WorldWideScience

Sample records for household dust metal

  1. Household dust metal levels in The Sao Paulo metropolitan area

    Energy Technology Data Exchange (ETDEWEB)

    Scapin, Valdirene O.; Scapin, Marcos A.; Sato, Ivone M. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil)

    2007-07-01

    A study about household dust is being conducted to determine the level of metal contamination in the Sao Paulo Metropolitan Area (SPMA). The SPMA, with 18 million inhabitants, is one of the largest urban areas of the world, with serious environmental problems, due to the great amount of industries, heavy traffic and the disordered growth of population. The pollutants originate from a multiplicity of indoor and outdoor sources. Indoor sources are originated from residual (hair, skin scales), pets, human activities, construction materials, and furnishings as well as biological material (pollen, insect parts).and outdoor pollution, usually from the urban traffic. The pollutant mixture involved in numerous physical and chemical processes and changes its characteristics with time. Its composition and concentration depend on the strengths of indoor sources, the concentration of pollutants outside and the properties of ventilation and air-conditioning systems. It is well recognized that many metals have chronic effects on humans, in particular toddlers, who are at an higher risk compared to adults because they engage in greater hand to-mouth activity and their neurological systems are still developing. The household dust samples were collected from different localities, using vacuum cleaner, and sieved up to particle size <63 {mu}m, which were then analyzed for 7 elements by X-ray fluorescence technique. The fundamental parameters method (FP) was applied and the simple pressed powder technique for sample preparation was used. The concentrations preliminary results of metals in the household dust were Cr, 18-188 {mu}g g{sup -1}; Mn, 119-369 {mu}g g{sup -1}; Fe, 372-1464 {mu}g g{sup -1}; Ni, 33-85 {mu}g g{sup -1}; Cu, 42-303 {mu}g g{sup -1}; Zn, 156-1369 {mu}g g{sup -1} and Pb, 26-160 {mu}g g{sup -1}. (author)

  2. Mechanisms of metal dusting corrosion

    DEFF Research Database (Denmark)

    Hummelshøj, Thomas Strabo

    In this thesis the early stages of metal dusting corrosion is addressed; the development of carbon expanded austenite, C, and the decomposition hereof into carbides. Later stages of metal dusting corrosion are explored by a systematic study of stainless steel foils exposed to metal dusting...... influence of oxygen and carbon on the metal dusting corrosion is explored. The results indicate that exposure to metal dusting conditions have a detrimental effect on the resistance against oxidation and, conversely, that exposure to oxidation has a detrimental effect on the resistance towards metal dusting....... Consequently, a combination of carburizing and oxidizing conditions has a strong mutual catalyzing effect on the metal dusting corrosion....

  3. A study on heavy metals in household dusts in 3 cities in Southwestern China%我国西南三市家庭灰尘重金属水平及差异

    Institute of Scientific and Technical Information of China (English)

    李晓燕; 谢馨洁

    2013-01-01

    以西南3个省会城市(直辖市)贵阳、南宁和重庆为研究对象,研究城市家庭灰尘中Ca、Fe、Cd、Cr、Cu、Ni、Pb和Zn的含量及累积状况.结果显示3个城市的家庭灰尘中Ca、Fe含量的空间变异度较小,其他元素空间变异度较大.贵阳与重庆家庭灰尘重金属水平较为接近,南宁相对略低.贵阳市家庭灰尘中Ca(10.1%)含量高于南宁市,Cd(1.18mg/kg)、Cu(207mg/kg)、Ni(87.3mg/kg)和Pb(259mg/kg)含量均高于重庆市和南宁市,其中贵阳市家庭灰尘中Ca、Cd和Cu含量显著高于南宁市.与3城市土壤重金属背景值相比,6种有毒重金属中,Zn、Pb和Cd在家庭灰尘中累积相对较重;3城市中,南宁市家庭灰尘重金属累积相对较重;贵阳、南宁和重庆家庭灰尘重金属累积较重的元素分别是Zn和Pb、Zn和Pb、Cd和Zn.%Previous studies on dust heavy metals are focused on outdoors with little concerning indoors in China. Samples of household dusts were collected from 3 cities including Guiyang, Nanning and Chongqing in Southwestern China, and the level and accumulation characteristics of Ca, Fe, Cd, Cr, Cu, Ni, Pb and Zn were analyzed and discussed. The results show that heavy metal levels of household dusts in Guiyang and Chongqing are nearly equivalent and relatively higher than that in Nanning. Concentrations of Cd(1.18 mg/kg), Cu(207 mg/kg), Ni(87.3 mg/kg)and Pb(259 mg/kg)in Guiyang are higher than those in Chongqing and Nanning, and concentrations of Ca, Cd and Cu in household dusts in Guiyang are significantly higher than those in Nanning. Compared with background levels of 6 studied toxic elements in soils, Zn, Pb and Cd accumulations in household dusts are serious and Nanning is the most serous city in the three investigated cities. Two sever accumulated heavy metals in household dusts in Guiyang, Nanning and Chongqing are Zn and Pb, Zn and Pb, and Cd and Zn, respectively.

  4. Chemical Associations of Lead, Cadmium, Chromium, Nickel and Zinc in Household Dust of Kathmandu Metropolitan Area

    Directory of Open Access Journals (Sweden)

    Pawan Raj Shakya

    2013-06-01

    Full Text Available Dust samples were collected from roadside houses of seven major locations in Kathmandu metropolitan area and trace element compositions was determined by atomic absorption spectrophotometer (AAS. Results show significant concentrations of Zn, Pb, Ni, Cr and Cd in the test household dusts as compared to the undisturbed (control area. The mean concentrations of all the studied locations were found to be 76.2 mg/kg for Zn, 40.6 mg/kg for Pb, 29.9 mg/kg for Cr, 23.9 mg/kg for Ni and 8.2 mg/kg for Cd, respectively. Increase in these trace metals in the dust can most likely be attributed to rapid urbanization, increased vehicle emissions to the atmosphere and other anthropogenic sources. Elevated Zn abundance in household dust probably originates from traffic sources. Besides, enrichment factor reveals that the household dust was most severely affected by Cd in almost all the locations. Also, correlations between metal levels in dust samples for all the metals were investigated.

  5. Polycyclic aromatic hydrocarbons in household dust near diesel transport routes.

    Science.gov (United States)

    Kuo, Chung-Yih; Chen, Heng-Chun; Cheng, Fang-Ching; Huang, Li-Ru; Chien, Po-Shan; Wang, Jing-Ya

    2012-02-01

    A river-dredging project has been undertaken in Nantou, Taiwan. A large number of diesel vehicles carrying gravel and sand shuttle back and forth on the main roads. Ten stations along major thoroughfares were selected as the exposure sites for testing, while a small village located about 9 km from a main traffic route was selected as the control site. Levels of household dust loading at the exposure sites (60.3 mg/m(2)) were significantly higher than those at the control site (38.2 mg/m(2)). The loading (μg/m(2)) of t-PAHs (total polycyclic aromatic hydrocarbons) in the household dust at the exposure sites was significantly higher (P < 0.05) than was the case at the control site. The diagnostic ratios of PAHs showed that diesel emissions were the dominant source of PAHs at the exposure sites. The lack of a significant correlation between the concentrations of Fe and t-PAHs suggested that the t-PAHs in household dust might come from diverse sources. However, a significant correlation (P = 0.003) between the concentrations of Mo and t-PAHs implied that the most of the t-PAHs in the household dust might have resulted from diesel emissions. The lifetime cancer risks of BaP(eq) from household dust exposure were markedly higher than those resulting from inhalation exposure.

  6. Metal Dusting-Mechanisms and Preventions

    Institute of Scientific and Technical Information of China (English)

    J.Q.ZHANG; D.J.YOUNG

    2009-01-01

    Metal dusting attacks iron, low and high alloy steels and nickel-or cobalt-base alloys by disintegrating bulk metals and alloys into metal particles in a coke deposit. It occurs in strongly carburising gas atmospheres (carbon activity aC>1) at elevated temperatures (400℃~1000℃). This phenomenon has been studied for decades, but the detailed mechanism is still not well understood. Current methods of protection against metal dusting are either directed to the process conditions-temperature and gas composition-or to the development of a dense adherent oxide layer on the surface of the alloy by selective oxidation. However, metal dusting still occurs by carbon dissolving in the base metal via defects in the oxide scale. The research work at UNSW is aimed at determining the detailed mechanism of metal dusting of both ferritic and austenitic alloys, in particular the microprocesses of graphite deposition, nanoparticle formation and underlying metal destruction. This work was carried out using surface observation, cross-section analysis by focused ion beam and electron microscopic examination of coke deposits at different stages of the reaction. It was found that surface orientation affected carbon deposition and metal dusting at the initial stage of the reaction. Metal dusting occurred only when graphite grew into the metal interior where the volume expansion is responsible for metal disintegration and dusting. It was also found that the metal dusting process could be significantly changed by alterations in alloy chemistry. Germanium was found to affect the iron dusting process by destabilising FeC but increasing the rate of carbon deposition and dusting, which questions the role of cementite in ferritic alloy dusting. Whilst adding copper to iron did not change the carburisation kinetics, cementite formation and coke morphology, copper alloying reduced nickel and nickel-base alloy dusting rates significantly. Application of these fundamental results to the dusting

  7. Home sweet home? A case study of household dust contamination in Hong Kong.

    Science.gov (United States)

    Tong, S T; Lam, K C

    2000-07-10

    It is well recognized that many heavy metals have chronic effects on humans and as such, they are potential environmental health hazards, particularly to young children (see, for example, Body P, Inglis G, Dolan P, Mulcahy D. Environmental lead: a review. Crit Rev Environ Control 1991;20:299-310). Considerable attention has been paid to the study of metal pollution in city air, roadside dusts and soils. However, there is a lack of concern of the presence of trace metals in house dust in the populous city of Hong Kong, where it has traditionally been assumed that such pollutants are rapidly dispersed by ocean breezes. This research aims at quantifying the concentrations of heavy metals within the home environment in Hong Kong and their relationships with environmental factors. The results of this study seem to suggest that traffic and the age of the building and neighborhood are more important factors than the types of industry and socioeconomic status in affecting household dust contamination. The metal burdens in Kwung Tong, an old area with heavy traffic, are significantly higher than other districts. When a Kruskal-Wallis one-way analysis of variance was performed on the ranked metal concentrations in different housing districts, the Chi-square values are all significant at a probability level of contaminating industries (such as metal smelters, battery plants and petrochemicals) in Hong Kong. The dust metals may travel from the roads, through the windows and balconies, into the houses, as those homes that do not have their windows opened often had a lower level of contaminants in their house dust (median Cd= 3.6 microg/g; median Cu = 313.2 microg/g; median Pb = 144.6 microg/g; median Mn = 211.6 microg/g; and median Zn = 1,333.7 microg/g). Moreover, those occupants who sweep their floors or dust their furniture on daily bases, or use vacuum cleaners, had a lower level of metals inside their houses. Another finding of interest is that the color of the wall paint

  8. The ecology of microscopic life in household dust

    National Research Council Canada - National Science Library

    Barberán, Albert; Dunn, Robert R; Reich, Brian J; Pacifici, Krishna; Laber, Eric B; Menninger, Holly L; Morton, James M; Henley, Jessica B; Leff, Jonathan W; Miller, Shelly L; Fierer, Noah

    2015-01-01

    .... Here, we investigated the fungal and bacterial communities found in settled dust collected from inside and outside approximately 1200 homes located across the continental US, homes that represent...

  9. Virginia Household Water Quality Program: Heavy Metals in Household Water

    OpenAIRE

    Ling, Erin; Benham, Brian Leslie, 1960-; Forrester, Scott

    2011-01-01

    Federal law requires public water utilities to provide biologically safe water. However, the safety of privately owned, individual water supplies such as wells, springs, and cisterns is the sole responsibility of the owner. This publication discusses the sources, testing, and treatment of heavy metals.

  10. Magnetic signature of indoor air pollution: Household dust study

    National Research Council Canada - National Science Library

    Górka-Kostrubiec, Beata; Jeleńska, Maria; Król, Elżbieta

    2014-01-01

    The combination of magnetic and geochemical methods was used to determine the mineralogy, grain size and domain structure of magnetic particles in indoor dust collected in 195 sites in Warsaw, Poland...

  11. Comparison of Gastric versus Gastrointestinal PBET Extractions for Estimating Oral Bioaccessibility of Metals in House Dust.

    Science.gov (United States)

    Boros, Kristina; Fortin, Danielle; Jayawardene, Innocent; Chénier, Marc; Levesque, Christine; Rasmussen, Pat E

    2017-01-18

    Oral bioaccessibility estimates for six metals which are prevalent as contaminants in Canada (zinc, lead, cadmium, copper, nickel, and chromium) are investigated for house dust using the simple gastric phase versus the two-phase physiologically-based extraction technique (PBET). The purpose is to determine whether a complete gastrointestinal (GI) assay yields a more conservative (i.e., higher) estimate of metal bioaccessibility in house dust than the gastric phase alone (G-alone). The study samples include household vacuum dust collected from 33 homes in Montreal, Canada, plus four certified reference materials (NIST 2583, NIST 2584, NIST 2710 and NIST 2710a). Results indicate that percent bioaccessibilities obtained using G-alone are generally greater than or equivalent to those obtained using the complete GI simulation for the six studied metals in house dust. Median bioaccessibilities for G-alone/GI in household vacuum dust samples (n = 33) are 76.9%/19.5% for zinc, 50.4%/6.2% for lead, 70.0%/22.4% for cadmium, 33.9%/30.5% for copper and 28.5%/20.7% for nickel. Bioaccessible chromium is above the detection limit in only four out of 33 samples, for which G-alone results are not significantly different from GI results (p = 0.39). It is concluded that, for the six studied metals, a simple G-alone extraction provides a conservative and cost-effective approach for estimating oral bioaccessibility of metals in house dust.

  12. Comparison of Gastric versus Gastrointestinal PBET Extractions for Estimating Oral Bioaccessibility of Metals in House Dust

    Science.gov (United States)

    Boros, Kristina; Fortin, Danielle; Jayawardene, Innocent; Chénier, Marc; Levesque, Christine; Rasmussen, Pat E.

    2017-01-01

    Oral bioaccessibility estimates for six metals which are prevalent as contaminants in Canada (zinc, lead, cadmium, copper, nickel, and chromium) are investigated for house dust using the simple gastric phase versus the two-phase physiologically-based extraction technique (PBET). The purpose is to determine whether a complete gastrointestinal (GI) assay yields a more conservative (i.e., higher) estimate of metal bioaccessibility in house dust than the gastric phase alone (G-alone). The study samples include household vacuum dust collected from 33 homes in Montreal, Canada, plus four certified reference materials (NIST 2583, NIST 2584, NIST 2710 and NIST 2710a). Results indicate that percent bioaccessibilities obtained using G-alone are generally greater than or equivalent to those obtained using the complete GI simulation for the six studied metals in house dust. Median bioaccessibilities for G-alone/GI in household vacuum dust samples (n = 33) are 76.9%/19.5% for zinc, 50.4%/6.2% for lead, 70.0%/22.4% for cadmium, 33.9%/30.5% for copper and 28.5%/20.7% for nickel. Bioaccessible chromium is above the detection limit in only four out of 33 samples, for which G-alone results are not significantly different from GI results (p = 0.39). It is concluded that, for the six studied metals, a simple G-alone extraction provides a conservative and cost-effective approach for estimating oral bioaccessibility of metals in house dust.

  13. Comparison of Gastric versus Gastrointestinal PBET Extractions for Estimating Oral Bioaccessibility of Metals in House Dust

    Directory of Open Access Journals (Sweden)

    Kristina Boros

    2017-01-01

    Full Text Available Oral bioaccessibility estimates for six metals which are prevalent as contaminants in Canada (zinc, lead, cadmium, copper, nickel, and chromium are investigated for house dust using the simple gastric phase versus the two-phase physiologically-based extraction technique (PBET. The purpose is to determine whether a complete gastrointestinal (GI assay yields a more conservative (i.e., higher estimate of metal bioaccessibility in house dust than the gastric phase alone (G-alone. The study samples include household vacuum dust collected from 33 homes in Montreal, Canada, plus four certified reference materials (NIST 2583, NIST 2584, NIST 2710 and NIST 2710a. Results indicate that percent bioaccessibilities obtained using G-alone are generally greater than or equivalent to those obtained using the complete GI simulation for the six studied metals in house dust. Median bioaccessibilities for G-alone/GI in household vacuum dust samples (n = 33 are 76.9%/19.5% for zinc, 50.4%/6.2% for lead, 70.0%/22.4% for cadmium, 33.9%/30.5% for copper and 28.5%/20.7% for nickel. Bioaccessible chromium is above the detection limit in only four out of 33 samples, for which G-alone results are not significantly different from GI results (p = 0.39. It is concluded that, for the six studied metals, a simple G-alone extraction provides a conservative and cost-effective approach for estimating oral bioaccessibility of metals in house dust.

  14. Dissolution of heavy metals from electrostatic precipitator (ESP) dust ...

    African Journals Online (AJOL)

    SIBOO

    precipitator (ESP) dust of a coal based sponge iron plant by fungal leaching ... Microbial leaching is based on the natural ... sponge iron plant ESP dust using three different fungal ..... Fungal bioleaching of metals in preservative treated wood.

  15. Association of pediatric asthma severity with exposure to common household dust allergens

    Energy Technology Data Exchange (ETDEWEB)

    Gent, Janneane F., E-mail: janneane.gent@yale.edu [Yale Center for Perinatal, Pediatric and Environmental Epidemiology, Department of Epidemiology and Public Health, Yale University School of Medicine, One Church Street, 6th Floor, New Haven, CT 06510 (United States); Belanger, Kathleen [Yale Center for Perinatal, Pediatric and Environmental Epidemiology, Department of Epidemiology and Public Health, Yale University School of Medicine, One Church Street, 6th Floor, New Haven, CT 06510 (United States); Triche, Elizabeth W. [Brown University, Department of Community Health/Epidemiology, Providence, RI (United States); Bracken, Michael B. [Yale Center for Perinatal, Pediatric and Environmental Epidemiology, Department of Epidemiology and Public Health, Yale University School of Medicine, One Church Street, 6th Floor, New Haven, CT 06510 (United States); Beckett, William S. [Mount Auburn Hospital, Department of Internal Medicine, Cambridge, MA (United States); Leaderer, Brian P. [Yale Center for Perinatal, Pediatric and Environmental Epidemiology, Department of Epidemiology and Public Health, Yale University School of Medicine, One Church Street, 6th Floor, New Haven, CT 06510 (United States)

    2009-08-15

    Background: Reducing exposure to household dust inhalant allergens has been proposed as one strategy to reduce asthma. Objective: To examine the dose-response relationships and health impact of five common household dust allergens on disease severity, quantified using both symptom frequency and medication use, in atopic and non-atopic asthmatic children. Methods: Asthmatic children (N=300) aged 4-12 years were followed for 1 year. Household dust samples from two indoor locations were analyzed for allergens including dust mite (Der p 1, Der f 1), cat (Fel d 1), dog (Can f 1), cockroach (Bla g 1). Daily symptoms and medication use were collected in monthly telephone interviews. Annual disease severity was examined in models including allergens, specific IgE sensitivity and adjusted for age, gender, atopy, ethnicity, and mother's education. Results: Der p 1 house dust mite allergen concentration of 2.0 {mu}g/g or more from the main room and the child's bed was related to increased asthma severity independent of allergic status (respectively, OR 2.93, 95% CI 1.37, 6.30 for 2.0-10.0 {mu}g/g and OR 2.55 95% CI 1.13, 5.73 for {>=}10.0 {mu}g/g). Higher pet allergen levels were associated with greater asthma severity, but only for those sensitized (cat OR 2.41 95% CI 1.19, 4.89; dog OR 2.06 95% CI 1.01, 4.22). Conclusion: Higher levels of Der p 1 and pet allergens were associated with asthma severity, but Der p 1 remained an independent risk factor after accounting for pet allergens and regardless of Der p 1 specific IgE status.

  16. Factors of influence on body lead and cadmium levels in regions of Saxony Anhalt with different pollution levels, with special consideration to heavy metal uptake via household dust; Einflussfaktoren auf die innere Blei- und Cadmiumbelastung in unterschiedlich belasteten Regionen Sachsen-Anhalts unter besonderer Beruecksichtigung der Schwermetallaufnahme ueber den Hausstaub

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, I.

    2002-07-01

    The present study is based on data from an environmental medicine study aimed at identifying possible health impairments in the population of Hettstedt, a metallurgical industry site, as compared with those of the industrial region of Bitterfeld and Zerbst as control region. The present study was designed as a six-year longitudinal study and based on three regional cross-sectional studies performed in school years 1992/93, 1995/96 and 1998/99. In all three of these surveys the study population was recruited from children just entering school (5 to 7 years), 3rd form (8 to 10 years) and 6th form school children. The study population of the first survey also included women aged 50 to 59. The goal of the present study was to identify predictors of lead and cadmium deposition in households of children from Hettstedt and women from Hettstedt, Bitterfeld and Zerbst. Furthermore, the extent to which body lead and cadmium levels are influenced by the deposition of these heavy metals in household dust and the possibility of a change in children's lead and cadmium body levels between 1992/93 and 1998/99 were explored. Body lead levels were measured in terms of blood lead levels, which reflect the exposure over the past few weeks. The most significant determinants of lead deposition in household dust was the proximity of the home to the metallurgical plants and factors reflecting the deposition of lead-containing dust in the home. Likewise, the main determinants of body lead levels were the proximity of the home to emitters and, in the case of children, the lead content of household dust associated with this and the whirling up of dust by pets. Boys were found to have markedly higher levels than girls. Whereas drinking lead-containing water and being in the garden had no demonstrable effect on body lead levels in children, in women these factors were found to play a significant role, along with smoking and the release of lead from the bones after the menopause. Body lead

  17. Organophosphate flame retardants in household dust before and after introduction of new furniture.

    Science.gov (United States)

    Keimowitz, A R; Strunsky, N; Wovkulich, K

    2016-04-01

    Flame retardant compounds originating from household items collect in household dust, a reasonable proxy for human exposure. Contributions of specific items or behaviors to dust are difficult to separate. This study examined standardized college housing before and after the introduction of new, flame retardant couches in order to explore any effect that changing upholstered furniture may have on flame retardant concentrations in dust. Two contradictory hypotheses were posited: (1) that new furniture might increase flame retardant releases immediately after introduction due to initial off-gassing of new materials or (2) that older furniture would release more flame retardants due to mechanical breakdown of polyurethane foam. This study was designed to determine which of these processes dominated. Prior to the introduction of new furniture, TDCIPP was detected in 12/20 samples at a median concentration of 22 μg/g and TCEP was detected in 1/20 samples at a concentration of 16 μg/g. TDCIPP and TCEP were not detected in any samples (N = 29) after the introduction of new couches. TPHP was detected both before (in 11/20 samples) and after (in 5/29 samples) introduction of new couches; the median concentrations before and after were 63 ± 49 and 16 ± 11 μg/g (standard deviation shown). Introduced couches contained TDCIPP (and not TPHP) at ∼1.25% (w/w). These data support the second hypothesis and indicate that removal of older furniture decreases TDCIPP and TCEP concentrations in dust and may potentially reduce total flame retardant concentrations in dust, at least immediately after introduction of the new furniture.

  18. Contributions of Paint and Soil to Pb in Household Dust Wipes: An XAS Study

    Science.gov (United States)

    Pingitore, N. E.; Clague, J. W.; Amaya, M. A.

    2010-12-01

    Speciation of Pb by X-ray absorption spectroscopy (XAS) indicated that Pb compounds associated with lead-based paint accounted for perhaps half of the Pb in 24 household dust wipes collected in El Paso, Texas. Soil-derived, sorbed Pb, likely Pb-humate, was also a major Pb species in many of the dust wipes. Household dust wipes are a standard technique for evaluating health risks of Pb to children, particularly toddlers, in public and private housing. The level of Pb in the wipes does not, however, indicate whether the source of the Pb is the house itself (peeling or powdering interior or exterior paint) or external, from contaminated soil or airborne particulate matter brought into the house by wind or foot traction. Understanding the origin of Pb in household dust is important in remediation: cover the old paint or remove the yard soil. XAS speciation can assist in understanding the source of Pb in household dust. The presence of significant Pb-humate requires a soil source, and suggests the need for soil remediation. Such species of Pb as hydrocerussite, lead sulfate, lead silicate, and lead chromate can be presumed to be components of lead-based paint. These may represent interior and/or exterior paint and thus do not uniquely identify the locus of the Pb source(s). Pb L-III edge XAFS data were collected on beam lines 7-3, 10-2, and 11-2 at SSRL at typical conditions of 3 GeV field and 80-200 mA current, using Si(220) water- or liquid-nitrogen-cooled monochromator crystals. Data were collected at ambient temperature in fluorescence mode using a 13- or 30-element Ge detector with a Se 3 or 6 filter and Soller slits to reduce scattered radiation. This publication was made possible by grant numbers 1RO1-ES11367 and 1 S11 ES013339-01A1 from the National Institute of Environmental Health Sciences (NIEHS), NIH. Its contents are solely the responsibility of the authors and do not necessarily represent the official views of the NIEHS, NIH. Portions of this research were

  19. IGM metal enrichment through dust sputtering

    CERN Document Server

    Bianchi, S; Bianchi, Simone; Ferrara, Andrea

    2005-01-01

    We study the motion of dust grains into the Intergalactic Medium (IGM) around redshift z=3, to test the hypothesis that grains can efficiently pollute the gas with metals through sputtering. We use the results available in the literature for radiation-driven dust ejection from galaxies as initial conditions, and follow the motion onward. Via this mechanism, grains are ejected into the IGM with velocities >100 km/s; as they move supersonically, grains can be efficiently eroded by non-thermal sputtering. However, Coulomb and collisional drag forces effectively reduce the charged grain velocity. Up-to-date sputtering yields for graphite and silicate (olivine) grains have been derived using the code TRIM, for which we provide analytic fits. After training our method on a homogeneous density case, we analyze the grain motion and sputtering in the IGM density field as derived from a LambdaCDM cosmological simulation at z = 3.27. We found that only large (a >~ 0.1-um) grains can travel up to considerable distances (...

  20. Durable Dust Repellent Coating for Metals Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The Durable Dust Repellent Coating (DDRC) consists of nano-phase silica, titania, or other oxide coatings to repel dust in a vacuum environment over a wide range of...

  1. World-Wide Indoor Exposure to Polyfluoroalkyl Phosphate Esters (PAPs) and other PFASs in Household Dust.

    Science.gov (United States)

    Eriksson, Ulrika; Kärrman, Anna

    2015-12-15

    Human exposure to perfluorooctanoic acid (PFOA) and other per- and polyfluoroalkyl substances (PFASs) is ongoing and in some cases increasing, despite efforts made to reduce emissions. The role of precursor compounds such as polyfluorinated phosphate esters (PAPs) has received increasing attention, but there are knowledge gaps regarding their occurrence and impact on human exposure. In this study, mono-, di-, and triPAPs, perfluorinated alkyl acids (PFAAs), saturated, and unsaturated fluorotelomer carboxylic acids (FTCA/FTUCAs), perfluoroalkane sulfonamides, and sulfonamidethanols (FOSA/FOSEs), and one fluorotelomer sulfonic acid (FTSA)) were compared in household dust samples from Canada, the Faroe Islands, Sweden, Greece, Spain, Nepal, Japan, and Australia. Mono-, di-, and triPAPs, including several diPAP homologues, were frequently detected in dust from all countries, revealing an ubiquitous spread in private households from diverse geographic areas, with significant differences between countries. The median levels of monoPAPs and diPAPs ranged from 3.7 ng/g to 1 023 ng/g and 3.6 ng/g to 692 ng/g, respectively, with the lowest levels found in Nepal and the highest in Japan. The levels of PAPs exceeded those of the other PFAS classes. These findings reveal the importance of PAPs as a source of PFAS exposure worldwide.

  2. Household vacuum cleaners vs. the high-volume surface sampler for collection of carpet dust samples in epidemiologic studies of children

    Directory of Open Access Journals (Sweden)

    Buffler Patricia A

    2008-02-01

    Full Text Available Abstract Background Levels of pesticides and other compounds in carpet dust can be useful indicators of exposure in epidemiologic studies, particularly for young children who are in frequent contact with carpets. The high-volume surface sampler (HVS3 is often used to collect dust samples in the room in which the child had spent the most time. This method can be expensive and cumbersome, and it has been suggested that an easier method would be to remove dust that had already been collected with the household vacuum cleaner. However, the household vacuum integrates exposures over multiple rooms, some of which are not relevant to the child's exposure, and differences in vacuuming equipment and practices could affect the chemical concentration data. Here, we compare levels of pesticides and other compounds in dust from household vacuums to that collected using the HVS3. Methods Both methods were used in 45 homes in California. HVS3 samples were collected in one room, while the household vacuum had typically been used throughout the home. The samples were analyzed for 64 organic compounds, including pesticides, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls (PCBs, using GC/MS in multiple ion monitoring mode; and for nine metals using conventional microwave-assisted acid digestion combined with ICP/MS. Results The methods agreed in detecting the presence of the compounds 77% to 100% of the time (median 95%. For compounds with less than 100% agreement, neither method was consistently more sensitive than the other. Median concentrations were similar for most analytes, and Spearman correlation coefficients were 0.60 or higher except for allethrin (0.15 and malathion (0.24, which were detected infrequently, and benzo(kfluoranthene (0.55, benzo(apyrene (0.55, PCB 105 (0.54, PCB 118 (0.54, and PCB 138 (0.58. Assuming that the HVS3 method is the "gold standard," the extent to which the household vacuum cleaner method yields relative risk

  3. The metals-to-dust ratio to very low metallicities using GRB and QSO absorbers; extremely rapid dust formation

    CERN Document Server

    Zafar, Tayyaba

    2013-01-01

    Among the key parameters defining the ISM of galaxies is the fraction of the metals that are locked up in dust: the metals-to-dust ratio. This ratio bears not only on the ISM and its evolution, but particularly on the origin of cosmic dust. We combine extinction and abundance data from GRB afterglows, from QSO absorbers, as well as from galaxy-lensed QSOs, to determine the metals-to-dust ratios for lines-of-sight through a wide diversity of galaxies from blue, dwarf starbursts to massive ellipticals, across a vast range in redshift z=0.1-6.3, and nearly three orders of magnitude in column density and metal abundance. We thus determine the metals-to-dust ratio in a unique way, providing direct determinations of in situ gas and dust columns without recourse to assumptions with large uncertainties. We find that the metals-to-dust ratios in these systems are surprisingly close to the value for the local group (10^{21.3} cm-2 A_V mag-1), with a mean value of 10^{21.2} cm-2 A_V mag-1 and a standard deviation of 0.3...

  4. Metals in dust fractions emitted at mechanical workstations.

    Science.gov (United States)

    Kondej, Dorota; Gawęda, Ewa

    2012-01-01

    Workers at metal machining workstations are exposed to airborne dust particles containing metals and their compounds. Their harmful impact on the workers' health depends on both their chemical composition and their distribution. The aim of this study was to determine the content of metals in dust fractions emitted in the process of mechanical machining of products made of brass, steel and cast iron. Samples taken during grinding, turning and drilling were tested. The concentration of metals in dust fractions was determined with atomic absorption spectrometry. The content of iron, manganese, chromium, zinc, lead, copper and nickel in the dust fractions was highly differentiated depending on the size of the particles, the material and the processes used.

  5. Development of materials resistant to metal dusting degradation.

    Energy Technology Data Exchange (ETDEWEB)

    Natesan, K.; Zeng, Z.

    2006-04-24

    Metal dusting corrosion has been a serious problem in the petroleum and petrochemical industries, such as reforming and syngas production systems. This form of deterioration has led to worldwide material loss for 50 years. For the past three years, we have studied the mechanism of metal dusting for Fe- and Ni-base alloys. In this report, we present a correlation between the weight loss and depth of pits that form in Ni-base alloys. Nickel-base alloys were also tested at 1 and 14.8 atm (210 psi), in a high carbon activity environment. Higher system pressure was found to accelerate corrosion in most Ni-base alloys. To reduce testing time, a pre-pitting method was developed. Mechanical scratches on the alloy surface led to fast metal dusting corrosion. We have also developed preliminary data on the performance of weldments of several Ni-base alloys in a metal dusting environment. Finally, Alloy 800 tubes and plates used in a reformer plant were examined by scanning electron microscopy, energy dispersive X-ray, and Raman spectroscopy. The oxide scale on the surface of the Alloy 800 primarily consists of Fe{sub 1+x}Cr{sub 2-X}O{sub 4} spinel phase with high Fe content. Carbon can diffuse through this oxide scale. It was discovered that the growth of metal dusting pits could be stopped by means of a slightly oxidized alloy surface. This leads to a new way to solve metal dusting problem.

  6. Development of materials resistant to metal dusting degradation.

    Energy Technology Data Exchange (ETDEWEB)

    Natesan, K.; Zeng, Z.; Nuclear Engineering Division

    2007-12-07

    The deposition of carbon from carbonaceous gaseous environments is prevalent in many chemical and petrochemical processes such as, hydrogen-, ammonia-, and methanol-reforming systems, syngas production systems, and iron-ore reduction plants. One of the major consequences of carbon deposition is the degradation of structural materials by a phenomenon known as ''metal dusting''. There are two major issues of importance in metal dusting. First is formation of coke and subsequent deposition of coke on metallic structural components. Second is the initiation and subsequent propagation of metal dusting degradation of the structural alloy. In the past, we reported on the mechanism for metal dusting of Fe- and Ni-base alloys. In this report, we present metal dusting data on both Fe- and Ni-base alloys after exposure in high and atmospheric pressure environments that simulate the gas chemistry in operating hydrogen reformers. We have also measured the progression of pits by measuring the depth as a function of exposure time for a variety of Fe- and Ni-base structural alloys. We have clearly established the role of transport of iron in forming a non-protective spinel phase in the initiation process and presence of carbon transfer channels in the oxide scale for the continued propagation of pits, by nano-beam X-ray analysis using the advance photon source (APS), Raman scattering, and SEM/EDX analysis. In this report, we have developed correlations between weight loss and pit progression rates and evaluated the effects of carbon activity, system pressure, and alloy chemistry, on weight loss and pit propagation. To develop pit propagation data for the alloys without incurring substantial time for the initiation of pits, especially for the Ni-base alloys that exhibit incubation times of thousands of hours, a pre-pitting method has been developed. The pre-pitted alloys exhibited pit propagation rates similar to those of materials tested without pre-pitting. We

  7. Lead isotopes and trace metals in dust at Yucca Mountain

    Science.gov (United States)

    Kwak, Loretta; Neymark, Leonid A.; Peterman, Zell E.

    2008-01-01

    Lead (Pb)-isotope compositions and trace-metal concentrations were determined for samples of dust collected from underground and surface locations at and near the proposed radioactive waste repository at Yucca Mountain, Nevada. Rare earth element concentrations in the dust samples from the underground tunnels are similar to those in wholerock samples of the repository host rocks (Miocene Tiva Canyon Tuff and Topopah Spring Tuff), supporting interpretation that the subsurface dust is mainly composed of rock comminuted during tunnel construction. Other trace metals (arsenic, cadmium, cobalt, chromium, copper, manganese, nickel, lead, antimony, thallium, and zinc) are variably enriched in the subsurface dust samples relative to the average concentrations in the host rocks. Average concentrations of arsenic and lead in dust samples, high concentrations of which can cause corrosion of waste canisters, have enrichment factors from 1.2 to 1.6 and are insignificant relative to the range of concentrations for these metals observed in the host rock samples. Most dust samples from surface sites also are enriched in many of these trace metals relative to average repository host rocks. At least some of these enrichments may be artifacts of sampling. Plotted on a 208Pb/206Pb-207Pb/206Pb graph, Pb-isotope compositions of dust samples from underground sites form a mixing line extending from host-rock Pb-isotope compositions towards compositions of many of the dust samples from surface sites; however, combined Pb concentration and isotope data indicate the presence of a Pbenriched component in the subsurface dust that is not derived from host rock or surface dust and may derive from anthropogenic materials introduced into the underground environment.

  8. Pesticides in house dust from urban and farmworker households in California: an observational measurement study

    Directory of Open Access Journals (Sweden)

    McKone Thomas E

    2011-03-01

    Full Text Available Abstract Background Studies report that residential use of pesticides in low-income homes is common because of poor housing conditions and pest infestations; however, exposure data on contemporary-use pesticides in low-income households is limited. We conducted a study in low-income homes from urban and agricultural communities to: characterize and compare house dust levels of agricultural and residential-use pesticides; evaluate the correlation of pesticide concentrations in samples collected several days apart; examine whether concentrations of pesticides phased-out for residential uses, but still used in agriculture (i.e., chlorpyrifos and diazinon have declined in homes in the agricultural community; and estimate resident children's pesticide exposures via inadvertent dust ingestion. Methods In 2006, we collected up to two dust samples 5-8 days apart from each of 13 urban homes in Oakland, California and 15 farmworker homes in Salinas, California, an agricultural community (54 samples total. We measured 22 insecticides including organophosphates (chlorpyrifos, diazinon, diazinon-oxon, malathion, methidathion, methyl parathion, phorate, and tetrachlorvinphos and pyrethroids (allethrin-two isomers, bifenthrin, cypermethrin-four isomers, deltamethrin, esfenvalerate, imiprothrin, permethrin-two isomers, prallethrin, and sumithrin, one phthalate herbicide (chlorthal-dimethyl, one dicarboximide fungicide (iprodione, and one pesticide synergist (piperonyl butoxide. Results More than half of the households reported applying pesticides indoors. Analytes frequently detected in both locations included chlorpyrifos, diazinon, permethrin, allethrin, cypermethrin, and piperonyl butoxide; no differences in concentrations or loadings were observed between locations for these analytes. Chlorthal-dimethyl was detected solely in farmworker homes, suggesting contamination due to regional agricultural use. Concentrations in samples collected 5-8 days apart in

  9. Evolution of Dust-to-Metal Ratio in Galaxies

    CERN Document Server

    Inoue, A K

    2003-01-01

    This paper investigates the evolution of the dust-to-metal ratio in galaxies based on a simple evolution model for the amount of metal and dust with infall. We take into account grain formation in stellar mass-loss gas, grain growth by the accretion of metallic atoms in a cold dense cloud, and grain destruction by SNe shocks. Especially, we propose that the accretion efficiency is independent of the star-formation history. This predicts various evolutionary tracks in the metallicity ($Z$)--dust-to-gas ratio ($\\cal D$) plane depending on the star-formation history. In this framework, the observed linear $Z$--$\\cal D$ relation of nearby spiral galaxies can be interpreted as a sequence of a constant galactic age. We emphasize that an observational study of the $Z$--$\\cal D$ relation of galaxies at $z\\sim 1$ is very useful to constrain the efficiencies of dust growth and destruction. We also suggest that the Lyman break galaxies at $z\\sim 3$ have a very low dust-to-metal ratio, typically $\\ltsim 0.1$. Although th...

