Sample records for hydrodesulfurization hds process

  1. Organometallic Modeling of the Hydrodesulfurization (HDS) Process: Rhenium Carbonyl-promoted C-S Bond Cleavage and Hydrogenation of Thiophenes and Benozothiophenes

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, Michael A. [Iowa State Univ., Ames, IA (United States)


    Organometallic modeling of the HDS process at single or multiple metal centers is one approach to better understanding the mechanism that govern commercial HDS. Therefore, we have currently been investigating the use of Re2(CO)10 as a potential model system for catalytic HDS with respect to S-binding, ring-opening, and hydrogenation of thiophenes andbenzothiophenes. We have also been investigating the use of UV-light as a method for activating thiophenic molecules towards C-S and C-H bond cleavage.

  2. HDS for fuel cell applications

    NARCIS (Netherlands)

    Alsolami, B.H.


    The objective of this chapter is to investigate the feasibility of developing a catalytic hydrodesulfurization (HDS) process operating under low pressure and high temperature conditions to produce a near-zero sulfur content diesel suitable for fuel cell applications. As expected, it was found that

  3. Integrating principal component analysis and vector quantization with support vector regression for sulfur content prediction in HDS process

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    Shokri Saeid


    Full Text Available An accurate prediction of sulfur content is very important for the proper operation and product quality control in hydrodesulfurization (HDS process. For this purpose, a reliable data- driven soft sensors utilizing Support Vector Regression (SVR was developed and the effects of integrating Vector Quantization (VQ with Principle Component Analysis (PCA were studied on the assessment of this soft sensor. First, in pre-processing step the PCA and VQ techniques were used to reduce dimensions of the original input datasets. Then, the compressed datasets were used as input variables for the SVR model. Experimental data from the HDS setup were employed to validate the proposed integrated model. The integration of VQ/PCA techniques with SVR model was able to increase the prediction accuracy of SVR. The obtained results show that integrated technique (VQ-SVR was better than (PCA-SVR in prediction accuracy. Also, VQ decreased the sum of the training and test time of SVR model in comparison with PCA. For further evaluation, the performance of VQ-SVR model was also compared to that of SVR. The obtained results indicated that VQ-SVR model delivered the best satisfactory predicting performance (AARE= 0.0668 and R2= 0.995 in comparison with investigated models.

  4. Trends in hydrodesulfurization catalysis based on realistic surface models

    DEFF Research Database (Denmark)

    Moses, P.G.; Grabow, L.C.; Fernandez Sanchez, Eva


    Trends in hydrodesulfurization (HDS) activity are investigated on the basis of surface properties calculated by density functional theory for a series of HDS catalysts. It is shown that approximately linear correlations exist between HS group binding energies and activation barriers of key elemen...

  5. Modeling and simulation of hydrodemetallation and hydrodesulfurization processes with transient catalytic efficiency

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    E.M. Matos


    Full Text Available A model is presented for the description of the concentration behavior of organometallic and sulfurated compounds in hydrodemetallation and hydrodesulfurization catalytic processes, where catalyst effectiveness decreases with time. Due to the complexity of the mixture, an approach based on pseudocomponents was adopted. The system is modeled as an isothermal tubular reactor with axial dispersion, where the gas phase (hydrogen in excess flows upward concurrently with the liquid phase (heavy oil while the solid phase (catalyst stays inside the reactor in an expanded (confined bed regime. The catalyst particles are very small and are assumed to be uniformly distributed in the reactor. The heavy oil fractions contain organometallics and sulfurated compounds, from which the metals and sulfur are to be removed, the metals as deposits in the catalyst pores and the sulfur as gas products. Simulations were carried out where the concentration profile inside the reactor was calculated for several residence times.

  6. PEMEX selects the H-Oil{reg_sign} process for their hydrodesulfurization residue complex at the Miguel Hidalgo Refinery

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    Wisdom, L.I.; Colyar, J.J. [Hydrocarbon Research, Inc., Princeton, NJ (United States)


    Petroleos Mexicanos (PEMEX) has selected the H-Oil Process for the conversion and upgrading of a blend of Maya and Isthmus vacuum residua at the Miguel Hidalgo Refinery. The 8,450 metric ton/day (50,000 bpsd) H-Oil Plant will produce a low sulfur (0.8 wt%) fuel oil, diesel, naphtha, and LPG. The H-Oil Plant will be a key component of the Hydrodesulfurization Residue (HDR) Complex which will be located at the Miguel Hidalgo Refinery in Tula, State of Hidalgo, Mexico. The project is part of PEMEX`s Ecology Projects currently underway in Mexico. This paper describes the HDR Complex and the design basis of the H-Oil Plant and provides the current status of this project.

  7. Sensitivity analysis of a light gas oil deep hydrodesulfurization process via catalytic distillation

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    Rosales-Quintero, A.; Vargas-Villamil, F.D. [Prog. de Matematicas Aplicadas y Computacion, Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152, Mexico, D.F. 07330 (Mexico); Arce-Medina, E. [Instituto Politecnico Nacional, ESIQIE, Ed. 8 Col. Lindavista, Mexico, D.F. 07738 (Mexico)


    In this work, a sensitivity analysis of a light gas oil deep hydrodesulfurization catalytic distillation column is presented. The aim is to evaluate the effects of various parameters and operating conditions on the organic sulfur compound elimination by using a realistic light gas oil fraction. The hydrocarbons are modeled using pseudocompounds, while the organic sulfur compounds are modeled using model compounds, i.e., dibenzothiophene (DBT) and 4,6-dimethyl dibenzothiophene (4,6-DMDBT). These are among the most refractive sulfur compounds present in the oil fractions. A sensitivity analysis is discussed for the reflux ratio, bottom flow rate, condenser temperature, hydrogen and gas oil feed stages, catalyst loading, the reactive, stripping, and rectifying stages, feed disturbances, and multiple feeds. The results give insight into the qualitative effect of some of the operating variables and disturbances on organic sulfur elimination. In addition, they show that special attention must be given to the bottom flow rate and LGO feed rate control. (author)

  8. Emissions of polycyclic aromatic hydrocarbons from thermal pre-treatment of waste hydrodesulfurization catalysts. (United States)

    Lai, Yi-Chieh; Lee, Wen-Jhy; Huang, Kuo-Lin; Huang, Hong-Hsin


    Despite increasing environmental concerns and stringent limitations on the sulfur content in fuels, many waste hydrodesulfurization (HDS) catalysts containing Co, Mo, Ni and V are generated in the petroleum refining process. To recover valuable metals in the waste HDS catalysts via hydrometallurgy, thermal treatment is usually performed first to remove contaminants (residual oil, carbon and sulfur) present on the surface of catalysts. In this study, the mass partitions of polycyclic aromatic hydrocarbons (PAHs) in different media (aqueous, particulate and gaseous) were quantified in order to determine the efficiency of three different air pollution control devices, cooling unit, filter and glass cartridge, on PAH removal. An afterburner and two furnace temperatures were used to observe the effect on the PAH contents of the treated residues. Results show that total-PAH content in treated residues decreased with the pyrolysis temperature of the primary furnace, while those generated in flue gases were destroyed by the afterburner at an efficiency of approximately 95%. In addition, the thermal process converts high molecular weight PAHs to low molecular weight PAHs, and the afterburner temperature involved (1200 degrees C) was high enough to prohibit the generation of high molecular weight PAHs (HM-PAHs), leading to the domination of low molecular weight PAHs (LM-PAHs) in flue gases, while treated residues were dominated by HM-PAHs. Finally, information on metal contents and their concentrations in the Toxicity Characteristic Leaching Procedure in waste HDS catalyst and thermal treated residues are examined as an index of the potential for metal recovery.

  9. The hydrodesulfurization of thiophene by Mo/Co treated oxyaluminum pillared montimorillonites


    Howard, Bret Harmon


    The purpose of this study was to investigate the synthesis and properties of oxyaluminum pillared montmorillonites prepared using the controlled hydrolysis of aluminum isopropoxide as the source of pillaring species and to evaluate pillared montmorillonites as supports for hydrodesulfurization (HDS) catalysts. Several synthesis schemes were evaluated for the preparation of pillared montmorillonites. Successful pillaring was accomplished by addition of cyclohexane solutions of aluminum isop...

  10. A new approach to synthesize supported ruthenium phosphides for hydrodesulfurization

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    Wang, Qingfang [Tianjin Key Laboratory of Water Environment and Resources, Tianjin Normal University, Tianjin 300387 (China); Key Laboratory of Advanced Energy Materials Chemistry (MOE), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071 (China); Wang, Zhiqiang [Tianjin Key Laboratory of Water Environment and Resources, Tianjin Normal University, Tianjin 300387 (China); Yin, Xiaoqian; Zhou, Linxi [Key Laboratory of Advanced Energy Materials Chemistry (MOE), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071 (China); Zhang, Minghui, E-mail: [Key Laboratory of Advanced Energy Materials Chemistry (MOE), Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), College of Chemistry, Nankai University, Tianjin 300071 (China); College of Chemistry and Environmental Science, Kashgar University, Kashgar 844006 (China)


    Highlights: • We bring out a new method to synthesize noble metal phosphides at low temperature. • Both RuP and Ru{sub 2}P were synthesized using triphenylphosphine as phosphorus sources. • Ru{sub 2}P was the better active phase for HDS than RuP and metal Ru. • RuP/SiO{sub 2} prepared by new method had better HDS activity to that by TPR method. - Abstract: Supported noble metal ruthenium phosphides were synthesized by one-step H{sub 2}-thermal treatment method using triphenylphosphine (TPP) as phosphorus sources at low temperatures. Two phosphides RuP and Ru{sub 2}P can be prepared by this method via varying the molar ratio of metal salt and TPP. The as-prepared phosphides were characterized by X-ray powder diffraction (XRD), low-temperature N{sub 2} adsorption, CO chemisorption and transmission electronic microscopy (TEM). The supported ruthenium phosphides prepared by new method and conventional method together with contradistinctive metallic ruthenium were evaluated in hydrodesulfurization (HDS) of dibenzothiophene (DBT). The catalytic results showed that metal-rich Ru{sub 2}P was the better active phase for HDS than RuP and metal Ru. Besides this, ruthenium phosphide catalyst prepared by new method exhibited superior HDS activity to that prepared by conventional method.

  11. Hydrothermal synthesis of Ni{sub 2}P nanoparticle and its hydrodesulfurization of dibenzothiophene

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    Zhao, Qi; Han, Yang; Huang, Xiang, E-mail:; Dai, Jinhui; Tian, Jintao; Zhu, Zhibin; Yue, Li [Ocean University of China, Institute of Materials Science and Engineering (China)


    Nanosized nickel phosphide (Ni{sub 2}P) has been synthesized via hydrothermal reaction with environmental-friendly red phosphorus and nickel chloride. The reaction mechanism has been studied by measurement techniques of IC, XRD ,TEM, EDS, and XPS. The results showed that the particle sizes of as-prepared Ni{sub 2}P are in nanoscale ranging from 10 to 30 nm. In hydrothermal reaction, red phosphorus reacts with water to its oxyacids, especially its hypophosphorous acid (or hypophosphite) which can reduce nickel chloride to nickel, and then metallic nickel will penetrate into the rest of red phosphorus to generate nano-Ni{sub 2}P. Furthermore, the catalytic performance of as-synthesized Ni{sub 2}P for the hydrodesulfurization of dibenzothiophene has been tested. It has been shown that the HDS reaction process over Ni{sub 2}P catalyst agrees well with the pseudo-first order kinetic equation, and the HDS conversion can reach up to 43.83% in 5 h with a stable increasing catalytic activity during the whole examination process.

  12. Characterization of coke, or carbonaceous matter, formed on CoMo catalysts used in hydrodesulfurization unit in oil refinery (United States)

    Kimura, Nobuharu; Iwanami, Yoshimu; Koide, Ryutaro; Kudo, Reiko


    When a mixture of light gas oil (LGO) and light cycle oil is fed into an oil refinery’s hydrodesulfurization (HDS) unit to produce diesel fuel, the catalyst in the HDS unit is rapidly deactivated. By contrast, when the feed is LGO mixed with residue desulfurization gas oil, the catalyst is deactivated slowly. Hoping to understand why, the authors focused on the coke formed on the catalysts during the HDS reaction. The result of a comprehensive analysis of the coke suggested that the ways coke formed and grew on the catalysts may differ depending on the feeds used, which in turn could affect the deactivation behaviors of the catalysts.

  13. A density functional study of inhibition of the HDS hydrogenation pathway by pyridine, benzene, and H2S on MoS2-based catalysts

    DEFF Research Database (Denmark)

    Logadottir, A.; Moses, Poul Georg; Hinnemann, Berit


    The inhibition of catalytic hydrodesulfurization (HDS) by basic nitrogen compounds is an important problem it) the production of ultra low sulfur transportation fuels and the origin of the inhibition effects is presently elucidated by performing density functional theory (DFT) calculations on the...

  14. Ambient Pressure Hydrodesulfurization of Refractory Sulfur Compounds in Highly Sensitive μ-Reactor Platform Coupled to a Time-of-Flight Mass Spectrometer

    DEFF Research Database (Denmark)

    Christoffersen, Ann-Louise N.; Bodin, Anders; Elkjær, Christian F.


    Tightened restrictions call for cleaner transportation fuels to minimize environmental and societal problems caused by the presence of sulfur in transportation fuels. This emphasizes the need for new and better catalysts in the field of hydrodesulfurization (HDS), which aims at removing the refra...

  15. Relation between Hydrogen Evolution and Hydrodesulfurization Catalysis

    DEFF Research Database (Denmark)

    Šaric, Manuel; Moses, Poul Georg; Rossmeisl, Jan


    A relation between hydrogen evolution and hydrodesulfurization catalysis was found by density functional theory calculations. The hydrogen evolution reaction and the hydrogenation reaction in hydrodesulfurization share hydrogen as a surface intermediate and, thus, have a common elementary step...

  16. Synergism between unsupported Re and Co or Ni sulfide catalysts in the HDS and HDN of gas oil

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    Escalona, N.; Garcia, R. [Facultad de Ciencias Quimicas, Universidad de Concepcion, Concepcion (Chile); Ojeda, J.; Baeza, P.; Gil-Llambas, F.J. [Universidad de Santiago de Chile, Casilla 40, Correo 33, Santiago (Chile); Palacios, J.M.; Fierro, J.L.G.; Agudo, A. Lopez [Instituto de Catalisis y Petroleoquimica, CSIC, Cantoblanco, 28049, Madrid (Spain)


    Two series of unsupported Co-Re and Ni-Re binary sulfide catalysts with variable atomic ratio {alpha}=Me/(Me+Re) from 0 to 1 were prepared by the co-maceration method. The catalysts were characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), and evaluated in the simultaneous hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) reactions of a real gas oil feed under industrial relevant conditions. The results showed a synergetic effect of the Co or Ni sulfide on the ReS{sub 2} in both HDS and HDN reactions. A maximum in activity at the same atomic ratio {alpha} circa 0.5 was observed for both reactions and both Co-Re and Ni-Re catalysts. The magnitude of the synergy was generally superior for HDS than for HDN, and at low reaction temperature (598K) larger for Ni-Re than for Co-Re catalysts, especially in HDS, while at high temperature (648K) it was reverse. Moreover, the Co-Re catalysts exhibited higher HDN/HDS selectivity than the Ni-Re catalysts. Neither XRD nor XPS results evidenced the presence of a Co-Re-S or Ni-Re-S like phase. It is suggested that the synergism could be associated to the hydrogen activation and spillover from the Co or Ni sulfide to ReS{sub 2}.

  17. SBA-15 Mesoporous Silica as Catalytic Support for Hydrodesulfurization Catalysts—Review

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    Eric M. Rivera-Muñoz


    Full Text Available SBA-15 is an interesting mesoporous silica material having highly ordered nanopores and a large surface area, which is widely employed as catalyst supports, absorbents, drug delivery materials, etc. Since it has a lack of functionality, heteroatoms and organic functional groups have been incorporated by direct or post-synthesis methods in order to modify their functionality. The aim of this article is to review the state-of-the-art related to the use of SBA-15-based mesoporous systems as supports for hydrodesulfurization (HDS catalysts.

  18. Hydrodesulfurization Properties of Rhodium Phosphide: Comparison with Rhodium Metal and Sulfide Catalysts

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    Hayes, John R.; Bowker, Richard H.; Gaudette, Amy F.; Smith, Mica C.; Moak, Cameron E.; Nam, Charles Y.; Pratum, Thomas K.; Bussell, Mark E.


    Silica-supported rhodium phosphide (Rh2P/SiO2) catalysts were prepared and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), 31P solid-state NMR spectroscopy, X-ray photoelectron spectroscopy (XPS), and chemisorption measurements. XRD and TEM analysis of a 5 wt.% Rh2P/SiO2 catalyst confirmed the presence of well-dispersed Rh2P crystallites on the silica support having an average crystallite size of 10 nm. NMR spectroscopy showed unsupported and silica-supported Rh2P to be metallic and XPS spectroscopy yielded a surface composition of Rh1.94P1.00 that is similar to that expected from the bulk stoichiometry. The 5 wt.% Rh2P/SiO2 catalyst exhibited a higher dibenzothiophene (DBT) hydrodesulfurization (HDS) activity than did Rh/SiO2 and sulfided Rh/SiO2 catalysts having a similar Rh loading and was also more active than a commercial NiAMo/Al2O3 catalyst. The Rh2P/SiO2 catalyst showed excellent stability over a 100 h DBT HDS activity measurement and was more S tolerant than the Rh/SiO2 catalyst. The Rh2P/SiO2 catalyst strongly favored the hydrogenation pathway for DBT HDS, while the Rh/SiO2 and sulfided Rh/SiO2 catalysts favored the direct desulfurization pathway.

  19. The effect of Co-promotion on MoS2 catalysts for hydrodesulfurization of thiophene: A density functional study

    DEFF Research Database (Denmark)

    Moses, Poul Georg; Hinnemann, Berit; Topsøe, Henrik


    We present density functional theory (DFT) calculations of the hydrogenation (HYD) and direct desulfurization (DDS) pathways of thiophene hydrodesulfurization (HDS) over cobalt-promoted MoS2. We find that the Co–Mo–S edge in its equilibrium state under HDS conditions is reactive toward both...... pathway. We compare our results to available experimental information and find a number of consistencies and parallels. Therefore, we can rationalize the promoting effect of Co such that at the Co–Mo–S edge, good hydrogenation properties are combined with the ability to bind additional sulfur upon C...... hydrogenation and C–S bond scission without the initial creation of vacancies. This can be accomplished such that additional S is bound to the Co–Mo–S subsequent to C–S bond scission and then removed in the final reaction step. We find thus that coordinatively unsaturated sites (CUS) are present...

  20. The Pore Confinement Effect of FDU-12 Mesochannels on MoS2 Active Phases and Their Hydrodesulfurization Performance

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    Cong Liu


    Full Text Available FDU-12 silica with highly ordered face-centered cubic mesoporous structure is developed as support to prepare Mo/FDU-12 catalysts for hydrodesulfurization (HDS of dibenzothiophene (DBT. A series of Mo/FDU-12 catalysts are synthesized by using incipient wetness impregnation method with different MoO3 loadings (6, 8, 10, 12, and 15 wt.%. The objective of this work is to explore the pore confinement effect of FDU-12 mesochannels on the MoS2 morphology with various metal loadings. It is found that, as increasing MoO3 loadings from 6 to 15 wt.%, the MoS2 nanocrystallites transform from monolayer to multilayer and the morphology changes from straight layered to curved and then to ring-like and finally to spherical-like morphology due to the restriction of cage-like pore channels of FDU-12 support. The HDS results show that the catalytic activity increases first and then decreases with the best HDS performance at the MoO3 loading of 10 wt.%. In addition, we compared the HDS activity of Mo catalyst supported on FDU-12 with that on the commercial γ-Al2O3 and SBA-15; the result exhibits that FDU-12 is superior to the other two supports due to its large pore size and ordered three-dimensional open pore channels.

  1. Microkinetic interpretation of HDS/HYDO selectivity of the transformation of a model FCC gasoline over transition metal sulfides

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    Daudin, A. [UMR CNRS 6503, Catalyse en Chimie Organique, Universite de Poitiers, Faculte des Sciences Fondamentales et Appliquees, 40 Avenue du Recteur Pineau, 86022 Poitiers Cedex (France); IFP-Lyon, Direction Catalyse et Separation, BP 3, 69390 Vernaison (France); Lamic, A.F.; Perot, G.; Brunet, S. [UMR CNRS 6503, Catalyse en Chimie Organique, Universite de Poitiers, Faculte des Sciences Fondamentales et Appliquees, 40 Avenue du Recteur Pineau, 86022 Poitiers Cedex (France); Raybaud, P. [IFP, Direction Chimie et Physico-Chimie Appliquees, 1-4 Av. de Bois Preau, 92858 Rueil Malmaison (France); IFP-Lyon, Direction Catalyse et Separation, BP 3, 69390 Vernaison (France); Bouchy, C. [IFP-Lyon, Direction Catalyse et Separation, BP 3, 69390 Vernaison (France)


    The conversion of a model FCC gasoline (composed of 2-methylthiophene (2MT), 2,3-dimethylbut-2-ene (23DMDB2N) and orthoxylene in n-heptane) under realistic hydrodesulfurization (HDS) conditions was investigated over a series of transition monometallic sulfides (Ni{sub 3}S{sub 2}, PdS, Co{sub 9}S{sub 8}, Rh{sub 2}S{sub 3}, RuS{sub 2}, PtS and MoS{sub 2}) and unsupported transition bimetallic sulfide catalysts (NiMoS and CoMoS). The results reveal for the first time that a volcano curve relationship exists between the ab initio calculated sulfur-metal bond energy, E(MS), descriptor of bulk TMS and their activities in olefin hydrogenation and in alkylthiophene desulfurization measured simultaneously. In particular, Rh{sub 2}S{sub 3} with an intermediate sulfur-metal bond energy of 119 kJ/mol is the most active catalyst in both case hydrogenation of the olefin and in HDS of a sulfur compound. Furthermore, the HDS/HYDO selectivity which is the most important parameter in the deep HDS of gasoline, presents a maximum for the NiMoS catalyst with E(MS) of 128 kJ/mol. A microkinetic model based on Broensted-Evans-Polanyi relationships and the competitive adsorption of the sulfur molecule and alkene on the catalytic site is proposed to give a rational interpretation of the experimental catalytic results. (author)

  2. Influence of double promotion on HDS catalysts prepared by urea-matrix combustion synthesis

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    Gonzalez-Cortes, Sergio L. [Laboratorio de Cinetica y Catalisis, Departamento de Quimica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101 (Venezuela); Xiao, Tian-Cun; Lin, Tsung-Wu; Green, Malcolm L.H. [Wolfson Catalysis Centre, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QR (United Kingdom)


    The stringent environmental regulations in the US, Japan and Europe are requiring significant improvement in the quality of transportation fuels. A new strategy based on urea-matrix combustion method for the synthesis of alumina-supported molybdate-based mixed oxides (i.e., bimetallic and trimetallic oxides) has been applied. This permits to control the alumina-mixed oxide interaction and therefore the HDS catalytic behaviour. The oxidic and sulfurized states of the HDS catalysts were characterized by X-ray diffraction (XRD), laser Raman spectroscopy (LRS), temperature-programmed reduction (TPR) and high resolution transmission electron microscopy (HRTEM). Catalyst performance was evaluated using a tubular fixed-bed reactor and the hydrodesulfurization of thiophene under normal pressure as model reaction. It has been found that Ni-promoted alumina-supported MoO{sub 3} catalyst precursor presented a non well-ordered structure of Ni-Mo phase supported on alumina surface. However, when cobalt was added to Ni-Mo precursor the {beta}-isomorph stability was significantly improved and the formation of alumina-supported {beta}-Co{sub 0.5}Ni{sub 0.5}MoO{sub 4} was observed. The activation treatments markedly affect the catalyst structure and hence the HDS catalytic performance. The catalyst series pretreated in H{sub 2}S-H{sub 2} was 2-3 times more active than those C{sub 4}H{sub 4}S-H{sub 2}-pretreated catalysts and ca. 2-10 times more active than the pre-reduced samples. A significantly greater HDS activity of H{sub 2}S-H{sub 2}-pretreated Co{sub 0.5}Mg{sub 0.5}MoS{sub x}/{gamma}-Al{sub 2}O{sub 3} catalyst was observed, which is attributed to the fact that both promoters are into the same network interacting directly with the molybdenum. This feature hinders not only the segregation of cobalt sulfide, but also the formation of long MoS{sub 2} slabs. (author)

  3. Mössbauer Spectroscopy Investigation and Hydrodesulfurization Properties of Iron–nickel Phosphide Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Gaudette, Amy F.; Burns, Autumn W.; Hayes, John R.; Smith, Mica C.; Bowker, Richard H.; Seda, Takele; Bussell, Mark E.


    Unsupported and silica-supported FexNi2-xPy catalysts having a range of metal compositions (0 < x 6 2.0) were investigated using Mössbauer spectroscopy, and the results correlated with the surface and hydrodesulfurization (HDS) properties of the supported catalysts. Mössbauer spectroscopy permits determination of the relative site occupancy of Fe atoms in tetrahedral (M(1)) and pyramidal (M(2)) sites in the FexNi2-xPy materials. Fe atoms preferentially occupy M(2) sites for materials with significant Fe contents (x > ~0.60), but the Fe site preference reverses as the Fe content decreases (x < ~0.60). Similar occupation trends are observed for the unsupported and silica-supported FexNi2-xPy materials. Thiophene HDS measurements of the FexNi2-xPy/SiO2 catalysts revealed catalysts with high Fe contents (0.80 6 x 6 2.00) to have low activities, while the activities of Ni-rich catalysts increased dramatically with increased Ni content (0.03 6 x 6 0.60). The highest HDS activity was measured for a catalyst having a nominal precursor composition of Fe0.03Ni1.97P2.00/SiO2; this catalyst was 40% more active than a optimized nickel phosphide catalyst prepared from a precursor having a nominal composition of Ni2.00P1.60/SiO2. The 25 wt.% Fe0.03Ni1.97P2.00/SiO2 catalyst also had a dibenzothiophene HDS activity just over 10% higher than that of the 25 wt.% Ni2.00P1.60/SiO2 catalyst at 548 K. The trend of increasing HDS activity for the FexNi2-xPy/ SiO2 catalysts correlates with preferential Fe occupation of M(1) sites (and, therefore, Ni occupation of M(2) sites). Supported by X-ray photoelectron spectroscopy and oxygen chemisorption measurements, we conclude that the high activity of Ni-rich FexNi2-xPy/SiO2 catalysts can be traced to a high surface density of Ni in M(2) sites that are resistant to site blockage due to S incorporation.

  4. Simultaneous hydrodesulfurization, hydrodenitrogenation, hydrogenolysis and hydrogenation over MoS{sub 2}-based catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Wang, W.; Wei, B.; Song, C.


    Simultaneous hydrodesulfurization (HDS), hydrodenitrogenation (HDN), hydrogenolysis (HYC) and hydrogenation (HYG) of model compounds were studied under high pressure with MoS{sub 2}-based catalysts. Such reactions are related to conversion of coal, heavy oil and resid as well as waste materials. Three metal sulfide catalysts have been examined, including dispersed MoS{sub 2} catalyst derived in-situ from ammonium tetrathiomolybdate [ATTM, (NH{sub 4}){sub 2}MoS{sub 4}] and sulfided Co-Mo/Al{sub 2}O{sub 3} (CR-344) and Ni-Mo/Al{sub 2}O{sub 3} (CR-424) catalysts from Criterion. In order to investigate the catalytic functions of these catalysts and the influence of co-reactants, five model compounds were examined both as individual reactants and as 5-component mixture in this work, including (1) 4-(1-naphthylmethyl)bibenzyl (100%), abbreviated as NMBB, (2) pyrene (99%), (3) dibenzothiophene (98%), abbreviated as DBT, (4) quinoline (99%), and (5) eicosane (99%). The experiments with 5-component mixture showed that the patterns of product distributions strongly depend on the type of catalysts, and the trends do not always parallel with those for single-component tests, indicating the influence of co-reactants. In general, pyrene and eicosane were hardest to convert in the mixtures. The dispersed MoS{sub 2} catalyst (ATTM as precursor) showed higher capabilities on HDN and hydrogenation of pyrene, but lower HDS/conversion of DBT. Compared with the other two catalysts, CR-424 was much more active for NMBB conversion than for pyrene conversion. Overall, CR-424 catalyst appears to be the most effective on HDS, HDN and on hydrogenolysis of C-C bond in NMBB.

  5. Effect of Mo and Co loading in HDS catalysts supported on solvo-thermally treated ZrO{sub 2}-TiO{sub 2} mixed oxides

    Energy Technology Data Exchange (ETDEWEB)

    Escobar, Jose; Cortes, Maria A. [Instituto Mexicano del Petroleo, Prog. de Ing. Molecular, Eje Central Lazaro Cardenas 152, Col. San Bartolo Atepehuacan, Gustavo A. Madero, Mexico, D.F. 07730 (Mexico); Barrera, Maria C. [Instituto Mexicano del Petroleo, Prog. de Ing. Molecular, Eje Central Lazaro Cardenas 152, Col. San Bartolo Atepehuacan, Gustavo A. Madero, Mexico, D.F. 07730 (Mexico); Universidad Autonoma Metropolitana-Iztapalapa, San Rafael Atlixco 186, Col. Vicentina, Iztapalapa, Mexico, D.F. 09340 (Mexico); Reyes, Jose A. De Los [Universidad Autonoma Metropolitana-Iztapalapa, San Rafael Atlixco 186, Col. Vicentina, Iztapalapa, Mexico, D.F. 09340 (Mexico); Santes, Victor [CIIEMAD-IPN, Calle 30 de Junio de 1520, Col. Barrio la Laguna Ticoman, Gustavo A. Madero, Mexico, D.F. 07340 (Mexico); Gomez, Elizabeth [Instituto de Quimica-UNAM, Circuito Exterior, Ciudad Universitaria, Mexico, D.F. 04510 (Mexico); Pacheco, Jose G. [Division Academica de Ciencias Basicas, Universidad Juarez Autonoma de Tabasco, Km. 1, Carretera Cunduacan-Jalpa de Mendez, Cunduacan, Tabasco (Mexico)


    Molybdenum (at 2.8, 3.3, 4.0 and 4.7 atoms nm{sup -2}) and cobalt (Co/(Co + Mo) ratios of 0.3, 0.4 and 0.5) were impregnated on wide-pore ZrO{sub 2}-TiO{sub 2} mixed oxides (30-70) prepared with solvo-thermal treatment (80 C, 1 day). Materials characterization comprised N{sub 2} physisorption, XRD, thermal analyses, and UV-vis DRS, Raman, and IR spectroscopies. For impregnated dried materials (non-calcined) at concentrations beyond 3.3 atom nm{sup -2} and activated by sulfiding (H{sub 2}S/H{sub 2}, 400 C) no further improvement in activity in dibenzothiophene (DBT) hydrodesulfurization (HDS) (at 5.59 MPa, T = 320 C) was observed. Thus, monolayer Mo dispersion was assumed at that content. The aforementioned formulation was chosen to be promoted by Co at different concentrations, the maximum HDS activity being found for sulfided catalyst with Co/(Co + Mo) = 0.4. Nevertheless, the promotion observed by Co addition was small (by a factor of {proportional_to}3.2). The activity trends observed in the DBT HDS were well confirmed in the hydrotreatment of a real feedstock (straight-run gasoil). Dibenzothiophene reliably represented the behavior of organo-sulfur compounds present in the middle distillate, at the reaction conditions used in this study where sterically hindered compounds remained unreacted in the hydrotreated gasoil. (author)

  6. Derivation of elastic stiffness formula for leaf type HDS and conceptual design of leaf type HDS of SMART FA

    Energy Technology Data Exchange (ETDEWEB)

    Song, Kee Nam; Kang, Heung Seok; Yoon, Kyung Ho; Suh, Jung Min; Lee, Jin Seok


    Based on the strain energy method and Euler beam theory, an elastic stiffness formula for the leaf type HDS, now widely used as the holddown spring for the FA of Westinghouse type PWRs, has been derived. Through comparisons with the characteristic test results of the test produced HDSs, it has been found that the derived formula is useful to reliably estimate an elastic stiffness with material properties and the geometric data of an HDS. Through sensitivity analysis of HDS`s elastic stiffness, the elastic stiffness sensitivity with respect to different design variables was identified, as well as the design variables having remarkable sensitivity. In addition, finite element analysis using surface-to-surface contact elements on the contact surface between the leaves shows that the analysis results are in good agreement with the elastic stiffness determined from the derived formula. It is therefore expected that the finite element model and the analysis method will be useful in the analysis of the elasto-plastic behavior of the leaf type HDS in the future. To both reduce the cobalt content, which is considered to be the source of radioactive contamination in the reactor core, and to design the HDS to meet the holddown requirements of the SMART FA, a conceptual design for the HDS of the SMART FA has been performed through two analyses of the elastic characteristics of the HDS : the possibility of substitution of the leaf spring`s material from Inconel 718 to Zircaloy and the effects on the HDS`s elastic characteristics according to the variation of leaf thickness and the number of leaves composing the HDS. (author). 34 refs., 33 tabs., 37 figs.

  7. Thiophene hydrodesulfurization over CoMo/Al2O3-CuY catalysts: Temperature effect study

    Directory of Open Access Journals (Sweden)

    Yamina Boukoberine


    Full Text Available CoMo/γ-Al2O3-CuY catalysts are prepared by physically mixing CoMo/γ-Al2O3 catalyst with Cu-exchanged Y zeolite. The CuY zeolite is prepared by the solid state ion exchange technique. The thiophene hydrodesulfurization is performed in a fixed bed reactor at high temperature and atmospheric pressure. The results show that the presence of CuY zeolite particles in CoMo/Al2O3 catalyst can have a noticeable effect on both the conversion and product selectivities. An increasing zeolite loading in catalyst results in a decrease of the thiophene HDS activity. This decrease is probably caused by the formation of heavy compounds and the deactivation of the zeolite at high temperatures.

  8. Monometallic Pd and Pt and Bimetallic Pd-Pt/Al2O3-TiO2 for the HDS of DBT: Effect of the Pd and Pt Incorporation Method

    Directory of Open Access Journals (Sweden)

    Reynaldo Martínez Guerrero


    Full Text Available The effect of the preparation method of monometallic Pd and Pt and bimetallic Pd-Pt/Al2O3-TiO2 catalysts on the hydrodesulfurization (HDS of dibenzothiophene (DBT was investigated in this study. The synthesis was accomplished using three methods: (A impregnation, (B metal organic chemical vapor deposition (MOCVD, and (C impregnation-MOCVD. The bimetallic Pd-Pt catalyst prepared by the impregnation-MOCVD method was most active for the HDS of DBT compared to those prepared by the single impregnation or MOCVD method due to the synergetic effect between both noble metals. The greater selectivity toward biphenyl indicated that this bimetallic Pd-Pt catalyst preferentially removes sulfur via the direct desulfurization mechanism. However, the bimetallic Pd-Pt catalyst prepared using the single MOCVD method did not produce any cyclohexylbenzene, which is most likely associated with the hydrogenation/dehydrogenation sites.

  9. Effects of chelating agents as additives on preparation of Co-Mo hydrodesulfurization catalysts. Effect of NTA (Nitrilotriacetic acid) addition on hydrodesulfurization activity and surface composition; Co-Mo kei datsuryu shokubai choseiji ni okeru kiretozai no tenka koka. Datsuryu kassei to hyomen sosei ni taisuru NTA (nitoriro sansakusan) no tenka koka

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, T.; Kasahara, S.; Kiyohara, T.; Kawahara, K.; Yamada, M. [Tohoku University, Sendai (Japan). Faculty of Engineering


    Co-Mo/Al2O3 catalysts prepared by an impregnation method using NTA (nitrilotriacetic acid) as a chelating agent, were used to test the hydrodesulfurization (HDS) activity of benzothiophene and to observe the effect of XPS (X-ray photoelectron spectroscopy). The NTA-added catalysts showed ca. 20% higher HDS activity than that of conventional catalysts. The result of the activity test as a function of Co/Mo ratio suggested that the same highly active sites were formed when Co/Mo ratio (atom/atom) was less than ca. 0.3, and above 0.3 less active Co species was formed. It was also suggested that NTA contributed to the formation and to increasing the number of highly alive sites. When the NTA-added catalysts were calcined before sulfidation, the increment of HDS acidity was reduced by half. XPS measurements for catalyst precursors (before sulfidation) revealed that, when they were not calcined, the Co concentration at the surface of the catalysts prepared by the NTA method was higher than that of the conventionally prepared catalysts. Accordingly, it was suggested that NTA has a role of increasing Co surface density; thus, increasing the catalytic activity. 18 refs., 7 figs., 1 tab.


    Directory of Open Access Journals (Sweden)

    Usman Usman


    Full Text Available The effect of boron addition was studied on the hydrodesulfurization (HDS of thiophene over Co-MoS2/B/Al2O3 (CVD-Co/MoS2/B/Al2O3, which was prepared by a CVD technique using Co(CO3NO as a precursor of Co. The catalyst was characterized by means of NO adsorption, XPS, Raman Spectroscopy, FTIR, and TEM. The HDS activity of CVD-Co/MoS2/B/Al2O3 catalyst increased as the boron content increased up to about 0.6 and 1.2 wt% B for the catalyst presulfided at 673 and 773 K respectively, followed by a decrease with a further addition of boron loading. In spite of the activity increase, the amount of NO adsorption on MoS2/B/Al2O3 steadily decreased with increasing boron loading, suggesting that the dispersion of MoS2 particles is decreased by the addition of boron. Selective formation of the CoMoS phase on CVD-Co/MoS2/B/Al2O3 was achieved by the CVD technique. The TOF of the HDS over the CVD-Co/MoS2/B/Al2O3 catalyst, defined by the activity per Co atom forming the CoMoS phase, increased as high as 1.6 and 1.9 times for the catalyst presulfided at 673 and 773 K, respectively. It is concluded that the addition of boron weakens the interaction between Mo oxides and Al2O3 surface, promoting the formation of the so called Co-Mo-S ";;;pseudo";;; type II over CVD-Co/MoS2/B/Al2O3 presulfided at 673 K. The Co-Mo-S ";;;pseudo";;; type II is a metastable phase with the TOF value intermediate between Co-Mo-S type I and type II. With CVD-Co/MoS2/B/Al2O3 presulfided at 773 K, the addition of boron promotes the formation of ";;;real";;; Co-Mo-S type II, possibly by the formation of well-crystallized MoS2 structure. Keywords: Hydrodesulfurization; Co-Mo sulfide catalysts; Effect of boron addition; CVD technique; Turnover frequency

  11. Revamping of diesel hydrodesulfurizers. Options available and future research needs

    Energy Technology Data Exchange (ETDEWEB)

    Bej, Shyamal K. [Department of Chemical Engineering, University of Michigan, 3230 H.H. Dow Building, 2300 Hayward Avenue, Ann Arbor, MI 48109 (United States)


    The legislative pressure is being increased to reduce maximum allowable sulfur content in diesel to 50 wppm and lower. Existing hydrodesulfurizers currently reducing sulfur level to 500 wppm will not be able to meet this future requirement. Some improvements can be made in these existing units by switching over to new generation of catalysts and changing the levels of various process variables. Installation of a second reactor to accommodate additional catalyst volume will probably be inevitable for meeting this requirement of new sulfur specification. In this article, the various issues related to the second reactor, such as selection of a proper catalyst, optimum level of process conditions, location and operating mode of the reactor are discussed. Various process configurations based on the location of the second reactor have been analyzed. Different options for operating the second reactor under a lean atmosphere of H{sub 2}S have also been discussed. All these process configurations differ in terms of capital investment, operating cost and desulfurization efficiencies. Future studies are required to take the optimum decision.

  12. Ultrasound assisted synthesis and physicochemical characterizations of fluorine-modified CoMo/Al2O3 nanocatalysts used for hydrodesulfurization of thiophene. (United States)

    Ebrahimynejad, Mitra; Haghighi, Mohammad; Asgari, Nazli


    A series of CoMo/F-Al2O3 nanocatalysts with different fluorine loadings of 0, 0.4, 0.8 and 1 wt% were successfully synthesized by a sonochemical method and used for catalytic hydrodesulfurization (HDS) of thiophene. The nanocatalysts were characterized with X-ray diffraction analysis (XRD), Field Emission Scanning Electron Microscopy (FESEM), BET nitrogen adsorption Brunauer-Emmett-Teller (BET) analysis, Fourier Transform Infrared Spectroscopy (FTIR) and temperature programmed desorption of ammonia (TPD-NH3) techniques. The XRD results showed a high dispersion of the molybdenum species on the γ-Al2O3 support due to the application of sonochemical method along with fluorine addition. The CoMo/F-Al2O3 nanocatalysts had a particle size less than 100 nm. The specific surface area of the samples was slightly decreased with increasing the fluorine content. The FTIR results confirmed that with the increase of fluorine amount in the CoMo/Al2O3 nanocatalysts, it would generate more active sites. Moreover, the TPD results showed that the fluorinated nanocatalysts had higher acidity than the promoter-free nanocatalysts, because of the formation of new strong acid sites on the γ-Al2O3 support by the promoter. The catalytic activity for thiophene HDS reaction was investigated in a stirred slurry-tank reactor in the atmospheric pressure to determine the effect of fluorine amount on the nanocatalyst performance. The results of thiophene HDS reaction showed that the fluorinated nanocatalysts were more active than fluorine-free nanocatalysts and consequently, they were able to remove nearly 100% of thiophene in the initial solution. Furthermore, the nanocatalyst with the fluorine content of 0.8 wt% had the highest activity in HDS of thiophene. However, further addition of fluorine led to decrease in catalytic activity which could be attributed to the agglomerated particles formed on the nanocatalyst surface.

  13. High Active Zn/Mg-Modified Ni–P/Al2O3 Catalysts Derived from ZnMgNiAl Layered Double Hydroxides for Hydrodesulfurization of Dibenzothiophene

    Directory of Open Access Journals (Sweden)

    Feng Li


    Full Text Available A series of ZnMgNiAl layered double hydroxides (LDHs containing 20 wt.% Ni and different Zn/Mg molar ratios were prepared by a coprecipitation method, and then were introduced with H2PO4− via a microwave-hydrothermal method. With the resulting mixtures as the precursors, Zn/Mg-modified ZnMgNi–P/Al2O3 catalysts were prepared. The Zn/Mg molar ratio affected the formation of Ni2P and Ni12P5 in nickel phosphides. The ZnMgNi–P/Al2O3 catalyst with a Zn/Mg molar ratio of 3:1 exhibits the best dibenzothiophene hydrodesulfurization (HDS activity. Compared with the Ni–P/Al2O3 catalyst prepared from the impregnation method, the ZnMgNi–P/Al2O3 catalyst shows a higher HDS activity (81.6% vs. 54.3% and promotes the direct desulfurization of dibenzothiophene.

  14. Enabling Ultra Deep Hydrodesulfurization by Nanoscale Engineering of New Catalysts

    DEFF Research Database (Denmark)

    Christoffersen, Ann-Louise Nygård

    to the adverse environmental and societal effects of sulfur emissions from on-road transportation, legislation has been continuously tightened, pushing oil refiners to produce ultra-low sulfur diesel (ULSD), with a maximum sulfur content of 15 ppm. Since these specifications are expected to be further tightened......, the existing HDS catalysts fall short. Experiments were performed on a setup dedicated to testing minute amounts of well-defined catalytic systems in the ambient pressure gas phase HDS of the model compounds dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT). An existing µ-reactor platform...

  15. Low-Dimensional ReS2/C Composite as Effective Hydrodesulfurization Catalyst

    Directory of Open Access Journals (Sweden)

    Juan Antonio Aliaga


    Full Text Available Single-layer, ultrasmall ReS2 nanoplates embedded in amorphous carbon were synthesized from a hydrothermal treatment involving ammonium perrhenate, thiourea, tetraoctylammonium bromide, and further annealing. The rhenium disulfide, obtained as a low dimensional carbon composite (ReS2/C, was tested in the hydrodesulfurization of light hydrocarbons, using 3-methylthiophene as the model molecule, and showed enhanced catalytic activity in comparison with a sulfide CoMo/γ-Al2O3 catalyst. The ReS2/C composite was characterized by X-ray diffraction (XRD, Raman spectroscopy, N2 adsorption–desorption isotherms, scanning electron microscopy (SEM, scanning transmission electron microscopy (STEM, energy-dispersive X-ray spectroscopy (EDS, and X-ray photoelectron spectroscopy (XPS. The improved catalytic performance of this ReS2/C composite may be ascribed to the presence of a non-stoichiometric sulfur species (ReS2−x, the absence of stacking along the c-axis, and the ultra-small basal planes, which offer a higher proportion of structural sulfur defects at the edge of the layers, known as a critical parameter for hydrodesulfurization catalytic processes.

  16. Effects of chelating agents as additives on preparation of Co-Mo hydrodesulfurization catalysts. Part 2. Effect of nitrilotriacetic acid addition on surface structure; Co-Mo kei datsuryushokubai choseiji ni okeru chelate zai no tenka koka. 2. Hyomen kozo ni oyobosu nitrilo san sakusan tenka no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, T.; Kiyohara, T.; Hiroshima, K.; Yamada, M. [Tohoku University, Sendai (Japan). Faculty of Engineering


    For the purpose of uncovering the cause of increased hydrodesulfurization (HDS) activity of Co-Mo/Al2O3 by the addition of nitrilotriacetic acid (NTA), the effects of order in adding NTA and the amount thereof on benzothiophene (BT) HDS activity were investigated. Effects of pretreatment condition were also studied, and it appeared that NTA did nor affect the optimum pretreatment condition. From the view of the surface structure, XPS was measured for the catalyst precursors, Mo EXAFS, FT-IR of adsorbed nitric oxide (NO), and the amount of NO adsorbed were measured for the sulfided catalysts, respectively. The XP spectra showed some concentration of Co at the surface of the catalyst precursor prepared with NTA. From the result of Mo EXAFS, it was thought that, when NTA was added during preparation, the growth of MoS2-like crystallite or the extent of crystallization was promoted. The IR spectra of NO adsorbed on sulfided catalysts showed that the adsorbed NO was mainly located on Co site. It was hence suggested that the addition of NTA promoted the coverage of Mo site with Co, and that the Co might have contributed toward the high HDS activity. The amount of NO adsorbed was found smaller for NTA-added catalyst than for the one prepared without NTA. Since the BT HDS activity was higher for NTA-added catalyst, it was thought that the addition of NTA might have promoted the formation of highly active sites. 14 refs., 7 figs., 3 tabs.

  17. Catalytic activities of Co(Ni)Mo/TiO{sub 2}-Al{sub 2}O{sub 3} catalysts in gasoil and thiophene HDS and pyridine HDN: effect of the TiO{sub 2}-Al{sub 2}O{sub 3} composition

    Energy Technology Data Exchange (ETDEWEB)

    Borque, M.P.; Lopez-Agudo, A. [Instituto de Catalisis y Petroleoquimica, CSIC, Cantoblanco, 28049 Madrid (Spain); Olguin, E.; Vrinat, M. [Institut de Recherches sur la Catalyse, 2 avenue Albert Einstein, 69626 Villeurbanne Cedex (France); Cedeno, L.; Ramirez, J. [Unicat, Facultad de Quimica UNAM, Cd. Universitaria, 04510 Mexico DF (Mexico)


    The effect of the TiO{sub 2}-Al{sub 2}O{sub 3} mixed oxide support composition on the hydrodesulfurization (HDS) of gasoil and the simultaneous HDS and hydrodenitrogenation (HDN) of gasoil+pyridine was studied over two series of CoMo and NiMo catalysts. The intrinsic activities for gasoil HDS and pyridine HDN were significantly increased by increasing the amount of TiO{sub 2} into the support, and particularly over rich- and pure-TiO{sub 2}-based catalysts. It is suggested that the increase in activity be due to an improvement in reducing and sulfiding of molybdena over TiO{sub 2}. The inhibiting effect of pyridine on gasoil HDS was found to be similar for all the catalysts, i.e., was independent of the support composition. The ranking of the catalysts for the gasoil HDS test differed from that obtained for the thiophene test at different hydrogen pressures. In the case of gasoil HDS, the activity increases with TiO{sub 2} content and large differences are observed between the catalysts supported on pure Al{sub 2}O{sub 3} and pure TiO{sub 2}. In contrast, in the case of the thiophene test, the pure Al{sub 2}O{sub 3}-based catalyst appeared relatively more active than the catalysts supported on mixed oxides. Also, in the thiophene test the difference in intrinsic activity between the pure Al{sub 2}O{sub 3}-based catalyst appeared relatively more active than the catalysts supported on mixed oxides. Also in the thiophene test, the difference in intrinsic activity between the pure Al{sub 2}O{sub 3}- and pure TiO{sub 2}-based catalysts is relatively small and dependent on the H{sub 2} pressure used. Such differences in activity trend among the gasoil and the thiophene tests are due to a different sensitivity of the catalysts (by different support or promoter) to the experimental conditions used. The results of the effect of the H{sub 2} partial pressure on the thiophene HDS, and on the effect of H{sub 2}S concentration on gasoil HDS demonstrate the importance of these

  18. Clinical and laboratory features of neuropathies with serum IgM binding to TS-HDS. (United States)

    Pestronk, Alan; Schmidt, Robert E; Choksi, Rati M; Sommerville, R Brian; Al-Lozi, Muhammad T


    In this investigation we studied clinical and laboratory features of polyneuropathies in patients with serum IgM binding to the trisulfated disaccharide IdoA2S-GlcNS-6S (TS-HDS). We retrospectively compared 58 patients with selective IgM binding to TS-HDS to 41 consecutive patients with polyneuropathies without TS-HDS binding. Patients with IgM vs. TS-HDS commonly had distal, sensory, axonal neuropathies. Weakness was associated with IgM M-proteins. Hand pain and serum IgM M-proteins were more common than in control neuropathy patients. TS-HDS antibody binding was often selectively κ class. Biopsies showed capillary pathology with thickened basal lamina and C5b9 complement deposition. IgM in sera with TS-HDS antibodies often bound to capillaries. Serum IgM binding to TS-HDS is associated with painful, sensory > motor, polyneuropathies with an increased frequency of persistent hand discomfort, serum IgM M-proteins, and capillary pathology. Serum IgM binding to TS-HDS suggests a possible immune etiology underlying some otherwise idiopathic sensory polyneuropathies. Copyright © 2011 Wiley Periodicals, Inc.

  19. Theoretical Studies in Heterogenous Catalysis: Towards a Rational Design of Novel Catalysts for Hydrodesulfurization and Hydrogen Production

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez,J.A.; Liu, P.


    important advantage of the cluster approach is that one can use the whole spectrum of quantum-chemical methods developed for small molecules with relatively minor modifications. On the other hand, the numerical effort involved in cluster calculations increases rather quickly with the size of the cluster. This problem does not exist when using slab models. Due to the explicit incorporation of the periodicity of the crystal lattice through the Bloch theorem, the actual dimension of a slab calculation depends only on the size of the unit cell. In practical terms, the slab approach is mainly useful for investigating the behavior of adsorbates at medium and high coverages. Very large unit cells are required at the limit of low to zero coverage, or when examining the properties and chemical behavior of isolated defect sites in a surface. In these cases, from a computational viewpoint, the cluster approach can be much more cost effective than the slab approach. Slab and cluster calculations can be performed at different levels of sophistication: semi-empirical methods, simple ab initio Hartree-Fock, ab initio post-Hartree-Fock (CI, MP2, etc), and density functional theory. Density-functional (DF) based calculations frequently give adsorption geometries with a high degree of accuracy and predict reliable trends for the energetics of adsorption reactions. This article provides a review of recent theoretical studies that deal with the behavior of novel catalysts used for hydrodesulfurization (HDS) reactions and the production of hydrogen (i.e. catalytic processes employed in the generation of clean fuels). These studies involve a strong coupling of theory and experiment. A significant fraction of the review is focused on the importance of size-effects and correlations between the electronic and chemical properties of catalytic materials. The article begins with a discussion of results for the desulfurization of thiophene on metal carbides and phosphides, systems which have the

  20. Texture of Mo-containing hydrodesulfurization catalysts on different supports

    Energy Technology Data Exchange (ETDEWEB)

    Krasnopol' skaya, S.M.; Lur' e, M.A.; Kurets, I.Z.; Rak, V.S.; Belyaeva, V.A.; Shmidt, F.K.


