Hydrodeoxygenation processes: advances on catalytic transformations of biomass-derived platform chemicals into hydrocarbon fuels.

Science.gov (United States)

De, Sudipta; Saha, Basudeb; Luque, Rafael

2015-02-01

Lignocellulosic biomass provides an attractive source of renewable carbon that can be sustainably converted into chemicals and fuels. Hydrodeoxygenation (HDO) processes have recently received considerable attention to upgrade biomass-derived feedstocks into liquid transportation fuels. The selection and design of HDO catalysts plays an important role to determine the success of the process. This review has been aimed to emphasize recent developments on HDO catalysts in effective transformations of biomass-derived platform molecules into hydrocarbon fuels with reduced oxygen content and improved H/C ratios. Liquid hydrocarbon fuels can be obtained by combining oxygen removal processes (e.g. dehydration, hydrogenation, hydrogenolysis, decarbonylation etc.) as well as by increasing the molecular weight via C-C coupling reactions (e.g. aldol condensation, ketonization, oligomerization, hydroxyalkylation etc.). Fundamentals and mechanistic aspects of the use of HDO catalysts in deoxygenation reactions will also be discussed. Copyright © 2014 Elsevier Ltd. All rights reserved.

Generation of transportation fuel from solid municipal waste plastics

Energy Technology Data Exchange (ETDEWEB)

Sarker, Moinuddin

2010-09-15

Transportation fuels derived from fossil fuels are subjected to the price fluctuations of the global marketplace, and constitute a major expense in the operation of a vehicle. Emissions from the evaporation and combustion of these fuels contribute to a range of environmental problems, causing poor air quality and emitting greenhouse gases that contribute to global warming. Alternative fuels created from domestic sources have been proposed as a solution to these problems, and many fuels are being developed based on biomass and other renewable sources. Natural State Research, Inc. developed different alternative hydrocarbon fuel which is produced from waste plastic materials.

Transportation fuel from plastic: Two cases of study.

Science.gov (United States)

Faussone, Gian Claudio

2018-03-01

Synthesis of liquid fuels from waste is a promising pathway for reducing the carbon footprint of transportation industry and optimizing waste management towards zero landfilling. The study of commercial plants that conduct pyrolysis of plastics from post-consumer recycled materials and directly mine from old landfills without any pre-treatment has revealed two cases that show the feasibility of manufacturing transportation fuels via these methods. Pyrolysis oil, consisting of almost 26% hydrocarbons within the gasoline range and almost 70% within the diesel range, is upgraded to transportation fuel in the existing refinery. A batch operating plant is able to deliver relatively good quality pyrolysis oil from post-consumer plastic waste, owing to the catalyst employed. Simple distillation was also evaluated as an alternative and cheaper upgrading process into transportation fuels, meeting EN590 diesel and ISO8217 marine fuel standards. Even though the two installations are outside the European Union, they represent good examples of the "circular economy" concept envisaged by the European Union via its ambitious "Circular Economy Package [1]", providing real world data for comparison with other experimental and lab results. Copyright © 2017 Elsevier Ltd. All rights reserved.

TECHNOLOGY FOR EFFICIENT USAGE OF HYDROCARBON-CONTAINING WASTE IN PRODUCTION OF MULTI-COMPONENT SOLID FUEL

Directory of Open Access Journals (Sweden)

B. M. Khroustalev

2016-01-01

Full Text Available The paper considers modern approaches to usage of hydrocarbon-containing waste as energy resources and presents description of investigations, statistic materials, analysis results on formation of hydrocarbon-containing waste in the Republic of Belarus. Main problems pertaining to usage of waste as a fuel and technologies for their application have been given in the paper. The paper describes main results of the investigations and a method for efficient application of viscous hydrocarbon-containing waste as an energy-packed component and a binding material while producing a solid fuel. A technological scheme, a prototype industrial unit which are necessary to realize a method for obtaining multi-component solid fuel are represented in the paper. A paper also provides a model of technological process with efficient sequence of technological operations and parameters of optimum component composition. Main factors exerting significant structure-formation influence in creation of structural composition of multi-component solid fuel have been presented in the paper. The paper gives a graphical representation of the principle for selection of mixture particles of various coarseness to form a solid fuel while using a briquetting method and comprising viscous hydrocarbon-containing waste. A dependence of dimensionless concentration g of emissions into atmosphere during burning of two-component solid fuel has been described in the paper. The paper analyzes an influence of the developed methodology for emission calculation of multi-component solid fuels and reveals a possibility to optimize the component composition in accordance with ecological function and individual peculiar features of fuel-burning equipment. Special features concerning storage and transportation, advantages and disadvantages, comparative characteristics, practical applicability of the developed multi-component solid fuel have been considered and presented in the paper. The paper

Method and apparatus for preventing agglomeration within fluid hydrocarbons

International Nuclear Information System (INIS)

Woodbridge, D.D.

1979-01-01

This invention relates to a process for treating a fluid hydrocarbon fuel for retarding the agglomeration between particles thereof and for retarding the growth of bacteria and fungi therein. The process includes that steps of transporting a plurality of unit volumes of said fluid hydrocarbon fuel through an irradiating location and irradiating each unit of the plurality of unit volumes at the irradiating location with either neutron or gamma radiation. An apparatus for treating the fluid hydrocarbon fuels with the nuclear radiation also is provided. The apparatus includes a generally conical central irradiating cavity which is surrounded by a spiral outer irradiating cavity. The fluid hydrocarbon fuel is transported through the cavities while being irradiated by the nuclear radiation

Inhalation of Hydrocarbon Jet Fuel Suppress Central Auditory Nervous System Function.

Science.gov (United States)

Guthrie, O'neil W; Wong, Brian A; McInturf, Shawn M; Reboulet, James E; Ortiz, Pedro A; Mattie, David R

2015-01-01

More than 800 million L/d of hydrocarbon fuels is used to power cars, boats, and jet airplanes. The weekly consumption of these fuels necessarily puts the public at risk for repeated inhalation exposure. Recent studies showed that exposure to hydrocarbon jet fuel produces lethality in presynaptic sensory cells, leading to hearing loss, especially in the presence of noise. However, the effects of hydrocarbon jet fuel on the central auditory nervous system (CANS) have not received much attention. It is important to investigate the effects of hydrocarbons on the CANS in order to complete current knowledge regarding the ototoxic profile of such exposures. The objective of the current study was to determine whether inhalation exposure to hydrocarbon jet fuel might affect the functions of the CANS. Male Fischer 344 rats were randomly divided into four groups (control, noise, fuel, and fuel + noise). The structural and functional integrity of presynaptic sensory cells was determined in each group. Neurotransmission in both peripheral and central auditory pathways was simultaneously evaluated in order to identify and differentiate between peripheral and central dysfunctions. There were no detectable effects on pre- and postsynaptic peripheral functions. However, the responsiveness of the brain was significantly depressed and neural transmission time was markedly delayed. The development of CANS dysfunctions in the general public and the military due to cumulative exposure to hydrocarbon fuels may represent a significant but currently unrecognized public health issue.

Canadian hydrocarbon transportation system : transportation assessment

International Nuclear Information System (INIS)

2006-06-01

This document provided an assessment of the Canadian hydrocarbon transportation system. In addition to regulating the construction and operation of Canada's 45,000 km of pipeline that cross international and provincial borders, Canada's National Energy Board (NEB) regulates the trade of natural gas, oil and natural gas liquids. The ability of pipelines to delivery this energy is critical to the country's economic prosperity. The pipeline system includes large-diameter, cross-country, high-pressure natural gas pipelines, low-pressure crude oil and oil products pipelines and small-diameter pipelines. In order to assess the hydrocarbon transportation system, staff at the NEB collected data from pipeline companies and a range of publicly available sources. The Board also held discussions with members of the investment community regarding capital markets and emerging issues. The assessment focused largely on evaluating whether Canadians benefit from an efficient energy infrastructure and markets. The safety and environmental integrity of the pipeline system was also evaluated. The current adequacy of pipeline capacity was assessed based on price differentials compared with firm service tolls for major transportation paths; capacity utilization on pipelines; and, the degree of apportionment on major oil pipelines. The NEB concluded that the Canadian hydrocarbon transportation system is working effectively, with an adequate capacity in place on existing natural gas pipelines, but with a tight capacity on oil pipelines. It was noted that shippers continue to indicate that they are reasonably satisfied with the services provided by pipeline companies and that the NEB-regulated pipeline companies are financially stable. 14 refs, 11 tabs., 28 figs., 4 appendices

Investigation Status of Heat Exchange while Boiling Hydrocarbon Fuel

Directory of Open Access Journals (Sweden)

D. S. Obukhov

2006-01-01

Full Text Available The paper contains analysis of heat exchange investigations while boiling hydrocarbon fuel. The obtained data are within the limits of the S.S. Kutateladze dependence proposed in 1939. Heat exchange at non-stationary heat release has not been investigated. The data for hydrocarbon fuel with respect to critical density of heat flow are not available even for stationary conditions.

National Gas Survey. Synthesized gaseous hydrocarbon fuels

Energy Technology Data Exchange (ETDEWEB)

None

1978-06-01

The supply-Technical Advisory Task Force-Synthesized Gaseous Hydrocarbon Fuels considered coal, hydrocarbon liquids, oil shales, tar sands, and bioconvertible materials as potential feedstocks for gaseous fuels. Current status of process technology for each feedstock was reviewed, economic evaluations including sensitivity analysis were made, and constraints for establishment of a synthesized gaseous hydrocarbon fuels industry considered. Process technology is presently available to manufacture gaseous hydrocarbon fuels from each of the feedstocks. In 1975 there were eleven liquid feedstock SNG plants in the United States having a capacity of 1.1 billion SCFD. There can be no contribution of SNG before 1982 from plants using feedstocks other than liquids because there are no plants in operation or under construction as of 1977. Costs for SNG are higher than current regulated prices for U.S. natural gas. Because of large reserves, coal is a prime feedstock candidate although there are major constraints in the area of coal leases, mining and water permits, and others. Commercial technology is available and several new gasification processes are under development. Oil shale is also a feedstock in large supply and commercial process technology is available. There are siting and permit constraints, and water availability may limit the ultimate size of an oil shale processing industry. Under projected conditions, bioconvertible materials are not expected to support the production of large quantities of pipeline quality gas during the next decade. Production of low or medium Btu gas from municipal solid wastes can be expected to be developed in urban areas in conjunction with savings in disposal costs. In the economic evaluations presented, the most significant factor for liquid feedstock plants is the anticipated cost of feedstock and fuel. The economic viability of plants using other feedstocks is primarily dependent upon capital requirements.

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil

Science.gov (United States)

Knauss, Kevin G.; Copenhaver, Sally C.; Aines, Roger D.

2000-01-01

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Integration of direct carbon and hydrogen fuel cells for highly efficient power generation from hydrocarbon fuels

Energy Technology Data Exchange (ETDEWEB)

Muradov, Nazim; Choi, Pyoungho; Smith, Franklyn; Bokerman, Gary [Florida Solar Energy Center, University of Central Florida, 1679 Clearlake Road, Cocoa, FL 32922-5703 (United States)

2010-02-15

In view of impending depletion of hydrocarbon fuel resources and their negative environmental impact, it is imperative to significantly increase the energy conversion efficiency of hydrocarbon-based power generation systems. The combination of a hydrocarbon decomposition reactor with a direct carbon and hydrogen fuel cells (FC) as a means for a significant increase in chemical-to-electrical energy conversion efficiency is discussed in this paper. The data on development and operation of a thermocatalytic hydrocarbon decomposition reactor and its coupling with a proton exchange membrane FC are presented. The analysis of the integrated power generating system including a hydrocarbon decomposition reactor, direct carbon and hydrogen FC using natural gas and propane as fuels is conducted. It was estimated that overall chemical-to-electrical energy conversion efficiency of the integrated system varied in the range of 49.4-82.5%, depending on the type of fuel and FC used, and CO{sub 2} emission per kW{sub el}h produced is less than half of that from conventional power generation sources. (author)

A Monte Carlo simulation method for assessing biotransformation effects on groundwater fuel hydrocarbon plume lengths

International Nuclear Information System (INIS)

McNab, W.W. Jr.

2000-01-01

Biotransformation of dissolved groundwater hydrocarbon plumes emanating from leaking underground fuel tanks should, in principle, result in plume length stabilization over relatively short distances, thus diminishing the environmental risk. However, because the behavior of hydrocarbon plumes is usually poorly constrained at most leaking underground fuel tank sites in terms of release history, groundwater velocity, dispersion, as well as the biotransformation rate, demonstrating such a limitation in plume length is problematic. Biotransformation signatures in the aquifer geochemistry, most notably elevated bicarbonate, may offer a means of constraining the relationship between plume length and the mean biotransformation rate. In this study, modeled plume lengths and spatial bicarbonate differences among a population of synthetic hydrocarbon plumes, generated through Monte Carlo simulation of an analytical solute transport model, are compared to field observations from six underground storage tank (UST) sites at military bases in California. Simulation results indicate that the relationship between plume length and the distribution of bicarbonate is best explained by biotransformation rates that are consistent with ranges commonly reported in the literature. This finding suggests that bicarbonate can indeed provide an independent means for evaluating limitations in hydrocarbon plume length resulting from biotransformation. (Author)

How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels

DEFF Research Database (Denmark)

Peterson, Andrew; Abild-Pedersen, Frank; Studt, Felix

2010-01-01

Density functional theory calculations explain copper's unique ability to convert CO2 into hydrocarbons, which may open up (photo-)electrochemical routes to fuels.......Density functional theory calculations explain copper's unique ability to convert CO2 into hydrocarbons, which may open up (photo-)electrochemical routes to fuels....

Motor vehicle fuel economy, the forgotten HC control stragegy. [Hydrocarbon (HC)

Energy Technology Data Exchange (ETDEWEB)

Deluchi, M.; Wang, Quanlu; Greene, D.L.

1992-06-01

Emissions of hydrocarbons from motor vehicles are recognized as major contributors to ozone pollution in urban areas. Petroleum-based motor fuels contain volatile organic compounds (VOC) which, together with oxides of nitrogen, promote the formation of ozone in the troposphere via complex photochemical reactions. VOC emissions from the tailpipe and evaporation from the fuel and engine systems of highway vehicles are believed to account for about 40% of total VOC emissions in any region. But motor fuels also generate emissions throughout the fuel cycle, from crude oil production to refining, storage, transportation, and handling, that can make significant contributions to the total inventory of VOC emissions. Many of these sources of emissions are directly related to the quantity of fuel produced and handled throughout the fuel cycle. It is, therefore, reasonable to expect that a reduction in total fuel throughput might result in a reduction of VOC emissions. In particular, reducing vehicle fuel consumption by increasing vehicle fuel economy should reduce total fuel throughput, thereby cutting total emissions of VOCS. In this report we identify the sources of VOC emissions throughout the motor fuel cycle, quantify them to the extent possible, and describe their dependence on automobile and light truck fuel economy.

High energy-density liquid rocket fuel performance

Science.gov (United States)

Rapp, Douglas C.

1990-01-01

A fuel performance database of liquid hydrocarbons and aluminum-hydrocarbon fuels was compiled using engine parametrics from the Space Transportation Engine Program as a baseline. Propellant performance parameters are introduced. General hydrocarbon fuel performance trends are discussed with respect to hydrogen-to-carbon ratio and heat of formation. Aluminum-hydrocarbon fuel performance is discussed with respect to aluminum metal loading. Hydrocarbon and aluminum-hydrocarbon fuel performance is presented with respect to fuel density, specific impulse and propellant density specific impulse.

Development of a Raman spectroscopy technique to detect alternate transportation fuel hydrocarbon intermediates in complex combustion environments.

Energy Technology Data Exchange (ETDEWEB)

Ekoto, Isaac W.; Barlow, Robert S.

2012-12-01

Spontaneous Raman spectra for important hydrocarbon fuels and combustion intermediates were recorded over a range of low-to-moderate flame temperatures using the multiscalar measurement facility located at Sandia/CA. Recorded spectra were extrapolated to higher flame temperatures and then converted into empirical spectral libraries that can readily be incorporated into existing post-processing analysis models that account for crosstalk from overlapping hydrocarbon channel signal. Performance testing of the developed libraries and reduction methods was conducted through an examination of results from well-characterized laminar reference flames, and was found to provide good agreement. The diagnostic development allows for temporally and spatially resolved flame measurements of speciated hydrocarbon concentrations whose parent is more chemically complex than methane. Such data are needed to validate increasingly complex flame simulations.

Hydrocarbon Fuel Thermal Performance Modeling based on Systematic Measurement and Comprehensive Chromatographic Analysis

Science.gov (United States)

2016-07-31

distribution unlimited Hydrocarbon Fuel Thermal Performance Modeling based on Systematic Measurement and Comprehensive Chromatographic Analysis Matthew...vital importance for hydrocarbon -fueled propulsion systems: fuel thermal performance as indicated by physical and chemical effects of cooling passage... analysis . The selection and acquisition of a set of chemically diverse fuels is pivotal for a successful outcome since test method validation and

Conversion of hydrocarbons and alcohols for fuel cells

Science.gov (United States)

Joensen, Finn; Rostrup-Nielsen, Jens R.

The growing demand for clean and efficient energy systems is the driving force in the development of fuel processing technology for providing hydrogen or hydrogen-containing gaseous fuels for power generation in fuel cells. Successful development of low cost, efficient fuel processing systems will be critical to the commercialisation of this technology. This article reviews various reforming technologies available for the generation of such fuels from hydrocarbons and alcohols. It also briefly addresses the issue of carbon monoxide clean-up and the question of selecting the appropriate fuel(s) for small/medium scale fuel processors for stationary and automotive applications.

Fuel transporting device

International Nuclear Information System (INIS)

Shiratori, Hirozo.

1979-01-01

Purpose: In a liquid-metal cooled reactor, to reduce the waiting time of fuel handling apparatuses and shorten the fuel exchange time. Constitution: A fuel transporting machine is arranged between a reactor vessel and an out-pile storage tank, thereby dividing the transportation line of the pot for contracting fuel and transporting the same. By assuming such a construction, the flow of fuel transportation which has heretofore been carried out through fuel transportation pipes is not limited to one direction but the take-out of fuels from the reactor and the take-in thereof from the storage tank can be carried out constantly, and much time is not required for fuel exchange. (Kamimura, M.)

Hydrocarbon bio-jet fuel from bioconversion of poplar biomass: techno-economic assessment.

Science.gov (United States)

Crawford, Jordan T; Shan, Chin Wei; Budsberg, Erik; Morgan, Hannah; Bura, Renata; Gustafson, Rick

2016-01-01

Infrastructure compatible hydrocarbon biofuel proposed to qualify as renewable transportation fuel under the U.S. Energy Independence and Security Act of 2007 and Renewable Fuel Standard (RFS2) is evaluated. The process uses a hybrid poplar feedstock, which undergoes dilute acid pretreatment and enzymatic hydrolysis. Sugars are fermented to acetic acid, which undergoes conversion to ethyl acetate, ethanol, ethylene, and finally a saturated hydrocarbon end product. An unfermentable lignin stream may be burned for steam and electricity production, or gasified to produce hydrogen. During biofuel production, hydrogen gas is required and may be obtained by various methods including lignin gasification. Both technical and economic aspects of the biorefinery are analyzed, with different hydrogen sources considered including steam reforming of natural gas and gasification of lignin. Cash operating costs for jet fuel production are estimated to range from 0.67 to 0.86 USD L -1 depending on facility capacity. Minimum fuel selling prices with a 15 % discount rate are estimated to range from 1.14 to 1.79 USD L -1 . Capacities of 76, 190, and 380 million liters of jet fuel per year are investigated. Capital investments range from 356 to 1026 million USD. A unique biorefinery is explored to produce a hydrocarbon biofuel with a high yield from bone dry wood of 330 L t -1 . This yield is achieved chiefly due to the use of acetogenic bacteria that do not produce carbon dioxide as a co-product during fermentation. Capital investment is significant in the biorefinery in part because hydrogen is required to produce a fully de-oxygenated fuel. Minimum selling price to achieve reasonable returns on investment is sensitive to capital financing options because of high capital costs. Various strategies, such as producing alternative, intermediate products, are investigated with the intent to reduce risk in building the proposed facility. It appears that producing and selling these

Nuclear fuel transport and particularly spent fuel transport

International Nuclear Information System (INIS)

Lenail, B.

1986-01-01

Nuclear material transport is an essential activity for COGEMA linking the different steps of the fuel cycle transport systems have to be safe and reliable. Spent fuel transport is more particularly examined in this paper because the development of reprocessing plant. Industrial, techmical and economical aspects are reviewed [fr

Experimental study of the thermal stability of hydrocarbon fuels

Science.gov (United States)

Marteney, P. J.; Colket, M. B.; Vranos, A.

1982-01-01

The thermal stability of two hydrocarbon fuels (premium diesel and regular diesel) was determined in a flow reactor under conditions representing operation of an aircraft gas turbine engine. Temperature was varied from 300 to 750 F (422 to 672 K) for fuel flows of 2.84 to 56.8 liters/hr (corresponding to 6.84 x 0.00010 to 1.63 x 0.010 kg/sec for regular diesel fuel and 6.55 x 0.00010 to 1.37 x 0.010 kg/sec for premium diesel fuel); test times varied between 1 and 8 hr. The rate of deposition was obtained through measurement of weight gained by metal discs fixed along the channel wall. The rate of deposit formation is best correlated by an Arrhenius expression. The sample discs in the flow reactor were varied among stainless steel, aluminum and brass; fuels were doped with quinoline, indole, and benzoyl perioxide to yield nitrogen or oxygen concentrations of approximately 1000 ppm. The most substantial change in rate was an increase in deposits for brass discs; other disc materials or the additives caused only small perturbations. Tests were also conducted in a static reactor at temperatures of 300 to 800 F for times of 30 min to 2 1/2 hr. Much smaller deposition was found, indicating the importance of fluid transport in the mechanism.

Effect of concentration gradients on biodegradation in bench-scale sand columns with HYDRUS modeling of hydrocarbon transport and degradation.

Science.gov (United States)

Horel, Agota; Schiewer, Silke; Misra, Debasmita

2015-09-01

The present research investigated to what extent results obtained in small microcosm experiments can be extrapolated to larger settings with non-uniform concentrations. Microbial hydrocarbon degradation in sandy sediments was compared for column experiments versus homogenized microcosms with varying concentrations of diesel, Syntroleum, and fish biodiesel as contaminants. Syntroleum and fish biodiesel had higher degradation rates than diesel fuel. Microcosms showed significantly higher overall hydrocarbon mineralization percentages (p transport and degradation of the investigated fuels in vadose zone conditions similar to those in laboratory column experiments. The numerical model was used to evaluate the impact of different degradation rate constants from microcosm versus column experiments.

Reduction of Fuel Consumption and Exhaust Pollutant Using Intelligent Transport Systems

Directory of Open Access Journals (Sweden)

Mostofa Kamal Nasir

2014-01-01

Full Text Available Greenhouse gas emitted by the transport sector around the world is a serious issue of concern. To minimize such emission the automobile engineers have been working relentlessly. Researchers have been trying hard to switch fossil fuel to alternative fuels and attempting to various driving strategies to make traffic flow smooth and to reduce traffic congestion and emission of greenhouse gas. Automobile emits a massive amount of pollutants such as Carbon Monoxide (CO, hydrocarbons (HC, carbon dioxide (CO2, particulate matter (PM, and oxides of nitrogen (NOx. Intelligent transport system (ITS technologies can be implemented to lower pollutant emissions and reduction of fuel consumption. This paper investigates the ITS techniques and technologies for the reduction of fuel consumption and minimization of the exhaust pollutant. It highlights the environmental impact of the ITS application to provide the state-of-art green solution. A case study also advocates that ITS technology reduces fuel consumption and exhaust pollutant in the urban environment.

Reduction of Fuel Consumption and Exhaust Pollutant Using Intelligent Transport Systems

Science.gov (United States)

Nasir, Mostofa Kamal; Md Noor, Rafidah; Kalam, M. A.; Masum, B. M.

2014-01-01

Greenhouse gas emitted by the transport sector around the world is a serious issue of concern. To minimize such emission the automobile engineers have been working relentlessly. Researchers have been trying hard to switch fossil fuel to alternative fuels and attempting to various driving strategies to make traffic flow smooth and to reduce traffic congestion and emission of greenhouse gas. Automobile emits a massive amount of pollutants such as Carbon Monoxide (CO), hydrocarbons (HC), carbon dioxide (CO2), particulate matter (PM), and oxides of nitrogen (NOx). Intelligent transport system (ITS) technologies can be implemented to lower pollutant emissions and reduction of fuel consumption. This paper investigates the ITS techniques and technologies for the reduction of fuel consumption and minimization of the exhaust pollutant. It highlights the environmental impact of the ITS application to provide the state-of-art green solution. A case study also advocates that ITS technology reduces fuel consumption and exhaust pollutant in the urban environment. PMID:25032239

Reduction of fuel consumption and exhaust pollutant using intelligent transport systems.

Science.gov (United States)

Nasir, Mostofa Kamal; Md Noor, Rafidah; Kalam, M A; Masum, B M

2014-01-01

Greenhouse gas emitted by the transport sector around the world is a serious issue of concern. To minimize such emission the automobile engineers have been working relentlessly. Researchers have been trying hard to switch fossil fuel to alternative fuels and attempting to various driving strategies to make traffic flow smooth and to reduce traffic congestion and emission of greenhouse gas. Automobile emits a massive amount of pollutants such as Carbon Monoxide (CO), hydrocarbons (HC), carbon dioxide (CO2), particulate matter (PM), and oxides of nitrogen (NO x ). Intelligent transport system (ITS) technologies can be implemented to lower pollutant emissions and reduction of fuel consumption. This paper investigates the ITS techniques and technologies for the reduction of fuel consumption and minimization of the exhaust pollutant. It highlights the environmental impact of the ITS application to provide the state-of-art green solution. A case study also advocates that ITS technology reduces fuel consumption and exhaust pollutant in the urban environment.

Characterization of a nose-only inhalation exposure system for hydrocarbon mixtures and jet fuels.

Science.gov (United States)

Martin, Sheppard A; Tremblay, Raphael T; Brunson, Kristyn F; Kendrick, Christine; Fisher, Jeffrey W

2010-04-01

A directed-flow nose-only inhalation exposure system was constructed to support development of physiologically based pharmacokinetic (PBPK) models for complex hydrocarbon mixtures, such as jet fuels. Due to the complex nature of the aerosol and vapor-phase hydrocarbon exposures, care was taken to investigate the chamber hydrocarbon stability, vapor and aerosol droplet compositions, and droplet size distribution. Two-generation systems for aerosolizing fuel and hydrocarbons were compared and characterized for use with either jet fuels or a simple mixture of eight hydrocarbons. Total hydrocarbon concentration was monitored via online gas chromatography (GC). Aerosol/vapor (A/V) ratios, and total and individual hydrocarbon concentrations, were determined using adsorbent tubes analyzed by thermal desorption-gas chromatography-mass spectrometry (TDS-GC-MS). Droplet size distribution was assessed via seven-stage cascade impactor. Droplet mass median aerodynamic diameter (MMAD) was between 1 and 3 mum, depending on the generator and mixture utilized. A/V hydrocarbon concentrations ranged from approximately 200 to 1300 mg/m(3), with between 20% and 80% aerosol content, depending on the mixture. The aerosolized hydrocarbon mixtures remained stable during the 4-h exposure periods, with coefficients of variation (CV) of less than 10% for the total hydrocarbon concentrations. There was greater variability in the measurement of individual hydrocarbons in the A-V phase. In conclusion, modern analytical chemistry instruments allow for improved descriptions of inhalation exposures of rodents to aerosolized fuel.

Volatile Fuel Hydrocarbons and MTBE in the Environment

Science.gov (United States)

Cozzarelli, I. M.; Baehr, A. L.

2003-12-01

elements of sulfur, nitrogen, and oxygen constitute less than 3% of most petroleum (Hunt, 1996). Releases to the environment occur during the production, transport, processing, storage, use and disposal of these hydrocarbons. The petroleum industry classifies oil naturally occurring in a liquid phase as either conventional oil or nonconventional oil. Conventional oils can be explored and produced by conventional primary and secondary recovery techniques, whereas nonconventional oils, such as heavy oils, tar sands, and synthetic oils, are more difficult to extract from the host rock ( Tissot and Welte, 1984). The history of liquid petroleum usage dates back centuries. Marco Polo described its use as a fuel for lamps in 1291 ( Testa and Winegardner, 2000). In the mid-nineteenth century, Native Americans used crude oil skimmed from creeks and rivers as a medicinal ointment ( Energy Information Administration, 1999). Commercial production in the United States began in 1859, with kerosene production for use in lamps. At the turn of the century, emphasis shifted to gasoline with the invention of the automobile, and in the 1930s and 1940s a substantial market for heating oil developed.In 2000, over 85% of the world's energy came from fossil fuels (Table 1), with oil production alone supplying 40% of that energy (Edwards, 2001). Oil, with its high British Thermal Unit (BTU) density and ease of transport, is the most valuable fuel in the world today, and the demand for world crude oil is ever increasing. Annual world crude-oil demand increased from 22 billion to 28 billion bbl of oil (BBO) ((3.5-4.5)×1012 L) from 1990 to 2000. Increasing population growth and industrialization in developing countries is expected to drive this annual oil demand up 1.5% annually to ˜38 BBO (6.0×1012 L) by 2030. As demand increases and known oil reserves are depleted, more emphasis will be placed on new discoveries and improved recovery technologies. Sources such as tar sands and oil shales are

Motor fuels by hydrogenation of liquid hydrocarbons

Energy Technology Data Exchange (ETDEWEB)

1938-05-07

A process is disclosed for the production of knock-stable low-boiling motor fuels by conversion of liquid hydrocarbons which are vaporizable under the reaction conditions, which comprises passing the initial material at a temperature above 380/sup 0/C in a true vapor phase under pressure of more than 40 atmospheres together with hydrogen and gaseous hydrocarbons containing more than 1 carbon atom in the molecule in an amount by volume larger than that of the hydrogen over catalysts stable to poisoning stationarily confined in the reaction vessel.

Ignition behavior of aviation fuels and some hydrocarbons

Energy Technology Data Exchange (ETDEWEB)

Koerber, F.

1975-01-01

Air relighting of jet engines is an important contribution to the operation safety of aircraft engines. Reignition is influenced by fuel properties in addition to the engine design. A survey is presented on the problems, considering the specific fuel properties. Investigations were made on the ignition behavior of aviation fuels and hydrocarbons in a simplified model combustion chamber. Air inlet conditions were 200 to 800 mbar and 300 to 500 K. Correlation between physical and chemical properties and ignitability is discussed.

Anisotropic amplification of proton transport in proton exchange membrane fuel cells

Science.gov (United States)

Thimmappa, Ravikumar; Fawaz, Mohammed; Devendrachari, Mruthyunjayachari Chattanahalli; Gautam, Manu; Kottaichamy, Alagar Raja; Shafi, Shahid Pottachola; Thotiyl, Musthafa Ottakam

2017-07-01

Though graphene oxide (GO) membrane shuttles protons under humid conditions, it suffer severe disintegration and anhydrous conditions lead to abysmal ionic conductivity. The trade-off between mechanical integrity and ionic conductivity challenge the amplification of GO's ionic transport under anhydrous conditions. We show anisotropic amplification of GO's ionic transport with a selective amplification of in plane contribution under anhydrous conditions by doping it with a plant extract, phytic acid (PA). The hygroscopic nature of PA stabilized interlayer water molecules and peculiar geometry of sbnd OH functionalities around saturated hydrocarbon ring anisotropically enhanced ionic transport amplifying the fuel cell performance metrics.

Properties of plasma flames sustained by microwaves and burning hydrocarbon fuels

International Nuclear Information System (INIS)

Hong, Yong Cheol; Uhm, Han Sup

2006-01-01

Plasma flames made of atmospheric microwave plasma and a fuel-burning flame were presented and their properties were investigated experimentally. The plasma flame generator consists of a fuel injector and a plasma flame exit connected in series to a microwave plasma torch. The plasma flames are sustained by injecting hydrocarbon fuels into a microwave plasma torch in air discharge. The microwave plasma torch in the plasma flame system can burn a hydrocarbon fuel by high-temperature plasma and high atomic oxygen density, decomposing the hydrogen and carbon containing fuel. We present the visual observations of the sustained plasma flames and measure the gas temperature using a thermocouple device in terms of the gas-fuel mixture and flow rate. The plasma flame volume of the hydrocarbon fuel burners was more than approximately 30-50 times that of the torch plasma. While the temperature of the torch plasma flame was only 868 K at a measurement point, that of the diesel microwave plasma flame with the addition of 0.019 lpm diesel and 30 lpm oxygen increased drastically to about 2280 K. Preliminary experiments for methane plasma flame were also carried out, measuring the temperature profiles of flames along the radial and axial directions. Finally, we investigated the influence of the microwave plasma on combustion flame by observing and comparing OH molecular spectra for the methane plasma flame and methane flame only

Thermodynamic characterization of bio-fuels: Excess functions for binary mixtures containing ETBE and hydrocarbons

International Nuclear Information System (INIS)

Segovia, Jose J.; Villamanan, Rosa M.; Martin, M. Carmen; Chamorro, Cesar R.; Villamanan, Miguel A.

2010-01-01

European energy policy is promoting the use of bio-fuels for transportation. Bioethers and bioalcohols are used as blending agents for enhancing the octane number. They make gasoline work harder, help the engine last longer and reduce air pollution. They also cause changes in the fuel properties. Development of renewable fuels needs both knowledge of new thermodynamic data and improvement of clean energy technologies. In this context, the use of ethanol of vegetable origin in its manufacture process, increases the interest of ETBE or bio-ETBE as an oxygenated additive. A complete study of the behaviour of ETBE + hydrocarbons mixtures is presented. Some experimental data concerning vapor-liquid equilibria and heats of mixing were determined in our laboratory. All the techniques have a high accuracy. The data were reduced by well-known models, such as NRTL and used to model the thermodynamic properties.

Emergency fuels utilization guidebook. Alternative Fuels Utilization Program

Energy Technology Data Exchange (ETDEWEB)

1980-08-01

The basic concept of an emergency fuel is to safely and effectively use blends of specification fuels and hydrocarbon liquids which are free in the sense that they have been commandeered or volunteered from lower priority uses to provide critical transportation services for short-duration emergencies on the order of weeks, or perhaps months. A wide variety of liquid hydrocarbons not normally used as fuels for internal combustion engines have been categorized generically, including limited information on physical characteristics and chemical composition which might prove useful and instructive to fleet operators. Fuels covered are: gasoline and diesel fuel; alcohols; solvents; jet fuels; kerosene; heating oils; residual fuels; crude oils; vegetable oils; gaseous fuels.

Assessment of ground-water flow and chemical transport in a tidally influenced aquifer using geostatistical filtering and hydrocarbon fingerprinting

International Nuclear Information System (INIS)

Marquis, S.A. Jr.; Smith, E.A.

1994-01-01

Traditional environmental investigations at tidally influenced hazardous waste sites such as marine fuel storage terminals have generally failed to characterize ground-water flow and chemical transport because they have been based on only a cursory knowledge of plume geometry, chemicals encountered, and hydrogeologic setting and synoptic ground-water level measurement. Single-time observations cannot be used to accurately determine flow direction and gradient in tidally fluctuating aquifers since these measurements delineate hydraulic head at only one point in time during a tidal cycle, not the net effect of the fluctuations. In this study, a more rigorous approach was used to characterize flow and chemical transport in a tidally influenced aquifer at a marine fuel storage terminal using: (1) ground-water-level monitoring over three tidal cycles (72 hours), (2) geostatistical filtering of ground-water-level data using 25-hour and 71-hour filtering methods, and (3) hydrocarbon fingerprinting analysis. The results from the study indicate that naphtha released from one of the on-site naphtha tanks has been the predominant contributor to the hydrocarbon plume both on-site and downgradient off-site and that net ground-water and hydrocarbon movement has been to the southeast away from the tank since 1989

Energy and climate impacts of producing synthetic hydrocarbon fuels from CO(2).

Science.gov (United States)

van der Giesen, Coen; Kleijn, René; Kramer, Gert Jan

2014-06-17

Within the context of carbon dioxide (CO2) utilization there is an increasing interest in using CO2 as a resource to produce sustainable liquid hydrocarbon fuels. When these fuels are produced by solely using solar energy they are labeled as solar fuels. In the recent discourse on solar fuels intuitive arguments are used to support the prospects of these fuels. This paper takes a quantitative approach to investigate some of the claims made in this discussion. We analyze the life cycle performance of various classes of solar fuel processes using different primary energy and CO2 sources. We compare their efficacy with respect to carbon mitigation with ubiquitous fossil-based fuels and conclude that producing liquid hydrocarbon fuels starting from CO2 by using existing technologies requires much more energy than existing fuels. An improvement in life cycle CO2 emissions is only found when solar energy and atmospheric CO2 are used. Producing fuels from CO2 is a very long-term niche at best, not the panacea suggested in the recent public discourse.

Sustainable fuel for the transportation sector.

Science.gov (United States)

Agrawal, Rakesh; Singh, Navneet R; Ribeiro, Fabio H; Delgass, W Nicholas

2007-03-20

A hybrid hydrogen-carbon (H(2)CAR) process for the production of liquid hydrocarbon fuels is proposed wherein biomass is the carbon source and hydrogen is supplied from carbon-free energy. To implement this concept, a process has been designed to co-feed a biomass gasifier with H(2) and CO(2) recycled from the H(2)-CO to liquid conversion reactor. Modeling of this biomass to liquids process has identified several major advantages of the H(2)CAR process. (i) The land area needed to grow the biomass is transportation sector. (ii) Whereas the literature estimates known processes to be able to produce approximately 30% of the United States transportation fuel from the annual biomass of 1.366 billion tons, the H(2)CAR process shows the potential to supply the entire United States transportation sector from that quantity of biomass. (iii) The synthesized liquid provides H(2) storage in an open loop system. (iv) Reduction to practice of the H(2)CAR route has the potential to provide the transportation sector for the foreseeable future, using the existing infrastructure. The rationale of using H(2) in the H(2)CAR process is explained by the significantly higher annualized average solar energy conversion efficiency for hydrogen generation versus that for biomass growth. For coal to liquids, the advantage of H(2)CAR is that there is no additional CO(2) release to the atmosphere due to the replacement of petroleum with coal, thus eliminating the need to sequester CO(2).

Fiber optic distributed chemical sensor for the real time detection of hydrocarbon fuel leaks

Science.gov (United States)

Mendoza, Edgar; Kempen, C.; Esterkin, Yan; Sun, Sunjian

2015-09-01

With the increase worldwide demand for hydrocarbon fuels and the vast development of new fuel production and delivery infrastructure installations around the world, there is a growing need for reliable hydrocarbon fuel leak detection technologies to provide safety and reduce environmental risks. Hydrocarbon leaks (gas or liquid) pose an extreme danger and need to be detected very quickly to avoid potential disasters. Gas leaks have the greatest potential for causing damage due to the explosion risk from the dispersion of gas clouds. This paper describes progress towards the development of a fast response, high sensitivity, distributed fiber optic fuel leak detection (HySense™) system based on the use of an optical fiber that uses a hydrocarbon sensitive fluorescent coating to detect the presence of fuel leaks present in close proximity along the length of the sensor fiber. The HySense™ system operates in two modes, leak detection and leak localization, and will trigger an alarm within seconds of exposure contact. The fast and accurate response of the sensor provides reliable fluid leak detection for pipelines, storage tanks, airports, pumps, and valves to detect and minimize any potential catastrophic damage.

A comparison of the C{sub 2}-C{sub 9} hydrocarbon compositions of vehicle fuels and urban air in Dublin, Ireland

Energy Technology Data Exchange (ETDEWEB)

Broderick, B M; Marnane, I S [Trinity College, Dublin (Ireland). Dept. of Civil, Structural and Environmental Engineering

2002-07-01

Hourly roadside hydrocarbon concentrations were measured over a six-week period at a heavily trafficked junction in Dublin city centre. Samples of ten typical leaded and unleaded petrol fuels used in Irish vehicles were also collected and their hydrocarbon compositions determined. The measured ambient hydrocarbon concentrations are presented, as are the properties of each of the analysed fuels. Comparison of the ambient hydrocarbon concentrations and the fuel hydrocarbon composition reveals a strong correlation for most hydrocarbons, except those compounds that were wholly combustion derived (i.e. not present in the fuel). Different characteristics were noted for aromatics, alkanes and alkenes. The comparison of roadside ambient air and fuel hydrocarbon content agrees well with other studies that have compared fuel content and exhaust composition. The relative impacts of exhaust and evaporative emissions on roadside hydrocarbon concentrations are apparent. (Author)

Reforming options for hydrogen production from fossil fuels for PEM fuel cells

Energy Technology Data Exchange (ETDEWEB)

Ersoz, Atilla; Olgun, Hayati [TUBITAK Marmara Research Center, Institute of Energy, Gebze, 41470 Kocaeli (Turkey); Ozdogan, Sibel [Marmara University Faculty of Engineering, Goztepe, 81040 Istanbul (Turkey)

2006-03-09

PEM fuel cell systems are considered as a sustainable option for the future transport sector in the future. There is great interest in converting current hydrocarbon based transportation fuels into hydrogen rich gases acceptable by PEM fuel cells on-board of vehicles. In this paper, we compare the results of our simulation studies for 100kW PEM fuel cell systems utilizing three different major reforming technologies, namely steam reforming (SREF), partial oxidation (POX) and autothermal reforming (ATR). Natural gas, gasoline and diesel are the selected hydrocarbon fuels. It is desired to investigate the effect of the selected fuel reforming options on the overall fuel cell system efficiency, which depends on the fuel processing, PEM fuel cell and auxiliary system efficiencies. The Aspen-HYSYS 3.1 code has been used for simulation purposes. Process parameters of fuel preparation steps have been determined considering the limitations set by the catalysts and hydrocarbons involved. Results indicate that fuel properties, fuel processing system and its operation parameters, and PEM fuel cell characteristics all affect the overall system efficiencies. Steam reforming appears as the most efficient fuel preparation option for all investigated fuels. Natural gas with steam reforming shows the highest fuel cell system efficiency. Good heat integration within the fuel cell system is absolutely necessary to achieve acceptable overall system efficiencies. (author)

Reforming options for hydrogen production from fossil fuels for PEM fuel cells

Science.gov (United States)

Ersoz, Atilla; Olgun, Hayati; Ozdogan, Sibel

PEM fuel cell systems are considered as a sustainable option for the future transport sector in the future. There is great interest in converting current hydrocarbon based transportation fuels into hydrogen rich gases acceptable by PEM fuel cells on-board of vehicles. In this paper, we compare the results of our simulation studies for 100 kW PEM fuel cell systems utilizing three different major reforming technologies, namely steam reforming (SREF), partial oxidation (POX) and autothermal reforming (ATR). Natural gas, gasoline and diesel are the selected hydrocarbon fuels. It is desired to investigate the effect of the selected fuel reforming options on the overall fuel cell system efficiency, which depends on the fuel processing, PEM fuel cell and auxiliary system efficiencies. The Aspen-HYSYS 3.1 code has been used for simulation purposes. Process parameters of fuel preparation steps have been determined considering the limitations set by the catalysts and hydrocarbons involved. Results indicate that fuel properties, fuel processing system and its operation parameters, and PEM fuel cell characteristics all affect the overall system efficiencies. Steam reforming appears as the most efficient fuel preparation option for all investigated fuels. Natural gas with steam reforming shows the highest fuel cell system efficiency. Good heat integration within the fuel cell system is absolutely necessary to achieve acceptable overall system efficiencies.

Chemical and toxicological characterization of exhaust emissions from alternative fuels for urban public transport

International Nuclear Information System (INIS)

Turrio Baldassarri, L.; Conti, R.; Crebelli, B.; Iamicelli, A.L.; De Berardis, M.; Gambino, A.L.; Iannaccone, S.

2008-01-01

The Istituto Superiore di Sanita (ISS, the National Institute of Health of Italy) and the Istituto dei Motori (IM) of the Consiglio Nazionale delle Ricerche (CNR, National Research Council) have carried out this study, jointly funded by the two institutes together with the Ministry of Environment. The chemical and toxicological characteristics of emissions from two urban bus engines were studied: a diesel engine fueled with both diesel oil and bio diesel blend and an equivalent spark-ignition one fuelled with compressed natural gas, operating in steady-state conditions. Regulated and unregulated pollutants, such as carcinogenic polycyclic aromatic hydrocarbons and nitrated derivatives, carbonyl compounds and light aromatic hydrocarbons were quantified. Mutagenicity of the emissions was evaluated by the Salmonella typhimurium/mammalian microsome assay. The effect of the fuels under study on the size distribution of particulate matter was also evaluated. The impact of diesel-powered transport on urban air quality, and the potential benefits for human health deriving from the use of natural gas for public transport, are discussed [it

Conversion of hydrocarbons in solid oxide fuel cells

DEFF Research Database (Denmark)

Mogensen, Mogens Bjerg; Kammer Hansen, K.

