WorldWideScience

Sample records for hydrocracker feedstocks quarterly

  1. New catalysts improves heavy feedstock hydro-cracking

    Energy Technology Data Exchange (ETDEWEB)

    Hoek, A.; Huizinga, T.; Esener, A.A.; Maxwell, I.E.; Stork, W. (Koninklijke/Shell Laboratorium, Amsterdam (NL)); van de Meerakker, F.J. (Shell Internationale Petroleum Maatschappij BV, The Hauge (NL)); Sy, O. (Shell Canada Ltd., Oakville, Ontario (CA))

    1991-04-22

    A new zeolite-Y-based second-stage hydrocracking catalyst, designated S-703, has been developed by Shell. Laboratory testing and commercial use show it has significantly improved performance with respect to gas make and middle-distillate selectivity in processing heavy feedstocks when compared to a Shell catalyst, S-753, developed earlier. Further, the new catalyst exhibits enhanced stability. Extensive laboratory testing of the S-703 catalyst has been carried out under single-stage, stacked- bed, two-stage-flow, and series-flow conditions. Commercial experience with the new catalyst has now been obtained in several units. To date, the commercial results have confirmed the laboratory results in terms of the superior, heavy- feedstock processing performance of the new catalyst in all respects. Because the trend toward heavier feedstocks is expected to continue, it is likely that catalysts such as S- 703 will find increasing applications in hydrocrackers in the future.

  2. Improvement of hydrogen solubility and entrainment in hydrocracker feedstocks. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Kabadi, V.N.

    1997-02-01

    The project consisted of two tasks: (1) development of a thermodynamic model for hydrogen solubility in hydrocarbons and extension of this model to predict solubility of hydrogen in hydrocracker feedstocks at conditions similar to those of hydrocracking operations, and (2) design and construction of a gas solubility apparatus to measure solubility of hydrogen in hydrocarbons and in hydrocracker feedstocks. The theoretical work proposed was fully accomplished by developing a sophisticated model for hydrogen solubility in hydrocarbons and in hydrocracker feedstocks at advanced temperatures and pressures. The proposed experimental work ran into a number of obstacles, especially to get the original and newly designed on-line sampling technique to function properly. A number of calibrations and tests for reproducibility were necessary to assure the accuracy of measured data. Although a very well designed gas solubility apparatus was built, not much time was left to generate significant hydrogen solubility data. The plans are to use the apparatus in future to measure hydrogen solubility data in liquid fuels to facilitate more efficient design of fuel conversion systems.

  3. Hydrocracking of waste chicken fat as a cost effective feedstock for renewable fuel production: A kinetic study

    Directory of Open Access Journals (Sweden)

    Samia A. Hanafi

    2016-12-01

    Full Text Available In this study, low cost waste chicken fat (WCF feedstock was used for fuel-like hydrocarbon production. The effects of varying reaction parameters on the hydrocracking of waste chicken fat using NiW/SiO2–Al2O3 catalyst were investigated. The reactions were carried out in a fixed bed down flow reactor at reaction temperatures of 400–450 °C, liquid hourly space velocity (LHSV of 1, 2, 4 h−1, H2/oil molar ratio of 450 v/v and hydrogen pressures of 6.0 MPa. The effects on hydrocracking conversion and distribution of products were investigated. The liquid product was analyzed using gas chromatography (GC to quantify n-alkanes. Hydrocracking conversion and organic liquid products (OLPs were evaluated by ASTM D-2887 distillation. The results showed that the catalytic hydrocracking of WCF generates fuels that have chemical and physical properties comparable to those specified for petroleum-based fuels. The amount of kerosene/diesel fractional product decreased with an increase in the temperature and a decrease in the LHSV; while gasoline like petroleum fuel increased. A considerable elimination of O2 from chicken waste fat molecules has been indicated by FTIR analysis. The oxygen removal pathway of WCF over NiW/SiO2–Al2O3 catalyst is primarily carried out by hydro-deoxygenation. The reaction was found to follow the second order mechanism, and the estimated activation energy Ea was 96 kJ mol−1. The exploited catalyst was employed in another run where the results showed the catalyst stability and can be used for several times.

  4. Application of Hydrocracking Process for Upgrading Tail Oil Quality in 1.0 Mt/a Hydrocracker Unit at SINOPEC Yangzi Petrochemical Company

    Institute of Scientific and Technical Information of China (English)

    Zhang Haichun; Dong Jianwei

    2009-01-01

    This article focuses on the hydrocracking technology for upgrading the quality of tail oil and the first commercial application of the RN-32V/RHC-1 catalysts in the 1.0 Mt/a hydrocracker at the Yangzi Petrochemical Company, which was started up successfully in September 2008. One month after start-up of the hydrocracking unit, an evaluation opera-tion has been conducted for assessing the catalysts performance. The technical calibration results showed that the RN-32V/RHC-1 catalysts had high activity, and the product yield distribution was reasonable. The hydrocracker can provide abundant feedstocks for the downstream aromatic production unit and ethylene production unit.

  5. Preparation and Commercial Application of ZHC-01 Hydrocracking Catalyst

    Institute of Scientific and Technical Information of China (English)

    Xu Xuejun; Liu Dongxiang; Wang Haitao; Feng Xiaoping; Wang Jifeng

    2007-01-01

    The ZHC-01 hydrocracking catalyst,characterized by high hydrogenation activity,good selectivity for middle distillates,strong resistance to nitrogen poisoning,was prepared by co-gelling.The catalyst is not only suited to the single-stage hydrocracking process,but also to the first stage of serial hydrocracking process.In parallel with the fully loaded operation of the 1.4 Mt/a hydrocracking unit at the SINOPEC Qilu Petrochemical Company,a pilot test of the ZHC-01 catalyst was also carried out on the hydrocracking unit.The test results indicated that the activity,the yield of major target products and quality of the ZHC-01 catalyst could comply with the design requirements for the hydrocracking unit,and this catalyst could be applied in the hydrocracking unit.The commercial test results showed that the ZHC-01 catalyst,featuring good activity,stability,and flexibility in production,not only could meet the demand for producing environmentally friendly middle distillates,but could also increase the resource of optimized steam cracking feedstock.

  6. Hydrocracking of vacuum gas oil-vegetable oil mixtures for biofuels production.

    Science.gov (United States)

    Bezergianni, Stella; Kalogianni, Aggeliki; Vasalos, Iacovos A

    2009-06-01

    Hydrocracking of vacuum gas oil (VGO)--vegetable oil mixtures is a prominent process for the production of biofuels. In this work both pre-hydrotreated and non-hydrotreated VGO are assessed whether they are suitable fossil components in a VGO-vegetable oil mixture as feed-stocks to a hydrocracking process. This assessment indicates the necessity of a VGO pre-hydrotreated step prior to hydrocracking the VGO-vegetable oil mixture. Moreover, the comparison of two different mixing ratios suggests that higher vegetable oil content favors hydrocracking product yields and qualities. Three commercial catalysts of different activity are utilized in order to identify a range of products that can be produced via a hydrocracking route. Finally, the effect of temperature on hydrocracking VGO-vegetable oil mixtures is studied in terms of conversion and selectivity to diesel, jet/kerosene and naphtha.

  7. New hydrocracking catalysts increase throughput, run length

    Energy Technology Data Exchange (ETDEWEB)

    Huizinga, T. [Shell Internationale Petroleum Mij., The Hague (Netherlands); Theunissen, J.M.H. [Rayong Refinery Co. Ltd., Rayong (Thailand); Minderhoud, H.; Veen, R. van [Koninklijke/Shell-Lab., Amsterdam (Netherlands)

    1995-06-26

    An improved, second-stage hydrocracking catalyst has been developed by combining stabilized Y zeolites with amorphous silica alumina cracking components. A commercial application of this catalyst, along with a new, first-stage zeolitic hydrocracking catalyst, resulted in increased unit throughput and cycle length. The paper discusses the hydrocracking process, first-stage catalysts, second-stage catalysts, hydrogenation process, commercial results, and product properties.

  8. Effect of catalyst deactivation on vacuum residue hydrocracking

    Directory of Open Access Journals (Sweden)

    Hoda S. Ahmed

    2013-12-01

    Full Text Available Accelerated deactivation tests of the pre-sulfided Mo–W/SiO2–Al2O3 commercial catalyst were performed using heavy vacuum petroleum feedstock. High reaction temperature employed in the accelerated catalyst aging resulted in large amounts of carbonaceous deposition with high aromaticity, which was found to be the principal deactivation cause. The effect of catalyst deactivation on hydrocracking of vacuum residue was studied. Experiments were carried out in a batch reactor at 60 bar, feed to catalyst ratio 10:1 and temperature 425 °C. The duration time for a cycle-run was 4 h. On increasing the interval duration times from 4 to 20 h (i.e. five cycles, the quality of the hydrocracked products was decreased. In each cycle-run, a fresh feedstock was used with the same sulfide catalyst. The quality of distillate products, such as hydrodesulfurization (HDS was decreased from 61.50% to 39.52%, while asphaltene contents of the total liquid product were increased from 2.7% to 5.2% and their boiling ranges were increased during these duration times due to the successive catalyst deactivation during the 5 cycle-runs, caused by successive adsorption of coke formation.

  9. Markets for Canadian bitumen-based feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Lauerman, V. [Canadian Energy Research Inst., Calgary, AB (Canada)

    2001-07-01

    The best types of refineries for processing western Canadian bitumen-based feedstock (BBF) were identified and a potential market for these feedstock for year 2007 was calculated. In addition, this power point presentation provided an estimation of potential regional and total demand for BBF. BBF included Athabasca bitumen blend, de-asphalted blend, coked sour crude oil (SCO), coked sweet SCO, hydrocracked SCO and hydrocracked/aromatic saturated SCO (HAS). Refinery prototypes included light and mixed prototypes for primary cracking units, light and heavy prototypes for primary coking units, as well as no coking, coking severe and residuum prototypes for primary hydrocracking units. The presentation included graphs depicting the natural market for Western Canadian crudes as well as U.S. crude oil production forecasts by PADD districts. It was forecasted that the market for bitumen-based feedstock in 2007 will be tight and that the potential demand for bitumen-based blends would be similar to expected production. It was also forecasted that the potential demand for SCO is not as promising relative to the expected production, unless price discounting or HAS will be available. 11 figs.

  10. Commercial Application of RMC Technology in the 1.5 Mt/a Hydrocracking Unit at Shanghai Petrochemical Company

    Institute of Scientific and Technical Information of China (English)

    Xiong Zhenlin; Wang Yiguan; Zhang Maoying; Lin Baohua; Mao Yichao

    2003-01-01

    The RMC technology developed by RIPP has been applied in a 1.5 Mt/a medium pressure hydrocracking unit at Shanghai Petrochemical Company. The unit was successfully put on stream in September 2002. Calibration of the performance of the commercial unit has shown that the RMC technology has higher hydrogenation activity and selectivity, and high quality product can be obtained under lower reaction temperature. The heavy naphtha with less than 0.5 ppm of sulfur and 58.5 m% potential aromatic content is a good feedstock for catalytic reforming unit. The diesel with less than 0.5 ppm of sulfur, 6.6 m% aromatics and cetane rating of 56 is a high-grade diesel fuel. The hydrocracked tail oil containing more than 14 m% hydrogen and mere 1.7m% aromatics could be used as a good feedstock for steam cracking process to produce ethylene.

  11. Hydroisomerization and hydrocracking of hydrocracker bottom for producing lube base oil

    Energy Technology Data Exchange (ETDEWEB)

    Ling, Hao; Shen, Ben-xian [State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237 (China); Wang, Qiang [Sinopec Maoming Petrochemical Co. Ltd, Maoming, Guangdong 525011 (China)

    2009-04-15

    The reaction of hydrocracker bottom hydroisomerization and hydrocracking was studied in a fixed bed micro reactor over a commercial catalyst. Normal hexadecane was used as model compound to judge the reactivity of the catalyst. Then, hydrocracker bottom was investigated, and the reaction liquid products were collected and distillated into light and heavy fractions for detailed investigation. Hydrocarbon types and carbon number distribution of them were fully analyzed. Results indicate that normal paraffins are easy to be hydroconverted into isoparaffins or small molecules. Isoparaffins and monocycloalkanes have similar hydroisomerization and hydrocracking properties. Fused cycloalkanes are hard to be cracked. Hydroconversion of normal paraffins, isoparaffins and monocycloalkanes dominate the reason of the drop of VI and pour point. (author)

  12. Synthesis and characterization of mesoporous hydrocracking catalysts

    Science.gov (United States)

    Munir, D.; Usman, M. R.

    2016-08-01

    Mesoporous catalysts have shown great prospective for catalytic reactions due to their high surface area that aids better distribution of impregnated metal. They have been found to contain more adsorption sites and controlled pore diameter. Hydrocracking, in the presence of mesoporous catalyst is considered more efficient and higher conversion of larger molecules is observed as compared to the cracking reactions in smaller microporous cavities of traditional zeolites. In the present study, a number of silica-alumina based mesoporous catalysts are synthesized in the laboratory. The concentration and type of surfactants and quantities of silica and alumina sources are the variables studied in the preparation of catalyst supports. The supports prepared are well characterized using SEM, EDX, and N2-BET techniques. Finally, the catalysts are tested in a high pressure autoclave reactor to study the activity and selectivity of the catalysts for the hydrocracking of a model mixture of plastics comprising of LDPE, HDPE, PP, and PS.

  13. Development of Hydrocracking Catalyst to Produce High Quality Clean Middle Distillates

    Institute of Scientific and Technical Information of China (English)

    Zhang Xuejun; Zhang Zhihua

    2004-01-01

    A novel hydrocracking Ni-W binary catalyst was tentatively designed and prepared by means of impregnation on mixed supports of modified Y zeolite and amorphous aluminosilicate. The structure and properties of catalyst were extensively characterized by XRD, NH3-TPD, IR and XRF techniques. The performance of catalyst was evaluated by a 100-ml hydrogenation laboratory test unit with two single-stage fixed-bed reactors connected in series. The characterization results showed that the catalyst has a developed and concentrated mesopores distribution, suitable acid sites and acid strength distribution, and uniform and high dispersion of metal sites. Under a high conversion rate of 73.8% with the >350℃ feedstock, a 98. 1m% of C5+yield and 83.5% of middle distillates selectivity were obtained. The yield of middle distillates boiling between 140℃and 370℃ was 68.70m% and its quality could meet the WWFC category Ⅲ specification. It means that this catalyst could be used to produce more high quality clean middle distillates derived from heavy oil hydrocracking. The potential aromatic content of heavy naphtha from 65℃ to 140℃ was 37.5m%. The BMCI value of >370℃ tail oil was 6.6. The heavy naphtha and tail oil are premium feedstocks for catalytic reforming and steam cracker units.

  14. Kinetic modelling of hydrocracking catalytic reactions by the single events theory; Modelisation cinetique des reactions catalytiques d`hydrocraquage par la theorie des evenements constitutifs

    Energy Technology Data Exchange (ETDEWEB)

    Schweitzer, J.M.

    1998-11-23

    Kinetic modelling of petroleum hydrocracking is particularly difficult given the complexity of the feedstocks. There are two distinct classes of kinetics models: lumped empirical models and detailed molecular models. The productivity of lumped empirical models is generally not very accurate, and the number of kinetic parameters increases rapidly with the number of lumps. A promising new methodology is the use of kinetic modelling based on the single events theory. Due to the molecular approach, a finite and limited number of kinetic parameters can describe the kinetic behaviour of the hydrocracking of heavy feedstock. The parameters are independent of the feedstock. However, the available analytical methods are not able to identify the products on the molecular level. This can be accounted for by means of an posteriori lamping technique, which incorporates the detailed knowledge of the elementary step network. Thus, the lumped kinetic parameters are directly calculated from the fundamental kinetic coefficients and the single event model is reduced to a re-lumped molecular model. Until now, the ability of the method to extrapolate to higher carbon numbers had not been demonstrated. In addition, no study had been published for three phase (gas-liquid-solid) systems and a complex feedstock. The objective of this work is to validate the `single events` method using a paraffinic feedstock. First of all, a series of experiments was conducted on a model compound (hexadecane) in order to estimate the fundamental kinetic parameters for acyclic molecules. To validate the single event approach, these estimated kinetic coefficients were used to simulate hydrocracking of a paraffinic mixture ranging from C11 to C18. The simulation results were then compared to the results obtained from the hydrocracking experiments. The comparison allowed to validate the model for acyclic molecules and to demonstrate that the model is applicable to compounds with higher carbon numbers. (author

  15. Hydrocracking of heavy ends to light hydrocarbons for steam-crackers feed

    Energy Technology Data Exchange (ETDEWEB)

    Cesana, A.; Buzzoni, R. [Eni S.p.A., Research Centre for Non-Conventional Energies, Novara (Italy). Ist. Eni Donegani

    2010-12-30

    Low value aromatic fractions, i.e. heavy pygas and pyrolysis fuel oil from naphtha steamcrackers or heavy distillates and ends from refinery, can be conveniently upgraded as high quality steamcracker feeds by severe hydrocracking treatment at 450 -530 C, 6 MPa H{sub 2} employing Ni-Mo or Zn-Mo on H-USY zeolite as catalysts. The process mainly leads to linear C{sub 2}-C{sub 4} alkanes with a low yield to CH{sub 4}. The robust catalytic system allows upgrading fractions with a high content of sulfur and nitrogen. Catalyst life and industrial feasibility have been assessed by long life runs using genuine industrial feedstocks. (orig.)

  16. Study on molecular modelling of the selectivity of catalysts for heavy petroleum fractions hydrocracking; Etude sur molecule modele des parametres regissant la selectivite des catalyseurs d'hydrocraquage des charges lourdes

    Energy Technology Data Exchange (ETDEWEB)

    Leite, L.

    2000-10-19

    Hydrocracking is a catalytic petroleum refining process that is commonly applied to upgrade the heavier fractions obtained from the distillation of crude oils. Nowadays the European demand for good quality middle distillates (kerosene and gas-oil) is high and one important goal for the refining is to transform selectively feedstocks into middle distillates. To understand how this transformation occurs, studies on model compounds have been investigated. Numerous studies have been devoted to paraffin hydrocracking. However theses molecules do not fully represent heavy petroleum fraction. Taking into account that the trend in the future will be to treat heavier feedstocks containing a large quantity of PNA (Polynuclear Aromatic hydrocarbons), the understanding of their transformation under hydrocracking conditions is a key point. In this study, we studied hydrocracking of phenanthrene over platinum on acid solids catalysts. Our main aim was to compare hydrocracking catalysts in term of catalytic activity and selectivity toward primary products thanks to our model reaction and to correlate these catalytic performances with acid solid properties and especially to rationalize the effects due to the acidity and the porosity of the acid solids. Catalytic experiments emphasised an effect of the porous structure on the selectivities. The acidity of the catalysts seemed to impose the catalytic activity but did not permit to explain the selectivities. This 'effect of the structure' has been clarified with the simulation of intermediate products adsorption and diffusion in the studied structures thanks to a molecular modelling study. Indeed, the selectivities obtained during phenanthrene hydrocracking have been linked up with the intermediate products adsorption energies in the structures. The results of this study permit to propose that the key-step for selectivities determination is the physical desorption of the primary products. (author)

  17. Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly report, April 1-June 30, 1980. [Pt/Pd

    Energy Technology Data Exchange (ETDEWEB)

    Yarrington, R M; Feins, I R; Hwang, H S

    1980-07-01

    Phase II of the contract, which involved catalyst preparation and evaluation, was nearly completed this quarter. Phase III, which calls for the design and construction of a fuel processor, was started. During the quarter, four types of tests were run on the small scale catalyst screening unit. The operating line for coke-free operations was found to be approximately between 0.41 to 0.44 O/sub 2//C level. Screening at lower O/sub 2//C levels led to problems with plugging. In other tests, increased severity for screening steam reforming catalysts was obtained by doubling the space velocity. Another series of tests were run to determine the gas composition from the catalytic partial oxidation (CPO) section and to evaluate two CPO catalysts. In the other series of tests, catalysts were aged for about 20 hours using a propane, steam, and air mixture before testing with No. 2 oil for another five hours. This latter test has been used to study Pt/Rh catalysts made with various supports. Differences were readily determined for Pt/Rh supported on alpha alumina and Pt/Rh supported on stabilized alumina. This test method will find continued use in evaluating metal-support interactions. Several samples must be evaluated by this method before aging runs are made in the larger unit. After leaching alumina from a used Pt/Rh catalyst, the x-ray diffraction pattern showed the presence of a Pt-Rh alloy in the metal residue. Experiments were run to show that the alloy was formed in the reactor during testing and not during catalyst preparation. A larger version of the ATR reactor has been designed and major components are on order. Completion of the construction phase is scheduled for the next quarter.

  18. High pressure hydrocracking of vacuum gas oil to middle distillates

    Science.gov (United States)

    Lahiri, C. R.; Biswas, Dipa

    1986-05-01

    Hydrocracking of heavier petroleum fractions into lighter ones is of increasing importance today to meet the huge demand, particularly for gasoline and middle distillates. Much work on hydrocracking of a gas oil range feed stock to mainly gasoline using modified zeolite catalyst-base exchanged with metals (namely Ni, Pd, Mo, etc.) has been reported. In India, however, present demand is for a maximum amount of middle distillate. The present investigation was therefore aimed to maximize the yield of middle distillate (140-270°C boiling range) by hydrocracking a vacuum gas oil (365-450°C boiling range) fraction from an Indian Refinery at high hydrogen pressure and temperature. A zeolite catalyst-base exchanged with 4.5% Ni was chosen for the reaction. A high pressure batch reactor with a rocking arrangement was used for the study. No pretreatment of the feed stock for sulphur removal applied as the total sulphur in the feed was less than 2%. The process variables studied for the maximum yield of the middle distillate were temperature 300-450°C, pressure 100-200 bar and residence period 1-3 h at the feed to catalyst ratio of 9.3 (wt/wt). The optimum conditions for the maximum yield of 36% middle distillate of the product were: temperature 400°C, pressure 34.5 bar (initially) and residence period 2 h. A carbon balance of 90-92% was found for each run.

  19. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

    2009-02-25

    The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using similar methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The "as received" feedstock to the pyrolysis plant will be "reactor ready". This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps: feed

  20. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

    2009-02-28

    The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using the same methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The “as received” feedstock to the pyrolysis plant will be “reactor ready.” This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps

  1. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

    2009-02-28

    The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using the same methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The “as received” feedstock to the pyrolysis plant will be “reactor ready.” This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps

  2. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

    2009-02-25

    The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using similar methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The "as received" feedstock to the pyrolysis plant will be "reactor ready". This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps: feed

  3. Study on Hydrocracking of VGO Derived from Kazakhstan-Russian Mixed Crude

    Institute of Scientific and Technical Information of China (English)

    Dong Yuancheng; Duan Yongsheng; Zou Yhiying; Wang Jian; Ye Xingbin; Yang Jianxin

    2006-01-01

    This article investigates the influence of the property of VGO derived trom the Kazakhstan-Russian mixed crude on the hydrocracking catalyst. The influence of reaction temperature, reaction pressure, space velocity and hydrogen/oil ratio on the distribution and quality of products was analyzed with the optimal process regime determined, when the VGO was hydrocracked in the presence of the FC-16 catalyst.

  4. Lignocellulosic feedstock resource assessment

    Energy Technology Data Exchange (ETDEWEB)

    Rooney, T.

    1998-09-01

    This report provides overall state and national information on the quantity, availability, and costs of current and potential feedstocks for ethanol production in the United States. It characterizes end uses and physical characteristics of feedstocks, and presents relevant information that affects the economic and technical feasibility of ethanol production from these feedstocks. The data can help researchers focus ethanol conversion research efforts on feedstocks that are compatible with the resource base.

  5. Studies on the hydrocracking of deashed oil (5)

    Energy Technology Data Exchange (ETDEWEB)

    Kimura, Takao; Masuyama, Tetsuo; Kageyama, Yoichi; Kawai, Satoshi (Asia Oil Co., Ltd., Tokyo, Japan; Mitsubishi Chemical Industries Ltd., Tokyo (Japan); Nippon Brown Coal Liquefaction Ltd., Tokyo (Japan))

    1987-10-01

    Preliminary sulfiding method of catalyst and the influences DAO (Delimed Ash Oil) exercises on decomposition response activity in the technical development of two-stage hydroliquefaction of Australian brown coal were studied by the TPS (Temperature Programmed Sulfiding) analysis and the X-ray Photoelectron Spectrum (XPS) analysis. The catalyst was Ca-Ni-Mo/Al{sub 2}O{sub 3}. As the gramma value becomes greater, the DAO invert ratio is increased and the coak formation is reduced. The additive Ca fixed to Mo atom by high-dispersion due to the CaMoO{sub 4} structure exists as CaS near the MOS{sub 2} polymer structure by sulfiding. The catalyst which went through structural rearrangement by sulfiding in this way forms a hydrocracking active spot by MoS{sub 2} (Mo-Ni-S structure). Ca interacts with a part of the solid acid spot which is formed accompanied with the formation of a hydrocracking active spot. As a result, the adsorption of the organic nitrogen compound and the polynuclear aromatic compound which are the preceding body of coak is weakened, and the lowering of the initial catalyst activity is suppressed. 4 refs., 4 figs.

  6. The construction of a hydrocracking installation at the Esso refinery in Rotterdam, Netherlands; Part 3. De bouw van een hydrocracker in het Esso raffinaderijcomplex in Rotterdam; Deel 3

    Energy Technology Data Exchange (ETDEWEB)

    Dijkgraaf, A.; Van Klooster, L.

    1993-03-01

    In three brief articles attention is paid to the title subject. The aim of the new hydrocracker is to produce sulfur-lean diesel oil. The first article highlights the composition of the project team, which consists of Esso employees, and the main contractor Fluor Daniels. Also important is to form a multi-disciplinary team of engineers. In the second article attention is paid to the importance of redundancy in the electric system of the hydrocracker. The chance of power supply failures is reduced considerably by means of a triple safety control with an error tolerance, which stops the hydrocracker when two of three meters report an error (Moonlight project). In this article the role of the process engineer in the design is highlighted. 1 fig.

  7. Pillared clays as catalysts for hydrocracking of heavy liquid fuels

    Energy Technology Data Exchange (ETDEWEB)

    Gyftopoulou, M.E.; Bridgwater, A.V. [Bio-Energy Research Group, Chemical Engineering and Applied Chemistry, School of Engineering and Applied Science, Aston University, Birmingham B4 7ET (United Kingdom); Millan, M.; Dugwell, D.; Kandiyoti, R. [Department of Chemical Engineering and Chemical Technology Imperial College London, London SW7 2BY (United Kingdom); Hriljac, J.A. [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

    2005-03-30

    Two sets of pillared clays (PILCs), chromia and tin-oxide-pillared montmorillonites and laponites, were successfully prepared at Aston University using both conventional and microwave-assisted methods and characterised by X-ray diffraction and thermogravimetric analysis. Microwave irradiation enabled the preparation of the PILCs in a fraction of time of the conventional methods. X-ray powder diffraction was not a suitable method for characterizing laponite or pillared laponites due to the lack of first order reflections attributed to the small size of individual particles and the random rather than uniform face-to-face orientation of the clay platelets. Laponite appeared to be more thermally stable than montmorillonite. For pillared montmorillonites, dehydroxylation shifted to a lower temperature compared to the starting materials, whereas for tin-oxide-pillared laponites such a shift did not occur. On the other hand for chromia laponite dehydroxylation took place over a much wider temperature range compared to all other materials. The prepared PILCs were employed as catalysts in the hydrocracking of coal-derived liquids in a conventional microbomb reactor at Imperial College exhibiting high-quality performance and remaining active after 4h utilization regardless of high coke deposition. They actually showed an increase in the total conversion when reused.

  8. 加氢裂化换热器阻垢剂的研制%Research and development of a new fouling inhibitor for heat exchangers in hydrocracking unit

    Institute of Scientific and Technical Information of China (English)

    么佳耀

    2012-01-01

    To solve the problem of gradual decrease of heat transfer efficiency of heat exchangers in hydrocracking unit, a new high-temperature resistant fouling inhibitor RIPP-7051 has been successfully developed through the study of fouling causes and the fouling formation mechanisms in heat exchanger of a hydro-cracking unit. IR spectra has found that the absorption peaks of the fouling from heating of the feedstock are at 3 352 cm-1 and 1 448 cm-1, When the RIPP-7051 fouling inhibitor was injected to the feedstock at a dosage of 200 mg/kg, these peaks almost completely disappeared, and a new peak at 570 cm-1 was observed. This indicates that the fouling may be the polymers containing active hydrogen, and the addition of RIPP-7051 can effectively inhibit their formation. The laboratory static and dynamic analysis of the feedstock with certain amount of fouling inhibitor shows that the fouling inhibition is obvious. The fouling inhibition rate increases with increased fouling inhibitor dosage. The commercial application also proves its good inhibition performance.%为解决加氢裂化装置换热器换热效率下降而影响装置正常运转这一问题,通过对其结垢原因和机理分析,针对性地研制出了一种耐高温阻垢剂RIPP-7051.通过红外光谱测定发现,未注入阻垢剂时原料经加热产生的烷基和芳基的吸收峰主要在3 352和1 448 cm-1处;同样条件下注入阻垢剂200 μg/g,上述吸收峰几乎消失,新产生的吸收峰在570 cm-1附近.说明积垢可能是含有活泼氢的聚合物,阻垢剂的注入抑制了这类物质的生成.对加入一定量的阻垢剂的原油,通过实验室静态和动态评定方法进行实验,均有明显的效果;阻垢效率随着阻垢剂用量的增加而提高.工业实验表明,阻垢效果显著.

  9. Biomass Feedstock National User Facility

    Data.gov (United States)

    Federal Laboratory Consortium — Bioenergy research at the Biomass Feedstock National User Facility (BFNUF) is focused on creating commodity-scale feed-stocks from native biomass that meet the needs...

  10. Uses of red mud based catalytic additives in hydrocracking. Pt. 1. Preparation and basic experiments. Einsatz von katalytischen Zusaetzen auf Rotmassebasis beim Hydrocracking. T. 1. Praeparation und Basisversuche

    Energy Technology Data Exchange (ETDEWEB)

    Sourkouni-Argirusi, G.

    1994-10-01

    This report contains two sections. In the first section a limited review is presented and the preparation of the red mud based additives is described. The additives are characterized by composition and their catalytic activity in hydrocracking is investigated in a batch autoclave under an initial hydrogen pressure of 12 MPa at 435 C and 30 min residence time. A quantitative characterization of the products is given. Comparisons between the red mud additives and coke respectively a commercial catalyst are made. (orig.)

  11. Thermal hydrocracking of indan. Effects of the hydrogen pressure on the kinetics and Arrhenius parameters

    NARCIS (Netherlands)

    Boven, van M.; Roskam, G.J.; Penninger, J.M.L.

    1975-01-01

    The kinetics of the thermal hydrocracking of indan were investigatedin a high-pressure flow reactor at temperatures from 470 to 530°C, total pressures of up to 300 atm, and molar ratios from 3 to 40. The effect of the hydrogen pressure was reflected especially in a change of the experimental rate eq

  12. Thermal hydrocracking of indan. Effects of the hydrogen pressure on the kinetics and Arrhenius parameters

    NARCIS (Netherlands)

    van Boven, M.; Roskam, G.J.; Penninger, J.M.L.

    1975-01-01

    The kinetics of the thermal hydrocracking of indan were investigatedin a high-pressure flow reactor at temperatures from 470 to 530°C, total pressures of up to 300 atm, and molar ratios from 3 to 40. The effect of the hydrogen pressure was reflected especially in a change of the experimental rate

  13. Biodiesel from conventional feedstocks.

    Science.gov (United States)

    Du, Wei; Liu, De-Hua

    2012-01-01

    At present, traditional fossil fuels are used predominantly in China, presenting the country with challenges that include sustainable energy supply, energy efficiency improvement, and reduction of greenhouse gas emissions. In 2007, China issued The Strategic Plan of the Mid-and-Long Term Development of Renewable Energy, which aims to increase the share of clean energy in the country's energy consumption to 15% by 2020 from only 7.5% in 2005. Biodiesel, an important renewable fuel with significant advantages over fossil diesel, has attracted great attention in the USA and European countries. However, biodiesel is still in its infancy in China, although its future is promising. This chapter reviews biodiesel production from conventional feedstocks in the country, including feedstock supply and state of the art technologies for the transesterification reaction through which biodiesel is made, particularly the enzymatic catalytic process developed by Chinese scientists. Finally, the constraints and perspectives for China's biodiesel development are highlighted.

  14. Effect of temperature in hydrocracking of light cycle oil on a noble metal-supported catalyst for fuel production

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez, A.; Arandes, J.M.; Castano, P.; Olazar, M.; Bilbao, J. [Universidad del Pais Vasco (UPV-EHU), Departamento de Ingenieria Quimica, Bilbao (Spain); Barona, A. [Universidad del Pais Vasco (UPV-EHU), Escuela de Ingenieria, Departamento de Ingenieria Quimica y Medio Ambiente, Alda, Urkijo s/n, Bilbao (Spain)

    2012-04-15

    The effect of temperature has been studied in hydrocracking of light cycle oil (LCO), byproduct of fluidized catalytic cracking (FCC) units on a bifunctional catalyst (Pt-Pd/HY zeolite). The increase in both temperature and H{sub 2} partial pressure have an important attenuating effect on catalyst deactivation, given that they decrease sulfur equilibrium adsorption and enhance hydrocracking of coke precursors. Therefore, the catalyst maintains significant hydrodesulfurization and hydrocracking activity. As the temperature is increased, hydrocracking conversion and naphtha selectivity increase, although there is no significant dearomatization of the medium distillate fraction in the range of the studied experimental conditions. 400 C is the more suitable temperature for obtaining a high yield of naphtha with a high content of i-paraffins. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  15. Biohydrogen production from lignocellulosic feedstock.

    Science.gov (United States)

    Cheng, Chieh-Lun; Lo, Yung-Chung; Lee, Kuo-Shing; Lee, Duu-Jong; Lin, Chiu-Yue; Chang, Jo-Shu

    2011-09-01

    Due to the recent energy crisis and rising concern over climate change, the development of clean alternative energy sources is of significant interest. Biohydrogen produced from cellulosic feedstock, such as second generation feedstock (lignocellulosic biomass) and third generation feedstock (carbohydrate-rich microalgae), is a promising candidate as a clean, CO2-neutral, non-polluting and high efficiency energy carrier to meet the future needs. This article reviews state-of-the-art technology on lignocellulosic biohydrogen production in terms of feedstock pretreatment, saccharification strategy, and fermentation technology. Future developments of integrated biohydrogen processes leading to efficient waste reduction, low CO2 emission and high overall hydrogen yield is discussed.

  16. Hydrocracking of ethyl laurate on bifunctional micro-/mesoporous composite materials

    Energy Technology Data Exchange (ETDEWEB)

    Adam, M.; Busse, O.; Reschetilowski, W. [Technische Univ. Dresden (Germany). Inst. for Industrial Chemistry

    2011-07-01

    Hydrocracking of ethyl laurate (dodecanoic acid ethyl ester) as a representative model compound of vegetable oil has been investigated in a fixed bed reactor under integral conditions. A synthesized micro-/mesoporous composite support material Al-MCM-41/ZSM-5 modified by different metal loadings (NiMo, NiW, PtNiW) was used as catalyst system. It could be demonstrated that the metal loading and reducibility influence product selectivity as well as deactivation behavior of catalyst samples. (orig.)

  17. Influence of metal loading on hydrocracking of rapeseed oil using bifunctional micro-/mesoporous composite materials

    Energy Technology Data Exchange (ETDEWEB)

    Gille, T.; Busse, O.; Reschetilowski, W. [Technische Univ. Dresden (Germany). Inst. of Industrial Chemistry

    2013-11-01

    Hydrocracking of rapeseed oil has been investigated in a fixed bed reactor under integral conditions. A synthesized micro-/mesoporous composite material Al-MCM-41/ZSM-5 modified by different metal loadings (NiMo, PtNiMo, Pt) was used as catalyst system. It could be demonstrated that the support material and their metal loading influence the product selectivity as well as the deactivation tendencies of the catalyst sample. (orig.)

  18. Synthesis of Faujasite from Fly Ash and its Applications for Hydrocracking of Petroleum Distillates

    OpenAIRE

    Sutarno Sutarno; Yateman Arryanto

    2007-01-01

    The synthesis of faujasite from fly ash and its application for hydrocracking catalyst of heavy petroleum distillates have been performed. Faujasite was synthesized from fly ash by hydrothermal reaction in alkaline solution via combination of reflux pretreatment of fly ash with HCl and fusion with NaOH. The preparation of nickel containing catalysts by ion exchange method under similar initial concentration of nickel resulted higher amount of nickel loaded on faujasite than those on ze...

  19. Synthesis and Characterization of Ni/Hydrotalcite and Its Application in Hydrocracking Calophyllum Inophyllum Oil

    Directory of Open Access Journals (Sweden)

    Hafshah

    2016-12-01

    Full Text Available This research aims to synthesize hydrotalcite as an alternatives of catalyst support of hydrocracking of vegetable oils. Hydrotalcite can be synthesized in several ways, the most common is coprecipitation method. Hydrotalcite was synthesized using Mg/Al mole ratio of 1: 1, NaOH and Na2CO3 as base solutions. Ni/hydrotalcite catalyst was synthesized by incipicient wetness impregnation method with Ni impregnation of 10% w/w. The characterization of the crystal structure was determined by X-ray diffraction (XRD. The spesific surface area (SBET was determined by adsorption-desorption of nitrogen, it were obtained 201 m2/g after impregnation and 191 m2/g before impregntion. The test of performance of catalyst was conducted by hydrocracking reaction of Calophyllum inophyllum oil. The liquid products were analyzed by gas chromatography mass spectrometry (GC-MS. Hydrocracking process produced gasoline, kerosene, gas oil with yield of 0.36%, 2.45%, 54.88% respectively, conversion of 96.26% and selectivity of gas oil of 84.39%.

  20. The construction of a hydrocracking installation at the Esso refinery in Rotterdam, Netherlands; Part 1 and 2. De bouw van een hydrocracker in het Esso raffinaderijcomplex in Rotterdam; Deel 1 en 2

    Energy Technology Data Exchange (ETDEWEB)

    Dijkgraaf, A.; Van Klooster, L.

    1993-03-01

    In three brief articles attention is paid to the title subject. The aim of the new hydrocracker is to produce sulfur-lean diesel oil. The first article highlights the composition of the project team, which consists of Esso employees, and the main contractor Fluor Daniels. Also important is to form a multi-disciplinary team of engineers. In the second article attention is paid to the importance of redundancy in the electric system of the hydrocracker. The chance of power supply failures is reduced considerably by means of a triple safety control with an error tolerance, which stops the hydrocracker when two of three meters report an error. For the third article a separate abstract has been prepared

  1. Synthesis of Faujasite from Fly Ash and its Applications for Hydrocracking of Petroleum Distillates

    Directory of Open Access Journals (Sweden)

    Sutarno Sutarno

    2007-10-01

    Full Text Available The synthesis of faujasite from fly ash and its application for hydrocracking catalyst of heavy petroleum distillates have been performed. Faujasite was synthesized from fly ash by hydrothermal reaction in alkaline solution via combination of reflux pretreatment of fly ash with HCl and fusion with NaOH. The preparation of nickel containing catalysts by ion exchange method under similar initial concentration of nickel resulted higher amount of nickel loaded on faujasite than those on zeolite Y, however, the structural damage of faujasite was higher than those of zeolite Y. In the hydrocracking of heavy petroleum distillates over Ni-faujasite and Ni-zeolite Y catalysts, the conversion of heavy gas oil fraction was the most pronounced. The selectivity toward hydrocarbons in the range of gasoline and kerosene obtained over Ni-faujasite catalyst was lower compared to those of Ni-zeolite Y reference catalyst. © 2007 BCREC UNDIP. All rights reserved.[Presented at Symposium and Congress of MKICS 2007, 18-19 April 2007, Semarang, Indonesia][How to Cite: S. Sutarno, Y. Arryanto. (2007. Synthesis of Faujasite from Fly Ash and its Applications for Hydrocracking of Petroleum Distillates. Bulletin of Chemical Reaction Engineering and Catalysis, 2 (2-3: 45-51.  doi:10.9767/bcrec.2.2-3.9.45-51][How to Link/DOI: http://dx.doi.org/10.9767/bcrec.2.2-3.9.45-51 || or local:  http://ejournal.undip.ac.id/index.php/bcrec/article/view/9][Cited by: Scopus 1 | ScienceAsia |

  2. Formation of alkanes alkylcycloalkanes and alkylbenzenes during the catalytic hydrocracking of vegetable oils

    Energy Technology Data Exchange (ETDEWEB)

    Filho, G.N. da Rocha; Brodzki, D.; Djega-Mariadassou, G. (Universite Pierre et Marie Curie, Paris (France). Lab. Reactivite de Surface et Structure)

    1993-04-01

    Catalytic hydrocracking of vegetable oils was performed in the presence of a NiMo/[gamma]-Al[sub 2]O[sub 3] catalyst sulfided in situ with elemental sulfur under hydrogen pressure. Various vegetable oils were selected to study the effect of the degree of saturation and lateral chain length: [ital Passiflora edulis] (maracuja), [ital Astrocaryum vulgare] (tucuma), [ital Mauritia flexuosa] (buriti), [ital Orbygnya martiana] (babassu) and soybean. The effects of reaction temperature and hydrogen pressure in cyclization were studied. Carboxylic acids were used as model compounds. 29 refs., 5 figs., 5 tabs.

  3. Simulation of Low-Temperature Coal Tar Hydrocracking in Supercritical Gasoline

    Institute of Scientific and Technical Information of China (English)

    Zhang Lei; Liu Zongkuan; Gu Zhaolin

    2013-01-01

    The aim of this paper was preliminary design of the process for low-temperature coal tar hydrocracking in supercritical gasoline based on Aspen Plus with the concept of energy self-sustainability. In order to ensure the correct-ness and accuracy of the simulation, we did the following tasks: selecting reasonable model compounds for low-tem-perature coal tar; describing the nature of products gasoline and diesel accurately; and conifrming the proper property study method for each block by means of experience and trial. The purpose of energy self-sustainability could be pos-sibly achieved, on one hand, by using hot stream to preheat cold stream and achieving temperature control of streams, and on the other hand, by utilizing gas (byproduct of the coal tar hydrocracking) combustion reaction to provide energy. Results showed that the whole process could provide a positive net power of about 609 kW·h for processing the low-temperature coal tar with a lfowrate of 2 268 kg/h. The total heat recovery amounted to 2 229 kW·h, among which 845 kW·h was obtained from the gas combustion reaction, and 1 116 kW·h was provided by the reactor’s outlet stream, with the rest furnished by hot streams of the products gasoline, diesel and residue. In addition, the process lfow sheet could achieve products separation well, and speciifcally the purity of product gasoline and diesel reached 97.2% and 100%, respectively.

  4. Development of Light Cycle Oil (LCO) Hydrocracking Technology over a Commercial W-Ni Based Catalyst

    Institute of Scientific and Technical Information of China (English)

    Peng Chong; Yang Xuejing; Fang Xiangchen; Huang Xinlu; Cheng Zhenmin; Zeng Ronghui; Guo Rong

    2015-01-01

    Because of its high density and low cetane number, the light cycle oil (LCO) containing heavy aromatics (60%—80%) can hardly be transformed through the conventional hydro-upgrading technology. In this report, a novel LCO hydrocracking technology (FD2G) was proposed for the utilization of LCO to manufacture high value-added products. Through the ingenious combination of hydroprocessing catalyst and the hydrocracking process, the high octane gasoline and the ultra-low sulfur diesel (ULSD) blendstocks were produced simultaneously. The inlfuence of catalyst type, reaction temperature, pressure, respectively, on the research octane number (RON) of produced gasoline was studied in a ifxed bed hydrogenation reactor. It indicated that high reaction temperature and medium pressurewould favor the production of high-octane gasoline through the conversion of bi-aromatic and tri-aromatic hydrocarbons. The typical results of FD2G tech-nology on commercial units showed that it could produce clean diesel with a sulfur content of less than 10 μg/g and clean gasoline with a research octane number (RON) of up to 92. It would be contributed to the achievement of the maximum proift of a reifnery, the FD2G technology could provide a higher economic efifciency than the other diesel quality upgrading technology under the current gasoline and diesel price system.

  5. Comparison of Kinetic-based and Artificial Neural Network Modeling Methods for a Pilot Scale Vacuum Gas Oil Hydrocracking Reactor

    Directory of Open Access Journals (Sweden)

    Sepehr Sadighi

    2013-12-01

    Full Text Available An artificial neural network (ANN and kinetic-based models for a pilot scale vacuum gas oil (VGO hydrocracking plant are presented in this paper. Reported experimental data in the literature were used to develop, train, and check these models. The proposed models are capable of predicting the yield of all main hydrocracking products including dry gas, light naphtha, heavy naphtha, kerosene, diesel, and unconverted VGO (residue. Results showed that kinetic-based and artificial neural models have specific capabilities to predict yield of hydrocracking products. The former is able to accurately predict the yield of lighter products, i.e. light naphtha, heavy naphtha and kerosene. However, ANN model is capable of predicting yields of diesel and residue with higher precision. The comparison shows that the ANN model is superior to the kinetic-base models.  © 2013 BCREC UNDIP. All rights reservedReceived: 9th April 2013; Revised: 13rd August 2013; Accepted: 18th August 2013[How to Cite: Sadighi, S., Zahedi, G.R. (2013. Comparison of Kinetic-based and Artificial Neural Network Modeling Methods for a Pilot Scale Vacuum Gas Oil Hydrocracking Reactor. Bulletin of Chemical Reaction Engineering & Catalysis, 8 (2: 125-136. (doi:10.9767/bcrec.8.2.4722.125-136][Permalink/DOI: http://dx.doi.org/10.9767/bcrec.8.2.4722.125-136

  6. 2009 Feedstocks Platform Review Report

    Energy Technology Data Exchange (ETDEWEB)

    Ferrell, John [Office of Energy Efficiency and Renewable Energy (EERE), Washington, DC (United States)

    2009-12-01

    This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the U.S. Department of Energy Biomass Program‘s Feedstock platform review meeting, held on April 8–10, 2009, at the Grand Hyatt Washington, Washington, D.C.

  7. Survey of alternative feedstocks for biodiesel production

    Science.gov (United States)

    Summarized will be results obtained from the production of biodiesel from several alternative feedstocks with promising agronomic characteristics. Such feedstocks include camelina (Camelina sativa L.), coriander (Coriandrum sativum L.), field pennycress (Thlaspi arvense L.), and meadowfoam (Limnanth...

  8. Hydrocracking of Cerbera manghas Oil with Co-Ni/HZSM-5 as Double Promoted Catalyst

    Directory of Open Access Journals (Sweden)

    Lenny Marlinda

    2017-05-01

    Full Text Available The effect of various reaction temperature on the hydrocracking of Cerbera manghas oil to produce a paraffin-rich mixture of hydrocarbons with Co-Ni/HZSM-5 as doubled promoted catalyst were studied. The Co-Ni/HZSM-5 catalyst with various metal loading and metal ratio was prepared by incipient wetness impregnation. The catalysts were characterized by XRD, AAS, and N2 adsorption-desorption. Surface area, pore diameter, and pore volume of catalysts decreased with the increasing of metals loading. The hydrocracking process was conducted under hydrogen initial pressure in batch reactor equipped with a mechanical stirrer. The reaction was carried out at a temperature of 300-375 oC for 2 h.  Depending on the experimental condition, the reaction pressure changed between 10 bar and 15 bar.   Several parameters were used to evaluate biofuel produced, including oxygen removal, hydrocarbon composition and gasoline/kerosene/diesel yields. Biofuel was analyzed by Fourier Transform Infrared Spectroscopic (FTIR and gas chromatography-mass spectrometry (GC-MS. The composition of hydrocarbon compounds in liquid products was similar to the compounds in the gasoil sold in unit of Pertamina Gas Stations, namely pentadecane, hexadecane, heptadecane, octadecane, and nonadecane with different amounts for each biofuel produced at different reaction temperatures. However, isoparaffin compounds were not formed at all operating conditions. Pentadecane (n-C15 and heptadecane (n-C17 were the most abundant composition in gasoil when Co-Ni/HZSM-5 catalyst was used. Cerbera Manghas oil can be recommended as the source of non-edible vegetable oil to produce gasoil as an environmentally friendly transportation fuel. Copyright © 2017 BCREC Group. All rights reserved Received: 20th May 2016; Revised: 30th January 2017; Accepted: 10th February 2017 How to Cite: Marlinda, L., Al-Muttaqii, M., Gunardi, I., Roesyadi, A., Prajitno, D.H. (2017. Hydrocracking of Cerbera manghas Oil

  9. Cracking and hydrocracking of triglycerides for renewable liquid fuels: alternative processes to transesterification

    Energy Technology Data Exchange (ETDEWEB)

    Frety, Roger; Rocha, Maria da Graca C. da; Brandao, Soraia T., E-mail: frety@unifacs.b [Universidade Federal da Bahia (IQ/UFBA), Salvador, BA (Brazil). Inst. de Quimica; Pontes, Luiz A.M; Padilha, Jose F. [Universidade de Salvador (UNIFACS), BA (Brazil); Borges, Luiz E.P.; Gonzalez, Wilma A. [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil). Secao de Quimica

    2011-07-01

    The most used industrial processes for the production of liquid fuels like diesel type are based on the methanolysis and ethanolysis of various oil reactants, such as palm, soybean and rapeseed oils, in the presence of homogeneous base catalysts. However, thermal and catalytic transformations of vegetable oils using available reactors and industrial processes are possible alternatives and deserve attention. In fact, three industrial processes are operating and new projects are announced. The present work analyses the experimental studies performed up to now by Brazilian researchers in the field of cracking, catalytic cracking and hydrocracking of pure or modified vegetable oils. From the published results, some research areas for the near future are suggested. (author)

  10. Application of Discrete Lumped Kinetic Modeling on Vacuum Gas Oil Hydrocracking

    Institute of Scientific and Technical Information of China (English)

    Han Longnian; Fang Xiangchen; Peng Chong; Zhao Tao

    2013-01-01

    The kinetic model of vacuum gas oil (VGO) hydrocracking based on discrete lumped approach was investigated, and some improvement was put forward at the same time in this article. A parallel reaction scheme to describe the conver-sion of VGO into products (gases, gasoline, and diesel) proposed by Orochko was used. The different experimental data were analyzed statistically and then the product distribution and kinetic parameters were simulated by available data. Fur-thermore, the kinetic parameters were correlated based on the feed property, reaction temperature, and catalyst activity. An optimization code in Matlab 2011b was written to ifne-tune these parameters. The model had a favorable ability to predict the product distribution and there was a good agreement between the model predictions and experiment data. Hence, the ki-netic parameters indeed had something to do with feed properties, reaction temperature and catalyst activity.

  11. Anomalous hydrocracking of triglycerides over CoMo-catalyst-influence of reaction intermediates

    Indian Academy of Sciences (India)

    M Anand; M G Sibi; D Verma; A K Sinha

    2014-03-01

    Reaction intermediates have been identified and followed to understand anomalous cracking of jathropha oil triglycerides in the presence of sulphided Co-Mo/Al2O3 catalyst. Undesirable C-C coupling reactions are favoured at temperatures between 320° and 340°C, giving waxy oligomerization products, whereas at temperatures above 340°C, direct hydrocracking of triglycerides to lighter and middle distillates were favoured. To minimize undesirable waxy oligomerization products, higher pressures (>80 bar) and higher H2/feed ratios (>1500) were necessary. Aldol condensation and ketonization reactions between the reaction intermediates are counter-productive as they result in waxy long chain oxygenated products which tend to accumulate on the catalyst surface, choke the reactor and cause rapid catalyst deactivation. Reaction conditions have to be optimized to minimize condensation reaction during this process.

  12. Synthesis of fuels and feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Sutton, Andrew D.; Brooks, Ty; Jenkins, Rhodri; Moore, Cameron; Staples, Orion

    2017-10-10

    Disclosed herein are embodiments of a method for making fuels and feedstocks from readily available alcohol starting materials. In some embodiments, the method concerns converting alcohols to carbonyl-containing compounds and then condensing such carbonyl-containing compounds together to form oligomerized species. These oligomerized species can then be reduced using by-products from the conversion of the alcohol. In some embodiments, the method further comprises converting saturated, oligomerized, carbonyl-containing compounds to aliphatic fuels.

  13. Engineered plant biomass feedstock particles

    Science.gov (United States)

    Dooley, James H.; Lanning, David N.; Broderick, Thomas F.

    2011-10-11

    A novel class of flowable biomass feedstock particles with unusually large surface areas that can be manufactured in remarkably uniform sizes using low-energy comminution techniques. The feedstock particles are roughly parallelepiped in shape and characterized by a length dimension (L) aligned substantially with the grain direction and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. The particles exhibit a disrupted grain structure with prominent end and surface checks that greatly enhances their skeletal surface area as compared to their envelope surface area. The L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers. The W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers. The L.times.W dimensions define a pair of substantially parallel top surfaces characterized by some surface checking between longitudinally arrayed fibers. The feedstock particles are manufactured from a variety of plant biomass materials including wood, crop residues, plantation grasses, hemp, bagasse, and bamboo.

  14. Engineered plant biomass feedstock particles

    Science.gov (United States)

    Dooley, James H [Federal Way, WA; Lanning, David N [Federal Way, WA; Broderick, Thomas F [Lake Forest Park, WA

    2011-10-18

    A novel class of flowable biomass feedstock particles with unusually large surface areas that can be manufactured in remarkably uniform sizes using low-energy comminution techniques. The feedstock particles are roughly parallelepiped in shape and characterized by a length dimension (L) aligned substantially with the grain direction and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. The particles exhibit a disrupted grain structure with prominent end and surface checks that greatly enhances their skeletal surface area as compared to their envelope surface area. The L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers. The W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers. The L.times.W dimensions define a pair of substantially parallel top surfaces characterized by some surface checking between longitudinally arrayed fibers. At least 80% of the particles pass through a 1/4 inch screen having a 6.3 mm nominal sieve opening but are retained by a No. 10 screen having a 2 mm nominal sieve opening. The feedstock particles are manufactured from a variety of plant biomass materials including wood, crop residues, plantation grasses, hemp, bagasse, and bamboo.

  15. COMPUTATIONAL RESOURCES FOR BIOFUEL FEEDSTOCK SPECIES

    Energy Technology Data Exchange (ETDEWEB)

    Buell, Carol Robin [Michigan State University; Childs, Kevin L [Michigan State University

    2013-05-07

    While current production of ethanol as a biofuel relies on starch and sugar inputs, it is anticipated that sustainable production of ethanol for biofuel use will utilize lignocellulosic feedstocks. Candidate plant species to be used for lignocellulosic ethanol production include a large number of species within the Grass, Pine and Birch plant families. For these biofuel feedstock species, there are variable amounts of genome sequence resources available, ranging from complete genome sequences (e.g. sorghum, poplar) to transcriptome data sets (e.g. switchgrass, pine). These data sets are not only dispersed in location but also disparate in content. It will be essential to leverage and improve these genomic data sets for the improvement of biofuel feedstock production. The objectives of this project were to provide computational tools and resources for data-mining genome sequence/annotation and large-scale functional genomic datasets available for biofuel feedstock species. We have created a Bioenergy Feedstock Genomics Resource that provides a web-based portal or clearing house for genomic data for plant species relevant to biofuel feedstock production. Sequence data from a total of 54 plant species are included in the Bioenergy Feedstock Genomics Resource including model plant species that permit leveraging of knowledge across taxa to biofuel feedstock species.We have generated additional computational analyses of these data, including uniform annotation, to facilitate genomic approaches to improved biofuel feedstock production. These data have been centralized in the publicly available Bioenergy Feedstock Genomics Resource (http://bfgr.plantbiology.msu.edu/).

  16. Catalytic hydrocracking of Kapuk seed oil (Ceiba pentandra) to produce biofuel using Zn-Mo supported HZSM-5 catalyst

    Science.gov (United States)

    Mirzayanti, Y. W.; Prajitno, D. H.; Roesyadi, A.

    2017-05-01

    In the present paper Kapuk seed oil (KSO) was considered as a potential biofuel for alternative fuel from inedible oil. Catalytic hydrocracking of Kapuk seed oil using Zn-Mo supported on the HZSM-5 catalyst in a slurry pressure batch reactor at various temperature with reactor pressure in range 10-15 bar. The Zn-Mo/HZSM-5 catalyst was prepared by incipient wetness impregnation. The physicochemical properties of the catalyst were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) method. The best catalyst performance on catalytic hydrocracking of KSO using Zn-Mo/HZSM-5 (Si/Al = 25) with loading 2.92%wt for Zn and 7.55%wt for Mo. It displayed the highest hydrocarbon content decarboxylation and/or decarbonylation were 35.51 area% of n-paraffins and the highest content for gasoil-range alkanes was 17.24 area% at 4000C. The liquid product predominant is n-C15, and the second component is n-C17. The catalyst Zn-Mo/HZSM-5 was helpful for the catalytic hydrocracking of KSO for hydrocarbon biofuel production.

