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Sample records for hydrodynamic chromatography electronic

  1. Size fractionation by slalom chromatography and hydrodynamic chromatography

    OpenAIRE

    Dias, Ricardo P.

    2008-01-01

    Hydrodynamic chromatography, also called separation by flow, is based on the use of the parabolic flow profile occurring in open capillaries or in the pores from a column filled with non-porous particles. The hydrodynamic chromatography separation medium, if any, is much simpler than that from size exclusion chromatography (porous particles), the former technique being used in the size-fractionation of many colloids and macromolecules. The transition between hydrodynamic chromatography (obtai...

  2. On-chip separation and sensing systems for hydrodynamic chromatography

    NARCIS (Netherlands)

    Blom, M.T.

    2002-01-01

    The feasibility of on-chip analytical separations using planar hydrodynamic chromatography (HDC) in Pyrex-silicon and fused silica chips has been demonstrated. In order to sketch the analytical separations area in which the HDC chip has to operate, an introduction was given of important macro-scale

  3. Hydrodynamic Electron Flow and Hall Viscosity

    Science.gov (United States)

    Scaffidi, Thomas; Nandi, Nabhanila; Schmidt, Burkhard; Mackenzie, Andrew P.; Moore, Joel E.

    2017-06-01

    In metallic samples of small enough size and sufficiently strong momentum-conserving scattering, the viscosity of the electron gas can become the dominant process governing transport. In this regime, momentum is a long-lived quantity whose evolution is described by an emergent hydrodynamical theory. Furthermore, breaking time-reversal symmetry leads to the appearance of an odd component to the viscosity called the Hall viscosity, which has attracted considerable attention recently due to its quantized nature in gapped systems but still eludes experimental confirmation. Based on microscopic calculations, we discuss how to measure the effects of both the even and odd components of the viscosity using hydrodynamic electronic transport in mesoscopic samples under applied magnetic fields.

  4. On-Chip Hydrodynamic Chromatography Separation and Detection of Nanoparticles and Biomolecules

    NARCIS (Netherlands)

    Blom, M.T.; Chmela, Emil; Oosterbroek, R.E.; Tijssen, Robert; van den Berg, Albert

    2003-01-01

    For the first time, on-chip planar hydrodynamic chromatography is combined with UV absorption detection. This technique is suitable for size characterization of synthetic polymers, biopolymers, and particles. Possible advantages of an on-chip hydrodynamic chromatography system over conventional

  5. A chip sustem for size separation of macromolecules and particles by hydrodynamic chromatography

    NARCIS (Netherlands)

    Chmela, Emil; Tijssen, Robert; Blom, M.T.; Gardeniers, Johannes G.E.; van den Berg, Albert

    2002-01-01

    For the first time, a miniaturized hydrodynamic chromatography chip system has been developed and tested on separation of fluorescent nanospheres and macromolecules. The device can be applied to size characterization of synthetic polymers, biopolymers, and particles, as an attractive alternative to

  6. Transport in nanoscale systems: hydrodynamics, turbulence, and local electron heating

    Science.gov (United States)

    di Ventra, Massimiliano

    2007-03-01

    Transport in nanoscale systems is usually described as an open-boundary scattering problem. This picture, however, says nothing about the dynamical onset of steady states, their microscopic nature, or their dependence on initial conditions [1]. In order to address these issues, I will first describe the dynamical many-particle state via an effective quantum hydrodynamic theory [2]. This approach allows us to predict a series of novel phenomena like turbulence of the electron liquid [2], local electron heating in nanostructures [3], and the effect of electron viscosity on resistance [4]. I will provide both analytical results and numerical examples of first-principles electron dynamics in nanostructures using the above approach. I will also discuss possible experimental tests of our predictions. Work supported in part by NSF and DOE. [1] N. Bushong, N. Sai and M. Di Ventra, ``Approach to steady-state transport in nanoscale systems'' Nano Letters, 5 2569 (2005); M. Di Ventra and T.N. Todorov, ``Transport in nanoscale systems: the microcanonical versus grand-canonical picture,'' J. Phys. Cond. Matt. 16, 8025 (2004). [2] R. D'Agosta and M. Di Ventra, ``Hydrodynamic approach to transport and turbulence in nanoscale conductors,'' cond-mat/05123326; J. Phys. Cond. Matt., in press. [3] R. D'Agosta, N. Sai and M. Di Ventra, ``Local electron heating in nanoscale conductors,'' cond-mat/0605312; Nano Letters, in press. [4] N. Sai, M. Zwolak, G. Vignale and M. Di Ventra, ``Dynamical corrections to the DFT-LDA electron conductance in nanoscale systems,'' Phys. Rev. Lett. 94, 186810 (2005).

  7. Hydrodynamic chromatography and field flow fractionation in finite aspect ratio channels.

    Science.gov (United States)

    Shendruk, T N; Slater, G W

    2014-04-25

    Hydrodynamic chromatography (HC) and field-flow fractionation (FFF) separation methods are often performed in 3D rectangular channels, though ideal retention theory assumes 2D systems. Devices are commonly designed with large aspect ratios; however, it can be unavoidable or desirable to design rectangular channels with small or even near-unity aspect ratios. To assess the significance of finite-aspect ratio effects and interpret experimental retention results, an ideal, analytical retention theory is needed. We derive a series solution for the ideal retention ratio of HC and FFF rectangular channels. Rather than limiting devices' ability to resolve samples, our theory predicts that retention curves for normal-mode FFF are well approximated by the infinite plate solution and that the performance of HC is actually improved. These findings suggest that FFF devices need not be designed with large aspect ratios and that rectangular HC channels are optimal when the aspect ratio is unity.

  8. Hydrodynamic injection on electrophoresis microchips using an electronic micropipette.

    Science.gov (United States)

    Gabriel, Ellen F M; Dos Santos, Rodrigo A; Lobo-Júnior, Eulício O; Rezende, Kariolanda C A; Coltro, Wendell K T

    2017-01-01

    Here we report for the first time the use of an electronic micropipette as hydrodynamic (HD) injector for microchip electrophoresis (ME) devices. The micropipette was directly coupled to a PDMS device, which had been fabricated in a simple cross format with two auxiliary channels for sample volume splitting. Sample flow during the injection procedure was controlled in automatic dispenser mode using a volume of 0.6µL. Channel width and device configuration were optimized and the best results were achieved using a simple cross layout containing two auxiliary channels with 300µm width for sample splitting. The performance of the HD injector was evaluated using a model mixture of high-mobility cationic species. The results obtained were compared to the data obtained via electrokinetic (EK) injection. Overall, the HD provided better analytical performance in terms of resolution and injection-to-injection repeatability. The relative standard deviation (RSD) values for peak intensities were lower than 5% (n=10) when the micropipette was employed. In comparison with EK injection, the use of the proposed HD injector revealed an unbiased profile for a mixture containing K(+) and Li(+)(300 µmol L(-1) each) over various buffer concentrations. For EK injection, the peak areas decreased from 2.92 ± 0.20-0.72 ± 0.14Vs for K(+) and from 1.30 ± 0.10-0.38 ± 0.10Vs for Li(+) when the running buffer increased from 20 to 50mmolL(-1). For HD injection, the peak areas for K(+) and Li(+) exhibited average values of 2.48±0.07 and 2.10±0.06Vs, respectively. The limits of detection (LDs) for K(+), Na(+) and Li(+) ranged from 18 to 23µmolL(-1). HD injection through an electronic micropipette allows to automatically dispense a bias-free amount of sample inside microchannels with acceptable repeatability. The proposed approach also exhibited instrumental simplicity, portability and minimal microfabrication requirements.

  9. Hydrodynamic theory for quantum plasmonics: Linear-response dynamics of the inhomogeneous electron gas

    DEFF Research Database (Denmark)

    Yan, Wei

    2015-01-01

    We investigate the hydrodynamic theory of metals, offering systematic studies of the linear-response dynamics for an inhomogeneous electron gas. We include the quantum functional terms of the Thomas-Fermi kinetic energy, the von Weizsa¨cker kinetic energy, and the exchange-correlation Coulomb...... response of complex metallic nanostructures, including quantum effects, by adjusting theory parameters appropriately....... energies under the local density approximation. The advantages, limitations, and possible improvements of the hydrodynamic theory are transparently demonstrated. The roles of various parameters in the theory are identified. We anticipate that the hydrodynamic theory can be applied to investigate the linear...

  10. Optical Electronic Bragg Reflection Sensor System with Hydrodynamic Flow Applications

    Science.gov (United States)

    Lyons, D. R.

    2003-01-01

    This project, as described in the following report, involved design and fabrication of fiber optic sensors for the detection and measurement of dynamic fluid density variations. These devices are created using UV (ultraviolet) ablation and generally modified transverse holographic fiber grating techniques. The resulting phase gratings created on or immediately underneath the flat portion of D-shaped optical waveguides are characterized as evanescent field sensing devices. The primary applications include the sensor portion of a real-time localized or distributed measurement system for hydrodynamic flow, fluid density measurements, and phase change phenomena. Several design modifications were implemented in an attempt to accomplish the tasks specified in our original proposal. In addition, we have established key collaborative relationships with numerous people and institutions.

  11. Electronic circuitry used to automate paper chromatography

    Science.gov (United States)

    Steffensen, G. R.

    1967-01-01

    Electronic circuit is used in a paper chromatograph instrument that has excellent sensitivity and furnishes a printed record of each test. The circuit measures and records changes in conductivity in a strip of chromatographic paper as different solutions are placed on it.

  12. Do electron-capture supernovae make neutron stars? First multidimensional hydrodynamic simulations of the oxygen deflagration

    CERN Document Server

    Jones, Samuel; Pakmor, Ruediger; Seitenzahl, Ivo R; Ohlmann, Sebastian T; Edelmann, Philipp V F

    2016-01-01

    In the classical picture, electron-capture supernovae and the accretion-induced collapse of oxygen-neon white dwarfs undergo an oxygen deflagration phase before gravitational collapse produces a neutron star. Such core collapse events are postulated to explain several astronomical phenomena. In this work, the oxygen deflagration phase is simulated for the first time using multidimensional hydrodynamics. By simulating the oxygen deflagration with multidimensional hydrodynamics and a level-set based flame approach, new insights can be gained into the explosive deaths of 8--10 solar-mass stars and oxygen-neon white dwarfs accreting material from a binary companion star. The main aim is to determine whether these events are thermonuclear or core-collapse supernova explosions, and hence whether neutron stars are formed by such phenomena. The oxygen deflagration is simulated in oxygen-neon cores with three different central ignition densities. The intermediate density case is perhaps the most realistic based on rec...

  13. Hydrodynamic theory of partially degenerate electron-hole fluids in semiconductors

    Science.gov (United States)

    Akbari-Moghanjoughi, M.; Eliasson, B.

    2016-10-01

    A quantum hydrodynamic theory for high-frequency electron-hole Langmuir and acoustic-like oscillations as well as static charge shielding effects in arbitrarily doped semiconductors is presented. The model includes kinetic corrections to the quantum statistical pressure and to the quantum Bohm potential for partially degenerate electrons and holes at finite temperatures. The holes contribute to the oscillations and screening effects in semiconductors in a similar manner as real particles. The dielectric functions are derived in the high-frequency limit for wave excitations and in the low-frequency limit for the study of static screening. The dispersion relation for the Langmuir and acoustic-like oscillations is examined for different parameters of doped silicon (Si). Some interesting properties and differences of electron hole dynamical behavior in N- and P-type Si are pointed out. Holes are also observed to enhance an attractive charge shielding effect when the semiconductor is highly acceptor-doped.

  14. Chromatography.

    Science.gov (United States)

    Brantley, L. Reed, Sr.; Demanche, Edna L.; Klemm, E. Barbara; Kyselka, Will; Phillips, Edwin A.; Pottenger, Francis M.; Yamamoto, Karen N.; Young, Donald B.

    This booklet presents some activities on chromatography. Directions for preparing leaf pigment extracts using alcohol are given, and paper chromatography and thin-layer chromatography are described as modifications of the basic principles of chromatography. (KHR)

  15. Chromatography.

    Science.gov (United States)

    Brantley, L. Reed, Sr.; Demanche, Edna L.; Klemm, E. Barbara; Kyselka, Will; Phillips, Edwin A.; Pottenger, Francis M.; Yamamoto, Karen N.; Young, Donald B.

    This booklet presents some activities on chromatography. Directions for preparing leaf pigment extracts using alcohol are given, and paper chromatography and thin-layer chromatography are described as modifications of the basic principles of chromatography. (KHR)

  16. Fast-ignition design transport studies: realistic electron source, integrated PIC-hydrodynamics, imposed magnetic fields

    CERN Document Server

    Strozzi, D J; Larson, D J; Divol, L; Kemp, A J; Bellei, C; Marinak, M M; Key, M H

    2012-01-01

    Transport modeling of idealized, cone-guided fast ignition targets indicates the severe challenge posed by fast-electron source divergence. The hybrid particle-in-cell [PIC] code Zuma is run in tandem with the radiation-hydrodynamics code Hydra to model fast-electron propagation, fuel heating, and thermonuclear burn. The fast electron source is based on a 3D explicit-PIC laser-plasma simulation with the PSC code. This shows a quasi two-temperature energy spectrum, and a divergent angle spectrum (average velocity-space polar angle of 52 degrees). Transport simulations with the PIC-based divergence do not ignite for > 1 MJ of fast-electron energy, for a modest 70 micron standoff distance from fast-electron injection to the dense fuel. However, artificially collimating the source gives an ignition energy of 132 kJ. To mitigate the divergence, we consider imposed axial magnetic fields. Uniform fields ~50 MG are sufficient to recover the artificially collimated ignition energy. Experiments at the Omega laser facil...

  17. Rapid Embedded Wire Heating via Resistive Guiding of Laser-Generated Fast Electrons as a Hydrodynamic Driver

    CERN Document Server

    Robinson, A P L; Pasley, J

    2014-01-01

    Resistively guiding laser-generated fast electron beams in targets consisting of a resistive wire embedded in lower $Z$ material should allow one to rapidly heat the wire to over 100eV over a substantial distance without strongly heating the surrounding material. On the multi-ps timescale this can drive hydrodynamic motion in the surrounding material. Thus ultra-intense laser solid interactions have the potential as a controlled driver of radiation hydrodynamics in solid density material. In this paper we assess the laser and target parameters needed to achieve such rapid and controlled heating of the embedded wire.

  18. Vlasov-Fokker-Planck simulations of fast-electron transport with hydrodynamic plasma response

    Energy Technology Data Exchange (ETDEWEB)

    Kingham, R J; Sherlock, M; Ridgers, C P; Evans, R G, E-mail: rj.kingham@imperial.ac.u [Plasma Physics Group, Imperial College London, London SW7 2AZ (United Kingdom)

    2010-08-01

    We report on kinetic simulations of the transport of laser-produced relativistic electron beams (REB) through solid-density plasma, including the hydrodynamic response of the plasma. We consider REBs with parameters relevant to fast-ignition of compressed inertial confinement fusion capsules. We show that over the 10-20ps timescales required for fast-ignition, thermal pressure (from Ohmic heating) can significantly modify the density which in turn strongly affects the propagation of injected fast-electrons; it allows them to re-collimate into a narrow, intense beam under conditions where they initially undergo beam-hollowing. Similar static-density calculations do not show re-collimation. The re-collimation effect is attributed to PdV cooling in the pressure-induced density-channel, which in turn suppresses defocusing magnetic fields generated by resistivity gradients. These simulations have been carried out using the new 2D-3V Vlasov-Fokker-Planck (VFP) code FIDO running in hybrid mode.

  19. Improved non-local electron thermal transport model for two-dimensional radiation hydrodynamics simulations

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Duc; Moses, Gregory [University of Wisconsin—Madison, 1500 Engineering Drive, Madison, Wisconsin 53706 (United States); Delettrez, Jacques [Laboratory for Laser Energetics of the University of Rochester, 250 East River Road, Rochester, New York 14623 (United States)

    2015-08-15

    An implicit, non-local thermal conduction algorithm based on the algorithm developed by Schurtz, Nicolai, and Busquet (SNB) [Schurtz et al., Phys. Plasmas 7, 4238 (2000)] for non-local electron transport is presented and has been implemented in the radiation-hydrodynamics code DRACO. To study the model's effect on DRACO's predictive capability, simulations of shot 60 303 from OMEGA are completed using the iSNB model, and the computed shock speed vs. time is compared to experiment. Temperature outputs from the iSNB model are compared with the non-local transport model of Goncharov et al. [Phys. Plasmas 13, 012702 (2006)]. Effects on adiabat are also examined in a polar drive surrogate simulation. Results show that the iSNB model is not only capable of flux-limitation but also preheat prediction while remaining numerically robust and sacrificing little computational speed. Additionally, the results provide strong incentive to further modify key parameters within the SNB theory, namely, the newly introduced non-local mean free path. This research was supported by the Laboratory for Laser Energetics of the University of Rochester.

  20. Two-valley Hydrodynamical Models for Electron Transport in Gallium Arsenide: Simulation of Gunn Oscillations

    Directory of Open Access Journals (Sweden)

    A. Marcello Anile

    2002-01-01

    Full Text Available To accurately describe non-stationary carrier transport in GaAs devices, it is necessary to use Monte Carlo methods or hydrodynamical (or energy transport models which incorporate population transfer between valleys.We present here simulations of Gunn oscillations in a GaAs diode based on two-valley hydrodynamical models: the classic Bløtekjær model and two recently developed moment expansion models. Scattering parameters within the models are obtained from homogeneous Monte Carlo simulations, and these are compared against expressions in the literature. Comparisons are made between our hydrodynamical results, existing work, and direct Monte Carlo simulations of the oscillator device.

  1. Combined effects of laser and non-thermal electron beams on hydrodynamics and shock formation in the Shock Ignition scheme

    Science.gov (United States)

    Nicolai, Ph.; Feugeas, J. L.; Touati, M.; Breil, J.; Dubroca, B.; Nguyen-Buy, T.; Ribeyre, X.; Tikhonchuk, V.; Gus'kov, S.

    2014-10-01

    An issue to be addressed in Inertial Confinement Fusion (ICF) is the detailed description of the kinetic transport of relativistic or non-thermal electrons generated by laser within the time and space scales of the imploded target hydrodynamics. We have developed at CELIA the model M1, a fast and reduced kinetic model for relativistic electron transport. The latter has been implemented into the 2D radiation hydrodynamic code CHIC. In the framework of the Shock Ignition (SI) scheme, it has been shown in simplified conditions that the energy transferred by the non-thermal electrons from the corona to the compressed shell of an ICF target could be an important mechanism for the creation of ablation pressure. Nevertheless, in realistic configurations, taking the density profile and the electron energy spectrum into account, the target has to be carefully designed to avoid deleterious effects on compression efficiency. In addition, the electron energy deposition may modify the laser-driven shock formation and its propagation through the target. The non-thermal electron effects on the shock propagation will be analyzed in a realistic configuration.

  2. Heavy flavor electron $R_\\text{AA}$ and $v_2$ in event-by-event relativistic hydrodynamics

    CERN Document Server

    Prado, Caio A G; Munhoz, Marcelo G; Noronha, Jorge; Suaide, Alexandre A P

    2016-01-01

    In this work we investigate how event-by-event hydrodynamics fluctuations affect the nuclear suppression factor and elliptic flow of heavy flavor mesons and non-photonic electrons. We use a 2D+1 Lagrangian ideal hydrodynamic code on an event-by-event basis in order to compute local temperature and flow profiles. Using a strong coupling inspired energy loss parametrization on top of the evolving space-time energy density distributions we are able to propagate the heavy quarks inside the medium until the freeze-out temperature is reached and a Pythia modeling of hadronization takes place. The resulting D$^0$ and heavy-flavor electron yield is compared with recent experimental data for $R_\\text{AA}$ and $v_2$ from the STAR and Phenix collaborations. In addition we present preditions for the higher order Fourier harmonic coefficients $v_3(p_T)$ of heavy-flavor electrons at RHIC's $\\sqrt{S_\\text{NN}} = 200$ GeV collisions.

  3. Radiation Hydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Castor, J I

    2003-10-16

    The discipline of radiation hydrodynamics is the branch of hydrodynamics in which the moving fluid absorbs and emits electromagnetic radiation, and in so doing modifies its dynamical behavior. That is, the net gain or loss of energy by parcels of the fluid material through absorption or emission of radiation are sufficient to change the pressure of the material, and therefore change its motion; alternatively, the net momentum exchange between radiation and matter may alter the motion of the matter directly. Ignoring the radiation contributions to energy and momentum will give a wrong prediction of the hydrodynamic motion when the correct description is radiation hydrodynamics. Of course, there are circumstances when a large quantity of radiation is present, yet can be ignored without causing the model to be in error. This happens when radiation from an exterior source streams through the problem, but the latter is so transparent that the energy and momentum coupling is negligible. Everything we say about radiation hydrodynamics applies equally well to neutrinos and photons (apart from the Einstein relations, specific to bosons), but in almost every area of astrophysics neutrino hydrodynamics is ignored, simply because the systems are exceedingly transparent to neutrinos, even though the energy flux in neutrinos may be substantial. Another place where we can do ''radiation hydrodynamics'' without using any sophisticated theory is deep within stars or other bodies, where the material is so opaque to the radiation that the mean free path of photons is entirely negligible compared with the size of the system, the distance over which any fluid quantity varies, and so on. In this case we can suppose that the radiation is in equilibrium with the matter locally, and its energy, pressure and momentum can be lumped in with those of the rest of the fluid. That is, it is no more necessary to distinguish photons from atoms, nuclei and electrons, than it is

  4. Evaluation of hydrodynamic chromatography coupled with UV-visible, fluorescence and inductively coupled plasma mass spectrometry detectors for sizing and quantifying colloids in environmental media.

    Science.gov (United States)

    Philippe, Allan; Schaumann, Gabriele E

    2014-01-01

    In this study, we evaluated hydrodynamic chromatography (HDC) coupled with inductively coupled plasma mass spectrometry (ICP-MS) for the analysis of nanoparticles in environmental samples. Using two commercially available columns (Polymer Labs-PDSA type 1 and 2), a set of well characterised calibrants and a new external time marking method, we showed that flow rate and eluent composition have few influence on the size resolution and, therefore, can be adapted to the sample particularity. Monitoring the agglomeration of polystyrene nanoparticles over time succeeded without observable disagglomeration suggesting that even weak agglomerates can be measured using HDC. Simultaneous determination of gold colloid concentration and size using ICP-MS detection was validated for elemental concentrations in the ppb range. HDC-ICP-MS was successfully applied to samples containing a high organic and ionic background. Indeed, online combination of UV-visible, fluorescence and ICP-MS detectors allowed distinguishing between organic molecules and inorganic colloids during the analysis of Ag nanoparticles in synthetic surface waters and TiO₂ and ZnO nanoparticles in commercial sunscreens. Taken together, our results demonstrate that HDC-ICP-MS is a flexible, sensitive and reliable method to measure the size and the concentration of inorganic colloids in complex media and suggest that there may be a promising future for the application of HDC in environmental science. Nonetheless the rigorous measurements of agglomerates and of matrices containing natural colloids still need to be studied in detail.

  5. Dual cloud point extraction coupled with hydrodynamic-electrokinetic two-step injection followed by micellar electrokinetic chromatography for simultaneous determination of trace phenolic estrogens in water samples.

    Science.gov (United States)

    Wen, Yingying; Li, Jinhua; Liu, Junshen; Lu, Wenhui; Ma, Jiping; Chen, Lingxin

    2013-07-01

    A dual cloud point extraction (dCPE) off-line enrichment procedure coupled with a hydrodynamic-electrokinetic two-step injection online enrichment technique was successfully developed for simultaneous preconcentration of trace phenolic estrogens (hexestrol, dienestrol, and diethylstilbestrol) in water samples followed by micellar electrokinetic chromatography (MEKC) analysis. Several parameters affecting the extraction and online injection conditions were optimized. Under optimal dCPE-two-step injection-MEKC conditions, detection limits of 7.9-8.9 ng/mL and good linearity in the range from 0.05 to 5 μg/mL with correlation coefficients R(2) ≥ 0.9990 were achieved. Satisfactory recoveries ranging from 83 to 108% were obtained with lake and tap water spiked at 0.1 and 0.5 μg/mL, respectively, with relative standard deviations (n = 6) of 1.3-3.1%. This method was demonstrated to be convenient, rapid, cost-effective, and environmentally benign, and could be used as an alternative to existing methods for analyzing trace residues of phenolic estrogens in water samples.

  6. Evaluation of hydrodynamic chromatography coupled with UV-visible, fluorescence and inductively coupled plasma mass spectrometry detectors for sizing and quantifying colloids in environmental media.

    Directory of Open Access Journals (Sweden)

    Allan Philippe

    Full Text Available In this study, we evaluated hydrodynamic chromatography (HDC coupled with inductively coupled plasma mass spectrometry (ICP-MS for the analysis of nanoparticles in environmental samples. Using two commercially available columns (Polymer Labs-PDSA type 1 and 2, a set of well characterised calibrants and a new external time marking method, we showed that flow rate and eluent composition have few influence on the size resolution and, therefore, can be adapted to the sample particularity. Monitoring the agglomeration of polystyrene nanoparticles over time succeeded without observable disagglomeration suggesting that even weak agglomerates can be measured using HDC. Simultaneous determination of gold colloid concentration and size using ICP-MS detection was validated for elemental concentrations in the ppb range. HDC-ICP-MS was successfully applied to samples containing a high organic and ionic background. Indeed, online combination of UV-visible, fluorescence and ICP-MS detectors allowed distinguishing between organic molecules and inorganic colloids during the analysis of Ag nanoparticles in synthetic surface waters and TiO₂ and ZnO nanoparticles in commercial sunscreens. Taken together, our results demonstrate that HDC-ICP-MS is a flexible, sensitive and reliable method to measure the size and the concentration of inorganic colloids in complex media and suggest that there may be a promising future for the application of HDC in environmental science. Nonetheless the rigorous measurements of agglomerates and of matrices containing natural colloids still need to be studied in detail.

  7. On the vanishing electron-mass limit in plasma hydrodynamics in unbounded media

    CERN Document Server

    Donatelli, Donatella; Novotny, Antonin

    2011-01-01

    We consider the zero-electron-mass limit for the Navier-Stokes-Poisson system in unbounded spatial domains. Assuming smallness of the viscosity coefficient and ill-prepared initial data, we show that the asymptotic limit is represented by the incompressible Navier-Stokes system, with a Brinkman damping, in the case when viscosity is proportional to the electron-mass, and by the incompressible Euler system provided the viscosity is dominated by the electron mass. The proof is based on the RAGE theorem and dispersive estimates for acoustic waves, and on the concept of suitable weak solutions for the compressible Navier-Stokes system.

  8. Hydrodynamic and kinetic models for spin-1/2 electron-positron quantum plasmas: Annihilation interaction, helicity conservation, and wave dispersion in magnetized plasmas

    CERN Document Server

    Andreev, Pavel A

    2014-01-01

    We discuss complete theory of spin-1/2 electron-positron quantum plasmas, when electrons and positrons move with velocities mach smaller than the speed of light. We derive a set of two fluid quantum hydrodynamic equations consisting of the continuity, Euler, spin (magnetic moment) evolution equations for each species. We explicitly include the Coulomb, spin-spin, Darwin and annihilation interactions. The annihilation interaction is the main topic of the paper. We consider contribution of the annihilation interaction in the quantum hydrodynamic equations and in spectrum of waves in magnetized electron-positron plasmas. We consider propagation of waves parallel and perpendicular to an external magnetic field. We also consider oblique propagation of longitudinal waves. We derive set of quantum kinetic equations for electron-positron plasmas with the Darwin and annihilation interactions. We apply the kinetic theory for the linear wave behavior in absence of external fields. We calculate contribution of the Darwin...

  9. Hydrodynamic equations for electrons in graphene obtained from the maximum entropy principle

    Energy Technology Data Exchange (ETDEWEB)

    Barletti, Luigi, E-mail: luigi.barletti@unifi.it [Dipartimento di Matematica e Informatica “Ulisse Dini”, Università degli Studi di Firenze, Viale Morgagni 67/A, 50134 Firenze (Italy)

    2014-08-15

    The maximum entropy principle is applied to the formal derivation of isothermal, Euler-like equations for semiclassical fermions (electrons and holes) in graphene. After proving general mathematical properties of the equations so obtained, their asymptotic form corresponding to significant physical regimes is investigated. In particular, the diffusive regime, the Maxwell-Boltzmann regime (high temperature), the collimation regime and the degenerate gas limit (vanishing temperature) are considered.

  10. Drying techniques for the visualisation of agarose-based chromatography media by scanning electron microscopy.

    Science.gov (United States)

    Nweke, Mauryn C; Turmaine, Mark; McCartney, R Graham; Bracewell, Daniel G

    2017-03-01

    The drying of chromatography resins prior to scanning electron microscopy is critical to image resolution and hence understanding of the bead structure at sub-micron level. Achieving suitable drying conditions is especially important with agarose-based chromatography resins, as over-drying may cause artefact formation, bead damage and alterations to ultrastructural properties; and under-drying does not provide sufficient resolution for visualization under SEM. This paper compares and contrasts the effects of two drying techniques, critical point drying and freeze drying, on the morphology of two agarose based resins (MabSelect™/dw ≈85 µm and Capto™ Adhere/dw ≈75 µm) and provides a complete method for both. The results show that critical point drying provides better drying and subsequently clearer ultrastructural visualization of both resins under SEM. Under this protocol both the polymer fibers (thickness ≈20 nm) and the pore sizes (diameter ≈100 nm) are clearly visible. Freeze drying is shown to cause bead damage to both resins, but to different extents. MabSelect resin encounters extensive bead fragmentation, whilst Capto Adhere resin undergoes partial bead disintegration, corresponding with the greater extent of agarose crosslinking and strength of this resin. While freeze drying appears to be the less favorable option for ultrastructural visualization of chromatography resin, it should be noted that the extent of fracturing caused by the freeze drying process may provide some insight into the mechanical properties of agarose-based chromatography media.

  11. Identification and measurement of chlorinated organic pesticides in water by electron-capture gas chromatography

    Science.gov (United States)

    Lamar, William L.; Goerlitz, Donald F.; Law, LeRoy M.

    1965-01-01

    Pesticides, in minute quantities, may affect the regimen of streams, and because they may concentrate in sediments, aquatic organisms, and edible aquatic foods, their detection and their measurement in the parts-per-trillion range are considered essential. In 1964 the U.S. Geological Survey at Menlo Park, Calif., began research on methods for monitoring pesticides in water. Two systems were selected--electron-capture gas chromatography and microcoulometric-titration gas chromatography. Studies on these systems are now in progress. This report provides current information on the development and application of an electron-capture gas chromatographic procedure. This method is a convenient and extremely sensitive procedure for the detection and measurement of organic pesticides having high electron affinities, notably the chlorinated organic pesticides. The electron-affinity detector is extremely sensitive to these substances but it is not as sensitive to many other compounds. By this method, the chlorinated organic pesticide may be determined on a sample of convenient size in concentrations as low as the parts-per-trillion range. To insure greater accuracy in the identifications, the pesticides reported were separated and identified by their retention times on two different types of gas chromatographic columns.

  12. Determination of phenoxy acid herbicides in water by electron-capture and microcoulometric gas chromatography

    Science.gov (United States)

    Goerlitz, D.F.; Lamar, William L.

    1967-01-01

    A sensitive gas chromatographic method using microcoulometric titration and electron-capture detection for the analysis of 2,4-D, silvex, 2,4,5-T, and other phenoxy acid herbicides in water is described. The herbicides are extracted from unfiltered water samples (800-1,000 ml) by use of ethyl ether ; then the herbicides are concentrated and esterilied. To allow the analyst a choice, two esterilication procedures--using either boron trifluoride-methanol or diazomethane--are evaluated. Microcoulometric gas chromatography is specific for the detection of halogenated compounds such as the phenoxy acid herbicides whereas it does not respond to nonhalogenated components. Microcoulometric gas chromatography requires care and patience. It is not convenient for rapid screening of l-liter samples that contain less than 1 microgram of the herbicide. Although electroncapture gas chromatography is less selective and more critically affected by interfering substances, it is, nevertheless, convenient and more sensitive than microcoulometric gas chromatography. Two different liquid phases are used in the gas chromatographic columns--DC-200 silicone in one column and QF-1 silicone in the other. The performance of both columns is improved by the addition of Carbowax 20M. The Gas Chrom Q support is coated with the liquid phases by the 'frontal-analysis' technique. The practical lower limits for measurement of the phenoxy acid herbicides in water primarily depend upon the sample size, interferences present, anal instrumentation used. With l-liter samples of water, the practical lower limits of measurement are 10 ppt (parts per trillion) for 2,4-D and 2 ppt for silvex and 2,4,5-T when electron-capture detection is used, and approximately 20 ppt for each herbicide when analyzed by microcoulometric-titration gas chromatography. Recoveries of the herbicides immediately after addition to unfiltered water samples averaged 92 percent for 2,4-D, 90 percent for silvex, and 98 percent for 2

  13. Hydrodynamic and kinetic models for spin-1/2 electron-positron quantum plasmas: Annihilation interaction, helicity conservation, and wave dispersion in magnetized plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Andreev, Pavel A., E-mail: andreevpa@physics.msu.ru [Faculty of Physics, Lomonosov Moscow State University, Moscow (Russian Federation)

    2015-06-15

    We discuss the complete theory of spin-1/2 electron-positron quantum plasmas, when electrons and positrons move with velocities mach smaller than the speed of light. We derive a set of two fluid quantum hydrodynamic equations consisting of the continuity, Euler, spin (magnetic moment) evolution equations for each species. We explicitly include the Coulomb, spin-spin, Darwin and annihilation interactions. The annihilation interaction is the main topic of the paper. We consider the contribution of the annihilation interaction in the quantum hydrodynamic equations and in the spectrum of waves in magnetized electron-positron plasmas. We consider the propagation of waves parallel and perpendicular to an external magnetic field. We also consider the oblique propagation of longitudinal waves. We derive the set of quantum kinetic equations for electron-positron plasmas with the Darwin and annihilation interactions. We apply the kinetic theory to the linear wave behavior in absence of external fields. We calculate the contribution of the Darwin and annihilation interactions in the Landau damping of the Langmuir waves. We should mention that the annihilation interaction does not change number of particles in the system. It does not related to annihilation itself, but it exists as a result of interaction of an electron-positron pair via conversion of the pair into virtual photon. A pair of the non-linear Schrodinger equations for the electron-positron plasmas including the Darwin and annihilation interactions is derived. Existence of the conserving helicity in electron-positron quantum plasmas of spinning particles with the Darwin and annihilation interactions is demonstrated. We show that the annihilation interaction plays an important role in the quantum electron-positron plasmas giving the contribution of the same magnitude as the spin-spin interaction.

  14. Hydrodynamic and kinetic models for spin-1/2 electron-positron quantum plasmas: Annihilation interaction, helicity conservation, and wave dispersion in magnetized plasmas

    Science.gov (United States)

    Andreev, Pavel A.

    2015-06-01

    We discuss the complete theory of spin-1/2 electron-positron quantum plasmas, when electrons and positrons move with velocities mach smaller than the speed of light. We derive a set of two fluid quantum hydrodynamic equations consisting of the continuity, Euler, spin (magnetic moment) evolution equations for each species. We explicitly include the Coulomb, spin-spin, Darwin and annihilation interactions. The annihilation interaction is the main topic of the paper. We consider the contribution of the annihilation interaction in the quantum hydrodynamic equations and in the spectrum of waves in magnetized electron-positron plasmas. We consider the propagation of waves parallel and perpendicular to an external magnetic field. We also consider the oblique propagation of longitudinal waves. We derive the set of quantum kinetic equations for electron-positron plasmas with the Darwin and annihilation interactions. We apply the kinetic theory to the linear wave behavior in absence of external fields. We calculate the contribution of the Darwin and annihilation interactions in the Landau damping of the Langmuir waves. We should mention that the annihilation interaction does not change number of particles in the system. It does not related to annihilation itself, but it exists as a result of interaction of an electron-positron pair via conversion of the pair into virtual photon. A pair of the non-linear Schrodinger equations for the electron-positron plasmas including the Darwin and annihilation interactions is derived. Existence of the conserving helicity in electron-positron quantum plasmas of spinning particles with the Darwin and annihilation interactions is demonstrated. We show that the annihilation interaction plays an important role in the quantum electron-positron plasmas giving the contribution of the same magnitude as the spin-spin interaction.

  15. Determination of toxaphene enantiomers by comprehensive two-dimensional gas chromatography with electron-capture detection.

    Science.gov (United States)

    Bordajandi, Luisa R; Ramos, Lourdes; González, María José

    2006-09-01

    Comprehensive two-dimensional gas chromatography with micro electron-capture detection (GC x GC-microECD) has been evaluated for the enantioseparation of five chiral toxaphenes typically found in real-life samples (Parlar 26, 32, 40, 44 and 50). From the two enantioselective beta-cyclodextrin-based columns evaluated as first dimension column, BGB-176SE and BGB-172, the latter provided the best results and was further combined with three non-enantioselective columns in the second dimension: HT-8, BPX-50 and Supelcowax-10. The combination BGB-172 x BPX-50 was finally selected because it provided a complete separation among all enantiomers. A satisfactory repeatability and reproducibility of the retention times in both the first and the second dimension were observed for all target compounds (RSDs below 0.8%, n = 4). Linear responses in the tested range of 10-200 pg/microl and limits of detection in the range of 2-6 pg/microl were obtained. The repeatability and reproducibility at a concentration of 100 pg/microl, evaluated as the RSDs calculated for the enantiomeric fraction (EF), was better than 11% (n = 4) in all instances. The feasibility of the method developed for real-life analyses was illustrated by the determination of the enantiomeric ratios and concentration levels of the test compounds in four commercial fish oil samples. These results were compared to those obtained by heart-cut multidimensional gas chromatography using the same enantioselective column.

  16. Evaluation of vermicompost maturity using scanning electron microscopy and paper chromatography analysis.

    Science.gov (United States)

    Senthil Kumar, D; Satheesh Kumar, P; Rajendran, N M; Uthaya Kumar, V; Anbuganapathi, G

    2014-04-02

    Vermicompost was produced from flower waste inoculated with biofertilizers using the earthworm Eisenia fetida. Principal component analysis (PCA) and cluster analysis (CA) were carried out on the basis of physicochemical parameters of vermicomposted samples. From the results of the PCA and CA, it was possible to classify two different groups of vermicompost samples in the following categories: E2 and E5; and E1, E3, E4, and control. Scanning electron microscopy and biodynamic circular paper chromatography analysis were used to investigate the changes in surface morphology and functional groups in the control and vermicompost products. SEM analysis of E1-E5 shows more fragment and pores than the control. Chromatographic analysis of vermicompost indicated the mature condition of the compost materials.

  17. Evaluation of gas chromatographyelectron ionization – full scan high resolution Orbitrap mass spectrometry for pesticide residue analysis

    NARCIS (Netherlands)

    Mol, Hans G.J.; Tienstra, Marc; Zomer, Paul

    2016-01-01

    Gas chromatography with electron ionization and full scan high resolution mass spectrometry with an Orbitrap mass analyzer (GC-EI-full scan Orbitrap HRMS) was evaluated for residue analysis. Pesticides in fruit and vegetables were taken as an example application. The relevant aspects for GC-MS

  18. Coupling gas chromatography and electronic nose detection for detailed cigarette smoke aroma characterization.

    Science.gov (United States)

    Rambla-Alegre, Maria; Tienpont, Bart; Mitsui, Kazuhisa; Masugi, Eri; Yoshimura, Yuta; Nagata, Hisanori; David, Frank; Sandra, Pat

    2014-10-24

    Aroma characterization of whole cigarette smoke samples using sensory panels or electronic nose (E-nose) devices is difficult due to the masking effect of major constituents and solvent used for the extraction step. On the other hand, GC in combination with olfactometry detection does not allow to study the delicate balance and synergetic effect of aroma solutes. To overcome these limitations a new instrumental set-up consisting of heart-cutting gas chromatography using a capillary flow technology based Deans switch and low thermal mass GC in combination with an electronic nose device is presented as an alternative to GC-olfactometry. This new hyphenated GC-E-nose configuration is used for the characterization of cigarette smoke aroma. The system allows the transfer, combination or omission of selected GC fractions before injection in the E-nose. Principal component analysis (PCA) and discriminant factor analysis (DFA) allowed clear visualizing of the differences among cigarette brands and classifying them independently of their nicotine content. Omission and perceptual interaction tests could also be carried out using this configuration. The results are promising and suggest that the GC-E-nose hyphenation is a good approach to measure the contribution level of individual compounds to the whole cigarette smoke. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. Relativistic hydrodynamics

    CERN Document Server

    Luciano, Rezzolla

    2013-01-01

    Relativistic hydrodynamics is a very successful theoretical framework to describe the dynamics of matter from scales as small as those of colliding elementary particles, up to the largest scales in the universe. This book provides an up-to-date, lively, and approachable introduction to the mathematical formalism, numerical techniques, and applications of relativistic hydrodynamics. The topic is typically covered either by very formal or by very phenomenological books, but is instead presented here in a form that will be appreciated both by students and researchers in the field. The topics covered in the book are the results of work carried out over the last 40 years, which can be found in rather technical research articles with dissimilar notations and styles. The book is not just a collection of scattered information, but a well-organized description of relativistic hydrodynamics, from the basic principles of statistical kinetic theory, down to the technical aspects of numerical methods devised for the solut...

  20. Theoretical hydrodynamics

    CERN Document Server

    Milne-Thomson, L M

    2011-01-01

    This classic exposition of the mathematical theory of fluid motion is applicable to both hydrodynamics and aerodynamics. Based on vector methods and notation with their natural consequence in two dimensions - the complex variable - it offers more than 600 exercises and nearly 400 diagrams. Prerequisites include a knowledge of elementary calculus. 1968 edition.

  1. Hydrodynamic bearings

    CERN Document Server

    Bonneau, Dominique; Souchet, Dominique

    2014-01-01

    This Series provides the necessary elements to the development and validation of numerical prediction models for hydrodynamic bearings. This book describes the rheological models and the equations of lubrication. It also presents the numerical approaches used to solve the above equations by finite differences, finite volumes and finite elements methods.

  2. Ship Hydrodynamics

    Science.gov (United States)

    Lafrance, Pierre

    1978-01-01

    Explores in a non-mathematical treatment some of the hydrodynamical phenomena and forces that affect the operation of ships, especially at high speeds. Discusses the major components of ship resistance such as the different types of drags and ways to reduce them and how to apply those principles for the hovercraft. (GA)

  3. Rapid determination of acrylamide contaminant in conventional fried foods by gas chromatography with electron capture detector.

    Science.gov (United States)

    Zhang, Yu; Dong, Yi; Ren, Yiping; Zhang, Ying

    2006-05-26

    Gas chromatography coupled with electron capture detector (GC-ECD) was successfully developed and applied for the rapid determination of acrylamide in conventional fried foods, such as potato crisps, potato chips, and fried chicken wings. The method included defatting with n-hexane, extraction with aqueous solution of sodium chloride (NaCl), derivatization with potassium bromate (KBrO3) and potassium bromide (KBr), and liquid-liquid extraction with ethyl acetate. The final acrylamide extract was analyzed by GC-ECD for quantification and by GC-MS for confirmation. The chromatographic analysis was performed on the HP-INNOWax capillary column, and good retention and peak response of acrylamide were achieved under the optimal conditions (numbers of theoretical plates N = 83,815). The limit of detection (LOD) was estimated to be 0.1 microg kg(-1) on the basis of ECD technique. Recoveries of acrylamide from conventional samples spiked at levels of 150, 500 and 1000 microg kg(-1) (n = 4 for each level) ranged between 87 and 97% with relative standard deviations (RSD) of less than 4%. Furthermore, the GC-ECD method showed that no clean-up steps of acrylamide derivative would be performed prior to injection and was slightly more sensitive than the MS/MS-based methods. Validation and quantification results demonstrated that this method should be regarded as a new, low-cost, and robust alternative for conventional investigation of acrylamide.

  4. Determination of guaifenesin in human serum by capillary gas chromatography and electron capture detection.

    Science.gov (United States)

    Sharaf, Maged H M; Stiff, Dwight D

    2004-06-29

    A method for the quantitation of guaifenesin in human serum has been developed and validated. The procedure involves liquid-liquid extraction of the serum sample in the presence of mephenesin as an internal standard, followed by derivatization and analysis using capillary gas chromatography (GC) and electron capture detection (ECD). Different solvents were tested for extraction of guaifenesin from serum. n-Hexane/dichloromethane (1:1, v/v) gave the highest recovery and the lowest background and was chosen as the extraction solvent. After extraction, the residue of guaifenesin was derivatized at 60 degrees C for 30 min, with trifluoroacetic acid anhydride (TFAA) in toluene in the presence of pyridine. Excess trifluoroacetic acid anhydride was removed using dilute solution of ammonium hydroxide. The method proved to be linear over the range of 25.0-1000 ng/ml. Recovery of guaifenesin from spiked samples was consistent, averaging 75.5% at 50.0 ng/ml with a range of 72.0-80.0% (N = 8 determinations) and averaging 78% at 800 ng/ml with a range of 76.0-81.0% (N = 8 determinations). The internal standard recovery was also consistent averaging 72.8% with a range of 67.0-76.0% (N = 16 determinations). Copyright 2004 Elsevier B.V.

  5. Octopamine Levels in Blattella Germanica L. Tissues by Capillary Gas Chromatography with Electron Capture Detection

    Directory of Open Access Journals (Sweden)

    Shuren Jiang

    2005-05-01

    Full Text Available Abstract: Distribution and levels of octopamine (OA, one of the biogenic amines in the invertebrate nervous system, may have significant effects on insect physiological processes including growth, feeding and reproduction. In this paper capillary gas chromatography with electron capture detection (GC-ECD and mass selective detection (GC-MS were used to determine the content of OA in Blattella germanica L. central nervous system (CNS, and that of OA in cockroach stressed by kinds of insecticides, known octopaminergic agonists and some essential oils. A derivatization method for organic extracts via reaction with pentafluoropropionic anhydride (PFPA was developed. The resulting OA derivatives were confirmed by GC-MS to be tris-pentafluoropropionyl-OA. The method was used to quantify the amount of OA in insect issues by capillary GC-ECD through an extraction-derivatization-liquid/liquid partition procedure. Average OA content in normal cockroaches was determined to be 68.49 ± 7.31 ng/g tissue (N=5 determinations. It was shown that insecticides including chlordimeform, methomyl, permethrin, chlorfluazuron, malathion, trichlorfon and some oxazolidine agonists, essential oils including eugenol, cinnamic alcohol, phenyl ethyl alcohol could led to significant increase of OA levels in the cockroach CNS comparing with which in insect treated by 1-butanone. Malathion, trichlorfon, chlorfluazuron and cinnamic alcohol were shown to be able to cause a 20- fold increase in OA levels.

  6. Headspace Analysis of Philippine Civet Coffee Beans Using Gas Chromatography-Mass Spectrometry and Electronic Nose

    Science.gov (United States)

    Ongo, E.; Sevilla, F.; Antonelli, A.; Sberveglieri, G.; Montevecchi, G.; Sberveglieri, V.; de Paola, E. L.; Concina, I.; Falasconi, M.

    2011-11-01

    Civet coffee, the most expensive and best coffee in the world, is an economically important export product of the Philippines. With a growing threat of food adulteration and counterfeiting, a need for quality authentication is essential to protect the integrity and strong market value of Philippine civet coffee. At present, there is no internationally accepted method of verifying whether a bean is an authentic civet coffee. This study presented a practical and promising approach to identify and establish the headspace qualitative profile of Philippine civet coffee using electronic nose (E-nose) and gas chromatography-mass spectrometry (GC-MS). E-nose analysis revealed that aroma characteristic is one of the most important quality indicators of civet coffee. The findings were supported by GC-MS analysis. Principal component analysis (PCA) exhibited a clearly separated civet coffees from their control beans. The chromatographic fingerprints indicated that civet coffees differed with their control beans in terms of composition and concentration of individual volatile constituents.

  7. Determination of fluvalinate residues in beeswax by gas chromatography with electron-capture detection.

    Science.gov (United States)

    Tsigouri, A; Menkissoglu-Spiroudi, U; Thrasyvoulou, A T; Diamantidis, G C

    2000-01-01

    A simple, rapid, and accurate method is described for the determination of residual fluvalinate in beeswax. The procedure consists of partitioning on a disposable column of diatomaceous earth (Extrelut), followed by chromatographic cleanup on a Florisil cartridge. The final extract is analyzed by capillary gas chromatography with electron-capture detection (GC-ECD). Briefly, wax samples were dissolved in n-hexane, and the solutions were sonicated and transferred to Extrelut columns. The fluvalinate was extracted with acetonitrile, and a portion of the extract was cleaned up on a Florisil cartridge. The fluvalinate was eluted with diethyl ether-n-hexane (1 + 1) and directly determined by GC-ECD. Recoveries from wax samples spiked at 5 fortification levels (100-1500 microg/kg) ranged from 77.4 to 87.3%, with coefficients of variation of 5.12-8.31%. The overall recovery of the method was 81.4 +/- 3.2%, and the limit of determination was 100 microg/kg.

  8. Trace analysis of sulfamethazine in animal feed, human urine, and wastewater by electron capture gas chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Holder, C.L.; Thompson, H.C. Jr.; Bowman, M.C.

    1981-12-01

    Sulfamethazine, a widely used antibacterial drug additive in feeds for swine, chickens, and cattle, was scheduled for toxicological evaluation because of potential human health hazards associated with its residues in edible animal tissues. Analytical chemical procedures that would ensure proper concentration, homogeneity, and stability of the drug in dosed feed and its safe usage during the animal studies were prerequisites for such toxicological tests. Electron capture gas chromatographic (EC/GC) methods were therefore devised for the analysis of sulfamethazine residues in animal feed, human urine, and wastewater at levels as low as 100, 10, and 10 ppb, respectively. Sample extracts were cleaned up by using liquid/liquid partitioning, and the extracts were subjected to two derivatizations followed by cleanup on a silica gel column. The derivatizations of sulfamethazine consisted of methylation followed by trifluoroacetylation of the primary amine function. Ancillary data concerning stability of the compound in animal feed, water, and as a dry residue on glass, extraction efficiencies, partition values with various solvents, and the analysis of residues in feed by high pressure liquid chromatography (HPLC) at levels as low as 1.0 ppm are presented.

  9. Classical electron ionization mass spectra in gas chromatography/mass spectrometry with supersonic molecular beams.

    Science.gov (United States)

    Gordin, Alexander; Fialkov, Alexander B; Amirav, Aviv

    2008-09-01

    A major benefit of gas chromatography/mass spectrometry (GC/MS) with a supersonic molecular beam (SMB) interface and its fly-through ion source is the ability to obtain electron ionization of vibrationally cold molecules (cold EI), which show enhanced molecular ions. However, GC/MS with an SMB also has the flexibility to perform 'classical EI' mode of operation which provides mass spectra to mimic those in commercial 70 eV electron ionization MS libraries. Classical EI in SMB is obtained through simple reduction of the helium make-up gas flow rate, which reduces the SMB cooling efficiency; hence the vibrational temperatures of the molecules are similar to those in traditional EI ion sources. In classical EI-SMB mode, the relative abundance of the molecular ion can be tuned and, as a result, excellent identification probabilities and very good matching factors to the NIST MS library are obtained. Classical EI-SMB with the fly-through dual cage ion source has analyte sensitivity similar to that of the standard EI ion source of a basic GC/MS system. The fly-through EI ion source in combination with the SMB interface can serve for cold EI, classical EI-SMB, and cluster chemical ionization (CCI) modes of operation, all easily exchangeable through a simple and quick change (not involving hardware). Furthermore, the fly-through ion source eliminates sample scattering from the walls of the ion source, and thus it offers full sample inertness, tailing-free operation, and no ion-molecule reaction interferences. It is also robust and enables increased column flow rate capability without affecting the sensitivity.

  10. Hydrodynamic chromatography coupled to single-particle ICP-MS for the simultaneous characterization of AgNPs and determination of dissolved Ag in plasma and blood of burn patients.

    Science.gov (United States)

    Roman, Marco; Rigo, Chiara; Castillo-Michel, Hiram; Munivrana, Ivan; Vindigni, Vincenzo; Mičetić, Ivan; Benetti, Federico; Manodori, Laura; Cairns, Warren R L

    2016-07-01

    Silver nanoparticles (AgNPs) are increasingly used in medical devices as innovative antibacterial agents, but no data are currently available on their chemical transformations and fate in vivo in the human body, particularly on their potential to reach the circulatory system. To study the processes involving AgNPs in human plasma and blood, we developed an analytical method based on hydrodynamic chromatography (HDC) coupled to inductively coupled plasma mass spectrometry (ICP-MS) in single-particle detection mode. An innovative algorithm was implemented to deconvolute the signals of dissolved Ag and AgNPs and to extrapolate a multiparametric characterization of the particles in the same chromatogram. From a single injection, the method provides the concentration of dissolved Ag and the distribution of AgNPs in terms of hydrodynamic diameter, mass-derived diameter, number and mass concentration. This analytical approach is robust and suitable to study quantitatively the dynamics and kinetics of AgNPs in complex biological fluids, including processes such as agglomeration, dissolution and formation of protein coronas. The method was applied to study the transformations of AgNP standards and an AgNP-coated dressing in human plasma, supported by micro X-ray fluorescence (μXRF) and micro X-ray absorption near-edge spectroscopy (μXANES) speciation analysis and imaging, and to investigate, for the first time, the possible presence of AgNPs in the blood of three burn patients treated with the same dressing. Together with our previous studies, the results strongly support the hypothesis that the systemic mobilization of the metal after topical administration of AgNPs is driven by their dissolution in situ. Graphical Abstract Simplified scheme of the combined analytical approach adopted for studying the chemical dynamics of AgNPs in human plasma/blood.

  11. Bacterial hydrodynamics

    CERN Document Server

    Lauga, Eric

    2015-01-01

    Bacteria predate plants and animals by billions of years. Today, they are the world's smallest cells yet they represent the bulk of the world's biomass, and the main reservoir of nutrients for higher organisms. Most bacteria can move on their own, and the majority of motile bacteria are able to swim in viscous fluids using slender helical appendages called flagella. Low-Reynolds-number hydrodynamics is at the heart of the ability of flagella to generate propulsion at the micron scale. In fact, fluid dynamic forces impact many aspects of bacteriology, ranging from the ability of cells to reorient and search their surroundings to their interactions within mechanically and chemically-complex environments. Using hydrodynamics as an organizing framework, we review the biomechanics of bacterial motility and look ahead to future challenges.

  12. Nanoflow hydrodynamics

    DEFF Research Database (Denmark)

    Hansen, Jesper Schmidt; Dyre, Jeppe C.; Daivis, Peter J.;

    2011-01-01

    We show by nonequilibrium molecular dynamics simulations that the Navier-Stokes equation does not correctly describe water flow in a nanoscale geometry. It is argued that this failure reflects the fact that the coupling between the intrinsic rotational and translational degrees of freedom becomes...... important for nanoflows. The coupling is correctly accounted for by the extended Navier-Stokes equations that include the intrinsic angular momentum as an independent hydrodynamic degree of freedom. © 2011 American Physical Society....

  13. 2D hydrodynamic simulations of a variable length gas target for density down-ramp injection of electrons into a laser wakefield accelerator

    Energy Technology Data Exchange (ETDEWEB)

    Kononenko, O., E-mail: olena.kononenko@desy.de [Deutsches Elektronen-Synchrotron DESY, Hamburg (Germany); Lopes, N.C.; Cole, J.M.; Kamperidis, C.; Mangles, S.P.D.; Najmudin, Z. [The John Adams Institute for Accelerator Science, The Blackett Laboratory, Imperial College London, SW7 2BZ UK (United Kingdom); Osterhoff, J. [Deutsches Elektronen-Synchrotron DESY, Hamburg (Germany); Poder, K. [The John Adams Institute for Accelerator Science, The Blackett Laboratory, Imperial College London, SW7 2BZ UK (United Kingdom); Rusby, D.; Symes, D.R. [Central Laser Facility, STFC Rutherford Appleton Laboratory, Chilton, Didcot OX11 0QX (United Kingdom); Warwick, J. [Queens University Belfast, North Ireland (United Kingdom); Wood, J.C. [The John Adams Institute for Accelerator Science, The Blackett Laboratory, Imperial College London, SW7 2BZ UK (United Kingdom); Palmer, C.A.J. [Deutsches Elektronen-Synchrotron DESY, Hamburg (Germany)

    2016-09-01

    In this work, two-dimensional (2D) hydrodynamic simulations of a variable length gas cell were performed using the open source fluid code OpenFOAM. The gas cell was designed to study controlled injection of electrons into a laser-driven wakefield at the Astra Gemini laser facility. The target consists of two compartments: an accelerator and an injector section connected via an aperture. A sharp transition between the peak and plateau density regions in the injector and accelerator compartments, respectively, was observed in simulations with various inlet pressures. The fluid simulations indicate that the length of the down-ramp connecting the sections depends on the aperture diameter, as does the density drop outside the entrance and the exit cones. Further studies showed, that increasing the inlet pressure leads to turbulence and strong fluctuations in density along the axial profile during target filling, and consequently, is expected to negatively impact the accelerator stability.

  14. Rapid direct analysis to discriminate geographic origin of extra virgin olive oils by flash gas chromatography electronic nose and chemometrics.

    Science.gov (United States)

    Melucci, Dora; Bendini, Alessandra; Tesini, Federica; Barbieri, Sara; Zappi, Alessandro; Vichi, Stefania; Conte, Lanfranco; Gallina Toschi, Tullia

    2016-08-01

    At present, the geographical origin of extra virgin olive oils can be ensured by documented traceability, although chemical analysis may add information that is useful for possible confirmation. This preliminary study investigated the effectiveness of flash gas chromatography electronic nose and multivariate data analysis to perform rapid screening of commercial extra virgin olive oils characterized by a different geographical origin declared in the label. A comparison with solid phase micro extraction coupled to gas chromatography mass spectrometry was also performed. The new method is suitable to verify the geographic origin of extra virgin olive oils based on principal components analysis and discriminant analysis applied to the volatile profile of the headspace as a fingerprint. The selected variables were suitable in discriminating between "100% Italian" and "non-100% Italian" oils. Partial least squares discriminant analysis also allowed prediction of the degree of membership of unknown samples to the classes examined.

  15. Enantioselective recognition of radezolid by cyclodextrin modified capillary electrokinetic chromatography and electronic circular dichroism.

    Science.gov (United States)

    Michalska, Katarzyna; Gruba, Ewa; Bocian, Wojciech; Cielecka-Piontek, Judyta

    2017-05-30

    A method for the enantioseparation of radezolid (RAD), an analogue of a truly new class of antibacterial agents, oxazolidinones, was developed based on capillary electrokinetic chromatography using a cyclodextrin as a chiral pseudophase (CD-cEKC). The mechanism of RAD separation, together with its precursor, were investigated to directly define the relationship between the oxazolidinone structure and the complexation process. During the development of the method, anionic single isomer cyclodextrins were tested. They were ranked in order from hydrophilic to hydrophobic as follows: heptakis-(2,3-dihydroxy-6-sulfo)-β-cyclodextrin (HS-β-CD), heptakis-(2,3-diacetyl-6-sulfo)-β-cyclodextrin (HDAS-β-CD) and heptakis-(2,3-dimethyl-6-sulfo)-β-cyclodextrin (HDMS-β-CD). Experiments were performed at pH values of 2.5, 6.6, 8.2 and 9.6. The cyclodextrins that had an acetyl or methyl group at the C2 and C3 positions, referred to as HDAS-β-CD and HDMS-β-CD, respectively, exhibited partial and baseline separation of enantiomers in a low pH buffer. However, higher temperatures were required for HDAS-β-CD and acetonitrile addition was required for HDMS-β-CD. During the experiments, different organic solvents, varying in their amphiprotic or aprotic nature, were tested. The best results for the separation of enantiomers using the CD-cEKC method were obtained with 40mM HDMS-β-CD dissolved in a 50mM phosphate buffer (pH 2.5) with the addition of acetonitrile (65:35, v/v) at 27°C, reversed polarity and a voltage equal to 28kV. The apparent binding constants for each enantiomer to HDAS-β-CD or HDMS-β-CD were calculated. Finally, the stereochemistry of (S) and (R)-RAD and the behaviour of selected complex formations were established using electronic circular dichroism. Copyright © 2017 Elsevier B.V. All rights reserved.

  16. Introduction to Hydrodynamics

    CERN Document Server

    Jeon, Sangyong

    2015-01-01

    We give a pedagogical review of relativistic hydrodynamics relevant to relativistic heavy ion collisions. Topics discussed include linear response theory derivation of 2nd order viscous hydrodynamics including the Kubo formulas, kinetic theory derivation of 2nd order viscous hydrodynamics, anisotropic hydrodynamics and a brief review of numerical algorithms. Emphasis is given to the theory of hydrodynamics rather than phenomenology.

  17. Submarine hydrodynamics

    CERN Document Server

    Renilson, Martin

    2015-01-01

    This book adopts a practical approach and presents recent research together with applications in real submarine design and operation. Topics covered include hydrostatics, manoeuvring, resistance and propulsion of submarines. The author briefly reviews basic concepts in ship hydrodynamics and goes on to show how they are applied to submarines, including a look at the use of physical model experiments. The issues associated with manoeuvring in both the horizontal and vertical planes are explained, and readers will discover suggested criteria for stability, along with rudder and hydroplane effectiveness. The book includes a section on appendage design which includes information on sail design, different arrangements of bow planes and alternative stern configurations. Other themes explored in this book include hydro-acoustic performance, the components of resistance and the effect of hull shape. Readers will value the author’s applied experience as well as the empirical expressions that are presented for use a...

  18. Analysis of neonicotinoids by gas chromatography coupled to nuclide {sup 63}Ni - Electron Capture Detector - GC/ECD

    Energy Technology Data Exchange (ETDEWEB)

    Amaral, Priscila O.; Leao, Claudio; Redigolo, Marcelo M.; Crepaldi, Caike; Bustillos, Oscar V., E-mail: priscilaoamaral@gmail.com, E-mail: claudio.leao@usp.br, E-mail: marceloredigolo@gmail.com, E-mail: caike1995@gmail.com, E-mail: ovega@ipen.bremails [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2015-07-01

    Recently, several reports have been published discussing reduction in bee population which polymerizes cultures around the world this phenomenon is known as Colony Collapse Disorder (CCD). The phenomenon describes the lack of worker honeybees in the colony despite having pups and food. The causes of this problem are unknown but there are studies that claim that reduction of population of bees is linked to poisoning through insecticides specifically neonicotinoids. Among this type of pesticide are imidacloprid (C{sub 9}H{sub 10}ClN{sub 5}O{sub 2}), clothianidin (C{sub 6}H{sub 8}ClN{sub 5}O{sub 2}S) and thiamethoxam (C{sub 8}H{sub 10}ClN{sub 5}O{sub 3}S). This paper presents the analysis of neonicotinoids - clothianidin, imidacloprid and thiamethoxam - by the technique of gas chromatography coupled to nuclide {sup 63}Ni electron capture detector (GC/ECD). The electron capture detector (ECD) is a gas chromatography detector that has been used for the detection of organic halogens, nitriles, nitrates and organometallic compounds. The ECD detector ionizes the analytes by the beta particles from the nuclide sources {sup 63}Ni within carrier gas N{sub 2}. The electrons produced in this process are collected and create a current that are amplified and generates a chromatographic peak. Methodology and details of the analysis are present in this work. (author)

  19. Determination of chloramphenicol residue in fish and shrimp tissues by gas chromatography with a microcell electron capture detector.