2003-01-01

Recently, a number of papers about direct oxidation of methane and hydrocarbon in solid oxide fuel cells (SOFC) at relatively low temperatures (about 700degreesC) have been published. Even though the conversion of almost dry CH4 at 1000degreesC on ceramic anodes was demonstrated more than 10 years...

Hydrocarbon fuel processing of micro solid oxide fuel cell systems[Dissertation 17455

Energy Technology Data Exchange (ETDEWEB)

Stutz, M. J.

2007-07-01

The scope of this thesis is the numerical and experimental investigation of the fuel processing of a micro solid oxide fuel cell (SOFC) running on hydrocarbon fuel. The goal is to enhance the overall system efficiency by optimization of the reforming process in the steady state and the improvement of the start-up process. Micro SOFC are a potential alternative to the currently used batteries in portable devices. Liquid butane in a cartridge could be the energy source. This dissertation is focused on the fuel processing of the system, namely the reforming and post-combusting processes. The reformer converts the hydrocarbon fuel to a hydrogen rich gas that can be utilized by the SOFC. The post-combustor depletes the toxic and/or explosive gases before leaving the exhaust. Chapter One presents a short introduction to the field of hydrocarbon fuel processing in micro solid oxide fuel cell systems, the next three chapters deal with computational modeling of the transport phenomena inside a micro-reformer, which leads to a better understanding of the chemistry and the physics therein, hence progress in the design and operation parameters. The experimental part (i.e. Chapter Five) of this thesis focuses on the feasibility of a novel hybrid start-up method of a fuel cell system that employs existing components as an additional heat source. In Chapter Two the effect of wall heat conduction on the syngas (hydrogen and carbon monoxide) production of a micro-reformer, representing micro-fabricated channels or monoliths, is investigated. Methane is used as a model hydrocarbon fuel since its heterogeneous reaction path on rhodium is known and validated. The simulations demonstrate that the axial wall conduction strongly influences the performance of the micro-reformer and should not be neglected without a careful a priori investigation of its impact. Methane conversion and hydrogen yield are strongly dependent of the wall inner surface temperature, which is influenced by the

A method of estimating the knock rating of hydrocarbon fuel blend

Science.gov (United States)

Sanders, Newell D

1943-01-01

The usefulness of the knock ratings of pure hydrocarbon compounds would be increased if some reliable method of calculating the knock ratings of fuel blends was known. The purpose of this study was to investigate the possibility of developing a method of predicting the knock ratings of fuel blends.

Horizontal arrangement of anodes of microbial fuel cells enhances remediation of petroleum hydrocarbon-contaminated soil.

Science.gov (United States)

Zhang, Yueyong; Wang, Xin; Li, Xiaojing; Cheng, Lijuan; Wan, Lili; Zhou, Qixing

2015-02-01

With the aim of in situ bioremediation of soil contaminated by hydrocarbons, anodes arranged with two different ways (horizontal or vertical) were compared in microbial fuel cells (MFCs). Charge outputs as high as 833 and 762C were achieved in reactors with anodes horizontally arranged (HA) and vertically arranged (VA). Up to 12.5 % of the total petroleum hydrocarbon (TPH) was removed in HA after 135 days, which was 50.6 % higher than that in VA (8.3 %) and 95.3 % higher than that in the disconnected control (6.4 %). Hydrocarbon fingerprint analysis showed that the degradation rates of both alkanes and polycyclic aromatic hydrocarbons (PAHs) in HA were higher than those in VA. Lower mass transport resistance in the HA than that of the VA seems to result in more power and more TPH degradation. Soil pH was increased from 8.26 to 9.12 in HA and from 8.26 to 8.64 in VA, whereas the conductivity was decreased from 1.99 to 1.54 mS/cm in HA and from 1.99 to 1.46 mS/cm in VA accompanied with the removal of TPH. Considering both enhanced biodegradation of hydrocarbon and generation of charge in HA, the MFC with anodes horizontally arranged is a promising configuration for future applications.

Transport of MOX fuel

International Nuclear Information System (INIS)

Porter, I.R.; Carr, M.

1997-01-01

The regulatory framework which governs the transport of MOX fuel is set out, including packages, transport modes and security requirements. Technical requirements for the packages are reviewed and BNFL's experience in plutonium and MOX fuel transport is described. The safety of such operations and the public perception of safety are described and the question of gaining public acceptance for MOX fuel transport is addressed. The paper concludes by emphasising the need for proactive programmes to improve the public acceptance of these operations. (Author)

Transportation of spent nuclear fuels

International Nuclear Information System (INIS)

Meguro, Toshiichi

1976-01-01

The spent nuclear fuel taken out of reactors is cooled in the cooling pool in each power station for a definite time, then transported to a reprocessing plant. At present, there is no reprocessing plant in Japan, therefore the spent nuclear fuel is shipped abroad. In this paper, the experiences and the present situation in Japan are described on the transport of the spent nuclear fuel from light water reactors, centering around the works in Tsuruga Power Station, Japan Atomic Power Co. The spent nuclear fuel in Tsuruga Power Station was first transported in Apr. 1973, and since then, about 36 tons were shipped to Britain by 5 times of transport. The reprocessing plant in Japan is expected to start operation in Apr. 1977, accordingly the spent nuclear fuel used for the trial will be transported in Japan in the latter half of this year. Among the permission and approval required for the transport of spent nuclear fuel, the acquisition of the certificate for transport casks and the approval of land and sea transports are main tasks. The relevant laws are the law concerning the regulations of nuclear raw material, nuclear fuel and reactors and the law concerning the safety of ships. The casks used in Tsuruga Power Station and EXL III type, and the charging of spent nuclear fuel, the decontamination of the casks, the leak test, land transport with a self-running vehicle, loading on board an exclusive carrier and sea transport are briefly explained. The casks and the ship for domestic transport are being prepared. (Kato, I.)

Fuels processing for transportation fuel cell systems

Science.gov (United States)

Kumar, R.; Ahmed, S.

Fuel cells primarily use hydrogen as the fuel. This hydrogen must be produced from other fuels such as natural gas or methanol. The fuel processor requirements are affected by the fuel to be converted, the type of fuel cell to be supplied, and the fuel cell application. The conventional fuel processing technology has been reexamined to determine how it must be adapted for use in demanding applications such as transportation. The two major fuel conversion processes are steam reforming and partial oxidation reforming. The former is established practice for stationary applications; the latter offers certain advantages for mobile systems and is presently in various stages of development. This paper discusses these fuel processing technologies and the more recent developments for fuel cell systems used in transportation. The need for new materials in fuels processing, particularly in the area of reforming catalysis and hydrogen purification, is discussed.

Electrode Design for Low Temperature Direct-Hydrocarbon Solid Oxide Fuel Cells

Science.gov (United States)

Chen, Fanglin (Inventor); Zhao, Fei (Inventor); Liu, Qiang (Inventor)

2015-01-01

In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

Electrode design for low temperature direct-hydrocarbon solid oxide fuel cells

Science.gov (United States)

Chen, Fanglin; Zhao, Fei; Liu, Qiang

2015-10-06

In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

Chemical storage of renewable electricity in hydrocarbon fuels via H{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Eilers, H.; Iglesias Gonzalez, M.; Schaub, G. [Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany). Engler-Bunte-Institute I

2012-07-01

The increased generation of renewable electricity leads to an increasing demand for storage due to its fluctuating production. Electrical energy can be stored as chemical energy carriers e.g. in form of H{sub 2} that can be further processed to hydrocarbons. Storage in form of hydrocarbons is advantageous compared to H{sub 2} storage since (i) a higher volumetric energy density in the product can be achieved and (ii) the infrastructure for hydrocarbon distribution, storage and utilization already exists. The present contribution introduces the potential of H{sub 2} integration in upgrading/production processes to hydrocarbon fuels, based on stoichiometry and kind of carbon feedstock. Processes include petroleum refining, vegetable oil hydrogenation, production of synfuel from lignocellulosic biomass and substitute natural gas from H{sub 2}/CO{sub 2}. In the case of fossil raw materials, yields per feedstock can be increased and fossil CO{sub 2} emissions decreased since fossil resources for H{sub 2} production can be avoided. In the case of biomass conversion to synfuels, product yields per biomass/hectare can be increased. If CO{sub 2} is hydrogenated to fuels, no gasification step is needed, however lower hydrocarbon product yields per H{sub 2} are achieved since CO{sub 2} has the highest oxygen content. (orig.)

Hydrocarbons and fuels analyses with the supersonic gas chromatography mass spectrometry--the novel concept of isomer abundance analysis.

Science.gov (United States)

Fialkov, Alexander B; Gordin, Alexander; Amirav, Aviv

2008-06-27

Hydrocarbon analysis with standard GC-MS is confronted by the limited range of volatile compounds amenable for analysis and by the similarity of electron ionization mass spectra for many compounds which show weak or no molecular ions for heavy hydrocarbons. The use of GC-MS with supersonic molecular beams (Supersonic GC-MS) significantly extends the range of heavy hydrocarbons that can be analyzed, and provides trustworthy enhanced molecular ion to all hydrocarbons. In addition, unique isomer mass spectral features are obtained in the ionization of vibrationally cold hydrocarbons. The availability of molecular ions for all hydrocarbons results in the ability to obtain unique chromatographic isomer distribution patterns that can serve as a new method for fuel characterization and identification. Examples of the applicability and use of this novel isomer abundance analysis (IAA) method to diesel fuel, kerosene and oil analyses are shown. It is suggested that in similarity to the "three ions method" for identification purposes, three isomer abundance patterns can serve for fuel characterization. The applications of the Supersonic GC-MS for engine motor oil analysis and transformer oil analysis are also demonstrated and discussed, including the capability to achieve fast 1-2s sampling without separation for oil and fuel fingerprinting. The relatively fast analysis of biodiesel is described, demonstrating the provision of molecular ions to heavy triglycerides. Isomer abundance analysis with the Supersonic GC-MS could find broad range of applications including petrochemicals and fuel analysis, arson analysis, environmental oil/fuel spill analysis, fuel adulteration analysis and motor oil analysis.

Transportation of nuclear fuel

International Nuclear Information System (INIS)

Prowse, D.R.

1979-01-01

Shipment of used fuel from nuclear reactors to a central fuel management facility is discussed with particular emphasis on the assessment of the risk to the public due to these shipments. The methods of transporting used fuel in large shipping containers is reviewed. In terms of an accident scenario, it is demonstrated that the primary risk of transport of used fuel is due to injury and death in common road accidents. The radiological nature of the used fuel cargo is, for all practical purposes, an insignificant factor in the total risk to the public. (author)

Physiological tolerance and stoichiometric potential of cyanobacteria for hydrocarbon fuel production

Czech Academy of Sciences Publication Activity Database

Kamarainen, J.; Knoop, H.; Stanford, N.; Guerrero, F.; Akhtar, M. K.; Aro, E. M.; Steuer, Ralf; Jones, P. R.

2012-01-01

Roč. 162, č. 1 (2012), s. 67-74 ISSN 0168-1656 Institutional support: RVO:67179843 Keywords : Cyanobacteria * Hydrocarbon * Fuel * Toxicity * Stoichiometric potential Subject RIV: EH - Ecology, Behaviour Impact factor: 3.183, year: 2012

Mathematical modelling on transport of petroleum hydrocarbons

Indian Academy of Sciences (India)

A brief theory has been included on the composition and transport of petroleum hydrocarbons following an onshore oil spill in order to demonstrate the level of complexity associated with the LNAPL dissolution mass transfer even in a classical porous medium. However, such studies in saturated fractured rocks are highly ...

Probability of spent fuel transportation accidents

International Nuclear Information System (INIS)

McClure, J.D.

1981-07-01

The transported volume of spent fuel, incident/accident experience and accident environment probabilities were reviewed in order to provide an estimate of spent fuel accident probabilities. In particular, the accident review assessed the accident experience for large casks of the type that could transport spent (irradiated) nuclear fuel. This review determined that since 1971, the beginning of official US Department of Transportation record keeping for accidents/incidents, there has been one spent fuel transportation accident. This information, coupled with estimated annual shipping volumes for spent fuel, indicated an estimated annual probability of a spent fuel transport accident of 5 x 10 -7 spent fuel accidents per mile. This is consistent with ordinary truck accident rates. A comparison of accident environments and regulatory test environments suggests that the probability of truck accidents exceeding regulatory test for impact is approximately 10 -9 /mile

European experience with spent fuel transport

International Nuclear Information System (INIS)

Hunter, I.A.

1995-01-01

Nuclear Transport Ltd has transported 5000 tonnes of spent fuel from 35 reactors in 8 European countries since 1972. Transport management is governed by the Quality Plan for: transport administration, packaging and shipment procedures at the shipping plant, operations at the power plant, and packaging and shipment organization at the power plant. Selection of a suitable carrier device is made with regard to the shipping plant requirements, physical limitations of the reactor, fuel characteristics, and transport route constraints. The transport plan is set up taking into account exploitation of the casks, reactor shut-down requirements, fuel acceptance plans at the reprocessing plant, and cask maintenance periods. A transport cycle involving spent fuel shipment to La Hague or to Sellafield takes typically two or four weeks, respectively. Most transports through Europe are by rail. A special-design railway ferry boat serves transports to the United Kingdom. Both wet or dry casks are employed. Modern casks are designed for high burnups and for oxide fuels. (J.B.)

Method of transporting fuel assemblies

International Nuclear Information System (INIS)

Okada, Katsutoshi.

1979-01-01

Purpose: To enable safety transportation of fuel assemblies for FBR type reactors by surrounding each of fuel elements in a wrapper tube by a rubbery, hollow cylindrical container and by sealing medium such as air to the inside of the container. Method: A fuel element is contained in a hollow cylindrical rubber-like tube. The fuel element has an upper end plug, a lower end plug and a wire spirally wound around the outer periphery. Upon transportation of the fuel assemblies, each of the fuel elements is covered with the container and arranged in the wrapper tube and then the fuel assemblies are assembled. Then, medium such as air is sealed for each of the fuel elements by way of an opening and then the opening is tightly closed. Before loading the transported fuel assemblies in the reactor, the medium is discharged through the opening and the container is completely extracted and removed from the inside of the wrapper tube. (Seki, T.)

MOX fuel transport: the French experience

International Nuclear Information System (INIS)

Sanchis, H.; Verdier, A.; Sanchis, H.

1999-01-01

In the back-end of the fuel cycle, several leading countries have chosen the Reprocessing, Conditioning, Recycling (RCR) option. Plutonium recycling in the form of MOX fuel is a mature industry, with successful operational experience and large-scale fabrication plants an several European countries. The COGEMA Group has developed the industrialized products to master the RCR operation including transport COGEMA subsidiary, TRANSNUCLEAIRE has been operating MOX fuel transports on an industrial scale for more than 10 years. In 1998, around 200 transports of Plutonium materials have been organised by TRANSNUCLEAIRE. These transports have been carried out by road between various facilities in Europe: reprocessing plants, manufacturing plants and power plants. The materials transported are either: PuO 2 and MOX powder; BWR and PWR MOX fuel rods; BWR and PWR MOX fuel assemblies. Because MOX fuel transport is subject to specific safety, security and fuel integrity requirements, the MOX fuel transport system implemented by TRANSNUCLEAIRE is fully dedicated. Packaging have been developed, licensed and manufactured for each kind of MOX material in compliance with relevant regulations. A fleet of vehicles qualified according to existing physical protection regulations is operated by TRANSNUCLEAIRE. TRANSNUCLEAIRE has gained a broad experience in MOX transport in 10 years. Technical and operational know-how has been developed and improved for each step: vehicles and packaging design and qualification; vehicle and packaging maintenance; transport operations. Further developments are underway to increase the payload of the packaging and to improve the transport conditions, safety and security remaining of course top priority. (authors)

SOLID FUEL OF HYDROCARBON, WOOD AND AGRICULTURAL WASTE FOR LOCAL HEAT SUPPLY SYSTEMS

Directory of Open Access Journals (Sweden)

B. M. Khroustalev

2017-01-01

Full Text Available In Belarus oil refining and oil producing industries are paid close attention. On the background of the active maintaining the level of oil processing and volume of oil extraction in our country and in the countries of the Eurasian Economic Union there is a steady formation of hydrocarbon-containing waste; therefore recycling of the latter is an urgent task to improve the competitiveness of production. The most cost-effective way of using hydrocarbon waste is the conversion of it into power resources. In this case it is possible to obtain significant power-saving and economic effect of the combined use of a hydrocarbon, wood, agricultural and other combustible waste, meanwhile improving the ecological situation at the sites of waste storage and creating a solid fuel with the necessary energy and specified physical-and-chemical properties. A comprehensive solution of a recycling problem makes it possible to use as energy resources a lot of waste that has not found application in other technologies, to produce alternative multi-component fuel which structure meets environmental and energy requirement for local heating systems. In addition, the implementation of such technology will make it possible to reduce power consumption of enterprises of various kinds that consume fuel and will also increase the share of local fuels in the energy balance of a particular region.

Transport of irradiated nuclear fuel

International Nuclear Information System (INIS)

1980-01-01

In response to public interest in the transport by rail through London of containers of irradiated fuel elements on their way from nuclear power stations to Windscale, the Central Electricity Generating Board and British Rail held three information meetings in London in January 1980. One meeting was for representatives of London Borough Councils and Members of Parliament with a known interest in the subject, and the others were for press, radio and television journalists. This booklet contains the main points made by the principal speakers from the CEGB and BR. (The points covered include: brief description of the fuel cycle; effect of the fission process in producing plutonium and fission products in the fuel element; fuel transport; the fuel flasks; protection against accidents; experience of transporting fuel). (U.K.)

Effect of turbulence models on predicting convective heat transfer to hydrocarbon fuel at supercritical pressure

Directory of Open Access Journals (Sweden)

Tao Zhi

2016-10-01

Full Text Available A variety of turbulence models were used to perform numerical simulations of heat transfer for hydrocarbon fuel flowing upward and downward through uniformly heated vertical pipes at supercritical pressure. Inlet temperatures varied from 373 K to 663 K, with heat flux ranging from 300 kW/m2 to 550 kW/m2. Comparative analyses between predicted and experimental results were used to evaluate the ability of turbulence models to respond to variable thermophysical properties of hydrocarbon fuel at supercritical pressure. It was found that the prediction performance of turbulence models is mainly determined by the damping function, which enables them to respond differently to local flow conditions. Although prediction accuracy for experimental results varied from condition to condition, the shear stress transport (SST and launder and sharma models performed better than all other models used in the study. For very small buoyancy-influenced runs, the thermal-induced acceleration due to variations in density lead to the impairment of heat transfer occurring in the vicinity of pseudo-critical points, and heat transfer was enhanced at higher temperatures through the combined action of four thermophysical properties: density, viscosity, thermal conductivity and specific heat. For very large buoyancy-influenced runs, the thermal-induced acceleration effect was over predicted by the LS and AB models.

Rationale for continuing R&D in direct coal conversion to produce high quality transportation fuels

Energy Technology Data Exchange (ETDEWEB)

Srivastava, R.D.; McIlvried, H.G. [Burns and Roe Services Corp., Pittsburgh, PA (United States); Gray, D. [Mitre Corp, McLean, VA (United States)] [and others

1995-12-31

For the foreseeable future, liquid hydrocarbon fuels will play a significant role in the transportation sector of both the United States and the world. Factors favoring these fuels include convenience, high energy density, and the vast existing infrastructure for their production and use. At present the U.S. consumes about 26% of the world supply of petroleum, but this situation is expected to change because of declining domestic production and increasing competition for imports from countries with developing economies. A scenario and time frame are developed in which declining world resources will generate a shortfall in petroleum supply that can be allieviated in part by utilizing the abundant domestic coal resource base. One option is direct coal conversion to liquid transportation fuels. Continued R&D in coal conversion technology will results in improved technical readiness that can significantly reduce costs so that synfuels can compete economically in a time frame to address the shortfall.

Spent fuels transportation coming from Australia

International Nuclear Information System (INIS)

2002-01-01

Maritime transportation of spent fuels from Australia to France fits into the contract between COGEMA and ANSTO, signed in 1999. This document proposes nine information cards in this domain: HIFAR a key tool of the nuclear, scientific and technological australian program; a presentation of the ANSTO Australian Nuclear Science and Technology Organization; the HIFAR spent fuel management problem; the COGEMA expertise in favor of the research reactor spent fuel; the spent fuel reprocessing at La Hague; the transports management; the transport safety (2 cards); the regulatory framework of the transports. (A.L.B.)

Self-potential and Complex Conductivity Monitoring of In Situ Hydrocarbon Remediation in Microbial Fuel Cell

Science.gov (United States)

Zhang, C.; Revil, A.; Ren, Z.; Karaoulis, M.; Mendonca, C. A.

2013-12-01

Petroleum hydrocarbon contamination of soil and groundwater in both non-aqueous phase liquid and dissolved forms generated from spills and leaks is a wide spread environmental issue. Traditional cleanup of hydrocarbon contamination in soils and ground water using physical, chemical, and biological remedial techniques is often expensive and ineffective. Recent studies show that the microbial fuel cell (MFC) can simultaneously enhance biodegradation of hydrocarbons in soil and groundwater and yield electricity. Non-invasive geophysical techniques such as self-potential (SP) and complex conductivity (induced polarization) have shown the potential to detect and characterize the nature of electron transport mechanism of in situ bioremediation of organic contamination plumes. In this study, we deployed both SP and complex conductivity in lab scale MFCs to monitor time-laps geophysical response of degradation of hydrocarbons by MFC. Two different sizes of MFC reactors were used in this study (DI=15 cm cylinder reactor and 94.5cm x 43.5 cm rectangle reactor), and the initial hydrocarbon concentration is 15 g diesel/kg soil. SP and complex conductivity measurements were measured using non-polarizing Ag/AgCl electrodes. Sensitivity study was also performed using COMSOL Multiphysics to test different electrode configurations. The SP measurements showed stronger anomalies adjacent to the MFC than locations afar, and both real and imaginary parts of complex conductivity are greater in areas close to MFC than areas further away and control samples without MFC. The joint use of SP and complex conductivity could in situ evaluate the dynamic changes of electrochemical parameters during this bioremediation process at spatiotemporal scales unachievable with traditional sampling methods. The joint inversion of these two methods to evaluate the efficiency of MFC enhanced hydrocarbon remediation in the subsurface.

Well-to-wheels analysis of fuel-cell vehicle/fuel systems

International Nuclear Information System (INIS)

Wang, M.

2002-01-01

Major automobile companies worldwide are undertaking vigorous research and development efforts aimed at developing fuel-cell vehicles (FCVs). Proton membrane exchange (PEM)-based FCVs require hydrogen (H(sub 2)) as the fuel-cell (FC) fuel. Because production and distribution infrastructure for H(sub 2) off board FCVs as a transportation fuel does not exist yet, researchers are developing FCVs that can use hydrocarbon fuels, such as methanol (MeOH) and gasoline, for onboard production of H(sub 2) via fuel processors. Direct H(sub 2) FCVs have no vehicular emissions, while FCVs powered by hydrocarbon fuels have near-zero emissions of criteria pollutants and some carbon dioxide (CO(sub 2)) emissions. However, production of H(sub 2) can generate a large amount of emissions and suffer significant energy losses. A complete evaluation of the energy and emission impacts of FCVs requires an analysis of energy use and emissions during all stages, from energy feedstock wells to vehicle wheels-a so-called ''well-to-wheels'' (WTW) analysis. This paper focuses on FCVs powered by several transportation fuels. Gasoline vehicles (GVs) equipped with internal combustion engines (ICEs) are the baseline technology to which FCVs are compared. Table 1 lists the 13 fuel pathways included in this study. Petroleum-to-gasoline (with 30-ppm sulfur[S] content) is the baseline fuel pathway for GVs

Solid fuel applications to transportation engines

Energy Technology Data Exchange (ETDEWEB)

Rentz, Richard L.; Renner, Roy A.

1980-06-01

The utilization of solid fuels as alternatives to liquid fuels for future transportation engines is reviewed. Alternative liquid fuels will not be addressed nor will petroleum/solid fuel blends except for the case of diesel engines. With respect to diesel engines, coal/oil mixtures will be addressed because of the high interest in this specific application as a result of the large number of diesel engines currently in transportation use. Final assessments refer to solid fuels only for diesel engines. The technical assessments of solid fuels utilization for transportation engines is summarized: solid fuel combustion in transportation engines is in a non-developed state; highway transportation is not amenable to solid fuels utilization due to severe environmental, packaging, control, and disposal problems; diesel and open-cycle gas turbines do not appear worthy of further development, although coal/oil mixtures for slow speed diesels may offer some promise as a transition technology; closed-cycle gas turbines show some promise for solid fuels utilization for limited applications as does the Stirling engine for use of cleaner solid fuels; Rankine cycle engines show good potential for limited applications, such as for locomotives and ships; and any development program will require large resources and sophisticated equipment in order to advance the state-of-the-art.

Combustion of High Molecular Weight Hydrocarbon Fuels and JP-8 at Moderate Pressures

Science.gov (United States)

2016-07-26

1. Introduction Fundamental knowledge of mechanisms of autoignition of condensed hydrocarbon fuels at elevated pressures is essential for accurate...particular JP-8) and surrogates of jet-fuels in laminar non-uniform flows at elevated pressures upto 2.5 MPa. Experimental and kinetic modeling studies...AGENCY NAME(S) AND ADDRESS (ES) U.S. Army Research Office P.O. Box 12211 Research Triangle Park, NC 27709-2211 Combustion, Jet Fuels, JP-8, Elevated

Laminar oxy-fuel diffusion flame supported by an oxygen-permeable-ion-transport membrane

KAUST Repository

Hong, Jongsup

2013-03-01

A numerical model with detailed gas-phase chemistry and transport was used to predict homogeneous fuel conversion processes and to capture the important features (e.g., the location, temperature, thickness and structure of a flame) of laminar oxy-fuel diffusion flames stabilized on the sweep side of an oxygen permeable ion transport membrane (ITM). We assume that the membrane surface is not catalytic to hydrocarbon or syngas oxidation. It has been demonstrated that an ITM can be used for hydrocarbon conversion with enhanced reaction selectivity such as oxy-fuel combustion for carbon capture technologies and syngas production. Within an ITM unit, the oxidizer flow rate, i.e., the oxygen permeation flux, is not a pre-determined quantity, since it depends on the oxygen partial pressures on the feed and sweep sides and the membrane temperature. Instead, it is influenced by the oxidation reactions that are also dependent on the oxygen permeation rate, the initial conditions of the sweep gas, i.e., the fuel concentration, flow rate and temperature, and the diluent. In oxy-fuel combustion applications, the sweep side is fuel-diluted with CO2, and the entire unit is preheated to achieve a high oxygen permeation flux. This study focuses on the flame structure under these conditions and specifically on the chemical effect of CO2 dilution. Results show that, when the fuel diluent is CO2, a diffusion flame with a lower temperature and a larger thickness is established in the vicinity of the membrane, in comparison with the case in which N2 is used as a diluent. Enhanced OH-driven reactions and suppressed H radical chemistry result in the formation of products with larger CO and H2O and smaller H2 concentrations. Moreover, radical concentrations are reduced due to the high CO2 fraction in the sweep gas. CO2 dilution reduces CH3 formation and slows down the formation of soot precursors, C2H2 and C2H4. The flame location impacts the species diffusion and heat transfer from the

Co-processing of standard gas oil and biocrude oil to hydrocarbon fuels

International Nuclear Information System (INIS)

Agblevor, Foster A.; Mante, O.; McClung, R.; Oyama, S.T.

2012-01-01

The major obstacle in thermochemical biomass conversion to hydrocarbon fuels using pyrolysis has been the high oxygen content and the poor stability of the product oils, which cause them to solidify during secondary processing. We have developed a fractional catalytic pyrolysis process to convert biomass feedstocks into a product termed “biocrude oils” (stable biomass pyrolysis oils) which are distinct from unstable conventional pyrolysis oils. The biocrude oils are stable, low viscosity liquids that are storable at ambient conditions without any significant increases in viscosity; distillable at both atmospheric pressure and under vacuum without char or solid formation. About 15 wt% biocrude oils containing 20–25% oxygen were blended with 85 wt% standard gas oil and co-cracked in an Advanced Catalyst Evaluation (ACE™) unit using fluid catalytic cracking (FCC) catalysts to produce hydrocarbon fuels that contain negligible amount of oxygen. For the same conversion of 70% for both the standard gas oil and the biocrude oil/gas oil blends, the product gasoline yield was 44 wt%, light cycle oil (LCO) 17 wt%, heavy cycle oil (HCO) 13 wt%, and liquefied petroleum gas (LPG) 16 wt%. However, the coke yield for the standard gas oil was 7.06 wt% compared to 6.64–6.81 wt% for the blends. There appeared to be hydrogen transfer from the cracking of the standard gas oil to the biocrude oil which subsequently eliminated the oxygen in the fuel without external hydrogen addition. We have demonstrated for the first time that biomass pyrolysis oils can be successfully converted into hydrocarbons without hydrogenation pretreatment. -- Highlights: ► The co-processed product had less than 1% oxygen content and contained biocarbons determined by 14 C analysis. ► The co-processing did not affect the yields of gasoline, LCO, and HCO. ► First demonstration of direct conversion of pyrolysis oils into drop-in hydrocarbon fuels.

Alternatives to traditional transportation fuels: An overview

Energy Technology Data Exchange (ETDEWEB)

1994-06-01

This report presents the first compilation by the Energy Information Administration (EIA) of information on alternatives to gasoline and diesel fuel. The purpose of the report is: (1) to provide background information on alternative transportation fuels and replacement fuels compared with gasoline and diesel fuel, and (2) to furnish preliminary estimates of alternative transportation fuels and alternative fueled vehicles as required by the Energy Policy Act of 1992 (EPACT), Title V, Section 503, ``Replacement Fuel Demand Estimates and Supply Information.`` Specifically, Section 503 requires the EIA to report annually on: (1) the number and type of alternative fueled vehicles in existence the previous year and expected to be in use the following year, (2) the geographic distribution of these vehicles, (3) the amounts and types of replacement fuels consumed, and (4) the greenhouse gas emissions likely to result from replacement fuel use. Alternative fueled vehicles are defined in this report as motorized vehicles licensed for on-road use, which may consume alternative transportation fuels. (Alternative fueled vehicles may use either an alternative transportation fuel or a replacement fuel.) The intended audience for the first section of this report includes the Secretary of Energy, the Congress, Federal and State agencies, the automobile manufacturing industry, the transportation fuel manufacturing and distribution industries, and the general public. The second section is designed primarily for persons desiring a more technical explanation of and background for the issues surrounding alternative transportation fuels.

Preliminary Economics for Hydrocarbon Fuel Production from Cellulosic Sugars

Energy Technology Data Exchange (ETDEWEB)

Collett, James R.; Meyer, Pimphan A.; Jones, Susanne B.

2014-05-18

Biorefinery process and economic models built in CHEMCAD and a preliminary, genome-scale metabolic model for the oleaginous yeast Lipomyces starkeyi were used to simulate the bioconversion of corn stover to lipids, and the upgrading of these hydrocarbon precursors to diesel and jet fuel. The metabolic model was based on the recently released genome sequence for L. starkeyi and on metabolic pathway information from the literature. The process model was based on bioconversion, lipid extraction, and lipid oil upgrading data found in literature, on new laboratory experimental data, and on yield predictions from the preliminary L. starkeyi metabolic model. The current plant gate production cost for a distillate-range hydrocarbon fuel was estimated by the process model Base Case to be $9.5/gallon ($9.0 /gallon of gasoline equivalent) with assumptions of 2011$, 10% internal return on investment, and 2205 ton/day dry feed rate. Opportunities for reducing the cost to below $5.0/gallon, such as improving bioconversion lipid yield and hydrogenation catalyst selectivity, are presented in a Target Case. The process and economic models developed for this work will be updated in 2014 with new experimental data and predictions from a refined metabolic network model for L. starkeyi. Attaining a production cost of $3.0/gallon will require finding higher value uses for lignin other than power generation, such as conversion to additional fuel or to a co-product.

Fuel element transport container

International Nuclear Information System (INIS)

Benna, P.; Neuenfeldt, W.

1979-01-01

The reprocessing system includes a large number of waterfilled ponds next to each other for the intermediate storage of fuel elements from LWR's. The fuel element transport device is allocated to a middle pond. The individual ponds are separated from each other by walls, and are only accessible from the middle pond via narrow passages. The transport device includes a telescopic running rail for a trolley with a grab device for the fuel element. The running rail is supported in turn by a second trolley, which can be moved by wheels on rails. Part of the drive of the first trolley is arranged on the second one. Using this transport device, adjacent ponds can be served through the passage openings. (DG) [de

Microbial activities in hydrocarbon-laden wastewaters: Impact on diesel fuel stability and the biocorrosion of carbon steel.

Science.gov (United States)

Liang, Renxing; Duncan, Kathleen E; Le Borgne, Sylvie; Davidova, Irene; Yakimov, Michail M; Suflita, Joseph M

2017-08-20

Anaerobic hydrocarbon biodegradation not only diminishes fuel quality, but also exacerbates the biocorrosion of the metallic infrastructure. While successional events in marine microbial ecosystems impacted by petroleum are well documented, far less is known about the response of communities chronically exposed to hydrocarbons. Shipboard oily wastewater was used to assess the biotransformation of different diesel fuels and their propensity to impact carbon steel corrosion. When amended with sulfate and an F76 military diesel fuel, the sulfate removal rate in the assay mixtures was elevated (26.8μM/d) relative to incubations receiving a hydroprocessed biofuel (16.1μM/d) or a fuel-unamended control (17.8μM/d). Microbial community analysis revealed the predominance of Anaerolineae and Deltaproteobacteria in F76-amended incubations, in contrast to the Beta- and Gammaproteobacteria in the original wastewater. The dominant Smithella-like sequences suggested the potential for syntrophic hydrocarbon metabolism. The general corrosion rate was relatively low (0.83 - 1.29±0.12mpy) and independent of the particular fuel, but pitting corrosion was more pronounced in F76-amended incubations. Desulfovibrionaceae constituted 50-77% of the sessile organisms on carbon steel coupons. Thus, chronically exposed microflora in oily wastewater were differentially acclimated to the syntrophic metabolism of traditional hydrocarbons but tended to resist isoalkane-laden biofuels. Copyright © 2017 Elsevier B.V. All rights reserved.

Recycling Carbon Dioxide into Sustainable Hydrocarbon Fuels: Electrolysis of Carbon Dioxide and Water

Science.gov (United States)

Graves, Christopher Ronald

Great quantities of hydrocarbon fuels will be needed for the foreseeable future, even if electricity based energy carriers begin to partially replace liquid hydrocarbons in the transportation sector. Fossil fuels and biomass are the most common feedstocks for production of hydrocarbon fuels. However, using renewable or nuclear energy, carbon dioxide and water can be recycled into sustainable hydrocarbon fuels in non-biological processes which remove oxygen from CO2 and H2O (the reverse of fuel combustion). Capture of CO2 from the atmosphere would enable a closed-loop carbon-neutral fuel cycle. The purpose of this work was to develop critical components of a system that recycles CO2 into liquid hydrocarbon fuels. The concept is examined at several scales, beginning with a broad scope analysis of large-scale sustainable energy systems and ultimately studying electrolysis of CO 2 and H2O in high temperature solid oxide cells as the heart of the energy conversion, in the form of three experimental studies. The contributions of these studies include discoveries about electrochemistry and materials that could significantly improve the overall energy use and economics of the CO2-to-fuels system. The broad scale study begins by assessing the sustainability and practicality of the various energy carriers that could replace petroleum-derived hydrocarbon fuels, including other hydrocarbons, hydrogen, and storage of electricity on-board vehicles in batteries, ultracapacitors, and flywheels. Any energy carrier can store the energy of any energy source. This sets the context for CO2 recycling -- sustainable energy sources like solar and wind power can be used to provide the most energy-dense, convenient fuels which can be readily used in the existing infrastructure. The many ways to recycle CO2 into hydrocarbons, based on thermolysis, thermochemical loops, electrolysis, and photoelectrolysis of CO2 and/or H 2O, are critically reviewed. A process based on high temperature co

Transportation of irradiated fuel elements

International Nuclear Information System (INIS)

1980-01-01

A critique is presented of current methods of transporting spent nuclear fuel and the inadequacies of the associated contingency plans, with particular reference to the transportation of irradiated fuel through London. Anti-nuclear and pro-nuclear arguments are presented on a number of factors, including tests on flasks, levels of radiation exposure, routine transport arrangements and contingency arrangements. (U.K.)

Assessing fuel spill risks in polar waters: Temporal dynamics and behaviour of hydrocarbons from Antarctic diesel, marine gas oil and residual fuel oil.

Science.gov (United States)

Brown, Kathryn E; King, Catherine K; Kotzakoulakis, Konstantinos; George, Simon C; Harrison, Peter L

2016-09-15

As part of risk assessment of fuel oil spills in Antarctic and subantarctic waters, this study describes partitioning of hydrocarbons from three fuels (Special Antarctic Blend diesel, SAB; marine gas oil, MGO; and intermediate grade fuel oil, IFO 180) into seawater at 0 and 5°C and subsequent depletion over 7days. Initial total hydrocarbon content (THC) of water accommodated fraction (WAF) in seawater was highest for SAB. Rates of THC loss and proportions in equivalent carbon number fractions differed between fuels and over time. THC was most persistent in IFO 180 WAFs and most rapidly depleted in MGO WAF, with depletion for SAB WAF strongly affected by temperature. Concentration and composition remained proportionate in dilution series over time. This study significantly enhances our understanding of fuel behaviour in Antarctic and subantarctic waters, enabling improved predictions for estimates of sensitivities of marine organisms to toxic contaminants from fuels in the region. Copyright © 2016 Elsevier Ltd. All rights reserved.

Jet-Fuel Range Hydrocarbons from Biomass-Derived Sorbitol over Ni-HZSM-5/SBA-15 Catalyst

Directory of Open Access Journals (Sweden)

Yujing Weng

2015-12-01

Full Text Available Aromatics and cyclic-hydrocarbons are the significant components of jet fuel with high energy-density. However, conventional technologies for bio-fuel production cannot produce these products without further aromatization and isomerization. In this work, renewable liquid fuel with high content of aromatics and cyclic-hydrocarbons was obtained through aqueous catalytic conversion of biomass sorbitol over Ni-HZSM-5/SBA-15 catalyst. Texture characteristics of the catalyst were determined by physisorption of N2, which indicated its bimodal pore structures were microporous (HZSM-5, pore width: 0.56 nm and mesoporous (SBA-15, pore width: 8 nm. The surface acidity included weak and strong acid sites, predominantly Lewis type, and was further confirmed by the NH3-TPD and Py-IR analysis. The catalytic performances were tested in a fixed-bed reactor under the conditions of 593 K, WHSV of 0.75 h−1, GHSV of 2500 h−1 and 4.0 MPa of hydrogen pressure, whereby oil yield of 40.4 wt. % with aromatics and cyclic-hydrocarbons content of 80.0% was obtained.

Alternatives to traditional transportation fuels 1993

Energy Technology Data Exchange (ETDEWEB)

1995-01-01

In recent years, gasoline and diesel fuel have accounted for about 80 percent of total transportation fuel and nearly all of the fuel used in on-road vehicles. Growing concerns about the environmental effects of fossil fuel use and the Nation`s high level of dependence on foreign oil are providing impetus for the development of replacements or alternatives for these traditional transportation fuels. (The Energy Policy Act of 1992 definitions of {open_quotes}replacement{close_quotes} and {open_quotes}alternative{close_quotes} fuels are presented in the following box.) The Alternative Motor Fuels Act of 1988, the Clean Air Act Amendments of 1990 (CAAA90) and the Energy Policy Act of 1992 (EPACT) are significant legislative forces behind the growth of replacement fuel use. Alternatives to Traditional Transportation Fuels 1993 provides the number of on-road alternative fueled vehicles in use in the United States, alternative and replacement fuel consumption, and information on greenhouse gas emissions resulting from the production, delivery, and use of replacement fuels for 1992, 1993, and 1995.

A reaction mechanism for gasoline surrogate fuels for large polycyclic aromatic hydrocarbons

KAUST Repository

Raj, Abhijeet; Charry Prada, Iran David; Amer, Ahmad Amer; Chung, Suk-Ho

2012-01-01

This work aims to develop a reaction mechanism for gasoline surrogate fuels (n-heptane, iso-octane and toluene) with an emphasis on the formation of large polycyclic aromatic hydrocarbons (PAHs). Starting from an existing base mechanism for gasoline

Process and catalysts for hydrocarbon conversion. [high antiknock motor fuel

Energy Technology Data Exchange (ETDEWEB)

1940-02-14

High anti-knock motor fuel is produced from hydrocarbons by subjecting it at an elevated temperature to contact with a calcined mixture of hydrated silica, hydrated alumina, and hydrated zirconia, substantially free from alkali metal compounds. The catalyst may be prepared by precipitating silica gel by the acidification of an aqueous solution of an alkali metal silicate, intimately mixing hydrated alumina and hydrated zirconia therewith, drying, purifying the composite to substantially remove alkali metal compounds, again drying, forming the dried material into particles, and finally calcining. The resultant conversion products may be fractionated to produce gasoline, hydrocarbon oil above gasoling boiling point range, and a gaseous fraction of olefins which are polymerized into gasoline boiling range polymers.

Spent fuel transportation problems

International Nuclear Information System (INIS)

Kondrat'ev, A.N.; Kosarev, Yu.A.; Yulikov, E.A.

1977-01-01

In this paper, problems of transportation of nuclear spent fuel to reprocessing plants are discussed. The solutions proposed are directed toward the achievement of the transportation as economic and safe as possible. The increase of the nuclear power plants number in the USSR and the great distances between these plants and the reprocessing plants involve an intensification of the spent fuel transportation. Higher burnup and holdup time reduction cause the necessity of more bulky casks. In this connection, the economic problems become still more important. One of the ways of the problem solution is the development of rational and cheap cask designs. Also, the enforcement in the world of the environmental and personnel health protection requires to increase the transportation reliability and safety. The paper summarizes safe transportation rules with clarifying the following questions: the increase of the transport unit quantity of the spent fuel; rational shipment organization that minimizes vehicle turnover cycle duration; development of the reliable calculation methods to determine strength, thermal conditions and nuclear safety of transport packaging as applied to the vehicles of high capacity; maximum unification of vehicles, calculation methods and documents; and cask testing on models and in pilot scale on specific test rigs to assure that they meet the international safe fuel shipment rules. Besides, some considerations on the choice and use of structural materials for casks are given, and problems of manufacturing such casks from uranium and lead are considered, as well as problems of the development of fireproof shells, control instrumentation, vehicles decontamination, etc. All the problems are considered from the point of view of normal and accidental shipment conditions. Conclusions are presented [ru

Sustainable hydrocarbon fuels by recycling CO2 and H2O with renewable or nuclear energy

DEFF Research Database (Denmark)

Graves, Christopher R.; Ebbesen, Sune; Mogensen, Mogens Bjerg

2011-01-01

) and biofuels have received the most attention, similar hydrocarbons can be produced without using fossil fuels or biomass. Using renewable and/or nuclear energy, carbon dioxide and water can be recycled into liquid hydrocarbon fuels in non-biological processes which remove oxygen from CO2 and H2O (the reverse...... of fuel combustion). Capture of CO2 from the atmosphere would enable a closed-loop carbon-neutral fuel cycle. This article critically reviews the many possible technological pathways for recycling CO2 into fuels using renewable or nuclear energy, considering three stages—CO2 capture, H2O and CO2...... by Fischer–Tropsch synthesis is identified as one of the most promising, feasible routes. An analysis of the energy balance and economics of this CO2 recycling process is presented. We estimate that the full system can feasibly operate at 70% electricity-to-liquid fuel efficiency (higher heating value basis...

C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

Energy Technology Data Exchange (ETDEWEB)

Gerald P. Huffman

2003-09-30

The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. These feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. Some highlights of the results obtained during the first year of the current research contract are summarized as: (1) Terminal alkynes are an effective chain initiator for Fischer-Tropsch (FT) reactions, producing normal paraffins with C numbers {ge} to that of the added alkyne. (2) Significant improvement in the product distribution towards heavier hydrocarbons (C{sub 5} to C{sub 19}) was achieved in supercritical fluid (SCF) FT reactions compared to that of gas-phase reactions. (3) Xerogel and aerogel silica supported cobalt catalysts were successfully employed for FT synthesis. Selectivity for diesel range products increased with increasing Co content. (4) Silicoaluminophosphate (SAPO) molecular sieve catalysts have been developed for methanol to olefin conversion, producing value-added products such as ethylene and propylene. (5) Hybrid Pt-promoted tungstated and sulfated zirconia catalysts are very effective in cracking n-C{sub 36} to jet and diesel fuel; these catalysts will be tested for cracking of FT wax. (6) Methane, ethane, and propane are readily decomposed to pure

CNG: a potential transport fuel

International Nuclear Information System (INIS)

Anon.

1992-01-01

Compressed Natural Gas (CNG) is an alternative transport fuel. Advantages of its use are briefly described. Infra structural requirements, if it is to be used in India are outlined. Applications of CNG as transport fuel for buses and trucks in India are discussed. (P.R.K.). 5 refs

Safety risks of hydrogen fuel for applications in transportation vehicles.

