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Sample records for hybrid electronic platform

  1. Hybrid Photonic Integration on a Polymer Platform

    Directory of Open Access Journals (Sweden)

    Ziyang Zhang

    2015-09-01

    Full Text Available To fulfill the functionality demands from the fast developing optical networks, a hybrid integration approach allows for combining the advantages of various material platforms. We have established a polymer-based hybrid integration platform (polyboard, which provides flexible optical input/ouptut interfaces (I/Os that allow robust coupling of indium phosphide (InP-based active components, passive insertion of thin-film-based optical elements, and on-chip attachment of optical fibers. This work reviews the recent progress of our polyboard platform. On the fundamental level, multi-core waveguides and polymer/silicon nitride heterogeneous waveguides have been fabricated, broadening device design possibilities and enabling 3D photonic integration. Furthermore, 40-channel optical line terminals and compact, bi-directional optical network units have been developed as highly functional, low-cost devices for the wavelength division multiplexed passive optical network. On a larger scale, thermo-optic elements, thin-film elements and an InP gain chip have been integrated on the polyboard to realize a colorless, dual-polarization optical 90° hybrid as the frontend of a coherent receiver. For high-end applications, a wavelength tunable 100Gbaud transmitter module has been demonstrated, manifesting the joint contribution from the polyboard technology, high speed polymer electro-optic modulator, InP driver electronics and ceramic electronic interconnects.

  2. Quantum photonics hybrid integration platform

    CERN Document Server

    Murray, Eoin; Meany, Thomas; Flother, Frederick F; Lee, James P; Griffiths, Jonathan P; Jones, Geb A C; Farrer, Ian; Ritchie, David A; Bennet, Anthony J; Shields, Andrew J

    2015-01-01

    Fundamental to integrated photonic quantum computing is an on-chip method for routing and modulating quantum light emission. We demonstrate a hybrid integration platform consisting of arbitrarily designed waveguide circuits and single photon sources. InAs quantum dots (QD) embedded in GaAs are bonded to an SiON waveguide chip such that the QD emission is coupled to the waveguide mode. The waveguides are SiON core embedded in a SiO2 cladding. A tuneable Mach Zehnder modulates the emission between two output ports and can act as a path-encoded qubit preparation device. The single photon nature of the emission was veri?ed by an on-chip Hanbury Brown and Twiss measurement.

  3. Quantum photonics hybrid integration platform

    Energy Technology Data Exchange (ETDEWEB)

    Murray, E.; Floether, F. F. [Cambridge Research Laboratory, Toshiba Research Europe Limited, 208 Science Park, Milton Road, Cambridge CB4 0GZ (United Kingdom); Cavendish Laboratory, University of Cambridge, J.J. Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Ellis, D. J. P.; Meany, T.; Bennett, A. J., E-mail: anthony.bennet@crl.toshiba.co.uk; Shields, A. J. [Cambridge Research Laboratory, Toshiba Research Europe Limited, 208 Science Park, Milton Road, Cambridge CB4 0GZ (United Kingdom); Lee, J. P. [Cambridge Research Laboratory, Toshiba Research Europe Limited, 208 Science Park, Milton Road, Cambridge CB4 0GZ (United Kingdom); Engineering Department, University of Cambridge, 9 J. J. Thomson Avenue, Cambridge CB3 0FA (United Kingdom); Griffiths, J. P.; Jones, G. A. C.; Farrer, I.; Ritchie, D. A. [Cavendish Laboratory, University of Cambridge, J.J. Thomson Avenue, Cambridge CB3 0HE (United Kingdom)

    2015-10-26

    Fundamental to integrated photonic quantum computing is an on-chip method for routing and modulating quantum light emission. We demonstrate a hybrid integration platform consisting of arbitrarily designed waveguide circuits and single-photon sources. InAs quantum dots (QD) embedded in GaAs are bonded to a SiON waveguide chip such that the QD emission is coupled to the waveguide mode. The waveguides are SiON core embedded in a SiO{sub 2} cladding. A tuneable Mach Zehnder interferometer (MZI) modulates the emission between two output ports and can act as a path-encoded qubit preparation device. The single-photon nature of the emission was verified using the on-chip MZI as a beamsplitter in a Hanbury Brown and Twiss measurement.

  4. Paper based electronics platform

    KAUST Repository

    Nassar, Joanna Mohammad

    2017-07-20

    A flexible and non-functionalized low cost paper-based electronic system platform fabricated from common paper, such as paper based sensors, and methods of producing paper based sensors, and methods of sensing using the paper based sensors are provided. A method of producing a paper based sensor can include the steps of: a) providing a conventional paper product to serve as a substrate for the sensor or as an active material for the sensor or both, the paper product not further treated or functionalized; and b) applying a sensing element to the paper substrate, the sensing element selected from the group consisting of a conductive material, the conductive material providing contacts and interconnects, sensitive material film that exhibits sensitivity to pH levels, a compressible and/or porous material disposed between a pair of opposed conductive elements, or a combination of two of more said sensing elements. The method of sensing can further include measuring, using the sensing element, a change in resistance, a change in voltage, a change in current, a change in capacitance, or a combination of any two or more thereof.

  5. Hybrid printed electronics

    NARCIS (Netherlands)

    Koetse, M.; Smits, E.; Rubingh, E.; Teunissen, P.; Kusters, R.; Abbel, R.; Brand, J. van den

    2016-01-01

    Although many electronic functionalities can be realized by printed or organic electronics, short-term marketable products often require robust, reproducible, and nondisturbing technologies. In this chapter we show how hybrid electronics, a combination of printed circuitry, thin-film electronics,

  6. Hybrid Platforms, Tools, and Resources

    Science.gov (United States)

    Linder, Kathryn E.; Bruenjes, Linda S.; Smith, Sarah A.

    2017-01-01

    This chapter discusses common tools and resources for building a hybrid course in a higher education setting and provides recommendations for best practices in Learning Management Systems and Open Educational Resources.

  7. Hybrid Integrated Platforms for Silicon Photonics

    Directory of Open Access Journals (Sweden)

    John E. Bowers

    2010-03-01

    Full Text Available A review of recent progress in hybrid integrated platforms for silicon photonics is presented. Integration of III-V semiconductors onto silicon-on-insulator substrates based on two different bonding techniques is compared, one comprising only inorganic materials, the other technique using an organic bonding agent. Issues such as bonding process and mechanism, bonding strength, uniformity, wafer surface requirement, and stress distribution are studied in detail. The application in silicon photonics to realize high-performance active and passive photonic devices on low-cost silicon wafers is discussed. Hybrid integration is believed to be a promising technology in a variety of applications of silicon photonics.

  8. DOE Hybrid and Electric Vehicle Test Platform

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Yimin [Advanced Vehicle Research Center, Danville, VA (United States)

    2012-03-31

    Based on the contract NT-42790 to the Department of Energy, “Plug-in Hybrid Ethanol Research Platform”, Advanced Vehicle Research Center (AVRC) Virginia has successfully developed the phase I electric drive train research platform which has been named as Laboratory Rapid Application Testbed (LabRAT). In phase II, LabRAT is to be upgraded into plug-in hybrid research platform, which will be capable of testing power systems for electric vehicles, and plug-in hybrid electric vehicles running on conventional as well as alternative fuels. LabRAT is configured as a rolling testbed with plentiful space for installing various component configurations. Component connections are modularized for flexibility and are easily replaced for testing various mechanisms. LabRAT is designed and built as a full functional vehicle chassis with a steering system, brake system and four wheel suspension. The rear drive axle offers maximum flexibility with a quickly changeable gear ratio final drive to accommodate different motor speed requirements. The electric drive system includes an electric motor which is mechanically connected to the rear axle through an integrated speed/torque sensor. Initially, a 100 kW UQM motor and corresponding UQM motor controller is used which can be easily replaced with another motor/controller combination. A lithium iron phosphate (LiFePO4) battery pack is installed, which consists of 108 cells of 100 AH capacity, giving the total energy capacity of 32.5 kWh. Correspondingly, a fully functional battery management system (BMS) is installed to perform battery cell operation monitoring, cell voltage balancing, and reporting battery real time operating parameters to vehicle controller. An advanced vehicle controller ECU is installed for controlling the drive train. The vehicle controller ECU receives traction or braking torque command from driver through accelerator and brake pedal position sensors and battery operating signals from the BMS through CAN BUS

  9. Multipurpose Platform for Electronic Currency System

    Directory of Open Access Journals (Sweden)

    Andreea Magdalena Dae

    2014-12-01

    Full Text Available Nowadays, there are multiple solutions for exchanging electronic currencies which will most probably replace physical money. This paper presents a platform for electronic currency system implemented within a Java smart card for accessing different types of products or services. The user interacts with an “electronic currency bank” and with a merchant through a secure protocol.

  10. Design & Evaluation of an Accessible Hybrid Violin Platform

    DEFF Research Database (Denmark)

    Overholt, Daniel; Gelineck, Steven

    2014-01-01

    platform accessibility for players and other researchers is approached via a simple ‘do-it-yourself’ design described herein. All hardware and software elements are open- source, and the build process requires minimal electronics skills. Cost has also been kept to a minimum where possible. Our initial...... prototype is based upon a relatively inexpensive electric violin that is widely available online. This instrument serves as the starting point for construction, to which our design adds Digital Signal Processing (DSP), gestural sensing, and local sound output. Real-time DSP algorithms run on a mobile device......We introduce and describe the initial evaluation of a new accessible (easily replicable) augmented violin prototype. Our research is focused on the user experience when playing such hybrid physical- digital instruments, and exploration of novel interactive performance techniques. The goal of wider...

  11. Electronics Platform of PS Linac 1 Preinjector

    CERN Multimedia

    1974-01-01

    For servicing during shutdowns, a draw-bridge from a door in the Faraday cage led to the "electronics platform" of the linac 1 preinjector (at 520 kV when in operation) and the top of the electronics platform was lifted on hydraulic jacks for easy access. Henry Charmot is busy with a service. The platform contained the electronics for the ion source, controlled from outside the Faraday cage via an infrared optical link. The ion source, also at 520 kV potential, is housed in the drum, visible in the background, on the insulator column, which at its right end is mounted at ground potential. Behind the wall, to the right, is the 50 MeV linac 1. See also 7403064X, 7403066X, 7403124.

  12. Comparison of Hybrid Cross-Platform Mobile Applications with Native Cross-Platform Applications

    Directory of Open Access Journals (Sweden)

    NOVAC Ovidiu Constantin

    2016-10-01

    Full Text Available In this paper we present two types of cross platform mobile applications, we will look at the advantages and disadvantages of each one. Hybrid applications are HTML5/Javascript applications which are given a native device wrapper in order to be able to run as a stand-alone application, rather than a web page which has to be rendered in the web browser. These types of application look the same on each platform they are deployed to. Native cross platform applications offers platform-like styling, making almost impossible to tell the difference between a native and a cross platform application.

  13. Mixed protonic and electronic conductors hybrid oxide synaptic transistors

    Science.gov (United States)

    Fu, Yang Ming; Zhu, Li Qiang; Wen, Juan; Xiao, Hui; Liu, Rui

    2017-05-01

    Mixed ionic and electronic conductor hybrid devices have attracted widespread attention in the field of brain-inspired neuromorphic systems. Here, mixed protonic and electronic conductor (MPEC) hybrid indium-tungsten-oxide (IWO) synaptic transistors gated by nanogranular phosphorosilicate glass (PSG) based electrolytes were obtained. Unique field-configurable proton self-modulation behaviors were observed on the MPEC hybrid transistor with extremely strong interfacial electric-double-layer effects. Temporally coupled synaptic plasticities were demonstrated on the MPEC hybrid IWO synaptic transistor, including depolarization/hyperpolarization, synaptic facilitation and depression, facilitation-stead/depression-stead behaviors, spiking rate dependent plasticity, and high-pass/low-pass synaptic filtering behaviors. MPEC hybrid synaptic transistors may find potential applications in neuron-inspired platforms.

  14. Development of an Electrochemical-Cantilever Hybrid Platform

    DEFF Research Database (Denmark)

    Fischer, Lee MacKenzie

    I denne afhandling er udviklingen af en nyskabende elektrokemisk-cantilever hybrid sensor platform præsenteret. Mikro cantileverer er meget følsomme over for ændringer i overflade stress, mens elektrokemiske metoder tillader kontrol og udlæsning af overflade ladning og potentiale. Det kan bruges...

  15. A hybrid silicon-PDMS optofluidic platform for sensing applications

    NARCIS (Netherlands)

    Testa, G.; Persichetti, G.; Sarro, P.M.; Bernini, R.

    2014-01-01

    A hybrid silicon-poly(dimethysiloxane) (PDMS) optofluidic platform for lab-on-a-chip applications is proposed. A liquid-core waveguide with a self-aligned solid-core waveguide and a microfluidic device are integrated with a multilayer approach, resulting in a three-dimensional device assembly. The

  16. Fiat designs a platform suitable for gasoline, electric or hybrid

    Energy Technology Data Exchange (ETDEWEB)

    Cappelli, P.G.; Bonino, M. [Fiat Auto SpA, Turin (Italy)

    1995-12-31

    With the debate between purpose-built and existing designs, Fiat is working on a strategy to use a common platform for its new generation models which will allow economic concurrent design and development of a small car range featuring thermal, electric and hybrid versions. (Author)

  17. Hybrid Theranostic Platforms for Cancer Nanomedical Treatment

    KAUST Repository

    Julfakyan, Khachatur

    2015-10-01

    Cancer is a leading case of mortality worldwide. Governments spent multibillion expenses on treatment and palliative care of diseased people. Despite these generous funding and intensive research with aim to find a cure or efficient treatment for cancer, until now there is a lack in selective cancer management strategies. Conventional treatment strategies for cancer, such as surgery, cytotoxic chemotherapy, radiation therapy, hormone therapy don’t have selectivity toward cancer – the property of discrimination of healthy organs and tissues from the diseased site. Chemotherapy is very challenging as the difference between effective and lethal doses is very minuscule in most cases. Moreover, devastating side effects dramatically changes the quality of life for cancer patients. To address these issues two main strategies are intensively utilized in chemistry: (I) the design and synthesis of novel anticancer organic compounds with higher selectivity and low toxicity profiles and the second, design and preparation of biocompatible nanocarriers for imaging and anticancer compound selective delivery nanomedicine. The following dissertation combines the above two strategies as bellows: First project is related to the design and synthetic route development toward novel nature-inspired group of heterocyclic compounds – iso-Phidianidines. The second project focused on design, preparation and evaluation of hybrid theranostics (therapeutic and diagnostic in a single entity). Chapter 1 is a general background review of the major topics that will be discussed in this dissertation. The first efficient and high-yielding synthetic route toward iso-phidianidines, containing regioisomeric form of 1,2,4-oxadiazole linked to the indole via methylene bridge is reported in Chapter 2. In vitro test of the synthesized library of iso-phidianidines revealed micromolar range of cytotoxicity toward human cervical cancer cell line. Structure activity relationship revealed the importance of

  18. Building a Hybrid Experimental Platform for Mobile Botnet Research

    Directory of Open Access Journals (Sweden)

    Apostolos Malatras

    2016-03-01

    Full Text Available Mobile botnets are an emerging security threat that aims at exploiting the wide penetration of mobile devices and systems and their vulnerabilities in the same spirit of traditional botnets. Mobile botmasters take advantage of infected mobile devices and issue command and control operations on them to extract personal information, cause denial of service or gain financially. To date, research on countering such attacks or studying their effects has been conducted in a sporadic manner that hinders the repetition of experiments and thus limits their validity. We present here our work on a hybrid experimental platform for mobile botnets that supports the execution and monitoring of related scenarios concerning their infection, attack vectors, propagation, etc. The platform is based on principles of flexibility, extensibility and facilitates the setup of scalable experiments utilising both real and emulated mobile systems. We also discuss a novel method of estimating the active bot population in a botnet and illustrate its deployment on the experimental platform.

  19. Photonic Integration on the Hybrid Silicon Evanescent Device Platform

    Directory of Open Access Journals (Sweden)

    Hyundai Park

    2008-01-01

    Full Text Available This paper reviews the recent progress of hybrid silicon evanescent devices. The hybrid silicon evanescent device structure consists of III-V epitaxial layers transferred to silicon waveguides through a low-temperature wafer bonding process to achieve optical gain, absorption, and modulation efficiently on a silicon photonics platform. The low-temperature wafer bonding process enables fusion of two different material systems without degradation of material quality and is scalable to wafer-level bonding. Lasers, amplifiers, photodetectors, and modulators have been demonstrated with this hybrid structure and integration of these individual components for improved optical functionality is also presented. This approach provides a unique way to build photonic active devices on silicon and should allow application of silicon photonic integrated circuits to optical telecommunication and optical interconnects.

  20. Hybrid Analysis Approach for Stochastic Response of Offshore Jacket Platforms

    Institute of Scientific and Technical Information of China (English)

    金伟良; 郑忠双; 李海波; 张立

    2000-01-01

    The dynamic response of offshore platforms is more serious in hostile sea environment than in shallow sea. In this paper, a hybrid solution combined with analytical and numerical method is proposed to compute the stochastic response of fixed offshore platforms to random waves, considering wave-structure interaction and non-linear drag force. The simulation program includes two steps: the first step is the eigenanalysis aspects associated the structure and the second step is response estimation based on spectral equations. The eigenanalysis could be done through conventional finite element method conveniently and its natural frequency and mode shapes obtained. In the second part of the process, the solution of the offshore structural response is obtained by iteration of a series of coupled spectral equations. Considering the third-order term in the drag force, the evaluation of the three-fold convolution should be demanded for nonlinear stochastic response analysis. To demonstrate this method, a numerical analysis is carried out for both linear and non-linear platform motions. The final response spectra have the typical two peaks in agreement with reality, indicating that the hybrid method is effective and can be applied to offshore engineering.

  1. An electrochemical-cantilever platform for hybrid sensing applications

    DEFF Research Database (Denmark)

    Fischer, Lee MacKenzie; Dohn, Søren; Boisen, Anja

    2011-01-01

    This work presents a fully-functional, microfabricated electrochemical-cantilever hybrid platform with flow control. A new cantilever chip format is designed, fabricated, and mounted in a custom polymer flow cell. Issues such as leakage and optical/electrical access are addressed, and combined me...... mechanical and electrochemical performance is investigated. Lastly, a cantilever is “defunctionalized” in situ to create a reference cantilever for differential measurements in detection of Cu2+ ions at concentrations of 10 μM and 100 nM....

  2. Islamic electronic trading platform on organized exchange

    Directory of Open Access Journals (Sweden)

    Ahmet Suayb Gundogdu

    2016-12-01

    Full Text Available Today Islamic finance industry is under severe criticism, particularly, concerning liquidity management practices of treasury departments. Since cash lending is not possible under Islamic Shari'ah, Islamic banks tend to use securitized asset related schemes which are by no means neither acceptable under Islamic finance jurisprudence nor compliant with Maqasiq Al-Shari'ah. Maqasid Al-Shariah oversees economic activities which produce wealth and prosperity for all members of society to empower any member with certain level of belongings to bestow freedom while condemning inequality. Under this wider aim of Maqasid Al-Shari'ah, this paper presents alternative state-of-art Shari'ah compliant products, which is used in international trade finance, to be migrated to electronic trading platform under organized exchange in pursuit of replacing controversial liquidity management products. Besides, this paper introduces Islamic Commodity Future Contract, derived from asset backed Murabaha, with physical delivery as an alternative liquidity management tool for Islamic FIs and hedging tool for companies.

  3. NextFlex Flexible Hybrid Electronics Manufacturing

    Science.gov (United States)

    2016-10-01

    and innovators, along with a robust U.S. network of manufacturing nodes, to advance a national flexible hybrid electronics (FHE) manufacturing...methods to scale up today’s FHE laboratory experiments into smart , affordable products. FHE manufacturing en- compasses innovative electronic...The software design tools will encompass multiphysics simulation (e.g., electrical , thermal, mechanical, etc., interactions based on first principles

  4. Wireless Hybrid Identification and Sensing Platform for Equipment Recovery (WHISPER) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Advanced Systems & Technologies proposed WHISPER (Wireless Hybrid Identification and Sensing Platform for Equipment Recovery) solution to NASA's need for...

  5. Introducing Blackboard: an electronic learning platform.

    Science.gov (United States)

    Cader, Raffik; McGovern, Michael

    Blackboard, an internet-based platform for teaching and learning, was introduced to students on the preregistration nursing programme at Northumbria University. Although clear educational advantages were identified, there were also potential pitfalls.

  6. Hybrid Exploration Agent Platform and Sensor Web System

    Science.gov (United States)

    Stoffel, A. William; VanSteenberg, Michael E.

    2004-01-01

    A sensor web to collect the scientific data needed to further exploration is a major and efficient asset to any exploration effort. This is true not only for lunar and planetary environments, but also for interplanetary and liquid environments. Such a system would also have myriad direct commercial spin-off applications. The Hybrid Exploration Agent Platform and Sensor Web or HEAP-SW like the ANTS concept is a Sensor Web concept. The HEAP-SW is conceptually and practically a very different system. HEAP-SW is applicable to any environment and a huge range of exploration tasks. It is a very robust, low cost, high return, solution to a complex problem. All of the technology for initial development and implementation is currently available. The HEAP Sensor Web or HEAP-SW consists of three major parts, The Hybrid Exploration Agent Platforms or HEAP, the Sensor Web or SW and the immobile Data collection and Uplink units or DU. The HEAP-SW as a whole will refer to any group of mobile agents or robots where each robot is a mobile data collection unit that spends most of its time acting in concert with all other robots, DUs in the web, and the HEAP-SWs overall Command and Control (CC) system. Each DU and robot is, however, capable of acting independently. The three parts of the HEAP-SW system are discussed in this paper. The Goals of the HEAP-SW system are: 1) To maximize the amount of exploration enhancing science data collected; 2) To minimize data loss due to system malfunctions; 3) To minimize or, possibly, eliminate the risk of total system failure; 4) To minimize the size, weight, and power requirements of each HEAP robot; 5) To minimize HEAP-SW system costs. The rest of this paper discusses how these goals are attained.

  7. Accelerated Aging Platform for Prognostics of Power Electronics

    Data.gov (United States)

    National Aeronautics and Space Administration — To advance the field of electronics prognostics, the study of transistor fault modes and their precursors is essential. This paper reports on a platform for the...

  8. Low-cost bioanalysis on paper-based and its hybrid microfluidic platforms.

    Science.gov (United States)

    Dou, Maowei; Sanjay, Sharma Timilsina; Benhabib, Merwan; Xu, Feng; Li, XiuJun

    2015-12-01

    Low-cost assays have broad applications ranging from human health diagnostics and food safety inspection to environmental analysis. Hence, low-cost assays are especially attractive for rural areas and developing countries, where financial resources are limited. Recently, paper-based microfluidic devices have emerged as a low-cost platform which greatly accelerates the point of care (POC) analysis in low-resource settings. This paper reviews recent advances of low-cost bioanalysis on paper-based microfluidic platforms, including fully paper-based and paper hybrid microfluidic platforms. In this review paper, we first summarized the fabrication techniques of fully paper-based microfluidic platforms, followed with their applications in human health diagnostics and food safety analysis. Then we highlighted paper hybrid microfluidic platforms and their applications, because hybrid platforms could draw benefits from multiple device substrates. Finally, we discussed the current limitations and perspective trends of paper-based microfluidic platforms for low-cost assays.

  9. Porous-Hybrid Polymers as Platforms for Heterogeneous Photochemical Catalysis

    KAUST Repository

    Haikal, Rana R.

    2016-07-18

    A number of permanently porous polymers containing Ru(bpy)n photosensitizer or a cobaloxime complex, as a proton-reduction catalyst, were constructed via one-pot Sonogashira-Hagihara (SH) cross-coupling reactions. This process required minimal workup to access porous platforms with control over the apparent surface area, pore volume, and chemical functionality from suitable molecular building blocks (MBBs) containing the Ru or Co complexes, as rigid and multi-topic nodes. The cobaloxime molecular building block, generated through in situ metalation, afforded a microporous solid that demonstrated noticeable catalytic activity towards hydrogen-evolution reaction (HER) with remarkable recyclability. We further demonstrated, in two cases, the ability to affect the excited state lifetime of the covalently-immobilized Ru(bpy)3 complex attained through deliberate utilization of the organic linkers of variable dimensions. Overall, this approach facilitates construction of tunable porous solids, with hybrid composition and pronounced chemical and physical stability, based on the well-known Ru(bpy)nor the cobaloxime complexes.

  10. Space qualified nanosatellite electronics platform for photon pair experiments

    CERN Document Server

    Cheng, Cliff; Tan, Yue Chuan; Ling, Alexander

    2015-01-01

    We report the design and implementation of a complete electronics platform for conducting a quantum optics experiment that will be operated on board a 1U CubeSat (a 10 x 10 x 10 cm satellite). The quantum optics experiment is designed to produce polarization-entangled photon pairs using non-linear optical crystals and requires opto-electronic components such as a pump laser, single photon detectors and liquid crystal based polarization rotators in addition to passive optical elements. The platform provides mechanical support for the optical assembly. It also communicates autonomously with the host satellite to provide experiment data for transmission to a ground station. A limited number of commands can be transmitted from ground to the platform enabling it to switch experimental modes. This platform requires less than 1.5W for all operations, and is space qualified. The implementation of this electronics platform is a major step on the road to operating quantum communication experiments using nanosatellites.

  11. Triple Hybrid Energy Harvesting Interface Electronics

    Science.gov (United States)

    Uluşan, H.; Chamanian, S.; Pathirana, W. M. P. R.; Zorlu, Ö.; Muhtaroğlu, A.; Külah, H.

    2016-11-01

    This study presents a novel triple hybrid system that combines simultaneously generated power from thermoelectric (TE), vibration-based electromagnetic (EM) and piezoelectric (PZT) harvesters for a relatively high power supply capability. In the proposed solution each harvesting source utilizes a distinct power management circuit that generates a DC voltage suitable for combining the three parallel supplies. The circuits are designed and implemented in 180 nm standard CMOS technology, and are terminated with a schottky diode to avoid reverse current flow. The harvested AC signal from the EM harvester is rectified with a self-powered AC-DC doubler, which utilizes active diode structures to minimize the forward- bias voltage drop. The PZT interface electronics utilizes a negative voltage converter as the first stage, followed by synchronous power extraction and DC-to-DC conversion through internal switches, and an external inductor. The ultra-low voltage DC power harvested by the TE generator is stepped up through a charge-pump driven by an LC oscillator with fully- integrated center-tapped differential inductors. Test results indicate that hybrid energy harvesting circuit provides more than 1 V output for load resistances higher than 100 kΩ (10 μW) where the stand-alone harvesting circuits are not able to reach 1 V output. This is the first hybrid harvester circuit that simultaneously extracts energy from three independent sources, and delivers a single DC output.

  12. RFID-based Electronic Identity Security Cloud Platform in Cyberspace

    Directory of Open Access Journals (Sweden)

    Bing Chen

    2012-07-01

    Full Text Available With the moving development of networks, especially Internet of Things, electronic identity administration in cyberspace is becoming more and more important. And personal identity management in cyberspace associated with individuals in reality has been one significant and urgent task for the further development of information construction in China. So this paper presents a RFID-based electronic identity security cloud platform in cyberspace to implement an efficient security management of cyber personal identity, and designs and realizes a strong and pervasive security cloud service platform, and discusses key technology including security authentication mechanism for the electronic identity card, super high frequency RFID with eID cards, multilevel privacy protection mechanism, security cloud service, security isolation and single-oriented transmission, and boundary security gateway protection, and it can well apply to personal identity management with virtual roles of citizens in cyberspace such as E-Government and E-Business, and the electronic identity security platform has been primary implemented and achieved good effects in actual applications.

  13. Graphene-Plasmonic Hybrid Platform for Label-Free SERS Biomedical Detection

    Science.gov (United States)

    Wang, Pu

    Surface Enhanced Raman Scattering (SERS) has attracted explosive interest for the wealth of vibrational information it provides with minimal invasive effects to target analyte. Nanotechnology, especially in the form of noble metal nanoparticles exhibit unique electromagnetic and chemical characteristics that are explored to realize ultra-sensitive SERS detection in chemical and biological analysis. Graphene, atom-thick carbon monolayer, exhibits superior chemical stability and bio-compatibility. A combination of SERS-active metal nanostructures and graphene will create various synergies in SERS. The main objective of this research was to exploit the applications of the graphene-Au tip hybrid platform in SERS. The hybrid platform consists of a periodic Au nano-pyramid substrate to provide reproducible plasmonic enhancement, and the superimposed monolayer graphene sheet, serving as "built-in" Raman marker. Extensive theoretical and experimental studies were conducted to determine the potentials of the hybrid platform as SERS substrate. Results from both Finite-Domain Time-Domain (FDTD) numerical simulation and Raman scattering of graphene suggested that the hybrid platform boosted a high density of hotspots yielding 1000 times SERS enhancement of graphene bands. Ultra-high sensitivity of the hybrid platform was demonstrated by bio-molecules including dye, protein and neurotransmitters. Dopamine and serotonin can be detected and distinguished at 10-9 M concentration in the presence of human body fluid. Single molecule detection was obtained using a bi-analyte technique. Graphene supported a vibration mode dependent SERS chemical enhancement of ˜10 to the analyte. Quantitative evaluation of hotspots was presented using spatially resolved Raman mapping of graphene SERS enhancement. Graphene plays a crucial role in quantifying SERS hotspots and paves the path for defining SERS EF that could be universally applied to various SERS systems. A reproducible and statistically

  14. SECURED ELECTRONIC VOTING PROTOCOL USING HYBRID CRYPTOSYSTEM

    Directory of Open Access Journals (Sweden)

    KALAICHELVI V

    2013-04-01

    Full Text Available Electronic Voting play a really vital role in the democracy of our life. In this paper, we propose an electronic voting protocol. Our scheme does not require a special voting channel and communication can occur entirely over the current Internet. This method integrates the Internet convenience and cryptology. In the existing protocol the Tallier has to wait until the decryption key is received from the voter. So it will consume lot of time. But, the proposed protocol is based on the hybrid cryptosystem. In this, the ballot is encrypted using faster secret key algorithm and the digital envelope is encrypted using Tallier’s public key. So, the Tallier will decrypt the digital envelope using his own private key to get the secret key and then the encrypted ballot is decrypted using that secret key. So, comparatively the proposed protocol consumes less time. This paper also analyzes the various security issues involved in an electronic voting like security, privacy, authentication, anonymous, uniqueness, accuracy, fairness, efficiency and uncoercibility.

  15. Innovative Mobile Platform Developments for Electronic Services Design and Delivery

    DEFF Research Database (Denmark)

    Scupola, Ada

    In the ever-growing world of technology, it is becoming more important to understand the developments of new electronic services and mobile applications. Innovative Mobile Platform Developments for Electronic Services Design, and Delivery is a comprehensive look at all aspects of production...... management, delivery and consumption of e-services, self services, and mobile communication including business-to-business, business-to-consumer, government-to-business, government-to-consumer, and consumer-to-consumer e-services. This volume is perfect for the interest of professionals, academic educators...

  16. Universal logic gates via liquid-electronic hybrid divider

    KAUST Repository

    Zhou, Bingpu

    2012-01-01

    We demonstrated two-input microdroplet-based universal logic gates using a liquid-electronic hybrid divider. All 16 Boolean logic functions have been realized by manipulating the applied voltages. The novel platform consists of a microfluidic chip with integrated microdroplet detectors and external electronic components. The microdroplet detectors act as the communication media for fluidic and electronic information exchange. The presence or absence of microdroplets at the detector translates into the binary signal 1 or 0. The embedded micro-mechanical pneumatically actuated valve (PAV), fabricated using the well-developed multilayer soft lithography technique, offers biocompatibility, flexibility and accuracy for the on-chip realization of different logic functions. The microfluidic chip can be scaled up to construct large-scale microfluidic logic computation. On the other hand, the microfluidic chip with a specific logic function can be applied to droplet-based chemical reactions for on-demand bio or chemical analysis. Our experimental results have presented an autonomously driven, precision-controlled microfluidic chip for chemical reactions based on the IF logic function. © 2012 The Royal Society of Chemistry.

  17. Development of a surface plasmon resonance and nanomechanical biosensing hybrid platform for multiparametric reading

    Science.gov (United States)

    Alvarez, Mar; Fariña, David; Escuela, Alfonso M.; Sendra, Jose Ramón; Lechuga, Laura M.

    2013-01-01

    We have developed a hybrid platform that combines two well-known biosensing technologies based on quite different transducer principles: surface plasmon resonance and nanomechanical sensing. The new system allows the simultaneous and real-time detection of two independent parameters, refractive index change (Δn), and surface stress change (Δσ) when a biomolecular interaction takes place. Both parameters have a direct relation with the mass coverage of the sensor surface. The core of the platform is a common fluid cell, where the solution arrives to both sensor areas at the same time and under the same conditions (temperature, velocity, diffusion, etc.).The main objective of this integration is to achieve a better understanding of the physical behaviour of the transducers during sensing, increasing the information obtained in real time in one single experiment. The potential of the hybrid platform is demonstrated by the detection of DNA hybridization.

  18. Development of a surface plasmon resonance and nanomechanical biosensing hybrid platform for multiparametric reading.

    Science.gov (United States)

    Alvarez, Mar; Fariña, David; Escuela, Alfonso M; Sendra, Jose Ramón; Lechuga, Laura M

    2013-01-01

    We have developed a hybrid platform that combines two well-known biosensing technologies based on quite different transducer principles: surface plasmon resonance and nanomechanical sensing. The new system allows the simultaneous and real-time detection of two independent parameters, refractive index change (Δn), and surface stress change (Δσ) when a biomolecular interaction takes place. Both parameters have a direct relation with the mass coverage of the sensor surface. The core of the platform is a common fluid cell, where the solution arrives to both sensor areas at the same time and under the same conditions (temperature, velocity, diffusion, etc.).The main objective of this integration is to achieve a better understanding of the physical behaviour of the transducers during sensing, increasing the information obtained in real time in one single experiment. The potential of the hybrid platform is demonstrated by the detection of DNA hybridization.

  19. Printable Spacecraft: Flexible Electronic Platforms for NASA Missions. Phase One

    Science.gov (United States)

    Short, Kendra (Principal Investigator); Van Buren, David (Principal Investigator)

    2012-01-01

    Atmospheric confetti. Inchworm crawlers. Blankets of ground penetrating radar. These are some of the unique mission concepts which could be enabled by a printable spacecraft. Printed electronics technology offers enormous potential to transform the way NASA builds spacecraft. A printed spacecraft's low mass, volume and cost offer dramatic potential impacts to many missions. Network missions could increase from a few discrete measurements to tens of thousands of platforms improving areal density and system reliability. Printed platforms could be added to any prime mission as a low-cost, minimum resource secondary payload to augment the science return. For a small fraction of the mass and cost of a traditional lander, a Europa flagship mission might carry experimental printed surface platforms. An Enceladus Explorer could carry feather-light printed platforms to release into volcanic plumes to measure composition and impact energies. The ability to print circuits directly onto a variety of surfaces, opens the possibility of multi-functional structures and membranes such as "smart" solar sails and balloons. The inherent flexibility of a printed platform allows for in-situ re-configurability for aerodynamic control or mobility. Engineering telemetry of wheel/soil interactions are possible with a conformal printed sensor tape fit around a rover wheel. Environmental time history within a sample return canister could be recorded with a printed sensor array that fits flush to the interior of the canister. Phase One of the NIAC task entitled "Printable Spacecraft" investigated the viability of printed electronics technologies for creating multi-functional spacecraft platforms. Mission concepts and architectures that could be enhanced or enabled with this technology were explored. This final report captures the results and conclusions of the Phase One study. First, the report presents the approach taken in conducting the study and a mapping of results against the proposed

  20. Analyzing Dynamic Task-Based Applications on Hybrid Platforms: An Agile Scripting Approach

    OpenAIRE

    Garcia Pinto, Vinicius; Stanisic, Luka; Legrand, Arnaud; Mello Schnorr, Lucas; Thibault, Samuel; Danjean, Vincent

    2016-01-01

    In this paper, we present visual analysis techniques to evaluate the performance of HPC task-based applications on hybrid architectures. Our approach is based on composing modern data analysis tools (pjdump, R, ggplot2, plotly), enabling an agile and flexible scripting framework with minor development cost. We validate our proposal by analyzing traces from the full-fledged implementation of the Cholesky decomposition available in the MORSE library running on a hybrid (CPU/GPU) platform. The a...

  1. Magnetic Particle-Based Hybrid Platforms for Bioanalytical Sensors

    Directory of Open Access Journals (Sweden)

    Silvana Andreescu

    2009-04-01

    Full Text Available Biomagnetic nano and microparticles platforms have attracted considerable interest in the field of biological sensors due to their interesting physico-chemical properties, high specific surface area, good mechanical stability and opportunities for generating magneto-switchable devices. This review discusses recent advances in the development and characterization of active biomagnetic nanoassemblies, their interaction with biological molecules and their use in bioanalytical sensors.

  2. A novel detection platform for parallel monitoring of DNA hybridization with high sensitivity and specificity

    DEFF Research Database (Denmark)

    Yi, Sun; Perch-Nielsen, Ivan R.; Wang, Zhenyu;

    We developed a high-sensitive platform to monior multiple hybridization events in real time. By creating a microoptical array in a polymeric chip, the system combine the excellent discriminative power of supercritical angle fluorescence (SAF) microscopy with high-throughput capabilities...

  3. Integrated nanophotonic frequency shifter on the silicon-organic hybrid (SOH) platform for laser vibrometry

    Energy Technology Data Exchange (ETDEWEB)

    Lauermann, M.; Weimann, C.; Palmer, R.; Schindler, P. C. [Institute of Photonics and Quantum Electronics, Karlsruhe Institute of Technology, 76131 Karlsruhe (Germany); Koeber, S.; Freude, W., E-mail: christian.koos@kit.edu; Koos, C., E-mail: christian.koos@kit.edu [Institute of Photonics and Quantum Electronics, Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany and Institute of Microstructure Technology, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen (Germany); Rembe, C. [Polytec GmbH, 76337 Waldbronn (Germany)

    2014-05-27

    We demonstrate a waveguide-based frequency shifter on the silicon photonic platform, enabling frequency shifts up to 10 GHz. The device is realized by silicon-organic hybrid (SOH) integration. Temporal shaping of the drive signal allows the suppression of spurious side-modes by more than 23 dB.

  4. A hybrid approach to device integration on a genetic analysis platform

    Science.gov (United States)

    Brennan, Des; Jary, Dorothee; Kurg, Ants; Berik, Evgeny; Justice, John; Aherne, Margaret; Macek, Milan; Galvin, Paul

    2012-10-01

    Point-of-care (POC) systems require significant component integration to implement biochemical protocols associated with molecular diagnostic assays. Hybrid platforms where discrete components are combined in a single platform are a suitable approach to integration, where combining multiple device fabrication steps on a single substrate is not possible due to incompatible or costly fabrication steps. We integrate three devices each with a specific system functionality: (i) a silicon electro-wetting-on-dielectric (EWOD) device to move and mix sample and reagent droplets in an oil phase, (ii) a polymer microfluidic chip containing channels and reservoirs and (iii) an aqueous phase glass microarray for fluorescence microarray hybridization detection. The EWOD device offers the possibility of fully integrating on-chip sample preparation using nanolitre sample and reagent volumes. A key challenge is sample transfer from the oil phase EWOD device to the aqueous phase microarray for hybridization detection. The EWOD device, waveguide performance and functionality are maintained during the integration process. An on-chip biochemical protocol for arrayed primer extension (APEX) was implemented for single nucleotide polymorphism (SNiP) analysis. The prepared sample is aspirated from the EWOD oil phase to the aqueous phase microarray for hybridization. A bench-top instrumentation system was also developed around the integrated platform to drive the EWOD electrodes, implement APEX sample heating and image the microarray after hybridization.

  5. Core-shell hybrid nanostructured delivery platforms for advanced RNAi therapeutics.

    Science.gov (United States)

    Sajeesh, S; Choe, Jeong Yong; Lee, Dong Ki

    2017-09-04

    Study was aimed at combining the advantages of nonclassical RNAi-triggering oligonucleotides with nanoparticle-based advanced delivery platforms for developing efficient therapeutic systems. We utilized a core-shell hybrid nanostructured platform for effectively delivering nonclassical RNAi triggers, namely long double stranded interfering RNA and tripodal interfering RNA. Core-shell structure was prepared by stably anchoring thiol-modified cationic polymer on the surface of growing crystal gold (Au) seeds, and the resulting particles were further complexed with nonclassical RNAi candidates via electrostatic interactions. Our studies clearly demonstrated that the unique combination of nonclassical RNAi structures with an advanced core-shell hybrid nanostructured platform is an effective module for advanced RNAi-based therapeutic development.

  6. iES - An Intelligent Electronic Sales Platform

    Energy Technology Data Exchange (ETDEWEB)

    Stanton, V L; Korbe III, W; Gao, J G

    2003-10-02

    Current e-commerce systems support online shopping based on electronic product catalogs. The major issues associated with catalog-based commerce systems are: difficulty in distinguishing one retailer from another, complex navigation with confusing links, and a lack of personalized service. This paper reports an intelligent solution to address these issues. Our solution will provide a more personalized sales experience through the use of a transaction-based knowledge model that includes both the rules used for reasoning as well as the corresponding actions. Based on this solution, we have developed an intelligent electronic sales platform that is supported by a framework which provides the desired personalization as well as extensibility and customization capabilities. This paper reports our design and development of this system and application examples.

  7. Novel electrochemical xanthine biosensor based on chitosan–polypyrrole–gold nanoparticles hybrid bio-nanocomposite platform

    Directory of Open Access Journals (Sweden)

    Muamer Dervisevic

    2017-07-01

    Full Text Available The aim of this study was the electrochemical detection of the adenosine-3-phosphate degradation product, xanthine, using a new xanthine biosensor based on a hybrid bio-nanocomposite platform which has been successfully employed in the evaluation of meat freshness. In the design of the amperometric xanthine biosensor, chitosan–polypyrrole–gold nanoparticles fabricated by an in situ chemical synthesis method on a glassy carbon electrode surface was used to enhance electron transfer and to provide good enzyme affinity. Electrochemical studies were carried out by the modified electrode with immobilized xanthine oxidase on it, after which the biosensor was tested to ascertain the optimization parameters. The Biosensor exhibited a very good linear range of 1–200 μM, low detection limit of 0.25 μM, average response time of 8 seconds, and was not prone to significant interference from uric acid, ascorbic acid, glucose, and sodium benzoate. The resulting bio-nanocomposite xanthine biosensor was tested with fish, beef, and chicken real-sample measurements.

  8. Hybrid Integrated Silicon Microfluidic Platform for Fluorescence Based Biodetection

    Directory of Open Access Journals (Sweden)

    André Darveau

    2007-09-01

    Full Text Available The desideratum to develop a fully integrated Lab-on-a-chip device capable ofrapid specimen detection for high throughput in-situ biomedical diagnoses and Point-of-Care testing applications has called for the integration of some of the novel technologiessuch as the microfluidics, microphotonics, immunoproteomics and Micro ElectroMechanical Systems (MEMS. In the present work, a silicon based microfluidic device hasbeen developed for carrying out fluorescence based immunoassay. By hybrid attachment ofthe microfluidic device with a Spectrometer-on-chip, the feasibility of synthesizing anintegrated Lab-on-a-chip type device for fluorescence based biosensing has beendemonstrated. Biodetection using the microfluidic device has been carried out usingantigen sheep IgG and Alexafluor-647 tagged antibody particles and the experimentalresults prove that silicon is a compatible material for the present application given thevarious advantages it offers such as cost-effectiveness, ease of bulk microfabrication,superior surface affinity to biomolecules, ease of disposability of the device etc., and is thussuitable for fabricating Lab-on-a-chip type devices.

  9. Plug-in Hybrid Power Platform for Technology Development%插电式混合动力轿车动力平台技术开发

    Institute of Scientific and Technical Information of China (English)

    韩友国; 王若飞

    2015-01-01

    本文以某款PHEV轿车为研究对象,对混合动力平台进行开发研究,研究前桥混合动力驱动系统的集成及优化,对后桥电子驱动系统的设计及布置合理性进行分析讨论,并对整车安全性能进行研究分析,最终得出确定此混合动力平台技术可行。%Based on chery G3 PHEV cars as the research object, research on hybrid platform for development, research front axle hybrid drive system integration and optimization, the rear axle of electronic drive system design and arrangement of rationality analysis discussion, and through analyzing the performance of the vehicle safety, ultimately determine the hybrid platform technology is feasible.

  10. Photovoltaics: Highly Efficient Hybrid Photovoltaics Based on Hyperbranched Three-Dimensional TiO 2 Electron Transporting Materials (Adv. Mater. 18/2015)

    KAUST Repository

    Mahmood, Khalid

    2015-05-01

    Solution-processed hybrid photovoltaics are a potentially disruptive third-generation solar cell technology. On page 2859, A. Amassian and co-workers demonstrate that an electrospun hyperbranched electron-transporting material is capable of achieving highly efficient hybrid solar cells across different platforms, including lead-halide perovskites (15.5%) and dye-sensitized solar cells (11.2%).

  11. Comparison Of Hybrid Sorting Algorithms Implemented On Different Parallel Hardware Platforms

    Directory of Open Access Journals (Sweden)

    Dominik Zurek

    2013-01-01

    Full Text Available Sorting is a common problem in computer science. There are lot of well-known sorting algorithms created for sequential execution on a single processor. Recently, hardware platforms enable to create wide parallel algorithms. We have standard processors consist of multiple cores and hardware accelerators like GPU. The graphic cards with their parallel architecture give new possibility to speed up many algorithms. In this paper we describe results of implementation of a few different sorting algorithms on GPU cards and multicore processors. Then hybrid algorithm will be presented which consists of parts executed on both platforms, standard CPU and GPU.

  12. Hybrid platforms of graphane–graphene 2D structures: prototypes for atomically precise nanoelectronics

    OpenAIRE

    Mota,F.B.; Rivelino, R.; Medeiros, P.V.C.; Mascarenhas, A.J.S.; de Castilho, C. M. C.

    2014-01-01

    p.23558-23563 First-principles calculations demonstrate that line/ribbon defects, resulting from a controlled dehydrogenation in graphane, lead to the formation of low-dimensional electron-rich tracks in a monolayer. The present simulations point out that hybrid graphane–graphene nanostructures exhibit important elements, greatly required for the fabrication of efficient electronic circuits at the atomic level.

  13. Using Instant Messaging Systems as a Platform for Electronic Voting

    Science.gov (United States)

    Meletiadou, Anastasia; Grimm, Rüdiger

    Many Instant Messaging (IM) systems like Skype or Spark offer ex tended services such as file sharing, VoIP, or a shared whiteboard. As the name suggests, IM applications are predominantly used for spontaneous text-based communication for private or business purposes. In this paper we explore their potential to serve as platforms for secure collaborative applications like electronic contract negotiation, e-payment or electronic voting. Such applications have to deal with challenges like time constraints (“instant” com munication is desired), integration of media channels and the absence of one uni fying “sphere of control” covering all participants. In this paper, we address these challenges by discussing one particular secure collaborative application: secure decision processes for small groups. We provide the following contribu tions: (1) we define three varying scenarios and corresponding security require ments (2) we present an IM-based architecture implementing these scenarios, in cluding a Video-based authentication mechanism, and (3) we discuss poten tial attack patterns.

  14. Hybrid simulation of electron cyclotron resonance heating

    CERN Document Server

    Ropponen, T; Suominen, P; Koponen, T K; Kalvas, T; Koivisto, H

    2008-01-01

    Electron Cyclotron Resonance (ECR) heating is a fundamentally important aspect in understanding the physics of Electron Cyclotron Resonance Ion Sources (ECRIS). Absorption of the radio frequency (RF) microwave power by electron heating in the resonance zone depends on many parameters including frequency and electric field strength of the microwave, magnetic field structure and electron and ion density profiles. ECR absorption has been studied in the past by e.g. modelling electric field behaviour in the resonance zone and its near proximity. This paper introduces a new ECR heating code that implements damping of the microwave power in the vicinity of the resonance zone, utilizes electron density profiles and uses right hand circularly polarized (RHCP) electromagnetic waves to simulate electron heating in ECRIS plasma.

  15. Hybrid simulation of electron cyclotron resonance heating

    Energy Technology Data Exchange (ETDEWEB)

    Ropponen, T. [Department of Physics, University of Jyvaeskylae, P.O. Box 35, FI-40014 (Finland)], E-mail: tommi.ropponen@phys.jyu.fi; Tarvainen, O. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Suominen, P. [CERN Geneve 23, CH-1211 (Switzerland); Koponen, T.K. [Department of Physics, University of Jyvaeskylae, Nanoscience Center, P.O. Box 35, FI-40014 (Finland); Kalvas, T.; Koivisto, H. [Department of Physics, University of Jyvaeskylae, P.O. Box 35, FI-40014 (Finland)

    2008-03-11

    Electron Cyclotron Resonance (ECR) heating is a fundamentally important aspect in understanding the physics of Electron Cyclotron Resonance Ion Sources (ECRIS). Absorption of the radio frequency (RF) microwave power by electron heating in the resonance zone depends on many parameters including frequency and electric field strength of the microwave, magnetic field structure and electron and ion density profiles. ECR absorption has been studied in the past by e.g. modelling electric field behaviour in the resonance zone and its near proximity. This paper introduces a new ECR heating code that implements damping of the microwave power in the vicinity of the resonance zone, utilizes electron density profiles and uses right hand circularly polarized (RHCP) electromagnetic waves to simulate electron heating in ECRIS plasma.

  16. Technique for Measuring Hybrid Electronic Component Reliability

    Energy Technology Data Exchange (ETDEWEB)

    Green, C.C.; Hernandez, C.L.; Hosking, F.M.; Robinson, D.; Rutherford, B.; Uribe, F.

    1999-01-01

    Materials compatibility studies of aged, engineered materials and hardware are critical to understanding and predicting component reliability, particularly for systems with extended stockpile life requirements. Nondestructive testing capabilities for component reliability would significantly enhance lifetime predictions. For example, if the detection of crack propagation through a solder joint can be demonstrated, this technique could be used to develop baseline information to statistically determine solder joint lifelengths. This report will investigate high frequency signal response techniques for nondestructively evaluating the electrical behavior of thick film hybrid transmission lines.

  17. Carbon dots rooted agarose hydrogel hybrid platform for optical detection and separation of heavy metal ions.

    Science.gov (United States)

    Gogoi, Neelam; Barooah, Mayuri; Majumdar, Gitanjali; Chowdhury, Devasish

    2015-02-11

    A robust solid sensing platform for an on-site operational and accurate detection of heavy metal is still a challenge. We introduce chitosan based carbon dots rooted agarose hydrogel film as a hybrid solid sensing platform for detection of heavy metal ions. The fabrication of the solid sensing platform is centered on simple electrostatic interaction between the NH3+ group present in the carbon dots and the OH- groups present in agarose. Simply on dipping the hydrogel film strip into the heavy metal ion solution, in particular Cr6+, Cu2+, Fe3+, Pb2+, Mn2+, the strip displays a color change, viz., Cr6+→yellow, Cu2+→blue, Fe3+→brown, Pb2+→white, Mn2+→tan brown. The optical detection limit of the respective metal ion is found to be 1 pM for Cr6+, 0.5 μM for Cu2+, and 0.5 nM for Fe3+, Pb2+, and Mn2+ by studying the changes in UV-visible reflectance spectrum of the hydrogel film. Moreover, the hydrogel film finds applicability as an efficient filtration membrane for separation of these quintet heavy metal ions. The strategic fundamental feature of this sensing platform is the successful capability of chitosan to form colored chelates with transition metals. This proficient hybrid hydrogel solid sensing platform is thus the most suitable to employ as an on-site operational, portable, cheap colorimetric-optical detector of heavy metal ion with potential skill in their separation. Details of the possible mechanistic insight into the colorimetric detection and ion separation are also discussed.

  18. Hybrid electronics and electrochemistry with conjugated polymers.

    Science.gov (United States)

    Inganäs, Olle

    2010-07-01

    In this critical review, we discuss the history and development of polymer devices wherein manipulation of the electronic conductivity by electrochemical redox processes in a conjugated polymer is used to form new functions. The devices employed are an electrochemical transistor, an electrolyte-gated field-effect transistor and light-emitting electrochemical cells, all of which combine doping/undoping of a conjugated polymer with modification of electronic transport (130 references).

  19. Development of a software platform for a plug-in hybrid electric vehicle simulator

    Science.gov (United States)

    Karlis, Athanasios; Bibeau, Eric; Zanetel, Paul; Lye, Zelon

    2012-03-01

    Electricity use for transportation has had limited applications because of battery storage range issues, although many recent successful demonstrations of electric vehicles have been achieved. Renewable biofuels such as biodiesel and bioethanol also contribute only a small percentage of the overall energy mix for mobility. Recent advances in hybrid technologies have significantly increased vehicle efficiencies. More importantly, hybridization now allows a significant reduction in battery capacity requirements compared to pure electric vehicles, allowing electricity to be used in the overall energy mix in the transportation sector. This paper presents an effort made to develop a Plug-in Hybrid Electric Vehicle (PHEV) platform that can act as a comprehensive alternative energy vehicle simulator. Its goal is to help in solving the pressing needs of the transportation sector, both in terms of contributing data to aid policy decisions for reducing fossil fuel use, and to support research in this important area. The Simulator will allow analysing different vehicle configurations, and control strategies with regards to renewable and non-renewable fuel and electricity sources. The simulation platform models the fundamental aspects of PHEV components, that is, process control, heat transfer, chemical reactions, thermodynamics and fluid properties. The outcomes of the Simulator are: (i) determining the optimal combination of fuels and grid electricity use, (ii) performing greenhouse gas calculations based on emerging protocols being developed, and (iii) optimizing the efficient and proper use of renewable energy sources in a carbon constrained world.

  20. Optical sensor array platform based on polymer electronic devices

    Science.gov (United States)

    Koetse, Marc M.; Rensing, Peter A.; Sharpe, Ruben B. A.; van Heck, Gert T.; Allard, Bart A. M.; Meulendijks, Nicole N. M. M.; Kruijt, Peter G. M.; Tijdink, Marcel W. W. J.; De Zwart, René M.; Houben, René J.; Enting, Erik; van Veen, Sjaak J. J. F.; Schoo, Herman F. M.

    2007-10-01

    Monitoring of personal wellbeing and optimizing human performance are areas where sensors have only begun to be used. One of the reasons for this is the specific demands that these application areas put on the underlying technology and system properties. In many cases these sensors will be integrated in clothing, be worn on the skin, or may even be placed inside the body. This implies that flexibility and wearability of the systems is essential for their success. Devices based on polymer semiconductors allow for these demands since they can be fabricated with thin film technology. The use of thin film device technology allows for the fabrication of very thin sensors (e.g. integrated in food product packaging), flexible or bendable sensors in wearables, large area/distributed sensors, and intrinsically low-cost applications in disposable products. With thin film device technology a high level of integration can be achieved with parts that analyze signals, process and store data, and interact over a network. Integration of all these functions will inherently lead to better cost/performance ratios, especially if printing and other standard polymer technology such as high precision moulding is applied for the fabrication. In this paper we present an optical transmission sensor array based on polymer semiconductor devices made by thin film technology. The organic devices, light emitting diodes, photodiodes and selective medium chip, are integrated with classic electronic components. Together they form a versatile sensor platform that allows for the quantitative measurement of 100 channels and communicates wireless with a computer. The emphasis is given to the sensor principle, the design, fabrication technology and integration of the thin film devices.

  1. Hybrid Microfluidic Platform for Multifactorial Analysis Based on Electrical Impedance, Refractometry, Optical Absorption and Fluorescence

    Directory of Open Access Journals (Sweden)

    Fábio M. Pereira

    2016-10-01

    Full Text Available This paper describes the development of a novel microfluidic platform for multifactorial analysis integrating four label-free detection methods: electrical impedance, refractometry, optical absorption and fluorescence. We present the rationale for the design and the details of the microfabrication of this multifactorial hybrid microfluidic chip. The structure of the platform consists of a three-dimensionally patterned polydimethylsiloxane top part attached to a bottom SU-8 epoxy-based negative photoresist part, where microelectrodes and optical fibers are incorporated to enable impedance and optical analysis. As a proof of concept, the chip functions have been tested and explored, enabling a diversity of applications: (i impedance-based identification of the size of micro beads, as well as counting and distinguishing of erythrocytes by their volume or membrane properties; (ii simultaneous determination of the refractive index and optical absorption properties of solutions; and (iii fluorescence-based bead counting.

  2. Photoinduced Reductive Electron Transfer in LNA:DNA Hybrids

    DEFF Research Database (Denmark)

    Wenge, Ulrike; Wengel, Jesper; Wagenknecht, Hans-Achim

    2012-01-01

    Lock it, but not too much: LNA units (locked or bridging nucleic acids) in LNA:DNA hybrids lead to a negative effect on electron transfer (ET), but they also force the nucleic acid structure in the A-type double helix, which allows a better base stacking than the normal B-type and thus positively...... influences the ET. This result is significant for the design of nucleic acids of molecular electronics....

  3. Throttleable GOX/ABS launch assist hybrid rocket motor for small scale air launch platform

    Science.gov (United States)

    Spurrier, Zachary S.

    Aircraft-based space-launch platforms allow operational flexibility and offer the potential for significant propellant savings for small-to-medium orbital payloads. The NASA Armstrong Flight Research Center's Towed Glider Air-Launch System (TGALS) is a small-scale flight research project investigating the feasibility for a remotely-piloted, towed, glider system to act as a versatile air launch platform for nano-scale satellites. Removing the crew from the launch vehicle means that the system does not have to be human rated, and offers a potential for considerable cost savings. Utah State University is developing a small throttled launch-assist system for the TGALS platform. This "stage zero" design allows the TGALS platform to achieve the required flight path angle for the launch point, a condition that the TGALS cannot achieve without external propulsion. Throttling is required in order to achieve and sustain the proper launch attitude without structurally overloading the airframe. The hybrid rocket system employs gaseous-oxygen and acrylonitrile butadiene styrene (ABS) as propellants. This thesis summarizes the development and testing campaign, and presents results from the clean-sheet design through ground-based static fire testing. Development of the closed-loop throttle control system is presented.

  4. arrayCGHbase: an analysis platform for comparative genomic hybridization microarrays

    Directory of Open Access Journals (Sweden)

    Moreau Yves

    2005-05-01

    Full Text Available Abstract Background The availability of the human genome sequence as well as the large number of physically accessible oligonucleotides, cDNA, and BAC clones across the entire genome has triggered and accelerated the use of several platforms for analysis of DNA copy number changes, amongst others microarray comparative genomic hybridization (arrayCGH. One of the challenges inherent to this new technology is the management and analysis of large numbers of data points generated in each individual experiment. Results We have developed arrayCGHbase, a comprehensive analysis platform for arrayCGH experiments consisting of a MIAME (Minimal Information About a Microarray Experiment supportive database using MySQL underlying a data mining web tool, to store, analyze, interpret, compare, and visualize arrayCGH results in a uniform and user-friendly format. Following its flexible design, arrayCGHbase is compatible with all existing and forthcoming arrayCGH platforms. Data can be exported in a multitude of formats, including BED files to map copy number information on the genome using the Ensembl or UCSC genome browser. Conclusion ArrayCGHbase is a web based and platform independent arrayCGH data analysis tool, that allows users to access the analysis suite through the internet or a local intranet after installation on a private server. ArrayCGHbase is available at http://medgen.ugent.be/arrayCGHbase/.

  5. High performance technique for database applicationsusing a hybrid GPU/CPU platform

    KAUST Repository

    Zidan, Mohammed A.

    2012-07-28

    Many database applications, such as sequence comparing, sequence searching, and sequence matching, etc, process large database sequences. we introduce a novel and efficient technique to improve the performance of database applica- tions by using a Hybrid GPU/CPU platform. In particular, our technique solves the problem of the low efficiency result- ing from running short-length sequences in a database on a GPU. To verify our technique, we applied it to the widely used Smith-Waterman algorithm. The experimental results show that our Hybrid GPU/CPU technique improves the average performance by a factor of 2.2, and improves the peak performance by a factor of 2.8 when compared to earlier implementations. Copyright © 2011 by ASME.

  6. Single Electron Transistor Platform for Microgravity Proteomics Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This Phase II program builds from the successful Phase I efforts to demonstrate that Quantum Logic Devices' nanoelectronic platform for biological detection could...

  7. Electrostatic electron cyclotron instabilities near the upper hybrid layer due to electron ring distributions

    Science.gov (United States)

    Eliasson, B.; Speirs, D. C.; Daldorff, L. K. S.

    2016-09-01

    A theoretical study is presented of the electrostatic electron cyclotron instability involving Bernstein modes in a magnetized plasma. The presence of a tenuous thermal ring distribution in a Maxwellian plasma decreases the frequency of the upper hybrid branch of the electron Bernstein mode until it merges with the nearest lower branch with a resulting instability. The instability occurs when the upper hybrid frequency is somewhat above the third, fourth, and higher electron cyclotron harmonics, and gives rise to a narrow spectrum of waves around the electron cyclotron harmonic nearest to the upper hybrid frequency. For a tenuous cold ring distribution together with a Maxwellian distribution an instability can take place also near the second electron cyclotron harmonic. Noise-free Vlasov simulations are used to assess the theoretical linear growth-rates and frequency spectra, and to study the nonlinear evolution of the instability. The relevance of the results to laboratory and ionospheric heating experiments is discussed.

  8. Electronic properties of hybrid metal-discotic liquid crystal nanostructures

    Science.gov (United States)

    Kelsall, R. W.; Pecchia, A.; Bourlange, A.; Movaghar, B.; Evans, S. D.; Hickey, B. J.; Boden, N.

    2003-04-01

    A new class of hybrid organic/inorganic nanostructures, comprising self-organised discotic liquid crystal layers deposited on ultrathin metal films, has been investigated both experimentally and theoretically. Calculations show that the periodic self-organised molecular layer gives rise to a new, hybrid electronic bandstructure, resulting in modulation of the metal film conductivity. In situ conductivity measurements during deposition of such self-organised layers confirm that the metal film conductivity is altered. Theoretical modeling also shows that the AC conductivity should show structure related to the carrier trapping and one-dimensional transport features of the self-organised layer.

  9. Quantitative data analysis methods for bead-based DNA hybridization assays using generic flow cytometry platforms.

    Science.gov (United States)

    Corrie, S R; Lawrie, G A; Battersby, B J; Ford, K; Rühmann, A; Koehler, K; Sabath, D E; Trau, M

    2008-05-01

    Bead-based assays are in demand for rapid genomic and proteomic assays for both research and clinical purposes. Standard quantitative procedures addressing raw data quality and analysis are required to ensure the data are consistent and reproducible across laboratories independent of flow platform. Quantitative procedures have been introduced spanning raw histogram analysis through to absolute target quantitation. These included models developed to estimate the absolute number of sample molecules bound per bead (Langmuir isotherm), relative quantitative comparisons (two-sided t-tests), and statistical analyses investigating the quality of raw fluorescence data. The absolute target quantitation method revealed a concentration range (below probe saturation) of Cy5-labeled synthetic cytokeratin 19 (K19) RNA of c.a. 1 x 10(4) to 500 x 10(4) molecules/bead, with a binding constant of c.a. 1.6 nM. Raw hybridization frequency histograms were observed to be highly reproducible across 10 triplex assay replicates and only three assay replicates were required to distinguish overlapping peaks representing small sequence mismatches. This study provides a quantitative scheme for determining the absolute target concentration in nucleic acid hybridization reactions and the equilibrium binding constants for individual probe/target pairs. It is envisaged that such studies will form the basis of standard analytical procedures for bead-based cytometry assays to ensure reproducibility in inter- and intra-platform comparisons of data between laboratories. (c) 2008 International Society for Advancement of Cytometry.

  10. Direct Electron Transfer of Enzymes in a Biologically Assembled Conductive Nanomesh Enzyme Platform.

    Science.gov (United States)

    Lee, Seung-Woo; Lee, Ki-Young; Song, Yong-Won; Choi, Won Kook; Chang, Joonyeon; Yi, Hyunjung

    2016-02-24

    Nondestructive assembly of a nanostructured enzyme platform is developed in combination of the specific biomolecular attraction and electrostatic coupling for highly efficient direct electron transfer (DET) of enzymes with unprecedented applicability and versatility. The biologically assembled conductive nanomesh enzyme platform enables DET-based flexible integrated biosensors and DET of eight different enzyme with various catalytic activities.

  11. Leveraging the Libguides Platform for Electronic Resources Access Assistance

    Science.gov (United States)

    Erb, Rachel A.; Erb, Brian

    2014-01-01

    This case study offers an alternative use of LibGuides beyond its intended purpose to offer course and subject guides. LibGuides have become an integral part of the virtual instruction landscape at Colorado State University (CSU) Libraries. We discovered that the LibGuides platform can also be effectively harnessed to provide support for…

  12. Leveraging the Libguides Platform for Electronic Resources Access Assistance

    Science.gov (United States)

    Erb, Rachel A.; Erb, Brian

    2014-01-01

    This case study offers an alternative use of LibGuides beyond its intended purpose to offer course and subject guides. LibGuides have become an integral part of the virtual instruction landscape at Colorado State University (CSU) Libraries. We discovered that the LibGuides platform can also be effectively harnessed to provide support for…

  13. Versatile Molecular Silver Ink Platform for Printed Flexible Electronics.

    Science.gov (United States)

    Kell, Arnold J; Paquet, Chantal; Mozenson, Olga; Djavani-Tabrizi, Iden; Deore, Bhavana; Liu, Xiangyang; Lopinski, Gregory P; James, Robert; Hettak, Khelifa; Shaker, Jafar; Momciu, Adrian; Ferrigno, Julie; Ferrand, Olivier; Hu, Jian Xiong; Lafrenière, Sylvie; Malenfant, Patrick R L

    2017-05-24

    A silver molecular ink platform formulated for screen, inkjet, and aerosol jet printing is presented. A simple formulation comprising silver neodecanoate, ethyl cellulose, and solvent provides improved performance versus that of established inks, yet with improved economics. Thin, screen-printed traces with exceptional electrical (10(4) were obtained, performance similar to that of evaporated metal contacts in analogous devices.

  14. Hybrid planar free-electron maser in the magnetoresonance regime

    Directory of Open Access Journals (Sweden)

    Vitaliy A. Goryashko

    2009-10-01

    Full Text Available We study the operation regime of a hybrid planar free-electron maser (FEM amplifier near the magnetoresonant value of the uniform longitudinal (guide magnetic field. Using analytical expressions for individual test electron trajectories and normal frequencies of their three-dimensional oscillations in the magnetostatic field of the hybrid planar FEM, an analytical condition of chaotization of motion is established and shown to be given by the Chirikov resonance-overlap criterion applied to the normal undulator and cyclotron frequencies with respect to the coupling induced by the undulator magnetic field. It is also shown analytically that, in spite of the well-known drop for the exact magnetoresonance, the gain attains its maximal value in the zone of regular dynamics slightly above the magnetoresonant value of the guide magnetic field. Under the condition of undulator resonance, it is practically independent of the amplitude of the undulator magnetic field and the wavelength of amplified signal. To account for space-charge effects, we propose a theoretical model of a weakly relativistic FEM, which accommodates not only potential but also rotational parts of the nonradiated electromagnetic field of a moving charged particle. It turns out that the rotational part of nonradiated field diminishes the defocusing influence of the potential part on the beam bunching. Numeric simulation of the nonlinear stage of amplification is fulfilled, taking into consideration adiabatic entrance of the electron beam to the interaction region and initial electron velocity spread. We find that nonradiated field and initial electron velocity spread do not influence essentially the efficiency of hybrid planar FEM amplification if parameters of the beam-microwave interaction correspond to the operational regime in the zone of regular dynamics near the magnetoresonance.

  15. Semiempirical Quantum Chemical Calculations Accelerated on a Hybrid Multicore CPU-GPU Computing Platform.

    Science.gov (United States)

    Wu, Xin; Koslowski, Axel; Thiel, Walter

    2012-07-10

    In this work, we demonstrate that semiempirical quantum chemical calculations can be accelerated significantly by leveraging the graphics processing unit (GPU) as a coprocessor on a hybrid multicore CPU-GPU computing platform. Semiempirical calculations using the MNDO, AM1, PM3, OM1, OM2, and OM3 model Hamiltonians were systematically profiled for three types of test systems (fullerenes, water clusters, and solvated crambin) to identify the most time-consuming sections of the code. The corresponding routines were ported to the GPU and optimized employing both existing library functions and a GPU kernel that carries out a sequence of noniterative Jacobi transformations during pseudodiagonalization. The overall computation times for single-point energy calculations and geometry optimizations of large molecules were reduced by one order of magnitude for all methods, as compared to runs on a single CPU core.

  16. Applications integration in a hybrid cloud computing environment: modelling and platform

    Science.gov (United States)

    Li, Qing; Wang, Ze-yuan; Li, Wei-hua; Li, Jun; Wang, Cheng; Du, Rui-yang

    2013-08-01

    With the development of application services providers and cloud computing, more and more small- and medium-sized business enterprises use software services and even infrastructure services provided by professional information service companies to replace all or part of their information systems (ISs). These information service companies provide applications, such as data storage, computing processes, document sharing and even management information system services as public resources to support the business process management of their customers. However, no cloud computing service vendor can satisfy the full functional IS requirements of an enterprise. As a result, enterprises often have to simultaneously use systems distributed in different clouds and their intra enterprise ISs. Thus, this article presents a framework to integrate applications deployed in public clouds and intra ISs. A run-time platform is developed and a cross-computing environment process modelling technique is also developed to improve the feasibility of ISs under hybrid cloud computing environments.

  17. Electronic structure of hybrid interfaces for polymer-based electronics.

    Science.gov (United States)

    Fahlman, M; Crispin, A; Crispin, X; Henze, S K M; de Jong, M P; Osikowicz, W; Tengstedt, C; Salaneck, W R

    2007-05-08

    The fundamentals of the energy level alignment at anode and cathode electrodes in organic electronics are described. We focus on two different models that treat weakly interacting organic/metal (and organic/organic) interfaces: the induced density of interfacial states model and the so-called integer charge transfer model. The two models are compared and evaluated, mainly using photoelectron spectroscopy data of the energy level alignment of conjugated polymers and molecules at various organic/metal and organic/organic interfaces. We show that two different alignment regimes are generally observed: (i) vacuum level alignment, which corresponds to the lack of vacuum level offsets (Schottky-Mott limit) and hence the lack of charge transfer across the interface, and (ii) Fermi level pinning where the resulting work function of an organic/metal and organic/organic bilayer is independent of the substrate work function and an interface dipole is formed due to charge transfer across the interface. We argue that the experimental results are best described by the integer charge transfer model which predicts the vacuum level alignment when the substrate work function is above the positive charge transfer level and below the negative charge transfer level of the conjugated material. The model further predicts Fermi level pinning to the positive (negative) charge transfer level when the substrate work function is below (above) the positive (negative) charge transfer level. The nature of the integer charge transfer levels depend on the materials system: for conjugated large molecules and polymers, the integer charge transfer states are polarons or bipolarons; for small molecules' highest occupied and lowest unoccupied molecular orbitals and for crystalline systems, the relevant levels are the valence and conduction band edges. Finally, limits and further improvements to the integer charge transfer model are discussed as well as the impact on device design.

