizations of Hydrogen Energy Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Energetics Inc

    2003-04-01

    In 1996, Dr. Ed Skolnik of Energetics, Incorporated, began a series of visits to the locations of various projects that were part of the DOE Hydrogen Program. The site visits/evaluations were initiated to help the DOE Program Management, which had limited time and limited travel budgets, to get a detailed snapshot of each project. The evaluations were soon found to have other uses as well: they provided reviewers on the annual Hydrogen Program Peer Review Team with an in-depth look at a project--something that is lacking in a short presentation--and also provided a means for hydrogen stakeholders to learn about the R&D that the Hydrogen Program is sponsoring. The visits were conducted under several different contract mechanisms, at project locations specified by DOE Headquarters Program Management, Golden Field Office Contract Managers, or Energetics, Inc., or through discussion by some or all of the above. The methodology for these site-visit-evaluations changed slightly over the years, but was fundamentally as follows: Contact the Principal Investigator (PI) and arrange a time for the visit; Conduct a literature review. This would include a review of the last two or three years of Annual Operating Plan submittals, monthly reports, the paper submitted with the last two or three Annual Peer Review, published reviewers' consensus comments from the past few years, publications in journals, and journal publications on the same or similar topics by other researchers; Send the PI a list of questions/topics about a week ahead of time, which we would discuss during the visit. The types of questions vary depending on the project, but include some detailed technical questions that delve into some fundamental scientific and engineering issues, and also include some economic and goal-oriented topics; Conduct the site-visit itself including--Presentations by the PI and/or his staff. This would be formal in some cases, informal in others, and merely a &apos

  17. Solar Photovoltaic Hydrogen: The Technologies and Their Place in Our Roadmaps and Energy Economics

    Energy Technology Data Exchange (ETDEWEB)

    Kazmerski, L. L.; Broussard, K.

    2004-08-01

    Future solar photovoltaics-hydrogen systems are discussed in terms of the evolving hydrogen economy. The focus is on distributed hydrogen, relying on the same distributed-energy strengths of solar-photovoltaic electricity in the built environment. Solar-hydrogen residences/buildings, as well as solar parks, are presented. The economics, feasibility, and potential of these approaches are evaluated in terms of roadmap predictions on photovoltaic and hydrogen pathways-and whether solar-hydrogen fit in these strategies and timeframes. Issues with the ''hydrogen future'' are considered, and alternatives to this hydrogen future are examined.

  18. Solar photovoltaic hydrogen: the technologies and their place in our road-maps and energy economics

    Energy Technology Data Exchange (ETDEWEB)

    Kazmerski, L.L. [National Renewable Energy Laboratory, Golden, Colorado (United States); Broussard, K. [Southern Univ., Baton Rouge, LA (United States)

    2004-07-01

    Future solar photovoltaic-hydrogen systems are discussed in terms of the evolving hydrogen economy. The focus is on distributed hydrogen, relying on the same distributed-energy strengths of solar-photovoltaic electricity in the built environment. Solar-hydrogen residences/buildings, as well as solar parks, are presented. The economics, feasibility, and potential of these approaches are evaluated in terms of road-map predictions on photovoltaic and hydrogen pathways and whether solar-hydrogen fit in these strategies and time-frames. Issues with the ''hydrogen future'' are considered, and alternatives to this hydrogen future are examined. (authors)

  19. Hydrogen: Its Future Role in the Nation's Energy Economy.

    Science.gov (United States)

    Winsche, W E; Hoffman, K C; Salzano, F J

    1973-06-29

    In examining the potential role of hydrogen in the energy economy of the future, we take an optimistic view. All the technology required for implementation is feasible but a great deal of development and refinement is necessary. A pessimistic approach would obviously discourage further thinking about an important and perhaps the most reasonable alternative for the future. We have considered a limited number of alternative energy systems involving hydrogen and have shown that hydrogen could be a viable secondary source of energy derived from nuclear power; for the immediate future, hydrogen could be derived from coal. A hydrogen supply system could have greater flexibility and be competitive with a more conventional all-electric delivery system. Technological improvements could make hydrogen as an energy source an economic reality. The systems examined in this article show how hydrogen can serve as a general-purpose fuel for residential and automotive applications. Aside from being a source of heat and motive power, hydrogen could also supply the electrical needs of the household via fuel cells (19), turbines, or conventional "total energy systems." The total cost of energy to a residence supplied with hydrogen fuel depends on the ratio of the requirements for direct fuel use to the requirements for electrical use. A greater direct use of hydrogen as a fuel without conversion to electricity reduces the overall cost of energy supplied to the household because of the greater expense of electrical transmission and distribution. Hydrogen fuel is especially attractive for use in domestic residential applications where the bulk of the energy requirement is for thermal energy. Although a considerable amount of research is required before any hydrogen energy delivery system can be implemented, the necessary developments are within the capability of present-day technology and the system could be made attractive economically .Techniques for producing hydrogen from water by

  20. Analytical potential energy function for the ground state(1A1) of hydrogen isotopic D2O molecule

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The present work is to construct the potential energy function of isotopic molecules. The so-called molecular potential energy function is the electronic energy function under Born-Oppenheimer approximation,in which the nuclear motions(translational,rotational and vibration motions) are not included,therefore,its nuclear vibration motion and isotopic effect need to be considered. Based on group theory and atomic and molecular reactive statics(AMRS),the reasonable dissociation limits of D2O(1A1)are determined,its equilibrium geometry and dissociation energy are calculated by density-functional theory(DFT) B3lyp,and then,using the many-body expansion method the potential energy function of D2O(1A1) is obtained for the first time. The potential contours are drawn,in which it is found that the reactive channel D + OD→D2O has no threshold energy,so it is a free radical reaction. But the reactive channel O + DD→D2O has a saddle point. The study of collision for D2O(1A1) is under way.

  1. Analytical potential energy function for the ground state (~X1A1) of hydrogen isotopic D2O molecule

    Institute of Scientific and Technical Information of China (English)

    RUAN Wen; LUO WenLang; ZHANG Li; ZHU ZhengHe

    2009-01-01

    The present work is to construct the potential energy function of Isotopic molecules. The so-called molecular potential energy function is the electronic energy function under Born-Oppenheimer ap-proximation, in which the nuclear motions (translational, rotational and vibration motions) are not in-cluded, therefore, its nuclear vibration motion and isotopic effect need to be considered. Based on group theory and atomic and molecular reactive statics (AMRS), the reasonable dissociation limits of D2O(~X1A1) are determined, its equilibrium geometry and dissociation energy are calculated by den-sity-functional theory (DFT) B3lyp, and then, using the many-body expansion method the potential en-ergy function of D2O (~X1A1) Is obtained for the first time. The potential contours are drawn, in which It is found that the reactive channel D + OD→D2O has no threshold energy, so it is a free radical reaction. But the reactive channel O + DD→D2P has a saddle point. The study of collision for D2O (~X1A1) is under way.

  2. Hydrogen Energy Storage (HES) and Power-to-Gas Economic Analysis; NREL (National Renewable Energy Laboratory)

    Energy Technology Data Exchange (ETDEWEB)

    Eichman, Joshua

    2015-07-30

    This presentation summarizes opportunities for hydrogen energy storage and power-to-gas and presents the results of a market analysis performed by the National Renewable Energy Laboratory to quantify the value of energy storage. Hydrogen energy storage and power-to-gas systems have the ability to integrate multiple energy sectors including electricity, transportation, and industrial. On account of the flexibility of hydrogen systems, there are a variety of potential system configurations. Each configuration will provide different value to the owner, customers and grid system operator. This presentation provides an economic comparison of hydrogen storage, power-to-gas and conventional storage systems. The total cost is compared to the revenue with participation in a variety of markets to assess the economic competitiveness. It is found that the sale of hydrogen for transportation or industrial use greatly increases competitiveness. Electrolyzers operating as demand response devices (i.e., selling hydrogen and grid services) are economically competitive, while hydrogen storage that inputs electricity and outputs only electricity have an unfavorable business case. Additionally, tighter integration with the grid provides greater revenue (e.g., energy, ancillary service and capacity markets are explored). Lastly, additional hours of storage capacity is not necessarily more competitive in current energy and ancillary service markets and electricity markets will require new mechanisms to appropriately compensate long duration storage devices.

  3. Reactors Save Energy, Costs for Hydrogen Production

    Science.gov (United States)

    2014-01-01

    While examining fuel-reforming technology for fuel cells onboard aircraft, Glenn Research Center partnered with Garrettsville, Ohio-based Catacel Corporation through the Glenn Alliance Technology Exchange program and a Space Act Agreement. Catacel developed a stackable structural reactor that is now employed for commercial hydrogen production and results in energy savings of about 20 percent.

  4. Hydrogen Energy Storage (HES) Activities at NREL; NREL (National Renewable Energy Laboratory)

    Energy Technology Data Exchange (ETDEWEB)

    Eichman, J.

    2015-04-21

    This presentation provides an overview of hydrogen and energy storage, including hydrogen storage pathways and international power-to-gas activities, and summarizes the National Renewable Energy Laboratory's hydrogen energy storage activities and results.

  5. Overview of International Energy Agency Annex 18 on evaluation of integrated hydrogen energy systems

    Energy Technology Data Exchange (ETDEWEB)

    Miles, S. [Natural Resources Canada, Ottawa, ON (Canada); Schoenung, S. [Longitude 122 West Inc., Menlo Park, CA (United States); Dube, J. [Services Mij Inc., Ste. Thecle, Quebec, (Canada); Ulleberg, O. [Inst. of Energy Technology, Halden (Norway); Weeda, M. [Energy Research Center of the Netherlands, Petten (Netherlands)

    2007-07-01

    Hydrogen and fuel cell technologies have the potential to break the link between transportation and carbon dioxide emissions. As part of Annex 18, the International Energy Agency (IEA) provides information about hydrogen integration into society by providing data and analysis to the hydrogen community; evaluating hydrogen demonstration projects in member countries; and, synthesizing the lessons learned from projects. This paper presented projects that were motivated by the use of clean, renewable energy to produce hydrogen with reduced carbon emissions. Annex 18 has been underway since January 2003. Demonstration systems involving vehicle refuelling stations and electric power systems in different member countries were evaluated in the first phase of Annex 18 through detailed modeling and documentation. These projects included hydrogen refueling stations in Sweden, Iceland and Canada; a PV/MH-telecom showcase in Madrid, Spain; a regenerative PEM FC-power system in Aichi, Japan; a hydrogen and renewables integration (HARI) system in Leistershire, United Kingdom; a hydrogen from the sun/ecological house in Brunate, Italy; an RES2H2 wind-hydrogen project in Athens, Greece; a combined wind/hydrogen desalination plant in the Canary Islands, Spain; a renewable hydrogen system at a remote site Totara Valley, New Zealand; and, a hydrogen power park with combined wind and geothermal electricity generation in Hawaii, United States. Phase 2 and is now scheduled to continue through December 2009. It will involve an accounting of the emissions in order to quantify the carbon reductions. Participants will continue to evaluate the performance of these demonstration systems and determine how the use of hydrogen can mitigate climate change in the future. The final phase will determine best practices and general lessons learned regarding the commercialization and operation of integrated hydrogen systems. 7 refs., 2 tabs., 13 figs.

  6. Wind-To-Hydrogen Energy Pilot Project

    Energy Technology Data Exchange (ETDEWEB)

    Ron Rebenitsch; Randall Bush; Allen Boushee; Brad G. Stevens; Kirk D. Williams; Jeremy Woeste; Ronda Peters; Keith Bennett

    2009-04-24

    WIND-TO-HYDROGEN ENERGY PILOT PROJECT: BASIN ELECTRIC POWER COOPERATIVE In an effort to address the hurdles of wind-generated electricity (specifically wind's intermittency and transmission capacity limitations) and support development of electrolysis technology, Basin Electric Power Cooperative (BEPC) conducted a research project involving a wind-to-hydrogen system. Through this effort, BEPC, with the support of the Energy & Environmental Research Center at the University of North Dakota, evaluated the feasibility of dynamically scheduling wind energy to power an electrolysis-based hydrogen production system. The goal of this project was to research the application of hydrogen production from wind energy, allowing for continued wind energy development in remote wind-rich areas and mitigating the necessity for electrical transmission expansion. Prior to expending significant funding on equipment and site development, a feasibility study was performed. The primary objective of the feasibility study was to provide BEPC and The U.S. Department of Energy (DOE) with sufficient information to make a determination whether or not to proceed with Phase II of the project, which was equipment procurement, installation, and operation. Four modes of operation were considered in the feasibility report to evaluate technical and economic merits. Mode 1 - scaled wind, Mode 2 - scaled wind with off-peak, Mode 3 - full wind, and Mode 4 - full wind with off-peak In summary, the feasibility report, completed on August 11, 2005, found that the proposed hydrogen production system would produce between 8000 and 20,000 kg of hydrogen annually depending on the mode of operation. This estimate was based on actual wind energy production from one of the North Dakota (ND) wind farms of which BEPC is the electrical off-taker. The cost of the hydrogen produced ranged from $20 to $10 per kg (depending on the mode of operation). The economic sensitivity analysis performed as part of the

  7. Feasibility study on recovering hydrogen energy from industrial wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Ming Der BAI; Chia-Jung HSIAO [Energy and Resource Laboratories, Industrial Technology Research Institute, 195, sec. 4 Chung Hsing Rd., Chutung, Hsinchu, Taiwan, 301 R.O.C. (China)

    2006-07-01

    Three wastewater obtained from different industries were evaluated for the feasibility of hydrogen fermentation. Because of the various components of the wastewater, the characteristics of the hydrogen accumulation were different. Several stages with different hydrogen producing rate were observed during the batch hydrogen fermentation of each wastewater. The obvious hydrogen consumption was observed in the last phase of hydrogen fermentation of the wastewater from the winery. It is similar to the reported hydrogen fermentation characteristic of starch. The wastewater coming from the fructose manufactory has the greatest hydrogen potential nearly 150 L-H{sub 2}/kg-COD. The wastewater from food industry has the lower hydrogen potential of 65 L-H{sub 2}/kg-COD. Some of its compounds were not suitable for hydrogen production. The lowest hydrogen potential was observed in the fermentation of the wastewater from the winery, because hydrogen consumption affects the hydrogen recovery from the wastewater from winery. (authors)

  8. Feasibility study on recovering hydrogen energy from industrial wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Ming Der Bai; Chia-Jung Hsiao [Energy and Resource Laboratories, Industrial Technology Research Institute, 195, sec. 4 Chung Hsing Rd., Chutung, Hsinchu, Taiwan, 301 R.O.C. (China)

    2006-07-01

    Three wastewater obtained from different industries were evaluated for the feasibility of hydrogen fermentation. Because of the various components of the wastewater, the characteristics of the hydrogen accumulation were different. Several stages with different hydrogen producing rate were observed during the batch hydrogen fermentation of each wastewater. The obvious hydrogen consumption was observed in the last phase of hydrogen fermentation of the wastewater from the winery. It is similar to the reported hydrogen fermentation characteristic of starch. The wastewater coming from the fructose manufactory has the greatest hydrogen potential nearly 150 L-H{sub 2}/kg-COD. The wastewater from food industry has the lower hydrogen potential of 65 L-H{sub 2}/kg-COD. Some of its compounds were not suitable for hydrogen production. The lowest hydrogen potential was observed in the fermentation of the wastewater from the winery, because hydrogen consumption affects the hydrogen recovery from the wastewater from winery. (authors)

  9. Key strategies of hydrogen energy systems for sustainability

    Energy Technology Data Exchange (ETDEWEB)

    Midilli, Adnan [Department of Mechanical Engineering, Faculty of Engineering, Nigde University, Nigde 51100 (Turkey); Dincer, Ibrahim [Faculty of Engineering and Applied Science, University of Ontario Institute of Technology (UOIT), 2000 Simcoe Street North, Oshawa, Ont. (Canada)

    2007-04-15

    Here we conduct a parametric study to investigate the effects of hydrogen energy utilization on the global stability and sustainability. In this regard, in order to derive the hydrogen energy based sustainability ratio, the green energy based sustainability ratio, as developed earlier, is modified to come up with a new parameter, namely ''hydrogen energy utilization ratio through non-fossil fuels''. We take actual historical data from key sources to determine the role of hydrogen energy for sustainability and make some future projections as the road map for hydrogen economy. In addition, an illustrative example on the hydrogen energy based sustainability ratio is presented by considering green energy sources such as solar, wind, hydro and nuclear to make hydrogen economy more environmentally benign and sustainable. It is found that hydrogen energy based global stability and sustainability ratios increase with the rise of hydrogen energy utilization ratio. The best results for hydrogen energy based sustainability ratio are obtained for the highest hydrogen energy impact ratios between 73.33% and 100%. In case of 10% of hydrogen energy utilization ratio, hydrogen based sustainability ratios for year 2010 are, respectively, determined to be 0.21%, 0.23%, 0.25%, 0.27% and 0.29% in 2.92% of hydrogen based global stability ratio by depending on the hydrogen energy impact ratios (=73.33%, 80%, 86.67%, 93.33% and 100%). In case of 20% of hydrogen energy utilization ratio, the hydrogen energy based sustainability ratios are found to be 1.09%, 1.19%, 1.28%, 1.38% and 1.48% in 7.41%, respectively. The results are really encouraging in a way that hydrogen economy appears to be one of the most significant players for better sustainability. (author)

  10. Plasma screening effects on the energies of hydrogen atom

    Energy Technology Data Exchange (ETDEWEB)

    Soylu, A. [Department of Physics, Nigde University, 51240 Nigde (Turkey)

    2012-07-15

    A more general exponential cosine screened Coulomb potential is used for the first time to investigate the screening effects on the hydrogen atom in plasmas. This potential is examined for four different cases that correspond to four different type potentials when the different parameters are used in the potential within the framework of the well-known asymptotic iteration method. By solving the corresponding the radial Schroedinger equation with the screened and exponential cosine screened Coulomb potentials and comparing the obtained energy eigenvalues with the results of other studies, the applicability of the method to this kind of plasma physics problem is shown. The energy values of more general exponential cosine screened Coulomb potential are presented for various parameters in the potential. One of the advantages of the present potential is that it exhibits stronger screening effect than that of the exponential cosine screened Coulomb potential and it is also reduced to screened Coulomb and exponential cosine screened Coulomb as well as Coulomb potentials for special values of parameters. The parameters in the potential would be useful to model screening effects which cause an increase or decrease in the energy values of hydrogen atom in both Debye and quantum plasmas and in this manner this potential would be useful for the investigations of the atomic structure and collisions in plasmas.

  11. 21st Century's energy: Hydrogen energy system

    Energy Technology Data Exchange (ETDEWEB)

    Veziroglu, T.N.; Sahin, S. [Gazi University, Ankara (Turkey)

    2008-07-15

    Fossil fuels (i.e., petroleum, natural gas and coal), which meet most of the world's energy demand today, are being depleted fast. Also, their combustion products are causing the global problems, such as the greenhouse effect, ozone layer depletion, acid rains and pollution, which are posing great danger for our environment and eventually for the life in our planet. Many engineers and scientists agree that the solution to these global problems would be to replace the existing fossil fuel system by the hydrogen energy system. Hydrogen is a very efficient and clean fuel. Its combustion will produce no greenhouse gases, no ozone layer depleting chemicals, little or no acid rain ingredients and pollution. Hydrogen, produced from renewable energy (e.g., solar) sources, would result in a permanent energy system, which we would never have to change. However, there are other energy systems proposed for the post-petroleum era, such as a synthetic fossil fuel system. In this system, synthetic gasoline and synthetic natural gas will be produced using abundant deposits of coal. In a way, this will ensure the continuation of the present fossil fuel system. The two possible energy systems for the post-fossil fuel era (i.e., the solar-hydrogen energy system and the synthetic fossil fuel system) are compared with the present fossil fuel system by taking into consideration production costs, environmental damages and utilization efficiencies. The results indicate that the solar-hydrogen energy system is the best energy system to ascertain a sustainable future, and it should replace the fossil fuel system before the end of the 21st century.

  12. Hydrogen based energy storage for solar energy systems

    Energy Technology Data Exchange (ETDEWEB)

    Vanhanen, J.P.; Hagstroem, M.T.; Lund, P.H. [Helsinki Univ. of Technology, Otaniemi (Finland). Dept. of Engineering Physics and Mathematics; Leppaenen, J.R.; Nieminen, J.P. [Neste Oy (Finland)

    1998-12-31

    Hydrogen based energy storage options for solar energy systems was studied in order to improve their overall performance. A 1 kW photovoltaic hydrogen (PV-H2) pilot-plant and commercial prototype were constructed and a numerical simulation program H2PHOTO for system design and optimisation was developed. Furthermore, a comprehensive understanding of conversion (electrolysers and fuel cells) and storage (metal hydrides) technologies was acquired by the project partners. The PV-H{sub 2} power system provides a self-sufficient solution for applications in remote locations far from electric grids and maintenance services. (orig.)

  13. Microalgal hydrogen production: prospects of an essential technology for a clean and sustainable energy economy.

    Science.gov (United States)

    Bayro-Kaiser, Vinzenz; Nelson, Nathan

    2017-09-01

    Modern energy production is required to undergo a dramatic transformation. It will have to replace fossil fuel use by a sustainable and clean energy economy while meeting the growing world energy needs. This review analyzes the current energy sector, available energy sources, and energy conversion technologies. Solar energy is the only energy source with the potential to fully replace fossil fuels, and hydrogen is a crucial energy carrier for ensuring energy availability across the globe. The importance of photosynthetic hydrogen production for a solar-powered hydrogen economy is highlighted and the development and potential of this technology are discussed. Much successful research for improved photosynthetic hydrogen production under laboratory conditions has been reported, and attempts are underway to develop upscale systems. We suggest that a process of integrating these achievements into one system to strive for efficient sustainable energy conversion is already justified. Pursuing this goal may lead to a mature technology for industrial deployment.

  14. Economic Dispatch of Hydrogen Systems in Energy Spot Markets

    DEFF Research Database (Denmark)

    You, Shi; Nørgård, Per Bromand

    2015-01-01

    Hydrogen system, as a new energy carrier, could deliver clean and efficient energy services in a wide range of applications. This paper presents an economic dispatch-based mathematical model that facilitates investigations on the techno-economic feasibility of hydrogen systems in the context...... of energy spot markets. The generic hydrogen system is comprised of an electrolysis for hydrogen production, a hydrogen storage tank and a fuel cell system for cogeneration of electricity and heat. A case study is presented with information from practical hydrogen systems and the Nordic energy markets...

  15. Seasonal energy storage - PV-hydrogen systems

    Energy Technology Data Exchange (ETDEWEB)

    Leppaenen, J. [Neste Oy/NAPS (Finland)

    1998-10-01

    PV systems are widely used in remote areas e.g. in telecommunication systems. Typically lead acid batteries are used as energy storage. In northern locations seasonal storage is needed, which however is too expensive and difficult to realise with batteries. Therefore, a PV- battery system with a diesel backup is sometimes used. The disadvantages of this kind of system for very remote applications are the need of maintenance and the need to supply the fuel. To overcome these problems, it has been suggested to use hydrogen technologies to make a closed loop autonomous energy storage system

  16. Hydrogen based energy storage for energy harvesting systems

    Energy Technology Data Exchange (ETDEWEB)

    Bretthauer, Christian

    2011-07-01

    This thesis presents the development of a novel type of silicon integrated alkaline fuel cell - electrolyser device as on-chip energy storage. The alkaline environment allows not only a facilitated water management compared to state-of-the-art acidic integrated fuel cell systems, it further allows the usage of non-precious metal catalysts and hydrogen storage materials, for the first time. Additionally, a button cell shaped version of the accumulator is presented that incorporates a photoactive SrTiO{sub 3} ceramic for solar recharge. The solar charging mechanism is shown to be inherently self-regulating such that the cell depicts essentially a Micro Hydrogen Economy including energy conversion, energy management and energy storage in a single device. (orig.)

  17. HYDROGEN ENERGY: TERCEIRA ISLAND DEMONSTRATION FACILITY

    Directory of Open Access Journals (Sweden)

    MARIO ALVES

    2008-07-01

    Full Text Available The present paper gives a general perspective of the efforts going on at Terceira Island in Azores, Portugal, concerning the implementation of an Hydrogen Economy demonstration campus. The major motivation for such a geographical location choice was the abundance of renewable resources like wind, sea waves and geothermal enthalpy, which are of fundamental importance for the demonstration of renewable hydrogen economy sustainability. Three main campus will be implemented: one at Cume Hill, where the majority of renewable hydrogen production will take place using the wind as the primary energy source, a second one at Angra do Heroismo Industrial park, where a cogen electrical – heat power station will be installed, mainly to feed a Municipal Solid Waste processing plant and a third one, the Praia da Vitoria Hydrogenopolis, where several final consumer demonstrators will be installed both for public awareness and intensive study of economic sustainability and optimization. Some of these units are already under construction, particularly the renewable hydrogen generation facilities.

  18. A hydrogen energy carrier. Volume 1: Summary. [for meeting energy requirements

    Science.gov (United States)

    Savage, R. L. (Editor); Blank, L. (Editor); Cady, T. (Editor); Cox, K. E. (Editor); Murray, R. (Editor); Williams, R. D. (Editor)

    1973-01-01

    The production, technology, transportation, and implementation of hydrogen into the energy system are discussed along with the fossil fuel cycle, hydrogen fuel cycle, and the demands for energy. The cost of hydrogen production by coal gasification; electrolysis by nuclear energy, and solar energy are presented. The legal aspects of a hydrogen economy are also discussed.

  19. Potential energy savings

    DEFF Research Database (Denmark)

    Schultz, Jørgen Munthe

    1996-01-01

    The background for the simulations of annual energy consumption and indoor temperature level is described.......The background for the simulations of annual energy consumption and indoor temperature level is described....

  20. Modeling of an Integrated Renewable Energy System (IRES) with hydrogen storage

    Science.gov (United States)

    Shenoy, Navin Kodange

    2010-12-01

    Scope and Method of Study. The purpose of the study was to consider the integration of hydrogen storage technology as means of energy storage with renewable sources of energy. Hydrogen storage technology consists of an alkaline electrolyzer, gas storage tank and a fuel cell. The Integrated Renewable Energy System (IRES) under consideration includes wind energy, solar energy from photovoltaics, solar thermal energy and biomass energy in the form of biogas. Energy needs are categorized depending on the type and quality of the energy requirements. After meeting all the energy needs, any excess energy available from wind and PVs is converted into hydrogen using an electrolyzer for later use in a fuel cell. Similarly, when renewable energy generation is not able to supply the actual load demand, the stored hydrogen is utilized through fuel cell to fulfill load demand. Analysis of how IRES operates in order to satisfy different types of energy needs is discussed. Findings and Conclusions. All simulations are performed using MATLAB software. Hydrogen storage technology consisting of an electrolyzer, gas storage tank and a fuel cell is incorporated in the IRES design process for a hypothetical remote community. Results show that whenever renewable energy generated is greater than the electrical demand, excess energy is stored in the form of hydrogen and in case of energy shortfall, the stored hydrogen is utilized through the fuel cell to supply to excess power demand. The overall operation of IRES is enhanced as a result of energy storage in the form of hydrogen. Hydrogen has immense potential to be the energy carrier of the future because of its clean character and the model of hydrogen storage discussed here can form an integral part of IRES for remote area applications.

  1. Analysis of the potential for hydrogen production in the province of Cordoba, Argentina, from wind resources

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, C.R.; Santa Cruz, R.; Aisa, S. [Universidad Empresarial Siglo 21, Monsenor Pablo Cabrera s/n calle, 5000 Cordoba (Argentina); Riso, M.; Jimenez Yob, G.; Ottogalli, R. [Subsecretaria de Infraestructuras y Programas, Ministerio de Obras y Servicios Publicos del Gobierno de la Provincia de Cordoba, Av. Poeta Lugones 12, 2do. Piso, 5000 Cordoba (Argentina); Jeandrevin, G. [Instituto Universitario Aeronautico, Avenida Fuerza Aerea km 6 1/2, 5022 Cordoba (Argentina); Leiva, E.P.M. [INFIQC, Unidad de Matematica y Fisica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Haya de la Torre s/n, 5010 Cordoba (Argentina)

    2010-06-15

    The potential for hydrogen production from wind resources in the province of Cordoba, second consumer of fossil fuels for transportation in Argentina, is analyzed. Three aspects of the problem are considered: the evaluation of the hydrogen resource from wind power, the analysis of the production costs via electrolysis and the annual requirements of wind energy to generate hydrogen to fuel the vehicular transport of the province. Different scenarios were considered, including pure hydrogen as well as the so-called CNG plus, where hydrogen is mixed with compressed natural gas in a 20% V/V dilution of the former. The potential for hydrogen production from wind resources is analyzed for each department of the province, excluding those regions not suited for wind farms. The analysis takes into account the efficiency of the electrolyzer and the capacity factor of the wind power system. It is concluded that the automotive transportation could be supplied by hydrogen stemming from wind resources via electrolysis. (author)

  2. Hydrogen-Based Energy Conservation System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Sustainable Innovations is developing a technology for efficient separation and compression of hydrogen gas. The electrochemical hydrogen separator and compressor...

  3. Hydrogen based global renewable energy network

    Energy Technology Data Exchange (ETDEWEB)

    Akai, Makoto [Mechanical Engineering Laboratory, AIST, MITI, Namiki, Tsukuba (Japan)

    1993-12-31

    In the last quarter of this century, global environmental problem has emerged as a major scientific, political and social issue. Specific Problems include: depletion of ozone layer by chlorofluorocarbons (CFCs), acid rain, destruction of tropical forests and desertification, pollution of the sea and global wanning due to the greenhouse effect by carbon dioxide and others. Among these problems, particular attention of the world has been focused on the global warming because it has direct linkage to energy consumption which our economic development depends on so far. On the other hand, the future program of The Sunshine Project for alternative energy technology R&D, The Moonlight Project for energy conservation technology R&D, and The Global Environmental Technology Program for environmental problem mitigating technology R&D which are Japan`s national projects being promoted by their Agency of Industrial Science and Technology (AIST) in the Ministry of International Trade and Industry have been reexamined in view of recent changes in the situations surrounding new energy technology. In this regard, The New Sunshine Program will be established by integrating these three activities to accelerate R&D in the field of energy and environmental technologies. In the reexamination, additional stress has been laid on the contribution to solving global environmental problem through development of clean renewable energies which constitute a major part of the {open_quotes}New Earth 21{close_quotes}, a comprehensive, long-term and international cooperative program proposed by MITI. The present paper discusses the results of feasibility study on hydrogen energy system leading to the concept of WE-NET following a brief summary on R&D status on solar and wind energy in Japan.

  4. The linear relationship between Koopmans' and hydrogen bond energies for some simple carbonyl molecules

    Directory of Open Access Journals (Sweden)

    Bruns Roy E.

    2002-01-01

    Full Text Available Recently Galabov and Bobadova-Parvanova have shown that the energy of hydrogen bond formation calculated at the HF/6-31G(d,p level is highly correlated with the molecular electrostatic potential at the acceptor site for a number of simple carbonyl compounds. Here it is shown that the electrostatic potential can be replaced by Koopmans' energy. The correlation between this energy and the hydrogen bond formation energy is just as high as the one observed by Galabov and Bobadova-Parvanova. The Siegbahn simple potential relating Koopmans' energies and GAPT charges shows that the hydrogen bond energy is not simply correlated with the charge of the acceptor site because the charges on the neighboring atoms are also important in the hydrogen bonding process.

  5. Proceedings of the DOE chemical energy storage and hydrogen energy systems contracts review

    Energy Technology Data Exchange (ETDEWEB)

    1980-02-01

    Sessions were held on electrolysis-based hydrogen storage systems, hydrogen production, hydrogen storage systems, hydrogen storage materials, end-use applications and system studies, chemical heat pump/chemical energy storage systems, systems studies and assessment, thermochemical hydrogen production cycles, advanced production concepts, and containment materials. (LHK)

  6. U.S. Department of Energy Hydrogen Storage Cost Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Law, Karen; Rosenfeld, Jeffrey; Han, Vickie; Chan, Michael; Chiang, Helena; Leonard, Jon

    2013-03-11

    The overall objective of this project is to conduct cost analyses and estimate costs for on- and off-board hydrogen storage technologies under development by the U.S. Department of Energy (DOE) on a consistent, independent basis. This can help guide DOE and stakeholders toward the most-promising research, development and commercialization pathways for hydrogen-fueled vehicles. A specific focus of the project is to estimate hydrogen storage system cost in high-volume production scenarios relative to the DOE target that was in place when this cost analysis was initiated. This report and its results reflect work conducted by TIAX between 2004 and 2012, including recent refinements and updates. The report provides a system-level evaluation of costs and performance for four broad categories of on-board hydrogen storage: (1) reversible on-board metal hydrides (e.g., magnesium hydride, sodium alanate); (2) regenerable off-board chemical hydrogen storage materials(e.g., hydrolysis of sodium borohydride, ammonia borane); (3) high surface area sorbents (e.g., carbon-based materials); and 4) advanced physical storage (e.g., 700-bar compressed, cryo-compressed and liquid hydrogen). Additionally, the off-board efficiency and processing costs of several hydrogen storage systems were evaluated and reported, including: (1) liquid carrier, (2) sodium borohydride, (3) ammonia borane, and (4) magnesium hydride. TIAX applied a bottom-up costing methodology customized to analyze and quantify the processes used in the manufacture of hydrogen storage systems. This methodology, used in conjunction with ® software and other tools, developed costs for all major tank components, balance-of-tank, tank assembly, and system assembly. Based on this methodology, the figure below shows the projected on-board high-volume factory costs of the various analyzed hydrogen storage systems, as designed. Reductions in the key cost drivers may bring hydrogen storage system costs closer to this DOE target

  7. Hydrogen Highways: Lessons on the Energy Technology-Policy Interface

    Science.gov (United States)

    Waegel, Alex; Byrne, John; Tobin, Daniel; Haney, Bryan

    2006-01-01

    The hydrogen economy has received increasing attention recently. Common reasons cited for investigating hydrogen energy options are improved energy security, reduced environmental impacts, and its contribution to a transition to sustainable energy sources. In anticipation of these benefits, national and local initiatives have been launched in the…

  8. On the energy of electric field in hydrogen atom

    OpenAIRE

    Kornyushin, Yuri

    2009-01-01

    It is shown that hydrogen atom is a unique object in physics having negative energy of electric field, which is present in the atom. This refers also to some hydrogen-type atoms: hydrogen anti-atom, atom composed of proton and antiproton, and positronium.

  9. Photosynthetic bacteria as alternative energy sources: overview on hydrogen production research

    Energy Technology Data Exchange (ETDEWEB)

    Mitsui, A.; Ohta, Y.; Frank, J.

    1979-01-01

    Hydrogen production research towards the application of marine and non-marine species of photosynthetic bacteria is reviewed. Potential use of photosynthetic bacteria as renewable energy resources is discussed.

  10. Hydrogen-Based Energy Conservation System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — NASA and many others often rely on delivery of cryogenic hydrogen to meet their facility needs. NASA's Stennis Space Center is one of the largest users of hydrogen,...

  11. Hydrogen peroxide potentiates organophosphate toxicosis in chicks

    Directory of Open Access Journals (Sweden)

    Banan K. Al-Baggou

    2011-11-01

    Full Text Available Objective: The purpose of the present study was to examine the effect of hydrogen peroxide(H2O2 on the acute toxicity of organophosphate insecticides dichlorvos and diazinon and their inhibitoryactions on plasma, brain and liver cholinesterase activities. Material and Methods: H2O2 was given indrinking water (0.5% v/v for 2 weeks in unsexed day old chicks, a regimen known to induce oxidativestress in this species. A control group received drinking tap water. All experiments were conducted onthe chicks at the age of 15 days after exposure to H2O2. The acute (24 h oral LD50 values of dichlorvosand diazinon in the insecticidal preparations as determined by the up-and-down method in the controlchicks were 9.4 and 15.6 mg/kg, respectively. Results: The poisoned chicks manifested signs ofcholinergic toxicosis within one hour after the dosing including salivation, lacrimation, gasping, frequentdefecation, drooping of wings, tremors, convulsions and recumbency. The acute (24 h oral LD50 valuesof dichlorvos and diazinon in chicks provided with H2O2 were reduced to 3.5 and 6.5 mg/kg, by 63 and58%, respectively when compared to respective control LD50 values. The intoxicated chicks also showedcholinergic signs of toxicosis as described above. Plasma, brain and liver cholinesterase activities of thechicks exposed to H2O2 were significantly lower than their respective control (H2O values by 25, 28 and27%, respectively. Oral dosing of chicks with dichlorvos at 3 mg/kg significantly inhibited cholinesteraseactivities in the plasma, brain and liver of both control (42-67% and H2O2-treated (15-59% chicks.Diazinon at 5 mg/kg, orally also inhibited cholinesterase activities in the plasma, brain and liver of bothcontrol (36-66% and H2O2-treated (15-30% chicks. In the H2O2 groups, dichlorvos inhibition of livercholinesterase activity and diazinon inhibition of liver and brain cholinesterase activities weresignificantly lesser than those of the respective values of

  12. Hydrogen Regional Infrastructure Program In Pennsylvania Potential Applications of Friction Stir Welding to the Hydrogen Economy

    Energy Technology Data Exchange (ETDEWEB)

    Brendlinger, Jennifer [Concurrent Technologies Corporation, Johnstown, PA (United States)

    2009-07-17

    Friction Stir Welding (FSW) is a solid-state welding technique developed by The Welding Institute (TWI) of Cambridge, UK in the early 1990’s. The process uses a non-consumable rotating tool to develop frictional heat and plastically deform workpieces to be joined, resulting in a solid-state weld on the trailing side of the advancing tool. Since the materials to be joined are not melted, FSW results in a finer grain structure and therefore enhanced properties, relative to fusion welds. And unlike fusion welding, a relatively small number of key process parameters exist for FSW: tool rotational speed, linear weld velocity and force perpendicular to the joining surface. FSW is more energy efficient than fusion welding and can be accomplished in one or two passes, versus many more passes required of fusion welding thicker workpieces. Reduced post-weld workpiece distortion is another factor that helps to reduce the cost of FSW relative to fusion welding. Two primary areas have been identified for potential impact on the hydrogen economy: FSW of metallic pipes for hydrogen transmission and FSW of aluminum pressure vessels for hydrogen storage. Both areas have been under active development and are explored in this paper.

  13. Wind Energy and Transport Synergy: Electric Vehicle or Hydrogen Vehicle?; Sinergia Energia Eolica Transporte: vehiculo electrico o vehiculo de hidrogeno?

    Energy Technology Data Exchange (ETDEWEB)

    Cruz, I.

    2009-07-01

    This article briefly analyzes the potential uses of hydrogen as a form of energy from wind power. It also briefly describes the different experiences gained in wind energy-based hydrogen production by water hydrolysis, and finally it concludes with a brief analysis of the competition between hydrogen and the new ion-lithium batteries used in motor vehicles as potential solutions to support wind energy management. (Author)

  14. IEA Energy Technology Essentials: Hydrogen Production and Distribution

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-04-15

    The IEA Energy Technology Essentials series offers concise four-page updates on the different technologies for producing, transporting and using energy. Hydrogen Production and Distribution are the topics covered in this edition.

  15. Long term hydrogen production potential of concentrated photovoltaic (CPV) system in tropical weather of Singapore

    KAUST Repository

    Burhan, Muhammad

    2016-08-23

    Concentrated photovoltaic (CPV) system provides highest solar energy conversion efficiency among all the photovoltaic technologies and provides the most suitable option to convert solar energy into hydrogen, as future sustainable energy carrier. So far, only conventional flat plate PV systems are being used for almost all of the commercial applications. However, most of the studies have only shown the maximum efficiency of hydrogen production using CPV. In actual field conditions, the performance of CPV-Hydrogen system is affected by many parameter and it changes continuously during whole day operation. In this paper, the daily average and long term performances are proposed to analyze the real field potential of the CPV-Hydrogen system, which is of main interest for designers and consumers. An experimental setup is developed and a performance model is proposed to investigate the average and long term production potential of CPV-Hydrogen system. The study is carried out in tropical weather of Singapore. The maximum CPV efficiency of 27-28% and solar to hydrogen (STH) efficiency of 18%, were recorded. In addition, the CPV-Hydrogen system showed the long term average efficiency of 15.5%, for period of one year (12-months), with electrolyser rating of 47 kWh/kg and STH production potential of 218 kWh/kg. Based upon the DNI availability, the system showed hydrogen production potential of 0.153-0.553 kg/m/month, with average production of 0.43 kg/m/month. However, CPV-Hydrogen system has shown annual hydrogen production potential of 5.162 kg/m/year in tropical weather of Singapore.

  16. Hydrogen Sulfide in Preeclampsia : Potential Therapeutic Implications

    NARCIS (Netherlands)

    Holwerda, Kim

    2015-01-01

    The thesis provide insights into the production and possible therapeutic effect of the gaseous molecule hydrogen sulfide (H2S) in preeclampsia (PE). H2S is an important molecule in the (human) body. It is among others involved in blood pressure regulation, stimulation of vascular growth and

  17. Hydrogen Sulfide in Preeclampsia : Potential Therapeutic Implications

    NARCIS (Netherlands)

    Holwerda, Kim

    2015-01-01

    The thesis provide insights into the production and possible therapeutic effect of the gaseous molecule hydrogen sulfide (H2S) in preeclampsia (PE). H2S is an important molecule in the (human) body. It is among others involved in blood pressure regulation, stimulation of vascular growth and modulati

  18. 78 FR 52764 - Extension of Public Comment Period Hydrogen Energy California's Integrated Gasification Combined...

    Science.gov (United States)

    2013-08-26

    ... Extension of Public Comment Period Hydrogen Energy California's Integrated Gasification Combined Cycle... period to October 1, 2013 and announces public hearings for the Hydrogen Energy California's Integrated... to California Energy Commission (CEC) or DOE concerning the Hydrogen Energy California Project...

  19. LHC Physics Potential versus Energy

    Energy Technology Data Exchange (ETDEWEB)

    Quigg, Chris; /Fermilab

    2009-08-01

    Parton luminosities are convenient for estimating how the physics potential of Large Hadron Collider experiments depends on the energy of the proton beams. I present parton luminosities, ratios of parton luminosities, and contours of fixed parton luminosity for gg, u{bar d}, and qq interactions over the energy range relevant to the Large Hadron Collider, along with example analyses for specific processes.

  20. Computed potential energy surfaces for chemical reactions

    Science.gov (United States)

    Walch, Stephen P.

    1994-01-01

    Quantum mechanical methods have been used to compute potential energy surfaces for chemical reactions. The reactions studied were among those believed to be important to the NASP and HSR programs and included the recombination of two H atoms with several different third bodies; the reactions in the thermal Zeldovich mechanism; the reactions of H atom with O2, N2, and NO; reactions involved in the thermal De-NO(x) process; and the reaction of CH(squared Pi) with N2 (leading to 'prompt NO'). These potential energy surfaces have been used to compute reaction rate constants and rates of unimolecular decomposition. An additional application was the calculation of transport properties of gases using a semiclassical approximation (and in the case of interactions involving hydrogen inclusion of quantum mechanical effects).

  1. A renewable energy based hydrogen demonstration park in Turkey. HYDEPARK

    Energy Technology Data Exchange (ETDEWEB)

    Ilhan, Niluefer; Ersoez, Atilla [TUEBITAK Marmara Research Center Energy Institute, Gebze Kocaeli (Turkey); Cubukcu, Mete [Ege Univ., Bornova, Izmir (Turkey). Solar Energy Inst.

    2010-07-01

    The main goal of this national project is to research hydrogen technologies and renewable energy applications. Solar and wind energy are utilized to obtain hydrogen via electrolysis, which can either be used in the fuel cell or stored in cylinders for further use. The management of all project work packages was carried by TUeBITAK Marmara Research Center (MRC) Energy Institute (EI) with the support of the collaborators. The aim of this paper is to present the units of the renewable energy based hydrogen demonstration park, which is in the demonstration phase now and share the experimental results. (orig.)

  2. Technical Analysis of the Hydrogen Energy Station Concept, Phase I and Phase II

    Energy Technology Data Exchange (ETDEWEB)

    TIAX, LLC

    2005-05-04

    Phase I Due to the growing interest in establishing a domestic hydrogen infrastructure, several hydrogen fueling stations already have been established around the country as demonstration units. While these stations help build familiarity with hydrogen fuel in their respective communities, hydrogen vehicles are still several years from mass production. This limited number of hydrogen vehicles translates to a limited demand for hydrogen fuel, a significant hurdle for the near-term establishment of commercially viable hydrogen fueling stations. By incorporating a fuel cell and cogeneration system with a hydrogen fueling station, the resulting energy station can compensate for low hydrogen demand by providing both hydrogen dispensing and combined heat and power (CHP) generation. The electrical power generated by the energy station can be fed back into the power grid or a nearby facility, which in turn helps offset station costs. Hydrogen production capacity not used by vehicles can be used to support building heat and power loads. In this way, an energy station can experience greater station utility while more rapidly recovering capital costs, providing an increased market potential relative to a hydrogen fueling station. At an energy station, hydrogen is generated on-site. Part of the hydrogen is used for vehicle refueling and part of the hydrogen is consumed by a fuel cell. As the fuel cell generates electricity and sends it to the power grid, excess heat is reclaimed through a cogeneration system for use in a nearby facility. Both the electrical generation and heat reclamation serve to offset the cost of purchasing the equivalent amount of energy for nearby facilities and the energy station itself. This two-phase project assessed the costs and feasibility of developing a hydrogen vehicle fueling station in conjunction with electricity and cogenerative heat generation for nearby Federal buildings. In order to determine which system configurations and operational

  3. World potential of renewable energies

    Energy Technology Data Exchange (ETDEWEB)

    Dessus, B.; Devin, B.; Pharabod, F.

    1991-07-01

    A comprehensive analysis, region by region, of the actually accessible renewable energies at a given horizon, is presented. The same methodology as the one employed to derive ``proven fossil energy reserves`` from ``energy resources`` is adopted, in which resources are defined by quantitative information on physical potential, while reserves take into account technical and economical accessibility. As renewable resources are fluctuating with time and are diluted in space and not readily transportable or storeable, it is necessary to consider the presence of populations or activities near enough to be able to profit by these diluted and volatile energies.

  4. Relativity, potential energy, and mass

    Science.gov (United States)

    Hecht, Eugene

    2016-11-01

    This paper is an exploration of the concept of energy, illuminated by the transformative insights of the special theory of relativity. Focusing on potential energy (PE), it will be shown that PE as presently defined is in conflict with the tenets of special relativity. Even though PE remains an indispensable theoretical device its actual physicality is questionable. Moreover its ontological status is quite different from that of both kinetic energy and mass, a significant point that is not widely appreciated. We will establish that PE is a theoretical concept as opposed to an empirical one; it is a descriptor of mass-energy without a detectable physical presence of its own. PE is a measure of energy stored, it is not the energy stored.

  5. Risoe energy report 3. Hydrogen and its competitors

    Energy Technology Data Exchange (ETDEWEB)

    Larsen, H.; Feidenhans' l, R.; Soenderberg Petersen, L. (eds.)

    2004-10-01

    Interest in the hydrogen economy has grown rapidly in recent years. Countries with long traditions of activity in hydrogen research and development have now been joined by a large number of newcomers. The main reason for this surge of interest is that the hydrogen economy may be an answer to the two main challenges facing the world in the years to come: climate change and the need for security of energy supplies. Both these challenges require the development of new, highly-efficient energy technologies that are either carbon-neutral or low emitting technologies. Another reason for the growing interest in hydrogen is the strong need for alternative fuels, especially in the transport sector. Alternative fuels could serve as links between the power system and the transport sector, to facilitate the uptake of emerging technologies and increase the flexibility and robustness of the energy system as a whole. This Risoe Energy Report provides a perspective on energy issues at global, regional and national levels. The following pages provide a critical examination of the hydrogen economy and its alternatives. The report explains the current R and D situation addresses the challenges facing the large-scale use of hydrogen, and makes some predictions for the future. The current and future role of hydrogen in energy systems is explored at Danish, European and global levels. The report discusses the technologies for producing, storing and converting hydrogen, the role of hydrogen in the transport sector and in portable electronics, hydrogen infrastructure and distribution systems, and environmental and safety aspects of the hydrogen economy. (BA)

  6. Optimal control strategies for hydrogen production when coupling solid oxide electrolysers with intermittent renewable energies

    Science.gov (United States)

    Cai, Qiong; Adjiman, Claire S.; Brandon, Nigel P.

    2014-12-01

    The penetration of intermittent renewable energies requires the development of energy storage technologies. High temperature electrolysis using solid oxide electrolyser cells (SOECs) as a potential energy storage technology, provides the prospect of a cost-effective and energy efficient route to clean hydrogen production. The development of optimal control strategies when SOEC systems are coupled with intermittent renewable energies is discussed. Hydrogen production is examined in relation to energy consumption. Control strategies considered include maximizing hydrogen production, minimizing SOEC energy consumption and minimizing compressor energy consumption. Optimal control trajectories of the operating variables over a given period of time show feasible control for the chosen situations. Temperature control of the SOEC stack is ensured via constraints on the overall temperature difference across the cell and the local temperature gradient within the SOEC stack, to link materials properties with system performance; these constraints are successfully managed. The relative merits of the optimal control strategies are analyzed.

  7. Early Forest Fire Detection Using Low Energy Hydrogen Sensors

    Directory of Open Access Journals (Sweden)

    Jürgen Müller

    2016-08-01

    Full Text Available The North-east German Lowlands is a region with one of the highest forest fire risks in Europe. In order to keep damage levels as low as possible, it is important to have an effective early warning system. Such a system is being developed on the basis of a hydrogen sensor, which makes it possible to detect a smouldering forest fire before the development of open flames. The prototype hydrogen sensor produced at the Humboldt University Berlin has a metal/ solid electrolyte/insulator/ semiconductor (MEIS structure, which allows cost-effective production. Due to the low energy consumption, an autarchic working unit could be installed in the forest. Field trials have shown that it is possible to identify a forest fire in its early stages when hydrogen concentrations are still low. A significant change in the signal due to a fire was measured at a distance of about 100m. In view of the potential impacts of climate change, the innovative pre-ignition warning system is an important early diagnosis and monitoring module for the protection of the forests.

  8. A renewable energy and hydrogen scenario for northern Europe

    DEFF Research Database (Denmark)

    Sørensen, Bent

    2008-01-01

    storage and fuel cell applications is studied and applied to both stationary energy use and transportation sectors. As an alternative, biofuels may take the role of hydrogen both as a storable fuel and for direct use in the transportation sector. It is shown that there is scope for considerable amounts...... renewable energy supply system is demonstrated with the use of the seasonal reservoir-based hydrocomponents in the northern parts of the region. The outcome of the competition between biofuels and hydrogen in the transportation sector is dependent on the development of viable fuel cells and on efficient......A scenario based entirely on renewable energy with possible use of hydrogen as an energy carrier is constructed for a group of North European countries. Temporal simulation of the demand-supply matching is carried out for various system configurations. The role of hydrogen technologies for energy...

  9. GIS-based preliminary wind-hydrogen energy assessment: A case study for Pakistan

    Science.gov (United States)

    Hussain Siyal, Shahid; Hopper, Miles; Lefvert, Adrian; Mentis, Dimitris; Korkovelos, Alexandros; Lopez De Briñas Gorosabel, Oier; Varela González, Cristina; Howells, Mark

    2017-04-01

    While the world is making progress on incorporating renewables in the electricity grid, the transport sector is still widely locked into using gasoline and diesel fuels. Simultaneously, wind energy is encountering resistance due to its intermittent nature. Wind to hydrogen energy conversion poses a solution to this problem, using wind powered electrolysis to produce hydrogen which can fuel the transport sector. In this report a preliminary assessment for wind to hydrogen energy conversion potential of Pakistan was made considering two different turbines; Vestas V82 and V112. Using available wind speed data, processed in ArcGIS, the hydrogen potential was calculated. Finally, the economic feasibility and potential environmental savings were assessed. From the results it was concluded that Pakistan has a good potential for wind to hydrogen conversion, with 63,807 and 80,232 ktons of hydrogen per year from the V82 and V112 turbines. This corresponds to 2,105 and 2,647 TWh of energy per year respectively. Only using 2% of that potential could give emissions savings of up to 11.43 and 14.37 MtCO2-eq, which would give good reason for more in-depth studies to evaluate the feasibility of a project in Pakistan.