  17. Feedstock storage, handling and processing

    Energy Technology Data Exchange (ETDEWEB)

    Egg, R.P.; Coble, C.G.; Engler, C.R. (Texas A and M Univ., College Station, TX (United States). Dept. of Agricultural Engineering); Lewis, D.H. (Texas A and M Univ., College Station, TX (United States). Dept. of Veterinary Microbiology and Parasitology)

    1993-01-01

    This paper is a review of the technology and research covering components of a methane from biomass system between the field and the digester. It deals primarily with sorghum as a feedstock and focuses on research conducted by the Texas Agricultural Experiment Station. Subjects included in this paper are harvesting, hay storage, ansiling, materials handling, pumping and hydraulic characteristics, hydraulic conductivity, pressure/density relationship, and biological pretreatment. This paper is not a comprehensive design manual; however, design equations and coefficients for sorghum are presented, where available, along with references describing the development and application of design models. (author)

  18. Conversion of Isoprenoid Oil by Catalytic Cracking and Hydrocracking over Nanoporous Hybrid Catalysts

    Directory of Open Access Journals (Sweden)

    Toshiyuki Kimura

    2012-01-01

    Full Text Available In order to produce petroleum alternatives from biomass, a significant amount of research has been focused on oils from microalgae due to their origin, which would not affect food availability. Nanoporous hybrid catalysts composed of ns Al2O3 and zeolites have been proven to be very useful compared to traditional catalysts in hydrotreating (HT, hydrocracking (HC, and catalytic cracking (CC of large molecules. To evaluate the reaction scheme and products from model isoprenoid compounds of microalgae oil, nanoporous hybrid catalyst technologies (CC: ns Al2O3/H-USY and ns Al2O3/H-GaAlMFI; HC: [Ni-Mo/γ-Al2O3]/ns Al2O3/H-beta were studied. The major product from CC on ns Al2O3/H-USY was highly aromatic gasoline, while the product from HC was half-isoparaffinic/olefinic kerosene. Although more than 50 wt% of the products from HT/CC on the USY catalyst was liquefied petroleum gas due to overcracking, the product from HT/CC on the MFI catalyst was high-octane-number gasoline. Delightfully, the product from HT/HC was kerosene and its average number was 11, with more than 80 wt% being isoparaffinic. As a result, it was demonstrated that hydrotreating may convert isoprenoid oil from microalgae over nanoporous hybrid catalysts into a variety of products.

  19. Conversion of isoprenoid oil by catalytic cracking and hydrocracking over nanoporous hybrid catalysts.

    Science.gov (United States)

    Kimura, Toshiyuki; Liu, Chen; Li, Xiaohong; Maekawa, Takaaki; Asaoka, Sachio

    2012-01-01

    In order to produce petroleum alternatives from biomass, a significant amount of research has been focused on oils from microalgae due to their origin, which would not affect food availability. Nanoporous hybrid catalysts composed of ns Al₂O₃ and zeolites have been proven to be very useful compared to traditional catalysts in hydrotreating (HT), hydrocracking (HC), and catalytic cracking (CC) of large molecules. To evaluate the reaction scheme and products from model isoprenoid compounds of microalgae oil, nanoporous hybrid catalyst technologies (CC: ns Al₂O₃/H-USY and ns Al₂O₃/H-GaAlMFI; HC: [Ni-Mo/γ-Al₂O₃]/ns Al₂O₃/H-beta) were studied. The major product from CC on ns Al₂O₃/H-USY was highly aromatic gasoline, while the product from HC was half-isoparaffinic/olefinic kerosene. Although more than 50 wt% of the products from HT/CC on the USY catalyst was liquefied petroleum gas due to overcracking, the product from HT/CC on the MFI catalyst was high-octane-number gasoline. Delightfully, the product from HT/HC was kerosene and its average number was 11, with more than 80 wt% being isoparaffinic. As a result, it was demonstrated that hydrotreating may convert isoprenoid oil from microalgae over nanoporous hybrid catalysts into a variety of products.

  20. New Feedstock for c-Si Photovoltaics

    Science.gov (United States)

    Kravtsov, Alexey; Shagun, Alexander; Kravtsov, Anatoly

    2015-03-01

    Results from functional tests of highly doped silicon purified with electron beam melting, a new feedstock for photovoltaics are presented. Possibility of obtaining dislocation free single crystals from such feedstock in typical industrial processes (CZ and FZ) is shown, crystals' parameters are tested for coherence with requirements for PV silicon.

  1. Evolution and Development of Effective Feedstock Specifications

    Energy Technology Data Exchange (ETDEWEB)

    Garold Gresham; Rachel Emerson; Amber Hoover; Amber Miller; William Bauer; Kevin Kenney

    2013-09-01

    The U.S. Department of Energy promotes the production of a range of liquid fuels and fuel blend stocks from lignocellulosic biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass collection, conversion, and sustainability. As part of its involvement in this program, the Idaho National Laboratory (INL) investigates the feedstock logistics economics and sustainability of these fuels. The 2012 feedstock logistics milestone demonstrated that for high-yield areas that minimize the transportation distances of a low-density, unstable biomass, we could achieve a delivered cost of $35/ton. Based on current conventional equipment and processes, the 2012 logistics design is able to deliver the volume of biomass needed to fulfill the 2012 Renewable Fuel Standard’s targets for ethanol. However, the Renewable Fuel Standard’s volume targets are continuing to increase and are expected to peak in 2022 at 36 billion gallons. Meeting these volume targets and achieving a national-scale biofuels industry will require expansion of production capacity beyond the 2012 Conventional Feedstock Supply Design Case to access diverse available feedstocks, regardless of their inherent ability to meet preliminary biorefinery quality feedstock specifications. Implementation of quality specifications (specs), as outlined in the 2017 Design Case – “Feedstock Supply System Design and Economics for Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels” (in progress), requires insertion of deliberate, active quality controls into the feedstock supply chain, whereas the 2012 Conventional Design only utilizes passive quality controls.

  2. ACTIVITY TEST AND REGENERATION OF NiMo/Z CATALYST FOR HYDROCRACKING OF WASTE PLASTIC FRACTION TO GASOLINE FRACTION

    Directory of Open Access Journals (Sweden)

    Rodiansono Rodiansono

    2010-06-01

    Full Text Available Activity test and regeneration of NiMo/active natural zeolite catalyst for hydrocracking of waste plastic fraction of polyprophylene (PP type have been carried out. The catalysts was prepared by loading Mo followed by Ni Metals onto the natural zeolite (Z sample, then calcined at 500oC, oxidized and reduced at 400oC under nitrogen, oxygen and hydrogen stream, respectively. The characterization of catalysts including spesific surface area, average pore radius, and total pore volume were performed by gas sorption analyzer, amount of total acid sites was determined by gas sorption method, and acid site strength was confirmed by IR spectroscopy. The hydrocracking process was carried out in a semi-flow reactor system at 360 oC and catalyst:feed ratio 0.5 under hydrogen stream (150 mL/hour. The feed was vaporized from the pyrolisis reactor into the hydrocracking reactor. A liquid product was collected and analyzed by gas chromatography (GC and gas chromatography-mass spectroscopy (GC-MS. The characterization results showed that spesific surface area, average pore radius, and total pore volume of the Z sample decreased after loading of the Ni and Mo metals. Amount of total acid sites of the NiMo/Z catalyst was higher than that of the Z sample. The activity of NiMo/Z catalyst decreased after several continously runs. Its regeneration produced the NiMo/Z reg catalyst with similar activity and selectivity to the fresh catalyst (NiMo/Z. The activity of catalysts at the optimum condition followed the order of NiMo/Z reg>NiMo/Z>Z (conversion of hydrocarbon C>12 and NiMo/Z reg>NiMo/Z>Z (total yield of gasoline fraction. The selectivity of catalysts for C7-C8 product followed the order of Z>NiMo/Z>NiMo/Z reg. Keywords: activity, polyprophylene, catalyst, gasoline fraction.

  3. Engineered plant biomass feedstock particles

    Science.gov (United States)

    Dooley, James H [Federal Way, WA; Lanning, David N [Federal Way, WA; Broderick, Thomas F [Lake Forest Park, WA

    2012-04-17

    A new class of plant biomass feedstock particles characterized by consistent piece size and shape uniformity, high skeletal surface area, and good flow properties. The particles of plant biomass material having fibers aligned in a grain are characterized by a length dimension (L) aligned substantially parallel to the grain and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. In particular, the L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers, the W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers, and the L.times.W dimensions define a pair of substantially parallel top and bottom surfaces. The L.times.W surfaces of particles with L/H dimension ratios of 4:1 or less are further elaborated by surface checking between longitudinally arrayed fibers. The length dimension L is preferably aligned within 30.degree. parallel to the grain, and more preferably within 10.degree. parallel to the grain. The plant biomass material is preferably selected from among wood, agricultural crop residues, plantation grasses, hemp, bagasse, and bamboo.

  4. Sheer加氢裂化技术——第一代Sheer加氢裂化技术开发%Sheer hydrocracking Process——Development of first-generation Sheer hydrocracking technologies

    Institute of Scientific and Technical Information of China (English)

    李立权; 陈崇刚

    2013-01-01

    Sheer加氢裂化技术是一项能量高效利用的综合技术,包括正常操作停运反应加热炉的加氢裂化专利技术、高温高压逆流传热技术、新型反应器内构件技术、微旋流分离技术、非直接接触在线防垢和除垢技术以及硫化态催化剂新型开工技术.第一代Sheer加氢裂化技术以某加氢裂化装置为基准的计算结果表明,能量转换和传输环节降低能耗2.2%~3.5%;能量利用环节降低能耗0.28%~0.39%;能量回收环节降低能耗7.0% ~ 19.6%.集成开发的第一代Sheer加氢裂化技术可使装置能耗降低9.48%~ 23.49%,SO2和CO2排放均降低9.48%~23.49%,装置工程投资减少6.32%~ 12.80%,实现装置低能耗、低投资、长周期运行.%Sheer hydrocracking process is a high-efficiency energy-saving process, which includes patented hydrocracking reactor furnace technology with no open fire, HT and HP counter-current heat transfer technology , state-of-art reactor internals technology, micro-swirl separation technology, non-direct-contact fouling prevention technology and new start-up technology for sulfided catalysts. The calculation results of first-generation Sheer hydrocracking process based upon a hydrocracking unit show that, the energy consumption in heat exchange and heat transfer is reduced by 2.2% -3.5%; the energy requirement in energy utilization is lowered by 0.28% ~0.39% ; the energy consumption in energy recovery is decreased by 7.0% ~ 19. 6%. The application of 1 st-generation Sheer hydrocracking process can reduce unit energy consumption by 9. 48% ~ 23.48% , lower SO2 and CO2 emissions by 9.48% -23, 48% and saves 6. 32% ~ 12. 8% project investment. The unit can be constructed with lower investment and operated reliably at low energy consumption.

  5. Mixed Culture PHA Production With Alternating Feedstocks

    DEFF Research Database (Denmark)

    Oliveira, C.S.S.; Duque, A.F.; Carvalho, Gilda

    Polyhydroxyalkanoates (PHA) are a sustainable alternative to conventional plastics that can be obtained from industrial wastes/by-products using mixed microbial cultures (MMC). MMC PHA production is commonly carried out in a 3-stage process consisting of an acidogenic stage, a PHA producing culture...... selection stage, and a PHA production phase. This work investigated the performance robustness and microbial population dynamics of a PHA producing MMC when subjected to a feedstock shift, mimicking a seasonal feedstock scenario, from cheese whey to sugar cane molasses. Research was focused...... on the possibility of tailoring PHA through the selection of feedstock: either using feedstocks with different compositions or mixing two or more fermented substrates with different organic acid profiles. This knowledge is expected to contribute to the extended application of this promising process for resource...

  6. 2011 Biomass Program Platform Peer Review: Feedstock

    Energy Technology Data Exchange (ETDEWEB)

    McCann, Laura [Office of Energy Efficiency and Renewable Energy (EERE), Washington, DC (United States)

    2012-02-01

    This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the 2011 U.S. Department of Energy Biomass Program’s Feedstock Platform Review meeting.

  7. Synthesis of supported and unsupported NiMo carbides and their properties for the catalytic hydrocracking of n-octane

    Energy Technology Data Exchange (ETDEWEB)

    Torre, A I Reyes de la [Instituto Tecnologico de Ciudad Madero, Division de Estudios de Posgrado e Investigacion, Juventino Rosas y Jesus Urueta S/N, Colonia Los Mangos, CP 89440, Ciudad Madero, Tamaulipas (Mexico); Banda, J A Melo [Instituto Tecnologico de Ciudad Madero, Division de Estudios de Posgrado e Investigacion, Juventino Rosas y Jesus Urueta S/N, Colonia Los Mangos, CP 89440, Ciudad Madero, Tamaulipas (Mexico); Alamilla, R GarcIa [Instituto Tecnologico de Ciudad Madero, Division de Estudios de Posgrado e Investigacion, Juventino Rosas y Jesus Urueta S/N, Colonia Los Mangos, CP 89440, Ciudad Madero, Tamaulipas (Mexico); Sandoval Robles, G [Instituto Tecnologico de Ciudad Madero, Division de Estudios de Posgrado e Investigacion, Juventino Rosas y Jesus Urueta S/N, Colonia Los Mangos, CP 89440, Ciudad Madero, Tamaulipas (Mexico); Rojas, E Terres [Instituto Mexicano del Petroleo, Molecular Engineering Program, 152 Eje Central L Cardenas, 07730 San Bartolo Atepehuacan, Delegacion Gustavo A Madero, Mexico DF (Mexico); Lopez Ortega, A [Instituto Mexicano del Petroleo, Molecular Engineering Program, 152 Eje Central L Cardenas, 07730 San Bartolo Atepehuacan, Delegacion Gustavo A Madero, Mexico DF (Mexico); Dominguez, J M [Instituto Mexicano del Petroleo, Molecular Engineering Program, 152 Eje Central L Cardenas, 07730 San Bartolo Atepehuacan, Delegacion Gustavo A Madero, Mexico DF (Mexico)

    2004-06-09

    Unsupported and {gamma}-Al{sub 2}O{sub 3}-, MCM-41-supported (Ni, Mo) carbides were prepared and modified by 'in situ' polymer (PAN: polyacrylonitrile) pyrolysis. The supported catalysts were impregnated with Ni and Mo metals, i.e. 2.8 atom Mo/nm{sup 2}, whose atomic ratio was Ni/Ni+Mo = 0.5. X-ray diffraction (XRD) showed single NiC, MoC phases in all cases, with relatively low surface areas, as verified by N{sub 2} adsorption (BET). The catalytic behaviour of the supported (Ni, Mo)C phases for n-C{sub 8} hydrocracking depended on the support type. (Ni, Mo)C/MCM41-PAN-P (P = pyrolyzed) showed a total conversion of 40% while it was only 15% on Ni,MoC/{gamma}-Al{sub 2}O{sub 3}. The most active catalysts were (Ni, Mo)C unsupported catalysts, i.e., 90% total conversion. In all cases the hydrocracking selectivity favoured lighter hydrocarbons (C{sub 1}-C{sub 4})

  8. Removal and Conversion of Tar in Syngas from Woody Biomass Gasification for Power Utilization Using Catalytic Hydrocracking

    Directory of Open Access Journals (Sweden)

    Jiu Huang

    2011-08-01

    Full Text Available Biomass gasification has yet to obtain industrial acceptance. The high residual tar concentrations in syngas prevent any ambitious utilization. In this paper a novel gas purification technology based on catalytic hydrocracking is introduced, whereby most of the tarry components can be converted and removed. Pilot scale experiments were carried out with an updraft gasifier. The hydrocracking catalyst was palladium (Pd. The results show the dominant role of temperature and flow rate. At a constant flow rate of 20 Nm3/h and temperatures of 500 °C, 600 °C and 700 °C the tar conversion rates reached 44.9%, 78.1% and 92.3%, respectively. These results could be increased up to 98.6% and 99.3% by using an operating temperature of 700 °C and lower flow rates of 15 Nm3/h and 10 Nm3/h. The syngas quality after the purification process at 700 °C/10 Nm3/h is acceptable for inner combustion (IC gas engine utilization.

  9. CARBONIZER TESTS WITH LAKELAND FEEDSTOCKS

    Energy Technology Data Exchange (ETDEWEB)

    C. Lu; Z. Fan; R. Froehlich; A. Robertson

    2003-09-01

    Research has been conducted under United States Department of Energy Contract (USDOE) DE-AC21-86MC21023 to develop a new type of coal-fired plant for electric power generation. This new type of plant, called a Second Generation Pressurized Fluidized Bed Combustion Plant (2nd Gen PFB), offers the promise of efficiencies greater than 48%, with both emissions and a cost of electricity that are significantly lower than those of conventional pulverized coal-fired (PC) plants with wet flue gas desulfurization/scrubbers. The 2nd Gen PFB plant incorporates the partial gasification of coal in a carbonizer, the combustion of carbonizer char in a pressurized circulating fluidized (PCFB) bed boiler, and the combustion of carbonizer syngas in a topping combustor to achieve gas turbine inlet temperatures of 2700 F and higher. Under the USDOE Clean Coal V Demonstration Plant Program, a nominal 260 MWe plant demonstrating 2nd Gen PFB technology has been proposed for construction at the McIntosh Power Plant of the City of Lakeland, Florida. In the September-December 1997 time period, four test runs were conducted in Foster Wheeler's 12-inch diameter carbonizer pilot plant in Livingston New Jersey to ascertain carbonizer performance characteristics with the Kentucky No. 9 coal and Florida limestone proposed for use in the Lakeland plant. The tests were of a short-term nature exploring carbonizer carbon conversions, sulfur capture efficiencies and syngas alkali levels. The tests were successful; observed carbonizer performance was in agreement with predictions and no operating problems, attributed to the planned feedstocks, were encountered. The results of the four test runs are reported herein.

  10. CARBONIZER TESTS WITH LAKELAND FEEDSTOCKS

    Energy Technology Data Exchange (ETDEWEB)

    C. Lu; Z. Fan; R. Froehlich; A. Robertson

    2003-09-01

    Research has been conducted under United States Department of Energy Contract (USDOE) DE-AC21-86MC21023 to develop a new type of coal-fired plant for electric power generation. This new type of plant, called a Second Generation Pressurized Fluidized Bed Combustion Plant (2nd Gen PFB), offers the promise of efficiencies greater than 48%, with both emissions and a cost of electricity that are significantly lower than those of conventional pulverized coal-fired (PC) plants with wet flue gas desulfurization/scrubbers. The 2nd Gen PFB plant incorporates the partial gasification of coal in a carbonizer, the combustion of carbonizer char in a pressurized circulating fluidized (PCFB) bed boiler, and the combustion of carbonizer syngas in a topping combustor to achieve gas turbine inlet temperatures of 2700 F and higher. Under the USDOE Clean Coal V Demonstration Plant Program, a nominal 260 MWe plant demonstrating 2nd Gen PFB technology has been proposed for construction at the McIntosh Power Plant of the City of Lakeland, Florida. In the September-December 1997 time period, four test runs were conducted in Foster Wheeler's 12-inch diameter carbonizer pilot plant in Livingston New Jersey to ascertain carbonizer performance characteristics with the Kentucky No. 9 coal and Florida limestone proposed for use in the Lakeland plant. The tests were of a short-term nature exploring carbonizer carbon conversions, sulfur capture efficiencies and syngas alkali levels. The tests were successful; observed carbonizer performance was in agreement with predictions and no operating problems, attributed to the planned feedstocks, were encountered. The results of the four test runs are reported herein.

  11. 加氢裂化装置生产喷气燃料存在问题及解决措施%Problems of producing jet fuel in hydrocracking unit and solutions

    Institute of Scientific and Technical Information of China (English)

    张学佳; 刘国海; 肖勇; 孙宏磊; 张启新

    2012-01-01

    介绍了中国石油天然气股份有限公司大庆石化分公司加氢裂化装置概况及生产状况,分析了装置生产喷气燃料的可行性,把装置生产的煤油分别与3号喷气燃料的国标及公司要求指标对比,发现适当调整煤油馏分的密度、冰点、润滑性及安定性指标就可使其成为合格的喷气燃料.归纳了影响装置产品质量的因素,由大到小依次为:操作条件、原料及产品、添加剂及设备因素.提出一系列的措施:控制好操作条件、稳定原料、改进工艺流程、加入添加剂、加强员工培训及细化管理等,其中严格控制好反应岗位、分馏岗位及制氢岗位的操作条件及平稳操作对生产合格喷气燃料尤为重要.装置生产的喷气燃料已通过了国家认证.%The conditions and production of the hydrocracking unit in the refinery of Daqing Petrochemical Company are introduced, and its feasibility of producing jet fuel is analyzed. The comparison with the requirements of national standard and specifications of Daqing Petrochemical Company for 3 Jet fuel shows that, the present kerosene fractions produced can be used as jet fuel when the density, freezing point, lubricity and stability of kerosene are well adjusted. The factors affecting product quality are given and the order of chief factors influencing jet fuel quality from high to low is listed, i. e. operating conditions, feedstock & products, additive and equipment. A series of relevant countermeasures and solutions are presented such as good control of operating conditions, stabling feedstock, improving process, adding additives, strengthening technical training and detailing management. Three major sections of reaction, fractionation and hydrogen production must have a strict control of operating conditions to maintain a stable operation of the unit which is very important for the production of on-spec jet fuels. The jet fuel produced by the hydrocracking unit meets

  12. 煤液化重质产物的催化加氢裂解研究%Study of catalytic hydrocracking of asphaltenes from heavy products of coal liquefaction

    Institute of Scientific and Technical Information of China (English)

    康士刚; 宗志敏; 水恒福; 王知彩; 魏贤勇

    2011-01-01

    为了使煤直接液化的重质产物转化为轻质油类,利用管式高压反应釜,以四氢萘为溶剂、FeS和S为催化剂,对沥青烯进行了加氢裂解研究.考察了催化剂种类及加入量、反应温度和反应压力等因素对沥青烯加氢液化的转化率和产物分布的影响.利用FTIR与元素分析仪对原料沥青烯及残余沥青烯进行了结构表征.结果表明:在一定实验条件下,FeS加硫后使原料的转化率由30.76%增加至53.94%,油+气的产率也由6.01%增至38.39%,而逆向缩合程度减少了9%;两种催化体系下原料的液化转化率均随着温度的升高而增加,但不加硫时增加的幅度为15.20%,明显小于加硫时的23.83%;随着压力的增加,两种催化条件下原料的转化率均增加,而逆向缩合程度在不加硫时随着压力的增加而增加(16.17%,6~30.54%),加硫时则相反.%In order to upgrading the heavy products from Xiaolongtan lignite liquefaction, the hydrocracking experiments of asphaltenes (AS) were carried out with tetralin as solvent and FeS or sulfur as catalyst in a batch micro-autoclave. The effects of types and amount of catalyst, reaction temperature and hydrogen pressure on the distribution of liquefied products were investigated. The elementary and FTIR analyses were used to illustrate the structural characteristics of feedstock AS and residue ASs. The results indicate that under specific conditions,the addition of sulfur into FeS catalyst increases the conversion of feedstock AS from 30. 76 %to 53.94% with the yield of oil+gas from 6.01% to 38.39%. The retrogressive condensation is reduced by 9%. In the two cases, both the conversions of feedstock AS increase with the increasing of reaction temperature. The conversion increment of 15.20% without sulfur addition is distinctly lower than that of 23.83% with sulfur addition. With the increasing of initial H2 pressure, the conversions of feedstock AS increase in the two cases, where

  13. Biofuel Feedstock Assessment for Selected Countries

    Energy Technology Data Exchange (ETDEWEB)

    Kline, K.L.; Oladosu, G.A.; Wolfe, A.K.; Perlack, R.D.; Dale, V.H.

    2008-02-18

    Findings from biofuel feedstock production assessments and projections of future supply are presented and discussed. The report aims to improve capabilities to assess the degree to which imported biofuel could contribute to meeting future U.S. targets to reduce dependence on imported oil. The study scope was focused to meet time and resource requirements. A screening process identified Argentina, Brazil, Canada, China, Colombia, India, Mexico, and the Caribbean Basin Initiative (CBI) region for initial analysis, given their likely role in future feedstock supply relevant to U.S. markets. Supply curves for selected feedstocks in these countries are projected for 2012, 2017 and 2027. The supply functions, along with calculations to reflect estimated supplies available for export and/or biofuel production, were provided to DOE for use in a broader energy market allocation study. Potential cellulosic supplies from crop and forestry residues and perennials were also estimated for 2017 and 2027. The analysis identified capacity to potentially double or triple feedstock production by 2017 in some cases. A majority of supply growth is derived from increasing the area cultivated (especially sugarcane in Brazil). This is supplemented by improving yields and farming practices. Most future supplies of corn and wheat are projected to be allocated to food and feed. Larger shares of future supplies of sugarcane, soybean and palm oil production will be available for export or biofuel. National policies are catalyzing investments in biofuel industries to meet targets for fuel blending that generally fall in the 5-10% range. Social and environmental concerns associated with rapid expansion of feedstock production are considered. If the 2017 projected feedstock supply calculated as ‘available’ for export or biofuel were converted to fuel, it would represent the equivalent of about 38 billion gallons of gasoline. Sugarcane and bagasse dominate the available supply, representing 64

  14. Wastepaper as a feedstock for ethanol production

    Energy Technology Data Exchange (ETDEWEB)

    Bergeron, P.W.; Riley, C.J.

    1991-11-01

    The possibility of using wastepaper as a cheap feedstock for production of ethanol is discussed. As the single largest material category in the municipal solid waste (MSW) stream, wastepaper is the main target of efforts to reduce the volume of MSW. And in the process for producing ethanol from lignocellulosics, the feedstock represents the highest cost. If wastepaper could be obtained cheaply in large enough quantities and if conversion process cost and efficiency prove to be similar to those for wood, the cost of ethanol could be significantly reduced. At the same time, the volume of wastepaper that must be disposed of in landfills could be lessened. 13 refs., 3 figs., 7 tabs.

  15. High quality transportation fuels from renewable feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Lindfors, Lars Peter

    2010-09-15

    Hydrotreating of vegetable oils is novel process for producing high quality renewable diesel. Hydrotreated vegetable oils (HVO) are paraffinic hydrocarbons. They are free of aromatics, have high cetane numbers and reduce emissions. HVO can be used as component or as such. HVO processes can also be modified to produce jet fuel. GHG savings by HVO use are significant compared to fossil fuels. HVO is already in commercial production. Neste Oil is producing its NExBTL diesel in two plants. Production of renewable fuels will be limited by availability of sustainable feedstock. Therefore R and D efforts are made to expand feedstock base further.

  16. NiO-PTA supported on ZIF-8 as a highly effective catalyst for hydrocracking of Jatropha oil.

    Science.gov (United States)

    Liu, Jing; He, Jing; Wang, Luying; Li, Rong; Chen, Pan; Rao, Xin; Deng, Lihong; Rong, Long; Lei, Jiandu

    2016-03-29

    Nickel oxide (NiO) and phosphotungstic acid (PTA) supported on a ZIF-8 (NiO-PTA/ZIF-8) catalyst was first synthesized and it showed high activity and good selectivity for the hydrocracking of Jatropha oil. The catalyst was characterized by SEM, SEM-EDS, TEM, N2 adsorption, FT-IR, XRD and XPS. Compared with the NiO-PTA/Al2O3 catalyst, the selectivity of C15-C18 hydrocarbon increased over 36%, and catalytic efficiency increased 10 times over the NiO-PTA/ZIF-8 catalyst. The prepared NiO-PTA/ZIF-8 catalyst was stable for a reaction time of 104 h and the kinetic behavior was also analyzed. This catalyst was found to bypass the presulfurization process, showing promise as an alternative to sulfided catalysts for green diesel production.

  17. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, John Howard

    2014-09-09

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  18. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    Science.gov (United States)

    Gordon, John Howard

    2014-09-09

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  19. Halophytes Energy Feedstocks: Back to Our Roots

    Science.gov (United States)

    Hendricks, Robert C.; Bushnell, Dennis M.

    2008-01-01

    Of the Earth s landmass, approx.43% is arid or semi-arid, and 97% of the Earth s water is seawater. Halophytes are salt-tolerant plants (micro and macro) that can prosper in seawater or brackish waters and are common feedstocks for fuel and food (fuel-food feedstocks) in depressed countries. Two types, broadly classed as coastal and desert, can be found in marshes, coastal planes, inland lakes, and deserts. Major arid or semi-arid halophyte agriculture problems include pumping and draining the required high volumes of irrigation water from sea or ocean sources. Also, not all arid or semi-arid lands are suitable for crops. Benefits of halophyte agriculture include freeing up arable land and freshwater resources, cleansing the environment, decontaminating soils, desalinating brackish waters, and carbon sequestration. Sea and ocean halophyte agriculture problems include storms, transport, and diffuse harvesting. Benefits include available nutrients, ample water, and Sun. Careful attention to details and use of saline agriculture fuel feedstocks are required to prevent anthropogenic disasters. It is shown that the potential for fuel-food feedstock halophyte production is high; based on test plot data, it could supply 421.4 Quad, or 94% of the 2004 world energy consumption and sequester carbon, with major impact on the Triangle of Conflicts.

  20. Preprocessing Moist Lignocellulosic Biomass for Biorefinery Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Neal Yancey; Christopher T. Wright; Craig Conner; J. Richard Hess

    2009-06-01

    Biomass preprocessing is one of the primary operations in the feedstock assembly system of a lignocellulosic biorefinery. Preprocessing is generally accomplished using industrial grinders to format biomass materials into a suitable biorefinery feedstock for conversion to ethanol and other bioproducts. Many factors affect machine efficiency and the physical characteristics of preprocessed biomass. For example, moisture content of the biomass as received from the point of production has a significant impact on overall system efficiency and can significantly affect the characteristics (particle size distribution, flowability, storability, etc.) of the size-reduced biomass. Many different grinder configurations are available on the market, each with advantages under specific conditions. Ultimately, the capacity and/or efficiency of the grinding process can be enhanced by selecting the grinder configuration that optimizes grinder performance based on moisture content and screen size. This paper discusses the relationships of biomass moisture with respect to preprocessing system performance and product physical characteristics and compares data obtained on corn stover, switchgrass, and wheat straw as model feedstocks during Vermeer HG 200 grinder testing. During the tests, grinder screen configuration and biomass moisture content were varied and tested to provide a better understanding of their relative impact on machine performance and the resulting feedstock physical characteristics and uniformity relative to each crop tested.

  1. Chemical or feedstock recycling of WEEE products

    NARCIS (Netherlands)

    Tukker, A.

    2012-01-01

    This chapter reviews initiatives with regard to chemical or feedstock recycling of plastics waste from electrical and electronic products. eurostat estimates the amount of waste from electrical and electronic products that is collected is 2.2 million tonnes. Roughly 20% of this waste consists of pla

  2. Preprocessing Moist Lignocellulosic Biomass for Biorefinery Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Neal Yancey; Christopher T. Wright; Craig Conner; J. Richard Hess

    2009-06-01

    Biomass preprocessing is one of the primary operations in the feedstock assembly system of a lignocellulosic biorefinery. Preprocessing is generally accomplished using industrial grinders to format biomass materials into a suitable biorefinery feedstock for conversion to ethanol and other bioproducts. Many factors affect machine efficiency and the physical characteristics of preprocessed biomass. For example, moisture content of the biomass as received from the point of production has a significant impact on overall system efficiency and can significantly affect the characteristics (particle size distribution, flowability, storability, etc.) of the size-reduced biomass. Many different grinder configurations are available on the market, each with advantages under specific conditions. Ultimately, the capacity and/or efficiency of the grinding process can be enhanced by selecting the grinder configuration that optimizes grinder performance based on moisture content and screen size. This paper discusses the relationships of biomass moisture with respect to preprocessing system performance and product physical characteristics and compares data obtained on corn stover, switchgrass, and wheat straw as model feedstocks during Vermeer HG 200 grinder testing. During the tests, grinder screen configuration and biomass moisture content were varied and tested to provide a better understanding of their relative impact on machine performance and the resulting feedstock physical characteristics and uniformity relative to each crop tested.

  3. Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Quarterly technical progress report, July--September 1995

    Energy Technology Data Exchange (ETDEWEB)

    Song, Chunshan; Schmidt, E.; Schobert, H.H.

    1996-01-01

    Coal liquefaction involves cleavage of methylene, dimethylene and ether bridges connecting polycyclic aromatic units and the reactions of various oxygen functional groups. Here in this quarterly, we report on the hydrocracking of 4-(l-naphthylmethyl)bibenzyl in the presence of iron (Fe) catalysts and sulfur and residual wall catalytic effect. Catalytic hydrocracking of 4-(1-naphthylmethyl)bibenzyl (NMBB) predominantly yielded naphthalene and 4-methylbibenzyl. Various iron compounds were examined as catalyst precursors. Sulfur addition to most catalyst precursors led to substantially higher catalyst activity and higher conversion. NMBB was also treated with sulfur in the absence of iron compounds, in concentrations of 1.2-3.4 wt%, corresponding to the conditions present in reactions with added iron compounds. Increasing sulfur concentrations led to higher NMBB conversions. Furthermore, sulfur had a permanent effect on the reactor walls. A black sulfide layer formed on the surface which could not be removed mechanically. The supposed non-catalytic reactions done in the same reactor but after experiments with added sulfur showed higher conversions than comparable experiments done in new reactors. This wall catalytic effect can be reduced by treating the sulfided reactors with hydrochloric acid. The results of this work demonstrate the significant effect of sulfur addition and sulfur-induced residual wall effects on carbon-carbon bond cleavage and hydrogenation of aromatics.

  4. Sustainable Use of Biotechnology for Bioenergy Feedstocks

    Science.gov (United States)

    Moon, Hong S.; Abercrombie, Jason M.; Kausch, Albert P.; Stewart, C. Neal

    2010-10-01

    Done correctly, cellulosic bioenergy should be both environmentally and economically beneficial. Carbon sequestration and decreased fossil fuel use are both worthy goals in developing next-generation biofuels. We believe that biotechnology will be needed to significantly improve yield and digestibility of dedicated perennial herbaceous biomass feedstocks, such as switchgrass and Miscanthus, which are native to the US and China, respectively. This Forum discusses the sustainability of herbaceous feedstocks relative to the regulation of biotechnology with regards to likely genetically engineered traits. The Forum focuses on two prominent countries wishing to develop their bioeconomies: the US and China. These two countries also share a political desire and regulatory frameworks to enable the commercialization and wide release of transgenic feedstocks with appropriate and safe new genetics. In recent years, regulators in both countries perform regular inspections of transgenic field releases and seriously consider compliance issues, even though the US framework is considered to be more mature and stringent. Transgene flow continues to be a pertinent environmental and regulatory issue with regards to transgenic plants. This concern is largely driven by consumer issues and ecological uncertainties. Regulators are concerned about large-scale releases of transgenic crops that have sexually compatible crops or wild relatives that can stably harbor transgenes via hybridization and introgression. Therefore, prior to the commercialization or extensive field testing of transgenic bioenergy feedstocks, we recommend that mechanisms that ensure biocontainment of transgenes be instituted, especially for perennial grasses. A cautionary case study will be presented in which a plant’s biology and ecology conspired against regulatory constraints in a non-biomass crop perennial grass (creeping bentgrass, Agrostis stolonifera), in which biocontainment was not attained. Appropriate

  5. Supply Deficit of Feedstock Oils for Carbon Black

    Institute of Scientific and Technical Information of China (English)

    Li Bingyan

    2007-01-01

    @@ Feedstock oils used for carbon blackproduction mainly include ethylene tar,anthracene oil and coal tar. With thegrowing output of carbon black in re-cent years, demand for feedstock oilshas increased constantly.

  6. Modeling and simulation of a pseudo-two-phase gas-liquid column reactor for thermal hydrocracking of petroleum heavy fractions

    Directory of Open Access Journals (Sweden)

    E.M. Matos

    2002-07-01

    Full Text Available This work presents a model to predict the behavior of velocity, gas holdup and local concentration fields in a pseudo-two-phase gas-liquid column reactor applied for thermal hydrocracking of petroleum heavy fractions. The model is based on the momentum and mass balances for the system, using an Eulerian-Eulerian approach. Using the k-epsilon model,fluid dynamics accounts for both laminar and turbulent flows, with discrete small bubbles (hydrogen flowing in a continuous pseudohomogeneous liquid phase (oil and catalyst particles. The petroleum is assumed to be a mixture of pseudocomponents, grouped by similar chemical structural properties, and the thermal hydrocracking is taken into account using a kinetic network based on these pseudocomponents.

  7. Alternative, Renewable and Novel Feedstocks for Producing Chemicals

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2007-07-01

    Vision2020 and ITP directed the Alternative, Renewable and Novel Feedstocks project to identify industrial options and to determine the work required to make alternative, renewable and novel feedstock options attractive to the U.S. chemicals industry. This report presents the Alternative, Renewable and Novel Feedstocks project findings which were based on a technology review and industry workshop.

  8. Biofuel Feedstock Assessment For Selected Countries

    Energy Technology Data Exchange (ETDEWEB)

    Kline, Keith L [ORNL; Oladosu, Gbadebo A [ORNL; Wolfe, Amy K [ORNL; Perlack, Robert D [ORNL; Dale, Virginia H [ORNL

    2008-02-01

    Findings from biofuel feedstock production assessments and projections of future supply are presented and discussed. The report aims to improve capabilities to assess the degree to which imported biofuel could contribute to meeting future U.S. targets to reduce dependence on imported oil. The study scope was focused to meet time and resource requirements. A screening process identified Argentina, Brazil, Canada, China, Colombia, India, Mexico, and the Caribbean Basin Initiative (CBI) region for initial analysis, given their likely role in future feedstock supply relevant to U.S. markets. Supply curves for selected feedstocks in these countries are projected for 2012, 2017 and 2027. The supply functions, along with calculations to reflect estimated supplies available for export and/or biofuel production, were provided to DOE for use in a broader energy market allocation study. Potential cellulosic supplies from crop and forestry residues and perennials were also estimated for 2017 and 2027. The analysis identified capacity to potentially double or triple feedstock production by 2017 in some cases. A majority of supply growth is derived from increasing the area cultivated (especially sugarcane in Brazil). This is supplemented by improving yields and farming practices. Most future supplies of corn and wheat are projected to be allocated to food and feed. Larger shares of future supplies of sugarcane, soybean and palm oil production will be available for export or biofuel. National policies are catalyzing investments in biofuel industries to meet targets for fuel blending that generally fall in the 5-10% range. Social and environmental concerns associated with rapid expansion of feedstock production are considered. If the 2017 projected feedstock supply calculated as 'available' for export or biofuel were converted to fuel, it would represent the equivalent of about 38 billion gallons of gasoline. Sugarcane and bagasse dominate the available supply

  9. Processing Cost Analysis for Biomass Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Badger, P.C.

    2002-11-20

    The receiving, handling, storing, and processing of woody biomass feedstocks is an overlooked component of biopower systems. The purpose of this study was twofold: (1) to identify and characterize all the receiving, handling, storing, and processing steps required to make woody biomass feedstocks suitable for use in direct combustion and gasification applications, including small modular biopower (SMB) systems, and (2) to estimate the capital and operating costs at each step. Since biopower applications can be varied, a number of conversion systems and feedstocks required evaluation. In addition to limiting this study to woody biomass feedstocks, the boundaries of this study were from the power plant gate to the feedstock entry point into the conversion device. Although some power plants are sited at a source of wood waste fuel, it was assumed for this study that all wood waste would be brought to the power plant site. This study was also confined to the following three feedstocks (1) forest residues, (2) industrial mill residues, and (3) urban wood residues. Additionally, the study was confined to grate, suspension, and fluidized bed direct combustion systems; gasification systems; and SMB conversion systems. Since scale can play an important role in types of equipment, operational requirements, and capital and operational costs, this study examined these factors for the following direct combustion and gasification system size ranges: 50, 20, 5, and 1 MWe. The scope of the study also included: Specific operational issues associated with specific feedstocks (e.g., bark and problems with bridging); Opportunities for reducing handling, storage, and processing costs; How environmental restrictions can affect handling and processing costs (e.g., noise, commingling of treated wood or non-wood materials, emissions, and runoff); and Feedstock quality issues and/or requirements (e.g., moisture, particle size, presence of non-wood materials). The study found that over the

  10. Thoughts on Optimization of Aromatic Feedstock

    Institute of Scientific and Technical Information of China (English)

    Cao Jian

    2002-01-01

    This article refers to four cases of process unit combinations with different throughputs of aromatics unit for production of 450 kt/a paraxylene at a certain petrochemical complex in order to against a representative case (provided with an 800-kt/a CCR unit and a 600-kt/a disproportionation unit) and the feasibility and advantage of using prolysis gasoline as aromatic feedstock is studied.

  11. Bioenergy Feedstock Development Program Status Report

    Energy Technology Data Exchange (ETDEWEB)

    Kszos, L.A.

    2001-02-09

    The U.S. Department of Energy's (DOE's) Bioenergy Feedstock Development Program (BFDP) at Oak Ridge National Laboratory (ORNL) is a mission-oriented program of research and analysis whose goal is to develop and demonstrate cropping systems for producing large quantities of low-cost, high-quality biomass feedstocks for use as liquid biofuels, biomass electric power, and/or bioproducts. The program specifically supports the missions and goals of DOE's Office of Fuels Development and DOE's Office of Power Technologies. ORNL has provided technical leadership and field management for the BFDP since DOE began energy crop research in 1978. The major components of the BFDP include energy crop selection and breeding; crop management research; environmental assessment and monitoring; crop production and supply logistics operational research; integrated resource analysis and assessment; and communications and outreach. Research into feedstock supply logistics has recently been added and will become an integral component of the program.

  12. Metal-ion pillared clays as hydrocracking catalysts (II): effect of contact time on products from coal extracts and petroleum distillation residues

    Energy Technology Data Exchange (ETDEWEB)

    S.D. Bodman; W.R. McWhinnie; V. Begon; M. Millan; I. Suelves; M.-J. Lazaro; A.A. Herod; R. Kandiyoti [Aston University, Birmingham (United Kingdom). Department of Chemical Engineering and Applied Chemistry

    2003-11-01

    Novel catalysts have been prepared, based on montmorillonite (a natural clay) and laponite (a synthetic clay) pillared with tin, chromium and aluminium pillars as well as layered double hydroxides based on polyoxo-vanadate and -molybdate as previously described. These novel catalysts were compared initially with a standard Ni/Mo catalyst supported on alumina and a dispersed catalyst, Mo(CO){sub 6} in hydrocracking a coal extract for a short contact time of 10 min at 440{sup o}C in a microbomb reactor with tetralin solvent and hydrogen at a pressure of 190 bar. In the present work, the best of the novel catalysts, chromium montmorillonite calcined at 500{sup o}C and tin laponite, have been compared with the supported catalyst and a dispersed catalyst (Mo(CO){sub 6}) in the repeated hydrocracking of fresh coal extract over three sequential periods of 1 h. Also, the chromium montmorillonite calcined at 500{sup o}C has been used in the hydrocracking of primary coal extracts, prepared in the flowing solvent liquefaction rig from Pittsburgh No. 8 and Illinois No. 6 coals, for reaction times of 10 min and 2 h. Further, the chromium montmorillonite calcined at 500{sup o}C and tin laponite, have been compared with the supported catalyst and in the absence of a catalyst, in the hydrocracking of a petroleum distillation residue with 10 min and 2 h reaction times. Results were compared by size exclusion chromatography in NMP solvent and by UV-fluorescence and evaluated by the extent of the shift of the SEC profile to small molecules and by the shift of the synchronous UV-fluorescence profiles to shorter wavelengths. The performances of both catalysts at short, long or repeated reaction times are seen to be better than that of the conventional NiMo catalyst for the hydrocracking of coal-derived materials and a petroleum residue. Trials on a longer time scale are necessary in the next level of evaluation. 37 refs., 14 figs., 1 tab.

  13. In situ sulfiding of Ni-W hydrocracking catalysts : differentiation of different preparation procedures using EXAFS and HRTEM.

    Energy Technology Data Exchange (ETDEWEB)

    Kelly, S. D.; Yang, N.; Mickelson, G. E.; Greenlay, N.; Karapetrova, E.; Sinkler, W.; Bare, S. R.; UOP LLC; EXAFS Analysis

    2009-01-01

    The detailed structural characterization of the metal function of two fully formulated Ni-W hydrocracking catalysts was investigated by time resolved in situ X-ray absorption spectroscopy (EXAFS and XANES) at both the Ni K-edge and W L{sub 3}-edge, and by high resolution transmission electron microscopy. These two hydrocracking catalysts (designated as HCA and HCB) contained the same wt% of Ni and W, the same wt% of the other constituents ({gamma}-Al{sub 2}O{sub 3}/silico-aluminate), and were calcined at the same temperature, but were prepared by different methods in order to highlight the sensitivity of the characterization techniques to the structural differences. The morphology of the WS{sub 2} particles in the sulfided catalyst is substantially different between the two catalysts: in the HCA catalyst there are many more particles with multiple WS{sub 2} layers whereas in HCB there are more single layers. The average diameter of the WS{sub 2} plates is similar in both. The catalysts show a difference in the amount of W sulfidation after the 410 C sulfidation treatment in 10% H{sub 2}S/H{sub 2}. The W of HCA catalyst was completely sulfided whereas 16% W of HCB catalyst was unsulfided. Similarly there is a difference in the amount of sulfided Ni: 16% Ni in HCA and 60% Ni in HCB remain unsulfided. In the sulfided form of both catalysts the Ni exists in three different morphologies: oxidized Ni (six-fold coordinate as a nickel aluminate), nanoparticulate Ni{sub 3}S{sub 2}, and Ni decorating the edge sites of the WS{sub 2}. In both the Ni{sub 3}S{sub 2}, and Ni decorating the edge sites of the WS{sub 2}, the Ni is in a tetrahedral coordination with sulfur. In both catalysts the sulfidation of the Ni and W occurs essentially simultaneously over most of the temperature range and the sulfidation of the W proceeds through the same tungsten oxysulfide in both samples. The characterization methodology presented here is a powerful one for elucidating the structural

  14. Ifp's New Flexible Hydrocracking Process Combines Maximum Conversion with Production of High Viscosity, High Vi Lube Stocks Le nouveau procédé IFP d'hydrocraquage à haute flexibilité combine conversion maximum et production de bases, huile à haute viscosité et à indice de viscosité élevé

    Directory of Open Access Journals (Sweden)

    Hennico A.

    2006-11-01

    Full Text Available Institut Français du Pétrole (IFP has developed a new dual catalytic system for its hydrocracking process that enables high conversion to middle distillates and production of high viscosity, high VI lube stocks. Although the hydrocracking process is mainly devoted to the conversion of vacuum distillates, deasphalted oil or mixture of both into high quality middle distillates, it can also produce a residue, that after dewaxing will be a very high VI lube base oil. In this presentation major emphasis is put on the possibility to produce very high VI lubes with high viscosity thanks to the development of the new catalytic system. Large flexibility in feedstock selection and easy control of operating variables allow the production of all grades of lube oils associated with high quality middle distillates for a large range of conversion levels. L'Institut Français du Pétrole (IFP a mis au point, pour son procédé d'hydrocraquage, un nouveau système catalytique à 2 catalyseurs qui permet une forte conversion en distillats moyens et la production de fractions lubrifiantes à haute viscosité et indice de viscosité élevé. Si le procédé d'hydrocraquage est essentiellement utilisé pour la conversion de distillats sous vide, d'huile désasphaltée ou d'un mélange des deux en distillats moyens de haute qualité, il peut aussi produire un résidu qui, après déparaffinage, fournira une base pour lubrifiant à indice de viscosité très élevé. Cet article souligne particulièrement la possibilité de produire des lubrifiants à indice de viscosité très élevé et haute viscosité, grâce à ce nouveau système catalytique. Une grande flexibilité dans le choix des produits à traiter et la facilité de contrôle des paramètres opératoires permet la production de toutes les qualités d'huiles lubrifiantes associées à des distillats moyens de haute qualité, pour une large gamme de niveaux de conversion.

  15. Survey of Alternative Feedstocks for Commodity Chemical Manufacturing

    Energy Technology Data Exchange (ETDEWEB)

    McFarlane, Joanna [ORNL; Robinson, Sharon M [ORNL

    2008-02-01

    The current high prices for petroleum and natural gas have spurred the chemical industry to examine alternative feedstocks for the production of commodity chemicals. High feedstock prices have driven methanol and ammonia production offshore. The U.S. Chemical Industry is the largest user of natural gas in the country. Over the last 30 years, alternatives to conventional petroleum and natural gas feedstocks have been developed, but have limited, if any, commercial implementation in the United States. Alternative feedstocks under consideration include coal from unconventional processing technologies, such as gasification and liquefaction, novel resources such as biomass, stranded natural gas from unconventional reserves, and heavy oil from tar sands or oil shale. These feedstock sources have been evaluated with respect to the feasibility and readiness for production of the highest volume commodity chemicals in the United States. Sources of organic compounds, such as ethanol from sugar fermentation and bitumen-derived heavy crude are now being primarily exploited for fuels, rather than for chemical feedstocks. Overall, government-sponsored research into the use of alternatives to petroleum feedstocks focuses on use for power and transportation fuels rather than for chemical feedstocks. Research is needed to reduce cost and technical risk. Use of alternative feedstocks is more common outside the United States R&D efforts are needed to make these processes more efficient and less risky before becoming more common domestically. The status of alternative feedstock technology is summarized.

  16. Invasive plants as feedstock for biochar and bioenergy production.

    Science.gov (United States)

    Liao, Rui; Gao, Bin; Fang, June

    2013-07-01

    In this work, the potential of invasive plant species as feedstock for value-added products (biochar and bioenergy) through pyrolysis was investigated. The product yield rates of two major invasive species in the US, Brazilian Pepper (BP) and Air Potato (AP), were compared to that of two traditional feedstock materials, water oak and energy cane. Three pyrolysis temperatures (300, 450, and 600°C) and four feedstock masses (10, 15, 20, and 25 g) were tested for a total of 12 experimental conditions. AP had high biochar and low oil yields, while BP had a high oil yield. At lower temperatures, the minimum feedstock residence time for biochar and bioenergy production increased at a faster rate as feedstock weight increased than it did at higher temperatures. A simple mathematical model was successfully developed to describe the relationship between feedstock weight and the minimum residence time.

  17. CBTL Design Case Summary Conventional Feedstock Supply System - Herbaceous

    Energy Technology Data Exchange (ETDEWEB)

    Christopher T. Wright; Erin M. Searcy

    2012-02-01

    A conventional bale feedstock design has been established that represents supply system technologies, costs, and logistics that are achievable today for supplying herbaceous feedstocks as a blendstock with coal for energy production. Efforts are made to identify bottlenecks and optimize the efficiency and capacities of this supply system, within the constraints of existing local feedstock supplies, equipment, and permitting requirements. The feedstock supply system logistics operations encompass all of the activities necessary to move herbaceous biomass feedstock from the production location to the conversion reactor ready for blending and insertion. This supply system includes operations that are currently available such that costs and logistics are reasonable and reliable. The system modeled for this research project includes the uses of field-dried corn stover or switchgrass as a feedstock to annually supply an 800,000 DM ton conversion facility.

  18. Preparation of gasification feedstock from leafy biomass.

    Science.gov (United States)

    Shone, C M; Jothi, T J S

    2016-05-01

    Dried leaves are a potential source of energy although these are not commonly used beside to satisfy daily energy demands in rural areas. This paper aims at preparing a leafy biomass feedstock in the form of briquettes which can be directly used for combustion or to extract the combustible gas using a gasifier. Teak (Tectona grandis) and rubber (Hevea brasiliensis) leaves are considered for the present study. A binder-assisted briquetting technique with tapioca starch as binder is adopted. Properties of these leafy biomass briquettes such as moisture content, calorific value, compressive strength, and shatter index are determined. From the study, briquettes with biomass-to-binder ratio of 3:5 are found to be stable. Higher mass percentage of binder is considered for preparation of briquettes due to the fact that leafy biomasses do not adhere well on densification with lower binder content. Ultimate analysis test is conducted to analyze the gasification potential of the briquettes. Results show that the leafy biomass prepared from teak and rubber leaves has calorific values of 17.5 and 17.8 MJ/kg, respectively, which are comparable with those of existing biomass feedstock made of sawdust, rice husk, and rice straw.

  19. Influence of feedstock sulfur content on cat cracking results

    Energy Technology Data Exchange (ETDEWEB)

    Manovyan, A.K.; Pivovarova, N.A.; Tarakanov, G.V. [and others

    1995-11-01

    In the interest of expanding the resources for cat cracking feedstocks, blends of vacuum distillate and resids are being used. The feedstock components are usually subjected to hydrotreating or deasphalting in order to lower the contents of resins and sulfur. However, there has been very little study of the question of how the cracking results are influenced by resins and sulfur remaining in the feedstock after hydrotreating or deasphalting. Here, the authors are reporting on a study of the influence of feedstock sulfur content on the content of olefins in the products from cracking.

  20. Socio-economic impact of biofuel feedstock production on local ...

    African Journals Online (AJOL)

    Keywords: Biofuel feedstock plantations; Jatropha curcas; land grabbing; local livelihoods; ... Consequently, many European and American governments, international ...... Biofuel biomass crop farm/plantation initiatives in the Northern Region.

  1. CATALYTIC HYDROCRACKING OF WASTE LUBRICANT OIL INTO LIQUID FUEL FRACTION USING ZnO, Nb2O5, ACTIVATED NATURAL ZEOLITE AND THEIR MODIFICATION

    Directory of Open Access Journals (Sweden)

    Wega Trisunaryanti

    2010-06-01

    Full Text Available Catalytic hydrocracking of waste lubricant oil into liquid fuel fraction using ZnO, Nb2O5, activated natural zeolite (ZAAH and their modification has been investigated. The zeolite was produced in Wonosari, Yogyakarta. Activation of the zeolite was carried out by refluxing with HCl 3M for 30 min, produced the activated natural zeolite (ZAAH. The ZnO/ZAAH catalyst was prepared by impregnation of Zn onto the ZAAH by ion exchange method using salt precursor of Zn(NO32.4H2O. The Nb2O5/ZAAH catalyst was prepared by mixing the ZAAH sample with Nb2O5 and oxalic acid solution until the paste was formed. The impregnation of Zn onto Nb2O5/ZAAH was carried out using the same method to that of the ZnO/ZAAH catalyst resulted ZnO/Nb2O5-ZAAH catalyst. Characterization of catalyst includes determination of Zn metal by Atomic Absorption Spectroscopy (AAS, acidity by gravimetric method and catalyst porosity by Surface Area Analyzer (NOVA-1000. Catalytic hydrocracking was carried out in a semi-batch reactor system using ZnO, ZAAH, ZnO/ZAAH and ZnO/Nb2O5-ZAAH catalysts at 450 oC under the H2 flow rate of 15 mL/min. and the ratio of catalyst/feed = 1/5. The composition of liquid products was analyzed by Gas Chromatograpy (GC.The results showed that impregnation of ZnO and/or Nb2O5 on the ZAAH increased the acidity and specific surface area of catalyst. The products of the hydrocracking process were liquid, coke and gas. Conversion of liquid products was increased by the increase of catalyst acidity. The highest liquid product was produced by ZnO/Nb2O5-ZAAH catalyst, 52.97 wt-%, consist of gasoline, 38.87 wt-% and diesel, 14.10 wt-%.   Keywords: hydrocracking, waste lubricant oil, liquid fuel fraction

  2. EMSL Quarterly Highlights Report: 1st Quarter, Fiscal Year 2009

    Energy Technology Data Exchange (ETDEWEB)

    Showalter, Mary Ann; Kathmann, Loel E.; Manke, Kristin L.

    2009-02-02

    The EMSL Quarterly Highlights Report covers the science, staff and user recognition, and publication activities that occurred during the 1st quarter (October 2008 - December 2008) of Fiscal Year 2009.

  3. EMSL Quarterly Highlights Report: 1st Quarter, FY08

    Energy Technology Data Exchange (ETDEWEB)

    Showalter, Mary Ann

    2008-01-28

    The EMSL Quarterly Highlights Report covers the science, staff and user recognition, and publication activities that occurred during the 1st quarter (October 2007 - December 2007) of Fiscal Year 2008.

  4. EMSL Quarterly Highlights Report: FY 2008, 3rd Quarter

    Energy Technology Data Exchange (ETDEWEB)

    Showalter, Mary Ann

    2008-09-16

    The EMSL Quarterly Highlights Report covers the science, staff and user recognition, and publication activities that occurred during the 1st quarter (October 2007 - December 2007) of Fiscal Year 2008.

  5. Interfacing feedstock logistics with bioenergy conversion

    Energy Technology Data Exchange (ETDEWEB)

    Sokhansanj, S. [British Columbia Univ., Vancouver, BC (Canada). Oak Ridge National Lab

    2010-07-01

    The interface between biomass production and biomass conversion platforms was investigated. Functional relationships were assembled in a modeling platform to simulate the flow of biomass feedstock from farm and forest to a densification plant. The model considers key properties of biomass for downstream pre-processing and conversion. These properties include moisture content, cellulose, hemicelluloses, lignin, ash, particle size, specific density and bulk density. The model simulates logistical operations such as grinding to convert biomass to pellets that are supplied to a biorefinery for conversion to heat, power, or biofuels. Equations were developed to describe the physical aspects of each unit operation. The effect that each of the process variables has on the efficiency of the conversion processes was described.

  6. Biodiesel from non-food alternative feed-stock

    Science.gov (United States)

    As a potential feedstock for biodiesel (BD) production, Jojoba oil was extracted from Jojoba (Simmondsia chinensis L.) plant seeds that contained around 50-60 wt.%, which were explored as non-food alternative feedstocks. Interestingly, Jojoba oil has long-chain wax esters and is not a typical trigly...

  7. Best practices guidelines for managing water in bioenergy feedstock production

    Science.gov (United States)

    Daniel G. Neary

    2015-01-01

    In the quest to develop renewable energy sources, woody and agricultural crops are being viewed as an important source of low environmental impact feedstocks for electrical generation and biofuels production (Hall and Scrase 1998, Eriksson et al. 2002, Somerville et al. 2010, Berndes and Smith 2013). In countries like the USA, the bioenergy feedstock potential is...