  18. A robust platform cooled by superconducting electronic refrigerators

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, H. Q. [Low Temperature Laboratory (OVLL), Aalto University School of Science, P.O. Box 13500, 00076 Aalto (Finland); Nano and Energy Center, Hanoi University of Science, VNU, Hanoi (Viet Nam); Meschke, M.; Pekola, J. P. [Low Temperature Laboratory (OVLL), Aalto University School of Science, P.O. Box 13500, 00076 Aalto (Finland)

    2015-01-05

    A biased tunnel junction between a superconductor and a normal metal can cool the latter electrode. Based on a recently developed cooler with high power and superior performance, we have integrated it with a dielectric silicon nitride membrane, and cooled phonons from 305 mK down to 200 mK. Without perforation and covered under a thin alumina layer, the membrane is rigorously transformed into a cooling platform that is robust and versatile for multiple practical purposes. We discussed our results and possibilities to further improve the device.

  19. Hybrid Model Testing Technique for Deep-Sea Platforms Based on Equivalent Water Depth Truncation

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    In this paper, an inner turret moored FPSO which works in the water of 320 m depth, is selected to study the so-called "passively-truncated + numerical-simulation" type of hybrid model testing technique while the truncated water depth is 160 m and the model scale λ=80. During the investigation, the optimization design of the equivalent-depth truncated system is performed by using the similarity of the static characteristics between the truncated system and the full depth one as the objective function. According to the truncated system, the corresponding physical test model is made. By adopting the coupling time domain simulation method, the truncated system model test is numerically reconstructed to carefully verify the computer simulation software and to adjust the corresponding hydrodynamic parameters. Based on the above work, the numerical extrapolation to the full depth system is performed by using the verified computer software and the adjusted hydrodynamic parameters. The full depth system model test is then performed in the basin and the results are compared with those from the numerical extrapolation. At last, the implementation procedure and the key technique of the hybrid model testing of the deep-sea platforms are summarized and printed. Through the above investigations, some beneficial conclusions are presented.

  20. Hybrid liposomal PEGylated calix[4]arene systems as drug delivery platforms for curcumin.

    Science.gov (United States)

    Drakalska, Elena; Momekova, Denitsa; Manolova, Yana; Budurova, Dessislava; Momekov, Georgi; Genova, Margarita; Antonov, Liudmil; Lambov, Nikolay; Rangelov, Stanislav

    2014-09-10

    The tremendous therapeutic potential of curcumin as a chemopreventive, antineoplastic and chemosensitizing agent has failed to progress towards clinical development and commercialization due to its unfavorable physicochemical properties, low aqueous solubility, chemical instability, and pharmacokinetics. The present contribution is focused on the feasibility of using PEGylated calixarene, in particular polyoxyethylene-derivatized tert-butylcalix[4]arene, to prepare various platforms for delivery of curcumin such as inclusion complex, supramolecular aggregates, and hybrid liposomal systems. The inclusion complex is characterized by UV-vis and FT-IR spectroscopy as well as thermal gravimetrical analysis and differential scanning calorimetry. At concentrations exceeding the critical micellization concentration of PEGylated calixarene, the tremendous solubility enhancement of curcumin is attributed to additional solubilization and hydrophobic non-covalent interactions of the drug with supramolecular aggregates. A hybrid liposomal system is created via encapsulation of the inclusion complex in dipalmitoylphosphatidylcholine:cholesterol liposomes. Bare and liposomal curcumin:BEC-X inclusion complexes, as well as free curcumin were additionally investigated for cytotoxicity and apoptogenic activity against human tumor cell lines.

  1. Platform links clinical data with electronic health records

    Science.gov (United States)

    To make data gathered from patients in clinical trials available for use in standard care, NCI has created a new computer tool to support interoperability between clinical research and electronic health record systems. This new software represents an inno

  2. Hybrid [5]Radialenes with Bispyrroloheteroles: New Electron-Donating Units.

    Science.gov (United States)

    Higashino, Tomohiro; Imahori, Hiroshi

    2015-09-14

    Bispyrroloheteroles have been synthesized to address their intrinsic structural, optical, and electrochemical properties. The X-ray crystal structures and calculated natural bond orbital (NBO) bond orders unambiguously demonstrated the existence of a two pyrrole-fused five-membered ring with short exocyclic C-C double bonds and long endocyclic C-C single bonds, supporting that the bispyrroloheteroles are rare examples of structurally characterized hybrid [5]radialenes. The bispyrroloheteroles were found to act as an electron-donating unit, which would be fascinating for the rational design of new charge-transporting and donor-acceptor photovoltaic materials as well as versatile charge-transfer complexes.

  3. Transmission electron microscopy of unstained hybrid Au nanoparticles capped with PPAA (plasma-poly-allylamine)

    DEFF Research Database (Denmark)

    Gontard, Lionel C.; Fernández, Asunción; Dunin-Borkowski, Rafal E.;

    2014-01-01

    Hybrid (organic shell-inorganic core) nanoparticles have important applications in nanomedicine. Although the inorganic components of hybrid nanoparticles can be characterized readily using conventional transmission electron microscopy (TEM) techniques, the structural and chemical arrangement of ...

  4. Structural and electronic properties of hybrid silicon-germanium nanosheets

    Directory of Open Access Journals (Sweden)

    F. L. Pérez Sánchez

    2014-12-01

    Full Text Available Using first principles molecular calculations, based on the Density Functional Theory (DFT, structural and electronic properties of hybrid graphene—like silicon—germanium circular nanosheets of hexagonal symmetry are investigated. The exchange—correlation functional of Perdew—Wang (PW in the local spin density approximation (LSDA based on the pseudopotentials of Dolg—Bergnre is applied. The finite extension nanosheets are represented by the CnHm—like cluster model with mono—hydrogenated armchair edges. Changes of the physicochemical properties were analyzed to learn on the chemical composition. We have obtained that the corrugation of the hybrid nanosheets is maintained (with respect to the pristine nanosheets of Ge and Si and is more pronounced when there is a high percentage of germanium. Moreover, hybrid nanosheets have ionic bonds (polarity in the interval from 0.18 to 0.77 D and exhibit a semimetal behavior. Three types of chemical compositions are considered: 1 the one—one relationship, 2 formation of Ge dimers and 3 formation of Ge hexagons. In each case it is observed an increase in the chemical reactivity. Finally, analyzing the work function we conclude that in cases 1 and 2 the chemical compositions improve the efficiency of the field emission and thereby they could expand the scope of nanotechnology applications.

  5. Electron imaging with Medipix2 hybrid pixel detector

    CERN Document Server

    McMullan, G; Chen, S; Henderson, R; Llopart, X; Summerfield, C; Tlustos, L; Faruqi, A R

    2007-01-01

    The electron imaging performance of Medipix2 is described. Medipix2 is a hybrid pixel detector composed of two layers. It has a sensor layer and a layer of readout electronics, in which each 55 μm×55 μm pixel has upper and lower energy discrimination and MHz rate counting. The sensor layer consists of a 300 μm slab of pixellated monolithic silicon and this is bonded to the readout chip. Experimental measurement of the detective quantum efficiency, DQE(0) at 120 keV shows that it can reach 85% independent of electron exposure, since the detector has zero noise, and the DQE(Nyquist) can reach 35% of that expected for a perfect detector (4/π2). Experimental measurement of the modulation transfer function (MTF) at Nyquist resolution for 120 keV electrons using a 60 keV lower energy threshold, yields a value that is 50% of that expected for a perfect detector (2/π). Finally, Monte Carlo simulations of electron tracks and energy deposited in adjacent pixels have been performed and used to calculate expected v...

  6. Electronic heat current rectification in hybrid superconducting devices

    Energy Technology Data Exchange (ETDEWEB)

    Fornieri, Antonio, E-mail: antonio.fornieri@sns.it; Giazotto, Francesco, E-mail: francesco.giazotto@sns.it [NEST, Istituto Nanoscienze-CNR and Scuola Normale Superiore, I-56127 Pisa (Italy); Martínez-Pérez, María José [Physikalisches Institut - Experimentalphysik II Universität Tübingen, D-72076 Tübingen (Germany)

    2015-05-15

    In this work, we review and expand recent theoretical proposals for the realization of electronic thermal diodes based on tunnel-junctions of normal metal and superconducting thin films. Starting from the basic rectifying properties of a single hybrid tunnel junction, we will show how the rectification efficiency can be largely increased by combining multiple junctions in an asymmetric chain of tunnel-coupled islands. We propose three different designs, analyzing their performance and their potential advantages. Besides being relevant from a fundamental physics point of view, this kind of devices might find important technological application as fundamental building blocks in solid-state thermal nanocircuits and in general-purpose cryogenic electronic applications requiring energy management.

  7. An analysis platform for multiscale hydrogeologic modeling with emphasis on hybrid multiscale methods.

    Science.gov (United States)

    Scheibe, Timothy D; Murphy, Ellyn M; Chen, Xingyuan; Rice, Amy K; Carroll, Kenneth C; Palmer, Bruce J; Tartakovsky, Alexandre M; Battiato, Ilenia; Wood, Brian D

    2015-01-01

    One of the most significant challenges faced by hydrogeologic modelers is the disparity between the spatial and temporal scales at which fundamental flow, transport, and reaction processes can best be understood and quantified (e.g., microscopic to pore scales and seconds to days) and at which practical model predictions are needed (e.g., plume to aquifer scales and years to centuries). While the multiscale nature of hydrogeologic problems is widely recognized, technological limitations in computation and characterization restrict most practical modeling efforts to fairly coarse representations of heterogeneous properties and processes. For some modern problems, the necessary level of simplification is such that model parameters may lose physical meaning and model predictive ability is questionable for any conditions other than those to which the model was calibrated. Recently, there has been broad interest across a wide range of scientific and engineering disciplines in simulation approaches that more rigorously account for the multiscale nature of systems of interest. In this article, we review a number of such approaches and propose a classification scheme for defining different types of multiscale simulation methods and those classes of problems to which they are most applicable. Our classification scheme is presented in terms of a flowchart (Multiscale Analysis Platform), and defines several different motifs of multiscale simulation. Within each motif, the member methods are reviewed and example applications are discussed. We focus attention on hybrid multiscale methods, in which two or more models with different physics described at fundamentally different scales are directly coupled within a single simulation. Very recently these methods have begun to be applied to groundwater flow and transport simulations, and we discuss these applications in the context of our classification scheme. As computational and characterization capabilities continue to improve

  8. Electron-phonon coupling in hybrid lead halide perovskites

    Science.gov (United States)

    Wright, Adam D.; Verdi, Carla; Milot, Rebecca L.; Eperon, Giles E.; Pérez-Osorio, Miguel A.; Snaith, Henry J.; Giustino, Feliciano; Johnston, Michael B.; Herz, Laura M.

    2016-05-01

    Phonon scattering limits charge-carrier mobilities and governs emission line broadening in hybrid metal halide perovskites. Establishing how charge carriers interact with phonons in these materials is therefore essential for the development of high-efficiency perovskite photovoltaics and low-cost lasers. Here we investigate the temperature dependence of emission line broadening in the four commonly studied formamidinium and methylammonium perovskites, HC(NH2)2PbI3, HC(NH2)2PbBr3, CH3NH3PbI3 and CH3NH3PbBr3, and discover that scattering from longitudinal optical phonons via the Fröhlich interaction is the dominant source of electron-phonon coupling near room temperature, with scattering off acoustic phonons negligible. We determine energies for the interacting longitudinal optical phonon modes to be 11.5 and 15.3 meV, and Fröhlich coupling constants of ~40 and 60 meV for the lead iodide and bromide perovskites, respectively. Our findings correlate well with first-principles calculations based on many-body perturbation theory, which underlines the suitability of an electronic band-structure picture for describing charge carriers in hybrid perovskites.

  9. Electron-phonon coupling in hybrid lead halide perovskites.

    Science.gov (United States)

    Wright, Adam D; Verdi, Carla; Milot, Rebecca L; Eperon, Giles E; Pérez-Osorio, Miguel A; Snaith, Henry J; Giustino, Feliciano; Johnston, Michael B; Herz, Laura M

    2016-05-26

    Phonon scattering limits charge-carrier mobilities and governs emission line broadening in hybrid metal halide perovskites. Establishing how charge carriers interact with phonons in these materials is therefore essential for the development of high-efficiency perovskite photovoltaics and low-cost lasers. Here we investigate the temperature dependence of emission line broadening in the four commonly studied formamidinium and methylammonium perovskites, HC(NH2)2PbI3, HC(NH2)2PbBr3, CH3NH3PbI3 and CH3NH3PbBr3, and discover that scattering from longitudinal optical phonons via the Fröhlich interaction is the dominant source of electron-phonon coupling near room temperature, with scattering off acoustic phonons negligible. We determine energies for the interacting longitudinal optical phonon modes to be 11.5 and 15.3 meV, and Fröhlich coupling constants of ∼40 and 60 meV for the lead iodide and bromide perovskites, respectively. Our findings correlate well with first-principles calculations based on many-body perturbation theory, which underlines the suitability of an electronic band-structure picture for describing charge carriers in hybrid perovskites.

  10. IMPLEMENTATION OF FUNCTIONS OF ELECTRONIC DEAN'S OFFICE USING PLATFORM MOODLE

    Directory of Open Access Journals (Sweden)

    Oleksandr A. Shcherbyna

    2016-01-01

    Full Text Available The introduction of information and communication technologies (ICT allows to more effectively and efficiently solve planning and organization tasks, as well as implementation and monitoring of educational process, which are usually handled by the dean's office. The article shows how the functions of electronic dean's office can be implemented in Moodle learning management system using public plugins. In particular, the methods for collection, processing and generalization of operational information about students’ performance are considered. A method of students’ enrollment is offered. The method uses the meta courses and cohorts mechanisms, which allow significantly reduce the amount of work for site administration.

  11. The coming of age of the first hybrid metrology software platform dedicated to nanotechnologies (Conference Presentation)

    Science.gov (United States)

    Foucher, Johann; Labrosse, Aurelien; Dervillé, Alexandre; Zimmermann, Yann; Bernard, Guilhem; Martinez, Sergio; Grönqvist, Hanna; Baderot, Julien; Pinzan, Florian

    2017-03-01

    The development and integration of new materials and structures at the nanoscale require multiple parallel characterizations in order to control mostly physico-chemical properties as a function of applications. Among all properties, we can list physical properties such as: size, shape, specific surface area, aspect ratio, agglomeration/aggregation state, size distribution, surface morphology/topography, structure (including crystallinity and defect structure), solubility and chemical properties such as: structural formula/molecular structure, composition (including degree of purity, known impurities or additives), phase identity, surface chemistry (composition, charge, tension, reactive sites, physical structure, photocatalytic properties, zeta potential), hydrophilicity/lipophilicity. Depending on the final material formulation (aerosol, powder, nanostructuration…) and the industrial application (semiconductor, cosmetics, chemistry, automotive…), a fleet of complementary characterization equipments must be used in synergy for accurate process tuning and high production yield. The synergy between equipment so-called hybrid metrology consists in using the strength of each technique in order to reduce the global uncertainty for better and faster process control. The only way to succeed doing this exercise is to use data fusion methodology. In this paper, we will introduce the work that has been done to create the first generic hybrid metrology software platform dedicated to nanotechnologies process control. The first part will be dedicated to process flow modeling that is related to a fleet of metrology tools. The second part will introduce the concept of entity model which describes the various parameters that have to be extracted. The entity model is fed with data analysis as a function of the application (automatic analysis or semi-automated analysis). The final part will introduce two ways of doing data fusion on real data coming from imaging (SEM, TEM, AFM

  12. Hybrid gate dielectric materials for unconventional electronic circuitry.

    Science.gov (United States)

    Ha, Young-Geun; Everaerts, Ken; Hersam, Mark C; Marks, Tobin J

    2014-04-15

    Recent advances in semiconductor performance made possible by organic π-electron molecules, carbon-based nanomaterials, and metal oxides have been a central scientific and technological research focus over the past decade in the quest for flexible and transparent electronic products. However, advances in semiconductor materials require corresponding advances in compatible gate dielectric materials, which must exhibit excellent electrical properties such as large capacitance, high breakdown strength, low leakage current density, and mechanical flexibility on arbitrary substrates. Historically, conventional silicon dioxide (SiO2) has dominated electronics as the preferred gate dielectric material in complementary metal oxide semiconductor (CMOS) integrated transistor circuitry. However, it does not satisfy many of the performance requirements for the aforementioned semiconductors due to its relatively low dielectric constant and intransigent processability. High-k inorganics such as hafnium dioxide (HfO2) or zirconium dioxide (ZrO2) offer some increases in performance, but scientists have great difficulty depositing these materials as smooth films at temperatures compatible with flexible plastic substrates. While various organic polymers are accessible via chemical synthesis and readily form films from solution, they typically exhibit low capacitances, and the corresponding transistors operate at unacceptably high voltages. More recently, researchers have combined the favorable properties of high-k metal oxides and π-electron organics to form processable, structurally well-defined, and robust self-assembled multilayer nanodielectrics, which enable high-performance transistors with a wide variety of unconventional semiconductors. In this Account, we review recent advances in organic-inorganic hybrid gate dielectrics, fabricated by multilayer self-assembly, and their remarkable synergy with unconventional semiconductors. We first discuss the principals and functional

  13. PaRSEC: A Software Framework for Performance and Productivity on Hybrid, Manycore Platforms

    Energy Technology Data Exchange (ETDEWEB)

    Dongarra, Jack [Univ. of Tennessee, Knoxville, TN (United States)

    2016-06-30

    As the era of computer architectures dominated by serial processors ends, the convergence of several unprecedented challenges suggests that closing the longstanding "application–architecture performance gap" will become more challenging than ever. To address this problem, the Parallel Runtime Scheduling and Execution Control (PaRSEC) project created a modular software framework that achieved two major objectives: first, it built a task-based runtime capable of delivering portable performance to a wide range of science and engineering applications at all levels of the platform pyramid, including the upcoming 100 Pflop/s systems and then exascale; and second, it supported and facilitated the work of developers in migrating their legacy codes and writing entirely new ones for the emerging hybrid and massively parallel manycore processor system designs. PaRSEC will support multiple domain-specific languages capable of increasing the developers' productivity while also providing the runtime with the constructs and flexibility necessary to exploit the maximal parallelism from parallel applications. Extensive preliminary research in dense linear algebra showed convincingly that a parameterized task graph representation that symbolically describes the algorithm content can achieve the project's twofold objective within that domain. The research also strongly suggested that this powerful method could be generalized to a far-wider variety of applications.

  14. Unified Electronic Currency Based on the Fourth Party Platform Integrated Payment Service

    Science.gov (United States)

    Yong, Xu; Qiqi, Hu

    This paper presents a solution of unified e-currency based on the fourth party platform integrated payment service. The purpose of the paper is to solve the problem of distribution and resource-wasting caused by the lack of unified electronic currency, and to solve regulatory difficulties due to regulation size caused by a wide variety of e-currency. Methods: This article first analyzes the problems in the development of electronic money, and then proposes the concept of a unified electronic currency based on the fourth party platform integrated payment service. Besides, it proposes a unified mechanism and transaction procedures for unified e-currency, and analyzes the liquidation process, security and regulatory requirements, which are involved in using unified electronic currency.

  15. Vertical Silicon Nanowire Platform for Low Power Electronics and Clean Energy Applications

    Directory of Open Access Journals (Sweden)

    D.-L. Kwong

    2012-01-01

    Full Text Available This paper reviews the progress of the vertical top-down nanowire technology platform developed to explore novel device architectures and integration schemes for green electronics and clean energy applications. Under electronics domain, besides having ultimate scaling potential, the vertical wire offers (1 CMOS circuits with much smaller foot print as compared to planar transistor at the same technology node, (2 a natural platform for tunneling FETs, and (3 a route to fabricate stacked nonvolatile memory cells. Under clean energy harvesting area, vertical wires could provide (1 cost reduction in photovoltaic energy conversion through enhanced light trapping and (2 a fully CMOS compatible thermoelectric engine converting waste-heat into electricity. In addition to progress review, we discuss the challenges and future prospects with vertical nanowires platform.

  16. Design, Analysis, Hybrid Testing and Orientation Control of a Floating Platform with Counter-Rotating Vertical-Axis Wind Turbines

    Science.gov (United States)

    Kanner, Samuel Adam Chinman

    The design and operation of two counter-rotating vertical-axis wind turbines on a floating, semi-submersible platform is studied. The technology, called the Multiple Integrated and Synchronized Turbines (MIST) platform has the potential to reduce the cost of offshore wind energy per unit of installed capacity. Attached to the platform are closely-spaced, counter-rotating turbines, which can achieve a higher power density per planform area because of synergistic interaction effects. The purpose of the research is to control the orientation of the platform and rotational speeds of the turbines by modifying the energy absorbed by each of the generators of the turbines. To analyze the various aspects of the platform and wind turbines, the analysis is drawn from the fields of hydrodynamics, electromagnetics, aerodynamics and control theory. To study the hydrodynamics of the floating platform in incident monochromatic waves, potential theory is utilized, taking into account the slow-drift yaw motion of the platform. Steady, second-order moments that are spatially dependent (i.e., dependent on the platform's yaw orientation relative to the incident waves) are given special attention since there are no natural restoring yaw moment. The aerodynamics of the counter-rotating turbines are studied in collaboration with researchers at the UC Berkeley Mathematics Department using a high-order, implicit, large-eddy simulation. An element flipping technique is utilized to extend the method to a domain with counter-rotating turbines and the effects from the closely-spaced turbines is compared with existing experimental data. Hybrid testing techniques on a model platform are utilized to prove the controllability of the platform in lieu of a wind-wave tank. A 1:82 model-scale floating platform is fabricated and tested at the UC Berkeley Physical-Model Testing Facility. The vertical-axis wind turbines are simulated by spinning, controllable actuators that can be updated in real-time of

  17. Electron transport in a mesoscopic superconducting ferromagnetic hybrid conductor

    Energy Technology Data Exchange (ETDEWEB)

    Giroud, M.; Hasselbach, K.; Courtois, H.; Pannetier, B. [Centre de Recherche sur les Tres Basses Temperatures, CNRS, 38 - Grenoble (France); Mailly, D. [Laboratoire de Photonique et de Nanostructures, 91 - Marcoussis (France)

    2003-01-01

    We present electrical transport experiments performed on submicron hybrid devices made of a ferromagnetic conductor (Co) and a superconducting (Al) electrode. The sample was patterned in order to separate the contributions of the Co conductor and of the Co-Al interface. We observed a strong influence of the Al electrode superconductivity on the resistance of the Co conductor. This effect is large only when the interface is highly transparent. We characterized the dependence of the observed resistance decrease on temperature, bias current and magnetic field. As the differential resistance of the ferromagnet exhibits a non-trivial asymmetry, we claim that the magnetic domain structure plays an important role in the electron transport properties of superconducting / ferromagnetic conductors. (authors)

  18. A platform for in-situ multi-probe electronic measurements and modification of nanodevices inside a transmission electron microscope

    Science.gov (United States)

    Xu, T. T.; Ning, Z. Y.; Shi, T. W.; Fu, M. Q.; Wang, J. Y.; Chen, Q.

    2014-06-01

    We developed a new platform that enables in-situ four-probe electronic measurements, in-situ three-probe field-effect measurements, nanomanipulation, and in-situ modification of nanodevices inside a transmission electron microscope (TEM). The platform includes a specially designed chip-holder and a silicon (Si) chip with suspended metal electrodes. The chip-holder can hold one Si chip with a size up to 3 mm × 3 mm and provides four electrical connections that can be connected to the micrometer-sized electrodes on the Si chip by wire-bonding. The other side of the electrical connections on the chip-holder is connected to the electronic instruments outside the TEM through a commercial Nanofactory SPM-TEM holder. The Si chip with suspended metal electrodes on one of its edges was fabricated by lithography and wet etching. Carbon nanotubes (CNTs), InAs nanowires, and tungsten disulfide nanowires were placed to stride over and connect to the suspended electrodes on the Si chip by nanomanipulations inside a scanning electron microscope (SEM). By using the platform, I-V curves of an individual single-walled CNT connecting to four electrodes were in-situ measured between any two of the four suspended electrodes, and a high-resolution TEM image of the same CNT was obtained. Furthermore, four-terminal I-V measurement on an InAs nanowire was achieved on this platform, and with a movable probe used as a gate electrode, field-effect measurement on the same InAs nanowire device was accomplished in SEM. In addition, by using the movable probe on the SPM-TEM holder, we could further in-situ modify nanomaterial and nanodevices. The present work demonstrates a method that allows a direct correlation between the atomic-level structure and the electronic property of nanomaterials or nanodevices whose structure can be further modified in-situ.

  19. Reactive Microcontact Printing of DNA Probes on (DMA-NAS-MAPS) Copolymer-Coated Substrates for Efficient Hybridization Platforms.

    Science.gov (United States)

    Castagna, Rossella; Bertucci, Alessandro; Prasetyanto, Eko Adi; Monticelli, Marco; Conca, Dario Valter; Massetti, Matteo; Sharma, Parikshit Pratim; Damin, Francesco; Chiari, Marcella; De Cola, Luisa; Bertacco, Riccardo

    2016-04-05

    High-performing hybridization platforms fabricated by reactive microcontact printing of DNA probes are presented. Multishaped PDMS molds are used to covalently bind oligonucleotides over a functional copolymer (DMA-NAS-MAPS) surface. Printed structures with minimum width of about 1.5 μm, spaced by 10 μm, are demonstrated, with edge corrugation lower than 300 nm. The quantification of the immobilized surface probes via fluorescence imaging gives a remarkable concentration of 3.3 × 10(3) oligonucleotides/μm(2), almost totally active when used as probes in DNA-DNA hybridization assays. Indeed, fluorescence and atomic force microscopy show a 95% efficiency in target binding and uniform DNA hybridization over printed areas.

  20. Hybrid LC filter for power electronic drives. Theory and implementation

    Energy Technology Data Exchange (ETDEWEB)

    Dzhankhotov, V.

    2009-07-01

    Power electronic converter drives use, for the sake of high efficiency, pulse-width modulation that results in sequences of high-voltage high-frequency steep-edged pulses. Such a signal contains a set of high harmonics not required for control purposes. Harmonics cause reflections in the cable between the motor and the inverter leading to faster winding insulation ageing. Bearing failures and problems with electromagnetic compatibility may also result. Electrical du/dt filters provide an effective solution to problems caused by pulse-width modulation, thereby increasing the performance and service life of the electrical machines. It is shown that RLC filters effectively decrease the reflection phenomena in the cable. Improved (simple, but effective) solutions are found for both differential- and common-mode signals; these solutions use a galvanic connection between the RLC filter star point and the converter DC link. Foil chokes and film capacitors are among the most widely used components in high-power applications. In actual applications they can be placed in different parts of the cabinet. This fact complicates the arrangement of the cabinet and decreases the reliability of the system. In addition, the inductances of connection wires may prevent filtration at high frequencies. This thesis introduces a new hybrid LC filter that uses a natural capacitance between the turns of the foil choke based on integration of an auxiliary layer into it. The main idea of the hybrid LC filter results from the fact that both the foil choke and the film capacitors have the same roll structure. Moreover, the capacitance between the turns ('intra capacitance') of the foil inductors is the reason for the deterioration of their properties at high frequencies. It is shown that the proposed filter has a natural cancellation of the intra capacitance. A hybrid LC filter may contain two or more foil layers isolated from each other and coiled on a core. The core material can be

  1. Design and Synchronization of Master-Slave Electronic Horizontal Platform System

    Directory of Open Access Journals (Sweden)

    Hang-Hong Kuo

    2012-01-01

    Full Text Available Horizontal platform system (HPS is one of the mechanical systems with rich behavior and has extensively been applied in offshore and earthquake engineering. A corresponding electronic HPS is proposed in this paper to reduce the research cost and time when studying dynamics of the mechanical HPS. Furthermore, an output feedback controller is proposed for global synchronization between coupled electronic HPS systems and its stability condition is also derived by employing the Lyapunov stability theory. The experimental simulations verify the dynamics of the proposed electronic HPS and the synchronization effectiveness of the proposed control scheme.

  2. Reduced density matrix hybrid approach: application to electronic energy transfer.

    Science.gov (United States)

    Berkelbach, Timothy C; Markland, Thomas E; Reichman, David R

    2012-02-28

    Electronic energy transfer in the condensed phase, such as that occurring in photosynthetic complexes, frequently occurs in regimes where the energy scales of the system and environment are similar. This situation provides a challenge to theoretical investigation since most approaches are accurate only when a certain energetic parameter is small compared to others in the problem. Here we show that in these difficult regimes, the Ehrenfest approach provides a good starting point for a dynamical description of the energy transfer process due to its ability to accurately treat coupling to slow environmental modes. To further improve on the accuracy of the Ehrenfest approach, we use our reduced density matrix hybrid framework to treat the faster environmental modes quantum mechanically, at the level of a perturbative master equation. This combined approach is shown to provide an efficient and quantitative description of electronic energy transfer in a model dimer and the Fenna-Matthews-Olson complex and is used to investigate the effect of environmental preparation on the resulting dynamics.

  3. Design and Optimization of OpenFOAM-based CFD Applications for Modern Hybrid and Heterogeneous HPC Platforms

    KAUST Repository

    AlOnazi, Amani A.

    2014-02-01

    The progress of high performance computing platforms is dramatic, and most of the simulations carried out on these platforms result in improvements on one level, yet expose shortcomings of current CFD packages. Therefore, hardware-aware design and optimizations are crucial towards exploiting modern computing resources. This thesis proposes optimizations aimed at accelerating numerical simulations, which are illus- trated in OpenFOAM solvers. A hybrid MPI and GPGPU parallel conjugate gradient linear solver has been designed and implemented to solve the sparse linear algebraic kernel that derives from two CFD solver: icoFoam, which is an incompressible flow solver, and laplacianFoam, which solves the Poisson equation, for e.g., thermal dif- fusion. A load-balancing step is applied using heterogeneous decomposition, which decomposes the computations taking into account the performance of each comput- ing device and seeking to minimize communication. In addition, we implemented the recently developed pipeline conjugate gradient as an algorithmic improvement, and parallelized it using MPI, GPGPU, and a hybrid technique. While many questions of ultimately attainable per node performance and multi-node scaling remain, the ex- perimental results show that the hybrid implementation of both solvers significantly outperforms state-of-the-art implementations of a widely used open source package.

  4. Research on Hybrid Isolation System for Micro-Nano-Fabrication Platform

    Directory of Open Access Journals (Sweden)

    Jie Fu

    2014-06-01

    Full Text Available In order to obtain better vibration suppression effect, this paper designs a semiactive/fully active hybrid isolator by using magnetorheological elastomer (MRE and piezoelectric material. Combined with multimode control scheme, full frequency vibration suppression is achieved. Firstly, series type structure is determined for the hybrid isolator, and the structure of hybrid isolator is designed. Next, the dynamic model of hybrid isolator is derived, the dynamic characteristics measurement for MRE isolator and piezoelectric stack actuator (PSA is established, and parameters such as voltage-displacement coefficient, stiffness and damping constant are identified from the experimental results, respectively. Meanwhile, the switch frequency is determined by experimental results of PSA and MRE isolator. Lastly, influence of the stiffness of MRE, control voltage of PSA, and intermediate mass on hybrid isolator system is analyzed by simulations, and the results show that the hybrid isolator proposed is effective.

  5. Application of a Dot Blot Hybridization Platform to Assess Streptococcus uberis Population Structure in Dairy Herds

    Science.gov (United States)

    Albuquerque, Pedro; Ribeiro, Niza; Almeida, Alexandre; Panschin, Irena; Porfirio, Afonso; Vales, Marta; Diniz, Francisca; Madeira, Helena; Tavares, Fernando

    2017-01-01

    Streptococcus uberis is considered one of the most important pathogens associated with bovine mastitis. While traditionally acknowledged as an environmental pathogen, S. uberis has been shown to adopt a contagious epidemiological pattern in several dairy herds. Since different control strategies are employed depending on the mode of transmission, in-depth studies of S. uberis populations are essential to determine the best practices to control this pathogen. In this work, we optimized and validated a dot blot platform, combined with automatic image analysis, to rapidly assess the population structure of infective S. uberis, and evaluated its efficiency when compared to multilocus sequence analysis (MLSA) genotyping. Two dairy herds with prevalent S. uberis infections were followed in a 6 month period, in order to collect and characterize isolates from cows with persistent infections. These herds, located in Portugal (Barcelos and Maia regions), had similar management practices, with the herd from Barcelos being smaller and having a better milking parlor management, since infected cow segregation was immediate. A total of 54 S. uberis isolates were obtained from 24 different cows from the two herds. To overcome operator-dependent analysis of the dot blots and increase the technique's consistency and reliability, the hybridization signals were converted into probability values, with average probabilities higher than 0.5 being considered positive results. These data allowed to confirm the isolates' identity as S. uberis using taxa-specific markers and to determine the presence of virulence- and antibiotic resistance-related genes. In addition, MLSA allowed to disclose the most prevalent S. uberis clonal lineages in both herds. Seven different clusters were identified, with Barcelos showing a high clonal diversity and Maia a dominant lineage infecting most cows, suggesting distinct epidemiological patterns, with S. uberis displaying an environmental or contagious

  6. Lower hybrid current drive favoured by electron cyclotron radiofrequency heating

    Energy Technology Data Exchange (ETDEWEB)

    Cesario, R.; Cardinali, A.; Castaldo, C.; Marinucci, M.; Tuccillo, A. A. [Associazione EURATOM/ENEA sulla Fusione, Centro Ricerche Frascati, 00044, Frascati (Italy); Amicucci, L.; Galli, A. [Università di Roma Sapienza, Dipartimento Ingegneria Elettronica, Rome (Italy); Giruzzi, G. [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France); Napoli, F.; Schettini, G. [Università di Roma Tre, Dipartimento Ingegneria Elettronica, Rome (Italy)

    2014-02-12

    The important goal of adding to the bootstrap a fraction of non-inductive plasma current, which would be controlled for obtaining and optimizing steady-state profiles, can be reached by using the Current Drive produced by Lower Hybrid waves (LHCD). FTU (Frascati Tokamak Upgrade) experiments demonstrated, indeed, that LHCD is effective at reactor-graded high plasma density, and the LH spectral broadening is reduced, operating with higher electron temperature in the outer region of plasma column (T{sub e-periphery}). This method was obtained following the guidelines of theoretical predictions indicating that the broadening of launched spectrum produced by parametric instability (PI) should be reduced, and the LHCD effect at high density consequently enabled, under higher (T{sub e-periphery}). In FTU, the temperature increase in the outer plasma region was obtained by operating with reduced particle recycling, lithized walls and deep gas fuelling by means of fast pellet. Heating plasma periphery with electron cyclotron resonant waves (ECRH) will provide a further tool for achieving steady-state operations. New FTU experimental results are presented here, demonstrating that temperature effect at the plasma periphery, affecting LH penetration, occurs in a range of plasma parameters broader than in previous work. New information is also shown on the modelling assessing frequencies and growth rates of the PI coupled modes responsible of spectral broadening. Finally, we present the design of an experiment scheduled on FTU next campaign, where ECRH power is used to slightly increase the electron temperature in the outer plasma region of a high-density discharge aiming at restoring LHCD. Consequent to model results, by operating with a toroidal magnetic field of 6.3 T, useful for locating the electron cyclotron resonant layer at the periphery of the plasma column (r/a∼0.8, f{sub 0}=144 GHz), an increase of T{sub e} in the outer plasma (from 40 eV to 80 eV at r/a∼0.8) is

  7. The electronics hybrid of the ATLAS-SCT endcap detector modules

    CERN Document Server

    Ketterer, C

    2004-01-01

    An electronics hybrid has been developed for the ATLAS silicon microstrip tracker endcaps. The high-density interconnect board carries 12 readout ASICs, as well as ASICs for the optical data transmission. Special requirements are that this hybrid has to be double sided, radiation hard, and low mass. A six-layer flexible circuit in copper-polyimide technology has been chosen for this purpose. It is folded around a highly heat conducting carbon-carbon composite substrate to form the rigid double-sided hybrid. Adequate thermal, mechanical, and electrical performance of the hybrid has been demonstrated. The production of the hybrids started in May 2003. (12 refs).

  8. E-learning platform for automated testing of electronic circuits using signature analysis method

    Science.gov (United States)

    Gherghina, Cǎtǎlina; Bacivarov, Angelica; Bacivarov, Ioan C.; Petricǎ, Gabriel

    2016-12-01

    Dependability of electronic circuits can be ensured only through testing of circuit modules. This is done by generating test vectors and their application to the circuit. Testability should be viewed as a concerted effort to ensure maximum efficiency throughout the product life cycle, from conception and design stage, through production to repairs during products operating. In this paper, is presented the platform developed by authors for training for testability in electronics, in general and in using signature analysis method, in particular. The platform allows highlighting the two approaches in the field namely analog and digital signature of circuits. As a part of this e-learning platform, it has been developed a database for signatures of different electronic components meant to put into the spotlight different techniques implying fault detection, and from this there were also self-repairing techniques of the systems with this kind of components. An approach for realizing self-testing circuits based on MATLAB environment and using signature analysis method is proposed. This paper analyses the benefits of signature analysis method and simulates signature analyzer performance based on the use of pseudo-random sequences, too.

  9. Hybrid Microfluidic Platform for Multifactorial Analysis Based on Electrical Impedance, Refractometry, Optical Absorption and Fluorescence

    National Research Council Canada - National Science Library

    Pereira, Fábio; Bernacka-Wojcik, Iwona; Ribeiro, Rita; Lobato, Maria; Fortunato, Elvira; Martins, Rodrigo; Igreja, Rui; Jorge, Pedro; Águas, Hugo; Oliva, Abel

    2016-01-01

    ...: electrical impedance, refractometry, optical absorption and fluorescence. We present the rationale for the design and the details of the microfabrication of this multifactorial hybrid microfluidic chip...

  10. Hybrid additive manufacturing of 3D electronic systems

    Science.gov (United States)

    Li, J.; Wasley, T.; Nguyen, T. T.; Ta, V. D.; Shephard, J. D.; Stringer, J.; Smith, P.; Esenturk, E.; Connaughton, C.; Kay, R.

    2016-10-01

    A novel hybrid additive manufacturing (AM) technology combining digital light projection (DLP) stereolithography (SL) with 3D micro-dispensing alongside conventional surface mount packaging is presented in this work. This technology overcomes the inherent limitations of individual AM processes and integrates seamlessly with conventional packaging processes to enable the deposition of multiple materials. This facilitates the creation of bespoke end-use products with complex 3D geometry and multi-layer embedded electronic systems. Through a combination of four-point probe measurement and non-contact focus variation microscopy, it was identified that there was no obvious adverse effect of DLP SL embedding process on the electrical conductivity of printed conductors. The resistivity maintained to be less than 4  ×  10-4 Ω · cm before and after DLP SL embedding when cured at 100 °C for 1 h. The mechanical strength of SL specimens with thick polymerized layers was also identified through tensile testing. It was found that the polymerization thickness should be minimised (less than 2 mm) to maximise the bonding strength. As a demonstrator a polymer pyramid with embedded triple-layer 555 LED blinking circuitry was successfully fabricated to prove the technical viability.

  11. One- and many-electron self-interaction error in local and global hybrid functionals

    Science.gov (United States)

    Schmidt, Tobias; Kümmel, Stephan

    2016-04-01

    Electronic self-interaction poses a fundamental challenge in density-functional theory. It greatly limits, e.g., the physical interpretation of eigenvalues as electron removal energies. We here investigate whether local hybrid functionals that are designed to be free from one-electron self-interaction lead to occupied Kohn-Sham eigenvalues and orbitals that approximate photoemission observables well. We compare the local hybrid results to the ones from global hybrid functionals that only partially counteract the self-interaction, and to the results that are obtained with a Perdew-Zunger-type self-interaction correction. Furthermore, we check whether being nominally free from one-electron self-interaction translates into a reduced many-electron self-interaction error. Our findings show that this is not the case for the local hybrid functionals that we studied: In practice they are similar to global hybrids in many respects, despite being formally superior. This finding indicates that there is a conceptual difference between the Perdew-Zunger way and the local hybrid way of translating the one-electron condition to a many-electron system. We also point out and solve some difficulties that occur when using local hybrid functionals in combination with pseudopotentials.

  12. A novel hybrid plasmonic waveguide with loss compensation via electrically pumped gain medium based on silicon platform

    Science.gov (United States)

    Zhu, Ning

    2013-01-01

    In this paper we propose and study a new hybrid plasmonic waveguide structure with gain medium. The structure is based on silicon platform with gain medium to be III-V material, which can be electrically pumped. The whole structure can be realized through the bonding technique. An adhesive polymer layer adopted in the bonding process acts as the low refractive index layer here in the hybrid plasmonic waveguide. Further simulation with gain presented shows that a moderate gain coefficient of 891 cm-1 is required for lossless propagation while keeping subwavelength modal size, especially in the lateral direction which is important for high density integration. Considering the fabrication compatibility, this new SPP structure would be highly favorable in the silicon photonics.

  13. Preparation of Graphene/Gold Nano-Hybrid Using Diamine Linker as Effective Surface-Enhanced Raman Scattering Platforms.

    Science.gov (United States)

    Yoon, Sang Su; Lee, Wonoh; Byun, Joon Hyung; Lee, Jea Uk

    2015-11-01

    Development of simple and efficient method for the large-scale production of gaphene/metal nanoparticle hybrids is highly desirable for practical applications, such as catalyst, energy generation and storage, optoelectronics, and sensors. Here, we present a facile approach for the preparation of graphene/gold nanoparticle (AuNP) hybrids by simply mixing the functionalized graphene oxide and AuNPs in aqueous media. Among various functionalized graphene sheets, amine-functionalized graphene oxide (GO-NH2) is used as the hybrid platform due to its synthetic convenience, good dispersity, scalable production with low cost, and positive charge on the surfacce, which could immobilize the AuNPs on the graphene sheets via electrostatic interaction. The synthesized graphene/AgNP hybrids show high surface-enhanced Raman scattering (SERS) sensitivity due to the combined effects of the high contents of amine functional groups on the GO-NH2 surface to adsorb more AgNPs and the electromagnetic enhancement of AgNPs.

  14. Hybrid fluorescence and electron cryo-microscopy for simultaneous electron and photon imaging.

    Science.gov (United States)

    Iijima, Hirofumi; Fukuda, Yoshiyuki; Arai, Yoshihiro; Terakawa, Susumu; Yamamoto, Naoki; Nagayama, Kuniaki

    2014-01-01

    Integration of fluorescence light and transmission electron microscopy into the same device would represent an important advance in correlative microscopy, which traditionally involves two separate microscopes for imaging. To achieve such integration, the primary technical challenge that must be solved regards how to arrange two objective lenses used for light and electron microscopy in such a manner that they can properly focus on a single specimen. To address this issue, both lateral displacement of the specimen between two lenses and specimen rotation have been proposed. Such movement of the specimen allows sequential collection of two kinds of microscopic images of a single target, but prevents simultaneous imaging. This shortcoming has been made up by using a simple optical device, a reflection mirror. Here, we present an approach toward the versatile integration of fluorescence and electron microscopy for simultaneous imaging. The potential of simultaneous hybrid microscopy was demonstrated by fluorescence and electron sequential imaging of a fluorescent protein expressed in cells and cathodoluminescence imaging of fluorescent beads. Copyright © 2013 Elsevier Inc. All rights reserved.

  15. The ASTRA Toolbox: A platform for advanced algorithm development in electron tomography

    Energy Technology Data Exchange (ETDEWEB)

    Aarle, Wim van, E-mail: wim.vanaarle@uantwerpen.be [iMinds-Vision Lab, University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk (Belgium); Palenstijn, Willem Jan, E-mail: willemjan.palenstijn@uantwerpen.be [iMinds-Vision Lab, University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk (Belgium); Centrum Wiskunde & Informatica, Science Park 123, NL-1098 XG Amsterdam (Netherlands); De Beenhouwer, Jan, E-mail: jan.debeenhouwer@uantwerpen.be [iMinds-Vision Lab, University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk (Belgium); Altantzis, Thomas, E-mail: thomas.altantzis@uantwerpen.be [Electron Microscopy for Materials Science, University of Antwerp, Groenenborgerlaan 171, B-2020 Wilrijk (Belgium); Bals, Sara, E-mail: sara.bals@uantwerpen.be [Electron Microscopy for Materials Science, University of Antwerp, Groenenborgerlaan 171, B-2020 Wilrijk (Belgium); Batenburg, K. Joost, E-mail: joost.batenburg@cwi.nl [iMinds-Vision Lab, University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk (Belgium); Centrum Wiskunde & Informatica, Science Park 123, NL-1098 XG Amsterdam (Netherlands); Mathematical Institute, Leiden University, P.O. Box 9512, NL-2300 RA Leiden (Netherlands); Sijbers, Jan, E-mail: jan.sijbers@uantwerpen.be [iMinds-Vision Lab, University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk (Belgium)

    2015-10-15

    We present the ASTRA Toolbox as an open platform for 3D image reconstruction in tomography. Most of the software tools that are currently used in electron tomography offer limited flexibility with respect to the geometrical parameters of the acquisition model and the algorithms used for reconstruction. The ASTRA Toolbox provides an extensive set of fast and flexible building blocks that can be used to develop advanced reconstruction algorithms, effectively removing these limitations. We demonstrate this flexibility, the resulting reconstruction quality, and the computational efficiency of this toolbox by a series of experiments, based on experimental dual-axis tilt series. - Highlights: • The ASTRA Toolbox is an open platform for 3D image reconstruction in tomography. • Advanced reconstruction algorithms can be prototyped using the fast and flexible building blocks. • This flexibility is demonstrated on a common use case: dual-axis tilt series reconstruction with prior knowledge. • The computational efficiency is validated on an experimentally measured tilt series.

  16. AuTom: a novel automatic platform for electron tomography reconstruction

    KAUST Repository

    Han, Renmin

    2017-07-26

    We have developed a software package towards automatic electron tomography (ET): Automatic Tomography (AuTom). The presented package has the following characteristics: accurate alignment modules for marker-free datasets containing substantial biological structures; fully automatic alignment modules for datasets with fiducial markers; wide coverage of reconstruction methods including a new iterative method based on the compressed-sensing theory that suppresses the “missing wedge” effect; and multi-platform acceleration solutions that support faster iterative algebraic reconstruction. AuTom aims to achieve fully automatic alignment and reconstruction for electron tomography and has already been successful for a variety of datasets. AuTom also offers user-friendly interface and auxiliary designs for file management and workflow management, in which fiducial marker-based datasets and marker-free datasets are addressed with totally different subprocesses. With all of these features, AuTom can serve as a convenient and effective tool for processing in electron tomography.

  17. Arsenic removal from contaminated groundwater by membrane-integrated hybrid plant: optimization and control using Visual Basic platform.

    Science.gov (United States)

    Chakrabortty, S; Sen, M; Pal, P

    2014-03-01

    A simulation software (ARRPA) has been developed in Microsoft Visual Basic platform for optimization and control of a novel membrane-integrated arsenic separation plant in the backdrop of absence of such software. The user-friendly, menu-driven software is based on a dynamic linearized mathematical model, developed for the hybrid treatment scheme. The model captures the chemical kinetics in the pre-treating chemical reactor and the separation and transport phenomena involved in nanofiltration. The software has been validated through extensive experimental investigations. The agreement between the outputs from computer simulation program and the experimental findings are excellent and consistent under varying operating conditions reflecting high degree of accuracy and reliability of the software. High values of the overall correlation coefficient (R (2) = 0.989) and Willmott d-index (0.989) are indicators of the capability of the software in analyzing performance of the plant. The software permits pre-analysis, manipulation of input data, helps in optimization and exhibits performance of an integrated plant visually on a graphical platform. Performance analysis of the whole system as well as the individual units is possible using the tool. The software first of its kind in its domain and in the well-known Microsoft Excel environment is likely to be very useful in successful design, optimization and operation of an advanced hybrid treatment plant for removal of arsenic from contaminated groundwater.

  18. Hybrid silicon evanescent devices

    Directory of Open Access Journals (Sweden)

    Alexander W. Fang

    2007-07-01

    Full Text Available Si photonics as an integration platform has recently been a focus of optoelectronics research because of the promise of low-cost manufacturing based on the ubiquitous electronics fabrication infrastructure. The key challenge for Si photonic systems is the realization of compact, electrically driven optical gain elements. We review our recent developments in hybrid Si evanescent devices. We have demonstrated electrically pumped lasers, amplifiers, and photodetectors that can provide a low-cost, scalable solution for hybrid integration on a Si platform by using a novel hybrid waveguide architecture, consisting of III-V quantum wells bonded to Si waveguides.

  19. Fast electron dynamics in lower hybrid current drive experiment on HT-7 tokamak

    Institute of Scientific and Technical Information of China (English)

    Shi Yue-Jiang; Kuang Gang-Li; Li Jian-Gang; HT-7 Team; Wan Bao-Nian; Chen Zhong-Yong; Hu Li-Qun; Lin Shi-Yao; Ruan Huai-Lin; Qian Jin-Ping; Zhen Xiang-Jun; Ding Bo-Jiang

    2005-01-01

    The dynamic behaviour of fast electron in lower hybrid current drive (LHCD) experiments is a crucial issue in the sense of enhancing plasma performance. A new hard x-ray diagnostic system on HT-7 allows the investigation of the lower hybrid wave dynamics. The behaviour of fast electron is studied in several kinds of LHCD experiments, including long pulse discharges, high performance discharges and counter-LHCD experiments.

  20. Design and Implementation of an Automated Management Platform for P2P Transactions with Electronic Money

    Directory of Open Access Journals (Sweden)

    Andrés Alcocer

    2016-03-01

    Full Text Available Electronic money is a payment tool implemented by the Ecuador’s Central Bank, it allows people to make commercial transactions using their cellphones; it can be used to pay into big chain stores like supermarkets, known as "macro agents", but it also can be employed for the consumption of goods and services into particular businesses such as restaurants or small shops by using “person to person” transfers known as P2P. However, the particular businesses present some disadvantages compared to the macro agents, the main one is the lack of a system that allows them to have a record of the transactions made with electronic money. This article details the design and implementation of a technological platform that allows all types of businesses and people to keep records of their P2P transactions into an automated system with the ability of generating payment’s balance sheets which can be easily viewed through Internet. A research was conducted in order to look for the most efficient technical solution to optimize the available resources. The use of this platform as an external tool extends the capabilities currently provided by the electronic money system.

  1. Metal-Semiconductor Nanoparticle Hybrids Formed by Self-Organization: A Platform to Address Exciton-Plasmon Coupling.

    Science.gov (United States)

    Strelow, Christian; Theuerholz, T Sverre; Schmidtke, Christian; Richter, Marten; Merkl, Jan-Philip; Kloust, Hauke; Ye, Ziliang; Weller, Horst; Heinz, Tony F; Knorr, Andreas; Lange, Holger

    2016-08-10

    Hybrid nanosystems composed of excitonic and plasmonic constituents can have different properties than the sum of of the two constituents, due to the exciton-plasmon interaction. Here, we report on a flexible model system based on colloidal nanoparticles that can form hybrid combinations by self-organization. The system allows us to tune the interparticle distance and to combine nanoparticles of different sizes and thus enables a systematic investigation of the exciton-plasmon coupling by a combination of optical spectroscopy and quantum-optical theory. We experimentally observe a strong influence of the energy difference between exciton and plasmon, as well as an interplay of nanoparticle size and distance on the coupling. We develop a full quantum theory for the luminescence dynamics and discuss the experimental results in terms of the Purcell effect. As the theory describes excitation as well as coherent and incoherent emission, we also consider possible quantum optical effects. We find a good agreement of the observed and the calculated luminescence dynamics induced by the Purcell effect. This also suggests that the self-organized hybrid system can be used as platform to address quantum optical effects.

  2. Biodynsensing: Sensing Through Dynamics of Hybrid Affinity/Cellular Platforms; Towards Appraisal of Environmental and Biological Risks of Nanobiotechnology

    Science.gov (United States)

    Gheorghiu, E.; Gheorghiu, M.; David, S.; Polonschii, C.

    Chemical cues and nano-topographies present on the surface or in the extracellular medium strongly influence the fate and adhesion of biological cells. Careful tuning of cell—matrix interaction via engineered surfaces, either attractive or repulsive, require non-invasive, long time monitoring capabilities and lay the foundation of sensing platforms for risk assessment. Aiming to assess changes underwent by biointerfaces due to cell—environment interaction (in particular nanotechnology products), we have developed hybrid cellular platforms allowing for time based dual assays, i.e., impedance/dielectric spectroscopy (IS) and Surface Plasmon Resonance (SPR). Such platforms comprising Flow Injection Analysis (FIA) have been advanced to assess the interaction between selected (normal and malignant) cells and nano-patterned and/or chemically modified surfaces, as well as the impact of engineered nanoparticles, revealed by the related changes exhibited by cell membrane, morphology, adhesion and monolayer integrity. Besides experimental aspects dealing with measurement set-up, we will emphasize theoretical aspects related to: dielectric modeling. Aiming for a quantitative approach, microscopic models on dielectric behavior of ensembles of interconnected cells have been developed and their capabilities will be outlined within the presentation. Assessment of affinity reactions as revealed by dielectric/impedance assays of biointerfaces. Modeling the dynamics of the impedance in relation to the “quality” of cell layer and sensor's active surface, this study presents further developments of our approach described in Analytical Chemistry, 2002. Data analysis. This issue is related to the following basic question: Are there “simple” Biosensing Platforms? When coping with cellular platforms, either in suspension or immobilized (on filters, adhered on surfaces or entrapped, e.g., on using set-ups) there is an intrinsic nonlinear behavior of biological systems related

  3. Development of Power Electronics Based Test Platform for Characterization and Testing of Magnetocaloric Materials

    Directory of Open Access Journals (Sweden)

    Deepak Elamalayil Soman

    2015-01-01

    Full Text Available Magnetocaloric effects of various materials are getting more and more interesting for the future, as they can significantly contribute towards improving the efficiency of many energy intensive applications such as refrigeration, heating, and air conditioning. Accurate characterization of magnetocaloric effects, exhibited by various materials, is an important process for further studies and development of the suitable magnetocaloric heating and cooling solutions. The conventional test facilities have plenty of limitations, as they focus only on the thermodynamic side and use magnetic machines with moving bed of magnetocaloric material or magnet. In this work an entirely new approach for characterization of the magnetocaloric materials is presented, with the main focus on a flexible and efficient power electronic based excitation and a completely static test platform. It can generate a periodically varying magnetic field using superposition of an ac and a dc magnetic field. The scale down prototype uses a customized single phase H-bridge inverter with essential protections and an electromagnet load as actuator. The preliminary simulation and experimental results show good agreement and support the usage of the power electronic test platform for characterizing magnetocaloric materials.

  4. Redox-active thionine-graphene oxide hybrid nanosheet: One-pot, rapid synthesis, and application as a sensing platform for uric acid

    Energy Technology Data Exchange (ETDEWEB)

    Sun Zhoumin; Fu Haiying [Key Laboratory of Resources Chemistry of Nonferrous Metals, Ministry of Education, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan (China); Deng Liu, E-mail: dengliu@csu.edu.cn [Key Laboratory of Resources Chemistry of Nonferrous Metals, Ministry of Education, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan (China); Wang Jianxiu [Key Laboratory of Resources Chemistry of Nonferrous Metals, Ministry of Education, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan (China)

    2013-01-25

    Highlights: Black-Right-Pointing-Pointer A simple wet-chemical strategy for synthesis of thionine-graphene oxide hybrid nanosheets (T-GOs). Black-Right-Pointing-Pointer T-GOs serve as a biocompatible matrix for enzyme assembly and a mediator. Black-Right-Pointing-Pointer A simple and effective sensor for assay of uric acid at physiological levels. Black-Right-Pointing-Pointer Demonstrate further application of GOs for biosensors and other fields. - Abstract: In this paper, we fabricate a sensitive and stable amperometric UA amperometric biosensor using nanobiocomposite derived from thionine modified graphene oxide in this study. A simple wet-chemical strategy for synthesis of thionine-graphene oxide hybrid nanosheets (T-GOs) through {pi}-{pi} stacking has been demonstrated. Various techniques, such as UV-vis absorption spectroscopy, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), atomic force microscopy (AFM) and electrochemistry have been utilized to characterize the formation of the T-GOs. Due to the synergistic effect between thionine and graphene oxide, the nanosheets exhibited excellent performance toward H{sub 2}O{sub 2} reduction. The incorporation of thionine onto graphene oxide surface resulted in more than a twice increase in the amperometric response to H{sub 2}O{sub 2} of the thionine modified electrode. The as-formed T-GOs also served as a biocompatible matrix for enzyme assembly and a mediator to facilitate the electron transfer between the enzyme and the electrode. Using UOx as a model system, we have developed a simple and effective sensing platform for assay of uric acid at physiological levels. UA has been successfully detected at -0.1 V without any interference due to other electroactive compounds at physiological levels of glucose (5 mM), ascorbic acid (0.1 mM), noradrenalin (0.1 mM), and dopamine (0.1 mM). The response displays a good linear range from 0.02 to 4.5 mM with detection limit 7 {mu}M. The application

  5. Simulating Strongly Correlated Electron Systems with Hybrid Monte Carlo

    Institute of Scientific and Technical Information of China (English)

    LIU Chuan

    2000-01-01

    Using the path integral representation, the Hubbard and the periodic Anderson model on D-dimensional cubic lattice are transformed into field theories of fermions in D + 1 dimensions. These theories at half-filling possess a positive definite real symmetry fermion matrix and can be simulated using the hybrid Monte Carlo method.

  6. Offshore energy structures for wind power, wave energy and hybrid marine platforms

    CERN Document Server

    Karimirad, Madjid

    2014-01-01

    This book provides all the key information needed to design offshore structures for renewable energy applications successfully. Suitable for practicing engineers and students, the author conveys design principles and best practices in a clear, concise manner, focusing on underlying physics while eschewing complicated mathematical detail. The text connects underlying scientific theory with industry standards and practical implementation issues for offshore wind turbines, wave energy converters and current turbines. Combined concepts such as wave-wind energy platforms are discussed, as well. Cov

  7. Quasi-analytical solutions of hybrid platform and the optimization of highly sensitive thin-film sensors for terahertz radiation

    CERN Document Server

    Tapsanit, Piyawath; Ishihara, Teruya; Otani, Chiko

    2016-01-01

    We present quasi-analytical solutions (QANS) of hybrid platform (HP) comprising metallic grating (MG) and stacked-dielectric layers for terahertz (THz) radiation. The QANS are validated by finite difference time domain simulation. It is found that the Wood anomalies induce the high-order spoof surface plasmon resonances in the HP. The QANS are applied to optimize new perfect absorber for THz sensing of large-area thin film with ultrahigh figure of merit reaching fifth order of magnitude for the film thickness 0.0001p (p: MG period). The first-order Wood's anomaly of the insulator layer and the Fabry-Perot in the slit's cavity account for the resonance of the perfect absorber. The QANS and the new perfect absorber may lead to highly sensitive and practical nano-film refractive index sensor for THz radiation.

  8. Protein-Metal Organic Framework Hybrid Composites with Intrinsic Peroxidase-like Activity as a Colorimetric Biosensing Platform.

    Science.gov (United States)

    Yin, Yuqing; Gao, Chen Ling; Xiao, Qi; Lin, Guo; Lin, Zian; Cai, Zongwei; Yang, Huang-Hao

    2016-10-04

    Artificial enzyme mimetics have received considerable attention because natural enzymes have some significant drawbacks, including enzyme autolysis, low catalytic activity, poor recovery and low stability to environmental changes. Herein, we demonstrated a facile approach for one-pot synthesis of hemeprotein-metal organic framework hybrid composites (H-MOFs) by using bovine hemoglobin (BHb) and zeolitic imidazolate framework-8 (ZIF-8) as a model reaction system. Surprisingly, the new hybrid composites exhibits 423% increase in peroxidase-like catalytic activity compared to free BHb. Taking advantages of the unique pore structure of H-MOFs with high catalytic property, a H-MOFs-based colorimetric biosensing platform was newly constructed and applied for the fast and sensitive detection of hydrogen peroxide (H2O2) and phenol. The corresponding detection limits as low as 1.0 μM for each analyte with wide linear ranges (0-800 μM for H2O2 and 0-200 μM for phenol) were obtained by naked-eye visualization. Significantly, sensitive and selective method for visual assay of trace H2O2 in cell and phenol in sewage was achieved with this platform. The stability of H-MOFs was also examined and excellent reproducibility and recyclability without losing in its activity were observed. In addition, the general applicability of H-MOFs was also investigated by using other hemeproteins (horseradish peroxidase, and myoglobin) and the corresponding catalytic activities were 291% and 273% enhancement, respectively. This present work not only expands the application of MOFs, but also provides an alternative technique for biological and environmental sample assay.

  9. Slow electron energy balance for hybrid models of direct-current glow discharges

    Science.gov (United States)

    Eliseev, S. I.; Bogdanov, E. A.; Kudryavtsev, A. A.

    2017-09-01

    In this paper, we present the formulation of slow electron energy balance for hybrid models of direct current (DC) glow discharge. Electrons originating from non-local ionization (secondary) contribute significantly to the energy balance of slow electrons. An approach towards calculating effective energy brought by a secondary electron to the group of slow electrons by means of Coulomb collisions is suggested. The value of effective energy shows a considerable dependence on external parameters of a discharge, such as gas pressure, type, and geometric parameters. The slow electron energy balance was implemented into a simple hybrid model that uses analytical formulation for the description of non-local ionization by fast electrons. Simulations of short (without positive column) DC glow discharge in argon are carried out for a range of gas pressures. Comparison with experimental data showed generally good agreement in terms of current-voltage characteristics, electron density, and electron temperature. Simulations also capture the trend of increasing electron density with decreasing pressure observed in the experiment. Analysis shows that for considered conditions, the product of maximum electron density ne and electron temperature Te in negative glow is independent of gas pressure and depends on the gas type, cathode material, and discharge current. Decreasing gas pressure reduces the heating rate of slow electrons during Coulomb collisions with secondary electrons, which leads to lower values of Te and, in turn, higher maximum ne.

  10. Bioresponsive antisense DNA gold nanobeacons as a hybrid in vivo theranostics platform for the inhibition of cancer cells and metastasis

    Science.gov (United States)

    Bao, Chenchen; Conde, João; Curtin, James; Artzi, Natalie; Tian, Furong; Cui, Daxiang

    2015-07-01

    Gold nanobeacons can be used as a powerful tool for cancer theranostics. Here, we proposed a nanomaterial platform based on gold nanobeacons to detect, target and inhibit the expression of a mutant Kras gene in an in vivo murine gastric cancer model. The conjugation of fluorescently-labeled antisense DNA hairpin oligonucleotides to the surface of gold nanoparticles enables using their localized surface plasmon resonance properties to directly track the delivery to the primary gastric tumor and to lung metastatic sites. The fluorescently labeled nanobeacons reports on the interaction with the target as the fluorescent Cy3 signal is quenched by the gold nanoparticle and only emit light following conjugation to the Kras target owing to reorganization and opening of the nanobeacons, thus increasing the distance between the dye and the quencher. The systemic administration of the anti-Kras nanobeacons resulted in approximately 60% tumor size reduction and a 90% reduction in tumor vascularization. More important, the inhibition of the Kras gene expression in gastric tumors prevents the occurrence of metastasis to lung (80% reduction), increasing mice survival in more than 85%. Our developed platform can be easily adjusted to hybridize with any specific target and provide facile diagnosis and treatment for neoplastic diseases.

  11. Tunable hybridization of electronic states of graphene and a metal surface

    OpenAIRE

    Gruneis, Alexander; Vyalikh, Denis

    2008-01-01

    We present an approach to monitor and control the strength of the hybridization between electronic states of graphene and metal surfaces. Inspecting the distribution of the $\\pi$ band in a high-quality graphene layer synthesized on Ni(111) by angle-resolved photoemission, we observe a new "kink" feature which indicates a strong hybridization between $\\pi$ and \\textit{d} states of graphene and nickel, respectively. Upon deposition and gradual intercalation of potassium atoms into the graphene/...

  12. Polymer-metal hybrid transparent electrodes for flexible electronics

    National Research Council Canada - National Science Library

    Kang, Hongkyu; Jung, Suhyun; Jeong, Soyeong; Kim, Geunjin; Lee, Kwanghee

    2015-01-01

    Despite nearly two decades of research, the absence of ideal flexible and transparent electrodes has been the largest obstacle in realizing flexible and printable electronics for future technologies...

  13. Robotics-assisted mass spectrometry assay platform enabled by open-source electronics.

    Science.gov (United States)

    Chiu, Shih-Hao; Urban, Pawel L

    2015-02-15

    Mass spectrometry (MS) is an important analytical technique with numerous applications in clinical analysis, biochemistry, environmental analysis, geology and physics. Its success builds on the ability of MS to determine molecular weights of analytes, and elucidate their structures. However, sample handling prior to MS requires a lot of attention and labor. In this work we were aiming to automate processing samples for MS so that analyses could be conducted without much supervision of experienced analysts. The goal of this study was to develop a robotics and information technology-oriented platform that could control the whole analysis process including sample delivery, reaction-based assay, data acquisition, and interaction with the analyst. The proposed platform incorporates a robotic arm for handling sample vials delivered to the laboratory, and several auxiliary devices which facilitate and secure the analysis process. They include: multi-relay board, infrared sensors, photo-interrupters, gyroscopes, force sensors, fingerprint scanner, barcode scanner, touch screen panel, and internet interface. The control of all the building blocks is achieved through implementation of open-source electronics (Arduino), and enabled by custom-written programs in C language. The advantages of the proposed system include: low cost, simplicity, small size, as well as facile automation of sample delivery and processing without the intervention of the analyst. It is envisaged that this simple robotic system may be the forerunner of automated laboratories dedicated to mass spectrometric analysis of biological samples.

  14. The Analytic Information Warehouse (AIW): a platform for analytics using electronic health record data.

    Science.gov (United States)

    Post, Andrew R; Kurc, Tahsin; Cholleti, Sharath; Gao, Jingjing; Lin, Xia; Bornstein, William; Cantrell, Dedra; Levine, David; Hohmann, Sam; Saltz, Joel H

    2013-06-01

    To create an analytics platform for specifying and detecting clinical phenotypes and other derived variables in electronic health record (EHR) data for quality improvement investigations. We have developed an architecture for an Analytic Information Warehouse (AIW). It supports transforming data represented in different physical schemas into a common data model, specifying derived variables in terms of the common model to enable their reuse, computing derived variables while enforcing invariants and ensuring correctness and consistency of data transformations, long-term curation of derived data, and export of derived data into standard analysis tools. It includes software that implements these features and a computing environment that enables secure high-performance access to and processing of large datasets extracted from EHRs. We have implemented and deployed the architecture in production locally. The software is available as open source. We have used it as part of hospital operations in a project to reduce rates of hospital readmission within 30days. The project examined the association of over 100 derived variables representing disease and co-morbidity phenotypes with readmissions in 5years of data from our institution's clinical data warehouse and the UHC Clinical Database (CDB). The CDB contains administrative data from over 200 hospitals that are in academic medical centers or affiliated with such centers. A widely available platform for managing and detecting phenotypes in EHR data could accelerate the use of such data in quality improvement and comparative effectiveness studies. Copyright © 2013 Elsevier Inc. All rights reserved.

  15. The SMART Platform: early experience enabling substitutable applications for electronic health records.

    Science.gov (United States)

    Mandl, Kenneth D; Mandel, Joshua C; Murphy, Shawn N; Bernstam, Elmer Victor; Ramoni, Rachel L; Kreda, David A; McCoy, J Michael; Adida, Ben; Kohane, Isaac S

    2012-01-01

    The Substitutable Medical Applications, Reusable Technologies (SMART) Platforms project seeks to develop a health information technology platform with substitutable applications (apps) constructed around core services. The authors believe this is a promising approach to driving down healthcare costs, supporting standards evolution, accommodating differences in care workflow, fostering competition in the market, and accelerating innovation. The Office of the National Coordinator for Health Information Technology, through the Strategic Health IT Advanced Research Projects (SHARP) Program, funds the project. The SMART team has focused on enabling the property of substitutability through an app programming interface leveraging web standards, presenting predictable data payloads, and abstracting away many details of enterprise health information technology systems. Containers--health information technology systems, such as electronic health records (EHR), personally controlled health records, and health information exchanges that use the SMART app programming interface or a portion of it--marshal data sources and present data simply, reliably, and consistently to apps. The SMART team has completed the first phase of the project (a) defining an app programming interface, (b) developing containers, and (c) producing a set of charter apps that showcase the system capabilities. A focal point of this phase was the SMART Apps Challenge, publicized by the White House, using http://www.challenge.gov website, and generating 15 app submissions with diverse functionality. Key strategic decisions must be made about the most effective market for further disseminating SMART: existing market-leading EHR vendors, new entrants into the EHR market, or other stakeholders such as health information exchanges.

  16. Preparation and property of a novel soluble electron transport POSS-based hybrid material

    Institute of Scientific and Technical Information of China (English)

    Xin Wang; Juan Shen; Jin Cui Wu; Min Fang; Hong Yao Xu

    2008-01-01

    A novel POSS-based organic/inorganic hybrid covalently attached at molecular level, 2-(4-(allyloxy)phenyl)-5-(4-(octyloxy)phenyl)-1,3,4-oxadiazole-POSS (6) (abbreviated as oxadiazole-POSS) was synthesized by Pt (dcp) catalyst. The hybrid was soluble in common organic solvents such as CHCl3, toluene, C2H4Cl2, and THF. Its structures and properties were characterized and evaluated with FTIR, 1H NMR, 13C NMR, 29Si NMR, EA, TGA, DSC, GPC, and CV, respectively. The results show that the novel hybrid possesses high thermal stability and good electron injection ability.

  17. Using an electronic platform interactively to improve treatment outcome in patients with rheumatoid arthritis

    DEFF Research Database (Denmark)

    Hetland, Merete L; Krogh, Niels Steen; Hørslev-Petersen, Kim;

    2016-01-01

    OBJECTIVES: Electronic platforms have been developed to help the clinician monitor disease activity in rheumatoid arthritis (RA) to support at treat-to-target strategy. We present an initiative to interactively improve disease control in patients with rheumatoid arthritis. METHODS: In patients who......>3.2. Which action do you as a physician take today: □ Intensify treatment, □ Treatment intensification is not possible currently/awaiting results of additional investigations, □ No further treatment intensification is possible, □ The patient does not want to intensify treatment, □ Other decisions...... taken" RESULTS: Of 21,056 patients with RA, 40% fulfilled the criteria for getting the alert message. The pop-up was activated and completed by the physician in 65% of those (5,428 patients). Treatment was intensified in 67%. In 2% of patients, no additional treatment intensification was possible, and 8...

  18. Using an electronic platform interactively to improve treatment outcome in patients with rheumatoid arthritis

    DEFF Research Database (Denmark)

    Hetland, Merete Lund; Krogh, Niels Steen; Hørslev-Petersen, Kim

    2016-01-01

    Objective. Electronic platforms have been developed to help the clinician monitor disease activity in rheumatoid arthritis (RA) to support at treat-to-target strategy. We present an initiative to interactively improve disease control in patients with rheumatoid arthritis. Methods. In patients who......CRP > 3.2. Which action do you as a physician take today: □ Intensify treatment, □Treatment intensification is not possible currently/awaiting results of additional investigations, □ No further treatment intensification is possible, □ The patient does not want to intensify treatment, □ Other decisions...... taken" Results. Of 21,056 patients with RA, 40% fulfilled the criteria for getting the alert message. The pop-up was activated and completed by the physician in 65% of those (5,428 patients). Treatment was intensified in 67%. In 2% of patients, no additional treatment intensification was possible, and 8...