  10. Simple Methods for Production of Nanoscale Metal Oxide Films from Household Sources

    Science.gov (United States)

    Campbell, Dean J.; Baliss, Michelle S.; Hinman, Jordan J.; Ziegenhorn, John W.; Andrews, Mark J.; Stevenson, Keith J.

    2013-01-01

    Production of thin metal oxide films was recently explored as part of an outreach program with a goal of producing nanoscale structures with household items. Household items coated with various metals or titanium compounds can be heated to produce colorful films with nanoscale thicknesses. As part of a materials chemistry laboratory experiment…

  11. Household mold and dust allergens: Exposure, sensitization and childhood asthma morbidity

    Energy Technology Data Exchange (ETDEWEB)

    Gent, Janneane F., E-mail: janneane.gent@yale.edu [Yale Center for Perinatal, Pediatric and Environmental Epidemiology, Department of Epidemiology and Public Health, Yale University School of Medicine, One Church Street, 6th Floor, New Haven, CT 06510 (United States); Kezik, Julie M., E-mail: julie.colburn@yale.edu [Yale Center for Perinatal, Pediatric and Environmental Epidemiology, Department of Epidemiology and Public Health, Yale University School of Medicine, One Church Street, 6th Floor, New Haven, CT 06510 (United States); Hill, Melissa E., E-mail: melissa.hill@yale.edu [Yale Center for Perinatal, Pediatric and Environmental Epidemiology, Department of Epidemiology and Public Health, Yale University School of Medicine, One Church Street, 6th Floor, New Haven, CT 06510 (United States); Tsai, Eling, E-mail: tsai.umiami@gmail.com [Yale Center for Perinatal, Pediatric and Environmental Epidemiology, Department of Epidemiology and Public Health, Yale University School of Medicine, One Church Street, 6th Floor, New Haven, CT 06510 (United States); Li, De-Wei, E-mail: DeWei.Li@ct.gov [Connecticut Agricultural Experiment Station, Valley Laboratory, 153 Cook Hill Road, Windsor, CT 06095 (United States); Leaderer, Brian P., E-mail: brian.leaderer@yale.edu [Yale Center for Perinatal, Pediatric and Environmental Epidemiology, Department of Epidemiology and Public Health, Yale University School of Medicine, One Church Street, 6th Floor, New Haven, CT 06510 (United States)

    2012-10-15

    Background: Few studies address concurrent exposures to common household allergens, specific allergen sensitization and childhood asthma morbidity. Objective: To identify levels of allergen exposures that trigger asthma exacerbations in sensitized individuals. Methods: We sampled homes for common indoor allergens (fungi, dust mites (Der p 1, Der f 1), cat (Fel d 1), dog (Can f 1) and cockroach (Bla g 1)) for levels associated with respiratory responses among school-aged children with asthma (N=1233) in a month-long study. Blood samples for allergy testing and samples of airborne fungi and settled dust were collected at enrollment. Symptoms and medication use were recorded on calendars. Combined effects of specific allergen sensitization and level of exposure on wheeze, persistent cough, rescue medication use and a 5-level asthma severity score were examined using ordered logistic regression. Results: Children sensitized and exposed to any Penicillium experienced increased risk of wheeze (odds ratio [OR] 2.12 95% confidence interval [CI] 1.12, 4.04), persistent cough (OR 2.01 95% CI 1.05, 3.85) and higher asthma severity score (OR 1.99 95% CI 1.06, 3.72) compared to those not sensitized or sensitized but unexposed. Children sensitized and exposed to pet allergen were at significantly increased risk of wheeze (by 39% and 53% for Fel d 1>0.12 {mu}g/g and Can f 1>1.2 {mu}g/g, respectively). Increased rescue medication use was significantly associated with sensitization and exposure to Der p 1>0.10 {mu}g/g (by 47%) and Fel d 1>0.12 {mu}g/g (by 32%). Conclusion: Asthmatic children sensitized and exposed to low levels of common household allergens Penicillium, Der p 1, Fel d 1 and Can f 1 are at significant risk for increased morbidity. - Highlights: Black-Right-Pointing-Pointer Few studies address concurrent allergen exposures, sensitization and asthma morbidity. Black-Right-Pointing-Pointer Children with asthma were tested for sensitivity to common indoor allergens

  12. Metal content in street dust as a reflection of atmospheric dust emissions from coal power plants, metal smelters, and traffic.

    Science.gov (United States)

    Žibret, Gorazd; Van Tonder, Danel; Žibret, Lea

    2013-07-01

    Resuspended street dust is a source of inhalable particles in urban environments. Despite contaminated street dust being a possible health risk factor for local population, little is known about the contribution of atmospheric dust emissions and other factors to the content of toxic metals in street dust. The impact of smelting, traffic, and power plants on metal contaminates in street dust is the focus of street dust sampling at 46 locations in the Witbank area (Republic of South Africa). This area is characterized by numerous open-pit coal mines in the Karoo coal basin, which provides a cheap source of energy to numerous metallurgical smelters and ironworks and supplies coal to the coal-fired power plants located nearby. Street dust was collected on asphalt or concrete surfaces with hard plastic brushes, avoiding collecting of possible sand, soil, or plant particles. Chemical analysis was done on the traffic which contributes to the high concentrations of Cu, Pb, Sb, and Sn, with the highest impacts detected in the town of Witbank. The second source is associated with the metal smelting industry, contributing to Fe, Co, Mn, and V emissions. The highest factor scores were observed around four metallurgical smelter operations, located in the Ferrobank, Highveld, and Clewer industrial areas. Impact of vanadium smelter to street dust composition could still be detected some 20 km away from the sources. Exceptionally high concentrations of Cr were observed in four samples collected next to the Ferrobank industrial area, despite Cr not being loaded in factor 2. The last source of the pollution is most probably fly ash associated with the coal-fired power plants and fly ash dumps. Elements which are associated with this source are Al, Sr, and Li. This factor is abundant in the coal mining part of the study area.

  13. Short-term variability of mineral dust, metals and carbon emission from road dust resuspension

    NARCIS (Netherlands)

    Amato, F.; Schaap, M.; Denier van der Gon, H.A.C.; Pandolfi, M.; Alastuey, A.; Keuken, M.; Querol, X.

    2013-01-01

    Particulate matter (PM) pollution in cities has severe impact on morbidity and mortality of their population. In these cities, road dust resuspension contributes largely to PM and airborne heavy metals concentrations. However, the short-term variation of emission through resuspension is not well

  14. Short-term variability of mineral dust, metals and carbon emission from road dust resuspension

    NARCIS (Netherlands)

    Amato, F.; Schaap, M.; Denier van der Gon, H.A.C.; Pandolfi, M.; Alastuey, A.; Keuken, M.; Querol, X.

    2013-01-01

    Particulate matter (PM) pollution in cities has severe impact on morbidity and mortality of their population. In these cities, road dust resuspension contributes largely to PM and airborne heavy metals concentrations. However, the short-term variation of emission through resuspension is not well des

  15. Comparison of Metal Dusting Behavior of Several Alloys

    Institute of Scientific and Technical Information of China (English)

    HAN Guang-wei; DENG Bo; FENG Di

    2004-01-01

    Metal dusting behaviors of several alloys with different chromium contents and other elements were investigated in a given gaseous environment. The samples of the alloys were exposed at 650 ℃ for 650 h, and were periodically removed to examine coke protrusions and pits formed on the sample surfaces by SEM and determine metal wastage. The results were interpreted in terms of the compositional variations of the employed alloys.

  16. Interaction of adhered metallic dust with transient plasma heat loads

    NARCIS (Netherlands)

    Ratynskaia, S.; Tolias, P.; I. Bykov,; Rudakov, D.; de Angeli, M.; Vignitchouk, L.; Ripamonti, D.; Riva, G.; Bardin, S.; van der Meiden, H.; Vernimmen, J.; Bystrov, K.; De Temmerman, G.

    2016-01-01

    The first study of the interaction of metallic dust (tungsten, aluminum) adhered on tungsten substrates with transient plasma heat loads is presented. Experiments were carried out in the Pilot-PSI linear device with transient heat fluxes up to 550 MW m −2 and in the DIII-D divertor tokamak. The cent

  17. The rarity of dust in metal-poor galaxies.

    Science.gov (United States)

    Fisher, David B; Bolatto, Alberto D; Herrera-Camus, Rodrigo; Draine, Bruce T; Donaldson, Jessica; Walter, Fabian; Sandstrom, Karin M; Leroy, Adam K; Cannon, John; Gordon, Karl

    2014-01-09

    Galaxies observed at redshift z > 6, when the Universe was less than a billion years old, thus far very rarely show evidence of the cold dust that accompanies star formation in the local Universe, where the dust-to-gas mass ratio is around one per cent. A prototypical example is the galaxy Himiko (z = 6.6), which--a mere 840 million years after the Big Bang--is forming stars at a rate of 30-100 solar masses per year, yielding a mass assembly time of about 150 × 10(6) years. Himiko is thought to have a low fraction (2-3 per cent of the Sun's) of elements heavier than helium (low metallicity), and although its gas mass cannot yet be determined its dust-to-stellar mass ratio is constrained to be less than 0.05 per cent. The local dwarf galaxy I Zwicky 18, which has a metallicity about 4 per cent that of the Sun's and is forming stars less rapidly (assembly time about 1.6 × 10(9) years) than Himiko but still vigorously for its mass, is also very dust deficient and is perhaps one of the best analogues of primitive galaxies accessible to detailed study. Here we report observations of dust emission from I Zw 18, from which we determine its dust mass to be 450-1,800 solar masses, yielding a dust-to-stellar mass ratio of about 10(-6) to 10(-5) and a dust-to-gas mass ratio of 3.2-13 × 10(-6). If I Zw 18 is a reasonable analogue of Himiko, then Himiko's dust mass must be around 50,000 solar masses, a factor of 100 below the current upper limit. These numbers are quite uncertain, but if most high-z galaxies are more like Himiko than like the very-high-dust-mass galaxy SDSS J114816.64 + 525150.3 at z ≈ 6, which hosts a quasar, then our prospects for detecting the gas and dust inside such galaxies are much poorer than hitherto anticipated.

  18. Survey of metals on antimicrobial and deodorant agents in household Necessities; Mukikei kokinsei kakoseihin no shiyojittai

    Energy Technology Data Exchange (ETDEWEB)

    Kan, Teruo

    1999-11-01

    It measured the metal bearing quantity in household necessities in order to clarify use actual condition of the metal system drug. And, it tried the detection of the drug used from detected metal. Too there is the report until now in the investigation of the metallic element in household necessities. However, metals examined this time are silver and zinc, four of copper and aluminum that it says that it has the antimicrobial action and is Key element of inorganic system antimicrobial agent. And, it carried out the analysis by inductive coupling plasma emission analysis method, after the wet digestion of the sample was done. (NEDO)

  19. Carbon formation and metal dusting in advanced coal gasification processes

    Energy Technology Data Exchange (ETDEWEB)

    DeVan, J.H.; Tortorelli, P.F.; Judkins, R.R.; Wright, I.G.

    1997-02-01

    The product gases generated by coal gasification systems contain high concentrations of CO and, characteristically, have relatively high carbon activities. Accordingly, carbon deposition and metal dusting can potentially degrade the operation of such gasifier systems. Therefore, the product gas compositions of eight representative gasifier systems were examined with respect to the carbon activity of the gases at temperatures ranging from 480 to 1,090 C. Phase stability calculations indicated that Fe{sub 3}C is stable only under very limited thermodynamic conditions and with certain kinetic assumptions and that FeO and Fe{sub 0.877}S tend to form instead of the carbide. As formation of Fe{sub 3}C is a necessary step in the metal dusting of steels, there are numerous gasifier environments where this type of carbon-related degradation will not occur, particularly under conditions associated with higher oxygen and sulfur activities. These calculations also indicated that the removal of H{sub 2}S by a hot-gas cleanup system may have less effect on the formation of Fe{sub 3}C in air-blown gasifier environments, where the iron oxide phase can exist and is unaffected by the removal of sulfur, than in oxygen-blown systems, where iron sulfide provides the only potential barrier to Fe{sub 3}C formation. Use of carbon- and/or low-alloy steels dictates that the process gas composition be such that Fe{sub 3}C cannot form if the potential for metal dusting is to be eliminated. Alternatively, process modifications could include the reintroduction of hydrogen sulfide, cooling the gas to perhaps as low as 400 C and/or steam injection. If higher-alloy steels are used, a hydrogen sulfide-free gas may be processed without concern about carbon deposition and metal dusting.

  20. Spatially resolved dust emission of extremely metal poor galaxies

    CERN Document Server

    Zhou, Luwenjia; Diaz-Santos, Taino; Armus, Lee; Helou, George; Stierwalt, Sabrina; Li, Aigen

    2016-01-01

    We present infrared (IR) spectral energy distributions (SEDs) of individual star-forming regions in four extremely metal poor (EMP) galaxies with metallicity Z around Zsun/10 as observed by the Herschel Space Observatory. With the good wavelength coverage of the SED, it is found that these EMP star-forming regions show distinct SED shapes as compared to those of grand design Spirals and higher metallicity dwarfs: they have on average much higher f70um/f160um ratios at a given f160um/f250um ratio; single modified black-body (MBB) fittings to the SED at \\lambda >= 100 um still reveal higher dust temperatures and lower emissivity indices compared to that of Spirals, while two MBB fittings to the full SED with a fixed emissivity index (beta = 2) show that even at 100 um about half of the emission comes from warm (50 K) dust, in contrast to the cold (~20 K) dust component. Our spatially resolved images further reveal that the far-IR colors including f70um/f160um, f160um/f250um and f250um/f350um are all related to ...

  1. Spatially resolved dust emission of extremely metal-poor galaxies*

    Science.gov (United States)

    Zhou, Luwenjia; Shi, Yong; Diaz-Santos, Taino; Armus, Lee; Helou, George; Stierwalt, Sabrina; Li, Aigen

    2016-05-01

    We present infrared (IR) spectral energy distributions (SEDs) of individual star-forming regions in four extremely metal-poor (EMP) galaxies with metallicity Z ≲ Z⊙/10 as observed by the Herschel Space Observatory. With the good wavelength coverage of the SED, it is found that these EMP star-forming regions show distinct SED shapes as compared to those of grand design Spirals and higher metallicity dwarfs: they have on average much higher f70μm/f160 μm ratios at a given f160 μm/f250 μm ratio; single modified blackbody (MBB) fittings to the SED at λ ≥ 100 μm still reveal higher dust temperatures and lower emissivity indices compared to that of Spirals, while two MBB fittings to the full SED with a fixed emissivity index (β = 2) show that even at 100 μm, about half of the emission comes from warm (50 K) dust, in contrast to the cold (˜20 K) dust component. Our spatially resolved images furthermore reveal that the far-IR colours including f70 μm/f160 μm, f160 μm/f250 μm and f250 μm/f350 μm are all related to the surface densities of young stars as traced by far-UV, 24 μm and star formation rates (SFRs), but not to the stellar mass surface densities. This suggests that the dust emitting at wavelengths from 70 to 350 μm is primarily heated by radiation from young stars.

  2. Metal-dusting resistance of uncoated and coated iron and nickel base materials against metal-dusting in heat treatment furnaces with carbonaceous atmospheres; Bestaendigkeit von unbeschichteten und beschichteten Eisen- und Nickelbasiswerkstoffen gegenueber Metal-Dusting in Aufkohlanlagen

    Energy Technology Data Exchange (ETDEWEB)

    Kleingries, Mirko; Ackermann, Helen; Lucka, Klaus [OWI Oel-Waerme-Institut GmbH, Aachen (Germany); Hoja, Timo; Mehner, Andeas; Zoch, Hans-Werner [IWT, Stiftung Institut fuer Werkstofftechnik, Bremen (Germany); Altena, Herwig [AICHELIN Ges.m.b.H, Moedling (Austria)

    2010-03-15

    Metal-Dusting is a well-known corrosion problem that occurs in carburizing atmospheres in industrial thermal processing plants. In literature almost no quantitative data on the metal dusting resistance of typical alloys employed in industrial furnaces are available. Therefore, a series of experiments with uncoated and sol gel ZrO{sub 2} coated high temperature materials was conducted in order to quantify their metal dusting behaviour under conditions close to those in case hardening furnaces. The experimental results show a strong influence of the surface conditions on the alloys resistance and a noticeable enhancement of the resistance by sol gel coatings. (orig.)

  3. Macrocyclic-, polycyclic-, and nitro musks in cosmetics, household commodities and indoor dusts collected from Japan: implications for their human exposure.

    Science.gov (United States)

    Nakata, Haruhiko; Hinosaka, Mari; Yanagimoto, Hayato

    2015-01-01

    This paper reported the occurrence and concentrations of macrocyclic-, polycyclic- and nitro musks in cosmetics and household commodities collected from Japan. The high concentrations and detection frequencies of Musk T, habanolide, and exaltolides were found in commercial products, suggesting their large amounts of production and usage in Japan. Polycyclic musks, HHCB and OTNE, also showed high concentrations in cosmetics and products. The estimated dairy intakes of Musk T and HHCB by the dermal exposure to commercial products were 7.8 and 7.9 μg/kg/day in human, respectively, and perfume and body lotion are dominant exposure sources. We also analyzed synthetic musks in house dusts. Polycyclic musks, HHCB and OTNE, showed high concentrations in samples, but macrocyclic musks were detected only in a few samples, although these types of musks were highly detected in commercial products. This is probably due to easy-degradation of macrocyclic musks in indoor environment. The dairy intakes of HHCB by dust ingestions were 0.22 ng/kg/day in human, which were approximately five orders of magnitudes lower than those of dermal absorption from commercial household commodities.

  4. How important are metal-poor AGB stars as cosmic dust producers?

    CERN Document Server

    Mattsson, Lars; Andersen, Anja C

    2015-01-01

    The efficiency of dust formation in oxygen-rich AGB stars should (in theory) be metallicity dependent since they are not producing their own raw material for dust production. Metal-poor carbon stars may not be very efficient dust producers either, because of more radiative heating of the grains forming in their atmospheres. We have just confirmed that inefficient dust and wind formation in simulations of metal-poor carbon stars is a real physical effect, albeit within the limitations of our simulations. Taken at face value, this implies that the amount of dust supplied by low-metallicity AGB stars to the build up of the cosmic dust component is clearly limited. Consequently, one may also ask how large a contribution AGB stars can make in general, when compared to recent observations of cosmic dust, which are suggesting major contributions from other sources?

  5. Evaluation of the concentration of allergens from mites in fur and households dust of dogs with atopic dermatitis

    Directory of Open Access Journals (Sweden)

    Dévaki L. de Assunção

    Full Text Available ABSTRACT: This study evaluated the concentration of Der p 1, Der f 1 and Blo t 5 in the fur and households of 20 dogs with atopic dermatitis (AD and 20 healthy dogs. The diagnosis of AD was clinical based on Favrot’s criteria. Dust samples were collected with a domestic vacuum cleaner. For each site, 1m2 was vacuumed for 2 min. The samples were collected in separate filters, transferred into plastic containers, sealed and kept frozen until ELISA analysis. In the fur of atopic dogs the average concentration of Der p 1 was 0.25μg/g compared to 0.03μg/g in healthy dogs. In households with atopic dogs the highest concentrations of Der p 1 were found in carpets (2.18μg/g, followed by couches (1.53μg/g, beds (1.14μg/g, dogs’ bed linen (0.64μg/g and floors (0.14μg/g. The concentrations of Der p 1 on carpets, couches and beds were significantly higher than in atopic dogs’ fur (p0.05. The concentrations of Der p 1, Der f 1 and Blo t 5 were equivalent in atopic and non-atopic dog’s households. Among the allergens studied, Der p 1 was the most commonly found, predominantly in carpets and couches.

  6. Heavy Metal Distribution in Street Dust from Traditional Markets and the Human Health Implications.

    Science.gov (United States)

    Kim, Jin Ah; Park, Jin Hee; Hwang, Won Ju

    2016-08-13

    Street dust is a hazard for workers in traditional markets. Exposure time is longer than for other people, making them vulnerable to heavy metals in street dust. This study investigated heavy metal concentrations in street dust samples collected from different types of markets. It compared the results with heavy metal concentrations in heavy traffic and rural areas. Street dust was significantly enriched with most heavy metals in a heavy traffic area while street dust from a fish market was contaminated with cupper (Cu), lead (Pb) and zinc (Zn). Street dust from medicinal herb and fruit markets, and rural areas were not contaminated. Principal component and cluster analyses indicated heavy metals in heavy traffic road and fish market dust had different sources. Relatively high heavy metal concentration in street dust from the fish market may negatively affect worker's mental health, as depression levels were higher compared with workers in other markets. Therefore, intensive investigation of the relationship between heavy metal concentrations in street dust and worker's health in traditional marketplaces should be conducted to elucidate the effect of heavy metals on psychological health in humans.

  7. Flame retardant transfers from U.S. households (dust and laundry wastewater) to the aquatic environment.

    Science.gov (United States)

    Schreder, Erika D; La Guardia, Mark J

    2014-10-07

    Levels of flame retardants in house dust and a transport pathway from homes to the outdoor environment were investigated in communities near the Columbia River in Washington state (WA). Residential house dust and laundry wastewater were collected from 20 homes in Vancouver and Longview, WA and analyzed for a suite of flame retardants to test the hypothesis that dust collecting on clothing and transferring to laundry water is a source of flame retardants to wastewater treatment plants (WWTPs) and subsequently to waterways. Influent and effluent from two WWTPs servicing these communities were also analyzed for flame retardants. A total of 21 compounds were detected in house dust, including polybrominated diphenyl ethers (PBDEs), 2-ethylhexyl-2,3,4,5-tetrabromobenzoate (TBB or EH-TBB), bis(2-ethylhexyl) 3,4,5,6-tetrabromophthalate (TBPH), 1,2-bis(2,4,6,-tribromophenoxy)ethane (BTBPE) and decabromodiphenylethane (DBDPE), hexabromocyclododecane (HBCD or HBCDD), tetrabromobisphenol A (TBBPA), and three chlorinated organophosphate flame retardants (ClOPFRs), tris(1,3-dichloro-2-propyl)phosphate (TDCPP or TDCIPP), tris(1-chloro-2-propyl)phosphate (TCPP or TCIPP), and tris(2-chloroethyl)phosphate (TCEP). Levels ranged from 3.6 to 82,700 ng g(-1) (dry weight). Of the 21 compounds detected in dust, 18 were also detected in laundry wastewater. Levels ranged from 47.1 to 561,000 ng L(-1). ClOPFRs were present at the highest concentrations in both dust and laundry wastewater, making up 72% of total flame retardant mass in dust and 92% in laundry wastewater. Comparison of flame retardant levels in WWTP influents to estimates based on laundry wastewater levels indicated that laundry wastewater may be the primary source to these WWTPs. Mass loadings to the Columbia River from each treatment plant were by far the highest for the ClOPFRs and ranged up to 114 kg/yr for TCPP.

  8. Elastic–plastic adhesive impacts of tungsten dust with metal surfaces in plasma environments

    Energy Technology Data Exchange (ETDEWEB)

    Ratynskaia, S., E-mail: svetlana.ratynskaia@ee.kth.se [KTH Royal Institute of Technology, Association EUROfusion-VR, Stockholm (Sweden); Tolias, P. [KTH Royal Institute of Technology, Association EUROfusion-VR, Stockholm (Sweden); Shalpegin, A. [Université de Lorraine, Institut Jean Lamour, Vandoeuvre-lès-Nancy (France); Vignitchouk, L. [KTH Royal Institute of Technology, Association EUROfusion-VR, Stockholm (Sweden); De Angeli, M. [Istituto di Fisica del Plasma – Consiglio Nazionale delle Ricerche, Milan (Italy); Bykov, I. [KTH Royal Institute of Technology, Association EUROfusion-VR, Stockholm (Sweden); Bystrov, K.; Bardin, S. [FOM Institute DIFFER, Dutch Institute For Fundamental Energy Research, Edisonbaan 14, 3439MN Nieuwegein (Netherlands); Brochard, F. [Université de Lorraine, Institut Jean Lamour, Vandoeuvre-lès-Nancy (France); Ripamonti, D. [Istituto per l’Energetica e le Interfasi – Consiglio Nazionale delle Ricerche, Milan (Italy); Harder, N. den; De Temmerman, G. [FOM Institute DIFFER, Dutch Institute For Fundamental Energy Research, Edisonbaan 14, 3439MN Nieuwegein (Netherlands)

    2015-08-15

    Dust-surface collisions impose size selectivity on the ability of dust grains to migrate in scrape-off layer and divertor plasmas and to adhere to plasma-facing components. Here, we report first experimental evidence of dust impact phenomena in plasma environments concerning low-speed collisions of tungsten dust with tungsten surfaces: re-bouncing, adhesion, sliding and rolling. The results comply with the predictions of the model of elastic-perfectly plastic adhesive spheres employed in the dust dynamics code MIGRAINe for sub- to several meters per second impacts of micrometer-range metal dust.

  9. Dust-Metal Sources in an Urbanized Arid Zone: Implications for Health-Risk Assessments.

    Science.gov (United States)

    García-Rico, Leticia; Meza-Figueroa, Diana; Gandolfi, A Jay; Del Río-Salas, Rafael; Romero, Francisco M; Meza-Montenegro, Maria Mercedes

    2016-04-01

    The available information concerning metal pollution in different dust sources and the health effects in children remains limited in Mexico. This study focuses on Hermosillo, which is an urbanized area located in the Sonoran Desert in which soil resuspension and dust emission processes are common. The metal content of arsenic (As), chromium (Cr), manganese (Mn), and lead (Pb) were determined in three dust sources (playgrounds, roofs, and roads), each representing different exposure media (EM) for these elements. The metal levels in dust were found in the order of Mn > Cr > Pb > As with the highest metal content found in road dust. Despite the similar average metal distributions, principal component analysis shows a clear separation of the three EM with playground dust related to Cr and Mn and road dust to As and Pb. However, the geoaccumulation index results indicate that dust samples are uncontaminated to moderately polluted, except for Pb in road dust, which is considerably high. In addition, the enrichment factor suggests an anthropogenic origin for all of the studied metals except for Mn. In this context, the hazard index (HI) for noncarcinogenic risk is >1 in this population and thus represents a potential health risk. The spatial distribution for each metal on EM and the HI related to the marginality index could represent a more accurate decision-making tool in risk assessment studies.

  10. ADDITION OF ELECTRIC ARC FURNACE DUST IN HOT METAL

    Directory of Open Access Journals (Sweden)

    Felipe Fardin Grillo

    2013-03-01

    Full Text Available This research aims to study the process of incorporation of the mass in final hot metal and volatilization mass contained in the electric arc furnace dust (EAFD, by addition in hot metal at a temperature of 1,400°C; 1,450°C and 1,500°C altering experimental conditions such as the percentage of EAFD to be added and the percentage of silicon in hot metal. Previously, the EAFD was characterized using techniques of chemical analysis and size analysis. After characterization, the EAFD to be added to the hot metal was agglomerated in the form of briquettes. The achievement of fusion experiments in laboratory scale was placed in a vertical tubular furnace with temperature control. A flow of inert gas (argon was maintained inside the furnace during the experiments. The result of the sample EAFD volatilized shows that there is an increase in the zinc concentration when compared with the concentration of zinc present in EAFD “as received”.

  11. Exposure Assessment of Allergens and Metals in Settled Dust in French Nursery and Elementary Schools

    Directory of Open Access Journals (Sweden)

    Nuno Canha

    2015-11-01

    Full Text Available The aim of this study was to characterise the contamination in settled dust in French classrooms and to provide an overview of the influencing factors of dust contamination. Cat, dog and dust mite allergens and metals were measured in 51 classrooms at 17 schools. The concentrations of pet allergens in settled dust were generally low (mean value of 0.1 µg·g−1, with carpeted and rug-covered floors presenting higher dust and cat allergen concentrations. The highest metal loadings in dust were observed for manganese (Mn and copper (Cu, while the lead (Pb loadings were lower (16 ± 19 µg·m−2 and fell below the French guideline. Higher metal leachability was found for cadmium (Cd, Cu, Pb and strontium (Sr at values of approximately 80%, which suggest that, in cases of dust ingestion by children, a large proportion should be assimilated through the gastro-intestinal tract. The intra-classroom and intra-school variabilities of the metal concentrations in settled dust were lower than the variability between schools. Classrooms with tiled floors had higher Pb loadings than classrooms with wood or vinyl floors. In addition, wet cleaning less than once a week resulted in greater loadings of Cu and Pb in the settled dust. Lastly, enrichment factors showed that metals in settled dust of classrooms were not only from the contribution of the natural background concentrations in soils.

  12. On the (in)variance of the dust-to-metals ratio in galaxies

    CERN Document Server

    Mattsson, Lars; Andersen, Anja C; Zafar, Tayyaba

    2014-01-01

    Recent works have demonstrated a surprisingly small variation of the dust-to-metals ratio in different environments and a correlation between dust extinction and the density of stars. Naively, one would interpret these findings as strong evidence of cosmic dust being produced mainly by stars. But other observational evidence suggest there is a significant variation of the dust-to-metals ratio with metallicity. As we demonstrate in this paper, a simple star-dust scenario is problematic also in the sense that it requires that destruction of dust in the interstellar medium (e.g., due to passage of supernova shocks) must be highly inefficient. We suggest a model where stellar dust production is indeed efficient, but where interstellar dust growth is equally important and acts as a replenishment mechanism which can counteract the effects of dust destruction. This model appears to resolve the seemingly contradictive observations, given that the ratio of the effective (stellar) dust and metal yields is not universal...

  13. Correlation of in vivo relative bioavailability to in vitro bioaccessibility for arsenic in household dust from China and its implication for human exposure assessment.

    Science.gov (United States)

    Li, Hong-Bo; Li, Jie; Juhasz, Albert L; Ma, Lena Q

    2014-12-01

    Incidental ingestion of household dust is an important arsenic (As) exposure pathway for children. However, compared to soils, assessment of As relative bioavailability (RBA) in household dust is limited. In this study, As-RBA in 12 household dust samples (7–38 mg kg(–1)) was measured using an in vivo mouse model and compared to As bioaccessibility determined using 4 assays [Solubility Bioaccessibility Research Consortium method (SBRC), in vitro gastrointestinal method (IVG), Deutsches Institut für Normunge.V. method (DIN), and physiologically based extraction test (PBET)]. Arsenic RBA ranged from 21.8 ± 1.6 to 85.6 ± 7.2% with samples containing low Fe and high total organic carbon content having higher As-RBA. Strong in vivo–in vitro correlations (IVIVC) were found between As-RBA and As bioaccessibility for SBRC and DIN (r2 = 0.63–0.85), but weaker ones were obtained for IVG and PBET (r2 = 0.29–0.55). The developed IVIVC for SBRC and DIN were used to calculate As-RBA based on As bioaccessibility for an additional 12 household dust samples. Although As bioaccessibility differed significantly (up to 7.7-fold) based on in vitro methods, predicted As-RBA was less variable (up to 3.0-fold) when calculated using As bioaccessibility data and the corresponding IVIVC. Our data suggested that both SBRC and DIN had potential to assess As bioavailability in household dust samples; however, additional research is needed.

  14. French children's exposure to metals via ingestion of indoor dust, outdoor playground dust and soil: contamination data.

    Science.gov (United States)

    Glorennec, Philippe; Lucas, Jean-Paul; Mandin, Corinne; Le Bot, Barbara

    2012-09-15

    In addition to dietary exposure, children are exposed to metals via ingestion of soils and indoor dust, contaminated by natural or anthropogenic outdoor and indoor sources. The objective of this nationwide study was to assess metal contamination of soils and dust which young French children are exposed to. A sample of 484 children (6 months to 6 years) was constituted in order to obtain representative results for young French children. In each home indoor settled dust was sampled by a wipe in up to five rooms. Outdoor playgrounds were sampled with a soil sample ring (n=315) or with a wipe in case of hard surfaces (n=53). As, Cd, Cr, Cu, Mn, Pb, Sb, Sr, and V were measured because of their potential health concern due to soil and dust ingestion. The samples were digested with hydrochloric acid, and afterwards aqua regia in order to determine both leachable and total metal concentrations and loadings by mass spectrometry with a quadrupole ICP-MS. In indoor settled dust most (total) loadings were below the Limit of Quantification (LOQ), except for Pb and Sr, whose median loadings were respectively 9 and 10 μg/m². The 95th percentile of loadings were 2 μg/m² for As, playgrounds were 2/16, playground soil median/95th percentile of concentrations (μg/g) were 8/26, soil and dust and the associated risks in urban and rural environments. Ratios of leachable/total concentrations and loadings, calculated on >LOQ measurements, differed among metals. To a lesser extent, they were also affected by type of matrix, with (except for Cd) a greater leachability of dust (especially indoor) compared to soils.

  15. Evolution of thermally pulsing asymptotic giant branch stars - III. Dust production at supersolar metallicities

    Science.gov (United States)

    Nanni, Ambra; Bressan, Alessandro; Marigo, Paola; Girardi, Léo

    2014-03-01

    We extend the formalism presented in our recent calculations of dust ejecta from the Thermally Pulsing Asymptotic Giant Branch (TP-AGB) phase to the case of super-solar metallicity stars. The TP-AGB evolutionary models are computed with the COLIBRI code. We adopt our preferred scheme for dust growth. For M-giants, we neglect chemisputtering by H2 molecules and for C-stars we assume a homogeneous growth scheme which is primarily controlled by the carbon over oxygen excess. At super-solar metallicities, dust forms more efficiently and silicates tend to condense significantly closer to the photosphere (r ˜ 1.5R*) - and thus at higher temperatures and densities - than at solar and sub-solar metallicities (r ˜ 2-3R*). In such conditions, the hypothesis of thermal decoupling between gas and dust becomes questionable, while dust heating due to collisions plays an important role. The heating mechanism delays dust condensation to slightly outer regions in the circumstellar envelope. We find that the same mechanism is not significant at solar and sub-solar metallicities. The main dust products at super-solar metallicities are silicates. We calculate the total dust ejecta and dust-to-gas ejecta, for various values of the stellar initial masses and initial metallicities Z = 0.04, 0.06. Merging these new calculations with those for lower metallicities it turns out that, contrary to what is often assumed, the total dust-to-gas ejecta of intermediate-mass stars exhibit only a weak dependence on the initial metal content.

  16. Searching for Dust around Hyper Metal-Poor Stars

    CERN Document Server

    Venn, Kim A; Divell, Mike; Cote, Stephanie; Lambert, David L; Starkenburg, Else

    2014-01-01

    We examine the mid-infrared fluxes and spectral energy distributions for metal-poor stars with iron abundances [Fe/H] $\\lesssim-5$, as well as two CEMP-no stars, to eliminate the possibility that their low metallicities are related to the depletion of elements onto dust grains in the formation of a debris disk. Six out of seven stars examined here show no mid-IR excess. These non-detections rule out many types of circumstellar disks, e.g. a warm debris disk ($T\\!\\le\\!290$ K), or debris disks with inner radii $\\le1$ AU, such as those associated with the chemically peculiar post-AGB spectroscopic binaries and RV Tau variables. However, we cannot rule out cooler debris disks, nor those with lower flux ratios to their host stars due to, e.g. a smaller disk mass, a larger inner disk radius, an absence of small grains, or even a multicomponent structure, as often found with the chemically peculiar Lambda Bootis stars. The only exception is HE0107-5240, for which a small mid-IR excess near 10 microns is detected at ...

  17. Arsenic in residential soil and household dust in Cornwall, south west England: potential human exposure and the influence of historical mining.

    Science.gov (United States)

    Middleton, Daniel R S; Watts, Michael J; Beriro, Darren J; Hamilton, Elliott M; Leonardi, Giovanni S; Fletcher, Tony; Close, Rebecca M; Polya, David A

    2017-04-19

    Exposure to arsenic (As) via residential soil and dust is a global concern, in regions affected by mining or with elevated concentrations present in underlying geology. Cornwall in south west England is one such area. Residential soil (n = 127) and household dust (n = 99) samples were collected from across Cornwall as part of a wider study assessing exposure to environmental As. Samples were analysed for total As (soil and dust samples) and human ingestion bioaccessible As (soil samples from properties with home-grown produce). Arsenic concentrations ranged from 12 to 992 mg kg(-1) in soil and 3 to 1079 mg kg(-1) in dust and were significantly higher in areas affected by metalliferous mineralisation. Sixty-nine percent of soils exceeded the 37 mg kg(-1) Category 4 Screening Level (C4SL), a generic assessment criteria for As in residential soils in England, which assumes 100% bioavailability following ingestion. The proportion of exceedance was reduced to 13% when the bioavailability parameter in the CLEA model was changed to generate household specific bioaccessibility adjusted assessment criteria (ACBIO). These criteria were derived using bioaccessibility data for a sub-set of individual household vegetable patch soils (n = 68). Proximity to former As mining locations was found to be a significant predictor of soil As concentration. This study highlights the value of bioaccessibility measurements and their potential for adjusting generic assessment criteria.

  18. [Seasonal Provincial Characteristics of Vertical Distribution of Dust Loadings and Heavy Metals near Surface in City].

    Science.gov (United States)

    Li, Xiao-yan; Zhang, Shu-ting

    2015-06-01

    With the emergence of urban high-rise building, the vertical space of human daily life gradually extended upward. Seasonal characteristics of vertical distribution of dust loadings and heavy metals near surface are remarkable. In this study, we collected dust deposited on the windowsill at different space height (1th-8th floor) from three buildings in Guiyang city during spring, summer, autumn and winter, and analyzed the deposition fluxes of dust and elements including Ca, Fe, Cd, Cr, Cu, Ni, Pb and Zn. The results showed that: the total changing trend of vertical distribution of dust loadings was that the deposition fluxes of dust in winter were the highest, followed by those in spring, and the deposition fluxes of dust in summer were the lowest. The degree of variation on dust loadings dependent on the change of elevation was the highest in winter, followed by that in summer, and was relatively lower in spring and autumn. The effect on dust loadings by seasonal changing was relatively heavier on windowsill on the lower level than on the higher level. The levels of elements were the highest in spring dust, while those in autumn were relatively lower. Among the 8 elements, the variability of Zn in dust related to space time variation was the most obvious, and that of Ca was weaker. The atmospheric inversion condition might be one of the reasons that improved the deposition fluxes of dust and the contents of Ph and Zn in dust during winter and spring.