    The thermal desorption of nitrogen was used to investigate the texture of molybdenum-containing hydrodesulfurization catalysts, synthesized on the basis of ..gamma..-Al/sub 2/O/sub 3/ and a genetic mixture of mountain cork (palygorskite) and montmorillonite. Their activity in the hydrogenolysis of thiophene has been determined. It has been shown that in the preparation of the oxide or sulfide forms the texture of the contact, containing the natural support, changes more strongly than that based on aluminum oxide. Elimination of the oxidizing calcination stage produces sulfide forms of the catalysts with a larger specific surface, porosity, and higher catalytic activity. A stronger effect is obtained on the natural support.


    Directory of Open Access Journals (Sweden)

    Subagjo Subagjo


    Full Text Available Evaluasi kinetika reaksi hidrodesulfurisasi (HDS dibenzothiophene dan simulasi nafta hydrotreater yang berada di PT. PERTAMINA Refinery Unit II Dumai menggunakan katalis NiMo/Al2O3 hasil pengembangan telah dilakukan. Kinetika reaksi HDS DBT dilakukan dalan sistem reaktor batch dengan variasi temperatur 280-320oC dan tekanan 30 bar. Data kinetika diolah dengan persamaan hukum pangkat (law power dan persamaan kinetik mekanistik (Langmuir Hinshelwood, LH. Berdasarkan model hukum pangkat, kinetika HDS DBT menggunakan NiMo/Al2O3 hasil pengembangan merupakan  orde satu  terhadap DBT dengan konstanta Arhenius  sebesar 165633 detik-1 dan energi aktivasi 69017 J/mol (16,56 kkal/mol. Model LH yang cocok untuk reaksi HDS DBT menggunakan NiMo/Al2O3 hasil pengembangan adalah model LH yang mengilustrasikan adanya kompetisi antara reaktan DBT dan H2 pada tipe pusat aktif yang sama, dengan DBT teradsorb secara kuat sedangkan H2 teradsorpsi secara lemah. Energi aktifasi dan konstanta Arhenius berdasarkan model LH ini ini berturut-turut adalah 81409 J/mol (19,34 kkal/mol dan 1658133 s-1. Dengan menggunakan persamaan laju reaksi hukum pangkat, model memberikan hasil konversi sulfur yang sama dengan hasil keluaran reaktor nafta hydrotreater RU II-Dumai, yaitu mencapai 98%.

  2. Effects of pH and chelating agent on the NiWS phase formation in NiW/γ-Al{sub 2}O{sub 3} HDS catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Santolalla-Vargas, C.E.; Suárez Toriello, V.A. [Universidad A. Metropolitana-Iztapalapa, Área de Ingeniería Química, Av. FFCC R, Atlixco 186, Vicentina, 09340 Distrito Federal (Mexico); Reyes, J.A. dos, E-mail: [Universidad A. Metropolitana-Iztapalapa, Área de Ingeniería Química, Av. FFCC R, Atlixco 186, Vicentina, 09340 Distrito Federal (Mexico); Cromwell, D.K. [University of New Hampshire, Department of Chemical Engineering, 207 Thompson Hall, Durham, NH 03824 (United States); Pawelec, B.; Fierro, J.L.G. [Instituto de Catálisis y Petroleoquímica, CSIC, Cantoblanco, E-28049, Madrid (Spain)


    In this article, NiW/γ-Al{sub 2}O{sub 3} samples were prepared by consecutive impregnations of a W/γ-Al{sub 2}O{sub 3}-based catalyst with aqueous solution of nickel salt. The structural control of the nickel ion precursor in the impregnation solution was achieved by the addition of 1,2-cyclohexanediamine-N,N,N′,N′-tetraacetic acid (CyDTA) as a chelating agent. The influence of pH of this aqueous solution on the NiWS phase formation in the sulfided catalysts was investigated. Coordination structures of the Ni–CyDTA complexes were evaluated by FT-IR and DRS UV–Vis spectroscopies. Sulfided catalysts were characterized by X-ray photoelectron spectroscopy (XPS) and high resolution transmission electron microscopy (HRTEM) and tested in hydrodesulfurization (HDS) of 4,6-dimethyldibenzothiophene (4,6-DMDBT) carried out in a batch reactor at 593 K and total H{sub 2} pressure of 55 bar. Spectroscopic characterization by DRS UV–Vis showed the predominance of the [Ni(CyDTA)]{sup 2−} species in solution. Following the impregnation and drying steps, the [Ni(CyDTA)]{sup 2−} complex showed no apparent changes of its structure, independent of the pH value of impregnation solution. The Ni/W/γ-Al{sub 2}O{sub 3} catalysts ex [Ni(CyDTA)]{sup 2−} complex exhibited high stability. The presence of CyDTA delayed the reduction of Ni and caused a remarkable decrease of the W-support interaction, thus increasing the formation of NiWS phase upon catalyst sulfiding. The catalyst activity–structure correlation demonstrated that the catalyst activity and selectivity is linked with formation of the most active NiWS phase having single or double WS{sub 2} slab structures. The catalyst prepared with [Ni(CyDTA)]{sup 2−} complex at pH of 4.0 exhibited the largest initial HDS activity, which was approximately triple compared with the CyDTA-free counterpart. For all catalysts, the HDS reaction proceeded via hydrogenation (HYD) and direct desulfurization (DDS) reaction routes

  3. Comparison of air and water quenching of HDS slugs

    Energy Technology Data Exchange (ETDEWEB)

    Burk, J.A.


    This memorandum recommends the use of water quenching, rather than air quenching, for pressed slugs in any future project to substantially update the Building 313-M slug manufacturing facility. At the outset of the recently canceled Project S-4092, Improved Slug Processing Facility (ISPF), 313-M, consensus of the SRP liaison team was to replace the existing water quench facility with air quenching. Principal motivations were to eliminate a liquid waste stream, reduce the quantity of process water used, and attain a more reliable mechanical system. During the ensuing years, unforeseen difficulties with air quenching have been realized. Also, effective methods of reducing and treating the waste streams generated by water quenching have been developed. Both methods the author believes will work. However, the propriety of either method of quenching is a function of the system into which it is being incorporated. Each method carried with it a lot of concealed constraint s and carefully designed additional equipment. There is today a consensus that water quenching is preferable. For future reference, some advantages and disadvantages of the two quenching methods are discussed.

  4. Brazilian experience using high-dose sequential therapy (HDS) followed by autologous hematopoietic stem cell transplantation (ASCT) for malignant lymphomas


    Souza,Cármino A.; Pagnano, Kátia B. B.; Lorand-Metze,Irene; Eliana C.M. Miranda; Baldissera, Renata; Aranha, Francisco J. P.; Afonso C. Vigorito; Duarte, Bruno K. L.


    Using the overall survival (OS), disease free survival (DFS) and progression free survival (PFS), as well as associated toxicity, the purpose of this work was to evaluate the effectiveness of HDS followed by ASCT as salvage therapy. A retrospective analysis was performed of 106 patients with high grade non-Hodgkin lymphoma receiving HDS followed by ASCT, between 1998 and 2006. Median age was 45 years (Range: 8-65), with 66 (62%) men. Histopathological classification was: 78% DLBCL patients, 1...

  5. Developing Enzyme and Biomimetic Catalysts for Upgrading Heavy Crudes via Biological Hydrogenation and Hydrodesulfurization

    Energy Technology Data Exchange (ETDEWEB)

    Borole, A P


    The recovery and conversion of heavy oils is limited due to the high viscosity of these crudes and their high heteroatom content. Conventional technology relies on thermochemical hydrogenation and hydrodesulfurization to address these problems and is energy intensive due to the high operating temperature and pressure. This project was initiated to explore biological catalysts for adding hydrogen to the heavy oil molecules. Biological enzymes are efficient at hydrogen splitting at very mild conditions such as room temperature and pressure, however, they are very specific in terms of the substrates they hydrogenate. The goal of the project was to investigate how the specificity of these enzymes can be altered to develop catalysts for oil upgrading. Three approaches were used. First was to perform chemical modification of the enzyme surface to improve binding of other non-natural substrates. Second approach was to expose the deeply buried catalytic active site of the enzyme by removal of protein scaffolding to enable better interaction with other substrates. The third approach was based on molecular biology to develop genetically engineered systems for enabling targeted structural changes in the enzyme. The first approach was found to be limited in success due to the non-specificity of the chemical modification and inability to target the region near the active site or the site of substrate binding. The second approach produced a smaller catalyst capable of catalyzing hydrogen splitting, however, further experimentation is needed to address reproducibility and stability issues. The third approach which targeted cloning of hydrogenase in alternate hosts demonstrated progress, although further work is necessary to complete the cloning process. The complex nature of the hydrogenase enzyme structure-function relationship and role of various ligands in the protein require significant more research to better understand the enzyme and to enable success in strategies in

  6. Cobalt Chemical Vapor Deposition Process on Molybdenite Basal Plane Observed by Ultrahigh-Vacuum Scanning Tunneling Microscopy (United States)

    Komiyama, Masaharu; Kiyohara, Kohei; Yoda, Eisuke; Kubota, Takeshi; Okamoto, Yasuaki


    The processes of high-temperature (473 K) resulfidation and cobalt carbonyl adsorption by chemical vapor deposition (CVD) on a cleaved basal plane of a natural molybdenite (MoS2) single crystal were examined by ultrahigh-vacuum scanning tunneling microscopy (UHV-STM) on the nanometer scale. The resulfided cleaved molybdenite basal plane showed a displacement of upper terraces, and a sinusoidal structure at step edges, both of which may be caused by the electronic effect at the surface. Cobalt carbonyl appeared to be adsorbed at both the S- and Mo-terminated edges, resulting in an agglomeration at the step edges on lower terraces with a width of a few tens of nanometers. When this surface with adsorbed carbonyl was sulfided at 513 K for 1 h, most of the adsorbed carbonyl clusters appeared to be desorbed while a small part were dispersed on the terraces in small clusters of 10-20 nm in size. The obtained results are discussed in terms of the preparation of Co-Mo hydrodesulfurization (HDS) catalysts.

  7. Application of datamining method (ID3) to data analysis for ultra deep hydrodesulfurization of straight-run light gas oil determination of effective factor of the feed properties to reaction rate of HDS

    Energy Technology Data Exchange (ETDEWEB)

    Narinobu Kagami; Ryuichiro Iwamoto; Tetsuji Tani [Idemitsu Kosan Co. Ltd, (Japan). Manufacturing Department, Petroleum Refining Technology Center


    Six kinds of straight run light gas oils were tested under various conditions in high pressure fixed bed reactor. First the formula of the corrected WAT (weight average temperature) normalized to the standard conditions was made by trial and error method, using the parameters chosen by the information of literature. Next the analysis of datamining method (ID3) and correlation coefficient were applied. This method is very unique and useful to evaluate the validity of the chosen parameters. The valid parameters of feed properties were density (SpGr), nitrogen content, and the temperature of 90% distillation (T90) under our experimental conditions. 17 refs., 5 figs., 5 tabs.

  8. EXAFS Determination of the Structure of Cobalt in Carbon-Supported Cobalt and Cobalt-Molybdenum Sulfide Hydrodesulfurization Catalysts.

    NARCIS (Netherlands)

    Koningsberger, D.C.; Bouwens, S.M.A.M.; Veen, J.A.R. van; Beer, V.H.J. de; Prins, R.


    The structure of the cobalt present in carbon-supported Co and Co-Mo sulfide catalysts was studied by means of X-ray absorption spectroscopy at the Co K-edge and by X-ray photoelectron spectroscopy (XPS). Thiophene hydrodesulfurization activities were used to measure the catalytic properties of

  9. A Big Five facet analysis of a psychopath: The validity of the HDS mischievous scale of sub-clinical psychopathy. (United States)

    Furnham, Adrian; Crump, John


    Around 5,700 British adults completed the NEO-PI-R, which measures the Big Five Personality factors at the Domain and the Facet level, as well as the Hogan Development Survey (HDS); measure of Anti-Social Personality Disorder called Mischievous. Previous work in this field has used clinical measures of psychopathy and either student or patient samples. This sought to validate this measure by comparing NEO facet correlational results with other studies. The Mischievous score from the HDS was the criterion variable in the correlations and multiple regressions. Mischievous people were Disagreeable, Stable, Extraverts, lacking in Conscientiousness. Facet analysis showed them high on Excitement-seeking but low of Straightforwardness, Anxiety and Deliberation. Limitations are of the study are discussed. © 2016 Scandinavian Psychological Associations and John Wiley & Sons Ltd.

  10. HDS, HDN and HDA activities of nickel-molybdenum catalysts supported on alumina

    Energy Technology Data Exchange (ETDEWEB)

    Dominguez-Crespo, M.A. [Instituto Mexicano del Petroleo, Programa de Tratamiento de Crudo Maya. Avenida Eje Central Lazaro Cardenas No.152, Col. San Bartolo Atepehuacan, 07730, Mexico D. F. (Mexico); Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada (CICATA-Altamira, IPN) Km 14.5 Carretera Tampico-puerto Industrial 89600, Altamira, Tamaulipas (Mexico); Torres-Huerta, A.M.; Ramirez-Meneses, E. [Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada (CICATA-Altamira, IPN) Km 14.5 Carretera Tampico-puerto Industrial 89600, Altamira, Tamaulipas (Mexico); Diaz-Garcia, L. [Instituto Mexicano del Petroleo, Programa de Tratamiento de Crudo Maya. Avenida Eje Central Lazaro Cardenas No.152, Col. San Bartolo Atepehuacan, 07730, Mexico D. F. (Mexico); Arce-Estrada, E.M. [Instituto Politecnico Nacional, Departamento de Metalurgia y Materiales. A.P. 75-876, 07300 Mexico, D. F. (Mexico)


    In this work, NiMo-Al{sub 2}O{sub 3} catalysts were prepared by using different alumina precursors. The supports were impregnated by means of the spray at incipient wetness technique in both basic and acid media. Both the supports and fresh catalysts were characterized by the adsorption-desorption isotherms, Temperature-Programmed Reduction (TPR), Thermal Pyridine Adsorption-Desorption (TPD) and X-Ray Diffraction analyses (XRD). After sulfidation, the NiMoS metallic particles were characterized by Transmission Electron Microscopy (TEM). The initial analyses were performed in a trickle-bed reactor by using a real feedstock (Mexican heavy gas oil) and performing hydrotreating reactions (HDS, HDN and HDA) at three different temperatures: 613, 633 and 653 K; and 54 kg cm{sup -} {sup 2}. The catalytic activities are discussed in relation to the physicochemical properties of the NiMo catalysts, alumina phase and pH of the impregnating solution. The catalytic results show an increase in the conversion profiles with temperature. The sulfur conversion was increased from 89 to 99.25%, 91-99%, 90.8-97%, 83-95% and 78-96% when the crystal size of the support varied from 3 to 20 nm, respectively. The nitrogen and aromatic conversions were also increased in the range of 23-45 wt.%. It was found that the {gamma} phase reached a higher catalytic performance than the {eta} phase. The NiMo catalysts synthesized in a basic medium showed a better catalytic performance than that obtained with those prepared in acid solutions. The significance of the kinetic data to compare the catalysts is discussed. The maximum value of the catalytic activity was reached with the catalysts with the smallest particle sizes. (author)

  11. Hydrodesulfurization of dibenzothiophene catalyzed by sulfided CoO-MoO/sub 3/. gamma. -Al/sub 2/O/sub 3/: the reaction network. [Dibenzothiophene

    Energy Technology Data Exchange (ETDEWEB)

    Houalla, M.; Nag, N.K.; Sapre, A.V.; Broderick, D.H.; Gates, B.C.


    Kinetic experiments in a high-pressure microreactor and a batch autoclave reactor elucidated the reaction network in the hydrodesulfurization of dibenzothiophene (a relatively unreactive compound in petroleum and coal-derived liquids), catalyzed by sulfided cobalt oxide/molybdenum trioxide/..gamma..-alumina at 573/sup 0/K and 102 atm. The predominant reaction was a direct sulfur extrusion, giving biphenyl and hydrogen sulfide; the biphenyl was subsequently hydrogenated slowly to give cyclohexylbenzene and then bicyclohexyl. Dibenzothiophene also underwent a primary hydrogenation reaction preceding sulfur removal, but it was about 1000 times slower than the sulfur extrusion reaction. The results showed that when methyl groups are present in the four and six positions of dibenzothiophene, the primary hydrogenation reaction is approximately as fast as the primary hydrodesulfurization reaction. Nickel and molybdenum or nickel and tungsten used instead of cobalt and molybdenum in the catalyst, or hydrogen sulfide in the reactant mixture, also favor hydrogenation relative to hydrodesulfurization.

  12. Implementation of a quantum cascade laser-based gas sensor prototype for sub-ppmv H2S measurements in a petrochemical process gas stream. (United States)

    Moser, Harald; Pölz, Walter; Waclawek, Johannes Paul; Ofner, Johannes; Lendl, Bernhard


    The implementation of a sensitive and selective as well as industrial fit gas sensor prototype based on wavelength modulation spectroscopy with second harmonic detection (2f-WMS) employing an 8-μm continuous-wave distributed feedback quantum cascade laser (CW-DFB-QCL) for monitoring hydrogen sulfide (H2S) at sub-ppm levels is reported. Regarding the applicability for analytical and industrial process purposes aimed at petrochemical environments, a synthetic methane (CH4) matrix of up to 1000 ppmv together with a varying H2S content was chosen as the model environment for the laboratory-based performance evaluation performed at TU Wien. A noise-equivalent absorption sensitivity (NEAS) for H2S targeting the absorption line at 1247.2 cm(-1) was found to be 8.419 × 10(-10) cm(-1) Hz(-1/2), and a limit of detection (LOD) of 150 ppbv H2S could be achieved. The sensor prototype was then deployed for on-site measurements at the petrochemical research hydrogenation platform of the industrial partner OMV AG. In order to meet the company's on-site safety regulations, the H2S sensor platform was installed in an industry rack and equipped with the required safety infrastructure for protected operation in hazardous and explosive environments. The work reports the suitability of the sensor prototype for simultaneous monitoring of H2S and CH4 content in the process streams of a research hydrodesulfurization (HDS) unit. Concentration readings were obtained every 15 s and revealed process dynamics not observed previously.

  13. Integration of non linearities in the economic refining model. Case of the hydro-desulfurization unit; Prise en compte de non-linearites dans la modelisation economique du raffinage. Cas de l`unite d`hydrodesulfuration

    Energy Technology Data Exchange (ETDEWEB)

    Baudouin, C.


    In recent years, the modifications in oil products demand and the increased quality requirements of European specifications have driven the oil industry towards more and more complex refining schemes. This situation should become even more pronounced in the future. Under these conditions, a technical analysis of the units operation must be carried out and combined with an economic approach. The research undertaken is divided into two parts. The first part is dedicated to the study of the European refining industry and its representation by the classic linear programming model. In these models, the units` operation is represented by typical running. The technical parameters are not explicitly taken into account. Therefore, in order to meet future requirements and to represent this activity in the best way, the current model must be improved. The second part relates to an analysis with forecasts future developments in the European refining sector up to 2010 and how linear programming models themselves will be adapted. Thus, the straight run gas oil hydro-desulfurization unit is completely redefined. The operating conditions and the design parameters of this unit are introduced into the model. Depending on the feed, they determine the performances and the material balance of the unit. Some of these operating conditions are new variables and appear in non linear equations. Therefore, we need non linear programming (the augmented Lagrangians method) to solve this detailed model. The results of the second part confirm those determined by the first part. They also provide us with a better representation of the hydro-desulfurization unit (taking the optimisation of the operating conditions into account). Using these models and the analysis described above, we can develop an outline plan of the future European refining industry. This shows that sizeable investments in both conventional and deep conversion capacity will be required to meet the requirements of changes in

  14. Hydrodesulfurization of dibenzothiophene and related compounds catalyzed by sulfided CoO--MoO/sub 3//. gamma. --Al/sub 2/O/sub 3/: effects of reactant structure on reactivity

    Energy Technology Data Exchange (ETDEWEB)

    Houalla, M.; Broderick, D.; de Beer, V.H.J.; Gates, B.C.; Kwart, H.


    The hydrodesulfurization of dibenzothiophene and methyl-substituted derivatives are shown to be first-order reactions and the relative first-order rate constants were determined. These data showed that effects of the position of the methyl group are responsible for an order of magnitude difference in the reactivities. A possible desulfurization mechanism is proposed. (JSR)

  15. Experiência Brasileira Utilizando Terapia Sequencial De Alta Dose Seguido De Transplante Autólogo De Célula-tronco Hematopoética Para Linfomas Malignos [brazilian Experience Using High-dose Sequential Therapy (hds) Followed By Autologous Hematopoietic Stem Cell Transplantation (asct) For Malignant Lymphomas


    de Souza C.A.; Pagnano K.B.B.; Lorand-Metze I.; Miranda E.C.M.; Baldissera R.; Aranha F.J.P.; Vigorito A.C.; Duarte B.K.L.


    Using the overall survival (OS), disease free survival (DFS) and progression free survival (PFS), as well as associated toxicity, the purpose of this work was to evaluate the effectiveness of HDS followed by ASCT as salvage therapy. A retrospective analysis was performed of 106 patients with high grade non-Hodgkin lymphoma receiving HDS followed by ASCT, between 1998 and 2006. Median age was 45 years (Range: 8-65), with 66 (62%) men. Histopathological classification was: 78% DLBCL patients, 1...

  16. Arsenic in industrial waste water from copper production technological process

    Directory of Open Access Journals (Sweden)

    Biljana Jovanović


    Full Text Available Investigation of arsenic in industrial waste water is of a great importance for environment. Discharge of untreated waste water from a copper production process results in serious pollution of surface water, which directly affects flora and fauna, as well as humans. There is a need for efficient and environmentally acceptable treament of waste waters containing heavy metals and arsenic. The paper presents an analyisis of the waste water from The Copper Smelter which is discharged into the Bor river. The expected arsenic content in treated waste water after using HDS procedure is also presented.

  17. Brazilian experience using high-dose sequential therapy (HDS followed by autologous hematopoietic stem cell transplantation (ASCT for malignant lymphomas Experiência brasileira utilizando terapia sequencial de alta dose seguido de transplante autólogo de célula-tronco hematopoética para linfomas malignos

    Directory of Open Access Journals (Sweden)

    Cármino A. de Souza


    Full Text Available Using the overall survival (OS, disease free survival (DFS and progression free survival (PFS, as well as associated toxicity, the purpose of this work was to evaluate the effectiveness of HDS followed by ASCT as salvage therapy. A retrospective analysis was performed of 106 patients with high grade non-Hodgkin lymphoma receiving HDS followed by ASCT, between 1998 and 2006. Median age was 45 years (Range: 8-65, with 66 (62% men. Histopathological classification was: 78% DLBCL patients, 12% T and anaplastic and 9% Mantle cell lymphomas; 87% had B cell and 12% T cell lymphomas; 83% were stage III-IV (Ann Arbor Staging, 63% had B symptoms, 32% had bone marrow involvement, 62% bulky disease and 42% high-intermediate or high risk IPI. After HDCY, 9 patients died, 7 from toxicity and 2 from sepsis. Eighty patients underwent ASCT, 47% were in complete remission (CR and 15% died, all from toxicity. Their OS was 45% over 8 years. During the follow-up, another 35 patients died [4 CR, 1 partial response (PR, 2 relapsed disease (RD and 28 disease progression (DP], 11 (31% had not performed ASCT. OS was 37%; DFS was 49% and PFS 28%. OS by diagnosis was 42% for DLBCL, 40% for T-cell (8 y and 20% for Mantle Cell (6 y (P=NS. OS by B symptom patients was 22% vs. 58% (P=0.002 and PFS was 23% vs. 37% (P=0.03. Patients who achieved CR after HDCY (38 had significantly better OS and PFS (38% and 17% than patients who remained in DP (PA proposta deste trabalho foi avaliar a eficácia da HDS seguida do transplante autólogo como terapia de salvamento através da sobrevida global, livre de doença e livre de progressão bem como sua toxicidade. Realizou-se estudo retrospectivo com 106 pacientes com LNH de alto grau de malignidade entre 1998 e 2006. A mediana de idade foi 45 anos (8-65; 62% homens; DLBCL, 78%; 12%, T e anaplásico e 9%, linfoma da zona do manto; 87%, células B; 83% estádios III-IV; 63% com sintomas B; 32% com infiltração da medula óssea ao diagn


    Energy Technology Data Exchange (ETDEWEB)

    Scott Collins; David Nunn


    The analysis of Petro Star diesel sulfur species is complete and a report is attached. Further analytical efforts will concentrate on characterization of diesel fuel, hydrodesulfurized to varying degrees, in order to determine sulfur species that may be problematic to hydrogen treatment and represent potential target substrates for biodesulfurization in a combined HDS-BDS process. Quotes have been received and are being considered for the partial treatment of Petro Star Inc. marine diesel fuel. Direction of research is changing slightly; economic analysis of the hyphenated--BDSHDS, BDS-CED--has shown the highest probability of success to be with a BDS-HDS process where the biodesulfurization precedes hydrodesulfurization. Thus, the microorganisms will be tailored to focus on those compounds that tend to be recalcitrant to hydrodesulfurization and decrease the severity of the hydrodesulfurization step. A separate, detailed justification for this change is being prepared. Research activities have continued in the characterization of the desulfurization enzymes from multiple sources. Genes for all DszA, -B, -C and -D enzymes (and homologs) have been cloned and expressed. Activity determinations, on a variety of substituted benzothiophene and dibenzothiophene substrates, have been carried out and continue. In addition, chemical synthesis efforts have been carried out to generate additional substrates for analytical standards and activity determinations. The generation of a GSSM mutant library of the ''Rhodococcus IGTS8 dszA'' gene has been completed and development of protocols for a high throughput screen to expand substrate specificity are nearing completion. In an effort to obtain improved hosts as biocatalyst, one hundred-thirty ''Rhodococcus'' and related strains are being evaluated for growth characteristics and other criteria deemed important for an optimal biocatalyst strain. We have also begun an effort to generate

  19. Process Considerations in the Biodesulfurization of Crude Oil

    Energy Technology Data Exchange (ETDEWEB)

    Borole, A.P.; Kaufman, E.N.


    Biodesulfurization offers an attractive alternative to conventional hydrodesulfurization due to the mild operating conditions and reaction specificity afforded by the biocatalyst. The enzymatic pathway existing in Rhodococcus has been demonstrated to oxidatively desulfhrize the organic sulfbr occurring in dibenzothiophene while leaving the hydrocarbon intact. In order for biodesulfiization to realize commercial success, a variety of process considerations must be addressed including reaction rate, emulsion formation and breakage, biocatalyst recovery, and both gas and liquid mass transport. This study compares batch stirred to electro-spray bioreactors in the biodesulfurization of both model organics and actual crudes in terms of their operating costs, ability to make and break emulsions, ability to effect efficient reaction rates and enhance mass transport. Further, sulfim speciation in crude oil is assessed and compared to the sulfur specificity of currently available biocatalyst.

  20. Atomic scale analysis of sterical effects in the adsorption of 4,6-dimethyldibenzothiophene on a CoMoS hydrotreating catalyst

    DEFF Research Database (Denmark)

    Grønborg, Signe S.; Šaric, Manuel; Moses, Poul Georg


    The low catalytic hydrodesulfurization (HDS) activity toward sterically hindered sulfur-containing molecules is a main industrial challenge in order to obtain ultra-low sulfur diesel. In this study we report a combined Scanning Tunneling Microscopy (STM) and Density Functional Theory (DFT...

  1. Future production of gasoline in Brazil; Producao futura de gasolina no Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Perisse, Juarez B.; Oddone, Maria Regina R.; Lemos, Solange S.F.; Lucena, Sergio Cunha de; Gomes, Hedemir F. [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)


    Faced with the challenge of making 2014 gasoline, PETROBRAS established the planning of a new refining park that made possible this production. The proposal comprised new process units with hydrotreating and conversion. These units have the function to work synergistically, according to the needs and characteristics of each refinery. The large reduction in the sulfur content generated the need to use cracked naphtha hydrodesulfurization units (HDS) in the refining scheme. However, these units, in addition to removing sulfur, reduce octane number due to saturation of some olefins, which would imply a drop in gasoline production. The reduction of the content of olefins in the specification led the need to dilute the produced olefins in the blend, as PETROBRAS gasoline is composed on average of 70% cracked naphtha. Catalytic Reforming Units (CCR) will become part of the refining scheme with two main functions, dilute olefins and restore the octane number loss in the hydrodesulfurization process. This is possible because reformed naphtha has no olefins and a high octane index. The feedstock must be hydrotreated to remove contaminants, and such units become even more severe if the feedstock is combined with naphtha from Delayed coking units (DCU). As a result, new hydrotreatment of naphtha (distillation and DCU) were also included in the new refinery schemes. All this new refining structure, focusing on the new gasoline specification, is being implemented. Each refinery has a new scheme of its own, according to its characteristics. (author)

  2. Influence of the sulfidation procedure on the performance and the selectivity of hydro-treating catalysts; Influence de la procedure de sulfuration sur la performance et la selectivite des catalyseurs d'hydrotraitement

    Energy Technology Data Exchange (ETDEWEB)

    Texier, S.


    This work is part of a general effort to reduce the sulfur content of fuels to satisfy new European regulations. The objective was to determine the influence of several activating agents during sulfidation on the activity of hydro-desulfurization (HDS) catalysts. Indeed, sulfidation is a critical step to achieve a good level of HDS activity on sulfide catalysts. Under industrial conditions, the activation by organo-sulfide compounds would be more beneficial to obtain active catalysts than the use of hydrogen sulfide. A systematic study of the various operational parameters of the activation process was thus carried out by comparing precisely activation by H{sub 2}S or by organo-sulfides. This study reveals that the recognized advantage of organo-sulfides compounds has not a 'purely chemical origin' but would be more probably related to a heating and/or thermodynamic effect which depends on the processes and on the implementation of sulfidation under the industrial conditions. (author)

  3. Achievement report for fiscal 2000 on development of technologies to reduce pollutants in oil refining; 2000 nendo sekiyu seisei osen busshitsu teigen nado gijutsu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)



    Research and development has been made on technologies to reduce sulfur content in light oil and on optimization of light oil quality. This paper summarizes the achievements in fiscal 2000. In the study of enhancing the desulfurization rate in gas oil deep hydrodesulfurization process, it was found that NiHY zeolite having Ni introduced by using the ion exchange method shows stable activity, whereas the target of sulfur content of 50 ppm or lower was achieved by adding the third constituent and by optimizing the impregnation solution to pH3. In the study of the Ni, Mo/alumina catalyst, the desulfurization activity was enhanced by optimization of carrier pore size to 120 to 140 angstroms and by addition of phosphorus and silica, having the target of sulfur content of 50 ppm or lower achieved. In the research of manufacturing low-sulfur light oil using heavy oil desulfurization and hydrocracking, optimization was performed on the catalyst used in the latter stage of heavy oil desulfurization, and evaluation was given on the performance in combination of commercially available hydrometallation catalyst/middle part HDS catalyst/bottom part HDS catalyst. As a result, achievement of the target of sulfur content in the desulfurized light oil of 300 ppm or lower was verified. Life evaluation test is in continuation on the heavy oil hydrocracking catalyst. (NEDO)

  4. A potassium tert-butoxide and hydrosilane system for ultra-deep desulfurization of fuels (United States)

    Toutov, Anton A.; Salata, Mike; Fedorov, Alexey; Yang, Yun-Fang; Liang, Yong; Cariou, Renan; Betz, Kerry N.; Couzijn, Erik P. A.; Shabaker, John W.; Houk, Kendall N.; Grubbs, Robert H.


    Hydrodesulfurization (HDS) is the process by which sulfur-containing impurities are removed from petroleum streams, typically using a heterogeneous, sulfided transition metal catalyst under high H2 pressures and temperatures. Although generally effective, a major obstacle that remains is the desulfurization of highly refractory sulfur-containing heterocycles, such as 4,6-dimethyldibenzothiophene (4,6-Me2DBT), which are naturally occurring in fossil fuels. Homogeneous HDS strategies using well-defined molecular catalysts have been designed to target these recalcitrant S-heterocycles; however, the formation of stable transition metal sulfide complexes following C-S bond activation has largely prevented catalytic turnover. Here we show that a robust potassium (K) alkoxide (O)/hydrosilane (Si)-based ('KOSi') system efficiently desulfurizes refractory sulfur heterocycles. Subjecting sulfur-rich diesel (that is, [S] ∼ 10,000 ppm) to KOSi conditions results in a fuel with [S] ∼ 2 ppm, surpassing ambitious future governmental regulatory goals set for fuel sulfur content in all countries.

  5. Process

    Energy Technology Data Exchange (ETDEWEB)

    Geenen, P.V.; Bennis, J.


    A process is described for minimizing the cracking tendency and uncontrolled dimensional change, and improving the strength of a rammed plastic refractory reactor liner comprising phosphate-bonded silicon carbide or phosphate-bonded alumina. It consists of heating the reactor liner placed or mounted in a reactor, prior to its first use, from ambient temperature up to a temperature of from about 490/sup 0/C to about 510/sup 0/C, the heating being carried out by heating the liner at a rate to produce a temperature increase of the liner not greater than about 6/sup 0/C per hour.

  6. Catalyst innovation improves commercial application of the OATS trademark process

    Energy Technology Data Exchange (ETDEWEB)

    Wache, W.; Schunk, C.; Botz, N.; Karl, G.; Braun, R. [Bayernoil GmbH, Ingolstadt (Germany)


    Many catalyzed reactions in the refinery are carried out in multi-phase reactors, for example in the most widely used technology for sulphur removal the HDS (Hydrodesulphurisation) process. Even if the reaction has been well known for over 40 years, the chemical process is still very complex. Temperature control as well as the scaling up of the reactor are important and problematic, e. g. leading to a complex reactor design requiring gas phase recycle with high costs for recompressing because the H{sub 2}-supply needs to exceed significantly what is chemically consumed. The OATS trademark (= Olefin Alkylation of Thiophenic Sulphur) process is an alternative route for sulfur removal and requires no hydrogen at all. In this non-HDS based desulphurisation technology, organic sulphur compounds are shifted to higher boiling points and thus can be removed by distillation from the light fractions and concentrated in the heavy boiling part of the refinery streams. In 2002 the Bayernoil Refinery in Bavaria licensed OATS trademark technical information and patents from BP Refining Technology, and built the very first two commercial OATS trademark plants in their Neustadt and Vohburg refineries. As with most new processes the units had some initial problems, but both units have now been successfully operated and are now producing continuously up to 200 m{sup 3}/h of ULSG (ultra low sulphur gasoline) with feed coming from all three of Bayernoil's FCC units. Working as a 2-phase system under mild conditions with low energy costs and without any use of metal compounds in the catalyst, ULSG with sulphur levels of < 30 ppm can be produced, allowing the blended products to meet the most severe motor gasoline specifications (Euro 5). (orig.)

  7. Morphology tuning of CoMo catalysts: Effect of La and Fe as an additive

    Directory of Open Access Journals (Sweden)

    Yu Pei


    Full Text Available Three catalysts CoMo/γ-Al2O3, CoMo-La/γ-Al2O3, CoMo-Fe/γ-Al2O3 with different morphologies were prepared for study the effect of introduction of La and Fe on morphology properties and hydrodesulfurization (HDS activity. The morphology properties of catalysts were characterized by BET, XPS and HRTEM. In addition, the catalytic performances of catalysts were investigated. The results indicated that the introduction of La and Fe promoted the sulfidation of Mo species and made the average length and stacking layer numbers of MoS2 slabs longer and higher. These effects could improve the activity of catalysts for HDS. The present results indicated that the catalyst modified by Fe had the best HDS activity with the optimal morphology among three catalysts

  8. Dispersed catalysts for co-processing and coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Bockrath, B.; Parfitt, D.; Miller, R. [Pittsburgh Energy Technology Center, PA (United States)


    The basic goal is to improve dispersed catalysts employed in the production of clean fuels from low value hydrocarbons. The immediate objective is to determine how the properties of the catalysts may be altered to match the demands placed on them by the properties of the feedstock, the qualities of the desired end products, and the economic constraints put upon the process. Several interrelated areas of the application of dispersed catalysts to co-processing and coal conversion are under investigation. The first involves control of the selectivity of MoS{sub 2} catalysts for HDN, HDS, and hydrogenation of aromatics. A second area of research is the development and use of methods to evaluate dispersed catalysts by means of activity and selectivity tests. A micro-flow reactor has been developed for determining intrinsic reactivities using model compounds, and will be used to compare catalysts prepared in different ways. Micro-autoclaves will also be used to develop data in batch experiments at higher partial pressures of hydrogen. The third area under investigation concerns hydrogen spillover reactions between MoS{sub 2} catalysts and carbonaceous supports. Preliminary results obtained by monitoring H{sub 2}/D{sub 2} exchange reactions with a pulse-flow microreactor indicate the presence of spillover between MoS{sub 2} and a graphitic carbon. A more complete study will be made at a later stage of the project. Accomplishments and conclusions are discussed.

  9. Probing topological electronic effects in catalysis: thiophene adsorption on NiMoS and CoMoS clusters

    Energy Technology Data Exchange (ETDEWEB)

    Borges Junior, Itamar; Silva, Alexander M., E-mail: [Instituto Militar de Engenharia (IME), Rio de Janeiro-RJ (Brazil). Programa de Pos-Graduacao em Engenharia de Defesa


    A general two-step theoretical approach to study electronic redistributions in catalytic processes is presented. In the first step, density functional theory (DFT) is used to fully optimize two geometries: the cluster representing the catalyst and the cluster plus adsorbed molecule system. In the second step, the converged electron density is divided into multipoles centered on atomic sites according to a distributed multipole analysis which provides detailed topological information on the charge redistribution of catalyst and molecule before and after adsorption. This approach is applied to thiophene adsorption on the 10{sup -}10 metal edge of Ni(Co)MoS catalysts and compared to the same reaction on bare MoS{sub 2}. Calculated adsorption energies, geometries and multipole analysis indicate weak thiophene chemisorption on both cases. A Coulombic bond model showed that surface metal-sulfur bond strengths in Ni(Co)MoS promoted catalysts are considerably smaller than in bare MoS{sub 2}, thus confirming the origin of the enhancement of hydrodesulfurization (HDS) activity in these catalysts. (author)

  10. Reactivity of pi-complexes of Ti, V, and Nb towards dithioacetic acid: Synthesis and structure of novel metal sulfur-containing complexes (United States)

    Duraj, Stan A.; Andras, Maria T.; Hepp, Aloysius F.


    In order to use sulfur-containing resources economically and with minimal environmental damage, it is important to understand the desulfurization processes. Hydrodesulfurization, for example, is carried out on the surface of a heterogeneous metal sulfide catalyst. Studies of simple, soluble inorganic systems provide information regarding the structure and reactivity of sulfur-containing compounds with metal complexes. Further, consistent with recent trends in materials chemistry, many model compounds warrant further study as catalyst precursors. The reactivity of low-valent organometallic sandwich pi-complexes toward dithiocarboxylic acids is described. For example, treatment of bisbenzene vanadium with CH3CSSH affords a divanadium tetrakis(dithioacetate) complex. The crystallographically determined V-V bond distance, 2.800(2), is nearly the same as the V-V bond distance in a V(mu-nu squared-S2)2V' unit in the mineral patonite (VS4)n. The stability of the V2S4 core in the dimer is demonstrated by evidence of V2S4(+) in the mass spectrum (70 eV, solid probe) of the vanadium dimer. Several other systems relevant to HDS catalysis are also discussed.

  11. Mo/MCM-41-Type mesoporous materials doubly promoted with Fe and Ni for hydrotreating reactions

    Energy Technology Data Exchange (ETDEWEB)

    Carlos F. Linares; Patricia Amezqueta; Carlos Scott [Universidad de Carabobo, Carabobo (Venezuela). Laboratorio de Catalisis y Metales de Transicion


    A Si-MCM-41-type material was synthesized and impregnated with a Mo solution in order to get a 15% MoO{sub 3} by weight. Then, it was doubly promoted with Ni and Fe in different proportions. Information on the structure of the precursors was revealed by XRD, TPR and surface area techniques. XRD results showed that the mesoporous materials were not affected for the successive impregnations carried out; while, their specific surface areas was partially blocked. These solids were tested for vanadyl octaethyl porphyrin hydrodeporphirinization (HDP), and individual and competitive reactions of dibenzothiophene (DBT) hydrodesulfurization (HDS) and 2-methyl naphthalene (2MN) hydrogenation (HYD). The DBT HDS activity was higher than 2MN HYD, and the presence of Fe in the catalysts did not produce a synergetic effect for this reactions. However, HDP activities of doubly promoted catalysts were superior to the monopromoted ones. 28 refs., 8 figs., 5 tabs.

  12. Atomic-scale insight into the origin of pyridine inhibition of MoS2-based hydrotreating catalysts

    DEFF Research Database (Denmark)

    Temel, Burcin; Tuxen, Anders K.; Kibsgaard, Jakob


    Basic nitrogen-containing compounds such as pyridine are well known to be inhibitors of the hydrodesulfurization (HDS) reaction for the MoS2-based catalysts. From an interplay of scanning tunneling microscopy (STM) experiments and density functional theory (DFT) calculations, atomic-scale insight...... also at the edges. The calculated DFT energies and simulated STM images allowed us to conclude that these species are pyridinium ions located at the catalytically active brim sites. Furthermore, the DFT results for the vibrational modes of the adsorbed pyridinium species agree well with those observed...... in earlier IR experiments on high surface alumina-supported MoS2 catalyst. The adsorption sites appear to be very similar to the brim sites involved in hydrogenation reactions in HDS. Thus, the combined STM and DFT results provide new atomic-scale insight into the inhibition effect of basic N...

  13. Density functional study of the adsorption and van der Waals binding of aromatic and conjugated compounds on the basal plane of MoS2

    DEFF Research Database (Denmark)

    Moses, Poul Georg; Mortensen, Jens Jørgen; Lundqvist, Bengt


    der Waals interactions are essential for binding energies on MoS2 surfaces and that DFT with a recently developed exchange-correlation functional (vdW-DF) accurately calculates the van der Waals energy. Values are calculated for the adsorption energies of butadiene, thiophene, benzothiophene, pyridine......, quinoline, benzene, and naphthalene on the basal plane of MoS2, showing good agreement with available experimental data, and the equilibrium geometry is found as flat at a separation of about 3.5 A for all studied molecules. This adsorption is found to be due to mainly van der Waals interactions......Accurate calculations of adsorption energies of cyclic molecules are of key importance in investigations of, e.g., hydrodesulfurization (HDS) catalysis. The present density functional theory (DFT) study of a set of important reactants, products, and inhibitors in HDS catalysis demonstrates that van...

  14. Modeling of a three-phase reactor for bitumen-derived gas oil hydrotreating

    Directory of Open Access Journals (Sweden)

    R. Chacón


    Full Text Available A three-phase reactor model for describing the hydrotreating reactions of bitumen-derived gas oil was developed. The model incorporates the mass-transfer resistance at the gas-liquid and liquid-solid interfaces and a kinetic rate expression based on a Langmuir-Hinshelwood-type model. We derived three correlations for determining the solubility of hydrogen (H2, hydrogen sulfide (H2S and ammonia (NH3 in hydrocarbon mixtures and the calculation of the catalyst effectiveness factor was included. Experimental data taken from the literature were used to determine the kinetic parameters (stoichiometric coefficients, reaction orders, reaction rate and adsorption constants for hydrodesulfuration (HDS and hydrodenitrogenation (HDN and to validate the model under various operating conditions. Finally, we studied the effect of operating conditions such as pressure, temperature, LHSV, H2/feed ratio and the inhibiting effect of H2S on HDS and NH3 on HDN.

  15. About the process improvement of adsorptive desulphurisation by adding hydrogen donators as additives in liquid fuels (United States)

    van Rheinberg, Oliver; Lucka, Klaus; Köhne, Heinrich

    For the use in fuel cell system commercial fuels, like diesel or domestic heating oil, have to be desulphurised to ultra deep sulphur levels of below 1 mg kg -1. To reach this goal the adsorptive desulphurisation using a nickel-based sorbent has been identified. The evaluation of the reaction mechanism reveals in principle the same route as that of the hydrodesulphurisation (HDS) whereas the sulphur is adsorbed by the sorbent instead of being converted to hydrogen sulphide. The required hydrogen for the process is provided out of the fuel itself and not by an external supply of hydrogen. This analysis leads to an easy applicable enhancement of the process by adding a hydrogen donator as an additive to the liquid fuel. In correlation to the mass fraction of the donator the reaction rates and sorbent capacities are improved significantly. Furthermore the influence of aromatic compounds has been investigated, which exhibit similar molecular structures and chemical properties than comparable high refractory sulphur species. This leads to side reactions especially of di- and tri-aromatics which influence the sulphur adsorption. A shift of the aromatic fraction from mono- to di- and tri-aromatic compounds has been observed as well as the alkylation of di- and tri-aromatics.

  16. Interim Report: Targeted Chronic Wasting Disease Surveillance in HDs 600 and 401 (United States)

    US Fish and Wildlife Service, Department of the Interior — In 2015 and 2016, Montana Fish, Wildlife, and Parks (MFWP) initiated a study in collaboration with the US Fish and Wildlife Service focused on the movement patterns...

  17. Innovative tools and OpenHDS for health and demographic surveillance on Rusinga Island, Kenya

    NARCIS (Netherlands)

    Homan, T.; Pasquale, di A.; Kiche, I.; Onoka, K.; Hiscox, A.F.; Mweresa, C.K.; Mukabana, W.R.; Takken, W.; Maire, N.


    Background Health in low and middle income countries is on one hand characterized by a high burden associated with preventable communicable diseases and on the other hand considered to be under-documented due to improper basic health and demographic record-keeping. health and demographic

  18. 76 FR 21748 - Health Disparities Subcommittee (HDS), Advisory Committee to the Director, Centers for Disease... (United States)


    ... on strategic and other health disparities and health equity issues and provide guidance on... charge and membership status of the Health Equity Workgroup; (2) an overall Health Equity activities... Strategy; Healthy People 2020; and Social Determinants of Health Strategy Brief. The agenda is subject to...


    Directory of Open Access Journals (Sweden)

    Iván Machín


    Full Text Available This paper presents a set of procedures based on mathematical optimization methods to establish optimal active sulphide phases with higher HDS activity. This paper proposes a list of active phases as a guide for orienting the experimental work in the search of new catalysts that permit optimize the HDS process. Studies in this paper establish Co-S, Cr-S, Nb-S and Ni-S systems have the greatest potential to improve HDS activity.

  20. Regeneration of Hydrotreating and FCC Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    CM Wai; JG Frye; JL Fulton; LE Bowman; LJ Silva; MA Gerber


    Hydrotreating, hydrocracking, and fluid catalytic cracking (FCC) catalysts are important components of petroleum refining processes. Hydrotreating and hydrocracking catalysts are used to improve the yield of high-quality light oil fractions from heavier crude oil and petroleum feedstocks containing high levels of impurities. FCC catalysts improve the yield of higher octane gasoline from crude oil. Residuum hydrotreating and cracking catalysts are susceptible to irreversible deactivation caused by adsorption of sulfur and by metals impurities, such as vanadium and nickel. The gradual buildup of these impurities in a hydrotreating catalyst eventually plugs the pores and deactivates it. Nickel and vanadium adversely affect the behavior of cracking catalysts, reducing product yield and quality. Replacing deactivated catalysts represents a significant cost in petroleum refining. Equally important are the costs and potential liabilities associated with treating and disposing spent catalysts. For example, recent US Environmental Protection Agency rulings have listed spent hydrotreating and hydrorefining catalysts as hazardous wastes. FCC catalysts, though more easily disposed of as road-base or as filler in asphalt and cement, are still an economic concern mainly because of the large volumes of spent catalysts generated. New processes are being considered to increase the useful life of catalysts or for meeting more stringent disposal requirements for spent catalysts containing metals. This report discusses a collaborative effort between Pacific Northwest National Laboratory (PNNL) and Phillips Petroleum, Inc., to identify promising chemical processes for removing metals adhered to spent hydrodesulfurization (HDS, a type of hydrotreating catalyst) and FCC catalysts. This study, conducted by PNNL, was funded by the US Department of Energy's Bartlesville Project Office. Fresh and spent catalysts were provided by Phillips Petroleum. The FCC catalyst was a rare

  1. USSR Report, Chemistry (United States)


    Hydrodesulfurization CA. I, Vagin , V, I. Yerofeyev, et al.f ZHURNAL TIZICHESKOY. KHIMII, No 11, Nov 84)............., • 23 Hydrogenatlon of...N. Anell , D. G, Pagava, et al,; KÄUCHUK I REZINA, No 11, Nov 84),... ,...,...,...,...,...... 125 Influence of Asbestos Dust on Processing...USED IN HYDRODESULFURIZATION Moscow ZHÜRNAL FIZICHESKOY KHIMII in Russian Vol 58, No 11, Nov 84 (man script received 17 Feb 83) pp 2727-2729 VAGIN

  2. Comprehensive Evaluation of Catalytic Hydroreduction and Nonthermal Plasma as Alternative Technologies for Detoxification of Chemical Wastes (United States)


    suggested that well- known HDS catalysts, such as Ni-Mo and Co-Mo, might be candidates for combined HDS and HDC of CEES. Another process developed by Kalnes ...7. Kalnes , T.N., and R.B. James, Innovative Hazardous Waste Treatment Technology Series, Vol. 1, Thermal Processes, Freeman, H.M., Ed., p. 65-76

  3. Effect of spatial coherence of LED sources on image resolution in holographic displays

    NARCIS (Netherlands)

    Pourreza Ghoushchi, Vahid; Aas, Mehdi; Ulusoy, Erdem; Ürey, Hakan


    Holographic Displays (HDs) provide 3D images with all natural depth cues via computer generated holograms (CGHs) implemented on spatial light modulators (SLMs). HDs are coherent light processing systems based on interference and diffraction, thus they generally use laser light. However, laser

  4. Pd-Rh promoted Co/HPS catalysts for heavy oil upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Hossain, M.M. [CREC, Chemical and Biochemical Engineering Department, University of Western Ontario, London, Ont. (Canada); Al-Saleh, M.A.; Shalabi, M.A. [CRP, The Research Institute, King Fahd University of Petroleum and Minerals, Dhahran (Saudi Arabia); Kimura, T.; Inui, T. [Japan Petroleum Energy Center, Kanagawa (Japan)


    This paper reports the promotional effects of Pd and Rh on hydrocracking (HC) and hydrodesulfurization (HDS) activity of Co/HPS catalyst. The catalysts were prepared by loading of noble metal followed by cobalt on the high porous saponite (HPS) support. The incipient impregnation technique was adapted for the loading of noble metal(s) while an ion exchange method was followed for cobalt loading on HPS. The catalysts were characterized by temperature-programmed reduction (TPR). Results showed that the reducibility of the catalysts was significantly improved in presence of the noble metals (Pd, Rh). The activity of the catalysts was tested in a batch autoclave reactor using vacuum gas oil as feedstock. Both the HC and HDS activity of noble metal-promoted Co/HPS catalysts were found to be higher than that of plain Co/HPS catalysts. Rh displayed higher promotional effects as compared to Pd in both HC and HDS purpose. This higher activity is consistent with the TPR results, which showed superior reducibility of Rh promoted catalysts. The most interesting part of this study pertained the effects of bi-noble (Pd-Rh) metal on Co/HPS. A trace amount of Rh along with Pd exhibited a significant enhancement of the catalytic activity of Co/HPS, which was comparable to what Rh alone did with a higher amount. The coke deposition on Pd-Rh promoted catalyst was also found lower than that of the plain and single noble metal promoted Co/HPS.