  19. Using an electronic platform interactively to improve treatment outcome in patients with rheumatoid arthritis

    DEFF Research Database (Denmark)

    Hetland, Merete L; Krogh, Niels Steen; Hørslev-Petersen, Kim

    2016-01-01

    OBJECTIVES: Electronic platforms have been developed to help the clinician monitor disease activity in rheumatoid arthritis (RA) to support at treat-to-target strategy. We present an initiative to interactively improve disease control in patients with rheumatoid arthritis. METHODS: In patients who......>3.2. Which action do you as a physician take today: □ Intensify treatment, □ Treatment intensification is not possible currently/awaiting results of additional investigations, □ No further treatment intensification is possible, □ The patient does not want to intensify treatment, □ Other decisions...... taken" RESULTS: Of 21,056 patients with RA, 40% fulfilled the criteria for getting the alert message. The pop-up was activated and completed by the physician in 65% of those (5,428 patients). Treatment was intensified in 67%. In 2% of patients, no additional treatment intensification was possible, and 8...

  20. Interaction of runaway electrons with lower hybrid waves via anomalous Doppler broadening

    Science.gov (United States)

    Martín-Solís, J. R.; Sánchez, R.; Esposito, B.

    2002-05-01

    Due to the relativistic decrease of the electron cyclotron frequency, a cyclotron resonance may appear between runaway electrons and lower hybrid waves. A single particle description of the runaway dynamics [J. R. Martín-Solís et al., Phys. Plasmas 5, 2370 (1998)] is extended to analyze the effect of the interaction of runaway electrons with lower hybrid waves via anomalous Doppler broadening. The conditions under which the resonant interaction can play a role in limiting the runaway energy are established and it is shown that, under typical lower hybrid current drive operation parameters, an efficient wave-particle coupling may occur. Observations of a fast pitch angle scattering event during the current decay phase of Ohmic discharges in the Toroidal Experiment for Technically Oriented Research (TEXTOR) [R. J. E. Jaspers, Ph.D. thesis, Technical University Eindhoven (1995)] are interpreted in terms of such interaction.

  1. Investigation of the hybrid electron linac with negative group velocity

    Science.gov (United States)

    Savin, E. A.; Alekhanov, R. Yu.; Bulanov, A. V.; Kaminskiy, V. I.; Matsievskiy, S. V.; Sobenin, N. P.

    2016-09-01

    Hybrid accelerator, incorporating travelling wave (TW) and standing wave (SW) structures is proposed and discussed. Accelerator can sum up an RF focusing in the SW buncher and lower losses in the TW accelerating structure walls. Moreover, the structure without dumping load is proposed. Input power and beam loading are chosen to minimize power reflection from buncher maintain travelling wave regime in the accelerating structure while beam loading is on. In this case SW buncher operates as a dumping load, so all input power either goes to beam or dissipates in the wall losses, it increases structure efficiency. RF characteristics and beam dynamics simulations have been performed.

  2. Design Patterns for Sparse-Matrix Computations on Hybrid CPU/GPU Platforms

    Directory of Open Access Journals (Sweden)

    Valeria Cardellini

    2014-01-01

    Full Text Available We apply object-oriented software design patterns to develop code for scientific software involving sparse matrices. Design patterns arise when multiple independent developments produce similar designs which converge onto a generic solution. We demonstrate how to use design patterns to implement an interface for sparse matrix computations on NVIDIA GPUs starting from PSBLAS, an existing sparse matrix library, and from existing sets of GPU kernels for sparse matrices. We also compare the throughput of the PSBLAS sparse matrix–vector multiplication on two platforms exploiting the GPU with that obtained by a CPU-only PSBLAS implementation. Our experiments exhibit encouraging results regarding the comparison between CPU and GPU executions in double precision, obtaining a speedup of up to 35.35 on NVIDIA GTX 285 with respect to AMD Athlon 7750, and up to 10.15 on NVIDIA Tesla C2050 with respect to Intel Xeon X5650.

  3. Paired-pulse facilitation achieved in protonic/electronic hybrid indium gallium zinc oxide synaptic transistors

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Li Qiang, E-mail: guoliqiang@ujs.edu.cn; Ding, Jian Ning; Huang, Yu Kai [Micro/Nano Science & Technology Center, Jiangsu University, Zhenjiang, 212013 (China); Zhu, Li Qiang, E-mail: lqzhu@nimte.ac.cn [Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201 (China)

    2015-08-15

    Neuromorphic devices with paired pulse facilitation emulating that of biological synapses are the key to develop artificial neural networks. Here, phosphorus-doped nanogranular SiO{sub 2} electrolyte is used as gate dielectric for protonic/electronic hybrid indium gallium zinc oxide (IGZO) synaptic transistor. In such synaptic transistors, protons within the SiO{sub 2} electrolyte are deemed as neurotransmitters of biological synapses. Paired-pulse facilitation (PPF) behaviors for the analogous information were mimicked. The temperature dependent PPF behaviors were also investigated systematically. The results indicate that the protonic/electronic hybrid IGZO synaptic transistors would be promising candidates for inorganic synapses in artificial neural network applications.

  4. Rechargeable Mg battery cathode TiS3 with d-p orbital hybridized electronic structures

    Science.gov (United States)

    Taniguchi, Kouji; Gu, Yunpeng; Katsura, Yukari; Yoshino, Takafumi; Takagi, Hidenori

    2016-01-01

    Rechargeable performance is realized in Mg batteries using a TiS3 cathode without the nanometer-scale downsizing of electrode particles. The specific capacity is about 80 mAh/g for the first 50 cycles at room temperature. This observed specific capacity is comparable to that of the prototype cathode for Mg batteries. First-principles calculation indicates that TiS3 is a semiconductor with d-p orbital hybridized electronic structures around the Fermi level. The reversible electrode performance is likely assisted by the delocalized electronic distribution over metal-ligand units through d-p orbital hybridization.

  5. Bioinspired near-infrared-excited sensing platform for in vitro antioxidant capacity assay based on upconversion nanoparticles and a dopamine-melanin hybrid system.

    Science.gov (United States)

    Wang, Dong; Chen, Chuan; Ke, Xuebin; Kang, Ning; Shen, Yuqing; Liu, Yongliang; Zhou, Xi; Wang, Hongjun; Chen, Changqing; Ren, Lei

    2015-02-11

    A novel core-shell structure based on upconversion fluorescent nanoparticles (UCNPs) and dopamine-melanin has been developed for evaluation of the antioxidant capacity of biological fluids. In this approach, dopamine-melanin nanoshells facilely formed on the surface of UCNPs act as ultraefficient quenchers for upconversion fluorescence, contributing to a photoinduced electron-transfer mechanism. This spontaneous oxidative polymerization of the dopamine-induced quenching effect could be effectively prevented by the presence of various antioxidants (typically biothiols, ascorbic acid (Vitamin C), and Trolox). The chemical response of the UCNPs@dopamine-melanin hybrid system exhibited great selectivity and sensitivity toward antioxidants relative to other compounds at 100-fold higher concentration. A satisfactory correlation was established between the ratio of the "anti-quenching" fluorescence intensity and the concentration of antioxidants. Besides the response of the upconversion fluorescence signal, a specific evaluation process for antioxidants could be visualized by the color change from colorless to dark gray accompanied by the spontaneous oxidation of dopamine. The near-infrared (NIR)-excited UCNP-based antioxidant capacity assay platform was further used to evaluate the antioxidant capacity of cell extracts and human plasma, and satisfactory sensitivity, repeatability, and recovery rate were obtained. This approach features easy preparation, fluorescence/visual dual mode detection, high specificity to antioxidants, and enhanced sensitivity with NIR excitation, showing great potential for screening and quantitative evaluation of antioxidants in biological systems.

  6. 3D electronics for hybrid pixel detectors – TWEPP-09

    CERN Document Server

    Godiot, S; Chantepie, B; Clémens, J C; Fei, R; Fleury, J; Fougeron, D; Garcia-Sciveres, M; Hemperek, T; Karagounis, M; Krueger, H; Mekkaoui, A; Pangaud, P; Rozanov, A; Wermes, N

    2009-01-01

    Future hybrid pixel detectors are asking for smaller pixels in order to improve spatial resolution and to deal with an increasing counting rate. Facing these requirements is foreseen to be done by microelectronics technology shrinking. However, this straightforward approach presents some disadvantages in term of performances and cost. New 3D technologies offer an alternative way with the advantage of technology mixing. For the upgrade of ATLAS pixel detector, a 3D conception of the read-out chip appeared as an interesting solution. Splitting the pixel functionalities into two separate levels will reduce pixel size and open the opportunity to take benefit of technology's mixing. Based on a previous prototype of the read-out chip FE-I4 (IBM 130nm), this paper presents the design of a hybrid pixel read-out chip using threedimensional Tezzaron-Chartered technology. In order to disentangle effects due to Chartered 130nm technology from effects involved by 3D architecture, a first translation of FEI4 prototype had ...

  7. WWC Review of the Report "Interactive Online Learning on Campus: Testing MOOCs and Other Platforms in Hybrid Formats in the University System of Maryland." What Works Clearinghouse Single Study Review

    Science.gov (United States)

    What Works Clearinghouse, 2015

    2015-01-01

    In the 2014 study, "Interactive Online Learning on Campus: Testing MOOCs and Other Platforms in Hybrid Formats in the University System of Maryland," researchers examined the impact of using hybrid forms of interactive online learning in seven undergraduate courses across seven universities in Maryland. Hybrid forms of interactive online…

  8. Electronic desalting for controlling the ionic environment in droplet-based biosensing platforms

    Energy Technology Data Exchange (ETDEWEB)

    Swaminathan, Vikhram Vilasur [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Dak, Piyush; Alam, Muhammad A., E-mail: rbashir@illinois.edu, E-mail: alam@purdue.edu [School of Electrical and Computer Engineering, Purdue University, West Lafayette, Indiana 47907 (United States); Reddy, Bobby; Duarte-Guevara, Carlos; Zhong, Yu [Department of Electrical and Computer Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Salm, Eric [Department of Bioengineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Fischer, Andrew [Abbott Laboratories, 1921 Hurd Drive, Dept. 8482 LC2 M/S 2-33, Irving, Texas 75038 (United States); Liu, Yi-Shao [Taiwan Semiconductor Manufacturing Company, Hsinchu 300-78, Taiwan (China); Bashir, Rashid, E-mail: rbashir@illinois.edu, E-mail: alam@purdue.edu [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Department of Electrical and Computer Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Department of Bioengineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States)

    2015-02-02

    The ability to control the ionic environment in saline waters and aqueous electrolytes is useful for desalination as well as electronic biosensing. We demonstrate a method of electronic desalting at micro-scale through on-chip micro electrodes. We show that, while desalting is limited in bulk solutions with unlimited availability of salts, significant desalting of ≥1 mM solutions can be achieved in sub-nanoliter volume droplets with diameters of ∼250 μm. Within these droplets, by using platinum-black microelectrodes and electrochemical surface treatments, we can enhance the electrode surface area to achieve >99% and 41% salt removal in 1 mM and 10 mM salt concentrations, respectively. Through self-consistent simulations and experimental measurements, we demonstrate that conventional double-layer theory over-predicts the desalting capacity and, hence, cannot be used to model systems that are mass limited or undergoing significant salt removal from the bulk. Our results will provide a better understanding of capacitive desalination, as well as a method for salt manipulation in high-throughput droplet-based microfluidic sensing platforms.

  9. Nanoscale Structure of Self-Assembling Hybrid Materials of Inorganic and Electronically Active Organic Phases

    Energy Technology Data Exchange (ETDEWEB)

    Sofos, M.; Goswami, D.A. Stone D.K.; Okasinski, J.S.; Jin, H.; Bedzyk, M.J.; Stupp, S.I. (NWU)

    2008-10-06

    Hybrid materials with nanoscale structure that incorporates inorganic and organic phases with electronic properties offer potential in an extensive functional space that includes photovoltaics, light emission, and sensing. This work describes the nanoscale structure of model hybrid materials with phases of silica and electronically active bola-amphiphile assemblies containing either oligo(p-phenylene vinylene) or oligo(thiophene) segments. The hybrid materials studied here were synthesized by evaporation-induced self-assembly and characterized by X-ray scattering techniques. Grazing-incidence X-ray scattering studies of these materials revealed the formation of two-dimensional hexagonally packed cylindrical micelles of the organic molecules with diameters between 3.1 and 3.6 nm and cylindrical axes parallel to the surface. During the self-assembly process at low pH, the cylindrical aggregates of conjugated molecules become surrounded by silica giving rise to a hybrid structure with long-range order. Specular X-ray reflectivity confirmed the long-range periodicity of the hybrid films within a specific range of molar ratios of tetraethyl orthosilicate to cationic amphiphile. We did not observe any long-range ordering in fully organic analogues unless quaternary ammonium groups were replaced by tertiary amines. These observations suggest that charge screening in these biscationic conjugated molecules by the mineral phase is a key factor in the evolution of long range order in the self-assembling hybrids.

  10. The electronic transport characteristics of hybridized hexagon beryllium sulfide and graphene nanoribbons

    Science.gov (United States)

    Wang, Lihua; Ding, Bingjun; Guo, Yong

    2017-01-01

    Hybridized Z-BexSyCz (x + y + z = 16) systems connected by zigzag beryllium-sulfide (BeS) and graphene nanoribbons are theoretically designed, and their electronic transport characteristics are explored by first-principles approach. For the hybridized systems with unequal number of x and y, i.e. z is an odd number, an exceptional negative differential resistance (NDR) property occurs. However, for the hybridized systems including an even number of zigzag carbon chains, namely x equal to y, an interesting current-limited behavior happens. Meanwhile, the NDR phenomenon disappears. The spin transport properties of these hybridized Z-BexSyCz systems with parallel magnetism configuration also reveal the above odd-even dependence conductance behavior.

  11. The “Chimera”: An Off-The-Shelf CPU/GPGPU/FPGA Hybrid Computing Platform

    Directory of Open Access Journals (Sweden)

    Ra Inta

    2012-01-01

    Full Text Available The nature of modern astronomy means that a number of interesting problems exhibit a substantial computational bound and this situation is gradually worsening. Scientists, increasingly fighting for valuable resources on conventional high-performance computing (HPC facilities—often with a limited customizable user environment—are increasingly looking to hardware acceleration solutions. We describe here a heterogeneous CPU/GPGPU/FPGA desktop computing system (the “Chimera”, built with commercial-off-the-shelf components. We show that this platform may be a viable alternative solution to many common computationally bound problems found in astronomy, however, not without significant challenges. The most significant bottleneck in pipelines involving real data is most likely to be the interconnect (in this case the PCI Express bus residing on the CPU motherboard. Finally, we speculate on the merits of our Chimera system on the entire landscape of parallel computing, through the analysis of representative problems from UC Berkeley’s “Thirteen Dwarves.”

  12. Using k-alpha emission to determine fast electron spectra using the Hybrid code ZEPHYROS

    CERN Document Server

    White, Thomas; Gregori, Gianluca

    2014-01-01

    A high intensity laser-solid interaction invariably drives a non-thermal fast electron current through the target, however characterizing these fast electron distributions can prove difficult. An understanding of how these electrons propagate through dense materials is of fundamental interest and has applications relevant to fast ignition schemes and ion acceleration. Here, we utilize an upgraded version of the Hybrid code ZEPHYROS to demonstrate how the resulting k-alpha emission from such an interaction can be used as a diagnostic to obtain the characteristic temperature, divergence and total energy of the fast electron population.

  13. Hybrid chromophore/template nanostructures: A customizable platform material for solar energy storage and conversion

    Energy Technology Data Exchange (ETDEWEB)

    Kolpak, AM; Grossman, JC

    2013-01-21

    Challenges with cost, cyclability, and/or low energy density have largely prevented the development of solar thermal fuels, a potentially attractive alternative energy technology based on molecules that can capture and store solar energy as latent heat in a closed cycle. In this paper, we present a set of novel hybrid photoisomer/template solar thermal fuels that can potentially circumvent these challenges. Using first-principles computations, we demonstrate that these fuels, composed of organic photoisomers bound to inexpensive carbon-based templates, can reversibly store solar energy at densities comparable to Li-ion batteries. Furthermore, we show that variation of the template material in combination with the photoisomer can be used to optimize many of the key performance metrics of the fuel-i.e., the energy density, the storage lifetime, the temperature of the output heat, and the efficiency of the solar-to-heat conversion. Our work suggests that the solar thermal fuels concept can be translated into a practical and highly customizable energy storage and conversion technology. (C) 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4773306

  14. Analysis Platform for Energy Efficiency Enhancement in Hybrid and Full Electric Vehicles

    Directory of Open Access Journals (Sweden)

    NICOLAICA, M.-O.

    2016-02-01

    Full Text Available The current paper presents a new virtual analysis method that is applied both on hybrid and electric vehicle architectures with the purpose of contributing to the improvement of energy efficiency. The study is based on Matlab modeling and simulation. A set of parameters are considered in order to assess the system performance. The benefit is given by the comparative overview obtained after the completed analysis. The effectiveness of the analysis method is confirmed by a sequence of simulation results combined in several case studies. The impulse of the research is given by the fact that the automotive market is focusing on wider simulation techniques and better control strategies that lead to more efficient vehicles. Applying the proposed method during design would improve the battery management and controls strategy. The advantage of this method is that the system behavior with regards to energy efficiency can be evaluated from an early concept phase. The results contribute to the actual necessity of driving more efficient and more environmental friendly vehicles.

  15. Hybrid chromophore/template nanostructures: a customizable platform material for solar energy storage and conversion.

    Science.gov (United States)

    Kolpak, Alexie M; Grossman, Jeffrey C

    2013-01-21

    Challenges with cost, cyclability, and/or low energy density have largely prevented the development of solar thermal fuels, a potentially attractive alternative energy technology based on molecules that can capture and store solar energy as latent heat in a closed cycle. In this paper, we present a set of novel hybrid photoisomer/template solar thermal fuels that can potentially circumvent these challenges. Using first-principles computations, we demonstrate that these fuels, composed of organic photoisomers bound to inexpensive carbon-based templates, can reversibly store solar energy at densities comparable to Li-ion batteries. Furthermore, we show that variation of the template material in combination with the photoisomer can be used to optimize many of the key performance metrics of the fuel-i.e., the energy density, the storage lifetime, the temperature of the output heat, and the efficiency of the solar-to-heat conversion. Our work suggests that the solar thermal fuels concept can be translated into a practical and highly customizable energy storage and conversion technology.

  16. My ENG 102 Class Has Gone to HEC: Creating the Hybrid Electronic Course.

    Science.gov (United States)

    Ross, Jeffrey

    In this paper, a college English professor shares his teaching experiences in a Hybrid Electronic Course (HEC), which combined traditional classroom meetings with e-mail-based workshops. The paper includes a general description of the course, the instructor's daily journals throughout the course, and his reflections following the course. Many of…

  17. Oxide nanomembrane hybrids with enhanced mechano- and thermo-sensitivity for semitransparent epidermal electronics.

    Science.gov (United States)

    Park, Minjoon; Do, Kyungsik; Kim, Jaemin; Son, Donghee; Koo, Ja Hoon; Park, Jinkyung; Song, Jun-Kyul; Kim, Ji Hoon; Lee, Minbaek; Hyeon, Taeghwan; Kim, Dae-Hyeong

    2015-05-01

    Oxide nanomembrane hybrids with enhanced mechano- and thermo-sensitivity for semitransparent epidermal electronics are developed. The use of nanomaterials (single wall nanotubes and silver nanoparticles) embedded in the oxide nanomembranes significantly enhances mechanical and thermal sensitivities. These mechanical and thermal sensors are utilized in wheelchair control and hypothermia detection, which are useful for patients with strokes.

  18. Bosch automotive electrics and automotive electronics systems and components, networking and hybrid drive

    CERN Document Server

    2014-01-01

    The significance of electrical and electronic systems has increased considerably in the last few years and this trend is set to continue. The characteristics feature of innovative systems is the fact that they can work together in a network. This requires powerful bus systems that the electronic control units can use to exchange information. Networking and the various bus systems used in motor vehicles are the prominent new topic in the 5th edition of the "Automotive Electric, Automotive Electronics" technical manual. The existing chapters have also been updated, so that this new edition brings the reader up to date on the subjects of electrical and electronic systems in the motor vehicle. Content Electrical and electronical systems – Basic principles of networking - Examples of networked vehicles – Bus systems – Architecture of electronic systems – Mechatronics – Elektronics – Electronic control Units – Software – Sensors – Actuators – Hybrid drives – Vehicle electrical system – Start...

  19. New materials strategies for creating hybrid electronic circuitry (Presentation Video)

    Science.gov (United States)

    Marks, Tobin J.

    2013-09-01

    This lecture focuses on the challenging design and realization of new materials for creating unconventional electronic circuitry. Fabrication methodologies to achieve these goals include high-throughput, large-area printing techniques. Materials design topics to be discussed include: 1. Rationally designed high-mobility p- and n-type organic semiconductors for printed organic CMOS, 2. Polycrystalline and amorphous oxide semiconductors for transparent and mechanically flexible electronics, 3) Self-assembled and printable high-k nanodielectrics enabling ultra-large capacitance, low leakage, high breakdown fields, minimal trapped interfacial charge, and device radiation hardness. 4) Combining these materials sets to fabricate a variety of high-performance thin-film transistor-based devices.

  20. Electronic Structure Rearrangements in Hybrid Ribozyme/Protein Catalysis

    Science.gov (United States)

    Kang, Jiyoung; Kino, Hiori; Field, Martin J.; Tateno, Masaru

    2017-04-01

    We analyzed the electronic structural changes that occur in the reaction cycle of a biological catalyst composed of RNA and protein, and elucidated the dynamical rearrangements of the electronic structure that was obtained from our previous study in which ab initio quantum mechanics/molecular mechanics molecular dynamics simulations were performed. Notable results that we obtained include the generation of a reactive HOMO that is responsible for bond formation in the initial stages of the reaction, and the appearance of a reactive LUMO that is involved in the bond rupture that leads to products. We denote these changes as dynamical induction of the reactive HOMO (DIRH) and LUMO (DIRL), respectively. Interestingly, we also find that the induction of the reactive HOMO is enhanced by the formation of a low-barrier hydrogen bond (LBHB), which, to the best of our knowledge, represents a novel role for LBHBs in enzymatic systems.

  1. Hybrid optical and electronic laser locking using spectral hole burning

    CERN Document Server

    Farr, Warrick G; Ledingham, Patrick M; Korystov, Dmitry; Longdell, Jevon J

    2010-01-01

    We report on a narrow linewidth laser diode system that is stabilized using both optical and electronic feedback to a spectral hole in cryogenic Tm:YAG. The laser system exhibits very low phase noise. The spectrum of the beat signal between two lasers, over millisecond timescales, is either Fourier limited or limited by the -111dBc/Hz noise floor. The resulting laser is well suited to quantum optics and sensing applications involving rare earth ion dopants.

  2. Application of electronic commerce platform%电子商务平台技术应用研究

    Institute of Scientific and Technical Information of China (English)

    朱建军; 周强; 祝红光

    2016-01-01

    电子商务在国内快速发展,技术日趋成熟,众多行业广泛应用,然而,电子商务平台存在重复开发的现象,业务逻辑和商务平台技术结合的有效性和规范化是目前研究的重要课题。本文通过对电商平台建设采用的关键技术研究分析,针对旅游类的商务网站建设特点,提出架构、技术实现的有效模式。对将要进入电商行业的企业建设电商平台具有一定的借鉴意义。%Electronic commerce is developing rapidly in China, and its technology is becoming more and more mature. The electronic commerce platform is widely used in many industry ifelds. While the phenomenon of repeated exploitation existed in the platform. The efficiency and standardization of business logic and commerce platform technology are important research topics in the current research. This article analyzed the key technologies used in the construction of electronic business platform, according to the characteristics of the construction of tourism commerce website, proposed the effective model of framework and technology. For the enterprise of entering the electronic commerce and constructing electronic commerce platform, it has a certain reference signiifcance.

  3. Transmission electron microscopy of unstained hybrid Au nanoparticles capped with PPAA (plasma-poly-allylamine): structure and electron irradiation effects.

    Science.gov (United States)

    Gontard, Lionel C; Fernández, Asunción; Dunin-Borkowski, Rafal E; Kasama, Takeshi; Lozano-Pérez, Sergio; Lucas, Stéphane

    2014-12-01

    Hybrid (organic shell-inorganic core) nanoparticles have important applications in nanomedicine. Although the inorganic components of hybrid nanoparticles can be characterized readily using conventional transmission electron microscopy (TEM) techniques, the structural and chemical arrangement of the organic molecular components remains largely unknown. Here, we apply TEM to the physico-chemical characterization of Au nanoparticles that are coated with plasma-polymerized-allylamine, an organic compound with the formula C3H5NH2. We discuss the use of energy-filtered TEM in the low-energy-loss range as a contrast enhancement mechanism for imaging the organic shells of such particles. We also study electron-beam-induced crystallization and amorphization of the shells and the formation of graphitic-like layers that contain both C and N. The resistance of the samples to irradiation by high-energy electrons, which is relevant for optical tuning and for understanding the degree to which such hybrid nanostructures are stable in the presence of biomedical radiation, is also discussed. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Synthesis and Applications of Multimodal Hybrid Albumin Nanoparticles for Chemotherapeutic Drug Delivery and Photothermal Therapy Platforms

    Science.gov (United States)

    Peralta, Donna V.

    cellular uptake of AuNR-HSAPs via fluorescence microscopy. Finally, camptothecin (CPT) an antineoplastic agent and BACPT (7-butyl-10-aminocamptothecin) were loaded into HSAPs to combat their aqueous insolubility. BACPT-HSAPs loaded up to 5.25 micrograms BACPT/ mg of HSA. CPT encapsulation could not be determined. BACPT-HSAPs and CPT-HSAPs showed cytotoxicity to human sarcoma cells in vitro. Key words: Hybrid Nanoparticles, Photothermal Therapy, Gold Nanomaterials, Drug Delivery, Combinational Cancer Therapies, Materials, Human Serum Albumin, Colloidal Carriers.

  5. Hybridized electromagnetic-triboelectric nanogenerator for scavenging biomechanical energy for sustainably powering wearable electronics.

    Science.gov (United States)

    Zhang, Kewei; Wang, Xue; Yang, Ya; Wang, Zhong Lin

    2015-01-01

    We report a hybridized electromagnetic-triboelectric nanogenerator for highly efficient scavenging of biomechanical energy to sustainably power wearable electronics by human walking. Based on the effective conjunction of triboelectrification and electromagnetic induction, the hybridized nanogenerator, with dimensions of 5 cm × 5 cm × 2.5 cm and a light weight of 60 g, integrates a triboelectric nanogenerator (TENG) that can deliver a peak output power of 4.9 mW under a loading resistance of 6 MΩ and an electromagnetic generator (EMG) that can deliver a peak output power of 3.5 mW under a loading resistance of 2 kΩ. The hybridized nanogenerator exhibits a good stability for the output performance and a much better charging performance than that of an individual energy-harvesting unit (TENG or EMG). Furthermore, the hybridized nanogenerator integrated in a commercial shoe has been utilized to harvest biomechanical energy induced by human walking to directly light up tens of light-emitting diodes in the shoe and sustainably power a smart pedometer for reading the data of a walking step, distance, and energy consumption. A wireless pedometer driven by the hybrid nanogenerator can work well to send the walking data to an iPhone under the distance of 25 m. This work pushes forward a significant step toward energy harvesting from human walking and its potential applications in sustainably powering wearable electronics.

  6. First-Principles Study of Electronic Structure of Type I Hybrid Carbon-Silicon Clathrates

    Science.gov (United States)

    Chan, Kwai S.; Peng, Xihong

    2016-08-01

    A new class of type I hybrid carbon-silicon clathrates has been designed using computational methods by substituting some of the Si atoms in the silicon clathrate framework with carbon atoms. In this work, the electronic structure of hybrid carbon-silicon clathrates with and without alkaline or alkaline-earth metal guest atoms has been computed within the density functional theory framework. The theoretical calculations indicate that a small number of carbon substitutions in the Si46 framework slightly reduces the density of states (DOS) near the band edge and narrows the bandgap of carbon-silicon clathrates. Weak hybridization of the conduction band occurs when alkaline metal (Li, Na, K) atoms are inserted into the structure, while strong hybridization of the conduction band occurs when alkaline-earth metal (Mg, Ca, Ba) atoms are inserted into the hybrid structure. Empty C y Si46- y clathrates within the composition range of 2 ≤ y ≤ 15 can be tuned to exhibit indirect bandgaps of 1.5 eV or less, and may be considered as potential electronic materials.

  7. Mode conversion and electron heating near the upper hybrid resonance frequency

    Energy Technology Data Exchange (ETDEWEB)

    Smith, B.L.; Okuda, H.; Abe, H.

    1983-11-01

    Mode conversion near the upper hybrid resonance frequency and electron heating are studied using a one-dimensional electromagnetic relativistic particle code. It is found that for a sufficiently small pump field E/sub 0/, E/sub 0//sup 2//4..pi..nT/sub e/ less than or equal to 0.01, electron heating is localized in a region near the electron cyclotron layer where the pump frequency is equal to the local electron gyrofrequency. For stronger pump fields, electron heating takes place more or less uniformly across a region between the upper hybrid resonance layer and the cyclotron layer. In addition, a significant fraction of electromagnetic energy associated with the pump is found to be reflected back into the vacuum from a region in the plasma near the upper hybrid resonance layer for both strong (E/sub 0//sup 2//4..pi..nT/sub e/ approx. = 1) and weak pumps (E/sub 0//sup 2//4..pi..nT/sub e/ << 1).

  8. Power electronics and electric machinery challenges and opportunities in electric and hybrid vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Adams, D.J.; Hsu, J.S.; Young, R.W. [Oak Ridge National Lab., TN (United States); Peng, F.Z. [Univ. of Tennessee, Knoxville, TN (United States)

    1997-06-01

    The development of power electronics and electric machinery presents significant challenges to the advancement of electric and hybrid vehicles. Electronic components and systems development for vehicle applications have progressed from the replacement of mechanical systems to the availability of features that can only be realized through interacting electronic controls and devices. Near-term applications of power electronics in vehicles will enable integrated powertrain controls, integrated chassis system controls, and navigation and communications systems. Future applications of optimized electric machinery will enable highly efficient and lightweight systems. This paper will explore the areas where research and development is required to ensure the continued development of power electronics and electric machines to meet the rigorous demands of automotive applications. Additionally, recent advances in automotive related power electronics and electric machinery at Oak Ridge National Laboratory will be explained. 3 refs., 5 figs.

  9. A review and design of power electronics converters for fuel cell hybrid system applications

    DEFF Research Database (Denmark)

    Zhang, Zhe; Pittini, Riccardo; Andersen, Michael A. E.

    2012-01-01

    This paper presents an overview of most promising power electronics topologies for a fuel cell hybrid power conversion system which can be utilized in many applications such as hybrid electrical vehicles (HEV), distributed generations (DG) and uninterruptible-power-supply (UPS) systems. Then......, a multiple-input power conversion system including a decoupled dual-input converter and a three-phase neutral-point-clamped (NPC) inverter is proposed. The system can operate in both stand-alone and grid-connected modes. Simulation and experimental results are provided to show the feasibility of the proposed...

  10. Efficient Hybrid Optimal Design Method for Power Electronics Converters

    CERN Document Server

    AUTHOR|(SzGeCERN)697719; Aguglia, Davide; Viarouge, Philippe; Cros, Jérôme

    2015-01-01

    This paper presents a novel design methodology for dimensioning optimal power-electronic converters, which is able to achieve the precision of numerical simulation-based optimization procedures, however minimizing the overall computation time. The approach is based on the utilization of analytical and frequency-domain design models for a numerical optimization process, a validation with numerical simulations of the intermediate optimal solutions, and the correction of the analytical design models precision from the numerical simulation results. This method allows using the numerical simulation in an efficient way, where typically less than ten correction iterations are required. In order to demonstrate the performances of the proposed methodology, the calculation of the control parameters for an H-bridge DC-DC converter and the optimal dimensioning of a damped output filter for a buck converter using the proposed approach is presented.

  11. Electronic and magnetic properties of modified silicene/graphene hybrid: Ab initio study

    Energy Technology Data Exchange (ETDEWEB)

    Chowdhury, Suman; Jana, Debnarayan, E-mail: cujanad@yahoo.com

    2016-11-01

    Among other two-dimensional (2D) novel materials, graphene and silicene both have drawn intense research interest among the researchers because they possess some unique intriguing properties which can change the scenario of the current electronic industry. In this work we have studied the electronic and the magnetic properties of a new kind of materials which is the hybrid of these two materials. Density functional theory (DFT) has been employed to calculate the relevant electronic and magnetic properties of this hybrid material. The pristine structure is modified by substitutional doping or by creating vacancy (Y-X, where one Y atom (Si or C) has been replaced by one X atom (B, N, Al, P or void)). The calculations have revealed that void systems are unstable while Si-B and Si-N are most stable ones. It has been noticed that some of these doped structures are magnetic in nature having induced mid-gap states in the system. In particular, Si-void structure is unstable yet it possess the highest magnetic moment of the order of 4 μ{sub B} (μ{sub B} being the Bohr magneton). The estimated band gaps of modified silicene/graphene hybrid from spin polarized partial density of states (PDOS) vary between 1.43–2.38 eV and 1.58–2.50 eV for spin-up and spin-down channel respectively. The implication of midgap states has been critically analysed in the light of magnetic nature. This study may be useful to build hybrid spintronic devices with controllable gap for spin up and spin down states. - Graphical abstract: We have studied the electronic and magnetic properties of silicene/graphene hybrid by employing density functional theory (DFT). - Highlights: • Electronic and magnetic properties of two dimensional graphene/silicene hybrid have been explored. • There is no magnetism in the system for a single carbon atom vacancy. • A net magnetic moment of 4.0 Bohr magneton is observed for a single silicon atom vacancy. • Unpaired electrons introduce mid-gap states which

  12. Hybridized Electromagnetic-Triboelectric Nanogenerator for a Self-Powered Electronic Watch.

    Science.gov (United States)

    Quan, Ting; Wang, Xue; Wang, Zhong Lin; Yang, Ya

    2015-12-22

    We report a hybridized nanogenerator including a triboelectric nanogenerator (TENG) and six electromagnetic generators (EMGs) that can effectively scavenge biomechanical energy for sustainably powering an electronic watch. Triggered by the natural motions of the wearer's wrist, a magnetic ball at the center in an acrylic box with coils on each side will collide with the walls, resulting in outputs from both the EMGs and the TENG. By using the hybridized nanogenerator to harvest the biomechanical energy, the electronic watch can be continuously powered under different motion types of the wearer's wrist, where the best approach is to charge a 100 μF capacitor in 39 s to maintain the continuous operation of the watch for 456 s. To increase the working time of the watch further, a homemade Li-ion battery has been utilized as the energy storage unit for realizing the continuous working of the watch for about 218 min by using the hybridized nanogenerator to charge the battery within 32 min. This work will provide the opportunities for developing a nanogenerator-based built-in power source for self-powered wearable electronics such as an electronic watch.

  13. A facile and green method for synthesis of reduced graphene oxide/Ag hybrids as efficient surface enhanced Raman scattering platforms.

    Science.gov (United States)

    Huang, Qingli; Wang, Jiaming; Wei, Wenxian; Yan, Qiuxiang; Wu, Changle; Zhu, Xiashi

    2015-01-01

    Reduced graphene oxide/Ag nanoparticles hybrids (rGO/AgNPs) were fabricated via a green and facile hydrothermal method. The as-synthesized materials were characterized in detail using various spectroscopic and microscopic techniques. Under a suitable dosage of silver ions, well-dispersed AgNPs on the reduced graphene oxide sheets were obtained. The surface plasmon resonance properties of AgNPs on graphene show that there is an interaction between AgNPs and graphene. Trace detection of organic dyes is studied based on rGO/AgNPs hybrids as efficient surface enhanced Raman scattering platforms. It has been found that the suitable experiment parameter is crucial to trace detection of organic dyes molecules. This work is of importance in the practical application in device-design based on the SERS effect of noble metal/reduced oxide graphene (or oxide graphene) hybrids. Copyright © 2014 Elsevier B.V. All rights reserved.

  14. Engineered Nano-bio Hybrid Electronic Platform for Solar Energy Harvesting

    Science.gov (United States)

    2010-06-01

    the protein with various conductive substrates of indium tin oxide, zinc oxide, and titanium dioxide nanotubes . Electrolytes tested included...material with inorganics, including semiconductor quantum dots (QDs) and titanium dioxide nanotubes (NTs), opens new possibilities for protein...transport substrate (5). TiO2 NTs were synthesized by anodization of bulk high purity titanium (Ti) foils and Ti6Al4V alloy foils, and into thin

  15. Photoionization of few electron systems with a hybrid Coupled Channels approach

    CERN Document Server

    Majety, Vinay Pramod; Scrinzi, Armin

    2014-01-01

    We present the hybrid anti-symmetrized coupled channels method for the calculation of fully differential photo-electron spectra of multi-electron atoms and small molecules interacting with strong laser fields. The method unites quantum chemical few-body electronic structure with strong-field dynamics by solving the time dependent Schr\\"odinger equation in a fully anti-symmetrized basis composed of multi-electron states from quantum chemistry and a one-electron numerical basis. Photoelectron spectra are obtained via the time dependent surface flux (tSURFF) method. Performance and accuracy of the approach are demonstrated for spectra from the helium and berryllium atoms and the hydrogen molecule in linearly polarized laser fields at wavelength from 21 nm to 400 nm. At long wavelengths, helium and the hydrogen molecule at equilibrium inter-nuclear distance can be approximated as single channel systems whereas beryllium needs a multi-channel description.

  16. On-chip hybrid photonic-plasmonic light concentrator for nanofocusing in an integrated silicon photonics platform.

    Science.gov (United States)

    Luo, Ye; Chamanzar, Maysamreza; Apuzzo, Aniello; Salas-Montiel, Rafael; Nguyen, Kim Ngoc; Blaize, Sylvain; Adibi, Ali

    2015-02-11

    The enhancement and confinement of electromagnetic radiation to nanometer scale have improved the performances and decreased the dimensions of optical sources and detectors for several applications including spectroscopy, medical applications, and quantum information. Realization of on-chip nanofocusing devices compatible with silicon photonics platform adds a key functionality and provides opportunities for sensing, trapping, on-chip signal processing, and communications. Here, we discuss the design, fabrication, and experimental demonstration of light nanofocusing in a hybrid plasmonic-photonic nanotaper structure. We discuss the physical mechanisms behind the operation of this device, the coupling mechanisms, and how to engineer the energy transfer from a propagating guided mode to a trapped plasmonic mode at the apex of the plasmonic nanotaper with minimal radiation loss. Optical near-field measurements and Fourier modal analysis carried out using a near-field scanning optical microscope (NSOM) show a tight nanofocusing of light in this structure to an extremely small spot of 0.00563(λ/(2n(rmax)))(3) confined in 3D and an exquisite power input conversion of 92%. Our experiments also verify the mode selectivity of the device (low transmission of a TM-like input mode and high transmission of a TE-like input mode). A large field concentration factor (FCF) of about 4.9 is estimated from our NSOM measurement with a radius of curvature of about 20 nm at the apex of the nanotaper. The agreement between our theory and experimental results reveals helpful insights about the operation mechanism of the device, the interplay of the modes, and the gradual power transfer to the nanotaper apex.

  17. A Novel Laser Direct Writing System Integrated with A&F XXY Alignment Platform for Rapid Fabrication of Flexible Electronics

    Directory of Open Access Journals (Sweden)

    Yi-Kai Liu

    2015-05-01

    Full Text Available In this study, a novel laser direct synthesis and pattering technology is applied in conjunction with an A&F XXY alignment platform to rapidly fabricate flexible conductors on a polymer substrate (polyimide film with designated patterns. In the process, a focused continuous wave green laser was focused onto the polymer substrate that is mounted and directed using the XXY alignment platform. The focused laser energy absorbed by the polymer substrate is used to heat the transparent and particle-free reactive silver ink on the polymer substrate surface. With appropriate programing of the XXY alignment platform motion to control the laser scanning parameters, silver patterns with good electrical conductivity were successfully obtained. This technology can be operated directly at atmospheric pressure and room temperature. It does not require the use of vacuum chamber, oven and photo-mask, etc. Therefore, this novel technology and system offers a new approach to the cost-effective and green fabrication for flexible electronics. The compact size and excellent stability of the XXY alignment platform make the fabrication system even more competitive. In particular, the programmable small radius plane rotation function of the XXY alignment platform provides flexibility in the pattern design with turnings while keeps the uniformity of the resulted micro metal lines.

  18. Vehicle height and posture control of the electronic air suspension system using the hybrid system approach

    Science.gov (United States)

    Sun, Xiaoqiang; Cai, Yingfeng; Chen, Long; Liu, Yanling; Wang, Shaohua

    2016-03-01

    The electronic air suspension (EAS) system can improve ride comfort, fuel economy and handling safety of vehicles by adjusting vehicle height. This paper describes the development of a novel controller using the hybrid system approach to adjust the vehicle height (height control) and to regulate the roll and pitch angles of the vehicle body during the height adjustment process (posture control). The vehicle height adjustment system of EAS poses challenging hybrid control problems, since it features different discrete modes of operation, where each mode has an associated linear continuous-time dynamic. In this paper, we propose a novel approach to the modelling and controller design problem for the vehicle height adjustment system of EAS. The system model is described firstly in the hybrid system description language (HYSDEL) to obtain a mixed logical dynamical (MLD) hybrid model. For the resulting model, a hybrid model predictive controller is tuned to improve the vehicle height and posture tracking accuracy and to achieve the on-off statuses direct control of solenoid valves. The effectiveness and performance of the proposed approach are demonstrated by simulations and actual vehicle tests.

  19. Hybrid quantum circuit with a superconducting qubit coupled to an electron spin ensemble

    Energy Technology Data Exchange (ETDEWEB)

    Kubo, Yuimaru; Grezes, Cecile; Vion, Denis; Esteve, Daniel; Bertet, Patrice [Quantronics Group, SPEC (CNRS URA 2464), CEA-Saclay, 91191 Gif-sur-Yvette (France); Diniz, Igor; Auffeves, Alexia [Institut Neel, CNRS, BP 166, 38042 Grenoble (France); Isoya, Jun-ichi [Research Center for Knowledge Communities, University of Tsukuba, 305-8550 Tsukuba (Japan); Jacques, Vincent; Dreau, Anais; Roch, Jean-Francois [LPQM (CNRS, UMR 8537), Ecole Normale Superieure de Cachan, 94235 Cachan (France)

    2013-07-01

    We report the experimental realization of a hybrid quantum circuit combining a superconducting qubit and an ensemble of electronic spins. The qubit, of the transmon type, is coherently coupled to the spin ensemble consisting of nitrogen-vacancy (NV) centers in a diamond crystal via a frequency-tunable superconducting resonator acting as a quantum bus. Using this circuit, we prepare arbitrary superpositions of the qubit states that we store into collective excitations of the spin ensemble and retrieve back into the qubit. We also report a new method for detecting the magnetic resonance of electronic spins at low temperature with a qubit using the hybrid quantum circuit, as well as our recent progress on spin echo experiments.

  20. Theoretical investigation of the electronic structures and carrier transport of hybrid graphene and boron nitride nanostructure

    Directory of Open Access Journals (Sweden)

    Jia-Tao Sun

    2012-09-01

    graphene and hexagonal boron nitride (C-BN nanostructures receive much research interest due to the complementary electronic properties. Graphene is a zero-gap semiconductor, while hexagonal boron nitride (h-BN is a wide gap semiconductor. Here we studied the electronic structures and carrier transport of hybrid C-BN nanostructures by using first principles calculations and deformation potential theory. We have found that the physical quantities in these systems under study, band gap, effective mass, deformation potential, and carrier mobility, can be categorised into three different families depending on the width of graphene nanoribbon. This family behavior is similar to pristine armchair graphene nanoribbon, but with slight difference from the individual component. New opportunities of designing nanoelectric devices are discussed by utilizing the quantum confinement effect based on such kind of hybrid nanostructures.

  1. Research Update: The electronic structure of hybrid perovskite layers and their energetic alignment in devices

    Directory of Open Access Journals (Sweden)

    Selina Olthof

    2016-09-01

    Full Text Available In recent years, the interest in hybrid organic–inorganic perovskites has increased at a rapid pace due to their tremendous success in the field of thin film solar cells. This area closely ties together fundamental solid state research and device application, as it is necessary to understand the basic material properties to optimize the performances and open up new areas of application. In this regard, the energy levels and their respective alignment with adjacent charge transport layers play a crucial role. Currently, we are lacking a detailed understanding about the electronic structure and are struggling to understand what influences the alignment, how it varies, or how it can be intentionally modified. This research update aims at giving an overview over recent results regarding measurements of the electronic structure of hybrid perovskites using photoelectron spectroscopy to summarize the present status.

  2. Hybrid simulation of whistler excitation by electron beams in two-dimensional non-periodic domains

    Energy Technology Data Exchange (ETDEWEB)

    Woodroffe, J.R., E-mail: woodrofj@erau.edu; Streltsov, A.V., E-mail: streltsa@erau.edu

    2014-11-01

    We present a two-dimensional hybrid fluid-PIC scheme for the simulation of whistler wave excitation by relativistic electron beams. This scheme includes a number of features which are novel to simulations of this type, including non-periodic boundary conditions and fresh particle injection. Results from our model suggest that non-periodicity of the simulation domain results in the development of fundamentally different wave characteristics than are observed in periodic domains.

  3. Role of Microstructure in the Electron-Hole Interaction of Hybrid Lead-Halide Perovskites

    OpenAIRE

    Grancini, Giulia; Srimath Kandada, Ajay Ram; Frost, Jarvist M.; Barker, Alex J; Bastiani, Michele; Gandini, Marina; Marras, Sergio; Lanzani, Guglielmo; Walsh, Aron; Petrozza, Annamaria

    2015-01-01

    Solar cells based on hybrid inorganic-organic halide perovskites have demonstrated high power conversion efficiencies in a range of architectures. The existence and stability of bound electron-hole pairs in these materials, and their role in the exceptional performance of optoelectronic devices, remains a controversial issue. Here we demonstrate, through a combination of optical spectroscopy and multiscale modeling as a function of the degree of polycrystallinity and temperature, that the ele...

  4. Electronic control of the telescope, dome, platform and spectrograph observing system of the Bosque Alegre Astrophysical Station

    Science.gov (United States)

    Martínez del Pozo, G.; Picco, G. A.; Díaz, R. J.; Recabarren, P.

    In this work we present the new electronic and software system developed to control the main components of the observing system at the Bosque Alegre Astrophysical Station. The control system operates the 1.54 m telescope, the maintenance platform, dome, auto-guiding system and the Multifunctional Spectrograph and its design is based in a Microchip PIC microcontroller system (16F877) linked with a PC computer.

  5. The superatom states of fullerenes and their hybridization into the nearly free electron bands of fullerites.

    Science.gov (United States)

    Zhao, Jin; Feng, Min; Yang, Jinlong; Petek, Hrvoje

    2009-04-28

    Motivated by the discovery of the superatom states of C60 molecules, we investigate the factors that influence their energy and wave function hybridization into nearly free electron bands in molecular solids. As the n = 3 solutions of the radial Schrodinger equation of the central attractive potential consisting of the short-range C atom core and the long-range collective screening potentials, respectively, located on the icosahedral C60 molecule shell and within its hollow core, superatom states are distinguished by their atom-like orbitals corresponding to different orbital angular momentum states (l = 0, 1, 2,...). Because they are less tightly bound than the pi orbitals, that is, the n = 2 states, which are often exploited in the intermolecular electron transport in aromatic organic molecule semiconductors, superatom orbitals hybridize more extensively among aggregated molecules to form bands with nearly free electron dispersion. The prospect of exploiting the strong intermolecular coupling to achieve metal-like conduction in applications such as molecular electronics may be attained by lowering the energy of superatom states from 3.5 eV for single chemisorbed C60 molecules to below the Fermi level; therefore, we study how the superatom state energies depend on factors such as their aggregation into 1D-3D solids, cage size, and exo- and endohedral doping by metal atoms. We find, indeed, that if the ionization potential of endohedral atom, such as copper, is sufficiently large, superatom states can form the conduction band in the middle of the gap between the HOMO and LUMO of the parent C60 molecule. Through a plane-wave density functional theory study, we provide insights for a new paradigm for intermolecular electronic interaction beyond the conventional one among the sp(n) hybridized orbitals of the organic molecular solids that could lead to design of novel molecular materials and quantum structures with extraordinary optical and electronic properties.

  6. Domain-dependent electronic structure and optical absorption property in hybrid organic-inorganic perovskite.

    Science.gov (United States)

    Meng, Xiang; Zhang, Ruifeng; Fu, Zhongheng; Zhang, Qianfan

    2016-10-05

    Hybrid organic-inorganic perovskites, represented by materials in the CH3NH3PbI3 series, have become one of the most promising materials for solar cells with a high power conversion efficiency and low cost. The ordered Pb-I cage in such hybrid perovskites can induce the polarized cations to form a variety of polarization domains with long-range order, which will lead to the formation of specific atomic conformations or metastable crystalline phases, unique electronic band structures and optical absorption properties. Such domain-dependent characteristics play a critical role in the phase transition and service stability of such solar cells, and also open up the opportunity of tuning their electronic structure. In the present study, we systematically investigate the band structures and optical absorption properties of different electronically ordered domains in CH3NH3PbI3. By comparing different perovskites containing various cations, we have clarified the important influence of cation polarization on domain-dependent properties. Our results provide not only a possible pathway for the manipulation of band structure by applying an external field, but also a novel scheme for improving the performance and stability of hybrid perovskites.

  7. One-chip electronic detection of DNA hybridization using precision impedance-based CMOS array sensor.

    Science.gov (United States)

    Lee, Kang-Ho; Lee, Jeong-Oen; Sohn, Mi-Jin; Lee, Byunghun; Choi, Suk-Hwan; Kim, Sang Kyu; Yoon, Jun-Bo; Cho, Gyu-Hyeong

    2010-12-15

    This paper describes a label-free and fully electronic detection method of DNA hybridization, which is achieved through the use of a 16×8 microarray sensor in conjunction with a new type of impedance spectroscopy constructed with standard complementary metal-oxide-semiconductor (CMOS) technology. The impedance-based method is based on changes in the reactive capacitance and the charge-transfer resistance after hybridization with complementary DNA targets. In previously published label-free techniques, the measured capacitance presented unstable capacitive properties due to the parallel resistance that is not infinite and can cause a leakage by discharging the charge on the capacitor. This paper presents an impedance extraction method that uses excitation by triangular wave voltage, which enables a reliable measurement of both C and R producing a highly sensitive sensor with a stable operation independent of external variables. The system was fabricated in an industrial 0.35-μm 4-metal 2-poly CMOS process, integrating working electrodes and readout electronics into one chip. The integrated readout, which uses a parasitic insensitive integrator, achieves an enlarged detection range and improved noise performance. The maximum average relative variations of C and R are 31.5% and 68.6%, respectively, after hybridization with a 1 μM target DNA. The proposed sensor allows quantitative evaluation of the molecule densities on the chip with distinguishable variation in the impedance. This fully electronic microsystem has great potential for use with bioanalytical tools and point-of-care diagnosis.

  8. Photoemission study of ferrocenes: insights into the electronic structure of Si-based hybrid materials

    Energy Technology Data Exchange (ETDEWEB)

    Boccia, A; Marrani, A G; Stranges, S; Zanoni, R [Dipartimento di Chimica, Universita degli Studi di Roma ' La Sapienza' , piazzale Aldo Moro 5, I-00185 Rome (Italy); Alagia, M [ISMN-CNR, Sezione Romal, Piazzale Aldo Moro 5, I-00185 Roma, Italy and Laboratorio Nazionale TASC-CNR SS-14, Km 163.5, Basovizza, I-34012 Trieste (Italy); Iozzi, M F; Cossi, M [Dipartimento di Scienze dell' Ambiente e della Vita, Universita del Piemonte Orientale, via V. Bellini 25/G, I-15100 Alessandria (Italy)], E-mail: Andrea.Marrani@uniromal.it

    2008-03-15

    We present here the results of synchrotron radiation-excited UV-photoemission investigation and DFT calculations on vinylferrocene (VFC), a redox molecule suitable for applications in molecular electronics. A detailed assignment is discussed of the valence photoelectron spectra (UPS), which provides new data on the electronic structure and offers a partial re-interpretation of previous assignments on VFC based on theoretical and experimental evidences. Furthermore, the present results can allow for a meaningful comparison of photoemission results from the corresponding hybrid obtained by covalently attaching VFC to Si oriented surfaces.

  9. Quantum teleportation and entanglement swapping of electron spins in superconducting hybrid structures

    Energy Technology Data Exchange (ETDEWEB)

    Bubanja, Vladimir, E-mail: vladimir.bubanja@callaghaninnovation.govt.nz

    2015-06-15

    We present schemes for quantum teleportation and entanglement swapping of electronic spin states in hybrid superconductor–normal-metal systems. The proposed schemes employ subgap transport whereby the lowest order processes involve Cooper pair-electron and double Cooper-pair cotunneling in quantum teleportation and entanglement swapping protocols, respectively. The competition between elastic cotunneling and Cooper-pair splitting results in the success probability of 25% in both cases. Described implementations of these protocols are within reach of present-day experimental techniques.

  10. User testing and performance evaluation of the Electronic Quality Improvement Platform for Plans and Pharmacies.

    Science.gov (United States)

    Pringle, Janice L; Kearney, Shannon M; Grasso, Kim; Boyer, Annette D; Conklin, Mark H; Szymanski, Keith A

    2015-01-01

    To user-test and evaluate a performance information management platform that makes standardized, benchmarked medication use quality data available to both health plans and community pharmacy organizations. Multiple health/drug plans and multiple chain and independent pharmacies across the United States. During the first phase of the study, user experience was measured via user satisfaction surveys and interviews with key personnel (pharmacists, pharmacy leaders, and health plan leadership). Improvements were subsequently made to the platform based on these findings. During the second phase of the study, the platform was implemented in a greater number of pharmacies and by a greater number of payers. User experience was then reevaluated to gather information for further improvements. The surveys and interviews revealed that users found the Web-based platform easy to use and beneficial in terms of understanding and comparing performance metrics. Primary concerns included lack of access to real-time data and patient-specific data. Many users also expressed uncertainty as to how they could use the information and data provided by the platform. The study findings indicate that while information management platforms can be used effectively in both pharmacy and health plan settings, future development is needed to ensure that the provided data can be transferred to pharmacy best practices and improved quality care.

  11. A hybrid density functional study on the electron and hole trap states in anatase titanium dioxide.

    Science.gov (United States)

    Yamamoto, Takenori; Ohno, Takahisa

    2012-01-14

    We present a theoretical study on electron and hole trap states in the bulk and (001) surface of anatase titanium dioxide using screened hybrid density functional calculations. In both the bulk and surface, calculations suggest that the neutral and ionized oxygen vacancies are possible electron traps. The doubly ionized oxygen vacancy is the most stable in the bulk, and is a candidate for a shallow donor in colorless anatase crystals. The hole trap states are localized at oxygen anions in both the bulk and surface. The self-trapped electron centered at a titanium cation cannot be produced in the bulk, but can be formed at the surface. The electron trap level at the surface oxygen vacancy is consistent with observations by photoelectron spectroscopy. The optical absorptions and luminescence in UV-irradiated anatase nanoparticles are found to come from the surface self-trapped hole and the surface oxygen vacancy.

  12. The nature of excess electrons in anatase and rutile from hybrid DFT and RPA.

    Science.gov (United States)

    Spreafico, Clelia; VandeVondele, Joost

    2014-12-21

    The behavior of excess electrons in undoped and defect free bulk anatase and rutile TiO2 has been investigated by state-of-the-art electronic structure methods including hybrid density functional theory (DFT) and the random phase approximation (RPA). Consistent with experiment, charge trapping and polaron formation is observed in both anatase and rutile. The difference in the anisotropic shape of the polarons is characterized, confirming for anatase the large polaron picture. For anatase, where polaron formation energies are small, charge trapping is observed also with standard hybrid functionals, provided the simulation cell is sufficiently large (864 atoms) to accommodate the lattice relaxation. Even though hybrid orbitals are required as a starting point for RPA in this system, the obtained polaron formation energies are relatively insensitive to the amount of Hartree-Fock exchange employed. The difference in trapping energy between rutile and anatase can be obtained accurately with both hybrid functionals and RPA. Computed activation energies for polaron hopping and delocalization clearly show that anatase and rutile might have different charge transport mechanisms. In rutile, only hopping is likely, whereas in anatase hopping and delocalization are competing. Delocalization will result in conduction-band-like and thus enhanced transport. Anisotropic conduction, in agreement with experimental data, is observed, and results from the tendency to delocalize in the [001] direction in rutile and the (001) plane in anatase. For future work, our calculations serve as a benchmark and suggest RPA on top on hybrid orbitals (PBE0 with 30% Hartree-Fock exchange), as a suitable method to study the rich chemistry and physics of TiO2.

  13. The yeast three-hybrid system as an experimental platform to identify proteins interacting with small signaling molecules in plant cells: Potential and limitations

    Directory of Open Access Journals (Sweden)

    Stéphanie eCottier

    2011-12-01

    Full Text Available Chemical genetics is a powerful scientific strategy that utilizes small bioactive molecules as experimental tools to unravel biological processes. Bioactive compounds occurring in nature represent an enormous diversity of structures that can be used to dissect functions of biological systems. Once the bioactivity of a natural or synthetic compound has been critically evaluated the challenge remains to identify its molecular target and mode of action, which usually is a time consuming and labor-intensive process. To facilitate this task, we decided to implement the yeast three-hybrid (Y3H technology as a general experimental platform to scan the whole Arabidopsis proteome for targets of small signaling molecules. The Y3H technology is based on the yeast two-hybrid system and allows direct cloning of proteins that interact in vivo with a synthetic hybrid ligand, which comprises the biologically active molecule of interest covalently linked to methotrexate (Mtx. In yeast nucleus the hybrid ligand connects two fusion proteins: the Mtx part binding to dihydrofolate reductase fused to a DNA binding domain (encoded in the yeast strain, and the bioactive molecule part binding to its potential protein target fused to a DNA activating domain (encoded on a cDNA expression vector. During cDNA library screening, the formation of this ternary, transcriptional activator complex leads to reporter gene activation in yeast cells, and thereby allows selection of the putative targets of small bioactive molecules of interest. Here we present the strategy and experimental details for construction and application of a Y3H platform, including chemical synthesis of different hybrid ligands, construction of suitable cDNA libraries, the choice of yeast strains, and appropriate screening conditions. Based on the results obtained and the current literature we discussed the perspectives and limitations of the Y3H approach for identifying targets of small bioactive molecules.

  14. The analysis of single-electron orbits in a free electron laser based upon a rectangular hybrid wiggler

    Science.gov (United States)

    Kordbacheh, A.; Ghahremaninezhad, Roghayeh; Maraghechi, B.

    2012-09-01

    A three-dimensional analysis of a novel free-electron laser (FEL) based upon a rectangular hybrid wiggler (RHW) is presented. This RHW is designed in a configuration composed of rectangular rings with alternating ferrite and dielectric spacers immersed in a solenoidal magnetic field. An analytic model of RHW is introduced by solution of Laplace's equation for the magnetostatic fields under the appropriate boundary conditions. The single-electron orbits in combined RHW and axial guide magnetic fields are studied when only the first and the third spatial harmonic components of the RHW field are taken into account and the higher order terms are ignored. The results indicate that the third spatial harmonic leads to group III orbits with a strong negative mass regime particularly in large solenoidal magnetic fields. RHW is found to be a promising candidate with favorable characteristics to be used in microwave FEL.

  15. Diamond nanoparticles as a way to improve electron transfer in sol-gel L-lactate biosensing platforms.

    Science.gov (United States)

    Briones, M; Casero, E; Vázquez, L; Pariente, F; Lorenzo, E; Petit-Domínguez, M D

    2016-02-18

    In the present work, we have included for the first time diamond nanoparticles (DNPs) in a sol-gel matrix derived from (3-mercaptopropyl)-trimethoxysilane (MPTS) in order to improve electron transfer in a lactate oxidase (LOx) based electrochemical biosensing platform. Firstly, an exhaustive AFM study, including topographical, surface potential (KFM) and capacitance gradient (CG) measurements, of each step involved in the biosensing platform development was performed. The platform is based on gold electrodes (Au) modified with the sol-gel matrix (Au/MPTS) in which diamond nanoparticles (Au/MPTS/DNPs) and lactate oxidase (Au/MPTS/DNPs/LOx) have been included. For the sake of comparison, we have also characterized a gold electrode directly modified with DNPs (Au/DNPs). Secondly, the electrochemical behavior of a redox mediator (hydroxymethyl-ferrocene, HMF) was evaluated at the platforms mentioned above. The response of Au/MPTS/DNPs/LOx towards lactate was obtained. A linear concentration range from 0.053 mM to 1.6 mM, a sensitivity of 2.6 μA mM(-1) and a detection limit of 16 μM were obtained. These analytical properties are comparable to other biosensors, presenting also as advantages that DNPs are inexpensive, environment-friendly and easy-handled nanomaterials. Finally, the developed biosensor was applied for lactate determination in wine samples.

  16. Direct switching control of DC-DC power electronic converters using hybrid system theory

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, J.; Lin, F. [Wayne State Univ., Detroit, MI (United States). Dept. of Electrical and Computer Engineering; Wang, C. [Wayne State Univ., Detroit, MI (United States). Dept. of Electrical and Computer Engineering; Wayne State Univ., Detroit, MI (United States). Div. of Engineering Technology

    2010-07-01

    A direct switching control (DSC) scheme for power electronics converters was described. The system was designed for use in both traditional and renewable energy applications as well as in electric drive vehicles. The proposed control scheme was based on a detailed hybrid system converter model that used model predictive control (MPC), piecewise affine (PWA) approximations and constrained optimal control methods. A DC-DC converter was modelled as a hybrid machine. Switching among different modes of the DC-DC converter were modelled as discrete events controlled by the hybrid controller. The modelling scheme was applied to a Buck converter. The DSC was used to control the switch of the power converter based on a hybrid machine model. Results of the study showed that the method can be used to regulate output voltage and inductor currents. The method also provides fast transient responses and effectively regulates both currents and voltage. The controller can be used to provide immediate responses to dynamic disturbances and output voltage fluctuations. 23 refs., 7 figs.

  17. Hybrid density functional study of the structural, bonding, and electronic properties of bismuth vanadate

    Science.gov (United States)

    Kweon, Kyoung E.; Hwang, Gyeong S.

    2012-10-01

    The structure and property prediction of metal oxides can significantly be improved by incorporating exact Hartree-Fock (HF) exchange into density functional theory (DFT), which is the so-called hybrid DFT. We explored the impact of HF exchange inclusion on the predicted structural, bonding, and electronic properties of bismuth vanadate (BiVO4), with particular attention to the difference between its monoclinic and tetragonal scheelite phases. The applied exchange-correlation (xc) functionals include the gradient corrected Perdew-Burke-Ernzerhof (PBE) and the PBE-HF hybrid functionals with HF exchange amounts of 10%, 25%, and 50%. We find that the PBE-HF25% yields a monoclinic structure in very close agreement with the experimentally determined structure, while the PBE-HF50% tends to overestimate the monoclinic distortion and the PBE/PBE-HF10% can hardly identify a distinct monoclinic configuration at ambient conditions. Electronic structure analysis reveals that the increasing monoclinic distortion with the amount of HF exchange is related to the enhancement of hybridization between Bi 6s-O 2p antibonding states and unoccupied Bi 6p states. The bonding mechanisms and band structures of the monoclinic and tetragonal phases of BiVO4 were also investigated, and we discuss how the predictions are sensitive to the xc functional choice.

  18. Electronic structures of one-dimensional metal-molecule hybrid chains studied using scanning tunneling microscopy and density functional theory.

    Science.gov (United States)

    Chung, Kyung-Hoon; Koo, Bon-Gil; Kim, Howon; Yoon, Jong Keon; Kim, Ji-Hoon; Kwon, Young-Kyun; Kahng, Se-Jong

    2012-05-28

    The electronic structures of self-assembled hybrid chains comprising Ag atoms and organic molecules were studied using scanning tunneling microscopy (STM) and spectroscopy (STS) in parallel with density functional theory (DFT). Hybrid chains were prepared by catalytic breaking of Br-C bonds in 4,4″-dibromo-p-terphenyl molecules, followed by spontaneous formation of Ag-C bonds on Ag(111). An atomic model was proposed for the observed hybrid chain structures. Four electronic states were resolved using STS measurements, and strong energy dependence was observed in STM images. These results were explained using first-principles calculations based on DFT.

  19. Application of the Aero-Hydro-Elastic Model, HAWC2-WAMIT, to Offshore Data from Floating Power Plants Hybrid Wind- and Wave-Energy Test Platform, P37

    DEFF Research Database (Denmark)

    Bellew, Sarah; Yde, Anders; Verelst, David Robert

    2014-01-01

    numerical models, which can combine the aerodynamic, hydrodynamic, structural exibility and mooring components. Very little oshore data exists, however, in order to validate these numerical models. Floating Power Plant are the developers of a oating, hybrid wind- and wave-energy device. The device uses...... full-scale prototype, the P80, which has a width of 80 m. As part of the development, Floating Power Plant have completed 4 oshore test-phases (totalling over 2 years oshore operation) on a 37 m wide scaled test device, the P37. This paper focuses on the comparison of one of the leading numerical...... the pitching wave energy devices, not only to increase and smooth the power output from the platform, but also to take the energy from the waves in a controlled manner, resulting in a stable platform for the wind turbine and a safe harbour for O&M. They are currently developing the nal design for their rst...

  20. Femtosecond spectroscopic studies of photoinduced electron transfer in MDMO-PPV:ZnO hybrid bulk heterojunctions

    Energy Technology Data Exchange (ETDEWEB)

    Cecchetto, E.; De Cola, L. [Institute of Physics, University of Muenster, Mendelstrasse 7, 48149 Muenster (Germany); Slooff, H. [ECN Solar Energy, P.O. Box 1, 1755 ZG Petten (Netherlands); Zhang, H. [Van ' t Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam (Netherlands)

    2007-01-15

    The photophysics of charge carriers (polaron) in MDMO-PPV:ZnO hybrid bulk heterojunction is studied at 80 K by femtosecond transient absorption spectroscopy. A short-lived positive polaron is observed in the blend phase in MDMO-PPV:ZnO blend films with a weight ratio of 1:1 and 1:2. Further increase of ZnO weight ratio results in a significant quenching of the polaron absorption. The results are discussed in the concept that both pristine polymer and MDMO-PPV:ZnO blend phases coexist in the blend films. It is concluded that a polaron is photogenerated within the excitation laser pulse (<100 fs) and electron transfer efficiency is highest in blend films 1:1 and 1:2. Lack of the interfacial area and faster back electron transfer process are discussed to be responsible for the quenching of the electron transfer efficiency in blend film 1:3.

  1. A linear dispersion relation for the hybrid kinetic-ion/fluid-electron model of plasma physics

    CERN Document Server

    Told, Daniel; Astfalk, Patrick; Jenko, Frank

    2016-01-01

    A dispersion relation for a commonly used hybrid model of plasma physics is developed, which combines fully kinetic ions and a massless-electron fluid description. Although this model and variations of it have been used to describe plasma phenomena for about 40 years, to date there exists no general dispersion relation to describe the linear wave physics contained in the model. Previous efforts along these lines are extended here to retain arbitrary wave propagation angles, temperature anisotropy effects, as well as additional terms in the generalized Ohm's law which determines the electric field. A numerical solver for the dispersion relation is developed, and linear wave physics is benchmarked against solutions of a full Vlasov-Maxwell dispersion relation solver. This work opens the door to a more accurate interpretation of existing and future wave and turbulence simulations using this type of hybrid model.

  2. Diamond nanoparticles as a way to improve electron transfer in sol–gel L-lactate biosensing platforms

    Energy Technology Data Exchange (ETDEWEB)

    Briones, M.; Casero, E. [Departamento de Química Analítica y Análisis Instrumental, Facultad de Ciencias, c/Francisco Tomás y Valiente, No7, Campus de Excelencia de la Universidad Autónoma de Madrid, 28049 Madrid (Spain); Vázquez, L. [Instituto de Ciencia de Materiales de Madrid (CSIC), c/Sor Juana Inés de la Cruz No3, Campus de Excelencia de la Universidad Autónoma de Madrid, 28049 Madrid (Spain); Pariente, F.; Lorenzo, E. [Departamento de Química Analítica y Análisis Instrumental, Facultad de Ciencias, c/Francisco Tomás y Valiente, No7, Campus de Excelencia de la Universidad Autónoma de Madrid, 28049 Madrid (Spain); Petit-Domínguez, M.D., E-mail: mdolores.petit@uam.es [Departamento de Química Analítica y Análisis Instrumental, Facultad de Ciencias, c/Francisco Tomás y Valiente, No7, Campus de Excelencia de la Universidad Autónoma de Madrid, 28049 Madrid (Spain)

    2016-02-18

    In the present work, we have included for the first time diamond nanoparticles (DNPs) in a sol–gel matrix derived from (3-mercaptopropyl)-trimethoxysilane (MPTS) in order to improve electron transfer in a lactate oxidase (LOx) based electrochemical biosensing platform. Firstly, an exhaustive AFM study, including topographical, surface potential (KFM) and capacitance gradient (CG) measurements, of each step involved in the biosensing platform development was performed. The platform is based on gold electrodes (Au) modified with the sol–gel matrix (Au/MPTS) in which diamond nanoparticles (Au/MPTS/DNPs) and lactate oxidase (Au/MPTS/DNPs/LOx) have been included. For the sake of comparison, we have also characterized a gold electrode directly modified with DNPs (Au/DNPs). Secondly, the electrochemical behavior of a redox mediator (hydroxymethyl-ferrocene, HMF) was evaluated at the platforms mentioned above. The response of Au/MPTS/DNPs/LOx towards lactate was obtained. A linear concentration range from 0.053 mM to 1.6 mM, a sensitivity of 2.6 μA mM{sup −1} and a detection limit of 16 μM were obtained. These analytical properties are comparable to other biosensors, presenting also as advantages that DNPs are inexpensive, environment-friendly and easy-handled nanomaterials. Finally, the developed biosensor was applied for lactate determination in wine samples. - Highlights: • We have included for the first time diamond nanoparticles (DNPs) in a sol–gel matrix for developing lactate biosensors. • DNPs facilitate electron-transfer within the sol–gel network in electrochemical biosensors. • Lactate biosensors show good sensitivity, detection limit, reproducibility and stability.

  3. Resonance Energy Transfer-Based Nucleic Acid Hybridization Assays on Paper-Based Platforms Using Emissive Nanoparticles as Donors.

    Science.gov (United States)

    Doughan, Samer; Noor, M Omair; Han, Yi; Krull, Ulrich J

    2017-01-01

    Quantum dots (QDs) and upconverting nanoparticles (UCNPs) are luminescent nanoparticles (NPs) commonly used in bioassays and biosensors as resonance energy transfer (RET) donors. The narrow and tunable emissions of both QDs and UCNPs make them versatile RET donors that can be paired with a wide range of acceptors. Ratiometric signal processing that compares donor and acceptor emission in RET-based transduction offers improved precision, as it accounts for fluctuations in the absolute photoluminescence (PL) intensities of the donor and acceptor that can result from experimental and instrumental variations. Immobilizing NPs on a solid support avoids problems such as those that can arise with their aggregation in solution, and allows for facile layer-by-layer assembly of the interfacial chemistry. Paper is an attractive solid support for the development of point-of-care diagnostic assays given its ubiquity, low-cost, and intrinsic fluid transport by capillary action. Integration of nanomaterials with paper-based analytical devices (PADs) provides avenues to augment the analytical performance of PADs, given the unique optoelectronic properties of nanomaterials. Herein, we describe methodology for the development of PADs using QDs and UCNPs as RET donors for optical transduction of nucleic acid hybridization. Immobilization of green-emitting QDs (gQDs) on imidazole functionalized cellulose paper is described for use as RET donors with Cy3 molecular dye as acceptors for the detection of SMN1 gene fragment. We also describe the covalent immobilization of blue-emitting UCNPs on aldehyde modified cellulose paper for use as RET donors with orange-emitting QDs (oQDs) as acceptors for the detection of HPRT1 gene fragment. The data described herein is acquired using an epifluorescence microscope, and can also be collected using technology such as a typical electronic camera.