    Science.gov (United States)

    Ding, Shuangyang; Shen, Jianzhong; Zhang, Suxia; Jiang, Haiyang; Sun, Zhiwen

    2005-01-01

    A gas chromatography method with microcell electron capture detection was developed for the determination of chloramphenicol residue in fish and shrimp muscle tissues. The tissue samples were extracted with ethyl acetate, defatted with hexane, and derivatized with Sylon BFT [N,O-bis (trimethylsilyl) trifluoroacetamide-trimethylchlorosilane (99 + 1)]. The limit of detection was 0.04 ng/g and the limit of quantitation 0.1 ng/g. Average recoveries were 70.8-90.8% for fish and 69.9-86.3% for shrimp, respectively. The method was validated for the determination of practical samples.

  20. Quality assurance of commercial beeswax. Part I. Gas chromatography-electron impact ionization mass spectrometry of hydrocarbons and monoesters.

    Science.gov (United States)

    Jiménez, J J; Bernal, J L; Aumente, S; del Nozal, Ma J; Martín, Ma T; Bernal, J

    2004-01-23

    The use of low-temperature capillary gas chromatography coupled to electron impact mass spectrometry for the characterization of crude beeswaxes yielded by Apis mellifera is described. The system allows the identification of a great number of compounds, some of them not reported till now in beeswax, such as a family of ethyl esters, tetracosyl oleate, and several saturated and unsaturated hydrocarbons. The information acquired makes possible the differentiation between pure beeswax and some foundation beeswax samples where mixture of pure beeswax with another substances is suspected.

  1. Relative Quantification of Sites of Peptide and Protein Modification Using Size Exclusion Chromatography Coupled with Electron Transfer Dissociation

    Science.gov (United States)

    Xie, Boer; Sharp, Joshua S.

    2016-08-01

    One difficult problem in the analysis of peptide modifications is quantifying isomeric modifications that differ by the position of the amino acid modified. HPLC separation using C18 reverse phase chromatography coupled with electron transfer dissociation (ETD) in tandem mass spectrometry has recently been shown to be able to relatively quantify how much of a given modification occurs at each amino acid position for isomeric mixtures; however, the resolution of reverse phase chromatography greatly complicates quantification of isomeric modifications by ETD because of the chromatographic separation of peptides with identical modifications at different sequence positions. Using peptide oxidation as a model system, we investigated the use of size exclusion chromatography coupled with ETD fragmentation to separate peptide sequences. This approach allows for the benefits of chromatographic separation of peptide sequences while ensuring co-elution of modification isomers for accurate relative quantification of modifications using standard data-dependent acquisitions. Using this method, the relative amount of modification at each amino acid can be accurately measured from single ETD MS/MS spectra in a standard data-dependent acquisition experiment.

  2. Comparison of gas chromatography-mass spectrometry and gas chromatography-tandem mass spectrometry with electron ionization for determination of N-nitrosamines in environmental water.

    Science.gov (United States)

    Chen, Wenwen; Li, Xiaoshui; Huang, Huanfang; Zhu, Xuetao; Jiang, Xiaoyu; Zhang, Yuan; Cen, Kuang; Zhao, Lunshan; Liu, Xiuli; Qi, Shihua

    2017-02-01

    N-nitrosamines are trace organic contaminants of environmental concern when present in groundwater and river water due to their potent carcinogenicity. Therefore, N-nitrosamine analysis is increasingly in demand. Gas chromatography-mass spectrometry (GC-MS) and GC-tandem mass spectrometry (GC-MS/MS), both with electron ionization (EI), were compared for analysis of nine N-nitrosamines extracted from environmental water matrices. A total of 20 fishpond water, river water, and groundwater samples from Sihui and Shunde, China were collected for a survey of N-nitrosamine concentrations in real water samples. Various solid-phase extraction (SPE) conditions and GC conditions were first examined for the pre-concentration and separation steps. The analysis of N-nitrosamines in environmental waters demonstrated that their quantification with GC-MS poses a challenge due to the occurrence of co-eluting interferences. Conversely, the use of GC-MS/MS increased selectivity because of the fragmentation generated from precursor ions in the 'multiple reaction monitoring' (MRM) mode, which is expected to extract target analytes from the environmental water matrix. Thus, the high performance of GC-MS/MS with EI was used to quantify nine N-nitrosamines in environmental waters with detection limits of 1.1-3.1 ng L(-1). N-nitrosodimethylamine (NDMA) concentrations were in the range of N.D. to 258 ng L(-1). Furthermore, other N-nitrosamines, except N-nitrosomethylethylamine (NMEA), N-nitroso-di-n-propylamine (NDPA) and N-nitrosopiperidine (NPIP), were also detected. Our findings suggest that GC-MS/MS with EI would be widely applicable in identifying N-nitrosamines in environmental waters and can be used for routine monitoring of these chemicals.

  3. Qualitative analysis of Copaifera oleoresin using comprehensive two-dimensional gas chromatography and gas chromatography with classical and cold electron ionisation mass spectrometry.

    Science.gov (United States)

    Wong, Yong Foo; Uekane, Thais M; Rezende, Claudia M; Bizzo, Humberto R; Marriott, Philip J

    2016-12-16

    Improved separation of both sesquiterpenes and diterpenic acids in Copaifera multijuga Hayne oleoresin, is demonstrated by using comprehensive two-dimensional gas chromatography (GC×GC) coupled to accurate mass time-of-flight mass spectrometry (accTOFMS). GC×GC separation employs polar phases (including ionic liquid phases) as the first dimension ((1)D) column, combined with a lower polarity (2)D phase. Elution temperatures (Te) of diterpenic acids (in methyl ester form, DAME) increased as the (1)D McReynolds' polarity value of the column phase decreased. Since Te of sesquiterpene hydrocarbons decreased with increased polarity, the very polar SLB-IL111 (1)D phase leads to excessive peak broadening in the (2)D apolar phase due to increased second dimension retention ((2)tR). The combination of SLB-IL59 with a nonpolar column phase was selected, providing reasonable separation and low Te for sesquiterpenes and DAME, compared to other tested column sets, without excessive (2)tR. Identities of DAME were aided by both soft (30eV) electron ionisation (EI) accurate mass TOFMS analysis and supersonic molecular beam ionisation (cold EI) TOFMS, both which providing less fragmentation and increased relative abundance of molecular ions. The inter-relation between EI energies, emission current, signal-to-noise and mass error for the accurate mass measurement of DAME are reported. These approaches can be used as a basis for conducting of GC×GC with soft EI accurate mass measurement of terpenes, particularly for unknown phytochemicals.

  4. Simultaneous analysis of polychlorinated biphenyls and organochlorine pesticides in seawater samples by membrane-assisted solvent extraction combined with gas chromatography-electron capture detector and gas chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Shi, Xizhi; Tang, Zigang; Sun, Aili; Zhou, Lei; Zhao, Jian; Li, Dexiang; Chen, Jiong; Pan, Daodong

    2014-12-01

    A highly efficient and environment-friendly membrane-assisted solvent extraction system combined with gas chromatography-electron capture detector was applied in the simultaneous determination of 17 polychlorinated biphenyls and organochlorine pesticides in seawater samples. Variables affecting extraction efficiency, including extraction solvent used, stirring rate, extraction time, and temperature, were optimized extensively. Under optimal extraction conditions, recoveries between 76.9% and 104.6% in seawater samples were achieved, and relative standard deviation values below 10% were obtained. The limit of detection (signal-to-noise ratio=3) and limit of quantification (signal-to-noise ratio=10) of 17 polychlorinated biphenyls and organochlorine pesticides in seawater ranged from 0.14ngL(-1) to 0.36ngL(-1) and 0.46ngL(-1) to 1.19ngL(-1), respectively. Matrix effects on extraction efficiency were evaluated by comparing with the results obtained using tap water. The extraction effect of developed membrane-assisted solvent extraction method was further demonstrated by gas chromatography-tandem mass spectrometry which can provide structural information of the analytes for more accurate identification, and results identical to those produced by gas chromatography-electron capture detector were obtained. These findings demonstrate the applicability of the developed membrane-assisted solvent extraction determination method for coupling to gas chromatography-electron capture detector or tandem mass spectrometry for determining polychlorinated biphenyls and organochlorine pesticides in seawater samples.

  5. Enrichment and Analysis of Non-enzymatically Glycated Peptides: Boronate Affinity Chromatography Coupled with Electron Transfer Dissociation Mass Spectrometry

    Science.gov (United States)

    Zhang, Qibin; Tang, Ning; Brock, Jonathan W. C.; Mottaz, Heather M.; Ames, Jennifer M.; Baynes, John W.; Smith, Richard D.; Metz, Thomas O.

    2008-01-01

    Non-enzymatic glycation of peptides and proteins by D-glucose has important implications in the pathogenesis of diabetes mellitus, particularly in the development of diabetic complications. However, no effective high-throughput methods exist for identifying proteins containing this low abundance post-translational modification in bottom-up proteomic studies. In this report, phenylboronate affinity chromatography was used in a two-step enrichment scheme to selectively isolate first glycated proteins and then glycated, tryptic peptides from human serum glycated in vitro. Enriched peptides were subsequently analyzed by alternating electron transfer dissociation (ETD) and collision induced dissociation (CID) tandem mass spectrometry. ETD fragmentation mode permitted identification of a significantly higher number of glycated peptides (87.6% of all identified peptides) versus CID mode (17.0% of all identified peptides), when utilizing enrichment on first the protein and then the peptide level. This study illustrates that phenylboronate affinity chromatography coupled with LC-MS/MS and using ETD as the fragmentation mode is an efficient approach for analysis of glycated proteins and may have broad application in studies of diabetes mellitus. PMID:17488106

  6. Enrichment and Analysis of Nonenzymatically Glycated Peptides: Boronate Affinity Chromatography Coupled with Electron-Transfer Dissociation Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Qibin; Tang, Ning; Brock, Jonathan W.; Mottaz, Heather M.; Ames, Jennifer M.; Baynes, John; Smith, Richard D.; Metz, Thomas O.

    2007-06-01

    Non-enzymatic glycation of peptides and proteins by D-glucose has important implications in the pathogenesis of diabetes mellitus, particularly in the development of diabetic complications. However, no effective high-throughput methods exist for identifying proteins containing this low abundance post-translational modification in bottom-up proteomic studies. In this report, phenylboronate affinity chromatography was used in a two-step enrichment scheme to selectively isolate first glycated proteins and then glycated, tryptic peptides from human serum glycated in vitro. Enriched peptides were subsequently analyzed by alternating electron transfer dissociation (ETD) and collision induced dissociation (CID) tandem mass spectrometry. It was observed that ETD fragmentation mode resulted in a significantly higher number of glycated peptide identifications (87.6% of all identified peptides) versus CID mode (17.0% of all identified peptides), when utilizing dual glycation enrichment on both the protein and peptide level. This study illustrates that phenylboronate affinity chromatography coupled with LC-MS/MS with ETD as the fragmentation mode is an efficient approach for analyses of glycated proteins and can have broad applications in studies of diabetes mellitus.

  7. Analytical Method Validation of Selected Organochlorine Pesticides in Fortified Rice Using Gas Chromatography with Electron Capture Detector

    Directory of Open Access Journals (Sweden)

    Mutia Kusuma Wardani

    2014-01-01

    Full Text Available Gas chromatography with electron capture detector (GC-ECD has been validated for simultaneous determination of selected organochlorine pesticides namely heptachlor, endosulfan, dieldrin, dan p,p’-dichlorodiphenyltrichloroethane (p,p’-DDT using aldrin as standard internal. Some parameters for analytical method validation were evaluated, i.e. linearity, precision, sensitivity expressed with limit of detection and limit of quantification, and recovery. GC-ECD was linear for determination of these pesticides with r values ≥ 0.99. The values of LOD obtained were 2.50, 2.97, 1.61, and 2.54 ng/mL for heptachlor, endosulphan, dieldrin, and p,p’-DDT, respectively. Furthermore, the relative standard deviation (RSD values obtained for the assessment of analytical precision were lower than those required by Horwitz. Finally, the used GC-ECD method was accurate for determination of these organochlorine psticides in fortified rice samples which were indicated by the acceptable recovery percentages.

  8. Determination of fluoxetine and norfluoxetine in plasma by gas chromatography with electron-capture detection

    Energy Technology Data Exchange (ETDEWEB)

    Nash, J.F.; Bopp, R.J.; Carmichael, R.H.; Farid, K.Z.; Lemberger, L.

    1982-10-01

    This gas-chromatographic method for assay of fluoxetine and norfluoxetine in human plasma involves extraction of the drugs and use of a /sup 63/Ni electron-capture detector. The linear range of detection is 25 to 800 micrograms/L for each drug. Overall precision (CV) in the concentration range of 10 to 100 micrograms/L for both drugs was approximately 10%. Accuracy (relative error) in the same concentration range was approximately +10%. None of the commonly prescribed antidepressants or tranquilizers that we tested interfere with the assay.

  9. Analysis of boronic acids by nano liquid chromatography-direct electron ionization mass spectrometry.

    Science.gov (United States)

    Flender, Cornelia; Leonhard, Peter; Wolf, Christian; Fritzsche, Matthias; Karas, Michael

    2010-05-15

    A new method, based on a direct-electron ionization (EI) interface, is presented for the analysis of compounds insufficiently amenable to usual MS methods. The instrumentation is composed of a nano liquid chromatograph (LC) and a mass spectrometer (MS) directly coupled by a transfer capillary. The eluent is directly introduced into the heated electron impact ion source of the MS. Significant advantages are the generation of reproducible spectra and the ability to ionize highly polar compounds. Boronic acids are used as coupling reagents to produce drugs, agrochemicals, or herbicides. The purity of educts is of high importance because impurities in the educt are directly associated with impurities in the product. Because of their high polarity and tendency to form boroxines, boronic acids require derivatization for GC analysis. The presented nano-LC-EI/MS method is easily applicable for a broad range of boronic acids. The method shows good detection limits for boronic acids up to 200 pg, is perfectly linear, and shows a very high robustness and reproducibility. A mixture of compounds could easily be separated on a monolithic RP18e column. The method represents a new, simple, robust, and reproducible approach for the detection of polar analytes. It is a good candidate to become a standard method for industrial applications.

  10. Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory; determination of chlorinated pesticides in aquatic tissue by capillary-column gas chromatography with electron-capture detection

    Science.gov (United States)

    Leiker, Thomas J.; Madsen, J.E.; Deacon, J.R.; Foreman, W.T.

    1995-01-01

    A method for the determination of chlorinated organic compounds in aquatic tissue by dual capillary-column gas chromatography with electron-capture detection is described. Whole-body-fish or corbicula tissue is homogenized, Soxhlet extracted, lipid removed by gel permeation chromatography, and fractionated using alumina/silica adsorption chromatography. The extracts are analyzed by dissimilar capillary-column gas chromatography with electron-capture detection. The method reporting limits are 5 micrograms per kilogram (μg/kg) for chlorinated compounds, 50 μg/kg for polychlorinated biphenyls, and 200 μg/kg for toxaphene.

  11. Determination of Isoflavone Content in SRM 3238 Using Liquid Chromatography-Particle Beam/Electron Ionization Mass Spectrometry

    Science.gov (United States)

    Zhang, Lynn X.; Burdette, Carolyn Q.; Phillips, Melissa M.; Rimmer, Catherine A.; Marcus, R. Kenneth

    2016-01-01

    The characterization of marker components in botanical materials is a challenging task and the increased consumption of botanicals and dietary supplements demands a greater understanding of the associated health benefits and risks. In order to successfully acquire and compare clinical results and correlate health trends, accurate, precise, and validated methods of analysis must be developed. Presented here is the development of a quantitative method for the determination of soy isoflavones (daidzin, glycitin, genistin, daidzein, and genistein) using liquid chromatography-particle beam/electron ionization mass spectrometry (LC-PB/EIMS). An internal standard (IS) approach for quantitation using 7-hydroxy-4-chromone as the IS compound was employed, with response factors for each individual isoflavone obtained from calibrant solutions. The results from this method were compared with the certified and reference values for NIST SRM 3238 Soy-Containing Solid Oral Dosage Form to demonstrate that the method was in control. Results obtained using LC-PB/EIMS were consistent with the NIST certified or reference values and their uncertainties for all five isoflavones, demonstrating that the LC-PB/EIMS approach is both accurate and precise when used for the determination of the target isoflavones in soy-containing dietary supplement finished products, while simultaneously providing structural information. PMID:26651559

  12. Comprehensive two-dimensional gas chromatography coupled with fast sulphur-chemiluminescence detection: implications of detector electronics.

    Science.gov (United States)

    Blomberg, Jan; Riemersma, Toby; van Zuijlen, Manfred; Chaabani, Hassan

    2004-09-24

    Within the petrochemical industry, there has been a growing interest in methods capable of providing detailed information on the distribution of sulphur-containing compounds in various product streams, going down to the level of separating and quantifying individual sulphur species. Since no single capillary gas chromatographic column is able to perform this separation, a refuge to multi-dimensional separation techniques has to be taken. In this respect, comprehensive two-dimensional gas chromatography (GC x GC) coupled with sulphur chemiluminescence detection (SCD) has shown to be highly promising. It has been suggested, however, that the detector volume of an SCD restricts its potential to keep up with the fast second-dimension separations of contemporary GC x GC. In this paper, we will demonstrate that the lack of speed of the SCD does not originate from its physical dimensions, but is largely determined by the speed of the electronics used. Additionally, some typical examples will be presented to illustrate the potential of GC x GC coupled with fast SCD.

  13. Identification and Quantification of Several Contaminated Compounds in Replacement Liquids of Electronic Cigarettes by Gas Chromatography-Mass Spectrometry.

    Science.gov (United States)

    Oh, Jin-Aa; Shin, Ho-Sang

    2015-07-01

    Electronic cigarettes (E-cigarettes) are devices that are refilled with replacement liquids, which normally contain propylene glycol, nicotine and the desired flavor blend. Many consumers suspect that hazardous substances are present in addition to nicotine content. In this study, eight contaminated compounds in 105 replacement liquids from 11 types of E-cigarettes sold in the Republic of Korea were identified and quantified by gas chromatography-mass spectrometry. Diethyl phthalate and diethylhexyl phthalate were detected in concentration ranges of 0.01-1745.20 mg/L (47.6% detection frequency) and 0.06-81.89 mg/L (79.1% detection frequency) in the replacement liquids. Triethylene glycol, tetraethylene glycol and pentaethylene glycol were quantified in concentration ranges of 0.1-19.3 mg/L (10.5% detection frequency), 0.1-30.1 mg/L (12.4% detection frequency) and 0.1-24.9 mg/L (6.7% detection frequency) in the same samples. cis-3-Hexene-1-ol, methyl cinnamate and dodecane were quantified in concentration ranges of 0.03-3267.46 mg/L (70.5% detection frequency), 4.41-637.54 mg/L (6.7% detection frequency) and 0.01-639.96 mg/L (47.6% detection frequency) in the samples.

  14. Elasto-hydrodynamic lubrication

    CERN Document Server

    Dowson, D; Hopkins, D W

    1977-01-01

    Elasto-Hydrodynamic Lubrication deals with the mechanism of elasto-hydrodynamic lubrication, that is, the lubrication regime in operation over the small areas where machine components are in nominal point or line contact. The lubrication of rigid contacts is discussed, along with the effects of high pressure on the lubricant and bounding solids. The governing equations for the solution of elasto-hydrodynamic problems are presented.Comprised of 13 chapters, this volume begins with an overview of elasto-hydrodynamic lubrication and representation of contacts by cylinders, followed by a discussio

  15. Elementary classical hydrodynamics

    CERN Document Server

    Chirgwin, B H; Langford, W J; Maxwell, E A; Plumpton, C

    1967-01-01

    Elementary Classical Hydrodynamics deals with the fundamental principles of elementary classical hydrodynamics, with emphasis on the mechanics of inviscid fluids. Topics covered by this book include direct use of the equations of hydrodynamics, potential flows, two-dimensional fluid motion, waves in liquids, and compressible flows. Some general theorems such as Bernoulli's equation are also considered. This book is comprised of six chapters and begins by introducing the reader to the fundamental principles of fluid hydrodynamics, with emphasis on ways of studying the motion of a fluid. Basic c

  16. Nonlocal transport and the hydrodynamic shear viscosity in graphene

    Science.gov (United States)

    Torre, Iacopo; Tomadin, Andrea; Geim, Andre K.; Polini, Marco

    2015-10-01

    Motivated by recent experimental progress in preparing encapsulated graphene sheets with ultrahigh mobilities up to room temperature, we present a theoretical study of dc transport in doped graphene in the hydrodynamic regime. By using the continuity and Navier-Stokes equations, we demonstrate analytically that measurements of nonlocal resistances in multiterminal Hall bar devices can be used to extract the hydrodynamic shear viscosity of the two-dimensional (2D) electron liquid in graphene. We also discuss how to probe the viscosity-dominated hydrodynamic transport regime by scanning probe potentiometry and magnetometry. Our approach enables measurements of the viscosity of any 2D electron liquid in the hydrodynamic transport regime.

  17. Quasiparticle anisotropic hydrodynamics

    CERN Document Server

    Alqahtani, Mubarak

    2016-01-01

    We study an azimuthally-symmetric boost-invariant quark-gluon plasma using quasiparticle anisotropic hydrodynamics including the effects of both shear and bulk viscosities. We compare results obtained using the quasiparticle method with the standard anisotropic hydrodynamics and viscous hydrodynamics. We consider the predictions of the three methods for the differential particle spectra and mean transverse momentum. We find that the three methods agree for small shear viscosity to entropy density ratio, $\\eta/s$, but show differences at large $\\eta/s$. Additionally, we find that the standard anisotropic hydrodynamics method shows suppressed production at low transverse-momentum compared to the other two methods, and the bulk-viscous correction can drive the primordial particle spectra negative at large $p_T$ in viscous hydrodynamics.

  18. Simultaneous determination of florfenicol and florfenicol amine in fish, shrimp, and swine muscle by gas chromatography with a microcell electron capture detector.

    Science.gov (United States)

    Zhang, Suxia; Sun, Fengyun; Li, Jiancheng; Cheng, Linli; Shen, Jianzhong

    2006-01-01

    A rapid and sensitive gas chromatography method was developed for the simultaneous determination of florfenicol (FF) and its metabolite florfenicol amine (FFA) in fish, shrimp, and swine muscle. The extracted samples were defatted with hexane and cleaned up by solid-phase extraction using Oasis MCX cartridges. The eluate was evaporated to dryness, and residues were derivatized and determined by gas chromatography with a microcell electron capture detector. Overall average recoveries ranged from 81.7 to 109.7% for fish, 94.1 to 103.4% for shrimp, and 71.5 to 91.4% for swine muscle. The detection limit was 0.5 ng/g for FF and 1 ng/g for FFA, respectively. The method was validated for the determination of incurred swine muscle samples in an actual residue study.

  19. Hydrodynamics and black holes

    CERN Document Server

    Oz, Yaron

    2015-01-01

    This chapter describes how the AdS/CFT correspondence (the Holographic Principle) relates field theory hydrodynamics to perturbations of black hole (brane) gravitational backgrounds. The hydrodynamics framework is first presented from the field theory point of view, after which the dual gravitational description is outlined, first for relativistic fluids and then for the nonrelativistic case. Further details of the fluid/gravity correspondence are then discussed, including the bulk geometry and the dynamics of the black hole horizon.

  20. Qualitative characteristics and comparison of volatile fraction of vodkas made from different botanical materials by comprehensive two-dimensional gas chromatography and the electronic nose based on the technology of ultra-fast gas chromatography.

    Science.gov (United States)

    Wiśniewska, Paulina; Śliwińska, Magdalena; Dymerski, Tomasz; Wardencki, Waldemar; Namieśnik, Jacek

    2017-03-01

    Vodka is a spirit-based beverage made from ethyl alcohol of agricultural origin. At present, increasingly more vodka brands have labels that specify the botanical origin of the product. Until now, the techniques for distinguishing between vodkas of different botanical origin have been costly, time-consuming and insufficient for making a distinction between vodka produced from similar raw materials. Therefore, it is of utmost importance to find a fast and relatively inexpensive technique for conducting such tests. In the present study, we employed comprehensive two-dimensional gas chromatography (GC×GC) and an electronic nose based on the technology of ultra-fast GC with chemometric methods such as partial least square discriminant analysis, discriminant function analysis and soft independent modeling of class analogy. Both techniques allow a distinction between the vodkas produced from different raw materials. In the case of GC×GC, the differences between vodkas were more noticeable than in the analysis by electronic nose; however, the electronic nose allowed the significantly faster analysis of vodkas. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

  1. Quality assurance of commercial beeswax II. Gas chromatography-electron impact ionization mass spectrometry of alcohols and acids.

    Science.gov (United States)

    Jiménez, J J; Bernal, J L; Aumente, S; Toribio, L; Bernal, J

    2003-07-25

    Gas chromatography with mass spectrometric detection was used to find the fraction of alcohols and acids present in pure beeswax from Apis mellifera. Some new compounds not described till now were found, such as a family of unsaturated linear fatty acids, several hydroxyacids and 1,2,3-propanetriol monoesters. The chromatographic profiles obtained from pure beeswax and bee-rejected foundation beeswax can be used to discriminate them; they mainly differ in the amount of some acids and alcohols.

  2. An evaluation of sucrose as a possible contaminant in e-liquids for electronic cigarettes by hydrophilic interaction liquid chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Kubica, Paweł; Wasik, Andrzej; Kot-Wasik, Agata; Namieśnik, Jacek

    2014-05-01

    The influence of sucrose combustion products on smoking and nicotine addiction is still controversial because the presence of the sucrose may be treated as a source of aldehydes and organic acids. In e-liquids used as refills for electronic cigarettes, which are made primarily of poly(propylene glycol), glycerine and ethanol, sucrose may be present at trace levels, and its impact on mainstream smoke formation, and hence on human health and smoking/nicotine addiction is unknown. An analytical method was developed where high-performance liquid chromatography in hydrophilic interaction liquid chromatography mode and tandem mass spectrometry were used for fast and simple determination of sucrose and other saccharides in e-liquids for electronic cigarettes. Minimal effort was required in the sample preparation step, and satisfactory results were obtained, and the sample matrix had an insignificant impact. The chromatographic separation was done using an Ascentis Express OH5 column (150 mm × 2.1 mm, 2.7 μm). The coefficients of variation for within-day precision for three concentrations were 2.4 %, 1.6 % and 2.3 %, and the between-day coefficients of variation for a single concentration were 2.1 %, 2.5 % and 1.7 % measured on the next 3 days. The detection limit was 0.73 μg/g, and the sucrose content in e-liquids ranged from 0.76 to 72.93 μg/g among 37 samples. Moreover, with the method presented it is possible to determine the presence of other saccharides such as fructose, glucose, maltose and lactose. However, only sucrose was found in all samples of e-liquids. The proposed method is rapid, simple and reliable in terms of high-performance liquid chromatography coupled with tandem mass spectrometry.

  3. Anisotropic hydrodynamics -- basic concepts

    CERN Document Server

    Florkowski, Wojciech; Ryblewski, Radoslaw; Strickland, Michael

    2013-01-01

    Due to the rapid longitudinal expansion of the quark-gluon plasma created in relativistic heavy ion collisions, potentially large local rest frame momentum-space anisotropies are generated. The magnitude of these momentum-space anisotropies can be so large as to violate the central assumption of canonical viscous hydrodynamical treatments which linearize around an isotropic background. In order to better describe the early-time dynamics of the quark gluon plasma, one can consider instead expanding around a locally anisotropic background which results in a dynamical framework called anisotropic hydrodynamics. In this proceedings contribution we review the basic concepts of the anisotropic hydrodynamics framework presenting viewpoints from both the phenomenological and microscopic points of view.

  4. Applying Chromatography.

    Science.gov (United States)

    Klein, Jessie W.; Patev, Paul

    1998-01-01

    Presents three experiments to introduce students to different kinds of chromatography: (1) paper chromatography; (2) gel filtration chromatography; and (3) reverse-phase liquid chromatography. Written in the form of a laboratory manual, explanations of each of the techniques, materials needed, procedures, and a glossary are included. (PVD)

  5. Dispersive hydrodynamics: Preface

    Science.gov (United States)

    Biondini, G.; El, G. A.; Hoefer, M. A.; Miller, P. D.

    2016-10-01

    This Special Issue on Dispersive Hydrodynamics is dedicated to the memory and work of G.B. Whitham who was one of the pioneers in this field of physical applied mathematics. Some of the papers appearing here are related to work reported on at the workshop "Dispersive Hydrodynamics: The Mathematics of Dispersive Shock Waves and Applications" held in May 2015 at the Banff International Research Station. This Preface provides a broad overview of the field and summaries of the various contributions to the Special Issue, placing them in a unified context.

  6. Determination of acrylamide in Chinese traditional carbohydrate-rich foods using gas chromatography with micro-electron capture detector and isotope dilution liquid chromatography combined with electrospray ionization tandem mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Yu [Department of Food Science and Nutrition, College of Biosystems Engineering and Food Science, Zhejiang University, Hangzhou 310029, Zhejiang Province (China); Ren Yiping [Zhejiang Provincial Center for Disease Prevention and Control, Hangzhou 310009, Zhejiang Province (China); Zhao Hangmei [Department of Food Science and Nutrition, College of Biosystems Engineering and Food Science, Zhejiang University, Hangzhou 310029, Zhejiang Province (China); Zhang Ying [Department of Food Science and Nutrition, College of Biosystems Engineering and Food Science, Zhejiang University, Hangzhou 310029, Zhejiang Province (China)]. E-mail: y_zhang@zju.edu.cn

    2007-02-19

    The present study developed two analytical methods for quantification of acrylamide in complex food matrixes, such as Chinese traditional carbohydrate-rich foods. One is based on derivatization with potassium bromate and potassium bromide without clean-up prior to gas chromatography with micro-electron capture detector (GC-MECD). Alternatively, the underivatized acrylamide was detected by high-performance liquid chromatography coupled to quadrupole tandem mass spectrometry (HPLC-MS/MS) in the positive electrospray ionization mode. For both methods, the Chinese carbohydrate-rich samples were homogenized, defatted with petroleum ether and extracted with aqueous solution of sodium chloride. Recovery rates for acrylamide from spiked Chinese style foods with the spiking level of 50, 500 and 1000 {mu}g kg{sup -1} were in the range of 79-93% for the GC-MECD including derivatization and 84-97% for the HPLC-MS/MS method. Typical quantification limits of the HPLC-MSMS method were 4 {mu}g kg{sup -1} for acrylamide. The GC-MECD method achieved quantification limits of 10 {mu}g kg{sup -1} in Chinese style foods. Thirty-eight Chinese traditional foods purchased from different manufacturers were analyzed and compared with four Western style foods. Acrylamide contaminant was found in all of samples at the concentration up to 771.1 and 734.5 {mu}g kg{sup -1} detected by the GC and HPLC method, respectively. The concentrations determined with the two different quantitative methods corresponded well with each other. A convenient and fast pretreatment procedure will be optimized in order to satisfy further investigation of hundreds of samples.

  7. Determination of acrylamide in Chinese traditional carbohydrate-rich foods using gas chromatography with micro-electron capture detector and isotope dilution liquid chromatography combined with electrospray ionization tandem mass spectrometry.

    Science.gov (United States)

    Zhang, Yu; Ren, Yiping; Zhao, Hangmei; Zhang, Ying

    2007-02-19

    The present study developed two analytical methods for quantification of acrylamide in complex food matrixes, such as Chinese traditional carbohydrate-rich foods. One is based on derivatization with potassium bromate and potassium bromide without clean-up prior to gas chromatography with micro-electron capture detector (GC-MECD). Alternatively, the underivatized acrylamide was detected by high-performance liquid chromatography coupled to quadrupole tandem mass spectrometry (HPLC-MS/MS) in the positive electrospray ionization mode. For both methods, the Chinese carbohydrate-rich samples were homogenized, defatted with petroleum ether and extracted with aqueous solution of sodium chloride. Recovery rates for acrylamide from spiked Chinese style foods with the spiking level of 50, 500 and 1000 microg kg(-1) were in the range of 79-93% for the GC-MECD including derivatization and 84-97% for the HPLC-MS/MS method. Typical quantification limits of the HPLC-MSMS method were 4 microg kg(-1) for acrylamide. The GC-MECD method achieved quantification limits of 10 microg kg(-1) in Chinese style foods. Thirty-eight Chinese traditional foods purchased from different manufacturers were analyzed and compared with four Western style foods. Acrylamide contaminant was found in all of samples at the concentration up to 771.1 and 734.5 microg kg(-1) detected by the GC and HPLC method, respectively. The concentrations determined with the two different quantitative methods corresponded well with each other. A convenient and fast pretreatment procedure will be optimized in order to satisfy further investigation of hundreds of samples.

  8. Smoothed Particle Hydrodynamic Simulator

    Energy Technology Data Exchange (ETDEWEB)

    2016-10-05

    This code is a highly modular framework for developing smoothed particle hydrodynamic (SPH) simulations running on parallel platforms. The compartmentalization of the code allows for rapid development of new SPH applications and modifications of existing algorithms. The compartmentalization also allows changes in one part of the code used by many applications to instantly be made available to all applications.

  9. Hydrodynamic aspect of caves

    Directory of Open Access Journals (Sweden)

    Franci Gabrovsek

    2008-01-01

    Full Text Available From a hydrological point of view, active caves are a series of connected conduits which drain water through an aquifer. Water tends to choose the easiest way through the system but different geological and morphological barriers act as flow restrictions. The number and characteristics of restrictions depends on the particular speleogenetic environment, which is a function of geological, geomorphological, climatological and hydrological settings. Such a variety and heterogeneity of underground systems has presented a challenge for human understanding for many centuries. Access to many underground passages, theoretical knowledge and recent methods (modeling, water pressure-resistant dataloggers, precise sensors etc. give us the opportunity to get better insight into the hydrodynamic aspect of caves. In our work we tried to approach underground hydrodynamics from both theoretical and practical points of view. We present some theoretical background of open surface and pressurized flow in underground rivers and present results of some possible scenarios. Moreover, two case studies from the Ljubljanica river basin are presented in more detail: the cave system between Planinsko polje and Ljubljansko barje, and the cave system between Bloško polje and Cerkniško polje. The approach and methodology in each case is somewhat different, as the aims were different at the beginning of exploration. However, they both deal with temporal and spatial hydrodynamics of underground waters. In the case of Bloško polje-Cerkniško polje system we also explain the feedback loop between hydrodynamics and Holocene speleogenesis.

  10. Hydrodynamics of the Dirac spectrum

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yizhuang, E-mail: yizhuang.liu@stonybrook.edu [Department of Physics and Astronomy, Stony Brook University, Stony Brook, NY 11794-3800 (United States); Warchoł, Piotr, E-mail: piotr.warchol@uj.edu.pl [M. Smoluchowski Institute of Physics, Jagiellonian University, PL-30348 Krakow (Poland); Zahed, Ismail, E-mail: ismail.zahed@stonybrook.edu [Department of Physics and Astronomy, Stony Brook University, Stony Brook, NY 11794-3800 (United States)

    2016-02-10

    We discuss a hydrodynamical description of the eigenvalues of the Dirac spectrum in even dimensions in the vacuum and in the large N (volume) limit. The linearized hydrodynamics supports sound waves. The hydrodynamical relaxation of the eigenvalues is captured by a hydrodynamical (tunneling) minimum configuration which follows from a pertinent form of Euler equation. The relaxation from a phase of unbroken chiral symmetry to a phase of broken chiral symmetry occurs over a time set by the speed of sound.

  11. Analysis of phthalate esters in soils near an electronics manufacturing facility and from a non-industrialized area by gas purge microsyringe extraction and gas chromatography.

    Science.gov (United States)

    Wu, Wei; Hu, Jia; Wang, Jinqi; Chen, Xuerong; Yao, Na; Tao, Jing; Zhou, Yi-Kai

    2015-03-01

    Here, a novel technique is described for the extraction and quantitative determination of six phthalate esters (PAEs) from soils by gas purge microsyringe extraction and gas chromatography. Recovery of PAEs ranged from 81.4% to 120.3%, and the relative standard deviation (n=6) ranged from 5.3% to 10.5%. Soil samples were collected from roadsides, farmlands, residential areas, and non-cultivated areas in a non-industrialized region, and from the same land-use types within 1 km of an electronics manufacturing facility (n=142). Total PAEs varied from 2.21 to 157.62 mg kg(-1) in non-industrialized areas and from 8.63 to 171.64 mg kg(-1) in the electronics manufacturing area. PAE concentrations in the non-industrialized area were highest in farmland, followed (in decreasing order) by roadsides, residential areas, and non-cultivated soil. In the electronics manufacturing area, PAE concentrations were highest in roadside soils, followed by residential areas, farmland, and non-cultivated soils. Concentrations of dimethyl phthalate (DMP), diethyl phthalate (DEP), and di-n-butyl phthalate (DnBP) differed significantly (P<0.01) between the industrial and non-industrialized areas. Principal component analysis indicated that the strongest explanatory factor was related to DMP and DnBP in non-industrialized soils and to butyl benzyl phthalate (BBP) and DMP in soils near the electronics manufacturing facility. Congener-specific analysis confirmed that diethylhexyl phthalate (DEHP) was a predictive indication both in the non-industrialized area (r(2)=0.944, P<0.01) and the industrialized area (r(2)=0.860, P<0.01). The higher PAE contents in soils near the electronics manufacturing facility are of concern, considering the large quantities of electronic wastes generated with ongoing industrialization.

  12. Chuaria circularis from the early Mesoproterozoic Suket Shale, Vindhyan Supergroup, India: Insights from light and electron microscopy and pyrolysis–gas chromatography

    Indian Academy of Sciences (India)

    Suryendu Dutta; Michael Steiner; Santanu Banerjee; Bernd-Dietrich Erdtmann; Silambuchelvan Jeevankumar; Ulrich Mann

    2006-02-01

    Chuaria circularis (Walcott 1899) from the Suket Shale of the Vindhyan Supergroup (central India) has been reinvestigated for its morphology and chemical composition using biostatistics,electron microscopy and pyrolysis –gas chromatography.Morphology and microscopic investigations provide little clues on the specific biological affinity of Chuaria as numerous preservational artifacts seem to be incorporated.On the contrary,the predominance of -aliphatic pyrolysates of presently studied Chuaria from India rather supports an algal affinity.Moreover,the reflectance of C. circularis can be used to obtain a comparative maturity parameter of the Precambrian sediments.The review of the age and geographical distribution of C. circularis constrains that this species cannot be considered as an index fossil for the Proterozoic time.

  13. Screening of priority pesticides in Ulva sp. seaweeds by selective pressurized solvent extraction before gas chromatography with electron capture detector analysis.

    Science.gov (United States)

    Pinto, M I; Micaelo, C; Vale, C; Sontag, G; Noronha, J P

    2014-11-01

    This work reports a fast and reliable analytical method for the screening of priority pesticides (PPs) in Ulva sp. seaweeds by gas chromatography with electron capture detection. Extraction and sample clean-up were performed in one single step by selective pressurized liquid extraction (SPLE). Several parameters affecting SPLE performance were optimized. Method performance was compared with standard Soxhlet extraction. Significant decrease of the time of analysis with better recoveries for a greater number of PPs was achieved by SPLE. Average recoveries ranged from 71 to 103% with RSD < 10%. Field application showed the presence of PP in the range of 3-11 ng g(-1) in seaweeds collected in a coastal lagoon after a long period of heavy rains. These results suggest that Ulva sp. seaweeds tend to accumulate PPs and have the potential to be used as early alert signals of aquatic pollution especially after rains and storm events.

  14. Ultra-performance liquid chromatography quadrupole time-of-flight MS for identification of electron beam from accelerator degradation products of aflatoxin B1.

    Science.gov (United States)

    Wang, Ruiqi; Liu, Ruijie; Chang, Ming; Jin, Qingzhe; Huang, Jianhua; Liu, Yuanfa; Wang, Xingguo

    2015-02-01

    Electron beam irradiation was proven to be a successful method in aflatoxin degradation in earlier researches. However, the exact nature of the result radiation products generated by the aflatoxins remains unknown. Based on ultra-performance liquid chromatography quadrupole time-of-flight mass spectrometry (UPLC-Q-TOF MS) analysis, the solution of aflatoxin B1 (AFB1) in acetonitrile irradiated by electron beam degraded to two kinds of major products. The doses employed were in the range of 0 (control) to 8.60 kGy. The absorbed doses were monitored with FWT-60-00 radio-chromic dosimeters. By using UPLC-Q-TOF MS, accurate masses and proposed molecular formula for the degradation products, 261.1233 m/z (C14H13O5) and 299.1104 m/z (C17H15O5), were obtained from low mass error and high matching properties. Structural formula for the radio-degradation products and the degradation pathways leading to the compounds were proposed, based on the molecular formula and MS-MS spectra. The results showed that electron beam (EB) irradiation is an effective method for degrading AFB1.

  15. Highly Selective Screening of Estrogenic Compounds in Consumer-Electronics Plastics by Liquid Chromatography in Parallel Combined with Nanofractionation-Bioactivity Detection and Mass Spectrometry.

    Science.gov (United States)

    Jonker, Willem; Ballesteros-Gómez, Ana; Hamers, Timo; Somsen, Govert W; Lamoree, Marja H; Kool, Jeroen

    2016-11-15

    The chemical safety of consumer products is an issue of emerging concern. Plastics are widely used, e.g. as casings of consumer electronics (TVs, computers, routers, etc.), which are present in houses and offices in continuously increasing numbers. In this study, we investigate the estrogenic activity of components of plastics coming from electronics' casings. A recently developed fractionation platform for effect-directed analysis (EDA) was used. This platform combines reversed-phase liquid chromatography in parallel with bioassay detection via nanofractionation and with online high-resolution time-of-flight mass spectrometry (TOFMS) for the identification of bioactives. Four out of eight of the analyzed plastics samples showed the presence of estrogenic compounds. Based on the MS results these were assigned to bisphenol A (BPA), 2,4-di-tert-butylphenol, and a possible bisphenol A analog. All samples contained flame retardants, but these did not show any estrogenicity. The observed BPA, however, could be an impurity of tetrabromo-BPA (TBBPA) or TBBPA-based flame retardants. Due to the plausible migration of additives from plastics into the environment, plastics from consumer electronics likely constitute a source of estrogenic compound contamination in the indoor environment.

  16. Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory; determination of organochlorine pesticides and polychlorinated biphenyls in bottom sediment by dual capillary-column gas chromatography with electron-capture detection

    Science.gov (United States)

    Foreman, William T.; Connor, Brooke F.; Furlong, Edward T.; Vaught, Deborah G.; Merten, Leslie M.

    1995-01-01

    A method for the determination of 30 individual organochlorine pesticides, total toxaphene, and total polychlorinated biphenyls (PCBs) in bottom sediment is described. The method isolates the pesticides and PCBs by solvent extraction with dichlorobenzene, removes inorganic sulfur, large naturally occurring molecules, and other unwanted interferences by gel permeation chromatography, and further cleans up and class fractionates the extract using adsorption chromatography. The com- pounds then are instrumentally determined using dual capillary-column gas chromatography with electron-capture detection. Reporting limits range from 1 to 5 micrograms per kilogram for 30 individual pesticides, 50 micrograms per kilogram for total PCBs, and 200 micrograms per kilogram for total toxaphene. The method also is designed to allow the simultaneous isolation of 79 other semivolatile organic compounds from the sediment, which are separately quantified using gas chromatography with mass spectrometric detection. The method was developed in support of the U.S. Geological Survey's National Water-Quality Assessment program.

  17. Scalability of Hydrodynamic Simulations

    CERN Document Server

    Tang, Shikui

    2009-01-01

    Many hydrodynamic processes can be studied in a way that is scalable over a vastly relevant physical parameter space. We systematically examine this scalability, which has so far only briefly discussed in astrophysical literature. We show how the scalability is limited by various constraints imposed by physical processes and initial conditions. Using supernova remnants in different environments and evolutionary phases as application examples, we demonstrate the use of the scaling as a powerful tool to explore the interdependence among relevant parameters, based on a minimum set of simulations. In particular, we devise a scaling scheme that can be used to adaptively generate numerous seed remnants and plant them into 3D hydrodynamic simulations of the supernova-dominated interstellar medium.

  18. Relativistic Hydrodynamics with Wavelets

    CERN Document Server

    DeBuhr, Jackson; Anderson, Matthew; Neilsen, David; Hirschmann, Eric W

    2015-01-01

    Methods to solve the relativistic hydrodynamic equations are a key computational kernel in a large number of astrophysics simulations and are crucial to understanding the electromagnetic signals that originate from the merger of astrophysical compact objects. Because of the many physical length scales present when simulating such mergers, these methods must be highly adaptive and capable of automatically resolving numerous localized features and instabilities that emerge throughout the computational domain across many temporal scales. While this has been historically accomplished with adaptive mesh refinement (AMR) based methods, alternatives based on wavelet bases and the wavelet transformation have recently achieved significant success in adaptive representation for advanced engineering applications. This work presents a new method for the integration of the relativistic hydrodynamic equations using iterated interpolating wavelets and introduces a highly adaptive implementation for multidimensional simulati...

  19. Burst Mechanisms in Hydrodynamics

    CERN Document Server

    Knobloch, E

    1999-01-01

    Different mechanisms believed to be responsible for the generation of bursts in hydrodynamical systems are reviewed and a new mechanism capable of generating regular or irregular bursts of large dynamic range near threshold is described. The new mechanism is present in the interaction between oscillatory modes of odd and even parity in systems of large but finite aspect ratio, and provides an explanation for the bursting behavior observed in binary fluid convection. Additional applications of the new mechanism are proposed.

  20. Relativistic cosmological hydrodynamics

    CERN Document Server

    Hwang, J

    1997-01-01

    We investigate the relativistic cosmological hydrodynamic perturbations. We present the general large scale solutions of the perturbation variables valid for the general sign of three space curvature, the cosmological constant, and generally evolving background equation of state. The large scale evolution is characterized by a conserved gauge invariant quantity which is the same as a perturbed potential (or three-space curvature) in the comoving gauge.

  1. Hydrodynamics of insect spermatozoa

    Science.gov (United States)

    Pak, On Shun; Lauga, Eric

    2010-11-01

    Microorganism motility plays important roles in many biological processes including reproduction. Many microorganisms propel themselves by propagating traveling waves along their flagella. Depending on the species, propagation of planar waves (e.g. Ceratium) and helical waves (e.g. Trichomonas) were observed in eukaryotic flagellar motion, and hydrodynamic models for both were proposed in the past. However, the motility of insect spermatozoa remains largely unexplored. An interesting morphological feature of such cells, first observed in Tenebrio molitor and Bacillus rossius, is the double helical deformation pattern along the flagella, which is characterized by the presence of two superimposed helical flagellar waves (one with a large amplitude and low frequency, and the other with a small amplitude and high frequency). Here we present the first hydrodynamic investigation of the locomotion of insect spermatozoa. The swimming kinematics, trajectories and hydrodynamic efficiency of the swimmer are computed based on the prescribed double helical deformation pattern. We then compare our theoretical predictions with experimental measurements, and explore the dependence of the swimming performance on the geometric and dynamical parameters.

  2. Hydrodynamics of fossil fishes.

    Science.gov (United States)

    Fletcher, Thomas; Altringham, John; Peakall, Jeffrey; Wignall, Paul; Dorrell, Robert

    2014-08-07

    From their earliest origins, fishes have developed a suite of adaptations for locomotion in water, which determine performance and ultimately fitness. Even without data from behaviour, soft tissue and extant relatives, it is possible to infer a wealth of palaeobiological and palaeoecological information. As in extant species, aspects of gross morphology such as streamlining, fin position and tail type are optimized even in the earliest fishes, indicating similar life strategies have been present throughout their evolutionary history. As hydrodynamical studies become more sophisticated, increasingly complex fluid movement can be modelled, including vortex formation and boundary layer control. Drag-reducing riblets ornamenting the scales of fast-moving sharks have been subjected to particularly intense research, but this has not been extended to extinct forms. Riblets are a convergent adaptation seen in many Palaeozoic fishes, and probably served a similar hydrodynamic purpose. Conversely, structures which appear to increase skin friction may act as turbulisors, reducing overall drag while serving a protective function. Here, we examine the diverse adaptions that contribute to drag reduction in modern fishes and review the few attempts to elucidate the hydrodynamics of extinct forms.

  3. Neuere Chromatographie

    Science.gov (United States)

    Hostettmann, K.

    1983-04-01

    Besides high-performance liquid chromatography (HPLC) which is now a well-established and currently used technique, several emerging methods for the isolation and separation of natural products are receiving considerable attention. Centrifugal thin-layer chromatography is a very rapid technique, but limited in resolution. Of special interest are the recently developed support-free liquid-liquid chromatography methods such as droplet counter-current chromatography (DCCC) and rotation locular counter-current chromatography (RLCC). This latter method was applied to the separation of the enantiomers of (±)-norephedrine.

  4. Analysis of phthalate esters in soils near an electronics manufacturing facility and from a non-industrialized area by gas purge microsyringe extraction and gas chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Wei [MOE Key Laboratory of Environment and Health, Institute of Environmental Medicine, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan, Hubei (China); Hu, Jia [Suzhou Center for Disease Prevention and Control, Suzhou, Jiangsu (China); Wang, Jinqi; Chen, Xuerong; Yao, Na [MOE Key Laboratory of Environment and Health, Institute of Environmental Medicine, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan, Hubei (China); Tao, Jing, E-mail: jingtao1982@126.com [MOE Key Laboratory of Environment and Health, Institute of Environmental Medicine, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan, Hubei (China); Zhou, Yi-Kai, E-mail: zhouyk@mails.tjmu.edu.cn [MOE Key Laboratory of Environment and Health, Institute of Environmental Medicine, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan, Hubei (China)

    2015-03-01

    Here, a novel technique is described for the extraction and quantitative determination of six phthalate esters (PAEs) from soils by gas purge microsyringe extraction and gas chromatography. Recovery of PAEs ranged from 81.4% to 120.3%, and the relative standard deviation (n = 6) ranged from 5.3% to 10.5%. Soil samples were collected from roadsides, farmlands, residential areas, and non-cultivated areas in a non-industrialized region, and from the same land-use types within 1 km of an electronics manufacturing facility (n = 142). Total PAEs varied from 2.21 to 157.62 mg kg{sup −1} in non-industrialized areas and from 8.63 to 171.64 mg kg{sup −1} in the electronics manufacturing area. PAE concentrations in the non-industrialized area were highest in farmland, followed (in decreasing order) by roadsides, residential areas, and non-cultivated soil. In the electronics manufacturing area, PAE concentrations were highest in roadside soils, followed by residential areas, farmland, and non-cultivated soils. Concentrations of dimethyl phthalate (DMP), diethyl phthalate (DEP), and di-n-butyl phthalate (DnBP) differed significantly (P < 0.01) between the industrial and non-industrialized areas. Principal component analysis indicated that the strongest explanatory factor was related to DMP and DnBP in non-industrialized soils and to butyl benzyl phthalate (BBP) and DMP in soils near the electronics manufacturing facility. Congener-specific analysis confirmed that diethylhexyl phthalate (DEHP) was a predictive indication both in the non-industrialized area (r{sup 2} = 0.944, P < 0.01) and the industrialized area (r{sup 2} = 0.860, P < 0.01). The higher PAE contents in soils near the electronics manufacturing facility are of concern, considering the large quantities of electronic wastes generated with ongoing industrialization. - Highlights: • A new method for determining phthalate esters in soil samples was developed. • Investigate six phthalates near an industry and a

  5. Separation of seventeen 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins and dibenzofurans and 12 dioxin-like polychlorinated biphenyls by comprehensive two-dimensional gas chromatography with electron-capture detection

    NARCIS (Netherlands)

    Korytar, P.; Danielsson, C.; Leonards, P.E.G.; Haglund, P.; Boer, de J.; Brinkman, U.A.Th.

    2004-01-01

    Comprehensive two-dimensional gas chromatography (GCxGC) with electron-capture detection (ECD) has been optimized for the separation of seventeen 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins and dibenzofurans and 12 dioxin-like polychlorinated biphenyls, with emphasis on the selection of th

  6. Structural determination of zinc dithiophosphates in lubricating oils by gas chromatography-mass spectrometry with electron impact and electron-capture negative ion chemical ionization.

    Science.gov (United States)

    Becchi, M; Perret, F; Carraze, B; Beziau, J F; Michel, J P

    2001-01-05

    Pentafluorobenzyl ester derivatives were used to identify zinc dialkyldithiophosphates and diaryldithiophosphates antiwear engine oil additives by GC-electron impact ionization (EI) MS and GC-electron-capture negative ion chemical ionization (ECNCI) MS analysis. GC-EI-MS of the dialkyldithiophosphate-pentafluorobenzyl derivatives afforded characteristic fragment ions corresponding to the cleavage of one and two alkyl radicals. In most cases, information was only obtained on one alkyl chain. Additional and complete information was obtained with retention time indices using synthetic derivatives and with GC-ECNCI-MS analysis. ECNCI afforded characteristic dithiophosphate anions which allowed the determination of the total number of carbon atoms in the alkyl radicals. The diastereoisomer mixtures of 2-hydroxy-sec.-alkyl radicals were completely separated on GC analysis.

  7. Comprehensive two-dimensional gas chromatography - time-of-flight mass spectrometry and simultaneous electron capture detection/nitrogen phosphorous detection for incense analysis

    Science.gov (United States)

    Tran, Tin C.; Marriott, Philip J.

    This study reports comprehensive two-dimensional gas chromatography hyphenated to time-of-flight mass spectrometry detection (GC × GC/TOFMS) for characterisation and identification of components generated by four different types of powdered incense headspace (H/S) and incense smoke. GC × GC/TOFMS allowed simultaneous separation and identification of compounds emitted into the atmosphere as a result of combustion of incense powder. The smoke stream comprised compounds originating from the incense powder, and combustion products such as saturated and unsaturated hydrocarbons, essential oil type compounds, nitromusks, fatty acid methyl esters (FAMEs), polycyclic aromatic hydrocarbons (PAHs, which possibly include oxygenated and nitrated PAH), N-heterocyclics, pyrans and furans, which were detected and tentatively identified by GC × GC/TOFMS. GC × GC-electron capture detector/nitrogen phosphorous detector (ECD/NPD) potentially offers the prospect of providing selective chemical compositional information of incense powder and smoke, such as nitrogen-containing (N-containing) and halogenated compounds. Results of GC×GC-ECD/NPD showed that both incense powder and smoke generated emission of N-containing and halogenated compounds. A significant number of halogenated and N-containing compounds were emitted during the incomplete combustion of incense. However, one further objective of this paper is to demonstrate the capacity of comprehensive two-dimensional gas chromatography coupled to specific and/or selective detectors such as those used in this study (GC × GC-ECD/NPD) for the detection of particular classes of compounds such as N-containing and halogenated compounds at trace level concentrations in complex smoke samples.

  8. Dispersive liquid-liquid microextraction method based on solidification of floating organic drop combined with gas chromatography with electron-capture or mass spectrometry detection.

    Science.gov (United States)

    Leong, Mei-I; Huang, Shang-Da

    2008-11-21

    A simple dispersive liquid-liquid microextraction (DLLME) method based on solidification of a floating organic drop (DLLME-SFO) technique combined with gas chromatography/electron-capture detection (GC/ECD) or gas chromatography/mass spectrometry (GC/MS) has been developed. The proposed method is simple, low in cost, and of high precision. It overcomes the most important problem in DLLME, the high-toxic solvent used. Halogenated organic compounds (HOCs) in water samples were determined as the model compounds. The parameters optimized for the DLLME-SFO technique were as follows: A mixture of 0.5 mL acetone, containing 10 microL 2-dodecanol (2-DD-OH), was rapidly injected by syringe into the 5 mL water sample. After centrifugation, the fine 2-DD-OH droplets (8+/-0.5 microL) were floated at the top of the screwcap test tube. The test tube was then cooled in an ice bath. After 5 min the 2-DD-OH solvent had solidified and was then transferred into a conical vial; it melted quickly at room temperature and 3 microL (for GC/ECD) or 2 microL (for GC/MS) of it was injected into a gas chromatograph for analysis. The limit of detection (LOD) for this technique was 0.005-0.05microgL(-1) for GC/ECD and was 0.005-0.047 microgL(-1) for GC/MS, respectively. The linear range of the calibration curve of DLLME-SFO was from 0.01 to 500 microgL(-1) with a coefficient of estimation (r2)>0.996 for GC/ECD and was from 0.02 to 500 microgL(-1) with a coefficient of estimation (r2)>0.996 for GC/MS.

  9. Foundations of radiation hydrodynamics

    CERN Document Server

    Mihalas, Dimitri

    1999-01-01

    Radiation hydrodynamics is a broad subject that cuts across many disciplines in physics and astronomy: fluid dynamics, thermodynamics, statistical mechanics, kinetic theory, and radiative transfer, among others. The theory developed in this book by two specialists in the field can be applied to the study of such diverse astrophysical phenomena as stellar winds, supernova explosions, and the initial phases of cosmic expansion, as well as the physics of laser fusion and reentry vehicles. As such, it provides students with the basic tools for research on radiating flows.Largely self-contained,

  10. Calculation of the gain of a self-launched high-density free-electron laser by using a newly confirmed law stated as the impossibility of free-electron net stimulated radiation and modal analysis based on plasma hydrodynamics

    Science.gov (United States)

    Kim, S. H.

    2017-05-01

    We reason based on the concept of stationary plasma fluctuation that in the free-electron laser (FEL), the Coulomb force from the surrounding electrons and the Ampérian force arising from the beam current do not disrupt the density-deviation mode driven by the laser field in cooperation with the magnetic wiggler. We adopt the synchronization principle that in the state of a stationary plasma density-wave and laser wave, all electrons arriving at the same position can emit laser photons all together only at t = NT + t o , where N is an integer and T is the laser period. We find that in the FEL, the incident laser radiation acts as a dummy field in net stimulated radiation. Using these findings and noticing a previously-recognized concept that the radiation power from an electron is given by Δ E/T, where Δ E is the amplitude of the net work done by the electron during T [1], we derive the laser gain of a self-launched FEL. The thusly derived gain is in excellent agreement with the measured gain.

  11. Molecular hydrodynamics from memory kernels

    CERN Document Server

    Lesnicki, Dominika; Carof, Antoine; Rotenberg, Benjamin

    2016-01-01

    The memory kernel for a tagged particle in a fluid, computed from molecular dynamics simulations, decays algebraically as $t^{-3/2}$. We show how the hydrodynamic Basset-Boussinesq force naturally emerges from this long-time tail and generalize the concept of hydrodynamic added mass. This mass term is negative in the present case of a molecular solute, at odds with incompressible hydrodynamics predictions. We finally discuss the various contributions to the friction, the associated time scales and the cross-over between the molecular and hydrodynamic regimes upon increasing the solute radius.

  12. Hydrodynamics of pronuclear migration

    Science.gov (United States)

    Nazockdast, Ehssan; Needleman, Daniel; Shelley, Michael

    2014-11-01

    Microtubule (MT) filaments play a key role in many processes involved in cell devision including spindle formation, chromosome segregation, and pronuclear positioning. We present a direct numerical technique to simulate MT dynamics in such processes. Our method includes hydrodynamically mediated interactions between MTs and other cytoskeletal objects, using singularity methods for Stokes flow. Long-ranged many-body hydrodynamic interactions are computed using a highly efficient and scalable fast multipole method, enabling the simulation of thousands of MTs. Our simulation method also takes into account the flexibility of MTs using Euler-Bernoulli beam theory as well as their dynamic instability. Using this technique, we simulate pronuclear migration in single-celled Caenorhabditis elegans embryos. Two different positioning mechanisms, based on the interactions of MTs with the motor proteins and the cell cortex, are explored: cytoplasmic pulling and cortical pushing. We find that although the pronuclear complex migrates towards the center of the cell in both models, the generated cytoplasmic flows are fundamentally different. This suggest that cytoplasmic flow visualization during pronuclear migration can be utilized to differentiate between the two mechanisms.

  13. Boosting the Detection Potential of Liquid Chromatography-Electron Ionization Mass Spectrometry Using a Ceramic Coated Ion Source

    Science.gov (United States)

    Magrini, Laura; Famiglini, Giorgio; Palma, Pierangela; Termopoli, Veronica; Cappiello, Achille

    2016-01-01

    Detection of target and non-target substances and their characterization in complex samples is a challenging task. Here we demonstrate that coating the electron ionization (EI) ion source of an LC-MS system with a sol-gel ceramic film can drastically improve the detection of high-molecular weight and high-boiling analytes. A new ion source coated with a ceramic material was developed and tested with a mixture of polycyclic aromatic hydrocarbons (PAH) with an increasing number of rings. Comparison of the results obtained with those for an uncoated stainless steel (SS) ion source shows a dramatic improvement in the MS signals, with a nearly 40-fold increase of the signal-to-noise ratio. We also demonstrate the ability of the new system to produce excellent chromatographic profiles for hard-to-detect hormones.

  14. Hyperbolic metamaterial lens with hydrodynamic nonlocal response

    DEFF Research Database (Denmark)

    Yan, Wei; Mortensen, N. Asger; Wubs, Martijn

    2013-01-01

    in the local-response approximation and in the hydrodynamic Drude model can differ considerably. In particular, the optimal frequency for imaging in the nonlocal theory is blueshifted with respect to that in the local theory. Thus, to detect whether nonlocal response is at work in a hyperbolic metamaterial, we......We investigate the effects of hydrodynamic nonlocal response in hyperbolic metamaterials (HMMs), focusing on the experimentally realizable parameter regime where unit cells are much smaller than an optical wavelength but much larger than the wavelengths of the longitudinal pressure waves...... of the free-electron plasma in the metal constituents. We derive the nonlocal corrections to the effective material parameters analytically, and illustrate the noticeable nonlocal effects on the dispersion curves numerically. As an application, we find that the focusing characteristics of a HMM lens...

  15. Hyperbolic metamaterial lens with hydrodynamic nonlocal response.

    Science.gov (United States)

    Yan, Wei; Mortensen, N Asger; Wubs, Martijn

    2013-06-17

    We investigate the effects of hydrodynamic nonlocal response in hyperbolic metamaterials (HMMs), focusing on the experimentally realizable parameter regime where unit cells are much smaller than an optical wavelength but much larger than the wavelengths of the longitudinal pressure waves of the free-electron plasma in the metal constituents. We derive the nonlocal corrections to the effective material parameters analytically, and illustrate the noticeable nonlocal effects on the dispersion curves numerically. As an application, we find that the focusing characteristics of a HMM lens in the local-response approximation and in the hydrodynamic Drude model can differ considerably. In particular, the optimal frequency for imaging in the nonlocal theory is blueshifted with respect to that in the local theory. Thus, to detect whether nonlocal response is at work in a hyperbolic metamaterial, we propose to measure the near-field distribution of a hyperbolic metamaterial lens.