  8. Feedstock Quality Factor Calibration and Data Model Development

    Energy Technology Data Exchange (ETDEWEB)

    Richard D. Boardman; Tyler L. Westover; Garold L. Gresham

    2010-05-01

    The goal of the feedstock assembly operation is to deliver uniform, quality-assured feedstock materials that will enhance downstream system performance by avoiding problems in the conversion equipment. In order to achieve this goal, there is a need for rapid screening tools and methodologies for assessing the thermochemical quality characteristics of biomass feedstock through the assembly process. Laser-induced breakdown spectroscopy (LIBS) has been identified as potential technique that could allow rapid elemental analyses of the inorganic content of biomass feedstocks; and consequently, would complement the carbohydrate data provided by near-infrared spectrometry (NIRS). These constituents, including Si, K, Ca, Na, S, P, Cl, Mg, Fe and Al, create a number of downstream problems in thermochemical processes. In particular, they reduce the energy content of the feedstock, influence reaction pathways, contribute to fouling and corrosion within systems, poison catalysts, and impact waste streams.

  9. C4 Plants as Biofuel Feedstocks: Optimising Biomass Production and Feedstock Quality from a Lignocellulosic Perspective

    Institute of Scientific and Technical Information of China (English)

    Caitlin S.Byrt; Christopher P.L.Grof; Robert T.Furbank

    2011-01-01

    The main feedstocks for bioethanol are sugarcane (Saccharum offic-inarum) and maize (Zea mays), both of which are C4 grasses, highly efficient at converting solar energy into chemical energy, and both are food crops. As the systems for lignocellulosic bioethanol production become more efficient and cost effective, plant biomass from any source may be used as a feedstock for bioethanol production. Thus, a move away from using food plants to make fuel is possible, and sources of biomass such as wood from forestry and plant waste from cropping may be used. However, the bioethanol industry will need a continuous and reliable supply of biomass that can be produced at a low cost and with minimal use of water, fertilizer and arable land. As many C4 plants have high light, water and nitrogen use efficiency, as compared with C3 species, they are ideal as feedstock crops. We consider the productivity and resource use of a number of candidate plant species, and discuss biomass 'quality', that is, the composition of the plant cell wall.

  10. High-quality bio-oil from one-pot catalytic hydrocracking of kraft lignin over supported noble metal catalysts in isopropanol system.

    Science.gov (United States)

    Yang, Jing; Zhao, Liang; Liu, Shaotong; Wang, Yuanyuan; Dai, Liyi

    2016-07-01

    Catalytic hydrocracking of kraft lignin was carried out in isopropanol system and an orthogonal array design (OAD) was employed to optimize the experimental conditions. GC-MS/FID, elemental analysis, GPC and (1)H-(13)C HSQC NMR were carried out for entire investigation of the liquid products. The results indicated that the hydrocracking process was thermally controlled and catalysts showed significant influences on the product distributions. Comparing with Pd/C, Pt/C and Ru/C, Rh/C inhibited the self-condensation of isopropanol and reduced the formation of oxygenic-chain compounds. The excellent catalytic activity for phenols conversion was obtained over Rh/C. The routes of oxygenic-chain compounds formation and phenol conversion were proposed in detail. The least oxygenic-chain compounds formation, the highest phenols conversion (93.4%), the lowest O/C ratio (0.094) and the highest HHV (37.969MJ/kg) provided the possibility of the high quality bio-oil obtained over Rh/C in isopropanol medium.

  11. Effects of Catalyst Preparation on Hydrocarbon Product Distribution in Hydrocracking of the Fischer-Tropsch Product with Low Pt-Loaded Catalysts

    Directory of Open Access Journals (Sweden)

    Toshiaki Hanaoka

    2015-11-01

    Full Text Available For the effective production of hydrocarbon liquid fuel in the hydrocracking of the Fischer-Tropsch (FT product, the catalytic performance of Pt-loaded catalysts with low Pt content was investigated using an autoclave at 250 °C, an initial H2 pressure of 0.5 MPa, and a reaction time of 1 h. A screening study using Pt-loaded catalysts with a Pt content of 0.1 wt. % indicated that zeolite supports were more favorable for jet fuel (carbon numbers 9–15 production than amorphous oxide supports. The small particle size of the supported Pt particles and the high amount of medium acid sites for the supports led to higher performance of the Pt-loaded zeolite catalysts. In the hydrocracking reaction over Pt catalysts using the zeolite support with the high amount of medium acid sites, the yields of the corresponding jet fuel at 0.02 and 0.1 wt. % were almost the same. Pt-loaded catalysts with a Pt content of 0.02 wt. % were prepared using water-in-oil (w/o microemulsions and their particle size was controlled between 1.0 and 2.6 nm. While the yield of the corresponding jet fuel was independent of Pt particle size, smaller Pt particles typically promoted the production of lighter hydrocarbons.

  12. Hydrocracking of cumene over Ni/Al 2O 3 as influenced by CeO 2 doping and γ-irradiation

    Science.gov (United States)

    El-Shobaky, G. A.; Doheim, M. M.; Ghozza, A. M.

    2004-01-01

    Cumene hydrocracking was carried out over pure and doped Ni/Al 2O 3 solids and also, on these solids after exposure to different doses of γ-rays between 0.4 and 1.6 MGy. The dopant concentration was varied between 1 and 4 mol% CeO 2. Pure and doped samples were subjected to heat treatment at 400°C and cumene hydrocracking reaction was carried out using various solids at temperatures between 250°C and 400°C by means of micropulse technique. The results showed that both CeO 2 doping and γ-irradiation of the investigated system brought about an increase in its specific surface area. γ-irradiation of pure samples increased their catalytic activities effectively. However, the doping caused a decrease in the catalytic activity. γ-irradiation of the doped samples brought about a net decrease in the catalytic activity. The catalytic reaction products over different investigated solids were ethylbenzene as a major product together with different amounts of toluene, benzene and C 1-C 3 gaseous hydrocarbons. The selectivity towards the formation of various reaction products varies with the reaction temperature, doping and γ-irradiation.

  13. Quarterly environmental data summary for first quarter 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-06-01

    In support of the Weldon Spring Site Remedial Action Project Federal Facilities Agreement, a copy of the Quarterly Environmental Data Summary (QEDS) for the first quarter of 1999 is enclosed. The data presented in this constitute the QEDS. The data, except for air monitoring data and site KPA generated data (uranium analyses), were received from the contract laboratories, verified by the Weldon Spring Site verification group and merged into the database during the first quarter of 1999. KPA results for on-site total uranium analyses performed during first quarter 1999 are included. Air monitoring data presented are the most recent complete sets of quarterly data.

  14. Quarterly fiscal policy

    NARCIS (Netherlands)

    Kendrick, D.A.; Amman, H.M.

    2014-01-01

    Monetary policy is altered once a month. Fiscal policy is altered once a year. As a potential improvement this article examines the use of feedback control rules for fiscal policy that is altered quarterly. Following the work of Blinder and Orszag, modifications are discussed in Congressional

  15. Quarterly Technical Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Ayman I. Hawari

    2002-12-30

    This report presents the progress made during the first quarter of phase 2 for the project entitled ''Development and Validation of Thermal Neutron Scattering Laws from Applications and Safety Implications in Generation IV Reactor Designs.'' (B204) THIS IS NOT A FINAL REPORT

  16. ASSERT FY16 Analysis of Feedstock Companion Markets

    Energy Technology Data Exchange (ETDEWEB)

    Lamers, Patrick [Idaho National Lab. (INL), Idaho Falls, ID (United States); Hansen, Jason [Idaho National Lab. (INL), Idaho Falls, ID (United States); Jacobson, Jacob J. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Nguyen, Thuy [Idaho National Lab. (INL), Idaho Falls, ID (United States); Nair, Shyam [Idaho National Lab. (INL), Idaho Falls, ID (United States); Searcy, Erin [Idaho National Lab. (INL), Idaho Falls, ID (United States); Hess, J. Richard [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-09-01

    Meeting Co-Optima biofuel production targets will require large quantities of mobilized biomass feedstock. Mobilization is of key importance as there is an abundance of biomass resources, yet little is available for purchase, let alone at desired quantity and quality levels needed for a continuous operation, e.g., a biorefinery. Therefore Co-Optima research includes outlining a path towards feedstock production at scale by understanding routes to mobilizing large quantities of biomass feedstock. Continuing along the vertically-integrated path that pioneer cellulosic biorefineries have taken will constrain the bioenergy industry to high biomass yield areas, limiting its ability to reach biofuel production at scale. To advance the cellulosic biofuels industry, a separation between feedstock supply and conversion is necessary. Thus, in contrast to the vertically integrated supply chain, two industries are required: a feedstock industry and a conversion industry. The split is beneficial for growers and feedstock processers as they are able to sell into multiple markets. That is, depots that produce value-add feedstock intermediates that are fully fungible in both the biofuels refining and other, so-called companion markets. As the biofuel industry is currently too small to leverage significant investment in up-stream infrastructure build-up, it requires an established (companion) market to secure demand, which de-risks potential investments and makes a build-up of processing and other logistics infrastructure more likely. A common concern to this theory however is that more demand by other markets could present a disadvantage for biofuels production as resource competition may increase prices leading to reduced availability of low-cost feedstock for biorefineries. To analyze the dynamics across multiple markets vying for the same resources, particularly the potential effects on resource price and distribution, the Companion Market Model (CMM) has been developed in this

  17. Method for determining processability of a hydrocarbon containing feedstock

    Science.gov (United States)

    Schabron, John F.; Rovani, Jr., Joseph F.

    2013-09-10

    Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

  18. Effect of Blended Feedstock on Pyrolysis Oil Composition

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Kristin M [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Gaston, Katherine R [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-09-28

    Current techno-economic analysis results indicate biomass feedstock cost represents 27% of the overall minimum fuel selling price for biofuels produced from fast pyrolysis followed by hydrotreating (hydro-deoxygenation, HDO). As a result, blended feedstocks have been proposed as a way to both reduce cost as well as tailor key chemistry for improved fuel quality. For this study, two feedstocks were provided by Idaho National Laboratory (INL). Both were pyrolyzed and collected under the same conditions in the National Renewable Energy Laboratory's (NREL) Thermochemical Process Development Unit (TCPDU). The resulting oil properties were then analyzed and characterized for statistical differences.

  19. Development of Oilfield Chemicals Based on Advantages in Petrochemical Feedstocks

    Institute of Scientific and Technical Information of China (English)

    Wang Xieqing; Peng Pu

    2002-01-01

    This article focuses on the routes for development of oilfield chemicals by making use of the feedstock advantages of the petrochemical industry. The diversification of oilfield chemicals has re sulted in thousand product grades. Because there are hundred domestic producers of oilfield chemicals,mostly medium and small producers, the fluctuations of feedstock prices and product quality cannot be conducive to the application and development of oilfield chemicals. This article illustrates the feasibility of oilfield chemical production by state-run medium and large petrochemical enterprises by allowing full play to their own advantages in petrochemical feedstocks.

  20. Geoffroea decorticans for Biofuels: A Promising Feedstock

    Directory of Open Access Journals (Sweden)

    Claudia Santibáñez

    2017-01-01

    Full Text Available In this work, chañar (Geoffroea decorticans fruit is evaluated as a potential feedstock for biodiesel and biomass pellets production with reference to some relevant properties. The fatty acid profile of this oil (83% unsaturated acids is found to be comparable to similar seed oils which have been attempted for biodiesel production. As a result, the methyl esters (biodiesel obtained from this oil exhibits high quality properties. Chañar biodiesel quality meets all other biodiesel international standards (ASTM D6751 and EN 14214. Moreover, the husk that surrounds the kernel showed a high potential for usage as densified solid fuels. The results demonstrate that chañar husks pellets have a higher calorific value when compared with other biomass pellets, typically, approximately 21 MJ kg−1 with 1.8% of ashes (which is equivalent to that obtained from the combustion of pellets produced from forest wastes. This study indicates that chañar can be used as a multipurpose energy crop in semiarid regions for biodiesel and densified solid fuels (pellets production.

  1. Butter as a feedstock for biodiesel production.

    Science.gov (United States)

    Haas, Michael J; Adawi, Nadia; Berry, William W; Feldman, Elaine; Kasprzyk, Stephen; Ratigan, Brian; Scott, Karen; Landsburg, Emily Bockian

    2010-07-14

    Fatty acid methyl esters (FAME) were produced from cow's milk (Bostaurus) butter by esterification/transesterification in the presence of methanol. The product was assayed according to the Standard Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels (ASTM D 6751). The preparation failed to meet the specifications for flash point, free and total glycerin contents, total sulfur, and oxidation stability. Failures to meet the flash point and free/total glycerin specifications were determined to be due to interference with standard assays for these parameters by short-chain-length fatty acid esters. The oxidation stability of the butterfat FAME was improved by supplementation with a commercial antioxidant formulation. Approximately 725 ppm of antioxidant was required to meet the ASTM-specified stability value for biodiesel. This work indicates that, without further purification to reduce a slightly excessive sulfur content, fatty acid ester preparations produced from butter are unacceptable as sole components of a biodiesel fuel. However, it is possible that even without further purification a butter-based ester preparation could be mixed with biodiesel from other feedstocks to produce a blend that meets the current quality standards for biodiesel. The results presented here also illustrate some potential weaknesses in the accepted methods for biodiesel characterization when employed in the analysis of FAME preparations containing mid- and short-chain fatty acid esters.

  2. Biomass Feedstock and Conversion Supply System Design and Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Jacobson, Jacob J. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Roni, Mohammad S. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Lamers, Patrick [Idaho National Lab. (INL), Idaho Falls, ID (United States); Cafferty, Kara G. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-09-01

    Idaho National Laboratory (INL) supports the U.S. Department of Energy’s bioenergy research program. As part of the research program INL investigates the feedstock logistics economics and sustainability of these fuels. A series of reports were published between 2000 and 2013 to demonstrate the feedstock logistics cost. Those reports were tailored to specific feedstock and conversion process. Although those reports are different in terms of conversion, some of the process in the feedstock logistic are same for each conversion process. As a result, each report has similar information. A single report can be designed that could bring all commonality occurred in the feedstock logistics process while discussing the feedstock logistics cost for different conversion process. Therefore, this report is designed in such a way that it can capture different feedstock logistics cost while eliminating the need of writing a conversion specific design report. Previous work established the current costs based on conventional equipment and processes. The 2012 programmatic target was to demonstrate a delivered biomass logistics cost of $55/dry ton for woody biomass delivered to fast pyrolysis conversion facility. The goal was achieved by applying field and process demonstration unit-scale data from harvest, collection, storage, preprocessing, handling, and transportation operations into INL’s biomass logistics model. The goal of the 2017 Design Case is to enable expansion of biofuels production beyond highly productive resource areas by breaking the reliance of cost-competitive biofuel production on a single, low-cost feedstock. The 2017 programmatic target is to supply feedstock to the conversion facility that meets the in-feed conversion process quality specifications at a total logistics cost of $80/dry T. The $80/dry T. target encompasses total delivered feedstock cost, including both grower payment and logistics costs, while meeting all conversion in-feed quality targets

  3. Feedstock and Conversion Supply System Design and Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Jacobson, J. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Mohammad, R. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Cafferty, K. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Kenney, K. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Searcy, E. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Hansen, J. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-09-01

    The success of the earlier logistic pathway designs (Biochemical and Thermochemical) from a feedstock perspective was that it demonstrated that through proper equipment selection and best management practices, conventional supply systems (referred to in this report as “conventional designs,” or specifically the 2012 Conventional Design) can be successfully implemented to address dry matter loss, quality issues, and enable feedstock cost reductions that help to reduce feedstock risk of variable supply and quality and enable industry to commercialize biomass feedstock supply chains. The caveat of this success is that conventional designs depend on high density, low-cost biomass with no disruption from incremental weather. In this respect, the success of conventional designs is tied to specific, highly productive regions such as the southeastern U.S. which has traditionally supported numerous pulp and paper industries or the Midwest U.S for corn stover.

  4. Feedstock Supply and Logistics: Biomass as a Commodity

    Energy Technology Data Exchange (ETDEWEB)

    None

    2013-05-06

    The Bioenergy Technologies Office and its partners are developing the technologies and systems needed to sustainably and economically deliver a broad range of biomass in formats that enable their efficient use as feedstocks for biorefineries.

  5. Biodiesel production from low cost and renewable feedstock

    Science.gov (United States)

    Gude, Veera; Grant, Georgene; Patil, Prafulla; Deng, Shuguang

    2013-12-01

    Sustainable biodiesel production should: a) utilize low cost renewable feedstock; b) utilize energy-efficient, nonconventional heating and mixing techniques; c) increase net energy benefit of the process; and d) utilize renewable feedstock/energy sources where possible. In this paper, we discuss the merits of biodiesel production following these criteria supported by the experimental results obtained from the process optimization studies. Waste cooking oil, non-edible (low-cost) oils (Jatropha curcas and Camelina Sativa) and algae were used as feedstock for biodiesel process optimization. A comparison between conventional and non-conventional methods such as microwaves and ultrasound was reported. Finally, net energy scenarios for different biodiesel feedstock options and algae are presented.

  6. Bibliography on Biomass Feedstock Research: 1978-2002

    Energy Technology Data Exchange (ETDEWEB)

    Cushman, J.H.

    2003-05-01

    This report provides bibliographic citations for more than 1400 reports on biomass feedstock development published by Oak Ridge National Laboratory and its collaborators from 1978 through 2002. Oak Ridge National Laboratory is engaged in analysis of biomass resource supplies, research on the sustainability of feedstock resources, and research on feedstock engineering and infrastructure. From 1978 until 2002, Oak Ridge National Laboratory also provided technical leadership for the U.S. Department of Energy's Bioenergy Feedstock Development Program (BFDP), which supported research to identify and develop promising energy crops. This bibliography lists reports published by Oak Ridge National Laboratory and by its collaborators in the BFDP, including graduate student theses and dissertations.

  7. Biodiesel From Alternative Oilseed Feedstocks: Production and Properties

    Science.gov (United States)

    Fatty acid methyl esters were prepared and evaluated as potential biodiesel fuels from several alternative oilseed feedstocks, which included camelina (Camelina sativa L.), coriander (Coriandrum sativum L.), field mustard (Brassica juncea L.), field pennycress (Thlaspi arvense L.), and meadowfoam (L...

  8. Microbial renewable feedstock utilization: A substrate-oriented approach

    NARCIS (Netherlands)

    Rumbold, K.; Buijsen, H.J.J. van; Gray, V.M.; Groenestijn, J.W. van; Overkamp, K.M.; Slomp, R.S.; Werf, M.J. van der; Punt, P.J.

    2010-01-01

    Increasingly lignocellulosic biomass hydrolysates are used as the feedstock for industrial fermentations. These biomass hydrolysates consist of complex mixtures of different fermentable sugars, but also contain inhibitors and salts that affect the performance of the productgenerating microbes. The p

  9. Horse manure as feedstock for anaerobic digestion.

    Science.gov (United States)

    Hadin, Sa; Eriksson, Ola

    2016-10-01

    Horse keeping is of great economic, social and environmental benefit for society, but causes environmental impacts throughout the whole chain from feed production to manure treatment. According to national statistics, the number of horses in Sweden is continually increasing and is currently approximately 360,000. This in turn leads to increasing amounts of horse manure that have to be managed and treated. Current practices could cause local and global environmental impacts due to poor performance or lack of proper management. Horse manure with its content of nutrients and organic material can however contribute to fertilisation of arable land and recovery of renewable energy following anaerobic digestion. At present anaerobic digestion of horse manure is not a common treatment. In this paper the potential for producing biogas and biofertiliser from horse manure is analysed based on a thorough literature review in combination with mathematical modelling and simulations. Anaerobic digestion was chosen as it has a high degree of resource conservation, both in terms of energy (biogas) and nutrients (digestate). Important factors regarding manure characteristics and operating factors in the biogas plant are identified. Two crucial factors are the type and amount of bedding material used, which has strong implications for feedstock characteristics, and the type of digestion method applied (dry or wet process). Straw and waste paper are identified as the best materials in an energy point of view. While the specific methane yield decreases with a high amount of bedding, the bedding material still makes a positive contribution to the energy balance. Thermophilic digestion increases the methane generation rate and yield, compared with mesophilic digestion, but the total effect is negligible.

  10. Sophorolipid production from lignocellulosic biomass feedstocks

    Science.gov (United States)

    Samad, Abdul

    The present study investigated the feasibility of production of sophorolipids (SLs) using yeast Candida bombicola grown on hydrolysates derived lignocellulosic feedstock either with or without supplementing oil as extra carbon source. Several researchers have reported using pure sugars and various oil sources for producing SLs which makes them expensive for scale-up and commercial production. In order to make the production process truly sustainable and renewable, we used feedstocks such as sweet sorghum bagasse, corn fiber and corn stover. Without oil supplementation, the cell densities at the end of day-8 was recorded as 9.2, 9.8 and 10.8 g/L for hydrolysate derived from sorghum bagasse, corn fiber, and corn fiber with the addition of yeast extract (YE) during fermentation, respectively. At the end of fermentation, the SL concentration was 3.6 g/L for bagasse and 1.0 g/L for corn fiber hydrolysate. Among the three major sugars utilized by C. bombicola in the bagasse cultures, glucose was consumed at a rate of 9.1 g/L-day; xylose at 1.8 g/L-day; and arabinose at 0.98 g/L-day. With the addition of soybean oil at 100 g/L, cultures with bagasse hydrolysates, corn fiber hydrolysates and standard medium had a cell content of 7.7 g/L; 7.9 g/L; and 8.9 g/L, respectively after 10 days. The yield of SLs from bagasse hydrolysate was 84.6 g/L and corn fiber hydrolysate was15.6 g/L. In the same order, the residual oil in cultures with these two hydrolysates was 52.3 g/L and 41.0 g/L. For this set of experiment; in the cultures with bagasse hydrolysate; utilization rates for glucose, xylose and arabinose was recorded as 9.5, 1.04 and 0.08 g/L-day respectively. Surprisingly, C. bombicola consumed all monomeric sugars and non-sugar compounds in the hydrolysates and cultures with bagasse hydrolysates had higher yield of SLs than those from a standard medium which contained pure glucose at the same concentration. Based on the SL concentrations and considering all sugars consumed

  11. Effect of NiW Modified HZSM-5 and HY Zeolites on Hydrocracking Conversion of Crude Palm Oil to Liquid Hydrocarbons

    Directory of Open Access Journals (Sweden)

    Maliwan Subsadsana

    2016-05-01

    Full Text Available The catalytic conversion of crude palm oil over HZSM-5 and HY zeolites modified with NiW as catalysts in the hydrocracking process was investigated. These zeolites supported by NiW catalysts were prepared employing the impregnation technique. NiW was added to the zeolites in order to induce bi-functional properties (both acid and metal sites in the catalysts. Subsequently, the catalysts were characterized by X-ray diffraction spectrometry (XRD, scanning electron microscope (SEM, transmission electron microscope (TEM, ammonia temperature programmed desorption (NH3-TPD andnitrogen adsorption-desorption isotherms analysis. The catalytic activity of prepared catalysts was evaluated through the conversion of crude palm oil to biofuels. These results indicate that the incorporation of NiW over HZSM-5 and HY zeolites improves the conversion efficiency and enhances the yield of biofuel (gasoline, kerosene, and diesel, possibly due to NiW promote of hydrogenation and dehydrogenation reaction.

  12. Roadmap for Agriculture Biomass Feedstock Supply in the United States

    Energy Technology Data Exchange (ETDEWEB)

    J. Richard Hess; Thomas D. Foust; Reed Hoskinson; David Thompson

    2003-11-01

    The Biomass Research and Development Technical Advisory Committee established a goal that biomass will supply 5% of the nation’s power, 20% of its transportation fuels, and 25% of its chemicals by 2030. These combined goals are approximately equivalent to 30% of the country’s current petroleum consumption. The benefits of a robust biorefinery industry supplying this amount of domestically produced power, fuels, and products are considerable, including decreased demand for imported oil, revenue to the depressed agricultural industry, and revitalized rural economies. A consistent supply of highquality, low-cost feedstock is vital to achieving this goal. This biomass roadmap defines the research and development (R&D) path to supplying the feedstock needs of the biorefinery and to achieving the important national goals set for biomass. To meet these goals, the biorefinery industry must be more sustainable than the systems it will replace. Sustainability hinges on the economic profitability of all participants, on environmental impact of every step in the process, and on social impact of the product and its production. In early 2003, a series of colloquies were held to define and prioritize the R&D needs for supplying feedstock to the biorefinery in a sustainable manner. These colloquies involved participants and stakeholders in the feedstock supply chain, including growers, transporters, equipment manufacturers, and processors as well as environmental groups and others with a vested interest in ensuring the sustainability of the biorefinery. From this series of colloquies, four high-level strategic goals were set for the feedstock area: • Biomass Availability – By 2030, 1 billion dry tons of lignocellulosic feedstock is needed annually to achieve the power, fuel, and chemical production goals set by the Biomass Research and Development Technology Advisory Production Committee • Sustainability – Production and use of the 1 billion dry tons annually must be

  13. 20 CFR 404.146 - When a calendar quarter cannot be a quarter of coverage.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 2 2010-04-01 2010-04-01 false When a calendar quarter cannot be a quarter...-AGE, SURVIVORS AND DISABILITY INSURANCE (1950- ) Insured Status and Quarters of Coverage Quarters of Coverage § 404.146 When a calendar quarter cannot be a quarter of coverage. This section applies when...

  14. Hydrocracking of cumene over Ni/Al{sub 2}O{sub 3} as influenced by CeO{sub 2} doping and {gamma}-irradiation[{gamma}-irradiation; CeO2 doping; Cumene hydrocracking; Ni/Al2O3

    Energy Technology Data Exchange (ETDEWEB)

    El-Shobaky, G.A. E-mail: elshobaky@yahoo.com; Doheim, M.M.; Ghozza, A.M

    2004-01-01

    Cumene hydrocracking was carried out over pure and doped Ni/Al{sub 2}O{sub 3} solids and also, on these solids after exposure to different doses of {gamma}-rays between 0.4 and 1.6 MGy. The dopant concentration was varied between 1 and 4 mol% CeO{sub 2}. Pure and doped samples were subjected to heat treatment at 400 deg. C and cumene hydrocracking reaction was carried out using various solids at temperatures between 250 deg. C and 400 deg. C by means of micropulse technique. The results showed that both CeO{sub 2} doping and {gamma}-irradiation of the investigated system brought about an increase in its specific surface area. {gamma}-irradiation of pure samples increased their catalytic activities effectively. However, the doping caused a decrease in the catalytic activity. {gamma}-irradiation of the doped samples brought about a net decrease in the catalytic activity. The catalytic reaction products over different investigated solids were ethylbenzene as a major product together with different amounts of toluene, benzene and C{sub 1}-C{sub 3} gaseous hydrocarbons. The selectivity towards the formation of various reaction products varies with the reaction temperature, doping and {gamma}-irradiation.

  15. Effect of hydrotreating FCC feedstock on product distribution

    Energy Technology Data Exchange (ETDEWEB)

    Salazar-Sotelo, D.; Maya-Yescas, R.; Mariaca-Dominguez, E.; Rodriguez-Salomon, S.; Aguilera-Lopez, M. [Programa de Tratamiento de Crudo Maya, Instituto Mexicano del Petroleo, Lazaro Cardenas 152, San Bartolo Atepehuacan, 07730 Mexico, D.F. (Mexico)

    2004-11-24

    The demand of low-sulfur fuels has been increasing during the last 20 years due to environmental concerns about SO{sub x} emissions from processing plants and engines. Due to its high contribution to the gasoline pool, hydrotreating fluid catalytic cracking (FCC) feedstock offers several advantages, such as the increase of conversion and yields of gasoline and liquid-phase gas, meanwhile sulfur content in fuels is diminished. However, there are more important factors to be considered when hydrotreating FCC feedstock.In this work, two FCC feedstocks, typical and hydrotreated, were converted in a microactivity test (MAT) reactor, as described by ASTM D-3907-92, at different severities and using two commercial catalysts. Feedstock conversion, product yields and selectivity to valuable products were compared against industrial-scale results predicted by using commercial FCC simulation software. Expected increment in conversion and yield to profitable products was observed when hydrotreated feedstock was used; simulation results follow acceptably MAT results. Some recommendations are given for looking closely at the overall behavior (riser-regenerator), using reliable kinetic models and simulation programs.

  16. Vermicompost derived from different feedstocks as a plant growth medium.

    Science.gov (United States)

    Warman, P R; Anglopez, M J

    2010-06-01

    This study determined feedstock effects on earthworm populations and the quality of resulting vermicomposts produced from different types of feedstocks using different vermicomposting durations. Feedstock combinations (Kitchen Paper Waste (KPW), Kitchen Yard Waste (KYW), Cattle Manure Yard Waste (CMY)), three durations of vermicomposting (45, 68 or 90 days), and two seed germination methods (with two concentrations of vermicompost) for radish, marigold and upland cress, served as the independent variables. The worms (Eisenia fetida) doubled their weight by day 68 in KPW and CMY vermicomposts and day 90 KPW vermicompost produced the greatest weight of worms. The direct seed germination method (seeding into soil or vermicompost-soil mixtures) indicated that KPW and KYW feedstocks decreased germination compared to the control, even in mature vermicompost. Seed germination was greater in the water extract method; however, most of the vermicompost extracts suppressed germination of the three seed species compared to the water controls. Vermicomposts from all three feedstocks increased leaf area and biomass compared to the control, especially in the 10% vermicompost:soil mix. Thus, seed germination and leaf area or plant biomass for these three species are contrasting vermicompost quality indicators.

  17. Coal liquefaction. Quarterly report, January--March 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-12-01

    Current ERDA work in coal liquefaction is aimed at improved process configurations for both catalytic and non-catalytic processes to provide more attractive processing economics and lower capital investment. Coal liquefaction can now be achieved under more moderate processing conditions and more rapidly than was the case in the 1930's. The advantage of coal liquefaction is that the entire range of liquid products, including heavy boiler fuel, distillate fuel oil, gasoline, jet fuel, and diesel oil, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquid fuels also have the potential for use as chemical feedstocks. To determine the most efficient means of utilizing coal resources, ERDA is sponsoring the development of several conversion processes that are currently in the pilot plant stage. Nineteen projects under development are described and progress for each in the quarter is detailed briefly. (LTN)

  18. Coal liquefaction. Quarterly report, July--September 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-02-01

    ERDA's program for the conversion of coal to liquid fuels is aimed at improved process configurations for both catalytic and noncatalytic processes to provide more attractive processing economics and lower capital investment. The advantage of coal liquefaction is that the entire range of liquid products, including heavy boiler fuel, distillate fuel oil, gasoline, jet fuel, and diesel oil, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquids also have the potential for use as chemical feedstocks. To provide efficient and practical means of utilizing coal resources, ERDA is sponsoring the development of several conversion processes that are currently in the pilot plant stage. Responsibility for the design, construction, and operation of these facilities is given and progress in the quarter is summarized. Several supporting or complementary projects are described similarly. (LTN)

  19. THE INFLUENCE OF Pd IMPREGNATION INTO Al-MCM-41 ON THE CHARACTERS AND ACTIVITY FOR BIOGASOLINE PRODUCTION BY CATALYTIC HYDROCRACKING OF FAMEs FROM NYAMPLUNG SEED OIL (Calophyllum Inophyllum

    Directory of Open Access Journals (Sweden)

    Hendro Juwono

    2013-08-01

    Full Text Available Biogasoline have been synthesized through catalytic hydrocracking reaction against FAMEs compounds (fatty acid methyl esters obtained from the transesterification of Nyamplung seed oil. The performance of Al-MCM-41 and Pd/Al-MCM-41 as the catalytic hydrocracking was compared. In this research, the influence of Pd impregnation into Al-MCM-41 catalyst on the characters and catalytic activity has been evaluated. The characters determined were crystallinity by using X-Ray Diffractometer (XRD, Si/Al ratio by Inductively Coupled Plasma (ICP, the acidity by pyridine adsorption, the surface area and pore volume by surface area analyzer and the morphology by Scanning Electron Microscopy (SEM. Catalytic activity was examined for hydrocracking of free fatty acid methyl esters (FAMEs produced from the transesterification of Nyamplung seed oil, by Hydrogen flowing. The research result showed that impregnation of Pd into Al-MCM-41 has been successfully carried out, which did not destroy the structural morphology of the catalyst. It was also discovered that the Pd impregnation could increase Si/Al ratio and the acidity but it leads to decrease in the catalyst surface area and the volume. Furthermore, Pd impregnated Al-MCM-41 showed superior activity compared to Al-MCM-41 for FAMEs hydrocracking. The superiority was indicated by higher effectiveness and yields selectiveness, that were 100% hydrocarbon composed of C9-C18 that was dominated by C12 emerging the gasoline fraction, compared of that by the results used Al-MCM-41 catalyst that were 97% hydrocarbon consisted of C8-C20 with equal abundance.

  20. An Overview of Composting Based on Variable Feedstock Material

    Directory of Open Access Journals (Sweden)

    Kadir Aeslina Abdul

    2016-01-01

    Full Text Available Composting is a biological treatment method that provides a potential sustainable way to convert food waste into organic compost. In composting, the feedstock material is an important item to ensure the success of the composting process. This paper reviewed the process of composting based on implementation different types of feedstock, namely: 1 animal waste such as cow dung, poultry litter, swine manure and chicken manure; and 2 agricultural waste such as sawdust, rice straw, bran, bagasse, banana waste and pine chip. The result for poultry litter, cow manure, swine manure, sawdust and rice straw has C/N ratio lower than 20 at final composting process which is considered as satisfactory level for compost maturity. As a conclusion, the selection of the feedstock material is based on the characteristics of the material itself and the selection of materials is important for the quality of compost.

  1. Bioprocessing of bio-based chemicals produced from lignocellulosic feedstocks.

    Science.gov (United States)

    Kawaguchi, Hideo; Hasunuma, Tomohisa; Ogino, Chiaki; Kondo, Akihiko

    2016-12-01

    The feedstocks used for the production of bio-based chemicals have recently expanded from edible sugars to inedible and more recalcitrant forms of lignocellulosic biomass. To produce bio-based chemicals from renewable polysaccharides, several bioprocessing approaches have been developed and include separate hydrolysis and fermentation (SHF), simultaneous saccharification and fermentation (SSF), and consolidated bioprocessing (CBP). In the last decade, SHF, SSF, and CBP have been used to generate macromolecules and aliphatic and aromatic compounds that are capable of serving as sustainable, drop-in substitutes for petroleum-based chemicals. The present review focuses on recent progress in the bioprocessing of microbially produced chemicals from renewable feedstocks, including starch and lignocellulosic biomass. In particular, the technological feasibility of bio-based chemical production is discussed in terms of the feedstocks and different bioprocessing approaches, including the consolidation of enzyme production, enzymatic hydrolysis of biomass, and fermentation.

  2. Cost Methodology for Biomass Feedstocks: Herbaceous Crops and Agricultural Residues

    Energy Technology Data Exchange (ETDEWEB)

    Turhollow Jr, Anthony F [ORNL; Webb, Erin [ORNL; Sokhansanj, Shahabaddine [ORNL

    2009-12-01

    This report describes a set of procedures and assumptions used to estimate production and logistics costs of bioenergy feedstocks from herbaceous crops and agricultural residues. The engineering-economic analysis discussed here is based on methodologies developed by the American Society of Agricultural and Biological Engineers (ASABE) and the American Agricultural Economics Association (AAEA). An engineering-economic analysis approach was chosen due to lack of historical cost data for bioenergy feedstocks. Instead, costs are calculated using assumptions for equipment performance, input prices, and yield data derived from equipment manufacturers, research literature, and/or standards. Cost estimates account for fixed and variable costs. Several examples of this costing methodology used to estimate feedstock logistics costs are included at the end of this report.

  3. Ensiling corn stover: effect of feedstock preservation on particleboard performance.

    Science.gov (United States)

    Ren, Haiyu; Richard, Tom L; Chen, Zhilin; Kuo, Monlin; Bian, Yilin; Moore, Kenneth J; Patrick, Patricia

    2006-01-01

    Ensilage is a truncated solid-state fermentation in which anaerobically produced organic acids accumulate to reduce pH and limit microbial activity. Ensilage can be used to both preserve and pretreat biomass feedstock for further downstream conversion into chemicals, fuels, and/or fiber products. This study examined the ensilage of enzyme-treated corn stover as a feedstock for particleboard manufacturing. Corn stover at three different particle size ranges (ensilage process, as indicated by sustained lower pH (P ensilage process. Compared with fresh stover, the ensilage process did increase IB of stover particleboard by 33% (P ensilage can be used as a long-term feedstock preservation method for particleboard production from corn stover. Enzyme-amended ensilage not only improved stover preservation but also enhanced the properties of particleboard products.

  4. CBTL Design Case Summary Conventional Feedstock Supply System - Woody

    Energy Technology Data Exchange (ETDEWEB)

    Christopher T. Wright; Erin M. Searcy

    2012-02-01

    A conventional woody feedstock design has been developed that represents supply system technologies, costs, and logistics that are achievable today for supplying woody biomass as a blendstock with coal for energy production. Efforts are made to identify bottlenecks and optimize the efficiency and capacities of this supply system, within the constraints and consideration of existing local feedstock supplies, equipment, and permitting requirements. The feedstock supply system logistics operations encompass all of the activities necessary to move woody biomass from the production location to the conversion reactor ready for blending and insertion. This supply system includes operations that are currently available such that costs and logistics are reasonable and reliable. The system modeled for this research project includes the use of the slash stream since it is a more conservative analysis and represents the material actually used in the experimental part of the project.

  5. Effects of milling and active surfactants on rheological behavior of powder injection molding feedstock

    Institute of Scientific and Technical Information of China (English)

    范景莲; 黄伯云; 曲选辉

    2001-01-01

    The effects of milling and active surfactants on the rheological behavior of powder injection molding feedstock were discussed. The feedstock consists of traditional compositional 90W-7Ni-3Fe powder mixture and a wax based polymer binder. Before mixing feedstock, the powder mixture was milled for different times in a QM-1 high-energy ball mill. The viscosity of the feedstock was examined in a capillary rheometer. The rheological behavior was evaluated from viscosity data. The results show that the feedstock belongs to a pseudoplastic fluid, milling decreases viscosity of the feedstock and the sensitivity of viscosity to shear strain rate. The flowability, rheology and powder loading of this feedstock are improved by milling. Active surfactants such as stearic acid (SA) and di-n-octyl-o-phthalate (DOP) have great influences on the rheological properties of the feedstock. DOP improves the flowability and rheological stability of the feedstock further.

  6. Macroalgae as a Biomass Feedstock: A Preliminary Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Roesijadi, Guritno; Jones, Susanne B.; Snowden-Swan, Lesley J.; Zhu, Yunhua

    2010-09-26

    A thorough of macroalgae analysis as a biofuels feedstock is warranted due to the size of this biomass resource and the need to consider all potential sources of feedstock to meet current biomass production goals. Understanding how to harness this untapped biomass resource will require additional research and development. A detailed assessment of environmental resources, cultivation and harvesting technology, conversion to fuels, connectivity with existing energy supply chains, and the associated economic and life cycle analyses will facilitate evaluation of this potentially important biomass resource.

  7. Elemental concentrations in Triticale straw, a potential bioenergy feedstock

    Science.gov (United States)

    Triticale (X Triticosecale Wittmack) is produced on more than three million ha world wide including 344,000 ha in the USA. Straw resulting from triticale production could provide feedstock for bioenergy production in many regions of the world, but high concentrations of certain elements, including s...

  8. Assessing hydrological impacts of tree-based bioenergy feedstock

    CSIR Research Space (South Africa)

    Gush, Mark B

    2010-01-01

    Full Text Available This chapter provides a methodology for assessing the hydrological impacts of tree-based bioenergy feedstock. Based on experience gained in South Africa, it discusses the tasks required to reach an understanding of the likely water resource impacts...

  9. A Landscape Vision for Sustainable Bioenergy Feedstock Production

    Science.gov (United States)

    Feedstock production for biofuel and other bioproducts is poised to rejuvenate rural economies, but may lead to long-term degradation of soil resources or other adverse and unintended environmental consequences if the practices are not developed in a sustainable manner. This presentation will examin...

  10. Maximum fossil fuel feedstock replacement potential of petrochemicals via biorefineries

    NARCIS (Netherlands)

    Brehmer, B.; Boom, R.M.; Sanders, J.P.M.

    2009-01-01

    The search for feedstock replacement options within the petrochemical industry should logically be based upon non-fossil resources. Retaining the functionality of the biochemicals in biomass for use as chemical products and precursors can lead to a sizeable reduction of fossil fuel consumption. This

  11. Biomass Program 2007 Program Peer Review - Feedstock Platform Summary

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2009-10-27

    This document discloses the comments provided by a review panel at the U.S. Department of Energy Office of the Biomass Program Peer Review held on November 15-16, 2007 in Baltimore, MD and the Feedstock Platform Portfolio Peer Review held on August 21st through 23rd in Washington D.C.

  12. Maximum fossil fuel feedstock replacement potential of petrochemicals via biorefineries

    NARCIS (Netherlands)

    Brehmer, B.; Boom, R.M.; Sanders, J.P.M.

    2009-01-01

    The search for feedstock replacement options within the petrochemical industry should logically be based upon non-fossil resources. Retaining the functionality of the biochemicals in biomass for use as chemical products and precursors can lead to a sizeable reduction of fossil fuel consumption. This

  13. The impact of silicon feedstock on the PV module cost

    NARCIS (Netherlands)

    del Coso, G.; del Cañizo, C.; Sinke, W.C.

    2010-01-01

    The impact of the use of new (solar grade) silicon feedstock materials on the manufacturing cost of wafer-based crystalline silicon photovoltaic modules is analyzed considering effects of material cost, efficiency of utilisation, and quality. Calculations based on data provided by European industry

  14. Fatty acid profile of 25 alternative lipid feedstocks

    Science.gov (United States)

    This study reports the fatty acid profiles of 25 alternative lipid feedstocks for the production of bio-based fuels and chemicals. Lipids were extracted using hexane from oil-bearing seeds using a standard Soxhlet apparatus. Fatty acid profiles were measured using gas chromatography-flame ionization...

  15. Lignocellulosic feedstock supply systems with intermodal and overseas transportation

    NARCIS (Netherlands)

    Hoefnagels, Ric; Searcy, E.; Kafferty, K.; Cornelissen, T.; Junginger, Martin; Jacobson, J.; Faaij, André

    2014-01-01

    With growing demand for internationally traded biomass, the logistic operations required to economically move biomass from the field or forest to end- users have become increasingly complex. To design cost effective and sustainable feedstock supply chains, it is important to understand the economics

  16. The impact of silicon feedstock on the PV module cost

    NARCIS (Netherlands)

    del Coso, G.; del Cañizo, C.; Sinke, W.C.

    2010-01-01

    The impact of the use of new (solar grade) silicon feedstock materials on the manufacturing cost of wafer-based crystalline silicon photovoltaic modules is analyzed considering effects of material cost, efficiency of utilisation, and quality. Calculations based on data provided by European industry

  17. Electronic Service Statistics - Quarterly Report

    Data.gov (United States)

    Social Security Administration — This is a quarterly report that compares electronic data vs non-electronic data for electronic services. Report contains six main sections namely, electronic access,...

  18. National Bioenergy Center, Biochemical Platform Integration Project: Quarterly Update, Winter 2011-2012 (Newsletter)

    Energy Technology Data Exchange (ETDEWEB)

    2012-04-01

    Winter 2011-2012 issue of the National Bioenergy Center Biochemical Platform Integration Project quarterly update. Issue topics: 34th Symposium on Biotechnology for Fuels and Chemicals; feasibility of NIR spectroscopy-based rapid feedstock reactive screening; demonstrating integrated pilot-scale biomass conversion. The Biochemical Process Integration Task focuses on integrating the processing steps in enzyme-based lignocellulose conversion technology. This project supports the U.S. Department of Energy's efforts to foster development, demonstration, and deployment of 'biochemical platform' biorefineries that economically produce ethanol or other fuels, as well as commodity sugars and a variety of other chemical products, from renewable lignocellulosic biomass.

  19. a Novel Framework for Incorporating Sustainability Into Biomass Feedstock Design

    Science.gov (United States)

    Gopalakrishnan, G.; Negri, C.

    2012-12-01

    There is a strong society need to evaluate and understand the sustainability of biofuels, especially due to the significant increases in production mandated by many countries, including the United States. Biomass feedstock production is an important contributor to environmental, social and economic impacts from biofuels. We present a systems approach where the agricultural, urban, energy and environmental sectors are considered as components of a single system and environmental liabilities are used as recoverable resources for biomass feedstock production. A geospatial analysis evaluating marginal land and degraded water resources to improve feedstock productivity with concomitant environmental restoration was conducted for the major corn producing states in the US. The extent and availability of these resources was assessed and geospatial techniques used to identify promising opportunities to implement this approach. Utilizing different sources of marginal land (roadway buffers, contaminated land) could result in a 7-fold increase in land availability for feedstock production and provide ecosystem services such as water quality improvement and carbon sequestration. Spatial overlap between degraded water and marginal land resources was found to be as high as 98% and could maintain sustainable feedstock production on marginal lands through the supply of water and nutrients. Multi-objective optimization was used to quantify the tradeoffs between net revenue, improvements in water quality and carbon sequestration at the farm scale using this design. Results indicated that there is an initial opportunity where land that is marginally productive for row crops and of marginal value for conservation purposes could be used to grow bioenergy crops such that that water quality and carbon sequestration benefits are obtained.

  20. Quarterly coal report, July--September 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-02-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks. Coke production consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1997 and aggregated quarterly historical data for 1991 through the second quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. 72 tabs.

  1. Fatty acid composition as a tool for screening alternative feedstocks for production of biodiesel

    Science.gov (United States)

    Fatty acid (FA) composition was used as a screening tool for the selection of feedstocks high in monounsaturated content for evaluation as biodiesel. The feedstocks were ailanthus (Ailanthus altissima), anise (Pimpinella anisum), arugula (Eruca vesicaria), camelina (Camelina sativa), coriander (Cori...

  2. Fatty acid profile as a basis for screening feedstocks for biodiesel production

    Science.gov (United States)

    Fatty acid (FA) profile was used as a screening tool for the selection of feedstocks high in monounsaturated content for evaluation as biodiesel. The feedstocks were ailanthus (Ailanthus altissima), anise (Pimpinella anisum), arugula (Eruca vesicaria), camelina (Camelina sativa), coriander (Coriandr...

  3. Soil C storage and greenhouse gas emission perennial grasses managed for bio energy feedstock

    Science.gov (United States)

    Perennial grasses like switchgrass or big bluestem when managed as bioenergy feedstock require nitrogenous inputs. Nitrogen fertilizer frequently cause nitrous oxide emission. Therefore, managing grasses as feedstock may reduce the greenhouse gas (GHG) mitigation potential expected from perennial. ...

  4. Feedstock and technology options for Bioethanol production in South Africa: Technoeconomic prefeasibility study

    CSIR Research Space (South Africa)

    Amigun, B

    2013-09-01

    Full Text Available profitable operation during times with high feedstock prices would be possible. A sensitivity analysis of the economic assumptions of the base-case model demonstrated that feedstock price is the most important determinant of production costs...

  5. Quarterly environmental data summary for first quarter 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-05-01

    In support of the Weldon Spring Site Remedial Action Project Federal Facilities Agreement, a copy of the Quarterly Environmental Data Summary (QEDS) for the first quarter of 1998 is enclosed. The data presented in this letter and attachment constitute the QEDS. The data were received from the contract laboratories, verified by the Weldon Spring Site verification group and, except for air monitoring data and site KPA generated data (uranium analyses), merged into the data base during the first quarter of 1998. Air monitoring data presented are the most recent complete sets of quarterly data. Air data are not stored in the data base, and KPA data are not merged into the regular data base. Significant data, defined as data values that have exceeded defined {open_quotes}above normal{close_quotes} Level 2 values, are discussed in this letter for Environmental Monitoring Plan (EMP) generated data only. Above normal Level 2 values are based, in ES&H procedures, on historical high values, DOE Derived Concentration Guides (DCGs), NPDES limits and other guidelines. The procedures also establish actions to be taken in the event that {open_quotes}above normal{close_quotes} data occur. All data received and verified during the first quarter were within a permissible range of variability except for those detailed below. Above normal occurrences are cited for groundwater, air, and NPDES data. There were none for springs or surface water. The following discussion offers a brief summary of the data merged during the first quarter that exceeded the above normal criteria and updates on past reported above normal data. The attached tables present the most recent data for air and the data merged into the data base during the first quarter 1998 for groundwater, NPDES, surface water, and springs. Graphs showing concentrations of selected contaminants of concern at some of the critical locations have also been included in this QEDS. The graphs are discussed in the separate sections.

  6. Preparation for Pt-Loaded Zeolite Catalysts Using w/o Microemulsion and Their Hydrocracking Behaviors on Fischer-Tropsch Product

    Directory of Open Access Journals (Sweden)

    Toshiaki Hanaoka

    2015-02-01

    Full Text Available Pt-loaded β-type zeolite catalysts with constant Pt content (0.11 wt.% and similar pore structure were prepared using a water-in-oil (w/o microemulsion. The effect of Pt particle synthesis conditions using microemulsion (a type of Pt complex-forming agents and the molar ratio of complex-forming agent to Pt4+ on loaded Pt particle size was investigated. The Pt particle size of the Pt catalyst using tetraethylammonium chloride (TEAC as a complex-forming agent with the molar TEAC/Pt ratio 10 was the minimum value (3.8 nm, and was much smaller than that (6.7 nm prepared by the impregnation method. The utilization of the complex-forming agent of which hydrophobic groups occupied a small volume and the appropriate complex-forming agent/Pt ratio were favorable for synthesis of small Pt particles. The effect of loaded Pt particle size on the hydrocracking of the Fischer-Tropsch (FT product was investigated using the Pt-loaded zeolite catalysts at 250 °C with an initial H2 pressure of 0.5 MPa, and reaction time of 1 h. The Pt catalyst with a Pt particle size of 4.2 nm prepared using the microemulsion exhibited the maximum corresponding jet fuel yield (30.0%, which was higher than that of the impregnated catalyst.

  7. A comparison of used cooking oils: a very heterogeneous feedstock for biodiesel

    Science.gov (United States)

    The increased interest in and use of biodiesel renders the availability of a sufficient supply of feedstock ever more urgent. While commodity vegetable oils such as soybean, rapeseed (canola), palm and sunflower may be seen as "classical" biodiesel feedstocks, additional feedstocks are needed to me...

  8. Short-term energy outlook: Quarterly projections, fourth quarter 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-14

    The Energy Information Administration (EIA) prepares quarterly short-term energy supply, demand, and price projections for printed publication in January, April, July, and October in the Short-Term Energy Outlook. The details of these projections, as well as monthly updates on or about the 6th of each interim month, are available on the internet at: www.eia.doe.gov/emeu/steo/pub/contents.html. The forecast period for this issue of the Outlook extends from the fourth quarter of 1997 through the fourth quarter of 1998. Values for the fourth quarter of 1997, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in EIA`s Weekly Petroleum Status Report) or are calculated from model simulations that use the latest exogenous information available (for example, electricity sales and generation are simulated by using actual weather data). The historical energy data, compiled in the fourth quarter 1997 version of the Short-Term Integrated Forecasting System (STIFS) database, are mostly EIA data regularly published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding. The STIFS model is driven principally by three sets of assumptions or inputs: estimates of key macroeconomic variables, world oil price assumptions, and assumptions about the severity of weather. 19 tabs.

  9. Quarterly environmental data summary for fourth quarter 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The Quarterly Environmental Data Summary (QEDS) for the fourth quarter of 1997 is prepared in support of the Weldon Spring Site Remedial Action Project Federal Facilities Agreement. The data presented constitute the QEDS. The data were received from the contract laboratories, verified by the Weldon Spring Site verification group and, except for air monitoring data and site KPA generated data (uranium analyses), merged into the data base during the fourth quarter of 1997. Air monitoring data presented are the most recent complete sets of quarterly data. Air data are not stored in the data base and KPA data are not merged into the regular data base. Significant data, defined as data values that have exceeded defined ``above normal`` level 2 values, are discussed in this letter for Environmental Monitoring Plan (EMP) generated data only. Above normal level 2 values are based, in ES and H procedures, on historical high values, DOE Derived Concentration Guides (DCGs), NPDES limits and other guidelines. The procedures also establish actions to be taken in response to such data. Data received and verified during the fourth quarter were within a permissible range of variability except for those which are detailed.

  10. Modeling Sustainable Bioenergy Feedstock Production in the Alps

    Science.gov (United States)

    Kraxner, Florian; Leduc, Sylvain; Kindermann, Georg; Fuss, Sabine; Pietsch, Stephan; Lakyda, Ivan; Serrano Leon, Hernan; Shchepashchenko, Dmitry; Shvidenko, Anatoly

    2016-04-01

    Sustainability of bioenergy is often indicated by the neutrality of emissions at the conversion site while the feedstock production site is assumed to be carbon neutral. Recent research shows that sustainability of bioenergy systems starts with feedstock management. Even if sustainable forest management is applied, different management types can impact ecosystem services substantially. This study examines different sustainable forest management systems together with an optimal planning of green-field bioenergy plants in the Alps. Two models - the biophysical global forest model (G4M) and a techno-economic engineering model for optimizing renewable energy systems (BeWhere) are implemented. G4M is applied in a forward looking manner in order to provide information on the forest under different management scenarios: (1) managing the forest for maximizing the carbon sequestration; or (2) managing the forest for maximizing the harvestable wood amount for bioenergy production. The results from the forest modelling are then picked up by the engineering model BeWhere, which optimizes the bioenergy production in terms of energy demand (power and heat demand by population) and supply (wood harvesting potentials), feedstock harvesting and transport costs, the location and capacity of the bioenergy plant as well as the energy distribution logistics with respect to heat and electricity (e.g. considering existing grids for electricity or district heating etc.). First results highlight the importance of considering ecosystem services under different scenarios and in a geographically explicit manner. While aiming at producing the same amount of bioenergy under both forest management scenarios, it turns out that in scenario (1) a substantially larger area (distributed across the Alps) will need to be used for producing (and harvesting) the necessary amount of feedstock than under scenario (2). This result clearly shows that scenario (2) has to be seen as an "intensification

  11. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, April 1--June 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-09-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. The paper describes activities carried out this quarter. 11 refs., 21 figs., 17 tabs.

  12. Demand and supply of hydrogen as chemical feedstock in USA

    Science.gov (United States)

    Huang, C. J.; Tang, K.; Kelley, J. H.; Berger, B. J.

    1979-01-01

    Projections are made for the demand and supply of hydrogen as chemical feedstock in USA. Industrial sectors considered are petroleum refining, ammonia synthesis, methanol production, isocyanate manufacture, edible oil processing, coal liquefaction, fuel cell electricity generation, and direct iron reduction. Presently, almost all the hydrogen required is produced by reforming of natural gas or petroleum fractions. Specific needs and emphases are recommended for future research and development to produce hydrogen from other sources to meet the requirements of these industrial sectors. The data and the recommendations summarized in this paper are based on the Workshop 'Supply and Demand of Hydrogen as Chemical Feedstock' held at the University of Houston on December 12-14, 1977.

  13. Multicrystalline silicon wafers prepared from upgraded metallurgical feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Degoulange, J.; Trassy, C. [SIMAP UMR CNRS, INP Grenoble (France); Perichaud, I.; Martinuzzi, S. [TECSEN UMR CNRS-University Paul Cezanne-Aix, Marseille III (France)

    2008-10-15

    A solution to the problem of the shortage of silicon feedstock used to grow multicrystalline ingots can be the production of a feedstock obtained by the direct purification of upgraded metallurgical silicon by means of a plasma torch. It is found that the dopant concentrations in the material manufactured following this metallurgical route are in the 10{sup 17} cm{sup -3} range. Minority carrier diffusion lengths L{sub n} are close to 35 {mu}m in the raw wafers and increases up to 120 {mu}m after the wafers go through the standard processing steps needed to make solar cells: phosphorus diffusion, aluminium-silicon alloying and hydrogenation by deposition of a hydrogen-rich silicon nitride layer followed by an annealing. L{sub n} values are limited by the presence of residual metallic impurities, mainly slow diffusers like aluminium, and also by the high doping level. (author)

  14. Hydrogen production via catalytic processing of renewable feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Nazim Muradov; Franklyn Smith; Ali T-Raissi [Florida Solar Energy Center, University of Central Florida, Cocoa, Florida, (United States)

    2006-07-01

    Landfill gas (LFG) and biogas can potentially become important feedstocks for renewable hydrogen production. The objectives of this work were: (1) to develop a catalytic process for direct reforming of CH{sub 4}-CO{sub 2} gaseous mixture mimicking LFG, (2) perform thermodynamic analysis of the reforming process using AspenPlus chemical process simulator, (3) determine operational conditions for auto-thermal (or thermo-neutral) reforming of a model CH{sub 4}-CO{sub 2} feedstock, and (4) fabricate and test a bench-scale hydrogen production unit. Experimental data obtained from catalytic reformation of the CH{sub 4}-CO{sub 2} and CH{sub 4}-CO{sub 2}-O{sub 2} gaseous mixtures using Ni-catalyst were in a good agreement with the simulation results. It was demonstrated that catalytic reforming of LFG-mimicking gas produced hydrogen with the purity of 99.9 vol.%. (authors)

  15. Pyrolysis of biomass to produce fuels and chemical feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Yaman, Serdar E-mail: yamans@itu.edu.tr

    2004-03-01

    This review presents the summary of new studies on pyrolysis of biomass to produce fuels and chemical feedstocks. A number of biomass species, varying from woody and herbaceous biomass to municipal solid waste, food processing residues and industrial wastes, were subjected to different pyrolysis conditions to obtain liquid, gas and solid products. The results of various biomass pyrolysis investigations connected with the chemical composition and some properties of the pyrolysis products as a result of the applied pyrolysis conditions were combined. The characteristics of the liquid products from pyrolysis were examined, and some methods, such as catalytic upgrading or steam reforming, were considered to improve the physical and chemical properties of the liquids to convert them to economic and environmentally acceptable liquid fuels or chemical feedstocks. Outcomes from the kinetic studies performed by applying thermogravimetric analysis were also presented.

  16. Pyrolysis of biomass to produce fuels and chemical feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Serdar Yaman [Istanbul Technical University (Turkey). Chemical Engineering Dept.