  4. Hybrid two-dimensional electronic systems and other applications of sp-2 bonded light elements

    Science.gov (United States)

    Kessler, Brian Maxwell

    The field-effect is a cornerstone of modern technology lying at the heart of transistors in consumer electronics. Experimentally, it allows one to continuously vary the carrier concentration in a material while studying its properties. The recent isolation of graphene, the first truly two-dimensional crystal, allows application of the field effect to a much wider range of physical situations. In the first part of the thesis, we investigate hybrid materials formed by coupling metals to the two-dimensional electron gas (2DEG) in graphene. We couple superconducting materials to the graphene sheet by cluster deposition. This material displays a superconducting phase whose properties are tuned by the carrier density via the field effect. The transition temperature is well-described by Berezinskii-Kosterlitz-Thouless vortex unbinding. The ground state properties show interesting effects due to the distribution of cluster spacings. Observations related to other hybrid electronic systems including ferromagnets and normal metals are presented. The second part of this thesis involves energy applications of light element materials. The mechanisms affecting coating of carbon nanotubes using atomic layer deposition is developed and applied to photovoltaic systems. The gas adsorption properties of activated boron nitride are investigated and the relative influence of surface area and hydrogen binding affinity is elaborated. The third part of this thesis explores electromechanical properties of suspended graphene membranes. We investigate buckling and strain in exfoliated graphene membranes as well as their deformation under an applied gate potential.

  5. Fluorescent Nanodiamond-Gold Hybrid Particles for Multimodal Optical and Electron Microscopy Cellular Imaging.

    Science.gov (United States)

    Liu, Weina; Naydenov, Boris; Chakrabortty, Sabyasachi; Wuensch, Bettina; Hübner, Kristina; Ritz, Sandra; Cölfen, Helmut; Barth, Holger; Koynov, Kaloian; Qi, Haoyuan; Leiter, Robert; Reuter, Rolf; Wrachtrup, Jörg; Boldt, Felix; Scheuer, Jonas; Kaiser, Ute; Sison, Miguel; Lasser, Theo; Tinnefeld, Philip; Jelezko, Fedor; Walther, Paul; Wu, Yuzhou; Weil, Tanja

    2016-10-12

    There is a continuous demand for imaging probes offering excellent performance in various microscopy techniques for comprehensive investigations of cellular processes by more than one technique. Fluorescent nanodiamond-gold nanoparticles (FND-Au) constitute a new class of "all-in-one" hybrid particles providing unique features for multimodal cellular imaging including optical imaging, electron microscopy, and, and potentially even quantum sensing. Confocal and optical coherence microscopy of the FND-Au allow fast investigations inside living cells via emission, scattering, and photothermal imaging techniques because the FND emission is not quenched by AuNPs. In electron microscopy, transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) analysis of FND-Au reveals greatly enhanced contrast due to the gold particles as well as an extraordinary flickering behavior in three-dimensional cellular environments originating from the nanodiamonds. The unique multimodal imaging characteristics of FND-Au enable detailed studies inside cells ranging from statistical distributions at the entire cellular level (micrometers) down to the tracking of individual particles in subcellular organelles (nanometers). Herein, the processes of endosomal membrane uptake and release of FNDs were elucidated for the first time by the imaging of individual FND-Au hybrid nanoparticles with single-particle resolution. Their convenient preparation, the availability of various surface groups, their flexible detection modalities, and their single-particle contrast in combination with the capability for endosomal penetration and low cytotoxicity make FND-Au unique candidates for multimodal optical-electronic imaging applications with great potential for emerging techniques, such as quantum sensing inside living cells.

  6. A CMOS-compatible silicon photonic platform for high-speed integrated opto-electronics

    Science.gov (United States)

    Galland, Christophe; Novack, Ari; Liu, Yang; Ding, Ran; Gould, Michael; Baehr-Jones, Tom; Li, Qi; Yang, Yisu; Ma, Yangjin; Zhang, Yi; Padmaraju, Kishore; Bergmen, Keren; Lim, Andy Eu-Jin; Lo, Guo-Qiang; Hochberg, Michael

    2013-05-01

    We have developed a CMOS-compatible Silicon-on-Insulator photonic platform featuring active components such as pi- n and photoconductive (MIM) Ge-on-Si detectors, p-i-n ring and Mach-Zehnder modulators, and traveling-wave modulators based on a p-n junction driven by an RF transmission line. We have characterized the yield and uniformity of the performance through automated cross-wafer testing, demonstrating that our process is reliable and scalable. The entire platform is capable of more than 40 GB/s data rate. Fabricated at the IME/A-STAR foundry in Singapore, it is available to the worldwide community through OpSIS, a successful multi-project wafer service based at the University of Delaware. After exposing the design, fabrication and performance of the most advanced platform components, we present our newest results obtained after the first public run. These include low loss passives (Y-junctions: 0.28 dB; waveguide crossings: 0.18 dB and cross-talk -41+/-2 dB; non-uniform grating couplers: 3.2+/-0.2 dB). All these components were tested across full 8" wafers and exhibited remarkable uniformity. The active devices were improved from the previous design kit to exhibit 3dB bandwidths ranging from 30 GHz (modulators) to 58 GHz (detectors). We also present new packaging services available to OpSIS users: vertical fiber coupling and edge coupling.

  7. Donor-acceptor graphene-based hybrid materials facilitating photo-induced electron-transfer reactions.

    Science.gov (United States)

    Stergiou, Anastasios; Pagona, Georgia; Tagmatarchis, Nikos

    2014-01-01

    Graphene research and in particular the topic of chemical functionalization of graphene has exploded in the last decade. The main aim is to increase the solubility and thereby enhance the processability of the material, which is otherwise insoluble and inapplicable for technological applications when stacked in the form of graphite. To this end, initially, graphite was oxidized under harsh conditions to yield exfoliated graphene oxide sheets that are soluble in aqueous media and amenable to chemical modifications due to the presence of carboxylic acid groups at the edges of the lattice. However, it was obvious that the high-defect framework of graphene oxide cannot be readily utilized in applications that are governed by charge-transfer processes, for example, in solar cells. Alternatively, exfoliated graphene has been applied toward the realization of some donor-acceptor hybrid materials with photo- and/or electro-active components. The main body of research regarding obtaining donor-acceptor hybrid materials based on graphene to facilitate charge-transfer phenomena, which is reviewed here, concerns the incorporation of porphyrins and phthalocyanines onto graphene sheets. Through illustrative schemes, the preparation and most importantly the photophysical properties of such graphene-based ensembles will be described. Important parameters, such as the generation of the charge-separated state upon photoexcitation of the organic electron donor, the lifetimes of the charge-separation and charge-recombination as well as the incident-photon-to-current efficiency value for some donor-acceptor graphene-based hybrids, will be discussed.

  8. Hybrid Numerical Solvers for Massively Parallel Eigenvalue Computation and Their Benchmark with Electronic Structure Calculations

    CERN Document Server

    Imachi, Hiroto

    2015-01-01

    Optimally hybrid numerical solvers were constructed for massively parallel generalized eigenvalue problem (GEP).The strong scaling benchmark was carried out on the K computer and other supercomputers for electronic structure calculation problems in the matrix sizes of M = 10^4-10^6 with upto 105 cores. The procedure of GEP is decomposed into the two subprocedures of the reducer to the standard eigenvalue problem (SEP) and the solver of SEP. A hybrid solver is constructed, when a routine is chosen for each subprocedure from the three parallel solver libraries of ScaLAPACK, ELPA and EigenExa. The hybrid solvers with the two newer libraries, ELPA and EigenExa, give better benchmark results than the conventional ScaLAPACK library. The detailed analysis on the results implies that the reducer can be a bottleneck in next-generation (exa-scale) supercomputers, which indicates the guidance for future research. The code was developed as a middleware and a mini-application and will appear online.

  9. Highly transparent, low-haze, hybrid cellulose nanopaper as electrodes for flexible electronics.

    Science.gov (United States)

    Xu, Xuezhu; Zhou, Jian; Jiang, Long; Lubineau, Gilles; Ng, Tienkhee; Ooi, Boon S; Liao, Hsien-Yu; Shen, Chao; Chen, Long; Zhu, J Y

    2016-06-16

    Paper is an excellent candidate to replace plastics as a substrate for flexible electronics due to its low cost, renewability and flexibility. Cellulose nanopaper (CNP), a new type of paper made of nanosized cellulose fibers, is a promising substrate material for transparent and flexible electrodes due to its potentially high transparency and high mechanical strength. Although CNP substrates can achieve high transparency, they are still characterized by high diffuse transmittance and small direct transmittance, resulting in high optical haze of the substrates. In this study, we proposed a simple methodology for large-scale production of high-transparency, low-haze CNP comprising both long cellulose nanofibrils (CNFs) and short cellulose nanocrystals (CNCs). By varying the CNC/CNF ratio in the hybrid CNP, we could tailor its total transmittance, direct transmittance and diffuse transmittance. By increasing the CNC content, the optical haze of the hybrid CNP could be decreased and its transparency could be increased. The direct transmittance and optical haze of the CNP were 75.1% and 10.0%, respectively, greatly improved from the values of previously reported CNP (31.1% and 62.0%, respectively). Transparent, flexible electrodes were fabricated by coating the hybrid CNP with silver nanowires (AgNWs). The electrodes showed a low sheet resistance (minimum 1.2 Ω sq(-1)) and a high total transmittance (maximum of 82.5%). The electrodes were used to make a light emitting diode (LED) assembly to demonstrate their potential use in flexible displays.

  10. An electrochemical immunosensor for sensitive detection of Escherichia coli O157:H7 by using chitosan, MWCNT, polypyrrole with gold nanoparticles hybrid sensing platform.

    Science.gov (United States)

    Güner, Ahmet; Çevik, Emre; Şenel, Mehmet; Alpsoy, Lokman

    2017-08-15

    An electrochemical immunosensor for the common food pathogen Escherichia coli O157:H7 was developed. This novel immunosensor based on the PPy/AuNP/MWCNT/Chi hybrid bionanocomposite modified pencil graphite electrode (PGE). This hybrid bionanocomposite platform was modified with anti-E. coli O157:H7 monoclonal antibody. The prepared bionanocomposite platform and immunosensor was characterized by using cyclic voltammetry (CV). Under the optimum conditions, the results have shown the order of the preferential selectivity of the method is gram negative pathogenic species E. coli O157:H7. Concentrations of E. coli O157:H7 from 3×10(1) to 3×10(7)cfu/mL could be detected. The detection limit was ∼30cfu/mL in PBS buffer. Briefly, we developed a high sensitive electrochemical immunosensor for specific detection of E. coli O157:H7 contamination with the use of sandwich assay evaluated in this study offered a reliable means of quantification of the bacteria. For the applications in food quality and safety control, our immunosensor showed reproducibility and stability. Copyright © 2017. Published by Elsevier Ltd.

  11. A hybrid electron donor comprising cyclopentadithiophene and dithiafulvenyl for dye-sensitized solar cells

    Directory of Open Access Journals (Sweden)

    Gleb Sorohhov

    2015-06-01

    Full Text Available Two new photosensitizers featured with a cyanoacrylic acid electron acceptor (A and a hybrid electron donor (D of cyclopentadithiophene and dithiafulvenyl, either directly linked or separated by a phenyl ring, were synthesized and characterized. Both of them undergo two reversible oxidations and strongly absorb in the visible spectral region due to a photo-induced intramolecular charge-transfer (ICT transition. To a great extent, the electronic interaction between the D and A units is affected by the presence of a phenyl spacer. Without a phenyl ring, the D unit appears more difficult to oxidize due to a strong electron-withdrawing effect of the A moiety. In sharp contrast, the insertion of the phenyl ring between the D and A units leads to a broken π-conjugation and therefore, the oxidation potentials remain almost unchanged compared to those of an analogue without the A group, suggesting that the electronic coupling between D and A units is relatively weak. As a consequence, the lowest-energy absorption band shows a slight hypsochromic shift upon the addition of the phenyl spacer, indicative of an increased HOMO–LUMO gap. In turn, the direct linkage of D and A units leads to an effective π-conjugation, thus substantially lowering the HOMO–LUMO gap. Moreover, the application in dye-sensitized solar cells was investigated, showing that the power conversion efficiency increases by the insertion of the phenyl unit.

  12. A hybrid electron donor comprising cyclopentadithiophene and dithiafulvenyl for dye-sensitized solar cells.

    Science.gov (United States)

    Sorohhov, Gleb; Yi, Chenyi; Grätzel, Michael; Decurtins, Silvio; Liu, Shi-Xia

    2015-01-01

    Two new photosensitizers featured with a cyanoacrylic acid electron acceptor (A) and a hybrid electron donor (D) of cyclopentadithiophene and dithiafulvenyl, either directly linked or separated by a phenyl ring, were synthesized and characterized. Both of them undergo two reversible oxidations and strongly absorb in the visible spectral region due to a photo-induced intramolecular charge-transfer (ICT) transition. To a great extent, the electronic interaction between the D and A units is affected by the presence of a phenyl spacer. Without a phenyl ring, the D unit appears more difficult to oxidize due to a strong electron-withdrawing effect of the A moiety. In sharp contrast, the insertion of the phenyl ring between the D and A units leads to a broken π-conjugation and therefore, the oxidation potentials remain almost unchanged compared to those of an analogue without the A group, suggesting that the electronic coupling between D and A units is relatively weak. As a consequence, the lowest-energy absorption band shows a slight hypsochromic shift upon the addition of the phenyl spacer, indicative of an increased HOMO-LUMO gap. In turn, the direct linkage of D and A units leads to an effective π-conjugation, thus substantially lowering the HOMO-LUMO gap. Moreover, the application in dye-sensitized solar cells was investigated, showing that the power conversion efficiency increases by the insertion of the phenyl unit.

  13. Tunable Radiation Response in Hybrid Organic-Inorganic Gate Dielectrics for Low-Voltage Graphene Electronics.

    Science.gov (United States)

    Arnold, Heather N; Cress, Cory D; McMorrow, Julian J; Schmucker, Scott W; Sangwan, Vinod K; Jaber-Ansari, Laila; Kumar, Rajan; Puntambekar, Kanan P; Luck, Kyle A; Marks, Tobin J; Hersam, Mark C

    2016-03-01

    Solution-processed semiconductor and dielectric materials are attractive for future lightweight, low-voltage, flexible electronics, but their response to ionizing radiation environments is not well understood. Here, we investigate the radiation response of graphene field-effect transistors employing multilayer, solution-processed zirconia self-assembled nanodielectrics (Zr-SANDs) with ZrOx as a control. Total ionizing dose (TID) testing is carried out in situ using a vacuum ultraviolet source to a total radiant exposure (RE) of 23.1 μJ/cm(2). The data reveal competing charge density accumulation within and between the individual dielectric layers. Additional measurements of a modified Zr-SAND show that varying individual layer thicknesses within the gate dielectric tuned the TID response. This study thus establishes that the radiation response of graphene electronics can be tailored to achieve a desired radiation sensitivity by incorporating hybrid organic-inorganic gate dielectrics.

  14. Role of Microstructure in the Electron-Hole Interaction of Hybrid Lead-Halide Perovskites

    Science.gov (United States)

    Frost, Jarvist M.; Barker, Alex J.; De Bastiani, Michele; Gandini, Marina; Marras, Sergio; Lanzani, Guglielmo; Walsh, Aron; Petrozza, Annamaria

    2015-01-01

    Solar cells based on hybrid inorganic-organic halide perovskites have demonstrated high power conversion efficiencies in a range of architectures. The existence and stability of bound electron-hole pairs in these materials, and their role in the exceptional performance of optoelectronic devices, remains a controversial issue. Here we demonstrate, through a combination of optical spectroscopy and multiscale modeling as a function of the degree of polycrystallinity and temperature, that the electron-hole interaction is sensitive to the microstructure of the material. The long-range order is disrupted by polycrystalline disorder and the variations in electrostatic potential found for smaller crystals suppress exciton formation, while larger crystals of the same composition demonstrate an unambiguous excitonic state. We conclude that fabrication procedures and morphology strongly influence perovskite behaviour, with both free carrier and excitonic regimes possible, with strong implications for optoelectronic devices. PMID:26442125

  15. Hybrid bio-organic interfaces with matchable nanoscale topography for durable high extracellular electron transfer activity.

    Science.gov (United States)

    Ding, Chunmei; Liu, Huan; Lv, Meiling; Zhao, Tianyi; Zhu, Ying; Jiang, Lei

    2014-07-21

    Here, we developed a novel hybrid bio-organic interface with matchable nano-scale topography between a polypyrrole nanowire array (PPy-NA) and the bacterium Shewanella, which enabled a remarkably increased extracellular electron transfer (EET) current from genus Shewanella over a rather long period. PPy-NA thus exhibited outstanding performance in mediating bacterial EET, which was superior to normal electrodes such as carbon plates, Au and tin-doped In₂O₃. It was proposed that the combined effect of the inherent electrochemical nature of PPy and the porous structured bacterial network that was generated on the PPy-NA enabled long-term stability, while the high efficiency was attributed to the enhanced electron transfer rate between PPy-NA and microbes caused by the enhanced local topological interactions.

  16. Role of Microstructure in the Electron-Hole Interaction of Hybrid Lead-Halide Perovskites.

    Science.gov (United States)

    Grancini, Giulia; Srimath Kandada, Ajay Ram; Frost, Jarvist M; Barker, Alex J; De Bastiani, Michele; Gandini, Marina; Marras, Sergio; Lanzani, Guglielmo; Walsh, Aron; Petrozza, Annamaria

    2015-10-01

    Solar cells based on hybrid inorganic-organic halide perovskites have demonstrated high power conversion efficiencies in a range of architectures. The existence and stability of bound electron-hole pairs in these materials, and their role in the exceptional performance of optoelectronic devices, remains a controversial issue. Here we demonstrate, through a combination of optical spectroscopy and multiscale modeling as a function of the degree of polycrystallinity and temperature, that the electron-hole interaction is sensitive to the microstructure of the material. The long-range order is disrupted by polycrystalline disorder and the variations in electrostatic potential found for smaller crystals suppress exciton formation, while larger crystals of the same composition demonstrate an unambiguous excitonic state. We conclude that fabrication procedures and morphology strongly influence perovskite behaviour, with both free carrier and excitonic regimes possible, with strong implications for optoelectronic devices.

  17. Detection of secondary electrons with pixelated hybrid semiconductor detectors; Sekundaerelektronennachweis mit pixelierten hybriden Halbleiterdetektoren

    Energy Technology Data Exchange (ETDEWEB)

    Gebert, Ulrike Sonja

    2011-09-14

    Within the scope of this thesis, secondary electrons were detected with a pixelated semiconductor detector named Timepix. The Timepix detector consists of electronics and a sensor made from a semiconductor material. The connection of sensor and electronics is done for each pixel individually using bump bonds. Electrons with energies above 3 keV can be detected with the sensor. One electron produces a certain amount of electron-hole pairs according to its energy. The charge then drifts along an electric field to the pixel electronics, where it induces an electric signal. Even without a sensor it is possible to detect an electric signal from approximately 1000 electrons directly in the pixel electronics. Two different detector systems to detect secondary electrons using the Timepix detector were investigated during this thesis. First of all, a hybrid photon detector (HPD) was used to detect single photoelectrons. The HPD consists of a vacuum vessel with an entrance window and a cesium iodine photocathode at the inner surface of the window. Photoelectrons are released from the photocathode by incident light and are accelerated in an electric field towards the Timepix detector, where the point of interaction and the arrival time of the electron is determined. With a proximity focusing setup, a time resolution of 12 ns (with an acceleration voltage of 20 kV between photocathode and Timepix detector) was obtained. The HPD examined in this thesis showed a strong dependence of the dark rate form the acceleration voltage and the pressure in the vacuum vessel. At a pressure of few 10{sup -5} mbar and an acceleration voltage of 20 kV, the dark rate was about 800 Hz per mm{sup 2} area of the read out photocathode. One possibility to reduce the dark rate is to identify ion feedback events. With a slightly modified setup it was possible to reduce the dark rate to 0.5 Hz/mm{sup 2}. To achieve this, a new photocathode was mounted in a shorter distance to the detector. The

  18. Ratiometric fluorescence transduction by hybridization after isothermal amplification for determination of zeptomole quantities of oligonucleotide biomarkers with a paper-based platform and camera-based detection

    Energy Technology Data Exchange (ETDEWEB)

    Noor, M. Omair; Hrovat, David [Chemical Sensors Group, Department of Chemical and Physical Sciences, University of Toronto Mississauga, 3359 Mississauga Road, Mississauga, ON L5L 1C6 (Canada); Moazami-Goudarzi, Maryam [Department of Cell and Systems Biology, University of Toronto Mississauga, 3359 Mississauga Road, Mississauga, ON L5L 1C6 (Canada); Espie, George S. [Department of Cell and Systems Biology, University of Toronto Mississauga, 3359 Mississauga Road, Mississauga, ON L5L 1C6 (Canada); Department of Biology, University of Toronto Mississauga, 3359 Mississauga Road, Mississauga, ON L5L 1C6 (Canada); Krull, Ulrich J., E-mail: ulrich.krull@utoronto.ca [Chemical Sensors Group, Department of Chemical and Physical Sciences, University of Toronto Mississauga, 3359 Mississauga Road, Mississauga, ON L5L 1C6 (Canada)

    2015-07-23

    Highlights: • Solid-phase QD-FRET transduction of isothermal tHDA amplicons on paper substrates. • Ratiometric QD-FRET transduction improves assay precision and lowers the detection limit. • Zeptomole detection limit by an iPad camera after isothermal amplification. • Tunable assay sensitivity by immobilizing different amounts of QD–probe bioconjugates. - Abstract: Paper is a promising platform for the development of decentralized diagnostic assays owing to the low cost and ease of use of paper-based analytical devices (PADs). It can be challenging to detect on PADs very low concentrations of nucleic acid biomarkers of lengths as used in clinical assays. Herein we report the use of thermophilic helicase-dependent amplification (tHDA) in combination with a paper-based platform for fluorescence detection of probe-target hybridization. Paper substrates were patterned using wax printing. The cellulosic fibers were chemically derivatized with imidazole groups for the assembly of the transduction interface that consisted of immobilized quantum dot (QD)–probe oligonucleotide conjugates. Green-emitting QDs (gQDs) served as donors with Cy3 as the acceptor dye in a fluorescence resonance energy transfer (FRET)-based transduction method. After probe-target hybridization, a further hybridization event with a reporter sequence brought the Cy3 acceptor dye in close proximity to the surface of immobilized gQDs, triggering a FRET sensitized emission that served as an analytical signal. Ratiometric detection was evaluated using both an epifluorescence microscope and a low-cost iPad camera as detectors. Addition of the tHDA method for target amplification to produce sequences of ∼100 base length allowed for the detection of zmol quantities of nucleic acid targets using the two detection platforms. The ratiometric QD-FRET transduction method not only offered improved assay precision, but also lowered the limit of detection of the assay when compared with the non

  19. Camera-based ratiometric fluorescence transduction of nucleic acid hybridization with reagentless signal amplification on a paper-based platform using immobilized quantum dots as donors.

    Science.gov (United States)

    Noor, M Omair; Krull, Ulrich J

    2014-10-21

    Paper-based diagnostic assays are gaining increasing popularity for their potential application in resource-limited settings and for point-of-care screening. Achievement of high sensitivity with precision and accuracy can be challenging when using paper substrates. Herein, we implement the red-green-blue color palette of a digital camera for quantitative ratiometric transduction of nucleic acid hybridization on a paper-based platform using immobilized quantum dots (QDs) as donors in fluorescence resonance energy transfer (FRET). A nonenzymatic and reagentless means of signal enhancement for QD-FRET assays on paper substrates is based on the use of dry paper substrates for data acquisition. This approach offered at least a 10-fold higher assay sensitivity and at least a 10-fold lower limit of detection (LOD) as compared to hydrated paper substrates. The surface of paper was modified with imidazole groups to assemble a transduction interface that consisted of immobilized QD-probe oligonucleotide conjugates. Green-emitting QDs (gQDs) served as donors with Cy3 as an acceptor. A hybridization event that brought the Cy3 acceptor dye in close proximity to the surface of immobilized gQDs was responsible for a FRET-sensitized emission from the acceptor dye, which served as an analytical signal. A hand-held UV lamp was used as an excitation source and ratiometric analysis using an iPad camera was possible by a relative intensity analysis of the red (Cy3 photoluminescence (PL)) and green (gQD PL) color channels of the digital camera. For digital imaging using an iPad camera, the LOD of the assay in a sandwich format was 450 fmol with a dynamic range spanning 2 orders of magnitude, while an epifluorescence microscope detection platform offered a LOD of 30 fmol and a dynamic range spanning 3 orders of magnitude. The selectivity of the hybridization assay was demonstrated by detection of a single nucleotide polymorphism at a contrast ratio of 60:1. This work provides an

  20. Design of hybrid sol gel films for direct x-ray and electron beam nanopatterning

    Science.gov (United States)

    Brusatin, Giovanna; Della Giustina, Gioia; Romanato, Filippo; Guglielmi, Massimo

    2008-04-01

    New epoxy based sol-gel organic inorganic materials, showing lithographic resist-like properties without the addition of any photocatalysts, are presented. To obtain a material sensitive to radiation, specific sol-gel syntheses based on an organically modified alkoxide containing an epoxy ring, 3-glycidoxypropyltrimethoxysilane (GPTMS), have been developed. The synthesis and the patternability of hybrid materials have been obtained controlling the inorganic crosslinking degree and with an almost total absence of organic polymerization. Two examples of directly patternable hybrid films, called GB and GGe, have been synthesized using acidic (GGe) and basic (GB) conditions and obtaining different compositions. After electron beam lithography (EBL) or x-ray synchrotron radiation lithography (XRL) the polymerization of the organic component of the sol-gel film occurs, generating a hardening of the structure after post-exposure baking. The exposed polymerized material becomes insoluble, determining a negative resist-like behaviour of the film: the lithographic process of nanopatterning results from the dissolution of the unexposed areas in proper solvents (developers). Spatial resolution of the order of 200 nm is reported and a contrast of 2.2 is achieved. The novelty of this work is that epoxy based materials, which have enhanced thermomechanical stability with respect to the more usual acrylic based resins, are directly nanopatterned for the first time by electron beam (EB) and/or x-ray beam radiation exposure without the aid of catalysts for polymerization. In contrast to common resists that are sacrificial layers of the fabrication process, direct patternable sol-gel hybrids constitute the final material of the devices. In fact, an example of doping with a light emitting dye is reported together with the achievement of directly patterned structures by EBL and XRL.

  1. Hybrid CIS-DFT method to study electric field effects on electronic excited states of ethylene

    Institute of Scientific and Technical Information of China (English)

    Ma Mei-Zhong; Zhu Zheng-He; Chen Xiao-Jun; Xu Guo-Liang; Zhang Yong-Bin; Mao Hua-Ping; Shen Xiao-Hong

    2005-01-01

    The present work is devoted to the study of the effects of external dipole electric field on the molecular structure of ethylene using a hybrid method which combines the single-excitation configuration interactions (CIS) with density functional theory (DFT), i.e. CIS-DFT(B3LYP). It is found that the effects of electric dipole field on the molecular geometry (D2h, D2d and C2v), dipole moment, transition dipole moment, polarizability and, particularly, excitation energy of ethylene are remarkable. The advantages of the hybrid CIS-DFT method are that it can determine the symmetry of molecule and the correct order of excitation as well as the Molecular Orbital (MO) electron configuration;thereby the electronic excitation states of ethylene are easily derived, and most of them are in agreement with those obtained in experiments or references. It may be the first time the effects of external electric field on ethylene molecule have been considered. Compared with other ab initio methods, the CIS-DFT method is relatively accurate and low cost in computation. We expect that it can be used to study other closed-shell molecules.

  2. SMART on FHIR: a standards-based, interoperable apps platform for electronic health records.

    Science.gov (United States)

    Mandel, Joshua C; Kreda, David A; Mandl, Kenneth D; Kohane, Isaac S; Ramoni, Rachel B

    2016-09-01

    In early 2010, Harvard Medical School and Boston Children's Hospital began an interoperability project with the distinctive goal of developing a platform to enable medical applications to be written once and run unmodified across different healthcare IT systems. The project was called Substitutable Medical Applications and Reusable Technologies (SMART). We adopted contemporary web standards for application programming interface transport, authorization, and user interface, and standard medical terminologies for coded data. In our initial design, we created our own openly licensed clinical data models to enforce consistency and simplicity. During the second half of 2013, we updated SMART to take advantage of the clinical data models and the application-programming interface described in a new, openly licensed Health Level Seven draft standard called Fast Health Interoperability Resources (FHIR). Signaling our adoption of the emerging FHIR standard, we called the new platform SMART on FHIR. We introduced the SMART on FHIR platform with a demonstration that included several commercial healthcare IT vendors and app developers showcasing prototypes at the Health Information Management Systems Society conference in February 2014. This established the feasibility of SMART on FHIR, while highlighting the need for commonly accepted pragmatic constraints on the base FHIR specification. In this paper, we describe the creation of SMART on FHIR, relate the experience of the vendors and developers who built SMART on FHIR prototypes, and discuss some challenges in going from early industry prototyping to industry-wide production use. © The Author 2016. Published by Oxford University Press on behalf of the American Medical Informatics Association.

  3. Design of Experimental Platform for Wind/Solar/Battery Hybrid Power System%风光储发电系统实验平台设计

    Institute of Scientific and Technical Information of China (English)

    李凯; 邹见效; 郑宏

    2012-01-01

    An experimental platform about wind/solar/battery hybrid power system with 1KW is designed in this paper.It consists of wind turbine,solar panel,wind/solar controller,battery,converter and AC-load.Some important experiments could be implemented on this platform,such as the tracking of maximum power point of wind power and solar power,charge and discharge management of battery,the output waveform of converter,and so on.This experimental platform shows many advantages in visualization and pertinence,which is very suitable for some designable experiments.%设计开发了一套1kW的风光储发电系统实验平台。该平台由风力发电机、太阳能电池板、风光互补控制器、蓄电池、单相逆变器和交流负载组成,实验平台可以实现风能和太阳能的最大功率跟踪、蓄电池的充放电管理、逆变的波形控制等功能。该实验平台直观形象,针对性强,适合开展多种开放设计性实验。

  4. Highly transparent, low-haze, hybrid cellulose nanopaper as electrodes for flexible electronics

    Science.gov (United States)

    Xu, Xuezhu; Zhou, Jian; Jiang, Long; Lubineau, Gilles; Ng, Tienkhee; Ooi, Boon S.; Liao, Hsien-Yu; Shen, Chao; Chen, Long; Zhu, J. Y.

    2016-06-01

    Paper is an excellent candidate to replace plastics as a substrate for flexible electronics due to its low cost, renewability and flexibility. Cellulose nanopaper (CNP), a new type of paper made of nanosized cellulose fibers, is a promising substrate material for transparent and flexible electrodes due to its potentially high transparency and high mechanical strength. Although CNP substrates can achieve high transparency, they are still characterized by high diffuse transmittance and small direct transmittance, resulting in high optical haze of the substrates. In this study, we proposed a simple methodology for large-scale production of high-transparency, low-haze CNP comprising both long cellulose nanofibrils (CNFs) and short cellulose nanocrystals (CNCs). By varying the CNC/CNF ratio in the hybrid CNP, we could tailor its total transmittance, direct transmittance and diffuse transmittance. By increasing the CNC content, the optical haze of the hybrid CNP could be decreased and its transparency could be increased. The direct transmittance and optical haze of the CNP were 75.1% and 10.0%, respectively, greatly improved from the values of previously reported CNP (31.1% and 62.0%, respectively). Transparent, flexible electrodes were fabricated by coating the hybrid CNP with silver nanowires (AgNWs). The electrodes showed a low sheet resistance (minimum 1.2 Ω sq-1) and a high total transmittance (maximum of 82.5%). The electrodes were used to make a light emitting diode (LED) assembly to demonstrate their potential use in flexible displays.Paper is an excellent candidate to replace plastics as a substrate for flexible electronics due to its low cost, renewability and flexibility. Cellulose nanopaper (CNP), a new type of paper made of nanosized cellulose fibers, is a promising substrate material for transparent and flexible electrodes due to its potentially high transparency and high mechanical strength. Although CNP substrates can achieve high transparency, they are

  5. Single electron tunneling in large scale nanojunction arrays with bisferrocene-nanoparticle hybrids

    Science.gov (United States)

    Karmakar, Shilpi; Kumar, Susmit; Marzo, Pasquale; Primiceri, Elisabetta; di Corato, Riccardo; Rinaldi, Ross; Cozzi, Pier Giorgio; Bramanti, Alessandro Paolo; Maruccio, Giuseppe

    2012-03-01

    We report on the fabrication and single electron tunneling behaviour of large scale arrays of nanogap electrodes bridged by bisferrocene-gold nanoparticle hybrids (BFc-AuNP). Coulomb staircase was observed in the low temperature current-voltage curves measured on the junctions with asymmetric tunnel barriers. On the other hand, junctions with symmetric tunneling barrier exhibited mere nonlinear current voltage characteristics without discrete staircase. The experimental results agreed well with simulations based on the orthodox theory. The junction resistance showed thermally activated conduction behaviour at higher temperature. The overall voltage and temperature dependent results show that the transport behaviour of the large arrays of single particle devices obtained by a facile optical lithography and chemical etching process corresponds with the behaviour of single particle devices fabricated by other techniques like e-beam lithography and mechanical breaking methods.We report on the fabrication and single electron tunneling behaviour of large scale arrays of nanogap electrodes bridged by bisferrocene-gold nanoparticle hybrids (BFc-AuNP). Coulomb staircase was observed in the low temperature current-voltage curves measured on the junctions with asymmetric tunnel barriers. On the other hand, junctions with symmetric tunneling barrier exhibited mere nonlinear current voltage characteristics without discrete staircase. The experimental results agreed well with simulations based on the orthodox theory. The junction resistance showed thermally activated conduction behaviour at higher temperature. The overall voltage and temperature dependent results show that the transport behaviour of the large arrays of single particle devices obtained by a facile optical lithography and chemical etching process corresponds with the behaviour of single particle devices fabricated by other techniques like e-beam lithography and mechanical breaking methods. Electronic supplementary

  6. Contribution of interlayer hybridization to the electronic structure in iron pnictides: a study of EELS and first-principles calculations.

    Science.gov (United States)

    Ma, Chao; Yang, Huaixin; Tian, Huanfang; Shi, Honglong; Wang, Zhiwei; Li, Jianqi

    2013-03-20

    Using electron energy loss spectroscopy (EELS) measurements and first-principles electronic structure calculations, the significant interlayer hybridization between the insulating layers (ReO or Ba) and the conducting FeAs layers was investigated in the layered iron pnictides, which is quite different from the case in the cuprate superconductors. This interlayer hybridization would result in an increase in the bandwidth near the Fermi level and interorbital charge transfer in the Fe 3d orbitals, which subsequently leads to a decrease in the Fe local moment and the modification of the Fermi surface topology. Therefore, a three-dimensional character of the electronic structure due to the interlayer hybridization is expected, as observed in previous experiments. These findings indicate that reduced dimensionality is no longer a necessary condition in the search for high-T(c) superconductors in iron pnictides.

  7. Single-Particle Cryo-EM and 3D Reconstruction of Hybrid Nanoparticles with Electron-Dense Components.

    Science.gov (United States)

    Yu, Guimei; Yan, Rui; Zhang, Chuan; Mao, Chengde; Jiang, Wen

    2015-10-01

    Single-particle cryo-electron microscopy (cryo-EM), accompanied with 3D reconstruction, is a broadly applicable tool for the structural characterization of macromolecules and nanoparticles. Recently, the cryo-EM field has pushed the limits of this technique to higher resolutions and samples of smaller molecular mass, however, some samples still present hurdles to this technique. Hybrid particles with electron-dense components, which have been studied using single-particle cryo-EM yet with limited success in 3D reconstruction due to the interference caused by electron-dense elements, constitute one group of such challenging samples. To process such hybrid particles, a masking method is developed in this work to adaptively remove pixels arising from electron-dense portions in individual projection images while maintaining maximal biomass signals for subsequent 2D alignment, 3D reconstruction, and iterative refinements. As demonstrated by the success in 3D reconstruction of an octahedron DNA/gold hybrid particle, which has been previously published without a 3D reconstruction, the devised strategy that combines adaptive masking and standard single-particle 3D reconstruction approach has overcome the hurdle of electron-dense elements interference, and is generally applicable to cryo-EM structural characterization of most, if not all, hybrid nanomaterials with electron-dense components.

  8. Electronic band structure effects in monolayer, bilayer, and hybrid graphene structures

    Science.gov (United States)

    Puls, Conor

    Since its discovery in 2005, graphene has been the focus of intense theoretical and experimental study owing to its unique two-dimensional band structure and related electronic properties. In this thesis, we explore the electronic properties of graphene structures from several perspectives including the magnetoelectrical transport properties of monolayer graphene, gap engineering and measurements in bilayer graphene, and anomalous quantum oscillation in the monolayer-bilayer graphene hybrids. We also explored the device implications of our findings, and the application of some experimental techniques developed for the graphene work to the study of a complex oxide, Ca3Ru2O7, exhibiting properties of strongly correlated electrons. Graphene's high mobility and ballistic transport over device length scales, make it suitable for numerous applications. However, two big challenges remain in the way: maintaining high mobility in fabricated devices, and engineering a band gap to make graphene compatible with logical electronics and various optical devices. We address the first challenge by experimentally evaluating mobilities in scalable monolayer graphene-based field effect transistors (FETs) and dielectric-covered Hall bars. We find that the mobility is limited in these devices, and is roughly inversely proportional to doping. By considering interaction of graphene's Dirac fermions with local charged impurities at the interface between graphene and the top-gate dielectric, we find that Coulomb scattering is responsible for degraded mobility. Even in the cleanest devices, a band gap is still desirable for electronic applications of graphene. We address this challenge by probing the band structure of bilayer graphene, in which a field-tunable energy band gap has been theoretically proposed. We use planar tunneling spectroscopy of exfoliated bilayer graphene flakes demonstrate both measurement and control of the energy band gap. We find that both the Fermi level and

  9. Mine or Theirs, Where Do Users Go? A Comparison of E-Journal Usage at the OhioLINK Electronic Journal Center Platform versus the Elsevier ScienceDirect Platform

    Science.gov (United States)

    Swanson, Juleah

    2015-01-01

    This research provides librarians with a model for assessing and predicting which platforms patrons will use to access the same content, specifically comparing usage at the Ohio Library and Information Network (OhioLINK) Electronic Journal Center (EJC) and at Elsevier's ScienceDirect from 2007 to 2013. Findings show that in the earlier years, the…

  10. Mine or Theirs, Where Do Users Go? A Comparison of E-Journal Usage at the OhioLINK Electronic Journal Center Platform versus the Elsevier ScienceDirect Platform

    Science.gov (United States)

    Swanson, Juleah

    2015-01-01

    This research provides librarians with a model for assessing and predicting which platforms patrons will use to access the same content, specifically comparing usage at the Ohio Library and Information Network (OhioLINK) Electronic Journal Center (EJC) and at Elsevier's ScienceDirect from 2007 to 2013. Findings show that in the earlier years, the…

  11. Stability of hybrid modes of a single-component electron plasma containing an admixture of background gas ions

    Science.gov (United States)

    Yeliseyev, Yu. N.

    2014-05-01

    The spectrum of eigenmodes of a waveguide completely filled with a cold electron plasma containing a small admixture of ions produced due to electron-impact ionization of background gas atoms is calculated numerically. The calculations were performed within the entire range of allowable values of the radial electric and longitudinal magnetic fields for both magnetized and unmagnetized ions by using the earlier derived nonlocal dispersion relation [Plasma Phys. Rep. 36, 563 (2010)]. The spectrum consists of three families of electron modes with frequencies equal to the Doppler-shifted upper and lower hybrid frequencies and modified ion cyclotron (MIC) modes. When the Doppler shift caused by electron rotation in the crossed electric and magnetic fields compensates for the hybrid frequency, the electron modes become low-frequency modes and interact with the ion modes. For m = 1, only the lower hybrid modes can be low-frequency ones, whereas at m ≥ 2, both lower and upper hybrid modes can be low-frequency ones. The spectrum of modes having the azimuthal number m = 2 is thoroughly analyzed. It is shown that, in this case, the lower hybrid modes behave similar to the m = 1 modes. The dispersion curves of the upper hybrid modes intersect with all harmonics of the MIC frequency (positive, negative, and zero) and are unstable in the vicinities of the intersections. The maximum value of the instability growth rate is several times higher than the ion plasma frequency. The MIC modes are unstable within a wide range of the field strengths, and their growth rates are two orders of magnitude slower. Instabilities are caused by the relative motion of electrons and ions (the transverse current) and the anisotropy of the ion distribution function.

  12. Television as a Hybrid Repertoire of Memory: New Dynamic Practices of Cultural Memory in the Multi-Platform Era

    NARCIS (Netherlands)

    Hagedoorn, B.

    2013-01-01

    In this article, television is reconsidered as a hybrid ‘repertoire’ of memory. It is demonstrated how new dynamic production and scheduling practices in connection with highly accessible and participatory forms of user engagement offer opportunities for television users to engage with the past, and

  13. 电子产品公共技术服务平台的开发%The Development of Electronic Products Public Technology Service Platform

    Institute of Scientific and Technical Information of China (English)

    万明刚; 勾博

    2011-01-01

    This platform is the use of computer technology, exchange of data storage technology, data retrieval,control network technology and the Intemet technology to build the"public technical service platform for electronic products in Jilin Province".The platform is able to ensure that collected information about electronic information enterprises in the province,included in the platform database and offers standard query to enterprise platform,companies demand support platform,expert support platform,resource libraries,enterprise marketing services platform and comprehensive information service platform.Achieve the integration of electronic information enterprises in Jilin province internal and external resources,achieve the goal of resource information sharing.%本平台是利用计算机技术、数据存储技术、数据交换检索技术、控制网络技术和互联网技术构建的省内“电子产品公共技术服务平台”。该平台能够保证收集省内电子信息企业的相关信息,纳入该平台数据库,并向各企业提供标准查询平台、企业需求支撑平台、专家支撑平台、资源库、企业市场服务平台以及综合信息服务平台。达到省内内电子信息企业整合内外部资源,实现资源信息共享的目标。

  14. Electronic data capture platform for clinical research based on mobile phones and near field communication technology.

    Science.gov (United States)

    Morak, Jürgen; Schwetz, Verena; Hayn, Dieter; Fruhwald, Friedrich; Schreier, Gunter

    2008-01-01

    Electronic data capture systems support data acquisition for clinical research and enable the evaluation of new investigational medical devices. In case of evaluating a device the most challenging part is the user interface i.e. the solution how to acquire the data within a clinical setting and to synchronize them with a web-based data centre. The aim of this paper is to describe the development of an electronic data capture system with a mobile data input solution based on mobile phones and Near Field Communication technology. This system was evaluated within a real clinical setting and demonstrated high usability, security and reliability.

  15. Donor–acceptor graphene-based hybrid materials facilitating photo-induced electron-transfer reactions

    Directory of Open Access Journals (Sweden)

    Anastasios Stergiou

    2014-09-01

    Full Text Available Graphene research and in particular the topic of chemical functionalization of graphene has exploded in the last decade. The main aim is to increase the solubility and thereby enhance the processability of the material, which is otherwise insoluble and inapplicable for technological applications when stacked in the form of graphite. To this end, initially, graphite was oxidized under harsh conditions to yield exfoliated graphene oxide sheets that are soluble in aqueous media and amenable to chemical modifications due to the presence of carboxylic acid groups at the edges of the lattice. However, it was obvious that the high-defect framework of graphene oxide cannot be readily utilized in applications that are governed by charge-transfer processes, for example, in solar cells. Alternatively, exfoliated graphene has been applied toward the realization of some donor–acceptor hybrid materials with photo- and/or electro-active components. The main body of research regarding obtaining donor–acceptor hybrid materials based on graphene to facilitate charge-transfer phenomena, which is reviewed here, concerns the incorporation of porphyrins and phthalocyanines onto graphene sheets. Through illustrative schemes, the preparation and most importantly the photophysical properties of such graphene-based ensembles will be described. Important parameters, such as the generation of the charge-separated state upon photoexcitation of the organic electron donor, the lifetimes of the charge-separation and charge-recombination as well as the incident-photon-to-current efficiency value for some donor–acceptor graphene-based hybrids, will be discussed.

  16. Highly transparent, low-haze, hybrid cellulose nanopaper as electrodes for flexible electronics

    KAUST Repository

    Xu, Xuezhu

    2016-06-01

    Paper is an excellent candidate to replace plastics as a substrate for flexible electronics due to its low cost, renewability and flexibility. Cellulose nanopaper (CNP), a new type of paper made of nanosized cellulose fibers, is a promising substrate material for transparent and flexible electrodes due to its potentially high transparency and high mechanical strength. Although CNP substrates can achieve high transparency, they are still characterized by high diffuse transmittance and small direct transmittance, resulting in high optical haze of the substrates. In this study, we proposed a simple methodology for large-scale production of high-transparency, low-haze CNP comprising both long cellulose nanofibrils (CNFs) and short cellulose nanocrystals (CNCs). By varying the CNC/CNF ratio in the hybrid CNP, we could tailor its total transmittance, direct transmittance and diffuse transmittance. By increasing the CNC content, the optical haze of the hybrid CNP could be decreased and its transparency could be increased. The direct transmittance and optical haze of the CNP were 75.1% and 10.0%, respectively, greatly improved from the values of previously reported CNP (31.1% and 62.0%, respectively). Transparent, flexible electrodes were fabricated by coating the hybrid CNP with silver nanowires (AgNWs). The electrodes showed a low sheet resistance (minimum 1.2 Ω sq-1) and a high total transmittance (maximum of 82.5%). The electrodes were used to make a light emitting diode (LED) assembly to demonstrate their potential use in flexible displays. © 2016 The Royal Society of Chemistry.

  17. Development of an Electronic Nose Sensing Platform for Undergraduate Education in Nanotechnology

    Science.gov (United States)

    Russo, Daniel V.; Burek, Michael J.; Iutzi, Ryan M.; Mracek, James A.; Hesjedal, Thorsten

    2011-01-01

    The teaching of the different aspects of a sensor system, with a focus on the involved nanotechnology, is a challenging, yet important task. We present the development of an electronic nose system that utilizes a nanoscale amperometric sensing mechanism for gas mixtures. The fabrication of the system makes use of a basic microfabrication facility,…

  18. Making hybrid [n]-rotaxanes as supramolecular arrays of molecular electron spin qubits

    Science.gov (United States)

    Fernandez, Antonio; Ferrando-Soria, Jesus; Pineda, Eufemio Moreno; Tuna, Floriana; Vitorica-Yrezabal, Iñigo J.; Knappke, Christiane; Ujma, Jakub; Muryn, Christopher A.; Timco, Grigore A.; Barran, Perdita E.; Ardavan, Arzhang; Winpenny, Richard E. P.

    2016-01-01

    Quantum information processing (QIP) would require that the individual units involved--qubits--communicate to other qubits while retaining their identity. In many ways this resembles the way supramolecular chemistry brings together individual molecules into interlocked structures, where the assembly has one identity but where the individual components are still recognizable. Here a fully modular supramolecular strategy has been to link hybrid organic-inorganic [2]- and [3]-rotaxanes into still larger [4]-, [5]- and [7]-rotaxanes. The ring components are heterometallic octanuclear [Cr7NiF8(O2CtBu)16]- coordination cages and the thread components template the formation of the ring about the organic axle, and are further functionalized to act as a ligand, which leads to large supramolecular arrays of these heterometallic rings. As the rings have been proposed as qubits for QIP, the strategy provides a possible route towards scalable molecular electron spin devices for QIP. Double electron-electron resonance experiments demonstrate inter-qubit interactions suitable for mediating two-qubit quantum logic gates.

  19. Enhancing Intrinsic Stability of Hybrid Perovskite Solar Cell by Strong, yet Balanced, Electronic Coupling

    Science.gov (United States)

    El-Mellouhi, Fedwa; Bentria, El Tayeb; Rashkeev, Sergey N.; Kais, Sabre; Alharbi, Fahhad H.

    2016-07-01

    In the past few years, the meteoric development of hybrid organic–inorganic perovskite solar cells (PSC) astonished the community. The efficiency has already reached the level needed for commercialization; however, the instability hinders its deployment on the market. Here, we report a mechanism to chemically stabilize PSC absorbers. We propose to replace the widely used methylammonium cation (CH3NH3+) by alternative molecular cations allowing an enhanced electronic coupling between the cation and the PbI6 octahedra while maintaining the band gap energy within the suitable range for solar cells. The mechanism exploits establishing a balance between the electronegativity of the materials’ constituents and the resulting ionic electrostatic interactions. The calculations demonstrate the concept of enhancing the electronic coupling, and hence the stability, by exploring the stabilizing features of CH3PH3+, CH3SH2+, and SH3+ cations, among several other possible candidates. Chemical stability enhancement hence results from a strong, yet balanced, electronic coupling between the cation and the halides in the octahedron. This shall unlock the hindering instability problem for PSCs and allow them to hit the market as a serious low-cost competitor to silicon based solar cell technologies.

  20. Enhancing Intrinsic Stability of Hybrid Perovskite Solar Cell by Strong, yet Balanced, Electronic Coupling

    Science.gov (United States)

    El-Mellouhi, Fedwa; Bentria, El Tayeb; Rashkeev, Sergey N.; Kais, Sabre; Alharbi, Fahhad H.

    2016-01-01

    In the past few years, the meteoric development of hybrid organic–inorganic perovskite solar cells (PSC) astonished the community. The efficiency has already reached the level needed for commercialization; however, the instability hinders its deployment on the market. Here, we report a mechanism to chemically stabilize PSC absorbers. We propose to replace the widely used methylammonium cation (CH3NH3+) by alternative molecular cations allowing an enhanced electronic coupling between the cation and the PbI6 octahedra while maintaining the band gap energy within the suitable range for solar cells. The mechanism exploits establishing a balance between the electronegativity of the materials’ constituents and the resulting ionic electrostatic interactions. The calculations demonstrate the concept of enhancing the electronic coupling, and hence the stability, by exploring the stabilizing features of CH3PH3+, CH3SH2+, and SH3+ cations, among several other possible candidates. Chemical stability enhancement hence results from a strong, yet balanced, electronic coupling between the cation and the halides in the octahedron. This shall unlock the hindering instability problem for PSCs and allow them to hit the market as a serious low-cost competitor to silicon based solar cell technologies. PMID:27457130

  1. Design guidelines for use of adhesives in hybrid microcircuits. [for electronic equipment in space applications

    Science.gov (United States)

    Caruso, S. V.; Perkins, K. L.; Licari, J. J.

    1973-01-01

    Although it is generally accepted that the use of adhesives in the assembly of hybrid microcircuits offers advantages over other bonding methods, there currently does not exist a set of guidelines for the selection of adhesives which will insure that hybrid microcircuits assembled with them will meet the long use-life, high-reliability requirements of electronic equipment for space applications. This study was directed to the identification of the properties of electrically insulative adhesives that potentially could cause problems in such an application, and to the development of evaluation tests to quantify these properties and thus form the basis for establishing suitable guidelines and, ultimately, specifications. Bond strength, outgassing after cure, and corrosivity were selected for detailed attention since they are considered to be especially critical. Introductory discussion includes enumeration and brief comments on the properties of adhesives considered to be important for the proposed application, a general review of polymeric types of adhesives, and identification of the major types of adhesives commercially available and specifically designed for microelectronic use. The specific tests developed to evaluate bond strength, outgassing after cure, and corrosivity are discussed in detail, and comparative results obtained for selected adhesives representative of the major types are given.

  2. Electron beam energy stabilization using a neural network hybrid controller at the Australian Synchrotron Linac.

    Energy Technology Data Exchange (ETDEWEB)

    Meier, E.; Morgan, M. J.; Biedron, S. G.; LeBlanc, G.; Wu, J. (OTD-ESE); (Monash Univ.); (Australian Synchrotron Project); (SLAC National Accelerator Lab.)

    2009-01-01

    This paper describes the implementation of a neural network hybrid controller for energy stabilization at the Australian Synchrotron Linac. The structure of the controller consists of a neural network (NNET) feed forward control, augmented by a conventional Proportional-Integral (PI) feedback controller to ensure stability of the system. The system is provided with past states of the machine in order to predict its future state, and therefore apply appropriate feed forward control. The NNET is able to cancel multiple frequency jitter in real-time. When it is not performing optimally due to jitter changes, the system can successfully be augmented by the PI controller to attenuate the remaining perturbations. With a view to control the energy and bunch length at the FERMI{at}Elettra Free Electron Laser (FEL), the present study considers a neural network hybrid feed forward-feedback type of control to rectify limitations related to feedback systems, such as poor response for high jitter frequencies or limited bandwidth, while ensuring robustness of control. The Australian Synchrotron Linac is equipped with a beam position monitor (BPM), that was provided by Sincrotrone Trieste from a former transport line thus allowing energy measurements and energy control experiments. The present study will consequently focus on correcting energy jitter induced by variations in klystron phase and voltage.

  3. Power sources for portable electronics and hybrid cars: lithium batteries and fuel cells.

    Science.gov (United States)

    Scrosati, Bruno

    2005-01-01

    The activities in progress in our laboratory for the development of batteries and fuel cells for portable electronics and hybrid car applications are reviewed and discussed. In the case of lithium batteries, the research has been mainly focused on the characterization of new electrode and electrolyte materials. Results related to disordered carbon anodes and improved, solvent-free, as well as gel-type, polymer electrolytes are particularly stressed. It is shown that the use of proper gel electrolytes, in combination with suitable electrode couples, allows the development of new types of safe, reliable, and low-cost lithium ion batteries which appear to be very promising power sources for hybrid vehicles. Some of the technologies proven to be successful in the lithium battery area are readapted for use in fuel cells. In particular, this approach has been followed for the preparation of low-cost and stable protonic membranes to be proposed as an alternative to the expensive, perfluorosulfonic membranes presently used in polymer electrolyte membrane fuel cells (PEMFCs). Copyright 2005 The Japan Chemical Journal Forum and Wiley Periodicals, Inc

  4. 3D hybrid simulations with gyrokinetic particle ions and fluid electrons

    Energy Technology Data Exchange (ETDEWEB)

    Belova, E.V.; Park, W.; Fu, G.Y. [Princeton Univ., NJ (United States). Plasma Physics Lab.; Strauss, H.R. [New York Univ., NY (United States); Sugiyama, L.E. [Massachusetts Inst. of Tech., Cambridge, MA (United States)

    1998-12-31

    The previous hybrid MHD/particle model (MH3D-K code) represented energetic ions as gyrokinetic (or drift-kinetic) particles coupled to MHD equations using the pressure or current coupling scheme. A small energetic to bulk ion density ratio was assumed, n{sub h}/n{sub b} {much_lt} 1, allowing the neglect of the energetic ion perpendicular inertia in the momentum equation and the use of MHD Ohm`s law E = {minus}v{sub b} {times} B. A generalization of this model in which all ions are treated as gyrokinetic/drift-kinetic particles and fluid description is used for the electron dynamics is considered in this paper.

  5. More stable hybrid organic solar cells deposited on amorphous Si electron transfer layer

    Energy Technology Data Exchange (ETDEWEB)

    Samiee, Mehran; Modtland, Brian; Dalal, Vikram L., E-mail: vdalal@iastate.edu [Iowa State University, Dept. of Electrical and Computer Engineering, Ames, Iowa 50011 (United States); Aidarkhanov, Damir [Nazarbayev University, Astana (Kazakhstan)

    2014-05-26

    We report on defect densities, performance, and stability of organic/inorganic hybrid solar cells produced using n-doped inorganic amorphous silicon-carbide layers as the electron transport layer (ETL). The organic material was poly-3-hexyl-thiophene (P3HT) and heterojunction was formed using phenyl-C{sub 71}-Butyric-Acid-Methyl Ester (PCBM). For comparison, inverted solar cells fabricated using Cs{sub 2}CO{sub 3} as ETL were fabricated. Defect densities and subgap quantum efficiency curves were found to be nearly identical for both types of cells. The cells were subjected to 2xsun illumination and it was found that the cells produced using doped a-Si as ETL were much more stable than the cells produced using Cs{sub 2}CO{sub 3}.

  6. The Detection of Defects in Optical Fibers Using a Hybrid Opto-electronic Correlator

    Institute of Scientific and Technical Information of China (English)

    LIU Yange; LIU Wei; ZHANG Yimo; ZHOU Ge

    2000-01-01

    A hybrid opto-electronic correlator for detecting defects in optical fibers is proposed. After the light from a He-Ne laser being expanded and filtered it is not collimated but directly passes a Fourier transform lens and illuminates a reference fiber and a test fiber at the same input plane. The Fourier transform spectrum of the two fibers is therefore obtained at the rear focal plane of the lens, where it is sampled via a CCD array connected with a computer through a frame grabber. The computer performs filter, inverse Fourier transform and setting threshold operation on classification. The system is an equivalent of joint transform correlator with a Fourier lens of long focal length. The experiment results for optical fibers having incoordinate defects are presented. The results indicate that the system can be used for fiber defect detection, and has the advantages of high identification, compact configuration, easy adjustment and flexible manipulation.

  7. Development of flash nanoprecipitation as a scalable platform for production of hybrid polymer-inorganic Janus particles

    Science.gov (United States)

    Lee, Victoria E.; Prud'Homme, Robert K.; Priestley, Rodney D.

    Polymer Janus particles, containing two or more distinct domains, can act as supports for inorganic nanoparticles, stabilizing them against aggregation and templating anisotropic functionalization of the microparticles. This anisotropy can be advantageous for applications such as biofuel upgrading, bionanosensors, and responsive materials. Here, we introduce flash nanoprecipitation (FNP) as a scalable, fast process to create hybrid polymer-inorganic Janus particles with control of particle size and anisotropy. During FNP, polymer Janus particles form by rapid intermixing of a polymer solution with a poor solvent, inducing polymer precipitation and phase separation. Inorganic nanoparticles are then adsorbed selectively onto one domain of the polymer support by exploiting electrostatic interactions between the charged particles. By tuning polymer concentration and ratio in the feed stream, the particle size and anisotropy can be controlled. We further demonstrate that these hybrid particles can simultaneously stabilize emulsions and selectively catalyze the degradation of dye in one phase. With support from the Princeton Imaging Analysis Center.

  8. Photoinduced energy transfer processes in hybrid organic-inorganic multichromophoric arrays arranged on a truxene-based platform.

    Science.gov (United States)

    Diring, Stéphane; Ventura, Barbara; Barbieri, Andrea; Ziessel, Raymond

    2012-11-14

    The synthesis, photophysical characterization and energy-transfer features of a series of hybrid truxene derivatives peripherally decorated with inorganic Os-containing polypyridine units and organic Bodipy dyes are reported. The photoactive terminal units are coupled to the central truxene scaffold by rigid ethynyl linkers in a star-shaped arrangement. The absorption range widely covers the UV-Vis spectrum and the Os (3)MLCT or the Bodipy triplet act as final collectors of the absorbed energy.

  9. Cross-Linkable and Dual Functional Hybrid Polymeric Electron Transporting Layer for High-Performance Inverted Polymer Solar Cells.

    Science.gov (United States)

    Dong, Sheng; Hu, Zhicheng; Zhang, Kai; Yin, Qingwu; Jiang, Xiaofang; Huang, Fei; Cao, Yong

    2017-06-20

    A cross-linkable dual functional polymer hybrid electron transport layer (ETL) is developed by simply adding an amino-functionalized polymer dopant (PN4N) and a light crosslinker into a commercialized n-type semiconductor (N2200) matrix. It is found that the resulting hybrid ETL not only has a good solvent resistance, facilitating multilayers device fabrication but also exhibits much improved electron transporting/extraction properties due to the doping between PN4N and N2200. As a result, by using PTB7-Th:PC71 BM blend as an active layer, the inverted device based on the hybrid ETL can yield a prominent power conversion efficiency of around 10.07%. More interestingly, photovoltaic property studies of bilayer devices suggest that the absorption of the hybrid ETL contributes to photocurrent and hence the hybrid ETL simultaneously acts as both cathode interlayer material and an electron acceptor. The resulting inverted polymer solar cells function like a novel device architectures with a combination of a bulk heterojunction device and miniature bilayer devices. This work provides new insights on function of ETLs and may be open up a new direction for the design of new ETL materials and novel device architectures to further improve device performance. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Analysis of Upper Hybrid Wave Growth Rates From Measured Electron Distributions; An Encounter With the Source of Auroral Roar

    Science.gov (United States)

    Bounds, S. R.; Kletzing, C. A.; Labelle, J. W.; Samara, M.; Yoon, P. H.

    2005-12-01

    In January of 2003, the High Bandwidth Auroral Rocket (HIBAR) passed through two regions of strong upper hybrid wave emission associated with the approximate matching of the upper hybrid frequency to twice the electron cyclotron frequency (fuh = 2 fce) (Samara 2004) These types of emission are believed to be the source of the HF auroral roar often observed by ground based receivers. The current model theorizes that the free space 0-mode waves observed on the ground are produced through mode conversion of strong emission of Z-mode, or upper hybrid waves. The relativistic electron cyclotron maser exhibits significant growth rates for the Z-mode when the local upper hybrid frequency is just below (~1%) twice the electron cyclotron frequency and with the appropriately unstable electron distribution (Yoon 1996, Yoon 1998, Yoon 2000). Though auroral roar is frequently observed from the ground, the source region has rarely been identified in-situ and even more rarely with sufficient bandwidth to analyze the underlying physical processes. Analysis of the electron distributions from HIBAR show good agreement with the theoretical distributions used by Yoon:98. HIBAR encountered three separate regions where fuh ≍ 2 fce, two of these regions include strong upper hybrid emission, while the third is void of upper hybrid wave activity. The measured particle distributions demonstrate that, in the two regions with wave emission, the relativistic electron cyclotron maser instability produces Z mode wave growth rates at least an order of magnitude greater than the electron collision frequency. In the third region without wave emission, the growth rates are much smaller in both amplitude and the extent of occurance. Samara, M., J. LaBelle, C. A. Kletzing, and S. R. Bounds, Rocket observations of structured upper hybrid wave at fuh=2fce, Geophys. Res. Lett., 31, L22804, doi:10.1029/2004GL021043. Yoon, P. H., A. T. Weatherwax, and T. J. Rosenberg, Lower ionospheric cyclotron maser

  11. Electronic and vibrational properties of transition metal-oxides: Comparison of GGA, GGA + U, and hybrid approaches

    Science.gov (United States)

    Pandey, Sumeet C.; Xu, Xu; Williamson, Izaak; Nelson, Eric B.; Li, Lan

    2017-02-01

    We estimate the Hubbard parameters for density-functional-theory (DFT) + U calculations of ZrO2, HfO2, TiO2, and NiO based on calibrating the electronic structure obtained from hybrid functional methods. The electronic density of states is used to assess the parameters and the values thus derived are employed for the full electron and phonon dispersion comparisons. The resulting values account for experimental band gaps and electron correlations that are computationally much less demanding to treat within the simpler DFT + U framework than with the typically more accurate yet expensive hybrid functional methods. Limitations of +U scheme is indicated towards describing TiO2 and HfO2 phase-stability.

  12. Microfluidic Integration of a Cloth-Based Hybridization Array System (CHAS) for Rapid, Colorimetric Detection of Enterohemorrhagic Escherichia coli (EHEC) Using an Articulated, Centrifugal Platform.

    Science.gov (United States)

    Geissler, Matthias; Clime, Liviu; Hoa, Xuyen D; Morton, Keith J; Hébert, Harold; Poncelet, Lucas; Mounier, Maxence; Deschênes, Mylène; Gauthier, Martine E; Huszczynski, George; Corneau, Nathalie; Blais, Burton W; Veres, Teodor

    2015-10-20

    We describe the translation of a cloth-based hybridization array system (CHAS), a colorimetric DNA detection method that is used by food inspection laboratories for colony screening of pathogenic agents, onto a microfluidic chip format. We also introduce an articulated centrifugal platform with a novel fluid manipulation concept based on changes in the orientation of the chip with respect to the centrifugal force field to time the passage of multiple components required for the process. The platform features two movable and motorized carriers that can be reoriented on demand between 0 and 360° during stage rotation. Articulation of the chip can be used to trigger on-the-fly fluid dispensing through independently addressable siphon structures or to relocate solutions against the centrifugal force field, making them newly accessible for downstream transfer. With the microfluidic CHAS, we achieved significant reduction in the size of the cloth substrate as well as the volume of reagents and wash solutions. Both the chip design and the operational protocol were optimized to perform the entire process in a reliable, fully automated fashion. A demonstration with PCR-amplified genomic DNA confirms on-chip detection and identification of Escherichia coli O157:H7 from colony isolates in a colorimetric multiplex assay using rfbO157, fliCH7, vt1, and vt2 genes.

  13. Hybrid nanowire ion-to-electron transducers for integrated bioelectronic circuitry (Conference Presentation)

    Science.gov (United States)

    Carrad, Damon J.; Mostert, Bernard; Meredith, Paul; Micolich, Adam P.

    2016-09-01

    A key task in bioelectronics is the transduction between ionic/protonic signals and electronic signals at high fidelity. This is a considerable challenge since the two carrier types exhibit intrinsically different physics. We present our work on a new class of organic-inorganic transducing interface utilising semiconducting InAs and GaAs nanowires directly gated with a proton transporting hygroscopic polymer consisting of undoped polyethylene oxide (PEO) patterned to nanoscale dimensions by a newly developed electron-beam lithography process [1]. Remarkably, we find our undoped PEO polymer electrolyte gate dielectric [2] gives equivalent electrical performance to the more traditionally used LiClO4-doped PEO [3], with an ionic conductivity three orders of magnitude higher than previously reported for undoped PEO [4]. The observed behaviour is consistent with proton conduction in PEO. We attribute our undoped PEO-based devices' performance to the small external surface and high surface-to-volume ratio of both the nanowire conducting channel and patterned PEO dielectric in our devices, as well as the enhanced hydration afforded by device processing and atmospheric conditions. In addition to studying the basic transducing mechanisms, we also demonstrate high-fidelity ionic to electronic conversion of a.c. signals at frequencies up to 50 Hz. Moreover, by combining complementary n- and p-type transducers we demonstrate functional hybrid ionic-electronic circuits can achieve logic (NOT operation), and with some further engineering of the nanowire contacts, potentially also amplification. Our device structures have significant potential to be scaled towards realising integrated bioelectronic circuitry. [1] D.J. Carrad et al., Nano Letters 14, 94 (2014). [2] D.J. Carrad et al., Manuscript in preparation (2016). [3] S.H. Kim et al., Advanced Materials 25, 1822 (2013). [4] S.K. Fullerton-Shirey et al., Macromolecules 42, 2142 (2009).

  14. DISTRIBUTION OF VEGF mRNA IN BREAST CANCER WITH NONRADIOACTIVE IN SITU HYBRIDIZATION AT ELECTRON MICROSCOPIC LEVELS

    Institute of Scientific and Technical Information of China (English)

    王医术; 林; 王心蕊; 李一雷; 吴珊; 张丽红

    2002-01-01

    Object: To localize the mRNA coding for VEGF at Ultrastractural level in human breast cancer by using digoxigenin-labeled cDNA probes. Methods: Nonradio- active in situ hybridization at electron microscopic level was employed to detected VEGF mRNA in breast cancer. Result: Cancer cells and endothelial cell of angiogensis show dark color in experiment sections. No dark color can be found in control sections. Positive hybridization signals showed dark dot and were locatedin various compartments of the breast cancer cell and endothelial cell in experiment section. No labeling was observed in control sections. In experiment sections, the staining appeared concentrated in cytoplasm and nucleus of the breast cancer cell and endothelial cell. Conclusion: Nonradioactive in situ hybridization at electron microscopic level is efficient for direct observation of the target site mRNA of VEGF in the cytoplasm and nucleus.

  15. Envelope Soliton in Multi-ion Plasma and Ion-Ion Hybrid Wave Excited by Energetic Electron Beam

    Institute of Scientific and Technical Information of China (English)

    WANG De-Yu; HUANG Guang-Li

    2001-01-01

    Another envelope soliton event below the H+ gyrofrequency and localized density depletion has been discoveredin the low auroral region (~1760 kin) by the Freja satellite. This envelope soliton has a characteristic frequencyat ~190 Hz, which is also close to the resonance frequency of hydrogen ion-oxygen ion hybrid wave. This event iscorrelated in time with the observations of the sharp increase of the ratio of oxygen ion density to hydrogen andwith the electron energization along the magnetic field. A theoretical model on the ion-ion hybrid wave excitedby an energetic electron beam has also been presented. It is found that the ion-ion hybrid wave is mainly excitedby the Cherenkov instability in the auroral region.

  16. Hybrid exchange-correlation functional for accurate prediction of the electronic and structural properties of ferroelectric oxides

    OpenAIRE

    D., I. Bilc; R., Orlando; R., Shaltaf; G., M. Rignanese; J., Íñiguez; Ph., Ghosez

    2008-01-01

    Using a linear combination of atomic orbitals approach, we report a systematic comparison of various Density Functional Theory (DFT) and hybrid exchange-correlation functionals for the prediction of the electronic and structural properties of prototypical ferroelectric oxides. It is found that none of the available functionals is able to provide, at the same time, accurate electronic and structural properties of the cubic and tetragonal phases of BaTiO$_3$ and PbTiO$_3$. Some, although not al...

  17. A segmented Hybrid Photon Detector with integrated auto-triggering front-end electronics for a PET scanner

    CERN Document Server

    Chesi, Enrico Guido; Joram, C; Mathot, S; Séguinot, Jacques; Weilhammer, P; Ciocia, F; De Leo, R; Nappi, E; Vilardi, I; Argentieri, A; Corsi, F; Dragone, A; Pasqua, D

    2006-01-01

    We describe the design, fabrication and test results of a segmented Hybrid Photon Detector with integrated auto-triggering front-end electronics. Both the photodetector and its VLSI readout electronics are custom designed and have been tailored to the requirements of a recently proposed novel geometrical concept of a Positron Emission Tomograph. Emphasis is put on the PET specific features of the device. The detector has been fabricated in the photocathode facility at CERN.

  18. Magnon, phonon, and electron temperature profiles and the spin Seebeck effect in magnetic insulator/normal metal hybrid structures

    NARCIS (Netherlands)

    Schreier, M.; Kamra, A.; Weiler, M.; Xiao, J.; Bauer, G.E.W.; Gross, R.; Goennenwein, S.T.B.