  19. In vitro bioavailability of heavy metals in pressure-treated wood dust.

    Science.gov (United States)

    Gordon, Terry; Spanier, Jonathan; Butala, John H; Li, Ping; Rossman, Toby G

    2002-05-01

    Pressure treatment with chromium, copper, and arsenic (CCA) is the most prevalent method for protecting wood used in outdoor construction projects. Although these metals are tightly bound to the wood fibers and are not released under most conditions of use, we examined the bioavailability of metals in CCA pressure-treated wood dust in vitro. Cytotoxicity and metallothionein (MT) mRNA expression were examined in V79 Chinese hamster lung fibroblast cells incubated with respirable-size wood dust generated by sanding CCA-treated and untreated (control) Southern yellow pine. In colony survival studies, increased cytotoxicity (p wood dust (351 +/- 77 microg/ml, mean +/- SE) compared with control wood dust (883 +/- 91 microg/ml). Increased cytotoxicity with CCA wood dust also occurred in an arsenic resistant subline of V79 cells, thus suggesting that arsenic was not responsible for the increased cytotoxicity. Metallothionein mRNA was significantly increased after 48 h of treatment with CCA wood dust compared with control wood dust. Incubation of CCA wood dust in cell culture media resulted in the transfer of copper, but not chromium or arsenic, into the media. Moreover, the treatment of cells with this filtered extract resulted in significantly increased metallothionein mRNA, suggesting that bioavailable copper is responsible for inducing metallothionein mRNA in V79 cells. Thus, these bioassays suggest that metals become bioavailable during in vitro culture of phagocytic V79 cells with CCA wood dust.

  20. Distribution of heavy metals in road dust along an urban-rural gradient in Massachusetts

    Science.gov (United States)

    Apeagyei, Eric; Bank, Michael S.; Spengler, John D.

    2011-04-01

    Human exposures to particulate matter emitted from on-road motor vehicles include complex mixtures of metals from tires, brakes, parts wear and resuspended road dust. The aim of this study was to assess road dust for metals associated with motor vehicle traffic, particularly those metals coming from brake and tire wears. We hypothesized that the road dust would show significant difference in both composition and concentration by traffic type, road class and by location. X-ray fluorescence (XRF) analyses of 115 parked car tires showed Zn and Ca were likely associated with tire wear dust. XRF results of three used brake pads indicated high concentrations of Fe, Ti, Cu, Ba, Mo and Zr. To assess heavy metal exposures associated with tires and brake wear adjacent to roads of varying traffic and functional classes, 85 samples of road dust were collected from road surfaces adjacent to the curb and analyzed by XRF. Median concentrations for Fe, Ca and K were greater than Ti (1619 ppm), with concentration ratios of Fe: Ca: K: Ti [16:5:3:1]. Cumulative frequency distribution graphs showed distribution of Fe, Ba, Cu, and Mo were similar regardless of road traffic rating. However, Zn, Ti, and Zr varied significantly ( p moderate > low traffic). Fe, Ba, Cu, and Mo also had similar distributions regardless of road class while composition of Zn, Ti, and Zr varied significantly across road class ( p Minor roads > highway). In comparing urban road dust to rural road dust, we observed Fe, Ca, K, and Ti were significantly greater in urban road dust ( p < 0.05). In urban road dust the Fe: Ca: K: Ti relationship with median Ti of 2216 ppm was 12: 6: 3.5: 1. These results indicate that roadway dust may be important sources of metals for runoff water and localized resuspended particulate matter.

  1. [Investigation of heavy metal and polycyclic aromatic hydrocarbons contamination in street dusts in urban Beijing].

    Science.gov (United States)

    Xiang, Li; Li, Ying-Xia; Shi, Jiang-Hong; Liu, Jing-Ling

    2010-01-01

    This paper investigated the contamination levels of heavy metal and polycyclic aromatic hydrocarbons (PAHs) in street dusts in different functional areas in urban Beijing. Results show that the mean concentrations of Cd, Hg, Cr, Cu, Ni, Pb and Zn in street dusts in Beijing are 710 ng/g, 307 ng/g, 85.0 microg/g, 78.3 microg/g, 41.1 microg/g, 69.6 microg/g and 248.5 microg/g, respectively, which are significantly lower than those in most cities around the world and Shenyang, Shanghai in China. The mean concentration of Sigma 16PAHs in street dusts in Beijing is 0.398 microg/g, which is also lower than those of Handan, Tianjin and Shanghai. Non-parametric Friedman test demonstrates significant differences of heavy metal contents on street dusts from different functional zones. Street dusts in residential area and parks have lower heavy metal and PAHs concentrations than the street dusts from areas of high traffic density. The concentrations of heavy metals follow the order Zn > Cr > Cu > Pb > Ni > Cd > Hg, which is consistent with the situation in other cities around the world. The geoaccumulation index analysis shows that street dust in urban Beijing is moderately polluted by Cd, Zn and Cu, little polluted by Cr and Pb and practically unpolluted by Ni. The contamination levels of Sigma 16PAHs on street dusts vary greatly in different functional zones with parks little polluted, residential areas moderately to strongly polluted and traffic related areas strongly polluted to extremely polluted. Mass loading of heavy metals and PAHs is largely associated with street dusts of size range dust sweeping devices to remove not only the fine particle but also the coarser particles.

  2. Determination of metal content in atmospheric dust samples using different vessel and filter materials

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, G.; Wentrup, G.J.

    1989-02-01

    In this paper materials like glassfibre and quartzglass filters were analysed with respect to their application for the analysis of metal contents in atmospheric dust samples. Furthermore different vessel materials, resistant to fluoric acid, have been tested too. In summary the most important fact for the determination of metal content in atmospheric dust samples - prior condition the chosen analysis method is suitable and sensitive enough - is the quality of the used materials. These materials are to be chosen thoroughly to the conditions required.

  3. Metal Dust Exposure and Respiratory Health of Male Steel Work¬ers in Terengganu, Malaysia

    Directory of Open Access Journals (Sweden)

    Nurul Ainun HAMZAH

    2015-10-01

    Full Text Available Background: This cross sectional study was carried out to determine the relationship between metal dust exposure and respiratory health in male steel workers in Terengganu, Malaysia.Methods: Subjects were interviewed using a structured questionnaire from British Medical Research Council (BMRC Questionnaire regarding respiratory symptoms and were examined their lung function using spirometer.Results: The mean trace metal dusts concentration TWA8 for cobalt and chromium in most of work unit exceeded occupational exposure prescribed values. Prevalence of chest tightness, chronic phlegm, and shortness of breath was 28.0%, 26.8%, 24.1%, and 20.2% respectively. Age and smoking were among the factors associated with respiratory symptoms (OR: 0.92 – 1.78. Smoking and cumulative respirable metal dust were negatively associated with FEV1.Conclusion: The mean metal dust for cobalt and chromium were 1 to 2 times higher than permissible exposure limit (PEL. This study found that respirable cumulative metal dust exposure is one of the contributing factors to lung function values among steel workers. Keywords: Respiratory symptoms, Lung function, Metal dust, Questionnaire

  4. Initial results for urban metal distributions in house dusts of Syracuse, New York, USA

    Institute of Scientific and Technical Information of China (English)

    D. L. Johnson; D. Prokhorova; L. Tidd; M. M. Millones; M. Vincent; J. Hager; A. Hunt; D. A. Griffith; S. Blount; S. Ellsworth; J. Hintz; R. Lucci; A. Mittiga

    2005-01-01

    A program of house dust sample collection and analysis has begun in Syracuse,New York, USA, in order to determine the feasibility of a geography-based exposure assessment for urban metals. The sampling program, and the protocols it employs, is described for two different types of wipe media, Ghost Wipes and Whatman Filters. Preliminary results show that strong spatial patterns of floor dust loading (mg dust per square foot) can be observed for data aggregated at a spatial scale of about 1600 m (~2.5 kin2). Floor dust metal concentrations were similar to those found in other urban environments, with some regional variation. The median floor dust Pb concentration was ~108 mg· kg-1 for this initial data set of ~264 sampled residential locations, and varied from 50 to 1100 mg Pb · kg-1.

  5. Trace metals, anions and polybromodiphenyl ethers in settled indoor dust and their association.

    Science.gov (United States)

    Kefeni, Kebede K; Okonkwo, Jonathan O

    2013-07-01

    Contaminants in settled indoor dust are potentially health hazardous to human. Thus, identification and quantification of toxic chemicals in settled indoor dust is of great concern. In this study, the levels of major anions ([Formula: see text]), trace metals (Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, As and Pb) and polybromodiphenyl ethers (PBDEs) in settled office and home dust were determined and correlations between the contaminants investigated. Depending on the available materials in both microenvironments, the most possible sources were identified. The results showed that the settled office dusts (n = 6 pooled samples from 85 offices) were more contaminated than home dusts (n = 8 homes). For anions, [Formula: see text] and Cl(-) accounted for 87 and 97% of the total office and home dust contaminants, respectively. For trace metals, Fe, Cu, Zn and Mn, accounted for 98% of the contaminants in both office and home dust samples. Fe exhibited the highest percentage of 76.7 and 87.3% in office and home dust samples, respectively. For PBDEs, the mean concentrations detected in office and home dust ranged between 5.8-86.3 and 1.5-20.6 ng g(-1), respectively. The log-transformed correlation between the total concentrations of trace metals and major anions detected in offices and homes was positive for offices and negative for homes with a statistically significant values (r = 0.73, p < 0.01; r = -0.22, p < 0.01, respectively). The daily exposure rates determined for the most hazardous such as As, Cd, Pb and PBDEs congeners, relative to the individual concentrations reported in the literature in settled indoor dust, were found very lower. Therefore, maybe it is possible to expect less potential health risk. Investigation of formation of coordination compounds between trace metals and PBDEs congeners is possible; however, this requires further study.

  6. Are the Formation and Abundances of Metal-poor Stars the Result of Dust Dynamics?

    Science.gov (United States)

    Hopkins, Philip F.; Conroy, Charlie

    2017-02-01

    Large dust grains can fluctuate dramatically in their local density, relative to the gas, in neutral turbulent disks. Small, high-redshift galaxies (before reionization) represent ideal environments for this process. We show via simple arguments and simulations that order-of-magnitude fluctuations are expected in local abundances of large grains (>100 Å) under these conditions. This can have important consequences for star formation and stellar metal abundances in extremely metal-poor stars. Low-mass stars can form in dust-enhanced regions almost immediately after some dust forms even if the galaxy-average metallicity is too low for fragmentation to occur. We argue that the metal abundances of these “promoted” stars may contain interesting signatures as the CNO abundances (concentrated in large carbonaceous grains and ices) and Mg and Si (in large silicate grains) can be enhanced and/or fluctuate almost independently. Remarkably, the otherwise puzzling abundance patterns of some metal-poor stars can be well fit by standard IMF-averaged core-collapse SNe yields if we allow for fluctuating local dust-to-gas ratios. We also show that the observed log-normal distribution of enhancements in these species agrees with our simulations. Moreover, we confirm that Mg and Si are correlated in these stars the abundance ratios are similar to those in local silicate grains. Meanwhile [Mg/Ca], predicted to be nearly invariant from pure SNe yields, shows very large enhancements and variations up to factors of ≳100 as expected in the dust-promoted model, preferentially in the [C/Fe]-enhanced metal-poor stars. Together, this suggests that (1) dust exists in second-generation star formation, (2) local dust-to-gas ratio fluctuations occur in protogalaxies and can be important for star formation, and (3) the light element abundances of these stars may be affected by the local chemistry of dust where they formed, rather than directly tracing nucleosynthesis from earlier

  7. [Particle Size Distribution, Seasonal Variation Characteristics and Human Exposure Assessment of Heavy Metals in Typical Settled Dust from Beijing].

    Science.gov (United States)

    Cao, Zhi-guo; Yu, Gang; Lü, Xiang-ying; Wang, Meng-lei; Li, Qi-lu; Feng, Jing-lan; Yan, Guang-xuan; Yu, Hao; Sun, Jian-hui

    2016-04-15

    Four types of dust from dormitories, offices, hotels and roads in Beijing were collected and fractionated into 9 fractions, respectively. Totally 36 samples were obtained and analyzed for heavy metals including Cu, Zn, Cr, Pb, Cd and Ni. Particle size distributions of those heavy metals in these four types of dust were investigated and the influencing mechanisms were discussed. Distribution patterns of the same heavy metal in different types of dust showed various characteristics. Also different metals in the same type of dust represented different distribution patterns. Heavy metals in road dust tended to concentrate in finer particles. Two offices from the same building, located in Beijing, China, were selected to study the seasonality of heavy metals in dust. Dust sampling from Office A was conducted at weekly intervals between March 2012 and August 2012, while dust from Office B was sampled fortnightly from March 2012 to December 2012. Generally, levels of all heavy metals remained stable among different seasons, however, Cr and Pb represented more significant fluctuations than other four heavy metals. Based on the geo-accumulation index method, the pollution of Zn, Cu and Pb was more serious in the investigated samples, and dust from offices and hotels were moderately polluted by Zn. According to the risk assessment results, the carcinogenic health risks of the six heavy metals in the four types of dust were negligible.

  8. Quantitative Risk Assessment for Lung Cancer from Exposure to Metal Ore Dust

    Institute of Scientific and Technical Information of China (English)

    FUHUA; JINGXIPENG; 等

    1992-01-01

    To quantitatively assess risk for lung cancer of metal miners,a historical cohort study was conducted.The cohort consisted of 1113 miners who were employed to underground work for at least 12 months between January 1,1960and December,12,1974,According to the records or dust concentration,a cumulative dust dose of each miner in the cohort was estimated.There wer 162 deaths in total and 45 deaths from lung cancer with a SMR of 2184,The SMR for lung cancer increased from 1019 for those with cumulative dust of less than 500mg-year to 2469 for those with the dose of greater than 4500mg-year.Furthermore,the risk in the highest category of combined cumulative dust dose and cigarette smoking was 46-fold greater than the lowest category of dust dose and smoking.This study showed that there was an exposure-response relationship between metal ore dust and lung cancer,and an interaction of lung cancer between smoking and metal ore dust exposure.

  9. The Metallicity and Dust Content of a Redshift 5 Gamma-Ray Burst Host Galaxy

    NARCIS (Netherlands)

    Sparre, M.; Hartoog, O.E.; Krühler, T.; Fynbo, J.P.U.; Watson, D.J.; Wiersema, K.; D'Elia, V.; Zafar, T.; Afonso, P.M.J.; Covino, S.; de Ugarte Postigo, A.; Flores, H.; Goldoni, P.; Greiner, J.; Hjorth, J.; Jakobsson, P.; Kaper, L.; Klose, S.; Levan, A.J.; Malesani, D.; Milvang-Jensen, B.; Nardini, M.; Piranomonte, S.; Sollerman, J.; Sánchez-Ramírez, R.; Schulze, S.; Tanvir, N.R.; Vergani, S.D.; Wijers, R.A.M.J.

    2014-01-01

    Observations of the afterglows of long gamma-ray bursts (GRBs) allow the study of star-forming galaxies across most of cosmic history. Here we present observations of GRB 111008A, from which we can measure metallicity, chemical abundance patterns, dust-to-metals ratio (DTM), and extinction of the GR

  10. Linking dust emission to fundamental properties in galaxies: The low-metallicity picture

    CERN Document Server

    Rémy-Ruyer, A; Galliano, F; Lebouteiller, V; Baes, M; Bendo, G J; Boselli, A; Ciesla, L; Cormier, D; Cooray, A; Cortese, L; De Looze, I; Doublier-Pritchard, V; Galametz, M; Jones, A P; Karczewski, O Ł; Lu, N; Spinoglio, L

    2015-01-01

    In this work, we aim at providing a consistent analysis of the dust properties from metal-poor to metal-rich environments by linking them to fundamental galactic parameters. We consider two samples of galaxies: the Dwarf Galaxy Survey (DGS) and KINGFISH, totalling 109 galaxies, spanning almost 2 dex in metallicity. We collect infrared (IR) to submillimetre (submm) data for both samples and present the complete data set for the DGS sample. We model the observed spectral energy distributions (SED) with a physically-motivated dust model to access the dust properties. Using a different SED model (modified blackbody), dust composition (amorphous carbon), or wavelength coverage at submm wavelengths results in differences in the dust mass estimate of a factor two to three, showing that this parameter is subject to non-negligible systematic modelling uncertainties. For eight galaxies in our sample, we find a rather small excess at 500 microns (< 1.5 sigma). We find that the dust SED of low-metallicity galaxies is ...

  11. How Does Metallicity Affect the Gas and Dust Properties of Galaxies?

    CERN Document Server

    Madden, Suzanne C; Remy-Ruyer, Aurelie

    2016-01-01

    Comparison of the ISM properties of a wide range of metal-poor galaxies with normal metal-rich galaxies reveals striking differences. We find that the combination of the low dust abundance and the active star formation results in a very porous ISM filled with hard photons, heating the dust in dwarf galaxies to overall higher temperatures than their metal-rich counterparts. This results in photodissociation of molecular clouds to greater depths, leaving relatively large PDR envelopes and difficult-to-detect CO cores. From detailed modeling of the low-metallicity ISM, we find significant fractions of CO-dark H2 - a reservoir of molecular gas not traced by CO, but present in the [CII] and [CI]-emitting envelopes. Self-consistent analyses of the neutral and ionized gas diagnostics along with the dust SED is the necessary way forward in uncovering the multiphase structure of galaxies

  12. Dust-to-metal ratios in damped Lyman-α absorbers. Fresh clues to the origins of dust and optical extinction towards γ-ray bursts

    Science.gov (United States)

    De Cia, A.; Ledoux, C.; Savaglio, S.; Schady, P.; Vreeswijk, P. M.

    2013-12-01

    Motivated by the anomalous dust-to-metal ratios derived in the literature for γ-ray burst (GRB) damped Lyman-α absorbers (DLAs), we measure these ratios using the dust-depletion pattern observed in UV/optical afterglow spectra associated with the interstellar medium (ISM) at the GRB host-galaxy redshifts. Our sample consists of 20 GRB absorbers and a comparison sample of 72 DLAs toward quasars (QSOs) with redshift 1.2 extinction AV increases steeply with the column density of iron in dust, N(Fe)dust, calculated from relative metal abundances, confirming that dust extinction is mostly occurring in the host galaxy ISM. Most GRB-DLAs display log N(Fe)dust > 14.7, above which several QSO-DLAs reveal molecular hydrogen, making GRB-DLAs promising candidates for molecular detection and study.

  13. Assessment of heavy metal contamination of road dusts from industrial areas of Hyderabad, India.

    Science.gov (United States)

    Mathur, Ramavati; Balaram, V; Satyanarayanan, M; Sawant, S S

    2016-09-01

    Road dust in industrial areas carries high levels of toxic heavy metals. Exposure to such polluted dust significantly affects the health of people residing in these areas, which is of major concern. The present study was taken up with an aim to highlight the magnitude and potential sources of accumulation of heavy metals in 32 road dust samples collected from six industrial areas of Hyderabad. Acid-digested sample solutions were analyzed by ICP-MS for Cu, Zn, Cr, Co, Pb, Ni, V, Zr, Ce, Y, and Hf. The road dusts exhibit significantly high mean metal levels which are much above their crustal abundances. The relative ordering of mean metal contents is Zr > Zn > Pb > Cr > Ce > Cu > V > Ni > Y > Co > Hf. Elevated pollution indices (I geo, EF, C (i) f, and C deg) reveal that the road dusts are pollution impacted showing varying degree of heavy metal contamination. Strong positive correlations exhibited by metal pairs Cu-Zn, Cr-Ni, Ce-V, Y-Ce, and Hf-Zr imply their origin from common anthropogenic sources. Principal component analysis grouped the metals according to the sources which contributed to their accumulation. The present study confirms to an intensive anthropogenic impact on the accumulation of heavy metals in the studied road dusts attributable mainly to strong influences of vehicular and industrial activity and partly to domestic and natural processes. The results obtained imply the need for further investigations to assess their ecological implications and human health risks.

  14. House dust and storage mite contamination of dry dog food stored in open bags and sealed boxes in 10 domestic households.

    Science.gov (United States)

    Gill, Christina; McEwan, Neil; McGarry, John; Nuttall, Tim

    2011-04-01

    Dry pet food is a potential source of exposure to house dust and storage mite allergens in canine atopic dermatitis. This study evaluated contamination of house dust and dry dog food stored in paper bags, sealable plastic bags and sealable plastic boxes in 10 households for 90 days using Acarex(®) tests for guanine, a Der p 1 ELISA and mite flotation. Acarex(®) tests were negative in all the food samples but positive in all the house dust samples. The Der p 1 levels and mite numbers significantly increased in food from paper bags (P = 0.0073 and P = 0.02, respectively), but not plastic bags or boxes. Mite numbers and Der p 1 levels were 10-1000 times higher in house dust than the corresponding food samples (P food from the paper (P food from the paper bags (P = 0.0007). Bedding and carpets were significantly associated with Der p 1 levels in house dust (P = 0.015 and P = 0.01, respectively), and food from the paper (both P = 0.02) and plastic bags (P = 0.03 and P = 0.04, respectively). Mites were identified in six of 10 paper bag, three of 10 plastic bag, one of 10 plastic box and nine of 10 house dust samples. These comprised Dermatophagoides (54%), Tyrophagus (10%; all from food) and unidentified mites (36%). Storage of food in sealable plastic boxes largely prevented contamination for 3 months. Exposure to mites and mite proteins in all the stored food, however, appeared to be trivial compared with house dust. © 2010 The Authors. Journal compilation © 2010 ESVD and ACVD.

  15. Small Community and Household Water Systems Research on Removal of Metals and Pesticides from Drinking Water Sources

    Science.gov (United States)

    The presentation entitled “Small Community and Household Water Systems Research on Removal of Metals and Pesticides from Drinking Water Sources” provides treatment alternatives for removal of metals and pesticides from surface and ground waters before human consumption. The pres...

  16. Determination of heavy metals in indoor dust from Istanbul, Turkey: estimation of the health risk.

    Science.gov (United States)

    Kurt-Karakus, Perihan Binnur

    2012-12-01

    Levels of eight potentially toxic heavy metals in indoor dust from homes and offices in Istanbul were investigated. The concentrations of heavy metals in indoor dust from homes+office ranged from 62 to 1800 μgg(-1) for Cu, 3-200 μgg(-1) for Pb, 0.4-20 μgg(-1) for Cd, 210-2800 μgg(-1) for Zn, 2.8-460μgg(-1) for Cr, 8-1300μgg(-1) for Mn, 2.4-25μgg(-1) for Co, 120-2600μgg(-1) for Ni. Results of the study were comparable to other studies conducted on indoor dust and street dust from a variety of cities globally. Considering only ingestion + inhalation, the carcinogenic risk level of Cr for adults and children (3.7×10(-5) and 2.7×10(-5)) in Istanbul was in the range of EPA's safe limits (1×10(-6) and 1×10(-4)), indicating that cancer risk of Cr due to exposure to indoor dust in Istanbul can be acceptable. According to calculated Hazard Quotient (HQ), for non-cancer effects, the ingestion of indoor dust appears to be the major route of exposure to the indoor dust that results in a higher risk for heavy metals, followed by dermal contact and inhalation pathways. However, compared to ingestion and dermal contact exposure, exposure through inhalation is almost negligible. Hazard Index (HI) values for all studied elements were lower than safe limit of 1 and this result suggested that none of the population groups would likely to experience potential health risk due to exposure to heavy metals from indoor dust in the study area.

  17. Effect of Heavy Metal Present in Cement Dust on Soil and Plants of Nokha (Bikaner)

    OpenAIRE

    Dr.(Mrs).Suruchi Gupta; Sarika Sharma

    2013-01-01

    In Nokha(Bikaner) cement industries emittes cement dust in nearby farmers fields. In these industries cement dust emitted contains traces of hexavalent chromium and lead well above permissible limit in area under investigation. However, cadmium and nickel were found below limits prescribed. To analyse heavy metals viz, Cr+6, lead, Cadmium and nickel one hundred and twenty samples were collected from four directions on surface and 20 cm depth, and analyzed on atomic absorption spectrophotomete...

  18. Saharan dust - A carrier of persistent organic pollutants, metals and microbes to the Caribbean?

    Science.gov (United States)

    Garrison, V.H.; Foreman, W.T.; Genualdi, S.; Griffin, Dale W.; Kellogg, C.A.; Majewski, M.S.; Mohammed, A.; Ramsubhag, A.; Shinn, E.A.; Simonich, S.L.; Smith, G.W.

    2006-01-01

    An international team of scientists from government agencies and universities in the United States, U.S. Virgin Islands (USVI), Trinidad & Tobago, the Republic of Cape Verde, and the Republic of Mali (West Africa) is working together to elucidate the role Saharan dust may play in the degradation of Caribbean ecosystems. The first step has been to identify and quantify the persistent organic pollutants (POPs), trace metals, and viable microorganisms in the atmosphere in dust source areas of West Africa, and in dust episodes at downwind sites in the eastern Atlantic (Cape Verde) and the Caribbean (USVI and Trinidad & Tobago). Preliminary findings show that air samples from Mali contain a greater number of pesticides, polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) and in higher concentrations than the Caribbean sites. Overall, POP concentrations were similar in USVI and Trinidad samples. Trace metal concentrations were found to be similar to crustal composition with slight enrichment of lead in Mali. To date, hundreds of cultureable microorganisms have been identified from Mali, Cape Verde, USVI, and Trinidad air samples. The sea fan pathogen, Aspergillus sydowii, has been identified in soil from Mali and in air samples from dust events in the Caribbean. We have shown that air samples from a dust-source region contain orders of magnitude more cultureable microorganisms per volume than air samples from dust events in the Caribbean, which in turn contain 3-to 4-fold more cultureable microbes than during non-dust conditions.

  19. ALMA observations of cool dust in a low-metallicity starburst, SBS0335-052

    CERN Document Server

    Hunt, L K; Casasola, V; Garcia-Burillo, S; Combes, F; Nikutta, R; Caselli, P; Henkel, C; Maiolino, R; Menten, K M; Sauvage, M; Weiss, A

    2013-01-01

    We present Atacama Large Millimeter/submillimeter Array (ALMA) Cycle 0 Band 7 observations of an extremely metal-poor dwarf starburst galaxy in the Local Universe, SBS0335-052 (12+log(O/H)~7.2). With these observations, dust is detected at 870micron (ALMA Band 7), but 87% of the flux in this band is due to free-free emission from the starburst. We have compiled a spectral energy distribution (SED) of SBS0335-052 that spans almost 6 orders of magnitude in wavelength and fit it with a spherical dust shell heated by a single-age stellar population; the best-fit model gives a dust mass of (3.8+/-0.6)x10^4 Msun. We have also constructed a SED including Herschel archival data for IZw18, another low-metallicity dwarf starburst (12+log(O/H)=7.17), and fit it with a similar model to obtain a dust mass of (3.4+/-1.0)x10^2 Msun. Compared with their atomic gas mass, the dust mass of SBS0335-052 far exceeds the prediction of a linear trend of dust-to-gas mass ratio with metallicity, while IZw18 falls far below. We use gas...

  20. Evolution of Thermally Pulsing Asymptotic Giant Branch Stars III. Dust production at supersolar metallicities

    CERN Document Server

    Nanni, Ambra; Marigo, Paola; Girardi, Léo

    2013-01-01

    We extend the formalism presented in our recent calculations of dust ejecta from the Thermally Pulsing Asymptotic Giant Branch (TP-AGB) phase, to the case of super-solar metallicity stars. The TP-AGB evolutionary models are computed with the COLIBRI code. We adopt our preferred scheme for dust growth. For M-giants, we neglect chemisputtering by H$_2$ molecules and, for C-stars we assume a homogeneous growth scheme which is primarily controlled by the carbon over oxygen excess. At super-solar metallicities, dust forms more efficiently and silicates tend to condense significantly closer to the photosphere (r~1.5 R$_*$) - and thus at higher temperatures and densities - than at solar and sub-solar metallicities (r~2-3 R$_*$). In such conditions, the hypothesis of thermal decoupling between gas and dust becomes questionable, while dust heating due to collisions plays an important role. The heating mechanism delays dust condensation to slightly outer regions in the circumstellar envelope. We find that the same mech...

  1. Biomonitoring and speciation of road dust for heavy metals using Calotropis procera and Delbergia sissoo

    Directory of Open Access Journals (Sweden)

    Santosh Kumar Prajapati

    2012-12-01

    Full Text Available The present study was conducted for identifying the important heavy metals present in the road dust and at the same time biomonitor them using Calotropis procera and Delbergia sissoo leaves. The study clearly indicated that both the plants can be used as biomonitor for As, Pb, Fe, V, Cd, Cr, Zn and Cu. The heavy metals were estimated using AAS-7000 (Shimadzu. Reason for selecting the plants were their abundance in the area and high air pollution indices. Presence of these heavy metals in the road dust can be attributed to the red soil and more importantly thermal power plants operating in the study area. Since plants are able to capture the road dust, they can also prevent the particulate pollution which is having adverse health impacts for humans.

  2. Are the Formation and Abundances of Metal-Poor Stars the Result of Dust Dynamics?

    CERN Document Server

    Hopkins, Philip F

    2015-01-01

    Large dust grains can fluctuate dramatically in their local density, relative to gas, in neutral, turbulent disks. Small, high-redshift galaxies (before reionization) represent ideal environments for this process. We show via simple arguments and simulations that order-of-magnitude fluctuations are expected in local abundances of large grains under these conditions. This can have important consequences for star formation and stellar abundances in extremely metal-poor stars. Low-mass stars could form in dust-enhanced regions almost immediately after some dust forms, even if the galaxy-average metallicity is too low for fragmentation to occur. The abundances of these 'promoted' stars may contain interesting signatures, as the CNO abundances (concentrated in large carbonaceous grains and ices) and Mg and Si (in large silicate grains) can be enhanced or fluctuate independently. Remarkably, otherwise puzzling abundance patterns of some metal-poor stars can be well-fit by standard core-collapse SNe yields, if we al...

  3. Dust metal loadings and the risk of childhood acute lymphoblastic leukemia.

    Science.gov (United States)

    Whitehead, Todd P; Ward, Mary H; Colt, Joanne S; Dahl, Gary; Ducore, Jonathan; Reinier, Kyndaron; Gunier, Robert B; Katharine Hammond, S; Rappaport, Stephen M; Metayer, Catherine

    2015-01-01

    We evaluated the relationship between the risk of childhood acute lymphoblastic leukemia (ALL) and the levels of metals in carpet dust. A dust sample was collected from the homes of 142 ALL cases and 187 controls participating in the California Childhood Leukemia Study using a high volume small surface sampler (2001-2006). Samples were analyzed using microwave-assisted acid digestion in combination with inductively coupled plasma mass spectrometry for arsenic, cadmium, chromium, copper, lead, nickel, tin, tungsten, and zinc. Eight metals were detected in at least 85% of the case and control homes; tungsten was detected in nickel: 0.95 (0.82, 1.09), tin: 0.96 (0.86, 1.08), and zinc: 0.94 (0.84, 1.05)). Our findings do not support the hypothesis that metals in carpet dust are risk factors for childhood ALL.

  4. The metal and dust yields of the first massive stars

    CERN Document Server

    Marassi, S; Limongi, M; Chieffi, A; Bocchio, M; Bianchi, S

    2015-01-01

    We quantify the role of Population (Pop) III core-collapse supernovae (SNe) as the first cosmic dust polluters. Starting from a homogeneous set of stellar progenitors with masses in the range [13 - 80] Msun, we find that the mass and composition of newly formed dust depend on the mixing efficiency of the ejecta and the degree of fallback experienced during the explosion. For standard Pop III SNe, whose explosions are calibrated to reproduce the average elemental abundances of Galactic halo stars with [Fe/H] < -2.5, between 0.18 and 3.1 Msun (0.39 - 1.76 Msun) of dust can form in uniformly mixed (unmixed) ejecta, and the dominant grain species are silicates. We also investigate dust formation in the ejecta of faint Pop III SN, where the ejecta experience a strong fallback. By examining a set of models, tailored to minimize the scatter with the abundances of carbon-enhanced Galactic halo stars with [Fe/H ] < -4, we find that amorphous carbon is the only grain species that forms, with masses in the range 2...

  5. Pollution distribution and health risk assessment of heavy metals in indoor dust in Anhui rural, China.

    Science.gov (United States)

    Lin, Yuesheng; Fang, Fengman; Wang, Fei; Xu, Minglu

    2015-09-01

    Zn, Pb, Cu, Cr, V, Ni, Co, and As concentrations of indoor dust in Anhui rural were determined by inductively coupled plasma-optical emission spectroscopy (ICP-OES). The degrees of metal pollution in indoor dust ranked as follows: Zn > Pb > Cr > Cu > V > Ni > Co > As, on average. The arithmetic means of Zn, Pb, Cu, Cr, V, Ni, Co, and As were 427.17, 348.73, 107.05, 113.68, 52.64, 38.93, 10.29, and 4.46 mg/kg, respectively. These were higher than background values of Anhui soil for Zn, Pb, Cu, Cr, and Ni, especially for Pb with the mean value of 13.21 times the background value. Heavy metal concentrations of indoor dust were different from different rural areas. House type (bungalows or storied house), sweeping frequency, and external environment around the house (such as the road grade) affected heavy metal concentrations in indoor dust. The results of factor analysis and correlation analysis indicated that Cu, Cr, Ni, Zn, and Co concentrations were mainly due to interior paint, metal objects, and building materials. Pb and As concentrations were due to vehicle emissions. V concentration was mainly of natural source. Average daily doses for the exposure pathway of the studied heavy metals decreased in children in the following order: hand-to-mouth ingestion > dermal contact > inhalation. The non-carcinogenic risks of heavy metals ranked as Pb > V > Cr > Cu > Zn > As > Co > Ni, and the carcinogenic risks of metals decreased in the order of Cr > Co > As > Ni. The non-carcinogenic hazard indexes and carcinogenic risks of metals in indoor dust were both lower than the safe values.

  6. DUST-TO-GAS RATIO IN THE EXTREMELY METAL-POOR GALAXY I Zw 18

    Energy Technology Data Exchange (ETDEWEB)

    Herrera-Camus, Rodrigo; Fisher, David B.; Bolatto, Alberto D. [Department of Astronomy and Laboratory of Millimeter Astronomy, University of Maryland, College Park, MD 20742 (United States); Leroy, Adam K. [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22903-2475 (United States); Walter, Fabian [Max-Planck-Institut fuer Astronomie, Konigstuehl 17, D-69117 Heidelberg (Germany); Gordon, Karl D.; Roman-Duval, Julia [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Donaldson, Jessica; Melendez, Marcio [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Cannon, John M. [Department of Physics and Astronomy, Macalester College, 1600 Grand Avenue, Saint Paul, MN 55105 (United States)

    2012-06-20

    The blue compact dwarf galaxy I Zw 18 is one of the most metal-poor systems known in the local universe (12+log(O/H) = 7.17). In this work we study I Zw 18 using data from Spitzer, Herschel Space Telescope, and IRAM Plateau de Bure Interferometer. Our data set includes the most sensitive maps of I Zw 18, to date, in both the far-infrared and the CO J = 1 {yields} 0 transition. We use dust emission models to derive a dust mass upper limit of only M{sub dust} {<=} 1.1 Multiplication-Sign 10{sup 4} M{sub Sun} (3{sigma} limit). This upper limit is driven by the non-detection at 160 {mu}m, and it is a factor of 4-10 times smaller than previous estimates (depending on the model used). We also estimate an upper limit to the total dust-to-gas mass ratio of M{sub Dust}/M{sub gas} {<=} 5.0 Multiplication-Sign 10{sup -5}. If a linear correlation between the dust-to-gas mass ratio and metallicity (measured as O/H) were to hold, we would expect a ratio of 3.9 Multiplication-Sign 10{sup -4}. We also show that the infrared spectral energy distribution is similar to that of starbursting systems.

  7. Dust-to-Gas Ratio in the Extremely Metal Poor Galaxy I ZW 18

    CERN Document Server

    Herrera-Camus, Rodrigo; Bolatto, Alberto D; Leroy, Adam K; Walter, Fabian; Gordon, Karl D; Roman-Duval, Julia; Donaldson, Jessica; Meléndez, Marcio; Cannon, John M

    2012-01-01

    The blue compact dwarf galaxy I Zw 18 is one of the most metal poor systems known in the local Universe (12 + log(O/H) $=$ 7.17). In this work we study I Zw 18 using data from {\\it Spitzer}, {\\it Herschel Space Telescope} and IRAM Plateau de Bure Interferometer. Our data set includes the most sensitive maps of I Zw 18, to date, in both, the far infrared and the CO $J=1\\rightarrow0$ transition. We use dust emission models to derive a dust mass upper limit of only M$_{dust}\\leq1.1\\times10^4$ M$_{\\odot}$ ($3\\sigma$ limit). This upper limit is driven by the non-detection at 160 $\\mu$m, and it is a factor of 4-10 times smaller than previous estimates (depending upon the model used). We also estimate an upper limit to the total dust-to-gas mass ratio of M$_{Dust}$/M$_{gas}\\leq5.0\\times10^{-5}$. If a linear correlation between the dust-to-gas mass ratio and metallicity (measure as O/H) were to hold, we would expect a ratio of 3.9$\\times10^{-4}$. We also show that the infrared SED is similar to that of starbursting s...

  8. Dust May Be More Rare Than Expected in Metal Poor Galaxies

    CERN Document Server

    Fisher, David B; Herrera-Camus, Rodrigo; Draine, Bruce T; Donaldson, Jessica; Walter, Fabian; Sandstrom, Karin M; Leroy, Adam K; Cannon, John; Gordon, Karl

    2013-01-01

    'Normal' galaxies observed at z>6, when the Universe was <1 billion years old, thus far show no evidence of the cold dust that accompanies star formation in the local Universe, where the dust-to-gas mass ratio is 1%. A prototypical example is 'Himiko' (z=6.6), which a mere 840 Myr after the Big Bang is forming stars at a rate of 30-100 Msun/yr, yielding a mass assembly time M^{star}/SFR 150x10^6 yr. Himiko is estimated to have a low fraction (2-3% of the Solar value) of elements heavier than helium (metallicity), and although its gas mass cannot be asserted at this time its dust-to-stellar mass ratio is constrained to be <0.05%. The local galaxy I Zw 18, with a metallicity 4% solar and forming stars less rapidly than Himiko but still vigorously for its mass (M^{star}/SFR 1.6x10^9 yr), is also very dust deficient and perhaps one of the best analogues of primitive galaxies accessible to detailed study. Here we report observations of dust emission from I Zw 18 from which we determine its dust mass to be 45...

  9. Carbon-rich dust production in metal-poor galaxies in the Local Group

    CERN Document Server

    Sloan, G C; Lagadec, E; van Loon, J Th; Kraemer, K E; McDonald, I; Groenewegen, M A T; Wood, P R; Bernard-Salas, J; Zijlstra, A A

    2012-01-01

    We have observed a sample of 19 carbon stars in the Sculptor, Carina, Fornax, and Leo I dwarf spheroidal galaxies with the Infrared Spectrograph on the Spitzer Space Telescope. The spectra show significant quantities of dust around the carbon stars in Sculptor, Fornax, and Leo I, but little in Carina. Previous comparisons of carbon stars with similar pulsation properties in the Galaxy and the Magellanic Clouds revealed no evidence that metallicity affected the production of dust by carbon stars. However, the more metal-poor stars in the current sample appear to be generating less dust. These data extend two known trends to lower metallicities. In more metal-poor samples, the SiC dust emission weakens, while the acetylene absorption strengthens. The bolometric magnitudes and infrared spectral properties of the carbon stars in Fornax are consistent with metallicities more similar to carbon stars in the Magellanic Clouds than in the other dwarf spheroidals in our sample. A study of the carbon budget in these sta...