  10. Early forest fire detection using low-energy hydrogen sensors

    Directory of Open Access Journals (Sweden)

    K. Nörthemann

    2013-11-01

    Full Text Available Most huge forest fires start in partial combustion. In the beginning of a smouldering fire, emission of hydrogen in low concentration occurs. Therefore, hydrogen can be used to detect forest fires before open flames are visible and high temperatures are generated. We have developed a hydrogen sensor comprising of a metal/solid electrolyte/insulator/semiconductor (MEIS structure which allows an economical production. Due to the low energy consumption, an autarkic working unit in the forest was established. In this contribution, first experiments are shown demonstrating the possibility to detect forest fires at a very early stage using the hydrogen sensor.

  11. Electron energy-loss spectroscopy study of hydrogenated amorphous silicon

    Energy Technology Data Exchange (ETDEWEB)

    Burnham, N.A.; Fisher, R.F.; Asher, S.E.; Kazmerski, L.L.

    1987-07-01

    Electron energy-loss spectroscopy is used to study hydrogenated amorphous silicon (a-Si:H). Core-level and plasma excitations were examined as a function of hydrogen content. This technique and its interpretation reveals a consistent picture of the electron excitations within this important material. The a-Si:H thin films were fabricated by rf sputtering. Their hydrogen concentrations ranged from 0% to 15%. Hydrogen content was determined by infrared spectroscopy and secondary ion mass spectroscopy. X-ray photoelectron spectroscopy and inspection of the silicon Auger-KLL peak confirmed the silicon core levels.

  12. Assessment of triton potential energy

    CERN Document Server

    Friar, J L

    1996-01-01

    An assessment is made of the dominant features contributing to the triton potential energy, with the objective of understanding qualitatively their origins and sensitivities. Relativistic effects, short-range repulsion, and OPEP dominance are discussed. A determination of the importance of various regions of nucleon-nucleon separation is made numerically.

  13. Assessment of Triton Potential Energy

    Science.gov (United States)

    Friar, J. L.; Payne, G. L.

    1995-12-01

    An assessment is made of the dominant features contributing to the triton potential energy, with the objective of understanding qualitatively their origins and sensitivities. Relativistic effects, short-range repulsion, and OPEP dominance are discussed. A determination of the importance of various regions of nucleon-nucleon separation is made numerically.

  14. Solar-hydrogen energy system model for Libya

    Energy Technology Data Exchange (ETDEWEB)

    Eljrushi, G.S.

    1987-01-01

    A solar-hydrogen energy-system model for Libya was developed, obtaining relationships for and between the main energy and energy related parameters of Libya and the world. The parameters included are: population, energy demand, fossil-fuel production, fossil-fuel resources, hydrogen production, hydrogen introduction rates, energy prices, gross domestic product, pollution and quality of life. The trends of these parameters with and without hydrogen introduction were investigated over a period of time - through the year 2100. The results indicate that the fossil-fuel resources in Libya could be exhausted, due to production for local and export demands, within three to four decades unless serious measures for reducing production are taken. The results indicate that adopting solar-hydrogen energy system would extend the availability of fossil-fuel resources for a longer time period, reduce pollution, improve quality of life and establish a permanent energy system for Libya. It also shows that eventually Libya could export hydrogen in lieu of oil and natural gas.

  15. Hydrogen and fuel cells - The clean energy system

    Science.gov (United States)

    Rohland, B.; Nitsch, J.; Wendt, H.

    1992-01-01

    A strategy where hydrogen is effectively converted into useful energies like electricity and heat by fuel cells in the cogeneration mode is presented. A scenario is presented where renewable energies are used in an extensive but technologically achievable way. Renewable shares of 13 percent (2005), 36 percent (2025), and 69 percent (2050) on the total energy demand will lead to hydrogen shares of 11 percent in 2025 and 34 percent in 2050. Fuel cells provide high conversion efficiencies with respect to electricity and make it possible to use waste heat at different temperature levels. Low- and medium temperature fuel cells using pure hydrogen and high-temperature fuel cells for a mixed biogas-hydrogen conversion with a high energy yield are discussed.

  16. Potential application of anaerobic extremophiles for hydrogen production

    Science.gov (United States)

    Pikuta, Elena V.; Hoover, Richard B.

    2004-11-01

    In processes of the substrate fermentation most anaerobes produce molecular hydrogen as a waste end product, which often controls the culture growth as an inhibitor. Usually in nature the hydrogen is easily removed from an ecosystem, due to its physical features, and an immediate consumption by the secondary anaerobes that sometimes behave as competitors for electron donors; a classical example of this kind of substrate competition in anaerobic microbial communities is the interaction between methanogens and sulfate- or sulfur-reducers. Previously, on the mixed cultures of anaerobes at neutral pH, it was demonstrated that bacterial hydrogen production could provide a good alternative energy source. At neutral pH the original cultures could easily contaminated by methanogens, and the most unpleasant side effect of these conditions is the development of pathogenic bacteria. In both cases the rate of hydrogen production was dramatically decreased since some part of the hydrogen was transformed to methane, and furthermore, the cultivation with pathogenic contaminants on an industrial scale would create an unsafe situation. In our laboratory the experiments with obligately alkaliphilic bacteria producing hydrogen as an end metabolic product were performed at different conditions. The mesophilic, haloalkaliphilic and obligately anaerobic bacterium Spirochaeta americana ASpG1T was studied and various cultivation regimes were compared for the most effective hydrogen production. In a highly mineralized media with pH 9.5-10.0 not many known methanogens are capable of growth, and the probability of developing pathogenic contaminants is theoretically is close to zero (in medicine carbonate- saturated solutions are applied as antiseptics). Therefore the cultivation of alkaliphilic hydrogen producing bacteria could be considered as a safe and economical process for large-scale industrial bio-hydrogen production in the future. Here we present and discuss the experimental data

  17. Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell.

    Science.gov (United States)

    Fukuzumi, Shunichi; Yamada, Yusuke; Karlin, Kenneth D

    2012-11-01

    This review describes homogeneous and heterogeneous catalytic reduction of dioxygen with metal complexes focusing on the catalytic two-electron reduction of dioxygen to produce hydrogen peroxide. Whether two-electron reduction of dioxygen to produce hydrogen peroxide or four-electron O2-reduction to produce water occurs depends on the types of metals and ligands that are utilized. Those factors controlling the two processes are discussed in terms of metal-oxygen intermediates involved in the catalysis. Metal complexes acting as catalysts for selective two-electron reduction of oxygen can be utilized as metal complex-modified electrodes in the electrocatalytic reduction to produce hydrogen peroxide. Hydrogen peroxide thus produced can be used as a fuel in a hydrogen peroxide fuel cell. A hydrogen peroxide fuel cell can be operated with a one-compartment structure without a membrane, which is certainly more promising for the development of low-cost fuel cells as compared with two compartment hydrogen fuel cells that require membranes. Hydrogen peroxide is regarded as an environmentally benign energy carrier because it can be produced by the electrocatalytic two-electron reduction of O2, which is abundant in air, using solar cells; the hydrogen peroxide thus produced could then be readily stored and then used as needed to generate electricity through the use of hydrogen peroxide fuel cells.

  18. Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell

    Science.gov (United States)

    Fukuzumi, Shunichi; Yamada, Yusuke; Karlin, Kenneth D.

    2012-01-01

    This review describes homogeneous and heterogeneous catalytic reduction of dioxygen with metal complexes focusing on the catalytic two-electron reduction of dioxygen to produce hydrogen peroxide. Whether two-electron reduction of dioxygen to produce hydrogen peroxide or four-electron O2-reduction to produce water occurs depends on the types of metals and ligands that are utilized. Those factors controlling the two processes are discussed in terms of metal-oxygen intermediates involved in the catalysis. Metal complexes acting as catalysts for selective two-electron reduction of oxygen can be utilized as metal complex-modified electrodes in the electrocatalytic reduction to produce hydrogen peroxide. Hydrogen peroxide thus produced can be used as a fuel in a hydrogen peroxide fuel cell. A hydrogen peroxide fuel cell can be operated with a one-compartment structure without a membrane, which is certainly more promising for the development of low-cost fuel cells as compared with two compartment hydrogen fuel cells that require membranes. Hydrogen peroxide is regarded as an environmentally benign energy carrier because it can be produced by the electrocatalytic two-electron reduction of O2, which is abundant in air, using solar cells; the hydrogen peroxide thus produced could then be readily stored and then used as needed to generate electricity through the use of hydrogen peroxide fuel cells. PMID:23457415

  19. A manual of recommended practices for hydrogen energy systems

    Energy Technology Data Exchange (ETDEWEB)

    Hoagland, W.; Leach, S. [W. Hoagland and Associates, Boulder, CO (United States)

    1997-12-31

    Technologies for the production, distribution, and use of hydrogen are rapidly maturing and the number and size of demonstration programs designed to showcase emerging hydrogen energy systems is expanding. The success of these programs is key to hydrogen commercialization. Currently there is no comprehensive set of widely-accepted codes or standards covering the installation and operation of hydrogen energy systems. This lack of codes or standards is a major obstacle to future hydrogen demonstrations in obtaining the requisite licenses, permits, insurance, and public acceptance. In a project begun in late 1996 to address this problem, W. Hoagland and Associates has been developing a Manual of Recommended Practices for Hydrogen Systems intended to serve as an interim document for the design and operation of hydrogen demonstration projects. It will also serve as a starting point for some of the needed standard-setting processes. The Manual will include design guidelines for hydrogen procedures, case studies of experience at existing hydrogen demonstration projects, a bibliography of information sources, and a compilation of suppliers of hydrogen equipment and hardware. Following extensive professional review, final publication will occur later in 1997. The primary goal is to develop a draft document in the shortest possible time frame. To accomplish this, the input and guidance of technology developers, industrial organizations, government R and D and regulatory organizations and others will be sought to define the organization and content of the draft Manual, gather and evaluate available information, develop a draft document, coordinate reviews and revisions, and develop recommendations for publication, distribution, and update of the final document. The workshop, Development of a Manual of Recommended Practices for Hydrogen Energy Systems, conducted on March 11, 1997 in Alexandria, Virginia, was a first step.

  20. Alternative propulsion concepts using high-energy batteries and hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Braess, H.-H.

    1988-07-01

    Current projects on electrical and hydrogen propulsion are discussed. The role of electricity and hydrogen in vehicle propulsion, whether in a purely solar energy system or in a mixed nuclear/solar system, but at any rate in an extremely low pollution energy economy is considered. Advanced systems such as the sodium-sulphur battery offer the possibility of providing urban and short range transport (up to a range of 200 km). Larger distances of 200-500 km would have to be covered by using liquid hydrogen fuelled cars with internal combustion engines.

  1. California Industrial Energy Efficiency Potential

    Energy Technology Data Exchange (ETDEWEB)

    Coito, Fred; Worrell, Ernst; Price, Lynn; Masanet, Eric; RafaelFriedmann; Rufo, Mike

    2005-06-01

    This paper presents an overview of the modeling approach andhighlights key findings of a California industrial energy efficiencypotential study. In addition to providing estimates of technical andeconomic potential, the study examines achievable program potential undervarious program-funding scenarios. The focus is on electricity andnatural gas savings for manufacturing in the service territories ofCalifornia's investor-owned utilities (IOUs). The assessment is conductedby industry type and by end use. Both crosscutting technologies andindustry-specific process measures are examined. Measure penetration intothe marketplace is modeled as a function of customer awareness, measurecost effectiveness, and perceived market barriers. Data for the studycomes from a variety of sources, including: utility billing records, theEnergy Information Association (EIA) Manufacturing Energy ConsumptionSurvey (MECS), state-sponsored avoided cost studies, energy efficiencyprogram filings, and technology savings and cost data developed throughLawrence Berkeley National Laboratory (LBNL). The study identifies 1,706GWh and 47 Mth (million therms) per year of achievable potential over thenext twelve years under recent levels of program expenditures, accountingfor 5.2 percent of industrial electricity consumption and 1.3 percent ofindustrial natural gas consumption. These estimates grow to 2,748 GWh and192 Mth per year if all cost-effective and achievable opportunities arepursued. Key industrial electricity end uses, in terms of energy savingspotential, include compressed air and pumping systems that combine toaccount for about half of the total achievable potential estimates. Fornatural gas, savings are concentrated in the boiler and process heatingend uses, accounting for over 99 percent to total achievablepotential.

  2. California Industrial Energy Efficiency Potential

    Energy Technology Data Exchange (ETDEWEB)

    Coito, Fred; Worrell, Ernst; Price, Lynn; Masanet, Eric; RafaelFriedmann; Rufo, Mike

    2005-06-01

    This paper presents an overview of the modeling approach andhighlights key findings of a California industrial energy efficiencypotential study. In addition to providing estimates of technical andeconomic potential, the study examines achievable program potential undervarious program-funding scenarios. The focus is on electricity andnatural gas savings for manufacturing in the service territories ofCalifornia's investor-owned utilities (IOUs). The assessment is conductedby industry type and by end use. Both crosscutting technologies andindustry-specific process measures are examined. Measure penetration intothe marketplace is modeled as a function of customer awareness, measurecost effectiveness, and perceived market barriers. Data for the studycomes from a variety of sources, including: utility billing records, theEnergy Information Association (EIA) Manufacturing Energy ConsumptionSurvey (MECS), state-sponsored avoided cost studies, energy efficiencyprogram filings, and technology savings and cost data developed throughLawrence Berkeley National Laboratory (LBNL). The study identifies 1,706GWh and 47 Mth (million therms) per year of achievable potential over thenext twelve years under recent levels of program expenditures, accountingfor 5.2 percent of industrial electricity consumption and 1.3 percent ofindustrial natural gas consumption. These estimates grow to 2,748 GWh and192 Mth per year if all cost-effective and achievable opportunities arepursued. Key industrial electricity end uses, in terms of energy savingspotential, include compressed air and pumping systems that combine toaccount for about half of the total achievable potential estimates. Fornatural gas, savings are concentrated in the boiler and process heatingend uses, accounting for over 99 percent to total achievablepotential.

  3. Hydrogen as an energy storage; Wasserstoff als Energiespeicher

    Energy Technology Data Exchange (ETDEWEB)

    Wulf, Christina [Technische Univ. Hamburg-Harburg, Hamburg (Germany). Inst. fuer Umwelttechnik und Energiewirtschaft; Hustadt, Daniel; Weinmann, Oliver [Vattenfall Europe Innovation GmbH, Hamburg (Germany)

    2013-05-15

    In order to investigate hydrogen in everyday life, its utilization will be tested and optimized in different scenarios in demonstration facilities. Currently, the excess current for example from wind power plants is not yet sufficient in order to refinance the high investment costs for electrolyzers. Under what conditions do economic potentials exist for the use of hydrogen?.

  4. Future production of hydrogen from solar energy and water - A summary and assessment of U.S. developments

    Science.gov (United States)

    Hanson, J. A.; Escher, W. J. D.

    1979-01-01

    The paper examines technologies of hydrogen production. Its delivery, distribution, and end-use systems are reviewed, and a classification of solar energy and hydrogen production methods is suggested. The operation of photoelectric processes, biophotolysis, photocatalysis, photoelectrolysis, and of photovoltaic systems are reviewed, with comments on their possible hydrogen production potential. It is concluded that solar hydrogen derived from wind energy, photovoltaic technology, solar thermal electric technology, and hydropower could supply some of the hydrogen for air transport by the middle of the next century.

  5. The potential of renewable energy

    Energy Technology Data Exchange (ETDEWEB)

    1990-03-01

    On June 27 and 28, 1989, the US Department of Energy (DOE) national laboratories were convened to discuss plans for the development of a National Energy Strategy (NES) and, in particular, the analytic needs in support of NES that could be addressed by the laboratories. As a result of that meeting, interlaboratory teams were formed to produce analytic white papers on key topics, and a lead laboratory was designated for each core laboratory team. The broad-ranging renewables assignment is summarized by the following issue statement from the Office of Policy, Planning and Analysis: to what extent can renewable energy technologies contribute to diversifying sources of energy supply What are the major barriers to greater renewable energy use and what is the potential timing of widespread commercialization for various categories of applications This report presents the results of the intensive activity initiated by the June 1989 meeting to produce a white paper on renewable energy. Scores of scientists, analysts, and engineers in the five core laboratories gave generously of their time over the past eight months to produce this document. Their generous, constructive efforts are hereby gratefully acknowledged. 126 refs., 44 figs., 32 tabs.

  6. Wind Energy Potential in Bangladesh

    Directory of Open Access Journals (Sweden)

    A.Z.A. Saifullah

    2016-07-01

    Full Text Available Bangladesh is encountering difficulties in supplying energy to maintain its economic growth. Government of Bangladesh is looking for renewable energy sources to meet up the total power demand in this country. The present study aims to assess wind energy potential in Bangladesh as a sustainable solution to overcome the energy crisis. Wind speed at six coastal zones Patenga, Cox’s Bazar, Teknaf, Char Fassion, Kuakata and Kutubdia at Bay of Bengal of Bangladesh have been analyzed. A near shore wind farm has been considered at these locations having a coastal line of 574 km. The turbines are spaced 7D apart in the prevailing wind direction, and 3D apart in the perpendicular direction, where D is rotor diameter. This near shore wind farm with an array of 5104 horizontal axis wind turbines with hub height of 100 m and rotor diameter of 75 m with a wind speed of 7 m/sec is capable to generate 1855.25 MW of electrical power. This can mitigate 55.93 per cent of energy shortage in 2016. By developing renewable energy sources it is possible to compensate 11.25 per cent of total power demand by 2020.

  7. India's hydrogen energy program - a status report

    Energy Technology Data Exchange (ETDEWEB)

    Sastri, M.V.C. (Madras Univ. (IN). Dept. of Energy)

    1989-01-01

    Hydrogen energy research in India started in 1976 on the initiative of the Government of India and covers almost all areas of technical relevance to the deployment of hydrogen as an energy vector. Specifically, these include its production from water by electrolysis, photoelectrolysis, photo-catalysis and biophotolysis, its storage as liquid hydrogen and metal hydrides, its consumptive use as engine fuel and thermal fuel and nonconsumptive application in metal hydrides-based chemical heat pumps. All this research is sponsored and supported by the Government of India. The genesis of hydrogen energy research in India and its growth during the first 10 years have already been reviewed at the VI-WHEC (Vienna, 1986). The present review is an update of the previous report. (author).

  8. Strategy for a sustainable development in the UAE through hydrogen energy

    Energy Technology Data Exchange (ETDEWEB)

    Kazim, Ayoub [Dubai Knowledge Village, P.O. Box 73000 Dubai (United Arab Emirates)

    2010-10-15

    Recently, it has been reported that United Arab Emirates is considered one of the highest energy consumers per capita in the world. Consequently, environmental pollution and carbon emission has been a major challenge facing the country over the past several years due to unprecedented high economic growth rate and abnormal population increase. Utilization of hydrogen energy to fulfill UAE's energy needs would be one of the key measures that the country could undertake to achieve a sustainable development and without any major environmental consequences. Hydrogen energy, which is an energy carrier, is consider by many scientists and researchers a major player in fulfilling the global energy demand due to its attractive features such as being environmentally clean, storable, transportable and inexhaustible. It can be used as a fuel in the proton exchange membrane (PEM) fuel cell, which is an electrochemical device that generates electric power and it can be utilized in various applications. Production of hydrogen energy can be carried out either through utilizing conventional resources or by renewable resources. Conventional resources such as crude oil and natural gas can produce hydrogen by steam-reformation while hydrogen can be produced from coal through gasification. On the other hand, hydrogen production through renewable resources can be achieved through biomass gasification, solar-hydrogen, wind-hydrogen and hydropower electrolysis process. Other renewable resources such as geothermal, wave, tidal and ocean thermal energy conversion (OTEC) can also contribute into hydrogen production but at a marginal level. In this report, a roadmap to achieve a sustainable development in the UAE through utilization of hydrogen energy is presented. The report highlights the potentials of energy resources that the country possesses with respect to both conventional and non-conventional energy and determines major resources that could significantly contribute to production

  9. Quantum mechanical electronic structure calculation reveals orientation dependence of hydrogen bond energy in proteins.

    Science.gov (United States)

    Mondal, Abhisek; Datta, Saumen

    2017-06-01

    Hydrogen bond plays a unique role in governing macromolecular interactions with exquisite specificity. These interactions govern the fundamental biological processes like protein folding, enzymatic catalysis, molecular recognition. Despite extensive research work, till date there is no proper report available about the hydrogen bond's energy surface with respect to its geometric parameters, directly derived from proteins. Herein, we have deciphered the potential energy landscape of hydrogen bond directly from the macromolecular coordinates obtained from Protein Data Bank using quantum mechanical electronic structure calculations. The findings unravel the hydrogen bonding energies of proteins in parametric space. These data can be used to understand the energies of such directional interactions involved in biological molecules. Quantitative characterization has also been performed using Shannon entropic calculations for atoms participating in hydrogen bond. Collectively, our results constitute an improved way of understanding hydrogen bond energies in case of proteins and complement the knowledge-based potential. Proteins 2017; 85:1046-1055. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

  10. Solar Hydrogen Energy Systems Science and Technology for the Hydrogen Economy

    CERN Document Server

    Zini, Gabriele

    2012-01-01

    It is just a matter of time when fossil fuels will become unavailable or uneconomical to retrieve. On top of that, their environmental impact is already too severe. Renewable energy sources can be considered as the most important substitute to fossil energy, since they are inexhaustible and have a very low, if none, impact on the environment. Still, their unevenness and unpredictability are drawbacks that must be dealt with in order to guarantee a reliable and steady energy supply to the final user. Hydrogen can be the answer to these problems. This book presents the readers with the modeling, functioning and implementation of solar hydrogen energy systems, which efficiently combine different technologies to convert, store and use renewable energy. Sources like solar photovoltaic or wind, technologies like electrolysis, fuel cells, traditional and advanced hydrogen storage are discussed and evaluated together with system management and output performance. Examples are also given to show how these systems are ...

  11. Proceedings of the 14. world hydrogen energy conference 2002 : The hydrogen planet. CD-ROM ed.

    Energy Technology Data Exchange (ETDEWEB)

    Venter, R.D.; Bose, T.K. [Quebec Univ., Trois-Rivieres, PQ (Canada). Institut de recherche sur l' hydrogene; Veziroglu, N. [International Association for Hydrogen Energy, Coral Gables, FL (United States)] (eds.)

    2002-07-01

    Hydrogen has often been named as the ultimate fuel because it can be generated from a variety of renewable and non-renewable fuels and its direct conversion to electricity in fuel cells is efficient and results in no emissions other than water vapour. The opportunities and issues associated with the use of hydrogen as the energy carrier of the future were presented at this conference which addressed all aspects of hydrogen and fuel cell development including hydrogen production, storage, hydrogen-fuelled internal combustion engines, hydrogen infrastructure, economics, and the environment. Hydrogen is currently used as a chemical feedstock and a space fuel, but it is receiving considerable attention for bring renewable energy into the transportation and power generation sectors with little or no environmental impact at the point of end use. Canada leads the way in innovative ideas for a hydrogen infrastructure, one of the most challenging tasks for the transportation sector along with hydrogen storage. Major vehicle manufacturers have announced that they will have hydrogen-fueled cars and buses on the market beginning in 2003 and 2004. Solid oxide fuel cells will be used for generating electricity with efficiencies of 70 per cent, and proton exchange membrane (PEM) and other fuel cells are being tested for residential power supply with efficiencies of 85 per cent. The conference included an industrial exposition which demonstrated the latest developments in hydrogen and fuel cell research. More than 300 papers were presented at various oral and poster sessions, of which 172 papers have been indexed separately for inclusion in the database.

  12. Hydrogen and the materials of a sustainable energy future

    Energy Technology Data Exchange (ETDEWEB)

    Zalbowitz, M. [ed.

    1997-02-01

    The National Educator`s Workshop (NEW): Update 96 was held October 27--30, 1996, and was hosted by Los Alamos National Laboratory. This was the 11th annual conference aimed at improving the teaching of material science, engineering and technology by updating educators and providing laboratory experiments on emerging technology for teaching fundamental and newly evolving materials concepts. The Hydrogen Education Outreach Activity at Los Alamos National Laboratory organized a special conference theme: Hydrogen and the Materials of a Sustainable Energy Future. The hydrogen component of the NEW:Update 96 offered the opportunity for educators to have direct communication with scientists in laboratory settings, develop mentor relationship with laboratory staff, and bring leading edge materials/technologies into the classroom to upgrade educational curricula. Lack of public education and understanding about hydrogen is a major barrier for initial implementation of hydrogen energy technologies and is an important prerequisite for acceptance of hydrogen outside the scientific/technical research communities. The following materials contain the papers and view graphs from the conference presentations. In addition, supplemental reference articles are also included: a general overview of hydrogen and an article on handling hydrogen safely. A resource list containing a curriculum outline, bibliography, Internet resources, and a list of periodicals often publishing relevant research articles can be found in the last section.

  13. Hydrogen energy demonstration plant in Patagonia: Description and safety issues

    Energy Technology Data Exchange (ETDEWEB)

    Aprea, Jose Luis [CNEA (Argentine Atomic Energy Commission), AAH, IRAM, Comahue University, CC 805, 8300 Neuquen (Argentina)

    2009-05-15

    Hydrogen safety issues and especially hydrogen hazard's address are key points to remove any safety-related barrier in the implementation process of hydrogen energy systems. Demonstrative systems based on hydrogen technologies represent a clear contribution to the task of showing the feasibility of the new technologies and their beneficial capabilities among the public. In this paper, the safety features of the first hydrogen energy demonstrative plant conceived in Latin America are analyzed. The facilities, located in the village of Pico Truncado, Patagonia, Argentina, serve to gain day-to-day experience in the production, storage, distribution, conversion and use of hydrogen in several applications. The plant uses electrolysis to generate pure hydrogen from renewable primary sources, taking advantage of the installed wind power capacity that is continually growing in the region. The installations were designed to accomplish with two primary objectives: total safety assurance and minimization of human errors. Some details of the plant, including a general layout, are presented here, in addition with design criteria, hydrogen hazards, structural precautions, gas monitoring system, existing regulations and safety requirements. (author)

  14. Hydrogen Production Costs of Various Primary Energy Sources

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Jae Hyuk; Tak, Nam Il; Kim, Yong Hee; Park, Won Seok

    2005-11-15

    Many studies on the economical aspects of hydrogen energy technologies have been conducted with the increase of the technical and socioeconomic importance of the hydrogen energy. However, there is still no research which evaluates the economy of hydrogen production from the primary energy sources in consideration of Korean situations. In this study, the hydrogen production costs of major primary energy sources are compared in consideration of the Korean situations such as feedstock price, electricity rate, and load factor. The evaluation methodology is based on the report of the National Academy of Science (NAS) of U.S. The present study focuses on the possible future technology scenario defined by NAS. The scenario assumes technological improvement that may be achieved if present research and development (R and D) programs are successful. The production costs by the coal and natural gas are 1.1 $/kgH{sub 2} and 1.36 $/kgH{sub 2}, respectively. However, the fossil fuels are susceptible to the price variation depending on the oil and the raw material prices, and the hydrogen production cost also depends on the carbon tax. The economic competitiveness of the renewable energy sources such as the wind, solar, and biomass are relatively low when compared with that of the other energy sources. The estimated hydrogen production costs from the renewable energy sources range from 2.35 $/kgH{sub 2} to 6.03 $/kgH{sub 2}. On the other hand, the production cost by nuclear energy is lower than that of natural gas or coal when the prices of the oil and soft coal are above $50/barrel and 138 $/ton, respectively. Taking into consideration the recent rapid increase of the oil and soft coal prices and the limited fossil resource, the nuclear-hydrogen option appears to be the most economical way in the future.

  15. The energy efficiency of onboard hydrogen storage

    DEFF Research Database (Denmark)

    Jensen, Jens Oluf; Li, Qingfeng; Bjerrum, Niels

    2010-01-01

    Global warming resulting from the use of fossil fuels is threatening the environment and energy efficiency is one of the most important ways to reduce this threat. Industry, transport and buildings are all high energy-using sectors in the world and even in the most technologically optimistic...... perspectives energy use is projected to increase in the next 50 years. How and when energy is used determines society's ability to create long-term sustainable energy systems. This is why this book, focusing on energy efficiency in these sectors and from different perspectives, is sharp and also important...

  16. Bio-hydrogen Production Potential from Market Waste

    Directory of Open Access Journals (Sweden)

    Lanna Jaitalee

    2010-07-01

    Full Text Available This research studied bio-hydrogen production from vegetable waste from a fresh market in order to recover energy. A series of batch experiments were conducted to investigate the effects of initial volatile solids concentration on the bio-hydrogen production process. Lab bench scale anaerobic continuous stirred-tank reactors (CSTR were used to study the effect of substrate and sludge inoculation on hydrogen production. Three different concentrations of initial total volatile solids (TVS of organic waste were varied from 2%, 3% and 5% respectively. The pH was controlled at 5.5 for all batches in the experiment. The results showed that bio-hydrogen production depended on feed-substrate concentration. At initial TVS content of 3%, the highest hydrogen production was achieved at a level of 0.59 L-H2/L at pH 5.5. The maximum hydrogen yield was 15.3 ml H2/g TVS or 8.5 ml H2/g COD. The composition of H2 in the biogas ranged from 28.1-30.9% and no CH4 was detected in all batch tests.

  17. Renewable Hydrogen Potential from Biogas in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Saur, G.; Milbrandt, A.

    2014-07-01

    This analysis updates and expands upon previous biogas studies to include total potential and net availability of methane in raw biogas with respect to competing demands and includes a resource assessment of four sources of biogas: (1) wastewater treatment plants, including domestic and a new assessment of industrial sources; (2) landfills; (3) animal manure; and (4) a new assessment of industrial, institutional, and commercial sources. The results of the biogas resource assessment are used to estimate the potential production of renewable hydrogen from biogas as well as the fuel cell electric vehicles that the produced hydrogen might support.

  18. Analytic Methods for Benchmarking Hydrogen and Fuel Cell Technologies; NREL (National Renewable Energy Laboratory)

    Energy Technology Data Exchange (ETDEWEB)

    Melaina, Marc; Saur, Genevieve; Ramsden, Todd; Eichman, Joshua

    2015-05-28

    This presentation summarizes NREL's hydrogen and fuel cell analysis work in three areas: resource potential, greenhouse gas emissions and cost of delivered energy, and influence of auxiliary revenue streams. NREL's hydrogen and fuel cell analysis projects focus on low-­carbon and economic transportation and stationary fuel cell applications. Analysis tools developed by the lab provide insight into the degree to which bridging markets can strengthen the business case for fuel cell applications.

  19. Hydrogen-air energy storage gas-turbine system

    Science.gov (United States)

    Schastlivtsev, A. I.; Nazarova, O. V.

    2016-02-01

    A hydrogen-air energy storage gas-turbine unit is considered that can be used in both nuclear and centralized power industries. However, it is the most promising when used for power-generating plants based on renewable energy sources (RES). The basic feature of the energy storage system in question is combination of storing the energy in compressed air and hydrogen and oxygen produced by the water electrolysis. Such a process makes the energy storage more flexible, in particular, when applied to RES-based power-generating plants whose generation of power may considerably vary during the course of a day, and also reduces the specific cost of the system by decreasing the required volume of the reservoir. This will allow construction of such systems in any areas independent of the local topography in contrast to the compressed-air energy storage gas-turbine plants, which require large-sized underground reservoirs. It should be noted that, during the energy recovery, the air that arrives from the reservoir is heated by combustion of hydrogen in oxygen, which results in the gas-turbine exhaust gases practically free of substances hazardous to the health and the environment. The results of analysis of a hydrogen-air energy storage gas-turbine system are presented. Its layout and the principle of its operation are described and the basic parameters are computed. The units of the system are analyzed and their costs are assessed; the recovery factor is estimated at more than 60%. According to the obtained results, almost all main components of the hydrogen-air energy storage gas-turbine system are well known at present; therefore, no considerable R&D costs are required. A new component of the system is the H2-O2 combustion chamber; a difficulty in manufacturing it is the necessity of ensuring the combustion of hydrogen in oxygen as complete as possible and preventing formation of nitric oxides.

  20. Alternative energies for transportation at the end of the mineral-oil aera. Pt. 2. Hydrogen systems particularly versatile - hydrogen-gasoline mixed operation as a first step

    Energy Technology Data Exchange (ETDEWEB)

    Buchner, H.; Saeufferer, H. (Daimler-Benz A.G., Stuttgart (Germany, F.R.)); May, H. (Kaiserslautern Univ. (Germany, F.R.). Lehrstuhl fuer Kraft- und Arbeitsmaschinen)

    1977-09-01

    Within the frame of a three-part series, alternative fuels for vehicle engines are tested with reference to their possible application potential. This second part deals with hydrogen as a fuel for vehicles. It is shown that the progress in the storage of hydrogen by means of hydride stores will help to use hydrogen as driving power for vehicles. For the present the petrol will be mixed with hydrogen at 10%. This, as was seen in experiments, leads to an improved efficiency of the engines, at the same time reducing the waste gas emission. After some experiences with commercial operation, the preconditions for complete replacement of petrol by hydrogen could be created. Finally the effects of a hydrogen-hydride energy conception with its effects on the energy supply in industry and private households are discussed.

  1. Hydrogen Storage Experiments for an Undergraduate Laboratory Course--Clean Energy: Hydrogen/Fuel Cells

    Science.gov (United States)

    Bailey, Alla; Andrews, Lisa; Khot, Ameya; Rubin, Lea; Young, Jun; Allston, Thomas D.; Takacs, Gerald A.

    2015-01-01

    Global interest in both renewable energies and reduction in emission levels has placed increasing attention on hydrogen-based fuel cells that avoid harm to the environment by releasing only water as a byproduct. Therefore, there is a critical need for education and workforce development in clean energy technologies. A new undergraduate laboratory…

  2. Hydrogen Storage Experiments for an Undergraduate Laboratory Course--Clean Energy: Hydrogen/Fuel Cells

    Science.gov (United States)

    Bailey, Alla; Andrews, Lisa; Khot, Ameya; Rubin, Lea; Young, Jun; Allston, Thomas D.; Takacs, Gerald A.

    2015-01-01

    Global interest in both renewable energies and reduction in emission levels has placed increasing attention on hydrogen-based fuel cells that avoid harm to the environment by releasing only water as a byproduct. Therefore, there is a critical need for education and workforce development in clean energy technologies. A new undergraduate laboratory…

  3. Hydrogen energy and fuel cells. A vision of our future

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    This document presents the possibilities of energy systems based on the hydrogen, in the world and more specially in Europe in the context of an environmental and energy strategy. It proposes then the necessary structures and actions to implement at a commercial feasibility. (A.L.B.)

  4. Positron impact ionization of atomic hydrogen at low energies

    Indian Academy of Sciences (India)

    K Chakrabarti

    2001-04-01

    Low energy positron impact ionization of atomic hydrogen is studies theoretically using the hyperspherical partial wave method of Das [1] in constant 12, equal energy sharing geometry. The TDCS reveal considerable differences in physics compared to electron impact ionization under the same geometry.

  5. Case Studies of integrated hydrogen systems. International Energy Agency Hydrogen Implementing Agreement, Final report for Subtask A of task 11 - Integrated Systems

    Energy Technology Data Exchange (ETDEWEB)

    Schucan, T. [Paul Scherrer Inst., Villigen PSI (Switzerland)

    1999-12-31

    Within the framework of the International Energy Agency Hydrogen Implementing Agreement, Task 11 was undertaken to develop tools to assist in the design and evaluation of existing and potential hydrogen demonstration projects. Emphasis was placed on integrated systems, from input energy to hydrogen end use. Included in the PDF document are the Executive Summary of the final report and the various case studies. The activities of task 11 were focused on near- and mid-term applications, with consideration for the transition from fossil-based systems to sustainable hydrogen energy systems. The participating countries were Canada, Italy, Japan, the Netherlands, Spain, Switzerland and the United States. In order for hydrogen to become a competitive energy carrier, experience and operating data need to be generated and collected through demonstration projects. A framework of scientific principles, technical expertise, and analytical evaluation and assessment needed to be developed to aid in the design and optimization of hydrogen demonstration projects to promote implementation. The task participants undertook research within the framework of three highly coordinated subtasks that focused on the collection and critical evaluation of data from existing demonstration projects around the world, the development and testing of computer models of hydrogen components and integrated systems, and the evaluation and comparison of hydrogen systems. While the Executive Summary reflects work on all three subtasks, this collection of chapters refers only to the work performed under Subtask A. Ten projects were analyzed and evaluated in detail as part of Subtask A, Case Studies. The projects and the project partners were: Solar Hydrogen Demonstration Project, Solar-Wasserstoff-Bayern, Bayernwerk, BMW, Linde, Siemens (Germany); Solar Hydrogen Plant on Residential House, M. Friedli (Switzerland); A.T. Stuart Renewable Energy Test Site; Stuart Energy Systems (Canada); PHOEBUS Juelich

  6. Engineering analysis of potential photosynthetic bacterial hydrogen-production systems

    Science.gov (United States)

    Herlevich, A.; Karpuk, M. E.

    1982-06-01

    Photosynthetic bacteria (PSB) are capable of generating hydrogen from organics in effluents from food processing, pulp and paper, and chemical and pharmaceutical industries. Hydrogen evolution takes place under light in the absence of air. The rate of hydrogen production is expected to range between 300 to 600 scf of hydrogen per 1000 galloons of waste stream treated per hour. This hydrogen production system has been demonstrated at a bench-scale level and is ready for engineering development. A conceptual design for a PSB hydrogen production system is described. The system is expected to be sited adjacent to a waste stream source which will be pretreated by fermentation and pH adjustment, innoculated with bacteria, and then passed into the reactor. The reactor effluent can either be discharged into a rapid infiltration system, an irrigation ditch, and/or recycled back into the reactor. Several potential reactor designs have been developed, analyzed, and costed. A large covered pond appears to be the most economical design approach.

  7. Hydrogen Energy Coordinating Committee annual report: Summary of DOE hydrogen programs for FY 1991--1992

    Energy Technology Data Exchange (ETDEWEB)

    1993-05-01

    The Hydrogen Energy Coordinating Committee (HECC) was established over 14 years ago to ensure that the many varied aspects of hydrogen technology research and development within the Department are coordinated. Each year the committee brings together technical representatives within the Department to coordinate activities, share research results and discuss future priorities and directions. An annual report is published summarizing the work in progress. This summary is the fourteenth consecutive report. It provides an overview of the hydrogen-related programs of the DOE offices represented in the HECC.

  8. Salinity-gradient energy driven microbial electrosynthesis of hydrogen peroxide

    Science.gov (United States)

    Li, Xiaohu; Angelidaki, Irini; Zhang, Yifeng

    2017-02-01

    Hydrogen peroxide (H2O2) as a strong oxidant, is widely used in various chemical industries and environmental remediation processes. In this study, we developed an innovative method for cost-effective production of H2O2 by using a microbial reverse-electrodialysis electrolysis cell (MREC). In the MREC, electrical potential generated by the exoelectrogens and the salinity-gradient between salt and fresh water were utilized to drive the high-rate H2O2 production. Operational parameters such as air flow rate, pH, cathodic potential, flow rate of salt and fresh water were investigated. The optimal H2O2 production was observed at salt and fresh water flow rate of 0.5 mL min-1, air flow rate of 12-20 mL min-1, cathode potential of -0.485 ± 0.025 V (vs Ag/AgCl). The maximum H2O2 accumulated concentration of 778 ± 11 mg L-1 was obtained at corresponding production rate of 11.5 ± 0.5 mg L-1 h-1. The overall energy input for the synthesis process was 0.45 ± 0.03 kWh kg-1 H2O2. Cathode potential was the key factor for H2O2 production, which was mainly affected by the air flow rate. This work for the first time proved the potential of MREC as an efficient platform technology for simultaneous electrosynthesis of valuable chemicals and utilization of salinity-gradient energy.

  9. Hydrogen tube vehicle for supersonic transport: 2. Speed and energy

    Energy Technology Data Exchange (ETDEWEB)

    Miller, Arnold R. [Vehicle Projects Inc and Supersonic Tubevehicle LLC, 200 Violet St, Suite 100, Golden, CO 80401 (United States)

    2010-06-15

    The central concept of a new idea in high-speed transport is that operation of a vehicle in a hydrogen atmosphere, because of the low density of hydrogen, would increase sonic speed by a factor of 3.8 and decrease drag by 15 relative to air. A hydrogen atmosphere requires that the vehicle operate within a hydrogen-filled tube or pipeline, which serves as a phase separator. The supersonic tube vehicle (STV) can be supersonic with respect to air outside the tube while remaining subsonic inside. It breathes hydrogen fuel for its propulsion fuel cells from the tube itself. This paper, second in a series on the scientific foundations of the supersonic tube vehicle, tests the hypothesis that the STV will be simultaneously fast and energy efficient by comparing its predicted speed and energy consumption with that of four long-haul passenger transport modes: road, rail, maglev, and air. The study establishes the speed ranking STV >> airplane > maglev > train > coach (intercity bus) and the normalized energy consumption ranking Airplane >> coach > maglev > train > STV. Consistent with the hypothesis, the concept vehicle is both the fastest and lowest energy consuming mode. In theory, the vehicle can cruise at Mach 2.8 while consuming less than half the energy per passenger of a Boeing 747 at a cruise speed of Mach 0.81. (author)

  10. Comparative study of hydrogen and methanol as energy carriers

    Energy Technology Data Exchange (ETDEWEB)

    Johansson, Anna

    1998-06-01

    This report has been written with the purpose to compare hydrogen and methanol, with gasoline, as energy carriers for new energy systems in the future. This energy system must satisfy the demands for sustainable development. The report focuses on motor vehicle applications. A few different criteria has been developed to help form the characterisation method. The criteria proposed in this thesis are developed for an environmental comparison mainly based on emissions from combustion. The criteria concerns the following areas: Renewable resources, The ozone layer, The greenhouse effect, The acidification, and Toxic substances. In many ways, hydrogen may seem as a very good alternative compared with gasoline and diesel oil. Combustion of hydrogen in air results in water and small amounts of oxides of nitrogen. In this report, hydrogen produced from renewable resources is investigated. This is necessary to fulfill the demands for sustainable development. Today, however, steam reforming of fossil fuels represent 99% of the hydrogen production market. Problem areas connected with hydrogen use are for instance storage and distribution. Methanol has many advantages, while comparing methanol and gasoline, like lower emissions of nitrogen oxides and hydrocarbons, limited emissions of carbon dioxide and no sulphur content. Methanol can be produced from many different resources, for example natural gas, naphtha, oil, coal or peat, and biomass. To meet demands for sustainable production, methanol has to be produced from biomass Examination paper. 32 refs, 20 figs, 13 tabs

  11. Applied hydrogen storage research and development: A perspective from the U.S. Department of Energy

    Energy Technology Data Exchange (ETDEWEB)

    O’Malley, Kathleen [SRA International, Inc., Fairfax, VA 22033 (United States); Ordaz, Grace; Adams, Jesse; Randolph, Katie [U.S. Department of Energy, 1000 Independence Ave., SW, EE-3F, Washington, DC 20585 (United States); Ahn, Channing C. [U.S. Department of Energy, 1000 Independence Ave., SW, EE-3F, Washington, DC 20585 (United States); California Institute of Technology, Pasadena, CA 91125 (United States); Stetson, Ned T., E-mail: Ned.Stetson@ee.doe.gov [U.S. Department of Energy, 1000 Independence Ave., SW, EE-3F, Washington, DC 20585 (United States)

    2015-10-05

    Highlights: • Overview of U.S. DOE-supported hydrogen storage technology development efforts. • Physical and materials-based strategy for developing hydrogen storage systems. • Materials requirements for automotive storage systems. • Key R&D developments. - Abstract: To enable the wide-spread commercialization of hydrogen fuel cell technologies, the U.S. Department of Energy, through the Office of Energy Efficiency and Renewable Energy’s Fuel Cell Technology Office, maintains a comprehensive portfolio of R&D activities to develop advanced hydrogen storage technologies. The primary focus of the Hydrogen Storage Program is development of technologies to meet the challenging onboard storage requirements for hydrogen fuel cell electric vehicles (FCEVs) to meet vehicle performance that consumers have come to expect. Performance targets have also been established for materials handling equipment (e.g., forklifts) and low-power, portable fuel cell applications. With the imminent release of commercial FCEVs by automobile manufacturers in regional markets, a dual strategy is being pursued to (a) lower the cost and improve performance of high-pressure compressed hydrogen storage systems while (b) continuing efforts on advanced storage technologies that have potential to surpass the performance of ambient compressed hydrogen storage.

  12. Study of potential leakage on several stressed fittings for hydrogen pressures up to 700 bar

    OpenAIRE

    Houssin-Agbomson, Deborah; Jamois, Didier; Proust, Christophe; Daubech, Jérôme; Ruban, Sidonie; Jallais, Simon

    2012-01-01

    International audience; In order to improve risk analyses and influence the design of the future H2 systems, an experimental study on 'real' leaks qualification and quantification was performed. In H2 energy applications, fittings appeared as a significant leakage potential and subsequently explosion and flame hazards. Thus, as a part of the 'Horizon Hydrogene Energie' French program, four kinds of commercial fittings usually employed on H2 systems were tested thanks to a new high pressure te...

  13. Computation of energy states of hydrogenic quantum dot with two-electrons

    Science.gov (United States)

    Yakar, Y.; Özmen, A.; ćakır, B.

    2016-03-01

    In this study we have investigated the electronic structure of the hydrogenic quantum dot with two electrons inside an impenetrable potential surface. The energy eigenvalues and wavefunctions of the ground and excited states of spherical quantum dot have been calculated by using the Quantum Genetic Algorithm (QGA) and Hartree-Fock Roothaan (HFR) method, and the energies are investigated as a function of dot radius. The results show that as dot radius increases, the energy of quantum dot decreases.

  14. Geometric effects on energy states of a hydrogenic impurity in multilayered spherical quantum dot

    Energy Technology Data Exchange (ETDEWEB)

    Boz, Figen Karaca, E-mail: figenkaraca@mynet.com [Department of Physics, Trakya University, Edirne 22030 (Turkey); Aktas, Saban [Department of Physics, Trakya University, Edirne 22030 (Turkey); Bilekkaya, Abdullah [Department of Electronics, Trakya University Edirne Vocational College of Technical Sciences, Edirne 22100 (Turkey); Okan, Sevket Erol [Department of Physics, Trakya University, Edirne 22030 (Turkey)

    2009-04-15

    The energy states of a hydrogenic impurity, located at the center of a multilayered spherical quantum dot, are calculated as functions of the barrier thickness and the inner dot thickness by using a fourth-order Runge-Kutta method. It is shown that the method is able to calculate all the energy states for any potential profile in the dot. Also, the binding energies show dramatic changes in comparison with those of single spherical quantum dots.

  15. Hydrogen energy in changing environmental scenario: Indian context

    Energy Technology Data Exchange (ETDEWEB)

    Leo Hudson, M. Sterlin; Dubey, P.K.; Pukazhselvan, D.; Pandey, Sunil Kumar; Singh, Rajesh Kumar; Raghubanshi, Himanshu; Shahi, Rohit. R.; Srivastava, O.N. [Hydrogen Energy Center, Department of Physics, Banaras Hindu University, Varanasi 221005, Uttar Pradesh (India)

    2009-09-15

    This paper deals with how the Hydrogen Energy may play a crucial role in taking care of the environmental scenario/climate change. The R and D efforts, at the Hydrogen Energy Center, Banaras Hindu University have been described and discussed to elucidate that hydrogen is the best option for taking care of the environmental/climate changes. All three important ingredients for hydrogen economy, i.e., production, storage and application of hydrogen have been dealt with. As regards hydrogen production, solar routes consisting of photoelectrochemical electrolysis of water have been described and discussed. Nanostructured TiO{sub 2} films used as photoanodes have been synthesized through hydrolysis of Ti[OCH(CH{sub 3}){sub 2}]{sub 4}. Modular designs of TiO{sub 2} photoelectrode-based PEC cells have been fabricated to get high hydrogen production rate ({proportional_to}10.35 lh{sup -1} m{sup -2}). However, hydrogen storage is a key issue in the success and realization of hydrogen technology and economy. Metal hydrides are the promising candidates due to their safety advantage with high volume efficient storage capacity for on-board applications. As regards storage, we have discussed the storage of hydrogen in intermetallics as well as lightweight complex hydride systems. For intermetallic systems, we have dealt with material tailoring of LaNi{sub 5} through Fe substitution. The La(Ni{sub l-x}Fe{sub x}){sub 5} (x = 0.16) has been found to yield a high storage capacity of {proportional_to}2.40 wt%. We have also discussed how CNT admixing helps to improve the hydrogen desorption rate of NaAlH{sub 4}. CNT (8 mol%) admixed NaAlH{sub 4} is found to be optimum for faster desorption ({proportional_to}3.3 wt% H{sub 2} within 2 h). From an applications point of view, we have focused on the use of hydrogen (stored in intermetallic La-Ni-Fe system) as fuel for Internal Combustion (IC) engine-based vehicular transport, particularly two and three-wheelers. It is shown that hydrogen

  16. Hydrogen energy and fuel cells. A vision of our future

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    Hydrogen and fuel cells are seen by many as key solutions for the 21 century, enabling clean efficient production of power and heat from a range of primary energy sources. The High Level Group for Hydrogen and Fuel Cells Technologies was initiated in October 2002 by the Vice President of the European Commission, Loyola de Palacio, Commissioner for Energy and Transport, and Mr Philippe Busquin, Commissioner for Research. The group was invited to formulate a collective vision on the contribution that hydrogen and fuel cells could make to the realisation of sustainable energy systems in future. The report highlights the need for strategic planning and increased effort on research, development and deployment of hydrogen and fuel cell technologies. It also makes wide-ranging recommendations for a more structured approach to European Energy policy and research, for education and training, and for developing political and public awareness. Foremost amongst its recommendations is the establishment of a European Hydrogen and Fuel Cell Technology Partnership and Advisory Council to guide the process. (author)

  17. Community Energy: Analysis of Hydrogen Distributed Energy Systems with Photovoltaics for Load Leveling and Vehicle Refueling

    Energy Technology Data Exchange (ETDEWEB)

    Steward, D.; Zuboy, J.

    2014-10-01

    Energy storage could complement PV electricity generation at the community level. Because PV generation is intermittent, strategies must be implemented to integrate it into the electricity system. Hydrogen and fuel cell technologies offer possible PV integration strategies, including the community-level approaches analyzed in this report: (1) using hydrogen production, storage, and reconversion to electricity to level PV generation and grid loads (reconversion scenario); (2) using hydrogen production and storage to capture peak PV generation and refuel hydrogen fuel cell electric vehicles (FCEVs) (hydrogen fueling scenario); and (3) a comparison scenario using a battery system to store electricity for EV nighttime charging (electric charging scenario).

  18. Preface: photosynthesis and hydrogen energy research for sustainability.

    Science.gov (United States)

    Tomo, Tatsuya; Allakhverdiev, Suleyman I

    2017-09-01

    Energy supply, climate change, and global food security are among the main chalenges facing humanity in the twenty-first century. Despite global energy demand is continuing to increase, the availability of low cost energy is decreasing. Together with the urgent problem of climate change due to CO2 release from the combustion of fossil fuels, there is a strong requirement of developing the clean and renewable energy system for the hydrogen production. Solar fuel, biofuel, and hydrogen energy production gained unlimited possibility and feasibility due to understanding of the detailed photosynthetic system structures. This special issue contains selected papers on photosynthetic and biomimetic hydrogen production presented at the International Conference "Photosynthesis Research for Sustainability-2016", that was held in Pushchino (Russia), during June 19-25, 2016, with the sponsorship of the International Society of Photosynthesis Research (ISPR) and of the International Association for Hydrogen Energy (IAHE). This issue is intended to provide recent information on the photosynthetic and biohydrogen production to our readers.