    2013-01-01

    We calculate the phonon, electron, and magnon temperature profiles in yttrium iron garnet/platinum bilayers by diffusive theory with appropriate boundary conditions, in particular taking into account interfacial thermal resistances. Our calculations show that in thin film hybrids, the interface magn

  19. N-type polymers as electron extraction layers in hybrid perovskite solar cells with improved ambient stability

    NARCIS (Netherlands)

    Shao, S.; Chen, Z.; Fang, H. -H.; ten Brink, G. H.; Bartesaghi, D.; Adjokatse, S.; Koster, L. J. A.; Kooi, B. J.; Facchetti, A.; Loi, M. A.

    2016-01-01

    We studied three n-type polymers of the naphthalenediimide-bithiophene family as electron extraction layers (EELs) in hybrid perovskite solar cells. The recombination mechanism in these devices is found to be heavily influenced by the EEL transport properties. The maximum efficiency of the devices u

  20. Scanning electron microscopy and fluorescent in situ hybridization of experimental Brachyspira (Serpulina) pilosicoli infection in growing pigs

    DEFF Research Database (Denmark)

    Jensen, Tim Kåre; Møller, Kristian; Boye, Mette

    2000-01-01

    Two groups of six 8-week-old pigs were challenged with 1X10(9) cfu Brachyspira (Serpulina) pilosicoli or Serpulina intermedia daily for 3 consecutive days to study the pathology of porcine colonic spirochetosis by scanning electron microscopy (SEM) and fluorescent in situ hybridization (FISH...

  1. MO-F-CAMPUS-T-02: An Electronic Whiteboard Platform to Manage Treatment Planning Process

    Energy Technology Data Exchange (ETDEWEB)

    DiCostanzo, D; Woollard, J; Gupta, N; Ayan, A [Ohio State University, Columbus, OH (United States); Thompson, S [Santa Cruz Radiation Oncology, Santa Cruz, CA (United States)

    2015-06-15

    Purpose: In an effort to improve patient safety and streamline the radiotherapy treatment planning (TP) process, a software based whiteboard had been developed and put in use in our facility Methods: The electronic whiteboard developed using SQL database (DB) and PHP/JavaScript based web interface, is published via department intranet and login credentials. The DB stores data for each TP process such as patient information, plan type, simulation/start dates, physician, dosimetrist, QA and the current status in planning process. Users interact with the DB per plan and perform status updates in real time as the planning process progresses. All user interactions with the DB are recorded with timestamps so as to calculate statistical information for TP process management such as contouring times, planning and review times, dosimetry, physics and therapist QA times. External beam and brachytherapy plans are categorized according to complexity (ex: IMRT, 3D, HDR, LDR etc) and treatment types and applicators. Each plan category is assigned specific timelines for each planning process. When a plan approaches or passes the predetermined timeline, users are alerted via color coded graphical cues. When certain process items are not completed in time, pre-determined actions are triggered such as a delay in treatment start date. Results: Our institution has been using the electronic whiteboard for two years. Implementation of pre-determined actions based on the statistical information collected by the whiteboard improved our TP process. For example, the average time for normal tissue contouring decreased from 0.73±1.37 to 0.24±0.33 days. The average time for target volume contouring decreased from 3.2±2.84 to 2.37±2.54 days. This increase in efficiency allows more time for quality assurance processes, improving patient safety. Conclusion: The electronic whiteboard has been an invaluable tool for streamlining our TP processes. It facilitates timely and accurate communication

  2. Towards a fully functional integrated photonic-electronic platform via a single SiGe growth step

    Science.gov (United States)

    Littlejohns, Callum G.; Dominguez Bucio, Thalia; Nedeljkovic, Milos; Wang, Hong; Mashanovich, Goran Z.; Reed, Graham T.; Gardes, Frederic Y.

    2016-01-01

    Silicon-germanium (Si1-xGex) has become a material of great interest to the photonics and electronics industries due to its numerous interesting properties including higher carrier mobilities than Si, a tuneable lattice constant, and a tuneable bandgap. In previous work, we have demonstrated the ability to form localised areas of single crystal, uniform composition SiGe-on-insulator. Here we present a method of simultaneously growing several areas of SiGe-on-insulator on a single wafer, with the ability to tune the composition of each localised SiGe area, whilst retaining a uniform composition in that area. We use a rapid melt growth technique that comprises of only a single Ge growth step and a single anneal step. This innovative method is key in working towards a fully integrated photonic-electronic platform, enabling the simultaneous growth of multiple compositions of device grade SiGe for electro-absorption optical modulators operating at a range of wavelengths, photodetectors, and bipolar transistors, on the same wafer. This is achieved by modifying the structural design of the SiGe strips, without the need to modify the growth conditions, and by using low cost, low thermal-budget methods.

  3. Self-powered textile for wearable electronics by hybridizing fiber-shaped nanogenerators, solar cells, and supercapacitors.

    Science.gov (United States)

    Wen, Zhen; Yeh, Min-Hsin; Guo, Hengyu; Wang, Jie; Zi, Yunlong; Xu, Weidong; Deng, Jianan; Zhu, Lei; Wang, Xin; Hu, Chenguo; Zhu, Liping; Sun, Xuhui; Wang, Zhong Lin

    2016-10-01

    Wearable electronics fabricated on lightweight and flexible substrate are believed to have great potential for portable devices, but their applications are limited by the life span of their batteries. We propose a hybridized self-charging power textile system with the aim of simultaneously collecting outdoor sunshine and random body motion energies and then storing them in an energy storage unit. Both of the harvested energies can be easily converted into electricity by using fiber-shaped dye-sensitized solar cells (for solar energy) and fiber-shaped triboelectric nanogenerators (for random body motion energy) and then further stored as chemical energy in fiber-shaped supercapacitors. Because of the all-fiber-shaped structure of the entire system, our proposed hybridized self-charging textile system can be easily woven into electronic textiles to fabricate smart clothes to sustainably operate mobile or wearable electronics.

  4. A ternary functional Ag@GO@Au sandwiched hybrid as an ultrasensitive and stable surface enhanced Raman scattering platform

    Science.gov (United States)

    Zhang, Cong-yun; Hao, Rui; Zhao, Bin; Hao, Yao-wu; Liu, Ya-qing

    2017-07-01

    The graphene-mediated surface enhanced Raman scattering (SERS) substrates by virtues of plasmonic metal nanostructures and graphene or its derivatives have attracted tremendous interests which are expected to make up the deficiency of traditional plasmonic metal substrates. Herein, we designed and fabricated a novel ternary Ag@GO@Au sandwich hybrid wherein the ultrathin graphene oxide (GO) films were seamlessly wrapped around the hierarchical flower-like Ag particle core and meanwhile provided two-dimensional anchoring scaffold for the coating of Au nanoparticles (NPs). The surface coverage density of loading Au NPs could be readily controlled by tuning the dosage amount of Au particle solutions. These features endowed the sandwiched structures high enrichment capability for analytes such as aromatic molecules and astonishing SERS performance. The Raman signals were enormously enhanced with an ultrasensitive detection limit of rhodamine-6G (R6G) as low as 10-13 M based on the chemical enhancement from GO and multi-dimensional plasmonic coupling between the metal nanoparticles. In addition, the GO interlayer as an isolating shell could effectively prevent the metal-molecule direct interaction and suppress the oxidation of Ag after exposure at ambient condition which enabled the substrates excellent reproducibility with less than 6% signal variations and prolonged life-time. To evaluate the feasibility and the practical application for SERS detection in real-world samples based on GO sandwiched hybrid as SERS-active substrate, three different prohibited colorants with a series of concentrations were measured with a minimum detected concentration down to 10-9 M. Furthermore, the prepared GO sandwiched nanostructures can be used to identify different types of colorants existing in red wine, implying the great potential applications for single-particle SERS sensing of biotechnology and on-site monitoring in food security.

  5. Organic-inorganic semiconductor hybrid systems. Structure, morphology, and electronic properties

    Energy Technology Data Exchange (ETDEWEB)

    El Helou, Mira

    2012-08-22

    This dissertation addresses the preparation and characterization of hybrid semiconducting systems combining organic with inorganic materials. Characterization methods used included to determine the structure, morphology, and thermal stability comprised X-ray diffraction (XRD), atomic force microscopy (AFM), thermal desorption spectroscopy (TDS), and X-ray photoelectron spectroscopy (XPS). One organic-inorganic semiconducting system was pentacene (C{sub 22}H{sub 14}) and zinc oxide. This interface was investigated in detail for pentacene on an oxygen-terminated zinc oxide surface, i.e. ZnO(000 anti 1). An extended study on the promising p-n junction was carried out for pentacene on ZnO with different orientations which exhibit different chemical and structural characteristics: ZnO(000 anti 1), ZnO(0001), and ZnO(10 anti 10). Moreover, the organic crystal structure of pentacene was selectively tuned by carefully choosing the substrate temperature. This defined interface with a physisorbed pentacene layer on ZnO was characterized by optical absorption which depends on the temperature of the measured system, the pentacene film thickness, and the molecular orientation and packing. The high quality of the pentacene films allowed in one case to characterize the Davydov splitting by linear polarized light focused on a single crystallite. Another subject in the field of organic-inorganic hybrid materials comprised conjugated dithiols used as self-assembled monolayers (SAMs) for immobilizing semiconducting CdS nanoparticles (NPs) on Au substrates. It was demonstrated that an appropriate selection and preparation of the conjugated SAMs is crucial for building up a light-addressable potentiometric sensor with a sufficient efficiency. An optimized electron transfer was achieved with SAMs of long range ordering, high stability, and adequate conductivity. This was examined for different linkers and was best for stilbenedithiol immobilized in solution at higher temperatures. Due

  6. A tapered undulator experiment at the ELBE far infrared hybrid-resonator oscillator free electron laser.

    Science.gov (United States)

    Asgekar, V; Lehnert, U; Michel, P

    2012-01-01

    A tapered undulator experiment was carried out at the ELBE far-infrared free electron laser (FEL). The oscillator FEL makes use of a hybrid optical resonator. The main motivation was to see whether the presence of a dispersive medium in the form of a waveguide in the resonator has any effect on the outcome. The FEL saturated power and the wavelength shifts have been measured as a function of both positive as well as negative undulator field amplitude tapering. In contrast to the typical high-gain FELs where positive tapering proves beneficial for the output power we observed an improvement of performance at negative taper. During the same experiments we studied the characteristics of the detuning curves. The width of the curves indicates a maximum small signal gain for zero taper while the output peak power increases with negative taper. The saturated power output, the detuning curve characteristics, and the wavelength shifts agrees with the theoretical predictions. Details of the experiment are presented.

  7. Characterization by fluorescence and electron microscopy in situ hybridization of a double Y isochromosome

    Energy Technology Data Exchange (ETDEWEB)

    Fetni, R.; Lemieux, N.; Richer, C.L. [Universite de Montreal, Quebec (Canada)] [and others

    1996-06-14

    A patient with mixed gonadal dysgenesis and Y isochromosomes I(Y) is described. Lymphocyte cultures from peripheral blood contained a high proportion of 45,X cells and several other cell lines with two different marker chromosomes (mars). These markers had either a monocentric (mar1) or a dicentric appearance (mar2). Following high-resolution GTG, RBG, QFQ, and CBG bandings, five cell lines were identified; 45,X/46,X, + mar1/46,X, + mar2/47,X, + mar1x2/47,X + mar2x2. The percentages were 66/6/26/1/1%, respectively. Chromosome banding analyses were insufficient for characterization of the markers. In situ hybridization of specific probes for the Y centromere and its short arm showed, both in fluorescence and electron microscopy (ENT), two different Y rearrangements. Mar1 is an isochromosome for the short arm i(Yp) and mar2 is a dicentric which was shown by EM to be a double isochromosome Yp, inv dup i(Yp). The breakpoint producing mar1 is within the centromere and the one producing mar2 is within one of the short arms of the Y isochromosome. The findings of different cell populations in peripheral blood lymphocytes indicate the postzygotic instability of this i(Yp). 24 refs., 3 figs., 1 tab.

  8. A cross-functional nanostructured platform based on carbon nanotube-Si hybrid junctions: where photon harvesting meets gas sensing

    Science.gov (United States)

    Rigoni, F.; Pintossi, C.; Drera, G.; Pagliara, S.; Lanti, G.; Castrucci, P.; de Crescenzi, M.; Sangaletti, L.

    2017-03-01

    A combination of the functionalities of carbon nanotube (CNT)-Si hybrid heterojunctions is presented as a novel method to steer the efficiency of the photovoltaic (PV) cell based on these junctions, and to increase the selectivity and sensitivity of the chemiresistor gas sensor operated with the p-doped CNT layer. The electrical characteristics of the junctions have been tracked by exposing the devices to oxidizing (NO2) and reducing (NH3) molecules. It is shown that when used as PV cells, the cell efficiency can be reversibly steered by gas adsorption, providing a tool to selectively dope the p-type layer through molecular adsorption. Tracking of the current-voltage curve upon gas exposure also allowed to use these cells as gas sensors with an enhanced sensitivity as compared to that provided by a readout of the electrical signal from the CNT layer alone. In turn, the chemiresistive response was improved, both in terms of selectivity and sensitivity, by operating the system under illumination, as the photo-induced charges at the junction increase the p-doping of CNTs making them more sensitive to NH3 and less to NO2.

  9. [The Impact of Electronic Monitoring on Healthcare Associated Infections: The Role of the HViTAL Platform].

    Science.gov (United States)

    Oliveira, Rita Fontes; Castro, Lídia; Almeida, José Pedro; Alves, Carlos; Ferreira, António

    2016-11-01

    In Portugal, 9.8% of patients admitted were inflicted with healthcare associated infections, corresponding to a prevalence of 11.7%. The Hospital de São João has developed a business intelligence platform able to supervise (the patients), monitor (the clinical condition) and notify (the healthcare personnel): HViTAL. This study aims to assess the impact of electronic monitoring on healthcare associated infections since the year of HViTAL implementation. We evaluated data since January 2008 (moment from which computerized records exist) until December 2011, comparing them with subsequent data, those corresponding to January 2012 (implementation date of HViTAL) until 19 October 2015. There was an upward trend of infection parameters in the 2008 - 2011 period. Since January 2012 and October 2015, all parameters of the infection indicator showed a negative linear trend. The results are very suggestive that the HVITAL may have had an impact on improving parameters associated to healthcare associated infections. Basic measures of infection control were highlighted since 2005, with an increasing number of health professional awareness campaigns, a fact which, although not analyzed in this report, may also have contributed to the observed improvement. Our study did not include other variables such as investment in human capital. There was a clear improvement in all areas characterizing the healthcare associated infections, with obvious positive impact with the introduction of HViTAL.

  10. Electron field emission characteristics of graphene/carbon nanotubes hybrid field emitter

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Leifeng, E-mail: chlf@hdu.edu.cn [College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018 (China); He, Hong; Yu, Hua; Cao, Yiqi [College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018 (China); Lei, Da, E-mail: leida126@126.com [Ordos College of Inner Mongolia University, Inner Mongolia University, Ordos 017000 (China); Menggen, QiQiGe [Ordos College of Inner Mongolia University, Inner Mongolia University, Ordos 017000 (China); Wu, Chaoxing; Hu, Liqin [College of Physics and Information Engineering, Fuzhou University, Fuzhou 350002 (China)

    2014-10-15

    The graphene (GP) and multi-walled carbon nanotubes (MCNTs) hybrid nanostructure emitter was constructed by a larger scale electrophoretic deposition (EPD) method. The field emission (FE) performance of the hybrid emitter is greatly improved compared with that of only GP or MCNTs emitter. The low turn-on electric field (EF), the low threshold EF and the reliability FE properties are obtained from the hybrid emitter. The better FE properties result from the improved electrical properties. For further enhancement FE of hybrids, Ag Nanoparticles (NPs) were decorated on the hybrids and FE characteristics were also studied. These studies indicate that we can use the hybrid nanostructure to improve conductivity and contact resistance, which results in enhancement of the FE properties.

  11. First Principles Study on the Electronic Structure and Interface Stability of Hybrid Silicene/Fluorosilicene Nanoribbons

    National Research Council Canada - National Science Library

    Jiang, Q G; Zhang, J F; Ao, Z M; Wu, Y P

    2015-01-01

    The interface stability of hybrid silicene/fluorosilicene nanoribbons (SFNRs) has been investigated by using density functional theory calculations, where fluorosilicene is the fully fluorinated silicene...

  12. Highly efficient hybrid photovoltaics based on hyperbranched three-dimensional TiO2 electron transporting materials

    KAUST Repository

    Mahmood, Khalid

    2015-03-23

    A 3D hyperbranched TiO2 electron transporting material is demonstrated, which exhibits superior carrier transport and lifetime, as well as excellent infiltration, leading to highly efficient mesostructured hybrid solar cells, such as lead-halide perovskites (15.5%) and dye-sensitized solar cells (11.2%). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Electron-transporting small molecule/ o-xylene hybrid additives to boost the performance of simplified inverted polymer solar cells

    Science.gov (United States)

    Qin, Dashan; Cao, Huan; Zhang, Jidong

    2017-05-01

    Electron-transporting small molecule bathophenanthroline (Bphen) together with o-xylene has been used as hybrid additives to improve the performance of simplified inverted polymer solar cells employing ITO alone as cathode and photoactive layer based on polymer [[2,6'-4,8-di(5-ethylhexylthienyl)benzo[1,2-b;3,3-b] dithiophene] [3-fluoro-2[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl

  14. The next-generation Hybrid Capture High-Risk HPV DNA assay on a fully automated platform.

    Science.gov (United States)

    Eder, Paul S; Lou, Jianrong; Huff, John; Macioszek, Jerzy

    2009-07-01

    A next-generation diagnostic system has been developed at QIAGEN. The QIAensemble system consists of an analytical subsystem (JE2000) that utilizes a re-engineered Hybrid Capture chemistry (NextGen) to maintain the high level of clinical sensitivity established by the digene High-Risk HPV DNA Test (HC2), while creating improved analytical specificity as shown both in plasmid-based analyses and in processing of clinical specimens. Limit-of-detection and cross-reactivity experiments were performed using plasmid DNA constructs containing multiple high-risk (HR) and low-risk (LR) HPV types. Cervical specimens collected into a novel specimen collection medium, DCM, were used to measure stability of specimens, as well as analytical specificity. Signal carryover, instrument precision, and specimen reproducibility were measured on the prototype JE2000 system using the automated NextGen assay. The Limit of Detection (LOD) is HPV 16 plasmid in the automated assay. No cross-reactivity (signal above cutoff) was detected on the automated system from any of 13 LR types tested at 10(7) copies per assay. Within-plate, plate-to-plate, and day-to-day performance in the prototype system yielded a CV of 20%. No indication of target carryover was found when samples containing up to 10(9) copies/ml of HPV DNA type 16 were processed on the JE2000 instrument. In an agreement study with HC2, 1038 donor cervical specimens were tested in both the manual NextGen assay and HC2 to evaluate agreement between the two tests. After eliminating discrepant specimens that were adjudicated by HR-HPV genotyping, the adjudicated positive agreement was 98.5% (95% CI: 94.6, 99.6). The JE2000 prototype system automates NextGen assay processing, yielding accurate, reproducible, and highly specific results with both plasmid analytical model tests and cervical specimens collected in DCM. The final system will process more than 2000 specimens in an 8-hour shift, with fully continuous loading.

  15. Long-Range Interfacial Electrochemical Electron Transfer of Pseudomonas aeruginosa Azurin-Gold Nanoparticle Hybrid Systems

    DEFF Research Database (Denmark)

    Jensen, Palle Skovhus; Chi, Qijin; Zhang, Jingdong

    2009-01-01

    We have prepared a "hybrid" of the blue copper protein azurin (Pseudomonas aeruginosa) and a 3 nm gold nanoparticle (AuNP). The AuNP/azurin hybrid was assembled on a Au(111)-electrode surface in a two-step process. The AuNP was first attached to the Au(111) electrode via Au-S chemisorption of a 4...

  16. Hybrid (particle in cell-fluid) simulation of ion-acoustic soliton generation including super-thermal and trapped electrons

    Energy Technology Data Exchange (ETDEWEB)

    Nopoush, M.; Abbasi, H. [Faculty of Physics, Amirkabir University of Technology, P. O. Box 15875-4413, Tehran (Iran, Islamic Republic of)

    2011-08-15

    The present paper is devoted to the simulation of the nonlinear disintegration of a localized perturbation into an ion-acoustic soliton in a plasma. Recently, this problem was studied by a simple model [H. Abbasi et al., Plasma Phys. Controlled Fusion 50, 095007 (2008)]. The main assumptions were (i) in the electron velocity distribution function (DF), the ion-acoustic soliton velocity was neglected in comparison to the electron thermal velocity, (ii) on the ion-acoustic evolution time-scale, the electron velocity DF was assumed to be stationary, and (iii) the calculation was restricted to the small amplitude case. In order to generalize the model, one has to consider the evolution of the electron velocity DF for finite amplitudes. For this purpose, a one dimensional electrostatic hybrid code, particle in cell (PIC)-fluid, was designed. It simulates the electrons dynamics by the PIC method and the cold ions dynamics by the fluid equations. The plasma contains a population of super-thermal electrons and, therefore, a Lorentzian (kappa) velocity DF is used to model the high energy tail in the electron velocity DF. Electron trapping is included in the simulation in view of their nonlinear resonant interaction with the localized perturbation. A Gaussian initial perturbation is used to model the localized perturbation. The influence of both the trapped and the super-thermal electrons on this process is studied and compared with the previous model.

  17. Electron energy distribution functions and negative ion concentrations in tandem and hybrid multicusp negative hydrogen ion sources

    Energy Technology Data Exchange (ETDEWEB)

    Hopkins, M.B. (Dublin City Univ. (Ireland). Dept. of Physics); Bacal, M. (Ecole Polytechnique, 91 - Palaiseau (France). Lab. de Physique des Milieux Ionises); Graham, W.G. (Queen' s Univ., Belfast, Northern Ireland (UK). School of Mathematics and Physics)

    1991-03-14

    The second derivative of a Langmuir probe characteristic is used to establish the electron energy distribution function (EEDF) in both a tandem and hybrid multicusp H{sup -} ion source. Moveable probes are used to establish the spatial variation of the EEDF. The negative ion density is measured by laser induced photo-detachment. In the case of the hybrid source the EEDF consists of a cold Maxwellian in the central region of the source; the electron temperature increases with increasing discharge current (rising from 0.3 eV at 1 A to 1.2 eV at 50 A when the pressure is 0.4 Pa). A hot electron tail exists in the EEDF of the driver region adjacent to each filament which is shown to consist of a distinct group of primary electrons at low pressure (0.08 Pa) but becomes degraded mainly through inelastic collisions at higher pressures (0.27 Pa). The tandem source, on the other hand, has a single driver region which extends throughout the central region. The primary electron confinement times are much longer so that even at the lowest pressure considered (0.07 Pa) the primaries are degraded. In both cases the measured EEDF at specific locations and values of discharge operating parameters are used to establish the rate coefficients for the processes of importance in H{sup -} production and destruction. (author).

  18. Tomography of the fast electron Bremsstrahlung emission during lower hybrid current drive on Tore Supra

    Energy Technology Data Exchange (ETDEWEB)

    Peysson, Y.; Imbeaux, F. [Association Euratom-CEA, CEA/Cadarache, Dept. de Recherches sur la Fusion Controlee (DRFC), 13 - Saint-Paul-lez-Durance (France)

    1999-04-01

    A new tomography dedicated to detailed studies of the fast electron Bremsstrahlung emission in the hard X-ray (HXR) energy range between 20 and 200 keV during lower hybrid (LH) current drive experiments on the TORE SUPRA tokamak [Equipe TORE SUPRA, in Proceedings of the 15. Conference on Plasma Physics and Controlled Nuclear Fusion Research, Seville (International Atomic Energy Agency, Vienna, 1995), 1, AIEA-CN-60 / A1-5, p. 105] is presented. Radiation detection is performed by cadmium telluride(CdTe) semiconductors, which have most of the desirable features for a powerful diagnosing of magnetically confined hot plasmas - compact size, high X-ray stopping efficiency, fast timing characteristics, good energy resolution, no sensitivity to magnetic field, reasonable susceptibility to performance degradation from neutron/{gamma}-induced damages. This instrument is made of two independent cameras viewing a poloidal cross-section of the plasma, with respectively 21 and 38 detectors. A coarse spectrometry - 8 energy channels - is carried out for each chord, with an energy resolution of 20 keV. The spatial resolution in the core of the plasma is 4-5 cm, while the time sampling may be lowered down to of 2-4 ms. Powerful inversion techniques based on maximum entropy or regularization algorithms take fully advantage of the large number of line-integrated measurements for very robust estimates of the local HXR profiles as a function of time and photon energy. A detailed account of main characteristics and performances of the diagnostic is reported as well as preliminary results on LH current drive experiments. (authors)

  19. Nature of electron correlation and hybridization in NixCu1−xMnSb Heusler alloys

    Directory of Open Access Journals (Sweden)

    I. Sarkar

    2016-08-01

    Full Text Available The electronic structure of Heusler alloys having mixed magnetic phases, comprising of vicinal anti-ferromagnetic and ferromagnetic orders, is of great significance. We present the results of an electronic structure study on NixCu1−xMnSb Heusler alloys, using Mn-2p core-level photoemission spectroscopy. Room temperature data in the paramagnetic phase reveal a non-monotonic variation of both electron correlation strength and conduction-band hybridization such that the former enhances while the latter weakens for compositions showing a mixed phase relative to compositions at the phase boundaries to the ordered phases. The results suggest a possible electronic driving force for settling mixed-magnetic phases.

  20. Dynamics of the electron thermal diffusivity at improved energy confinement during lower hybrid plasma heating in the FT-2 tokamak

    Science.gov (United States)

    Kouprienko, D. V.; Altukhov, A. B.; Gurchenko, A. D.; Gusakov, E. Z.; Kantor, M. Yu.; Lashkul, S. I.; Esipov, L. A.

    2010-05-01

    The dynamics of electron heat transport at improved energy confinement during lower hybrid plasma heating in the FT-2 tokamak was studied experimentally. Evolution of the profiles of the electron temperature and density was thoroughly investigated under conditions of fast variation in the plasma parameters. The energy balance in the electron channel is calculated with the help of the ASTRA code by using the measured plasma parameters. Correlation is revealed between the dynamics of electron heat transport and the behavior of small-scale drift turbulence measured using the enhanced scattering correlation diagnostics. The suppression of heat transfer and turbulence agrees well with the increase in the shear of poloidal plasma rotation calculated from experimental data in the neoclassical approximation.

  1. Redox-active organometallics: magnetic and electronic couplings through carbon-silicon hybrid molecular connectors.

    Science.gov (United States)

    Hamon, Paul; Justaud, Frederic; Cador, Olivier; Hapiot, Philippe; Rigaut, Stéphane; Toupet, Loïc; Ouahab, Lahcène; Stueger, Harald; Hamon, Jean-René; Lapinte, Claude

    2008-12-24

    Treatment of the triflate complex Cp*(dppe)FeOTf [12; Cp* = eta(5)-C(5)(CH(3))(5), dppe = 1,2-bis(diphenylphosphino)ethane, OTf = CF(3)SO(3)] with an excess of HC[triple bond]C-(Si(CH(3))(2))(x)-C[triple bond]CH (x = 2-4) in diethyl ether provides the binuclear bis(vinylidene) derivatives [Cp*(dppe)Fe=C=CH(Si(CH(3))(2))(x)CH=C=Fe(dppe)Cp*][OTf](2) (x = 2, 13; x = 3, 14; x = 4, 15), which were isolated as ochre solids and rapidly characterized by FT-IR, (1)H, (31)P, and (13)C NMR spectroscopies. The complexes 13-15 were reacted with potassium tert-butoxide to afford the bis(alkynediyl) complexes [Cp*(dppe)Fe-C[triple bond]C(Si(CH(3))(2))(x)C[triple bond]C-Fe(dppe)Cp*] (x = 2, 1; x = 3, 2; x = 4, 3), which were isolated as orange powders in yields ranging from 76 to 91%. The IR, cyclic voltammetry, and UV-vis data obtained for 1-3 and the X-ray crystal structures determined for 1 and 3 reveal the importance of the sigma-pi conjugation (hyperconjugation) between the Si-Si sigma bond and the adjacent C[triple bond]C pi-symmetric orbitals in the description of the electronic structure of the ground state of these complexes. When reacted at low temperature with 2 equiv of [(C(5)H(5))(2)Fe]X or AgX [X = BPh(4), B(3,5-(CF(3))(2)C(6)H(3))(4))], compounds 1-3 provide 1[X](2), 2[X](2), and 3[X](2), which can be isolated and stored below -20 degrees C. EPR spectroscopy and magnetization measurements established that the superexchange interaction propagates through the Si-Si bonds (J = -0.97(2) cm(-1) for 3[X](2)). UV-vis-near-IR spectra were obtained with an optically transparent thin-layer electrosynthetic (OTTLE) cell for 1-3[OTf](n) (n = 0-2). A band with a maximum that increases from 6400 cm(-1) (1[OTf]) to 8500 cm(-1) (3[OTf]) observed for the mixed-valence species was ascribed to intervalence charge transfer evidencing photodriven electron transfer through the carbon-silicon hybrid connectors with H(ab) parameters ranging from 64 to 285 cm(-1).

  2. Operation of Lanzhou all permanent electron cyclotron resonance ion source No. 2 on 320 kV platform with highly charged ions.

    Science.gov (United States)

    Lu, W; Li, J Y; Kang, L; Liu, H P; Li, H; Li, J D; Sun, L T; Ma, X W

    2014-02-01

    The 320 kV platform for multi-discipline research with highly charged ions is a heavy ion beam acceleration instrument developed by Institute of Modern Physics, which is dedicated to basic scientific researches such as plasma, atom, material physics, and astrophysics, etc. The platform has delivered ion beams of 400 species for 36,000 h. The average operation time is around 5000 h/year. With the beams provided by the platform, lots of outstanding progresses were made in various research fields. The ion source of the platform is an all-permanent magnet electron cyclotron resonance ion source, LAPECR2 (Lanzhou All Permanent ECR ion source No. 2). The maximum axial magnetic fields are 1.28 T at injection and 1.07 T at extraction, and the radial magnetic field is up to 1.21 T at the inner wall of the plasma chamber. The ion source is capable to produce low, medium, and high charge state gaseous and metallic ion beams, such as H(+), (40)Ar(8+), (129)Xe(30+), (209)Bi(33+), etc. This paper will present the latest result of LAPECR2 and the routine operation status for the high voltage platform.

  3. Operation of Lanzhou all permanent electron cyclotron resonance ion source No. 2 on 320 kV platform with highly charged ions

    Science.gov (United States)

    Lu, W.; Li, J. Y.; Kang, L.; Liu, H. P.; Li, H.; Li, J. D.; Sun, L. T.; Ma, X. W.

    2014-02-01

    The 320 kV platform for multi-discipline research with highly charged ions is a heavy ion beam acceleration instrument developed by Institute of Modern Physics, which is dedicated to basic scientific researches such as plasma, atom, material physics, and astrophysics, etc. The platform has delivered ion beams of 400 species for 36 000 h. The average operation time is around 5000 h/year. With the beams provided by the platform, lots of outstanding progresses were made in various research fields. The ion source of the platform is an all-permanent magnet electron cyclotron resonance ion source, LAPECR2 (Lanzhou All Permanent ECR ion source No. 2). The maximum axial magnetic fields are 1.28 T at injection and 1.07 T at extraction, and the radial magnetic field is up to 1.21 T at the inner wall of the plasma chamber. The ion source is capable to produce low, medium, and high charge state gaseous and metallic ion beams, such as H+, 40Ar8+, 129Xe30+, 209Bi33+, etc. This paper will present the latest result of LAPECR2 and the routine operation status for the high voltage platform.

  4. Operation of Lanzhou all permanent electron cyclotron resonance ion source No. 2 on 320 kV platform with highly charged ions

    Energy Technology Data Exchange (ETDEWEB)

    Lu, W., E-mail: luwang@impcas.ac.cn [Institute of Modern Physics, CAS, Lanzhou 730000 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Li, J. Y.; Kang, L.; Liu, H. P.; Li, H.; Li, J. D.; Sun, L. T.; Ma, X. W. [Institute of Modern Physics, CAS, Lanzhou 730000 (China)

    2014-02-15

    The 320 kV platform for multi-discipline research with highly charged ions is a heavy ion beam acceleration instrument developed by Institute of Modern Physics, which is dedicated to basic scientific researches such as plasma, atom, material physics, and astrophysics, etc. The platform has delivered ion beams of 400 species for 36 000 h. The average operation time is around 5000 h/year. With the beams provided by the platform, lots of outstanding progresses were made in various research fields. The ion source of the platform is an all-permanent magnet electron cyclotron resonance ion source, LAPECR2 (Lanzhou All Permanent ECR ion source No. 2). The maximum axial magnetic fields are 1.28 T at injection and 1.07 T at extraction, and the radial magnetic field is up to 1.21 T at the inner wall of the plasma chamber. The ion source is capable to produce low, medium, and high charge state gaseous and metallic ion beams, such as H{sup +}, {sup 40}Ar{sup 8+}, {sup 129}Xe{sup 30+}, {sup 209}Bi{sup 33+}, etc. This paper will present the latest result of LAPECR2 and the routine operation status for the high voltage platform.

  5. Fabrication and interfacial electronic structure studies on polypyrrole/TiO2 nano hybrid systems for photovoltaic aspects.

    Science.gov (United States)

    Kumar, Ganesan Mohan; Kawakita, Jin; Jayavel, Ramasamy

    2011-05-01

    The progress in studying the interfacial electronic structures of the developing new class of hybrid organic/inorganic material systems have envisaged a new dimension into the field of photovoltaics, which could be of great help in understanding the nature of charge transfer in them. In this regard, electropolymerization of pyrrole monomers have been carried out at room temperature on the surface of TiO2 working electrodes (assisted by UV radiations) and their interfacial electronic structure has been studied as a function of the applied photo anodic potentials. The formation of polypyrrole deposits has been ensured using FT-IR and Raman spectroscopy. Surface analysis of the hybrid matrix revealed the tendency of polymer molecules to cover up the spherical surface of TiO2 nanoparticles that could help in improving the light absorption rate. Signals (bands) corresponding to pyrrole molecules observed in the ultraviolet photoelectron spectroscopy measurements have been correlated with the polaronic states formed and identified to shift as a function of the applied photo anodic potentials, revealing the decrease in work function of the hybrid system to take place (confirmed using cyclic voltammetry measurements). The decreasing trend in the work function elucidates the adjustment in electronic structure of the system (hybrid materials possessing smaller work functions are generally preferred for photovoltaic studies). The aforementioned behavioural aspects have been reasoned with the increase in overpotential values for polarization, from the decrease in up-take rate of the anionic dopant, which increases the current density values, thereby modifying the conductivity of the systems.

  6. A Nanostructured Bifunctional platform for Sensing of Glucose Biomarker in Artificial Saliva: Synergy in hybrid Pt/Au surfaces.

    Science.gov (United States)

    Raymundo-Pereira, Paulo A; Shimizu, Flávio M; Coelho, Dyovani; Piazzeta, Maria H O; Gobbi, Angelo L; Machado, Sergio A S; Oliveira, Osvaldo N

    2016-12-15

    We report on a bimetallic, bifunctional electrode where a platinum (Pt) surface was patterned with nanostructured gold (Au) fingers with different film thicknesses, which was functionalized with glucose oxidase (GOx) to yield a highly sensitive glucose biosensor. This was achieved by using selective adsorption of a self-assembled monolayer (SAM) onto Au fingers, which allowed GOx immobilization only onto the Au-SAM surface. This modified electrode was termed bifunctional because it allowed to simultaneously immobilize the biomolecule (GOx) on gold to catalyze glucose, and detect hydrogen peroxide on Pt sites. Optimized electrocatalytic activity was reached for the architecture Pt/Au-SAM/GOx with 50nm thickness of Au, where synergy between Pt and Au allowed for detection of hydrogen peroxide (H2O2) at a low applied potential (0V vs. Ag/AgCl). Detection was performed for H2O2 in the range between 4.7 and 102.7 nmol L(-1), with detection limit of 3.4×10(-9) mol L(-1) (3.4 nmol L(-1)) and an apparent Michaelis-Menten rate constant of 3.2×10(-6)molL(-1), which is considerably smaller than similar devices with monometallic electrodes. The methodology was validated by measuring glucose in artificial saliva, including in the presence of interferents. The synergy between Pt and Au was confirmed in electrochemical impedance spectroscopy measurements with an increased electron transfer, compared to bare Pt and Au electrodes. The approach for fabricating the reproducible bimetallic Pt/Au electrodes is entirely generic and may be explored for other types of biosensors and biodevices where advantage can be taken of the combination of the two metals.

  7. Protonic/electronic hybrid oxide transistor gated by chitosan and its full-swing low voltage inverter applications

    Energy Technology Data Exchange (ETDEWEB)

    Chao, Jin Yu [Shanxi Province Key Laboratory High Gravity Chemical Engineering, North University of China, Taiyuan 030051 (China); Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201 (China); Zhu, Li Qiang, E-mail: lqzhu@nimte.ac.cn; Xiao, Hui [Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201 (China); Yuan, Zhi Guo, E-mail: ncityzg@163.com [Shanxi Province Key Laboratory High Gravity Chemical Engineering, North University of China, Taiyuan 030051 (China)

    2015-12-21

    Modulation of charge carrier density in condensed materials based on ionic/electronic interaction has attracted much attention. Here, protonic/electronic hybrid indium-zinc-oxide (IZO) transistors gated by chitosan based electrolyte were obtained. The chitosan-based electrolyte illustrates a high proton conductivity and an extremely strong proton gating behavior. The transistor illustrates good electrical performances at a low operating voltage of ∼1.0 V such as on/off ratio of ∼3 × 10{sup 7}, subthreshold swing of ∼65 mV/dec, threshold voltage of ∼0.3 V, and mobility of ∼7 cm{sup 2}/V s. Good positive gate bias stress stabilities are obtained. Furthermore, a low voltage driven resistor-loaded inverter was built by using an IZO transistor in series with a load resistor, exhibiting a linear relationship between the voltage gain and the supplied voltage. The inverter is also used for decreasing noises of input signals. The protonic/electronic hybrid IZO transistors have potential applications in biochemical sensors and portable electronics.

  8. Medium-energy electrons and heavy ions in Jupiter's magnetosphere - Effects of lower hybrid wave-particle interactions

    Science.gov (United States)

    Barbosa, D. D.

    1986-01-01

    A theory of medium-energy (about keV) electrons and heavy ions in Jupiter's magnetosphere is presented. Lower hybrid waves are generated by the combined effects of a ring instability of neutral wind pickup ions and the modified two-stream instability associated with transport of cool Iogenic plasma. The quasi-linear energy diffusion coefficient for lower hybrid wave-particle interactions is evaluated, and several solutions to the diffusion equation are given. Calculations based on measured wave properties show that the noise substantially modifies the particle distribution functions. The effects are to accelerate superthermal ions and electrons to keV energies and to thermalize the pickup ions on time scales comparable to the particle residence time. The S(2+)/S(+) ratio at medium energies is a measure of the relative contribution from Iogenic thermal plasma and neutral wind ions, and this important quantity should be determined from future measurements. The theory also predicts a preferential acceleration of heavy ions with an accleration time that scales inversely with the root of the ion mass. Electrons accelerated by the process contribute to further reionization of the neutral wind by electron impact, thus providing a possible confirmation of Alfven's critical velocity effect in the Jovian magnetosphere.

  9. An Analysis Of Methods For Sharing An Electronic Platform Of Public Administration Services Using Cloud Computing And Service Oriented Architecture

    Directory of Open Access Journals (Sweden)

    Maciej Hamiga

    2012-01-01

    Full Text Available This paper presents a case study on how to design and implement a publicadministration services platform, using the SOA paradigm and cloud model forsharing among citizens belonging to particular districts and provinces, providingtight integration with an existing ePUAP system. The basic requirements,architecture and implementation of the platform are all discussed. Practicalevaluation of the solution is elaborated using real-case scenario of the BusinessProcess Management related activities.

  10. A platform for large-scale graphene electronics--CVD growth of single-layer graphene on CVD-grown hexagonal boron nitride.

    Science.gov (United States)

    Wang, Min; Jang, Sung Kyu; Jang, Won-Jun; Kim, Minwoo; Park, Seong-Yong; Kim, Sang-Woo; Kahng, Se-Jong; Choi, Jae-Young; Ruoff, Rodney S; Song, Young Jae; Lee, Sungjoo

    2013-05-21

    Direct chemical vapor deposition (CVD) growth of single-layer graphene on CVD-grown hexagonal boron nitride (h-BN) film can suggest a large-scale and high-quality graphene/h-BN film hybrid structure with a defect-free interface. This sequentially grown graphene/h-BN film shows better electronic properties than that of graphene/SiO2 or graphene transferred on h-BN film, and suggests a new promising template for graphene device fabrication.

  11. A layer-by-layer ZnO nanoparticle-PbS quantum dot self-assembly platform for ultrafast interfacial electron injection

    KAUST Repository

    Eita, Mohamed Samir

    2014-08-28

    Absorbent layers of semiconductor quantum dots (QDs) are now used as material platforms for low-cost, high-performance solar cells. The semiconductor metal oxide nanoparticles as an acceptor layer have become an integral part of the next generation solar cell. To achieve sufficient electron transfer and subsequently high conversion efficiency in these solar cells, however, energy-level alignment and interfacial contact between the donor and the acceptor units are needed. Here, the layer-by-layer (LbL) technique is used to assemble ZnO nanoparticles (NPs), providing adequate PbS QD uptake to achieve greater interfacial contact compared with traditional sputtering methods. Electron injection at the PbS QD and ZnO NP interface is investigated using broadband transient absorption spectroscopy with 120 femtosecond temporal resolution. The results indicate that electron injection from photoexcited PbS QDs to ZnO NPs occurs on a time scale of a few hundred femtoseconds. This observation is supported by the interfacial electronic-energy alignment between the donor and acceptor moieties. Finally, due to the combination of large interfacial contact and ultrafast electron injection, this proposed platform of assembled thin films holds promise for a variety of solar cell architectures and other settings that principally rely on interfacial contact, such as photocatalysis. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Effect of primary electron drift on the negative ion efficiency of a volume hybrid multicusp H[sup [minus

    Energy Technology Data Exchange (ETDEWEB)

    Courteille, C.; Bruneteau, J.; Valckx, F.P.G.; Sledziewski, Z.; Bacal, M. (Laboratoire de Physique des Milieux Ionises, Laboratoire du CNRS, Ecole Polytechnique, 91128 Palaiseau Cedex (France))

    1992-10-05

    A new, large, hybrid volume negative ion source is described. Observations of curvature and [ital grad] [ital B] primary electron drift in the multicusp magnetic field are reported. The direction of the electron drift changes from one filament to the neighboring one, because of the change in the direction of the magnetic field. For a given discharge current the extracted negative ion current and the plasma density at the center of the extraction region are affected by the direction of the primary electron drift of the active filaments. It was shown, however, that the negative ion current is controlled by the plasma density at the center of the extraction region. A trajectory calculation, effected in the guiding center approximation, allows to estimate the average drift velocity.

  13. Ti/Au Cathode for Electronic transport material-free organic-inorganic hybrid perovskite solar cells

    Science.gov (United States)

    Shi, Tongfei; Chen, Jian; Zheng, Jianqiang; Li, Xinhua; Zhou, Bukang; Cao, Huaxiang; Wang, Yuqi

    2016-12-01

    We have fabricated organic-inorganic hybrid perovskite solar cell that uses a Ti/Au multilayer as cathode and does not use electron transport materials, and achieved the highest power conversion efficiency close to 13% with high reproducibility and hysteresis-free photocurrent curves. Our cell has a Schottky planar heterojunction structure (ITO/PEDOT:PSS/perovskite/Ti/Au), in which the Ti insertion layer isolate the perovskite and Au layers, thus proving good contact between the Au and perovskite and increasing the cells’ shunt resistance greatly. Moreover, the Ti/Au cathode in direct contact with hybrid perovskite showed no reaction for a long-term exposure to the air, and can provide sufficient protection and avoid the perovskite and PEDOT:PSS layers contact with moisture. Hence, the Ti/Au based devices retain about 70% of their original efficiency after 300 h storage in the ambient environment.

  14. SU-E-T-112: An OpenCL-Based Cross-Platform Monte Carlo Dose Engine (oclMC) for Coupled Photon-Electron Transport

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Z; Shi, F; Folkerts, M; Qin, N; Jiang, S; Jia, X [The University of Texas Southwestern Medical Ctr, Dallas, TX (United States)

    2015-06-15

    Purpose: Low computational efficiency of Monte Carlo (MC) dose calculation impedes its clinical applications. Although a number of MC dose packages have been developed over the past few years, enabling fast MC dose calculations, most of these packages were developed under NVidia’s CUDA environment. This limited their code portability to other platforms, hindering the introduction of GPU-based MC dose engines to clinical practice. To solve this problem, we developed a cross-platform fast MC dose engine named oclMC under OpenCL environment for external photon and electron radiotherapy. Methods: Coupled photon-electron simulation was implemented with standard analogue simulation scheme for photon transport and Class II condensed history scheme for electron transport. We tested the accuracy and efficiency of oclMC by comparing the doses calculated using oclMC and gDPM, a previously developed GPU-based MC code on NVidia GPU platform, for a 15MeV electron beam and a 6MV photon beam in a homogenous water phantom, a water-bone-lung-water slab phantom and a half-slab phantom. We also tested code portability of oclMC on different devices, including an NVidia GPU, two AMD GPUs and an Intel CPU. Results: Satisfactory agreements were observed in all photon and electron cases, with ∼0.48%–0.53% average dose differences at regions within 10% isodose line for electron beam cases and ∼0.15%–0.17% for photon beam cases. It took oclMC 3–4 sec to perform transport simulation for electron beam on NVidia Titan GPU and 35–51 sec for photon beam, both with ∼0.5% statistical uncertainty. The computation was 6%–17% slower than gDPM due to the differences in both physics model and development environment, which is considered not significant for clinical applications. In terms of code portability, gDPM only runs on NVidia GPUs, while oclMC successfully runs on all the tested devices. Conclusion: oclMC is an accurate and fast MC dose engine. Its high cross-platform

  15. Organic-inorganic hybrid lead halide perovskites for optoelectronic and electronic applications.

    Science.gov (United States)

    Zhao, Yixin; Zhu, Kai

    2016-02-07

    Organic and inorganic hybrid perovskites (e.g., CH(3)NH(3)PbI(3)), with advantages of facile processing, tunable bandgaps, and superior charge-transfer properties, have emerged as a new class of revolutionary optoelectronic semiconductors promising for various applications. Perovskite solar cells constructed with a variety of configurations have demonstrated unprecedented progress in efficiency, reaching about 20% from multiple groups after only several years of active research. A key to this success is the development of various solution-synthesis and film-deposition techniques for controlling the morphology and composition of hybrid perovskites. The rapid progress in material synthesis and device fabrication has also promoted the development of other optoelectronic applications including light-emitting diodes, photodetectors, and transistors. Both experimental and theoretical investigations on organic-inorganic hybrid perovskites have enabled some critical fundamental understandings of this material system. Recent studies have also demonstrated progress in addressing the potential stability issue, which has been identified as a main challenge for future research on halide perovskites. Here, we review recent progress on hybrid perovskites including basic chemical and crystal structures, chemical synthesis of bulk/nanocrystals and thin films with their chemical and physical properties, device configurations, operation principles for various optoelectronic applications (with a focus on solar cells), and photophysics of charge-carrier dynamics. We also discuss the importance of further understanding of the fundamental properties of hybrid perovskites, especially those related to chemical and structural stabilities.

  16. Driving electrocatalytic activity by interface electronic structure control in a metalloprotein hybrid catalyst for efficient hydrogen evolution.

    Science.gov (United States)

    Behera, Sushant Kumar; Deb, Pritam; Ghosh, Arghya

    2016-08-17

    The rational design of metalloprotein hybrid structures and precise calculations for understanding the role of the interfacial electronic structure in regulating the HER activity of water splitting sites and their microscopic effect for obtaining robust hydrogen evolution possess great promise for developing highly efficient nano-bio hybrid HER catalysts. Here, we employ high-accuracy linear-scaling density functional theory calculations using a near-complete basis set and a minimal parameter implicit solvent model within the self-consistent calculations, on silver (Ag) ions assimilated on bacteriorhodopsin (bR) at specific binding sites. Geometry optimization indicates the formation of active sites at the interface of the metalloprotein complex and the density of states reflects the metallic nature of the active sites. The reduced value of the canonical orbital gap indicates the state of dynamic nature after Ag ion assimilation on active sites and smooth electron transfer. These incorporated active protein sites are more efficient in electrolytic splitting of water than pristine sites due to their low value of Gibbs free energy for the HER in terms of hydrogen coverages. Volcano plot analysis and the free energy diagram are compared for understanding the hydrogen evolution efficiency. Moreover, the essential role of the interfacial electronic properties in regulating the HER catalytic activity of water splitting sites and enhancing the efficiency is elucidated.

  17. Applications of the Hybrid Theory to the Scattering of Electrons from HE+ and Li++ and Resonances in these Systems

    Science.gov (United States)

    Bhatia, Anand K.

    2008-01-01

    Applications of the hybrid theory to the scattering of electrons from Ile+ and Li++ and resonances in these systems, A. K. Bhatia, NASA/Goddard Space Flight Center- The Hybrid theory of electron-hydrogen elastic scattering [I] is applied to the S-wave scattering of electrons from He+ and Li++. In this method, both short-range and long-range correlations are included in the Schrodinger equation at the same time. Phase shifts obtained in this calculation have rigorous lower bounds to the exact phase shifts and they are compared with those obtained using the Feshbach projection operator formalism [2], the close-coupling approach [3], and Harris-Nesbet method [4]. The agreement among all the calculations is very good. These systems have doubly-excited or Feshbach resonances embedded in the continuum. The resonance parameters for the lowest ' S resonances in He and Li+ are calculated and they are compared with the results obtained using the Feshbach projection operator formalism [5,6]. It is concluded that accurate resonance parameters can be obtained by the present method, which has the advantage of including corrections due to neighboring resonances and the continuum in which these resonances are embedded.

  18. ORNL TNS program: microwave start-up of tokamak plasmas near electron cyclotron and upper hybrid resonances

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Y. K.M.; Borowski, S. K.

    1977-12-01

    The scenario of toroidal plasma start-up with microwave initiation and heating near the electron cyclotron frequency is suggested and examined here. We assume microwave irradiation from the high field side and an anomalously large absorption of the extraordinary waves near the upper hybrid resonance. The dominant electron energy losses are assumed to be due to magnetic field curvature and parallel drifts, ionization of neutrals, cooling by ions, and radiation by low Z impurities. It is shown by particle and energy balance considerations that electron temperatures around 250 eV and densities of 10/sup 12/ to 10/sup 13/ cm/sup -3/ can be maintained, at least in a narrow region near the upper hybrid resonance, with modest microwave powers in the Impurity Study Experiment (ISX) (120 kW at 28 GHz) and The Next Step (TNS) (0.57 MW at 120 GHz). The loop voltages required for start-up from these initial plasmas are also estimated. It is shown that the loop voltage can be reduced by a factor of five to ten from that for unassisted start-up without an increase in the resistive loss in volt-seconds. If this reduction in loop voltage is verified in the ISX experiments, substantial savings in the cost of power supplies for the ohmic heating (OH) and equilibrium field (EF) coils can be realized in future large tokamaks.

  19. Controlled growth of carbon nanotube-graphene hybrid materials for flexible and transparent conductors and electron field emitters.

    Science.gov (United States)

    Nguyen, Duc Dung; Tai, Nyan-Hwa; Chen, Szu-Ying; Chueh, Yu-Lun

    2012-01-21

    We report a versatile synthetic process based on rapid heating and cooling chemical vapor deposition for the growth of carbon nanotube (CNT)-graphene hybrid materials where the thickness of graphene and density of CNTs are properly controlled. Graphene films are demonstrated as an efficient barrier layer for preventing poisoning of iron nanoparticles, which catalyze the growth of CNTs on copper substrates. Based on this method, the opto-electronic and field emission properties of graphene integrated with CNTs can be remarkably tailored. A graphene film exhibits a sheet resistance of 2.15 kΩ sq(-1) with a transmittance of 85.6% (at 550 nm), while a CNT-graphene hybrid film shows an improved sheet resistance of 420 Ω sq(-1) with an optical transmittance of 72.9%. Moreover, CNT-graphene films are demonstrated as effective electron field emitters with low turn-on and threshold electric fields of 2.9 and 3.3 V μm(-1), respectively. The development of CNT-graphene films with a wide range of tunable properties presented in this study shows promising applications in flexible opto-electronic, energy, and sensor devices.

  20. 3D electrostatic gyrokinetic electron and fully kinetic ion simulation of lower-hybrid drift instability of Harris current sheet

    Science.gov (United States)

    Wang, Zhenyu; Lin, Yu; Wang, Xueyi; Tummel, Kurt; Chen, Liu

    2016-07-01

    The eigenmode stability properties of three-dimensional lower-hybrid-drift-instabilities (LHDI) in a Harris current sheet with a small but finite guide magnetic field have been systematically studied by employing the gyrokinetic electron and fully kinetic ion (GeFi) particle-in-cell (PIC) simulation model with a realistic ion-to-electron mass ratio mi/me . In contrast to the fully kinetic PIC simulation scheme, the fast electron cyclotron motion and plasma oscillations are systematically removed in the GeFi model, and hence one can employ the realistic mi/me . The GeFi simulations are benchmarked against and show excellent agreement with both the fully kinetic PIC simulation and the analytical eigenmode theory. Our studies indicate that, for small wavenumbers, ky, along the current direction, the most unstable eigenmodes are peaked at the location where k →.B → =0 , consistent with previous analytical and simulation studies. Here, B → is the equilibrium magnetic field and k → is the wavevector perpendicular to the nonuniformity direction. As ky increases, however, the most unstable eigenmodes are found to be peaked at k →.B → ≠0 . In addition, the simulation results indicate that varying mi/me , the current sheet width, and the guide magnetic field can affect the stability of LHDI. Simulations with the varying mass ratio confirm the lower hybrid frequency and wave number scalings.

  1. Construction of Multi-Platform Electronic Music System%多系统平台协作电子音乐系统研究与实现

    Institute of Scientific and Technical Information of China (English)

    杨万钧

    2014-01-01

    With the development of computer technology, there are more possibility in electronic music composition and production. As hardware and software systems developing, taking advantage of multi-platform in the composition of electronic music is coming true. The article will try to analyze the factors of construction of multi-platform electronic music system, and help the electronic musicians to construct and research in the ifeld.%计算机技术的发展,为电子音乐的创作与实现提供了基本保障,并且为电子音乐的发展提供了更多的可能性。随着软硬件系统的发展,利用多种不同软硬件平台的协作,共同完成电子音乐创作与实践也就成为一种可能。通过对相关要素的梳理,为构建多系统平台协作的电子音乐系统提供理论和实践的分析与支撑。

  2. A software platform to analyse the ethical issues of electronic patient privacy policy: the S3P example

    OpenAIRE

    Mizani, M A; Baykal, N

    2007-01-01

    Paper‐based privacy policies fail to resolve the new changes posed by electronic healthcare. Protecting patient privacy through electronic systems has become a serious concern and is the subject of several recent studies. The shift towards an electronic privacy policy introduces new ethical challenges that cannot be solved merely by technical measures. Structured Patient Privacy Policy (S3P) is a software tool assuming an automated electronic privacy policy in an electronic healthcare setting...

  3. 移动电子支付平台的设计探讨%The design of mobile electronic payment platform

    Institute of Scientific and Technical Information of China (English)

    徐可塑

    2014-01-01

    Mobile electronic payment belongs to the Banks and mobile operators to launch a new service projects together,it is the advantage of the wireless communication technology and the current financial business,supply convenient,fast and free service for the customer.There are many ways to the current mobile payment,such as SMS,STK,BREW,WAP,etc.,mobile electronic payment platform,customer interface is very convenient,the input and output are more convenient,safe and easy to popularize.Through the system compatibility and language advantage,make the function of the server.The design of mobile electronic payment platform is an important part of mobile e-commerce.For mobile electronic payment platform,its security,privacy,ease of use has become the most important points.At present,there are many different types of technology for mobile electronic payment can,this paper discusses the design for mobile electronic payment platform.%移动电子支付属于银行及移动运营商一同推出的全新的服务项目,它把无线通信技术的优势以及当前的金融业务相融合,为客户供应便利、快捷、自由的服务。当前手机支付有很多方式,例如:SMS、STK、BREW、WAP等,移动电子支付平台的客户界面非常便利,输入和输出较为方便,安全性较高并且易于普及。通过系统的兼容性和语言的优势,让服务器的功能得以实现。移动电子支付平台的设计是移动电子商务的一项重要部分。对于移动电子支付平台来讲,其安全性、私密性、易用性成为了最重要的几点。当前,有很多不同类别的技术可以进行移动电子支付,文章针对移动电子支付平台设计进行探讨。

  4. Design of thermal reliability platform for electronic equipment%电子设备的热可靠性平台设计

    Institute of Scientific and Technical Information of China (English)

    杨青

    2016-01-01

    本文是针对于电子设备的热属性测试和热设计优化建立一个可靠性应用研发平台。平台分为热测试和热设计两个模块,热测试半导体器件的热学属性的精确测量和外围散热设备的选型和验证,并结合热设计部分,保证仿真结果的准确性,并可进行结构和选型的优化,平台囊括电力电子产品化过程中热可靠性设计的所有环节。%This paper is aimed at the thermal property testing and thermal design optimization of electronic equipment to establish a reliable application research and development platform.Selection and validation of the platform is divided into two modules,thermal test and thermal design,thermal test semiconductor device thermal properties of accurate measurement and peripheral cooling equipment,combined with thermal design,ensure the accuracy of the simulation results,and can carry on the optimization of structure and selection,the platform include thermal reliability design in the course of power electronic products in all aspects.

  5. Study of the hybrid controller electronics for the nano-stabilization of mechanical vibrations of CLIC quadrupoles

    CERN Document Server

    Fernandez Carmona, P; Collette, C; Esposito, M; Guinchard, M; Janssens, S; Kuzmin, A; Moron Ballester, R

    2011-01-01

    In order to achieve the required levels of luminosity in the CLIC linear collider, mechanical stabilization of quadrupoles to the nanometre level is required. The paper describes a design of hybrid electronics combining an analogue controller and digital communication with the main machine controller. The choice of local analogue control ensures the required low latency while still keeping sufficiently low noise level. Furthermore, it reduces the power consumption, rack space and cost. Sensitivity to radiation single events upsets is reduced compared to a digital controller. The digital part is required for fine tuning and real time monitoring via digitization of critical parameters.

  6. A camera for imaging hard x-rays from suprathermal electrons during lower hybrid current drive on PBX-M

    Energy Technology Data Exchange (ETDEWEB)

    von Goeler, S.; Kaita, R.; Bernabei, S.; Davis, W.; Fishman, H.; Gettelfinger, G.; Ignat, D.; Roney, P.; Stevens, J.; Stodiek, W. (Princeton Univ., NJ (United States). Plasma Physics Lab.); Jones, S.; Paoletti, F. (Massachusetts Inst. of Tech., Cambridge, MA (United States). Plasma Fusion Center); Petravich, G. (Hungarian Academy of Sciences, Budapest (Hungary). Central Research Inst. for Physics); Rimini,

    1993-05-01

    During lower hybrid current drive (LHCD), suprathermal electrons are generated that emit hard X-ray bremsstrahlung. A pinhole camera has been installed on the PBX-M tokamak that records 128 [times] 128 pixel images of the bremsstrahlung with a 3 ms time resolution. This camera has identified hollow radiation profiles on PBX-M, indicating off-axis current drive. The detector is a 9in. dia. intensifier. A detailed account of the construction of the Hard X-ray Camera, its operation, and its performance is given.

  7. Ultrafast electron transfer from low band gap conjugated polymer to quantum dots in hybrid photovoltaic materials

    Science.gov (United States)

    Couderc, Elsa; Greaney, Matthew J.; Thornbury, William; Brutchey, Richard L.; Bradforth, Stephen E.

    2014-09-01

    Ultrafast transient absorption spectroscopy is used in conjunction with chemical doping experiments to study the photo-generation of charges in hybrid thin films composed of PCPDTBT and CdSe quantum dots. We show how we use chemical doping experiments to de-convolute the spectral signatures of the transient states in the near infrared.

  8. Understanding the electronic structure of CdSe quantum dot-fullerene (C60) hybrid nanostructure for photovoltaic applications

    Science.gov (United States)

    Sarkar, Sunandan; Rajbanshi, Biplab; Sarkar, Pranab

    2014-09-01

    By using the density-functional tight binding method, we studied the electronic structure of CdSe quantum dot(QD)-buckminsterfullerene (C60) hybrid systems as a function of both the size of the QD and concentration of the fullerene molecule. Our calculation reveals that the lowest unoccupied molecular orbital energy level of the hybrid CdSeQD-C60 systems lies on the fullerene moiety, whereas the highest occupied molecular orbital (HOMO) energy level lies either on the QD or the fullerene depending on size of the CdSe QD. We explored the possibility of engineering the energy level alignment by varying the size of the CdSe QD. With increase in size of the QD, the HOMO level is shifted upward and crosses the HOMO level of the C60-thiol molecule resulting transition from the type-I to type-II band energy alignment. The density of states and charge density plot support these types of band gap engineering of the CdSe-C60 hybrid systems. This type II band alignment indicates the possibility of application of this nanohybrid for photovoltaic purpose.

  9. A New Approach of Electronics and Photonics Convergence on Si CMOS Platform: How to Reduce Device Diversity of Photonics for Integration

    Directory of Open Access Journals (Sweden)

    Kazumi Wada

    2008-01-01

    Full Text Available Integrated photonics via Si CMOS technology has been a strategic area since electronics and photonics convergence should be the next platform for information technology. The platform is recently referred to as “Si photonics” that attracts much interest of researchers in industries as well as academia in the world. The main goal of Si Photonics is currently to reduce material diversity of photonic devices to pursuing CMOS-compatibility. In contrast, the present paper proposes another route of Si Photonics, reducing diversity of photonic devices. The proposed device unifying functionality of photonics is a microresonator with a pin diode structure that enables the Purcell effect and Franz-Keldysh effect to emit and to modulate light from SiGe alloys.

  10. Efficient Electron Collection in Hybrid Polymer Solar Cells: In-Situ-Generated ZnO/Poly(3-hexylthiophene) Scaffolded by a TiO2 Nanorod Array.

    Science.gov (United States)

    Liao, Wen-Pin; Wu, Jih-Jen

    2013-06-06

    A nanoarchitectural hybrid polymer solar cell, integrating the ordered and the bulk heterojunction hybrid polymer solar cells, is fabricated by infiltrating the diethylzinc/poly(3-hexylthiophene) (P3HT) solution into the interstices of the TiO2 nanorod (NR) array. An inorganic network composed of tiny ZnO nanocrystals is constructed in the in-situ-generated hybrid within the interstice of the single-crystalline TiO2 NRs. The TiO2 NR array, which possesses a longer electron lifetime and an appropriate electron-transport rate, serves not only as an electron transporter/collector extended from fluorine-doped tin oxide (FTO) electrode to sustain the efficient electron collection but also as a scaffold to hold the sufficient amount of ZnO/P3HT hybrid. The in-situ-generated ZnO/P3HT hybrid layer with superior charge separation efficiency can therefore be thickened in the presence of a TiO2 NR array for increasing the light-harvesting efficiency. A notable efficiency of 2.46% is therefore attained in the TiO2 NR-ZnO/P3HT hybrid solar cell.

  11. Screened Hybrid and DFT + U Studies of the Structural, Electronic, and Optical Properties of U3O8

    Energy Technology Data Exchange (ETDEWEB)

    Wen, Xiaodong; Martin, Richard L.; Scuseria, Gustavo E.; Rudin, Sven P.; Batista, Enrique R.; Burrell, Anthony K.

    2012-11-26

    A systematic comparison of the structures and electronic and optical properties of U3O8 in the c2mm, P¯62m, and P21/m structures (the α, β, and γ phases, respectively) is performed using density functional theory + U (PBE + U) and the Heyd–Scuseria–Ernzerhof screened hybrid functional (HSE). The relationship between the semiconducting C2mm phase of U3O8 and the high temperature, metallic P¯62m phase is explored in more detail. Our calculated results show that the HSE functional gives a better description of the electronic and optical properties when compared with available experimental data for the α and β phases, but neither approach does particularly well for the high pressure γ phase.

  12. Screened hybrid and DFT + U studies of the structural, electronic, and optical properties of U3O8

    Science.gov (United States)

    Wen, Xiao-Dong; Martin, Richard L.; Scuseria, Gustavo E.; Rudin, Sven P.; Batista, Enrique R.; Burrell, Anthony K.

    2013-01-01

    A systematic comparison of the structures and electronic and optical properties of U3O8 in the c2mm, P\\bar {6}2 m, and P21/m structures (the α, β, and γ phases, respectively) is performed using density functional theory + U (PBE + U) and the Heyd-Scuseria-Ernzerhof screened hybrid functional (HSE). The relationship between the semiconducting C2mm phase of U3O8 and the high temperature, metallic P\\bar {6}2 m phase is explored in more detail. Our calculated results show that the HSE functional gives a better description of the electronic and optical properties when compared with available experimental data for the α and β phases, but neither approach does particularly well for the high pressure γ phase.

  13. Hybrids of organic molecules and flat, oxide-free silicon: high-density monolayers, electronic properties, and functionalization.

    Science.gov (United States)

    Li, Yan; Calder, Steven; Yaffe, Omer; Cahen, David; Haick, Hossam; Kronik, Leeor; Zuilhof, Han

    2012-07-03

    Since the first report of Si-C bound organic monolayers on oxide-free Si almost two decades ago, a substantial amount of research has focused on studying the fundamental mechanical and electronic properties of these Si/molecule surfaces and interfaces. This feature article covers three closely related topics, including recent advances in achieving high-density organic monolayers (i.e., atomic coverage >55%) on oxide-free Si(111) substrates, an overview of progress in the fundamental understanding of the energetics and electronic properties of hybrid Si/molecule systems, and a brief summary of recent examples of subsequent functionalization on these high-density monolayers, which can significantly expand the range of applicability. Taken together, these topics provide an overview of the present status of this active area of research.

  14. Electronic and optical properties of (U,Th)O2 compound from screened hybrid density functional studies

    Science.gov (United States)

    Mo, Chongjie; Yang, Yu; Kang, Wei; Zhang, Ping

    2016-04-01

    The electronic structure and optical properties for the (U,Th)O2 compound are systematically studied by employing the Heyd-Scuseria-Ernzerh method (HSE) of screened hybrid density functional. The electronic band gap of (U,Th)O2 is predicted to be 3.06 eV, in the middle of the values of UO2 and ThO2. Based on wavefunction analysis, we conclude (U,Th)O2 to be a Mott insulator in its ground state. The frequency dependent dielectric functions and optical properties are then calculated and compared with those of ThO2 and UO2. At the visible light frequency range, the adsorption coefficients for ThO2, UO2 and (U,Th)O2 are totally different, which gives an accessible method to predict the proportion of U atoms in an arbitrary unknown (U,Th)O2 compounds from the adsorption spectrum of visible lights.

  15. Photovoltaic System Test Platform with Integrated Battery Energy Storage Emulator

    DEFF Research Database (Denmark)

    Spataru, Sergiu; Sera, Dezso; Stroe, Daniel-Ioan

    2017-01-01

    In this work, we present a hybrid simulation and a real-time test platform for developing control systems for photovoltaic (PV) inverters with integrated battery energy storage (BES). The platform consists of a dual-stage single-phase PV inverter system, DC coupled with a full-bridge grid connected...... inverter, which emulates the charge regulator and battery bank. The real-time control of the two power electronic converters is implemented in a Simulink/dSpace platform, together with the real-time simulation model of the battery pack, whereas the PV array input can be connected to a PV emulator...... or directly to a physical PV array. The platform enables real-time testing of PV+BES control systems, including battery (BMS) and energy management systems (EMS), for a variety of battery technologies, which can be modelled in detail and emulated by the full-bridge grid connected inverter. Such flexibility...

  16. Tuning the electronic hybridization in the heavy fermion cage compound YbFe2Zn20 with Cd doping

    Science.gov (United States)

    Cabrera-Baez, M.; Ribeiro, R. A.; Avila, M. A.

    2016-09-01

    The tuning of the electronic properties of heavy fermion compounds by chemical substitution provides excellent opportunities for further understanding the physics of hybridized ions in crystal lattices. Here we present an investigation on the effects of Cd doping in flux-grown single crystals of the complex intermetallic cage compound YbFe2Zn20, which has been described as a heavy fermion with a Sommerfeld coefficient of 535 mJ mol-1 · K-2. The substitution of Cd for Zn disturbs the system by expanding the unit cell and, in this case, the size of the Zn cages that surround the Yb and Fe. With an increasing amount of Cd, the hybridization between the Yb 4f electrons and the conduction electrons is weakened, as shown by a decrease in the Sommerfeld coefficient, which should be accompanied by a valence shift of the Yb3+ due to the negative chemical pressure effect. This scenario is also supported by the low temperature DC magnetic susceptibility, which is gradually suppressed and shows an increment of the Kondo temperature, based on a shift to higher temperatures of the characteristic broad susceptibility peak. Furthermore, the DC resistivity decreases with the isoelectronic substitution of Cd for Zn, contrary to expectations in an increasingly disordered system, and implying that the valence shift is not related to charge carrier doping. The combined results demonstrate the excellent complementarity between positive physical pressure and negative chemical pressure, and point to a rich playground for exploring the physics and chemistry of strongly correlated electron systems in the general family of Zn20 compounds, despite their structural complexity.

  17. Implications of orbital hybridization on the electronic properties of doped quantum dots: the case of Cu:CdSe

    Energy Technology Data Exchange (ETDEWEB)

    Wright, Joshua T.; Forsythe, Kyle; Hutchins, Jamie; Meulenberg, Robert W.

    2016-04-13

    This paper investigates how chemical dopants affect the electronic properties of CdSe quantum dots (QDs) and why a model that incorporates the concepts of orbital hybridization must be used to understand these properties. Extended X-ray absorption fine structure spectroscopy measurements show that copper dopants in CdSe QDs occur primarily through a statistical doping mechanism. Ultraviolet photoemission spectroscopy (UPS) experiments provide a detailed insight on the valence band (VB) structure of doped and undoped QDs. Using UPS measurements, we are able to observe photoemission from the Cu d-levels above VB maximum of the QDs which allows a complete picture of the energy band landscape of these materials. This information provides insights into many of the physical properties of doped QDs, including the highly debated near-infrared photoluminescence in Cu doped CdSe QDs. We show that all our results point to a common theme of orbital hybridization in Cu doped CdSe QDs which leads to optically and electronically active states below the conduction band minimum. Our model is supported from current–voltage measurements of doped and undoped materials, which exhibit Schottky to Ohmic behavior with Cu doping, suggestive of a tuning of the lowest energy states near the Fermi level.

  18. Design of Passive Analog Electronic Circuits Using Hybrid Modified UMDA algorithm

    Directory of Open Access Journals (Sweden)

    J. Slezak

    2015-04-01

    Full Text Available Hybrid evolutionary passive analog circuits synthesis method based on modified Univariate Marginal Distribution Algorithm (UMDA and a local search algorithm is proposed in the paper. The modification of the UMDA algorithm which allows to specify the maximum number of the nodes and the maximum number of the components of the synthesized circuit is proposed. The proposed hybrid approach efficiently reduces the number of the objective function evaluations. The modified UMDA algorithm is used for synthesis of the topology and the local search algorithm is used for determination of the parameters of the components of the designed circuit. As an example the proposed method is applied to a problem of synthesis of the fractional capacitor circuit.