  10. Source identification of heavy metals in atmospheric dust using Platanus orientalis L. leaves as bioindicator

    Directory of Open Access Journals (Sweden)

    Samira Norouzi

    2015-07-01

    Full Text Available Studies on atmospheric dust have been limited by the high cost of instrumental monitoring methods and also sampling difficulties. The use of organisms acting as bioaccumulators has recently been proposed. In this study, the leaves of Platanus orientalis L., as a possible biomonitor of heavy metals in atmospheric dust, were evaluated to understand the likely source(s of pollution in Isfahan, Iran. Concentration of Zn, Cu, Ni and Mn and Magnetic susceptibility (χlf were determined in washed (WL and unwashed leaves (UL, monthly sampled from May to Nov., 2012. By subtracting the amount of metal concentrations and χlf in UL and WL, the amount of these parameters in dust deposited on the leaves (UL-WL were calculated. Enrichment factor analysis (EF, correlation coeficient, principal component analysis (PCA and cluster analysis (CA on the UL-WL data were employed to trace the heavy metals sources. Results showed that the metal concentration in UL and WL in primary sampling times was not statistically different. As time passed, this difference became more noticeable. Seasonal accumulation trends of elements concentration in UL-WL, referred to as accumulative biomonitors showing the accumulation of dust on the leaves are considerable and the contamination of plants by metal occurs mainly by retention of particulate matter. All the heavy metals are well correlated with χlf, indicating the potential of magnetic measurement as an inexpensive and less laborious method to estimate heavy metals. Cu and Zn exhibited a very strong correlation with each other and the highest correlation with χlf, suggesting an anthropogenic nature of these two metals. High EF of Cu and Zn showed that anthropogenic sources contribute a substantial amount of these metals to dust deposited on leaves. Whereas, less EF for Mn and Ni shows that natural source and local polluted soils might be the main origins of these metals. PCA results showed 2 principal components. Factor 1 with

  11. speciation of heavy metals in street dust samples from sakarya i ...

    African Journals Online (AJOL)

    Preferred Customer

    20 dust samples collected from the streets of the Organized Industrial District in ... The presence of heavy metals pollution is of great concern since their harmful effects on human ... The collected samples stored in air and moisture .... volume in the uncovered tube was reduced almost to dryness after cooling, 25 mL of 1 M.

  12. Effect of Heavy Metal Present in Cement Dust on Soil and Plants of Nokha (Bikaner

    Directory of Open Access Journals (Sweden)

    Dr.(Mrs.Suruchi Gupta

    2013-08-01

    Full Text Available In Nokha(Bikaner cement industries emittes cement dust in nearby farmers fields. In these industries cement dust emitted contains traces of hexavalent chromium and lead well above permissible limit in area under investigation. However, cadmium and nickel were found below limits prescribed. To analyse heavy metals viz, Cr+6, lead, Cadmium and nickel one hundred and twenty samples were collected from four directions on surface and 20 cm depth, and analyzed on atomic absorption spectrophotometer. From the above study it is clear that in case of Sarvottam cement works only lead content was higher in all directions and depths than other two plants. At tiger and Nokha cement works contamination of lead was more over limited in the first 1 km except in east direction. Mobility of lead was relatively more on top soil than 20cm depth. Hexavalent chromium content in south western direction was more for Nokha cement. Whereas, it was more in east direction in case of tiger cement. This indicated influence of prevailing direction of wind on distribution of heavy metals present in cement dust.Heavy metal toxicity results in reduction in plant height, burning of leaf margins and tip, slow leaf growth and over all wilting of Prosopis cineraria, Pearlmillet and clusterbean plants, when this metal deposits in Human body results in genetic disorders. Electrostatic precipitator can be installed to reduce the cement dust emission.

  13. Identifying Hot-Spots of Metal Contamination in Campus Dust of Xi’an, China

    Directory of Open Access Journals (Sweden)

    Hao Chen

    2016-06-01

    Full Text Available The concentrations of heavy metals (As, Ba, Co, Cr, Cu, Mn, Ni, Pb, V, and Zn in campus dust from kindergartens, elementary schools, middle schools, and universities in the city of Xi’an, China, were determined by X-ray fluorescence spectrometry. The pollution levels and hotspots of metals were analyzed using a geoaccumulation index and Local Moran’s I, an indicator of spatial association, respectively. The dust samples from the campuses had metal concentrations higher than background levels, especially for Pb, Zn, Co, Cu, Cr, and Ba. The pollution assessment indicated that the campus dusts were not contaminated with As, Mn, Ni, or V, were moderately or not contaminated with Ba and Cr and were moderately to strongly contaminated with Co, Cu, Pb, and Zn. Local Moran’s I analysis detected the locations of spatial clusters and outliers and indicated that the pollution with these 10 metals occurred in significant high-high spatial clusters, low-high, or even high-low spatial outliers. As, Cu, Mn, Ni, Pb, V, and Zn had important high-high patterns in the center of Xi’an. The western and southwestern regions of the study area, i.e., areas of old and high-tech industries, have strongly contributed to the Co content in the campus dust.

  14. Assessing the bioavailability and risk from metal contaminated soils and dusts#

    Science.gov (United States)

    Exposure to contaminated soil and dust is an important pathway in human and ecological risk assessment and often is the "risk-driver" for metal contaminated soil. Site-specific soil physical and chemical characteristics, as well as biological factors, determine the bioavailabilit...

  15. Middle East Desert Dust Exposure: Health Risks from Metals and Microbial Pathogens

    Science.gov (United States)

    Lyles, M. B.

    2014-12-01

    In the Middle East, dust and sand storms are a persistent problem and can deliver significant amounts of micro-particulates via inhalation into the mouth, nasal pharynx, & lungs due to the fine size and abundance of these micro-particulates. The chronic and acute health risks of this dust inhalation have not been well studied nor has the dust been effectively characterized as to its chemical composition, mineral content, or microbial flora. Scientific experiments were designed to study the Kuwaiti and Iraqi dust as to its physical, chemical, and biological characteristics and for its potential to cause adverse health effects. First, dust samples from different locations were collected and processed and exposure data collected. Initial chemical and physical characterization of each sample including particle size distribution and inorganic analysis was conducted, followed by characterization of biologic flora of the dust, including bacteria, fungi and viruses. Data indicates that the mineralized dust is composed of calcium carbonate over a matrix of metallic silicate nanocrystals containing a variety of trace and heavy metals constituting ~3 % of the PM10 particles by weight, of which ~1% is bioaccessible aluminum and reactive iron, each. The particles also consist of ~1% bioavailable aluminum and reactive iron each. Microbial analysis reveals a significant biodiversity of bacterial, fungi, and viruses of which ~30% are known pathogens. Of the microbes identified, several have hemolytic properties and most have significant antibiotic resistance. Viral analysis indicates a tremendous amount of virons with a large percent of RNA viruses. The level of total suspended particle mass at PM 10 along with environmental & physiological conditions present constitute an excessive exposure to micro-particulates including PM 2.5 and the potential for adverse health effects. Reported data on cell culture and animal studies have indicated a high level of toxicity to these dust

  16. Biomagnetic monitoring of heavy metals contamination in deposited atmospheric dust, a case study from Isfahan, Iran.

    Science.gov (United States)

    Norouzi, Samira; Khademi, Hossein; Cano, Angel Faz; Acosta, Jose A

    2016-05-15

    Tree leaves are considered as one of the best biogenic dust collectors due to their ability to trap and retain particulate matter on their surfaces. In this study, the magnetic susceptibility (MS) and the concentration of selected heavy metals of plane tree (Platanus orientalis L.) leaves and deposited atmospheric dust, sampled by an indirect and a direct method, respectively, were determined to investigate the relationships between leaf magnetic parameters and the concentration of heavy metals in deposited atmospheric dust. The objective was to develop a biomagnetic method as an alternative to the common ones used for determining atmospheric heavy metal contaminations. Plane tree leaves were monthly sampled on the 19th of May to November, 2012 (T1-T7), for seven months from 21 different sites in the city of Isfahan, central Iran. Deposited atmospheric dust samples were also collected using flat glass surfaces from the same sites on the same dates, except for T1. MS (χlf, χhf) values in washed (WL) and unwashed leaves (UL) as well as Cu, Fe, Mn, Ni, Pb, and Zn concentrations in UL and deposited atmospheric dust samples were determined. The results showed that the MS content with a biogenic source was low with almost no significant change during the sampling period, while an increasing trend was observed in the MS content of UL samples due to the deposition of heavy metals and magnetic particles on leaf surfaces throughout the plant growth. The latter type of MS content could be reduced through washing off by rain. Most heavy metals examined, as well as the Tomlinson pollution load index (PLI) in UL, showed statistically significant correlations with MS values. The correlation between heavy metals content in atmospheric dust deposited on glass surfaces and leaf MS values was significant for Cu, Fe, Pb, and Zn. Moreover, the similarity observed between the spatial distribution maps of leaf MS and deposited atmospheric dust PLI provided convincing evidence regarding

  17. [Bioavailability of heavy metals in urban surface dust and rainfall-runoff system].

    Science.gov (United States)

    Chang, Jing; Liu, Min; Li, Xian-hua; Lin, Xiao; Wang, Li-li; Gao, Lei

    2009-08-15

    A sequential digest was used to examine the speciation of particulate-associated heavy metals in multi-media environment of surface dust and rainfall-runoff system. Within the Shanghai central district, different environment medium in four sites were sampled including street dust, runoff suspended particles, gully pot sediment and river sediment during April 2006. The result shows that in the study area, heavy metal concentrations of surface dusts are significantly higher than the Shanghai soil background values and the nonpoint runoff pollution of Pb, Cr and Ni are serious while Cd, Cu and Zn pollution degree relatively light. In the multi-media transport process, the order of heavy metal bioavailability is Zn > Ni > Cd> Cu > Pb > Cr. For Cr, Zn and Cu, the dominated chemical forms of the four different environmental media remain the same phase of residual, carbonates and organic fractions respectively. For Ni, the main fraction of surface dust is associated with residual form, while the other three media become associated with carbonate fractions. For Cd, the surface dust is mainly associated with carbonates, while runoff particles mainly with labile fractions. The dominated chemical form of Pb also changes from Fe/Mn oxides phase to organic phase. The runoff particles contain the highest percentage of the labile fraction (F1 + F2), and the mean value of transporting ratio of the runoff suspended particles equals to 1.74, indicating that in urban runoff water, the high bioavailability of the heavy metals and the potential toxicity effect deserves our attention greatly. In gutter inlet and rivers deposit components, the low percentages of the labile fraction and the higher content of residual fraction reduce the environmental risk of the heavy metals and act as the sink of these elements.

  18. Spatially resolved dust emission of extremely metal-poor galaxies

    OpenAIRE

    Zhou, Luwenjia; Shi, Yong; Diaz-Santos, Taino; Armus, Lee; Helou, George; Stierwalt, Sabrina; Li, Aigen

    2016-01-01

    We present infrared (IR) spectral energy distributions (SEDs) of individual star-forming regions in four extremely metal-poor (EMP) galaxies with metallicity Z ≲ Z_⊙/10 as observed by the Herschel Space Observatory. With the good wavelength coverage of the SED, it is found that these EMP star-forming regions show distinct SED shapes as compared to those of grand design Spirals and higher metallicity dwarfs: they have on average much higher f_(70μm)/f_(160 μm) ratios at a given f_(160 μm)/f_(2...

  19. The role of dust in "active" and "passive" low-metallicity star formation

    CERN Document Server

    Hirashita, N

    2004-01-01

    We investigate the role of dust in star formation activity of extremely metal-poor blue compact dwarf galaxies (BCDs). Observations suggest that star formation in BCDs occurs in two different regimes: "active" and "passive". The "active" BCDs host super star clusters (SSCs), and are characterised by compact size, rich H2 content, large dust optical depth, and high dust temperature; the "passive" BCDs are more diffuse with cooler dust, and lack SSCs and large amounts of H2. By treating physical processes concerning formation of stars and dust, we are able to simultaneously reproduce all the above properties of both modes of star formation (active and passive). We find that the difference between the two regimes can be understood through the variation of the "compactness" of the star-forming region: an "active" mode emerges if the region is compact (with radius $\\la 50$ pc) and dense (with gas number density $\\ga 500$ cm$^{-3}$). The dust, supplied from Type II supernovae in a compact star-forming region, effec...

  20. Saharan dust - a carrier of persistent organic pollutants, metals and microbes to the Caribbean?

    Directory of Open Access Journals (Sweden)

    V.H Garrison

    2006-12-01

    Full Text Available An international team of scientists from government agencies and universities in the United States, U.S. Virgin Islands (USVI, Trinidad & Tobago, the Republic of Cape Verde, and the Republic of Mali (West Africa is working together to elucidate the role Saharan dust may play in the degradation of Caribbean ecosystems. The first step has been to identify and quantify the persistent organic pollutants (POPs, trace metals, and viable microorganisms in the atmosphere in dust source areas of West Africa, and in dust episodes at downwind sites in the eastern Atlantic (Cape Verde and the Caribbean (USVI and Trinidad & Tobago. Preliminary findings show that air samples from Mali contain a greater number of pesticides, polychlorinated biphenyls (PCBs and polycyclic aromatic hydrocarbons (PAHs and in higher concentrations than the Caribbean sites. Overall, POP concentrations were similar in USVI and Trinidad samples. Trace metal concentrations were found to be similar to crustal composition with slight enrichment of lead in Mali. To date, hundreds of cultureable micro-organisms have been identified from Mali, Cape Verde, USVI, and Trinidad air samples. The sea fan pathogen, Aspergillus sydowii, has been identified in soil from Mali and in air samples from dust events in the Caribbean. We have shown that air samples from a dust-source region contain orders of magnitude more cultureable micro-organisms per volume than air samples from dust events in the Caribbean, which in turn contain 3-to 4-fold more cultureable microbes than during non-dust conditions. Rev. Biol. Trop. 54 (Suppl. 3: 9-21. Epub 2007 Jan. 15.

  1. Health risk implications of potentially toxic metals in street dust and surface soil of Tehran, Iran.

    Science.gov (United States)

    Dehghani, Sharareh; Moore, Farid; Keshavarzi, Behnam; Hale, Beverley A

    2017-02-01

    In this study a total of 30 street dusts and 10 surface soils were collected in the central district of Tehran and analyzed for major potentially toxic metals. Street dust was found to be greatly enriched in Sb, Pb, Cu and Zn and moderately enriched in Cr, Mn, Mo and Ni. Contamination of Cu, Sb, Pb and Zn was clearly related to anthropogenic sources such as brake wear, tire dust, road abrasion and fossil fuel combustion. Spatial distribution of pollution load index in street dust suggested that industries located south-west of the city intensify street dust pollution. Microscopic studies revealed six dominant group of morphological structures in calculation of the exposurethe street dusts and surface soils, with respect to different geogenic and anthropogenic sources. The BCR (the European Community Bureau of Reference) sequential extraction results showed that Sb, Ni, Mo, As and Cr bonded to silicates and sulfide minerals were highly resistant to dissolution. In contrast, Zn, Cd, and Mn were mostly associated with the exchangeable phase and thus would be easily mobilized in the environment. Cu was the most abundant metal in the reducible fraction, indicating its adsorption to iron and manganese oxy-hydroxides. Pb was equally extracted from exchangeable and reducible fractions. Anthropogenic sources related to traffic apparently play a small role in Cr, Ni and Mo contamination and dispersed them as bioavailable forms but with reduced mobility and bioavailablity due to high potential of complexation and adsorption to organic matter and iron and manganese oxy-hydroxides. Calculated Hazard Index (HI) suggests ingestion as the most important pathway for the majority of PTMs in children and dermal contact as the main exposure route for Cr, Cd and Sb for adults. The HIs and fractionation pattern of elements revealed Pb as the sole element that bears potential health risk in street dust and surface soil. Copyright © 2016 Elsevier Inc. All rights reserved.

  2. Impact of dust filter installation in ironworks and construction on brownfield area on the toxic metal concentration in street and house dust (Celje, Slovenia).

    Science.gov (United States)

    Zibret, Gorazd

    2012-05-01

    This article presents the impact of the ecological investment in ironworks (dust filter installation) and construction works at a highly contaminated brownfield site on the chemical composition of household dust (HD) and street sediment (SS) in Celje, Slovenia. The evaluation is based on two sampling campaigns: the first was undertaken 1 month before the ecological investment became operational and the second 3 years later. The results show that dust filter installations reduced the content of Co, Cr, Fe, Mn, Mo, W and Zn on average by 58% in HD and by 51% in SS. No reduction was observed at sampling points in the upwind direction from the ironworks. By contrast, the impact of the construction works on the highly contaminated brownfield site was detected by a significant increase (on average by 37%) of elements connected to the brownfield contamination in SS. Such increase was not detected in HD.

  3. Distribution Pattern of Metals in Atmospheric Settling Dust along Roads in Kano Metropolis, Nigeria

    Directory of Open Access Journals (Sweden)

    O. J. Okunola

    2015-01-01

    Full Text Available The sequential extraction of Cd, Cr, Ni, Pb, Cu, and Zn in atmospheric dust particles collected along ten high traffic roads in Kano metropolis was carried out. Analyses of metals in the extracts were done using flame atomic absorption spectrometry (FAAS. The samples analyzed for metals indicated high levels of Cd, Cr, Ni, Pb, Cu, and Zn in the atmospheric dust samples. The sequential extractions that showed significant amount of Cd were associated with CO32- and Fe-MnO fractions especially during the dry seasons. For Cr and Ni, their occlusion in crystal lattice of the soil fraction exhibited the highest percentage. Pb in the particulate dust samples is significantly associated with the carbonate bound fraction with range of 8.81–64.69% across the season. The behaviour of Cu is quite different from other metals in that percentage fractions are higher in the organic bound. As for Zn, significant amounts were associated with the residue fractions ranging from 0.96 to 87.50% across the seasons. This study revealed contamination of the particulate dust with Cd and Pb; this implies health risks to human, living or carrying out daily activities along the corridors of these roads.

  4. Heavy metals and polycyclic aromatic hydrocarbons: pollution and ecological risk assessment in street dust of Tehran.

    Science.gov (United States)

    Saeedi, Mohsen; Li, Loretta Y; Salmanzadeh, Mahdiyeh

    2012-08-15

    50 street dust samples from four major streets in eastern and southern Tehran, the capital of Iran, were analyzed for metal pollution (Cu, Cr, Pb, Ni, Cd, Zn, Fe, Mn and Li). Hakanson's method was used to determine the Risk Index (RI) and ecological risks. Amongst these samples, 21 were also analyzed for polycyclic aromatic hydrocarbons (PAHs). Correlation, cluster and principal component analyses identified probable natural and anthropogenic sources of contaminants. The dust had elevated concentrations of Pb, Cd, Cu, Cr, Ni, Zn, Fe and PAHs. Enrichment factors of Cu, Pb, Cd and Zn showed that the dust is extremely enriched in these metals. Multivariate statistical analyses revealed that Cu, Pb, Zn, Fe and PAHs and, to a lesser extent, Cr and Ni have common anthropogenic sources. While Mn and Li were identified to have natural sources, Cd may have different anthropogenic origins. All samples demonstrated high ecological risk. Traffic and related activities, petrogenic and pyrogenic sources are likely to be the main anthropogenic sources of heavy metals and PAHs in Tehran dust.

  5. [Speciation Distribution and Risk Assessment of Heavy Metals in Typical Material Roof Dusts].

    Science.gov (United States)

    Li, Dun-zhu; Guan, Yun-tao; Liu, An; Li, Si-yuan

    2015-09-01

    With the modified BCR sequential extraction procedure, the chemical speciation and risk for 10 heavy metals (Ba, Co, Cr, Cu, Mn, Ni, Pb, Sb, Sr and Zn) in roof dusts were investigated. The subjects of this study were collected from four typical material paved roofs (i. e., ceramic tile, concrete, metal and asphalt) in southeast China. The results indicated that the average contents of heavy metals in roof dust significantly exceeded road dust. The analysis of chemical fraction showed that the acid soluble/exchangeable fraction of Zn was much higher than other elements, the existence of Pb and Cu was mainly in oxidization fraction, while other heavy metals dominated by the residual fraction. The mobility sequence percentages for all roof dust samples decreased in the order of Pb > Zn > Cu >Mn > Co >Sr > Sb > Ni > Ba > Cr, and it should be noted that Pb, Zn, Cu, Mn and Co all have more than 50% proportion in mobility sequence. Based on environmental risk assessment, the highest values of contamination factors (Cf) and risk assessment code (RAC) consistently was observed in Zn, which indicated that Zn had relatively high ecological risk. Health risk assessment showed that the non-carcinogenic hazard indexes (HI) of heavy metals decreased in the order of Pb > Cr > Sb > Zn > Mn > Cu > Ba > Ni > Co > Sr, the HI of heavy metals for adults were lower than safe value while the HI of Pb for children was higher than safe value, suggesting that they will not harm the adult's health except Pb for children. The carcinogenic risk for Cr, Co and Ni were all below the threshold values, which indicated that there was no carcinogenic risk.

  6. Heavy metal distribution in dust from elementary schools in Hermosillo, Sonora, México

    Science.gov (United States)

    Meza-Figueroa, Diana; De la O-Villanueva, Margarita; De la Parra, Maria Luisa

    The city of Hermosillo, Sonora in northern Mexico was investigated for its heavy metals content. Samples of sedimented dust in roofs from 25 elementary schools were analyzed for their contents of Ni, Cr, Zn, Cd, Co, Ba, V, Pb, Fe and Cu after digestion with nitric acid. The results of the analysis were used to determine spatial distribution and magnitude of heavy metals pollution. The results of this study reveal that heavy metals distribution is different in two areas of the city. The southern area contains higher concentrations of heavy metals than the northcentral area. The mean level of Cd in exterior dust is 5.65 mg kg -1 in the southern area whereas the mean level of Cd is 2.83 mg kg -1 in the northcentral area. Elevated concentrations of Zn (2012 mg kg -1), Pb (101.88 mg kg -1), Cr (38.13 mg kg -1) and Cd (28.38 mg kg -1) in roof dust were found in samples located near industrial areas. Principal component analysis (PCA) was applied to the data matrix to evaluate the analytical results and to identify the possible pollution sources of metals. PCA shows two main sources: (1) Pb, Cd, Cr and Zn are mainly derived from industrial sources, combined with traffic sources; (2) Fe, Co and Ba are mainly derived from natural sources. V and Ni are highly correlated and possibly related to fuel combustion processes. Enrichment factors were calculated, which in turn further confirms the source identification. Ba and Co are dominantly crustal. Anthropogenically added Cd, Pb, Zn and Cr show maximum enrichment relative to the upper continental crustal component. The distribution of the heavy metals in dust does not seem to be controlled only by the topography of the city, but also by the location of the emission sources.

  7. AN INFRARED CENSUS OF DUST IN NEARBY GALAXIES WITH SPITZER (DUSTiNGS). II. DISCOVERY OF METAL-POOR DUSTY AGB STARS

    Energy Technology Data Exchange (ETDEWEB)

    Boyer, Martha L.; Sonneborn, George [Observational Cosmology Lab, Code 665, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); McQuinn, Kristen B. W.; Gehrz, Robert D.; Skillman, Evan [Minnesota Institute for Astrophysics, School of Physics and Astronomy, 116 Church Street SE, University of Minnesota, Minneapolis, MN 55455 (United States); Barmby, Pauline [Department of Physics and Astronomy, University of Western Ontario, London, ON N6A 3K7 (Canada); Bonanos, Alceste Z. [IAASARS, National Observatory of Athens, GR-15236 Penteli (Greece); Gordon, Karl D.; Meixner, Margaret [STScI, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Groenewegen, M. A. T. [Royal Observatory of Belgium, Ringlaan 3, B-1180 Brussels (Belgium); Lagadec, Eric [Laboratoire Lagrange, UMR7293, Univ. Nice Sophia-Antipolis, CNRS, Observatoire de la Côte d' Azur, F-06300 Nice (France); Lennon, Daniel [ESA-European Space Astronomy Centre, Apdo. de Correo 78, E-28691 Villanueva de la Cañada, Madrid (Spain); Marengo, Massimo [Department of Physics and Astronomy, Iowa State University, Ames, IA 50011 (United States); McDonald, Iain; Zijlstra, Albert [Jodrell Bank Centre for Astrophysics, Alan Turing Building, University of Manchester, Manchester M13 9PL (United Kingdom); Sloan, G. C. [Astronomy Department, Cornell University, Ithaca, NY 14853-6801 (United States); Van Loon, Jacco Th., E-mail: martha.boyer@nasa.gov [Astrophysics Group, Lennard-Jones Laboratories, Keele University, Staffordshire ST5 5BG (United Kingdom)

    2015-02-10

    The DUSTiNGS survey (DUST in Nearby Galaxies with Spitzer) is a 3.6 and 4.5 μm imaging survey of 50 nearby dwarf galaxies designed to identify dust-producing asymptotic giant branch (AGB) stars and massive stars. Using two epochs, spaced approximately six months apart, we identify a total of 526 dusty variable AGB stars (sometimes called ''extreme'' or x-AGB stars; [3.6]-[4.5] > 0.1 mag). Of these, 111 are in galaxies with [Fe/H] < –1.5 and 12 are in galaxies with [Fe/H] < –2.0, making them the most metal-poor dust-producing AGB stars known. We compare these identifications to those in the literature and find that most are newly discovered large-amplitude variables, with the exception of ≈30 stars in NGC 185 and NGC 147, 1 star in IC 1613, and 1 star in Phoenix. The chemical abundances of the x-AGB variables are unknown, but the low metallicities suggest that they are more likely to be carbon-rich than oxygen-rich and comparisons with existing optical and near-IR photometry confirm that 70 of the x-AGB variables are confirmed or likely carbon stars. We see an increase in the pulsation amplitude with increased dust production, supporting previous studies suggesting that dust production and pulsation are linked. We find no strong evidence linking dust production with metallicity, indicating that dust can form in very metal-poor environments.

  8. Impact of overland traffic on heavy metal levels in highway dust and soils of Istanbul, Turkey.

    Science.gov (United States)

    Guney, Mert; Onay, Turgut T; Copty, Nadim K

    2010-05-01

    The purpose of this study was to investigate the impact of overland traffic on the spatial distribution of heavy metals in urban soils (Istanbul, Turkey). Road dust, surface, and subsurface soil samples were collected from a total of 41 locations along highways with dense traffic and secondary roads with lower traffic and analyzed for lead (Pb), zinc (Zn), and copper (Cu) concentrations. Statistical evaluation of the heavy metal concentrations observed along highways and along the secondary roads showed that the data were bimodally distributed. The maximum observed Pb, Zn, and Cu concentrations were 1,573, 522 and 136 mg/kg, respectively, in surface soils along highways and 99.3, 156, and 38.1 mg/kg along secondary roads. Correlation analysis of the metal concentrations in road dust, surface and 20-cm depth soils suggests the presence of a common pollution source. However, metal concentrations in the deeper soils were substantially lower than those observed at the surface, indicating low mobility of heavy metals, especially for Pb and Zn. A modified kriging approach that honors the bimodality of the data was used to estimate the spatial distribution of the surface concentrations of metals, and to identify hotspots. Results indicate that despite the presence of some industrial zones within the study area, traffic is the main heavy metal pollution source.

  9. Gas-to-Dust mass ratios in local galaxies over a 2 dex metallicity range

    CERN Document Server

    Rémy-Ruyer, A; Galliano, F; Galametz, M; Takeuchi, T T; Asano, R S; Zhukovska, S; Lebouteiller, V; Cormier, D; Jones, A; Bocchio, M; Baes, M; Bendo, G J; Boquien, M; Boselli, A; DeLooze, I; Doublier-Pritchard, V; Hughes, T; Karczewski, O Ł; Spinoglio, L

    2013-01-01

    This paper analyses the behaviour of the gas-to-dust mass ratio (G/D) of local Universe galaxies over a large metallicity range. We combine three samples: the Dwarf Galaxy Survey, the KINGFISH survey and a subsample from Galametz et al. (2011) totalling 126 galaxies, covering a 2 dex metallicity range, with 30% of the sample with 12+log(O/H) < 8.0. The dust masses are homogeneously determined with a semi-empirical dust model, including submm constraints. The atomic and molecular gas masses are compiled from the literature. Two XCO are used to estimate molecular gas masses: the Galactic XCO, and a XCO depending on the metallicity (as Z^{-2}). Correlations with morphological types, stellar masses, star formation rates and specific star formation rates are discussed. The trend between G/D and metallicity is empirically modelled using power-laws (slope of -1 and free) and a broken power-law. We compare the evolution of the G/D with predictions from chemical evolution models. We find that out of the five tested...

  10. Exposure to wood dust and heavy metals in workers using CCA pressure-treated wood.

    Science.gov (United States)

    Decker, Paul; Cohen, Beverly; Butala, John H; Gordon, Terry

    2002-01-01

    Chemical pesticide treatment enables relatively nonresistant woods to be used in outdoor construction projects. The most prevalent procedure used to protect these woods is pressure treatment with chromium, copper, and arsenic (CCA). This pilot study examined the airborne concentration and particle size distribution of wood particles, chromium, copper, and arsenic at both outdoor (measured over the whole work day) and indoor (measured during the performance of specific tasks) work sites. At the outdoor residential deck construction sites, the arithmetic mean total dust concentration, measured using personal filter cassette samplers, was 0.57 mg/m3. The mass median aerodynamic diameter (da) of the outdoor wood dust was greater than 20 microm. Indoor wood dust concentrations were significantly greater than those measured outdoor and were job category-dependent. The highest mean breathing zone dust concentration, 49.0 mg/m3, was measured at the indoor sanding operation. Personal impactor sampling demonstrated that the mean total airborne concentration of arsenic, but not chromium or copper, was consistently above recommended occupational exposure levels at the indoor work site, and occasionally at the outdoor work sites. At the indoor sanding operation, the mean total chromium, copper, and arsenic concentrations were 345, 170, and 342 microg/m3, respectively. Thus, significant exposure to airborne heavy metals can occur as a result of indoor and outdoor exposure to CCA pressure-treated wood dust. Therefore, current standards for wood dust may not adequately protect workers from the heavy metals commonly used in CCA pressure-treated wood.

  11. Impacts of crystal metal on secondary aliphatic amine aerosol formation during dust storm episodes in Beijing

    Science.gov (United States)

    Liu, Qingyang; Bei, Yiling

    2016-03-01

    Trimethylamine (TMA) enters the atmosphere from a variety of sources and is a ubiquitous atmospheric organic base. The atmospheric reaction mechanism of TMA with key atmospheric oxidants is important to predict its distribution and environmental behavior in the particle phase. While previous studies have extensively focused on the production of particle amine salts (i.e. trimethylamine-N-oxide (TMAO)) using chamber experiments, the atmospheric behavior of TMAO in the environment is still poorly understood. Ambient fine particulate matter (PM2.5) was collected at two sampling sites in Beijing from March 10 to May 10, 2012. We analyzed the samples for water-soluble ions, crystal metals, TMA, and TMAO. Water-soluble ions (e.g. SO42-, NO3-, NH4+), TMA, and TMAO were measured using ion chromatography, while crystal metal (e.g. Al, Fe, Mn) in PM2.5 was quantified by inductively coupled plasma mass spectrometry (ICP-MS). Two dust storms (DS) occurred during the sampling period on March 28 and April 28. Mineral dust impacted PM2.5 mass and composition greatly during dust storm days, as it contributed approximately 1.2-4.0 times greater on dust storm days versus non-dust storm days. We found TMAO concentrations were highly associated with aluminum in PM2.5. Further, we applied the density functional theory (DFT) method to confirm that aluminum plays a catalytic effect in the reaction of TMA with ozone (O3). Our work improves understanding of the effect of crystal metals on secondary aliphatic amine aerosol formation in the atmosphere.

  12. The transition from carbon dust to silicates production in low-metallicity AGB and SAGB stars

    CERN Document Server

    Ventura, P; Schneider, R; Carini, R; Valiante, R; D'Antona, F; Gallerani, S; Maiolino, R; Tornambé, A

    2011-01-01

    We compute the mass and composition of dust produced by stars with masses in the range 1Msunmetallicity of Z=0.001 during their AGB and Super AGB phases. Stellar evolution is followed from the pre-main sequence phase using the code ATON which provides, at each timestep, the thermodynamics and the chemical stucture of the wind. We use a simple model to describe the growth of the dust grains under the hypothesis of a time-independent, spherically symmetric stellar wind. We find that the total mass of dust injected by AGB stars in the interstellar medium does not increase monotonically with stellar mass and ranges between a minimum of 10^{-6}Msun for the 1.5Msun stellar model, up to 2x10^{-4} Msun, for the 6Msun case. Dust composition depends on the stellar mass: low-mass stars (M < 3Msun) produce carbon-rich dust, whereas more massive stars, experiencing Hot Bottom Burning, never reach the carbon-star stage, and produce silicates and iron. This is in partial disagreement with previ...

  13. Heavy Metal Pollution in the Floor Dust of Yazd Battery Repairing Workshops in 2014

    Directory of Open Access Journals (Sweden)

    M Sabouhi

    2016-06-01

    Full Text Available Background and Objectives: The presence of industrial workshops has increased urban pollution. This study aimed to investigate the heavy metal pollutants of Yazd battery repairing workshops and to identify the ecological and environmental effects resulted. Materials and Methods: This descriptive cross-sectional study was carried out in Yazd. In this regard, the city was divided into three parts on the basis of geographical features. Then, 30 workshops were selected from each part through stratified random sampling method. Heavy metals (Pb, Cd, Cr, Zn, Cu, Fe, Mn in the floor were measured using atomic absorption spectrophotometry (AAS. The impacts assessment of heavy metals was evaluated using environmental potential risk index (RI, cumulative pollution index (IPI, pollution coefficient factor (Cf, and the degree of modified contamination (mCd and Pearson’s correlation statistical test. Results: The trend of heavy metals concentrations in floor dust particles of workshops was as Fe>Cu>Pb>Zn>Mn>Cr>Cd. Therefore, the average concentrations of Fe and Cd in the samples were 27011.52 ±4721.05 and 78.25±21.07 mg/kg respectively. The results of the RI showed that heavy metal of floor dust had very high danger (2816.29. The mCd value was as 63.35 indicating these workshops were at severe contamination class. The value of Cf was as 304.17 revealing that these workshops were at very severe contamination class. Conclusions: This research showed that the high concentration of heavy metals in battery repairing workshops is due to the interaction of heavy metals of industrial wastes components, including electrical wastes and battery with the dust having mankind origin.

  14. Heavy metal speciation in various grain sizes of industrially contaminated street dust using multivariate statistical analysis.

    Science.gov (United States)

    Yıldırım, Gülşen; Tokalıoğlu, Şerife

    2016-02-01

    A total of 36 street dust samples were collected from the streets of the Organised Industrial District in Kayseri, Turkey. This region includes a total of 818 work places in various industrial areas. The modified BCR (the European Community Bureau of Reference) sequential extraction procedure was applied to evaluate the mobility and bioavailability of trace elements (Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in street dusts of the study area. The BCR was classified into three steps: water/acid soluble fraction, reducible and oxidisable fraction. The remaining residue was dissolved by using aqua regia. The concentrations of the metals in street dust samples were determined by flame atomic absorption spectrometry. Also the effect of the different grain sizes (Cu (48.9)>Pb (42.8)=Cr (42.1)>Ni (41.4)>Zn (40.9)>Co (36.6)=Mn (36.3)>Fe (3.1). No significant difference was observed among metal partitioning for the three particle sizes. Correlation, principal component and cluster analysis were applied to identify probable natural and anthropogenic sources in the region. The principal component analysis results showed that this industrial district was influenced by traffic, industrial activities, air-borne emissions and natural sources. The accuracy of the results was checked by analysis of both the BCR-701 certified reference material and by recovery studies in street dust samples.

  15. Pollution and health risk of potentially toxic metals in urban road dust in Nanjing, a mega-city of China.

    Science.gov (United States)

    Liu, Enfeng; Yan, Ting; Birch, Gavin; Zhu, Yuxin

    2014-04-01

    Spatial variations in concentrations of a suite of potentially toxic metals (Ba, Cr, Cu, Fe, Mn, Ni, Pb and Zn) and Ca in road dusts (n=99) from urban trunk roads (TR) in Nanjing, a mega-city in China, were established. Metal pollution levels, sources and human health risk (non-carcinogenic) were studied. In contrast to previous studies, we labeled the indicative metals relating to non-exhaust traffic emissions by comparing metal pollution between crossroad and park road dusts, and then anthropogenic sources of metals in TR dusts were assessed combining their spatial pollution patterns, principal component analysis and Pb isotopic compositions. Results showed that the metals were enriched in TR dusts compared to background soil concentrations with mean enrichment factors (EFs) of 2.2-23, indicating considerable anthropogenic influence. The degrees of metal pollution ranged from minimal to extremely high and ranked by Ca>Cu>Pb≈Zn>Cr≈Fe>Ni≈Ba>Mn on average. Pollution of Cr, Cu, Fe, Mn, Ni, Pb and Zn in TR dusts resulted primarily from industrial emissions (e.g., coal combustion and smelting) and high pollution levels were found close to suburb industrial complexes, whereas pollution of Ba and Ca was mainly related to construction/demolition sources and was generally distributed homogeneously. The relatively minor contribution of non-exhaust traffic emissions to metal pollution in TR dusts was considered to be due to overwhelming industrial and construction/demolition contributions, as well as to the dilution effect of natural soil particles. Ingestion appears to be the major route of exposure for road dust for both adults and children, followed by dermal contact. The non-carcinogenic health risk resulting from exposure to the potentially toxic metals in TR dusts was within the safe level based on the Hazard Index (HI), except in pollution hotspots where exposure to Pb, Cr, and Cu may be hazardous to children.

  16. Carbon formation and metal dusting in hot-gas cleanup systems of coal gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    Judkins, R.R.; Tortorelli, P.F.; Judkins, R.R.; DeVan, J.H.; Wright, I.G. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1995-11-01

    The product gas resulting from the partial oxidation of Carboniferous materials in a gasifier is typically characterized by high carbon and sulfur, but low oxygen, activities and, consequently, severe degradation of the structural and functional materials can occur. The objective of this task was to establish the potential risks of carbon deposition and metal dusting in advanced coal gasification processes by examining the current state of knowledge regarding these phenomena, making appropriate thermochemical calculations for representative coal gasifiers, and addressing possible mitigation methods. The paper discusses carbon activities, iron-based phase stabilities, steam injection, conditions that influence kinetics of carbon deposition, and influence of system operating parameters on carbon deposition and metal dusting.