    2004-03-01

    This review presents the summary of new studies on pyrolysis of biomass to produce fuels and chemical feedstocks. A number of biomass species, varying from woody and herbaceous biomass to municipal solid waste, food processing residues and industrial wastes, were subjected to different pyrolysis conditions to obtain liquid, gas and solid products. The results of various biomass pyrolysis investigations connected with the chemical composition and some properties of the pyrolysis products as a result of the applied pyrolysis conditions were combined. The characteristics of the liquid products from pyrolysis were examined, and some methods, such as catalytic upgrading or steam reforming, were considered to improve the physical and chemical properties of the liquids to convert them to economic and environmentally acceptable liquid fuels or chemical feedstocks. Outcomes from the kinetic studies performed by applying thermogravimetric analysis were also presented. (author)

  17. Effects of feedstocks on the process integration of biohydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Foglia, Domenico; Wukovits, Walter; Friedl, Anton [Vienna University of Technology, Vienna (Austria); Ljunggren, Mattias; Zacchi, Guido [Lund University, P. O. Box 124, Lund (Sweden); Urbaniec, Krzysztof; Markowski, Mariusz [Warsaw University of Technology, Plock (Poland)

    2011-08-15

    Future production of hydrogen must be sustainable. To obtain it, renewable resources have to be employed for its production. Fermentation of biomasses could be a viable way. The process evaluated is a two-step fermentation to produce hydrogen from biomass. Process options with barley straws, PSP, and thick juice as feedstocks have been compared on the basis of process balances. Aspen Plus has been used to calculate mass and energy balances taking into account the integration of the process. Results show that the production of hydrogen as energy carrier is technically feasible with all the considered feedstocks and thanks to heat integration, second generation biomass (PSP and barley straws) are competitive with food crops (thick juice). (orig.)

  18. Effects of surfactant on properties of MIM feedstock

    Institute of Scientific and Technical Information of China (English)

    LI Yi-min; LIU Xiang-quan; LUO Feng-hua; YUE Jian-ling

    2007-01-01

    Effects of the surfactant for improving the properties of MIM feedstock were investigated. Feedstocks were prepared by 17-4PH stainless steel(SS) powder and paraffin wax-based binder containing different contents of stearic acid(SA) as the surfactant. The viscosity of the feedstock decreases significantly when the SA is added. Besides, the wetting angle of the binder against the 17-4PH SS powder decreases greatly and the critical solid loading increases with the adding of the SA. Fourier transformation infrared spectroscopy(FTIR) analysis was used to prove the interaction between the SA and the 17-4PH SS powder. Chemical bonding is found on the surface of 17-4PH SS powder after mixing and it helps a lot to enhance the interacting force between the binder and the powder. Then an adsorbing model was adopted to estimate the least content of the surfactant that formed a monolayer adsorption on the mono-sized spherical powder (with smooth surface). The least content of the surfactant is calculated to be 0.19%. Whereas, the experiments indicate that about 5% is the optimal value to improve the properties of the feedstock. The reason may come from two aspects: firstly, the powders used in current experiment are not all mono-sized spheres and the coarse surface of the powder has a great effect on the adsorptive capacity of the powder; secondly, multilayer adsorption is likely to occur on the powder surface, which will also increase the adsorptive capacity.

  19. Kurdistan crude oils as feedstock for production of aromatics

    Directory of Open Access Journals (Sweden)

    Abdulsalam R. Karim

    2017-05-01

    Full Text Available Crude oils from various locations in Iraqi Kurdistan were fully evaluated, so that enables refiners to improve their operation by selecting the best crude oil that yields high naphtha content to be used as a catalytic reforming feedstock after determination of total sulfur content and then de sulfurizing them, then cyclizing or reforming these sweet naphtha cuts to produce aromatic fractions which can be split into benzene, toluene, and xylenes.

  20. LIGNOCELLULOSIC BIOMASS: A POTENTIAL FEEDSTOCK TO REPLACE PETROLEUM

    OpenAIRE

    Lucian A. Lucia

    2008-01-01

    Sustainability considerations for product and energy production in a future US economy can be met with lignocellulosic biomass. The age of petroleum as the key resource to meet the US economy requirements is rapidly dwindling, given the limited resources of petroleum, the growing global population, and concurrent detrimental effects on environmental safety. The use of natural and renewable feedstocks such as trees and switchgrass is becoming more attractive; indeed, lignocellulosic biomass i...

  1. Processes for liquefying carbonaceous feedstocks and related compositions

    Energy Technology Data Exchange (ETDEWEB)

    MacDonnell, Frederick M.; Dennis, Brian H.; Billo, Richard E.; Priest, John W.

    2017-02-28

    Methods for the conversion of lignites, subbituminous coals and other carbonaceous feedstocks into synthetic oils, including oils with properties similar to light weight sweet crude oil using a solvent derived from hydrogenating oil produced by pyrolyzing lignite are set forth herein. Such methods may be conducted, for example, under mild operating conditions with a low cost stoichiometric co-reagent and/or a disposable conversion agent.

  2. Expected international demand for woody and herbaceous feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Lamers, Patrick [Idaho National Lab. (INL), Idaho Falls, ID (United States); Jacobson, Jacob [Idaho National Lab. (INL), Idaho Falls, ID (United States); Mohammad, Roni [Idaho National Lab. (INL), Idaho Falls, ID (United States); Wright, Christopher [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-03-01

    The development of a U.S. bioenergy market and ultimately ‘bioeconomy’ has primarily been investigated with a national focus. Limited attention has been given to the potential impacts of international market developments. The goal of this project is to advance the current State of Technology of a single biorefinery to the global level providing quantitative estimates on how international markets may influence the domestic feedstock supply costs. The scope of the project is limited to feedstock that is currently available and new crops being developed to be used in a future U.S. bioeconomy including herbaceous residues (e.g., corn stover), woody biomass (e.g., pulpwood), and energy crops (e.g., switchgrass). The timeframe is set to the periods of 2022, 2030, and 2040 to align with current policy targets (e.g., the RFS2) and future updates of the Billion Ton data. This particular milestone delivers demand volumes for generic woody and herbaceous feedstocks for the main (net) importing regions along the above timeframes. The regional focus of the study is the European Union (EU), currently the largest demand region for U.S. pellets made from pulpwood and forest residues. The pellets are predominantly used in large-scale power plants (>5MWel) in the United Kingdom (UK), the Netherlands (NL), Belgium (BE), and Denmark (DK).

  3. Physiochemical Characterization of Briquettes Made from Different Feedstocks

    Directory of Open Access Journals (Sweden)

    C. Karunanithy

    2012-01-01

    Full Text Available Densification of biomass can address handling, transportation, and storage problems and also lend itself to an automated loading and unloading of transport vehicles and storage systems. The purpose of this study is to compare the physicochemical properties of briquettes made from different feedstocks. Feedstocks such as corn stover, switchgrass, prairie cord grass, sawdust, pigeon pea grass, and cotton stalk were densified using a briquetting system. Physical characterization includes particle size distribution, geometrical mean diameter (GMD, densities (bulk and true, porosity, and glass transition temperature. The compositional analysis of control and briquettes was also performed. Statistical analyses confirmed the existence of significant differences in these physical properties and chemical composition of control and briquettes. Correlation analysis confirms the contribution of lignin to bulk density and durability. Among the feedstocks tested, cotton stalk had the highest bulk density of 964 kg/m3 which is an elevenfold increase compared to control cotton stalk. Corn stover and pigeon pea grass had the highest (96.6% and lowest (61% durability.

  4. Using Populus as a lignocellulosic feedstock for bioethanol.

    Science.gov (United States)

    Porth, Ilga; El-Kassaby, Yousry A

    2015-04-01

    Populus species along with species from the sister genus Salix will provide valuable feedstock resources for advanced second-generation biofuels. Their inherent fast growth characteristics can particularly be exploited for short rotation management, a time and energy saving cultivation alternative for lignocellulosic feedstock supply. Salicaceae possess inherent cell wall characteristics with favorable cellulose to lignin ratios for utilization as bioethanol crop. We review economically important traits relevant for intensively managed biofuel crop plantations, genomic and phenotypic resources available for Populus, breeding strategies for forest trees dedicated to bioenergy provision, and bioprocesses and downstream applications related to opportunities using Salicaceae as a renewable resource. Challenges need to be resolved for every single step of the conversion process chain, i.e., starting from tree domestication for improved performance as a bioenergy crop, bioconversion process, policy development for land use changes associated with advanced biofuels, and harvest and supply logistics associated with industrial-scale biorefinery plants using Populus as feedstock. Significant hurdles towards cost and energy efficiency, environmental friendliness, and yield maximization with regards to biomass pretreatment, saccharification, and fermentation of celluloses and the sustainability of biorefineries as a whole still need to be overcome.

  5. How non-conventional feedstocks will affect aromatics technologies

    Energy Technology Data Exchange (ETDEWEB)

    Koehler, E. [Clariant Produkte (Deutschland) GmbH, Muenchen (Germany)

    2013-11-01

    The abundance of non-conventional feedstocks such as coal and shale gas has begun to affect the availability of traditional base chemicals such as propylene and BTX aromatics. Although this trend is primarily fueled by the fast growing shale gas economy in the US and the abundance of coal in China, it will cause the global supply and demand situation to equilibrate across the regions. Lower demand for gasoline and consequently less aromatics rich reformate from refineries will further tighten the aromatics markets that are expected to grow at healthy rates, however. Refiners can benefit from this trend by abandoning their traditional fuel-oriented business model and becoming producers of petrochemical intermediates, with special focus on paraxylene (PX). Cheap gas from coal (via gasification) or shale reserves is an advantaged feedstock that offers a great platform to make aromatics in a cost-competitive manner, especially in regions where naphtha is in short supply. Gas condensates (LPG and naphtha) are good feedstocks for paraffin aromatization, and methanol from coal or (shale) gas can be directly converted to BTX aromatics (MTA) or alkylated with benzene or toluene to make paraxylene. Most of today's technologies for the production and upgrading of BTX aromatics and their derivatives make use of the unique properties of zeolites. (orig.)

  6. Thermodynamics of hydrocracking and isomerization reaction of Fischer-Tropsch syncrude%费托合成油品加氢裂化异构化反应的热力学

    Institute of Scientific and Technical Information of China (English)

    吴建民; 孙启文; 张宗森; 庞利峰

    2014-01-01

    利用 Benson 基团贡献法和 ABWY 法计算了费托合成油品的标准摩尔生成焓、标准熵及摩尔定压热容等基础数据,在298-750 K,对费托合成油品加氢裂化异构化反应体系的反应焓、吉布斯自由能以及平衡常数等热力学数据进行了计算;对体系中各反应的热力学可能性与生成顺序进行了判断以及各反应的热力平衡与限度进行了分析。结果表明:费托合成油品加氢裂化异构化反应是放热反应,低温时大部分反应在热力学上均能够自发的进行,且平衡常数均较大,能够进行到较高的程度;从热力学上看,升高温度不利于加氢裂化异构化反应的进行,适宜反应温度的选择应兼顾各种反应的进行;烯烃比烷烃更容易发生加氢裂化异构化反应;所获得的热力学数据可为费托合成油品加氢裂化异构化工艺研究、反应器开发以及新型催化剂研制等提供理论依据。%The standard molar enthalpy of formation,the standard entropy and isobaric molar heat capacity of Fischer-Tropsch syncrude were estimated by Benson group contribution method and ABWY method.The enthalpy change,Gibbs free energy change and equilibrium constant of hydrocracking and isomerization reaction of Fischer-Tropsch syncrude were calculated as a function of the temperature from 298 K to 750 K.The thermodynamic possibility and formation sequences of hydrocracking and isomerization reaction of Fischer-Tropsch syncrude were judged.Meanwhile,the thermodynamic equilibrium and the limit of different reaction steps were also analyzed. The results show that the hydrocracking and isomerization reaction of Fischer-Tropsch syncrude is an exothermic reaction,most of which are spontaneous at low temperature and can reach to a deep extent.Improving the temperature is not good for hydrocracking and isomerization reaction from a thermodynamic point of view.The choice of the suitable temperature should take

  7. Feeding a sustainable chemical industry: do we have the bioproducts cart before the feedstocks horse?

    Science.gov (United States)

    Dale, Bruce E

    2017-07-20

    A sustainable chemical industry cannot exist at scale without both sustainable feedstocks and feedstock supply chains to provide the raw materials. However, most current research focus is on producing the sustainable chemicals and materials. Little attention is given to how and by whom sustainable feedstocks will be supplied. In effect, we have put the bioproducts cart before the sustainable feedstocks horse. For example, bulky, unstable, non-commodity feedstocks such as crop residues probably cannot supply a large-scale sustainable industry. Likewise, those who manage land to produce feedstocks must benefit significantly from feedstock production, otherwise they will not participate in this industry and it will never grow. However, given real markets that properly reward farmers, demand for sustainable bioproducts and bioenergy can drive the adoption of more sustainable agricultural and forestry practices, providing many societal "win-win" opportunities. Three case studies are presented to show how this "win-win" process might unfold.

  8. Short-term energy outlook, quarterly projections, first quarter 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-01-01

    The forecast period for this issue of the Outlook extends from the first quarter of 1998 through the fourth quarter of 1999. Values for the fourth quarter of 1997, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in EIA`s Weekly Petroleum Status Report) or are calculated from model simulations that use the latest exogenous information available (for example, electricity sales and generation are simulated by using actual weather data). The historical energy data, compiled in the first quarter 1998 version of the Short-Term Integrated Forecasting System (STIFS) database, are mostly EIA data regularly published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications. Minor discrepancies between the data in these publications and the historical data in this Outlook are due to independent rounding. The STIFS model is driven principally by three sets of assumptions or inputs: estimates of key macroeconomic variables, world oil price assumptions, and assumptions about the severity of weather. Macroeconomic estimates are adjusted by EIA to reflect EIA assumptions which may affect the macroeconomic outlook. By varying the assumptions, alternative cases are produced by using the STIFS model. 24 figs., 19 tabs.

  9. Short-Term Energy Outlook: Quarterly projections. Fourth quarter 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-11-05

    The Energy Information Administration (EIA) prepares quarterly, short-term energy supply, demand, and price projections for publication in February, May, August, and November in the Short-Term Energy Outlook (Outlook). An annual supplement analyzes the performance of previous forecasts, compares recent cases with those of other forecasting services, and discusses current topics related to the short-term energy markets. (See Short-Term Energy Outlook Annual Supplement, DOE/EIA-0202.) The forecast period for this issue of the Outlook extends from the fourth quarter of 1993 through the fourth quarter of 1994. Values for the third quarter of 1993, however, are preliminary EIA estimates (for example, some monthly values for petroleum supply and disposition are derived in part from weekly data reported in the Weekly Petroleum Status Report) or are calculated from model simulations using the latest exogenous information available (for example, electricity sales and generation are simulated using actual weather data). The historical energy data are EIA data published in the Monthly Energy Review, Petroleum Supply Monthly, and other EIA publications.

  10. Refining and end use study of coal liquids. Quarterly report, October--December 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-31

    Bechtel, with South west research Institute, Amoco Oil R&D, and the M. W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the US Department of Energy`s Pittsburgh Energy Technology Center to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. To enhance management of the study, the work has been divided into two parts, the Basic Program and Option 1. The objectives of the Basic Program are to: characterize the coal liquids; develop an optimized refinery configuration for processing indirect and direct coal liquids; and develop a LP refinery model with Process Industry Modeling System software. The objective of Option 1 are to: confirm the validity of the optimization work of the Basic Program; produce large quantities of liquid transportation fuel blending stocks; conduct engine emission tests; and determine the value and the processing costs of the coal liquids. The major effort conducted during the fourth quarter of 1995 were in the areas of: IL catalytic cracking--microactivity tests were conducted on various wax blends; IL wax hydrocracking--a pilot plant run was conducted on a wax/petroleum blend; and DL2 characterization and fractionation.

  11. Quarterly coal report, July--September 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-02-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1998 and aggregated quarterly historical data for 1992 through the second quarter of 1998. 58 tabs.

  12. 10 CFR 34.29 - Quarterly inventory.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 1 2010-01-01 2010-01-01 false Quarterly inventory. 34.29 Section 34.29 Energy NUCLEAR... RADIOGRAPHIC OPERATIONS Equipment § 34.29 Quarterly inventory. (a) Each licensee shall conduct a quarterly physical inventory to account for all sealed sources and for devices containing depleted uranium...

  13. Apprentices & Trainees: September Quarter, 2012

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2013

    2013-01-01

    This publication presents estimates of apprentice and trainee activity in Australia for the September quarter 2012. The figures in this publication are derived from the National Apprentice and Trainee Collection no.74 (December 2012 estimates). The most recent figures in this publication are estimated (those for training activity from the March…

  14. South African Crime Quarterly 59

    African Journals Online (AJOL)

    SA Crime QuArterly No. 59 • mArCh ... Section 77 of the Criminal Procedure Act 51 of 1977 deals with the treatment of persons who are unable to ..... resource considerations alone.36 .... membership of groups; as demonstrated in. President of ...

  15. Study of Recycled and Virgin Compounded Metal Injection Moulded Feedstock for Stainless Steel 630

    Science.gov (United States)

    Manonukul, Anchalee; Likityingwara, Warakij; Rungkiatnawin, Phataraporn; Muenya, Nattapol; Amoranan, Suttha; Kittinantapol, Witoo; Surapunt, Suphachai

    Fine rounded powders preferable for metal injection moulding (MIM) are expensive. This forces MIM makers to recycle green scraps, for example, the runner system and defected green parts. This is particularly necessary for injection moulded small parts where parts are only a small portion of the injection short size. There is very little published data, although recycling feedstock has been practise throughout the industry. This work aims at investigating the effects of recycled stainless steel 630 feedstock content on the density, mechanical properties, dimensional changes and microstructure. Five batches of compounded virgin and recycled feedstock were studies from 0% to 100% recycled feedstock with the increment of 25%. Homogenously compounded feedstock was injected using the same injection condition. Subsequently, green parts were debinded and sintered at 1325°C for 2 hours in argon atmosphere. The results suggest that the green density increases linearly with increasing percentage of recycled feedstock because the polymeric binder was broken down during previous process. However, the sintered density remains nominally constant. As a result, the mechanical properties and microstructure of sintered parts are independent of recycled feedstock content. However, the volumetric and linear shrinkage decreases linearly with the increase in percentage of recycled feedstock. The difference in shrinkage is vital to dimensional control during commercial production. For example, only 4.5% of recycled feedstock can be added to virgin feedstock if a tolerance of ±0.3 mm is required for a 25 mm MIM part.

  16. Renewable Enhanced Feedstocks for Advanced Biofuels and Bioproducts (REFABB)

    Energy Technology Data Exchange (ETDEWEB)

    Peoples, Oliver [Metabolix Inc., Cambridge, MA (United States); Snell, Kristi [Metabolix Inc., Cambridge, MA (United States)

    2016-06-09

    The basic concept of the REFABB project was that by genetically engineering the biomass crop switchgrass to produce a natural polymer PHB, which is readily broken down by heating (thermolysis) into the chemical building block crotonic acid, sufficient additional economic value would be added for the grower and processor to make it an attractive business at small scale. Processes for using thermolysis to upgrade biomass to densified pellets (char) or bio-oil are well known and require low capital investment similar to a corn ethanol facility. Several smaller thermolysis plants would then supply the densified biomass, which is easier to handle and transport to a centralized biorefinery where it would be used as the feedstock. Crotonic acid is not by itself a large volume commodity chemical, however, the project demonstrated that it can be used as a feedstock to produce a number of large volume chemicals including butanol which itself is a biofuel target. In effect the project would try to address three key technology barriers, feedstock logistics, feedstock supply and cost effective biomass conversion. This project adds to our understanding of the potential for future biomass biorefineries in two main areas. The first addressed in Task A was the importance and potential of developing an advanced value added biomass feedstock crop. In this Task several novel genetic engineering technologies were demonstrated for the first time. One important outcome was the identification of three novel genes which when re-introduced into the switchgrass plants had a remarkable impact on increasing the biomass yield based on dramatically increasing photosynthesis. These genes also turned out to be critical to increasing the levels of PHB in switchgrass by enabling the plants to fix carbon fast enough to support both plant growth and higher levels of the polymer. Challenges in the critical objective of Task B, demonstrating conversion of the PHB in biomass to crotonic acid at over 90

  17. Forest feedstocks : systems for recovery of residual biomass

    Energy Technology Data Exchange (ETDEWEB)

    MacDonald, J. [FP Innovations, Vancouver, BC (Canada). FERIC Div.

    2007-07-01

    Interest in forest feedstock is growing due to high energy costs, the need for energy self-sufficiency and climate change issues. The Mountain Pine Beetle (MPB) epidemic in British Columbia has also contributed to the growing interest in forest feedstock. This presentation discussed the potential for wood to be used for liquid fuels conversion, pellets and biorefineries. The extraction of energy from residue biomass was reviewed with reference to traditional sources such as hog fuel and black liquor, as well as new sources that consider the changing landscape. These include harvest residues, MPB-killed stands, burned stands, non-merchantable stands, and stumps. Early thinning and FireSmart treatments were outlined along with the value of purpose-grown energy plantations. The variety of available recovery methods and equipment was demonstrated, including whole-tree chippers; disc and drum chippers; grinders and shredders; overhead conveyor systems; blower attachments; and, wheel-mounted equipment. The performance of each method and equipment was reviewed along with challenges regarding the transportation of a low-value, low bulk-density material over long distances. Although residue bundlers have been developed, it was suggested that it may be more cost effective to convert the feedstock in the field using a mobile biorefinery, and then transport the denser fuel. It was shown that although a range of equipment is available, nothing has been designed specifically for full-tree residue. It was noted that coordination with conventional harvesting is desirable, but may not be possible in all cases. Lessons from studies have indicated that the distance from the mill is a major cost factor and that the debris should be prepared in advance to shipping. tabs., figs.

  18. Quarterly coal report, October--December 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for October through December 1996 and aggregated quarterly historical data for 1990 through the third quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 72 tabs.

  19. Quarterly coal report, October--December 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for October through December 1998 and aggregated quarterly historical data for 1992 through the third quarter of 1998. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. 58 tabs.

  20. Quarterly coal report, January--March 1998

    Energy Technology Data Exchange (ETDEWEB)

    Young, P.

    1998-08-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for January through March 1998 and aggregated quarterly historical data for 1992 through the fourth quarter of 1997. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the United States, historical information has been integrated in this report. 58 tabs.

  1. Quarterly coal report, April--June, 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for April through June 1998 and aggregated quarterly historical data for 1992 through the first quarter of 1998. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. 58 tabs.

  2. Estimating Biofuel Feedstock Water Footprints Using System Dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Inman, Daniel; Warner, Ethan; Stright, Dana; Macknick, Jordan; Peck, Corey

    2016-07-01

    Increased biofuel production has prompted concerns about the environmental tradeoffs of biofuels compared to petroleum-based fuels. Biofuel production in general, and feedstock production in particular, is under increased scrutiny. Water footprinting (measuring direct and indirect water use) has been proposed as one measure to evaluate water use in the context of concerns about depleting rural water supplies through activities such as irrigation for large-scale agriculture. Water footprinting literature has often been limited in one or more key aspects: complete assessment across multiple water stocks (e.g., vadose zone, surface, and ground water stocks), geographical resolution of data, consistent representation of many feedstocks, and flexibility to perform scenario analysis. We developed a model called BioSpatial H2O using a system dynamics modeling and database framework. BioSpatial H2O could be used to consistently evaluate the complete water footprints of multiple biomass feedstocks at high geospatial resolutions. BioSpatial H2O has the flexibility to perform simultaneous scenario analysis of current and potential future crops under alternative yield and climate conditions. In this proof-of-concept paper, we modeled corn grain (Zea mays L.) and soybeans (Glycine max) under current conditions as illustrative results. BioSpatial H2O links to a unique database that houses annual spatially explicit climate, soil, and plant physiological data. Parameters from the database are used as inputs to our system dynamics model for estimating annual crop water requirements using daily time steps. Based on our review of the literature, estimated green water footprints are comparable to other modeled results, suggesting that BioSpatial H2O is computationally sound for future scenario analysis. Our modeling framework builds on previous water use analyses to provide a platform for scenario-based assessment. BioSpatial H2O's system dynamics is a flexible and user

  3. Biofuel production from microalgae as feedstock: current status and potential.

    Science.gov (United States)

    Han, Song-Fang; Jin, Wen-Biao; Tu, Ren-Jie; Wu, Wei-Min

    2015-06-01

    Algal biofuel has become an attractive alternative of petroleum-based fuels in the past decade. Microalgae have been proposed as a feedstock to produce biodiesel, since they are capable of mitigating CO2 emission and accumulating lipids with high productivity. This article is an overview of the updated status of biofuels, especially biodiesel production from microalgae including fundamental research, culture selection and engineering process development; it summarizes research on mathematical and life cycle modeling on algae growth and biomass production; and it updates global efforts of research and development and commercialization attempts. The major challenges are also discussed.

  4. Biofuels Feedstock Development Program annual progress report for 1991

    Energy Technology Data Exchange (ETDEWEB)

    Wright, L.L.; Cushman, J.H.; Ehrenshaft, A.R.; McLaughlin, S.B.; McNabb, W.A.; Ranney, J.W.; Tuskan, G.A.; Turhollow, A.F.

    1992-12-01

    This report provides an overview of the ongoing research funded in 1991 by the Department of Energy's Biofuels Feedstock Development Program (BFDP). The BFDP is managed by the Environmental Sciences Division of the Oak Ridge National Laboratory and encompasses the work formerly funded by the Short Rotation Woody Crops Program and the Herbaceous Energy Crops Program. The combined program includes crop development research on both woody and herbaceous energy crop species, cross-cutting energy and environmental analysis and integration, and information management activities. Brief summaries of 26 different program activities are included in the report.

  5. Biofuels Feedstock Development Program annual progress report for 1991

    Energy Technology Data Exchange (ETDEWEB)

    Wright, L.L.; Cushman, J.H.; Ehrenshaft, A.R.; McLaughlin, S.B.; McNabb, W.A.; Ranney, J.W.; Tuskan, G.A.; Turhollow, A.F.

    1992-12-01

    This report provides an overview of the ongoing research funded in 1991 by the Department of Energy`s Biofuels Feedstock Development Program (BFDP). The BFDP is managed by the Environmental Sciences Division of the Oak Ridge National Laboratory and encompasses the work formerly funded by the Short Rotation Woody Crops Program and the Herbaceous Energy Crops Program. The combined program includes crop development research on both woody and herbaceous energy crop species, cross-cutting energy and environmental analysis and integration, and information management activities. Brief summaries of 26 different program activities are included in the report.

  6. Energy supply chain optimization of hybrid feedstock processes: a review.

    Science.gov (United States)

    Elia, Josephine A; Floudas, Christodoulos A

    2014-01-01

    The economic, environmental, and social performances of energy systems depend on their geographical locations and the surrounding market infrastructure for feedstocks and energy products. Strategic decisions to locate energy conversion facilities must take all upstream and downstream operations into account, prompting the development of supply chain modeling and optimization methods. This article reviews the contributions of energy supply chain studies that include heat, power, and liquid fuels production. Studies are categorized based on specific features of the mathematical model, highlighting those that address energy supply chain models with and without considerations of multiperiod decisions. Studies that incorporate uncertainties are discussed, and opportunities for future research developments are outlined.

  7. Development of feedstock of tungsten-nickel-iron- polyformaldehyde for MIM technology

    Science.gov (United States)

    Kostin, D. V.; Parkhomenko, A. V.; Amosov, A. P.; Samboruk, A. R.; Chemashkin, A. V.

    2016-11-01

    The article presents the results of the research and development of technology and formulation of the feedstock from domestic metal powders and polymers to fabricate complexshaped components from heavy alloy of VNZh 7-3 brand (90 wt. % tungsten - 7% nickel - 3% iron) by Metal Injection Molding (MIM technology). The metal part of the feedstock is composed of powders of tungsten, nickel and iron, and the polymer part is composed of polyformaldehyde with the addition of low-density polyethylene and beeswax. The modes of mixing the components and the influence of the composition of the feedstock on the melt flow rate and the homogeneity of the feedstock were investigated. The optimal formulation of the feedstock was determined. Microstructure, density and hardness of control samples fabricated by MIM technology from the developed feedstock, correspond to, and in some respects are superior to the samples of VNZh 7-3 alloy fabricated by technology of traditional powder metallurgy.

  8. Increasing Feedstock Production for Biofuels: Economic Drivers, Environmental Implications, and the Role of Research

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2009-10-27

    The Biomass Research and Development Board (Board) commissioned an economic analysis of feedstocks to produce biofuels. The Board seeks to inform investments in research and development needed to expand biofuel production. This analysis focuses on feedstocks; other interagency teams have projects underway for other parts of the biofuel sector (e.g., logistics). The analysis encompasses feedstocks for both conventional and advanced biofuels from agriculture and forestry sources.

  9. Alternative Feedstocks Program Technical and Economic Assessment: Thermal/Chemical and Bioprocessing Components

    Energy Technology Data Exchange (ETDEWEB)

    Bozell, J. J.; Landucci, R.

    1993-07-01

    This resource document on biomass to chemicals opportunities describes the development of a technical and market rationale for incorporating renewable feedstocks into the chemical industry in both a qualitative and quantitative sense. The term "renewable feedstock?s" can be defined to include a huge number of materials such as agricultural crops rich in starch, lignocellulosic materials (biomass), or biomass material recovered from a variety of processing wastes.

  10. Ligncellulosic feedstock supply systems with intermodal and overseas transportation

    Energy Technology Data Exchange (ETDEWEB)

    Ric Hoefnagels; Kara Cafferty; Erin Searcy; Jacob J. Jacobson; Martin Junginger; Thijs Cornelissen; Andre Faaij

    2014-12-01

    With growing demand for biomass from industrial uses and international trade, the logistic operations required to economically move the biomass from the field or forest to the end users have become increasingly complex. In addition to economics, understanding energy and GHG emissions is required to design cost effective, sustainable logistic process operations; in order to improve international supply chains it is also important to understate their interdependencies and related uncertainties. This article presents an approach to assess lignocellulosic feedstock supply systems at the operational level. For this purpose, the Biomass Logistic Model (BLM) has been linked with the Geographic Information Systems based Biomass Intermodal Transportation model (BIT-UU) and extended with inter-continental transport routes. Case studies of herbaceous and woody biomass, produced in the U.S. Midwest and U.S. Southeast, respectively, and shipped to Europe for conversion to Fischer-Tropsch (FT) diesel are included to demonstrate how intermodal transportation and, in particular, overseas shipping integrates with the bioenergy supply chains. For the cases demonstrated, biomass can be supplied at 99 € Mg-1 to 117 € Mg-1 (dry) and converted to FT-diesel at 19 € GJ-1 to 24 € GJ-1 depending on the feedstock type and location, intermediate (chips or pellets) and size of the FT-diesel production plant. With the flexibility to change the design of supply chains as well as input variables, many alternative supply chain cases can be assessed.

  11. Evaluation of attached periphytical algal communities for biofuel feedstock generation

    Energy Technology Data Exchange (ETDEWEB)

    Sandefur, H.N.; Matlock, M.D.; Costello, T.A. [Arkansas Univ., Division of Agriculture, Fayetteville, AR (United States). Dept. of Biological and Agricultural Engineering, Center for Agricultural and Rural Sustainability

    2010-07-01

    This paper reported on a study that investigated the feasibility of using algal biomass as a feedstock for biofuel production. Algae has a high lipid content, and with its high rate of production, it can produce more oil on less land than traditional bioenergy crops. In addition, algal communities can remove nutrients from wastewater. Enclosed photobioreactors and open pond systems are among the many different algal growth systems that can be highly productive. However, they can also be difficult to maintain. The objective of this study was to demonstrate the ability of a pilot scale algal turf scrubber (ATS) to facilitate the growth of attached periphytic algal communities for the production of biomass feedstock and the removal of nutrients from a local stream in Springdale, Arizona. The ATS operated for a 9 month sampling period, during which time the system productivity averaged 26 g per m{sup 2} per day. The removal of total phosphorus and total nitrogen averaged 48 and 13 per cent, respectively.

  12. Biodiesel production with microalgae as feedstock: from strains to biodiesel.

    Science.gov (United States)

    Gong, Yangmin; Jiang, Mulan

    2011-07-01

    Due to negative environmental influence and limited availability, petroleum-derived fuels need to be replaced by renewable biofuels. Biodiesel has attracted intensive attention as an important biofuel. Microalgae have numerous advantages for biodiesel production over many terrestrial plants. There are a series of consecutive processes for biodiesel production with microalgae as feedstock, including selection of adequate microalgal strains, mass culture, cell harvesting, oil extraction and transesterification. To reduce the overall production cost, technology development and process optimization are necessary. Genetic engineering also plays an important role in manipulating lipid biosynthesis in microalgae. Many approaches, such as sequestering carbon dioxide from industrial plants for the carbon source, using wastewater for the nutrient supply, and maximizing the values of by-products, have shown a potential for cost reduction. This review provides a brief overview of the process of biodiesel production with microalgae as feedstock. The methods associated with this process (e.g. lipid determination, mass culture, oil extraction) are also compared and discussed.

  13. Biofuels feedstock development program. Annual progress report for 1992

    Energy Technology Data Exchange (ETDEWEB)

    Wright, L.L.; Cushman, J.H.; Ehrenshaft, A.R.; McLaughlin, S.B.; McNabb, W.A.; Martin, S.A.; Ranney, J.W.; Tuskan, G.A.; Turhollow, A.F.

    1993-11-01

    The Department of Energy`s (DOE`s) Biofuels Feedstock Development Program (BFDP) leads the nation in the research, development, and demonstration of environmentally acceptable and commercially viable dedicated feedstock supply systems (DFSS). The purpose of this report is to highlight the status and accomplishments of the research that is currently being funded by the BFDP. Highlights summarized here and additional accomplishments are described in more detail in the sections associated with each major program task. A few key accomplishments include (1) development of a methodology for doing a cost-supply analysis for energy crops and the application of that methodology to looking at possible land use changes around a specific energy facility in East Tennessee; (2) preliminary documentation of the relationship between woody crop plantation locations and bird diversity at sites in the Midwest, Canada, and the pacific Northwest supplied indications that woody crop plantations could be beneficial to biodiversity; (3) the initiation of integrated switchgrass variety trials, breeding research, and biotechnology research for the south/southeast region; (4) development of a data base management system for documenting the results of herbaceous energy crop field trials; (5) publication of three issues of Energy Crops Forum and development of a readership of over 2,300 individuals or organizations as determined by positive responses on questionnaires.

  14. Security of feedstocks supply for future bio-ethanol production in Thailand

    Energy Technology Data Exchange (ETDEWEB)

    Silalertruksa, Thapat; Gheewala, Shabbir H. [The Joint Graduate School of Energy and Environment, King Mongkut' s University of Technology Thonburi, 126 Prachauthit Road, Bangkok 10140 (Thailand)

    2010-11-15

    This study assesses the security of feedstock supply to satisfy the increased demand for bio-ethanol production based on the recent 15 years biofuels development plan and target (year 2008-2022) of the Thai government. Future bio-ethanol systems are modeled and the feedstock supply potentials analyzed based on three scenarios including low-, moderate- and high-yields improvement. The three scenarios are modeled and key dimensions including availability; diversity; and environmental acceptability of feedstocks supply in terms of GHG reduction are evaluated through indicators such as net feedstock balances, Shannon index and net life cycle GHG emissions. The results show that only the case of high yields improvement scenario can result in a reliable and sufficient supply of feedstocks to satisfy the long-term demands for bio-ethanol and other related industries. Cassava is identified as the critical feedstock and a reduction in cassava export is necessary. The study concludes that to enhance long-term security of feedstocks supply for sustainable bio-ethanol production in Thailand, increasing use of sugarcane juice as feedstock, improved yields of existing feedstocks and promoting production of bio-ethanol derived from agricultural residues are three key recommendations that need to be urgently implemented by the policy makers. (author)

  15. Strategic Studies Quarterly- Spring 2016

    Science.gov (United States)

    2016-01-01

    Khyber Pakhtunkhwa, bordering Afghanistan. A number of analysts agree that if conflict breaks out with India, Pakistan would immediately rede - ploy...the military should not risk its capacity to fight just to become an instrument of social progress but at the same rook pride in ending the...the " social experiments" conducted during his tenure are not yet known. The former Secretary STRATEGIC STUDIES QuARTERLY + SPRING 2016 [ 149] Book

  16. Coal liquefaction. Quarterly report, January--March 1978. [Brief summary of 15 pilot plant projects supported by US DOE

    Energy Technology Data Exchange (ETDEWEB)

    1978-09-01

    The advantage of coal liquefaction is that the entire range of liquid products, including heavy boiler fuel, distillate fuel oil, gasoline, jet fuel, and diesel oil, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquids have the potential for use as chemical feedstocks. To provide efficient and practical means of utilizing coal resources, DOE is sponsoring the development of several conversion processes currently in the pilot plant stage. Fifteen coal liquefaction projects supported by US DOE are described briefly, with flowsheets, funding, history and progress during the quarter. (LTN)

  17. Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane

    Science.gov (United States)

    Gordon, John Howard; Alvare, Javier

    2016-09-13

    A reactor has two chambers, namely an oil feedstock chamber and a source chamber. An ion separator separates the oil feedstock chamber from the source chamber, wherein the ion separator allows alkali metal ions to pass from the source chamber, through the ion separator, and into the oil feedstock chamber. A cathode is at least partially housed within the oil feedstock chamber and an anode is at least partially housed within the source chamber. A quantity of an oil feedstock is within the oil feedstock chamber, the oil feedstock comprising at least one carbon atom and a heteroatom and/or one or more heavy metals, the oil feedstock further comprising naphthenic acid. When the alkali metal ion enters the oil feedstock chamber, the alkali metal reacts with the heteroatom, the heavy metals and/or the naphthenic acid, wherein the reaction with the alkali metal forms inorganic products.

  18. Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, John Howard; Alvare, Javier

    2016-09-13

    A reactor has two chambers, namely an oil feedstock chamber and a source chamber. An ion separator separates the oil feedstock chamber from the source chamber, wherein the ion separator allows alkali metal ions to pass from the source chamber, through the ion separator, and into the oil feedstock chamber. A cathode is at least partially housed within the oil feedstock chamber and an anode is at least partially housed within the source chamber. A quantity of an oil feedstock is within the oil feedstock chamber, the oil feedstock comprising at least one carbon atom and a heteroatom and/or one or more heavy metals, the oil feedstock further comprising naphthenic acid. When the alkali metal ion enters the oil feedstock chamber, the alkali metal reacts with the heteroatom, the heavy metals and/or the naphthenic acid, wherein the reaction with the alkali metal forms inorganic products.

  19. Renewable fuels as feedstocks in industrial organic chemistry; Nachwachsende Rohstoffe als Feedstock in der industriellen organischen Chemie

    Energy Technology Data Exchange (ETDEWEB)

    Marquardt, J.

    1995-10-01

    Fossil fuels are used in the chemical industry for providing process energy but primarily as chemical feedstocks. In view of the necessity ofsaving fossil resources and reducing anthropogenic greenhouse gas emissions, the author investigates inhowfar renewable fuels may serve as substitutes for the fossil carbon carriers now used in the chemical industry. He starts with a bibliographic research which also takes account of studies on the uses of biomass for power generation. On this basis, an outline of current production processes (including specific data for cultivation and processing), production volumes and consumption structures is given for the main types of renewable raw materials (sugar, starch, cellulose and vegetable fats and oils). (orig./SR) [Deutsch] Fossile Energietraeger werden in der chemischen Industrie ausser zur Bereitstellung von Prozessenergie vor allem nichtenergetisch, d.h. als chemische Rohstoffe (sog. Feedstock), eingesetzt. Angesichts der Notwendigkeit, die fossilen Rohstoffvorraete zu schonen und die anthropogenen Klimagasemissionen zu vermindern, stellt sich die Frage, inwieweit nachwachsende Rohstoffe die im Chemiesektor fuer nichtenergetische Zwecke eingesetzten fossilen Kohlenstofftraeger ersetzen koennen. Im Rahmen der Studienarbeit soll zunaechst eine Literaturrecherche zu diesem Themenkomplex durchgefuehrt werden, wobei auch Untersuchungen zur energetischen Nutzung von Biomasse zu beruecksichtigen sind. Auf dieser Basis soll fuer die Haupttypen nachwachsender Rohstoffe (Zucker, Staerke, Cellulose und pflanzliche Fette/Oele) ein Ueberblick zu den heutigen Produktionsverfahren (inkl. Anbau- und verarbeitungsspezifischer Daten), Produktionsmengen und Verbrauchsstrukturen gegeben werden. (orig./SR)

  20. Coal liquefaction. Quarterly report, April-June 1979

    Energy Technology Data Exchange (ETDEWEB)

    None

    1980-04-01

    DOE's program for the conversion of coal to liquid fuels was begun by two of DOE's predecessor agencies: Office of Coal Research (OCR) in 1962, and Bureau of Mines, US Department of the Interior, in the 1930's. Current work is aimed at improved process configurations for both catalytic and non-catalytic processes to provide more attractive processing economics and lower capital investment. The advantage of coal liquefaction is that the entire range of liquid products, especially boiler fuel, distillate fuel oil, and gasoline, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquids have the potential for use as chemical feedstocks. To provide efficient and practical means of utilizing coal resources, DOE is supporting the development of several conversion processes that are currently in the pilot plant stage. DOE, together with the Electric Power Research Institue, has contracted with fourteen projects are described brieflly: funding, description, status, history, and progress in the current quarter. (LTN)

  1. Coal demonstration plants. Quarterly report, July--September 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-02-01

    The objective of DOE's demonstration plant program is to establish the technical and financial feasibility of coal conversion technologies proven during pilot plant testing. Demonstration plants will minimize the technical and economic risks of commercialization by providing a near commercial size plant for testing and production. Thus, DOE is sponsoring the development of a series of demonstration plants, each of which will be a smaller version of commercial plants envisioned for the 1980's. These plants will be wholly integrated, self-sufficient in terms of heat generation, and dependent only on feedstock of coal, water, and air. Contracts for designing, constructing, and operating the demonstration plants will be awarded through competitive procedures and will be jointly funded. The conceptual design phase will be funded by the government, with the detailed design, procurement, construction, and operation phases being co-funded, 50% from industry and 50% from the government. The cost involved in building and operating a demonstration plant will probably be between $200 million and $500 million, depending on the size of the plant. Twenty-two projects involving demonstration plants or support projects for such plants are reviewed, including a summary for each of progress in the quarter. (LTN)

  2. Coal demonstration plants. Quarterly report, April--June 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-01-01

    The objective of DOE's demonstration plant program is to establish the technical and financial feasibility of coal conversion technologies proven during pilot plant testing. Demonstration plants will minimize the technical and economic risks of commercialization by providing a near commercial size plant for testing and production. Thus, DOE is sponsoring the development of a series of demonstration plants, each of which will be a smaller version of commercial plants envisioned for the 1980's. These plants will be wholly integrated, self-sufficient in terms of heat generation, and dependent only on feedstock of coal, water, and air. Under the DOE program, contracts for designing, constructing, and operating the demonstration plants will be awarded through competitive procedures and will be jointly funded. The conceptual design phase will be funded by the government, with the detailed design, procurement, construction, and operation phases being co-funded, 50% from industry and 50% from the government. The cost involved in building and operating a demonstration plant will probably be between $200 million and $500 million, depending on the size of the plant. Six of these demonstration plant projects are described and progress in the quarter is summarized. Several support and complementary projects are described (fuel feeding system development, performance testing and comparative evaluation, engineering support, coal grinding equipment development and a critical components test facility). (LTN)

  3. Coal demonstration plants. Quarterly report, January--March 1978

    Energy Technology Data Exchange (ETDEWEB)

    1978-09-01

    The Department of Energy's demonstration plant program was started in 1974 by one of the Department of Energy's predecessor agencies, the Office of Coal Research, US Department of the Interior. The objective of the program is to establish the technical and financial feasibility of coal conversion technologies proven during pilot plant testing. Demonstration plants will minimize the technical and economic risks of commercialization by providing a near commercial size plant for testing and production. Thus, DOE is sponsoring the development of a series of demonstration plants, each of which will be a smaller version of commercial plants envisioned for the 1980's. These plants will be wholly integrated, self-sufficient in terms of heat generation, and dependent only on feedstock of coal, water, and air. Under the DOE program, contracts for designing, constructing, and operating the demonstration plants will be awarded through competitive procedures and will be jointly funded. The conceptual design phase will be funded by the government, with the detailed design, procurement, construction, and operation phases being co-funded, 50% from industry and 50% from the government. The cost involved in building and operating a demonstration plant will probably be between $200 million and $500 million, depending on the size of the plant. Seventeen projects in this program are discussed briefly with identification of the company involved, funding, flow sheets, history and progress during the quarter. (LTN)

  4. Climatic impacts of managed landscapes for sustainable biofuel feedstocks production.

    Science.gov (United States)

    Gelfand, I.; Kravchenko, A. N.; Hamilton, S. K.; Jackson, R. D.; Thelen, K.; Robertson, G. P.

    2016-12-01

    Sustainable production of biofuels cannot be achieved without multiple-use landscapes where food, feed, and fuel can be co-produced without environmental harm. Here we use field level measurements in seven biofuel feedstock production systems grown under similar climatic conditions, but on different soils in two Midwestern (USA) states to understand their relative climatic impacts. We studied annual corn stover, and 6 perennial ecosystems including three polycultures: successional vegetation, restored prairie and a 3-species grass mix; and 3 monocultures: poplar, switchgrass, and miscanthus. All studied ecosystems were grown in replicated plots on moderately fertile soils of SW Michigan and highly fertile soils of central Wisconsin. We measured components of greenhouse gas (GHG) balances over 6 years. On the fertile soil perennial monocultures had GHG emission reductions potentials of 53% relative to fossil fuels, while polycultures had 64% reduction; corn stover had an 84% emissions reduction. Net sequestration ranged from 0.6 MgCO2e ha-1yr-1 (successional vegetation) to 3.1 MgCO2e ha-1yr-1, (corn stover). Among feedstocks produced on less fertile soils, perennial monocultures had GHG emissions reduction of 80%, and polycultures had emission reduction of 54%; miscanthus and poplar exhibited the largest sequestration potentials of 5.9 and 3.9 MgCO2e ha-1yr-1 respectively, while polycultures sequestered less then 1.0 MgCO2e ha-1yr-1 on average and corn stover was intermediate with 1.4 MgCO2e ha-1yr-1. All studied systems averaged energy production of 30 GJ ha-1 yr-1, except miscanthus (71 GJ ha-1 yr-1) and successional vegetation (20 GJ ha-1 yr-1). Our results inform the design of multiple-use landscapes: more fertile soils could produce food and feed with residuals collected for bioethanol production and more marginal soils could be used for various poly- or mono-cultures of purpose grown biofuel feedstocks but with differential climate benefits.

  5. Quarterly coal report, October--December 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-23

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1994 and aggregated quarterly historical data for 1986 through the third quarter of 1994. Appendix A displays, from 1986 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  6. Quarterly coal report, January--March 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-24

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for January through March 1995 and aggregated quarterly historical data for 1987 through the fourth quarter of 1994. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  7. Quarterly coal report, October--December 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-05-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities. This report presents detailed quarterly data for october through December 1997 and aggregated quarterly historical data for 1991 through the third quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data, as specified in Section 202 of the energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 73 tabs.

  8. Quarterly coal report, January--March 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-08-24

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for January through March 1994 and aggregated quarterly historical data for 1986 through the fourth quarter of 1993. Appendix A displays, from 1986 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  9. Short-term energy outlook, quarterly projections, second quarter 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-04-01

    The Energy Information Administration (EIA) prepares quarterly short-term energy supply, demand, and price projections. The details of these projections, as well as monthly updates, are available on the Internet at: www.eia.doe.gov/emeu/steo/pub/contents.html. The paper discusses outlook assumptions; US energy prices; world oil supply and the oil production cutback agreement of March 1998; international oil demand and supply; world oil stocks, capacity, and net trade; US oil demand and supply; US natural gas demand and supply; US coal demand and supply; US electricity demand and supply; US renewable energy demand; and US energy demand and supply sensitivities. 29 figs., 19 tabs.

  10. Applied Meteorology Unit (AMU) Quarterly Report - Fourth Quarter FY-09

    Science.gov (United States)

    Bauman, William; Crawford, Winifred; Barrett, Joe; Watson, Leela; Wheeler, Mark

    2009-01-01

    This report summarizes the Applied Meteorology Unit (AMU) activities for the fourth quarter of Fiscal Year 2009 (July - September 2009). Tasks reports include: (1) Peak Wind Tool for User Launch Commit Criteria (LCC), (2) Objective Lightning Probability Tool. Phase III, (3) Peak Wind Tool for General Forecasting. Phase II, (4) Update and Maintain Advanced Regional Prediction System (ARPS) Data Analysis System (ADAS), (5) Verify MesoNAM Performance (6) develop a Graphical User Interface to update selected parameters for the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLlT)

  11. Applied Meteorology Unit (AMU) Quarterly Report Third Quarter FY-08

    Science.gov (United States)

    Bauman, William; Crawford, Winifred; Barrett, Joe; Watson, Leela; Dreher, Joseph

    2008-01-01

    This report summarizes the Applied Meteorology Unit (AMU) activities for the third quarter of Fiscal Year 2008 (April - June 2008). Tasks reported on are: Peak Wind Tool for User Launch Commit Criteria (LCC), Anvil Forecast Tool in AWIPS Phase II, Completion of the Edward Air Force Base (EAFB) Statistical Guidance Wind Tool, Volume Averaged Height Integ rated Radar Reflectivity (VAHIRR), Impact of Local Sensors, Radar Scan Strategies for the PAFB WSR-74C Replacement, VAHIRR Cost Benefit Analysis, and WRF Wind Sensitivity Study at Edwards Air Force Base

  12. Coffee oil as a potential feedstock for biodiesel production.

    Science.gov (United States)

    Oliveira, Leandro S; Franca, Adriana S; Camargos, Rodrigo R S; Ferraz, Vany P

    2008-05-01

    A preliminary evaluation of the feasibility of producing biodiesel using oil extracted from defective coffee beans was conducted as an alternative means of utilizing these beans instead of roasting for consumption of beverage with depreciated quality. Direct transesterifications of triglycerides from refined soybean oil (reference) and from oils extracted from healthy and defective coffee beans were performed. Type of alcohol employed and time were the reaction parameters studied. Sodium methoxide was used as alkaline catalyst. There was optimal phase separation after reactions using both soybean and healthy coffee beans oils when methanol was used. This was not observed when using the oil from defective beans which required further processing to obtain purified alkyl esters. Nevertheless, coffee oil was demonstrated to be a potential feedstock for biodiesel production, both from healthy and defective beans, since the corresponding oils were successfully converted to fatty acid methyl and ethyl esters.

  13. Arid lands plants as feedstocks for fuels and chemicals

    Energy Technology Data Exchange (ETDEWEB)

    Hoffmann, J.J.

    1983-01-01

    The purpose of this paper is to review the recent research on arid-adapted plants that have potential as producers of fuels or chemicals. The major focus will be on plant species that appear to have commercial value. Research on guayule (Parthenium argentatum) and jojoba (Simmondsia chinensis) will be mentioned only briefly, since these plants have been discussed extensively in the literature, and excellent reviews are already in existence. In this review the literature on arid-adapted plants that have potential uses for solid fuels, liquid fuels, and chemical feedstocks is summarized, followed by an overview of the research directions and types of development that are needed in order for bio-energy production systems to reach the commercial stage. 127 references.

  14. Study on the Adaptability of Etheriifcation Feedstock to Reactor Type

    Institute of Scientific and Technical Information of China (English)

    Mao Junyi; Yuan Qing; Wang Lei; Huang Tao

    2016-01-01

    A reactive C5 oleifns and methanol etheriifcation kinetic model based on E-R mechanism was established and three different types of reactors including the adiabatic ifxed-bed liquid reactor, the external loop reactor and the mixed-phase reactor were constructed by Aspen Plus. The adaptability of reactive C5 oleifns to these reactors was studied and simulated using various gasoline fractions with different oleifns content. After the theoretical model was validated by the experimental data of the etheriifcation of three C5 light cut fractions from different gasoline sources in different reactors, the simulated isoamylene conversion with reactive C5 olefin contents increasing from 10% to 60% was studied in the three different types of reactors for etheriifcation with methanol, respectively. Test results show that there is an obvious adaptability of the feedstock composition to the reactor type to achieve a high conversion.

  15. New Zealand Coals - A Potential Feedstock for Deep Microbial Life

    DEFF Research Database (Denmark)

    Glombitza, Clemens

    2010-01-01

    a broad and almost continuous maturity range representing diagenetic to catagenetic coalification levels were investigated to estimate their feedstock potential for deep microbial life using a novel developed analytical procedure to analyse kerogen-bound LMWOAs liberated by selective chemical degradation...... maturation leading to more sterically protected kerogen-bound LMWOAs and, therefore, to a slower substrate release with ongoing maturation. Additional information about the structure of the macromolecular network were obtained by selective ether-cleavage procedure revealing that aliphatic alcohols with more...... than one hydroxy groups represent important cross-linkage structures. In contrast to the terminal ether-bound monoalcohols which show a rapid decrease during diagenetic alteration, these compounds show relatively high concentrations even in the more mature coals suggesting that these cross-link bridges...

  16. Biorefining of lignocellulosic feedstock--Technical, economic and environmental considerations.

    Science.gov (United States)

    Luo, Lin; van der Voet, Ester; Huppes, Gjalt

    2010-07-01

    Biorefinery, an example of a multiple products system, integrates biomass conversion processes and equipment to produce fuels, power and chemicals from biomass. This study focuses on technical design, economic and environmental analysis of a lignocellulosic feedstock (LCF) biorefinery producing ethanol, succinic acid, acetic acid and electricity. As the potential worldwide demand of succinic acid and its derivatives can reach 30 million tons per year, succinic acid is a promising high-value product if production cost and market price are substantially lowered. The results of the economic analysis show that the designed refinery has great potentials compared to the single-output ethanol plant; even when the price of succinic acid is lowered or the capital investment doubled. In terms of eco-efficiency, the LCF biorefinery shows better environmental performances mainly in global warming potential due to CO(2) fixation during acid fermentation. The overall evaluation of the eco-efficiency depends on the importance attached to each impact category.

  17. Sweet sorghum as biofuel feedstock: recent advances and available resources.

    Science.gov (United States)

    Mathur, Supriya; Umakanth, A V; Tonapi, V A; Sharma, Rita; Sharma, Manoj K

    2017-01-01

    Sweet sorghum is a promising target for biofuel production. It is a C4 crop with low input requirements and accumulates high levels of sugars in its stalks. However, large-scale planting on marginal lands would require improved varieties with optimized biofuel-related traits and tolerance to biotic and abiotic stresses. Considering this, many studies have been carried out to generate genetic and genomic resources for sweet sorghum. In this review, we discuss various attributes of sweet sorghum that make it an ideal candidate for biofuel feedstock, and provide an overview of genetic diversity, tools, and resources available for engineering and/or marker-assisting breeding of sweet sorghum. Finally, the progress made so far, in identification of genes/quantitative trait loci (QTLs) important for agronomic traits and ongoing molecular breeding efforts to generate improved varieties, has been discussed.

  18. Development of a lactic acid production process using lignocellulosic biomass as feedstock

    NARCIS (Netherlands)

    Pol, van der E.C.

    2016-01-01

    The availability of crude oil is finite. Therefore, an alternative feedstock has to be found for the production of fuels and plastics. Lignocellulose is such an alternative feedstock. It is present in large quantities in agricultural waste material such as sugarcane bagasse. In this PhD thesis, lign

  19. The effect of aqueous ammonia soaking pretreatment on methane generation uing different lignocellulosic feedstocks

    DEFF Research Database (Denmark)

    Antonopoulou, Georgia; Jonuzaj, Suela; Gavala, Hariklia N.

    2014-01-01

    Lignocellulosic biomass including agricultural and forestry residues, perennial crops, softwoods and hardwoods, can be used as feedstock for methane production. Although being abundant and almost zero cost feedstocks, the main obstacles of their use are the low efficiencies and yields attained, due...

  20. Thermo-chemical and biological conversion potential of various biomass feedstocks to ethanol

    Science.gov (United States)

    The goal of this study is to evaluate the potential and the economy of producing ethanol from gasification-fermentation of various biomass feedstocks. The biomass feedstocks include winter cover crops (wheat, rye, clover, hairy betch), summer cover crop (sunhemp), chicken litter, and woody biomass. ...

  1. Systems and processes for conversion of ethylene feedstocks to hydrocarbon fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lilga, Michael A.; Hallen, Richard T.; Albrecht, Karl O.; Cooper, Alan R.; Frye, John G.; Ramasamy, Karthikeyan Kallupalayam

    2017-05-30

    Systems, processes, and catalysts are disclosed for obtaining fuel and fuel blends containing selected ratios of open-chain and closed-chain fuel-range hydrocarbons suitable for production of alternate fuels including gasolines, jet fuels, and diesel fuels. Fuel-range hydrocarbons may be derived from ethylene-containing feedstocks and ethanol-containing feedstocks.

  2. Technology for biomass feedstock production in southern forests and GHG implications

    Science.gov (United States)

    Bob Rummer; John Klepac; Jason Thompson

    2012-01-01

    Woody biomass production in the South can come from four distinct feedstocks - logging residues, thinnings, understory harvesting, or energywood plantations. A range of new technology has been developed to collect, process and transport biomass and a key element of technology development has been to reduce energy consumption. We examined three different woody feedstock...

  3. Nitrous oxide emission and soil carbon sequestration from herbaceous perennial biofuel feedstocks

    Science.gov (United States)

    Greenhouse gas (GHG) mitigation and renewable, domestic fuels are needed in the United States. Switchgrass (Panicum virgatum L.) and big bluestem (Andropogon gerdardii Vitman) are potential bioenergy feedstocks that may meet this need. However, managing perennial grasses for feedstock requires nitro...