  19. First Principles Study on the Electronic Structure and Interface Stability of Hybrid Silicene/Fluorosilicene Nanoribbons

    OpenAIRE

    Jiang, Q G; Zhang, J. F.; Ao, Z. M.; Y. P. Wu

    2015-01-01

    The interface stability of hybrid silicene/fluorosilicene nanoribbons (SFNRs) has been investigated by using density functional theory calculations, where fluorosilicene is the fully fluorinated silicene. It is found that the diffusion of F atoms at the zigzag and armchair interfaces of SFNRs is endothermic, and the corresponding minimum energy barriers are respectively 1.66 and 1.56?eV, which are remarkably higher than the minimum diffusion energy barrier of one F atom and two F atoms on pri...

  20. HySDeP: a computational platform for on-board hydrogen storage systems – hybrid high-pressure solid-state and gaseous storage

    DEFF Research Database (Denmark)

    Mazzucco, Andrea; Rokni, Masoud

    2016-01-01

    A computational platform is developed in the Modelica® language within the DymolaTM environment to provide a tool for the design and performance comparison of on-board hydrogen storage systems. The platform has been coupled with an open source library for hydrogen fueling stations to investigate...

  1. Carbon and metal nanotube hybrid structures on graphene as efficient electron field emitters

    Science.gov (United States)

    Heo, Kwang; Lee, Byung Yang; Lee, Hyungwoo; Cho, Dong-guk; Arif, Muhammad; Kim, Kyu Young; Choi, Young Jin; Hong, Seunghun

    2016-07-01

    We report a facile and efficient method for the fabrication of highly-flexible field emission devices by forming tubular hybrid structures based on carbon nanotubes (CNTs) and nickel nanotubes (Ni NTs) on graphene-based flexible substrates. By employing an infiltration process in anodic alumina oxide (AAO) templates followed by Ni electrodeposition, we could fabricate CNT-wrapped Ni NT/graphene hybrid structures. During the electrodeposition process, the CNTs served as Ni nucleation sites, resulting in a large-area array of high aspect-ratio field emitters composed of CNT-wrapped Ni NT hybrid structures. As a proof of concepts, we demonstrate that high-quality flexible field emission devices can be simply fabricated using our method. Remarkably, our proto-type field emission devices exhibited a current density higher by two orders of magnitude compared to other devices fabricated by previous methods, while maintaining its structural integrity in various bending deformations. This novel fabrication strategy can be utilized in various applications such as optoelectronic devices, sensors and energy storage devices.

  2. Hybrid matrix method for stable numerical analysis of the propagation of Dirac electrons in gapless bilayer graphene superlattices

    Science.gov (United States)

    Briones-Torres, J. A.; Pernas-Salomón, R.; Pérez-Álvarez, R.; Rodríguez-Vargas, I.

    2016-05-01

    Gapless bilayer graphene (GBG), like monolayer graphene, is a material system with unique properties, such as anti-Klein tunneling and intrinsic Fano resonances. These properties rely on the gapless parabolic dispersion relation and the chiral nature of bilayer graphene electrons. In addition, propagating and evanescent electron states coexist inherently in this material, giving rise to these exotic properties. In this sense, bilayer graphene is unique, since in most material systems in which Fano resonance phenomena are manifested an external source that provides extended states is required. However, from a numerical standpoint, the presence of evanescent-divergent states in the eigenfunctions linear superposition representing the Dirac spinors, leads to a numerical degradation (the so called Ωd problem) in the practical applications of the standard Coefficient Transfer Matrix (K) method used to study charge transport properties in Bilayer Graphene based multi-barrier systems. We present here a straightforward procedure based in the hybrid compliance-stiffness matrix method (H) that can overcome this numerical degradation. Our results show that in contrast to standard matrix method, the proposed H method is suitable to study the transmission and transport properties of electrons in GBG superlattice since it remains numerically stable regardless the size of the superlattice and the range of values taken by the input parameters: the energy and angle of the incident electrons, the barrier height and the thickness and number of barriers. We show that the matrix determinant can be used as a test of the numerical accuracy in real calculations.

  3. A software platform to analyse the ethical issues of electronic patient privacy policy: the S3P example.

    Science.gov (United States)

    Mizani, M A; Baykal, N

    2007-12-01

    Paper-based privacy policies fail to resolve the new changes posed by electronic healthcare. Protecting patient privacy through electronic systems has become a serious concern and is the subject of several recent studies. The shift towards an electronic privacy policy introduces new ethical challenges that cannot be solved merely by technical measures. Structured Patient Privacy Policy (S3P) is a software tool assuming an automated electronic privacy policy in an electronic healthcare setting. It is designed to simulate different access levels and rights of various professionals involved in healthcare in order to assess the emerging ethical problems. The authors discuss ethical issues concerning electronic patient privacy policies that have become apparent during the development and application of S3P.

  4. Hybrid Simulation of Laser-Plasma Interactions and Fast Electron Transport in Inhomogeneous Plasma

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, B I; Kemp, A; Divol, L

    2009-05-27

    A new framework is introduced for kinetic simulation of laser-plasma interactions in an inhomogenous plasma motivated by the goal of performing integrated kinetic simulations of fast-ignition laser fusion. The algorithm addresses the propagation and absorption of an intense electromagnetic wave in an ionized plasma leading to the generation and transport of an energetic electron component. The energetic electrons propagate farther into the plasma to much higher densities where Coulomb collisions become important. The high-density plasma supports an energetic electron current, return currents, self-consistent electric fields associated with maintaining quasi-neutrality, and self-consistent magnetic fields due to the currents. Collisions of the electrons and ions are calculated accurately to track the energetic electrons and model their interactions with the background plasma. Up to a density well above critical density, where the laser electromagnetic field is evanescent, Maxwell's equations are solved with a conventional particle-based, finite-difference scheme. In the higher-density plasma, Maxwell's equations are solved using an Ohm's law neglecting the inertia of the background electrons with the option of omitting the displacement current in Ampere's law. Particle equations of motion with binary collisions are solved for all electrons and ions throughout the system using weighted particles to resolve the density gradient efficiently. The algorithm is analyzed and demonstrated in simulation examples. The simulation scheme introduced here achieves significantly improved efficiencies.

  5. Electronic Interfacing Between a Living Cell and a Nanodevice: A Bio-Nano Hybrid System

    Energy Technology Data Exchange (ETDEWEB)

    Saraf, Ravi F. [Univ. of Nebraska, Lincoln, NE (United States). Dept. of Chemical and Biomolecular Engineering

    2013-12-31

    The primary goal of this program was to couple physical electronics with live cells to leverage the highly sophisticated functions of a biological system to ultimately create advanced functionality. The study was built on a unique self-assembled architecture of nanoparticles that exhibits transport properties that are sensitive to single-electron charge modulation. At room temperature, the energy of switching due to single-electron charge modulation was in the range of 4 to 100 kT. The structure invented in the principal investigator’s lab is a two-dimensional (2D) network of one-dimensional (1D) necklaces of 10 nm Au nanoparticles. The electron transport through the necklace network is regulated by quantum mechanical single-electron traps. As a result of the single electron traps, the all metal nanoparticle network array displays a conduction band gap. Fundamental studies on the transport properties of the network in air and water were studied to regulate the band gap by tailoring the network structure to demonstrate the first electrochemical single electron transistor operating in water. Cells were interfaced with the network to observe electrochemical activity in a cell during photosynthesis and single viral infection.

  6. Probing Electron Transfer Mechanisms in Shewanella oneidensis MR-1 using a Nanoelectrode Platform and Single-Cell Imaging

    Science.gov (United States)

    2010-01-01

    nanowires The capability of bacteria, such as Shewanella and Geobacter ,to transfer electrons from metabolism of organic sources to electrodes without...filamentous pili growth from Shewanella and Geobacter cells report a third mechanism for extracellular electron transfer through biological nanowires (12

  7. Business analysis for a sustainable, multi-stakeholder ecosystem for leveraging the Electronic Health Records for Clinical Research (EHR4CR) platform in Europe.

    Science.gov (United States)

    Dupont, Danielle; Beresniak, Ariel; Sundgren, Mats; Schmidt, Andreas; Ainsworth, John; Coorevits, Pascal; Kalra, Dipak; Dewispelaere, Marc; De Moor, Georges

    2017-01-01

    The Electronic Health Records for Clinical Research (EHR4CR) technological platform has been developed to enable the trustworthy reuse of hospital electronic health records data for clinical research. The EHR4CR platform can enhance and speed up clinical research scenarios: protocol feasibility assessment, patient identification for recruitment in clinical trials, and clinical data exchange, including for reporting serious adverse events. Our objective was to seed a multi-stakeholder ecosystem to enable the scalable exploitation of the EHR4CR platform in Europe, and to assess its economic sustainability. Market analyses were conducted by a multidisciplinary task force to define an EHR4CR emerging ecosystem and multi-stakeholder value chain. This involved mapping stakeholder groups and defining their unmet needs, incentives, potential barriers for adopting innovative solutions, roles and interdependencies. A comprehensive business model, value propositions, and sustainability strategies were developed accordingly. Using simulation modelling (including Monte Carlo simulations) and a 5-year horizon, the potential financial outcomes of the business model were forecasted from the perspective of an EHR4CR service provider. A business ecosystem was defined to leverage the EHR4CR multi-stakeholder value chain. Value propositions were developed describing the expected benefits of EHR4CR solutions for all stakeholders. From an EHR4CR service provider's viewpoint, the business model simulation estimated that a profitability ratio of up to 1.8 could be achieved at year 1, with potential for growth in subsequent years depending on projected market uptake. By enhancing and speeding up existing processes, EHR4CR solutions promise to transform the clinical research landscape. The ecosystem defined provides the organisational framework for optimising the value and benefits for all stakeholders involved, in a sustainable manner. Our study suggests that the exploitation of EHR4CR

  8. Single-Crystalline 3C-SiC anodically Bonded onto Glass: An Excellent Platform for High-Temperature Electronics and Bioapplications.

    Science.gov (United States)

    Phan, Hoang-Phuong; Cheng, Han-Hao; Dinh, Toan; Wood, Barry; Nguyen, Tuan-Khoa; Mu, Fengwen; Kamble, Harshad; Vadivelu, Raja; Walker, Glenn; Hold, Leonie; Iacopi, Alan; Haylock, Ben; Dao, Dzung Viet; Lobino, Mirko; Suga, Tadatomo; Nguyen, Nam-Trung

    2017-08-23

    Single-crystal cubic silicon carbide has attracted great attention for MEMS and electronic devices. However, current leakage at the SiC/Si junction at high temperatures and visible-light absorption of the Si substrate are main obstacles hindering the use of the platform in a broad range of applications. To solve these bottlenecks, we present a new platform of single crystal SiC on an electrically insulating and transparent substrate using an anodic bonding process. The SiC thin film was prepared on a 150 mm Si with a surface roughness of 7 nm using LPCVD. The SiC/Si wafer was bonded to a glass substrate and then the Si layer was completely removed through wafer polishing and wet etching. The bonded SiC/glass samples show a sharp bonding interface of less than 15 nm characterized using deep profile X-ray photoelectron spectroscopy, a strong bonding strength of approximately 20 MPa measured from the pulling test, and relatively high optical transparency in the visible range. The transferred SiC film also exhibited good conductivity and a relatively high temperature coefficient of resistance varying from -12 000 to -20 000 ppm/K, which is desirable for thermal sensors. The biocompatibility of SiC/glass was also confirmed through mouse 3T3 fibroblasts cell-culturing experiments. Taking advantage of the superior electrical properties and biocompatibility of SiC, the developed SiC-on-glass platform offers unprecedented potentials for high-temperature electronics as well as bioapplications.

  9. Effects of APTEOS content and electron beam irradiation on physical and separation properties of hybrid nylon-66 membranes

    Energy Technology Data Exchange (ETDEWEB)

    Linggawati, A. [Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Mohammad, A.W., E-mail: wahabm@eng.ukm.my [Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Leo, C.P. [School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, Seri Ampangan, 14300 Nibong Tebal, S.P.S., Penang (Malaysia)

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Hybrid nylon-66 membranes were prepared using APTEOS and modified by EB irradiation. Black-Right-Pointing-Pointer APTEOS increase the formation of cellular pores. Black-Right-Pointing-Pointer EB irradiation causes the growth of dense layer. Black-Right-Pointing-Pointer 10 wt% of APTEOS and irradiation at 70 kGy shows satisfactory separation of salt. - Abstract: Nylon-66 contains functional groups which form hydrogen bonds with inorganic silica networks and allow the creation of hybrid membranes. As a typical semicrystalline polymer, nylon-66 can be crosslinked through electron beam (EB) irradiation to form nanofiltration membranes. The effects of {gamma}-aminopropyltriethoxylsilane (APTEOS) and EB irradiation on the physical and separation properties of nylon-66 membranes were studied in this work. Hybrid nylon-66 membranes were prepared by adding an APTEOS solution (5 wt%, 10 wt% and 20 wt%) into nylon-66 which was dissolved in formic acid. Before air drying, membranes were irradiated at 60 kGy, 70 kGy and 80 kGy. More cellular pores were formed in nylon-66 membranes with the addition of APTEOS. However, increased irradiation dose caused the formation of a dense layer in nylon-66 membranes. Crosslinked silica in nylon-66 membranes was confirmed by FT-IR and DMA, while XRD results showed that there was a high degree of crystallinity in some membranes after irradiation. With improvements in membrane pore size and the ratio of membrane thickness to porosity, nylon-66 membrane with 10 wt% of APTEOS irradiated at 70 kGy exhibited satisfactory permeability, excellent removal of neutral solutes and improved rejection of divalent ions.

  10. Conducting polymer-coated Physarum polycephalum towards the synthesis of bio-hybrid electronic devices

    Science.gov (United States)

    de Lacy Costello, B. J. P.; Mayne, R.; Adamatzky, A.

    2015-04-01

    This paper presents a generic method for the production of functionalized coatings on biological substrates. The specific method described involves the functionalization of the living plasmodial stage of Physarum polycephalum with the conducting organic polymer polypyrrole. The simple method involves localized treatment of tube sections with a solution of ferric chloride, followed by exposure to the vapour or a liquid solution of the pyrrole monomer. This technique enables the production of surface-coated conducting plasmodial tubes of certain lengths to be formed at specific points. Measurement of the electrical resistance of a 1 cm functionalized tube gave a value of 100 k? . The use of this selective functionalization technique means that the majority of the growing plasmodium remains unfunctionalized and living; thus, a true hybrid device is formed. It can be seen how a range of functionalized polymers and materials whereby a chemical activator, for the formation of the product (or the pre-cursor) can be added to P. polycephalum (or other organisms) followed by reaction to form a hybrid material.

  11. Electronic structure modeling of InAs/GaSb superlattices with hybrid density functional theory

    Science.gov (United States)

    Garwood, T.; Modine, N. A.; Krishna, S.

    2017-03-01

    The application of first-principles calculations holds promise for greatly improving our understanding of semiconductor superlattices. Developing a procedure to accurately predict band gaps using hybrid density functional theory lays the groundwork for future studies investigating more nuanced properties of these structures. Our approach allows a priori prediction of the properties of SLS structures using only the band gaps of the constituent materials. Furthermore, it should enable direct investigation of the effects of interface structure, e.g., intermixing or ordering at the interface, on SLS properties. In this paper, we present band gap data for various InAs/GaSb type-II superlattice structures calculated using the generalized Kohn-Sham formulation of density functional theory. A PBE0-type hybrid functional was used, and the portion of the exact exchange was tuned to fit the band gaps of the binary compounds InAs and GaSb with the best agreement to bulk experimental values obtained with 18% of the exact exchange. The heterostructures considered in this study are 6 monolayer (ML) InAs/6 ML GaSb, 8 ML InAs/8 ML GaSb and 10 ML InAs/10 ML GaSb with deviations from the experimental band gaps ranging from 3% to 11%.

  12. Design and Production of Electronic Newspapers Platform%互联网电子报刊平台的设计与制作

    Institute of Scientific and Technical Information of China (English)

    王颖; 司占军

    2016-01-01

    采用方正飞腾和NpMaker两款软件将校内各部门各学院制作的报纸、期刊制作成电子报刊的形式,并发布到互联网电子报刊平台上,实现在线阅读。该设计先将收集到的不同格式的报刊进行处理得到文字稿和图像稿,然后用方正飞腾按照原版原式进行排版,之后再进行发排和部分发排,把部分发排得到的EPS格式文件转化为JPG格式,最后用NpMaker将报刊制作成电子报刊,这时候就可以将报刊发布到平台上,通过网页浏览器即可访问平台,在线阅读电子报刊,并且可以在本地电脑进行电子报刊平台的管理和维护。将各院刊物实现数字化,一站式网络在线阅读,不仅可以使受众面扩大,增进学院之间的了解交流,同时平台提供检索功能,可以在全部刊物间实现文章检索。%The newspaper and periodicals made by each department in the school are made into electronic newspapers and periodi⁃cals by Founder and NpMaker software, then posted to the electronic newspapers platform and achieved online reading. The design first collected the different format newspapers were processing draft scripts and images, and using Founder typesetting in accor⁃dance with the original type, after publishing and part of publishing, the conversion of part of the publishing of the EPS file format to JPG format, and finally the newspapers make into electronic newspapers by NpMaker, this time release to the platform, through a web browser can access platform, online reading electronic newspapers, and on the local computer for platform of electronic periodi⁃cals management and maintenance. The publication of the journal to achieve digital, a one-stop online reading, not only can make the audience to expand, enhance understanding between the exchange, while the platform to provide information retrieval func⁃tions, can be achieved in all publications search.

  13. Hybrid Orbital and Numerical Grid Representationfor Electronic Continuum Processes: Double Photoionization of Atomic Beryllium

    Energy Technology Data Exchange (ETDEWEB)

    Yip, Frank L; McCurdy, C. William; Rescigno, Thomas N

    2010-04-19

    A general approach for ab initio calculations of electronic continuum processes is described in which the many-electron wave function is expanded using a combination of orbitals at short range and the finite-element discrete variable representation(FEM-DVR) at larger distances. The orbital portion of the basis allows the efficient construction of many-electron configurations in which some of the electrons are bound, but because the orbitals are constructed from an underlying FEM-DVR grid, the calculation of two-electron integrals retains the efficiency of the primitive FEM-DVR approach. As an example, double photoionization of beryllium is treated in a calculation in which the 1s{sup 2} core is frozen. This approach extends the use of exterior complex scaling (ECS) successfully applied to helium and H{sub 2} to calculations with two active electrons on more complicated targets. Integrated, energy-differential and triply-differential cross sections are exhibited, and the results agree well with other theoretical investigations.

  14. An enhanced security solution for electronic medical records based on AES hybrid technique with SOAP/XML and SHA-1.

    Science.gov (United States)

    Kiah, M L Mat; Nabi, Mohamed S; Zaidan, B B; Zaidan, A A

    2013-10-01

    This study aims to provide security solutions for implementing electronic medical records (EMRs). E-Health organizations could utilize the proposed method and implement recommended solutions in medical/health systems. Majority of the required security features of EMRs were noted. The methods used were tested against each of these security features. In implementing the system, the combination that satisfied all of the security features of EMRs was selected. Secure implementation and management of EMRs facilitate the safeguarding of the confidentiality, integrity, and availability of e-health organization systems. Health practitioners, patients, and visitors can use the information system facilities safely and with confidence anytime and anywhere. After critically reviewing security and data transmission methods, a new hybrid method was proposed to be implemented on EMR systems. This method will enhance the robustness, security, and integration of EMR systems. The hybrid of simple object access protocol/extensible markup language (XML) with advanced encryption standard and secure hash algorithm version 1 has achieved the security requirements of an EMR system with the capability of integrating with other systems through the design of XML messages.

  15. Calculation of two-centre two-electron integrals over Slater-type orbitals revisited. I. Coulomb and hybrid integrals

    CERN Document Server

    Lesiuk, Michał

    2014-01-01

    In this paper, which constitutes the first part of the series, we consider calculation of two-centre Coulomb and hybrid integrals over Slater-type orbitals (STOs). General formulae for these integrals are derived with no restrictions on the values of the quantum numbers and nonlinear parameters. Direct integration over the coordinates of one of the electrons leaves us with the set of overlap-like integrals which are evaluated by using two distinct methods. The first one is based on the transformation to the ellipsoidal coordinates system and the second utilises a recursive scheme for consecutive increase of the angular momenta in the integrand. In both methods simple one-dimensional numerical integrations are used in order to avoid severe digital erosion connected with the straightforward use of the alternative analytical formulae. It is discussed that the numerical integration does not introduce a large computational overhead since the integrands are well-behaved functions, calculated recursively with decent...

  16. Femtosecond timing-jitter between photo-cathode laser and ultra-short electron bunches by means of hybrid compression

    Science.gov (United States)

    Pompili, R.; Anania, M. P.; Bellaveglia, M.; Biagioni, A.; Castorina, G.; Chiadroni, E.; Cianchi, A.; Croia, M.; Di Giovenale, D.; Ferrario, M.; Filippi, F.; Gallo, A.; Gatti, G.; Giorgianni, F.; Giribono, A.; Li, W.; Lupi, S.; Mostacci, A.; Petrarca, M.; Piersanti, L.; Di Pirro, G.; Romeo, S.; Scifo, J.; Shpakov, V.; Vaccarezza, C.; Villa, F.

    2016-08-01

    The generation of ultra-short electron bunches with ultra-low timing-jitter relative to the photo-cathode (PC) laser has been experimentally proved for the first time at the SPARC_LAB test-facility (INFN-LNF, Frascati) exploiting a two-stage hybrid compression scheme. The first stage employs RF-based compression (velocity-bunching), which shortens the bunch and imprints an energy chirp on it. The second stage is performed in a non-isochronous dogleg line, where the compression is completed resulting in a final bunch duration below 90 fs (rms). At the same time, the beam arrival timing-jitter with respect to the PC laser has been measured to be lower than 20 fs (rms). The reported results have been validated with numerical simulations.

  17. Femtosecond timing-jitter between photo-cathode laser and ultra-short electron bunches by means of hybrid compression

    CERN Document Server

    Pompili, Riccardo; Bellaveglia, M; Biagioni, A; Castorina, G; Chiadroni, E; Cianchi, A; Croia, M; Di Giovenale, D; Ferrario, M; Filippi, F; Gallo, A; Gatti, G; Giorgianni, F; Giribono, A; Li, W; Lupi, S; Mostacci, A; Petrarca, M; Piersanti, L; Di Pirro, G; Romeo, S; Scifo, J; Shpakov, V; Vaccarezza, C; Villa, F

    2017-01-01

    The generation of ultra-short electron bunches with ultra-low timing-jitter relative to the photo-cathode (PC) laser has been experimentally proved for the first time at the SPARC_LAB test-facility (INFN-LNF, Frascati) exploiting a two-stage hybrid compression scheme. The first stage employs RF-based compression (velocity-bunching), which shortens the bunch and imprints an energy chirp on it. The second stage is performed in a non-isochronous dogleg line, where the compression is completed resulting in a final bunch duration below 90 fs (rms). At the same time, the beam arrival timing-jitter with respect to the PC laser has been measured to be lower than 20 fs (rms). The reported results have been validated with numerical simulations.

  18. Multicentre clinical trials' data management: a hybrid solution to exploit the strengths of electronic data capture and electronic health records systems.

    Science.gov (United States)

    Fraccaro, Paolo; Dentone, Chiara; Fenoglio, Daniela; Giacomini, Mauro

    2013-12-01

    Clinical Trials (CTs) are indispensable instruments for evidence-based medicine and frequently necessitate the management, sharing and analysis of large amounts of data amongst partners in different locations. To effectively satisfy these requirements, the proposed solution combines a web platform and a Clinical Data Management System (CDMS) to exploit the strengths of Electronic Health Records (EHR) and Electronic Data Capture (EDC) systems. The core of the proposal is a relational database which has high data structuring characteristics and utilises biomedical controlled vocabularies (e.g. LOINC and ICD). In addition, units and normality ranges were collected for data comparison through the application of the Z-score transformation. The obtained CDMS preserves the EDC's flexibility and user autonomy and permits the creation of patient cohorts, as in the EHR. Accordingly, clinical information, after the initial recording, is available for different simultaneous multicentre CTs. Furthermore, interface runtime controls guarantee high data quality during data entering processes. Currently, the proposed system has been developed in the HIV and eye diseases fields in Italy. The proposed solution is flexible and suitable to perform multicentre research within a varying range of medical domains. In the future, the automatic importation of information from hospitals has been planned through an HL7 standard interface which would improve both data quantity and quality.

  19. Research Update: Relativistic origin of slow electron-hole recombination in hybrid halide perovskite solar cells

    Science.gov (United States)

    Azarhoosh, Pooya; McKechnie, Scott; Frost, Jarvist M.; Walsh, Aron; van Schilfgaarde, Mark

    2016-09-01

    The hybrid perovskite CH3NH3PbI3 (MAPI) exhibits long minority-carrier lifetimes and diffusion lengths. We show that slow recombination originates from a spin-split indirect-gap. Large internal electric fields act on spin-orbit-coupled band extrema, shifting band-edges to inequivalent wavevectors, making the fundamental gap indirect. From a description of photoluminescence within the quasiparticle self-consistent GW approximation for MAPI, CdTe, and GaAs, we predict carrier lifetime as a function of light intensity and temperature. At operating conditions we find radiative recombination in MAPI is reduced by a factor of more than 350 compared to direct gap behavior. The indirect gap is retained with dynamic disorder.

  20. Research Update: Relativistic origin of slow electron-hole recombination in hybrid halide perovskite solar cells

    Directory of Open Access Journals (Sweden)

    Pooya Azarhoosh

    2016-09-01

    Full Text Available The hybrid perovskite CH3NH3PbI3 (MAPI exhibits long minority-carrier lifetimes and diffusion lengths. We show that slow recombination originates from a spin-split indirect-gap. Large internal electric fields act on spin-orbit-coupled band extrema, shifting band-edges to inequivalent wavevectors, making the fundamental gap indirect. From a description of photoluminescence within the quasiparticle self-consistent GW approximation for MAPI, CdTe, and GaAs, we predict carrier lifetime as a function of light intensity and temperature. At operating conditions we find radiative recombination in MAPI is reduced by a factor of more than 350 compared to direct gap behavior. The indirect gap is retained with dynamic disorder.

  1. Engineered hybrid cardiac patches with multifunctional electronics for online monitoring and regulation of tissue function

    Science.gov (United States)

    Feiner, Ron; Engel, Leeya; Fleischer, Sharon; Malki, Maayan; Gal, Idan; Shapira, Assaf; Shacham-Diamand, Yosi; Dvir, Tal

    2016-01-01

    In cardiac tissue engineering approaches to treat myocardial infarction, cardiac cells are seeded within three-dimensional porous scaffolds to create functional cardiac patches. However, current cardiac patches do not allow for online monitoring and reporting of engineered-tissue performance, and do not interfere to deliver signals for patch activation or to enable its integration with the host. Here, we report an engineered cardiac patch that integrates cardiac cells with flexible, free-standing electronics and a 3D nanocomposite scaffold. The patch exhibited robust electronic properties, enabling the recording of cellular electrical activities and the on-demand provision of electrical stimulation for synchronizing cell contraction. We also show that electroactive polymers containing biological factors can be deposited on designated electrodes to release drugs in the patch microenvironment on-demand. We expect that the integration of complex electronics within cardiac patches will eventually provide therapeutic control and regulation of cardiac function. PMID:26974408

  2. Increasing Completion Rate of an M4 Emergency Medicine Student End-of-Shift Evaluation Using a Mobile Electronic Platform and Real-Time Completion

    Directory of Open Access Journals (Sweden)

    Matthew C. Tews

    2016-06-01

    Full Text Available Introduction: Medical students on an emergency medicine rotation are traditionally evaluated at the end of each shift with paper-based forms, and data are often missing due to forms not being turned in or completed. Because students’ grades depend on these evaluations, change was needed to increase form rate of return. We analyzed a new electronic evaluation form and modified completion process to determine if it would increase the completion rate without altering how faculty scored student performance. Methods: During fall 2013, 29 faculty completed paper N=339 evaluations consisting of seven competencies for 33 students. In fall 2014, an electronic evaluation form with the same competencies was designed using an electronic platform and completed N=319 times by 27 faculty using 25 students’ electronic devices. Feedback checkboxes were added to facilitate collection of common comments. Data was analyzed with IBM® SPSS® 21.0 using multi-factor analysis of variance with the students’ global rating (GR as an outcome. Inter-item reliability was determined with Cronbach alpha. Results: There was a significantly higher completion rate (p=0.001 of 98% electronic vs. 69% paper forms, lower (p=0.001 missed GR rate (1% electronic. vs 12% paper, and higher mean scores (p=0.001 for the GR with the electronic (7.0±1.1 vs. paper (6.8±1.2 form. Feedback checkboxes were completed on every form. The inter-item reliability for electronic and paper forms was each alpha=0.95. Conclusion: The use of a new electronic form and modified completion process for evaluating students at the end of shift demonstrated a higher faculty completion rate, a lower missed data rate, a higher global rating and consistent collection of common feedback. The use of the electronic form and the process for obtaining the information made our end-of-shift evaluation process for students more reliable and provided more accurate, up-to-date information for student feedback and when

  3. Graphene/MoS2 hybrid technology for large-scale two-dimensional electronics.

    Science.gov (United States)

    Yu, Lili; Lee, Yi-Hsien; Ling, Xi; Santos, Elton J G; Shin, Yong Cheol; Lin, Yuxuan; Dubey, Madan; Kaxiras, Efthimios; Kong, Jing; Wang, Han; Palacios, Tomás

    2014-06-11

    Two-dimensional (2D) materials have generated great interest in the past few years as a new toolbox for electronics. This family of materials includes, among others, metallic graphene, semiconducting transition metal dichalcogenides (such as MoS2), and insulating boron nitride. These materials and their heterostructures offer excellent mechanical flexibility, optical transparency, and favorable transport properties for realizing electronic, sensing, and optical systems on arbitrary surfaces. In this paper, we demonstrate a novel technology for constructing large-scale electronic systems based on graphene/molybdenum disulfide (MoS2) heterostructures grown by chemical vapor deposition. We have fabricated high-performance devices and circuits based on this heterostructure, where MoS2 is used as the transistor channel and graphene as contact electrodes and circuit interconnects. We provide a systematic comparison of the graphene/MoS2 heterojunction contact to more traditional MoS2-metal junctions, as well as a theoretical investigation, using density functional theory, of the origin of the Schottky barrier height. The tunability of the graphene work function with electrostatic doping significantly improves the ohmic contact to MoS2. These high-performance large-scale devices and circuits based on this 2D heterostructure pave the way for practical flexible transparent electronics.

  4. Interface Engineering for Organic Electronics; Manufacturing of Hybrid Inorganic-Organic Molecular Crystal Devices

    NARCIS (Netherlands)

    de Veen, P.J.

    2011-01-01

    Organic semiconductors are at the basis of Organic Electronics. Objective of this dissertation is “to fabricate high-quality organic molecular single-crystal devices”, to explore the intrinsic properties of organic semiconductors. To achieve this, the in situ fabrication of complete field-effect

  5. Flow Regime Transition in Inner Grooved Minichannel Cold Plates for Cooling Hybrid Electric Power Electronics

    Science.gov (United States)

    2013-01-01

    system to create a military base microgrid (1). There are several motivations for replacing the traditional internal combustion (IC) motors and...appropriate control electronics, several HEVs can form a microgrid with a robust source of utility power (1). This use of HEVs can reduce the need for

  6. Multiplex PCR, amplicon size and hybridization efficiency on the NanoChip electronic microarray

    DEFF Research Database (Denmark)

    Børsting, Claus; Sanchez, Juan J; Morling, Niels

    2004-01-01

    We tested the SNP typing protocol developed for the NanoChip electronic microarray by analyzing the four Y chromosome loci SRY1532, SRY8299, TAT, and 92R7. Amplicons of different lengths containing the same locus were purified and addressed to the NanoChip array and fluorescently labelled reporter...

  7. Hybrid dendrimer hydrogel/poly(lactic-co-glycolic acid) nanoparticle platform: an advanced vehicle for topical delivery of antiglaucoma drugs and a likely solution to improving compliance and adherence in glaucoma management.

    Science.gov (United States)

    Yang, Hu; Leffler, Christopher T

    2013-03-01

    Glaucoma therapy typically begins with topical medications, of which there are 4 major classes in common use in the United States: beta-adrenergic antagonists, alpha-agonists, carbonic anhydrase inhibitors, and prostaglandin analogs. Unfortunately, all 4 classes require at least daily dosing, and 3 of the 4 classes are approved to be administered 2 or 3 times daily. This need for frequent dosing with multiple medications makes compliance difficult. Longer-acting formulations and combinations that require less frequent administration might improve compliance and therefore medication effectiveness. Recently, we developed an ocular drug delivery system, a hybrid dendrimer hydrogel/poly(lactic-co-glycolic acid) nanoparticle platform for delivering glaucoma therapeutics topically. This platform is designed to deliver glaucoma drugs to the eye efficiently and release the drug in a slow fashion. Furthermore, this delivery platform is designed to be compatible with many of the glaucoma drugs that are currently approved for use. In this article, we review this new delivery system with in-depth discussion of its structural features, properties, and preclinical application in glaucoma treatment. In addition, future directions and translational efforts for marketing this technology are elaborated.

  8. 基于混合云的融合媒体实践教学平台设计%Design for Fusion Media Practice Teaching Platform Based on Hybrid Cloud

    Institute of Scientific and Technical Information of China (English)

    胡一梁; 江月明子

    2016-01-01

    This paper describes the business demand of hybrid cloud fusion media practice teaching platform, analyzes the basic composition and function of the platform, proposed the non functional design of the system business requirements, and media cloud platform for seamless integration, realize an end-to -end fusion media teaching service, in the integration of the media practice teaching activities, cloud, IP and other aspects has carried on the significant exploration and the practice.%描述了基于混合云的融合媒体实践教学平台需求,分析了平台的基本组成与功能,提出了系统非功能业务设计要求,与融合媒体云平台无缝对接,实现了端到端的融合媒体教学业务服务,并在融合媒体实践教学活动云化、IP化等方面进行了有意义的探索与实践。

  9. Control electronic platform based on floating-point DSP and FPGA for a NPC multilevel back-to-back converter

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, Francisco J.; Cobreces, Santiago; Bueno, Emilio J.; Hernandez, Alvaro; Mateos, Raul; Espinosa, Felipe [Department of Electronics, University of Alcala, Alcala de Henares, Madrid (Spain)

    2008-09-15

    Modern energy concepts as Distributed Power Generation are changing the appearance of electric distribution and transmission and challenging power electronics researchers, which try to develop new solutions of electronic controllers. The aim is to enable the implementation of new and more complex control algorithms to verify the last standards related to the grid energy quality for new power converters, and, also, for equipments which nowadays are operating. This paper presents the design, implementation and test of a novel real-time controller for a Neutral Point Clamped (NPC) (three-level) multilevel converter based on a floating-point Digital Signal Processor (DSP) and on a Field-Programmable Gate Array (FPGA), by operating in a cooperative way. Although the proposed system can be readily applied to any power electronic application, in this work, it is focused on the next system: a 150 kVA back-to-back three-level NPC Voltage Source Converter (VSC) for wind power applications. (author)

  10. Design of a novel damping mechanism for the opto-electronic platform%光电平台新型隔振机构设计

    Institute of Scientific and Technical Information of China (English)

    刘树峰; 白鸿柏; 李冬伟; 李玉龙; 高山

    2012-01-01

    振动会严重影响动载体光电平台的成像质量和跟踪精度,必须采取隔振措施.分析了振动对光电平台成像质量的影响,提出了一种新型隔振机构设计方案,设计了两种新型金属橡胶隔振器,应用线阵CCD二维动态测角仪对光电平台的动态角位移进行了测量.光电平台振动扫频试验结果显示,内外隔振器组合的隔振机构能够衰减3个正交方向20 Hz以上的振动.测角结果显示,平台最大角位移为5.5″,小于8″的设计要求.隔振机构不但有效隔离了中高频振动,而且实现了平台无角位移运动,为动载体光电平台的研究提供了理论支持,并具有重要军事意义.%Vibration can influence the imaging quality and tracking precision of the moving opto-electronic platform seriously, measures of reducing vibration must be taken into consideration.The influence that vibration works on the imaging quality is analyzed, a novel design scheme of the damping mechanism is proposed, two new types Metal Rubber Damper (MRD) are designed, and linear CCD two dimensional dynamic angle goniometer is applied to measure the dynamic rotational displacement of the opto-electronic platform. The result of sweeping experiment shows that the damping mechanism consisting of inner and outer vibration absorbers can reduce the vibration in three orthogonal directions, which is higher than 20 Hz. The angle-measurement result presents that themaximum rotational displacement is 5. 5", which is less than the design demand 8". The damping mechanism not only isolates the Medium-High Frequency (MHF) vibration effectively, but also realizes the irrotational displacement movement, the research offers an theoretic support for the researches of moving opto-electronic platform and has important military significance.

  11. In-situ spectroscopy and nanoscale electronics in superconductor-topological insulator hybrid devices: a combined thin film growth and quantum transport study

    NARCIS (Netherlands)

    Ngabonziza, Prosper

    2016-01-01

    In this dissertation, we presented a combined thin film growth and quantum transport study on superconductor topological insulator hybrid devices. Understanding of the electronic properties of topological insulators (TIs), their preparation in high quality thin film form and their interaction with o

  12. Electron hybridization and anharmonic thermal vibration effect on structure transition of SrTiO3 at high-pressure and low-temperature

    Science.gov (United States)

    Yamanaka, Takamitsu; Ahart, Muhtar; Mao, Ho-kwang; Suzuki, Takeyuki

    2017-01-01

    We execute electron density analysis of SrTiO3 at low temperatures up 80 K and high pressures up to 11.88 GPa using X-ray single-crystal diffraction and ab initio quantum chemical molecular orbital (MO) calculation. By changing pressures, the cubic SrTiO3 with perovskite structure goes through a antiferroelastic distortion to tetragonal symmetry above the critical pressure Pc=7 GPa with c/a1 and increasing with lowering temperature. Difference Fourier (D-F) synthesis experimentally proves the residual electron densities Δρ(xyz) are associated with two different effects: electron hybridization bonding electron and anharmonic thermal vibration atoms. The d-p-π hybridization between Ti(3d) and O(2p) orbitals is confirmed in the residual electron density, which is deformed from the ideal spherical density conducted by the atomic scattering factor fi using Hartree-Fock (HF) approximation. MO calculation also reveals the electron hybridization. Anharmonic thermal vibration of atoms yields a large effect to the structure transition. Mulliken charges analysis of MO calculation indicates much smaller charges than their formal ionic charges. Their ionicity increases from cubic to tetragonal above Pc and below Tc.

  13. Final Technical Report - 300°C Capable Electronics Platform and Temperature Sensor System For Enhanced Geothermal Systems

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Cheng-Po; Shaddock, David; Sandvik, Peter; Saia, Rich; Amita Patil, Alexey Vert; Zhang, Tan

    2012-11-30

    A silicon carbide (SiC) based electronic temperature sensor prototype has been demonstrated to operate at 300°C. We showed continuous operation of 1,000 hours with SiC operational amplifier and surface mounted discreet resistors and capacitors on a ceramic circuit board. This feasibility demonstration is a major milestone in the development of high temperature electronics in general and high temperature geothermal exploration and well management tools in particular. SiC technology offers technical advantages that are not found in competing technologies such as silicon-on-insulator (SOI) at high temperatures of 200°C to 300°C and beyond. The SiC integrated circuits and packaging methods can be used in new product introduction by GE Oil and Gas for high temperature down-hole tools. The existing SiC fabrication facility at GE is sufficient to support the quantities currently demanded by the marketplace, and there are other entities in the United States and other countries capable of ramping up SiC technology manufacturing. The ceramic circuit boards are different from traditional organic-based electronics circuit boards, but the fabrication process is compatible with existing ceramic substrate manufacturing. This project has brought high temperature electronics forward, and brings us closer to commercializing tools that will enable and reduce the cost of enhanced geothermal technology to benefit the public in terms of providing clean renewable energy at lower costs.

  14. Final Technical Report - 300°C Capable Electronics Platform and Temperature Sensor System For Enhanced Geothermal Systems

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Cheng-Po; Shaddock, David; Sandvik, Peter; Saia, Rich; Amita Patil, Alexey Vert; Zhang, Tan

    2012-11-30

    A silicon carbide (SiC) based electronic temperature sensor prototype has been demonstrated to operate at 300°C. We showed continuous operation of 1,000 hours with SiC operational amplifier and surface mounted discreet resistors and capacitors on a ceramic circuit board. This feasibility demonstration is a major milestone in the development of high temperature electronics in general and high temperature geothermal exploration and well management tools in particular. SiC technology offers technical advantages that are not found in competing technologies such as silicon-on-insulator (SOI) at high temperatures of 200°C to 300°C and beyond. The SiC integrated circuits and packaging methods can be used in new product introduction by GE Oil and Gas for high temperature down-hole tools. The existing SiC fabrication facility at GE is sufficient to support the quantities currently demanded by the marketplace, and there are other entities in the United States and other countries capable of ramping up SiC technology manufacturing. The ceramic circuit boards are different from traditional organic-based electronics circuit boards, but the fabrication process is compatible with existing ceramic substrate manufacturing. This project has brought high temperature electronics forward, and brings us closer to commercializing tools that will enable and reduce the cost of enhanced geothermal technology to benefit the public in terms of providing clean renewable energy at lower costs.

  15. Microstructure, chemistry, and electronic structure of natural hybrid composites in abalone shell.

    Science.gov (United States)

    Srot, Vesna; Wegst, Ulrike G K; Salzberger, Ute; Koch, Christoph T; Hahn, Kersten; Kopold, Peter; van Aken, Peter A

    2013-05-01

    The crystal structure and chemical composition at the inorganic/inorganic and inorganic/organic interfaces in abalone shell (genus Haliotis) were investigated using advanced analytical transmission electron microscopy (TEM) methods. Electron energy-loss near-edge structures (ELNES) of Ca-M2,3, C-K, Ca-L2,3, O-K and low-loss EEL spectra acquired from aragonite and calcite are distinctly different. When comparing biogenic with inorganic material for aragonite, only minor differences in C-K fine structures could be detected. The crystal structure of the mineral bridges was confirmed by ELNES experiments. ELNES and energy-filtered TEM (EFTEM) experiments of regular and self-healed interfaces between nacreous aragonite and prismatic calcite reveal relatively rough transitions. In this work, the importance of TEM specimen preparation and specimen damage on structural features is discussed.

  16. Electronic and mechanical properties of hybrid graphene/h-BN nanoribbons

    Energy Technology Data Exchange (ETDEWEB)

    Pooja,, E-mail: j.poojaa1228@gmail.com; Sharma, Munish; Ahluwalia, P. K. [Physics Department, Himachal Pradesh University, Shimla-171005 (India); Kumar, Ashok [Physics Department, Panjab University, Chandigarh-160014 (India); Thakur, Anil [Physics Department, Govt. Collage Solan, Himachal Pradesh-173212 (India)

    2015-06-24

    The electronic and mechanical properties of one-dimensional super lattice which are composed of controlled domain size of graphene and h-BN nanoribbons with saturated and unsaturated edges are studied by means of the first-principles method. The results show that the studied zigzag- nanoribbons (Z-GBNNR) with unsaturated edges are half-metallic, while they transform into non-magnetic semiconductor on hydrogen passivations. On the other hand the band-gap of armchair-edges nanoribbons (A-GBNNR) get enhanced by the edges saturation. Furthermore, unsaturated edges A-GBNNR and saturated edges Z-GBNNR are found mechanically more stable. These results provide a fingerprint for their use in spintronics and electronics devices.

  17. Role of microstructure in the electron-hole interaction of hybrid lead halide perovskites

    Science.gov (United States)

    Grancini, Giulia; Srimath Kandada, Ajay Ram; Frost, Jarvist M.; Barker, Alex J.; de Bastiani, Michele; Gandini, Marina; Marras, Sergio; Lanzani, Guglielmo; Walsh, Aron; Petrozza, Annamaria

    2015-10-01

    Organic-inorganic metal halide perovskites have demonstrated high power conversion efficiencies in solar cells and promising performance in a wide range of optoelectronic devices. The existence and stability of bound electron-hole pairs in these materials and their role in the operation of devices with different architectures remains a controversial issue. Here we demonstrate, through a combination of optical spectroscopy and multiscale modelling as a function of the degree of polycrystallinity and temperature, that the electron-hole interaction is sensitive to the microstructure of the material. The long-range order is disrupted by polycrystalline disorder and the variations in electrostatic potential found for smaller crystals suppress exciton formation, while larger crystals of the same composition demonstrate an unambiguous excitonic state. We conclude that fabrication procedures and morphology strongly influence perovskite behaviour, with both free carrier and excitonic regimes possible, with strong implications for optoelectronic devices.

  18. Hybrid optical-electrochemical electronic nose system based on Zn-porphyrin and multi-walled carbon nanotube composite.

    Science.gov (United States)

    Kladsomboon, Sumana; Lutz, Mario; Pogfay, Tawee; Puntheeranurak, Theeraporn; Kerdcharoen, Teerakiat

    2012-07-01

    In this work, we have enhanced the capability of an e-nose system based on combined optical and electrochemical transduction within a single gas sensor array. The optical part of this e-nose is based on detection of the absorption changes of light emitted from eight light emitting diodes (LEDs) as measured by a CMOS photo-detector. The electrochemical part works by measuring the change in electrical resistivity of the sensing materials upon contact with the sample vapor. Zinc-5,10,15,20-tetra-phenyl-21H,23H-porphyrin (ZnTPP) and multi-walled carbon nanotube (MWCNT) composite was used as the sensing materials based on its good optoelectronic properties. This sensing layer was characterized by UV-Vis spectroscopy and atomic force microscope and tested with various VOC vapors. Density functional theory (DFT) calculations were performed to investigate the electronic properties and interaction energies between ZnTPP and analyte molecules. It can be clearly seen that this hybrid optical-electrochemical electronic nose system can classify the vapor of different volatile organic compounds.

  19. Electronic, structural, and thermodynamic properties of mixed actinide dioxides (U, Pu, Am) O2 from hybrid density functional theory

    Science.gov (United States)

    Ma, Li; Ray, Asok K.

    2010-03-01

    As a continuation of our studies of pure actinide metals using hybrid density functional theory,footnotetextR. Atta-Fynn and A. K. Ray, Europhysics Letters, 85, 27008-p1- p6 (2009); Chemical Physics Letters, 482, 223-227 (2009). we present here a systematic study of the electronic and geometric structure properties of mixed actinide dioxides, U0.5Pu0.5O2, U0.5Am0.5O2, Pu0.5Am0.5 O2 and U0.8Pu0.2O2. The fraction of exact Hartree-Fock exchange used was 40%. To investigate the effect of spin-orbit coupling on the ground state electronic and geometric structure properties, computations have been carried out at two theoretical levels, one at the scalar-relativistic level with no spin-orbit coupling and one at the fully relativistic level with spin-orbit coupling. Thermodynamic properties have been calculated by a coupling of first-principles calculation and lattice dynamics.

  20. Defects Energetics and Electronic Properties of Li Doped ZnO: A Hybrid Hartree-Fock and Density Functional Study

    Institute of Scientific and Technical Information of China (English)

    Xu Sun; You-song Gu; Xue-qiang Wang; Yue Zhang

    2012-01-01

    The electronic properties and stability of Li-doped ZnO with various defects have been studied by calculating the electronic structures and defect formation energies via first-principles calculations using hybrid Hartree-Fock and density functional methods.The results from formation energy calculations show that Li pair complexes have the lowest formation energy in most circumstances and they consume most of the Li content in Li doped ZnO,which make the p-type conductance hard to obtain.The formation of Li pair complexes is the main obstacle to realize p-type conductance in Li doped ZnO.However,the formation energy of Lizn decreases as environment changes from Zn-rich to O-rich and becomes more stable than that of Li-pair complexes at highly O-rich environment.Therefore,p-type conductance can be obtained by Li doped ZnO grown or post annealed in oxygen rich atmosphere.

  1. Spin-triplet electron transport in hybrid superconductor heterostructures with a composite ferromagnetic interlayer

    Energy Technology Data Exchange (ETDEWEB)

    Sheyerman, A. E., E-mail: karen@hitech.cplire.ru; Constantinian, K. Y.; Ovsyannikov, G. A.; Kislinskii, Yu. V.; Shadrin, A. V. [Russian Academy of Sciences, Kotelnikov Institute of Radio Engineering and Electronics (Russian Federation); Kalabukhov, A. V. [Chalmers University of Technology (Sweden); Khaydukov, Yu. N. [Max-Planck Institute for Solid State Research (Germany)

    2015-06-15

    Hybrid YBa{sub 2}Cu{sub 3}O{sub 7−x}/SrRuO{sub 3}/La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/Au-Nb superconductor mesastructures with a composite manganite-ruthenate ferromagnetic interlayer are studied using electrophysical, magnetic, and microwave methods. The supercurrent in the mesastructure is observed when the interlayer thickness is much larger than the coherence length of ferromagnetic materials. The peak on the dependence of the critical current density on the interlayer material thickness corresponds to the coherence length, which is in qualitative agreement with theoretical predictions for a system with spit-triplet superconducting correlations. The magnetic-field dependence of the critical current is determined by penetration of magnetic flux quanta and by the magnetic domain structure, as well as by the field dependence of disorientation of the magnetization vectors of the layers in the composite magnetic interlayer. It is found that the supercurrent exists in magnetic fields two orders of magnitude stronger than the field corresponding to entry of a magnetic flux quantum into the mesastructure. The current-phase relation (CPR) of the supercurrent of mesastructures is investigated upon a change in the magnetic field from zero to 30 Oe; the ratio of the second CPR harmonic to the first, determined from the dependence of the Shapiro steps on the microwave radiation amplitude, does not exceed 50%.

  2. A hybrid electronic tongue for direct classification of baby liquid foods with or without gluten

    OpenAIRE

    Peres, António M.; Dias, L. G.; Veloso, Ana C. A.; Sousa, Mara E.B.C.; Machado, A.A.S.C.

    2011-01-01

    People suffering from celiac disease are gluten intolerant and inadvertent ingestion of gluten proteins must be avoided. Several techniques have been proposed to detect/quantify gluten proteins in foodstuffs: immunochemical methods, mass tandem spectrometry and polymerase chain reaction as well as gluten sensors [1]. Recently, a potentiometric electronic tongue (ET) with lipo/polymeric membranes has been used to detect gliadins, which are gluten proteins, in foodstuffs [2]. How...

  3. Realizing the Hybrid Library.

    Science.gov (United States)

    Pinfield, Stephen; Eaton, Jonathan; Edwards, Catherine; Russell, Rosemary; Wissenburg, Astrid; Wynne, Peter

    1998-01-01

    Outlines five projects currently funded by the United Kingdom's Electronic Libraries Program (eLib): HyLiFe (Hybrid Library of the Future), MALIBU (MAnaging the hybrid Library for the Benefit of Users), HeadLine (Hybrid Electronic Access and Delivery in the Library Networked Environment), ATHENS (authentication scheme), and BUILDER (Birmingham…

  4. Hybrid-PIC modeling of laser-plasma interactions and hot electron generation in gold hohlraum walls

    Science.gov (United States)

    Thoma, C.; Welch, D. R.; Clark, R. E.; Rose, D. V.; Golovkin, I. E.

    2017-06-01

    The walls of the hohlraum used in experiments at the national ignition facility are heated by laser beams with intensities ˜ 10 15 W/cm2, a wavelength of ˜ 1 / 3 μm, and pulse lengths on the order of a ns, with collisional absorption believed to be the primary heating mechanism. X-rays generated by the hot ablated plasma at the gold walls are then used to implode a target in the hohlraum interior. In addition to the collisional absorption of laser energy at the walls, non-linear laser-plasma interactions (LPI), such as stimulated Raman scattering and two plasmon decay, are believed to generate a population of supra-thermal electrons which, if present in the hohlraum, can have a deleterious effect on target implosion. We describe results of hohlraum modeling using a hybrid particle-in-cell code. To enable this work, new particle-based algorithms for a multiple-ion magneto-hydrodynamic (MHD) treatment, and a particle-based ray-tracing model were developed. The use of such hybrid methods relaxes the requirement to resolve the laser wavelength, and allows for relatively large-scale hohlraum simulations with a reasonable number of cells. But the non-linear effects which are believed to be the cause of hot electron generation can only be captured by fully kinetic simulations with good resolution of the laser wavelength. For this reason, we employ a two-tiered approach to hohlraum modeling. Large-scale simulations of the collisional absorption process can be conducted using the fast quasi-neutral MHD algorithm with fluid particle species. From these simulations, we can observe the time evolution of the hohlraum walls and characterize the density and temperature profiles. From these results, we can transition to smaller-scale highly resolved simulations using traditional kinetic particle-in-cell methods, from which we can fully model all of the non-linear laser-plasma interactions, as well as assess the details of the electron distribution function. We find that vacuum

  5. {ital s} -{ital p} Hybridization and Electron Shell Structures in Aluminum Clusters: A Photoelectron Spectroscopy Study

    Energy Technology Data Exchange (ETDEWEB)

    Li, X.; Wu, H.; Wang, X.; Wang, L. [Department of Physics, Washington State University, 2710 University Drive, Richland, Washington 99352-1671 (United States)]|[W. R. Wiley Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, MS K8-88, P.O. Box 999, Richland, Washington 99352 (United States)

    1998-08-01

    Using photoelectron spectroscopy of size-selected Al{sub x}{sup {minus}} (x=1{endash}162) clusters, we studied the electronic structure evolution of Al{sub x} and observed that the Al 3s - and 3p -derived bands evolve and broaden with cluster size and begin to overlap at Al{sub 9} . Direct spectroscopic signatures were obtained for electron shell structures with spherical shell closings at Al{sub 11}{sup {minus}} , Al{sub 13}{sup {minus}} , Al{sub 19}{sup {minus}} , Al{sub 23}{sup {minus}} , Al{sub 35}{sup {minus}} , Al{sub 37}{sup {minus}} , Al{sub 46} , Al{sub 52} , Al{sub 55}{sup {minus}} , Al{sub 56} , Al{sub 66} , and Al{sub 73}{sup {minus}} . The electron shell effect diminishes above Al{sub 75} and new spectral features appearing in Al{sub x}{sup {minus}} (x{gt}100) suggest a possible geometrical packing effect in large clusters. {copyright} {ital 1998} {ital The American Physical Society}

  6. Platform Constellations

    DEFF Research Database (Denmark)

    Staykova, Kalina Stefanova; Damsgaard, Jan

    2016-01-01

    This research paper presents an initial attempt to introduce and explain the emergence of new phenomenon, which we refer to as platform constellations. Functioning as highly modular systems, the platform constellations are collections of highly connected platforms which co-exist in parallel...... and as such allow us to study platforms not only as separate entities, but also to investigate the relationship between several platforms offered and governed by one and the same platform provider. By investigating two case studies of indigenous platform constellations formed around the hugely popular instant...... messaging apps KakaoTalk and LINE, we are able to gain valuable insights about the nature of these new constructions and to capture and synthesize their main characteristics in a framework. Our results show that platform constellations possess unique innovative capabilities, which can improve users...

  7. Portraits of colloidal hybrid nanostructures: controlled synthesis and potential applications.

    Science.gov (United States)

    Nguyen, Thanh-Dinh

    2013-03-01

    Inorganic hybrid nanostructures containing two or more nanocomponents have been emerging in many areas of materials science in recent years. The particle-particle interactions in a hybrid particle system could significantly improve existing local electronic structure and induce tunable physiochemical responses. The current work reviews the diverse inorganic hybrid nanostructures formed by adhesion of the different single components via seed-mediated method. The hybrid nanomaterials have great potentials for real applications in many other fields. The nanohybrids have been used as efficient heterocatalysts for carbon monoxide conversion and photodegradation of organic contaminants. The enhanced catalytic activity of these hybrid nanocatalysts could be attributed the formation of oxygen vacancies and electron transfer across the structural junction in a hybrid system as a result of the interfacial particle-particle interactions. The synergistic combination of up-converting and semiconducting properties in an up-converting semiconducting hybrid particle results in appearance of sub-band-gap photoconductivity. This behavior has a great significance for the design of photovoltaic devices for effective solar energy conversion. The functionalization and subsequent bioconjugation of the hybrid nanostructures to afford the multifunctional nanomedical platforms for simultaneous diagnosis and therapy are reviewed. The conjugated multifunctional hybrid nanostructures exhibit high biocompatibility and highly selective binding with functional groups-fabricated alive organs through delivering them to the tumor sites. The clever combinations of multifunctional features and antibody conjugation within these vehicles make them to generally offer new opportunities for clinical diagnostics and therapeutics.

  8. Photon counting performance measurements of transfer electron InGaAsP photocathode hybrid photomultiplier tubes at 1064 nm wavelength

    Science.gov (United States)

    Sun, Xiaoli; Krainak, Michael A.; Hasselbrack, William B.; La Rue, Ross A.

    2007-05-01

    We report the test results of a hybrid photomultiplier tube (HPMT) with a transfer electron (TE) InGaAsP photocathode and GaAs Schottky avalanche photodiode (APD) anode. Unlike Geiger mode InGaAsP APDs, these HPMTs (also known as intensified photodiode (IPD), vacuum APD, or hybrid photodetector) operate in linear mode without the need for quenching and gating. Their greatest advantages are wide dynamic range, high speed, large photosensitive area, and potential for photon counting and analog detection dual mode operation. The photon detection efficiency we measured was 25% at 1064 nm wavelength with a dark count rate of 60,000/s at -22 degrees Celsius. The output pulse width in response to a single photon detection is about 0.9 ns. The maximum count rate was 90 Mcts/s and was limited solely by the speed of the discriminator used in the measurement (10 ns dead time). The spectral response of these devices extended from 900 to 1300 nm. We also measured the HPMT response to 60 ps laser pulses. The average output pulse amplitude increased monotonically with the input pulse energy, which suggested that we can resolve photon number in an incident pulse. The jitter of the HPMT output was found to be about 0.5 ns standard deviation and depended on bias voltage applied to the TE photocathode. To our knowledge, these HPMTs are the most sensitive non gating photon detectors at 1064 nm wavelength, and they will have many applications in laser altimeters, atmospheric lidars, and free space laser communication systems.

  9. Incorporation of the electron energy equation into the hybrid Monte Carlo - fluid model for glow discharge: the applicability and reliability of the model

    Science.gov (United States)

    Eylenceoglu, Ender; Rafatov, Ismail; Kudryavtsev, Anatoly

    2016-09-01

    A modification of the conventional hybrid Monte Carlo - fluid model for glow discharge, which incorporates the electron energy equation, is considered. In the proposed model electrons are separated into two groups, namely, high energetic fast and low energetic slow (bulk) electrons. Density profiles of ions, slow electrons, and meta-stable particles are determined from the solution of corresponding continuity equations. Fast electrons, which are responsible for ionization and excitation events in the discharge, are simulated by the Monte-Carlo method. The temperature profile for slow electrons is obtained from the solution of the energy balance equation. The transport (mobility and diffusion) coefficients as well as the reaction rates for slow electrons are determined as functions of the electron temperature. Test calculations are carried out for the direct current glow discharge in argon within two-dimensional geometry. Comparison of the computed results with those obtained from the conventional fluid and hybrid models and the experimental data is done, the applicability and reliability of the proposed model is studied in details.

  10. Flexible and Disposable Sensing Platforms Based on Newspaper.

    Science.gov (United States)

    Yang, MinHo; Jeong, Soon Woo; Chang, Sung Jin; Kim, Kyung Hoon; Jang, Minjeong; Kim, Chi Hyun; Bae, Nam Ho; Sim, Gap Seop; Kang, Taejoon; Lee, Seok Jae; Choi, Bong Gill; Lee, Kyoung G

    2016-12-28

    The flexible sensing platform is a key component for the development of smart portable devices targeting healthcare, environmental monitoring, point-of-care diagnostics, and personal electronics. Herein, we demonstrate a simple, scalable, and cost-effective strategy for fabrication of a sensing electrode based on a waste newspaper with conformal coating of parylene C (P-paper). Thin polymeric layers over cellulose fibers allow the P-paper to possess improved mechanical and chemical stability, which results in high-performance flexible sensing platforms for the detection of pathogenic E. coli O157:H7 based on DNA hybridization. Moreover, P-paper electrodes have the potential to serve as disposable, flexible sensing platforms for point-of-care testing biosensors.

  11. A hybrid approach to simulation of electron transfer in complex molecular systems

    Science.gov (United States)

    Kubař, Tomáš; Elstner, Marcus

    2013-01-01

    Electron transfer (ET) reactions in biomolecular systems represent an important class of processes at the interface of physics, chemistry and biology. The theoretical description of these reactions constitutes a huge challenge because extensive systems require a quantum-mechanical treatment and a broad range of time scales are involved. Thus, only small model systems may be investigated with the modern density functional theory techniques combined with non-adiabatic dynamics algorithms. On the other hand, model calculations based on Marcus's seminal theory describe the ET involving several assumptions that may not always be met. We review a multi-scale method that combines a non-adiabatic propagation scheme and a linear scaling quantum-chemical method with a molecular mechanics force field in such a way that an unbiased description of the dynamics of excess electron is achieved and the number of degrees of freedom is reduced effectively at the same time. ET reactions taking nanoseconds in systems with hundreds of quantum atoms can be simulated, bridging the gap between non-adiabatic ab initio simulations and model approaches such as the Marcus theory. A major recent application is hole transfer in DNA, which represents an archetypal ET reaction in a polarizable medium. Ongoing work focuses on hole transfer in proteins, peptides and organic semi-conductors. PMID:23883952

  12. Bionano donor-acceptor hybrids of porphyrin, ssDNA, and semiconductive single-wall carbon nanotubes for electron transfer via porphyrin excitation.

    Science.gov (United States)

    D'Souza, Francis; Das, Sushanta K; Zandler, Melvin E; Sandanayaka, Atula S D; Ito, Osamu

    2011-12-14

    Photoinduced electron transfer in self-assemblies of porphyrins ion-paired with ssDNA wrapped around single-wall carbon nanotubes (SWCNTs) has been reported. To accomplish the three-component hybrids, two kinds of diameter-sorted semiconducting SWCNT(n,m)s of different diameter ((n,m) = (6,5) and (7,6)) and free-base or zinc porphyrin bearing peripheral positive charges ((TMPyP(+))M (tetrakis(4-N-methylpyridyl)porphyrin); M = Zn and H(2)) serving as light-absorbing photoactive materials are utilized. The donor-acceptor hybrids are held by ion-pairing between the negatively charged phosphate groups of ssDNA on the surface of the SWCNT and the positively charged at the ring periphery porphyrin macrocycle. The newly assembled bionano donor-acceptor hybrids have been characterized by transmission electron microscopy (TEM) and spectroscopic methods. Photoinduced electron transfer from the excited singlet porphyrin to the SWCNTs directly and/or via ssDNA as an electron mediator has been established by performing systematic studies involving the steady-state and time-resolved emission as well as the transient absorption studies. Higher charge-separation efficiency has been successfully demonstrated by the selection of the appropriate semiconductive SWCNTs with the right band gap, in addition to the aid of ssDNA as the electron mediator. © 2011 American Chemical Society

  13. Low-temperature electronic transport in one-dimensional hybrid systems: Metal cluster embedded carbon nanotubes

    Science.gov (United States)

    Soldano, Caterina

    The investigation of the electronic and magnetotransport properties at low temperature in individual MWNT with embedded clusters are here presented. The majority of studies of transport in MWNT reported in literature has been carried out on arc-discharge grown tubes, generally considered "clean" and defect-free. In this project, individual MWNT grown in alumina template are used; these tubes are highly disordered compared for example to arc-discharge ones, conditions that dramatically will impact the charge transport. As-fabricated devices are in general highly resistive. A large decrease in the value of the device resistance can be achieved through a controlled and fast high-bias sweep method (HBT) across the sample. Scanning electron microscopy analysis shows that this method induces a metal (platinum) decoration of the MWNT surface as a consequence of the large amount of Joule heating developed during the sweep. Temperature dependence study (5wires. DFT calculations show that the enhancement in conductance can be explained in term of enhanced density of states around the Fermi energy due to presence of platinum on the wall. Magneto-transport measurements carried out up to a value of magnetic field up to |5|T show a clear dependence from the energy (i.e. applied bias). A nearly symmetric and monotonically increasing positive magneto-conductance is observed in the range of the applied field, confirming the presence of weak localization in the system. A small but distinct Rashba spin-orbit scattering effect in the magneto-conductance in the low-field regime (|B|<.5T) is found and attributed to the surface decoration. Electronic and magnetotransport measurements independently confirm the 1D nature of the transport in the system. "Zero-field" measurements were performed on magnetic cluster-embedded MWNT-based devices (FM-MWNT). Temperature dependence of the conductance reveals a Luttinger liquid type of behavior in the range of investigated temperatures but no

  14. 3D printed electromagnetic transmission and electronic structures fabricated on a single platform using advanced process integration techniques

    Science.gov (United States)

    Deffenbaugh, Paul Issac

    3D printing has garnered immense attention from many fields including in-office rapid prototyping of mechanical parts, outer-space satellite replication, garage functional firearm manufacture, and NASA rocket engine component fabrication. 3D printing allows increased design flexibility in the fabrication of electronics, microwave circuits and wireless antennas and has reached a level of maturity which allows functional parts to be printed. Much more work is necessary in order to perfect the processes of 3D printed electronics especially in the area of automation. Chapter 1 shows several finished prototypes of 3D printed electronics as well as newly developed techniques in fabrication. Little is known about the RF and microwave properties and applications of the standard materials which have been developed for 3D printing. Measurement of a wide variety of materials over a broad spectrum of frequencies up to 10 GHz using a variety of well-established measurement methods is performed throughout chapter 2. Several types of high frequency RF transmission lines are fabricated and valuable model-matched data is gathered and provided in chapter 3 for future designers' use. Of particular note is a fully 3D printed stripline which was automatically fabricated in one process on one machine. Some core advantages of 3D printing RF/microwave components include rapid manufacturing of complex, dimensionally sensitive circuits (such as antennas and filters which are often iteratively tuned) and the ability to create new devices that cannot be made using standard fabrication techniques. Chapter 4 describes an exemplary fully 3D printed curved inverted-F antenna.

  15. Hermetically sealable package for hybrid solid-state electronic devices and the like

    Science.gov (United States)

    Miller, Wilson N. (Inventor); Gray, Ormal E. (Inventor)

    1988-01-01

    A light-weight, inexpensively fabricated, hermetically sealable, repairable package for small electronic or electromechanical units, having multiple connections, is described. A molded ring frame of polyamide-imide plastic (Torlon) is attached along one edge to a base plate formed of a highly heat conducting material, such as aluminum or copper. Bores are placed through a base plate within the area of the edge surface of ring frame which result in an attachment of the ring frame to the base plate during molding. Electrical leads are molded into the ring frame. The leads are L-shaped gold-plated copper wires imbedded within widened portions of the side wall of the ring frame. Within the plastic ring frame wall the leads are bent (typically, though not necessarily at 90 deg) so that they project into the interior volume of the ring frame for connection to the solid state devices.

  16. Co-functionalized organic/inorganic hybrid ZnO nanorods as electron transporting layers for inverted organic solar cells

    Science.gov (United States)

    Ambade, Swapnil B.; Ambade, Rohan B.; Eom, Seung Hun; Baek, Myung-Jin; Bagde, Sushil S.; Mane, Rajaram S.; Lee, Soo-Hyoung

    2016-02-01

    In an unprecedented attempt, we present an interesting approach of coupling solution processed ZnO planar nanorods (NRs) by an organic small molecule (SM) with a strong electron withdrawing cyano moiety and the carboxylic group as binding sites by a facile co-functionalization approach. Direct functionalization by SMs (SM-ZnO NRs) leads to higher aggregation owing to the weaker solubility of SMs in solutions of ZnO NRs dispersed in chlorobenzene (CB). A prior addition of organic 2-(2-methoxyethoxy)acetic acid (MEA) over ZnO NRs not only inhibits aggregation of SMs over ZnO NRs, but also provides enough sites for the SM to strongly couple with the ZnO NRs to yield transparent SM-MEA-ZnO NRs hybrids that exhibited excellent capability as electron transporting layers (ETLs) in inverted organic solar cells (iOSCs) of P3HT:PC60BM bulk-heterojunction (BHJ) photoactive layers. A strongly coupled SM-MEA-ZnO NR hybrid reduces the series resistance by enhancing the interfacial area and tunes the energy level alignment at the interface between the (indium-doped tin oxide, ITO) cathode and BHJ photoactive layers. A significant enhancement in power conversion efficiency (PCE) was achieved for iOSCs comprising ETLs of SM-MEA-ZnO NRs (3.64%) advancing from 0.9% for pristine ZnO NRs, while the iOSCs of aggregated SM-ZnO NRs ETL exhibited a much lower PCE of 2.6%, thus demonstrating the potential of the co-functionalization approach. The superiority of the co-functionalized SM-MEA-ZnO NRs ETL is also evident from the highest PCE of 7.38% obtained for the iOSCs comprising BHJ of PTB7-Th:PC60BM compared with extremely poor 0.05% for non-functionalized ZnO NRs.In an unprecedented attempt, we present an interesting approach of coupling solution processed ZnO planar nanorods (NRs) by an organic small molecule (SM) with a strong electron withdrawing cyano moiety and the carboxylic group as binding sites by a facile co-functionalization approach. Direct functionalization by SMs (SM

  17. The electron-transfer based interaction between transition metal ions and photoluminescent graphene quantum dots (GQDs): a platform for metal ion sensing.

    Science.gov (United States)

    Huang, Hongduan; Liao, Lei; Xu, Xiao; Zou, Mingjian; Liu, Feng; Li, Na

    2013-12-15

    The electron-transfer based quenching effect of commonly encountered transition metal ions on the photoluminescence of grapheme quantum dots (GQDs) was for the first time investigated, and was found to be associated with electron configuration of the individual metal ion. Ethylene diamine tetraacetic acid (EDTA), the metal ion chelator, can competitively interact with metal ions to recover the quenched photoluminescence of GQDs. Basically, metal ions with empty or completely filled d orbits could not quench the photoluminescence of GQDs, but this quenching effect was observed for the metal ions with partly filled d orbits. Based on the quenching-recovering strategy, a simple optical metal sensing platform was established by taking Ni(2+) as an example. Using the nickel ion-specific chelating reagent, dimethylglyoxime (DMG), to replace EDTA, a detection limit of 4.1 μM was obtained in standard solution. This proposed strategy does not need further functionalization of GQDs, facilitating the application for simple, fast and cost-effective screening of metal ions.

  18. A Hybrid MCDM Model for Improving the Electronic Health Record to Better Serve Client Needs

    Directory of Open Access Journals (Sweden)

    James J. H. Liou

    2017-10-01

    Full Text Available Although the electronic health record (EHR is a promising innovation in the healthcare industry, the implementation of EHR has been relatively slow. A theoretical structure for the exploration and improvement of this usage of EHR is proposed. Incorporating the theoretical structure of TOE (technology-organization-environment, we apply the DEMATEL (decision-making trial and evaluation laboratory technique to illustrate the influence-matrix and to construct the INRM (influential network relationship map. Based on this DEMATEL influence matrix and the fundamental concepts of ANP (Analytic Hierarchy Process, we derive influential weights for the criteria. These influential weights are then combined with the modified VIKOR (VlseKriterijumska Optimizacija I Kompromisno Resenje method to find ways to understand and enhance the usage of EHR technology. The outcome demonstrates that our model can not only be used for implementation of EHR technology, but can also be applied to analyze the gaps in performance between the aspiration level and present performance values in individual criterion/dimension.