  16. Comprehensive gas chromatography-electron ionisation mass spectrometric analysis of fatty acids and sterols using sequential one-pot silylation: quantification and isotopologue analysis.

    Science.gov (United States)

    Kloos, Dick-Paul; Gay, Emmanuel; Lingeman, Henk; Bracher, Franz; Müller, Christoph; Mayboroda, Oleg A; Deelder, André M; Niessen, Wilfried M A; Giera, Martin

    2014-07-15

    Fatty acids and sterol lipids play crucial roles in several biological processes and several biological facts underline the interconnection between these lipid classes. Therefore, it is of interest to develop a comprehensive method analysing both classes in the form of their most favourable derivatives suitable for quantification and isotopologue analysis. Lipids were derivatised by a sequential one-pot procedure using N-tert-butyldimethylsilyl-N-methyltrifluoroacetamide (MtBSTFA) and N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA). No clean-up or concentration steps were necessary. The prepared samples were directly available for gas chromatography-electron ionisation mass spectrometric (GC-EI-MS) analysis on a standard column. For quantification, the SIM mode was used and for isotopologue analysis scheduled scan mode was applied. Development of a sequential one-pot derivatisation for GC-EI-MS allowing comprehensive analysis of fatty acids and sterols as their most favourable derivatives. Validation carried out using human plasma, comparison with certified NIST plasma. LLOQ of usually 3.3 ng/mL achieved. Isotopologue analysis of 2-[(13)C]-acetate incorporation in HL-60 cells proving feasibility of method. The presented method successfully combines two consecutive silylation reactions in one pot, enabling the analysis of both fatty acids and sterols in a comprehensive analytical method. The method has great potential for the quantification of lipids as well as the comprehensive study of both biochemical pathways, using [(13)C]-flux analysis. Copyright © 2014 John Wiley & Sons, Ltd.

  17. Dispersive Liquid-Liquid Microextraction Based on Solidification of Floating Organic Drop Followed by Gas Chromatography-Electron Capture Detector for Determination of Some Pesticides in Water Samples

    Directory of Open Access Journals (Sweden)

    Mostafa Bashiri Juybari

    2011-01-01

    Full Text Available In this study dispersive liquid-liquid microextraction based on solidification of floating organic drop (DLLME-SFO followed by gas chromatography-electron capture detection (GC-ECD was developed for determination of some pesticides in the water samples. Some important parameters, such as type and volumes of extraction and disperser solvent and salt effect on the extraction recovery of analytes from aqueous solution were investigated. Under the optimum conditions (extraction solvent: 1-undecanol, 15.0 μL; disperser solvent: acetone, 1.0 mL, and without salt addition, the preconcentration factors were obtained ranged from 802 to 915 for analytes. The linear ranges were from 0.05 to 100 μg L−1, and detection limits ranged from 0.05 to 0.008 μg L−1. The relative standard deviations (RSDs%, =5 were between 3.2% and 6.7%. The proposed method was successfully applied to the determination of target analytes in the tap, sea, and river water samples, and satisfactory recoveries were obtained.

  18. Use of green coating (cork) in solid-phase microextraction for the determination of organochlorine pesticides in water by gas chromatography-electron capture detection.

    Science.gov (United States)

    Dias, Adriana Neves; Simão, Vanessa; Merib, Josias; Carasek, Eduardo

    2015-03-01

    A novel method for the determination of organochlorine pesticides in water samples with extraction using cork fiber and analysis by gas chromatography with electron capture detector was developed. Also, the procedure to extract these pesticides with DVB/Car/PDMS fiber was optimized. The optimization of the variables involved in the extraction of organochlorine pesticides using the aforementioned fibers was carried out by multivariate design. The optimum extraction conditions were sample temperature 75 °C, extraction time 60 min and sodium chloride concentration 10% for the cork fiber and sample temperature 50 °C and extraction time 60 min (without salt) for the DVB/Car/PDMS fiber. The quantification limits for the two fibers varied between 1.0 and 10.0 ng L(-1). The linear correlation coefficients were >0.98 for both fibers. The method applied with the use of the cork fiber provided recovery values between 60.3 and 112.7 and RSD≤25.5 (n=3). The extraction efficiency values for the cork and DVB/Car/PDMS fibers were similar. The results show that cork is a promising alternative as a coating for SPME.

  19. Application of the standard addition method for the determination of acrylamide in heat-processed starchy foods by gas chromatography with electron capture detector.

    Science.gov (United States)

    Zhu, Yonghong; Li, Genrong; Duan, Yunpeng; Chen, Shiqi; Zhang, Chun; Li, Yanfei

    2008-08-15

    A gas chromatography electron capture detector (GC-ECD) using the standard addition method was developed for the determination of acrylamide in heat-processed foods. The method entails extraction of acrylamide with water, filtration, defatting with n-hexane, derivatization with hydrobromic acid and saturated bromine-water, and liquid-liquid extraction with ethyl acetate. The sample pretreatment required no SPE clean-up and concentration steps prior to injection. The final extract was analyzed by GC-ECD. The chromatographic analysis was performed on polar columns, e.g. Supelcowax-10 capillary column, and good retention and peak response of the analyte were achieved under the optimal conditions. The qualification of the analyte was by identifying the peak with same retention time as standard compound 2,3-DBPA and confirmed by GC-MS. GC-MS analysis confirmed that 2,3-DBPA was converted to 2-BPA nearly completely on the polar capillary column, whether or not treated with triethylamine. A four-point standard addition protocol was used to quantify acrylamide in food samples. The limit of detection (LOD) was estimated to be 0.6μg/kg on the basis of ECD technique. Validation and quantification results demonstrated that the method should be regarded as a low-cost, convenient, and reliable alternative for conventional investigation of acrylamide.

  20. The Verification of the Usefulness of Electronic Nose Based on Ultra-Fast Gas Chromatography and Four Different Chemometric Methods for Rapid Analysis of Spirit Beverages.

    Science.gov (United States)

    Wiśniewska, Paulina; Śliwińska, Magdalena; Namieśnik, Jacek; Wardencki, Waldemar; Dymerski, Tomasz

    2016-01-01

    Spirit beverages are a diverse group of foodstuffs. They are very often counterfeited which cause the appearance of low quality products or wrongly labelled products on the market. It is important to find a proper quality control and botanical origin method enabling the same time preliminary check of the composition of investigated samples, which was the main goal of this work. For this purpose, the usefulness of electronic nose based on ultra-fast gas chromatography (fast GC e-nose) was verified. A set of 24 samples of raw spirits, 33 samples of vodkas, and 8 samples of whisky were analysed by fast GC e-nose. Four data analysis methods were used. The PCA was applied for the visualization of dataset, observation of the variation inside groups of samples, and selection of variables for the other three statistical methods. The SQC method was utilized to compare the quality of the samples. Both the DFA and SIMCA data analysis methods were used for discrimination of vodka, whisky, and spirits samples. The fast GC e-nose combined with four statistical methods can be used for rapid discrimination of raw spirits, vodkas, and whisky and in the same for preliminary determination of the composition of investigated samples.

  1. The Verification of the Usefulness of Electronic Nose Based on Ultra-Fast Gas Chromatography and Four Different Chemometric Methods for Rapid Analysis of Spirit Beverages

    Directory of Open Access Journals (Sweden)

    Paulina Wiśniewska

    2016-01-01

    Full Text Available Spirit beverages are a diverse group of foodstuffs. They are very often counterfeited which cause the appearance of low quality products or wrongly labelled products on the market. It is important to find a proper quality control and botanical origin method enabling the same time preliminary check of the composition of investigated samples, which was the main goal of this work. For this purpose, the usefulness of electronic nose based on ultra-fast gas chromatography (fast GC e-nose was verified. A set of 24 samples of raw spirits, 33 samples of vodkas, and 8 samples of whisky were analysed by fast GC e-nose. Four data analysis methods were used. The PCA was applied for the visualization of dataset, observation of the variation inside groups of samples, and selection of variables for the other three statistical methods. The SQC method was utilized to compare the quality of the samples. Both the DFA and SIMCA data analysis methods were used for discrimination of vodka, whisky, and spirits samples. The fast GC e-nose combined with four statistical methods can be used for rapid discrimination of raw spirits, vodkas, and whisky and in the same for preliminary determination of the composition of investigated samples.

  2. Group-selective enrichment and determination of pyrethroid insecticides in aquaculture seawater via molecularly imprinted solid phase extraction coupled with gas chromatography-electron capture detection.

    Science.gov (United States)

    Shi, Xizhi; Liu, Jinghua; Sun, Aili; Li, Dexiang; Chen, Jiong

    2012-03-02

    Two types of molecularly imprinted polymers (MIPs) for the simultaneous determination of six pyrethroid insecticides have been developed using deltamethrin (D-MIPs) and cypermethrin (C-MIPs) as template molecules. A comparison of the performance of D-MIPs, C-MIPs, and the corresponding non-imprinted polymers (NIPs) were conducted. Stronger group-selective interactions between the C-MIPs and the six pyrethroid insecticides were achieved. The MISPE method based on the C-MIPs displayed higher extraction recoveries (86.4-96.0%) with RSD values ranging from 2.4 to 7.8% for the six pyrethroid insecticides in aquaculture seawater. After the C-MIP cartridge procedure, the limits of detection and quantification for fenvalerate, deltamethrin, cypermethrin, cyfluthrin, and bifenthrin were in the 16.6-37.0 and 55.3-109.1 ng L⁻¹ ranges, respectively, and 0.68 and 2.26 μg L⁻¹ for phenothrin, respectively. The proposed MISPE method coupled with gas chromatography-electron capture detection was successfully used for the determination of the six pyrethroid insecticides in aquaculture seawater.

  3. Determination of trihalomethanes in soil matrices by simplified quick, easy, cheap, effective, rugged and safe extraction and fast gas chromatography with electron capture detection.

    Science.gov (United States)

    Herrero Martín, Sara; García Pinto, Carmelo; Pérez Pavón, José Luis; Moreno Cordero, Bernardo

    2010-07-23

    A method based on QuEChERS extraction is proposed for the determination of trihalomethanes (chloroform, bromodichloromethane, dibromocloromethane and bromoform) in soil samples. The new version of QuEChERS adapted to soil samples consists of liquid extraction with ethyl acetate, the addition of water to moisten the samples, salting-out partitioning of the water with anhydrous MgSO4, and direct injection of the organic extract, obtained after the centrifugation step, into the gas chromatograph. This simplified extraction procedure maintains the advantages of the original method and avoids some steps, making the final procedure simpler, faster, and cheaper, with the consequent reduction in errors associated with sample manipulation. The experimental conditions of the analytical method, based on fast gas chromatography (FGC) and micro-electron capture detection (microECD), were optimized. The column and oven program used allowed fast separation of the compounds in less than 4 min and the total analysis cycle time was as short as 10 min. The existence of a matrix effect was checked and the analytical conditions of the method were studied in a fortified garden soil sample. The highly sensitive and selective detector used afforded to detection limits in the order of ng/kg for the target compounds. To validate the proposed method two certified reference materials (CRMs) were analyzed.

  4. Measurement of polychlorinated biphenyls in solid waste such as transformer insulation paper by supercritical fluid extraction and gas chromatography electron capture detection.

    Science.gov (United States)

    Chikushi, Hiroaki; Fujii, Yuka; Toda, Kei

    2012-09-21

    In this work, a method for measuring polychlorinated biphenyls (PCBs) in contaminated solid waste was investigated. This waste includes paper that is used in electric transformers to insulate electric components. The PCBs in paper sample were extracted by supercritical fluid extraction and analyzed by gas chromatography-electron capture detection. The recoveries with this method (84-101%) were much higher than those with conventional water extraction (0.08-14%), and were comparable to those with conventional organic solvent extraction. Limit of detection was 0.0074 mg kg(-1) and measurable up to 2.5 mg kg(-1) for 0.5 g of paper sample. Data for real insulation paper by the proposed method agreed well with those by the conventional organic solvent extraction. Extraction from wood and concrete was also investigated and good performance was obtained as well as for paper samples. The supercritical fluid extraction is simpler, faster, and greener than conventional organic solvent extraction. Copyright © 2012 Elsevier B.V. All rights reserved.

  5. Determination of catechins and caffeine in proposed green tea standard reference materials by liquid chromatography-particle beam/electron ionization mass spectrometry (LC-PB/EIMS).

    Science.gov (United States)

    Castro, Joaudimir; Pregibon, Tara; Chumanov, Kristina; Marcus, R Kenneth

    2010-10-15

    Presented here is the quantitative analysis of green tea NIST standard reference materials (SRMs) via liquid chromatography-particle beam/electron ionization mass spectrometry (LC-PB/EIMS). Three different NIST green tea standard reference materials (SRM 3254 Camellia sinesis Leaves, SRM 3255 C. sinesis Extract and SRM 3256 Green Tea-containing Oral Dosage Form) are characterized for the content of caffeine and a series of catechin species (gallic acid, catechin, epicatechin, epigallocatechin, epicatechin gallate and epigallocatechin gallate (EGCG)). The absolute limits of detection for caffeine and the catechin species were determined to be on the nanogram level. A reversed-phase chromatographic separation of the green tea reference materials was carried out on a commercial C(18) column using a gradient of water (containing 0.1% TFA) and 2:1 methanol:acetonitrile (containing 0.1%TFA) at 0.9mLmin(-1) and an analysis time of 50min. Quantification of caffeine and the catechin species was carried out using the standard addition and internal standard methods, with the latter providing appreciable improvements in precision and recovery.

  6. Determination of alkyltrimethylammonium surfactants in hair conditioners and fabric softeners by gas chromatography-mass spectrometry with electron-impact and chemical ionization.

    Science.gov (United States)

    Tsai, Pei-Chuan; Ding, Wang-Hsien

    2004-02-20

    The commercial hair conditioners and fabric softeners were analyzed for the content of alkyltrimethylammonium compounds (ATMACs) by gas chromatography-mass spectrometry (GC-MS) with electron impact (EI) and low-pressure positive-ion chemical ionization (PICI) modes. The method involves mixed diluted samples (adjust pH to 10.0) with potassium iodide to enhance the extraction of iodide-ATMA+ ion pairs by direct liquid-liquid extraction. The iodide-ATMA+ pairs were then demethylated to their corresponding nonionic alkyldimethylamines (ADMAs) by thermal decomposition in a GC injection-port. A high abundance of ADMAs was detected at the temperature above 300 degrees C in the GC injection-port. The enhanced selectivity of quasi-molecular ion chromatograms of C12-C18-ADMA, obtained using methanol PICI-MS enables ADMAs to be identified. The accuracy and precision of the method was validated and was successfully applied to determine contents of ATMAC in commercial hair conditioners and fabric softeners. The contents of total measured ATMAC ranged from 0.4 to 6.9% for hair conditioners, and from 3.3 to 4.6% for fabric softeners.

  7. The simultaneous separation and determination of chloropropanols in soy sauce and other flavoring with gas chromatography-mass spectrometry in negative chemical and electron impact ionization modes.

    Science.gov (United States)

    Xu, Xiaomin; Ren, Yiping; Wu, Pinggu; Han, Jianlong; Shen, Xianghong

    2006-02-01

    Both gas chromatography-mass spectrometry in electron ionization (GC-MS-EI) and negative chemical ionization (GC-MS-NCI) modes are reported in this paper for the simultaneous determination of 1,3-dichloropropan-2-ol (1,3-DCP), 2,3-dichloropropan-1-ol (2,3-DCP), 3-chloropropane-1,2-diol (3-MCPD) and 2-chloropropane-1,3-diol (2-MCPD) in soy sauce and other flavoring. D(5)-3-MCPD (for 3-MCPD and 2-MCPD) and d(5)-1,3-DCP (for 1,3-DCP and 2,3-DCP) were used as the deuterium isotopic labelled internal standards. The feasibility of using heptafluorobutyric anhydride modified with triethylamine (HFBA-Et(3)N) as a new derivatization reagent to replace heptafluorobutyrylimidazole (HFBI) is proposed. Liquid/liquid extraction with hexane was introduced for high lipid content samples. A small survey was carried out of soy sauces (103 samples) and instant noodles (45 samples) and the applicability of GC-MS-NCI and GC-MS-EI was assessed in these different matrices.

  8. Solid phase extraction with silicon dioxide microsphere adsorbents in combination with gas chromatography-electron capture detection for the determination of DDT and its metabolites in water samples.

    Science.gov (United States)

    Zhou, Qingxiang; Wu, Wei; Xie, Guohong

    2013-01-01

    The goal of the present study was to investigate the feasibility of silicon dioxide (SiO(2)) microspheres without special modification to enrich dichlorodiphenyltrichloroethane (DDT) and its main metabolites, p,p'-dichlorodiphenyl-2,2-dichloroethylene (p,p'-DDD) and p,p'-dichlorodiphenyldichloroethylene (DDE) in combination with gas chromatography-electron-capture detection. The experimental results indicated that an excellent linear relationship between the recoveries and the concentrations of DDT and its main metabolites was obtained in the range of 0.2-30 ng mL(-1) and the correlation coefficients were in the range of 99.96-99.99%. The detection limits based on the ratio of signal to the baseline noise (S/N = 3) were 2.2, 2.9, 3.8 and 4.1 ng L(-1) for p,p'-DDD, p,p'-DDT, o,p'-DDT, and p,p'-DDE, respectively. The precisions of the proposed method were all below 10% (n = 6). Four real water samples were utilized for validation of the proposed method, and satisfactory spiked recoveries in the range of 72.4-112.9% were achieved. These results demonstrated that the developed method was a simple, sensitive, and robust analytical method for the monitoring of pollutants in the environment.

  9. A novel high-performance liquid chromatography-electron spray ionization-mass spectrometry method for simultaneous determination of guggulsterones, piperine and gallic acid in Triphala guggulu

    Directory of Open Access Journals (Sweden)

    Ganesh Muguli

    2015-01-01

    Full Text Available "Triphalaguggulu0" is an important Ayurvedic formulation comprising of Guggulu, that is, Commiphora wightii (Arn. Bhandari as a base wherein powdered fruits of triphala, that is, Phyllanthus emblica L., Terminalia bellirica (Gaertn. Roxb and Terminalia chebula Retz, along with powdered fruit of Piper longum L. are compounded. This polyherbal preparation has been strongly recommended in chronic inflammation, piles, and fistula. However, due to the complexity of compound formulation standardization of commercial products is challenging. In the present communication marker-based standardization of "Triphalaguggulu" preparation using gallic acid (for triphala, piperine (for P. longum L. and guggulsterones (for guggulu is reported. These compounds of diverse chemistry were successfully separated on a Waters HR-C18 column by isocratic elution with methanol and water (80:20 v/v as mobile phase at the flow rate of 1.0 mL/min coupled with photodiode array detector. These optimal chromatographic conditions were used for simultaneous quantification of gallic acid, guggulsterones (E and Z and piperine in commercial samples by high-performance liquid chromatography-electron spray ionization-mass spectrometry and method was validated as per ICH guidelines.

  10. Comparison of electron and chemical ionization modes for the quantification of thiols and oxidative compounds in white wines by gas chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Thibon, Cécile; Pons, Alexandre; Mouakka, Nadia; Redon, Pascaline; Méreau, Raphaël; Darriet, Philippe

    2015-10-09

    A rapid, sensitive method for assaying volatile impact compounds in white wine was developed using gas chromatography-tandem mass spectrometry (GC-MS/MS) technology, with a triple quadrupole analyzer operating in chemical ionization and electron impact mode. This GC-MS/MS method made it possible to assay volatile thiols (3SH: 3-sulfanylhexanol, formerly 3MH; 3SHA: 3-sulfanylhexyl acetate, formerly 3MHA; 4MSP: 4-methyl-4-sulfanylpentan-2-one, formerly 4MMP; BM: benzenemethanethiol; E2SA: ethyl 2-sulfanylacetate; and 2FM: 2-furanmethanethiol) and odoriferous oxidation markers (Sotolon: 4,5-dimethyl-3-hydroxy-2(5)H-furanone, methional, and phenylacetaldehyde) simultaneously in dry white wines, comparing electron impact (EI) and chemical ionization (CI) modes. More molecular ions were produced by CI than protonated molecules, despite the greater fragmentation caused by EI. So, even using the best reactant gas giving the highest signal for thiols, EI was the best ionization mode, with the lowest detection limits. For all compounds of interest, the limits of quantification (LOQ) obtained were well below their detection thresholds (ranging from 0.5 to 8.5ng/L for volatile thiols and 65-260ng/L for oxidation markers). Recovery rates ranged from 86% to 111%, reproducibility (in terms of relative standard deviation; RSD) was below 18% in all cases, with correlation coefficients above 0.991 for all analytes. The method was successfully applied to the analysis of compounds of interest in Sauvignon Blanc wines from a single estate and ten different vintages.

  11. Fluctuations in Relativistic Causal Hydrodynamics

    CERN Document Server

    Kumar, Avdhesh; Mishra, Ananta P

    2013-01-01

    The formalism to calculate the hydrodynamics fluctuation using the quasi-stationary fluctuation theory of Onsager to the relativistic Navier-Stokes hydrodynamics is already known. In this work we calculate hydrodynamic fluctuations in relativistic causal theory of Muller, Israel and Stewart and other related causal hydrodynamic theories. We show that expressions for the Onsager coefficients and the correlation functions have form similar to the ones obtained by using Navier-Stokes equation. However, temporal evolution of the correlation functions obtained using MIS and the other causal theories can be significantly different than the correlation functions obtained using the Navier-Stokes equation. Finally, as an illustrative example, we explicitly plot the correlation functions obtained using the causal-hydrodynamics theories and compare them with correlation functions obtained by earlier authors using the expanding boost-invariant (Bjorken) flows.

  12. Gradient expansion for anisotropic hydrodynamics

    CERN Document Server

    Florkowski, Wojciech; Spaliński, Michał

    2016-01-01

    We compute the gradient expansion for anisotropic hydrodynamics. The results are compared with the corresponding expansion of the underlying kinetic-theory model with the collision term treated in the relaxation time approximation. We find that a recent formulation of anisotropic hydrodynamics based on an anisotropic matching principle yields the first three terms of the gradient expansion in agreement with those obtained for the kinetic theory. This gives further support for this particular hydrodynamic model as a good approximation of the kinetic-theory approach. We further find that the gradient expansion of anisotropic hydrodynamics is an asymptotic series, and the singularities of the analytic continuation of its Borel transform indicate the presence of non-hydrodynamic modes.

  13. Lifshitz Superfluid Hydrodynamics

    CERN Document Server

    Chapman, Shira; Oz, Yaron

    2014-01-01

    We construct the first order hydrodynamics of quantum critical points with Lifshitz scaling and a spontaneously broken symmetry. The fluid is described by a combination of two flows, a normal component that carries entropy and a super-flow which has zero viscosity and carries no entropy. We analyze the new transport effects allowed by the lack of boost invariance and constrain them by the local second law of thermodynamics. Imposing time-reversal invariance, we find eight new parity even transport coefficients. The formulation is applicable, in general, to any superfluid/superconductor with an explicit breaking of boost symmetry, in particular to high $T_c$ superconductors. We discuss possible experimental signatures.

  14. Hydrodynamics of Ship Propellers

    DEFF Research Database (Denmark)

    Breslin, John P.; Andersen, Poul

    This book deals with flows over propellers operating behind ships, and the hydrodynamic forces and moments which the propeller generates on the shaft and on the ship hull.The first part of the text is devoted to fundamentals of the flow about hydrofoil sections (with and without cavitation......) and about wings. It then treats propellers in uniform flow, first via advanced actuator disc modelling, and then using lifting-line theory. Pragmatic guidance is given for design and evaluation of performance, including the use of computer modelling.The second part covers the development of unsteady forces...... arising from operation in non-uniform hull wakes. First, by a number of simplifications, various aspects of the problem are dealt with separately until the full problem of a non-cavitating, wide-bladed propeller in a wake is treated by a new and completely developed theory. Next, the complicated problem...

  15. Hydrodynamic effects on coalescence.

    Energy Technology Data Exchange (ETDEWEB)

    Dimiduk, Thomas G.; Bourdon, Christopher Jay; Grillet, Anne Mary; Baer, Thomas A.; de Boer, Maarten Pieter; Loewenberg, Michael (Yale University, New Haven, CT); Gorby, Allen D.; Brooks, Carlton, F.

    2006-10-01

    The goal of this project was to design, build and test novel diagnostics to probe the effect of hydrodynamic forces on coalescence dynamics. Our investigation focused on how a drop coalesces onto a flat surface which is analogous to two drops coalescing, but more amenable to precise experimental measurements. We designed and built a flow cell to create an axisymmetric compression flow which brings a drop onto a flat surface. A computer-controlled system manipulates the flow to steer the drop and maintain a symmetric flow. Particle image velocimetry was performed to confirm that the control system was delivering a well conditioned flow. To examine the dynamics of the coalescence, we implemented an interferometry capability to measure the drainage of the thin film between the drop and the surface during the coalescence process. A semi-automated analysis routine was developed which converts the dynamic interferogram series into drop shape evolution data.

  16. Hydrodynamics of sediment threshold

    Science.gov (United States)

    Ali, Sk Zeeshan; Dey, Subhasish

    2016-07-01

    A novel hydrodynamic model for the threshold of cohesionless sediment particle motion under a steady unidirectional streamflow is presented. The hydrodynamic forces (drag and lift) acting on a solitary sediment particle resting over a closely packed bed formed by the identical sediment particles are the primary motivating forces. The drag force comprises of the form drag and form induced drag. The lift force includes the Saffman lift, Magnus lift, centrifugal lift, and turbulent lift. The points of action of the force system are appropriately obtained, for the first time, from the basics of micro-mechanics. The sediment threshold is envisioned as the rolling mode, which is the plausible mode to initiate a particle motion on the bed. The moment balance of the force system on the solitary particle about the pivoting point of rolling yields the governing equation. The conditions of sediment threshold under the hydraulically smooth, transitional, and rough flow regimes are examined. The effects of velocity fluctuations are addressed by applying the statistical theory of turbulence. This study shows that for a hindrance coefficient of 0.3, the threshold curve (threshold Shields parameter versus shear Reynolds number) has an excellent agreement with the experimental data of uniform sediments. However, most of the experimental data are bounded by the upper and lower limiting threshold curves, corresponding to the hindrance coefficients of 0.2 and 0.4, respectively. The threshold curve of this study is compared with those of previous researchers. The present model also agrees satisfactorily with the experimental data of nonuniform sediments.

  17. Simultaneous analysis of non-steroidal anti-inflammatory drugs and estrogenic hormones in water and wastewater samples using gas chromatography-mass spectrometry and gas chromatography with electron capture detection

    Energy Technology Data Exchange (ETDEWEB)

    Migowska, Natalia; Caban, Magda; Stepnowski, Piotr; Kumirska, Jolanta, E-mail: kumirska@chem.univ.gda.pl

    2012-12-15

    Non-steroidal anti-inflammatory drugs are the group of pharmaceuticals that is most often found in the environment, whereas estrogenic hormones are considered to be potent endocrine disruptors. However, the fate and persistence of these compounds in the environment are still unclear. In this study we propose two approaches for determining these compounds in environmental water samples: GC-MS using time windows and operating in selected ion-monitoring mode (SIM) and, for the first time, gas chromatography with electron capture detection (GC-ECD). The identification criteria of both methods fulfilled the requirements of Directive 2002/657/EC. The use of time windows improved the sensitivity of GC-MS measurements. In GC-MS analysis the pharmaceuticals were determined as trimethylsilyl, in GC-ECD as pentafluoropropionyl derivatives. The influence of such parameters as the type of reagent, type of solvent, reaction time, reaction temperature and microwave irradiation in a household microwave oven on the efficacy of silylation was investigated. Derivatization using N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA) and 1% trimethylchlorosilane (TMCS) in pyridine (1:1, v/v) for 30 min in 60 Degree-Sign C was found to be optimal. Optimization of the solid phase extraction procedure (SPE) confirmed that the application of Oasis HLB cartridges, the acidification of loading samples to pH 2 and the use of methanol as eluent gave the best absolute recoveries (ARs) of the target compounds. The following ARs of all the compounds were achieved: 58.2-106.8% in influent wastewater, 77.8-103.4% in effluent wastewater and 81.2-101.9% in surface water samples. Validation of the SPE-GC-MS method enables 13 pharmaceuticals to be determined with MDLs between 3.3 and 343.6 ng/L, depending on the analytes and matrices. GC-ECD analysis enables the determination of 6 pharmaceuticals in surface water samples with MDLs between 0.7 and 5.4 ng/L. The proposed methods were successfully used for

  18. Determination of homovanillic, isohomovanillic and vanillylmandelic acids in human urine by means of glass capillary gas-liquid chromatography with temperature-programmed electron-capture detection.

    Science.gov (United States)

    Chauhan, J; Darbre, A

    1980-10-10

    The determination of urinary homovanillic, isohomovanillic and vanillylmandelic acids as their trifluoroacetylhexafluoroisopropyl ester derivatives by glass capillary gas-liquid chromatography has been studied. It was shown that even with high column efficiencies a single peak-single compound relationship could not be assumed and for reliable quantitation it was necessary to check determinations with a second gas-liquid chromatography column.

  19. Recent development of hydrodynamic modeling

    Science.gov (United States)

    Hirano, Tetsufumi

    2014-09-01

    In this talk, I give an overview of recent development in hydrodynamic modeling of high-energy nuclear collisions. First, I briefly discuss about current situation of hydrodynamic modeling by showing results from the integrated dynamical approach in which Monte-Carlo calculation of initial conditions, quark-gluon fluid dynamics and hadronic cascading are combined. In particular, I focus on rescattering effects of strange hadrons on final observables. Next I highlight three topics in recent development in hydrodynamic modeling. These include (1) medium response to jet propagation in di-jet asymmetric events, (2) causal hydrodynamic fluctuation and its application to Bjorken expansion and (3) chiral magnetic wave from anomalous hydrodynamic simulations. (1) Recent CMS data suggest the existence of QGP response to propagation of jets. To investigate this phenomenon, we solve hydrodynamic equations with source term which exhibits deposition of energy and momentum from jets. We find a large number of low momentum particles are emitted at large angle from jet axis. This gives a novel interpretation of the CMS data. (2) It has been claimed that a matter created even in p-p/p-A collisions may behave like a fluid. However, fluctuation effects would be important in such a small system. We formulate relativistic fluctuating hydrodynamics and apply it to Bjorken expansion. We found the final multiplicity fluctuates around the mean value even if initial condition is fixed. This effect is relatively important in peripheral A-A collisions and p-p/p-A collisions. (3) Anomalous transport of the quark-gluon fluid is predicted when extremely high magnetic field is applied. We investigate this possibility by solving anomalous hydrodynamic equations. We found the difference of the elliptic flow parameter between positive and negative particles appears due to the chiral magnetic wave. Finally, I provide some personal perspective of hydrodynamic modeling of high energy nuclear collisions

  20. Special Relativistic Hydrodynamics with Gravitation

    Science.gov (United States)

    Hwang, Jai-chan; Noh, Hyerim

    2016-12-01

    Special relativistic hydrodynamics with weak gravity has hitherto been unknown in the literature. Whether such an asymmetric combination is possible has been unclear. Here, the hydrodynamic equations with Poisson-type gravity, considering fully relativistic velocity and pressure under the weak gravity and the action-at-a-distance limit, are consistently derived from Einstein’s theory of general relativity. An analysis is made in the maximal slicing, where the Poisson’s equation becomes much simpler than our previous study in the zero-shear gauge. Also presented is the hydrodynamic equations in the first post-Newtonian approximation, now under the general hypersurface condition. Our formulation includes the anisotropic stress.

  1. Special relativistic hydrodynamics with gravitation

    CERN Document Server

    Hwang, Jai-chan

    2016-01-01

    The special relativistic hydrodynamics with weak gravity is hitherto unknown in the literature. Whether such an asymmetric combination is possible was unclear. Here, the hydrodynamic equations with Poisson-type gravity considering fully relativistic velocity and pressure under the weak gravity and the action-at-a-distance limit are consistently derived from Einstein's general relativity. Analysis is made in the maximal slicing where the Poisson's equation becomes much simpler than our previous study in the zero-shear gauge. Also presented is the hydrodynamic equations in the first post-Newtonian approximation, now under the {\\it general} hypersurface condition. Our formulation includes the anisotropic stress.

  2. The flow of heavy flavor in hydrodynamics

    CERN Document Server

    Song, Taesoo; Lee, Su Houng

    2011-01-01

    The flow of charm is calculated in 2+1 ideal hydrodynamics by introducing the charge of $c\\bar{c}$ pair assuming that the number of $c\\bar{c}$ pairs is conserved in relativistic heavy-ion collisions. It is found that the mean radial flow velocity of charm quarks is smaller than that of bulk matter by 10$\\sim$15 \\% and the measured $v_2$ of heavy-flavor electrons is reproduced up to $p_T^e=$ 1.5 GeV/c in Au+Au collision at RHIC. The same flow is applied to regenerated $J/\\psi$ and its $v_2$ is discussed.

  3. Bosonization and quantum hydrodynamics

    Indian Academy of Sciences (India)

    Girish S Setlur

    2006-03-01

    It is shown that it is possible to bosonize fermions in any number of dimensions using the hydrodynamic variables, namely the velocity potential and density. The slow part of the Fermi field is defined irrespective of dimensionality and the commutators of this field with currents and densities are exponentiated using the velocity potential as conjugate to the density. An action in terms of these canonical bosonic variables is proposed that reproduces the correct current and density correlations. This formalism in one dimension is shown to be equivalent to the Tomonaga-Luttinger approach as it leads to the same propagator and exponents. We compute the one-particle properties of a spinless homogeneous Fermi system in two spatial dimensions with long-range gauge interactions and highlight the metal-insulator transition in the system. A general formula for the generating function of density correlations is derived that is valid beyond the random phase approximation. Finally, we write down a formula for the annihilation operator in momentum space directly in terms of number conserving products of Fermi fields.

  4. Engineering Hydrodynamic AUV Hulls

    Science.gov (United States)

    Allen, J.

    2016-12-01

    AUV stands for autonomous underwater vehicle. AUVs are used in oceanography and are similar to gliders. MBARIs AUVs as well as other AUVs map the ocean floor which is very important. They also measure physical characteristics of the water, such as temperature and salinity. My science fair project for 4th grade was a STEM activity in which I built and tested 3 different AUV bodies. I wanted to find out which design was the most hydrodynamic. I tested three different lengths of AUV hulls to see which AUV would glide the farthest. The first was 6 inches. The second was 12 inches and the third was 18 inches. I used clay for the nosecone and cut a ruler into two and made it the fin. Each AUV used the same nosecone and fin. I tested all three designs in a pool. I used biomimicry to create my hypothesis. When I was researching I found that long slim animals swim fastest. So, my hypothesis is the longer AUV will glide farthest. In the end I was right. The longer AUV did glide the farthest.

  5. Dispersive liquid-liquid microextraction combined with gas chromatography-electron capture detection for the determination of polychlorinated biphenyls in soils

    Energy Technology Data Exchange (ETDEWEB)

    Hu Jia [Department of Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027 (China); Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, Central China Normal University, Wuhan 430079 (China); Fu Lingyan; Zhao Xinna; Liu Xiujuan [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, Central China Normal University, Wuhan 430079 (China); Wang Huili; Wang Xuedong [School of Environmental Science and Public Health, Wenzhou Medical College, Wenzhou 325035 (China); Dai Liyan, E-mail: dailiyan@zju.edu.cn [Department of Chemical Engineering, Zhejiang University, Hangzhou, Zhejiang 310027 (China)

    2009-04-27

    In this article, dispersive liquid-liquid microextraction (DLLME) and gas chromatography-electron capture detection (GC-ECD) were presented for the extraction and determination of five polychlorinated biphenyls (PCBs) in soil samples. Acetone was used as extraction solvent for the extraction of PCBs from soil samples. In DLLME, the target analytes in the extraction solvent were rapidly transferred from the acetone extract to chlorobenzene when the extraction process began. The main advantages of this method are quick speed, high enrichment factor, high recovery and good repeatability. Under the optimum conditions, the method yields a linear calibration curve in the concentration range from 2 to 2000 {mu}g kg{sup -1}for PCB 52, and 0.4 to 400 {mu}g kg{sup -1} for other target analytes. Coefficients of correlation (r{sup 2}) ranged from 0.9993 to 0.9999. The repeatability was tested by spiking soil samples at a concentration level of 10 {mu}g kg{sup -1} for PCBs. The relative standard deviations (RSDs, n = 11) varied between 2.2% and 6.4%. The limits of detection (LODs), based on signal-to-noise (S/N) of 3, were between 0.20 and 0.50 {mu}g kg{sup -1}. The relative recoveries of the five PCBs from soil S1, S2 and S3 at spiking levels of 10, 20 and 50 {mu}g kg{sup -1} were in the range of 88.70-103.8%, 82.50-106.3% and 82.30-113.6%, respectively. Therefore, DLLME combined with GC-ECD can be successfully applied for the determination of trace PCB residues in real soil samples.

  6. Novel methods for identification and quantification of the mushroom nephrotoxin orellanine. Thin-layer chromatography and electrophoresis screening of mushrooms with electron spin resonance determination of the toxin.

    Science.gov (United States)

    Oubrahim, H; Richard, J M; Cantin-Esnault, D; Seigle-Murandi, F; Trécourt, F

    1997-01-10

    Orellanine, (2,2'-bipyridine)-3,3',4,4'-tetrol-1,1'-dioxide, the toxin from several Cortinariace species, induces an acute renal failure which can be very severe or even irreversible and fatal. It is therefore important to be able to quickly and simply identify orellanine in mushroom samples with classical methods, readily available in any laboratory, such as anti-poison centers. This article reports the results of three analytical methods: classical TLC on cellulose plates in n-butanol--acetic acid--water and two original methods, electrophoresis on agarose gel and direct electron spin resonance (ESR) after enzymatic oxidation. They were applied to detect orellanine in 34 Cortinariaceae and 4 other species of toadstools. Our three sets of results are convergent. TLC (detection limit: 15 ng with fluorescence densitometry), electrophoresis (25 ng) and even ESR (5 micrograms), are sensitive enough for our purpose, and a sophisticated method like HPLC (detection limit: 50 pg) is not required. As the ESR spectrum of the toxin semiquinone is highly specific, TLC or electrophoresis coupled with ESR are a convenient alternative to liquid chromatography coupled with mass spectrometry, with the same specificity, for a confirmation or with samples such as ours with high toxin contents. ESR unambiguously confirms the relatively high contents of orellanine, from 0.45% (C. henrici) to 1.1-1.4% (C. orellanus), found in five Cortinarius from the subgenus Leprocybe, section Orellani. The five species, though they are from different geographic origins, have a more or less common pattern of fluorescent compounds, among which orellinine and orelline beside orellanine. It can be useful to note that orellanine semiquinone can be easily detected by ESR directly in the fresh mushroom. The toxin is absent in the other mushrooms we tested, especially in D. cinnamomea and C. splendens, which have been claimed as toxic and suspected to contain orellanine.

  7. Separation and screening of short-chain chlorinated paraffins in environmental samples using comprehensive two-dimensional gas chromatography with micro electron capture detection.

    Science.gov (United States)

    Xia, Dan; Gao, Lirong; Zhu, Shuai; Zheng, Minghui

    2014-11-01

    Short-chain chlorinated paraffins (SCCPs) are highly complex technical mixtures with thousands of isomers and numerous homologs. They are classified as priority candidate persistent organic pollutants under the Stockholm Convention for their persistence, bioaccumulation, and toxicity. Analyzing SCCPs is challenging because of the complexity of the mixtures. Chromatograms of SCCPs acquired using one-dimensional (1D) gas chromatography (GC) contain a large characteristic "peak" with a broad and unresolved profile. Comprehensive two-dimensional GC (GC×GC) shows excellent potential for separating complex mixtures. In this study, GC×GC coupled with micro electron capture detection (μECD) was used to separate and screen SCCPs. The chromatographic parameters, including the GC column types, oven temperature program, and modulation period, were systematically optimized. The SCCP congeners were separated into groups using a DM-1 column connected to a BPX-50 column. The SCCP congeners in technical mixtures were separated according to the number of chlorine substituents for a given carbon chain length and according to the number of carbon atoms plus chlorine atoms for different carbon chain lengths. A fish tissue sample was analyzed to illustrate the feasibility of the GC×GC-μECD method in analyzing biological samples. Over 1,500 compounds were identified in the fish extract, significantly more than were identified using 1D GC. The detection limits for five selected SCCP congeners were between 1 and 5 pg/L using the GC×GC method, and these were significantly lower than those achieved using 1D GC. This method is a good choice for analysis of SCCPs in environmental samples, exhibiting good separation and good sensitivity.

  8. Determination of volatile organic compounds including alcohols in refill fluids and cartridges of electronic cigarettes by headspace solid-phase micro extraction and gas chromatography-mass spectrometry.

    Science.gov (United States)

    Lim, Hyun-Hee; Shin, Ho-Sang

    2017-02-01

    An analytical method for the detection of 14 volatile organic compounds (VOCs) was developed to investigate VOCs in refill fluids and cartridges of electronic cigarettes (EC) using headspace solid-phase micro extraction (HS-SPME) coupled with gas chromatography-mass spectrometry (GC-MS). In total, 14 VOCs were identified and quantified in 283 flavored liquids, 21 nicotine liquids, and 12 disposable cartridges. The detected concentration ranges of the VOCs are as follows: benzene (0.008-2.28 mg L(-1)), toluene (0.006-0.687 mg L(-1)), ethylbenzene (0.01-1.21 mg L(-1)), m-xylene (0.002-1.13 mg L(-1)), p-xylene (0.007-2.8 mg L(-1)), o-xylene (0.004-2.27 mg L(-1)), styrene (0.011-0.339 mg L(-1)), ethyl acetate (0.3-669.9 mg L(-1)), ethanol (16-38,742 mg L(-1)), methanol (66-3375 mg L(-1)), pyridine (0.077-99.7 mg L(-1)), acetylpyrazine (0.077-147 mg L(-1)), 2,3,5-trimethylpyrazine (0.008-96.8 mg L(-1)), and octamethylcyclotetrasiloxane (0.1-57.2 mg L(-1)). Benzene, toluene, ethylbenzene, m-xylene, p-xylene, and o-xylene coexisted in samples, which may have originated from the use of petrogenic hydrocarbons as an extraction solvent for flavor and nicotine from natural plants. The maximum detected concentrations of benzene, methanol, and ethanol in liquid samples were found in quantities higher than their authorized maximum limits as residual solvents in pharmaceutical products.

  9. Gas chromatography/olfactometry and electronic nose analyses of retronasal aroma of espresso and correlation with sensory evaluation by an artificial neural network.

    Science.gov (United States)

    Michishita, Tomomi; Akiyama, Masayuki; Hirano, Yuta; Ikeda, Michio; Sagara, Yasuyuki; Araki, Tetsuya

    2010-01-01

    To develop a method for evaluating and designing the retronasal aroma of espresso, sensory evaluation data was correlated with data obtained from gas chromatography/olfactometry (GC/O, CharmAnalysis™) and from an electronic nose system αFOX4000 (E-nose). The volatile compounds of various kinds of espresso (arabica coffee beans from 6 production countries: Brazil, Ethiopia, Guatemala, Colombia, Indonesia, and Tanzania; 3 roasting degrees for each country: L values, 18, 23, and 26) were collected with a retronasal aroma simulator (RAS) and examined by GC/O and E-nose. In addition, sensory descriptive analysis using a 7-point scale for RAS effluent gas was performed by 5 trained flavorists using sensory descriptors selected based on the frequency in use and coefficient of correlation. The charm values of 10 odor descriptions obtained from GC/O analysis exhibited the significant (P sensor resistances and factor analysis on the sensory evaluation scores showed that the differences of aroma characteristics among the roasting degrees were larger than those among the origins. Based on an artificial neural network (ANN) model applied to the data from GC/O analyses and sensory evaluations, the perceptual factor of the RAS aroma was predicted to be mainly affected by sweet-caramel, smoke-roast, and acidic odors. Also, 3 metal oxide semiconductor sensors (LY2/Gh, P30/1, and T40/1) of E-nose were selected for analyses of RAS aroma and correlated with the sensory descriptive scores by the ANN to support sensory evaluation.

  10. Homogeneous liquid-liquid extraction combined with gas chromatography-electron capture detector for the determination of three pesticide residues in soils

    Energy Technology Data Exchange (ETDEWEB)

    Wang Xuedong [School of Environmental Science and Public Health, Wenzhou Medical College, Wenzhou 325035 (China)], E-mail: zjuwxd@yahoo.com.cn; Zhao Xinna; Liu Xiujuan; Li Yanyan; Fu Lingyan; Hu Jia [Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, Central China Normal University, Wuhan 430079 (China); Huang Changjiang [School of Environmental Science and Public Health, Wenzhou Medical College, Wenzhou 325035 (China)

    2008-07-14

    In this study, a new method was developed for analyzing malathion, cypermethrin and lambda-cyhalothrin from soil samples by using homogeneous liquid-liquid extraction (HLLE) and gas chromatography with electron capture detector (GC-ECD). Acetone was used as extraction solvent for the extraction of target pesticides from soil samples. When the extraction process was finished, the target analytes in the extraction solvent were rapidly transferred from the acetone extract to carbon tetrachloride, using HLLE. Under the optimum conditions, linearity was obtained in the range of 0.05-40 {mu}g kg{sup -1} for malathion, 0.04-10 {mu}g kg{sup -1} for lambda-cyhalothrin and 0.05-50 {mu}g kg{sup -1} for cypermethrin, respectively. Coefficients of correlation (r{sup 2}) ranged from 0.9993 to 0.9998. The repeatability was carried out by spiking soil samples at concentration levels of 2.5 {mu}g kg{sup -1} for lambda-cyhalothrin, and 10 {mu}g kg{sup -1} for malathion and cypermethrin, respectively. The relative standard deviations (RSDs) varied between 2.3 and 9.6% (n = 3). The limits of detection (LODs), based on signal-to-noise ratio (S/N) of 3, varied between 0.01 and 0.04 {mu}g kg{sup -1}. The relative recoveries of three pesticides from soil A1, A2 and A3 at spiking levels of 2.5, 5 and 10 {mu}g kg{sup -1} were in the range of 82.20-91.60%, 88.90-110.5% and 77.10-98.50%, respectively. In conclusion, the proposed method can be successfully applied for the determination of target pesticide residues in real soil samples.

  11. In matrix derivatization of trichloroethylene metabolites in human plasma with methyl chloroformate and their determination by solid-phase microextraction-gas chromatography-electron capture detector.

    Science.gov (United States)

    Mudiam, Mohana Krishna Reddy; Jain, Rajeev; Varshney, Meenu; Ch, Ratnasekhar; Chauhan, Abhishek; Goyal, Sudhir Kumar; Khan, Haider A; Murthy, R C

    2013-04-15

    Trichloroethylene (TCE) is a common industrial chemical that has been widely used as metal degreaser and for many industrial purposes. In humans, TCE is metabolized into dichloroacetic acid (DCA), trichloroacetic acid (TCA) and trichloroethanol (TCOH). A simple and rapid method has been developed for the quantitative determination of TCE metabolites. The procedure involves the in situ derivatization of TCE metabolites with methyl chloroformate (MCF) directly in diluted plasma samples followed by extraction and analysis with solid-phase microextraction (SPME) coupled to gas chromatography-electron capture detector (GC-ECD). Factors which can influence the efficiency of derivatization such as amount of MCF and pyridine (PYR), ratio of water/methanol were optimized. The factors which can affect the extraction efficiencies of SPME were screened using 2(7-4) Placket-Burman Design (PBD). A central composite design (CCD) was then applied to further optimize the most significant factors for optimum SPME extraction. The optimum factors for the SPME extraction were found to be 562.5mg of NaCl, pH at 1 and an extraction time of 22 min. Recoveries and detection limits of all three analytes in plasma were found to be in the range of 92.69-97.55% and 0.036-0.068 μg mL(-1) of plasma, respectively. The correlation coefficients were found to be in the range of 0.990-0.995. The intra- and inter-day precisions for TCE metabolites were found to be in the range of 2.37-4.81% and 5.13-7.61%, respectively. The major advantage of this method is that MCF derivatization allows conversion of TCE metabolites into their methyl esters in very short time (≤30 s) at room temperature directly in the plasma samples, thus makes it a solventless analysis. The method developed was successfully applied to the plasma samples of humans exposed to TCE.

  12. Reciprocal relations in dissipationless hydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Melnikovsky, L. A., E-mail: leva@kapitza.ras.ru [Russian Academy of Sciences, Kapitza Institute for Physical Problems (Russian Federation)

    2014-12-15

    Hidden symmetry in dissipationless terms of arbitrary hydrodynamics equations is recognized. We demonstrate that all fluxes are generated by a single function and derive conventional Euler equations using the proposed formalism.

  13. Relativistic Hydrodynamics on Graphic Cards

    CERN Document Server

    Gerhard, Jochen; Bleicher, Marcus

    2012-01-01

    We show how to accelerate relativistic hydrodynamics simulations using graphic cards (graphic processing units, GPUs). These improvements are of highest relevance e.g. to the field of high-energetic nucleus-nucleus collisions at RHIC and LHC where (ideal and dissipative) relativistic hydrodynamics is used to calculate the evolution of hot and dense QCD matter. The results reported here are based on the Sharp And Smooth Transport Algorithm (SHASTA), which is employed in many hydrodynamical models and hybrid simulation packages, e.g. the Ultrarelativistic Quantum Molecular Dynamics model (UrQMD). We have redesigned the SHASTA using the OpenCL computing framework to work on accelerators like graphic processing units (GPUs) as well as on multi-core processors. With the redesign of the algorithm the hydrodynamic calculations have been accelerated by a factor 160 allowing for event-by-event calculations and better statistics in hybrid calculations.

  14. Gradient expansion for anisotropic hydrodynamics

    Science.gov (United States)

    Florkowski, Wojciech; Ryblewski, Radoslaw; Spaliński, Michał

    2016-12-01

    We compute the gradient expansion for anisotropic hydrodynamics. The results are compared with the corresponding expansion of the underlying kinetic-theory model with the collision term treated in the relaxation time approximation. We find that a recent formulation of anisotropic hydrodynamics based on an anisotropic matching principle yields the first three terms of the gradient expansion in agreement with those obtained for the kinetic theory. This gives further support for this particular hydrodynamic model as a good approximation of the kinetic-theory approach. We further find that the gradient expansion of anisotropic hydrodynamics is an asymptotic series, and the singularities of the analytic continuation of its Borel transform indicate the presence of nonhydrodynamic modes.

  15. An introduction to astrophysical hydrodynamics

    CERN Document Server

    Shore, Steven N

    1992-01-01

    This book is an introduction to astrophysical hydrodynamics for both astronomy and physics students. It provides a comprehensive and unified view of the general problems associated with fluids in a cosmic context, with a discussion of fluid dynamics and plasma physics. It is the only book on hydrodynamics that addresses the astrophysical context. Researchers and students will find this work to be an exceptional reference. Contents include chapters on irrotational and rotational flows, turbulence, magnetohydrodynamics, and instabilities.

  16. Slurry bubble column hydrodynamics

    Science.gov (United States)

    Rados, Novica

    Slurry bubble column reactors are presently used for a wide range of reactions in both chemical and biochemical industry. The successful design and scale up of slurry bubble column reactors require a complete understanding of multiphase fluid dynamics, i.e. phase mixing, heat and mass transport characteristics. The primary objective of this thesis is to improve presently limited understanding of the gas-liquid-solid slurry bubble column hydrodynamics. The effect of superficial gas velocity (8 to 45 cm/s), pressure (0.1 to 1.0 MPa) and solids loading (20 and 35 wt.%) on the time-averaged solids velocity and turbulent parameter profiles has been studied using Computer Automated Radioactive Particle Tracking (CARPT). To accomplish this, CARPT technique has been significantly improved for the measurements in highly attenuating systems, such as high pressure, high solids loading stainless steel slurry bubble column. At a similar set of operational conditions time-averaged gas and solids holdup profiles have been evaluated using the developed Computed Tomography (CT)/Overall gas holdup procedure. This procedure is based on the combination of the CT scans and the overall gas holdup measurements. The procedure assumes constant solids loading in the radial direction and axially invariant cross-sectionally averaged gas holdup. The obtained experimental holdup, velocity and turbulent parameters data are correlated and compared with the existing low superficial gas velocities and atmospheric pressure CARPT/CT gas-liquid and gas-liquid-solid slurry data. The obtained solids axial velocity radial profiles are compared with the predictions of the one dimensional (1-D) liquid/slurry recirculation phenomenological model. The obtained solids loading axial profiles are compared with the predictions of the Sedimentation and Dispersion Model (SDM). The overall gas holdup values, gas holdup radial profiles, solids loading axial profiles, solids axial velocity radial profiles and solids

  17. CALIBRATED HYDRODYNAMIC MODEL

    Directory of Open Access Journals (Sweden)

    Sezar Gülbaz

    2015-01-01

    Full Text Available The land development and increase in urbanization in a watershed affect water quantityand water quality. On one hand, urbanization provokes the adjustment of geomorphicstructure of the streams, ultimately raises peak flow rate which causes flood; on theother hand, it diminishes water quality which results in an increase in Total SuspendedSolid (TSS. Consequently, sediment accumulation in downstream of urban areas isobserved which is not preferred for longer life of dams. In order to overcome thesediment accumulation problem in dams, the amount of TSS in streams and inwatersheds should be taken under control. Low Impact Development (LID is a BestManagement Practice (BMP which may be used for this purpose. It is a land planningand engineering design method which is applied in managing storm water runoff inorder to reduce flooding as well as simultaneously improve water quality. LID includestechniques to predict suspended solid loads in surface runoff generated over imperviousurban surfaces. In this study, the impact of LID-BMPs on surface runoff and TSS isinvestigated by employing a calibrated hydrodynamic model for Sazlidere Watershedwhich is located in Istanbul, Turkey. For this purpose, a calibrated hydrodynamicmodel was developed by using Environmental Protection Agency Storm WaterManagement Model (EPA SWMM. For model calibration and validation, we set up arain gauge and a flow meter into the field and obtain rainfall and flow rate data. Andthen, we select several LID types such as retention basins, vegetative swales andpermeable pavement and we obtain their influence on peak flow rate and pollutantbuildup and washoff for TSS. Consequently, we observe the possible effects ofLID on surface runoff and TSS in Sazlidere Watershed.

  18. The hydrodynamics of colloidal gelation.

    Science.gov (United States)

    Varga, Zsigmond; Wang, Gang; Swan, James

    2015-12-14

    Colloidal gels are formed during arrested phase separation. Sub-micron, mutually attractive particles aggregate to form a system spanning network with high interfacial area, far from equilibrium. Models for microstructural evolution during colloidal gelation have often struggled to match experimental results with long standing questions regarding the role of hydrodynamic interactions. In nearly all models, these interactions are neglected entirely. In the present work, we report simulations of gelation with and without hydrodynamic interactions between the suspended particles executed in HOOMD-blue. The disparities between these simulations are striking and mirror the experimental-theoretical mismatch in the literature. The hydrodynamic simulations agree with experimental observations, however. We explore a simple model of the competing transport processes in gelation that anticipates these disparities, and conclude that hydrodynamic forces are essential. Near the gel boundary, there exists a competition between compaction of individual aggregates which suppresses gelation and coagulation of aggregates which enhances it. The time scale for compaction is mildly slowed by hydrodynamic interactions, while the time scale for coagulation is greatly accelerated. This enhancement to coagulation leads to a shift in the gel boundary to lower strengths of attraction and lower particle concentrations when compared to models that neglect hydrodynamic interactions. Away from the gel boundary, differences in the nearest neighbor distribution and fractal dimension persist within gels produced by both simulation methods. This result necessitates a fundamental rethinking of how dynamic, discrete element models for gelation kinetics are developed as well as how collective hydrodynamic interactions influence the arrest of attractive colloidal dispersions.

  19. Gas chromatography

    Science.gov (United States)

    Guiochon, Georges; Guillemin, Claude L.

    1990-11-01

    Gas chromatography is a powerful separation technique for gas and vapor mixtures. Combining separation and on-line detection permits accurate quantitative analysis of complex mixtures, including traces of compounds down to parts per trillions in some particular cases. The importance of gas chromatography in quality control and process control in the chemical and drug industry, in environmental pollution investigations and in clinical analysis is critical. The principles of the technique are discussed, the main components of a gas chromatograph are described and some idea of the importance of the applications is given.

  20. Hydrodynamic model for picosecond propagation of laser-created nanoplasmas

    CERN Document Server

    Saxena, Vikrant; Ziaja, Beata; Santra, Robin

    2015-01-01

    The interaction of a free-electron-laser pulse with a moderate or large size cluster is known to create a quasi-neutral nanoplasma, which then expands on hydrodynamic timescale, i.e., $>1$ ps. To have a better understanding of ion and electron data from experiments derived from laser-irradiated clusters, one needs to simulate cluster dynamics on such long timescales for which the molecular dynamics approach becomes inefficient. We therefore propose a two-step Molecular Dynamics-Hydrodynamic scheme. In the first step we use molecular dynamics code to follow the dynamics of an irradiated cluster until all the photo-excitation and corresponding relaxation processes are finished and a nanoplasma, consisting of ground-state ions and thermalized electrons, is formed. In the second step we perform long-timescale propagation of this nanoplasma with a computationally efficient hydrodynamic approach. In the present paper we examine the feasibility of a hydrodynamic two-fluid approach to follow the expansion of spherica...

  1. Green chromatography.

    Science.gov (United States)

    Płotka, Justyna; Tobiszewski, Marek; Sulej, Anna Maria; Kupska, Magdalena; Górecki, Tadeusz; Namieśnik, Jacek

    2013-09-13

    Analysis of organic compounds in samples characterized by different composition of the matrix is very important in many areas. A vast majority of organic compound determinations are performed using gas or liquid chromatographic methods. It is thus very important that these methods have negligible environmental impact. Chromatographic techniques have the potential to be greener at all steps of the analysis, from sample collection and preparation to separation and final determination. The paper summarizes the approaches used to accomplish the goals of green chromatography. While complete elimination of sample preparation would be an ideal approach, it is not always practical. Solventless extraction techniques offer a very good alternative. Where solvents must be used, the focus should be on the minimization of their consumption. The approaches used to make chromatographic separations greener differ depending on the type of chromatography. In gas chromatography it is advisable to move away from using helium as the carrier gas because it is a non-renewable resource. GC separations using low thermal mass technology can be greener because of energy savings offered by this technology. In liquid chromatography the focus should be on the reduction of solvent consumption and replacement of toxic and environmentally hazardous solvents with more benign alternatives. Multidimensional separation techniques have the potential to make the analysis greener in both GC and LC. The environmental impact of the method is often determined by the location of the instrument with respect to the sample collection point.

  2. Ion Chromatography.

    Science.gov (United States)

    Mulik, James D.; Sawicki, Eugene

    1979-01-01

    Accurate for the analysis of ions in solution, this form of analysis enables the analyst to directly assay many compounds that previously were difficult or impossible to analyze. The method is a combination of the methodologies of ion exchange, liquid chromatography, and conductimetric determination with eluant suppression. (Author/RE)

  3. Full Hydrodynamic Model of Nonlinear Electromagnetic Response in Metallic Metamaterials

    CERN Document Server

    Fang, Ming; Sha, Wei E I; Xiong, Xiaoyan Y Z; Wu, Xianliang

    2016-01-01

    Applications of metallic metamaterials have generated significant interest in recent years. Electromagnetic behavior of metamaterials in the optical range is usually characterized by a local-linear response. In this article, we develop a finite-difference time-domain (FDTD) solution of the hydrodynamic model that describes a free electron gas in metals. Extending beyond the local-linear response, the hydrodynamic model enables numerical investigation of nonlocal and nonlinear interactions between electromagnetic waves and metallic metamaterials. By explicitly imposing the current continuity constraint, the proposed model is solved in a self-consistent manner. Charge, energy and angular momentum conservation laws of high-order harmonic generation have been demonstrated for the first time by the Maxwell-hydrodynamic FDTD model. The model yields nonlinear optical responses for complex metallic metamaterials irradiated by a variety of waveforms. Consequently, the multiphysics model opens up unique opportunities f...

  4. Recent progress in anisotropic hydrodynamics

    CERN Document Server

    Strickland, Michael

    2016-01-01

    The quark-gluon plasma created in a relativistic heavy-ion collisions possesses a sizable pressure anisotropy in the local rest frame at very early times after the initial nuclear impact and this anisotropy only slowly relaxes as the system evolves. In a kinetic theory picture, this translates into the existence of sizable momentum-space anisotropies in the underlying partonic distribution functions, . In such cases, it is better to reorganize the hydrodynamical expansion by taking into account momentum-space anisotropies at leading-order in the expansion instead of as a perturbative correction to an isotropic distribution. The resulting anisotropic hydrodynamics framework has been shown to more accurately describe the dynamics of rapidly expanding systems such as the quark-gluon plasma. In this proceedings contribution, I review the basic ideas of anisotropic hydrodynamics, recent progress, and present a few preliminary phenomenological predictions for identified particle spectra and elliptic flow.

  5. Numerical Hydrodynamics in Special Relativity

    Directory of Open Access Journals (Sweden)

    Martí José Maria

    2003-01-01

    Full Text Available This review is concerned with a discussion of numerical methods for the solution of the equations of special relativistic hydrodynamics (SRHD. Particular emphasis is put on a comprehensive review of the application of high-resolution shock-capturing methods in SRHD. Results of a set of demanding test bench simulations obtained with different numerical SRHD methods are compared. Three applications (astrophysical jets, gamma-ray bursts and heavy ion collisions of relativistic flows are discussed. An evaluation of various SRHD methods is presented, and future developments in SRHD are analyzed involving extension to general relativistic hydrodynamics and relativistic magneto-hydrodynamics. The review further provides FORTRAN programs to compute the exact solution of a 1D relativistic Riemann problem with zero and nonzero tangential velocities, and to simulate 1D relativistic flows in Cartesian Eulerian coordinates using the exact SRHD Riemann solver and PPM reconstruction.

  6. Comparative hydrodynamics of bacterial polymorphism

    CERN Document Server

    Spagnolie, Saverio E

    2011-01-01

    Most bacteria swim through fluids by rotating helical flagella which can take one of twelve distinct polymorphic shapes. The most common helical waveform is the "normal" form, used during forward swimming runs. To shed light on the prevalence of the normal form in locomotion, we gather all available experimental measurements of the various polymorphic forms and compute their intrinsic hydrodynamic efficiencies. The normal helical form is found to be the most hydrodynamically efficient of the twelve polymorphic forms by a significant margin - a conclusion valid for both the peritrichous and polar flagellar families, and robust to a change in the effective flagellum diameter or length. The hydrodynamic optimality of the normal polymorph suggests that, although energetic costs of locomotion are small for bacteria, fluid mechanical forces may have played a significant role in the evolution of the flagellum.