  5. The results of monitoring of hazardous natural processes in the coastal shelf zone of the gulf of Peter the Great in 2012-2013 (United States)

    Anokhin, Vladimir; Shcherbakov, Victor; Motychko, Victor; Sokolov, Georgy; Kotov, Sergey; Kartashov, Alexander; Anokhina (1)(2), Zoya


    The monitoring of hazardous natural processes In coastal and shelf zone of the gulf of Peter the Great (sea of Japan) in 2012-2013 was made by staff of the Gramberg Institute VNIIOKEANGEOLOGIA . The complex of field researches are: - laser scanning beaches (tachometer Leica HDS 3000); - echosounding underwater coastal slope (sounder-Navigator LCX-37C); - high-frequency acoustic profiling (GeoPulse Subbotom Profilier); - hydromagnetic shooting magnetometer SeaSPY Marine Magnetics; - sonar shooting (complex GEO-CM-MAX); - research of the water column (sounding and sampling); - bottom sampling, including gasgeochemical shooting. The result of this work is the following conclusions: 1. As the shore, and the underwater slope of the district are experiencing the preemptive destruction, the areas of which are quantitative and spatially prevail over the stable and accumulate zones (except the shores of the inland parts of bays and gulfs). 2. The rate of destruction of coast in the Gulf of Peter the Great is 1-20 meters for 100 years, that could pose a serious danger to the population and infrastructure. 3. Number of gasgeochemical anomalies on the shelf of the Gulf of Peter the Great spatially associated with fault lines, limiting blocks of the earth's crust within shelf. 4. Perhaps it is these faults are of the greatest seismic hazard in the moment. 5. Danger of themselves gas emissions The following significant hazards and risks to the region have been studied: seismic and tsunami destruction of shore, gas emissions, technogenic pollution.

  6. Surface chemistry of activated hydrodesulfurization catalysts by x-ray photoelectron spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Brinen, J.S.; Armstrong, W.D.


    The XPS spectra of unsulfided and sulfided catalyst containing 12-30% molybdenum trioxide and 0-6% cobalt oxide on alumina or carbon showed that the cobalt is reduced by sulfiding with hydrogen/hydrogen sulfide at 400/sup 0/C, probably to the zero-valent state; no cobalt sulfide was observed. A bulk cobalt molybdate sample treated under the same sulfiding conditions as the supported catalysts, showed the expected Co/sub 9/S/sub 8/ formation. On alumina supports, part of the cobalt formed CoAl/sub 2/O/sub 4/, in amounts that depended on the temperature of calcining prior to sulfiding; cobalt bound as aluminate was neither sulfided nor reduced. The differences between the supported and unsupported catalysts are attributed to the dispersion.

  7. Highly dispersed NiW/{gamma}-Al{sub 2}O{sub 3} catalyst prepared by hydrothermal deposition method

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hao [State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 (China); Fan, Yu.; Bao, Xiaojun [State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 (China); The Key Laboratory of Catalysis, China National Petroleum Corp., China University of Petroleum, Beijing 102249 (China); Shi, Gang; Liu, Haiyan [The Key Laboratory of Catalysis, China National Petroleum Corp., China University of Petroleum, Beijing 102249 (China); Liu, Zhihong [Science and Technology Management Department, PetroChina Company Ltd., World Tower, 16 Andelu, Dongcheng District, Beijing 100011 (China)


    This article describes a novel hydrothermal deposition method for preparing highly dispersed NiW/{gamma}-Al{sub 2}O{sub 3} catalysts and demonstrates its advantages over the conventional impregnation method. Via the hydrothermal precipitation reactions between sodium tungstate and hydrochloric acid and between nickel nitrate and urea, respectively, the active species W and Ni were deposited on {gamma}-Al{sub 2}O{sub 3}. In the hydrothermal deposition of WO{sub 3}, a surfactant hexadecyltrimethyl ammonium bromide (CTAB) was used to prevent the aggregation of WO{sub 3}. The characterization results obtained by means of X-ray photoelectron spectroscopy (XPS), N{sub 2} adsorption and high-resolution transmission electron microscopy (HRTEM) measurements showed that compared with the catalyst prepared by the conventional impregnation method, the catalyst with the same metal contents prepared by the hydrothermal deposition had much higher W and Ni dispersion, higher specific surface area, larger pore volume, the significantly decreased slab length and slightly increased stacking degree of sulfided W species, leading to the significantly enhanced dibenzothiophene (DBT) hydrodesulfurization (HDS) activity. The DBT HDS assessment results also revealed that the catalyst containing 17.7 wt% WO{sub 3} and 2.4 wt% NiO prepared by the hydrothermal deposition method had the similar DBT HDS activity as a commercial NiW/{gamma}-Al{sub 2}O{sub 3} catalyst containing 23 wt% WO{sub 3} and 2.6 wt% NiO, resulting in the greatly decreased amount of active metals for achieving the same HDS activity. (author)

  8. Friction coefficient and limiter load test analysis by flexibility coefficient model of Hold-Down Spring of nuclear reactor vessel internals

    Energy Technology Data Exchange (ETDEWEB)

    Xie, Linjun [Zhejiang Univ. of Technology, Hangzhou (China). College of Mechanical Engineering; Xue, Guohong; Zhang, Ming [Shanghai Nuclear Engineering Research and Design Institute, Shanghai (China)


    The friction force between the contact surfaces of a reactor internal hold-down spring (HDS) and core barrel flanges can directly influence the axial stiffness of an HDS. However, friction coefficient cannot be obtained through theoretical analysis. This study performs a mathematical deduction of the physical model of an HDS. Moreover, a mathematical model of axial load P, displacement δ, and flexibility coefficient is established, and a set of test apparatuses is designed to simulate the preloading process of the HDS. According to the experimental research and theoretical analysis, P-δ curves and the flexibility coefficient λ are obtained in the loading processes of the HDS. The friction coefficient f of the M1000 HDS is further calculated as 0.224. The displacement limit load value (4,638 kN) can be obtained through a displacement limit experiment. With the friction coefficient considered, the theoretical load is 4,271 kN, which is relatively close to the experimental result. Thus, the friction coefficient exerts an influence on the displacement limit load P. The friction coefficient should be considered in the design analysis for HDS.

  9. Primary Processing

    NARCIS (Netherlands)

    Mulder, W.J.; Harmsen, P.F.H.; Sanders, J.P.M.; Carre, P.; Kamm, B.; Schoenicke, P.


    Primary processing of oil-containing material involves pre-treatment processes, oil recovery processes and the extraction and valorisation of valuable compounds from waste streams. Pre-treatment processes, e.g. thermal, enzymatic, electrical and radio frequency, have an important effect on the oil

  10. Research on friction coefficient of nuclear Reactor Vessel Internals Hold Down Spring: Stress coefficient test analysis method

    Energy Technology Data Exchange (ETDEWEB)

    Linjun, Xie, E-mail: [College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou 310014 (China); Guohong, Xue; Ming, Zhang [Shanghai Nuclear Engineering Research & Design Institute, Shanghai 200233 (China)


    Graphical abstract: HDS stress coefficient test apparatus. - Highlights: • This paper performs mathematic deduction to the physical model of Hold Down Spring (HDS), establishes a mathematic model of axial load P and stress, stress coefficient and friction coefficient and designs a set of test apparatuses for simulating the pretightening process of the HDS for the first time according to a model similarity criterion. • The mathematical relation between the load and the strain is obtained about the HDS, and the mathematical model of the stress coefficient and the friction coefficient is established. So, a set of test apparatuses for obtaining the stress coefficient is designed according to the model scaling criterion and the friction coefficient of the K1000 HDS is calculated to be 0.336 through the obtained stress coefficient. • The relation curve between the theoretical load and the friction coefficient is obtained through analysis and indicates that the change of the friction coefficient f would influence the pretightening load under the condition of designed stress. The necessary pretightening load in the design process is calculated to be 5469 kN according to the obtained friction coefficient. Therefore, the friction coefficient and the pretightening load under the design conditions can provide accurate pretightening data for the analysis and design of the reactor HDS according to the operations. - Abstract: This paper performs mathematic deduction to the physical model of Hold Down Spring (HDS), establishes a mathematic model of axial load P and stress, stress coefficient and friction coefficient and designs a set of test apparatuses for simulating the pretightening process of the HDS for the first time according to a model similarity criterion. By carrying out tests and researches through a stress testing technique, P–σ curves in loading and unloading processes of the HDS are obtained and the stress coefficient k{sub f} of the HDS is obtained. So, the

  11. Elektrokemiske Processer

    DEFF Research Database (Denmark)

    Bech-Nielsen, Gregers


    Electrochemical processes in: Power sources, Electrosynthesis, Corrosion.Pourbaix-diagrams.Decontamination of industrial waste water for heavy metals.......Electrochemical processes in: Power sources, Electrosynthesis, Corrosion.Pourbaix-diagrams.Decontamination of industrial waste water for heavy metals....

  12. Data processing

    CERN Document Server

    Fry, T F


    Data Processing discusses the principles, practices, and associated tools in data processing. The book is comprised of 17 chapters that are organized into three parts. The first part covers the characteristics, systems, and methods of data processing. Part 2 deals with the data processing practice; this part discusses the data input, output, and storage. The last part discusses topics related to systems and software in data processing, which include checks and controls, computer language and programs, and program elements and structures. The text will be useful to practitioners of computer-rel

  13. Process mining

    DEFF Research Database (Denmark)

    van der Aalst, W.M.P.; Rubin, V.; Verbeek, H.M.W.


    Process mining includes the automated discovery of processes from event logs. Based on observed events (e.g., activities being executed or messages being exchanged) a process model is constructed. One of the essential problems in process mining is that one cannot assume to have seen all possible...... behavior. At best, one has seen a representative subset. Therefore, classical synthesis techniques are not suitable as they aim at finding a model that is able to exactly reproduce the log. Existing process mining techniques try to avoid such “overfitting” by generalizing the model to allow for more...

  14. Stochastic processes

    CERN Document Server

    Parzen, Emanuel


    Well-written and accessible, this classic introduction to stochastic processes and related mathematics is appropriate for advanced undergraduate students of mathematics with a knowledge of calculus and continuous probability theory. The treatment offers examples of the wide variety of empirical phenomena for which stochastic processes provide mathematical models, and it develops the methods of probability model-building.Chapter 1 presents precise definitions of the notions of a random variable and a stochastic process and introduces the Wiener and Poisson processes. Subsequent chapters examine

  15. Magnetics Processing (United States)

    Federal Laboratory Consortium — The Magnetics Processing Lab equipped to perform testing of magnetometers, integrate them into aircraft systems, and perform data analysis, including noise reduction...

  16. Design Processes

    DEFF Research Database (Denmark)

    Ovesen, Nis


    Inspiration for most research and optimisations on design processes still seem to focus within the narrow field of the traditional design practise. The focus in this study turns to associated businesses of the design professions in order to learn from their development processes. Through interviews...... advantages and challenges of agile processes in mobile software and web businesses are identified. The applicability of these agile processes is discussed in re- gards to design educations and product development in the domain of Industrial Design and is briefly seen in relation to the concept of dromology...

  17. Three-dimensional interconnected nickel phosphide networks with hollow microstructures and desulfurization performance

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Shuna, E-mail: [College of Textile Engineering, Zhejiang Industry Polytechnic College, Shaoxing 312000 (China); Zhang, Shujuan [College of Science, Tianjin University of Science and Technology, Tianjin 300457 (China); Song, Limin, E-mail: [College of Environment and Chemical Engineering and State Key Laboratory of Hollow-Fiber Membrane Materials and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387 (China); Wu, Xiaoqing [Institute of Composite Materials and Ministry of Education Key Laboratory of Advanced Textile Composite Materials, Tianjin Polytechnic University, Tianjin 300387 (China); Fang, Sheng, E-mail: [College of Environment and Chemical Engineering and State Key Laboratory of Hollow-Fiber Membrane Materials and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387 (China)


    Graphical abstract: Three-dimensional interconnected nickel phosphide networks with hollow microstructures and desulfurization performance. - Highlights: • Three-dimensional Ni{sub 2}P has been prepared using foam nickel as a template. • The microstructures interconnected and formed sponge-like porous networks. • Three-dimensional Ni{sub 2}P shows superior hydrodesulfurization activity. - Abstract: Three-dimensional microstructured nickel phosphide (Ni{sub 2}P) was fabricated by the reaction between foam nickel (Ni) and phosphorus red. The as-prepared Ni{sub 2}P samples, as interconnected networks, maintained the original mesh structure of foamed nickel. The crystal structure and morphology of the as-synthesized Ni{sub 2}P were characterized by X-ray diffraction, scanning electron microscopy, automatic mercury porosimetry and X-ray photoelectron spectroscopy. The SEM study showed adjacent hollow branches were mutually interconnected to form sponge-like networks. The investigation on pore structure provided detailed information for the hollow microstructures. The growth mechanism for the three-dimensionally structured Ni{sub 2}P was postulated and discussed in detail. To investigate its catalytic properties, SiO{sub 2} supported three-dimensional Ni{sub 2}P was prepared successfully and evaluated for the hydrodesulfurization (HDS) of dibenzothiophene (DBT). DBT molecules were mostly hydrogenated and then desulfurized by Ni{sub 2}P/SiO{sub 2}.

  18. Information processing

    NARCIS (Netherlands)

    Jong, de Peter J.; Emmelkamp, Paul; Ehring, Thomas


    Cognitive models imply that emotional disorders critically depend on the existence of maladaptive cognitive structures in memory. These so-called schemas are assumed to automatically influence all stages of individuals' information processing. The basic assumption of the information-processing

  19. Food processing

    NARCIS (Netherlands)

    Teodorowicz, Malgorzata; Neerven, Van Joost; Savelkoul, Huub


    The majority of foods that are consumed in our developed society have been processed. Processing promotes a non-enzymatic reaction between proteins and sugars, the Maillard reaction (MR). Maillard reaction products (MRPs) contribute to the taste, smell and color of many food products, and thus

  20. Sustainable processing

    DEFF Research Database (Denmark)

    Kristensen, Niels Heine


    Kristensen_NH and_Beck A: Sustainable processing. In Otto Schmid, Alexander Beck and Ursula Kretzschmar (Editors) (2004): Underlying Principles in Organic and "Low-Input Food" Processing - Literature Survey. Research Institute of Organic Agriculture FiBL, CH-5070 Frick, Switzerland. ISBN 3-906081-58-3...

  1. Image processing

    NARCIS (Netherlands)

    van der Heijden, Ferdinand; Spreeuwers, Lieuwe Jan; Blanken, Henk; Vries de, A.P.; Blok, H.E.; Feng, L; Feng, L.


    The field of image processing addresses handling and analysis of images for many purposes using a large number of techniques and methods. The applications of image processing range from enhancement of the visibility of cer- tain organs in medical images to object recognition for handling by

  2. Organizing Process

    DEFF Research Database (Denmark)

    Hull Kristensen, Peer; Bojesen, Anders

    This paper invites to discuss the processes of individualization and organizing being carried out under what we might see as an emerging regime of change. The underlying argumentation is that in certain processes of change, competence becomes questionable at all times. The hazy characteristics...

  3. Process Fragments (United States)

    Eberle, Hanna; Unger, Tobias; Leymann, Frank

    The concepts presented in this paper are motivated by the assumption that process knowledge is distributed knowledge and not completely known just by one person. Driven by this assumption we deal in this paper with the following questions: How can partial process knowledge be represented? How can this partial knowledge be used to define something more complete? To use higher level artefacts as building blocks to new applications has a long tradition in software engineering to increase flexibility and reduce modeling costs. In this paper we take a first step in applying this concept to processes, by defining process building blocks and operations which compose process building blocks. The building blocks will be referred to as process fragments in the following. The process fragment composition may take place either at design or runtime of the process. The design time approach reduces design costs by reusing artefacts. However the runtime fragment composition approach realizes high flexibility due to the possibility in the dynamic selection of the fragments to be composed. The contribution of this work lies in a fragment definition that enables the fragment modeler to represent his 'local' and fragmentary knowledge in a formal way and which allows fragment models to be composed.

  4. Membrane processes (United States)

    Staszak, Katarzyna


    The membrane processes have played important role in the industrial separation process. These technologies can be found in all industrial areas such as food, beverages, metallurgy, pulp and paper, textile, pharmaceutical, automotive, biotechnology and chemical industry, as well as in water treatment for domestic and industrial application. Although these processes are known since twentieth century, there are still many studies that focus on the testing of new membranes' materials and determining of conditions for optimal selectivity, i. e. the optimum transmembrane pressure (TMP) or permeate flux to minimize fouling. Moreover the researchers proposed some calculation methods to predict the membrane processes properties. In this article, the laboratory scale experiments of membrane separation techniques, as well their validation by calculation methods are presented. Because membrane is the "heart" of the process, experimental and computational methods for its characterization are also described.

  5. Magnetic edge states in MoS2 characterized using density-functional theory

    DEFF Research Database (Denmark)

    Vojvodic, Aleksandra; Hinnemann, B.; Nørskov, Jens Kehlet


    It is known that the edges of a two-dimensional slab of insulating MoS2 exhibit one-dimensional metallic edge states, the so-called "brim states." Here, we find from density-functional theory calculations that several edge structures, which are relevant for the hydrodesulfurization process......, are magnetic. The magnetism is an edge phenomenon associated with certain metallic edge states. Interestingly, we find that among the two low-index edges, only the S edge displays magnetism under hydrodesulfurization conditions. In addition, the implications of this on the catalytic activity are investigated...

  6. Sewer Processes

    DEFF Research Database (Denmark)

    Hvitved-Jacobsen, Thorkild; Vollertsen, Jes; Nielsen, Asbjørn Haaning

    Since the first edition was published over a decade ago, advancements have been made in the design, operation, and maintenance of sewer systems, and new problems have emerged. For example, sewer processes are now integrated in computer models, and simultaneously, odor and corrosion problems caused...... by hydrogen sulfide and other volatile organic compounds, as well as other potential health issues, have caused environmental concerns to rise. Reflecting the most current developments, Sewer Processes: Microbial and Chemical Process Engineering of Sewer Networks, Second Edition, offers the reader updated...... and valuable information on the sewer as a chemical and biological reactor. It focuses on how to predict critical impacts and control adverse effects. It also provides an integrated description of sewer processes in modeling terms. This second edition is full of illustrative examples and figures, includes...

  7. Electrochemical Processes

    DEFF Research Database (Denmark)

    Bech-Nielsen, Gregers


    The notes describe in detail primary and secondary galvanic cells, fuel cells, electrochemical synthesis and electroplating processes, corrosion: measurments, inhibitors, cathodic and anodic protection, details of metal dissolution reactions, Pourbaix diagrams and purification of waste water from...

  8. Processing Proteases

    DEFF Research Database (Denmark)

    Ødum, Anders Sebastian Rosenkrans

    Processing proteases are proteases which proteolytically activate proteins and peptides into their biologically active form. Processing proteases play an important role in biotechnology as tools in protein fusion technology. Fusion strategies where helper proteins or peptide tags are fused...... to the protein of interest are an elaborate method to optimize expression or purification systems. It is however critical that fusion proteins can be removed and processing proteases can facilitate this in a highly specific manner. The commonly used proteases all have substrate specificities to the N......-terminal of the scissile bond, leaving C-terminal fusions to have non-native C-termini after processing. A solution yielding native C-termini would allow novel expression and purification systems for therapeutic proteins and peptides.The peptidyl-Lys metallopeptidase (LysN) of the fungus Armillaria mellea (Am) is one...

  9. Gamma Processes (United States)


    coupling two Gamma processes so that the marginal processes will have negative serial correlations. It is actually easier to implement this analyze a long sequence of wind speeds. This sequence is very non-stationary, containing yearly cycles. The model actually used is v(n)G n , where P...1967). "Some Problems of Statistical Inference Relating to Double-Gamma Distribution," Trabajos de Estadistica , 18, 67-87. Hugus, D. K. (1982

  10. Renewal processes

    CERN Document Server

    Mitov, Kosto V


    This monograph serves as an introductory text to classical renewal theory and some of its applications for graduate students and researchers in mathematics and probability theory. Renewal processes play an important part in modeling many phenomena in insurance, finance, queuing systems, inventory control and other areas. In this book, an overview of univariate renewal theory is given and renewal processes in the non-lattice and lattice case are discussed. A pre-requisite is a basic knowledge of probability theory.

  11. Process development for the separation and recovery of Mo and Co from chloride leach liquors of petroleum refining catalyst by solvent extraction

    Energy Technology Data Exchange (ETDEWEB)

    Banda, Raju [Department of Advanced Material Science and Engineering, Mokpo National University, Chonnam 534-729 (Korea, Republic of); Sohn, Seong Ho [Korea Institute of Industrial Technology, Incheon Technology Service Centre, 7-47, Songdo-dong, Incheon 406-840 (Korea, Republic of); Lee, Man Seung, E-mail: [Department of Advanced Material Science and Engineering, Mokpo National University, Chonnam 534-729 (Korea, Republic of)


    Highlights: Black-Right-Pointing-Pointer Separation of Mo and Co from HCl solution was investigated by solvent extraction. Black-Right-Pointing-Pointer The solution was synthetic leaching solution of spent HDS catalysts. Black-Right-Pointing-Pointer Extraction with TOPO led to complete separation of Mo. Black-Right-Pointing-Pointer Alamine 308 can separate Co from the Mo free raffinate. Black-Right-Pointing-Pointer Recovery percentage of both metals was higher than 99%. - Abstract: The separation and recovery of Mo and Co from the synthetic chloride leach liquors of petroleum refining catalyst has been investigated by employing TOPO and Alamine 308 as extractants. The synthetic leach liquor contained Mo 394 mg/L, Al 1782 mg/L, Co 119 mg/L in 3 M HCl. The separation of Mo from Co and Al was achieved with 0.05 M TOPO in Escaid 110 and complete stripping of Mo was attained with combination of 0.1 M NH{sub 4}OH and 0.05 M (NH{sub 4}){sub 2}CO{sub 3}. After separation of molybdenum, cobalt can be selectively extracted by Alamine 308 from Mo free raffinate after adjusting the concentration of chloride ion to 5 M by adding AlCl{sub 3}. The back-extraction of cobalt was obtained easily from loaded Alamine 308 with acidified water (pH = 1.0). McCabe-Thiele diagrams were constructed from the extraction and stripping experiments of each element (Mo and Co). From the batch simulation of the counter-current extraction and stripping experiments, it was confirmed that Mo and Co recovery of 99.4% and 99.1% respectively was obtained from the synthetic leach liquor of the chloride solutions. Finally a hydrometallurgical process flow sheet was developed.

  12. FLUORINATION PROCESS (United States)

    McMillan, T.S.


    A process for the fluorination of uranium metal is described. It is known that uranium will react with liquid chlorine trifluoride but the reaction proceeds at a slow rate. However, a mixture of a halogen trifluoride together with hydrogen fluoride reacts with uranium at a significantly faster rate than does a halogen trifluoride alone. Bromine trifluoride is suitable for use in the process, but chlorine trifluoride is preferred. Particularly suitable is a mixture of ClF/sub 3/ and HF having a mole ratio (moles

  13. Modeling of a three-phase reactor for bitumen-derived gas oil hydrotreating

    Energy Technology Data Exchange (ETDEWEB)

    Chacon, R.; Canale, A.; Bouza, A. [Departamento de Termodinamica y Fenomenos de Transporte. Universidad Simon Bolivar, Caracas (Venezuela, Bolivarian Republic of); Sanchez, Y. [Departamento de Procesos y Sistemas. Universidad Simon Bolivar (Venezuela, Bolivarian Republic of)


    A three-phase reactor model for describing the hydrotreating reactions of bitumen-derived gas oil was developed. The model incorporates the mass-transfer resistance at the gas-liquid and liquid-solid interfaces and a kinetic rate expression based on a Langmuir-Hinshelwood-type model. We derived three correlations for determining the solubility of hydrogen (H{sub 2}), hydrogen sulfide (H{sub 2}S) and ammonia (NH{sub 3}) in hydrocarbon mixtures and the calculation of the catalyst effectiveness factor was included. Experimental data taken from the literature were used to determine the kinetic parameters (stoichiometric coefficients, reaction orders, reaction rate and adsorption constants for hydrodesulfuration (HDS) and hydrodenitrogenation (HDN)) and to validate the model under various operating conditions. Finally, we studied the effect of operating conditions such as pressure, temperature, LHSV, H{sub 2}/feed ratio and the inhibiting effect of H{sub 2}S on HDS and NH{sub 3} on HDN. (author)

  14. Innovation process

    DEFF Research Database (Denmark)

    Kolodovski, A.


    Purpose of this report: This report was prepared for RISO team involved in design of the innovation system Report provides innovation methodology to establish common understanding of the process concepts and related terminology The report does not includeRISO- or Denmark-specific cultural, economic...

  15. Processing Determinism (United States)

    O'Grady, William


    I propose that the course of development in first and second language acquisition is shaped by two types of processing pressures--internal efficiency-related factors relevant to easing the burden on working memory and external input-related factors such as frequency of occurrence. In an attempt to document the role of internal factors, I consider…


    Directory of Open Access Journals (Sweden)

    Anamarija Kutlić


    Full Text Available Bentonite has vide variety of uses. Special use of bentonite, where its absorbing properties are employed to provide water-tight sealing is for an underground repository in granites In this paper, bentonite processing and beneficiation are described.

  17. Arobin process

    Energy Technology Data Exchange (ETDEWEB)

    Welz, H.


    The Arobin (Aromatenbenzin = aromatic gasoline) process was developed to operate on highly aromatic residues from various other processes (especially the HF process) for production of aviation gasoline and similar fuels. Those residues generally had boiling points from about 165/sup 0/ to 325/sup 0/C, so they were not included in the gasoline mde by the other processes. The Arobin process was able to split these residues into lower-boiling-point compounds which made up a high-performance gasoline containing 70% to 75% aromatics by volume. In order to accomplish this, it was necessary to choose the proper catalyst, one in which the splitting effect was much more pronounced than the hydrogenating effect. The catalyst which seemed to be most effective was an alkali-free aluminum silicate with small amounts (1%) molybdic acid (MoO/sub 3/) added. (An aluminum oxide catalyst used at about 500/sup 0/C produced even higher percentages of aromatics, but it seemed best suited for production of single pure compounds such as toluene.) The Arobin process was carried out at about 200 atm pressure and 400/sup 0/C, with a ratio of 1:1 for fresh starting material to recycled material and a throughput of 1 kg per liter of catalyst per hour. The overall yield of gasoline distilled up to 165/sup 0/C was 85% to 87%, and the time-yield was 0.43 kg per liter of catalyst per hour; the process used 360 m/sup 3/ hydrogen and 200 Calories of heat per (metric) ton of product gasoline. The Arobin gasoline could be blended with a lower-octane aviation gasoline to produce a blend with 50% aromatics; in this way, one (metric) ton of HF residue could give rise to 1.2 tons of such blended gasoline. The oxide catalyst could generally be regenerated by a heated steam of nitrogen diluted with air, unless damaged by certain nitrogen or oxygen compounds. 1 diagram, 3 tables.

  18. Highly active sulfided CoMo catalysts supported on (ZrO{sub 2}–TiO{sub 2})/Al{sub 2}O{sub 3} ternary oxides

    Energy Technology Data Exchange (ETDEWEB)

    Escobar, José, E-mail: [Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas 152, Col. San Bartolo Atepehuacan, Gustavo A. Madero, México, D.F. 07730 (Mexico); De Los Reyes, José A., E-mail: [Area de Ing. Química, UAM – Iztapalapa, San Rafael Atlixco 186, Col. Vicentina, Iztapalapa, México, D.F. 09340 (Mexico); Ulín, Carlos A. [Area de Ing. Química, UAM – Iztapalapa, San Rafael Atlixco 186, Col. Vicentina, Iztapalapa, México, D.F. 09340 (Mexico); Barrera, María C., E-mail: [Facultad de Ciencias Químicas, Universidad Veracruzana, Av. Universidad km. 7.5, Col. Santa Isabel, Coatzacoalcos, Veracruz, México, D.F. 96538 (Mexico)


    (ZrO{sub 2}–TiO{sub 2})/Al{sub 2}O{sub 3} ternary oxide at 20 mol% Al{sub 2}O{sub 3} (80% ZrO{sub 2}–TiO{sub 2}, in turn at 40–60 mol ratio) prepared by controlled co-precipitation (by urea thermal decomposition) of zirconium (ZrOCl{sub 2}·8H{sub 2}O) and titanium (TiCl{sub 4}) chlorides over a ground alumina substrate constitutes a promising material to be used as carrier of sulfided hydrodesulfurization (HDS) catalysts. After calcining (at 500 °C), the ternary oxide presented textural properties (S{sub g} = 387 m{sup 2} g{sup −1}, V{sub p} = 0.74 ml g{sup −1}, mean pore diameter = 7.6 nm) suitable to its utilization as carrier of catalysts applied in the oil-derived middle distillates HDS. As determined by temperature programmed-reduction and Raman and UV–vis spectroscopies ZrO{sub 2}–TiO{sub 2} deposition over alumina substrate resulted in decreased proportion of Mo{sup 6+} species in tetrahedral coordination on the oxidic impregnated material. As those species constitute hardly reducible precursors, their diminished concentration could be reflected in enhanced amount of Mo species susceptible of activation by sulfiding (H{sub 2}S/H{sub 2} at 400 °C) over our ternary carrier. Limiting the concentration of zirconia-titania (at 40–60 mol ratio) to 20 mol% in the mixed oxides support allowed the preparation of highly active promoted (by cobalt, at Co/(Co + Mo) = 0.3) MoS{sub 2} phase (at 2.8 atoms/nm{sup 2}), that formulation showing excellent properties in hydrodesulfurization (HDS) of both dibenzothiophene and highly-refractory 4,6-dimethyl-dibenzothiophene. Due to alike yields to various HDS products over CoMo/(ZrO{sub 2}–TiO{sub 2})/Al{sub 2}O{sub 3} and the corresponding Al{sub 2}O{sub 3}-supported formulation, presence of similar actives sites over those catalysts was strongly suggested. It seemed that enhanced concentration of octahedral Mo{sup 6+} over the oxidic impregnated precursor with (ZrO{sub 2}–TiO{sub 2})/Al{sub 2}O{sub 3

  19. Stochastic processes

    CERN Document Server

    Borodin, Andrei N


    This book provides a rigorous yet accessible introduction to the theory of stochastic processes. A significant part of the book is devoted to the classic theory of stochastic processes. In turn, it also presents proofs of well-known results, sometimes together with new approaches. Moreover, the book explores topics not previously covered elsewhere, such as distributions of functionals of diffusions stopped at different random times, the Brownian local time, diffusions with jumps, and an invariance principle for random walks and local times. Supported by carefully selected material, the book showcases a wealth of examples that demonstrate how to solve concrete problems by applying theoretical results. It addresses a broad range of applications, focusing on concrete computational techniques rather than on abstract theory. The content presented here is largely self-contained, making it suitable for researchers and graduate students alike.

  20. Processing Branches

    DEFF Research Database (Denmark)

    Schindler, Christoph; Tamke, Martin; Tabatabai, Ali


    Angled and forked wood – a desired material until 19th century, was swept away by industrialization and its standardization of processes and materials. Contemporary information technology has the potential for the capturing and recognition of individual geometries through laser scanning and compu......Angled and forked wood – a desired material until 19th century, was swept away by industrialization and its standardization of processes and materials. Contemporary information technology has the potential for the capturing and recognition of individual geometries through laser scanning...... and computation and subsequently design and bespoke CNC fabrication. The question whether this allows for a new approach to the uniqueness that is offered to us by nature is discussed in a series of workshops and projects, which explore the performative potential of naturally grown materials....

  1. Optical Processing. (United States)


    and evaluation of technologies suitable for discrete optical computing is described, where particular emphasis has applied to ZnSe non- linea :, and...met. The processes are similar to that used in proving an algebraic theorem. Among the daunting practical difficulties encount- ered are:- (a) Formal...implementation of algorithms. Usually, such algorithms exhibit a highly regular S- structure as typified by linear algebra problems, and are generally

  2. Residue processing

    Energy Technology Data Exchange (ETDEWEB)

    Gieg, W.; Rank, V.


    In the first stage of coal hydrogenation, the liquid phase, light and heavy oils were produced; the latter containing the nonliquefied parts of the coal, the coal ash, and the catalyst substances. It was the problem of residue processing to extract from these so-called let-down oils that which could be used as pasting oils for the coal. The object was to obtain a maximum oil extraction and a complete removal of the solids, because of the latter were returned to the process they would needlessly burden the reaction space. Separation of solids in residue processing could be accomplished by filtration, centrifugation, extraction, distillation, or low-temperature carbonization (L.T.C.). Filtration or centrifugation was most suitable since a maximum oil yield could be expected from it, since only a small portion of the let-down oil contained in the filtration or centrifugation residue had to be thermally treated. The most satisfactory centrifuge at this time was the Laval, which delivered liquid centrifuge residue and centrifuge oil continuously. By comparison, the semi-continuous centrifuges delivered plastic residues which were difficult to handle. Various apparatus such as the spiral screw kiln and the ball kiln were used for low-temperature carbonization of centrifuge residues. Both were based on the idea of carbonization in thin layers. Efforts were also being made to produce electrode carbon and briquette binder as by-products of the liquid coal phase.

  3. Sciencecraft process (United States)

    Beauchamp, Patricia M.; Alkalai, Leon; Brown, Robert H.; Capps, Richard W.; Chen, Gun-Shing; Crisp, Michael P.; Cutts, James A.; Davidson, J. M.; Petrick, Stanley W.; Rodgers, David H.; Vane, Gregg; Soderblom, Laurance A.; Yelle, Roger V.


    In this paper, the authors propose a new process for the development and operation of unmanned vehicles for the exploration of space. We call the vehicle (and the process used to create it) sciencecraft. A Sciencecraft is an integrated unit that combines into a single system those elements (but no more) which are necessary to achieve the science objectives of the mission, including science instruments, electronics, telecommunications, power, and propulsion. the design of a sciencecraft begins with the definition of the mission science objectives. This is followed by the establishment of measurement goals and the definition of a critical data set. Next an observational sequence is developed, which will provide the data set. This step is followed by the design of the integrated sensor system that will make the observations. The final step in the development of a sciencecraft is the design of the hardware subsystems needed to deliver the sensor to its target and return the science data to the earth. This approach assures that the sciencecraft hardware design and overall architecture will be driven by the science objectives and the sensor requirements rather than the reverse, as has historically been the case. Throughout the design process, there is an emphasis on shared functionality, shared redundancy, and reduced cost. We illustrate the power of the sciencecraft approach by describing the Planetary Integrated Camera Spectrometer (PICS), an integrated sensor system in which the 'sciencecraft' process has been applied to the development of a single subsystem, which integrates multiple functionalities. PICS is a case-in-point where the sciencecraft process has been successfully demonstrated. We then describe a sciencecraft mission for exploration of the outer Solar System, including flybys of Uranus, Neptune, and an object in the Kuiper Belt. This mission, called the Kuiper Express, will use solar electric propulsion to shape its trajectory in the inner solar system

  4. Heterolytic Activation of Hydrogen Promoted by Ruthenium Nanoparticles immobilized on Basic Supports and Hydrogenation of Aromatic Compounds (United States)

    Fang, Minfeng

    Despite the aggressive development and deployment of new renewable and nuclear technologies, petroleum-derived transportation fuels---gasoline, diesel and jet fuels---will continue to dominate the markets for decades. Environmental legislation imposes severe limits on the tolerable proportion of aromatics, sulfur and nitrogen contents in transportation fuels, which is difficult to achieve with current refining technologies. Catalytic hydrogenation plays an important role in the production of cleaner fuels, both as a direct means to reduce the aromatics and as a key step in the hydrodenitrogenation (HDN) and hydrodesulfurization (HDS) processes. However, conventional catalysts require drastic conditions and/or are easily poisoned by S or N aromatics. Therefore, there is still a need for new efficient catalysts for hydrogenation reactions relevant to the production of cleaner fossil fuels. Our catalyst design involves metallic nanoparticles intimately associated with a basic support, with the aim of creating a nanostructure capable of promoting the heterolytic activation of hydrogen and ionic hydrogenation mechanisms, as a strategy to avoid catalyst poisoning and enhance catalytic activity. We have designed and prepared a new nanostructured catalytic material composed of RuNPs immobilized on the basic polymer P4VPy. We have demonstrated that the Ru/P4VPy catalyst can promote heterolytic hydrogen activation and a unique surface ionic hydrogenation mechanism for the efficient hydrogenation of N-aromatics. This is the first time these ionic hydrogenation pathways have been demonstrated on solid surfaces. For the RuNPs surfaces without basic sites in close proximity, the conventional homolytic H2 splitting is otherwise involved. Using the mechanistic concepts from Ru/P4VPy, we have designed and prepared the Ru/MgO catalyst, with the aim to improve the catalytic efficiency for the hydrogenation of heteroatom aromatics operating by the ionic hydrogenation mechanism. The Ru

  5. Offshoring Process

    DEFF Research Database (Denmark)

    Slepniov, Dmitrij; Sørensen, Brian Vejrum; Katayama, Hiroshi


    The purpose of this chapter is to contribute to the knowledge on how production offshoring and international operations management vary across cultural contexts. The chapter attempts to shed light on how companies approach the process of offshoring in different cultural contexts. In order...... to achieve this objective, the authors employ a qualitative methodology and compare three Danish and three Japanese manufacturing companies. On the basis of this comparative investigation, the authors find that the parent companies from both contexts employ offshoring as a remedy for the challenges...

  6. Shared processes

    Directory of Open Access Journals (Sweden)

    María Auxiliadora Gálvez Pérez


    Full Text Available AbstractThe comparison between the creative processes in dance and architecture constitute a panorama, which is able to fi gure out reality with different and intense perceptive connotations. It is about a reality where the important thing is the immersion into the spatial-temporal phenomena, the contact of the space of our body and the spatial essence that is outside our skin limits. Under an architectonical point of view, dance would be a key  discipline, a laboratory where it is possible to freely explore the concepts related to the body-space system, consequently it is also a good frame to seek the necessary tools to work with them. One of the most important examples of this laboratory consolidated in the intersection of choreographical, and architectonical processes is the collaboration betweenLawrence Halprin, landscape architect, and Anna Halprin, choreographer. Through the direct experience of the body in space, they will develop notations and creative cycles able to work with the material of this expanded perception of reality. The review of these creative cycles tested mainly in the sixties is nowadays specially appropriated, when diverse branches of philosophy rooted in phenomenology are interested precisely in dance and architecture as key territories. It seems that it is the opportune moment to expand the architectonical tools, which have been implemented till now, following phenomenological concerns.

  7. Markov processes

    CERN Document Server

    Kirkwood, James R


    Review of ProbabilityShort HistoryReview of Basic Probability DefinitionsSome Common Probability DistributionsProperties of a Probability DistributionProperties of the Expected ValueExpected Value of a Random Variable with Common DistributionsGenerating FunctionsMoment Generating FunctionsExercisesDiscrete-Time, Finite-State Markov ChainsIntroductionNotationTransition MatricesDirected Graphs: Examples of Markov ChainsRandom Walk with Reflecting BoundariesGambler’s RuinEhrenfest ModelCentral Problem of Markov ChainsCondition to Ensure a Unique Equilibrium StateFinding the Equilibrium StateTransient and Recurrent StatesIndicator FunctionsPerron-Frobenius TheoremAbsorbing Markov ChainsMean First Passage TimeMean Recurrence Time and the Equilibrium StateFundamental Matrix for Regular Markov ChainsDividing a Markov Chain into Equivalence ClassesPeriodic Markov ChainsReducible Markov ChainsSummaryExercisesDiscrete-Time, Infinite-State Markov ChainsRenewal ProcessesDelayed Renewal ProcessesEquilibrium State f...

  8. Modelling of an adiabatic trickle-bed reactor with phase change

    DEFF Research Database (Denmark)

    Ramirez Castelan, Carlos Eduardo; Hidalgo-Vivas, Angelica; Brix, Jacob


    This paper describes a modelling approach of the behavior of trickle-bed reactors used for catalytic hydrotreating of oil fractions. A dynamic plug-flow heterogeneous one-dimensional adiabatic model was used to describe the main reactions present in the hydrotreating process: hydrodesulfurization...

  9. Facile synthesis of hierarchical double-shell WO{sub 3} microspheres with enhanced photocatalytic activity

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhenfeng [College of Environment and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387 (China); State Key Laboratory of Hollow-Fiber Membrane Materials and Membrane Processes, Tianjin 300387 (China); Chu, Deqing, E-mail: [College of Environment and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387 (China); State Key Laboratory of Hollow-Fiber Membrane Materials and Membrane Processes, Tianjin 300387 (China); Wang, Limin, E-mail: [School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387 (China); State Key Laboratory of Hollow-Fiber Membrane Materials and Membrane Processes, Tianjin 300387 (China); Wang, Lipeng [School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387 (China); Hu, Wenhui; Chen, Xiangyu; Yang, Huifang [College of Environment and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387 (China); Sun, Jingjing [School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387 (China)


    Highlights: • HDS-WO{sub 3} were fabricated via mild process. • A possible growth mechanism for HDS-WO{sub 3} is proposed. • The excellent photocatalytic activity is attributed to the larger surface area of the HDS-WO{sub 3} nanostructures. - Abstract: Hierarchical double-shell WO{sub 3} microspheres (HDS-WO{sub 3}) have been successfully obtained through the thermal decomposition of WO{sub 3}·H{sub 2}O formed by metal salts as the templates. The products were characterized by X-ray diffraction (XRD), and the morphology was investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). In addition, the HDS-WO{sub 3} microspheres were analyzed by the Thermogravimetric (TG) and Brunauer-Emmett-Teller (BET) analysis. The synthetic mechanism of the products with hierarchical structures was proposed. The obtained HDS-WO{sub 3} exhibits excellent photocatalytic efficiency (84.9%), which is much higher than other WO{sub 3} sample under visible light illumination.

  10. Crystallization process (United States)

    Adler, Robert J.; Brown, William R.; Auyang, Lun; Liu, Yin-Chang; Cook, W. Jeffrey


    An improved crystallization process is disclosed for separating a crystallizable material and an excluded material which is at least partially excluded from the solid phase of the crystallizable material obtained upon freezing a liquid phase of the materials. The solid phase is more dense than the liquid phase, and it is separated therefrom by relative movement with the formation of a packed bed of solid phase. The packed bed is continuously formed adjacent its lower end and passed from the liquid phase into a countercurrent flow of backwash liquid. The packed bed extends through the level of the backwash liquid to provide a drained bed of solid phase adjacent its upper end which is melted by a condensing vapor.

  11. Lithospheric processes

    Energy Technology Data Exchange (ETDEWEB)

    Baldridge, W. [and others


    The authors used geophysical, geochemical, and numerical modeling to study selected problems related to Earth's lithosphere. We interpreted seismic waves to better characterize the thickness and properties of the crust and lithosphere. In the southwestern US and Tien Shari, crust of high elevation is dynamically supported above buoyant mantle. In California, mineral fabric in the mantle correlate with regional strain history. Although plumes of buoyant mantle may explain surface deformation and magmatism, our geochemical work does not support this mechanism for Iberia. Generation and ascent of magmas remains puzzling. Our work in Hawaii constrains the residence of magma beneath Hualalai to be a few hundred to about 1000 years. In the crust, heat drives fluid and mass transport. Numerical modeling yielded robust and accurate predictions of these processes. This work is important fundamental science, and applies to mitigation of volcanic and earthquake hazards, Test Ban Treaties, nuclear waste storage, environmental remediation, and hydrothermal energy.

  12. WELDING PROCESS (United States)

    Zambrow, J.; Hausner, H.


    A method of joining metal parts for the preparation of relatively long, thin fuel element cores of uranium or alloys thereof for nuclear reactors is described. The process includes the steps of cleaning the surfaces to be jointed, placing the sunfaces together, and providing between and in contact with them, a layer of a compound in finely divided form that is decomposable to metal by heat. The fuel element members are then heated at the contact zone and maintained under pressure during the heating to decompose the compound to metal and sinter the members and reduced metal together producing a weld. The preferred class of decomposable compounds are the metal hydrides such as uranium hydride, which release hydrogen thus providing a reducing atmosphere in the vicinity of the welding operation.

  13. Dairy processing. (United States)

    Bailey, Kenneth W


    The United States dairy processing sector is dynamic and adaptive to new changes in the market place. Changes in consumer preferences and manufacturing technologies are resulting in new challenges to the processing sector. Consumers want a wider array of quality dairy products. Fluid processors are adapting to changing consumer demands for beverage products by introducing new flavors, providing ultrapasteurization, and using creative packaging. In addition, United States food manufacturers are requesting dairy processors to provide new dairy fractions such as MPC for new nutrition products. United States dairy policy is attempting to adapt to these changes. Federal order reform has resulted in new market-oriented signals for dairy farmers to produce what the market wants; namely, quality milk components. US dairy farmers, however, also wants to maintain programs such as the DPSP that have had the unfortunate consequence of spurring demand for protein imports (i.e., MPCs, casein, and caseinates) and also resulted in a disincentive to produce these new innovative protein products here in the United States. Surplus skim milk solids are now moving into US Government warehouses rather than into commercial markets. The future of the United States dairy industry will clearly be toward producing innovative products that the market wants. There is a strong market for dairy products not only here in the United States but also overseas, which will mean learning to compete on a global scale. The challenge is to modernize our United States milk pricing programs to provide dairy farmers and processors proper price signals while providing a minimum level of support to dairy farmers. The benefit of a greater orientation toward the market place will be stronger rates of growth for United States-produced dairy products.

  14. Information Processing - Administrative Data Processing (United States)

    Bubenko, Janis

    A three semester, 60-credit course package in the topic of Administrative Data Processing (ADP), offered in 1966 at Stockholm University (SU) and the Royal Institute of Technology (KTH) is described. The package had an information systems engineering orientation. The first semester focused on datalogical topics, while the second semester focused on the infological topics. The third semester aimed to deepen the students’ knowledge in different parts of ADP and at writing a bachelor thesis. The concluding section of this paper discusses various aspects of the department’s first course effort. The course package led to a concretisation of our discipline and gave our discipline an identity. Our education seemed modern, “just in time”, and well adapted to practical needs. The course package formed the first concrete activity of a group of young teachers and researchers. In a forty-year perspective, these people have further developed the department and the topic to an internationally well-reputed body of knowledge and research. The department has produced more than thirty professors and more than one hundred doctoral degrees.


    Directory of Open Access Journals (Sweden)

    Engin GÜRTEKİN


    Full Text Available Biological wastewater treatment is not effective treatment method if raw wastewater contains toxic and refractory organics. Advanced oxidation processes are applied before or after biological treatment for the detoxification and reclamation of this kind of wastewaters. The advanced oxidation processes are based on the formation of powerful hydroxyl radicals. Among advanced oxidation processes Fenton process is one of the most promising methods. Because application of Fenton process is simple and cost effective and also reaction occurs in a short time period. Fenton process is applied for many different proposes. In this study, Fenton process was evaluated as an advanced oxidation process in wastewater treatment.

  16. Sites and reactivity of sulfides in hydro-treatment catalysis: theoretical ab-initio study; Sites et reactivite des sulfures en catalyse d`hydrotraitement: etude theorique ab-initio

    Energy Technology Data Exchange (ETDEWEB)

    Raybaud, P.


    Ab-initio calculations within the DFT and GGA have been carried out in an attempt to understand better which property sets the activity of transition metal sulfides (TMS) in the hydro-desulfurization reaction (HDS), a most important step in the refining of crude oil. A systematic study of the structural cohesive and electronic properties of more than thirty bulk TMS has allowed us to find a new simple relationship between the experimental catalytic activities known in HDS, and the properly defined sulfur-metal (S-M) bond energy. On this volcano curve reminiscent of the Sabatier principles, ionic metallic sulfides (as Ni{sub 3}S{sub 2}, Ci{sub 9}S{sub 8}) exhibit the weakest bonds whereas ion-covalent semi-conductors (as MoS{sub 2}) exhibit the strongest bonds: the highest activities correspond to intermediate bond strengths (RuS{sub 2}). Our study of the electronic structure of the MoS{sub 2} edge surfaces has revealed acceptor surface states localized on Coordinatively Unsaturated Mo ions and the significance of those states for the activation of hetero-aromatic molecules like thiophene. On such surfaces, the energetic profiles we establish for the thiophene HDS reaction point out the surface anionic vacancy regeneration steps as rate determining. We have calculated the optimal positions of Co (Ni) in decoration on the MoS{sub 2} edge planes, in excellent agreement with available EXAFS data on real catalysts. Introducing the promoter Co (Ni) induces a lower optimal sulfur coverage and a lower surface S-M bond strength in proportion of the Co (Ni) coverage, and lower for Ni than for Co. Simplified energy profiles for the thiophene HDS reactions on promoted (101-bar 0) surfaces show that the C-S scission step is likely to become rate determining. Our results show altogether that bulk and surface S-M strengths in TMS systems show similar trends, insofar as they are primarily determined by the local electronic structure. (author)

  17. Management of processes of electrochemical dimensional processing (United States)

    Akhmetov, I. D.; Zakirova, A. R.; Sadykov, Z. B.


    In different industries a lot high-precision parts are produced from hard-processed scarce materials. Forming such details can only be acting during non-contact processing, or a minimum of effort, and doable by the use, for example, of electro-chemical processing. At the present stage of development of metal working processes are important management issues electrochemical machining and its automation. This article provides some indicators and factors of electrochemical machining process.

  18. Studies on process synthesis and process integration


    Fien, Gert-Jan A. F.


    This thesis discusses topics in the field of process engineering that have received much attention over the past twenty years: (1) conceptual process synthesis using heuristic shortcut methods and (2) process integration through heat-exchanger networks and energy-saving power and refrigeration systems. The shortcut methods for conceptual process synthesis presented in Chapter 2, utilize Residue Curve Maps in ternary diagrams and are illustrated with examples of processes...

  19. Extensible packet processing architecture (United States)

    Robertson, Perry J.; Hamlet, Jason R.; Pierson, Lyndon G.; Olsberg, Ronald R.; Chun, Guy D.


    A technique for distributed packet processing includes sequentially passing packets associated with packet flows between a plurality of processing engines along a flow through data bus linking the plurality of processing engines in series. At least one packet within a given packet flow is marked by a given processing engine to signify by the given processing engine to the other processing engines that the given processing engine has claimed the given packet flow for processing. A processing function is applied to each of the packet flows within the processing engines and the processed packets are output on a time-shared, arbitered data bus coupled to the plurality of processing engines.