  19. Demonstration projects of hydrogen mobility. The clean energy partnership (CEP)

    Energy Technology Data Exchange (ETDEWEB)

    Kirchner, Rene [TOTAL Deutschland GmbH / Clean Energy Partnership, Berlin (Germany)

    2013-06-01

    The Clean Energy Partnership (CEP)- an alliance of currently sixteen leading companies in Germany- shows that it may be doable to establish hydrogen as 'fuel of the future'. With Air Liquide, Berliner Verkehrsbetriebe (BVG), BMW, Daimler, EnBW, Ford, GM/Opel, Hamburger Hochbahn, Honda, Linde, Shell, Siemens, Total, Toyota, Vattenfall Europe and Volkswagen, the project partners include technology, oil and utility companies as well as major car manufacturers and two leading public transport companies of the two biggest German cities. The goal of CEP is to test using hydrogen- and fuel-cell technology on an everyday basis in the mobility sector with regard to individual traffic and public transport. Challenges are the use and supply of ''green'' hydrogen as well the serial production of hydrogen vehicles as well as the extension of the hydrogen filling station network. Nevertheless, Germany is a frontrunner when it comes to hydrogen mobility with currently 15 stations and 50% green hydrogen offered already today. (orig.)

  20. Hydrogen Energy Storage and Power-to-Gas: Establishing Criteria for Successful Business Cases

    Energy Technology Data Exchange (ETDEWEB)

    Eichman, Joshua; Melaina, Marc

    2015-10-27

    As the electric sector evolves and increasing amounts of variable generation are installed on the system, there are greater needs for system flexibility, sufficient capacity and greater concern for overgeneration. As a result there is growing interest in exploring the role of energy storage and demand response technologies to support grid needs. Hydrogen is a versatile feedstock that can be used in a variety of applications including chemical and industrial processes, as well as a transportation fuel and heating fuel. Traditionally, hydrogen technologies focus on providing services to a single sector; however, participating in multiple sectors has the potential to provide benefits to each sector and increase the revenue for hydrogen technologies. The goal of this work is to explore promising system configurations for hydrogen systems and the conditions that will make for successful business cases in a renewable, low-carbon future. Current electricity market data, electric and gas infrastructure data and credit and incentive information are used to perform a techno-economic analysis to identify promising criteria and locations for successful hydrogen energy storage and power-to-gas projects. Infrastructure data will be assessed using geographic information system applications. An operation optimization model is used to co-optimizes participation in energy and ancillary service markets as well as the sale of hydrogen. From previous work we recognize the great opportunity that energy storage and power-to-gas but there is a lack of information about the economic favorability of such systems. This work explores criteria for selecting locations and compares the system cost and potential revenue to establish competitiveness for a variety of equipment configurations. Hydrogen technologies offer unique system flexibility that can enable interactions between multiple energy sectors including electric, transport, heating fuel and industrial. Previous research established that

  1. Hydrogen scenarios using fossil, nuclear or renewable energy

    Energy Technology Data Exchange (ETDEWEB)

    Sorensen, B. [Roskilde Univ., Danish Hydrogen Committee, Project leader fm. Danish Hydrogen, Implementation Project, advisor to Danish-Italian PEM fuel cell small car project., Roskilde (Denmark)

    2003-09-01

    Over the last decade, the Roskilde University Energy and Environment Group has worked on scenarios for a transition to a hydrogen society (Sorensen, 1996; Sorensen, Kuemmel and Meibom, 1999; Sorensen, 2000; Sorensen and Meibom, 2000; Sorensen et al., 2001; Sorensen, 2004). Hydrogen is proposed as a convenient energy carrier due to its versatility in use, transmission and as an energy storage medium. The primary energy input can be of three types: 1) fossil energy (natural gas reformation, goal gasification), ideally involving CO{sub 2} removal; 2) nuclear energy (medium temperature catalytic conversion or via electricity production and electrolysis), ideally involving safe nuclear reactors; 3) renewable energy such as wind, bio and solar (using electricity and electrolysis, or reverse fuel cell), with management of intermittence. The storage and distribution issues are studied by use of simulation models. Particularly for hydrogen based upon renewable energy inputs, there are basic system design issues of storage and allocation of surpluses and deficits on a short time scale. These are investigated using spatial GIS (geographical information system) techniques and hourly time series for simulation. For the fuel-based input scenarios, global models showing country balances of supply and demand are constructed. (O.M.)

  2. Predicted energy densitites for nickel-hydrogen and silver-hydrogen cells embodying metallic hydrides for hydrogen storage

    Science.gov (United States)

    Easter, R. W.

    1974-01-01

    Simplified design concepts were used to estimate gravimetric and volumetric energy densities for metal hydrogen battery cells for assessing the characteristics of cells containing metal hydrides as compared to gaseous storage cells, and for comparing nickel cathode and silver cathode systems. The silver cathode was found to yield superior energy densities in all cases considered. The inclusion of hydride forming materials yields cells with very high volumetric energy densities that also retain gravimetric energy densities nearly as high as those of gaseous storage cells.

  3. Hydrolysis of ammonia borane as a hydrogen source: fundamental issues and potential solutions towards implementation.

    Science.gov (United States)

    Sanyal, Udishnu; Demirci, Umit B; Jagirdar, Balaji R; Miele, Philippe

    2011-12-16

    In today's era of energy crisis and global warming, hydrogen has been projected as a sustainable alternative to depleting CO(2)-emitting fossil fuels. However, its deployment as an energy source is impeded by many issues, one of the most important being storage. Chemical hydrogen storage materials, in particular B-N compounds such as ammonia borane, with a potential storage capacity of 19.6 wt % H(2) and 0.145 kg(H2)L(-1), have been intensively studied from the standpoint of addressing the storage issues. Ammonia borane undergoes dehydrogenation through hydrolysis at room temperature in the presence of a catalyst, but its practical implementation is hindered by several problems affecting all of the chemical compounds in the reaction scheme, including ammonia borane, water, borate byproducts, and hydrogen. In this Minireview, we exhaustively survey the state of the art, discuss the fundamental problems, and, where applicable, propose solutions with the prospect of technological applications.

  4. Calculation of Internal Energy and Pressure of Dense hydrogen Plasma by Direct Path Integral Monte Carlo Approach

    Institute of Scientific and Technical Information of China (English)

    刘松芬; 胡北来

    2003-01-01

    The internal energy and pressure of dense hydrogen plasma are calculated by the direct path integral Monte Carlo approach. The Kelbg potential is used as interaction potentials both between electrons and between protons and electrons in the calculation. The complete formulae for internal energy and pressure in dense hydrogen plasma derived for the simulation are presented. The correctness of the derived formulae are validated by the obtained simulation results. The numerical results are discussed in details.

  5. 78 FR 54640 - Extension of Public Comment Period Hydrogen Energy California's Integrated Gasification Combined...

    Science.gov (United States)

    2013-09-05

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Extension of Public Comment Period Hydrogen Energy California's Integrated Gasification Combined Cycle... Public Comment Period and Public Hearing for the Hydrogen Energy California's Integrated...

  6. Transportable Hydrogen Research Plant Based on Renewable Energy

    Energy Technology Data Exchange (ETDEWEB)

    Mikel Fernandez; Carlos Madina; Asier Gil de Muro [LABEIN, Parque Tecnologico, edificio 700, 48160 Derio, Bizkaia (Spain); Jose Angel Alzolab; Iker Marino; Javier Garcia-Tejedor [ROBOTIKER, Parque Tecnologico, edificio 202, 48170 Zamudio, Bizkaia, (Spain); Juan Carlos Mugica; Inaki Azkkrate; Jose Angel Alzola [INASMET, Mikeletegi Pasalekua, Parque Tecnologico, E-20009 San Sebastian, Guipuzcoa (Spain)

    2006-07-01

    Efficiency and cost are nowadays the most important barriers for the penetration of systems based on hydrogen and renewable energies. According to this background, TECNALIA Corporation has started in 2004 the HIDROTEC project: 'Hydrogen Technologies for Renewable Energy Applications'. The ultimate aim of this project is the implementation of a multipurpose demonstration and research plant in order to explore diverse options for sustainable energetic solutions based on hydrogen. The plant is conceived as an independent system that can be easily transported and assembled. Research and demonstration activities can thus be carried out at very different locations, including commercial renewable facilities. Modularity and scalability have also been taken into account for an optimised exploitation. (authors)

  7. EMR modelling of a hydrogen-based electrical energy storage

    Science.gov (United States)

    Agbli, K. S.; Hissel, D.; Péra, M.-C.; Doumbia, I.

    2011-05-01

    This paper deals with multi-physics modelling of the stationary system. This modelling is the first step to reach the fuel cell system dimensioning aim pursued. Besides this modelling approach based on the stationary energetic system, the novelty in this paper is both the new approach of the photovoltaic EMR modelling and the EMR of the hydrogen storage process. The granular modelling approach is used to model each component of the system. Considering a stand alone PEM fuel cell system, hydrogen is expected to be produced and stored on the spot from renewable energy (photovoltaic) in order to satisfy the fuel availability. In fact, to develop a generic and modular model, energetic macroscopic representation (EMR) is used as graphical modelling tool. Allowing to be easily grasped by the experts even not necessarily gotten used to the modelling formalism, EMR is helpful to model the multi-domains energetic chain. The solar energy through solar module is converted in electrical energy; part of this energy is transformed in chemical energy (hydrogen) thanks to an electrolyser. Then the hydrogen is compressed into a tank across a storage system. The latter part of the solar module energy is stored as electrical energy within supercapacitor or lead-acid battery. Using the modularity feature of the EMR, the whole system is modelled entity by entity; afterwards by putting them together the overall system has been reconstructed. According to the scale effect of the system entities, some simulation and/or experimental results are given. Given to the different aims which are pursued in the sustainable energy framework like prediction, control and optimisation, EMR modelling approach is a reliable option for the energy management in real time of energetic system in macroscopic point of view.

  8. Electric utility applications of hydrogen energy storage systems

    Energy Technology Data Exchange (ETDEWEB)

    Swaminathan, S.; Sen, R.K.

    1997-10-15

    This report examines the capital cost associated with various energy storage systems that have been installed for electric utility application. The storage systems considered in this study are Battery Energy Storage (BES), Superconducting Magnetic Energy Storage (SMES) and Flywheel Energy Storage (FES). The report also projects the cost reductions that may be anticipated as these technologies come down the learning curve. This data will serve as a base-line for comparing the cost-effectiveness of hydrogen energy storage (HES) systems in the electric utility sector. Since pumped hydro or compressed air energy storage (CAES) is not particularly suitable for distributed storage, they are not considered in this report. There are no comparable HES systems in existence in the electric utility sector. However, there are numerous studies that have assessed the current and projected cost of hydrogen energy storage system. This report uses such data to compare the cost of HES systems with that of other storage systems in order to draw some conclusions as to the applications and the cost-effectiveness of hydrogen as a electricity storage alternative.

  9. FEASIBILITY OF HYDROGEN PRODUCTION USING LASER INERTIAL FUSION AS THE PRIMARY ENERGY SOURCE

    Energy Technology Data Exchange (ETDEWEB)

    Gorensek, M

    2006-11-03

    The High Average Power Laser (HAPL) program is developing technology for Laser IFE with the goal of producing electricity from the heat generated by the implosion of deuterium-tritium (DT) targets. Alternatively, the Laser IFE device could be coupled to a hydrogen generation system where the heat would be used as input to a water-splitting process to produce hydrogen and oxygen. The production of hydrogen in addition to electricity would allow fusion energy plants to address a much wider segment of energy needs, including transportation. Water-splitting processes involving direct and hybrid thermochemical cycles and high temperature electrolysis are currently being developed as means to produce hydrogen from high temperature nuclear fission reactors and solar central receivers. This paper explores the feasibility of this concept for integration with a Laser IFE plant, and it looks at potential modifications to make this approach more attractive. Of particular interest are: (1) the determination of the advantages of Laser IFE hydrogen production compared to other hydrogen production concepts, and (2) whether a facility of the size of FTF would be suitable for hydrogen production.

  10. Space Charge Compensation in the Linac4 Low Energy Beam Transport Line with Negative Hydrogen Ions

    CERN Document Server

    Valerio-Lizarraga, C; Leon-Monzon, I; Lettry, J; Midttun, O; Scrivens, R

    2014-01-01

    The space charge effect of low energy, unbunched ion beams can be compensated by the trapping of ions or electrons into the beam potential. This has been studied for the 45 keV negative hydrogen ion beam in the CERN Linac4 Low Energy Beam Tranport (LEBT) using the package IBSimu1, which allows the space charge calculation of the particle trajectories. The results of the beam simulations will be compared to emittance measurements of an H- beam at the CERN Linac4 3 MeV test stand, where the injection of hydrogen gas directly into the beam transport region has been used to modify the space charge compensation degree.

  11. Expert Opinion Analysis on Renewable Hydrogen Storage Systems Potential in Europe

    Directory of Open Access Journals (Sweden)

    Davide Astiaso Garcia

    2016-11-01

    Full Text Available Among the several typologies of storage technologies, mainly on different physical principles (mechanical, electrical and chemical, hydrogen produced by power to gas (P2G from renewable energy sources complies with chemical storage principle and is based on the conversion of electrical energy into chemical energy by means of the electrolysis of water which does not produce any toxic or climate-relevant emission. This paper aims to pinpoint the potential uses of renewable hydrogen storage systems in Europe, analysing current and potential locations, regulatory framework, governments’ outlooks, economic issues, and available renewable energy amounts. The expert opinion survey, already used in many research articles on different topics including energy, has been selected as an effective method to produce realistic results. The obtained results highlight strategies and actions to optimize the storage of hydrogen produced by renewables to face varying electricity demand and generation-driven fluctuations reducing the negative effects of the increasing share of renewables in the energy mix of European Countries.

  12. Hydrogen atom in space with a compactified extra dimension and potential defined by Gauss' law

    CERN Document Server

    Bureš, Martin

    2014-01-01

    We investigate the consequences of one extra spatial dimension for the stability and energy spectrum of the non-relativistic hydrogen atom with a potential defined by Gauss' law, i.e. proportional to $1/|x|^2$. The additional spatial dimension is considered to be either infinite or curled-up in a circle of radius $R$. In both cases, the energy spectrum is bounded from below for charges smaller than the same critical value and unbounded from below otherwise. As a consequence of compactification, negative energy eigenstates appear: if $R$ is smaller than a quarter of the Bohr radius, the corresponding Hamiltonian possesses an infinite number of bound states with minimal energy extending at least to the ground state of the hydrogen atom.

  13. Hydrogen atom in space with a compactified extra dimension and potential defined by Gauss' law

    Science.gov (United States)

    Bureš, Martin; Siegl, Petr

    2015-03-01

    We investigate the consequences of one extra spatial dimension for the stability and energy spectrum of the non-relativistic hydrogen atom with a potential defined by Gauss' law, i.e. proportional to 1 /| x | 2. The additional spatial dimension is considered to be either infinite or curled-up in a circle of radius R. In both cases, the energy spectrum is bounded from below for charges smaller than the same critical value and unbounded from below otherwise. As a consequence of compactification, negative energy eigenstates appear: if R is smaller than a quarter of the Bohr radius, the corresponding Hamiltonian possesses an infinite number of bound states with minimal energy extending at least to the ground state of the hydrogen atom.

  14. Stategy for Locating Potential Sites for Hydrogen in Minerals

    Science.gov (United States)

    Ross, N. L.; Gibbs, G. V.; Rosso, K. M.

    2002-12-01

    Neutron diffraction is ideally suited for determining structural positions of hydrogen in minerals and usually the sample is deuterated in order to reduce the incoherent scattering from the hydrogen. In many cases, however, difficulties in location of hydrogen in minerals by neutron diffraction may arise because the there may be too little hydrogen in the sample to detect, the sample cannot be deuterated, there may be deterioration in the quality of diffraction data collected in pressure cells, etc. We propose a strategy that will aid in both the determination of potential docking sites of hydrogen and in the determination of the crystallographic orientation of O-H bonds. The strategy is based on determining the Laplacian of the electron density, -∇ 2ρ (r), of the mineral. As demonstrated by Bader et al. (1984), a mapping of the Laplacian of the electron density distribution yields a series of concentric shells centered at the nucleus of each atom defining where the electron density distribution, ρ, is alternately locally concentrated and locally depleted, a distribution that reflects the shell structure of the atom. The region where the distribution is positive is called the valence-shell charge concentration (VSCC) of the atom (Bader, 1990). When two atoms combine and a bond is formed, the VSCC of each atom is distorted to one degree or another with the concomitant formation of maxima and minima in the VSCC of each atom. The maxima define domains where Ÿƒ is locally concentrated and the minima define domains where ρ is locally depleted. It has been found that the number, the location and the relative sizes of the maxima provide a faithful representation of the bonded and non-bonded electron pairs of the Lewis model. The non-bonded electron pairs correspond with sites of potential electrophilic attack. Gibbs et al. (2002) has extended this approach to minerals and predicted potential sites for hydrogen in coesite. The theoretical results agree very well

  15. High-energy Physics with Hydrogen Bubble Chambers

    Science.gov (United States)

    Alvarez, L. W.

    1958-03-07

    Recent experience with liquid hydrogen bubble chambers of 25 and 40 cm dia. in high-energy physics experiments is discussed. Experiments described are: interactions of K{sup -} mesons with protons, interactions of antiprotons with protons, catalysis of nuclear fusion reactions by muons, and production and decay of hyperons from negative pions. (W.D.M.)

  16. First-principles predictions of potential hydrogen storage materials: Nanosized Ti(core)/Mg(shell) hydrides

    Science.gov (United States)

    Tao, S. X.; Notten, P. H. L.; van Santen, R. A.; Jansen, A. P. J.

    2011-05-01

    MgH2 is one of the most promising hydrogen storage materials. However MgH2 is thermodynamicly too stable, leading to a too high desorption temperature of 300°C at atmospheric pressure, which is a major impediment for practical applications. In this study, aiming to tune the thermodynamic stability of the MgH2, nanosized two-dimensional Mg/Ti/Mg sandwich and three-dimensional Ti(core)/Mg(shell) hydrides have been investigated by using density functional theory calculations. For both structures, four types of hydrogen atoms can be distinguished: on the surface of the Mg (Hsurf), within the Mg (HMg), at the Mg/Ti interface (HMgTi), and within the Ti (HTi). For the dehydrogenation reaction, the hydrogen desorption from the hydride is in the order Hsurf, HMg, HMgTi, HTi. The desorption energy of Hsurf is unexpectedly high. As expected, due to the well-preserved fluorite structure of the partially hydrogenated hydride, the desorption energy of HMg is significantly lower than that of bulk rutile MgH2. The further desorption of HMgTi and HTi becomes more difficult due to the strong Ti-H bonding. We propose that partial hydrogenation without adsorption of Hsurf and partial dehydrogenation without desorption of HMgTi and HTi would keep the fluorite symmetry with its favorable thermodynamics. The reversible hydrogen capacity (HMg) of the Mg/Ti/Mg sandwich structure is low, whereas the reversible hydrogen capacity of the Ti(core)/Mg(shell) is calculated to be reasonable high. Our results predicted Ti(core)/Mg(shell) structures are potential useful materials for hydrogen storage application.

  17. Efficiency of nuclear energy generation by hydrogen burning

    Energy Technology Data Exchange (ETDEWEB)

    Mitalas, R.

    1989-03-01

    An explicit formula for the efficiency of the PP chain energy generation in terms of the branching fractions to the three PP chains is derived and the variation of the efficiency with temperature and hydrogen abundance is illustrated. The PP chain efficiency is shown to have a minimum as a function of Y/X. The combined efficiency of simultaneous nuclear energy generation by the PP chain and the equilibrium CN cycle is then presented. 6 refs.

  18. Energy Technology Analysis Prospects for Hydrogen and Fuel Cells

    CERN Document Server

    2005-01-01

    Energy security, economic prosperity and environmental protection are prominent challenges for all countries. The use of hydrogen as an energy carrier and fuel cells as motive devices in transportation and energy distribution systems are possible solutions. This book provides the reader with an authoritative and objective analysis of policy responses and hurdles and business opportunities. Information regarding the latest RD&D, policy initiatives and private sector plans are assessed from the perspective of the rapidly changing global energy system in the next half century. This book prov

  19. Hydrogen as a fuel

    Energy Technology Data Exchange (ETDEWEB)

    1979-01-01

    A panel of the Committee on Advanced Energy Storage Systems of the Assembly of Engineering has examined the status and problems of hydrogen manufacturing methods, hydrogen transmission and distribution networks, and hydrogen storage systems. This examination, culminating at a time when rapidly changing conditions are having noticeable impact on fuel and energy availability and prices, was undertaken with a view to determining suitable criteria for establishing the pace, timing, and technical content of appropriate federally sponsored hydrogen R and D programs. The increasing urgency to develop new sources and forms of fuel and energy may well impact on the scale and timing of potential future hydrogen uses. The findings of the panel are presented. Chapters are devoted to hydrogen sources, hydrogen as a feedstock, hydrogen transport and storage, hydrogen as a heating fuel, automotive uses of hydrogen, aircraft use of hydrogen, the fuel cell in hydrogen energy systems, hydrogen research and development evaluation, and international hydrogen programs.

  20. Alternative Energetics DC Microgrid With Hydrogen Energy Storage System

    Directory of Open Access Journals (Sweden)

    Zaļeskis Genadijs

    2016-12-01

    Full Text Available This paper is related to an alternative energetics microgrid with a wind generator and a hydrogen energy storage system. The main aim of this research is the development of solutions for effective use of the wind generators in alternative energetics devices, at the same time providing uninterrupted power supply of the critical loads. In this research, it was accepted that the alternative energetics microgrid operates in an autonomous mode and the connection to the conventional power grid is not used. In the case when wind speed is low, the necessary power is provided by the energy storage system, which includes a fuel cell and a tank with stored hydrogen. The theoretical analysis of the storage system operation is made. The possible usage time of the stored hydrogen depends on the available amount of hydrogen and the consumption of the hydrogen by the fuel cell. The consumption, in turn, depends on used fuel cell power. The experimental results suggest that if the wind generator can provide only a part of the needed power, the abiding power can be provided by the fuel cell. In this case, a load filter is necessary to decrease the fuel cell current pulsations.

  1. Geothermal Energy: Tapping the Potential

    Science.gov (United States)

    Johnson, Bill

    2008-01-01

    Ground source geothermal energy enables one to tap into the earth's stored renewable energy for heating and cooling facilities. Proper application of ground-source geothermal technology can have a dramatic impact on the efficiency and financial performance of building energy utilization (30%+). At the same time, using this alternative energy…

  2. Biowaste energy potential in Kenya

    NARCIS (Netherlands)

    Nzila, C.; DeWulf, J.; Spanjers, H.; Kiriamiti, H.; Langenhove, H.

    2010-01-01

    Energy affects all aspects of national development. Hence the current global energy crisis demands greater attention to new initiatives on alternative energy sources that are renewable, economically feasible and sustainable. The agriculture-dependent developing countries in Africa can mitigate the e

  3. Electronic excitation of molecular hydrogen by low-energy electrons

    Science.gov (United States)

    Hargreaves, Leigh

    2016-09-01

    Molecular hydrogen is the most abundant element in the universe, particularly in interstellar plasmas such as atmospheres of gas giant planets and stars. Electron collision data for hydrogen is critical to interpreting the spectroscopy of interstellar objects, as well as being of applied value for modelling technological plasmas. Hydrogen is also fundamentally interesting, as while highly accurate wave functions for this simple molecule are available, providing an accurate, ab initio, treatment the collision dynamics has proven challenging, on account of the need to have a complete description of channel coupling and polarization effects. To date, no single theoretical approach has been able to replicate experimental results across all transitions and incident energies, while the experimental database that is available is far from complete and not all available measurements are in satisfactory agreement. In this talk, we present differential and integral cross section measurements for electronic excitation cross sections for molecular hydrogen by low-energy electron impact. The data were measured at incident energies below 20eV, using a well-tested crossed beam apparatus and employing a moveable gas source approach to ensure that background contributions to the scattering are accurately accounted for. These measurements are compared with new theoretical results employing the convergent close coupling approach.

  4. Renewable energy costs, potentials, barriers: Conceptual issues

    Energy Technology Data Exchange (ETDEWEB)

    Verbruggen, Aviel, E-mail: aviel.verbruggen@ua.ac.b [University of Antwerp (Belgium); Fischedick, Manfred [Wuppertal Institute for Climate, Environment, Energy (Germany); Moomaw, William [Tufts University, Center for International Environment and Resource Policy (United States); Weir, Tony [University of the South Pacific, Fiji Islands (Fiji); Nadai, Alain [Centre International de Recherche sur nvironnement et le Developpement CIRED (France); Nilsson, Lars J. [University of Lund (Sweden); Nyboer, John [Simon Fraser University, School of Resource and Environmental Management (Canada); Sathaye, Jayant [Lawrence Berkeley Laboratory (United States)

    2010-02-15

    Renewable energy can become the major energy supply option in low-carbon energy economies. Disruptive transformations in all energy systems are necessary for tapping widely available renewable energy resources. Organizing the energy transition from non-sustainable to renewable energy is often described as the major challenge of the first half of the 21st century. Technological innovation, the economy (costs and prices) and policies have to be aligned to achieve full renewable energy potentials, and barriers impeding that growth need to be removed. These issues are also covered by IPCC's special report on renewable energy and climate change to be completed in 2010. This article focuses on the interrelations among the drivers. It clarifies definitions of costs and prices, and of barriers. After reviewing how the third and fourth assessment reports of IPCC cover mitigation potentials and commenting on definitions of renewable energy potentials in the literature, we propose a consistent set of potentials of renewable energy supplies.

  5. Kinetics with deactivation of methylcyclohexane dehydrogenation for hydrogen energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Maria, G.; Marin, A.; Wyss, C.; Mueller, S.; Newson, E. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    The methylcyclohexane dehydrogenation step to recycle toluene and release hydrogen is being studied as part of a hydrogen energy storage project. The reaction is performed catalytically in a fixed bed reactor, and the efficiency of this step significantly determines overall system economics. The fresh catalyst kinetics and the deactivation of the catalyst by coke play an important role in the process analysis. The main reaction kinetics were determined from isothermal experiments using a parameter sensitivity analysis for model discrimination. An activation energy for the main reaction of 220{+-}11 kJ/mol was obtained from a two-parameter model. From non-isothermal deactivation in PC-controlled integral reactors, an activation energy for deactivation of 160 kJ/mol was estimated. A model for catalyst coke content of 3-17 weight% was compared with experimental data. (author) 3 figs., 6 refs.

  6. Assessment of potential future hydrogen markets in the U.S.

    Science.gov (United States)

    Kashani, A. K.

    1980-01-01

    Potential future hydrogen markets in the United States are assessed. Future hydrogen markets for various use sectors are projected, the probable range of hydrogen production costs from various alternatives is estimated, stimuli and barriers to the development of hydrogen markets are discussed, an overview of the status of technologies for the production and utilization of hydrogen is presented, and, finally, societal aspects of hydrogen production and utilization are discussed.

  7. Hydrogen Production from Sea Wave for Alternative Energy Vehicles for Public Transport in Trapani (Italy

    Directory of Open Access Journals (Sweden)

    Vincenzo Franzitta

    2016-10-01

    Full Text Available The coupling of renewable energy and hydrogen technologies represents in the mid-term a very interesting way to match the tasks of increasing the reliable exploitation of wind and sea wave energy and introducing clean technologies in the transportation sector. This paper presents two different feasibility studies: the first proposes two plants based on wind and sea wave resource for the production, storage and distribution of hydrogen for public transportation facilities in the West Sicily; the second applies the same approach to Pantelleria (a smaller island, including also some indications about solar resource. In both cases, all buses will be equipped with fuel-cells. A first economic analysis is presented together with the assessment of the avoidable greenhouse gas emissions during the operation phase. The scenarios addressed permit to correlate the demand of urban transport to renewable resources present in the territories and to the modern technologies available for the production of hydrogen from renewable energies. The study focuses on the possibility of tapping the renewable energy potential (wind and sea wave for the hydrogen production by electrolysis. The use of hydrogen would significantly reduce emissions of particulate matter and greenhouse gases in urban districts under analysis. The procedures applied in the present article, as well as the main equations used, are the result of previous applications made in different technical fields that show a good replicability.

  8. Hydrogen based energy storage for solar energy systems

    Energy Technology Data Exchange (ETDEWEB)

    Vanhanen, J.; Hagstroem, M.; Lund, P. [Helsinki Univ. of Technology, Otaniemi (Finland). Advanced Energy Systems

    1998-10-01

    The main technical constraint in solar energy systems which operate around the year is the lack of suitable long-term energy storage. Conventional solutions to overcome the problem of seasonal storage in PV power systems are to use oversized batteries as a seasonal energy storage, or to use a diesel back-up generator. However, affordable lead-acid batteries are not very suitable for seasonal energy storage because of a high self-discharge rate and enhanced deterioration and divergence of the single cells during prolonged periods of low state of charge in times of low irradiation. These disadvantages can be avoided by a back-up system, e.g. a diesel generator, which car supply energy to the loads and charge the battery to the full state of charge to avoid the above mentioned disadvantages. Unfortunately, diesel generators have several disadvantages, e.g. poor starting reliability, frequent need for maintenance and noise

  9. Energy efficiency potentials and energy management practices in Swedish firms

    OpenAIRE

    Backlund, Sandra; Broberg, Sarah; Ottosson, Mikael; Thollander, Patrik

    2012-01-01

    In order to improve energy efficiency and reach the EU:s 20-20-20 primary energy saving target, focus has mainly been on diffusion of technology. Previous studies have illustrated large untapped energy saving potentials from implementing energy management practices in firms. Energy management practices have large effects on energy utilization and also a short pay-back time. According to these studies, energy management practices also effect investment decisions and the outcome of investments ...

  10. Photobiological production of hydrogen: a solar energy conversion option

    Energy Technology Data Exchange (ETDEWEB)

    Weaver, P.; Lien, S.; Seibert, M.

    1979-01-01

    This literature survey of photobiological hydrogen production covers the period from its discovery in relatively pure cultures during the early 1930s to the present. The focus is hydrogen production by phototrophic organisms (and their components) which occurs at the expense of light energy and electron-donating substrates. The survey covers the major contributions in the area; however, in many cases, space has limited the degree of detail provided. Among the topics included is a brief historical overview of hydrogen metabolism in photosynthetic bacteria, eucaryotic algae, and cyanobacteria (blue--green algae). The primary enzyme systems, including hydrogenase and nitrogenase, are discussed along with the manner in which they are coupled to electron transport and the primary photochemistry of photosynthesis. A number of in vivo and in vitro photobiological hydrogen evolving schemes including photosynthetic bacterial, green algal, cyanobacterial, two-stage, and cell-free systems are examined in some detail. The remainder of the review discusses specific technical problem areas that currently limit the yield and duration of many of the systems and research that might lead to progress in these specific areas. The final section outlines, in broadest terms, future research directions necessary to develop practical photobiological hydrogen-producing systems. Both whole cell (near- to mid-term) and cell-free (long-term) systems should be emphasized. Photosynthetic bacteria currently show the most promise for near-term applied systems.

  11. Dissociation Energies of Sulfur-Centered Hydrogen-Bonded Complexes.

    Science.gov (United States)

    Ghosh, Sanat; Bhattacharyya, Surjendu; Wategaonkar, Sanjay

    2015-11-01

    In this work we have determined dissociation energies of O-H···S hydrogen bond in the H2S complexes of various phenol derivatives using 2-color-2-photon photofragmentation spectroscopy in combination with zero kinetic energy photoelectron (ZEKE-PE) spectroscopy. This is the first report of direct determination of dissociation energy of O-H···S hydrogen bond. The ZEKE-PE spectra of the complexes revealed a long progression in the intermolecular stretching mode with significant anharmonicity. Using the anharmonicity information and experimentally determined dissociation energy, we also validated Birge-Sponer (B-S) extrapolation method, which is an approximate method to estimate dissociation energy. Experimentally determined dissociation energies were compared with a variety of ab initio calculations. One of the important findings is that ωB97X-D functional, which is a dispersion corrected DFT functional, was able to predict the dissociation energies in both the cationic as well as the ground electronic state very well for almost every case.

  12. Wind energy, electricity, and hydrogen in the Netherlands

    NARCIS (Netherlands)

    Schenk, Niels J.; Moll, Henri C.; Potting, José; Benders, René M.J.

    2007-01-01

    The curbing of greenhouse gases (GHG) is an important issue on the international political agenda. The substitution of fossil fuels by renewable energy sources is an often-advocated mitigation strategy. Wind energy is a potential renewable energy source. However, wind energy is not reliable since

  13. Wind energy, electricity, and hydrogen in the Netherlands

    NARCIS (Netherlands)

    Schenk, Niels J.; Moll, Henri C.; Potting, José; Benders, René M.J.

    2007-01-01

    The curbing of greenhouse gases (GHG) is an important issue on the international political agenda. The substitution of fossil fuels by renewable energy sources is an often-advocated mitigation strategy. Wind energy is a potential renewable energy source. However, wind energy is not reliable since it

  14. Hybrid functional calculations of potential hydrogen storage material: Complex dimagnesium iron hydride

    KAUST Repository

    Ul Haq, Bakhtiar

    2014-06-01

    By employing the state of art first principles approaches, comprehensive investigations of a very promising hydrogen storage material, Mg 2FeH6 hydride, is presented. To expose its hydrogen storage capabilities, detailed structural, elastic, electronic, optical and dielectric aspects have been deeply analysed. The electronic band structure calculations demonstrate that Mg2FeH6 is semiconducting material. The obtained results of the optical bandgap (4.19 eV) also indicate that it is a transparent material for ultraviolet light, thus demonstrating its potential for optoelectronics application. The calculated elastic properties reveal that Mg2FeH6 is highly stiff and stable hydride. Finally, the calculated hydrogen (H2) storage capacity (5.47 wt.%) within a reasonable formation energy of -78 kJ mol-1, at room temperature, can be easily achievable, thus making Mg2FeH6 as potential material for practical H2 storage applications. Copyright © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

  15. Electronic structure, molecular bonding and potential energy surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Ruedenberg, K. [Ames Laboratory, IA (United States)

    1993-12-01

    By virtue of the universal validity of the generalized Born-Oppenheimer separation, potential energy surfaces (PES`) represent the central conceptual as well as quantitative entities of chemical physics and provide the basis for the understanding of most physicochemical phenomena in many diverse fields. The research in this group deals with the elucidation of general properties of PES` as well as with the quantitative determination of PES` for concrete systems, in particular pertaining to reactions involving carbon, oxygen, nitrogen and hydrogen molecules.

  16. Japan's New Sunshine Project. 1998 Annual summary of hydrogen energy R and D

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    Summarized herein are the reports on R and D efforts on hydrogen energy, as part of the FY 1998 New Sunshine Project. For production of hydrogen, characteristics related to transport number were investigated for steam electrolysis at high temperature, in which a sintered ceramic powder was used as the electrolyte and the cell was equipped with platinum electrodes. For utilization of hydrogen, energy conversion techniques were investigated using hydrogen occluding alloys for testing methods for alloy microstructures and hydrogenation characteristics, and preparation of and performance testing methods for the cathodes charged with the aid of hydrogen gas. For analysis/assessment for development of hydrogen-related techniques, the investigated items included water electrolysis with solid polymer electrolytes, hydrogen transport techniques using metal hydrides, hydrogen storing techniques using metal hydrides, hydrogen engines, and techniques for preventing hydrogen embrittlement. Analysis/assessment for development of hydrogen turbines was also investigated as one of the 12 R and D themes reported herein. (NEDO)

  17. Potential of renewable and alternative energy sources

    Science.gov (United States)

    Konovalov, V.; Pogharnitskaya, O.; Rostovshchikova, A.; Matveenko, I.

    2015-11-01

    The article deals with application potential of clean alternative renewable energy sources. By means of system analysis the forecast for consumption of electrical energy in Tomsk Oblast as well as main energy sources of existing energy system have been studied up to 2018. Engineering potential of renewable and alternative energy sources is evaluated. Besides, ranking in the order of their efficiency descending is performed. It is concluded that Tomsk Oblast has high potential of alternative and renewable energy sources, among which the most promising development perspective is implementation of gasification stations to save fuel consumed by diesel power stations as well as building wind-power plants.

  18. Mixed Potential Energy Surfaces of the Ultrafast Isomerization of Retinal in Bacteriorhodopsin

    Directory of Open Access Journals (Sweden)

    Prokhorenko Valentyn I.

    2013-03-01

    Full Text Available We observe, using electronic two-dimensional photon echo spectroscopy, that the cis and trans potential energy surfaces of the ultrafast isomerization of retinal in bacteriorhodopsin are mixed via the hydrogen out of plane (HOOP mode.

  19. Estimating the energy of intramolecular hydrogen bonds in chitosan oligomers

    Science.gov (United States)

    Mikhailov, G. P.; Lazarev, V. V.

    2016-07-01

    The effect the number of chitosan monomer units CTS n ( n = 1-5), the protonation of chitosan dimers, and the interaction between CTS n ( n = 1-3) and acetate ions have on the energy of intramolecular hydrogen bonds is investigated by means of QTAIM analysis and solving the vibrational problem within the cluster-continuum model. It is established that the number of H-bonds in CTS n is 2 n - 1 and the total energy of H-bonds grows by ~20 kJ/mol. It is concluded that the hydrogen bonds between CTS and acetate ions play a major role in the stabilization of polyelectrolyte complexes in dilute acetic acid solutions of CTS.

  20. Solar hydrogen energy pilot project for Libya, SHEPL

    Energy Technology Data Exchange (ETDEWEB)

    Gibril S Eljrushi [Faculty of Engineering, University of 7th October, Misurata, (Libyan Arab Jamahiriya); Madani A Dakhil [Faculty of Science, Al-Fateh University, Tripoli, (Libyan Arab Jamahiriya); Mohammed F Aldrini [G. S., Faculty of Engineering, University of 7th October, Misurata, (Libyan Arab Jamahiriya)

    2006-07-01

    This work presents the first stage of the SHEPL project which includes technical and economic analysis of the main project components. These are Photovoltaics power generation of one MW, electrolysis plant for hydrogen production, fuel cells power plant to generate electricity at night time, sea water desalination plant, and other required facilities. The project is intended to supply a small community of twenty families with all its energy and water requirements, to be completely independent from local utilities. (authors)

  1. Hydrogen-Oxygen PEM Regenerative Fuel Cell Energy Storage System

    Science.gov (United States)

    Bents, David J.; Scullin, Vincent J.; Chang, Bei-Jiann; Johnson, Donald W.; Garcia, Christopher P.

    2005-01-01

    An introduction to the closed cycle hydrogen-oxygen polymer electrolyte membrane (PEM) regenerative fuel cell (RFC), recently constructed at NASA Glenn Research Center, is presented. Illustrated with explanatory graphics and figures, this report outlines the engineering motivations for the RFC as a solar energy storage device, the system requirements, layout and hardware detail of the RFC unit at NASA Glenn, the construction history, and test experience accumulated to date with this unit.

  2. Thermodynamic Stability of Ice II and Its Hydrogen-Disordered Counterpart: Role of Zero-Point Energy.

    Science.gov (United States)

    Nakamura, Tatsuya; Matsumoto, Masakazu; Yagasaki, Takuma; Tanaka, Hideki

    2016-03-03

    We investigate why no hydrogen-disordered form of ice II has been found in nature despite the fact that most of hydrogen-ordered ices have hydrogen-disordered counterparts. The thermodynamic stability of a set of hydrogen-ordered ice II variants relative to ice II is evaluated theoretically. It is found that ice II is more stable than the disordered variants so generated as to satisfy the simple ice rule due to the lower zero-point energy as well as the pair interaction energy. The residual entropy of the disordered ice II phase gradually compensates the unfavorable free energy with increasing temperature. The crossover, however, occurs at a high temperature well above the melting point of ice III. Consequently, the hydrogen-disordered phase does not exist in nature. The thermodynamic stability of partially hydrogen-disordered ices is also scrutinized by examining the free-energy components of several variants obtained by systematic inversion of OH directions in ice II. The potential energy of one variant is lower than that of the ice II structure, but its Gibbs free energy is slightly higher than that of ice II due to the zero-point energy. The slight difference in the thermodynamic stability leaves the possibility of the partial hydrogen-disorder in real ice II.

  3. Modular Energy Storage System for Hydrogen Fuel Cell Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, Janice [Magna International, Rochester Mills, MI (United States)

    2010-08-27

    The objective of the project is to develop technologies, specifically power electronics, energy storage electronics and controls that provide efficient and effective energy management between electrically powered devices in alternative energy vehicles plug-in electric vehicles, hybrid vehicles, range extended vehicles, and hydrogen-based fuel cell vehicles. The in-depth research into the complex interactions between the lower and higher voltage systems from data obtained via modeling, bench testing and instrumented vehicle data will allow an optimum system to be developed from a performance, cost, weight and size perspective. The subsystems are designed for modularity so that they may be used with different propulsion and energy delivery systems. This approach will allow expansion into new alternative energy vehicle markets.

  4. NMR relaxation rate and the libron energy of solid hydrogen

    Science.gov (United States)

    Sugawara, K.; Woollam, J. A.

    1978-01-01

    By taking the rotational relaxation of orthohydrogen (o-H2) in solid hydrogen into account, the authors have theoretically investigated the longitudinal NMR spin lattice relaxation rate of o-H2. The rate is characterized by an anomalous maximum, as a function of temperature, at temperatures close to the mean libron energy of o-H2. Application of the theory for o-H2 concentrations between 42% and 75% reveals a nearly concentration-independent mean libron energy equivalent to about 1 K. This qualitatively and quantitatively contradicts the conclusions of other theories, but agrees with recent experiments.

  5. Hydrogen energy system & economic development of China%Hydrogen energy system & economic develop ment of China

    Institute of Scientific and Technical Information of China (English)

    T.Nejat Veziroglu

    2009-01-01

    @@ Today fossil fuels(coal,petroleum and natural gas)meet about 80 percent of oar worldwide energy requirements.The demand for energy is growing with time for two reasons:(1)the growing population,and(2)the increasing demand for energy by the developing countries(especially China and India with very large populations).

  6. Potential energy savings and thermal comfort

    DEFF Research Database (Denmark)

    Jensen, Karsten Ingerslev; Rudbeck, Claus Christian; Schultz, Jørgen Munthe

    1996-01-01

    The simulation results on the energy saving potential and influence on indoor thermal comfort by replacement of common windows with aerogel windows as well as commercial low-energy windows are described and analysed.......The simulation results on the energy saving potential and influence on indoor thermal comfort by replacement of common windows with aerogel windows as well as commercial low-energy windows are described and analysed....

  7. Hydrogen - the source of energy for future transport

    Energy Technology Data Exchange (ETDEWEB)

    Wacker, M.; Schubert, J.

    2001-07-01

    Although the European laws for the limitation of emissions proved to be very efficient in leading to very good results, it is doubtful whether gasoline and diesel can be used as fuels in motor vehicles for an unlimited period of time. The problem of the 'greenhouse-effect' generated partly by the release of CO{sub 2} from combustion engines along with the limitation of the natural reserves of oil and natural gas call for the search for an alternative fuel. Hydrogen is currently the undisputed alternative for the future. Therefore a lot of tests have already been done with hydrogen powered vehicles in Germany. The most successful concepts are those in which the fuel cell is implemented to produce on-board power. On assignment of the Ministry for Environment and Traffic of the state of Baden-Wuerttemberg (Germany) the short-term, medium-term and long-term effects of the introduction of hydrogen powered fuel cell busses are being analyzed by means of three scenarios taking the state of Baden-Wuerttemberg as an example. The evaluation of the economic effects is intended to illustrate the supplementary costs arising for the bus operators due to the new actuation concept. The ecological and economic effects are being estimated in dependence of the presentation of energy consumption and emissions occurring in the case of implementation of hydrogen powered fuel cell busses in comparison to values furnished by diesel powered busses. (orig.)

  8. Phase II Final Project Report SBIR Project: "A High Efficiency PV to Hydrogen Energy System"

    Energy Technology Data Exchange (ETDEWEB)

    Slade, A; Turner, J; Stone, K; McConnell, R

    2008-09-02

    The innovative research conducted for this project contributed greatly to the understanding of generating low-cost hydrogen from solar energy. The project’s research identified two highly leveraging and complementary pathways. The first pathway is to dramatically increase the efficiency of converting sunlight into electricity. Improving solar electric conversion efficiency directly increases hydrogen production. This project produced a world record efficiency for silicon solar cells and contributed to another world record efficiency for a solar concentrator module using multijunction solar cells. The project’s literature review identified a second pathway in which wasted heat from the solar concentration process augments the electrolysis process generating hydrogen. One way to do this is to use a “heat mirror” that reflects the heat-producing infrared and transmits the visible spectrum to the solar cells; this also increases solar cell conversion efficiency. An economic analysis of this concept confirms that, if long-term concentrator photovoltaic (CPV) and solid-oxide electrolyzer cost goals can be achieved, hydrogen will be produced from solar energy cheaper than the cost of gasoline. The potential public benefits from this project are significant. The project has identified a potential energy source for the nation’s future electricity and transportation needs that is entirely “home grown” and carbon free. As CPV enter the nation’s utility markets, the opportunity for this approach to be successful is greatly increased. Amonix strongly recommends further exploration of this project’s findings.

  9. Hydrogen Energy Storage: Grid and Transportation Services (Technical Report)

    Energy Technology Data Exchange (ETDEWEB)

    2015-02-01

    Proceedings of an expert workshop convened by the U.S. Department of Energy and Industry Canada, and hosted by the National Renewable Energy Laboratory and the California Air Resources Board, May 14-15, 2014, in Sacramento, California, to address the topic of hydrogen energy storage (HES). HES systems provide multiple opportunities to increase the resilience and improve the economics of energy sup supply systems underlying the electric grid, gas pipeline systems, and transportation fuels. This is especially the case when considering particular social goals and market drivers, such as reducing carbon emissions, increasing reliability of supply, and reducing consumption of conventional petroleum fuels. This report compiles feedback collected during the workshop, which focused on policy and regulatory issues related to HES systems. Report sections include an introduction to HES pathways, market demand, and the "smart gas" concept; an overview of the workshop structure; and summary results from panel presentations and breakout groups.

  10. Long-term environmental and socio-economic impact of a hydrogen energy program in Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Lutero Carmo de [Uberlandia Univ., Dept. of Mechanical Engineering, Uberlandia, MG (Brazil); Veziroglu, T. Nejat [Miami Univ., Clean Energy Research Inst., Coral Gables, FL (United States)

    2001-07-01

    In this study, a program of electrolytic hydrogen generation for Brazil through the assistance of photovoltaic cell panels is proposed. The generated hydrogen will serve as an energy carrier and will be used in every application where fossil fuels are being used today. Three scenarios have been considered: fast hydrogen introduction, slow hydrogen introduction, and no hydrogen introduction. The results show that hydrogen introduction (1) will increase the energy consumption, (2) will increase the gross national product per capita, (3) will reduce pollution, and (4) will increase the quality of life in Brazil. Fast hydrogen introduction brings the benefits by 20 years earlier. (Author)

  11. Hydrogen, energy vector of the future?; L'hydrogene, vecteur energetique de l'avenir?

    Energy Technology Data Exchange (ETDEWEB)

    Perrin, J. [Air Liquide, Programme de R and D Hydrogene-Energie, 75 - Paris (France); Deschamps, J.F. [Air Liquide, Marche Hydrogene Clients Industriels, 75 - Paris (France)

    2004-07-01

    In the framework of a sustainable development with a reduction of the greenhouse gases emissions, the hydrogen seems a good solution because its combustion produces only water. From the today hydrogen industrial market, the authors examine the technological challenges and stakes of the hydrogen-energy. They detail the hydrogen production, distribution and storage and compare with the petrol and the natural gas. Then they explain the fuel cells specificity and realize a classification of the energy efficiency of many associations production-storage-distribution-use. a scenario of transition is proposed. (A.L.B.)

  12. Hydrogen and renewable energy sources integrated system for greenhouse heating

    Directory of Open Access Journals (Sweden)

    Ileana Blanco

    2013-09-01

    Full Text Available A research is under development at the Department of Agro- Environmental Sciences of the University of Bari “Aldo Moro” in order to investigate the suitable solutions of a power system based on solar energy (photovoltaic and hydrogen, integrated with a geothermal heat pump for powering a self sustained heated greenhouse. The electrical energy for heat pump operation is provided by a purpose-built array of solar photovoltaic modules, which supplies also a water electrolyser system controlled by embedded pc; the generated dry hydrogen gas is conserved in suitable pressured storage tank. The hydrogen is used to produce electricity in a fuel cell in order to meet the above mentioned heat pump power demand when the photovoltaic system is inactive during winter night-time or the solar radiation level is insufficient to meet the electrical demand. The present work reports some theoretical and observed data about the electrolyzer operation. Indeed the electrolyzer has required particular attention because during the experimental tests it did not show a stable operation and it was registered a performance not properly consistent with the predicted performance by means of the theoretical study.

  13. Evaluation of the photochemical production of hydrogen from solar energy

    Energy Technology Data Exchange (ETDEWEB)

    Heppert, J. A.

    1977-08-09

    The potential for utilizing solar energy through photochemical storage were investigated. Both water and nitrosyl chloride systems are examined. A comprehensive review of the literature led to the conclusion that many major questions must be answered before photochemical energy storage becomes a viable alternate means of exploiting solar energy.

  14. Basis set effects on the energy and hardness profiles of the hydrogen fluoride dimer

    Indian Academy of Sciences (India)

    Miquel Torrent-Sucarrat; Miquel Duran; Josep M Luis; Miquel Solà

    2005-09-01

    In earlier work, the present authors have shown that hardness profiles are less dependent on the level of calculation than energy profiles for potential energy surfaces (PESs) having pathological behaviors. At variance with energy profiles, hardness profiles always show the correct number of stationary points. This characteristic has been used to indicate the existence of spurious stationary points on the PESs. In the present work, we apply this methodology to the hydrogen fluoride dimer, a classical difficult case for the density functional theory methods.

  15. [Biomass energy utilization in microbial fuel cells: potentials and challenges].

    Science.gov (United States)

    Huang, Liping; Cheng, Shaoan

    2010-07-01

    Microbial fuel cells (MFCs) that can harvest biomass energy from organic wastes through microbial catalysis have garnered more and more attention within the past decade due to its potential benefits to ecological environment. In this article, the updated progress in MFCs is reviewed, with a focus on frontier technologies such as chamber configurations, feedstock varieties and the integration of MFCs with microbial electrolysis cells for hydrogen production. And on the other hand, the challenges like development of cost-effective electrode materials, improvement of biomass energy recovery and power output, design and optimization of commercial MFC devices are presented.

  16. High Temperature Electrolysis for Hydrogen Production from Nuclear Energy – TechnologySummary

    Energy Technology Data Exchange (ETDEWEB)

    J. E. O' Brien; C. M. Stoots; J. S. Herring; M. G. McKellar; E. A. Harvego; M. S. Sohal; K. G. Condie

    2010-02-01

    The Department of Energy, Office of Nuclear Energy, has requested that a Hydrogen Technology Down-Selection be performed to identify the hydrogen production technology that has the best potential for timely commercial demonstration and for ultimate deployment with the Next Generation Nuclear Plant (NGNP). An Independent Review Team has been assembled to execute the down-selection. This report has been prepared to provide the members of the Independent Review Team with detailed background information on the High Temperature Electrolysis (HTE) process, hardware, and state of the art. The Idaho National Laboratory has been serving as the lead lab for HTE research and development under the Nuclear Hydrogen Initiative. The INL HTE program has included small-scale experiments, detailed computational modeling, system modeling, and technology demonstration. Aspects of all of these activities are included in this report. In terms of technology demonstration, the INL successfully completed a 1000-hour test of the HTE Integrated Laboratory Scale (ILS) technology demonstration experiment during the fall of 2008. The HTE ILS achieved a hydrogen production rate in excess of 5.7 Nm3/hr, with a power consumption of 18 kW. This hydrogen production rate is far larger than has been demonstrated by any of the thermochemical or hybrid processes to date.

  17. Journal Of The Korean Hydrogen Energy Society 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-11-15

    This book is the Journal of the Korean hydrogen energy society, which includes study on the improvement of the electrochemical characteristics of surface-modified V-Ti-Cr alloy by Ball-milling by Kim, Jin Ho; Lee, Sang Min; Lee, Ho; Lee, Paul S. and Lee, Jai Young, hydrogen generation from water using cds-zns photocatalysts by Heo, Gwi Suk, characteristics of Y-Hx Film by Cho, Young Sin; Kim, Sun Hee, and effect of Cu powder as a compacting material on the discharge characteristics of the negative electrode of Ni-MH battery by Jung, J. H.; Han, Y. S.; Yu, J. S.; Jang, K. J.; Lee, J. Y.