  4. Methods for determination of biomethane potential of feedstocks: a review

    Directory of Open Access Journals (Sweden)

    Raphael Muzondiwa Jingura

    2017-06-01

    Full Text Available Biogas produced during anaerobic digestion (AD of biodegradable organic materials. AD is a series of biochemical reactions in which microorganisms degrade organic matter under anaerobic conditions. There are many biomass resources that can be degraded by AD to produce biogas. Biogas consists of methane, carbon dioxide, and trace amounts of other gases. The gamut of feedstocks used in AD includes animal manure, municipal solid waste, sewage sludge, and various crops. Several factors affect the potential of feedstocks for biomethane production. The factors include nutrient content, total and volatile solids (VS content, chemical and biological oxygen demand, carbon/nitrogen ratio, and presence of inhibitory substances. The biochemical methane potential (BMP, often defined as the maximum volume of methane produced per g of VS substrate provides an indication of the biodegradability of a substrate and its potential to produce methane via AD. The BMP test is a method of establishing a baseline for performance of AD. BMP data are useful for designing AD parameters in order to optimise methane production. Several methods which include experimental and theoretical methods can be used to determine BMP. The objective of this paper is to review several methods with a special focus on their advantages and disadvantages. The review shows that experimental methods, mainly the BMP test are widely used. The BMP test is credited for its reliability and validity. There are variants of BMP assays as well. Theoretical models are alternative methods to estimate BMP. They are credited for being fast and easy to use. Spectroscopy has emerged as a new experimental tool to determine BMP. Each method has its own advantages and disadvantages with reference to efficacy, time, and ease of use. Choosing a method to use depends on various exigencies. More work needs to be continuously done in order to improve the various methods used to determine BMP.

  5. Sorghum as Dry Land Feedstock for Fuel Ethanol Production

    Institute of Scientific and Technical Information of China (English)

    WANG Donghai; WU Xiaorong

    2010-01-01

    Dry land crops such as sorghums(grain sorghum,sweet sorghum and forage sorghum)have been identified aspromising feedstocks for fuel ethanol production.The major issue for using the sweet sorghum as feedstock is its stability at room temperature.At room temperature,the sweet sorghum juice could lose from 40%to50%of its fermentable sugars from 7to14 days.No significant sugar content and profile changes were observed in juice stored at refrigerator temperature in two weeks.Ethanolfermentation efficiencies of fresh and frozen juice were high(-93%).Concentrated juice(≥25%sugar)had significantly lower efficiencies and large amounts of fructose left in finished beer; however,winery yeast strains and novel fermentation techniques maysolve these problems.The ethanol yield from sorghum grain increased as starch content increased.No linear relationship betweenstarch content and fermentation efficiency was found.Key factors affecting the ethanol fermentation efficiency of sorghum includestarches and protein digestibility,amylose-lipid complexes,tannin content,and mash viscosity.Life cycle analysis showed a positivenet energy value(NEV)=25 500 Btu/gal ethanol.Fourier transform infrared(FTIR)spectroscopy and X-ray diffraction(XRD)were used to determine changes in the structure and chemical composition of sorghum biomasses.Dilute sulfuric acid pretreatment waseffective in removing the hemicellulose from biomasses and exposing the cellulose for enzymatic hydrolysis.Forage sorghum ligninhad a lower syringyl/guaiacyl ratio and its pretreated biomass was easier to hydrolyze.Up to 72% hexose yield and 94% pentoseyield were obtained by using a modified steam explosion with 2% sulfuric acid at 140"C for 30 min and enzymatic hydrolysis withcellulase.

  6. Quarterly coal report, April--June 1990

    Energy Technology Data Exchange (ETDEWEB)

    1990-11-02

    The Quarterly Coal Report provides comprehensive information about US coal production, exports, imports, receipts, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. This issue presents detailed quarterly data for April 1990 through June 1990, aggregated quarterly historical data for 1982 through the second quarter of 1990, and aggregated annual historical data for 1960 through 1989 and projected data for selected years from 1995 through 2010. To provide a complete picture of coal supply and demand in the United States, historical information and forecasts have been integrated in this report. 7 figs., 37 tabs.

  7. An alternative feedstock of corn meal for industrial fuel ethanol production: delignified corncob residue.

    Science.gov (United States)

    Lei, Cheng; Zhang, Jian; Xiao, Lin; Bao, Jie

    2014-09-01

    Delignified corncob residue is an industrial solid waste from xylose production using corncob as feedstock. In this study, delignified corncob residue was used as the feedstock of ethanol production by simultaneous saccharification and fermentation (SSF) and the optimal fermentation performance was investigated under various operation conditions. The ethanol titer and yield reached 75.07 g/L and 89.38%, respectively, using a regular industrial yeast strain at moderate cellulase dosage and high solids loading. A uniform SSF temperature of 37°C at both prehydrolysis and SSF stages was tested. The fermentation performance and cost of delignified corncob residue and corn meal was compared as feedstock of ethanol fermentation. The result shows that the delignified corncob residue is competitive to corn meal as ethanol production feedstock. The study gives a typical case to demonstrate the potential of intensively processed lignocellulose as the alternative feedstock of corn meal for industrial fuel ethanol production.

  8. Method for estimating processability of a hydrocarbon-containing feedstock for hydroprocessing

    Science.gov (United States)

    Schabron, John F; Rovani, Jr., Joseph F

    2014-01-14

    Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitates asphaltenes. Determined parameters and processabilities for a plurality of feedstocks can be used to generate a mathematical relationship between parameter and processability; this relationship can be used to estimate the processability for hydroprocessing for a feedstock of unknown processability.

  9. Chemical Preconversion: Application of Low-Severity Pretreatment Chemistries for Commoditization of Lignocellulosic Feedstock

    Energy Technology Data Exchange (ETDEWEB)

    David N. Thompson; Timothy Campbell; Bryan Bals; Troy Runge; Farzaneh Teymouri

    2013-05-01

    Securing biofuels project financing is challenging, in part because of risks in feedstock supply. Commoditization of the feedstock and decoupling its supply from the biorefinery will promote greater economies of scale, reduce feedstock supply risk and reduce the need for overdesign of biorefinery pretreatment technologies. We present benefits and detractions of applying low-severity chemical treatments or ‘chemical preconversion treatments’ to enable this approach through feedstock modification and densification early in the supply chain. General structural modifications to biomass that support cost-effective densification and transportation are presented, followed by available chemistries to achieve these modifications with minimal yield loss and the potential for harvesting value in local economies. A brief review of existing biomass pretreatment technologies for cellulolytic hydrolysis at biorefineries is presented, followed by a discussion toward economically applying the underlying chemistries at reduced severity in light of capital and operational limitations of small-scale feedstock depots.

  10. Quarterly coal report, January--March 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-20

    The United States produced 242 million short tons of coal in the first quarter of 1993, a decrease of 6 percent (14 million short tons) from the amount produced during the first quarter of 1992. The decrease was due to a decline in production east of the Mississippi River. All major coal-producing States in this region had lower coal production levels led by West Virginia, which produced 5 million short tons less coal. The principal reasons for the overall drop in coal output compared to a year earlier were: A decrease in demand for US coal in foreign markets; a slower rate of producer/distributor stock build-up; and a drawn-down of electric utility coal stocks. Distribution of US coal in the first quarter of 1993 was 10 million short tons lower than in the first quarter of 1992, with 5 million short tons less distributed to both electric utilities and overseas markets. The average price of coal delivered to electric utilities during the first quarter of 1993 was $28.65 per short ton, the lowest value since the first quarter of 1980. Coal consumption in the first quarter of 1993 was 230 million short tons, 4 percent higher than in the first quarter of 1992, due primarily to a 5-percent increase in consumption at electric utility plants. Total consumer stocks, at 153 million short tons, and electric utility stocks, at 144 million short tons, were at their lowest quarterly level since the end of 1989. US. coal exports totaled 19 million short tons, 6 million short tons less than in the first quarter of 1992, and the lowest quarterly level since 1988. The decline was primarily due to a 1-million-short-ton drop in exports to each of the following destinations: Italy, France, Belgium and Luxembourg, and Canada.

  11. Weldon Spring Site Remedial Action Project quarterly environmental data summary (QEDS) for fourth quarter 1998

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-02-01

    This report contains the Quarterly Environmental Data Summary (QEDS) for the fourth quarter of 1998 in support of the Weldon Spring Site Remedial Action Project Federal Facilities Agreement. The data, except for air monitoring data and site KPA generated data (uranium analyses) were received from the contract laboratories, verified by the Weldon Spring Site verification group, and merged into the database during the fourth quarter of 1998. KPA results for on-site total uranium analyses performed during fourth quarter 1998 are included. Air monitoring data presented are the most recent complete sets of quarterly data.

  12. United States housing, fourth quarter 2013

    Science.gov (United States)

    Delton Alderman

    2017-01-01

    In the beginning of 2013, the U.S. housing construction market indicated increases in all sectors; yet, by the fourth quarter’s end, only housing under construction improved. Moderation and declines are to be expected in the fourth quarter, as winter is setting in. Permits, starts, housing under construction, completions, and new and existing house sales all exceeded...

  13. United States housing, second quarter 2013

    Science.gov (United States)

    Delton Alderman

    2017-01-01

    The U.S. housing market’s quarter two results were disap¬pointing compared with the first quarter. Although overall expected gains did not materialize, certain sectors improved slightly. Housing under construction, completions, and new and existing home sales exhibited slight increases. Overall permit data declined, and the decrease in starts was due primarily to a...

  14. Applied Meteorology Unit (AMU) Quarterly Report - Fourth Quarter FY-10

    Science.gov (United States)

    Bauman, William; Crawford, Winifred; Barrett, Joe; Watson, Leela; Wheeler, Mark

    2010-01-01

    Three AMU tasks were completed in this Quarter, each resulting in a forecast tool now being used in operations and a final report documenting how the work was done. AMU personnel completed the following tasks (1) Phase II of the Peak Wind Tool for General Forecasting task by delivering an improved wind forecasting tool to operations and providing training on its use; (2) a graphical user interface (GUI) she updated with new scripts to complete the ADAS Update and Maintainability task, and delivered the scripts to the Spaceflight Meteorology Group on Johnson Space Center, Texas and National Weather Service in Melbourne, Fla.; and (3) the Verify MesoNAM Performance task after we created and delivered a GUI that forecasters will use to determine the performance of the operational MesoNAM weather model forecast.

  15. Gasification reactivity and ash sintering behaviour of biomass feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Moilanen, A.; Nasrullah, M.

    2011-12-15

    Char gasification reactivity and ash sintering properties of forestry biomass feedstocks selected for large-scale gasification process was characterised. The study was divided into two parts: (1) Internal variation of the reactivity and the ash sintering of feedstocks. (2) Measurement of kinetic parameters of char gasification reactions to be used in the modelling of a gasifier. The tests were carried out in gases relevant to pressurized oxygen gasification, i.e. steam and carbon dioxide, as well as their mixtures with the product gases H{sub 2} and CO. The work was based on experimental measurements using pressurized thermobalance. In the tests, the temperatures were below 1000 deg C, and the pressure range was between 1 and 20 bar. In the first part, it was tested the effect of growing location, storage, plant parts and debarking method. The following biomass types were tested: spruce bark, pine bark, aspen bark, birch bark, forestry residue, bark feedstock mixture, stump chips and hemp. Thick pine bark had the lowest reactivity (instantaneous reaction rate 14%/min) and hemp the highest (250%/min); all other biomasses laid between these values. There was practically no difference in the reactivities among the spruce barks collected from the different locations. For pine bark, the differences were greater, but they were probably due to the thickness of the bark rather than to the growth location. For the spruce barks, the instantaneous reaction rate measured at 90% fuel conversion was 100%/min, for pine barks it varied between 14 and 75%/min. During storage, quite large local differences in reactivity seem to develop. Stump had significantly lower reactivity compared with the others. No clear difference in the reactivity was observed between barks obtained with the wet and dry debarking, but, the sintering of the ash was more enhanced for the bark from dry debarking. Char gasification rate could not be modelled in the gas mixture of H{sub 2}O + CO{sub 2} + H{sub 2

  16. Idaho National Laboratory Quarterly Occurrence Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Lisbeth Ann [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-11-01

    This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 85 reportable events (18 from the 4th Qtr FY-15 and 67 from the prior three reporting quarters), as well as 25 other issue reports (including events found to be not reportable and Significant Category A and B conditions) identified at INL during the past 12 months (8 from this quarter and 17 from the prior three quarters).

  17. Regional Feedstock Partnership Summary Report: Enabling the Billion-Ton Vision

    Energy Technology Data Exchange (ETDEWEB)

    Owens, Vance N. [South Dakota State Univ., Brookings, SD (United States). North Central Sun Grant Center; Karlen, Douglas L. [Dept. of Agriculture Agricultural Research Service, Ames, IA (United States). National Lab. for Agriculture and the Environment; Lacey, Jeffrey A. [Idaho National Lab. (INL), Idaho Falls, ID (United States). Process Science and Technology Division

    2016-07-12

    The U.S. Department of Energy (DOE) and the Sun Grant Initiative established the Regional Feedstock Partnership (referred to as the Partnership) to address information gaps associated with enabling the vision of a sustainable, reliable, billion-ton U.S. bioenergy industry by the year 2030 (i.e., the Billion-Ton Vision). Over the past 7 years (2008–2014), the Partnership has been successful at advancing the biomass feedstock production industry in the United States, with notable accomplishments. The Billion-Ton Study identifies the technical potential to expand domestic biomass production to offset up to 30% of U.S. petroleum consumption, while continuing to meet demands for food, feed, fiber, and export. This study verifies for the biofuels and chemical industries that a real and substantial resource base could justify the significant investment needed to develop robust conversion technologies and commercial-scale facilities. DOE and the Sun Grant Initiative established the Partnership to demonstrate and validate the underlying assumptions underpinning the Billion-Ton Vision to supply a sustainable and reliable source of lignocellulosic feedstock to a large-scale bioenergy industry. This report discusses the accomplishments of the Partnership, with references to accompanying scientific publications. These accomplishments include advances in sustainable feedstock production, feedstock yield, yield stability and stand persistence, energy crop commercialization readiness, information transfer, assessment of the economic impacts of achieving the Billion-Ton Vision, and the impact of feedstock species and environment conditions on feedstock quality characteristics.

  18. Molding Properties of Inconel 718 Feedstocks Used in Low-Pressure Powder Injection Molding

    Directory of Open Access Journals (Sweden)

    Fouad Fareh

    2016-01-01

    Full Text Available The impact of binders and temperature on the rheological properties of feedstocks used in low-pressure powder injection molding was investigated. Experiments were conducted on different feedstock formulations obtained by mixing Inconel 718 powder with wax-based binder systems. The shear rate sensitivity index and the activation energy were used to study the degree of dependence of shear rate and temperature on the viscosity of the feedstocks. The injection performance of feedstocks was then evaluated using an analytical moldability model. The results indicated that the viscosity profiles of feedstocks depend significantly on the binder constituents, and the secondary binder constituents play an important role in the rheological behavior (pseudoplastic or near-Newtonian exhibited by the feedstock formulations. Viscosity values as low as 0.06 to 2.9 Pa·s were measured at high shear rates and high temperatures. The results indicate that a feedstock containing a surfactant agent exhibits the best moldability characteristics.

  19. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.

    2016-06-14

    Methods and systems for making dibasic esters and/or dibasic acids using metathesis are generally disclosed. In some embodiments, the methods comprise reacting a terminal olefin ester with an internal olefin ester in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In some embodiments, the terminal olefin ester or the internal olefin ester are derived from a renewable feedstock, such as a natural oil feedstock. In some such embodiments, the natural oil feedstock, or a transesterified derivative thereof, is metathesized to make the terminal olefin ester or the internal olefin ester.

  20. Method for predicting fouling tendency of a hydrocarbon-containing feedstock

    Science.gov (United States)

    Schabron, John F; Rovani, Jr., Joseph F

    2013-07-23

    Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock fouling tendency for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

  1. Two Types of Novel Feedstock Injection Structures of the FCC Riser Reactor

    Institute of Scientific and Technical Information of China (English)

    范怡平; 蔡飞鹏; 时铭显; 徐春明

    2004-01-01

    Based on the analysis of flow characteristics of the FCC riser feedstock injection zone, two novel feedstock injection structures are put forward. By investigating three flow parameters in the feedstock injection zone under the three different structures (the traditional and the novel No. 1, No. 2 structures): the local density, the particle backmixng ratio, and the jet eigen-concentration, the flow feature under three structures were obtained. The experimental results demonstrate that the flow features under both proposed structures are obviously improved comparing with those under the traditional structure. Especially, the performance of the deflector-structured No. 2 is more desirable than that of No. 1.

  2. Low-Cost Feedstock Conversion to Biodiesel via Ultrasound Technology

    Directory of Open Access Journals (Sweden)

    Farouk Ameer

    2010-10-01

    Full Text Available Biodiesel has attracted increasing interest and has proved to be a good substitute for fossil-based fuels due to its environmental advantages and availability from renewable resources such as refined and waste vegetable oils. Several studies have shown that biodiesel is a better fuel than the fossil-derived diesel in terms of engine performance, emissions reduction, lubricity and environmental benefits. The increasing popularity of biodiesel has generated great demand for its commercial production methods, which in turn calls for the development of technically and economically sound process technologies. This paper explores the applicability of ultrasound in the optimization of low-cost feedstock – in this case waste cooking oil – in the transesterification conversion to biodiesel. It was found that the conversion efficiency of the waste oil using ultrasound was higher than with the mechanical stirring method. The optimized variables of 6:1 methanol/oil ratio at a reaction temperature of 30 °C and a reaction time of 30 min and 0.75% KOH (wt/wt catalyst concentration was obtained for the transesterification of the waste oil via the use of ultrasound.

  3. Rheological assessment of titanium MIM feedstocks [Conference paper

    CSIR Research Space (South Africa)

    Benson, JM

    2010-10-01

    Full Text Available � ������������������������������������������������������������������������������ � Page 348� � 2. Experimental Procedure A binder system, based on EVA and a wax, was used to prepare feedstock with varying powder loadings. In all three cases the total mass of the binder components were kept constant, while only the mass... ivit ric s In nfe ic �� IC eri e cu ess ap e se e ent y r mo fr ill ed e me ati an ibe n t u t ies an iti ren hte ��� A J al xc rre th art tot re tal ial e-m uld om in bi mo nt ve d m s t he...

  4. Evaluation of filamentous green algae as feedstocks for biofuel production.

    Science.gov (United States)

    Zhang, Wei; Zhao, Yonggang; Cui, Binjie; Wang, Hui; Liu, Tianzhong

    2016-11-01

    Compared with unicellular microalgae, filamentous algae have high resistance to grazer-predation and low-cost recovery in large-scale production. Green algae, as the most diverse group of algae, included numerous filamentous genera and species. In this study, records of filamentous genera and species in green algae were firstly censused and classified. Then, seven filamentous strains subordinated in different genera were cultivated in bubbled-column to investigate their growth rate and energy molecular (lipid and starch) capacity. Four strains including Stigeoclonium sp., Oedogonium nodulosum, Hormidium sp. and Zygnema extenue were screened out due to their robust growth. And they all could accumulate triacylglycerols and starch in their biomass, but with different capacity. After nitrogen starvation, Hormidium sp. and Oedogonium nodulosum respectively exhibited high capacity of lipid (45.38% in dry weight) and starch (46.19% in dry weight) accumulation, which could be of high potential as feedstocks for biodiesel and bioethanol production. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Practical Considerations of Moisture in Baled Biomass Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    William A. Smith; Ian J. Bonner; Kevin L. Kenney; Lynn M. Wendt

    2013-01-01

    Agricultural residues make up a large portion of the immediately available biomass feedstock for renewable energy markets. Current collection and storage methods rely on existing feed and forage practices designed to preserve nutrients and properties of digestibility. Low-cost collection and storage practices that preserve carbohydrates across a range of inbound moisture contents are needed to assure the economic and technical success of the emerging biomass industry. This study examines the movement of moisture in storage and identifies patterns of migration resulting from several on-farm storage systems and their impacts on moisture measurement and dry matter recovery. Baled corn stover and energy sorghum were stored outdoors in uncovered, tarp-covered, or wrapped stacks and sampled periodically to measure moisture and dry matter losses. Interpolation between discrete sampling locations in the stack improved bulk moisture content estimates and showed clear patterns of accumulation and re-deposition. Atmospheric exposure, orientation, and contact with barriers (i.e., soil, tarp, and wrap surfaces) were found to cause the greatest amount of moisture heterogeneity within stacks. Although the bulk moisture content of many stacks remained in the range suitable for aerobic stability, regions of high moisture were sufficient to support microbial activity, thus support dry matter loss. Stack configuration, orientation, and coverage methods are discussed relative to impact on moisture management and dry matter preservation. Additionally, sample collection and data analysis are discussed relative to assessment at the biorefinery as it pertains to stability in storage, queuing, and moisture carried into processing.

  6. Bioplastic production using wood mill effluents as feedstock.

    Science.gov (United States)

    Ben, M; Mato, T; Lopez, A; Vila, M; Kennes, C; Veiga, M C

    2011-01-01

    Fibreboard production is one of the most important industrial activities in Galicia (Spain). Great amounts of wastewater are generated, with properties depending on the type of wood, treatment process, final product and water reusing, among others. These effluents are characterized by a high chemical oxygen demand, low pH and nutrients limitation. Although anaerobic digestion is one of the most suitable processes for the treatment, lately bioplastics production (mainly polyhydroxyalkanoates) from wastewaters with mixed cultures is being evaluated. Substrate requirements for these processes consist of high organic matter content and low nutrient concentration. Therefore, wood mill effluents could be a suitable feedstock. In this work, the possibility of producing bioplastics from to wood mill effluents is evaluated. First, wood mill effluent was converted to volatile fatty acids in an acidogenic reactor operated at two different hydraulic retention times of 1 and 1.5 d. The acidification percentage obtained was 37% and 42%, respectively. Then, aerobic batch assays were performed using fermented wood mill effluents obtained at different hydraulic retention times. Assays were developed using different cultures as inoculums. The maximum storage yield of 0.57 Cmmol/Cmmol was obtained when when the culture was enriched on a synthetic media.

  7. Design, modeling, and analysis of a feedstock logistics system.

    Science.gov (United States)

    Judd, Jason D; Sarin, Subhash C; Cundiff, John S

    2012-01-01

    Given the location of a bio-energy plant for the conversion of biomass to bio-energy, a feedstock logistics system that relies on the use of satellite storage locations (SSLs) for temporary storage and loading of round bales is proposed. Three equipment systems are considered for handling biomass at the SSLs, and they are either placed permanently or are mobile and thereby travel from one SSL to another. A mathematical programming-based approach is utilized to determine SSLs and equipment routes in order to minimize the total cost. The use of a Side-loading Rack System results in average savings of 21.3% over a Densification System while a Rear-loading Rack System is more expensive to operate than either of the other equipment systems. The utilization of mobile equipment results in average savings of 14.8% over the equipment placed permanently. Furthermore, the Densification System is not justifiable for transportation distances less than 81 km. Copyright © 2011 Elsevier Ltd. All rights reserved.

  8. Plant triacylglycerols as feedstocks for the production of biofuels.

    Science.gov (United States)

    Durrett, Timothy P; Benning, Christoph; Ohlrogge, John

    2008-05-01

    Triacylglycerols produced by plants are one of the most energy-rich and abundant forms of reduced carbon available from nature. Given their chemical similarities, plant oils represent a logical substitute for conventional diesel, a non-renewable energy source. However, as plant oils are too viscous for use in modern diesel engines, they are converted to fatty acid esters. The resulting fuel is commonly referred to as biodiesel, and offers many advantages over conventional diesel. Chief among these is that biodiesel is derived from renewable sources. In addition, the production and subsequent consumption of biodiesel results in less greenhouse gas emission compared to conventional diesel. However, the widespread adoption of biodiesel faces a number of challenges. The biggest of these is a limited supply of biodiesel feedstocks. Thus, plant oil production needs to be greatly increased for biodiesel to replace a major proportion of the current and future fuel needs of the world. An increased understanding of how plants synthesize fatty acids and triacylglycerols will ultimately allow the development of novel energy crops. For example, knowledge of the regulation of oil synthesis has suggested ways to produce triacylglycerols in abundant non-seed tissues. Additionally, biodiesel has poor cold-temperature performance and low oxidative stability. Improving the fuel characteristics of biodiesel can be achieved by altering the fatty acid composition. In this regard, the generation of transgenic soybean lines with high oleic acid content represents one way in which plant biotechnology has already contributed to the improvement of biodiesel.

  9. Crop residues as soil amendments and feedstock for bioethanol production.

    Science.gov (United States)

    Lal, R

    2008-01-01

    Traditional solid fuels account for more than 90% of the energy supply for 3 billion people in developing countries. However, liquid biofuels (e.g., ethanol) are perceived as an important alternative to fossil fuel. Global crop residue production is estimated at about 4 billion Mg for all crops and 3 billion Mg per annum for lignocellulosic residues of cereals. One Mg of corn stover can produce 280L of ethanol, compared with 400L from 1Mg of corn grains; 1Mg of biomass is also equivalent to 18.5GJ of energy. Thus, 3 billion Mg of residues are equivalent to 840 billion L of ethanol or 56x10(9)GJ of energy. However, removal of crop residues exacerbates soil degradation, increases net emission of CO2, and aggravates food insecurity. Increasing the SOC pool by 1 Mg C ha(-1)yr(-1) through residue retention on soil can increase world food grain production by 24-40 million Mg yr(-1), and root/tuber production by 6-11 million Mg yr(-1). Thus, identifying alternate sources of biofuel feedstock (e.g., biofuel plantations, animal waste, municipal sold waste) is a high priority. Establishing biofuel plantations on agriculturally marginal or degraded lands can off-set 3.5-4 Pg Cyr(-1).

  10. Assessing Pinyon Juniper Feedstock Properties and Utilization Options

    Energy Technology Data Exchange (ETDEWEB)

    Gresham, Garold Linn [Idaho National Lab. (INL), Idaho Falls, ID (United States); Kenney, Kevin Louis [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-08-01

    Pinyon-juniper woodlands are a major ecosystem type found in the Southwest and the Intermountain West regions of the United States. These ecosystems are characterized by the presence of several different species of pinyon pine and juniper as the dominant plant cover. Since the 1800s, pinyon-juniper woodlands have rapidly expanded their range at the expense of existing ecosystems. Additionally, existing woodlands have become more dense, potentially increasing fire hazards. Land managers responsible for these areas often desire to reduce pinyonjuniper coverage on their lands for a variety of reasons, including restoration to previous vegetative cover, mitigation of fire risk, and improvement in wildlife habitat. However, the cost of clearing or thinning pinyon-juniper stands can be prohibitive. One reason for this is the lack of utilization options for the resulting biomass that could help recover some of the cost of pinyonjuniper stand management. The goal of this project was to assess the feedstock characteristics of biomass from a pinyon-juniper harvest so that potential applications for the biomass may be evaluated.

  11. Strategic Petroleum Reserve: Annual/quarterly report

    Energy Technology Data Exchange (ETDEWEB)

    1994-02-16

    Section 165 of the Energy Policy and Conservation Act (Public Law 94-163), as amended, requires the Secretary of Energy to submit annual and quarterly reports to the President and the Congress on activities of the Strategic Petroleum Reserve. This report combines the fourth quarter 1993 Quarterly Report with the 1993 Annual Report. Key activities described include appropriations; life extension planning; expansion planning; Strategic Petroleum Reserve oil acquisition; the oil stabilization program; and the refined petroleum product reserve test programs. Sections of this report also describe the program mission; the storage facility development program; environmental compliance; budget and finance; and drawdown and distribution.

  12. Econometric Methods within Romanian Quarterly National Accounts

    Directory of Open Access Journals (Sweden)

    Livia Marineta Drăguşin

    2013-04-01

    Full Text Available The aim of the present paper is to synthesise the main econometric methods (including the mathematical and statistical ones used in the Romanian Quarterly National Accounts compilation, irrespectively of Quarterly Gross Domestic Product (QGDP. These methods are adapted for a fast manner to operatively provide information about the country macroeconomic evolution to interested users. In this context, the mathematical and econometric methods play an important role in obtaining quarterly accounts valued in current prices and in constant prices, in seasonal adjustments and flash estimates of QGDP.

  13. Microbial production host selection for converting second-generation feedstocks into bioproducts

    NARCIS (Netherlands)

    Rumbold, K.; Buijsen, H.J.J. van; Overkamp, K.M.; Groenestijn, J.W. van; Punt, P.J.; Werf, M.J.V.D.

    2009-01-01

    Increasingly lignocellulosic biomass hydrolysates are used as the feedstock for industrial fermentations. These biomass hydrolysates are complex mixtures of different fermentable sugars, but also inhibitors and salts that affect the performance of the microbial production host. The performance of si

  14. Mechanical behaviour study on SBR/EVA composite for FDM feedstock fabrication

    Science.gov (United States)

    Raveverma, P.; Ibrahim, M.; Sa'ude, N.; Yarwindran, M.; Nasharuddin, M.

    2017-04-01

    This paper presents the research development of a new SBR/EVA composite flexible feedstock material by the injection moulding machine. The material consists of poly (ethylene-co-vinyl acetate) in styrene butadiene rubber cross-linked by Dicumyl Peroxide. In this study, the mechanical behaviour of injection moulded SBR/EVA composite with different blend ratio investigated experimentally. The formulations of blend ratio with several combinations of a new SBR/EVA flexible feedstock was done by volume percentage (vol. %). Based on the result obtained from the mechanical testing done which is tensile and hardness the composite of SBR/EVA has the high potency to be fabricated as the flexible filament feedstock. The ratio of 80:20 which as an average hardness and tensile strength proved to be the suitable choice to be fabricated as the flexible filament feedstock. The study has reached its goals on the fabricating and testing a new PMC which is flexible.

  15. Idaho National Laboratory Quarterly Occurrence Analysis 4th Quarter FY 2016

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Lisbeth Ann [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-11-01

    This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System, as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 84 reportable events (29 from the 4th quarter fiscal year 2016 and 55 from the prior three reporting quarters), as well as 39 other issue reports (including events found to be not reportable and Significant Category A and B conditions) identified at INL during the past 12 months (two from this quarter and 37 from the prior three quarters).

  16. Idaho National Laboratory Quarterly Occurrence Analysis for the 1st Quarter FY2017

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Lisbeth Ann [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2017-01-01

    This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 82 reportable events (13 from the 1st quarter (Qtr) of fiscal year (FY) 2017 and 68 from the prior three reporting quarters), as well as 31 other issue reports (including events found to be not reportable and Significant Category A and B conditions) identified at INL during the past 12 months (seven from this quarter and 24 from the prior three quarters).

  17. State of the art on reactor designs for solar gasification of carbonaceous feedstock

    DEFF Research Database (Denmark)

    Puig Arnavat, Maria; Tora, E.A.; Bruno, J.C.

    2013-01-01

    to produce high quality synthesis gas with a higher output per unit of feedstock and that allows for the chemical storage of solar energy in the form of a readily transportable fuel, among other advantages. The present paper describes the latest advances in solar thermochemical reactors for gasification...... of carbonaceous feedstocks. This work is categorized in this paper into patents and research/journal papers. © 2013 Elsevier Ltd....

  18. Process for Generation of Hydrogen Gas from Various Feedstocks Using Thermophilic Bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Ooteghem Van, Suellen

    2005-09-13

    A method for producing hydrogen gas is provided comprising selecting a bacteria from the Order Thermotogales, subjecting the bacteria to a feedstock and to a suitable growth environment having an oxygen concentration below the oxygen concentration of water in equilibrium with air; and maintaining the environment at a predetermined pH and at a temperature of at least approximately 45 degrees C. for a time sufficient to allow the bacteria to metabolize the feedstock.

  19. 20 CFR 404.1412 - Compensation quarters of coverage.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 2 2010-04-01 2010-04-01 false Compensation quarters of coverage. 404.1412... the Railroad Retirement Program § 404.1412 Compensation quarters of coverage. As used in this subpart, a compensation quarter of coverage is any quarter of coverage computed with respect to...

  20. Pectin-rich biomass as feedstock for fuel ethanol production

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, Meredith C.; Doran-Peterson, Joy [Georgia Univ., Athens, GA (United States). Dept. of Microbiology

    2012-08-15

    The USA has proposed that 30 % of liquid transportation fuel be produced from renewable resources by 2030 (Perlack and Stokes 2011). It will be impossible to reach this goal using corn kernel-based ethanol alone. Pectin-rich biomass, an under-utilized waste product of the sugar and juice industry, can augment US ethanol supplies by capitalizing on this already established feedstock. Currently, pectin-rich biomass is sold (at low value) as animal feed. This review focuses on the three most studied types of pectin-rich biomass: sugar beet pulp, citrus waste and apple pomace. Fermentations of these materials have been conducted with a variety of ethanologens, including yeasts and bacteria. Escherichia coli can ferment a wide range of sugars including galacturonic acid, the primary component of pectin. However, the mixed acid metabolism of E. coli can produce unwanted side products. Saccharomyces cerevisiae cannot naturally ferment galacturonic acid nor pentose sugars but has a homoethanol pathway. Erwinia chrysanthemi is capable of degrading many of the cell wall components of pectin-rich materials, including pectin. Klebsiella oxytoca can metabolize a diverse array of sugars including cellobiose, one degradation product of cellulose. However, both E. chrysanthemi and K. oxytoca produce side products during fermentation, similar to E. coli. Using pectin-rich residues from industrial processes is beneficial because the material is already collected and partially pretreated to facilitate enzymatic deconstruction of the plant cell walls. Using biomass already produced for other purposes is an attractive practice because fewer greenhouse gases (GHG) will be anticipated from land-use changes. (orig.)

  1. Coal power and combustion. Quarterly report, January--March 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-12-01

    ERDA's coal combustion and power program has focused on two major areas: Direct combustion of coal and advanced power systems. Efforts in the area of direct combustion are concentrated on: Development of atmospheric and pressurized systems capable of burning high-sulfur coal of all rank and quality in fluidized-bed combustors; development of advanced technology power systems to generate power more economically than present technology permits while using medium- and high-sulfur coal in an environmentally-acceptable manner; development of the technology enabling coal-oil slurries to be substituted as feedstock for gas or oil-fired combustors; and improvement of the efficiency of present boilers. Compared with conventional coal-fired systems, fluidized-bed combustion systems give higher power generation efficiencies and cleaner exhaust gases, even when burning high-sulfur coals. If the fluidized-bed system is pressurized, additional economies in capital and operating costs may be realized. The benefits from high-pressure combustion are a reduction of furnace size due to decreased gas volume and better sulfur removal. High-pressure combustion, however, requires the development of equipment to clean the hot combustion products to make them suitable for use in power generation turbines. The advanced power systems program is directed toward developing electric power systems capable of operating on coal or coal-derived fuels. These systems involve the use of high temperature gas turbines burning low-Btu gas and turbine systems using inert gases and alkali metal vapors. Some 25 projects in these areas are described, including a brief summary of progress during the quarter. (LTN)

  2. Coal liquefaction. Quarterly report, April--June 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-01-01

    The United States has more energy available in coal than in petroleum, natural gas, oil shale, and tar sands combined. Nationwide energy shortages, together with the availability of abundant coal reserves, make commercial production of synthetic fuels from coal vital to the Nation's total supply of clean energy. In response to this need, the Office of Fossil Energy of the Energy Research and Development Administration (ERDA) is conducting a research and development program to provide technology that will permit rapid commercialization of processes for converting coal to synthetic liquid and gaseous fuels and for improved direct combustion of coal. These fuels must be storable and suitable for power generation, transportation, and residential and industrial uses. ERDA's program for the conversion of coal to liquid fuels was begun by two of ERDA's predecessor agencies: Office of Coal Research (OCR) in 1962, and Bureau of Mines, U.S. Department of the Interior, in the 1930's. Current work in coal liquefaction is aimed at improved process configurations for both catalytic and non-catalytic processes to provide more attractive processing economics and lower capital investment. Coal liquefaction can now be achieved under more moderate processing conditions and more rapidly than was the case in the 1930's. The advantage of coal liquefaction is that the entire range of liquid products, including heavy boiler fuel, distillate fuel oil, gasoline, jet fuel, and diesel oil, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquid fuels also have the potential for use as chemical feedstocks. To determine the most efficient means of utilizing coal resources, ERDA is sponsoring the development of several conversion processes that are currently in the pilot plant stage. Nineteen projects under development are described and progress for each in the quarter is detailed briefly

  3. The Use of Artificial Neural Networks for Identifying Sustainable Biodiesel Feedstocks

    Directory of Open Access Journals (Sweden)

    Zoran D. Ristovski

    2013-07-01

    Full Text Available Over the past few decades, biodiesel produced from oilseed crops and animal fat is receiving much attention as a renewable and sustainable alternative for automobile engine fuels, and particularly petroleum diesel. However, current biodiesel production is heavily dependent on edible oil feedstocks which are unlikely to be sustainable in the longer term due to the rising food prices and the concerns about automobile engine durability. Therefore, there is an urgent need for researchers to identify and develop sustainable biodiesel feedstocks which overcome the disadvantages of current ones. On the other hand, artificial neural network (ANN modeling has been successfully used in recent years to gain new knowledge in various disciplines. The main goal of this article is to review recent literatures and assess the state of the art on the use of ANN as a modeling tool for future generation biodiesel feedstocks. Biodiesel feedstocks, production processes, chemical compositions, standards, physio-chemical properties and in-use performance are discussed. Limitations of current biodiesel feedstocks over future generation biodiesel feedstock have been identified. The application of ANN in modeling key biodiesel quality parameters and combustion performance in automobile engines is also discussed. This review has determined that ANN modeling has a high potential to contribute to the development of renewable energy systems by accelerating biodiesel research.

  4. Plasma-Powder Feedstock Interaction During Plasma Spray-Physical Vapor Deposition

    Science.gov (United States)

    Anwaar, Aleem; Wei, Lianglinag; Guo, Hongbo; Zhang, Baopeng

    2017-02-01

    Plasma spray-physical vapor deposition is a new process developed to produce coatings from the vapor phase. To achieve deposition from the vapor phase, the plasma-feedstock interaction inside the plasma torch, i.e., from the powder injection point to the nozzle exit, is critical. In this work, the plasma characteristics and the momentum and heat transfer between the plasma and powder feedstock at different torch input power levels were investigated theoretically to optimize the net plasma torch power, among other important factors such as the plasma gas composition, powder feed rate, and carrier gas. The plasma characteristics were calculated using the CEA2 code, and the plasma-feedstock interaction was studied inside the torch nozzle at low-pressure (20-25 kPa) conditions. A particle dynamics model was introduced to compute the particle velocity, coupled with Xi Chen's drag model for nonevaporating particles. The results show that the energy transferred to the particles and the coating morphology are greatly influenced by the plasma gas characteristics and the particle dynamics inside the nozzle. The heat transfer between the plasma gas and feedstock material increased with the net torch power up to an optimum at 64 kW, at which a maximum of 3.4% of the available plasma energy was absorbed by the feedstock powder. Experimental results using agglomerated 7-8 wt.% yttria-stabilized zirconia (YSZ) powder as feedstock material confirmed the theoretical predictions.

  5. Plasma-Powder Feedstock Interaction During Plasma Spray-Physical Vapor Deposition

    Science.gov (United States)

    Anwaar, Aleem; Wei, Lianglinag; Guo, Hongbo; Zhang, Baopeng

    2017-01-01

    Plasma spray-physical vapor deposition is a new process developed to produce coatings from the vapor phase. To achieve deposition from the vapor phase, the plasma-feedstock interaction inside the plasma torch, i.e., from the powder injection point to the nozzle exit, is critical. In this work, the plasma characteristics and the momentum and heat transfer between the plasma and powder feedstock at different torch input power levels were investigated theoretically to optimize the net plasma torch power, among other important factors such as the plasma gas composition, powder feed rate, and carrier gas. The plasma characteristics were calculated using the CEA2 code, and the plasma-feedstock interaction was studied inside the torch nozzle at low-pressure (20-25 kPa) conditions. A particle dynamics model was introduced to compute the particle velocity, coupled with Xi Chen's drag model for nonevaporating particles. The results show that the energy transferred to the particles and the coating morphology are greatly influenced by the plasma gas characteristics and the particle dynamics inside the nozzle. The heat transfer between the plasma gas and feedstock material increased with the net torch power up to an optimum at 64 kW, at which a maximum of 3.4% of the available plasma energy was absorbed by the feedstock powder. Experimental results using agglomerated 7-8 wt.% yttria-stabilized zirconia (YSZ) powder as feedstock material confirmed the theoretical predictions.

  6. A Review on Biomass Densification Systems to Develop Uniform Feedstock Commodities for Bioenergy Application

    Energy Technology Data Exchange (ETDEWEB)

    Jaya Shankar Tumuluru; Christopher T. Wright; J. Richard Hess; Kevin L. Kenney

    2011-11-01

    Developing uniformly formatted, densified feedstock from lignocellulosic biomass is of interest to achieve consistent physical properties like size and shape, bulk and unit density, and durability, which significantly influence storage, transportation and handling characteristics, and, by extension, feedstock cost and quality. A variety of densification systems are considered for producing a uniform format feedstock commodity for bioenergy applications, including (a) baler, (b) pellet mill, (c) cuber, (d) screw extruder, (e) briquette press, (f) roller press, (g) tablet press, and (g) agglomerator. Each of these systems has varying impacts on feedstock chemical and physical properties, and energy consumption. This review discusses the suitability of these densification systems for biomass feedstocks and the impact these systems have on specific energy consumption and end product quality. For example, a briquette press is more flexible in terms of feedstock variables where higher moisture content and larger particles are acceptable for making good quality briquettes; or among different densification systems, a screw press consumes the most energy because it not only compresses but also shears and mixes the material. Pretreatment options like preheating, grinding, steam explosion, torrefaction, and ammonia fiber explosion (AFEX) can also help to reduce specific energy consumption during densification and improve binding characteristics. Binding behavior can also be improved by adding natural binders, such as proteins, or commercial binders, such as lignosulphonates. The quality of the densified biomass for both domestic and international markets is evaluated using PFI (United States Standard) or CEN (European Standard).

  7. Integration of Feedstock Assembly System and Cellulosic Ethanol Conversion Models to Analyze Bioenergy System Performance

    Energy Technology Data Exchange (ETDEWEB)

    Jared M. Abodeely; Douglas S. McCorkle; Kenneth M. Bryden; David J. Muth; Daniel Wendt; Kevin Kenney

    2010-09-01

    Research barriers continue to exist in all phases of the emerging cellulosic ethanol biorefining industry. These barriers include the identification and development of a sustainable and abundant biomass feedstock, the assembly of viable assembly systems formatting the feedstock and moving it from the field (e.g., the forest) to the biorefinery, and improving conversion technologies. Each of these phases of cellulosic ethanol production are fundamentally connected, but computational tools used to support and inform analysis within each phase remain largely disparate. This paper discusses the integration of a feedstock assembly system modeling toolkit and an Aspen Plus® conversion process model. Many important biomass feedstock characteristics, such as composition, moisture, particle size and distribution, ash content, etc. are impacted and most effectively managed within the assembly system, but generally come at an economic cost. This integration of the assembly system and the conversion process modeling tools will facilitate a seamless investigation of the assembly system conversion process interface. Through the integrated framework, the user can design the assembly system for a particular biorefinery by specifying location, feedstock, equipment, and unit operation specifications. The assembly system modeling toolkit then provides economic valuation, and detailed biomass feedstock composition and formatting information. This data is seamlessly and dynamically used to run the Aspen Plus® conversion process model. The model can then be used to investigate the design of systems for cellulosic ethanol production from field to final product.

  8. Effect of biomass feedstock chemical and physical properties on energy conversion processes: Volume 2, Appendices

    Energy Technology Data Exchange (ETDEWEB)

    Butner, R.S.; Elliott, D.C.; Sealock, L.J., Jr.; Pyne, J.W.

    1988-12-01

    This report presents an exploration of the relationships between biomass feedstocks and the conversion processes that utilize them. Specifically, it discusses the effect of the physical and chemical structure of biomass on conversion yields, rates, and efficiencies in a wide variety of available or experimental conversion processes. A greater understanding of the complex relationships between these conversion systems and the production of biomass for energy uses is required to help optimize the complex network of biomass production, collection, transportation, and conversion to useful energy products. The review of the literature confirmed the scarcity of research aimed specifically at identifying the effect of feedstock properties on conversion. In most cases, any mention of feedstock-related effects was limited to a few brief remarks (usually in qualitative terms) in the conclusions, or as a topic for further research. Attempts to determine the importance of feedstock parameters from published data were further hampered by the lack of consistent feedstock characterization and the difficulty of comparing results between different experimental systems. Further research will be required to establish quantitative relationships between feedstocks and performance criteria in conversion. 127 refs., 4 figs., 7 tabs.

  9. TPAOH Template Removal from High-Silica ZSM-5 by Low-Temperature Hydrocracking%低温加氢裂解脱除高硅ZSM-5分子筛内TPAOH模板剂

    Institute of Scientific and Technical Information of China (English)

    赵淑蘅; 郎林; 阴秀丽; 杨文申; 吴创之

    2015-01-01

    分子筛膜的合成和应用是近年来的研究热点,特别是具有独特孔道结构的MFI型分子筛膜。但由于膜内有机模板剂在高温脱除时会导致膜产生缺陷,进而影响分子筛膜的应用。所以分子筛膜及分子筛晶体中有机模板剂的低温脱除工艺一直是研究者们致力解决的问题之一。本文系统考察了高硅ZSM-5分子筛晶体内有机模板剂(四丙基氢氧化铵, TPAOH)在H2/N2气氛下的低温裂解脱除规律,采用低温加氢裂解工艺,在350°C以下可有效脱除分子筛晶体孔道内的有机模板剂。通过对裂解后分子筛晶体的比表面积(BET)、热失重(TG)、傅里叶变换红外(FTIR)光谱和拉曼光谱表征证实,相比于空气和氮气气氛,含氢还原性气氛更有利于模板剂的低温脱除,脱除率随温度的升高而增加;280°C时,加氢裂解后晶体的BET比表面积已达到252 m2∙g-1,仍有少量有机残余物;350°C时,加氢裂解后晶体的BET比表面积可达到399 m2∙g-1,仅有微量无机碳残余物。此外,低温加氢裂解后的分子筛表面相对洁净,且氨气程序升温脱附(NH3-TPD)结果表明低温加氢裂解后的ZSM-5分子筛晶体具有相对较多的酸性位。%Zeolite membranes, especial y the MFI-type zeolite membranes, have attracted significant attention for decades because of their special properties. While organic templates such as tetrapropylammonium hydroxide (TPAOH) have typical y been used for the synthesis of ZSM-5 zeolite and zeolite membranes, the templates remain trapped in the as-synthesized zeolite crystals. A common method for removing organic templates and generating porous frameworks is calcination;however, during this process, the channel structure may be affected. In particular, for ZSM-5 membranes, membrane defects may be produced and the separation efficiency therefore may decrease to some extent. In this study, the low-temperature hydrocracking of TPAOH in ZSM-5 zeolite

  10. Quarterly Fishery Surveys - Salton Sea [ds428

    Data.gov (United States)

    California Department of Resources — In the spring of 2003, California Department of Fish and Game (CDFG) personnel began quarterly sampling of Salton Sea fish at fourteen stations around the sea, as...

  11. 76 FR 22910 - ACHP Quarterly Business Meeting

    Science.gov (United States)

    2011-04-25

    ... From the Federal Register Online via the Government Publishing Office ADVISORY COUNCIL ON HISTORIC PRESERVATION ACHP Quarterly Business Meeting AGENCY: Advisory Council on Historic Preservation. ACTION: Notice... c. Southwest Renewable Energy Development and Historic Preservation Working Group IX. New Business...

  12. Evaluation of shredder residue as cement manufacturing feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Boughton, Bob [California Environmental Protection Agency, Department of Toxic Substances Control, Office of Pollution Prevention and Technology Development, 1001 I Street, P.O. Box 806, Sacramento, CA 95812 (United States)

    2007-09-15

    Metal recycling from automobiles, appliances and scrap steel occurs at over 200 dedicated metal shredding operations in the US. Shredder residue (SR) consists of glass, rubber, plastics, fibers, dirt, and fines that remain after ferrous and non-ferrous metals have been removed. Over 3 million tonnes of SR generated in the US each year are landfilled. The results of a previous end-of-life impact assessment showed that use of SR as a fuel supplement for cement manufacturing was environmentally beneficial to the current practice of landfilling and appears better in comparison to the other management methods studied. However, because many reuse and recycling options may not be cost effective, there is a need for further study. Simplistic methods to separate SR into energy and mineral rich streams may facilitate the use of a sizable fraction of SR. Due to the large scale of the cement industry in the US, a significant amount of SR is recoverable. The goal of this study was to identify the feedstock quality parameters needed to satisfy kiln operators and then to assess the mechanical means necessary to process SR into material acceptable as coal and mineral substitutes. Field tests were conducted to separate and beneficiate the coarse SR waste stream. Density separation techniques commonly used by shredders in the past were tested to separate rubber and plastics from non-combustibles and contaminants (e.g., PVC and copper wire). A fraction constituting about 30 wt% of the total SR had fuel characteristics mirroring those of coal. However, remaining levels of potentially problematic constituents (e.g., total chlorine and heavy metals) may limit use to a low relative addition rate at some kilns. An economic review of a full-scale separation system showed that processing SR appears to be economically marginal considering avoided landfilling costs alone. However, significant economic benefits would result from additional non-ferrous metals recovery (namely copper). The

  13. Designing biochar properties through pre-pyrolysis feedstock metal blending

    Science.gov (United States)

    Anca-Couce, Andrés; Dieguez-Alonso, Alba; Moreno, Eduardo; Fristak, Vladimir; Soja, Gerhard; Husson, Olivier; Conte, Pellegrino; Kienzl, Norbert; Hagemann, Nikolas; Bucheli, Thomas; Hilber, Isabel; Schmidt, Hans-Peter

    2017-04-01

    Metal enhanced biochars have been produced by pyrolysis of wood chips previously blended with different metal-containing compounds: Cu(OH)2, Mg(OH)2, MgCl2, FeSO4, KCl and AlCl3; under an inert gas at 400 and 700°C. The obtained metal-enriched biochars have an organic and inorganic fraction, each accounting approximately to 50% of the mass, and they have been characterized in detail and compared to control samples produced without previous metal blending. The characterization at different European laboratories includes elemental analysis, surface area, pore size distribution, thermo-gravimetric analysis (TGA), sorption isotherms with P and As, pH, Eh, nuclear magnetic resonance (NMR), and zeta potential. It is shown that the presence of metals during pyrolysis affects to a great extent the structure and functionality of the obtained chars. The biochars have a high concentration (>15% in mass for almost all cases) of elemental metals introduced before pyrolysis. These metals strongly affect the development of char internal surface area and pore structure. The total surface area and pore volume increase while porosity decreases, and the pore size distribution and pore network are significantly modified. At high temperatures (700°C), some metals enhance char graphitization and its thermal stability. Mg(OH)2 produces the highest impact on physical structure. Furthermore, the blending with Mg, Al and Fe increased the sorption capacities for anionic forms of As and P by more than 800% compared to control biochar. Depending on the blended metal species and pyrolysis temperature, the pH of the biochar blends varied between 2.7 (Fe) and 10.8 (Cu) while Eh varied between 228 mV (Mg(OH)2 at 400°C) and 504 mV (MgCl2 at 700°C). The promising results obtained with pre-pyrolysis feedstock metal blending open the possibility towards designing biochars for special functions and purposes.

  14. Value of Distributed Preprocessing of Biomass Feedstocks to a Bioenergy Industry

    Energy Technology Data Exchange (ETDEWEB)

    Christopher T Wright

    2006-07-01

    Biomass preprocessing is one of the primary operations in the feedstock assembly system and the front-end of a biorefinery. Its purpose is to chop, grind, or otherwise format the biomass into a suitable feedstock for conversion to ethanol and other bioproducts. Many variables such as equipment cost and efficiency, and feedstock moisture content, particle size, bulk density, compressibility, and flowability affect the location and implementation of this unit operation. Previous conceptual designs show this operation to be located at the front-end of the biorefinery. However, data are presented that show distributed preprocessing at the field-side or in a fixed preprocessing facility can provide significant cost benefits by producing a higher value feedstock with improved handling, transporting, and merchandising potential. In addition, data supporting the preferential deconstruction of feedstock materials due to their bio-composite structure identifies the potential for significant improvements in equipment efficiencies and compositional quality upgrades. Theses data are collected from full-scale low and high capacity hammermill grinders with various screen sizes. Multiple feedstock varieties with a range of moisture values were used in the preprocessing tests. The comparative values of the different grinding configurations, feedstock varieties, and moisture levels are assessed through post-grinding analysis of the different particle fractions separated with a medium-scale forage particle separator and a Rototap separator. The results show that distributed preprocessing produces a material that has bulk flowable properties and fractionation benefits that can improve the ease of transporting, handling and conveying the material to the biorefinery and improve the biochemical and thermochemical conversion processes.

  15. Idaho National Laboratory Quarterly Occurrence Analysis - 3rd Quarter FY-2016

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Lisbeth Ann [Idaho National Laboratory

    2016-09-01

    This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 73 reportable events (23 from the 3rd Qtr FY-16 and 50 from the prior three reporting quarters), as well as 45 other issue reports (including events found to be not reportable and Significant Category A and B conditions) identified at INL during the past 12 months (16 from this quarter and 29 from the prior three quarters).

  16. Idaho National Laboratory Quarterly Occurrence Analysis - 1st Quarter FY 2016

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Lisbeth Ann [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-03-01

    This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 74 reportable events (16 from the 1st Qtr FY-16 and 58 from the prior three reporting quarters), as well as 35 other issue reports (including events found to be not reportable and Significant Category A and B conditions) identified at INL during the past 12 months (15 from this quarter and 20 from the prior three quarters).

  17. Use of tamarisk as a potential feedstock for biofuel production.

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Amy Cha-Tien; Norman, Kirsten

    2011-01-01

    This study assesses the energy and water use of saltcedar (or tamarisk) as biomass for biofuel production in a hypothetical sub-region in New Mexico. The baseline scenario consists of a rural stretch of the Middle Rio Grande River with 25% coverage of mature saltcedar that is removed and converted to biofuels. A manufacturing system life cycle consisting of harvesting, transportation, pyrolysis, and purification is constructed for calculating energy and water balances. On a dry short ton woody biomass basis, the total energy input is approximately 8.21 mmBTU/st. There is potential for 18.82 mmBTU/st of energy output from the baseline system. Of the extractable energy, approximately 61.1% consists of bio-oil, 20.3% bio-char, and 18.6% biogas. Water consumptive use by removal of tamarisk will not impact the existing rate of evapotranspiration. However, approximately 195 gal of water is needed per short ton of woody biomass for the conversion of biomass to biocrude, three-quarters of which is cooling water that can be recovered and recycled. The impact of salt presence is briefly assessed. Not accounted for in the baseline are high concentrations of Calcium, Sodium, and Sulfur ions in saltcedar woody biomass that can potentially shift the relative quantities of bio-char and bio-oil. This can be alleviated by a pre-wash step prior to the conversion step. More study is needed to account for the impact of salt presence on the overall energy and water balance.

  18. Cellulose solvent- and organic solvent-based lignocellulose fractionation enabled efficient sugar release from a variety of lignocellulosic feedstocks.

    Science.gov (United States)

    Sathitsuksanoh, Noppadon; Zhu, Zhiguang; Zhang, Y-H Percival

    2012-08-01

    Developing feedstock-independent biomass pretreatment would be vital to second generation biorefineries that would fully utilize diverse non-food lignocellulosic biomass resources, decrease transportation costs of low energy density feedstock, and conserve natural biodiversity. Cellulose solvent- and organic solvent-based lignocellulose fractionation (COSLIF) was applied to a variety of feedstocks, including Miscanthus, poplar, their mixture, bagasse, wheat straw, and rice straw. Although non-pretreated biomass samples exhibited a large variation in enzymatic digestibility, the COSLIF-pretreated biomass samples exhibited similar high enzymatic glucan digestibilities and fast hydrolysis rates. Glucan digestibilities of most pretreated feedstocks were ∼93% at five filter paper units per gram of glucan. The overall glucose and xylose yields for the Miscanthus:poplar mixture at a weight ratio of 1:2 were 93% and 85%, respectively. These results suggested that COSLIF could be regarded as a feedstock-independent pretreatment suitable for processing diverse feedstocks by adjusting pretreatment residence time only.

  19. Rheological study of copper and copper grapheme feedstock for powder injection molding

    Science.gov (United States)

    Azaman, N. Emira Binti; Rafi Raza, M.; Muhamad, N.; Niaz Akhtar, M.; Bakar Sulong, A.

    2017-01-01

    Heatsink is one of the solution to optimize the performance of smart electronic devices. Copper and its composites are helping the electronic industry to solve the heating problem. Copper-graphene heat sink material with enhanced thermal conductivity is the ultimate goal.Powder injection molding (PIM) has advantages of high precision and production rate, complex shape, low cost and suitabality for metal and cremics.PIM consists of four sub sequential steps; feedstock preparation, molding, debinding and sintering. Feedstock preparation is a critical step in PIM process. Any deficiency at this stage cannot be recovered at latter stages. Therefore, this research was carried out to investigate the injectability of copper and copper graphene composite using PIM. PEG based multicomponent binder system was used and the powder loading was upto 7vol.% less than the critical powder loading was used to provide the wettability of the copper powder and graphene nanoplatelets (GNps). Corpper-graphene feedstock contained 0.5vol.% of GNps . To ensure the homogeneity of GNps within feedstock a unique technique was addopted. The microscopic results showed that the feedstock is homogeneous and ready for injection. The viscosity-shear rate relationship was determined and results showed that the addition of 0.5vol.% of GNps in copper has increased the viscosity upto 64.9% at 140˚C than that of pure copper feedstock. This attribute may be due to the large surface area of GNps. On the other hand, by increasing the temperature, viscosity of the feedstock was decreased, which was recommended for PIM. The overall viscosity and share rate lies within the range recommended for PIM process. It is clear that both feedstocks showed pseudo plastic behaviour which is suitable for PIM process. In the pseudo plastic behaviour, the viscosity decreases with the shear rate. It may be due to change in the structure of the solid particles or the binder. The molding results showed that both copper

  20. Effects of Torrefaction Temperature on Pyrolysis Vapor Products of Woody and Herbaceous Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Starace, Anne K.; Evans, Robert J.; Lee, David D.; Carpenter, Daniel L.