  20. Bioaugmentation of nitrate-dependent anaerobic ferrous oxidation by heterotrophic denitrifying sludge addition: A promising way for promotion of chemoautotrophic denitrification. (United States)

    Wang, Ru; Zheng, Ping; Zhang, Meng; Zhao, He-Ping; Ji, Jun-Yuan; Zhou, Xiao-Xin; Li, Wei


    Nitrate-dependent anaerobic ferrous oxidation (NAFO) is a new and valuable bio-process for the treatment of wastewaters with low C/N ratio, and the NAFO process is in state of the art. The heterotrophic denitrifying sludge (HDS), possessing NAFO activity, was used as bioaugmentation to enhance NAFO efficiency. At a dosage of 6% (V/V), the removal of nitrate and ferrous was 2.4 times and 2.3 times of as primary, and the volumetric removal rate (VRR) of nitrate and ferrous was 2.4 times and 2.2 times of as primary. Tracing experiments of HDS indicated that the bioaugmentation on NAFO reactor was resulted from the NAFO activity by HDS itself. The predominant bacteria in HDS were identified as Thauera (52.5%) and Hyphomicrobium (20.0%) which were typical denitrifying bacteria and had potential ability to oxidize ferrous. In conclusion, HDS could serve as bioaugmentation or a new seeding sludge for operating high-efficiency NAFO reactors. Copyright © 2015 Elsevier Ltd. All rights reserved.

  1. Thinning spatial point processes into Poisson processes

    DEFF Research Database (Denmark)

    Møller, Jesper; Schoenberg, Frederic Paik

    , and where one simulates backwards and forwards in order to obtain the thinned process. In the case of a Cox process, a simple independent thinning technique is proposed. In both cases, the thinning results in a Poisson process if and only if the true Papangelou conditional intensity is used, and thus can...

  2. Thinning spatial point processes into Poisson processes

    DEFF Research Database (Denmark)

    Møller, Jesper; Schoenberg, Frederic Paik


    are identified, and where we simulate backwards and forwards in order to obtain the thinned process. In the case of a Cox process, a simple independent thinning technique is proposed. In both cases, the thinning results in a Poisson process if and only if the true Papangelou conditional intensity is used, and...

  3. Investigation and development of heavy oil upgrading catalysts. 3

    Energy Technology Data Exchange (ETDEWEB)

    Lee, D.K.; Lee, I.C.; Yoon, W.L.; Lee, H.T.; Chung, H.; Hwang, Y.J.; Park, S.H. [Korea Inst. of Energy Research, Taejon (Korea, Republic of)


    This study aimed at the domestic development of HDS catalysts which are most fundamental and wide-used in the petroleum refinery. In this year, some experimental works were conducted for developing the effective utilization technology of the novel dispersed-catalysts in the hydro-desulfurization of heavy oils, and improving the reaction performance of alumina-supported Mo-based hydro-treating catalysts conventionally used in most of refineries. First, it was experimentally proved that the dispersed catalysts of Co-Mo could be employed for the hydro-desulfurization of a heavy atmospheric residual oil excluding the catalyst deactivation. The utilization of a carbon-expanded reactor in combination with this dispersed catalyst system exhibited an enhanced reaction performance and provided an efficient way for the separation and recovery of the dispersed catalytic component from oils. Second, the tungsten-incorporated WCoMo/{gamma}-Al{sub 2}O{sub 3} catalyst revealed the improved catalytic performance in the various hydro-treating reactions and in the initial deactivation rates for the high pressure hydro-treatment of a heavy oil as compared with the commercial CoMo/{gamma}-Al{sub 2}O{sub 3} catalyst. This new experimental finding for the promoting role of the monomeric WO{sub 3} species in CoMo/{gamma}-Al{sub 2}O{sub 3} catalyst may be generally applicable to the Mo-based alumina-sulfide phase, higher catalytic activity, and more extended service life. (author). 101 refs., 33 figs., 18 tabs.

  4. The permanent process

    DEFF Research Database (Denmark)

    Møller, Jesper; McCullagh, Peter

    We extend the boson process first to a large class of Cox processes and second an even larger class of infinitely divisible point processes. Density and moment results are studied in detail. These results are obtained in closed form as weighted permanents, so the extension is called a permanent...... process. Temporal extensions and a particularly tractable case of the permanent process are also studied. Extensions of the ferminon process along similar lines, leading to so-called determinant processes, are discussed at the end. While the permanent process is attractive, the determinant process...

  5. 4,6-Dimethyl-dibenzothiophene conversion over Al{sub 2}O{sub 3}-TiO{sub 2}-supported noble metal catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Nunez, Sara [Departamento de Ingenieria de Procesos e Hidraulica, Universidad Autonoma Metropolitana-Iztapalapa, San Rafael Atlixco 186, Vicentina, Iztapalapa, 09340, Mexico, D.F. (Mexico); Escobar, Jose, E-mail: [Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152, San Bartolo Atepehuacan, Gustavo A. Madero, 07730, Mexico, D.F. (Mexico); Vazquez, Armando; Reyes, Jose Antonio de los [Departamento de Ingenieria de Procesos e Hidraulica, Universidad Autonoma Metropolitana-Iztapalapa, San Rafael Atlixco 186, Vicentina, Iztapalapa, 09340, Mexico, D.F. (Mexico); Hernandez-Barrera, Melissa [Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152, San Bartolo Atepehuacan, Gustavo A. Madero, 07730, Mexico, D.F. (Mexico)


    Research highlights: {yields} Al{sub 2}O{sub 3} and Al{sub 2}O{sub 3}-TiO{sub 2} (molar ratio Al/Ti = 2, AT2) mixed oxides were pore-filling impregnated to obtain Pd, Pt and Pd-Pt catalysts with {approx}1 wt% nominal metal loading. {yields} Reduced catalysts were tested in the 4,6-dimethyl-dibenzothiophene hydrodesulfurization (HDS). {yields} In Pd-containing materials, TiO{sub 2} incorporation into the alumina support was favorable to the catalytic activity of noble metal catalysts. {yields} Enhanced intrinsic activity (per exposed metallic site) was obtained in Pt-containing catalysts supported on the AT2 mixed oxide. {yields} Yield to different products over various catalysts seemed to be strongly influenced by metallic particles dispersion. - Abstract: Al{sub 2}O{sub 3} and Al{sub 2}O{sub 3}-TiO{sub 2} (molar ratio Al/Ti = 2, AT2) mixed oxides were synthesized using a low-temperature sol-gel method and were further pore-filling impregnated to obtain Pd and Pt catalysts with {approx}1 wt% nominal metal loading. Simultaneous impregnation was used to prepare bimetallic materials at Pd:Pt = 80:20. Solids characterization was carried out by N{sub 2}-physisorption, high-resolution transmission electron microscopy (HR-TEM and E-FTEM), X-ray diffraction, temperature-programmed reduction and CO-chemisorption. Reduced (350 deg. C, H{sub 2} flow) catalysts were tested in the 4,6-dimethyl-dibenzothiophene hydrodesulfurization (HDS) (in n-dodecane, at 300 deg. C and 5.5 MPa, batch reactor). In Pd-containing materials, TiO{sub 2} incorporation into the alumina support was favorable to the catalytic activity of noble metal catalysts, where bimetallic Pd-Pt with AT2 carrier had the highest organo-S compound conversion. Enhanced intrinsic activity (per exposed metallic site) was obtained in Pt-containing catalysts supported on the AT2 mixed oxide (as compared to alumina-supported ones). Yield to different products over various catalysts seemed to be strongly influenced by

  6. Food processing and allergenicity

    NARCIS (Netherlands)

    Verhoeckx, K.C.M.; Vissers, Y.M.; Baumert, J.L.; Faludi, R.; Feys, M.; Flanagan, S.; Herouet-Guicheney, C.; Holzhauser, T.; Shimojo, R.; Bolt, N. van der; Wichers, H.; Kimber, I.


    Food processing can have many beneficial effects. However, processing may also alter the allergenic properties of food proteins. A wide variety of processing methods is available and their use depends largely on the food to be processed. In this review the impact of processing (heat and non-heat

  7. Food Processing and Allergenicity

    NARCIS (Netherlands)

    Verhoeckx, K.; Vissers, Y.; Baumert, J.L.; Faludi, R.; Fleys, M.; Flanagan, S.; Herouet-Guicheney, C.; Holzhauser, T.; Shimojo, R.; Bolt, van der Nieke; Wichers, H.J.; Kimber, I.


    Food processing can have many beneficial effects. However, processing may also alter the allergenic properties of food proteins. A wide variety of processing methods is available and their use depends largely on the food to be processed.

    In this review the impact of processing (heat and

  8. Process Intensification: A Perspective on Process Synthesis

    DEFF Research Database (Denmark)

    Lutze, Philip; Gani, Rafiqul; Woodley, John


    In recent years, process intensification (PI) has attracted considerable academic interest as a potential means for process improvement, to meet the increasing demands for sustainable production. A variety of intensified operations developed in academia and industry creates a large number...... of options to potentially improve the process but to identify the set of feasible solutions for PI in which the optimal can be found takes considerable resources. Hence, a process synthesis tool to achieve PI would potentially assist in the generation and evaluation of PI options. Currently, several process...... design tools with a clear focus on specific PI tasks exist. Therefore, in this paper, the concept of a general systematic framework for synthesis and design of PI options in hierarchical steps through analyzing an existing process, generating PI options in a superstructure and evaluating intensified...

  9. Process algebra modelling styles for biomolecular processes


    Calder, M.; Hillston, J.


    We investigate how biomolecular processes are modelled in process algebras, focussing on chemical reactions. We consider various modelling styles and how design decisions made in the definition of the process algebra have an impact on how a modelling style can be applied. Our goal is to highlight the often implicit choices that modellers make in choosing a formalism, and illustrate, through the use of examples, how this can affect expressability as well as the type and complexity of the analy...


    Directory of Open Access Journals (Sweden)

    Suyono .


    Full Text Available The marginal distribution of integrated renewal process is derived in this paper. Our approach is based on the theory of point processes, especially Poisson point processes. The results are presented in the form of Laplace transforms.

  11. Business Process Customization using Process Merging Techniques

    NARCIS (Netherlands)

    Bulanov, Pavel; Lazovik, Alexander; Aiello, Marco


    One of the important application of service composition techniques lies in the field of business process management. Essentially a business process can be considered as a composition of services, which is usually prepared by domain experts, and many tasks still have to be performed manually. These

  12. Idaho Chemical Processing Plant Process Efficiency improvements

    Energy Technology Data Exchange (ETDEWEB)

    Griebenow, B.


    In response to decreasing funding levels available to support activities at the Idaho Chemical Processing Plant (ICPP) and a desire to be cost competitive, the Department of Energy Idaho Operations Office (DOE-ID) and Lockheed Idaho Technologies Company have increased their emphasis on cost-saving measures. The ICPP Effectiveness Improvement Initiative involves many activities to improve cost effectiveness and competitiveness. This report documents the methodology and results of one of those cost cutting measures, the Process Efficiency Improvement Activity. The Process Efficiency Improvement Activity performed a systematic review of major work processes at the ICPP to increase productivity and to identify nonvalue-added requirements. A two-phase approach was selected for the activity to allow for near-term implementation of relatively easy process modifications in the first phase while obtaining long-term continuous improvement in the second phase and beyond. Phase I of the initiative included a concentrated review of processes that had a high potential for cost savings with the intent of realizing savings in Fiscal Year 1996 (FY-96.) Phase II consists of implementing long-term strategies too complex for Phase I implementation and evaluation of processes not targeted for Phase I review. The Phase II effort is targeted for realizing cost savings in FY-97 and beyond.

  13. Thin film processes

    CERN Document Server

    Vossen, John L


    Remarkable advances have been made in recent years in the science and technology of thin film processes for deposition and etching. It is the purpose of this book to bring together tutorial reviews of selected filmdeposition and etching processes from a process viewpoint. Emphasis is placed on the practical use of the processes to provide working guidelines for their implementation, a guide to the literature, and an overview of each process.

  14. Business process transformation the process tangram framework

    CERN Document Server

    Sharma, Chitra


    This book presents a framework through transformation and explains  how business goals can be translated into realistic plans that are tangible and yield real results in terms of the top line and the bottom line. Process Transformation is like a tangram puzzle, which has multiple solutions yet is essentially composed of seven 'tans' that hold it together. Based on practical experience and intensive research into existing material, 'Process Tangram' is a simple yet powerful framework that proposes Process Transformation as a program. The seven 'tans' are: the transformation program itself, triggers, goals, tools and techniques, culture, communication and success factors. With its segregation into tans and division into core elements, this framework makes it possible to use 'pick and choose' to quickly and easily map an organization's specific requirements. Change management and process modeling are covered in detail. In addition, the book approaches managed services as a model of service delivery, which it ex...

  15. Hyperspectral processing in graphical processing units (United States)

    Winter, Michael E.; Winter, Edwin M.


    With the advent of the commercial 3D video card in the mid 1990s, we have seen an order of magnitude performance increase with each generation of new video cards. While these cards were designed primarily for visualization and video games, it became apparent after a short while that they could be used for scientific purposes. These Graphical Processing Units (GPUs) are rapidly being incorporated into data processing tasks usually reserved for general purpose computers. It has been found that many image processing problems scale well to modern GPU systems. We have implemented four popular hyperspectral processing algorithms (N-FINDR, linear unmixing, Principal Components, and the RX anomaly detection algorithm). These algorithms show an across the board speedup of at least a factor of 10, with some special cases showing extreme speedups of a hundred times or more.

  16. Process innovation laboratory

    DEFF Research Database (Denmark)

    Møller, Charles


    Most organizations today are required not only to operate effective business processes but also to allow for changing business conditions at an increasing rate. Today nearly every business relies on their enterprise information systems (EIS) for process integration and future generations of EIS...... will increasingly be driven by business process models. Consequently business process modelling and improvement is becoming a serious challenge. The aim of this paper is to establish a conceptual framework for business process innovation (BPI) in the supply chain based on advanced EIS. The challenge is thus...... to create a new methodology for developing and exploring process models and applications. The paper outlines the process innovation laboratory as a new approach to BPI. The process innovation laboratory is a comprehensive framework and a collaborative workspace for experimenting with process models...

  17. Cognitive processes in CBT

    NARCIS (Netherlands)

    Becker, E.S.; Vrijsen, J.N.


    Automatic cognitive processing helps us navigate the world. However, if the emotional and cognitive interplay becomes skewed, those cognitive processes can become maladaptive and result in psychopathology. Although biases are present in most mental disorders, different disorders are characterized by

  18. Anticipating Accountabilty Processes

    NARCIS (Netherlands)

    Meijer, A.J.


    This article deals with the relationship between records management and accountability. Anticipating accountability processes is presented as a key concept. Analyses of business processes and information requirements of accountability forums are presented as a basis for records management which

  19. Radiochemical Processing Laboratory (RPL) (United States)

    Federal Laboratory Consortium — The Radiochemical Processing Laboratory (RPL)�is a scientific facility funded by DOE to create and implement innovative processes for environmental clean-up and...

  20. Laser material processing

    CERN Document Server

    Steen, William


    This text moves from the basics of laser physics to detailed treatments of all major materials processing techniques for which lasers are now essential. New chapters cover laser physics, drilling, micro- and nanomanufacturing and biomedical laser processing.

  1. Drug Development Process (United States)

    ... Device Approvals The Drug Development Process The Drug Development Process Share Tweet Linkedin Pin it More sharing ... Pin it Email Print Step 1 Discovery and Development Discovery and Development Research for a new drug ...

  2. Group Decision Process Support

    DEFF Research Database (Denmark)

    Gøtze, John; Hijikata, Masao


    Introducing the notion of Group Decision Process Support Systems (GDPSS) to traditional decision-support theorists.......Introducing the notion of Group Decision Process Support Systems (GDPSS) to traditional decision-support theorists....

  3. Business Process Inventory (United States)

    Office of Personnel Management — Inventory of maps and descriptions of the business processes of the U.S. Office of Personnel Management (OPM), with an emphasis on the processes of the Office of the...

  4. The plasma hearth process: Process residuals characterization

    Energy Technology Data Exchange (ETDEWEB)

    Leatherman, G.L.; Geimer, R.; Batdorf, J.; Hassel, G.; Wolfe, P. [Science Applications International Corp., Idaho Falls, ID (United States); Carney, K.P. [Argonne National Lab., IL (United States)


    The Plasma Hearth Process (PHP) is a high-temperature waste treatment process being developed by Science Applications International Corporation (SAIC) for the Department of Energy (DOE) that destroys hazardous organics while stabilizing radionuclides and hazardous metals in a vitreous slag waste form. The PHP has potential application for the treatment of a wide range of mixed waste types in both the low-level and transuranic (TRU) mixed waste categories. DOE, through the Office of Technology Development`s Mixed Waste Integrated Program (MWIP) is conducting a three phase development project to ready the PHP for implementation in the DOE complex.

  5. Process Safety Index in Chemical Process


    Sudarni, Dyan H.A; Juwari, Juwari


    Safety is a strategy to reduce the risk of major process accidents. The principle of a safety is to reduce the risk of fails and can be applied easily as the inherent safety. the research which assesses the safety and appeared have a lot of new methods. This study tried to summarize some of the existing methods. The study focused on the case of making methyl methacrylate (MMA) with acetone cyanohydrin (ACH). The processing manufacturing production is divided into four stages or routes. Which ...

  6. Mining processes in dentistry


    Mans, R..S.; H. A. REIJERS; van Genuchten, M.; Wismeijer, D


    Business processes in dentistry are quickly evolving towards "digital dentistry". This means that many steps in the dental process will increasingly deal with computerized information or computerized half products. A complicating factor in the improvement of process performance in dentistry, however, is the large number of independent dental professionals that are involved in the entire process. In order to reap the benefits of digital dentistry, it is essential to obtain an accurate view on ...

  7. Modeling multiphase materials processes

    CERN Document Server

    Iguchi, Manabu


    ""Modeling Multiphase Materials Processes: Gas-Liquid Systems"" describes the methodology and application of physical and mathematical modeling to multi-phase flow phenomena in materials processing. The book focuses on systems involving gas-liquid interaction, the most prevalent in current metallurgical processes. The performance characteristics of these processes are largely dependent on transport phenomena. This volume covers the inherent characteristics that complicate the modeling of transport phenomena in such systems, including complex multiphase structure, intense turbulence, opacity of

  8. Dosimetry for radiation processing

    DEFF Research Database (Denmark)

    Miller, Arne


    During the past few years significant advances have taken place in the different areas of dosimetry for radiation processing, mainly stimulated by the increased interest in radiation for food preservation, plastic processing and sterilization of medical products. Reference services both...... and sterilization dosimetry, optichromic dosimeters in the shape of small tubes for food processing, and ESR spectroscopy of alanine for reference dosimetry. In this paper the special features of radiation processing dosimetry are discussed, several commonly used dosimeters are reviewed, and factors leading...

  9. Software Process Improvement Defined

    DEFF Research Database (Denmark)

    Aaen, Ivan


    This paper argues in favor of the development of explanatory theory on software process improvement. The last one or two decades commitment to prescriptive approaches in software process improvement theory may contribute to the emergence of a gulf dividing theorists and practitioners....... It is proposed that this divide be met by the development of theory evaluating prescriptive approaches and informing practice with a focus on the software process policymaking and process control aspects of improvement efforts...

  10. Mining local process models


    Tax, Niek; Sidorova, Natalia; Haakma, Reinder; van der Aalst, Wil M.P.


    In this paper we describe a method to discover frequent behavioral patterns in event logs. We express these patterns as \\emph{local process models}. Local process model mining can be positioned in-between process discovery and episode / sequential pattern mining. The technique presented in this paper is able to learn behavioral patterns involving sequential composition, concurrency, choice and loop, like in process mining. However, we do not look at start-to-end models, which distinguishes ou...

  11. Integrated Renewal Process


    Suyono .; Van der Weide, J.A.M.


    The marginal distribution of integrated renewal process is derived in this paper. Our approach is based on the theory of point processes, especially Poisson point processes. The results are presented in the form of Laplace transforms. DOI :

  12. Semisolid Metal Processing Consortium

    Energy Technology Data Exchange (ETDEWEB)



    Mathematical modeling and simulations of semisolid filling processes remains a critical issue in understanding and optimizing the process. Semisolid slurries are non-Newtonian materials that exhibit complex rheological behavior. There the way these slurries flow in cavities is very different from the way liquid in classical casting fills cavities. Actually filling in semisolid processing is often counter intuitive

  13. Picturing Quantum Processes (United States)

    Coecke, Bob; Kissinger, Aleks


    Preface; 1. Introduction; 2. Guide to reading this textbook; 3. Processes as diagrams; 4. String diagrams; 5. Hilbert space from diagrams; 6. Quantum processes; 7. Quantum measurement; 8. Picturing classical-quantum processes; 9. Picturing phases and complementarity; 10. Quantum theory: the full picture; 11. Quantum foundations; 12. Quantum computation; 13. Quantum resources; 14. Quantomatic; Appendix A. Some notations; References; Index.

  14. Clinical Process Intelligence

    DEFF Research Database (Denmark)

    Vilstrup Pedersen, Klaus


    .e. local guidelines. From a knowledge management point of view, this externalization of generalized processes, gives the opportunity to learn from, evaluate and optimize the processes. "Clinical Process Intelligence" (CPI), will denote the goal of getting generalized insight into patient centered health...

  15. Teaching Process Design through Integrated Process Synthesis (United States)

    Metzger, Matthew J.; Glasser, Benjamin J.; Patel, Bilal; Hildebrandt, Diane; Glasser, David


    The design course is an integral part of chemical engineering education. A novel approach to the design course was recently introduced at the University of the Witwatersrand, Johannesburg, South Africa. The course aimed to introduce students to systematic tools and techniques for setting and evaluating performance targets for processes, as well as…

  16. Statistical Process Control for KSC Processing (United States)

    Ford, Roger G.; Delgado, Hector; Tilley, Randy


    The 1996 Summer Faculty Fellowship Program and Kennedy Space Center (KSC) served as the basis for a research effort into statistical process control for KSC processing. The effort entailed several tasks and goals. The first was to develop a customized statistical process control (SPC) course for the Safety and Mission Assurance Trends Analysis Group. The actual teaching of this course took place over several weeks. In addition, an Internet version of the same course complete with animation and video excerpts from the course when it was taught at KSC was developed. The application of SPC to shuttle processing took up the rest of the summer research project. This effort entailed the evaluation of SPC use at KSC, both present and potential, due to the change in roles for NASA and the Single Flight Operations Contractor (SFOC). Individual consulting on SPC use was accomplished as well as an evaluation of SPC software for KSC use in the future. A final accomplishment of the orientation of the author to NASA changes, terminology, data format, and new NASA task definitions will allow future consultation when the needs arise.

  17. Zeolites Remove Sulfur From Fuels (United States)

    Voecks, Gerald E.; Sharma, Pramod K.


    Zeolites remove substantial amounts of sulfur compounds from diesel fuel under relatively mild conditions - atmospheric pressure below 300 degrees C. Extracts up to 60 percent of sulfur content of high-sulfur fuel. Applicable to petroleum refineries, natural-gas processors, electric powerplants, and chemical-processing plants. Method simpler and uses considerably lower pressure than current industrial method, hydro-desulfurization. Yields cleaner emissions from combustion of petroleum fuels, and protects catalysts from poisoning by sulfur.

  18. Towards better process understanding

    DEFF Research Database (Denmark)

    Matero, Sanni Elina; van der Berg, Franciscus Winfried J; Poutiainen, Sami


    , current best practice to control a typical process is to not allow process-related factors to vary i.e. lock the production parameters. The problem related to the lack of sufficient process understanding is still there: the variation within process and material properties is an intrinsic feature...... to achieve a thorough understanding and control over the production process. PAT includes the frames for measurement as well as data analyzes and controlling for in-depth understanding, leading to more consistent and safer drug products with less batch rejections. In the optimal situation, by applying...

  19. Colloid process engineering

    CERN Document Server

    Peukert, Wolfgang; Rehage, Heinz; Schuchmann, Heike


    This book deals with colloidal systems in technical processes and the influence of colloidal systems by technical processes. It explores how new measurement capabilities can offer the potential for a dynamic development of scientific and engineering, and examines the origin of colloidal systems and its use for new products. The future challenges to colloidal process engineering are the development of appropriate equipment and processes for the production and obtainment of multi-phase structures and energetic interactions in market-relevant quantities. The book explores the relevant processes and for controlled production and how they can be used across all scales.

  20. Data processing made simple

    CERN Document Server

    Wooldridge, Susan


    Data Processing: Made Simple, Second Edition presents discussions of a number of trends and developments in the world of commercial data processing. The book covers the rapid growth of micro- and mini-computers for both home and office use; word processing and the 'automated office'; the advent of distributed data processing; and the continued growth of database-oriented systems. The text also discusses modern digital computers; fundamental computer concepts; information and data processing requirements of commercial organizations; and the historical perspective of the computer industry. The

  1. Thin film processes II

    CERN Document Server

    Kern, Werner


    This sequel to the 1978 classic, Thin Film Processes, gives a clear, practical exposition of important thin film deposition and etching processes that have not yet been adequately reviewed. It discusses selected processes in tutorial overviews with implementation guide lines and an introduction to the literature. Though edited to stand alone, when taken together, Thin Film Processes II and its predecessor present a thorough grounding in modern thin film techniques.Key Features* Provides an all-new sequel to the 1978 classic, Thin Film Processes* Introduces new topics, and sever

  2. Process-based costing. (United States)

    Lee, Robert H; Bott, Marjorie J; Forbes, Sarah; Redford, Linda; Swagerty, Daniel L; Taunton, Roma Lee


    Understanding how quality improvement affects costs is important. Unfortunately, low-cost, reliable ways of measuring direct costs are scarce. This article builds on the principles of process improvement to develop a costing strategy that meets both criteria. Process-based costing has 4 steps: developing a flowchart, estimating resource use, valuing resources, and calculating direct costs. To illustrate the technique, this article uses it to cost the care planning process in 3 long-term care facilities. We conclude that process-based costing is easy to implement; generates reliable, valid data; and allows nursing managers to assess the costs of new or modified processes.

  3. Auditory processing models

    DEFF Research Database (Denmark)

    Dau, Torsten


    The Handbook of Signal Processing in Acoustics will compile the techniques and applications of signal processing as they are used in the many varied areas of Acoustics. The Handbook will emphasize the interdisciplinary nature of signal processing in acoustics. Each Section of the Handbook...... will present topics on signal processing which are important in a specific area of acoustics. These will be of interest to specialists in these areas because they will be presented from their technical perspective, rather than a generic engineering approach to signal processing. Non-specialists, or specialists...

  4. Gas processing handbook

    Energy Technology Data Exchange (ETDEWEB)


    Brief details are given of processes including: BGC-Lurgi slagging gasification, COGAS, Exxon catalytic coal gasification, FW-Stoic 2-stage, GI two stage, HYGAS, Koppers-Totzek, Lurgi pressure gasification, Saarberg-Otto, Shell, Texaco, U-Gas, W-D.IGI, Wellman-Galusha, Westinghouse, and Winkler coal gasification processes; the Rectisol process; the Catacarb and the Benfield processes for removing CO/SUB/2, H/SUB/2s and COS from gases produced by the partial oxidation of coal; the selectamine DD, Selexol solvent, and Sulfinol gas cleaning processes; the sulphur-tolerant shift (SSK) process; and the Super-meth process for the production of high-Btu gas from synthesis gas.

  5. Business Process Redesign: Design the Improved Process (United States)


    resources. The emphasis was on unification and standardization. The strategies were to be devised at the DoD level rather than being an amalgam of the...following a scent. If an interviewer does not recognize the wisp on an answer, a trail that might 53 provide rich data may never be taken [Higginbotham...should achieve those objectives. Advocates of this theory insist that by reducing a process to its logical essence, the following benefits will be

  6. A two-layer ONIOM study of thiophene cracking catalyzed by proton- and cation-exchanged FAU zeolite. (United States)

    Sun, Yingxin; Mao, Xinfeng; Pei, Supeng


    A two-layer ONIOM study on the hydrodesulfurization mechanism of thiophene in H-FAU and M-FAU (M = Li(+), Na(+), and K(+)) has been carried out. The calculated results reveal that in H-FAU, for a unimolecular mechanism, the rate-determining step is hydrogenation of alkoxide intermediate. The assistance of H2O and H2S molecules does not reduce the difficulty of the C-S bond cracking step more effectively. A bimolecular hydrodesulfurization mechanism is more favorable due to the lower activation barriers. The rate-determining step is the formation of 2-methylthiophene, not the C-S bond cracking of thiophene. Moreover, the ring opening of thiophene is much easier to occur than the desulfurization step. A careful analysis of energetics indicates that H2S, propene, and methyl thiophene are the major products for the hydrodesulfurization process of thiophene over H-FAU zeolite, in good agreement with experimental findings. In M-FAU zeolites, both unimolecular and bimolecular cracking processes are difficult to occur because of the high energy barriers. Compared to the case on H-FAU, the metal cations on M-FAU increase the difficulty of occurrence of bimolecular polymerization and subsequent C-S bond cracking steps. Graphical abstract Hydrodesulfurization process of thiophene can take place in H-FAU zeolite. Two different mechanisms, unimolecular and bimolecular ones, have been proposed and evaluated in detail. The bimolecular mechanism is more favorable due to lower activation barrier as described in the picture above. Our calculated data indicate that H2S, propene, and methylthiophene are the major products, in good agreement with experimental observations. The effect of metal cations on the reaction mechanism is also investigated in this work.

  7. Badge Office Process Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Haurykiewicz, John Paul [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dinehart, Timothy Grant [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Parker, Robert Young [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    The purpose of this process analysis was to analyze the Badge Offices’ current processes from a systems perspective and consider ways of pursuing objectives set forth by SEC-PS, namely increased customer flow (throughput) and reduced customer wait times. Information for the analysis was gathered for the project primarily through Badge Office Subject Matter Experts (SMEs), and in-person observation of prevailing processes. Using the information gathered, a process simulation model was constructed to represent current operations and allow assessment of potential process changes relative to factors mentioned previously. The overall purpose of the analysis was to provide SEC-PS management with information and recommendations to serve as a basis for additional focused study and areas for potential process improvements in the future.

  8. Multimodal Processes Rescheduling

    DEFF Research Database (Denmark)

    Bocewicz, Grzegorz; Banaszak, Zbigniew A.; Nielsen, Peter


    Cyclic scheduling problems concerning multimodal processes are usually observed in FMSs producing multi-type parts where the Automated Guided Vehicles System (AGVS) plays a role of a material handling system. Schedulability analysis of concurrently flowing cyclic processes (SCCP) exe-cuted in the......Cyclic scheduling problems concerning multimodal processes are usually observed in FMSs producing multi-type parts where the Automated Guided Vehicles System (AGVS) plays a role of a material handling system. Schedulability analysis of concurrently flowing cyclic processes (SCCP) exe......-cuted in these kinds of systems can be considered using a declarative modeling framework. Proposed representation provides a unified way for performance evaluation of local cyclic as well as supported by them multimodal processes. The main question regards of reachability of a SCCP cyclic behavior. In this context......, the sufficient conditions guarantee the reachability of both local and multimodal processes cyclic steady state spaces are discussed....

  9. Thin Film Processes

    CERN Document Server

    Vossen, John L.


    This sequel to the 1978 classic, Thin Film Processes, gives a clear, practical exposition of important thin film deposition and etching processes that have not yet been adequately reviewed. It discusses selected processes in tutorial overviews with implementation guide lines and an introduction to the literature. Though edited to stand alone, when taken together, Thin Film Processes II and its predecessor present a thorough grounding in modern thin film techniques. Key Features * Provides an all-new sequel to the 1978 classic, Thin Film Processes * Introduces new topics, and several key topics presented in the original volume are updated * Emphasizes practical applications of major thin film deposition and etching processes * Helps readers find the appropriate technology for a particular application

  10. Business Model Process Configurations

    DEFF Research Database (Denmark)

    Taran, Yariv; Nielsen, Christian; Thomsen, Peter


    Purpose – The paper aims: 1) To develop systematically a structural list of various business model process configuration and to group (deductively) these selected configurations in a structured typological categorization list. 2) To facilitate companies in the process of BM innovation, by develop......Purpose – The paper aims: 1) To develop systematically a structural list of various business model process configuration and to group (deductively) these selected configurations in a structured typological categorization list. 2) To facilitate companies in the process of BM innovation......, by developing (inductively) an ontological classification framework, in view of the BM process configurations typology developed. Design/methodology/approach – Given the inconsistencies found in the business model studies (e.g. definitions, configurations, classifications) we adopted the analytical induction...... method of data analysis. Findings - A comprehensive literature review and analysis resulted in a list of business model process configurations systematically organized under five classification groups, namely, revenue model; value proposition; value configuration; target customers, and strategic...

  11. Linearity in Process Languages

    DEFF Research Database (Denmark)

    Nygaard, Mikkel; Winskel, Glynn


    The meaning and mathematical consequences of linearity (managing without a presumed ability to copy) are studied for a path-based model of processes which is also a model of affine-linear logic. This connection yields an affine-linear language for processes, automatically respecting open-map bisi......The meaning and mathematical consequences of linearity (managing without a presumed ability to copy) are studied for a path-based model of processes which is also a model of affine-linear logic. This connection yields an affine-linear language for processes, automatically respecting open......-map bisimulation, in which a range of process operations can be expressed. An operational semantics is provided for the tensor fragment of the language. Different ways to make assemblies of processes lead to different choices of exponential, some of which respect bisimulation....

  12. Technology or Process First?

    DEFF Research Database (Denmark)

    Siurdyban, Artur Henryk; Svejvig, Per; Møller, Charles

    Enterprise Systems Management (ESM) and Business Pro- cess Management (BPM), although highly correlated, have evolved as alternative and mutually exclusive approaches to corporate infrastruc- ture. As a result, companies struggle to nd the right balance between technology and process factors...... in infrastructure implementation projects. The purpose of this paper is articulate a need and a direction to medi- ate between the process-driven and the technology-driven approaches. Using a cross-case analysis, we gain insight into two examples of sys- tems and process implementation. We highlight the dierences...... between them using strategic alignment, Enterprise Systems and Business Process Management theories. We argue that the insights from these cases can lead to a better alignment between process and technology. Implications for practice include the direction towards a closer integration of process...

  13. Multiquantum processes. Mnogokvantovye protsessy

    Energy Technology Data Exchange (ETDEWEB)

    Kovarskii, V.A.; Perelman, N.F.; Averbukh, I.SH.


    The book is concerned with the theory and methods of multiquantum (multiphonon and multiphoton) processes, including resonance multiphoton processes in atoms, molecules, and solid bodies as well as optical and nonradiative multiphonon transitions in molecules and solids. In particular, attention is given to the Green function method in the theory of multiphoton processes, the probability of transitions in two-level quantum systems under the effect of slowly varying perturbations, multiphoton nonadiabatic transitions, and nonadiabatic effects in electron-vibrational systems. 234 references.

  14. Business process transformation

    CERN Document Server

    Grover, Varun


    Featuring contributions from prominent thinkers and researchers, this volume in the ""Advances in Management Information Systems"" series provides a rich set of conceptual, empirical, and introspective studies that epitomize fundamental knowledge in the area of Business Process Transformation. Processes are interpreted broadly to include operational and managerial processes within and between organizations, as well as those involved in knowledge generation. Transformation includes radical and incremental change, its conduct, management, and outcome. The editors and contributing authors pay clo

  15. Process Improvement Essentials

    CERN Document Server

    Persse, James R


    Process Improvement Essentials combines the foundation needed to understand process improvement theory with the best practices to help individuals implement process improvement initiatives in their organization. The three leading programs: ISO 9001:2000, CMMI, and Six Sigma--amidst the buzz and hype--tend to get lumped together under a common label. This book delivers a combined guide to all three programs, compares their applicability, and then sets the foundation for further exploration.

  16. Business process trends


    von Rosing, Mark; Polovina, Simon


    Business process and business process management (BPM) concepts have matured over the years and new technology, concepts, standards and solutions appear. In this chapter\\ud we will therefore focus on the current and future process trends. We will elaborate on the importance of trends, the maturity of the subject, giving a perspective on what emerging trends, industry trends, mega trends are, what is hyped at the moment, and what has reached a market adoption where it has started to become the...

  17. Standard Model processes

    CERN Document Server

    Mangano, M.L.; Aguilar Saavedra, J.A.; Alekhin, S.; Badger, S.; Bauer, C.W.; Becher, T.; Bertone, V.; Bonvini, M.; Boselli, S.; Bothmann, E.; Boughezal, R.; Cacciari, M.; Carloni Calame, C.M.; Caola, F.; Campbell, J.M.; Carrazza, S.; Chiesa, M.; Cieri, L.; Cimaglia, F.; Febres Cordero, F.; Ferrarese, P.; D'Enterria, D.; Ferrera, G.; Garcia i Tormo, X.; Garzelli, M.V.; Germann, E.; Hirschi, V.; Han, T.; Ita, H.; Jäger, B.; Kallweit, S.; Karlberg, A.; Kuttimalai, S.; Krauss, F.; Larkoski, A.J.; Lindert, J.; Luisoni, G.; Maierhöfer, P.; Mattelaer, O.; Martinez, H.; Moch, S.; Montagna, G.; Moretti, M.; Nason, P.; Nicrosini, O.; Oleari, C.; Pagani, D.; Papaefstathiou, A.; Petriello, F.; Piccinini, F.; Pierini, M.; Pierog, T.; Pozzorini, S.; Re, E.; Robens, T.; Rojo, J.; Ruiz, R.; Sakurai, K.; Salam, G.P.; Salfelder, L.; Schönherr, M.; Schulze, M.; Schumann, S.; Selvaggi, M.; Shivaji, A.; Siodmok, A.; Skands, P.; Torrielli, P.; Tramontano, F.; Tsinikos, I.; Tweedie, B.; Vicini, A.; Westhoff, S.; Zaro, M.; Zeppenfeld, D.; CERN. Geneva. ATS Department


    This report summarises the properties of Standard Model processes at the 100 TeV pp collider. We document the production rates and typical distributions for a number of benchmark Standard Model processes, and discuss new dynamical phenomena arising at the highest energies available at this collider. We discuss the intrinsic physics interest in the measurement of these Standard Model processes, as well as their role as backgrounds for New Physics searches.

  18. Privatisation Process in Kosovo


    Dr.Sc. Hysni Terziu


    This paper aims at analysing activities of the privatisation process in Kosovo, seeing that privatisation is treated as a fundamental factor of overall transformation of the whole society. It may be established that the primary aim of privatisation process is increasing economic efficiency, reflection of the current state and directions of development in general. Privatisation as a process has as primary aim of opening new areas of freedom, economic efficiency and individualism. Key a...

  19. Microwave Processing of Materials (United States)


    reactions in sol-gel processing, gas-phase synthesis , solution evaporation/decomposition, or hydrothermal reactions. Each of these, and other powder... synthesis methods, will be described next. Sol-Gel Decomposition/Drying Microwaves have been used in several of the processing stages to synthesize BaTiO3 ...high surface areas (10-700 m2/g). Hydrothermal Reactions Microwave- hydrothermal processing has been utilized in catalyzing the synthesis of crystalline

  20. Basic digital signal processing

    CERN Document Server

    Lockhart, Gordon B


    Basic Digital Signal Processing describes the principles of digital signal processing and experiments with BASIC programs involving the fast Fourier theorem (FFT). The book reviews the fundamentals of the BASIC program, continuous and discrete time signals including analog signals, Fourier analysis, discrete Fourier transform, signal energy, power. The text also explains digital signal processing involving digital filters, linear time-variant systems, discrete time unit impulse, discrete-time convolution, and the alternative structure for second order infinite impulse response (IIR) sections.

  1. Jointly Poisson processes


    Johnson, D. H.; Goodman, I. N.


    What constitutes jointly Poisson processes remains an unresolved issue. This report reviews the current state of the theory and indicates how the accepted but unproven model equals that resulting from the small time-interval limit of jointly Bernoulli processes. One intriguing consequence of these models is that jointly Poisson processes can only be positively correlated as measured by the correlation coefficient defined by cumulants of the probability generating functional.

  2. Technologies for Optical Processing

    DEFF Research Database (Denmark)

    Stubkjær, Kristian


    The article consists of a Powerpoint presentation on technologies for optical processing. The paper concludes that the nonlinear elements based on SOA, fibers and waveguide structures have capabilities of simple processing at data rates of 100-600 Gb/s. Switching powers comparable to electronics....... Photonic bandgap structures and nanowaveguides have potential for more compact photonic circuits. Nanostructures in switching at the very beginning plasmons may be useful for more compact photonic signal processing elements....

  3. Multiphoton processes: conference proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Lambropoulos, P.; Smith, S.J. (eds.)


    The chapters of this volume represent the invited papers delivered at the conference. They are arranged according to thermatic proximity beginning with atoms and continuing with molecules and surfaces. Section headings include multiphoton processes in atoms, field fluctuations and collisions in multiphoton process, and multiphoton processes in molecules and surfaces. Abstracts of individual items from the conference were prepared separately for the data base. (GHT)

  4. The process audit. (United States)

    Hammer, Michael


    Few executives question the idea that by redesigning business processes--work that runs from end to end across an enterprise--they can achieve extraordinary improvements in cost, quality, speed, profitability, and other key areas Yet in spite of their intentions and investments, many executives flounder, unsure about what exactly needs to be changed, by how much, and when. As a result, many organizations make little progress--if any at all--in their attempts to transform business processes. Michael Hammer has spent the past five years working with a group of leading companies to develop the Process and Enterprise Maturity Model (PEMM), a new framework that helps executives comprehend, formulate, and assess process-based transformation efforts. He has identified two distinct groups of characteristics that are needed for business processes to perform exceptionally well over a long period of time. Process enablers, which affect individual processes, determine how well a process is able to function. They are mutually interdependent--if any are missing, the others will be ineffective. However, enablers are not enough to develop high-performance processes; they only provide the potential to deliver high performance. A company must also possess or establish organizational capabilities that allow the business to offer a supportive environment. Together, the enablers and the capabilities provide an effective way for companies to plan and evaluate process-based transformations. PEMM is different from other frameworks, such as Capability Maturity Model Integration (CMMI), because it applies to all industries and all processes. The author describes how several companies--including Michelin, CSAA, Tetra Pak, Shell, Clorox, and Schneider National--have successfully used PEMM in various ways and at different stages to evaluate the progress of their process-based transformation efforts.

  5. Linearity in Process Languages

    DEFF Research Database (Denmark)

    Nygaard, Mikkel; Winskel, Glynn


    The meaning and mathematical consequences of linearity (managing without a presumed ability to copy) are studied for a path-based model of processes which is also a model of affine-linear logic. This connection yields an affine-linear language for processes, automatically respecting open......-map bisimulation, in which a range of process operations can be expressed. An operational semantics is provided for the tensor fragment of the language. Different ways to make assemblies of processes lead to different choices of exponential, some of which respect bisimulation....

  6. The Integrated Renovation Process

    DEFF Research Database (Denmark)

    Galiotto, Nicolas

    and constructivist multiple criteria decision-making analysis method is selected for developing the work further. The method is introduced and applied to the renovation of a multi-residential historic building. Furthermore, a new scheme, the Integrated Renovation Process, is presented. Finally, the methodology...... disciplines including architectural, process, energy and environmental engineering as well as economics, psychology and social sciences. The developed methodology is implementable on a large scale and allows an optimal integration of non-expert decision makers and associated project stakeholders...... to keep the decision making process economically viable and timely, the process still needs to be improved and new tools need to be developed....

  7. Process modeling style

    CERN Document Server

    Long, John


    Process Modeling Style focuses on other aspects of process modeling beyond notation that are very important to practitioners. Many people who model processes focus on the specific notation used to create their drawings. While that is important, there are many other aspects to modeling, such as naming, creating identifiers, descriptions, interfaces, patterns, and creating useful process documentation. Experience author John Long focuses on those non-notational aspects of modeling, which practitioners will find invaluable. Gives solid advice for creating roles, work produ

  8. Biased predecision processing. (United States)

    Brownstein, Aaron L


    Decision makers conduct biased predecision processing when they restructure their mental representation of the decision environment to favor one alternative before making their choice. The question of whether biased predecision processing occurs has been controversial since L. Festinger (1957) maintained that it does not occur. The author reviews relevant research in sections on theories of cognitive dissonance, decision conflict, choice certainty, action control, action phases, dominance structuring, differentiation and consolidation, constructive processing, motivated reasoning, and groupthink. Some studies did not find evidence of biased predecision processing, but many did. In the Discussion section, the moderators are summarized and used to assess the theories.

  9. Conceptualizing operations strategy processes

    DEFF Research Database (Denmark)

    Rytter, Niels Gorm; Boer, Harry; Koch, Christian


    Purpose - The purpose of this paper is to present insights into operations strategy (OS) in practice. It outlines a conceptualization and model of OS processes and, based on findings from an in-depth and longitudinal case study, contributes to further development of extant OS models and methods...... which presently mainly focus on OS content, as distinct from process issues. DesignImethodology/approach - The methodology combines action research and a longitudinal single site case study of OS processes in practice. Findings - The paper conceptualises an OS process as: events of dialogue and action...

  10. Quantum information processing

    National Research Council Canada - National Science Library

    Leuchs, Gerd; Beth, Thomas


    ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.5 SimulationofHamiltonians... References... 1 1 1 3 5 8 10 2 Quantum Information Processing and Error Correction with Jump Codes (G. Alber, M. Mussinger...

  11. Mineral Processing Sector (United States)

    Find environmental regulatory and compliance information for the nonmetallic mineral processing sector (NAICS 327), including NESHAPs for asbestos and hazardous waste, and wastewater permit information.

  12. Chemisorption and catalytic reactivity of cobalt and sulfur monolayers on ordered molybdenum surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Knight, Colette Clarissa [Univ. of California, Berkeley, CA (United States)


    Complex Co/Mo sulfide catalysts are modelled by the chemisorption of layers on Mo single crystal surfaces. Growth and structure of overlayers on flat, stepped and kinked surfaces were investigated. Growth of Co overlayers on clean and S covered Mo surfaces was studied using AES and CO chemisorption; results reveal that Co grows as a flat monolayer on clean Mo surfaces. Co multilayers then form 3-D islands. When Co is deposited on S covered surfaces, the S overlayer migrates to the top; this topmost overlayer reduces CO adsorption capacity. While growth mode of Co overlayers are similar on flat and stepped surfaces, the number and type of ordered Co and S structures on flat and stepped surfaces are different. In the case of Co, an ordered (3 x 1) structure is formed on Mo(910) and (28,4,1) surfaces; this structure does not develop on clean (100) surface. Only one of two possible (3 x 1) Co domains are formed on Mo(910) and Mo(28,4,1) surfaces. These domains have one side of (3 x 1) unit cell parallel to the step edges, suggesting that Co adsorbs at the step edges. The (3 x 1) structure does not form on Mo(911) surface, indicating that step orientation can restrict formation of ordered overlayers. For chemisorbed S, only a subset of ordered overlayers on flat (100) surface nucleate on (910) and (911) and (28,4,1) surfaces. Ordered S overlayers also form domains that maximize the number of sulfur-step atom bonds. The adsorption and ordering of S overlayers on stepped and kinked Mo surfaces lead to doubling of step height and terrace width. Thiophene hydrodesulfurization (HDS) reactions were performed over Mo crystal surfaces modified by chemisorption of S, Co, C, and S + Co. The stepped and kinked Mo surfaces have reactivities greater than low Miller index (100) surface. Chemisorption of adsorbates decreased the thiophene HDS reactivity. Deposition of Co on Mo single crystal surfaces did not lead to increased HDS activity.

  13. Chemisorption and catalytic reactivity of cobalt and sulfur monolayers on ordered molybdenum surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Knight, C.C.


    Complex Co/Mo sulfide catalysts are modelled by the chemisorption of layers on Mo single crystal surfaces. Growth and structure of overlayers on flat, stepped and kinked surfaces were investigated. Growth of Co overlayers on clean and S covered Mo surfaces was studied using AES and CO chemisorption; results reveal that Co grows as a flat monolayer on clean Mo surfaces. Co multilayers then form 3-D islands. When Co is deposited on S covered surfaces, the S overlayer migrates to the top; this topmost overlayer reduces CO adsorption capacity. While growth mode of Co overlayers are similar on flat and stepped surfaces, the number and type of ordered Co and S structures on flat and stepped surfaces are different. In the case of Co, an ordered (3 {times} 1) structure is formed on Mo(910) and (28,4,1) surfaces; this structure does not develop on clean (100) surface. Only one of two possible (3 {times} 1) Co domains are formed on Mo(910) and Mo(28,4,1) surfaces. These domains have one side of (3 {times} 1) unit cell parallel to the step edges, suggesting that Co adsorbs at the step edges. The (3 {times} 1) structure does not form on Mo(911) surface, indicating that step orientation can restrict formation of ordered overlayers. For chemisorbed S, only a subset of ordered overlayers on flat (100) surface nucleate on (910) and (911) and (28,4,1) surfaces. Ordered S overlayers also form domains that maximize the number of sulfur-step atom bonds. The adsorption and ordering of S overlayers on stepped and kinked Mo surfaces lead to doubling of step height and terrace width. Thiophene hydrodesulfurization (HDS) reactions were performed over Mo crystal surfaces modified by chemisorption of S, Co, C, and S + Co. The stepped and kinked Mo surfaces have reactivities greater than low Miller index (100) surface. Chemisorption of adsorbates decreased the thiophene HDS reactivity. Deposition of Co on Mo single crystal surfaces did not lead to increased HDS activity.

  14. Synthesis of Nanoparticle Model Systems for Sustainable Catalysis by Gas Aggregation

    DEFF Research Database (Denmark)

    Bodin, Anders

    , summarized in the following: Platinum Catalysts for TW-Scale H2 Production: Platinum has the highest activity of known catalysts for the hydrogen evolution reaction (HER), but due to scarcity and price it is often assumed to by infeasible for photoelectrochemical water splitting on the terawatt......-scale that is needed for significant global impact. This study investigates the relationship between catalytic activity for the HER and platinum catalyst loading using well-defined model systems with different loadings of mass-selected 5nm Pt nanoparticles. Using the knowledge gained on these systems, a technoeconomic...... morphologies. Using a microreactor platform, the catalytic activity of the nanoparticles is assesed for hydrodesulfurization (HDS) of dibenzothiophene, relevant for e.g. production of diesel with ultra-low sulfur content. It is found that in-flight sulfided Ni-Mo-S nanoparticles have more than twice as high...

  15. Effect of catalyst deactivation on vacuum residue hydrocracking

    Directory of Open Access Journals (Sweden)

    Hoda S. Ahmed


    Full Text Available Accelerated deactivation tests of the pre-sulfided Mo–W/SiO2–Al2O3 commercial catalyst were performed using heavy vacuum petroleum feedstock. High reaction temperature employed in the accelerated catalyst aging resulted in large amounts of carbonaceous deposition with high aromaticity, which was found to be the principal deactivation cause. The effect of catalyst deactivation on hydrocracking of vacuum residue was studied. Experiments were carried out in a batch reactor at 60 bar, feed to catalyst ratio 10:1 and temperature 425 °C. The duration time for a cycle-run was 4 h. On increasing the interval duration times from 4 to 20 h (i.e. five cycles, the quality of the hydrocracked products was decreased. In each cycle-run, a fresh feedstock was used with the same sulfide catalyst. The quality of distillate products, such as hydrodesulfurization (HDS was decreased from 61.50% to 39.52%, while asphaltene contents of the total liquid product were increased from 2.7% to 5.2% and their boiling ranges were increased during these duration times due to the successive catalyst deactivation during the 5 cycle-runs, caused by successive adsorption of coke formation.

  16. Kinetic modelling of hydro-treatment reactions by study of different chemical groups; Modelisation cinetique des reactions d`hydrotraitement par regroupement en familles chimiques

    Energy Technology Data Exchange (ETDEWEB)

    Bonnardot, J.