  7. Quantum Plasmas An Hydrodynamic Approach

    CERN Document Server

    Haas, Fernando

    2011-01-01

    This book provides an overview of the basic concepts and new methods in the emerging scientific area known as quantum plasmas. In the near future, quantum effects in plasmas will be unavoidable, particularly in high density scenarios such as those in the next-generation intense laser-solid density plasma experiment or in compact astrophysics objects. Currently, plasmas are in the forefront of many intriguing questions around the transition from microscopic to macroscopic modeling of charged particle systems. Quantum Plasmas: an Hydrodynamic Approach is devoted to the quantum hydrodynamic model paradigm, which, unlike straight quantum kinetic theory, is much more amenable to investigate the nonlinear realm of quantum plasmas. The reader will have a step-by-step construction of the quantum hydrodynamic method applied to plasmas. The book is intended for specialists in classical plasma physics interested in methods of quantum plasma theory, as well as scientists interested in common aspects of two major areas of...

  8. HYDRODYNAMIC INTERACTIONS BETWEEN TWO BODIES

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    On the basis of model tests, potential flow theory, and viscous Computational Fluid Dynamics (CFD) method, the hydrodynamic interactions between two underwater bodies were investigated to determine the influencing factors, changing rule, interaction mechanism, and appropriate methods describing them. Some special phenomena were discovered in two series of near-wall interaction experiments. The mathematical model and predicting methods were presented for interacting forces near wall, and the calculation results agreed well with the experimental ones. From the comparisons among numerical results with respect to nonviscosity, numerical results with respect to viscosity, and measured results, data on the influence of viscosity on hydrodynamic interactions were obtained. For hydrodynamic interaction related to multi-body unsteady motions with six degrees of freedom that is difficult to simulate in tests, numerical predictions of unsteady interacting forces were given.

  9. Hydrodynamic shocks in microroller suspensions

    Science.gov (United States)

    Delmotte, Blaise; Driscoll, Michelle; Chaikin, Paul; Donev, Aleksandar

    2017-09-01

    We combine experiments, large-scale simulations, and continuum models to study the emergence of coherent structures in a suspension of magnetically driven microrollers sedimented near a floor. Collective hydrodynamic effects are predominant in this system, leading to strong density-velocity coupling. We characterize a uniform suspension and show that density waves propagate freely in all directions in a dispersive fashion. When sharp density gradients are introduced in the suspension, we observe the formation of a shock. Unlike Burgers' shocklike structures observed in other active and driven confined hydrodynamic systems, the shock front in our system has a well-defined finite width and moves rapidly compared to the mean suspension velocity. We introduce a continuum model demonstrating that the finite width of the front is due to far-field nonlocal hydrodynamic interactions and governed by a geometric parameter, the average particle height above the floor.

  10. Numerical Hydrodynamics in Special Relativity.

    Science.gov (United States)

    Martí, José Maria; Müller, Ewald

    2003-01-01

    This review is concerned with a discussion of numerical methods for the solution of the equations of special relativistic hydrodynamics (SRHD). Particular emphasis is put on a comprehensive review of the application of high-resolution shock-capturing methods in SRHD. Results of a set of demanding test bench simulations obtained with different numerical SRHD methods are compared. Three applications (astrophysical jets, gamma-ray bursts and heavy ion collisions) of relativistic flows are discussed. An evaluation of various SRHD methods is presented, and future developments in SRHD are analyzed involving extension to general relativistic hydrodynamics and relativistic magneto-hydrodynamics. The review further provides FORTRAN programs to compute the exact solution of a 1D relativistic Riemann problem with zero and nonzero tangential velocities, and to simulate 1D relativistic flows in Cartesian Eulerian coordinates using the exact SRHD Riemann solver and PPM reconstruction.

  11. Anisotropic hydrodynamics: Motivation and methodology

    Energy Technology Data Exchange (ETDEWEB)

    Strickland, Michael

    2014-06-15

    In this proceedings contribution I review recent progress in our understanding of the bulk dynamics of relativistic systems that possess potentially large local rest frame momentum-space anisotropies. In order to deal with these momentum-space anisotropies, a reorganization of relativistic viscous hydrodynamics can be made around an anisotropic background, and the resulting dynamical framework has been dubbed “anisotropic hydrodynamics”. I also discuss expectations for the degree of momentum-space anisotropy of the quark–gluon plasma generated in relativistic heavy ion collisions at RHIC and LHC from second-order viscous hydrodynamics, strong-coupling approaches, and weak-coupling approaches.

  12. Hydrodynamics of oceans and atmospheres

    CERN Document Server

    Eckart, Carl

    1960-01-01

    Hydrodynamics of Oceans and Atmospheres is a systematic account of the hydrodynamics of oceans and atmospheres. Topics covered range from the thermodynamic functions of an ideal gas and the thermodynamic coefficients for water to steady motions, the isothermal atmosphere, the thermocline, and the thermosphere. Perturbation equations, field equations, residual equations, and a general theory of rays are also presented. This book is comprised of 17 chapters and begins with an introduction to the basic equations and their solutions, with the aim of illustrating the laws of dynamics. The nonlinear

  13. Abnormal pressures as hydrodynamic phenomena

    Science.gov (United States)

    Neuzil, C.E.

    1995-01-01

    So-called abnormal pressures, subsurface fluid pressures significantly higher or lower than hydrostatic, have excited speculation about their origin since subsurface exploration first encountered them. Two distinct conceptual models for abnormal pressures have gained currency among earth scientists. The static model sees abnormal pressures generally as relict features preserved by a virtual absence of fluid flow over geologic time. The hydrodynamic model instead envisions abnormal pressures as phenomena in which flow usually plays an important role. This paper develops the theoretical framework for abnormal pressures as hydrodynamic phenomena, shows that it explains the manifold occurrences of abnormal pressures, and examines the implications of this approach. -from Author

  14. Inter-laboratory reproducibility of fast gas chromatography-electron impact-time of flight mass spectrometry (GC-EI-TOF/MS) based plant metabolomics

    NARCIS (Netherlands)

    Allwood, J.W.; Erban, A.; Koning, S.; Dun, W.B.; Luedemann, A.; Lommen, A.; Kay, L.; Löscher, R.; Kopka, J.; Goodacre, R.

    2009-01-01

    The application of gas chromatography¿mass spectrometry (GC¿MS) to the `global¿ analysis of metabolites in complex samples (i.e. metabolomics) has now become routine. The generation of these data-rich profiles demands new strategies in data mining and standardisation of experimental and reporting as

  15. Hydrodynamics of a quark droplet

    DEFF Research Database (Denmark)

    Bjerrum-Bohr, Johan J.; Mishustin, Igor N.; Døssing, Thomas

    2012-01-01

    We present a simple model of a multi-quark droplet evolution based on the hydrodynamical description. This model includes collective expansion of the droplet, effects of the vacuum pressure and surface tension. The hadron emission from the droplet is described following Weisskopf's statistical...

  16. Numerical Hydrodynamics in General Relativity

    Directory of Open Access Journals (Sweden)

    Font José A.

    2003-01-01

    Full Text Available The current status of numerical solutions for the equations of ideal general relativistic hydrodynamics is reviewed. With respect to an earlier version of the article, the present update provides additional information on numerical schemes, and extends the discussion of astrophysical simulations in general relativistic hydrodynamics. Different formulations of the equations are presented, with special mention of conservative and hyperbolic formulations well-adapted to advanced numerical methods. A large sample of available numerical schemes is discussed, paying particular attention to solution procedures based on schemes exploiting the characteristic structure of the equations through linearized Riemann solvers. A comprehensive summary of astrophysical simulations in strong gravitational fields is presented. These include gravitational collapse, accretion onto black holes, and hydrodynamical evolutions of neutron stars. The material contained in these sections highlights the numerical challenges of various representative simulations. It also follows, to some extent, the chronological development of the field, concerning advances on the formulation of the gravitational field and hydrodynamic equations and the numerical methodology designed to solve them.

  17. Anomalous hydrodynamics in two dimensions

    Indian Academy of Sciences (India)

    Rabin Banerjee

    2016-02-01

    A new approach is presented to discuss two-dimensional hydrodynamics with gauge and gravitational anomalies. Exact constitutive relations for the stress tensor and charge current are obtained. Also, a connection between response parameters and anomaly coefficients is discussed. These are new results which, in the absence of the gauge sector, reproduce the results found by the gradient expansion approach.

  18. Hydrodynamic Noise and Surface Compliance.

    Science.gov (United States)

    1982-09-08

    Lighthill, 3,4 Ffowcs-Wiiliams, 5-7 and Morse and Ingard .8 Ffowcs-Williams’ 7 excellent review identifies five distinctly different theoretical...Williams, "Hydrodynamic Noise," Annual Review of Fluid Mechanics (Annual Reviews, Palo Alto, CA), vol. 1, 1969, pp. 197-222. 8. P. Morse and K. V. Ingard

  19. Hydrodynamic slip in silicon nanochannels

    Science.gov (United States)

    Ramos-Alvarado, Bladimir; Kumar, Satish; Peterson, G. P.

    2016-03-01

    Equilibrium and nonequilibrium molecular dynamics simulations were performed to better understand the hydrodynamic behavior of water flowing through silicon nanochannels. The water-silicon interaction potential was calibrated by means of size-independent molecular dynamics simulations of silicon wettability. The wettability of silicon was found to be dependent on the strength of the water-silicon interaction and the structure of the underlying surface. As a result, the anisotropy was found to be an important factor in the wettability of these types of crystalline solids. Using this premise as a fundamental starting point, the hydrodynamic slip in nanoconfined water was characterized using both equilibrium and nonequilibrium calculations of the slip length under low shear rate operating conditions. As was the case for the wettability analysis, the hydrodynamic slip was found to be dependent on the wetted solid surface atomic structure. Additionally, the interfacial water liquid structure was the most significant parameter to describe the hydrodynamic boundary condition. The calibration of the water-silicon interaction potential performed by matching the experimental contact angle of silicon led to the verification of the no-slip condition, experimentally reported for silicon nanochannels at low shear rates.

  20. Hydrodynamical approach to transport in nanostructures

    Science.gov (United States)

    D'Agosta, Roberto; di Ventra, Massimiliano

    2006-03-01

    The electrical resistance induced by the viscous properties of the electron liquid has been recently derived.^1 In addition, it is known that the geometric constriction experienced by electrons flowing in a nanostructure gives rise to a fast ``collisional'' process.^2 These facts allow us to derive Navier-Stokes-type of equations, and therefore describe the electron flow on a par with a viscous and compressible liquid. By using this hydrodynamical approach we study electron transport in nanoscale systems and derive the conditions for the transition from laminar to turbulent flow in quantum point contacts. We also discuss possible experimental tests of these predictions. ^1 N. Sai, M. Zwolak, G. Vignale, and M. Di Ventra, Phys. Rev. Lett. 94, 186810 (2005).^2 M. Di Ventra and T.N. Todorov, J. Phys. Cond. Matt. 16, 8025 (2004); N. Bushong, N. Sai and, M. Di Ventra, Nano Lett. (in press).Work supported by the Department of Energy (DE-FG02-05ER46204)

  1. Kinetic simulation of hydrodynamic equivalent capsule implosions

    Science.gov (United States)

    Kwan, Thomas; Le, Ari; Schmitt, Mark; Herrmann, Hans

    2016-10-01

    We have carried out simulations of direct-drive hydrodynamic equivalent capsule implosion experiments conducted on Omega laser facility at the Laboratory of Laser Energetics of the University of Rochester. The capsules had a glass shell (SiO2) 4.87 μm with an inner diameter of 1086 μm. One was filled with deuterium (D) and tritium (T) at 6.635 and 2.475 atmospheric pressure respectively. The other capsule with D, T, and He-3 at 2.475, 2.475, and 5.55 atmospheric pressure respectively. The capsules were imploded with 60 laser beams with a square pulse length of 0.6ns of total energy of 15.6 kJ. One-dimensional radiation hydrodynamic calculations with HYDRA and kinetic particle/hybrid simulations with LSP are carried out for the post-shot analysis. HYDRA outputs at 0.6ns are linked to LSP, in which the electrons are treated as a fluid while all the ion dynamics is simulated by the standard particle-in-cell technique. Additionally, simulations with the new photon package in LSP are initiated at the beginning of the implosion to include the implosion phase of the capsule. The simulation results of density, temperature, and velocity profiles of the electrons, D, T, He-3, and SiO2species are compared with HYDRA. Detail comparisons among the kinetic simulations, rad-hydro simulations, and experimental results of neutron yield, yield ratio, fusion burn histories, and shell convergence will be presented to assess plasma kinetic effects. Work performed under the auspices of the US DOE by the Los Alamos National Laboratory under Contract No. W7405-ENG-36.

  2. Brain vascular and hydrodynamic physiology

    Science.gov (United States)

    Tasker, Robert C.

    2013-01-01

    Protecting the brain in vulnerable infants undergoing surgery is a central aspect of perioperative care. Understanding the link between blood flow, oxygen delivery and oxygen consumption leads to a more informed approach to bedside care. In some cases, we need to consider how high can we let the partial pressure of carbon dioxide go before we have concerns about risk of increased cerebral blood volume and change in intracranial hydrodynamics? Alternatively, in almost all such cases, we have to address the question of how low can we let the blood pressure drop before we should be concerned about brain perfusion? This review, provides a basic understanding of brain bioenergetics, hemodynamics, hydrodynamics, autoregulation and vascular homeostasis to changes in blood gases that is fundamental to our thinking about bedside care and monitoring. PMID:24331089

  3. Hydrodynamic interactions in two dimensions

    Science.gov (United States)

    di Leonardo, R.; Keen, S.; Ianni, F.; Leach, J.; Padgett, M. J.; Ruocco, G.

    2008-09-01

    We measure hydrodynamic interactions between colloidal particles confined in a thin sheet of fluid. The reduced dimensionality, compared to a bulk fluid, increases dramatically the range of couplings. Using optical tweezers we force a two body system along the eigenmodes of the mobility tensor and find that eigenmobilities change logarithmically with particle separation. At a hundred radii distance, the mobilities for rigid and relative motions differ by a factor of 2, whereas in bulk fluids, they would be practically indistinguishable. A two dimensional counterpart of Oseen hydrodynamic tensor quantitatively reproduces the observed behavior, once the relevant boundary conditions are recognized. These results highlight the importance of dimensionality for transport and interactions in colloidal systems and proteins in biological membranes.

  4. Algorithm refinement for fluctuating hydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Williams, Sarah A.; Bell, John B.; Garcia, Alejandro L.

    2007-07-03

    This paper introduces an adaptive mesh and algorithmrefinement method for fluctuating hydrodynamics. This particle-continuumhybrid simulates the dynamics of a compressible fluid with thermalfluctuations. The particle algorithm is direct simulation Monte Carlo(DSMC), a molecular-level scheme based on the Boltzmann equation. Thecontinuum algorithm is based on the Landau-Lifshitz Navier-Stokes (LLNS)equations, which incorporate thermal fluctuations into macroscopichydrodynamics by using stochastic fluxes. It uses a recently-developedsolver for LLNS, based on third-order Runge-Kutta. We present numericaltests of systems in and out of equilibrium, including time-dependentsystems, and demonstrate dynamic adaptive refinement by the computationof a moving shock wave. Mean system behavior and second moment statisticsof our simulations match theoretical values and benchmarks well. We findthat particular attention should be paid to the spectrum of the flux atthe interface between the particle and continuum methods, specificallyfor the non-hydrodynamic (kinetic) time scales.

  5. Hydrodynamics from Landau initial conditions

    Energy Technology Data Exchange (ETDEWEB)

    Sen, Abhisek [University of Tennessee, Knoxville (UTK); Gerhard, Jochen [Frankfurt Institute for Advanced Studies (FIAS), Germany; Torrieri, Giorgio [Universidade Estadual de Campinas, Instituto de Física " Gleb Wataghin" (IFGW), Sao Paulo, Brazil; Read jr, Kenneth F. [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); Wong, Cheuk-Yin [ORNL

    2015-01-01

    We investigate ideal hydrodynamic evolution, with Landau initial conditions, both in a semi-analytical 1+1D approach and in a numerical code incorporating event-by-event variation with many events and transverse density inhomogeneities. The object of the calculation is to test how fast would a Landau initial condition transition to a commonly used boost-invariant expansion. We show that the transition to boost-invariant flow occurs too late for realistic setups, with corrections of O (20 - 30%) expected at freezeout for most scenarios. Moreover, the deviation from boost-invariance is correlated with both transverse flow and elliptic flow, with the more highly transversely flowing regions also showing the most violation of boost invariance. Therefore, if longitudinal flow is not fully developed at the early stages of heavy ion collisions, 2+1 dimensional hydrodynamics is inadequate to extract transport coefficients of the quark-gluon plasma. Based on [1, 2

  6. Non-boost-invariant dissipative hydrodynamics

    CERN Document Server

    Florkowski, Wojciech; Strickland, Michael; Tinti, Leonardo

    2016-01-01

    The one-dimensional non-boost-invariant evolution of the quark-gluon plasma, presumably produced during the early stages of heavy-ion collisions, is analyzed within the frameworks of viscous and anisotropic hydrodynamics. We neglect transverse dynamics and assume homogeneous conditions in the transverse plane but, differently from Bjorken expansion, we relax longitudinal boost invariance in order to study the rapidity dependence of various hydrodynamical observables. We compare the results obtained using several formulations of second-order viscous hydrodynamics with a recent approach to anisotropic hydrodynamics, which treats the large initial pressure anisotropy in a non-perturbative fashion. The results obtained with second-order viscous hydrodynamics depend on the particular choice of the second-order terms included, which suggests that the latter should be included in the most complete way. The results of anisotropic hydrodynamics and viscous hydrodynamics agree for the central hot part of the system, ho...

  7. Gas Chromatography

    Science.gov (United States)

    Qian, Michael C.

    Gas chromatography (GC) has many applications in the analysis of food products. GC has been used for the determination of fatty acids, triglycerides, cholesterol, gases, water, alcohols, pesticides, flavor compounds, and many more. While GC has been used for other food components such as sugars, oligosaccharides, amino acids, peptides, and vitamins, these substances are more suited to analysis by high performance liquid chromatography. GC is ideally suited to the analysis of volatile substances that are thermally stable. Substances such as pesticides and flavor compounds that meet these criteria can be isolated from a food and directly injected into the GC. For compounds that are thermally unstable, too low in volatility, or yield poor chromatographic separation due to polarity, a derivatization step must be done before GC analysis. The two parts of the experiment described here include the analysis of alcohols that requires no derivatization step, and the analysis of fatty acids which requires derivatization. The experiments specify the use of capillary columns, but the first experiment includes conditions for a packed column.

  8. Hydrodynamics of catheter biofilm formation

    CERN Document Server

    Sotolongo-Costa, Oscar; Rodriguez-Perez, Daniel; Martinez-Escobar, Sergio; Fernandez-Barbero, Antonio

    2009-01-01

    A hydrodynamic model is proposed to describe one of the most critical problems in intensive medical care units: the formation of biofilms inside central venous catheters. The incorporation of approximate solutions for the flow-limited diffusion equation leads to the conclusion that biofilms grow on the internal catheter wall due to the counter-stream diffusion of blood through a very thin layer close to the wall. This biological deposition is the first necessary step for the subsequent bacteria colonization.

  9. Soliton propagation in relativistic hydrodynamics

    CERN Document Server

    Fogaça, D A; 10.1016/j.nuclphysa.2007.03.104

    2013-01-01

    We study the conditions for the formation and propagation of Korteweg-de Vries (KdV) solitons in nuclear matter. In a previous work we have derived a KdV equation from Euler and continuity equations in non-relativistic hydrodynamics. In the present contribution we extend our formalism to relativistic fluids. We present results for a given equation of state, which is based on quantum hadrodynamics (QHD).

  10. Hydrodynamic Evolution of GRB Afterglow

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    We investigate the dynamics of a relativistic fireball which decelerates as it sweeps up ambient matter. Not only the radiative and adiabatic cases, but also the realistic intermediate cases are calculated. We perform numerical calcula-tion for various ambient media and sizes of beaming expansion, and find that the deceleration radius R0 may play an important role for the hydrodynamic evolution of GRB afterglow.

  11. Recent progress in anisotropic hydrodynamics

    Directory of Open Access Journals (Sweden)

    Strickland Michael

    2017-01-01

    Full Text Available The quark-gluon plasma created in a relativistic heavy-ion collisions possesses a sizable pressure anisotropy in the local rest frame at very early times after the initial nuclear impact and this anisotropy only slowly relaxes as the system evolves. In a kinetic theory picture, this translates into the existence of sizable momentum-space anisotropies in the underlying partonic distribution functions, 〈 pL2〉 ≪ 〈 pT2〉. In such cases, it is better to reorganize the hydrodynamical expansion by taking into account momentum-space anisotropies at leading-order in the expansion instead of as a perturbative correction to an isotropic distribution. The resulting anisotropic hydrodynamics framework has been shown to more accurately describe the dynamics of rapidly expanding systems such as the quark-gluon plasma. In this proceedings contribution, I review the basic ideas of anisotropic hydrodynamics, recent progress, and present a few preliminary phenomenological predictions for identified particle spectra and elliptic flow.

  12. Counter-current motion in counter-current chromatography.

    Science.gov (United States)

    Ito, Yoichiro

    2014-12-12

    After the CCC2012 meeting, I have received an e-mail regarding the terminology of "Countercurrent Chromatography". It stated that the term "Countercurrent" is a misnomer, because its stationary phase is motionless in the column and that the method should be renamed as liquid-liquid separations or centrifugal separations. However, it was found that these names are already used for various other techniques as found via Google search. The term "Countercurrent Chromatography" was originally made after two preparative methods of Countercurrent distribution and liquid Chromatography, both having no countercurrent motion in the column. However, it is surprising to find that this F1 hybrid method "Countercurrent Chromatography" can clearly exhibit countercurrent motion within the separation column in both hydrodynamic and hydrostatic equilibrium systems. This justifies that "Countercurrent Chromatography" is a proper term for this chromatographic method. Published by Elsevier B.V.

  13. Entropy-limited hydrodynamics: a novel approach to relativistic hydrodynamics

    Science.gov (United States)

    Guercilena, Federico; Radice, David; Rezzolla, Luciano

    2017-07-01

    We present entropy-limited hydrodynamics (ELH): a new approach for the computation of numerical fluxes arising in the discretization of hyperbolic equations in conservation form. ELH is based on the hybridisation of an unfiltered high-order scheme with the first-order Lax-Friedrichs method. The activation of the low-order part of the scheme is driven by a measure of the locally generated entropy inspired by the artificial-viscosity method proposed by Guermond et al. (J. Comput. Phys. 230(11):4248-4267, 2011, doi: 10.1016/j.jcp.2010.11.043). Here, we present ELH in the context of high-order finite-differencing methods and of the equations of general-relativistic hydrodynamics. We study the performance of ELH in a series of classical astrophysical tests in general relativity involving isolated, rotating and nonrotating neutron stars, and including a case of gravitational collapse to black hole. We present a detailed comparison of ELH with the fifth-order monotonicity preserving method MP5 (Suresh and Huynh in J. Comput. Phys. 136(1):83-99, 1997, doi: 10.1006/jcph.1997.5745), one of the most common high-order schemes currently employed in numerical-relativity simulations. We find that ELH achieves comparable and, in many of the cases studied here, better accuracy than more traditional methods at a fraction of the computational cost (up to {˜}50% speedup). Given its accuracy and its simplicity of implementation, ELH is a promising framework for the development of new special- and general-relativistic hydrodynamics codes well adapted for massively parallel supercomputers.

  14. Semi-relativistic hydrodynamics of three-dimensional and low-dimensional quantum plasma

    CERN Document Server

    Andreev, Pavel; Kuz'menkov, Leonid

    2014-01-01

    Contributions of the current-current and Darwin interactions and weak-relativistic addition to kinetic energy in the quantum hydrodynamic equations are considered. Features of hydrodynamic equations for two-dimensional layer of plasma (two-dimensional electron gas for instance) are described. It is shown that the force fields caused by the Darwin interaction and weak-relativistic addition to kinetic energy are partially reduced. Dispersion of three- and two-dimensional semi-relativistic Langmuir waves is calculated.

  15. Hydrodynamic theory of thermoelectric transport and negative magnetoresistance in Weyl semimetals

    Science.gov (United States)

    Lucas, Andrew; Davison, Richard A.; Sachdev, Subir

    2016-08-01

    We present a theory of thermoelectric transport in weakly disordered Weyl semimetals where the electron-electron scattering time is faster than the electron-impurity scattering time. Our hydrodynamic theory consists of relativistic fluids at each Weyl node, coupled together by perturbatively small intervalley scattering, and long-range Coulomb interactions. The conductivity matrix of our theory is Onsager reciprocal and positive semidefinite. In addition to the usual axial anomaly, we account for the effects of a distinct, axial-gravitational anomaly expected to be present in Weyl semimetals. Negative thermal magnetoresistance is a sharp, experimentally accessible signature of this axial-gravitational anomaly, even beyond the hydrodynamic limit.

  16. Hydrodynamic theory of thermoelectric transport and negative magnetoresistance in Weyl semimetals.

    Science.gov (United States)

    Lucas, Andrew; Davison, Richard A; Sachdev, Subir

    2016-08-23

    We present a theory of thermoelectric transport in weakly disordered Weyl semimetals where the electron-electron scattering time is faster than the electron-impurity scattering time. Our hydrodynamic theory consists of relativistic fluids at each Weyl node, coupled together by perturbatively small intervalley scattering, and long-range Coulomb interactions. The conductivity matrix of our theory is Onsager reciprocal and positive semidefinite. In addition to the usual axial anomaly, we account for the effects of a distinct, axial-gravitational anomaly expected to be present in Weyl semimetals. Negative thermal magnetoresistance is a sharp, experimentally accessible signature of this axial-gravitational anomaly, even beyond the hydrodynamic limit.

  17. Annual Report: Hydrodynamics and Radiative Hydrodynamics with Astrophysical Applications

    Energy Technology Data Exchange (ETDEWEB)

    R. Paul Drake

    2005-12-01

    We report the ongoing work of our group in hydrodynamics and radiative hydrodynamics with astrophysical applications. During the period of the existing grant, we have carried out two types of experiments at the Omega laser. One set of experiments has studied radiatively collapsing shocks, obtaining high-quality scaling data using a backlit pinhole and obtaining the first (ever, anywhere) Thomson-scattering data from a radiative shock. Other experiments have studied the deeply nonlinear development of the Rayleigh-Taylor (RT) instability from complex initial conditions, obtaining the first (ever, anywhere) dual-axis radiographic data using backlit pinholes and ungated detectors. All these experiments have applications to astrophysics, discussed in the corresponding papers either in print or in preparation. We also have obtained preliminary radiographs of experimental targets using our x-ray source. The targets for the experiments have been assembled at Michigan, where we also prepare many of the simple components. The above activities, in addition to a variety of data analysis and design projects, provide good experience for graduate and undergraduates students. In the process of doing this research we have built a research group that uses such work to train junior scientists.

  18. Galaxy clusters as hydrodynamics laboratories

    Science.gov (United States)

    Roediger, Elke; Sheardown, Alexander; Fish, Thomas; ZuHone, John; Hunt, Matthew; Su, Yuanyuan; Kraft, Ralph P.; Nulsen, Paul; Forman, William R.; Churazov, Eugene; Randall, Scott W.; Jones, Christine; Machacek, Marie E.

    2017-08-01

    The intra-cluster medium (ICM) of galaxy clusters shows a wealth of hydrodynamical features that trace the growth of clusters via the infall of galaxies or smaller subclusters. Such hydrodynamical features include the wakes of the infalling objects as well as the interfaces between the host cluster’s ICM and the atmosphere of the infalling object. Furthermore, the cluster dynamics can be traced by merger shocks, bow shocks, and sloshing motions of the ICM.The characteristics of these dynamical features, e.g., the direction, length, brightness, and temperature of the galaxies' or subclusters' gas tails varies significantly between different objects. This could be due to either dynamical conditions or ICM transport coefficients such as viscosity and thermal conductivity. For example, the cool long gas tails of of some infalling galaxies and groups have been attributed to a substantial ICM viscosity suppressing mixing of the stripped galaxy or group gas with the hotter ambient ICM.Using hydrodynamical simulations of minor mergers we show, however, that these features can be explained naturally by the dynamical conditions of each particular galaxy or group infall. Specifically, we identify observable features to distinguish the first and second infall of a galaxy or group into its host cluster as well as characteristics during apocentre passage. Comparing our simulations with observations, we can explain several puzzling observations such as the long and cold tail of M86 in Virgo and the very long and tangentially oriented tail of the group LEDA 87445 in Hydra A.Using our simulations, we also assess the validity of the stagnation pressure method that is widely used to determine an infalling galaxy's velocity. We show that near pericentre passage the method gives reasonable results, but near apocentre it is not easily applicable.

  19. Pyrolysis-gas chromatography-mass spectrometry with electron-ionization or resonance-enhanced-multi-photon-ionization for characterization of polycyclic aromatic hydrocarbons in the Baltic Sea.

    Science.gov (United States)

    Otto, Stefan; Streibel, Thorsten; Erdmann, Sabrina; Klingbeil, Sophie; Schulz-Bull, Detlef; Zimmermann, Ralf

    2015-10-15

    Polycyclic aromatic hydrocarbons (PAH), as a part of dissolved organic matter (DOM), are environmental pollutants of the marine compartment. This study investigates the origin of PAH, which is supposed to derive mainly from anthropogenic activities, and their alteration along the salinity gradient of the Baltic Sea. Pyrolysis in combination with gas chromatography and two mass selective detectors in one measurement cycle are utilized as a tool for an efficient trace analysis of such complex samples, by which it is possible to detect degradation products of high molecular structures. Along the north-south transect of the Baltic Sea a slightly rising trend for PAH is visible. Their concentration profiles correspond to the ship traffic as a known anthropogenic source, underlined by the value of special isomer ratios such as phenanthrene and anthracene (0.31-0.45) or pyrene and fluoranthene (0.44-0.53). The detection of naphthalene and the distribution of its alkylated representatives support this statement.

  20. Hydrodynamic characteristics of UASB bioreactors.

    Science.gov (United States)

    John, Siby; Tare, Vinod

    2011-10-01

    The hydrodynamic characteristics of UASB bioreactors operated under different organic loading and hydraulic loading rates were studied, using three laboratory scale models treating concocted sucrose wastewater. Residence time distribution (RTD) analysis using dispersion model and tanks-in-series model was directed towards the characterization of the fluid flow pattern in the reactors and correlation of the hydraulic regime with the biomass content and biogas production. Empty bed reactors followed a plug flow pattern and the flow pattern changed to a large dispersion mixing with biomass and gas production. Effect of increase in gas production on the overall hydraulics was insignificant.

  1. Disruptive Innovation in Numerical Hydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Waltz, Jacob I. [Los Alamos National Laboratory

    2012-09-06

    We propose the research and development of a high-fidelity hydrodynamic algorithm for tetrahedral meshes that will lead to a disruptive innovation in the numerical modeling of Laboratory problems. Our proposed innovation has the potential to reduce turnaround time by orders of magnitude relative to Advanced Simulation and Computing (ASC) codes; reduce simulation setup costs by millions of dollars per year; and effectively leverage Graphics Processing Unit (GPU) and future Exascale computing hardware. If successful, this work will lead to a dramatic leap forward in the Laboratory's quest for a predictive simulation capability.

  2. Turbulence Models of Hydrodynamic Lubrication

    Institute of Scientific and Technical Information of China (English)

    张直明; 王小静; 孙美丽

    2003-01-01

    The main theoretical turbulence models for application to hydrodynamic lubrication problems were briefly reviewed, and the course of their development and their fundamentals were explained. Predictions by these models on flow fields in turbulent Couette flows and shear-induced countercurrent flows were compared to existing measurements, and Zhang & Zhang' s combined k-ε model was shown to have surpassingly satisfactory results. The method of application of this combined k-ε model to high speed journal bearings and annular seals was summarized, and the predicted results were shown to be satisfactory by comparisons with existing experiments of journal bearings and annular seals.

  3. Highly-anisotropic hydrodynamics for central collisions

    CERN Document Server

    Ryblewski, Radoslaw

    2016-01-01

    The framework of leading-order anisotropic hydrodynamics is supplemented with realistic equation of state and self-consistent freeze-out prescription. The model is applied to central proton-nucleus collisions. The results are compared to those obtained within standard Israel-Stewart second-order viscous hydrodynamics. It is shown that the resulting hadron spectra are highly-sensitive to the hydrodynamic approach that has been used.

  4. Determination of 5alpha-androst-16-en-3alpha-ol in truffle fermentation broth by solid-phase extraction coupled with gas chromatography-flame ionization detector/electron impact mass spectrometry.

    Science.gov (United States)

    Wang, Guan; Li, Yuan-Yuan; Li, Dong-Sheng; Tang, Ya-Jie

    2008-07-15

    A novel method using solid-phase extraction coupled with gas chromatography and flame ionization detector (FID)/electron impact mass spectrometry (EIMS) was developed for the determination of 5alpha-androst-16-en-3alpha-ol (androstenol), a steroidal compound belonging to the group of musk odorous 16-androstenes, in truffle fermentation broth. Comparison studies between FID and EIMS indicated two detectors gave similar quantitative results. The highest androstenol concentration of 123.5 ng/mL was detected in Tuber indicum fermentation broth, while no androstenol was found in Tuber aestivum fermentation broth. For the first time, this work confirmed the existence of androstenol in the truffle fermentation broth, which suggested truffle fermentation is a promising alternative for androstenol production on a large scale.

  5. Some open questions in hydrodynamics

    CERN Document Server

    Dyndal, Mateusz

    2014-01-01

    When speaking of unsolved problems in physics, this is surprising at first glance to discuss the case of fluid mechanics. However, there are many deep open questions that come with the theory of fluid mechanics. In this paper, we discuss some of them that we classify in two categories, the long term behavior of solutions of equations of hydrodynamics and the definition of initial (boundary) conditions. The first set of questions come with the non-relativistic theory based on the Navier-Stokes equations. Starting from smooth initial conditions, the purpose is to understand if solutions of Navier-Stokes equations remain smooth with the time evolution. Existence for just a finite time would imply the evolution of finite time singularities, which would have a major influence on the development of turbulent phenomena. The second set of questions come with the relativistic theory of hydrodynamics. There is an accumulating evidence that this theory may be relevant for the description of the medium created in high en...

  6. 气相色谱电子流量/压力控制模块研制和应用%Study and application of gas chromatography electron flow/pressure control module

    Institute of Scientific and Technical Information of China (English)

    何国琛; 戴星明

    2011-01-01

    为了提高气相色谱仪气路控制自动化水平,研制了电子流量/压力控制模块.该模块在基于闭环控制的方式上,通过小流量比例电磁阀、小流量和压力传感器、微型可调限流装置、颗粒过滤网、集成流路块体的优化设计,以放大基准电路、A/D转换、单片机控制系统PID、D/A转换、功率驱动电路来达到控制气体流量/压力的目的.再以单气路控制为最小单位,组合成在气相色谱中所使用的多气路为一体的控制模块组件.最后以毛细柱进样口和氢火焰离子检测器作为实例,证实了EPC电子流量/压力控制在气相色谱中应用的成功.%In order to accelerate the increase in the level of automation about gas control of gas chromatography, an electronic flow/pressure control module was developed. The module was based on the closed-loop control mode to achieve control of gas flow/pressure purposes through low flow proportional solenoid valves, low flow and pressure sensors, micro-adjustable current limiting devices, particle filters, the optimization design of integration flow path block, enlargement reference circuit, A/D conversion, single-chip system PID, D/A conversion and power drive circuit. Then the multi-gas control module component, in the gas chromatography, was made up of a single pneumatic control for smallest unit. Finally, by the capillary inlet and flame ionization detector as an example, it was confirmed that the EPC electronic flow/pressure control was successful in gas chromatography application.

  7. Instrumentation: Ion Chromatography.

    Science.gov (United States)

    Fritz, James S.

    1987-01-01

    Discusses the importance of ion chromatography in separating and measuring anions. The principles of ion exchange are presented, along with some applications of ion chromatography in industry. Ion chromatography systems are described, as well as ion pair and ion exclusion chromatography, column packings, detectors, and programming. (TW)

  8. An integrated analytical approach using ion chromatography, PIXE and electron microscopy to point out the differences in composition of PM10 individual particles

    Science.gov (United States)

    Masiol, Mauro; Ceccato, Daniele; Squizzato, Stefania; Carturan, Sara; Pavoni, Bruno

    2013-07-01

    This study presents a part of a project aiming at characterizing the PM10 composition in the Venice area with detailed chemical analyses using various techniques. The concentrations of six major inorganic ions (Cl-, NO3-, SO42-, Na+, NH4+, Mg2+) and 19 elements (Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br, Pb) were quantified using ion chromatography and PIXE, respectively. The masses of PM10 daily samples and their chemical contents were studied in relationship to micro-meteorological parameters to select a few of them characterized by very different chemical profiles. Four samples from the whole period were categorized as representative of i) clean days; ii) sea spray generation events; iii) high contribution of mineral dust and iv) heavy pollution events. Individual particle analyses of the samples were also performed by SEM-EDS microscopy. Six different classes of particles were identified (mineral particles, chlorides, sulfates, elemental and organic carbon compounds, metals and biological particles) and an estimation of their abundance yielded a significant relationship between the chemical content and composition in individual particles of PM10. Further information was also obtained on PM10 source contributions, morphology, mineralogy and mixed state of particles demonstrating the importance of combining different analytical approaches.

  9. Peptide sequencing and characterization of post-translational modifications by enhanced ion-charging and liquid chromatography electron-transfer dissociation tandem mass spectrometry

    DEFF Research Database (Denmark)

    Kjeldsen, Frank; Giessing, Anders; Ingrell, Christian R

    2007-01-01

    We have tested the effect of m-nitrobenzyl alcohol (m-NBA) as a method to increase the average charge state of protonated gas-phase molecular ions generated by ESI from tryptic peptides and phosphopeptides. Various concentrations of m-NBA were added to the mobile phases of a liquid chromatography...... system coupled to an ESI tandem mass spectrometer. Addition of just 0.1% m-NBA changed the average charge state for the identified tryptic BSA peptides from 2.2+ to 2.6+. As a result, the predominant charge states for BSA peptides were changed from 2+ to > or =3+. To evaluate the benefits of peptide...... Mascot score (24 units) than doubly charged peptides. m-NBA also increased the average charge state of phosphopeptides by up to 0.5 charge unit. The ease of implementation and the analytical benefits of charge enhancement of tryptic peptides by addition of m-NBA to the LC solvents suggest the general...

  10. Relativistic Hydrodynamics for Heavy-Ion Collisions

    Science.gov (United States)

    Ollitrault, Jean-Yves

    2008-01-01

    Relativistic hydrodynamics is essential to our current understanding of nucleus-nucleus collisions at ultrarelativistic energies (current experiments at the Relativistic Heavy Ion Collider, forthcoming experiments at the CERN Large Hadron Collider). This is an introduction to relativistic hydrodynamics for graduate students. It includes a detailed…

  11. Hydrodynamic models of a Cepheid atmosphere

    Science.gov (United States)

    Karp, A. H.

    1975-01-01

    Instead of computing a large number of coarsely zoned hydrodynamic models covering the entire atmospheric instability strip, the author computed a single model as well as computer limitations allow. The implicit hydrodynamic code of Kutter and Sparks was modified to include radiative transfer effects in optically thin zones.

  12. Hydrodynamic correlation functions in nematic liquid crystals

    NARCIS (Netherlands)

    Lekkerkerker, H.N.W.; Carle, D.; Laidlaw, W.G.

    1976-01-01

    The result, recently discovered by Forster, that the strength factors of the nonpropagating modes in certain hydrodynamic correlation functions in nematic liquid crystals are not fully determined by the hydrodynamic matrix is reconsidered. Using time reversal and space inversion symmetry one finds t

  13. Hydrodynamic Overview at Hot Quarks 2016

    CERN Document Server

    Noronha-Hostler, Jacquelyn

    2016-01-01

    This presents an overview of relativistic hydrodynamic modeling in heavy-ion collisions prepared for Hot Quarks 2016, at South Padre Island, TX, USA. The influence of the initial state and viscosity on various experimental observables are discussed. Specific problems that arise in the hydrodynamical modeling at the Beam Energy Scan are briefly discussed.

  14. Measurement of the hydrodynamic resistance of microdroplets.

    Science.gov (United States)

    Jakiela, Slawomir

    2016-10-07

    Here, we demonstrate a novel method of measurement which determines precisely the hydrodynamic resistance of a droplet flowing through a channel. The obtained results show that the hydrodynamic resistance of a droplet in a microchannel achieves its maximum for lengths of the droplet ranging from 3w to 4w and that interactions between beads in a train exist.

  15. Hydrodynamic correlation functions in nematic liquid crystals

    NARCIS (Netherlands)

    Lekkerkerker, H.N.W.; Carle, D.; Laidlaw, W.G.

    1976-01-01

    The result, recently discovered by Forster, that the strength factors of the nonpropagating modes in certain hydrodynamic correlation functions in nematic liquid crystals are not fully determined by the hydrodynamic matrix is reconsidered. Using time reversal and space inversion symmetry one finds t

  16. Quasiparticle anisotropic hydrodynamics for central collisions

    CERN Document Server

    Alqahtani, Mubarak; Strickland, Michael

    2016-01-01

    We use quasiparticle anisotropic hydrodynamics to study an azimuthally-symmetric boost-invariant quark-gluon plasma including the effects of both shear and bulk viscosities. In quasiparticle anisotropic hydrodynamics, a single finite-temperature quasiparticle mass is introduced and fit to the lattice data in order to implement a realistic equation of state. We compare results obtained using the quasiparticle method with the standard method of imposing the equation of state in anisotropic hydrodynamics and viscous hydrodynamics. Using these three methods, we extract the primordial particle spectra, total number of charged particles, and average transverse momentum for various values of the shear viscosity to entropy density ratio eta/s. We find that the three methods agree well for small shear viscosity to entropy density ratio, eta/s, but differ at large eta/s. We find, in particular, that when using standard viscous hydrodynamics, the bulk-viscous correction can drive the primordial particle spectra negative...

  17. Hydrodynamic Approaches in Relativistic Heavy Ion Reactions

    CERN Document Server

    de Souza, Rafael Derradi; Kodama, Takeshi

    2016-01-01

    We review several facets of the hydrodynamic description of the relativistic heavy ion collisions, starting from the historical motivation to the present understandings of the observed collective aspects of experimental data, especially those of the most recent RHIC and LHC results. In this report, we particularly focus on the conceptual questions and the physical foundations of the validity of the hydrodynamic approach itself. We also discuss recent efforts to clarify some of the points in this direction, such as the various forms of derivations of relativistic hydrodynamics together with the limitations intrinsic to the traditional approaches, variational approaches, known analytic solutions for special cases, and several new theoretical developments. Throughout this review, we stress the role of course-graining procedure in the hydrodynamic description and discuss its relation with the physical observables through the analysis of a hydrodynamic mapping of a microscopic transport model. Several questions to...

  18. Hydrodynamics research of wastewater treatment bioreactors

    Institute of Scientific and Technical Information of China (English)

    REN Nan-qi; ZHANG Bing; ZHOU Xue-fei

    2009-01-01

    To optimize the design and improve the performance of wastewater treatment bioreactors, the review concerning the hydrodynamics explored by theoretical equations, process experiments, modeling of the hydrody-namics and flow field measurement is presented. Results of different kinds of experiments show that the hydro-dynamic characteristics can affect sludge characteristics, mass transfer and reactor performance significantly. A-long with the development of theoretical equations, turbulence models including large eddy simulation models and Reynolds-averaged Navier-Stokes (RANS) models are widely used at present. Standard and modified k-ε models are the most widely used eddy viscosity turbulence models for simulating flows in bioreactors. Numericalsimulation of hydrodynamics is proved to be efficient for optimizing design and operation. The development of measurement techniques with high accuracy and low intrusion enables the flow filed in the bioreactors to be transparent. Integration of both numerical simulation and experimental measurement can describe the hydrody-namics very well.

  19. Hydrodynamic Nambu Brackets derived by Geometric Constraints

    CERN Document Server

    Blender, Richard

    2015-01-01

    A geometric approach to derive the Nambu brackets for ideal two-dimensional (2D) hydrodynamics is suggested. The derivation is based on two-forms with vanishing integrals in a periodic domain, and with resulting dynamics constrained by an orthogonality condition. As a result, 2D hydrodynamics with vorticity as dynamic variable emerges as a generic model, with conservation laws which can be interpreted as enstrophy and energy functionals. Generalized forms like surface quasi-geostrophy and fractional Poisson equations for the stream-function are also included as results from the derivation. The formalism is extended to a hydrodynamic system coupled to a second degree of freedom, with the Rayleigh-B\\'{e}nard convection as an example. This system is reformulated in terms of constitutive conservation laws with two additive brackets which represent individual processes: a first representing inviscid 2D hydrodynamics, and a second representing the coupling between hydrodynamics and thermodynamics. The results can b...

  20. Hydrodynamics of evaporating sessile drops

    CERN Document Server

    Barash, L Yu

    2010-01-01

    Several dynamical stages of the Marangoni convection of an evaporating sessile drop are obtained. We jointly take into account the hydrodynamics of an evaporating sessile drop, effects of the thermal conduction in the drop and the diffusion of vapor in air. The stages are characterized by different number of vortices in the drop and the spatial location of vortices. During the early stage the array of vortices arises near a surface of the drop and induces a non-monotonic spatial distribution of the temperature over the drop surface. The number of near-surface vortices in the drop is controlled by the Marangoni cell size, which is calculated similar to that given by Pearson for flat fluid layers. The number of vortices quickly decreases with time, resulting in three bulk vortices in the intermediate stage. The vortex structure finally evolves into the single convection vortex in the drop, existing during about 1/2 of the evaporation time.

  1. Decoherent Histories and Hydrodynamic Equations

    CERN Document Server

    Halliwell, J J

    1998-01-01

    For a system consisting of a large collection of particles, a set of variables that will generally become effectively classical are the local densities (number, momentum, energy). That is, in the context of the decoherent histories approach to quantum theory, it is expected that histories of these variables will be approximately decoherent, and that their probabilites will be strongly peaked about hydrodynamic equations. This possibility is explored for the case of the diffusion of the number density of a dilute concentration of foreign particles in a fluid. It is shown that, for certain physically reasonable initial states, the probabilities for histories of number density are strongly peaked about evolution according to the diffusion equation. Decoherence of these histories is also shown for a class of initial states which includes non-trivial superpositions of number density. Histories of phase space densities are also discussed. The case of histories of number, momentum and energy density for more general...

  2. Hydrodynamic stability and stellar oscillations

    Indian Academy of Sciences (India)

    H M Antia

    2011-07-01

    Chandrasekhar’s monograph on Hydrodynamic and hydromagnetic stability, published in 1961, is a standard reference on linear stability theory. It gives a detailed account of stability of fluid flow in a variety of circumstances, including convection, stability of Couette flow, Rayleigh–Taylor instability, Kelvin–Helmholtz instability as well as the Jean’s instability for star formation. In most cases he has extended these studies to include effects of rotation and magnetic field. In a later paper he has given a variational formulation for equations of non-radial stellar oscillations. This forms the basis for helioseismic inversion techniques as well as extension to include the effect of rotation, magnetic field and other large-scale flows using a perturbation treatment.

  3. Integration of quantum hydrodynamical equation

    Science.gov (United States)

    Ulyanova, Vera G.; Sanin, Andrey L.

    2007-04-01

    Quantum hydrodynamics equations describing the dynamics of quantum fluid are a subject of this report (QFD).These equations can be used to decide the wide class of problem. But there are the calculated difficulties for the equations, which take place for nonlinear hyperbolic systems. In this connection, It is necessary to impose the additional restrictions which assure the existence and unique of solutions. As test sample, we use the free wave packet and study its behavior at the different initial and boundary conditions. The calculations of wave packet propagation cause in numerical algorithm the division. In numerical algorithm at the calculations of wave packet propagation, there arises the problem of division by zero. To overcome this problem we have to sew together discrete numerical and analytical continuous solutions on the boundary. We demonstrate here for the free wave packet that the numerical solution corresponds to the analytical solution.

  4. Particle hydrodynamics with tessellation techniques

    CERN Document Server

    Hess, S

    2009-01-01

    Lagrangian smoothed particle hydrodynamics (SPH) is a well-established approach to model fluids in astrophysical problems, thanks to its geometric flexibility and ability to automatically adjust the spatial resolution to the clumping of matter. However, a number of recent studies have emphasized inaccuracies of SPH in the treatment of fluid instabilities. The origin of these numerical problems can be traced back to spurious surface effects across contact discontinuities, and to SPH's inherent prevention of mixing at the particle level. We here investigate a new fluid particle model where the density estimate is carried out with the help of an auxiliary mesh constructed as the Voronoi tessellation of the simulation particles instead of an adaptive smoothing kernel. This Voronoi-based approach improves the ability of the scheme to represent sharp contact discontinuities. We show that this eliminates spurious surface tension effects present in SPH and that play a role in suppressing certain fluid instabilities. ...

  5. Nonstandard Gaits in Unsteady Hydrodynamics

    Science.gov (United States)

    Fairchild, Michael; Rowley, Clarence

    2016-11-01

    Marine biology has long inspired the design and engineering of underwater vehicles. The literature examining the kinematics and dynamics of fishes, ranging from undulatory anguilliform swimmers to oscillatory ostraciiform ones, is vast. Past numerical studies of these organisms have principally focused on gaits characterized by sinusoidal pitching and heaving motions. It is conceivable that more sophisticated gaits could perform better in some respects, for example as measured by thrust generation or by cost of transport. This work uses an unsteady boundary-element method to numerically investigate the hydrodynamics and propulsive efficiency of high-Reynolds-number swimmers whose gaits are encoded by Fourier series or by Jacobi elliptic functions. Numerical results are presented with an emphasis on identifying particular wake structures and modes of motion that are associated with optimal swimming. This work was supported by the Office of Naval Research through MURI Grant N00014-14-1-0533.

  6. Introduction to Magneto-Hydrodynamics

    Science.gov (United States)

    Pelletier, Guy

    Magneto-Hydrodynamics (hereafter MHD) describes plasmas on large scales and more generally electrically conducting fluids. This description does not discriminate between the various fluids that constitute the medium. In laboratory, it allows to globally describe a plasma machine, for instance a toroidal nuclear fusion reactor like a Tokamak. In astrophysics it plays an essential role in the description of cosmic objects and their environments, as well as the media, such as the interstellar or the intergalactic medium. A set of phenomena are specific to MHD description. Some of them will be presented in this lecture such as the tension effect, confinement, magnetic diffusivity, magnetic field freezing, Alfvén waves, magneto-sonic waves, reconnection. A celebrated phenomenon of MHD will not be introduced in this brief lecture, namely the dynamo effect.

  7. Hydrodynamic dispersion within porous biofilms

    KAUST Repository

    Davit, Y.

    2013-01-23

    Many microorganisms live within surface-associated consortia, termed biofilms, that can form intricate porous structures interspersed with a network of fluid channels. In such systems, transport phenomena, including flow and advection, regulate various aspects of cell behavior by controlling nutrient supply, evacuation of waste products, and permeation of antimicrobial agents. This study presents multiscale analysis of solute transport in these porous biofilms. We start our analysis with a channel-scale description of mass transport and use the method of volume averaging to derive a set of homogenized equations at the biofilm-scale in the case where the width of the channels is significantly smaller than the thickness of the biofilm. We show that solute transport may be described via two coupled partial differential equations or telegrapher\\'s equations for the averaged concentrations. These models are particularly relevant for chemicals, such as some antimicrobial agents, that penetrate cell clusters very slowly. In most cases, especially for nutrients, solute penetration is faster, and transport can be described via an advection-dispersion equation. In this simpler case, the effective diffusion is characterized by a second-order tensor whose components depend on (1) the topology of the channels\\' network; (2) the solute\\'s diffusion coefficients in the fluid and the cell clusters; (3) hydrodynamic dispersion effects; and (4) an additional dispersion term intrinsic to the two-phase configuration. Although solute transport in biofilms is commonly thought to be diffusion dominated, this analysis shows that hydrodynamic dispersion effects may significantly contribute to transport. © 2013 American Physical Society.

  8. The hydrodynamics of dolphin drafting

    Directory of Open Access Journals (Sweden)

    Weihs Daniel

    2004-05-01

    Full Text Available Abstract Background Drafting in cetaceans is defined as the transfer of forces between individuals without actual physical contact between them. This behavior has long been surmised to explain how young dolphin calves keep up with their rapidly moving mothers. It has recently been observed that a significant number of calves become permanently separated from their mothers during chases by tuna vessels. A study of the hydrodynamics of drafting, initiated in the hope of understanding the mechanisms causing the separation of mothers and calves during fishing-related activities, is reported here. Results Quantitative results are shown for the forces and moments around a pair of unequally sized dolphin-like slender bodies. These include two major effects. First, the so-called Bernoulli suction, which stems from the fact that the local pressure drops in areas of high speed, results in an attractive force between mother and calf. Second is the displacement effect, in which the motion of the mother causes the water in front to move forwards and radially outwards, and water behind the body to move forwards to replace the animal's mass. Thus, the calf can gain a 'free ride' in the forward-moving areas. Utilizing these effects, the neonate can gain up to 90% of the thrust needed to move alongside the mother at speeds of up to 2.4 m/sec. A comparison with observations of eastern spinner dolphins (Stenella longirostris is presented, showing savings of up to 60% in the thrust that calves require if they are to keep up with their mothers. Conclusions A theoretical analysis, backed by observations of free-swimming dolphin schools, indicates that hydrodynamic interactions with mothers play an important role in enabling dolphin calves to keep up with rapidly moving adult school members.

  9. Non-targeted analysis of electronics waste by comprehensive two-dimensional gas chromatography combined with high-resolution mass spectrometry: Using accurate mass information and mass defect analysis to explore the data.

    Science.gov (United States)

    Ubukata, Masaaki; Jobst, Karl J; Reiner, Eric J; Reichenbach, Stephen E; Tao, Qingping; Hang, Jiliang; Wu, Zhanpin; Dane, A John; Cody, Robert B

    2015-05-22

    Comprehensive two-dimensional gas chromatography (GC×GC) and high-resolution mass spectrometry (HRMS) offer the best possible separation of their respective techniques. Recent commercialization of combined GC×GC-HRMS systems offers new possibilities for the analysis of complex mixtures. However, such experiments yield enormous data sets that require new informatics tools to facilitate the interpretation of the rich information content. This study reports on the analysis of dust obtained from an electronics recycling facility by using GC×GC in combination with a new high-resolution time-of-flight (TOF) mass spectrometer. New software tools for (non-traditional) Kendrick mass defect analysis were developed in this research and greatly aided in the identification of compounds containing chlorine and bromine, elements that feature in most persistent organic pollutants (POPs). In essence, the mass defect plot serves as a visual aid from which halogenated compounds are recognizable on the basis of their mass defect and isotope patterns. Mass chromatograms were generated based on specific ions identified in the plots as well as region of the plot predominantly occupied by halogenated contaminants. Tentative identification was aided by database searches, complementary electron-capture negative ionization experiments and elemental composition determinations from the exact mass data. These included known and emerging flame retardants, such as polybrominated diphenyl ethers (PBDEs), hexabromobenzene, tetrabromo bisphenol A and tris (1-chloro-2-propyl) phosphate (TCPP), as well as other legacy contaminants such as polychlorinated biphenyls (PCBs) and polychlorinated terphenyls (PCTs).

  10. Simultaneous Glycan-Peptide Characterization Using Hydrophilic Interaction Chromatography and Parallel Fragmentation by CID, Higher Energy Collisional Dissociation, and Electron Transfer Dissociation MS Applied to the N-Linked Glycoproteome of Campylobacter jejuni*

    Science.gov (United States)

    Scott, Nichollas E.; Parker, Benjamin L.; Connolly, Angela M.; Paulech, Jana; Edwards, Alistair V. G.; Crossett, Ben; Falconer, Linda; Kolarich, Daniel; Djordjevic, Steven P.; Højrup, Peter; Packer, Nicolle H.; Larsen, Martin R.; Cordwell, Stuart J.

    2011-01-01

    Campylobacter jejuni is a gastrointestinal pathogen that is able to modify membrane and periplasmic proteins by the N-linked addition of a 7-residue glycan at the strict attachment motif (D/E)XNX(S/T). Strategies for a comprehensive analysis of the targets of glycosylation, however, are hampered by the resistance of the glycan-peptide bond to enzymatic digestion or β-elimination and have previously concentrated on soluble glycoproteins compatible with lectin affinity and gel-based approaches. We developed strategies for enriching C. jejuni HB93-13 glycopeptides using zwitterionic hydrophilic interaction chromatography and examined novel fragmentation, including collision-induced dissociation (CID) and higher energy collisional (C-trap) dissociation (HCD) as well as CID/electron transfer dissociation (ETD) mass spectrometry. CID/HCD enabled the identification of glycan structure and peptide backbone, allowing glycopeptide identification, whereas CID/ETD enabled the elucidation of glycosylation sites by maintaining the glycan-peptide linkage. A total of 130 glycopeptides, representing 75 glycosylation sites, were identified from LC-MS/MS using zwitterionic hydrophilic interaction chromatography coupled to CID/HCD and CID/ETD. CID/HCD provided the majority of the identifications (73 sites) compared with ETD (26 sites). We also examined soluble glycoproteins by soybean agglutinin affinity and two-dimensional electrophoresis and identified a further six glycosylation sites. This study more than doubles the number of confirmed N-linked glycosylation sites in C. jejuni and is the first to utilize HCD fragmentation for glycopeptide identification with intact glycan. We also show that hydrophobic integral membrane proteins are significant targets of glycosylation in this organism. Our data demonstrate that peptide-centric approaches coupled to novel mass spectrometric fragmentation techniques may be suitable for application to eukaryotic glycoproteins for simultaneous

  11. Simultaneous glycan-peptide characterization using hydrophilic interaction chromatography and parallel fragmentation by CID, higher energy collisional dissociation, and electron transfer dissociation MS applied to the N-linked glycoproteome of Campylobacter jejuni.

    Science.gov (United States)

    Scott, Nichollas E; Parker, Benjamin L; Connolly, Angela M; Paulech, Jana; Edwards, Alistair V G; Crossett, Ben; Falconer, Linda; Kolarich, Daniel; Djordjevic, Steven P; Højrup, Peter; Packer, Nicolle H; Larsen, Martin R; Cordwell, Stuart J

    2011-02-01

    Campylobacter jejuni is a gastrointestinal pathogen that is able to modify membrane and periplasmic proteins by the N-linked addition of a 7-residue glycan at the strict attachment motif (D/E)XNX(S/T). Strategies for a comprehensive analysis of the targets of glycosylation, however, are hampered by the resistance of the glycan-peptide bond to enzymatic digestion or β-elimination and have previously concentrated on soluble glycoproteins compatible with lectin affinity and gel-based approaches. We developed strategies for enriching C. jejuni HB93-13 glycopeptides using zwitterionic hydrophilic interaction chromatography and examined novel fragmentation, including collision-induced dissociation (CID) and higher energy collisional (C-trap) dissociation (HCD) as well as CID/electron transfer dissociation (ETD) mass spectrometry. CID/HCD enabled the identification of glycan structure and peptide backbone, allowing glycopeptide identification, whereas CID/ETD enabled the elucidation of glycosylation sites by maintaining the glycan-peptide linkage. A total of 130 glycopeptides, representing 75 glycosylation sites, were identified from LC-MS/MS using zwitterionic hydrophilic interaction chromatography coupled to CID/HCD and CID/ETD. CID/HCD provided the majority of the identifications (73 sites) compared with ETD (26 sites). We also examined soluble glycoproteins by soybean agglutinin affinity and two-dimensional electrophoresis and identified a further six glycosylation sites. This study more than doubles the number of confirmed N-linked glycosylation sites in C. jejuni and is the first to utilize HCD fragmentation for glycopeptide identification with intact glycan. We also show that hydrophobic integral membrane proteins are significant targets of glycosylation in this organism. Our data demonstrate that peptide-centric approaches coupled to novel mass spectrometric fragmentation techniques may be suitable for application to eukaryotic glycoproteins for simultaneous

  12. Application of multi-way analysis to UV-visible spectroscopy, gas chromatography and electronic nose data for wine ageing evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Prieto, N. [Department of Condensed Matter Physics, Faculty of Sciences, University of Valladolid, 47011 Valladolid (Spain); Department of Inorganic Chemistry, Escuela de Ingenierias Industriales, University of Valladolid, Paseo del Cauce, 59, 47011 Valladolid (Spain); Rodriguez-Mendez, M.L. [Department of Inorganic Chemistry, Escuela de Ingenierias Industriales, University of Valladolid, Paseo del Cauce, 59, 47011 Valladolid (Spain); Leardi, R. [Department of Pharmaceutical and Food Chemistry and Technology, University of Genoa, Via Brigata Salerno 13, I-16147 8 Genoa (Italy); Oliveri, P., E-mail: oliveri@dictfa.unige.it [Department of Pharmaceutical and Food Chemistry and Technology, University of Genoa, Via Brigata Salerno 13, I-16147 8 Genoa (Italy); Hernando-Esquisabel, D.; Iniguez-Crespo, M. [Gobierno de la Rioja, Consejeria de Agricultura y Alimentacion, Estacion Enologica, Breton de los Herreros 4, 26200 Haro, La Rioja (Spain); Saja, J.A. de [Department of Condensed Matter Physics, Faculty of Sciences, University of Valladolid, 47011 Valladolid (Spain)

    2012-03-16

    Highlights: Black-Right-Pointing-Pointer Wine samples were analytically characterised according to their ageing process. Black-Right-Pointing-Pointer Signals from a sensor-based electronic nose were fused with GC-MS and UV-visible data. Black-Right-Pointing-Pointer The study involved 6 periodical determinations of 20 variables on 6 different wines. Black-Right-Pointing-Pointer Multi-way analysis allowed to efficiently extract the maximum information from data. Black-Right-Pointing-Pointer Multi-way methods represent the most suitable tool for processing three-mode data. - Abstract: In this study, a multi-way method (Tucker3) was applied to evaluate the performance of an electronic nose for following the ageing of red wines. The odour evaluation carried out with the electronic nose was combined with the quantitative analysis of volatile composition performed by GC-MS, and colour characterisation by UV-visible spectroscopy. Thanks to Tucker3, it was possible to understand connections among data obtained from these three different systems and to estimate the effect of different sources of variability on wine evaluation. In particular, the application of Tucker3 supplied a global visualisation of data structure, which was very informative to understand relationships between sensors responses and chemical composition of wines. The results obtained indicate that the analytical methods employed are useful tools to follow the wine ageing process, to differentiate wine samples according to ageing type (either in barrel or in stainless steel tanks with the addition of small oak wood pieces) and to the origin (French or American) of the oak wood. Finally, it was possible to designate the volatile compounds which play a major role in such a characterisation.