  18. Biohydrogen production as a potential energy fuel in South Africa

    Directory of Open Access Journals (Sweden)

    P.T. Sekoai

    2015-06-01

    Full Text Available Biohydrogen production has captured increasing global attention due to it social, economic and environmental benefits. Over the past few years, energy demands have been growing significantly in South Africa due to rapid economic and population growth. The South African parastatal power supplier i.e. Electricity Supply Commission (ESKOM has been unable to meet the country’s escalating energy needs. As a result, there have been widespread and persistent power cuts throughout the country. This prompts an urgent need for exploration and implementation of clean and sustainable energy fuels like biohydrogen production in order to address this crisis. Therefore, this paper discusses the current global energy challenges in relation to South Africa’s problems. It then examines the feasibility of using biohydrogen production as a potential energy fuel in South Africa. Finally, it reviews the hydrogen-infrastructure development plans in the country.

  19. Storing unsteady energy, like photovoltaically generated electric energy, as potential energy

    OpenAIRE

    Kutz, Nadja

    2012-01-01

    A proposal to store unsteady energy in potential energy via lifting masses with a rough quantitative overview. Some applications and methods to harvest the potential energy are also given. A focus is put on photovoltaically generated energy.

  20. Study on Introduction of CO2 Free Energy to Japan with Liquid Hydrogen

    Science.gov (United States)

    Kamiya, Shoji; Nishimura, Motohiko; Harada, Eichi

    In Japan, both CO2(Carbon dioxide) emission reduction and energy security are the very important social issues after Fukushima Daiichi accident. On the other hand, FCV (Fuel Cell Vehicle)using hydrogen will be on the market in 2015. Introducing large mass hydrogen energy is being expected as expanding hydrogen applications, or solution to energy issues of Japan.And then,the Japanese government announced the road map for introducing hydrogen energy supply chain in this June,2014. Under these circumstances, imported CO2 free hydrogen will be one of the solutions for energy security and CO2 reduction, if the hydrogen price is affordable. To achieve this, Kawasaki Heavy Industries, Ltd. (KHI) performed a feasibility studyon CO2-free hydrogen energy supply chainfrom Australian brown coal linked with CCS (Carbon dioxide Capture and Storage) to Japan. In the study, hydrogen production systems utilizing brown coal gasificationandLH2 (liquid hydrogen)systems as storing and transporting hydrogen are examined.This paper shows the possibilityof realizingthe CO2 free hydrogen supply chain, the cost breakdown of imported hydrogen cost, its cost competitiveness with conventionalfossil, andLH2systems as key technologies of the hydrogen energy chain.

  1. Geothermal Energy Potential in Western United States

    Science.gov (United States)

    Pryde, Philip R.

    1977-01-01

    Reviews types of geothermal energy sources in the western states, including hot brine systems and dry steam systems. Conversion to electrical energy is a major potential use of geothermal energy, although it creates environmental disruptions such as noise, corrosion, and scaling of equipment. (AV)

  2. Geothermal Energy Potential in Western United States

    Science.gov (United States)

    Pryde, Philip R.

    1977-01-01

    Reviews types of geothermal energy sources in the western states, including hot brine systems and dry steam systems. Conversion to electrical energy is a major potential use of geothermal energy, although it creates environmental disruptions such as noise, corrosion, and scaling of equipment. (AV)

  3. Energy potential mapping for energy-producing neighborhoods

    NARCIS (Netherlands)

    Dobbelsteen, van den A.; Broersma, S.; Stremke, S.

    2011-01-01

    Over the past five years, the method of energy potential mapping (EPM) has evolved from a cartoonish charting of climatic features with energy consequences to a detailed methodology for the development of spatial plans based on energy-effective foundations. By means of EPM the rudimentary features

  4. Assessment of wind energy potential in China

    Institute of Scientific and Technical Information of China (English)

    Zhu Rong; Zhang De; Wang Yuedong; Xing Xuhuang; Li Zechun

    2009-01-01

    China wind atlas was made by numerical simulation and the wind energy potential in China was calculated. The model system for wind energy resource assessment was set up based on Canadian Wind Energy Simulating Toolkit (WEST) and the simulating method was as follows. First, the weather classes were obtained depend on meteorological data of 30 years. Then, driven by the initial meteorological field produced by each weather class, the meso-scale model ran for the distribution of wind energy resources according each weather class condition one by one. Finally, averaging all the modeling output weighted by the occurrence frequency of each weather class, the annual mean distribution of wind energy resources was worked out. Compared the simulated wind energy potential with other results from several ac-tivities and studies for wind energy resource assessment, it is found that the simulated wind energy potential in mainland of China is 3 times that from the second and the third investigations for wind energy resources by CMA, and is similar to the wind energy potential obtained by NREL in Solar and Wind Energy Resource Assessment (SWERA) project. The simulated offshore wind energy potential of China seems smaller than the true value. According to the simulated results of CMA and considering lots of limited factors to wind energy development, the final conclusion can be obtained that the wind energy availability in China is 700~1 200 GW, in which 600~1 000 GW is in mainland and 100~200 GW is on offshore, and wind power will become the important part of energy composition in future.

  5. Hydrogen amid the change of the energy supply system; Wasserstoff im Wandel der Energieversorgung

    Energy Technology Data Exchange (ETDEWEB)

    Hoehlein, Bernd; Kattenstein, Thomas [EnergieAgentur.NRW, Duesseldorf (Germany). Netzwerk Brennstoffzelle und Wasserstoff NRW; Toepler, Johannes [Deutscher Wasserstoff und Brennstoffzellenverband e.V., Berlin (Germany)

    2013-01-15

    Germany has set itself ambitious goals for the energy turnaround. Being a complementary energy carrier hydrogen could play an important role in their achievement. One of the great advantages of hydrogen is its excellent storability. Due to the fact that energy can be converted back and forth between hydrogen and electricity, making use of hydrogen alongside the heavily fluctuating feed-in of renewable energy could prove a wise decision. The present article analyses what opportunities are associated with the integration of hydrogen but also what challenges must be taken into consideration and ultimately mastered.

  6. Renewable energy costs, potentials, barriers. Conceptual issues

    Energy Technology Data Exchange (ETDEWEB)

    Verbruggen, Aviel [University of Antwerp (Belgium); Fischedick, Manfred [Wuppertal Institute for Climate, Environment, Energy (Germany); Moomaw, William [Tufts University, Center for International Environment and Resource Policy (United States); Weir, Tony [University of the South Pacific, Fiji Islands (Fiji); Nadai, Alain [Centre International de Recherche sur Environnement et le Developpement CIRED (France); Nilsson, Lars J. [University of Lund (Sweden); Nyboer, John [Simon Fraser University, School of Resource and Environmental Management (Canada); Sathaye, Jayant [Lawrence Berkeley Laboratory (United States)

    2010-02-15

    Renewable energy can become the major energy supply option in low-carbon energy economies. Disruptive transformations in all energy systems are necessary for tapping widely available renewable energy resources. Organizing the energy transition from non-sustainable to renewable energy is often described as the major challenge of the first half of the 21st century. Technological innovation, the economy (costs and prices) and policies have to be aligned to achieve full renewable energy potentials, and barriers impeding that growth need to be removed. These issues are also covered by IPCC's special report on renewable energy and climate change to be completed in 2010. This article focuses on the interrelations among the drivers. It clarifies definitions of costs and prices, and of barriers. After reviewing how the third and fourth assessment reports of IPCC cover mitigation potentials and commenting on definitions of renewable energy potentials in the literature, we propose a consistent set of potentials of renewable energy supplies. (author)

  7. Hydrogen.

    Science.gov (United States)

    Bockris, John O'M

    2011-11-30

    The idea of a "Hydrogen Economy" is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO₂ in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H₂ from the electrolyzer. Methanol made with CO₂ from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan). Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs) by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech.

  8. Model for energy conversion in renewable energy system with hydrogen storage

    Science.gov (United States)

    Kélouwani, S.; Agbossou, K.; Chahine, R.

    A dynamic model for a stand-alone renewable energy system with hydrogen storage (RESHS) is developed. In this system, surplus energy available from a photovoltaic array and a wind turbine generator is stored in the form of hydrogen, produced via an electrolyzer. When the energy production from the wind turbine and the photovoltaic array is not enough to meet the load demand, the stored hydrogen can then be converted by a fuel cell to produce electricity. In this system, batteries are used as energy buffers or for short time storage. To study the behavior of such a system, a complete model is developed by integrating individual sub-models of the fuel cell, the electrolyzer, the power conditioning units, the hydrogen storage system, and the batteries (used as an energy buffer). The sub-models are valid for transient and steady state analysis as a function of voltage, current, and temperature. A comparison between experimental measurements and simulation results is given. The model is useful for building effective algorithms for the management, control and optimization of stand-alone RESHSs.

  9. Viability of Hydrogen Pathways that Enhance Energy Security: A Comparison of China and Denmark

    DEFF Research Database (Denmark)

    Ren, Jingzheng; Andreasen, Kristian, Peter; Sovacool, Benjamin, K.

    2014-01-01

    When designed and built properly, hydrogen energy systems can enhance energy security through technological diversification and minimizing dependence on foreign imports of energy fuels. However, hydrogen can be produced from different feedstocks according to separate pathways, and these different...... objectives. The results are useful for stakeholders and energy analysts so that they can correctly plan and research the most socially optimal portfolio of hydrogen technologies....

  10. Hydrogen Generation Through Renewable Energy Sources at the NASA Glenn Research Center

    Science.gov (United States)

    Colozza, Anthony; Prokopius, Kevin

    2007-01-01

    An evaluation of the potential for generating high pressure, high purity hydrogen at the NASA Glenn Research Center (GRC) was performed. This evaluation was based on producing hydrogen utilizing a prototype Hamilton Standard electrolyzer that is capable of producing hydrogen at 3000 psi. The present state of the electrolyzer system was determined to identify the refurbishment requirements. The power for operating the electrolyzer would be produced through renewable power sources. Both wind and solar were considered in the analysis. The solar power production capability was based on the existing solar array field located at NASA GRC. The refurbishment and upgrade potential of the array field was determined and the array output was analyzed with various levels of upgrades throughout the year. The total available monthly and yearly energy from the array was determined. A wind turbine was also sized for operation. This sizing evaluated the wind potential at the site and produced an operational design point for the wind turbine. Commercially available wind turbines were evaluated to determine their applicability to this site. The system installation and power integration were also addressed. This included items such as housing the electrolyzer, power management, water supply, gas storage, cooling and hydrogen dispensing.

  11. The Hydrogen Economy Making the Transition to the Third Industrial Revolution and a New Energy Era

    Energy Technology Data Exchange (ETDEWEB)

    Jeremy Rifkin

    2006-07-01

    Jeremy Rifkin is the author of the international best seller, The Hydrogen Economy, which has been translated into fourteen languages. It is the most widely read book in the world on the future of renewable energy and the hydrogen economy. In his presentation on 'The Hydrogen Economy', Mr. Rifkin takes us on an eye-opening journey into the next great commercial era in history. He envisions the dawn of a new economy powered by hydrogen that will fundamentally change the nature of our market, political and social institutions, just as coal and steam power did at the beginning of the industrial age. Rifkin observes that we are fast approaching a critical watershed for the fossil-fuel era, with potentially dire consequences for industrial civilization. Experts had been saying that we had another forty or so years of cheap available crude oil left. Now, however, some of the world's leading petroleum geologists are suggesting that global oil production could peak and begin a steep decline much sooner, as early as the second decade of the 21. century. Non-OPEC oil producing countries are already nearing their peak production, leaving most of the remaining reserves in the politically unstable Middle East. Increasing tensions between Islam and the West are likely to further threaten our access to affordable oil. In desperation, the U.S. and other nations could turn to dirtier fossil-fuels, coal, tar sand, and heavy oil, which will only worsen global warming and imperil the earth's already beleaguered ecosystems. Looming oil shortages make industrial life vulnerable to massive disruptions and possibly even collapse. While the fossil-fuel era is entering its sunset century, a new energy regime is being born that has the potential to remake civilization along radical new lines, according to Rifkin. Hydrogen is the most basic and ubiquitous element in the universe. It is the stuff of the stars and of our sun and, when properly harnessed, it is the &apos

  12. Hydrogen Technology and Energy Curriculum (HyTEC)

    Energy Technology Data Exchange (ETDEWEB)

    Nagle, Barbara

    2013-02-28

    The Lawrence Hall of Science of the University of California, Berkeley has collaborated with scientists and engineers, a local transit agency, school districts, and a commercial curriculum publisher to develop, field-test nationally, and publish a two-week curriculum module on hydrogen and fuel cells for high school science. Key partners in this project are the Schatz Energy Research Center (SERC) of Humboldt State University, the Alameda-Contra Costa Transit District (AC Transit), FilmSight Productions, Lab-Aids, Inc., and 32 teachers and 2,370 students in field-test classrooms in California, Connecticut, Ohio, New York, South Carolina, and Washington. Field-test teachers received two to three days of professional development before teaching the curriculum and providing feedback used for revision of the curriculum. The curriculum, titled Investigating Alternative Energy: Hydrogen and Fuel Cells and published by Lab-Aids, Inc., includes a teachers guide (with lesson plans, resources, and student handout pages), two interactive computer animations, a video, a website, and a laboratory materials kit. The project has been disseminated to over 950 teachers through awareness workshops at state, regional, and national science teacher conferences.

  13. On the dynamics of a wind-hydrogen energy system undergoing a suitable operation planning

    Energy Technology Data Exchange (ETDEWEB)

    Garcia Clua, J.G. [National University of La Plata, Buenos Aires (Argentina). Faculty of Engineering. Lab. de Electronica Industrial, Control e Instrumentacion (LEICI)]. E-mail: jose.garciaclua@ing.unlp.edu.ar; Mantz, R.J. [National University of La Plata, Buenos Aires (Argentina). Scientific Research Commission of the Province of Buenos Aires (CICpBA); Battista, H. de [Consejo Nacional de Investigaciones Cientificas y Tecnicas - CONICET, Buenos Aires (Argentina)

    2008-07-01

    Hydrogen production from renewable energy sources represents a potential solution for sustainable development. However, there are still some barriers to a cost-competitive hydrogen economy. Among other open topics, there is a need for suitable controllers being capable of maximizing the wind energy extraction despite the primary resource variability and, at the same time, of accomplishing the electrolyzer specifications. Several operation strategies have been proposed to cope with these objectives. Nevertheless, the design of dynamic controllers to track a given strategy is a problem less treated in literature, though not less important. For the proper design of such controllers it is necessary to study the inherent properties of the system dynamics. In this context, this paper is devoted to investigate the dynamic behaviour of a wind-hydrogen energy system where the wind turbine is coupled to the electrolyzer through an electronic converter. Particular attention is given to the zero dynamics of the system because of their potential limitations to the operation strategy tracking. It is found that the zero dynamics exhibits interesting phenomena such as bifurcation of equilibria, which mainly appears because of the nonlinearity introduced by the aerodynamic torque. (author)

  14. Integrated photoelectrochemical energy storage: solar hydrogen generation and supercapacitor.

    Science.gov (United States)

    Xia, Xinhui; Luo, Jingshan; Zeng, Zhiyuan; Guan, Cao; Zhang, Yongqi; Tu, Jiangping; Zhang, Hua; Fan, Hong Jin

    2012-01-01

    Current solar energy harvest and storage are so far realized by independent technologies (such as solar cell and batteries), by which only a fraction of solar energy is utilized. It is highly desirable to improve the utilization efficiency of solar energy. Here, we construct an integrated photoelectrochemical device with simultaneous supercapacitor and hydrogen evolution functions based on TiO(2)/transition metal hydroxides/oxides core/shell nanorod arrays. The feasibility of solar-driven pseudocapacitance is clearly demonstrated, and the charge/discharge is indicated by reversible color changes (photochromism). In such an integrated device, the photogenerated electrons are utilized for H(2) generation and holes for pseudocapacitive charging, so that both the reductive and oxidative energies are captured and converted. Specific capacitances of 482 F g(-1) at 0.5 A g(-1) and 287 F g(-1) at 1 A g(-1) are obtained with TiO(2)/Ni(OH)(2) nanorod arrays. This study provides a new research strategy for integrated pseudocapacitor and solar energy application.

  15. Space charge compensation in the Linac4 low energy beam transport line with negative hydrogen ions

    Energy Technology Data Exchange (ETDEWEB)

    Valerio-Lizarraga, Cristhian A., E-mail: cristhian.alfonso.valerio.lizarraga@cern.ch [CERN, Geneva (Switzerland); Departamento de Investigación en Física, Universidad de Sonora, Hermosillo (Mexico); Lallement, Jean-Baptiste; Lettry, Jacques; Scrivens, Richard [CERN, Geneva (Switzerland); Leon-Monzon, Ildefonso [Facultad de Ciencias Fisico-Matematicas, Universidad Autónoma de Sinaloa, Culiacan (Mexico); Midttun, Øystein [CERN, Geneva (Switzerland); University of Oslo, Oslo (Norway)

    2014-02-15

    The space charge effect of low energy, unbunched ion beams can be compensated by the trapping of ions or electrons into the beam potential. This has been studied for the 45 keV negative hydrogen ion beam in the CERN Linac4 Low Energy Beam Transport using the package IBSimu [T. Kalvas et al., Rev. Sci. Instrum. 81, 02B703 (2010)], which allows the space charge calculation of the particle trajectories. The results of the beam simulations will be compared to emittance measurements of an H{sup −} beam at the CERN Linac4 3 MeV test stand, where the injection of hydrogen gas directly into the beam transport region has been used to modify the space charge compensation degree.

  16. Space charge compensation in the Linac4 low energy beam transport line with negative hydrogen ions.

    Science.gov (United States)

    Valerio-Lizarraga, Cristhian A; Lallement, Jean-Baptiste; Leon-Monzon, Ildefonso; Lettry, Jacques; Midttun, Øystein; Scrivens, Richard

    2014-02-01

    The space charge effect of low energy, unbunched ion beams can be compensated by the trapping of ions or electrons into the beam potential. This has been studied for the 45 keV negative hydrogen ion beam in the CERN Linac4 Low Energy Beam Transport using the package IBSimu [T. Kalvas et al., Rev. Sci. Instrum. 81, 02B703 (2010)], which allows the space charge calculation of the particle trajectories. The results of the beam simulations will be compared to emittance measurements of an H(-) beam at the CERN Linac4 3 MeV test stand, where the injection of hydrogen gas directly into the beam transport region has been used to modify the space charge compensation degree.

  17. Space charge compensation in the Linac4 low energy beam transport line with negative hydrogen ions

    Science.gov (United States)

    Valerio-Lizarraga, Cristhian A.; Lallement, Jean-Baptiste; Leon-Monzon, Ildefonso; Lettry, Jacques; Midttun, Øystein; Scrivens, Richard

    2014-02-01

    The space charge effect of low energy, unbunched ion beams can be compensated by the trapping of ions or electrons into the beam potential. This has been studied for the 45 keV negative hydrogen ion beam in the CERN Linac4 Low Energy Beam Transport using the package IBSimu [T. Kalvas et al., Rev. Sci. Instrum. 81, 02B703 (2010)], which allows the space charge calculation of the particle trajectories. The results of the beam simulations will be compared to emittance measurements of an H- beam at the CERN Linac4 3 MeV test stand, where the injection of hydrogen gas directly into the beam transport region has been used to modify the space charge compensation degree.

  18. Offshore wind potential in Libya: possibilities for strategic plans for hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    El-Osta, W.; Khalifa, Y. [Center for Solar Energy Studies, Tripoli (Libya)

    2002-07-01

    In Libya the wind potential, in-land, probably is not very high. The wind speed on the coast ranges between 5.5am/s and 7.9am/s at 10am a.g.l. in regions of roughness class 1. The wind potential offshore is not assessed yet. Unfortunately, there are no real measurements at sea. WAsP software was used to assess the wind potential at the Mediterranean sea at distances close to the coast. So wind data from the 9-Meteorological stations exist .on the coast was used and was extrapolated to offshore region. The results revealed that the wind speed offshore ranges between 6.8am/s and 8.9am/s at 10am height and from 8am/s to 10.4am/s at 50am height. Consequently the available power ranges from 435aw/m{sup 2} to 1483aw/m{sup 2} at 10am height and from 661aw/m{sup 2} to 2242aw/m{sup 2} at 50am height.The population density in Libya, with respect to the total area, is very low compared to other regions ( 2.9apersons/km{sup 2}). The energy demand is growing very fast through the last several years, and if the wind potential in-land was exploited; even with this fast growing electric energy demand, it could be more than sufficient to meet this demand (ignoring technical and economic constrains and other limitations). But the wind potential at the sea would be, for sure, much greater than that inland. Since the wind potential still has not been exploited, it might be beneficial to exploite the wind potential offshore for the following reasons: The wind potential is higher than the potential in-land. To solve the future expected problems of water-shortages in some regions by water desalination using wind power. Use wind power, and probably other solar technologies, to produce hydrogen for local supply ofahydrogen energy and for export to European countries. This paper will assess the wind potential offshore in Libya and will discuss the possibility of hydrogen production for local consumption and hydrogen export to Europe. The technical and financial problems and costraints that

  19. The birth, growth, and share of a new market in the world and in Turkey: ‘Hydrogen energy and hydrogen technology products’ market

    Directory of Open Access Journals (Sweden)

    Nurcan Kılınç

    2007-08-01

    Full Text Available While the needs for energy continuously increase, the searches for new energy sources are also intensified. In the last hundred or hundred and fifty years, there has been a gradual shift from coal to petroleum, and from petroleum to natural gas. This transition process to alternative energies is expected to continue. The next phase is expected to be the ‘hydrogen’ as the source of primary energy in the near future. It is estimated that the current energy sources such as petroleum and natural gas last for about 60 years. However, there is an ongoing research and development (R&D activities focused on alternative energy sources. At present, hydrogen energy looks the closest alternative to be used because of variety of reasons. The existing fossil fuels (coal, petroleum, and natural gas has limited potential but hydrogen has unlimited production capability, it can be transferred easily and safely, and can be used in variety of different areas including industry, residential and transportation. It is also safe, clean and environmentally friendly. All these features have made hydrogen energy as one of the most popular sources of energy for the future. World’s leading firms and research institutions have focused on R&D activities and have spent considerable financial resources and efforts in order to catch or lead the developments in the area regarding the existing technological developments in the area and size of the market potential in the world. Leading countries have taken role in the process of technology development with considerable financial supports. Even at present, the market has reached to a considerable size, into which many national and international companies have launched variety of products. In such conditions, many countries and firms are trying hard to have the largest share from it. This study investigates the birth, growth, and share of the world and Turkish hydrogen markets with respect to the current literature.

  20. The birth, growth, and share of a new market in the world and in Turkey: ‘Hydrogen energy and hydrogen technology products’ market

    Directory of Open Access Journals (Sweden)

    Cihat Polat

    2007-08-01

    Full Text Available While the needs for energy continuously increase, the searches for new energy sources are also intensified. In the last hundred or hundred and fifty years, there has been a gradual shift from coal to petroleum, and from petroleum to natural gas. This transition process to alternative energies is expected to continue. The next phase is expected to be the ‘hydrogen’ as the source of primary energy in the near future. It is estimated that the current energy sources such as petroleum and natural gas last for about 60 years. However, there is an ongoing research and development (R&D activities focused on alternative energy sources. At present, hydrogen energy looks the closest alternative to be used because of variety of reasons. The existing fossil fuels (coal, petroleum, and natural gas has limited potential but hydrogen has unlimited production capability, it can be transferred easily and safely, and can be used in variety of different areas including industry, residential and transportation. It is also safe, clean and environmentally friendly. All these features have made hydrogen energy as one of the most popular sources of energy for the future. World’s leading firms and research institutions have focused on R&D activities and have spent considerable financial resources and efforts in order to catch or lead the developments in the area regarding the existing technological developments in the area and size of the market potential in the world.  Leading countries have taken role in the process of technology development with considerable financial supports. Even at present, the market has reached to a considerable size, into which many national and international companies have launched variety of products.  In such conditions, many countries and firms are trying hard to have the largest share from it. This study investigates the birth, growth, and share of the world and Turkish hydrogen markets with respect to the current literature.

  1. Mg-based compounds for hydrogen and energy storage

    NARCIS (Netherlands)

    Crivello, J. -C.; Denys, R. V.; Dornheim, M.; Felderhoff, M.; Grant, D. M.; Huot, J.; Jensen, T. R.; de Jongh, P.|info:eu-repo/dai/nl/186125372; Latroche, M.; Walker, G. S.; Webb, C. J.; Yartys, V. A.

    Magnesium-based alloys attract significant interest as cost-efficient hydrogen storage materials allowing the combination of high gravimetric storage capacity of hydrogen with fast rates of hydrogen uptake and release and pronounced destabilization of the metal–hydrogen bonding in comparison with

  2. Wind energy in China: Estimating the potential

    Science.gov (United States)

    Yuan, Jiahai

    2016-07-01

    Persistent and significant curtailment has cast concern over the prospects of wind power in China. A comprehensive assessment of the production of energy from wind has identified grid-integrated wind generation potential at 11.9-14% of China's projected energy demand by 2030.

  3. H2 at Scale: Benefitting our Future Energy System - Update for the Hydrogen Technical Advisory Committee

    Energy Technology Data Exchange (ETDEWEB)

    Ruth, Mark

    2016-12-06

    Hydrogen is a flexible, clean energy carrying intermediate that enables aggressive market penetration of renewables while deeply decarbonizing our energy system. H2 at Scale is a concept that supports the electricity grid by utilizing energy without other demands at any given time and also supports transportation and industry by providing low-priced hydrogen to them. This presentation is an update to the Hydrogen Technical Advisory Committee (HTAC).

  4. Hydrogen sulfide: physiological properties and therapeutic potential in ischaemia.

    Science.gov (United States)

    Bos, Eelke M; van Goor, Harry; Joles, Jaap A; Whiteman, Matthew; Leuvenink, Henri G D

    2015-03-01

    Hydrogen sulfide (H2 S) has become a molecule of high interest in recent years, and it is now recognized as the third gasotransmitter in addition to nitric oxide and carbon monoxide. In this review, we discuss the recent literature on the physiology of endogenous and exogenous H2 S, focusing upon the protective effects of hydrogen sulfide in models of hypoxia and ischaemia.

  5. Accurate global potential energy surface for the H + OH+ collision

    Science.gov (United States)

    Gannouni, M. A.; Jaidane, N. E.; Halvick, P.; Stoecklin, T.; Hochlaf, M.

    2014-05-01

    We mapped the global three-dimensional potential energy surface (3D-PES) of the water cation at the MRCI/aug-cc-pV5Z including the basis set superposition (BSSE) correction. This PES covers the molecular region and the long ranges close to the H + OH+(X3Σ-), the O + H2+(X2Σg+), and the hydrogen exchange channels. The quality of the PES is checked after comparison to previous experimental and theoretical results of the spectroscopic constants of H2O+(tilde X2B1) and of the diatomic fragments, the vibronic spectrum, the dissociation energy, and the barrier to linearity for H2O+(tilde X2B1). Our data nicely approach those measured and computed previously. The long range parts reproduce quite well the diatomic potentials. In whole, a good agreement is found, which validates our 3D-PES.

  6. Autonomous energy technological complex with hydrogen as the secondary energy carrier

    Energy Technology Data Exchange (ETDEWEB)

    Muminov, M.; Zakhidov, R. [AN Uzbekskoj SSR, Tashkent (Uzbekistan). Inst. Yadernoj Fiziki; Basteev, A.; Bazima, L. [Zhukovsky National Aerospace Univ. ' ' Kharkov Aviation Inst.' ' , Kharkov (Ukraine); Rashkovan, V. [Inst. Politecnico Nacional de Mexico, SEPI, Culhucan, La Escuela Superior de Ingenieria Mecanica Y Electrica (Mexico); Solovey, V.; Prognimak, A. [Podgorny Inst. of Mechanical Engineering Problems, National Academy of Sciences, Kharkov (Ukraine); Glazkov, V.; Golubenko, N. [Yangel State Design Office ' ' YUZHNOYE' ' (Ukraine)

    2001-07-01

    The energy-technological complex (ETC) destination is the transforming of primary sun/wind energy into electric one as well the sub-products fabrication. The ETC consists of the following constituent elements that should be characterized by the harmonized parameters: wind power station, photo-voltaic transformer, distiller, fuel cell, hydrogen and oxygen generator like the electrolyzer and compressed gases storing and supply system (SSS). The hydrogen and oxygen are generated in the electrolyzer and stored in the SSS and then used in fuel cell for standard electric energy generation. The desalination of seawater and sea salt yielding is the ETC output as well. The base ETC configuration with power 6 - 10 kW are considered. The operational peculiarities of ETC constituent element are considered as well. The creation and operational demonstration of the autonomous ETC are supported by STCU (projectaUZB-23j). (orig.)

  7. Schematic potential energy for interaction between isobutene and zeolite mordenite

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Serrano, L A [Programa de Crudo Maya, IMP, AP 15-805, DF 07730 (Mexico); Flores-Sandoval, C A [Programa de Crudo Maya, IMP, AP 15-805, DF 07730 (Mexico); Zaragoza, I P [Programa de Ingenieria Molecular, IMP, AP 15-805, DF 07730 (Mexico)

    2004-06-09

    A schematic representation of the potential energy for the interaction between isobutene and H mordenite was presented by using eight different positions (P1-P8) of C{sub 1} or C{sub 2} atoms located in front of the acid hydrogen (H{sup +}). In all cases a {pi} complex was formed yielding different values of the adsorption energy. In some cases of the adsorption point in P1-P8 the frontier orbitals are shown. The P8 position exhibits the highest value obtained for the adsorption energy, where the C{sub 1} atom is in front of the H{sup +}. Calculations were of all electron type employing HF/6-31G**.

  8. Timing of potential and metabolic brain energy

    DEFF Research Database (Denmark)

    Korf, Jakob; Gramsbergen, Jan Bert

    2007-01-01

    The temporal relationship between cerebral electro-physiological activities, higher brain functions and brain energy metabolism is reviewed. The duration of action potentials and transmission through glutamate and GABA are most often less than 5 ms. Subjects may perform complex psycho-physiologic......The temporal relationship between cerebral electro-physiological activities, higher brain functions and brain energy metabolism is reviewed. The duration of action potentials and transmission through glutamate and GABA are most often less than 5 ms. Subjects may perform complex psycho...... functions. We introduce the concepts of potential and metabolic brain energy to distinguish trans-membrane gradients of ions or neurotransmitters and the capacity to generate energy from intra- or extra-cerebral substrates, respectively. Higher brain functions, such as memory retrieval, speaking...

  9. Carbamoylation abrogates the antioxidant potential of hydrogen sulfide.

    Science.gov (United States)

    Praschberger, Monika; Hermann, Marcela; Laggner, Christian; Jirovetz, Leopold; Exner, Markus; Kapiotis, Stylianos; Gmeiner, Bernhard M K; Laggner, Hilde

    2013-11-01

    Hydrogen sulfide (H2S) has been identified as the third gasotransmitter. Beside its role as signaling molecule in the cardiovascular and nervous system the antioxidant and cyto-protective properties of H2S have gained much attention. In the present study we show that cyanate, an uremic toxin which is found in abundant concentration in sera of patients suffering from chronic kidney disease (CKD), can abrogate the antioxidant and cytoprotective activity of H2S via S-carbamoylation reaction, a reaction that previously has only been shown to have a physiological effect on cysteine groups, but not on H2S. Carbamoylation strongly inhibited the free radical scavenging (ABTS(+·) and alkylperoxyl ROO(·)) properties of H2S. The extent of intracellular ROS formation induced by ROO(·) was diminished by H2S whereas carbamoylation counteracted the protective effect. Reagent HOCl was rapidly inactivated by H2S in contrast to the carbamoylated compound. Protein modification by HOCl was inhibited by H2S but carbamoylation significantly reduced the effect. Thus, S-carbamoylation of low molecular weight thiols by abrogating their antioxidant potential may contribute to the higher oxidative stress observed in CKD.

  10. Biochemistry and therapeutic potential of hydrogen sulfide - reality or fantasy?

    Science.gov (United States)

    Brodek, Paulina; Olas, Beata

    2016-08-11

    Hydrogen sulfide (H2S) is a signaling gasotransmitter, involved in different physiological and pathological processes. H2S regulates apoptosis, the cell cycle and oxidative stress. H2S exerts powerful effects on smooth muscle cells, endothelial cells, inflammatory cells, endoplasmic reticulum, mitochondria and nuclear transcription factors. H2S is known to be produced from L-cysteine, D-cysteine and L-homocysteine in the body. Four enzymes - cystathionine-b synthase (CBS), mercaptopyruvate sulfurtransferase (3-MST), cystathionine-γ lyase (CSE) and cysteine aminotransferase (CAT) - are involved in H2S synthesis. The biosynthetic pathway for the production of H2S from D-cysteine involves 3-MST and D-amino acid oxidase (DAO). The therapeutic potential of H2S is not clear. However, recently results have demonstrated that H2S has protective action for ischemic heart disease or hypertension, and protects against ischemia of the brain. This review summarizes the negative and the positive roles of H2S in various biological systems, for example the cardiovascular system and nervous system. We also discuss the function of classical, therapeutic and natural (for example garlic) donors of H2S in pre-clinical and clinical studies.

  11. Estimation of Intramolecular Hydrogen-bonding Energy via the Substitution Method

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The intramolecular hydrogen-bonding energies for eighteen molecules were calculated based on the substitution method, and compared with those predicted by the cis-trans method.The energy values obtained from two methods are close to each other with a correlation coefficient of 0.96.Furthermore, the hydrogen-bonding energies based on the substitution method are consistent with the geometrical features of intramolecular hydrogen bonds.Both of them demonstrate that the substitution method is capable of providing a good estimation of intramolecular hydrogen-bonding energy.

  12. Bohm's Quantum Potential as an Internal Energy

    OpenAIRE

    Dennis, Glen; De Gosson, Maurice,; Hiley, Basil

    2014-01-01

    We pursue our discussion of Fermi's surface initiated in Dennis, de Gosson and Hiley and show that Bohm's quantum potential can be viewed as an internal energy of a quantum system. This gives further insight into the role it played by the quantum potential in stationary states. It also allows us to provide a physically motivated derivation of Schr\\"odinger's equation for a particle in an external potential.

  13. Macro-System Model for Hydrogen Energy Systems Analysis in Transportation: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Diakov, V.; Ruth, M.; Sa, T. J.; Goldsby, M. E.

    2012-06-01

    The Hydrogen Macro System Model (MSM) is a simulation tool that links existing and emerging hydrogen-related models to perform rapid, cross-cutting analysis. It allows analysis of the economics, primary energy-source requirements, and emissions of hydrogen production and delivery pathways.

  14. Development of a Hydrogen Energy System as a Grid Frequency Management Tool

    Energy Technology Data Exchange (ETDEWEB)

    Ewan, Mitch [Univ. of Hawaii, Honolulu, HI (United States); Rocheleau, Richard [Univ. of Hawaii, Honolulu, HI (United States); Swider-Lyons, Karen [U.S. Naval Research Lab., Washington, DC (United States); Virji, Meheboob [GRandalytics, Honolulu, HI (United States); Randolph, Guenter [Hydrogen Renewable Energy System Analysis, Pickering, ON (Canada)

    2016-07-15

    The Hawai‘i Natural Energy Institute (HNEI) is conducting research to assess the technical potential of using an electrolyzer-based hydrogen (H2) production and storage system as a grid demand response tool using battery data from a 200 MW grid to show the kind of response required. The hydrogen produced by the electrolyzer is used for transportation. A 65 kg/day hydrogen energy system (HES) consisting of a PEM electrolyzer, 35 bar buffer tank, 450 bar compressor, and associated chiller systems was purchased and installed at the Hawaii Natural Energy Laboratory Hawaii Authority (NELHA) to demonstrate long-term durability of the electrolyzer under cyclic operation required for frequency regulation on an island grid system. The excess hydrogen was stored for use by three fuel-cell buses to be operated at Hawai‘i Volcanoes National Park (HAVO) and by the County of Hawai‘i Mass Transit Agency (MTA). This paper describes the site selection and equipment commissioning, plus a comprehensive test plan that was developed to characterize the performance and durability of the electrolyzer under dynamic load conditions. The controls were modified for the operating envelope and dynamic limits of the electrolyzer. While the data showed these modifications significantly improved the system response time, it is not fast enough to match a BESS response time for grid frequency management. The electrolyzer can only be used for slower acting changes (1 to 0.5 Hz). A potential solution is to design an electrolyzer/BESS hybrid system and develop a modeling program to find the optimum mix of battery and electrolyzer to provide the maximum grid regulation services at minimum cost.

  15. Nordic hydrogen energy foresight - challenges of managing the interactive process

    DEFF Research Database (Denmark)

    Eerola, A.; Loikkanen, T.; Koljonen, T.

    2005-01-01

    of the project in the light of a dynamic model ofshared knowledge creation. In particular, the ways in which the design and the methodological tools facilitated the process and its management are discussed. Some suggestions for forthcoming foresight exercises are also presented....... decision support for companies and research institutes in defining their R&D priorities and to assist governmental decisionmakers in making effectiveframework policies for successful introduction of hydrogen energy. Development of Nordic networks to gain the required critical mass in wider international...... contexts was considered equally important. The overall intention was to contribute to the strategicintelligence of the Nordic knowledge region in issues related to wellbeing and sustainable developments. The paper examines the rationale behind the project design and the contribution of the various steps...

  16. Why hydrogen; Pourquoi l'hydrogene?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-02-01

    The energy consumption increase and the associated environmental risks, led to develop new energy sources. The authors present the potentialities of the hydrogen in this context of energy supply safety. They detail the today market and the perspectives, the energy sources for the hydrogen production (fossils, nuclear and renewable), the hydrogen transport, storage, distribution and conversion, the application domains, the associated risks. (A.L.B.)

  17. Why hydrogen; Pourquoi l'hydrogene?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-02-01

    The energy consumption increase and the associated environmental risks, led to develop new energy sources. The authors present the potentialities of the hydrogen in this context of energy supply safety. They detail the today market and the perspectives, the energy sources for the hydrogen production (fossils, nuclear and renewable), the hydrogen transport, storage, distribution and conversion, the application domains, the associated risks. (A.L.B.)

  18. Hydrogen

    Directory of Open Access Journals (Sweden)

    John O’M. Bockris

    2011-11-01

    Full Text Available The idea of a “Hydrogen Economy” is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO2 in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H2 from the electrolyzer. Methanol made with CO2 from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan. Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech.

  19. Hydrogen and Biofuels - A Modeling Analysis of Competing Energy Carriers for Western Europe

    Energy Technology Data Exchange (ETDEWEB)

    Guel, Timur; Kypreos, Socrates; Barreto, Leonardo

    2007-07-01

    This paper deals with the prospects of hydrogen and biofuels as energy carriers in the Western European transportation sector. The assessment is done by combining the US hydrogen analysis H2A models for the design of hydrogen production and delivery chains, and the Western European Hydrogen Markal Model EHM with a detailed representation of biofuels, and the European electricity and transportation sector. The paper derives policy recommendations to support the market penetration of hydrogen and biofuels, and investigates learning interactions between the different energy carriers. (auth)

  20. One million ton of hydrogen is the key piece in the Danish renewable energy puzzle

    DEFF Research Database (Denmark)

    Grandal, Rune Duban; Mathiesen, Brian Vad; Connolly, David

    2013-01-01

    production is 1:1. If so, the main task is direct balancing between the surplus and the deficit, making hydro storage a potential alternative. However, the biomass demand in this situation is much above the sustainable biomass potential. To reduce the biomass dependency from this level down to a level of 200...... PJ/year, the production of wind power has to be increased to a level of surplus electricity of almost 150 PJ/year in order to ensure sufficient quantities of hydrogen for the hydrocarbon demand. At this high electricity surplus, the ratio between deficit and surplus becomes 1:20. In such a situation......Designing a 100 % renewable energy system (RES) for Denmark, the availability of a sustainable biomass resource potential is found to be a limiting factor. The biomass demand derives from specific needs in the system, i.e. 1) storable fuel for energy for balancing fluctuating power production, 2...

  1. Nitrogen-doped fullerene as a potential catalyst for hydrogen fuel cells.

    Science.gov (United States)

    Gao, Feng; Zhao, Guang-Lin; Yang, Shizhong; Spivey, James J

    2013-03-06

    We examine the possibility of nitrogen-doped C60 fullerene (N-C60) as a cathode catalyst for hydrogen fuel cells. We use first-principles spin-polarized density functional theory calculations to simulate the electrocatalytic reactions on N-C60. The first-principles results show that an O2 molecule can be adsorbed and partially reduced on the N-C complex sites (Pauling sites) of N-C60 without any activation barrier. Through a direct pathway, the partially reduced O2 can further react with H(+) and additional electrons and complete the water formation reaction (WFR) with no activation energy barrier. In the indirect pathway, reduced O2 reacts with H(+) and additional electrons to form H2O molecules through a transition state (TS) with a small activation barrier (0.22-0.37 eV). From an intermediate state to a TS, H(+) can obtain a kinetic energy of ∼0.95-3.68 eV, due to the Coulomb electric interaction, and easily overcome the activation energy barrier during the WFR. The full catalytic reaction cycles can be completed energetically, and N-C60 fullerene recovers to its original structure for the next catalytic reaction cycle. N-C60 fullerene is a potential cathode catalyst for hydrogen fuel cells.

  2. A new method for screening potential sII and sH hydrogen clathrate hydrate promoters with model potentials.

    Science.gov (United States)

    Frankcombe, Terry J; Kroes, Geert-Jan

    2011-08-01

    A new predictive computational method for classifying clathrate hydrate promoter molecules is presented, based on the interaction energies between potential promoters and the water networks of sII and sH clathrates. The motivation for this work is identifying promoters for storing hydrogen compactly in clathrate hydrates. As a first step towards achieving this goal, we have developed a general method aimed at distinguishing between molecules that form sII clathrate hydrates and molecules that can-together with a weakly interacting help gas-form sH clathrate hydrates. The new computational method calculates differences in estimated formation energies of the sII and the sH clathrate hydrate. Model interaction potentials have been used, including the electrostatic interactions with newly calculated partial charges for all the considered potential promoter molecules. The methodology can discriminate between the clathrate structure types (sII or sH) formed by each potential promoter with good selectivity, i.e., better than achieved with a simple van der Waals diameter criterion.

  3. Energy conversion performance of black liquor gasification to hydrogen production using direct causticization with CO(2) capture.

    Science.gov (United States)

    Naqvi, M; Yan, J; Dahlquist, E

    2012-04-01

    This paper estimates potential hydrogen production via dry black liquor gasification system with direct causticization integrated with a reference pulp mill. The advantage of using direct causticization is elimination of energy intensive lime kiln. Pressure swing adsorption is integrated in the carbon capture process for hydrogen upgrading. The energy conversion performance of the integrated system is compared with other bio-fuel alternatives and evaluated based on system performance indicators. The results indicated a significant hydrogen production potential (about 141MW) with an energy ratio of about 0.74 from the reference black liquor capacity (about 243.5MW) and extra biomass import (about 50MW) to compensate total energy deficit. About 867,000tonnes of CO(2) abatement per year is estimated i.e. combining CO(2) capture and CO(2) offset from hydrogen replacing motor gasoline. The hydrogen production offers a substantial motor fuel replacement especially in regions with large pulp and paper industry e.g. about 63% of domestic gasoline replacement in Sweden. Copyright © 2012 Elsevier Ltd. All rights reserved.

  4. Risø energy report 3. Hydrogen and its competitors

    DEFF Research Database (Denmark)

    Larsen, Hans Hvidtfeldt; Sønderberg Petersen, Leif

    2004-01-01

    Interest in the hydrogen economy has grown rapidly in recent years. Those countries with long traditions of activity in hydrogen research and development have now been joined by a large number of newcomers. The main reason for this surge of interest isthat the hydrogen economy may be an answer...

  5. Energy Transfer in Scattering by Rotating Potentials

    Indian Academy of Sciences (India)

    Volker Enss; Vadim Kostrykin; Robert Schrader

    2002-02-01

    Quantum mechanical scattering theory is studied for time-dependent Schrödinger operators, in particular for particles in a rotating potential. Under various assumptions about the decay rate at infinity we show uniform boundedness in time for the kinetic energy of scattering states, existence and completeness of wave operators, and existence of a conserved quantity under scattering. In a simple model we determine the energy transferred to a particle by collision with a rotating blade.

  6. Alternative energies: Engineering, economics, market potential

    Energy Technology Data Exchange (ETDEWEB)

    Hake, B.

    1981-11-01

    Rentability calculations are disappointing for most alternative energies. Technical improvements that might change this are not in sight, so that the dependence on imported oil and gas will hardly be reduced. Producers of solar collectors, heat pumps, solar cells, and cogeneration units must keep in mind that the market will hardly expand. This was the result of a seminar on 'Alternative energy sources: Technology, economics, marketing potential - a critical review', held on May 5 at Haus der Technik, Essen.

  7. Molecular hydrogen: An abundant energy source for bacterial activity in nuclear waste repositories

    Science.gov (United States)

    Libert, M.; Bildstein, O.; Esnault, L.; Jullien, M.; Sellier, R.

    A thorough understanding of the energy sources used by microbial systems in the deep terrestrial subsurface is essential since the extreme conditions for life in deep biospheres may serve as a model for possible life in a nuclear waste repository. In this respect, H 2 is known as one of the most energetic substrates for deep terrestrial subsurface environments. This hydrogen is produced from abiotic and biotic processes but its concentration in natural systems is usually maintained at very low levels due to hydrogen-consuming bacteria. A significant amount of H 2 gas will be produced within deep nuclear waste repositories, essentially from the corrosion of metallic components. This will consequently improve the conditions for microbial activity in this specific environment. This paper discusses different study cases with experimental results to illustrate the fact that microorganisms are able to use hydrogen for redox processes (reduction of O 2, NO3-, Fe III) in several waste disposal conditions. Consequences of microbial activity include: alteration of groundwater chemistry and shift in geochemical equilibria, gas production or consumption, biocorrosion, and potential modifications of confinement properties. In order to quantify the impact of hydrogen bacteria, the next step will be to determine the kinetic rate of the reactions in realistic conditions.

  8. Ultrasonic assisted synthesis of Bikitaite zeolite: A potential material for hydrogen storage application.

    Science.gov (United States)

    Roy, Priyanka; Das, Nandini

    2017-05-01

    Li containing Bikitaite zeolite has been synthesized by an ultrasound-assisted method and used as a potential material for hydrogen storage application. The Sonication energy was varied from 150W to 250W and irradiation time from 3h to 6h. The Bikitaite nanoparticles were characterized by X-ray diffraction (XRD), infrared (IR) spectral analysis, and field-emission scanning electron microscopy (FESEM) thermo-gravimetrical analysis and differential thermal analysis (TGA, DTA). XRD and IR results showed that phase pure, nano crystalline Bikitaite zeolites were started forming after 3h irradiation and 72h of aging with a sonication energy of 150W and nano crystalline Bikitaite zeolite with prominent peaks were obtained after 6h irradiation of 250W sonic energy. The Brunauer-Emmett-Teller (BET) surface area of the powder by N2 adsorption-desorption measurements was found to be 209m(2)/g. The TEM micrograph and elemental analysis showed that desired atomic ratio of the zeolite was obtained after 6h irradiation. For comparison, sonochemical method, followed by the hydrothermal method, with same initial sol composition was studied. The effect of ultrasonic energy and irradiation time showed that with increasing sonication energy, and sonication time phase formation was almost completed. The FESEM images revealed that 50nm zeolite crystals were formed at room temperature. However, agglomerated particles having woollen ball like structure was obtained by sonochemical method followed by hydrothermal treatment at 100°C for 24h. The hydrogen adsorption capacity of Bikitaite zeolite with different Li content, has been investigated. Experimental results indicated that the hydrogen adsorption capacities were dominantly related to their surface areas as well as total pore volume of the zeolite. The hydrogen adsorption capacity of 143.2c.c/g was obtained at 77K and ambient pressure of (0.11MPa) for the Bikitaite zeolite with 100% Li, which was higher than the reported values for

  9. Hydrogen energy recovery from high strength organic wastewater with ethanol type fermentation using acidogenic EGSB reactor

    Institute of Scientific and Technical Information of China (English)

    REN Nan-qi; GUO Wan-qian; WANG Xiang-jing; ZHANG Lu-si

    2005-01-01

    A lab-scale expanded granular sludge bed (EGSB) reactor was employed to evaluate the feasibility of the hydrogen energy recovery potential from high strength organic wastewater. The results showed that a maxioperation. At the acidogenic phase, COD removal rate was stable at about 15%. In the steady operation peri od, the main liquid end products were ethanol and acetic acid, which represented ethanol type fermentation. Among the liquid end products, the concentration percentage of ethanol and acetic acid amounted to 69.5% ~89.8% and the concentration percentage of ethanol took prominent about 51.7% ~ 59.1%, which is better than the utilization of substrate for the methanogenic bacteria. An ethanol type fermentation pathway was suggested in the operation of enlarged industrial continuous hydrogen bio-producing reactors.

  10. What is required to make hydrogen a real energy carrier option?

    Energy Technology Data Exchange (ETDEWEB)

    Braeuninger, S.; Schindler, G.; Schwab, E.; Weck, A. [BASF SE, Ludwigshafen (Germany)

    2010-12-30

    The driver for the introduction of hydrogen as mobile energy-carrier is regulatory measures to avoid the CO{sub 2} emissions which are related to the current fossil carbon based situation. H{sub 2} is a large volume chemical product with an annual production of about 45 million tons, most of which currently is also derived from fossil sources. The German transport sector consumes 2,6.10{sup 12} MJ/a which in terms of energy is equivalent to nearly 50% of the current world hydrogen production. There is the proposal to start the ''hydrogen economy'' with ''excess H{sub 2}'' which is believed to be available as inadvertently occurring byproduct of chemical processes. A potential {proportional_to}2 million tons is estimated for this ''excess H{sub 2}'' in Europe; the proposal however does not take into account, that current uses of this H{sub 2} would have to be substituted. Therefore, an overall gain for the environment cannot be expected. Therefore, a sustainable hydrogen based energy scenario has to rely on new sources. Besides Biomass gasification which in terms of technology would resemble the conventional fossil based hydrogen production, the only other viable carbon-free hydrogen source is water, which has to be split into its constituting elements. The current paper is restricted to the latter path, the feasibility of the biomass approach needs to be discussed elsewhere. If hypothetically the above mentioned energy for the German transport sector would be provided by H{sub 2} from water electrolysis an electricity input of 4.10{sup 12} MJ would be needed. This number exceeds the currently installed German wind turbine capacity by a factor of 6 and even by a factor of 36, if the weather-based {proportional_to}16% year-round on-stream factor for onshore plants is taken into account. (orig.)

  11. Final Technical Report: Hydrogen Energy in Engineering Education (H2E3)

    Energy Technology Data Exchange (ETDEWEB)

    Lehman, Peter A.; Cashman, Eileen; Lipman, Timothy; Engel, Richard A.

    2011-09-15

    Schatz Energy Research Center's Hydrogen Energy in Engineering Education curriculum development project delivered hydrogen energy and fuel cell learning experiences to over 1,000 undergraduate engineering students at five California universities, provided follow-on internships for students at a fuel cell company; and developed commercializable hydrogen teaching tools including a fuel cell test station and a fuel cell/electrolyzer experiment kit. Monitoring and evaluation tracked student learning and faculty and student opinions of the curriculum, showing that use of the curriculum did advance student comprehension of hydrogen fundamentals. The project web site (hydrogencurriculum.org) provides more information.

  12. Energy potential of fruit tree pruned biomass in Croatia

    Energy Technology Data Exchange (ETDEWEB)

    Bilandzija, N.; Voca, N.; Kricka, T.; Martin, A.; Jurisic, V.