    2016-07-21

    A variety of hardwood, softwood, and herbaceous feedstocks (oak, southern yellow pine mix, loblolly pine, pinyon-juniper mix, and switchgrass) were each torrefied at 200, 250, and 300 degrees C. Each of the feedstocks was pyrolyzed and the resulting vapors were analyzed with a molecular beam mass spectrometer (py-MBMS). Compositional analysis was used to measure the total lignin content of three of the feedstocks (southern yellow pine, softwood; oak, hardwood; and switchgrass, herbaceous) before and after torrefaction at 300 degrees C, and large differences in the fraction of lignin lost during torrefaction were found between feedstocks, with oak having the largest decrease in lignin during torrefaction and switchgrass having the least. It is hypothesized that these differences in the thermal degradation are due to, in part, the different ratios of S, G, and H lignins in the feedstocks. Additionally, the torrefaction of kraft lignin was studied using thermogravimetric analysis coupled with Fourier transform infrared spectroscopy (TGA-FTIR) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR).

  1. Acceptable contamination levels in solar grade silicon: From feedstock to solar cell

    Energy Technology Data Exchange (ETDEWEB)

    Hofstetter, J. [Instituto de Energia Solar, Avd. Complutense s/n, 28040 Madrid (Spain)], E-mail: jasmin.hofstetter@ies-def.upm.es; Lelievre, J.F.; Canizo, C.; Luque, A. del [Instituto de Energia Solar, Avd. Complutense s/n, 28040 Madrid (Spain)

    2009-03-15

    Ultimately, alternative ways of silicon purification for photovoltaic applications are developed and applied. There is an ongoing debate about what are the acceptable contamination levels within the purified silicon feedstock to specify the material as solar grade silicon. Applying a simple model and making some additional assumptions, we calculate the acceptable contamination levels of different characteristic impurities for each fabrication step of a typical industrial mc-Si solar cell. The acceptable impurity concentrations within the finished solar cell are calculated for SRH recombination exclusively and under low injection conditions. It is assumed that during solar cell fabrication impurity concentrations are only altered by a gettering step. During the crystallization process, impurity segregation at the solid-liquid interface and at extended defects are taken into account. Finally, the initial contamination levels allowed within the feedstock are deduced. The acceptable concentration of iron in the finished solar cell is determined to be 9.7x10{sup -3} ppma whereas the concentration in the silicon feedstock can be as high as 12.5 ppma. In comparison, the titanium concentration admitted in the solar cell is calculated to be 2.7x10{sup -4} ppma and the allowed concentration of 2.2x10{sup -2} ppma in the feedstock is only two orders of magnitude higher. Finally, it is shown theoretically and experimentally that slow cooling rates can lead to a decrease of the interstitial Fe concentration and thus relax the purity requirements in the feedstock.

  2. The use of co-digested solid fraction as feedstock for biogas plants

    Directory of Open Access Journals (Sweden)

    Elio Dinuccio

    2014-02-01

    Full Text Available A comparative study was set up in order to assess the technical feasibility of the long-term reuse of the mechanically separated co-digested solid fraction as a feedstock for anaerobic digestion plants (ADP. The biogas yields of two feedstock mixtures (A and B were assessed in mesophilic conditions (40°C±2°C using 6 lab-scale continuous stirredtank reactors. Feedstock mixture A (control consisted of pig slurry (70%, farmyard manure (4%, sorghum silage (12% and maize silage (14%. Feedstock mixture B was the same as the control plus the solid fraction derived from the mechanical separation of the output raw codigestate collected from the reactors. All reactors were fed simultaneously, three times a week, over a period of nine month. According to the study results, the reuse of the co-digested solid fraction as feedstock for ADP could increase the methane yield by approximately 4%. However, ADP efficiency evaluation (e.g., daily yield of methane per m3 of digester suggests limiting this practice to a maximum time period of 120 days.

  3. The use of co-digested solid fraction as feedstock for biogas plants

    Directory of Open Access Journals (Sweden)

    E. Dinuccio

    2013-09-01

    Full Text Available A comparative study was set up in order to assess the technical feasibility of the long-term reuse of the mechanically separated co-digested solid fraction as a feedstock for anaerobic digestion plants (ADP. The biogas yields of two feedstock mixtures (A and B were assessed in mesophilic conditions (40 °C ± 2 °C using 8 lab-scale continuous stirred-tank reactors (CSRT. Feedstock mixture A (control consisted of pig slurry (70%, farmyard manure (4%, sorghum silage (12% and maize silage (14%. Feedstock mixture B was the same as the control plus the solid fraction derived from the mechanical separation of the output raw co-digestate collected on daily basis from the reactors. All reactors were fed simultaneously, three times a week, over a period of nine month. According to the study results, the reuse of the co-digested solid fraction as feedstock for ADP could increase the methane yield by approximately 4%. However, ADP efficiency evaluation (e.g., daily yield of methane per m3 of digester suggest to limit this practice to a maximum time period of 120 days.

  4. Idaho National Laboratory Quarterly Performance Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Lisbeth [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-11-01

    This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 60 reportable events (23 from the 4th Qtr FY14 and 37 from the prior three reporting quarters) as well as 58 other issue reports (including not reportable events and Significant Category A and B conditions) identified at INL from July 2013 through October 2014. Battelle Energy Alliance (BEA) operates the INL under contract DE AC07 051D14517.

  5. ER Consolidated Quarterly Report October 2014

    Energy Technology Data Exchange (ETDEWEB)

    Cochran, John R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2014-10-01

    This Environmental Restoration Operations (ER) Consolidated Quarterly Report (ER Quarterly Report) provides the status of ongoing corrective actions and related Long- Term Stewardship (LTS) activities being implemented by Sandia National Laboratories, New Mexico (SNL/NM) ER for the April, May, and June 2014 quarterly reporting period. Section 2.0 provides the status of ER Operations activities including closure activities for the Mixed Waste Landfill (MWL), project management and site closure, and hydrogeologic characterizations. Section 3.0 provides the status of LTS activities that relate to the Chemical Waste Landfill (CWL) and the associated Corrective Action Management Unit (CAMU). Section 4.0 provides the references noted in Section I of this report.

  6. Long term storage of dilute acid pretreated corn stover feedstock and ethanol fermentability evaluation.

    Science.gov (United States)

    Zhang, Jian; Shao, Shuai; Bao, Jie

    2016-02-01

    This study reported a new solution of lignocellulose feedstock storage based on the distributed pretreatment concept. The dry dilute sulfuric acid pretreatment (DDAP) was conducted on corn stover feedstock, instead of ammonia fiber explosion pretreatment. Then the dry dilute acid pretreated corn stover was stored for three months during summer season with high temperature and humidity. No negative aspects were found on the physical property, composition, hydrolysis yield and ethanol fermentability of the long term stored pretreated corn stover, plus the additional merits including no chemicals recovery operation, anti-microbial contaminant environment from stronger acid and inhibitor contents, as well as the mild and slow hydrolysis in the storage. The new pretreatment method expanded the distributed pretreatment concept of feedstock storage with potential for practical application.

  7. Biobutanol as a Potential Sustainable Biofuel - Assessment of Lignocellulosic and Waste-based Feedstocks

    Directory of Open Access Journals (Sweden)

    Johanna Niemisto

    2013-06-01

    Full Text Available This paper introduces the production process of an alternative transportation biofuel, biobutanol. European legislation concerning biofuels and their sustainability criteria are also briefly described. The need to develop methods to ensure more sustainable and efficient biofuel production processes is recommended. In addition, the assessment method to evaluate the sustainability of biofuels is considered and sustainability assessment of selected feedstocks for biobutanol production is performed. The benefits and potential of using lignocellulosic and waste materials as feedstocks in the biobutanol production process are also discussed. Sustainability assessment in this paper includes cultivation, harvest/collection and upstream processing (pretreatment of feedstocks, comparing four main biomass sources: food crops, non-food crops, food industry by-product and wood-based biomass. It can be concluded that the highest sustainable potential in Finland is when biobutanol production is integrated into pulp & paper mills.

  8. Economic evaluation of United States ethanol production from ligno-cellulosic feedstocks

    Science.gov (United States)

    Choi, Youn-Sang

    This paper evaluates the economic feasibility and economy-wide impacts of the U. S. ethanol production from lignocellulosic feedstocks (LCF) using Tennessee Valley Authority's (TVA's) dilute acid hydrolysis process. A nonlinear mathematical programming model of a single ethanol producer, whose objective is profit maximization, is developed. Because of differences in their chemical composition and production process, lignocellulosic feedstocks are divided into two groups: Biomass feedstocks, which refer to crop residues, energy crops and woody biomass, and municipal solid waste (MSW). Biomass feedstocks are more productive and less costly in producing ethanol and co-products, while MSW generates an additional income to the producer from a tipping fee and recycling. The analysis suggests that, regardless of types of feedstocks used, TVA's conversion process can enhance the economic viability of ethanol production as long as furfural is produced from the hemicellulose fraction of feedstocks as a co-product. The high price of furfural makes it a major factor in determining the economic feasibility of ethanol production. Along with evaluating economic feasibility of LCF-to-ethanol production, the optimal size of a plant producing ethanol using TVA's conversion process is estimated. The larger plant would have the advantage of economies of scale, but also have a disadvantage of increased collection and transportation costs for bulky biomass from more distant locations. We assume that the plant is located in the state of Missouri and utilizes only feedstocks produced in the state. The results indicate that the size of a plant using Biomass feedstocks is much bigger than one using MSW. The difference of plant sizes results from plant location and feedstock availability. One interesting finding is that energy crops are not feasible feedstocks for LCF-to-ethanol production due to their high price. Next, a static CGE model is developed to estimate the U.S. economy

  9. Effects of feedstock characteristics on microwave-assisted pyrolysis - A review.

    Science.gov (United States)

    Zhang, Yaning; Chen, Paul; Liu, Shiyu; Peng, Peng; Min, Min; Cheng, Yanling; Anderson, Erik; Zhou, Nan; Fan, Liangliang; Liu, Chenghui; Chen, Guo; Liu, Yuhuan; Lei, Hanwu; Li, Bingxi; Ruan, Roger

    2017-04-01

    Microwave-assisted pyrolysis is an important approach to obtain bio-oil from biomass. Similar to conventional electrical heating pyrolysis, microwave-assisted pyrolysis is significantly affected by feedstock characteristics. However, microwave heating has its unique features which strongly depend on the physical and chemical properties of biomass feedstock. In this review, the relationships among heating, bio-oil yield, and feedstock particle size, moisture content, inorganics, and organics in microwave-assisted pyrolysis are discussed and compared with those in conventional electrical heating pyrolysis. The quantitative analysis of data reported in the literature showed a strong contrast between the conventional processes and microwave based processes. Microwave-assisted pyrolysis is a relatively new process with limited research compared with conventional electrical heating pyrolysis. The lack of understanding of some observed results warrant more and in-depth fundamental research. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Strategy of changing cracking furnace feedstock based on improved group search optimization

    Institute of Scientific and Technical Information of China (English)

    Xiaoyu Nian; Zhenlei Wang; Feng Qian

    2015-01-01

    The scheduling process of cracking furnace feedstock is important in an ethylene plant. In this paper it is described as a constraint optimization problem. The constraints consist of the cycle of operation, maximum tube metal temperature, process time of each feedstock, and flow rate. A modified group search optimizer is pro-posed to deal with the optimization problem. Double fitness values are defined for every group. First, the factor of penalty function should be changed adaptively by the ratio of feasible and general solutions. Second, the“excel-lent”infeasible solution should be retained to guide the search. Some benchmark functions are used to evaluate the new algorithm. Final y, the proposed algorithm is used to optimize the scheduling process of cracking furnace feedstock. And the optimizing result is obtained.

  11. Efficient process for producing saccharides and ethanol from a biomass feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Okeke, Benedict C.; Nanjundaswamy, Ananda K.

    2017-04-11

    Described herein is a process for producing saccharides and ethanol from biomass feedstock that includes (a) producing an enzyme composition by culturing a fungal strain(s) in the presence of a lignocellulosic medium, (b) using the enzyme composition to saccharify the biomass feedstock, and (c) fermenting the saccharified biomass feedstock to produce ethanol. The process is scalable and, in certain aspects, is capable of being deployed on farms, thereby allowing local production of saccharides and ethanol and resulting in a reduction of energy and other costs for farm operators. Optional steps to improve the biomass-to-fuel conversion efficiency are also contemplated, as are uses for byproducts of the process described herein.

  12. Solar cells from 120 PPMA carbon-contaminated feedstock without significantly higher reverse current or shunt

    Energy Technology Data Exchange (ETDEWEB)

    Manshanden, P.; Coletti, G. [ECN Solar Energy, Petten (Netherlands)

    2012-09-15

    In a bid to drive down the cost of silicon wafers, several options for solar grade silicon feedstock have been investigated over the years. All methods have in common that the resulting silicon contains higher levels of impurities like dopants, oxygen, carbon or transition metals, the type and level of impurities depending on the raw materials and refining processes. In this work wafers from a p-type mc-Si ingot made with feedstock contaminated with 120 ppma of carbon have been processed into solar cells together with reference uncontaminated feedstock from semiconductor grade polysilicon with <0.4 ppma carbon. The results show that comparable reverse current, shunts, and efficiencies can be reached for both types of wafers. Gettering and defect hydrogenation effectiveness also did not deviate from the reference. Electroluminescence pictures do not show increased hotspot formation, even at -16V.

  13. Quarterly report for the electricity market. 1. quarter of 2012; Kvartalsrapport for kraftmarknaden. 1. kvartal 2012

    Energy Technology Data Exchange (ETDEWEB)

    Pettersen, Finn Erik Ljaastad; Eliston, Anton Jaynanand; Guren, Ingri; Homqvist, Erik; Lund, Per Tore Jensen; Magnussen, Ingrid; Rasmussen, Kristian; Ulriksen, Margit Iren

    2012-07-01

    The first quarter of 2012 was unusually mild and wetter than normal. Total inflow was 16.8 TWh, 7.5 TWh more than normal. This ensured a high reservoir levels and at the end of the quarter the filling was 50.5 percent. It is 12.5 percentage points over the normal for the time of year and 32.4 percentage points higher than the same time last year. Norway had a power consumption of 37.5 TWh in the first quarter, which is 2.3 percent less than in the same quarter last year. the past 12 months, consumption has been 124.2 TWh, compared with 129.7 TWh the preceding 12 months. Power production in Norway was 42.3 TWh in the first quarter - an increase of 32.3 percent compared with the same quarter last year. The last 12 months have the Norwegian production been 138.5 TWh compared to 117.7 TWh the the previous 12 months. The production increase is due to milder and wetter weather than normal over the past year. This involvement also high the exports abroad. In the first quarter, Norway had a net export of 4.8 TWh, compared with a net import of 6.4 TWh in the first quarter last year. The good resource, combined with a low consumption gave a low price level in wholesale market for electricity. On average for the fourth quarter was the average spot price in the South and West Norway, Nok 272 and 275 / MWh. In Eastern Norway, the average price of Nok 283 / MWh, while it was Nok 285 / MWh in the Middle and Northern Norway. (Author)

  14. Quarterly report for the electricity market. 2. quarter of 2012; Kvartalsrapport for kraftmarknaden. 2. kvartal 2012

    Energy Technology Data Exchange (ETDEWEB)

    Eliston, Anton Jaynand; Holmqvist, Erik; Lund, Per Tore Jensen; Magnussen, Ingrid; Viggen, Kjerstin Dahl; Willumsen, Mats Oeivind; Guren, Ingrid; Ulriksen, Margit Iren

    2012-07-01

    Fourth quarter of 2011 was unusually mild and wet, resulting in high energy inflow to the Norwegian reservoirs. Total inflow for the year was 149.2 TWh, 26.7 TWh more than normal. This ensured record-high 80.3 percent load factor at the end of the quarter.The stored energy amount in the reservoirs was thus 29.5 TWh greater than at the end of 2010/2011. Norway had a power consumption of 34.1 TWh in the fourth quarter. Compared with the same quarter of 2010, a decrease of 4.2 TWh, which can be connected to the mild weather development. The total Norwegian electricity consumption in 2011 was 125.1 TWh, or 6.9 TWh less than in 2010. Electricity production in the fourth quarter of 2011 was 38.3 GWh, an increase of 3.7 TWh from the same quarter the year before. The production increase were a result of the large volume of water in the system. Power production for the year 2011 was 128.1 TWh, an increase of 3.7 TWh from 2010. Kraft surplus was therefore large, and it was Norwegian net export of 4.2 TWh in the fourth quarter, and 3.0 TWh total for the year. In comparison, in the fourth quarter of 2010 Norwegian net import of 0.8 TWh and 7.5 TWh annually. The good resource combined with the low consumption gave a unusually low price levels in the wholesale market for electricity. On average for fourth quarter, the price of power in the East and South-East Norway Nok 264 / MWh, in western Norway Nok 260 / MWh, in Central Norway Nok 270 / MWh (eb)

  15. Quarterly report for the electricity market. 2. quarter of 2012; Kvartalsrapport for kraftmarknaden. 2. kvartal 2012

    Energy Technology Data Exchange (ETDEWEB)

    Pettersen, Finn Erik Ljaastad; Eliston, Anton Jayanand; Vaeringstad, Thomas; Lund, Per Tore Jensen; Magnussen, Ingrid; Langseth, Benedicte; Willumsen, Mats Oeivind; Rasmussen, Kristian; Guren, Ingri

    2012-07-01

    Second quarter of 2012 was cold. Total inflow was 47.0 TWh, 8.8 TWh less than normal. At the end of the quarter, the reservoir level 68.4 percent. It is 1.8 percentage points above normal for time of year and 1.2 percentage points higher than the same time last year. Norway had a power consumption of 28.2 TWh in the second quarter, which is 4.2 percent higher than in the same quarter last year. The last 12 months the consumption have been 125.7 TWh, compared with 128.7 TWh the preceding 12 months. The power production in Norway was 33.3 TWh in the second quarter - an increase of 26.1 percent compared with the same quarter last year. The last 12 months the Norwegian production has been 145.8 TWh, compared with 120.9 TWh the preceding 12 months. The production increase is due to that the last year has been much wetter than the preceding. This has also given high export abroad. In the second quarter Norway had a net export of 5.1 TWh, compared with a net import of 0.6 TWh in the second quarter last year. The good resource gave a low price level in the wholesale market for electricity. On average for the second quarter was the average spot price in West, Southwest and Eastern Norway, 201, 202 and 203 Nok / MWh. In Central and Northern Norway, the average price 218 and 213 Nok/ MWh. (eb)

  16. Sinopec's Profits up Drastically in First Quarter

    Institute of Scientific and Technical Information of China (English)

    Wang Yuxiao

    2003-01-01

    @@ Sinopec, Asia's largest refiner,announced on April 29 that its net first quarter profit skyrocketed almost 12-fold as it sold more refined oil and petrochemical products, cashing in on the international price hikes in oil during the period. However, analysts said the growth of China's second largest oil company is expected to recede in the second quarter as oil prices fall due to the end of the Iraq War. They still anticipate the company's full-year profit will increase by 15 percent or more on the back of a domestic oil market recovery.

  17. Polyolefin Backbone Substitution in Binders for Low Temperature Powder Injection Moulding Feedstocks

    Directory of Open Access Journals (Sweden)

    Berenika Hausnerova

    2014-02-01

    Full Text Available This paper reports the substitution of polyolefin backbone binder components with low melting temperature carnauba wax for powder injection moulding applications. The effect of various binder compositions of Al2O3 feedstock on thermal degradation parameters is investigated by thermogravimetric analysis. Within the experimental framework 29 original feedstock compositions were prepared and the superiority of carnauba wax over the polyethylene binder backbone was demonstrated in compositions containing polyethylene glycol as the initial opening agent and governing the proper mechanism of the degradation process. Moreover, the replacement of synthetic polymer by the natural wax contributes to an increase of environmental sustainability of modern industrial technologies.

  18. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Snead, Thomas E; Cohen, Steven A; Gildon, Demond L

    2015-04-07

    Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

  19. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.

    2016-03-15

    Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

  20. Low temperature microwave-assisted vs conventional pyrolysis of various biomass feedstocks

    Institute of Scientific and Technical Information of China (English)

    Peter Shuttleworth; Vitaliy Budarin; Mark Gronnow; James H. Clark; Rafael Luque

    2012-01-01

    A comparison between conventional pyrolysis and a novel developed low-temperature microwave-assisted pyrolysis methodology has been performed for the valorisation of a range of biomass feedstocks including waste residues.Microwave pyrolysis was found to efficiently deliver comparable evolution of bio-gases in the system as compared with conventional pyrolysis at significantly reduced temperatures (120-180 ℃ vs 250-400 ℃).The gas obtained from microwave-assistet pyrolysis was found to contain CO2,CH4 and CO as major components as well as other related chemicals (e.g.acids,aldehydes,alkanes) which were obtained in different proportions depending on the selected feedstock.

  1. Catalytic Hydrothermal Conversion of Wet Biomass Feedstocks and Upgrading – Process Design and Optimization

    DEFF Research Database (Denmark)

    Hoffmann, Jessica; Toor, Saqib; Rosendahl, Lasse

    Liquid biofuels will play a major role for a more sustainable energy system of the future. The CatLiq® process is a 2nd generation biomass conversion process that is based on hydrothermal liquefaction. Hydrothermal liquefaction offers a very efficient and feedstock flexible way of converting...... biomass to bio-oil. Bio-oils from hydrothermal liquefaction are characterised by their high feedstock flexibility. Upgrading of complete bio-oils derived from hydrothermal conversion has not yet been extensively studied. Purpose of this work is to reduce the oxygen content of the bio-oil to improve...

  2. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    Science.gov (United States)

    Snead, Thomas E; Cohen, Steven A; Gildon, Demond L

    2015-04-07

    Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

  3. Thermal conversion of biomass to valuable fuels, chemical feedstocks and chemicals

    Science.gov (United States)

    Peters, William A.; Howard, Jack B.; Modestino, Anthony J.; Vogel, Fredreric; Steffin, Carsten R.

    2009-02-24

    A continuous process for the conversion of biomass to form a chemical feedstock is described. The biomass and an exogenous metal oxide, preferably calcium oxide, or metal oxide precursor are continuously fed into a reaction chamber that is operated at a temperature of at least 1400.degree. C. to form reaction products including metal carbide. The metal oxide or metal oxide precursor is capable of forming a hydrolizable metal carbide. The reaction products are quenched to a temperature of 800.degree. C. or less. The resulting metal carbide is separated from the reaction products or, alternatively, when quenched with water, hydolyzed to provide a recoverable hydrocarbon gas feedstock.

  4. Bioethanol - Status report on bioethanol production from wood and other lignocellulosic feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Scott-Kerr, Chris; Johnson, Tony; Johnson, Barbara; Kiviaho, Jukka

    2010-09-15

    Lignocellulosic biomass is seen as an attractive feedstock for future supplies of renewable fuels, reducing the dependence on imported petroleum. However, there are technical and economic impediments to the development of commercial processes that utilise biomass feedstocks for the production of liquid fuels such as ethanol. Significant investment into research, pilot and demonstration plants is on-going to develop commercially viable processes utilising the biochemical and thermochemical conversion technologies for ethanol. This paper reviews the current status of commercial lignocellulosic ethanol production and identifies global production facilities.

  5. Process for improving the energy density of feedstocks using formate salts

    Science.gov (United States)

    Wheeler, Marshall Clayton; van Heiningen, Adriaan R.P.; Case, Paige A.

    2015-09-01

    Methods of forming liquid hydrocarbons through thermal deoxygenation of cellulosic compounds are disclosed. Aspects cover methods including the steps of mixing a levulinic acid salt-containing feedstock with a formic acid salt, exposing the mixture to a high temperature condition to form hydrocarbon vapor, and condensing the hydrocarbon vapor to form liquid hydrocarbons, where both the formic acid salt and the levulinic acid salt-containing feedstock decompose at the high temperature condition and wherein one or more of the mixing, exposing, and condensing steps is carried out a pressure between about vacuum and about 10 bar.

  6. Sunflower-based Feedstocks in Nonfood Applications: Perspectives from Olefin Metathesis

    Science.gov (United States)

    Marvey, Bassie B.

    2008-01-01

    Sunflower (Helianthus annuus L.) oil remains under-utilised albeit one of the major seed oils produced world-wide. Moreover, the high oleic sunflower varieties make the oil attractive for applications requiring high temperature processes and those targeting the C=C double bond functionality. Herein an overview of the recent developments in olefin metathesis of sunflower-based feedstocks is presented. The improved performance of olefin metathesis catalysts leading to high turnover numbers, high selectivity and catalyst recyclability, opens new opportunities for tailoring sunflower-based feedstocks into products required for possible new niche market applications. Promising results in biofuel, biopolymers, fragrances and fine chemicals applications have been reported. PMID:19325810

  7. An integrated bioconversion process for the production of L-lactic acid from starchy feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, S.P.; Moon, S.H.

    1997-07-01

    The potential market for lactic acid as the feedstock for biodegradable polymers, oxygenated chemicals, and specialty chemicals is significant. L-lactic acid is often the desired enantiomer for such applications. However, stereospecific lactobacilli do not metabolize starch efficiently. In this work, Argonne researchers have developed a process to convert starchy feedstocks into L-lactic acid. The processing steps include starch recovery, continuous liquefaction, and simultaneous saccharification and fermentation. Over 100 g/L of lactic acid was produced in less than 48 h. The optical purity of the product was greater than 95%. This process has potential economical advantages over the conventional process.

  8. The Effects of Trace Contaminants on Catalytic Processing of Biomass-Derived Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.; Peterson, Keith L.; Muzatko, Danielle S.; Alderson, Eric V.; Hart, Todd R.; Neuenschwander, Gary G.

    2004-03-25

    Trace components in biomass feedstocks are potential catalyst poisons when catalytically processing these materials to value-added chemical products. Trace components include inorganic elements such as alkali metals and alkaline earths, phosphorus or sulfur, aluminum or silicon, chloride, or transition metals. Protein components in biomass feedstocks can lead to formation of peptide fractions (from hydrolysis) or ammonium ions (from more severe breakdown) both of which might interfere with catalysis. The effects of these components on catalytic hydrogenation processing has been studied in batch reactor processing tests

  9. Watermelon juice: a promising feedstock supplement, diluent, and nitrogen supplement for ethanol biofuel production

    Directory of Open Access Journals (Sweden)

    Bruton Benny D

    2009-08-01

    Full Text Available Abstract Background Two economic factors make watermelon worthy of consideration as a feedstock for ethanol biofuel production. First, about 20% of each annual watermelon crop is left in the field because of surface blemishes or because they are misshapen; currently these are lost to growers as a source of revenue. Second, the neutraceutical value of lycopene and L-citrulline obtained from watermelon is at a threshold whereby watermelon could serve as starting material to extract and manufacture these products. Processing of watermelons to produce lycopene and L-citrulline, yields a waste stream of watermelon juice at the rate of over 500 L/t of watermelons. Since watermelon juice contains 7 to 10% (w/v directly fermentable sugars and 15 to 35 μmol/ml of free amino acids, its potential as feedstock, diluent, and nitrogen supplement was investigated in fermentations to produce bioethanol. Results Complete watermelon juice and that which did not contain the chromoplasts (lycopene, but did contain free amino acids, were readily fermentable as the sole feedstock or as diluent, feedstock supplement, and nitrogen supplement to granulated sugar or molasses. A minimum level of ~400 mg N/L (~15 μmol/ml amino nitrogen in watermelon juice was required to achieve maximal fermentation rates when it was employed as the sole nitrogen source for the fermentation. Fermentation at pH 5 produced the highest rate of fermentation for the yeast system that was employed. Utilizing watermelon juice as diluent, supplemental feedstock, and nitrogen source for fermentation of processed sugar or molasses allowed complete fermentation of up to 25% (w/v sugar concentration at pH 3 (0.41 to 0.46 g ethanol per g sugar or up to 35% (w/v sugar concentration at pH 5 with a conversion to 0.36 to 0.41 g ethanol per g sugar. Conclusion Although watermelon juice would have to be concentrated 2.5- to 3-fold to serve as the sole feedstock for ethanol biofuel production, the results

  10. Quarterly Progress Report Fuels Development Operation October - December 1960

    Energy Technology Data Exchange (ETDEWEB)

    Cadwell, J. J. [Hanford Site (HNF), Richland, WA (United States); Tobin, J. C. [Hanford Site (HNF), Richland, WA (United States); Last, G. A. [Hanford Site (HNF), Richland, WA (United States); Evans, E. A. [Hanford Site (HNF), Richland, WA (United States); Minor, J. E. [Hanford Site (HNF), Richland, WA (United States)

    1961-01-13

    The present Quarterly Report is the continuation of a series issued by the new Fuels Development Operation. Reports in this series combine portions of the quarterly reports by the former Metallurgy Research and Fuel Technology Sub-Sections.

  11. Genetic predictions of racing performance in quarter horses

    National Research Council Canada - National Science Library

    Willham, R. L; Wilson, D. E

    1991-01-01

    .... Research on the racing performance of quarter horses has been used to develop genetic prediction summaries on all horses with at least one start on record at the American Quarter Horse Association...

  12. ARM Operations Quarterly Report October 1-December 31, 2013

    Energy Technology Data Exchange (ETDEWEB)

    Voyles, Jimmy W. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2013-12-31

    The U.S. Department of Energy requires national user facilities to report time-based operating data. This quarterly report is written to comply with this requirement. This reports on the first quarter facility statistics.

  13. Environmental Biosciences Program Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Lawrence C. Mohr, M.D.

    2009-01-30

    Current research projects have focused Environmental Biosciences Program (EBP) talent and resources on providing the scientific basis for risk-based standards, risk-based decision making and the accelerated clean-up of widespread environmental hazards. These hazards include trichloroethylene, low-dose ionizing radiation (gamma and neutron) and alpha radiation from plutonium. Trichloroethylene research has been conducted as a joint collaborative effort with the University of Georgia. Work on the trichloroethylene research projects has been slowed as a result of funding uncertainties. The impact of these funding uncertainties has been discussed with the United States Department of Energy (DOE). Laboratory work has been completed on several trichloroethylene risk assessment projects, and these projects have been brought to a close. Plans for restructuring the performance schedule of the remaining trichloroethylene projects have been submitted to the department. A comprehensive manuscript on the scientific basis of trichloroethylene risk assessment is in preparation. Work on the low-dose radiation risk assessment projects is also progressing at a slowed rate as a result of funding uncertainties. It has been necessary to restructure the proponency and performance schedule of these projects, with the project on Low-Dose Radiation: Epidemiology Risk Models transferred to DOE Office of Science proponency under a separate funding instrument. Research on this project will continue under the provisions of the DOE Office of Science funding instrument, with progress reported in accordance with the requirements of that funding instrument. Progress on that project will no longer be reported in quarterly reports for DE-FC09-02CH11109. Following a meeting at the Savannah River Site on May 8, 2008, a plan was submitted for development of an epidemiological cohort study and prospective medical surveillance system for the assessment of disease rates among workers at the Savannah River

  14. 10 CFR 34.69 - Records of quarterly inventory.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 1 2010-01-01 2010-01-01 false Records of quarterly inventory. 34.69 Section 34.69 Energy... INDUSTRIAL RADIOGRAPHIC OPERATIONS Recordkeeping Requirements § 34.69 Records of quarterly inventory. (a) Each licensee shall maintain records of the quarterly inventory of sealed sources and of...

  15. 12 CFR 620.10 - Preparing the quarterly report.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 6 2010-01-01 2010-01-01 false Preparing the quarterly report. 620.10 Section 620.10 Banks and Banking FARM CREDIT ADMINISTRATION FARM CREDIT SYSTEM DISCLOSURE TO SHAREHOLDERS Quarterly Report § 620.10 Preparing the quarterly report. (a) Each institution of the Farm Credit...

  16. Natural gas imports and exports. Second quarter report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The Office of Natural Gas and Petroleum Import and Export Activities prepares quarterly reports summarizing the data provided by companies authorized to import or export natural gas. Companies are required, as a condition of their authorizations, to file quarterly reports. This report is for the second quarter of 1997 (April through June).

  17. Quarterly coal report, April 1995--June 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    This document provides comprehensive information about U.S. coal production, distribution, imports, exports, prices, and consumption. Coke production, consumption, distribution, imports, and exports are also provided. This report presents compiled data for April thru June, and historical data for 1987 thru the first quarter of 1995.

  18. Bangladesh Quarterly Economic Update - December 2014

    OpenAIRE

    Asian Development Bank

    2015-01-01

    The Bangladesh Quarterly Economic Update (QEU) has been produced by the Bangladesh Resident Mission of the Asian Development Bank since March 2001. The QEU provides information and analysis on Bangladesh’s macroeconomic and sector developments, key development challenges, and policy and institutional reforms. The QEU has wide readership in government, academia, development partners, private sector, and civil society.

  19. Bangladesh Quarterly Economic Update June 2014

    OpenAIRE

    Asian Development Bank

    2014-01-01

    The Bangladesh Quarterly Economic Update (QEU) has been produced by the Bangladesh Resident Mission of the Asian Development Bank since March 2001. The QEU provides information and analysis on Bangladesh’s macroeconomic and sector developments, key development challenges, and policy and institutional reforms. The QEU has wide readership in government, academia, development partners, private sector, and civil society.

  20. Bangladesh Quarterly Economic Update September 2014

    OpenAIRE

    Asian Development Bank

    2014-01-01

    The Bangladesh Quarterly Economic Update (QEU) has been produced by the Bangladesh Resident Mission of the Asian Development Bank since March 2001. The QEU provides information and analysis on Bangladesh’s macroeconomic and sector developments, key development challenges, and policy and institutional reforms. The QEU has wide readership in government, academia, development partners, private sector, and civil society.

  1. "The Career Development Quarterly": A Centennial Retrospective

    Science.gov (United States)

    Savickas, Mark L.; Pope, Mark; Niles, Spencer G.

    2011-01-01

    "The Career Development Quarterly" has been the premier journal in the field of vocational guidance and career intervention since its inception 100 years ago. To celebrate its centennial, 3 former editors trace its evolution from a modest and occasional newsletter to its current status as a major professional journal. They recount its history of…

  2. Musculoskeletal injuries in nonracing quarter horses.

    Science.gov (United States)

    Scott, Mike

    2008-04-01

    Quarter horses used for western performance competitions commonly sustain a variety of musculoskeletal injuries. It is important for the veterinarian to have an understanding of some of the breed characteristics and the nature of the competitions in which individual horses are being used so as to diagnose, treat, and prevent injury as effectively as possible.

  3. Transient Fanconi syndrome in Quarter horses.

    Science.gov (United States)

    Ohmes, Cameon M; Davis, Elizabeth G; Beard, Laurie A; Vander Werf, Karie A; Bianco, Alex W; Giger, Urs

    2014-02-01

    Two Quarter horses with weight loss had glucosuria, euglycemia, and a mild metabolic acidosis suggesting a proximal renal tubular defect. Further testing revealed transient generalized aminoaciduria, lactic aciduria, and glucosuria, indicating Fanconi syndrome. Both horses recovered with supportive therapy. This is the first report of acquired Fanconi syndrome in horses.

  4. Apprentices and Trainees: March Quarter, 2010

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2010

    2010-01-01

    This publication presents estimates of apprentice and trainee activity in Australia for the March quarter 2010. The figures in this publication are derived from the National Apprentice and Trainee Collection no.64 (June 2010 estimates). The most recent figures in this publication are estimated (those for training activity from the September…

  5. Quarter-controlled milking in dairy cows

    NARCIS (Netherlands)

    Ipema, A.H.; Hogewerf, P.H.

    2008-01-01

    The design of a milking stall with special functions for monitoring and control is described. The milk removal process per quarter is described. The milking stall was equipped with four milk containers, whose advancing weight was recorded permanently. The data were online converted into milk flow ra

  6. Apprentices and Trainees: September Quarter, 2009

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2010

    2010-01-01

    This publication presents estimates of apprentice and trainee activity in Australia for the September quarter 2009. The figures in this publication are derived from the National Apprentice and Trainee Collection no. 62 (December 2009 estimates). There were 425,500 apprentices and trainees in-training as at 30 September 2009, a decrease of 2.4%…

  7. Apprentices and Trainees: December Quarter, 2009

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2010

    2010-01-01

    This publication presents estimates of apprentice and trainee activity in Australia for the December quarter 2009. The figures in this publication are derived from the National Apprentice and Trainee Collection no.63 (March 2010 estimates). There were 414 900 apprentices and trainees in-training as at 31 December 2009, a decrease of 0.6% from the…

  8. "The Career Development Quarterly": A Centennial Retrospective

    Science.gov (United States)

    Savickas, Mark L.; Pope, Mark; Niles, Spencer G.

    2011-01-01

    "The Career Development Quarterly" has been the premier journal in the field of vocational guidance and career intervention since its inception 100 years ago. To celebrate its centennial, 3 former editors trace its evolution from a modest and occasional newsletter to its current status as a major professional journal. They recount its history of…

  9. "Library Quarterly" Management Literature, 1931-2004

    Science.gov (United States)

    Young, Arthur P.

    2006-01-01

    Management literature appearing in "Library Quarterly," 1931-2004, is examined in this essay. A total of 145 articles are identified that focus on administrative and managerial issues related to libraries during this period. Management literature is construed expansively and includes accounting, administration, assessment, budgets, facilities,…

  10. 77 FR 3784 - ACHP Quarterly Business Meeting

    Science.gov (United States)

    2012-01-25

    ... From the Federal Register Online via the Government Publishing Office ADVISORY COUNCIL ON HISTORIC PRESERVATION ACHP Quarterly Business Meeting AGENCY: Advisory Council on Historic Preservation. ACTION: Notice... Implementation C. Bureau of Land Management Nationwide Programmatic Agreement VIII. New Business IX. Adjourn...

  11. The Research Quarterly and its Antecedents.

    Science.gov (United States)

    Park, Roberta J.

    1980-01-01

    There is little evidence that indicates that the American Alliance for Health, Physical Education, Recreation, and Dance (AAHPERD) has given vigorous, sustained support to the Research Quarterly. Many scholars may become disillusioned with this policy and submit their research to other more specialized journals. (CJ)

  12. Approximating the DGP of China's Quarterly GDP

    NARCIS (Netherlands)

    Ph.H.B.F. Franses (Philip Hans); H. Mees (Heleen)

    2010-01-01

    textabstractWe demonstrate that the data generating process (DGP) of China’s cumulated quarterly Gross Domestic Product (GDP, current prices), as it is reported by the National Bureau of Statistics of China, can be (very closely) approximated by a simple rule. This rule is that annual growth in any

  13. Approximating the DGP of China's Quarterly GDP

    NARCIS (Netherlands)

    Ph.H.B.F. Franses (Philip Hans); H. Mees (Heleen)

    2010-01-01

    textabstractWe demonstrate that the data generating process (DGP) of China’s cumulated quarterly Gross Domestic Product (GDP, current prices), as it is reported by the National Bureau of Statistics of China, can be (very closely) approximated by a simple rule. This rule is that annual growth in any

  14. Environmental and energy system analysis of bio-methane production pathways : A comparison between feedstocks and process optimizations

    NARCIS (Netherlands)

    Pierie, F.; van Someren, C. E. J.; Benders, R. M. J.; Bekkering, J.; van Gemert, W. J. Th; Moll, H. C.

    2015-01-01

    The energy efficiency and sustainability of an anaerobic green gas production pathway was evaluated, taking into account five biomass feedstocks, optimization of the green gas production pathway, replacement of current waste management pathways by mitigation, and transport of the feedstocks. Sustain

  15. 78 FR 49749 - Williams Olefins Feedstock Pipelines, L.L.C.; Notice of Petition for Declaratory Order

    Science.gov (United States)

    2013-08-15

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Williams Olefins Feedstock Pipelines, L.L.C.; Notice of Petition for... Practices and Procedure, 18 CFR 385.207(a)(2)(2012), Williams Olefins Feedstock Pipelines, L.L.C., filed...

  16. Idaho National Laboratory Quarterly Performance Analysis for the 2nd Quarter FY 2015

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Lisbeth A. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-04-01

    This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of events for the 2nd Qtr FY-15.

  17. Idaho National Laboratory Quarterly Performance Analysis - 3rd Quarter FY2014

    Energy Technology Data Exchange (ETDEWEB)

    Lisbeth A. Mitchell

    2014-09-01

    This report is published quarterly by the Idaho National Laboratory (INL) Performance Assurance Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of occurrence reports and other non-reportable issues identified at INL from July 2013 through June 2014.

  18. Effects of Game Location, Quality of Opposition, and Starting Quarter Score in the Outcome of Elite Water Polo Quarters.

    Science.gov (United States)

    Ruano, Miguel Á; Serna, Ana D; Lupo, Corrado; Sampaio, Jaime E

    2016-04-01

    The notational analysis is used to investigate teams' performance in water polo, especially focused on the determinants of success. Recently, a new topic has emerged "the situational variables," which includes the game conditions that may influence the performance at a behavioral level. The aim of this study was to identify the interactive effects of starting quarter score (SQS) (i.e., score difference at the beginning of each quarter and at the final score) and game location (GL) (i.e., home and away teams) in relation to quality of opposition (i.e., positions of difference between opposing teams at the end-of-season rankings) in elite men's water polo games. Data comprised 528 games (n = 2,112 quarters) from the first Spanish water polo division. A linear regression analysis was applied to show the impact of SQS and GL in relation to quality of opposition (unbalanced and balanced) for quarter (all quarters, and second, third, and fourth quarters). Results showed that SQS has an important effect for all quarters (0.16) and for the second (0.14) and third (0.14) quarters in balanced games (whereas the fourth quarter has an unpredictable outcome), and for each quarter (all quarters: 0.33; second quarter: 0.55; third quarter: 0.44; fourth quarter: 0.26) in unbalanced games. In addition, GL effects emerged for balanced (0.31) and unbalanced (0.45) games for all quarters and specifically for the second quarter of the unbalanced games. Therefore, this study showed that the elite water polo game dynamics, indirectly providing a reference for coaches (i.e., effective tactical approach) and physical trainers (i.e., high performance intensities), plans to improve their players' performance.

  19. Hydrocraquage sous pression d'une huile de soja : procédé d'étude et allure générale de la transformation Soybean Oil Hydrocracking under Pressure: Process and General Aspect of the Transformation

    Directory of Open Access Journals (Sweden)

    Nunes P. P.

    2006-11-01

    Full Text Available Un procédé d'étude de l'hydrocraquage des huiles végétales en autoclave est décrit. Les principaux objectifs de cette étude sont relatifs à la transformation de l'huile de soja (composé modèle en essence et gazole, en limitant la formation de polymères et de coke. L'analyse des gaz et la chromatographie haute résolution de deux fractions résultant de la distillation sous vide de la phase liquide ont permis de mettre en évidence les principales étapes de l'hydrocraquage. Pour cette première approche du processus général, trois types d'hydrocraquages ont été utilisés : thermique et en présence d'un oxyde ou d'un catalyseur bifonctionnel performant (hydrogénant/craquant. Dans ce dernier cas, l'hydrogénation des doubles liaisons des chaînes latérales des triglycérides a été mise en évidence pendant le chauffage du réacteur jusqu'à environ 673 K, température à laquelle s'initie le véritable hydrocraquage. A cette température sont observées la décarbonylation/décarboxylation des acides gras (précédemment issus de la coupure des liaisons ester des triglycérides et une hydrogénolyse marquée en présence d'un catalyseur métallique. Il en résulte principalement des alcanes dont la structure linéaire est celle des acides gras initiaux. Le rendement global brut peut atteindre 83 % dans les conditions de température et de pression choisies, y inclus le pourcentage en fraction gazeuse (CO, CO2, C1-C4 A laboratory process for studying the hydrocracking of vegetable oils in a high-pressure batch reactor is described. The main goals of this study concern the transformation of soybean oil (used as a model into gasoline and diesel fuel fractions while limiting polymerization and coking. Gas analysis and high-resolution chromatography of two liquid fractions resulting from vacuum distillation were used to determine the main steps in the hydrocracking process. For this initial study of the general process, the three

  20. 26 CFR 48.4082-7 - Kerosene; exemption for feedstock purposes.

    Science.gov (United States)

    2010-04-01

    ... 26 Internal Revenue 16 2010-04-01 2010-04-01 true Kerosene; exemption for feedstock purposes. 48.4082-7 Section 48.4082-7 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY... same form as the model certificate provided in paragraph (e)(2) of this section, and contains...

  1. A Century Long Pursuit of Alternative Fuels and Feedstocks: A Content Analysis

    Science.gov (United States)

    2011-03-01

    loss of forest land in Indonesia and a 20% loss in Malaysia while up to 85% of new palm oil plantations in some provinces being created on former...Dornburg, V., & Faaij, A. (2011). Exploring land use changes and the role of palm oil production in Indonesia and Malaysia. Land Use Policy, 193-206...50 Palm Oil as a Feedstock

  2. Towards fermentation of galacturonic acid-containing feedstocks with Saccharomyces cerevisiae

    NARCIS (Netherlands)

    Huisjes, E.H.

    2013-01-01

    The ambition to reduce our current dependence on fossil transportation fuels has driven renewed interest in bioethanol. Pectin-rich feedstocks like sugar beet pulp and citrus peel, which are currently sold as cattle feed, are promising raw materials for the production of bioethanol. This thesis expl

  3. Nutrient and water requirements for elephantgrass production as a bio-fuel feedstock

    Science.gov (United States)

    Elephantgrass (Pennisetum purpureum Schumacher) is a tall tropical bunch grass that produces high enough yields to being considered an excellent bio-energy feedstock for the lower South. However, previous studies have shown that production is not sustainable without fertilizer application and adequ...

  4. Development and Characterization of a Metal Injection Molding Bio Sourced Inconel 718 Feedstock Based on Polyhydroxyalkanoates

    Directory of Open Access Journals (Sweden)

    Alexandre Royer

    2016-04-01

    Full Text Available The binder plays the most important role in the metal injection molding (MIM process. It provides fluidity of the feedstock mixture and adhesion of the powder to keep the molded shape during injection molding. The binder must provide strength and cohesion for the molded part and must be easy to remove from the molded part. Moreover, it must be recyclable, environmentally friendly and economical. Also, the miscibility between polymers affects the homogeneity of the injected parts. The goal of this study is to develop a feedstock of superalloy Inconel 718 that is environmentally friendly. For these different binders, formulations based on polyethylene glycol (PEG, because of his water solubility property, and bio sourced polymers were studied. Polyhydroxyalkanoates (PHA were investigated as a bio sourced polymer due to its miscibility with the PEG. The result is compared to a standard formulation using polypropylene (PP. The chemical and rheological behavior of the binder formulation during mixing, injection and debinding process were investigated. The feedstock was characterized in the same way as the binders and the interactions between the powder and the binders were also studied. The results show the well adapted formulation of polymer binder to produce a superalloy Inconel 718 feedstock.

  5. Two-stage Hydrolysis of Invasive Algal Feedstock for Ethanol Fermentation

    Institute of Scientific and Technical Information of China (English)

    Xin Wang; Xianhua Liu; Guangyi Wang

    2011-01-01

    The overall goal of this work was to develop a saccharification method for the production of third generation biofuel(i.e.bioethanol) using feedstock of the invasive marine macroalga Gracilaria salicornia.Under optimum conditions(120℃ and 2% sulfuric acid for 30 min), dilute acid hydrolysis of the homogenized invasive plants yielded a low concentration of glucose(4.1mM or 4.3g glucose/kg fresh algal biomass). However, two-stage hydrolysis of the homogenates (combination of dilute acid hydrolysis with enzymatic hydrolysis) produced 13.8g of glucose from one kilogram of fresh algal feedstock. Batch fermentation analysis produced 79.1g EtOH from one kilogram of dried invasive algal feedstock using the ethanologenic strain Escherichia coli K011. Furthermore, ethanol production kinetics indicated that the invasive algal feedstock contained different types of sugar, including C5-sugar. This study represents the first report on third generation biofuel production from invasive macroalgae, suggesting that there is great potential for the production of renewable energy using marine invasive biomass.

  6. Weed Control Systems for Peanut (Arachis hypogaea L.) Grown as a Biofuel Feedstock

    Science.gov (United States)

    Peanut (Arachis hypogaea L.) has not been utilized as a true oilseed crop, especially for the production of fuel. However, peanut makes a superior feedstock for biodiesel, especially in on-farm or small cooperative business plans, where producers can dictate the cost of making their own fuel. Fiel...

  7. Effect of organic loading rate and feedstock composition on foaming in manure-based biogas reactors

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; Angelidaki, Irini

    2013-01-01

    Foaming is one of the major problems that occasionally occur in biogas plants, affecting negatively the overall digestion process. In the present study, the effect of organic loading rate (OLR) and feedstock composition on foaming was elucidated in continuous reactor experiments. By stepwise...

  8. Interactions of woody biofuel feedstock production systems with water resources: considerations for sustainability

    Science.gov (United States)

    Carl C. Trettin; Devendra Amatya; Mark Coleman

    2008-01-01

    Water resources are important for the production of woody biofuel feedstocks. It is necessary to ensure that production systems do not adversely affect the quantity or quality of surface and ground water. The effects of woody biomass plantations on water resources are largely dependent on the prior land use and the management regime. Experience from both irrigated and...

  9. Effects of Biochar Feedstock and Pyrolysis Temperature on Growth of Corn, Soybean, Lettuce and Carrot

    Science.gov (United States)

    Biochar, the carbon-rich material remaining after pyrolysis (low oxygen) of cellulosic feedstocks, has the potential as a soil amendment to sequester carbon, improve soil water-holding capacity, and increase nutrient retention thereby enhancing soil conditions to benefit plant gr...

  10. Drought effects on composition and yield for corn stover, mixed grasses, and Miscanthus as bioenergy feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Rachel Emerson; Amber Hoover; Allison Ray; Jeffrey Lacey; Marnie Cortez; Courtney Payne; Doug Karlen; Stuart Birrell; David Laird; Robert Kallenbach; Josh Egenolf; Matthew Sousek; Thomas Voigt

    2014-11-01

    Drought conditions in 2012 were some of the most severe reported in the United States. It is necessary to explore the effects of drought on the quality attributes of current and potential bioenergy feedstocks. Compositional analysis data for corn stover, Miscanthus, and CRP grasses from one or more locations for years 2010 (normal precipitation levels) and 2012 (a known severe drought year nationally) was collected. Results & discussion: The general trend for samples that experienced drought was an increase in extractives and a decrease in structural sugars and lignin. The TEY yields were calculated to determine the drought effects on ethanol production. All three feedstocks had a decrease of 12-14% in TEY when only decreases of carbohydrate content was analyzed. When looking at the compounded effect of both carbohydrate content and the decreases in dry matter loss for each feedstock there was a TEY decrease of 25%-59%. Conclusion: Drought had a significant impact on the quality of all three bioenergy crops. In all cases where drought was experienced both the quality of the feedstock and the yield decreased. These drought induced effects could have significant economic impacts on biorefineries.

  11. Surface properties correlate to the digestibility of hydrothermally pretreated lignocellulosic Poaceae biomass feedstocks

    DEFF Research Database (Denmark)

    Tristan Djajadi, Demi; Hansen, Aleksander R.; Jensen, Anders

    2017-01-01

    in response to hydrothermal pretreatment at different severities are still not sufficiently understood. Results: Potentially important lignocellulosic feedstocks for biorefining, corn stover (Zea mays subsp. mays L.), stalks of Miscanthus × giganteus, and wheat straw (Triticum aestivum L.) were systematically...... lignocellulosic biomass and may help design new approaches to overcome biomass recalcitrance....

  12. Effects of Biochar Feedstock and Pyrolysis Temperature on Growth of Corn, Soybean, Lettuce and Carrot

    Science.gov (United States)

    Biochar, the carbon-rich material remaining after pyrolysis (low oxygen) of cellulosic feedstocks, has the potential as a soil amendment to sequester carbon, improve soil water-holding capacity, and increase nutrient retention thereby enhancing soil conditions to benefit plant gr...

  13. Valorization of guayule as a feedstock for lignocellulosic biorefineries using ammonia fiber expansion (AFEX) pretreatment

    Science.gov (United States)

    Natural rubber latex extraction from guayule leaves behind greater than 80% (by weight) of agricultural residue as a feedstock suitable for conversion to biofuels via a thermochemical or biochemical route. Untreated guayule shrub and bagasse (after latex extraction) has shown to be very recalcitrant...

  14. CONTEXT MATTERS: THE IMPORTANCE OF MARKET CHARACTERISTICS IN THE VOLATILITY OF FEEDSTOCK COSTS FOR BIOGAS PLANTS.

    Science.gov (United States)

    Mertens, A; Van Meensel, J; Mondelaers, K; Buysse, J

    2015-01-01

    Recently, biogas plant managers in Flanders face increased financial uncertainty. Between 2011 and 2012, 20% of the Flemish biogas plants went bankrupt. Difficulties in obtaining feedstock at stable and affordable prices is one reason why the biogas sector struggles. In literature, contracting is often proposed as a way to decrease the volatility of the feedstock costs. However, these studies generally do not consider the context in which the biogas plant manager needs to buy the feedstock. Yet, this context could be of specific importance when biogas plant managers are in competition with other users of the same biomass type. Silage maize is an example of such a feedstock, as it is both used by dairy farmers and biogas plant managers. Using a combination of qualitative research and agent-based modelling, we investigated the effect of specific characteristics of the silage maize market on the acquisition of local silage maize by biogas plant managers. This paper details the institutional arrangements of the silage maize market in Flanders and the results of a scenario analysis, simulating three different scenarios. As shown by the results, the time of entry into the market, as well as the different institutional arrangements used by the biogas plant managers as opposed to dairy farmers could explain the difficulties in obtaining a stable supply of local silage maize by biogas plants. Our findings can help to develop mitigation strategies addressing these difficulties.

  15. Dislocation formation in seed crystals induced by feedstock indentation during growth of quasimono crystalline silicon ingots

    Science.gov (United States)

    Trempa, M.; Beier, M.; Reimann, C.; Roßhirth, K.; Friedrich, J.; Löbel, C.; Sylla, L.; Richter, T.

    2016-11-01

    In this work the dislocation formation in the seed crystal induced by feedstock indentation during the growth of quasimono (QM) silicon ingots for photovoltaic application was investigated. It could be shown by special laboratory indentation experiments that the formed dislocations propagate up to several millimeters deep into the volume of the seed crystal in dependence on the applied pressure of the feedstock particles on the surface of the seed crystal. Further, it was demonstrated that these dislocations if they were not back-melted during the seeding process grow further into the silicon ingot and drastically reduce its material quality. An estimation of the apparent pressure values in a G5 industrial crucible/feedstock setup reveals that the indentation phenomenon is a critical issue for the industrial production of QM silicon ingots. Therefore, some approaches to avoid/reduce the indentation events were tested with the result, that the most promising solution should be the usage of suitable feedstock particles as coverage of the seed.

  16. Sorghum as a renewable feedstock for production of fuels and industrial chemicals

    Science.gov (United States)

    Considerable efforts have been made in the USA and other countries to develop renewable feedstocks for production of fuels and chemicals. Among these, sorghum has attracted strong interest because of its many good characteristics such as rapid growth and high sugar accumulation, high biomass product...

  17. Influence of feedstock particle size on lignocellulose conversion--a review.

    Science.gov (United States)

    Vidal, Bernardo C; Dien, Bruce S; Ting, K C; Singh, Vijay

    2011-08-01

    Feedstock particle sizing can impact the economics of cellulosic ethanol commercialization through its effects on conversion yield and energy cost. Past studies demonstrated that particle size influences biomass enzyme digestibility to a limited extent. Physical size reduction was able to increase conversion rates to maximum of ≈ 50%, whereas chemical modification achieved conversions of >70% regardless of biomass particle size. This suggests that (1) mechanical pretreatment by itself is insufficient to attain economically feasible biomass conversion, and, therefore, (2) necessary particle sizing needs to be determined in the context of thermochemical pretreatment employed for lignocellulose conversion. Studies of thermochemical pretreatments that have taken into account particle size as a factor have exhibited a wide range of maximal sizes (i.e., particle sizes below which no increase in pretreatment effectiveness, measured in terms of the enzymatic conversion resulting from the pretreatment, were observed) from pretreatment employed, with maximal size range decreasing as follows: steam explosion > liquid hot water > dilute acid and base pretreatments. Maximal sizes also appeared dependent on feedstock, with herbaceous or grassy biomass exhibiting lower maximal size range (biomass (>3 mm). Such trends, considered alongside the intensive energy requirement of size reduction processes, warrant a more systematic study of particle size effects across different pretreatment technologies and feedstock, as a requisite for optimizing the feedstock supply system.

  18. Biodiesel from Citrus reticulata (Mandarin orange) seed oil, a potential non-food feedstock

    Science.gov (United States)

    Oil extracted from Citrus reticulata (Mandarin orange) seeds was investigated as a potential feedstock for the production of biodiesel. The biodiesel fuel was prepared by sodium methoxide-catalyzed transesterification of the oil with methanol. Fuel properties that were determined include cetane numb...

  19. Effect of biochemical factors from mixed animal wastes feedstock in biogas production

    Science.gov (United States)

    Animal wastes can serve as the feedstock for biogas production (mainly methane) that could be used as alternative energy source. The green energy derived from animal wastes is considered to be carbon neutral and offsetting those generated from fossil fuels. In this study, an evaluation of methane...