Science.gov (United States)

2009-04-01

Combustion of hydrocarbon fuels in many practical applications produces pollutants that are harmful to human health and environment. Hydrogen fuel is considered to be a potential answer to the clean energy demands, especially with the advances in fue...

Intermodal transportation of spent fuel

International Nuclear Information System (INIS)

Elder, H.K.

1983-09-01

Concepts for transportation of spent fuel in rail casks from nuclear power plant sites with no rail service are under consideration by the US Department of Energy in the Commercial Spent Fuel Management program at the Pacific Northwest Laboratory. This report identifies and evaluates three alternative systems for intermodal transfer of spent fuel: heavy-haul truck to rail, barge to rail, and barge to heavy-haul truck. This report concludes that, with some modifications and provisions for new equipment, existing rail and marine systems can provide a transportation base for the intermodal transfer of spent fuel to federal interim storage facilities. Some needed land transportation support and loading and unloading equipment does not currently exist. There are insufficient shipping casks available at this time, but the industrial capability to meet projected needs appears adequate

Study utilization of extractable petroleum hydrocarbons biodegradation waste as the main material for making solid fuels

Science.gov (United States)

Hendrianie, Nuniek; Juliastuti, Sri Rachmania; Ar-rosyidah, Fanny Husna; Rochman, Hilal Abdur

2017-05-01

Nowadays the existence of energy sources of oil and was limited. Therefore, it was important to searching for new innovations of renewable energy sources by utilizing the waste into a source of energy. On the other hand, the process of extractable petroleum hydrocarbons biodegradation generated sludge that had calorific value and untapped. Because of the need for alternative sources of energy innovation with the concept of zero waste and the fuel potential from extractable petroleum hydrocarbons biodegradation waste, so it was necessary to study the use of extractable petroleum hydrocarbons biodegradation waste as the main material for making solid fuel. In addition, sawdust is a waste that had a great quantities and also had a high calorific value to be mixed with extractable petroleum hydrocarbons biodegradation waste. The purpose of this study was to determine the characteristics of the extractable petroleum hydrocarbons biodegradation waste and to determine the potential and a combination of a mixture of extractable petroleum hydrocarbons biodegradation waste and sawdust which has the best calorific value. The variables of this study was the composition of the waste and sawdust as follows 1:1; 1:3; and 3:1 (mass of sawdust : mass of waste) and time of sawdust carbonization was 10, 15 and 20 minutes. Sawdust was carbonized to get the high heating value. The characteristic of main material and fuel analysis performed with proximate analysis. While the calorific value analysis was performed with a bomb calorimeter. From the research, it was known that extractable petroleum hydrocarbons biodegradation waste had a moisture content of 3.06%; volatile matter 19.98%; ash content of 0.56%; fixed carbon content of 76.4% and a calorific value of 717 cal/gram. And a mixture that had the highest calorific value (4286.5 cal/gram) achieved in comparison sawdust : waste (3:1) by carbonization of sawdust for 20 minutes.

Transport and deposition of injected hydrocarbons in plasma generator PSI-2

International Nuclear Information System (INIS)

Bohmeyer, W.; Naujoks, D.; Markin, A.; Arkhipov, I.; Koch, B.; Schroeder, D.; Fussmann, G.

2005-01-01

The transport and deposition of hydrocarbons were studied in the stationary plasma of plasma generator PSI-2. CH 4 or C 2 H 4 were injected into the plasma at different positions in the target chamber. After an interaction between the plasma and the hydrocarbons, different species are produced, some of them having high sticking probabilities and forming a:CH films on a temperature controlled collector. The film growth is studied in situ for different plasma parameters. The 3D Monte Carlo code ERO including three different sets of atomic data is used to describe the formation of hydrocarbon films

Standard casks for the transport of LWR spent fuel. Storage/transport casks for long cooled spent fuel

International Nuclear Information System (INIS)

Blum, P.; Sert, G.; Gagnon, R.

1983-01-01

During the past decade, TRANSNUCLEAIRE has developed, licensed and marketed a family of standard casks for the transport of spent fuel from LWR reactors to reprocessing plants and the ancillary equipments necessary for their operation and transport. A large number of these casks are presently used for European and intercontinental transports and manufactured under TRANSNUCLEAIRE supervision in different countries. The main advantages of these casks are: - large payload for considered modes of transport, - moderate cost, - reliability due to the large experience gained by TRANSNUCLEAIRE as concerns fabrication and operation problems, - standardization faciliting fabrication, operation and spare part supply. Recently, TRANSNUCLEAIRE also developed a new generation of casks for the dry storage and occasional transport of LWR spent fuel which has been cooled for 5 years or 7 years in case of consolidated fuel rods. These casks have an optimum payload which takes into account the shielding requirements and the weight limitations at most sites. This paper deals more particularly with the TN 24 model which exists in 4 versions among which one for 24 PWR 900 fuel assemblies and another one for the consolidated fuel rods from 48 of same fuel assemblies

Cost reductions of fuel cells for transport applications: fuel processing options

Energy Technology Data Exchange (ETDEWEB)

Teagan, W P; Bentley, J; Barnett, B [Arthur D. Little, Inc., Cambridge, MA (United States)

1998-03-15

The highly favorable efficiency/environmental characteristics of fuel cell technologies have now been verified by virtue of recent and ongoing field experience. The key issue regarding the timing and extent of fuel cell commercialization is the ability to reduce costs to acceptable levels in both stationary and transport applications. It is increasingly recognized that the fuel processing subsystem can have a major impact on overall system costs, particularly as ongoing R and D efforts result in reduction of the basic cost structure of stacks which currently dominate system costs. The fuel processing subsystem for polymer electrolyte membrane fuel cell (PEMFC) technology, which is the focus of transport applications, includes the reformer, shift reactors, and means for CO reduction. In addition to low cost, transport applications require a fuel processor that is compact and can start rapidly. This paper describes the impact of factors such as fuel choice operating temperature, material selection, catalyst requirements, and controls on the cost of fuel processing systems. There are fuel processor technology paths which manufacturing cost analyses indicate are consistent with fuel processor subsystem costs of under $150/kW in stationary applications and $30/kW in transport applications. As such, the costs of mature fuel processing subsystem technologies should be consistent with their use in commercially viable fuel cell systems in both application categories. (orig.)

Transport and reprocessing of irradiated nuclear fuel

International Nuclear Information System (INIS)

Lenail, B.

1981-01-01

This contribution deals with transport and packaging of oxide fuel from and to the Cogema reprocessing plant at La Hague (France). After a general discussion of nuclear fuel and the fuel cycle, the main aspects of transport and reprocessing of oxide fuel are analysed. (Auth.)

Fuel cell water transport

Science.gov (United States)

Vanderborgh, Nicholas E.; Hedstrom, James C.

1990-01-01

The moisture content and temperature of hydrogen and oxygen gases is regulated throughout traverse of the gases in a fuel cell incorporating a solid polymer membrane. At least one of the gases traverses a first flow field adjacent the solid polymer membrane, where chemical reactions occur to generate an electrical current. A second flow field is located sequential with the first flow field and incorporates a membrane for effective water transport. A control fluid is then circulated adjacent the second membrane on the face opposite the fuel cell gas wherein moisture is either transported from the control fluid to humidify a fuel gas, e.g., hydrogen, or to the control fluid to prevent excess water buildup in the oxidizer gas, e.g., oxygen. Evaporation of water into the control gas and the control gas temperature act to control the fuel cell gas temperatures throughout the traverse of the fuel cell by the gases.

Estimating road transport fuel consumption in Ecuador

International Nuclear Information System (INIS)

Sierra, Jaime Cevallos

2016-01-01

Road transport is one of the sectors with highest energy consumptions in the planet, with large dependence of fossil fuels, and contribution for global greenhouse gas emissions. Although, Latin America is not a high-energy consumer, its share in global consumption is expected to grow, especially in the transportation sector. This make essential for developing countries the adoption of better policies to identify the vehicle groups with largest fuel demands. The present study describes the VKT technique to disaggregate road transport energy consumption by vehicle type, applied to the road transportation system of Ecuador. It also describes the procedures performed to estimate the variables required to run the model, and some of the practical applications that be used to create public policies. Results show as the biggest fuel consumers the heavy-duty freight cargo, followed by light duty vehicles. The estimation of greenhouse gas emissions evidence that road transport released 14.3 million tons of CO_2 in 2012. When fuel consumption is compared by it costs, it can be confirmed that Ecuadorean Government covered, through subsidies, for 68% of the annual fuel costs of national road transport, demonstrating the importance of restructuring these expenditures in order to achieve an efficient road transport system. - Highlights: •The vehicle-kilometers traveled has been estimated from local info. •The fuel economy has been calculated from national and international data. •The groups with higher fuel consumption has been located. •The fuel-type dependency has been estimated for each vehicle group. •Greenhouse gas emission, and fuel costs, has been estimated for local road transport.

High quality transportation fuels from renewable feedstock

Energy Technology Data Exchange (ETDEWEB)

Lindfors, Lars Peter

2010-09-15

Hydrotreating of vegetable oils is novel process for producing high quality renewable diesel. Hydrotreated vegetable oils (HVO) are paraffinic hydrocarbons. They are free of aromatics, have high cetane numbers and reduce emissions. HVO can be used as component or as such. HVO processes can also be modified to produce jet fuel. GHG savings by HVO use are significant compared to fossil fuels. HVO is already in commercial production. Neste Oil is producing its NExBTL diesel in two plants. Production of renewable fuels will be limited by availability of sustainable feedstock. Therefore R and D efforts are made to expand feedstock base further.

Methods of producing transportation fuel

Science.gov (United States)

Nair, Vijay [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Cherrillo, Ralph Anthony [Houston, TX; Bauldreay, Joanna M [Chester, GB

2011-12-27

Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing transportation fuel is described herein. The method for producing transportation fuel may include providing formation fluid having a boiling range distribution between -5.degree. C. and 350.degree. C. from a subsurface in situ heat treatment process to a subsurface treatment facility. A liquid stream may be separated from the formation fluid. The separated liquid stream may be hydrotreated and then distilled to produce a distilled stream having a boiling range distribution between 150.degree. C. and 350.degree. C. The distilled liquid stream may be combined with one or more additives to produce transportation fuel.

Transport of MOX fuel from Europe to Japan

International Nuclear Information System (INIS)

2002-01-01

The MOX fuel transports from Europe to Japan represent a main part in the implementing of the Japan nuclear program. They complement the 160 transports of spent fuels realized from Japan to Europe and the vitrified residues return from France to Japan. In this framework the document presents the MOX fuel, the use of the MOX fuel in reactor, the proliferation risks, the MOX fuel transport to Japan, the public health, the transport regulations, the safety and the civil liability. (A.L.B.)

Hydrocarbon Biocomponents use in Aviation Fuels - Preliminary Analysis of Issues

Directory of Open Access Journals (Sweden)

Gawron Bartosz

2015-01-01

Full Text Available Article is related to the aspect of the introduction of biofuels to power turbine aircraft engines. The paper presents the current trends in the use of alternative fuels in aviation and the problems connected with the introduction of hydrocarbon biocomponents. It is pointed to the need to take research and implementation works in the field of the subject, also in Poland.

Spent fuel transport in fuel cycle

International Nuclear Information System (INIS)

Labrousse, M.

1977-01-01

The transport of radioactive substances is a minor part of the fuel cycle because the quantities of matter involved are very small. However the length and complexity of the cycle, the weight of the packing, the respective distances between stations, enrichment plants and reprocessing plants are such that the problem is not negligible. In addition these transports have considerable psychological importance. The most interesting is spent fuel transport which requires exceptionally efficient packaging, especially where thermal and mechanical resistance are concerned. To meet the safety criteria necessary for the protection of both public and users it was decided to use the maximum capacity consistent with rail transport and to avoid coolant fluids under pressure. Since no single type of packing is suitable for all existing stations an effort has been made to standardise handling accessories, and future trands are towards maximum automation. A discussion on the various technical solutions available for the construction of these packing systems is followed by a description of those used for the two types of packaging ordered by COGEMA [fr

Interactions between oxygen permeation and homogeneous-phase fuel conversion on the sweep side of an ion transport membrane

KAUST Repository

Hong, Jongsup

2013-02-01

The interactions between oxygen permeation and homogeneous fuel oxidation reactions on the sweep side of an ion transport membrane (ITM) are examined using a comprehensive model, which couples the dependency of the oxygen permeation rate on the membrane surface conditions and detailed chemistry and transport in the vicinity of the membrane. We assume that the membrane surface is not catalytic to hydrocarbon or syngas oxidation. Results show that increasing the sweep gas inlet temperature and fuel concentration enhances oxygen permeation substantially. This is accomplished through promoting oxidation reactions (oxygen consumption) and the transport of the products and reaction heat towards the membrane, which lowers the oxygen concentration and increases the gas temperature near the membrane. Faster reactions at higher fuel concentration and higher inlet gas temperature support substantial fuel conversion and lead to a higher oxygen permeation flux without the contribution of surface catalytic activity. Beyond a certain maximum in the fuel concentration, extensive heat loss to the membrane (and feed side) reduces the oxidation kinetic rates and limits oxygen permeation as the reaction front reaches the membrane. The sweep gas flow rate and channel height have moderate impacts on oxygen permeation and fuel conversion due to the residence time requirements for the chemical reactions and the location of the reaction zone relative to the membrane surface. © 2012 Elsevier B.V.

Improvement on performance and efficiency of direct methanol fuel cells using hydrocarbon-based membrane electrode assembly

International Nuclear Information System (INIS)

Kim, Joon-Hee; Yang, Min-Jee; Park, Jun-Young

2014-01-01

Highlights: • Faradaic efficiency and water transfer coefficient (WTC) of DMFC MEAs are calculated based on mass balance measurements. • Faradaic efficiency of the HC-based MEAs is generally improved over the Nafion-based MEAs. • Nafion-based MEAs show a WTC of 3, whereas the HC-based MEAs show a very low WTC of -2. • Low WTC of the HC-based MEAs indicates the back-diffusion of water from the cathode to the anode. • Performance of HC-based MEAs is improved as the fuel stoichiometry increases, maintaining high Faradaic efficiency. - Abstract: In order to improve the energy efficiency (fuel efficiency and electrical power) of direct methanol fuel cells (DMFCs), the hydrocarbon (HC) membrane-based membrane electrode assemblies (MEAs) are investigated under various operating conditions. The MEAs are then compared with the conventional Nafion-based MEA in terms of their efficiency and performance. The Faradaic efficiency and water transfer coefficient (WTC) are calculated based on mass balance measurements. The Faradaic efficiency of the HC-based MEAs is improved over the Nafion-based MEAs since methanol crossover decreased. The performance of HC-based MEAs shows strong dependency on the anode stoichiometry at high current densities probably because of the limited mass transport of fuel, which is not observed for the Nafion-based MEAs. The Nafion-based MEAs show a WTC of 3, whereas the HC-based MEAs show a very low WTC of −2, indicating the back-diffusion of water from the cathode to the anode. This may have limited mass transport by interrupting proton conduction at high current densities. The performance of HC-based MEAs at high current densities is improved as the fuel stoichiometry increases; High Faradaic efficiency is maintained by decreasing the cathode stoichiometry

Method of Generating Hydrocarbon Reagents from Diesel, Natural Gas and Other Logistical Fuels

Science.gov (United States)

Herling, Darrell R [Richland, WA; Aardahl, Chris L [Richland, WA; Rozmiarek, Robert T [Middleton, WI; Rappe, Kenneth G [Richland, WA; Wang, Yong [Richland, WA; Holladay, Jamelyn D [Kennewick, WA

2008-10-14

The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

Sustainable fuel for the transportation sector

Science.gov (United States)

Agrawal, Rakesh; Singh, Navneet R.; Ribeiro, Fabio H.; Delgass, W. Nicholas

2007-01-01

A hybrid hydrogen-carbon (H2CAR) process for the production of liquid hydrocarbon fuels is proposed wherein biomass is the carbon source and hydrogen is supplied from carbon-free energy. To implement this concept, a process has been designed to co-feed a biomass gasifier with H2 and CO2 recycled from the H2-CO to liquid conversion reactor. Modeling of this biomass to liquids process has identified several major advantages of the H2CAR process. (i) The land area needed to grow the biomass is CAR process shows the potential to supply the entire United States transportation sector from that quantity of biomass. (iii) The synthesized liquid provides H2 storage in an open loop system. (iv) Reduction to practice of the H2CAR route has the potential to provide the transportation sector for the foreseeable future, using the existing infrastructure. The rationale of using H2 in the H2CAR process is explained by the significantly higher annualized average solar energy conversion efficiency for hydrogen generation versus that for biomass growth. For coal to liquids, the advantage of H2CAR is that there is no additional CO2 release to the atmosphere due to the replacement of petroleum with coal, thus eliminating the need to sequester CO2. PMID:17360377

Influence of performance characteristic of a gaseous fuel supply system on hydrocarbon emissions of a dual-fuel engine

Energy Technology Data Exchange (ETDEWEB)

Ren, J.; Wang, Z.Y.; Zhong, H.; Hao, S.H. [Xi' an Jiaotong Univ., Dept. of Automobile Engineering, Xi' an (China)

2000-11-01

The performance of the gaseous fuel supply and its influence on hydrocarbon (HC) emissions of dual-fuel engines have been investigated. A new design of manifold respirators with mixers is also presented in the paper. The design of the gaseous fuel supply system has a great influence on HC emissions in the dual-fuel engine at light load. The problem of scavenging is discussed and solved by using the manifold respirators in the dual-fuel engine. It performs the function of retarding the gaseous fuel entry timing from the moment of intake valve opening, and its delaying effects have been measured and tested. Experimental results show that the manifold respirator gives the best performance in reducing HC emissions compared with a common pipe mixer and a respirator with bo miser. In addition, the mixing effects are sensitive to the mixer configuration. (Author)

Phenomena in thermal transport in fuels

International Nuclear Information System (INIS)

Chernatynskiy, A.; Tulenko, J.S.; Phillpot, S.R.; El-Azab, A.

2015-01-01

Thermal transport in nuclear fuels is a key performance metric that affects not only the power output, but is also an important consideration in potential accident situations. While the fundamental theory of the thermal transport in crystalline solids was extensively developed in the 1950's and 1960's, the pertinent analytic approaches contained significant simplifications of the physical processes. While these approaches enabled estimates of the thermal conductivity in bulk materials with microstructure, they were not comprehensive enough to provide the detailed guidance needed for the in-pile fuel performance. Rather, this guidance has come from data painfully accumulated over 50 years of experiments on irradiated uranium dioxide, the most widely used nuclear fuel. At this point, a fundamental theoretical understanding of the interplay between the microstructure and thermal conductivity of irradiated uranium dioxide fuel is still lacking. In this chapter, recent advances are summarised in the modelling approaches for thermal transport of uranium dioxide fuel. Being computational in nature, these modelling approaches can, at least in principle, describe in detail virtually all mechanisms affecting thermal transport at the atomistic level, while permitting the coupling of the atomistic-level simulations to the mesoscale continuum theory and thus enable the capture of the impact of microstructural evolution in fuel on thermal transport. While the subject of current studies is uranium dioxide, potential applications of the methods described in this chapter extend to the thermal performance of other fuel forms. (authors)

Fuel Mix Impacts from Transportation Fuel Carbon Intensity Standards in Multiple Jurisdictions

Science.gov (United States)

Witcover, J.

2017-12-01

Fuel carbon intensity standards have emerged as an important policy in jurisdictions looking to target transportation greenhouse gas (GHG) emissions for reduction. A carbon intensity standard rates transportation fuels based on analysis of lifecycle GHG emissions, and uses a system of deficits and tradable, bankable credits to reward increased use of fuels with lower carbon intensity ratings while disincentivizing use of fuels with higher carbon intensity ratings such as conventional fossil fuels. Jurisdictions with carbon intensity standards now in effect include California, Oregon, and British Columbia, all requiring 10% reductions in carbon intensity of the transport fuel pool over a 10-year period. The states and province have committed to grow demand for low carbon fuels in the region as part of collaboration on climate change policies. Canada is developing a carbon intensity standard with broader coverage, for fuels used in transport, industry, and buildings. This study shows a changing fuel mix in affected jurisdictions under the policy in terms of shifting contribution of transportation energy from alternative fuels and trends in shares of particular fuel pathways. It contrasts program designs across the jurisdictions with the policy, highlights the opportunities and challenges these pose for the alternative fuel market, and discusses the impact of having multiple policies alongside federal renewable fuel standards and sometimes local carbon pricing regimes. The results show how the market has responded thus far to a policy that incentivizes carbon saving anywhere along the supply chain at lowest cost, in ways that diverged from a priori policy expectations. Lessons for the policies moving forward are discussed.

Transport fuel

DEFF Research Database (Denmark)

Ronsse, Frederik; Jørgensen, Henning; Schüßler, Ingmar

2014-01-01

Worldwide, the use of transport fuel derived from biomass increased four-fold between 2003 and 2012. Mainly based on food resources, these conventional biofuels did not achieve the expected emission savings and contributed to higher prices for food commod - ities, especially maize and oilseeds...

Inspection of nuclear fuel transport in Spain

International Nuclear Information System (INIS)

Lobo Mendez, J.

1977-01-01

The experience acquired in inspecting nuclear fuel shipments carried out in Spain will serve as a basis for establishing the regulations wich must be adhered to for future transports, as the transport of nuclear fuels in Spain will increase considerably within the next years as a result of the Spanish nuclear program. The experience acquired in nuclear fuel transport inspection is described. (author) [es

Environmental impact study on a degassing and scaling of cistern trucks for fuel transportation plant.

OpenAIRE

Tupia, Elmer

2014-01-01

The present Study of Environmental Impact (EIA) it is carried out by the Company Ecoplanet Group from the Peru CORP, to application of Servisya CORP, proprietor of a degassing plant and scaling of trucks cistern for transports of derived liquid fuels of the hydrocarbons, the environment of the location area undestood in the Country of Lima of the district of Villa El Salvador being. El presente estudio de Impacto Ambiental(EIA) es realizado por la empresa Ecoplanet group del Perú S.A. a s...

Direct production of fractionated and upgraded hydrocarbon fuels from biomass

Science.gov (United States)

Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

2014-08-26

Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

Analysis of near-term spent fuel transportation hardware requirements and transportation costs

International Nuclear Information System (INIS)

Daling, P.M.; Engel, R.L.

1983-01-01

A computer model was developed to quantify the transportation hardware requirements and transportation costs associated with shipping spent fuel in the commercial nucler fuel cycle in the near future. Results from this study indicate that alternative spent fuel shipping systems (consolidated or disassembled fuel elements and new casks designed for older fuel) will significantly reduce the transportation hardware requirements and costs for shipping spent fuel in the commercial nuclear fuel cycle, if there is no significant change in their operating/handling characteristics. It was also found that a more modest cost reduction results from increasing the fraction of spent fuel shipped by truck from 25% to 50%. Larger transportation cost reductions could be realized with further increases in the truck shipping fraction. Using the given set of assumptions, it was found that the existing spent fuel cask fleet size is generally adequate to perform the needed transportation services until a fuel reprocessing plant (FRP) begins to receive fuel (assumed in 1987). Once the FRP opens, up to 7 additional truck systems and 16 additional rail systems are required at the reference truck shipping fraction of 25%. For the 50% truck shipping fraction, 17 additional truck systems and 9 additional rail systems are required. If consolidated fuel only is shipped (25% by truck), 5 additional rail casks are required and the current truck cask fleet is more than adequate until at least 1995. Changes in assumptions could affect the results. Transportation costs for a federal interim storage program could total about $25M if the FRP begins receiving fuel in 1987 or about $95M if the FRP is delayed until 1989. This is due to an increased utilization of federal interim storage facility from 350 MTU for the reference scenario to about 750 MTU if reprocessing is delayed by two years

Transport device for nuclear fuel powder

International Nuclear Information System (INIS)

Adelmann, M.

1987-01-01

The transport device for nuclear fuel powder, which does not disintegrate during transport, has a transport pipe which starts with its entry end from the floor or a closed container and opens with its outlet end at the top into a closed separation container connect via a powder filter to a suction pump. By alternate regular opening and closing of a first control valve for transport gas fitted to a transport pipe to a supply duct and a second control valve for transport gas fitted to the container to an additional supply duct, alternating plugs of nuclear fuel powder and transport gas cushions are formed and are transported to the outlet end of the transport pipe. (orig./HP) [de

Simulation study of a PEM fuel cell system fed by hydrogen produced by partial oxidation

Energy Technology Data Exchange (ETDEWEB)

Ozdogan, S [Marmara University, Faculty of Engineering, Istanbul (Turkey); Ersoz, A; Olgun, H [TUBITAK Marmara Research Center, Energy Systems and Environmental Research Institute, Kocaeli (Turkey)

2003-09-01

Within the frame of sustainable development, efficient and clean, if possible zero emission energy production technologies are of utmost importance in various sectors such as utilities, industry, households and transportation. Low-temperature fuel cell systems are suitable for powering transportation systems such as automobiles and trucks in an efficient and low-emitting manner. Proton exchange membrane (PEM) fuel cell systems constitute the most promising low temperature fuel cell option being developed globally. PEM fuel cells generate electric power from air and hydrogen or from a hydrogen rich gas via electrochemical reactions. Water and waste heat are the only by-products of PEM fuel cells. There is great interest in converting current hydrocarbon based common transportation fuels such as gasoline and diesel into hydrogen rich gases acceptable by PEM fuel cells. Hydrogen rich gases can be produced from conventional transportation fuels via various reforming technologies. Steam reforming, partial oxidation and auto-thermal reforming are the three major reforming technologies. In this paper, we discuss the results of a simulation study for a PEM fuel cell with partial oxidation. The Aspen HYSYS 3.1 code has been used for simulation purposes. Two liquid hydrocarbon fuels have been selected to investigate the effect of average molecular weights of hydrocarbons, on the fuel processing efficiency. The overall system efficiency depends on the fuel preparation and fuel cell efficiencies as well as on the heat integration within the system. It is desired to investigate the overall system efficiencies for net electrical power production at 100 kW considering bigger scale transport applications. Results indicate that fuel properties, fuel preparation system operating parameters and PEM fuel cell polarization curve characteristics all affect the overall system efficiency. (authors)

Alternatives to traditional transportation fuels 1996

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-12-01

Interest in alternative transportation fuels (ATF`s) has increased in recent years due to the drives for cleaner air and less dependence upon foreign oil. This report, Alternatives to Traditional Transportation Fuels 1996, provides information on ATFs, as well as the vehicles that consume them.

Methodological aspects of fuel performance system analysis at raw hydrocarbon processing plants

Science.gov (United States)

Kulbjakina, A. V.; Dolotovskij, I. V.

2018-01-01

The article discusses the methodological aspects of fuel performance system analysis at raw hydrocarbon (RH) processing plants. Modern RH processing facilities are the major consumers of energy resources (ER) for their own needs. To reduce ER, including fuel consumption, and to develop rational fuel system structure are complex and relevant scientific tasks that can only be done using system analysis and complex system synthesis. In accordance with the principles of system analysis, the hierarchical structure of the fuel system, the block scheme for the synthesis of the most efficient alternative of the fuel system using mathematical models and the set of performance criteria have been developed on the main stages of the study. The results from the introduction of specific engineering solutions to develop their own energy supply sources for RH processing facilities have been provided.

Multi-fuel reformers for fuel cells used in transportation. Phase 1: Multi-fuel reformers

Science.gov (United States)

1994-05-01

DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

Transportation 2000. Spent fuel transportation trends in the new millenium

International Nuclear Information System (INIS)

Blee, David; Viebrock, James; Patterson, John

1999-01-01

The paper will provide a comparison of foreign research reactor spent fuel transportation today verses the assumptions used by the Department of Energy in the Environmental Impact Statement. In addition, it will suggest changes that are likely to occur in transportation logistics through the remainder of the U.S. spent fuel returns program. Cask availability, certification status, shipment strategy, cost issues, and public acceptance are among the topical areas that will be examined. Transportation requirements will be assessed in light of current participation in the returns program and the tendency for shipment plans to shift toward spent fuel return toward the end of the 13 year period of eligibility. (author)

Effects of fueling profiles on plasma transport

International Nuclear Information System (INIS)

Houlberg, W.A.; Mense, A.T.; Attenberger, S.E.; Milora, S.L.

1977-01-01

The effects of cold particle fueling profiles on particle and energy transport in an ignition sized tokamak plasma are investigated in this study with a one-dimensional, multifluid transport model. A density gradient driven trapped particle microinstability model for plasma transport is used to demonstrate potential effects of fueling profiles on ignition requirements. Important criteria for the development of improved transport models under the conditions of shallow particle fueling profiles are outlined. A discrete pellet fueling model indicates that large fluctuations in density and temperature may occur in the outer regions of the plasma with large, shallowly penetrating pellets, but fluctuations in the pressure profile are small. The hot central core of the plasma remains unaffected by the large fluctuations near the plasma edge

Comparison of the Transportation Risks Resulting from Accidents during the Transportation of the Spent Fuel

International Nuclear Information System (INIS)

Jeong Jong Tae; Cho, Dong Kuen; Choi, Heui Joo; Choi, Jong Won

2007-01-01

The safe, environmentally sound and publicly acceptable disposal of high level wastes and spent fuels is becoming a very important issue. The operational safety assessment of a repository including a transportation safety assessment is a fundamental part in order to achieve this goal. According to the long term management strategy for spent fuels in Korea, they will be transported from the spent fuel pools in each nuclear power plant to the central interim storage facility (CISF) which is to start operation in 2016. Therefore, we have to determine the safe and economical logistics for the transportation of these spent fuels by considering their transportation risks and costs. In this study, we developed four transportation scenarios by considering the type of transportation casks and transport means in order to suggest safe and economical transportation logistics for spent fuels. Also, we estimated and compared the transportation risks resulting from the accidents during the transportation of spent fuels for these four transportation scenarios

A survey of Opportunities for Microbial Conversion of Biomass to Hydrocarbon Compatible Fuels

Energy Technology Data Exchange (ETDEWEB)

Jovanovic, Iva; Jones, Susanne B.; Santosa, Daniel M.; Dai, Ziyu; Ramasamy, Karthikeyan K.; Zhu, Yunhua

2010-09-01

Biomass is uniquely able to supply renewable and sustainable liquid transportation fuels. In the near term, the Biomass program has a 2012 goal of cost competitive cellulosic ethanol. However, beyond 2012, there will be an increasing need to provide liquid transportation fuels that are more compatible with the existing infrastructure and can supply fuel into all transportation sectors, including aviation and heavy road transport. Microbial organisms are capable of producing a wide variety of fuel and fuel precursors such as higher alcohols, ethers, esters, fatty acids, alkenes and alkanes. This report surveys liquid fuels and fuel precurors that can be produced from microbial processes, but are not yet ready for commercialization using cellulosic feedstocks. Organisms, current research and commercial activities, and economics are addressed. Significant improvements to yields and process intensification are needed to make these routes economic. Specifically, high productivity, titer and efficient conversion are the key factors for success.

The effect of fuel and chlorinated hydrocarbons on a vapor phase carbon adsorption system

International Nuclear Information System (INIS)

Crawford, W.J.; Cheney, J.L.; Taggart, D.B.

1995-01-01

A soil vapor extraction (SVE) system installed at the South Tacoma Well 12A Superfund Site was designed to recover 1,2-dichloroethylene (DCE), trichloroethylene (TCE), tetrachloroethylene (PCE), and 1,1,2,2-tetrachloroethane (1,1,2,2-TCA) from the vadose zone. The basic system consisted of twenty-two extraction wells, three centrifugal blowers, and three carbon adsorbers. The carbon adsorbers were regenerated on site by steam stripping. The mixture of steam and stripped organics was condensed and then decanted to separate the water from the organic phase. The recovered water was air stripped to remove the dissolved organics prior to discharge to the city storm sewer. The recovered organic phase was then shipped off site for thermal destruction. Previous reports described operating difficulties with the decanter, and air strippers. Sampling and analyses were performed which identified the problem as the simultaneous recovery of unexpected fuel hydrocarbons in addition to the solvents. Recovery of fuels resulted in a light phase in the decanter in addition to the water and heavy solvent phases. This required redesign of the decanter to handle the third phase. The effectiveness of desorption of the carbon beds by steam stripping gradually decreased as the remediation progressed into the second year of operation. Samples were collected from the carbon beds to evaluate the effect of the fuel and chlorinated hydrocarbons on the activated carbon. This report describes the results of these analyses. The data indicated that both 1,1,2,2-TCA and fuel hydrocarbons in the C-9 to C-24 range remained in the carbon beds after steam regeneration in sufficient quantities to require replacing the carbon

Spent fuel and HLW transportation the French experience

International Nuclear Information System (INIS)

Giraud, J.P.; Charles, J.L.

1995-01-01

With 53 nuclear power plants in operation at EDF and a fuel cycle with recycling policy of the valuable materials, COGEMA is faced with the transport of a wide range of radioactive materials. In this framework, the transport activity is a key link in closing the fuel cycle. COGEMA has developed a comprehensive Transport Organization System dealing with all the sectors of the fuel cycle. The paper will describe the status of transportation of spent fuel and HLW in France and the experience gathered. The Transport Organization System clearly defines the role of all actors where COGEMA, acting as the general coordinator, specifies the tasks to be performed and brings technical and commercial support to its various subcontractors: TRANSNUCLEAIRE, specialized in casks engineering and transport operations, supplies packaging and performs transport operations, LEMARECHAL and CELESTIN operate transport by truck in the Vicinity of the nuclear sites while French Railways are in charge of spent fuel transport by train. HLW issued from the French nuclear program is stored for 30 years in an intermediate storage installation located at the La Hague reprocessing plant. Ultimately, these canisters will be transported to the disposal site. COGEMA has set up a comprehensive transport organization covering all operational aspects including adapted procedures, maintenance programs and personnel qualification

Worldwide spent fuel transportation logistics

International Nuclear Information System (INIS)

Best, R.E.; Garrison, R.F.

1978-01-01

This paper presents an overview of the worldwide transportation requirements for spent fuel. Included are estimates of numbers and types of shipments by mode and cask type for 1985 and the year 2000. In addition, projected capital and transportation costs are presented. For the year 1977 and prior years inclusive, there is a cumulative worldwide requirement for approximately 300 MTU of spent fuel storage at away-from-reactor (AFR) facilities. The cumulative requirements for years through 1985 are projected to be nearly 10,000 MTU, and for the years through 2000 the requirements are conservatively expected to exceed 60,000 MTU. These AFR requirements may be related directly to spent fuel transportation requirements. In total nearly 77,000 total cask shipments of spent fuel will be required between 1977 and 2000. These shipments will include truck, rail, and intermodal moves with many ocean and coastal water shipments. A limited number of shipments by air may also occur. The US fraction of these is expected to include 39,000 truck shipments and 14,000 rail shipments. European shipments to regional facilities are expected to be primarily by rail or water mode and are projected to account for 16,000 moves. Pacific basin shipments will account for 4500 moves. The remaining are from other regions. Over 400 casks will be needed to meet the transportation demands. Capital investment is expected to reach $800,000,000 in 1977 dollars. Cumulative transport costs will be a staggering $4.4 billion dollars

Transport device of spent fuel

International Nuclear Information System (INIS)

Watanabe, Takashi.

1976-01-01

Object: To provide a transport device of spent fuel particularly used in a fast breeder, which can enhance accessibility to travelling mechanism portions and exchangeability thereof to facilitate maintenance in the event of failure. Structure: On a travelling floor, which has a function to shield radioactive rays, extending in a direction of transporting spent fuel and being formed with a break passing through in a direction wall thickness, a travelling body is moved along the break. The travelling body has a support rod member mounted thereon, and the support rod member is moved within the break, the support rod member having a fuel support pocket suspended therefrom. (Furukawa, Y.)

BNFL's new spent fuel transport flask - Excellox 8

International Nuclear Information System (INIS)

McWilliam, D.S.

2002-01-01

Since British Nuclear Fuels plc (BNFL) was formed in 1971 its transport service has safely moved spent light water reactor fuel from many locations abroad to its fuel handling plants at Sellafield in the UK. To support this business a number of types of flasks have been designed and used. One of the types used has been the Excellox family of water-filled flasks. To support future business opportunities a new flask, designed to meet the requirements of the new IAEA transport regulations TS-R-1 (ST-1, Revised), has been developed. The flask will be a type B(U)F. This new flask design will maximise fuel carrying capacity to minimise transport costs. The design capacity of the new Excellox 8 flask is to be 12 pressurised water reactor or 32 boiling water reactor fuel assemblies. The objective of this BNFL project is to provide another economic spent nuclear fuel transport system, in support of BNFL transport business. (author)

Transportation fuels of the future?

International Nuclear Information System (INIS)

Piel, W.J.

2001-01-01

Society is putting more emphasis on the mobile transportation sector to achieve future goals of sustainability and a cleaner environment. To achieve these goals, does society need to jump to a new combination of fuel and vehicle technology or can we just continue to improve on the current fuels and drive train technology that has powered us the past 70 or more years? Do we need to move to more exotic energy conversion technology (fuel cell vehicles?), or can improving fuel properties further allow us to continue using combustion engines to power our vehicles? What fuel properties can still be improved in gasoline and diesel? Besides removing sulfur, should there be less aromatics in fuels? Should aromatics be eliminated? Is there a role for oxygenates in gasoline and diesel? Do blending oxygenates in fuels help or hinder in achieving the environmental goals? Can we and should we reduce our dependency on crude oil for transportation energy? Why have not the previous government-sponsored Alternative Fuel programs displaced crude oil? The marketplace will determine which fuel and vehicle technology combination will eventually be used in the future. Does the information we know today give us insight to this future? This paper will attempt to address some of the key issues and questions on the role fuels may play in that marketplace decision

Fuels and Combustion | Transportation Research | NREL

Science.gov (United States)

Fuels and Combustion Fuels and Combustion This is the March 2015 issue of the Transportation and , combustion strategy, and engine design hold the potential to maximize vehicle energy efficiency and performance of low-carbon fuels in internal combustion engines with a whole-systems approach to fuel chemistry

Transportation of spent MTR fuels

Energy Technology Data Exchange (ETDEWEB)

Raisonnier, D.

1997-08-01

This paper gives an overview of the various aspects of MTR spent fuel transportation and provides in particular information about the on-going shipment of 4 spent fuel casks to the United States. Transnucleaire is a transport and Engineering Company created in 1963 at the request of the French Atomic Energy Commission. The company followed the growth of the world nuclear industry and has now six subsidiaries and affiliated companies established in countries with major nuclear programs.

Transportation of spent MTR fuels

International Nuclear Information System (INIS)

Raisonnier, D.

1997-01-01

This paper gives an overview of the various aspects of MTR spent fuel transportation and provides in particular information about the on-going shipment of 4 spent fuel casks to the United States. Transnucleaire is a transport and Engineering Company created in 1963 at the request of the French Atomic Energy Commission. The company followed the growth of the world nuclear industry and has now six subsidiaries and affiliated companies established in countries with major nuclear programs

Hydrocarbon transport in the laboratory plasma (MAP)

Energy Technology Data Exchange (ETDEWEB)

Matsuyama, Seiji; Yamaguchi, Kenji; Yamawaki, Michio [Tokyo Univ., Tokai, Ibaraki (Japan). Nuclear Engineering Research Lab.; Tanaka, Satoru

1996-10-01

Hydrocarbons are admitted in the laboratory plasma in order to investigate the transport processes of carbon - containing molecules in relation to redeposition processes in the fusion boundary plasma. When CH{sub 4} was introduced into the plasma, CH radical band spectra were optically identified, while in the case of C{sub 2}H{sub 2} introduction, C{sub 2} radicals were also identified in addition to CH radicals. Excitation temperature was determined from CH and C{sub 2} spectra band, which was observed to increase on approaching to the target. (author)

DOE perspective on fuel cells in transportation

Energy Technology Data Exchange (ETDEWEB)

Kost, R.

1996-04-01

Fuel cells are one of the most promising technologies for meeting the rapidly growing demand for transportation services while minimizing adverse energy and environmental impacts. This paper reviews the benefits of introducing fuel cells into the transportation sector; in addition to dramatically reduced vehicle emissions, fuel cells offer the flexibility than use petroleum-based or alternative fuels, have significantly greater energy efficiency than internal combustion engines, and greatly reduce noise levels during operation. The rationale leading to the emphasis on proton-exchange-membrane fuel cells for transportation applications is reviewed as are the development issues requiring resolution to achieve adequate performance, packaging, and cost for use in automobiles. Technical targets for power density, specific power, platinum loading on the electrodes, cost, and other factors that become increasingly more demanding over time have been established. Fuel choice issues and pathways to reduced costs and to a renewable energy future are explored. One such path initially introduces fuel cell vehicles using reformed gasoline while-on-board hydrogen storage technology is developed to the point of allowing adequate range (350 miles) and refueling convenience. This scenario also allows time for renewable hydrogen production technologies and the required supply infrastructure to develop. Finally, the DOE Fuel Cells in Transportation program is described. The program, whose goal is to establish the technology for fuel cell vehicles as rapidly as possible, is being implemented by means of the United States Fuel Cell Alliance, a Government-industry alliance that includes Detroit`s Big Three automakers, fuel cell and other component suppliers, the national laboratories, and universities.

High Pressure Preignition Chemistry of Hydrocarbons and Hydrocarbon Mixtures

National Research Council Canada - National Science Library

Cernansky, N.P

1998-01-01

.... The research program entailed mechanistic studies examining the oxidation chemistry of single-component hydrocarbons and ignition studies examining the overall ignition of pure single component fuels and fuel blends...

Transporting spent nuclear fuel: an overview

International Nuclear Information System (INIS)

1986-03-01

Although high-level radioactive waste from both commercial and defense activities will be shipped to the repository, this booklet focuses on various aspects of transporting commercial spent fuel, which accounts for the majority of the material to be shipped. The booklet is intended to give the reader a basic understanding of the following: the reasons for transportation of spent nuclear fuel, the methods by which it is shipped, the safety and security precautions taken for its transportation, emergency response procedures in the event of an accident, and the DOE program to develop a system uniquely appropriate to NWPA transportation requirements

Transportation of radioactive wastes from nuclear fuel cycles

International Nuclear Information System (INIS)

1979-09-01

This paper discusses current and foreseen radioactive waste transportation systems as they apply to the INFCE Working Group 7 study. The types of wastes considered include spent fuel, which is treated as a waste in once-through fuel cycles; high-, medium-, and low-level waste; and gaseous waste. Regulatory classification of waste quantities and containers applicable to these classifications are discussed. Radioactive wastes are presently being transported in a safe and satisfactory manner. None of the INFCE candidate fuel cycles pose any extraordinary problems to future radioactive waste transportation and such transportation will not constitute a decisive factor in the choice of a preferred fuel cycle

The transportation of PuO2 and MOX fuel and management of irradiated MOX fuel

International Nuclear Information System (INIS)

Dyck, H.P.; Rawl, R.; Durpel, L. van den

2000-01-01

Information is given on the transportation of PuO 2 and mixed-oxide (MOX) fuel, the regulatory requirements for transportation, the packages used and the security provisions for transports. The experience with and management of irradiated MOX fuel and the reprocessing of MOX fuel are described. Information on the amount of MOX fuel irradiated is provided. (author)

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels

Science.gov (United States)

Berry, David A [Morgantown, WV; Shekhawat, Dushyant [Morgantown, WV; Haynes, Daniel [Morgantown, WV; Smith, Mark [Morgantown, WV; Spivey, James J [Baton Rouge, LA

2012-03-13

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Comparison of the transportation risks for the spent fuel in Korea for different transportation scenarios

International Nuclear Information System (INIS)

Jeong, Jongtae; Cho, D.K.; Choi, H.J.; Choi, J.W.

2011-01-01

According to the long term management strategy for spent fuels in Korea, they will be transported from the spent fuel pools in each nuclear power plant to the central interim storage facility (CISF) which is to start operation in 2016. At the start of the operation of the final repository (FR), by the year 2065, transport will then take place between the CISF and the FR. Therefore, we have to determine the safe and economical logistics for the transportation of these spent fuels by considering their transportation risks and costs. In this study, we developed four transportation scenarios for a maritime transportation by considering the type of transportation casks and transport means in order to suggest safe and economical transportation logistics for the spent fuels in Korea. And, we estimated and compared the transportation risks for these four transportation scenarios. Also, we estimated and compared the transportation risks resulting from accidents during the transportation of PWR and PHWR spent fuels by road trailers from the CISF and the FR. From the results of this study, we found that risks resulting from accidents during the transportation of the spent fuels have a very low radiological risk activity with a manageable safety and health consequences. The results of this study can be used as basic data for the development of safe and economical logistics for a transportation of the spent fuels in Korea by considering the transportation costs for the four scenarios which will be needed in the near future.