    Hydro-treatment of petroleum shortcuts permits elimination of unwanted components in order to increase combustion in engine and to decrease atmospheric pollution. Hydro-desulfurization (HDS), Hydro-denitrogenation (HDN) and Hydrogenation of aromatics (HDA) of a LCO (Light Cycle Oil)-Type gas oil have been studied using a new pilot at a fixed temperature with a NiMo/Al{sub 2}O{sub 3} catalyst. A hydrodynamic study showed that reactions occurring in the up-flow fixed bed reactor that has been used during the experiments, were governed exclusively by chemical reaction rates and not by diffusion. Through detailed chemical analysis, height chemical groups have been considered: three aromatics groups, one sulfided group, one nitrogenized and NH{sub 3}, H{sub 2}S, H{sub 2}. Two Langmuir-Hinshelwood-type kinetic models with either one or two types of sites have been established. The model with two types of site - one site of hydrogenation and one site of hydrogenolysis - showed a better fit in the modeling of the experimental results. This model enables to forecast the influence of partial pressure of H{sub 2}S and partial pressure of H{sub 2} on hydro-treatment reactions of a LCO-type gas oil. (author) 119 refs.

  17. Synthesis of a Mo/Nb mixed carbide

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira da Silva, V.L. [NUCAT/PEQ/COPPE/Universidade Federal do Rio de Janeiro, Caixa Postal 68502, Rio de Janeiro, RJ-21945-970 (Brazil)]|[Environmental Catalysis and Materials Laboratory, Department of Chemical Engineering, Virginia Polytechnic Institute State University, Blacksburg, Virginia 24061 (United States); Schmal, M. [NUCAT/PEQ/COPPE/Universidade Federal do Rio de Janeiro, Caixa Postal 68502, Rio de Janeiro, RJ-21945-970 (Brazil); Schwartz, V.; Oyama, S.T. [Environmental Catalysis and Materials Laboratory, Department of Chemical Engineering, Virginia Polytechnic Institute State University, Blacksburg, Virginia 24061 (United States)


    Molybdenum and niobium carbides ({beta}{endash}Mo{sub 2}C, NbC), as well as mixed carbides of molybdenum and niobium, were synthesized by the temperature-programmed carburization method (TPC) using a 20 vol.thinsp{percent} CH{sub 4}/H{sub 2} gas mixture. The starting materials were MoO{sub 3}, B-Nb{sub 2}O{sub 5}, and physical mixtures of B-Nb{sub 2}O{sub 5}/MoO{sub 3} with Nb/(Nb+Mo) atomic ratios varying from 0.2 to 0.8, respectively. Results from catalytic and temperature-programmed oxidation (TPO) measurements indicate that during the carburization of the Nb{sub 2}O{sub 5}/MoO{sub 3} physical mixture with Nb/(Nb+Mo)=0.8 there is, besides {beta}{endash}Mo{sub 2}C and NbC formation, the appearance of a carbidic phase not detectable by x-ray diffraction (XRD). This phase appears to be highly active and selective for the dibenzothiophene hydrodesulfurization (HDS) reaction. {copyright} {ital 1998 Materials Research Society.}

  18. Chemical process hazards analysis

    Energy Technology Data Exchange (ETDEWEB)



    The Office of Worker Health and Safety (EH-5) under the Assistant Secretary for the Environment, Safety and Health of the US Department (DOE) has published two handbooks for use by DOE contractors managing facilities and processes covered by the Occupational Safety and Health Administration (OSHA) Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119), herein referred to as the PSM Rule. The PSM Rule contains an integrated set of chemical process safety management elements designed to prevent chemical releases that can lead to catastrophic fires, explosions, or toxic exposures. The purpose of the two handbooks, ``Process Safety Management for Highly Hazardous Chemicals`` and ``Chemical Process Hazards Analysis,`` is to facilitate implementation of the provisions of the PSM Rule within the DOE. The purpose of this handbook ``Chemical Process Hazards Analysis,`` is to facilitate, within the DOE, the performance of chemical process hazards analyses (PrHAs) as required under the PSM Rule. It provides basic information for the performance of PrHAs, and should not be considered a complete resource on PrHA methods. Likewise, to determine if a facility is covered by the PSM rule, the reader should refer to the handbook, ``Process Safety Management for Highly Hazardous Chemicals`` (DOE- HDBK-1101-96). Promulgation of the PSM Rule has heightened the awareness of chemical safety management issues within the DOE. This handbook is intended for use by DOE facilities and processes covered by the PSM rule to facilitate contractor implementation of the PrHA element of the PSM Rule. However, contractors whose facilities and processes not covered by the PSM Rule may also use this handbook as a basis for conducting process hazards analyses as part of their good management practices. This handbook explains the minimum requirements for PrHAs outlined in the PSM Rule. Nowhere have requirements been added beyond what is specifically required by the rule.

  19. Mineral Processing Technology Roadmap

    Energy Technology Data Exchange (ETDEWEB)



    This document represents the roadmap for Processing Technology Research in the US Mining Industry. It was developed based on the results of a Processing Technology Roadmap Workshop sponsored by the National Mining Association in conjunction with the US Department of Energy, Office of Energy Efficiency and Renewable Energy, Office of Industrial Technologies. The Workshop was held January 24 - 25, 2000.

  20. Relational Processing Following Stroke (United States)

    Andrews, Glenda; Halford, Graeme S.; Shum, David; Maujean, Annick; Chappell, Mark; Birney, Damian


    The research examined relational processing following stroke. Stroke patients (14 with frontal, 30 with non-frontal lesions) and 41 matched controls completed four relational processing tasks: sentence comprehension, Latin square matrix completion, modified Dimensional Change Card Sorting, and n-back. Each task included items at two or three…

  1. Food-Processing Wastes. (United States)

    Frenkel, Val S; Cummings, Gregg A; Maillacheruvu, K Y; Tang, Walter Z


    Literature published in 2016 and early 2017 related to food processing wastes treatment for industrial applications are reviewed. This review is a subsection of the Treatment Systems section of the annual Water Environment Federation literature review and covers the following food processing industries and applications: general, meat and poultry, fruits and vegetables, dairy and beverage, and miscellaneous treatment of food wastes.

  2. Hyperspectral image processing methods (United States)

    Hyperspectral image processing refers to the use of computer algorithms to extract, store and manipulate both spatial and spectral information contained in hyperspectral images across the visible and near-infrared portion of the electromagnetic spectrum. A typical hyperspectral image processing work...

  3. Suppliers solve processing problems (United States)

    The year's IFT food expo showcased numerous companies and organizations offering solutions to food processing needs and challenges. From small-scale unit operations to commercial-scale equipment lines, exhibitors highlighted both traditional and novel food processing operations fro food product dev...

  4. How cheese is processed (United States)

    This column continues the theme of "How Is It Processed?" with a focus on cheese. A fun fact is that it takes 10 pounds of milk to make one pound of cheese. Production of cheese is described in this column, as well as the effects of processing on the final properties of this popular food....

  5. Correctness of concurrent processes

    NARCIS (Netherlands)

    E.R. Olderog (Ernst-Rüdiger)


    textabstractA new notion of correctness for concurrent processes is introduced and investigated. It is a relationship P sat S between process terms P built up from operators of CCS [Mi 80], CSP [Ho 85] and COSY [LTS 79] and logical formulas S specifying sets of finite communication sequences as in

  6. Trapped in Process. (United States)

    Avallone, Susan; Berry, John


    The American Library Association (ALA) 1987 Midwinter Conference was characterized by process, particularly the new planning process which threatens to drain ALA's money and leadership energy away from the substantive issues that need attention, such as the next Librarian of Congress's qualifications and services to minorities and the poor. (EM)

  7. How honey is processed (United States)

    This month's column follows the "How Is It Processed?" theme. Honey has been called "the nectar of the gods" because of its rich histor and contribution to foods. This column will explore the properties of honey as well as how honey is processed - from flower to food....

  8. Uranium processing and properties

    CERN Document Server


    Covers a broad spectrum of topics and applications that deal with uranium processing and the properties of uranium Offers extensive coverage of both new and established practices for dealing with uranium supplies in nuclear engineering Promotes the documentation of the state-of-the-art processing techniques utilized for uranium and other specialty metals

  9. Advances in Solidification Processing

    Indian Academy of Sciences (India)


    Advances in Solidification Processing. FOREWORD. Solidification phenomena are the heart of most of ... Besides these, the new advances in the understanding of the process have led to the ... steel chemistry on the thermo-mechanical state of solidifying strands is discussed. Finally, control of continuous casting of stainless ...

  10. Process, Product, and Playmaking (United States)

    Fisher, Maisha T.; Purcell, Susie Spear; May, Rachel


    This article examines relationships among process, product, and playmaking in a southeastern playwriting and performance program for teen girls, Playmaking for Girls (PFG). The authors have chosen to focus on tensions between process and product. Such tensions are present in the challenges teachers experience when privileging student-centered…

  11. The Analytical Hierarchy Process

    DEFF Research Database (Denmark)

    Barfod, Michael Bruhn


    The technical note gathers the theory behind the Analytical Hierarchy Process (AHP) and present its advantages and disadvantages in practical use.......The technical note gathers the theory behind the Analytical Hierarchy Process (AHP) and present its advantages and disadvantages in practical use....

  12. Dissection of kinesin's processivity.

    Directory of Open Access Journals (Sweden)

    Sarah Adio

    Full Text Available The protein family of kinesins contains processive motor proteins that move stepwise along microtubules. This mechanism requires the precise coupling of the catalytic steps in the two heads, and their precise mechanical coordination. Here we show that these functionalities can be uncoupled in chimera of processive and non-processive kinesins. A chimera with the motor domain of Kinesin-1 and the dimerization domain of a non-processive Kinesin-3 motor behaves qualitatively as conventional kinesin and moves processively in TIRF and bead motility assays, suggesting that spatial proximity of two Kinein-1 motor domains is sufficient for processive behavior. In the reverse chimera, the non-processive motor domains are unable to step along microtubules, despite the presence of the Kinesin-1 neck coiled coil. Still, ATP-binding to one head of these chimera induces ADP-release from the partner head, a characteristic feature of alternating site catalysis. These results show that processive movement of kinesin dimers requires elements in the motor head that respond to ADP-release and induce stepping, in addition to a proper spacing of the motor heads via the neck coiled coil.

  13. Contaminated nickel scrap processing

    Energy Technology Data Exchange (ETDEWEB)

    Compere, A.L.; Griffith, W.L.; Hayden, H.W.; Johnson, J.S. Jr.; Wilson, D.F.


    The DOE will soon choose between treating contaminated nickel scrap as a legacy waste and developing high-volume nickel decontamination processes. In addition to reducing the volume of legacy wastes, a decontamination process could make 200,000 tons of this strategic metal available for domestic use. Contaminants in DOE nickel scrap include {sup 234}Th, {sup 234}Pa, {sup 137}Cs, {sup 239}Pu (trace), {sup 60}Co, U, {sup 99}Tc, and {sup 237}Np (trace). This report reviews several industrial-scale processes -- electrorefining, electrowinning, vapormetallurgy, and leaching -- used for the purification of nickel. Conventional nickel electrolysis processes are particularly attractive because they use side-stream purification of process solutions to improve the purity of nickel metal. Additionally, nickel purification by electrolysis is effective in a variety of electrolyte systems, including sulfate, chloride, and nitrate. Conventional electrorefining processes typically use a mixed electrolyte which includes sulfate, chloride, and borate. The use of an electrorefining or electrowinning system for scrap nickel recovery could be combined effectively with a variety of processes, including cementation, solvent extraction, ion exchange, complex-formation, and surface sorption, developed for uranium and transuranic purification. Selected processes were reviewed and evaluated for use in nickel side-stream purification. 80 refs.

  14. Heavy oils processing materials requirements crude processing

    Energy Technology Data Exchange (ETDEWEB)

    Sloley, Andrew W. [CH2M Hill, Englewood, CO (United States)


    Over time, recommended best practices for crude unit materials selection have evolved to accommodate new operating requirements, feed qualities, and product qualities. The shift to heavier oil processing is one of the major changes in crude feed quality occurring over the last 20 years. The three major types of crude unit corrosion include sulfidation attack, naphthenic acid attack, and corrosion resulting from hydrolyzable chlorides. Heavy oils processing makes all three areas worse. Heavy oils have higher sulfur content; higher naphthenic acid content; and are more difficult to desalt, leading to higher chloride corrosion rates. Materials selection involves two major criteria, meeting required safety standards, and optimizing economics of the overall plant. Proper materials selection is only one component of a plant integrity approach. Materials selection cannot eliminate all corrosion. Proper materials selection requires appropriate support from other elements of an integrity protection program. The elements of integrity preservation include: materials selection (type and corrosion allowance); management limits on operating conditions allowed; feed quality control; chemical additives for corrosion reduction; and preventive maintenance and inspection (PMI). The following discussion must be taken in the context of the application of required supporting work in all the other areas. Within that context, specific materials recommendations are made to minimize corrosion due to the most common causes in the crude unit. (author)

  15. Customer Innovation Process Leadership

    DEFF Research Database (Denmark)

    Lindgren, Peter; Jørgensen, Jacob Høj; Goduscheit, René Chester


    their innovation process. The customer innovation process and CIP-leadership are examined in 5 European case companies. The articles stress the necessity to have companies' innovation focus come closer to the customer and the customer innovation process. A key finding is the relative importance of placing......Innovation leadership has traditionally been focused on leading the companies' product development fast, cost effectively and with an optimal performance driven by technological inventions or by customers´ needs. To improve the efficiency of the product development process focus has been...... on different types of organisational setup to the product development model and process. The globalization and enhanced competitive markets are however changing the innovation game and the challenge to innovation leadership Excellent product development innovation and leadership seems not any longer to enough...

  16. Logistics Innovation Process Revisited

    DEFF Research Database (Denmark)

    Gammelgaard, Britta; Su, Shong-Iee Ivan; Yang, Su-Lan


    Purpose – The purpose of this paper is to learn more about logistics innovation processes and their implications for the focal organization as well as the supply chain, especially suppliers. Design/methodology/approach – The empirical basis of the study is a longitudinal action research project...... that was triggered by the practical needs of new ways of handling material flows of a hospital. This approach made it possible to revisit theory on logistics innovation process. Findings – Apart from the tangible benefits reported to the case hospital, five findings can be extracted from this study: the logistics...... on internal stakeholders as on external relationships; and logistics innovation process may start out as a dialectic, conflict ridden process and end up in a well-ordered goal-oriented teleological process. Research limitations/implications – In general, the study contributes to the knowledge base...

  17. Business process support

    Energy Technology Data Exchange (ETDEWEB)

    Carle, Adriana; Fiducia, Daniel [Transportadora de Gas del Sur S.A. (TGS), Buenos Aires (Argentina)


    This paper is about the own development of business support software. The developed applications are used to support two business processes: one of them is the process of gas transportation and the other is the natural gas processing. This software has interphases with the ERP SAP, software SCADA and on line gas transportation simulation software. The main functionalities of the applications are: entrance on line real time of clients transport nominations, transport programming, allocation of the clients transport nominations, transport control, measurements, balanced pipeline, allocation of gas volume to the gas processing plants, calculate of product tons processed in each plant and tons of product distributed to clients. All the developed software generates information to the internal staff, regulatory authorities and clients. (author)

  18. Managing Software Process Evolution

    DEFF Research Database (Denmark)

    This book focuses on the design, development, management, governance and application of evolving software processes that are aligned with changing business objectives, such as expansion to new domains or shifting to global production. In the context of an evolving business world, it examines...... the complete software process lifecycle, from the initial definition of a product to its systematic improvement. In doing so, it addresses difficult problems, such as how to implement processes in highly regulated domains or where to find a suitable notation system for documenting processes, and provides...... essential insights and tips to help readers manage process evolutions. And last but not least, it provides a wealth of examples and cases on how to deal with software evolution in practice. Reflecting these topics, the book is divided into three parts. Part 1 focuses on software business transformation...

  19. Beryllium chemistry and processing

    CERN Document Server

    Walsh, Kenneth A


    This book introduces beryllium; its history, its chemical, mechanical, and physical properties including nuclear properties. The 29 chapters include the mineralogy of beryllium and the preferred global sources of ore bodies. The identification and specifics of the industrial metallurgical processes used to form oxide from the ore and then metal from the oxide are thoroughly described. The special features of beryllium chemistry are introduced, including analytical chemical practices. Beryllium compounds of industrial interest are identified and discussed. Alloying, casting, powder processing, forming, metal removal, joining and other manufacturing processes are covered. The effect of composition and process on the mechanical and physical properties of beryllium alloys assists the reader in material selection. The physical metallurgy chapter brings conformity between chemical and physical metallurgical processing of beryllium, metal, alloys, and compounds. The environmental degradation of beryllium and its all...

  20. Manufacturing processes 4 forming

    CERN Document Server

    Klocke, Fritz


    This book provides essential information on metal forming, utilizing a practical distinction between bulk and sheet metal forming. In the field of bulk forming, it examines processes of cold, warm and hot bulk forming, as well as rolling and a new addition, the process of thixoforming. As for the field of sheet metal working, on the one hand it deals with sheet metal forming processes (deep drawing, flange forming, stretch drawing, metal spinning and bending). In terms of special processes, the chapters on internal high-pressure forming and high rate forming have been revised and refined. On the other, the book elucidates and presents the state of the art in sheet metal separation processes (shearing and fineblanking). Furthermore, joining by forming has been added to the new edition as a new chapter describing mechanical methods for joining sheet metals. The new chapter “Basic Principles” addresses both sheet metal and bulk forming, in addition to metal physics, plastomechanics and computational basics; ...

  1. Formed HIP Can Processing

    Energy Technology Data Exchange (ETDEWEB)

    Clarke, Kester Diederik [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)


    The intent of this report is to document a procedure used at LANL for HIP bonding aluminum cladding to U-10Mo fuel foils using a formed HIP can for the Domestic Reactor Conversion program in the NNSA Office of Material, Management and Minimization, and provide some details that may not have been published elsewhere. The HIP process is based on the procedures that have been used to develop the formed HIP can process, including the baseline process developed at Idaho National Laboratory (INL). The HIP bonding cladding process development is summarized in the listed references. Further iterations with Babcock & Wilcox (B&W) to refine the process to meet production and facility requirements is expected.

  2. Quantum independent increment processes

    CERN Document Server

    Franz, Uwe


    This is the second of two volumes containing the revised and completed notes of lectures given at the school "Quantum Independent Increment Processes: Structure and Applications to Physics". This school was held at the Alfried-Krupp-Wissenschaftskolleg in Greifswald in March, 2003, and supported by the Volkswagen Foundation. The school gave an introduction to current research on quantum independent increment processes aimed at graduate students and non-specialists working in classical and quantum probability, operator algebras, and mathematical physics. The present second volume contains the following lectures: "Random Walks on Finite Quantum Groups" by Uwe Franz and Rolf Gohm, "Quantum Markov Processes and Applications in Physics" by Burkhard Kümmerer, Classical and Free Infinite Divisibility and Lévy Processes" by Ole E. Barndorff-Nielsen, Steen Thorbjornsen, and "Lévy Processes on Quantum Groups and Dual Groups" by Uwe Franz.

  3. Beyond the search process

    DEFF Research Database (Denmark)

    Hyldegård, Jette


    This paper reports on the findings from a longitudinal case study exploring Kuhlthau's information search process (ISP)-model in a group based academic setting. The research focus is on group members' activities and cognitive and emotional experiences during the task process of writing an assignm......This paper reports on the findings from a longitudinal case study exploring Kuhlthau's information search process (ISP)-model in a group based academic setting. The research focus is on group members' activities and cognitive and emotional experiences during the task process of writing...... seeking, the cognitive pattern associated with focus formulation and the tendency towards an increase in writing activities while searching activities decreased. Differences in behavior were also found, which were associated with contextual and social factors beyond the mere search process...

  4. Branching processes in biology

    CERN Document Server

    Kimmel, Marek


    This book provides a theoretical background of branching processes and discusses their biological applications. Branching processes are a well-developed and powerful set of tools in the field of applied probability. The range of applications considered includes molecular biology, cellular biology, human evolution and medicine. The branching processes discussed include Galton-Watson, Markov, Bellman-Harris, Multitype, and General Processes. As an aid to understanding specific examples, two introductory chapters, and two glossaries are included that provide background material in mathematics and in biology. The book will be of interest to scientists who work in quantitative modeling of biological systems, particularly probabilists, mathematical biologists, biostatisticians, cell biologists, molecular biologists, and bioinformaticians. The authors are a mathematician and cell biologist who have collaborated for more than a decade in the field of branching processes in biology for this new edition. This second ex...

  5. Continuous affine processes

    DEFF Research Database (Denmark)

    Buchardt, Kristian


    Affine processes possess the property that expectations of exponential affine transformations are given by a set of Riccati differential equations, which is the main feature of this popular class of processes. In this paper we generalise these results for expectations of more general transformati......Affine processes possess the property that expectations of exponential affine transformations are given by a set of Riccati differential equations, which is the main feature of this popular class of processes. In this paper we generalise these results for expectations of more general...... transformations. This is of interest in, e.g. doubly stochastic Markov models, in particular in life insurance. When using affine processes for modelling the transition rates and interest rate, the results presented allow for easy calculation of transition probabilities and expected present values....

  6. Characterization of fundamental catalytic properties of MoS2/WS2 nanotubes and nanoclusters for desulfurization catalysis - a surface temperature study

    Energy Technology Data Exchange (ETDEWEB)

    U. Burghaus


    The prior project consisted of two main project lines. First, characterization of novel nanomaterials for hydrodesulfurization (HDS) applications. Second, studying more traditional model systems for HDS such as vapor-deposited silica-supported Mo and MoSx clusters. In the first subproject, we studied WS2 and MoS2 fullerene-like nanoparticles as well as WS2 nanotubes. Thiophene (C4H4S) was used as the probe molecule. Interestingly, metallic and sulfur-like adsorption sites could be identified on the silica-supported fullerene-particles system. Similar structures are seen for the traditional system (vapor-deposited clusters). Thus, this may be a kinetics fingerprint feature of modern HDS model systems. In addition, kinetics data allowed characterization of the different adsorption sites for thiophene on and inside WS2 nanotube bundles. The latter is a unique feature of nanotubes that has not been reported before for any inorganic nanotube system; however, examples are known for carbon nanotubes, including prior work of the PI. Although HDS has been studied for decades, utilizing nanotubes as nanosized HDS reactors has never been tried before, as far as we know. This is of interest from a fundamental perspective. Unfortunately, the HDS activity of the nanocatalysts at ultra-high vacuum (UHV) conditions was close to the detection limit of our techniques. Therefore, we propose to run experiments at ambient pressure on related nanopowder samples as part of the renewal application utilizing a now-available GC (gas chromatograph) setup. In addition, Ni and Co doped nanocatalyts are proposed for study. These dopants will boost the catalytic activity. In the second subproject of the prior grant, we studied HDS-related chemistry on more traditional supported cluster catalysts. Mo clusters supported by physical vapor deposition (PVD) on silica have been characterized. Two reaction pathways are evident when adsorbing thiophene on Mo and MoSx clusters: molecular adsorption and

  7. Euglena Transcript Processing. (United States)

    McWatters, David C; Russell, Anthony G


    RNA transcript processing is an important stage in the gene expression pathway of all organisms and is subject to various mechanisms of control that influence the final levels of gene products. RNA processing involves events such as nuclease-mediated cleavage, removal of intervening sequences referred to as introns and modifications to RNA structure (nucleoside modification and editing). In Euglena, RNA transcript processing was initially examined in chloroplasts because of historical interest in the secondary endosymbiotic origin of this organelle in this organism. More recent efforts to examine mitochondrial genome structure and RNA maturation have been stimulated by the discovery of unusual processing pathways in other Euglenozoans such as kinetoplastids and diplonemids. Eukaryotes containing large genomes are now known to typically contain large collections of introns and regulatory RNAs involved in RNA processing events, and Euglena gracilis in particular has a relatively large genome for a protist. Studies examining the structure of nuclear genes and the mechanisms involved in nuclear RNA processing have revealed that indeed Euglena contains large numbers of introns in the limited set of genes so far examined and also possesses large numbers of specific classes of regulatory and processing RNAs, such as small nucleolar RNAs (snoRNAs). Most interestingly, these studies have also revealed that Euglena possesses novel processing pathways generating highly fragmented cytosolic ribosomal RNAs and subunits and non-conventional intron classes removed by unknown splicing mechanisms. This unexpected diversity in RNA processing pathways emphasizes the importance of identifying the components involved in these processing mechanisms and their evolutionary emergence in Euglena species.

  8. Welding processes handbook

    CERN Document Server

    Weman, Klas


    Deals with the main commercially significant and commonly used welding processes. This title takes the student or novice welder through the individual steps involved in each process in an easily understood way. It covers many of the requirements referred to in European Standards including EN719, EN 729, EN 729 and EN 287.$bWelding processes handbook is a concise, explanatory guide to the main commercially significant and commonly-used welding processes. It takes the novice welder or student through the individual steps involved in each process in a clear and easily understood way. It is intended to provide an up-to-date reference to the major applications of welding as they are used in industry. The contents have been arranged so that it can be used as a textbook for European welding courses in accordance with guidelines from the European Welding Federation. Welding processes and equipment necessary for each process are described so that they can be applied to all instruction levels required by the EWF and th...

  9. States in Process Calculi

    Directory of Open Access Journals (Sweden)

    Christoph Wagner


    Full Text Available Formal reasoning about distributed algorithms (like Consensus typically requires to analyze global states in a traditional state-based style. This is in contrast to the traditional action-based reasoning of process calculi. Nevertheless, we use domain-specific variants of the latter, as they are convenient modeling languages in which the local code of processes can be programmed explicitly, with the local state information usually managed via parameter lists of process constants. However, domain-specific process calculi are often equipped with (unlabeled reduction semantics, building upon a rich and convenient notion of structural congruence. Unfortunately, the price for this convenience is that the analysis is cumbersome: the set of reachable states is modulo structural congruence, and the processes' state information is very hard to identify. We extract from congruence classes of reachable states individual state-informative representatives that we supply with a proper formal semantics. As a result, we can now freely switch between the process calculus terms and their representatives, and we can use the stateful representatives to perform assertional reasoning on process calculus models.

  10. Organic waste incineration processes

    Energy Technology Data Exchange (ETDEWEB)

    Lemort, F.; Charvillat, J.P.; Nabot, J.P. [CEA Valrho, Bagnols sur Ceze Cedex (France); Chateauvieux, H.; Thiebaut, C. [CEA Valduc, 21 - Is-sur-Tille (France)


    Nuclear activities produce organic waste compatible with thermal processes designed to obtain a significant weight and volume reduction as well as to stabilize the inorganic residue in a form suitable for various interim storage or disposal routes. Several processes may be implemented (e.g. excess air, plasma, fluidized bed or rotating furnace) depending on the nature of the waste and the desired objectives. The authors focus on the IRIS rotating-kiln process, which was used for the first time with radioactive materials during the first half of 1999. IRIS is capable of processing highly chlorinated and {alpha}-contaminated waste at a rate of several kilograms per hour, while limiting corrosion due to chlorine as well as mechanical entrainment of radioactive particles in the off-gas stream. Although operated industrially, the process is under continual development to improve its performance and adapt it to a wider range of industrial applications. The main focus of attention today is on adapting the pyrolytic processes to waste with highly variable compositions and to enhance the efficiency of the off-gas purification systems. These subjects are of considerable interest for a large number of heat treatment processes (including all off-gas treatment systems) for which extremely durable, high-performance and low-flow electrostatic precipitators are now being developed. (author)

  11. Biological process linkage networks.

    Directory of Open Access Journals (Sweden)

    Dikla Dotan-Cohen

    Full Text Available The traditional approach to studying complex biological networks is based on the identification of interactions between internal components of signaling or metabolic pathways. By comparison, little is known about interactions between higher order biological systems, such as biological pathways and processes. We propose a methodology for gleaning patterns of interactions between biological processes by analyzing protein-protein interactions, transcriptional co-expression and genetic interactions. At the heart of the methodology are the concept of Linked Processes and the resultant network of biological processes, the Process Linkage Network (PLN.We construct, catalogue, and analyze different types of PLNs derived from different data sources and different species. When applied to the Gene Ontology, many of the resulting links connect processes that are distant from each other in the hierarchy, even though the connection makes eminent sense biologically. Some others, however, carry an element of surprise and may reflect mechanisms that are unique to the organism under investigation. In this aspect our method complements the link structure between processes inherent in the Gene Ontology, which by its very nature is species-independent. As a practical application of the linkage of processes we demonstrate that it can be effectively used in protein function prediction, having the power to increase both the coverage and the accuracy of predictions, when carefully integrated into prediction methods.Our approach constitutes a promising new direction towards understanding the higher levels of organization of the cell as a system which should help current efforts to re-engineer ontologies and improve our ability to predict which proteins are involved in specific biological processes.

  12. Staging Collaborative Innovation Processes

    DEFF Research Database (Denmark)

    Pedersen, Signe; Clausen, Christian

    and public private innovation partnerships. Based on a case study of a collaborative design process in a large electronics company the paper points to the key importance of staging and navigation of collaborative innovation process. Staging and navigation is presented as a combined activity: 1) to translate......Organisations are currently challenged by demands for increased collaborative innovation internally as well as with external and new entities - e.g. across the value chain. The authors seek to develop new approaches to managing collaborative innovative processes in the context of open innovation...

  13. Revealing the programming process

    DEFF Research Database (Denmark)

    Bennedsen, Jens; Caspersen, Michael Edelgaard


    One of the most important goals of an introductory programming course is that the students learn a systematic approach to the development of computer programs. Revealing the programming process is an important part of this; however, textbooks do not address the issue -- probably because...... the textbook medium is static and therefore ill-suited to expose the process of programming. We have found that process recordings in the form of captured narrated programming sessions are a simple, cheap, and efficient way of providing the revelation.We identify seven different elements of the programming...

  14. Product and Process Modelling

    DEFF Research Database (Denmark)

    Cameron, Ian T.; Gani, Rafiqul

    of process industries. The book builds on the extensive modelling experience of the authors, who have developed models for both research and industrial purposes. It complements existing books by the authors in the modelling area. Those areas include the traditional petroleum and petrochemical industries...... to biotechnology applications, food, polymer and human health application areas. The book highlights to important nature of modern product and process modelling in the decision making processes across the life cycle. As such it provides an important resource for students, researchers and industrial practitioners....

  15. Irreversible processes kinetic theory

    CERN Document Server

    Brush, Stephen G


    Kinetic Theory, Volume 2: Irreversible Processes deals with the kinetic theory of gases and the irreversible processes they undergo. It includes the two papers by James Clerk Maxwell and Ludwig Boltzmann in which the basic equations for transport processes in gases are formulated, together with the first derivation of Boltzmann's ""H-theorem"" and a discussion of this theorem, along with the problem of irreversibility.Comprised of 10 chapters, this volume begins with an introduction to the fundamental nature of heat and of gases, along with Boltzmann's work on the kinetic theory of gases and s

  16. Robot welding process control (United States)

    Romine, Peter L.


    This final report documents the development and installation of software and hardware for Robotic Welding Process Control. Primary emphasis is on serial communications between the CYRO 750 robotic welder, Heurikon minicomputer running Hunter & Ready VRTX, and an IBM PC/AT, for offline programming and control and closed-loop welding control. The requirements for completion of the implementation of the Rocketdyne weld tracking control are discussed. The procedure for downloading programs from the Intergraph, over the network, is discussed. Conclusions are made on the results of this task, and recommendations are made for efficient implementation of communications, weld process control development, and advanced process control procedures using the Heurikon.

  17. Plasma processing for VLSI

    CERN Document Server

    Einspruch, Norman G


    VLSI Electronics: Microstructure Science, Volume 8: Plasma Processing for VLSI (Very Large Scale Integration) discusses the utilization of plasmas for general semiconductor processing. It also includes expositions on advanced deposition of materials for metallization, lithographic methods that use plasmas as exposure sources and for multiple resist patterning, and device structures made possible by anisotropic etching.This volume is divided into four sections. It begins with the history of plasma processing, a discussion of some of the early developments and trends for VLSI. The second section

  18. Transnational Learning Processes

    DEFF Research Database (Denmark)

    Nedergaard, Peter

    This paper analyses and compares the transnational learning processes in the employment field in the European Union and among the Nordic countries. Based theoretically on a social constructivist model of learning and methodologically on a questionnaire distributed to the relevant participants......, a number of hypotheses concerning transnational learning processes are tested. The paper closes with a number of suggestions regarding an optimal institutional setting for facilitating transnational learning processes.Key words: Transnational learning, Open Method of Coordination, Learning, Employment......, European Employment Strategy, European Union, Nordic countries....

  19. The image processing handbook

    CERN Document Server

    Russ, John C


    Now in its fifth edition, John C. Russ's monumental image processing reference is an even more complete, modern, and hands-on tool than ever before. The Image Processing Handbook, Fifth Edition is fully updated and expanded to reflect the latest developments in the field. Written by an expert with unequalled experience and authority, it offers clear guidance on how to create, select, and use the most appropriate algorithms for a specific application. What's new in the Fifth Edition? ·       A new chapter on the human visual process that explains which visual cues elicit a response from the vie

  20. Ultrasonic Processing of Materials

    Energy Technology Data Exchange (ETDEWEB)

    Meek, Thomas T.; Han, Qingyou; Jian, Xiaogang; Xu, Hanbing


    The purpose of this project was to determine the impact of a new breakthrough technology, ultrasonic processing, on various industries, including steel, aluminum, metal casting, and forging. The specific goals of the project were to evaluate core principles and establish quantitative bases for the ultrasonc processing of materials, and to demonstrate key applications in the areas of grain refinement of alloys during solidification and degassing of alloy melts. This study focussed on two classes of materials - aluminum alloys and steels - and demonstrated the application of ultrasonic processing during ingot casting.

  1. Getting Started with Processing

    CERN Document Server

    Reas, Casey


    Learn computer programming the easy way with Processing, a simple language that lets you use code to create drawings, animation, and interactive graphics. Programming courses usually start with theory, but this book lets you jump right into creative and fun projects. It's ideal for anyone who wants to learn basic programming, and serves as a simple introduction to graphics for people with some programming skills. Written by the founders of Processing, this book takes you through the learning process one step at a time to help you grasp core programming concepts. You'll learn how to sketch wi

  2. Semi-Markov processes

    CERN Document Server



    Semi-Markov Processes: Applications in System Reliability and Maintenance is a modern view of discrete state space and continuous time semi-Markov processes and their applications in reliability and maintenance. The book explains how to construct semi-Markov models and discusses the different reliability parameters and characteristics that can be obtained from those models. The book is a useful resource for mathematicians, engineering practitioners, and PhD and MSc students who want to understand the basic concepts and results of semi-Markov process theory. Clearly defines the properties and

  3. IT Project Prioritization Process

    DEFF Research Database (Denmark)

    Shollo, Arisa; Constantiou, Ioanna


    In most of the large companies IT project prioritization process is designed based on principles of evidencebased management. We investigate a case of IT project prioritization in a financial institution, and in particular, how managers practice evidence-based management during this process. We use...... a rich dataset built from a longitudinal study of the prioritization process for the IT projects. Our findings indicate that managers reach a decision not only by using evidence but from the interplay between the evidence and the judgment devices that managers employ. The interplay between evidence...

  4. Hydrodesulfurization of methyl-substituted dibenzothiophenes (DBT) catalyzed by sulfided Co-Mo/. gamma. -Al/sub 2/O/sub 3/

    Energy Technology Data Exchange (ETDEWEB)

    Houalla, M.; Broderick, D.H.; Sapre, A.V.; Nag, N.K.; De Beer, V.H.J.; Gates, B.C.; Kwart, H.


    Integral conversion data were obtained for DBT, 2,8-dimethyl-DBT, 3,7-dimethyl-DBT, 4-methyl-DBT, and 4,6-dimethyl-DBT over commercial sulfided alumina-supported cobalt-molybdenum catalyst at 300/sup 0/C and 102 atm. Pseudo-first-order rate constants showed that methyl substitution in the 2 and 8 positions of DBT had very little effect, that methyl substitution in the 3 and 7 positions of DBT reduced the reactivity slightly, and that methyl substitution in the 4 and 6 positions reduced the reactivity considerably. The reactivities of the methylated DBT's were of the same order in competitive reactions of substituted DBT with DBT, but the rate constant of DBT decreased, which indicated that competitive adsorption occurred. Product distributions suggested subsequent reactions of DBT or methyl-substituted DBT to biphenyl or methyl-substituted biphenyl and to cyclohexylbenzene or methyl-substituted cyclohexylbenzene; the compounds with methyl groups in the 4 position probably experienced more hydrogenation prior to sulfur removal.

  5. Hydrodesulfurization of methyl-substituted dibenzothiophenes catalzed by sulfided Co-MO/. gamma. -Al/sub 2/O/sub 3/

    Energy Technology Data Exchange (ETDEWEB)

    Houalla, M.; Broderick, D.H.; Sapre, A.V.; Nag, N.K.; De Beer, V.H.J.; Gates, B.C.; Kwart, H.


    The objective of the experiments was to provide a quantitative measure of the reactivities of methyl-substituted dibenzothiophenes under high-pressure reaction conditions representative of industrial practice. A flow microreactor was used with liquid feeds containing n-hexadecane (carrier oil), H/sub 2/, and either a single sulfur-containing compound or a pair of sulfur-containing compounds, one of them being DBT. The results show that, to a first approximation, each of the compounds reacted by simple sulfur extrusion (with DBT, for example, giving primarily biphenyl + H/sub 2/S). Methyl substituents in the 4 and 4 and 6 positions reduced the reactivity significantly. The competitive reaction studies indicate competitive adsorption of the sulfur- containing reactants, with the less reactive compounds being less strongly adsorbed and being less effective as inhibitors. The catalyst was commercial Co-MO/..gamma..-Al/sub 2/O/sub 3/. The data presented here are supportive of the idea that adsorption of the reactants involves bonding to the catalyst surface with the ..pi.. electrons of the benzenoid rings as well as with the sulfur atom; mild steric effects explain the influence of methyl groups in the 4 and 6 positions. 1 figure, 1 table. (DP)

  6. Business Process Outsourcing

    National Research Council Canada - National Science Library

    Hurbean, Luminita; FOTACHE, Doina


    Business Process Outsourcing (BPO) is gaining widespread acceptance throughout the US, Europe, South America and Asia Pacific as the top executives of leading multinationals turn to outsourcing as a strategic management tool...

  7. Survey of welding processes. (United States)


    The current KYTC SPECIAL PROVISION NO. 4 WELDING STEEL BRIDGES prohibits the use of welding processes other than shielded metal arc welding (SMAW) and submerged arc welding (SAW). Nationally, bridge welding is codified under ANSI/AASHTO/AWS D1....

  8. Attention processes in autism

    National Research Council Canada - National Science Library

    Martos-Pérez, J


    ... findings that have been obtained so far are also reported. Some attentional processes, such as selective or sustained attention, are not altered in autism or not enough evidence has been found to support such a hypothesis...

  9. Rubber compounding and processing

    CSIR Research Space (South Africa)

    John, MJ


    Full Text Available This chapter presents an overview on the compounding and processing techniques of natural rubber compounds. The introductory portion deals with different types of rubbers and principles of rubber compounding. The primary and secondary fillers used...

  10. Vocal process granuloma. (United States)

    al-Dousary, S


    Vocal process granuloma or contact ulcer is uncommon disease in which there is chronic irritation and granulation tissue formation at the posterior third of the vocal folds. Thirteen patients (11 men and two women) with vocal process granuloma were enrolled in this study; cases of intubation granuloma were excluded. The most frequent complaints were throat irritation, frequent throat clearing and voice change. Forty-seven percent of patients had a recurrence two to four months after surgery. Computed tomography (CT) of the larynx in four patients showed arytenoid sclerosis on the involved side and disclosed moderate enhancement of the vocal fold granuloma after contrast injection in one. Three patients had hyperacidity and four had hyperfunctioning granulomas: two used their voices excessively and the other two had bilateral sulcus vocalis. To our knowledge this is the first report of sulcus vocalis with vocal process granuloma, and of enhanced vocal process granuloma.

  11. Radiation processing in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Makuuchi, Keizo [Japan Atomic Energy Research Inst., Takasaki, Gunma (Japan). Takasaki Radiation Chemistry Research Establishment


    Economic scale of radiation application in the field of industry, agriculture and medicine in Japan in 1997 was investigated to compare its economic impacts with that of nuclear energy industry. Total production value of radiation application accounted for 54% of nuclear industry including nuclear energy industry and radiation applications in three fields above. Industrial radiation applications were further divided into five groups, namely nondestructive test, RI instruments, radiation facilities, radiation processing and ion beam processing. More than 70% of the total production value was brought about by ion beam processing for use with IC and semiconductors. Future economic prospect of radiation processing of polymers, for example cross-linking, EB curing, graft polymerization and degradation, is reviewed. Particular attention was paid to radiation vulcanization of natural rubber latex and also to degradation of natural polymers. (S. Ohno)

  12. Processed Products Database System (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Collection of annual data on processed seafood products. The Division provides authoritative advice, coordination and guidance on matters related to the collection,...

  13. Introduction to stochastic processes

    CERN Document Server

    Cinlar, Erhan


    Clear presentation employs methods that recognize computer-related aspects of theory. Topics include expectations and independence, Bernoulli processes and sums of independent random variables, Markov chains, renewal theory, more. 1975 edition.

  14. Project management process. (United States)


    This course provides INDOT staff with foundational knowledge and skills in project management principles and methodologies. INDOTs project management processes provide the tools for interdisciplinary teams to efficiently and effectively deliver pr...

  15. Dissolution processes. [224 references

    Energy Technology Data Exchange (ETDEWEB)

    Silver, G.L.


    This review contains more than 100 observations and 224 references on the dissolution phenomenon. The dissolution processes are grouped into three categories: methods of aqueous attack, fusion methods, and miscellaneous observations on phenomena related to dissolution problems. (DLC)

  16. Processing composite materials (United States)

    Baucom, R. M.


    The fabrication of several composite structural articles including DC-10 upper aft rudders, L-1011 vertical fins and composite biomedical appliances are discussed. Innovative composite processing methods are included.

  17. Essentials of stochastic processes

    CERN Document Server

    Durrett, Richard


    Building upon the previous editions, this textbook is a first course in stochastic processes taken by undergraduate and graduate students (MS and PhD students from math, statistics, economics, computer science, engineering, and finance departments) who have had a course in probability theory. It covers Markov chains in discrete and continuous time, Poisson processes, renewal processes, martingales, and option pricing. One can only learn a subject by seeing it in action, so there are a large number of examples and more than 300 carefully chosen exercises to deepen the reader’s understanding. Drawing from teaching experience and student feedback, there are many new examples and problems with solutions that use TI-83 to eliminate the tedious details of solving linear equations by hand, and the collection of exercises is much improved, with many more biological examples. Originally included in previous editions, material too advanced for this first course in stochastic processes has been eliminated while treatm...

  18. Product and Process Modelling

    DEFF Research Database (Denmark)

    Cameron, Ian T.; Gani, Rafiqul

    to biotechnology applications, food, polymer and human health application areas. The book highlights to important nature of modern product and process modelling in the decision making processes across the life cycle. As such it provides an important resource for students, researchers and industrial practitioners.......This book covers the area of product and process modelling via a case study approach. It addresses a wide range of modelling applications with emphasis on modelling methodology and the subsequent in-depth analysis of mathematical models to gain insight via structural aspects of the models....... These approaches are put into the context of life cycle modelling, where multiscale and multiform modelling is increasingly prevalent in the 21st century. The book commences with a discussion of modern product and process modelling theory and practice followed by a series of case studies drawn from a variety...

  19. Product and Process Modelling

    DEFF Research Database (Denmark)

    Cameron, Ian T.; Gani, Rafiqul

    This book covers the area of product and process modelling via a case study approach. It addresses a wide range of modelling applications with emphasis on modelling methodology and the subsequent in-depth analysis of mathematical models to gain insight via structural aspects of the models...... of process industries. The book builds on the extensive modelling experience of the authors, who have developed models for both research and industrial purposes. It complements existing books by the authors in the modelling area. Those areas include the traditional petroleum and petrochemical industries...... to biotechnology applications, food, polymer and human health application areas. The book highlights to important nature of modern product and process modelling in the decision making processes across the life cycle. As such it provides an important resource for students, researchers and industrial practitioners....

  20. Auditory Processing Disorders (United States)

    ... APD is common in older adults, particularly when hearing loss is present. It is likely that many processes and problems contribute to APD in children. In adults, neurological disorders such as stroke, tumors, degenerative disease (such as ...


    Directory of Open Access Journals (Sweden)

    Yu. Taranenko


    Full Text Available The article deals with the theoretical basis of the simulation. The study shows the simulation of logistic processes in industrial countries is an integral part of many economic projects aimed at the creation or improvement of logistics systems. The paper was used model Beer Game for management of logistics processes in the enterprise. The simulation model implements in AnyLogic package. AnyLogic product allows us to consider the logistics processes as an integrated system, which allows reaching better solutions. Logistics process management involves pooling the sales market, production and distribution to ensure the temporal level of customer service at the lowest cost overall. This made it possible to conduct experiments and to determine the optimal size of the warehouse at the lowest cost.


    Directory of Open Access Journals (Sweden)

    Igor G. Fedorov


    Full Text Available We can be mistaken to formulate basic concepts of process management, and we are at risk to be on the wrong way solving the focused problems – instead of process management we could do automatization, instead of process system we could introduce function-oriented system. Without having a clear idea of the model we have to execute, we can plan this model as an analytical one and do not include all the necessary tools for management on the stage of planning. The article is targeted for the analysts who have skills in analytical modeling of business processes and would like to make a step forward to the implementation of these models. In order to become professionals in this field it is necessary to learn the terminology, first of all. 

  3. Nonferrous Metal Processing Plants (United States)

    Department of Homeland Security — This map layer includes nonferrous metal processing plants in the United States. The data represent commodities covered by the Minerals Information Team (MIT) of the...

  4. The Critical Design Process

    DEFF Research Database (Denmark)

    Brunsgaard, Camilla; Knudstrup, Mary-Ann; Heiselberg, Per


    The “Comfort Houses” project is the most ambitious building project for passive, single-family houses even undertaken in Denmark. Thus far, different consortiums have designed and built 10 houses. Besides fulfilling the German passive-house standard, the goal of the project was to build the houses...... within Danish tradition of architecture and construction. The objective of the research presented in this paper, is to compare the different design processes behind the making of passive houses in a Danish context. We evaluated the process with regard to the integrated and traditional design process....... Data analysis showed that the majority of the consortiums worked in an integrated manner; though there was room for improvment. Additionally, the paper discusses the challanges of implementing the integrated design process in practice and suggests ways of overcomming some of the barriers . In doing so...

  5. Acoustic MIMO signal processing

    CERN Document Server

    Huang, Yiteng; Chen, Jingdong


    A timely and important book addressing a variety of acoustic signal processing problems under multiple-input multiple-output (MIMO) scenarios. It uniquely investigates these problems within a unified framework offering a novel and penetrating analysis.

  6. Cooperative processing data bases (United States)

    Hasta, Juzar


    Cooperative processing for the 1990's using client-server technology is addressed. The main theme is concepts of downsizing from mainframes and minicomputers to workstations on a local area network (LAN). This document is presented in view graph form.

  7. Type Certification Process (United States)


    This order prescribes the responsibilities and procedures for Federal Aviation Administration (FAA) aircraft certification personnel responsible for the certification process required by the Federal Aviation Regulations for civil aircraft,aircraft en...

  8. Ultrahigh bandwidth signal processing

    DEFF Research Database (Denmark)

    Oxenløwe, Leif Katsuo


    Optical time lenses have proven to be very versatile for advanced optical signal processing. Based on a controlled interplay between dispersion and phase-modulation by e.g. four-wave mixing, the processing is phase-preserving, an hence useful for all types of data signals including coherent multi......-level modulation founats. This has enabled processing of phase-modulated spectrally efficient data signals, such as orthogonal frequency division multiplexed (OFDM) signa In that case, a spectral telescope system was used, using two time lenses with different focal lengths (chirp rates), yielding a spectral...... regeneratio These operations require a broad bandwidth nonlinear platform, and novel photonic integrated nonlinear platform like aluminum gallium arsenide nano-waveguides used for 1.28 Tbaud optical signal processing will be described....

  9. Laser Processed Heat Exchangers (United States)

    Hansen, Scott


    The Laser Processed Heat Exchanger project will investigate the use of laser processed surfaces to reduce mass and volume in liquid/liquid heat exchangers as well as the replacement of the harmful and problematic coatings of the Condensing Heat Exchangers (CHX). For this project, two scale unit test articles will be designed, manufactured, and tested. These two units are a high efficiency liquid/liquid HX and a high reliability CHX.

  10. Catalyzing alignment processes

    DEFF Research Database (Denmark)

    Lauridsen, Erik Hagelskjær; Jørgensen, Ulrik


    This paper describes how environmental management systems (EMS) spur the circulation of processes that support the constitution of environmental issues as specific environ¬mental objects and objectives. EMS catalyzes alignmentprocesses that produce coherence among the different elements involved...... time and in combination with other social processes establish more aligned and standardized environmental performance between countries. However, examples of the introduction of environmental management suggests that EMS’ only plays a minor role in developing the actual environmental objectives...

  11. Image Processing Research (United States)


    Picture Processing," USCEE Report No. 530, 1974, pp. 11-19. 4.7 Spectral Sensitivity Estimation of a Color Image Scanner Clanton E. Mancill and William...Projects: the improvement of image fidelity and presentation format; (3) Image Data Extraction Projects: the recognition of objects within pictures ...representation; (5) Image Proc- essing Systems Projects: the development of image processing hardware and software support systems. 14. Key words : Image

  12. Poststroke neuroplasticity processes

    Directory of Open Access Journals (Sweden)

    I. V. Damulin


    Full Text Available The paper considers different aspects of neuroplasticity in patients with stroke. It underlines the dynamism of this process and the ambiguity of involvement of the structures of the contralateral cerebral hemisphere in the restorative process. It considers the periods after onset of stroke and the activation of different brain regions (of both the involved and intact hemisphere in the poststroke period. Particular emphasis is placed on the issues of neurorehabilitation in this category of patients. Delay in rehabilitation measures leads to a worse outcome, the patients must be at hospital longer. It is emphasized that the neurorehabilitaton measures should use strategies aimed at improving plasticity processes at the level of synaptic transmission and neuronal communications. At the same time, of great importance are the processes of structural and functional remodeling of neuronal communications with the involvement of surviving neurons that are located in the peri-infarct area and partially damaged during ischemia. To recover stroke-induced lost motor functions, measures are implemented to modulate the ipsilateral motor cortex, contralateral motor cortex, and sensory afferentation. Remodeling processes, one of the manifestations of neuroplasticity, vary with the size and location of an ischemic focus. The specific features of this process with subcortical and cortical foci are considered. It is stressed that there are genetically determined neurotrophic factors that may enhance remodeling processes in the peri-infarct area, as well as factors that inhibit these processes. The sensory system is noted to have a high potential of compensation, which is appreciably associated with the considerable extent of sensory fibers even at the level of the cerebral cortex.

  13. Diasporic Relationships and Processes

    DEFF Research Database (Denmark)

    Singla, Rashmi


    How does moving across the geographical borders affect the relationships of diaspora members both here – in the country of residence and there- in the country of origin? The article delineates some of the processes through gendered experiences of the young adults perceived as active actors based...... an empirical longitudinal study. The results indicate transformations in belongings and longings indicating reinterpretation of the self, others and home in context of exclusion processes at various levels....