  13. Towards Liquid Chromatography Time-Scale Peptide Sequencing and Characterization of Post-Translational Modifications in the Negative-Ion Mode Using Electron Detachment Dissociation Tandem Mass Spectrometry

    DEFF Research Database (Denmark)

    Kjeldsen, Frank; Hørning, Ole B; Jensen, Søren S

    2008-01-01

    Electron detachment dissociation (EDD) of peptide poly-anions is gentle towards post-translational modifications (PTMs) and produces predictable and interpretable fragment ion types (a., x ions). However, EDD is considered an inefficient fragmentation technique and has not yet been implemented...... coverage) were sequenced by both EDD and ECD. The relative small overlap of identified BSA peptides demonstrates the complementarity of the two dissociation modes. Phosphopeptide mixtures from three trypsin-digested phosphoproteins were subjected to LC-EDD-MS/MS resulting in the identification of five...

  14. Numerical solution of nonlocal hydrodynamic Drude model for arbitrary shaped nano-plasmonic structures using finite elements method

    CERN Document Server

    Hiremath, Kirankumar R; Schmidt, Frank

    2012-01-01

    Nonlocal material response distinctively changes the optical properties of nano-plasmonic scatterers and waveguides. It is described by the nonlocal hydrodynamic Drude model, which -- in frequency domain -- is given by a coupled system of equations for the electric field and an additional polarization current of the electron gas modeled analogous to a hydrodynamic flow. Recent works encountered difficulties in dealing with the grad-div operator appearing in the governing equation of the hydrodynamic current. Therefore, in these studies the model has been simplified with the curl-free hydrodynamic current approximation; but this causes spurious resonances. In this paper we present a rigorous weak formulation in the Sobolev spaces $H(\\mathrm{curl})$ for the electric field and $H(\\mathrm{div})$ for the hydrodynamic current, which directly leads to a consistent discretization based on N\\'ed\\'elec's finite element spaces. Comparisons with the Mie theory results agree well. We also demonstrate the capability of the...

  15. Application of multi-way analysis to UV-visible spectroscopy, gas chromatography and electronic nose data for wine ageing evaluation.

    Science.gov (United States)

    Prieto, N; Rodriguez-Méndez, M L; Leardi, R; Oliveri, P; Hernando-Esquisabel, D; Iñiguez-Crespo, M; de Saja, J A

    2012-03-16

    In this study, a multi-way method (Tucker3) was applied to evaluate the performance of an electronic nose for following the ageing of red wines. The odour evaluation carried out with the electronic nose was combined with the quantitative analysis of volatile composition performed by GC-MS, and colour characterisation by UV-visible spectroscopy. Thanks to Tucker3, it was possible to understand connections among data obtained from these three different systems and to estimate the effect of different sources of variability on wine evaluation. In particular, the application of Tucker3 supplied a global visualisation of data structure, which was very informative to understand relationships between sensors responses and chemical composition of wines. The results obtained indicate that the analytical methods employed are useful tools to follow the wine ageing process, to differentiate wine samples according to ageing type (either in barrel or in stainless steel tanks with the addition of small oak wood pieces) and to the origin (French or American) of the oak wood. Finally, it was possible to designate the volatile compounds which play a major role in such a characterisation. Copyright © 2012 Elsevier B.V. All rights reserved.

  16. Determination of isoflavone content in soy, red clover, and kudzu dietary supplement materials by liquid chromatography-particle beam/electron ionization mass spectrometry.

    Science.gov (United States)

    Burdette, Carolyn Q; Marcus, R Kenneth

    2013-01-01

    Increased consumption of dietary supplements brings about important requirements of analytical methods to allow accurate and precise measurements of the chemical composition of these botanical materials. Presented here is the isoflavone content in proposed National Institute of Standards and Technology standard reference materials (SRMs) determined by LC-particle beam/electron ionization MS. Botanical materials (soy, red clover, and kudzu) are characterized for the content of a suite of five isoflavones (puerarin, daidzein, genistein, formononetin, and biochanin A). These compounds are of interest due to correlations with certain health benefits. An RP chromatographic separation was first optimized using UV-Vis spectrophotometric detection. The LC output was then introduced to an electron ionization source using a particle beam interface on an Extrel Benchmark MS system. The separation was carried out using a commercial C18 column and a linear gradient using water and methanol (both containing 0.1% trifluoroacetic acid as mobile phases A and B, at a flow rate of 1.0 mL/min over 40 min. LOD values for the isoflavones were determined to be at the ng level. Quantitation was performed using an internal standard (IS) approach with 7-hydroxy-4-chromone as the IS compound. The levels of isoflavones in the botanical products were determined for the proposed SRMs.

  17. A Displayer of Stellar Hydrodynamics Processes

    Science.gov (United States)

    Vigo, José Antonio Escartín; Senz, Domingo García

    The graphics display tool that we present here was originally developed to meet the needs of the Astronomy and Astrophysics group at the UPC (GAA). At present, it is used to display the plots obtained from hydrodynamic simulations using the SPH (smoothed particle hydrodynamics) method. It is, however, a generic program that can be used for other multidimensional hydrodynamic methods. The application combines the most widely used features of other programs (most of them commercial) such as GnuPlot, Surfer, Grapher, IDL, Voxler, etc.

  18. Non abelian hydrodynamics and heavy ion collisions

    Energy Technology Data Exchange (ETDEWEB)

    Calzetta, E. [Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires and IFIBA, CONICET, Ciudad Universitaria, Buenos Aires 1428 (Argentina)

    2014-01-14

    The goal of the relativistic heavy ion collisions (RHIC) program is to create a state of matter where color degrees of freedom are deconfined. The dynamics of matter in this state, in spite of the complexities of quantum chromodynamics, is largely determined by the conservation laws of energy momentum and color currents. Therefore it is possible to describe its main features in hydrodynamic terms, the very short color neutralization time notwithstanding. In this lecture we shall give a simple derivation of the hydrodynamics of a color charged fluid, by generalizing the usual derivation of hydrodynamics from kinetic theory to the non abelian case.

  19. Quantum ideal hydrodynamics on the lattice

    CERN Document Server

    Burch, Tommy

    2013-01-01

    After discussing the problem of defining the hydrodynamic limit from microscopic scales, we give an introduction to ideal hydrodynamics in the Lagrange picture, and show that it can be viewed as a field theory, which can be quantized using the usual Feynman sum-over-paths prescription. We then argue that this picture can be connected to the usually neglected thermal microscopic scale in the hydrodynamic expansion. After showing that this expansion is generally non-perturbative, we show how the lattice can be used to understand the impact quantum and thermal fluctuations can have on the fluid behavior.

  20. Non abelian hydrodynamics and heavy ion collisions

    CERN Document Server

    Calzetta, Esteban

    2013-01-01

    The goal of the relativistic heavy ion collisions (RHIC) program is to create a state of matter where color degrees of freedom are deconfined. The dynamics of matter in this state, in spite of the complexities of quantum chromodynamics, is largely determined by the conservation laws of energy momentum and color currents. Therefore it is possible to describe its main features in hydrodynamic terms, the very short color neutralization time notwithstanding. In this lecture we shall give a simple derivation of the hydrodynamics of a color charged fluid, by generalizing the usual derivation of hydrodynamics from kinetic theory to the non abelian case.

  1. Basic Principles of Chromatography

    Science.gov (United States)

    Ismail, Baraem; Nielsen, S. Suzanne

    Chromatography has a great impact on all areas of analysis and, therefore, on the progress of science in general. Chromatography differs from other methods of separation in that a wide variety of materials, equipment, and techniques can be used. [Readers are referred to references (1-19) for general and specific information on chromatography.]. This chapter will focus on the principles of chromatography, mainly liquid chromatography (LC). Detailed principles and applications of gas chromatography (GC) will be discussed in Chap. 29. In view of its widespread use and applications, high-performance liquid chromatography (HPLC) will be discussed in a separate chapter (Chap. 28). The general principles of extraction are first described as a basis for understanding chromatography.

  2. Radiative Hydrodynamic Models of Optical and Ultraviolet Emission from M Dwarf Flares

    CERN Document Server

    Allred, J C; Carlsson, M; Hawley, S L; Abbett, William P.; Allred, Joel C.; Carlsson, Mats; Hawley, Suzanne L.

    2006-01-01

    We report on radiative hydrodynamic simulations of M dwarf stellar flares and compare the model predictions to observations of several flares. The flares were simulated by calculating the hydrodynamic response of a model M dwarf atmosphere to a beam of non-thermal electrons. Radiative backwarming through numerous soft X-ray, extreme ultraviolet, and ultraviolet transitions are also included. The equations of radiative transfer and statistical equilibrium are treated in non-LTE for many transitions of hydrogen, helium and the Ca II ion allowing the calculation of detailed line profiles and continuum radiation. Two simulations were carried out, with electron beam fluxes corresponding to moderate and strong beam heating. In both cases we find the dynamics can be naturally divided into two phases: an initial gentle phase in which hydrogen and helium radiate away much of the beam energy, and an explosive phase characterized by large hydrodynamic waves. During the initial phase, lower chromospheric material is evap...

  3. Smoothed particle hydrodynamics and magnetohydrodynamics

    Science.gov (United States)

    Price, Daniel J.

    2012-02-01

    This paper presents an overview and introduction to smoothed particle hydrodynamics and magnetohydrodynamics in theory and in practice. Firstly, we give a basic grounding in the fundamentals of SPH, showing how the equations of motion and energy can be self-consistently derived from the density estimate. We then show how to interpret these equations using the basic SPH interpolation formulae and highlight the subtle difference in approach between SPH and other particle methods. In doing so, we also critique several 'urban myths' regarding SPH, in particular the idea that one can simply increase the 'neighbour number' more slowly than the total number of particles in order to obtain convergence. We also discuss the origin of numerical instabilities such as the pairing and tensile instabilities. Finally, we give practical advice on how to resolve three of the main issues with SPMHD: removing the tensile instability, formulating dissipative terms for MHD shocks and enforcing the divergence constraint on the particles, and we give the current status of developments in this area. Accompanying the paper is the first public release of the NDSPMHD SPH code, a 1, 2 and 3 dimensional code designed as a testbed for SPH/SPMHD algorithms that can be used to test many of the ideas and used to run all of the numerical examples contained in the paper.

  4. Fluctuating hydrodynamics for ionic liquids

    Science.gov (United States)

    Lazaridis, Konstantinos; Wickham, Logan; Voulgarakis, Nikolaos

    2017-04-01

    We present a mean-field fluctuating hydrodynamics (FHD) method for studying the structural and transport properties of ionic liquids in bulk and near electrified surfaces. The free energy of the system consists of two competing terms: (1) a Landau-Lifshitz functional that models the spontaneous separation of the ionic groups, and (2) the standard mean-field electrostatic interaction between the ions in the liquid. The numerical approach used to solve the resulting FHD-Poisson equations is very efficient and models thermal fluctuations with remarkable accuracy. Such density fluctuations are sufficiently strong to excite the experimentally observed spontaneous formation of liquid nano-domains. Statistical analysis of our simulations provides quantitative information about the properties of ionic liquids, such as the mixing quality, stability, and the size of the nano-domains. Our model, thus, can be adequately parameterized by directly comparing our prediction with experimental measurements and all-atom simulations. Conclusively, this work can serve as a practical mathematical tool for testing various theories and designing more efficient mixtures of ionic liquids.

  5. Direct electron transfer biosensor for hydrogen peroxide carrying nanocomplex composed of horseradish peroxidase and Au-nanoparticle – Characterization and application to bienzyme systems

    Directory of Open Access Journals (Sweden)

    Yusuke Okawa

    2015-09-01

    Full Text Available A reagentless electrochemical biosensor for hydrogen peroxide was fabricated. The sensor carries a monolayer of nanocomplex composed of horseradish peroxidase and Au-nanoparticle, and responds to hydrogen peroxide through the highly efficient direct electron transfer at a mild electrode potential without any soluble mediator. Formation of the nanocomplex was studied with visible spectroscopy and size exclusion chromatography. The sensor performance was analyzed based on a hydrodynamic electrochemical technique and enzyme kinetics. The sensor was applied to fabrication of sensors for glucose and uric acid through further modification of the nanocomplex-carrying electrode with the corresponding hydrogen peroxide-generating oxidases, glucose oxidase and urate oxidase, respectively.

  6. The Design of Miniature Electronic Control Unit for Variable Speed Hydrodynamic Clutch%调速型液力偶合器微型电控单元设计

    Institute of Scientific and Technical Information of China (English)

    刘丹丹; 邵万珍; 类延磊; 姜文震

    2015-01-01

    With variable speed hydraulic coupling for the study, according to the characteristics of their work to design a miniature electronic control unit for hydraulic coupling automation control. In this paper, using the FPGA programmable logic controller chip to deploy peripher-al circuits. Completed the detection of the variable speed hydraulic coupling on oil well pump and turbine speed, automatic control design. Hardware circuit comprises a signal acquisition module, a signal processing module, and a driving external device control module. The PID regulation technology has the characteristics of small overshoot on the speed and temperature, fast response and accurate.%以调速型液力偶合器为研究对象,根据其工作特点设计一套用于液力偶合器自动化控制的微型电控单元。该文采用FPGA可编程逻辑控制芯片,部署外围电路。完成调速型液力偶合器对油温、油压以及泵轮和涡轮速度的检测、自动控制偶合器的输出转速设计。硬件电路包括信号采集模块、信号处理模块以及驱动外部设备控制模块。采用PID调节技术,控制参数的超调量小、响应速度快、准确。

  7. Hydrodynamically driven colloidal assembly in dip coating.

    Science.gov (United States)

    Colosqui, Carlos E; Morris, Jeffrey F; Stone, Howard A

    2013-05-01

    We study the hydrodynamics of dip coating from a suspension and report a mechanism for colloidal assembly and pattern formation on smooth substrates. Below a critical withdrawal speed where the coating film is thinner than the particle diameter, capillary forces induced by deformation of the free surface prevent the convective transport of single particles through the meniscus beneath the film. Capillary-induced forces are balanced by hydrodynamic drag only after a minimum number of particles assemble within the meniscus. The particle assembly can thus enter the thin film where it moves at nearly the withdrawal speed and rapidly separates from the next assembly. The interplay between hydrodynamic and capillary forces produces periodic and regular structures below a critical ratio Ca(2/3)/sqrt[Bo] particles in suspension. The hydrodynamically driven assembly documented here is consistent with stripe pattern formations observed experimentally in dip coating.

  8. Adiabatic hydrodynamics: The eightfold way to dissipation

    CERN Document Server

    Haehl, Felix M; Rangamani, Mukund

    2015-01-01

    We provide a complete solution to hydrodynamic transport at all orders in the gradient expansion compatible with the second law constraint. The key new ingredient we introduce is the notion of adiabaticity, which allows us to take hydrodynamics off-shell. Adiabatic fluids are such that off-shell dynamics of the fluid compensates for entropy production. The space of adiabatic fluids is quite rich, and admits a decomposition into seven distinct classes. Together with the dissipative class this establishes the eightfold way of hydrodynamic transport. Furthermore, recent results guarantee that dissipative terms beyond leading order in the gradient expansion are agnostic of the second law. While this completes a transport taxonomy, we go on to argue for a new symmetry principle, an Abelian gauge invariance that guarantees adiabaticity in hydrodynamics. We suggest that this symmetry is the macroscopic manifestation of the microscopic KMS invariance. We demonstrate its utility by explicitly constructing effective ac...

  9. Quantification of trace fatty acid methyl esters in diesel fuel by using multidimensional gas chromatography with electron and chemical ionization mass spectrometry.

    Science.gov (United States)

    Webster, R L; Rawson, P M; Evans, D J; Marriott, P J

    2016-07-01

    Measurement of contamination of marine and naval diesel fuels (arising from product mixing or adulteration) with biodiesel or fatty acid methyl esters can be problematic, especially at very low levels. A suitable solution for this task for trace amounts of individual fatty acid methyl esters with resolution and quantification can be achieved by using a multidimensional gas chromatographic approach with electron and chemical ionization mass spectrometric detection. A unique column set comprising a 100 m methyl-siloxane nonpolar first dimension column and high-temperature ionic liquid column in the second dimension enabled identification of individual fatty acid methyl esters at below the lowest concentrations required to be reported in a diesel fuel matrix. Detection limits for individual fatty acid methyl esters compounds ranged from 0.5 to 5.0 mg/L, with excellent linearity up to 5000 mg/L and repeatability of the method from 1.3 to 3.2%. The method was applied to the analysis of diesel fuel samples with suspected biodiesel contamination. Contamination at 568 mg/L was calculated for an unknown sample and interpretation of the results permitted the determination of a likely source of the contamination.

  10. Semiautomatic method for the screening and determination of 23 organochlorine pesticides in horticultural samples by gas chromatography with electron-capture detection.

    Science.gov (United States)

    Columé, A; Cárdenas, S; Gallego, M; Valcárcel, M

    1999-07-16

    A rapid, simple, efficient device for the extraction-preconcentration of 23 organochlorine pesticides currently applied to vegetables is proposed. Pesticide residues are extracted from chopped samples by using a mixture of distilled water and light petroleum (1:1, v/v). After phase separation, an aliquot of the organic layer is continuously evaporated to dryness under a N2 stream as it is dropped into a glass tube containing distilled water. The aqueous phase, containing the analytes, is then passed through a miniaturized RP-C18 column for preconcentration, clean-up and subsequent elution with 150 microliters of ethyl acetate. A volume of 1 microliter of the extract containing pesticides is injected into the gas chromatograph, fitted with an electron-capture detector, for their selective determination. Limits of detection vary between 0.04 and 10 ng/ml, with linear ranges from 0.2 to 500 ng/ml; the average relative standard deviation at the low nanogram-per-millilitre level is 5.3%. The potential of the proposed method was realized by applying it to the screening/determination of organochlorine pesticides in horticultural commodities.

  11. Comparison of sample preparation methods combined with gas chromatography with electron-capture detection for the analysis of multipesticide residues in lotus seeds.

    Science.gov (United States)

    Miao, Qing; Kong, Weijun; Yang, Shihai; Yang, Meihua

    2013-06-01

    Sample preparation is always the major bottleneck in analytical chemistry for the determination of pesticide residues. Different sample preparation methods have been proposed due to the wide variety of pesticides used and the inherent complexity of the matrices. In this study, different sample preparation methods including SPE, matrix solid-phase dispersion, the quick, easy, cheap, efficient, rugged, and safe method, and a one-step completion method were compared and evaluated for extracting pesticides from lotus seeds. Analysis was carried out using GC with electron-capture detection. The results showed that good recoveries for tested pesticides were obtained by using Florisil in the four methods, and the extraction efficiency of the one-step completion method was superior to the other three methods. The one-step completion method was confirmed to have good linearity, reproducibility, stability, and recovery for the detection of 36 pesticides in lotus seed samples. The data collected from this study are expected to prove useful in regulating the concentration of the residues in lotus seeds, as well as in protecting human health from the hazards posed by these residues.

  12. Thermo--hydrodynamics As a Field Theory

    CERN Document Server

    Jezierski, Jacek

    2011-01-01

    The field theoretical description of thermo-hydrodynamics is given. It is based on the duality between the physical space--time and the "material space-time" which we construct here. The material space appearing in a natural way in the canonical formulation of the hydrodynamics is completed with a material time playing role of the field potential for temperature. Both Lagrangian and Hamiltonian formulations, the canonical structure, Poisson bracket, N\\"other theorem and conservation laws are discussed.

  13. Hydrodynamics of bacterial colonies: Phase diagrams

    Science.gov (United States)

    Lega, J.; Passot, T.

    2004-09-01

    We present numerical simulations of a recent hydrodynamic model describing the growth of bacterial colonies on agar plates. We show that this model is able to qualitatively reproduce experimentally observed phase diagrams, which relate a colony shape to the initial quantity of nutrients on the plate and the initial wetness of the agar. We also discuss the principal features resulting from the interplay between hydrodynamic motions and colony growth, as described by our model.

  14. Improvements to SOIL: An Eulerian hydrodynamics code

    Energy Technology Data Exchange (ETDEWEB)

    Davis, C.G.

    1988-04-01

    Possible improvements to SOIL, an Eulerian hydrodynamics code that can do coupled radiation diffusion and strength of materials, are presented in this report. Our research is based on the inspection of other Eulerian codes and theoretical reports on hydrodynamics. Several conclusions from the present study suggest that some improvements are in order, such as second-order advection, adaptive meshes, and speedup of the code by vectorization and/or multitasking. 29 refs., 2 figs.

  15. Relabeling symmetries in hydrodynamics and magnetohydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Padhye, N.; Morrison, P.J.

    1996-04-01

    Lagrangian symmetries and concomitant generalized Bianchi identities associated with the relabeling of fluid elements are found for hydrodynamics and magnetohydrodynamics (MHD). In hydrodynamics relabeling results in Ertel`s theorem of conservation of potential vorticity, while in MHD it yields the conservation of cross helicity. The symmetries of the reduction from Lagrangian (material) to Eulerian variables are used to construct the Casimir invariants of the Hamiltonian formalism.

  16. Rapid and simple determination of acrylamide in conventional cereal-based foods and potato chips through conversion to 3-[bis(trifluoroethanoyl)amino]-3-oxopropyl trifluoroacetate by gas chromatography coupled with electron capture and ion trap mass spectrometry detectors.

    Science.gov (United States)

    Russo, Mario Vincenzo; Avino, Pasquale; Centola, Angela; Notardonato, Ivan; Cinelli, Giuseppe

    2014-03-01

    A new, simple, rapid and fully validated method based on gas chromatography coupled with Electron capture and ion trap mass spectrometry detectors (GC-ECD and GC-IT/MS) is presented for quantitative analysis of acrylamide contaminant in conventional cereal-based foods and potato chips. Before analysis acrylamide was efficiently derivatized with trifluoroacetic anhydride, the effects of temperature, reaction time and catalyst on the acylation reaction were evaluated. Chromatographic analysis was performed on SE-54 capillary column; good retention and peak response of the acrylamide derivative achieved under the optimal conditions. The analytical method has been fully validated by assessment of the following parameters: LODs and LOQs (1 and 25ngg(-1) by GC-ECD and 2 and 36ngg(-1) by GC-IT/MS, with a Relative Standard Deviations acrylamide spiked at levels of 1, 20, 50 and 100ngg(-1)). Furthermore, the method proposed requires no clean-up step of the acrylamide derivative to be performed prior to injection. The developed method has been successfully applied to determine acrylamide in different commercial cereal-based foods (including French fries and potato chips).

  17. 皮革中短链氯化石蜡的GC—ECD测定方法探讨%Determination of Short Chain Chlorinated Paraffins in Leather by Gas Chromatography Combined Electron Capture Detector

    Institute of Scientific and Technical Information of China (English)

    马贺伟

    2012-01-01

    Analysis of short - chain chlorinated paraffins (SCCPs) in leather was studied using gas chromatography combined electron capture detector (GC -ECD). The results show the wide co -eluting chromatogram of SCCPs, and the response factors are dependent on the degree of chlorination. Significant interference problems from medium - chain chlorinated paraffins ( MC- CPs) are expected due to the difficult chromatographic separation. GC - ECD could not provide satisfactory results for scanning SCCPs in leather because of the low selectivity and the complex matrix influences.%采用气相色谱-电子捕获检测器(GC—ECD)对皮革中的短链氯化石蜡(SCCPs)进行测定。结果表明:SCCPs的GC—ECD共流出色谱峰保留时间跨度大,仪器响应值表现出对氯含量的依赖;中链氯化石蜡(MCCPs)的存在对SCCPs的分析过程干扰严重;实际皮革基质非常复杂,导致样品中SCCPs的定性困难。

  18. [Determination of short-chain chlorinated paraffins in ambient air using high-volume sampling combined with high resolutimi gas chromatography-electron capture negative ion-low resolution mass spectrometry].

    Science.gov (United States)

    Shi, Loimeng; Gao, Yuan; Hou, Xiaohong; Zhang, Haijun; Zhang, Yichi; Chen, Jiping

    2016-02-01

    An analytical method for quantifying short-chain chlorinated paraffins (SCCPs) in ambient air using high-volume sampling combined with high resolution gas chromatography-electron capture negative ion-low resolution mass spectrometry ( HRGC-ECNI-LRMS) was developed. An acidified silica gel column and a basic alumina column were used to optimize the cleanup procedures. The results showed a good linearity (R2>0. 99) between the total response factors and the degree of chlorination of SCCPs in the content range of 58. 1%-63. 3%. The limits of detection (S/N ≥3) and the limits of quantification (S/N ≥ 10) were 4. 2 and 12 µg, respectively. The method detection limit (MDL) for SCCPs was 0. 34 ng/m3 (n = 7). The recoveries of SCCPs in air samples were in the range of 81. 9% to 94. 2%. It is demonstrated that the method is suitable for the quantitative analysis of SCCPs in air samples.

  19. Rapid and sensitive detection of fipronil and its metabolites in edible oils by solid-phase extraction based on humic acid bonded silica combined with gas chromatography with electron capture detection.

    Science.gov (United States)

    Peng, Xi-Tian; Li, Yu-Nan; Xia, Hong; Peng, Li-Jun; Feng, Yu-Qi

    2016-06-01

    Solid-phase extraction based on humic acid bonded silica followed by gas chromatography with electron capture detection was developed to determine fipronil and its metabolites in edible oil. To achieve the best extraction performance, we systematically investigated a series of solid-phase extraction parameters. Under the optimized conditions, the method was validated according to linearity, recovery, and precision. Good linearities were obtained with R(2) more than 0.9996 for all analytes. The limits of detection were between 0.3 and 0.5 ng/g, and the recoveries ranged from 83.1 to 104.0% at three spiked concentrations with intra- and interday relative standard deviation values less than 8.7%. Finally, the proposed method was applied to determine fipronil and its metabolites in 11 edible oil samples taken from Wuhan markets. Fipronil was detectable in four samples with concentrations ranging from 3.0 to 5.2 ng/g. In China, the maximum residue limits of fipronil in some vegetables and maize are 20 and 100 ng/g (GB/T 2763-2014), respectively. The residues of fipronil and its metabolites in commercial edible oils might exhibit some potential threat to human health as a result of high consumption of edible oil as part of daily intake. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Use of pressurized liquid extraction (PLE)/gas chromatography-electron capture detection (GC-ECD) for the determination of biodegradation intermediates of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in soils.

    Science.gov (United States)

    Zhang, Baohong; Pan, Xiaoping; Cobb, George P; Anderson, Todd A

    2005-09-25

    A rapid, sensitive, and reproducible method was developed for quantitative determination of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) and its biodegradation intermediates, hexahydro-1-nitroso-3,5-dinitro-1,3,5-triazine (MNX), hexahydro-1,3-dinitroso-5-nitro-1,3,5-triazine (DNX), and hexahydro-1,3,5-trinitroso-1,3,5-triazine (TNX) in soils. RDX, MNX, DNX, or TNX was extracted from soil by pressurized liquid extraction (PLE), followed by cleanup using florisil. Instrumental analysis was performed using gas chromatography with electron capture detection (GC-ECD), which was highly sensitive to the parent explosive and its metabolites. The method detection limits (MDLs) were 0.243, 0.095, 0.138, and 0.057 ng/g for RDX, MNX, DNX, and TNX, respectively. The method gave high recovery (98-102%), good precision (0.22-5.14%), and reproducibility, and proved to be suitable for real world sample analysis.

  1. Hydrodynamics of soft active matter

    Science.gov (United States)

    Marchetti, M. C.; Joanny, J. F.; Ramaswamy, S.; Liverpool, T. B.; Prost, J.; Rao, Madan; Simha, R. Aditi

    2013-07-01

    This review summarizes theoretical progress in the field of active matter, placing it in the context of recent experiments. This approach offers a unified framework for the mechanical and statistical properties of living matter: biofilaments and molecular motors in vitro or in vivo, collections of motile microorganisms, animal flocks, and chemical or mechanical imitations. A major goal of this review is to integrate several approaches proposed in the literature, from semimicroscopic to phenomenological. In particular, first considered are “dry” systems, defined as those where momentum is not conserved due to friction with a substrate or an embedding porous medium. The differences and similarities between two types of orientationally ordered states, the nematic and the polar, are clarified. Next, the active hydrodynamics of suspensions or “wet” systems is discussed and the relation with and difference from the dry case, as well as various large-scale instabilities of these nonequilibrium states of matter, are highlighted. Further highlighted are various large-scale instabilities of these nonequilibrium states of matter. Various semimicroscopic derivations of the continuum theory are discussed and connected, highlighting the unifying and generic nature of the continuum model. Throughout the review, the experimental relevance of these theories for describing bacterial swarms and suspensions, the cytoskeleton of living cells, and vibrated granular material is discussed. Promising extensions toward greater realism in specific contexts from cell biology to animal behavior are suggested, and remarks are given on some exotic active-matter analogs. Last, the outlook for a quantitative understanding of active matter, through the interplay of detailed theory with controlled experiments on simplified systems, with living or artificial constituents, is summarized.

  2. Resonance shifts and spill-out effects in self-consistent hydrodynamic nanoplasmonics

    DEFF Research Database (Denmark)

    Toscano, Giuseppe; Straubel, Jakob; Kwiatkowski, Alexander;

    2015-01-01

    The standard hydrodynamic Drude model with hard-wall boundary conditions can give accurate quantitative predictions for the optical response of noble-metal nanoparticles. However, it is less accurate for other metallic nanosystems, where surface effects due to electron density spill-out in free s...

  3. Detection with flash gas chromatography electronic nose of the general influences of glutathione, ascorbic acid, tannin and carbon dioxide treatments on the volatile profiles of white wines of feteasca regala

    Directory of Open Access Journals (Sweden)

    Antoce Arina Oana

    2017-01-01

    Full Text Available The present work aimed to determine some of the influences of the treatments with glutathione (GSH, ascorbic acid (AA, catechinic tannin (T and carbon dioxide (CO2 during winemaking or bottling on the volatile profiles of white wines of Feteasca Regala. The study is based on the use of a flash gas chromatography electronic nose, which is able to discriminate various clusters of wine samples prepared with various combinations of antioxidants. The treatments that induce enough differences in the volatile profiles of the wine that the electronic nose is able to discriminate are likely to be discriminated also by the consumers. When the electronic nose does not discriminate the clusters of samples with certain treatments it is very likely that those treatments are not sufficient to induce a practically important difference in the aromatic profile of wines. The main detectable influences of the antioxidant treatments are presented and discussed. The treatment of musts with AA (50 mg/l clearly influences the volatile profile of the wines, reducing their aromatic complexity. The treatment during bottling with catechinic tannin (20 mg/l does not seem to have an important influence of the profile of the wines produced with the addition of AA and or GSH. The addition of carbon dioxide during bottling does not show much influence one year after bottling, but it shows that in the samples most prone to oxidation, a difference is present. The CO2 treated wines belonging to the cluster of wines treated with 40 mg/l GSH and 50 mg/l AA have distinct profiles, different from those not protected and closer to the clusters of the less oxidised wines. The treatment of musts with GSH shows clear influences at the dose of 40 mg/l, but for the lower dose of 20 mg/l GSH in Feteasca regala wines it is difficult to identify differences compared to the wines included in the cluster of samples not treated with GSH. This finding is particularly relevant as the

  4. 气相色谱-质谱法测定电子产品中的四溴双酚-A%Determination of tetrabromobisphenol-A in electronic products by gas chromatography-mass spectrometry

    Institute of Scientific and Technical Information of China (English)

    肖进进; 富玉; 林舒; 张姝

    2011-01-01

    A method for the determination of tetrabromobisphenol-A ( TBBP-A ) in electronic products was developed by gas chromatography-mass spectrometry ( GC-MS ). The TBBP-A was extracted from electronic products by automatic digestion oven with acetone and concentrated by the evaporation of solvent. It was redissolved in methylene chloride , back-extracted by potassium carbonate solution and reacted with acetic anhydride. The derivative was extracted by hexane and determined by GC-MS. The linear calibration curve was obtained in the range of 0.25 - 5.0 mg/L with a correlation coefficient of 0.996. The detection limit of the method was 0.05 mg/kg. The recoveries were 87.3% - 104.1% and the relative standard deviations were 5.6% - 8.5%. The method is accurate and sensitive, and it is suitable for the analysis of tetrabromobisphenol-A in electronic products.%建立了电子产品中四溴双酚-A(TBBP-A)的气相色谱-质谱联用(GC-MS)检测方法.样品经丙酮提取后挥发至干,经二氯甲烷重新溶解后,用碳酸钾溶液反提取,反提取液与乙酸酐衍生化反应.衍生产物经正己烷提取后,采用GC-MS进行分析.结果表明,方法的线性范围为0.25~5.0 mg/L,相关系数为0.996;方法的检出限为0.05mg/kg;平均回收率为87.3%~104.1%,相对标准偏差为5.6%~8.5%.该方法准确、灵敏,可用于实际电子产品中四溴双酚-A的分析.

  5. Status of the Dual-Axis Radiographic Hydrodynamics Test Facility

    Energy Technology Data Exchange (ETDEWEB)

    Burns, M.J.; Allison, P.W.; Carlson, R.L.; Downing, J.N.; Moir, D.C.; Shurter, R.P.

    1996-09-01

    The Dual-Axis Radiographic Hydrodynamics Test (DARHT) Facility will employ two electron linear induction accelerators to produce intense, bremsstrahlung x-ray pulses for flash radiography with sub-millimeter spatial resolution of very dense (attentuations>10{sup 5}), dynamic objects. We will produce an intense x-ray pulse using a 19.75-MeV, 3.5-4 kA, 60-ns flattop electron beam focused on a tungsten target. A 3.75-MeV injector with either a cold velvet cathode or a laser-driven photocathode will produce a beam to be accelerated through a series of 64 ferrite-loaded induction cells with solenoid focusing. Accelerator technology demonstrations have been underway for several years at the DARHT Integrated Test Stand and results including beam energy, emittance, and beam breakup measurements are discussed.

  6. Hydrodynamic Modeling and Its Application in AUC.

    Science.gov (United States)

    Rocco, Mattia; Byron, Olwyn

    2015-01-01

    The hydrodynamic parameters measured in an AUC experiment, s(20,w) and D(t)(20,w)(0), can be used to gain information on the solution structure of (bio)macromolecules and their assemblies. This entails comparing the measured parameters with those that can be computed from usually "dry" structures by "hydrodynamic modeling." In this chapter, we will first briefly put hydrodynamic modeling in perspective and present the basic physics behind it as implemented in the most commonly used methods. The important "hydration" issue is also touched upon, and the distinction between rigid bodies versus those for which flexibility must be considered in the modeling process is then made. The available hydrodynamic modeling/computation programs, HYDROPRO, BEST, SoMo, AtoB, and Zeno, the latter four all implemented within the US-SOMO suite, are described and their performance evaluated. Finally, some literature examples are presented to illustrate the potential applications of hydrodynamics in the expanding field of multiresolution modeling.

  7. Anisotropic hydrodynamics for conformal Gubser flow

    Energy Technology Data Exchange (ETDEWEB)

    Strickland, Michael; Nopoush, Mohammad [Kent State University, Kent OH 44242 (United States); Ryblewski, Radoslaw [The H. Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, PL-31342 Kraków (Poland)

    2016-12-15

    In this proceedings contribution, we review the exact solution of the anisotropic hydrodynamics equations for a system subject to Gubser flow. For this purpose, we use the leading-order anisotropic hydrodynamics equations which assume that the distribution function is ellipsoidally symmetric in local-rest-frame momentum. We then prove that the SO(3){sub q} symmetry in de Sitter space constrains the anisotropy tensor to be of spheroidal form with only one independent anisotropy parameter remaining. As a consequence, the exact solution reduces to the problem of solving two coupled non-linear differential equations. We show that, in the limit that the relaxation time goes to zero, one obtains Gubser's ideal hydrodynamic solution and, in the limit that the relaxation time goes to infinity, one obtains the exact free streaming solution obtained originally by Denicol et al. For finite relaxation time, we solve the equations numerically and compare to the exact solution of the relaxation-time-approximation Boltzmann equation subject to Gubser flow. Using this as our standard, we find that anisotropic hydrodynamics describes the spatio-temporal evolution of the system better than all currently known dissipative hydrodynamics approaches.

  8. Chromatography resin support

    Science.gov (United States)

    Dobos, James G.

    2002-01-01

    An apparatus and method of using an improved chromatography resin support is disclosed. The chromatography support platform is provided by a stainless steel hollow cylinder adapted for being inserted into a chromatography column. An exterior wall of the stainless steel cylinder defines a groove for carrying therein an "O"-ring. The upper surface of the stainless steel column is covered by a fine stainless steel mesh welded to the edges of the stainless steel cylinder. When placed upon a receiving ledge defined within a chromatography column, the "O"-ring provides a fluid tight seal with the inner edge wall of the chromatography cylinder. The stainless steel mesh supports the chromatography matrix and provides a back flushable support which is economical and simple to construct.

  9. Separation techniques: Chromatography

    Science.gov (United States)

    Coskun, Ozlem

    2016-01-01

    Chromatography is an important biophysical technique that enables the separation, identification, and purification of the components of a mixture for qualitative and quantitative analysis. Proteins can be purified based on characteristics such as size and shape, total charge, hydrophobic groups present on the surface, and binding capacity with the stationary phase. Four separation techniques based on molecular characteristics and interaction type use mechanisms of ion exchange, surface adsorption, partition, and size exclusion. Other chromatography techniques are based on the stationary bed, including column, thin layer, and paper chromatography. Column chromatography is one of the most common methods of protein purification. PMID:28058406

  10. Fun with Paper Chromatography.

    Science.gov (United States)

    Coleman, Dava; Hounshell, Paul B.

    1982-01-01

    Discusses paper chromatographic techniques and provides examples of typical classroom activities. Includes description of retardation values obtained during chromatography exercises and suggests using them for math lessons. (JN)

  11. Low density solvent based dispersive liquid-liquid microextraction with gas chromatography-electron capture detection for the determination of cypermethrin in tissues and blood of cypermethrin treated rats.

    Science.gov (United States)

    Mudiam, Mohana Krishna Reddy; Jain, Rajeev; Maurya, Shailendra Kumar; Khan, Haider A; Bandyopadhyay, Sanghamitra; Murthy, R C

    2012-05-01

    A simple and rapid method to determine the cypermethrin (CYP) insecticide in rat tissues (kidney, liver and brain) and blood has been developed for the first time using low density solvent-dispersive liquid-liquid microextraction (LDS-DLLME) followed by gas chromatography-electron capture detector (GC-ECD) analysis. Initially, tissue samples containing CYP were homoginized in acetone. Subsequently, homogenate was mixed with n-hexane (extraction solvent) and the mixture was rapidly injected into water. The upper n-hexane layer was collected in a separate microtube and injected into GC-ECD for analysis. Blood samples were diluted with ultrapure water and subjected to DLLME through similar procedure. Parameters such as type and volume of disperser and extraction solvent, salting out effect and extraction time, which can affect the extraction efficiency of DLLME, were optimized. Method was validated by investigating linearity, precision, recovery, limit of detection (LOD) and quantification (LOQ). LODs in tissue were in the range of 0.043-0.314 ng mg(-1) and for blood it was 8.6 ng mL(-1) with a signal to noise ratio of 3:1. LOQs in tissue were in the range of 0.143-1.03 ng mg(-1) and for blood it was 28.3 ng mL(-1) with a signal to noise ratio of 10:1. Mean recoveries of CYP at three different concentation levels in all the matrices were found to be in the range of 81.6-103.67%. The results show that, LDS-DLLME coupled with GC-ECD offers a simple, rapid and efficient technique for extraction and determination of CYP in rat tissues and blood samples, which in turn would be useful for toxicological studies of CYP.

  12. Analysis of nicotine solution of electronic cigarette by pyrolysis-gas chromatography mass spectrometry%热裂解气相色谱质谱检测电子烟烟碱液

    Institute of Scientific and Technical Information of China (English)

    张伟童; 王小伍

    2014-01-01

    在电子烟烟碱液未经预处理以及经历在空气中多次蒸馏预处理两种条件下,采用热裂解气相色谱质谱(Py-GCMS)检测了电子烟烟碱液组分变化情况。未经预处理进行Py-GCMS时,由于烟碱液气化时与空气隔绝,气体组分的物质类型稳定,包含丙二醇、丙三醇和尼古丁,尼古丁含量低于10%;经历高温下空气中反复蒸馏预处理的烟碱液,气化后组分的物质类型和比例都与预处理的温度有关,蒸馏温度160℃时,尼古丁含量达到了21.07%。%Pyrolysis-Gas chromatography mass spectrometry method is used to analyze the relation between temperature and component and content of nicotine solution of electronic cigarette at two situations, namely without pretreatment on nicotine solution and after nicotine solution being evaporated five times in the air at set temperature. For the former situation, nicotine solution shows stable components, Propylene Glycol, Glycerin and nicotine, in which the content of nicotine is always lower than 10%. This is because nicotine solution is isolated from air when evaporating. For the latter situation, the component and content all change with evaporating temperature. When evaporating temperature is 160 ℃, the content of nicotine comes to 21.07%.

  13. Application of modified hollow fiber liquid phase microextraction in conjunction with chromatography-electron capture detection for quantification of acrylamide in waste water samples at ultra-trace levels.

    Science.gov (United States)

    Sobhi, Hamid Reza; Ghambarian, Mahnaz; Behbahani, Mohammad; Esrafili, Ali

    2017-03-03

    Herein, a simple and sensitive method was successfully developed for the extraction and quantification of acrylamide in water samples. Initially, acrylamide was derivatized through a bromination process. Subsequently, a modified hollow-fiber liquid-phase microextraction was applied for the extraction of the brominated acrylamide from a 10-ml portion of an aqueous sample. Briefly, in this method, the derivatized acrylamide (2,3-dibromopropionamide) was extracted from the aqueous sample into a thin layer of an organic solvent sustained in pores of a porous hollow fiber. Then, it was back-extracted using a small volume of organic acceptor solution (acetonitril, 25μl) located inside the lumen of the hollow fiber followed by gas chromatography-electron capture detection (GC-ECD). The optimal conditions were examined for the extraction of the analyte such as: the organic solvent: dihexyl ether+10% tri-n-octyl phosphine oxide; stirring rate: 750rpm; no salt addition and 30min extraction time. These optimal extraction conditions allowed excellent enrichment factor values for the method. Enrichment factor, detection limit (S/N=3) and dynamic linear range of 60, 2ngL(-1) and 50-1000ngL(-1) to be determined for the analyte. The relative standard deviations (RSD%) representing precision of the method were in the range of 2.2-5.8 based on the average of three measurements. Accuracy of the method was tested by the relative recovery experiments on spiked samples, with results ranging from 93 to 108%. Finally, the method proved to be simple, rapid, and cost-effective for routine screen of acrylamide-contaminated highly-complicated untreated waste water samples. Copyright © 2017 Elsevier B.V. All rights reserved.

  14. Combining drop-to-drop solvent microextraction with gas chromatography/mass spectrometry using electronic ionization and self-ion/molecule reaction method to determine methoxyacetophenone isomers in one drop of water.

    Science.gov (United States)

    Wu, Hui-Fen; Yen, Jyh-Hao; Chin, Chen-Che

    2006-03-01

    A novel analytical technique termed drop-to-drop solvent microextraction (DDSME) was developed to determine three methoxyacetophenone isomers in one drop of water, which were then detected by gas chromatography/mass spectrometry using electronic ionization mass spectrometry for quantification analysis and self-ion/molecule reaction/tandem mass spectrometry for isomer differentiation. The best optimum parameters for the DDSME technique were as follows: extraction time, 5 min; using toluene as the extraction solvent; volume of extraction solvent, 0.5 microL and no salt addition. The advantages of this method are rapidity, convenience, ease of operation, simplicity of the device, and extremely little solvent and sample consumption. The limit of detection (LOD) for this technique was 1 ng/mL. The relative standard deviation was less than 2.6% (n = 5). The linear range of the calibration curve of DDSME is from 0.01 to 5 microg/mL with correlation coefficient (r2) of >0.954. In the comparison of the LOD of DDSME with other sample pretreatment methods including liquid/liquid extraction (LLE), single-drop microextraction (SDME), solid-phase microextraction (SPME), and liquid-phase microextraction (LPME) using a dual gauge microsyringe with hollow fiber methods, this method shows much better in sensitivity than the LLE (25 ng/mL) and it is compatible with SDME (0.5 ng/mL), SPME (0.5 ng/mL), and LPME using a dual gauge microsyringe with a hollow fiber (1 ng/mL). However, DDSME was more convenient than the LPME using a dual gauge microsyringe with a hollow fiber method and much lower cost than the SPME technique.

  15. Analysis of Sheng-Mai-San, a Ginseng-Containing Multiple Components Traditional Chinese Herbal Medicine Using Liquid Chromatography Tandem Mass Spectrometry and Physical Examination by Electron and Light Microscopies.

    Science.gov (United States)

    Cheng, Yung-Yi; Tsai, Tung-Hu

    2016-09-01

    Sheng-Mai-San is a multi-component traditional Chinese herbal preparation. Due to the fact granulated additives, such as starch, carboxymethyl cellulose, lactose and raw herbal powder may alter the content of the bioactive markers in the herbal products, a developed ultra-high performance liquid chromatography tandem mass spectrometry (UHPLC-MS/MS) method was used to measure the herbal biomarkers of ginsenoside Rb₁, Rb₂, Rc, Rd, Re, Rg₁, Rh₁, compound K, ophiopogonin D and schizandrin from the Sheng-Mai-San herbal formulation. Besides, scanning electron microscopy (SEM) was used to observe the morphology of the herbal granular powders. Light microscopy with Congo red and iodine-KI reagent staining was used to identify the cellulose fiber and cornstarch added to pharmaceutical herbal products. The swelling power (SP), water solubility index (WSI), and crude fiber analysis were used to determine the contents of cellulose fiber and cornstarch in pharmaceutical herbal products. In this study, we developed a novel skill to assess the quantification of appended cornstarch in pharmaceutical herbal products using Aperio ImageScope software. Compared with the traditional cornstarch analysis, our analysis method is a rapid, simple and conversion process which could be applied to detect the percentage of added cornstarch in unknown powder products. The various range of the herbal content for the five pharmaceutical manufacturers varied by up to several hundreds-fold. The physical examination reveals that the morphology of the herbal pharmaceutical products is rough and irregular with sharp layers. This study provides a reference standard operating procedure guide for the quality control of the Chinese herbal pharmaceutical products of Sheng-Mai-San.

  16. Simultaneous analysis of organochlorine pesticides and polychlorinated biphenyls in air samples by using accelerated solvent extraction (ASE) and solid-phase micro-extraction (SPME) coupled to gas chromatography dual electron capture detection.

    Science.gov (United States)

    Mokbel, Haifaa; Al Dine, Enaam Jamal; Elmoll, Ahmad; Liaud, Céline; Millet, Maurice

    2016-04-01

    An analytical method associating accelerated solvent extraction (ASE) and solid-phase micro-extraction (SPME) in immersion mode combined with gas chromatography dual electrons capture detectors (SPME-GC-2ECD) has been developed and studied for the simultaneous determination of 19 organochlorine pesticides (OCPs) and 22 polychlorinated biphenyls (PCBs) in air samples (active and XAD-2 passive samplers). Samples were extracted with ASE with acetonitrile using the following conditions: temperature, 150 °C; pressure, 1500 psi; static, 15 min; cycles, 3; purge, 300 s; flush, 100 %. Extracts were reduced to 1 mL, and 500 μL of this extract, filled with deionised water, was subject to SPME extraction. Experimental results indicated that the proposed method attained the best extraction efficiency under the optimised conditions: extraction of PCB-OCP mixture using 100-μm PDMS fibre at 80 °C for 40 min with no addition of salt. The performance of the proposed ASE-SPME-GC-2ECD methodology with respect to linearity, limit of quantification and detection was evaluated by spiking of XAD-2 resin with target compounds. The regression coefficient (R (2)) of most compounds was found to be high of 0.99. limits of detection (LODs) are between 0.02 and 4.90 ng m(-3), and limits of quantification (LOQs) are between 0.05 and 9.12 ng m(-3) and between 0.2 and 49 ng/sampler and 0.52 and 91 ng/sampler, respectively, for XAD-2 passive samplers. Finally, a developed procedure was applied to determine selected PCBs and OCPs in the atmosphere.

  17. Hollow fiber liquid-liquid-liquid microextraction followed by solid-phase microextraction and in situ derivatization for the determination of chlorophenols by gas chromatography-electron capture detection.

    Science.gov (United States)

    Saraji, Mohammad; Ghani, Milad

    2015-10-30

    A method based on the combination of hollow fiber liquid-liquid-liquid microextraction and solid-phase microextraction (SPME) followed by gas chromatography-electron capture detection was developed for the determination of chlorophenols in water and wastewater samples. Silica microstructures fabricated on the surface of a stainless steel wire were coated by an organic solvent and used as a SPME fiber. The analytes were extracted through a hollow fiber membrane containing n-decane from sample solution to an alkaline aqueous acceptor phase. They were then extracted and in situ derivatized on the SPME fiber using acetic anhydride. Experimental parameters such as the type of extraction solvent, acceptor phase NaOH concentration, donor phase HCl concentration, the amount of derivatizing reagent, salt concentration, stirring rate and extraction time were investigated and optimized. The precision of the method for the analytes at 0.02-30μgL(-1) concentration level ranged from 7.1 to 10.2% (as intra-day relative standard deviation) and 6.4 to 9.8% (as inter-day relative standard deviation). The linear dynamic ranges were in the interval of 5-500μgL(-1), 0.05-5μgL(-1), 0.02-1μgL(-1) and 0.001-0.5μgL(-1) for 2-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol and pentachlorophenol, respectively. The enrichment factors were between 432 and 785. The limits of detection were in the range of 0.0004-1.2μgL(-1). Tap water, well water and wastewater samples were also analyzed to evaluate the method capability for real sample analysis.

  18. Status and future of hydrodynamical model atmospheres

    CERN Document Server

    Ludwig, H G

    2004-01-01

    Since about 25 years ago work has been dedicated to the development of hydrodynamical model atmospheres for cool stars (of A to T spectral type). Despite their obviously sounder physical foundation in comparison with standard hydrostatic models, their general application has been rather limited. In order to understand why this is, and how to progress, we review the present status of hydrodynamical modelling of cool star atmospheres. The development efforts were and are motivated by the theoretical interest of understanding the dynamical processes operating in stellar atmospheres. To show the observational impact, we discuss examples in the fields of spectroscopy and stellar structure where hydrodynamical modelling provided results on a level qualitatively beyond standard models. We stress present modelling challenges, and highlight presently possible and future observations that would be particularly valuable in the interplay between model validation and interpretation of observables, to eventually widen the ...

  19. First Numerical Simulations of Anomalous Hydrodynamics

    CERN Document Server

    Hongo, Masaru; Hirano, Tetsufumi

    2013-01-01

    Anomalous hydrodynamics is a low-energy effective theory that captures effects of quantum anomalies. We develop a numerical code of anomalous hydrodynamics and apply it to dynamics of heavy-ion collisions, where anomalous transports are expected to occur. This is the first attempt to perform fully non-linear numerical simulations of anomalous hydrodynamics. We discuss implications of the simulations for possible experimental observations of anomalous transport effects. From analyses of the charge-dependent elliptic flow parameters ($v_2^\\pm$) as a function of the net charge asymmetry $A_\\pm$, we quantitatively verify that the linear dependence of $\\Delta v_2 \\equiv v_2^- - v_2^+$ on the net charge asymmetry $A_\\pm$ cannot be regarded as a sensitive signal of anomalous transports, contrary to previous studies. We, however, find that the intercept $\\Delta v_2(A_\\pm=0)$ is sensitive to anomalous transport effects.

  20. Hydrodynamics of a unitary Bose gas

    Science.gov (United States)

    Man, Jay; Fletcher, Richard; Lopes, Raphael; Navon, Nir; Smith, Rob; Hadzibabic, Zoran

    2016-05-01

    In general, normal-phase Bose gases are well described by modelling them as ideal gases. In particular, hydrodynamic flow is usually not observed in the expansion dynamics of normal gases, and is more readily observable in Bose-condensed gases. However, by preparing strongly-interacting clouds, we observe hydrodynamic behaviour in normal-phase Bose gases, including the `maximally' hydrodynamic unitary regime. We avoid the atom losses that often hamper experimental access of this regime by using radio-frequency injection, which switches on interactions much faster than trap or loss timescales. At low phase-space densities, we find excellent agreement with a collisional model based on the Boltzmann equation. At higher phase-space densities our results show a deviation from this model in the vicinity of an Efimov resonance, which cannot be accounted for by measured losses.

  1. Hydrodynamics of the Chiral Dirac Spectrum

    CERN Document Server

    Liu, Yizhuang; Zahed, Ismail

    2016-01-01

    We derive a hydrodynamical description of the eigenvalues of the chiral Dirac spectrum in the vacuum and in the large $N$ (volume) limit. The linearized hydrodynamics supports sound waves. The stochastic relaxation of the eigenvalues is captured by a hydrodynamical instanton configuration which follows from a pertinent form of Euler equation. The relaxation from a phase of localized eigenvalues and unbroken chiral symmetry to a phase of de-localized eigenvalues and broken chiral symmetry occurs over a time set by the speed of sound. We show that the time is $\\Delta \\tau=\\pi\\rho(0)/2\\beta N$ with $\\rho(0)$ the spectral density at zero virtuality and $\\beta=1,2,4$ for the three Dyson ensembles that characterize QCD with different quark representations in the ergodic regime.

  2. Hydrodynamics of bacterial colonies: A model

    Science.gov (United States)

    Lega, J.; Passot, T.

    2003-03-01

    We propose a hydrodynamic model for the evolution of bacterial colonies growing on soft agar plates. This model consists of reaction-diffusion equations for the concentrations of nutrients, water, and bacteria, coupled to a single hydrodynamic equation for the velocity field of the bacteria-water mixture. It captures the dynamics inside the colony as well as on its boundary and allows us to identify a mechanism for collective motion towards fresh nutrients, which, in its modeling aspects, is similar to classical chemotaxis. As shown in numerical simulations, our model reproduces both usual colony shapes and typical hydrodynamic motions, such as the whirls and jets recently observed in wet colonies of Bacillus subtilis. The approach presented here could be extended to different experimental situations and provides a general framework for the use of advection-reaction-diffusion equations in modeling bacterial colonies.

  3. Dynamo efficiency controlled by hydrodynamic bistability.

    Science.gov (United States)

    Miralles, Sophie; Herault, Johann; Herault, Johann; Fauve, Stephan; Gissinger, Christophe; Pétrélis, François; Daviaud, François; Dubrulle, Bérengère; Boisson, Jean; Bourgoin, Mickaël; Verhille, Gautier; Odier, Philippe; Pinton, Jean-François; Plihon, Nicolas

    2014-06-01

    Hydrodynamic and magnetic behaviors in a modified experimental setup of the von Kármán sodium flow-where one disk has been replaced by a propeller-are investigated. When the rotation frequencies of the disk and the propeller are different, we show that the fully turbulent hydrodynamic flow undergoes a global bifurcation between two configurations. The bistability of these flow configurations is associated with the dynamics of the central shear layer. The bistable flows are shown to have different dynamo efficiencies; thus for a given rotation rate of the soft-iron disk, two distinct magnetic behaviors are observed depending on the flow configuration. The hydrodynamic transition controls the magnetic field behavior, and bifurcations between high and low magnetic field branches are investigated.

  4. Hydrodynamics, resurgence and trans-asymptotics

    CERN Document Server

    Basar, Gokce

    2015-01-01

    The second-order hydrodynamical description of a homogeneous conformal plasma that undergoes a boost- invariant expansion is given by a single nonlinear ordinary differential equation, whose resurgent asymptotic properties we study, developing further the recent work of Heller and Spalinski [Phys. Rev. Lett. 115, 072501 (2015)]. Resurgence clearly identifies the non-hydrodynamic modes that are exponentially suppressed at late times, analogous to the quasi-normal-modes in gravitational language, organizing these modes in terms of a trans-series expansion. These modes are analogs of instantons in semi-classical expansions, where the damping rate plays the role of the instanton action. We show that this system displays the generic features of resurgence, with explicit quantitative relations between the fluctuations about different orders of these non-hydrodynamic modes. The imaginary part of the trans-series parameter is identified with the Stokes constant, and the real part with the freedom associated with init...

  5. Holography, Hydrodynamization and Heavy-Ion Collisions

    CERN Document Server

    Heller, Michal P

    2016-01-01

    In the course of the past several years holography has emerged as an ab initio tool in exploring strongly-time-dependent phenomena in gauge theories. These lecture notes overview recent developments in this area driven by phenomenological questions concerning applicability of hydrodynamics under extreme conditions occurring in ultrarelativistic heavy-ion collisions at RHIC and LHC. The topics include equilibration time scales, holographic collisions and hydrodynamization from the point of view of the asymptotic character of the hydrodynamic gradient expansion. The emphasis is put on concepts rather than calculational techniques and particular attention is devoted to present these developments in the context of the most recent advances and some of the open problems.

  6. The RAGE radiation-hydrodynamic code

    CERN Document Server

    Gittings, Michael; Clover, Michael; Betlach, Thomas; Byrne, Nelson; Coker, Robert; Dendy, Edward; Hueckstaedt, Robert; New, Kim; Oakes, W Rob; Ranta, Dale; Stefan, Ryan

    2008-01-01

    We describe RAGE, the ``Radiation Adaptive Grid Eulerian'' radiation-hydrodynamics code, including its data structures, its parallelization strategy and performance, its hydrodynamic algorithm(s), its (gray) radiation diffusion algorithm, and some of the considerable amount of verification and validation efforts. The hydrodynamics is a basic Godunov solver, to which we have made significant improvements to increase the advection algorithm's robustness and to converge stiffnesses in the equation of state. Similarly, the radiation transport is a basic gray diffusion, but our treatment of the radiation-material coupling, wherein we converge nonlinearities in a novel manner to allow larger timesteps and more robust behavior, can be applied to any multi-group transport algorithm.

  7. Hydrodynamic simulations with the Godunov SPH

    CERN Document Server

    Murante, Giuseppe; Brunino, Riccardo; Cha, Suneg-Hoon

    2011-01-01

    We present results based on an implementation of the Godunov Smoothed Particle Hydrodynamics (GSPH), originally developed by Inutsuka (2002), in the GADGET-3 hydrodynamic code. We first review the derivation of the GSPH discretization of the equations of moment and energy conservation, starting from the convolution of these equations with the interpolating kernel. The two most important aspects of the numerical implementation of these equations are (a) the appearance of fluid velocity and pressure obtained from the solution of the Riemann problem between each pair of particles, and (b the absence of an artificial viscosity term. We carry out three different controlled hydrodynamical three-dimensional tests, namely the Sod shock tube, the development of Kelvin-Helmholtz instabilities in a shear flow test, and the "blob" test describing the evolution of a cold cloud moving against a hot wind. The results of our tests confirm and extend in a number of aspects those recently obtained by Cha (2010): (i) GSPH provi...

  8. Hydrodynamic dispersion broadening of a sedimentation front

    Science.gov (United States)

    Martin, J.; Rakotomalala, N.; Salin, D.

    1994-10-01

    Hydrodynamic dispersion is responsible for the spreading of the sedimentation front even in a noncolloidal monodisperse suspension. Measurements of the broadening of the top front observed during sedimentation have been used in determining the hydrodynamic dispersion coefficient. Hindered settling has an opposed effect and leads to the self-sharpening of the front. Both effects have to be taken into account simultaneously. This Letter provides a simple, but complete determination of the space and time concentration profile and shows that the final front should consist of a steady-shape profile propagating at constant velocity. With such a solution, the data of Davis et al. [AIChE J. 34, 123 (1988); J. Fluid Mech. 196, 107 (1988)] give hydrodynamic dispersion coefficient five times larger than their former analysis, in agreement with Lee et al. [Phys. Fluids A 4, 2601 (1992)].

  9. Radiation hydrodynamics integrated in the PLUTO code

    Science.gov (United States)

    Kolb, Stefan M.; Stute, Matthias; Kley, Wilhelm; Mignone, Andrea

    2013-11-01

    Aims: The transport of energy through radiation is very important in many astrophysical phenomena. In dynamical problems the time-dependent equations of radiation hydrodynamics have to be solved. We present a newly developed radiation-hydrodynamics module specifically designed for the versatile magnetohydrodynamic (MHD) code PLUTO. Methods: The solver is based on the flux-limited diffusion approximation in the two-temperature approach. All equations are solved in the co-moving frame in the frequency-independent (gray) approximation. The hydrodynamics is solved by the different Godunov schemes implemented in PLUTO, and for the radiation transport we use a fully implicit scheme. The resulting system of linear equations is solved either using the successive over-relaxation (SOR) method (for testing purposes) or using matrix solvers that are available in the PETSc library. We state in detail the methodology and describe several test cases to verify the correctness of our implementation. The solver works in standard coordinate systems, such as Cartesian, cylindrical, and spherical, and also for non-equidistant grids. Results: We present a new radiation-hydrodynamics solver coupled to the MHD-code PLUTO that is a modern, versatile, and efficient new module for treating complex radiation hydrodynamical problems in astrophysics. As test cases, either purely radiative situations, or full radiation-hydrodynamical setups (including radiative shocks and convection in accretion disks) were successfully studied. The new module scales very well on parallel computers using MPI. For problems in star or planet formation, we added the possibility of irradiation by a central source.

  10. Polymer-functionalized single-walled carbon nanotubes as a novel sol-gel solid-phase micro-extraction coated fiber for determination of poly-brominated diphenyl ethers in water samples with gas chromatography-electron capture detection.

    Science.gov (United States)

    Zhang, Weiya; Sun, Yin; Wu, Caiying; Xing, Jun; Li, Jianying

    2009-04-15

    Single-walled carbon nanotubes (SWNTs) were functionalized with a hydroxyl-terminated silicone oil (TSO-OH). It is synthesized by the reactions of carbonyl chloride groups on the surface of SWNTs and hydroxyl groups of silicone oil (TSO-OH). The functionalized product SWNTs-TSO-OH was first used as precursor and selective stationary phase to prepare the sol-gel derived poly(SWNTs-TSO-OH) solid-phase microextraction (SPME) fiber for determination of polybrominated diphenyl ethers (PBDEs) in water samples. The possible major reaction of the sol-gel coating process was discussed and confirmed by IR spectra, Raman spectroscopy, and scanning electron microscopy. Some parameters of SPME fiber for the determination of PBDEs were investigated by headspace SPME/gas chromatography with electron-capture detection (HS-SPME/GC-ECD). Compared with the commercial SPME fiber, the new coated fiber showed higher extraction efficiency to PBDEs, better thermal stability (over 340 degrees C), and longer life span (over 200 times). All of these advantages are mainly due to the incorporation of SWNTs, which enhanced the pi-pi interaction with PBDEs and increased the surface area of extraction in contact with the sample. Moreover, the sol-gel coating technology additionally provided the porous structure of the 3-D silica network and the strong chemical binding provided which also will improve the extraction efficiency. Under optimized conditions, the method detection limits for seven PBDEs were 0.08-0.8 ng/L (S/N = 3) and the precision (RSD, n = 5) was 2.2-7.5% at the 50 ng/L level. The linearity of the developed method is in the range of 5-500 ng/L with coefficients of correlation greater than 0.995. The developed method was successfully applied for the analysis of trace PBDEs in reservoir water and wastewater samples. The recoveries obtained at spiking 50 ng/L were between 74% and 109% (n = 5) for PBDEs in water samples.