  20. Evaluation of biochemical factors from mixed animal wastes feedstock in biogas production

    Science.gov (United States)

    Animal wastes can serve as the feedstock for biogas production (mainly methane) that could be used as alternative energy source. The green energy derived from animal wastes is considered to be carbon neutral and offsetting those generated from fossil fuels. In this study, an evaluation of methane ...

  1. Dedicated Industrial Oilseed Crops as Metabolic Engineering Platforms for Sustainable Industrial Feedstock Production

    NARCIS (Netherlands)

    Zhu, Li Hua; Krens, Frans; Smith, Mark A.; Li, Xueyuan; Qi, Weicong; Loo, Van Eibertus N.; Iven, Tim; Feussner, Ivo; Nazarenus, Tara J.; Huai, Dongxin; Taylor, David C.; Zhou, Xue Rong; Green, Allan G.; Shockey, Jay; Klasson, Thomas K.; Mullen, Robert T.; Huang, Bangquan; Dyer, John M.; Cahoon, Edgar B.

    2016-01-01

    Feedstocks for industrial applications ranging from polymers to lubricants are largely derived from petroleum, a non-renewable resource. Vegetable oils with fatty acid structures and storage forms tailored for specific industrial uses offer renewable and potentially sustainable sources of petroch

  2. Models to Predict the Viscosity of Metal Injection Molding Feedstock Materials as Function of Their Formulation

    Directory of Open Access Journals (Sweden)

    Joamin Gonzalez-Gutierrez

    2016-05-01

    Full Text Available The viscosity of feedstock materials is directly related to its processability during injection molding; therefore, being able to predict the viscosity of feedstock materials based on the individual properties of their components can greatly facilitate the formulation of these materials to tailor properties to improve their processability. Many empirical and semi-empirical models are available in the literature that can be used to predict the viscosity of polymeric blends and concentrated suspensions as a function of their formulation; these models can partly be used also for metal injection molding binders and feedstock materials. Among all available models, we made a narrow selection and used only simple models that do not require knowledge of molecular weight or density and have parameters with physical background. In this paper, we investigated the applicability of several of these models for two types of feedstock materials each one with different binder composition and powder loading. For each material, an optimal model was found, but each model was different; therefore, there is not a universal model that fits both materials investigated, which puts under question the underlying physical meaning of these models.

  3. Exometabolomics Approaches in Studying the Application of Lignocellulosic Biomass as Fermentation Feedstock

    NARCIS (Netherlands)

    Zha, Y.; Punt, P.J.

    2013-01-01

    Lignocellulosic biomass is the future feedstock for the production of biofuel and bio-based chemicals. The pretreatment-hydrolysis product of biomass, so-called hydrolysate, contains not only fermentable sugars, but also compounds that inhibit its fermentability by microbes. To reduce the toxicity o

  4. Sustainable bioenergy feedstock production systems: Integrating carbon dynamics, erosion, water quality, and greenhouse gas production

    Science.gov (United States)

    Reducing greenhouse gas (GHG) emission is one of several rationales for developing renewable biomass energy. Unfortunately, there are few studies reporting direct impacts of harvesting biomass feedstocks on GHG, especially effects on nitrous oxide (N2O) flux. Overzealous biomass harvest may accelera...

  5. Ericameria Nauseosa (rubber rabbitbrush): a complementary rubber feedstock to augment the guayule rubber production stream

    Science.gov (United States)

    Ericameria nauseosa (rubber rabbitbrush) is a highly prolific desert shrub that produces high quality natural rubber. Over the past several years we have investigated rabbitbrush’s potential as a commercial rubber feedstock. Like guayule, rabbitbrush produces natural rubber within its bark tissues a...

  6. Apparatus and method for converting biomass to feedstock for biofuel and biochemical manufacturing processes

    Science.gov (United States)

    Kania, John; Qiao, Ming; Woods, Elizabeth M.; Cortright, Randy D.; Myren, Paul

    2015-12-15

    The present invention includes improved systems and methods for producing biomass-derived feedstocks for biofuel and biochemical manufacturing processes. The systems and methods use components that are capable of transferring relatively high concentrations of solid biomass utilizing pressure variations between vessels, and allows for the recovery and recycling of heterogeneous catalyst materials.

  7. Gene flow matters in switchgrass (Panicum virgatum L.), a potential widespread biofuel feedstock.

    Science.gov (United States)

    Kwit, Charles; Stewart, C Neal

    2012-01-01

    There currently exists a large push for the use, improvement, and expansion via landscape modification of dedicated biofuel crops (feedstocks) in the United States and in many parts of the world. Ecological concerns have been voiced because many biofuel feedstocks exhibit characteristics associated with invasiveness, and due to potential negative consequences of agronomic genes in native wild populations. Seed purity concerns for biofuel feedstock cultivars whose seeds would be harvested in agronomic fields also exist from the agribusiness sector. The common thread underlying these concerns, which have regulatory implications, is gene flow; thus detailed knowledge of gene flow in biofuel crop plants is important in the formulation of environmental risk management plans. Here, we synthesize the current state of knowledge of gene flow in an exemplary biofuel crop, switchgrass (Panicum virgatum L.), which is native to eastern North America and is currently experiencing conventional and technological advances in biomass yields and ethanol production. Surprisingly little is known regarding aspects of switchgrass pollen flow and seed dispersal, and whether native populations of conspecific or congeneric relatives will readily cross with current agronomic switchgrass cultivars. We pose that filling these important gaps will be required to confront the sustainability challenges of widespread planting of biofuel feedstocks.

  8. Dedicated Industrial Oilseed Crops as Metabolic Engineering Platforms for Sustainable Industrial Feedstock Production

    NARCIS (Netherlands)

    Zhu, Li Hua; Krens, Frans; Smith, Mark A.; Li, Xueyuan; Qi, Weicong; Loo, Van Eibertus N.; Iven, Tim; Feussner, Ivo; Nazarenus, Tara J.; Huai, Dongxin; Taylor, David C.; Zhou, Xue Rong; Green, Allan G.; Shockey, Jay; Klasson, Thomas K.; Mullen, Robert T.; Huang, Bangquan; Dyer, John M.; Cahoon, Edgar B.

    2016-01-01

    Feedstocks for industrial applications ranging from polymers to lubricants are largely derived from petroleum, a non-renewable resource. Vegetable oils with fatty acid structures and storage forms tailored for specific industrial uses offer renewable and potentially sustainable sources of petroch

  9. Evaluation of Indian milkweed (Calotropis gigantea) seed oil as alternative feedstock for biodiesel

    Science.gov (United States)

    Calotropis gigantea (Indian milkweed) is a common plant in Asia that grows as a weed on open waste ground. Flowering and fruiting take place throughout the year. In this study, Indian milkweed oil was evaluated as a potential feedstock for biodiesel production. The oil was extracted from Indian milk...

  10. Multi-utilization of swine manure as a bioenergy feedstock: Carbonization and combustion

    Science.gov (United States)

    The use of animal manure and other organic-based waste products as bioenergy feedstocks is gaining interest for waste-to-bioenergy conversion processes. While thermochemical conversion of animal manure via combustion, pyrolysis, and gasification is becoming a new frontier of manure treatment; there ...

  11. The National Biofuels Strategy - Importance of sustainable feedstock production systems in regional-based supply chains

    Science.gov (United States)

    Region-based production systems are needed to produce the feedstocks that will be turned into the biofuels required to meet Federal mandated targets. Executive and Legislative actions have put into motion significant government responses designed to advance the development and production of domestic...

  12. Analyzing hydrotreated renewable jet fuel (HRJ) feedstock availability using crop simulation modeling

    Science.gov (United States)

    While hydrotreated renewable jet fuel (HRJ) has been demonstrated for use in commercial and military aviation, a challenge to large-scale adoption is availability of cost competitive feedstocks. Brassica oilseed crops like Brassica napus, B. rapa, B. juncea, B. carinata, Sinapis alba, and Camelina s...

  13. An overview of palm, jatropha and algae as a potential biodiesel feedstock in Malaysia

    Science.gov (United States)

    Yunus, S.; Abdullah, N. R.; Mamat, R.; Rashid, A. A.

    2013-12-01

    The high demand to replace petroleum fuel makes renewable and sustainable sources such as Palm oil, Jatropha oil and Algae a main focus feedstock for biodiesel production in Malaysia. There are many studies conducted on Palm oil and Jatropha oil, however, the use of Algae as an alternative fuel is still in its infancy. Malaysia already implemented B5 based Palm oil as a feedstock and this biodiesel has been proven safe and can be used without any engine modification. The use of biodiesel produced from these feedstock will also developed domestic economic and provide job opportunities especially in the rural area. In addition, biodiesel has many advantages especially when dealing with the emissions produce as compared to petroleum fuel such as; it can reduce unwanted gases and particulate matter harmful to the atmosphere and mankind. Thus, this paper gathered and examines the most prominent engine emission produced from Palm oil and Jatropha feedstock and also to observe the potential of Algae to be one of the sources of alternative fuel in Malaysia.

  14. Biomass Feedstock Availability in the United States: 1999 State Level Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Walsh, Marie E. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Perlack, Robert L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Turhollow, Anthony [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); de la Torre Ugarte, Daniel [Univ. of Tennessee, Knoxville, TN (United States); Becker, Denny A. [Science Applications International Corporation, Oak Ridge, TN (United States); Graham, Robin L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Slinsky, Stephen E. [Univ. of Tennessee, Knoxville, TN (United States); Ray, Daryll E. [Univ. of Tennessee, Knoxville, TN (United States)

    2000-01-01

    Interest in using biomass feedstocks to produce power, liquid fuels, and chemicals in the U.S. is increasing. Central to determining the potential for these industries to develop is an understanding of the location, quantities, and prices of biomass resources. This paper describes the methodology used to estimate biomass quantities and prices for each state in the continental United States.

  15. Agave: a biofuel feedstock for arid and semi-arid environments

    Energy Technology Data Exchange (ETDEWEB)

    Gross, Stephen; Martin, Jeffrey; Simpson, June; Wang, Zhong; Visel, Axel

    2011-05-31

    Efficient production of plant-based, lignocellulosic biofuels relies upon continued improvement of existing biofuel feedstock species, as well as the introduction of newfeedstocks capable of growing on marginal lands to avoid conflicts with existing food production and minimize use of water and nitrogen resources. To this end, specieswithin the plant genus Agave have recently been proposed as new biofuel feedstocks. Many Agave species are adapted to hot and arid environments generally unsuitable forfood production, yet have biomass productivity rates comparable to other second-generation biofuel feedstocks such as switchgrass and Miscanthus. Agavesachieve remarkable heat tolerance and water use efficiency in part through a Crassulacean Acid Metabolism (CAM) mode of photosynthesis, but the genes andregulatory pathways enabling CAM and thermotolerance in agaves remain poorly understood. We seek to accelerate the development of agave as a new biofuelfeedstock through genomic approaches using massively-parallel sequencing technologies. First, we plan to sequence the transcriptome of A. tequilana to provide adatabase of protein-coding genes to the agave research community. Second, we will compare transcriptome-wide gene expression of agaves under different environmentalconditions in order to understand genetic pathways controlling CAM, water use efficiency, and thermotolerance. Finally, we aim to compare the transcriptome of A.tequilana with that of other Agave species to gain further insight into molecular mechanisms underlying traits desirable for biofuel feedstocks. These genomicapproaches will provide sequence and gene expression information critical to the breeding and domestication of Agave species suitable for biofuel production.

  16. Quarterly coal report July--September 1996, February 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-02-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1996 and aggregated quarterly historical data for 1990 through the second quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data. 8 figs., 72 tabs.

  17. Quarterly coal report July--September 1996, February 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-02-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1996 and aggregated quarterly historical data for 1990 through the second quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data. 8 figs., 72 tabs.

  18. Greenhouse gas mitigation for U.S. plastics production: energy first, feedstocks later

    Science.gov (United States)

    Posen, I. Daniel; Jaramillo, Paulina; Landis, Amy E.; Griffin, W. Michael

    2017-03-01

    Plastics production is responsible for 1% and 3% of U.S. greenhouse gas (GHG) emissions and primary energy use, respectively. Replacing conventional plastics with bio-based plastics (made from renewable feedstocks) is frequently proposed as a way to mitigate these impacts. Comparatively little research has considered the potential for green energy to reduce emissions in this industry. This paper compares two strategies for reducing greenhouse gas emissions from U.S. plastics production: using renewable energy or switching to renewable feedstocks. Renewable energy pathways assume all process energy comes from wind power and renewable natural gas derived from landfill gas. Renewable feedstock pathways assume that all commodity thermoplastics will be replaced with polylactic acid (PLA) and bioethylene-based plastics, made using either corn or switchgrass, and powered using either conventional or renewable energy. Corn-based biopolymers produced with conventional energy are the dominant near-term biopolymer option, and can reduce industry-wide GHG emissions by 25%, or 16 million tonnes CO2e/year (mean value). In contrast, switching to renewable energy cuts GHG emissions by 50%–75% (a mean industry-wide reduction of 38 million tonnes CO2e/year). Both strategies increase industry costs—by up to 85/tonne plastic (mean result) for renewable energy, and up to 3000 tonne‑1 plastic for renewable feedstocks. Overall, switching to renewable energy achieves greater emission reductions, with less uncertainty and lower costs than switching to corn-based biopolymers. In the long run, producing bio-based plastics from advanced feedstocks (e.g. switchgrass) and/or with renewable energy can further reduce emissions, to approximately 0 CO2e/year (mean value).

  19. Microbial production host selection for converting second-generation feedstocks into bioproducts

    Directory of Open Access Journals (Sweden)

    van Groenestijn Johan W

    2009-12-01

    Full Text Available Abstract Background Increasingly lignocellulosic biomass hydrolysates are used as the feedstock for industrial fermentations. These biomass hydrolysates are complex mixtures of different fermentable sugars, but also inhibitors and salts that affect the performance of the microbial production host. The performance of six industrially relevant microorganisms, i.e. two bacteria (Escherichia coli and Corynebacterium glutamicum, two yeasts (Saccharomyces cerevisiae and Pichia stipitis and two fungi (Aspergillus niger and Trichoderma reesei were compared for their (i ability to utilize monosaccharides present in lignocellulosic hydrolysates, (ii resistance against inhibitors present in lignocellulosic hydrolysates, (iii their ability to utilize and grow on different feedstock hydrolysates (corn stover, wheat straw, sugar cane bagasse and willow wood. The feedstock hydrolysates were generated in two manners: (i thermal pretreatment under mild acid conditions followed by enzymatic hydrolysis and (ii a non-enzymatic method in which the lignocellulosic biomass is pretreated and hydrolyzed by concentrated sulfuric acid. Moreover, the ability of the selected hosts to utilize waste glycerol from the biodiesel industry was evaluated. Results Large differences in the performance of the six tested microbial production hosts were observed. Carbon source versatility and inhibitor resistance were the major discriminators between the performances of these microorganisms. Surprisingly all 6 organisms performed relatively well on pretreated crude feedstocks. P. stipitis and A. niger were found to give the overall best performance C. glutamicum and S. cerevisiae were shown to be the least adapted to renewable feedstocks. Conclusion Based on the results obtained we conclude that a substrate oriented instead of the more commonly used product oriented approach towards the selection of a microbial production host will avoid the requirement for extensive metabolic

  20. Impact of Technology and Feedstock Choice on the Environmental Footprint of Biofuels

    Science.gov (United States)

    Schultz, P. B.; Dodder, R. S.

    2012-12-01

    The implementation of the U.S. Renewable Fuel Standard program (RFS2) has led to a dramatic shift in the use of biofuel in the U.S. transportation system over the last decade. To satisfy this demand, the production of U.S. corn-based ethanol has grown rapidly, with an average increase of over 25% annually from 2002 to 2010. RFS2 requires a similarly steep increase in the production of advanced biofuels, such as cellulosic ethanol. Unlike corn-based ethanol, which is derived from the biochemical fermentation of sugars in wet and dry mills, it is likely that a more diverse suite of technologies will need to be developed to be able to meet the advanced biofuel RFS2 targets, including biochemical as well as thermochemical (e.g., gasification and pyrolysis) approaches. Rather than relying on energy crops, a potential advantage of thermochemical approaches is the ability to use a wider variety of feedstocks, including municipal solid waste and wood waste. In this work, we conduct a system-level analysis to understand how technology and feedstock choice can impact the environmental footprint of biofuels in the U.S. We use a least-cost optimization model of the U.S. energy system to account for interactions between various components of the energy system: industrial, transportation, electric, and residential/commercial sectors. The model was used to understand the scale of feedstock demand required from dedicated energy crops, as well as other biomass feedstocks, in order to meet the RFS2 mandate. On a regional basis, we compare the overall water-consumption and land requirements for biofuels production given a suite of liquid-fuel production technologies. By considering a range of scenarios, we examine how the use of various feedstocks (e.g., agricultural residues, wood wastes, mill residues and municipal wastes) can be used to off-set environmental impacts as compared to relying solely on energy crops.

  1. Bio-energy feedstock yields and their water quality benefits in Mississippi

    Energy Technology Data Exchange (ETDEWEB)

    Parajuli, Prem B.

    2011-08-10

    Cellulosic and agricultural bio-energy crops can, under careful management, be harvested as feedstock for bio-fuels production and provide environmental benefits. However, it is required to quantify their relative advantages in feedstock production and water quality. The primary objective of this research was to evaluate potential feedstock yield and water quality benefit scenarios of bioenergy crops: Miscanthus (Miscanthus-giganteus), Switchgrass (Panicum virgatum), Johnsongrass (Sorghum halepense), Alfalfa (Medicago sativa L.), Soybean {Glycine max (L.) Merr.}, and Corn (Lea mays) in the Upper Pearl River watershed (UPRW), Mississippi using a Soil and Water Assessment Tool (SWAT). The SWAT model was calibrated (January 1981 to December 1994) and validated (January 1995 to September 2008) using monthly measured stream flow data. The calibrated and validated model determined good to very good performance for stream flow prediction (R2 and E from 0.60 to 0.86). The RMSE values (from 14 m3 s-1 to 37 m3 s-1) were estimated at similar levels of errors during model calibration and validation. The long-term average annual potential feedstock yield as an alternative energy source was determined the greatest when growing Miscanthus grass (373,849 Mg) as followed by Alfalfa (206,077 Mg), Switchgrass (132,077 Mg), Johnsongrass (47,576 Mg), Soybean (37,814 Mg), and Corn (22,069 Mg) in the pastureland and cropland of the watershed. Model results determined that average annual sediment yield from the Miscanthus grass scenario determined the least (1.16 Mg/ha) and corn scenario the greatest (12.04 Mg/ha). The SWAT model simulated results suggested that growing Miscanthus grass in the UPRW would have the greatest potential feedstock yield and water quality benefits.

  2. Plant oils as feedstock alternatives to petroleum - A short survey of potential oil crop platforms.

    Science.gov (United States)

    Carlsson, Anders S

    2009-06-01

    Our society is highly depending on petroleum for its activities. About 90% is used as an energy source for transportation and for generation of heat and electricity and the remaining as feedstocks in the chemical industry. However, petroleum is a finite source as well as causing several environmental problems such as rising carbon dioxide levels in the atmosphere. Petroleum therefore needs to be replaced by alternative and sustainable sources. Plant oils and oleochemicals derived from them represent such alternative sources, which can deliver a substantial part of what is needed to replace the petroleum used as feedstocks. Plant derived feedstock oils can be provided by two types of oil qualities, multi-purpose and technical oils. Multi-purpose oils represent oil qualities that contain common fatty acids and that can be used for both food and feedstock applications. Technical oil qualities contain unusual fatty acids with special properties gained from their unique molecular structure and these types of oils should only be used for feedstock applications. As a risk mitigation strategy in the selection of crops, technical oil qualities should therefore preferably be produced by oil crop platforms dedicated for industrial usage. This review presents a short survey of oil crop platforms to be considered for either multi-purpose or technical oils production. Included among the former platforms are some of the major oil crops in cultivation such as oil palm, soybean and rapeseed. Among the later are those that could be developed into dedicated industrial platforms such as crambe, flax, cotton and Brassica carinata. The survey finishes off by highlighting the potential of substantial increase in plant oil production by developing metabolic flux platforms, which are starch crops converted into oil crops.

  3. Analyses of Problems of Dry Gas Seals in a Cycle Compressor of Hydrocracking Unit%加氢裂化装置干气密封的故障分析与改造

    Institute of Scientific and Technical Information of China (English)

    钟伟明; 李纪云; 许静

    2011-01-01

    针对某厂加氢裂化装置循环压缩机轴端用T型槽干气密封(T-DGS)在开工不久和首次改造后使用过程中连续两次失效造成停车的事故,对干气密封进行解体分析,提出密封失效的原因和相应的技改措施,在解决现场装置中存在的主密封气短路、密封气带液、火炬气反窜等问题之后,机组开车一次成功,确保了生产装置的安全稳定运行.有关成果将为现场T-DGS出现相似问题的及时解决及T-DGS的设计提供有益指导.%Dry gas seals with T-grooves were disintegrated and analyzed for resolving the problems related to the two continuous failures when they were used in a cycle compressor of hydrocracking unit. The causes for the failures of such T-grooved dry gas seals and their solutions were presented. The cycle compressor with the improved T-grooved gas seal had operated successfully at one time after the problems were resolved, which mainly- referred to primary sealed gas short-circle, sealed gas condensed to liquid,flare gas returning. The unit was sure to be running in normal condition. The methods and experiences presented here should be useful to the problems resolved and the geometrical designs of a T-grooved dry gas seal.

  4. 加氢裂化装置往复压缩机填料密封故障分析与改造%Failure Analysis and Transformation on Reciprocating Compressor Packing Seal of Hydrocracking Unit

    Institute of Scientific and Technical Information of China (English)

    莫才颂; 吴海智

    2012-01-01

    针对加氢裂化装置C102新型往复压缩机填料密封存在的泄漏问题,对压缩机气缸活塞填料密封结构、密封原理及其密封条件进行研究,在对密封填料函结构和填料受力等讨论的基础上,分析压缩机气缸填料密封失效的主要原因,提出改进填料密封环结构、冷却系统、规范密封环加工工艺程序及优化安装等措施.实践证明,改造后密封效果显著提高,设备使用寿命延长.%According to the packing seal leakage problems existed at new reciprocating compressor of C102 hydrocrac-king unit,the compressor cylinder piston filler sealing structure,sealing principle and sealing condition were studied. Based on discussion to the seal stuffing box structure and packing stress and etc. ,the main reason resulting in compressor cylinder packing seal failure was analyzed. Some measures including improving the filler sealing ring structure and cooling system, regulating the processing technology and optimizing the program of sealing ring installation were put forward. Practice proves,after the transformation,the sealing effect is significantly enhanced,unit use has longer life spans.

  5. The role of microalgae as biodiesel feedstock in a tropical setting: Economics, agro-energy competitiveness, and potential impacts on regional agricultural feedstock production

    Science.gov (United States)

    Boll, Matias G.

    The objective of this study is to obtain a realistic evaluation of the potential role of microalgae as a biodiesel feedstock in a tropical setting. First, microalgae economics are estimated, including the detailed design of a 400 ha microalgae open pond production farm together with the microalgae biomass and crude oil production costs calculations. Sensitivity analysis and a stochastic evaluation of the microalgae venture chances for profit are also included. Next, microalgae potential for biodiesel production is compared to traditional oil crops such as soybeans and African palm. This comparison is performed using the Northeast Region (NER) of Brazil as background. Six potential biodiesel feedstock sources produced in the NER and microalgae are compared considering selected environmental, economic and social sustainability indicators. Finally, in the third chapter, the study proposes a cropland allocation model for the NER. The model aims to offer insights to the decision maker concerning biofuel development strategies and their impact on regional agricultural feedstock production. In the model, cropland allocation among three agriculture feedstock sectors, namely staple food, commodity export and biofuel is optimized through the use of the multiple objective technique referred to as compromise programming (CP). Our results indicate a projected microalgae total production cost of R 78,359 ha-1 (US43,533), which has a breakdown as follows: R 34,133 ha-1 (US18,963) for operating costs and R 44,226 ha-1 (US24,570) for overhead (ownership) costs. Our stochastic analysis indicates that microalgae production under the conditions assumed in the baseline scenario of this study has a 0% chance to present a positive NPV for a microalgae crude oil price of R 1.86. This price corresponds to an international oil price around US 77 bbl-1. To obtain a reasonable investment return (IRR = 12%) from the microalgae farm, an international oil price as high as US 461 bbl-1 is

  6. Review of the Proposed Quarterly Coal Review

    Energy Technology Data Exchange (ETDEWEB)

    1981-04-01

    This Review of the Proposed Quarterly Coal Review is the second of two reports and contains the results of our analysis of issues regarding the publication of a new summary publication, the Quarterly Coal Review. The first report on the QCR was submitted to the Office of Energy Data Operations (OEDO) in January 1981 and included results of our analysis and recommendations concerning data availability and content organization. This report concentrates on data presentation and publication format for the proposed QCR. Comprised of two sections, the report addresses chapter and table formats and presents a detailed analysis of chapter content. The first section of this report, Chapter, Table and Graph Formats, consists of findings and recommendations on the ordering, titling, end notes and cosmetics of the tables proposed for the QCR. The next section, Detailed Analysis of Chapter Content, is the result of a more in-depth analysis of chapters in the QCR.

  7. Potential land competition between open-pond microalgae production and terrestrial dedicated feedstock supply systems in the U.S.

    Energy Technology Data Exchange (ETDEWEB)

    Langholtz, Matthew H.; Coleman, Andre M.; Eaton, Laurence M.; Wigmosta, Mark S.; Hellwinckel, Chad M.; Brandt, Craig C.

    2016-08-01

    Biofuels produced from both terrestrial and algal biomass feedstocks can contribute to energy security while providing economic, environmental, and social benefits. To assess the potential for land competition between these two feedstock types in the United States, we evaluate a scenario in which 41.5 x 109 L yr-1 of second-generation biofuels are produced on pastureland, the most likely land base where both feedstock types may be deployed. This total includes 12.0 x 109 L yr-1 of biofuels from open-pond microalgae production and 29.5 x 109 L yr-1 of biofuels from terrestrial dedicated feedstock supply systems. Under these scenarios, open-pond microalgae production is projected to use 1.2 million ha of private pastureland, while terrestrial dedicated feedstock supply systems would use 14.0 million ha of private pastureland. A spatial meta-analysis indicates that potential competition for land under these scenarios would be concentrated in 110 counties, containing 1.0 and 1.7 million hectares of algal and terrestrial dedicated feedstock production, respectively. A land competition index applied to these 110 counties suggests that 38 to 59 counties could experience competition for upwards of 40% of a county’s pastureland. However, this combined 2.7 million ha represents only 2%-5% of total pastureland in the U.S., with the remaining 12.5 million ha of algal or terrestrial dedicated feedstock production on pastureland in non-competing areas.

  8. A Walk around Irkutsk’s Quarters

    Directory of Open Access Journals (Sweden)

    Elena Grigoryeva

    2016-10-01

    Full Text Available The article presents the key issues of the Concept of reconstruction of the 11 Irkutsk’s quarters adjacent to the Trading Axis. While remaining basic, the trading function should reduce its overwhelming domination to be in harmony with other functions of the city environment, which attract inhabitants and guests to the historical area of Irkutsk, that is culture, education, leisure, recreation, and housing.

  9. A Notice Soliciting Contribution to Peace Quarterly

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    Dear readers at home and abroad:Peace quarterly in English is published by the Chinese People’s Association for Peace and Disarmament(CPAPD)since its founding in June 1985.Over the past 30 years,we have received kind support from all your readers in China and overseas.We wish to take this opportunity to express our appreciation to you all from the bottom of our hearts.

  10. Genetic Improvement of Switchgrass and Other Herbaceous Plants for Use as Biomass Fuel Feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Vogel, K.P.

    2001-01-11

    It should be highly feasible to genetically modify the feedstock quality of switchgrass and other herbaceous plants using both conventional and molecular breeding techniques. Effectiveness of breeding to modify herbages of switchgrass and other perennial and annual herbaceous species has already been demonstrated. The use of molecular markers and transformation technology will greatly enhance the capability of breeders to modify the plant structure and cell walls of herbaceous plants. It will be necessary to monitor gene flow to remnant wild populations of plants and have strategies available to curtail gene flow if it becomes a potential problem. It also will be necessary to monitor plant survival and long-term productivity as affected by genetic changes that improve forage quality. Information on the conversion processes that will be used and the biomass characteristics that affect conversion efficiency and rate is absolutely essential as well as information on the relative economic value of specific traits. Because most forage or biomass quality characteristics are highly affected by plant maturity, it is suggested that plant material of specific maturity stages be used in research to determining desirable feedstock quality characteristics. Plant material could be collected at various stages of development from an array of environments and storage conditions that could be used in conversion research. The same plant material could be used to develop NIRS calibrations that could be used by breeders in their selection programs and also to develop criteria for a feedstock quality assessment program. Breeding for improved feedstock quality will likely affect the rate of improvement of biomass production per acre. If the same level of resources are used, multi-trait breeding simply reduces the selection pressure and hence the breeding progress that can be made for a single trait unless all the traits are highly correlated. Since desirable feedstock traits are likely

  11. MODEL BASED BIOMASS SYSTEM DESIGN OF FEEDSTOCK SUPPLY SYSTEMS FOR BIOENERGY PRODUCTION

    Energy Technology Data Exchange (ETDEWEB)

    David J. Muth, Jr.; Jacob J. Jacobson; Kenneth M. Bryden

    2013-08-01

    Engineering feedstock supply systems that deliver affordable, high-quality biomass remains a challenge for the emerging bioenergy industry. Cellulosic biomass is geographically distributed and has diverse physical and chemical properties. Because of this feedstock supply systems that deliver cellulosic biomass resources to biorefineries require integration of a broad set of engineered unit operations. These unit operations include harvest and collection, storage, preprocessing, and transportation processes. Design decisions for each feedstock supply system unit operation impact the engineering design and performance of the other system elements. These interdependencies are further complicated by spatial and temporal variances such as climate conditions and biomass characteristics. This paper develops an integrated model that couples a SQL-based data management engine and systems dynamics models to design and evaluate biomass feedstock supply systems. The integrated model, called the Biomass Logistics Model (BLM), includes a suite of databases that provide 1) engineering performance data for hundreds of equipment systems, 2) spatially explicit labor cost datasets, and 3) local tax and regulation data. The BLM analytic engine is built in the systems dynamics software package PowersimTM. The BLM is designed to work with thermochemical and biochemical based biofuel conversion platforms and accommodates a range of cellulosic biomass types (i.e., herbaceous residues, short- rotation woody and herbaceous energy crops, woody residues, algae, etc.). The BLM simulates the flow of biomass through the entire supply chain, tracking changes in feedstock characteristics (i.e., moisture content, dry matter, ash content, and dry bulk density) as influenced by the various operations in the supply chain. By accounting for all of the equipment that comes into contact with biomass from the point of harvest to the throat of the conversion facility and the change in characteristics, the

  12. Development of High Yield Feedstocks and Biomass Conversion Technology for Renewable Energy

    Energy Technology Data Exchange (ETDEWEB)

    Hashimoto, Andrew G. [Univ. of Hawaii, Honolulu, HI (United States); Crow, Susan [Univ. of Hawaii, Honolulu, HI (United States); DeBeryshe, Barbara [Univ. of Hawaii, Honolulu, HI (United States); Ha, Richard [Hamakua Springs County Farms, Hilo, HI (United States); Jakeway, Lee [Hawaiian Commercial and Sugar Company, Puunene, HI (United States); Khanal, Samir [Univ. of Hawaii, Honolulu, HI (United States); Nakahata, Mae [Hawaiian Commercial and Sugar Company, Puunene, HI (United States); Ogoshi, Richard [Univ. of Hawaii, Honolulu, HI (United States); Shimizu, Erik [Univ. of Hawaii, Honolulu, HI (United States); Stern, Ivette [Univ. of Hawaii, Honolulu, HI (United States); Turano, Brian [Univ. of Hawaii, Honolulu, HI (United States); Turn, Scott [Univ. of Hawaii, Honolulu, HI (United States); Yanagida, John [Univ. of Hawaii, Honolulu, HI (United States)

    2015-04-09

    This project had two main goals. The first goal was to evaluate several high yielding tropical perennial grasses as feedstock for biofuel production, and to characterize the feedstock for compatible biofuel production systems. The second goal was to assess the integration of renewable energy systems for Hawaii. The project focused on high-yield grasses (napiergrass, energycane, sweet sorghum, and sugarcane). Field plots were established to evaluate the effects of elevation (30, 300 and 900 meters above sea level) and irrigation (50%, 75% and 100% of sugarcane plantation practice) on energy crop yields and input. The test plots were extensive monitored including: hydrologic studies to measure crop water use and losses through seepage and evapotranspiration; changes in soil carbon stock; greenhouse gas flux (CO2, CH4, and N2O) from the soil surface; and root morphology, biomass, and turnover. Results showed significant effects of environment on crop yields. In general, crop yields decrease as the elevation increased, being more pronounced for sweet sorghum and energycane than napiergrass. Also energy crop yields were higher with increased irrigation levels, being most pronounced with energycane and less so with sweet sorghum. Daylight length greatly affected sweet sorghum growth and yields. One of the energy crops (napiergrass) was harvested at different ages (2, 4, 6, and 8 months) to assess the changes in feedstock characteristics with age and potential to generate co-products. Although there was greater potential for co-products from younger feedstock, the increased production was not sufficient to offset the additional cost of harvesting multiple times per year. The feedstocks were also characterized to assess their compatibility with biochemical and thermochemical conversion processes. The project objectives are being continued through additional support from the Office of Naval Research, and the Biomass Research and Development

  13. 2nd Quarter Transportation Report FY 2014

    Energy Technology Data Exchange (ETDEWEB)

    Gregory, L.

    2014-07-30

    This report satisfies the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Field Office (NNSA/NFO) commitment to prepare a quarterly summary report of radioactive waste shipments to the Nevada National Security Site (NNSS) Radioactive Waste Management Complex (RWMC) at Area 5. There were no shipments sent for offsite treatment and returned to the NNSS this quarter. This report summarizes the second quarter of fiscal year (FY) 2014 low-level radioactive waste (LLW) and mixed low-level radioactive waste (MLLW) shipments. This report also includes annual summaries for FY 2014 in Tables 4 and 5. Tabular summaries are provided which include the following: Sources of and carriers for LLW and MLLW shipments to and from the NNSS; Number and external volume of LLW and MLLW shipments; Highway routes used by carriers; and Incident/accident data applicable to LLW and MLLW shipments. In this report shipments are accounted for upon arrival at the NNSS, while disposal volumes are accounted for upon waste burial. The disposal volumes presented in this report do not include minor volumes of non-radioactive materials that were approved for disposal. Volume reports showing cubic feet (ft3) generated using the Low-Level Waste Information System may vary slightly due to differing rounding conventions.

  14. Mixed Waste Management Facility groundwater monitoring report. Second quarter 1994

    Energy Technology Data Exchange (ETDEWEB)

    Chase, J.A.

    1994-09-01

    Currently, 125 wells monitor groundwater quality in the uppermost aquifer beneath the Mixed Waste Management Facility (MWMF) at the Savannah River Site. Samples from the wells are analyzed for selected heavy metals, indicator parameters, radionuclides, volatile organic compounds, and other constituents. During second quarter 1994, chloroethene (vinyl chloride), 1,1-dichloroethylene, gross alpha, lead, tetrachloroethylene, trichloroethylene, or tritium exceeded final Primary Drinking Water Standards (PDWS) in approximately half of the downgradient wells at the MWMF. Consistent with historical trends, elevated constituent levels were found primarily in Aquifer Zone. As in previous quarters, tritium and trichloroethylene were the most widespread elevated constituents during second quarter 1994. Sixty-two of the 125 monitoring wells contained elevated tritium activities. Trichloroethylene concentrations exceeded the final PDWS in 23 wells. Chloroethene, 1,1-dichloroethylene, lead, and tetrachloroethylene, elevated in one or more wells during second quarter 1994, also occurred in elevated levels during first quarter 1994. These constituents generally were elevated in the same wells during both quarters. Gross alpha, which was not elevated in any well during first quarter 1994, was elevated in one well during second quarter. Copper, mercury, and nonvolatile beta were elevated during first quarter 1994 but not during second quarter.

  15. Idaho National Laboratory Quarterly Performance Analysis - 1st Quarter FY2015

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Lisbeth A. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-03-01

    This report is published quarterly by the Idaho National Laboratory (INL) Quality and Performance Management Organization. The Department of Energy (DOE) Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of 73 reportable events (27 from the 1St Qtr FY-15 and 46 from the prior three reporting quarters), as well as 38 other issue reports (including nine not reportable events and Significant Category A and B conditions reported during the1st Qtr FY-15) identified at INL during the past 12 months.

  16. Sunflower-based Feedstocks in Nonfood Applications: Perspectives from Olefin Metathesis

    Directory of Open Access Journals (Sweden)

    Bassie B. Marvey

    2008-08-01

    Full Text Available Sunflower (Helianthus annuus L. oil remains under-utilised albeit one of the major seed oils produced world-wide. Moreover, the high oleic sunflower varieties make the oil attractive for applications requiring high temperature processes and those targeting the C=C double bond functionality. Herein an overview of the recent developments in olefin metathesis of sunflower-based feedstocks is presented. The improved performance of olefin metathesis catalysts leading to high turnover numbers, high selectivity and catalyst recyclability, opens new opportunities for tailoring sunflower-based feedstocks into products required for possible new niche market applications. Promising results in biofuel, biopolymers, fragrances and fine chemicals applications have been reported.

  17. A Saponification Method for Chlorophyll Removal from Microalgae Biomass as Oil Feedstock

    Science.gov (United States)

    Li, Tao; Xu, Jin; Wu, Hualian; Wang, Guanghua; Dai, Shikun; Fan, Jiewei; He, Hui; Xiang, Wenzhou

    2016-01-01

    Microalgae oil is an optimal feedstock for nutraceutical, pharmaceutical and biodiesel production, but its high levels of chlorophyll limit its large-scale application. To date, few effective approaches have been developed to remove chlorophyll from microalgae oil. The main purpose of this study was to present a preprocessing method of algae oil feedstock (Scenedesmus) to remove chlorophyll by saponification. The results showed that 96% of chlorophyll in biomass was removed. High quality orange transparent oil could be extracted from the chlorophyll reduced biomass. Specifically, the proportion of neutral lipids and saturation levels of fatty acids increased, and the pigments composition became carotenoids-based. The critical parameters of chlorophyll reduced biodiesel conformed to the standards of the USA, China and EU. Sodium copper chlorophyllin could be prepared from the bleaching effluent. The results presented herein offer a useful pathway to improve the quality of microalgae oil and reduce the cost of microalgae biodiesel. PMID:27618070

  18. A Saponification Method for Chlorophyll Removal from Microalgae Biomass as Oil Feedstock

    Directory of Open Access Journals (Sweden)

    Tao Li

    2016-09-01

    Full Text Available Microalgae oil is an optimal feedstock for nutraceutical, pharmaceutical and biodiesel production, but its high levels of chlorophyll limit its large-scale application. To date, few effective approaches have been developed to remove chlorophyll from microalgae oil. The main purpose of this study was to present a preprocessing method of algae oil feedstock (Scenedesmus to remove chlorophyll by saponification. The results showed that 96% of chlorophyll in biomass was removed. High quality orange transparent oil could be extracted from the chlorophyll reduced biomass. Specifically, the proportion of neutral lipids and saturation levels of fatty acids increased, and the pigments composition became carotenoids-based. The critical parameters of chlorophyll reduced biodiesel conformed to the standards of the USA, China and EU. Sodium copper chlorophyllin could be prepared from the bleaching effluent. The results presented herein offer a useful pathway to improve the quality of microalgae oil and reduce the cost of microalgae biodiesel.

  19. Feedstock to Tailpipe Initiative: Kansas Biofuels Production, Testing and Certification Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Stagg-Williams, Susan M. [Univ. of Kansas, Lawrence, KS (United States). Dept. of Chemical and Petroleum Engineering; Depcik, Chris [Univ. of Kansas, Lawrence, KS (United States). Dept. of Chemical and Petroleum Engineering; Sturm, Belinda [Univ. of Kansas, Lawrence, KS (United States). Dept. of Chemical and Petroleum Engineering

    2013-12-31

    The primary task of this grant was to establish an ASTM testing facility for biodiesel and ethanol and to use this facility to develop methods to predict fuel characteristics based on feedstock composition and feedstock cultivation. In addition to characterizing fuel properties, this grant allowed for the purchase and installation of a Fourier Transform Infrared Spectroscopy (FTIR) emissions analyzer that will provide an analysis of the emissions leaving the engine in order to meet EPA regulations. This FTIR system is combined with an Alternating Current (AC) dynamometer that allows the engine to follow Environmental Protection Agency (EPA) Federal Test Procedure (FTP) cycles. A secondary task was to investigate cultivating algae utilizing wastewater and top-down ecological control and subsequent harvesting using coagulation and dissolved air flotation. Lipid extraction utilizing environmentally-friendly and cost-effective solvents, with and without cell-disruption pretreatment was also explored. Significant work on the hydrothermal liquefaction of wastewater cultivated algae was conducted.

  20. A Saponification Method for Chlorophyll Removal from Microalgae Biomass as Oil Feedstock.

    Science.gov (United States)

    Li, Tao; Xu, Jin; Wu, Hualian; Wang, Guanghua; Dai, Shikun; Fan, Jiewei; He, Hui; Xiang, Wenzhou

    2016-09-07

    Microalgae oil is an optimal feedstock for nutraceutical, pharmaceutical and biodiesel production, but its high levels of chlorophyll limit its large-scale application. To date, few effective approaches have been developed to remove chlorophyll from microalgae oil. The main purpose of this study was to present a preprocessing method of algae oil feedstock (Scenedesmus) to remove chlorophyll by saponification. The results showed that 96% of chlorophyll in biomass was removed. High quality orange transparent oil could be extracted from the chlorophyll reduced biomass. Specifically, the proportion of neutral lipids and saturation levels of fatty acids increased, and the pigments composition became carotenoids-based. The critical parameters of chlorophyll reduced biodiesel conformed to the standards of the USA, China and EU. Sodium copper chlorophyllin could be prepared from the bleaching effluent. The results presented herein offer a useful pathway to improve the quality of microalgae oil and reduce the cost of microalgae biodiesel.

  1. Calophyllum inophyllum L. as a future feedstock for bio-diesel production

    Energy Technology Data Exchange (ETDEWEB)

    Atabania, A.E. [Department of Mechanical Engineering, University of Khartoum (Sudan)], email: a_atabani2@msn.com, email: ardinsu@yahoo.co.id; Silitonga, A.S.; Mahlia, T.M.I.; Masjukia, H.H.; Badruddin, I.A. [University of Malaya (Malaysia)

    2011-07-01

    Due to the energy crisis and the concerns about climate change, the possibility of using biodiesel as an alternative energy resource has been examined. It has been found that biodiesel could be a solution for the future but the first generation of biodiesel, prepared from edible vegetable oils, has raised important concerns about food and environmental problems. The aim of this study is to assess if Calophyllum inophyllum, a non-edible oil, could be used for biodiesel production. Density, kinematic viscosity, cetane number, flashpoint and iodine value were determined on Calophyllum inophyllum trees from Cilacap, Indonesia and compared in light of ASTM D6751 biodiesel standards. It was found that Calophyllum inophyllum would be a satisfactory feedstock to produce biodiesel in the future. This study demonstrated that Calophyllum inophyllum has the potential to be a biodiesel feedstock and further research should be carried out on engine performance, combustion and emission performance of biodiesel produced from Calophyllum inophyllum.

  2. Syngas. The flexible solution in a volatile feed-stock market

    Energy Technology Data Exchange (ETDEWEB)

    Wurzel, T. [Air Liquide Global E und C Solutions c/o Lurgi GmbH, Frankfurt a.M. (Germany)

    2013-11-01

    The paper presents the versatility of syngas allowing the extended application of new feedstock sources such as shale gas or coal to deliver fuels and chemicals traditionally derived from crude oil. In order to provide a holistic view on this topic of current interest, the syngas market, the pre-dominant production technologies and main economic consideration for selected applications are presented and analyzed. It can be concluded that a broad portfolio of well-mastered and referenced syngas production technologies which are continuously improved to meet actual market requirements (e.g. ability to valorize biomass) will remain key to enable economic solutions in a world characterized by growing dynamics with regards to the supply of (carbonaceous) feedstock. (orig.)

  3. Computer Vision and Machine Learning for Autonomous Characterization of AM Powder Feedstocks

    Science.gov (United States)

    DeCost, Brian L.; Jain, Harshvardhan; Rollett, Anthony D.; Holm, Elizabeth A.

    2017-03-01

    By applying computer vision and machine learning methods, we develop a system to characterize powder feedstock materials for metal additive manufacturing (AM). Feature detection and description algorithms are applied to create a microstructural scale image representation that can be used to cluster, compare, and analyze powder micrographs. When applied to eight commercial feedstock powders, the system classifies powder images into the correct material systems with greater than 95% accuracy. The system also identifies both representative and atypical powder images. These results suggest the possibility of measuring variations in powders as a function of processing history, relating microstructural features of powders to properties relevant to their performance in AM processes, and defining objective material standards based on visual images. A significant advantage of the computer vision approach is that it is autonomous, objective, and repeatable.

  4. Interactions of Woody Biofuel Feedstock Production Systems with Water Resources: Considerations for Sustainability

    Energy Technology Data Exchange (ETDEWEB)

    Trettin, Carl C. [US Forest Service Center for Forested Wetlands Research, Cordesville, SC (United States); Amatya, Devendra [US Forest Service Center for Forested Wetlands Research, Cordesville, SC (United States); Coleman, Mark [US Forest Service Center for Forested Wetlands Research, Cordesville, SC (United States)

    2008-04-15

    Water resources are important for the production of woody biofuel feedstocks. It is necessary to ensure that production systems do not adversely affect the quantity or quality of surface and ground water. The effects of woody biomass plantations on water resources are largely dependent on the prior land use and the management regime. Experience from both irrigated and non-irrigated systems has demonstrated that woody biofuel production systems do not impair water quality. Water quality actually improves from conversion of idle or degraded agricultural lands to woody biomass plantations. Site water balance may be altered by cultivation of woody biomass plantations relative to agricultural use, due to increases in evapostranspiration (ET) and storage. Incorporation of woody biomass production plantations within the landscape provides an opportunity to improve the quality of runoff water and soil conservation. Finally, given the centrality of water resources to the sustainability of ecosystem services and other values derived, the experience with woody biofuels feedstock production systems is positive.

  5. Influence of chemical group composition of feedstock on results from catalytic cracking

    Energy Technology Data Exchange (ETDEWEB)

    Zhorov, Y.M.; Panchenkov, G.M.; Pivovarova, N.A.

    1983-01-01

    The work reported here is aimed at determining whether it is the distillation range of the chemical composition of the feed that influences the results obtained in catalytic cracking. For a quantitative evaluation of the influence of feedstock chemical composition on the cracking results, a linear equation relating the naptha yield to the contents of the group components is derived. The equation indicates that the ''light'' aromatics form considerable amounts of naptha, whereas the ''heavy'' aromatics retard the cracking. These relationships can be used in developing a mathematical model of the process and in selecting the severity of preliminary treating of catalytic cracking feedstocks.

  6. Modelling of pretreatment and saccharification with different feedstocks and kinetic modeling of sorghum saccharification.

    Science.gov (United States)

    Prathyusha, N; Kamesh, Reddi; Rani, K Yamuna; Sumana, C; Sridhar, S; Prakasham, R S; Yashwanth, V V N; Sheelu, G; Kumar, M Pradeep

    2016-12-01

    Experiments have been performed for pretreatment of sorghum, wheat straw and bamboo through high temperature alkali pretreatment with different alkaline loading and temperatures, and the data on extent of delignification in terms of the final compositions of cellulose, hemicellulose and lignin have been generated. Further, enzymatic saccharification has been carried out in all the cases to find the extent of conversion possible after 72h. The effect of different operating parameters on the extent of delignification and cellulose conversion are evaluated. This data is employed to develop a generalized multi-feedstock and individual feedstock based models which can be used to determine the extent of delignification and cellulose conversion for any and specific biomass respectively with alkaline pretreatment and similar enzyme conditions as considered in the present study. Also, a kinetic model is developed and validated for sorghum for cellulosic conversion.

  7. Effect of thermo-mechanical properties of PIM feedstock on compacts shape retention during debinding process

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The removal of the binder from the powder compacts (debinding) can be a slow step and a source of problems. To improve the debinding process of powder injection molding operation, it's necessary to understand the thermal and mechanical properties of powder injection molding feedstocks and to find the major causes responsible for molding difficulties and compacts shape retention during debinding process. The effects of thermo-mechanical properties of the PIM feedstock on the compacts shape retention during debinding process were discussed and explained from practical point of view. The results indicate that the heat of fusion affects the cooling time. The binder component with high heat of fusion and high-decomposed temperature is more effective as the second binder component for the compact to retain its shape during debinding.

  8. Multi-scale process and supply chain modelling: from lignocellulosic feedstock to process and products.

    Science.gov (United States)

    Hosseini, Seyed Ali; Shah, Nilay

    2011-04-06

    There is a large body of literature regarding the choice and optimization of different processes for converting feedstock to bioethanol and bio-commodities; moreover, there has been some reasonable technological development in bioconversion methods over the past decade. However, the eventual cost and other important metrics relating to sustainability of biofuel production will be determined not only by the performance of the conversion process, but also by the performance of the entire supply chain from feedstock production to consumption. Moreover, in order to ensure world-class biorefinery performance, both the network and the individual components must be designed appropriately, and allocation of resources over the resulting infrastructure must effectively be performed. The goal of this work is to describe the key challenges in bioenergy supply chain modelling and then to develop a framework and methodology to show how multi-scale modelling can pave the way to answer holistic supply chain questions, such as the prospects for second generation bioenergy crops.

  9. Computer Vision and Machine Learning for Autonomous Characterization of AM Powder Feedstocks

    Science.gov (United States)

    DeCost, Brian L.; Jain, Harshvardhan; Rollett, Anthony D.; Holm, Elizabeth A.

    2016-12-01

    By applying computer vision and machine learning methods, we develop a system to characterize powder feedstock materials for metal additive manufacturing (AM). Feature detection and description algorithms are applied to create a microstructural scale image representation that can be used to cluster, compare, and analyze powder micrographs. When applied to eight commercial feedstock powders, the system classifies powder images into the correct material systems with greater than 95% accuracy. The system also identifies both representative and atypical powder images. These results suggest the possibility of measuring variations in powders as a function of processing history, relating microstructural features of powders to properties relevant to their performance in AM processes, and defining objective material standards based on visual images. A significant advantage of the computer vision approach is that it is autonomous, objective, and repeatable.

  10. Modifying lignin to improve bioenergy feedstocks: strengthening the barrier against pathogens?

    Directory of Open Access Journals (Sweden)

    Scott eSattler

    2013-04-01

    Full Text Available Lignin is a ubiquitous polymer present in cell walls of all vascular plants, where it rigidifies and strengthens the cell wall structure through covalent cross-linkages to cell wall polysaccharides. The presence of lignin makes the cell wall recalcitrant to conversion into fermentable sugars for bioenergy uses. Therefore, reducing lignin content and modifying its linkages have become major targets for bioenergy feedstock development through either biotechnology or traditional plant breeding. In addition, lignin synthesis has long been implicated as an important plant defense mechanism against pathogens, because lignin synthesis is often induced at the site of pathogen attack. This article explores the impact of lignin modifications on the susceptibility of a range of plant species to their associated pathogens, and the implications for development of feedstocks for the second-generation biofuels industry. Surprisingly, there are some instances where plants modified in lignin synthesis may display increased resistance to associated pathogens, which is explored in this article.

  11. Promotion of microalgal growth by co-culturing with Cellvibrio pealriver using xylan as feedstock.

    Science.gov (United States)

    Xie, Zhangzhang; Lin, Weitie; Luo, Jianfei

    2016-01-01

    In this work, a Cellvibrio pealriver-microalga co-cultivation mode was used to promote the growths of four microalgae by using xylan as feedstock. After 12days of cultivation, the biomass concentrations of Chlorella sacchrarophila, Chlorella pyrenoidosa and Chlamydomonas reinhardtii in co-cultivation were equal to those in mixotrophic growth on glucose, and the Dunaliella was about 1.6-fold higher than that on glucose. The comparative transcriptomes analysis demonstrated that the xylose and xylan hydrolysates were catalyzed to some active substrates by C. pealriver via some functional enzymes; these active substrates are possibly responsible for the promotion of microalgal growth. This C. pealriver-microalga co-cultivation mode is a potential method to produce low-cost microalgal biodiesel by using hemicellulose as feedstock.

  12. Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.; Beltran, Leslie V.; Kunz, Linda A.; Pals, Tessa M.; Quinn, Jordan R; Behrends, Jr., Raymond T.; Bernhardt, Randal J.

    2016-07-05

    Methods are provided for refining natural oil feedstocks and producing isomerized esters and acids. The methods comprise providing a C4-C18 unsaturated fatty ester or acid, and isomerizing the fatty acid ester or acid in the presence of heat or an isomerization catalyst to form an isomerized fatty ester or acid. In some embodiments, the methods comprise forming a dibasic ester or dibasic acid prior to the isomerizing step. In certain embodiments, the methods further comprise hydrolyzing the dibasic ester to form a dibasic acid. In certain embodiments, the olefin is formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having unsaturated esters.

  13. Nutrient contributions and biogas potential of co-digestion of feedstocks and dairy manure.

    Science.gov (United States)

    Ma, Guiling; Neibergs, J Shannon; Harrison, Joseph H; Whitefield, Elizabeth M

    2017-06-01

    This study focused on collection of data on nutrient flow and biogas yield at a commercial anaerobic digester managed with dairy manure from a 1000 cow dairy and co-digestion of additional feedstocks. Feedstocks included: blood, fish, paper pulp, out of date beverages and grease trap waste. Mass flow of inputs and outputs, nutrient concentration of inputs and outputs, and biogas yield were obtained. It was determined that manure was the primary source of nutrients to the anaerobic digester when co-digested with feedstocks. The percentage of contribution from manure to the total nutrient inputs for total nitrogen, ammonia-nitrogen, phosphorus and total solids was 46.3%, 67.7%, 32.8% and 23.4%, respectively. On average, manure contributed the greatest amount of total nitrogen and ammonia-nitrogen. Grease trap waste contributed the greatest amount of phosphorus and total solids at approximately 50%. Results demonstrated that a reliable estimate of nutrient inflow could be obtained from the product of the nutrient analyses of a single daily composite of influent subsamples times the total daily flow estimated with an in-line flow meter. This approach to estimate total daily nutrient inflow would be more cost effective than testing and summing the contribution of individual feedstocks. Data collected after liquid-solid separation confirmed that the majority (>75%) of nutrients remain with the liquid effluent portion of the manure stream. It was demonstrated that the ash concentration in solids before and after composting could be used to estimate the mass balance of total solids during the compost process. This data confirms that biogas or methane yield could be accurately measured from the ratio of % volatile solids to % total solids. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1: Availability of Feedstock and Technology

    Energy Technology Data Exchange (ETDEWEB)

    Valkenburt, Corinne; Walton, Christie W.; Thompson, Becky L.; Gerber, Mark A.; Jones, Susanne B.; Stevens, Don J.

    2008-12-01

    This report investigated the potential of using municipal solid waste (MSW) to make synthesis gas (syngas) suitable for production of liquid fuels. Issues examined include: • MSW physical and chemical properties affecting its suitability as a gasifier feedstock and for liquid fuels synthesis • expected process scale required for favorable economics • the availability of MSW in quantities sufficient to meet process scale requirements • the state-of-the-art of MSW gasification technology.

  15. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    Energy Technology Data Exchange (ETDEWEB)

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2016-07-05

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  16. Biocatalysis for the application of CO2 as a chemical feedstock

    OpenAIRE

    Apostolos Alissandratos; Easton, Christopher J.

    2015-01-01

    Biocatalysts, capable of efficiently transforming CO2 into other more reduced forms of carbon, offer sustainable alternatives to current oxidative technologies that rely on diminishing natural fossil-fuel deposits. Enzymes that catalyse CO2 fixation steps in carbon assimilation pathways are promising catalysts for the sustainable transformation of this safe and renewable feedstock into central metabolites. These may be further converted into a wide range of fuels and commodity chemicals, thro...

  17. Combined hydrothermal liquefaction and catalytic hydrothermal gasification system and process for conversion of biomass feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2017-09-12

    A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.

  18. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    Science.gov (United States)

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2016-07-05

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  19. Impacts of near-future cultivation of biofuel feedstocks on atmospheric composition and local air quality

    Directory of Open Access Journals (Sweden)

    K. Ashworth

    2012-01-01

    Full Text Available Large-scale production of feedstock crops for biofuels will lead to land use changes. We quantify the effects of realistic land use change scenarios for biofuel feedstock production on isoprene emissions and hence atmospheric composition and chemistry using the HadGEM2 model. Two feedstocks are considered: oil palm for biodiesel in the tropics and short rotation coppice (SRC in the mid-latitudes. In total, 69 Mha of oil palm and 9 Mha of SRC are planted, each sufficient to replace just over 1% of projected global fossil fuel demand in 2020. Both planting scenarios result in increases in total global annual isoprene emissions of about 1%. In each case, changes in surface concentrations of ozone and biogenic secondary organic aerosol (bSOA are substantial at the regional scale, with implications for air quality standards. However, the changes in tropospheric burden of ozone and the OH radical, and hence effects on global climate, are negligible. Over SE Asia, one region of oil palm planting, increases in annual mean surface ozone and bSOA concentrations reach over 3 ppbv (+11% and 0.4 μg m−3 (+10% respectively for parts of Borneo, with monthly mean increases of up to 6.5 ppbv (+25% and 0.5 μg m−3 (+12%. Under the SRC scenario, Europe experiences monthly mean changes of over 0.6 ppbv (+1% and 0.1 μg m−3 (+5% in June and July, with peak increases of over 2 ppbv (+3% and 0.5 μg m−3 (+8 %. That appreciable regional atmospheric impacts result from low level planting scenarios demonstrates the need to include changes in emissions of reactive trace gases such as isoprene in life cycle assessments performed on potential biofuel feedstocks.