Toxicity of jet fuel aliphatic and aromatic hydrocarbon mixtures on human epidermal Keratinocytes: evaluation based on in vitro cytotoxicity and interleukin-8 release

Energy Technology Data Exchange (ETDEWEB)

Yang, Jen-Hung (Chung-Shan Medical University Hospital, Department of Dermatology, Taichung, Taiwan, R.O.C); Lee, Chia-Hue; Tsang, Chau-Loong [National Chung-Hsing University, College of Veterinary Medicine, Taichung (Taiwan); Monteiro-Riviere, Nancy A.; Riviere, Jim E. [North Carolina State University, Center for Chemical Toxicology Research and Pharmacokinetics (CCTRP), Raleigh, NC (United States); Chou, Chi-Chung [National Chung-Hsing University, College of Veterinary Medicine, Taichung (Taiwan); National Chung-Hsing University, College of Veterinary Medicine, Taichung (Taiwan)

2006-08-15

Jet fuels are complex mixtures of aliphatic (ALI) and aromatic (ARO) hydrocarbons that vary significantly in individual cytotoxicity and proinflammatory activity in human epidermal keratinocytes (HEK). In order to delineate the toxicological interactions among individual hydrocarbons in a mixture and their contributions to cutaneous toxicity, nine ALI and five ARO hydrocarbons were each divided into five (high/medium/low cytotoxic and strong/weak IL-8 induction) groups and intra/inter-mixed to assess for their mixture effects on HEK mortality and IL-8 release. Addition of single hydrocarbon to JP-8 fuel was also evaluated for their changes in fuel dermatotoxicity. The results indicated that when hydrocarbons were mixed, HEK mortality and IL-8 release were not all predictable by their individual ability affecting these two parameters. The lowest HEK mortality (7%) and the highest IL-8 production were induced with mixtures including high cytotoxic and weak IL-8 inductive ARO hydrocarbons. Antagonistic reactions not consistently correlated with ALI carbon chain length and ARO structure were evident and carried different weight in the overall mixture toxicities. Single addition of benzene, toluene, xylene or ethylbenzene for up to tenfold in JP-8 did not increase HEK mortality while single addition of ALI hydrocarbons exhibited dose-related differential response in IL-8. In an all ALI environment, no single hydrocarbon is the dominating factor in the determination of HEK cytotoxicity while deletion of hexadecane resulted in a 2.5-fold increase in IL-8 production. Overall, decane, undecane and dodecane were the major hydrocarbons associated with high cytotoxicity while tetradecane, pentadecane and hexadecane were those which had the greatest buffering effect attenuating dermatotoxicity. The mixture effects must be considered when evaluating jet fuel toxicity to HEK. (orig.)

Transport of encapsulated nuclear fuels

International Nuclear Information System (INIS)

Broman, Ulrika; Dybeck, Peter; Ekendahl, Ann-Mari

2005-12-01

The transport system for encapsulated fuel is described, including a preliminary drawing of a transport container. In the report, the encapsulation plant is assumed to be located to Oskarshamn, and the repository to Oskarshamn or Forsmark

Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels

Energy Technology Data Exchange (ETDEWEB)

University of Central Florida

2004-01-30

The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

Transportation of irradiated fuel elements

International Nuclear Information System (INIS)

Preece, A.H.

1980-01-01

The report falls under the headings: introduction (explaining the special interest of the London Borough of Brent, as forming part of the route for transportation of irradiated fuel elements); nuclear power (with special reference to transport of spent fuel and radioactive wastes); the flask aspect (design, safety regulations, criticisms, tests, etc.); the accident aspect (working manual for rail staff, train formation, responsibility, postulated accident situations); the emergency arrangements aspect; the monitoring aspect (health and safety reports); legislation; contingency plans; radiation - relevant background information. (U.K.)

An improved assembly for the transport of fuel elements

International Nuclear Information System (INIS)

Myers, G.

1979-01-01

An improved assembly for the transport and storage of radioactive nuclear fuel elements is described. The fuel element transport canister is of the type in which the fuel elements are submerged in liquid with a self regulating ullage system, so that the fuel elements are always submerged in the liquid even when the assembly is used in one orientation during loading and another orientation during transportation. (UK)

Alternatives to traditional transportation fuels 1995

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-12-01

This report provides information on transportation fuels other than gasoline and diesel, and the vehicles that use these fuels. The Energy Information Administration (EIA) provides this information to support the U.S. Department of Energy`s reporting obligations under Section 503 of the Energy Policy Act of 1992 (EPACT). The principal information contained in this report includes historical and year-ahead estimates of the following: (1) the number and type of alterative-fueled vehicles (AFV`s) in use; (2) the consumption of alternative transportation fuels and {open_quotes}replacement fuels{close_quotes}; and (3) the number and type of alterative-fueled vehicles made available in the current and following years. In addition, the report contains some material on special topics. The appendices include a discussion of the methodology used to develop the estimates (Appendix A), a map defining geographic regions used, and a list of AFV suppliers.

Control system of fuel transporting device

International Nuclear Information System (INIS)

Yokota, Minoru.

1981-01-01

Purpose: To effectively avoid an obstacle in a fuel transporting device by reading the outputs of absolute position detectors mounted on movable trucks, controlling the movements of the trucks, and thereby smoothly and accurately positioning the fuel transporting device at predetermined position and providing a contact detector thereat. Method: The outputs from absolute position detectors which are mounted on a longitudinally movable truck and a laterally movable truck are input to an input/output control circuit. The input/output control circuit serves to compare, the position a fuel transporting device is to be moved to, with the present position on the basis of said input detection signal and a command signal from an operator console, to calculate the amount of movement to be driven, to produce an operation signal therefor to a control panel, and to drive and control the drive motors which are respectively mounted on the trucks for the fuel transfer device. On the other hand, in case that the transfer device comes into contact with an obstacle, the contact detector will immediately operate to produce a stop command through the control panel to the transporting device, and avoid a collision with the obstacle. (Yoshino, Y.)

Contributions to LWR spent fuel storage and transport

International Nuclear Information System (INIS)

The papers included in this document describe the aspects of spent LWR fuel storage and transport-behaviour of spent fuel during storage; use of compact storage packs; safety of storage; design of storage facilities AR and AFR; description of transport casks and transport procedures

Ordinance concerning the filing of transport of nuclear fuel materials

International Nuclear Information System (INIS)

1987-01-01

This Order provides provisions concerning nuclear fuel substances requiring notification (nuclear fuel substance, material contaminated with nuclear fuel substances, fissionable substances, etc.), procedure for notification (to prefectural public safety commission), certificate of transpot (issued via public safety commission), instructions (speed of vehicle for transporting nuclear fuel substances, parking of vehicle, place for loading and unloading of nuclear fuel substances, method for loading and unloading, report to police, measures for disaster prevention during transport, etc.), communication among members of public safety commission (for smooth transport), notification of alteration of data in transport certificate (application to be submitted to public safety commission), application of reissue of transport certificate, return of transport certificate, inspection concerning transport (to be performed by police), submission of report (to be submitted by refining facilities manager, processing facilities manager, nuclear reactor manager, master of foreign nuclear powered ship, reprocessing facilities manager, waste disposal facilities manager; concerning stolen or missing nuclear fuel substances, traffic accident, unusual leakage of nuclear fuel substances, etc.). (Nogami, K.)

Nuclear-electrolytic hydrogen as a transportation fuel

International Nuclear Information System (INIS)

DeLuchi, M.A.

1989-01-01

Hydrogen is a very attractive transportation fuel in three important ways: it is the least polluting fuel that can be used in an internal combustion engine, it produces no greenhouse gases, and it is potentially available anywhere there is water and a clean source of power. The prospect of a clean, widely available transportation fuel has motivated much of the research on hydrogen fuels. This paper is a state-of-the art review of the production, storage, performance, environmental impacts, safety, and cost of nuclear-electrolytic hydrogen for highway vehicles

EDF energy generation UK transport of irradiated fuel

Energy Technology Data Exchange (ETDEWEB)

James, R. [EDF Energy, London, (United Kingdom)

2015-07-01

This paper give an overview of irradiated fuel transport in the UK. It describes the design of irradiated fuel flask used by EDF Energy; operational experience and good practices learnt from over 50 years of irradiated fuel transport. The AGRs can store approximately 9 months generation of spent fuel, hence the ability to transport irradiated fuel is vital. Movements are by road to the nearest railhead, typically less than 2 miles and then by rail to Sellafield, up to 400 miles, for reprocessing or long term storage. Road and rail vehicles are covered. To date in the UK: over 30,000 Magnox flask journeys and over 15,000 AGR A2 flask journeys have been carried out.

Thermal model of spent fuel transport cask

International Nuclear Information System (INIS)

Ahmed, E.E.M.; Rahman, F.A.; Sultan, G.F.; Khalil, E.E.

1996-01-01

The investigation provides a theoretical model to represent the thermal behaviour of the spent fuel elements when transported in a dry shipping cask under normal transport conditions. The heat transfer process in the spent fuel elements and within the cask are modeled which include the radiant heat transfer within the cask and the heat transfer by thermal conduction within the spent fuel element. The model considers the net radiant method for radiant heat transfer process from the inner most heated element to the surrounding spent elements. The heat conduction through fuel interior, fuel-clad interface and on clad surface are also presented. (author) 6 figs., 9 refs

Comparison of the fuel oil biodegradation potential of hydrocarbon-assimilating microorganisms isolated from a temperate agricultural soil

International Nuclear Information System (INIS)

Chaineau, C.H.; Dupont, J.; Bury, E.; Oudot, J.; Morel, J.

1999-01-01

Strains of hydrocarbon-degrading microorganisms (bacteria and fungi) were isolated from an agricultural soil in France. In a field, a portion was treated with oily cuttings resulting from the drilling of an onshore well. The cuttings which were spread at the rate of 600 g HC m -2 contained 10% of fuel oil hydrocarbons (HC). Another part of the field was left untreated. Three months after HC spreading, HC adapted bacteria and fungi were isolated at different soil depths in the two plots and identified. The biodegradation potential of the isolated strains was monitored by measuring the degradation rate of total HC, saturated hydrocarbons, aromatic hydrocarbons and resins of the fuel. Bacteria of the genera Pseudomonas, Brevundimonas, Sphingomonas, Acinetobacter, Rhodococcus, Arthrobacter, Corynebacterium and fungi belonging to Aspergillus, Penicillium, Beauveria, Acremonium, Cladosporium, Fusarium, and Trichoderma were identified. The most active strains in the assimilation of saturates and aromatics were Arthrobacter sp., Sphingomonas spiritivorum, Acinetobacter baumanii, Beauveria alba and Penicillum simplicissimum. The biodegradation potential of the hydrocarbon utilizing microorganisms isolated from polluted or unpolluted soils were similar. In laboratory pure cultures, saturated HC were more degraded than aromatic HC, whereas resins were resistant to microbial attack. On an average, individual bacterial strains were more active than fungi in HC biodegradation. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

Transporting fuel debris from TMI-2 to INEL

International Nuclear Information System (INIS)

Quinn, G.J.; Burton, H.M.; Bixby, W.W.; McIntosh, T.W.; McGoff, O.J.; Barkonic, R.J.; Henrie, J.O.

1986-06-01

Transportation of the damaged fuel from Unit 2 of Three Mile Island (TMI-2) presented noteworthy technical challenges involving complex institutional issues. The program resulted from both a need to package and remove the accident debris and also the opportunity to receive and study damaged core components. These combined to establish the safe transport of the TMI-2 fuel debris as a high priority for many diverse organizations. The capability of the sending and receiving facilities to handle spent fuel transport casks in the most cost-effective manner was assessed and resulted in the development by Nuclear Packaging Inc. (NuPac) of the NuPac 125-B rail cask. This paper reviews the technical challenges in preparation of the TMI-2 core debris for transport from TMI-2 to the Idaho National Engineering Laboratory (INEL) and receipt and storage of that material at INEL. Challenges discussed include design and testing of fuel debris canisters; design, fabrication and licensing of a new rail cask for spent fuel transport; cask loading operations, equipment and facilities at TMI-2; transportation logistics; and, receipt, storage and core examination operations at INEL. 10 refs

Effects of fueling profiles on plasma transport

International Nuclear Information System (INIS)

Mense, A.T.; Houlberg, W.A.; Attenberger, S.E.; Milora, S.L.

1978-04-01

A one-dimensional (1-D), multifluid transport model is used to investigate the effects of particle fueling profiles on plasma transport in an ignition-sized tokamak (TNS). Normal diffusive properties of plasmas will likely maintain the density at the center of the discharge even if no active fueling is provided there. This significantly relaxes the requirements for fuel penetration. Not only is lower fuel penetration easier to achieve, but it may have the advantage of reducing or eliminating density gradient-driven trapped particle microinstabilities. Simulation of discrete pellet fueling indicates that relatively low velocity (approximately 10 3 m/sec) pellets may be sufficient to fuel a TNS-sized device (approximately 1.25-m minor radius), to produce a relatively broad, cool edge region of plasma which should reduce the potential for sputtering, and also to reduce the likelihood of trapped particle mode dominated transport. Low penetrating pellets containing up to 10 to 20 percent of the total plasma ions can produce fluctuations in density and temperature at the plasma edge, but the pressure profile and fusion alpha production remain almost constant

Risk assessment in spent fuel storage and transportation

International Nuclear Information System (INIS)

Pandimani, S.

1989-01-01

Risk assessment in various stages of nuclear fuel cycle is still an active area of Nuclear safety studies. From the results of risk assessment available in literature, it can be determined that the risk resulting from shipments of plutonium and spent-fuel are much greater than that resulting from the transport of other materials within the nuclear fuel cycle. In India spent fuels are kept in Spent Fuel Storage Pool (SFSP) for about 240-400 days, which is relatively a longer period compared to the usual 120 days as recommended by regulatory authorities. After cooling spent fuels are transported to the reprocessing sites which are mostly situated close to the plants. India has two high level waste treatment facilities, one PREFRE (Plutonium Reprocessing and Fuel Recycling) at Tarapur and the other one, a unit of Nuclear Fuel Complex at Hyderabad. This paper presents the risk associated with spent fuel storage and transportation for the Indian conditions. All calculations are based on a typical CANDU reactor system. Simple fault tree models are evolved for SFSP and for Transportation Accident Mode (TAM) for both road and rail. Fault tree quantification and risk assessment are done to each of these models. All necessary data for SFSP are taken mostly from Reactor Safety Study, (1975). Similarly, the data for rail TAM are taken from Annual Statistical Statements, (1987-8) and that for road TAM from Special Issue on Motor Vehicle Accident Statistics in India, (1986). Simulation method is used wherever necessary. Risk is also estimated for normal/accident free transport

Polycyclic aromatic hydrocarbons - fate and long-range atmospheric transport studied using a global model, EMAC-SVOC

Science.gov (United States)

Octaviani, Mega; Tost, Holger; Lammel, Gerhard

2017-04-01

Polycyclic aromatic hydrocarbons (PAHs) are emitted by incomplete combustion from fossil fuel, vehicles, and biomass burning. They may persist in environmental compartments, pose a health hazard and may bio accumulate along food chains. The ECHAM/MESSy Atmospheric Chemistry (EMAC) model had been used to simulate global tropospheric, stratospheric chemistry and climate. In this study, we improve the model to include simulations of the transport and fate of semi-volatile organic compounds (SVOC). The EMAC-SVOC model takes into account essential environmental processes including gas-particle partitioning, dry and wet deposition, chemical and bio-degradation, and volatilization from sea surface, soils, vegetation, and snow. The model was evaluated against observational data in the Arctic, mid-latitudes, and tropics, and further applied to study total environmental lifetime and long-range transport potential (LRTP) of PAHs. We selected four compounds for study, spanning a wide range of volatility, i.e., phenanthrene, fluoranthene, pyrene, and benzo[a]pyrene. Several LRTP indicators were investigated, including the Arctic contamination potential, meridional spreading, and zonal and meridional fluxes to remote regions.

French experience in research reactor fuel transportation

International Nuclear Information System (INIS)

Raisonnier, Daniele

1996-01-01

Since 1963 Transnucleaire has safely performed a large number of national and international transports of radioactive material. Transnucleaire has also designed and supplied suitable packaging for all types of nuclear fuel cycle radioactive material from front-end and back-end products and for power or for research reactors. Transportation of spent fuel from power reactors are made on a regular and industrial basis, but this is not yet the case for the transport of spent fuel coming from research reactors. Each shipment is a permanent challenge and requires a reactive organization dealing with all the transportation issues. This presentation will explain the choices made by Transnucleaire and its associates to provide and optimize the corresponding services while remaining in full compliance with the applicable regulations and customer requirements. (author)

Irradiated nuclear fuel transport from Japan to Europe

International Nuclear Information System (INIS)

Kavanagh, M.T.; Shimoyama, S.

1976-01-01

Irradiated nuclear fuel has been transported from Japan to Europe since 1969, although U.K. experience goes back almost two decades. Both magnox and oxide fuel have been transported, and the technical requirements associated with each type of fuel are outlined. The specialized ships used by British Nuclear Fuels Limited (BNFL) for this transport are described, as well as the ships being developed for future use in the Japan trade. The ship requirements are related to the regulatory position both in the United Kingdom and internationally, and the Japanese regulatory requirements are described. Finally, specific operational experience of a Japanese reactor operator is described

Spent fuels transportation coming from Australia; Transport de combustible use en provenance d'Australie

Energy Technology Data Exchange (ETDEWEB)

NONE

2002-07-01

Maritime transportation of spent fuels from Australia to France fits into the contract between COGEMA and ANSTO, signed in 1999. This document proposes nine information cards in this domain: HIFAR a key tool of the nuclear, scientific and technological australian program; a presentation of the ANSTO Australian Nuclear Science and Technology Organization; the HIFAR spent fuel management problem; the COGEMA expertise in favor of the research reactor spent fuel; the spent fuel reprocessing at La Hague; the transports management; the transport safety (2 cards); the regulatory framework of the transports. (A.L.B.)

Biomass conversion to hydrocarbon fuels using the MixAlco™ process at a pilot-plant scale

International Nuclear Information System (INIS)

Taco Vasquez, Sebastian; Dunkleman, John; Chaudhuri, Swades K.; Bond, Austin; Holtzapple, Mark T.

2014-01-01

Texas A and M University has built a MixAlco™ pilot plant that converts biomass to hydrocarbons (i.e., jet fuel, gasoline) using the following steps: fermentation, descumming, dewatering, thermal ketonization, distillation, hydrogenation, and oligomerization. This study describes the pilot plant and reports results from an 11-month production campaign. The focus was to produce sufficient jet fuel to be tested by the U.S. military. Because the scale was relatively small, energy-saving features were not included in the pilot plant. Further, the equipment was operated in a manner to maximize productivity even if yields were low. During the production campaign, a total of 6.015 Mg of shredded paper and 120 kg of chicken manure (dry basis) were fermented to produce 126.5 m 3 of fermentation broth with an average concentration of 12.5 kg m −3 . A total of 1582 kg of carboxylate salts were converted to 587 L of raw ketones, which were distilled and hydrogenated to 470 L of mixed alcohols ranging from C3 to C12. These alcohols, plus 300 L of alcohols made by an industrial partner (Terrabon, Inc.) were shipped to an independent contractor (General Electric) and transformed to jet fuel (∼100 L) and gasoline (∼100 L) byproduct. - Highlights: • We produce hydrocarbons from paper and chicken manure in a pilot-scale production using the MixAlco™ process. • About 100 L of jet fuel were produced for military testing. • High production rates and good product quality were preferred rather than high yields or energy efficiency. • The MixAlco™ process converted successfully lignocellulosic biomass to hydrocarbons and viable for commercial-scale production

Fossil Fuel-Derived Polycyclic Aromatic Hydrocarbons in the Taiwan Strait, China, and Fluxes across the Air-Water Interface.

Science.gov (United States)

Ya, Miaolei; Xu, Li; Wu, Yuling; Li, Yongyu; Zhao, Songhe; Wang, Xinhong

2018-06-14

On the basis of the application of compound-specific radiocarbon analysis (CSRA) and air-water exchange models, the contributions of fossil fuel and biomass burning derived polycyclic aromatic hydrocarbons (PAHs) as well as their air-water transport were elucidated. The results showed that fossil fuel-derived PAHs (an average contribution of 89%) presented the net volatilization process at the air-water interface of the Taiwan Strait in summer. Net volatile fluxes of the dominant fluorene and phenanthrene (>58% of the total PAHs) were 27 ± 2.8 μg m -2 day -1 , significantly higher than the dry deposition fluxes (average 0.43 μg m -2 day -1 ). The Δ 14 C contents of selected PAHs (fluorene, phenanthrene plus anthracene, fluoranthene, and pyrene) determined by CSRA in the dissolved seawater ranged from -997 ± 4‰ to -873 ± 6‰, indicating that 89-100% (95 ± 4%) of PAHs were supplied by fossil fuels. The South China Sea warm current originating from the southwest China in summer (98%) and the Min-Zhe coastal current originating from the north China in winter (97%) input more fossil fuel PAHs than the Jiulong River estuary (90%) and Xiamen harbor water (93%). The more radioactive decayed 14 C of fluoranthene (a 4-ring PAH) than that of phenanthrene and anthracene (3-ring PAHs) represented a greater fossil fuel contribution to the former in dissolved seawater.

Fuel-cycle greenhouse gas emissions impacts of alternative transportation fuels and advanced vehicle technologies

International Nuclear Information System (INIS)

Wang, M. Q.

1998-01-01

At an international conference on global warming, held in Kyoto, Japan, in December 1997, the United States committed to reduce its greenhouse gas (GHG) emissions by 7% over its 1990 level by the year 2012. To help achieve that goal, transportation GHG emissions need to be reduced. Using Argonne's fuel-cycle model, I estimated GHG emissions reduction potentials of various near- and long-term transportation technologies. The estimated per-mile GHG emissions results show that alternative transportation fuels and advanced vehicle technologies can help significantly reduce transportation GHG emissions. Of the near-term technologies evaluated in this study, electric vehicles; hybrid electric vehicles; compression-ignition, direct-injection vehicles; and E85 flexible fuel vehicles can reduce fuel-cycle GHG emissions by more than 25%, on the fuel-cycle basis. Electric vehicles powered by electricity generated primarily from nuclear and renewable sources can reduce GHG emissions by 80%. Other alternative fuels, such as compressed natural gas and liquefied petroleum gas, offer limited, but positive, GHG emission reduction benefits. Among the long-term technologies evaluated in this study, conventional spark ignition and compression ignition engines powered by alternative fuels and gasoline- and diesel-powered advanced vehicles can reduce GHG emissions by 10% to 30%. Ethanol dedicated vehicles, electric vehicles, hybrid electric vehicles, and fuel-cell vehicles can reduce GHG emissions by over 40%. Spark ignition engines and fuel-cell vehicles powered by cellulosic ethanol and solar hydrogen (for fuel-cell vehicles only) can reduce GHG emissions by over 80%. In conclusion, both near- and long-term alternative fuels and advanced transportation technologies can play a role in reducing the United States GHG emissions

Fuel-cycle greenhouse gas emissions impacts of alternative transportation fuels and advanced vehicle technologies.

Energy Technology Data Exchange (ETDEWEB)

Wang, M. Q.

1998-12-16

At an international conference on global warming, held in Kyoto, Japan, in December 1997, the United States committed to reduce its greenhouse gas (GHG) emissions by 7% over its 1990 level by the year 2012. To help achieve that goal, transportation GHG emissions need to be reduced. Using Argonne's fuel-cycle model, I estimated GHG emissions reduction potentials of various near- and long-term transportation technologies. The estimated per-mile GHG emissions results show that alternative transportation fuels and advanced vehicle technologies can help significantly reduce transportation GHG emissions. Of the near-term technologies evaluated in this study, electric vehicles; hybrid electric vehicles; compression-ignition, direct-injection vehicles; and E85 flexible fuel vehicles can reduce fuel-cycle GHG emissions by more than 25%, on the fuel-cycle basis. Electric vehicles powered by electricity generated primarily from nuclear and renewable sources can reduce GHG emissions by 80%. Other alternative fuels, such as compressed natural gas and liquefied petroleum gas, offer limited, but positive, GHG emission reduction benefits. Among the long-term technologies evaluated in this study, conventional spark ignition and compression ignition engines powered by alternative fuels and gasoline- and diesel-powered advanced vehicles can reduce GHG emissions by 10% to 30%. Ethanol dedicated vehicles, electric vehicles, hybrid electric vehicles, and fuel-cell vehicles can reduce GHG emissions by over 40%. Spark ignition engines and fuel-cell vehicles powered by cellulosic ethanol and solar hydrogen (for fuel-cell vehicles only) can reduce GHG emissions by over 80%. In conclusion, both near- and long-term alternative fuels and advanced transportation technologies can play a role in reducing the United States GHG emissions.

Summary of the transportation of spent fuel attitude survey

International Nuclear Information System (INIS)

Roop, E.; Price, D.L.; Paquet, V.L.

1992-01-01

The proposed repository at Yucca Mountain, Nevada will increase highway and railway transportation of spent fuel and high level nuclear wastes. The purpose of the survey was to determine the attitudes and differences in attitudes of important actors in the transportation of spent fuel. The three major areas of investigation were 1) perceived risks associated with the transportation of spent fuel, 2) confidence in the government and others responsible for transporting spent fuel, and 3) certain transportation requirements. Response was 34.3% of the original mailing and included: 193 safety personnel, 141 employees of the nuclear industry, 260 government employees, 34 native Americans, and 9 employees of environmental organizations. This paper summarizes overall and group attitudes and opinions for the three areas mentioned above. (author)

Deoxygenation of palm kernel oil to jet fuel-like hydrocarbons using Ni-MoS_2/γ-Al_2O_3 catalysts

International Nuclear Information System (INIS)

Itthibenchapong, Vorranutch; Srifa, Atthapon; Kaewmeesri, Rungnapa; Kidkhunthod, Pinit; Faungnawakij, Kajornsak

2017-01-01

Highlights: • The Ni-MoS_2/γ-Al_2O_3 catalysts synthesized using thiourea solution processing. • The Ni-MoS_2 showed semi-amorphous crystallinity with crystallite size of 5–10 nm. • The Ni K-edge XANES and EXAFS indicated the Ni substitution in MoS_2 structure. • A high yield of jet fuel-like hydrocarbon (>90%) from the palm kernel oil feedstock. • The HDO pathway was highly selective, while the DCO_2 and DCO pathways were minor. - Abstract: In the current study, palm kernel oil was used as a renewable feedstock for production of jet fuel-like hydrocarbons via the deoxygenation over the Ni-MoS_2/γ-Al_2O_3 catalyst. The dominant C12 fatty acid content in palm kernel oil makes it promising for jet fuel application. Synthesized by a liquid processing method with thiourea organosulfur agent, the catalyst revealed MoS_2 structure with low stacking, while Ni substitution in the MoS_2 structure and interaction with the Al_2O_3 support were determined based on the Ni K-edge XANES and EXAFS results. A high hydrodeoxygenation (HDO) activity, which as the major pathway in the deoxygenation, was observed upon application of a H_2 pressure of 30–50 bar over Ni-MoS_2/γ-Al_2O_3. The optimum product yield of approximately 92% was obtained mainly from the HDO pathway (∼60%) with 58% selectivity to C10–C12 jet fuel hydrocarbons. The flow property of the jet fuel-like hydrocarbons was more desirable than those obtained from palm olein oil-derived fuel.

Development of nuclear spent fuel Maritime transportation scenario

International Nuclear Information System (INIS)

Yoo, Min; Kang, Hyun Gook

2014-01-01

Spent fuel transportation of South Korea is to be conducted through near sea because it is able to ship a large amount of the spent fuel far from the public comparing to overland transportation. The maritime transportation is expected to be increased and its risk has to be assessed. For the risk assessment, this study utilizes the probabilistic safety assessment (PSA) method and the notions of the combined event. Risk assessment of maritime transportation of spent fuel is not well developed in comparison with overland transportation. For the assessment, first, the transportation scenario should be developed and categorized. Categories are assorted into the locations, release aspects and exposure aspects. This study deals with accident that happens on voyage and concentrated on ship-ship collision. The collision accident scenario is generated with event tree analysis. The scenario will be exploited for the maritime transportation risk model which includes consequence and accident probability

Development of nuclear spent fuel Maritime transportation scenario

Energy Technology Data Exchange (ETDEWEB)

Yoo, Min; Kang, Hyun Gook [KAIST, Daejeon (Korea, Republic of)

2014-08-15

Spent fuel transportation of South Korea is to be conducted through near sea because it is able to ship a large amount of the spent fuel far from the public comparing to overland transportation. The maritime transportation is expected to be increased and its risk has to be assessed. For the risk assessment, this study utilizes the probabilistic safety assessment (PSA) method and the notions of the combined event. Risk assessment of maritime transportation of spent fuel is not well developed in comparison with overland transportation. For the assessment, first, the transportation scenario should be developed and categorized. Categories are assorted into the locations, release aspects and exposure aspects. This study deals with accident that happens on voyage and concentrated on ship-ship collision. The collision accident scenario is generated with event tree analysis. The scenario will be exploited for the maritime transportation risk model which includes consequence and accident probability.

Risk of transporting spent nuclear fuel by train

International Nuclear Information System (INIS)

Elder, H.K.

1981-12-01

This paper presents results of a study which analyzes the risk of transporting spent fuel by train. The risk assessment methodology consists of 4 basic steps: (1) a description of the system being analyzed; (2) identification of sequences of events that could lead to a release of material during transportation; (3) evaluation of the probability and consequences of each release sequence; and (4) assessment of the risk and evaluation of the results. The conclusion reached was that considering the substantial benefits derived from the fuel, the current spent fuel transportation system poses reasonably low risks

Alternative Fuels Data Center: Biodiesel Truck Transports Capitol Christmas

Science.gov (United States)

Tree Biodiesel Truck Transports Capitol Christmas Tree to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Truck Transports Capitol Christmas Tree on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Truck Transports Capitol Christmas Tree on Twitter Bookmark Alternative

Impact of Transmutation Scenarios on Fuel Transportation

International Nuclear Information System (INIS)

Saturnin, A.; Duret, B.; Allou, A.; Jasserand, F.; Fillastre, E.; Giffard, F.X.; Chabert, C.; Caron-Charles, M.; Garzenne, C.; Laugier, F.

2015-01-01

Minor actinides transmutation scenarios have been studied in the frame of the French Sustainable Radioactive Waste Management Act of 28 June 2006. Transmutation scenarios supposed the introduction of a sodium-cooled fast reactor fleet using homogeneous or heterogeneous recycling modes for the minor actinides. Americium, neptunium and curium (MA) or americium alone (Am) can be transmuted together in a homogeneous way embedded in FR-MOX fuel or incorporated in MA or Am-Bearing radial Blankets (MABB or AmBB). MA transmutation in Accelerator Driven System has also been studied while plutonium is being recycled in SFR. Assessments and comparisons of these advanced cycles have been performed considering technical and economic criteria. Transportation needs for fresh and used transmutation fuels is one of these criteria. Transmutation fuels have specific characteristics in terms of thermal load and neutron emissions. Thermal, radiation and criticality constraints have been taken into account in this study to suggest cask concepts for routine conditions of transport, to estimate the number of assemblies to be transported in a cask and the number of annual transports. Comparison with the no transmutation option, i.e. management of uranium and plutonium in SFRs, is also presented. Regarding these matters, no high difficulties appear for assemblies with limited content of Am (homogeneous or heterogeneous recycling modes). When fuels contain curium, technical transport uncertainties increase because of the important heat release requiring dividing fresh fuels and technological innovations development (MABB and ADS). (authors)

Road transport fuels in europe: the explosion of demand for diesel fuel

International Nuclear Information System (INIS)

Bensaid, B.

2004-01-01

In the last 20 years, road transport fuel consumption has more than doubled in European countries, due to strong growth on the diesel passenger car segment and in the transport of road freight. In an economy heavily dependent on oil, European authorities are seeking to promote alternative energy solutions, such as motor fuels produced from biomass

Numerical simulation of ion transport membrane reactors: Oxygen permeation and transport and fuel conversion

KAUST Repository

Hong, Jongsup

2012-07-01

Ion transport membrane (ITM) based reactors have been suggested as a novel technology for several applications including fuel reforming and oxy-fuel combustion, which integrates air separation and fuel conversion while reducing complexity and the associated energy penalty. To utilize this technology more effectively, it is necessary to develop a better understanding of the fundamental processes of oxygen transport and fuel conversion in the immediate vicinity of the membrane. In this paper, a numerical model that spatially resolves the gas flow, transport and reactions is presented. The model incorporates detailed gas phase chemistry and transport. The model is used to express the oxygen permeation flux in terms of the oxygen concentrations at the membrane surface given data on the bulk concentration, which is necessary for cases when mass transfer limitations on the permeate side are important and for reactive flow modeling. The simulation results show the dependence of oxygen transport and fuel conversion on the geometry and flow parameters including the membrane temperature, feed and sweep gas flow, oxygen concentration in the feed and fuel concentration in the sweep gas. © 2012 Elsevier B.V.

Assessment of bio-fuel options for solid oxide fuel cell applications

Science.gov (United States)

Lin, Jiefeng

Rising concerns of inadequate petroleum supply, volatile crude oil price, and adverse environmental impacts from using fossil fuels have spurred the United States to promote bio-fuel domestic production and develop advanced energy systems such as fuel cells. The present dissertation analyzed the bio-fuel applications in a solid oxide fuel cell-based auxiliary power unit from environmental, economic, and technological perspectives. Life cycle assessment integrated with thermodynamics was applied to evaluate the environmental impacts (e.g., greenhouse gas emission, fossil energy consumption) of producing bio-fuels from waste biomass. Landfill gas from municipal solid wastes and biodiesel from waste cooking oil are both suggested as the promising bio-fuel options. A nonlinear optimization model was developed with a multi-objective optimization technique to analyze the economic aspect of biodiesel-ethanol-diesel ternary blends used in transportation sectors and capture the dynamic variables affecting bio-fuel productions and applications (e.g., market disturbances, bio-fuel tax credit, policy changes, fuel specification, and technological innovation). A single-tube catalytic reformer with rhodium/ceria-zirconia catalyst was used for autothermal reformation of various heavy hydrocarbon fuels (e.g., diesel, biodiesel, biodiesel-diesel, and biodiesel-ethanol-diesel) to produce a hydrogen-rich stream reformates suitable for use in solid oxide fuel cell systems. A customized mixing chamber was designed and integrated with the reformer to overcome the technical challenges of heavy hydrocarbon reformation. A thermodynamic analysis, based on total Gibbs free energy minimization, was implemented to optimize the operating environment for the reformations of various fuels. This was complimented by experimental investigations of fuel autothermal reformation. 25% biodiesel blended with 10% ethanol and 65% diesel was determined to be viable fuel for use on a truck travelling with

Transportation risks in the US nuclear fuel cycle

International Nuclear Information System (INIS)

Rhoads, R.E.; Andrews, W.B.

1980-01-01

Estimated risks associated with accidental releases of materials transported for each step of the nuclear fuel cycle are presented. The risk estimates include both immediate and latent fatilities caused by releases of these materials in transportation accidents. Studies of the risk of transporting yellowcake, fresh nuclear and low level wastes from the front end of the fuel cycle have not been completed. Existing information does permit estimates of the risks to be made. The estimates presented result from the very low hazards associated with release of these materials. These estimates are consistent with the results of other studies. The results show that risks from all the fuel cycle transportation steps are low. The results also indicate that the total transportation risks associated with the nuclear fuel cycle are distributed about evenly between the fuel supply end and waste management end of the cycle. Risks in the front end of the cycle result primarily from the chemical toxicity of the materials transported. The results of the risk analysis studies for transportation of nuclear fuel cycle materials are compared with the results for the three studies that have been completed for non-nuclear systems. The risk analysis methodology used in these studies identifies the complete spectrum of potential accident consequences and estimates the probability of events producing that level of consequence. The maximum number of fatalities predicted for each material is presented. A variety of risk measures have been used because of the inherent difficulties in making risk comparisons. Examination of a number of risk measures can provide additional insights and help guard against conclusions that are dependent on the way the risk information has been developed and displayed. The results indicate that the risks from transporting these materials are all relatively low in comparison to other risks in society

Design of a transportation cask for irradiated CANDU fuel

International Nuclear Information System (INIS)

Nash, K.E.; Gavin, M.E.

1983-01-01

A major step in the development of a large-scale transportation system for irradiated CANDU fuel is being made by Ontario Hydro in the design and construction of a demonstration cask by 1988/89. The system being designed is based on dry transportation with the eventual fully developed system providing for dry fuel loading and unloading. Research carried out to date has demonstrated that it is possible to transport irradiated CANDU fuel in a operationally efficient and simple manner without any damage which would prejudice subsequent automated fuel handling

Spent Fuel Transportation Package Performance Study - Experimental Design Challenges

International Nuclear Information System (INIS)

Snyder, A. M.; Murphy, A. J.; Sprung, J. L.; Ammerman, D. J.; Lopez, C.

2003-01-01

Numerous studies of spent nuclear fuel transportation accident risks have been performed since the late seventies that considered shipping container design and performance. Based in part on these studies, NRC has concluded that the level of protection provided by spent nuclear fuel transportation package designs under accident conditions is adequate. [1] Furthermore, actual spent nuclear fuel transport experience showcase a safety record that is exceptional and unparalleled when compared to other hazardous materials transportation shipments. There has never been a known or suspected release of the radioactive contents from an NRC-certified spent nuclear fuel cask as a result of a transportation accident. In 1999 the United States Nuclear Regulatory Commission (NRC) initiated a study, the Package Performance Study, to demonstrate the performance of spent fuel and spent fuel packages during severe transportation accidents. NRC is not studying or testing its current regulations, a s the rigorous regulatory accident conditions specified in 10 CFR Part 71 are adequate to ensure safe packaging and use. As part of this study, NRC currently plans on using detailed modeling followed by experimental testing to increase public confidence in the safety of spent nuclear fuel shipments. One of the aspects of this confirmatory research study is the commitment to solicit and consider public comment during the scoping phase and experimental design planning phase of this research

A system for transportation of hydrocarbons at sea; System for transport av hydrokarboner til havs

Energy Technology Data Exchange (ETDEWEB)

Breivik, K.; Smedal, A.

1997-04-01

To exploit the offshore oil and gas fields economically it is important to use suitable methods and equipment for transporting the oil and gas to the landing sites. The present invention concerns a system for transportation of hydrocarbons to the landing sites. It consists of one or more loading buoys and a number of preferably conventional tankers and at least one offshore loading ship arranged to receive hydrocarbons from the loading buoy to which it is connected by means of a coupling device in the ship`s bow. The tankers have in their sterns arrangements to convey the fluid through flexible tubes from complementary arrangements in the bow of the loading ship. The loading ship and the tanker have a position reference system for mutual dynamical positioning. The entire operation of connecting the tubes and transferring the fluid flow takes place with both ships moving, at least at steerage way. The invention aims to provide efficient use of the expensive special ships that are needed to communicate with the loading buoys. Another aim is to reduce the need for expensive specialized equipment onboard both the loading ships and the tankers. 5 figs.

Transport of MOX fuel from Europe to Japan; Transport de combustible mox d' Europe vers le Japon

Energy Technology Data Exchange (ETDEWEB)

NONE

2002-07-01

The MOX fuel transports from Europe to Japan represent a main part in the implementing of the Japan nuclear program. They complement the 160 transports of spent fuels realized from Japan to Europe and the vitrified residues return from France to Japan. In this framework the document presents the MOX fuel, the use of the MOX fuel in reactor, the proliferation risks, the MOX fuel transport to Japan, the public health, the transport regulations, the safety and the civil liability. (A.L.B.)

Sensor system for fuel transport vehicle

Science.gov (United States)

Earl, Dennis Duncan; McIntyre, Timothy J.; West, David L.

2016-03-22

An exemplary sensor system for a fuel transport vehicle can comprise a fuel marker sensor positioned between a fuel storage chamber of the vehicle and an access valve for the fuel storage chamber of the vehicle. The fuel marker sensor can be configured to measure one or more characteristics of one or more fuel markers present in the fuel adjacent the sensor, such as when the marked fuel is unloaded at a retail station. The one or more characteristics can comprise concentration and/or identity of the one or more fuel markers in the fuel. Based on the measured characteristics of the one or more fuel markers, the sensor system can identify the fuel and/or can determine whether the fuel has been adulterated after the marked fuel was last measured, such as when the marked fuel was loaded into the vehicle.

Studies of Lanthanide Transport in Metallic Fuel

Energy Technology Data Exchange (ETDEWEB)

Zhang, Jinsuo; Taylor, Christopher

2018-04-02

Metallic nuclear fuels were tested in fast reactor programs and performed well. However, metallic fuels have shown the phenomenon of FCCI that are due to deleterious reactions between lanthanide fission products and cladding material. As the burnup is increased, lanthanide fission products that contact with the cladding could react with cladding constituents such as iron and chrome. These reactions produce higher-melting intermetallic compounds and low-melting alloys, and weaken the mechanical integrity. The lanthanide interaction with clad in metallic fuels is recognized as a long-term, high-burnup cause of the clad failures. Therefore, one of the key concerns of using metallic fuels is the redistribution of lanthanide fission products and migration to the fuel surface. It is believed that lanthanide migration is in part due to the thermal gradient between the center and the fuel-cladding interface, but also largely in part due to the low solubility of lanthanides within the uranium-based metal fuel. PIE of EBR-II fuels shows that lanthanides precipitate directly and do not dissolve to an appreciable extent in the fuel matrix. Based on the PIE data from EBR-II, a recent study recommended a so-called “liquid-like” transport mechanism for lanthanides and certain other species. The liquid-like transport model readily accounts for redistribution of Ln, noble metal fission products, and cladding components in the fuel matrix. According to the novel mechanism, fission products can transport as solutes in liquid metals, such as liquid cesium or liquid cesium–sodium, and on pore surfaces and fracture surfaces for metals near their melting temperatures. Transport in such solutions is expected to be much more rapid than solid-state diffusion. The mechanism could explain the Ln migration to the fuel slug peripheral surface and their deposition with a sludge-like form. Lanthanides have high solubility in liquid cesium but have low solubility in liquid sodium. As a

Spent-fuel transportation - a success story

International Nuclear Information System (INIS)

Gertz, C.P.; Schoonen, D.H.; Wakeman, B.H.

1986-01-01

Spent nuclear fuel research and development (R and D) demonstrations and associated transportation activities are being performed as a part of the storage cask performance testing programs at the Idaho National Engineering Laboratory (INEL). These spent-fuel programs support the Nuclear Waste Policy Act (NWPA) and US Department of Energy (DOE) objectives for cooperative demonstrations with the utilities, testing at federal sites, and alternatives for viable transportation systems. A cooperative demonstration program with the private sector to develop dry storage technologies that the US Nuclear Regulatory Commission (NRC) can generically approve is in place as well as cost-shared dry storage R and D program at a federal facility to collect the necessary licensing data. In addition to the accomplishments in the cask performance and testing demonstrations, the long-distance transportation of a large number of spent-fuel assemblies is considered a success story. The evaluation and implementation of applicable requirements, industry perspective, and extensive planning all contributed to this achievement

Lifecycle analysis of renewable natural gas and hydrocarbon fuels from wastewater treatment plants’ sludge

Energy Technology Data Exchange (ETDEWEB)

Lee, Uisung [Argonne National Lab. (ANL), Argonne, IL (United States); Han, Jeongwoo [Argonne National Lab. (ANL), Argonne, IL (United States); Urgun Demirtas, Meltem [Argonne National Lab. (ANL), Argonne, IL (United States); Wang, Michael [Argonne National Lab. (ANL), Argonne, IL (United States); Tao, Ling [National Renewable Energy Lab. (NREL), Golden, CO (United States)

2016-09-01

Wastewater treatment plants (WWTPs) produce sludge as a byproduct when they treat wastewater. In the United States, over 8 million dry tons of sludge are produced annually just from publicly owned WWTPs. Sludge is commonly treated in anaerobic digesters, which generate biogas; the biogas is then largely flared to reduce emissions of methane, a potent greenhouse gas. Because sludge is quite homogeneous and has a high energy content, it is a good potential feedstock for other conversion processes that make biofuels, bioproducts, and power. For example, biogas from anaerobic digesters can be used to generate renewable natural gas (RNG), which can be further processed to produce compressed natural gas (CNG) and liquefied natural gas (LNG). Sludge can be directly converted into hydrocarbon liquid fuels via thermochemical processes such as hydrothermal liquefaction (HTL). Currently, the environmental impacts of converting sludge into energy are largely unknown, and only a few studies have focused on the environmental impacts of RNG produced from existing anaerobic digesters. As biofuels from sludge generate high interest, however, existing anaerobic digesters could be upgraded to technology with more economic potential and more environmental benefits. The environmental impacts of using a different anaerobic digestion (AD) technology to convert sludge into energy have yet to be analyzed. In addition, no studies are available about the direct conversion of sludge into liquid fuels. In order to estimate the energy consumption and greenhouse gas (GHG) emissions impacts of these alternative pathways (sludge-to-RNG and sludge-to-liquid), this study performed a lifecycle analysis (LCA) using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model. The energy uses and GHG emissions associated with the RNG and hydrocarbon liquid are analyzed relative to the current typical sludge management case, which consists of a single-stage mesophilic

Investigation of the ignition of liquid hydrocarbon fuels with nanoadditives

Science.gov (United States)

Bakulin, V. N.; Velikodnyi, V. Yu.; Levin, Yu. K.; Popov, V. V.