  11. Fish stocking density impacts tank hydrodynamics

    DEFF Research Database (Denmark)

    Rasmussen, Michael R.; Lunger, Angela; Laursen, Jesper;

    2006-01-01

    hydrodynamics was established using in-tank-based Rhodamine WT fluorometry at a flow rate of 0.23 l s-1 (tank exchange rate of 1.9 h-1). With increasing numbers of animals, curvilinear relationships were observed for dispersion coefficients and tank mixing times. Stocking densities of 3, 6, 9 and 12 kg m-3......The effect of stocking density upon the hydrodynamics of a circular tank, configured in a recirculation system, was investigated. Red drums Sciaenops ocellatus of approximately 140 g wet weight, were stocked at five rates varying from 0 to 12 kg m-3. The impact of the presence of fish upon tank...

  12. Bounce-free Spherical Hydrodynamic Implosion

    CERN Document Server

    Kagan, Grigory; Hsu, Scott C; Awe, Thomas J

    2011-01-01

    In a bounce-free spherical hydrodynamic implosion, the post-stagnation hot core plasma does not expand against the imploding flow. Such an implosion scheme has the advantage of improving the dwell time of the burning fuel, resulting in a higher fusion burn-up fraction. The existence of bounce-free spherical implosions is demonstrated by explicitly constructing a family of self-similar solutions to the spherically symmetric ideal hydrodynamic equations. When applied to a specific example of plasma liner driven magneto-inertial fusion, the bounce-free solution is found to produce at least a factor of four improvement in dwell time and fusion energy gain.

  13. Introduction to physics mechanics, hydrodynamics thermodynamics

    CERN Document Server

    Frauenfelder, P

    2013-01-01

    Introduction of Physics: Mechanics , Hydrodynamics, Thermodynamics covers the principles of matter and its motion through space and time, as well as the related concepts of energy and force. This book is composed of eleven chapters, and begins with an introduction to the basic principles of mechanics, hydrodynamics, and thermodynamics. The subsequent chapters deal with the statics of rigid bodies and the dynamics of particles and rigid bodies. These topics are followed by discussions on elasticity, mechanics of fluids, the basic concept of thermodynamic, kinetic theory, and crystal structure o

  14. Supernova hydrodynamics experiments using the Nova laser

    Energy Technology Data Exchange (ETDEWEB)

    Remington, B.A.; Glendinning, S.G.; Estabrook, K.; Wallace, R.J.; Rubenchik, A. [Lawrence Livermore National Lab., CA (United States); Kane, J.; Arnett, D. [Arizona Univ., Tucson, AZ (United States). Stewart Observatory; Drake, R.P. [Michigan Univ., Ann Arbor, MI (United States); McCray, R. [Colorado Univ., Boulder, CO (United States)

    1997-04-01

    We are developing experiments using the Nova laser to investigate two areas of physics relevant to core-collapse supernovae (SN): (1) compressible nonlinear hydrodynamic mixing and (2) radiative shock hydrodynamics. In the former, we are examining the differences between the 2D and 3D evolution of the Rayleigh-Taylor instability, an issue critical to the observables emerging from SN in the first year after exploding. In the latter, we are investigating the evolution of a colliding plasma system relevant to the ejecta-stellar wind interactions of the early stages of SN remnant formation. The experiments and astrophysical implications are discussed.

  15. Broken Lifshitz invariance, spin waves and hydrodynamics

    CERN Document Server

    Roychowdhury, Dibakar

    2016-01-01

    In this paper, based on the basic principles of thermodynamics, we explore the hydrodynamic regime of interacting Lifshitz field theories in the presence of broken rotational invariance. We compute the entropy current and discover new dissipative effects those are consistent with the principle of local entropy production in the fluid. In our analysis, we consider both the parity even as well as the parity odd sector upto first order in the derivative expansion. Finally, we argue that the present construction of the paper could be systematically identified as that of the hydrodynamic description associated with \\textit{spin waves} (away from the domain of quantum criticality) under certain limiting conditions.

  16. Colliding shockwaves and hydrodynamics in extreme conditions

    CERN Document Server

    Chesler, Paul M

    2015-01-01

    Using numerical holography, we study the collision of a planar sheet of energy with a bounded localized distribution of energy. The collision, which mimics proton-nucleus collisions, produces a localized lump of debris with transverse size $R \\sim 1/T_{\\rm eff}$ with $T_{\\rm eff}$ the effective temperature, and has large gradients and large transverse flow. Nevertheless, the post-collision evolution is well-described by viscous hydrodynamics. Our results bolster the notion that debris produced in proton-nucleus collisions may be modeled using hydrodynamics.

  17. Hydrodynamic interactions between nearby slender filaments

    CERN Document Server

    Man, Yi; Lauga, Eric

    2016-01-01

    Cellular biology abound with filaments interacting through fluids, from intracellular microtubules, to rotating flagella and beating cilia. While previous work has demonstrated the complexity of capturing nonlocal hydrodynamic interactions between moving filaments, the problem remains difficult theoretically. We show here that when filaments are closer to each other than their relevant length scale, the integration of hydrodynamic interactions can be approximately carried out analytically. This leads to a set of simplified local equations, illustrated on a simple model of two interacting filaments, which can be used to tackle theoretically a range of problems in biology and physics.

  18. Holography and hydrodynamics in small systems

    Science.gov (United States)

    Chesler, Paul M.

    2016-12-01

    Using holographic duality, we present results for the off-center collision of Gaussian wave packets in strongly coupled N = 4 supersymmetric Yang-Mills theory. The wave packets are thin along the collision axis and superficially at least resemble Lorentz contracted colliding protons. The collision results in the formation of a droplet of liquid of size R ∼ 1 /Teff where Teff is the effective temperature, which is the characteristic microscopic scale in strongly coupled plasma. These results demonstrate the applicability of hydrodynamics to microscopically small systems and bolster the notion that hydrodynamics can be applied to heavy-light ion collisions as well as proton-proton collisions.

  19. Liquid Chromatography in 1982.

    Science.gov (United States)

    Freeman, David H.

    1982-01-01

    Reviews trends in liquid chromatography including apparatus, factors affecting efficient separation of a mixture (peak sharpness and speed), simplified problem-solving, adsorption, bonded phase chromatography, ion selectivity, and size exclusion. The current trend is to control chemical selectivity by the liquid phase. (Author/JN)

  20. Column Liquid Chromatography.

    Science.gov (United States)

    Majors, Ronald E.; And Others

    1984-01-01

    Reviews literature covering developments of column liquid chromatography during 1982-83. Areas considered include: books and reviews; general theory; columns; instrumentation; detectors; automation and data handling; multidimensional chromatographic and column switching techniques; liquid-solid chromatography; normal bonded-phase, reversed-phase,…

  1. Hydrodynamic theory of thermoelectric transport and negative magnetoresistance in Weyl semimetals

    CERN Document Server

    Lucas, Andrew; Sachdev, Subir

    2016-01-01

    We present a minimal hydrodynamic formalism for thermoelectric transport in Weyl semimetals where the electron-electron scattering time is faster than the electron-impurity scattering time. Our model consists of relativistic fluids at each Weyl node, coupled together by perturbatively small inter-valley scattering, and long-range Coulomb interactions. We analytically compute all thermoelectric transport coefficients in the limit of perturbatively weak disorder and magnetic field, and confirm Onsager reciprocity and positive-definiteness of the conductivity matrix. Three distinct anomalous relaxation times govern negative magnetoresistance in the thermoelectric transport coefficients: while negative electrical magnetoresistance is governed by the standard chiral anomaly, negative thermal magnetoresistance is governed by a distinct gauge-gravitational anomaly. All of the hydrodynamic coefficients in our formalism may be computed for a given microscopic model of a Weyl semimetal via memory matrix techniques.

  2. Stabilizing geometry for hydrodynamic rotary seals

    Science.gov (United States)

    Dietle, Lannie L.; Schroeder, John E.

    2010-08-10

    A hydrodynamic sealing assembly including a first component having first and second walls and a peripheral wall defining a seal groove, a second component having a rotatable surface relative to said first component, and a hydrodynamic seal comprising a seal body of generally ring-shaped configuration having a circumference. The seal body includes hydrodynamic and static sealing lips each having a cross-sectional area that substantially vary in time with each other about the circumference. In an uninstalled condition, the seal body has a length defined between first and second seal body ends which varies in time with the hydrodynamic sealing lip cross-sectional area. The first and second ends generally face the first and second walls, respectively. In the uninstalled condition, the first end is angulated relative to the first wall and the second end is angulated relative to the second wall. The seal body has a twist-limiting surface adjacent the static sealing lip. In the uninstalled condition, the twist-limiting surface is angulated relative to the peripheral wall and varies along the circumference. A seal body discontinuity and a first component discontinuity mate to prevent rotation of the seal body relative to the first component.

  3. Hydrodynamic modelling of hydrostatic magnesium extrusion

    NARCIS (Netherlands)

    Moodij, E.; Rooij, de M.B.; Schipper, D.J.

    2006-01-01

    Wilson’s hydrodynamic model of the hydrostatic extrusion process is extended to meet the geometry found on residual billets. The transition from inlet to work zone of the process is not considered sharp as in the model of Wilson but as a rounded edge, modelled by a parabolic function. It is shown th

  4. Hydrodynamic limits of the Vlasov equation

    Energy Technology Data Exchange (ETDEWEB)

    Caprino, S. (Universita' de L' Aquila Coppito (Italy)); Esposito, R.; Marra, R. (Universita' di Roma tor Vergata, Roma (Italy)); Pulvirenti, M. (Universita' di Roma la Sapienza, Roma (Italy))

    1993-01-01

    In the present work, the authors study the Vlasov equation for repulsive forces in the hydrodynamic regime. For initial distributions at zero temperature the limit equations turn out to be the compressible and incompressible Euler equations under suitable space-time scalings. 17 refs.

  5. Microflow Cytometers with Integrated Hydrodynamic Focusing

    Directory of Open Access Journals (Sweden)

    Martin Schmidt

    2013-04-01

    Full Text Available This study demonstrates the suitability of microfluidic structures for high throughput blood cell analysis. The microfluidic chips exploit fully integrated hydrodynamic focusing based on two different concepts: Two-stage cascade focusing and spin focusing (vortex principle. The sample—A suspension of micro particles or blood cells—is injected into a sheath fluid streaming at a substantially higher flow rate, which assures positioning of the particles in the center of the flow channel. Particle velocities of a few m/s are achieved as required for high throughput blood cell analysis. The stability of hydrodynamic particle positioning was evaluated by measuring the pulse heights distributions of fluorescence signals from calibration beads. Quantitative assessment based on coefficient of variation for the fluorescence intensity distributions resulted in a value of about 3% determined for the micro-device exploiting cascade hydrodynamic focusing. For the spin focusing approach similar values were achieved for sample flow rates being 1.5 times lower. Our results indicate that the performances of both variants of hydrodynamic focusing suit for blood cell differentiation and counting. The potential of the micro flow cytometer is demonstrated by detecting immunologically labeled CD3 positive and CD4 positive T-lymphocytes in blood.

  6. Hydrodynamics and Roughness of Irregular Boundaries

    Science.gov (United States)

    2011-01-01

    principle component analysis (PCA) similar to that used by Preston (2009) for ship- mounted multibeam data. Several variables derived from the...complex boundaries as well as characterization of acoustic and optical processes. Turbulent processes at the seabed are at the foundation of littoral...nearshore hydrodynamics, turbulence over rough beds influences optical and acoustic properties. Bed roughness also directly affects acoustic propagation in

  7. Impact of Hydrodynamics on Oral Biofilm Strength

    NARCIS (Netherlands)

    Paramonova, E.; Kalmykowa, O. J.; van der Mei, H. C.; Busscher, H. J.; Sharma, P. K.

    2009-01-01

    Mechanical removal of oral biofilms is ubiquitously accepted as the best way to prevent caries and periodontal diseases. Removal effectiveness strongly depends on biofilm strength. To investigate the influence of hydrodynamics on oral biofilm strength, we grew single- and multi-species biofilms of S

  8. Hydrodynamic erosion process of undisturbed clay

    NARCIS (Netherlands)

    Zhao, G.; Visser, P.J.; Vrijling, J.K.

    2011-01-01

    This paper describes the hydrodynamic erosion process of undisturbed clay due to the turbulent flow, based on theoretical analysis and experimental results. The undisturbed clay has the unique and complicated characteristics of cohesive force among clay particles, which are highly different from dis

  9. Hydrodynamic impact response, a flexible view

    NARCIS (Netherlands)

    Vredeveldt, A.W.; Hoogeland, M.; Janssen, G.Th.M.

    2001-01-01

    The popularity of high-speed craft is steadily increasing. Until now, much attention has been focussed on the hydrodynamic aspects of these craft. The structural design of these vessels is usually considered in a quasi static sense. However, due to the requirement of light ship structures, fast ship

  10. Hydrodynamics: Fluctuating initial conditions and two-particle correlations

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, R.P.G.; Grassi, F. [Instituto de Fisica, Universidade de Sao Paulo (Brazil); Hama, Y., E-mail: hama@fma.if.usp.b [Instituto de Fisica, Universidade de Sao Paulo (Brazil); Qian, W.-L. [Instituto de Fisica, Universidade de Sao Paulo (Brazil)

    2011-03-15

    Event-by-event hydrodynamics (or hydrodynamics with fluctuating initial conditions) has been developed in the past few years. Here we discuss how it may help to understand the various structures observed in two-particle correlations.

  11. Simulation of Helical Flow Hydrodynamics in Meanders and Advection-Turbulent Diffusion Using Smoothed Particle Hydrodynamics

    Science.gov (United States)

    Gusti, T. P.; Hertanti, D. R.; Bahsan, E.; Soeryantono, H.

    2013-12-01

    Particle-based numerical methods, such as Smoothed Particle Hydrodynamics (SPH), may be able to simulate some hydrodynamic and morphodynamic behaviors better than grid-based numerical methods. This study simulates hydrodynamics in meanders and advection and turbulent diffusion in straight river channels using Microsoft Excel and Visual Basic. The simulators generate three-dimensional data for hydrodynamics and one-dimensional data for advection-turbulent diffusion. Fluid at rest, sloshing, and helical flow are simulated in the river meanders. Spill loading and step loading are done to simulate concentration patterns associated with advection-turbulent diffusion. Results indicate that helical flow is formed due to disturbance in morphology and particle velocity in the stream and the number of particles does not have a significant effect on the pattern of advection-turbulent diffusion concentration.

  12. Scaling supernova hydrodynamics to the laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Kane, J.O.

    1999-06-01

    Supernova (SN) 1987A focused attention on the critical role of hydrodynamic instabilities in the evolution of supernovae. To test the modeling of these instabilities, we are developing laboratory experiments of hydrodynamic mixing under conditions relevant to supernovae. Initial results were reported in J. Kane et al., Astrophys. J.478, L75 (1997) The Nova laser is used to shock two-layer targets, producing Richtmyer-Meshkov (RM) and Rayleigh-Taylor (RT) instabilities at the interfaces between the layers, analogous to instabilities seen at the interfaces of SN 1987A. Because the hydrodynamics in the laser experiments at intermediate times (3-40 ns) and in SN 1987A at intermediate times (5 s-10{sup 4} s) are well described by the Euler equations, the hydrodynamics scale between the two regimes. The experiments are modeled using the hydrodynamics codes HYADES and CALE, and the supernova code PROMETHEUS, thus serving as a benchmark for PROMETHEUS. Results of the experiments and simulations are presented. Analysis of the spike and bubble velocities in the experiment using potential flow theory and a modified Ott thin shell theory is presented. A numerical study of 2D vs. 3D differences in instability growth at the O-He and He-H interface of SN 1987A, and the design for analogous laser experiments are presented. We discuss further work to incorporate more features of the SN in the experiments, including spherical geometry, multiple layers and density gradients. Past and ongoing work in laboratory and laser astrophysics is reviewed, including experimental work on supernova remnants (SNRs). A numerical study of RM instability in SNRs is presented.

  13. Determination of tetrabromobisphenol in a electronics by gas chromatography-mass spectrometry with ultrasonic extraction and derivatisation%气相色谱-质谱法测定电子产品中四溴双酚A

    Institute of Scientific and Technical Information of China (English)

    陈啟荣; 郎爽; 魏岩; 范筱京; 夏敏

    2011-01-01

    A method for the determination of tetrabromobisphenol A in electronics using ultrasonic extraction and derivatisation by Gas Chromatography-Mass spectrometry was established. Samples were extracted with hexane and acetone mixtures. A derivatisation step was carried out with BSTFA + TMCS as derivatisation reagents. Effect of experiment conditions, such as derivative volume, derivatisation time and temperature were investigated. Under the optimized conditions, the calibration curve showed good linearity between 0. 4 μg/mL and 4. 0 μg/mL. The results showed that the recoveries of samples were 61.2% ~ 93%. The relative standard deviation was less than 5%. The limit of detection was 1. 25 mg/kg, and the limit of quantity was 3.75 mg/kg.%建立了超声提取-硅烷化气相色谱-质谱测定电子产品中四溴双酚A的方法.样品用正己烷/丙酮作提取剂,浸泡后超声提取,经N,O-双三甲基硅烷三氟乙酰胺(BSTFA)+1%三甲基氯硅烷(TMCS)衍生化,利用气相色谱-质谱仪进行定性定量分析.讨论了浸泡时间对提取效率的影响,优化衍生温度和衍生时间.结果表明:标样衍生后在0.4~4.0 μg/mL范围内具有良好的线性.加标回收率范围在61%~93%之间,平行测定的相对标准偏差小于5%.方法的检出限为1.25 mg/kg,定量限为3.75 mg/kg.

  14. Axisymmetric Simulations of Hot Jupiter-Stellar Wind Hydrodynamic Interaction

    CERN Document Server

    Christie, Duncan; Li, Zhi-Yun

    2016-01-01

    Gas giant exoplanets orbiting at close distances to the parent star are subjected to large radiation and stellar wind fluxes. In this paper, hydrodynamic simulations of the planetary upper atmosphere and its interaction with the stellar wind are carried out to understand the possible flow regimes and how they affect the Lyman-alpha transmission spectrum. Following Tremblin and Chiang, charge exchange reactions are included to explore the role of energetic atoms as compared to thermal particles. In order to understand the role of the tail as compared to the leading edge of the planetary gas, the simulations were carried out under axisymmetry, and photoionization and stellar wind electron impact ionization reactions were included to limit the extent of the neutrals away from the planet. By varying the planetary gas temperature, two regimes are found. At high temperature, a supersonic planetary wind is found, which is turned around by the stellar wind and forms a tail behind the planet. At lower temperatures, th...

  15. Beam Induced Hydrodynamic Tunneling in the Future Circular Collider Components

    Science.gov (United States)

    Tahir, N. A.; Burkart, F.; Schmidt, R.; Shutov, A.; Wollmann, D.; Piriz, A. R.

    2016-08-01

    A future circular collider (FCC) has been proposed as a post-Large Hadron Collider accelerator, to explore particle physics in unprecedented energy ranges. The FCC is a circular collider in a tunnel with a circumference of 80-100 km. The FCC study puts an emphasis on proton-proton high-energy and electron-positron high-intensity frontier machines. A proton-electron interaction scenario is also examined. According to the nominal FCC parameters, each of the 50 TeV proton beams will carry an amount of 8.5 GJ energy that is equivalent to the kinetic energy of an Airbus A380 (560 t) at a typical speed of 850 km /h . Safety of operation with such extremely energetic beams is an important issue, as off-nominal beam loss can cause serious damage to the accelerator and detector components with a severe impact on the accelerator environment. In order to estimate the consequences of an accident with the full beam accidently deflected into equipment, we have carried out numerical simulations of interaction of a FCC beam with a solid copper target using an energy-deposition code (fluka) and a 2D hydrodynamic code (big2) iteratively. These simulations show that, although the penetration length of a single FCC proton and its shower in solid copper is about 1.5 m, the full FCC beam will penetrate up to about 350 m into the target because of the "hydrodynamic tunneling." These simulations also show that a significant part of the target is converted into high-energy-density matter. We also discuss this interesting aspect of this study.

  16. Inductive voltage adder advanced hydrodynamic radiographic technology demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Mazarakis, M.G.; Poukey, J.W.; Maenchen; Rovang, D.C. [and others

    1997-04-01

    This paper presents the design, results, and analysis of a high-brightness electron beam technology demonstration experiment completed at Sandia National Laboratories, performed in collaboration with Los Alamos National Laboratory. The anticipated electron beam parameters were: 12 MeV, 35-40 kA, 0.5-mm rms radius, and 40-ns full width half maximum (FWHM) pulse duration. This beam, on an optimum thickness tantalum converter, should produce a very intense x-ray source of {approximately} 1.5-mm spot size and 1 kR dose @ 1 m. The accelerator utilized was SABRE, a pulsed inductive voltage adder, and the electron source was a magnetically immersed foilless electron diode. For these experiments, SABRE was modified to high-impedance negative-polarity operation. A new 100-ohm magnetically insulated transmission line cathode electrode was designed and constructed; the cavities were rotated 180{degrees} poloidally to invert the central electrode polarity to negative; and only one of the two pulse forming lines per cavity was energized. A twenty- to thirty-Tesla solenoidal magnet insulated the diode and contained the beam at its extremely small size. These experiments were designed to demonstrate high electron currents in submillimeter radius beams resulting in a high-brightness high-intensity flash x-ray source for high-resolution thick-object hydrodynamic radiography. The SABRE facility high-impedance performance was less than what was hoped. The modifications resulted in a lower amplitude (9 MV), narrower-than-anticipated triangular voltage pulse, which limited the dose to {approximately} 20% of the expected value. In addition, halo and ion-hose instabilities increased the electron beam spot size to > 1.5 mm. Subsequent, more detailed calculations explain these reduced output parameters. An accelerator designed (versus retrofit) for this purpose would provide the desired voltage and pulse shape.

  17. Effective Hydrodynamic Boundary Conditions for Corrugated Surfaces

    CERN Document Server

    Mongruel, Anne; Asmolov, Evgeny S; Vinogradova, Olga I

    2012-01-01

    We report measurements of the hydrodynamic drag force acting on a smooth sphere falling down under gravity to a plane decorated with microscopic periodic grooves. Both surfaces are lyophilic, so that a liquid (silicone oil) invades the surface texture being in the Wenzel state. A significant decrease in the hydrodynamic resistance force as compared with that predicted for two smooth surfaces is observed. To quantify the effect of roughness we use the effective no-slip boundary condition, which is applied at the imaginary smooth homogeneous isotropic surface located at an intermediate position between top and bottom of grooves. Such an effective condition fully characterizes the force reduction measured with the real surface, and the location of this effective plane is related to geometric parameters of the texture by a simple analytical formula.

  18. Axially symmetric pseudo-Newtonian hydrodynamics code

    CERN Document Server

    Kim, Jinho; Choptuik, Matthew William; Lee, Hyung Mok

    2012-01-01

    We develop a numerical hydrodynamics code using a pseudo-Newtonian formulation that uses the weak field approximation for the geometry, and a generalized source term for the Poisson equation that takes into account relativistic effects. The code was designed to treat moderately relativistic systems such as rapidly rotating neutron stars. The hydrodynamic equations are solved using a finite volume method with High Resolution Shock Capturing (HRSC) techniques. We implement several different slope limiters for second order reconstruction schemes and also investigate higher order reconstructions. We use the method of lines (MoL) to convert the mixed spatial-time partial differential equations into ordinary differential equations (ODEs) that depend only on time. These ODEs are solved using 2nd and 3rd order Runge-Kutta methods. The Poisson equation for the gravitational potential is solved with a multigrid method. In order to confirm the validity of our code, we carry out four different tests including one and two...

  19. Kinetic and hydrodynamic models of chemotactic aggregation

    CERN Document Server

    Chavanis, Pierre-Henri

    2007-01-01

    We derive general kinetic and hydrodynamic models of chemotactic aggregation that describe certain features of the morphogenesis of biological colonies (like bacteria, amoebae, endothelial cells or social insects). Starting from a stochastic model defined in terms of N coupled Langevin equations, we derive a nonlinear mean field Fokker-Planck equation governing the evolution of the distribution function of the system in phase space. By taking the successive moments of this kinetic equation and using a local thermodynamic equilibrium condition, we derive a set of hydrodynamic equations involving a damping term. In the limit of small frictions, we obtain a hyperbolic model describing the formation of network patterns (filaments) and in the limit of strong frictions we obtain a parabolic model which is a generalization of the standard Keller-Segel model describing the formation of clusters (clumps). Our approach connects and generalizes several models introduced in the chemotactic literature. We discuss the anal...

  20. SPHGR: Smoothed-Particle Hydrodynamics Galaxy Reduction

    Science.gov (United States)

    Thompson, Robert

    2015-02-01

    SPHGR (Smoothed-Particle Hydrodynamics Galaxy Reduction) is a python based open-source framework for analyzing smoothed-particle hydrodynamic simulations. Its basic form can run a baryonic group finder to identify galaxies and a halo finder to identify dark matter halos; it can also assign said galaxies to their respective halos, calculate halo & galaxy global properties, and iterate through previous time steps to identify the most-massive progenitors of each halo and galaxy. Data about each individual halo and galaxy is collated and easy to access. SPHGR supports a wide range of simulations types including N-body, full cosmological volumes, and zoom-in runs. Support for multiple SPH code outputs is provided by pyGadgetReader (ascl:1411.001), mainly Gadget (ascl:0003.001) and TIPSY (ascl:1111.015).

  1. Filter-less submicron hydrodynamic size sorting.

    Science.gov (United States)

    Fouet, M; Mader, M-A; Iraïn, S; Yanha, Z; Naillon, A; Cargou, S; Gué, A-M; Joseph, P

    2016-02-21

    We propose a simple microfluidic device able to separate submicron particles (critical size ∼0.1 μm) from a complex sample with no filter (minimum channel dimension being 5 μm) by hydrodynamic filtration. A model taking into account the actual velocity profile and hydrodynamic resistances enables prediction of the chip sorting properties for any geometry. Two design families are studied to obtain (i) small sizes within minutes (low-aspect ratio, two-level chip) and (ii) micron-sized sorting with a μL flow rate (3D architecture based on lamination). We obtain quantitative agreement of sorting performances both with experiments and with numerical solving, and determine the limits of the approach. We therefore demonstrate a passive, filter-less sub-micron size sorting with a simple, robust, and easy to fabricate design.

  2. VH1 Hydrodynamics for Introductory Astronomy

    Science.gov (United States)

    Christian, Wolfgang; Blondin, John

    1997-05-01

    Improvements in personal computer operating systems and hardware now makes it possible to run research grade Fortran simulations on student computers. Unfortunately, many legacy applications do not have a graphical user interface and are sometimes hard coded to a specific problem making them unsuitable for beginning students. A good way to re-purpose such legacy code for undergraduate teaching is to build a graphical front end using a Rapid Application Development, RAD, tool that starts the simulation as a separate thread. This technique is being used with Virginia Hydrodynamics One, VH1, to provide an introduction to computational hydrodynamics. Standard test problems including gravitational collapse of an interstellar cloud, radiation cooling, and formation of shocks are demonstrated using this on Microsoft Windows 95/NT.

  3. Electro-hydrodynamic synchronization of piezoelectric flags

    CERN Document Server

    Xia, Yifan; Michelin, Sebastien

    2016-01-01

    Hydrodynamic coupling of flexible flags in axial flows may profoundly influence their flapping dynamics, in particular driving their synchronization. This work investigates the effect of such coupling on the harvesting efficiency of coupled piezoelectric flags, that convert their periodic deformation into an electrical current. Considering two flags connected to a single output circuit, we investigate using numerical simulations the relative importance of hydrodynamic coupling to electrodynamic coupling of the flags through the output circuit due to the inverse piezoelectric effect. It is shown that electrodynamic coupling is dominant beyond a critical distance, and induces a synchronization of the flags' motion resulting in enhanced energy harvesting performance. We further show that this electrodynamic coupling can be strengthened using resonant harvesting circuits.

  4. Application of hydrodynamics to heavy ion collisions

    Energy Technology Data Exchange (ETDEWEB)

    Felsberger, Lukas

    2014-12-02

    The Bjorken model is a simple tool for making rough predictions of the hydrodynamic evolution of the thermalized matter created in a heavy ion collision. The advantage of the model clearly lies in its simplicity, rather than accuracy. As it is still used for making rough estimations 'by hand', in this thesis, I investigate in which cases the Bjorken model gives useful results and in which it is not recommended. For central collisions, I show which critical size the nuclei should have so that the Bjorken model can be applied. For non-central collisions, I demonstrate that using Glauber initial conditions combined with the Bjorken evolution, leads to reasonable results up to large impact parameters. Finally, I study the case of a non-ideal (viscous) description of the thermalized matter which leads to strongly differing results if first- or second-order hydrodynamics is applied.

  5. Simple Waves in Ideal Radiation Hydrodynamics

    CERN Document Server

    Johnson, Bryan M

    2008-01-01

    In the dynamic diffusion limit of radiation hydrodynamics, advection dominates diffusion; the latter primarily affects small scales and has negligible impact on the large scale flow. The radiation can thus be accurately regarded as an ideal fluid, i.e., radiative diffusion can be neglected along with other forms of dissipation. This viewpoint is applied here to an analysis of simple waves in an ideal radiating fluid. It is shown that much of the hydrodynamic analysis carries over by simply replacing the material sound speed, pressure and index with the values appropriate for a radiating fluid. A complete analysis is performed for a centered rarefaction wave, and expressions are provided for the Riemann invariants and characteristic curves of the one-dimensional system of equations. The analytical solution is checked for consistency against a finite difference numerical integration, and the validity of neglecting the diffusion operator is demonstrated. An interesting physical result is that for a material comp...

  6. Pursuit and Synchronization in Hydrodynamic Dipoles

    CERN Document Server

    Kanso, Eva

    2015-01-01

    We study theoretically the behavior of a class of hydrodynamic dipoles. This study is motivated by recent experiments on synthetic and biological swimmers in microfluidic \\textit{Hele-Shaw} type geometries. Under such confinement, a swimmer's hydrodynamic signature is that of a potential source dipole, and the long-range interactions among swimmers are obtained from the superposition of dipole singularities. Here, we recall the equations governing the positions and orientations of interacting asymmetric swimmers in doubly-periodic domains, and focus on the dynamics of swimmer pairs. We obtain two families of `relative equilibria'-type solutions that correspond to pursuit and synchronization of the two swimmers, respectively. Interestingly, the pursuit mode is stable for large tail swimmers whereas the synchronization mode is stable for large head swimmers. These results have profound implications on the collective behavior reported in several recent studies on populations of confined microswimmers.

  7. Low Mach Number Fluctuating Hydrodynamics for Electrolytes

    CERN Document Server

    Péraud, Jean-Philippe; Chaudhri, Anuj; Bell, John B; Donev, Aleksandar; Garcia, Alejandro L

    2016-01-01

    We formulate and study computationally the low Mach number fluctuating hydrodynamic equations for electrolyte solutions. We are interested in studying transport in mixtures of charged species at the mesoscale, down to scales below the Debye length, where thermal fluctuations have a significant impact on the dynamics. Continuing our previous work on fluctuating hydrodynamics of multicomponent mixtures of incompressible isothermal miscible liquids (A. Donev, et al., Physics of Fluids, 27, 3, 2015), we now include the effect of charged species using a quasielectrostatic approximation. Localized charges create an electric field, which in turn provides additional forcing in the mass and momentum equations. Our low Mach number formulation eliminates sound waves from the fully compressible formulation and leads to a more computationally efficient quasi-incompressible formulation. We demonstrate our ability to model saltwater (NaCl) solutions in both equilibrium and nonequilibrium settings. We show that our algorithm...

  8. Hydrodynamics of charge fluctuations and balance functions

    CERN Document Server

    Ling, B; Stephanov, M

    2013-01-01

    We apply stochastic hydrodynamics to the study of charge density fluctuations in QCD matter undergoing Bjorken expansion. We find that the charge density correlations are given by a time integral over the history of the system, with the dominant contribution coming from the QCD crossover region where the change of susceptibility per entropy, chi T/s, is most significant. We study the rapidity and azimuthal angle dependence of the resulting charge balance function using a simple analytic model of heavy-ion collision evolution. Our results are in agreement with experimental measurements, indicating that hydrodynamic fluctuations contribute significantly to the measured charge correlations in high energy heavy-ion collisions. The sensitivity of the balance function to the value of the charge diffusion coefficient D allows us to estimate the typical value of this coefficient in the crossover region to be rather small, of the order of 1/(2pi T), characteristic of a strongly coupled plasma.

  9. Frictionless dispersive hydrodynamics of Stokes flows

    CERN Document Server

    Maiden, Michelle D; Anderson, Dalton V; Schubert, Marika E; Hoefer, Mark A

    2016-01-01

    Effectively frictionless, dispersive flow characterizes superfluids, nonlinear optical diffraction, and geophysical fluid interfaces. Dispersive shock waves (DSWs) and solitons are fundamental nonlinear excitations in these media, but DSW studies to date have been severely constrained by a loss of coherence. Here we report on a novel dispersive hydrodynamics testbed: the effectively frictionless flow of interfacial waves between two high contrast, low Reynolds' number Stokes fluids. This system enables high fidelity observations of large amplitude DSWs, found to agree quantitatively with a nonlinear wave averaging theory. We then report on observations of highly coherent phenomena including DSW backflow, the refraction or absorption of solitons by DSWs, and multi-phase DSW-DSW merger. The complex, coherent, nonlinear mixing of DSWs and solitons observed here are universal features of dissipationless, dispersive hydrodynamic flows.

  10. Electro-hydrodynamics near Hydrophobic Surfaces

    CERN Document Server

    Maduar, S R; Lobaskin, V; Vinogradova, O I

    2014-01-01

    We show that the dynamics of the electrostatic diffuse layer at the slippery hydrophobic surface depends strongly on the mobility of surface charges. For a hydrophobic surface with immobile charges the fluid transport is considerably amplified by the existence of a hydrodynamic slippage. In contrast, near the hydrophobic surface with mobile adsorbed charges it is also controlled by an additional electric force, which increases the shear stress at the slipping interface. To account for this we formulate electro-hydrodynamic boundary conditions at the slipping interface, which are applied to quantify electro-osmotic flows. Our theoretical predictions are fully supported by dissipative particle dynamics simulations with explicit charges. These results lead to a new general concept of zeta-potential of hydrophobic surfaces.

  11. Hydrodynamic theory of tissue shear flow

    CERN Document Server

    Popović, Marko; Merkel, Matthias; Etournay, Raphaël; Eaton, Suzanne; Jülicher, Frank; Salbreux, Guillaume

    2016-01-01

    We propose a hydrodynamic theory to describe shear flows in developing epithelial tissues. We introduce hydrodynamic fields corresponding to state properties of constituent cells as well as a contribution to overall tissue shear flow due to rearrangements in cell network topology. We then construct a constitutive equation for the shear rate due to topological rearrangements. We identify a novel rheological behaviour resulting from memory effects in the tissue. We show that anisotropic deformation of tissue and cells can arise from two distinct active cellular processes: generation of active stress in the tissue, and actively driven cellular rearrangements. These two active processes result in distinct cellular and tissue shape changes, depending on boundary conditions applied on the tissue. Our findings have consequences for the understanding of tissue morphogenesis during development.

  12. Hydrodynamics of ultra-relativistic bubble walls

    Directory of Open Access Journals (Sweden)

    Leonardo Leitao

    2016-04-01

    Full Text Available In cosmological first-order phase transitions, gravitational waves are generated by the collisions of bubble walls and by the bulk motions caused in the fluid. A sizeable signal may result from fast-moving walls. In this work we study the hydrodynamics associated to the fastest propagation modes, namely, ultra-relativistic detonations and runaway solutions. We compute the energy injected by the phase transition into the fluid and the energy which accumulates in the bubble walls. We provide analytic approximations and fits as functions of the net force acting on the wall, which can be readily evaluated for specific models. We also study the back-reaction of hydrodynamics on the wall motion, and we discuss the extrapolation of the friction force away from the ultra-relativistic limit. We use these results to estimate the gravitational wave signal from detonations and runaway walls.

  13. Chaos in hydrodynamic BL Herculis models

    CERN Document Server

    Smolec, R

    2014-01-01

    We present non-linear, convective, BL Her-type hydrodynamic models that show complex variability characteristic for deterministic chaos. The bifurcation diagram reveals a rich structure, with many phenomena detected for the first time in hydrodynamic models of pulsating stars. The phenomena include not only period doubling cascades en route to chaos (detected in earlier studies) but also periodic windows within chaotic band, type-I and type-III intermittent behaviour, interior crisis bifurcation and others. Such phenomena are known in many textbook chaotic systems, from the simplest discrete logistic map, to more complex systems like Lorenz equations. We discuss the physical relevance of our models. Although except of period doubling such phenomena were not detected in any BL Her star, chaotic variability was claimed in several higher luminosity siblings of BL Her stars - RV Tau variables, and also in longer-period, luminous irregular pulsators. Our models may help to understand these poorly studied stars. Pa...

  14. Hydrodynamic model for expansion and collisional relaxation of x-ray laser-excited multi-component nanoplasma

    CERN Document Server

    Saxena, Vikrant

    2016-01-01

    The irradiation of an atomic cluster with a femtosecond x-ray free-electron laser pulse results in a nanoplasma formation. This typically occurs within a few hundreds femtoseconds. By this time the x-ray pulse is over, and the direct photoinduced processes no longer contributing. All created electrons within the nanoplasma are thermalized. The nanoplasma thus formed is a mixture of atoms, electrons and ions of various charges. While expanding, it is undergoing electron impact ionization and three-body recombination. Below we present a hydrodynamic model to describe the dynamics of such multi-component nanoplasma. The model equations are derived by taking the moments of the corresponding Boltzmann kinetic equations. We include the equations obtained, together with the source terms due to electron impact ionization and three-body recombination, in our hydrodynamic solver. Model predictions for a test case: expanding spherical Ar nanoplasma are obtained. With this model we complete the two-step approach to simul...

  15. Novel techniques for slurry bubble column hydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Dudukovic, M.P.

    1999-05-14

    The objective of this cooperative research effort between Washington University, Ohio State University and Exxon Research Engineering Company was to improve the knowledge base for scale-up and operation of slurry bubble column reactors for syngas conversion and other coal conversion processes by increased reliance on experimentally verified hydrodynamic models. During the first year (July 1, 1995--June 30, 1996) of this three year program novel experimental tools (computer aided radioactive particle tracking (CARPT), particle image velocimetry (PIV), heat probe, optical fiber probe and gamma ray tomography) were developed and tuned for measurement of pertinent hydrodynamic quantities, such as velocity field, holdup distribution, heat transfer and bubble size. The accomplishments were delineated in the First Technical Annual Report. The second year (July, 1996--June 30, 1997) was spent on further development and tuning of the novel experimental tools (e.g., development of Monte Carlo calibration for CARPT, optical probe development), building up the hydrodynamic data base using these tools and comparison of the two techniques (PIV and CARPT) for determination of liquid velocities. A phenomenological model for gas and liquid backmixing was also developed. All accomplishments were summarized in the Second Annual Technical Report. During the third and final year of the program (July 1, 1997--June 30, 1998) and during the nine months no cost extension, the high pressure facility was completed and a set of data was taken at high pressure conditions. Both PIV, CT and CARPT were used. More fundamental hydrodynamic modeling was also undertaken and model predictions were compared to data. The accomplishments for this period are summarized in this report.

  16. VH-1: Multidimensional ideal compressible hydrodynamics code

    Science.gov (United States)

    Hawley, John; Blondin, John; Lindahl, Greg; Lufkin, Eric

    2012-04-01

    VH-1 is a multidimensional ideal compressible hydrodynamics code written in FORTRAN for use on any computing platform, from desktop workstations to supercomputers. It uses a Lagrangian remap version of the Piecewise Parabolic Method developed by Paul Woodward and Phil Colella in their 1984 paper. VH-1 comes in a variety of versions, from a simple one-dimensional serial variant to a multi-dimensional version scalable to thousands of processors.

  17. On the convexity of Relativistic Hydrodynamics

    CERN Document Server

    Ibáñez, José María; Martí, José María; Miralles, Juan Antonio; 10.1088/0264-9381/30/5/057002

    2013-01-01

    The relativistic hydrodynamic system of equations for a perfect fluid obeying a causal equation of state is hyperbolic (Anile 1989 {\\it Relativistic Fluids and Magneto-Fluids} (Cambridge: Cambridge University Press)). In this report, we derive the conditions for this system to be convex in terms of the fundamental derivative of the equation of state (Menikoff and Plohr 1989 {\\it Rev. Mod. Phys.} {\\bf 61} 75). The classical limit is recovered.

  18. Modeling Water Waves with Smoothed Particle Hydrodynamics

    Science.gov (United States)

    2013-09-30

    flows, such as undertow, longshore currents, and rip currents. APPROACH The approach is based on improving various aspects of the SPH code ...Smoothed Particle Hydrodynamics ( SPH ) is a meshless numerical method that is being developed for the study of nearshore waves and other Navy needs. The...Lagrangian nature of SPH allows the modeling of wave breaking, surf zones, ship waves, and wave-structure interaction, where the free surface becomes

  19. An Owner's Guide to Smoothed Particle Hydrodynamics

    OpenAIRE

    Martin, T.J.; Pearce, F. R.; Thomas, P. A.

    1993-01-01

    We present a practical guide to Smoothed Particle Hydrodynamics (\\SPH) and its application to astrophysical problems. Although remarkably robust, \\SPH\\ must be used with care if the results are to be meaningful since the accuracy of \\SPH\\ is sensitive to the arrangement of the particles and the form of the smoothing kernel. In particular, the initial conditions for any \\SPH\\ simulation must consist of particles in dynamic equilibrium. We describe some of the numerical difficulties that may be...

  20. Numerical Hydrodynamics and Magnetohydrodynamics in General Relativity

    Directory of Open Access Journals (Sweden)

    Font José A.

    2008-09-01

    Full Text Available This article presents a comprehensive overview of numerical hydrodynamics and magnetohydrodynamics (MHD in general relativity. Some significant additions have been incorporated with respect to the previous two versions of this review (2000, 2003, most notably the coverage of general-relativistic MHD, a field in which remarkable activity and progress has occurred in the last few years. Correspondingly, the discussion of astrophysical simulations in general-relativistic hydrodynamics is enlarged to account for recent relevant advances, while those dealing with general-relativistic MHD are amply covered in this review for the first time. The basic outline of this article is nevertheless similar to its earlier versions, save for the addition of MHD-related issues throughout. Hence, different formulations of both the hydrodynamics and MHD equations are presented, with special mention of conservative and hyperbolic formulations well adapted to advanced numerical methods. A large sample of numerical approaches for solving such hyperbolic systems of equations is discussed, paying particular attention to solution procedures based on schemes exploiting the characteristic structure of the equations through linearized Riemann solvers. As previously stated, a comprehensive summary of astrophysical simulations in strong gravitational fields is also presented. These are detailed in three basic sections, namely gravitational collapse, black-hole accretion, and neutron-star evolutions; despite the boundaries, these sections may (and in fact do overlap throughout the discussion. The material contained in these sections highlights the numerical challenges of various representative simulations. It also follows, to some extent, the chronological development of the field, concerning advances in the formulation of the gravitational field, hydrodynamics and MHD equations and the numerical methodology designed to solve them. To keep the length of this article reasonable

  1. Laser driven hydrodynamic instability experiments. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    Remington, B.A.; Weber, S.V.; Haan, S.W.; Kilkenny, J.D.; Glendinning, S.G.; Wallace, R.J.; Goldstein, W.H.; Wilson, B.G.; Nash, J.K.

    1993-02-17

    An extensive series of experiments has been conducted on the Nova laser to measure hydrodynamic instabilities in planar foils accelerated by x-ray ablation. Single mode experiments allow a measurement of the fundamental growth rates from the linear well into the nonlinear regime. Two-mode foils allow a first direct observation of mode coupling. Surface-finish experiments allow a measurement of the evolution of a broad spectrum of random initial modes.

  2. Smoothed Particle Hydrodynamics: Applications Within DSTO

    Science.gov (United States)

    2006-10-01

    dimensional SPH code. They used SPH to model wave overtopping on the decks of offshore platforms and ships and used moving boundary particles to create...loading on offshore structures is a subject area which is now becoming amenable to detailed study using sophisticated computational fluid dynamics codes...incorporation of bending, torsional stiffness, and hydrodynamic loads, thus making it ideal for the simulation of umbilical cables on ROVs and AUVs

  3. A hydrodynamic approach to QGP instabilities

    CERN Document Server

    Calzetta, E

    2013-01-01

    We show that the usual linear analysis of QGP Weibel instabilities based on the Maxwell-Boltzmann equation may be reproduced in a purely hydrodynamic model. The latter is derived by the Entropy Production Variational Method from a transport equation including collisions, and can describe highly nonequilibrium flow. We find that, as expected, collisions slow down the growth of Weibel instabilities. Finally, we discuss the strong momentum anisotropy limit.

  4. 2D Transonic Hydrodynamics in General Relativity

    CERN Document Server

    Beskin, V S

    2002-01-01

    The goal of my lecture is to present the introduction into the hydrodynamical version of the Grad-Shafranov equation. Although not so well-known as the full MHD one, it allows us to clarify the nontrivial structure of the Grad-Shafranov approach as well as to discuss the simplest version of the 3+1-split language -- the most convenient one for the description of the ideal flows in the vicinity of a rotating black hole.

  5. Testing hydrodynamics schemes in galaxy disc simulations

    Science.gov (United States)

    Few, C. G.; Dobbs, C.; Pettitt, A.; Konstandin, L.

    2016-08-01

    We examine how three fundamentally different numerical hydrodynamics codes follow the evolution of an isothermal galactic disc with an external spiral potential. We compare an adaptive mesh refinement code (RAMSES), a smoothed particle hydrodynamics code (SPHNG), and a volume-discretized mesh-less code (GIZMO). Using standard refinement criteria, we find that RAMSES produces a disc that is less vertically concentrated and does not reach such high densities as the SPHNG or GIZMO runs. The gas surface density in the spiral arms increases at a lower rate for the RAMSES simulations compared to the other codes. There is also a greater degree of substructure in the SPHNG and GIZMO runs and secondary spiral arms are more pronounced. By resolving the Jeans length with a greater number of grid cells, we achieve more similar results to the Lagrangian codes used in this study. Other alterations to the refinement scheme (adding extra levels of refinement and refining based on local density gradients) are less successful in reducing the disparity between RAMSES and SPHNG/GIZMO. Although more similar, SPHNG displays different density distributions and vertical mass profiles to all modes of GIZMO (including the smoothed particle hydrodynamics version). This suggests differences also arise which are not intrinsic to the particular method but rather due to its implementation. The discrepancies between codes (in particular, the densities reached in the spiral arms) could potentially result in differences in the locations and time-scales for gravitational collapse, and therefore impact star formation activity in more complex galaxy disc simulations.

  6. MUFASA: galaxy formation simulations with meshless hydrodynamics

    Science.gov (United States)

    Davé, Romeel; Thompson, Robert; Hopkins, Philip F.

    2016-11-01

    We present the MUFASA suite of cosmological hydrodynamic simulations, which employs the GIZMO meshless finite mass (MFM) code including H2-based star formation, nine-element chemical evolution, two-phase kinetic outflows following scalings from the Feedback in Realistic Environments zoom simulations, and evolving halo mass-based quenching. Our fiducial (50 h-1 Mpc)3 volume is evolved to z = 0 with a quarter billion elements. The predicted galaxy stellar mass functions (GSMFs) reproduces observations from z = 4 → 0 to ≲ 1.2σ in cosmic variance, providing an unprecedented match to this key diagnostic. The cosmic star formation history and stellar mass growth show general agreement with data, with a strong archaeological downsizing trend such that dwarf galaxies form the majority of their stars after z ˜ 1. We run 25 and 12.5 h-1 Mpc volumes to z = 2 with identical feedback prescriptions, the latter resolving all hydrogen-cooling haloes, and the three runs display fair resolution convergence. The specific star formation rates broadly agree with data at z = 0, but are underpredicted at z ˜ 2 by a factor of 3, re-emphasizing a longstanding puzzle in galaxy evolution models. We compare runs using MFM and two flavours of smoothed particle hydrodynamics, and show that the GSMF is sensitive to hydrodynamics methodology at the ˜×2 level, which is sub-dominant to choices for parametrizing feedback.

  7. Hydrodynamic slip length as a surface property

    Science.gov (United States)

    Ramos-Alvarado, Bladimir; Kumar, Satish; Peterson, G. P.

    2016-02-01

    Equilibrium and nonequilibrium molecular dynamics simulations were conducted in order to evaluate the hypothesis that the hydrodynamic slip length is a surface property. The system under investigation was water confined between two graphite layers to form nanochannels of different sizes (3-8 nm). The water-carbon interaction potential was calibrated by matching wettability experiments of graphitic-carbon surfaces free of airborne hydrocarbon contamination. Three equilibrium theories were used to calculate the hydrodynamic slip length. It was found that one of the recently reported equilibrium theories for the calculation of the slip length featured confinement effects, while the others resulted in calculations significantly hindered by the large margin of error observed between independent simulations. The hydrodynamic slip length was found to be channel-size independent using equilibrium calculations, i.e., suggesting a consistency with the definition of a surface property, for 5-nm channels and larger. The analysis of the individual trajectories of liquid particles revealed that the reason for observing confinement effects in 3-nm nanochannels is the high mobility of the bulk particles. Nonequilibrium calculations were not consistently affected by size but by noisiness in the smallest systems.

  8. Crystallization: Key thermodynamic, kinetic and hydrodynamic aspects

    Indian Academy of Sciences (India)

    Sreepriya Vedantam; Vivek V Ranade

    2013-12-01

    Crystallization is extensively used in different industrial applications, including the production of a wide range of materials such as fertilizers, detergents, food and pharmaceutical products, as well as in the mineral processing industries and treatment of waste effluents. In spite of the wide-spread use of crystallization, a clear understanding of the thermodynamic, kinetic and hydrodynamic aspects of the design methodologies are not yet well established. More often than not crystallization is still considered an art especially in fine-chemicals, pharmaceuticals and life-sciences sector. It is essential to understand and relate key thermodynamic, kinetic and hydrodynamic aspects to crystallizer performance, not just in terms of yield but also in terms of product quality (characterized by particle size distribution, morphology, polymorphism and the amount of strain as well as the uptake of solvent or impurities in the crystal lattice). This paper attempts to do that by critically reviewing published experimental and modelling studies on establishing and enhancing state-of-the-art thermodynamic, kinetic and hydrodynamic aspects of crystallization. Efforts are made to discuss and raise points for emerging modelling tools needed for a flexible design and operation of crystallizers and crystallization processes that are needed to meet the ever increasing demand on precise product specifications. Focus is on bringing out the trends which can be used as perspectives for future studies in this field.

  9. Hydrodynamics of an Electrochemical Membrane Bioreactor

    Science.gov (United States)

    Wang, Ya-Zhou; Wang, Yun-Kun; He, Chuan-Shu; Yang, Hou-Yun; Sheng, Guo-Ping; Shen, Jin-You; Mu, Yang; Yu, Han-Qing

    2015-05-01

    An electrochemical membrane bioreactor (EMBR) has recently been developed for energy recovery and wastewater treatment. The hydrodynamics of the EMBR would significantly affect the mass transfers and reaction kinetics, exerting a pronounced effect on reactor performance. However, only scarce information is available to date. In this study, the hydrodynamic characteristics of the EMBR were investigated through various approaches. Tracer tests were adopted to generate residence time distribution curves at various hydraulic residence times, and three hydraulic models were developed to simulate the results of tracer studies. In addition, the detailed flow patterns of the EMBR were acquired from a computational fluid dynamics (CFD) simulation. Compared to the tank-in-series and axial dispersion ones, the Martin model could describe hydraulic performance of the EBMR better. CFD simulation results clearly indicated the existence of a preferential or circuitous flow in the EMBR. Moreover, the possible locations of dead zones in the EMBR were visualized through the CFD simulation. Based on these results, the relationship between the reactor performance and the hydrodynamics of EMBR was further elucidated relative to the current generation. The results of this study would benefit the design, operation and optimization of the EMBR for simultaneous energy recovery and wastewater treatment.

  10. Hydrodynamics of spacetime and vacuum viscosity

    CERN Document Server

    Eling, Christopher

    2008-01-01

    It has recently been shown that the Einstein equation can be derived by demanding a non-equilibrium entropy balance law dS = dQ/T + dS_i hold for all local acceleration horizons through each point in spacetime. The entropy change dS is proportional to the change in horizon area while dQ and T are the energy flux across the horizon and Unruh temperature seen by an accelerating observer just inside the horizon. The internal entropy production term dS_i is proportional to the squared shear of the horizon and the ratio of the proportionality constant to the area entropy density must be \\hbar/4\\pi. Here we will show that this derivation can be reformulated in the language of hydrodynamics. We postulate that the vacuum thermal state in the Rindler wedge of spacetime obeys the holographic principle. Hydrodynamic perturbations of this state exist and are manifested in the dynamics of a stretched horizon fluid at the horizon boundary. Using the equations of hydrodynamics we derive the entropy balance law and show the ...

  11. Hydrodynamic simulations of the core helium flash

    CERN Document Server

    Mocak, M; Weiss, A; Kifonidis, K; 10.1017/S1743921308022813

    2009-01-01

    We describe and discuss hydrodynamic simulations of the core helium flash using an initial model of a 1.25 M_sol star with a metallicity of 0.02 near at its peak. Past research concerned with the dynamics of the core helium flash is inconclusive. Its results range from a confirmation of the standard picture, where the star remains in hydrostatic equilibrium during the flash (Deupree 1996), to a disruption or a significant mass loss of the star (Edwards 1969; Cole & Deupree 1980). However, the most recent multidimensional hydrodynamic study (Dearborn 2006) suggests a quiescent behavior of the core helium flash and seems to rule out an explosive scenario. Here we present partial results of a new comprehensive study of the core helium flash, which seem to confirm this qualitative behavior and give a better insight into operation of the convection zone powered by helium burning during the flash. The hydrodynamic evolution is followed on a computational grid in spherical coordinates using our new version of th...

  12. Hydrodynamic slip length as a surface property.

    Science.gov (United States)

    Ramos-Alvarado, Bladimir; Kumar, Satish; Peterson, G P

    2016-02-01

    Equilibrium and nonequilibrium molecular dynamics simulations were conducted in order to evaluate the hypothesis that the hydrodynamic slip length is a surface property. The system under investigation was water confined between two graphite layers to form nanochannels of different sizes (3-8 nm). The water-carbon interaction potential was calibrated by matching wettability experiments of graphitic-carbon surfaces free of airborne hydrocarbon contamination. Three equilibrium theories were used to calculate the hydrodynamic slip length. It was found that one of the recently reported equilibrium theories for the calculation of the slip length featured confinement effects, while the others resulted in calculations significantly hindered by the large margin of error observed between independent simulations. The hydrodynamic slip length was found to be channel-size independent using equilibrium calculations, i.e., suggesting a consistency with the definition of a surface property, for 5-nm channels and larger. The analysis of the individual trajectories of liquid particles revealed that the reason for observing confinement effects in 3-nm nanochannels is the high mobility of the bulk particles. Nonequilibrium calculations were not consistently affected by size but by noisiness in the smallest systems.

  13. Accurate, Meshless Methods for Magneto-Hydrodynamics

    CERN Document Server

    Hopkins, Philip F

    2016-01-01

    Recently, we developed a pair of meshless finite-volume Lagrangian methods for hydrodynamics: the 'meshless finite mass' (MFM) and 'meshless finite volume' (MFV) methods. These capture advantages of both smoothed-particle hydrodynamics (SPH) and adaptive mesh-refinement (AMR) schemes. Here, we extend these to include ideal magneto-hydrodynamics (MHD). The MHD equations are second-order consistent and conservative. We augment these with a divergence-cleaning scheme, which maintains div*B~0 to high accuracy. We implement these in the code GIZMO, together with a state-of-the-art implementation of SPH MHD. In every one of a large suite of test problems, the new methods are competitive with moving-mesh and AMR schemes using constrained transport (CT) to ensure div*B=0. They are able to correctly capture the growth and structure of the magneto-rotational instability (MRI), MHD turbulence, and the launching of magnetic jets, in some cases converging more rapidly than AMR codes. Compared to SPH, the MFM/MFV methods e...

  14. Use of electron ionization and atmospheric pressure chemical ionization in gas chromatography coupled to time-of-flight mass spetrometry for screening and identification of organic pollutants in waters

    NARCIS (Netherlands)

    Portoles, T.; Mol, J.G.J.; Sancho, J.V.; Hernandez, F.

    2014-01-01

    A new approach has been developed for multiclass screening of organic contaminants in water based on the use of gas chromatography coupled to hybrid quadrupole high-resolution time-of-flight mass spectrometry with atmospheric pressure chemical ionization (GC–(APCI)QTOF MS). The soft ionization promo

  15. Self-consistent hydrodynamic approach to nanoplasmonics: Resonance shifts and spill-out effects

    CERN Document Server

    Toscano, Giuseppe; Evers, Ferdinand; Xu, Hongxing; Mortensen, N Asger; Wubs, Martijn

    2014-01-01

    The standard hydrodynamic Drude model with hard-wall boundary conditions can give accurate quantitative predictions for the optical response of noble-metal nanoparticles. However, it is less accurate for other metallic nanosystems, where surface effects due to electron density spill-out in free space cannot be neglected. Here we address the fundamental question whether the description of surface effects in plasmonics necessarily requires a fully quantum-mechanical approach, such as time-dependent density-functional theory (TD-DFT), that goes beyond an effective Drude-type model. We present a more general formulation of the hydrodynamic model for the inhomogeneous electron gas, which additionally includes gradients of the electron density in the energy functional. In doing so, we arrive at a Self-Consistent Hydrodynamic Model (SC-HDM), where spill-out emerges naturally. We find a redshift for the optical response of Na nanowires, and a blueshift for Ag nanowires, which are both in quantitative agreement with e...

  16. Investigation, comparison and design of chambers used in centrifugal partition chromatography on the basis of flow pattern and separation experiments.

    Science.gov (United States)

    Schwienheer, C; Merz, J; Schembecker, G

    2015-04-17

    In centrifugal partition chromatography (CPC) the separation efficiency is mainly influenced by the hydrodynamic of mobile and stationary phase in the chambers. Thus, the hydrodynamic has to be investigated and understood in order to enhance a CPC separation run. Different chamber geometries have been developed in the past and the influence of several phase systems and CPC operating conditions were investigated for these chambers. However, a direct comparison between the different chamber types has not been performed yet. In order to investigate the direct influence of the chamber design on the hydrodynamic, several chamber designs - partially similar in geometry to commercial available designs - are investigated under standardized conditions in the present study. The results show the influence of geometrical aspects of the chamber design on the hydrodynamic and therewith, on the separation efficiency. As a conclusion of the present study, some ideas for an optimal chamber design for laboratory and industrial purpose are proposed.

  17. Radiation-hydrodynamical modelling of underluminous Type II plateau supernovae

    Science.gov (United States)

    Pumo, M. L.; Zampieri, L.; Spiro, S.; Pastorello, A.; Benetti, S.; Cappellaro, E.; Manicò, G.; Turatto, M.

    2017-01-01

    With the aim of improving our knowledge about the nature of the progenitors of low-luminosity Type II plateau supernovae (LL SNe IIP), we made radiation-hydrodynamical models of the well-sampled LL SNe IIP 2003Z, 2008bk and 2009md. For these three SNe, we infer explosion energies of 0.16-0.18 foe, radii at explosion of 1.8-3.5 × 1013 cm and ejected masses of 10-11.3 M⊙. The estimated progenitor mass on the main sequence is in the range ˜13.2-15.1 M⊙ for SN 2003Z and ˜11.4-12.9 M⊙ for SNe 2008bk and 2009md, in agreement with estimates from observations of the progenitors. These results together with those for other LL SNe IIP modelled in the same way enable us also to conduct a comparative study on this SN sub-group. The results suggest that (a) the progenitors of faint SNe IIP are slightly less massive and have less energetic explosions than those of intermediate-luminosity SNe IIP; (b) both faint and intermediate-luminosity SNe IIP originate from low-energy explosions of red (or yellow) supergiant stars of low to intermediate mass; (c) some faint objects may also be explained as electron-capture SNe from massive super-asymptotic giant branch stars; and (d) LL SNe IIP form the underluminous tail of the SNe IIP family, where the main parameter `guiding' the distribution seems to be the ratio of the total explosion energy to the ejected mass. Further hydrodynamical studies should be performed and compared to a more extended sample of LL SNe IIP before drawing any conclusion on the relevance of fall-back to this class of events.

  18. High Performance Liquid Chromatography

    Science.gov (United States)

    Talcott, Stephen

    High performance liquid chromatography (HPLC) has many applications in food chemistry. Food components that have been analyzed with HPLC include organic acids, vitamins, amino acids, sugars, nitrosamines, certain pesticides, metabolites, fatty acids, aflatoxins, pigments, and certain food additives. Unlike gas chromatography, it is not necessary for the compound being analyzed to be volatile. It is necessary, however, for the compounds to have some solubility in the mobile phase. It is important that the solubilized samples for injection be free from all particulate matter, so centrifugation and filtration are common procedures. Also, solid-phase extraction is used commonly in sample preparation to remove interfering compounds from the sample matrix prior to HPLC analysis.

  19. Micellar Electrokinetic Chromatography

    Science.gov (United States)

    Bald, Edward; Kubalczyk, Paweł

    Since the introduction of micellar electrokinetic chromatography by Terabe, several authors have paid attention to the fundamental characteristics of this separation method. In this chapter the theoretical and practical aspects of resolution optimization, as well as the effect of different separation parameters on the migration behavior are discussed. These among others include fundamentals of separation, retention factor and resolution equation, efficiency, selectivity, and various surfactants and additives. Initial conditions for method development and instrumental approaches such as mass spectrometry detection are also mentioned covering the proposals for overcoming the difficulties arising from the coupling micellar electrokinetic chromatography with mass spectrometry detection.

  20. Micellar liquid chromatography

    Science.gov (United States)

    Basova, Elena M.; Ivanov, Vadim M.; Shpigun, Oleg A.

    1999-12-01

    Background and possibilities of practical applications of micellar liquid chromatography (MLC) are considered. Various retention models in MLC, the effects of the nature and concentration of surfactants and organic modifiers, pH, temperature and ionic strength on the MLC efficiency and selectivity are discussed. The advantages and limitations of MLC are demonstrated. The performance of MLC is critically evaluated in relationship to the reversed-phase HPLC and ion-pair chromatography. The potential of application of MLC for the analysis of pharmaceuticals including that in biological fluids and separation of inorganic anions, transition metal cations, metal chelates and heteropoly compounds is described. The bibliography includes 146 references.