    2012-11-01

    The world's most developed countries and the European Union (EU) deem that the renewable energy sources should partly substitute fossil fuels and become a bridge to the utilization of other energy sources of the future. This paper will present the possibility of using pruned biomass from fruit cultivars. It will also present the calculation of potential energy from the mentioned raw materials in order to determine the extent of replacement of non-renewable sources with these types of renewable energy. One of the results of the intensive fruit-growing process, in post pruning stage, is large amount of pruned biomass waste. Based on the calculated biomass (kg ha{sup 1}) from intensively grown woody fruit crops that are most grown in Croatia (apple, pear, apricots, peach and nectarine, sweet cherry, sour cherry, prune, walnut, hazelnut, almond, fig, grapevine, and olive) and the analysis of combustible (carbon 45.55-49.28%, hydrogen 5.91-6.83%, and sulphur 0.18-0.21%) and non-combustible matters (oxygen 43.34-46.6%, nitrogen 0.54-1.05%, moisture 3.65-8.83%, ashes 1.52-5.39%) with impact of lowering the biomass heating value (15.602-17.727 MJ kg{sup 1}), the energy potential of the pruned fruit biomass is calculated at 4.21 PJ. (Author) 31 refs.

  13. Production systems and energy potential of tidal energy

    Directory of Open Access Journals (Sweden)

    Julián Rodrigo Quintero-González

    2016-01-01

    Full Text Available This article discusses the concept of tidal power and distinguishes the types of systems to exploitation the tidal energy; the same way; it also shows how this technology serves as a source of energy in some countries around the world, which is a role associated with the energy potential available in each region. This point equally shows through numbers in GWh/year per km2 reservoir surface. Last but not least, it is the influence that this technology has had on the environment, its contributions for improving and evaluating from an environmental point of view.

  14. Potential of hydrogen bond in water. Comparison of the theory with vibrational spectra and results of molecular dynamics simulations.

    Science.gov (United States)

    Efimov, Yuri Ya; Naberukhin, Yuri I

    2011-02-01

    Potential of hydrogen bond is the function which relates its energy to geometrical parameters of hydrogen bridge: its length R(O…O) and angles between direction O…O and OH group [φ (H-O…O)] and/or lone pair of proton accepting oxygen atom [χ(-O…O)]. Previously we have suggested an approach to design such potentials based on the approximate numerical solution of a reverse problem of the spectrum band shape in the frames of the fluctuation theory of hydrogen bonding. In the given work this method is applied to construction of the two-parameter potentials that depend on parameters {R(O…O), φ (H-O…O} or {φ (H-O…O), χ (-O…O)}. Using them, the spectra of OH vibrations of HOD molecules in a liquid phase are calculated theoretically in good agreement with experiment in the temperature range up to 200 °C. Distributions of angles P(φ, T), P(χ, T), and energies P(E) are calculated also. The same distributions and spectra are independently calculated on the basis of the geometrical parameters of the hydrogen bridges obtained from molecular dynamics models of water. The shapes of the spectral contours and their temperature evolution calculated for computer models turned out to be similar to experimental ones only for the potential that includes the length of H-bond R(O…O).

  15. Effect of chemical potential on the computer simulation of hydrogen storage in single walled carbon nanotubes

    Institute of Scientific and Technical Information of China (English)

    ZHENG; Hong; WANG; Shaoqing; CHENG; Huiming

    2004-01-01

    Grand canonical Monte Carlo molecular simulations were carried out for hydrogen adsorption in single-walled carbon nanotubes. It was found that variations in chemical potential may result in a great change in the hydrogen storage capacity of single-walled carbon nanotubes. Hydrogen adsorption isotherms of single-walled carbon nanotubes at 298.15 K were calculated using a modified chemical potential, and the result obtained is closer to the experimental results. By comparing the experimental and simulation results, it is proposed that chemical adsorption may exist for hydrogen adsorption in single-walled carbon nanotubes.

  16. Thermodynamic analysis of alternate energy carriers, hydrogen and chemical heat pipes

    Science.gov (United States)

    Cox, K. E.; Carty, R. H.; Conger, W. L.; Soliman, M. A.; Funk, J. E.

    1976-01-01

    Hydrogen and chemical heat pipes were proposed as methods of transporting energy from a primary energy source (nuclear, solar) to the user. In the chemical heat pipe system, primary energy is transformed into the energy of a reversible chemical reaction; the chemical species are then transmitted or stored until the energy is required. Analysis of thermochemical hydrogen schemes and chemical heat pipe systems on a second law efficiency or available work basis show that hydrogen is superior especially if the end use of the chemical heat pipe is electrical power.

  17. Thermodynamic analysis of alternate energy carriers, hydrogen and chemical heat pipes

    Science.gov (United States)

    Cox, K. E.; Carty, R. H.; Conger, W. L.; Soliman, M. A.; Funk, J. E.

    1976-01-01

    Hydrogen and chemical heat pipes were proposed as methods of transporting energy from a primary energy source (nuclear, solar) to the user. In the chemical heat pipe system, primary energy is transformed into the energy of a reversible chemical reaction; the chemical species are then transmitted or stored until the energy is required. Analysis of thermochemical hydrogen schemes and chemical heat pipe systems on a second law efficiency or available work basis show that hydrogen is superior especially if the end use of the chemical heat pipe is electrical power.

  18. Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy Storage

    Energy Technology Data Exchange (ETDEWEB)

    Steward, D. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Saur, G. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Penev, M. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Ramsden, T. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2009-11-01

    This report presents the results of an analysis evaluating the economic viability of hydrogen for medium- to large-scale electrical energy storage applications compared with three other storage technologies: batteries, pumped hydro, and compressed air energy storage (CAES).

  19. Proceedings of the DOE chemical/hydrogen energy systems contractor review

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-05-01

    This volume contains 45 papers as well as overviews of the two main project areas: the NASA Hydrogen Energy Storage Technology Project and Brookhaven National Laboratory's program on Electrolysis-Based Hydrogen Storage Systems. Forty-six project summaries are included. Individual papers were processed for inclusion in the Energy Data Base.

  20. Potential energy surface of alanine polypeptide chains

    DEFF Research Database (Denmark)

    Solov'yov, Ilia; Yakubovich, Alexander V.; Solov'yov, Andrey V.

    2006-01-01

    The multidimensional potential energy surfaces of the peptide chains consisting of three and six alanine (Ala) residues have been studied with respect to the degrees of freedom related to the twist of these molecules relative to the peptide backbone (these degrees of freedom are responsible...

  1. Energy from streaming current and potential

    NARCIS (Netherlands)

    Olthuis, Wouter; Schippers, Bob; Eijkel, Jan C.T.; van den Berg, Albert

    2005-01-01

    It is investigated how much energy can be delivered by a streaming current source. A streaming current and subsequent streaming potential originate when double layer charge is transported by hydrodynamic flow. Theory and a network model of such a source is presented and initial experimental results

  2. Application of Liquid Hydrogen with SMES for Efficient Use of Renewable Energy in the Energy Internet

    Directory of Open Access Journals (Sweden)

    Xin Wang

    2017-02-01

    Full Text Available Considering that generally frequency instability problems occur due to abrupt variations in load demand growth and power variations generated by different renewable energy sources (RESs, the application of superconducting magnetic energy storage (SMES may become crucial due to its rapid response features. In this paper, liquid hydrogen with SMES (LIQHYSMES is proposed to play a role in the future energy internet in terms of its combination of the SMES and the liquid hydrogen storage unit, which can help to overcome the capacity limit and high investment cost disadvantages of SMES. The generalized predictive control (GPC algorithm is presented to be appreciatively used to eliminate the frequency deviations of the isolated micro energy grid including the LIQHYSMES and RESs. A benchmark micro energy grid with distributed generators (DGs, electrical vehicle (EV stations, smart loads and a LIQHYSMES unit is modeled in the Matlab/Simulink environment. The simulation results show that the proposed GPC strategy can reschedule the active power output of each component to maintain the stability of the grid. In addition, in order to improve the performance of the SMES, a detailed optimization design of the superconducting coil is conducted, and the optimized SMES unit can offer better technical advantages in damping the frequency fluctuations.

  3. Key Factors in Planning a Sustainable Energy Future Including Hydrogen and Fuel Cells

    Science.gov (United States)

    Hedstrom, Lars; Saxe, Maria; Folkesson, Anders; Wallmark, Cecilia; Haraldsson, Kristina; Bryngelsson, Marten; Alvfors, Per

    2006-01-01

    In this article, a number of future energy visions, especially those basing the energy systems on hydrogen, are discussed. Some often missing comparisons between alternatives, from a sustainability perspective, are identified and then performed for energy storage, energy transportation, and energy use in vehicles. It is shown that it is important…

  4. Key Factors in Planning a Sustainable Energy Future Including Hydrogen and Fuel Cells

    Science.gov (United States)

    Hedstrom, Lars; Saxe, Maria; Folkesson, Anders; Wallmark, Cecilia; Haraldsson, Kristina; Bryngelsson, Marten; Alvfors, Per

    2006-01-01

    In this article, a number of future energy visions, especially those basing the energy systems on hydrogen, are discussed. Some often missing comparisons between alternatives, from a sustainability perspective, are identified and then performed for energy storage, energy transportation, and energy use in vehicles. It is shown that it is important…

  5. Efficiency Evaluation of a Photovoltaic System Simultaneously Generating Solar Electricity and Hydrogen for Energy Storage

    Directory of Open Access Journals (Sweden)

    Abermann S.

    2012-10-01

    Full Text Available The direct combination of a photovoltaic system with an energy storage component appears desirable since it produces and stores electrical energy simultaneously, enabling it to compensate power generation fluctuations and supply sufficient energy during low- or non-irradiation periods. A novel concept based on hydrogenated amorphous silicon (a-Si:H triple-junction solar cells, as for example a-Si:H/a-SiGe:H/a-SiGe:H, and a solar water splitting system integrating a polymer electrolyte membrane (PEM electrolyser is presented. The thin film layer-by-layer concept allows large-area module fabrication applicable to buildings, and exhibits strong cost-reduction potential as compared to similar concepts. The evaluation shows that it is possible to achieve a sufficient voltage of greater than 1.5 V for effective water splitting with the a-Si based solar cell. Nevertheless, in the case of grid-connection, the actual energy production cost for hydrogen storage by the proposed system is currently too high.

  6. Potential energy surfaces and reaction dynamics of polyatomic molecules

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Yan-Tyng.

    1991-11-01

    A simple empirical valence bond (EVB) model approach is suggested for constructing global potential energy surfaces for reactions of polyatomic molecular systems. This approach produces smooth and continuous potential surfaces which can be directly utilized in a dynamical study. Two types of reactions are of special interest, the unimolecular dissociation and the unimolecular isomerization. For the first type, the molecular dissociation dynamics of formaldehyde on the ground electronic surface is investigated through classical trajectory calculations on EVB surfaces. The product state distributions and vector correlations obtained from this study suggest very similar behaviors seen in the experiments. The intramolecular hydrogen atom transfer in the formic acid dimer is an example of the isomerization reaction. High level ab initio quantum chemistry calculations are performed to obtain optimized equilibrium and transition state dimer geometries and also the harmonic frequencies.

  7. Hydrogen sulfide : physiological properties and therapeutic potential in ischaemia

    NARCIS (Netherlands)

    Bos, Eelke M.; van Goor, Harry; Joles, Jaap A.; Whiteman, Matthew; Leuvenink, Henri G. D.

    2015-01-01

    Hydrogen sulfide (H2S) has become a molecule of high interest in recent years, and it is now recognized as the third gasotransmitter in addition to nitric oxide and carbon monoxide. In this review, we discuss the recent literature on the physiology of endogenous and exogenous H2S, focusing upon the

  8. Potential Applications of Hydrogen Sulfide-Induced Suspended Animation

    NARCIS (Netherlands)

    H. Aslami; M.J. Schultz; N.P. Juffermans

    2009-01-01

    A suspended animation-like state has been induced in rodents with the use of hydrogen sulfide, resulting in hypothermia with a concomitant reduction in metabolic rate. Also oxygen demand was reduced, thereby protecting against hypoxia. Several therapeutic applications of induction of a hibernation-l

  9. Potential Energy Cost Savings from Increased Commercial Energy Code Compliance

    Energy Technology Data Exchange (ETDEWEB)

    Rosenberg, Michael I.; Hart, Philip R.; Athalye, Rahul A.; Zhang, Jian; Cohan, David F.

    2016-08-22

    An important question for commercial energy code compliance is: “How much energy cost savings can better compliance achieve?” This question is in sharp contrast to prior efforts that used a checklist of code requirements, each of which was graded pass or fail. Percent compliance for any given building was simply the percent of individual requirements that passed. A field investigation method is being developed that goes beyond the binary approach to determine how much energy cost savings is not realized. Prototype building simulations were used to estimate the energy cost impact of varying levels of non-compliance for newly constructed office buildings in climate zone 4C. Field data collected from actual buildings on specific conditions relative to code requirements was then applied to the simulation results to find the potential lost energy savings for a single building or for a sample of buildings. This new methodology was tested on nine office buildings in climate zone 4C. The amount of additional energy cost savings they could have achieved had they complied fully with the 2012 International Energy Conservation Code is determined. This paper will present the results of the test, lessons learned, describe follow-on research that is needed to verify that the methodology is both accurate and practical, and discuss the benefits that might accrue if the method were widely adopted.

  10. Divacancy binding energy, formation energy and surface energy of BCC transition metals using MEAM potentials

    Science.gov (United States)

    Uniyal, Shweta; Chand, Manesh; Joshi, Subodh; Semalty, P. D.

    2016-05-01

    The modified embedded atom method (MEAM) potential parameters have been employed to calculate the unrelaxed divacancy formation energy, binding energy and surface energies for low index planes in bcc transition metals. The calculated results of divacancy binding energy and vacancy formation energy compare well with experimental and other available calculated results.

  11. Heat energy from hydrogen-metal nuclear interactions

    Science.gov (United States)

    Hadjichristos, John; Gluck, Peter

    2013-11-01

    The discovery of the Fleischmann-Pons Effect in 1989, a promise of an abundant, cheap and clean energy source was premature in the sense that theoretical knowledge, relative technologies and the experimental tools necessary for understanding and for scale-up still were not available. Therefore the field, despite efforts and diversification remained quasi-stagnant, the effect (a scientific certainty) being of low intensity leading to mainstream science to reject the phenomenon and not supporting its study. Recently however, the situation has changed, a new paradigm is in statunascendi and the obstacles are systematically removed by innovative approaches. Defkalion, a Greek company (that recently moved in Canada for faster progress) has elaborated an original technology for the Ni-H system [1-3]. It is about the activation of hydrogen and creation of nuclear active nano-cavities in the metal through a multi-stage interaction, materializing some recent breakthrough announcements in nanotechnology, superconductivity, plasma physics, astrophysics and material science. A pre-industrial generator and a novel mass-spectrometry instrumentations were created. Simultaneously, a meta-theory of phenomena was sketched in collaboration with Prof. Y. Kim (Purdue U).

  12. Hydrogen in the making: how an energy company organises under uncertainty

    Energy Technology Data Exchange (ETDEWEB)

    Koefoed, Anne Louise

    2011-07-01

    This thesis combines an analytical interest in innovation process studies with an empirical interest in clean energy development. My work concentrates on innovation processes from initiation to realisation in a company setting focusing on hydrogen as an energy carrier. A Norwegian energy company, Norsk Hydro, is used as a case to explore the intraorganisational processes involved in business building. This is relevant to the research question - how hydrogen energy takes on reality and relevance for business activity? Further, a concrete hydrogen demonstration project involving research and development of a new technology combination, in collaboration with partners, has also been studied.(Author)

  13. Sparse representation for a potential energy surface

    Science.gov (United States)

    Seko, Atsuto; Takahashi, Akira; Tanaka, Isao

    2014-07-01

    We propose a simple scheme to estimate the potential energy surface (PES) for which the accuracy can be easily controlled and improved. It is based on model selection within the framework of linear regression using the least absolute shrinkage and selection operator (LASSO) technique. Basis functions are selected from a systematic large set of candidate functions. The sparsity of the PES significantly reduces the computational cost of evaluating the energy and force in molecular dynamics simulations without losing accuracy. The usefulness of the scheme for describing the elemental metals Na and Mg is clearly demonstrated.

  14. Evaluation of bio-energy potential using world energy models; Sekai energy model ni yoru bio energy no potential hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Fujino, J.; Yamaji, K. [The University of Tokyo, Tokyo (Japan); Yamamoto, H. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1997-01-30

    Bio-energy potential is evaluated using world energy models. The world energy model is a dynamic model by which the total cost of energy systems between 1995 and 2055 can be minimized on the basis of the optimization type world energy demand and supply model. For the given utilization costs of transportation, recovery and planting, the utilization of bio-energy is promoted even under the cost minimization condition. However, the utilization amount varies in a wide range by changing the utilization costs. Among conversion technologies of bio-energy, it is biomass liquefaction that provides the largest utilization amount. Thermal demand, direct combustion for power generation, and biomass gasification follow to the above. Biomass-integrated gasifier/gas turbine (BIG/GT) is to be used up to 2020. It is not to be used after 2030, due to the complete shift to the biomass liquefaction. For a model including the utilization of fast breeder after 2030, the utilization amount of bio-energy is not to change. Competition with food and land utilization is to be investigated. 11 refs., 19 figs., 4 tabs.

  15. Evaluation of bio-energy potential using world energy models; Sekai energy model ni yoru bio energy no potential hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Fujino, J.; Yamaji, K. [The University of Tokyo, Tokyo (Japan); Yamamoto, H. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1997-01-30

    Bio-energy potential is evaluated using world energy models. The world energy model is a dynamic model by which the total cost of energy systems between 1995 and 2055 can be minimized on the basis of the optimization type world energy demand and supply model. For the given utilization costs of transportation, recovery and planting, the utilization of bio-energy is promoted even under the cost minimization condition. However, the utilization amount varies in a wide range by changing the utilization costs. Among conversion technologies of bio-energy, it is biomass liquefaction that provides the largest utilization amount. Thermal demand, direct combustion for power generation, and biomass gasification follow to the above. Biomass-integrated gasifier/gas turbine (BIG/GT) is to be used up to 2020. It is not to be used after 2030, due to the complete shift to the biomass liquefaction. For a model including the utilization of fast breeder after 2030, the utilization amount of bio-energy is not to change. Competition with food and land utilization is to be investigated. 11 refs., 19 figs., 4 tabs.

  16. Hydrogen energy and fuel cells: a recent R and D program in Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Sebastian, P.J.; Martinez, M. [Universidad Nacional Autonoma de Mexico, Mexico City (Mexico). Inst. de Investigaciones en Materiales; Eapen, D. [UNAM, Morelos (Mexico). Inst. de Biotecnologia; Solorza, O. [CINVESTAV-IPN, Mexico (Mexico). Dept. de Quimica; Savadogo, O. [Ecole Polytechnique, Montreal, PQ (Canada). Dept. of Metallurgy and Materials Engineering

    1996-12-31

    A recent R and D program on hydrogen production, storage and application in fuel cells by employing various physicochemical and biological routes was initiated among the three institutions in Mexico in collaboration with Ecole Polytechnique, Canada. The major theme of this R and D program is hydrogen production using various physicochemical and biological methods, development of high efficiency storage materials and applications of hydrogen in fuel cells for production of electricity. The future of the hydrogen energy program in Mexico is reviewed in the light of the high pollution level in several large cities and the energy scenario from 1962 onwards. (Author)

  17. Potential Environmental Impacts of Hydrogen-based Transportation and Power Systems

    Energy Technology Data Exchange (ETDEWEB)

    Grieb, Thomas M; Mills, W B; Jacobson, Mark Z; Summers, Karen V; Crossan, A Brook

    2010-12-31

    Hydrogen (H2) offers advantages as an energy carrier: minimal discharge of pollutants, production from multiple sources, increased thermodynamic efficiencies compared to fossil fuels, and reduced dependence on foreign oil. However, potential impacts from the H2 generation processes, transport and distribution of H2, and releases of H2 into the atmosphere have been proposed. The goal of this project was to analyze the effects of emissions of hydrogen, the six criteria pollutants and greenhouse gases on climate, human health, materials and structures. This project was part of a larger effort by DOE to assess the life-cycle costs and benefits and environmental impacts to inform decisions regarding future hydrogen research. Technical Approach: A modeling approach was developed and used to evaluate the potential environmental effects associated with the conversion of the on-road vehicle fleet from fossil-fuel vehicles to hydrogen fuel cell vehicles. GATOR-GCMOM was the primary tool used to predict atmospheric concentrations of gases and aerosols for selected scenarios. This model accounts for all feedbacks among major atmospheric processes based on first principles. The future scenarios and the emission rates selected for this analysis of hydrogen environmental effects are based on the scenarios developed by IPCC. The scenarios selected for the model simulations are a 2000 and 2050 A1B base cases, and a 2050 A1B case with hydrogen fuel cell vehicles (HFCVs). The hydrogen fuel cell scenario assumed conversion of 90% of fossil-fuel on-road vehicles (FFOV) in developed countries and 45% of FFOVs vehicles in other countries to HFCVs, with the H2 produced by steam-reforming of natural gas (SHFCVs). Simulations were conducted to examine the effect of converting the world's FFOVs to HFCVs, where the H2 is produced by wind-powered electrolysis (WHFCVs). In all scenarios a 3% leakage of H2 consumed was assumed. Two new models were developed that provide the ability to

  18. Progress of Palladium Alloy Membranes in Hydrogen Energy

    Institute of Scientific and Technical Information of China (English)

    MA Guang; LI Jin; LI Yin'e; SUN Xiaoliang; CAO Qigao; JIA Zhihua

    2012-01-01

    Palladium and palladium alloy membranes have attracted wide attention in hydrogen permeation areas for their excellent permeability,perm-selectivity and thermal stability.This paper review the principle of hydrogen permeation,type of alloys and the fabrication methods.At last,the progress and achievements on palladium alloy membranes by Northwest Institute for Non-Ferrous Metal Research are emphasized.

  19. Hydrogen carriers

    Science.gov (United States)

    He, Teng; Pachfule, Pradip; Wu, Hui; Xu, Qiang; Chen, Ping

    2016-12-01

    Hydrogen has the potential to be a major energy vector in a renewable and sustainable future energy mix. The efficient production, storage and delivery of hydrogen are key technical issues that require improvement before its potential can be realized. In this Review, we focus on recent advances in materials development for on-board hydrogen storage. We highlight the strategic design and optimization of hydrides of light-weight elements (for example, boron, nitrogen and carbon) and physisorbents (for example, metal-organic and covalent organic frameworks). Furthermore, hydrogen carriers (for example, NH3, CH3OH-H2O and cycloalkanes) for large-scale distribution and for on-site hydrogen generation are discussed with an emphasis on dehydrogenation catalysts.

  20. Towards a hydrogen-driven society? Calculations and neutron scattering on potential hydrogen storage materials

    NARCIS (Netherlands)

    Schimmel, H.G.

    2005-01-01

    For sustainable development, the resources of the earth need to be maintained and carbon dioxide emission should be avoided. In particular, we need to find an alternative for the use of fossil fuels in vehicles. Since long, hydrogen has been recognised as the fuel of the future because it exhausts

  1. Towards a hydrogen-driven society? Calculations and neutron scattering on potential hydrogen storage materials

    NARCIS (Netherlands)

    Schimmel, H.G.

    2005-01-01

    For sustainable development, the resources of the earth need to be maintained and carbon dioxide emission should be avoided. In particular, we need to find an alternative for the use of fossil fuels in vehicles. Since long, hydrogen has been recognised as the fuel of the future because it exhausts o

  2. On Euclidean designs and the potential energy

    CERN Document Server

    Miezaki, Tsuyoshi

    2011-01-01

    We study Euclidean designs from the viewpoint of the potential energy. For a finite set in Euclidean space, We formulate a linear programming bound for the potential energy by applying harmonic analysis on a sphere. We also introduce the concept of strong Euclidean designs from the viewpoint of the linear programming bound, and we give a Fisher type inequality for strong Euclidean designs. A finite set on Euclidean space is called a Euclidean a-code if any distinct two points in the set are separated at least by a. As a corollary of the linear programming bound, we give a method to determine an upper bound on the cardinalities of Euclidean a-codes on concentric spheres of given radii. Similarly we also give a method to determine a lower bound on the cardinalities of Euclidean t-designs as an analogue of the linear programming bound.

  3. Wave energy potential in Galicia (NW Spain)

    DEFF Research Database (Denmark)

    Iglesias, Gregorio; López, Mario; Carballo, Rodrigo;

    2009-01-01

    Wave power presents significant advantages with regard to other CO2-free energy sources, among which the predictability, high load factor and low visual and environmental impact stand out. Galicia, facing the Atlantic on the north-western corner of the Iberian Peninsula, is subjected to a very...... harsh wave climate; in this work its potential for energy production is assessed based on three-hourly data from a third generation ocean wave model (WAM) covering the period 1996 - 2005. Taking into account the results of this assessment along with other relevant considerations such as the location...... of ports, navigation routes, and fishing and aquaculture zones, an area is selected for wave energy exploitation. The transformation of the offshore wave field as it propagates into this area is computed by means of a nearshore wave model (SWAN) in order to select the optimum locations for a wave farm. Two...

  4. Learning Potential Energy Landscapes using Graph Kernels

    CERN Document Server

    Ferré, G; Barros, K

    2016-01-01

    Recent machine learning methods make it possible to model potential energy of atomic configurations with chemical-level accuracy (as calculated from ab-initio calculations) and at speeds suitable for molecular dynamics simulation. Best performance is achieved when the known physical constraints are encoded in the machine learning models. For example, the atomic energy is invariant under global translations and rotations; it is also invariant to permutations of same-species atoms. Although simple to state, these symmetries are complicated to encode into machine learning algorithms. In this paper, we present a machine learning approach based on graph theory that naturally incorporates translation, rotation, and permutation symmetries. Specifically, we use a random walk graph kernel to measure the similarity of two adjacency matrices, each of which represents a local atomic environment. We show on a standard benchmark that our Graph Approximated Energy (GRAPE) method is competitive with state of the art kernel m...

  5. Potential energy surfaces of Polonium isotopes

    Science.gov (United States)

    Nerlo-Pomorska, B.; Pomorski, K.; Schmitt, C.; Bartel, J.

    2015-11-01

    The evolution of the potential energy landscape is analysed in detail for ten even-even polonium isotopes in the mass range 188\\lt A\\lt 220 as obtained within the macroscopic-microscopic approach, relying on the Lublin-Strasbourg drop model and the Yukawa-folded single-particle energies for calculating the microscopic shell and pairing corrections. A variant of the modified Funny-Hills nuclear shape parametrization is used to efficiently map possible fission paths. The approach explains the main features of the fragment partition as measured in low-energy fission along the polonium chain. The latter lies in a transitional region of the nuclear chart, and will be essential to consistently understand the evolution of fission properties from neutron-deficient mercury to heavy actinides. The ability of our method to predict fission observables over such an extended region looks promising.

  6. The Wind Energy Potential of Iceland

    Science.gov (United States)

    Nawri, Nikolai; Nína Petersen, Guðrún; Bjornsson, Halldór; Hahmann, Andrea N.; Jónasson, Kristján; Bay Hasager, Charlotte; Clausen, Niels-Erik

    2014-05-01

    While Iceland has an abundant wind energy resource, its use for electrical power production has so far been limited. Electricity in Iceland is generated primarily from hydro- and geothermal sources, and adding wind energy has so far not been considered practical or even necessary. However, wind energy is becoming a more viable option, as opportunities for new hydro- or geothermal power installations become limited. In order to obtain an estimate of the wind energy potential of Iceland, a wind atlas has been developed as part of the joint Nordic project 'Improved Forecast of Wind, Waves and Icing' (IceWind). Downscaling simulations performed with the Weather Research and Forecasting (WRF) model were used to determine the large-scale wind energy potential of Iceland. Local wind speed distributions are represented by Weibull statistics. The shape parameter across Iceland varies between 1.2 and 3.6, with the lowest values indicative of near-exponential distributions at sheltered locations, and the highest values indicative of normal distributions at exposed locations in winter. Compared with summer, average power density in winter is increased throughout Iceland by a factor of 2.0 - 5.5. In any season, there are also considerable spatial differences in average wind power density. Relative to the average value within 10 km of the coast, power density across Iceland varies between 50 - 250%, excluding glaciers, or between 300 - 1500 W m-2 at 50 m above ground level in winter. At intermediate elevations of 500 - 1000 m above mean sea level, power density is independent of the distance to the coast. In addition to seasonal and spatial variability, differences in average wind speed and power density also exist for different wind directions. Along the coast in winter, power density of onshore winds is higher by 100 - 700 W m-2 than that of offshore winds. The regions with the highest average wind speeds are impractical for wind farms, due to the distances from road

  7. Energy Savings Potential of Radiative Cooling Technologies

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, Nicholas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wang, Weimin [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Alvine, Kyle J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Katipamula, Srinivas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-11-30

    Pacific Northwest National Laboratory (PNNL), with funding from the U.S. Department of Energy’s (DOE’s) Building Technologies Program (BTP), conducted a study to estimate, through simulation, the potential cooling energy savings that could be achieved through novel approaches to capturing free radiative cooling in buildings, particularly photonic ‘selective emittance’ materials. This report documents the results of that study.

  8. Potential energy landscapes of tetragonal pyramid molecules

    Science.gov (United States)

    Yoshida, Yuichiro; Sato, Hirofumi; Morgan, John W. R.; Wales, David J.

    2016-11-01

    Hiraoka et al. have developed a self-assembling system referred to as a nanocube (Hiraoka et al., 2008). In the present contribution a coarse-grained model for this system is analysed, focusing on how the potential energy landscape for self-assembly is related to the geometry of the building blocks. We find that six molecules assemble to form various clusters, with cubic and sheet structures the most stable. The relative stability is determined by the geometry of the building blocks.

  9. High Performance, Low Cost Hydrogen Generation from Renewable Energy

    Energy Technology Data Exchange (ETDEWEB)

    Ayers, Katherine [Proton OnSite; Dalton, Luke [Proton OnSite; Roemer, Andy [Proton OnSite; Carter, Blake [Proton OnSite; Niedzwiecki, Mike [Proton OnSite; Manco, Judith [Proton OnSite; Anderson, Everett [Proton OnSite; Capuano, Chris [Proton OnSite; Wang, Chao-Yang [Penn State University; Zhao, Wei [Penn State University

    2014-02-05

    Renewable hydrogen from proton exchange membrane (PEM) electrolysis is gaining strong interest in Europe, especially in Germany where wind penetration is already at critical levels for grid stability. For this application as well as biogas conversion and vehicle fueling, megawatt (MW) scale electrolysis is required. Proton has established a technology roadmap to achieve the necessary cost reductions and manufacturing scale up to maintain U.S. competitiveness in these markets. This project represents a highly successful example of the potential for cost reduction in PEM electrolysis, and provides the initial stack design and manufacturing development for Proton’s MW scale product launch. The majority of the program focused on the bipolar assembly, from electrochemical modeling to subscale stack development through prototyping and manufacturing qualification for a large active area cell platform. Feasibility for an advanced membrane electrode assembly (MEA) with 50% reduction in catalyst loading was also demonstrated. Based on the progress in this program and other parallel efforts, H2A analysis shows the status of PEM electrolysis technology dropping below $3.50/kg production costs, exceeding the 2015 target.

  10. The Effect of Converting to a U.S. Hydrogen Fuel Cell Vehicle Fleet on Emissions and Energy Use

    Science.gov (United States)

    Colella, W. G.; Jacobson, M. Z.; Golden, D. M.

    2004-12-01

    This study analyzes the potential change in emissions and energy use from replacing fossil-fuel based vehicles with hydrogen fuel cell vehicles. This study examines three different hydrogen production scenarios to determine their resultant emissions and energy usage: hydrogen produced via 1) steam reforming of methane, 2) coal gasification, or 3) wind electrolysis. The atmospheric model simulations require two primary sets of data: the actual emissions associated with hydrogen fuel production and use, and the corresponding reduction in emissions associated with reducing fossil fuel use. The net change in emissions is derived using 1) the U.S. EPA's National Emission Inventory (NEI) that incorporates several hundred categories of on-road vehicles and 2) a Process Chain Analysis (PCA) for the different hydrogen production scenarios. NEI: The quantity of hydrogen-related emission is ultimately a function of the projected hydrogen consumption in on-road vehicles. Data for hydrogen consumption from on-road vehicles was derived from the number of miles driven in each U.S. county based on 1999 NEI data, the average fleet mileage of all on-road vehicles, the average gasoline vehicle efficiency, and the efficiency of advanced 2004 fuel cell vehicles. PCA: PCA involves energy and mass balance calculations around the fuel extraction, production, transport, storage, and delivery processes. PCA was used to examine three different hydrogen production scenarios: In the first scenario, hydrogen is derived from natural gas, which is extracted from gas fields, stored, chemically processed, and transmitted through pipelines to distributed fuel processing units. The fuel processing units, situated in similar locations as gasoline refueling stations, convert natural gas to hydrogen via a combination of steam reforming and fuel oxidation. Purified hydrogen is compressed for use onboard fuel cell vehicles. In the second scenario, hydrogen is derived from coal, which is extracted from

  11. Potential Fluctuation Equality for Free Energy Evaluation

    CERN Document Server

    Ngo, Van

    2011-01-01

    Jarzynski's equality [1] allows us to investigate free energy landscapes (FELs) by constructing distributions of work performed on a system from an initial ensemble of states to final states. This work is experimentally measured by extension-versus-force (EVF) curves. We proposed a new approach that enables us to reconstruct such FELs without necessity of measuring EVF curves. We proved that any free energy changes could be computed by measuring the fluctuations of a harmonic external potential in final states. The main assumption of our proof is that one should probably treat a potential's minimum {\\lambda} (thought to be control parameter) and time in separate and independent manners. We recovered Jarzynski's equality from the introduction of a double Heaviside function. We then applied the approach in molecular dynamics (MD) simulations to compute the free energy barrier of breaking DNA base pairs (bps). The free energy barrier for breaking a CG bp in our simulations is identified as 1.7 +/- 0.2 kcal/mol t...

  12. Effect of hydrogenation, low energy ion irradiation and annealing on hydrogen bonding to polycrystalline diamond surface studied by high resolution electron energy loss spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Michaelson, S.; Ternyak, O.; Akhvlediani, R.; Hoffman, A. [Schulich Faculty of Chemistry, Technion, Israeli Institute of Technology, Haifa (Israel); Lafosse, A.; Bertin, M.; Azria, R. [Paris-Sud Univ. et CNRS, Lab. des Collisions Atomiques et Moleculaires, 91 - Orsay (France)

    2007-09-15

    The effects of different processes of hydrogenation, thermal treatment and ion irradiation of hydrogenated polycrystalline diamond surface have been investigated by means of high resolution electron energy loss spectroscopy (HR-EELS). Analysis of the different contributions in the CH stretching, overtones and combination modes, as well as changes in relative intensities of the diamond CC and CH{sub x} related vibrations allowed us to identify the CH{sub x} adsorbed species on the diamond surface following the different treatments. Ex-situ hydrogenation of diamond surface by means of exposure to H-MW plasma results in a fully hydrogenated well-ordered diamond surface and etching of the amorphous phase located on the grain boundaries present on the sample after CVD-deposition. Annealing this surface to 600 C results in some subtle changes in the HR-EELS, probably associated with decomposition of CH{sub x} (x=2,3) adsorbed species. Ion irradiation on the surface induces partial desorption of hydrogen from the diamond phase and a large amount of amorphous defects, some of them of sp and the most of them of sp{sup 2} character. Annealing to 600-700 C of the irradiated surface leads to hydrogen desorption. In-situ hydrogenation of the irradiated and annealed sample does not restore the diamond structure, and results in hydrogenated amorphous surface, unstable with thermal annealing above 600-700 C. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  13. Solar-hydrogen energy as an alternative energy source for mobile robots and the new-age car

    Science.gov (United States)

    Sulaiman, A.; Inambao, F.; Bright, G.

    2014-07-01

    The disastrous effects of climate change as witnessed in recent violent storms, and the stark reality that fossil fuels are not going to last forever, is certain to create renewed demands for alternative energy sources. One such alternative source, namely solar energy, although unreliable because of its dependence on available sunlight, can nevertheless be utilised to generate a secondary source of energy, namely hydrogen, which can be stored and thereby provide a constant and reliable source of energy. The only draw-back with hydrogen, though, is finding efficient means for its storage. This study demonstrates how this problem can be overcome by the use of metal hydrides which offers a very compact and safe way of storing hydrogen. It also provides a case study of how solar and hydrogen energy can be combined in an energy system to provide an efficient source of energy that can be applied for modern technologies such as a mobile robot. Hydrogen energy holds out the most promise amongst the various alternative energy sources, so much so that it is proving to be the energy source of choice for automobile manufacturers in their quest for alternative fuels to power their cars of the future.

  14. Key challenges and recent progress in batteries, fuel cells, and hydrogen storage for clean energy systems

    Science.gov (United States)

    Chalk, Steven G.; Miller, James F.

    Reducing or eliminating the dependency on petroleum of transportation systems is a major element of US energy research activities. Batteries are a key enabling technology for the development of clean, fuel-efficient vehicles and are key to making today's hybrid electric vehicles a success. Fuel cells are the key enabling technology for a future hydrogen economy and have the potential to revolutionize the way we power our nations, offering cleaner, more efficient alternatives to today's technology. Additionally fuel cells are significantly more energy efficient than combustion-based power generation technologies. Fuel cells are projected to have energy efficiency twice that of internal combustion engines. However before fuel cells can realize their potential, significant challenges remain. The two most important are cost and durability for both automotive and stationary applications. Recent electrocatalyst developments have shown that Pt alloy catalysts have increased activity and greater durability than Pt catalysts. The durability of conventional fluorocarbon membranes is improving, and hydrocarbon-based membranes have also shown promise of equaling the performance of fluorocarbon membranes at lower cost. Recent announcements have also provided indications that fuel cells can start from freezing conditions without significant deterioration. Hydrogen storage systems for vehicles are inadequate to meet customer driving range expectations (>300 miles or 500 km) without intrusion into vehicle cargo or passenger space. The United States Department of Energy has established three centers of Excellence for hydrogen storage materials development. The centers are focused on complex metal hydrides that can be regenerated onboard a vehicle, chemical hydrides that require off-board reprocessing, and carbon-based storage materials. Recent developments have shown progress toward the 2010 DOE targets. In addition DOE has established an independent storage material testing center

  15. Viability of Hydrogen Pathways that Enhance Energy Security: A Comparison of China and Denmark

    DEFF Research Database (Denmark)

    Ren, Jingzheng; Andreasen, Kristian Peter; Sovacool, Benjamin

    2014-01-01

    pathways create particular consequences on a nation's overall energy security. The objective of this study is to investigate the superiorities and inferiorities of hydrogen pathways from the perspective of China and Denmark, and to determine which pathways best contribute to national energy security...... objectives. The results are useful for stakeholders and energy analysts so that they can correctly plan and research the most socially optimal portfolio of hydrogen technologies....

  16. In Search of the Wind Energy Potential

    DEFF Research Database (Denmark)

    Lundtang Petersen, Erik

    2017-01-01

    The worldwide advancement of wind energy is putting high demands on a number of underlying technologies such as wind turbine aerodynamics, structural dynamics, gearbox design, electrical grid connections, and so on. As wind is the only fuel for wind power plants, naturally, wind-meteorology and w......The worldwide advancement of wind energy is putting high demands on a number of underlying technologies such as wind turbine aerodynamics, structural dynamics, gearbox design, electrical grid connections, and so on. As wind is the only fuel for wind power plants, naturally, wind......-meteorology and wind-climatology are essential for any utilization of wind energy. This is what we are concerned about here with a view on what has happened in wind energy potential assessments in the last 25 years where the utilization of wind turbines in national power supply has accelerated and what......., The New Worldwide Microscale Wind Resource Assessment Data on IRENA's Global Atlas (The EUDP Global Wind Atlas, 2015)], and finally, the perspective for the current work with the New European Wind Atlas [E. L. Petersen et al., Energy Bull. 17, 34–39 (2014); Environ. Res. Lett. 8(1), 011005 (2013...

  17. A novel kerf-free wafering process combining stress-induced spalling and low energy hydrogen implantation

    Energy Technology Data Exchange (ETDEWEB)

    Pingault, Timothee; Pokam-Kuisseu, Pauline Sylvia; Ntsoenzok, Esidor [CEMTHI - CNRS, Site Cyclotron, 3 A rue de la Ferollerie, 45071 Orleans (France); Blondeau, Jean-Philippe [CEMTHI - CNRS, Site Cyclotron, 3 A rue de la Ferollerie, 45071 Orleans (France); Universite d' Orleans, Chateau de la Source, 45100 Orleans (France); Ulyashin, Alexander [SINTEF, Forskningsveien 1, 0314 Oslo (Norway); Labrim, Hicham; Belhorma, Bouchra [CNESTEN, B.P. 1382 R.P., 10001 Rabat (Morocco)

    2016-12-15

    In this work, we studied the potential use of low-energy hydrogen implantation as a guide for the stress-induced cleavage. Low-energy, high fluence hydrogen implantation in silicon leads, in the right stiffening conditions, to the detachment of a thin layer, around a few hundreds nm thick, of monocrystalline silicon. We implanted monocrystalline silicon wafers with low-energy hydrogen, and then glued them on a cheap metal layer. Upon cooling down, the stress induced by the stressor layers (hardened glue and metal) leads to the detachment of a thin silicon layer, which thickness is determined by the implantation energy. We were then able to clearly demonstrate that, as expected, hydrogen oversaturation layer is very efficient to guide the stress. Using such process, thin silicon layers of around 710 nm-thick were successfully detached from low-energy implanted silicon wafers. Such layers can be used for the growth of very good quality monocrystalline silicon of around 50 μm-thick or less. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  18. Hexagonal boron nitride nanoparticles decorated halloysite clay nanotubes as a potential hydrogen storage medium

    Energy Technology Data Exchange (ETDEWEB)

    Muthu, R. Naresh, E-mail: rnaresh7708@gmail.com; Rajashabala, S. [School of Physics, Madurai Kamaraj University, Madurai-625021, Tamil Nadu (India); Kannan, R. [Department of Physics, University College of Engineering, Anna University, Dindigul-624622 (India); Department of Materials Science and Engineering, Cornell University, Ithaca 14850, New York (United States)

    2016-05-23

    The light weight and compact hydrogen storage materials is still prerequisite for the carbon free hydrogen fuel cell technology. In this work, the hydrogen storage performance of acid treated halloysite clay nanotubes (A-HNTs) and hexagonal boron nitride (h-BN) nanoparticles decorated acid treated halloysite nanoclay composite (A-HNT-h-BN) are demonstrated, where facile ultrasonic technique is adopted for the synthesis of A-HNT-h-BN nanoclay composite. Hydrogen storage studies were carried out using Sieverts-like hydrogenation setup. The A-HNTs and A-HNT-h-BN nanoclay composite were analyzed by XRD, FTIR, HRTEM, EDX, CHNS-elemental analysis and TGA. The A-HNT-h-BN nanoclay composite shows superior storage capacity of 2.19 wt% at 50 °C compared to the A-HNTs (0.58 wt%). A 100% desorption of stored hydrogen is noted in the temperature range of 138–175 °C. The average binding energy of hydrogen was found to be 0.34 eV for the prepared A-HNT-h-BN nanoclay composite. The excellent storage capability of A-HNT-h-BN nanoclay composite towards hydrogen at ambient temperature may find bright perspective in hydrogen fuel cell technology in near future.

  19. Hexagonal boron nitride nanoparticles decorated halloysite clay nanotubes as a potential hydrogen storage medium

    Science.gov (United States)

    Muthu, R. Naresh; Rajashabala, S.; Kannan, R.

    2016-05-01

    The light weight and compact hydrogen storage materials is still prerequisite for the carbon free hydrogen fuel cell technology. In this work, the hydrogen storage performance of acid treated halloysite clay nanotubes (A-HNTs) and hexagonal boron nitride (h-BN) nanoparticles decorated acid treated halloysite nanoclay composite (A-HNT-h-BN) are demonstrated, where facile ultrasonic technique is adopted for the synthesis of A-HNT-h-BN nanoclay composite. Hydrogen storage studies were carried out using Sieverts-like hydrogenation setup. The A-HNTs and A-HNT-h-BN nanoclay composite were analyzed by XRD, FTIR, HRTEM, EDX, CHNS-elemental analysis and TGA. The A-HNT-h-BN nanoclay composite shows superior storage capacity of 2.19 wt% at 50 °C compared to the A-HNTs (0.58 wt%). A 100% desorption of stored hydrogen is noted in the temperature range of 138-175 °C. The average binding energy of hydrogen was found to be 0.34 eV for the prepared A-HNT-h-BN nanoclay composite. The excellent storage capability of A-HNT-h-BN nanoclay composite towards hydrogen at ambient temperature may find bright perspective in hydrogen fuel cell technology in near future.

  20. Evaluation of the individual hydrogen bonding energies in N-methylacetamide chains

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The individual hydrogen bonding energies in N-methylacetamide chains were evaluated at the MP2/6-31+G** level including BSSE correction and at the B3LYP/6-311++G(3df,2pd) level including BSSE and van der Waals correction.The calculation results indicate that compared with MP2 results,B3LYP calculations without van der Waals correction underestimate the individual hydrogen bonding energies about 5.4 kJ m ol-1 for both the terminal and central hydrogen bonds,whereas B3LYP calculations with van der Waals correction produce almost the same individual hydrogen bonding energies as MP2 does for those terminal hydrogen bonds,but still underestimate the individual hydrogen bonding energies about 2.5 kJ mol-1 for the hydrogen bonds near the center.Our calculation results show that the individual hydrogen bonding energy becomes more negative (more attractive) as the chain becomes longer and that the hydrogen bonds close to the interior of the chain are stronger than those near the ends.The weakest individual hydrogen bonding energy is about-29.0 kJ m ol-1 found in the dimer,whereas with the growth of the N-methylacetamide chain the individual hydrogen bonding energy was estimated to be as large as-62.5 kJ mol-1 found in the N-methylacetamide decamer,showing that there is a significant hydrogen bond cooperative effect in N-methylacetamide chains.The natural bond orbital analysis indicates that a stronger hydrogen bond corresponds to a larger positive charge for the H atom and a larger negative charge for the O atom in the N-H···O=C bond,corresponds to a stronger second-order stabilization energy between the oxygen lone pair and the N-H antibonding orbital,and corresponds to more charge transfer between the hydrogen bonded donor and acceptor molecules.

  1. Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell

    OpenAIRE

    Fukuzumi, Shunichi; Yamada, Yusuke; Karlin, Kenneth D.

    2012-01-01

    This review describes homogeneous and heterogeneous catalytic reduction of dioxygen with metal complexes focusing on the catalytic two-electron reduction of dioxygen to produce hydrogen peroxide. Whether two-electron reduction of dioxygen to produce hydrogen peroxide or four-electron O2-reduction to produce water occurs depends on the types of metals and ligands that are utilized. Those factors controlling the two processes are discussed in terms of metal-oxygen intermediates involved in the ...

  2. Therapeutic application of hydrogen sulfide donors: the potential and challenges.

    Science.gov (United States)

    Wu, Dan; Hu, Qingxun; Zhu, Yizhun

    2016-03-01

    Hydrogen sulfide (H2S), a colorless gas smelling of rotten egg, has long been considered a toxic gas and environment hazard. However, evidences show that H2S plays a great role in many physiological and pathological activities, and it exhibits different effects when applied at various doses. In this review, we summarize the chemistry and biomedical applications of H2S-releasing compounds, including inorganic salts, phosphorodithioate derivatives, derivatives of Allium sativum extracts, derivatives of thioaminoacids, and derivatives of antiinflammatory drugs.

  3. Progress of green energy hydrogen energy and technology of hydrogen production by water electrolysis%绿色能源氢能及其电解水制氢技术进展

    Institute of Scientific and Technical Information of China (English)

    刘芸

    2012-01-01

    With the increasingly serious environmental pollution, more and more studies focus on the green non-polluting energy. Hydrogen energy which is a clean, pollution -free, efficient, and renewable energy, is the most excellent potential energy carriers in the future. The technology of hydrogen electrolyzed water is the most promising technology, also is a cost-effective technology. The status of hydrogen research and hydrogen water technology was described, and the alkaline electrolyzer, proton exchange membrane electrolysis technology, and solid oxide water electrolysis technology were focused on. A systematic summary of this technology was presented.%随着环境污染日益严重,越来越多的研究关注于绿色无污染能源,其中氢能清洁无污染、高效、可再生,是未来最有潜力的能源载体.而利用电解水技术制氢是目前最有潜力的技术,也是一种经济有效的技术.介绍了氢能的研究现状和水电制氢技术,着重介绍了碱性电解槽、质子交换膜电解技术以及固体氧化物水电解技术,对现有技术进行了总结.

  4. Integration of Wind Energy, Hydrogen and Natural Gas Pipeline Systems to Meet Community and Transportation Energy Needs: A Parametric Study

    Directory of Open Access Journals (Sweden)

    Shahryar Garmsiri

    2014-04-01

    Full Text Available The potential benefits are examined of the “Power-to-Gas” (P2G scheme to utilize excess wind power capacity by generating hydrogen (or potentially methane for use in the natural gas distribution grid. A parametric analysis is used to determine the feasibility and size of systems producing hydrogen that would be injected into the natural gas grid. Specifically, wind farms located in southwestern Ontario, Canada are considered. Infrastructure requirements, wind farm size, pipeline capacity, geographical dispersion, hydrogen production rate, capital and operating costs are used as performance measures. The model takes into account the potential production rate of hydrogen and the rate that it can be injected into the local gas grid. “Straw man” systems are examined, centered on a wind farm size of 100 MW integrating a 16-MW capacity electrolysis system typically producing 4700 kg of hydrogen per day.

  5. The rotating Morse potential energy eigenvalues solved by using the analytical transfer matrix method

    Institute of Scientific and Technical Information of China (English)

    He Ying; Tao Qiu-Gong; Yang Yan-Fang

    2012-01-01

    We study the eigenvalues of the rotating Morse potential by using the quantization condition from the analytical transfer matrix (ATM) method.A hierarchy of supersymmetric partner potentials is obtained with Pekeris approximation,which can be used to calculate the energies of higher rotational states from the energies of lower states.The energies of rotational states of the hydrogen molecule are calculated by the ATM condition,and comparison of the results with those from the hypervirial perturbation method reveals that the accuracy of the approximate expression of Pekeris for the eigenvalues of the rotating Morse potential can be improved substantially in the framework of supersymmetric quantum mechanics.

  6. Potential Environmental Impacts of Hydrogen-based Transportation and Power Systems

    Energy Technology Data Exchange (ETDEWEB)

    Grieb, Thomas M; Mills, W B; Jacobson, Mark Z; Summers, Karen V; Crossan, A Brook

    2010-12-31

    Hydrogen (H2) offers advantages as an energy carrier: minimal discharge of pollutants, production from multiple sources, increased thermodynamic efficiencies compared to fossil fuels, and reduced dependence on foreign oil. However, potential impacts from the H2 generation processes, transport and distribution of H2, and releases of H2 into the atmosphere have been proposed. The goal of this project was to analyze the effects of emissions of hydrogen, the six criteria pollutants and greenhouse gases on climate, human health, materials and structures. This project was part of a larger effort by DOE to assess the life-cycle costs and benefits and environmental impacts to inform decisions regarding future hydrogen research. Technical Approach: A modeling approach was developed and used to evaluate the potential environmental effects associated with the conversion of the on-road vehicle fleet from fossil-fuel vehicles to hydrogen fuel cell vehicles. GATOR-GCMOM was the primary tool used to predict atmospheric concentrations of gases and aerosols for selected scenarios. This model accounts for all feedbacks among major atmospheric processes based on first principles. The future scenarios and the emission rates selected for this analysis of hydrogen environmental effects are based on the scenarios developed by IPCC. The scenarios selected for the model simulations are a 2000 and 2050 A1B base cases, and a 2050 A1B case with hydrogen fuel cell vehicles (HFCVs). The hydrogen fuel cell scenario assumed conversion of 90% of fossil-fuel on-road vehicles (FFOV) in developed countries and 45% of FFOVs vehicles in other countries to HFCVs, with the H2 produced by steam-reforming of natural gas (SHFCVs). Simulations were conducted to examine the effect of converting the world's FFOVs to HFCVs, where the H2 is produced by wind-powered electrolysis (WHFCVs). In all scenarios a 3% leakage of H2 consumed was assumed. Two new models were developed that provide the ability to

  7. Mg-based compounds for hydrogen and energy storage

    Science.gov (United States)

    Crivello, J.-C.; Denys, R. V.; Dornheim, M.; Felderhoff, M.; Grant, D. M.; Huot, J.; Jensen, T. R.; de Jongh, P.; Latroche, M.; Walker, G. S.; Webb, C. J.; Yartys, V. A.