2017-12-01

During our experimental studies we showed a high efficiency of the influence of nanoparticle additives on the stability of the ignition of hydrocarbon fuels and the stabilization of their combustion in a highfrequency high-voltage discharge. We detected the effects of a jet deceleration, an increase in the volume of the combustible mixture, and a reduction in the inflammation delay time. These effects have been estimated quantitatively by digitally processing the video frames of the ignition of a bubbled kerosene jet with 0.5% graphene nanoparticle additives and without these additives. This effect has been explained by the influence of electrodynamic processes.

Thermodynamic analysis of synthetic hydrocarbon fuel production in pressurized solid oxide electrolysis cells

DEFF Research Database (Denmark)

Sun, Xiufu; Chen, Ming; Jensen, Søren Højgaard

2012-01-01

A promising way to store wind and solar electricity is by electrolysis of H2O and CO2 using solid oxide electrolysis cells (SOECs) to produce synthetic hydrocarbon fuels that can be used in existing fuel infrastructure. Pressurized operation decreases the cell internal resistance and enables...... improved system efficiency, potentially lowering the fuel production cost significantly. In this paper, we present a thermodynamic analysis of synthetic methane and dimethyl ether (DME) production using pressurized SOECs, in order to determine feasible operating conditions for producing the desired......, and outlet gas composition. For methane production, low temperature and high pressure operation could improve the system efficiency, but might lead to a higher capital cost. For DME production, high pressure SOEC operation necessitates higher operating temperature in order to avoid carbon formation at higher...

Agricultural transportation fuels

International Nuclear Information System (INIS)

Anon.

1993-01-01

The recommendations on the title subject are focused on the question whether advantages and disadvantages of agricultural fuels compared to fossil fuels justify the Dutch policy promotion of the use of agricultural products as basic materials for agricultural fuels. Attention is paid to energetic, environmental and economical aspects of both fuel types. Four options to apply agricultural transportation fuels are discussed: (1) 10% bio-ethanol in euro-unleaded gasoline for engines of passenger cars, equipped with a three-way catalyst; (2) the substitution of 15% methyl tertiair butyl ether (MTBE) by ethyl tertiair butyl ether (ETBE) as a substituent for lead in unleaded super plus gasoline (Sp 98) for engines of passenger cars, equipped with a three-way catalyst; (3) 50% KME (rapeseed oil ester) in low-sulfur diesel (0.05%S D) for engines of vans without a catalyst; and (4) the substitution of 0.05% S D by bio-ethanol or KME for buses with fuel-adjusted engines, equipped with a catalyst. Also the substitution by liquefied petroleum gas (LPG), compressed natural gas (CNG) or E 95 was investigated in option four. Each of the options investigated can contribute to a reduction of the use of fossil energy and the environmental effects of the use of fossil fuels, although some environmental effects from agricultural fuels must be taken into consideration. It is recommended to seriously pay attention to the promotion of agricultural fuels, not only in the Netherlands, but also in an international context. Policy instruments to be used in the stimulation of the use of such fuels are the existing European Community subsidies on fallow lands, exemption of the European Community energy levy, and the use of tax differentiation. Large-scale demonstration projects must be started to quantify hazardous emissions and to solve still existing technical problems. 8 figs., 3 tabs., refs., 4 appendices

Considerations for the transportation of spent fuel

International Nuclear Information System (INIS)

Jefferson, R.M.

1984-01-01

In our society today the transportation of radioactive materials, and most particularly spent reactor fuel, is surrounded by considerable emotion and a wealth of information, good and bad. The transportation of these materials is viewed as unique and distinct from the transportation of other hazardous materials and as a particularly vulnerable component of the nuclear power activities of this nation. Added to this is the concept, widely held, that almost everyone is an expert on the transportation of radioactive materials. One significant contribution to this level of emotion is the notion that all roads (rail and highway), on which these goods will be transported, somehow traverse everyone's backyard. The issue of the transportation of spent fuel has thus become a political battleground. Perhaps this should not be surprising since it has all of the right characteristics for such politicization in that it is pervasive, emotional, and visible. In order that those involved in the discussion of this activity might be able to reach some rational conclusions, this paper offers some background information which might be useful to a broad range of individuals in developing their own perspectives. The intent is to address the safety of transporting spent fuel from a technical standpoint without the emotional content which is frequently a part of this argument

Integrated risk assessment for spent fuel transportation using developed software

International Nuclear Information System (INIS)

Yun, Mi Rae; Christian, Robby; Kim, Bo Gyung; Almomani, Belal; Ham, Jae Hyun; Kang, Gook Hyun; Lee, Sang hoon

2016-01-01

As on-site spent fuel storage meets limitation of their capacity, spent fuel need to be transported to other place. In this research, risk of two ways of transportation method, maritime transportation and on-site transportation, and interim storage facility were analyzed. Easier and integrated risk assessment for spent fuel transportation will be possible by applying this software. Risk assessment for spent fuel transportation has not been researched and this work showed a case for analysis. By using this analysis method and developed software, regulators can get some insights for spent fuel transportation. For example, they can restrict specific region for preventing ocean accident and also they can arrange spend fuel in interim storage facility avoiding most risky region which have high risk from aircraft engine shaft. Finally, they can apply soft material on the floor for specific stage for on-site transportation. In this software, because we targeted Korea, we need to use Korean reference data. However, there were few Korean reference data. Especially, there was no food chain data for Korean ocean. In MARINRAD, they used steady state food chain model, but it is far from reality. Therefore, to get Korean realistic reference data, dynamic food chain model for Korean ocean need to be developed

Integrated risk assessment for spent fuel transportation using developed software

Energy Technology Data Exchange (ETDEWEB)

Yun, Mi Rae; Christian, Robby; Kim, Bo Gyung; Almomani, Belal; Ham, Jae Hyun; Kang, Gook Hyun [KAIST, Daejeon (Korea, Republic of); Lee, Sang hoon [Keimyung University, Daegu (Korea, Republic of)

2016-05-15

As on-site spent fuel storage meets limitation of their capacity, spent fuel need to be transported to other place. In this research, risk of two ways of transportation method, maritime transportation and on-site transportation, and interim storage facility were analyzed. Easier and integrated risk assessment for spent fuel transportation will be possible by applying this software. Risk assessment for spent fuel transportation has not been researched and this work showed a case for analysis. By using this analysis method and developed software, regulators can get some insights for spent fuel transportation. For example, they can restrict specific region for preventing ocean accident and also they can arrange spend fuel in interim storage facility avoiding most risky region which have high risk from aircraft engine shaft. Finally, they can apply soft material on the floor for specific stage for on-site transportation. In this software, because we targeted Korea, we need to use Korean reference data. However, there were few Korean reference data. Especially, there was no food chain data for Korean ocean. In MARINRAD, they used steady state food chain model, but it is far from reality. Therefore, to get Korean realistic reference data, dynamic food chain model for Korean ocean need to be developed.

Determination of prerequisites for the estimation of transportation cost of spent fuels

International Nuclear Information System (INIS)

Choi, Heui Joo; Lee, Jong Youl; Kim, Seong Ki; Cha, Jeong Hoon; Choi, Jong Won

2007-10-01

The cost for the spent fuel management includes the costs for the interim storage, the transportation, and the permanent disposal of the spent fuels. The scope of this report is limited to the cost for the spent fuel transportation. KAERI is developing a cost estimation method for the spent fuel transportation through a joint study with the French AREVA TN. Several prerequisites should be fixed in order to estimate the cost for the spent fuel transportation properly. In this report we produced them considering the Korean current status on the management of spent fuels. The representative characteristics of a spent fuel generated from the six nuclear reactors at the YG site were determined. Total 7,200 tons of spent fuels are projected with the lifespan of 60 years. As the transportation mode, sea transportation and road transportation is recommended considering the location of the YG site and the hypothetical Centralized Interim Storage Facility (CISF) and Final Repository (FR). The sea route and transportation time were analyzed by using a sea distance analysis program which the NORI (National Oceanographic Research Institute) supplies on a web. Based on the results of the analysis, the shipping rates were determined. The regulations related to the spent fuel transportation were reviewed. The characteristics of the transportation vessel and a trailer were suggested. The handling and transportation systems at the YG site, Centralized Interim Storage Facility, and the Final Repository were described in detail for the purpose of the cost estimation of the spent fuel transportation. From the detail description the major components of the transportation system were determined for the conceptual design. It is believed that the conceptual design of the transportation system developed in this report will be used for the analysis of transportation logistics and the cost estimation of spent fuels

High atmosphere–ocean exchange of semivolatile aromatic hydrocarbons

KAUST Repository

González-Gaya, Belén

2016-05-16

Polycyclic aromatic hydrocarbons, and other semivolatile aromatic-like compounds, are an important and ubiquitous fraction of organic matter in the environment. The occurrence of semivolatile aromatic hydrocarbons is due to anthropogenic sources such as incomplete combustion of fossil fuels or oil spills, and other biogenic sources. However, their global transport, fate and relevance for the carbon cycle have been poorly assessed, especially in terms of fluxes. Here we report a global assessment of the occurrence and atmosphere-ocean fluxes of 64 polycyclic aromatic hydrocarbons analysed in paired atmospheric and seawater samples from the tropical and subtropical Atlantic, Pacific and Indian oceans. The global atmospheric input of polycyclic aromatic hydrocarbons to the global ocean is estimated at 0.09 Tg per month, four times greater than the input from the Deepwater Horizon spill. Moreover, the environmental concentrations of total semivolatile aromatic-like compounds were 10 2 -10 3 times higher than those of the targeted polycyclic aromatic hydrocarbons, with a relevant contribution of an aromatic unresolved complex mixture. These concentrations drive a large global deposition of carbon, estimated at 400 Tg C yr -1, around 15% of the oceanic CO2 uptake. © 2016 Macmillan Publishers Limited.

Transport of nuclear used fuel and waste materials

Energy Technology Data Exchange (ETDEWEB)

Neau, H.J. [World Nuclear Transport Institute, London (United Kingdom)

2015-07-01

20 millions consignments of radioactive materials are routinely transported annually on public roads, railways and ships. 5% of these are nuclear fuel cycle related. International Atomic Energy Agency Regulations have been in force since 1961. The sector has an excellent safety record spanning over 50 years. Back end transport covers the operations concerned with spent fuel that leaves reactors and wastes. Since 1971, there have been 70,000 shipments of used fuel (i.e. over 80,000 tonnes) with no damage to property or person. The excellent safety record spanning over 50 years praised every year by the General Conference of the International Atomic Energy Agency. More than 200 sea voyages over a distance of more than 8 million kilometres of transport of used fuel or high-level wastes.

Environmental economics of lignin derived transport fuels

OpenAIRE

Obydenkova, SV; Kouris, P Panagiotis; Hensen, EJM Emiel; Heeres, Hero J; Boot, MD Michael

2017-01-01

This paper explores the environmental and economic aspects of fast pyrolytic conversion of lignin, obtained from 2G ethanol plants, to transport fuels for both the marine and automotive markets. Various scenarios are explored, pertaining to aggregation of lignin from several sites, alternative energy carries to replace lignin, transport modalities, and allocation methodology. The results highlight two critical factors that ultimately determine the economic and/or environmental fuel viability....

Some technical subjects on production of hydrocarbon fuel from synthetic gas

Energy Technology Data Exchange (ETDEWEB)

Suzuki, Takashi

1987-06-20

Since fuel oil meeting the requirements of current petroleum products can be produced by SASOL F-T synthetic process, the manufacturing process of hydrocarbon fuel oil from the coal-derived synthesis gas, downstream processes are being successively investigated. Mobile M-gasoline, MTG, process which produces gasoline from the natural gas-derived synthesis gas through methanol went into commercial operation in New Zealand in 1986. Although the gasoline suffices the quality of commercial gasoline by both fixed bed and fluidized bed systems, the price and service life of catalyst and control of by-product durene must be improved. Any STG processes have not been completed yet and the yield and quality of gasoline are inferior to those of gasoline produced by the MTG process. Applying two-stage process, the STG process will be more economically effective.(21 refs, 4 figs, 10 tabs)

Ethanol dehydration via azeotropic distillation with gasoline fractions as entrainers: A pilot-scale study of the manufacture of an ethanol–hydrocarbon fuel blend

OpenAIRE

Gomis Yagües, Vicente; Pedraza Berenguer, Ricardo; Saquete Ferrándiz, María Dolores; Font, Alicia; Garcia-Cano, Jorge

2015-01-01

We establish experimentally and through simulations the economic and technical viability of dehydrating ethanol by means of azeotropic distillation, using a hydrocarbon as entrainer. The purpose of this is to manufacture a ready-to-use ethanol–hydrocarbon fuel blend. In order to demonstrate the feasibility of this proposition, we have tested an azeotropic water–ethanol feed mixture, using a hydrocarbon as entrainer, in a semi pilot-plant scale distillation column. Four different hydrocarbons ...

Transport of MOX fuel from Europe to Japan; Transport de combustible mox d' Europe vers le Japon

Energy Technology Data Exchange (ETDEWEB)

NONE

2002-07-01

The MOX fuel transports from Europe to Japan represent a main part in the implementing of the Japan nuclear program. They complement the 160 transports of spent fuels realized from Japan to Europe and the vitrified residues return from France to Japan. In this framework the document presents the MOX fuel, the use of the MOX fuel in reactor, the proliferation risks, the MOX fuel transport to Japan, the public health, the transport regulations, the safety and the civil liability. (A.L.B.)

Dynamic characteristics of hydrocarbon fuel within the channel at supercritical and pyrolysis condition

Science.gov (United States)

Yu, Bin; Zhou, Weixing; Qin, Jiang; Bao, Wen

2017-12-01

Regenerative cooling with fuel as the coolant is used in the scramjet engine. In order to grasp the dynamic characteristics of engine fuel supply processes, this article studies the dynamic characteristics of hydrocarbon fuel within the channel. A one-dimensional dynamic model was proved, the thermal energy storage effect, fuel volume effect and chemical dynamic effect have been considered in the model, the ordinary differential equations were solved using a 4th order Runge-Kutta method. The precision of the model was validated by three groups of experimental data. The effects of input signal, working condition, tube size on the dynamic characteristics of pressure, flow rate, temperature have been simulated. It is found that cracking reaction increased the compressibility of the fuel pyrolysis mixture and lead to longer responding time of outlet flow. The responding time of outlet flow can reach 3s when tube is 5m long which will greatly influence the control performance of the engine thrust system. Meanwhile, when the inlet flow rate appears the step change, the inlet pressure leads to overshoot, the overshoot can reach as much as 100%, such highly transient impulse will result in detrimental effect on fuel pump.

Transport in porous media containing residual hydrocarbon. 2: Experiments

International Nuclear Information System (INIS)

Hatfield, K.; Ziegler, J.; Burris, D.R.

1993-01-01

When liquid hydrocarbons or nonaqueous-phase liquids (NAPLs) become entrapped below the water table, flowing ground waters carry soluble NAPL components away from the spill zone. Transport of these dissolved NAPL components is controlled by several processes including advection, dispersion, sorption to aquifer materials, and liquid-liquid partitioning. To better understand these processes, miscible displacement experiments were conducted to generate break-through curves (BTCs) of pentafluorobenzoic acid (PFBA), benzene, and toluene on sand column with and without a fixed decane residual. A departure from equilibrium transport is observed in BTCs from the sand-decane system. These BTCs show characteristics of early breakthrough, asymmetry, and tailing. The cause of nonequilibrium is hypothesized to be rate-limited solute exchange between decane and water. A new transport model, capable of handling time-dependent exchange processes, is successfully applied to reproduce experimental BATCs. Results indicate that time-dependent partitioning becomes increasingly important as the solute decane-water partition coefficient and the aqueous-phase fluid velocity increase

Safety evaluation on MOX new fuel at marine transport

International Nuclear Information System (INIS)

Tsumune, Daisuke; Ito, Chihiro; Saegusa, Toshiari; Maruyama, Koki

2000-01-01

In the Central Research Institute of Electric Power Industry, in order to confirm effects of MOX new fuel on the public are as small as possible even when its marine transport goes down, some exposed radiation dose has previously conducted on imaginary shipwreck of marine transport on used nuclear fuel, plutonium dioxide, and high level return glass solid. Under a base of such informations, some investigations on safety on marine transport of the MOX new fuel was conducted. On September, 1999, five transport vessels of the MOX new fuel was at first transported on marine. The value of five times of estimated exposed radiation dose (max. 8.1 x 10 -8 mSv/y) corresponds to an evaluation result assumed by shipwreck in marine transport this time. As a result, it was found that the exposed radiation dose estimated on this case would be sufficiently less than an effective dose equivalent limit (1 mSv/y) of public exposure according to the recommendation of ICRP in both coastal and oceanic areas. (G.K.)

Transport phenomena in fuel cells : from microscale to macroscale

Energy Technology Data Exchange (ETDEWEB)

Djilali, N. [Victoria Univ., BC (Canada). Dept. of Mechanical Engineering]|[Victoria Univ., BC (Canada). Inst. for Integrated Energy Systems

2006-07-01

Proton Exchange Membrane (PEM) fuel cells rely on an array of thermofluid transport processes for the regulated supply of reactant gases and the removal of by-product heat and water. Flows are characterized by a broad range of length and time scales that take place in conjunction with reaction kinetics in a variety of regimes and structures. This paper examined some of the challenges related to computational fluid dynamics (CFD) modelling of PEM fuel cell transport phenomena. An overview of the main features, components and operation of PEM fuel cells was followed by a discussion of the various strategies used for component modelling of the electrolyte membrane; the gas diffusion layer; microporous layer; and flow channels. A review of integrated CFD models for PEM fuel cells included the coupling of electrochemical thermal and fluid transport with 3-D unit cell simulations; air-breathing micro-structured fuel cells; and stack level modelling. Physical models for modelling of transport at the micro-scale were also discussed. Results of the review indicated that the treatment of electrochemical reactions in a PEM fuel cell currently combines classical reaction kinetics with solutions procedures to resolve charged species transport, which may lead to thermodynamically inconsistent solutions for more complex systems. Proper representation of the surface coverage of all the chemical species at all reaction sites is needed, and secondary reactions such as platinum (Pt) dissolution and oxidation must be accounted for in order to model and understand degradation mechanisms in fuel cells. While progress has been made in CFD-based modelling of fuel cells, functional and predictive capabilities remain a challenge because of fundamental modelling and material characterization deficiencies in ionic and water transport in polymer membranes; 2-phase transport in porous gas diffusion electrodes and gas flow channels; inadequate macroscopic modelling and resolution of catalyst

NEW MATERIAL NEEDS FOR HYDROCARBON FUEL PROCESSING: Generating Hydrogen for the PEM Fuel Cell

Science.gov (United States)

Farrauto, R.; Hwang, S.; Shore, L.; Ruettinger, W.; Lampert, J.; Giroux, T.; Liu, Y.; Ilinich, O.

2003-08-01

The hydrogen economy is fast approaching as petroleum reserves are rapidly consumed. The fuel cell promises to deliver clean and efficient power by combining hydrogen and oxygen in a simple electrochemical device that directly converts chemical energy to electrical energy. Hydrogen, the most plentiful element available, can be extracted from water by electrolysis. One can imagine capturing energy from the sun and wind and/or from the depths of the earth to provide the necessary power for electrolysis. Alternative energy sources such as these are the promise for the future, but for now they are not feasible for power needs across the globe. A transitional solution is required to convert certain hydrocarbon fuels to hydrogen. These fuels must be available through existing infrastructures such as the natural gas pipeline. The present review discusses the catalyst and adsorbent technologies under development for the extraction of hydrogen from natural gas to meet the requirements for the proton exchange membrane (PEM) fuel cell. The primary market is for residential applications, where pipeline natural gas will be the source of H2 used to power the home. Other applications including the reforming of methanol for portable power applications such as laptop computers, cellular phones, and personnel digital equipment are also discussed. Processing natural gas containing sulfur requires many materials, for example, adsorbents for desulfurization, and heterogeneous catalysts for reforming (either autothermal or steam reforming) water gas shift, preferential oxidation of CO, and anode tail gas combustion. All these technologies are discussed for natural gas and to a limited extent for reforming methanol.

Airbreathing Propulsion Fuels and Energy Exploratory Research and Development (APFEERD) Sub Task: Review of Bulk Physical Properties of Synthesized Hydrocarbon:Kerosenes and Blends

Science.gov (United States)

2017-06-01

Fuels and Energy Branch Turbine Engine Division Turbine Engine Division CHARLES W. STEVENS, Lead Engineer Turbine Engine Division Aerospace Systems...evaluation concludes, based on fundamental physical chemistry , that all hydrocarbon kerosenes that meet the minimum density requirement will have bulk...alternative jet fuels; renewable jet fuel; fuel physical properties; fuel chemistry ; fuel properties 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF

Regulation on the transport of nuclear fuel materials by vehicles

International Nuclear Information System (INIS)

1984-01-01

The regulations applying to the transport of nuclear fuel materials by vehicles, mentioned in the law for the regulations of nuclear source materials, nuclear fuel materials and reactors. The transport is for outside of the factories and the site of enterprises by such modes of transport as rail, trucks, etc. Covered are the following: definitions of terms, places of fuel materials handling, loading methods, limitations on mix loading with other cargo, radiation dose rates concerning the containers and the vehicles, transport indexes, signs and indications, limitations on train linkage during transport by rail, security guards, transport of empty containers, etc. together with ordinary rail cargo and so on. (Mori, K.)

Conversion of Dimethyl Ether to Branched Hydrocarbons Over Cu/BEA: the Roles of Lewis Acidic and Metallic Sites in H2 Incorporation

Energy Technology Data Exchange (ETDEWEB)

Hensley, Jesse E.; Schaidle, Joshua A.; Ruddy, Daniel A.; Cheah, Singfoong; Habas, Susan E.; Pan, Ming; Zhang, Guanghui; Miller, Jeffrey T.

2017-04-26

Conversion of biomass to fuels remains as one of the most promising approach to support our energy needs. It has been previously shown that the gasification of non-edible cellulosic biomass can be used to derive fuels like methanol and dimethyl ether (DME). However, the use of methanol and DME is limited due to the fact that they have low energy densities, poor lubricity and lower viscosity when compared to long-chain hydrocarbons. Increasing the blending percentage can also lead to undesired amounts of oxygenated molecules in the transportation fuel infrastructure, which restrict their applicability as jet or diesel fuels. Consequently, the petroleum-derived hydrocarbons remain as the main constituent of the middle-distillate based fuels. One way to increase the share of biofuels in middle-distillates is to use methanol/DME as building blocks for producing renewable, energy-dense hydrocarbons. One way to achieve this is by catalytically converting the DME and methanol to light olefins, followed by oligomerization to higher molecular weight premium alkanes, which can directly be used as kerosene/diesel fuels. Here, we report the catalytic dimerization of biomass-derived deoxygenated olefins into transportation fuel-range hydrocarbons under liquid-phase stirred-batch conditions. Specifically, the effect of operating conditions, such as reaction temperature, solvent-type, reaction duration and olefin-structure, on the conversion, selectivity and kinetics of dimerization of triptene (2,3,3-trimethyl-1-butene) were investigated. Triptene, as previously reported, is one of the major products of DME-homologation reaction over a BEA zeolite4. We show that triptene can be converted to high quality middle-distillates using a commercially available ion-exchange acid resin, Amberlyst-35 (dry) by the process of catalytic dimerization.

Fuel cell development for transportation: Catalyst development

Energy Technology Data Exchange (ETDEWEB)

Doddapaneni, N. [Sandia National Lab., Albuquerque, NM (United States)

1996-04-01

Fuel cells are being considered as alternate power sources for transportation and stationary applications. With proton exchange membrane (PEM) fuel cells the fuel crossover to cathodes causes severe thermal management and cell voltage drop due to oxidation of fuel at the platinized cathodes. The main goal of this project was to design, synthesize, and evaluate stable and inexpensive transition metal macrocyclic catalysts for the reduction of oxygen and be electrochemically inert towards anode fuels such as hydrogen and methanol.

World-wide French experience in research reactor fuel cycle transportation

International Nuclear Information System (INIS)

Raisonnier, D.

1997-01-01

Since 1963 Transnucleaire has safely performed a large number of national and international transports of radioactive material. Transnucleaire has also designed and supplied suitable packagings for all types of nuclear fuel cycle radioactive material from front-end and back-end products and for power or for research reactors. Transportation of the nuclear fuel material for power reactors is made on a regular and industrial basis. The transportation of material for the research reactor fuel cycle is quite different due to the small quantities involved, the categorisation of material and the numerous places of delivery world-wide. Adapted solutions exist, which require a reactive organisation dealing with all the transportation issues for LEU and HEU products as metal, oxide, fresh fuel elements, spent fuel elements including supply of necessary transport packaging and equipment. This presentation will: - explain the choices made by Transnucleaire and its associates to provide and optimise the corresponding services, - demonstrate the capability to achieve, through reliable partnership, transport operations involving new routes, specific equipment and new political constraints while respecting sophisticated safety and security regulations. (author)

Experience feedback from the transportation of Framatome fuel assemblies

International Nuclear Information System (INIS)

Robin, M.E.; Gaillard, G.; Aubin, C.

1998-01-01

Framatome, the foremost world nuclear fuel manufacturer, has for 25 years been delivering fuel elements from its three factories (Dessel, Romans, Pierrelatte) to the various sites in France and abroad (Germany, Sweden, Belgium, China, Korea, South Africa, Switzerland). During this period, Framatome has built up experience and expertise in fuel element transportation by road, rail and sea. In this filed, the range of constraints is very wide: safety and environmental protection constraints; constraints arising from the control and protection of nuclear materials, contractual and financial constraints, media watchdogs. Through the experience feedback from the transportation of FRAMATOME assemblies, this paper addresses all the phases in the transportation of fresh fuel assemblies. (authors)

Standardized, utility-DOE compatible, spent fuel storage-transport systems

International Nuclear Information System (INIS)

Smith, M.L.

1991-01-01

Virginia Power has developed and licensed a facility for dry storage of spent nuclear fuel in metal spent fuel storage casks. The modifications to the design of these casks necessary for licensing for both storage and transport of spent fuel are discussed along with the operational advantages of dual purpose storage-transport casks. Dual purpose casks can be used for storage at utility and DOE sites (MRS or repository) and for shipment between these sites with minimal spent fuel handling. The cost for a standardized system of casks that are compatible for use at both DOE and utility sites is discussed along with possible arrangements for sharing both the cost and benefits of dual purpose storage-transport casks

A comparison of hydrogen, methanol and gasoline as fuels for fuel cell vehicles: implications for vehicle design and infrastructure development

Science.gov (United States)

Ogden, Joan M.; Steinbugler, Margaret M.; Kreutz, Thomas G.

All fuel cells currently being developed for near term use in electric vehicles require hydrogen as a fuel. Hydrogen can be stored directly or produced onboard the vehicle by reforming methanol, or hydrocarbon fuels derived from crude oil (e.g., gasoline, diesel, or middle distillates). The vehicle design is simpler with direct hydrogen storage, but requires developing a more complex refueling infrastructure. In this paper, we present modeling results comparing three leading options for fuel storage onboard fuel cell vehicles: (a) compressed gas hydrogen storage, (b) onboard steam reforming of methanol, (c) onboard partial oxidation (POX) of hydrocarbon fuels derived from crude oil. We have developed a fuel cell vehicle model, including detailed models of onboard fuel processors. This allows us to compare the vehicle performance, fuel economy, weight, and cost for various vehicle parameters, fuel storage choices and driving cycles. The infrastructure requirements are also compared for gaseous hydrogen, methanol and gasoline, including the added costs of fuel production, storage, distribution and refueling stations. The delivered fuel cost, total lifecycle cost of transportation, and capital cost of infrastructure development are estimated for each alternative. Considering both vehicle and infrastructure issues, possible fuel strategies leading to the commercialization of fuel cell vehicles are discussed.

Modeling the highway transportation of spent fuel

International Nuclear Information System (INIS)

Harrison, I.G.

1986-01-01

There will be a substantial increase in the number of spent fuel shipments on the nation's highway system in the next thirty years. Most of the spent fuel will be moving from reactors to a spent fuel repository. This study develops two models that evaluate the risk and cost of moving the spent fuel. The Minimum Total Transport Risk Model (MTTRM) seeks an efficient solution for this problem by finding the minimum risk path through the network and sending all the spent fuel shipments over this one path. The Equilibrium Transport Risk Model (ETRM) finds an equitable solution by distributing the shipments over a number of paths in the network. This model decreases the risk along individual paths, but increases society's risk because the spent fuel shipments are traveling over more links in the network. The study finds that there is a trade off between path risk and societal risk. As path risk declines, societal risk rises. The cost of shipping also increases as the number of paths expand. The cost and risk of shipping spent fuel from ten reactors to four potential repository sites are evaluated using the MTTRM. The temporary monitored retrievable storage (MRS) facility in Tennessee is found to be the minimum cost and minimum risk solution. When direct shipment to the permanent sites is considered, Deaf Smith, Texas is the least cost and least incident free transport risk location. Yucca Mountain, Nevada is the least risk location when the focus is placed on the potential consequences of an accident

Transportation of spent fuel from light water reactors

International Nuclear Information System (INIS)

Bernard, H.

1993-01-01

The French 'Compagnie Generale des Matieres Nucleaires' - COGEMA - is involved in the whole nuclear fuel cycle about 20 years. Among the different parts of the cycle, the Transport of Radioactive Materials, acting as a link between the differents plants has a great importance. As nuclear material transportation is the only fuel cycle step to be performed on public grounds, the industrial task has to be performed with the utmost stringent safety criteria. COGEMA and associates is now operating a fully mature commercial activity, with some 300 spent fuel shipments per year from its reprocessing customer's reactors to the LA HAGUE plant, either by rail, road or sea. The paper will review the organization of COGEMA transportation business, the level of technology with an update of the casks used for spent fuel, and the operational experience, with a particular view of the maintenance policy. (author)

Hydrocarbon emission fingerprints from contemporary vehicle/engine technologies with conventional and new fuels

Science.gov (United States)

Montero, Larisse; Duane, Matthew; Manfredi, Urbano; Astorga, Covadonga; Martini, Giorgio; Carriero, Massimo; Krasenbrink, Alois; Larsen, B. R.

2010-06-01

The present paper presents results from the analysis of 29 individual C 2-C 9 hydrocarbons (HCs) specified in the European Commission Ozone Directive. The 29 HCs are measured in exhaust from common, contemporary vehicle/engine/fuel technologies for which very little or no data is available in the literature. The obtained HC emission fingerprints are compared with fingerprints deriving from technologies that are being phased out in Europe. Based on the total of 138 emission tests, thirteen type-specific fingerprints are extracted (Mean ± SD percentage contributions from individual HCs to the total mass of the 29 HCs), essential for receptor modelling source apportionment. The different types represent exhaust from Euro3 and Euro4 light-duty (LD) diesel and petrol-vehicles, Euro3 heavy-duty (HD) diesel exhaust, and exhaust from 2-stroke preEuro, Euro1 and Euro2 mopeds. The fuels comprise liquefied petroleum gas, petrol/ethanol blends (0-85% ethanol), and mineral diesel in various blends (0-100%) with fatty acid methyl esters, rapeseed methyl esters palm oil methyl esters, soybean oil methyl or sunflower oil methyl esters. Type-specific tracer compounds (markers) are identified for the various vehicle/engine/fuel technologies. An important finding is an insignificant effect on the HC fingerprints of varying the test driving cycle, indicating that combining HC fingerprints from different emission studies for receptor modelling purposes would be a robust approach. The obtained results are discussed in the context of atmospheric ozone formation and health implications from emissions (mg km -1 for LD and mopeds and mg kW h -1 for HD, all normalised to fuel consumption: mg dm -3 fuel) of the harmful HCs, benzene and 1,3-butadiene. Another important finding is a strong linear correlation of the regulated "total" hydrocarbon emissions (tot-HC) with the ozone formation potential of the 29 HCs (ΣPO 3 = (1.66 ± 0.04) × tot-RH; r2 = 0.93). Tot-HC is routinely monitored in

Valorization of Waste Lipids through Hydrothermal Catalytic Conversion to Liquid Hydrocarbon Fuels with in Situ Hydrogen Production

Energy Technology Data Exchange (ETDEWEB)

Kim, Dongwook; Vardon, Derek R.; Murali, Dheeptha; Sharma, Brajendra K.; Strathmann, Timothy J.

2016-03-07

We demonstrate hydrothermal (300 degrees C, 10 MPa) catalytic conversion of real waste lipids (e.g., waste vegetable oil, sewer trap grease) to liquid hydrocarbon fuels without net need for external chemical inputs (e.g., H2 gas, methanol). A supported bimetallic catalyst (Pt-Re/C; 5 wt % of each metal) previously shown to catalyze both aqueous phase reforming of glycerol (a triacylglyceride lipid hydrolysis coproduct) to H2 gas and conversion of oleic and stearic acid, model unsaturated and saturated fatty acids, to linear alkanes was applied to process real waste lipid feedstocks in water. For reactions conducted with an initially inert headspace gas (N2), waste vegetable oil (WVO) was fully converted into linear hydrocarbons (C15-C17) and other hydrolyzed byproducts within 4.5 h, and H2 gas production was observed. Addition of H2 to the initial reactor headspace accelerated conversion, but net H2 production was still observed, in agreement with results obtained for aqueous mixtures containing model fatty acids and glycerol. Conversion to liquid hydrocarbons with net H2 production was also observed for a range of other waste lipid feedstocks (animal fat residuals, sewer trap grease, dry distiller's grain oil, coffee oil residual). These findings demonstrate potential for valorization of waste lipids through conversion to hydrocarbons that are more compatible with current petroleum-based liquid fuels than the biodiesel and biogas products of conventional waste lipid processing technologies.

Alternative transportation fuels in the USA: government hydrogen vehicle programs

International Nuclear Information System (INIS)

Cannon, J.S.

1993-01-01

The linkage between natural gas-based transportation and hydrogen-based transportation strategies, two clean burning gaseous fuels, provides a strong policy rationale for increased government sponsorship of hydrogen vehicle research and demonstration programs. Existing federal and state government hydrogen vehicle projects are discussed in this paper: research at the NREL, alternate-fueled buses, Renewable Hydrogen for the State of Hawaii program, New York state alternative transportation fuels program, Colorado program. 9 refs

Integrated modeling for optimized regional transportation with compressed natural gas fuel

Directory of Open Access Journals (Sweden)

Hossam A. Gabbar

2016-03-01

Full Text Available Transportation represents major energy consumption where fuel is considered as a primary energy source. Recent development in the vehicle technology revealed possible economical improvements when using natural gas as a fuel source instead of traditional gasoline. There are several fuel alternatives such as electricity, which showed potential for future long-term transportation. However, the move from current situation where gasoline vehicle is dominating shows high cost compared to compressed natural gas vehicle. This paper presents modeling and simulation methodology to optimize performance of transportation based on quantitative study of the risk-based performance of regional transportation. Emission estimation method is demonstrated and used to optimize transportation strategies based on life cycle costing. Different fuel supply scenarios are synthesized and evaluated, which showed strategic use of natural gas as a fuel supply.

Determination of catalyst residues in hydrocarbon fuels by instrumental neutron activation analysis

International Nuclear Information System (INIS)

Burgess, D.D.

1982-01-01

A procedure has been developed for the determination of entrained catalytic cracking catalyst in hydrocarbon fuels. Aluminium is measured by instrumental neutron activation analysis and the amount of catalyst present is calculated from the amount of aluminium found and the known composition of the catalyst. Entrained catalyst may be determined at levels above 3 ppm with a precision of +-2%-25% according to sample composition. Only simple procedures are required. Vanadium may reduce sensitivity by dead time and pulse pile-up. No other interferences were observed. (author)

Synthetic fuel production via carbon neutral cycles with high temperature nuclear reactors as a power source

Energy Technology Data Exchange (ETDEWEB)

Konarek, E.; Coulas, B.; Sarvinis, J. [Hatch Ltd., Mississauga, Ontario (Canada)

2016-06-15

This paper analyzes a number of carbon neutral cycles, which could be used to produce synthetic hydrocarbon fuels. Synthetic hydrocarbons are produced via the synthesis of Carbon Monoxide and Hydrogen. The . cycles considered will either utilize Gasification processes, or carbon capture as a source of feed material. In addition the cycles will be coupled to a small modular Nuclear Reactor (SMR) as a power and heat source. The goal of this analysis is to reduce or eliminate the need to transport diesel and other fossil fuels to remote regions and to provide a carbon neutral, locally produced hydrocarbon fuel for remote communities. The technical advantages as well as the economic case are discussed for each of the cycles presented. (author)

Synthetic fuel production via carbon neutral cycles with high temperature nuclear reactors as a power source

International Nuclear Information System (INIS)

Konarek, E.; Coulas, B.; Sarvinis, J.

2016-01-01

This paper analyzes a number of carbon neutral cycles, which could be used to produce synthetic hydrocarbon fuels. Synthetic hydrocarbons are produced via the synthesis of Carbon Monoxide and Hydrogen. The . cycles considered will either utilize Gasification processes, or carbon capture as a source of feed material. In addition the cycles will be coupled to a small modular Nuclear Reactor (SMR) as a power and heat source. The goal of this analysis is to reduce or eliminate the need to transport diesel and other fossil fuels to remote regions and to provide a carbon neutral, locally produced hydrocarbon fuel for remote communities. The technical advantages as well as the economic case are discussed for each of the cycles presented. (author)

INTERACTION OF AIR TRANSPORTATION AND FUEL-SUPPLY COMPANIES

Directory of Open Access Journals (Sweden)

I. P. Zheleznaya

2014-01-01

Full Text Available The article describes the role of aviation fuel in the life of air transport. Fueling industry worldwide solves two main tasks - ensuring the safety and economy of air traffic. In Russia, there is one more task of airlines fuel supply. The article deals with fuel pricing taking into consideration today's realities.

An Indian perspective for transportation and storage of spent fuel

International Nuclear Information System (INIS)

Dey, P.K.

2005-01-01

The spent fuel discharged from the reactors are temporarily stored at the reactor pool. After a certain cooling time, the spent fuel is moved to the storage locations either on or off reactor site depending on the spent fuel management strategy. As India has opted for a closed fuel cycle for its nuclear energy development, reprocessing of the spent fuel, recycling of the reprocessed plutonium and uranium and disposal of the wastes from the reprocessing operations forms the spent fuel management strategy. Since the reprocessing operations are planned to match the nuclear energy programme, storage of the spent fuel in ponds are adopted prior to reprocessing. Transport of the spent fuel to the storage locations are carried out adhering to international and national guide lines. India is having 14 operating power reactors and three research reactors. The spent fuel from the two safeguarded BWRs are stored at-reactor (AR) storage pond. A separate wet storage facility away-from-reactor (AFR) has been designed, constructed and made operational since 1991 for additional fuel storage. Storage facilities are provided in ARs at other reactor locations to cater to 10 reactor-years of operation. A much lower capacity spent fuel storage is provided in reprocessing plants on the same lines of AR fuel storage design. Since the reprocessing operations are carried out on a need basis, to cater to the increased storage needs two new spent fuel storage facilities (SFSF) are being designed and constructed near the existing nuclear plant sites. India has mastered the technology for design, construction and operation of wet spent fuel storage facility meeting all the international standards Wet storage of the spent fuel is the most commonly adopted mode all over the world. Recently an alternate mode viz. dry storage has also been considered. India has designed, constructed and operated lead shielded dry storage casks and is operational at one site. A dry storage cask made of concrete

Environmental economics of lignin derived transport fuels.

Science.gov (United States)

Obydenkova, Svetlana V; Kouris, Panos D; Hensen, Emiel J M; Heeres, Hero J; Boot, Michael D

2017-11-01

This paper explores the environmental and economic aspects of fast pyrolytic conversion of lignin, obtained from 2G ethanol plants, to transport fuels for both the marine and automotive markets. Various scenarios are explored, pertaining to aggregation of lignin from several sites, alternative energy carries to replace lignin, transport modalities, and allocation methodology. The results highlight two critical factors that ultimately determine the economic and/or environmental fuel viability. The first factor, the logistics scheme, exhibited the disadvantage of the centralized approach, owing to prohibitively expensive transportation costs of the low energy-dense lignin. Life cycle analysis (LCA) displayed the second critical factor related to alternative energy carrier selection. Natural gas (NG) chosen over additional biomass boosts well-to-wheel greenhouse gas emissions (WTW GHG) to a level incompatible with the reduction targets set by the U.S. renewable fuel standard (RFS). Adversely, the process' economics revealed higher profits vs. fossil energy carrier. Copyright © 2017 The Author(s). Published by Elsevier Ltd.. All rights reserved.

Proceedings of the 2008 transportation technologies and fuels forum

International Nuclear Information System (INIS)

2008-01-01

As a large emitter of pollutants, the transportation industry is now seeking to develop a sustainable transportation plan for the future by developing methods of reducing emissions and improving the fuel efficiency of vehicles. This forum discussed recent innovations in vehicle transportation technologies. Industry leaders, government representatives, and researchers discussed methods of reducing greenhouse gases (GHGs) and air pollution in the transportation sector. Advanced combustion technologies were outlined, and recent developments in hybrid electric-powered vehicles were discussed. Research related to fuel cells, hydrogen fuels and biofuels was presented. The impacts of polluting vehicles on public health were also discussed. The forum was divided into the following 5 sessions: (1) setting the scene, (2) future fuels, (3) emissions, (4) EVs now, and (5) the road to the future. The sessions were followed by a panel on technology roadmaps. The forum featured 14 presentations, of which 4 have been catalogued separately for inclusion in this database. tabs., figs.

Drop analysis for structural integrity evaluation of KJRR fuel transport container

International Nuclear Information System (INIS)

Yang, Yun Young; Lim, Jong Min; Choi, Woo Seok; Lee, Ju Chan

2016-01-01

A fuel transport container for KiJang Research Reactor(KJRR) has been developed to transport fresh fuel assemblies and fission molly targets which are used for a research reactor built in Kijang. The KJRR fuel transport container is a type-A(F) container, which is defined in domestic and foreign regulations of a radioactive substance container. According to Nuclear Safety and Security Commission's notification, the container should meet the accident conditions defined in IAEA safety Standard Series, US NRC and etc. In this study, a structural integrity of the KJRR fuel transport container is evaluated by conducting computational analyses of 9-meter free drop and 1 meter puncture. It is confirmed that structural integrity of the KJRR fuel transport container can be maintained in the transportation accident condition. Hereafter, when the test model is produced, a safety test will be conducted and its result will be compared with the result of drop and puncture analyses.

Numerical simulation of ion transport membrane reactors: Oxygen permeation and transport and fuel conversion

KAUST Repository

Hong, Jongsup; Kirchen, Patrick; Ghoniem, Ahmed F.

2012-01-01

Ion transport membrane (ITM) based reactors have been suggested as a novel technology for several applications including fuel reforming and oxy-fuel combustion, which integrates air separation and fuel conversion while reducing complexity

Spent fuel transportation in the United States: commercial spent fuel shipments through December 1984

International Nuclear Information System (INIS)

1986-04-01

This report has been prepared to provide updated transportation information on light water reactor (LWR) spent fuel in the United States. Historical data are presented on the quantities of spent fuel shipped from individual reactors on an annual basis and their shipping destinations. Specifically, a tabulation is provided for each present-fuel shipment that lists utility and plant of origin, destination and number of spent-fuel assemblies shipped. For all annual shipping campaigns between 1980 and 1984, the actual numbers of spent-fuel shipments are defined. The shipments are tabulated by year, and the mode of shipment and the casks utilized in shipment are included. The data consist of the current spent-fuel inventories at each of the operating reactors as of December 31, 1984. This report presents historical data on all commercial spent-fuel transportation shipments have occurred in the United States through December 31, 1984

Proton conducting hydrocarbon membranes: Performance evaluation for room temperature direct methanol fuel cells

International Nuclear Information System (INIS)

Krivobokov, Ivan M.; Gribov, Evgeniy N.; Okunev, Alexey G.

2011-01-01

The methanol permeability, proton conductivity, water uptake and power densities of direct methanol fuel cells (DMFCs) at room temperature are reported for sulfonated hydrocarbon (sHC) and perfluorinated (PFSA) membranes from Fumatech, and compared to Nafion membranes. The sHC membranes exhibit lower proton conductivity (25-40 mS cm -1 vs. ∼95-40 mS cm -1 for Nafion) as well as lower methanol permeability (1.8-3.9 x 10 -7 cm 2 s -1 vs. 2.4-3.4 x 10 -6 cm 2 s -1 for Nafion). Water uptake was similar for all membranes (18-25 wt%), except for the PFSA membrane (14 wt%). Methanol uptake varied from 67 wt% for Nafion to 17 wt% for PFSA. The power density of Nafion in DMFCs at room temperature decreases with membrane thickness from 26 mW cm -2 for Nafion 117 to 12.5 mW cm -2 for Nafion 112. The maximum power density of the Fumatech membranes ranges from 4 to 13 mW cm -1 . Conventional transport parameters such as membrane selectivity fail to predict membrane performance in DMFCs. Reliable and easily interpretable results are obtained when the power density is plotted as a function of the transport factor (TF), which is the product of proton concentration in the swollen membrane and the methanol flux. At low TF values, cell performance is limited by low proton conductivity, whereas at high TF values it decreases due to methanol crossover. The highest maximum power density corresponds to intermediate values of TF.