  20. Impacts of near-future cultivation of biofuel feedstocks on atmospheric composition and local air quality

    Science.gov (United States)

    Ashworth, K.; Folberth, G.; Hewitt, C. N.; Wild, O.

    2012-01-01

    Large-scale production of feedstock crops for biofuels will lead to land use changes. We quantify the effects of realistic land use change scenarios for biofuel feedstock production on isoprene emissions and hence atmospheric composition and chemistry using the HadGEM2 model. Two feedstocks are considered: oil palm for biodiesel in the tropics and short rotation coppice (SRC) in the mid-latitudes. In total, 69 Mha of oil palm and 9 Mha of SRC are planted, each sufficient to replace just over 1% of projected global fossil fuel demand in 2020. Both planting scenarios result in increases in total global annual isoprene emissions of about 1%. In each case, changes in surface concentrations of ozone and biogenic secondary organic aerosol (bSOA) are substantial at the regional scale, with implications for air quality standards. However, the changes in tropospheric burden of ozone and the OH radical, and hence effects on global climate, are negligible. Over SE Asia, one region of oil palm planting, increases in annual mean surface ozone and bSOA concentrations reach over 3 ppbv (+11%) and 0.4 μg m-3 (+10%) respectively for parts of Borneo, with monthly mean increases of up to 6.5 ppbv (+25%) and 0.5 μg m-3 (+12%). Under the SRC scenario, Europe experiences monthly mean changes of over 0.6 ppbv (+1%) and 0.1 μg m-3 (+5%) in June and July, with peak increases of over 2 ppbv (+3%) and 0.5 μg m-3 (+8 %). That appreciable regional atmospheric impacts result from low level planting scenarios demonstrates the need to include changes in emissions of reactive trace gases such as isoprene in life cycle assessments performed on potential biofuel feedstocks.

  1. Development and use of bioenergy feedstocks for semi-arid and arid lands.

    Science.gov (United States)

    Cushman, John C; Davis, Sarah C; Yang, Xiaohan; Borland, Anne M

    2015-07-01

    Global climate change is predicted to increase heat, drought, and soil-drying conditions, and thereby increase crop sensitivity to water vapour pressure deficit, resulting in productivity losses. Increasing competition between agricultural freshwater use and municipal or industrial uses suggest that crops with greater heat and drought durability and greater water-use efficiency will be crucial for sustainable biomass production systems in the future. Agave (Agavaceae) and Opuntia (Cactaceae) represent highly water-use efficient bioenergy crops that could diversify bioenergy feedstock supply yet preserve or expand feedstock production into semi-arid, abandoned, or degraded agricultural lands, and reclaim drylands. Agave and Opuntia are crassulacean acid metabolism species that can achieve high water-use efficiencies and grow in water-limited areas with insufficient precipitation to support traditional C3 or C4 bioenergy crops. Both Agave and Opuntia have the potential to produce above-ground biomass rivalling that of C3 and C4 crops under optimal growing conditions. The low lignin and high amorphous cellulose contents of Agave and Opuntia lignocellulosic biomass will be less recalcitrant to deconstruction than traditional feedstocks, as confirmed by pretreatments that improve saccharification of Agave. Refined environmental productivity indices and geographical information systems modelling have provided estimates of Agave and Opuntia biomass productivity and terrestrial sequestration of atmospheric CO2; however, the accuracy of such modelling efforts can be improved through the expansion of field trials in diverse geographical settings. Lastly, life cycle analysis indicates that Agave would have productivity, life cycle energy, and greenhouse gas balances comparable or superior to those of traditional bioenergy feedstocks, but would be far more water-use efficient.

  2. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    Science.gov (United States)

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2017-05-23

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  3. Fractional condensation of pyrolysis vapors produced from Nordic feedstocks in cyclone pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Johansson, Ann-Christine; Iisa, Kristiina; Sandström, Linda; Ben, Haoxi; Pilath, Heidi; Deutch, Steve; Wiinikka, Henrik; Öhrman, Olov G. W.

    2017-01-01

    Pyrolysis oil is a complex mixture of different chemical compounds with a wide range of molecular weights and boiling points. Due to its complexity, an efficient fractionation of the oil may be a more promising approach of producing liquid fuels and chemicals than treating the whole oil. In this work a sampling system based on fractional condensation was attached to a cyclone pyrolysis pilot plant to enable separation of the produced pyrolysis vapors into five oil fractions. The sampling system was composed of cyclonic condensers and coalescing filters arranged in series. The objective was to characterize the oil fractions produced from three different Nordic feedstocks and suggest possible applications. The oil fractions were thoroughly characterized using several analytical techniques including water content; elemental composition; heating value, and chemical compound group analysis using solvent fractionation, quantitative 13C NMR and 1H NMR and GC x GC - TOFMS. The results show that the oil fractions significantly differ from each other both in chemical and physical properties. The first fractions and the fraction composed of aerosols were highly viscous and contained larger energy-rich compounds of mainly lignin-derived material. The middle fraction contained medium-size compounds with relatively high concentration of water, sugars, alcohols, hydrocarbonyls and acids and finally the last fraction contained smaller molecules such as water, aldehydes, ketones and acids. However, the properties of the respective fractions seem independent on the studied feedstock types, i.e. the respective fractions produced from different feedstock are rather similar. This promotes the possibility to vary the feedstock depending on availability while retaining the oil properties. Possible applications of the five fractions vary from oil for combustion and extraction of the pyrolytic lignin in the early fractions to extraction of sugars from the early and middle fractions, and

  4. New technologies and alternative feedstocks in petrochemistry and refining. Preprints of the conference

    Energy Technology Data Exchange (ETDEWEB)

    Ernst, S.; Jess, A.; Lercher, J.A.; Lichtscheidl, J.; Marchionna, M. (eds.)

    2013-11-01

    This international conference paper provides a forum for chemists and engineers from refinery, petrochemistry and the chemical industry as well as from academia to discuss new technologies and alternative feedstocks in petrochemistry and refining with the special topic ''Shale Gas, Heavy Oils and Coal''. 23 Lectures and 18 Posters are presented. All papers are analyzed for the ENERGY database.

  5. Idaho National Laboratory Quarterly Event Performance Analysis FY 2013 4th Quarter

    Energy Technology Data Exchange (ETDEWEB)

    Lisbeth A. Mitchell

    2013-11-01

    This report is published quarterly by the Idaho National Laboratory (INL) Performance Assurance Organization. The Department of Energy Occurrence Reporting and Processing System (ORPS) as prescribed in DOE Order 232.2 “Occurrence Reporting and Processing of Operations Information” requires a quarterly analysis of events, both reportable and not reportable for the previous twelve months. This report is the analysis of occurrence reports and deficiency reports (including not reportable events) identified at the Idaho National Laboratory (INL) during the period of October 2012 through September 2013.

  6. Idaho National Laboratory Quarterly Performance Analysis - 2nd Quarter FY2014

    Energy Technology Data Exchange (ETDEWEB)

    Lisbeth A. Mitchell

    2014-06-01

    This report is published quarterly by the Idaho National Laboratory (INL) Performance Assurance Organization. The Department of Energy Occurrence Reporting and Processing System (ORPS), as prescribed in DOE Order 232.2, “Occurrence Reporting and Processing of Operations Information,” requires a quarterly analysis of events, both reportable and not reportable, for the previous 12 months. This report is the analysis of occurrence reports and other deficiency reports (including not reportable events) identified at INL from January 2014 through March 2014.

  7. Quarterly coal report July--September 1995, February 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-16

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for July through September 1995 and aggregated quarterly historical data for 1987 through the second quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  8. Sorghum as a renewable feedstock for production of fuels and industrial chemicals

    Directory of Open Access Journals (Sweden)

    Nhuan P. Nghiem

    2016-01-01

    Full Text Available Considerable efforts have been made in the USA and other countries to develop renewable feedstocks for production of fuels and chemicals. Among these, sorghum has attracted strong interest because of its many good characteristics such as rapid growth and high sugar accumulation, high biomass production potential, excellent nitrogen usage efficiency, wide adaptability, drought resistance, and water lodging tolerance and salinity resistance. The ability to withstand severe drought conditions and its high water usage efficiency make sorghum a good renewable feedstock suitable for cultivation in arid regions, such as the southern US and many areas in Africa and Asia. Sorghum varieties include grain sorghum, sweet sorghum, and biomass sorghum. Grain sorghum, having starch content equivalent to corn, has been considered as a feedstock for ethanol production. Its tannin content, however, may cause problems during enzyme hydrolysis. Sweet sorghum juice contains sucrose, glucose and fructose, which are readily fermentable by Saccharomyces cerevisiae and hence is a good substrate for ethanol fermentation. The enzyme invertase, however, needs to be added to convert sucrose to glucose and fructose if the juice is used for production of industrial chemicals in fermentation processes that employ microorganisms incapable of metabolizing sucrose. Biomass sorghum requires pretreatment prior to enzymatic hydrolysis to generate fermentable sugars to be used in the subsequent fermentation process. This report reviews the current knowledge on bioconversion of sorghum to fuels and chemicals and identifies areas that deserve further studies.

  9. The Rheology behind Stress-Induced Solidification in Native Silk Feedstocks.

    Science.gov (United States)

    Laity, Peter R; Holland, Chris

    2016-10-29

    The mechanism by which native silk feedstocks are converted to solid fibres in nature has attracted much interest. To address this question, the present work used rheology to investigate the gelation of Bombyx mori native silk feedstock. Exceeding a critical shear stress appeared to be more important than shear rate, during flow-induced initiation. Compositional changes (salts, pH etc.,) were not required, although their possible role in vivo is not excluded. Moreover, after successful initiation, gel strength continued to increase over a considerable time under effectively quiescent conditions, without requiring further application of the initial stimulus. Gelation by elevated temperature or freezing was also observed. Prior to gelation, literature suggests that silk protein adopts a random coil configuration, which argued against the conventional explanation of gelation, based on hydrophilic and hydrophobic interactions. Instead, a new hypothesis is presented, based on entropically-driven loss of hydration, which appears to explain the apparently diverse methods by which silk feedstocks can be gelled.

  10. The Rheology behind Stress-Induced Solidification in Native Silk Feedstocks

    Directory of Open Access Journals (Sweden)

    Peter R. Laity

    2016-10-01

    Full Text Available The mechanism by which native silk feedstocks are converted to solid fibres in nature has attracted much interest. To address this question, the present work used rheology to investigate the gelation of Bombyx mori native silk feedstock. Exceeding a critical shear stress appeared to be more important than shear rate, during flow-induced initiation. Compositional changes (salts, pH etc., were not required, although their possible role in vivo is not excluded. Moreover, after successful initiation, gel strength continued to increase over a considerable time under effectively quiescent conditions, without requiring further application of the initial stimulus. Gelation by elevated temperature or freezing was also observed. Prior to gelation, literature suggests that silk protein adopts a random coil configuration, which argued against the conventional explanation of gelation, based on hydrophilic and hydrophobic interactions. Instead, a new hypothesis is presented, based on entropically-driven loss of hydration, which appears to explain the apparently diverse methods by which silk feedstocks can be gelled.

  11. Progress in the production of bioethanol on starch-based feedstocks

    Directory of Open Access Journals (Sweden)

    Dragiša Savić

    2009-10-01

    Full Text Available Bioethanol produced from renewable biomass, such as sugar, starch, or lignocellulosic materials, is one of the alternative energy resources, which is both renewable and environmentally friendly. Although, the priority in global future ethanol production is put on lignocellulosic processing, which is considered as one of the most promising second-generation biofuel technologies, the utilizetion of lignocellulosic material for fuel ethanol is still under improvement. Sugar- based (molasses, sugar cane, sugar beet and starch-based (corn, wheat, triticale, potato, rice, etc. feedstock are still currently predominant at the industrial level and they are, so far, economically favorable compared to lingocelluloses. Currently, approx. 80 % of total world ethanol production is obtained from the fermentation of simple sugars by yeast. In Serbia, one of the most suitable and available agricultural raw material for the industrial ethanol production are cereals such as corn, wheat and triticale. In addition, surpluses of this feedstock are being produced in our country constantly. In this paper, a brief review of the state of the art in bioethanol production and biomass availability is given, pointing out the progress possibilities on starch-based production. The progress possibilities are discussed in the domain of feedstock choice and pretreatment, optimization of fermentation, process integration and utilization of the process byproducts.

  12. Screening microalgae isolated from urban storm- and wastewater systems as feedstock for biofuel

    Directory of Open Access Journals (Sweden)

    Rebecca Massimi

    2016-09-01

    Full Text Available Exploiting microalgae as feedstock for biofuel production is a growing field of research and application, but there remain challenges related to industrial viability and economic sustainability. A solution to the water requirements of industrial-scale production is the use of wastewater as a growth medium. Considering the variable quality and contaminant loads of wastewater, algal feedstock would need to have broad tolerance and resilience to fluctuating wastewater conditions during growth. As a first step in targeting strains for growth in wastewater, our study isolated microalgae from wastewater habitats, including urban stormwater-ponds and a municipal wastewater-treatment system, to assess growth, fatty acids and metal tolerance under standardized conditions. Stormwater ponds in particular have widely fluctuating conditions and metal loads, so microalgae from this type of environment may have desirable traits for growth in wastewater. Forty-three algal strains were isolated in total, including several strains from natural habitats. All strains, with the exception of one cyanobacterial strain, are members of the Chlorophyta, including several taxa commonly targeted for biofuel production. Isolates were identified using taxonomic and 18S rRNA sequence methods, and the fastest growing strains with ideal fatty acid profiles for biodiesel production included Scenedesmus and Desmodesmus species (Growth rate (d−1 > 1. All isolates in a small, but diverse taxonomic group of test-strains were tolerant of copper at wastewater-relevant concentrations. Overall, more than half of the isolated strains, particularly those from stormwater ponds, show promise as candidates for biofuel feedstock.

  13. Design of a GIS-Based Web Application for Simulating Biofuel Feedstock Yields

    Directory of Open Access Journals (Sweden)

    Olga Prilepova

    2014-07-01

    Full Text Available Short rotation woody crops (SRWC, such as hybrid poplar, have the potential to serve as a valuable feedstock for cellulosic biofuels. Spatial estimates of biomass yields under different management regimes are required for assisting stakeholders in making better management decisions and to establish viable woody cropping systems for biofuel production. To support stakeholders in their management decisions, we have developed a GIS-based web interface using a modified 3PG model for spatially predicting poplar biomass yields under different management and climate conditions in the U.S. Pacific Northwest region. The application is implemented with standard HTML5 components, allowing its use in a modern browser and dynamically adjusting to the client screen size and device. In addition, cloud storage of the results makes them accessible on any Internet-enabled device. The web interface appears simple, but is powerful in parameter manipulation and in visualizing and sharing the results. Overall, this application comprises dynamic features that enable users to run SRWC crop growth simulations based on GIS information and contributes significantly to choosing appropriate feedstock growing locations, anticipating the desired physiological properties of the feedstock and incorporating the management and policy analysis needed for growing hybrid poplar plantations.

  14. Screening microalgae isolated from urban storm- and wastewater systems as feedstock for biofuel.

    Science.gov (United States)

    Massimi, Rebecca; Kirkwood, Andrea E

    2016-01-01

    Exploiting microalgae as feedstock for biofuel production is a growing field of research and application, but there remain challenges related to industrial viability and economic sustainability. A solution to the water requirements of industrial-scale production is the use of wastewater as a growth medium. Considering the variable quality and contaminant loads of wastewater, algal feedstock would need to have broad tolerance and resilience to fluctuating wastewater conditions during growth. As a first step in targeting strains for growth in wastewater, our study isolated microalgae from wastewater habitats, including urban stormwater-ponds and a municipal wastewater-treatment system, to assess growth, fatty acids and metal tolerance under standardized conditions. Stormwater ponds in particular have widely fluctuating conditions and metal loads, so microalgae from this type of environment may have desirable traits for growth in wastewater. Forty-three algal strains were isolated in total, including several strains from natural habitats. All strains, with the exception of one cyanobacterial strain, are members of the Chlorophyta, including several taxa commonly targeted for biofuel production. Isolates were identified using taxonomic and 18S rRNA sequence methods, and the fastest growing strains with ideal fatty acid profiles for biodiesel production included Scenedesmus and Desmodesmus species (Growth rate (d(-1)) > 1). All isolates in a small, but diverse taxonomic group of test-strains were tolerant of copper at wastewater-relevant concentrations. Overall, more than half of the isolated strains, particularly those from stormwater ponds, show promise as candidates for biofuel feedstock.

  15. Demonstration of laccase-based removal of lignin from wood and non-wood plant feedstocks.

    Science.gov (United States)

    Gutiérrez, Ana; Rencoret, Jorge; Cadena, Edith M; Rico, Alejandro; Barth, Dorothee; del Río, José C; Martínez, Angel T

    2012-09-01

    The ability of Trametes villosa laccase, in conjuction with 1-hydroxybenzotriazole (HBT) as mediator and alkaline extraction, to remove lignin was demonstrated during treatment of wood (Eucalyptus globulus) and non-wood (Pennisetum purpureum) feedstocks. At 50 Ug(-1) laccase and 2.5% HBT concentration, 48% and 32% of the Eucalyptus and Pennisetum lignin were removed, respectively. Two-dimensional nuclear magnetic resonance of the feedstocks, swollen in dimethylsulfoxide-d(6), revealed the removal of p-hydroxyphenyl, guaiacyl and syringyl lignin units and aliphatic (mainly β-O-4'-linked) side-chains of lignin, and a moderate removal of p-coumaric acid (present in Pennisetum) without a substantial change in polysaccharide cross-signals. The enzymatic pretreatment (at 25 Ug(-1)) of Eucalyptus and Pennisetum feedstocks increased the glucose (by 61% and 12% in 72 h) and ethanol (by 4 and 2 g L(-1) in 17 h) yields from both lignocellulosic materials, respectively, as compared to those without enzyme treatment. Copyright © 2012 Elsevier Ltd. All rights reserved.

  16. Optimal Distribution of Biofuel Feedstocks within Marginal Land in the USA

    Science.gov (United States)

    Jaiswal, D.

    2015-12-01

    The United States can have 43 to 123 Mha of marginal land to grow second generation biofuel feedstocks. A physiological and biophysical model (BioCro) was run using 30 yr climate data (NARR) and SSURGO soil data for the conterminous United Stated to simulate growth of miscanthus, switchgrass, sugarcane, and short rotation coppice. Overlay analyses of the regional maps of predicted yields and marginal land suggest maximum availability of 0.33, 1.15, 1.13, and 1.89 PG year-1 of biomass from sugarcane, willow, switchgrass, and miscanthus, respectively. Optimal distribution of these four biofuel feedstocks within the marginal land in the USA can provide up to 2 PG year-1 of biomass for the production of second generation of biofuel without competing for crop land used for food production. This approach can potentially meet a significant fraction of liquid fuel demand in the USA and reduce greenhouse gas emission while ensuring that current crop land under food production is not used for growing biofuel feedstocks.

  17. Extraction and characterization of triglycerides from coffeeweed and switchgrass seeds as potential feedstocks for biodiesel production.

    Science.gov (United States)

    Armah-Agyeman, Grace; Gyamerah, Michael; Biney, Paul O; Woldesenbet, Selamawit

    2016-10-01

    Although switchgrass has been developed as a biofuel feedstock and its potential for bioethanol and bio-oil from fast pyrolysis reported in the literature, the use of the seeds of switchgrass as a source of triglycerides for biodiesel production has not been reported. Similarly, the potential for extracting triglycerides from coffeeweed (an invasive plant of no current economic value) needs to be investigated to ascertain its potential economic use for biodiesel production. The results show that coffeeweed and switchgrass seeds contain known triglycerides which are 983 and 1000 g kg(-1) respectively of the fatty acids found in edible vegetable oils such as sunflower, corn and soybean oils. In addition, the triglyceride yields of 53-67 g kg(-1) of the seed samples are in the range of commercial oil-producing seeds such as corn (42 g kg(-1) ). The results also indicate that the two non-edible oils could be used as substitutes for edible oil for biodiesel production. In addition, the use of seeds of switchgrass for non-edible oil production (as a feedstock for the production of biodiesel) further increases the total biofuel yield when switchgrass is cultivated for use as energy feedstock for pyrolysis oil and biodiesel production. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

  18. Compositional and Agronomic Evaluation of Sorghum Biomass as a Potential Feedstock for Renewable Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Dahlberg, J.; Wolfrum, E.; Bean, B.; Rooney, W. L.

    2011-12-01

    One goal of the Biomass Research and Development Technical Advisory Committee was to replace 30% of current U.S. petroleum consumption with biofuels by 2030. This will take mixtures of various feedstocks; an annual biomass feedstock such as sorghum will play an important role in meeting this goal. Commercial forage sorghum samples collected from field trials grown in Bushland, TX in 2007 were evaluated for both agronomic and compositional traits. Biomass compositional analysis of the samples was performed at the National Renewable Energy Lab in Golden, CO following NREL Laboratory Analytical Procedures. Depending on the specific cultivar, several additional years of yield data for this location were considered in establishing agronomic potential. Results confirm that sorghum forages can produce high biomass yields over multiple years and varied growing conditions. In addition, the composition of sorghum shows significant variation, as would be expected for most crops. Using theoretical estimates for ethanol production, the sorghum commercial forages examined in this study could produce an average of 6147 L ha{sup -1} of renewable fuels. Given its genetic variability, a known genomic sequence, a robust seed industry, and biomass composition, sorghum will be an important annual feedstock to meet the alternative fuel production goals legislated by the US Energy Security Act of 2007.

  19. Strategic Studies Quarterly, Volume 4, Number 3, Fall 2010

    Science.gov (United States)

    2010-01-01

    1948-12 May 1949)—perhaps the best- known relief operation in American history—the Air Force provided vital S QUARTER! > • FAU 2010 \\_ •’ I food...and personnel to begin performing at least the first two functions immediately. [28] STRATEGIC STUDIES QUARTERLY • FAU 2010 Guidelines for Nation...assistance, as measured as a share of GDP, than more-settled societies. Whereas most STRATEGIC STUDIES QUARTERLY • FAU 2010 [35] James F. Dobbins

  20. Financial return from traditional wood products, feedstock, and carbon sequestration in loblolly pine plantations in the Southern U.S

    Science.gov (United States)

    Umesh K. Chaudhan; Michael B. Kane

    2015-01-01

    We know that planting trees is a key approach for mitigating climate change; however, we are uncertain of what planting density per unit of land and what cultural regimes are needed to optimize traditional timber products, feedstock, and carbon sequestration.

  1. Bioenergy grass feedstock: current options and prospects for trait improvement using emerging genetic, genomic, and systems biology toolkits

    Directory of Open Access Journals (Sweden)

    Feltus Frank

    2012-11-01

    Full Text Available Abstract For lignocellulosic bioenergy to become a viable alternative to traditional energy production methods, rapid increases in conversion efficiency and biomass yield must be achieved. Increased productivity in bioenergy production can be achieved through concomitant gains in processing efficiency as well as genetic improvement of feedstock that have the potential for bioenergy production at an industrial scale. The purpose of this review is to explore the genetic and genomic resource landscape for the improvement of a specific bioenergy feedstock group, the C4 bioenergy grasses. First, bioenergy grass feedstock traits relevant to biochemical conversion are examined. Then we outline genetic resources available bioenergy grasses for mapping bioenergy traits to DNA markers and genes. This is followed by a discussion of genomic tools and how they can be applied to understanding bioenergy grass feedstock trait genetic mechanisms leading to further improvement opportunities.

  2. Bioenergy grass feedstock: current options and prospects for trait improvement using emerging genetic, genomic, and systems biology toolkits.

    Science.gov (United States)

    Feltus, Frank Alex; Vandenbrink, Joshua P

    2012-11-02

    For lignocellulosic bioenergy to become a viable alternative to traditional energy production methods, rapid increases in conversion efficiency and biomass yield must be achieved. Increased productivity in bioenergy production can be achieved through concomitant gains in processing efficiency as well as genetic improvement of feedstock that have the potential for bioenergy production at an industrial scale. The purpose of this review is to explore the genetic and genomic resource landscape for the improvement of a specific bioenergy feedstock group, the C4 bioenergy grasses. First, bioenergy grass feedstock traits relevant to biochemical conversion are examined. Then we outline genetic resources available bioenergy grasses for mapping bioenergy traits to DNA markers and genes. This is followed by a discussion of genomic tools and how they can be applied to understanding bioenergy grass feedstock trait genetic mechanisms leading to further improvement opportunities.

  3. R3DO: A Plastic Recycling System For Creating 3D Printer Feedstock On-Orbit Project

    Data.gov (United States)

    National Aeronautics and Space Administration — An automated in-space recycling system for 3D printer feedstock will provide game-changing resupply benefits including but not limited to launch mass reduction,...

  4. 20 CFR 404.145 - When you acquire a quarter of coverage.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 2 2010-04-01 2010-04-01 false When you acquire a quarter of coverage. 404... DISABILITY INSURANCE (1950- ) Insured Status and Quarters of Coverage Quarters of Coverage § 404.145 When you acquire a quarter of coverage. If we credit you with a quarter of coverage (QC) for a calendar...

  5. 20 CFR 404.140 - What is a quarter of coverage.

    Science.gov (United States)

    2010-04-01

    ... 20 Employees' Benefits 2 2010-04-01 2010-04-01 false What is a quarter of coverage. 404.140... DISABILITY INSURANCE (1950- ) Insured Status and Quarters of Coverage Quarters of Coverage § 404.140 What is a quarter of coverage. (a) General. A quarter of coverage (QC) is the basic unit of social...

  6. Short communication: Immunoglobulin variation in quarter-milked colostrum.

    Science.gov (United States)

    Baumrucker, Craig R; Stark, Andrea; Wellnitz, Olga; Dechow, Chad; Bruckmaier, Rupert M

    2014-01-01

    Whereas whole first-milked colostrum IgG1 variation is documented, the IgG1 difference between the quarter mammary glands of dairy animals is unknown. First colostrum was quarter-collected from healthy udders of 8 multiparous dairy cows, all within 3h of parturition. Weight of colostrum produced by individual quarters was determined and a sample of each was frozen for subsequent analysis. Immunoglobulin G1 concentration (mg/mL) was measured by ELISA and total mass (g) was calculated. Standard addition method was used to overcome colostrum matrix effects and validate the standard ELISA measures. Analysis of the data showed that cow and quarter (cow) were significantly different in both concentration and total mass per quarter. Analysis of the mean IgG1 concentration of the front and rear quarters showed that this was not different, but the large variation in individual quarters confounds the analysis. This quarter difference finding indicates that each mammary gland develops a different capacity to accumulate precolostrum IgG1, whereas the circulating hormone concentrations that induce colostrogenesis reach the 4 glands similarly. This finding also shows that the variation in quarter colostrum production is a contributor to the vast variation in first milking colostrum IgG1 content. Finally, the data suggests other factors, such as locally acting autocrine or paracrine, epigenetic, or stochasticity, in gene regulation mechanisms may impinge on colostrogenesis capacity.

  7. Natural gas imports and exports: First quarter report 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    The Office of Fuels Programs prepares quarterly reports summarizing the data provided by companies authorized to import or export natural gas. Companies are required, as a condition of their authorizations, to file quarterly reports with the OFP. This quarter`s focus is market penetration of gas imports into New England. Attachments show the following: % takes to maximum firm contract levels and weighted average per unit price for the long-term importers, volumes and prices of gas purchased by long-term importers and exporters, volumes and prices for gas imported on short-term or spot market basis, and gas exported short-term to Canada and Mexico.

  8. On the genetic bias of the quarter of birth instrument.

    Science.gov (United States)

    Rietveld, Cornelius A; Webbink, Dinand

    2016-05-01

    Many studies in economics use quarter of birth as an instrument for identifying the causal effect of schooling on outcomes such as earnings and health. The key assumption in these studies is that people born in different quarters of the year do not differ systematically in their unobserved abilities. This study uses genetic data from the US Health and Retirement Study to analyze the validity of the quarter of birth instrument. We find some evidence that genetic factors influencing education are not randomly distributed over the year. However, these factors only slightly change the effect of quarter of birth on schooling.

  9. Mixed Waste Management Facility groundwater monitoring report: Third quarter 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-12-01

    Currently, 125 wells monitor groundwater quality in the uppermost aquifer beneath the Mixed Waste Management Facility (MWMF) at the Savannah River Site. Samples from the wells are analyzed for selected heavy metals, herbicides/pesticides, indicator parameters, radionuclides, volatile organic compounds, and other constituents. As in previous quarters, tritium and trichloroethylene were the most widespread elevated constituents during third quarter 1994. Sixty-four (51%) of the 125 monitoring wells contained elevated tritium activities. Trichloroethylene concentrations exceeded the final PDWS in 22 (18%) wells. Chloroethene, 1,1-dichloroethylene, and tetrachloroethylene, elevated in one or more wells during third quarter 1994, also occurred in elevated levels during second quarter 1994. These constituents generally were elevated in the same wells during both quarters. Gross alpha, which was elevated in only one well during second quarter 1994, was elevated again during third quarter. Mercury, which was elevated during first quarter 1994, was elevated again in one well. Dichloromethane was elevated in two wells for the first time in several quarters.

  10. Test Plan for Evaluating Hammer and Fixed Cutter Grinders Using Multiple Varieties and Moistures of Biomass Feedstock

    Energy Technology Data Exchange (ETDEWEB)

    Not listed

    2007-07-01

    Biomass preprocessing is a critical operation in the preparation of feedstock for the front-end of a cellulosic ethanol biorefinery. Its purpose is to chop, grind, or otherwise format the biomass material into a suitable feedstock for optimum conversion to ethanol and other bioproducts. Without this operation, the natural size, bulk density, and flowability characteristics of harvested biomass would decrease the capacities and efficiencies of feedstock assembly unit operations and biorefinery conversion processes to the degree that programmatic cost targets could not be met. The preprocessing unit operation produces a bulk flowable material that 1) improves handling and conveying efficiencies throughout the feedstock assembly system and biorefinery 2) increases biomass surface areas for improved pretreatment efficiencies, 3) reduces particle sizes for improved feedstock uniformity and density, and 4) fractionates structural components for improved compositional quality. The Idaho National Laboratory (INL) is tasked with defining the overall efficiency/effectiveness of current commercial hammer and fixed cutter grinding systems and other connecting systems such as harvest and collection, storage, transportation, and handling for a wide variety of feedstock types used in bioethanol or syngas production. This test plan details tasks and activities for two separate full-scale grinding tests: Material Characterization Test and Machine Characterization Test. For the Material Characterization Test, a small amount (~5-7 tons each) of several feedstock varieties will be ground. This test will define the fractionation characteristics of the grinder that affect the bulk density, particle size distribution, and quality of the size reduced biomass resulting from different separation screen sizes. A specific screen size will be selected based on the characteristics of the ground material. The Machine Characterization Test will then use this selected screen to grind several 30

  11. Genetic Modification of Short Rotation Poplar Biomass Feedstock for Efficient Conversion to Ethanol

    Energy Technology Data Exchange (ETDEWEB)

    Dinus, R.J.

    2000-08-30

    The Bioenergy Feedstock Development Program, Environmental Sciences Division, Oak Ridge National Laboratory is developing poplars (Populus species and hybrids) as sources of renewable energy, i.e., ethanol. Notable increases in adaptability, volume productivity, and pest/stress resistance have been achieved via classical selection and breeding and intensified cultural practices. Significant advances have also been made in the efficiencies of harvesting and handling systems. Given these and anticipated accomplishments, program leaders are considering shifting some attention to genetically modifying feedstock physical and chemical properties, so as to improve the efficiency with which feedstocks can be converted to ethanol. This report provides an in-depth review and synthesis of opportunities for and feasibilities of genetically modifying feedstock qualities via classical selection and breeding, marker-aided selection and breeding, and genetic transformation. Information was collected by analysis of the literature, with emphasis on that published since 1995, and interviews with prominent scientists, breeders, and growers. Poplar research is well advanced, and literature is abundant. The report therefore primarily reflects advances in poplars, but data from other species, particularly other shortrotation hardwoods, are incorporated to fill gaps. An executive summary and recommendations for research, development, and technology transfer are provided immediately after the table of contents. The first major section of the report describes processes most likely to be used for conversion of poplar biomass to ethanol, the various physical and chemical properties of poplar feedstocks, and how such properties are expected to affect process efficiency. The need is stressed for improved understanding of the impact of change on both overall process and individual process step efficiencies. The second part documents advances in trait measurement instrumentation and methodology

  12. Synthesis and Characterization of Oxide Feedstock Powders for the Fuel Cycle R&D Program

    Energy Technology Data Exchange (ETDEWEB)

    Voit, Stewart L [ORNL; Vedder, Raymond James [ORNL; Johnson, Jared A [ORNL

    2010-09-01

    Nuclear fuel feedstock properties, such as physical, chemical, and isotopic characteristics, have a significant impact on the fuel fabrication process and, by extension, the in-reactor fuel performance. This has been demonstrated through studies with UO{sub 2} spanning greater than 50 years. The Fuel Cycle R&D Program with The Department of Energy Office of Nuclear Energy has initiated an effort to develop a better understanding of the relationships between oxide feedstock, fresh fuel properties, and in-reactor fuel performance for advanced mixed oxide compositions. Powder conditioning studies to enable the use of less than ideal powders for ceramic fuel pellet processing are ongoing at Los Alamos National Laboratory (LANL) and an understanding of methods to increase the green density and homogeneity of pressed pellets has been gained for certain powders. Furthermore, Oak Ridge National Laboratory (ORNL) is developing methods for the co-conversion of mixed oxides along with techniques to analyze the degree of mixing. Experience with the fabrication of fuel pellets using co-synthesized multi-constituent materials is limited. In instances where atomically mixed solid solutions of two or more species are needed, traditional ceramic processing methods have been employed. Solution-based processes may be considered viable synthesis options, including co-precipitation (AUPuC), direct precipitation, direct-conversion (Modified Direct Denitration or MDD) and internal/external gelation (sol-gel). Each of these techniques has various advantages and disadvantages. The Fiscal Year 2010 feedstock development work at ORNL focused on the synthesis and characterization of one batch of UO{sub x} and one batch of U{sub 80}Ce{sub 20}O{sub x}. Oxide material synthesized at ORNL is being shipped to LANL for fuel fabrication process development studies. The feedstock preparation was performed using the MDD process which utilizes a rotary kiln to continuously thermally denitrate double

  13. Leaching Pretreatments for Improving Biomass Quality: Feedstocks, Solvents, and Extraction Modeling

    Science.gov (United States)

    Yu, Chao Wei

    In this research, a systematic study was conducted to quantify the inorganic and organic compounds leached from rice straw, wheat straw, corn stover, switchgrass, Jose Tall Wheatgrass, Douglas fir, and Miscanthus with water, and to evaluate the feedstock quality and characteristics of leached solids for thermal process applications. Leaching feedstocks with water at ambient temperature with a 20 L/kg (dry matter) ratio for 2 hours greatly increased the ash fusion temperature of rice straw (from 1050°C to above 1550°C) and wheat straw (from 900°C to 1250°C), but the treatment only increased the ash fusion temperature of corn stover from 900°C to 950°C. Miscanthus had relatively good initial feedstock quality and leaching may not prove necessary for this feedstock in thermal systems. Leaching also changed the combustion kinetics of biomass by increasing the initial degradation temperature of most feedstocks from originally between 165°C and 186°C to between 180°C and 250°C depending on feedstock. Moreover, leaching increased the maximum rate of weight loss of feedstock by 11% to 54% and increased the corresponding temperatures for peak loss up to 34°C. Leaching removed a sizeable fraction of organic compounds (between 2% and 12% of dry matter). These organic extracts were identified as mostly sugars and acids which might be valuable co-products. Moisture contents of feedstocks after leaching were typically high, ranging between 68 and 81% wet basis. A dewatering step is generally required prior to using the leached biomass for thermochemical conversion. Solvents with ability to dissolve ion-exchangeable, organically associated, and acid soluble metals can further remove non-water soluble metals from biomass and may also improve feedstock quality. In a solvent evaluation, corn stover and wheat straw were leached with water, 1M ammonium acetate, 1M HCl, 100% methanol, 50% methanol, 100% ethanol, and 50% ethanol, and leached solids and leachate were

  14. Operation of Finnish nuclear power plants. Quarterly report, 2nd quarter 1997

    Energy Technology Data Exchange (ETDEWEB)

    Tossavainen, K. [ed.

    1997-12-01

    Quarterly Reports on the operation of Finnish nuclear power plants describe events and observations relating to nuclear and radiation safety which STUK - Radiation and Nuclear Safety Authority considers safety significant. Safety improvements at the plants are also described. The Report also includes a summary of the radiation safety of plant personnel and of the environment and tabulated data on the plants` production and load factors. The Finnish nuclear power plant units were in power operation in the second quarter of 1997, except for the annual maintenance outages of Olkiluoto plant units and the Midsummer outage at Olkiluoto 2 due to reduced demand for electricity. There were also brief interruptions in power operation at the Olkiluoto plant units due to three reactor scrams. All plant units are undergoing long-term test operation at upgraded reactor power level which has been approved by STUK The load factor average of all plant units was 88.7 %. One event in the second quarter of 1997 was classified level 1 on the INES. The event in question was a scram at Olkiluoto 1 which was caused by erroneous opening of switches. Other events in this quarter were level 0. Occupational doses and radioactive releases off-site were below authorized limits. Radioactive substances were measurable in samples collected around the plants in such quantities only as have no bearing on the radiation exposure of the population. (orig.).

  15. Operation of Finnish nuclear power plants. Quarterly report, 3rd quarter 1996

    Energy Technology Data Exchange (ETDEWEB)

    Sillanpaeae, T. [ed.

    1997-02-01

    Quarterly Reports on the operation of Finnish nuclear power plants describe events and observations relating to nuclear and radiation safety which the Finnish Centre for Radiation and Nuclear Safety (STUK) considers safety significant. Safety improvements at the plants are also described. The Report also includes a summary of the radiation safety of plant personnel and of the environment and tabulated data on the plants` production and load factors. In the third quarter of 1996, the Finnish nuclear power plant units were in power operation except for the annual maintenance outages of Loviisa plant units and a shutdown at Olkiluoto 1 to identify and repair malfunctions of a high pressure turbine control valve. The load factor average of all plant units was 77.2%. Events in the third quarter of 1996 were classified level 0 on the International Nuclear Event Scale. Occupational doses and radioactive releases off-site were below authorised limits. Radioactive substances were measurable in samples collected around the plants in such quantities only as have no bearing on the radiation exposure of the population. The names of Teollisuuden Voima Oy`s plant units have changed. Olkiluoto 1 and Olkiluoto 2 now replace the names TVO I and TVO II previously used in quarterly reports. (orig.).

  16. The WSTIAC Quarterly. Volume 9, Number 4

    Science.gov (United States)

    2010-04-28

    elements of command– Major Eric D. Trias Captain Bryan M. Bell US Air Force You have to know the past to understand the present. — Carl Sagan This article is...Quarterly, Volume 9, Number 4 3 INTRODUCTION Carl von Clausewitz defined war as “…an act of violence intended to compel our opponent to fulfill our will...controlled systems. NOTES & REFERENCES ‡ Joint Pub 3-13 provides the doctrinal foundation for the conduct of IO in joint operations. [1] von Clausewitz, Carl

  17. Quarterly coal report, July--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    1994-02-18

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended.

  18. Performance indicators, third quarter CY-1991

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    Secretary of Energy Notice (SEN-29-91) directed that a Department- wide ``uniform system of Performance Indicators (PI`s) for trending and analyzing operational data to help assess and support progress in improving performance and in strengthening line management control of operations relating to environmental safety, and health activities`` be developed. This Performance Indicator Report represents a compilation of data for the third quarter of calendar year 1991 for the following Lawrence Berkeley Laboratory (LBL) facilities: (1) Bevalac, (2) 88-Inch Cyclotron, (3) Materials Sciences Division.

  19. Performance indicators, third quarter CY-1991

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    Secretary of Energy Notice (SEN-29-91) directed that a Department- wide uniform system of Performance Indicators (PI's) for trending and analyzing operational data to help assess and support progress in improving performance and in strengthening line management control of operations relating to environmental safety, and health activities'' be developed. This Performance Indicator Report represents a compilation of data for the third quarter of calendar year 1991 for the following Lawrence Berkeley Laboratory (LBL) facilities: (1) Bevalac, (2) 88-Inch Cyclotron, (3) Materials Sciences Division.

  20. Quail Egg compared to a quarter

    Science.gov (United States)

    2003-01-01

    Quail eggs are small (shown here with a quarter for scale) and develop quickly, making them ideal for space experiments. The Avian Development Facility (ADF) supports 36 eggs in two carousels (below), one of which rotates to provide a 1-g control for comparing to eggs grown in microgravity. The ADF originated in NASA's Shuttle Student Involvement program in the 1980s and was developed under the NASA Small Business Irnovation Research program. In late 2001, the ADF made its first flight and carried eggs used in two investigations, Development and function of the inner-ear balance system in normal and altered gravity environments, and Skeletal development in embryonic quail.

  1. Operation of Finnish nuclear power plants. Quarterly report, 2nd quarter 1999

    Energy Technology Data Exchange (ETDEWEB)

    Tossavainen, K. [ed.

    1999-12-01

    Quarterly reports on the operation of Finnish NPPs describe events and observations relating to nuclear and radiation safety that the Finnish Radiation and Nuclear Safety Authority (STUK) considers safety significant. Safety improvements at the plants are also described. The report includes a summary of the radiation safety of plant personnel and the environment and tabulated data on the plants' production and load factors. All Finnish NPP units were in power operation for the whole second quarter of 1999, with the exception of the annual maintenance outages of the Olkiluoto plant units. The load factor average of the plant units in this quarter was 93.1%. Two events in this quarter were classified Level 1 on the INKS Scale. At Olkiluoto 1, a valve of the containment gas treatment system had been in an incorrect position for almost a month, owing to which the system would not have been available as planned in an accident. At Olkiluoto 2, main circulation pump work was done during the annual maintenance outage and a containment personnel air lock was briefly open in violation of the Technical Specifications. Water leaking out of the reactor in an accident could not have been directed to the emergency cooling system because it would have leaked out from the containment via the open personnel air lock. Other events in this quarter had no bearing on the nuclear or radiation safety of the plant units. The individual doses of NPP personnel and also radioactive releases off-site were well below authorised limits. Radioactive substances were measurable in samples collected around the plants in such quantities only as have no bearing on the radiation exposure of the population. (orig.)

  2. Review of a Proposed Quarterly Coal Publication

    Energy Technology Data Exchange (ETDEWEB)

    1981-01-01

    This Review of a Proposed Quartery Coal Publication contains findings and recommendations regarding the content of a new summary Energy Information Administration (EIA) coal and coke publication entitled The Quarterly Coal Review (QCR). It is divided into five sections: results of interviews with selected EIA data users; identification of major functions of the coal and coke industries; analysis of coal and coke data collection activities; evaluation of issues conerning data presentation including recommendations for the content of the proposed QCR; and comparison of the proposed QCR with other EIA publications. Major findings and recommendations are as follows: (1) User interviews indicate a definite need for a compehensive publication that would support analyses and examine economic, supply and demand trends in the coal industry; (2) the organization of the publication should reflect the natural order of activities of the coal and coke industries. Based on an analysis of the industries, these functions are: production, stocks, imports, exports, distribution, and consumption; (3) current EIA coal and coke surveys collect sufficient data to provide a summary of the coal and coke industries on a quarterly basis; (4) coal and coke data should be presented separately. Coke data could be presented as an appendix; (5) three geographic aggregations are recommended in the QCR. These are: US total, coal producing districts, and state; (6) coal consumption data should be consolidated into four major consumer categories: electric utilities, coke plants, other industrial, and residential commercial; (7) several EIA publications could be eliminated by the proposed QCR.

  3. Quarterly Technical Progress Report June 2015

    Energy Technology Data Exchange (ETDEWEB)

    Buchholz, Bruce A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2015-06-08

    The project has two main goals: 1) Identify the types of adducts naphthalene (NA) forms with DNA and 2) determine whether adduct formation correlates with site selective tumor formation in defined subcompartments of the respiratory tract (respiratory and olfactory nasal epithelium and airways of mice, rats and rhesus monkeys). Five tasks are associated with the completion of the goals. Task 1: Contracting and Animal Use Approvals. IACUC and ACURO approvals are complete, The subcontract with UC Davis (UCD) was executed in December 2014. Task 2: Perform In Vitro Study for Goal 1. Rat samples exposed and in freezer while adduct standards are being made. Mouse samples need to be exposed in next quarter. Task 3: Perform In Vitro Study for Goal 2. Mouse ex vivo samples completed. Rat and monkey samples need to be completed in the next quarter. Task 4: Sample Preparation and Analysis. Mouse Goal 2 samples completed. Other samples remain to be done. Task 5: Data Interpretation and Reporting. Need rat data to write paper on adduct formation.

  4. 41 CFR 114-51.100 - Departmental Quarters Handbook.

    Science.gov (United States)

    2010-07-01

    ... Handbook. 114-51.100 Section 114-51.100 Public Contracts and Property Management Federal Property...-General § 114-51.100 Departmental Quarters Handbook. The Office of Acquisition and Property Management (PAM) has prepared the Departmental Quarters Handbook (DQH), 400 DM, which provides detailed guidelines...

  5. Apprentices & Trainees: Early Trend Estimates. December Quarter, 2014

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2015

    2015-01-01

    This publication presents early estimates of apprentice and trainee commencements for the December quarter 2014. Indicative information about this quarter is presented here; the most recent figures are estimated, taking into account reporting lags that occur at the time of data collection. The early trend estimates are derived from the National…

  6. Apprentices & Trainees: Early Trend Estimates. March Quarter, 2012

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2012

    2012-01-01

    This publication presents early estimates of apprentice and trainee commencements for the March quarter 2012. Indicative information about this quarter is presented here; the most recent figures are estimated, taking into account reporting lags that occur at the time of data collection. The early trend estimates are derived from the National…

  7. Apprentices and Trainees: Early Trend Estimates. December Quarter 2010

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2011

    2011-01-01

    This publication presents early estimates of apprentice and trainee commencements for the December quarter 2010. Indicative information about this quarter is presented here; the most recent figures are estimated, taking into account reporting lags that occur at the time of data collection. The early trend estimates are derived from the National…

  8. Apprentices & Trainees: Early Trend Estimates. March Quarter 2010

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2010

    2010-01-01

    This new publication presents early estimates of apprentice and trainee commencements in the March quarter 2010. Indicative information about the current quarter is presented here in response to the demand for more timely data. The most recent figures are estimated, taking into account reporting lags that occur at the time of data collection. The…

  9. Apprentices & Trainees: Early Trend Estimates. December Quarter, 2012

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2013

    2013-01-01

    This publication presents early estimates of apprentice and trainee commencements for the December quarter 2012. Indicative information about this quarter is presented here; the most recent figures are estimated, taking into account reporting lags that occur at the time of data collection. The early trend estimates are derived from the National…

  10. Apprentices & Trainees: Early Trend Estimates. December Quarter 2011

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2012

    2012-01-01

    This publication presents early estimates of apprentice and trainee commencements for the December quarter 2011. Indicative information about this quarter is presented here; the most recent figures are estimated, taking into account reporting lags that occur at the time of data collection. The early trend estimates are derived from the National…

  11. Apprentices and Trainees: Early Trend Estimates. June Quarter 2010

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2010

    2010-01-01

    This publication presents early estimates of apprentice and trainee commencements for the June quarter 2010. Indicative information about this quarter is presented here; the most recent figures are estimated, taking into account reporting lags that occur at the time of data collection. The early trend estimates are derived from the National…

  12. A vector of quarters representation for bivariate time series

    NARCIS (Netherlands)

    Ph.H.B.F. Franses (Philip Hans)

    1995-01-01

    textabstractIn this paper it is shown that several models for a bivariate nonstationary quarterly time series are nested in a vector autoregression with cointegration restrictions for the eight annual series of quarterly observations. Or, the Granger Representation Theorem is extended to incorporate

  13. Western Gas Sands Project Quarterly Basin Activities Report

    Energy Technology Data Exchange (ETDEWEB)

    Atkinson, C H

    1979-04-30

    This quarterly basin activities report is a summation of three months drilling and testing activities in the Greater Green River Basin, Northern Great Plains Province, Piceance Basin, and Uinta Basin. Detailed information is given for each study area for the first quarter of 1979.

  14. 77 FR 51705 - Rescission of Quarterly Financial Reporting Requirements

    Science.gov (United States)

    2012-08-27

    ... Financial Reporting Requirements AGENCY: Federal Motor Carrier Safety Administration (FMCSA), DOT. ACTION... the quarterly financial reporting requirements for certain for-hire motor carriers of property (Form... notice of proposed rulemaking in the near future proposing the elimination of the quarterly...

  15. Three Oil Giants Achieved Good Operating Performances in First Quarter

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    @@ PetroChina announced performance results PetroChina released its operation data for the first quarter this year on April 15th. A manager in PetroChina said that the increase rate of production of PetroChina in the first quarter this year has created the best level since PetroChina registered in HK in 2000.

  16. Jet fuel from 18 cool-season oilseed feedstocks in a semi-arid environment

    Science.gov (United States)

    Allen, Brett; Jabro, Jay

    2017-04-01

    Renewable jet fuel feedstocks can potentially offset the demand for petroleum based transportation resources, diversify cropping systems, and provide numerous ecosystem services . However, identifying suitable feedstock supplies remains a primary constraint to adoption. A 4-yr, multi-site experiment initiated in fall 2012 investigated the yield potential of six winter- and twelve spring-types of cool-season oilseed feedstocks. Sidney, MT (250 mm annual growing season precipitation) was one of eight sites in the western USA with others in Colorado, Idaho, Iowa, Minnesota, North Dakota, Oregon, and Texas. Winter types of Camelina sativa (1), Brassica napus (4), and B. rapa (1) were planted in mid-September, while spring types of Camelina sativa (1), B. napus (4), B. rapa (1), B. juncea (2), B. carinata (2), and Sinapis alba (2) were planted in early to late April. Seeding rates varied by entry and were between 4 to 11 kg/ha. All plots were under no-till management. Plots were 3 by 9 m with each treatment (oilseed entry) replicated four times. Camelina 'Joelle' was the only fall-seeded entry that survived winters with little to no snow cover on plots and where minimum air temperature reached -32°C. Stands of 'Joelle' in the spring of all years were excellent. 'Joelle' plots were typically harvested in July, while spring types were harvested 2-6 weeks later. Severe hailstorms during the late growing seasons of 2013 and 2015 resulted in up to 95% seed loss, preventing normal seed yield harvest of spring types. The B. carinata and spring camelina were the least and most susceptible to hail damage during plant maturity, respectively. 'Joelle' winter camelina was harvested before the severe weather in both years, showing the benefit of an early maturing crop in regions prone to late season hail. Overall, camelina was the only winter type that showed potential as an oilseed feedstock due to its superior winter hardiness. For spring types, B. napus, Camelina sativa, and B

  17. Development of a system for characterizing biomass quality of lignocellulosic feedstocks for biochemical conversion

    Science.gov (United States)

    Murphy, Patrick Thomas

    The purpose of this research was twofold: (i) to develop a system for screening lignocellulosic biomass feedstocks for biochemical conversion to biofuels and (ii) to evaluate brown midrib corn stover as feedstock for ethanol production. In the first study (Chapter 2), we investigated the potential of corn stover from bm1-4 hybrids for increased ethanol production and reduced pretreatment intensity compared to corn stover from the isogenic normal hybrid. Corn stover from hybrid W64A X A619 and respective isogenic bm hybrids was pretreated by aqueous ammonia steeping using ammonium hydroxide concentrations from 0 to 30%, by weight, and the resulting residues underwent simultaneous saccharification and cofermentation (SSCF) to ethanol. Dry matter (DM) digested by SSCF increased with increasing ammonium hydroxide concentration across all genotypes (P>0.0001) from 277 g kg-1 DM in the control to 439 g kg-1 DM in the 30% ammonium hydroxide pretreatment. The bm corn stover materials averaged 373 g kg-1 DM of DM digested by SSCF compared with 335 g kg-1 DM for the normal corn stover (Pcell-wall carbohydrate hydrolysis of corn stover, (ii) the lowest initial cell-wall carbohydrate concentration, (iii) the lowest dry matter remaining after pretreatment, and (iv) the highest amount of monosaccharides released during enzymatic hydrolysis. However, bm corn stover did not reduce the severity of aqueous ammonia steeping pretreatment needed to maximize DM hydrolysis during SSCF compared with normal corn stover. In the remaining studies (Chapters 3 thru 5), a system for analyzing the quality of lignocellulosic biomass feedstocks for biochemical conversion to biofuels (i.e., pretreatment, enzymatic hydrolysis, and fermentation) was developed. To accomplish this, a carbohydrate availability model was developed to characterize feedstock quality. The model partitions carbohydrates within a feedstock material into fractions based on their availability to be converted to fermentable

  18. Performance Analysis of an Integrated Fixed Bed Gasifier Model for Different Biomass Feedstocks

    Directory of Open Access Journals (Sweden)

    Sharmina Begum

    2013-12-01

    Full Text Available Energy recovery from biomass by gasification technology has attracted significant interest because it satisfies a key requirement of environmental sustainability by producing near zero emissions. Though it is not a new technology, studies on its integrated process simulation and analysis are limited, in particular for municipal solid waste (MSW gasification. This paper develops an integrated fixed bed gasifier model of biomass gasification using the Advanced System for Process ENngineering (Aspen Plus software for its performance analysis. A computational model was developed on the basis of Gibbs free energy minimization. The model is validated with experimental data of MSW and food waste gasification available in the literature. A reasonable agreement between measured and predicted syngas composition was found. Using the validated model, the effects of operating conditions, namely air-fuel ratio and gasifier temperature, on syngas production are studied. Performance analyses have been done for four different feedstocks, namely wood, coffee bean husks, green wastes and MSWs. The ultimate and proximate analysis data for each feedstock was used for model development. It was found that operating parameters have a significant influence on syngas composition. An air-fuel ratio of 0.3 and gasifier temperature of 700 °C provides optimum performance for a fixed bed gasifier for MSWs, wood wastes, green wastes and coffee bean husks. The developed model can be useful for gasification of other biomasses (e.g., food wastes, rice husks, poultry wastes and sugarcane bagasse to predict the syngas composition. Therefore, the study provides an integrated gasification model which can be used for different biomass feedstocks.

  19. The potential impacts of biomass feedstock production on water resource availability.

    Science.gov (United States)

    Stone, K C; Hunt, P G; Cantrell, K B; Ro, K S

    2010-03-01

    Biofuels are a major topic of global interest and technology development. Whereas bioenergy crop production is highly dependent on water, bioenergy development requires effective allocation and management of water. The objectives of this investigation were to assess the bioenergy production relative to the impacts on water resource related factors: (1) climate and weather impact on water supplies for biomass production; (2) water use for major bioenergy crop production; and (3) potential alternatives to improve water supplies for bioenergy. Shifts to alternative bioenergy crops with greater water demand may produce unintended consequences for both water resources and energy feedstocks. Sugarcane and corn require 458 and 2036 m(3) water/m(3) ethanol produced, respectively. The water requirements for corn grain production to meet the US-DOE Billion-Ton Vision may increase approximately 6-fold from 8.6 to 50.1 km(3). Furthermore, climate change is impacting water resources throughout the world. In the western US, runoff from snowmelt is occurring earlier altering the timing of water availability. Weather extremes, both drought and flooding, have occurred more frequently over the last 30 years than the previous 100 years. All of these weather events impact bioenergy crop production. These events may be partially mitigated by alternative water management systems that offer potential for more effective water use and conservation. A few potential alternatives include controlled drainage and new next-generation livestock waste treatment systems. Controlled drainage can increase water available to plants and simultaneously improve water quality. New livestock waste treatments systems offer the potential to utilize treated wastewater to produce bioenergy crops. New technologies for cellulosic biomass conversion via thermochemical conversion offer the potential for using more diverse feedstocks with dramatically reduced water requirements. The development of bioenergy

  20. Methodological issues in life cycle assessment of mixed-culture polyhydroxyalkanoate production utilising waste as feedstock.

    Science.gov (United States)

    Heimersson, Sara; Morgan-Sagastume, Fernando; Peters, Gregory M; Werker, Alan; Svanström, Magdalena

    2014-06-25

    Assessing the environmental performance of emerging technologies using life cycle assessment (LCA) can be challenging due to a lack of data in relation to technologies, application areas or other life cycle considerations, or a lack of LCA methodology that address the specific concerns. Nevertheless, LCA can be a valuable tool in the environmental optimisation in the technology development phase. One emerging technology is the mixed-culture production of polyhydroxyalkanoates (PHAs). PHA production by pure microbial cultures has been developed and assessed in several LCAs during the previous decade. Recent developments within mixed-culture PHA production call for environmental assessment to guide in technology development. Mixed-culture PHA production can use the organic content in wastewater as a feedstock; the production may then be integrated with wastewater treatment (WWT) processes. This means that mixed-culture PHA is produced as a by-product from services in the WWT. This article explores different methodological challenges for LCA of mixed-culture PHA production using organic material in wastewater as feedstock. LCAs of both pure- and mixed-culture PHA production were reviewed. Challenges, similarities and differences when assessing PHA production by mixed- or pure-cultures were identified and the resulting implications for methodological choices in LCA were evaluated and illustrated, using a case study with mixed- and pure-culture PHA model production systems, based on literature data. Environmental impacts of processes producing multiple products or services need to be allocated between the different products or services. Such situations occur both in feedstock production and when the studied system is providing multiple functions. The selection of allocation method is shown to determine the LCA results. The type of data used, for electricity in the energy system, is shown to be important for the results, which indicates, a strong regional dependency of