  14. Electron Beam Materials Processing (United States)

    Powers, Donald E.


    In electron beam processing, a well-defined beam of relatively energetic electrons produced by a high voltage acceleration gap is used to transmit thermal energy into a material in a precise manner. This controlled deposition of heat is employed in a wide variety of industrial applications for precision cutting, drilling, and welding of materials as well as annealing, glazing, and surface hardening. This chapter will describe the equipment used and the most prominent industrial applications for this process.

  15. Solution Processing - Rodlike Polymers (United States)


    side it necessary and identify by block number) Para-ordered Polymers High Modulus Fibers and Films Polybenzobisoxazoles Polybenzobisthiazoles 20...considerations important in solution processing are considered, with special emphasis on the dry-jet wet spinning process used to form fibers . Pertinent...Company, Summit, N.J. iii TABLE OF CONTENTS 1. INTRODUCTION ................ .......................... .. 1 2. REMARKS ON DRY-JET WET SPUN FIBER

  16. Process for compound transformation

    KAUST Repository

    Basset, Jean-Marie


    Embodiments of the present disclosure provide for methods of using a catalytic system to chemically transform a compound (e.g., a hydrocarbon). In an embodiment, the method does not employ grafting the catalyst prior to catalysis. In particular, embodiments of the present disclosure provide for a process of hydrocarbon (e.g., C1 to C20 hydrocarbon) metathesis (e.g., alkane, olefin, or alkyne metathesis) transformation, where the process can be conducted without employing grafting prior to catalysis.

  17. The Integrated Renovation Process

    DEFF Research Database (Denmark)

    Galiotto, Nicolas; Heiselberg, Per; Knudstrup, Mary-Ann


    . With the purpose of overcoming such barriers, a new scheme was proposed: the Integrated Renovation Process. In this paper, the scheme is applied to two single-family homes and is called the Integrated Renovation Process for Homes (IRP4homes). In both case studies, the newly developed methodology successfully led...... renovated home. Most homeowners’ needs, preferences and personal values were fulfilled. Eventually, all homeowners selected a high-performance renovation scenario....

  18. Personal sale process

    Directory of Open Access Journals (Sweden)

    Gašović Milan


    Full Text Available Experience from prior successful sale of many companies from different business activities, tells us that it is necessary to create approach system, flexible to different buyers and environment. The base of this system is a belief that salesmen can stimulate big buyers to make buying decisions, if the selling process is done well. Emphasis is made on practical selling techniques which are used in the whole selling process.

  19. Biomedical signal processing

    CERN Document Server

    Akay, Metin


    Sophisticated techniques for signal processing are now available to the biomedical specialist! Written in an easy-to-read, straightforward style, Biomedical Signal Processing presents techniques to eliminate background noise, enhance signal detection, and analyze computer data, making results easy to comprehend and apply. In addition to examining techniques for electrical signal analysis, filtering, and transforms, the author supplies an extensive appendix with several computer programs that demonstrate techniques presented in the text.

  20. Privatisation Process in Kosovo

    Directory of Open Access Journals (Sweden)

    Dr.Sc. Hysni Terziu


    Full Text Available This paper aims at analysing activities of the privatisation process in Kosovo, seeing that privatisation is treated as a fundamental factor of overall transformation of the whole society. It may be established that the primary aim of privatisation process is increasing economic efficiency, reflection of the current state and directions of development in general. Privatisation as a process has as primary aim of opening new areas of freedom, economic efficiency and individualism. Key aim of privatisation process in Kosovo must be increase of economic efficiency, preservation of the healthy economic potential created up to date, and ensuring of the long term concept, which enables growth and macroeconomic stability. The policy of privatisation should give a response related to strategic aspects of privatisation of these sectors: of models, procedures, potential investors, technological modernisation and overtaking of social barriers. Process of privatisation and transition which has now covered countries of the Eastern and Central Europe, aims at profound economic and political transformation of these countries. To achieve this, it is necessarily required to have some basic preconditions, which are related to incitement of general efficiency of the enterprises, expansion of the capital market, introduction of competition, development of business culture in private property and freedom of entrepreneurship. Impacts of privatisation in economic development of Kosovo take a considerable place compared to other countries, therefore our aim is that through this paper we analyse factors and methods of implementation in this process.

  1. Helium process cycle (United States)

    Ganni, Venkatarao


    A unique process cycle and apparatus design separates the consumer (cryogenic) load return flow from most of the recycle return flow of a refrigerator and/or liquefier process cycle. The refrigerator and/or liquefier process recycle return flow is recompressed by a multi-stage compressor set and the consumer load return flow is recompressed by an independent consumer load compressor set that maintains a desirable constant suction pressure using a consumer load bypass control valve and the consumer load return pressure control valve that controls the consumer load compressor's suction pressure. The discharge pressure of this consumer load compressor is thereby allowed to float at the intermediate pressure in between the first and second stage recycle compressor sets. Utilizing the unique gas management valve regulation, the unique process cycle and apparatus design in which the consumer load return flow is separate from the recycle return flow, the pressure ratios of each recycle compressor stage and all main pressures associated with the recycle return flow are allowed to vary naturally, thus providing a naturally regulated and balanced floating pressure process cycle that maintains optimal efficiency at design and off-design process cycle capacity and conditions automatically.

  2. FY 1999 report on the results of the technology development for abatement of pollutants related to oil refining; 1999 nendo sekiyu seisei osen busshitsu teigen nado gijutsu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)



    The technologies are developed for efficiently, economically improving quality of automobile fuels by, e.g., abatement of environmental pollutants present in the oil products. For improvement of hydrodesulfurization rate of gas oil deep hydrodesulfurization process, the catalyst components high in isomerization ability of the hard-to-desulfurize compounds are investigated, and effectiveness of zeolite is confirmed. For production of low-sulfur gas oil by hydrodesulfurization and hydrocracking of heavy oil, the catalyst with small pores is preferable for desulfurization of gas oil as the co-product of the treatment of heavy oil in the presence of catalyst for heavy oil desulfurization. For hydrocracking, the catalysts are prepared, on a trial basis, for achieving the target gas oil sulfur content of 10ppm or less by optimizing the zeolite and matrix properties. For suitability of gas oil qualities, it is found that the hydrogenation step is the rate-determining step among the reaction routes involved in the hydrogenation of difficult-to-desulfurize compounds. The data of low-sulfur gas oil qualities in Europe are collected. (NEDO)

  3. Continuous Correctness of Business Processes Against Process Interference

    NARCIS (Netherlands)

    van Beest, Nick; Bucur, Doina


    In distributed business process support environments, process interference from multiple stakeholders may cause erroneous process outcomes. Existing solutions to detect and correct interference at runtime employ formal verification and the automatic generation of intervention processes at runtime.

  4. Novel food processing techniques

    Directory of Open Access Journals (Sweden)

    Vesna Lelas


    Full Text Available Recently, a lot of investigations have been focused on development of the novel mild food processing techniques with the aim to obtain the high quality food products. It is presumed also that they could substitute some of the traditional processes in the food industry. The investigations are primarily directed to usage of high hydrostatic pressure, ultrasound, tribomechanical micronization, microwaves, pulsed electrical fields. The results of the scientific researches refer to the fact that application of some of these processes in particular food industry can result in lots of benefits. A significant energy savings, shortening of process duration, mild thermal conditions, food products with better sensory characteristics and with higher nutritional values can be achieved. As some of these techniques act also on the molecular level changing the conformation, structure and electrical potential of organic as well as inorganic materials, the improvement of some functional properties of these components may occur. Common characteristics of all of these techniques are treatment at ambient or insignificant higher temperatures and short time of processing (1 to 10 minutes. High hydrostatic pressure applied to various foodstuffs can destroy some microorganisms, successfully modify molecule conformation and consequently improve functional properties of foods. At the same time it acts positively on the food products intend for freezing. Tribomechanical treatment causes micronization of various solid materials that results in nanoparticles and changes in structure and electrical potential of molecules. Therefore, the significant improvement of some rheological and functional properties of materials occurred. Ultrasound treatment proved to be potentially very successful technique of food processing. It can be used as a pretreatment to drying (decreases drying time and improves functional properties of food, as extraction process of various components

  5. Carbon dioxide reducing processes; Koldioxidreducerande processer

    Energy Technology Data Exchange (ETDEWEB)

    Svensson, Fredrik


    This thesis discusses different technologies to reduce or eliminate the carbon dioxide emissions, when a fossil fuel is used for energy production. Emission reduction can be accomplished by separating the carbon dioxide for storage or reuse. There are three different ways of doing the separation. The carbon dioxide can be separated before the combustion, the process can be designed so that the carbon dioxide can be separated without any energy consumption and costly systems or the carbon dioxide can be separated from the flue gas stream. Two different concepts of separating the carbon dioxide from a combined cycle are compared, from the performance and the economical point of view, with a standard natural gas fired combined cycle where no attempts are made to reduce the carbon dioxide emissions. One concept is to use absorption technologies to separate the carbon dioxide from the flue gas stream. The other concept is based on a semi-closed gas turbine cycle using carbon dioxide as working fluid and combustion with pure oxygen, generated in an air-separating unit. The calculations show that the efficiency (power) drop is smaller for the first concept than for the second, 8.7 % points compared to 13.7 % points, when power is produced. When both heat and power are produced, the relation concerning the efficiency (power) remains. Regarding the overall efficiency (heat and power) the opposite relation is present. A possible carbon dioxide tax must exceed 0.21 SEK/kg CO{sub 2} for it to be profitable to separate carbon dioxide with any of these technologies.

  6. 21 CFR 1271.220 - Processing and process controls. (United States)


    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Processing and process controls. 1271.220 Section... process controls. (a) General. If you are an establishment that processes HCT/Ps, you must process each... mixed in a single receptacle) during manufacturing. (c) In-process control and testing. You must ensure...

  7. Nonconscious processes and health. (United States)

    Sheeran, Paschal; Gollwitzer, Peter M; Bargh, John A


    Health behavior theories focus on the role of conscious, reflective factors (e.g., behavioral intentions, risk perceptions) in predicting and changing behavior. Dual-process models, on the other hand, propose that health actions are guided not only by a conscious, reflective, rule-based system but also by a nonconscious, impulsive, associative system. This article argues that research on health decisions, actions, and outcomes will be enriched by greater consideration of nonconscious processes. A narrative review is presented that delineates research on implicit cognition, implicit affect, and implicit motivation. In each case, we describe the key ideas, how they have been taken up in health psychology, and the possibilities for behavior change interventions, before outlining directions that might profitably be taken in future research. Correlational research on implicit cognitive and affective processes (attentional bias and implicit attitudes) has recently been supplemented by intervention studies using implementation intentions and practice-based training that show promising effects. Studies of implicit motivation (health goal priming) have also observed encouraging findings. There is considerable scope for further investigations of implicit affect control, unconscious thought, and the automatization of striving for health goals. Research on nonconscious processes holds significant potential that can and should be developed by health psychologists. Consideration of impulsive as well as reflective processes will engender new targets for intervention and should ultimately enhance the effectiveness of behavior change efforts. PsycINFO Database Record (c) 2013 APA, all rights reserved.

  8. VLSI signal processing technology

    CERN Document Server

    Swartzlander, Earl


    This book is the first in a set of forthcoming books focussed on state-of-the-art development in the VLSI Signal Processing area. It is a response to the tremendous research activities taking place in that field. These activities have been driven by two factors: the dramatic increase in demand for high speed signal processing, especially in consumer elec­ tronics, and the evolving microelectronic technologies. The available technology has always been one of the main factors in determining al­ gorithms, architectures, and design strategies to be followed. With every new technology, signal processing systems go through many changes in concepts, design methods, and implementation. The goal of this book is to introduce the reader to the main features of VLSI Signal Processing and the ongoing developments in this area. The focus of this book is on: • Current developments in Digital Signal Processing (DSP) pro­ cessors and architectures - several examples and case studies of existing DSP chips are discussed in...

  9. Anaerobic thermophilic biogas process

    Energy Technology Data Exchange (ETDEWEB)

    Angelidaki, I.


    Investigations into several important aspects concerning thermophilic, anaerobic treatment of livestock wastes and other types of wastes in Denmark was carried out. Lipids, typically found in industrial organic waste, could be effectively degraded during anaerobic treatment with a high biogas yield. Long-chain fatty acids (LCFA) could also inhibit the biogas process at relatively low concentrations. Lipid-containing waste should be introduced gradually and fed continuously to the biogas process in order to permit adaptation. Fed-bacth cultivation was shown to be a successful method for enriching bacteria which are exposed to substrate inhibition. The end product of the degradation were methane and carbon dioxide. Ammonia concentrations at or above 4 g-N/l were shown to inhibit thermophilic digestion of cattle manure, but if the ammonia concentration was gradually increased, adaptation of the process occurred. It was found that addition of bentonite or the waste product bentonite-bound oil counteracted to some extent the inhibitory effect of ammonia. The effect was observed only when the ammonia concentration was increased gradually. When the ammonia load was high, reduction of the temperature below 55 Deg. C was shown to have a positive effect on process performance, while at ammonia non-inhibitory concentrations a temperature of 55 deg. C was found to be the optimal temperature. A mathematical model of the biogas process was formulated with main emphasis on free ammonia inhibition, pH simulation and temperature effects. (au) (140 refs.).

  10. Radiation processes in astrophysics

    CERN Document Server

    Tucker, Wallace H


    The purpose of this book is twofold: to provide a brief, simple introduction to the theory of radiation and its application in astrophysics and to serve as a reference manual for researchers. The first part of the book consists of a discussion of the basic formulas and concepts that underlie the classical and quantum descriptions of radiation processes. The rest of the book is concerned with applications. The spirit of the discussion is to present simple derivations that will provide some insight into the basic physics involved and then to state the exact results in a form useful for applications. The reader is referred to the original literature and to reviews for rigorous derivations.The wide range of topics covered is illustrated by the following table of contents: Basic Formulas for Classical Radiation Processes; Basic Formulas for Quantum Radiation Processes; Cyclotron and Synchrotron Radiation; Electron Scattering; Bremsstrahlung and Collision Losses; Radiative Recombination; The Photoelectric Effect; a...

  11. Stochastic processes inference theory

    CERN Document Server

    Rao, Malempati M


    This is the revised and enlarged 2nd edition of the authors’ original text, which was intended to be a modest complement to Grenander's fundamental memoir on stochastic processes and related inference theory. The present volume gives a substantial account of regression analysis, both for stochastic processes and measures, and includes recent material on Ridge regression with some unexpected applications, for example in econometrics. The first three chapters can be used for a quarter or semester graduate course on inference on stochastic processes. The remaining chapters provide more advanced material on stochastic analysis suitable for graduate seminars and discussions, leading to dissertation or research work. In general, the book will be of interest to researchers in probability theory, mathematical statistics and electrical and information theory.

  12. Topological signal processing

    CERN Document Server

    Robinson, Michael


    Signal processing is the discipline of extracting information from collections of measurements. To be effective, the measurements must be organized and then filtered, detected, or transformed to expose the desired information.  Distortions caused by uncertainty, noise, and clutter degrade the performance of practical signal processing systems. In aggressively uncertain situations, the full truth about an underlying signal cannot be known.  This book develops the theory and practice of signal processing systems for these situations that extract useful, qualitative information using the mathematics of topology -- the study of spaces under continuous transformations.  Since the collection of continuous transformations is large and varied, tools which are topologically-motivated are automatically insensitive to substantial distortion. The target audience comprises practitioners as well as researchers, but the book may also be beneficial for graduate students.

  13. WWTP Process Tank Modelling

    DEFF Research Database (Denmark)

    Laursen, Jesper

    hydrofoil shaped propellers. These two sub-processes deliver the main part of the supplied energy to the activated sludge tank, and for this reason they are important for the mixing conditions in the tank. For other important processes occurring in the activated sludge tank, existing models and measurements...... zones in mind, its special construction poses strict demands to the hydrodynamic model. In case study three the model is extended to a three-phase model where also the injection of air bubbles during the aeration process is modeled. The aeration of sludge is controlled through a simple expression...... for the reoxygenation of the wastewater phase as a function of the local volume fraction of air and the concentration of soluble oxygen. A simple model for the bulk consumption of oxygen is linked to the reoxygenation expression in order to model measured oxygen concentrations in the suspension. In the final case study...

  14. Robots and image processing (United States)

    Peterson, C. E.


    Developments in integrated circuit manufacture are discussed, with attention given to the current expectations of industrial automation. It is shown that the growing emphasis on image processing is a natural consequence of production requirements which have generated a small but significant range of vision applications. The state of the art in image processing is discussed, with the main research areas delineated. The main areas of application will be less in welding and diecasting than in assembly and machine tool loading, with vision becoming an ever more important facet of the installation. The two main approaches to processing images in a computer (depending on the aims of the project) are discussed. The first involves producing a system that does a specific task, the second is to achieve an understanding of some basic issues in object recognition.

  15. Foundations of signal processing

    CERN Document Server

    Vetterli, Martin; Goyal, Vivek K


    This comprehensive and engaging textbook introduces the basic principles and techniques of signal processing, from the fundamental ideas of signals and systems theory to real-world applications. Students are introduced to the powerful foundations of modern signal processing, including the basic geometry of Hilbert space, the mathematics of Fourier transforms, and essentials of sampling, interpolation, approximation and compression. The authors discuss real-world issues and hurdles to using these tools, and ways of adapting them to overcome problems of finiteness and localisation, the limitations of uncertainty and computational costs. Standard engineering notation is used throughout, making mathematical examples easy for students to follow, understand and apply. It includes over 150 homework problems and over 180 worked examples, specifically designed to test and expand students' understanding of the fundamentals of signal processing, and is accompanied by extensive online materials designed to aid learning, ...

  16. The Nursing Process

    Directory of Open Access Journals (Sweden)

    M. Hammond


    Full Text Available The essence of the nursing process can be summed up in this quotation by Sir Francis Bacon: “Human knowledge and human powers meet in one; for where the cause is not known the effect cannot be produced.” Arriving at a concise, accurate definition of the nursing process was, for me, an impossible task. It is altogether too vast and too personal a topic to contract down into a niftylooking, we-pay-lip-service-to-it cliché. So what I propose to do is to present my understanding of the nursing process throughout this essay, and then to leave the reader with some overall, general impression of what it all entails.

  17. Quantum independent increment processes

    CERN Document Server

    Franz, Uwe


    This volume is the first of two volumes containing the revised and completed notes lectures given at the school "Quantum Independent Increment Processes: Structure and Applications to Physics". This school was held at the Alfried-Krupp-Wissenschaftskolleg in Greifswald during the period March 9 – 22, 2003, and supported by the Volkswagen Foundation. The school gave an introduction to current research on quantum independent increment processes aimed at graduate students and non-specialists working in classical and quantum probability, operator algebras, and mathematical physics. The present first volume contains the following lectures: "Lévy Processes in Euclidean Spaces and Groups" by David Applebaum, "Locally Compact Quantum Groups" by Johan Kustermans, "Quantum Stochastic Analysis" by J. Martin Lindsay, and "Dilations, Cocycles and Product Systems" by B.V. Rajarama Bhat.

  18. Laser Processing and Chemistry

    CERN Document Server

    Bäuerle, Dieter


    This book gives an overview of the fundamentals and applications of laser-matter interactions, in particular with regard to laser material processing. Special attention is given to laser-induced physical and chemical processes at gas-solid, liquid-solid, and solid-solid interfaces. Starting with the background physics, the book proceeds to examine applications of lasers in “standard” laser machining and laser chemical processing (LCP), including the patterning, coating, and modification of material surfaces. This fourth edition has been enlarged to cover the rapid advances in the understanding of the dynamics of materials under the action of ultrashort laser pulses, and to include a number of new topics, in particular the increasing importance of lasers in various different fields of surface functionalizations and nanotechnology. In two additional chapters, recent developments in biotechnology, medicine, art conservation and restoration are summarized. Graduate students, physicists, chemists, engineers, a...

  19. Plasma processing of nanomaterials

    CERN Document Server

    Sankaran, R Mohan


    CRC Press author R. Mohan Sankaran is the winner of the 2011 Peter Mark Memorial Award "… for the development of a tandem plasma synthesis method to grow carbon nanotubes with unprecedented control over the nanotube properties and chirality." -2011 AVS Awards Committee"Readers who want to learn about how nanomaterials are processed, using the most recent methods, will benefit greatly from this book. It contains very recent technical details on plasma processing and synthesis methods used by current researchers developing new nano-based materials, with all the major plasma-based processing techniques used today being thoroughly discussed."-John J. Shea, IEEE Electrical Insulation Magazine, May/June 2013, Vol. 29, No. 3.

  20. Quartz resonator processing system (United States)

    Peters, Roswell D. M.


    Disclosed is a single chamber ultra-high vacuum processing system for the oduction of hermetically sealed quartz resonators wherein electrode metallization and sealing are carried out along with cleaning and bake-out without any air exposure between the processing steps. The system includes a common vacuum chamber in which is located a rotatable wheel-like member which is adapted to move a plurality of individual component sets of a flat pack resonator unit past discretely located processing stations in said chamber whereupon electrode deposition takes place followed by the placement of ceramic covers over a frame containing a resonator element and then to a sealing stage where a pair of hydraulic rams including heating elements effect a metallized bonding of the covers to the frame.

  1. Silicon production process evaluations (United States)


    Engineering design of the third distillation column in the process was accomplished. The initial design is based on a 94.35% recovery of dichlorosilane in the distillate and a 99.9% recovery of trichlorosilane in the bottoms. The specified separation is achieved at a reflux ratio of 15 with 20 trays (equilibrium stages). Additional specifications and results are reported including equipment size, temperatures and pressure. Specific raw material requirements necessary to produce the silicon in the process are presented. The primary raw materials include metallurgical grade silicon, silicon tetrachloride, hydrogen, copper (catalyst) and lime (waste treatment). Hydrogen chloride is produced as by product in the silicon deposition. Cost analysis of the process was initiated during this reporting period.

  2. Product and Process Modelling

    DEFF Research Database (Denmark)

    Cameron, Ian T.; Gani, Rafiqul

    This book covers the area of product and process modelling via a case study approach. It addresses a wide range of modelling applications with emphasis on modelling methodology and the subsequent in-depth analysis of mathematical models to gain insight via structural aspects of the models....... These approaches are put into the context of life cycle modelling, where multiscale and multiform modelling is increasingly prevalent in the 21st century. The book commences with a discussion of modern product and process modelling theory and practice followed by a series of case studies drawn from a variety...... of process industries. The book builds on the extensive modelling experience of the authors, who have developed models for both research and industrial purposes. It complements existing books by the authors in the modelling area. Those areas include the traditional petroleum and petrochemical industries...

  3. Thermal stir welding process (United States)

    Ding, R. Jeffrey (Inventor)


    A welding method is provided for forming a weld joint between first and second elements of a workpiece. The method includes heating the first and second elements to form an interface of material in a plasticized or melted state interface between the elements. The interface material is then allowed to cool to a plasticized state if previously in a melted state. The interface material, while in the plasticized state, is then mixed, for example, using a grinding/extruding process, to remove any dendritic-type weld microstructures introduced into the interface material during the heating process.

  4. Advanced Polymer Processing Facility

    Energy Technology Data Exchange (ETDEWEB)

    Muenchausen, Ross E. [Los Alamos National Laboratory


    Some conclusions of this presentation are: (1) Radiation-assisted nanotechnology applications will continue to grow; (2) The APPF will provide a unique focus for radiolytic processing of nanomaterials in support of DOE-DP, other DOE and advanced manufacturing initiatives; (3) {gamma}, X-ray, e-beam and ion beam processing will increasingly be applied for 'green' manufacturing of nanomaterials and nanocomposites; and (4) Biomedical science and engineering may ultimately be the biggest application area for radiation-assisted nanotechnology development.

  5. Integrated Renovation Process

    DEFF Research Database (Denmark)

    Galiotto, Nicolas; Heiselberg, Per; Knudstrup, Mary-Ann


    structured and holistic method of decision making toward nearly zero-energy building renovation. The methodology is evolutive, implementable on a large scale, and allows an optimal integration of nonexpert decision makers. In practice, such a scheme allowed most behavioral barriers to sustainable home...... renovation to be overcome. The homeowners were better integrated and their preferences and immaterial values were better taken into account. To keep the decision-making process economically viable and timely, the process as known today still needs to be improved, and new tools need to be developed...

  6. The Integrated Renovation Process

    DEFF Research Database (Denmark)

    Galiotto, Nicolas; Heiselberg, Per; Knudstrup, Mary-Ann

    The Integrated Renovation Process (IRP) is a user customized methodology based on judiciously selected constructivist and interactive multi-criteria decision making methods (Galiotto, Heiselberg, & Knudstrup, 2014 (expected)). When applied for home renovation, the Integrated Renovation Process...... for Homes (IRP4homes) supports, informs and reassures homeowners to decide on a sustainable renovation of their home while getting the corresponding associated benefits and therefore a home more adapted to their lifestyles. The IRP4homes also helps the building experts to be more effective...

  7. Fault Tolerant Distributive Processing (United States)

    Quesnell, Harris


    A fault tolerant design used to enhanced the survivability of a distributive processing system is described. Based on physical limitations, mission duration and maintenance support, the approach has emphasized functional redundancy in place of the traditional hardware or software level redundancy. A top down architecture within the system's hierarchy allows sharing of common resources. Various techniques used to enhance the survivability of the hardware at the equipment, module and component level were analyzed. The intent of the on going work is to demonstrate the ability of a distributive processing system to maintain itself for a long period of time.

  8. Normal modified stable processes

    DEFF Research Database (Denmark)

    Barndorff-Nielsen, Ole Eiler; Shephard, N.


    This paper discusses two classes of distributions, and stochastic processes derived from them: modified stable (MS) laws and normal modified stable (NMS) laws. This extends corresponding results for the generalised inverse Gaussian (GIG) and generalised hyperbolic (GH) or normal generalised inverse...... Gaussian (NGIG) laws. The wider framework thus established provides, in particular, for added flexibility in the modelling of the dynamics of financial time series, of importance especially as regards OU based stochastic volatility models for equities. In the special case of the tempered stable OU process...

  9. Nucleic acid isolation process

    Energy Technology Data Exchange (ETDEWEB)

    Longmire, J.L.; Lewis, A.K.; Hildebrand, C.E.


    This patent describes a process for preparing DNA from cellular materials for use in genetic studies of eukaryotic systems, a process for isolating DNA fragments from proteolytic digestion products and detergent products in a solution with the DNA fragments produced in stripping undesired cellular constituents from the DNA. It comprises the step of dialyzing a solution containing the DNA fragments, detergent products, and proteolytic digestion products against a solution containing PEG for a time effective to yield DNA sufficiently pure of the genetic studies.

  10. Silicon web process development (United States)

    Duncan, C. S.; Seidensticker, R. G.; Mchugh, J. P.; Skutch, M. E.; Driggers, J. M.; Hopkins, R. H.


    The silicon web process takes advantage of natural crystallographic stabilizing forces to grow long, thin single crystal ribbons directly from liquid silicon. The ribbon, or web, is formed by the solidification of a liquid film supported by surface tension between two silicon filaments, called dendrites, which border the edges of the growing strip. The ribbon can be propagated indefinitely by replenishing the liquid silicon as it is transformed to crystal. The dendritic web process has several advantages for achieving low cost, high efficiency solar cells. These advantages are discussed.

  11. Data processing on FPGAs

    CERN Document Server

    Teubner, Jens


    Roughly a decade ago, power consumption and heat dissipation concerns forced the semiconductor industry to radically change its course, shifting from sequential to parallel computing. Unfortunately, improving performance of applications has now become much more difficult than in the good old days of frequency scaling. This is also affecting databases and data processing applications in general, and has led to the popularity of so-called data appliances-specialized data processing engines, where software and hardware are sold together in a closed box. Field-programmable gate arrays (FPGAs) incr

  12. Genomic signal processing

    CERN Document Server

    Shmulevich, Ilya


    Genomic signal processing (GSP) can be defined as the analysis, processing, and use of genomic signals to gain biological knowledge, and the translation of that knowledge into systems-based applications that can be used to diagnose and treat genetic diseases. Situated at the crossroads of engineering, biology, mathematics, statistics, and computer science, GSP requires the development of both nonlinear dynamical models that adequately represent genomic regulation, and diagnostic and therapeutic tools based on these models. This book facilitates these developments by providing rigorous mathema

  13. A grieving process illustrated? (United States)

    Hutchinson, Rory


    The sudden death of Pablo Picasso's closest friend Carlos Casagemas in 1901 came as a great shock to the young Picasso. From a young age, Picasso had ruminated on life and death; however, this was his first experience of bereavement. Following the death of Casagemas, Picasso's paintings can be seen as a diary of his grieving process and clearly illustrate the five stages of the grieving process as outlined by Kubler-Ross in 'On Death and Dying' (1969). Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to

  14. Biomedical Image Processing

    CERN Document Server

    Deserno, Thomas Martin


    In modern medicine, imaging is the most effective tool for diagnostics, treatment planning and therapy. Almost all modalities have went to directly digital acquisition techniques and processing of this image data have become an important option for health care in future. This book is written by a team of internationally recognized experts from all over the world. It provides a brief but complete overview on medical image processing and analysis highlighting recent advances that have been made in academics. Color figures are used extensively to illustrate the methods and help the reader to understand the complex topics.

  15. Identification of wastewater processes

    DEFF Research Database (Denmark)

    Carstensen, Niels Jacob

    of ammonia, nitrate, and phosphate concentrations, which are measured in the aeration tanks of the biological nutrient removal system. The alternatign operation modes of the BIO-DENITRO and BIO-DENIPHO processes are of particular interest. Time series models of the hydraulic and biological processes are very...... useful for gaining insight in real time operation of wastewater treatment systems with variable influent flows and pollution loads, and for the design of plant operation control. In the present context non-linear structural time series models are proposed, which are identified by combining the well...

  16. Reversible brazing process (United States)

    Pierce, Jim D.; Stephens, John J.; Walker, Charles A.


    A method of reversibly brazing surfaces together. An interface is affixed to each surface. The interfaces can be affixed by processes such as mechanical joining, welding, or brazing. The two interfaces are then brazed together using a brazing process that does not defeat the surface to interface joint. Interfaces of materials such as Ni-200 can be affixed to metallic surfaces by welding or by brazing with a first braze alloy. The Ni-200 interfaces can then be brazed together using a second braze alloy. The second braze alloy can be chosen so that it minimally alters the properties of the interfaces to allow multiple braze, heat and disassemble, rebraze cycles.

  17. Solar industrial process heat

    Energy Technology Data Exchange (ETDEWEB)

    Lumsdaine, E.


    The aim of the assessment reported is to candidly examine the contribution that solar industrial process heat (SIPH) is realistically able to make in the near and long-term energy futures of the United States. The performance history of government and privately funded SIPH demonstration programs, 15 of which are briefly summarized, and the present status of SIPH technology are discussed. The technical and performance characteristics of solar industrial process heat plants and equipment are reviewed, as well as evaluating how the operating experience of over a dozen SIPH demonstration projects is influencing institutional acceptance and economoc projections. Implications for domestic energy policy and international implications are briefly discussed. (LEW)

  18. The Recruitment Process:

    DEFF Research Database (Denmark)

    Holm, Anna

    The aim of this research was to determine whether the introduction of e-recruitment has an impact on the process and underlying tasks, subtasks and activities of recruitment. Three large organizations with well-established e-recruitment practices were included in the study. The three case studies......, which were carried out in Denmark in 2008-2009 using qualitative research methods, revealed changes in the sequence, divisibility and repetitiveness of a number of recruitment tasks and subtasks. The new recruitment process design was identified and presented in the paper. The study concluded...

  19. Lasers in materials processing

    Energy Technology Data Exchange (ETDEWEB)

    Davis, J.I.; Rockower, E.B.


    A status report on the uranium Laser Isotope Separation (LIS) Program at the Lawrence Livermore National Laboratory is presented. Prior to this status report, process economic analysis is presented so as to understand how the unique properties of laser photons can be best utilized in the production of materials and components despite the high cost of laser energy. The characteristics of potential applications that are necessary for success are identified, and those factors that have up to now frustrated attempts to find commercially viable laser induced chemical and physical process for the production of new or existing materials are pointed out.

  20. Statecharts Via Process Algebra (United States)

    Luttgen, Gerald; vonderBeeck, Michael; Cleaveland, Rance


    Statecharts is a visual language for specifying the behavior of reactive systems. The Language extends finite-state machines with concepts of hierarchy, concurrency, and priority. Despite its popularity as a design notation for embedded system, precisely defining its semantics has proved extremely challenging. In this paper, a simple process algebra, called Statecharts Process Language (SPL), is presented, which is expressive enough for encoding Statecharts in a structure-preserving and semantic preserving manner. It is establish that the behavioral relation bisimulation, when applied to SPL, preserves Statecharts semantics

  1. An Integrated Design Process

    DEFF Research Database (Denmark)

    Petersen, Mads Dines; Knudstrup, Mary-Ann


    Present paper is placed in the discussion about how sustainable measures are integrated in the design process by architectural offices. It presents results from interviews with four leading Danish architectural offices working with sustainable architecture and their experiences with it, as well...... as the requirements they meet in terms of how to approach the design process – especially focused on the early stages like a competition. The interviews focus on their experiences with working in multidisciplinary teams and using digital tools to support their work with sustainable issues. The interviews show...

  2. An Integrated Desgin Process

    DEFF Research Database (Denmark)

    Petersen, Mads Dines; Knudstrup, Mary-Ann


    Present paper is placed in the discussion about how sustainable measures are integrated in the design process by architectural offices. It presents results from interviews with four leading Danish architectural offices working with sustainable architecture and their experiences with it, as well...... as the requirements they meet in terms of how to approach the design process – especially focused on the early stages like a competition. The interviews focus on their experiences with working in multidisciplinary teams and using digital tools to support their work with sustainable issues. The interviews show...

  3. Validation Process Methods

    Energy Technology Data Exchange (ETDEWEB)

    Lewis, John E. [National Renewable Energy Lab. (NREL), Golden, CO (United States); English, Christine M. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Gesick, Joshua C. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Mukkamala, Saikrishna [National Renewable Energy Lab. (NREL), Golden, CO (United States)


    This report documents the validation process as applied to projects awarded through Funding Opportunity Announcements (FOAs) within the U.S. Department of Energy Bioenergy Technologies Office (DOE-BETO). It describes the procedures used to protect and verify project data, as well as the systematic framework used to evaluate and track performance metrics throughout the life of the project. This report also describes the procedures used to validate the proposed process design, cost data, analysis methodologies, and supporting documentation provided by the recipients.

  4. The Player Engagement Process

    DEFF Research Database (Denmark)

    Schoenau-Fog, Henrik


    Engagement is an essential element of the player experience, and the concept is described in various ways in the literature. To gain a more detailed comprehension of this multifaceted concept, and in order to better understand what aspects can be used to evaluate engaging game play and to design......, categories and triggers involved in this process. By applying grounded theory to the analysis of the responses, a process-oriented player engagement framework was developed and four main components consisting of objectives, activities, accomplishments and affects as well as the corresponding categories...

  5. Geology And Image Processing (United States)

    Daily, Mike


    The design of digital image processing systems for geological applications will be driven by the nature and complexity of the intended use, by the types and quantities of data, and by systems considerations. Image processing will be integrated with geographic information systems (GIS) and data base management systems (DBMS). Dense multiband data sets from radar and multispectral scanners (MSS) will tax memory, bus, and processor architectures. Array processors and dedicated-function chips (VLSI/VHSIC) will allow the routine use of FFT and classification algorithms. As this geoprocessing capability becomes available to a larger segment of the geological community, user friendliness and smooth interaction will become a major concern.

  6. Process Change Patterns (Aktuelles Schlagwort)

    NARCIS (Netherlands)

    Weber, Barbara; Rinderle, S.B.; Reichert, M.U.

    This paper presents a set of process changes patterns to foster the comparison of existing process-aware information systems with respect to process change definition. More precisely, change patterns allow for high-level process adaptations at both the process type and the process instance level. We


    Directory of Open Access Journals (Sweden)

    Magdalena LUCA (DEDIU


    Full Text Available Business process reengineering determines the change of organizational functions from an orientation focused on operations through a multidimensional approach. Former employees who were mere executors are now determined to take their own decisions and as a result the functional departments lose their reason to exist. Managers do not act anymore as supervisors, but mainly as mentors, while the employees focus more attention on customer needs and less than the head’s. Under these conditions, new organizational paradigms are required, the most important being that of learning organizations. In order to implement a reengineering of the economic processes and promoting a new organizational paradigm the information technology plays a decisive role. The article presents some results obtained in a research theme ANSTI funded by contract no. 501/2000. Economic and financial analysis is performed in order to know the current situation to achieve better results in the future. One of its objectives is the production analyzed as a labour process and the interaction elements of this process. The indicators investigated in the analysis of financial and economic activity of production reflect the development directions, the means and resources to accomplish predetermined objectives and express the results and effectiveness of what is expected.

  8. Rethinking lessons learned processes

    NARCIS (Netherlands)

    Buttler, T.; Lukosch, S.G.; Kolfschoten, G.L.; Verbraeck, A.


    Lessons learned are one way to retain experience and knowledge in project-based organizations, helping them to prevent reinventin,g the wheel or to repeat past mistakes. However, there are several challenges that make these lessonts learned processes a challenging endeavor. These include capturing

  9. Qualitative Process Theory. (United States)


    LIili Analysis ...18 5. Itcrvmu t aland I)ifferen ial Q uallative Analysis ........................................................................... ZO 6. (ausalit and...causing a heat flow). Ill Cualitative Process theory the value of quantities arc represented by a partial ordering of other quantities dztenniiied by the

  10. Change Process in Organizations. (United States)


    This document consists of four papers presented during a symposium on the change process in organizations moderated by John Redding at the 1996 conference of the Academy of Human Resource Development (AHRD). "Corporate Culture: Friend or Foe of Change?" (Joanne Burgess) reports a study of the characteristics of corporate culture that facilitate…

  11. Cauchy cluster process

    DEFF Research Database (Denmark)

    Ghorbani, Mohammad


    In this paper we introduce an instance of the well-know Neyman–Scott cluster process model with clusters having a long tail behaviour. In our model the offspring points are distributed around the parent points according to a circular Cauchy distribution. Using a modified Cramér-von Misses test...


    The report examines process alternatives for the optimal use of natural gas and biomass for production of fuel-cell vehicle fuel, emphasizing maximum displacement of petroleum and maximum reduction of overall fuel-cycle carbon dioxide (CO2) emissions at least cost. Three routes a...

  13. Asymmetric inclusion process. (United States)

    Reuveni, Shlomi; Eliazar, Iddo; Yechiali, Uri


    We introduce and explore the asymmetric inclusion process (ASIP), an exactly solvable bosonic counterpart of the fermionic asymmetric exclusion process (ASEP). In both processes, random events cause particles to propagate unidirectionally along a one-dimensional lattice of n sites. In the ASEP, particles are subject to exclusion interactions, whereas in the ASIP, particles are subject to inclusion interactions that coalesce them into inseparable clusters. We study the dynamics of the ASIP, derive evolution equations for the mean and probability generating function (PGF) of the sites' occupancy vector, obtain explicit results for the above mean at steady state, and describe an iterative scheme for the computation of the PGF at steady state. We further obtain explicit results for the load distribution in steady state, with the load being the total number of particles present in all lattice sites. Finally, we address the problem of load optimization, and solve it under various criteria. The ASIP model establishes bridges between statistical physics and queueing theory as it represents a tandem array of queueing systems with (unlimited) batch service, and a tandem array of growth-collapse processes.

  14. A Process Document

    International Development Research Centre (IDRC) Digital Library (Canada)

    and primary health care–related structures, legis- lation, regulation and policy, and decision-making processes;. 2. Review of peer review and grey literature;. 3. .... Ministry of Health, with representation from state-level government (Health Commissioner and Directors of. Planning and Research) and civil society. For a list of.

  15. Software Process Improvement

    DEFF Research Database (Denmark)

    Kuhrmann, Marco; Diebold, Philipp; Münch, Jürgen


    Software process improvement (SPI) is around for decades: frameworks are proposed, success factors are studied, and experiences have been reported. However, the sheer mass of concepts, approaches, and standards published over the years overwhelms practitioners as well as researchers. What is out...

  16. Real space process algebra

    NARCIS (Netherlands)

    Bergstra, J.A.; Baeten, J.C.M.


    The real time process algebra of Baeten and Bergstra [Formal Aspects of Computing, 3, 142-188 (1991)] is extended to real space by requiring the presence of spatial coordinates for each atomic action, in addition to the required temporal attribute. It is found that asynchronous communication

  17. Accent processing in dementia (United States)

    Hailstone, Julia C.; Ridgway, Gerard R.; Bartlett, Jonathan W.; Goll, Johanna C.; Crutch, Sebastian J.; Warren, Jason D.


    Accented speech conveys important nonverbal information about the speaker as well as presenting the brain with the problem of decoding a non-canonical auditory signal. The processing of non-native accents has seldom been studied in neurodegenerative disease and its brain basis remains poorly understood. Here we investigated the processing of non-native international and regional accents of English in cohorts of patients with Alzheimer's disease (AD; n=20) and progressive nonfluent aphasia (PNFA; n=6) in relation to healthy older control subjects (n=35). A novel battery was designed to assess accent comprehension and recognition and all subjects had a general neuropsychological assessment. Neuroanatomical associations of accent processing performance were assessed using voxel-based morphometry on MR brain images within the larger AD group. Compared with healthy controls, both the AD and PNFA groups showed deficits of non-native accent recognition and the PNFA group showed reduced comprehension of words spoken in international accents compared with a Southern English accent. At individual subject level deficits were observed more consistently in the PNFA group, and the disease groups showed different patterns of accent comprehension impairment (generally more marked for sentences in AD and for single words in PNFA). Within the AD group, grey matter associations of accent comprehension and recognition were identified in the anterior superior temporal lobe. The findings suggest that accent processing deficits may constitute signatures of neurodegenerative disease with potentially broader implications for understanding how these diseases affect vocal communication under challenging listening conditions. PMID:22664324

  18. Bounded Gaussian process regression

    DEFF Research Database (Denmark)

    Jensen, Bjørn Sand; Nielsen, Jens Brehm; Larsen, Jan


    We extend the Gaussian process (GP) framework for bounded regression by introducing two bounded likelihood functions that model the noise on the dependent variable explicitly. This is fundamentally different from the implicit noise assumption in the previously suggested warped GP framework. We...

  19. Assessing Process and Product

    DEFF Research Database (Denmark)

    Bennedsen, Jens; Caspersen, Michael E.


    The final assessment of a course must reflect its goals, and contents. An important goal of our introductory programming course is that the students learn a systematic approach for the development of computer programs. Having the programming process as learning objective naturally raises the ques...

  20. Ideology as Communication Process. (United States)

    Brown, William R.


    Ideologizing is presented as the function of innate intrapersonal and interpersonal categorizing of experience. Ideologies flourish in open systems and decline in closed ones. Classical conceptions of science illustrate the process, to the end that an autonomous scientific ideology for the social sciences, including communication, is suggested.…

  1. Authenticizing the Research Process

    Directory of Open Access Journals (Sweden)

    Nora Elizondo-Schmelkes, MA, Ph.D. Candidate


    Full Text Available This study reflects the main concern of students (national and international who are trying to get a postgraduate degree in a third world (or “in means of development” country. The emergent problem found is that students have to finish their thesis or dissertation but they do not really know how to accomplish this goal. They resolve this problem by authenticizing the process as their own. The theory of authenticizing involves compassing their way to solve the problem of advancing in the research process. Compassing allows the student to authenticize his/her research process, making it a personal and „owned. process. The main categories of compassing are the intellectual, physical and emotional dimension patterns that the student has, learns and follows in order to finish the project and get a degree. Authenticizing implies to author with authenticity their thesis or dissertation. Compassing allows them to do this in their own way, at their own pace or time and with their own internal resources, strengths and weaknesses.

  2. Semiarid hillslope processes

    NARCIS (Netherlands)

    Cammeraat, E.L.H.; Shroder, J.F.


    Semiarid environments show specific hydrological responses and geomorphological processes. Semiarid environments are characterized by dry conditions that do not allow for a full but, instead, only for a partial vegetation cover. The vegetation cover is generally patterned in a heterogeneous mosaic

  3. Identity Management Processes Automation

    Directory of Open Access Journals (Sweden)

    A. Y. Lavrukhin


    Full Text Available Implementation of identity management systems consists of two main parts, consulting and automation. The consulting part includes development of a role model and identity management processes description. The automation part is based on the results of consulting part. This article describes the most important aspects of IdM implementation.

  4. Intelligent OCR Processing. (United States)

    Sun, Wei; And Others


    Identifies types and distributions of errors in text produced by optical character recognition (OCR) and proposes a process using machine learning techniques to recognize and correct errors in OCR texts. Results of experiments indicating that this strategy can reduce human interaction required for error correction are reported. (25 references)…

  5. Performance Evaluation Process. (United States)


    This document contains four papers from a symposium on the performance evaluation process and human resource development (HRD). "Assessing the Effectiveness of OJT (On the Job Training): A Case Study Approach" (Julie Furst-Bowe, Debra Gates) is a case study of the effectiveness of OJT in one of a high-tech manufacturing company's product…

  6. Quantum Markov Processes (United States)

    Kümmerer, Burkhard

    These notes give an introduction to some aspects of quantum Markov processes. Quantum Markov processes come into play whenever a mathematical description of irreversible time behaviour of quantum systems is aimed at. Indeed, there is hardly a book on quantum optics without having at least a chapter on quantum Markov processes. However, it is not always easy to recognize the basic concepts of probability theory in families of creation and annihilation operators on Fock space. Therefore, in these lecture notes much emphasis is put on explaining the intuition behind the mathematical machinery of classical and quantum probability. The lectures start with describing how probabilistic intuition is cast into the mathematical language of classical probability (Sects. 4.1-4.3). Later on, we show how this formulation can be extended such as to incorporate the Hilbert space formulation of quantum mechanics (Sects. 4.4,4.5). Quantum Markov processes are constructed and discussed in Sects. 4.6,4.7, and we add some further discussions and examples in Sects. 4.8-4.11.

  7. Video processing project

    CSIR Research Space (South Africa)

    Globisch, R


    Full Text Available Video processing source code for algorithms and tools used in software media pipelines (e.g. image scalers, colour converters, etc.) The currently available source code is written in C++ with their associated libraries and DirectShow- Filters....

  8. (3) Simple processing method

    African Journals Online (AJOL)

    Adeyinka Odunsi

    Simple Processing Method for Recycling Poultry Waste into. Animal Feed Ingredient. *Komolafe, A. A. and Sonaiya, E. B. ... recycled and become consumables to livestock, thus entering the human food chain. Poultry waste is not ... on the concrete roof (20.5 m high) of the Faculty of Agriculture, Obafemi. Awolowo University ...

  9. School Review Process Guide (United States)

    Center for Comprehensive School Reform and Improvement, 2008


    The use of relevant data is at the core of the school review process approach. Various forms of relevant data are gathered, including demographic data, student achievement data, community perception data, and data on the current program (e.g., curriculum, instructional strategies, school climate factors, etc.). Perception questionnaires are…

  10. Students' Differentiated Translation Processes (United States)

    Bossé, Michael J.; Adu-Gyamfi, Kwaku; Chandler, Kayla


    Understanding how students translate between mathematical representations is of both practical and theoretical importance. This study examined students' processes in their generation of symbolic and graphic representations of given polynomial functions. The purpose was to investigate how students perform these translations. The result of the study…

  11. Evaluation of innovation processes

    Directory of Open Access Journals (Sweden)

    Jakub Tabas


    Full Text Available In present, innovations are spoken as an engine of the world economy because the innovations are transforming not only business entities but the whole industries. The innovations have become a necessity for business entities in order to survive on floating challenging markets. This way, innovations are driving force of companies’ performance. The problem which arises here is a question of measurement innovation’s effect on the financial performance of company or selection between two or more possible variants of innovation’s realization. Various authors which are focused on innovations processes are divided into two groups in their attitudes towards the question of influence of innovations on financial performance of companies. One group of the authors present the idea that any reliable measurement is not possible or efficient. The second group of authors present some methods theoretically applicable on this measurement but they base their approaches mostly on the methods of measurement of investments effectiveness or they suggest employment of indicators or ratios which wouldn’t be clearly connected with the outcome of innovation process. The aim of submitted article is to compare different approaches to evaluation of the innovation processes. The authors compare various approaches here and by use of analysis and synthesis, they determine their own method how to measure outcome of innovation process.

  12. Governing Knowledge Processes

    DEFF Research Database (Denmark)

    Foss, Nicolai Juul; Husted, Kenneth; Michailova, Snejina


    An under-researched issue in work within the `knowledge movement' is therelation between organizational issues and knowledge processes (i.e., sharingand creating knowledge). We argue that managers can shape formalorganization structure and organization forms and can influence the moreinformal org...

  13. Industrial Information Processing

    DEFF Research Database (Denmark)

    Svensson, Carsten


    This paper demonstrates, how cross-functional business processes may be aligned with product specification systems in an intra-organizational environment by integrating planning systems and expert systems, thereby providing an end-to-end integrated and an automated solution to the “build-to-order...

  14. Soil properties and processes

    NARCIS (Netherlands)

    Hartemink, A.E.; McBratney, A.B.; White, R.E.


    This four-volume set, edited by leading experts in soil science, brings together in one collection a series of papers that have been fundamental to the development of soil science as a defined discipline. Tis volume 2 on Soil Properties and Processes covers: - Soil physics - Soil (bio)chemistry -

  15. EERA Bioenergy. Thermochemical Processing

    Energy Technology Data Exchange (ETDEWEB)

    Sipilaa, K.; Wilen, C. [VTT Technical Research Centre of Finland, Laskut (Finland); Kiel, J. [ECN Biomass, Coal and Environmental Research, Petten (Netherlands); Girio, F. [Laboratorio Nacional de Energia e Geologia LNEG, Lisboa (Portugal); Pilegaard, K. [Risoe, Roskilde (Denmark); Gabrielle, B. [Environment and Arable Crops Research Unit, Institut National de la Recherche Agronomique INRA, Thiverval-Grignon (France); Van Bree, B. [ECN Policy Studies, Energy research Centre of the Netherlands ECN, Petten (Netherlands)


    One of the joint programmes within EERA (European Energy Research Alliance) concerns bioenergy. In this presentation background information is given on the EERA, focusing on the bioenergy programme. And more in particular on the bioenergy sub-programme thermochemical processes. The current focus of EERA Bioenergy is on biofuels.

  16. Udfordringer for transkulturelle processer

    DEFF Research Database (Denmark)

    Petersen, Karen Bjerg


    at indskrænke mulighedsrummet for transkulturelle processer og for det at lære fra en terra nullius position. Der er fokus på empiriske undersøgelser af kultursyn i lovgivning om opholdstilladelse fra 2010, lovgivning om statsborgerskab fra 2006 samt kultursyn i den i 2003 indførte obligatoriske...

  17. Microwave processing heats up (United States)

    Microwaves are a common appliance in many households. In the United States microwave heating is the third most popular domestic heating method food foods. Microwave heating is also a commercial food processing technology that has been applied for cooking, drying, and tempering foods. It's use in ...

  18. Communicating Process Achitectures 2005

    NARCIS (Netherlands)

    Groothuis, M.A.; Broenink, Johannes F.; Roebbers, Herman W.; Sunters, Johan P.E.; Welch, Peter H.; Wood, David C.