Demonstration of a transportable storage system for spent nuclear fuel

International Nuclear Information System (INIS)

Shetler, J.R.; Miller, K.R.; Jones, R.E.

1993-01-01

The purpose of this paper is to discuss the joint demonstration project between the Sacramento Municipal Utility District (SMUD) and the US Department of Energy (DOE) regarding the use of a transportable storage system for the long-term storage and subsequent transport of spent nuclear fuel. SMUD's Rancho Seco nuclear generating station was shut down permanently in June 1989. After the shutdown, SMUD began planning the decommissioning process, including the disposition of the spent nuclear fuel. Concurrently, Congress had directed the Secretary of Energy to develop a plan for the use of dual-purpose casks. Licensing and demonstrating a dual-purpose cask, or transportable storage system, would be a step toward achieving Congress's goal of demonstrating a technology that can be used to minimize the handling of spent nuclear fuel from the time the fuel is permanently removed from the reactor through to its ultimate disposal at a DOE facility. For SMUD, using a transportable storage system at the Rancho Seco Independent Spent-Fuel Storage Installation supports the goal of abandoning Rancho Seco's spent-fuel pool as decommissioning proceeds

Transport of fresh MOX fuel assemblies for the Monju initial core

International Nuclear Information System (INIS)

Kurakami, J.; Ouchi, Y.; Usami, M.

1997-01-01

Transport of fresh MOX fuel assemblies for the prototype FBR MONJU initial core started in July 1992 and ended in March 1994. As many as 205 fresh MOX fuel assemblies for an inner core, 91 assemblies for an outer core and 5 assemblies for testing) were transported in nine transport missions. The packaging for fuel assemblies, which has shielding and shock absorbing material inside, meets IAEA regulatory requirements for Type B(U) packaging including hypothetical accident conditions such as the 9 m drop test, fire test, etc. Moreover, this package design feature such advanced technologies as high performance neutron shielding material and an automatic hold-down mechanism for the fuel assemblies. Every effort was made to carry out safe transport in conjunction with the cooperation of every competent organisation. This effort includes establishment of the transport control centre, communication training, and accompanying of the radiation monitoring expert. No transport accident occurred during the transport and all the transport missions were successfully completed on schedule. (Author)

Potential hydrocarbon producing species of Western Ghats, Tamil Nadu, India

Energy Technology Data Exchange (ETDEWEB)

Augustus, G.D.P.S.; Jayabalan, M.; Rajarathinam, K. [Research Centre in Bombay, V.H.N.S.N. College, Virudhunagar (India); Ray, A.K. [Sardar Patel Univ., Anand (India). Dept. of Chemistry; Seiler, G.J. [USDA, ARS, Northern Crop Science Lab., Fargo, ND (United States)

2002-09-01

The decline in the world supplies of hydrocarbons has led to the search for alternate sources of fuel and chemicals. Plant species are potential sources of hydrocarbons. Large-scale screening of plants growing in the Western Ghats, Tamil Nadu, India was conducted to assess the hydrocarbon production and the type of isoprene compound(s) present. Three species contained more than 3% hydrocarbon. Sarcostemma brevistigma had the highest concentration of hydrocarbon with 3.6%. Seven species contained more than 2% of hydrocarbons among the plant species screened. The hydrocarbon fraction of Ficus elastica (leaf) had a gross heat value of 9834 cal/g (41.17 MJ/kg), which is close to the caloric value of fuel oil. Six hydrocarbon fractions contained gross heat values of more than 9000 cal/g (37.68 MJ/kg). Of the 13 species hydrocarbon fraction analysed, seven species contained cis-polyisoprene compounds, while two species contained trans-polyisoprenes. Cis and trans polyisoprenes are potential alternative energy sources for fuel and/or as industrial raw materials. (author)

Emissions of hydrocarbons from combustion of biofuels

International Nuclear Information System (INIS)

Olsson, Mona; Persson, Eva Marie.

1991-10-01

Evaluations and measurements of emissions of hydrocarbons from power plants with a capacity exceeding 1 MW using biofuels (wood fuels and peat) have been studied in order to identify and quantify the emissions of incompletely combusted hydrocarbons. The influence of the type of fuel and the combustion technology applied were also studied, using literature references. The report summarizes monitoring results from a number of plants using biofuels. The reported emissions from the different plants can not be compared as they are relatively few and the test results have been obtained under various conditions using different methods of testing and analysis. The methods used are often poorly documented in the studied reports. Few investigations of emissions of hydrocarbons from plants in the range of 1 to 10 MW have been carried out. The plant and the technology used are important factors determining the amount and type of emissions of hydrocarbons. Larger temporary emissions can occur during start up, operational disturbances or when using fuel of inhomogeneous quality. In order to minimize the emissions the combustion process must be efficiently controlled, and a fuel of a hohogeneous quality must be used. The report also summarizes sampling and analysis methods used for monitoring emissions of hydrocarbons. (29 refs., 17 figs.)

Topical absorption and toxicity studies of jet fuel hydrocarbons in skin

Science.gov (United States)

Muhammad, Faqir

Kerosene-based fuels have been used for many decades. Over 2 million military and civilian personnel each year are occupationally exposed to various jet fuel mixtures. Dermatitis is one of the major health concerns associated with these exposures. In the past, separate absorption and toxicity studies have been conducted to find the etiology of such skin disorders. There was a need for integrated absorption and toxicity studies to define the causative constituents of jet fuel responsible for skin irritation. The focus of this thesis was to study the percutaneous absorption and to identify the hydrocarbons (HC) causing irritation in jet fuels so that preventive measures could be taken in the future. The initial study was conducted to understand the possible mechanism for additive interactions on hydrocarbon absorption/disposition in silastic, porcine skin and isolated perfused porcine skin flap (IPPSF) models. The influence of JP-8 (100) additives (MDA, BHT, 8Q405) on the dermal kinetics of 14C-naphthalene and 14C/3H-dodecane as markers of HC absorption was evaluated. This study indicated that individual and combination of additives influenced marker disposition in different membranes. MDA was a significant suppressor while BHT was a significant enhancer of naphthalene absorption in IPPSF. The 8Q405 significantly reduced naphthalene content in dosed silastic and skin indicating a direct interaction between additive and marker HC. Similarly, the individual MDA and BHT significantly retained naphthalene in the stratum corneum of porcine skin, but the combination of both of these additives statistically decreased the marker retention in the stratum corneum suggesting a potential biological interaction. This study concluded that all components of a chemical mixture should be assessed since the effects of single components administered alone or as pairs may be confounded when all are present in the complete mixture. However, this study indicated that the marker HC

Chevron's technologies for converting unconventional hydrocarbons into transportation fuels

Energy Technology Data Exchange (ETDEWEB)

Zestar, L.P.; Nordrum, L.J. [Chevron Energy Technology Co., San Roman, CA (United States); Farshid, D.; Reynolds, B.E. [Chevron Global Downstream, San Ramon, CA (United States). Technology Marketing Div.

2009-07-01

Molecules laden with metal, sulphur and nitrogen impurities limit the value of unconventional heavy oils and produce large amounts of low-value byproducts during the processing phase. This paper discussed a vacuum resid slurry hydrocracking (VRSH) process for upgrading vacuum resid from bitumens and extra-heavy oil. The process converted all hydrocarbon materials in the field into high quality, high-value products. The technology used a proprietary ultra-fine slurry catalyst to achieve nearly 100 per cent resid conversion. The majority of the product was converted to distillates. The remaining unconverted oil was retained in a slurry reactor with a highly active and concentrated catalyst in order to enable higher resid conversion. The process generated significant amounts of hydrogen. It was concluded that the process can be operated in high conversion or high throughput modes. 1 tab., 4 figs.

Memento. Maritime transport of MOX fuels from Europe to Japan

International Nuclear Information System (INIS)

1999-07-01

The maritime transport of MOX fuels from Europe to Japan represents the last of the 3 steps of transport of the nuclear fuel reprocessing-recycling program settled between ORC (Japan), BNFL (UK) and Cogema (France). This document summarizes the different aspects of this program: the companies concerned, the physical protection measures, the US-Japan agreements (accompanying warship), the in-depth safety, the handling of MOX fuels (containers and ships), and the Japan MOX fuel needs. (J.S.)

Exorcising spent fuel transportation using comparative hazard assessment methods

International Nuclear Information System (INIS)

Pennington, Charles W.

2003-01-01

Spent fuel transportation has achieved an exemplary safety record over more than three decades within both the United States (U.S.) and the global community at large. Today, many groups are attempting to precipitate fear of spent fuel transportation within the general public by 'demonizing' this proven technology and by creating a highly charged environment of radiation phobia. The actions of these groups within the U.S. result from the confluence of the terrorist acts of September 11, 2001, and the acceptance by the President and Congress of the U.S. Department of Energy's (DOE) recommendation of Yucca Mountain as the repository site for the disposal of the nation's spent fuel. This paper offers a comparative hazard assessment demonstrating the relative safety of spent fuel transportation in the context of currently accepted practices within society to show that there are no 'demons' associated with spent fuel transportation. The paper provides an assessment of potential population exposures based on more than 25 years of transport cask analysis and testing under beyond-design-basis (BDB) event conditions, including missile attacks, with those from current accepted activities within society that produce high dose exposures to the general public. Over the last quarter of a century, several spent fuel cask test programs have produced data that allow calculation of potential releases and population doses resulting from a terrorist attack. The DOE has used this information to develop projected worst-case population exposures as part of the Final Environmental Impact Statement (FEIS) for the Yucca Mountain repository. The paper discusses these potential releases and population exposures. Additionally, the paper identifies current unregulated activities and practices within societies yielding population exposures that exceed significantly those that would result from such highly hypothetical and improbable events as a terrorist missile attack on a spent fuel

Exorcising spent fuel transportation using comparative hazard assessment methods

Energy Technology Data Exchange (ETDEWEB)

Pennington, Charles W. [NAC international, Norcross (United States)

2003-07-01

Spent fuel transportation has achieved an exemplary safety record over more than three decades within both the United States (U.S.) and the global community at large. Today, many groups are attempting to precipitate fear of spent fuel transportation within the general public by 'demonizing' this proven technology and by creating a highly charged environment of radiation phobia. The actions of these groups within the U.S. result from the confluence of the terrorist acts of September 11, 2001, and the acceptance by the President and Congress of the U.S. Department of Energy's (DOE) recommendation of Yucca Mountain as the repository site for the disposal of the nation's spent fuel. This paper offers a comparative hazard assessment demonstrating the relative safety of spent fuel transportation in the context of currently accepted practices within society to show that there are no 'demons' associated with spent fuel transportation. The paper provides an assessment of potential population exposures based on more than 25 years of transport cask analysis and testing under beyond-design-basis (BDB) event conditions, including missile attacks, with those from current accepted activities within society that produce high dose exposures to the general public. Over the last quarter of a century, several spent fuel cask test programs have produced data that allow calculation of potential releases and population doses resulting from a terrorist attack. The DOE has used this information to develop projected worst-case population exposures as part of the Final Environmental Impact Statement (FEIS) for the Yucca Mountain repository. The paper discusses these potential releases and population exposures. Additionally, the paper identifies current unregulated activities and practices within societies yielding population exposures that exceed significantly those that would result from such highly hypothetical and improbable events as a terrorist missile

Current status of sea transport of nuclear fuel materials and LLW in Japan

International Nuclear Information System (INIS)

Kitagawa, Hiroshi; Akiyama, Hideo

2000-01-01

Along with the basic policy of the nuclear fuel cycle of Japan, many fuel cycle facilities have been already constructed in Rokkasho-Mura, Aomori prefecture, such as the uranium enrichment plant, the low level waste disposal center and the receiving pool of the spent nuclear fuels for reprocessing. These facilities belong to the Japan Nuclear Fuel Limited. (JNFL). Domestic sea transport of the spent nuclear fuels (SF) has been carried out since 1977 to the Tokai Reprocessing Plant, and the first sea transport of the SF to the fuel cycle facility in Rokkasho-Mura was done in Oct, 1998 using a new exclusive ship 'Rokuei-Maru'. Sea transport of the low level radioactive wastes (LLW) has been carried out since 1992 to the Rokkasho LLW Disposal Center, and about 130,000 LLW drams were transported from the nuclear power plant sites. These sea transport have demonstrated the safety of the transport of the nuclear fuel cycle materials. It is hoped that the safe sea transport of the nuclear fuel materials will contribute to the more progress of the nuclear fuel cycle activities of Japan. (author)

Fundamentals of Hydrocarbon Upgrading to Liquid Fuels and Commodity Chemicals over Catalytic Metallic Nanoparticles

Science.gov (United States)

Chen, Tao

Promising new technologies for biomass conversion into fuels and chemical feedstocks rely on the production of bio-oils, which need to be upgraded in order to remove oxygen-containing hydrocarbons and water. A high oxygen concentration makes bio-oils acidic and corrosive, unstable during storage, and less energetically valuable per unit weight than petroleum-derived hydrocarbons. Although there are efficient processes for the production of bio-oils, there are no efficient technologies for their upgrading. Current technologies utilize traditional petroleum refining catalysts, which are not optimized for biomass processing. New upgrading technologies are, therefore, urgently needed for development of sustainable energy resources. Development of such new technologies, however, is severely hindered by a lack of fundamental understanding of how oxygen and oxygen-containing hydrocarbons derived from biomass interact with promising noble-metal catalysts. In this study, kinetic reaction measurements, catalyst characterization and quantum chemical calculations using density functional theory were combined for determining adsorption modes and reaction mechanisms of hydrocarbons in the presence of oxygen on surfaces of catalytic noble-metal nanoparticles. The results were used for developing improved catalyst formulations and optimization of reaction conditions. The addition of molybdenum to platinum catalysts was shown to improve catalytic activity, stability, and selectivity in hydrodeoxygenation of acetic acid, which served as a model biomass compound. The fundamental results that describe interactions of oxygen and hydrocarbons with noble-metal catalysts were extended to other reactions and fields of study: evaluation of the reaction mechanism for hydrogen peroxide decomposition, development of improved hydrogenation catalysts and determination of adsorption modes of a spectroscopic probe molecule.

Remarks on the transportation of spent fuel elements

International Nuclear Information System (INIS)

Krull, W.

1992-01-01

Information and data are provided on several aspects of the transportation of spent fuel elements. These aspects include contract, transportation, reprocessing batch size, and economical considerations. (author)

Formation of polycyclic aromatic hydrocarbons and soot in fuel-rich oxidation of methane in a laminar flow reactor

DEFF Research Database (Denmark)

Skjøth-Rasmussen, Martin Skov; Glarborg, Peter; Østberg, M.

2004-01-01

Conversion of methane to higher hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and soot was investigated under fuel-rich conditions in a laminar flow reactor. The effects of stoichiometry, dilution, and water vapor addition were studied at temperatures between 1073 and 1823 K. A chemical...... kinetic mechanism was established for methane oxidation, with emphasis on formation of higher hydrocarbons and PAH. A submodel for soot formation was adopted from the work of Frenklach and co-workers without changes. Modeling predictions showed good agreement with experimental results. Reactants, stable...... decrease with increasing addition of water vapor. The effect is described qualitatively by the reaction mechanism. The enhanced oxidation of acetylene is attributed to higher levels of hydroxyl radicals, formed from the reaction between the water vapor and hydrogen atoms....

Safety assessment of ammonia as a transport fuel

Energy Technology Data Exchange (ETDEWEB)

Duijm, N.J.; Markert, F.; Lundtang paulsen, Jette

2005-02-01

This report describes the safety study performed as part of the EU supported project 'Ammonia Cracking for Clean Electric Power Technology' The study addresses the following activities: safety of operation of the ammonia-powered vehicle under normal and accident (collision) conditions, safety of transport of ammonia to the refuelling stations and safety of the activities at the refuelling station (unloading and refuelling). Comparisons are made between the safety of using ammonia and the safety of other existing or alternative fuels. The conclusion is that the hazards in relation to ammonia need to be controlled by a combination of technical and regulatory measures. The most important requirements are: - Advanced safety systems in the vehicle - Additional technical measures and regulations are required to avoid releases in maintenance workshops and unauthorised maintenance on the fuel system - Road transport of ammonia to refuelling stations in refrigerated form - Sufficient safety zones between refuelling stations and residential or otherwise public areas. When these measures are applied, the use of ammonia as a transport fuel wouldnt cause more risks than currently used fuels (using current practice). (au)

Studies and research concerning BNFP. Nuclear spent fuel transportation studies

International Nuclear Information System (INIS)

Anderson, R.T.; Maier, J.B.

1979-11-01

Currently, there are a number of institutional problems associated with the shipment of spent fuel assemblies from commercial nuclear power plants: new and conflicting regulations, embargoing of certain routes, imposition of transport safeguards, physical security in-transit, and a lack of definition of when and where the fuel will be moved. This report presents a summary of these types and kinds of problems. It represents the results of evaluations performed relative to fuel receipt at the Barnwell Nuclear Fuel Plant. Case studies were made which address existing reactor sites with near-term spent fuel transportation needs. Shipment by either highway, rail, water, or intermodal water-rail was considered. The report identifies the impact of new regulations and uncertainty caused by indeterminate regulatory policy and lack of action on spent fuel acceptance and storage. This stagnant situation has made it impossible for industry to determine realistic transportation scenarios for business planning and financial risk analysis. A current lack of private investment in nuclear transportation equipment is expected to further prolong the problems associated with nuclear spent fuel and waste disposition. These problems are expected to intensify in the 1980's and in certain cases will make continuing reactor plant operation difficult or impossible

Some UK experience and practice in the packaging and transport of irradiated fuel

International Nuclear Information System (INIS)

Edney, C.J.; Rutter, R.L.

1977-01-01

The origin and growth of irradiated fuel transport within and to the U.K. is described and the role of the organisations presently carrying out transport operations is explained. An explanation of the relevant U.K. regulations and laws affecting irradiated fuel transport and the role of the controlling body, the Department of the Environment is given. An explanation is given of the technical requirements for the transport of irradiated Magnox fuel and of the type of flask used, and the transport arrangements, both within the U.K. and to the U.K., from overseas is discussed. The technical requirements for the transport of C.A.G.R. fuel are outlined and the flask and transport arrangements are discussed. The transport requirements of oxide fuel from water reactors is outlined and the flask and shipping arrangements under which this fuel is brought to the U.K. from overseas is explained. The shipping arrangements are explained with particular reference to current international and national requirements. The requirements of the transport of M.T.R. fuel are discussed and the flask type explained. The expected future expansion of the transport of irradiated fuel within and to the U.K. is outlined and the proposed operating methods are briefly discussed. A summary is given of the U.K. experience and the lessons to be drawn from that experience

Modeling the Thermal Rocket Fuel Preparation Processes in the Launch Complex Fueling System

Directory of Open Access Journals (Sweden)

A. V. Zolin

2015-01-01

Full Text Available It is necessary to carry out fuel temperature preparation for space launch vehicles using hydrocarbon propellant components. A required temperature is reached with cooling or heating hydrocarbon fuel in ground facilities fuel storages. Fuel temperature preparing processes are among the most energy-intensive and lengthy processes that require the optimal technologies and regimes of cooling (heating fuel, which can be defined using the simulation of heat exchange processes for preparing the rocket fuel.The issues of research of different technologies and simulation of cooling processes of rocket fuel with liquid nitrogen are given in [1-10]. Diagrams of temperature preparation of hydrocarbon fuel, mathematical models and characteristics of cooling fuel with its direct contact with liquid nitrogen dispersed are considered, using the numerical solution of a system of heat transfer equations, in publications [3,9].Analytical models, allowing to determine the necessary flow rate and the mass of liquid nitrogen and the cooling (heating time fuel in specific conditions and requirements, are preferred for determining design and operational characteristics of the hydrocarbon fuel cooling system.A mathematical model of the temperature preparation processes is developed. Considered characteristics of these processes are based on the analytical solutions of the equations of heat transfer and allow to define operating parameters of temperature preparation of hydrocarbon fuel in the design and operation of the filling system of launch vehicles.The paper considers a technological system to fill the launch vehicles providing the temperature preparation of hydrocarbon gases at the launch site. In this system cooling the fuel in the storage tank before filling the launch vehicle is provided by hydrocarbon fuel bubbling with liquid nitrogen. Hydrocarbon fuel is heated with a pumping station, which provides fuel circulation through the heat exchanger-heater, with

Emissions of greenhouse gases from the use of transportation fuels and electricity

International Nuclear Information System (INIS)

DeLuchi, M.A.

1991-11-01

This report presents estimates of full fuel-cycle emissions of greenhouse gases from using transportation fuels and electricity. The data cover emissions of carbon dioxide (CO 2 ), methane, carbon monoxide, nitrous oxide, nitrogen oxides, and nonmethane organic compounds resulting from the end use of fuels, compression or liquefaction of gaseous transportation fuels, fuel distribution, fuel production, feedstock transport, feedstock recovery, manufacture of motor vehicles, maintenance of transportation systems, manufacture of materials used in major energy facilities, and changes in land use that result from using biomass-derived fuels. The results for electricity use are in grams of CO 2 -equivalent emissions per kilowatt-hour of electricity delivered to end users and cover generating plants powered by coal, oil, natural gas, methanol, biomass, and nuclear energy. The transportation analysis compares CO 2 -equivalent emissions, in grams per mile, from base-case gasoline and diesel fuel cycles with emissions from these alternative- fuel cycles: methanol from coal, natural gas, or wood; compressed or liquefied natural gas; synthetic natural gas from wood; ethanol from corn or wood; liquefied petroleum gas from oil or natural gas; hydrogen from nuclear or solar power; electricity from coal, uranium, oil, natural gas, biomass, or solar energy, used in battery-powered electric vehicles; and hydrogen and methanol used in fuel-cell vehicles

Hydrodeoxygenation of oxidized distilled bio-oil for the production of gasoline fuel type

International Nuclear Information System (INIS)

Luo, Yan; Guda, Vamshi Krishna; Hassan, El Barbary; Steele, Philip H.; Mitchell, Brian; Yu, Fei

2016-01-01

Highlights: • Oxidation had more influence on the yield of total hydrocarbons than distillation. • The highest total hydrocarbon yield was obtained from oxidized distilled bio-oil. • The 2nd-stage hydrocarbons were in the range of gasoline fuel boiling points. • The main products for upgrading of oxidized bio-oil were aliphatic hydrocarbons. • The main products for upgrading of non-oxidized bio-oil were aromatic hydrocarbons. - Abstract: Distilled and oxidized distilled bio-oils were subjected to 1st-stage mild hydrodeoxygenation and 2nd-stage full hydrodeoxygenation using nickel/silica–alumina catalyst as a means to enhance hydrocarbon yield. Raw bio-oil was treated for hydrodeoxygenation as a control to which to compare study treatments. Following two-stage hydrodeoxygenation, four types of hydrocarbons were mainly comprised of gasoline and had water contents, oxygen contents and total acid numbers of nearly zero and higher heating values of 44–45 MJ/kg. Total hydrocarbon yields for raw bio-oil, oxidized raw bio-oil, distilled bio-oil and oxidized distilled bio-oil were 11.6, 16.2, 12.9 and 20.5 wt.%, respectively. The results indicated that oxidation had the most influence on increasing the yield of gasoline fuel type followed by distillation. Gas chromatography/mass spectrometry characterization showed that 66.0–76.6% of aliphatic hydrocarbons and 19.5–31.6% of aromatic hydrocarbons were the main products for oxidized bio-oils while 35.5–38.7% of aliphatic hydrocarbons and 58.2–63.1% of aromatic hydrocarbons were the main products for non-oxidized bio-oils. Both aliphatic and aromatic hydrocarbons are important components for liquid transportation fuels and chemical products.

Safety criteria for spent-fuel transport. Final report

International Nuclear Information System (INIS)

Goldmann, K.; Gekler, W.C.

1986-10-01

The focus of this study is on the question, ''Do current regulations provide reasonable assurance of safety for a transport scenario of spent fuel, as presently anticipated by the Department of Energy, under the Nuclear Waste Policy Act.'' This question has been addressed by developing a methodology for identifying the expected frequency of Accidents Which Exceed Regulatory Conditions in Severity (AWERCS) for spent fuel transport casks and then assessing the health effects resulting from that frequency. By applying the methodology to an illustrative case of road transports, it was found that the accidental release of radioactive material from impact AWERCS would make negligible contributions to health effects associated with spent fuel transports by road. It is also concluded that the current regulatory drop test requirements in 10 CFR 71.51 which form the basis for cask design and were used to establish AWERCS screening criteria for this study are adequate, and that no basis was found to conclude that cask performance under expected road accident conditions represents an undue risk to the public

Analyses of the transportation of spent research reactor fuel in the United States

International Nuclear Information System (INIS)

Cashwell, J.W.; Neuhauser, K.S.

1989-01-01

The Transportation Technology Center at Sandia National Laboratories has analyzed the impacts of transportation of research reactor spent fuel from US and foreign reactors for the US Department of Energy (DOE) Office of Defense Programs. This effort represents the first comprehensive analytical evaluation of the risks of transporting high-, medium-, and low-enriched uranium spent research reactor fuel by both sea and land. Two separate shipment programs have been analyzed: the shipment of research reactor spent fuel from Taiwan to the US (Fuel Movement Program), and the return of research reactor spent fuels of US origin from foreign and domestic reactors (Research Reactor Fuel Return Program). In order to perform these analyses, a comprehensive methodology for analyzing the probabilities and consequences of transportation in coastal waters and port facilities, handling at the port, and shipment by truck to reprocessing facilities was developed. The Taiwanese fuel consists of low-burnup aluminum-clad metallic uranium research reactor spent fuel; the other fuels are primarily aluminum-clad oxide fuels. The Fuel Movement Program is ongoing, while the Fuel Return Program addresses future shipments over a ten-year period. The operational aspects of the Taiwanese shipments have been uniform, but several possible shipping configurations are possible for the Fuel Return Program shipments. Comprehensive assessments, which bound the impacts of spent fuel transport, demonstrate that when shipments are made in compliance with applicable regulations, the risks for all such transport are low. For comparison with previously licensed transport activities and to provide continuity with earlier analyses, the results for shipment of 150-day-old commercial pressurized water reactor (PWR) spent fuel are presented as part of this study

Transport insurance of unirradiated nuclear fuels

International Nuclear Information System (INIS)

Matto, H.

1985-01-01

Special conditions must be taken into account in transport insurance for nuclear materials even if the nuclear risk involved is negligible, as in shipments of unirradiated nuclear fuels. The shipwreck of the 'Mont Louis' has raised a number of open points which must be solved pragmatically within the framework of transport insurance. Some proposals are outlined in the article. (orig.) [de

Physiological tolerance and stoichiometric potential of cyanobacteria for hydrocarbon fuel production.

Science.gov (United States)

Kämäräinen, Jari; Knoop, Henning; Stanford, Natalie J; Guerrero, Fernando; Akhtar, M Kalim; Aro, Eva-Mari; Steuer, Ralf; Jones, Patrik R

2012-11-30

Cyanobacteria are capable of directly converting sunlight, carbon dioxide and water into hydrocarbon fuel or precursors thereof. Many biological and non-biological factors will influence the ability of such a production system to become economically sustainable. We evaluated two factors in engineerable cyanobacteria which could potentially limit economic sustainability: (i) tolerance of the host to the intended end-product, and (ii) stoichiometric potential for production. Alcohols, when externally added, inhibited growth the most, followed by aldehydes and acids, whilst alkanes were the least inhibitory. The growth inhibition became progressively greater with increasing chain-length for alcohols, whilst the intermediate C6 alkane caused more inhibition than both C3 and C11 alkane. Synechocystis sp. PCC 6803 was more tolerant to some of the tested chemicals than Synechococcus elongatus PCC 7942, particularly ethanol and undecane. Stoichiometric evaluation of the potential yields suggested that there is no difference in the potential productivity of harvestable energy between any of the studied fuels, with the exception of ethylene, for which maximal stoichiometric yield is considerably lower. In summary, it was concluded that alkanes would constitute the best choice metabolic end-product for fuel production using cyanobacteria if high-yielding strains can be developed. Copyright © 2012 Elsevier B.V. All rights reserved.

Gas transport in solid oxide fuel cells

CERN Document Server

He, Weidong; Dickerson, James

2014-01-01

This book provides a comprehensive overview of contemporary research and emerging measurement technologies associated with gas transport in solid oxide fuel cells. Within these pages, an introduction to the concept of gas diffusion in solid oxide fuel cells is presented. This book also discusses the history and underlying fundamental mechanisms of gas diffusion in solid oxide fuel cells, general theoretical mathematical models for gas diffusion, and traditional and advanced techniques for gas diffusivity measurement.

Development and use of GREET 1.6 fuel-cycle model for transportation fuels and vehicle technologies

International Nuclear Information System (INIS)

Wang, M. Q.

2001-01-01

Since 1995, with funds from the U.S. Department of Energy's (DOE's) Office of Transportation Technologies (OTT), Argonne National Laboratory has been developing the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model. The model is intended to serve as an analytical tool for use by researchers and practitioners in estimating fuel-cycle energy use and emissions associated with alternative transportation fuels and advanced vehicle technologies. Argonne released the first version of the GREET model--GREET 1.0--in June 1996. Since then, it has released a series of GREET versions with revisions, updates, and upgrades. In February 2000, the latest public version of the model--GREET 1.5a--was posted on Argonne's Transportation Technology Research and Development Center (TTRDC) Web site (www.transportation.anl.gov/ttrdc/greet). Major publications that address GREET development are listed. These reports document methodologies, development, key default assumptions, applications, and results of the GREET model. They are also posted, along with additional materials for the GREET model, on the TTRDC Web site. For a given transportation fuel/technology combination, the GREET model separately calculates: (A)--Fuel-cycle energy consumption for the following three source categories: (1) Total energy (all energy sources), (2) Fossil fuels (petroleum, natural gas [NG], and coal), and (3) Petroleum. (B)--Fuel-cycle emissions of the following three greenhouse gases (GHGs): (1) Carbon dioxide (CO 2 ) (with a global warming potential [GWP] of 1), (2) Methane (CH 4 ) (with a GWP of 21), and (3) Nitrous oxide (N 2 O) (with a GWP of 310). (C)--Fuel-cycle emissions of the following five criteria pollutants (separated into total [T] and urban [U] emissions): (1) Volatile organic compounds (VOCs), (2) Carbon monoxide (CO), (3) Nitrogen oxides (NO x ), (4) Particulate matter with a mean aerodynamic diameter of 10 (micro)m or less (PM 10 ), and (5) Sulfur oxides

Renewable hydrocarbon fuels from hydrothermal liquefaction: A techno-economic analysis

DEFF Research Database (Denmark)

Pedersen, Thomas Helmer; Hansen, Nick Høy; Pérez, Oscar Miralles

2018-01-01

This study demonstrates the economic feasibility of producing renewable transportation drop-in fuels from lignocellulosic biomass through hydrothermal liquefaction and upgrading. An Aspen Plus® process model is developed based on extensive experimental data to document a techno-economic assessmen...

Conceptual Assessment of a Fresh Fuel Transport Package for KJRR

Energy Technology Data Exchange (ETDEWEB)

Lee, Ju-Chan; Choi, W. S.; Bang, K. S.; Yu, S. H.; Park, J. S.; Yang, Y. Y. [KAERI, Daejeon (Korea, Republic of)

2016-05-15

The IAEA and domestic regulations stipulate that the fissile material transport package be subjected to the cumulative effects of a 9 m drop, 1 m puncture, 800 ℃ thermal and water leakage tests. A fissile material transport package should be maintained the subcriticality during the normal and accident conditions for contingency of leakage of water into or out of package, rearrangement of the contents, reduction of spaces and temperature changes. KAERI has been developing a fresh fuel transport package for Kijang research reactor (KJRR). This paper describes a conceptual design and preliminary safety analysis of the transport package for KJRR. The transport package was designed for shipment of a fresh fuel and a FM (Fission Molybdenum) target. Low-enriched uranium (LEU) of U-Mo fuel with U-235 enrichment of 19.75 w/o is used as a research reactor fuel. And LEU of UAlx-Al with U-235 enrichment of 19.75 w/o is used as a FM target material. The transport package was designed for shipment of a fresh fuel and a FM target. Safety analyses were conducted on all areas, including criticality, structural, and thermal fields. In the criticality analysis, effective neutron multiplication factors were below the criticality safety limit. In the structural analysis, the maximum stress satisfied the stress requirement stipulated in the ASME code. After 9 m free drop and 1 m puncture test, there was no significant deformation of fuel basket to cause a criticality. In the thermal analysis, the maximum temperatures at each part were lower than the allowable values.

The dieselization of America: An integrated strategy for future transportation fuels

Energy Technology Data Exchange (ETDEWEB)

Eberhardt, J.J. [Dept. of Energy, Washington, DC (United States)

1997-12-31

The Diesel Cycle engine has already established itself as the engine-of-choice for the heavy duty transport industry because of its fuel efficiency, durability, and reliability. In addition, it has also been shown to be capable of using alternative fuels, albeit at efficiencies lower than that achieved with petroleum-derived diesel fuel. Alternative fuel dedicated engines have not made significant penetration of the heavy duty truck market because truck fleet operators need a cost-competitive fuel and reliable supply and fueling infrastructure. In lieu of forcing diverse fuels from many diverse domestic feedstocks onto the end-users, the Office of Heavy Vehicle Technologies envisions that a future fuels strategy for the heavy duty transport sector is one where the diverse feedstocks are utilized to provide a single fuel specification (dispensed from the existing fueling infrastructure) that would run efficiently in a single high efficiency energy conversion device, the Diesel Cycle engine. In so doing, the US Commercial transport industry may gain a measure of security from the rapid fuel price increases by relying less on a single feedstock source to meet its increasing fuel requirements.

Fuel cells in transportation

Energy Technology Data Exchange (ETDEWEB)

Erdmann, G [Technische Univ., Berlin (Germany); Hoehlein, B [Research Center Juelich (Germany)

1996-12-01

A promising new power source for electric drive systems is the fuel cell technology with hydrogen as energy input. The worldwide fuel cell development concentrates on basic research efforts aiming at improving this new technology and at developing applications that might reach market maturity in the very near future. Due to the progress achieved, the interest is now steadily turning to the development of overall systems such as demonstration plants for different purposes: electricity generation, drive systems for road vehicles, ships and railroads. This paper does not present results concerning the market potential of fuel cells in transportation but rather addresses some questions and reflections that are subject to further research of both engineers and economists. Some joint effort of this research will be conducted under the umbrella of the IEA Implementing Agreement 026 - Annex X, but there is a lot more to be done in this challenging but also promising fields. (EG) 18 refs.

Shielding Performance Measurements of Spent Fuel Transportation Container

Directory of Open Access Journals (Sweden)

SUN Hong-chao

2015-11-01

Full Text Available The safety supervision of radioactive material transportation package has been further stressed and implemented. The shielding performance measurements of spent fuel transport container is the important content of supervision. However, some of the problems and difficulties reflected in practice need to be solved, such as the neutron dose rate on the surface of package is too difficult to measure exactly, the monitoring results are not always reliable, etc. The monitoring results using different spectrometers were compared and the simulation results of MCNP runs were considered. An improvement was provided to the shielding performance measurements technique and management of spent fuel transport.

Analyses of the transportation of spent research reactor fuel in the United States

International Nuclear Information System (INIS)

Cashwell, J.W.; Neuhauser, K.S.

1989-01-01

We analyzed the impacts of transportation of research reactor spent fuel from US and foreign reactors for the US Department of Energy's (DOE) Office of Defense Programs. Two separate shipment programs were analyzed. The shipment of research reactor spent fuel from Taiwan to the US (Fuel Movement Program), and the return of research reactor spent fuels of US origin from foreign and domestic reactors (Research Reactor Fuel Return Program). To perform these analyses, a comprehensive methodology for analyzing the probabilities and consequences of transportation in coastal waters and port facilities, handling at the port, and shipment by truck to reprocessing facilities was developed. The Taiwanese fuel consists of low-burnup aluminum-clad metallic uranium research reactor spent fuel; the other fuels are primarily aluminum-clad oxide fuels. The Fuel Movement Program is ongoing, while the Fuel Return Program addresses future shipments over a ten-year period. The operational aspects of the Taiwanese shipments have been uniform, but several possible shipping configurations are possible for the Fuel Return Program shipments. The risks of transporting spent nuclear fuel and other radioactive materials by all modes have been analyzed extensively. Comprehensive assessments, which bound the impacts of spent fuel transport, demonstrate that when shipments are made in compliance with applicable regulations, the risks for all such transport are low. For comparison with previously licensed transport activities and to provide continuity with earlier analyses, the results for shipment of 150-day-old commercial pressurized water reactor (PWR) spent fuel are presented as part of this study

Safe transport of irradiated fuel by sea

International Nuclear Information System (INIS)

Miller, M.L.

1997-01-01

The development is described of a transport system dedicated to the sea transport of irradiated nuclear fuel. The background is reviewed of why shipments were required and the establishment of a specialist shipping company, Pacific Nuclear Transport Limited. A description of the ships, flasks and other equipment utilised is provided, together with details of key procedures implemented to ensure safety and customer satisfaction. (Author)

The sea transport of irradiated nuclear fuel

International Nuclear Information System (INIS)

Miller, M.L.

1995-01-01

The paper describes the development of a transport system dedicated to the sea transport of irradiated nuclear fuel. It reviews the background to why shipments were required and the establishment of a specialist shipping company, Pacific Nuclear Transport Limited. A description of the ships, flasks and other equipment utilized is provided, together with details of key procedures implemented to ensure safety and customer satisfaction

HEU and Leu FueL Shielding Comparative Study Applied for Spent Fuel Transport

International Nuclear Information System (INIS)

Margeanu, C.A.; Margeanu, S.; Barbos, D.

2009-01-01

INR Pitesti owns and operates a TRIGA dual-core Research Reactor for material testing, power reactor fuel and nuclear safety studies. The dual core concept involves the operation of a 14 MW TRIGA steady-state, high flux research and material testing reactor at one end of a large pool, and the independent operation of an annular-core pulsing reactor (TRIGA-ACPR) at the other end of the pool. The steady-state reactor is mostly used for long term testing of power reactor fuel components (pellets, pins, subassemblies and fuel assemblies) followed by post-irradiation examination. Following the general trend to replace the He fuel type (High Enriched Uranium) by Leu fuel type (Low Enriched Uranium), in the light of international agreements between IAEA and the states using He fuel in their nuclear reactors, Inr Past's have been accomplished the TRIGA research reactor core full conversion on May 2006. The He fuel repatriation in US in the frame of Foreign Research Reactor Spent Nuclear Fuel Return Programme effectively started in 1999, the final stage being achieved in summer of 2008. Taking into account for the possible impact on the human and environment, in all activities associated to nuclear fuel cycle, the spent fuel or radioactive waste characteristics must be well known. Shielding calculations basic tasks consist in radiation doses calculation, in order to prevent any risks both for personnel protection and impact on the environment during the spent fuel manipulation, transport and storage. The paper is a comparative study of Leu and He fuel utilization effects for the shielding analysis during spent fuel transport. A comparison against the measured data for He spent fuel, available from the last stage of the spent fuel repatriation, is presented. All the geometrical and material data related on the spent fuel shipping cask were considered according to the Nac-Lt Cask approved model. The shielding analysis estimates radiation doses to shipping cask wall surface

Estimated routine radiation doses to transportation workers in alternative spent-fuel transportation systems

International Nuclear Information System (INIS)

Schneider, K.J.; Smith, R.I.; Daling, P.M.; Ross, W.A.; McNair, G.W.

1988-01-01

The federal system for the management of spent fuel and high-level radioactive waste includes the acceptance by the US Department of Energy (DOE) of the spent fuel or waste loaded in casks at the reactor or other waste generators, its transportation to a repository, and its handling and final emplacement in the repository. The DOE plans to implement a transportation system that is safe, secure, efficient, and cost-effective and will meet applicable regulatory safety and security requirements. The DOE commissioned the Pacific Northwest Laboratory (PNL) to develop estimates of the routine radiation doses that would result from the operation of a system postulated using current designs and practices. From that evaluation, PNL identified activities/operations that result in the higher fraction of doses, proposed conceptual alternatives that would effectively reduce such exposures, and evaluated the cost-effectiveness of such alternatives. The study is one of a series used in making overall system design and operational decisions in the development of the DOE's spent-fuel/high-level waste transportation system. This paper contains the highlights from the PNL study of the estimated radiation doses to the transportation workers in a postulated reference transportation system and potential alternatives to that system

Comparison of fuel production costs for future transportation

DEFF Research Database (Denmark)

Ridjan, Iva; Mathiesen, Brian Vad; Connolly, David

The purpose of this poster is to provide an overview of fuel production costs for two types of synthetic fuels – methanol and methane, along with comparable costs for first and second generation biodiesel, two types of second generation bioethanol, and biogas. The model analysed is a 100% renewable...... scenario of Denmark for 2050, where the data for the transport sector has been changed to estimate the fuel production costs for eight different fuel pathways....

Remarks on the transportation of spent fuel elements

International Nuclear Information System (INIS)

Krull, W.

1986-01-01

In this chapter topics discussed are the need for contracts, a transport company and risk insurance. Also, a section on transportation covers cranes, subpressure, contamination, cask limitations, physical protection and shipping. Reprocessing discusses minimum reprocessing batch and spent fuel. Finally, economical considerations concerning transportation and reprocessing are given

Fuel gases in Algeria

International Nuclear Information System (INIS)

Arachiche, B.; Elandaloussi, H.

1996-01-01

For a country like Algeria, fuel gases represent an important economical challenge. To answer the increasing energy demand in the transportation sector, the use of fuel gases allows to preserve the petroleum reserves and to create specific industrial structures devoted to LPG-f (liquefied petroleum gas-fuel) and NGV (natural gas for vehicles). This paper presents the energy policy of Algeria, its reserves, production, and exportations of hydrocarbons and the internal rational use of energy sources according to its economic and environmental policy and to its internal needs. The energy consumption of Algeria in the transportation sector represents 2/3 of the petroleum products consumed in the internal market and follows a rapid increase necessary to the socio-economic development of the country. The Algerian experience in fuel gases is analysed according to the results of two successive experimentation periods for the development of NGV before and after 1994, and the resulting transportation and distribution network is described. The development of LPG-f has followed also an experimental phase for the preparation of regulation texts and a first statement of the vehicles conversion to LPG-f is drawn with its perspectives of development according to future market and prices evolutions. (J.S.)

Spent fuel shipping costs for transportation logistics analyses

International Nuclear Information System (INIS)

Cole, B.M.; Cross, R.E.; Cashwell, J.W.

1983-05-01

Logistics analyses supplied to the nuclear waste management programs of the U.S. Department of Energy through the Transportation Technology Center (TTC) at Sandia National Laboratories are used to predict nuclear waste material logistics, transportation packaging demands, shipping and receiving rates and transportation-related costs for alternative strategies. This study is an in-depth analysis of the problems and contingencies associated with the costs of shipping irradiated reactor fuel. These costs are extremely variable however, and have changed frequently (sometimes monthly) during the past few years due to changes in capital, fuel, and labor costs. All costs and charges reported in this study are based on January 1982 data using existing transport cask systems and should be used as relative indices only. Actual shipping costs would be negotiable for each origin-destination combination

Macroscopic Modeling of Transport Phenomena in Direct Methanol Fuel Cells

DEFF Research Database (Denmark)

Olesen, Anders Christian

An increasing need for energy efficiency and high energy density has sparked a growing interest in direct methanol fuel cells for portable power applications. This type of fuel cell directly generates electricity from a fuel mixture consisting of methanol and water. Although this technology...... surpasses batteries in important areas, fundamental research is still required to improve durability and performance. Particularly the transport of methanol and water within the cell structure is difficult to study in-situ. A demand therefore exist for the fundamental development of mathematical models...... for studying their transport. In this PhD dissertation the macroscopic transport phenomena governing direct methanol fuel cell operation are analyzed, discussed and modeled using the two-fluid approach in the computational fluid dynamics framework of CFX 14. The overall objective of this work is to extend...

Storage, transportation and disposal system for used nuclear fuel assemblies

Science.gov (United States)

Scaglione, John M.; Wagner, John C.

2017-01-10

An integrated storage, transportation and disposal system for used fuel assemblies is provided. The system includes a plurality of sealed canisters and a cask sized to receive the sealed canisters in side by side relationship. The plurality of sealed canisters include an internal basket structure to receive a plurality of used fuel assemblies. The internal basket structure includes a plurality of radiation-absorbing panels and a plurality of hemispherical ribs generally perpendicular to the canister sidewall. The sealed canisters are received within the cask for storage and transportation and are removed from the cask for disposal at a designated repository. The system of the present invention allows the handling of sealed canisters separately or collectively, while allowing storage and transportation of high burnup fuel and damaged fuel to the designated repository.