  17. Influence of population density on the concentration and speciation of metals in the soil and street dust from urban areas.

    Science.gov (United States)

    Acosta, J A; Gabarrón, M; Faz, A; Martínez-Martínez, S; Zornoza, R; Arocena, J M

    2015-09-01

    Street dust and soil from high, medium and low populated cities and natural area were analysed for selected physical-chemical properties, total and chemical speciation of Zn, Pb, Cu, Cr, Cd, Co, Ni to understand the influence of human activities on metal accumulation and mobility in the environment. The pH, salinity, carbonates and organic carbon contents were similar between soil and dust from the same city. Population density increases dust/soil salinity but has no influence on metals concentrations in soils. Increases in metal concentrations with population density were observed in dusts. Cu, Zn, Pb, Cr can be mobilized more easily from dust compared to the soil. In addition, population density increase the percentage of Pb and Zn associated to reducible and carbonate phase in the dust. The behaviour of metals except Cd in soil is mainly affected by physico-chemical properties, while total metal influenced the speciation except Cr and Ni in dusts. Copyright © 2015 Elsevier Ltd. All rights reserved.

  18. Heavy Metal Contamination and Assessment of Roadside and Foliar Dust along the Outer-Ring Highway of Shanghai, China.

    Science.gov (United States)

    Yin, Ruijuan; Wang, Dongqi; Deng, Huanguang; Shi, Runhe; Chen, Zhenlou

    2013-11-01

    Foliar and roadside dust samples were collected from five sites along the outer-ring highway of Shanghai, one of the biggest metropolitan areas of China, to assess heavy/toxic metal contamination. Concentrations of Zn, Cu, Ni, As, and Hg in foliar dust were higher than in roadside dust, whereas concentrations of Pb and Cd were higher in roadside dust. In the roadside dust, average concentrations of all metals except As in foliar and roadside dust samples were significantly above the background values of soil in Shanghai: the ratios between the average of samples and background values of Shanghai were in the order: Cd (25.1) > Zn (12.2) > Cu (6.16) > Pb (5.74) > Ni (5.50) > Hg (5.18) > As (1.05). By using the geo-accumulation index, the pollution grades of seven heavy metals at five sampling sites were calculated. Roadside dust was heavily to extremely contaminated with Cd; moderately to heavily contaminated with Zn; and moderately contaminated with Cu, Hg, Pb, and Ni. Foliar dust was heavily contaminated with Cd; moderately to heavily contaminated with Zn and Cu; and moderately contaminated with Hg, Pb, and Ni. The contamination level of heavy metals in the Puxi area was greater than that in the Pudong area, which might be related to the industrial distribution and land use. Combined with correlation analysis, hierarchical cluster analysis indicated that atmospheric deposition is the main source of Cd, Hg, As, and Pb in dust and that Cu and Zn in dust are mainly from heavy traffic on the highway. A portion of Ni in dust also comes from the parent soil.

  19. Evolution of thermally pulsing asymptotic giant branch stars - II. Dust production at varying metallicity

    Science.gov (United States)

    Nanni, Ambra; Bressan, Alessandro; Marigo, Paola; Girardi, Léo

    2013-09-01

    We present the dust ejecta of the new stellar models for the thermally pulsing asymptotic giant branch (TP-AGB) phase computed with the COLIBRI code. We use a formalism of dust growth coupled with a stationary wind for both M- and C-stars. In the original version of this formalism, the most efficient destruction process of silicate dust in M-giants is chemisputtering by H2 molecules. For these stars, we find that dust grains can only form at relatively large radial distances (r ˜ 5R*), where they cannot be efficiently accelerated, in agreement with other investigations. In the light of recent laboratory results, we also consider the alternative case that the condensation temperature of silicates is determined only by the competition between growth and free evaporation processes (i.e. no chemisputtering). With this latter approach we obtain dust condensation temperatures that are significantly higher (up to Tcond ˜ 1400 K) than those found when chemisputtering is included (Tcond ˜ 900 K), and in better agreement with condensation experiments. As a consequence, silicate grains can remain stable in inner regions of the circumstellar envelopes (r ˜ 2 R*), where they can rapidly grow and can be efficiently accelerated. With this modification, our models nicely reproduce the observed trend between terminal velocities and mass-loss rates of Galactic M-giants. For C-stars the formalism is based on the homogeneous growth scheme where the key role is played by the carbon over oxygen excess. The models reproduce fairly well the terminal velocities of Galactic stars and there is no need to invoke changes in the standard assumptions. At decreasing metallicity the carbon excess becomes more pronounced and the efficiency of dust formation increases. This trend could be in tension with recent observational evidence in favour of a decreasing efficiency, at decreasing metallicity. If confirmed by more observational data, it would indicate that either the amount of the carbon

  20. The first low-mass stars: critical metallicity or dust-to-gas ratio?

    CERN Document Server

    Schneider, Raffaella; Bianchi, Simone; Valiante, Rosa

    2011-01-01

    We explore the minimal conditions which enable the formation of metal-enriched solar and sub-solar mass stars. We find that in the absence of dust grains, gas fragmentation occurs at densities nH ~ [10^4-10^5]cm^{-3} when the metallicity exceeds Z ~ 10^{-4} Zsun. The resulting fragmentation masses are > 10 Msun. The inclusion of Fe and Si cooling does not affect the thermal evolution as this is dominated by molecular cooling even for metallicities as large as Z = 10^{-2} Zsun. The presence of dust is the key driver for the formation of low-mass stars. We focus on three representative core-collapse supernova (SN) progenitors, and consider the effects of reverse shocks of increasing strength: these reduce the depletion factors, fdep = Mdust/(Mdust+Mmet), alter the shape of the grain size distribution function and modify the relative abundances of grain species and of metal species in the gas phase. We find that the lowest metallicity at which fragmentation occurs is Z=10^{-6} Zsun for gas pre-enriched by the ex...

  1. Inhalable desert dust, urban emissions, and potentially biotoxic metals in urban Saharan-Sahelian air

    Science.gov (United States)

    Garrison, Virginia H.; Majewski, Michael S.; Konde, Lassana; Wolf, Ruth E.; Otto, Richard D.; Tsuneoka, Yutaka

    2014-01-01

    Saharan dust incursions and particulates emitted from human activities degrade air quality throughout West Africa, especially in the rapidly expanding urban centers in the region. Particulate matter (PM) that can be inhaled is strongly associated with increased incidence of and mortality from cardiovascular and respiratory diseases and cancer. Air samples collected in the capital of a Saharan–Sahelian country (Bamako, Mali) between September 2012 and July 2013 were found to contain inhalable PM concentrations that exceeded World Health Organization (WHO) and US Environmental Protection Agency (USEPA) PM2.5 and PM10 24-h limits 58 – 98% of days and European Union (EU) PM10 24-h limit 98% of days. Mean concentrations were 1.2-to-4.5 fold greater than existing limits. Inhalable PM was enriched in transition metals, known to produce reactive oxygen species and initiate the inflammatory response, and other potentially bioactive and biotoxic metals/metalloids. Eroded mineral dust composed the bulk of inhalable PM, whereas most enriched metals/metalloids were likely emitted from oil combustion, biomass burning, refuse incineration, vehicle traffic, and mining activities. Human exposure to inhalable PM and associated metals/metalloids over 24-h was estimated. The findings indicate that inhalable PM in the Sahara–Sahel region may present a threat to human health, especially in urban areas with greater inhalable PM and transition metal exposure.

  2. The metallicity and dust content of a redshift 5 gamma-ray burst host galaxy

    DEFF Research Database (Denmark)

    Sparre, M.; Hartoog, O. E.; Krühler, T.

    2014-01-01

    Observations of the afterglows of long gamma-ray bursts (GRBs) allow the study of star-forming galaxies across most of cosmic history. Here we present observations of GRB 111008A from which we can measure metallicity, chemical abundance patterns, dust-to-metals ratio and extinction of the GRB host...... galaxy at z=5.0. The host absorption system is a damped Lyman-alpha absorber (DLA) with a very large neutral hydrogen column density of log N(HI)/cm^(-2) = 22.30 +/- 0.06, and a metallicity of [S/H]= -1.70 +/- 0.10. It is the highest redshift GRB with such a precise metallicity measurement. The presence...

  3. The evolution of the dust-to-metals ratio in high-redshift galaxies probed by GRB-DLAs

    CERN Document Server

    Wiseman, P; Bolmer, J; Krühler, T; Yates, R M; Greiner, J; Fynbo, J P U

    2016-01-01

    Context: Several issues regarding the nature of dust at high redshift remain unresolved: its composition, its production and growth mechanisms, and its effect on background sources. Aims: This paper aims to provide a more accurate relation between dust depletion levels and dust-to-metals ratio (DTM), and to use the DTM to investigate the origin and evolution of dust in the high redshift Universe via GRB-DLAs. Methods: We use absorption-line measured metal column densities for a total of 19 GRB-DLAs, including five new GRB afterglow spectra from VLT/X-shooter. We use the latest linear models to calculate the dust depletion strength factor in each DLA. Using this we calculate total dust and metal column densities to determine a DTM. We explore the evolution of DTM with metallicity, and compare this to previous trends in DTM measured with different methods. Results: We find significant dust depletion in 16 of our 19 GRB-DLAs, yet 18 of the 19 have a DTM significantly lower than the Milky Way. We find that DTM is...

  4. Evaluation of heavy metal contamination hazards in nuisance dust particles, in Kurdistan Province, western Iran.

    Science.gov (United States)

    Khuzestani, Reza Bashiri; Souri, Bubak

    2013-07-01

    The effects of natural and geochemical factors depending on heavy metal contamination in nuisance dust particles were evaluated. The nuisance dust particles were sampled using passive deposit gauge method for one year from April 2010 to March 2011 and the obtained samples were measured for the total contents and the contamination levels of Fe, Mn, Cu and As using geo-accumulation index (l(geo)), enrichment factor (EF) and the integrated pollution index (IPI). The results showed that, the contamination levels of Fe and Mn based on I(geo) values, were uncontaminated (I(geo) < 0) (variations of the I(geo) index was from -3.11 to -1.751 for Fe, from -0.630 to -1.925 for Mn), while the values of Cu and As were demonstrated to have moderate contamination based on l(geo) values (variations of I(geo) index was from -1.125 to 0.848 for Cu, and from -2.002 to 1.249 for As). The analysis of EF also revealed minor to moderate enrichment for Mn (1.215-4.214), minor to moderately severe enrichment for Cu (2.791-6.484), and As (1.370-8.462), respectively. The variation of the IPI index also showed low to moderate level of heavy metal pollution in nuisance dust particulates (0.511-1.829). The analysis of the results also approved that the natural processes and geochemical variables (the changing meteorological parameters) can significantly affect the availability of heavy metals in nuisance dust particles in Western Iran.

  5. THE DUST BUDGET OF THE SMALL MAGELLANIC CLOUD: ARE ASYMPTOTIC GIANT BRANCH STARS THE PRIMARY DUST SOURCE AT LOW METALLICITY?

    Energy Technology Data Exchange (ETDEWEB)

    Boyer, M. L.; Gordon, K. D.; Meixner, M.; Sargent, B. A. [STScI, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Srinivasan, S. [UPMC-CNRS UMR7095, Institut d' Astrophysique de Paris, F-75014 Paris (France); Riebel, D. [Department of Physics and Astronomy, The Johns Hopkins University, Homewood Campus, Baltimore, MD 21218 (United States); McDonald, I. [Jodrell Bank Centre for Astrophysics, Alan Turing Building, University of Manchester, Manchester M13 9PL (United Kingdom); Van Loon, J. Th. [Astrophysics Group, Lennard-Jones Laboratories, Keele University, Staffordshire ST5 5BG (United Kingdom); Clayton, G. C. [Department of Physics and Astronomy, Louisiana State University, 233-A Nicholson Hall, Tower Dr., Baton Rouge, LA 70803-4001 (United States); Sloan, G. C., E-mail: mboyer@stsci.edu [Astronomy Department, Cornell University, Ithaca, NY 14853-6801 (United States)

    2012-03-20

    We estimate the total dust input from the cool evolved stars in the Small Magellanic Cloud, using the 8 {mu}m excess emission as a proxy for the dust-production rate (DPR). We find that asymptotic giant branch (AGB) and red supergiant (RSG) stars produce (8.6-9.5) Multiplication-Sign 10{sup -7} M{sub Sun} yr{sup -1} of dust, depending on the fraction of far-infrared sources that belong to the evolved star population (with 10%-50% uncertainty in individual DPRs). RSGs contribute the least (<4%), while carbon-rich AGB stars (especially the so-called extreme AGB stars) account for 87%-89% of the total dust input from cool evolved stars. We also estimate the dust input from hot stars and supernovae (SNe), and find that if SNe produce 10{sup -3} M{sub Sun} of dust each, then the total SN dust input and AGB input are roughly equivalent. We consider several scenarios of SN dust production and destruction and find that the interstellar medium (ISM) dust can be accounted for solely by stellar sources if all SNe produce dust in the quantities seen around the dustiest examples and if most SNe explode in dense regions where much of the ISM dust is shielded from the shocks. We find that AGB stars contribute only 2.1% of the ISM dust. Without a net positive contribution from SNe to the dust budget, this suggests that dust must grow in the ISM or be formed by another unknown mechanism.

  6. Pollution and health risk of potentially toxic metals in urban road dust in Nanjing, a mega-city of China

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Enfeng, E-mail: efliu@niglas.ac.cn [State Key Laboratory of Lake Science and Environment, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008 (China); Yan, Ting [State Key Laboratory of Lake Science and Environment, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008 (China); Graduate University of Chinese Academy of Sciences, Beijing 100049 (China); Birch, Gavin [School of Geosciences, University of Sydney, Sydney, NSW 2006 (Australia); Zhu, Yuxin [State Key Laboratory of Lake Science and Environment, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008 (China)

    2014-04-01

    Spatial variations in concentrations of a suite of potentially toxic metals (Ba, Cr, Cu, Fe, Mn, Ni, Pb and Zn) and Ca in road dusts (n = 99) from urban trunk roads (TR) in Nanjing, a mega-city in China, were established. Metal pollution levels, sources and human health risk (non-carcinogenic) were studied. In contrast to previous studies, we labeled the indicative metals relating to non-exhaust traffic emissions by comparing metal pollution between crossroad and park road dusts, and then anthropogenic sources of metals in TR dusts were assessed combining their spatial pollution patterns, principal component analysis and Pb isotopic compositions. Results showed that the metals were enriched in TR dusts compared to background soil concentrations with mean enrichment factors (EFs) of 2.2–23, indicating considerable anthropogenic influence. The degrees of metal pollution ranged from minimal to extremely high and ranked by Ca > Cu > Pb ≈ Zn > Cr ≈ Fe > Ni ≈ Ba > Mn on average. Pollution of Cr, Cu, Fe, Mn, Ni, Pb and Zn in TR dusts resulted primarily from industrial emissions (e.g., coal combustion and smelting) and high pollution levels were found close to suburb industrial complexes, whereas pollution of Ba and Ca was mainly related to construction/demolition sources and was generally distributed homogeneously. The relatively minor contribution of non-exhaust traffic emissions to metal pollution in TR dusts was considered to be due to overwhelming industrial and construction/demolition contributions, as well as to the dilution effect of natural soil particles. Ingestion appears to be the major route of exposure for road dust for both adults and children, followed by dermal contact. The non-carcinogenic health risk resulting from exposure to the potentially toxic metals in TR dusts was within the safe level based on the Hazard Index (HI), except in pollution hotspots where exposure to Pb, Cr, and Cu may be hazardous to children. - Highlights: • Pollution and

  7. Evolution of the dust-to-metals ratio in high-redshift galaxies probed by GRB-DLAs

    Science.gov (United States)

    Wiseman, P.; Schady, P.; Bolmer, J.; Krühler, T.; Yates, R. M.; Greiner, J.; Fynbo, J. P. U.

    2017-02-01

    Context. Several issues regarding the nature of dust at high redshift remain unresolved: its composition, its production and growth mechanisms, and its effect on background sources. Aims: We provide a more accurate relation between dust depletion levels and dust-to-metals ratio (DTM), and to use the DTM to investigate the origin and evolution of dust in the high-redshift Universe via gamma-ray burst damped Lyman-alpha absorbers (GRB-DLAs). Methods: We use absorption-line measured metal column densities for a total of 19 GRB-DLAs, including five new GRB afterglow spectra from VLT/X-Shooter. We use the latest linear models to calculate the dust depletion strength factor in each DLA. Using these values we calculate total dust and metal column densities to determine a DTM. We explore the evolution of DTM with metallicity, and compare it to previous trends in DTM measured with different methods. Results: We find significant dust depletion in 16 of our 19 GRB-DLAs, yet 18 of the 19 have a DTM significantly lower than the Milky Way. We find that DTM is positively correlated with metallicity, which supports a dominant ISM grain-growth mode of dust formation. We find a substantial discrepancy between the dust content measured from depletion and that derived from the total V-band extinction, AV, measured by fitting the afterglow SED. We advise against using a measurement from one method to estimate that from the other until the discrepancy can be resolved. Based on observations collected at the European Southern Observatory, Paranal, Chile, Program IDs: 088.A-0051(B), 089.A-0067(B), 091.C-0934, 094.A-0134(A).

  8. Comparison of metal pollution and health risks of urban dust in Beijing in 2007 and 2012.

    Science.gov (United States)

    Yu, Yang; Ma, Junhua; Song, Ningning; Wang, Xi; Wei, Tong; Yang, Zhifeng; Li, Yingxia

    2016-12-01

    Urban dust in cities is a useful indicator of ambient environmental conditions and a sink for pollutants emitted through various natural and human activities. In this study, metal distributions in urban dust samples collected in 2007, using vacuuming, and 2012, using brushing, were compared. Experiments comparing the vacuuming and brushing methods were performed and translation equations were developed to correct the vacuuming results so that they could be compared with the brushing results. Cadmium concentrations were lower in 2012 than 2007; this could be because many industries moved out of the Beijing region after 2007. Concentrations of Cr, Cu, and Zn changed slightly, which could result from a combination of decreased industrial pollution and increased traffic pollution. A health risk assessment found that except for Cr, exposure to metals in urban dust in the Beijing study area would not cause serious health impacts on residents in 2007 or 2012. However, the health risk for children was higher than for adults in both years. Chromium had the highest hazxard index (0.44) and the highest carcinogenic risk (4.16 × 10(-6)).

  9. Leaching of metals from copper smelter flue dust (Mufulira, Zambian Copperbelt)

    DEFF Research Database (Denmark)

    Vítková, Martina; Ettler, Vojtěch; Hyks, Jiri

    2011-01-01

    ) and delafossite (CuFeO2) represented the principal phases of the studied dust. In contact with water, chalcanthite was dissolved and hydrated Cu sulphates precipitated at pH4–7. Gypsum (CaSO4·2H2O) and secondary Fe or Al phases were observed in the leached residues. Serious environmental impact due to leaching...... and PHREEQC-2 modelling were investigated in the pH range of 3–7. The highest concentrations of metals were released at pH 3–4.5, which encompasses the natural pH of the dust suspension (∼4.3). About 40% of the total Cu was leached at pH3, yielding 107g/kg. Chalcanthite (CuSO4·5H2O), magnetite (Fe3O4......The leaching behaviour of electrostatic precipitator dust from the Mufulira Cu smelter (Copperbelt, Zambia) was studied using a 48-h pH-static leaching experiment (CEN/TS 14997). The release of metals (Cd, Co, Cu, Ni, Pb and Zn) and changes in mineralogical composition using X-ray diffraction...

  10. Dust formation around AGB and SAGB stars: a trend with metallicity?

    CERN Document Server

    Ventura, P; Schneider, R; Carini, R; Valiante, R; D'Antona, F; Gallerani, S; Maiolino, R; Tornambe, A

    2012-01-01

    We calculate the dust formed around AGB and SAGB stars of metallicity Z=0.008 by following the evolution of models with masses in the range 1Mdust forms via condensation of molecules within a wind expanding isotropically from the stellar surface. We find that, because of the strong Hot Bottom Burning (HBB) experienced, high mass models produce silicates, whereas lower mass objects are predicted to be surrounded by carbonaceous grains; the transition between the two regimes occurs at a threshold mass of 3.5M. These fndings are consistent with the results presented in a previous investigation, for Z=0.001. However, in the present higher metallicity case, the production of silicates in the more massive stars continues for the whole AGB phase, because the HBB experienced is softer at Z=0.008 than at Z=0.001, thus the oxygen in the envelope, essential for the formation of water molecules, is never consumed completely. The total amount of dust formed fo...

  11. Heavy Metals Content in Classroom Dust of Some Public Primary Schools in Metropolitan Lagos, Nigeria

    Directory of Open Access Journals (Sweden)

    O.E. Popoola

    2012-04-01

    Full Text Available This aim of the study is to determine the levels of heavy metals (Pb, Cr, Cd and Mn in 40 dust samples obtained from the classrooms of some public primary schools in Lagos State, Nigeria. Children are more susceptible to the adverse health effects of heavy metal pollution due to their small body size, developing nervous system, high absorption rate and behavioral pattern present during childhood. Exposure to heavy metalladen dustis considered to be a significant contributor. To assess the extent of pollution by heavy metals, classroom dust samples were obtained from 40 selected schools in Lagos, Nigeria. The samples were subjected to aqua regia microwave digestion and analysed using graphite furnace atomic absorption spectrophotometer.The results showed that the classroom dusts contained PbHD 23.89±16.39, PbLD 22.77±9.21; CrHD 10.53±5.08, CrLD 6.17±2.47; CdHD 0.09±0.12, CdLD 0.09±0.10 μg/g, respectively. Interestingly, the highest concentration of lead (82.51 μg/g was found in a classroom far removed from any commercial or industrial activites, Ajeromi-Ifelodun high density area while Ikeja, a more industrialized area has lower concentration of the metal. The values obtained in this study are lower than expected but it is still a source of concern since children are exposed to this environment daily and for appreciable period of time.

  12. Dust-to-metal ratios in Damped Lyman-alpha absorbers: Fresh clues to the origins of dust and optical extinction towards gamma-ray bursts

    CERN Document Server

    De Cia, A; Savaglio, S; Schady, P; Vreeswijk, P M

    2013-01-01

    Motivated by the anomalous dust-to-metal ratios (DTM) derived in the literature for gamma-ray burst (GRB) damped Ly-alpha absorbers (DLAs), we measure these ratios using the dust-depletion pattern observed in UV/optical afterglow spectra, associated with the interstellar medium (ISM) at the GRB host-galaxy redshifts. Our sample consists of 20 GRB absorbers and a comparison sample of 72 QSO-DLAs, overall at redshift 1.2 14.7, above which several QSO-DLAs reveal H2, making GRB-DLAs promising candidates for molecular research.

  13. Determination of Metal Ion Concentrations in Components of Household Solid Waste in the Akwapim South Municipality of Ghana

    Directory of Open Access Journals (Sweden)

    M. Ackah

    2011-08-01

    Full Text Available The potential of household solid waste to supply micro-nutrients is studied. The study aimed at finding the levels of metal ion concentrations in domestic refuse typically the organic, paper and plastic waste stream components which constituted the highest waste stream fractions generated by residents in the Nsawam- Adoadjiri townships. INAA was used to determine metal ions concentrations in household solid organic, paper and plastic components of wastes generated by sampled households of Nsawam and Adoagyiri townships of the Akwapim South Municipality of Ghana. The analysis covered (Ca, K, Mg, Na, Cu, Mn, Al, Cl, and V. Standard reference materials were also analysed in the same manner as the waste samples to ensure good quality control/quality assurance procedures. Higher mean concentrations of 5.59 μg/g and 13.27 mg/g were recorded for Mn and Cl, respectively in organic waste stream component as compared to 1.13 μg/g and 0.19 mg/g in paper/cardboard waste stream and 2.67 μg/g and 13.27 mg/g in rubber/plastic waste stream components respectively. These values are comparable to literature values.

  14. Human Health Risks Associated with Metals from Urban Soil and Road Dust in an Oilfield Area of Southeastern Algeria.

    Science.gov (United States)

    Benhaddya, Mohammed Lamine; Boukhelkhal, Abdelaziz; Halis, Youcef; Hadjel, Mohammed

    2016-04-01

    Hassi Messaoud town is a recent city that is situated inside the oil field, which hosts an important petroleum extraction field and refinery. Large-scale and long-term oil refinery and corresponding industrial activities may contaminate the surrounding soil/dust and could lead to pollution levels that can affect human health. The soil and road dust samples were analysed for different trace elements: copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), and zinc (Zn). Geo-accumulation index (I(geo)), pollution index (PI), and integrated pollution index (IPI) were calculated to evaluate the heavy metal contamination level of urban soil and road dust. The I(geo) values indicate unpolluted to moderate polluted of investigated metals in the soil samples. The assessment results of PI support the results of I(geo), and IPI indicates heavy metals in road dust polluted seriously. The noncarcinogenic health risk assessment shows that ingestion of soil/dust particles is the route for exposure to heavy metals, followed by dermal adsorption. The human exposure risk assessment based on different exposure pathways showed that the hazard index (HI) was <1.0 for all of the elements. The relative exposure risk (noncarcinogenic) was greater for toddlers. Although the overall risk was within the acceptable limit of 1.00, the HI of Pb from the soil (0.103) and road dust (0.132) was close to the threshold limits, which over the long-term may pose a health risk.

  15. Saharan dust - a carrier of persistent organic pollutants, metals and microbes to the Caribbean?

    Directory of Open Access Journals (Sweden)

    V.H Garrison

    2006-12-01

    Full Text Available An international team of scientists from government agencies and universities in the United States, U.S. Virgin Islands (USVI, Trinidad & Tobago, the Republic of Cape Verde, and the Republic of Mali (West Africa is working together to elucidate the role Saharan dust may play in the degradation of Caribbean ecosystems. The first step has been to identify and quantify the persistent organic pollutants (POPs, trace metals, and viable microorganisms in the atmosphere in dust source areas of West Africa, and in dust episodes at downwind sites in the eastern Atlantic (Cape Verde and the Caribbean (USVI and Trinidad & Tobago. Preliminary findings show that air samples from Mali contain a greater number of pesticides, polychlorinated biphenyls (PCBs and polycyclic aromatic hydrocarbons (PAHs and in higher concentrations than the Caribbean sites. Overall, POP concentrations were similar in USVI and Trinidad samples. Trace metal concentrations were found to be similar to crustal composition with slight enrichment of lead in Mali. To date, hundreds of cultureable micro-organisms have been identified from Mali, Cape Verde, USVI, and Trinidad air samples. The sea fan pathogen, Aspergillus sydowii, has been identified in soil from Mali and in air samples from dust events in the Caribbean. We have shown that air samples from a dust-source region contain orders of magnitude more cultureable micro-organisms per volume than air samples from dust events in the Caribbean, which in turn contain 3-to 4-fold more cultureable microbes than during non-dust conditions. Rev. Biol. Trop. 54 (Suppl. 3: 9-21. Epub 2007 Jan. 15.Un grupo internacional de agencias gubernamentales y universidades de los Estados Unidos, las Islas Vírgenes (EUA, Trinidad y Tobago, la República de Cabo Verde y la República de Mali (África Oeste, está trabajando en conjunto para elucidar el papel que el polvo del Sahara puede estar jugando en el deterioro de los ecosistemas caribeños. El

  16. Assessment of Heavy Metals in Street Dust in Kathmandu Metropolitan City and their Possible Impacts on the Environment

    Directory of Open Access Journals (Sweden)

    Pawan Raj Shakya

    2011-12-01

    Full Text Available Street dust often contains elevated concentrations of heavy metals and can influence on environment and human health. Therefore, a study on the characteristics of heavy metals in street dusts at different localities was carried out in the metropolitan city of Kathmandu of Nepal. A total of 20 street dusts have been sampled from four sampling sites with various activities or characteristics such as mechanical workshops (MWK, motor parks (MPK, market areas (MKA and residential areas (RDA and analyzed for Zn, Pb, Ni, Cr and Cd using the atomic absorption spectrophotometric method. Results showed that street dust samples contained significant levels of the metals studied compared to the values from the control site. The variation in concentration of most of the heavy metals determined decreased in an order represented as MWK>MPK>MKA>RDA>Control. While the RDA and MKA give the same element abundance order as Zn > Pb > Ni > Cr > Cd, the MPK and MWK show different abundance order in some elemental contents. In all the street dusts, zinc is the most available and labile element followed by lead. From the place of low activity (RDA to the place of high activity (MWK, the metal concentrations in street dusts varied from 55.4-419.3 μg g-1 for Zn, 12.3-116.8 μg g-1 for Pb, 4.9-86.3 μg g-1 for Ni, 1.4-14.3 μg g-1 for Cr and 0.3-39.6 μg g-1 for Cd respectively. Results indicate that the metal pollutants in street dusts could significantly contribute to deteriorate the environmental status of the city of Kathmandu metropolis.

  17. Carbon Formation and Metal Dusting in Hot-Gas Cleanup Systems of Coal Gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    Tortorelli, Peter F.; Judkins, Roddie R.; DeVan, Jackson H.; Wright, Ian G.

    1995-12-31

    There are several possible materials/systems degradation modes that result from gasification environments with appreciable carbon activities. These processes, which are not necessarily mutually exclusive, include carbon deposition, carburization, metal dusting, and CO disintegration of refractories. Carbon formation on solid surfaces occurs by deposition from gases in which the carbon activity (a sub C) exceeds unity. The presence of a carbon layer CO can directly affect gasifier performance by restricting gas flow, particularly in the hot gas filter, creating debris (that may be deposited elsewhere in the system or that may cause erosive damage of downstream components), and/or changing the catalytic activity of surfaces.

  18. Potential threat of heavy metals in re-suspended dusts on building surfaces in oilfield city

    Science.gov (United States)

    Kong, Shaofei; Lu, Bing; Bai, Zhipeng; Zhao, Xueyan; Chen, Li; Han, Bin; Li, Zhiyong; Ji, Yaqin; Xu, Yonghai; Liu, Yong; Jiang, Hua

    2011-08-01

    30 re-suspended dust samples were collected from building surfaces of an oilfield city, then re-suspended through PM 2.5, PM 10 and PM 100 inlets and analyzed for 10 metals including V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd and Pb by inductively coupled plasma-mass spectroscopy. Metals concentrations in different fractions and locations were studied. Metals sources were identified by cluster and primary component analysis. The potential risk to human health was assessed by human exposure model. Results showed that Zn, Mn, Pb and Cu were higher in all the three fractions. V, Cr, Mn and Co ranged close to the background values of Chinese soil indicating that they were mainly from crustal materials. Concentrations of Zn, Mn, Pb, V, Cr, Ni, Co and Cd were higher in old district than that in new district for the three fractions. The PM 2.5/PM 10, PM 10/PM 100 and PM 2.5/PM 100 ratios were higher for Zn, Cd, Cu, Pb, Ni, As and Cr (all higher than 1.0), and lower for Co, Mn and V (all less than or close to 1.0) which meant that anthropologic sources associated metals were more easily accumulated in finer particles than metals from crustal materials. Spatial variations indicated that the ten metals peaked at surroundings near railway station, gas stations, industrial boilers and machine manufacturing plant implying the influence of local vehicle emission, fossil fuel combustion and industrial activities as well as crustal materials which was verified by cluster analysis and primary component analysis results. Ingestion of dust particles appeared to be the main route of exposure to re-suspended dust. Hazard Indexes of As were both highest for children and adult which could be a potential threat to human health for non-cancer effect and it also exhibited the highest values for cancer effect as 1.01E-06, 7.04E-07 and 7.21E-07 for PM 2.5, PM 10 and PM 100, respectively.

  19. FMOS near-IR spectroscopy of Herschel selected galaxies: star formation rates, metallicity and dust attenuation at z~1

    CERN Document Server

    Roseboom, I G; Sumiyoshi, M; Wang, L; Dalton, G; Akiyama, M; Bock, J; Bonfield, D; Buat, V; Casey, C; Chapin, E; Clements, D L; Conley, A; Curtis-Lake, E; Cooray, A; Dunlop, J S; Farrah, D; Ham, S J; Ibar, E; Iwamuro, F; Kimura, M; Lewis, I; Macaulay, E; Magdis, G; Maihara, T; Marsden, G; Mauch, T; Moritani, Y; Ohta, K; Oliver, S J; Page, M J; Schulz, B; Scott, Douglas; Symeonidis, M; Takato, N; Tamura, N; Totani, T; Yabe, K; Zemcov, M

    2012-01-01

    We investigate the properties (e.g. star formation rate, dust attentuation, stellar mass and metallicity) of a sample of infrared luminous galaxies at z \\sim 1 via near-IR spectroscopy with Subaru-FMOS. Our sample consists of Herschel SPIRE and Spitzer MIPS selected sources in the COSMOS field with photometric redshifts in the range 0.7 = 0.51\\pm0.27 for = 10^12 Lsol sources at = 1.36. By comparing star formation rates estimated from the IR and from the dust uncorrected H{\\alpha} line we find a strong relationship between dust attenuation and star formation rate. This relation is broadly consistent with that previously seen in star-forming galaxies at z ~ 0.1. Finally, we investigate the metallicity via the N2 ratio, finding that z ~ 1 IR-selected sources are indistinguishable from the local mass-metallicity relation. We also find a strong correlation between dust attentuation and metallicity, with the most metal-rich IR-sources experiencing the largest levels of dust attenuation.

  20. Tracing Sources and Contamination Assessments of Heavy Metals in Road and Foliar Dusts in a Typical Mining City, China

    Science.gov (United States)

    Yang, Jie; Teng, Yanguo; Song, Liuting; Zuo, Rui

    2016-01-01

    Road and foliar dust samples from four land-use districts of Panzhihua City, a famous V-Ti magnetite production area of China, were collected to investigate the sources and distribution characteristics of 9 heavy metals (V, Pb, Cd, Cu, Zn, Ni, Cr, Fe, and Mn). The results suggest that foliar samples had smaller particle size and higher heavy metal contents than road dusts. The contamination assessments of heavy metals were as follows: Pb and V (significant enrichment) > Zn, Ni, Cr, Fe, and Mn (moderate enrichment) > Cd and Ni (minimal enrichment). Statistical analyses showed Pb, as the primary pollution element, originated from waste incineration and lead-fuel combustion. The sources of Zn, Ni, Cr, Fe, V, and Mn were fugitive dust and traffic activities. Potential origins of Cu were corrosion of alloys used in vehicle components, vehicle covers, or other metallic surfaces and materials. The sources of Cd were different from any other heavy metals. Traffic and industrial activities were the main anthropogenic origins of heavy metals in dusts of Panzhihua, and more attention should be paid to heavy metal pollution in agricultural area. PMID:27992518

  1. Trace-metal concentrations in African dust: effects of long-distance transport and implications for human health

    Science.gov (United States)

    Garrison, Virginia; Lamothe, Paul; Morman, Suzette; Plumlee, Geoffrey S.; Gilkes, Robert; Prakongkep, Nattaporn

    2010-01-01

    The Sahara and Sahel lose billions of tons of eroded mineral soils annually to the Americas and Caribbean, Europe and Asia via atmospheric transport. African dust was collected from a dust source region (Mali, West Africa) and from downwind sites in the Caribbean [Trinidad-Tobago (TT) and U.S. Virgin Islands (VI)] and analysed for 32 trace-elements. Elemental composition of African dust samples was similar to that of average upper continental crust (UCC), with some enrichment or depletion of specific trace-elements. Pb enrichment was observed only in dust and dry deposition samples from the source region and was most likely from local use of leaded gasoline. Dust particles transported long-distances (VI and TT) exhibited increased enrichment of Mo and minor depletion of other elements relative to source region samples. This suggests that processes occurring during long-distance transport of dust produce enrichment/depletion of specific elements. Bioaccessibility of trace-metals in samples was tested in simulated human fluids (gastric and lung) and was found to be greater in downwind than source region samples, for some metals (e.g., As). The large surface to volume ratio of the dust particles (<2.5 µm) at downwind sites may be a factor.

  2. Human health risk assessment based on trace metals in suspended air particulates, surface dust, and floor dust from e-waste recycling workshops in Hong Kong, China.

    Science.gov (United States)

    Lau, Winifred Ka Yan; Liang, Peng; Man, Yu Bon; Chung, Shan Shan; Wong, Ming Hung

    2014-03-01

    This study investigated health risks exerted on electronic waste (e-waste) recycling workers exposed to cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), nickel (Ni), mercury (Hg), and zinc (Zn) in Hong Kong. E-waste recycling workshops were classified into eight working areas: 1 = office, 2 = repair, 3 = dismantling, 4 = storage, 5 = desoldering, 6 = loading, 7 = cable shredding, and 8 = chemical waste. The aforementioned metal concentrations were analyzed in suspended air particulates, surface dust and floor dust collected from the above study areas in five workshops. Elevated Pb levels were measured in dismantling and desoldering areas (582 and 486 μg/100 cm(2) in surface and 3,610 and 19,172 mg/kg in floor dust, respectively). Blood lead levels of 10 and 39.5 μg/dl were estimated using United States Environmental Protection Agency's Adult Lead Model as a result of exposure to the floor dust from these two areas. Human health risk assessments were conducted to evaluate cancer and noncancer risks resulting from exposure to floor dust through the combined pathways of ingestion, dermal contact, and inhalation. Findings indicated that workers may be exposed to cancer risks above the acceptable range at 147 in a million at the 95th percentile in the dismantling area. Workers should be informed of associated risks to safeguard their health.