  1. Hydrodynamics of slip wedge and optimization of surface slip property

    Institute of Scientific and Technical Information of China (English)

    MA GuoJun; WU ChengWei; ZHOU Ping

    2007-01-01

    The hydrodynamic load support generated by a slip wedge of a slider bearing was studied. The surface slip property was optimized so that a maximum hydrodynamic load support could be obtained. A multi-linearity method was given for the slip control equation of two-dimensional (2-D) wall slip. We investigated 2-D wall slip and the hydrodynamics of a finite length bearing with any values of the surface limiting shear stress. It was found that the hydrodynamic effect of the slip wedge is greater than the traditional geometrical convergent-wedge. Even though the geometrical gap is a parallel or divergent sliding gap, the slip wedge still gives rise to a very big hydrodynamic pressure. The optimized slip wedge can give rise to a hydrodynamic load support as high as 2.5 times of what the geometrical convergent-wedge can produce. Wall slip usually gives a small surface friction.

  2. Assessment for hydrodynamic masses of HANARO flow tubes

    Energy Technology Data Exchange (ETDEWEB)

    Ryu, Jeong Soo; Cho, Yeong Garp; Kim, Doo Kie; Woo, Jong Sug; Park, Jin Ho

    2000-06-01

    The effect of hydrodynamic masses is investigated in dynamic characteristics and seismic response analyses of the submerged HANARO hexagonal flow tubes. Consistent hydrodynamic masses of the surrounding water are evaluated by the prepared program using the finite element method, in which arbitrary cross-sections of submerged structures and boundary conditions of the surrounding fluid can be considered. Also lumped hydrodynamic masses are calculated using simple formula applied to hexagonal flow tubes in the infinite fluid. Modal analyses and seismic response spectrum analyses were performed using hydrodynamic masses obtained by the finite element method and the simple formula. The results of modal analysis were verified by comparing the results measured from modal tests. And the displacement results of the seismic response spectrum analysis were assessed by comparing the consistent and the lumped hydrodynamic masses obtained by various methods. Finally practical criteria based on parametric studies are proposed as the lumped hydrodynamic masses for HANARO flow tubes.

  3. An overview of hydrodynamic studies of mineralization

    Directory of Open Access Journals (Sweden)

    Guoxiang Chi

    2011-07-01

    Full Text Available Fluid flow is an integral part of hydrothermal mineralization, and its analysis and characterization constitute an important part of a mineralization model. The hydrodynamic study of mineralization deals with analyzing the driving forces, fluid pressure regimes, fluid flow rate and direction, and their relationships with localization of mineralization. This paper reviews the principles and methods of hydrodynamic studies of mineralization, and discusses their significance and limitations for ore deposit studies and mineral exploration. The driving forces of fluid flow may be related to fluid overpressure, topographic relief, tectonic deformation, and fluid density change due to heating or salinity variation, depending on specific geologic environments and mineralization processes. The study methods may be classified into three types, megascopic (field observations, microscopic analyses, and numerical modeling. Megascopic features indicative of significantly overpressured (especially lithostatic or supralithostatic fluid systems include horizontal veins, sand injection dikes, and hydraulic breccias. Microscopic studies, especially microthermometry of fluid inclusions and combined stress analysis and microthermometry of fluid inclusion planes (FIPs can provide important information about fluid temperature, pressure, and fluid-structural relationships, thus constraining fluid flow models. Numerical modeling can be carried out to solve partial differential equations governing fluid flow, heat transfer, rock deformation and chemical reactions, in order to simulate the distribution of fluid pressure, temperature, fluid flow rate and direction, and mineral precipitation or dissolution in 2D or 3D space and through time. The results of hydrodynamic studies of mineralization can enhance our understanding of the formation processes of hydrothermal deposits, and can be used directly or indirectly in mineral exploration.

  4. Hydrodynamic impact of particle shape in slurry packed liquid chromatography columns

    DEFF Research Database (Denmark)

    Lottes, F.; Arlt, W.; Minceva, M.;

    2009-01-01

    We report on a series of flow velocity and efficiency profiles, which were measured across the cross section of preparative chromatographic columns packed with different stationary phase materials using computed tomography. It is shown that this non-invasive technique is very useful for visualiza......We report on a series of flow velocity and efficiency profiles, which were measured across the cross section of preparative chromatographic columns packed with different stationary phase materials using computed tomography. It is shown that this non-invasive technique is very useful...... for visualization of the inner part of a packed column and measurement of the spatial resolved column packing properties. For evaluation of the influence of the particle shape on the velocity distribution and column performance, irregular and spherical reversed phases were studied in detail. The results showed...... a decreasing velocity towards the column wall most certainly due to a lower permeability. This effect was much less pronounced in the case of spherical particles, indicating a more homogenous packing structure. The influence of the column packing pressure, as a possible measure for improvement of the packing...

  5. Smoothed Particle Hydrodynamics for the Simulation of Laser Produced Plasmas

    Science.gov (United States)

    Griffith, Alec; Holladay, Tyler; Murillo, Michael S.

    2016-10-01

    To address the design and interpretation of experiments at next generation light sources such as at the SLAC LCLS and the LANL proposed MaRIE a simulation of the laser produced plasma targets has been developed. Smoothed particle hydrodynamics is used to capture the full experimental time and length scales, large degrees of deformation, and the experimental environment's open boundary conditions. Additionally the model incorporates plasma transport with thermal conduction, the electric potential, and a two species model of the electrons and ions. The electron and ion particle representations in SPH allow for time dependent ionization and recombination while addressing the disparate masses of the two species. To gain computational speedup our simulation takes advantage of parallelism, and to reduce computational cost we have explored using data structures such as the linked cell list and octree as well as algorithmic techniques such as the fast mutipole method. We will discuss the results of simulating several possible experimental configurations using our model. This work was supported by the Los Alamos National Laboratory computational physics workshop.

  6. Kinetics and Hydrodynamics of Silver Ion Flotation

    OpenAIRE

    2012-01-01

    This paper studies and determines the dispersion properties (Jg, Eg and Db), kinetics parameters and hydrodynamics of the process and its effect on the recovery of silver contained in spent diluted fixers by techniques of ion flotation in columns. The experimental results show silver recoveries of 97 % using sodium isopropyl xanthate (SIX) 0.06 g·L-1 and 0.04 g·L-1 of frother, at a Jg of 1.0 cm·s-1 and Jl of 0.72 cm·s-1. Xanthate-promoter combinations do not improve the separation; however, r...

  7. Anomalous transport in second order hydrodynamics

    Science.gov (United States)

    Megías, Eugenio; Valle, Manuel

    2016-11-01

    We study the non-dissipative transport effects appearing at second order in the hydrodynamic expansion for a non-interacting gas of chiral fermions by using the partition function formalism. We discuss some features of the corresponding constitutive relations, derive the explicit expressions for the conductivities and compare with existing results in the literature. Talk given by E. Megías at the 4th International Conference on New Frontiers in Physics (ICNFP 2015), 23-30 August 2015, Kolymbari, Crete, Greece.

  8. Dual-support Smoothed Particle Hydrodynamics

    CERN Document Server

    Ren, Huilong; Zhuang, Xiaoying; Rabczuk, Timon

    2016-01-01

    In this paper we develop a dual-support smoothed particle hydrodynamics (DS-SPH) that naturally satisfies the conservation of momentum, angular momentum and energy when the varying smoothing length is utilized. The DS-SPH is based on the concept of dual-support, which is introduced to consider the unbalanced interactions between the particles with different smoothing lengths. Our DS-SPH formulation can be implemented in traditional SPH with little changes and improve the computational efficiency. Several numerical examples are presented to demonstrate the capability of the method.

  9. Hydrodynamic approach to p–Pb

    Energy Technology Data Exchange (ETDEWEB)

    Bożek, Piotr, E-mail: piotr.bozek@ifj.edu.pl [AGH University of Science and Technology, Faculty of Physics and Applied Computer Science, PL-30059 Kraków (Poland); Institute of Nuclear Physics PAN, PL-31342 Kraków (Poland); Broniowski, Wojciech, E-mail: wojciech.broniowski@ifj.edu.pl [Institute of Nuclear Physics PAN, PL-31342 Kraków (Poland); Institute of Physics, Jan Kochanowski University, PL-25406 Kielce (Poland)

    2014-06-15

    The formation and collective expansion of the fireball formed in ultrarelativistic p–A and d–A collisions is discussed. Predictions of the hydrodynamic model are compared to recent experimental results. The presence of strong final state interaction effects in the small dense systems is consistent with the observed azimuthal anisotropy of the flow and with the mass dependence of the average transverse momentum and of the elliptic flow. This raises the question of the mechanism explaining such a rapid build-up of the collective flow and the large degree of local equilibration needed to justify this scenario.

  10. Postexplosion hydrodynamics of supernovae in red supergiants

    Science.gov (United States)

    Herant, Marc; Woosley, S. E.

    1994-01-01

    Shock propagation, mixing, and clumping are studied in the explosion of red supergiants as Type II supernovae using a two-dimensional smooth particle hydrodynamic (SPH) code. We show that extensive Rayleigh-Talor instabilities develop in the ejecta in the wake of the reverse shock wave. In all cases, the shell structure of the progenitor is obliterated to leave a clumpy, well-mixed supernova remnant. However, the occurrence of mass loss during the lifetime of the progenitor can significantly reduce the amount of mixing. These results are independent of the Type II supernova explosion mechanism.

  11. Fast lattice Boltzmann solver for relativistic hydrodynamics.

    Science.gov (United States)

    Mendoza, M; Boghosian, B M; Herrmann, H J; Succi, S

    2010-07-01

    A lattice Boltzmann formulation for relativistic fluids is presented and numerically validated through quantitative comparison with recent hydrodynamic simulations of relativistic fluids. In order to illustrate its capability to handle complex geometries, the scheme is also applied to the case of a three-dimensional relativistic shock wave, generated by a supernova explosion, impacting on a massive interstellar cloud. This formulation opens up the possibility of exporting the proven advantages of lattice Boltzmann methods, namely, computational efficiency and easy handling of complex geometries, to the context of (mildly) relativistic fluid dynamics at large, from quark-gluon plasmas up to supernovae with relativistic outflows.

  12. Hydrodynamic modeling of ns-laser ablation

    Directory of Open Access Journals (Sweden)

    David Autrique

    2013-10-01

    Full Text Available Laser ablation is a versatile and widespread technique, applied in an increasing number of medical, industrial and analytical applications. A hydrodynamic multiphase model describing nanosecond-laser ablation (ns-LA is outlined. The model accounts for target heating and mass removal mechanisms as well as plume expansion and plasma formation. A copper target is placed in an ambient environment consisting of helium and irradiated by a nanosecond-laser pulse. The effect of variable laser settings on the ablation process is explored in 1-D numerical simulations.

  13. Impact modeling with Smooth Particle Hydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Stellingwerf, R.F.; Wingate, C.A.

    1993-07-01

    Smooth Particle Hydrodynamics (SPH) can be used to model hypervelocity impact phenomena via the addition of a strength of materials treatment. SPH is the only technique that can model such problems efficiently due to the combination of 3-dimensional geometry, large translations of material, large deformations, and large void fractions for most problems of interest. This makes SPH an ideal candidate for modeling of asteroid impact, spacecraft shield modeling, and planetary accretion. In this paper we describe the derivation of the strength equations in SPH, show several basic code tests, and present several impact test cases with experimental comparisons.

  14. Hydrodynamics of anisotropic quark and gluon fluids

    Science.gov (United States)

    Florkowski, Wojciech; Maj, Radoslaw; Ryblewski, Radoslaw; Strickland, Michael

    2013-03-01

    The recently developed framework of anisotropic hydrodynamics is generalized to describe the dynamics of coupled quark and gluon fluids. The quark and gluon components of the fluids are characterized by different dynamical anisotropy parameters. The dynamical equations describing such mixtures are derived from kinetic theory, with the collisional kernel treated in the relaxation-time approximation, allowing for different relaxation times for quarks and gluons. Baryon number conservation is enforced in the quark and antiquark components of the fluid, but overall parton number nonconservation is allowed in the system. The resulting equations are solved numerically in the (0+1)-dimensional boost-invariant case at zero and finite baryon density.

  15. Hydrodynamics of anisotropic quark and gluon fluids

    CERN Document Server

    Florkowski, Wojciech; Ryblewski, Radoslaw; Strickland, Michael

    2012-01-01

    The recently developed framework of anisotropic hydrodynamics is generalized to describe the dynamics of coupled quark and gluon fluids. The quark and gluon components of the fluids are characterized by different dynamical anisotropy parameters. The dynamical equations describing such mixtures are derived from kinetic theory with the collisional kernel treated in the relaxation-time approximation. Baryon number conservation is enforced in the quark and anti-quark components of the fluid, but overall parton number non-conservation is allowed in the system. The resulting equations are solved numerically in the (0+1)-dimensional boost-invariant case at zero and finite baryon density.

  16. Effect of geometry on hydrodynamic film thickness

    Science.gov (United States)

    Brewe, D. E.; Hamrock, B. J.; Taylor, C. M.

    1978-01-01

    The influence of geometry on the isothermal hydrodynamic film separating two rigid solids was investigated. Pressure-viscosity effects were not considered. The minimum film thickness is derived for fully flooded conjunctions by using the Reynolds boundary conditions. It was found that the minimum film thickness had the same speed, viscosity, and load dependence as Kapitza's classical solution. However, the incorporation of Reynolds boundary conditions resulted in an additional geometry effect. Solutions using the parabolic film approximation are compared with those using the exact expression for the film in the analysis. Contour plots are shown that indicate in detail the pressure developed between the solids.

  17. Hydrodynamic Study Of Column Bioleaching Processes

    Directory of Open Access Journals (Sweden)

    Sadowski Zygmunt

    2015-06-01

    Full Text Available The modelling of flow leaching solution through the porous media has been considered. The heap bioleaching process can be tested using the column experimental equipment. This equipment was employed to the hydrodynamic studies of copper ore bioleaching. The copper ore (black shale ore with the support, inertial materials (glass small balls and polyethylene beads was used to the bioleaching tests. The packed beds were various composition, the ore/support ratio was changed. The correlation between the bed porosity and bioleaching kinetics, and copper recovery was investigated.

  18. Rapidity Correlation Structures from Causal Hydrodynamics

    CERN Document Server

    Gavin, Sean; Zin, Christopher

    2016-01-01

    Viscous diffusion can broaden the rapidity dependence of two-particle transverse momentum fluctuations. Surprisingly, measurements at RHIC by the STAR collaboration demonstrate that this broadening is accompanied by the appearance of unanticipated structure in the rapidity distribution of these fluctuations in the most central collisions. Although a first order classical Navier-Stokes theory can roughly explain the rapidity broadening, it cannot explain the additional structure. We propose that the rapidity structure can be explained using the second order causal Israel-Stewart hydrodynamics with stochastic noise.

  19. Hydrodynamic instabilities in an ablation front

    Energy Technology Data Exchange (ETDEWEB)

    Piriz, A R; Portugues, R F [E.T.S.I. Industriales, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain)

    2004-06-01

    The hydrodynamic stability of an ablation front is studied for situations in which the wavelength of the perturbations is larger than the distance to the critical surface where the driving radiation is absorbed. An analytical model is presented, and it shows that under conditions in which the thermal flux is limited within the supercritical region of the ablative corona, the front may behave like a flame or like an ablation front, depending on the perturbation wavelength. For relatively long wavelengths the critical and ablation surfaces practically lump together into a unique surface and the front behaves like a flame, whereas for the shortest wavelengths the ablation front substructure is resolved.

  20. Computer simulation of the fire-tube boiler hydrodynamics

    OpenAIRE

    Khaustov Sergei A.; Zavorin Alexander S.; Buvakov Konstantin V.; Sheikin Vyacheslav A.

    2015-01-01

    Finite element method was used for simulating the hydrodynamics of fire-tube boiler with the ANSYS Fluent 12.1.4 engineering simulation software. Hydrodynamic structure and volumetric temperature distribution were calculated. The results are presented in graphical form. Complete geometric model of the fire-tube boiler based on boiler drawings was considered. Obtained results are suitable for qualitative analysis of hydrodynamics and singularities identification in fire-tube boiler water shell.

  1. Hydrodynamic Analysis to Process of Hydrostatic Extrusion for Tungsten Alloy

    Institute of Scientific and Technical Information of China (English)

    Fuchi WANG; Zhaohui ZHANG; Shukui LI

    2001-01-01

    The hydrodynamic analysis to the process of the hydrostatic extrusion for tungsten alloy is carried through the hydrodynamic lubrication theory and Reynolds equation in this paper. The critical velocity equation when the hydrodynamic lubrication conditions appear between the surfaces of the work- piece and the die is obtained, and the relationship between the critical velocity and the extrusion parameters is discussed, which build the theoretical bases to the application of the hydrostatic extrusion for tungsten alloy.

  2. Computer simulation of the fire-tube boiler hydrodynamics

    Directory of Open Access Journals (Sweden)

    Khaustov Sergei A.

    2015-01-01

    Full Text Available Finite element method was used for simulating the hydrodynamics of fire-tube boiler with the ANSYS Fluent 12.1.4 engineering simulation software. Hydrodynamic structure and volumetric temperature distribution were calculated. The results are presented in graphical form. Complete geometric model of the fire-tube boiler based on boiler drawings was considered. Obtained results are suitable for qualitative analysis of hydrodynamics and singularities identification in fire-tube boiler water shell.

  3. Intrinsic ambiguity in second order viscosity parameters in relativistic hydrodynamics

    CERN Document Server

    Nakayama, Yu

    2012-01-01

    We show that relativistic hydrodynamics in Minkowski space-time has intrinsic ambiguity in second order viscosity parameters in the Landau-Lifshitz frame. This stems from the possibility of improvements of energy-momentum tensor. There exist at least two viscosity parameters which can be removed by using this ambiguity in scale invariant hydrodynamics in (1+3) dimension, and seemingly non-conformal hydrodynamic theories can be hiddenly conformal invariant.

  4. Hydrodynamic Coefficients of Ships with Forward Speed in Shallow Waters

    Institute of Scientific and Technical Information of China (English)

    M.HASANADIL; DUANWen-yang; WANGYu

    2004-01-01

    Effects of depth and forward speed on hydrodynamic coefficients of ships are presented in this paper. A modified simple Green function technique was used to calculate 2D coefficients while strip theory was used to calculate 3D coefficients. Numerical results are provided for hydrodynamic coefficients of parabolic hull ship. It is found out that both depth and forward speed have considerable effects on hydrodynamic coefficients of ship.

  5. PREDICTION OF HYDRODYNAMIC PERFORMANCE OF THE FLAP RUDDER

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The paper presents a new method for predicting the hydrodynamic performance of the flap rudder behind a propeller. The hydrodynamics of the rudder was calculated by the panel method and the performance of the propeller was predicted by the simplified propeller theoty. The interaction between the rudder and propeller was determined by iterative procedure. The pressure distribution on rudder surface and the hydrodynamic performance of the flap rudder are discussed in the paper.

  6. ASYMPTOTIC LIMITS OF ONE-DIMENSIONAL HYDRODYNAMIC MODELS FOR PLASMAS AND SEMICONDUCTORS

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    This paper studies the zero-electron-mass limit, the quasi-neutral limit and the zerorelaxation-time limit in one-dimensional hydrodynamic models of Euler-Poisson system for plasmas and semiconductors. For each limit in the steady-state models, the author proves the strong convergence of the sequence of solutions and gives the corresponding convergence rate. In the time-dependent models, the author shows some useful estimates for the quasi-neutral limit and the zero-electron-mass limit. This study completes the analysis made in [11,12,13,14,19].

  7. A hydrodynamically suspended, magnetically sealed mechanically noncontact axial flow blood pump: design of a hydrodynamic bearing.

    Science.gov (United States)

    Mitamura, Yoshinori; Kido, Kazuyuki; Yano, Tetsuya; Sakota, Daisuke; Yambe, Tomoyuki; Sekine, Kazumitsu; OKamoto, Eiji

    2007-03-01

    To overcome the drive shaft seal and bearing problem in rotary blood pumps, a hydrodynamic bearing, a magnetic fluid seal, and a brushless direct current (DC) motor were employed in an axial flow pump. This enabled contact-free rotation of the impeller without material wear. The axial flow pump consisted of a brushless DC motor, an impeller, and a guide vane. The motor rotor was directly connected to the impeller by a motor shaft. A hydrodynamic bearing was installed on the motor shaft. The motor and the hydrodynamic bearing were housed in a cylindrical casing and were waterproofed by a magnetic fluid seal, a mechanically noncontact seal. Impeller shaft displacement was measured using a laser sensor. Axial and radial displacements of the shaft were only a few micrometers for motor speed up to 8500 rpm. The shaft did not make contact with the bearing housing. A flow of 5 L/min was obtained at 8000 rpm at a pressure difference of 100 mm Hg. In conclusion, the axial flow blood pump consisting of a hydrodynamic bearing, a magnetic fluid seal, and a brushless DC motor provided contact-free rotation of the impeller without material wear.

  8. UNIFIED THEORETICAL MOMENT EXPRESSIONS FOR ELUTION CHROMATOGRAPHY AND FRONTAL CHROMATOGRAPHY

    Institute of Scientific and Technical Information of China (English)

    YANGGengliang; TAOZuyi

    1992-01-01

    The unified theoretical moment expressions for elution chromatography and frontal chromatography when the sorption process is described by a linear model were derived. The moment expressions derived by previous authors can be obtained from these unified theoretical moment expressions. In this paper, a mathematical analysis has been carried out so as to set up a unified theoretical basis for elution and frontal chromatography.

  9. Hydrodynamization and transient modes of expanding plasma in kinetic theory

    CERN Document Server

    Heller, Michal P; Spalinski, Michal

    2016-01-01

    We study the transition to hydrodynamics in a weakly-coupled model of quark-gluon plasma given by kinetic theory in the relaxation time approximation. Our studies uncover qualitative similarities to the results on hydrodynamization in strongly coupled gauge theories. In particular, we demonstrate that the gradient expansion in this model has vanishing radius of convergence. The asymptotic character of the hydrodynamic gradient expansion is crucial for the recently discovered applicability of hydrodynamics at large gradients. Furthermore, the analysis of the resurgent properties of the series provides, quite remarkably, indication for the existence of a novel transient, damped oscillatory mode of expanding plasmas in kinetic theory.

  10. Hydrodynamic force between a sphere and a soft, elastic surface.

    Science.gov (United States)

    Kaveh, Farzaneh; Ally, Javed; Kappl, Michael; Butt, Hans-Jürgen

    2014-10-07

    The hydrodynamic drainage force between a spherical silica particle and a soft, elastic polydimethylsiloxane surface was measured using the colloidal probe technique. The experimental force curves were compared to finite element simulations and an analytical model. The hydrodynamic repulsion decreased when the particle approached the soft surface as compared to a hard substrate. In contrast, when the particle was pulled away from the surface again, the attractive hydrodynamic force was increased. The hydrodynamic attraction increased because the effective area of the narrow gap between sphere and the plane on soft surfaces is larger than on rigid ones.

  11. Methodology for optimally sized centrifugal partition chromatography columns.

    Science.gov (United States)

    Chollet, Sébastien; Marchal, Luc; Jérémy Meucci; Renault, Jean-Hugues; Legrand, Jack; Foucault, Alain

    2015-04-01

    Centrifugal Partition Chromatography (CPC) is a separation process based on the partitioning of solutes between two partially miscible liquid phases. There is no solid support for the stationary phase. The centrifugal acceleration is responsible for both stationary phase retention and mobile phase dispersion. CPC is thus a process based on liquid-liquid mass transfer. The separation efficiency is mainly influenced by the hydrodynamics of the phases in each cell of the column. Thanks to a visualization system, called "Visual CPC", it was observed that the mobile phase can flow through the stationary phase as a sheet, or a spray. Hydrodynamics, which directly governs the instrument efficiency, is directly affected during scale changes, and non-linear phenomena prevent the successful achievement of mastered geometrical scale changes. In this work, a methodology for CPC column sizing is proposed, based on the characterization of the efficiency of advanced cell shapes, taking into account the hydrodynamics. Knowledge about relationship between stationary phase volume, cell efficiency and separation resolution in CPC allowed calculating the optimum cell number for laboratory and industrial scale CPC application. The methodology is highlighted with results on five different geometries from 25 to 5000 mL, for two applications: the separation of alkylbenzene by partitioning with heptane/methanol/water biphasic system; and the separation of peptides by partitioning with n-butanol/acetic acid/water (4/1/5) biphasic system. With this approach, it is possible to predict the optimal CPC column length leading to highest productivity.

  12. Modern Thin-Layer Chromatography.

    Science.gov (United States)

    Poole, Colin F.; Poole, Salwa K.

    1989-01-01

    Some of the important modern developments of thin-layer chromatography are introduced. Discussed are the theory and instrumentation of thin-layer chromatography including multidimensional and multimodal techniques. Lists 53 references. (CW)

  13. Modern Thin-Layer Chromatography.

    Science.gov (United States)

    Poole, Colin F.; Poole, Salwa K.

    1989-01-01

    Some of the important modern developments of thin-layer chromatography are introduced. Discussed are the theory and instrumentation of thin-layer chromatography including multidimensional and multimodal techniques. Lists 53 references. (CW)

  14. Chromatography in industry

    NARCIS (Netherlands)

    Schoenmakers, P.

    2009-01-01

    This review focuses on the chromatography research that has been carried out within industry or in close cooperation with industry and that has been reported in the scientific literature between 2006 and mid-2008. Companies in the health care sector, such as pharmaceutical and biotechnology companie

  15. Extending Paper Chromatography Inquiry

    Science.gov (United States)

    Finson, Kevin

    2004-01-01

    One of the "good old" standard activities middle school students seem to enjoy is paper chromatography. The procedures and materials needed are relatively simple and the results can be colorful. All too often, the activity ends just after these colorful results are obtained, cutting short the potential it holds for some further inquiry. With some…

  16. Thermal equilibrium solution to new model of bipolar hybrid quantum hydrodynamics

    Science.gov (United States)

    Di Michele, Federica; Mei, Ming; Rubino, Bruno; Sampalmieri, Rosella

    2017-08-01

    In this paper we study the hybrid quantum hydrodynamic model for nano-sized bipolar semiconductor devices in thermal equilibrium. By introducing a hybrid version of the Bhom potential, we derive a bipolar hybrid quantum hydrodynamic model, which is able to account for quantum effects in a localized region of the device for both electrons and holes. Coupled with Poisson equation for the electric potential, the steady-state system is regionally degenerate in its ellipticity, due to the quantum effect only in part of the device. This regional degeneracy of ellipticity makes the study more challenging. The main purpose of the paper is to investigate the existence and uniqueness of the weak solutions to this new type of equations. We first establish the uniform boundedness of the smooth solutions to the modified bipolar quantum hydrodynamic model by the variational method, then we use the compactness technique to prove the existence of weak solutions to the original hybrid system by taking hybrid limit. In particular, we account for two different kinds of hybrid behaviour. We perform the first hybrid limit when both electrons and holes behave quantum in a given region of the device, and the second one when only one carrier exhibits hybrid behaviour, whereas the other one is presented classically in the whole domain. The semi-classical limit results are also obtained. Finally, the theoretical results are tested numerically on a simple toy model.

  17. Peak capacity in unidimensional chromatography.

    Science.gov (United States)

    Neue, Uwe Dieter

    2008-03-14

    The currently existing knowledge about peak capacity in unidimensional separations is reviewed. The majority of the paper is dedicated to reversed-phase gradient chromatography, covering specific techniques as well as the subject of peak compression. Other sections deal with peak capacity in isocratic chromatography, size-exclusion chromatography and ion-exchange chromatography. An important topic is the limitation of the separation power and the meaning of the concept of peak capacity for real applications.

  18. Hydrodynamics of nearly smooth granular gases.

    Science.gov (United States)

    Goldhirsch, I; Noskowicz, S H; Bar-Lev, O

    2005-11-17

    Hydrodynamic equations of motion for a monodisperse collection of nearly smooth homogeneous spheres have been derived from the corresponding Boltzmann equation, using a Chapman-Enskog expansion around the elastic smooth spheres limit. Because in the smooth limit the rotational degrees of freedom are uncoupled from the translational ones, it turns out that the required hydrodynamic fields include (in addition to the standard density, velocity, and translational granular temperature fields) the (infinite) set of number densities, n(s,r, t), corresponding to the continuum of values of the angular velocities. The Chapman-Enskog expansion was carried out to high (up to 10th) order in a Sonine polynomial expansion by using a novel computer-aided method. One of the consequences of these equations is that the asymptotic spin distribution in the homogeneous cooling state for nearly smooth, nearly elastic spheres, is highly non-Maxwellian. The simple sheared flow possesses a highly non-Maxwellian distribution as well. In the case of wall-bounded shear, it is shown that the angular velocity injected at the boundaries has a finite penetration length.

  19. Particle Mesh Hydrodynamics for Astrophysics Simulations

    Science.gov (United States)

    Chatelain, Philippe; Cottet, Georges-Henri; Koumoutsakos, Petros

    We present a particle method for the simulation of three dimensional compressible hydrodynamics based on a hybrid Particle-Mesh discretization of the governing equations. The method is rooted on the regularization of particle locations as in remeshed Smoothed Particle Hydrodynamics (rSPH). The rSPH method was recently introduced to remedy problems associated with the distortion of computational elements in SPH, by periodically re-initializing the particle positions and by using high order interpolation kernels. In the PMH formulation, the particles solely handle the convective part of the compressible Euler equations. The particle quantities are then interpolated onto a mesh, where the pressure terms are computed. PMH, like SPH, is free of the convection CFL condition while at the same time it is more efficient as derivatives are computed on a mesh rather than particle-particle interactions. PMH does not detract from the adaptive character of SPH and allows for control of its accuracy. We present simulations of a benchmark astrophysics problem demonstrating the capabilities of this approach.

  20. Building a Hydrodynamics Code with Kinetic Theory

    CERN Document Server

    Sagert, Irina; Colbry, Dirk; Pickett, Rodney; Strother, Terrance

    2013-01-01

    We report on the development of a test-particle based kinetic Monte Carlo code for large systems and its application to simulate matter in the continuum regime. Our code combines advantages of the Direct Simulation Monte Carlo and the Point-of-Closest-Approach methods to solve the collision integral of the Boltzmann equation. With that, we achieve a high spatial accuracy in simulations while maintaining computational feasibility when applying a large number of test-particles. The hybrid setup of our approach allows us to study systems which move in and out of the hydrodynamic regime, with low and high particle densities. To demonstrate our code's ability to reproduce hydrodynamic behavior we perform shock wave simulations and focus here on the Sedov blast wave test. The blast wave problem describes the evolution of a spherical expanding shock front and is an important verification problem for codes which are applied in astrophysical simulation, especially for approaches which aim to study core-collapse supern...

  1. Flagellar synchronization through direct hydrodynamic interactions.

    Science.gov (United States)

    Brumley, Douglas R; Wan, Kirsty Y; Polin, Marco; Goldstein, Raymond E

    2014-07-29

    Flows generated by ensembles of flagella are crucial to development, motility and sensing, but the mechanisms behind this striking coordination remain unclear. We present novel experiments in which two micropipette-held somatic cells of Volvox carteri, with distinct intrinsic beating frequencies, are studied by high-speed imaging as a function of their separation and orientation. Analysis of time series shows that the interflagellar coupling, constrained by lack of connections between cells to be hydrodynamical, exhibits a spatial dependence consistent with theory. At close spacings it produces robust synchrony for thousands of beats, while at increasing separations synchrony is degraded by stochastic processes. Manipulation of the relative flagellar orientation reveals in-phase and antiphase states, consistent with dynamical theories. Flagellar tracking with exquisite precision reveals waveform changes that result from hydrodynamic coupling. This study proves unequivocally that flagella coupled solely through a fluid can achieve robust synchrony despite differences in their intrinsic properties.DOI: http://dx.doi.org/10.7554/eLife.02750.001.

  2. Anisotropic matching principle for the hydrodynamic expansion

    Science.gov (United States)

    Tinti, Leonardo

    2016-10-01

    Following the recent success of anisotropic hydrodynamics, I propose here a new, general prescription for the hydrodynamic expansion around an anisotropic background. The anisotropic distribution fixes exactly the complete energy-momentum tensor, just like the effective temperature fixes the proper energy density in the ordinary expansion around local equilibrium. This means that momentum anisotropies are already included at the leading order, allowing for large pressure anisotropies without the need of a next-to-leading-order treatment. The first moment of the Boltzmann equation (local four-momentum conservation) provides the time evolution of the proper energy density and the four-velocity. Differently from previous prescriptions, the dynamic equations for the pressure corrections are not derived from the zeroth or second moment of the Boltzmann equation, but they are taken directly from the exact evolution given by the Boltzmann equation. As known in the literature, the exact evolution of the pressure corrections involves higher moments of the Boltzmann distribution, which cannot be fixed by the anisotropic distribution alone. Neglecting the next-to-leading-order contributions corresponds to an approximation, which depends on the chosen form of the anisotropic distribution. I check the the effectiveness of the leading-order expansion around the generalized Romatschke-Stricklad distribution, comparing with the exact solution of the Boltzmann equation in the Bjorken limit with the collisional kernel treated in the relaxation-time approximation, finding an unprecedented agreement.

  3. Three Dimensional Hydrodynamic Model With Multiquadtree Meshes

    Directory of Open Access Journals (Sweden)

    G. P. Vanegas

    2008-01-01

    Full Text Available This study presents a three dimensional model for the transport of conservative contaminants, which can be used for bodies of water which are affected by winds and/or tides. The model solves the equation of mass transport, based on results obtained using a hydrodynamic model for shallow waters that works in a finite volume scheme and a type of hierarchical grid, called multi-quadtree, which is adaptable to the bathymetry. To solve the vertical coordinates, the coordinate z is transformed into a sigma (σ coordinate, thus allowing the same number of layers in the vertical, regardless of depth. This hydrodynamic model is validated using two cases: a long wave propagated in a channel of variable width and bottom and wind action in a rectangular basin. Finally, the results obtained are presented for a hypothetical single port outfall in the bay of Campeche, México. The model developed here is both quick and easy to use and is efficient when compared with models presented by other authors since it uses adaptable grids which allow detailed solutions to be obtained for areas of interest such as coastlines and the area around an outfall.

  4. Relativistic hydrodynamics on graphics processing units

    CERN Document Server

    Sikorski, Jan; Porter-Sobieraj, Joanna; Słodkowski, Marcin; Krzyżanowski, Piotr; Książek, Natalia; Duda, Przemysław

    2016-01-01

    Hydrodynamics calculations have been successfully used in studies of the bulk properties of the Quark-Gluon Plasma, particularly of elliptic flow and shear viscosity. However, there are areas (for instance event-by-event simulations for flow fluctuations and higher-order flow harmonics studies) where further advancement is hampered by lack of efficient and precise 3+1D~program. This problem can be solved by using Graphics Processing Unit (GPU) computing, which offers unprecedented increase of the computing power compared to standard CPU simulations. In this work, we present an implementation of 3+1D ideal hydrodynamics simulations on the Graphics Processing Unit using Nvidia CUDA framework. MUSTA-FORCE (MUlti STAge, First ORder CEntral, with a~slope limiter and MUSCL reconstruction) and WENO (Weighted Essentially Non-Oscillating) schemes are employed in the simulations, delivering second (MUSTA-FORCE), fifth and seventh (WENO) order of accuracy. Third order Runge-Kutta scheme was used for integration in the t...

  5. Mix and hydrodynamic instabilities on NIF

    Science.gov (United States)

    Smalyuk, V. A.; Robey, H. F.; Casey, D. T.; Clark, D. S.; Döppner, T.; Haan, S. W.; Hammel, B. A.; MacPhee, A. G.; Martinez, D.; Milovich, J. L.; Peterson, J. L.; Pickworth, L.; Pino, J. E.; Raman, K.; Tipton, R.; Weber, C. R.; Baker, K. L.; Bachmann, B.; Berzak Hopkins, L. F.; Bond, E.; Caggiano, J. A.; Callahan, D. A.; Celliers, P. M.; Cerjan, C.; Dixit, S. N.; Edwards, M. J.; Felker, S.; Field, J. E.; Fittinghoff, D. N.; Gharibyan, N.; Grim, G. P.; Hamza, A. V.; Hatarik, R.; Hohenberger, M.; Hsing, W. W.; Hurricane, O. A.; Jancaitis, K. S.; Jones, O. S.; Khan, S.; Kroll, J. J.; Lafortune, K. N.; Landen, O. L.; Ma, T.; MacGowan, B. J.; Masse, L.; Moore, A. S.; Nagel, S. R.; Nikroo, A.; Pak, A.; Patel, P. K.; Remington, B. A.; Sayre, D. B.; Spears, B. K.; Stadermann, M.; Tommasini, R.; Widmayer, C. C.; Yeamans, C. B.; Crippen, J.; Farrell, M.; Giraldez, E.; Rice, N.; Wilde, C. H.; Volegov, P. L.; Gatu Johnson, M.

    2017-06-01

    Several new platforms have been developed to experimentally measure hydrodynamic instabilities in all phases of indirect-drive, inertial confinement fusion implosions on National Ignition Facility. At the ablation front, instability growth of pre-imposed modulations was measured with a face-on, x-ray radiography platform in the linear regime using the Hydrodynamic Growth Radiography (HGR) platform. Modulation growth of "native roughness" modulations and engineering features (fill tubes and capsule support membranes) were measured in conditions relevant to layered DT implosions. A new experimental platform was developed to measure instability growth at the ablator-ice interface. In the deceleration phase of implosions, several experimental platforms were developed to measure both low-mode asymmetries and high-mode perturbations near peak compression with x-ray and nuclear techniques. In one innovative technique, the self-emission from the hot spot was enhanced with argon dopant to "self-backlight" the shell in-flight. To stabilize instability growth, new "adiabat-shaping" techniques were developed using the HGR platform and applied in layered DT implosions.

  6. Multithread Hydrodynamic Modeling of a Solar Flare

    Science.gov (United States)

    Warren, Harry P.

    2006-01-01

    Past hydrodynamic simulations have been able to reproduce the high temperatures and densities characteristic of solar flares. These simulations, however, have not been able to account for the slow decay of the observed flare emission or the absence of blueshifts in high spectral resolution line profiles. Recent work has suggested that modeling a flare as a sequence of independently heated threads instead of as a single loop may resolve the discrepancies between the simulations and observations. In this paper, we present a method for computing multithread, time-dependent hydrodynamic simulations of solar flares and apply it to observations of the Masuda flare of 1992 January 13. We show that it is possible to reproduce the temporal evolution of high temperature thermal flare plasma observed with the instruments on the GOES and Yohkoh satellites. The results from these simulations suggest that the heating timescale for a individual thread is on the order of 200 s. Significantly shorter heating timescales (20 s) lead to very high temperatures and are inconsistent with the emission observed by Yohkoh.

  7. Low Mach number fluctuating hydrodynamics for electrolytes

    Science.gov (United States)

    Péraud, Jean-Philippe; Nonaka, Andy; Chaudhri, Anuj; Bell, John B.; Donev, Aleksandar; Garcia, Alejandro L.

    2016-11-01

    We formulate and study computationally the low Mach number fluctuating hydrodynamic equations for electrolyte solutions. We are interested in studying transport in mixtures of charged species at the mesoscale, down to scales below the Debye length, where thermal fluctuations have a significant impact on the dynamics. Continuing our previous work on fluctuating hydrodynamics of multicomponent mixtures of incompressible isothermal miscible liquids [A. Donev et al., Phys. Fluids 27, 037103 (2015), 10.1063/1.4913571], we now include the effect of charged species using a quasielectrostatic approximation. Localized charges create an electric field, which in turn provides additional forcing in the mass and momentum equations. Our low Mach number formulation eliminates sound waves from the fully compressible formulation and leads to a more computationally efficient quasi-incompressible formulation. We demonstrate our ability to model saltwater (NaCl) solutions in both equilibrium and nonequilibrium settings. We show that our algorithm is second order in the deterministic setting and for length scales much greater than the Debye length gives results consistent with an electroneutral approximation. In the stochastic setting, our model captures the predicted dynamics of equilibrium and nonequilibrium fluctuations. We also identify and model an instability that appears when diffusive mixing occurs in the presence of an applied electric field.

  8. (Non)-Dissipative Hydrodynamics on Embedded Surfaces

    CERN Document Server

    Armas, Jay

    2014-01-01

    We construct the theory of dissipative hydrodynamics of uncharged fluids living on embedded space-time surfaces to first order in a derivative expansion in the case of codimension-1 surfaces (including fluid membranes) and the theory of non-dissipative hydrodynamics to second order in a derivative expansion in the case of codimension higher than one under the assumption of no angular momenta in transverse directions to the surface. This construction includes the elastic degrees of freedom, and hence the corresponding transport coefficients, that take into account transverse fluctuations of the geometry where the fluid lives. Requiring the second law of thermodynamics to be satisfied leads us to conclude that in the case of codimension-1 surfaces the stress-energy tensor is characterized by 2+1 independent transport coefficients to first order in the expansion while for codimension higher than one, and for non-dissipative flows, the stress-energy tensor is characterized by 7+3 independent transport coefficient...

  9. Testing Hydrodynamics Schemes in Galaxy Disc Simulations

    CERN Document Server

    Few, C G; Pettitt, A; Konstandin, L

    2016-01-01

    We examine how three fundamentally different numerical hydrodynamics codes follow the evolution of an isothermal galactic disc with an external spiral potential. We compare an adaptive mesh refinement code (RAMSES), a smoothed particle hydrodynamics code (sphNG), and a volume-discretised meshless code (GIZMO). Using standard refinement criteria, we find that RAMSES produces a disc that is less vertically concentrated and does not reach such high densities as the sphNG or GIZMO runs. The gas surface density in the spiral arms increases at a lower rate for the RAMSES simulations compared to the other codes. There is also a greater degree of substructure in the sphNG and GIZMO runs and secondary spiral arms are more pronounced. By resolving the Jeans' length with a greater number of grid cells we achieve more similar results to the Lagrangian codes used in this study. Other alterations to the refinement scheme (adding extra levels of refinement and refining based on local density gradients) are less successful i...

  10. High Performance Thin Layer Chromatography.

    Science.gov (United States)

    Costanzo, Samuel J.

    1984-01-01

    Clarifies where in the scheme of modern chromatography high performance thin layer chromatography (TLC) fits and why in some situations it is a viable alternative to gas and high performance liquid chromatography. New TLC plates, sample applications, plate development, and instrumental techniques are considered. (JN)

  11. High Performance Thin Layer Chromatography.

    Science.gov (United States)

    Costanzo, Samuel J.

    1984-01-01

    Clarifies where in the scheme of modern chromatography high performance thin layer chromatography (TLC) fits and why in some situations it is a viable alternative to gas and high performance liquid chromatography. New TLC plates, sample applications, plate development, and instrumental techniques are considered. (JN)

  12. Coupling hydrodynamics and radiation calculations for star-jet interactions in AGN

    CERN Document Server

    de la Cita, Víctor M; Paredes-Fortuny, Xavier; Khangulyan, Dmitry; Perucho, Manel

    2016-01-01

    Stars and their winds can contribute to the non-thermal (NT) emission in extragalactic jets. Given the complexity of jet-star interactions, the properties of the resulting emission are strongly linked to those of the emitting flows. We simulate the interaction between a stellar wind and a relativistic extragalactic jet and use the hydrodynamic results to compute the NT emission under different conditions. We perform relativistic axisymmetric hydrodynamical simulations of a relativistic jet interacting with a supersonic, non-relativistic stellar wind. We compute the corresponding streamlines out of the simulation results, and calculate the injection, evolution, and emission of NT particles accelerated in the jet shock, focusing on electrons or $e^\\pm$-pairs. Several cases are explored, considering different jet-star interaction locations, magnetic fields and observer lines of sight. The jet luminosity and star properties are fixed, but the results are easily scalable under changes of these parameters. Individu...

  13. Development of an Electron-Positron Source for Positron Annihilation Lifetime Spectroscopy

    Science.gov (United States)

    2009-12-19

    boosted frame where electric field reaches the Schwinger limit for production of electron-positron pairs from vacuum. The theoretical framework...were directed toward radiative shock hydrodynamics. Lowering the threshold for Schwinger electron-positron pair production (Stepan Bulanov

  14. Schinus terebinthifolius countercurrent chromatography (Part III): Method transfer from small countercurrent chromatography column to preparative centrifugal partition chromatography ones as a part of method development.

    Science.gov (United States)

    das Neves Costa, Fernanda; Hubert, Jane; Borie, Nicolas; Kotland, Alexis; Hewitson, Peter; Ignatova, Svetlana; Renault, Jean-Hugues

    2017-03-03

    Countercurrent chromatography (CCC) and centrifugal partition chromatography (CPC) are support free liquid-liquid chromatography techniques sharing the same basic principles and features. Method transfer has previously been demonstrated for both techniques but never from one to another. This study aimed to show such a feasibility using fractionation of Schinus terebinthifolius berries dichloromethane extract as a case study. Heptane - ethyl acetate - methanol -water (6:1:6:1, v/v/v/v) was used as solvent system with masticadienonic and 3β-masticadienolic acids as target compounds. The optimized separation methodology previously described in Part I and II, was scaled up from an analytical hydrodynamic CCC column (17.4mL) to preparative hydrostatic CPC instruments (250mL and 303mL) as a part of method development. Flow-rate and sample loading were further optimized on CPC. Mobile phase linear velocity is suggested as a transfer invariant parameter if the CPC column contains sufficient number of partition cells. Copyright © 2017 Elsevier B.V. All rights reserved.

  15. pyro: Python-based tutorial for computational methods for hydrodynamics

    Science.gov (United States)

    Zingale, Michael

    2015-07-01

    pyro is a simple python-based tutorial on computational methods for hydrodynamics. It includes 2-d solvers for advection, compressible, incompressible, and low Mach number hydrodynamics, diffusion, and multigrid. It is written with ease of understanding in mind. An extensive set of notes that is part of the Open Astrophysics Bookshelf project provides details of the algorithms.

  16. SPHYNX: SPH hydrocode for subsonic hydrodynamical instabilities and strong shocks

    Science.gov (United States)

    Cabezon, Ruben M.; Garcia-Senz, Domingo

    2017-09-01

    SPHYNX addresses subsonic hydrodynamical instabilities and strong shocks; it is Newtonian, grounded on the Euler-Lagrange formulation of the smoothed-particle hydrodynamics technique, and density based. SPHYNX uses an integral approach for estimating gradients, a flexible family of interpolators to suppress pairing instability, and incorporates volume elements to provides better partition of the unity.

  17. On the Coefficients of a Hyperbolic Hydrodynamic Model

    CERN Document Server

    Muroya, Shin

    2012-01-01

    Based on the Nakajima-Zubarev type nonequilibrium density operator, we derive a hyperbolic hydrodynamical equation. Microscopic Kubo-formulas for all coefficients in the hyperbolic hydrodynamics are obtained. Coefficients $\\alpha_{i}$'s and $\\beta_{i}$'s in the Israel-Stewart equation are given as current-weighted correlation lengths which are to be calculated in statistical mechanics.

  18. Hydrodynamics of a Multistage Wet Scrubber Incineration Conditions

    Science.gov (United States)

    Said, M. M.; Manyele, S. V.; Raphael, M. L.

    2012-01-01

    The objective of the study was to determine the hydrodynamics of the two stage counter-current cascade wet scrubbers used during incineration of medical waste. The dependence of the hydrodynamics on two main variables was studied: Inlet air flow rate and inlet liquid flow rate. This study introduces a new wet scrubber operating features, which are…

  19. Turbulent behaviour in magnetic hydrodynamics is not universal

    CERN Document Server

    Dmitriy, W

    1996-01-01

    A short distance expansion method (SDE) that is well known in the quantum field theory for analysis of turbulent behaviour of stochastic magnetic hydrodynamics of incompressible conductive fluid is applied. As a result is shown that in an inertial range the turbulent spectra of magnetic hydrodynamics depend on a scale of arising of curls.

  20. Combined Modeling of Acceleration, Transport, and Hydrodynamic Response in Solar Flares. II. Inclusion of Radiative Transfer with RADYN

    CERN Document Server

    da Costa, Fatima Rubio; Petrosian, Vahe'; Carlsson, Mats

    2015-01-01

    Solar flares involve complex processes that are coupled together and span a wide range of temporal, spatial, and energy scales. Modeling such processes self-consistently has been a challenge in the past. Here we present such a model to simulate the coupling of high-energy particle kinetics with hydrodynamics of the atmospheric plasma. We combine the Stanford unified Fokker-Planck code that models particle acceleration, transport, and bremsstrahlung radiation with the RADYN hydrodynamic code that models the atmospheric response to collisional heating by non-thermal electrons through detailed radiative transfer calculations. We perform simulations using different injection electron spectra, including an {\\it ad hoc} power law and more realistic spectra predicted by the stochastic acceleration model due to turbulence or plasma waves. Surprisingly, stochastically accelerated electrons, even with energy flux $\\ll 10^{10}$ erg s$^{-1}$ cm$^{-2}$, cause "explosive" chromospheric evaporation and drive stronger up- an...

  1. Hydrodynamic model for expansion and collisional relaxation of x-ray laser-excited multi-component nanoplasma

    Energy Technology Data Exchange (ETDEWEB)

    Saxena, Vikrant, E-mail: vikrant.saxena@desy.de [Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, 22607 Hamburg (Germany); Hamburg Center for Ultrafast Imaging, Luruper Chaussee 149, 22761 Hamburg (Germany); Ziaja, Beata, E-mail: ziaja@mail.desy.de [Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, 22607 Hamburg (Germany); Hamburg Center for Ultrafast Imaging, Luruper Chaussee 149, 22761 Hamburg (Germany); Institute of Nuclear Physics, Polish Academy of Sciences, Radzikowskiego 152, 31-342 Kraków (Poland)

    2016-01-15

    The irradiation of an atomic cluster with a femtosecond x-ray free-electron laser pulse results in a nanoplasma formation. This typically occurs within a few hundred femtoseconds. By this time the x-ray pulse is over, and the direct photoinduced processes no longer contributing. All created electrons within the nanoplasma are thermalized. The nanoplasma thus formed is a mixture of atoms, electrons, and ions of various charges. While expanding, it is undergoing electron impact ionization and three-body recombination. Below we present a hydrodynamic model to describe the dynamics of such multi-component nanoplasmas. The model equations are derived by taking the moments of the corresponding Boltzmann kinetic equations. We include the equations obtained, together with the source terms due to electron impact ionization and three-body recombination, in our hydrodynamic solver. Model predictions for a test case, expanding spherical Ar nanoplasma, are obtained. With this model, we complete the two-step approach to simulate x-ray created nanoplasmas, enabling computationally efficient simulations of their picosecond dynamics. Moreover, the hydrodynamic framework including collisional processes can be easily extended for other source terms and then applied to follow relaxation of any finite non-isothermal multi-component nanoplasma with its components relaxed into local thermodynamic equilibrium.

  2. Hydrodynamics of slip wedge and optimization of surface slip property

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The hydrodynamic load support generated by a slip wedge of a slider bearing was studied. The surface slip property was optimized so that a maximum hydrodynamic load support could be obtained. A multi-linearity method was given for the slip control equation of two-dimensional (2-D) wall slip. We investigated 2-D wall slip and the hydrodynamics of a finite length bearing with any values of the surface limiting shear stress. It was found that the hydrodynamic effect of the slip wedge is greater than the traditional geometrical convergent-wedge. Even though the geo- metrical gap is a parallel or divergent sliding gap, the slip wedge still gives rise to a very big hydrodynamic pressure. The optimized slip wedge can give rise to a hy- drodynamic load support as high as 2.5 times of what the geometrical conver- gent-wedge can produce. Wall slip usually gives a small surface friction.

  3. EXPERIMENTS ON HYDRODYNAMIC INTERACTION BETWEEN 3-D OVAL AND WALL

    Institute of Scientific and Technical Information of China (English)

    SUN Ke; SHENG Qi-hu; ZHANG Liang; LI Feng-lai

    2007-01-01

    The boundary hydrodynamic interaction of a 3-D oval body was experimentally surveyed for different cases. The regression method was employed to find the experimental formulae of hydrodynamic coefficients relating to the attack angle, clearance to wall, and moving speed. The mechanism of interaction was discussed. The experimental results show that there exists a lifting effect, similar to wings in flow. The lifting effect is remarkable. The boundary hydrodynamic interaction of the small aspect ratio model is almost linearly dependent on the attack angle, but the effect of the moving speed of the body on the hydrodynamic coefficients is very small. The effect of clearance is related to the geometric shape. The boundary hydrodynamic interaction always enhances the lifting effect if the clearance is small.

  4. Elasto-hydrodynamic network analysis of colloidal gels

    Science.gov (United States)

    Swan, James; Varga, Zsigmond

    Colloidal gels formed at low particle volume fractions result from a competition between two rate processes: aggregation of colloids and compaction of pre-gel aggregates. Recent work has shown that the former process is highly sensitive to the nature of the hydrodynamic interactions between suspended colloids. This same sensitivity to hydrodynamic flows within the gel leads to pronounced differences in the spectrum of relaxation times and response to deformation of the gel. This talk explores those differences and their consequences through computational simulations and the framework of elasto-hydrodynamic network analysis. We demonstrate a significant impact of hydrodynamic interactions between gelled colloids on macroscopic gel dynamics and rheology as well as the effect of hydrodynamic screening in gelled materials.

  5. Optimization of Submarine Hydrodynamic Coefficients Based on Immune Genetic Algorithm

    Institute of Scientific and Technical Information of China (English)

    HU Kun; XU Yi-fan

    2010-01-01

    Aiming at the demand for optimization of hydrodynamic coefficients in submarine's motion equations, an adaptive weight immune genetic algorithm was proposed to optimize hydrodynamic coefficients in motion equations. Some hydrody-namic coefficients of high sensitivity to control and maneuver were chosen as the optimization objects in the algorithm. By using adaptive weight method to determine the weight and target function, the multi-objective optimization could be transla-ted into single-objective optimization. For a certain kind of submarine, three typical maneuvers were chosen to be the objects of study: overshoot maneuver in horizontal plane, overshoot maneuver in vertical plane and turning circle maneuver in horizontal plane. From the results of computer simulations using primal hydrodynamic coefficient and optimized hydrody-namic coefficient, the efficiency of proposed method is proved.

  6. Separation techniques: Chromatography

    OpenAIRE

    Coskun, Ozlem

    2016-01-01

    Chromatography is an important biophysical technique that enables the separation, identification, and purification of the components of a mixture for qualitative and quantitative analysis. Proteins can be purified based on characteristics such as size and shape, total charge, hydrophobic groups present on the surface, and binding capacity with the stationary phase. Four separation techniques based on molecular characteristics and interaction type use mechanisms of ion exchange, surface adsorp...

  7. Radiation-Hydrodynamics of Hot Jupiter Atmospheres

    CERN Document Server

    Menou, Kristen

    2009-01-01

    Radiative transfer in planetary atmospheres is usually treated in the static limit, i.e., neglecting atmospheric motions. We argue that hot Jupiter atmospheres, with possibly fast (sonic) wind speeds, may require a more strongly coupled treatment, formally in the regime of radiation-hydrodynamics. To lowest order in v/c, relativistic Doppler shifts distort line profiles along optical paths with finite wind velocity gradients. This leads to flow-dependent deviations in the effective emission and absorption properties of the atmospheric medium. Evaluating the overall impact of these distortions on the radiative structure of a dynamic atmosphere is non-trivial. We present transmissivity and systematic equivalent width excess calculations which suggest possibly important consequences for radiation transport in hot Jupiter atmospheres. If winds are fast and bulk Doppler shifts are indeed important for the global radiative balance, accurate modeling and reliable data interpretation for hot Jupiter atmospheres may p...

  8. Preliminary study of disc hydrodynamic polishing.

    Science.gov (United States)

    Li, Yan; Lin, Bin; Zhang, XiaoFeng; Liu, PengFei

    2016-10-01

    In this paper, a developed polishing method based on elastic emission machining and Jules Verne-a variation on fluid jet polishing-is presented. This method is named disc hydrodynamic polishing (DHDP). A computational fluid dynamics (CFD)-based model that consists of a CFD model and an erosion model is introduced to predict the surface roughness obtained by DHDP. The performance of DHDP is studied by experiments. The slurry used in the experiments comprises 95% deionized water and 5% cerium oxide particles. Fused-silica glass is chosen as the workpiece. After the experiments, an ultrasmooth surface without cracks is obtained. The simulation results principally coincide with the experimental results. The experimental results show that the actual roughness is slightly less than the prediction and smaller particles are more favorable for obtaining a better surface roughness.

  9. Hydrodynamics of R-charged black holes

    CERN Document Server

    Son, D T; Son, Dam T.; Starinets, Andrei O.

    2006-01-01

    We consider hydrodynamics of N=4 supersymmetric SU(N_c) Yang-Mills plasma at a nonzero density of R-charge. In the regime of large N_c and large 't Hooft coupling the gravity dual description involves an asymptotically Anti- de Sitter five-dimensional charged black hole solution of Behrnd, Cvetic and Sabra. We compute the shear viscosity as a function of chemical potentials conjugated to the three U(1) \\subset SO(6)_R charges. The ratio of the shear viscosity to entropy density is independent of the chemical potentials and is equal to 1/4\\pi. For a single charge black hole we also compute the thermal conductivity, and investigate the critical behavior of the transport coefficients near the boundary of thermodynamic stability.

  10. On some hydrodynamical aspects of quantum mechanics

    CERN Document Server

    Spera, Mauro

    2009-01-01

    In this note we first set up an analogy between spin and vorticity of a perfect 2d-fluid flow, based on the Borel-Weil contruction of the irreducible unitary representations of SU(2), and looking at the Madelung-Bohm velocity attached to the ensuing spin wave functions. We also show that, in the framework of finite dimensional geometric quantum mechanics, the Schr\\"odinger velocity field on projective Hilbert space is divergence-free (being Killing with respect to the Fubini-Study metric) and fulfils the stationary Euler equation, with pressure proportional to the Hamiltonian uncertainty (squared). We explicitly compute the pressure gradient of this "Schr\\"odinger fluid" and determine its critical points. Its vorticity is also calculated and shown to depend on the spacings of the energy levels. These results follow from hydrodynamical properties of Killing vector fields valid in any (finite dimensional) Riemannian manifold, of possible independent interest.

  11. On some hydrodynamical aspects of quantum mechanics

    Science.gov (United States)

    Spera, Mauro

    2010-02-01

    In this note we first set up an analogy between spin and vorticity of a perfect 2d-fluid flow, based on the complex polynomial (i.e. Borel-Weil) realization of the irreducible unitary representations of SU(2), and looking at the Madelung-Bohm velocity attached to the ensuing spin wave functions. We also show that, in the framework of finite dimensional geometric quantum mechanics, the Schrödinger velocity field on projective Hilbert space is divergence-free (being Killing with respect to the Fubini-Study metric) and fulfils the stationary Euler equation, with pressure proportional to the Hamiltonian uncertainty (squared). We explicitly determine the critical points of the pressure of this "Schrödinger fluid", together with its vorticity, which turns out to depend on the spacings of the energy levels. These results follow from hydrodynamical properties of Killing vector fields valid in any (finite dimensional) Riemannian manifold, of possible independent interest.

  12. Study of hydrodynamic characteristics in tubular photobioreactors.

    Science.gov (United States)

    Zhang, Qinghua; Wu, Xia; Xue, Shengzhang; Liang, Kehong; Cong, Wei

    2013-02-01

    In this work, the hydrodynamic characteristics in tubular photobioreactors with a series of helical static mixers built-in were numerically investigated using computational fluid dynamics (CFD). The influences of height and screw pitch of the helical static mixer and fluid inlet velocity on the cell trajectories, swirl numbers and energy consumption were examined. In order to verify the actual results for cultivation of microalgae, cultivation experiments of freshwater Chlorella sp. were carried out in photobioreactor with and without helical static mixer built-in at the same time. It was shown that with built-in helical static mixer, the mixing of fluid could be intensified, and the light/dark cycle could also be achieved which is of benefit for the growth of microalgae. The biomass productivity of Chlorella sp. in tubular photobioreactor with helical static mixer built-in was 37.26 % higher than that in the photobioreactor without helical static mixer.

  13. Separation of blood cells using hydrodynamic lift

    Science.gov (United States)

    Geislinger, T. M.; Eggart, B.; Braunmüller, S.; Schmid, L.; Franke, T.

    2012-04-01

    Using size and deformability as intrinsic biomarkers, we separate red blood cells (RBCs) from other blood components based on a repulsive hydrodynamic cell-wall-interaction. We exploit this purely viscous lift effect at low Reynolds numbers to induce a lateral migration of soft objects perpendicular to the streamlines of the fluid, which closely follows theoretical prediction by Olla [J. Phys. II 7, 1533, (1997)]. We study the effects of flow rate and fluid viscosity on the separation efficiency and demonstrate the separation of RBCs, blood platelets, and solid microspheres from each other. The method can be used for continuous and label-free cell classification and sorting in on-chip blood analysis.

  14. Quantum hydrodynamics in the rotating reference frame

    CERN Document Server

    Trukhanova, Mariya Iv

    2016-01-01

    In this paper we apply quantum hydrodynamics (QHD) to study the quantum evolution of a system of spinning particles and particles that have the electric dipole moments EDM in the rotating reference frame. The method presented is based on the many-particle microscopic Schrodinger equation in the rotating reference frame. Fundamental QHD equations for charged or neutral spinning and EDM-bearing particles were shaped due to this method and contain the spin-dependent inertial force field. The polarization dynamics in systems of neutral particles in the rotating frame is shown to cause formation of a new type of waves, the dipole-inertial waves. We have analyzed elementary excitations in a system of neutral polarized fluids placed into an external electric field in 2D and 3D cases. We predict the novel type of 2D dipole-inertial wave and 3D - polarization wave modified by rotation in systems of particles with dipole-dipole interactions.

  15. An analysis of smoothed particle hydrodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Swegle, J.W.; Attaway, S.W.; Heinstein, M.W.; Mello, F.J. [Sandia National Labs., Albuquerque, NM (United States); Hicks, D.L. [Michigan Technological Univ., Houghton, MI (United States)

    1994-03-01

    SPH (Smoothed Particle Hydrodynamics) is a gridless Lagrangian technique which is appealing as a possible alternative to numerical techniques currently used to analyze high deformation impulsive loading events. In the present study, the SPH algorithm has been subjected to detailed testing and analysis to determine its applicability in the field of solid dynamics. An important result of the work is a rigorous von Neumann stability analysis which provides a simple criterion for the stability or instability of the method in terms of the stress state and the second derivative of the kernel function. Instability, which typically occurs only for solids in tension, results not from the numerical time integration algorithm, but because the SPH algorithm creates an effective stress with a negative modulus. The analysis provides insight into possible methods for removing the instability. Also, SPH has been coupled into the transient dynamics finite element code PRONTO, and a weighted residual derivation of the SPH equations has been obtained.