Proposal of guidelines for selecting optimum options in packagings and transportation systems of spent fuel

International Nuclear Information System (INIS)

Saegusa, T.; Abe, H.; Fukuda, S.

1983-01-01

Type and size of spent fuel shipping packagings and packaging transport ships in spent fuel transport system would have been determined separately in response to technical requirements etc. of reactor sites and reprocessing plants. However, since more and more spent fuel will be generated from world's nuclear power plants and will be transported much frequently to reprocessing plants or storage facilities, the current spent fuel transport system will have to be necessarily reexamined from the operational and economical aspects or an optimum transport system may have to be newly determined in the near future. In the literature, a variety of options are found, particularly of spent fuel packagings. This paper listed and classified options of spent fuel packagings and packaging transport ships in the transportation systems of spent fuel on the basis of literature surveys. These options were discussed from viewpoints of designers and users and compared in terms of transport efficiency. Finally, one way to determine an optimum transport system of spent fuel was indicated considering the total transport system in the light of safety, operational efficiency and economy

An evaluation of the alternative transport fuel policies for Turkey

International Nuclear Information System (INIS)

Arslan, Ridvan; Ulusoy, Yahya; Tekin, Yuecel; Suermen, Ali

2010-01-01

The search for alternative fuels and new fuel resources is a top priority for Turkey, as is the case in the majority of countries throughout the world. The fuel policies pursued by governmental or civil authorities are of key importance in the success of alternative fuel use, especially for widespread and efficient use. Following the 1973 petroleum crisis, many users in Turkey, especially in transportation sector, searched for alternative fuels and forms of transportation. Gasoline engines were replaced with diesel engines between the mid-1970s and mid-1980s. In addition, natural gas was introduced to the Turkish market for heating in the early 1990s. Liquid petroleum gas was put into use in the mid-1990s, and bio-diesel was introduced into the market for transportation in 2003. However, after long periods of indifference governmental action, guidance and fuel policies were so weak that they did not make sense. Entrepreneurs and users experienced great economical losses and lost confidence in future attempts to search for other possible alternatives. In the present study, we will look at the history of alternative fuel use in the recent past and investigate the alternative engine fuel potential of Turkey, as well as introduce possible future policies based on experience.

Reduced Gravity Studies of Soret Transport Effects in Liquid Fuel Combustion

Science.gov (United States)

Shaw, Benjamin D.

2004-01-01

Soret transport, which is mass transport driven by thermal gradients, can be important in practical flames as well as laboratory flames by influencing transport of low molecular weight species (e.g., monatomic and diatomic hydrogen). In addition, gas-phase Soret transport of high molecular weight fuel species that are present in practical liquid fuels (e.g., octane or methanol) can be significant in practical flames (Rosner et al., 2000; Dakhlia et al., 2002) and in high pressure droplet evaporation (Curtis and Farrell, 1992), and it has also been shown that Soret transport effects can be important in determining oxygen diffusion rates in certain classes of microgravity droplet combustion experiments (Aharon and Shaw, 1998). It is thus useful to obtain information on flames under conditions where Soret effects can be clearly observed. This research is concerned with investigating effects of Soret transport on combustion of liquid fuels, in particular liquid fuel droplets. Reduced-gravity is employed to provide an ideal (spherically-symmetrical) experimental model with which to investigate effects of Soret transport on combustion. The research will involve performing reduced-gravity experiments on combustion of liquid fuel droplets in environments where Soret effects significantly influence transport of fuel and oxygen to flame zones. Experiments will also be performed where Soret effects are not expected to be important. Droplets initially in the 0.5 to 1 mm size range will be burned. Data will be obtained on influences of Soret transport on combustion characteristics (e.g., droplet burning rates, droplet lifetimes, gas-phase extinction, and transient flame behaviors) under simplified geometrical conditions that are most amenable to theoretical modeling (i.e., spherical symmetry). The experiments will be compared with existing theoretical models as well as new models that will be developed. Normal gravity experiments will also be performed.

Transport equations in an enzymatic glucose fuel cell

Science.gov (United States)

Jariwala, Soham; Krishnamurthy, Balaji

2018-01-01

A mathematical model is developed to study the effects of convective flux and operating temperature on the performance of an enzymatic glucose fuel cell with a membrane. The model assumes isothermal operating conditions and constant feed rate of glucose. The glucose fuel cell domain is divided into five sections, with governing equations describing transport characteristics in each region, namely - anode diffusion layer, anode catalyst layer (enzyme layer), membrane, cathode catalyst layer and cathode diffusion layer. The mass transport is assumed to be one-dimensional and the governing equations are solved numerically. The effects flow rate of glucose feed on the performance of the fuel cell are studied as it contributes significantly to the convective flux. The effects of operating temperature on the performance of a glucose fuel cell are also modeled. The cell performances are compared using cell polarization curves, which were found compliant with experimental observations.

Experience of European LWR irradiated fuel transport: the first five hundred tonnes

International Nuclear Information System (INIS)

Curtis, H.W.

1978-01-01

The paper describes the service provided by an international company specializing in the transport of LWR irradiated fuel throughout Europe. Methods of transport used to the reprocessing plants at La Hague and Windscale include road transport of 38 te flasks over the whole route; transport of flasks between 55 and 105 te by rail, with rail-head and the reprocessing plant, where required, performed by road using heavy trailers; roll-on, roll-off sea ferries; and charter ships. Different modes of transport have been developed to cater for the various limitations on access to reactor sites arising from geographical and routing considerations. The experience of transporting more than 500 tonnes of irradiated uranium from twenty-one power reactors is used to illustrate the flexibility which the transport organization requires when the access and handling facilities are different at almost every reactor. Variations in fuel cross sections and lengths of fuel elements used in first generation reactors created the need for first generation flasks with sufficient variants to accommodate all reactor fuels but the trend now is towards standardization of flasks to perhaps two basic types. The safety record of irradiated fuel transport is examined with explanation of the means whereby this has been achieved. The problems of programming the movement of a pool of eighteen flasks for twenty-one reactors in eight countries are discussed together with the steps taken to ensure that the service operates fairly to give priority to those reactors with the greatest problems. The transport of irradiated fuel across several national frontiers is an international task which requires an international company. The transport of European irradiated fuel can be presented as an example of international collaboration which works

Probabilistic safety analysis of transportation of spent fuel

International Nuclear Information System (INIS)

Subramaniam, Chitra

1999-11-01

The report presents the results of the study carried out to estimate the accident risk involved in the transport of spent fuel from Rajasthan Atomic Power Station near Kota to the fuel reprocessing plant at Tarapur. The technique of probabilistic safety analysis is used. The fuel considered is the Indian pressurised heavy water reactor fuel with a minimum cooling period of 485 days. The spent fuel is transported in a cuboidal, naturally-cooled shipping cask over a distance of 822 km by rail. The Indian rail accident statistics are used to estimate the basic rail accident frequency. The possible ways in which a release of radioactive material can occur from the spent fuel cask are identified by the fault tree analysis technique. The release sequences identified are classified into eight accident severity categories, and release fractions are assigned to each. The consequences resulting from the release are estimated by the computer code RADTRAN 4. Results of the risk analysis indicate that the accident risk values are very low and hence acceptable. Parametric studies show that the risk would continue to be small even if the controlling parameters were to simultaneously take extreme adverse values. (author)

Fuel cell assembly with electrolyte transport

Science.gov (United States)

Chi, Chang V.

1983-01-01

A fuel cell assembly wherein electrolyte for filling the fuel cell matrix is carried via a transport system comprising a first passage means for conveying electrolyte through a first plate and communicating with a groove in a second plate at a first point, the first and second plates together sandwiching the matrix, and second passage means acting to carry electrolyte exclusively through the second plate and communicating with the groove at a second point exclusive of the first point.

Experience of European irradiated fuel transport - the first four hundred tonnes

International Nuclear Information System (INIS)

Curtis, H.W.

1977-01-01

The paper describes the successful integration of the experience of its three shareholders into an international company providing an irradiated fuel transport service throughout Europe. The experience of transporting more than 400 tonnes of irradiated uranium from fifteen power reactors is used to illustrate the flexibility which the transport organisation requires when the access and handling facilities are different at almost every reactor. Variations in fuel cross sections and lengths of fuel elements used in first generation reactors created the need for first generation flasks with sufficient variants to accommodate all reactor fuels but the trend now is towards standardisation of flasks to perhaps two basic types. Increases in fuel rating have raised the flask shielding and heat dissipation requirements and have influenced the design of later flasks. More stringent criticality acceptance criteria have tended to reduce the flask capacity below the maximum number of elements which could physically be contained. Reprocessing plant acceptance criteria initiated because of the presence of substantial quantities of loose crud released in the flask and the need to transport substantial numbers of failed elements have also reduced the flask capacity. Different modes of transport have been developed to cater for the various limitations on access to reactor sites arising from geographical and routing considerations. The safety record of irradiated fuel transport is examined with explanation of the means whereby this has been achieved. The problems of programming the movement of a pool of flasks for fifteen reactors in eight countries are discussed together with the steps taken to ensure that the service operates fairly to give priority to those reactors with the greatest problems. The transport of European irradiated fuel can be presented as an example of international collaboration which works

Transportation of high-level waste and spent fuel

International Nuclear Information System (INIS)

Carlson, J.H.; Lake, W.H.; Thompson, J.H.

1993-01-01

The Office of Civilian Radioactive Waste Management (OCRWM) transportation program is a multifaceted undertaking to transport spent nuclear fuel from commercial reactors to temporary and permanent storage facilities commencing in 1998. One of the significant ingredients necessary to achieving this goal is the development and acquisition of shipping casks. Efforts to design and acquire high capacity casks is ongoing, as are efforts to purchase casks that can be made available using current technology. By designing casks that are optimized to the specifications of the older cooler spent fuel that will be shipped, and by designing to current NRC requirements, OCRWM's new generation of spent fuel casks will be more efficient and at least as safe as current cask designs. (J.P.N.)

Method to mount defect fuel elements i transport casks

International Nuclear Information System (INIS)

Borgers, H.; Deleryd, R.

1996-01-01

Leaching or otherwise failed fuel elements are mounted in special containers that fit into specially designed chambers in a transportation cask for transport to reprocessing or long-time storage. The fuel elements are entered into the container under water in a pool. The interior of the container is dried before transfer to the cask. Before closing the cask, its interior, and the exterior of the container are dried. 2 figs

Ordinance concerning the filing of transport of nuclear fuel materials

International Nuclear Information System (INIS)

1979-01-01

The ordinance is defined under the law for the regulations of nuclear source materials, nuclear fuel materials and reactors and the order for execution of the law. Any person who reports the transport of nuclear fuel materials shall file four copies of a notification according to the form attached to the public safety commission of the prefecture in charge of the dispatching place. When the transportation extends over the area in charge of another public safety commission, the commission which has received the notice shall report without delay date and route of the transport, kind and quantity of nuclear fuel materials and other necessary matters to the commission concerned and hear from the latter opinions on the items informed. The designation by the ordinance includes speed of the vehicle loaded with nuclear fuel materials, disposition of an accompanying car, arrangement of the line of the loaded vehicle and accompanying and other escorting cars, location of the parking, place of unloading and temporary storage, etc. Reports concerning troubles and measures taken shall be filed in ten days to the public safety commission which has received the notification, when accidents occur on the way, such as: theft or loss of nuclear fuel materials; traffic accident; irregular leaking of nuclear fuel materials and personal trouble by the transport. (Okada, K.)

The role of hydrocarbons in energy transition

International Nuclear Information System (INIS)

2015-11-01

This publication presents some reflections and statements as well as data regarding the role of hydrocarbons in energy production and consumption, in order to better highlight the role hydrocarbons may have in energy transition. It outlines the still very important share of oil in primary and final energy, and more particularly in transports, and that, despite the development of other energies, an energy transition is always very slow. It discusses the perspectives for hydrocarbon reserves and production of oil and natural gas. It outlines that oil remains the most important energy for mobility, the benefits of conventional fuels, and that distribution infrastructures must be preserved and developed. It discusses the evolution of the economic situation of the refining activity (more particularly its margin). It outlines the high contribution of oil industry to economic activity and employment in France, discusses the French energy taxing policy and environmental taxing policy, discusses the issue of security of energy supply (with its different components: exploration-production, refining, logistics and depots, distribution and station network). It discusses the possible role shale hydrocarbons may have in the future. For each issue, the position and opinion of the UFIP (the French Union of oil industries) is stated. The second part of the document proposes a Power Point presentation with several figures and data on these issues

One approach to accepting and transporting spent fuel from early-generation reactors with short fuel assemblies

International Nuclear Information System (INIS)

Peterson, R.W.; Bentz, E.J. Jr.; Bentz, C.B.

1993-01-01

In the early days of development of commercial nuclear power reactors in the U.S., the overall length and uranium loading of the fuel assemblies were considerably less than those of later generation facilities. In turn, some of these early facilities were designed for handling shorter casks than currently-certified casks. The spent fuel assemblies from these facilities are nearly all standard fuel within the definition in the Standard Contract (10 CFR 961) between the utilities and the U.S. Department of Energy (DOE) (the Big Rock Point fuel cross-section is outside the standard fuel dimension), and the utilities involved hold early delivery rights under DOE's oldest-fuel-first (OFF) allocation scenario. However, development of casks suitable for satisfying the acceptance and transportation requirements of some of these facilities is not currently underway in the DOE Cask System Development Program (CSDP). While the total MTU of these fuels is relatively small compared to the total program, the number of assemblies to be transported is significant, especially in the early years of operation according to the OFF allocation scenario. We therefore perceive a need for DOE to develop an approach and to implement plans to satisfy the unique acceptance and transportation requirements of these facilities. One such approach is outlined below. (author)

European experience in the transport of irradiated light-water reactor fuel

International Nuclear Information System (INIS)

Curtis, H.W.

1979-01-01

Various methods of transport of irradiated fuel flasks in Europe are described. While many problems in the transport of heavy flasks have been solved some remain and new ones have appeared. Some of these problems are the accumulation of crud on the surface of fuel elements, the problems of failed fuel, stringent criticality criteria, the ''sweating out'' of contaminated flasks, the access, road or rail, to reactor sites, and the maintenance of the transport vehicles. Some future trends in the direction of heavy flasks in the range of 75 to 100 tonnes are indicated

Transportation of failed or damaged foreign research reactor spent nuclear fuel

International Nuclear Information System (INIS)

Messick, Charles E.; Mustin, Tracy P.; Massey, Charles D.

1999-01-01

Since initiating the Foreign Research Reactor Spent Nuclear Fuel (FRR SNF) Acceptance Program in 1996, the Program has had to deal with difficult issues associated with the transportation of failed or damaged spent fuel. In several instances, problems with failed or damaged fuel have prevented the acceptance of the fuel at considerable cost to both the Department of Energy and research reactor operators. In response to the problems faced by the Acceptance Program, DOE has undertaken significant steps to better define the spent fuel acceptance criteria. DOE has worked closely with the U.S. Nuclear Regulatory Commission to address failed or damaged research reactor spent fuel causing a degradation of the fuel assembly exposing fuel meat and to identify cask certificate issues which must be resolved by cask owners and foreign regulatory authorities. The specific issues and implementation challenges associated with the transport of MTR type FRR SNF will be discussed. The information presented will include U.S. Nuclear Regulatory Commission regulatory issues, cask certificate issues, technical constraints, implementation status, and lessons learned. Specific information will also be provided on the latest efforts to revise DOE's Appendix B, Transport Package (Cask) Acceptance Criteria. The information presented in this paper will be of interest to foreign research reactor operators, shippers, and cask vendors in evaluating the condition of their fuel to ensure it can be transported in accordance with appropriate cask certificate requirements. (author)

A Study of Transport Airplane Crash-Resistant Fuel Systems

National Research Council Canada - National Science Library

Robertson, S

2002-01-01

...), of transport airplane crash-resistant fuel system (CRFS). The report covers the historical studies related to aircraft crash fires and fuel containment concepts undertaken by the FAA, NASA, and the U.S...

Regional analysis of renewable transportation fuels - production and consumption

Science.gov (United States)

Liu, Xiaoshuai

The transportation sector contributes more than a quarter of total U.S. greenhouse gas emissions. Replacing fossil fuels with renewable fuels can be a key solution to mitigate GHG emissions from the transportation sector. Particularly, we have focused on land-based production of renewable fuels from landfills and brownfield in the southeastern region of the United States. These so call marginal lands require no direct land-use change to avoid environmental impact and, furthermore, have rendered opportunities for carbon trading and low-carbon intensity business. The resources potential and production capacity were derived using federal and state energy databases with the aid of GIS techniques. To maximize fuels production and land-use efficiency, a scheme of co-location renewable transportation fuels for production on landfills was conducted as a case study. Results of economic modeling analysis indicate that solar panel installed on landfill sites could generate a positive return within the project duration, but the biofuel production within the landfill facility is relatively uncertain, requiring proper sizing of the onsite processing facility, economic scale of production and available tax credits. From the consumers' perspective, a life-cycle cost analysis has been conducted to determine the economic and environmental implications of different transportation choices by consumers. Without tax credits, only the hybrid electric vehicles have lifetime total costs equivalent to a conventional vehicles differing by about 1 to 7%. With tax credits, electric and hybrid electric vehicles could be affordable and attain similar lifetime total costs as compared to conventional vehicles. The dissertation research has provided policy-makers and consumers a pathway of prioritizing investment on sustainable transportation systems with a balance of environmental benefits and economic feasibility.

Emission factors of carbonaceous particulate matter and polycyclic aromatic hydrocarbons from residential solid fuel combustions

Energy Technology Data Exchange (ETDEWEB)

Shen, Guofeng [Jiangsu Academy of Environmental Science, Nanjing (China). Inst. of Atmospheric Sciences

2014-07-01

Emission inventory is basic for the understanding of environmental behaviors and potential effects of compounds, however, current inventories are often associated with relatively high uncertainties. One important reason is the lack of emission factors, especially for the residential solid fuel combustion in developing countries. In the present study, emission factors of a group of pollutants including particulate matter, organic carbon, elemental carbon (sometimes known as black carbon) and polycyclic aromatic hydrocarbons were measured for a variety of residential solid fuels including coal, crop straw, wood, and biomass pellets in rural China. The study provided a large number of emission factors that can be further used in emission estimation. Composition profiles and isomer ratios were investigated and compared so as to be used in source apportionment. In addition, the present study identified and quantified the influence of factors like fuel moisture, volatile matter on emission performance.

Biodiesel fuel costs and environmental issues when powering railway locomotives

Energy Technology Data Exchange (ETDEWEB)

Mirza, Abdul; Ziemer, Norbert; Tatara, Robert; Moraga, Reinaldo; Mirman, Clifford; Vohra, Promod

2010-09-15

Issues for adopting biodiesel fuel, instead of petrodiesel, to power railroad locomotives are engine performance and emissions, fuel infrastructure, and fuel cost. These are evaluated for B2 through B100 blends. Biodiesel's solvent action on fuel systems is addressed. With biodiesel, hydrocarbon, carbon monoxide, and particulate emissions are unchanged or reduced. Nitrogen oxides are elevated but it is believed that engine alterations can minimize these emissions. A Transportation Model, using data from a major railway, has demonstrated that refueling depots can be fully supplied with biodiesel at a pricing premium of 1% to 26%, depending on blend and geographical location.

Micro-Solid Oxide Fuel Cell: A multi-fuel approach for portable applications

International Nuclear Information System (INIS)

Patil, Tarkeshwar C.; Duttagupta, Siddhartha P.

2016-01-01

Highlights: • We report the oxygen ion transport properties at the electrode–electrolyte interface (EEI) of the SOFC for the first time. • This ion transport plays a key role in the overall performance of SOFCs with different fuels. • The GIIB mechanism is also studied for the first time. • GIIB is assumed to be the prime reason for low power density and ion conductivity at the EEI when using hydrocarbon fuels. • Due to its scalability, a fuel cell can serve as a power source for on-chip applications and all portable equipment. - Abstract: The impact of oxygen ion transport at the electrolyte–electrode interface of a micro-solid oxide fuel cell using different fuels is investigated. Model validation is performed to verify the results versus the reported values. Furthermore, as the hydrogen-to-carbon ratio decreases, the diffusivity of the oxygen ion increases. This increase in diffusivity is observed because the number of hydrogen atoms available as the reacting species increases in fuels with lower hydrogen-to-carbon ratios. The oxygen ion conductivity and output power density decrease as the hydrogen-to-carbon ratio of the fuels decreases. The reason behind this impact is the formation of a gas-induced ion barrier at the electrode–electrolyte interface by the CO_2 molecules formed during the reaction at the interface, thus blocking the flow of oxygen ions. As the oxygen ions become blocked, the output current contribution from the reaction also decreases and thereby affects the overall performance of the micro-solid oxide fuel cell. The experimental verification confirms this because of a significant decrease in the output power density. Furthermore, as per the application in portable devices, the appropriate choice of fuel can be chosen so that the micro-solid oxide fuel cell operates at the maximum power density.

Arrival condition of spent fuel after storage, handling, and transportation

International Nuclear Information System (INIS)

Bailey, W.J.; Pankaskie, P.J.; Langstaff, D.C.; Gilbert, E.R.; Rising, K.H.; Schreiber, R.E.

1982-11-01

This report presents the results of a study conducted to determine the probable arrival condition of spent light-water reactor (LWR) fuel after handling and interim storage in spent fuel storage pools and subsequent handling and accident-free transport operations under normal or slightly abnormal conditions. The objective of this study was to provide information on the expected condition of spent LWR fuel upon arrival at interim storage or fuel reprocessing facilities or at disposal facilities if the fuel is declared a waste. Results of a literature survey and data evaluation effort are discussed. Preliminary threshold limits for storing, handling, and transporting unconsolidated spent LWR fuel are presented. The difficulty in trying to anticipate the amount of corrosion products (crud) that may be on spent fuel in future shipments is also discussed, and potential areas for future work are listed. 95 references, 3 figures, 17 tables

Polycyclic Aromatic Hydrocarbons in Fine Particulate Matter Emitted from Burning Kerosene, Liquid Petroleum Gas, and Wood Fuels in Household Cookstoves

Science.gov (United States)

This study measured polycyclic aromatic hydrocarbon (PAH) composition in particulate matter emissions from residential cookstoves. A variety of fuel and cookstove combinations were examined, including: (i) liquid petroleum gas (LPG), (ii) kerosene in a wick stove, (iii) wood (10%...

Investigation on thermo-acoustic instability dynamic characteristics of hydrocarbon fuel flowing in scramjet cooling channel based on wavelet entropy method

Science.gov (United States)

Zan, Hao; Li, Haowei; Jiang, Yuguang; Wu, Meng; Zhou, Weixing; Bao, Wen

2018-06-01

As part of our efforts to find ways and means to further improve the regenerative cooling technology in scramjet, the experiments of thermo-acoustic instability dynamic characteristics of hydrocarbon fuel flowing have been conducted in horizontal circular tubes at different conditions. The experimental results indicate that there is a developing process from thermo-acoustic stability to instability. In order to have a deep understanding on the developing process of thermo-acoustic instability, the method of Multi-scale Shannon Wavelet Entropy (MSWE) based on Wavelet Transform Correlation Filter (WTCF) and Multi-Scale Shannon Entropy (MSE) is adopted in this paper. The results demonstrate that the developing process of thermo-acoustic instability from noise and weak signals is well detected by MSWE method and the differences among the stability, the developing process and the instability can be identified. These properties render the method particularly powerful for warning thermo-acoustic instability of hydrocarbon fuel flowing in scramjet cooling channels. The mass flow rate and the inlet pressure will make an influence on the developing process of the thermo-acoustic instability. The investigation on thermo-acoustic instability dynamic characteristics at supercritical pressure based on wavelet entropy method offers guidance on the control of scramjet fuel supply, which can secure stable fuel flowing in regenerative cooling system.

Long-Term Hydrocarbon Trade Options for the Maghreb Region and Europe—Renewable Energy Based Synthetic Fuels for a Net Zero Emissions World

Directory of Open Access Journals (Sweden)

Mahdi Fasihi

2017-02-01

Full Text Available Concerns about climate change and increasing emission costs are drivers for new sources of fuels for Europe. Sustainable hydrocarbons can be produced synthetically by power-to-gas (PtG and power-to-liquids (PtL facilities, for sectors with low direct electrification such as aviation, heavy transportation and chemical industry. Hybrid PV–Wind power plants can harvest high solar and wind potentials of the Maghreb region to power these systems. This paper calculates the cost of these fuels for Europe, and presents a respective business case for the Maghreb region. Calculations are hourly resolved to find the least cost combination of technologies in a 0.45° × 0.45° spatial resolution. Results show that, for 7% weighted average cost of capital (WACC, renewable energy based synthetic natural gas (RE-SNG and RE-diesel can be produced in 2030 for a minimum cost of 76 €/MWhHHV (0.78 €/m3SNG and 88 €/MWhHHV (0.85 €/L, respectively. While in 2040, these production costs can drop to 66 €/MWhHHV (0.68 €/m3SNG and 83 €/MWhHHV (0.80 €/L, respectively. Considering access to a WACC of 5% in a de-risking project, oxygen sales and CO2 emissions costs, RE-diesel can reach fuel-parity at crude oil prices of 101 and 83 USD/bbl in 2030 and 2040, respectively. Thus, RE-synthetic fuels could be produced to answer fuel demand and remove environmental concerns in Europe at an affordable cost.

L. Transportation of fuel and wastes

International Nuclear Information System (INIS)

1976-01-01

The principles applied to the transport of nuclear fuels and wastes have been founded on the more general provisions governing the transport of radioactive materials. Safe shipment of radioactive materials has historically been sought by specifying required characteristics in the shipping packages and establishing minimum acceptable levels of package integrity. The reason for this is that in the course of transport by road, rail, sea, or air, consignments of radioactive material are in close proximity to members of the public, and in many cases they are loaded or unloaded by transport workers who have had no special training or experience in the handling of such substances. The procedures adopted to ensure transport safety have worked satisfactorily. Both in the USA and the UK, the industry and regulatory authorities have established outstanding safety records in shipping radioactive materials over a period of thirty years. It is claimed that there have been no injuries due to the radioactive nature of the shipments, nor has there been a release of nuclear materials serious enough to be a threat of death or injury. Admittedly, about 95% of the 800,000 shipments estimated in the USA each year involve small quantities for use in industry, medicine, agriculture and education. However the principals underlying the safe packaging of these and reactor fuels are the same, and there is little reason to doubt that a similar safety record can be maintained

Physical and chemical comparison of soot in hydrocarbon and biodiesel fuel diffusion flames: A study of model and commercial fuels

Energy Technology Data Exchange (ETDEWEB)

Matti Maricq, M. [Research and Advanced Engineering, Ford Motor Company, Dearborn, MI (United States)

2011-01-15

Data are presented to compare soot formation in both surrogate and practical fatty acid methyl ester biodiesel and petroleum fuel diffusion flames. The approach here uses differential mobility analysis to follow the size distributions and electrical charge of soot particles as they evolve in the flame, and laser ablation particle mass spectrometry to elucidate their composition. Qualitatively, these soot properties exhibit a remarkably similar development along the flames. The size distributions begin as a single mode of precursor nanoparticles, evolve through a bimodal phase marking the onset of aggregate formation, and end in a self preserving mode of fractal-like particles. Both biodiesel and hydrocarbon fuels yield a common soot composition dominated by C{sub x}H{sub y}{sup +} ions, stabilomer PAHs, and fullerenes in the positive ion mass spectrum, and C{sub x}{sup -} and C{sub 2x}H{sup -} in the negative ion spectrum. These ion intensities initially grow with height in the diffusion flames, but then decline during later stages, consistent with soot carbonization. There are important quantitative differences between fuels. The surrogate biodiesel fuel methyl butanoate substantially reduces soot levels, but soot formation and evolution in this flame are delayed relative to both soy and petroleum fuels. In contrast, soots from soy and hexadecane flames exhibit nearly quantitative agreement in their size distribution and composition profiles with height, suggesting similar soot precursor chemistry. (author)

Considerations in the selection of transport modes for spent nuclear fuel shipments

International Nuclear Information System (INIS)

Daling, P.M.; McNair, G.W.; Andrews, W.B.

1985-07-01

This paper discusses the factors associated with selecting a particular transport mode for spent fuel shipments. These factors include transportation costs, economics of potential transportation accidents, risk/safety of spent fuel transportation, routing alternatives, shipping cask handling capabilities, and shipping cask availability. Data needed to estimate transportation costs and risks are presented and discussed. The remaining factors are discussed qualitatively and can be used as guidance for selecting a particular transport mode. 15 refs., 3 tabs

Commercializing an alternate transportation fuel: lessons learned from NGV

International Nuclear Information System (INIS)

Flynn, P.C.

2001-01-01

An alternate transportation fuel, compressed natural gas, was adopted in Canada in the mid-1980s due to the unique conditions present at the time. The factors that had an impact on the limited acceptance of the fuel, keeping its rate of adoption below the critical point were examined in this paper. It was revealed that a lack of infrastructure to support converted vehicles was the deciding factor. Existing refueling stations failed to become profitable, preventing further investment in refueling facilities and resulting in depressed sales of converted vehicles. Excessive parts markup by conversion dealers was another major hurdle, as was exaggerated claims for environmental and economic benefits. In addition, promotional programs were poorly designed. In the late 1980s, the relative values of oil and natural gas shifted, lowering the momentum from sales of conversions. The consequence was major players leaving the market and natural gas remained on the fringe in both Canada and the United States. Different alternate transportation fuels, including electricity and hydrogen, are being favored by new technologies and driving forces. The growth to commercial viability for those fuels will likely be influenced by some of the factors that played a role in the fate of natural gas as a transportation fuel. 4 refs., 1 fig

Dynamic analysis and application of fuel elements pneumatic transportation in a pebble bed reactor

International Nuclear Information System (INIS)

Liu, Hongbing; Du, Dong; Han, Zandong; Zou, Yirong; Pan, Jiluan

2015-01-01

Almost 10,000 spherical fuel elements are transported pneumatically one by one in the pipeline outside the core of a pebble bed reactor every day. Any failure in the transportation will lead to the shutdown of the reactor, even safety accidents. In order to ensure a stable and reliable transportation, it's of great importance to analyze the motion and force condition of the fuel element. In this paper, we focus on the dynamic analysis of the pneumatic transportation of the fuel element and derive kinetic equations. Then we introduce the design of the transportation pipeline. On this basis we calculate some important data such as the velocity of the fuel element, the force between the fuel element and the pipeline and the efficiency of the pneumatic transportation. Then we analyze these results and provide some suggestions for the design of the pipeline. The experiment was carried out on an experimental platform. The velocities of the fuel elements were measured. The experimental results were consistent with and validated the theoretical analysis. The research may offer the basis for the design of the transportation pipeline and the optimization of the fuel elements transportation in a pebble bed reactor. - Highlights: • The kinetic equations of the fuel element in pneumatic transportation are derived. • The dynamic characteristics of the fuel element are analyzed. • Some important parameters are calculated based on the kinetic equations. • The experimental results were consistent with the analysis and verified the analysis. • This paper may offer an important guide to the research of a pebble bed reactor

Determination of Critical Properties of Endothermic Hydrocarbon Fuel RP-3 Based on Flow Visualization

Science.gov (United States)

Wang, Ning; Zhou, Jin; Pan, Yu; Wang, Hui

2014-01-01

The critical pressure and temperature of an endothermic hydrocarbon fuel RP-3 were determined by flow visualization. The flow pattern images of RP-3 at different pressures and temperatures were obtained. The critical pressure is identified by disappearance of the phase change while the critical temperature is determined by appearance of the opalescence phenomenon under the critical pressure. The opalescence phenomenon is unique to the critical point. The critical pressure and temperature of RP-3 are determined to be 2.3 MPa and 646 K, respectively.

Final technical report for the Center for Catalytic Hydrocarbon Functionalization (an EFRC)

Energy Technology Data Exchange (ETDEWEB)

Gunnoe, Thomas Brent [Univ. of Virginia, Charlottesville, VA (United States)

2016-11-11

Greater than 95% of all materials produced by the chemical industry are derived from a small slate of simple hydrocarbons that are derived primarily from natural gas and petroleum, predominantly through oxygenation, C–C bond formation, halogenation or amination. Yet, current technologies for hydrocarbon conversion are typically high temperature, multi-step processes that are energy and capital intensive and result in excessive emissions (including carbon dioxide). The Center for Catalytic Hydrocarbon Functionalization (CCHF) brought together research teams with the broad coalition of skills and knowledge needed to make the fundamental advances in catalysis required for next-generation technologies to convert hydrocarbons (particularly light alkanes and methane) at high efficiency and low cost. Our new catalyst technologies offer many opportunities including enhanced utilization of natural gas in the transportation sector (via conversion to liquid fuels), more efficient generation of electricity from natural gas using direct methane fuel cells, reduced energy consumption and waste production for large petrochemical processes, and the preparation of high value molecules for use in biological/medical applications or the agricultural sector. The five year collaborative project accelerated fundamental understanding of catalyst design for the conversion of C–H bonds to functionalized products, essential to achieve the goals listed above, as evidenced by the publication of 134 manuscripts. Many of these fundamental advancements provide a foundation for potential commercialization, as evidenced by the submission of 11 patents from research support by the CCHF.

Hydrocarbon Rocket Technology Impact Forecasting

Science.gov (United States)

Stuber, Eric; Prasadh, Nishant; Edwards, Stephen; Mavris, Dimitri N.

2012-01-01

Ever since the Apollo program ended, the development of launch propulsion systems in the US has fallen drastically, with only two new booster engine developments, the SSME and the RS-68, occurring in the past few decades.1 In recent years, however, there has been an increased interest in pursuing more effective launch propulsion technologies in the U.S., exemplified by the NASA Office of the Chief Technologist s inclusion of Launch Propulsion Systems as the first technological area in the Space Technology Roadmaps2. One area of particular interest to both government agencies and commercial entities has been the development of hydrocarbon engines; NASA and the Air Force Research Lab3 have expressed interest in the use of hydrocarbon fuels for their respective SLS Booster and Reusable Booster System concepts, and two major commercially-developed launch vehicles SpaceX s Falcon 9 and Orbital Sciences Antares feature engines that use RP-1 kerosene fuel. Compared to engines powered by liquid hydrogen, hydrocarbon-fueled engines have a greater propellant density (usually resulting in a lighter overall engine), produce greater propulsive force, possess easier fuel handling and loading, and for reusable vehicle concepts can provide a shorter turnaround time between launches. These benefits suggest that a hydrocarbon-fueled launch vehicle would allow for a cheap and frequent means of access to space.1 However, the time and money required for the development of a new engine still presents a major challenge. Long and costly design, development, testing and evaluation (DDT&E) programs underscore the importance of identifying critical technologies and prioritizing investment efforts. Trade studies must be performed on engine concepts examining the affordability, operability, and reliability of each concept, and quantifying the impacts of proposed technologies. These studies can be performed through use of the Technology Impact Forecasting (TIF) method. The Technology Impact

Transportation of failed or damaged foreign research reactor spent nuclear fuel

International Nuclear Information System (INIS)

Messick, C.E.; Mustin, T.P.; Massey, C.D.

1998-01-01

Since resuming the Foreign Research Reactor Spent Nuclear Fuel (FRR SNF) Acceptance Program in 1996, the Program has had to deal with difficult issues associated with the transportation of failed or damaged spent fuel. In several instances, problems with failed or damaged fuel have prevented the acceptance of the fuel at considerable cost to both the Department of Energy (DOE) and research reactor operators. In response to the problems faced by the Acceptance Program, DOE has undertaken significant steps to better define the spent fuel acceptance criteria. DOE has worked closely with the U.S. Nuclear Regulatory Commission to address failed or damaged research reactor spent fuel and to identify cask certificate issues which must be resolved by cask owners and foreign regulatory authorities. The specific issues associated with the transport of Materials Testing Reactor (MTR)-type FRR SNF will be discussed. The information presented will include U.S. Nuclear Regulatory Commission regulatory issues, cask certificate issues, technical constraints, and lessons learned. Specific information will also be provided on the latest efforts to revise DOE's Appendix B, Transport Package (Cask) Acceptance Criteria. The information presented in this paper will be important to foreign research reactor operators, shippers, and cask vendors, so that appropriate amendments to the Certificate of Compliance for spent fuel casks can be submitted in a timely manner to facilitate the safe and scheduled transport of FRR SNF

Summary report on transportation of nuclear fuel materials in Japan : transportation infrastructure, threats identified in open literature, and physical protection regulations.

Energy Technology Data Exchange (ETDEWEB)

Cochran, John Russell; Ouchi, Yuichiro (Japan Atomic Energy Agency, Japan); Furaus, James Phillip; Marincel, Michelle K.

2008-03-01

This report summarizes the results of three detailed studies of the physical protection systems for the protection of nuclear materials transport in Japan, with an emphasis on the transportation of mixed oxide fuel materials1. The Japanese infrastructure for transporting nuclear fuel materials is addressed in the first section. The second section of this report presents a summary of baseline data from the open literature on the threats of sabotage and theft during the transport of nuclear fuel materials in Japan. The third section summarizes a review of current International Atomic Energy Agency, Japanese and United States guidelines and regulations concerning the physical protection for the transportation of nuclear fuel materials.

Transport of volatile fission products in the fuel-to-sheath gap of defective fuel elements during normal and reactor accident conditions

International Nuclear Information System (INIS)

Lewis, B.J.; Bonin, H.W.

1995-01-01

An analytical treatment has been used to model the vapour transport of radioactive fission products released into the fuel-to-sheath gap of defective nuclear fuel elements. The model accounts for both diffusive and bulk-convective transport. Convective transport becomes important as a result of a significant release of gaseous fission products into the gap during a high-temperature reactor accident. However, during normal reactor operation, diffusion is shown to be the dominant process of transport. The model is based on an analysis of several in-reactor tests with operating defective fuel elements, and high-temperature annealing experiments with irradiated fuel specimens. ((orig.))

Present status and prospect of spent fuel transportation

International Nuclear Information System (INIS)

Adachi, H.

1987-01-01

Problems linked with spent fuel transportation in Japan, where there are 35 NPPs in operation, are considered. Every year about 500 t U are shipped to fuel reprocessing plants in Japan, as well as in France and UK. Four kinds of casks: HZ, EXCELLOX, TN and TK - are used for this purpose. By the mid-1990's it is suggested to build in Japan fuel reprocessing plant with capacity of 800 t U per year

Improvement of lean combustion characteristics of heavy-hydrocarbon fuels with hydrogen addition; Suiso tenka ni yoru kokyu tanka suisokei nenryo no kihaku nensho no kaizen

Energy Technology Data Exchange (ETDEWEB)

Sakai, Y. [Saitama Institute of Technology, Saitama (Japan); Ishizuka, S. [Hiroshima University, Hiroshima (Japan). Faculty of Engineering

1999-09-25

The Lewis numbers of lean heavy-hydrocarbon fuels are larger than unity, and hence, their flames are prone to extinction in a shear flow, which occurs in a turbulent combustion. Here, propane is used as a representative fuel of heavy-hydrocarbon fuels because the Lewis number of lean propane/air mixtures is larger than unity, and an attempt to improve its combustion characteristics by hydrogen addition has been made. A tubular flame burner is used to evaluate its improvement, since a rotating, stretched vortex flow is established in the burner. The results show that with' hydrogen addition, the fuel concentration, the flame diameter and the flame temperature at extinction are reduced and its combustion characteristics are improved. However, it is found that the effective equivalence ration at extinction cannot become so small as that of lean methane/air mixture, which has a Lewis number less than unity. (author)

The single SNR fuel assembly container (ESBB) to transport unirradiated SNR 300 fuel assemblies

International Nuclear Information System (INIS)

Hilbert, F.; Hottenrott, G.

1998-01-01

In this paper a new type B(U) package design is presented. The Single SNR Fuel Assembly Container (ESBB) is designed for the transport and storage of a single SNR 300 fuel assembly. This package is the main component for the future interim storage of the fuel assemblies in heavy storage casks. Its benefits are that it is compatible with the Category I transport system of Nuclear Cargo + Service NCS) used in Germany and that it can be easily handled at the current storage locations as well as in an interim storage facility. In total 205 fuel assemblies are currently stored in Hanau, Germany and Dounreay, U.K. Former studies have shown, that heavy transport and storage casks can be handled there only with considerable efforts. But the required category I transport to an interim storage is not reasonably feasible. To overcome these problems the ESBB was designed. It consists of a stainless steel tube with welded bottom, a welded plug as closure system and shock absorbers 26 packages at maximum can be transported in one batch with the NCS security vehicle. The safety analysis shows that the package complies with IAEA 1996. Standard calculations methods and computer codes like HEATING 7.2 (Childs 1993) have been used for the analysis. Criticality safety assessment is based on conservative assumptions as required in IAEA 1996. Drop tests carried out by BAM will be used to verify the design. These tests are scheduled for mid 1998. For the validation of the design prototypes have already been manufactured. Handling tests show that the design complies with the requirements. Preliminary drop tests show that the certification drop tests will be passed positively. (authors)

Basic planning of a newly built exclusive ship for spent fuel transport

International Nuclear Information System (INIS)

Obara, I.; Sasao, T.; Akiyama, H.; Kybota, T.

1998-01-01

A commercial reprocessing plant is under construction at the Fuel Cycle Facilities in Rokkasho-mura, Aomori Prefecture. To prepare for the transport of spent nuclear fuels (SF) from all Japanese nuclear power stations to this reprocessing plant, the need for an exclusive transport ship was recognized. Nuclear Fuel Transport Co. Ltd. (NFT), in cooperation with electric power utilities planned the construction of such a ship over a period of several years. During this period NFT developed new types of cask to transport high burn-up spent fuels to the reprocessing plant. Six kinds of casks were developed and 40 units are now under fabrication. The ship was designed to carry a maximum of 20 units. Based on the Irradiated Nuclear Fuel (INF) Code adopted by the International Maritime Organization (IMO), the Japanese Ministry of Transport (MoT) issued new domestic regulations in September, 1995 which covered design criteria for ships carrying Irradiated Nuclear Fuels. The new SF transport ship is the first one to which this new regulation was applied. Although the ship will only ply the coastal routes of Japan, she has been designed to conform with all the international requirements for the Class-3 of the INF Code. In May 1995, Nuclear Fuel Shipping Co. Ltd (NFS), a wholly-owned subsidiary of NFT, concluded a contract with Mitsui Engineering and Shipbuilding Co., Ltd. for the construction of the exclusive transport ship. The keel was laid in November 1995. The ship was launched in april 1996 and named 'Rokuei-Maru'. At the end of September, she was completed and delivered to the ship owner, NFS. (authors)

Two-dimensional radiation shielding optimization analysis of spent fuel transport container

International Nuclear Information System (INIS)

Tian Yingnan; Chen Yixue; Yang Shouhai

2013-01-01

The intelligent radiation shielding optimization design software platform is a one-dimensional multi-target radiation shielding optimization program which is developed on the basis of the genetic algorithm program and one-dimensional discrete ordinate program-ANISN. This program was applied in the optimization design analysis of the spent fuel transport container radiation shielding. The multi-objective optimization calculation model of the spent fuel transport container radiation shielding was established, and the optimization calculation of the spent fuel transport container weight and radiation dose rate was carried by this program. The calculation results were checked by Monte-Carlo program-MCNP/4C. The results show that the weight of the optimized spent fuel transport container decreases to 81.1% of the origin and the radiation dose rate decreases to below 65.4% of the origin. The maximum deviation between the calculated values from the program and the MCNP is below 5%. The results show that the optimization design scheme is feasible and the calculation result is correct. (authors)

Alternative Fuel Transportation Optimization Tool : Description, Methodology, and Demonstration Scenarios.

Science.gov (United States)

2015-09-01

This report describes an Alternative Fuel Transportation Optimization Tool (AFTOT), developed by the U.S. Department of Transportation (DOT) Volpe National Transportation Systems Center (Volpe) in support of the Federal Aviation Administration (FAA)....

Method of making a graphite fuel element having carbonaceous fuel bodies

International Nuclear Information System (INIS)

Miertschin, G.N.; Leary, D.F.

1977-01-01

Particulate nuclear fuel material, particulate carbon and pitch are combined with an additive which is effective to reduce the coke yield upon carbonization to mold a green fuel body. The additive may be polystyrene, a styrene-butadiene copolymer, an aromatic hydrocarbon having a molecular weight between about 75 and 300 or a saturated hydrocarbon polymer. The green fuel body is inserted in a complementary cavity within a porous nuclear fuel element body and heated in situ to decompose the pitch and additive, leaving a relatively close-fitting fuel body in the cavity

Spent nuclear fuel transport problems

International Nuclear Information System (INIS)

Kondrat'ev, A.N.; Kosarev, Yu.A.; Yulikov, E.I.