    The awareness of the ideas characterized by Communicating Processes Architecture and their adoption by industry beyond their traditional base in safety-critical systems and security is growing. The complexity of modern computing systems has become so great that no one person – maybe not even a small

  19. Process control device

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, Toshifumi; Kobayashi, Hiroshi


    A process control device comprises a memory device for memorizing a plant operation target, a plant state or a state of equipments related with each other as control data, a read-only memory device for storing programs, a plant instrumentation control device or other process control devices, an input/output device for performing input/output with an operator, and a processing device which conducts processing in accordance with the program and sends a control demand or a display demand to the input/output device. The program reads out control data relative to a predetermined operation target, compares and verify them with actual values to read out control data to be a practice premise condition which is further to be a practice premise condition if necessary, thereby automatically controlling the plant or requiring or displaying input. Practice presuming conditions for the operation target can be examined succesively in accordance with the program without constituting complicated logical figures and AND/OR graphs. (N.H.).

  20. Research in Stochastic Processes. (United States)


    a finite segment of the past, and of the partial sum of the infintie linear least squares predictor of the process to the Kolmogorov-Wiener predictor...consider two approaches to robust estimation for the Box -Cox power transformation model. One approach maximizes weighted, modified likeli- hoods. A

  1. Oxygen Dependent Biocatalytic Processes

    DEFF Research Database (Denmark)

    Pedersen, Asbjørn Toftgaard

    to aldehydes and ketones, oxyfunctionalization of C-H bonds, and epoxidation of C-C double bonds. Although oxygen dependent biocatalysis offers many possibilities, there are numerous chal-lenges to be overcome before an enzyme can be implemented in an industrial process. These challenges requires the combined...

  2. Modeling hyporheic zone processes (United States)

    Runkel, Robert L.; McKnight, Diane M.; Rajaram, Harihar


    Stream biogeochemistry is influenced by the physical and chemical processes that occur in the surrounding watershed. These processes include the mass loading of solutes from terrestrial and atmospheric sources, the physical transport of solutes within the watershed, and the transformation of solutes due to biogeochemical reactions. Research over the last two decades has identified the hyporheic zone as an important part of the stream system in which these processes occur. The hyporheic zone may be loosely defined as the porous areas of the stream bed and stream bank in which stream water mixes with shallow groundwater. Exchange of water and solutes between the stream proper and the hyporheic zone has many biogeochemical implications, due to differences in the chemical composition of surface and groundwater. For example, surface waters are typically oxidized environments with relatively high dissolved oxygen concentrations. In contrast, reducing conditions are often present in groundwater systems leading to low dissolved oxygen concentrations. Further, microbial oxidation of organic materials in groundwater leads to supersaturated concentrations of dissolved carbon dioxide relative to the atmosphere. Differences in surface and groundwater pH and temperature are also common. The hyporheic zone is therefore a mixing zone in which there are gradients in the concentrations of dissolved gasses, the concentrations of oxidized and reduced species, pH, and temperature. These gradients lead to biogeochemical reactions that ultimately affect stream water quality. Due to the complexity of these natural systems, modeling techniques are frequently employed to quantify process dynamics.

  3. Cognitive Processes in Spelling. (United States)

    Frith, Uta, Ed.

    The purpose of this book is to encourage a more serious study of spelling by discussing it as both a skill and a problem and by highlighting some previously ill-understood processes involved in learning to spell. The 22 chapters are arranged under the following eight categories: spelling instruction and spelling reform, spelling and language,…

  4. Food Process Engineering

    DEFF Research Database (Denmark)

    Friis, Alan; Jensen, Bo Boye Busk; Risum, Jørgen

    to calculate the requirements of heat processing. Our goal is to put food engineering into a production context. Other courses teach food chemistry, food microbiology and food technology. Topics of great importance and all have to be seen in a broader context of producing good and safe food in a large scale...

  5. Process intensification : Industrial applications

    NARCIS (Netherlands)

    Kiss, Anton A.


    The chapter presents process intensification technologies used in industrial applications, for increasing the eco-efficiency of the chemical equipment with the benefit of lower capital costs, substantial energy saving, reduced footprint, and safety by design. The key topics cover compact heat

  6. Conditional Processes Induced by Birth and Death Processes


    Masaru Iizuka; Matsuyo Tomisaki


    For birth and death processes with finite state space, we consider stochastic processes induced by conditioning on hitting the right boundary point before hitting the left boundary point. We call the induced stochastic processes the conditional processes. We show that the conditional processes are again birth and death processes when the right boundary point is absorbing. On the other hand, it is shown that the conditional processes do not have Markov property and they are not birth and death...

  7. PROcess Based Diagnostics PROBE (United States)

    Clune, T.; Schmidt, G.; Kuo, K.; Bauer, M.; Oloso, H.


    Many of the aspects of the climate system that are of the greatest interest (e.g., the sensitivity of the system to external forcings) are emergent properties that arise via the complex interplay between disparate processes. This is also true for climate models most diagnostics are not a function of an isolated portion of source code, but rather are affected by multiple components and procedures. Thus any model-observation mismatch is hard to attribute to any specific piece of code or imperfection in a specific model assumption. An alternative approach is to identify diagnostics that are more closely tied to specific processes -- implying that if a mismatch is found, it should be much easier to identify and address specific algorithmic choices that will improve the simulation. However, this approach requires looking at model output and observational data in a more sophisticated way than the more traditional production of monthly or annual mean quantities. The data must instead be filtered in time and space for examples of the specific process being targeted.We are developing a data analysis environment called PROcess-Based Explorer (PROBE) that seeks to enable efficient and systematic computation of process-based diagnostics on very large sets of data. In this environment, investigators can define arbitrarily complex filters and then seamlessly perform computations in parallel on the filtered output from their model. The same analysis can be performed on additional related data sets (e.g., reanalyses) thereby enabling routine comparisons between model and observational data. PROBE also incorporates workflow technology to automatically update computed diagnostics for subsequent executions of a model. In this presentation, we will discuss the design and current status of PROBE as well as share results from some preliminary use cases.

  8. Privatization Process in Kosovo

    Directory of Open Access Journals (Sweden)

    Ing. Florin Aliu


    Full Text Available Privatization is considered an initial step toward market economy, restructuring financial and economic sector that enables competition in the economy. Privatization is the most painful process in economy where beside legal establishment and political will, it includes also the aspect of fairness and honesty. Analysis of this process is based on the models and comparisons between Kosovo and countries of central and Eastern Europe, in order to give a clearer picture on the overall process of privatization in Kosovo Methodology that is used to analyze this issue is based on empirical results and also qualitative interpretation of the models and also on studying particular asset privatization process. A widely discussed case of privatization in Kosovo is that of Post and Telecom of Kosovo (PTK. Since each company has its own value, I have focused my appraising analysis on the financial statements with a special observation on Cash Flow from Operation, as the most significant indicator on showing how company is using her physical and human recourses to generate money. I have based my research on using methodology of discounted cash flow from operation analysis, even though the company valuation was done using net cash flow from operation analysis. Cash Flow valuation then was discounted by the T-bonds interest rate. This paper tries to bring a conclusion that privatization process in Kosovo have not brought the results excepted, firstly by setting an inappropriate price of assets and lastly by restructuring overall privatization sector and the overall industry. Kosovo, consequently, lost a big opportunity to create a competitive environment of financial industry: starting from the banking industry followed the pension trust which remained at their initial steps of development

  9. Biosphere Process Model Report

    Energy Technology Data Exchange (ETDEWEB)

    J. Schmitt


    To evaluate the postclosure performance of a potential monitored geologic repository at Yucca Mountain, a Total System Performance Assessment (TSPA) will be conducted. Nine Process Model Reports (PMRs), including this document, are being developed to summarize the technical basis for each of the process models supporting the TSPA model. These reports cover the following areas: (1) Integrated Site Model; (2) Unsaturated Zone Flow and Transport; (3) Near Field Environment; (4) Engineered Barrier System Degradation, Flow, and Transport; (5) Waste Package Degradation; (6) Waste Form Degradation; (7) Saturated Zone Flow and Transport; (8) Biosphere; and (9) Disruptive Events. Analysis/Model Reports (AMRs) contain the more detailed technical information used to support TSPA and the PMRs. The AMRs consists of data, analyses, models, software, and supporting documentation that will be used to defend the applicability of each process model for evaluating the postclosure performance of the potential Yucca Mountain repository system. This documentation will ensure the traceability of information from its source through its ultimate use in the TSPA-Site Recommendation (SR) and in the National Environmental Policy Act (NEPA) analysis processes. The objective of the Biosphere PMR is to summarize (1) the development of the biosphere model, and (2) the Biosphere Dose Conversion Factors (BDCFs) developed for use in TSPA. The Biosphere PMR does not present or summarize estimates of potential radiation doses to human receptors. Dose calculations are performed as part of TSPA and will be presented in the TSPA documentation. The biosphere model is a component of the process to evaluate postclosure repository performance and regulatory compliance for a potential monitored geologic repository at Yucca Mountain, Nevada. The biosphere model describes those exposure pathways in the biosphere by which radionuclides released from a potential repository could reach a human receptor

  10. Resurfacing processes on Vesta (United States)

    Krohn, K.; Jaumann, R.; Otto, K.; Elbeshausen, D.; Stephan, K.; Kneissl, T.; Schmedemann, N.; Roatsch, T.; Raymond, C.; Russell, C.


    Planetary surfaces are steadily modified by endogenic processes. The most important resurfacing processes on dry airless bodies are: mass-wasting processes, volcanic activity, and tectonics due to impact cratering. Due to the absence of volcanic activity on Vesta [1], mass wasting and impact cratering are the most likely resurfacing processes on Vesta. The high elevation differences on Vesta [2] and the steady bombardment of Vesta's surface by impacts cause seismic shaking which promote material to move downwards. We analyzed different types of mass-wasting features in the South Polar Region, such as slumping blocks at the steep scarp Matronalia Rupes, spur-and-gully morphologies, and landslides in craters [3]. Collapse processes, instability of slopes, and seismic-triggered events cause the landslides, rotational slumping blocks on scarps, as well as spur-and-gully morphologies on crater walls and scarps. Spur-and-gully morphology is known to form on Mars and the Earth normally supported by liquid flow but, on Vesta, these features formed under dry conditions. At Matronalia Rupes, rotational rock slumping blocks are clearly exposed as material slumped down the scarp wall in a stair-stepped pattern, which is interrupted by minor scarps and covers the underlying terrain. This rotational rock slumping is affected by slope instability and gravitationally triggered events, such as seismic shaking mostly produced by impacts elsewhere on Vesta [3]. The sloping surface of Vesta cause not only the formation of mass wasting features, but also the formation of craters on slopes. These craters are in turn influenced by mass wasting and show an asymmetric crater shape with a sharp uphill rim and a smooth downhill rim. The craters show a sharp crater rim uphill and a smooth one downhill as well as ejecta on the downhill rim and only thin ejecta over the uphill rim. Three-dimensional numerical simulations have been performed to study the formation process of the unusual craters

  11. Managing Process Variants in the Process Life Cycle

    NARCIS (Netherlands)

    Hallerbach, A.; Bauer, Th.; Reichert, M.U.


    When designing process-aware information systems, often variants of the same process have to be specified. Each variant then constitutes an adjustment of a particular process to specific requirements building the process context. Current Business Process Management (BPM) tools do not adequately

  12. Fundamentals of process intensification: A process systems engineering view

    DEFF Research Database (Denmark)

    Babi, Deenesh Kavi; Sales Cruz, Alfonso Mauricio; Gani, Rafiqul


    This chapter gives an overview of the fundamentals of process intensification from a process systems engineering point of view. The concept of process intensification, including process integration, is explained together with the drivers for applying process intensification, which can be achieved...... intensification using a systems approach....

  13. Lump wood combustion process (United States)

    Kubesa, Petr; Horák, Jiří; Branc, Michal; Krpec, Kamil; Hopan, František; Koloničný, Jan; Ochodek, Tadeáš; Drastichová, Vendula; Martiník, Lubomír; Malcho, Milan


    The article deals with the combustion process for lump wood in low-power fireplaces (units to dozens of kW). Such a combustion process is cyclical in its nature, and what combustion facility users are most interested in is the frequency, at which fuel needs to be stoked to the fireplace. The paper defines the basic terms such as burnout curve and burning rate curve, which are closely related to the stocking frequency. The fuel burning rate is directly dependent on the immediate thermal power of the fireplace. This is also related to the temperature achieved in the fireplace, magnitude of flue gas losses and the ability to generate conditions favouring the full burnout of the fuel's combustible component, which, at once ensures the minimum production of combustible pollutants. Another part of the paper describes experiments conducted in traditional fireplaces with a grate, at which well-dried lump wood was combusted.

  14. Integral Politics as Process

    Directory of Open Access Journals (Sweden)

    Tom Atlee


    Full Text Available Using the definition proposed here, integral politics can be a process of integrating diverse perspectives into wholesome guidance for a community or society. Characteristics that follow from this definition have ramifications for understanding what such political processes involve. Politics becomes integral as it transcends partisan battle and nurtures generative conversation toward the common good. Problems, conflicts and crises become opportunities for new (or renewed social coherence. Conversational methodologies abound that can help citizen awareness temporarily expand during policy-making, thus helping raise society’s manifested developmental stage. Convening archetypal stakeholders or randomly selected citizens in conversations designed to engage the broader public enhances democratic legitimacy. With minimal issue- and candidate-advocacy, integral political leaders would develop society’s capacity to use integral conversational tools to improve its health, resilience, and collective intelligence. This both furthers and manifests evolution becoming conscious of itself.

  15. processes in the BLMSSM (United States)

    Dong, Xing-Xing; Zhao, Shu-Min; Zhan, Xi-Jie; Yang, Zhong-Jun; Zhang, Hai-Bin; Feng, Tai-Fu


    In a supersymmetric extension of the Standard Model (SM) where baryon and lepton numbers are local gauge symmetries (BLMSSM), we investigate the charged lepton flavor violating (CLFV) processes after introducing new gauginos and right-handed neutrinos. In this model, the branching ratios of are around (10-8-10-10), which approach the present experimental upper bounds. We hope that the branching ratios for these CLFV processes can be detected in the near future. Supported by Major Project of NNSFC (11535002, 11605037, 11647120, 11275036), Natural Science Foundation of Hebei Province (A2016201010, A2016201069) and Natural Science Fund of Hebei University (2011JQ05, 2012-242), Hebei Key Lab of Optic-Electronic Information and Materials, the Midwest Universities Comprehensive Strength Promotion Project

  16. Soft Pion Processes (United States)

    Nambu, Y.


    My talk is concerned with a review, not necessarily of the latest theoretical developments, but rather of an old idea which has contributed to recent theoretical activities. By soft pion processes I mean processes in which low energy pions are emitted or absorbed or scattered, just as we use the word soft photon in a similar context. Speaking more quantitatively, we may call a pion soft if its energy is small compared to a natural scale in the reaction. This scale is determined by the particular dynamics of pion interaction, and one may roughly say that a pion is soft if its energy is small compared to the energies of the other individual particles that participate in the reaction. It is important to note at this point that pion is by far the lightest member of all the hadrons, and much of the success of the soft pion formulas depends on this fact.

  17. Nucleic acid isolation process

    Energy Technology Data Exchange (ETDEWEB)

    Longmire, Jonathan L. (Los Alamos, NM); Lewis, Annette K. (La Jolla, CA); Hildebrand, Carl E. (Los Alamos, NM)


    A method is provided for isolating DNA from eukaryotic cell and flow sorted chromosomes. When DNA is removed from chromosome and cell structure, detergent and proteolytic digestion products remain with the DNA. These products can be removed with organic extraction, but the process steps associated with organic extraction reduce the size of DNA fragments available for experimental use. The present process removes the waste products by dialyzing a solution containing the DNA against a solution containing polyethylene glycol (PEG). The waste products dialyze into the PEG leaving isolated DNA. The remaining DNA has been prepared with fragments containing more than 160 kb. The isolated DNA has been used in conventional protocols without affect on the protocol.

  18. Posttranslational processing of progastrin

    DEFF Research Database (Denmark)

    Bundgaard, Jens René; Rehfeld, Jens F.


    Gastrin and cholecystokinin (CCK) are homologous hormones with important functions in the brain and the gut. Gastrin is the main regulator of gastric acid secretion and gastric mucosal growth, whereas cholecystokinin regulates gall bladder emptying, pancreatic enzyme secretion and besides acts...... as a major neurotransmitter in the central and peripheral nervous systems. The tissue-specific expression of the hormones is regulated at the transcriptional level, but the posttranslational phase is also decisive and is highly complex in order to ensure accurate maturation of the prohormones in a cell...... specific manner. Despite the structural similarities of gastrin and CCK, there are decisive differences in the posttranslational processing and secretion schemes, suggesting that specific features in the processing may have evolved to serve specific purposes. For instance, CCK peptides circulate in low...

  19. Improving Healthcare Logistics Processes

    DEFF Research Database (Denmark)

    Feibert, Diana Cordes

    provision whilst providing high quality care. Logistics activities in hospitals provide a significant opportunity for cost containment in healthcare through the implementation of best practices. Literature provides little guidance on how to improve healthcare logistics processes. This study investigates...... at hospitals in Denmark and the US investigating three different types of processes: bed logistics, hospital cleaning, and pharmaceutical distribution. Based on an analysis and comparison of the case studies, a set of factors were identified influencing the decision on how to improve healthcare logistics......Healthcare costs are increasing due to an ageing population and more sophisticated technologies and treatments. At the same time, patients expect high quality care at an affordable cost. The healthcare industry has therefore experienced increasing pressures to reduce the cost of healthcare...

  20. Posttranslational processing of progastrin

    DEFF Research Database (Denmark)

    Bundgaard, Jens René; Rehfeld, Jens F.


    Gastrin and cholecystokinin (CCK) are homologous hormones with important functions in the brain and the gut. Gastrin is the main regulator of gastric acid secretion and gastric mucosal growth, whereas cholecystokinin regulates gall bladder emptying, pancreatic enzyme secretion and besides acts...... specific manner. Despite the structural similarities of gastrin and CCK, there are decisive differences in the posttranslational processing and secretion schemes, suggesting that specific features in the processing may have evolved to serve specific purposes. For instance, CCK peptides circulate in low...... picomolar concentrations, whereas the cellular expression of gastrin is expressed at higher levels, and accordingly gastrin circulates in 10-20-fold higher concentrations. Both common cancers and the less frequent neuroendocrine tumors express the gastrin gene and prohormone. But the posttranslational...

  1. Surgeons and cognitive processes. (United States)

    Hall, J C; Ellis, C; Hamdorf, J


    The surgical mind is geared to make important decisions and perform highly skilled tasks. The aim of this review is to explore the cognitive processes that link these actions. The core of this review is derived from a literature search of a computer database (Medline). The surgical image is one of action. However, the effective performance of surgery requires more than mere manual dexterity and it is evident that competent surgeons exhibit the cognitive traits that are held by all experts. The changes that are occurring in surgery indicate a need to place greater emphasis on the cognitive processes that underpin the practice of surgery. It is important that surgeons do not become victims of their own cult image. Copyright 2002 British Journal of Surgery Society Ltd. Published by John Wiley & Sons, Ltd.

  2. Oxygen Dependent Biocatalytic Processes

    DEFF Research Database (Denmark)

    Pedersen, Asbjørn Toftgaard

    Enzyme catalysts have the potential to improve both the process economics and the environ-mental profile of many oxidation reactions especially in the fine- and specialty-chemical industry, due to their exquisite ability to perform stereo-, regio- and chemo-selective oxida-tions at ambient temper...... far below their potential maximum catalytic rate at industrially relevant oxygen concentrations. Detailed knowledge of the en-zyme kinetics are therefore required in order to determine the best operating conditions and design oxygen supply to minimize processing costs. This is enabled...... by the development of the tube-in-tube reactor (TiTR) setup, capable of performing fully automated kinetic char-acterization of oxygen dependent enzymes - at oxygen concentrations allowing full satura-tion of the enzyme. The development of the TiTR enables us to characterize a range of en-zyme variants developed...

  3. Improving staff selection processes. (United States)

    Cerinus, Marie; Shannon, Marina


    This article, the second in a series of articles on Leading Better Care, describes the actions undertaken in recent years in NHS Lanarkshire to improve selection processes for nursing, midwifery and allied health professional (NMAHP) posts. This is an area of significant interest to these professions, management colleagues and patients given the pivotal importance of NMAHPs to patient care and experience. In recent times the importance of selecting staff not only with the right qualifications but also with the right attributes has been highlighted to ensure patients are well cared for in a safe, effective and compassionate manner. The article focuses on NMAHP selection processes, tracking local, collaborative development work undertaken to date. It presents an overview of some of the work being implemented, highlights a range of important factors, outlines how evaluation is progressing and concludes by recommending further empirical research.

  4. A Logical Process Calculus (United States)

    Cleaveland, Rance; Luettgen, Gerald; Bushnell, Dennis M. (Technical Monitor)


    This paper presents the Logical Process Calculus (LPC), a formalism that supports heterogeneous system specifications containing both operational and declarative subspecifications. Syntactically, LPC extends Milner's Calculus of Communicating Systems with operators from the alternation-free linear-time mu-calculus (LT(mu)). Semantically, LPC is equipped with a behavioral preorder that generalizes Hennessy's and DeNicola's must-testing preorder as well as LT(mu's) satisfaction relation, while being compositional for all LPC operators. From a technical point of view, the new calculus is distinguished by the inclusion of: (1) both minimal and maximal fixed-point operators and (2) an unimple-mentability predicate on process terms, which tags inconsistent specifications. The utility of LPC is demonstrated by means of an example highlighting the benefits of heterogeneous system specification.

  5. Processing of verb tense

    Directory of Open Access Journals (Sweden)

    Kostić Aleksandar Đ.


    Full Text Available Processing of Serbian inflected verbs was investigated in two lexical decision experiments. In the first experiment subjects were presented with five forms of future tense, while in the second experiment the same verbs were presented in three forms of present and future tense. The outcome of the first experiment indicates that processing of inflected verb is determined by the amount of information derived from the average probability per congruent personal pronoun of a particular verb form. This implies that the cognitive system is not sensitive to verb person per se, nor to the gender of congruent personal pronoun. Results of the second experiment show that for verb forms of different tenses, presented in the same experiment, the amount of information has to be additionally modulated by tense probability. Such an outcome speaks in favor of cognitive relevance of verb tense.

  6. Organic food processing

    DEFF Research Database (Denmark)

    Kahl, Johannes; Alborzi, Farnaz; Beck, Alexander


    In 2007 EU Regulation (EC) 834/2007 introduced principles and criteria for organic food processing. These regulations have been analysed and discussed in several scientific publications and research project reports. Recently, organic food quality was described by principles, aspects and criteria....... These principles from organic agriculture were verified and adapted for organic food processing. Different levels for evaluation were suggested. In another document, underlying paradigms and consumer perception of organic food were reviewed against functional food, resulting in identifying integral product...... identity as the underlying paradigm and a holistic quality view connected to naturalness as consumers' perception of organic food quality. In a European study, the quality concept was applied to the organic food chain, resulting in a problem, namely that clear principles and related criteria were missing...

  7. On the Radicalization Process. (United States)

    Leistedt, Samuel J


    This study aimed to provide an in-depth description of the radicalization process, which is a very important step in terrorist activities. The author proposes a translational analysis that is first based on the author's experience in the psychological evaluation of terrorist behavior and second on an exhaustive review of the current literature. The search terms "terrorism," "radicalization," "social psychology," and "psychopathology" were used to identify relevant studies in the following databases: Scopus, Medline, PubCentral, and Science Direct. Because of its importance, understanding radicalization process should be one of the priorities of behavioral scientists. International studies should be performed with a focus on several aspects, such as radicalization risk factors, brainwashing, the role of the media, and finally, in de-radicalization programs. © 2016 American Academy of Forensic Sciences.

  8. Plant hydrocarbon recovery process

    Energy Technology Data Exchange (ETDEWEB)

    Dzadzic, P.M.; Price, M.C.; Shih, C.J.; Weil, T.A.


    A process for production and recovery of hydrocarbons from hydrocarbon-containing whole plants in a form suitable for use as chemical feedstocks or as hydrocarbon energy sources which process comprises: (A) pulverizing by grinding or chopping hydrocarbon-containing whole plants selected from the group consisting of euphorbiaceae, apocynaceae, asclepiadaceae, compositae, cactaceae and pinaceae families to a suitable particle size, (B) drying and preheating said particles in a reducing atmosphere under positive pressure (C) passing said particles through a thermal conversion zone containing a reducing atmosphere and with a residence time of 1 second to about 30 minutes at a temperature within the range of from about 200* C. To about 1000* C., (D) separately recovering the condensable vapors as liquids and the noncondensable gases in a condition suitable for use as chemical feedstocks or as hydrocarbon fuels.

  9. Process Improvement: Customer Service. (United States)

    Cull, Donald


    Utilizing the comment section of patient satisfaction surveys, Clark Memorial Hospital in Jeffersonville, IN went through a thoughtful process to arrive at an experience that patients said they wanted. Two Lean Six Sigma tools were used--the Voice of the Customer (VoC) and the Affinity Diagram. Even when using these tools, a facility will not be able to accomplish everything the patient may want. Guidelines were set and rules were established for the Process Improvement Team in order to lessen frustration, increase focus, and ultimately be successful. The project's success is driven by the team members carrying its message back to their areas. It's about ensuring that everyone is striving to improve the patients' experience by listening to what they say is being done right and what they say can be done better. And then acting on it.

  10. Representative process sampling - in practice

    DEFF Research Database (Denmark)

    Esbensen, Kim; Friis-Pedersen, Hans Henrik; Julius, Lars Petersen


    Didactic data sets representing a range of real-world processes are used to illustrate "how to do" representative process sampling and process characterisation. The selected process data lead to diverse variogram expressions with different systematics (no range vs. important ranges; trends and/or...... presented cases of variography either solved the initial problems or served to understand the reasons and causes behind the specific process structures revealed in the variograms. Process Analytical Technologies (PAT) are not complete without process TOS....

  11. Viruses as living processes. (United States)

    Dupré, John; Guttinger, Stephan


    The view that life is composed of distinct entities with well-defined boundaries has been undermined in recent years by the realisation of the near omnipresence of symbiosis. What had seemed to be intrinsically stable entities have turned out to be systems stabilised only by the interactions between a complex set of underlying processes (Dupré, 2012). This has not only presented severe problems for our traditional understanding of biological individuality but has also led some to claim that we need to switch to a process ontology to be able adequately to understand biological systems. A large group of biological entities, however, has been excluded from these discussions, namely viruses. Viruses are usually portrayed as stable and distinct individuals that do not fit the more integrated and collaborative picture of nature implied by symbiosis. In this paper we will contest this view. We will first discuss recent findings in virology that show that viruses can be 'nice' and collaborate with their hosts, meaning that they form part of integrated biological systems and processes. We further offer various reasons why viruses should be seen as processes rather than things, or substances. Based on these two claims we will argue that, far from serving as a counterexample to it, viruses actually enable a deeper understanding of the fundamentally interconnected and collaborative nature of nature. We conclude with some reflections on the debate as to whether viruses should be seen as living, and argue that there are good reasons for an affirmative answer to this question. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Process through practice

    DEFF Research Database (Denmark)

    Burry, Jane; Burry, Mark; Tamke, Martin


    This paper describes the development of a design and prototype production system for novel structural use of networked small components of wood deploying elastic and plastic bending. The design process engaged with a significant number of different overlapping and interrelated design criteria...... visual feedback and to capture new knowledge specifically regarding intrinsic material behavior applied and tested in a heterogeneous networked context. The outcome was a prototype system of design ideation, conceptualization, development and production that integrated real time material performance...

  13. Stochastic conditional intensity processes

    DEFF Research Database (Denmark)

    Bauwens, Luc; Hautsch, Nikolaus


    In this article, we introduce the so-called stochastic conditional intensity (SCI) model by extending Russell’s (1999) autoregressive conditional intensity (ACI) model by a latent common dynamic factor that jointly drives the individual intensity components. We show by simulations that the propos...... for a joint latent factor and show that its inclusion allows for an improved and more parsimonious specification of the multivariate intensity process...

  14. Aluminum powder metallurgy processing

    Energy Technology Data Exchange (ETDEWEB)

    Flumerfelt, J.F.


    The objective of this dissertation is to explore the hypothesis that there is a strong linkage between gas atomization processing conditions, as-atomized aluminum powder characteristics, and the consolidation methodology required to make components from aluminum powder. The hypothesis was tested with pure aluminum powders produced by commercial air atomization, commercial inert gas atomization, and gas atomization reaction synthesis (GARS). A comparison of the GARS aluminum powders with the commercial aluminum powders showed the former to exhibit superior powder characteristics. The powders were compared in terms of size and shape, bulk chemistry, surface oxide chemistry and structure, and oxide film thickness. Minimum explosive concentration measurements assessed the dependence of explosibility hazard on surface area, oxide film thickness, and gas atomization processing conditions. The GARS aluminum powders were exposed to different relative humidity levels, demonstrating the effect of atmospheric conditions on post-atomization processing conditions. The GARS aluminum powders were exposed to different relative humidity levels, demonstrating the effect of atmospheric conditions on post-atomization oxidation of aluminum powder. An Al-Ti-Y GARS alloy exposed in ambient air at different temperatures revealed the effect of reactive alloy elements on post-atomization powder oxidation. The pure aluminum powders were consolidated by two different routes, a conventional consolidation process for fabricating aerospace components with aluminum powder and a proposed alternative. The consolidation procedures were compared by evaluating the consolidated microstructures and the corresponding mechanical properties. A low temperature solid state sintering experiment demonstrated that tap densified GARS aluminum powders can form sintering necks between contacting powder particles, unlike the total resistance to sintering of commercial air atomization aluminum powder.


    Johnson, B.M. Jr.; Barton, G.B.


    A process for treating radioactive waste solutions prior to disposal is described. A water-soluble phosphate, borate, and/or silicate is added. The solution is sprayed with steam into a space heated from 325 to 400 deg C whereby a powder is formed. The powder is melted and calcined at from 800 to 1000 deg C. Water vapor and gaseous products are separated from the glass formed. (AEC)

  16. Image processing occupancy sensor (United States)

    Brackney, Larry J.


    A system and method of detecting occupants in a building automation system environment using image based occupancy detection and position determinations. In one example, the system includes an image processing occupancy sensor that detects the number and position of occupants within a space that has controllable building elements such as lighting and ventilation diffusers. Based on the position and location of the occupants, the system can finely control the elements to optimize conditions for the occupants, optimize energy usage, among other advantages.

  17. Processing of larch oleoresin

    Energy Technology Data Exchange (ETDEWEB)

    Delkova, K.K. Repyakh, S.M.; Rachinskii, A.V.; Gornostaeva, L.I.; Manakov, V.A.; Ivanov, A.F.


    Larch oleoresin was processed by conventional method involving distillation of turpentine by direct steam or CO/sub 2/ clarification with H/sub 3/PO/sub 4/ in slightly higher concentration than that used for pine oleoresin. Larch rosin has the following composition: resin acids 57.13, unsaponifiable matter 24.60, fatty acids, 9.24, and oxidized matter 8.68%. In general, larch rosin is slightly inferior to pine rosin, but still meets the basic requirements.

  18. Femtosecond laser materials processing

    Energy Technology Data Exchange (ETDEWEB)

    Stuart, B. C., LLNL


    Femtosecond lasers enable materials processing of most any material with extremely high precision and negligible shock or thermal loading to the surrounding area Applications ranging from drilling teeth to cutting explosives to making high-aspect ratio cuts in metals with no heat-affected zone are made possible by this technology For material removal at reasonable rates, we developed a fully computer-controlled 15-Watt average power, 100-fs laser machining system.

  19. Fastdata processing with Spark

    CERN Document Server

    Karau, Holden


    This book will be a basic, step-by-step tutorial, which will help readers take advantage of all that Spark has to offer.Fastdata Processing with Spark is for software developers who want to learn how to write distributed programs with Spark. It will help developers who have had problems that were too much to be dealt with on a single computer. No previous experience with distributed programming is necessary. This book assumes knowledge of either Java, Scala, or Python.

  20. Technology Management Process Framework


    Yamamoto, Ikura; Pujotomo, Darminto


    The effective management of technology as a source of competitive advantage is of vital importance for many organizations. It is necessary to understand, communicate and integrate technology strategy with marketing, financial, operations and human resource strategies. This is of particular importance when one considers the increasing cost, pace and complexity of technology developments, combined with shortening product life cycles. A five process model provides a framework within which techno...

  1. Parallel processing ITS

    Energy Technology Data Exchange (ETDEWEB)

    Fan, W.C.; Halbleib, J.A. Sr.


    This report provides a users` guide for parallel processing ITS on a UNIX workstation network, a shared-memory multiprocessor or a massively-parallel processor. The parallelized version of ITS is based on a master/slave model with message passing. Parallel issues such as random number generation, load balancing, and communication software are briefly discussed. Timing results for example problems are presented for demonstration purposes.

  2. Electrostatic containerless processing system (United States)

    Rulison, Aaron J.; Watkins, John L.; Zambrano, Brian


    We introduce a materials science tool for investigating refractory solids and melts: the electrostatic containerless processing system (ESCAPES). ESCAPES maintains refractory specimens of materials in a pristine state by levitating and heating them in a vacuum chamber, thereby avoiding the contaminating influences of container walls and ambient gases. ESCAPES is designed for the investigation of thermophysical properties, phase equilibria, metastable phase formation, undercooling and nucleation, time-temperature-transformation diagrams, and other aspects of materials processing. ESCAPES incorporates several design improvements over prior electrostatic levitation technology. It has an informative and responsive computer control system. It has separate light sources for heating and charging, which prevents runaway discharging. Both the heating and charging light sources are narrow band, which allows the use of optical pyrometry and other diagnostics at all times throughout processing. Heat is provided to the levitated specimens by a 50 W Nd:YAG laser operating at 1.064 μm. A deuterium arc lamp charges the specimen through photoelectric emission. ESCAPES can heat metals, ceramics, and semiconductors to temperatures exceeding 2300 K; specimens range in size from 1 to 3 mm diam. This article describes the design, capabilities, and applications of ESCAPES, focusing on improvements over prior electrostatic levitation technology.

  3. Monolith electroplating process (United States)

    Agarrwal, Rajev R.


    An electroplating process for preparing a monolith metal layer over a polycrystalline base metal and the plated monolith product. A monolith layer has a variable thickness of one crystal. The process is typically carried in molten salts electrolytes, such as the halide salts under an inert atmosphere at an elevated temperature, and over deposition time periods and film thickness sufficient to sinter and recrystallize completely the nucleating metal particles into one single crystal or crystals having very large grains. In the process, a close-packed film of submicron particle (20) is formed on a suitable substrate at an elevated temperature. The temperature has the significance of annealing particles as they are formed, and substrates on which the particles can populate are desirable. As the packed bed thickens, the submicron particles develop necks (21) and as they merge into each other shrinkage (22) occurs. Then as micropores also close (23) by surface tension, metal density is reached and the film consists of unstable metal grain (24) that at high enough temperature recrystallize (25) and recrystallized grains grow into an annealed single crystal over the electroplating time span. While cadmium was used in the experimental work, other soft metals may be used.

  4. The Caroline interrogatory process

    Energy Technology Data Exchange (ETDEWEB)

    Degagne, D. [Alberta Energy and Utilities Board, Calgary, AB (Canada); Gibson, T. [Gecko Management, Calgary, AB (Canada)


    Using the specific case study of the Caroline interrogatory process, an example is given of how an effective communications and public involvement program can re-establish trust and credibility levels within an community after an incident. The public is nervous about sour gas, especially about blowouts of gas from a pipeline. The post-approval period was marked by high expectations and a community consultation program which included a community advisory board, an emergency planning committee, socio-economic factors, and environmental monitoring and studies. Information and education involves newspaper articles, newsletters, tours, public consultation meetings, and weekly e-mail. Mercury was detected as a potential hazard at the site, and company actions are illustrated. Overall lessons learned included: starting early paid off, face to face resident contacts were the most effective, the willingness to make changes was the key to success, the community helped, knowing all the answers is not essential, and there is a need for empathy. The interrogatory process includes a hybrid technique that is comprised of four stages: 1) process review and public input, 2) identification and clarification of issues, 3) responses by industry and government, and 4) a public forum and follow-up action.

  5. The Caroline interrogatory process

    Energy Technology Data Exchange (ETDEWEB)

    Degagne, D. (Alberta Energy and Utilities Board, Calgary, AB (Canada)); Gibson, T. (Gecko Management, Calgary, AB (Canada))


    Using the specific case study of the Caroline interrogatory process, an example is given of how an effective communications and public involvement program can re-establish trust and credibility levels within an community after an incident. The public is nervous about sour gas, especially about blowouts of gas from a pipeline. The post-approval period was marked by high expectations and a community consultation program which included a community advisory board, an emergency planning committee, socio-economic factors, and environmental monitoring and studies. Information and education involves newspaper articles, newsletters, tours, public consultation meetings, and weekly e-mail. Mercury was detected as a potential hazard at the site, and company actions are illustrated. Overall lessons learned included: starting early paid off, face to face resident contacts were the most effective, the willingness to make changes was the key to success, the community helped, knowing all the answers is not essential, and there is a need for empathy. The interrogatory process includes a hybrid technique that is comprised of four stages: 1) process review and public input, 2) identification and clarification of issues, 3) responses by industry and government, and 4) a public forum and follow-up action.

  6. Multivariate Statistical Process Control

    DEFF Research Database (Denmark)

    Kulahci, Murat


    As sensor and computer technology continues to improve, it becomes a normal occurrence that we confront with high dimensional data sets. As in many areas of industrial statistics, this brings forth various challenges in statistical process control (SPC) and monitoring for which the aim is to iden......As sensor and computer technology continues to improve, it becomes a normal occurrence that we confront with high dimensional data sets. As in many areas of industrial statistics, this brings forth various challenges in statistical process control (SPC) and monitoring for which the aim...... is to identify “out-of-control” state of a process using control charts in order to reduce the excessive variation caused by so-called assignable causes. In practice, the most common method of monitoring multivariate data is through a statistic akin to the Hotelling’s T2. For high dimensional data with excessive...... amount of cross correlation, practitioners are often recommended to use latent structures methods such as Principal Component Analysis to summarize the data in only a few linear combinations of the original variables that capture most of the variation in the data. Applications of these control charts...

  7. Advanced microwave processing concepts

    Energy Technology Data Exchange (ETDEWEB)

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L. [Oak Ridge National Lab., TN (United States)


    The purpose of this work is to explore the feasibility of several advanced microwave processing concepts to develop new energy-efficient materials and processes. The project includes two tasks: (1) commercialization of the variable-frequency microwave furnace; and (2) microwave curing of polymeric materials. The variable frequency microwave furnace, whose initial conception and design was funded by the AIM Materials Program, allows the authors, for the first time, to conduct microwave processing studies over a wide frequency range. This novel design uses a high-power traveling wave tube (TWT) originally developed for electronic warfare. By using this microwave source, one can not only select individual microwave frequencies for particular experiments, but also achieve uniform power densities over a large area by the superposition of many different frequencies. Microwave curing of various thermoset resins will be studied because it holds the potential of in-situ curing of continuous-fiber composites for strong, lightweight components or in-situ curing of adhesives, including metal-to-metal. Microwave heating can shorten curing times, provided issues of scaleup, uniformity, and thermal management can be adequately addressed.

  8. Software Process Assessment (SPA) (United States)

    Rosenberg, Linda H.; Sheppard, Sylvia B.; Butler, Scott A.


    NASA's environment mirrors the changes taking place in the nation at large, i.e. workers are being asked to do more work with fewer resources. For software developers at NASA's Goddard Space Flight Center (GSFC), the effects of this change are that we must continue to produce quality code that is maintainable and reusable, but we must learn to produce it more efficiently and less expensively. To accomplish this goal, the Data Systems Technology Division (DSTD) at GSFC is trying a variety of both proven and state-of-the-art techniques for software development (e.g., object-oriented design, prototyping, designing for reuse, etc.). In order to evaluate the effectiveness of these techniques, the Software Process Assessment (SPA) program was initiated. SPA was begun under the assumption that the effects of different software development processes, techniques, and tools, on the resulting product must be evaluated in an objective manner in order to assess any benefits that may have accrued. SPA involves the collection and analysis of software product and process data. These data include metrics such as effort, code changes, size, complexity, and code readability. This paper describes the SPA data collection and analysis methodology and presents examples of benefits realized thus far by DSTD's software developers and managers.

  9. Onboard image processing (United States)

    Martin, D. R.; Samulon, A. S.


    The possibility of onboard geometric correction of Thematic Mapper type imagery to make possible image registration is considered. Typically, image registration is performed by processing raw image data on the ground. The geometric distortion (e.g., due to variation in spacecraft location and viewing angle) is estimated by using a Kalman filter updated by correlating the received data with a small reference subimage, which has known location. Onboard image processing dictates minimizing the complexity of the distortion estimation while offering the advantages of a real time environment. In keeping with this, the distortion estimation can be replaced by information obtained from the Global Positioning System and from advanced star trackers. Although not as accurate as the conventional ground control point technique, this approach is capable of achieving subpixel registration. Appropriate attitude commands can be used in conjunction with image processing to achieve exact overlap of image frames. The magnitude of the various distortion contributions, the accuracy with which they can be measured in real time, and approaches to onboard correction are investigated.

  10. 18. Preparedness process. (United States)


    This Chapter provides a layout for the development, implementation, and evaluation of interventions designed to enhance/augment the levels of preparedness of the public health and medical care aspects of disasters. The preparedness framework is provided for the analysis of the preparedness process and consists of 17 steps: (1) hazard and risk identification; (2) vulnerabilities, historical perspectives and predictions; (3) selection of hazard(s) to address; (4) selection of indicators; (5) standards and benchmarks for preparedness; (6) current status; (7) identification of preparedness needs; (8) strategic planning; (9) selection of intervention; (10) operational planning; (11) implementation; (12) conclusion/finalise: end points; (13) documentation of effects; (14) transition, maintenance, sustainability; (15) evaluation; and (16) feedback. At any time in this algorithm the process may be terminated by or after consultation with the coordination and control centre. Each of these processes is described in detail. In addition, attention is directed to the coordination and control centre during planning, preparedness, and evaluations of preparedness.

  11. Process Information and Evolution. (United States)

    Chastain, Erick; Smith, Cameron


    Universal Semantic Communication (USC) is a theory that models communication among agents without the assumption of a fixed protocol. We demonstrate a connection, via a concept we refer to as process information, between a special case of USC and evolutionary processes. In this context, one agent attempts to interpret a potentially arbitrary signal produced within its environment. Sources of this effective signal can be modeled as a single alternative agent. Given a set of common underlying concepts that may be symbolized differently by different sources in the environment, any given entity must be able to correlate intrinsic information with input it receives from the environment in order to accurately interpret the ambient signal and ultimately coordinate its own actions. This scenario encapsulates a class of USC problems that provides insight into the semantic aspect of a model of evolution proposed by Rivoire and Leibler. Through this connection, we show that evolution corresponds to a means of solving a special class of USC problems, can be viewed as a special case of the Multiplicative Weights Updates algorithm, and that infinite population selection with no mutation and no recombination conforms to the Rivoire-Leibler model. Finally, using process information we show that evolving populations implicitly internalize semantic information about their respective environments.

  12. Aeolian processes on Venus (United States)

    Greeley, R.


    Many of the questions regarding aeolian processes on Venus and the subsequent implications for surface history involve understanding the physics of particle motion in the venusian environment. The surface environment of Venus is simulated as closely as practicable using the Venus Wind Tunnel and to determine threshold wind speeds, particle flux, particle velocities, and the characteristics of various aeolian bedforms. Despite the relatively low wind speeds on Venus, the flux of windblown material on Venus is potentially high. A high fraction of material is transported as surface creep by rolling, estimates yield rates up to 100 kg per cm lane width per year depending upon the availability of material and wind frequency, suggesting that the formation of lowland plains by aeolian processes and the burial of various landforms such as impact craters could occur on short geological time-scales. Wind tunnel simulations demonstrate that aeolian processes may be very effective in modifying the surface through erosion and deposited and may have an important influence on the composition of the atmosphere.


    Jonke, A.A.


    In improved solvent extraction process is described for the extraction of metal values from highly dilute aqueous solutions. The process comprises contacting an aqueous solution with an organic substantially water-immiscible solvent, whereby metal values are taken up by a solvent extract phase; scrubbing the solvent extract phase with an aqueous scrubbing solution; separating an aqueous solution from the scrubbed solvent extract phase; and contacting the scrubbed solvent phase with an aqueous medium whereby the extracted metal values are removed from the solvent phase and taken up by said medium to form a strip solution containing said metal values, the aqueous scrubbing solution being a mixture of strip solution and an aqueous solution which contains mineral acids anions and is free of the metal values. The process is particularly effective for purifying uranium, where one starts with impure aqueous uranyl nitrate, extracts with tributyl phosphate dissolved in carbon tetrachloride, scrubs with aqueous nitric acid and employs water to strip the uranium from the scrubbed organic phase.

  14. Processing of iron aluminides

    Energy Technology Data Exchange (ETDEWEB)

    Sundar, R.S.; Prasad, Y.V.R.K.; Sastry, D.H. [Indian Inst. of Science, Bangalore (India). Dept. of Metallurgy; Baligidad, R.G. [Defence Metallurgical Research Laboratory, Hyderabad 500 058 (India)


    A processing route comprising of air induction melting (AIM) with protective cover and electroslag remelting (ESR) for production of iron aluminide (Fe{sub 3}Al) alloys has been developed. The use of protective cover during AIM results in the minimization of hydrogen gas porosity and a significant reduction in the impurity levels (S, O and N). Attempts have been made to further improve the ductility and hot workability through ESR. The AIM melted with high carbon ingots exhibit excellent tensile properties compared to the low (<0.074 wt.%) carbon ingots where cracks persist even after ESR. Processing maps were developed for vacuum induction melted as-cast binary and ternary (Cr and Mn) Fe{sub 3}Al alloys. Processing maps of Fe{sub 3}Al and Fe{sub 3}Al-Cr exhibit a dynamic recrystallisation domain at temperatures >1123 K. Dynamic recrystallisation in iron aluminides is controlled by migration of interfaces. In the case of Fe{sub 3}Al-Mn, dynamic recrystallisation is suppressed due to greater resistance to the migration of interfaces. Instead, large grain superplasticity is observed. (orig.) 20 refs.

  15. Mars Aqueous Processing System (United States)

    Berggren, Mark; Wilson, Cherie; Carrera, Stacy; Rose, Heather; Muscatello, Anthony; Kilgore, James; Zubrin, Robert


    The goal of the Mars Aqueous Processing System (MAPS) is to establish a flexible process that generates multiple products that are useful for human habitation. Selectively extracting useful components into an aqueous solution, and then sequentially recovering individual constituents, can obtain a suite of refined or semi-refined products. Similarities in the bulk composition (although not necessarily of the mineralogy) of Martian and Lunar soils potentially make MAPS widely applicable. Similar process steps can be conducted on both Mars and Lunar soils while tailoring the reaction extents and recoveries to the specifics of each location. The MAPS closed-loop process selectively extracts, and then recovers, constituents from soils using acids and bases. The emphasis on Mars involves the production of useful materials such as iron, silica, alumina, magnesia, and concrete with recovery of oxygen as a byproduct. On the Moon, similar chemistry is applied with emphasis on oxygen production. This innovation has been demonstrated to produce high-grade materials, such as metallic iron, aluminum oxide, magnesium oxide, and calcium oxide, from lunar and Martian soil simulants. Most of the target products exhibited purities of 80 to 90 percent or more, allowing direct use for many potential applications. Up to one-fourth of the feed soil mass was converted to metal, metal oxide, and oxygen products. The soil residue contained elevated silica content, allowing for potential additional refining and extraction for recovery of materials needed for photovoltaic, semiconductor, and glass applications. A high-grade iron oxide concentrate derived from lunar soil simulant was used to produce a metallic iron component using a novel, combined hydrogen reduction/metal sintering technique. The part was subsequently machined and found to be structurally sound. The behavior of the lunar-simulant-derived iron product was very similar to that produced using the same methods on a Michigan iron

  16. Data model for Process Documentation


    Munroe, S; Groth, P; Jiang, Sheng; Miles, S; Tan, V; Moreau, L


    This document describes the data model for \\emph{process documentation}; information describing process. It starts by describing the logical organisation of process documentation, before drilling down into the models of the different forms of process documentation. It then describes how individual pieces of process documentation and data items can be identified. Finally, a model of context is provided.

  17. Discovery as a process

    Energy Technology Data Exchange (ETDEWEB)

    Loehle, C.


    The three great myths, which form a sort of triumvirate of misunderstanding, are the Eureka! myth, the hypothesis myth, and the measurement myth. These myths are prevalent among scientists as well as among observers of science. The Eureka! myth asserts that discovery occurs as a flash of insight, and as such is not subject to investigation. This leads to the perception that discovery or deriving a hypothesis is a moment or event rather than a process. Events are singular and not subject to description. The hypothesis myth asserts that proper science is motivated by testing hypotheses, and that if something is not experimentally testable then it is not scientific. This myth leads to absurd posturing by some workers conducting empirical descriptive studies, who dress up their study with a ``hypothesis`` to obtain funding or get it published. Methods papers are often rejected because they do not address a specific scientific problem. The fact is that many of the great breakthroughs in silence involve methods and not hypotheses or arise from largely descriptive studies. Those captured by this myth also try to block funding for those developing methods. The third myth is the measurement myth, which holds that determining what to measure is straightforward, so one doesn`t need a lot of introspection to do science. As one ecologist put it to me ``Don`t give me any of that philosophy junk, just let me out in the field. I know what to measure.`` These myths lead to difficulties for scientists who must face peer review to obtain funding and to get published. These myths also inhibit the study of science as a process. Finally, these myths inhibit creativity and suppress innovation. In this paper I first explore these myths in more detail and then propose a new model of discovery that opens the supposedly miraculous process of discovery to doser scrutiny.

  18. Solar Flares: Magnetohydrodynamic Processes

    Directory of Open Access Journals (Sweden)

    Kazunari Shibata


    Full Text Available This paper outlines the current understanding of solar flares, mainly focused on magnetohydrodynamic (MHD processes responsible for producing a flare. Observations show that flares are one of the most explosive phenomena in the atmosphere of the Sun, releasing a huge amount of energy up to about 10^32 erg on the timescale of hours. Flares involve the heating of plasma, mass ejection, and particle acceleration that generates high-energy particles. The key physical processes for producing a flare are: the emergence of magnetic field from the solar interior to the solar atmosphere (flux emergence, local enhancement of electric current in the corona (formation of a current sheet, and rapid dissipation of electric current (magnetic reconnection that causes shock heating, mass ejection, and particle acceleration. The evolution toward the onset of a flare is rather quasi-static when free energy is accumulated in the form of coronal electric current (field-aligned current, more precisely, while the dissipation of coronal current proceeds rapidly, producing various dynamic events that affect lower atmospheres such as the chromosphere and photosphere. Flares manifest such rapid dissipation of coronal current, and their theoretical modeling has been developed in accordance with observations, in which numerical simulations proved to be a strong tool reproducing the time-dependent, nonlinear evolution of a flare. We review the models proposed to explain the physical mechanism of flares, giving an comprehensive explanation of the key processes mentioned above. We start with basic properties of flares, then go into the details of energy build-up, release and transport in flares where magnetic reconnection works as the central engine to produce a flare.