    2016-02-01

    Magnesium-based alloys attract significant interest as cost-efficient hydrogen storage materials allowing the combination of high gravimetric storage capacity of hydrogen with fast rates of hydrogen uptake and release and pronounced destabilization of the metal-hydrogen bonding in comparison with binary Mg-H systems. In this review, various groups of magnesium compounds are considered, including (1) RE-Mg-Ni hydrides (RE = La, Pr, Nd); (2) Mg alloys with p-elements (X = Si, Ge, Sn, and Al); and (3) magnesium alloys with d-elements (Ti, Fe, Co, Ni, Cu, Zn, Pd). The hydrogenation-disproportionation-desorption-recombination process in the Mg-based alloys (LaMg12, LaMg11Ni) and unusually high-pressure hydrides synthesized at pressures exceeding 100 MPa (MgNi2H3) and stabilized by Ni-H bonding are also discussed. The paper reviews interrelations between the properties of the Mg-based hydrides and p- T conditions of the metal-hydrogen interactions, chemical composition of the initial alloys, their crystal structures, and microstructural state.

  8. WIND SPEED AND ENERGY POTENTIAL ANALYSES

    Directory of Open Access Journals (Sweden)

    A. TOKGÖZLÜ

    2013-01-01

    Full Text Available This paper provides a case study on application of wavelet techniques to analyze wind speed and energy (renewable and environmental friendly energy. Solar and wind are main sources of energy that allows farmers to have the potential for transferring kinetic energy captured by the wind mill for pumping water, drying crops, heating systems of green houses, rural electrification's or cooking. Larger wind turbines (over 1 MW can pump enough water for small-scale irrigation. This study tried to initiate data gathering process for wavelet analyses, different scale effects and their role on wind speed and direction variations. The wind data gathering system is mounted at latitudes: 37° 50" N; longitude 30° 33" E and height: 1200 m above mean sea level at a hill near Süleyman Demirel University campus. 10 minutes average values of two levels wind speed and direction (10m and 30m above ground level have been recorded by a data logger between July 2001 and February 2002. Wind speed values changed between the range of 0 m/s and 54 m/s. Annual mean speed value is 4.5 m/s at 10 m ground level. Prevalent wind

  9. Development potential of wind energy in Turkey

    Directory of Open Access Journals (Sweden)

    İsmet Akova

    2011-07-01

    energy potential, as part of the renewable energy sources of Turkey, are highly important and each of these two sources has the technical potential to cover the electric production in 2008. The recent increase in the number of wind energy power stations can be related to the preparation of Turkish Wind Atlas, the preparation of legal arrangements to support private sector entrepreneurs and the rise in oil prices. Wind energy power stations are active in Marmara, Aegean region and the Mediterreanean region witnessing more constant and strong winds and are anticipated to be founded in other geographical regions as well in the future.

  10. The extended Lennard-Jones potential energy function: A simpler model for direct-potential-fit analysis

    Science.gov (United States)

    Hajigeorgiou, Photos G.

    2016-12-01

    An analytical model for the diatomic potential energy function that was recently tested as a universal function (Hajigeorgiou, 2010) has been further modified and tested as a suitable model for direct-potential-fit analysis. Applications are presented for the ground electronic states of three diatomic molecules: oxygen, carbon monoxide, and hydrogen fluoride. The adjustable parameters of the extended Lennard-Jones potential model are determined through nonlinear regression by fits to calculated rovibrational energy term values or experimental spectroscopic line positions. The model is shown to lead to reliable, compact and simple representations for the potential energy functions of these systems and could therefore be classified as a suitable and attractive model for direct-potential-fit analysis.

  11. Commercializing larger PEM-based hydrogen generators for energy and industrial applications

    Energy Technology Data Exchange (ETDEWEB)

    Moulthrop, L.; Anderson, E.; Chow, O.; Friedland, R.; Porter, S. [Distributed Energy Systems, Wallingford, CT (United States)

    2007-07-01

    As economic, security and environmental drivers converge, there is a demand for larger and better on-site hydrogen generators. This paper outlined the measures needed to scale-up a commercial 12 kg/day proton exchange membrane (PEM) hydrogen generator to a 100 to 500 kg hydrogen per day capacity range. The commercial hydrogen generators using PEM water electrolysis are well proven and currently serve industrial applications worldwide in more than 50 countries. However, North American liquid hydrogen shortages, increasing trucking costs, developing economies with no liquid infrastructure, utilities, and forklift fuel cell fueling applications are all working to increase market demand for commercial on-site hydrogen generation. Water electrolysis was recently identified as the hydrogen technology that will enable solar renewable energy to fill the 17 TW carbon free energy gap projected worldwide by 2050. The scale-up must consider fixed cost as well as operating costs of the electrolyzer and power conditioning, compression and storage ancillaries. It was noted that although commercial applications may be well-satisfied with a 100 kg hydrogen/day PEM hydrogen generator module for the next five years, after that, the 500 kg hydrogen/day module will be required for hydrogen vehicle fueling stations, utility load-leveling, and renewables to hydrogen generation. It was suggested that a paced development effort can be synchronized with evolving fuel cell markets and market price points. The projection of future market price points can be generated using market data and specific cases of the H2A model developed by the United States Department of Energy for electrolysis based fueling. H2A modeling and system analysis identify the components and subsystem development priorities, requirements, and challenges. Codes and standards are maturing to help manufacturers and certification authorities make safe and compliant equipment. It was noted that this development effort is

  12. Theoretical studies of potential energy surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Harding, L.B. [Argonne National Laboratory, IL (United States)

    1993-12-01

    The goal of this program is to calculate accurate potential energy surfaces (PES) for both reactive and nonreactive systems. To do this the electronic Schrodinger equation must be solved. Our approach to this problem starts with multiconfiguration self-consistent field (MCSCF) reference wavefunctions. These reference wavefunctions are designed to be sufficiently flexible to accurately describe changes in electronic structure over a broad range of geometries. Electron correlation effects are included via multireference, singles and doubles configuration interaction (MRSDCI) calculations. With this approach, the authors are able to provide useful predictions of the energetics for a broad range of systems.

  13. World Hydrogen Energy Conference, 5th, Toronto, Canada, July 15-19, 1984, Proceedings

    Science.gov (United States)

    Veziroglu, T. N.; Taylor, J. B.

    Among the topics discussed are thermochemical and hybrid processes for hydrogen production, pyrite-assisted water electrolysis, a hydrogen distribution network for industrial use in Western Europe, the combustion of alternative fuels in spark-ignition engines, the use of fuel cells in locomotive propulsion, hydrogen storage by glass microencapsulation, and FeTi compounds' hydriding. Also covered are plasmachemical methods of energy carrier production, synthetic fuels' production in small scale plants, products found in the anodic oxidation of coal, hydrogen embrittlement, and the regulating step in LaNi5 hydride formation.

  14. The role of boron nitride nanotube as a new chemical sensor and potential reservoir for hydrogen halides environmental pollutants

    Science.gov (United States)

    Yoosefian, Mehdi; Etminan, Nazanin; Moghani, Maryam Zeraati; Mirzaei, Samaneh; Abbasi, Shima

    2016-10-01

    Density functional theory (DFT) studies on the interaction of hydrogen halides (HX) environmental pollutants and the boron nitride nanotubes (BNNTs) have been reported. To exploit the possibility of BNNTs as gas sensors, the adsorption of hydrogen fluoride (HF), hydrogen chloride (HCl) and hydrogen bromide (HBr) on the side wall of armchair (5,5) boron nitride nanotubes have been investigated. B3LYP/6-31G (d) level were used to analyze the structural and electronic properties of investigate sensor. The adsorption process were interpreted by highest occupied molecular orbital (HOMO)-lowest unoccupied molecular orbital (LUMO), quantum theory of atoms in molecules (QTAIM), natural bond orbital (NBO) and molecular electrostatic potential (MEP) analysis. Topological parameters of bond critical points have been used to calculate as measure of hydrogen bond (HB) strength. Stronger binding energy, larger charge transfer and charge density illustrate that HF gas possesses chemisorbed adsorption process. The obtained results also show the strongest HB in HF/BNNT complex. We expect that results could provide helpful information for the design of new BNNTs based sensing devices.

  15. Simple and Efficient System for Combined Solar Energy Harvesting and Reversible Hydrogen Storage.

    Science.gov (United States)

    Li, Lu; Mu, Xiaoyue; Liu, Wenbo; Mi, Zetian; Li, Chao-Jun

    2015-06-24

    Solar energy harvesting and hydrogen economy are the two most important green energy endeavors for the future. However, a critical hurdle to the latter is how to safely and densely store and transfer hydrogen. Herein, we developed a reversible hydrogen storage system based on low-cost liquid organic cyclic hydrocarbons at room temperature and atmospheric pressure. A facile switch of hydrogen addition (>97% conversion) and release (>99% conversion) with superior capacity of 7.1 H2 wt % can be quickly achieved over a rationally optimized platinum catalyst with high electron density, simply regulated by dark/light conditions. Furthermore, the photodriven dehydrogenation of cyclic alkanes gave an excellent apparent quantum efficiency of 6.0% under visible light illumination (420-600 nm) without any other energy input, which provides an alternative route to artificial photosynthesis for directly harvesting and storing solar energy in the form of chemical fuel.

  16. Hydrogen Production from Sea Wave for Alternative Energy Vehicles for Public Transport in Trapani (Italy)

    OpenAIRE

    2016-01-01

    The coupling of renewable energy and hydrogen technologies represents in the mid-term a very interesting way to match the tasks of increasing the reliable exploitation of wind and sea wave energy and introducing clean technologies in the transportation sector. This paper presents two different feasibility studies: the first proposes two plants based on wind and sea wave resource for the production, storage and distribution of hydrogen for public transportation facilities in the West Sicily; t...

  17. Collisions of low-energy antiprotons with molecular hydrogen: ionization, excitation and stopping power

    DEFF Research Database (Denmark)

    Lühr, Armin Christian; Saenz, Alejandro

    2009-01-01

    A time-dependent coupled-channel approach was used to calculate ionization, excitation, and energy-loss cross sections as well as energy spectra for antiproton and proton collisions with molecular hydrogen for impact energies 8 < E < 4000 keV....

  18. United States Energy Association Final Report International Partnership for the Hydrogen Economy Ministerial Conference

    Energy Technology Data Exchange (ETDEWEB)

    William L. Polen

    2006-04-05

    This report summarizes the activities of the United States Energy Association as it conducted the initial Ministerial Meeting of the International Partnership for the Hydrogen Economy in Washington, DC on November 18-21, 2003. The report summarizes the results of the meeting and subsequent support to the Office of Energy Efficiency and Renewable Energy in its role as IPHE Secretariat.

  19. Fiscal 1998 research report on International Clean Energy Network using Hydrogen Conversion (WE-NET). Subtask 2. Research on promotion of international cooperation (research on standardization of hydrogen energy technologies); 1998 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) sub task. 2. Kokusai kyoryoku suishin no tame no chosa kento (suiso energy gijutsu hyojunka ni kansuru chosa kento)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This report summarizes the fiscal 1998 research result on the basic research on standardization of hydrogen energy technologies, and ISO/TC197. As for the standardization, in relation to the hydrogen station in the WE-NET second phase research, the laws related to handling of gaseous hydrogen, and the basic issues on facility and safe handling were studied. As for ISO/TC197, the following draft standards were examined: Fuel supply system interface for liquid hydrogen vehicles, fuel tank for liquid hydrogen vehicles, container for liquid hydrogen transport, specification of hydrogen fuel, hydrogen fuel supply facility for air ports, gaseous hydrogen and hydrogen mixture fuel system for vehicles, gaseous hydrogen fuel connector for vehicles, gaseous hydrogen fuel tank for vehicles, and basic items for hydrogen system safety. Final examination of the fuel supply system interface for liquid hydrogen vehicles, and the specification of hydrogen fuel was finished, and these are scheduled to be registered for ISO. (NEDO)

  20. Salinity-gradient energy driven microbial electrosynthesis of hydrogen peroxide

    DEFF Research Database (Denmark)

    Li, Xiaohu; Angelidaki, Irini; Zhang, Yifeng

    2017-01-01

    Hydrogen peroxide (H2O2) as a strong oxidant, is widely used in various chemical industries and environmental remediation processes. In this study, we developed an innovative method for cost-effective production of H2O2 by using a microbial reverse-electrodialysis electrolysis cell (MREC). In the......Hydrogen peroxide (H2O2) as a strong oxidant, is widely used in various chemical industries and environmental remediation processes. In this study, we developed an innovative method for cost-effective production of H2O2 by using a microbial reverse-electrodialysis electrolysis cell (MREC...

  1. Energy Dense, Lighweight, Durable, Systems for Storage and Delivery of Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Jacky Pruez; Samir Shoukry; Gergis William; Thomas Evans; Hermann Alcazar

    2008-12-31

    The work presented in this report summarizes the current state-of-the-art in on-board storage on compressed gaseous hydrogen as well as the development of analysis tools, methods, and theoretical data for devising high performance design configurations for hydrogen storage. The state-of-the-art in the area of compressed hydrogen storage reveals that the current configuration of the hydrogen storage tank is a seamless cylindrical part with two end domes. The tank is composed of an aluminum liner overwrapped with carbon fibers. Such a configuration was proved to sustain internal pressures up to 350 bars (5,000 psi). Finite-element stress analyses were performed on filament-wound hydrogen storage cylindrical tanks under the effect of internal pressure of 700 bars (10,000 psi). Tank deformations, stress fields, and intensities induced at the tank wall were examined. The results indicated that the aluminum liner can not sustain such a high pressure and initiate the tank failure. Thus, hydrogen tanks ought to be built entirely out of composite materials based on carbon fibers or other innovative composite materials. A spherical hydrogen storage tank was suggested within the scope of this project. A stress reduction was achieved by this change of the tank geometry, which allows for increasing the amount of the stored hydrogen and storage energy density. The finite element modeling of both cylindrical and spherical tank design configurations indicate that the formation of stress concentration zones in the vicinity of the valve inlet as well as the presence of high shear stresses in this area. Therefore, it is highly recommended to tailor the tank wall design to be thicker in this region and tapered to the required thickness in the rest of the tank shell. Innovative layout configurations of multiple tanks for enhanced conformability in limited space have been proposed and theoretically modeled using 3D finite element analysis. Optimum tailoring of fiber orientations and lay

  2. Low energy, high power hydrogen neutral beam for plasma heating

    Energy Technology Data Exchange (ETDEWEB)

    Deichuli, P.; Davydenko, V.; Ivanov, A., E-mail: ivanov@inp.nsk.su; Mishagin, V.; Sorokin, A.; Stupishin, N. [Budker Institute of Nuclear Physics, Prospect Lavrentieva 11, 630090 Novosibirsk (Russian Federation); Korepanov, S.; Smirnov, A. [Tri Alpha Energy, Inc., Foothill Ranch, California 92610 (United States)

    2015-11-15

    A high power, relatively low energy neutral beam injector was developed to upgrade of the neutral beam system of the gas dynamic trap device and C2-U experiment. The ion source of the injector produces a proton beam with the particle energy of 15 keV, current of up to 175 A, and pulse duration of a few milliseconds. The plasma emitter of the ion source is produced by superimposing highly ionized plasma jets from an array of four arc-discharge plasma generators. A multipole magnetic field produced with permanent magnets at the periphery of the plasma box is used to increase the efficiency and improve the uniformity of the plasma emitter. Multi-slit grids with 48% transparency are fabricated from bronze plates, which are spherically shaped to provide geometrical beam focusing. The focal length of the Ion Optical System (IOS) is 3.5 m and the initial beam diameter is 34 cm. The IOS geometry and grid potentials were optimized numerically to ensure accurate beam formation. The measured angular divergences of the beam are ±0.01 rad parallel to the slits and ±0.03 rad in the transverse direction.

  3. Low energy, high power hydrogen neutral beam for plasma heating

    Science.gov (United States)

    Deichuli, P.; Davydenko, V.; Ivanov, A.; Korepanov, S.; Mishagin, V.; Smirnov, A.; Sorokin, A.; Stupishin, N.

    2015-11-01

    A high power, relatively low energy neutral beam injector was developed to upgrade of the neutral beam system of the gas dynamic trap device and C2-U experiment. The ion source of the injector produces a proton beam with the particle energy of 15 keV, current of up to 175 A, and pulse duration of a few milliseconds. The plasma emitter of the ion source is produced by superimposing highly ionized plasma jets from an array of four arc-discharge plasma generators. A multipole magnetic field produced with permanent magnets at the periphery of the plasma box is used to increase the efficiency and improve the uniformity of the plasma emitter. Multi-slit grids with 48% transparency are fabricated from bronze plates, which are spherically shaped to provide geometrical beam focusing. The focal length of the Ion Optical System (IOS) is 3.5 m and the initial beam diameter is 34 cm. The IOS geometry and grid potentials were optimized numerically to ensure accurate beam formation. The measured angular divergences of the beam are ±0.01 rad parallel to the slits and ±0.03 rad in the transverse direction.

  4. Electric vehicles and renewable energy in the transport sector - energy system consequences. Main focus: Battery electric vehicles and hydrogen based fuel cell vehicles

    DEFF Research Database (Denmark)

    Nielsen, L.H.; Jørgensen K.

    2000-01-01

    The aim of the project is to analyse energy, environmental and economic aspects of integrating electric vehicles in the future Danish energy system. Consequences of large-scale utilisation of electric vehicles are analysed. The aim is furthermore toillustrate the potential synergistic interplay...... between the utilisation of electric vehicles and large-scale utilisation of fluctuating renewable energy resources, such as wind power. Economic aspects for electric vehicles interacting with a liberalisedelectricity market are analysed. The project focuses on battery electric vehicles and fuel cell...... vehicles based on hydrogen. Based on assumptions on the future technical development for battery electric vehicles, fuel cell vehicles on hydrogen, and forthe conventional internal combustion engine vehicles, scenarios are set up to reflect expected options for the long-term development of road transport...

  5. Recent progress in hydrogen storage

    Directory of Open Access Journals (Sweden)

    Ping Chen

    2008-12-01

    Full Text Available The ever-increasing demand for energy coupled with dwindling fossil fuel resources make the establishment of a clean and sustainable energy system a compelling need. Hydrogen-based energy systems offer potential solutions. Although, in the long-term, the ultimate technological challenge is large-scale hydrogen production from renewable sources, the pressing issue is how to store hydrogen efficiently on board hydrogen fuel-cell vehicles1,2.

  6. Hydrogen energy program (we-net) of Japan ministry of international trade and industry; Programme hydrogene (we-net) du ministere du commerce international et de l'industrie du Japon

    Energy Technology Data Exchange (ETDEWEB)

    Fukuda, K. [Institute of Applied Energy (Japan)

    2000-07-01

    The Kyoto Protocol determined at COP3 in Dec 1997 is forcing Japan to reduce the emission of greenhouse gases by 6% in the year 2008-2012 compared to 1990 level. Concern with potential global climate change will become greater within the next decade, forcing society to move toward energies that will minimize the emission of greenhouse gases. Hydrogen energy is considered to present a potential effective option for achieving the greenhouse gas minimization. The MITI (Ministry of International Trade and Industry) of Japanese Government is promoting the WE-NET (World Energy Network System) Project (Phase I: 1993-1998, Phase II: 1999-2003) which envisions (1) construction of a global energy network for effective supply, transportation, storage and utilization of renewable energy using hydrogen as an energy carrier as a long-term option of sustainable energy economy, and (2) promotion of market entry of hydrogen energy in near and/or mid future even before construction of a WE-NET system. The present status of the research and development activities in the WE-NET Project will be presented with an emphasis on hydrogen production technology. (author)

  7. Sunlight to hydrogen conversion: Design optimization and energy management of concentrated photovoltaic (CPV-Hydrogen) system using micro genetic algorithm

    KAUST Repository

    Burhan, Muhammad

    2016-02-14

    Owing to the intermittent solar irradiance from cloud cover in the diurnal period and unavailability at night time, the practical design of a solar system requires energy backup storage for an uninterrupted supply or for off-grid operation. However, for highly efficient CPV (concentrated photovoltaic) system, the literature is lacking for energy management and optimization algorithm and tool for standalone operation. In this paper, a system with CPV and electrolyser is presented where beam irradiance of sunlight is harnessed to convert the instantaneously generated electricity into useful Hydrogen/Oxygen gas, where they can be stored and re-used for downstream applications such as the fuel cells, etc. The multi-variable design and multi-objective optimization strategies are proposed and presented for a standalone operation of the CPV-Hydrogen system as well as their system performances, particularly electrical rating of CPV based upon the real weather data of Singapore. © 2016 Elsevier Ltd.

  8. Marrying gas power and hydrogen energy: A catalytic system for combining methane conversion and hydrogen generation

    NARCIS (Netherlands)

    Beckers, J.; Gaudillère, C.; Farrusseng, D.; Rothenberg, G.

    2009-01-01

    Ceria-based catalysts are good candidates for integrating methane combustion and hydrogen generation. These new, tuneable catalysts are easily prepared. They are robust inorganic crystalline materials, and perform well at the 400 °C-550 °C range, in some cases even without precious metals. This make

  9. Socio-cultural barriers to the development of a sustainable energy system - the case of hydrogen

    DEFF Research Database (Denmark)

    Petersen, Lars Kjerulf; Andersen, Anne Holst

    Any transition to a more sustainable energy system, radically reducing greenhouse gas emissions, is bound to run in to a host of different barriers - technological and economic, but also socio-cultural. This will also be the case for any large-scale application of hydrogen as energy carrier......, especially if the system is going to be based on renewable energy sources. The aim of these research notes is to review and discuss major socio-cultural barriers to new forms of energy supply in general and to hydrogen specifically. Reaching sufficient reductions in greenhouse gas emissions may require more...

  10. Destabilisation of magnesium hydride by germanium as a new potential multicomponent hydrogen storage system.

    Science.gov (United States)

    Walker, Gavin S; Abbas, Marwa; Grant, David M; Udeh, Chima

    2011-07-28

    MgH(2) has too high an operating temperature for many hydrogen storage applications. However, MgH(2) ball-milled with Ge leads to a thermodynamic destabilisation of >50 kJ mol(-1)(H(2)). This has dramatically reduced the temperature of dehydrogenation to 130 °C, opening up the potential for Mg-based multicomponent systems as hydrogen stores for a range of applications.

  11. Energy research programmes on hydrogen and fuel cells for the period 2008 - 2011; Energieforschungsprogramme Wasserstoff und Brennstoffzellen fuer die Jahre 2008-2011

    Energy Technology Data Exchange (ETDEWEB)

    Gut, A.; Luzzi, A.; Spirig, M.

    2007-12-15

    This comprehensive report for the Swiss Federal Office of Energy (SFOE) reports on the concept for research in Switzerland in the area of hydrogen and fuel cells for the period 2008 - 2011. The starting position is noted with a short review of the vision of a 'hydrogen economy'. The present-day production of hydrogen for non-energetic purposes is noted and the current state-of-the-art is discussed. The potential in Switzerland for the production of hydrogen and the use of fuel cells is discussed, as are research efforts and pilot projects in these areas. Private and public expenditure in the area is reviewed. The aims and the focal points of research during the period 2008 - 2011 are discussed, as are potentials both in Switzerland as well as world-wide. Further topics dealt with include system integration and hydrogen storage, service life, reliability and cost factors.

  12. Metabolic flux analysis of the hydrogen production potential in Synechocystis sp. PCC6803

    Energy Technology Data Exchange (ETDEWEB)

    Navarro, E. [Departamento de Lenguajes y Ciencias de la Computacion, Campus de Teatrinos, Universidad de Malaga, 29071 Malaga (Spain); Montagud, A.; Fernandez de Cordoba, P.; Urchueguia, J.F. [Instituto Universitario de Matematica Pura y Aplicada, Universidad Politecnica de Valencia, Camino de Vera 14, 46022 Valencia (Spain)

    2009-11-15

    Hydrogen is a promising energy vector; however, finding methods to produce it from renewable sources is essential to allow its wide-scale use. In that line, biological hydrogen production, although it is considered as a possible alternative, requires substantial improvements to overcome its present low yields. In that direction, genetic manipulation probably will play a central role and from that point of view metabolic flux analysis (MFA) constitutes an important tool to guide a priori most suitable genetic modifications oriented to a hydrogen yield increase. In this work MFA has been applied to analyze hydrogen photoproduction of Synechocystis sp. PCC6803. Flux analysis was carried out based on literature data and several basic fluxes were estimated in different growing conditions of the system. From this analysis, an upper limit for hydrogen photoproduction has been determined indicating a wide margin for improvement. MFA was also used to find a feasible operating space for hydrogen production, which avoids oxygen inhibition, one of the most important limitations to make hydrogen production cost effective. In addition, a set of biotechnological strategies are proposed that would be consistent with the performed mathematical analysis. (author)

  13. The Wind Energy Potential of Iceland

    DEFF Research Database (Denmark)

    Nawri, Nikolai; Petersen, Guðrún Nína; Björnsson, Halldór

    2014-01-01

    Downscaling simulations performed with theWeather Research and Forecasting (WRF) model were used to determine the large-scale wind energy potential of Iceland. Local wind speed distributions are represented by Weibull statistics. The shape parameter across Iceland varies between 1.2 and 3.......6, with the lowest values indicative of near-exponential distributions at sheltered locations, and the highest values indicative of normal distributions at exposed locations in winter. Compared with summer, average power density in winter is increased throughout Iceland by a factor of 2.0e5.5. In any season......, there are also considerable spatial differences in average wind power density. Relative to the average value within 10 km of the coast, power density across Iceland varies between 50 and 250%, excluding glaciers, or between 300 and 1500 W m_2 at 50 m above ground level in winter. At intermediate elevations...

  14. Effects of the interaction between the magnetic moments of the proton and electron on the energy states of hydrogen atom

    CERN Document Server

    Dolocan, Voicu

    2014-01-01

    We make a comparison between the energy levels of the hydrogen atom, calculated by using standard methods, and that by using a modified Coulomb potential due to the interaction between the magnetic moments of the proton and electron. In this later method we use to ways. One is that in which we solve the Schroedinger equation with the modified Coulomb potential and some constraint conditions. The other is that in which we expand the modified Coulomb potential in Taylor series. The obtained results show that the first way gives a better agreement with experimental data.

  15. Hydrogen Isotopes in Amino Acids and Soils Offer New Potential to Study Complex Processes

    Science.gov (United States)

    Fogel, M. L.; Newsome, S. D.; Williams, E. K.; Bradley, C. J.; Griffin, P.; Nakamoto, B. J.

    2016-12-01

    Hydrogen isotopes have been analyzed extensively in the earth and biogeosciences to trace water through various environmental systems. The majority of the measurements have been made on water in rocks and minerals (inorganic) or non-exchangeable H in lipids (organic), important biomarkers that represent a small fraction of the organic molecules synthesized by living organisms. Our lab has been investigating hydrogen isotopes in amino acids and complex soil organic matter, which have traditionally been thought to be too complex to interpret owing to complications from potentially exchangeable hydrogen. For the amino acids, we show how hydrogen in amino acids originates from two sources, food and water, and demonstrate that hydrogen isotopes can be routed directly between organisms. Amino acid hydrogen isotopes may unravel cycling in extremophiles in order to discover novel biochemical pathways central to the organism. For soil organic matter, recent approaches to understanding the origin of soil organic matter are pointing towards root exudates along with microbial biomass as the source, rather than aboveground leaf litter. Having an isotope tracer in very complex, potentially exchangeable organic matter can be handled with careful experimentation. Although no new instrumentation is being used per se, extension of classes of organic matter to isotope measurements has potential to open up new doors for understanding organic matter cycling on earth and in planetary materials.

  16. Geothermal Energy: Delivering on the Global Potential

    Directory of Open Access Journals (Sweden)

    Paul L. Younger

    2015-10-01

    Full Text Available Geothermal energy has been harnessed for recreational uses for millennia, but only for electricity generation for a little over a century. Although geothermal is unique amongst renewables for its baseload and renewable heat provision capabilities, uptake continues to lag far behind that of solar and wind. This is mainly attributable to (i uncertainties over resource availability in poorly-explored reservoirs and (ii the concentration of full-lifetime costs into early-stage capital expenditure (capex. Recent advances in reservoir characterization techniques are beginning to narrow the bounds of exploration uncertainty, both by improving estimates of reservoir geometry and properties, and by providing pre-drilling estimates of temperature at depth. Advances in drilling technologies and management have potential to significantly lower initial capex, while operating expenditure is being further reduced by more effective reservoir management—supported by robust models—and increasingly efficient energy conversion systems (flash, binary and combined-heat-and-power. Advances in characterization and modelling are also improving management of shallow low-enthalpy resources that can only be exploited using heat-pump technology. Taken together with increased public appreciation of the benefits of geothermal, the technology is finally ready to take its place as a mainstream renewable technology, exploited far beyond its traditional confines in the world’s volcanic regions.

  17. The Wind Energy Potential of Kurdistan, Iran.

    Science.gov (United States)

    Arefi, Farzad; Moshtagh, Jamal; Moradi, Mohammad

    2014-01-01

    In the current work by using statistical methods and available software, the wind energy assessment of prone regions for installation of wind turbines in, Qorveh, has been investigated. Information was obtained from weather stations of Baneh, Bijar, Zarina, Saqez, Sanandaj, Qorveh, and Marivan. The monthly average and maximum of wind speed were investigated between the years 2000-2010 and the related curves were drawn. The Golobad curve (direction and percentage of dominant wind and calm wind as monthly rate) between the years 1997-2000 was analyzed and drawn with plot software. The ten-minute speed (at 10, 30, and 60 m height) and direction (at 37.5 and 10 m height) wind data were collected from weather stations of Iranian new energy organization. The wind speed distribution during one year was evaluated by using Weibull probability density function (two-parametrical), and the Weibull curve histograms were drawn by MATLAB software. According to the average wind speed of stations and technical specifications of the types of turbines, the suitable wind turbine for the station was selected. Finally, the Divandareh and Qorveh sites with favorable potential were considered for installation of wind turbines and construction of wind farms.

  18. Hydrogen production by hydrogen sulfide splitting using concentrated solar energy - Thermodynamics and economic evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Villasmil, W. [Department of Mechanical and Process Engineering, ETH Zurich, 8092 Zurich (Switzerland); Steinfeld, A. [Department of Mechanical and Process Engineering, ETH Zurich, 8092 Zurich (Switzerland); Solar Technology Laboratory, Paul Scherrer Institute, 5232 Villigen PSI (Switzerland)

    2010-11-15

    Thermodynamic and economic analyses were carried out to evaluate the use of concentrated solar energy for driving the endothermic dissociation reaction H{sub 2}S {yields} H{sub 2} + 0.5S{sub 2}. Three different schemes were assessed: (1) a pure solar process; (2) a hybrid process, which uses both solar and natural gas combustion as the energy sources of high-temperature process heat; and (3) the Claus process. This study indicates that the pure solar process has the potential of lowering the disposal costs of H{sub 2}S vis-a-vis the conventional Claus process while co-producing H{sub 2} without concomitant CO{sub 2} emissions. An economic assessment for a 40 MWth chemical plant using solar tower technology indicates savings of approximately 45% in comparison to the Claus process. Solar H{sub 2} production is estimated at a cost in the range of 0.061-0.086 $/kW h, based on its lower heating value and without credit attributed to H{sub 2}S disposal. A sensitivity analysis revealed that the quench efficiency represents the parameter with the highest impact on the economics of the process. A hybrid natural gas/solar plant design able to operate 24 h-a-day is predicted to reduce the H{sub 2} production cost to 0.058 $/kW h at current fuel prices, however, at the expense of increased complexity related with the hybrid reactor design and operation plus the associated CO{sub 2} emissions of 0.42 kg/kW h. (author)

  19. 18{sup th} world hydrogen energy conference 2010 (WHEC 2010). Proceedings. Speeches and plenary talks

    Energy Technology Data Exchange (ETDEWEB)

    Stolten, Detlef; Emonts, Bernd (eds.)

    2012-07-03

    the broad spectrum of potential readers. The editors gratefully acknowledge the strong and sustained support of the State of North Rhine Westphalia and the EnergieAgentur.NRW.

  20. POTENTIAL FOR WASTEWATER MANAGEMENT USING ENERGY CROPS

    Directory of Open Access Journals (Sweden)

    Alistair R. McCRACKEN

    2015-04-01

    Full Text Available In most countries within Europe there are numerous small rural Waste Water Treatment Works (WWTWs often serving a small number of people equivalents (PEs. It is usually impractical and expensive to upgrade such WWTWs and yet they are often delivering potentially highly polluting effluent into streams and rivers. Short Rotation Coppice (SRC willow, grown as an energy source, may be an ideal crop for the bioremediation of a variety of effluents and wastewater streams. As part of an EU funded (INTERREG IVA project called ANSWER (Agricultural Need for Sustainable Willow Effluent Recycling four Proof of Concept irrigation schemes were established ranging in size from 5 to 15 ha. One of the larger of these at Bridgend, Co. Donegal, Republic of Ireland was planted in spring 2013 and has been irrigated with municipal effluent since June 2014. Over 19,000 m3 of effluent has been applied to the willow thus preventing 617 kg N and 28.5 kg P from being discharged to a neighbouring stream. Using SRC willow for the bioremediation of effluent from small rural WWWTs offers a sustainable, cost-effective and practical solution to wastewater management in many countries. There may be also potential to use willow for the bioremediation of landfill leachates, within the footprint of the landfill site.

  1. Role and potential of renewable energy and energy efficiency for global energy supply

    Energy Technology Data Exchange (ETDEWEB)

    Krewitt, Wolfram; Nienhaus, Kristina [German Aerospace Center e.V. (DLR), Stuttgart (Germany); Klessmann, Corinna; Capone, Carolin; Stricker, Eva [Ecofys Germany GmbH, Berlin (Germany); Graus, Wina; Hoogwijk, Monique [Ecofys Netherlands BV, Utrecht (Netherlands); Supersberger, Nikolaus; Winterfeld, Uta von; Samadi, Sascha [Wuppertal Institute for Climate, Environment and Energy GmbH, Wuppertal (Germany)

    2009-12-15

    The analysis of different global energy scenarios in part I of the report confirms that the exploitation of energy efficiency potentials and the use of renewable energies play a key role in reaching global CO2 reduction targets. An assessment on the basis of a broad literature research in part II shows that the technical potentials of renewable energy technologies are a multiple of today's global final energy consumption. The analysis of cost estimates for renewable electricity generation technologies and even long term cost projections across the key studies in part III demonstrates that assumptions are in reasonable agreement. In part IV it is shown that by implementing technical potentials for energy efficiency improvements in demand and supply sectors by 2050 can be limited to 48% of primary energy supply in IEA's ''Energy Technology Perspectives'' baseline scenario. It was found that a large potential for cost-effective measures exists, equivalent to around 55-60% of energy savings of all included efficiency measures (part V). The results of the analysis on behavioural changes in part VI show that behavioural dimensions are not sufficiently included in energy scenarios. Accordingly major research challenges are revealed. (orig.)

  2. Energetic multifunctionalized nitraminopyrazoles and their ionic derivatives: ternary hydrogen-bond induced high energy density materials.

    Science.gov (United States)

    Yin, Ping; Parrish, Damon A; Shreeve, Jean'ne M

    2015-04-15

    Diverse functionalization was introduced into the pyrazole framework giving rise to a new family of ternary hydrogen-bond induced high energy density materials. By incorporating extended cationic interactions, nitramine-based ionic derivatives exhibit good energetic performance and enhanced molecular stability. Performance parameters including heats of formation and detonation properties were calculated by using Gaussian 03 and EXPLO5 v6.01 programs, respectively. It is noteworthy to find that 5-nitramino-3,4-dinitropyrazole, 4, has a remarkable measured density of 1.97 g cm(-3) at 298 K, which is consistent with its crystal density (2.032 g cm(-3), 150 K), and ranks highest among azole-based CHNO compounds. Energetic evaluation indicates that, in addition to the molecular compound 4, some ionic derivatives, 9, 11, 12, 17, 19, and 22, also have high densities (1.83-1.97 g cm(-3)), excellent detonation pressures and velocities (P, 35.6-41.6 GPa; vD, 8880-9430 m s(-1)), as well as acceptable impact and friction sensitivities (IS, 4-30 J; FS, 40-240 N). These attractive features highlight the application potential of nitramino hydrogen-bonded interactions in the design of advanced energetic materials.

  3. Rototranslational collision-induced absorption and collision-induced light scattering spectra of molecular hydrogen using isotropic intermolecular potentials

    Energy Technology Data Exchange (ETDEWEB)

    El-Kader, M.S.A., E-mail: Mohamedsay68@hotmail.com [Department of Engineering Mathematics and Physics, Faculty of Engineering, Cairo University, Giza 12211 (Egypt); Maroulis, G. [Department of Chemistry, University of Patras, GR-26500 Patras (Greece); Bich, E. [Institut fuer Chemie, Universitaet Rostock Albert-Einstein-Strasse 3a, D-18059 Rostock (Germany)

    2012-07-25

    Highlights: Black-Right-Pointing-Pointer We have determined an isotropic intermolecular potential for the interaction of hydrogen. Black-Right-Pointing-Pointer The thermophysical and transport properties are calculated for this system. Black-Right-Pointing-Pointer The rovibrational energy levels and scattering cross-sections are determined. Black-Right-Pointing-Pointer We have adopted a model for the induced dipole moment {mu}(r) with adjustable parameters. Black-Right-Pointing-Pointer The quantum lineshapes of absorption and scattering are calculated. -- Abstract: Quantum mechanical lineshapes of collision-induced absorption (CIA) at different temperatures and of collision-induced light scattering (CILS) at room temperature are computed for gaseous molecular hydrogen using theoretical values for induced dipole moments and pair-polarizability trace and anisotropy as input. Comparison with measured spectra of absorption, isotropic and anisotropic light scattering shows satisfactory agreement, for which the uncertainty in measurement of its spectral moments is seen to be large. Empirical models of the dipole moment and pair-polarizability trace and anisotropy which reproduce the experimental spectra and the first three spectral moments more closely than the fundamental theory are also given. Good agreement between computed and experimental lineshapes of both absorption and scattering is obtained when potential models which are constructed from the thermophysical, transport, total scattering cross-section and spectroscopic properties are used. Also, the use of the new potential in lattice dynamic calculations yields good results for several properties of solid hydrogen.

  4. Computation of hyperfine energies of hydrogen, deuterium and tritium quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Çakır, Bekir, E-mail: bcakir@selcuk.edu.tr [Physics Department, Faculty of Science, Selcuk University, Campus 42075, Konya (Turkey); Özmen, Ayhan [Physics Department, Faculty of Science, Selcuk University, Campus 42075, Konya (Turkey); Yakar, Yusuf, E-mail: yuyakar@yahoo.com [Physics Department, Faculty of Arts and Science, Aksaray University, Campus 68100, Aksaray (Turkey)

    2016-01-15

    The hyperfine energies and hyperfine constants of the ground and excited states of hydrogen, deuterium and tritium quantum dots(QDs) are calculated. Quantum genetic algorithm (QGA) and Hartree–Fock–Roothaan (HFR) methods are employed to calculate the unperturbed wave functions and energy eigenvalues. The results show that in the medium and strong confinement regions the hyperfine energy and hyperfine constant are strongly affected by dot radius, impurity charge, electron spin orientation, impurity spin and impurity magnetic moment. Besides, in all dot radii, the hyperfine splitting and hyperfine constant of the confined hydrogen and tritium atoms are approximately equivalent to each other and they are greater than the confined deuterium atom.

  5. Computation of hyperfine energies of hydrogen, deuterium and tritium quantum dots

    Science.gov (United States)

    Çakır, Bekir; Özmen, Ayhan; Yakar, Yusuf

    2016-01-01

    The hyperfine energies and hyperfine constants of the ground and excited states of hydrogen, deuterium and tritium quantum dots(QDs) are calculated. Quantum genetic algorithm (QGA) and Hartree-Fock-Roothaan (HFR) methods are employed to calculate the unperturbed wave functions and energy eigenvalues. The results show that in the medium and strong confinement regions the hyperfine energy and hyperfine constant are strongly affected by dot radius, impurity charge, electron spin orientation, impurity spin and impurity magnetic moment. Besides, in all dot radii, the hyperfine splitting and hyperfine constant of the confined hydrogen and tritium atoms are approximately equivalent to each other and they are greater than the confined deuterium atom.

  6. Energy potential of region and its quantitative assessment

    Directory of Open Access Journals (Sweden)

    Tatyana Aleksandrovna Kovalenko

    2013-09-01

    Full Text Available The purpose of the article is the development of the concept of the energy potential of the region (EPR, the analysis of the existing structure of relationships for the EPR elements in Ukraine and improvement of a quantitative assessment of energy potential of the region (country. The methods of an assessment of the existing condition of energy potential of the territory are the subject matter of the research. As a result of the analysis of concept’s definitions of energy potential of the region, it has further development and included the consumer potential of energy resources and capacity of management. The structure of relationships between elements of energy potential is developed for the Ukraine region. The new economic indicator — the realized energy potential is offered for an EPR assessment. By means of this indicator, the assessment of energy potential for the different countries of the world and a number of Ukraine areas of is performed.

  7. A two-stage bio hydrogen process for energy generation from municipal solid wastes

    Energy Technology Data Exchange (ETDEWEB)

    Acevedo-Benitez, J. a.; Poggi-Varaldo, H. M.

    2009-07-01

    Energy supply and disposal of solid wastes are two big challenges that great cities face at the present time. Several experts have shown that hydrogen is the fuel of the future, due to their high energy content (three times more than that of the gasoline) and its clean combustion. (Author)

  8. NaBH4 generator integrated with energy conversion device based on hydrogen combustion

    Science.gov (United States)

    Netskina, O. V.; Fursenko, R. V.; Komova, O. V.; Odintsov, E. S.; Simagina, V. I.

    2015-01-01

    A thermoelectric energy conversion device operating on the heat generated by a hydrogen diffusion microflame has been developed. For the first time, a NaBH4 hydrogen generator has been employed as a source of fuel for such type of power generator. A 1%Ru-3%Co/Sibunit catalyst ensures hydrogen generation at a rate of 3 cm3 s-1 during 3 h. Power and efficiency characteristics of the integrated system consisting of a hydrogen generator and an energy converter based on combustion technologies have been studied experimentally. The total efficiency and the generated power of the system were measured to achieve values of up to 1.23% and 0.25 W, respectively. Ways to further improve the system's power output and efficiency characteristics have been discussed.

  9. Potential of renewable energy systems in China

    DEFF Research Database (Denmark)

    Liu, Wen; Lund, Henrik; Mathiesen, Brian Vad

    2011-01-01

    Along with high-speed economic development and increasing energy consumption, the Chinese Government faces a growing pressure to maintain the balance between energy supply and demand. In 2009, China has become both the largest energy consumer and CO2 emitting country in the world. In this case...... system has demonstrated the possibility of converting into a 100% renewable energy system. This paper discusses the perspective of renewable energy in China firstly, and then analyses whether it is suitable to adopt similar methodologies applied in other countries as China approaches a renewable energy......, the inappropriate energy consumption structure should be changed. As an alternative, a suitable infrastructure for the implementation of renewable energy may serve as a long-term sustainable solution. The perspective of a 100% renewable energy system has been analyzed and discussed in some countries previously...

  10. Socio-cultural barriers to the development of a sustainable energy system - the case of hydrogen

    DEFF Research Database (Denmark)

    Petersen, Lars Kjerulf; Andersen, Anne Holst

    Any transition to a more sustainable energy system, radically reducing greenhouse gas emissions, is bound to run in to a host of different barriers - technological and economic, but also socio-cultural. This will also be the case for any large-scale application of hydrogen as energy carrier......, especially if the system is going to be based on renewable energy sources. The aim of these research notes is to review and discuss major socio-cultural barriers to new forms of energy supply in general and to hydrogen specifically. Reaching sufficient reductions in greenhouse gas emissions may require more...... than large-scale dissemination of renewable energy sources. Also reductions or moderations in energy demand may be necessary. Hence, a central point in the research notes is to consider not only socio-cultural obstacles for changing technologies in energy production, distribution and consumption...

  11. Energy spectrum of the hydrogen atom in a space with one compactified extra dimension, R3 ×S1

    Science.gov (United States)

    Bureš, Martin

    2015-12-01

    We investigate the consequences of one extra compactified dimension for the energy spectrum of the non-relativistic hydrogen atom with a potential defined by Gauss' law, i.e. proportional to 1 /| x | 2 in non-compactified 4d space. The calculations were performed numerically by diagonalizing the Hamiltonian in two different sets of basis vectors. The energy levels and electron probability density are plotted as a function of the compactification radius. The occurrence of several physical effects is discussed and interpreted.

  12. A stress tensor eigenvector projection space for the (H2O)5 potential energy surface

    Science.gov (United States)

    Xu, Tianlv; Farrell, James; Momen, Roya; Azizi, Alireza; Kirk, Steven R.; Jenkins, Samantha; Wales, David J.

    2017-01-01

    A stress tensor eigenvector projection space is created to describe reaction pathways on the (H2O)5 MP2 potential energy surface. Evidence for the stabilizing role of the O--O bonding interactions is found from the length of the recently introduced stress tensor trajectory in the stress tensor eigenvector projection space. The stress tensor trajectories demonstrate coupling behavior of the adjoining covalent (σ) O-H and hydrogen bonds due to sharing of covalent character. Additionally, the stress tensor trajectories can show dynamic coupling effects of pairs of σ bonds and of pairs of hydrogen bonds.

  13. Alaska's renewable energy potential.

    Energy Technology Data Exchange (ETDEWEB)

    2009-02-01

    This paper delivers a brief survey of renewable energy technologies applicable to Alaska's climate, latitude, geography, and geology. We first identify Alaska's natural renewable energy resources and which renewable energy technologies would be most productive. e survey the current state of renewable energy technologies and research efforts within the U.S. and, where appropriate, internationally. We also present information on the current state of Alaska's renewable energy assets, incentives, and commercial enterprises. Finally, we escribe places where research efforts at Sandia National Laboratories could assist the state of Alaska with its renewable energy technology investment efforts.

  14. An estimation of the capacity to produce hydrogen by wasted hydroelectric energy for the three largest Brazilian hydroelectric

    Energy Technology Data Exchange (ETDEWEB)

    Padilha, Janine C.; Trindade, Leticia G. da; Souza, Roberto F. de [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Inst. of Chemistry], Email: janine@iq.ufrgs.br; Miguel, Marcelo [Itaipu Binacional, Foz do Iguacu, PR (Brazil)

    2010-07-01

    The use of water wasted in hydroelectric plants as normalization dam excess, which constitute a hydrodynamic potential useful to generate electric energy which can be subsequently used to produce hydrogen and its subsequent consumption in fuel cells has been considered as an alternative for hydraulic energy-rich countries like Brazil. The case is examined in which all the water wasted in the hydroelectric plants, spilled by dam gates to maintain acceptable water levels, from the 3 largest Brazilian hydroelectric plants was used to produce hydrogen. During the year of 2008, the electric energy produced from this utilization would have been equivalent to 52.8 TWh, an amount that corresponds to an increase of ca. 15% of the total electric energy produced in the country. Furthermore, if this amount of hydrogen was used in the replacement of internal combustion vehicles by fuel cells, this would have prevented the production of 2.26 x 10{sup 7} ton of Co{sub 2} per year. This plan would also significantly decrease production and release of greenhouse gases. (author)

  15. Vibrational Distribution of Hydrogen Molecular Ions in High-Energy Ionization Processes

    Institute of Scientific and Technical Information of China (English)

    CHEN Shao-Hao; HE Chun-Long; CHEN Chao; LI Jia-Ming

    2005-01-01

    @@ A theoretical time-dependent wave-packet dynamics method is applied to calculate the distribution of vibrational states of hydrogen molecular ions produced in high-energy ionization processes of hydrogen molecules. The isotope effect is elucidated in agreement with the available experimental measurements. Our proposed method should be readily applied in other atomic and molecular processes considering great advances in electronic computation science and technology.

  16. Solar-energy potential in Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Sozen, Adnan; Ozalp, Mehmet [Gazi Univ., Mechanical Education Dept., Ankara (Turkey); Arcaklioglu, Erol [Kirikkale Univ., Mechanical Engineering Dept., Kirikkale (Turkey); Kanit, E. Galip [Turkish State Meteorological Office, Ankara (Turkey)

    2005-04-01

    In this study, a new formula based on meteorological and geographical data was developed to determine the solar-energy potential in Turkey using artificial neural-networks (ANNs). Scaled conjugate gradient (SCG) and Levenberg-Marquardt (LM) learning algorithms and a logistic sigmoid transfer function were used in the network. Meteorological data for the last four years (2000-2003) from 18 cities (Bilecik, Kirsehir, Akhisar, Bingol, Batman, Bodrum, Uzunkopru, Sile, Bartin, Yalova, Horasan, Polatli, Malazgirt, Koycegiz, Manavgat, Dortyol, Karatas and Birecik) spread over Turkey were used as data in order to train the neural network. Meteorological and geographical data (latitude, longitude, altitude, month, mean sunshine duration, and mean temperature) were used in the input layer of the network. Solar radiation is the output layer. One-month test data for each city was used, and these months data were not used for training. The results show that the maximum mean absolute percentage error (MAPE) was found to be 3.448% and the R{sup 2} value 0.9987 for Polatli. The best approach was found for Kirsehir (MAPE=1.2257, R{sup 2}=0.9998). The MAPE and R{sup 2} for the testing data were 3.3477 and 0.998534, respectively. The ANN models show greater accuracy for evaluating solar-resource possibilities in regions where a network of monitoring stations has not been established in Turkey. This study confirms the ability of the ANN to predict solar-radiation values precisely (Author)

  17. Solar-energy potential in Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Soezen, Adnan; Arcaklioglu, Erol; Oezalp, Mehmet; Kanit, E. Galip

    2005-04-01

    In this study, a new formula based on meteorological and geographical data was developed to determine the solar-energy potential in Turkey using artificial neural-networks (ANNs). Scaled conjugate gradient (SCG) and Levenberg-Marquardt (LM) learning algorithms and a logistic sigmoid transfer function were used in the network. Meteorological data for the last four years (2000 {yields} 2003) from 18 cities (Bilecik, Kirsehir, Akhisar, Bingoel, Batman, Bodrum, Uzunkoeprue, Sile, Bartin, Yalova, Horasan, Polatli, Malazgirt, Koeycegiz, Manavgat, Doertyol, Karatas and Birecik) spread over Turkey were used as data in order to train the neural network. Meteorological and geographical data (latitude, longitude, altitude, month, mean sunshine duration, and mean temperature) were used in the input layer of the network. Solar radiation is the output layer. One-month test data for each city was used, and these months data were not used for training. The results show that the maximum mean absolute percentage error (MAPE) was found to be 3.448% and the R{sup 2} value 0.9987 for Polatli. The best approach was found for Kirsehir (MAPE=1.2257, R{sup 2}=0.9998). The MAPE and R{sup 2} for the testing data were 3.3477 and 0.998534, respectively. The ANN models show greater accuracy for evaluating solar-resource possibilities in regions where a network of monitoring stations has not been established in Turkey. This study confirms the ability of the ANN to predict solar-radiation values precisely.

  18. Prediction of activation energies for hydrogen abstraction by cytochrome p450

    DEFF Research Database (Denmark)

    Olsen, Lars; Rydberg, Patrik; Rod, Thomas Holm

    2006-01-01

    We have estimated the activation energy for hydrogen abstraction by compound I in cytochrome P450 for a diverse set of 24 small organic substrates using state-of-the-art density functional theory (B3LYP). We then show that these results can be reproduced by computationally less demanding methods......, for example, by using small organic mimics of compound I with both B3LYP and the semiempirical AM1 method (mean absolute error of 3-4 kJ/mol) or by calculating the bond dissociation energy, without relaxation of the radical (B3LYP) or estimated from three-point fit to a Morse potential (AM1; errors of 4 and 5...... kJ/mol, respectively). We can assign activation energies of 74, 61, 53, 47, and 30 kJ/mol to primary carbons, secondary/tertiary carbons, carbons with adjacent sp(2) or aromatic groups, ethers/thioethers, and amines, respectively, which gives a very simple and predictive model. Finally, some...