1977-01-01

The paper considers the problems of shipping spent fuel from nuclear power stations to reprocessing plants and also the principal ways of solving these problems with a view to achieving maximum economy and safety in transport. The increase in the number of nuclear power plants in the USSR will entail an intensification of spent-fuel shipments. Higher burnup and the need to reduce cooling time call for heavier and more complex shipping containers. The problem of shipping spent fuel should be tackled comprehensively, bearing in mind the requirements of safety and economy. One solution to these problems is to develop rational and cheap designs of such containers. In addition, the world-wide trend towards more thorough protection of the environment against pollution and of the health of the population requires the devotion of constant attention to improving the reliability and safety of shipments. The paper considers the prospects for nuclear power development in the USSR and in other member countries of the CMEA (1976-1980), the composition and design of some Soviet packaging assemblies, the appropriate cooling time for spent fuel from thermal reactor power stations, procedures for reducing fuel-shipping costs, some methodological problems of container calculation and design, and finally problems of testing and checking containers on test rigs. (author)

Hydrocarbons and air pollution

International Nuclear Information System (INIS)

Herz, O.

1992-01-01

This paper shows the influence of hydrocarbons vapors, emitted by transports or by volatile solvents using, on air pollution. Hydrocarbons are the principal precursors of photochemical pollution. After a brief introduction on atmospheric chemistry and photochemical reactions, the author describes the french prevention program against hydrocarbons emissions. In the last chapter, informations on international or european community programs for photochemical pollution study are given. 5 figs., 10 tabs

Effects of fuel particle size distributions on neutron transport in stochastic media

International Nuclear Information System (INIS)

Liang, Chao; Pavlou, Andrew T.; Ji, Wei

2014-01-01

Highlights: • Effects of fuel particle size distributions on neutron transport are evaluated. • Neutron channeling is identified as the fundamental reason for the effects. • The effects are noticeable at low packing and low optical thickness systems. • Unit cells of realistic reactor designs are studied for different size particles. • Fuel particle size distribution effects are not negligible in realistic designs. - Abstract: This paper presents a study of the fuel particle size distribution effects on neutron transport in three-dimensional stochastic media. Particle fuel is used in gas-cooled nuclear reactor designs and innovative light water reactor designs loaded with accident tolerant fuel. Due to the design requirements and fuel fabrication limits, the size of fuel particles may not be perfectly constant but instead follows a certain distribution. This brings a fundamental question to the radiation transport computation community: how does the fuel particle size distribution affect the neutron transport in particle fuel systems? To answer this question, size distribution effects and their physical interpretations are investigated by performing a series of neutron transport simulations at different fuel particle size distributions. An eigenvalue problem is simulated in a cylindrical container consisting of fissile fuel particles with five different size distributions: constant, uniform, power, exponential and Gaussian. A total of 15 parametric cases are constructed by altering the fissile particle volume packing fraction and its optical thickness, but keeping the mean chord length of the spherical fuel particle the same at different size distributions. The tallied effective multiplication factor (k eff ) and the spatial distribution of fission power density along axial and radial directions are compared between different size distributions. At low packing fraction and low optical thickness, the size distribution shows a noticeable effect on neutron

Electricity as Transportation ``Fuel''

Science.gov (United States)

Tamor, Michael

2013-04-01

The personal automobile is a surprisingly efficient device, but its place in a sustainable transportation future hinges on its ability use a sustainable fuel. While electricity is widely expected to be such a ``fuel,'' the viability of electric vehicles rests on the validity of three assumptions. First, that the emissions from generation will be significantly lower than those from competing chemical fuels whether `renewable' or fossil. Second, that advances in battery technology will deliver adequate range and durability at an affordable cost. Third, that most customers will accept any functional limitations intrinsic to electrochemical energy storage. While the first two are subjects of active research and vigorous policy debate, the third is treated virtually as a given. Popular statements to the effect that ``because 70% of all daily travel is accomplished in less than 100 miles, mass deployment of 100 mile EVs will electrify 70% of all travel'' are based on collections of one-day travel reports such as the National Household Travel Survey, and so effectively ignore the complexities of individual needs. We have analyzed the day-to-day variations of individual vehicle usage in multiple regions and draw very different conclusions. Most significant is that limited EV range results in a level of inconvenience that is likely to be unacceptable to the vast majority of vehicle owners, and for those who would accept that inconvenience, battery costs must be absurdly low to achieve any economic payback. In contrast, the plug-in hybrid (PHEV) does not suffer range limitations and delivers economic payback for most users at realistic battery costs. More importantly, these findings appear to be universal in developed nations, with labor market population density being a powerful predictor of personal vehicle usage. This ``scalable city'' hypothesis may prove to a powerful predictor of the evolution of transportation in the large cities of the developing world.

Review of current results in computational studies of hydrocarbon phase and transport properties in nanoporous structures

Science.gov (United States)

Stroev, N.; Myasnikov, A.

2017-12-01

This article provides a general overview of the main simulation results on the behavior of gas/liquids under confinement conditions, namely hydrocarbons in shale formations, and current understanding of such phenomena. In addition to the key effects, which different research groups obtained and which have to be taken into account during the creation of reservoir simulation software, a list of methods is briefly covered. Comprehensive understanding of both fluid phase equilibrium and transport properties in nanoscale structures is of great importance for many scientific and technical disciplines, especially for petroleum engineering considering the hydrocarbon behavior in complex shale formations, the development of which increases with time. Recent estimations show that a significant amount of resources are trapped inside organic matter and clays, which has extremely low permeability and yet great economic potential. The issue is not only of practical importance, as the existing conventional approaches by definition are unable to capture complicated physics phenomena for effective results, but it is also of fundamental value. The research of the processes connected with such deposits is necessary for both evaluations of petroleum reservoir deposits and hydrodynamic simulators. That is why the review is divided into two major parts—equilibrium states of hydrocarbons and their transport properties in highly confined conditions.

Real driving emissions and fuel consumption characteristics of Istanbul public transportation

Directory of Open Access Journals (Sweden)

Ozener Orkun

2017-01-01

Full Text Available Public transportation, which uses intra city lines frequently, has vital importance on the cities air pollution. The fossil fuel based drive units, which emits pollutants, are the primary source of this interest. Also, the fuel consumption is another major concern because of economic aspects. For an efficient and clear transportation, the pollutants and fuel consumption has to be analyzed, considering the operating conditions. In this context, the Metrobus line of Istanbul city which crosses from European side to Asian side of the city was analyzed with portable emission measurement system and portable fuel consumption meter devices. The relevant bus operating data were also collected during the operation. The data were analyzed while considering the operating modes like acceleration, deceleration, and constant speed cruises. The emission factors were developed. The pollutant emissions generally decreased as the vehicle speed increased while the fuel consumption increased for the same acceleration level. These results show the importance of operating conditions and their non-linear effect on emissions and fuel consumption Istanbul public transportation.

Evaluation of next generation biomass derived fuels for the transport sector

International Nuclear Information System (INIS)

Tsita, Katerina G.; Pilavachi, Petros A.

2013-01-01

This paper evaluates next generation biomass derived fuels for the transport sector, employing the Analytic Hierarchy Process. Eight different alternatives of fuels are considered in this paper: bio-hydrogen, bio-synthetic natural gas, bio-dimethyl ether, bio-methanol, hydro thermal upgrading diesel, bio-ethanol, algal biofuel and electricity from biomass incineration. The evaluation of alternative fuels is performed according to various criteria that include economic, technical, social and policy aspects. In order to evaluate each alternative fuel, one base scenario and five alternative scenarios with different weight factors selection per criterion are presented. After deciding the alternative fuels’ scoring against each criterion and the criteria weights, their synthesis gives the overall score and ranking for all alternative scenarios. It is concluded that synthetic natural gas and electricity from biomass incineration are the most suitable next generation biomass derived fuels for the transport sector. -- Highlights: •Eight alternative fuels for the transport sector have been evaluated. •The method of the AHP was used. •The evaluation is performed according to economic, technical, social and policy criteria. •Bio-SNG and electricity from biomass incineration are the most suitable fuels

Subcontinuum mass transport of hydrocarbons in nanoporous media and long-time kinetics of recovery from unconventional reservoirs

Science.gov (United States)

Bocquet, Lyderic

2015-11-01

In this talk I will discuss the transport of hydrocarbons across nanoporous media and analyze how this transport impacts at larger scales the long-time kinetics of hydrocarbon recovery from unconventional reservoirs (the so-called shale gas). First I will establish, using molecular simulation and statistical mechanics, that the continuum description - the so-called Darcy law - fails to predict transport within a nanoscale organic matrix. The non-Darcy behavior arises from the strong adsorption of the alkanes in the nanoporous material and the breakdown of hydrodynamics at the nanoscale, which contradicts the assumption of viscous flow. Despite this complexity, all permeances collapse on a master curve with an unexpected dependence on alkane length, which can be described theoretically by a scaling law for the permeance. Then I will show that alkane recovery from such nanoporous reservoirs is dynamically retarded due to interfacial effects occuring at the material's interface. This occurs especially in the hydraulic fracking situation in which water is used to open fractures to reach the hydrocarbon reservoirs. Despite the pressure gradient used to trigger desorption, the alkanes remain trapped for long times until water desorbs from the external surface. The free energy barrier can be predicted in terms of an effective contact angle on the composite nanoporous surface. Using a statistical description of the alkane recovery, I will then demonstrate that this retarded dynamics leads to an overall slow - algebraic - decay of the hydrocarbon flux. Such a behavior is consistent with algebraic decays of shale gas flux from various wells reported in the literature. This work was performed in collaboration with B. Coasne, K. Falk, T. Lee, R. Pellenq and F. Ulm, at the UMI CNRS-MIT, Massachusetts Institute of Technology, Cambridge, USA.

Study of fuel systems for LH2-fueled subsonic transport aircraft, volume 1

Science.gov (United States)

Brewer, G. D.; Morris, R. E.; Davis, G. W.; Versaw, E. F.; Cunnington, G. R., Jr.; Riple, J. C.; Baerst, C. F.; Garmong, G.

1978-01-01

Several engine concepts examined to determine a preferred design which most effectively exploits the characteristics of hydrogen fuel in aircraft tanks received major emphasis. Many candidate designs of tank structure and cryogenic insulation systems were evaluated. Designs of all major elements of the aircraft fuel system including pumps, lines, valves, regulators, and heat exchangers received attention. Selected designs of boost pumps to be mounted in the LH2 tanks, and of a high pressure pump to be mounted on the engine were defined. A final design of LH2-fueled transport aircraft was established which incorporates a preferred design of fuel system. That aircraft was then compared with a conventionally fueled counterpart designed to equivalent technology standards.

Transportation capabilities study of DOE-owned spent nuclear fuel

Energy Technology Data Exchange (ETDEWEB)

Clark, G.L.; Johnson, R.A.; Smith, R.W. [Packaging Technology, Inc., Tacoma, WA (United States); Abbott, D.G.; Tyacke, M.J. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States)

1994-10-01

This study evaluates current capabilities for transporting spent nuclear fuel owned by the US Department of Energy. Currently licensed irradiated fuel shipping packages that have the potential for shipping the spent nuclear fuel are identified and then matched against the various spent nuclear fuel types. Also included are the results of a limited investigation into other certified packages and new packages currently under development. This study is intended to support top-level planning for the disposition of the Department of Energy`s spent nuclear fuel inventory.

Fuel Consumption Management in the Transportation Sector in Iran

DEFF Research Database (Denmark)

Dastjerdi, Aliasghar M.; Araghi, Bahar Namaki

2011-01-01

Energy consumption in the transportation sector in Iran is significantly higher than global norms and standards which caused some issues including wasting national resources, deteriorating air quality, GHG emissions etc. The major purpose of this paper is to introduce practical policies, strategies...... and technologies to reduce liquid fuel consumption known as a dominant source of energy in transport sector in Iran. Since, the road subsector has the major share in consuming liquid fuel amongst others, more attention is given to the methods for reducing consumption in this subsector. The relating policies...... and actions were classified by optimization measures according to four separate categories as follows; “Optimization of Supply of Transportation Services”, “Optimization of Transport Demand”, “Optimization of Energy Consumption” and “Optimization of Car Manufacturing”....

Usage Inspection of KN-12 Spent Fuel Transport Cask

International Nuclear Information System (INIS)

Lee, J. C.; Seo, K. S.; Bang, K. S.; Cho, I. J.; Kim, D. H.; Min, D. K.

2007-03-01

The usage inspection of the KN-12 spent nuclear fuel transport package was performed to receive the license for reuse. According to the Korea Atomic Energy Act, all type B transport package should receive and pass the usage inspection every five years. The KN-12 transport cask was designed to transport twelve spent PWR fuel assemblies under wet and dry conditions. The cask was developed and licensed in 2002 in accordance with the Korea and the IAEA's safe transport regulations. The areas of usage inspection include: visual inspection, nondestructive weld inspection, load test, maximum operating pressure test, leakage test, shielding test, thermal test, external surface contamination test. In the results of the usage inspection, the damage or defect could not found out and the performance of the cask was maintained according to the requirements of the regulation. Therefore, the usage inspection was successfully performed to acquire the license for the reuse

Experience of air transport of nuclear fuel material in Japan

International Nuclear Information System (INIS)

Yamashita, T.; Toguri, D.; Kawasaki, M.

2004-01-01

Certified Reference Materials (hereafter called as to CRMs), which are indispensable for Quality Assurance and Material Accountability in nuclear fuel plants, are being provided by overseas suppliers to Japanese nuclear entities as Type A package (non-fissile) through air transport. However, after the criticality accident at JCO in Japan, special law defining nuclear disaster countermeasures (hereafter called as to the LAW) has been newly enforced in June 2000. Thereafter, nuclear fuel materials must meet not only to the existing transport regulations but also to the LAW for its transport

Research reactor fuel transport in the U.K

Energy Technology Data Exchange (ETDEWEB)

Panter, R [U.K. Atomic Energy Authority, Harwell (United Kingdom)

1983-09-01

This paper describes the containers currently used for transport of fresh or spent fuel elements for Research and Materials Test Reactors in the U.K., their status, operating procedures and some of the practical difficulties. In the U.K., MTR fuel cycle work is almost entirely the responsibility of the U.K. Atomic Energy Authority.

Biological Production of a Hydrocarbon Fuel Intermediate Polyhydroxybutyrate (PHB) from a Process Relevant Lignocellulosic Derived Sugar (Poster)

Energy Technology Data Exchange (ETDEWEB)

Wang, W.; Mittal, A.; Mohagheghi, A.; Johnson, D. K.

2014-04-01

PHAs are synthesized by many microorganisms to serve as intracellular carbon storage molecules. In some bacterial strains, PHB can account for up to 80% of cell mass. In addition to its application in the packaging sector, PHB also has great potential as an intermediate in the production of hydrocarbon fuels. PHB can be thermally depolymerized and decarboxylated to propene which can be upgraded to hydrocarbon fuels via commercial oligomerization technologies. Cupriavidus necator is the microorganism that has been most extensively studied and used for PHB production on an industrial scale; However the substrates used for producing PHB are mainly fructose, glucose, sucrose, fatty acids, glycerol, etc., which are expensive. In this study, we demonstrate production of PHB from a process relevant lignocellulosic derived sugar stream, i.e., saccharified slurry from pretreated corn stover. The strain was first investigated in shake flasks for its ability to utilize glucose, xylose and acetate. In addition, the strain was also grown on pretreated lignocellulose hydrolyzate slurry and evaluated in terms of cell growth, sugar utilization, PHB accumulation, etc. The mechanism of inhibition in the toxic hydrolysate generated by the pretreatment and saccharification process of biomass, was also studied.

Integrated spent fuel storage and transportation system using NUHOMS

International Nuclear Information System (INIS)

Lehnert, R.; McConaghy, W.; Rosa, J.

1990-01-01

As utilities with nuclear power plants face increasing near term spent fuel store needs, various systems for dry storage such as the NUTECH Horizontal Modular Storage (NUHOMS) system are being implemented to augment existing spent fuel pool storage capacities. These decisions are based on a number of generic and utility specific considerations including both short term and long term economics. Since the US Department of Energy (DOE) is tasked by the Nuclear Waste Policy Act with the future responsibility of transporting spent fuel from commercial nuclear power plants to a Monitored Retrievable Storage (MRS) facility anchor a permanent geologic repository, the interfaces between the utilities at-reactor dry storage system and the DOE's away-from-reactor transportation system become important. This paper presents a study of the interfaces between the current at-reactor NUHOMS system and the future away-from-reactor DOE transportation system being developed under the Office of Civilian Radioactive Waste Management (OCRWM) program. 7 refs., 9 figs., 1 tab

Biological Production of a Hydrocarbon Fuel Intermediate Polyhydroxybutyrate (Phb) from a Process Relevant Lignocellulosic Derived Sugar

Energy Technology Data Exchange (ETDEWEB)

Wang, Wei; Mohagheghi, Ali; Mittal, Ashutosh; Pilath, Heidi; Johnson, David K.

2015-03-22

PHAs are synthesized by many microorganisms to serve as intracellular carbon storage molecules. In some bacterial strains, PHB can account for up to 80% of cell mass. In addition to its application in the packaging sector, PHB also has great potential as an intermediate in the production of hydrocarbon fuels. PHB can be thermally depolymerized and decarboxylated to propene which can be upgraded to hydrocarbon fuels via commercial oligomerization technologies. In recent years a great effort has been made in bacterial production of PHB, yet the production cost of the polymer is still much higher than conventional petrochemical plastics. The high cost of PHB is because the cost of the substrates can account for as much as half of the total product cost in large scale fermentation. Thus searching for cheaper and better substrates is very necessary for PHB production. In this study, we demonstrate production of PHB by Cupriavidus necator from a process relevant lignocellulosic derived sugar stream, i.e., saccharified hydrolysate slurry from pretreated corn stover. Good cell growth was observed on slurry saccharified with advanced enzymes and 40~60% of PHB was accumulated in the cells. The mechanism of inhibition in the toxic hydrolysate generated by pretreatment and saccharification of biomass, will be discussed.

Efficiency Analysis of Technological Methods for Reduction of NOx Emissions while Burning Hydrocarbon Fuels in Heat and Power Plants

Directory of Open Access Journals (Sweden)

S. M. Kabishov

2013-01-01

Full Text Available The paper contains a comparative efficiency analysis pertaining to application of existing technological methods for suppression of nitric oxide formation in heating boilers of heat generators. A special attention has been given to investigation of NOx  emission reduction while burning hydrocarbon fuel with the help of oxygen-enriched air. The calculations have demonstrated that while enriching oxidizer with the help of oxygen up to 50 % (by volume it is possible to reduce volume of NOx formation (while burning fuel unit by 21 %.

Potential exposures and health effects from spent fuel transportation

International Nuclear Information System (INIS)

Sandquist, G.M.; Rogers, V.C.

1986-01-01

The radiation exposures and consequent health effects associated with normal operations and accidents during transportation of spent fuel have been analyzed and evaluated. This study was performed for the U.S. Department of Energy (DOE) as contributory data for response to specific public inquires regarding the Draft Environmental Assessments issued by DOE in 1984. Large quantities of spent fuel from power reactors will be shipped by truck and/or rail from the site of generation or temporary storage to nuclear waste repositories. This transportation activity has the potential for increasing radiation exposures and risks above normal background levels in the vicinity of the transportation route. For normal, accident-free transport of spent fuel, radiation exposures arise from both gamma and neutron sources within the spent fuel cask. U.S. regulations limit the radiation dose equivalent rate to 10 millirem per hour at any point 2 meters from the outer lateral surfaces of the transport vehicle. Computer program PATHRAE-T was developed and employed to determine the total, combined dose field. PATHRAE-T was used to estimate the maximum individual doses from rail cask accidents. The maximum individual exposure, primarily due to inhalation, is about 10 rem and occurs about 70 meters downwind. Ground deposited nuclides account for 99 percent of the population dose. The maximum population dose accident could result in about 22 latent health effects for the urban population. The same case rail cask accidents were also evaluated for a maximum water pathway contamination scenario. The nuclide contaminated plume was assumed to be transported over a large reservoir used for domestic and agricultural water. This accident could result in a 63,000 person-rem dose causing about 13 latent health effects in the absence of any natural and industrial processes for nuclide removal from the water

Regulations concerning the transport of nuclear fuel materials outside the works or the enterprise

International Nuclear Information System (INIS)

1979-01-01

The regulations are defined under the law for the regulations of nuclear source materials, nuclear fuel materials and reactors and the order for execution of the law. Basic concepts and terms are explained, such as: vehicle transport; easy transport; nuclear fuel material load, exclusive loading, employee, accumulative dose and exposure dose. Technical standards of vehicle transport are specified in detail on nucler fuel materials as nuclear fuel load, L,A, EM and BU type of load, nuclear fuel load of fission substances, the second and third type of fission load and materials contaminated by nuclear fuel substances to be carried not as nuclear fuel loads. Special exceptional measures to such transport and technical standards of easy transport are also designated. The application for confirmation of the transport shall be filed to the Director General of Science and Technology Agency according to the form attached with documents explaining nuclear fuel materials to be transferred, the vessel of such materials and construction, material and method of production of such a vessel, safety of nuclear materials contained, etc. Measures in dangerous situations shall be taken to fight a fire or prohibit the entrance of persons other than the staff concerned. Reports shall be presented in 10 days to the Director, when theft, loss or irregular leaking of nuclear fuel materials or personal troubles occur on the way. (Okada, K.)

Methods of reforming hydrocarbon fuels using hexaaluminate catalysts

Science.gov (United States)

Gardner, Todd H [Morgantown, WV; Berry, David A [Morgantown, WV; Shekhawat, Dushyant [Morgantown, WV

2012-03-27

A metal substituted hexaaluminate catalyst for reforming hydrocarbon fuels to synthesis gas of the general formula AB.sub.yAl.sub.12-yO.sub.19-.delta., A being selected from alkali metals, alkaline earth metals and lanthanide metals or mixtures thereof. A dopant or surface modifier selected from a transitions metal, a spinel of an oxygen-ion conductor is incorporated. The dopant may be Ca, Cs, K, La, Sr, Ba, Li, Mg, Ce, Co, Fe, Ir, Rh, Ni, Ru, Cu, Pe, Os, Pd, Cr, Mn, W, Re, Sn, Gd, V, Ti, Ag, Au, and mixtures thereof. The oxygen-ion conductor may be a perovskite selected from M'RhO.sub.3, M'PtO.sub.3, M'PdO.sub.3, M'IrO.sub.3, M'RuO.sub.3 wherein M'=Mg, Sr, Ba, La, Ca; a spinel selected from MRh.sub.2O.sub.4, MPt.sub.2O.sub.4, MPd.sub.2O.sub.4, MIr.sub.2O.sub.4, MRu.sub.2O.sub.4 wherein M=Mg, Sr, Ba, La, Ca and mixtures thereof; a florite is selected from M''O.sub.2.

Fuel transporting device in nuclear reactor

International Nuclear Information System (INIS)

Inoue, Tatsumi.

1975-01-01

Object: To obtain a support structure of an excellent quakeproof property for a fuel transporting device provided for the transportation of fuel between a reactor building and an auxiliary building in a pressure tube reactor or the like. Structure: The structure comprises an oblique transfer chute loosely penetrating the reactor building, reactor container and auxiliary building, a transfer chute support outer cylinder surrounding the transfer chute and having one end coupled to the transfer chute and other end coupled to the container, flexible seal members respectively provided on the reactor building side and on the auxiliary building side and surrounding the transfer chute and a slidable support supported on the side of the auxiliary building such that it can be in frictional contact with the outer periphery of the transfer chute. With this construction, the relative displacements of various parts caused by an earthquake or the like can be absorbed by the support outer cylinder, flexible seals and slidable support. (Ikeda, J.)

Postulated accident scenarios for the on-site transport of spent nuclear fuel

International Nuclear Information System (INIS)

Morandin, G.; Sauve, R.

2004-01-01

Once a spent fuel container is loaded with spent fuel it typically travels on-site to a processing building for permanent lid attachment. During on-site transport a lid clamp is utilized to ensure the container lid remains in place. The safe on-site transport of spent nuclear fuel must rely on the structural integrity of the transport container and system of transport. Regard for on-site traffic and safe, efficient travel routes are important and manageable with well thought-out planning. Non-manageable incidences, such as flying debris from tornado force winds or postulated blasts in proximity to the transport container, that may result in high velocity impact and shock loading on the transport system must be considered. This paper consists of simulations that consider these types of postulated accident scenarios using detailed nonlinear finite element techniques

Preliminary assessment of costs and risks of transporting spent fuel by barge

International Nuclear Information System (INIS)

Tobin, R.L.; Meshkov, N.K.; Jones, R.H.

1985-12-01

The purpose of this study is to analyze the costs and risks associated with transporting spent fuel by barge. The barge movements would be made in combination with rail movements to transport spent fuel from plants to a repository. For the purpose of this analysis, three candidate repository sites are analyzed: Yucca Mountain, Nevada, Deaf Smith, Texas, and Hanford, Washington. This report complements a report prepared by Sandia National Laboratories in 1984 that analyzes the costs and risks of transporting spent fuel by rail and by truck to nine candidate repository sites

Spent nuclear fuel and high level radioactive waste transportation. White paper

International Nuclear Information System (INIS)

1985-06-01

The High-Level Radioactive Waste Committee of the Western Interstate Energy Board has been involved in a year-long cooperative project with the US Department of Energy (DOE) to develop an information base on the transportation of spent nuclear fuel and high-level radioactive waste (HLW) so that western states can be constructive and informed participants in the repository program under the Nuclear Waste Policy Act (NWPA). The historical safety record of transportation of HLW and spent fuel is excellent; no release of these radioactive materials has ever occurred during transportation. Projected shipments under the NWPA will, however, greatly exceed current shipments in the US. For example, over the past five years, 119 metric tons of civilian spent fuel have been shipped in this country, while shipments to the first and second repository are each expected to peak at 3000 metric tons per year. The Committee believes that the successful development and operation of a national HLW/spent fuel transportation system can best be accomplished through an open process based on the common sense approach of taking all reasonable measures to minimize public risk and performing whatever actions are reasonably required to promote public acceptance. Therefore, the Committee recommends that the Department of Energy further the goals of the NWPA by developing a Comprehensive Transportation Plan which adopts a systematic, comprehensive, and integrated approach to resolving all spent fuel and HLW transportation issues in a timely manner. The suggested scope of such a plan is discussed in this White paper. Many of the suggested elements of such a plan are similar to those being developed by the Department of energy for inclusion in the Department's Transportation Institutional Plan

Problems relating to international transport of nuclear fuels

International Nuclear Information System (INIS)

Timm, U.E.

1985-01-01

Owing to the tremendous geographic distances between uranium deposits of interest, to the various degrees of sophistication of nuclear industry in industrialized countries and to the close international cooperation in the field of nuclear energy, safe international transports, physical protection and transport handling play an important role. It is suggested to better coordinate the activities of nuclear power plant operators, the nuclear industry and specialized transport companies with respect to all national and international issues of nuclear fuel transports. (DG) [de

Fuel Prices as a Factor of Shaping Profitability of Road Transport in Poland

Directory of Open Access Journals (Sweden)

Marzantowicz Łukasz

2016-12-01

Full Text Available The goal of this article is to determine the relation between the price of fuel and the profitability of the company. For this purpose, the article defines the profitability of transport enterprises and points the source of the impact of changes in fuel prices on the profitability of companies in the road transport sector. The case of the ABC transport company shows the relationship between the costs incurred for the purchase of fuel and the cost of transport activities. To test the theoretical assumptions, case study method was used.

A Lifecycle Emissions Model (LEM): Lifecycle Emissions from Transportation Fuels, Motor Vehicles, Transportation Modes, Electricity Use, Heating and Cooking Fuels, and Materials, APPENDIX A: Energy Use and Emissions from the Lifecycle of Diesel-Like Fuels Derived From Biomass

OpenAIRE

Delucchi, Mark; Lipman, Timothy

2003-01-01

An Appendix to the Report, “A Lifecycle Emissions Model (LEM): Lifecycle Emissions From Transportation Fuels, Motor Vehicles, Transportation Modes, Electricity Use, Heating and Cooking Fuels, and Materialsâ€

Development and use of GREET 1.6 fuel-cycle model for transportation fuels and vehicle technologies

International Nuclear Information System (INIS)

Wang, M. Q.

2001-01-01

Since 1995, with funds from the U.S. Department of Energy's (DOE's) Office of Transportation Technologies (OTT), Argonne National Laboratory has been developing the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model. The model is intended to serve as an analytical tool for use by researchers and practitioners in estimating fuel-cycle energy use and emissions associated with alternative transportation fuels and advanced vehicle technologies. Argonne released the first version of the GREET mode--GREET 1.0--in June 1996. Since then, it has released a series of GREET versions with revisions, updates, and upgrades. In February 2000, the latest public version of the model--GREET 1.5a--was posted on Argonne's Transportation Technology Research and Development Center (TTRDC) Web site (www.transportation.anl.gov/ttrdc/greet)

Integrated Radiation Transport and Nuclear Fuel Performance for Assembly-Level Simulations

Energy Technology Data Exchange (ETDEWEB)

Clarno, Kevin T [ORNL; Hamilton, Steven P [ORNL; Philip, Bobby [ORNL; Berrill, Mark A [ORNL; Sampath, Rahul S [ORNL; Allu, Srikanth [ORNL; Pugmire, Dave [ORNL; Dilts, Gary [Los Alamos National Laboratory (LANL); Banfield, James E [ORNL

2012-02-01

The Advanced Multi-Physics (AMP) Nuclear Fuel Performance code (AMPFuel) is focused on predicting the temperature and strain within a nuclear fuel assembly to evaluate the performance and safety of existing and advanced nuclear fuel bundles within existing and advanced nuclear reactors. AMPFuel was extended to include an integrated nuclear fuel assembly capability for (one-way) coupled radiation transport and nuclear fuel assembly thermo-mechanics. This capability is the initial step toward incorporating an improved predictive nuclear fuel assembly modeling capability to accurately account for source-terms and boundary conditions of traditional (single-pin) nuclear fuel performance simulation, such as the neutron flux distribution, coolant conditions, and assembly mechanical stresses. A novel scheme is introduced for transferring the power distribution from the Scale/Denovo (Denovo) radiation transport code (structured, Cartesian mesh with smeared materials within each cell) to AMPFuel (unstructured, hexagonal mesh with a single material within each cell), allowing the use of a relatively coarse spatial mesh (10 million elements) for the radiation transport and a fine spatial mesh (3.3 billion elements) for thermo-mechanics with very little loss of accuracy. In addition, a new nuclear fuel-specific preconditioner was developed to account for the high aspect ratio of each fuel pin (12 feet axially, but 1 4 inches in diameter) with many individual fuel regions (pellets). With this novel capability, AMPFuel was used to model an entire 17 17 pressurized water reactor fuel assembly with many of the features resolved in three dimensions (for thermo-mechanics and/or neutronics), including the fuel, gap, and cladding of each of the 264 fuel pins; the 25 guide tubes; the top and bottom structural regions; and the upper and lower (neutron) reflector regions. The final, full assembly calculation was executed on Jaguar using 40,000 cores in under 10 hours to model over 162

Notification determining technical details concerning measures for transportation of nuclear fuel materials

International Nuclear Information System (INIS)

1977-01-01

These provisions are established on the basis of and to enforce ''The regulation for installation and operation of reactor'', ''The regulation concerning the fabricating business of nuclear fuel'' and ''The regulations concerning the reprocessing business of spent fuel''. The terms used hereinafter are according to those used in such regulations. The limit of radioactivity concentration of things contaminated by the nuclear fuel materials which are not required to be enclosed in vessels is defined in the lists attached. In the applications for the approval of the measures concerning the transport of things remarkably difficult to be enclosed in vessels, the name and the address of the applicant, the kind, quantity, form and constitution of the thing contaminated by the nuclear fuel materials to be transported, the date and route of the transport and the measures for the prevention of injuries during the transport must be written. The limit of quantity of nuclear fuel materials classifying the performance of vessels is defined respectively in the lists attached. The radiation dose rates provided for by the Director General of the Science and Technology Agency concerning transported things and transporting apparatuses are 200 millirem per hour on the surfaces of such things and containers. The nuclear fission materials specified, for which the measures for the prevention of criticality are especially required, include uranium 233, uranium 235, plutonium 238, plutonium 239, plutonium 241, and the chemical compounds of such substances, and the nuclear fuel materials containing one or two and more of such substances, excluding the nuclear fuel materials with less than 15 grams of such uranium and plutonium. (Okada, K.)

Transportation impact analysis for shipment of irradiated N-reactor fuel and associated materials

International Nuclear Information System (INIS)

Daling, P.M.; Harris, M.S.

1994-12-01

An analysis of the radiological and nonradiological impacts of highway transportation of N-Reactor irradiated fuel (N-fuel) and associated materials is described in this report. N-fuel is proposed to be transported from its present locations in the 105-KE and 105-KW Basins, and possibly the PUREX Facility, to the 327 Building for characterization and testing. Each of these facilities is located on the Hanford Site, which is near Richland, Washington. The projected annual shipping quantity is 500 kgU/yr for 5 years for a total of 2500 kgU. It was assumed the irradiated fuel would be returned to the K- Basins following characterization, so the total amount of fuel shipped was assumed to be 5000 kgU. The shipping campaign may also include the transport and characterization of liquids, gases, and sludges from the storage basins, including fuel assembly and/or canister parts that may also be present in the basins. The impacts of transporting these other materials are bounded by the impacts of transporting 5000 kgU of N-fuel. This report was prepared to support an environmental assessment of the N-fuel characterization program. The RADTRAN 4 and GENII computer codes were used to evaluate the radiological impacts of the proposed shipping campaign. RADTRAN 4 was used to calculate the routine exposures and accident risks to workers and the general public from the N-fuel shipments. The GENII computer code was used to calculate the consequences of the maximum credible accident. The results indicate that the transportation of N-fuel in support of the characterization program should not cause excess radiological-induced latent cancer fatalities or traffic-related nonradiological accident fatalities. The consequences of the maximum credible accident are projected to be small and result in no excess latent cancer fatalities

Usage Inspection of KN-12 Spent Fuel Transport Cask

Energy Technology Data Exchange (ETDEWEB)

Lee, J. C.; Seo, K. S.; Bang, K. S.; Cho, I. J.; Kim, D. H.; Min, D. K

2007-03-15

The usage inspection of the KN-12 spent nuclear fuel transport package was performed to receive the license for reuse. According to the Korea Atomic Energy Act, all type B transport package should receive and pass the usage inspection every five years. The KN-12 transport cask was designed to transport twelve spent PWR fuel assemblies under wet and dry conditions. The cask was developed and licensed in 2002 in accordance with the Korea and the IAEA's safe transport regulations. The areas of usage inspection include: visual inspection, nondestructive weld inspection, load test, maximum operating pressure test, leakage test, shielding test, thermal test, external surface contamination test. In the results of the usage inspection, the damage or defect could not found out and the performance of the cask was maintained according to the requirements of the regulation. Therefore, the usage inspection was successfully performed to acquire the license for the reuse.

Probabilistic Risk Assessment on Maritime Spent Nuclear Fuel Transportation

Energy Technology Data Exchange (ETDEWEB)

Christian, Robby; Kang, Hyun Gook [KAIST, Daejeon (Korea, Republic of)

2016-05-15

Spent nuclear fuel (SNF) management has been an indispensable issue in South Korea. Before a long term SNF solution is implemented, there exists the need to distribute the spent fuel pool storage loads. Transportation of SNF assemblies from populated pools to vacant ones may preferably be done through the maritime mode since all nuclear power plants in South Korea are located at coastal sites. To determine its feasibility, it is necessary to assess risks of the maritime SNF transportation. This work proposes a methodology to assess the risk arising from ship collisions during the transportation of SNF by sea. Its scope is limited to the damage probability of SNF packages given a collision event. The effect of transport parameters' variation to the package damage probability was investigated to obtain insights into possible ways to minimize risks. A reference vessel and transport cask are given in a case study to illustrate the methodology's application.

Performance and Exhaust Emissions in a Natural-Gas Fueled Dual-Fuel Engine

Science.gov (United States)

Shioji, Masahiro; Ishiyama, Takuji; Ikegami, Makoto; Mitani, Shinichi; Shibata, Hiroaki

In order to establish the optimum fueling in a natural gas fueled dual fuel engine, experiments were done for some operational parameters on the engine performances and the exhaust emissions. The results show that the pilot fuel quantity should be increased and its injection timing should be advanced to suppress unburned hydrocarbon emission in the middle and low output range, while the quantity should be reduced and the timing retarded to avoid onset of knock at high loads. Unburned hydrocarbon emission and thermal efficiency are improved by avoiding too lean natural gas mixture by restricting intake charge air. However, the improvement is limited because the ignition of pilot fuel deteriorates with excessive throttling. It is concluded that an adequate combination of throttle control and equivalence ratio ensures low hydrocarbon emission and the thermal efficiency comparable to diesel operation.

Ethanol as a Fuel for Road Transportation

Energy Technology Data Exchange (ETDEWEB)

Larsen, U.; Johansen, T.; Schramm, J.

2009-05-15

Bioethanol as a motor fuel in the transportation sector, mainly for road transportation, has been subject to many studies and much discussion. Furthermore, the topic involves not only the application and engine technical aspects, but also the understanding of the entire life cycle of the fuel, well-to-wheels, including economical, environmental, and social aspects. It is not, however, the aim of this report to assess every single one of these aspects. The present report aims to address the technical potential and problems as well as the central issues related to the general application of bioethanol as an energy carrier in the near future. A suitable place to start studying a fuel is at the production stage, and bioethanol has been found to have a potential to mitigate greenhouse gases, depending on the production method. This and a potential for replacing fossil fuel-based oil (and being renewable) are the main reasons why ethanol is considered and implemented. Therefore, we must focus on two central questions related to ethanol implementation: how much carbon dioxide (CO2) can be mitigated and how much fossil fuel can be replaced? A number of life cycle assessments have been performed in order to provide estimates. These assessments have generally shown that bioethanol has very good potential and can mitigate CO2 emissions very effectively, but It has also been shown that the potential for both fossil fuel replacement and CO2 mitigation is totally dependent on the method used to produce the fuel. Bioethanol can be made from a wide range of biomass resources, not all equally effective at mitigating CO2 emissions and replacing fossil fuel. The Brazilian ethanol experience has in many ways shown the way for the rest of the world, not least in the production stage. Brazil was the first and biggest producer of bioethanol, but the United States, China, India, and European Union have since then increased their production dramatically. Overall, bioethanol represents the

Spent fuel transportation regulatory and institutional issues

International Nuclear Information System (INIS)

Lippek, H.E.

1978-01-01

The problems that could result from state and local governments and other groups with relation to regulations concerning the transportation of spent nuclear fuels are discussed. The powers of the individual states as spelled out in the Clean Air Act Amendments of 1977 are set forth in some detail. The possibility of transportation employees gaining a position to demand and receive more stringent protections from hazards of radiation is pointed out

Assessment of health risks brought about by transportation of spent fuel

International Nuclear Information System (INIS)

Suolanen, V.; Lautkaski, R.; Rossi, J.

1999-03-01

In the study health risks caused by transportation of spent fuel from Olkiluoto and from Loviisa NPP's to the planned disposal site have been evaluated. The Olkiluoto NPP is owned by Teollisuuden Voima Oy (TVO) and the Loviisa NPP, situated at Haestholmen, by Fortum Power and Heat Oy. According to the base scenario of 40 years use of the current NPP's the total amount of spent fuel will be 1840 tU (TVO) and 860 tU (Fortum). Annually, 110 tU on the average and at most 250 tU will be transported to the disposal site. The considered transportation routes are from Olkiluoto to Haestholmen, from Olkiluoto to Kivetty, from Olkiluoto to Romuvaara, from Haestholmen to Olkiluoto, from Haestholmen to Kivetty and from Haestholmen to Romuvaara. The considered transportation modes are truck, rail or ship, or combinations of these modes. Each transportation route has been divided into homogenised sequences with respect to population density and/or route type. Total amount of analysed route options were 40, some route sequences are overlapping. Radiation exposures to the population along the routes have been calculated in normal, incident and accident situations during transportation. Occupational radiation doses to the personnel have been estimated for normal transportation only. The consequences of normal transportation have been evaluated based on RADTRAN-model, developed by the Sandia National Laboratories. As incidents, stopping of spent fuel transportation for an exceptionally long period of time, and in another case contamination of outer surface of spent fuel cask have been considered. Expected collective doses and health risks of transportation accidents connected to the routes have been calculated with RADTRAN-model. Single hypothetical transport accidents with pessimistic release assumptions have been further analysed in more detail with the ARANO-model, developed by VTT (Technical Research Centre of Finland). (orig.)

Transport of Spent Nuclear Fuels, High and Intermediate Level Wastes: A Continuous Challenge

International Nuclear Information System (INIS)

Otton, C.; Blachet, L.

2009-01-01

For more than 45 years TN International has been involved in the radioactive materials transportation field. Since the beginning the used nuclear fuel transportation has been its core business. During all these years TN International, now part of AREVA, has been able to anticipate and fulfil the needs for new transport or storage casks design to fit the nuclear industry evolutions. A whole fleet of casks able to transport all the materials of the nuclear fuel cycle has been developed. In this presentation we will focus on the casks for the spent fuel, high level waste and intermediate level waste transportation. Answering to the constant evolution of the nuclear industry transport needs is a challenge that TN International faces routinely. Concerning the spent nuclear fuel transportation, TN International has developed in the early 80's a fleet of TN12 type casks fitted with several types of baskets able to safely transport all the spent fuel from the nuclear power plant or the research laboratories to AREVA La Hague plant. The current challenge is the design of a new transport cask generation taking into account the needs of the industry for the next 30 years. The replacement of the TN12 cask generation is to be scheduled as the regulations have changed and the fuel characteristics have evolved. The new generation of casks will take into account all the technical evolutions made during the TN12 thirty years of use. MOX spent fuel has now its dedicated cask: the TN112 which certificate of approval has been obtained in July 2008. This cask is able to transport 12 MOX spent fuel elements with a short cooling time. The first loading of the cask has been performed in 2008 in the EDF nuclear power plant of Saint-Laurent-des-Eaux. Concerning the high level waste such as the La Hague vitrified residues a whole fleet of casks has been developed such as the TN 28 VT dedicated to transport, the TN81 and TN85 dedicated to transport and storage. These casks have permitted the

Overview of fuel conversion

International Nuclear Information System (INIS)

Green, A.E.S.

1991-01-01

The conversion of solid fuels to cleaner-burning and more user-friendly solid liquid or gaseous fuels spans many technologies. In this paper, the authors consider coal, residual oil, oil shale, tar sends tires, municipal oil waste and biomass as feedstocks and examine the processes which can be used in the production of synthetic fuels for the transportation sector. The products of mechanical processing to potentially usable fuels include coal slurries, micronized coal, solvent refined coal, vegetable oil and powdered biomall. The thermochemical and biochemical processes considered include high temperature carbide production, liquefaction, gasification, pyrolysis, hydrolysis-fermentation and anaerobic digestion. The products include syngas, synthetic natural gas, methanol, ethanol and other hydrocarbon oxygenates synthetic gasoline and diesel and jet engine oils. The authors discuss technical and economic aspects of synthetic fuel production giving particular attention and literature references to technologies not discussed in the five chapters which follow. Finally the authors discuss economic energy, and environmental aspects of synthetic fuels and their relationship to the price of imported oil

Highly durable, coking and sulfur tolerant, fuel-flexible protonic ceramic fuel cells.

Science.gov (United States)

Duan, Chuancheng; Kee, Robert J; Zhu, Huayang; Karakaya, Canan; Chen, Yachao; Ricote, Sandrine; Jarry, Angelique; Crumlin, Ethan J; Hook, David; Braun, Robert; Sullivan, Neal P; O'Hayre, Ryan

2018-05-01

Protonic ceramic fuel cells, like their higher-temperature solid-oxide fuel cell counterparts, can directly use both hydrogen and hydrocarbon fuels to produce electricity at potentially more than 50 per cent efficiency 1,2 . Most previous direct-hydrocarbon fuel cell research has focused on solid-oxide fuel cells based on oxygen-ion-conducting electrolytes, but carbon deposition (coking) and sulfur poisoning typically occur when such fuel cells are directly operated on hydrocarbon- and/or sulfur-containing fuels, resulting in severe performance degradation over time 3-6 . Despite studies suggesting good performance and anti-coking resistance in hydrocarbon-fuelled protonic ceramic fuel cells 2,7,8 , there have been no systematic studies of long-term durability. Here we present results from long-term testing of protonic ceramic fuel cells using a total of 11 different fuels (hydrogen, methane, domestic natural gas (with and without hydrogen sulfide), propane, n-butane, i-butane, iso-octane, methanol, ethanol and ammonia) at temperatures between 500 and 600 degrees Celsius. Several cells have been tested for over 6,000 hours, and we demonstrate excellent performance and exceptional durability (less than 1.5 per cent degradation per 1,000 hours in most cases) across all fuels without any modifications in the cell composition or architecture. Large fluctuations in temperature are tolerated, and coking is not observed even after thousands of hours of continuous operation. Finally, sulfur, a notorious poison for both low-temperature and high-temperature fuel cells, does not seem to affect the performance of protonic ceramic fuel cells when supplied at levels consistent with commercial fuels. The fuel flexibility and long-term durability demonstrated by the protonic ceramic fuel cell devices highlight the promise of this technology and its potential for commercial application.