  19. Food Processing Antioxidants. (United States)

    Hidalgo, F J; Zamora, R

    Food processing has been carried out since ancient times as a way to preserve and improve food nutritional and organoleptic properties. Although it has some undesirable consequences, such as the losses of some nutrients and the potential formation of toxic compounds, a wide range of benefits can be enumerated. Among them, the increased total antioxidant capacity of many processed foods has been known for long. This consequence has been related to both the release or increased availability of natural antioxidants and the de novo formation of substances with antioxidant properties as a consequence of the produced reactions. This review analyzes the chemical changes produced in foods during processing with special emphasis on the formation of antioxidants as a consequence of carbonyl-amine reactions produced by both carbohydrate- and lipid-derived reactive carbonyls. It discusses the lastest advances produced in the characterization of carbonyl-amine adducts and their potential action as primary (free radical scavengers), secondary (chelating and other ways to prevent lipid oxidation), and tertiary (carbonyl scavengers as a way to avoid lipid oxidation consequences) antioxidants. Moreover, the possibility of combining amino compounds with different hydrophobicity, such as aminophospholipids and proteins, with a wide array of reactive carbonyls points out to the use of carbonyl-amine reactions as a new way to induce the formation of a great variety of substances with antioxidant properties and very variable hydrophilia/lipophilia. All presented results point out to carbonyl-amine reactions as an effective method to generate efficacious antioxidants that can be used in food technology. © 2017 Elsevier Inc. All rights reserved.

  20. Time processing in dyscalculia

    Directory of Open Access Journals (Sweden)

    marinella eCappelletti


    Full Text Available To test whether atypical number development may affect other types of quantity processing, we investigated temporal discrimination in adults with developmental dyscalculia (DD. This also allowed us to test whether (1 number and time may be sub-served by a common quantity system or decision mechanisms –in which case they may both be impaired, or (2 whether number and time are distinct –and therefore they may dissociate. Participants judged which of two successively presented horizontal lines was longer in duration, the first line being preceded by either a small or a large number prime (‘1’ or ‘9’ or by a neutral symbol (‘#’, or in third task decide which of two Arabic numbers (either ‘1’, ‘5’, ’9’ lasted longer. Results showed that (i DD’s temporal discriminability was normal as long as numbers were not part of the experimental design even as task-irrelevant stimuli; however (ii task-irrelevant numbers dramatically disrupted DD’s temporal discriminability, the more their salience increased, though the actual magnitude of the numbers had no effect; and in contrast (iii controls’ time perception was robust to the presence of numbers but modulated by numerical quantity such that small number primes or numerical stimuli made durations appear shorter than veridical and the opposite for larger numerical prime or numerical stimuli. This study is the first to investigate continuous quantity as time in a population with a congenital number impairment and to show that atypical development of numerical competence leaves continuous quantity processing spared. Our data support the idea of a partially shared quantity system across numerical and temporal dimensions, which allows dissociations and interactions among dimensions; furthermore, they suggest that impaired number in DD is unlikely to originate from systems initially dedicated to continuous quantity processing like time.

  1. Process for fullerene functionalization (United States)

    Cahill, Paul A.; Henderson, Craig C.


    Di-addended and tetra-addended Buckminster fullerenes are synthesized through the use of novel organoborane intermediates. The C.sub.60, C.sub.70, or higher fullerene is reacted with a borane such as BH.sub.3 in a solvent such as toluene to form an organoborane intermediate. Reaction of the organoborane such as hydrolysis with water or alcohol results in the product di-addended and tetra-addended fullerene in up to 30% yields. Dihydrofullerenes and tetrahydrofullerenes are produced by the process of the invention.

  2. Medical image processing

    CERN Document Server

    Dougherty, Geoff


    This book is designed for end users in the field of digital imaging, who wish to update their skills and understanding with the latest techniques in image analysis. This book emphasizes the conceptual framework of image analysis and the effective use of image processing tools. It uses applications in a variety of fields to demonstrate and consolidate both specific and general concepts, and to build intuition, insight and understanding. Although the chapters are essentially self-contained they reference other chapters to form an integrated whole. Each chapter employs a pedagogical approach to e

  3. Navigating the Publishing Process. (United States)

    Roush, Karen


    : This is the fourth and final article in a series to help nurses share their knowledge, skills, and insight through writing for publication. Nurses have something important to contribute no matter what their nursing role. This series will help nurses develop good writing habits and sharpen their writing skills. It will take nurses step by step through the publication process, highlighting what gets published and why, how to submit articles and work with editors, and common pitfalls to avoid. For the previous articles in this series, see

  4. Automatic Seismic Signal Processing (United States)


    81-04 4 February 1982 AUTOMATIC SEISMIC SIGNAL PROCESSING FINAL TECHNICAL REPORT i j Contract F08606-80.C-0021" PREPARED BY ILKKA NOPONEN, ROBERT SAX...PERFORMING ORG. REPORT NUMBER SAS-FR-81-04 7. AUTHOR(e) a. CONTRACT OR GRANT NUMBER(e) F08606- 80-C-0021 ILKKA NOPONEN, ROBERT SAX AND F 6 C0 STEVEN...observed, as also Swindell and Snell (1977), that the distribu- tion of x was slightly skewed, we used the median of x instead of aver- age of x for U(x

  5. Introduction to information processing

    CERN Document Server

    Dietel, Harvey M


    An Introduction to Information Processing provides an informal introduction to the computer field. This book introduces computer hardware, which is the actual computing equipment.Organized into three parts encompassing 12 chapters, this book begins with an overview of the evolution of personal computing and includes detailed case studies on two of the most essential personal computers for the 1980s, namely, the IBM Personal Computer and Apple's Macintosh. This text then traces the evolution of modern computing systems from the earliest mechanical calculating devices to microchips. Other chapte

  6. Phonocardiography Signal Processing

    CERN Document Server

    Abbas, Abbas K


    The auscultation method is an important diagnostic indicator for hemodynamic anomalies. Heart sound classification and analysis play an important role in the auscultative diagnosis. The term phonocardiography refers to the tracing technique of heart sounds and the recording of cardiac acoustics vibration by means of a microphone-transducer. Therefore, understanding the nature and source of this signal is important to give us a tendency for developing a competent tool for further analysis and processing, in order to enhance and optimize cardiac clinical diagnostic approach. This book gives the

  7. Fischer-Tropsch process (United States)

    Dyer, Paul N.; Pierantozzi, Ronald; Withers, Howard P.


    A Fischer-Tropsch process utilizing a product selective and stable catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas is selectively converted to higher hydrocarbons of relatively narrow carbon number range is disclosed. In general, the selective and notably stable catalyst, consist of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of a Fischer-Tropsch metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

  8. Hyperspectral image processing

    CERN Document Server

    Wang, Liguo


    Based on the authors’ research, this book introduces the main processing techniques in hyperspectral imaging. In this context, SVM-based classification, distance comparison-based endmember extraction, SVM-based spectral unmixing, spatial attraction model-based sub-pixel mapping, and MAP/POCS-based super-resolution reconstruction are discussed in depth. Readers will gain a comprehensive understanding of these cutting-edge hyperspectral imaging techniques. Researchers and graduate students in fields such as remote sensing, surveying and mapping, geosciences and information systems will benefit from this valuable resource.

  9. Optical processes in microcavities

    CERN Document Server

    Chang, R K


    The dielectric microstructures act as ultrahigh Q factors optical cavities, which modify the spontaneous emission rates and alter the spatial distributions of the input and output radiation. The editors have selected leading scientists who have made seminal contributions in different aspects of optical processes in microcavities. Every attempt has been made to unify the underlying physics pertaining to microcavities of various shapes. This book begins with a chapter on the role of microcavity modes with additional chapters on how these microcavity modes affect the spontaneous and stimulated em

  10. Digital signal processing

    CERN Document Server

    O'Shea, Peter; Hussain, Zahir M


    In three parts, this book contributes to the advancement of engineering education and that serves as a general reference on digital signal processing. Part I presents the basics of analog and digital signals and systems in the time and frequency domain. It covers the core topics: convolution, transforms, filters, and random signal analysis. It also treats important applications including signal detection in noise, radar range estimation for airborne targets, binary communication systems, channel estimation, banking and financial applications, and audio effects production. Part II considers sel


    Directory of Open Access Journals (Sweden)

    V. N. Konishchev


    Full Text Available This paper presents a new approach to the analysis of the genetic nature of the mineral substance of loessial rocks. At the present time, the prevailing view on this issue is the eolian accumulation of loess, while the influence of other factors of formation has not been practically taken into account. However, loess accumulation can be explained by other mechanisms, e.g., active processes of cryogenic weathering under a very harsh climate. The latter concept is based on the results of analysis of wedge-shaped structures in loess thickness, as well as numerous data of spore-pollen, microfaunistic, and other types of analysis. Further developing concepts of loess formation, the authors made an attempt to assess the degree of influence of cryogenic processes on the composition and structure of loess. The proposed method is based on a differentiated analysis of the distribution of the main rock-forming minerals (quartz and feldspars along the granulometric spectrum. Two criteria are proposed − the coefficient of cryogenic contrast and the heavy fraction coefficient (i.e., the coefficient of distribution of heavy minerals − which allow determining the degree of participation of cryogenic processes, as well as aeolian and aqueous sedimentation, in the formation of loessial rocks. This method was used to study two sections of loessial thickness − in the south of the Russian Plain and within the Loess Plateau of China. The results of the study revealed the role of cryogenic factors in the formation of the composition of the loess horizons of soil-loess sequences of different territories. Particularly clearly the effect of cryogenesis was manifested in the loess section in the south of the Russian Plain. In the section of the Loess Plateau, only the youngest deposits of the last formation stage are affected by cryogenesis. It follows that not only within the long-term periglacial permafrost zone, but also under the conditions of seasonal freezing

  12. FHR Process Instruments

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, David Eugene [ORNL


    Fluoride salt-cooled High temperature Reactors (FHRs) are entering into early phase engineering development. Initial candidate technologies have been identified to measure all of the required process variables. The purpose of this paper is to describe the proposed measurement techniques in sufficient detail to enable assessment of the proposed instrumentation suite and to support development of the component technologies. This paper builds upon the instrumentation chapter of the recently published FHR technology development roadmap. Locating instruments outside of the intense core radiation and high-temperature fluoride salt environment significantly decreases their environmental tolerance requirements. Under operating conditions, FHR primary coolant salt is a transparent, low-vapor-pressure liquid. Consequently, FHRs can employ standoff optical measurements from above the salt pool to assess in-vessel conditions. For example, the core outlet temperature can be measured by observing the fuel s blackbody emission. Similarly, the intensity of the core s Cerenkov glow indicates the fission power level. Short-lived activation of the primary coolant provides another means for standoff measurements of process variables. The primary coolant flow and neutron flux can be measured using gamma spectroscopy along the primary coolant piping. FHR operation entails a number of process measurements. Reactor thermal power and core reactivity are the most significant variables for process control. Thermal power can be determined by measuring the primary coolant mass flow rate and temperature rise across the core. The leading candidate technologies for primary coolant temperature measurement are Au-Pt thermocouples and Johnson noise thermometry. Clamp-on ultrasonic flow measurement, that includes high-temperature tolerant standoffs, is a potential coolant flow measurement technique. Also, the salt redox condition will be monitored as an indicator of its corrosiveness. Both

  13. Scramjet Combustion Processes (United States)


    Propulsion a vitesse elevee : Conception du moteur - integration et gestion thermique ) 14. ABSTRACT 15. SUBJECT TERMS 16. SECURITY CLASSIFICATION OF...entrance to the combustion duct, where the production of the chemical radicals, which are a first stage in Scramjet Combustion Processes RTO-EN-AVT-185...314KM) Nosecone Eject (47SEC,73KM,M7.7) Orion Burnout (39SEC,56KM,M7.1) Orion Ignition (12SEC,9.4KM,M3.2) Terrier Ignition (0SEC,0KM,M0) Stage

  14. The FICFB - gasification process

    Energy Technology Data Exchange (ETDEWEB)

    Hofbauer, H.; Veronik, G.; Fleck, T.; Rauch, R. [Vienna University of Technology (Austria); Mackinger, H.; Fercher, E. [Austrian Energy and Environment, Graz (Austria)


    A novel fluidized bed gasification reactor has been developed to get a product gas with a high calorific value (up to 15 MJ/Nm{sup 3}) and nearly free of nitrogen. The gasification process is based on an internally circulating fluidized system and consists of a gasification zone fluidized with steam and a combustion zone fluidized with air. The circulating bed material acts as heat carrier from the combustion to the gasification zone. Gas mixing between these two zones is avoided by construction measures. Furthermore, the apparatus is characterized by a very compact design. The results attained came fully up to expectations. (author)

  15. Frugal innovation process

    DEFF Research Database (Denmark)

    Hossain, Mokter; Levänen, Jarkko; Lindeman, Sara


    The objective of this paper is to understand the processes of the development of frugal innovation with an entrepreneurial spirit. The contributions of this study are twofold. First, we explore, compare, and contrast two very different contexts - grassroots and elite - of frugal innovation proces...... and another developed by an individual from the Gujarat, India. Using effectuation theory we find that there are some distinct differences between two categories regarding finance, access to science and technology, the motivation of innovators, options they have, actions they take, etc....

  16. Noncommutative stationary processes

    CERN Document Server

    Gohm, Rolf


    Quantum probability and the theory of operator algebras are both concerned with the study of noncommutative dynamics. Focusing on stationary processes with discrete-time parameter, this book presents (without many prerequisites) some basic problems of interest to both fields, on topics including extensions and dilations of completely positive maps, Markov property and adaptedness, endomorphisms of operator algebras and the applications arising from the interplay of these themes. Much of the material is new, but many interesting questions are accessible even to the reader equipped only with basic knowledge of quantum probability and operator algebras.

  17. Anaerobic Digestion: Process

    DEFF Research Database (Denmark)

    Angelidaki, Irini; Batstone, Damien J.


    Organic waste may degrade anaerobically in nature as well as in engineered systems. The latter is called anaerobic digestion or biogasification. Anaerobic digestion produces two main outputs: An energy-rich gas called biogas and an effluent. The effluent, which may be a solid as well as liquid...... with very little dry matter may also be called a digest. The digest should not be termed compost unless it specifically has been composted in an aerated step. This chapter describes the basic processes of anaerobic digestion. Chapter 9.5 describes the anaerobic treatment technologies, and Chapter 9.......6 addresses the mass balances and environmental aspects of anaerobic digestion....

  18. Process for treating biomass (United States)

    Campbell, Timothy J.; Teymouri, Farzaneh


    This invention is directed to a process for treating biomass. The biomass is treated with a biomass swelling agent within the vessel to swell or rupture at least a portion of the biomass. A portion of the swelling agent is removed from a first end of the vessel following the treatment. Then steam is introduced into a second end of the vessel different from the first end to further remove swelling agent from the vessel in such a manner that the swelling agent exits the vessel at a relatively low water content.

  19. Software Process Improvement

    DEFF Research Database (Denmark)

    Kuhrmann, Marco; Konopka, Claudia; Nellemann, Peter


    Software process improvement (SPI) is around for decades: frameworks are proposed, success factors are studied, and experiences have been reported. However, the sheer mass of concepts, approaches, and standards published over the years overwhelms practitioners as well as researchers. What is out...... directions. An analysis of 635 publications draws a big picture of SPI-related research of the past 25 years. Our study shows a high number of solution proposals, experience reports, and secondary studies, but only few theories. In particular, standard SPI models are analyzed and evaluated for applicability...

  20. Digital signal processing laboratory

    CERN Document Server

    Kumar, B Preetham


    INTRODUCTION TO DIGITAL SIGNAL PROCESSING Brief Theory of DSP ConceptsProblem SolvingComputer Laboratory: Introduction to MATLAB®/SIMULINK®Hardware Laboratory: Working with Oscilloscopes, Spectrum Analyzers, Signal SourcesDigital Signal Processors (DSPs)ReferencesDISCRETE-TIME LTI SIGNALS AND SYSTEMS Brief Theory of Discrete-Time Signals and SystemsProblem SolvingComputer Laboratory: Simulation of Continuous Time and Discrete-Time Signals and Systems ReferencesTIME AND FREQUENCY ANALYSIS OF COMMUNICATION SIGNALS Brief Theory of Discrete-Time Fourier Transform (DTFT), Discrete Fourier Transform

  1. Computers and data processing

    CERN Document Server

    Deitel, Harvey M


    Computers and Data Processing provides information pertinent to the advances in the computer field. This book covers a variety of topics, including the computer hardware, computer programs or software, and computer applications systems.Organized into five parts encompassing 19 chapters, this book begins with an overview of some of the fundamental computing concepts. This text then explores the evolution of modern computing systems from the earliest mechanical calculating devices to microchips. Other chapters consider how computers present their results and explain the storage and retrieval of

  2. Multivariate Statistical Process Control Process Monitoring Methods and Applications

    CERN Document Server

    Ge, Zhiqiang


      Given their key position in the process control industry, process monitoring techniques have been extensively investigated by industrial practitioners and academic control researchers. Multivariate statistical process control (MSPC) is one of the most popular data-based methods for process monitoring and is widely used in various industrial areas. Effective routines for process monitoring can help operators run industrial processes efficiently at the same time as maintaining high product quality. Multivariate Statistical Process Control reviews the developments and improvements that have been made to MSPC over the last decade, and goes on to propose a series of new MSPC-based approaches for complex process monitoring. These new methods are demonstrated in several case studies from the chemical, biological, and semiconductor industrial areas.   Control and process engineers, and academic researchers in the process monitoring, process control and fault detection and isolation (FDI) disciplines will be inter...

  3. Dynamic control of remelting processes

    Energy Technology Data Exchange (ETDEWEB)

    Bertram, Lee A. (Dublin, CA); Williamson, Rodney L. (Albuquerque, NM); Melgaard, David K. (Albuquerque, NM); Beaman, Joseph J. (Austin, TX); Evans, David G. (Clinton, NY)


    An apparatus and method of controlling a remelting process by providing measured process variable values to a process controller; estimating process variable values using a process model of a remelting process; and outputting estimated process variable values from the process controller. Feedback and feedforward control devices receive the estimated process variable values and adjust inputs to the remelting process. Electrode weight, electrode mass, electrode gap, process current, process voltage, electrode position, electrode temperature, electrode thermal boundary layer thickness, electrode velocity, electrode acceleration, slag temperature, melting efficiency, cooling water temperature, cooling water flow rate, crucible temperature profile, slag skin temperature, and/or drip short events are employed, as are parameters representing physical constraints of electroslag remelting or vacuum arc remelting, as applicable.

  4. Oxytocin and emotion processing. (United States)

    Di Simplicio, Martina; Harmer, Catherine J


    Since the observation that oxytocin has key effects on social decision making, research on this exciting neuropeptide has doubled in volume: hundreds of studies have pursued the promise of a specific oxytocin action on high-level cognition and social function with wide potential translational implications (from autism to social anxiety to dementia). Here we review the evidence on whether the complex behavioural effects observed in humans after exogenous oxytocin administration build on changes in basic emotional information processing, in particular emotional facial expressions recognition, and attention and memory for emotionally-valenced stimuli.We observe that recent studies confirm a facilitatory effect of oxytocin to more accurate emotion processing, irrespective of emotion type. However, it remains unclear whether this action precedes, is independent of or even secondary to the neuropeptide promoting a greater salience of social stimuli. Overall, this growing research area has shown that oxytocin produces behavioural and neurofunctional outcomes that are highly dependent on the experimental context and on individual differences (gender, personality, life experiences). This poses an exciting challenge for future experimental medicine designs to address and unpack complex interactions between individual and context characteristic, which is needed for the development of more precise clinical applications. © The Author(s) 2016.

  5. Understanding the Budget Process

    Directory of Open Access Journals (Sweden)

    Mesut Yalvaç


    Full Text Available Many different budgeting techniques can be used in libraries, and some combination of these will be appropriate for almost any individual situation. Li-ne-item, program, performance, formula, variable, and zero-base budgets all have features that may prove beneficial in the preparation of a budget. Budgets also serve a variety of functions, providing for short-term and long-term financial planning as well as for cash management over a period of time. Short-term plans are reflected in the operating budget, while long-term plans are reflected in the capital budget. Since the time when cash is available to an organization does not usually coincide with the time that disbursements must be made, it is also important to carefully plan for the inflow and outflow of funds by means of a cash budget.      During the budget process an organization selects its programs and activities by providing the necessary funding; the library, along with others in the organization, must justify its requests. Because of the cyclical nature of the budget process, it is possible continually to gather information and evaluate alternatives for the next budget period so that the library may achieve its maximum potential for service to its patrons.

  6. Sustainability of abrasive processes

    DEFF Research Database (Denmark)

    Aurich, J.C.; Linke, B.; Hauschild, Michael Zwicky


    This paper presents an overview of research on sustainability of abrasive processes. It incorporates results from a round robin study on ‘‘energy-efficiency of abrasive processes’’ which has been carried out within the scientific technical committee ‘‘abrasive processes’’ (STC G) of CIRP, the con......This paper presents an overview of research on sustainability of abrasive processes. It incorporates results from a round robin study on ‘‘energy-efficiency of abrasive processes’’ which has been carried out within the scientific technical committee ‘‘abrasive processes’’ (STC G) of CIRP......, the content of technical presentations in STC G, and the results of a comprehensive literature study. The approach to sustainability includes environmental, social, and economic sustainability in accordance with the definition proposed in the Brundtland Report of the United Nations [156]. The main focus...... is on environmental and social sustainability. Economic sustainability will be considered as manufacturing productivity. © 2013 CIRP....

  7. ARM Mentor Selection Process

    Energy Technology Data Exchange (ETDEWEB)

    Sisterson, D. L. [Argonne National Lab. (ANL), Argonne, IL (United States)


    The Atmospheric Radiation Measurement (ARM) Program was created in 1989 with funding from the U.S. Department of Energy (DOE) to develop several highly instrumented ground stations to study cloud formation processes and their influence on radiative transfer. In 2003, the ARM Program became a national scientific user facility, known as the ARM Climate Research Facility. This scientific infrastructure provides for fixed sites, mobile facilities, an aerial facility, and a data archive available for use by scientists worldwide through the ARM Climate Research Facility—a scientific user facility. The ARM Climate Research Facility currently operates more than 300 instrument systems that provide ground-based observations of the atmospheric column. To keep ARM at the forefront of climate observations, the ARM infrastructure depends heavily on instrument scientists and engineers, also known as lead mentors. Lead mentors must have an excellent understanding of in situ and remote-sensing instrumentation theory and operation and have comprehensive knowledge of critical scale-dependent atmospheric processes. They must also possess the technical and analytical skills to develop new data retrievals that provide innovative approaches for creating research-quality data sets. The ARM Climate Research Facility is seeking the best overall qualified candidate who can fulfill lead mentor requirements in a timely manner.

  8. The anaerobic digestion process

    Energy Technology Data Exchange (ETDEWEB)

    Rivard, C.J. [National Renewable Energy Lab., Golden, CO (United States); Boone, D.R. [Oregon Graduate Inst., Portland, OR (United States)


    The microbial process of converting organic matter into methane and carbon dioxide is so complex that anaerobic digesters have long been treated as {open_quotes}black boxes.{close_quotes} Research into this process during the past few decades has gradually unraveled this complexity, but many questions remain. The major biochemical reactions for forming methane by methanogens are largely understood, and evolutionary studies indicate that these microbes are as different from bacteria as they are from plants and animals. In anaerobic digesters, methanogens are at the terminus of a metabolic web, in which the reactions of myriads of other microbes produce a very limited range of compounds - mainly acetate, hydrogen, and formate - on which the methanogens grow and from which they form methane. {open_quotes}Interspecies hydrogen-transfer{close_quotes} and {open_quotes}interspecies formate-transfer{close_quotes} are major mechanisms by which methanogens obtain their substrates and by which volatile fatty acids are degraded. Present understanding of these reactions and other complex interactions among the bacteria involved in anaerobic digestion is only now to the point where anaerobic digesters need no longer be treated as black boxes.

  9. Incremental Forming Process

    Directory of Open Access Journals (Sweden)

    Adrian Blaga


    Full Text Available This paper comprises an experimental study for a complex geometry part obtained by incremental forming. Due to the process complexity (the presence of forces on three directions—a vertical one and two in the blank's plane, a three axes CNC milling machine, capable of describing the complex paths covered by the punch for obtaining the truncated cone-shaped parts, has been chosen. To obtain a truncated cone, three different trajectories were selected: in first and second variants after each vertical press having a constant step, the punch covers a circular path. The differences show that the following circular trajectory can start at the same point or can be shifted at an angle of 90° from the previous press point. In the last variant, the punch performs a spatial spiral trajectory. The main objective of our study was to determine the optimal forming strategy, by shifting the press position of the punch and the path it follows to obtain a truncated cone through single point incremental forming. Thus, the strain distribution can be homogeneous, and the thickness reduction and the process forces are minimal.

  10. Multidimensional diffusion processes

    CERN Document Server

    Stroock, Daniel W


    From the reviews: "… Both the Markov-process approach and the Itô approach … have been immensely successful in diffusion theory. The Stroock-Varadhan book, developed from the historic 1969 papers by its authors, presents the martingale-problem approach as a more powerful - and, in certain regards, more intrinsic-means of studying the foundations of the subject. […] … the authors make the uncompromising decision not "to proselytise by intimidating the reader with myriad examples demonstrating the full scope of the techniques", but rather to persuade the reader "with a careful treatment of just one problem to which they apply". […] Most of the main tools of stochastic-processes theory are used, ..but it is the formidable combination of probability theory with analysis … which is the core of the work. […] I have emphasized the great importance of the Stroock-Varadhan book. It contains a lot more than I have indicated; in particular, its many exercises conain much interesting material. For immediat...

  11. Sensor array signal processing

    CERN Document Server

    Naidu, Prabhakar S


    Chapter One: An Overview of Wavefields 1.1 Types of Wavefields and the Governing Equations 1.2 Wavefield in open space 1.3 Wavefield in bounded space 1.4 Stochastic wavefield 1.5 Multipath propagation 1.6 Propagation through random medium 1.7 ExercisesChapter Two: Sensor Array Systems 2.1 Uniform linear array (ULA) 2.2 Planar array 2.3 Distributed sensor array 2.4 Broadband sensor array 2.5 Source and sensor arrays 2.6 Multi-component sensor array2.7 ExercisesChapter Three: Frequency Wavenumber Processing 3.1 Digital filters in the w-k domain 3.2 Mapping of 1D into 2D filters 3.3 Multichannel Wiener filters 3.4 Wiener filters for ULA and UCA 3.5 Predictive noise cancellation 3.6 Exercises Chapter Four: Source Localization: Frequency Wavenumber Spectrum4.1 Frequency wavenumber spectrum 4.2 Beamformation 4.3 Capon's w-k spectrum 4.4 Maximum entropy w-k spectrum 4.5 Doppler-Azimuth Processing4.6 ExercisesChapter Five: Source Localization: Subspace Methods 5.1 Subspace methods (Narrowband) 5.2 Subspace methods (B...

  12. Grants Process Overview (United States)

    This infographic shows the steps in the National Institutes of Health and National Cancer Institute Grants Process. The graphic shows which steps are done by the Principle Investigator, Grantee Institution, and by NIH. The process is represented by a circular flow of steps. Starting from the top and reading clockwise: The Principle Investigator “Initiates Research Idea and Prepares Application” The Grantee Institution “Submits Application” NIH “NIH Center For Scientific Review, Assigns To NCI And To Study Section” NIH “Scientific Review Group (NCI OR CSR) Evaluates for Scientific Merit” NIH “National Cancer Advisory Board Recommends Action” NIH “NCI Evaluates Program Relevance And Need” NIH “NCI Makes Funding Selections And Issues Grant Awards” (NIH) NIH “NCI Monitors Programmatic and Business Management Performance of the Grant” The Grantee Institution “Manages Funds” The Principle Investigator “Conducts Research” Source: Icons made by Freepik from is licensed by CC BY3.0”

  13. Aquarius Digital Processing Unit (United States)

    Forgione, Joshua; Winkert, George; Dobson, Norman


    Three documents provide information on a digital processing unit (DPU) for the planned Aquarius mission, in which a radiometer aboard a spacecraft orbiting Earth is to measure radiometric temperatures from which data on sea-surface salinity are to be deduced. The DPU is the interface between the radiometer and an instrument-command-and-data system aboard the spacecraft. The DPU cycles the radiometer through a programmable sequence of states, collects and processes all radiometric data, and collects all housekeeping data pertaining to operation of the radiometer. The documents summarize the DPU design, with emphasis on innovative aspects that include mainly the following: a) In the radiometer and the DPU, conversion from analog voltages to digital data is effected by means of asynchronous voltage-to-frequency converters in combination with a frequency-measurement scheme implemented in field-programmable gate arrays (FPGAs). b) A scheme to compensate for aging and changes in the temperature of the DPU in order to provide an overall temperature-measurement accuracy within 0.01 K includes a high-precision, inexpensive DC temperature measurement scheme and a drift-compensation scheme that was used on the Cassini radar system. c) An interface among multiple FPGAs in the DPU guarantees setup and hold times.

  14. Hybrid microcircuit intraconnection processes

    Energy Technology Data Exchange (ETDEWEB)

    Bonham, H.B.


    Hybrid intraconnections join thin film networks and applique components into an electrically functional hybrid microcircuit (HMC). Applique components were intraconnected with thermocompression (TC) bonds to chromium/gold metallized thin film networks. The project determined critical processes, material parameters, quality criteria, and characterization techniques. The program began on July 1, 1970, and initial efforts consisted of organizing the development program and forecasting needed equipment and manpower. The total time schedule was then PERT-charted. Gold beam-lead devices, gold wire, and chromium/gold films had already been selected for these intraconnection technologies. Thermocompression bonding was developed to provide intraconnections between the HMC gold conductor metallization and gold beam-lead active devices, gold plated external leads, and gold terminated applique devices, such as capacitors. An optimum combination of bonding parameters based on the fundamental physics of the process was developed. This philosophy required bonding equipment to be thoroughly characterized so that the value of bonding parameters (such as force and temperature) indicated on the bonder could be translated into measurable values of the force and temperature within the bond zone.

  15. Beryllium Manufacturing Processes

    Energy Technology Data Exchange (ETDEWEB)

    Goldberg, A


    This report is one of a number of reports that will be combined into a handbook on beryllium. Each report covers a specific topic. To-date, the following reports have been published: (1) Consolidation and Grades of Beryllium; (2) Mechanical Properties of Beryllium and the Factors Affecting these Properties; (3) Corrosion and Corrosion Protection of Beryllium; (4) Joining of Beryllium; (5) Atomic, Crystal, Elastic, Thermal, Nuclear, and other Properties of Beryllium; and (6) Beryllium Coating (Deposition) Processes and the Influence of Processing Parameters on Properties and Microstructure. The conventional method of using ingot-cast material is unsuitable for manufacturing a beryllium product. Beryllium is a highly reactive metal with a high melting point, making it susceptible to react with mold-wall materials forming beryllium compounds (BeO, etc.) that become entrapped in the solidified metal. In addition, the grain size is excessively large, being 50 to 100 {micro}m in diameter, while grain sizes of 15 {micro}m or less are required to meet acceptable strength and ductility requirements. Attempts at refining the as-cast-grain size have been unsuccessful. Because of the large grain size and limited slip systems, the casting will invariably crack during a hot-working step, which is an important step in the microstructural-refining process. The high reactivity of beryllium together with its high viscosity (even with substantial superheat) also makes it an unsuitable candidate for precision casting. In order to overcome these problems, alternative methods have been developed for the manufacturing of beryllium. The vast majority of these methods involve the use of beryllium powders. The powders are consolidated under pressure in vacuum at an elevated temperature to produce vacuum hot-pressed (VHP) blocks and vacuum hot-isostatic-pressed (HIP) forms and billets. The blocks (typically cylindrical), which are produced over a wide range of sizes (up to 183 cm dia. by 61

  16. Poultry Slaughtering and Processing Facilities (United States)

    Department of Homeland Security — Agriculture Production Poultry Slaughtering and Processing in the United States This dataset consists of facilities which engage in slaughtering, processing, and/or...

  17. Particle processing technology (United States)

    Yoshio, Sakka


    In recent years, there has been strong demand for the development of novel devices and equipment that support advanced industries including IT/semiconductors, the environment, energy and aerospace along with the achievement of higher efficiency and reduced environmental impact. Many studies have been conducted on the fabrication of innovative inorganic materials with novel individual properties and/or multifunctional properties including electrical, dielectric, thermal, optical, chemical and mechanical properties through the development of particle processing. The fundamental technologies that are key to realizing such materials are (i) the synthesis of nanoparticles with uniform composition and controlled crystallite size, (ii) the arrangement/assembly and controlled dispersion of nanoparticles with controlled particle size, (iii) the precise structural control at all levels from micrometer to nanometer order and (iv) the nanostructural design based on theoretical/experimental studies of the correlation between the local structure and the functions of interest. In particular, it is now understood that the application of an external stimulus, such as magnetic energy, electrical energy and/or stress, to a reaction field is effective in realizing advanced particle processing [1-3]. This special issue comprises 12 papers including three review papers. Among them, seven papers are concerned with phosphor particles, such as silicon, metals, Si3N4-related nitrides, rare-earth oxides, garnet oxides, rare-earth sulfur oxides and rare-earth hydroxides. In these papers, the effects of particle size, morphology, dispersion, surface states, dopant concentration and other factors on the optical properties of phosphor particles and their applications are discussed. These nanoparticles are classified as zero-dimensional materials. Carbon nanotubes (CNT) and graphene are well-known one-dimensional (1D) and two-dimensional (2D) materials, respectively. This special issue also


    Directory of Open Access Journals (Sweden)

    Harjito -


    Full Text Available Telah dilakukan kajian mengenai pengaruh temperatur hidrodesulfurisasi terhadap produk hidrodesulfurisasi tiofen. Penelitian dilakukan untuk mengetahui temperatur optimum hidrodesulfurisasi tiofen dengan katalis Ni-Mo/zeolite alam. Variasi temperatur yang dilakukan adalah 3000C, 3500Cdan 4000C. Katalis Ni-Mo/Zeolit alam dipreparasi secara koimpregnasi. Proses hidrodesulfurisasi dilakukan dengan umpan campuran tiofen-n-heksan dengan komposisi 1:1. Sebagai gas pembawa digunakan gas hydrogen dengan laju alir 25 mL/menit. Hasil hidrodesulfurisasi didinginkan dan dianalisis dengan kromatografi gas. Hasil analisis menunjukkan terjadinya peningkatan jumlah produk dan komponen produk pada setiap kenaikan temperatur 500C. Namun demikian kenaikan jumlah produk pada kenaikan temperatur dari 3500C ke 4000C jika dibandingkan dengan kenaikan produk pada kenaikan temperatur dari 3000C ke 3500C tidak cukup signifikan. Jadi dapat disimpulkan bahwa temperatur hidrodesulfurisasi tiofen terkatalisis Ni-Mo/Zeolit alam adalah 3500C. The study on the effect of temperature on the product tiofen hydrodesulfurization by using Ni/Mo/natural tiofen-n-hexane. The study was done conducted to determine the optimum temperature of  hydrodesulfurization tiofen by using Ni-Mo/ natural zeolite catalyst and the temperature variation was 300oC, 350oC dan 400oC. The Ni-Mo/ natural Zeolit  catalysts were prepared by coimpregnation and hydrodesulfurization process was done by tiofen-n-hexane feed mixture with composition of 1:1, hydrogen gas was used as a carrier gas with a flow rate 25 ml/min. The result of  hydrodesulfurization was cooled and analyzed by gas chromatography  and it revealed an increasing number of products and product components at for each 50°C rising of temperature. However, the increasing of number of products on the temperature rise of  350°C to 400°C was not significant if compared to the increasing of product temperature that increased

  19. Discovering Reference Process Models by Mining Process Variants

    NARCIS (Netherlands)

    Li, C.; Reichert, M.U.; Wombacher, Andreas

    Recently, a new generation of adaptive Process-Aware Information Systems (PAIS) has emerged, which allows for dynamic process and service changes (e.g., to insert, delete, and move activities and service executions in a running process). This, in turn, has led to a large number of process variants

  20. 5 CFR 1653.13 - Processing legal processes. (United States)


    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Processing legal processes. 1653.13 Section 1653.13 Administrative Personnel FEDERAL RETIREMENT THRIFT INVESTMENT BOARD COURT ORDERS AND LEGAL PROCESSES AFFECTING THRIFT SAVINGS PLAN ACCOUNTS Legal Process for the Enforcement of a Participant's Legal...

  1. Business process modeling for processing classified documents using RFID technology

    Directory of Open Access Journals (Sweden)

    Koszela Jarosław


    Full Text Available The article outlines the application of the processing approach to the functional description of the designed IT system supporting the operations of the secret office, which processes classified documents. The article describes the application of the method of incremental modeling of business processes according to the BPMN model to the description of the processes currently implemented (“as is” in a manual manner and target processes (“to be”, using the RFID technology for the purpose of their automation. Additionally, the examples of applying the method of structural and dynamic analysis of the processes (process simulation to verify their correctness and efficiency were presented. The extension of the process analysis method is a possibility of applying the warehouse of processes and process mining methods.

  2. Modeling of biopharmaceutical processes. Part 2: Process chromatography unit operation

    DEFF Research Database (Denmark)

    Kaltenbrunner, Oliver; McCue, Justin; Engel, Philip


    Process modeling can be a useful tool to aid in process development, process optimization, and process scale-up. When modeling a chromatography process, one must first select the appropriate models that describe the mass transfer and adsorption that occurs within the porous adsorbent....... The theoretical understanding of chromatographic behavior can augment available experimental data and aid in the design of specific experiments to develop a more complete understanding of the behavior of a unit operation....

  3. [Signal Processing Suite Design (United States)

    Sahr, John D.; Mir, Hasan; Morabito, Andrew; Grossman, Matthew


    Our role in this project was to participate in the design of the signal processing suite to analyze plasma density measurements on board a small constellation (3 or 4) satellites in Low Earth Orbit. As we are new to space craft experiments, one of the challenges was to simply gain understanding of the quantity of data which would flow from the satellites, and possibly to interact with the design teams in generating optimal sampling patterns. For example, as the fleet of satellites were intended to fly through the same volume of space (displaced slightly in time and space), the bulk plasma structure should be common among the spacecraft. Therefore, an optimal, limited bandwidth data downlink would take advantage of this commonality. Also, motivated by techniques in ionospheric radar, we hoped to investigate the possibility of employing aperiodic sampling in order to gain access to a wider spatial spectrum without suffering aliasing in k-space.

  4. Field Geology/Processes (United States)

    Allen, Carlton; Jakes, Petr; Jaumann, Ralf; Marshall, John; Moses, Stewart; Ryder, Graham; Saunders, Stephen; Singer, Robert


    The field geology/process group examined the basic operations of a terrestrial field geologist and the manner in which these operations could be transferred to a planetary lander. Four basic requirements for robotic field geology were determined: geologic content; surface vision; mobility; and manipulation. Geologic content requires a combination of orbital and descent imaging. Surface vision requirements include range, resolution, stereo, and multispectral imaging. The minimum mobility for useful field geology depends on the scale of orbital imagery. Manipulation requirements include exposing unweathered surfaces, screening samples, and bringing samples in contact with analytical instruments. To support these requirements, several advanced capabilities for future development are recommended. Capabilities include near-infrared reflectance spectroscopy, hyper-spectral imaging, multispectral microscopy, artificial intelligence in support of imaging, x ray diffraction, x ray fluorescence, and rock chipping.

  5. Supplier Evaluation Processes

    DEFF Research Database (Denmark)

    Hald, Kim Sundtoft; Ellegaard, Chris


    Purpose – The purpose of this paper is to illuminate how supplier evaluation practices are linked to supplier performance improvements. Specifically, the paper investigates how performance information travelling between the evaluating buyer and the evaluated suppliers is shaped and reshaped...... in the evaluation process. Design/methodology/approach – The paper relies on a multiple, longitudinal case research methodology. The two cases show two companies' efforts in designing, implementing, and using supplier evaluation in order to improve supplier performance. Findings – The findings show how the dynamics...... of representing, reducing, amplifying, dampening, and directing shape and reshape supplier evaluation information. In both companies, evaluation practices were defined, redefined, and re-directed by the involved actors' perception and decision making, as well as organisational structures, IT systems...

  6. Advanced powder processing

    Energy Technology Data Exchange (ETDEWEB)

    Janney, M.A. [Oak Ridge National Lab., TN (United States)


    Gelcasting is an advanced powder forming process. It is most commonly used to form ceramic or metal powders into complex, near-net shapes. Turbine rotors, gears, nozzles, and crucibles have been successfully gelcast in silicon nitride, alumina, nickel-based superalloy, and several steels. Gelcasting can also be used to make blanks that can be green machined to near-net shape and then high fired. Green machining has been successfully applied to both ceramic and metal gelcast blanks. Recently, the authors have used gelcasting to make tooling for metal casting applications. Most of the work has centered on H13 tool steel. They have demonstrated an ability to gelcast and sinter H13 to near net shape for metal casting tooling. Also, blanks of H13 have been cast, green machined into complex shape, and fired. Issues associated with forming, binder burnout, and sintering are addressed.

  7. Process and plant safety

    CERN Document Server

    Hauptmanns, Ulrich


    Accidents in technical installations are random events. Hence they cannot be totally avoided. Only the probability of their occurrence may be reduced and their consequences be mitigated. The book proceeds from hazards caused by materials and process conditions to indicating technical and organizational measures for achieving the objectives of reduction and mitigation. Qualitative methods for identifying weaknesses of design and increasing safety as well as models for assessing accident consequences are presented. The quantitative assessment of the effectiveness of safety measures is explained. The treatment of uncertainties plays a role there. They stem from the random character of the accident and from lacks of knowledge on some of the phenomena to be addressed. The reader is acquainted with the simulation of accidents, safety and risk analyses and learns how to judge the potential and limitations of mathematical modelling. Risk analysis is applied amongst others to “functional safety” and the determinat...

  8. Welding processes handbook

    CERN Document Server

    Weman, Klas


    Offers an introduction to the range of available welding technologies. This title includes chapters on individual techniques that cover principles, equipment, consumables and key quality issues. It includes material on such topics as the basics of electricity in welding, arc physics, and distortion, and the weldability of particular metals.$bThe first edition of Welding processes handbook established itself as a standard introduction and guide to the main welding technologies and their applications. This new edition has been substantially revised and extended to reflect the latest developments. After an initial introduction, the book first reviews gas welding before discussing the fundamentals of arc welding, including arc physics and power sources. It then discusses the range of arc welding techniques including TIG, plasma, MIG/MAG, MMA and submerged arc welding. Further chapters cover a range of other important welding technologies such as resistance and laser welding, as well as the use of welding techniqu...

  9. Forward Osmosis Process

    KAUST Repository

    Duan, Jintang


    A process that can alleviate the internal concentration polarization and can enhance membrane performance of a forward osmosis system includes the steps of passing a fluid in a forward osmosis system from a feed solution with a first osmotic pressure, through a membrane into a draw solution comprising a draw solute with a second osmotic pressure, where the first osmotic pressure is lower than the second osmotic pressure, the membrane includes an active layer and a support layer, and the membrane is oriented such that the active layer of the membrane faces a draw side, and the support layer faces a feed side; and applying an external force to the fluid on the feed side of the membrane.

  10. Epoxidation catalyst and process (United States)

    Linic, Suljo; Christopher, Phillip


    Disclosed herein is a catalytic method of converting alkenes to epoxides. This method generally includes reacting alkenes with oxygen in the presence of a specific silver catalyst under conditions suitable to produce a yield of the epoxides. The specific silver catalyst is a silver nanocrystal having a plurality of surface planes, a substantial portion of which is defined by Miller indices of (100). The reaction is performed by charging a suitable reactor with this silver catalyst and then feeding the reactants to the reactor under conditions to carry out the reaction. The reaction may be performed in batch, or as a continuous process that employs a recycle of any unreacted alkenes. The specific silver catalyst has unexpectedly high selectivity for epoxide products. Consequently, this general method (and its various embodiments) will result in extraordinarily high epoxide yields heretofore unattainable.

  11. Business Process Outsourcing

    Directory of Open Access Journals (Sweden)

    Doina FOTACHE


    Full Text Available Business Process Outsourcing (BPO is gaining widespread acceptance throughout the US, Europe, South America and Asia Pacific as the top executives of leading multinationals turn to outsourcing as a strategic management tool for improving corporate performance, profitability and shareholder value. BPO started to emerge a few years ago as follow-on to IT outsourcing. The concept is not new; BPO is the contracting of a specific business task. Outsourcing focuses on adding value typically to non-core and non-complex activities by buying in best practices and economies of scale. Because reduce costs, focus on core strategic activities and improve customer service, an increasing number of organizations in both the public and the private sector are looking toward BPO as a solution to their needs.

  12. Catalyst Alloys Processing (United States)

    Tan, Xincai


    Catalysts are one of the key materials used for diamond formation at high pressures. Several such catalyst products have been developed and applied in China and around the world. The catalyst alloy most widely used in China is Ni70Mn25Co5 developed at Changsha Research Institute of Mining and Metallurgy. In this article, detailed techniques for manufacturing such a typical catalyst alloy will be reviewed. The characteristics of the alloy will be described. Detailed processing of the alloy will be presented, including remelting and casting, hot rolling, annealing, surface treatment, cold rolling, blanking, finishing, packaging, and waste treatment. An example use of the catalyst alloy will also be given. Industrial experience shows that for the catalyst alloy products, a vacuum induction remelt furnace can be used for remelting, a metal mold can be used for casting, hot and cold rolling can be used for forming, and acid pickling can be used for metal surface cleaning.

  13. Foam process models.

    Energy Technology Data Exchange (ETDEWEB)

    Moffat, Harry K.; Noble, David R.; Baer, Thomas A. (Procter & Gamble Co., West Chester, OH); Adolf, Douglas Brian; Rao, Rekha Ranjana; Mondy, Lisa Ann


    In this report, we summarize our work on developing a production level foam processing computational model suitable for predicting the self-expansion of foam in complex geometries. The model is based on a finite element representation of the equations of motion, with the movement of the free surface represented using the level set method, and has been implemented in SIERRA/ARIA. An empirically based time- and temperature-dependent density model is used to encapsulate the complex physics of foam nucleation and growth in a numerically tractable model. The change in density with time is at the heart of the foam self-expansion as it creates the motion of the foam. This continuum-level model uses an homogenized description of foam, which does not include the gas explicitly. Results from the model are compared to temperature-instrumented flow visualization experiments giving the location of the foam front as a function of time for our EFAR model system.

  14. Perception and information processing

    DEFF Research Database (Denmark)

    Scholderer, Joachim


    Consumer researchers are interested in the responses of people to commercial stimuli. Usually, these stimuli are products and services, including all attributes, issues, persons, communications, situations, and behaviours related to them. Perception is the first bottleneck in this process...... information and to characterise the operations they perform. To avoid confusion, it should be stressed that the term "perception" is often used in a colloquial sense in consumer research. In concepts like perceived quality, perceived value, or perceived risk, the modifier "perceived" simply highlights...... the subjective nature of these phenomena. However, many of these phenomena are the result of rather complex evaluative judgments and should therefore be regarded as attitudes, not as perceptions in a narrow sense. In this chapter, the term perception will be used in its narrow sense, referring to the selection...

  15. Time processing in dyscalculia. (United States)

    Cappelletti, Marinella; Freeman, Elliot D; Butterworth, Brian L


    To test whether atypical number development may affect other types of quantity processing, we investigated temporal discrimination in adults with developmental dyscalculia (DD). This also allowed us to test whether number and time may be sub-served by a common quantity system or decision mechanisms: if they do, both should be impaired in dyscalculia, but if number and time are distinct they should dissociate. Participants judged which of two successively presented horizontal lines was longer in duration, the first line being preceded by either a small or a large number prime ("1" or "9") or by a neutral symbol ("#"), or in a third task participants decided which of two Arabic numbers (either "1," "5," "9") lasted longer. Results showed that (i) DD's temporal discriminability was normal as long as numbers were not part of the experimental design, even as task-irrelevant stimuli; however (ii) task-irrelevant numbers dramatically disrupted DD's temporal discriminability the more their salience increased, though the actual magnitude of the numbers had no effect; in contrast (iii) controls' time perception was robust to the presence of numbers but modulated by numerical quantity: therefore small number primes or numerical stimuli seemed to make durations appear shorter than veridical, but longer for larger numerical prime or numerical stimuli. This study is the first to show spared temporal discrimination - a dimension of continuous quantity - in a population with a congenital number impairment. Our data reinforce the idea of a partially shared quantity system across numerical and temporal dimensions, which supports both dissociations and interactions among dimensions; however, they suggest that impaired number in DD is unlikely to originate from systems initially dedicated to continuous quantity processing like time.

  16. Renewal Processes and Repairable Systems

    NARCIS (Netherlands)


    In this thesis we discuss the following topics: 1. Renewal reward processes The marginal distributions of renewal reward processes and its version, which we call in this thesis instantaneous reward processes, are derived. Our approach is based on the theory of point processes, especially Poisson

  17. Meadow enriched ACP process algebras

    NARCIS (Netherlands)

    Bergstra, J.A.; Middelburg, C.A.


    We introduce the notion of an ACP process algebra. The models of the axiom system ACP are the origin of this notion. ACP process algebras have to do with processes in which no data are involved. We also introduce the notion of a meadow enriched ACP process algebra, which is a simple generalization

  18. Multivariate supOU processes

    DEFF Research Database (Denmark)

    Barndorff-Nielsen, Ole Eiler; Stelzer, Robert


    Univariate superpositions of Ornstein–Uhlenbeck-type processes (OU), called supOU processes, provide a class of continuous time processes capable of exhibiting long memory behavior. This paper introduces multivariate supOU processes and gives conditions for their existence and finiteness of momen...

  19. EDITORIAL: Ultrafast magnetization processes (United States)

    Hillebrands, Burkard


    This Cluster Issue of Journal of Physics D: Applied Physics is devoted to ultrafast magnetization processes. It reports on the scientific yield of the Priority Programme 1133 'Ultrafast Magnetization Processes' which was funded by the Deutsche Forschungsgemeinschaft in the period 2002-2008 in three successive two-year funding periods, supporting research of 17-18 groups in Germany. Now, at the end of this Priority Programme, the members feel that the achievements made in the course of the programme merit communication to the international scientific community in a concerted way. Therefore, each of the projects of the last funding period presents a key result in a published contribution to this Cluster Issue. The purpose of the funding by a Priority Programme is to advance knowledge in an emerging field of research through collaborative networked support over several locations. Priority Programmes are characterized by their enhanced quality of research through the use of new methods and forms of collaboration in emerging fields, by added value through interdisciplinary cooperation, and by networking. The aim of the Priority Programme 1133 'Ultrafast Magnetization Processes' may be well characterized by the call for projects in June 2001 after the programme was approved by the Deutsche Forschungsgemeinschaft: 'The aim of the priority programme is the achievement of a basic understanding of the temporal evolution of fast magnetization processes in magnetically ordered films, multilayers and micro-structured systems. The challenge lies in the advancement of the field of ultrafast magnetization processes into the regime of a few femtoseconds to nanoseconds, a topic not yet well explored. A general aim is to understand the fundamental mechanisms needed for applications in ultrafast magneto-electronic devices. The fundamental topic to be addressed is the response of the magnetization of small structures upon the application of pulsed magnetic fields, laser pulses or

  20. Fluidized bed coal desulfurization (United States)

    Ravindram, M.


    Laboratory scale experiments were conducted on two high volatile bituminous coals in a bench scale batch fluidized bed reactor. Chemical pretreatment and posttreatment of coals were tried as a means of enhancing desulfurization. Sequential chlorination and dechlorination cum hydrodesulfurization under modest conditions relative to the water slurry process were found to result in substantial sulfur reductions of about 80%. Sulfur forms as well as proximate and ultimate analyses of the processed coals are included. These studies indicate that a fluidized bed reactor process has considerable potential for being developed into a simple and economic process for coal desulfurization.