  19. Potential energy savings and thermal comfort

    DEFF Research Database (Denmark)

    Jensen, Karsten Ingerslev; Rudbeck, Claus Christian; Schultz, Jørgen Munthe

    1996-01-01

    Results of simulations carried out on four different buildings with common windows, commercial low-energy windows and xerogel windows are presented. The results are the annual energy consumption for space heating and the indoor air temperature level....

  20. Renewable Energy Potential for New Mexico

    Science.gov (United States)

    RE-Powering America's Land: Renewable Energy on Contaminated Land and Mining Sites was presented by Penelope McDaniel, during the 2008 Brown to Green: Make the Connection to Renewable Energy workshop.

  1. How universal are hydrogen bond correlations? A density functional study of intramolecular hydrogen bonding in low-energy conformers of α-amino acids

    Science.gov (United States)

    Ramaniah, Lavanya M.; Kamal, C.; Kshirsagar, Rohidas J.; Chakrabarti, Aparna; Banerjee, Arup

    2013-10-01

    Hydrogen bonding is one of the most important and ubiquitous interactions present in Nature. Several studies have attempted to characterise and understand the nature of this very basic interaction. These include both experimental and theoretical investigations of different types of chemical compounds, as well as systems subjected to high pressure. The O-H..O bond is of course the best studied hydrogen bond, and most studies have concentrated on intermolecular hydrogen bonding in solids and liquids. In this paper, we analyse and characterise normal hydrogen bonding of the general type, D-H...A, in intramolecular hydrogen bonding interactions. Using a first-principles density functional theory approach, we investigate low energy conformers of the twenty α-amino acids. Within these conformers, several different types of intramolecular hydrogen bonds are identified. The hydrogen bond within a given conformer occurs between two molecular groups, either both within the backbone itself, or one in the backbone and one in the side chain. In a few conformers, more than one (type of) hydrogen bond is seen to occur. Interestingly, the strength of the hydrogen bonds in the amino acids spans quite a large range, from weak to strong. The signature of hydrogen bonding in these molecules, as reflected in their theoretical vibrational spectra, is analysed. With the new first-principles data from 51 hydrogen bonds, various parameters relating to the hydrogen bond, such as hydrogen bond length, hydrogen bond angle, bond length and vibrational frequencies are studied. Interestingly, the correlation between these parameters in these bonds is found to be in consonance with those obtained in earlier experimental studies of normal hydrogen bonds on vastly different systems. Our study provides some of the most detailed first-principles support, and the first involving vibrational frequencies, for the universality of hydrogen bond correlations in materials.

  2. Life cycle environmental and economic analyses of a hydrogen station with wind energy

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Ji-Yong [Eco Strategy Team, LG Electronics, 16 Woomyeon-Dong, Seocho-Gu, Seoul (Korea); An, Sanghyuk; Cha, Kyounghoon; Hur, Tak [Dept. of Chemical and Biological Engineering, Konkuk University, 1, Hwayang-dong, Gwangjin-gu, Seoul (Korea)

    2010-03-15

    This study aimed to identify the environmental and economic aspects of the wind-hydrogen system using life cycle assessment (LCA) and life cycle costing (LCC) methodologies. The target H{sub 2} pathways are the H{sub 2} pathway of water electrolysis (WE) with wind power (WE[Wind]) and the H{sub 2} pathway of WE by Korean electricity mix (WE[KEM]). Conventional fuels (gasoline and diesel) are also included as target fuel pathways to identify the fuel pathways with economic and environmental advantages over conventional fuels. The key environmental issues in the transportation sector are analyzed in terms of fossil fuel consumption (FFC), regulated air pollutants (RAPs), abiotic resource depletion (ARD), and global warming (GW). The life cycle costs of the target fuel pathways consist of the well-to-tank (WTT) costs and the tank-to-wheel (TTW) costs. Moreover, two scenarios are analyzed to predict potential economic and environmental improvements offered by wind energy-powered hydrogen stations. In LCA results, WE[Wind] is superior to the other pathways in all environmental categories. The LCC results show that the projected WTT cost savings of WE[Wind] and WE[KEM] compared to gasoline are US $ 0.050 and US $ 0.036 per MJ, respectively, because hydrogen will not be subjected to any fuel tax according to the Korean Energy Policy in 2015. Although WE[KEM] and WE[Wind] incur high capital costs owing to the required capital investment in fuel cell vehicles (FCVs), they have lower well-to-wheel (WTW) costs than those of conventional fuels due to the high FCV efficiency in fuel utilization stage. WTW costs for gasoline are higher than those of WE[KEM] and WE[Wind] by US $ 12,600 and US $ 10,200, respectively. This study demonstrated the future competitiveness of the WE[Wind] pathway in both environmental and economic aspects. In the WTT stage, the point-of-sale of the electricity produced by the wind power plant (WPP) cannot be controlled because the wind

  3. Predicting hydrogen and methane adsorption in carbon nanopores for energy storage

    Science.gov (United States)

    Ihm, Yungok; Morris, James; Cooper, Valentino; Morris Lab, U. tennessee Collaboration; Advanced material Group, ORNL Collaboration

    2013-03-01

    There are increasing demands for alternate fuels for transportation, which requires safe, high energy density, lightweight storage materials. Experimental measurements and theoretical predictions show relatively low hydrogen storage capacities in various porous materials, limiting hydrogen as a viable alternative for automobiles. In this work, we use a continuum model based on van der Waals density functional (vdW-DF) calculations to elucidate the role that long-range interactions play in the hydrogen adsorption properties of model slit nanopores in carbon. The proper treatment of long-range interactions gives an optimal pore size for hydrogen storage of 8-9 Å (larger than previously predicted). Remarkably, we find a peak hydrogen density close to that of liquid H2 at ambient temperatures, in agreement with recent experimental results on pore-size dependent adsorption in nanoporous carbon. We then show that such nanopores would be better suited to storing methane, possibly providing an alternative to fill the gap between the capacity required by DOE goals and that attainable with current hydrogen storage technology. Research supported by the U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Engineering Division.

  4. Limitations on hydrogen production in a renewable regenerative energy system due to thermal transients

    Energy Technology Data Exchange (ETDEWEB)

    Bergen, A.; Djilali, N.; Pitt, L.; Rowe, A.; Wild, P. [Victoria Univ., BC (Canada). Inst. for Integrated Energy Systems

    2007-07-01

    The integrated renewable energy experiment (IRENE) was developed to aid in the development of simulation tools for renewable energy-based distributed residential-scale hydrogen systems. This study focused on evaluating the interactions between system components that influence hydrogen production. The principal components of IRENE included a controllable input power source, power conversion elements; AC load devices; a hydrogen storage system; a fuel cell loop; and, a control and data acquisition system. The system was fully instrumented to measure mass and energy flows between system elements. A simplified power conditioning unit was used to allow throttling of the current to the electrolyser by passively reducing the input voltage. Power transfer to the electrolyser was limited at low bus voltages. A power input profile was used to validate the modelling electrolyser step function response predictions with IRENE's experimental data. Preliminary experimental results showed that some modelling assumptions made for renewable hydrogen systems over-estimate hydrogen production capabilities. Values obtained were between 10 to 20 per cent lower than values typically reported in the literature. It was concluded that the thermal characteristics and bus limiting interactions should be considered if accurate modelling of hydrogen production capacity is required. 11 refs., 1 tab., 4 figs.

  5. Energy savings potential from energy-conserving irrigation systems

    Energy Technology Data Exchange (ETDEWEB)

    Wilfert, G.L.; Patton, W.P.; Harrer, B.J.; Clark, M.A.

    1982-11-01

    This report systematically compares, within a consistent framework, the technical and economic characteristics of energy-conserving irrigation systems with those of conventional irrigation systems and to determine total energy savings. Levelized annual costs of owning and operating both energy-conserving and conventional irrigation systems have been developed and compared for all 17 states to account for the differences in energy costs and irrigation conditions in each state. Market penetration of energy-conserving systems is assessed for those systems having lower levelized annual costs than conventional systems performing the same function. Annual energy savings were computed by matching the energy savings per system with an assumed maximum market penetration of 100 percent in those markets where the levelized annual costs of energy-conserving systems are lower than the levelized annual costs of conventional systems.

  6. Hydrogen as the solar energy translator. [in photochemical and photovoltaic processes

    Science.gov (United States)

    Kelley, J. H.

    1979-01-01

    Many concepts are being investigated to convert sunlight to workable energy forms with emphasis on electricity and thermal energy. The electrical alternatives include direct conversion of photons to electricity via photovoltaic solar cells and solar/thermal production of electricity via heat-energy cycles. Solar cells, when commercialized, are expected to have efficiencies of about 12 to 14 percent. The cells would be active about eight hours per day. However, solar-operated water-splitting process research, initiated through JPL, shows promise for direct production of hydrogen from sunlight with efficiencies of up to 35 to 40 percent. The hydrogen, a valuable commodity in itself, can also serve as a storable energy form, easily and efficiently converted to electricity by fuel cells and other advanced-technology devices on a 24-hour basis or on demand with an overall efficiency of 25 to 30 percent. Thus, hydrogen serves as the fundamental translator of energy from its solar form to electrical form more effectively, and possibly more efficiently, than direct conversion. Hydrogen also can produce other chemical energy forms using solar energy.

  7. Hydrogen as the solar energy translator. [in photochemical and photovoltaic processes

    Science.gov (United States)

    Kelley, J. H.

    1979-01-01

    Many concepts are being investigated to convert sunlight to workable energy forms with emphasis on electricity and thermal energy. The electrical alternatives include direct conversion of photons to electricity via photovoltaic solar cells and solar/thermal production of electricity via heat-energy cycles. Solar cells, when commercialized, are expected to have efficiencies of about 12 to 14 percent. The cells would be active about eight hours per day. However, solar-operated water-splitting process research, initiated through JPL, shows promise for direct production of hydrogen from sunlight with efficiencies of up to 35 to 40 percent. The hydrogen, a valuable commodity in itself, can also serve as a storable energy form, easily and efficiently converted to electricity by fuel cells and other advanced-technology devices on a 24-hour basis or on demand with an overall efficiency of 25 to 30 percent. Thus, hydrogen serves as the fundamental translator of energy from its solar form to electrical form more effectively, and possibly more efficiently, than direct conversion. Hydrogen also can produce other chemical energy forms using solar energy.

  8. The Assessment of Hydrogen Energy Systems for Fuel Cell Vehicles Using Principal Componenet Analysis and Cluster Analysis

    DEFF Research Database (Denmark)

    Ren, Jingzheng; Tan, Shiyu; Dong, Lichun

    2012-01-01

    Hydrogen energy which has been recognized as an alternative instead of fossil fuel has been developed rapidly in fuel cell vehicles. Different hydrogen energy systems have different performances on environmental, economic, and energy aspects. A methodology for the quantitative evaluation and anal......Hydrogen energy which has been recognized as an alternative instead of fossil fuel has been developed rapidly in fuel cell vehicles. Different hydrogen energy systems have different performances on environmental, economic, and energy aspects. A methodology for the quantitative evaluation...... to verify the correctness and accuracy of the principal components (PCs) determined by PCA in this paper. A case including 11 different hydrogen energy systems for fuel cell vehicles has been studied in this paper, and the system using steam reforming of natural gas for hydrogen production, pipeline...... for transportation of hydrogen, hydrogen gas tank for the storage of hydrogen at refueling stations, and gaseous hydrogen as power energy for fuel cell vehicles has been recognized as the best scenario. Also, the clustering results calculated by CA are consistent with those determined by PCA, denoting...

  9. Special document: which energies for tomorrow? Fossil, renewable, nuclear, hydrogen energies; the CEA of Saclay at the heart of the research; energy, greenhouse effect, climate; Dossier special: quelles energies pour demain? Energies fossiles, renouvelables, nucleaires, hydrogene; le Centre CEA de Saclay au coeur de la recherche; energie, effet de serre, climat

    Energy Technology Data Exchange (ETDEWEB)

    Anon

    2003-04-01

    The Cea devotes many research programs in the energy domain and especially in the development of new energetic solutions: hydrogen program, photovoltaic program, energy conservation domain and improvement of energy production systems. In this framework, this document presents synthetical information on the France situation in the world energy space and on the Cea Saclay researches. The energy policy and the electric power in France, the fossil energies, the nuclear energy, the renewable energies, the hydrogen and the fuel cell, the greenhouse effect and the climatology are detailed. (A.L.B.)

  10. Viscosity Measurement of Hydrogen-Methane Mixed Gas for Future Energy Systems

    Science.gov (United States)

    Kobayashi, Yohei; Kurokawa, Akira; Hirata, Masaru

    In order to reduce the CO2 emission, in May 2004, the European Union (EU) started an experimental approach known as the “naturalhy Project” in order to transport hydrogen by mixing it with the existing high-pressure natural gas in the pipelines. Naturalhy represents a mixture of hydrogen and natural gas. In other words, this gas is also known as hythane, which is an abbreviation of hydrogen and methane. The name “hythane” is the registered trademark of Hydrogen Consulting Inc., USA. Why will this gas gain importance? It is generally considered that the sudden realization of a hydrogen energy society cannot take place. It is normally assumed that the present status of methane as an energy carrier gradually changes to a state of hydrogen-methane mixed gas and finally to 100% hydrogen. This is why the authors investigate the properties of this mixture. This study is considered to be the first to measure the temperature dependence of the viscosity of hydrogen-methane mixed gas. In order to measure the viscosity, the authors used a capillary method that measures the pressure drop in the laminar flow through a pipe. It was conducted in an electrically polished, ultra clean and smooth tube and the pressure drop between the upstream and downstream was carefully measured using a capacitance manometer. In order to remove the effect of temperature dependence, the tube was placed in a constant temperature bath, and the temperature fluctuation was maintained within ±0.3°C throughout this experimental study. The authors obtained the viscosity of the hydrogen-methane mixed gas within a temperature range of 20-70°C.

  11. Hydrogen Pathways: Updated Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Ten Hydrogen Production, Delivery, and Distribution Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Ramsden, T.; Ruth, M.; Diakov, V.; Laffen, M.; Timbario, T. A.

    2013-03-01

    This report describes a life-cycle assessment conducted by the National Renewable Energy Laboratory (NREL) of 10 hydrogen production, delivery, dispensing, and use pathways that were evaluated for cost, energy use, and greenhouse gas (GHG) emissions. This evaluation updates and expands on a previous assessment of seven pathways conducted in 2009. This study summarizes key results, parameters, and sensitivities to those parameters for the 10 hydrogen pathways, reporting on the levelized cost of hydrogen in 2007 U.S. dollars as well as life-cycle well-to-wheels energy use and GHG emissions associated with the pathways.

  12. Industry requirements for introduction of alternative energies with emphasis on hydrogen fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Delabbio, F. [Rio Tinto, Canadian Exploration Ltd., Toronto, ON (Canada); Starbuck, D. [Newmont Mining Corp., Denver, CO (United States); Akerman, A. [CVRD-Inco, Toronto, ON (Canada); Betournay, M.C. [Natural Resources Canada, Ottawa, ON (Canada). CANMET Mining and Mineral Sciences Laboratories

    2007-07-01

    This paper discussed issues related to the use of alternate sources of energy in underground mining applications. Hydrogen power systems were examined in relation to operational drivers, available commercial supplies, site supplies, health and safety issues, capital and operating costs, mine production, and the role of government. Hydrogen power systems are being considered for mining applications in an effort to reduce greenhouse gas (GHG) emissions and reduce cooling and ventilation requirements. This article examined a range of issues that must be addressed before alternate energy systems such as hydrogen fuel cell technology can be used in larger-scale underground mining applications. The mining industry supports the development of new technologies. However, the introduction of alternate energy technologies must proceed in steps which include proof of concept testing, the development of generic infrastructure, power systems and regulations, and whole operating system studies. 13 refs., 1 fig.

  13. Chemical/hydrogen energy storage systems. Annual report, January 1, 1979-December 31, 1979

    Energy Technology Data Exchange (ETDEWEB)

    1980-05-01

    The progress made in 1979 in the Chemical/Hydrogen Energy Storage Systems Program is described. The program is managed by Brookhaven National Laboratory for the Division of Energy Storage Systems of the Department of Energy. The program consists of research and development activities in the areas of Hydrogen Production, Storage and Materials, End-Use Applications/Systems Studies, and in Chemical Heat Pumps. The report outlines the progress made by key industrial contractors such as General Electric in the development of SPE water electrolyzers; INCO in the studies of surface poisoning (and reactivation) of metal hydrides; and Air Products and Chemicals in the evaluation of hydrogen production at small hydropower sites. The BNL in-house supporting research, as well as that at universities and other national laboratories for which BNL has technical oversight, is also described.

  14. A study of hydro-graphene for energy storage (2) Hydrogen absorption

    Energy Technology Data Exchange (ETDEWEB)

    Tokio Yamabe; Mitsuhiro Fujii [Nagasaki Institute ofApplied Science, 536 Aba-machi, Nagasaki 851-0193, (Japan); Yoshio Furuya [Department of Technology, Faculty of Education, Nagasaki University, 1-14 bunkyo-cho, Nagasaki 852-8521, (Japan); Shiro Mori; Shizukuni Yata [Energy Conversion Research Laboratory, KRI Inc., Kyoto Research Park, 134 Chudoji Minami-machi, Shimogyo-ku, Kyoto 600-8813, (Japan)

    2005-07-01

    The technology of hydrogen storage is one of the most important challenges in hydrogen energy system for clean environment. Some carbon materials are expected to have such advantage for hydrogen storage. We have studied about PAS and PAHs, which are marginal members of the carbon allotropes containing a significant amount of hydrogen atoms, and which show a variety of interesting properties lacking pure carbon materials. They constituted by graphite sheets terminated by hydrogen atoms, and so it may be called 'hydro-graphene'. In this work, we prepared two kinds of hydro-graphene, such as PAS and PAHs, by the pyrolysis at 550 C. The [H]/[C] molar ratio of PAS was 0.45, and that of PAHs was 0.33. The interlayer distance of PAS was broad, and that of PAH was 3.68 A. We examined their ability of hydrogen storage by two methods. It was measured the amount of equilibrium pressure change of sample room, on the first method of increasing hydrogen pressure at 77 K, and on the second method of temperature increasing to R.T. in vacuum after reducing pressure. On the former method, the hydrogen storage amount of PAS was 0.5 wt-%, and that of PAHs was 0.4 wt-%. On the latter, that of PAS was 0.4 wt-%, and that of PAHs was 0.3 wt-%. Those results indicate that each total capacity of hydrogen storage was estimated 0.5-6 wt-%. We will discuss the mechanism of hydrogen adsorption to hydro-graphene based on the quantum chemical viewpoint. (authors)

  15. Wind turbine tower for storing hydrogen and energy

    Science.gov (United States)

    Fingersh, Lee Jay [Westminster, CO

    2008-12-30

    A wind turbine tower assembly for storing compressed gas such as hydrogen. The tower assembly includes a wind turbine having a rotor, a generator driven by the rotor, and a nacelle housing the generator. The tower assembly includes a foundation and a tubular tower with one end mounted to the foundation and another end attached to the nacelle. The tower includes an in-tower storage configured for storing a pressurized gas and defined at least in part by inner surfaces of the tower wall. In one embodiment, the tower wall is steel and has a circular cross section. The in-tower storage may be defined by first and second end caps welded to the inner surface of the tower wall or by an end cap near the top of the tower and by a sealing element attached to the tower wall adjacent the foundation, with the sealing element abutting the foundation.

  16. Storage of Renewable Energy by Reduction of CO2 with Hydrogen.

    Science.gov (United States)

    Züttel, Andreas; Mauron, Philippe; Kato, Shunsuke; Callini, Elsa; Holzer, Marco; Huang, Jianmei

    2015-01-01

    The main difference between the past energy economy during the industrialization period which was mainly based on mining of fossil fuels, e.g. coal, oil and methane and the future energy economy based on renewable energy is the requirement for storage of the energy fluxes. Renewable energy, except biomass, appears in time- and location-dependent energy fluxes as heat or electricity upon conversion. Storage and transport of energy requires a high energy density and has to be realized in a closed materials cycle. The hydrogen cycle, i.e. production of hydrogen from water by renewable energy, storage and use of hydrogen in fuel cells, combustion engines or turbines, is a closed cycle. However, the hydrogen density in a storage system is limited to 20 mass% and 150 kg/m(3) which limits the energy density to about half of the energy density in fossil fuels. Introducing CO(2) into the cycle and storing hydrogen by the reduction of CO(2) to hydrocarbons allows renewable energy to be converted into synthetic fuels with the same energy density as fossil fuels. The resulting cycle is a closed cycle (CO(2) neutral) if CO(2) is extracted from the atmosphere. Today's technology allows CO(2) to be reduced either by the Sabatier reaction to methane, by the reversed water gas shift reaction to CO and further reduction of CO by the Fischer-Tropsch synthesis (FTS) to hydrocarbons or over methanol to gasoline. The overall process can only be realized on a very large scale, because the large number of by-products of FTS requires the use of a refinery. Therefore, a well-controlled reaction to a specific product is required for the efficient conversion of renewable energy (electricity) into an easy to store liquid hydrocarbon (fuel). In order to realize a closed hydrocarbon cycle the two major challenges are to extract CO(2) from the atmosphere close to the thermodynamic limit and to reduce CO(2) with hydrogen in a controlled reaction to a specific hydrocarbon. Nanomaterials with

  17. Optimization of efficiency and energy density of passive micro fuel cells and galvanic hydrogen generators

    CERN Document Server

    Hahn, Robert; Krumbholz, Steffen; Reichl, Herbert

    2008-01-01

    A PEM micro fuel cell system is described which is based on self-breathing PEM micro fuel cells in the power range between 1 mW and 1W. Hydrogen is supplied with on-demand hydrogen production with help of a galvanic cell, that produces hydrogen when Zn reacts with water. The system can be used as a battery replacement for low power applications and has the potential to improve the run time of autonomous systems. The efficiency has been investigated as function of fuel cell construction and tested for several load profiles.

  18. Optimization of efficiency and energy density of passive micro fuel cells and galvanic hydrogen generators

    OpenAIRE

    Hahn, Robert; Wagner,Stefan; Krumbholz, Steffen; Reichl, Herbert

    2008-01-01

    Submitted on behalf of EDA Publishing Association (http://irevues.inist.fr/handle/2042/16838); International audience; A PEM micro fuel cell system is described which is based on self-breathing PEM micro fuel cells in the power range between 1 mW and 1W. Hydrogen is supplied with on-demand hydrogen production with help of a galvanic cell, that produces hydrogen when Zn reacts with water. The system can be used as a battery replacement for low power applications and has the potential to improv...

  19. Calculation of Electron Beam Potential Energy from RF Photocathode Gun

    CERN Document Server

    Liu Wan Ming; Power, John G; Wang, Haitao

    2005-01-01

    In this paper, we consider the contribution of potential energy to beam dynamics as simulated by PARMELA at low energies (10 - 30MeV). We have developed a routine to calculate the potential energy of the relativistic electron beam using the static coulomb potential in the rest frame (first order approximation as in PARMELA). We found that the potential energy contribution to the beam dynamics could be very significant, particularly with high charge beams generated by an RF photocathode gun. Our results show that when the potential energy is counted correctly and added to the kinetic energy from PARMELA, the total energy is conserved. Simulation results of potential and kinetic energies for short beams (~1 mm) at various charges (1 - 100 nC) generated by a high current RF photocathode gun are presented.

  20. User behaviour impact on energy savings potential

    DEFF Research Database (Denmark)

    Rose, Jørgen

    2014-01-01

    corresponding to different levels of energy consumption. The purpose of the analysis is to identify the importance of each of the four primary user-related parameters in terms of their relative and combined impact on the overall energy needs before/after upgrading; 1) Indoor temperature, 2) Internal heat gain......, 3) Domestic hot water consumption and 4) Air change rate. Based on the analysis, a methodology is established that can be used to make more realistic and accurate predictions of expected energy savings associated with energy upgrading taking into account user behaviour....

  1. The statistical shift of the chemical potential causing anomalous conductivity in hydrogenated microcrystalline silicon

    NARCIS (Netherlands)

    Lof, R.W.; Schropp, R.E.I.

    2010-01-01

    The behavior of the electrical conductivity in hydrogenated microcrystalline silicon (μ c-Si:H) that is frequently observed is explained by considering the statistical shift in the chemical potential as a function of the crystalline fraction (Xc), the dangling bond density (N db), and the doping den

  2. Hydrogen as Future Energy Carrier: The ENEA Point of View on Technology and Application Prospects

    Directory of Open Access Journals (Sweden)

    Marina Ronchetti

    2009-03-01

    Full Text Available Hydrogen and fuel cells should reduce costs and increase reliability and durability to compete in the energy market. A considerable long term effort is necessary for research, development and demonstration of adequate solutions; important programs in this sense are carried out in the main industrialized countries, with the involvement of many industries, research structures and stakeholders. In such framework a relevant role is played in Italy by ENEA (Italian Agency for New Technologies, Energy and Environment. In the paper the main aspects related to the possible hydrogen role in the future society are addressed, according to ENEA perspectives.

  3. Hydrogen evolution by fermentation using seaweed as substrates and the contribution to the clean energy production

    Energy Technology Data Exchange (ETDEWEB)

    Tanisho, S.; Suganuma, T.; Yamaguchi, A. [Yokohama National Univ. (Japan). Dept. of Environmental Sciences

    2001-07-01

    It is an important theme in Japan to use the sea for energy production, because Japan is surrounded by seas on all sides. Brown algae such as Laminaria have high value as the substrate of fermentative hydrogen production, since they have very high growth rate and also have high ability on the productivity of mannitol. I would like to present about the affection of salt concentration on the hydrogen production of Enterobacter aerogenes, and also the contribution on clean energy production by the seaweed cultivation in Japan. (orig.)

  4. Electronic stopping power of hydrogen in KCl at the stopping maximum and at very low energies

    Science.gov (United States)

    Primetzhofer, D.; Markin, S. N.; Bauer, P.

    2011-10-01

    The electronic energy loss of hydrogen ions in KCl was investigated in a wide energy range. Thin films of KCl were evaporated on an Au/Si substrate. Rutherford Backscattering Spectrometry (RBS) was performed with protons and deuterons at energies from 30 to 400 keV/nucleon. At lower energies experiments were performed by Time-Of-Flight Low energy ion scattering (TOF-LEIS) again with proton and deuteron projectiles. Experimental results are compared to calculated/tabulated values for the electronic energy loss. Whereas at energies beyond the stopping maximum very good agreement is found, at lower ion energies discrepancies between experiment and calculations increase. At very low ion velocities the extrapolated stopping cross section ɛ predicts vanishing electronic energy loss at energies below 100 eV/nucleon.

  5. Energy Efficiency Improvement Potential in Historical Brick Building

    OpenAIRE

    Žogla, Gatis; Blumberga, Andra; Zvaigznītis, Kristaps; Dzikēvičs, Miķelis; Blumberga, Dagnija; Burinskiene, Marija

    2013-01-01

    Energy efficiency in historical heritage buildings is viewed as a taboo because these buildings usually are law-protected and no energy efficiency measures that would change the appearance of building are allowed. In this paper we look at a potential of increasing energy efficiency level in historical buildings. Measurements to determine energy efficiency of a historical brick building have been done, which also give the possibility to determine the potential of energy efficiency measures in ...

  6. Energy conservation potential of surface modification technologies

    Energy Technology Data Exchange (ETDEWEB)

    Le, H.K.; Horne, D.M.; Silberglitt, R.S.

    1985-09-01

    This report assesses the energy conservation impact of surface modification technologies on the metalworking industries. The energy conservation impact of surface modification technologies on the metalworking industries is assessed by estimating their friction and wear tribological sinks and the subsequent reduction in these sinks when surface modified tools are used. Ion implantation, coatings, and laser and electron beam surface modifications are considered.

  7. A study of hydro-graphene for energy storage (2) hydrogen absorption

    Energy Technology Data Exchange (ETDEWEB)

    Tokio, Yamabe; Mitsuhiro, Fujii [Nagasaki Institute of Applied Science, Nagasaki (Japan); Yoshio, Furuya [Faculty of Education, Dept. of Technology, Nagasaki (Japan); Shiro, Mori; Shizukuni, Yata [Energy Conversion Research Lab., KRI Inc., Kyoto (Japan)

    2005-07-01

    The technology of hydrogen storage is one of the most important challenges in hydrogen energy system for clean environment [1]. Some carbon materials are expected to have such advantage for hydrogen storage. We have studied about PAS and PAHs, which are marginal members of the carbon allotropes containing a significant amount of hydrogen atoms, and which show a variety of interesting properties lacking pure carbon materials [2-9]. They constituted by graphite sheets terminated by hydrogen atoms, and so it may be called 'hydro-graphene' [10]. In this work, we prepared two kinds of hydro-graphene, such as PAS [8,9] and PAHs [7], by the pyrolysis at 550 C. The [H]/[C] molar ratio of PAS was 0.45, and that of PAHs was 0.33. The interlayer distance of PAS was broad, and that of PAH was 3.68 A. We examined their ability of hydrogen storage by two methods. It was measured the amount of equilibrium pressure change of sample room, on the first method of increasing hydrogen pressure at 77 K, and on the second method of temperature increasing to R.T. in vacuum after reducing pressure. On the former method, the hydrogen storage amount of PAS was 0.5 wt-%, and that of PAHs was about 0.4 wt-%. On the latter, that of PAS was 0.4 wt-%, d that of PAHs was 0.3 wt-%. Those results indicate that each total capacity of hydrogen storage was estimated 0.5-0.6 wt%. We will discuss the mechanism of hydrogen adsorption to hydro-graphene based on the quantum chemical viewpoint. [1] DOE Hydrogen Program: www.hydrogen.energy.gov. [2] P. Novac, K. Muller, K. S. V. Santhanam, O. Haas: Chem. Rev., 97, 270, 1997; [3] T. Yamabe, K. Tanaka, K. Ohzeki, S. Yata: Solid State Commun., 44, 823, 1982; [4] S. Yata, Y. Hato, K. Sakurai, H. Satake, K. Mukai, K. Tanaka, T. Yamabe: Synth. Met., 38, 169, 1990; [5] S. Yata, H. Kinoshita, M. Komori, N. Ando, T. Kashiwamura, T. Harada, K Tanaka, T. Yamabe: Synth. Met., 62, 153, 1994; [6] J. R. Dahn, T. Zheng, Y. Liu, J. S. Xue: Science, 270, 590, 1995

  8. Review of electrical energy storage technologies and systems and of their potential for the UK

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This report presents the findings of a review of current energy storage technologies and their potential application in the UK. Five groups of storage technologies are examined: compressed air energy storage; battery energy storage systems including lead-acid, nickel-cadmium, sodium-sulphur, sodium-nickel and lithium ion batteries; electrochemical flow cell systems, including the vanadium redox battery, the zinc bromide battery and the polysulphide battery; kinetic energy storage systems, ie flywheel storage; and fuel cell/electrolyser systems based on hydrogen. Details are given of the technology, its development status, potential applications and the key developers, manufacturers and suppliers. The opportunities available to UK industry and the potential for systems integration and wealth creation are also discussed.

  9. Solid Hydrogen Experiments for Atomic Propellants: Particle Formation Energy and Imaging Analyses

    Science.gov (United States)

    Palaszewski, Bryan

    2002-01-01

    This paper presents particle formation energy balances and detailed analyses of the images from experiments that were conducted on the formation of solid hydrogen particles in liquid helium during the Phase II testing in 2001. Solid particles of hydrogen were frozen in liquid helium and observed with a video camera. The solid hydrogen particle sizes and the total mass of hydrogen particles were estimated. The particle formation efficiency is also estimated. Particle sizes from the Phase I testing in 1999 and the Phase II testing in 2001 were similar. Though the 2001 testing created similar particles sizes, many new particle formation phenomena were observed. These experiment image analyses are one of the first steps toward visually characterizing these particles and it allows designers to understand what issues must be addressed in atomic propellant feed system designs for future aerospace vehicles.

  10. High-Capacity Hydrogen-Based Green-Energy Storage Solutions For The Grid Balancing

    Science.gov (United States)

    D'Errico, F.; Screnci, A.

    One of the current main challenges in green-power storage and smart grids is the lack of effective solutions for accommodating the unbalance between renewable energy sources, that offer intermittent electricity supply, and a variable electricity demand. Energy management systems have to be foreseen for the near future, while they still represent a major challenge. Integrating intermittent renewable energy sources, by safe and cost-effective energy storage systems based on solid state hydrogen is today achievable thanks to recently some technology breakthroughs. Optimized solid storage method made of magnesium-based hydrides guarantees a very rapid absorption and desorption kinetics. Coupled with electrolyzer technology, high-capacity storage of green-hydrogen is therefore practicable. Besides these aspects, magnesium has been emerging as environmentally friend energy storage method to sustain integration, monitoring and control of large quantity of GWh from high capacity renewable generation in the EU.

  11. Hydrogen as energy carrier for eco-resorts on Dalmatian Islands: pilot program

    Energy Technology Data Exchange (ETDEWEB)

    Vujcic, R.; Kovacevic, I. [Split-Dalmatian County, Split (Croatia). Dept. of Economic Management; Hrastnik, B. [Energy Inst. Hrvoje Pozar, Zagreb (Croatia); Barbir, F. [Proton Energy Systems, Rocky Hill, CT (United States)

    2002-07-01

    Agriculture, tourism, fishing, stone excavation and processing, and the production of wine and wine distillate are the major economic levers of Dalmatian Islands in Croatia. A proposal was discussed in this paper for the establishment of eco-resorts on Dalmatian Islands. This project would involve combining renewable energy and organic farming as a stepping stone toward sustainable development. It could also be used to showcase achievements. Indigenous energy sources such as solar and wind energy, combined with hydrogen technologies for energy storage and the use of hydrogen as fuel would be used to power these eco-resorts. The technical and economic feasibility of this proposed energy system and organic farming were discussed by the authors in this paper. The proposed establishment of a pilot project on one of the islands was also discussed. 13 refs., 6 tabs., 9 figs.

  12. Peculiar features of the interaction potential between hydrogen and antihydrogen at intermediate separations

    Institute of Scientific and Technical Information of China (English)

    Lee Teck-Ghee; Wong Cheuk-Yin; Wang Lee-Shien

    2008-01-01

    This paper evaluates the interaction potential between a hydrogen and an antihydrogen using the second-order perturbation theory within the framework of the four-body system in a separable two-body basis. It finds that the H-H interaction potential possesses the peculiar features of a shallow local minimum located around interatomic separations of r ~ 6a.u. and a barrier rising at r<~ 5a.u.

  13. The quasi-Gaussian entropy theory : Free energy calculations based on the potential energy distribution function

    NARCIS (Netherlands)

    Amadei, A; Apol, MEF; DiNola, A; Berendsen, HJC

    1996-01-01

    A new theory is presented for calculating the Helmholtz free energy based on the potential energy distribution function. The usual expressions of free energy, internal energy and entropy involving the partition function are rephrased in terms of the potential energy distribution function, which must

  14. The quasi-Gaussian entropy theory : Free energy calculations based on the potential energy distribution function

    NARCIS (Netherlands)

    Amadei, A; Apol, MEF; DiNola, A; Berendsen, HJC

    1996-01-01

    A new theory is presented for calculating the Helmholtz free energy based on the potential energy distribution function. The usual expressions of free energy, internal energy and entropy involving the partition function are rephrased in terms of the potential energy distribution function, which must

  15. MIGREYD Modular IGCC concepts for in-Refinery Energy and Hydrogen supply

    Energy Technology Data Exchange (ETDEWEB)

    Romey, I.; Obladen, M.; Schulz, A. [Univ. Duisburg-Essen, Inst. Technology of Energy Supply and Energery Conversion Systems (TEE), Essen (Germany)

    2004-07-01

    There is an increasing tendency for refineries to produce a greater proportion of light, high-hydrogen-content chemicals, which also results in greater quantities of heavy residues which require disposal. Gasification of these residues offers a number of options for utilisation of the resulting products. Importantly, gasification offers the opportunity for cost-effective production of hydrogen, which may not only be used in the refinery processes, but also in future fuel cell applications, either for stationary or transport options. The MIGREYD project opens an important bridge for the transition from the use of conventional fossil fuels to a future hydrogen based energy system. Through this project, an advanced, highly efficient in-refinery energy and hydrogen supply system will be developed that is flexible in terms of fuels (biomass, oil refinery residues, low-grade fossil fuels) and products (hydrogen, cogeneration of power and process heat, and other chemicals). The improved efficiency of the process stages and the synergistic benefits of poly-generation will realise savings of primary fossil energy resources, sustainable pollution control and a significant decrease of the total plant's CO{sub 2} emissions. (orig.)

  16. Risk Perception of an Emergent Technology: The Case of Hydrogen Energy

    Directory of Open Access Journals (Sweden)

    Rob Flynn

    2006-01-01

    Full Text Available Although hydrogen has been used in industry for many years as a chemical commodity, its use as a fuel or energy carrier is relatively new and expert knowledge about its associated risks is neither complete nor consensual. Public awareness of hydrogen energy and attitudes towards a future hydrogen economy are yet to be systematically investigated. This paper opens by discussing alternative conceptualisations of risk, then focuses on issues surrounding the use of emerging technologies based on hydrogen energy. It summarises expert assessments of risks associated with hydrogen. It goes on to review debates about public perceptions of risk, and in doing so makes comparisons with public perceptions of other emergent technologies—Carbon Capture and Storage (CCS, Genetically Modified Organisms and Food (GM and Nanotechnology (NT—for which there is considerable scientific uncertainty and relatively little public awareness. The paper finally examines arguments about public engagement and "upstream" consultation in the development of new technologies. It is argued that scientific and technological uncertainties are perceived in varying ways and different stakeholders and different publics focus on different aspects or types of risk. Attempting to move public consultation further "upstream" may not avoid this, because the framing of risks and benefits is necessarily embedded in a cultural and ideological context, and is subject to change as experience of the emergent technology unfolds. URN: urn:nbn:de:0114-fqs0601194

  17. Control analysis of renewable energy system with hydrogen storage for residential applications

    Science.gov (United States)

    Bilodeau, A.; Agbossou, K.

    The combination of an electrolyzer and a fuel cell can provide peak power control in a decentralized/distributed power system. The electrolyzer produces hydrogen and oxygen from off-peak electricity generated by the renewable energy sources (wind turbine and photovoltaic array), for later use in the fuel cell to produce on-peak electricity. An issue related to this system is the control of the hydrogen loop (electrolyzer, tank, fuel cell). A number of control algorithms were developed to decide when to produce hydrogen and when to convert it back to electricity, most of them assuming that the electrolyzer and the fuel cell run alternatively to provide nominal power (full power). This paper presents a complete model of a stand-alone renewable energy system with hydrogen storage controlled by a dynamic fuzzy logic controller (FLC). In this system, batteries are used as energy buffers and for short time storage. To study the behavior of such a system, a complete model is developed by integrating the individual sub-models of the fuel cell, the electrolyzer, the power conditioning units, the hydrogen storage system, and the batteries. An analysis of the performances of the dynamic fuzzy logic controller is then presented. This model is useful for building efficient peak power control.

  18. Energy performance contracting - energy saving potential of selected energy conservation measures (ECM)

    Energy Technology Data Exchange (ETDEWEB)

    Johansson, M. (Dansk Energi Analyse A/S, Frederiksberg (Denmark)); Langkilde, G.; Olesen, Bjarne W. (Technical Univ. of Denmark, ICIEE, Kgs. Lyngby (Denmark)); Moerck, O. (Cenergia Energy Consultants, Herlev (Denmark)); Sundman, O. (DONG Energy, Copenhagen (Denmark)); Engelund Thomsen, K. (Aalborg Univ., SBi, Hoersholm (Denmark))

    2008-09-15

    This report has been developed under the research project 'Etablering af grundlag for energitjenester i Danmark' (project number: ENS-33031-0185) under the Danish research programme - EFP. The objective of this project has been to contribute to the utilisation of the large potential for energy conservations in the building sector within the public, industry and service sectors through the development of a better basis for decision making for both the Energy Service Companies (ESCOes) and the building owners. The EU directive on Energy Service Contracting points at the buildings as the area where the biggest potential market for energy services and energy efficiency improvements are. The EFP-project has two parts: (1) A Danish part and (2) participation in the international cooperation project 'Holistic Assesment Tool-Kit on Energy Efficient Retrofit Measures for Government Buildings (EnERGo)', Annex 46 under the IEA R and D program 'Energy Conservation In Buildings And Community Systems' (ECBCS). This report describes the Danish contributions to the IEA projects subtask B, which has a primary objective to develop a database of energy conservation measures (ECM) with descriptions and performance characteristics of these. (au)

  19. Perlite as a potential support for nickel catalyst in the process of sunflower oil hydrogenation

    Science.gov (United States)

    Radonjić, V.; Krstić, J.; Lončarević, D.; Jovanović, D.; Vukelić, N.; Stanković, M.; Nikolova, D.; Gabrovska, M.

    2015-12-01

    Investigation was conducted in order to elucidate the possibility of using perlite as support for preparation of nickel based precursor catalyst, potentially applicable in vegetable oil hydrogenation process. On three differently prepared expanded perlite, nickel catalyst precursors with identical Ni/SiO2 = 1.1 and Ni/Mg = 10/1 ratios were synthesized by precipitation-deposition method. Different techniques, SEM micrography, He-pycnometry, calcimetry, Hg-porosimetry, N2-physisorption, H2-chemisorption and temperature programmed reduction, were used for characterization of obtained samples. Determining the precursor texture, morphology and reducibility shows a successfully deposited nickel phase on perlite support with promising properties for vegetable oil hydrogenation. Chosen precursor was reduced and passivated in paraffin oil and the obtained catalyst showed significant catalytic activity in the test of sunflower oil hydrogenation.

  20. Energy Diagram for the Catalytic Decomposition of Hydrogen Peroxide

    Science.gov (United States)

    Tatsuoka, Tomoyuki; Koga, Nobuyoshi

    2013-01-01

    Drawing a schematic energy diagram for the decomposition of H[subscript 2]O[subscript 2] catalyzed by MnO[subscript 2] through a simple thermometric measurement outlined in this study is intended to integrate students' understanding of thermochemistry and kinetics of chemical reactions. The reaction enthalpy, delta[subscript r]H, is…

  1. Characteristics of Ampel bamboo as a biomass energy source potential in Bali

    Science.gov (United States)

    Sucipta, M.; Putra Negara, D. N. K.; Tirta Nindhia, T. G.; Surata, I. W.

    2017-05-01

    Currently, non-renewable fossil energy dominates utilization of the world energy need for many applications. Efforts has been developed to find alternative renewable energy sources, due to fossil energy availability is diminishing. And one of renewable energy source is from biomass. The aim of this research is to determine characteristics of the Ampel bamboo (Bambusa vulgaris) as an energy potential of biomass. The Ampel bamboo’s characteristics possessed are evaluated based on its chemical composition; moisture, volatile, ash, and fixed carbon through proximate analysis; and also carbon, hydrogen and nitrogen content through ultimate analysis. From the Thermo-gravimetric analysis (TGA) indicates that Ampel bamboo contains of about 18.10% hemicelluloses, 47.75% cellulose and 18.86% lignin. While from the ultimate analysis results in the content of carbon, hydrogen, and Nitrogen of Ampel bamboo are 39.75%, 5.75% and 0% respectively. With such characteristics, it indicates that Ampel bamboo has an attractive potential as a renewable energy source.

  2. DFTB Parameters for the Periodic Table, Part 2: Energies and Energy Gradients from Hydrogen to Calcium.

    Science.gov (United States)

    Oliveira, Augusto F; Philipsen, Pier; Heine, Thomas

    2015-11-10

    In the first part of this series, we presented a parametrization strategy to obtain high-quality electronic band structures on the basis of density-functional-based tight-binding (DFTB) calculations and published a parameter set called QUASINANO2013.1. Here, we extend our parametrization effort to include the remaining terms that are needed to compute the total energy and its gradient, commonly referred to as repulsive potential. Instead of parametrizing these terms as a two-body potential, we calculate them explicitly from the DFTB analogues of the Kohn-Sham total energy expression. This strategy requires only two further numerical parameters per element. Thus, the atomic configuration and four real numbers per element are sufficient to define the DFTB model at this level of parametrization. The QUASINANO2015 parameter set allows the calculation of energy, structure, and electronic structure of all systems composed of elements ranging from H to Ca. Extensive benchmarks show that the overall accuracy of QUASINANO2015 is comparable to that of well-established methods, including PM7 and hand-tuned DFTB parameter sets, while coverage of a much larger range of chemical systems is available.

  3. Hydrogen production through nuclear energy, a sustainable scenario in Mexico; Produccion de hidrogeno mediante energia nuclear, un escenario sostenible en Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Ortega V, E.; Francois L, J.L. [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Laboratorio de Analisis en Ingenieria de Reactores Nucleares, Paseo Cuauhnahuac 8532, Jiutepec, Morelos (Mexico)]. e-mail: iqoren@gmail.com

    2007-07-01

    The energy is a key point in the social and economic development of a country, for such motive to assure the energy supply in Mexico it is of vital importance. The hydrogen it is without a doubt some one of the alternating promising fuels before the visible one necessity to decentralize the energy production based on hydrocarbons. The versatility of their applications, it high heating power and having with the more clean fuel cycle of the energy basket with which count at the moment, they are only some examples of their development potential. However the more abundant element of the universe it is not in their elementary form in our planet, it forms molecules like in the hydrocarbons or water and it stops their use it should be extracted. At the present time different methods are known for the extraction of hydrogen, there is thermal, electric, chemical, photovoltaic among others. The election of the extraction method and the primary energy source to carry out it are decisive to judge the sustainability of the hydrogen production. The sustainable development is defined as development that covers the present necessities without committing the necessity to cover the necessities of the future generations, and in the mark of this definition four indicators of the sustainable development of the different cycles of fuel were evaluated in the hydrogen production in Mexico. These indicators take in consideration the emissions of carbon dioxide in the atmosphere (environment), the readiness of the energy resources (technology), the impacts in the floor use (social) and the production costs of the cycles (economy). In this work the processes were studied at the moment available for the generation of hydrogen, those that use coal, natural gas, hydraulic, eolic energy, biomass and nuclear, as primary energy sources. These processes were evaluated with energy references of Mexico to obtain the best alternative for hydrogen production. (Author)

  4. Meeting Cathala-Letort named: the challenges of the processes engineering facing the hydrogen-energy; Journee Cathala-Letort intitulee: les defis du genie des procedes face a l'hydrogene-energie

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This document provides the presentations proposed during the day Cathala-Letort on the challenges of the processes engineering facing the hydrogen-energy. In the context of the greenhouse effect increase and the fossil energies resources decrease, it brings information on researches on hydrogen technologies, carbon dioxide sequestration, hydrogen supply, production, storage and distribution and the thermo-chemical cycles. (A.L.B.)

  5. Hydrogen production potentials and fermentative characteristics of various substrates with different heat-pretreated natural microflora

    Energy Technology Data Exchange (ETDEWEB)

    Akutsu, Yohei [Department of Civil and Environmental Engineering, Tohoku University, 6-6-06 Aoba, Sendai, Miyagi 980-8579 (Japan); Lee, Dong-Yeol [Research Center for Material Cycles and Waste Management, National Institute for Environmental Studies, 16-2, Onogawa, Tsukuba, Ibaraki 305-8506 (Japan); Li, Yu-You [Department of Environmental Science, Tohoku University, 6-6-06 Aoba, Sendai, Miyagi 980-8579 (Japan); Department of Environmental and Municipal Engineering, Tianjin Institute of Urban Construction, Jinjinggonglu 26, Tianjin 300384 (China); Noike, Tatsuya [Advanced Research Institute for the Sciences and Humanities, Nihon University, 2-1 Kudan-kita 4-chome, Chiyoda-ku, Tokyo 102-0073 (Japan)

    2009-07-15

    Batch tests were carried out to investigate the effects of heat-pretreated inocula on the fermentative hydrogen production characteristics of various types of substrates. A total of 8 different inocula and 4 different substrates (starch, glycerol, oil and peptone) were used. Heat pretreatment of the inocula was conducted in order to harvest spore-forming clostridial bacteria. Significant hydrogen production potentials were observed from starch (20.5-174.4 ml H{sub 2}/g-COD{sub starch}) and glycerol (11.5-38.1 ml H{sub 2}/g-COD{sub glycerol}); however, almost no hydrogen was produced from oil and peptone. When starch was used as a substrate, two different fermentation patterns were observed, according to the inocula: butyric acid-type and ethanol-type fermentation. Polymerase chain reaction combined with denaturing gradient gel electrophoresis (PCR-DGGE) analysis was conducted to compare the bacterial structures cultivated on the starch medium. Different species of clostridial bacteria were observed between the butyric acid-type and ethanol-type fermentation cultures. When glycerol was used as a substrate, 1,3-propanediol was the main by-product with each inoculum. The results of the present study suggest that simultaneous production of ethanol or 1,3-propanediol in addition to hydrogen is a more promising strategy than conventional hydrogen production in acidogenesis. (author)

  6. Hydrogen atom wave function and eigen energy in the Rindler space

    CERN Document Server

    Dai, De-Chang

    2016-01-01

    We study the hydrogen atom eigenstate energy and wave function in the Rindler space. The probability distribution is tilted because the electric field of the nucleus is no longer spherically symmetric. The hydrogen atom therefore cannot be treated exactly in the same way as what it is in an inertial frame. We also find that if the external force accelerates only the nucleus and then the nucleus accelerates its surrounding electrons through electromagnetic force, the electrons can tunnel through the local energy gap and split the hydrogen atom into an ion. This is similar to what one expects from the Stark effect. However, the critical acceleration is about $3\\times 10^{22} m/s^2$. It is well beyond the gravitational acceleration on a regular star surface.

  7. Exergetic Aspects of Hydrogen Energy Systems—The Case Study of a Fuel Cell Bus

    Directory of Open Access Journals (Sweden)

    Evanthia A. Nanaki

    2017-02-01

    Full Text Available Electrifying transportation is a promising approach to alleviate climate change issues arising from increased emissions. This study examines a system for the production of hydrogen using renewable energy sources as well as its use in buses. The electricity requirements for the production of hydrogen through the electrolysis of water, are covered by renewable energy sources. Fuel cells are being used to utilize hydrogen to power the bus. Exergy analysis for the system is carried out. Based on a steady-state model of the processes, exergy efficiencies are calculated for all subsystems. The subsystems with the highest proportion of irreversibility are identified and compared. It is shown that PV panel has exergetic efficiency of 12.74%, wind turbine of 45%, electrolysis of 67%, and fuel cells of 40%.

  8. Investigation of Highly Designable Dented Structures in HP Model with Hydrogen Bond Energy

    Institute of Scientific and Technical Information of China (English)

    ZHANG Wei; HUANG Shengyou; YU Tao; ZOU Xianwu

    2007-01-01

    Some highly designable protein structures have dented on the surface of their native structures, and are not full compactly folded. According to hydrophobic-polar (HP) model the most designable structures are full compactly folded. To investigate the designability of the dented structures, we introduce the hydrogen bond energy in the secondary structures by using the secondary-structure-favored HP model proposed by Ou-yang etc. The result shows that the average designability increases with the strength of the hydrogen bond. The designabilities of the structures with same dented shape increase exponentially with the number of secondary structure sites. The dented structures can have the highest designabilities for a certain value of hydrogen bond energy density.

  9. Hydrogen atom wave function and eigen energy in the Rindler space

    Science.gov (United States)

    Dai, De-Chang

    2016-10-01

    We study the hydrogen atom eigenstate energy and wave function in the Rindler space. The probability distribution is tilted because the electric field of the nucleus is no longer spherically symmetric. The hydrogen atom therefore cannot be treated exactly in the same way as what it is in an inertial frame. We also find that if the external force accelerates only the nucleus and then the nucleus accelerates its surrounding electrons through electromagnetic force, the electrons can tunnel through the local energy gap and split the hydrogen atom into an ion. This is similar to what one expects from the Stark effect. However, the critical acceleration is about 3 ×1022 m /s2. It is well beyond the gravitational acceleration on a regular star surface.