  16. Effects of hydrodynamic interactions in bacterial swimming.

    Science.gov (United States)

    Chattopadhyay, Suddhashil; Lun Wu, Xiao

    2008-03-01

    The lack of precise experimental data has prevented the investigation of the effects of long range hydrodynamic interactions in bacterial swimming. We perform measurements on various strains of bacteria with the aid of optical tweezers to shed light on this aspect of bacterial motility. Geometrical parameters recorded by fluorescence microscopy are used with theories which model flagella propulsion (Resistive force theory & Lighthill's formulation which includes long range interactions). Comparison of the predictions of these theories with experimental data, observed directly from swimming bacterium, led to the conclusion that while long range inetractions were important for single polar flagellated strains (Vibrio Alginolyticus & Caulobacter Crescentus), local force theory was adequate to describe the swimming of multi-flagellated Esherichia Coli. We performed additional measurements on E. Coli minicells (miniature cells with single polar flagellum) to try and determine the cause of this apparent effect of shielding of long range interactions in multiple flagellated bacteria.

  17. Phonon hydrodynamics in two-dimensional materials.

    Science.gov (United States)

    Cepellotti, Andrea; Fugallo, Giorgia; Paulatto, Lorenzo; Lazzeri, Michele; Mauri, Francesco; Marzari, Nicola

    2015-03-06

    The conduction of heat in two dimensions displays a wealth of fascinating phenomena of key relevance to the scientific understanding and technological applications of graphene and related materials. Here, we use density-functional perturbation theory and an exact, variational solution of the Boltzmann transport equation to study fully from first-principles phonon transport and heat conductivity in graphene, boron nitride, molybdenum disulphide and the functionalized derivatives graphane and fluorographene. In all these materials, and at variance with typical three-dimensional solids, normal processes keep dominating over Umklapp scattering well-above cryogenic conditions, extending to room temperature and more. As a result, novel regimes emerge, with Poiseuille and Ziman hydrodynamics, hitherto typically confined to ultra-low temperatures, characterizing transport at ordinary conditions. Most remarkably, several of these two-dimensional materials admit wave-like heat diffusion, with second sound present at room temperature and above in graphene, boron nitride and graphane.

  18. Fluidization of Wet Granulates under Hydrodynamic Shear

    CERN Document Server

    Battiato, I

    2012-01-01

    We investigate the fluidization threshold of three-dimensional cohesive granulates under hydrodynamic shear forces exerted by a creeping ow. A continuum model of flow through porous media provides an analytical expression for the average drag force on a single grain. The balance equation for the forces and a force propagation model are then used to investigate the effects of porosity and packing structure on the stability of the pile. We obtain a closed-form expression for the fluidization threshold of a regular packing of mono-disperse frictionless cohesive spherical grains in a planar fracture. The compound effect of structural (packing orientation and porosity) and dynamical properties of the system on its stability is quantified.

  19. Classes of hydrodynamic and magnetohydrodynamic turbulent decay

    CERN Document Server

    Brandenburg, Axel

    2016-01-01

    We perform numerical simulations of decaying hydrodynamic and magnetohydrodynamic turbulence. We classify our time-dependent solutions by their evolutionary tracks in parametric plots between instantaneous scaling exponents. We find distinct classes of solutions evolving along specific trajectories toward points on a line of self-similar solutions. These trajectories are determined by the underlying physics governing individual cases, and not by the initial conditions, as is widely assumed. In the helical case, even for a scale-invariant initial spectrum (inversely proportional to wavenumber k), the solution evolves along the same trajectory as for a Batchelor spectrum (proportional to k^4). All of our self-similar solutions have an intrinsic subinertial range close to k^4$.

  20. Resolving mixing in Smoothed Particle Hydrodynamics

    CERN Document Server

    Read, J I; Agertz, O

    2009-01-01

    Standard formulations of smoothed particle hydrodynamics (SPH) are unable to resolve mixing at fluid boundaries. We use an error and stability analysis of the generalised SPH equations of motion to prove that this is due to two distinct problems. The first is a leading order error in the momentum equation. This should decrease with increasing neighbour number, but does not because numerical instabilities cause the kernel to be irregularly sampled. We identify two important instabilities: the clumping instability and the banding instability, and we show that both are cured by a suitable choice of kernel. The second problem is the local mixing instability (LMI). This occurs as particles attempt to mix on the kernel scale, but are unable to due to entropy conservation. The result is a pressure discontinuity at boundaries that pushes fluids of different entropy apart. We cure the LMI by using a temperature weighted density estimate that both reduces errors in the continuity equation and allows individual particle...

  1. Using river locks to teach hydrodynamic concepts

    Science.gov (United States)

    Carvalho-Santos, Vagson L.; Mendes, Thales C.; Silva, Enisvaldo C.; Rios, Márcio L.; Silva, Anderson A. P.

    2013-11-01

    In this work, the use of a river lock as a non-formal setting for teaching hydrodynamical concepts is proposed. In particular, we describe the operation of a river lock situated at the Sobradinho dam, on the São Francisco River (Brazil). A model to represent and to analyse the dynamics of river lock operation is presented and we derive the dynamical equations for the rising of the water column as an example to understand the Euler equation. Furthermore, with this activity, we enable the integration of content initially introduced in the classroom with practical applications, thereby allowing the association of physical themes to content relevant in disciplines such as history and geography. In addition, experiences of this kind enable teachers to talk about the environmental and social impacts caused by the construction of a dam and, consequently, a crossover of concepts has been made possible, leading to more meaningful learning for the students.

  2. Hydrodynamic models for slurry bubble column reactors

    Energy Technology Data Exchange (ETDEWEB)

    Gidaspow, D. [IIT Center, Chicago, IL (United States)

    1995-12-31

    The objective of this investigation is to convert a {open_quotes}learning gas-solid-liquid{close_quotes} fluidization model into a predictive design model. This model is capable of predicting local gas, liquid and solids hold-ups and the basic flow regimes: the uniform bubbling, the industrially practical churn-turbulent (bubble coalescence) and the slugging regimes. Current reactor models incorrectly assume that the gas and the particle hold-ups (volume fractions) are uniform in the reactor. They must be given in terms of empirical correlations determined under conditions that radically differ from reactor operation. In the proposed hydrodynamic approach these hold-ups are computed from separate phase momentum balances. Furthermore, the kinetic theory approach computes the high slurry viscosities from collisions of the catalyst particles. Thus particle rheology is not an input into the model.

  3. Tears of Venom: Hydrodynamics of Reptilian Envenomation

    Science.gov (United States)

    Young, Bruce A.; Herzog, Florian; Friedel, Paul; Rammensee, Sebastian; Bausch, Andreas; van Hemmen, J. Leo

    2011-05-01

    In the majority of venomous snakes, and in many other reptiles, venom is conveyed from the animal’s gland to the prey’s tissue through an open groove on the surface of the teeth and not through a tubular fang. Here we focus on two key aspects of the grooved delivery system: the hydrodynamics of venom as it interacts with the groove geometry, and the efficiency of the tooth-groove-venom complex as the tooth penetrates the prey’s tissue. We show that the surface tension of the venom is the driving force underlying the envenomation dynamics. In so doing, we explain not only the efficacy of the open groove, but also the prevalence of this mechanism among reptiles.

  4. Using river locks to teach hydrodynamic concepts

    CERN Document Server

    Carvalho-Santos, Vagson L; Silva, Enisvaldo C; Rios, Márcio L; Silva, Anderson A P

    2013-01-01

    In this work, the use of a river lock as a non-formal setting for teaching Q2 hydrodynamical concepts is proposed. In particular, we describe the operation of a river lock situated at the Sobradinho dam, on the S\\~ao Francisco River (Brazil). A model to represent and to analyse the dynamics of river lock operation is presented and we derive the dynamical equations for the rising of the water column as an example to understand the Euler equation. Furthermore, with this activity, we enable the integration of content initially introduced in the classroom with practical applications, thereby allowing the association of physical themes to content relevant in disciplines such as history and geography. In addition, experiences of this kind enable teachers to talk about the environmental and social impacts caused by the construction of a dam and, consequently, a crossover of concepts has been made possible, leading to more meaningful learning for the students.

  5. Flow stabilization with active hydrodynamic cloaks

    CERN Document Server

    Urzhumov, Yaroslav A; 10.1103/PhysRevE.86.056313

    2012-01-01

    We demonstrate that fluid flow cloaking solutions based on active hydrodynamic metamaterials exist for two-dimensional flows past a cylinder in a wide range of Reynolds numbers, up to approximately 200. Within the framework of the classical Brinkman equation for homogenized porous flow, we demonstrate using two different methods that such cloaked flows can be dynamically stable for $Re$ in the range 5-119. The first, highly efficient, method is based on a linearization of the Brinkman-Navier-Stokes equation and finding the eigenfrequencies of the least stable eigen-perturbations; the second method is a direct, numerical integration in the time domain. We show that, by suppressing the Karman vortex street in the weekly turbulent wake, porous flow cloaks can raise the critical Reynolds number up to about 120, or five times greater than for a bare, uncloaked cylinder.

  6. Hydrodynamics of Microbial Filter-Feeding

    Science.gov (United States)

    Andersen, Anders; Nielsen, Lasse Tor; Dolger, Julia; Kiorboe, Thomas

    2016-11-01

    Microbial filter-feeders form an important group of plankton with significance to the aquatic food webs. While the concept of filter-feeding is straightforward, our quantitative understanding of microbial filter-feeding leaves a lot to be desired. As a model organism, we focus on the filter-feeding choanoflagellate Diaphanoeca grandis. We quantify the feeding flow using particle tracking, and demonstrate that hydrodynamic theory underestimates the observed clearance rate by an order of magnitude. We find similar discrepancies for other choanoflagellate species, highlighting an apparent paradox. To resolve the paradox we argue that D. grandis and other choanoflagellates must have so far unbeknownst morphological features. Specifically, we suggest a flagellar vane that connects the flagellum to the filter, as known in choanocytes of sponges, creating a radically different, and order of magnitude more capable, pumping mechanism. The Centre for Ocean Life is a VKR Centre of Excellence supported by the Villum Foundation.

  7. The aerodynamics and hydrodynamics of plants.

    Science.gov (United States)

    Ennos, A R

    1999-12-01

    Because they grow away from their substratum to compete for light, plants have to withstand hydrodynamic or aerodynamic drag. Both water and land plants reconfigure in response to this drag, and this is presumed to reduce the risk of mechanical failure. However, there is little unequivocal evidence of drag reduction in large trees as a result of reconfiguration. Land plants must also transport water internally to their tissues, and many have developed xylem tracheids and vessels that help speed up this process. Recent evidence that tree height is limited by water supply suggests that water transport efficiency must be a crucial element in tree design. However, the resistance of many parts of the xylem is still unknown. More focused work is urgently required to shed light on the evolution and ecology of plants in relation to the flow of fluids.

  8. Hydrodynamics of primordial black hole formation

    Science.gov (United States)

    Nadezhin, D. K.; Novikov, I. D.; Polnarev, A. G.

    1979-01-01

    The hydrodynamic picture of the formation of primordial black holes (PBH) at the early stages of expansion of the Universe is considered. It is assumed that close to singularity, expansion occurs in a quasi-isotropic way. Using an EVM, a spherically symmetrical nonlinear problem of the evolution of primary strong deviation from the Fridman solution was solved. What these deviations must be, so that the formation of PBH occurred was clarified. Attention was devoted to the role of pressure gradients. It is pointed out that at the moment of formation of PBH, only a small part of matter enters into it, primarily the component of perturbation. It is also pointed out that at this moment, the mass of PBH essentially is smaller than the mass considered within the cosmic horizon. The possibility of changing the mass of the PBH as a result of accretion is analyzed.

  9. Heat Transfer and hydrodynamics in Annular Chromatography:CFD—Simulation and Experiments

    Institute of Scientific and Technical Information of China (English)

    Hans-JoergBart; JorgBrozio; 等

    2000-01-01

    Continuous annular chromatography(CAC) is a separation process for multicomponent liquid mixtures.The performance of the apparatus can be seriously decreased by temperature gradients inside the adsorbent bed.It is shown.that the temperature gradients can be significantly reduced by a pre-heating of the entering liquid in the apparatus itself.Heat transfer and hydrodynamics in the porous media are described by two different modlelling approaches.Both are based on a pseudo-homogeneous model for heat transfer with temperature dependent fluid viscosities,The first model considers one-dimensional fiud flow and two-dimensional heat transfer,The second,ore rigorous one is a three-dimensional model for heat transfer and hydrodynamics.The simulation results obtained with both models are in good agreement with experimental results.The experiments have been performed with glass beads as the stationary phase and water as the liquid phase under different boundary conditions.The temparature profiles inside the packed bed have been measured with thermocouples.

  10. Calculating rotating hydrodynamic and magneto-hydrodynamic waves to understand magnetic effects on dynamical tides

    CERN Document Server

    Wei, Xing

    2016-01-01

    For understanding magnetic effects on dynamical tides, we study the rotating magneto-hydrodynamic (MHD) flow driven by harmonic forcing. The linear responses are analytically derived in a periodic box under the local WKB approximation. Both the kinetic and Ohmic dissipations at the resonant frequencies are calculated and the various parameters are investigated. Although magnetic pressure may be negligible compared to thermal pressure, magnetic field can be important for the first-order perturbation, e.g. dynamical tides. It is found that magnetic field splits the resonant frequency, namely the rotating hydrodynamic flow has only one resonant frequency but the rotating MHD flow has two, one positive and the other negative. In the weak field regime the dissipations are asymmetric around the two resonant frequencies and this asymmetry is more striking with a weaker magnetic field. It is also found that both the kinetic and Ohmic dissipations at the resonant frequencies are inversely proportional to the Ekman num...

  11. Steady State Thermo-Hydrodynamic Analysis of Two-Axial groove and Multilobe Hydrodynamic Bearings

    Directory of Open Access Journals (Sweden)

    C. Bhagat

    2014-12-01

    Full Text Available Steady state thermo-hydrodynamic analysis of two axial groove and multi lobe oil journal bearings is performed in this paper. To study the steady state thermo-hydrodynamic characteristics Reynolds equation is solved simultaneously along with the energy equation and heat conduction equation in bush and shaft. The effect of groove geometry, cavitation in the fluid film, the recirculation of lubricant, shaft speed has also been taken into account. Film temperature in case of three-lobe bearing is found to be high as compared to other studied bearing configurations. The data obtained from this analysis can be used conveniently in the design of such bearings, which are presented in dimensionless form.

  12. Hydrodynamic modeling and explosive compaction of ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Hoenig, C.; Holt, A.; Finger, M.; Kuhl, W.

    1977-09-01

    High-density ceramics with high-strength microstructure were achieved by explosive compaction. Well-characterized Al/sub 2/O/sub 3/, AlN, and boron powders were explosively compacted in both cylindrical and flat plate geometries. In cylindrical geometries compacted densities between 91 and 98 percent of theoretical were achieved. Microhardness measurements indicated that the strength and integrity of the microstructure were comparable to conventionally fabricated ceramics, even though all samples with densities greater than 90 percent theoretical contained macrocracks. Fractured surfaces evaluated by SEM showed evidence of boundary melting. Equation of state data for porous Al/sub 2/O/sub 3/ were used to calculate the irreversible work done on the sample as a function of pressure. This was expressed as a percentage of the total sample which could be melted. Calculations show that very little melting can be expected in samples shocked to less than 3 GPa. Significant melting and grain boundary fusion can be expected in samples shocked to pressures greater than 8 GPa. Hydrodynamic modeling of right cylinder compaction with detonation at one end was attempted by using a two-dimensional computer code. The complications of this analysis led to experiments using plane shock waves. Flat-plate compaction assemblies were designed and analyzed by 2-D hydrodynamic codes. The use of porous shock attenuators was evaluated. Experiments were performed on aluminum oxide powders in plane wave geometry. Microstructure evaluations were made as a function of location in the flat plate samples. 11 figures, 1 table.

  13. On the Hydrodynamical Structure of Superwinds

    Science.gov (United States)

    Rodríguez-González, A.; Tenorio-Tagle, G.; Silich, S.

    2006-06-01

    We present the hydrodynamical stucture of superwinds (SWs) driven by super star clusters (SSCs). We show the impact of the radiative cooling in the SW properties (Silich et al. 2003, ApJ, 590, 796; Silich et al. 2004, ApJ, 610, 226; Tenorio-Tagle et al. 2005, ApJ, 620, 217). The SSCs recently found by HST in a large variety of starburst galaxies present a typical radius and masses that range from to several times. These are now believed to be the unit of violent star formation in starburst galaxies. The mass and energy injected by stellar winds and SN explosions (in the SSC volume) is totally thermalized via random interactions. This generates the large central over pressure that continuously accelerates the ejected gas and eventually blows it out of the SSC volume. This outflow is called SW. An adiabatic steady wind solution was proposed by Chevalier & Clegg (1985, Nature, 317, 44). However, this solution is not applicable in the case of massive and concentrated cluster. The radiative cooling changes the temperature distribution, it makes that the temperature drops faster to in a very tiny radius than in the adiabatic case. For more energetic clusters, strong radiative cooling promotes the sudden leakage of thermal energy right within the star cluster volume itself, and for the cases in which the radiative losses exceed of stellar energy deposition rate, the cooling becomes catastrophic. For that case the stationary superwind solution is totally inhibited. We solved the hydrodynamics properties of the ejected gas driven by massive stars (via stellar winds and SN) in function of star formation lifetime, and found 3 important stages. And we show the observational signature for each super star cluster stages.

  14. Full sphere hydrodynamic and dynamo benchmarks

    KAUST Repository

    Marti, P.

    2014-01-26

    Convection in planetary cores can generate fluid flow and magnetic fields, and a number of sophisticated codes exist to simulate the dynamic behaviour of such systems. We report on the first community activity to compare numerical results of computer codes designed to calculate fluid flow within a whole sphere. The flows are incompressible and rapidly rotating and the forcing of the flow is either due to thermal convection or due to moving boundaries. All problems defined have solutions that alloweasy comparison, since they are either steady, slowly drifting or perfectly periodic. The first two benchmarks are defined based on uniform internal heating within the sphere under the Boussinesq approximation with boundary conditions that are uniform in temperature and stress-free for the flow. Benchmark 1 is purely hydrodynamic, and has a drifting solution. Benchmark 2 is a magnetohydrodynamic benchmark that can generate oscillatory, purely periodic, flows and magnetic fields. In contrast, Benchmark 3 is a hydrodynamic rotating bubble benchmark using no slip boundary conditions that has a stationary solution. Results from a variety of types of code are reported, including codes that are fully spectral (based on spherical harmonic expansions in angular coordinates and polynomial expansions in radius), mixed spectral and finite difference, finite volume, finite element and also a mixed Fourier-finite element code. There is good agreement between codes. It is found that in Benchmarks 1 and 2, the approximation of a whole sphere problem by a domain that is a spherical shell (a sphere possessing an inner core) does not represent an adequate approximation to the system, since the results differ from whole sphere results. © The Authors 2014. Published by Oxford University Press on behalf of The Royal Astronomical Society.

  15. AXISYMMETRIC SIMULATIONS OF HOT JUPITER–STELLAR WIND HYDRODYNAMIC INTERACTION

    Energy Technology Data Exchange (ETDEWEB)

    Christie, Duncan; Arras, Phil; Li, Zhi-Yun [Department of Astronomy, University of Virginia, Charlottesville, VA 22904 (United States)

    2016-03-20

    Gas giant exoplanets orbiting at close distances to the parent star are subjected to large radiation and stellar wind fluxes. In this paper, hydrodynamic simulations of the planetary upper atmosphere and its interaction with the stellar wind are carried out to understand the possible flow regimes and how they affect the Lyα transmission spectrum. Following Tremblin and Chiang, charge exchange reactions are included to explore the role of energetic atoms as compared to thermal particles. In order to understand the role of the tail as compared to the leading edge of the planetary gas, the simulations were carried out under axisymmetry, and photoionization and stellar wind electron impact ionization reactions were included to limit the extent of the neutrals away from the planet. By varying the planetary gas temperature, two regimes are found. At high temperature, a supersonic planetary wind is found, which is turned around by the stellar wind and forms a tail behind the planet. At lower temperatures, the planetary wind is shut off when the stellar wind penetrates inside where the sonic point would have been. In this regime mass is lost by viscous interaction at the boundary between planetary and stellar wind gases. Absorption by cold hydrogen atoms is large near the planetary surface, and decreases away from the planet as expected. The hot hydrogen absorption is in an annulus and typically dominated by the tail, at large impact parameter, rather than by the thin leading edge of the mixing layer near the substellar point.

  16. Hydrodynamic theory of diffusion in two-temperature multicomponent plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Ramshaw, J.D.; Chang, C.H. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

    1995-12-31

    Detailed numerical simulations of multicomponent plasmas require tractable expressions for species diffusion fluxes, which must be consistent with the given plasma current density J{sub q} to preserve local charge neutrality. The common situation in which J{sub q} = 0 is referred to as ambipolar diffusion. The use of formal kinetic theory in this context leads to results of formidable complexity. We derive simple tractable approximations for the diffusion fluxes in two-temperature multicomponent plasmas by means of a generalization of the hydrodynamical approach used by Maxwell, Stefan, Furry, and Williams. The resulting diffusion fluxes obey generalized Stefan-Maxwell equations that contain driving forces corresponding to ordinary, forced, pressure, and thermal diffusion. The ordinary diffusion fluxes are driven by gradients in pressure fractions rather than mole fractions. Simplifications due to the small electron mass are systematically exploited and lead to a general expression for the ambipolar electric field in the limit of infinite electrical conductivity. We present a self-consistent effective binary diffusion approximation for the diffusion fluxes. This approximation is well suited to numerical implementation and is currently in use in our LAVA computer code for simulating multicomponent thermal plasmas. Applications to date include a successful simulation of demixing effects in an argon-helium plasma jet, for which selected computational results are presented. Generalizations of the diffusion theory to finite electrical conductivity and nonzero magnetic field are currently in progress.

  17. STEADY-STATE SOLUTIONS FOR A ONE-DIMENSIONAL NONISENTROPIC HYDRODYNAMIC MODEL WITH NON-CONSTANT LATTICE TEMPERATURE

    Institute of Scientific and Technical Information of China (English)

    Li Yeping

    2008-01-01

    A one-dimensional stationary nonisentropic hydrodynamic model for semicon-ductor devices with non-constant lattice temperature is studied. This model consists of the equations for the electron density, the electron current density and electron tempera-ture, coupled with the Poisson equation of the electrostatic potential in a bounded interval supplemented with proper boundary conditions. The existence and uniqueness of a strong subsonic steady-state solution with positive particle density and positive temperature is established. The proof is based on the fixed-point arguments, the Stampacchia truncation methods, and the basic energy estimates.

  18. Principles of Liquid Chromatography

    Science.gov (United States)

    Bakalyar, Stephen R.

    This article reviews the basic principles of high performance liquid chromatography (HPLC). The introductory section provides an overview of the HPLC technique, placing it in historical context and discussing the elementary facts of the separation mechanism. The next section discusses the nature of resolution, describing the two principal aspects, zone center separation and zone spreading. The third section takes a detailed look at how HPLC is used in practice to achieve a separation. It discusses the three key variables that need to be adjusted: retention, efficiency, and selectivity. A fourth section is concerned with various relationships of practical importance: flow rate, temperature, and pressure. A final section discusses future trends in HPLC.

  19. Hydrodynamic properties of magnetic nanoparticles with tunable shape anisotropy: prediction and experimental verification.

    Science.gov (United States)

    Martchenko, Ilya; Dietsch, Hervé; Moitzi, Christian; Schurtenberger, Peter

    2011-12-15

    We describe the characterization of the hydrodynamic properties of anisotropic magnetic nanoparticles using a combination of transmission electron microscopy (TEM) and dynamic as well as depolarized dynamic light scattering (DLS/DDLS). The particles used are nearly monodisperse hematite spindles with an average length of 280 nm and a minor axis of 57 nm, coated with a layer of silica of variable thickness that allows us to tune the particle aspect ratio between 5 and 2. Their geometrical dimensions can thus be determined easily and quantitatively from TEM. Moreover, their size is ideal to employ DLS and DDLS to measure the translational and rotational diffusion coefficients D(T) and D(R), while the presence of a magnetic core opens a plethora of opportunities for future studies and applications. We demonstrate that we can successfully predict the hydrodynamic properties of the different particles based on a TEM characterization of their size distribution and using established theoretical models for the hydrodynamic properties of anisotropic particles. When compared with the theoretical predictions, our light scattering measurements are in quantitative agreement. This agreement between theory and experiment is achieved without having to invoke any adjustable free parameter, as the TEM results are used to calculate the corresponding diffusion coefficients on an absolute scale. We demonstrate that this is achieved due to a new and simple method for the statistical weighting of the TEM information, and the use of the correct hydrodynamic models for the observed particle shape. In addition, we also demonstrate an enhanced sensitivity of the rotational diffusion for the surface properties of ellipsoidal nanoparticles, and point out that this may serve as an ideal tool toward characterizing functionalized surfaces.

  20. Simulation and Modeling of Submicron Semiconductor Devices by a New Hydrodynamic Method.

    Science.gov (United States)

    Lin, Qi.

    Robust numerical methods for the solution of the hydrodynamic model are developed and implemented for the simulation of submicron semiconductor devices. The hydrodynamic equations are reformulated into readily solvable self-adjoint forms with the aid of newly defined HD-Slotboom state variables. A new discretization strategy is developed to resolve the rapid variation in the carrier densities and carrier temperatures. The approach also yields a coefficient matrix for each discretized hydrodynamic equation, which is guaranteed to be diagonally dominant. The hydrodynamic equations are decoupled by using a Gummel block iteration method. A fixed-point iteration technique is employed to solve the discretized equations, which guarantees that each decoupled equation converges for any starting value. Furthermore, the decoupling of equations and use of the fixed-point iteration scheme obviate the need for direct solutions of large matrix equations, and thereby eliminate the need for large memory allocations. The algorithm is inherently parallel, so it can be readily implemented on parallel machines to increase computation speed. Using these methods, several simulation packages are developed for the analysis of one-dimensional (1-D) n^+-n-n^+ devices, and square electric fields, two-dimensional (2-D) & three-dimensional (3-D) MOSFET's, and two-dimensional SOI MOSFET's. Various simulation results for these devices are presented. Some one-dimensional simulation results are compared with Monte Carlo calculations, and a good agreement is observed. Also convergence, stability, and efficiency of the methods are examined by a set of numerical experiments. The device simulators are applied to investigate the hot-electron induced degradation in submicron SOI devices and EPROM's. The impact of localized interface charge on device characteristics is studied. Some measured results are used to calibrate the process parameters in the simulators so that the simulators can predict device

  1. A comparison of cosmological hydrodynamic codes

    Science.gov (United States)

    Kang, Hyesung; Ostriker, Jeremiah P.; Cen, Renyue; Ryu, Dongsu; Hernquist, Lars; Evrard, August E.; Bryan, Greg L.; Norman, Michael L.

    1994-01-01

    We present a detailed comparison of the simulation results of various hydrodynamic codes. Starting with identical initial conditions based on the cold dark matter scenario for the growth of structure, with parameters h = 0.5 Omega = Omega(sub b) = 1, and sigma(sub 8) = 1, we integrate from redshift z = 20 to z = O to determine the physical state within a representative volume of size L(exp 3) where L = 64 h(exp -1) Mpc. Five indenpendent codes are compared: three of them Eulerian mesh-based and two variants of the smooth particle hydrodynamics 'SPH' Lagrangian approach. The Eulerian codes were run at N(exp 3) = (32(exp 3), 64(exp 3), 128(exp 3), and 256(exp 3)) cells, the SPH codes at N(exp 3) = 32(exp 3) and 64(exp 3) particles. Results were then rebinned to a 16(exp 3) grid with the exception that the rebinned data should converge, by all techniques, to a common and correct result as N approaches infinity. We find that global averages of various physical quantities do, as expected, tend to converge in the rebinned model, but that uncertainites in even primitive quantities such as (T), (rho(exp 2))(exp 1/2) persists at the 3%-17% level achieve comparable and satisfactory accuracy for comparable computer time in their treatment of the high-density, high-temeprature regions as measured in the rebinned data; the variance among the five codes (at highest resolution) for the mean temperature (as weighted by rho(exp 2) is only 4.5%. Examined at high resolution we suspect that the density resolution is better in the SPH codes and the thermal accuracy in low-density regions better in the Eulerian codes. In the low-density, low-temperature regions the SPH codes have poor accuracy due to statiscal effects, and the Jameson code gives the temperatures which are too high, due to overuse of artificial viscosity in these high Mach number regions. Overall the comparison allows us to better estimate errors; it points to ways of improving this current generation ofhydrodynamic

  2. Two Dimensional Hydrodynamic Analysis of the Moose Creek Floodway

    Science.gov (United States)

    2012-09-01

    ER D C/ CH L TR -1 2 -2 0 Two Dimensional Hydrodynamic Analysis of the Moose Creek Floodway C oa st al a n d H yd ra u lic s La b or at...distribution is unlimited. ERDC/CHL TR-12-20 September 2012 Two Dimensional Hydrodynamic Analysis of the Moose Creek Floodway Stephen H. Scott, Jeremy A...A two-dimensional Adaptive Hydraulics (AdH) hydrodynamic model was developed to simulate the Moose Creek Floodway. The Floodway is located

  3. From hyperbolic regularization to exact hydrodynamics for linearized Grad's equations.

    Science.gov (United States)

    Colangeli, Matteo; Karlin, Iliya V; Kröger, Martin

    2007-05-01

    Inspired by a recent hyperbolic regularization of Burnett's hydrodynamic equations [A. Bobylev, J. Stat. Phys. 124, 371 (2006)], we introduce a method to derive hyperbolic equations of linear hydrodynamics to any desired accuracy in Knudsen number. The approach is based on a dynamic invariance principle which derives exact constitutive relations for the stress tensor and heat flux, and a transformation which renders the exact equations of hydrodynamics hyperbolic and stable. The method is described in detail for a simple kinetic model -- a 13 moment Grad system.

  4. LOCAL CLASSICAL SOLUTIONS TO THE EQUATIONS OF RELATIVISTIC HYDRODYNAMICS

    Institute of Scientific and Technical Information of China (English)

    史一蓬

    2001-01-01

    In this paper, we prove that the convexity of the negative thermodynamical entropy of the equations of relativistic hydrodynamics for ideal gas keeps its invariance under the Lorentz transformation if and only if the local sound speed is less than the light speed in vacuum. Then a symmetric form for the equations of relativistic hydrodynamics is presented and the local classical solution is obtained. Based on this,we prove that the nonrelativistic limit of the local classical solution to the relativistic hydrodynamics equations for relativistic gas is the local classical solution of the Euler equations for polytropic gas.

  5. Hydrodynamics in heavy-ion collisions: recent developments

    CERN Document Server

    Jaiswal, Amaresh

    2016-01-01

    Relativistic hydrodynamics has been quite successful in explaining the collective behaviour of the QCD matter produced in high energy heavy-ion collisions at RHIC and LHC. We briefly review the latest developments in the hydrodynamical modeling of relativistic heavy-ion collisions. Essential ingredients of the model such as the hydrodynamic evolution equations, dissipation, initial conditions, equation of state, and freeze-out process are reviewed. We discuss observable quantities such as particle spectra and anisotropic flow as well as the event-by-event fluctuations of these quantities. We also discuss the extraction of transport coefficients of the hot and dense QCD matter from the experimental data of collective flow.

  6. Applicability of the hydrodynamic description of classical fluids

    CERN Document Server

    Mithen, James P; Gregori, Gianluca

    2010-01-01

    We investigate using numerical simulations the domain of applicability of the hydrodynamic description of classical fluids at and near equilibrium. We find this to be independent of the degree of many-body correlations in the system; the range r_c of the microscopic interactions completely determines the maximum wavenumber k_{max} at which the hydrodynamic description is applicable by k_{max}r_c ~ 0.43. For the important special case of the Coulomb potential of infinite range, we show that the ordinary hydrodynamic description is never valid.

  7. Ion holes in the hydrodynamic regime in ultracold neutral plasmas

    Energy Technology Data Exchange (ETDEWEB)

    McQuillen, P.; Castro, J.; Strickler, T.; Bradshaw, S. J.; Killian, T. C. [Department of Physics and Astronomy, Rice University, Houston, Texas 77005 (United States)

    2013-04-15

    We describe the creation of localized density perturbations, or ion holes, in an ultracold neutral plasma in the hydrodynamic regime, and show that the holes propagate at the local ion acoustic wave speed. We also observe the process of hole splitting, which results from the formation of a density depletion initially at rest in the plasma. One-dimensional, two-fluid hydrodynamic simulations describe the results well. Measurements of the ion velocity distribution also show the effects of the ion hole and confirm the hydrodynamic conditions in the plasma.

  8. Hydrodynamics of Exploding Foil X-Ray Lasers with Time-Dependent Ionization Effect

    Science.gov (United States)

    Wang, Yu; Su, Dandan; Li, Yingjun

    2016-12-01

    A simple modified model is presented based on R. A. London's self-similarity model on time-independent ionization hydrodynamics of exploding foil X-ray lasers. In our model, the time-dependent ionization effect is under consideration and the average ion charge depends on the temperature. Then we obtain the new scaling laws for temperature, scale length and electron density, which have better agreement with experimental results. supported by National Natural Science Foundation of China (Nos. 11574390, 11374360, 41472130) and the National Basic Research Program of China (No. 2013CBA01504)

  9. Numerical simulation of shock wave phenomena in hydrodynamic model of semiconductor devices

    Institute of Scientific and Technical Information of China (English)

    XU Ning; YANG Geng

    2007-01-01

    We propose a finite element method to investigate the phenomena of shock wave and to simulate the hydrodynamic model in semiconductor devices. An introduction of this model is discussed first. Then some scaling factors and a relationship between the changing variables are discussed. And then, we use a finite element method (P1-iso-P2 element) to discrete the equations. Some boundary conditions are also discussed. Finally,a sub-micron n+-n-n+ silicon diode and Si MESFET device are simulated and the results are analyzed. Numerical results show that electronic fluids are transonic under some conditions.

  10. Spiral Countercurrent Chromatography

    Science.gov (United States)

    Ito, Yoichiro; Knight, Martha; Finn, Thomas M.

    2013-01-01

    For many years, high-speed countercurrent chromatography conducted in open tubing coils has been widely used for the separation of natural and synthetic compounds. In this method, the retention of the stationary phase is solely provided by the Archimedean screw effect by rotating the coiled column in the centrifugal force field. However, the system fails to retain enough of the stationary phase for polar solvent systems such as the aqueous–aqueous polymer phase systems. To address this problem, the geometry of the coiled channel was modified to a spiral configuration so that the system could utilize the radially acting centrifugal force. This successfully improved the retention of the stationary phase. Two different types of spiral columns were fabricated: the spiral disk assembly, made by stacking multiple plastic disks with single or four interwoven spiral channels connected in series, and the spiral tube assembly, made by inserting the tetrafluoroethylene tubing into a spiral frame (spiral tube support). The capabilities of these column assemblies were successfully demonstrated by separations of peptides and proteins with polar two-phase solvent systems whose stationary phases had not been well retained in the earlier multilayer coil separation column for high-speed countercurrent chromatography. PMID:23833207

  11. An implicit Smooth Particle Hydrodynamic code

    Energy Technology Data Exchange (ETDEWEB)

    Knapp, Charles E. [Univ. of New Mexico, Albuquerque, NM (United States)

    2000-05-01

    An implicit version of the Smooth Particle Hydrodynamic (SPH) code SPHINX has been written and is working. In conjunction with the SPHINX code the new implicit code models fluids and solids under a wide range of conditions. SPH codes are Lagrangian, meshless and use particles to model the fluids and solids. The implicit code makes use of the Krylov iterative techniques for solving large linear-systems and a Newton-Raphson method for non-linear corrections. It uses numerical derivatives to construct the Jacobian matrix. It uses sparse techniques to save on memory storage and to reduce the amount of computation. It is believed that this is the first implicit SPH code to use Newton-Krylov techniques, and is also the first implicit SPH code to model solids. A description of SPH and the techniques used in the implicit code are presented. Then, the results of a number of tests cases are discussed, which include a shock tube problem, a Rayleigh-Taylor problem, a breaking dam problem, and a single jet of gas problem. The results are shown to be in very good agreement with analytic solutions, experimental results, and the explicit SPHINX code. In the case of the single jet of gas case it has been demonstrated that the implicit code can do a problem in much shorter time than the explicit code. The problem was, however, very unphysical, but it does demonstrate the potential of the implicit code. It is a first step toward a useful implicit SPH code.

  12. Hydrodynamic characterization of fluid bed cokers

    Energy Technology Data Exchange (ETDEWEB)

    Knapper, B. [Saskatchewan Univ., Saskatoon, SK (Canada); Berruti, F. [Western Ontario Univ., London, ON (Canada); Grace, J.R.; Bi, H.T.; Lim, C.J. [British Columbia Univ., Vancouver, BC (Canada)

    2002-07-01

    Syncrude Canada Ltd. uses fluid bed cokers for thermal conversion of bitumen from Northern Alberta tar sands into distillates. This paper presents the results of a study that examined the hydrodynamic characteristics of a geometrically and dynamically scaled-down cold flow model of an industrial fluid bed coker. The cold flow model was constructed with Plexiglass with a semi-circular geometry to enable flow visualization of the solid particles. Several operating conditions were examined and measured for key characteristic parameters. Local void fractions were measured with an optical fibre probe, and a suction probe was used to determine the local solids mass fluxes at varying radial and axial locations of the fluidized bed. It was determined that there are large axial and radial variations in both the local voidage and solids mass flux in terms of gas-solids flow. The core-annulus model for dilute riser flow gives unsatisfactory predictions because the model is not able to forecast radial variations in the annular region. A modified core-annulus flow model was developed to address this problem. The modified model has continuous profiles for the gas velocity and solids flux to significantly improve predictions.16 refs., 1 tab., 3 figs.

  13. Hydrodynamic interaction between particles near elastic interfaces

    CERN Document Server

    Daddi-Moussa-Ider, Abdallah

    2016-01-01

    We present an analytical calculation of the hydrodynamic interaction between two spherical particles near an elastic interface such as a cell membrane. The theory predicts the frequency dependent self- and pair-mobilities accounting for the finite particle size up to the 5th order in the ratio between particle diameter and wall distance as well as between diameter and interparticle distance. We find that particle motion towards a membrane with pure bending resistance always leads to mutual repulsion similar as in the well-known case of a hard-wall. In the vicinity of a membrane with shearing resistance, however, we observe an attractive interaction in a certain parameter range which is in contrast to the behavior near a hard wall. This attraction might facilitate surface chemical reactions. Furthermore, we show that there exists a frequency range in which the pair-mobility for perpendicular motion exceeds its bulk value, leading to short-lived superdiffusive behavior. Using the analytical particle mobilities ...

  14. Hydrodynamic waves in an anomalous charged fluid

    Science.gov (United States)

    Abbasi, Navid; Davody, Ali; Hejazi, Kasra; Rezaei, Zahra

    2016-11-01

    We study the collective excitations in a relativistic fluid with an anomalous U (1) current. In 3 + 1 dimensions at zero chemical potential, in addition to ordinary sound modes we find two propagating modes in presence of an external magnetic field. The first one which is a transverse degenerate mode, propagates with a velocity proportional to the coefficient of gravitational anomaly; this is in fact the Chiral Alfvén wave recently found in [1]. Another one is a wave of density perturbation, namely a chiral magnetic wave (CMW). The velocity dependence of CMW on the chiral anomaly coefficient is well known. We compute the dependence of CMW's velocity on the coefficient of gravitational anomaly as well. We also show that the dissipation splits the degeneracy of CAW. At finite chiral charge density we show that in general there may exist five chiral hydrodynamic waves. Of these five waves, one is the CMW while the other four are mixed Modified Sound-Alfvén waves. It turns out that in propagation transverse to the magnetic field no anomaly effect appears while in parallel to the magnetic field we find sound waves become dispersive due to anomaly.

  15. Hydrodynamic design of the humpback whale flipper.

    Science.gov (United States)

    Fish, F E; Battle, J M

    1995-07-01

    The humpback whale (Megaptera novaeangliae) is reported to use its elongate pectoral flippers during swimming maneuvers. The morphology of the flipper from a 9.02-m whale was evaluated with regard to this hydrodynamic function. The flipper had a wing-like, high aspect ratio planform. Rounded tubercles were regularly interspersed along the flipper's leading edge. The flipper was cut into 71 2.5-cm cross-sections and photographed. Except for sections near the distal tip, flipper sections were symmetrical with no camber. Flipper sections had a blunt, rounded leading edge and a highly tapered trailing edge. Placement of the maximum thickness placement for each cross-section varied from 49% of chord at the tip to 19% at mid-span. Section thickness ratio averaged 0.23 with a range of 0.20-0.28. The humpback whale flipper had a cross-sectional design typical of manufactured aerodynamic foils for lift generation. The morphology and placement of leading edge tubercles suggest that they function as enhanced lift devices to control flow over the flipper and maintain lift at high angles of attack. The morphology of the humpback whale flipper suggests that it is adapted for high maneuverability associated with the whale's unique feeding behavior.

  16. Hydrodynamic Simulations of Unevenly Irradiated Jovian Planets

    CERN Document Server

    Langton, Jonathan

    2007-01-01

    We employ a two-dimensional grid-based hydrodynamic model to simulate upper atmospheric dynamics on extrasolar giant planets. Our model is well-suited to simulate the dynamics of the atmospheres of planets with high orbital eccentricity that are subject to widely-varying irradiation conditions. We identify six such planets, with eccentricities between $e=0.28$ and $e=0.93$ and semimajor axes ranging from $a=0.0508$ A.U. to $a=0.432$ A.U., as particularly interesting objects for study. For each of these planets, we determine the temperature profile and resulting infrared light curves in the 8-$\\mu$m Spitzer bands. Especially notable are the results for HD 80606b, which has the largest eccentricity ($e=0.9321$) of any known planet, and HAT-P-2b, which transits its parent star, so that its physical properties are well-constrained. Despite the variety of orbital parameters, the atmospheric dynamics of these eccentric planets display a number of interesting common properties. In all cases, the atmospheric response...

  17. DBI scalar field theory for QGP hydrodynamics

    Science.gov (United States)

    Nastase, Horatiu

    2016-07-01

    A way to describe the hydrodynamics of the quark-gluon plasma using a Dirac-Born-Infeld (DBI) action is proposed, based on the model found by Heisenberg for high energy scattering of nucleons. The expanding plasma is described as a shockwave in a DBI model for a real scalar standing in for the pion, and I show that one obtains a fluid description in terms of a relativistic fluid that near the shock is approximately ideal (η ≃0 ) and conformal. One can introduce an extra term inside the square root of the DBI action that generates a shear viscosity term in the energy-momentum tensor near the shock, as well as a bulk viscosity, and regulates the behavior of the energy density at the shock, making it finite. The resulting fluid satisfies the relativistic Navier-Stokes equation with uμ,ρ ,P ,η defined in terms of ϕ and its derivatives. One finds a relation between the parameters of the theory and the quark-gluon plasma thermodynamics, α /β2=η /(s T ), and by fixing α and β from usual (low multiplicity) particle scattering, one finds T ∝mπ.

  18. An analytical model of flagellate hydrodynamics

    Science.gov (United States)

    Dölger, Julia; Bohr, Tomas; Andersen, Anders

    2017-04-01

    Flagellates are unicellular microswimmers that propel themselves using one or several beating flagella. We consider a hydrodynamic model of flagellates and explore the effect of flagellar arrangement and beat pattern on swimming kinematics and near-cell flow. The model is based on the analytical solution by Oseen for the low Reynolds number flow due to a point force outside a no-slip sphere. The no-slip sphere represents the cell and the point force a single flagellum. By superposition we are able to model a freely swimming flagellate with several flagella. For biflagellates with left–right symmetric flagellar arrangements we determine the swimming velocity, and we show that transversal forces due to the periodic movements of the flagella can promote swimming. For a model flagellate with both a longitudinal and a transversal flagellum we determine radius and pitch of the helical swimming trajectory. We find that the longitudinal flagellum is responsible for the average translational motion whereas the transversal flagellum governs the rotational motion. Finally, we show that the transversal flagellum can lead to strong feeding currents to localized capture sites on the cell surface.

  19. Hydrodynamic transport functions from quantum kinetic theory

    CERN Document Server

    Calzetta, E A; Ramsey, S

    2000-01-01

    Starting from the quantum kinetic field theory [E. Calzetta and B. L. Hu, Phys. Rev. D37, 2878 (1988)] constructed from the closed-time-path (CTP), two-particle-irreducible (2PI) effective action we show how to compute from first principles the shear and bulk viscosity functions in the hydrodynamic-thermodynamic regime. For a real scalar field with $\\lambda \\Phi ^{4}$ self-interaction we need to include 4 loop graphs in the equation of motion. This work provides a microscopic field-theoretical basis to the ``effective kinetic theory'' proposed by Jeon and Yaffe [S. Jeon and L. G. Yaffe, Phys. Rev. D53, 5799 (1996)], while our result for the bulk viscosity reproduces their expression derived from linear response theory and the imaginary-time formalism of thermal field theory. Though unavoidably involved in calculations of this sort, we feel that the approach using fundamental quantum kinetic field theory is conceptually clearer and methodically simpler than the effective kinetic theory approach, as the success...

  20. Rheological and fractal hydrodynamics of aerobic granules.

    Science.gov (United States)

    Tijani, H I; Abdullah, N; Yuzir, A; Ujang, Zaini

    2015-06-01

    The structural and hydrodynamic features for granules were characterized using settling experiments, predefined mathematical simulations and ImageJ-particle analyses. This study describes the rheological characterization of these biologically immobilized aggregates under non-Newtonian flows. The second order dimensional analysis defined as D2=1.795 for native clusters and D2=1.099 for dewatered clusters and a characteristic three-dimensional fractal dimension of 2.46 depicts that these relatively porous and differentially permeable fractals had a structural configuration in close proximity with that described for a compact sphere formed via cluster-cluster aggregation. The three-dimensional fractal dimension calculated via settling-fractal correlation, U∝l(D) to characterize immobilized granules validates the quantitative measurements used for describing its structural integrity and aggregate complexity. These results suggest that scaling relationships based on fractal geometry are vital for quantifying the effects of different laminar conditions on the aggregates' morphology and characteristics such as density, porosity, and projected surface area.

  1. MUFASA: Galaxy Formation Simulations With Meshless Hydrodynamics

    CERN Document Server

    Davé, Romeel; Hopkins, Philip F

    2016-01-01

    We present the MUFASA suite of cosmological hydrodynamic simulations, which employs the GIZMO meshless finite mass (MFM) code including H2-based star formation, nine-element chemical evolution, two-phase kinetic outflows following scalings from the Feedback in Realistic Environments zoom simulations, and evolving halo mass-based quenching. Our fiducial (50 Mpc/h)^3 volume is evolved to z=0 with a quarter billion particles, The predicted galaxy stellar mass functions (GSMF) reproduce observations from z=4-0 to <1.2sigma in cosmic variance, providing an unprecedented match to this key diagnostic. The cosmic star formation history and stellar mass growth show general agreement with data, with a strong archaeological downsizing trend such that dwarf galaxies form the majority of their stars after z~1. We run 25 Mpc/h and 12.5 Mpc/h volumes to z=2 with identical feedback prescriptions, the latter resolving all hydrogen-cooling halos, and the three runs display fair resolution convergence. The specific star form...

  2. Bounce-free spherical hydrodynamic implosion

    Science.gov (United States)

    Kagan, Grigory; Tang, Xian-Zhu; Hsu, Scott C.; Awe, Thomas J.

    2011-10-01

    In a bounce-free spherical hydrodynamic implosion, the post-stagnation hot core plasma does not expand against the imploding flow. A solution family realizing such a regime has been explicitly found. This regime found is most naturally applied and would be of most benefit to plasma liner driven magneto-inertial fusion (MIF). That is, this version of inertial confinement relies on maintaining the compressed hot spot within the thermonuclear burning condition for as long as possible, rather than on initiating the burn wave. Consequently, in MIF it is the best-case scenario that the fuel target persists in the state of maximum compression after reaching stagnation. Also, the plasma liner driven MIF provides substantial freedom in shaping the profiles of the imploding flow (i.e. liner) pressure, density and fluid velocity. By comparing the fuel disassembly time against that of a stationary imploding flow case, we find that shaping this flow appropriately is likely to increase the dwell time and fusion gain by a factor of four or more. Moreover, in this newly found regime the shocked region of the liner is at rest. That is, the kinetic energy of the original liner is entirely converted into internal energy. Hence, our result supports the idea of using the deuterium-tritium in the inner parts of the liner or the so-called ``after-burner,'' which upon becoming shocked will also burn, thus further increasing the gain. The work is supported by LANL LDRD.

  3. Hydrodynamical description of Galactic dark matter

    CERN Document Server

    Cabral, L G; Sussman, R A; Matos, T

    2003-01-01

    We consider simple hydrodynamical models of galactic dark matter in which the galactic halo is a self-gravitating and self-interacting gas that dominates the dynamics of the galaxy. Modeling this halo as a sphericaly symmetric and static perfect fluid satisfying the field equations of General Relativity, visible barionic matter can be treated as 'test particles' in the geometry of this field. We show that the assumption of an empirical 'universal rotation curve' that fits a wide variety of galaxies is compatible, under suitable approximations, with state variables characteristic of a non-relativistic Maxwell-Boltzmann gas that becomes an isothermal sphere in the Newtonian limit. Consistency criteria lead to a minimal bound for particle masses in the range 30 eV < m < 60 eV and to a constraint between the central temperature and the particles mass. The allowed mass range includes popular supersymmetric particle candidates, such as the neutslino, axino and gravitino, as well as lighter particles (m - keV)...

  4. Hydrodynamics of marine and offshore structures

    Institute of Scientific and Technical Information of China (English)

    FALTINSEN O. M

    2014-01-01

    An overview of hydrodynamic problems related to the broad variety of ships and sea structures involved in transportation, oil and gas exploration and production, marine operations, recovery of oil-spill, renewable energy, infrastructure and aquaculture is given. An approximate hydroelastic model for wave and current induced response of a floating fish farm with circular plastic collar and net cage is discussed. Weakly nonlinear potential-flow problems such as slow-drift motions and stationkeeping, springing of ships and ringing are given special attention. Body-fixed coordinate system is recommended in weakly nonlinear potential-flow ana-lysis of bodies with sharp corners. Dynamic ship instabilities, Mathieu-type instabilities, chaos and two-phase flow involving inter-face instabilities are discussed. It is advocated that slamming must be coupled with structural mechanics in order to find important time scales of the many physical effects associated with slamming and that both water entry and exit matter in describing the global wetdeck slamming effects. Further, sloshing-induced slamming in prismatic LNG tanks is perhaps the most complicated slamming problem because many fluid mechanic and thermodynamic parameters as well as hydroelasticity may matter.

  5. Modeling the hydrodynamics of phloem sieve plates

    Directory of Open Access Journals (Sweden)

    Kaare Hartvig Jensen

    2012-07-01

    Full Text Available Sieve plates have an enormous impact on the efficiency of the phloem vascular system of plants, responsible for the distribution of photosynthetic products. These thin plates, which separate neighboring phloem cells, are perforated by a large number of tiny sieve pores and are believed to play a crucial role in protecting the phloem sap from intruding animals by blocking flow when the phloem cell is damaged. The resistance to the flow of viscous sap in the phloem vascular system is strongly affected by the presence of the sieve plates, but the hydrodynamics of the flow through them remains poorly understood. We propose a theoretical model for quantifying the effect of sieve plates on the phloem in the plant, thus unifying and improving previous work in the field. Numerical simulations of the flow in real and idealized phloem channels verify our model, and anatomical data from 19 plant species are investigated. We find that the sieve plate resistance is correlated to the cell lumen resistance, and that the sieve plate and the lumen contribute almost equally to the total hydraulic resistance of the phloem translocation pathway.

  6. Hydrodynamics of the Veracruz Reef System

    Science.gov (United States)

    Marin Hernandez, M.

    2013-05-01

    One year of hydrographic and current measurements in the Veracruz Reef System National Park (VRSNP) at the southwestern Gulf of Mexico are analyzed. To our knowledge, this is the first study of seasonal variations from observations in the region. The area has a particular dynamics because this reef system receives discharges of three rivers, in the northern (Antigua river), in the center (Jamapa river) and in the southern (Papaloapan river), dividing the VRSNP in two reef groups. In order to know the hydrodynamics, four transects perpendicular to the coast were accomplished, two on every side of the reef groups. Up to the date, there have been completed 6 oceanographic campaigns every 2 months, where ADCP currents data were collected continuously on all transects and thermohaline fields were obtained from 24 survey stations along transects using CTD. The area has three well-marked seasons: dry, rain and Nortes (strong winds resulting from the passage of cold fronts). During the rain season the river discharges have a significant impact in the thermohaline profiles. Temporary changes in stratification of the water column, spatial distribution of temperature and salinity, as well as temporary changes in currents direction were established for the three seasons.

  7. A hydrodynamic model for cooperating solidary countries

    Science.gov (United States)

    De Luca, Roberto; Di Mauro, Marco; Falzarano, Angelo; Naddeo, Adele

    2017-07-01

    The goal of international trade theories is to explain the exchange of goods and services between different countries, aiming to benefit from it. Albeit the idea is very simple and known since ancient history, smart policy and business strategies need to be implemented by each subject, resulting in a complex as well as not obvious interplay. In order to understand such a complexity, different theories have been developed since the sixteenth century and today new ideas still continue to enter the game. Among them, the so called classical theories are country-based and range from Absolute and Comparative Advantage theories by A. Smith and D. Ricardo to Factor Proportions theory by E. Heckscher and B. Ohlin. In this work we build a simple hydrodynamic model, able to reproduce the main conclusions of Comparative Advantage theory in its simplest setup, i.e. a two-country world with country A and country B exchanging two goods within a genuine exchange-based economy and a trade flow ruled only by market forces. The model is further generalized by introducing money in order to discuss its role in shaping trade patterns. Advantages and drawbacks of the model are also discussed together with perspectives for its improvement.

  8. A Smoothed Particle Hydrodynamics approach for poroelasticity

    Science.gov (United States)

    Osorno, Maria; Steeb, Holger

    2016-04-01

    Within the framework of the SHynergie project we look to investigate hydraulic fracturing and crack evolving in poroelastic media. We model biphasic media assuming incompressible solid grain and incompressible pore liquid. Modeling evolving fractures and fracture networks in elastic and poroelastic media by mesh-based numerical approaches, like X-FEM, is especially in 3-dim a challenging task. Therefore, we propose a meshless particle method for fractured media based on the Smoothed Particle Hydrodynamics (SPH) approach. SPH is a meshless Lagrangian method highly suitable for the simulation of large deformations including free surfaces and/or interfaces. Within the SPH method, the computational domain is discretized with particles, avoiding the computational expenses of meshing. Our SPH solution is implemented in a parallel computational framework, which allows to simulate large domains more representative of the scale of our study cases. Our implementation is carefully validated against classical mesh-based approaches and compared with classical solutions for consolidation problems. Furthermore, we discuss fracture initiation and propagation in poroelastic rocks at the reservoir scale.

  9. Hydrodynamic simulations on a moving Voronoi mesh

    CERN Document Server

    Springel, Volker

    2011-01-01

    At the heart of any method for computational fluid dynamics lies the question of how the simulated fluid should be discretized. Traditionally, a fixed Eulerian mesh is often employed for this purpose, which in modern schemes may also be adaptively refined during a calculation. Particle-based methods on the other hand discretize the mass instead of the volume, yielding an approximately Lagrangian approach. It is also possible to achieve Lagrangian behavior in mesh-based methods if the mesh is allowed to move with the flow. However, such approaches have often been fraught with substantial problems related to the development of irregularity in the mesh topology. Here we describe a novel scheme that eliminates these weaknesses. It is based on a moving unstructured mesh defined by the Voronoi tessellation of a set of discrete points. The mesh is used to solve the hyperbolic conservation laws of ideal hydrodynamics with a finite volume approach, based on a second-order Godunov scheme with an exact Riemann solver. A...

  10. Hydrodynamics of pedestrians' instability in floodwaters

    Science.gov (United States)

    Arrighi, Chiara; Oumeraci, Hocine; Castelli, Fabio

    2017-01-01

    People's safety is the first objective to be fulfilled by flood risk mitigation measures, and according to existing reports on the causes of casualties, most of the fatalities are due to inappropriate behaviour such as walking or driving in floodwaters. Currently available experimental data on people instability in floodwaters suffer from a large dispersion primarily depending on the large variability of the physical characteristics of the subjects. This paper introduces a dimensionless mobility parameter θP for people partly immersed in flood flows, which accounts for both flood and subject characteristics. The parameter θP is capable of identifying a unique threshold of instability depending on a Froude number, thus reducing the scatter of existing experimental data. Moreover, a three-dimensional (3-D) numerical model describing the detailed geometry of a human body and reproducing a selection of critical pairs of water depth and velocity is presented. The numerical results in terms of hydrodynamic forces and force coefficients are analysed and discussed. Both the mobility parameter θP and the numerical results hint at the crucial role of the Froude number and relative submergence as the most relevant dimensionless numbers to interpret the loss of stability. Finally, the mobility parameter θP is compared with an analogous dimensionless parameter for vehicles' instability in floodwaters, providing a new contribution to support flood risk management and educating people.

  11. Flow Rates in Liquid Chromatography, Gas Chromatography and Supercritical Fluid Chromatography: A Tool for Optimization

    OpenAIRE

    Joris Meurs

    2016-01-01

    This paper aimed to develop a standalone application for optimizing flow rates in liquid chromatography (LC), gas chromatography (GC) and supercritical fluid chromatography (SFC). To do so, Van Deemter’s equation, Knox’ equation and Golay’s equation were implemented in a MATLAB script and subsequently a graphical user interface (GUI) was created. The application will show the optimal flow rate or linear velocity and the corresponding plate height for the set input parameters. Furthermore, a p...

  12. Concurrent multiscale modelling of atomistic and hydrodynamic processes in liquids

    Science.gov (United States)

    Markesteijn, Anton; Karabasov, Sergey; Scukins, Arturs; Nerukh, Dmitry; Glotov, Vyacheslav; Goloviznin, Vasily

    2014-01-01

    Fluctuations of liquids at the scales where the hydrodynamic and atomistic descriptions overlap are considered. The importance of these fluctuations for atomistic motions is discussed and examples of their accurate modelling with a multi-space–time-scale fluctuating hydrodynamics scheme are provided. To resolve microscopic details of liquid systems, including biomolecular solutions, together with macroscopic fluctuations in space–time, a novel hybrid atomistic–fluctuating hydrodynamics approach is introduced. For a smooth transition between the atomistic and continuum representations, an analogy with two-phase hydrodynamics is used that leads to a strict preservation of macroscopic mass and momentum conservation laws. Examples of numerical implementation of the new hybrid approach for the multiscale simulation of liquid argon in equilibrium conditions are provided. PMID:24982246

  13. Effect of hydrodynamic cavitation on zooplankton: A tool for disinfection

    Digital Repository Service at National Institute of Oceanography (India)

    Sawant, S.S.; Anil, A.C.; Venkat, K.; Gaonkar, C.; Kolwalkar, J.; Khandeparker, L.; Desai, D.V.; Mahulkar, A.V.; Ranade, V.V.; Pandit, A.B.

    Application of hydrodynamic cavitation for disinfection of water is gaining momentum, as it provides environmentally and economically sound options. In this effort, the effect of cavitating conditions created by differential pump valve opening...

  14. Combining Hydrodynamic and Evolution Calculations of Rotating Stars

    Science.gov (United States)

    Deupree, R. G.

    1996-12-01

    Rotation has two primary effects on stellar evolutionary models: the direct influence on the model structure produced by the rotational terms, and the indirect influence produced by rotational instabilities which redistribute angular momentum and composition inside the model. Using a two dimensional, fully implicit finite difference code, I can follow events on both evolutionary and hydrodynamic timescales, thus allowing the simulation of both effects. However, there are several issues concerning how to integrate the results from hydrodynamic runs into evolutionary runs that must be examined. The schemes I have devised for the integration of the hydrodynamic simulations into evolutionary calculations are outlined, and the positive and negative features summarized. The practical differences among the various schemes are small, and a successful marriage between hydrodynamic and evolution calculations is possible.

  15. RANDOM ATTRACTORS FOR A STOCHASTIC HYDRODYNAMICAL EQUATION IN HEISENBERG PARAMAGNET

    Institute of Scientific and Technical Information of China (English)

    Guo Boling; Guo Chunxiao; Pu Xueke

    2011-01-01

    This article studies the asymptotic behaviors of the solution for a stochastic hydrodynamical equation in Heisenberg paramagnet in a two-dimensional periodic domain. We obtain the existence of random attractors in H1.

  16. Smooth Solutions for a Stochastic Hydrodynamical Equation in Heisenberg Paramagnet

    Institute of Scientific and Technical Information of China (English)

    Xue Ke PU; Bo Ling GUO; Yong Qian HAN

    2011-01-01

    In this article,we consider a stochastic hydrodynamical equation in Heisenberg paramagnet driven by additive noise.We prove the existence and uniqueness of smooth solutions to this equation with difference method.

  17. The use of hydrodynamic disintegration as a means to improve ...

    African Journals Online (AJOL)

    2008-09-15

    Sep 15, 2008 ... Disintegration by hydrodynamic cavitation has a positive effect on the degree and rate of sludge anaerobic digestion. ... (ball mill, ultrasonic), oxidation (ozone and hydrogen per- .... American Public Health Association, Wash-.

  18. Non-dissipative hydrodynamics: Effective actions versus entropy current

    CERN Document Server

    Bhattacharya, Jyotirmoy; Rangamani, Mukund

    2012-01-01

    While conventional hydrodynamics incorporating dissipative effects is hard to derive from an action principle, it is nevertheless possible to construct classical actions when the dissipative terms are switched off. In this note we undertake a systematic exploration of such constructions from an effective field theory approach and argue for the existence of non-trivial second order non-dissipative hydrodynamics involving pure energy-momentum transport. We find these fluids to be characterized by five second-order transport coefficients based on the effective action (a three parameter family is Weyl invariant). On the other hand since all flows of such fluids are non-dissipative, they entail zero entropy production; one can therefore understand them using the entropy current formalism which has provided much insight into hydrodynamic transport. An analysis of the most general stress tensor with zero entropy production however turns out to give a seven parameter family of non-dissipative hydrodynamics (a four pa...

  19. Instability of aqueous solutions of polyacrylamide in a hydrodynamic field

    Science.gov (United States)

    Makogon, B. P.; Bykova, E. N.; Bezrukova, M. A.; Klenin, S. I.; Ivanyuta, Yu. F.; Povkh, I. L.; Toryanik, A. I.

    1985-09-01

    This article discusses findings obtained regarding the effect of a hydrodynamic field on the reduced viscosity, effect of turbulent friction reduction, light scattering, double refraction, and optical density of aqueous solutions of hydrolyzed polyacrylamide.

  20. Jeans instability and hydrodynamic roots of Landau damping

    CERN Document Server

    Ershkovich, Alexander

    2015-01-01

    Landau damping of Langmuir waves is shown to have hydrodynamic roots, and, in principle, might have been predicted (along with Langmuir waves) several decades earlier, soon after Jeans (1902) paper appeared.