  3. Metal contamination in campus dust of Xi'an, China: A study based on multivariate statistics and spatial distribution

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Hao [School of Tourism and Environment, Shaanxi Normal University, Xi' an 710062 (China); Lu, Xinwei, E-mail: luxinwei@snnu.edu.cn [School of Tourism and Environment, Shaanxi Normal University, Xi' an 710062 (China); Li, Loretta Y., E-mail: lli@civil.ubc.ca [Department of Civil Engineering, University of British Columbia, Vancouver V6T 1Z4 (Canada); Gao, Tianning; Chang, Yuyu [School of Tourism and Environment, Shaanxi Normal University, Xi' an 710062 (China)

    2014-06-01

    The concentrations of As, Ba, Co, Cr, Cu, Mn, Ni, Pb, V and Zn in campus dust from kindergartens, elementary schools, middle schools and universities of Xi'an, China were determined by X-ray fluorescence spectrometry. Correlation coefficient analysis, principal component analysis (PCA) and cluster analysis (CA) were used to analyze the data and to identify possible sources of these metals in the dust. The spatial distributions of metals in urban dust of Xi'an were analyzed based on the metal concentrations in campus dusts using the geostatistics method. The results indicate that dust samples from campuses have elevated metal concentrations, especially for Pb, Zn, Co, Cu, Cr and Ba, with the mean values of 7.1, 5.6, 3.7, 2.9, 2.5 and 1.9 times the background values for Shaanxi soil, respectively. The enrichment factor results indicate that Mn, Ni, V, As and Ba in the campus dust were deficiently to minimally enriched, mainly affected by nature and partly by anthropogenic sources, while Co, Cr, Cu, Pb and Zn in the campus dust and especially Pb and Zn were mostly affected by human activities. As and Cu, Mn and Ni, Ba and V, and Pb and Zn had similar distribution patterns. The southwest high-tech industrial area and south commercial and residential areas have relatively high levels of most metals. Three main sources were identified based on correlation coefficient analysis, PCA, CA, as well as spatial distribution characteristics. As, Ni, Cu, Mn, Pb, Zn and Cr have mixed sources — nature, traffic, as well as fossil fuel combustion and weathering of materials. Ba and V are mainly derived from nature, but partly also from industrial emissions, as well as construction sources, while Co principally originates from construction. - Highlights: • Metal content in dust from schools was determined by XRF. • Spatial distribution of metals in urban dust was focused on campus samples. • Multivariate statistic and spatial distribution were used to identify metal

  4. An Infrared Census of DUST in Nearby Galaxies with Spitzer (DUSTiNGS), II. Discovery of Metal-poor Dusty AGB Stars

    CERN Document Server

    Boyer, Martha L; Barmby, P; Bonanos, A Z; Gehrz, R D; Gordon, K D; Groenewegen, M A T; Lagadec, E; Lennon, D; Marengo, M; McDonald, I; Meixner, M; Skillman, E; Sloan, G C; Sonneborn, G; van Loon, J Th; Zijlstra, A

    2014-01-01

    The DUSTiNGS survey (DUST in Nearby Galaxies with Spitzer) is a 3.6 and 4.5 micron imaging survey of 50 nearby dwarf galaxies designed to identify dust-producing Asymptotic Giant Branch (AGB) stars and massive stars. Using two epochs, spaced approximately six months apart, we identify a total of 526 dusty variable AGB stars (sometimes called "extreme" or x-AGB stars; [3.6]-[4.5]>0.1 mag). Of these, 111 are in galaxies with [Fe/H] < -1.5 and 12 are in galaxies with [Fe/H] < -2.0, making them the most metal-poor dust-producing AGB stars known. We compare these identifications to those in the literature and find that most are newly discovered large-amplitude variables, with the exception of approximately 30 stars in NGC 185 and NGC 147, one star in IC 1613, and one star in Phoenix. The chemical abundances of the x-AGB variables are unknown, but the low metallicities suggest that they are more likely to be carbon-rich than oxygen-rich and comparisons with existing optical and near-IR photometry confirms tha...

  5. Tetrabromobisphenol A and heavy metal exposure via dust ingestion in an e-waste recycling region in Southeast China.

    Science.gov (United States)

    Wu, Yuanyuan; Li, Yanyan; Kang, Duan; Wang, Jingjing; Zhang, Yanfang; Du, Dongli; Pan, Bishu; Lin, Zhenkun; Huang, Changjiang; Dong, Qiaoxiang

    2016-01-15

    This study was designed to investigate a prevalent brominated flame retardant tetrabromobisphenol A (TBBPA) and four heavy metals of Pb, Cr, As, Cd in dust samples (52 indoor and 52 outdoor) collected from residential houses in an e-waste recycling area in Southeast China. For TBBPA, the mean concentration in indoor dust (3435 ng/g, dw) was higher than that in outdoor dust (1998 ng/g, dw). For heavy metals, the mean concentrations of Pb, Cr, As, Cd were 399, 151, 48.13, and 5.85 mg/kg in indoor dust, respectively, and were 328, 191, 17.59, and 4.07 mg/kg in outdoor dust, respectively. Except for As, concentrations of TBBPA and other metals decreased with the increased distance away from the e-waste recycling center, suggesting significant contribution of e-waste activities. The daily exposure doses of TBBPA ranged from 0.04 to 7.50 ng/kg-bw/day for adults and from 0.31 to 58.54 ng/kg-bw/day for children, representing the highest values reported to date for TBBPA exposure via dust ingestion. Daily exposure doses of Cr, As, and Cd were all below the reference doses. However, daily exposure dose of Pb for children in areas near the e-waste processing center was above the reference dose, posing significant health concern for children in that region.

  6. Cytotoxicity of dust constituents towards alveolar macrophages: interactions of heavy metal compounds.

    Science.gov (United States)

    Geertz, R; Gulyas, H; Gercken, G

    1994-01-26

    The interactions between different heavy metal compounds which affect their cytotoxicity towards rabbit alveolar macrophages were investigated. The cells were exposed in vitro to combinations of As3+, Cd2+, Hg2+, Ni2+, or V5+ with different concentrations of another heavy metal compound. Toxicity was determined as the depression of zymosan-induced release of superoxide anion radicals. Significant antagonisms occurred in the combinations Cd2+/Zn2+, Hg2+/As3+, and Hg2+/Se4+, while significant synergisms were exhibited by the combinations Cd2+/Cu2+, Cd2+/Sn2+, Hg2+/Cu2+, Ni2+/Cd2+, Ni2+/Cu2+, Ni2+/Sn2+ and V5+/Cu2+. In the combinations As3+/Zn2+, Hg2+/Cd2+ and Hg2+/Zn2+, both kinds of interactions were observed depending on the concentrations of the heavy metal compounds. An interpretation of the measured heavy metal interactions with reference to the toxicity of heavy metal-containing dusts is attempted.

  7. Determination of heavy metals in dust from selected nursery and kindergarten classrooms within the Kumasi metropolis of Ghana

    OpenAIRE

    Marian Asantewah Nkansah; Joseph Richmond Fianko; Stephen Mensah; Michael Debrah; George William Francis

    2015-01-01

    The exposure potential of children in nursery and kindergarten schools to metals in dust in the Kumasi Metropolis was studied. Dust samples from 20 selected schools were analyzed for heavy metal levels using atomic absorption spectrophotometry. The results showed that concentrations were in the range of below detection −9.710 μg/g for cobalt, below detection to 33.291 μg/g for chromium, below detection to 41.909 μg/g for lead, below detection to 1.383 μg/g for mercury, while cadmium levels we...

  8. First-principles investigations of Ni3Al(111) and NiAl(110) surfaces at metal dusting conditions

    DEFF Research Database (Denmark)

    Saadi, Souheil; Hinnemann, Berit; Appel, Charlotte C.

    2011-01-01

    We investigate the structure and surface composition of the γ′-Ni3Al(111) and β-NiAl(110) alloy surfaces at conditions relevant for metal dusting corrosion related to catalytic steam reforming of natural gas. In regular service as protective coatings, nickel–aluminum alloys are protected...... by an oxide scale, but in case of oxide scale spallation, the alloy surface may be directly exposed to the reactive gas environment and vulnerable to metal dusting. By means of density functional theory and thermochemical calculations for both the Ni3Al and NiAl surfaces, the conditions under which CO and OH...

  9. H I Column Densities, Metallicities, and Dust Extinction of Metal-Strong Damped Lya Systems

    CERN Document Server

    Kaplan, Kyle F; Herbert-Fort, Stephane; Ellison, Sara L; Dessauges-Zavadsky, Miroslava

    2010-01-01

    With the Blue Channel Spectrograph (BCS) on the MMT telescope, we have obtained spectra to the atmospheric cutoff of quasars previously known to show at least one absorption system at z>1.6 with very strong metal lines (candidate metal-strong damped Lya systems; cMSDLAs). The BCS/MMT spectra yield precise estimates of the HI column densities (NHI) of the systems through Voigt profile analysis of their Lya transitions. Nearly all of the cMSDLAs (41/43) satisfy the NHI criterion of DLAs, 10^20.3. As a population, these systems have systematically higher NHI values than DLAs chosen randomly from quasar sightlines. Combining our NHI measurements with previously measured metal column densities, we estimate metallicities for the MSDLAs. These systems have significantly higher values than randomly selected DLAs; at z~2, the MSDLAs show a median metallicity [M/H] ~ -0.67 that is 0.6dex higher than a corresponding control sample. This establishes MSDLAs as having amongst the most metal-rich gas in the high z universe....

  10. Impacts of dust deposition on dissolved trace metal concentrations (Mn, Al and Fe during a mesocosm experiment

    Directory of Open Access Journals (Sweden)

    K. Wuttig

    2013-04-01

    Full Text Available The deposition of atmospheric dust is the primary process supplying trace elements abundant in crustal rocks (e.g. Al, Mn and Fe to the surface ocean. Upon deposition, the residence time in surface waters for each of these elements differs according to their chemical speciation and biological utilization. Presently, however, the chemical and physical processes occurring after atmospheric deposition are poorly constrained, principally because of the difficulty in following natural dust events in situ. In the present work we examined the temporal changes in the biogeochemistry of crustal metals (in particular Al, Mn and Fe after an artificial dust deposition event. The experiment was contained inside trace metal clean mesocosms (0–12.5 m depths deployed in the surface waters of the northwestern Mediterranean, close to the coast of Corsica within the frame of the DUNE project (a DUst experiment in a low Nutrient, low chlorophyll Ecosystem. Two consecutive artificial dust deposition events, each mimicking a wet deposition of 10 g m−2 of dust, were performed during the course of this DUNE-2 experiment. The changes in dissolved manganese (Mn, iron (Fe and aluminum (Al concentrations were followed immediately after the seeding with dust and over the following week. The Mn, Fe and Al inventories and loss or dissolution rates were determined. The evolution of the inventories after the two consecutive additions of dust showed distinct behaviors for dissolved Mn, Al and Fe. Even though the mixing conditions differed from one seeding to the other, Mn and Al showed clear increases directly after both seedings due to dissolution processes. Three days after the dust additions, Al concentrations decreased as a consequence of scavenging on sinking particles. Al appeared to be highly affected by the concentrations of biogenic particles, with an order of magnitude difference in its loss rates related to the increase of biomass after the addition of dust. In

  11. The metallicity and dust content of a redshift 5 gamma-ray burst host galaxy

    Energy Technology Data Exchange (ETDEWEB)

    Sparre, M.; Krühler, T.; Fynbo, J. P. U.; Watson, D. J.; De Ugarte Postigo, A.; Hjorth, J.; Malesani, D. [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, 2100 Copenhagen (Denmark); Hartoog, O. E.; Kaper, L. [Anton Pannekoek Institute for Astronomy, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam (Netherlands); Wiersema, K. [Department of Physics and Astronomy, University of Leicester, University Road, Leicester, LE1 7RH (United Kingdom); D' Elia, V. [INAF/Rome Astronomical Observatory, via Frascati 33, I-00040 Monteporzio Catone (Roma) (Italy); Zafar, T. [European Southern Observatory, Karl-Schwarzschild-Strasse 2, D-85748 Garching (Germany); Afonso, P. M. J. [Physics and Astronomy Department, American River College, 4700 College Oak Drive, Sacramento, CA 95841 (United States); Covino, S. [INAF, Osservatorio Astronomico di Brera, via E. Bianchi 46, I-23807 Merate (Italy); Flores, H. [Laboratoire GEPI, Observatoire de Paris, CNRS-UMR8111, Universite Paris Diderot 5 place Jules Janssen, F-92195 Meudon (France); Goldoni, P. [APC, Astroparticule et Cosmologie, Universite Paris Diderot, CNRS/IN2P3, CEA/Irfu, Observatoire de Paris, Sorbonne Paris Cité, 10, Rue Alice Domon et Léonie Duquet, F-75205 Paris, Cedex 13 (France); Greiner, J. [Max-Planck-Institut für extraterrestrische Physik, Giessenbachstraße, D-85748 Garching (Germany); Jakobsson, P. [Centre for Astrophysics and Cosmology, Science Institute, University of Iceland, Dunhagi 5, IS-107 Reykjavik (Iceland); Klose, S. [Thüringer Landessternwarte Tautenburg, Sternwarte 5, D-07778 Tautenburg (Germany); Levan, A. J., E-mail: sparre@dark-cosmology.dk [Department of Physics, University of Warwick, Coventry CV4 7AL (United Kingdom); and others

    2014-04-20

    Observations of the afterglows of long gamma-ray bursts (GRBs) allow the study of star-forming galaxies across most of cosmic history. Here we present observations of GRB 111008A, from which we can measure metallicity, chemical abundance patterns, dust-to-metals ratio (DTM), and extinction of the GRB host galaxy at z = 5.0. The host absorption system is a damped Lyα absorber with a very large neutral hydrogen column density of log N(H I)/cm{sup −2}=22.30±0.06 and a metallicity of [S/H] = –1.70 ± 0.10. It is the highest-redshift GRB with such a precise metallicity measurement. The presence of fine-structure lines confirms the z = 5.0 system as the GRB host galaxy and makes this the highest redshift where Fe II fine-structure lines have been detected. The afterglow is mildly reddened with A{sub V} = 0.11 ± 0.04 mag, and the host galaxy has a DTM that is consistent with being equal to or lower than typical values in the Local Group.

  12. Dust-driven Winds and Mass Loss of C-rich AGB Stars with subsolar Metallicities

    CERN Document Server

    Wachter, A; Schröder, K -P; Sedlmayr, E

    2008-01-01

    We investigate the mass loss of highly evolved, low- and intermediate mass stars and stellar samples with subsolar metallicity. We give a qualitative as well as quantitative description which can be applied to LMC/SMC-type stellar populations. For that purpose we apply the same approach as we did for solar metallicity stars and calculate hydrodynamical wind models including dust formation with LMC and SMC abundances under consideration of an adapted model assumption. In particular, we improved the treatment of the radiative transfer problem in order to accommodate larger non-local contributions occurring with smaller opacities. For each wind model we determine an averaged mass-loss rate. The resulting, approximate mass-loss formulae are then applied to well-tested and calibrated stellar evolution calculations in order to quantify the stellar mass loss. The dynamical models for LMC and SMC metallicity result in mass-loss rates of the same order of magnitude as the solar metallicity models which is in this basi...

  13. Digestion of plastic materials for the determination of toxic metals with a microwave oven for household use.

    Science.gov (United States)

    Sakurai, Hiroki; Noro, Junji; Kawase, Akira; Fujinami, Masanori; Oguma, Koichi

    2006-02-01

    A rapid sample-digestion method for the determination of toxic metals, cadmium, chromium, and lead, in polyethylene and polyvinyl chloride has been developed by using a microwave oven for household use. An appropriate amount of the sample taken in a PTFE decomposition vessel was mixed with nitric acid or nitric and sulfuric acids. The vessel was heated in a microwave oven by a predetermined operating program. The digested sample was diluted to a definite volume with water after evaporating most of the nitric acid. The precipitate, if formed, was filtered off by a membrane filter. The metals were determined by ICP-AES. The sample digestion required 5 min (for 20-mg sample) to 25 min (for 60-mg sample). The analytical results obtained for cadmium, chromium, and lead in a polyethylene certified reference material, BCR-680, digested with nitric acid, were in good agreement with the certified values.

  14. Organic contaminants and heavy metals in indoor dust from e-waste recycling, rural, and urban areas in South China: Spatial characteristics and implications for human exposure.

    Science.gov (United States)

    He, Chun-Tao; Zheng, Xiao-Bo; Yan, Xiao; Zheng, Jing; Wang, Mei-Huan; Tan, Xiao; Qiao, Lin; Chen, She-Jun; Yang, Zhong-Yi; Mai, Bi-Xian

    2017-02-27

    The concentrations of several organic contaminants (OCs) and heavy metals were measured in indoor dust from e-waste recycling, rural, and urban areas in South China to illustrate the spatial characteristics of these pollutants and to further evaluate human exposure risks. The median concentrations of polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), decabromodiphenyl ethane (DBDPE), and dechlorane plus (DPs) were 38.6-3560, 2360-30,100, 665-2720, and 19.5-1860ng/g, while the median concentrations of Cd, Pb, Cu, Cr, and Zn were 2.46-40.4, 206-1380, 217- 1200, 25.3-134, and 176-212μg/g in indoor dust. The levels of all pollutants, except Zn, in dust from the e-waste recycling area were significantly higher than those from the other areas. Cd, Pb, and most OCs exhibited similar pollution patterns in the three areas, indicating that e-waste recycling activities are the major pollution source. In contrast, Cu, Cr, Zn, and penta-BDE are likely derived from household products in the rural and urban areas. The highest estimated daily intakes (EDIs) of PCBs, PBDEs, DBDPE, and DPs were 0.15-163, 3.97-1470, 1.26-169, and 0.11-134ng/kg bw/day for toddlers and adults. The highest EDIs of BDE 209 and Pb in toddlers in the e-waste recycling area were 16% and 18 times higher than the reference doses, indicating the high exposure risk of these pollutants in the e-waste recycling area.

  15. Environmental arsenic, cadmium and lead dust emissions from metal mine operations: Implications for environmental management, monitoring and human health

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, Mark Patrick, E-mail: mark.taylor@mq.edu.au; Mould, Simon Anthony; Kristensen, Louise Jane; Rouillon, Marek

    2014-11-15

    Although blood lead values in children are predominantly falling globally, there are locations where lead exposure remains a persistent problem. One such location is Broken Hill, Australia, where the percentage of blood lead values >10 μg/dL in children aged 1–4 years has risen from 12.6% (2010), to 13% (2011) to 21% (2012). The purpose of this study was to determine the extent of metal contamination in places accessible to children. This study examines contemporary exposure risks from arsenic, cadmium, lead, silver and zinc in surface soil and dust, and in pre- and post-play hand wipes at six playgrounds across Broken Hill over a 5-day period in September 2013. Soil lead (mean 2,450 mg/kg) and zinc (mean 3,710 mg/kg) were the most elevated metals in playgrounds. Surface dust lead concentrations were consistently elevated (mean 27,500 μg/m{sup 2}) with the highest lead in surface dust (59,900 μg/m{sup 2}) and post-play hand wipes (60,900 μg/m{sup 2}) recorded close to existing mining operations. Surface and post-play hand wipe dust values exceeded national guidelines for lead and international benchmarks for arsenic, cadmium and lead. Lead isotopic compositions ({sup 206}Pb/{sup 207}Pb, {sup 208}Pb/{sup 207}Pb) of surface dust wipes from the playgrounds revealed the source of lead contamination to be indistinct from the local Broken Hill ore body. The data suggest frequent, cumulative and ongoing mine-derived dust metal contamination poses a serious risk of harm to children. - Highlights: 1.Playground soils and surface dust in a mining town have high metal concentrations. 2.Elevated levels of As, Cd, Pb and Zn dust are found on playground users′ hands. 3.Pb isotope analysis shows that the source of playground dust is ore body Pb. 4.Surface mine operations must be contained to reduce childhood lead exposure risks. 5.Mine environmental licences need to set trigger values for As, Cd, Pb and Zn dust.

  16. Separation of heavy metals from salts in multicomponent gas by a two-stage dust collection technique

    Energy Technology Data Exchange (ETDEWEB)

    Okada, Takashi, E-mail: t-okada@u-fukui.ac.jp [Laboratory of Solid Waste Disposal Engineering, Graduate School of Engineering, Hokkaido University, Kita 13 Nishi 8, Kita-ku, Sapporo 060-8628 (Japan); Headquarters for Innovative Society-Academic cooperation, Fukui University, Bunkyo 3-9-1, Fukui 910-8507 (Japan); Nishimoto, Kaoru [Laboratory of Solid Waste Disposal Engineering, Graduate School of Engineering, Hokkaido University, Kita 13 Nishi 8, Kita-ku, Sapporo 060-8628 (Japan)

    2013-06-15

    Highlights: • A heavy metal separation method from salts in a multicomponent gas was studied. • A two-stage dust collection technique was used for the metal separation. • The first stage dust collection at 800 °C was better for the separation. • A reductive atmosphere also promoted the efficiency of the separation. •The collected heavy metals were extracted with water, acid, or CH{sub 3}COONH{sub 4} solution. -- Abstract: A Pb and Zn separation method from salts (Na, K, and Cl) in a simulated multicomponent gas generated by the incineration fly ash melting is studied. The heavy metals are separated using a two-stage dust collection technique. A standard reagents mixture is volatilized by heating in a lab-scale reactor to generate the simulated multicomponent gas. The volatilized salts in the gas are condensed and collected by a filter at a high temperature (600–800 °C), allowing Pb and Zn to pass through the filter as gaseous species. The gaseous heavy metals are condensed by lowering their temperature to 100 °C and collected. The metal separation is promoted by elevating the temperature used in the first-stage dust collection to 800 °C and maintaining a reductive atmosphere in the reactor. Subsequently, a sequential chemical extraction is performed on the obtained materials to evaluate the metals leaching characteristics from the materials. In the separated salts to be landfilled, a portion of toxic metals such as Pb, Cd, As, and Cr remain as water-soluble compounds. The separated Pb and Zn, to be extracted and recovered with precipitation for the metal enrichment, can be extracted using water, acid (pH 3), or CH{sub 3}COONH{sub 4} solution (1 M)

  17. Identification of trace metal pollution in urban dust from kindergartens using magnetic, geochemical and lead isotopic analyses

    Science.gov (United States)

    Zhu, Zongmin; Sun, Guangyi; Bi, Xiangyang; Li, Zhonggen; Yu, Genhua

    2013-10-01

    In the present study, magnetic measurements were combined with geochemical analysis and stable Pb isotopic ratios to reveal the distribution and origination of trace metal pollutants in kindergarten dusts from a typical urban environment of Wuhan, central China. The geoaccumulation index (Igeo) of magnetic properties was more prominent than those of individual metals. The magnetic susceptibility (MS) and trace metals (Zn, Pb, and Cu) in this study together with published results from other Chinese cities formed a liner relationship, suggesting that metal contaminants in Chinese urban areas had similar MS to metal ratios, which could be used as an indicator for identification of pollution sources between Chinese cities and the other Asian cities. Stable Pb isotopic ratios (1.1125-1.1734 for 206Pb/207Pb and 2.4457-2.4679 for 208Pb/207Pb) in the urban dusts from Wuhan were characterized by higher 208Pb component in comparison with those from other Chinese cities. This result combined with principal component analysis (PCA) indicated that metal pollutants in the dusts were derived from industrial activities and coal combustion, whereas the traffic emissions were no longer a predominant pollution source in urban environment. Our study demonstrated that environmental magnetic methods could not only reveal the overall situation of trace metal contamination, but also prove evidence in the identification of pollution sources.

  18. Dust Abundance Variations in the Magellanic Clouds: Probing the Life-cycle of Metals with All-sky Surveys

    Science.gov (United States)

    Roman-Duval, Julia; Bot, Caroline; Chastenet, Jeremy; Gordon, Karl

    2017-06-01

    Observations and modeling suggest that dust abundance (gas-to-dust ratio, G/D) depends on (surface) density. Variations of the G/D provide timescale constraints for the different processes involved in the life cycle of metals in galaxies. Recent G/D measurements based on Herschel data suggest a factor of 5-10 decrease in dust abundance between the dense and diffuse interstellar media (ISM) in the Magellanic Clouds. However, the relative nature of the Herschel measurements precludes definitive conclusions as to the magnitude of those variations. We investigate variations of the dust abundance in the LMC and SMC using all-sky far-infrared surveys, which do not suffer from the limitations of Herschel on their zero-point calibration. We stack the dust spectral energy distribution (SED) at 100, 350, 550, and 850 microns from IRAS and Planck in intervals of gas surface density, model the stacked SEDs to derive the dust surface density, and constrain the relation between G/D and gas surface density in the range 10-100 M ⊙ pc-2 on ˜80 pc scales. We find that G/D decreases by factors of 3 (from 1500 to 500) in the LMC and 7 (from 1.5× {10}4 to 2000) in the SMC between the diffuse and dense ISM. The surface-density-dependence of G/D is consistent with elemental depletions, and with simple modeling of the accretion of gas-phase metals onto dust grains. This result has important implications for the sub-grid modeling of galaxy evolution, and for the calibration of dust-based gas-mass estimates, both locally and at high redshift.

  19. Carcinogenicity studies on fibres, metal compounds, and some other dusts in rats.

    Science.gov (United States)

    Pott, F; Ziem, U; Reiffer, F J; Huth, F; Ernst, H; Mohr, U

    1987-01-01

    About 50 dusts were examined on their carcinogenicity in rats mainly after intraperitoneal injection and some after intratracheal instillation. In the i.p. test, very low doses between 0.05 and 0.5 mg asbestos led to tumour incidences of about 20 to 80%. Polyvinyl-pyridine-N-oxide prolonged the tumour latency after injection of actinolite. 60 mg attapulgite from three sources with short fibre lengths were not shown to be carcinogenic but an attapulgite sample with longer fibres had a moderate effect. Relatively thick rock and ceramic fibres (median greater than 1 micron) induced tumours, but slag and wollastonite fibres did not, probably because of their better solubility. Intratracheal instillations of glass microfibres (20 X 0.5 mg) led to lung tumours in 5 of 34 rats (0 in control). The carcinogenic potency of an inorganic fibre depends on its size and persistency, and possibly also on other properties, especially on the surface. Nickel powder, nickel oxide, nickel subsulfide and cadmium sulfide were all found to be carcinogenic in the two tests. Cadmium chloride and cadmium oxide could only be administered in very low doses because of their high acute toxicity. A high amount of magnetite (15 X 15 mg i.tr.) led to an unexpected lung tumour incidence of 69%. The i.p. test in rats proved to be very sensitive for detecting the carcinogenic potency of non-acute toxic natural and man-made mineral dusts as well as metal compounds. This means that, if a high dose of one of these dusts does not induce tumours in this test, no suspicion of carcinogenic potency can be substantiated.

  20. Extraction of Nanostructured Metal Oxides from the Furnace Dust for the Realization of Low Cost Solar Applications

    Science.gov (United States)

    Girisun, T. C. Sabari; Babeela, C.; Vidhya, V.

    This article reports the simple one step process for the extraction of nanostructured metal oxides from the industrial waste (EOFD) for the realization of low cost solar applications. By hydrothermal technique with NaOH and H2SO4, valuable metals were obtained in the form of metal oxides. The identification of compounds and structural characterization were carried out through XRD and SEM analysis. Thus the metal oxides derived could be helpful to reduce the burden on the environment from the electric oil furnace dust, increase the development of the source nano material and reduce the cost of raw materials for solar cell applications.

  1. Concentrations and bioaccessibility of metals in vegetation and dust near a mining haul road, Cape Krusenstern National Monument, Alaska

    Science.gov (United States)

    Brumbaugh, William G.; Morman, Suzette A.; May, Thomas W.

    2011-01-01

    Vegetation, sub-surface peat, and road dust were sampled near the Delong Mountain Transportation System (DMTS) haul road in northwest Alaska in 2005-2006 to document aluminum, barium, cadmium, lead, and zinc concentrations, and to evaluate bioaccessibility of these metals. The DMTS haul road is the transport corridor between Red Dog Mine (a large-scale, lead-zinc mine and mill) and the coastal shipping port, and it traverses National Park Service lands. Compared to reference locations, total metal concentrations in four types of vegetation (birch, cranberry, and willow leaves, and cotton grass blades/stalks) collected 25 m from the haul road were enriched on average by factors of 3.5 for zinc, 8.0 for barium, 20 for cadmium, and 150 for lead. Triple rinsing of vegetation with a water/methanol mixture reduced metals concentrations by at most 50%, and cadmium and zinc concentrations were least affected by rinsing. Cadmium and zinc bioaccessibility was greater in vegetation (50% to 100%) than in dust (15% to 20%); whereas the opposite pattern was observed for lead bioaccessibility (<30% in vegetation; 50% in dust). Barium exhibited low-to-intermediate bioaccessibility in dust and vegetation (20% to 40%), whereas aluminum bioaccessibility was relatively low (<6%) in all sample types. Our reconnaissance-level study indicates that clean-up and improvements in lead/zinc concentrate transfer activities have been effective; however, as of 2006, metal dispersion from past and/or present releases of fugitive dusts along the DMTS road still may have been contributing to elevated metals in surface vegetation. Vegetation was most enriched in lead, but because bioaccessibility of cadmium was greater, any potential risks to animals that forage near the haul road might be equally important for both of these metals.

  2. Metal and Metalloid Contaminants in Airborne Dust Associated with Mining Operations

    Science.gov (United States)

    Betterton, E. A.; Csavina, J. L.; Field, J. P.; Landázuri, A. C.; Felix Villar, O.; Rine, K. P.; Sáez, A.; Pence, J.; Shayan, H.; Russell, M.

    2011-12-01

    Mining operations are potential sources of airborne metal and metalloid contaminants through both direct smelter emissions and wind erosion of mine tailings. The warmer, drier conditions predicted for the Southwestern US by climate models may make contaminated atmospheric dust and aerosols increasingly important, with potential deleterious effects on human health and ecology. In this work, we report the size-resolved chemical characterization of atmospheric aerosols sampled near an inactive Superfund site and at an active mining and smelting site in Arizona. Aerosols were characterized with 10-stage (0.054 to 18 μm aerodynamic diameter) multiple orifice uniform deposit impactors (MOUDI), Dustrack monitors, and total suspended particulate (TSP) collectors. The MOUDI results show that arsenic and lead concentrations follow a bimodal distribution, with maxima centered at approximately 0.3 and 7.0 μm aerodynamic diameter. We hypothesize that the sub-micron arsenic and lead are the product of condensation and coagulation of smelting vapors. In the coarse size, contaminants are thought to originate as aeolian dust from mine tailings and other sources.

  3. Impacts of dust deposition on dissolved trace metal concentrations (Mn, Al and Fe during a mesocosm experiment

    Directory of Open Access Journals (Sweden)

    K. Wuttig

    2012-10-01

    Full Text Available The deposition of atmospheric dust is the primary process supplying trace elements abundant in crustal rocks (e.g. Al, Mn and Fe to the surface ocean. Upon deposition, the residence time in surface waters for each of these elements differs according to their chemical speciation and biological utilization. Presently however their behavior after atmospheric deposition is poorly constrained, principally because of the difficulty in following natural dust events in-situ. In the present work we examined the temporal changes in the biogeochemistry of crustal metals (in particular Al, Mn and Fe after an artificial dust deposition event. The experiment was contained inside trace metal clean mesocosms (0–12.5 m depths deployed in the surface waters of the Northwestern Mediterranean, close to the coast of Corsica in the frame of the DUNE project (a DUst experiment in a low Nutrient low chlorophyll Ecosystem. Two consecutive artificial dust deposition events, each mimicking a wet deposition of 10 g m−2 of dust, were performed during the course of this DUNE-2 experiment. The changes in dissolved manganese (dMn, iron (dFe and aluminium (dAl concentrations were followed immediately and over the following week and their inventories and loss or dissolution rates were determined. The evolution of the inventories after the two consecutive additions of dust showed distinct behaviors for dMn, dAl and dFe. Even though the mixing conditions differed from one seeding to the other, dMn and dAl showed clear increases directly after both seedings due to dissolution processes. Three days after the dust additions, dAl concentrations decreased as a consequence of scavenging on sinking particles. dAl appeared to be highly affected by the concentrations of biogenic particles, with an order of magnitude difference in its loss rates related to the increase of biomass after the addition of dust. For dFe concentrations, the first dust addition decreased the

  4. Metallicities and dust content of proximate damped Lyman alpha systems in the Sloan Digital Sky Survey

    CERN Document Server

    Ellison, Sara L; Mendel, J Trevor

    2010-01-01

    Composite spectra of 85 proximate absorbers (log N(HI)>20 and velocity difference between the absorption and emission redshift, dv6000 km/s, with further sub-samples to investigate the metal line dependence on N(HI) and QSO luminosity. Low (e.g. SiII and FeII) and high ionization (e.g. SiIV and CIV) species alike have equivalent widths (EWs) that are larger by factors of 1.5 -- 3 in the dv6000 km/s spectrum. The EWs show an even stronger dependence on dv if only the highest neutral hydrogen column density (log N(HI)>20.7) absorbers are considered. We conclude that PDLAs generally have higher metallicities than intervening absorbers, with the enhancement being a function of both dv and N(HI). It is also found that absorbers near QSOs with lower rest-frame UV luminosities have significantly stronger metal lines. We speculate that absorbers near to high luminosity QSOs may have had their star formation prematurely quenched. Finally, we search for the signature of dust reddening by the PDLAs, based on an analysis...

  5. Incense and Joss Stick Making in Small Household Factories, Thailand

    Directory of Open Access Journals (Sweden)

    S Siripanich

    2014-07-01

    Full Text Available Background: Incense and joss stick are generally used in the world. Most products were made in small household factories. There are many environmental and occupational hazards in these factories. Objective: To evaluate the workplace environmental and occupational hazards in small household incense and joss stick factories in Roi-Et, Thailand. Methods: Nine small household factories in rural areas of Roi-Et, Thailand, were studied. Dust concentration and small aerosol particles were counted through real time exposure monitoring. The inductively coupled plasma optical emission spectrometry (ICP-OES was used for quantitative measurement of heavy metal residue in incense products. Results: Several heavy metals were found in dissolved dye and joss sticks. Those included barium, manganese, and lead. Rolling and shaking processes produced the highest concentration of dust and aerosols. Only 3.9 % of female workers used personal protection equipment. Conclusion: Dust and chemicals were major threats in small household incense and joss stick factories in Thailand. Increasing awareness towards using personal protection equipment and emphasis on elimination of environmental workplace hazards should be considered to help the workers of this industry.

  6. Partitioning of heavy metals over different chemical fraction in street dust of Murcia (Spain) as a basis for risk assessment

    NARCIS (Netherlands)

    Acosta, J.A.; Faz, A.; Kalbitz, K.; Jansen, B.; Martínez-Martínez, S.

    2014-01-01

    Dust samples were collected from urban, suburban, industrial, highways, and natural sites from the vicinity of Murcia City, Spain. Chemical and physical properties were determined as well as the partitioning of the heavy metals Cu, Pb, Zn and Cd over exchangeable pools, association with carbonates,

  7. Attic Dust Analysis Approach for Evaluation of Heavy Metal Deposition on the El Paso Del Norte Region

    Science.gov (United States)

    Shekhter, E. G.; van Pelt, S.; Pannell, K.; Gill, T. E.; Barnes, M. A.

    2010-12-01

    The El Paso del Norte region in the United States is a region of complex topography that is the home to more than 2 million people who share the same air. A large non-ferrous smelter (primary lead-copper smelter),owned by the American Smelting and Refining Company (ASARCO), was functioning in the Rio Grande River valley on the west side of the Franklin Mountains that divide the city of El Paso and across the river from Juarez, Mexico’s largest city on the United States border. During the more than 100 years of operation, beginning in 1887, the ASARCO smelter emissions considerably deteriorated the already complex environmental condition on the US-Mexican border. In order to identify the sources and patterns of heavy metal dispersion, we used an attic dust analyses approach which has not been previously been applied in this area. Undisturbed attic dust can provide an integrated history of atmospheric loading of particulates emanating from geological, biological and anthropogenic sources and can help to reconstruct the air pollution history on a local scale. We sampled attic dust and dust from undisturbed surfaces in 15 buildings of varying ages from three neighborhoods in the cities of El Paso and Juarez. The dust samples and samples of unpolluted buried soil horizons in the area were extracted with aqua regia and analyzed by ICP-AES and ICP-MS. Enrichment ratios (ER) were calculated by dividing the concentration of a trace metal in the attic dust by the mean concentration of the same element in the buried soil horizons. Mean ER for Pb were 263.3, 95.4, and 70.2 for dust collected in a neighborhood near the smelter, downtown Juarez, and an El Paso neighborhood on the other side of the Franklin Mountains from the smelter. Greater ER for As, Cd, Zn, Sb, and Cu followed the same trends, by neighborhood, noted for Pb. In addition, dust collected from attics surfaces (pipes, ducts, storage containers) post-dating smelter disclosure had lower ER for the trace metals

  8. Revealing the cold dust in low-metallicity environments. I. Photometry analysis of the Dwarf Galaxy Survey with Herschel

    Science.gov (United States)

    Rémy-Ruyer, A.; Madden, S. C.; Galliano, F.; Hony, S.; Sauvage, M.; Bendo, G. J.; Roussel, H.; Pohlen, M.; Smith, M. W. L.; Galametz, M.; Cormier, D.; Lebouteiller, V.; Wu, R.; Baes, M.; Barlow, M. J.; Boquien, M.; Boselli, A.; Ciesla, L.; De Looze, I.; Karczewski, O. Ł.; Panuzzo, P.; Spinoglio, L.; Vaccari, M.; Wilson, C. D.

    2013-09-01

    Context. We present new photometric data from our Herschel guaranteed time key programme, the Dwarf Galaxy Survey (DGS), dedicated to the observation of the gas and dust in low-metallicity environments. A total of 48 dwarf galaxies were observed with the PACS and SPIRE instruments onboard the Herschel Space Observatory at 70, 100, 160, 250, 350, and 500 μm. Aims: The goal of this paper is to provide reliable far-infrared (FIR) photometry for the DGS sample and to analyse the FIR/submillimetre (submm) behaviour of the DGS galaxies. We focus on a systematic comparison of the derived FIR properties (FIR luminosity, LFIR, dust mass, Mdust, dust temperature, T, emissivity index, β) with more metal-rich galaxies and investigate the detection of a potential submm excess. Methods: The data reduction method is adapted for each galaxy in order to derive the most reliable photometry from the final maps. The derived PACS flux densities are compared with the Spitzer MIPS 70 and 160 μm bands. We use colour-colour diagrams to analyse the FIR/submm behaviour of the DGS galaxies and modified blackbody fitting procedures to determine their dust properties. To study the variation in these dust properties with metallicity, we also include galaxies from the Herschel KINGFISH sample, which contains more metal-rich environments, totalling 109 galaxies. Results: The location of the DGS galaxies on Herschel colour-colour diagrams highlights the differences in dust grain properties and/or global environments of low-metallicity dwarf galaxies. The dust in DGS galaxies is generally warmer than in KINGFISH galaxies (TDGS ~ 32 K and TKINGFISH ~ 23 K). The emissivity index, β, is ~1.7 in the DGS, however metallicity does not make a strong effect on β. The proportion of dust mass relative to stellar mass is lower in low-metallicity galaxies: Mdust/Mstar ~ 0.02% for the DGS versus 0.1% for KINGFISH. However, per unit dust mass, dwarf galaxies emit about six times more in the FIR/submm than

  9. Sustainable synthesis of metals-doped ZnO nanoparticles from zinc-bearing dust for photodegradation of phenol.

    Science.gov (United States)

    Wu, Zhao-Jin; Huang, Wei; Cui, Ke-Ke; Gao, Zhi-Fang; Wang, Ping

    2014-08-15

    A novel strategy of waste-cleaning-waste is proposed in the present work. A metals-doped ZnO (M-ZnO, M = Fe, Mg, Ca and Al) nanomaterial has been prepared from a metallurgical zinc-containing solid waste "fabric filter dust" by combining sulfolysis and co-precipitation processes, and is found to be a favorable photocatalyst for photodegradation of organic substances in wastewater under visible light irradiation. All the zinc and dopants (Fe, Mg, Ca and Al) for preparing M-ZnO are recovered from the fabric filter dust, without any addition of chemical as elemental source. The dust-derived M-ZnO samples deliver single phase indexed as the hexagonal ZnO crystal, with controllable dopants species. The photocatalytic activity of the dust-derived M-ZnO samples is characterized by photodegradation of phenol aqueous solution under visible light irradiation, giving more prominent photocatalytic behaviors than undoped ZnO. Such enhancements may be attributed to incorporation of the dust-derived metal elements (Fe, Mg, Ca and Al) into ZnO structure, which lead to the modification of band gap and refinement of grain size. The results show a feasibility to utilize the industrial waste as a resource of photodegradating organic substances in wastewater treatments.