  10. Effect of Cadmium Plating Thickness on the Charpy Impact Energy of Hydrogen-Charged 4340 Steel

    Science.gov (United States)

    Es-Said, O. S.; Alcisto, J.; Guerra, J.; Jones, E.; Dominguez, A.; Hahn, M.; Ula, N.; Zeng, L.; Ramsey, B.; Mulazimoglu, H.; Li, Yong-Jun; Miller, M.; Alrashid, J.; Papakyriakou, M.; Kalnaus, S.; Lee, E. W.; Frazier, W. E.

    2016-09-01

    Hydrogen was intentionally introduced into ultra-high strength steel by cadmium plating. The purpose was to examine the effect of cadmium plate thickness and hence hydrogen on the impact energy of the steel. The AISI 4340 steel was austenitized at 1000 °C for 1 h, water quenched, and tempered at temperatures between 257 and 593 °C in order to achieve a range of targeted strength levels. The specimens were cadmium plated with 0.00508 mm (0.2 mils), 0.00762 mm (0.3 mils), and 0.0127 mm (0.5 mils). Results demonstrated that the uncharged specimens exhibited higher impact energy values when compared to the plated specimens at all tempering temperatures. The cadmium-plated specimens had very low Charpy impact values irrespective of their ultimate tensile strength values. The model of hydrogen transport by mobile dislocations to the fracture site appears to provide the most suitable explanation of the results.

  11. High-energy tail of the linear momentum distribution in the ground state of hydrogen atoms or hydrogen-like ions

    Energy Technology Data Exchange (ETDEWEB)

    Oks, E. [Physics Department, Auburn University, Auburn, AL (United States)

    2001-06-14

    A long-standing dispute concerning the high-energy tail of the linear momentum distribution (HTMD) in the ground state of hydrogen atoms/hydrogen-like ions (GSHA) has been unresolved up to now. A possible resolution of the above dispute might be connected to the problem of the role of singular solutions of quantal equations, which is a fundamental problem in its own right. The paradigm is that, even allowing for finite nuclear sizes, singular solutions of the Dirac equation for the Coulomb problem should be rejected for nuclear charges Z<1/{alpha}{approx}137. In this paper we break this paradigm. First, we derive a general condition for matching a regular interior solution with a singular exterior solution of the Dirac equation for arbitrary interior and exterior potentials. Then we find explicit forms of several classes of potentials that allow such a match. Finally, we show that, as an outcome, the HTMD for the GSHA acquires terms falling off much slower than the 1/p{sup 6}-law prescribed by the previously adopted quantal result. Our results open up a unique way to test intimate details of the nuclear structure by performing atomic (rather than nuclear) experiments and calculations. (author)

  12. Calculated dipole moment and energy in collision of a hydrogen molecule and a hydrogen atom

    Science.gov (United States)

    Patch, R. W.

    1973-01-01

    Calculations were carried out using three Slater-type 1s orbitals in the orthogonalized valencebond theory of McWeeny. Each orbital exponent was optimized, the H2 internuclear distance was varied from 7.416 x 10 to the -11th power to 7.673 x 10 to the -11th power m (1.401 to 1.450 bohrs). The intermolecular distance was varied from 1 to 4 bohrs (0.5292 to 2.117 x 10 to the 10th power). Linear, scalene, and isosceles configurations were used. A weighted average of the interaction energies was taken for each intermolecular distance. Although energies are tabulated, the principal purpose was to calculate the electric dipole moment and its derivative with respect to H2 internuclear distance.

  13. Hg/HgO electrode and hydrogen evolution potentials in aqueous sodium hydroxide

    Energy Technology Data Exchange (ETDEWEB)

    Nickell, Ryan A.; Zhu, Wenhua H.; Payne, Robert U.; Cahela, Donald R.; Tatarchuk, Bruce J. [Center for Microfibrous Materials Manufacturing, Department of Chemical Engineering, 230 Ross Hall, Auburn University, Auburn, AL 36849 (United States)

    2006-10-27

    The Hg/HgO electrode is usually utilized as a reference electrode in alkaline solution such as for development of an alkaline hydrogen electrode. The reference electrode provides a suitable reference point but is available from few commercial vendors and suffers from inadequate documentation on potential in varying electrolytes. A new numerical method uses activity, activity coefficients, and a few correlated empirical equations to determine the potential values in both dilute and concentrated sodium hydroxide solutions at temperatures of 0-90{sup o}C and at concentrations of 0.100-12.8mol kg{sub H{sub 2}O}{sup -1}. The computed potentials of the Hg/HgO electrodes versus a normal hydrogen electrode (NHE) at 25{sup o}C and 1atm are 0.1634V for 0.100m, 0.1077V for 1.00m, and 0.0976V for 1.45m NaOH solutions. The Hg/HgO reduction potential further changes to -0.0751V versus NHE and hydrogen evolution potential changes to -0.9916V versus NHE in a solution of 30.0wt.% NaOH at 80{sup o}C. The calculated values are compared with the measured data at 25 and 75{sup o}C. The experimental data agree well with the numerical values computed from the theoretical and empirical equations. (author)

  14. Hg/HgO electrode and hydrogen evolution potentials in aqueous sodium hydroxide

    Science.gov (United States)

    Nickell, Ryan A.; Zhu, Wenhua H.; Payne, Robert U.; Cahela, Donald R.; Tatarchuk, Bruce J.

    The Hg/HgO electrode is usually utilized as a reference electrode in alkaline solution such as for development of an alkaline hydrogen electrode. The reference electrode provides a suitable reference point but is available from few commercial vendors and suffers from inadequate documentation on potential in varying electrolytes. A new numerical method uses activity, activity coefficients, and a few correlated empirical equations to determine the potential values in both dilute and concentrated sodium hydroxide solutions at temperatures of 0-90 °C and at concentrations of 0.100-12.8 mol k gH2O-1 . The computed potentials of the Hg/HgO electrodes versus a normal hydrogen electrode (NHE) at 25 °C and 1 atm are 0.1634 V for 0.100m, 0.1077 V for 1.00m, and 0.0976 V for 1.45m NaOH solutions. The Hg/HgO reduction potential further changes to -0.0751 V versus NHE and hydrogen evolution potential changes to -0.9916 V versus NHE in a solution of 30.0 wt.% NaOH at 80 °C. The calculated values are compared with the measured data at 25 and 75 °C. The experimental data agree well with the numerical values computed from the theoretical and empirical equations.

  15. Geothermal energy market potential in industrial processing

    Energy Technology Data Exchange (ETDEWEB)

    Schultz, R.J.; Hanny, J.A.; Knuth, W.H.

    1978-11-01

    Geothermal energy is currently being used for a number of industrial processes in countries throughout the world. Its application in the United States is mainly limited to space heating even though the temperature of the geothermal fluid is sufficient for process uses, and could be sold at attractive prices while maintaining a high return on investment. The temperature span for industrial use ranges from 40 to 275/sup 0/C, thus encompassing both the abundant low temperature and the less available high temperature resources. Hydrothermal fluids can be used either directly or indirectly dependent upon fluid quality and process needs. The barriers facing hydrothermal industrial process development are (a) the development infrastructure does not exist, (b) energy users are not aware of hydrothermal energy and its advantages, (c) federal incentives are limited, (d) resources are not fully defined.

  16. Generalized gradient approximation exchange energy functional with correct asymptotic behavior of the corresponding potential

    Energy Technology Data Exchange (ETDEWEB)

    Carmona-Espíndola, Javier, E-mail: jcarmona-26@yahoo.com.mx [Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, México D. F. 09340, México (Mexico); Gázquez, José L., E-mail: jlgm@xanum.uam.mx [Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, México D. F. 09340, México (Mexico); Departamento de Química, Centro de Investigación y de Estudios Avanzados, Av. Instituto Politécnico Nacional 2508, México D. F. 07360, México (Mexico); Vela, Alberto [Departamento de Química, Centro de Investigación y de Estudios Avanzados, Av. Instituto Politécnico Nacional 2508, México D. F. 07360, México (Mexico); Trickey, S. B. [Quantum Theory Project, Department of Physics and Department of Chemistry, University of Florida, P.O. Box 118435, Gainesville, Florida 32611-8435 (United States)

    2015-02-07

    A new non-empirical exchange energy functional of the generalized gradient approximation (GGA) type, which gives an exchange potential with the correct asymptotic behavior, is developed and explored. In combination with the Perdew-Burke-Ernzerhof (PBE) correlation energy functional, the new CAP-PBE (CAP stands for correct asymptotic potential) exchange-correlation functional gives heats of formation, ionization potentials, electron affinities, proton affinities, binding energies of weakly interacting systems, barrier heights for hydrogen and non-hydrogen transfer reactions, bond distances, and harmonic frequencies on standard test sets that are fully competitive with those obtained from other GGA-type functionals that do not have the correct asymptotic exchange potential behavior. Distinct from them, the new functional provides important improvements in quantities dependent upon response functions, e.g., static and dynamic polarizabilities and hyperpolarizabilities. CAP combined with the Lee-Yang-Parr correlation functional gives roughly equivalent results. Consideration of the computed dynamical polarizabilities in the context of the broad spectrum of other properties considered tips the balance to the non-empirical CAP-PBE combination. Intriguingly, these improvements arise primarily from improvements in the highest occupied and lowest unoccupied molecular orbitals, and not from shifts in the associated eigenvalues. Those eigenvalues do not change dramatically with respect to eigenvalues from other GGA-type functionals that do not provide the correct asymptotic behavior of the potential. Unexpected behavior of the potential at intermediate distances from the nucleus explains this unexpected result and indicates a clear route for improvement.

  17. Potential evaluation of biomass-based energy sources for Turkey

    Directory of Open Access Journals (Sweden)

    Mustafa Ozcan

    2015-06-01

    Full Text Available Turkey has great potential with respect to renewable energy sources (RES and, among such sources, “biomass energy” is of particular importance. The purpose of this study is to determine the primary electrical energy potential obtainable from the biomass potential, according to different biomass source types. In this study, the biomass sources of municipal solid wastes, energy crops, animal manure and urban wastewater treatment sludge are evaluated. For each source, individual biogas and biomass energy potential calculations are made. Methods for energy conversion from wastes applicable to the conditions of Turkey, and technical and economic parameters are used. As a result of the calculations made, the total primary energy value of biogas obtainable from the examined sources is 188.21 TWh/year. The total primary energy value related to the potential of the evaluated biomass sources is 278.40 TWh/year.

  18. Renewable Energy and Hydrogen System Concepts for Remote Communities in the West Nordic Region

    Energy Technology Data Exchange (ETDEWEB)

    Ulleberg, Oeystein; Moerkved, Andreas

    2008-02-25

    In 2003 the Nordic Council of Ministers granted the funding for the first of several studies on renewable energy and hydrogen (RE/H2) energy systems for remote communities in the West Nordic region. The objective with this report is to summarize the main findings from Phase II and III of the West Nordic project. The island Nolsoy, Faroe Islands, was selected as a case study. The main conclusion is that it makes sense to design a wind/diesel-system with thermal storage, both from a techno-economical and environmental point of view. Such systems can have close to 100% local utilization of the wind energy, and can cover up to 75% of the total annual electricity demand and 35% of the annual heat demand at a cost of energy around 0.07 - 0.09 euro/kWh. The introduction of a hydrogen system is technically feasible, but doubles the overall investment costs

  19. Energy potential in the food industry; Store energipotensialer i naeringsmiddelindustrien

    Energy Technology Data Exchange (ETDEWEB)

    Rosenberg, E; Risberg, T M; Mydske, H J; Helgerud, H E

    2007-07-01

    The food industry is one of the most power consuming industries (excluding the heavy industry) and has large potential for reducing the energy consumption. This report explains the most energy efficient measures and if the injunctions are followed

  20. Physico-chemical properties and energy potential of wood wastes ...

    African Journals Online (AJOL)

    Physico-chemical properties and energy potential of wood wastes from ... Journal Home > Vol 36, No 2 (2017) > ... The results are indications that the wood wastes are suitable as feedstock for renewable energy generation with little or no ...

  1. Efficient Energy Transfer in Supramolecular, Hydrogen-Bonded Polypyridylruthenium-Osmium Complexes

    NARCIS (Netherlands)

    Rau, Sven; Schäfer, Bernhard; Schebesta, Sebastian; Grüßing, André; Poppitz, Wolfgang; Walther, Dirk; Duati, Marco; Browne, Wesley R.; Vos, Johannes G.

    2003-01-01

    Hydrogen bond association between ruthenium bibenzimidazole and carboxylated polypyridylosmium complexes results in stable supramolecular aggregates. The determined stability constant of logK approximate to 6 +/- 0.3 allows efficient energy transfer from the ruthenium to the osmium moiety. (C) Wiley

  2. Control, monitoring and data acquisition architecture design for clean production of hydrogen from mini-wind energy

    Energy Technology Data Exchange (ETDEWEB)

    Villarroya, Sebastian; Cotos, Jose M. [Santiago de Compostela Univ. (Spain). Lab. of Systems; Gomez, Guillermo; Plaza, Borja [National Institute for Aerospace Technology (INTA), Torrejon de Ardoz, Madrid (Spain); Fontan, Manuel; Magdaleno, Alexander [OBEKI Innobe, Ibarra, Gipuzkoa (Spain); Vallve, Xavier; Palou, Jaume [Trama TecnoAmbiental, Barcelona (Spain)

    2010-07-01

    One of the pillars that holds up the stability and economic development of our society is the need to ensure a reliable and affordable supply of energy that meets our current energy needs. The high dependence on fossil fuels, our main source of primary energy, has many drawbacks mainly caused by greenhouse gases. It is urgent to address this unsustainable energy future through innovation, adoption of new energy alternatives and better use of existing technologies. In this context, hydrogen associated to renewable energy is probably an important part of that future. This paper presents a real demonstrator of energy generation and storage through the clean production of hydrogen from small wind energy. Thus, this demonstrator will allow the study of the technical and econonmic feasibility of hydrogen production. Wind energy will be stored as hydrogen for a later use. In this way hydrogen represents a form of no-loss energy battery. The use of small wind energy allows a more modular and scattered production even in developing countries. In this way, we avoid the transport of hydrogen and the electricity to produce it, improving system efficiency. Moreover, small wind systems require a lower initial investment in infrastructure which will facilitate the development of a separate market for hydrogen production. (orig.)

  3. Energy Efficient Catalytic Activation of Hydrogen peroxide for Green Chemical Processes: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Collins, Terrence J.; Horwitz, Colin

    2004-11-12

    A new, highly energy efficient approach for using catalytic oxidation chemistry in multiple fields of technology has been pursued. The new catalysts, called TAML® activators, catalyze the reactions of hydrogen peroxide and other oxidants for the exceptionally rapid decontamination of noninfectious simulants (B. atrophaeus) of anthrax spores, for the energy efficient decontamination of thiophosphate pesticides, for the facile, low temperature removal of color and organochlorines from pulp and paper mill effluent, for the bleaching of dyes from textile mill effluents, and for the removal of recalcitrant dibenzothiophene compounds from diesel and gasoline fuels. Highlights include the following: 1) A 7-log kill of Bacillus atrophaeus spores has been achieved unambiguously in water under ambient conditions within 15 minutes. 2) The rapid total degradation under ambient conditions of four thiophosphate pesticides and phosphonate degradation intermediates has been achieved on treatment with TAML/peroxide, opening up potential applications of the decontamination system for phosphonate structured chemical warfare agents, for inexpensive, easy to perform degradation of stored and aged pesticide stocks (especially in Africa and Asia), for remediation of polluted sites and water bodies, and for the destruction of chemical warfare agent stockpiles. 3) A mill trial conducted in a Pennsylvanian bleached kraft pulp mill has established that TAML catalyst injected into an alkaline peroxide bleach tower can significantly lower color from the effluent stream promising a new, more cost effective, energy-saving approach for color remediation adding further evidence of the value and diverse engineering capacity of the approach to other field trials conducted on effluent streams as they exit the bleach plant. 4) Dibenzothiophenes (DBTs), including 4,6-dimethyldibenzothiophene, the most recalcitrant sulfur compounds in diesel and gasoline, can be completely removed from model gasoline

  4. Wind Energy and Hydrogen, a previous Symbiosis announced; Energia eolica e hidrogeno. Una simbiosis anticipada

    Energy Technology Data Exchange (ETDEWEB)

    Aso Aguarta, I.; Correas Uson, L.; Burkhalter, E.

    2008-07-01

    Nowadays, renewable energies are taken an important role into electricity generation, in order to mitigate the Co2 emissions, which are producing the Climate Change. Spain, is a special case where wind energy has been developed for several years, so the percentage wind energy producing is really high, but as a renewable energy, this energy is only available when primary resources exist, in this case the wind, and in cases in which it does not exit, production is reduced drastically, so, it is necessary to develop energy storage systems, in order to increase the amount wind energy introduce into the electrical system, in order to be able to control the production. One storage method proposed is produce hydrogen, in order to be use later when the resources are not available, to produce energy. (Author) 8 refs.

  5. Charge state studies of low energy heavy ions passing through hydrogen and helium gas

    CERN Document Server

    Liu, W; Buchmann, L; Chen, A A; D'Auria, J M; D'Onofrio, A; Engel, S; Gialanella, L; Greife, U; Hunter, D; Hussein, A; Hutcheon, D A; Olin, A; Ottewell, D; Rogalla, D; Rogers, J; Romano, M; Roy, G; Terrasi, F

    2003-01-01

    Studies of the charge state distribution of low energy (<1.5 MeV/u), low Z (<13) heavy ions passing through hydrogen and helium gas of varying target pressure have been performed using separate windowless gas target systems at TRIUMF and the University of Naples. Semi-empirical relationships have been deduced to estimate the equilibrium charge state distributions as a function of beam energy. From these distributions, cross-sections for the relevant charge changing reactions have been deduced.

  6. Optimizing the Binding Energy of Hydrogen on Nanostructured Carbon Materials through Structure Control and Chemical Doping

    Energy Technology Data Exchange (ETDEWEB)

    Jie Liu

    2011-02-01

    The DOE Hydrogen Sorption Center of Excellence (HSCoE) was formed in 2005 to develop materials for hydrogen storage systems to be used in light-duty vehicles. The HSCoE and two related centers of excellence were created as follow-on activities to the DOE Office of Energy Efficiency and Renewable Energy’s (EERE’s) Hydrogen Storage Grand Challenge Solicitation issued in FY 2003. The Hydrogen Sorption Center of Excellence (HSCoE) focuses on developing high-capacity sorbents with the goal to operate at temperatures and pressures approaching ambient and be efficiently and quickly charged in the tank with minimal energy requirements and penalties to the hydrogen fuel infrastructure. The work was directed at overcoming barriers to achieving DOE system goals and identifying pathways to meet the hydrogen storage system targets. To ensure that the development activities were performed as efficiently as possible, the HSCoE formed complementary, focused development clusters based on the following four sorption-based hydrogen storage mechanisms: 1. Physisorption on high specific surface area and nominally single element materials 2. Enhanced H2 binding in Substituted/heterogeneous materials 3. Strong and/or multiple H2 binding from coordinated but electronically unsatruated metal centers 4. Weak Chemisorption/Spillover. As a member of the team, our group at Duke studied the synthesis of various carbon-based materials, including carbon nanotubes and microporous carbon materials with controlled porosity. We worked closely with other team members to study the effect of pore size on the binding energy of hydrogen to the carbon –based materials. Our initial project focus was on the synthesis and purification of small diameter, single-walled carbon nanotubes (SWNTs) with well-controlled diameters for the study of their hydrogen storage properties as a function of diameters. We developed a chemical vapor deposition method that synthesized gram quantities of carbon nanotubes with

  7. Supersymmetry of Demkov-Ostrovsky effective potentials at zero energy

    CERN Document Server

    Rosu, H C; Wolf, K B; Obregón, O; Rosu, Haret C; Reyes, Marco A; Wolf, Kurt Bernardo; Obregon, Octavio

    1995-01-01

    We present a Natanzon-type supersymmetric analysis of the wave problem with Demkov-Ostrovsky (DO) spherically symmetric class of focusing potentials at zero energy. It is known that at zero binding energy there exists a degenerate ``bound" state for this class of potentials. Working at zero energy and in the so-called R_{0}=0 sector, we obtain the corresponding superpartner (fermionic) DO scattering potentials within the standard one-dimensional supersymmetric procedure.

  8. Available Potential Energy and the Maintenance of the General Circulation

    OpenAIRE

    Lorenz, Edward N.

    2011-01-01

    The available potential energy of the atmosphere may be defined as the difference between the total potential energy and the minimum total potential energy which could result from any adiabatic redistribution of mass. It vanishes if the density stratification is horizontal and statically stable everywhere, and is positive otherwise. It is measured approximately by a weighted vertical average of the horizontal variance of temperature. In magnitude it is generally about ten times the total kine...

  9. Potential evaluation of biomass-based energy sources for Turkey

    OpenAIRE

    Mustafa Ozcan; Semra Öztürk; Yuksel Oguz

    2015-01-01

    Turkey has great potential with respect to renewable energy sources (RES) and, among such sources, “biomass energy” is of particular importance. The purpose of this study is to determine the primary electrical energy potential obtainable from the biomass potential, according to different biomass source types. In this study, the biomass sources of municipal solid wastes, energy crops, animal manure and urban wastewater treatment sludge are evaluated. For each source, individual biogas and biom...

  10. Introduction of hydrogen in the Norwegian energy system. NorWays - Regional model analysis

    Energy Technology Data Exchange (ETDEWEB)

    Rosenberg, Eva; Fidje, Audun; Espegren, Kari Aamodt

    2008-12-15

    The overall aim of the NorWays project has been to provide decision support for the introduction of hydrogen as an energy carrier in the Norwegian energy system. The NorWays project is a research project funded by the Research Council of Norway. An important task has been to develop alternative scenarios and identifying market segments and regions of the Norwegian energy system where hydrogen may play a significant role. The main scenarios in the project have been: Reference: Based on the assumptions of World Energy Outlook with no new transport technologies; HyWays: Basic assumptions with technology costs (H{sub 2}) based on results from the HyWays project; No tax: No taxes on transport energy ('revenue neutral'); CO{sub 2} reduction: Reduced CO{sub 2} emissions by 75% in 2050. Three regional models have been developed and used to analyse the introduction of hydrogen as energy carrier in competition with other alternatives such as natural gas, electricity, district heating and bio fuels.The focus of the analysis has been on the transportation sector. (Author)

  11. Scalable water splitting on particulate photocatalyst sheets with a solar-to-hydrogen energy conversion efficiency exceeding 1.

    Science.gov (United States)

    Wang, Qian; Hisatomi, Takashi; Jia, Qingxin; Tokudome, Hiromasa; Zhong, Miao; Wang, Chizhong; Pan, Zhenhua; Takata, Tsuyoshi; Nakabayashi, Mamiko; Shibata, Naoya; Li, Yanbo; Sharp, Ian D; Kudo, Akihiko; Yamada, Taro; Domen, Kazunari

    2016-06-01

    Photocatalytic water splitting using particulate semiconductors is a potentially scalable and economically feasible technology for converting solar energy into hydrogen. Z-scheme systems based on two-step photoexcitation of a hydrogen evolution photocatalyst (HEP) and an oxygen evolution photocatalyst (OEP) are suited to harvesting of sunlight because semiconductors with either water reduction or oxidation activity can be applied to the water splitting reaction. However, it is challenging to achieve efficient transfer of electrons between HEP and OEP particles. Here, we present photocatalyst sheets based on La- and Rh-codoped SrTiO3 (SrTiO3:La, Rh; ref. ) and Mo-doped BiVO4 (BiVO4:Mo) powders embedded into a gold (Au) layer. Enhancement of the electron relay by annealing and suppression of undesirable reactions through surface modification allow pure water (pH 6.8) splitting with a solar-to-hydrogen energy conversion efficiency of 1.1% and an apparent quantum yield of over 30% at 419 nm. The photocatalyst sheet design enables efficient and scalable water splitting using particulate semiconductors.

  12. Scalable water splitting on particulate photocatalyst sheets with a solar-to-hydrogen energy conversion efficiency exceeding 1%

    Science.gov (United States)

    Wang, Qian; Hisatomi, Takashi; Jia, Qingxin; Tokudome, Hiromasa; Zhong, Miao; Wang, Chizhong; Pan, Zhenhua; Takata, Tsuyoshi; Nakabayashi, Mamiko; Shibata, Naoya; Li, Yanbo; Sharp, Ian D.; Kudo, Akihiko; Yamada, Taro; Domen, Kazunari

    2016-06-01

    Photocatalytic water splitting using particulate semiconductors is a potentially scalable and economically feasible technology for converting solar energy into hydrogen. Z-scheme systems based on two-step photoexcitation of a hydrogen evolution photocatalyst (HEP) and an oxygen evolution photocatalyst (OEP) are suited to harvesting of sunlight because semiconductors with either water reduction or oxidation activity can be applied to the water splitting reaction. However, it is challenging to achieve efficient transfer of electrons between HEP and OEP particles. Here, we present photocatalyst sheets based on La- and Rh-codoped SrTiO3 (SrTiO3:La, Rh; ref. ) and Mo-doped BiVO4 (BiVO4:Mo) powders embedded into a gold (Au) layer. Enhancement of the electron relay by annealing and suppression of undesirable reactions through surface modification allow pure water (pH 6.8) splitting with a solar-to-hydrogen energy conversion efficiency of 1.1% and an apparent quantum yield of over 30% at 419 nm. The photocatalyst sheet design enables efficient and scalable water splitting using particulate semiconductors.

  13. Binding energies of hydrogen molecules to isoreticular metal-organic framework materials

    Science.gov (United States)

    Sagara, Tatsuhiko; Klassen, James; Ortony, Julia; Ganz, Eric

    2005-07-01

    Recently, several novel isoreticular metal-organic framework (IRMOF) structures have been fabricated and tested for hydrogen storage applications. To improve our understanding of these materials, and to promote quantitative calculations and simulations, the binding energies of hydrogen molecules to the MOF have been studied. High-quality second-order Møller-Plesset (MP2) calculations using the resolution of the identity approximation and the quadruple zeta QZVPP basis set were used. These calculations use terminated molecular fragments from the MOF materials. For H2 on the zinc oxide corners, the MP2 binding energy using Zn4O(HCO2)6 molecule is 6.28kJ/mol. For H2 on the linkers, the binding energy is calculated using lithium-terminated molecular fragments. The MP2 results with coupled-cluster singles and doubles and noniterative triples method corrections and charge-transfer corrections are 4.16kJ/mol for IRMOF-1, 4.72kJ/mol for IRMOF-3, 4.86kJ/mol for IRMOF-6, 4.54kJ/mol for IRMOF-8, 5.50 and 4.90kJ/mol for IRMOF-12, 4.87 and 4.84kJ/mol for IRMOF-14, 5.42kJ/mol for IRMOF-18, and 4.97 and 4.66kJ/mol for IRMOF-993. The larger linkers are all able to bind multiple hydrogen molecules per side. The linkers of IRMOF-12, IRMOF-993, and IRMOF-14 can bind two to three, three, and four hydrogen molecules per side, respectively. In general, the larger linkers have the largest binding energies, and, together with the enhanced surface area available for binding, will provide increased hydrogen storage. We also find that adding up NH2 or CH3 groups to each linker can provide up to a 33% increase in the binding energy.

  14. Bandwidth Study on Energy Use and Potential Energy Savings Opportunities in U.S. Petroleum Refining

    Energy Technology Data Exchange (ETDEWEB)

    Sabine Brueske, Caroline Kramer, Aaron Fisher

    2015-06-01

    Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. petroleum refining. The study relies on multiple sources to estimate the energy used in nine individual process areas, representing 68% of sector-wide energy consumption. Energy savings opportunities for individual processes are based on technologies currently in use or under development; these potential savings are then extrapolated to estimate sector-wide energy savings opportunity.

  15. Bandwidth Study on Energy Use and Potential Energy Saving Opportunities in U.S. Chemical Manufacturing

    Energy Technology Data Exchange (ETDEWEB)

    Sabine Brueske, Caroline Kramer, Aaron Fisher

    2015-06-01

    Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. chemical manufacturing. The study relies on multiple sources to estimate the energy used in the production of 74 individual chemicals, representing 57% of sector-wide energy consumption. Energy savings opportunities for individual chemicals and for 15 subsectors of chemicals manufacturing are based on technologies currently in use or under development; these potential savings are then extrapolated to estimate sector-wide energy savings opportunity.

  16. High level theoretical study of binding and of the potential energy surface in benzene-hydride system

    Energy Technology Data Exchange (ETDEWEB)

    Coletti, Cecilia, E-mail: ccoletti@unich.it [Dipartimento di Scienze del Farmaco, Universita ' G. d' Annunzio' Chieti-Pescara, Via dei Vestini 31, 66100 Chieti (Italy); Re, Nazzareno [Dipartimento di Scienze del Farmaco, Universita ' G. d' Annunzio' Chieti-Pescara, Via dei Vestini 31, 66100 Chieti (Italy)

    2012-04-04

    Graphical abstract: In-plane minimum geometries for benzene-H{sup -} non-covalent adducts: linear adduct (left) with the hydride ion hydrogen bonded to one aromatic hydrogen; bifurcated adduct (right), with the hydride ion hydrogen bonded to two adjacent aromatic hydrogens. Highlights: Black-Right-Pointing-Pointer Theoretical study on covalent and non-covalent binding in benzene-hydride. Black-Right-Pointing-Pointer Two non-covalent stable adducts were characterized in the in-plane geometry. Black-Right-Pointing-Pointer Significant sections of the potential energy surface were determined. Black-Right-Pointing-Pointer Formation of a very stable C{sub 6}H{sub 7}{sup -} anion upon covalent binding to carbon. - Abstract: High level ab initio calculations were performed on the interaction of the hydride anion with benzene, a system of potential interest for modelling the interactions occurring in hydrogen rich planetary atmospheres. We investigated both non-covalent and covalent binding, exploring the complete basis set limit using highly correlated MP2 and CCSD(T) levels of theory. Two non-covalent minima on the potential energy surface have been characterized, and found to correspond to moderately strong hydrogen bonding interactions. To gain further insight on the nature of binding, the total interaction energy was decomposed into its physically meaningful components and selected sections of the potential energy surface were calculated. Moreover, we found that H{sup -} can easily covalently bind to one of the carbon atoms of benzene to form a stable C{sub 6}H{sub 7}{sup -} anion, a global minimum on the potential energy surface, characterized by a puckered geometry, with a carbon atom bending out of the benzene plane. A slightly less stable planar C{sub 6}H{sub 7}{sup -} structure was also identified, corresponding to the transition state for the flipping motion of the puckered species.

  17. Energy Savings Potential and Research & Development Opportunities for Commercial Refrigeration

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2009-09-01

    This study documents the energy consumption of commercial refrigeration equipment (CRE) in the U.S. and evaluated the energy savings potential of various technologies and energy efficiency measures that could be applied to such equipment. The study provided an overview of CRE applications, assessed the energy-savings potential of CRE in the U.S., outline key barriers to adoption of energy-savings technologies, and recommended opportunities for advanced energy saving technology research. The study was modeled after an earlier 1996 report by Arthur D. Little, Inc., and updated key information, examined more equipment types, and outlined long-term research and development opportunities.

  18. Toward high-precision values of the self energy of non-S states in hydrogen and hydrogen-like ions

    CERN Document Server

    Le Bigot, E O; Jentschura, U D; Mohr, P J; Bigot, Eric-Olivier Le; Indelicato, Paul; Jentschura, Ulrich D.; Mohr, Peter J.; ccsd-00003072, ccsd

    2004-01-01

    The method and status of a study to provide numerical, high-precision values of the self-energy level shift in hydrogen and hydrogen-like ions is described. Graphs of the self energy in hydrogen-like ions with nuclear charge number between 20 and 110 are given for a large number of states. The self-energy is the largest contribution of Quantum Electrodynamics (QED) to the energy levels of these atomic systems. These results greatly expand the number of levels for which the self energy is known with a controlled and high precision. Applications include the adjustment of the Rydberg constant and atomic calculations that take into account QED effects.

  19. Linac4 low energy beam measurements with negative hydrogen ions.

    Science.gov (United States)

    Scrivens, R; Bellodi, G; Crettiez, O; Dimov, V; Gerard, D; Granemann Souza, E; Guida, R; Hansen, J; Lallement, J-B; Lettry, J; Lombardi, A; Midttun, Ø; Pasquino, C; Raich, U; Riffaud, B; Roncarolo, F; Valerio-Lizarraga, C A; Wallner, J; Yarmohammadi Satri, M; Zickler, T

    2014-02-01

    Linac4, a 160 MeV normal-conducting H(-) linear accelerator, is the first step in the upgrade of the beam intensity available from the LHC proton injectors at CERN. The Linac4 Low Energy Beam Transport (LEBT) line from the pulsed 2 MHz RF driven ion source, to the 352 MHz RFQ (Radiofrequency Quadrupole) has been built and installed at a test stand, and has been used to transport and match to the RFQ a pulsed 14 mA H(-) beam at 45 keV. A temporary slit-and-grid emittance measurement system has been put in place to characterize the beam delivered to the RFQ. In this paper a description of the LEBT and its beam diagnostics is given, and the results of beam emittance measurements and beam transmission measurements through the RFQ are compared with the expectation from simulations.

  20. Linac4 Low Energy Beam Measurements with Negative Hydrogen

    CERN Document Server

    Scrivens, R; Crettiez, O; Dimov, V; Gerard, D; Granemann Souza, E; Guida, R; Hansen, J; Lallement, J B; Lettry, J; Lombardi, A; Midttun, O; Pasquino, C; Raich, U; Riffaud, B; Roncarolo, F; Valerio-Lizarraga, C A; Wallner, J; Yarmohammadi Satri, M; Zickler, T

    2014-01-01

    Linac4, a 160 MeV normal-conducting H- linear accelerator, is the first step in the upgrade of the beam intensity available from the LHC proton injectors at CERN. The Linac4 Low Energy Beam Transport (LEBT) line from the pulsed 2 MHz RF driven ion source, to the 352 MHz RFQ has been built and installed at a test stand, and has been used to transport and match to the RFQ a pulsed 14 mA H- beam at 45 keV. A temporary slit-and-grid emittance measurement system has been put in place to characterize the beam delivered to the RFQ. In this paper a description of the LEBT and its beam diagnostics is given, and the results of beam emittance measurements and beam transmission measurements through the RFQ are compared with the expectation from simulations.

  1. Linac4 low energy beam measurements with negative hydrogen ions

    Energy Technology Data Exchange (ETDEWEB)

    Scrivens, R., E-mail: richard.scrivens@cern.ch; Bellodi, G.; Crettiez, O.; Dimov, V.; Gerard, D.; Granemann Souza, E.; Guida, R.; Hansen, J.; Lallement, J.-B.; Lettry, J.; Lombardi, A.; Midttun, Ø.; Pasquino, C.; Raich, U.; Riffaud, B.; Roncarolo, F.; Valerio-Lizarraga, C. A.; Wallner, J.; Yarmohammadi Satri, M.; Zickler, T. [CERN, 1211 Geneva 23 (Switzerland)

    2014-02-15

    Linac4, a 160 MeV normal-conducting H{sup −} linear accelerator, is the first step in the upgrade of the beam intensity available from the LHC proton injectors at CERN. The Linac4 Low Energy Beam Transport (LEBT) line from the pulsed 2 MHz RF driven ion source, to the 352 MHz RFQ (Radiofrequency Quadrupole) has been built and installed at a test stand, and has been used to transport and match to the RFQ a pulsed 14 mA H{sup −} beam at 45 keV. A temporary slit-and-grid emittance measurement system has been put in place to characterize the beam delivered to the RFQ. In this paper a description of the LEBT and its beam diagnostics is given, and the results of beam emittance measurements and beam transmission measurements through the RFQ are compared with the expectation from simulations.

  2. Socio-cultural barriers to the development of a sustainable energy system - the case of hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Kjerulf Petersen, L.; Holst Andersen, A.

    2009-02-15

    Any transition to a more sustainable energy system, radically reducing greenhouse gas emissions, is bound to run in to a host of different barriers - technological and economic, but also socio-cultural. This will also be the case for any large-scale application of hydrogen as energy carrier, especially if the system is going to be based on renewable energy sources. The aim of these research notes is to review and discuss major socio-cultural barriers to new forms of energy supply in general and to hydrogen specifically. Reaching sufficient reductions in greenhouse gas emissions may require more than large-scale dissemination of renewable energy sources. Also reductions or moderations in energy demand may be necessary. Hence, a central point in the research note is to consider not only socio-cultural obstacles for changing technologies in energy production, distribution and consumption but also obstacles for changing the scale of energy consumption, i.e. moderating the growth in how much energy is consumed or even reducing consumption volumes. (au)

  3. Laboratory of alternative energies and hydrogen in ESPOL. Coupling needs and knowledge

    Energy Technology Data Exchange (ETDEWEB)

    Mendieta, E. [Escuela Superior Politecnica del Litoral, Campus Gustavo Galindo, Guayaquil (Ecuador)

    2009-07-01

    The Ecuadorian problems with electricity and oil for the near future are shortly assessed in this paper. The main Ecuadorian universities contribution towards a real solution is also mentioned here. Projected Knowledge Park of ESPOL (PARCON) and its 7 integrated research centers is presented briefly. The integration of multidisciplinary research being developed in ESPOL is one foundation for this Knowledge Park. The results of previous researches like the Hydrogen project will be used to set the first stage database for future R and D initiatives. The University of Applied Science of Stralsund is one formal partner for ESPOL in Alternative Energies and Hydrogen utilization. (orig.)

  4. Variational calculations for the hydrogen-antihydrogen system with a mass-scaled Born-Oppenheimer potential

    CERN Document Server

    Stegeby, Henrik; Karlsson, Hans O; Lindh, Roland; Froelich, Piotr

    2012-01-01

    The problem of proton-antiproton motion in the ${\\rm H}$--${\\rm \\bar{H}}$ system is investigated by means of the variational method. We introduce a modified nuclear interaction through mass-scaling of the Born-Oppenheimer potential. This improved treatment of the interaction includes the nondivergent part of the otherwise divergent adiabatic correction and shows the correct threshold behavior. Using this potential we calculate the vibrational energy levels with angular momentum 0 and 1 and the corresponding nuclear wave functions, as well as the S-wave scattering length. We obtain a full set of all bound states together with a large number of discretized continuum states that might be utilized in variational four-body calculations. The results of our calculations gives an indication of resonance states in the hydrogen-antihydrogen system.

  5. Potential Energy Sources Pose Mining Problem

    Science.gov (United States)

    Chemical and Engineering News, 1974

    1974-01-01

    Summarizes the discussions of a Division of Industrial and Engineering Chemistry symposium on solids handling for synthetic fuels production. Included is a description of technical difficulties with the use of coal seams and deposits of oil shale and oil sand as potential sources of fuel. (CC)

  6. Hydrogen production by hybrid electrolysis combined with assistance of solar energy

    Science.gov (United States)

    Takehara, Z.; Yoshizawa, S.

    As a means of reducing the electrical energy needed to produce hydrogen from water, a process is presented, whereby an aqueous sulfuric acid solution containing Fe(2+) ions is electrolyzed, hydrogen being an energy storage material which levels load variation of electrical utilities. In an electrolytic cell, Fe(2+) ions are oxidized on a packed bed carbon anode to form Fe(3+) ions. H(+) ions diffuse through a cation exchange membrane, and are then reduced to hydrogen gas on the cathode. The Fe(3+) ions, produced in the cell, are decomposed in a photodecomposition cell. Oxygen evolves on the TiO2 anode, illuminated by solar light; the produced H(+) ions are diffused through a cation exchange membrane and electrons move through the metal inserted in the membrane to the cathode. The solution containing Fe(+) ions, introduced in the cathode chamber, is reduced cathodically on the platinized platinum. Cell voltage is determined for the process and it is found to be only about 1.0 V for electrolysis of 50mA/sq cm at room temperature. For the case of direct electrolysis of 2N NaOH aqueous solution, the cell voltage is 2.2V electrolysis of 30mA/sq cm. Results indicate a large reduction of electrical energy needed for the production of hydrogen in the process presented.

  7. Zeta-function approach to Casimir energy with singular potentials

    CERN Document Server

    Khusnutdinov, N R

    2006-01-01

    In the framework of zeta-function approach the Casimir energy for three simple model system: single delta potential, step function potential and three delta potentials is analyzed. It is shown that the energy contains contributions which are peculiar to the potentials. It is suggested to renormalize the energy using the condition that the energy of infinitely separated potentials is zero which corresponds to subtraction all terms of asymptotic expansion of zeta-function. The energy obtained in this way obeys all physically reasonable conditions. It is finite in the Dirichlet limit and it may be attractive or repulsive depending on the strength of potential. The effective action is calculated and it is shown that the surface contribution appears. The renormalization of the effective action is discussed.

  8. Results of the 2008/2009 Knowledge and Opinions Surveys Conducted for the U.S. Department of Energy Hydrogen Program

    Energy Technology Data Exchange (ETDEWEB)

    Schmoyer, R. L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Truett, Tykey [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Cooper, Christy [Dept. of Energy (DOE), Washington DC (United States); Chew, Andrea [Dept. of Energy (DOE), Washington DC (United States)

    2010-04-01

    This report presents results of a 2008/2009 survey of hydrogen and fuel cell awareness conducted for the U.S. Department of Energy (DOE). The 2008/2009 survey follows up on a similar DOE survey conducted in 2004, measuring levels of awareness and understanding of hydrogen and fuel cell technologies in four populations: (1) the general public, (2) students, (3) personnel in state and local governments, and (4) potential end users of hydrogen and fuel cell technologies in business and industry. The 2008/2009 survey includes these four groups and adds a fifth group, safety and code officials. The same survey methods were used for both surveys; the 2008/2009 survey report includes a comparison of 2004 and 2008/2009 findings. Information from these surveys will be used to enhance hydrogen and fuel cell education strategies.

  9. Diabatic potential energy surfaces of H+ + CO

    Indian Academy of Sciences (India)

    F George D X; Sanjay Kumar

    2007-09-01

    Ab initio adiabatic and diabatic surfaces of the ground and the first excited electronic states have been computed for the H+ + CO system for the collinear ( = 0°) and the perpendicular ( = 90°) geometries employing the multi-reference configuration interaction method and Dunning's -VTZ basis set. Other properties such as mixing angle before coupling potential and before coupling matrix elements have also been obtained in order to provide an understanding of the coupling dynamics of inelastic and charge transfer process.

  10. Properties of SBA-15 modified by iron nanoparticles as potential hydrogen adsorbents and sensors

    Science.gov (United States)

    Bouazizi, N.; Ouargli, R.; Nousir, S.; Slama, R. Ben; Azzouz, A.

    2015-02-01

    SBA-15-Fe was synthesized via the incorporation of Fe0 nanoparticles (Fe(0)-Nps) in the mesoporous channels. Electron microscopy and X-ray diffraction showed that dispersion of fine iron NPs occurs mainly inside the channels of SBA-15, producing a slight structure compaction. This was accompanied by a significant improvement of both the affinity towards hydrogen and electrical conductivity, as supported by hydrogen adsorption tests and impedance measurements. CO2 thermal programmed desorption measurements revealed an attenuation of the acid character of the solid surface. This was explained in terms of strong iron interaction with the lattice oxygen atoms that reduces the SiO-H bond polarity. The close vicinity of fine Fe(0)-Nps combined with the large pore size of SBA-15 appear to contribute to a synergistic improvement of the electrical conductivity. The results reported herein open new prospects for SBA-15 as potential adsorbents for hydrogen storage and carriers for hydrogen sensors. The use of iron in lieu of noble metals for designing such materials is a novelty, because such applications of iron-loaded silica have not been envisaged so far due to the high reactivity of iron towards air and water. The development of such technologies, if any, should address this issue.

  11. On the hypothetical utilization of atmospheric potential energy

    Directory of Open Access Journals (Sweden)

    Thomas Frisius

    2014-09-01

    Full Text Available Atmospheric potential energy is typically divided into an available and a nonavailable part. In this article a hypothetical utilization of a fraction of the nonavailable potential energy is described. This part stems from the water vapor that can be converted into the liquid phase. An energy gain results when the potential energy of the condensate relative to a reference height exceeds the energy necessary to condensate the water vapor. It is shown that this can be the case in a saturated atmosphere without convective available potential energy. Finally, simulations with the numerical cloud model HURMOD are performed to estimate the usability of the device in practice. Indeed, a positive energy output results in a simulation with immediate gathering of the condensate. On the contrary, potential energy gained falls significantly short of the necessary energy for forming the condensate when a realistic cloud microphysical scheme allowing re-evaporation of condensate is applied. Taken together it can be concluded that, a utilization of atmospheric potential energy is hypothetically possible but the practical realization is probably not feasible.

  12. A hierarchy of potential energy surfaces constructed from energies and energy derivatives calculated on grids

    Science.gov (United States)

    Matito, Eduard; Toffoli, Daniele; Christiansen, Ove

    2009-04-01

    In this work we develop and test a methodology for the generation of Born-Oppenheimer potential energy surfaces (PES) for use in vibrational structure calculations. The method relies on the widely used restricted-mode-coupling expansion of the fully coupled potential surface where only up to n or less vibrational coordinates are coupled in the potential. Low-order derivatives of the energy are then used to extrapolate the higher mode-coupling potential terms; derivative information is thus used in a convenient way for the evaluation of higher mode couplings avoiding their explicit calculation on multidimensional grids. The formulation, which is a variant of the popular modified Shepard interpolation, is general for any extrapolation of (n +p)-mode-coupling terms from n-mode couplings and can be applied to the energy or any other molecular property surface for which derivative information is available. The method depends only on analytical parameter-free weight functions that satisfy important limiting conditions and control the contribution from each direction of extrapolation. The procedure has been applied on a representative set of 13 molecules, and its accuracy has been tested using only gradients and using both gradients and Hessians. The results provide evidence for the importance of higher mode couplings and illustrate the cost efficiency of the proposed approach.

  13. Wind energy potential in Aden-Yemen

    Energy Technology Data Exchange (ETDEWEB)

    Algifri, A.H. [University of Aden (Republic of Yemen). Faculty of Engineering

    1998-02-01

    In this article a number of years data on wind speed in Aden has been studied and presented. A statistical analysis was carried out from which the annual wind speed was found to be 4.5 m/s and most of the time the wind speed is in the range of 3.5-7.5 m/s. The wind speed distributions were represented by Weibull and Rayleigh distributions. It was found that the Rayleigh distribution is suitable to represent the actual probability of wind speed data for Aden. The wind speed data showed that the maximum monthly wind speed occurs in the month of February with the maximum in the month of June. It is concluded that Aden can be explored for wind energy applications. (author)

  14. Scaling properties of adsorption energies for hydrogen-containing molecules on transition-metal surfaces

    DEFF Research Database (Denmark)

    Abild-Pedersen, Frank; Greeley, Jeffrey Philip; Studt, Felix

    2007-01-01

    with the adsorption energy of the central, C, N, O, or S atom, the scaling constant depending only on x. A model is proposed to understand this behavior. The scaling model is developed into a general framework for estimating the reaction energies for hydrogenation and dehydrogenation reactions.......Density functional theory calculations are presented for CHx, x=0,1,2,3, NHx, x=0,1,2, OHx, x=0,1, and SHx, x=0,1 adsorption on a range of close-packed and stepped transition-metal surfaces. We find that the adsorption energy of any of the molecules considered scales approximately...

  15. Geothermal energy potential in the San Luis Valley, Colorado

    Energy Technology Data Exchange (ETDEWEB)

    Coe, B.A.

    1980-01-01

    The background of the area itself is investigated considering the geography, population, economy, attitudes of residents, and energy demands of the area. The requirements for geothermal energy development are considered, including socio-economic, institutional, and environmental conditions as well as some technical aspects. The current, proposed, and potential geothermal energy developments are described. The summary, conclusions, and methodology are included. (MHR)

  16. Energy saving potential of emerging technologies in milk powder production

    NARCIS (Netherlands)

    Moejes, S.N.; Boxtel, van A.J.B.

    2017-01-01

    Background

    The food industry has a large potential for energy reduction which, with an eye on the future, has to be exploited. Milk powder production consists of many thermal processes and is responsible for 15% of the total energy use in the dairy industry. A reduction in energy consumptio

  17. Efficiency and cost advantages of an advanced-technology nuclear electrolytic hydrogen-energy production facility

    Science.gov (United States)

    Donakowski, T. D.; Escher, W. J. D.; Gregory, D. P.

    1977-01-01

    The concept of an advanced-technology (viz., 1985 technology) nuclear-electrolytic water electrolysis facility was assessed for hydrogen production cost and efficiency expectations. The facility integrates (1) a high-temperature gas-cooled nuclear reactor (HTGR) operating a binary work cycle, (2) direct-current (d-c) electricity generation via acyclic generators, and (3) high-current-density, high-pressure electrolyzers using a solid polymer electrolyte (SPE). All subsystems are close-coupled and optimally interfaced for hydrogen production alone (i.e., without separate production of electrical power). Pipeline-pressure hydrogen and oxygen are produced at 6900 kPa (1000 psi). We found that this advanced facility would produce hydrogen at costs that were approximately half those associated with contemporary-technology nuclear electrolysis: $5.36 versus $10.86/million Btu, respectively. The nuclear-heat-to-hydrogen-energy conversion efficiency for the advanced system was estimated as 43%, versus 25% for the contemporary system.

  18. Morphing ab initio potential energy curve of beryllium monohydride

    Science.gov (United States)

    Špirko, Vladimír

    2016-12-01

    Effective (mass-dependent) potential energy curves of the ground electronic states of 9BeH, 9BeD, and 9BeT are constructed by morphing a very accurate MR-ACPF ab initio potential of Koput (2011) within the framework of the reduced potential energy curve approach of Jenč (1983). The morphing is performed by fitting the RPC parameters to available experimental ro-vibrational data. The resulting potential energy curves provide a fairly quantitative reproduction of the fitted data. This allows for a reliable prediction of the so-far unobserved molecular states in terms of only a small number of fitting parameters.

  19. Standard hydrogen electrode and potential of zero charge in density functional calculations

    DEFF Research Database (Denmark)

    Tripkovic, Vladimir; Björketun, Mårten; Skúlason, Egill

    2011-01-01

    Methods to explicitly account for half-cell electrode potentials have recently appeared within the framework of density functional theory. The potential of the electrode relative to the standard hydrogen electrode is typically determined by subtracting the experimental value of the absolute......) the calculated work function strongly depends on the structure of the water film covering the metal surface. In this paper, we first identify the most accurate experimental reference for the ASHEP by revisiting up-to-date literature, and validate the choice of electron reference level in single-electrode density...

  20. Final Technical Report: Hawaii Hydrogen Center for Development and Deployment of Distributed Energy Systems

    Energy Technology Data Exchange (ETDEWEB)

    Rocheleau, Richard E.

    2008-09-30

    Hydrogen power park experiments in Hawai‘i produced real-world data on the performance of commercialized electrochemical components and power systems integrating renewable and hydrogen technologies. By analyzing the different losses associated with the various equipment items involved, this work identifies the different improvements necessary to increase the viability of these technologies for commercial deployment. The stand-alone power system installed at Kahua Ranch on the Big Island of Hawaii required the development of the necessary tools to connect, manage and monitor such a system. It also helped the electrolyzer supplier to adapt its unit to the stand-alone power system application. Hydrogen fuel purity assessments conducted at the Hawai‘i Natural Energy Institute (HNEI) fuel cell test facility yielded additional knowledge regarding fuel cell performance degradation due to exposure to several different fuel contaminants. In addition, a novel fitting strategy was developed to permit accurate separation of the degradation of fuel cell performance due to fuel impurities from other losses. A specific standard MEA and a standard flow field were selected for use in future small-scale fuel cell experiments. Renewable hydrogen production research was conducted using photoelectrochemical (PEC) devices, hydrogen production from biomass, and biohydrogen analysis. PEC device activities explored novel configurations of ‘traditional’ photovoltaic materials for application in high-efficiency photoelectrolysis for solar hydrogen production. The model systems investigated involved combinations of copper-indium-gallium-diselenide (CIGS) and hydrogenated amorphous silicon (a-Si:H). A key result of this work was the establishment of a robust “three-stage” fabrication process at HNEI for high-efficiency CIGS thin film solar cells. The other key accomplishment was the development of models, designs and prototypes of novel ‘four-terminal’ devices integrating high