  19. Electronic Tongue Based on Nanostructured Hybrid Films of Gold Nanoparticles and Phthalocyanines for Milk Analysis

    Directory of Open Access Journals (Sweden)

    Luiza A. Mercante

    2015-01-01

    Full Text Available The use of gold nanoparticles combined with other organic and inorganic materials for designing nanostructured films has demonstrated their versatility for various applications, including optoelectronic devices and chemical sensors. In this study, we reported the synthesis and characterization of gold nanoparticles stabilized with poly(allylamine hydrochloride (Au@PAH NPs, as well as the capability of this material to form multilayer Layer-by-Layer (LbL nanostructured films with metal tetrasulfonated phthalocyanines (MTsPc. Film growth was monitored by UV-Vis absorption spectroscopy, atomic force microscopy (AFM, and Fourier transform infrared spectroscopy (FTIR. Once LbL films have been applied as active layers in chemical sensors, Au@PAH/MTsPc and PAH/MTsPc LbL films were used in an electronic tongue system for milk analysis regarding fat content. The capacitance data were treated using Principal Component Analysis (PCA, revealing the role played by the gold nanoparticles on the LbL films electrical properties, enabling this kind of system to be used for analyzing complex matrices such as milk without any prior pretreatment.

  20. Surface Electronic Structure of Hybrid Organo Lead Bromide Perovskite Single Crystals

    KAUST Repository

    Komesu, Takashi

    2016-08-24

    The electronic structure and band dispersion of methylammonium lead bromide, CH3NH3PbBr3, has been investigated through a combination of angle-resolved photoemission spectroscopy (ARPES) and inverse photoemission spectroscopy (IPES), as well as theoretical modeling based on density functional theory. The experimental band structures are consistent with the density functional calculations. The results demonstrate the presence of a dispersive valence band in MAPbBr3 that peaks at the M point of the surface Brillouin zone. The results also indicate that the surface termination of the CH3NH3PbBr3 is the methylammonium bromide (CH3NH3Br) layer. We find our results support models that predict a heavier hole effective mass in the region of -0.23 to -0.26 me, along the Γ (surface Brillouin center) to M point of the surface Brillouin zone. The surface appears to be n-type as a result of an excess of lead in the surface region. © 2016 American Chemical Society.

  1. Layer-by-layer assembled multilayer TiO(x) for efficient electron acceptor in polymer hybrid solar cells.

    Science.gov (United States)

    Kang, Hyunbum; Lee, Chanwoo; Yoon, Sung Cheol; Cho, Chul-Hee; Cho, Jinhan; Kim, Bumjoon J

    2010-11-16

    We demonstrate that TiO(x) nanocomposite films fabricated using electrostatic layer-by-layer (LbL) assembly improve the power conversion efficiency of photovoltaic cells compared to conventional TiO(x) films fabricated via the sol-gel process. For this study, titanium precursor/poly(allylamine hydrochloride) (PAH) multilayer films were first deposited onto indium tin oxide-coated glass to produce TiO(x) nanocomposites (TiO(x)NC). The specific effect of the LbL processed TiO(x) on photovoltaic performance was investigated using the planar bilayer TiO(x)NC and highly regioregular poly(3-hexylthiophene) (P3HT) solar cells, and the P3HT/LbL TiO(x)NC solar cells showed a dramatic increase in power efficiency, particularly in terms of the short current density and fill factor. The improved efficiency of this device is mainly due to the difference in the chemical composition of the LbL TiO(x)NC films, including the much higher Ti(3+)/Ti(4+) ratio and the highly reactive facets of crystals as demonstrated by XPS and XRD measurement, thus enhancing the electron transfer between electron donors and acceptors. In addition, the grazing incidence wide-angle X-ray scattering (GIWAXS) study revealed the presence of more highly oriented P3HT stacks parallel to the substrate on the LbL TiO(x)NC film compared to those on the sol-gel TiO(x) films, possibly influencing the hole mobility of P3HT and the energy transfer near and at the interface between the P3HT and TiO(x) layers. The results of this study demonstrate that this approach is a promising one for the design of hybrid solar cells with improved efficiency.

  2. Heterogeneous oligonucleotide-hybridization assay based on hot electron-induced electrochemiluminescence of a rhodamine label at oxide-coated aluminum and silicon electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Spehar-Deleze, Anna-Maria [Laboratory of Sensors, Actuators and Microsystems, Institute of Microtechnology, University of Neuchatel, Rue Jaquet-Droz 1, CH-2007 Neuchatel (Switzerland) and Laboratory of Inorganic and Analytical Chemistry, Helsinki University of Technology, Kemistintie 1, FIN-02015 HUT (Finland)]. E-mail: anna-maria.spehar@unine.ch; Suomi, Johanna [Laboratory of Inorganic and Analytical Chemistry, Helsinki University of Technology, Kemistintie 1, FIN-02015 HUT (Finland); Jiang Qinghong [Laboratory of Inorganic and Analytical Chemistry, Helsinki University of Technology, Kemistintie 1, FIN-02015 HUT (Finland); Rooij, Nico de [Laboratory of Sensors, Actuators and Microsystems, Institute of Microtechnology, University of Neuchatel, Rue Jaquet-Droz 1, CH-2007 Neuchatel (Switzerland); Koudelka-Hep, Milena [Laboratory of Sensors, Actuators and Microsystems, Institute of Microtechnology, University of Neuchatel, Rue Jaquet-Droz 1, CH-2007 Neuchatel (Switzerland); Kulmala, Sakari [Laboratory of Inorganic and Analytical Chemistry, Helsinki University of Technology, Kemistintie 1, FIN-02015 HUT (Finland)

    2006-07-28

    This paper describes a heterogeneous oligonucleotide-hybridization assay based on hot electron-induced electrochemiluminescence (HECL) of a rhodamine label. Thin oxide-film coated aluminum and silicon electrodes were modified with an aminosilane layer and derivatized with short, 15-mer oligonucleotides via diisothiocyanate coupling. Target oligonucleotides were conjugated with tetramethylrhodamine (TAMRA) dye at their amino modified 5' end and hybridization was detected using HECL of TAMRA. Preliminary results indicate sensitivity down to picomolar level and low nonspecific adsorption. The sensitivity was better on oxide-coated silicon compared to oxide-coated aluminum electrodes and two-base pair mismatched hybrids were successfully discriminated. The experimental results presented here might be useful for the design of disposable electrochemiluminescent DNA biosensors.

  3. The nature of electronic excitations at the metal-bioorganic interface illustrated on histidine-silver hybrids.

    Science.gov (United States)

    Sanader, Željka; Mitrić, Roland; Bonačić-Koutecký, Vlasta; Bellina, Bruno; Antoine, Rodolphe; Dugourd, Philippe

    2014-01-21

    We present a joint theoretical and experimental study of the structure selective optical properties of cationic and anionic histidine-silver complexes with Ag and Ag3 which were prepared in the gas phase using mass spectroscopy coupled to electrospray ion source. Our TDDFT calculations provide general insight into the nature of electronic excitations at the metal-bioorganic interface that involve π-π* excitation within bioorganic subunits, charge transfer between two subunits and intrametallic excitations. The binding of silver to histidine, one of the most important amino acids, induces red shift in the optical absorption of protonated histidine particularly for anionic species. The presence of the smallest metallic subunit Ag3 increases the intensity of low energy transitions of histidine illustrating a metal cluster-induced enhancement of absorption of biomolecules in hybrid systems. Comparison of calculated absorption spectra with experimental photofragmentation yield provides structural assignment of the measured spectroscopic patterns. Our findings may serve to establish silver-labeling as the tool for the detection of histidine or histidine-tagged proteins.

  4. New adders using hybrid circuit consisting of three-gate single-electron transistors (TG-SETs) and MOSFETs.

    Science.gov (United States)

    Yu, YunSeop; Choi, JungBum

    2007-11-01

    A half-adder (HA) and a full-adder (FA) using hybrid circuits combining three-gate single-electron transistors (TG-SETs) with metal-oxide-semiconductor field-effect-transistors (MOSFETs) are proposed. The proposed HA consists of three TG-SETs, two enhanced-mode NMOSFETs, and two depletion-mode NMOSFETs, and the proposed FA consists of eight TG-SETs, two enhanced-mode NMOSFETs, and two depletion-mode NMOSFETs. The complexities in the HA and the FA are 7 and 12, respectively, and the worst-case delays in the HA and the FA are 1.48 ns and 2.25 ns, respectively. Compared with the conventional CMOS FA with 0.35 microm technology, the proposed FA can be constructed with 0.43 of devices, and can operate with 3.5 of worst-case delay, 1/534 of average power consumption, and 1/152 of power-delay-product (PDP). The proposed HA and FA can be operated as a half-subtractor (HS) and a full-subtractor (FS) in the case when the levels of the control gates in the HA and the FA are fitly determined. The basic operations of the proposed HA and the proposed FA have been successfully confirmed through SPICE circuit simulation based on the physical device model of TG-SETs.

  5. Effects of nonmetal doping on electronic structures of NaNbO3 based on hybrid density functional calculation

    Science.gov (United States)

    Shi, Haifeng; Lan, Benyue; Zhang, Chengliang; Ye, Enjia; Nie, Yanguang; Bian, Baoan

    2016-10-01

    The influences of a series of anion doping on the electronic structures of sodium niobate (NaNbO3) have been systematically investigated by density functional theory (DFT) calculations with the hybrid B3LYP functional. As for B(C,P)-doped NaNbO3, the isolated B 2p (C 2p, P 3p) states were formed above the valence band maximum (VBM) of NaNbO3, which were too weak to mix with O 2p states and thus produced band gap narrowing. While the band gap of NaNbO3 was slightly narrowed after F doping. As for S-doped NaNbO3, the S 3p states mixed with O 2p states well and thus reduced the band gap energy. According to the calculation results, we tentatively put forward that S doping would be appropriate for single anion doping NaNbO3, while the B(C,P) elements would be suitable candidates for co-doping NaNbO3.

  6. Payment Platform

    DEFF Research Database (Denmark)

    Hjelholt, Morten; Damsgaard, Jan

    2012-01-01

    Payment transactions through the use of physical coins, bank notes or credit cards have for centuries been the standard formats of exchanging money. Recently online and mobile digital payment platforms has entered the stage as contenders to this position and possibly could penetrate societies...... thoroughly and substitute current payment standards in the decades to come. This paper portrays how digital payment platforms evolve in socio-technical niches and how various technological platforms aim for institutional attention in their attempt to challenge earlier platforms and standards. The paper...... applies a co-evolutionary multilevel perspective to model the interplay and processes between technology and society wherein digital payment platforms potentially will substitute other payment platforms just like the credit card negated the check. On this basis this paper formulate a multilevel conceptual...

  7. Adaptation of a web-based, open source electronic medical record system platform to support a large study of tuberculosis epidemiology

    Directory of Open Access Journals (Sweden)

    Fraser Hamish SF

    2012-11-01

    Full Text Available Abstract Background In 2006, we were funded by the US National Institutes of Health to implement a study of tuberculosis epidemiology in Peru. The study required a secure information system to manage data from a target goal of 16,000 subjects who needed to be followed for at least one year. With previous experience in the development and deployment of web-based medical record systems for TB treatment in Peru, we chose to use the OpenMRS open source electronic medical record system platform to develop the study information system. Supported by a core technical and management team and a large and growing worldwide community, OpenMRS is now being used in more than 40 developing countries. We adapted the OpenMRS platform to better support foreign languages. We added a new module to support double data entry, linkage to an existing laboratory information system, automatic upload of GPS data from handheld devices, and better security and auditing of data changes. We added new reports for study managers, and developed data extraction tools for research staff and statisticians. Further adaptation to handle direct entry of laboratory data occurred after the study was launched. Results Data collection in the OpenMRS system began in September 2009. By August 2011 a total of 9,256 participants had been enrolled, 102,274 forms and 13,829 laboratory results had been entered, and there were 208 users. The system is now entirely supported by the Peruvian study staff and programmers. Conclusions The information system served the study objectives well despite requiring some significant adaptations mid-stream. OpenMRS has more tools and capabilities than it did in 2008, and requires less adaptations for future projects. OpenMRS can be an effective research data system in resource poor environments, especially for organizations using or considering it for clinical care as well as research.

  8. Research on hybrid modeling method based on platform of Creo Parametric software%基于Creo Parametric软件平台的混合式建模方法研究

    Institute of Scientific and Technical Information of China (English)

    吴江奎; 史庆春

    2013-01-01

    Computer - aided industrial design has been more and more widely applied in the process of designing. In this paper, drawbacks of both parametric modeling and freestyle modeling; are pointed out by the result of a comparative study, and a solution of hybrid modeling method which is based on Creo Parametric software platform is proposed. The case of a hair dryer product model building process is to illustrate the workflow of hybrid modeling method, and the analysis of the model verifies the feasibility of this approach.%计算机辅助工业设计在设计流程中的应用越来越广泛.通过对参数化建模和自由式建模的对比研究,指出了这两种方法各自的弊端,提出基于Creo Parametric软件平台的混合式建模办法.以电吹风产品模型构建的案例来说明混合式建模方法的工作流程,并通过模型分析验证了这种方法的可行性.

  9. Characteristics of electron cyclotron resonance plasma formed by lower hybrid current drive grill antenna

    Indian Academy of Sciences (India)

    P K Sharma; S L Rao; K Mishra; R G Trivedi; D Bora

    2008-03-01

    A 3.7 GHz system, which is meant for LHCD experiments on ADITYA tokamak, is used for producing ECR discharge. The ECR discharge is produced by setting the appropriate resonance magnetic field of 0.13 T, with hydrogen at a fill pressure of about 5 × 10-5 Torr. The RF powe r, up to 10 kW (of which ∼ 50% is reflected back), with a typical pulse length of 50 ms, is injected into the vacuum chamber of the ADITYA tokamak by a LHCD grill antenna and is used for plasma formation. The average coupled RF power density (the RF power/a typical volume of the plasma) is estimated to be ∼ 5 kW/m3. When the ECR appears inside the tokamak chamber for the given pumping frequency ( = 3.7 GHz) a plasma with a density () ∼ 4 × 1016 m-3 and electron temperature ∼ 8 eV is produced. The density and temperature during the RF pulse are measured by sets of Langmuir probes, located toroidally, on either side of the antenna. signals are also monitored to detect ionization. An estimate of density and temperature based on simple theoretical calculation agrees well with our experimental measurements. The plasma produced by the above mechanism is further used to characterize the ECR-assisted low voltage Ohmic start-up discharges. During this part of the experiments, Ohmic plasma is formed using capacitor banks. The plasma loop voltage is gradually decreased, till the discharge ceases to form. The same is repeated in the presence of ECR-formed plasma (RF pre-ionization), formed 10 ms prior to the loop voltage. We have observed that (with LHCD-induced) ECR-assisted Ohmic start-up discharges is reliably and repeatedly obtained with reduced loop voltage requirement and breakdown time decreases substantially. The current ramp-up rates also decrease with reduced loop voltage operation. These studies established that ECR plasma formed with LHCD system exhibits similar characteristics as reported earlier by dedicated ECR systems. This experiment also addresses the issue of whether ECR plasma

  10. Use of the "Moodle" Platform to Promote an Ongoing Learning When Lecturing General Physics in the Physics, Mathematics and Electronic Engineering Programmes at the University of the Basque Country UPV/EHU

    Science.gov (United States)

    López, Gabriel A.; Sáenz, Jon; Leonardo, Aritz; Gurtubay, Idoia G.

    2016-01-01

    The "Moodle" platform has been used to put into practice an ongoing evaluation of the students' Physics learning process. The evaluation has been done on the frame of the course General Physics, which is lectured during the first year of the Physics, Mathematics and Electronic Engineering Programmes at the Faculty of Science and…

  11. Use of the "Moodle" Platform to Promote an Ongoing Learning When Lecturing General Physics in the Physics, Mathematics and Electronic Engineering Programmes at the University of the Basque Country UPV/EHU

    Science.gov (United States)

    López, Gabriel A.; Sáenz, Jon; Leonardo, Aritz; Gurtubay, Idoia G.

    2016-01-01

    The "Moodle" platform has been used to put into practice an ongoing evaluation of the students' Physics learning process. The evaluation has been done on the frame of the course General Physics, which is lectured during the first year of the Physics, Mathematics and Electronic Engineering Programmes at the Faculty of Science and…

  12. ELISA-PLA: A novel hybrid platform for the rapid, highly sensitive and specific quantification of proteins and post-translational modifications.

    Science.gov (United States)

    Tong, Qing-He; Tao, Tao; Xie, Li-Qi; Lu, Hao-Jie

    2016-06-15

    Detection of low-abundance proteins and their post-translational modifications (PTMs) remains a great challenge. A conventional enzyme-linked immunosorbent assay (ELISA) is not sensitive enough to detect low-abundance PTMs and suffers from nonspecific detection. Herein, a rapid, highly sensitive and specific platform integrating ELISA with a proximity ligation assay (PLA), termed ELISA-PLA, was developed. Using ELISA-PLA, the specificity was improved by the simultaneous and proximate recognition of targets through multiple probes, and the sensitivity was significantly improved by rolling circle amplification (RCA). For GFP, the limit of detection (LOD) was decreased by two orders of magnitude compared to that of ELISA. Using site-specific phospho-antibody and pan-specific phospho-antibody, ELISA-PLA was successfully applied to quantify the phosphorylation dynamics of ERK1/2 and the overall tyrosine phosphorylation level of ERK1/2, respectively. ELISA-PLA was also used to quantify the O-GlcNAcylation of AKT, c-Fos, CREB and STAT3, which is faster and more sensitive than the conventional immunoprecipitation and western blotting (IP-WB) method. As a result, the sample consumption of ELISA-PLA was reduced 40-fold compared to IP-WB. Therefore, ELISA-PLA could be a promising platform for the rapid, sensitive and specific detection of proteins and PTMs.

  13. Organic electronic materials: Recent advances in the dft description of the ground and excited states using tuned range-separated hybrid functionals

    KAUST Repository

    Körzdörfer, Thomas

    2014-11-18

    Density functional theory (DFT) and its time-dependent extension (TD-DFT) are powerful tools enabling the theoretical prediction of the ground- and excited-state properties of organic electronic materials with reasonable accuracy at affordable computational costs. Due to their excellent accuracy-to-numerical-costs ratio, semilocal and global hybrid functionals such as B3LYP have become the workhorse for geometry optimizations and the prediction of vibrational spectra in modern theoretical organic chemistry. Despite the overwhelming success of these out-of-the-box functionals for such applications, the computational treatment of electronic and structural properties that are of particular interest in organic electronic materials sometimes reveals severe and qualitative failures of such functionals. Important examples include the overestimation of conjugation, torsional barriers, and electronic coupling as well as the underestimation of bond-length alternations or excited-state energies in low-band-gap polymers.In this Account, we highlight how these failures can be traced back to the delocalization error inherent to semilocal and global hybrid functionals, which leads to the spurious delocalization of electron densities and an overestimation of conjugation. The delocalization error for systems and functionals of interest can be quantified by allowing for fractional occupation of the highest occupied molecular orbital. It can be minimized by using long-range corrected hybrid functionals and a nonempirical tuning procedure for the range-separation parameter.We then review the benefits and drawbacks of using tuned long-range corrected hybrid functionals for the description of the ground and excited states of π-conjugated systems. In particular, we show that this approach provides for robust and efficient means of characterizing the electronic couplings in organic mixed-valence systems, for the calculation of accurate torsional barriers at the polymer limit, and for the

  14. Synthesis, and crystal and electronic structure of sodium metal phosphate for use as a hybrid capacitor in non-aqueous electrolyte.

    Science.gov (United States)

    Sundaram, Manickam Minakshi; Watcharatharapong, Teeraphat; Chakraborty, Sudip; Ahuja, Rajeev; Duraisamy, Shanmughasundaram; Rao, Penki Tirupathi; Munichandraiah, Nookala

    2015-12-14

    Energy storage devices based on sodium have been considered as an alternative to traditional lithium based systems because of the natural abundance, cost effectiveness and low environmental impact of sodium. Their synthesis, and crystal and electronic properties have been discussed, because of the importance of electronic conductivity in supercapacitors for high rate applications. The density of states of a mixed sodium transition metal phosphate (maricite, NaMn(1/3)Co(1/3)Ni(1/3)PO4) has been determined with the ab initio generalized gradient approximation (GGA)+Hubbard term (U) method. The computed results for the mixed maricite are compared with the band gap of the parent NaFePO4 and the electrochemical experimental results are in good agreement. A mixed sodium transition metal phosphate served as an active electrode material for a hybrid supercapacitor. The hybrid device (maricite versus carbon) in a non-aqueous electrolyte shows redox peaks in the cyclic voltammograms and asymmetric profiles in the charge-discharge curves while exhibiting a specific capacitance of 40 F g(-1) and these processes are found to be quasi-reversible. After long term cycling, the device exhibits excellent capacity retention (95%) and coulombic efficiency (92%). The presence of carbon and the nanocomposite morphology, identified through X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) studies, ensures the high rate capability while offering possibilities to develop new cathode materials for sodium hybrid devices.

  15. Direct spectroscopic evidence of ultrafast electron transfer from a low band gap polymer to CdSe quantum dots in hybrid photovoltaic thin films.

    Science.gov (United States)

    Couderc, Elsa; Greaney, Matthew J; Brutchey, Richard L; Bradforth, Stephen E

    2013-12-11

    Ultrafast transient absorption spectroscopy is used to study charge transfer dynamics in hybrid films composed of the low band gap polymer PCPDTBT and CdSe quantum dots capped with tert-butylthiol ligands. By selectively exciting the polymer, a spectral signature for electrons on the quantum dots appears on ultrafast time scales (≲ 65 fs), which indicates ultrafast electron transfer. From this time scale, the coupling between the polymer chains and the quantum dots is estimated to be J ≳ 17 meV. The reduced quantum dot acceptors exhibit an unambiguous spectral bleach signature, whose amplitude allows for the first direct calculation of the absolute electron transfer yield in a hybrid solar cell (82 ± 5%). We also show that a limitation of the hybrid system is rapid and measurable geminate recombination due to the small separation of the initial charge pair. The fast recombination is consistent with the internal quantum efficiency of the corresponding solar cell. We therefore have identified and quantified a main loss mechanism in this type of third generation solar cell.

  16. FY1995 study of electronic coservice project which used Optical-Smart Hybrid Card; 1995 nendo hikari IC hybrid card wo mochiite katei kara ukeru gyosei denshika service project

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    As one of advanced multi media service, We can think about electoronization-network changing of the public coservice. that the official system provides. It can be expected to improve the life environment for a nation by the electronization. The purpose of this research is to clarify the off-line administration of an individual information and the issue on security. We constructed the experimental system using the Internet and Optical-IC hybrid card that an individual information is administrated. The system provides the following services. (1) On-stop moving service (2) Electronic certificate publishing service (3) Electronic ticket publishing service We have mounted client terminals at Fuchu city hall, Yokohama city hall, and Keio University, and made field experimentation. (NEDO)

  17. Kinetic Cascade in Solar-wind Turbulence: 3D3V Hybrid-kinetic Simulations with Electron Inertia

    Science.gov (United States)

    Cerri, Silvio Sergio; Servidio, Sergio; Califano, Francesco

    2017-09-01

    Understanding the nature of the turbulent fluctuations below the ion gyroradius in solar-wind (SW) turbulence is a great challenge. Recent studies have been mostly in favor of kinetic Alfvén wave (KAW)-type fluctuations, but other kinds of fluctuations with characteristics typical of magnetosonic, whistler, and ion-Bernstein modes could also play a role depending on the plasma parameters. Here, we investigate the properties of the subproton-scale cascade with high-resolution hybrid-kinetic simulations of freely decaying turbulence in 3D3V phase space, including electron inertia effects. Two proton plasma beta are explored: the “intermediate” β p = 1 and “low” β p = 0.2 regimes, both typically observed in the SW and corona. The magnetic energy spectum exhibits {k}\\perp -8/3 and {k}\\parallel -7/2 power laws at β p = 1, while they are slightly steeper at β p = 0.2. Nevertheless, both regimes develop a spectral anisotropy consistent with {k}\\parallel ∼ {k}\\perp 2/3 at {k}\\perp {ρ }p> 1 and pronounced small-scale intermittency. In this context, we find that the kinetic-scale cascade is dominated by KAW-like fluctuations at β p = 1, whereas the low-β case presents a more complex scenario suggesting the simultaneous presence of different types of fluctuations. In both regimes, however, a possible role of the ion-Bernstein-type fluctuations at the smallest scales cannot be excluded.

  18. Electronic structures and phonon free energies of LaCoO3 using hybrid-exchange density functional theory

    Science.gov (United States)

    Mukhopadhyay, S.; Finnis, M. W.; Harrison, N. M.

    2013-03-01

    Hybrid-exchange density functional theory has been used to model the electronic structure of LaCoO3. Based on a rhombohedral unit cell of R3¯c symmetry containing two Co atoms we find a mixed spin phase, comprising alternating low and high spin Co+3 ions, with a total energy at 0 K just 57 meV per formula unit above that of a nonmagnetic semiconducting ground state. In the mixed spin phase the high-spin Co+3 ions have spin moments of 3.1μB and the state is insulating with a band gap of 2.2 eV. Our calculations suggest that the effective on-site Coulomb repulsion energy Ueff on Co+3 ions is spin dependent. The Ueff on Co+3 ions is 7.1 eV and 8.5 eV for the nonmagnetic ground state and for the magnetic high spin state, respectively. For the mixed spin state, two different Ueff are estimated for two Co+3 ions in the unit cell having different spin states, 8.0 eV for the high-spin Co+3 ion and 7.0 eV for the low-spin Co+3 ion. An estimate of the harmonic phonon free energy suggests that this mixed spin phase would become the more stable phase as the temperature increases, which is consistent with experimental evidence. An alternative intermediate spin state is higher in energy at all temperatures.

  19. Electronic thermal sensor and Data Collection Platform technology: Part 5 in Thermal surveillance of active volcanoes using the Landsat-1 Data Collection System

    Science.gov (United States)

    Preble, Duane M.; Friedman, Jules D.; Frank, David

    1976-01-01

    Five Data Collection Platforms (DCP) were integrated electronically with thermall sensing systems, emplaced and operated in an analog mode at selected thermally significant volcanic and geothermal sites. The DCP's transmitted 3260 messages comprising 26,080 ambient, surface, and near-surface temperature records at an accuracy of ±1.15 °C for 1121 instrument days between November 14, 1972 and April 17, 1974. In harsh, windy, high-altitude volcanic environments the DCP functioned best with a small dipole antenna. Sixteen kg of alkaline batteries provided a viable power supply for the DCP systems, operated at a low-duty cycle, for 5 to 8 months. A proposed solar power supply system would lengthen the period of unattended operation of the system considerably. Special methods of data handling such as data storage via a proposed memory system would increase the significance of the twice-daily data reception enabling the DCP's to record full diurnal-temperature cycles at volcanic or geothermal sites. Refinements in the temperature-monitoring system designed and operated in experiment SR 251 included a backup system consisting of a multipoint temperature scanner, a servo mechanism and an analog-to-digital recorder. Improvements were made in temperature-probe design and in construction of corrosion-resistant seals by use of a hydrofluoric-acid-etching technique.

  20. Designing and Implementation of Fuzzy Case-based Reasoning System on Android Platform Using Electronic Discharge Summary of Patients with Chronic Kidney Diseases

    Science.gov (United States)

    Tahmasebian, Shahram; Langarizadeh, Mostafa; Ghazisaeidi, Marjan; Mahdavi-Mazdeh, Mitra

    2016-01-01

    Introduction: Case-based reasoning (CBR) systems are one of the effective methods to find the nearest solution to the current problems. These systems are used in various spheres as well as industry, business, and economy. The medical field is not an exception in this regard, and these systems are nowadays used in the various aspects of diagnosis and treatment. Methodology: In this study, the effective parameters were first extracted from the structured discharge summary prepared for patients with chronic kidney diseases based on data mining method. Then, through holding a meeting with experts in nephrology and using data mining methods, the weights of the parameters were extracted. Finally, fuzzy system has been employed in order to compare the similarities of current case and previous cases, and the system was implemented on the Android platform. Discussion: The data on electronic discharge records of patients with chronic kidney diseases were entered into the system. The measure of similarity was assessed using the algorithm provided in the system, and then compared with other known methods in CBR systems. Conclusion: Developing Clinical fuzzy CBR system used in Knowledge management framework for registering specific therapeutic methods, Knowledge sharing environment for experts in a specific domain and Powerful tools at the point of care. PMID:27708490

  1. The electronic structure of organic-inorganic hybrid compounds : (NH4)(2)CuCl4, (CH3NH3)(2)CuCl4 and (C2H5NH3)(2)CuCl4

    NARCIS (Netherlands)

    Zolfaghari, P.; de Wijs, G. A.; de Groot, R. A.

    2013-01-01

    Hybrid organic-inorganic compounds are an intriguing class of materials that have been experimentally studied over the past few years because of a potential broad range of applications. The electronic and magnetic properties of three organic-inorganic hybrid compounds with compositions (NH4)(2)CuCl4

  2. The electronic structure of organic-inorganic hybrid compounds : (NH4)(2)CuCl4, (CH3NH3)(2)CuCl4 and (C2H5NH3)(2)CuCl4

    NARCIS (Netherlands)

    Zolfaghari, P.; de Wijs, G. A.; de Groot, R. A.

    2013-01-01

    Hybrid organic-inorganic compounds are an intriguing class of materials that have been experimentally studied over the past few years because of a potential broad range of applications. The electronic and magnetic properties of three organic-inorganic hybrid compounds with compositions

  3. Electronic Attack Platform Placement Optimization

    Science.gov (United States)

    2014-09-01

    Processing in VBA ...............................................................33 2. Client-Server Using Two Different Excel Application...42 E. ENTER PE STRIKE ROUTE ......................................................................43 IV. MODEL ...FORMULATION AND SIMULATION RESULTS ..............................45 A. MODEL FORMULATION

  4. [Lens platform].

    Science.gov (United States)

    Łukaszewska-Smyk, Agnieszka; Kałuzny, Józef

    2010-01-01

    The lens platform defines lens structure and lens material. Evolution of lens comprises change in their shape, angulation of haptens and transition of three-piece lens into one-piece lens. The lens fall into two categories: rigid (PMMA) and soft (siliconic, acrylic, colameric). The main lens maaterials are polymers (hydrophilic and hydrophobic). The lens platform has an effect on biocompatibility, bioadhesion, stability of lens in capsule, degree of PCO evolution and sensitiveness to laser damages.

  5. Platform contents

    OpenAIRE

    Renault, Régis

    2014-01-01

    A monopoly platform hosts advertisers who compete on a market for horizontally differentiated products. These products may be either mass market products that appeal broadly to the entire consumer population or niche products that are tailored to the tastes of some particular group. Consumers search sequentially through ads incurring a surfing cost of moving to the next ad. They may click on an ad at some cost, which provides all relevant information and the opportunity to buy. The platform c...

  6. Facile fabrication of FeN nanoparticles/nitrogen-doped graphene core-shell hybrid and its use as a platform for NADH detection in human blood serum.

    Science.gov (United States)

    Balamurugan, Jayaraman; Thanh, Tran Duy; Kim, Nam Hoon; Lee, Joong Hee

    2016-09-15

    Herein, we present a novel strategy for the synthesis of an iron nitride nanoparticles-encapsulated nitrogen-doped graphene (FeN NPs/NG) core-shell hierarchical nanostructure to boost the electrochemical performance in a highly sensitive, selective, reproducible, and stable sensing platform for nicotinamide adenine dinucleotide (NADH). This core-shell hierarchical nanostructure provides an excellent conductive network for effective charge transfer and avoids the agglomeration and restacking of NG sheets, which provides better access to the electrode material for NADH oxidation. The FeN NPs/NG core-shell hierarchical nanostructure demonstrates direct and mediatorless responses to NADH oxidation at a low potential. This material displays a high sensitivity of 0.028μA/μMcm(2), a wide linear range from 0.4 to 718μM, and a detection limit of 25nM with a fast response time of less than 3s. The interferences from common interferents, such as glucose, uric acid, dopamine, and ascorbic acid, are negligible. The fabricated sensor was further tested for the determination of NADH in human blood serum. The resulting high sensitivity, excellent selectivity, outstanding stability, and good reproducibility make the proposed FeN NPs/NG core-shell hierarchical nanostructure as a promising candidate for biomedical applications. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. Structure of a Deep Space Telemetry Receiver Based on Hybrid Computing Platform%基于混合平台的深空通信遥测接收机架构设计

    Institute of Scientific and Technical Information of China (English)

    侯毅; 刘荣科; 葛帅; 赵岭

    2012-01-01

    This paper proposes a CCSDS (Consultative Committee for Space Data Systems)-conforming structural design of deep space telemetry receiver based on hybrid computing platform to improve the reconfigurability and expandability of current receivers. The design makes full use of features including low access latency of GPU (Graphic Processing Unit) on-chip memory, parallel processing characteristics of streaming multi-processors in GPU and flexible development under CUDA (Compute Unified Device Architecture) programming architecture, and achieves high-speed frame synchronization and channel decoding. FPGA (Field Programmable Gate Array) is also contained in the hybrid computing platform for demodulation processing and CPU (Central Processing Unit) is used for control of data streaming. Experimental results show that the proposed design provides a feasible and effective way to reconfigure among multiple code lengths and code rates of CCSDS-conforming LDPC (Low Density Parity Check) codes. Throughput of the receiver is at least lOMbit/s follwoing decoding.%针对目前深空通信遥测信号接收机硬件实现存在的重配置及扩展灵活性较差的问题,提出了一种符合CCSDS(空间数据系统咨询委员会)标准基于混合平台的接收机架构设计.本设计充分利用了GPU(图形处理器)平台片上存储资源的低访问延迟特性、流多处理器的高速并行处理特性以及CUDA(统一计算架构)软件开发的配置灵活性,对接收过程中的帧同步和信道译码进行了高速实现.同时采用FPGA(现场可编程门阵列)对接收数据进行解调处理,通过CPU(中央处理器)对接收机内部数据流传输进行控制,实现了可重配置的混合平台接收机架构.实验结果表明本接收机架构在采用CCSDS标准的LDPC(低密度奇偶校验)编码时能够灵活切换多种码长码率模式,译码后数据吞吐率能够达到10 Mbit/s以上.

  8. TiO2 nanotube array photoelectrocatalyst and Ni-Sb-SnO2 electrocatalyst bifacial electrodes: a new type of bifunctional hybrid platform for water treatment.

    Science.gov (United States)

    Yang, So Young; Choi, Wonyong; Park, Hyunwoong

    2015-01-28

    Bifunctional hybrid electrodes capable of generating various reactive oxygen species (ROS) over a wide range of potentials were developed by coupling electrocatalysts and photoelectrocatalysts. To achieve this, Ni-doped Sb-SnO2 (NSS) was deposited on one side of a titanium (Ti) foil while the other side was anodized to grow a TiO2 nanotube array (TNA) for electrochemical ozone generation and photoelectrochemical hydroxyl radical generation, respectively. Surface characterization indicated that NSS and TNA were formed and spatially separated yet electrically connected through the Ti substrate. While each catalyst possessed unique electrochemical properties, the coupling of both catalysts resulted in mixed electrochemical properties that drove electrocatalysis at high potentials and photoelectrocatalysis at low potentials. The performance of the NSS/TNA electrode for phenol decomposition was ∼3 times greater than that of single-layer catalysts and ∼1.5 times greater than the combined catalytic performances of the individual NSS and TNA catalysts. This synergistic effect was attributed partly to the simultaneous generation of hydroxyl radicals and ozone, followed by the production of other ROS. A mechanism for the generation of ROS was discussed.

  9. Effect of Rashba and Dresselhaus Spin-Orbit Couplings on Electron Spin Polarization in a Hybrid Magnetic-Electric Barrier Nanostructure

    Science.gov (United States)

    Yang, Shi-Peng; Lu, Mao-Wang; Huang, Xin-Hong; Tang, Qiang; Zhou, Yong-Long

    2017-04-01

    A theoretical study has been carried out on the spin-dependent electron transport in a hybrid magnetic-electric barrier nanostructure with both Rashba and Dresselhaus spin-orbit couplings, which can be experimentally realized by depositing a ferromagnetic strip and a Schottky metal strip on top of a semiconductor heterostructure. The spin-orbit coupling-dependent transmission coefficient, conductance, and spin polarization are calculated by solving the Schrödinger equation exactly with the help of the transfer-matrix method. We find that both the magnitude and sign of the electron spin polarization vary strongly with the spin-orbit coupling strength. Thus, the degree of electron spin polarization can be manipulated by properly adjusting the spin-orbit coupling strength, and such a nanosystem can be employed as a controllable spin filter for spintronics applications.

  10. Design Features of a Planar Hybrid/Permanent Magnet Strong Focusing Undulator for Free Electron Laser (FEL) And Synchrotron Radiation (SR) Applications

    Energy Technology Data Exchange (ETDEWEB)

    Tatchyn, Roman; /SLAC

    2011-09-09

    Insertion devices for Angstrom-wavelength Free Electron Laser (FEL) amplifiers driven by multi-GeV electron beams generally require distributed focusing substantially stronger than their own natural focusing fields. Over the last several years a wide variety of focusing schemes and configurations have been proposed for undulators of this class, ranging from conventional current-driven quadrupoles external to the undulator magnets to permanent magnet (PM) lattices inserted into the insertion device gap. In this paper we present design studies of a flexible high-field hybrid/PM undulator with strong superimposed planar PM focusing proposed for a 1.5 Angstrom Linac Coherent Light Source (LCLS) driven by an electron beam with a 1 mm-mr normalized emittance. Attainable field parameters, tuning modes, and potential applications of the proposed structure are discussed.

  11. A Novel Hybrid Ultramicrotomy/FIB-SEM Technique: Preparation of Serial Electron-Transparent Thin Sections of a Hayabusa Grain

    Science.gov (United States)

    Berger, Eve L.; Keller, Lindsay P.

    2014-01-01

    The Japanese space agency's (JAXA) Hayabusa mission returned the first particulate samples (typically SEM). Using a diamond trim knife, the epoxy surrounding the grain is removed on 3 sides (to within a few microns of the grain); the depth of material removed extends well below the bottom of the particle. The sample is attached to an SEM pin mount, the epoxy coated with conductive paint, and the entire assembly coated with approx. 40nm of carbon to eliminate sample charging during FIB work. A protective carbon cap is placed according to the plan for the 15 FIB sections. The central 'spine' of the cap runs perpendicular to the front of the sample, and the 'ribs' protruding from either side run parallel. Each rib indicates the location of a planned FIB section, and the spine contains the final two planned sections. We use a cap with a 4 micron-wide spine and 2micron-wide ribs that have ?3.5 micron of space between them (narrower cuts result in too much re-deposition of material inside the trenches). Using a 30kV, 3nA ion-beam we expose the front surface of the grain and commence milling trenches between sections. Rather than using the typical C-cut to prepare the sample for lift-out, an L-cut is used instead, leaving the sample connected by an interior tab. tab. Sections are lifted out, attached to TEM grids and thinned to electron transparency. TEM analyses show that our hybrid technique preserves both interior and edge features, including surface modifications from exposure to the space environment, such as damaged rims that form in response to solar wind implantation effects and adhering grains. In addition, the FIB sections provide larger areas that are free of fractures and chatter effects in comparison to the microtome thin sections, thus enabling more accurate measurements of solar flare particle track densities that are used to determine the surface exposure age of the particles.

  12. A Comparative Analysis of Different Finishing and Polishing Devices on Nanofilled, Microfilled, and Hybrid Composite: A Scanning Electron Microscopy and Profilometric Study

    Science.gov (United States)

    Yadav, Rishi D; Raisingani, Deepak; Mathur, Rachit

    2016-01-01

    The continuous development of esthetically acceptable adhesive restorative material has made a variety of tooth-colored materials available for clinical use. The advent of visible light polymerizing resin and the use of finer filler particles permit resin composites to be polished to higher degree. The effect of polishing systems on surface finish has been reported to be material-dependent, and the effectiveness of these systems was mostly product-dependent. Hence, the purpose of this study was to evaluate the efficiency of finishing and polishing systems on the surface roughness of nanofilled, microfilled, and hybrid composite restorative materials available in the market. How to cite this article Yadav RD, Raisingani D, Jindal D, Mathur R. A Comparative Analysis of Different Finishing and Polishing Devices on Nanofilled, Microfilled, and Hybrid Composite: A Scanning Electron Microscopy and Profilometric Study. Int J Clin Pediatr Dent 2016;9(3):201-208. PMID:27843250

  13. Self-consistent kinetic simulations of lower hybrid drift instability resulting in electron current driven by fusion products in tokamak plasmas

    CERN Document Server

    Cook, J W S; Dendy, R O

    2010-01-01

    We present particle-in-cell (PIC) simulations of minority energetic protons in deuterium plasmas, which demonstrate a collective instability responsible for emission near the lower hybrid frequency and its harmonics. The simulations capture the lower hybrid drift instability in a regime relevant to tokamak fusion plasmas, and show further that the excited electromagnetic fields collectively and collisionlessly couple free energy from the protons to directed electron motion. This results in an asymmetric tail antiparallel to the magnetic field. We focus on obliquely propagating modes under conditions approximating the outer mid-plane edge in a large tokamak, through which there pass confined centrally born fusion products on banana orbits that have large radial excursions. A fully self-consistent electromagnetic relativistic PIC code representing all vector field quantities and particle velocities in three dimensions as functions of a single spatial dimension is used to model this situation, by evolving the in...

  14. Protocol for a Randomized Controlled Trial of Proactive Web-Based Versus Telephone-Based Information and Support: Can Electronic Platforms Deliver Effective Care for Lung Cancer Patients?

    Science.gov (United States)

    Boyes, Allison W; O'Brien, Lorna; Baker, Amanda L; Henskens, Frans A; Clinton-McHarg, Tara; Bellamy, Douglas; Colburn, Glenda; Rose, Shiho; Cox, Martine E; Fradgley, Elizabeth A; Baird, Hannah; Barker, Daniel

    2016-01-01

    Background Community-based services such as telephone support lines can provide valuable informational, emotional, and practical support for cancer patients via telephone- or Web-based (live chat or email) platforms. However, very little rigorous research has examined the efficacy of such services in improving patient outcomes. Objective This study will determine whether: proactive telephone or Web-delivered support produces outcomes superior to printed information; and Web-delivered support produces outcomes comparable to telephone support. Methods A consecutive sample of 501 lung cancer outpatients will be recruited from 50 Australian health services to participate in a patient-randomized controlled trial (RCT). Eligible individuals must: be 18 years or older; have received a lung cancer diagnosis (including mesothelioma) within the previous 4 months; have an approximate life expectancy of at least 6 months; and have Internet access. Participants will be randomly allocated to receive: (1) an information booklet, (2) proactive telephone support, or (3) proactive Web support, chat, and/or email. The primary patient outcomes will be measured by the General Health Questionnaire (GHQ-12) and Health Education and Impact Questionnaire (heiQ) at 3 and 6 months post recruitment. The acceptability of proactive recruitment strategies will also be assessed. Results It is hypothesized that participants receiving telephone or Web support will report reduced distress (GHQ-12 scores that are 0.3 standard deviations (SD) lower) and greater self-efficacy (heiQ scores that are 0.3 SDs higher) than participants receiving booklets. Individuals receiving Web support will report heiQ scores within 0.29 SDs of individuals receiving telephone support. Conclusions If proven effective, electronic approaches such as live-chat and email have the potential to increase the accessibility and continuity of supportive care delivered by community-based services. This evidence may also inform the

  15. Design and implementation of electronic dictionary based on Android platform%基于Android平台电子词典的设计与实现

    Institute of Scientific and Technical Information of China (English)

    黄艺锋; 闫巧

    2011-01-01

    研究了在Android开发平台下电子词典软件的设计与实现过程,该系统是使用Android软件开发工具包和Eclipse集成开发环境进行开发的,实现了英语单词的翻译、学习、复习、测验、生词本、导入删除词库、背诵常用句子等功能,内置了相应的词库句库,也允许用户导入需要的词库进行学习.在词汇存储及检索方面,系统利用了Android集成的小型嵌入式数据库SQLite的开发接口.应用程序是基于Java语言开发完成的,并且已经在设备模拟器上测试通过.%This paper discussed the design and implementation process of electronic dictionary software on Android development platform. This application, using Android SDK and the Eclipse IDE to develop, is available in English translation, learning, reviewing, testing, attention book, import or delete dictionary, reciting English sentence and other functions. The software has built-in dictionaries, also allows users to import the necessary dictionary to learn. The system uses Android integrated development interface of SQLite to store and retrieve vocabulary. The applications are developed based on Java language, and worked as expected on the emulator.

  16. Bipolar resistive switching properties of Ti-CuO/(hexafluoro-hexa-peri-hexabenzocoronene)-Cu hybrid interface device: Influence of electronic nature of organic layer

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Bharti; Mehta, B. R.; Varandani, Deepak [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India); Govind [Surface Physics Group, National Physical Laboratory (CSIR), New Delhi-110012 (India); Narita, A.; Feng, X.; Muellen, K. [Max-Planck Institute for Polymer Research, D-55128 Mainz (Germany)

    2013-05-28

    This study reports the change in the structural and junction properties of Ti-CuO-Cu structure on incorporation of a 2-dimensional (2D) organic layer comprising of n-type hexafluoro-hexa-peri-hexabenzocoronene (6F-HBC). A bipolar resistive switching is observed in the device having interface between sputter deposited copper oxide (CuO) and vacuum sublimated 6F-HBC hybrid interface. The CuO/6F-HBC hybrid interface exhibits rectifying I-V characteristics in complete contrast to the ohmic and rectifying characteristics of junctions based on individual 6F-HBC and CuO layers. Large change in resistive switching property from unipolar resistive switching in CuO/HBC to bipolar resistive switching in CuO/6F-HBC interface was observed. At the CuO/6F-HBC interface, C1s peak corresponding to fluorinated carbon is shifted by 0.68 eV towards higher binding energy (BE) side and O1s peak due to non-lattice oxygen is shifted by 0.6 eV towards lower BE, confirming the interaction of O{sup 2-} ion in CuO with fluorinated carbon atoms in 6F-HBC at the hybrid interface. Correlation between conductive atomic force microscopy images and atomic force microscopy topography images, I-V characteristics in conducting, non-conducting, and pristine regions along with x-ray photoelectron spectroscopy results establishes the important role of hybrid interface to determining the resistive switching properties. This study demonstrates that the resistive switching and interface properties of a hybrid device based on inorganic and organic 2D materials can be modified by changing the electronic properties of organic layer by attaching suitable functional groups.

  17. Construction of NiO/MnO2/CeO2 hybrid nanoflake arrays as platform for electrochemical energy storage

    Science.gov (United States)

    Cui, Lihua; Cui, Jiewu; Zheng, Hongmei; Wang, Yan; Qin, Yongqiang; Shu, Xia; Liu, Jiaqin; Zhang, Yong; Wu, Yucheng

    2017-09-01

    Rational design and fabrication of novel electrode materials are of great importance for developing supercapacitors with remarkable capacitance and enhanced cycling stability. In this paper, we present a simple one-pot hydrothermal deposition followed by calcinations process for the in situ construction of homogeneous NiO/MnO2/CeO2 (NMC) nanoflake arrays on Ni foam substrate, which could be directly adopted as the binder-free electrode materials for high performance supercapacitors. The field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDX) are carried out to investigate the morphology, microstructure and composition of NMC nanoflake arrays. As-prepared hierarchical NMC nanoflake arrays exhibit the specific capacitance of 1027.8 F g-1 at a current density of 3.1 A g-1 and excellent cycling stability of 97.8% after 5000 charge/discharge cycles. This facile, cost-effective and controllable fabrication route and the robust supercapacitive activity suggest that the ordered NMC nanoflake arrays could be promising candidate electrode materials for high performance electrochemical energy storage devices.

  18. Particle-in-cell simulations of an alpha channeling scenario: electron current drive arising from lower hybrid drift instability of fusion-born ions

    Science.gov (United States)

    Cook, James; Chapman, Sandra; Dendy, Richard

    2010-11-01

    Particle-in-cell (PIC) simulations of fusion-born protons in deuterium plasmas demonstrate a key alpha channeling phenomenon for tokamak fusion plasmas. We focus on obliquely propagating modes at the plasma edge, excited by centrally born fusion products on banana orbits, known to be responsible for observations of ion cyclotron emission in JET and TFTR. A fully self-consistent electromagnetic 1D3V PIC code evolves a ring-beam distribution of 3MeV protons in a 10keV thermal deuterium-electron plasma with realistic mass ratio. A collective instability occurs, giving rise to electromagnetic field activity in the lower hybrid range of frequencies. Waves spontaneously excited by this lower hybrid drift instability undergo Landau damping on resonant electrons, drawing out an asymmetric tail in the distribution of electron parallel velocities, which constitutes a net current. These simulations demonstrate a key building block of some alpha channeling scenarios: the direct collisionless coupling of fusion product energy into a form which can help sustain the equilibrium of the tokamak.

  19. ITS Platform

    DEFF Research Database (Denmark)

    Tøfting, Svend; Lahrmann, Harry; Agerholm, Niels

    2014-01-01

    Aalborg University and two local companies have over the past four years developed and tested an ITS Platform, which can be used for communication with cars and for providing a number of services to the drivers. The purpose has been to perform a technological test of the possible use of a hidden ...... not have to be very intelligent. This is gradually taken over by applications on smart phones. The ITS Platform with 425 test drivers is now completely developed and can be used for technological testing of e.g. payment systems.......Aalborg University and two local companies have over the past four years developed and tested an ITS Platform, which can be used for communication with cars and for providing a number of services to the drivers. The purpose has been to perform a technological test of the possible use of a hidden...

  20. ITS Platform

    DEFF Research Database (Denmark)

    Tøfting, Svend; Lahrmann, Harry; Agerholm, Niels

    2014-01-01

    Aalborg University and two local companies have over the past four years developed and tested an ITS Platform, which can be used for communication with cars and for providing a number of services to the drivers. The purpose has been to perform a technological test of the possible use of a hidden ...... not have to be very intelligent. This is gradually taken over by applications on smart phones. The ITS Platform with 425 test drivers is now completely developed and can be used for technological testing of e.g. payment systems....

  1. Exploration of Compound Talents Cultivation Paths of Medical Beauty Products Cross-border Electronic Commerce Platform%医疗美容产品跨境电商平台复合型人才培养路径探析

    Institute of Scientific and Technical Information of China (English)

    陈静静

    2016-01-01

    本文以我国跨境电商平台发展为背景,简要介绍了医疗美容行业跨境电子商务发展现状,分析了医疗美容产品跨境电商平台人才需求,以市场需求、社会需求为导向,分析了我国医疗美容产品跨境电商平台人才培养困境,并从人才培养模式、人才培养机制、人才培养具体措施三个路径进行探索,提出医疗美容产品跨境电商平台复合型人才培养建议。%This paper is based on the development of China's cross-border electric business platform as the background, bri-efly describes the status of cross-border electronic commerce development of the medical beauty industry, analyzes the talent needs of medical beauty products cross-border electronic business platform, and analyzes the talents plight, then explores the paths from talent cultivation mode, system and measures, then proposes compound talent cultivation recommendations for cross-border electronic commerce products business platform.

  2. Note: Easy-to-maintain electron cyclotron resonance (ECR) plasma sputtering apparatus featuring hybrid waveguide and coaxial cables for microwave delivery.

    Science.gov (United States)

    Akazawa, Housei

    2016-06-01

    The branched-waveguide electron cyclotron resonance plasma sputtering apparatus places quartz windows for transmitting microwaves into the plasma source not in the line of sight of the target. However, the quartz windows must be replaced after some time of operation. For maintenance, the loop waveguide branching from the T-junction must be dismounted and re-assembled accurately, which is a time-consuming job. We investigated substituting the waveguide branches with two sets of coaxial cables and waveguide/coaxial cable converters to simplify assembly as far as connection and disconnection go. The resulting hybrid system worked well for the purposes of plasma generation and film deposition.

  3. Destination bonding: Hybrid cognition using Instagram

    Directory of Open Access Journals (Sweden)

    Arup Kumar Baksi

    2015-01-01

    Full Text Available Empirical research has identified the phenomenon of destination bonding as a result of summated physical and emotional values associated with the destination. Physical values, namely natural landscape & other physical settings and emotional values, namely the enculturation processes, have a significant role to play in portraying visitors’ cognitive framework for destination preference. The physical values seemed to be the stimulator for bonding that embodies action or behavior tendencies in imagery. The emotional values were the conditions that lead to affective bonding and are reflected in attitudes for a place which were evident in text narratives. Social networking on virtual platforms offers the scope for hybrid cognitive expression using imagery and text to the visitors. Instagram has emerged as an application-window to capture these hybrid cognitions of visitors. This study focuses on assessing the relationship between hybrid cognition of visitors expressed via Instagram and their bond with the destination. Further to this, the study attempts to examine the impact of hybrid cognition of visitors on the behavioral pattern of prospective visitors to the destination. The study revealed that sharing of visual imageries and related text by the visitors is an expression of the physico-emotional bonding with the destination. It was further established that hybrid cognition strongly asserts destination bonding and has been also found to have moderating impact on the link between destination bonding and electronic-word-of-mouth.

  4. Traffic sounds and cycling safety : the use of electronic devices by cyclists and the quietness of hybrid and electric cars.

    NARCIS (Netherlands)

    Stelling-Konczak, A. Hagenzieker, M.P. & Wee, B. van

    2015-01-01

    The growing popularity of electric devices and the increasing number of hybrid and electric cars have recently raised concerns about the use of auditory signals by vulnerable road users. This paper consolidates current knowledge about the two trends in relation to cycling safety. Both a literature r

  5. Traffic sounds and cycling safety : the use of electronic devices by cyclists and the quietness of hybrid and electric cars.

    NARCIS (Netherlands)

    Stelling-Konczak, A. Hagenzieker, M.P. & Wee, B. van

    2015-01-01

    The growing popularity of electric devices and the increasing number of hybrid and electric cars have recently raised concerns about the use of auditory signals by vulnerable road users. This paper consolidates current knowledge about the two trends in relation to cycling safety. Both a literature

  6. Synthesis of and evidence for electronic communication within heteromultimetallic Tetrakis(NCN-pincer metal) - (Metallo)porphyrin Hybrids

    NARCIS (Netherlands)

    Suijkerbuijk, B.M.J.M.; Tooke, D.M.; Lutz, M.|info:eu-repo/dai/nl/304828971; Spek, A.L.|info:eu-repo/dai/nl/156517566; Jenneskens, L.W.|info:eu-repo/dai/nl/071635246; van Koten, G.|info:eu-repo/dai/nl/073839191; Klein Gebbink, R.J.M.|info:eu-repo/dai/nl/166032646

    2010-01-01

    Several heteromultimetallic pincer-porphyrin hybrids have been prepared in excellent yields by stepwise metalation of a general precursor, [2H(Br(NCN))4], which was designed in such a way so as to guarantee selectivity for either the porphyrin or pincer sites during themetalation steps. First, ameta

  7. The Digital electronic Guideline Library (DeGeL): a hybrid framework for representation and use of clinical guidelines.

    Science.gov (United States)

    Shahar, Yuval; Young, Ohad; Shalom, Erez; Mayaffit, Alon; Moskovitch, Robert; Hessing, Alon; Galperin, Maya

    2004-01-01

    We propose to present a poster (and potentially also a demonstration of the implemented system) summarizing the current state of our work on a hybrid, multiple-format representation of clinical guidelines that facilitates conversion of guidelines from free text to a formal representation. We describe a distributed Web-based architecture (DeGeL) and a set of tools using the hybrid representation. The tools enable performing tasks such as guideline specification, semantic markup, search, retrieval, visualization, eligibility determination, runtime application and retrospective quality assessment. The representation includes four parallel formats: Free text (one or more original sources); semistructured text (labeled by the target guideline-ontology semantic labels); semiformal text (which includes some control specification); and a formal, machine-executable representation. The specification, indexing, search, retrieval, and browsing tools are essentially independent of the ontology chosen for guideline representation, but editing the semi-formal and formal formats requires ontology-specific tools, which we have developed in the case of the Asbru guideline-specification language. The four formats support increasingly sophisticated computational tasks. The hybrid guidelines are stored in a Web-based library. All tools, such as for runtime guideline application or retrospective quality assessment, are designed to operate on all representations. We demonstrate the hybrid framework by providing examples from the semantic markup and search tools.

  8. Platform computing

    CERN Multimedia

    2002-01-01

    "Platform Computing releases first grid-enabled workload management solution for IBM eServer Intel and UNIX high performance computing clusters. This Out-of-the-box solution maximizes the performance and capability of applications on IBM HPC clusters" (1/2 page) .

  9. Improved photochromic properties on viologen-based inorganic-organic hybrids by using π-conjugated substituents as electron donors and stabilizers.

    Science.gov (United States)

    Lin, Rong-Guang; Xu, Gang; Wang, Ming-Sheng; Lu, Gang; Li, Pei-Xin; Guo, Guo-Cong

    2013-02-04

    A series of inorganic-organic hybrid compounds L(2)(Bi(2)Cl(10)) (L = HMV(2+) = N-proton-N'-methyl-4,4'-bipyridinium for 1, L = HBzV(2+) = N-proton-N'-benzyl-4,4'-bipyridinium for 2, and L = HPeV(2+) = N-proton-N'-phenethyl-4,4'-bipyridinium for 3) have been successfully synthesized by an in situ solvothermal reaction. Compounds 1-3, with the same metal halide as anions but different asymmetric viologen molecules as cations, are ideal model compounds for investigating the detailed effect of different photochromically active molecules on the photochromic properties of the hybrids. Compound 1 shows no photochromic behavior, but compounds 2 and 3 possess photochromism and show a faster photoresponse rate than other reported viologen metal halide hybrids. Studies on the relationship between the structure and photochromic behavior clearly reveal that π-conjugated substituents could be used to improve the photoresponsibility and enrich the developed color efficiently and that the π···π interaction among organic components may not only be a powerful factor to stabilize the viologen monocation radical but also act as the second path of electron transfer from the π-conjugated substituent to the viologen cation for the photochromic process, which significantly influences the photochromic properties.

  10. Remote Sensing from Ground to Space Platforms Associated with Terrain Attributes as a Hybrid Strategy on the Development of a Pedological Map

    Directory of Open Access Journals (Sweden)

    José A. M. Demattê

    2016-10-01

    Full Text Available There is a consensus about the necessity to achieve a quick soil spatial information with few human resources. Remote/proximal sensing and pedotransference are methods that can be integrated into this approach. On the other hand, there is still a lack of strategies indicating on how to put this in practice, especially in the tropics. Thus, the objective of this work was to suggest a strategy for the spatial prediction of soil classes by using soil spectroscopy from ground laboratory spectra to space images platform, as associated with terrain attributes and spectral libraries. The study area is located in São Paulo State, Brazil, which was covered by a regular grid (one per ha, with 473 boreholes collected at top and undersurface. All soil samples were analyzed in laboratory (granulometry and chemical, and scanned with a VIS-NIR-SWIR (400–2500 nm spectroradiometer. We developed two traditional pedological maps with different detail levels for comparison: TFS-1 regarding orders and subgroups; and TFS-2 with additional information such as color, iron and fertility. Afterwards, we performed a digital soil map, generated by models, which used the following information: (i predicted soil attributes from undersurface layer (diagnostic horizon, obtained by using a local spectral library; (ii spectral reflectance of a bare soil surface obtained by Landsat image; and (iii derivative of terrain attributes. Thus, the digital map was generated by a combination of three variables: remote sensing (Landsat data, proximal sensing (laboratory spectroscopy and relief. Landsat image with bare soil was used as a first observation of surface. This strategy assisted on the location of topossequences to achieve soil variation in the area. Afterwards, spectral undersurface information from these locations was used to modelize soil attributes quantification (156 samples. The model was used to quantify samples in the entire area by spectra (other 317 samples. Since

  11. First-principles hybrid functional study of the electronic structure and charge carrier mobility in perovskite CH3NH3SnI3

    Science.gov (United States)

    Wu, Li-Juan; Zhao, Yu-Qing; Chen, Chang-Wen; Wang, Lin-Zhi; Liu, Biao; Cai, Meng-Qiu

    2016-10-01

    We calculate the electronic properties and carrier mobility of perovskite CH3NH3SnI3 as a solar cell absorber by using the hybrid functional method. The calculated result shows that the electron and hole mobilities have anisotropies with a large magnitude of 1.4 × 104 cm2·V-1·s-1 along the y direction. In view of the huge difference between hole and electron mobilities, the perovskite CH3NH3SnI3 can be considered as a p-type semiconductor. We also discover a relationship between the effective mass anisotropy and electronic occupation anisotropy. The above results can provide reliable guidance for its experimental applications in electronics and optoelectronics. Project supported by the National Natural Science Foundation of China (Grant No. 51172067), the Hunan Provincial Natural Science Fund for Distinguished Young Scholars, China (Grant No. 13JJ1013), the Specialized Research Fund for the Doctoral Program of Higher Education, China (Grant No. 20130161110036), and the New Century Excellent Talents in University, China (Grant No. NCET-12-0171.D).

  12. Nonlinear electronic excitations in crystalline solids using meta-generalized gradient approximation and hybrid functional in time-dependent density functional theory

    Science.gov (United States)

    Sato, Shunsuke A.; Taniguchi, Yasutaka; Shinohara, Yasushi; Yabana, Kazuhiro

    2015-12-01

    We develop methods to calculate electron dynamics in crystalline solids in real-time time-dependent density functional theory employing exchange-correlation potentials which reproduce band gap energies of dielectrics; a meta-generalized gradient approximation was proposed by Tran and Blaha [Phys. Rev. Lett. 102, 226401 (2009)] (TBm-BJ) and a hybrid functional was proposed by Heyd, Scuseria, and Ernzerhof [J. Chem. Phys. 118, 8207 (2003)] (HSE). In time evolution calculations employing the TB-mBJ potential, we have found it necessary to adopt the predictor-corrector step for a stable time evolution. We have developed a method to evaluate electronic excitation energy without referring to the energy functional which is unknown for the TB-mBJ potential. For the HSE functional, we have developed a method for the operation of the Fock-like term in Fourier space to facilitate efficient use of massive parallel computers equipped with graphic processing units. We compare electronic excitations in silicon and germanium induced by femtosecond laser pulses using the TB-mBJ, HSE, and a simple local density approximation (LDA). At low laser intensities, electronic excitations are found to be sensitive to the band gap energy: they are close to each other using TB-mBJ and HSE and are much smaller in LDA. At high laser intensities close to the damage threshold, electronic excitation energies do not differ much among the three cases.

  13. Nonlinear electronic excitations in crystalline solids using meta-generalized gradient approximation and hybrid functional in time-dependent density functional theory

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Shunsuke A. [Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571 (Japan); Taniguchi, Yasutaka [Center for Computational Science, University of Tsukuba, Tsukuba 305-8571 (Japan); Department of Medical and General Sciences, Nihon Institute of Medical Science, 1276 Shimogawara, Moroyama-Machi, Iruma-Gun, Saitama 350-0435 (Japan); Shinohara, Yasushi [Max Planck Institute of Microstructure Physics, 06120 Halle (Germany); Yabana, Kazuhiro [Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571 (Japan); Center for Computational Science, University of Tsukuba, Tsukuba 305-8571 (Japan)

    2015-12-14

    We develop methods to calculate electron dynamics in crystalline solids in real-time time-dependent density functional theory employing exchange-correlation potentials which reproduce band gap energies of dielectrics; a meta-generalized gradient approximation was proposed by Tran and Blaha [Phys. Rev. Lett. 102, 226401 (2009)] (TBm-BJ) and a hybrid functional was proposed by Heyd, Scuseria, and Ernzerhof [J. Chem. Phys. 118, 8207 (2003)] (HSE). In time evolution calculations employing the TB-mBJ potential, we have found it necessary to adopt the predictor-corrector step for a stable time evolution. We have developed a method to evaluate electronic excitation energy without referring to the energy functional which is unknown for the TB-mBJ potential. For the HSE functional, we have developed a method for the operation of the Fock-like term in Fourier space to facilitate efficient use of massive parallel computers equipped with graphic processing units. We compare electronic excitations in silicon and germanium induced by femtosecond laser pulses using the TB-mBJ, HSE, and a simple local density approximation (LDA). At low laser intensities, electronic excitations are found to be sensitive to the band gap energy: they are close to each other using TB-mBJ and HSE and are much smaller in LDA. At high laser intensities close to the damage threshold, electronic excitation energies do not differ much among the three cases.

  14. Assessing the Quality, Feasibility, and Efficacy of Electronic Patient Platforms Designed to Support Adolescents and Young Adults With Cancer: A Systematic Review Protocol

    Science.gov (United States)

    McCann, Lisa

    2017-01-01

    Background A range of innovative websites, mobile technologies, eHealth and mHealth platforms have emerged to support adolescents and young adults (AYAs) with cancer. Previous reviews have identified these various applications and solutions, but no review has summarized the quality, feasibility, and efficacy of existing patient platforms (inclusive of websites, mobile technologies, mHealth and eHealth platforms) developed specifically for young people with cancer. Objective This paper describes the design of a protocol to conduct a review of published studies or reports which describe or report on an existing platform designed specifically for AYAs who have had a cancer diagnosis. Methods A search string was developed using a variety of key words and Medical Subject Heading and applied to bibliographic databases. General data (sample characteristics, patient platform development, design and, if applicable, pilot testing outcomes) will be extracted from reports and studies. Drawing on a previously developed coding schematic, the identified patient platforms will be coded for mode of delivery into (1) automated functions, (2) communicative functions, and (3) use of supplementary modes. An adapted version of the Mobile App Rating Scale (MARS) will be used to assess the of quality of each identified patient platform. The methodological quality of included studies will be assessed using the Quality Assessment Criteria for Evaluating Primary Research Papers from a Variety of Fields (QualSyst). Both authors will independently screen eligible studies for final inclusion and will both be responsible for data extraction and appraisal. Data will be synthesized narratively to provide an overview of identified patient platforms. Results The review began in October 2016 and is currently in progress. The review paper will be submitted for peer-review and publication in the summer of 2017. Conclusions This review will be unique in its focus on assessing, where possible, the

  15. Assessing the Quality, Feasibility, and Efficacy of Electronic Patient Platforms Designed to Support Adolescents and Young Adults With Cancer: A Systematic Review Protocol.

    Science.gov (United States)

    Pugh, Gemma; McCann, Lisa

    2017-01-17

    A range of innovative websites, mobile technologies, eHealth and mHealth platforms have emerged to support adolescents and young adults (AYAs) with cancer. Previous reviews have identified these various applications and solutions, but no review has summarized the quality, feasibility, and efficacy of existing patient platforms (inclusive of websites, mobile technologies, mHealth and eHealth platforms) developed specifically for young people with cancer. This paper describes the design of a protocol to conduct a review of published studies or reports which describe or report on an existing platform designed specifically for AYAs who have had a cancer diagnosis. A search string was developed using a variety of key words and Medical Subject Heading and applied to bibliographic databases. General data (sample characteristics, patient platform development, design and, if applicable, pilot testing outcomes) will be extracted from reports and studies. Drawing on a previously developed coding schematic, the identified patient platforms will be coded for mode of delivery into (1) automated functions, (2) communicative functions, and (3) use of supplementary modes. An adapted version of the Mobile App Rating Scale (MARS) will be used to assess the of quality of each identified patient platform. The methodological quality of included studies will be assessed using the Quality Assessment Criteria for Evaluating Primary Research Papers from a Variety of Fields (QualSyst). Both authors will independently screen eligible studies for final inclusion and will both be responsible for data extraction and appraisal. Data will be synthesized narratively to provide an overview of identified patient platforms. The review began in October 2016 and is currently in progress. The review paper will be submitted for peer-review and publication in the summer of 2017. This review will be unique in its focus on assessing, where possible, the quality and efficacy of patient platforms for

  16. Development of CAN Network Monitoring Platform for Hybrid Electric Vehicle Based on Virtual Instrument%基于虚拟仪器的混合动力汽车CAN网络监控平台

    Institute of Scientific and Technical Information of China (English)

    曾秋萍; 陈笃红; 邵斌

    2012-01-01

    Connected via twisted pair,the engine controller, motor controller, vehicle controller,battery management unit and instrument display controller constituted CAN communication network. The PC connected with CAN bus via the PXI - 8464 interface card, which could get the real-time parameters of each controller and modify the inner data of them. The CAN network monitoring platform for hybrid electric vehicle was developed by graphical programming language LabVIEW9.0. The monitoring platform has the function of real-time parameters displaying, command giving, data saving and interactive human-computer interface, and fully satisfy the requirements of CAN network monitoring for HEV. The experimental results show that the system has high reliability, simple operation, timely data processing, and greatly improved the test rig efficiency.%将混合动力汽车的发动机控制器、电机控制器、整车控制器、电池管理单元和仪表显示控制器通过双绞线相连,构成CAN通讯网络,上位机通过PXI-8464接口卡接到CAN总线上,实时读取各控制器的参数及修改控制器中的数据.采用图形化编程语言LabVIEW 9.0开发了混合动力汽车CAN网络监控平台,此平台具有参数实时显示、指令发送、数据保存等功能和良好的人机交互式界面,满足了混合动力汽车CAN网络监控的各种需求.试验表明:系统操作简单明了,数据处理及时可靠,极大地改善了台架性能试验的工作效率.

  17. 3D-hybrid material design with electron/lithium-ion dual-conductivity for high-performance Li-sulfur batteries

    Science.gov (United States)

    Zhao, Yan; Tan, Rui; Yang, Jie; Wang, Kai; Gao, Rongtan; Liu, Dong; Liu, Yidong; Yang, Jinlong; Pan, Feng

    2017-02-01

    We report a novel 3D-hybrid cathode material with three-dimensional (3D) N-GO/CNT framework to load sulfur (77.6 wt %), and sulfonated polyaniline (SPANI) of coating layer. Used as a cathode material, it possesses a high capacity (1196 mAh g-1@0.3 A g-1@1.6 mg cm-2), excellent charging-discharging rate (680 mAh g-1@7.5 A g-1) and long-life performance (maintaining 71.1% capacity over 450 cycles), which is mainly attributed to the benefits of excellent electronic/Li-ionic dual-conductivity and confinement effect of the 3D-hybrid N-GO/CNT framework coated by self-doping conducting polymer SPANI. Thus, a 3D sulfur cathode modified with electronic/Li-ionic dual-conduction network can significantly enhance the electrochemical performance and stability, and this novel type of material is very promising for commercial applications that require high energy and power density, long life, and excellent abuse tolerance.