  10. Dust Production from Sub-Solar to Super-Solar Metallicity in Thermally Pulsing Asymptotic Giant Branch Stars

    Science.gov (United States)

    Nanni, A.; Bressan, A.; Marigo, P.; Girardi, L.; Javadi, A.; van Loon, J. Th.

    2015-08-01

    We discuss the dust chemistry and growth in the circumstellar envelopes (CSEs) of Thermally Pulsing Asymptotic Giant Branch (TP-AGB) star models, computed with the COLIBRI code, at varying initial mass and metallicity (Z = 0.001, 0.008, 0.02, 0.04, 0.06). A relevant result of our analysis deals with silicate production in M stars. We show that, in order to reproduce the observed trend between terminal velocities and mass-loss rates in Galactic M giants, one has to significantly reduce the efficiency of chemisputtering by H2 molecules, usually considered the most effective dust destruction mechanism. This conclusion is in agreement with the most recent laboratory results, which show that silicates may condense already at Tcond˜1400 K, rather than only at Tcond˜1000 K, as obtained by models that include chemisputtering. From analysis of the total dust ejecta, we find that the dust-to-gas ratios of the total ejecta from intermediate-mass stars are much less dependent on metallicity than usually assumed. In a broader context, our results are suitable for studying the dust enrichment of the interstellar medium provided by TP-AGB stars in both nearby and high-redshift galaxies.

  11. Dust-off

    OpenAIRE

    Maycroft, Neil; Cheang, Shu Lea

    2015-01-01

    The fan of a motherboard switches on and off intermittently. It blows household dust, removed from the inside of a computer carcass, into the air. The dust then settles onto the motherboard, to be blown off again. This continual movement of dust is contained in the piece. However, it should remind us that the ceaseless creation and motion of unconfined dust accompanies all stages of the e-waste journey.

  12. Dust-off

    OpenAIRE

    Maycroft, Neil; Cheang, Shu Lea

    2015-01-01

    The fan of a motherboard switches on and off intermittently. It blows household dust, removed from the inside of a computer carcass, into the air. The dust then settles onto the motherboard, to be blown off again. This continual movement of dust is contained in the piece. However, it should remind us that the ceaseless creation and motion of unconfined dust accompanies all stages of the e-waste journey.

  13. Environmental arsenic, cadmium and lead dust emissions from metal mine operations: Implications for environmental management, monitoring and human health.

    Science.gov (United States)

    Taylor, Mark Patrick; Mould, Simon Anthony; Kristensen, Louise Jane; Rouillon, Marek

    2014-11-01

    Although blood lead values in children are predominantly falling globally, there are locations where lead exposure remains a persistent problem. One such location is Broken Hill, Australia, where the percentage of blood lead values >10 μg/dL in children aged 1-4 years has risen from 12.6% (2010), to 13% (2011) to 21% (2012). The purpose of this study was to determine the extent of metal contamination in places accessible to children. This study examines contemporary exposure risks from arsenic, cadmium, lead, silver and zinc in surface soil and dust, and in pre- and post-play hand wipes at six playgrounds across Broken Hill over a 5-day period in September 2013. Soil lead (mean 2,450 mg/kg) and zinc (mean 3,710 mg/kg) were the most elevated metals in playgrounds. Surface dust lead concentrations were consistently elevated (mean 27,500 μg/m(2)) with the highest lead in surface dust (59,900 μg/m(2)) and post-play hand wipes (60,900 μg/m(2)) recorded close to existing mining operations. Surface and post-play hand wipe dust values exceeded national guidelines for lead and international benchmarks for arsenic, cadmium and lead. Lead isotopic compositions ((206)Pb/(207)Pb, (208)Pb/(207)Pb) of surface dust wipes from the playgrounds revealed the source of lead contamination to be indistinct from the local Broken Hill ore body. The data suggest frequent, cumulative and ongoing mine-derived dust metal contamination poses a serious risk of harm to children.

  14. Experimental approaches and analytical technique for determining heavy metals in fallen dust at ferrosilicon production factory in Edfu, Aswan, Egypt

    Institute of Scientific and Technical Information of China (English)

    SOLTAN M.E.; RAGEH H.M.; RAGEH N.M.; AHMED M.E.

    2005-01-01

    In this study aimed to evaluate the pollution extent of metals and nonmetals inside and outside the ferrosilicon production factory in Edfu, Aswan, Egypt, raw materials (quartz, cokes, iron oxides), ferrosilicon alloy, silica fume, dust and suspended dust (at different sites) samples were collected from the factory, and fallen dust samples were collected from outside the factory, horizontally (at different sites and different distance and directions) and vertically (at different floors in the selected buildings). Gravimetric methods, X-ray fluorescence (XRF), flame photometer, wide range carbon determinator and atomic absorption spectroscopy tools were used for elements determination. The results indicating that the fallen dust and its element contents on southern factory walls being higher than those on eastern factory walls may be due to the nature of the dusts and effects of wind force and wind direction. Fallen dust levels in different regions outside the factory were found to be affected by the distance, direction and floors. The nature of dust samples was affected by gravity and the suspended dust in different factory units depended on the work capacity and method of handling materials by personnel in different production units. Silica fume was a complicated problem, had dangerous effect against the workers' health, and was characterized by high concentrations of SiO2(90.6%~93.6%) and heavy metals (Mn, 420.6×10-6~520.3×10-6; Fe, 2354×10-6~2685×10-6; Co, 80.7×10-6~101.6×10 6 and Ni,5.3× 10-6~6.05× 10-6). The TSP (Total Suspended Particulate) levels in all factory units were higher than the recommended air quality value (70 μg/m3) under Egyptian law. The effect of ferrosilicon factory fallen dust on the surrounding regions decreased with increasing distance between the factory and these regions. The suspended dust samples in the factory units and their components greatly exceeded national and international standards, so health and

  15. Heavy metal pollution of road dust and roadside soil near a major rural highway.

    Science.gov (United States)

    Pagotto, C; Rémy, N; Legret, M; Le Cloirec, P

    2001-03-01

    The concentrations of lead, copper, cadmium, zinc, nickel and chromium were measured in road dust and roadside soils from a French major highway. The profiles of total levels in the soil as a function of distance from the road edge and as a function of depth were investigated. Lead, zinc, copper and, to a lesser extent, cadmium contamination were found in samples taken on the surface and in the immediate vicinity of the road. The observed concentrations decreased rapidly with distance and depth. Soil samples appeared to exhibit little nickel and chromium pollution. The geochemical phases on which heavy metals (lead, copper, zinc, cadmium and chromium) were fixed preferentially, as well as the potential mobility of the different metals under certain physical and chemical conditions were evaluated. Sequential extractions and single extractions with different reagents were performed. Chromium, which was present mostly in residual form, was mainly of natural origin in the studied samples and was not highly mobilisable. Cadmium was the most easily exchangeable element in case of variations in the physical and chemical conditions but the quantities involved remained small. Lead and copper did not appear to be highly mobile. Only drastic conditions, such as those that may be produced by accidental spillage of a chemical product (acid or complexing agent), mobilised them quantitatively. A significant risk of mobilisation was to be feared only in the case of zinc, which is very sensitive to acid pH.

  16. Assessing the bioavailability and risk from metal-contaminated soils and dusts

    Science.gov (United States)

    Exposure to contaminated soil and dust is an important pathway in human health risk assessment. Physical and chemical characteristics, as well as biological factors, determine the bioaccessibility/bioavailability of soil and dust contaminants. Within a single sample, contaminat...

  17. Assessment of contamination for inorganic elements and phthalate esters in household dust from the metropolitan region of Sao Paulo; Avaliacao da contaminacao por elementos inorganicos e esteres ftalicos em poeira domestica da regiao metropolitana de Sao Paulo

    Energy Technology Data Exchange (ETDEWEB)

    Scapin, Valdirene de Oliveira

    2009-07-01

    Household dust has been identified as an important vector of exposure by inorganic and organic substances potentially toxic in children and adults. The dust composition has a strong influence of contaminants provided from internal and external environments. During the natural process of wearing or weather incidents of artifacts and materials variety, the chemical substances are released into the environment in the steam form or by leaching from final products. Once released, they can be accumulated and enriched in the dust; and by continuous exposure (inhalation, ingestion and dermal contact mechanisms), these substances are harmful to human health. In this work, a study to determine the inorganic constituents and phthalate esters concentrations in residential indoor environment dust samples, correlating them with the probable anthropogenic sources was proposed. Dust samples were collected from 69 residences in neighborhoods Pirituba, Freguesia do O, Jaragua and Perus of the Sao Paulo metropolitan region, using a domestic vacuum cleaner, between 2006 and 2008. The samples were sieved in the fractions of 850, 850-300, 300-150, 150-75, 75-63 and <63 {mu}m. The analysis by X-ray fluorescence (WDXRF) showed the presence of Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Br, Rb, Sr, Zr and Pb. The presence of phthalate esters (DEHP, DnBP, DEP, DEHA, DMP and BBP) was detected, by GCMS analyses. From the enrichment factor (EF), the elements P, S, Cr, Ni, Cu, Zn and Pb were classified as being significant and extremely enriched in the dust. The natural and anthropogenic contributions by statistical tools as factor analysis (AF) and cluster were identified. The elements Cr, Ni, Cu, Zn and Pb were present significantly elevated concentrations in relation to the total exposure values (ingestion, inhalation and skin contact) and to risk. (author)

  18. Metallicities and dust content of proximate damped Lyman α systems in the Sloan Digital Sky Survey

    Science.gov (United States)

    Ellison, Sara L.; Prochaska, J. Xavier; Mendel, J. T.

    2011-03-01

    Composite spectra of 85 proximate absorbers [log N(H I) ≥ 20 cm-2 and velocity difference between the absorption and emission redshifts, ΔV 6000 km s-1, with further sub-samples to investigate the metal-line dependence on N(H I) and QSO luminosity. Low (e.g. Si II and Fe II) and high ionization (e.g. Si IV and C IV) species alike have equivalent widths (EWs) that are larger by factors of 1.5-3 in the ΔV 6000 km s-1 spectrum. The EWs show an even stronger dependence on ΔV if only the highest neutral hydrogen column density [log N(H I) ≥ 20.7] absorbers are considered. We conclude that proximate damped Lyman α systems (PDLAs) generally have higher metallicities than intervening absorbers, with the enhancement being a function of both ΔV and N(H I). It is also found that absorbers near QSOs with lower rest-frame UV luminosities have significantly stronger metal lines. We speculate that absorbers near to high luminosity QSOs may have had their star formation prematurely quenched. There is no evidence for Lyα emission in the trough of the composite spectrum. Finally, we search for the signature of dust reddening by the PDLAs, based on an analysis of the QSO continuum slopes relative to a control sample, and determine a limit of E(B-V) extinction curve. This work provides an empirical motivation for distinguishing between proximate and intervening DLAs and establishes a connection between the QSO environment and galaxy properties at high redshifts.

  19. The Herschel Virgo Cluster Survey. IX. Dust-to-gas mass ratio and metallicity gradients in four Virgo spiral galaxies

    CERN Document Server

    Magrini, Laura; Corbelli, Edvige; Cortese, Luca; Hunt, Leslie; Smith, Matthew; Vlahakis, Catherine; Davies, Jonathan; Bendo, George J; Baes, Maarten; Boselli, Alessandro; Clemens, Marcel; Casasola, Viviana; De Looze, Ilse; Fritz, Jacopo; Giovanardi, Carlo; Grossi, Marco; Hughes, Thomas; Madden, Suzanne; Pappalardo, Ciro; Pohlen, Michael; Alighieri, Sperello di Serego; Verstappen, Joris

    2011-01-01

    Using Herschel data from the Open Time Key Project the Herschel Virgo Cluster Survey (HeViCS), we investigated the relationship between the metallicity gradients expressed by metal abundances in the gas phase as traced by the chemical composition of HII regions, and in the solid phase, as traced by the dust-to-gas mass ratio. We derived the radial gradient of the dust-to-gas mass ratio for all galaxies observed by HeViCS whose metallicity gradients are available in the literature. They are all late type Sbc galaxies, namely NGC4254, NGC4303, NGC4321, and NGC4501. We examined different dependencies on metallicity of the CO-to-H$_2$ conversion factor (\\xco), used to transform the $^{12}$CO observations into the amount of molecular hydrogen. We found that in these galaxies the dust-to-gas mass ratio radial profile is extremely sensitive to choice of the \\xco\\ value, since the molecular gas is the dominant component in the inner parts. We found that for three galaxies of our sample, namely NGC4254, NGC4321, and N...

  20. VARIATIONS OF MID- AND FAR-INFRARED LUMINOSITIES AMONG EARLY-TYPE GALAXIES: RELATION TO STELLAR METALLICITY AND COLD DUST

    Energy Technology Data Exchange (ETDEWEB)

    Mathews, William G.; Brighenti, Fabrizio [University of California Observatories/Lick Observatory, Board of Studies in Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States); Temi, Pasquale; Amblard, Alexandre, E-mail: mathews@ucolick.org, E-mail: fabrizio.brighenti@unibo.it, E-mail: pasquale.temi@nasa.gov [Astrophysics Branch, NASA/Ames Research Center, MS 245-6, Moffett Field, CA 94035 (United States)

    2013-05-01

    The Hubble morphological sequence from early to late galaxies corresponds to an increasing rate of specific star formation. The Hubble sequence also follows a banana-shaped correlation between 24 and 70 {mu}m luminosities, both normalized with the K-band luminosity. We show that this correlation is significantly tightened if galaxies with central active galactic nucleus (AGN) emission are removed, but the cosmic scatter of elliptical galaxies in both 24 and 70 {mu}m luminosities remains significant along the correlation. We find that the 24 {mu}m variation among ellipticals correlates with stellar metallicity, reflecting emission from hot dust in winds from asymptotic giant branch stars of varying metallicity. Infrared surface brightness variations in elliptical galaxies indicate that the K - 24 color profile is U-shaped for reasons that are unclear. In some elliptical galaxies, cold interstellar dust emitting at 70 and 160 {mu}m may arise from recent gas-rich mergers. However, we argue that most of the large range of 70 {mu}m luminosity in elliptical galaxies is due to dust transported from galactic cores by feedback events in (currently IR-quiet) AGNs. Cooler dusty gas naturally accumulates in the cores of elliptical galaxies due to dust-cooled local stellar mass loss and may accrete onto the central black hole, releasing energy. AGN-heated gas can transport dust in cores 5-10 kpc out into the hot gas atmospheres where it radiates extended 70 {mu}m emission but is eventually destroyed by sputtering. This, and some modest star formation, defines a cycle of dust creation and destruction. Elliptical galaxies evidently undergo large transient excursions in the banana plot in times comparable to the sputtering time or AGN duty cycle, 10 Myr. Normally regarded as passive, elliptical galaxies are the most active galaxies in the IR color-color correlation.

  1. [Dust particles and metals in outdoor and indoor air of Upper Silesia].

    Science.gov (United States)

    Górny, R L; Jedrzejczak, A; Pastuszka, J S

    1995-01-01

    This work contains the results of the aerosol mass size distribution and preliminary studies on concentrations and size distribution of heavy metals (Pb, Zn, Cu, Mn, Fe and Cd) in indoor and outdoor environment in Upper Silesia (the highly industrialized region in the southern part of Poland). In studies, the measurements of aerosol concentration, mass size distribution, and evaluation of heavy metals concentration were made from December 1992 to April 1994 in some apartments in five towns in Upper Silesia and in one village in the Beskidy Mountains in both indoor and outdoor environments. The particles were fractionated in Andersen cascade impactor. The sampling time was 6-7 days and 4-5 days for indoor and outdoor respectively. Aerosol particulates were collected on A-type glass fiber collection substrate used later for determination of heavy concentrations by atomic absorption spectrophotometry (AAS 3, Carl Zeiss Jena). The dust was mineralized by the means of the mixture of hydrofluoric and nitric acids. The results of mass size distribution as well as the measurements of TSP for indoor and outdoor aerosol show that the main source of particulate matter indoors, in this region, are heavy polluted outdoor air and cigarette smoking. It can be said that, except homes in Knurów and Sosnowiec with hard smokers, the indoor levels of particulate pollution were significant lower than the outdoors levels. Whenever in the indoor environment appear additional source of particulate emission situation can changed. When we compare mass size distribution for outdoor aerosol and indoor aerosol contaminated by tobacco smoke, we can observed considerable increase of indoor aerosol level in the 0.33-0.54 microns size range. Besides, indoor aerosol status may be changed by coal stove emission (displacement of maximum peak to direction of coarse particles). The observed differences in concentration of particulate matter may also indicate the important differences in chemical and

  2. Dust production from sub-solar to super-solar metallicity in Thermally Pulsing Asymptotic Giant Branch Stars

    CERN Document Server

    Ambra, Nanni; Paola, Marigo; Léo, Girardi; Atefeh, Javadi; Jacco, van Loon

    2014-01-01

    We discuss the dust chemistry and growth in the circumstellar envelopes (CSEs) of Thermally Pulsing Asymptotic Giant Branch (TP-AGB) star models computed with the COLIBRI code, at varying initial mass and metallicity (Z=0.001, 0.008, 0.02, 0.04, 0.06). A relevant result of our analysis deals with the silicate production in M-stars. We show that, in order to reproduce the observed trend between terminal velocities and mass-loss rates in Galactic M-giants, one has to significantly reduce the efficiency of chemisputtering by H2 molecules, usually considered as the most effective dust destruction mechanism. This indication is also in agreement with the most recent laboratory results, which show that silicates may condense already at T=1400 K, instead than at Tcond=1000 K, as obtained by models that include chemisputtering. From the analysis of the total dust ejecta, we find that the total dust-to-gas ejecta of intermediate-mass stars are much less dependent on metallicity than usually assumed. In a broader contex...

  3. Variation of Mid and Far-IR Luminosities among Early-Type Galaxies: Relation to Stellar Metallicity and Cold Dust

    CERN Document Server

    Mathews, William G; Brighenti, Fabrizio; Amblard, Alexandre

    2013-01-01

    The Hubble morphological sequence from early to late galaxies corresponds to an increasing rate of specific star formation. The Hubble sequence also follows a banana-shaped correlation between 24 and 70 micron luminosities, both normalized with the K-band luminosity. We show that this correlation is significantly tightened if galaxies with central AGN emission are removed, but the cosmic scatter of elliptical galaxies in both 24 and 70 micron luminosities remains significant along the correlation. We find that the 24 micron variation among ellipticals correlates with stellar metallicity, reflecting emission from hot dust in winds from asymptotic giant branch stars of varying metallicity. Infrared surface brightness variations in elliptical galaxies indicate that the K - 24 color profile is U-shaped for reasons that are unclear. In some elliptical galaxies cold interstellar dust emitting at 70 and 160 microns may arise from recent gas-rich mergers. However, we argue that most of the large range of 70 micron lu...

  4. Contributions To The Study Of Heavy Metals Concentration Variation In Sedimentable Dusts According To The Distance From The Pollution Source

    Directory of Open Access Journals (Sweden)

    Mariana DOBRA

    2006-01-01

    Full Text Available The environment in areas where geological and mining activities, such as the extraction of ores containing heavy metals, take place, is heavily polluted with dusts resulting from these activities, as well as with residual waters from the mines. Depending on the meteorological conditions, as well as on the conditions under which sedimentable dusts or dusts in suspension are emitted into the air, the distance from the main pollution source varies considerably. In order to estimate the pollution level and the danger presented by this phenomenon, some analyses are required with regard to determining the concentration of heavy pollutant metals in air, soil and plants samples, as well as in dusts from the air. For the precise determination of the major components, as well as the minor ones, and also the ones in traces, the analytical techniques used must have low detection limits and the lowest matrix effects possible [1,2]. The methods that respond to these requirements are from the category of inductively coupled plasma atomic emission spectrometry (ICP-AES. The research was done in an area where there are industrial units whose main field of activity is extraction of certain ores which contain Pb, Cu and Zn as major components, as well as Cr, Mn, Ni, Co, Ag, Au, Al, and Fe as minor components or in traces. It is obvious that the presence of these metals in the air, water and soil has a negative impact on human health, plants and animals. This paper is a study of these aspects in an area where pollution with heavy metals reaches alarming quotas.

  5. Concentrations and bioaccessibility of metals in vegetation and dust near a mining haul road, Cape Krusenstern National Monument, Alaska

    Science.gov (United States)

    Brumbaugh, W.G.; Morman, S.A.; May, T.W.

    2011-01-01

    Vegetation, sub-surface peat, and road dust were sampled near the Delong Mountain Transportation System (DMTS) haul road in northwest Alaska in 2005-2006 to document aluminum, barium, cadmium, lead, and zinc concentrations, and to evaluate bioaccessibility of these metals. The DMTS haul road is the transport corridor between Red Dog Mine (a large-scale, lead-zinc mine and mill) and the coastal shipping port, and it traverses National Park Service lands. Compared to reference locations, total metal concentrations in four types of vegetation (birch, cranberry, and willow leaves, and cotton grass blades/stalks) collected 25 m from the haul road were enriched on average by factors of 3.5 for zinc, 8.0 for barium, 20 for cadmium, and 150 for lead. Triple rinsing of vegetation with a water/methanol mixture reduced metals concentrations by at most 50%, and cadmium and zinc concentrations were least affected by rinsing. Cadmium and zinc bioaccessibility was greater in vegetation (50% to 100%) than in dust (15% to 20%); whereas the opposite pattern was observed for lead bioaccessibility (concentrate transfer activities have been effective; however, as of 2006, metal dispersion from past and/or present releases of fugitive dusts along the DMTS road still may have been contributing to elevated metals in surface vegetation. Vegetation was most enriched in lead, but because bioaccessibility of cadmium was greater, any potential risks to animals that forage near the haul road might be equally important for both of these metals. ?? 2011 Springer Science+Business Media B.V. (outside the USA).

  6. Human exposure to toxic metals via contaminated dust: Bio-accumulation trends and their potential risk estimation.

    Science.gov (United States)

    Mohmand, Jawad; Eqani, Syed Ali Musstjab Akber Shah; Fasola, Mauro; Alamdar, Ambreen; Mustafa, Irfan; Ali, Nadeem; Liu, Liangpo; Peng, Siyuan; Shen, Heqing

    2015-08-01

    We assessed the levels of potentially toxic trace metals, Zinc (Zn), Lead (Pb), Manganese (Mn), Copper (Cu), Nickel (Ni), Chromium (Cr), Cobalt (Co), and Cadmium (Cd), in dust, hair, nail and serum, sampled in rural, urban and industrial areas of Punjab, Pakistan. Trace metals occurrence in all samples, in descending order, was: Zn, Pb, Mn, Cu, Cr, Ni, Co, Cd. The samples from the urban areas showed significantly higher concentration of toxic trace metals (Zn, Ni, Cr, Co, Mn, and Cd) than those from industrial (which conversely had higher levels of Pb and Cu), and than samples from rural areas. Bioaccumulation patterns showed that dust exposure is one of the major routes into human body for Cd, Pb, Co, Mn and Cr, while the burden of Zn, Cu, and Ni can be more linked to dietary sources. The concentrations of trace metals in the samples from Punjab were comparable and/or higher than those reported worldwide. In many cases, the levels of Zn, Cr, Pb, Ni and Cd in hair and nail were beyond the ATSDR threshold guideline values that may cause some serious health effects. Hazard Index (HI) calculated for trace metal concentrations in the human population of Punjab points particularly to health risks from Cd (for children in urban and industrial areas) and from Pb (for all sub-groups). Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. Pollution characteristics and health risk assessment of heavy metals in street dusts from different functional areas in Beijing, China.

    Science.gov (United States)

    Wei, Xin; Gao, Bo; Wang, Peng; Zhou, Huaidong; Lu, Jin

    2015-02-01

    Street dusts from Heavy Density Traffic Area, Residential Area, Educational Area and Tourism Area in Beijing, China, were collected to study the distribution, accumulation and health risk assessment of heavy metals. Cr, Cu, Zn, Cd and Pb concentrations were in higher concentrations in these four locations than in the local soil background. In comparison with the concentrations of selected metals in other cities, the concentrations of heavy metals in Beijing were generally at moderate or low levels. Ni, Cu, Zn and Pb concentrations in the Tourism Area were the highest among four different areas in Beijing. A pollution assessment by Geoaccumulation Index showed that the pollution level for the heavy metals is in the following order: Cd>Pb>Zn>Cu>Cr>Ni. The Cd levels can be considered "heavily contaminated" status. The health risk assessment model that was employed to calculate human exposure indicated that both non-carcinogenic and carcinogenic risks of selected metals in street dusts were generally in the low range, except for the carcinogenic risk from Cr for children. Copyright © 2014 Elsevier Inc. All rights reserved.

  8. Dust-depletion sequences in damped Lyman-{\\alpha} absorbers: a unified picture from low-metallicity systems to the Galaxy

    CERN Document Server

    De Cia, Annalisa; Mattsson, Lars; Petitjean, Patrick; Srianand, Raghunathan; Gavignaud, Isabelle; Jenkins, Edward B

    2016-01-01

    We study metal depletion due to dust in the interstellar medium (ISM) to infer the properties of dust grains and characterize the metal and dust content of galaxies, down to low metallicity and intermediate redshift z. We provide metal column densities and abundances of a sample of 70 damped Lyman-{\\alpha} absorbers (DLAs) towards quasars, observed at high spectral resolution with the Very Large Telescope (VLT) Ultraviolet and Visual Echelle Spectrograph (UVES). This is the largest sample of phosphorus abundances measured in DLAs so far. We use literature measurements for Galactic clouds to cover the high-metallicity end. We discover tight (scatter <= 0.2 dex) correlations between [Zn/Fe] and the observed relative abundances, which are due to dust depletion. This implies that grain-growth in the ISM is an important process of dust production. These sequences are continuous in [Zn/Fe] from dust-free to dusty DLAs, and to Galactic clouds, suggesting that the availability of refractory metals in the ISM is cr...

  9. Allergens in household dust and serological indicators of atopy and sensitization in Detroit children with history--based eivdence of asthma

    Science.gov (United States)

    BACKGROUND: Home exposure to allergens is an important factor in the development of sensitization and subsequent exacerbations of allergic asthma. We investigated linkages among allergen exposure, immunological measurements, and asthma by examining (1) reservoir dust allergen lev...

  10. Polybrominated diphenyl ethers (PBDEs) and heavy metals in road dusts from a plastic waste recycling area in north China: implications for human health.

    Science.gov (United States)

    Tang, Zhenwu; Huang, Qifei; Yang, Yufei; Nie, Zhiqiang; Cheng, Jiali; Yang, Jun; Wang, Yuwen; Chai, Miao

    2016-01-01

    Road dusts were collected from an area where intense mechanical recycling of plastic wastes occurs in Wen'an, north China. These dusts were investigated for polybrominated diphenyl ethers (PBDEs) and heavy metals contamination to assess the health risk related to these components. Decabromodiphenyl ether (BDE-209) and Σ21PBDE concentrations in these dusts ranged from 2.67 to 10,424 ng g(-1) and from 3.23 to 10,640 ng g(-1), respectively. These PBDE concentrations were comparable to those observed in road dust from e-waste recycling areas but were 1-2 orders of magnitude higher than concentrations in outdoor or road dusts from other areas. This indicates that road dusts in the study area have high levels of PBDE pollution. BDE-209 was the predominant congener, accounting for 86.3% of the total PBDE content in dusts. Thus, commercial deca-BDE products were the dominant source. The average concentrations of As, Cd, Cr, Cu, Hg, Pb, Sb, and Zn in these same dust samples were 10.1, 0.495, 112, 54.7, 0.150, 71.8, 10.6, and 186 mg kg(-1), respectively. The geoaccumulation index suggests that road dusts in this area are moderately to heavily polluted with Cd, Hg, and Sb. This study shows that plastic waste processing is a major source of toxic pollutants in road dusts in this area. Although the health risk from exposure to dust PBDEs was low, levels of some heavy metals in this dust exceeded acceptable risk levels for children and are of great concern.

  11. The use of a sequential extraction procedure for heavy metal analysis of house dusts by atomic absorption spectrometry.

    Science.gov (United States)

    Altundag, Huseyin; Dundar, Mustafa Sahin; Doganci, Secil; Celik, Muhammed; Tuzen, Mustafa

    2013-01-01

    In general, dust is considered as house or street dust. Indoor dust, as a contamination source, has been studied for many years. In this work, the original Community Bureau of Reference of the European Commission (BCR) three-stage sequential extraction procedure was applied to the fractionation of Cr, Cu, Fe, Mn, Pb, and Zn in 20 house dust samples from five different areas of Sakarya, Turkey. Acetic acid, hydroxylammonium chloride, and hydrogen peroxide plus ammonium acetate were used for the first, second, and third steps of the BCR method, respectively. The extracts were analyzed for the studied heavy metals using flame atomic absorption spectrometry. Validation of the results was performed by using a standard reference material (BCR 701 Sediment) to certify the experimental results obtained and to evaluate the reliability of the method used. The elemental loadings typically increased in magnitude according to the area order: Izmit Caddesi>Ankara Caddesi >Erenler>Karaman>Korucuk. The results were in agreement with values reported in the literature.

  12. Carbon formation and metal dusting in hot-gas cleanup systems of coal gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    Tortorelli, P.F.; DeVan, H.J.; Judkins, R.R. [and others

    1995-06-01

    The product gas resulting from the partial oxidation of carboniferous materials in a gasifier consists predominantly of CO, CO{sub 2}, H{sub 2}, H{sub 2}O, CH{sub 4}, and, for air-blown units, N{sub 2} in various proportions at temperatures ranging from about 400 to 1000{degree}C. Depending on the source of the fuel, smaller concentrations of H{sub 2}S, COS, and NH{sub 3} can also be present. The gas phase is typically characterized by high carbon and sulfur, but low oxygen, activities and, consequently, severe degradation of the structural and functional materials used in the gasifier can occur. Therefore, there are numerous concerns about materials performance in coal gasification systems, particularly at the present time when demonstration-scale projects are in or nearing the construction and operation phases. This study focused on the subset of materials degradation phenomena resulting from carbon formation and carburization processes, which are related to potential operating problems in certain gasification components and subsystems. More specifically, it examined the current state of knowledge regarding carbon deposition and a carbon-related degradation phemonenon known as metal dusting as they affect the long-term operation of the gas clean-up equipment downstream of the gasifier and addressed possible means to mitigate the degradation processes. These effects would be primarily associated with the filtering and cooling of coal-derived fuel gases from the gasifier exit temperature to as low as 400{degree}C. However, some of the consideratins are sufficiently general to cover conditions relevant to other parts of gasification systems.

  13. Determination of heavy metals in dust from selected nursery and kindergarten classrooms within the Kumasi metropolis of Ghana

    Directory of Open Access Journals (Sweden)

    Marian Asantewah Nkansah

    2015-12-01

    Full Text Available The exposure potential of children in nursery and kindergarten schools to metals in dust in the Kumasi Metropolis was studied. Dust samples from 20 selected schools were analyzed for heavy metal levels using atomic absorption spectrophotometry. The results showed that concentrations were in the range of below detection −9.710 μg/g for cobalt, below detection to 33.291 μg/g for chromium, below detection to 41.909 μg/g for lead, below detection to 1.383 μg/g for mercury, while cadmium levels were below detection for all samples. The mean levels of metals therefore decreased in the order: Cr > Pb > Co > Hg and Cd. Geographical variation correlated with heavy metal load. Health risk assessment using hazard quotient (HQ and hazard index (HI calculations indicated that ingestion contributed more to exposure than dermal contact. However, the values obtained by HQ and HI do not pose any immediate health risk but the cumulative effect is a matter of concern.

  14. Monitoring of heavy metal levels in roadside dusts of Thessaloniki, Greece in relation to motor vehicle traffic density and flow.

    Science.gov (United States)

    Ewen, Caroline; Anagnostopoulou, Maria A; Ward, Neil I

    2009-10-01

    In recent years, the level of heavy metal pollution in urban areas has been of considerable concern. The principal source has been attributed to the motor vehicle and increasing inner city congestion, which has lead to a change and enlargement of transport stop-start zones. These areas of high traffic density are associated with an increased release of heavy metals into the adjacent residential or commercial areas. Seventy-five roadside dust samples were collected throughout the inner city and by-pass motorway areas of Thessaloniki, Northern Greece. Samples were taken from arterial, major and minor roads, as well as the ring road, to compare and contrast the levels of heavy metals, namely Cu, Zn, Cd, Mn and Pb. Flame Atomic Absorption Spectroscopy (FAAS) was developed to quantitatively determine concentrations of both total element and geochemical fractionation, within the two dust particulate fraction sizes congestion/stop-start traffic patterns did influence and have led to increased levels of heavy metal deposition along inner city roads compared to levels observed on the new relief ring road. Dust particulate fraction sizes were only found to show statistically significant differences in cadmium and manganese, at the probability P 0.05 or 95% confidence limit. Road type was seen to have little affect on cadmium and manganese, though lead, copper and zinc were all found to show higher levels on the inner city routes. This can be related back to the wear-and-tear of vehicle components as a result of the stop-start traffic patterns (brake pads etc). Both Pb and Zn have shown to be in chemical forms that are bio available to ecosystems.

  15. Inhaled dust and disease

    Energy Technology Data Exchange (ETDEWEB)

    Holt, P.F.

    1987-01-01

    This book discusses the following: the respiratory system; respirable dust; the fate of inhaled dust; translocation and some general effects of inhaled dust; silicosis; experimental research on silica-related disease; natural fibrous silicates; asbestos dust levels and dust sources; asbestos-related diseases - asbestosis, lung cancer, mesothelioma and other diseases, cancers at sites other than lung and pleura; experimental research relating to asbestos-related diseases; asbestos hazard - mineral types and hazardous occupations, neighbourhood and domestic hazard; silicates other than asbestos-man-made mineral fibres, mineral silicates and cement; metals; coal mine dust, industrial carbon and arsenic; natural and synthetic organic substances; dusts that provoke allergic alveolitis; tobacco smoke.

  16. Chemical speciation, human health risk assessment and pollution level of selected heavy metals in urban street dust of Shiraz, Iran

    Science.gov (United States)

    Keshavarzi, Behnam; Tazarvi, Zahra; Rajabzadeh, Mohammad Ali; Najmeddin, Ali

    2015-10-01

    The distribution, pollution level, sources and health risk of Hg, As, Cd, Cu, Cr, Ni, Mn, Fe, Pb, Sb and Zn in urban street dust were investigated. X-ray diffraction analysis of dust samples shows that the mineralogy of airborne dusts is dominated by calcite, dolomite and quartz. The total concentration of trace elements across the sampling sites ranged from 36.8 to 234.3 mg kg-1 for Pb, 0.004-4.504 mg kg-1 for Hg, 160.9-778.3 mg kg-1 for Zn, 245-652 mg kg-1 for Mn, 39.4-117.9 mg kg-1 for Ni, 31.6-105.9 mg kg-1 for Cr, 49.8-232.5 mg kg-1 for Cu, 5.3-8.6 mg kg-1 for As, 0.31-0.85 mg kg-1 for Cd, 0.76-9.45 mg kg-1 for Sb, and 16,300-24,900 mg kg-1 for Fe. The enrichment factor results reveal the following order: Cu > Hg > Sb > Zn > Pb > Ni > Cr > As > Mn > Cd > Fe. Among the measured elements, the highest mobility factor belongs to Pb (79.2%), Hg (74.6%), Zn (64.1%) and Mn (56.4%). According to the calculated Hazard Quotient (HQ) and Hazard Index (HI), special attention should be paid to Hg, Pb, Zn, and Mn in the street dusts of Shiraz. Multivariate statistics indicate that traffic, natural soil particles and industrial activities are likely to be the main sources of heavy metals in Shiraz street dusts.

  17. Ecological and human health hazards of heavy metals and polycyclic aromatic hydrocarbons (PAHs) in road dust of Isfahan metropolis, Iran.

    Science.gov (United States)

    Soltani, Naghmeh; Keshavarzi, Behnam; Moore, Farid; Tavakol, Tahereh; Lahijanzadeh, Ahmad Reza; Jaafarzadeh, Nemat; Kermani, Maryam

    2015-02-01

    This study investigates trace elements and PAHs content in road dust of Isfahan metropolis, central Iran. The mean concentrations of As, Cd, Cu, Ni, Pb, Sb and Zn are 22.15, 2.14, 182.26, 66.63, 393.33, 6.95 and 707.19 mg kg(-1), respectively. When compared with upper continental crust, the samples generally display elevated trace element concentrations, except for Co and Cr. The decreasing trend of calculated enrichment factors (EFs) is Cd>Pb>Sb>Zn>Cu>As>Ni>Cr>Co. Calculated potential ecological risk reveals that among the analyzed metals, Cd and Pb, have a higher potential ecological risk. Statistically, two identified main sources of trace elements include road traffic emissions and resuspension of soil particles. As, Cd, Cu, Pb, Sb and Zn in Isfahan road dust are strongly influenced by anthropogenic activity, mainly traffic emissions, while Co, Cr and Ni originate from resuspension of soil natural parent particles. The sum of 13 major PAHs (∑13PAHs) mass concentration ranges from 184.64 to 3221.72 μg kg(-1) with the mean being 1074.58 μg kg(-1). PAHs sources are identified using PCA analysis. It is demonstrated that the PAHs in Isfahan road dust are mainly derived from traffic emission, coal combustion and petroleum. Toxic equivalent concentrations (TEQs) of PAHs in the road dust ranges between 25.021 μg kg(-1) and 230.893 μg kg(-1). High correlation coefficients (r(2)=0.909 and 0.822, p<0.01) between Benzo[a]pyrene, Benzo[b+k]fluoranthene and toxicity equivalent concentrations of road dust indicate that Benzo[a]pyrene and Benzo[b+k]fluoranthenes are major TEQ contributors. The total incremental life time cancer risk (ILCR) of exposure to PAHs from Isfahan metropolis urban dust is 4.85 × 10(-4) for adult and 5.02 × 10(-4) for children. Estimated results of ILCR indicate that Isfahan residents are potentially exposed to high cancer risk via both dust ingestion and dermal contact.