  18. Research on Electronic Document Management Platform Based on Attribute Encrypted%基于属性加密的电子文档管理平台的研究

    Institute of Scientific and Technical Information of China (English)

    周强; 吴克力

    2015-01-01

    With the rapid development of Internet technology, the electronic commerce also increasingly fre-quent, the resulting safety problems also more and more.To deal with the problem of message leaking, tampe-ring and disavowing in the electronic documents in electronic commerce and the electronic government affairs activity, this paper proposes a encrypted electronic document management platform based on attribute.The platform can deposit user’ s electronic contract documents and add security authentication watermark and read-only protection for the document.When there is doubt among users, they can get the document from hosting platforms and use that to resolve the dispute.The platform also provides two-factor authentication access con-trol.If users want to browse to the document, they must be certified by the identity of the client and the prop-erties of the attributes of the user set decryption certification.%随着互联网技术的飞速发展,电子商务活动也越发频繁,随之带来的安全隐患也越来越多。针对电子商务活动中存在的电子文档容易被泄密、篡改和抵赖等问题,提出了一种基于属性加密的电子文档管理平台。此平台可以托管用户的电子文档,并且添加防伪认证的数字水印和只读保护,当用户对协议产生异议时,可以从托管平台获取文档并以此来解决纠纷;该平台还提供了双重认证的访问控制,必须通过客户端的身份认证和用户相关属性的属性集合解密认证,用户才能有权限浏览到该文件。

  19. 基于嵌入式技术的高职高专电子专业实验教学平台设计%Design of Vocational College of Electronic Professional Experiment Teaching Platform Based on Embedded Technology

    Institute of Scientific and Technical Information of China (English)

    杨真理

    2015-01-01

    Analysis of the current vocational col ege,the present situation of electronic professional experiment teaching platform for its shortcoming designed a smal embedded electronic professional experiment teaching platform,through this platform to enable students to better grasp the theoretical knowledge,improve the comprehensive design ability.The possible problems in the process of experiment and subsequent development are discussed in this paper.%分析了目前高职高专院校电子专业实验教学平台现状,针对其不足之处设计了一款小型嵌入式电子专业实验教学平台,通过此平台使学生能够更好地掌握理论知识,提高综合设计能力,并就实验过程中可能出现的问题以及后续发展进行了探讨。

  20. A Portable and Autonomous Magnetic Detection Platform for Biosensing

    Directory of Open Access Journals (Sweden)

    Moisés S. Piedade

    2009-05-01

    Full Text Available This paper presents a prototype of a platform for biomolecular recognition detection. The system is based on a magnetoresistive biochip that performs biorecognition assays by detecting magnetically tagged targets. All the electronic circuitry for addressing, driving and reading out signals from spin-valve or magnetic tunnel junctions sensors is implemented using off-the-shelf components. Taking advantage of digital signal processing techniques, the acquired signals are processed in real time and transmitted to a digital analyzer that enables the user to control and follow the experiment through a graphical user interface. The developed platform is portable and capable of operating autonomously for nearly eight hours. Experimental results show that the noise level of the described platform is one order of magnitude lower than the one presented by the previously used measurement set-up. Experimental results also show that this device is able to detect magnetic nanoparticles with a diameter of 250 nm at a concentration of about 40 fM. Finally, the biomolecular recognition detection capabilities of the platform are demonstrated by performing a hybridization assay using complementary and non-complementary probes and a magnetically tagged 20mer single stranded DNA target.

  1. 飞机大部件调姿平台力位混合控制系统设计%Design on hybrid force position control of large aircraft components posture alignment platform

    Institute of Scientific and Technical Information of China (English)

    罗中海; 孟祥磊; 巴晓甫; 费少华; 方强

    2015-01-01

    In order to solve the problem that perpendicularity and parallelism error of three‐axis localizers cause posture alignment error and internal force of aircraft components ,the paper introduces a hybrid force position control system for posture alignment platform of large aircraft components . Error model of posture alignment was established to explain the problem .Then the strategy to select axes under position control and axes under force control was proposed based on condition number of mechanism’s Jacobian matrix .Static error calculation indicates that hybrid control strategy may improve posture accuracy and reduce internal force significantly under the given posture alignment condition w hen 0 .05 mm/m perpendicularity error exists on each localizer and the maximum parallelism error was 0 .1 mm/m and the averaged parallelism error was 0 .07 mm/m between localizers .The experiment indicates that the torque controller follows the desire torque signal properly with disturbing position signal and the dynamic torque error is below 0 .03 N · m ,w hich is applicable on real posture alignment platform .%为了解决调姿平台中,由于三坐标定位器自身各轴垂直度和相互各轴平行度误差引起的调姿误差以及对飞机大部件造成内力的问题,提出一种飞机大部件调姿平台的力/位置混合控制方法.通过建立调姿误差模型,分析三坐标定位器自身垂直度和相互平行度误差对姿态控制以及部件内力的影响;根据机构雅可比矩阵条件数,提出调姿平台力控制轴和位置控制轴分配策略;通过静态误差计算得到,在三坐标定位器垂直度误差为0.05 m m/m ,同向轴两两之间最大平行度误差为0.1 mm/m且平均平行度误差为0.07 mm/m时,在给定的部件尺寸和调姿轨迹下,力/位置混合控制方法的调姿精度优于全位置控制方法,并且显著降低了调姿部件内力.实验结果表明,力控

  2. Platform Constellations

    DEFF Research Database (Denmark)

    Staykova, Kalina Stefanova; Damsgaard, Jan

    2016-01-01

    messaging apps KakaoTalk and LINE, we are able to gain valuable insights about the nature of these new constructions and to capture and synthesize their main characteristics in a framework. Our results show that platform constellations possess unique innovative capabilities, which can improve users......’ acquisition and users’ engagement rates as well as unlock new sources of value creation and diversify revenue streams....

  3. 基于 Matlab/GUI 的电力电子电路仿真平台构建%Construction of simulation platform for power electronic circuits based on Matlab/GUI

    Institute of Scientific and Technical Information of China (English)

    刘芳; 吴成就; 潘俊涛

    2016-01-01

    基于 Matlab 的图形用户界面开发工具,构建了一套具有 Windows 风格的电力电子电路仿真平台;以三相桥式全控整流电路为例,展示了该平台的主要功能和实现方法。用户无需具备专业的 Matlab 知识,即可利用该平台进行工作原理分析、元器件参数设置、理论工作值计算并将仿真波形图在仿真界面上以人机交互的动态方式进行实时显示等一系列便捷操作。此外,该平台还可供学生进行自主学习、自主创新设计。该平台对于教师开展研究性和讨论式教学,提供开放性实验教学,增进学生对电力电子电路与系统的理解,提高学生自主学习和独立研究的能力有一定的帮助。%A Windows style simulation platform for the power electronic circuits is constructed by exploiting Matlab’s graphical user interface (GUI),and its main features and implementation methods are showed with a three-phase bridge type full-control rectifying circuit as an example.Without any professional knowledge of Matlab,a series of convenient operations,such as analyzing the working principle,setting parameters, calculating theoretical values,displaying the simulation waveforms dynamically on the platform with a good interactive interface,etc.,can be carried out with the developed platform by the users.Furthermore,the proposed platform can be used for the students to implement their active learning and independent innovation design.It is shown that the proposed platform could be used not only to help teachers in study-based teaching, study-discussion teaching and opening experimental teaching,but also to offer guidance to students to develop a better understanding in dealing with the power electronic circuits and systems,and to obtain their ability for learning and researching corresponding power electronics technology on their own.

  4. Bimaterial Microcantilevers as a Hybrid Sensing Platform

    Science.gov (United States)

    2008-01-01

    brush macromolecules, mi- celles and polymer/ biopolymer conjugates have been em- ployed for various applications including sensing, actuation...compensate for proteins, salts, and car - bohydrates taken up by the growing bacteria with the overall mass transfer monitored with cantilever deflection

  5. Effect of the electric field pattern on the generation of fast electrons in front of lower hybrid launchers

    Energy Technology Data Exchange (ETDEWEB)

    Valade, Laurent, E-mail: laurent.valade@cea.fr; Ekedahl, Annika; Colas, Laurent; Goniche, Marc; Hillairet, Julien [CEA, IRFM, F-13108 Saint Paul-lez-Durance (France); Fuchs, Vladimir; Petrzilka, Vaclav [Institute of Plasma Physics, AS CR, Prague (Czech Republic); Li, Miaohui; Zhang, Bin [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China)

    2015-12-10

    The effect of the detailed waveguide spectrum on the electron acceleration has been studied for the 3.7 GHz LHCD launchers in Tore Supra, i.e. the ITER-like passive-active multijunction (PAM) launcher and the fully-active-multijunction (FAM) launcher, using test electron modelling technique. The detailed launched antenna wave spectrum is used as input to the code that computes the dynamics of the electrons in the electric field. Comparison with the LHCD launchers in EAST, operating at 2.45 GHz and 4.6 GHz, has also been made. The simulations show that the PAM-design generates lower flux of fast electrons than FAM-launchers, this could be the consequence of the wider waveguide of PAM-launcher (14.65 mm for Tore-Supra) than FAM-launcher (8 mm for Tore-Supra)

  6. 光电平台伺服系统稳定环结构谐振自抗扰控制%An Active Disturbance Rejection Controller of the Stable Loop Structure Resonance of an Opto-electronic Platform Servo System

    Institute of Scientific and Technical Information of China (English)

    周涛

    2013-01-01

    The structure resonance perhaps causes the unstable system, which limits the tracking precision and the dynamic response speed of an airborne opto-electronic platform servo system. According to the zero-pole assignment principle, an active disturbance rejection controller is designed with a nominal control input. The active disturbance rejection controller is used to compensate the stable loop structure resonance of the opto-electronic platform servo system. Simulation experiment results demonstrate that the controller could inhibit the structure resonance influence on the servo system and increase the stable loop velocity tracking precision of the opto-electronic platform. Moreover, it is robust to the parameters’ changes of the structure resonance model.%  结构谐振可能造成系统不稳定,限制机载光电平台伺服系统的跟踪精度和动态响应速度。根据零极点配置原理,采用名义控制量进行自抗扰控制器的设计,利用该自抗扰控制器补偿光电平台伺服系统稳定环的结构谐振。仿真实验结果表明它较好地抑制了结构谐振对伺服系统的影响,提高了光电平台稳定环的速度跟踪精度,并且对结构谐振传递函数中参数较大范围的变化具有鲁棒性。

  7. High current density and longtime stable field electron transfer from large-area densely arrayed graphene nanosheet-carbon nanotube hybrids.

    Science.gov (United States)

    Deng, Jian-Hua; Cheng, Lin; Wang, Fan-Jie; Li, Guo-Zheng; Li, De-Jun; Cheng, Guo-An

    2014-12-10

    Achieving high current and longtime stable field emission from large area (larger than 1 mm(2)), densely arrayed emitters is of great importance in applications for vacuum electron sources. We report here the preparation of graphene nanosheet-carbon nanotube (GNS-CNT) hybrids by following a process of iron ion prebombardment on Si wafers, catalyst-free growth of GNSs on CNTs, and high-temperature annealing. Structural observations indicate that the iron ion prebombardment influences the growth of CNTs quite limitedly, and the self-assembled GNSs sparsely distributed on the tips of CNTs with their sharp edges unfolded outside. The field emission study indicates that the maximum emission current density (Jmax) is gradually promoted after these treatments, and the composition with GNSs is helpful for decreasing the operation fields of CNTs. An optimal Jmax up to 85.10 mA/cm(2) is achieved from a 4.65 mm(2) GNS-CNT sample, far larger than 7.41 mA/cm(2) for the as-grown CNTs. This great increase of Jmax is ascribed to the reinforced adhesion of GNS-CNT hybrids to substrates. We propose a rough calculation and find that this adhesion is promoted by 7.37 times after the three-step processing. We consider that both the ion prebombardment produced rough surface and the wrapping of CNT foot by catalyst residuals during thermal processing are responsible for this enhanced adhesion. Furthermore, the three-step prepared GNS-CNT hybrids present excellent field emission stability at high emission current densities (larger than 20 mA/cm(2)) after being perfectly aged.

  8. Platform for controlled supramolecular nanoassembly.

    Science.gov (United States)

    Czolkos, Ilja; Hannestad, Jonas K; Jesorka, Aldo; Kumar, Ravindra; Brown, Tom; Albinsson, Bo; Orwar, Owe

    2009-06-01

    We here present a two-dimensional (2D) micro/nano-fluidic technique where reactant-doped liquid-crystal films spread and mix on micro- and nanopatterned substrates. Surface-supported phospholipid monolayers are individually doped with complementary DNA molecules which hybridize when these lipid films mix. Using lipid films to convey reactants reduces the dimensionality of traditional 3D chemistry to 2D, and possibly to 1D by confining the lipid film to nanometer-sized lanes. The hybridization event was observed by FRET using single-molecule-sensitive confocal fluorescence detection. We could successfully detect hybridization in lipid streams on 250 nm wide lanes. Our results show that the number and density of reactants as well as sequence of reactant addition can be controlled within confined liquid crystal films, providing a platform for nanochemistry with potential for kinetic control.

  9. A hybrid electron and photon IMRT planning technique that lowers normal tissue integral patient dose using standard hardware.

    Science.gov (United States)

    Rosca, Florin

    2012-06-01

    To present a mixed electron and photon IMRT planning technique using electron beams with an energy range of 6-22 MeV and standard hardware that minimizes integral dose to patients for targets as deep as 7.5 cm. Ten brain cases, two lung, a thyroid, an abdominal, and a parotid case were planned using two planning techniques: a photon-only IMRT (IMRT) versus a mixed modality treatment (E+IMRT) that includes an enface electron beam and a photon IMRT portion that ensures a uniform target coverage. The electron beam is delivered using a regular cutout placed in an electron cone. The electron energy was chosen to provide a good trade-off between minimizing integral dose and generating a uniform, deliverable plan. The authors choose electron energies that cover the deepest part of PTV with the 65%-70% isodose line. The normal tissue integral dose, the dose for ring structures around the PTV, and the volumes of the 75%, 50%, and 25% isosurfaces were used to compare the dose distributions generated by the two planning techniques. The normal tissue integral dose was lowered by about 20% by the E+IMRT plans compared to the photon-only IMRT ones for most studied cases. With the exception of lungs, the dose reduction associated to the E+IMRT plans was more pronounced further away from the target. The average dose ratio delivered to the 0-2 cm and the 2-4 cm ring structures for brain patients for the two planning techniques were 89.6% and 70.8%, respectively. The enhanced dose sparing away from the target for the brain patients can also be observed in the ratio of the 75%, 50%, and 25% isodose line volumes for the two techniques, which decreases from 85.5% to 72.6% and further to 65.1%, respectively. For lungs, the lateral electron beams used in the E+IMRT plans were perpendicular to the mostly anterior/posterior photon beams, generating much more conformal plans. The authors proved that even using the existing electron delivery hardware, a mixed electron/photon planning

  10. 基于电子签证平台的海事静态监管新模式%n the New Mode for MSA Static Control Based on Electronic Endorsement Platform

    Institute of Scientific and Technical Information of China (English)

    步长水

    2015-01-01

    Based on the electronic endorsement platform, Rizhao MSA has effectively integrated various affairs and established a new mode for static control. With high level of IT application, the mode, being scientific and efficient, will play an important role in the future maritime administration.%基于电子签证平台,日照海事局有效整合多种业务,创建了静态监管新模式。该模式科学高效,信息化程度高,将在以后的监管工作发挥重要的作用。

  11. Functional separation of oxidation–reduction reactions and electron transport in PtRu/ND and conductive additive hybrid electrocatalysts during methanol oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yan; Wang, Yanhui [State Key Laboratory of Metastable Materials Science and Technology, College of Materials Science and Engineering, Yanshan University, Qinhuangdao 066004 (China); Bian, Linyan [College of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000 (China); Lu, Rui [State Key Laboratory of Metastable Materials Science and Technology, College of Materials Science and Engineering, Yanshan University, Qinhuangdao 066004 (China); Zang, Jianbing, E-mail: jbzang@ysu.edu.cn [State Key Laboratory of Metastable Materials Science and Technology, College of Materials Science and Engineering, Yanshan University, Qinhuangdao 066004 (China)

    2016-02-28

    Graphical abstract: - Highlights: • Functional separation of reactions and electron transport in PtRu/ND + AB (or CNT). • A conductive network was formed after the addition of AB or CNT. • PtRu/ND + AB (or CNT) exhibited enhanced activity and stability than PtRu/ND. - Abstract: Undoped nanodiamond (ND) supported PtRu (PtRu/ND) electrocatalyst for methanol oxidation reactions (MOR) in direct methanol fuel cells was prepared by a microwave-assisted polyol reduction method. Sp{sup 3}-bonded ND possesses high electrochemical stability but low conductivity, while sp{sup 2}-bonded carbon nanomaterials with high conductivity are prone to oxidation. Therefore, the functions of the supporting material were separated in this study. ND (sp{sup 3}), as a support, and AB or CNTs (sp{sup 2}), as a conductive additive, were combined to form the hybrid electrocatalysts PtRu/ND + AB and PtRu/ND + CNT for MOR. The morphology of the electrocatalysts was characterized by scanning electron microscopy and electrochemical measurements were performed using an electrochemical workstation. The results indicated that the electrocatalytic activity of PtRu/ND for MOR was improved with the addition of AB or CNTs as a conductive additive. Moreover, adding CNTs to PtRu/ND as a conductive additive showed better electrocatalytic activities than adding AB, which can be ascribed to the better electron-transfer ability of CNTs.

  12. Interfacial electronic structure and charge transfer of hybrid graphene quantum dot and graphitic carbon nitride nanocomposites: insights into high efficiency for photocatalytic solar water splitting.

    Science.gov (United States)

    Ma, Zuju; Sa, Rongjian; Li, Qiaohong; Wu, Kechen

    2016-01-14

    New metal-free carbon nanodot/carbon nitride (C3N4) nanocomposites have shown to exhibit high efficiency for photocatalytic solar water splitting. (J. Liu, et al., Science, 2015, 347, 970) However, the mechanism underlying the ultrahigh performance of these nanocomposites and consequently the possibilities for further improvements are not at present clear. In this work, we performed hybrid functional calculations and included long-range dispersion corrections to accurately characterize the interfacial electron coupling of the graphene quantum dot-graphitic carbon nitride composites (Gdot/g-C3N4). The results revealed that the band gap of Gdot/g-C3N4 could be engineered by changing the lateral size of Gdots. In particular, the C24H12/g-C3N4 composites present an ideal band gap of 1.92 eV to harvest a large part of solar light. More interestingly, a type-II heterojunction is formed at the interface of the Gdot/g-C3N4 composites, a desirable feature for enhanced photocatalytic activity. The charge redistribution at the interface leads to strong electron depletion above the Gdot sheet and electron accumulation below the g-C3N4 monolayer, potentially facilitating the separation of H2O oxidation and reduction reactions. Furthermore, we suggested that the photocatalytic performance of the Gdot/g-C3N4 nanocomposites can be further improved by decreasing the thickness of Gdots and tuning the size of Gdots.

  13. Hybrid functional study of structural, electronic and magnetic properties of S-doped ZnO with and without neutral vacancy

    Energy Technology Data Exchange (ETDEWEB)

    Debbichi, M., E-mail: mourad_fsm@yahoo.fr [Laboratoire de la matière condensée et nanosciences, Département de Physique, Faculté des Sciences de Monastir, 5019 Monastir (Tunisia); Sakhraoui, T. [Laboratoire de la matière condensée et nanosciences, Département de Physique, Faculté des Sciences de Monastir, 5019 Monastir (Tunisia); Debbichi, L. [Institut Carnot de Bourgogne, UMR 6303, Université de Bourgogne-CNRS, 21078 Dijon (France); Said, M. [Laboratoire de la matière condensée et nanosciences, Département de Physique, Faculté des Sciences de Monastir, 5019 Monastir (Tunisia)

    2013-11-25

    Highlights: •S-doped ZnO have been investigated by DFT and EPM. •Good agreement with the experimental data is obtained by HSE (α = 0.28) functional on lattice parameters and band gap energy. •Zn vacancy introduced in S doped ZnO is studied by HSE to determine its electronic and magnetic properties. -- Abstract: The structural and electronic properties of S-doped ZnO are investigated by density functional theory (DFT) and empirical pseudopotential method (EPM). Using the Heyd–Scuseria–Ernzerhof (HSE) hybrid functional with an adjusted mixing coefficient α, we obtain a good agreement on lattice parameters and band gap energy with the available experimental data. We have also investigate the Zn-vacancy effects on the electronic and magnetic properties of S-doped ZnO. Our calculations demonstrate that S impurity prefers to be close to the cation vacancy in the apical position. The magnetic analysis with the HSE functional shows a triplet state character with a total magnetic moment of 1.81 μ{sub B}, which is mainly arises from the p-orbitals of the atoms around the Zn-vacancy (15% from S, 12% from Zn and 73% from O-atoms). The substitution of S by an isovalent atom decreases the total magnetic moments of the system and weakens the local triplet state without destroying it.

  14. Structural, electronic and energetic properties of giant icosahedral fullerenes up to C6000: insights from an ab initio hybrid DFT study.

    Science.gov (United States)

    Noël, Yves; De La Pierre, Marco; Zicovich-Wilson, Claudio M; Orlando, Roberto; Dovesi, Roberto

    2014-07-14

    The properties of the (n,n) icosahedral family of carbon fullerenes up to n = 10 (6000 atoms) have been investigated through ab initio quantum-mechanical simulation by using a Gaussian type basis set of double zeta quality with polarization functions (84,000 atomic orbitals for the largest case), the hybrid B3LYP functional and the CRYSTAL14 code featuring generalization of symmetry treatment. The geometry of giant fullerenes shows hybrid features, between a polyhedron and a sphere; as n increases, it approaches the former. Hexagon rings at face centres take a planar, graphene-like configuration; the 12 pentagon rings at vertices impose, however, a severe structural constraint to which hexagon rings at the edges must adapt smoothly, adopting a bent (rather than sharp) transversal profile and an inward longitudinal curvature. The HOMO and LUMO electronic levels, as well as the band gap, are well described using power laws. The gap is predicted to become zero for n ≥ 34 (69,360 atoms). The atomic excess energy with respect to the ideal graphene sheet goes to zero following the log(Nat)/Nat law, which is well described through the continuum elastic theory applied to graphene; the limits for the adopted model are briefly outlined. Compared to larger fullerenes of the series, C60 shows unique features with respect to all the considered properties; C240 presents minor structural and energetic peculiarities, too.

  15. The electronic structure of organic-inorganic hybrid compounds: (NH₄)₂CuCl₄, (CH₃NH₃)₂CuCl₄ and (C₂H₅NH₃)₂CuCl₄.

    Science.gov (United States)

    Zolfaghari, P; de Wijs, G A; de Groot, R A

    2013-07-24

    Hybrid organic-inorganic compounds are an intriguing class of materials that have been experimentally studied over the past few years because of a potential broad range of applications. The electronic and magnetic properties of three organic-inorganic hybrid compounds with compositions (NH4)2CuCl4, (CH3NH3)2CuCl4 and (C2H5NH3)2CuCl4 are investigated for the first time with density functional theory plus on-site Coulomb interaction. A strong Coulomb interaction on the copper causes a relatively weak exchange coupling within the layers of the octahedral network, in good agreement with experiment. The character of the exchange interaction (responsible for magnetic behavior) is analyzed. The calculations reveal that (C2H5NH3)2CuCl4 has the strongest Jahn-Teller (JT) distortion in comparison with the two other compounds. The easy axis of magnetization is investigated, showing a weak anisotropic interaction between inter-layer Cu(2+) ions in the (C2H5NH3)2CuCl4 structure. Orbital ordering is concluded from our partial density of states calculations: a cooperation of the JT distortion with an antiferro-distortive pattern.

  16. 跨境电商全球速卖通平台店铺运营分析与实践%Analysis and practice of cross-border electronic business store operation on global speed-selling platform

    Institute of Scientific and Technical Information of China (English)

    刘世鹏; 张欣雨

    2016-01-01

    With the improvement of global e-commerce system, the emergence of global speed-selling platform provides a new carrier and path for cross-border electronic business. In order to adapt to the characteristics of electronic commerce, internationalization and interconnection, cross-border electronic merchants should make full use of the global speed-selling platform to speed up the flattening of cross-border electronic business transactions, automation of the process, and promote the change and innovation process from the aspects of logistics, talents and trade, so as to make the effective support and active adaptation for the development of cross-border electronic business.%在全球电子商务体系逐步完善的今天,全球速卖通平台的出现为跨境电商提供了新的载体和路径。为了顺应商务电子化、国际化和互联互通的时代特点,跨境电商要更好地运用全球速卖通平台,以店铺运营作为中心,加速跨境电商交易的扁平化、流程的自动化,从物流、人才、交易等各个层面推进变革与创新的进程,达到对跨境电商发展的有效支持和积极适应。

  17. First principle study of electronic and optical properties of molecular ion (BF4- ) substituted hybrid perovskite (CH3NH3PbI3)

    Science.gov (United States)

    Rani, Shalu; Singh, Poorva

    2017-05-01

    Hybrid organic/inorganic perovskites have garnered significant research interest due to the extraordinary increase in energy conversion efficiency as witnessed in photovoltaic devices based on CH3NH3PbI3. An experimental report has shown that the substitution of BF4- in the perovskite CH3NH3PbI3 can lead to the high efficiency for solar cell. Employing first-principles calculations based on density functional theory, we have studied several different perovskites CH3NH3PbI3 , CH3NH3PbI2BF4, CH3NH3PbI(BF4)2, CH3NH3Pb(BF4)3 and examined their electronic structure and optical properties.

  18. ZnO Nanorods on a LaAlO 3 -SrTiO 3 Interface: Hybrid 1D-2D Diodes with Engineered Electronic Properties

    KAUST Repository

    Bera, Ashok

    2015-12-28

    Integrating nanomaterials with different dimensionalities and properties is a versatile approach toward realizing new functionalities in advanced devices. Here, a novel diode-type heterostructure is reported consisting of 1D semiconducting ZnO nanorods and 2D metallic LaAlO3-SrTiO3 interface. Tunable insulator-to-metal transitions, absent in the individual components, are observed as a result of the competing temperature-dependent conduction mechanisms. Detailed transport analysis reveals direct tunneling at low bias, Fowler-Nordheim tunneling at high forward bias, and Zener breakdown at high reverse bias. Our results highlight the rich electronic properties of such artificial diodes with hybrid dimensionalities, and the design principle may be generalized to other nanomaterials. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. ZnO Nanorods on a LaAlO3 -SrTiO3 Interface: Hybrid 1D-2D Diodes with Engineered Electronic Properties.

    Science.gov (United States)

    Bera, Ashok; Lin, Weinan; Yao, Yingbang; Ding, Junfeng; Lourembam, James; Wu, Tom

    2016-02-10

    Integrating nanomaterials with different dimensionalities and properties is a versatile approach toward realizing new functionalities in advanced devices. Here, a novel diode-type heterostructure is reported consisting of 1D semiconducting ZnO nanorods and 2D metallic LaAlO3-SrTiO3 interface. Tunable insulator-to-metal transitions, absent in the individual components, are observed as a result of the competing temperature-dependent conduction mechanisms. Detailed transport analysis reveals direct tunneling at low bias, Fowler-Nordheim tunneling at high forward bias, and Zener breakdown at high reverse bias. Our results highlight the rich electronic properties of such artificial diodes with hybrid dimensionalities, and the design principle may be generalized to other nanomaterials.

  20. Application of P-wave Hybrid Theory to the Scattering of Electrons from He+ and Resonances in He and H ion

    Science.gov (United States)

    Bhatia, A. K.

    2012-01-01

    The P-wave hybrid theory of electron-hydrogen elastic scattering [Phys. Rev. A 85, 052708 (2012)] is applied to the P-wave scattering from He ion. In this method, both short-range and long-range correlations are included in the Schroedinger equation at the same time, by using a combination of a modified method of polarized orbitals and the optical potential formalism. The short-correlation functions are of Hylleraas type. It is found that the phase shifts are not significantly affected by the modification of the target function by a method similar to the method of polarized orbitals and they are close to the phase shifts calculated earlier by Bhatia [Phys. Rev. A 69, 032714 (2004)]. This indicates that the correlation function is general enough to include the target distortion (polarization) in the presence of the incident electron. The important fact is that in the present calculation, to obtain similar results only a 20-term correlation function is needed in the wave function compared to the 220- term wave function required in the above-mentioned calculation. Results for the phase shifts, obtained in the present hybrid formalism, are rigorous lower bounds to the exact phase shifts. The lowest P-wave resonances in He atom and hydrogen ion have been calculated and compared with the results obtained using the Feshbach projection operator formalism [Phys. Rev. A, 11, 2018 (1975)]. It is concluded that accurate resonance parameters can be obtained by the present method, which has the advantage of including corrections due to neighboring resonances, bound states and the continuum in which these resonance are embedded.

  1. Electronic self-monitoring of mood using IT platforms in adult patients with bipolar disorder: A systematic review of the validity and evidence

    DEFF Research Database (Denmark)

    Faurholt-Jepsen, Maria; Munkholm, Klaus; Frost, Mads

    2016-01-01

    in the majority of studies. Conclusions: Electronic self-monitoring of mood in depression appears to be a valid measure of mood in contrast to self-monitoring of mood in mania. There are yet few studies on the effect of electronic self-monitoring of mood in bipolar disorder. The evidence of electronic self......Background: Various paper-based mood charting instruments are used in the monitoring of symptoms in bipolar disorder. During recent years an increasing number of electronic self-monitoring tools have been developed. The objectives of this systematic review were 1) to evaluate the validity...... of electronic self-monitoring tools as a method of evaluating mood compared to clinical rating scales for depression and mania and 2) to investigate the effect of electronic self-monitoring tools on clinically relevant outcomes in bipolar disorder. Methods: A systematic review of the scientific literature...

  2. Electronic self-monitoring of mood using IT platforms in adult patients with bipolar disorder: A systematic review of the validity and evidence

    OpenAIRE

    2016-01-01

    Background Various paper-based mood charting instruments are used in the monitoring of symptoms in bipolar disorder. During recent years an increasing number of electronic self-monitoring tools have been developed. The objectives of this systematic review were 1) to evaluate the validity of electronic self-monitoring tools as a method of evaluating mood compared to clinical rating scales for depression and mania and 2) to investigate the effect of electronic self-monitoring tools on clinicall...

  3. Structural and electronic properties of hybrid perovskites for high-efficiency thin-film photovoltaics from first-principles

    Directory of Open Access Journals (Sweden)

    Federico Brivio

    2013-10-01

    Full Text Available The performance of perovskite solar cells recently exceeded 15% solar-to-electricity conversion efficiency for small-area devices. The fundamental properties of the active absorber layers, hybrid organic-inorganic perovskites formed from mixing metal and organic halides [e.g., (NH4PbI3 and (CH3NH3PbI3], are largely unknown. The materials are semiconductors with direct band gaps at the boundary of the first Brillouin zone. The calculated dielectric constants and band gaps show an orientation dependence, with a low barrier for rotation of the organic cations. Due to the electric dipole of the methylammonium cation, a photoferroic effect may be accessible, which could enhance carrier collection.

  4. Growth and Transfer of Seamless 3D Graphene-Nanotube Hybrids.

    Science.gov (United States)

    Kim, Nam Dong; Li, Yilun; Wang, Gunuk; Fan, Xiujun; Jiang, Jinlong; Li, Lei; Ji, Yongsung; Ruan, Gedeng; Hauge, Robert H; Tour, James M

    2016-02-10

    Seamlessly connected graphene and carbon nanotube hybrids (GCNTs) have great potential as carbon platform structures in electronics due to their high conductivity and high surface area. Here, we introduce a facile method for making patterned GCNTs and their intact transfer onto other substrates. The mechanism for selective growth of vertically aligned CNTs (VA-CNTs) on the patterned graphene is discussed. The complete transfer of the GCNT pattern onto other substrates is possible because of the mechanical strength of the GCNT hybrids. Electrical conductivity measurements of the transferred GCNT structures show Ohmic contact through the VA-CNTs to graphene--evidence of its integrity after the transfer process.

  5. Research on the Fourth Party Logistics Management Platform Based on the Electronic Commerce Environment%基于电子商务环境下第四方物流管理平台研究

    Institute of Scientific and Technical Information of China (English)

    严维红

    2014-01-01

    文章对目前电子商务物流存在的问题进行了分析。以第四方物流为切入点,试图建立一个第四方物流运作平台,用来为电子商务提供更快、更好的物流服务,降低物流成本,提高客户的满意度和忠诚度。%This paper analyzes the problems of electronic com-merce logistics. Taking the fourth party logistics as the break-through point, this paper tries to build a fourth party logistics platform. We intend to provide faster, better service for the electronic commerce logistics, reduce logistics costs, improve customer's satisfaction and loyalty.

  6. Multifunctional Inverse Opal-Like TiO2 Electron Transport Layer for Efficient Hybrid Perovskite Solar Cells.

    Science.gov (United States)

    Chen, Xiao; Yang, Shuang; Zheng, Yi Chu; Chen, Ying; Hou, Yu; Yang, Xiao Hua; Yang, Hua Gui

    2015-09-01

    A novel multifunctional inverse opal-like TiO2 electron transport layer (IOT-ETL) is designed to replace the traditional compact layer and mesoporous scaffold layer in perovskite solar cells (PSCs). Improved light harvesting efficiency and charge transporting performance in IOT-ETL based PSCs yield high power conversion efficiency of 13.11%.

  7. 基于云计算的电子政务公共平台建设研究%Research on the Building of Electronic Government Public Platform Based on the Cloud Computing

    Institute of Scientific and Technical Information of China (English)

    吕小刚

    2016-01-01

    伴随着我国进入智慧政府建设阶段,政府信息化建设模式也从政府主导转向满足公众需求为核心点的需求导向、问题导向的全新模式。新形势下政府云平台的建设更好地整合硬件和服务资源,并实现资源的高效调度与公众需求最大化契合。文章通过对云计算相关概念的阐述,以“创新、协调、绿色、开放、共享”理念为基础,剖析出基于云计算的电子政务公共平台建设的意义,探索基于云计算电子政务公共平台建设的对策。%With our government developing into intelligent government, the information construction mode of government has transformed from government-led to a new mode that must be need for the public. Under the new situation government cloud platform construction is integrating the hardware resources and software resources together better, and dispatching all kinds of resources for the need of public. By stating the conception of the cloud computing, based on the ethos of“innovation, co-ordination, environment, opening, sharing”, the paper analyzes the meaning of the building of electronic government public platform based on the cloud computing and explores the strategy of building of electronic government public platform based on the cloud computing.

  8. ZrO2/TiO2 Electron Collection Layer for Efficient Meso-Superstructured Hybrid Perovskite Solar Cells.

    Science.gov (United States)

    Mejía Escobar, Mario Alejandro; Pathak, Sandeep; Liu, Jiewei; Snaith, Henry J; Jaramillo, Franklin

    2017-01-25

    Since the first reports of efficient organic-inorganic perovskite solar cells in 2012, an explosion of research activity has emerged around the world, which has led to a rise in the power conversion efficiencies (PCEs) to over 20%. Despite the impressive efficiency, a key area of the device which remains suboptimal is the electron extraction layer and its interface with the photoactive perovskite. Here, we implement an electron collection "bilayer" composed of a thin layer of zirconia coated with titania, sitting upon the transparent conductive oxide fluorine-doped tin oxide (FTO). With this double collection layer we have reached up to 17.9% power conversion efficiency, delivering a stabilized power output (SPO) of 17.0%, measured under simulated AM 1.5 sunlight of 100 mW cm(-2) irradiance. Finally, we propose a mechanism of the charge transfer processes within the fabricated architectures in order to explain the obtained performance of the devices.

  9. Theoretical and experimental investigations of optical, structural and electronic properties of the lower-dimensional hybrid [NH3-(CH2)10-NH3]ZnCl4

    Science.gov (United States)

    El Mrabet, R.; Kassou, S.; Tahiri, O.; Belaaraj, A.; Guionneau, P.

    2016-10-01

    In the current study, a combination between theoretical and experimental studies has been made for the hybrid perovskite [NH3-(CH2)10-NH3]ZnCl4. The density functional theory (DFT) was performed to investigate structural and electronic properties of the tilted compound. A local approximation (LDA) and semi-local approach (GGA) were employed. The results are obtained using, respectively, the local exchange correlation functional of Perdew-Wang 92 (PW92) and semi local functional of Perdew-Burke-Ernzerhof (PBE). The optimized cell parameters are in good agreement with the experimental results. Electronic properties have been studied through the calculation of band structures and density of state (DOS), while structural properties are investigated by geometry optimization of the cell. Fritz-Haber-Institute (FHI) pseudopotentials were employed to perform all calculations. The optical diffuse reflectance spectra was mesured and applied to deduce the refractive index ( n), the extinction coefficient ( k), the absorption coefficient (α), the real and imaginary dielectric permittivity parts (ɛr,ɛi)) and the optical band gap energy Eg. The optical band gap energy value shows good consistent with that obtained from DFT calculations and reveals the insulating behavior of the material.

  10. A hybrid functional study of the electronic and optical properties of tetragonal PbO-type phase of ZnO under pressure

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Qingbo [State Key Laboratory of Material Processing and Die and Mould Technology and School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei (China); School of Mathematics and Physics, China University of Geosciences (Wuhan), Wuhan 430074, Hubei (China); Wen, Yanwei [State Key Laboratory of Material Processing and Die and Mould Technology and School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei (China); Chen, Rong, E-mail: rongchen@mail.hust.edu.cn [State Key Laboratory of Digital Manufacturing Equipment and Technology and School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei (China); Shan, Bin, E-mail: bshan@mail.hust.edu.cn [State Key Laboratory of Material Processing and Die and Mould Technology and School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei (China); Department of Materials Science and Engineering, The University of Texas at Dallas, Richardson, TX 75080 (United States)

    2014-02-15

    Highlights: • HSE was used to study the electronic and optical properties of new B10 ZnO phase. • Band gap is ranging from 6.08 to 7.06 eV under high pressure from 236 to 316 GPa. • The optical constants undergo a blue shift with the increasing pressure. -- Abstract: To extend our knowledge on the tetragonal PbO-type (B10) phase of ZnO under high pressure, we used the hybrid functional theory to calculate its electronic and optical properties. Our calculations indicate that the B10 phase is a transparent insulator and has an indirect band gap ranging from 6.08 to 7.06 eV with pressure increasing from 236 to 316 GPa. The B10 phase under 236 GPa has excellent dielectric properties except metallic behaviors at around 25 and 37 eV photon excitation. We found a blue shift in optical properties of the B10 phase with the increase of pressure.

  11. Ground-state phase diagram, fermionic entanglement and kinetically-induced frustration in a hybrid ladder with localized spins and mobile electrons

    Science.gov (United States)

    Carvalho, R. C. P.; Pereira, M. S. S.; de Oliveira, I. N.; Strečka, J.; Lyra, M. L.

    2017-09-01

    We introduce an exactly solvable hybrid spin-ladder model containing localized nodal Ising spins and interstitial mobile electrons, which are allowed to perform a quantum-mechanical hopping between the ladder’s legs. The quantum-mechanical hopping process induces an antiferromagnetic coupling between the ladder’s legs that competes with a direct exchange coupling of the nodal spins. The model is exactly mapped onto the Ising spin ladder with temperature-dependent two- and four-spin interactions, which is subsequently solved using the transfer-matrix technique. We report the ground-state phase diagram and compute the fermionic concurrence to characterize the quantum entanglement between the pair of interstitial mobile electrons. We further provide a detailed analysis of the local spin ordering including the pair and four-spin correlation functions around an elementary plaquette, as well as, the local ordering diagrams. It is shown that a complex sequence of distinct local orderings and frustrated correlations takes place when the model parameters drive the investigated system close to a zero-temperature triple coexistence point.

  12. A hybrid digital-signature and zero-watermarking approach for authentication and protection of sensitive electronic documents.

    Science.gov (United States)

    Tayan, Omar; Kabir, Muhammad N; Alginahi, Yasser M

    2014-01-01

    This paper addresses the problems and threats associated with verification of integrity, proof of authenticity, tamper detection, and copyright protection for digital-text content. Such issues were largely addressed in the literature for images, audio, and video, with only a few papers addressing the challenge of sensitive plain-text media under known constraints. Specifically, with text as the predominant online communication medium, it becomes crucial that techniques are deployed to protect such information. A number of digital-signature, hashing, and watermarking schemes have been proposed that essentially bind source data or embed invisible data in a cover media to achieve its goal. While many such complex schemes with resource redundancies are sufficient in offline and less-sensitive texts, this paper proposes a hybrid approach based on zero-watermarking and digital-signature-like manipulations for sensitive text documents in order to achieve content originality and integrity verification without physically modifying the cover text in anyway. The proposed algorithm was implemented and shown to be robust against undetected content modifications and is capable of confirming proof of originality whilst detecting and locating deliberate/nondeliberate tampering. Additionally, enhancements in resource utilisation and reduced redundancies were achieved in comparison to traditional encryption-based approaches. Finally, analysis and remarks are made about the current state of the art, and future research issues are discussed under the given constraints.

  13. A Hybrid Digital-Signature and Zero-Watermarking Approach for Authentication and Protection of Sensitive Electronic Documents

    Directory of Open Access Journals (Sweden)

    Omar Tayan

    2014-01-01

    Full Text Available This paper addresses the problems and threats associated with verification of integrity, proof of authenticity, tamper detection, and copyright protection for digital-text content. Such issues were largely addressed in the literature for images, audio, and video, with only a few papers addressing the challenge of sensitive plain-text media under known constraints. Specifically, with text as the predominant online communication medium, it becomes crucial that techniques are deployed to protect such information. A number of digital-signature, hashing, and watermarking schemes have been proposed that essentially bind source data or embed invisible data in a cover media to achieve its goal. While many such complex schemes with resource redundancies are sufficient in offline and less-sensitive texts, this paper proposes a hybrid approach based on zero-watermarking and digital-signature-like manipulations for sensitive text documents in order to achieve content originality and integrity verification without physically modifying the cover text in anyway. The proposed algorithm was implemented and shown to be robust against undetected content modifications and is capable of confirming proof of originality whilst detecting and locating deliberate/nondeliberate tampering. Additionally, enhancements in resource utilisation and reduced redundancies were achieved in comparison to traditional encryption-based approaches. Finally, analysis and remarks are made about the current state of the art, and future research issues are discussed under the given constraints.

  14. A hybrid method for protection against threats to a network infrastructure for an electronic warfare management system

    Science.gov (United States)

    Byłak, Michał; RóŻański, Grzegorz

    2017-04-01

    The article presents the concept of ensuring the security of network information infrastructure for the management of Electronic Warfare (EW) systems. The concept takes into account the reactive and proactive tools against threats. An overview of the methods used to support the safety of IT networks and information sources about threats is presented. Integration of mechanisms that allow for effective intrusion detection and rapid response to threats in a network has been proposed. The architecture of the research environment is also presented.

  15. SECURITY STRATEGY AND APPLICATION ANALYSIS OF TIANJIN GRAIN & OIL COMMODITY ELECTRONIC TRADING PLATFORM SYSTEM%天津粮油商品电子交易平台系统安全策略及应用分析

    Institute of Scientific and Technical Information of China (English)

    谢智勇; 吴维吉; 赵韫珂; 杜宝峰

    2015-01-01

    The security of the electronic trading platform plays a vital role in the process of the operation of the system.Aiming at improving the security of electronic trading system,the paper expounds on the security strate-gy of Tianjin Grain &Oil Electronic Trading System in the light of the development process of Tianjin Grain &Oil Electronic Trading System from 4 aspects such as system security,server security,network security,applica-tion system security,in order to reduce the security risk of the trading system to the maximum extent.%电子交易平台的安全性在系统运行过程中起着至关重要的作用。以提高电子交易系统安全性为目的,结合天津粮油电子交易系统的开发过程,从系统安全、服务器安全、网络安全、应用系统安全等4方面,阐述了天津粮油电子交易系统所使用的安全策略,最大程度降低了交易系统运行的安全风险。

  16. AN ANALYSIS ON CHOOSING A PROPER ECOMMERCE PLATFORM

    OpenAIRE

    Radu Lixandroiu; Catalin Maican

    2015-01-01

    Choosing an electronic trading platform is a very important decision when opening an online store. A suitable platform must be able to meet many of the requirements as to not confuse the user. It should provide an online business operation providing tools for managing back-office of technically. There are dozens maybe hundreds of electronic ecommerce platforms available to create an online store, so the decision to choose a platform is difficult. In this article, we tried to compare 19 of the...

  17. OPTESIM, a versatile toolbox for numerical simulation of electron spin echo envelope modulation (ESEEM) that features hybrid optimization and statistical assessment of parameters.

    Science.gov (United States)

    Sun, Li; Hernandez-Guzman, Jessica; Warncke, Kurt

    2009-09-01

    Electron spin echo envelope modulation (ESEEM) is a technique of pulsed-electron paramagnetic resonance (EPR) spectroscopy. The analyis of ESEEM data to extract information about the nuclear and electronic structure of a disordered (powder) paramagnetic system requires accurate and efficient numerical simulations. A single coupled nucleus of known nuclear g value (g(N)) and spin I=1 can have up to eight adjustable parameters in the nuclear part of the spin Hamiltonian. We have developed OPTESIM, an ESEEM simulation toolbox, for automated numerical simulation of powder two- and three-pulse one-dimensional ESEEM for arbitrary number (N) and type (I, g(N)) of coupled nuclei, and arbitrary mutual orientations of the hyperfine tensor principal axis systems for N>1. OPTESIM is based in the Matlab environment, and includes the following features: (1) a fast algorithm for translation of the spin Hamiltonian into simulated ESEEM, (2) different optimization methods that can be hybridized to achieve an efficient coarse-to-fine grained search of the parameter space and convergence to a global minimum, (3) statistical analysis of the simulation parameters, which allows the identification of simultaneous confidence regions at specific confidence levels. OPTESIM also includes a geometry-preserving spherical averaging algorithm as default for N>1, and global optimization over multiple experimental conditions, such as the dephasing time (tau) for three-pulse ESEEM, and external magnetic field values. Application examples for simulation of (14)N coupling (N=1, N=2) in biological and chemical model paramagnets are included. Automated, optimized simulations by using OPTESIM lead to a convergence on dramatically shorter time scales, relative to manual simulations.

  18. Amorphous Tin Oxide as a Low-Temperature-Processed Electron-Transport Layer for Organic and Hybrid Perovskite Solar Cells

    KAUST Repository

    Barbe, Jeremy

    2017-02-08

    Chemical bath deposition (CBD) of tin oxide (SnO) thin films as an electron-transport layer (ETL) in a planar-heterojunction n-i-p organohalide lead perovskite and organic bulk-heterojunction (BHJ) solar cells is reported. The amorphous SnO (a-SnO) films are grown from a nontoxic aqueous bath of tin chloride at a very low temperature (55 °C) and do not require postannealing treatment to work very effectively as an ETL in a planar-heterojunction n-i-p organohalide lead perovskite or organic BHJ solar cells, in lieu of the commonly used ETL materials titanium oxide (TiO) and zinc oxide (ZnO), respectively. Ultraviolet photoelectron spectroscopy measurements on the glass/indium-tin oxide (ITO)/SnO/methylammonium lead iodide (MAPbI)/2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobifluorene device stack indicate that extraction of photogenerated electrons is facilitated by a perfect alignment of the conduction bands at the SnO/MAPbI interface, while the deep valence band of SnO ensures strong hole-blocking properties. Despite exhibiting very low electron mobility, the excellent interfacial energetics combined with high transparency (E > 4 eV) and uniform substrate coverage make the a-SnO ETL prepared by CBD an excellent candidate for the potentially low-cost and large-scale fabrication of organohalide lead perovskite and organic photovoltaics.

  19. Liquid Water- and Heat-Resistant Hybrid Perovskite Photovoltaics via an Inverted ALD Oxide Electron Extraction Layer Design.

    Science.gov (United States)

    Kim, In Soo; Cao, Duyen H; Buchholz, D Bruce; Emery, Jonathan D; Farha, Omar K; Hupp, Joseph T; Kanatzidis, Mercouri G; Martinson, Alex B F

    2016-12-14

    Despite rapid advances in conversion efficiency (>22%), the environmental stability of perovskite solar cells remains a substantial barrier to commercialization. Here, we show a significant improvement in the stability of inverted perovskite solar cells against liquid water and high operating temperature (100 °C) by integrating an ultrathin amorphous oxide electron extraction layer via atomic layer deposition (ALD). These unencapsulated inverted devices exhibit a stable operation over at least 10 h when subjected to high thermal stress (100 °C) in ambient environments, as well as upon direct contact with a droplet of water without further encapsulation.

  20. The Effect of Electronic Word of Mouth on Intention to Book Accommodation via Online Peer-to-Peer Platform: Investigation of Theory of Planned Behaviour

    Directory of Open Access Journals (Sweden)

    See-Kwong Goh

    2016-01-01

    Full Text Available The main purpose for conducting the research is to investigate whether positive eWOM received by consumers would influence their intention to book accommodation via a peer-to-peer website or mobile phone apps (such as Airbnb. The research was conducted by utilizing the Theory of Planned Behaviour which integrates the eWOM, attitude, subjective norms, perceived behavioural control and behavioural intention. A total of 226 responses had been recorded. The main findings from this research are related to the key role played by positive eWOM received towards an individual’s attitude, subjective norm and perceived behavioural control which influences their intention to book their accommodation through an online peer-to-peer platform.

  1. Perovskite oxide SrTiO3 as an efficient electron transporter for hybrid perovskite solar cells

    KAUST Repository

    Bera, Ashok

    2014-12-11

    In this work, we explored perovskite oxide SrTiO3 (STO) for the first time as the electron-transporting layer in organolead trihalide perovskite solar cells. The steady-state photoluminescence (PL) quenching and transient absorption experiments revealed efficient photoelectron transfer from CH3NH3PbI3-xClx to STO. Perovskite solar cells with meso-STO exhibit an open circuit voltage of 1.01 V, which is 25% higher than the value of 0.81 V achieved in the control device with the conventional meso-TiO2. In addition, an increase of 17% in the fill factor was achieved by tailoring the thickness of the meso-STO layer. We found that the application of STO leads to uniform perovskite layers with large grains and complete surface coverage, leading to a high shunt resistance and improved performance. These findings suggest STO as a competitive candidate as electron transport material in organometal perovskite solar cells.

  2. ZnO-(Cu/Ag)TCNQ heterostructure network over flexible platform for enhanced cold cathode application

    Science.gov (United States)

    Pal, Shreyasi; Maiti, Soumen; Narayan Maiti, Uday; Chattopadhyay, Kalyan Kumar

    2016-07-01

    Multistage field emitters consisting of organic/inorganic hybrid nanostructures with branched geometry are designed via a two-step protocol: a simple wet chemical method followed by a vapor-solid-phase technique. (Cu/Ag)TCNQ (copper/silver-7,7,8,8-tetracyanoquinodimethane) nanowires (NWs) were grown hierarchically on zinc oxide (ZnO) nanorods (NRs) to form ZnO-(Cu/Ag)TCNQ heterostructure assemblies. By monitoring the metallic Cu and Ag coating thickness on ZnO NRs, precise control over the morphology and orientations of the secondary organic NWs is achieved. In-depth analysis of electron field emission (FE) behavior of the ZnO-(Cu/Ag)TCNQ-based hierarchy suggests highest emission performance with low turn-on as well as threshold fields of 1.15 and 3.75 V μm-1 respectively from the morphology-optimized hierarchy. Beneficial orientation of the branched organic NWs ensures sequential electric field enhancement in the consecutive stem and branches whereas its low work function eases electron emission; these aspects combined together render an overall enhancement in the emission behavior of the hybrid system. As compared to individual building units, the heterostructures show improved field electron emission. Additionally, successful construction of this novel hybrid over a fabric platform displays great potential in opening up new pathways in the highly-anticipated field of flexible electronics.

  3. Photoinduced electron transfer pathways in hydrogen-evolving reduced graphene oxide-boosted hybrid nano-bio catalyst.

    Science.gov (United States)

    Wang, Peng; Dimitrijevic, Nada M; Chang, Angela Y; Schaller, Richard D; Liu, Yuzi; Rajh, Tijana; Rozhkova, Elena A

    2014-08-26

    Photocatalytic production of clean hydrogen fuels using water and sunlight has attracted remarkable attention due to the increasing global energy demand. Natural and synthetic dyes can be utilized to sensitize semiconductors for solar energy transformation using visible light. In this study, reduced graphene oxide (rGO) and a membrane protein bacteriorhodopsin (bR) were employed as building modules to harness visible light by a Pt/TiO2 nanocatalyst. Introduction of the rGO boosts the nano-bio catalyst performance that results in hydrogen production rates of approximately 11.24 mmol of H2 (μmol protein)(-1) h(-1). Photoelectrochemical measurements show a 9-fold increase in photocurrent density when TiO2 electrodes were modified with rGO and bR. Electron paramagnetic resonance and transient absorption spectroscopy demonstrate an interfacial charge transfer from the photoexcited rGO to the semiconductor under visible light.

  4. A DETECTION METHOD FOR CLOUD PLATFORM COVERT CHANNEL BASED ON HYBRID INDICATORS OF ENTROPY AND STANDARD DEVIATION%一种基于熵率和标准差混合指标的云平台隐蔽信道检测方法

    Institute of Scientific and Technical Information of China (English)

    邱桂华

    2013-01-01

    Cloud computing is the focus at present in the field of information technology , and the cloud platform covert channel is a new safety problem caused by the infrastructure of cloud computing platform .The covert channel in cloud platform will leak the confidential information of cloud customers , seriously damages the safety of cloud platform .We summarise the correlative works of the covert channel detection, aiming at the cloud platform covert channel based on CPU response time , we abstract its model, and put forward at the first time a detection method with hybrid indicators of the integration of entropy and standard deviation .Experimental results show that this detection method can reach a false positive rate less than 5%, therefore has good detection performance .%云计算是目前信息技术领域研究的热点,而云平台隐蔽信道是由云计算平台的基础架构导致的新的安全问题。云平台隐蔽信道会泄漏云客户的机密信息,严重危害云平台安全。总结隐蔽信道检测的相关工作,并针对基于CPU响应时间的云平台隐蔽信道,抽象云平台隐蔽信道模型,首次提出融合熵率和标准差混合指标的检测方法。实验结果表明使用该检测方法能够达到低于5%的误报率,具有很好的检测性能。

  5. Energetic stability, oxidation states, and electronic structure of Bi-doped NaTaO3: a first-principles hybrid functional study.

    Science.gov (United States)

    Joo, Paul H; Behtash, Maziar; Yang, Kesong

    2016-01-14

    We studied the defect formation energies, oxidation states of the dopants, and electronic structures of Bi-doped NaTaO3 using first-principles hybrid density functional theory calculations. Three possible structural models, including Bi-doped NaTaO3 with Bi at the Na site (Bi@Na), with Bi at the Ta site (Bi@Ta), and with Bi at both Na and Ta sites [Bi@(Na,Ta)], are constructed. Our results show that the preferred doping sites of Bi are strongly related to the preparation conditions of NaTaO3. It is energetically more favorable to form a Bi@Na structure under Na-poor conditions, to form a Bi@Ta structure under Na-rich conditions, and to form a Bi@(Na,Ta) structure under mildly Na-rich conditions. The Bi@Na doped model shows an n-type conducting character along with an expected blueshift of the optical absorption edge, in which the Bi atoms exist as Bi(3+) (6s(2)6p(0)). The Bi@Ta doped model has empty gap states consisting of Bi 6s states in its band gap, which can lead to visible-light absorption via the electron transition among the valence band, the conduction band, and the gap states. The Bi dopant is present as a Bi(5+) ion in this model, consistent with the experimental results. In contrast, the Bi@(Na,Ta) doped model has occupied gap states consisting of Bi 6s states in its band gap, and thus visible-light absorption is also expected in this system due to electron excitation from these occupied states to the conduction band, in which the Bi dopants exist as Bi(3+) ions. Our first-principles electronic structure calculations revealed the relationship between the Bi doping sites and the material preparation conditions, and clarified the oxidation states of Bi dopants in NaTaO3 as well as the origin of different visible-light photocatalytic hydrogen evolution behaviors in Bi@Ta and Bi@(Na,Ta) doped NaTaO3. This work can provide a useful reference for preparing a Bi-doped NaTaO3 photocatalyst with desired doping sites.

  6. 建立我国网上药店统一电子交易平台的探讨%Exploration on Establishment of Unified Electronic Trading Platform of Online Pharmacies in China

    Institute of Scientific and Technical Information of China (English)

    孟令全; 武志昂

    2012-01-01

    OBJECTIVE: To provide reference to promote the development of online pharmacies in China. METHODS: The situation and development bottle neck of online pharmacy in China and the necessity, feasibility and development mode of unified electronic trading platform were analyzed according to literature study. RESULTS & CONCLUSIONS: Up to Sept. 22th, 2011, a total of 48 online pharmacies have been approved, while only 10 pharmacies run formally. The main development bottlenecks of online pharmacies in China are that online pharmacy electronic trading platform hadn't been coupled with online medicare payment system, and there was lack of the influential brand or aircraft carrier class online pharmacies. The establishment of unified electronic trading platforms of online pharmacy contributes to online retail market development with low cost by pharmaceutical enterprise, to the drug price compared by consumers and loyalty of consumer to online pharmacy, to the supervision of the government departments on online drug retail and purchase behavior, and to creating online pharmacies brand website, and it is feasible in the fields of technology, economy and operation. China' s online pharmacies unified electronic trading platform can speed up development and improve the whole level of service through the alliance mode and the third party mode.%目的:为促进我国网上药店的发展提供参考.方法:根据文献,对我国网上药店的现状、发展瓶颈,建立统一电子交易平台的必要性、可行性以及发展模式进行分析.结果与结论:截至2011年9月22日,我国批准的网上药店共48家,而正式经营的仅十余家.我国网上药店统一电子交易平台存在未与医疗保障体系对接、有影响力的品牌或航母级网上药店缺失等主要发展瓶颈.我国网上药店统一电子交易平台的建立利于医药企业低成本开拓网上零售市场、利于消费者比较药品价格及提升消费者对网上药店的忠

  7. 基于云计算的电商平台设计方案的研究%Research on the Design Scheme of an Electronic Business Platform Based on Cloud Computing

    Institute of Scientific and Technical Information of China (English)

    顾海燕

    2015-01-01

    The paper is to introduce the basic concepts of cloud computing. To solve the problems of the Yantai-Apple industry,the paper proposes a scheme of building the electronic business platform of the Yantai-Apple Based on Cloud Computing, and introduces the detailed design ideas.%本文在介绍了云计算的基本概念的基础上,针对烟台苹果行业出现的问题,提出了在云计算基础上搭建烟台苹果电商平台的方案,并介绍了方案的详细设计思路。

  8. 基于电子医嘱平台的医护沟通的新模式%New Model of Doctor-Nurse Communication Based on Electronic Medical Advice Platform

    Institute of Scientific and Technical Information of China (English)

    曹阳; 丁爱民; 王燕

    2012-01-01

    介绍了借助电子医嘱平台,建立医护之间沟通的新模式.该模式在提高医护工作效率、安全治疗病人、防范医疗事故,减少医疗差错等方面取得了显著的效果.%This article introduces a new model of the communication between doctors and nurses, with the aid of the electronic medical advice platform. This model has achieved good results in improving doctor and nurse's co-working efficiency, treating patients safely, preventing medical accidents, reducing medical errors and so on.

  9. Real-space and plane-wave hybrid method for electronic structure calculations for two-dimensional materials

    Science.gov (United States)

    Do, V. Nam; Le, H. Anh; Vu, V. Thieu

    2017-04-01

    We propose a computational approach to combining the plane-wave method and the real-space treatment to describe the periodic variation in the material plane and the decay of wave functions from the material surfaces. The proposed approach is natural for two-dimensional material systems and thus may circumvent some intrinsic limitations involving the artificial replication of material layers in traditional supercell methods. In particular, we show that the proposed method is easy to implement and, especially, computationally effective since low-cost computational algorithms, such as iterative and recursive techniques, can be used to treat matrices with block tridiagonal structure. Using this approach we show first-principles features that supplement the current knowledge of some fundamental issues in bilayer graphene systems, including the coupling between the two graphene layers, the preservation of the σ band of monolayer graphene in the electronic structure of the bilayer system, and the differences in low-energy band structure between the AA- and AB-stacked configurations.

  10. Material platforms for integrated quantum photonics

    CERN Document Server

    Bogdanov, Simeon; Boltasseva, Alexandra; Shalaev, Vladimir M

    2016-01-01

    On-chip integration of quantum optical systems could be a major factor enabling photonic quantum technologies. Unlike the case of electronics, where the essential device is a transistor and the dominant material is silicon, the toolbox of elementary devices required for both classical and quantum photonic integrated circuits is vast. Therefore, many material platforms are being examined to host the future quantum photonic computers and network nodes. We discuss the pros and cons of several platforms for realizing various elementary devices, compare the current degrees of integration achieved in each platform and review several composite platform approaches.

  11. Diverse application platform for hard X-ray diffraction in SACLA (DAPHNIS): application to serial protein crystallography using an X-ray free-electron laser.

    Science.gov (United States)

    Tono, Kensuke; Nango, Eriko; Sugahara, Michihiro; Song, Changyong; Park, Jaehyun; Tanaka, Tomoyuki; Tanaka, Rie; Joti, Yasumasa; Kameshima, Takashi; Ono, Shun; Hatsui, Takaki; Mizohata, Eiichi; Suzuki, Mamoru; Shimamura, Tatsuro; Tanaka, Yoshiki; Iwata, So; Yabashi, Makina

    2015-05-01

    An experimental system for serial femtosecond crystallography using an X-ray free-electron laser (XFEL) has been developed. It basically consists of a sample chamber, fluid injectors and a two-dimensional detector. The chamber and the injectors are operated under helium atmosphere at 1 atm. The ambient pressure operation facilitates applications to fluid samples. Three kinds of injectors are employed to feed randomly oriented crystals in aqueous solution or highly viscous fluid. Experiments on lysozyme crystals were performed by using the 10 keV XFEL of the SPring-8 Angstrom Compact free-electron LAser (SACLA). The structure of model protein lysozyme from 1 µm crystals at a resolution of 2.4 Å was obtained.

  12. A zero dimensional hybrid organic-inorganic perovskite ZnCl4 based: Synthesis, crystal structure, UV-vis, and electronic properties

    Science.gov (United States)

    El Mrabet, Rajae; Kassou, Said; Tahiri, Obaida; Belaaraj, Abdesselam; El Ammari, Lahcen; Saadi, Mohamed

    2017-08-01

    A low dimensional hybrid perovskite-like system [H3Nsbnd (CH2)8sbnd NH3]ZnCl4 was synthesized by slow evaporation method at room temperature. Single crystal X-ray diffraction was used to characterize the crystal structure. The compound crystallizes into triclinic system P-1 space group with mutually surrounded inorganic (ZnCl4)-2 organic (H3Nsbnd (CH2)8sbnd NH3) entities, and the following unit cell parameters: a = 6.9998(1) Å, b = 10.7846(2) Å, c = 11.0332(2) Å, α = 83.1730(10)°, β = 82.0490(10)°, γ = 73.2820(10)°, V = 787.27(2) Å3 and Z = 2. The optical band gap deduced from UV-visible spectroscopy was found to be 4.9 eV. Hirshfeld surface analysis shows the importance of hydrogen bonding interactions to ensure the cohesion of the studied crystal. The band structures and electronic properties, such as total and partial densities of state, were investigated by density functional theory (DFT) using a local LDA and semi local GGA approaches. The obtained results reveal the insulating behavior of the material.

  13. Electrochemical immunoassay of benzo[a]pyrene based on dual amplification strategy of electron-accelerated Fe{sub 3}O{sub 4}/polyaniline platform and multi-enzyme-functionalized carbon sphere label

    Energy Technology Data Exchange (ETDEWEB)

    Lin Mouhong [Institute of Biomaterials, College of Sciences, South China Agricultural University, Guangzhou 510642, Guangdong Province (China); Liu Yingju, E-mail: liuyingju@hotmail.com [Institute of Biomaterials, College of Sciences, South China Agricultural University, Guangzhou 510642, Guangdong Province (China); Sun Zihong; Zhang Shenglai; Yang Zhuohong [Institute of Biomaterials, College of Sciences, South China Agricultural University, Guangzhou 510642, Guangdong Province (China); Ni Chunlin, E-mail: niclchem@scau.edu.cn [Institute of Biomaterials, College of Sciences, South China Agricultural University, Guangzhou 510642, Guangdong Province (China)

    2012-04-13

    Graphical abstract: Schematic representation of Fe{sub 3}O{sub 4}/PANI/Nafion-based immunosensor using multi-HRP-HCS-Ab{sub 2} bioconjugates as labels. Highlights: Black-Right-Pointing-Pointer An electrochemical immunosensor for high sensitive detection of BaP. Black-Right-Pointing-Pointer A dual amplification strategy by Fe{sub 3}O{sub 4}/PANI/Nafion film and multi-HRP-HCS-Ab{sub 2} label. Black-Right-Pointing-Pointer An accelerated electron transfer pathway by the Fe{sub 3}O{sub 4}/PANI/Nafion film. - Abstract: An electrochemical immunosensor, basing on a dual amplification strategy by employing a biocompatible Fe{sub 3}O{sub 4}/polyaniline/Nafion (Fe{sub 3}O{sub 4}/PANI/Nafion) layer as sensor platform and multi-enzyme-antibody functionalized highly-carbonized spheres (multi-HRP-HCS-Ab{sub 2}) as label, was constructed for sensitive detection of benzo[a]pyrene (BaP). The stable film, Fe{sub 3}O{sub 4}/PANI/Nafion, can not only immobilize biomolecules, but also catalyze the reduction of hydrogen peroxide, indicating an accelerated electron transfer pathway of the platform. The experimental conditions, including the concentration of Nafion, concentration of Fe{sub 3}O{sub 4}/polyaniline (Fe{sub 3}O{sub 4}/PANI), pH of the detection solution and concentrations of biomolecules, were studied in detail. Basing on a competitive immunoassay, the current change was proportional to the logarithm of BaP concentration in the range of 8 pM and 2 nM with the detection limit of 4 pM. The proposed immunosensor exhibited acceptable reproducibility and stability. This new type of dual amplification strategy may provide potential applications for the detection of environmental pollutants.

  14. Flying Electronic Warfare Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — FUNCTION: Provides NP-3D aircraft host platforms for Effectiveness of Navy Electronic Warfare Systems (ENEWS) Program antiship missile (ASM) seeker simulators used...

  15. Flying Electronic Warfare Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — FUNCTION: Provides NP-3D aircraft host platforms for Effectiveness of Navy Electronic Warfare Systems (ENEWS) Program antiship missile (ASM) seeker simulators used...

  16. Graphene on Pt3Ni(1 1 1): a suitable platform for tunable charge doping, electron-phonon coupling and plasmonic excitations

    Science.gov (United States)

    Politano, Antonio; Chiarello, Gennaro

    2017-09-01

    Despite intensive investigations, the comprehension of the mechanisms ruling the interplay of charge doping, electron-phonon coupling and dynamic screening in supported graphene remains elusive yet. Using a combination of surface-science spectroscopies, we have studied these phenomena for graphene on both Pt-skin-terminated and nickel-oxide-skin-terminated Pt3Ni(1 1 1). Graphene epitaxially grown on the (1 1 1)-oriented Pt skin behaves as a charge-neutral graphene/metal contact, exhibiting a reduced coupling of the out-of-plane optical phonon with Dirac-cone electrons. Conversely, p-doped graphene/Pt(1 1 1) exhibits giant Kohn anomalies arising from the electron-phonon coupling. Upon oxidation, the Pt skin of Pt3Ni(1 1 1) evolves into a nickel-oxide skin, which results into a p-type doped graphene sheet. The plasmonic spectrum shows dramatic changes when going from a graphene/Pt-skin/Pt3Ni to a graphene/nickel-oxide/Pt3Ni configuration. Finally, we show that the presence of Ni atoms in the metal alloy does not affect the temperature at which the graphene phase is formed, contrarily to the interpretation of previous experiments.

  17. Microgravity Platforms

    Science.gov (United States)

    Del Basso, Steve

    2000-01-01

    The world's space agencies have been conducting microgravity research since the beginning of space flight. Initially driven by the need to understand the impact of less than- earth gravity physics on manned space flight, microgravity research has evolved into a broad class of scientific experimentation that utilizes extreme low acceleration environments. The U.S. NASA microgravity research program supports both basic and applied research in five key areas: biotechnology - focusing on macro-molecular crystal growth as well as the use of the unique space environment to assemble and grow mammalian tissue; combustion science - focusing on the process of ignition, flame propagation, and extinction of gaseous, liquid, and solid fuels; fluid physics - including aspects of fluid dynamics and transport phenomena; fundamental physics - including the study of critical phenomena, low-temperature, atomic, and gravitational physics; and materials science - including electronic and photonic materials, glasses and ceramics, polymers, and metals and alloys. Similar activities prevail within the Chinese, European, Japanese, and Russian agencies with participation from additional international organizations as well. While scientific research remains the principal objective behind these program, all hope to drive toward commercialization to sustain a long range infrastructure which .benefits the national technology and economy. In the 1997 International Space Station Commercialization Study, conducted by the Potomac Institute for Policy Studies, some viable microgravity commercial ventures were identified, however, none appeared sufficiently robust to privately fund space access at that time. Thus, government funded micro gravity research continues on an evolutionary path with revolutionary potential.

  18. Hybrid photon detectors

    CERN Document Server

    D'Ambrosio, C

    2003-01-01

    Hybrid photon detectors detect light via vacuum photocathodes and accelerate the emitted photoelectrons by an electric field towards inversely polarized silicon anodes, where they are absorbed, thus producing electron-hole pairs. These, in turn, are collected and generate electronic signals on their ohmic contacts. This review first describes the characteristic properties of the main components of hybrid photon detectors: light entrance windows, photocathodes, and silicon anodes. Then, essential relations describing the trajectories of photoelectrons in electric and magnetic fields and their backscattering from the silicon anodes are derived. Depending on their anode configurations, three families of hybrid photon detectors are presented: hybrid photomultiplier tubes with single anodes for photon counting with high sensitivity and for gamma spectroscopy; multi-anode photon detector tubes with anodes subdivided into square or hexagonal pads for position-sensitive photon detection; imaging silicon pixel array t...

  19. AMITIS: A 3D GPU-Based Hybrid-PIC Model for Space and Plasma Physics

    Science.gov (United States)

    Fatemi, Shahab; Poppe, Andrew R.; Delory, Gregory T.; Farrell, William M.

    2017-05-01

    We have developed, for the first time, an advanced modeling infrastructure in space simulations (AMITIS) with an embedded three-dimensional self-consistent grid-based hybrid model of plasma (kinetic ions and fluid electrons) that runs entirely on graphics processing units (GPUs). The model uses NVIDIA GPUs and their associated parallel computing platform, CUDA, developed for general purpose processing on GPUs. The model uses a single CPU-GPU pair, where the CPU transfers data between the system and GPU memory, executes CUDA kernels, and writes simulation outputs on the disk. All computations, including moving particles, calculating macroscopic properties of particles on a grid, and solving hybrid model equations are processed on a single GPU. We explain various computing kernels within AMITIS and compare their performance with an already existing well-tested hybrid model of plasma that runs in parallel using multi-CPU platforms. We show that AMITIS runs ∼10 times faster than the parallel CPU-based hybrid model. We also introduce an implicit solver for computation of Faraday’s Equation, resulting in an explicit-implicit scheme for the hybrid model equation. We show that the proposed scheme is stable and accurate. We examine the AMITIS energy conservation and show that the energy is conserved with an error < 0.2% after 500,000 timesteps, even when a very low number of particles per cell is used.

  20. Product Platform Performance

    DEFF Research Database (Denmark)

    Munk, Lone

    engaging in platform-based product development. Similarly platform assessment criteria lack empirical verification regarding relevance and sufficiency. The thesis focuses on • the process of identifying and estimating internal effects, • verification of performance of product platforms, (i...... to support this understanding. Finally a categorisation of different approaches to platform-based product development is introduced, based on the companies from the industrial study.......The aim of this research is to improve understanding of platform-based product development by studying platform performance in relation to internal effects in companies. Platform-based product development makes it possible to deliver product variety and at the same time reduce the needed resources...