  18. Evaluation of the vehicle contributions of metals to indoor environments.

    Science.gov (United States)

    Kuo, Chung-Yih; Wang, Jing-Ya; Liu, Wan-Tzu; Lin, Pin-Yu; Tsai, Ching-Tsan; Cheng, Man-Ting

    2012-09-01

    A large number of diesel vehicles carrying gravel and sand shuttle back and forth every day on the major thoroughfares (Tai-16 and Tai-21) from Shinyi to Jiji in Nantou, Taiwan. A total of 10 stations along the major thoroughfares were selected as the exposure sites, whereas a small village located ∼9 km from a main traffic route was selected as the control site. Outdoor and indoor aerosol samples were collected using high-volume samplers and Harvard samplers, respectively. The metal concentrations of outdoor and indoor PM(10) at the exposure sites were, respectively, higher than those at the control site. The plots between metal contents in the aerosols and road dust showed that diesel vehicles contributed significant amounts of metals to the outdoor and indoor aerosols at the exposure sites. Household dust samples along the roadside within 30 m of the main road in the small towns were collected using the wipe method. Based on the results of principal component analysis (PCA), three major components for household dust were identified: resuspended from road dust, brake wear and diesel emissions. Enrichment factors were applied to assess the contribution of pollution sources to household dust. These factors were calculated with respect to unpolluted river dust samples (EF(river)) and road dust (EF(road)). The differences between EF(river) and EF(road) could be mainly attributed to the effects of resuspension by passing vehicles. Approximately 72%, 68%, 68%, 73% and 86% of the vehicle-related metals Pb, Zn, Cu, Ni and Mo content, respectively, in household dust were the result of the resuspension of road dust by passing vehicles. The data of daily intakes of five metals (i.e., Fe, Pb, Cu, Ni and Mo) from inhalation and ingestion pathways showed that the doses from the ingestion pathway were much higher than those from the inhalation pathway.

  19. Heavy metals in road dust from Xiandao District, Changsha City, China: characteristics, health risk assessment, and integrated source identification.

    Science.gov (United States)

    Li, Fei; Zhang, Jingdong; Huang, Jinhui; Huang, Dawei; Yang, Jun; Song, Yongwei; Zeng, Guangming

    2016-07-01

    The physicochemical properties and the contents of metals (Cu, Zn, Pb, Cd, Cr, and Fe) in 51 road dust samples from Xiandao District (XDD) were investigated. Enrichment factor (EF), multivariate statistics, geostatistics, and health risk assessment model were adopted to study the spatial pollution pattern and to identify the priority pollutants and regions of concern and sources of studied metals. The mean EFs revealed the following order: Cd > Zn ≈ Pb ≈ Cu > Cr. For non-carcinogenic effects, the exposure pathway which resulted in the highest levels of exposure risk for children and adults was ingestion, followed by dermal contact and inhalation. Hazard index (HI) values for the studied metals at each site were within the safe level of 1 except maximum HI Cr (1.08) for children. The carcinogenic risk (CR) for Cd and Cr at each site was within the acceptable risk level (1E-06) except CR Cr (1.08E-06) for children in the road intersection between the Changchang highway and the Yuelin highway. Cr was identified as the priority pollutant followed by Pb and Cd with consideration of the local population distribution. Spatially, northwest and northeast of XDD were regarded as the priority regions of concern. Results based on the proposed integrated source identification method indicated that Pb was probably sourced from traffic-related sources, Cd was associated with the dust organic material mainly originated from industrial sources, and Cr was mainly derived from both sources.

  20. Metals recovery of spent household batteries using a hydrometallurgical process; Recuperacao de metais de sucatas de pilhas e baterias pos-consumo utilizando processamento hidrometalurgico

    Energy Technology Data Exchange (ETDEWEB)

    Souza, K.P.; Tenorio, J.A.S., E-mail: kprovazi@gmail.co [Universidade de Sao Paulo (USP), SP (Brazil). Dept. de Engenharia Metalurgica e de Materiais

    2010-07-01

    The objective of the work is to study a method for metals recovery from a sample composed by a mixture of the main types of spent household batteries. Segregation of the main metals is investigated using a treatment route consisting of the following steps: manual identified and dismantling, grinding, electric furnace reduction, acid leaching and selective precipitation with sodium hydroxide with and without hydrogen peroxide. Before and after precipitations the solutions had been analyzed by Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP/OES) and the precipitated analyzed by Scanning Electron Microscopy (SEM) with Spectrometry of Energy Dispersion Spectroscopy (EDS). The results had indicated that the great majority of metals had been precipitated in pHs studied, also had co-precipitation or simultaneous precipitation of metals in some pHs. (author)

  1. Metal enrichment and lead isotope analysis for source apportionment in the urban dust and rural surface soil.

    Science.gov (United States)

    Yu, Yang; Li, Yingxia; Li, Ben; Shen, Zhenyao; Stenstrom, Michael K

    2016-09-01

    To understand the metal accumulation in the environment and identify its sources, 29 different metal contents and lead (Pb) isotope ratios were determined for 40 urban dust samples, 36 surface soil samples, and one river sediment sample collected in the municipality of Beijing, China. Results showed that cadmium, copper (Cu), mercury, Pb, antimony (Sb), and zinc demonstrated to be the typical urban contaminants and mostly influenced by the adjacent human activities with higher content to background ratios and SD values. Among the 29 metal elements investigated, Cu and Sb were found to be the most distinct elements that were highly affected by the developing level and congestion status of the cities with much higher contents in dust in more developed and congested cities. There was a relatively wider range of Pb isotope ratios of country surface soil than those of urban dust. The results of source identification based on Pb isotope ratios showed that coal combustion was the first largest Pb source and vehicle exhaust was the second largest source. The sum of them accounted for 74.6% mass proportion of overall Pb pollution on average. The surface soil sample collected at an iron mine had the highest (204)Pb/(206)Pb, (207)Pb/(206)Pb, and (208)Pb/(206)Pb ratios indicating ore had much higher ratios than other sources. The fine particle subsamples had higher (204)Pb/(206)Pb, (207)Pb/(206)Pb, and (208)Pb/(206)Pb ratios than the coarse particle subsamples indicating more anthropogenic sources of coal combustion and vehicle exhaust for fine particles and more background influence for coarse particles. These results help with pinpointing the major Pb sources and applying suitable measures for the target sources.

  2. Household Finance

    OpenAIRE

    Campbell, John

    2006-01-01

    The welfare benefits of financial markets depend in large part on how effectively households use these markets. The study of household finance is challenging because household behavior is difficult to measure accurately, and because households face constraints that are not captured by textbook models, including fixed costs, uninsurable income risk, borrowing constraints, and contracts that are non-neutral with respect to inflation. Evidence on participation, diversification, and the exercise ...

  3. Evolution of Thermally Pulsing Asymptotic Giant Branch Stars II. Dust production at varying metallicity

    CERN Document Server

    Nanni, Ambra; Marigo, Paola; Girardi, Léo

    2013-01-01

    We present the dust ejecta of the new stellar models for the Thermally Pulsing Asymptotic Giant Branch (TP-AGB) phase computed with the COLIBRI code. We use a formalism of dust growth coupled with a stationary wind for both M and C-stars. In the original version of this formalism, the most efficient destruction process of silicate dust in M-giants is chemisputtering by H2 molecules. For these stars we find that dust grains can only form at relatively large radial distances (r~5 R*), where they cannot be efficiently accelerated, in agreement with other investigations. In the light of recent laboratory results, we also consider the alternative case that the condensation temperature of silicates is determined only by the competition between growth and free evaporation processes (i.e. no chemisputtering). With this latter approach we obtain dust condensation temperatures that are significantly higher (up to Tcond~1400 K) than those found when chemisputtering is included (Tcond~900 K), and in better agreement with...

  4. The wind speeds, dust content, and mass-loss rates of evolved AGB and RSG stars at varying metallicity

    Science.gov (United States)

    Goldman, Steven R.; van Loon, Jacco Th.; Zijlstra, Albert A.; Green, James A.; Wood, Peter R.; Nanni, Ambra; Imai, Hiroshi; Whitelock, Patricia A.; Matsuura, Mikako; Groenewegen, Martin A. T.; Gómez, José F.

    2017-02-01

    We present the results of our survey of 1612-MHz circumstellar OH maser emission from asymptotic giant branch (AGB) stars and red supergiants (RSGs) in the Large Magellanic Cloud (LMC). We have discovered four new circumstellar maser sources in the LMC, and increased the number of reliable wind speeds from infrared (IR) stars in the LMC from 5 to 13. Using our new wind speeds, as well as those from Galactic sources, we have derived an updated relation for dust-driven winds: vexp ∝ ZL0.4. We compare the subsolar metallicity LMC OH/IR stars with carefully selected samples of more metal-rich OH/IR stars, also at known distances, in the Galactic Centre and Galactic bulge. We derive pulsation periods for eight of the bulge stars for the first time by using near-IR photometry from the Vista Variables in the Via Lactea survey. We have modelled our LMC OH/IR stars and developed an empirical method of deriving gas-to-dust ratios and mass-loss rates by scaling the models to the results from maser profiles. We have done this also for samples in the Galactic Centre and bulge and derived a new mass-loss prescription which includes luminosity, pulsation period, and gas-to-dust ratio dot{M} = 1.06^{+3.5}_{-0.8} × }10^{-5 (L/10^4 L_{⊙})^{0.9± 0.1}(P/500 {d})^{0.75± 0.3} (r_gd/200)^{-0.03± 0.07} M⊙ yr-1. The tightest correlation is found between mass-loss rate and luminosity. We find that the gas-to-dust ratio has little effect on the mass-loss of oxygen-rich AGB stars and RSGs within the Galaxy and the LMC. This suggests that the mass-loss of oxygen-rich AGB stars and RSGs is (nearly) independent of metallicity between a half and twice solar.

  5. The wind speeds, dust content, and mass-loss rates of evolved AGB and RSG stars at varying metallicity

    CERN Document Server

    Goldman, Steven R; Zijlstra, Albert A; Green, James A; Wood, Peter R; Nanni, Ambra; Imai, Hiroshi; Whitelock, Patricia A; Matsuura, Mikako; Groenewegen, Martin A T; Gómez, José F

    2016-01-01

    We present the results of our survey of 1612 MHz circumstellar OH maser emission from asymptotic giant branch (AGB) stars and red supergiants (RSGs) in the Large Magellanic Cloud. We have discovered four new circumstellar maser sources in the LMC, and increased the number of reliable wind speeds from IR stars in the LMC from 5 to 13. Using our new wind speeds, as well as those from Galactic sources, we have derived an updated relation for dust driven winds: $v_{exp} \\propto Z L^{0.4}$. We compare the sub-solar metallicity LMC OH/IR stars with carefully selected samples of more metal-rich OH/IR stars, also at known distances, in the Galactic Centre and Galactic Bulge. For 8 of the Bulge stars we derive pulsation periods for the first time, using near-IR photometry from the VVV survey. We have modeled our LMC OH/IR stars and developed an empirical method of deriving gas-to-dust ratios and mass loss rates by scaling the models to the results from maser profiles. We have done this also for samples in the Galactic...

  6. First-principles investigations of Ni3Al(111) and NiAl(110) surfaces at metal dusting conditions

    Energy Technology Data Exchange (ETDEWEB)

    Saadi, Souheil

    2011-03-01

    We investigate the structure and surface composition of the {gamma}{prime}-Ni{sub 3}Al(111) and {beta}-NiAl(110) alloy surfaces at conditions relevant for metal dusting corrosion related to catalytic steam reforming of natural gas. In regular service as protective coatings, nickel-aluminum alloys are protected by an oxide scale, but in case of oxide scale spallation, the alloy surface may be directly exposed to the reactive gas environment and vulnerable to metal dusting. By means of density functional theory and thermochemical calculations for both the Ni{sub 3}Al and NiAl surfaces, the conditions under which CO and OH adsorption is to be expected and under which it is inhibited, are mapped out. Because CO and OH are regarded as precursors for nucleating graphite or oxide on the surfaces, phase diagrams for the surfaces provide a simple description of their stability. Specifically, this study shows how the CO and OH coverages depend on the steam to carbon ratio (S/C) in the gas and thereby provide a ranking of the carbon limits on the different surface phases.

  7. A solid-phase mechanism of shock-wave formation of dust particles of heavy metals

    Science.gov (United States)

    Lin, E. E.; Mikhailov, A. L.; Khvorostin, V. N.

    2016-08-01

    The possibility of formation of dust particles in solid as a result of shock-wave destruction of the initial crystalline material structure and subsequent coalescence of atomic clusters (nanoparticles), which leads to the aggregation of mesocrystalline particles (grains) in the shocked layer, is discussed.

  8. PCB-containing wood floor finish is a likely source of elevated PCBs in residents' blood, household air and dust: a case study of exposure.

    Science.gov (United States)

    Rudel, Ruthann A; Seryak, Liesel M; Brody, Julia G

    2008-01-17

    Polychlorinated biphenyls (PCBs) are persistent pollutants identified worldwide as human blood and breast milk contaminants. Because they bioaccumulate, consumption of meat, fish, and dairy products predicts human blood concentrations. PCBs were also used widely in building materials, including caulks and paints, but few studies have evaluated the contribution of these exposures to body burden. In an earlier study, we detected PCBs in indoor air in 31% of 120 homes on Cape Cod, MA. Two of the homes had much higher concentrations than the rest, so we retested to verify the initial finding, evaluate blood PCB concentrations of residents, and identify the PCB source. Air and dust concentrations remained elevated over 5 years between initial and follow-up sampling. Blood serum concentrations of PCBs in residents of the homes were generally elevated above the 95th percentile of a representative sample of the US population. Serum concentrations in residents and air and dust concentrations were especially high in a home where a resident reported use of PCB-containing floor finish in the past, and where the floor of one room was sanded and refinished just prior to sample collection. This case-study suggests that PCB residues in homes may be more significant contributors to overall exposure than diet for some people, and that use of a commercially-available PCB-containing wood floor finish in residences during the 1950s and 1960s is an overlooked but potentially important source of current PCB exposure in the general population.

  9. Household hazardous waste

    DEFF Research Database (Denmark)

    Fjelsted, Lotte; Christensen, Thomas Højlund

    2007-01-01

    'Paint waste', a part of the 'household hazardous waste', amounting to approximately 5 tonnes was collected from recycling stations in two Danish cities. Sorting and analyses of the waste showed paint waste comprised approximately 65% of the mass, paint-like waste (cleaners, fillers, etc.......) comprised 15-25% and foreign items comprised 10-20%. Water-based paint was the dominant part of the paint waste. The chemical composition of the paint waste and the paint-like waste was characterized by an analysis of 27 substances in seven waste fractions. The content of critical substances was tow...... and the paint waste was less contaminated with heavy metals than was the ordinary household waste. This may suggest that households no longer need to source-segregate their paint if the household waste is incinerated, since the presence of a small quantity of solvent-based paint will not be harmful when...

  10. Potential cytotoxicity of water-soluble fraction of dust and particulate matters and relation to metal(loid)s based on three human cell lines.

    Science.gov (United States)

    Huang, Minjuan; Kang, Yuan; Wang, Wei; Chan, Chuen Yu; Wang, Xuemei; Wong, Ming Hung

    2015-09-01

    Hepatocellular liver carcinoma (HepG2), human skin derived keratinocyte (KERTr,) and lung epithelial carcinoma (A549) were employed in MTT assay to evaluate the cytotoxicity of water-soluble fraction of road dust, air-conditioning (AC) filter dust and PM2.5 via ingestion, dermal contact and inhalation. Their effects on cell growth were dependent on exposure time and concentration. The LC20s of PM2.5 for A549 cell were approximately one order of magnitude lower than those of road dust and AC filter dust for KERTr cell and HepG2 cell. The LC20s of aqueous extracts were negatively correlated to the water-soluble metal(loid)s contained in dust coarse particles (KERTr: p=0.004; HepG2: p0.05). Other water-soluble components in dust and PM might cause the cell hazards synergistically or additively with metal(loid)s. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. The heavy metal partition in size-fractions of the fine particles in agricultural soils contaminated by waste water and smelter dust.

    Science.gov (United States)

    Zhang, Haibo; Luo, Yongming; Makino, Tomoyuki; Wu, Longhua; Nanzyo, Masami

    2013-03-15

    The partitioning of pollutant in the size-fractions of fine particles is particularly important to its migration and bioavailability in soil environment. However, the impact of pollution sources on the partitioning was seldom addressed in the previous studies. In this study, the method of continuous flow ultra-centrifugation was developed to separate three size fractions (dust respectively. The mineralogy and physicochemical properties of each size-fraction were characterized by X-ray diffraction, transmission electron microscope etc. Total content of the polluted metals and their chemical speciation were measured. A higher enrichment factor of the metals in the fractions of dust. The organic substance in the wastewater and calcite from lime application were assumed to play an important role in the metal accumulation in the fine particles of the wastewater polluted soil. While the metal accumulation in the fine particles of the smelter dust polluted soil is mainly associated with Mn oxides. Cadmium speciation in both soils is dominated by dilute acid soluble form and lead speciation in the smelter dust polluted soil is dominated by reducible form in all particles. This implied that the polluted soils might be a high risk to human health and ecosystem due to the high bioaccessibility of the metals as well as the mobility of the fine particles in soil.

  12. The heavy metal partition in size-fractions of the fine particles in agricultural soils contaminated by waste water and smelter dust

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Haibo, E-mail: hbzhang@yic.ac.cn [Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003 (China); Luo, Yongming, E-mail: ymluo@yic.ac.cn [Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003 (China); Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China); Makino, Tomoyuki [National Institute for Agro-Environmental Sciences, Tsukuba 3058604 (Japan); Wu, Longhua [Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China); Nanzyo, Masami [Tohoku University, Sendai 9808576 (Japan)

    2013-03-15

    Highlights: ► A continuous flow ultra-centrifugation method has been developed to obtain fine particles from polluted agricultural soil. ► Pollution source affected the heavy metal fractionation in size-fractions by changing soil particle properties. ► The iron oxides affected the distribution of lead species more than other metals in the smelter dust polluted particles. -- Abstract: The partitioning of pollutant in the size-fractions of fine particles is particularly important to its migration and bioavailability in soil environment. However, the impact of pollution sources on the partitioning was seldom addressed in the previous studies. In this study, the method of continuous flow ultra-centrifugation was developed to separate three size fractions (<1 μm, <0.6 μm and <0.2 μm) of the submicron particles from the soil polluted by wastewater and smelter dust respectively. The mineralogy and physicochemical properties of each size-fraction were characterized by X-ray diffraction, transmission electron microscope etc. Total content of the polluted metals and their chemical speciation were measured. A higher enrichment factor of the metals in the fractions of <1 μm or less were observed in the soil contaminated by wastewater than by smelter dust. The organic substance in the wastewater and calcite from lime application were assumed to play an important role in the metal accumulation in the fine particles of the wastewater polluted soil. While the metal accumulation in the fine particles of the smelter dust polluted soil is mainly associated with Mn oxides. Cadmium speciation in both soils is dominated by dilute acid soluble form and lead speciation in the smelter dust polluted soil is dominated by reducible form in all particles. This implied that the polluted soils might be a high risk to human health and ecosystem due to the high bioaccessblity of the metals as well as the mobility of the fine particles in soil.

  13. Heavy metals in food, house dust, and water from an e-waste recycling area in South China and the potential risk to human health.

    Science.gov (United States)

    Zheng, Jing; Chen, Ke-hui; Yan, Xiao; Chen, She-Jun; Hu, Guo-Cheng; Peng, Xiao-Wu; Yuan, Jian-gang; Mai, Bi-Xian; Yang, Zhong-Yi

    2013-10-01

    Concentrations of heavy metals (Cd, Pb, Cu, Zn, and Ni) were measured in the foodstuffs, house dust, underground/drinking water, and soil from an electronic waste (e-waste) area in South China. Elevated concentrations of these potentially toxic metals were observed in the samples but not in drinking water. The health risks for metal exposure via food consumption, dust ingestion, and drinking water were evaluated for local residents. For the average residents in the e-waste area, the non-carcinogenic risks arise predominantly from rice (hazard index=3.3), vegetables (2.2), and house dust (1.9) for adults, while the risks for young children are dominated by house dust (15). Drinking water may provide a negligible contribution to risk. However, local residents who use groundwater as a water supply source are at high non-carcinogenic risk. The potential cancer risks from oral intake of Pb are 8×10(-5) and 3×10(-4) for average adults and children, and thus groundwater would have a great potential to induce cancer (5×10(-4) and 1×10(-3)) in a highly exposed population. The results also reveal that the risk from oral exposure is much higher than the risk from inhalation and dermal contact with house dust. Copyright © 2013 Elsevier Inc. All rights reserved.

  14. Metals and metalloids in atmospheric dust: Use of lead isotopic analysis for source apportionment

    Science.gov (United States)

    Felix Villar, Omar I.

    Mining activities generate aerosol in a wide range of sizes. Smelting activities produce mainly fine particles ( 1 microm). The adverse effects of aerosols on human health depend mainly on two key characteristics: size and chemical composition. One of the main objectives of this research is to analyze the size distribution of contaminants in aerosol produced by mining operations. For this purpose, a Micro-Orifice Uniform Deposit Impactor (MOUDI) was utilized. Results from the MOUDI samples show higher concentrations of the toxic elements like lead and arsenic in the fine fraction (Mitigation strategies could be developed if the source of contamination is well defined. Environmental conditions as wind speed, wind direction, relative humidity and precipitation have an important role in the concentration of atmospheric dust. Dry environments with low relative humidity are ideal for the transport of aerosols. Results obtained from this research show the relationship between dust concentrations and meteorological parameters. Dust concentrations are highly correlated with relative humidity and wind speed. With all the data collected on site and the analysis of the meteorological parameters, models can be develop to predict the transport of particles as well as the concentration of contaminants at a specific point. These models were developed and are part of the results shown in this dissertation.

  15. Analysis of Potentially Toxic Metals in Airborne Cement Dust Around Sagamu, Southwestern Nigeria

    Science.gov (United States)

    Gbadebo, A. M.; Bankole, O. D.

    This study analyzed the concentration levels of potentially toxic and harmful elements contained in the airborne cement dust generated in the vicinity and farther away 500 m in the conventional four cardinal directions from the West African Portland Cement Company (WAPCO) factory mill, Sagamu. The results indicated that the concentration range of these toxic elements fall between 40.0 and 280,000 μg g-1 in the cement dust samples. Also, the concentration range of these toxic elements in 1 L of air samples varies between 0.01 μg g-1 and 29.92 μg L-1. The results generally show elevated concentrations of all the elements when compared with USA threshold limit of particulate mental concentration (e.g., Pb (1.5 g m-3); Cd (0.004-0.026 g m-3) in the air. These elements in the airborne cement dusts may pose a great threat to the health of plants, animals and residents in and around the factory and also to workers and visitors to the factory.

  16. PCB-containing wood floor finish is a likely source of elevated PCBs in residents' blood, household air and dust: a case study of exposure

    Science.gov (United States)

    Rudel, Ruthann A; Seryak, Liesel M; Brody, Julia G

    2008-01-01

    Background Polychlorinated biphenyls (PCBs) are persistent pollutants identified worldwide as human blood and breast milk contaminants. Because they bioaccumulate, consumption of meat, fish, and dairy products predicts human blood concentrations. PCBs were also used widely in building materials, including caulks and paints, but few studies have evaluated the contribution of these exposures to body burden. Methods In an earlier study, we detected PCBs in indoor air in 31% of 120 homes on Cape Cod, MA. Two of the homes had much higher concentrations than the rest, so we retested to verify the initial finding, evaluate blood PCB concentrations of residents, and identify the PCB source. Results Air and dust concentrations remained elevated over 5 years between initial and follow-up sampling. Blood serum concentrations of PCBs in residents of the homes were generally elevated above the 95th percentile of a representative sample of the US population. Serum concentrations in residents and air and dust concentrations were especially high in a home where a resident reported use of PCB-containing floor finish in the past, and where the floor of one room was sanded and refinished just prior to sample collection. Conclusion This case-study suggests that PCB residues in homes may be more significant contributors to overall exposure than diet for some people, and that use of a commercially-available PCB-containing wood floor finish in residences during the 1950s and 1960s is an overlooked but potentially important source of current PCB exposure in the general population. PMID:18201376

  17. PCB-containing wood floor finish is a likely source of elevated PCBs in residents' blood, household air and dust: a case study of exposure

    Directory of Open Access Journals (Sweden)

    Seryak Liesel M

    2008-01-01

    Full Text Available Abstract Background Polychlorinated biphenyls (PCBs are persistent pollutants identified worldwide as human blood and breast milk contaminants. Because they bioaccumulate, consumption of meat, fish, and dairy products predicts human blood concentrations. PCBs were also used widely in building materials, including caulks and paints, but few studies have evaluated the contribution of these exposures to body burden. Methods In an earlier study, we detected PCBs in indoor air in 31% of 120 homes on Cape Cod, MA. Two of the homes had much higher concentrations than the rest, so we retested to verify the initial finding, evaluate blood PCB concentrations of residents, and identify the PCB source. Results Air and dust concentrations remained elevated over 5 years between initial and follow-up sampling. Blood serum concentrations of PCBs in residents of the homes were generally elevated above the 95th percentile of a representative sample of the US population. Serum concentrations in residents and air and dust concentrations were especially high in a home where a resident reported use of PCB-containing floor finish in the past, and where the floor of one room was sanded and refinished just prior to sample collection. Conclusion This case-study suggests that PCB residues in homes may be more significant contributors to overall exposure than diet for some people, and that use of a commercially-available PCB-containing wood floor finish in residences during the 1950s and 1960s is an overlooked but potentially important source of current PCB exposure in the general population.

  18. Source identification and health risk assessment of metals in indoor dust in the vicinity of phosphorus mining, Guizhou Province, China.

    Science.gov (United States)

    Yang, Qin; Chen, Huaguo; Li, Baizhan

    2015-01-01

    An investigation was performed to identify the sources of arsenic (As) and heavy metals in house dust and to assess the associated human health risks in the vicinity of phosphorus (P) mining in Guizhou, China. The concentrations and spatial distributions of mercury (Hg), As, cadmium (Cd), lead (Pb), iron (Fe), copper (Cu), manganese (Mn), and P in 23 house dust samples from the study area were determined. Greater concentrations of As and Pb were found compared with values in other investigations in various countries. Pollution sources were identified using multivariate statistical analysis. As, Pb, Mn, and Hg pollution was mainly attributed to mining activities, and Mn and Cd levels were largely associated with automobile emissions. The dominant wind direction and the distance of the residence from the mining region were found to play an important role in element distributions. A health risk assessment showed that As and Pb should be paid more attention, although the noncancer risks of the studied elements were within the safe range and the cancer risks of As and Cd are within the acceptable range under present conditions.

  19. A Trio of Metal-Rich Dust and Gas Disks Found Orbiting Candidate White Dwarfs with K-Band Excess

    CERN Document Server

    Farihi, J; Steele, P R; Girven, J; Burleigh, M R; Breedt, E; Koester, D

    2011-01-01

    This paper reports follow-up photometric and spectroscopic observations, including warm Spitzer IRAC photometry of seven white dwarfs from the SDSS with apparent excess flux in UKIDSS K-band observations. Six of the science targets were selected from 16,785 DA star candidates identified either spectroscopically or photometrically within SDSS DR7, spatially cross-correlated with HK detections in UKIDSS DR8. Thus the selection criteria are completely independent of stellar mass, effective temperature above 8000 K, and the presence (or absence) of atmospheric metals. The infrared fluxes of one target are compatible with a spatially-unresolved late M or early L-type companion, while three stars exhibit excess emissions consistent with warm circumstellar dust. These latter targets have spectral energy distributions similar to known dusty white dwarfs with high fractional infrared luminosities (thus the K-band excesses). Optical spectroscopy reveals the stars with disk-like excesses are polluted with heavy elements...

  20. Modeling of amphoteric heavy metals solubility in stabilized/solidified steel foundry dust

    OpenAIRE

    Fernández Olmo, Ignacio; Lasa Díaz, María Cristina; Lavín Castañeda, María Ángeles; Irabien Gulías, José Ángel

    2009-01-01

    The influence of pH on the leaching of metals from waste materials can be described by geochemical and empirical models. These equations may be integrated into dynamic leaching models in order to describe the longterm behavior of waste-derived forms or they can be used to predict the concentration of metals in equilibrium leaching tests at a given pH. The aim of this work is to describe the equilibrium concentration of the main metals (Zn, Pb, and Cr) contained in untreated and stabilized/sol...

  1. Lead and other elements in house dust of Japanese residences--source of lead and health risks due to metal exposure.

    Science.gov (United States)

    Yoshinaga, Jun; Yamasaki, Kumiko; Yonemura, Ayumi; Ishibashi, Yuri; Kaido, Takaya; Mizuno, Kodai; Takagi, Mai; Tanaka, Atsushi

    2014-06-01

    The levels of 25 elements in house dust collected from 100 general Japanese residences were measured. Factor analysis was applied on the multi-element data to explore source of Pb (median concentration 49.1 mg/kg) in house dust. Six factors were extracted and Pb was found to have great loading on the fifth factor with Sb and Sn, suggesting solder (Sn), and plastic and metals (Sb) may be the sources of Pb in the house dust of Japanese residences. No significant loading was found on soil-related factors indicating non-significant contribution of Pb in track-in soil. Seven heavy metals (Cd, Cu, Mo, Pb, Sb, Sn, and Zn) were found in house dust at >10 times more condensed than crustal abundance. Health risk of these elements to children via the ingestion of house dust was estimated based on the comparison with tolerable daily intake and found to be non-significant for most of the elements.

  2. Bioaccessibility and size distribution of metals in road dust and roadside soils along a peri-urban transect.

    Science.gov (United States)

    Padoan, Elio; Romè, Chiara; Ajmone-Marsan, Franco

    2017-12-01

    Road dust (RD), together with surface soils, is recognized as one of the main sinks of pollutants in urban environments. Over the last years, many studies have focused on total and bioaccessible concentrations while few have assessed the bioaccessibility of size-fractionated elements in RD. Therefore, the distribution and bioaccessibility of Fe, Mn, Cd, Cr, Cu, Ni, Pb, Sb and Zn in size fractions of RD and roadside soils (Bioaccessibility Extraction Test. Concentrations of metals in soils are higher than legislative limits for Cu, Cr, Ni, Pb and Zn. Fine fractions appear enriched in Fe, Mn, Cu, Pb, Sb and Zn, and 2.5-10μm particles are the most enriched. In RD, Cu, Pb, Sb and Zn derive primarily from non-exhaust sources, while Zn is found in greater concentrations in the bioaccessibility in the two finer fractions, while anthropic metals (Cu, Pb, Sb and Zn) do not. In RD, only Zn has significantly higher bioaccessibility at traffic sites compared to background, and the finest particles are always the most bioaccessible; >90% of Pb, Zn and Cu is bioaccessible in the bioaccessibility of size-fractionated particles appear to be a necessity for correct estimation of risk in urban areas. Copyright © 2017 Elsevier B.V. All rights reserved.

  3. [Magnetic Response of Dust-loaded Leaves in Parks of Shanghai to Atmospheric Heavy Metal Pollution].

    Science.gov (United States)

    Liu, Fei; Chu, Hui-min; Zheng, Xiang-min

    2015-12-01

    To reveal the magnetic response to the atmospheric heavy metal pollution in leaves along urban parks, Camphor leaf samples, widely distributed at urban parks, were collected along the year leading wind direction of Shanghai, by setting two vertical and horizontal sections, using rock magnetic properties and heavy metal contents analysis. The results showed that the magnetic minerals of samples were predominated by ferromagnetic minerals, and both the concentration and grain size of magnetite particles gradually decreased with the winter monsoon direction from the main industrial district. A rigorous cleaning of leaves using ultrasonic agitator washer could remove about 63%-90% of low-field susceptibility values of the leaves, and this strongly indicated that the intensity of magnetic signal was mainly controlled by the PMs accumulated on the leaves surfaces. Moreover, there was a significant linear relationship between heavy metals contents (Fe, Mn, Zn, Cu, Cr, V and Pb) and magnetic parameters (0.442 ≤ R ≤ 0.799, P magnetic parameters of urban park leaves could be used as a proxy for atmospheric heavy metal pollution. The results of multivariate statistical analysis showed that the content of magnetic minerals and heavy metal indust-loaded tree leaves was affected by associated pollution of industry and traffic.

  4. Heavy Metal Pollution in Settled Dust Associated with Different Urban Functional Areas in a Heavily Air-Polluted City in North China.

    Science.gov (United States)

    Wan, Dejun; Han, Zhangxiong; Yang, Jinsong; Yang, Guanglin; Liu, Xingqi

    2016-11-10

    Understanding variations of heavy metals in atmospheric particles between different functional areas is significant for pollution control and urban planning in cities. To reveal pollution and spatial distribution of heavy metals in atmospheric particles from different urban functional areas in Shijiazhuang in North China, 43 settled dust samples were collected over the main urban area and heavy metal concentrations were determined in their pollution indexes (IPIs) of the ten heavy metals are 2.7-13.6 (5.7 ± 2.2), suggesting high or very high pollution levels of most dust. Relatively lower IPIs occur mainly in the administration-education area, the commercial area, and other unclassified sites; while peaks occur mainly in the North Railway Station, the northeastern industrial area, and some sites near heavily trafficked areas, implying the significant influence of intensive industrial (including coal combustion) and traffic activities on atmospheric heavy metal accumulation. These results suggest a clear need of mitigating atmospheric heavy metal pollution via controlling emissions of toxic metals (especially Cd and Pb) from industrial and traffic sources in the city.

  5. Evaluating the mobile heavy metal pool in soak-away sediment, road dust and soil through sequential extraction and isotopic exchange.

    Science.gov (United States)

    Kumar, Manish; Furumai, Hiroaki; Kurisu, Futoshi; Kasuga, Ikuro

    2010-01-01

    Selective sequential dissolution (SSD) and isotopic dilution are two most commonly applied techniques for the measurement of mobile fraction of heavy metal present in the urban environment. This work examined the compliance between SSD proposed by the Community Bureau of Reference (BCR) and isotopic dilution technique (IDT) for determination of mobile pool of heavy metal contained in soakaway sediment, road dust, and soil sample. Heavy metals (Cu, Zn, Cd and Pb) were fractionated using the three-stage BCR protocol, while isotopically exchangeable metal concentrations (E-value) were investigated through isotopic tracers (¹¹¹Cd, ⁶⁵Cu, ²⁰⁷Pb and ⁶⁶Zn). In general, total contamination level, E-value and BCR exchangeable fractions of different samples followed the similar order of road dust > soakaway sediment > soil. Results revealed that the E-value exceeded the BCR exchangeable fraction in all samples. In addition, the first three fractions of BCR which have potential to become mobile under certain environmental conditions were collectively termed as "potential mobile pool" and compared with E-value. It was concluded that metal extracted by weak acid underestimates the exchangeable fraction while the potential mobile pool extracted by three reagents overestimates the real mobile forms of heavy metals. However, better mobility characteristics of heavy metals can be assessed by coupling information obtained through sequential extraction and isotopic exchange.

  6. Mineral phases containing heavy metals in the suspended dust from Budapest, Hungary

    Directory of Open Access Journals (Sweden)

    Sipos P.

    2013-04-01

    Full Text Available The mineralogy, geochemistry and magnetic properties of total suspended particulate (TSP matter in Budapest, Hungary were studied to identify their heavy metal-bearing mineral phases. Amorphous organic matter, magnetite, salts as well as mineral phases characteristic of the surrounding geology are the main components of the TSP. They show significant enrichment in several heavy metals, such as Zn (up to 19 046 mg/kg, Pb (up to 3597 mg/kg, Cu (up to 699 mg/kg and Mo (up to 53 mg/kg. The most frequent heavy metal-bearing mineral phases are spherular or xenomorphic magnetite particles containing 2-3 wt% Pb and Zn. They often form aggregates and are closely associated with soot and/or clay minerals. The size of these particles is rarely below 30 nm. Cu and Mo could be associated to magnetite too. Clay minerals and mica particles may also contain significant amount of Zn (up to 5wt%. Additionally, ZnO and ZnCO3 particles were found in the sample with highest Zn content and our data suggest the potential association of Pb and carbonates, as well. Magnetite particles are resistant to weathering releasing its toxic components slowly to the environment, while layer silicates (and carbonates may be the potential source of mobile toxic metals in the TSP.

  7. Total suspended dust and heavy metal levels emitted from a workplace compared with nearby residential houses

    Science.gov (United States)

    Abdul-Wahab, Sabah A.; Yaghi, Basma

    Total suspended particulate matter (TSP) were collected from the workplace in Sohar Industrial Estate (SIE) in Oman. The samples were taken from 19 different industrial activities that represent major sources of particulate matter in the SIE. The collected samples were analyzed for 9 heavy metals (Cr, Cu, Mn, Ni, Pb, Zn, Cd, V and Mo) by using the inductively coupled plasma optical emission spectrometry analysis (ICP-OES). Furthermore, the indoor TSP and heavy metal concentrations were measured inside 12 houses within Sohar residential area to determine the contributions of various industrial activities on nearby residential houses. The results indicated that the mean concentrations of heavy metals in the TSP were too low to yield any known environmental health effects. In general, the results showed that the concentrations of heavy metals in the workplaces of SIE and its nearby houses were low compared to the guideline values. In addition, the values were low in comparison with other known sites around the world. Moreover, significant contribution from industrial sources at SIE was evidenced at nearby houses.

  8. Assessment on the occupational exposure of urban public bus drivers to bioaccessible trace metals through resuspended fraction of settled bus dust.

    Science.gov (United States)

    Gao, Peng; Liu, Sa; Ye, Wenyuan; Lin, Nan; Meng, Ping; Feng, Yujie; Zhang, Zhaohan; Cui, Fuyi; Lu, Binyu; Xing, Baoshan

    2015-03-01

    Limited information is available on the bioaccessible fraction of trace metals in the resuspended fraction of settled bus dust in order to estimate bus drivers' occupational exposure. In this study, 45 resuspended fraction of settled dust samples were collected from gasoline and compressed natural gas (CNG) powered buses and analyzed for trace metals and their fraction concentrations using a three-step sequential extraction procedure. Experimental results showed that zinc (Zn) had the greatest bioaccessible fraction, recorded as an average of 608.53 mg/kg, followed in order of decreasing concentration by 129.80 mg/kg lead (Pb), 56.77 mg/kg copper (Cu), 34.03 mg/kg chromium (Cr), 22.05 mg/kg nickel (Ni), 13.17 mg/kg arsenic (As) and 2.77 mg/kg cadmium (Cd). Among the three settled bus dust exposure pathways, ingestion was the main route. Total exposure hazard index (HIt) for non-carcinogenic effect trace metals was lower than the safety level of 1. The incremental lifetime cancer risk (ILCR) for drivers was estimated for trace metal exposure. Pb and Ni presented relatively high potential risks in the non-carcinogenic and potentially carcinogenic health assessment for all drivers. ILCR was in the range of 1.84E-05 to 7.37E-05 and 1.74E-05 to 6.95E-05 for gasoline and CNG buses, respectively. Copyright © 2014 Elsevier B.V. All rights reserved.

  9. Health Risks and Contamination Levels of Heavy Metals in Dusts from Parks and Squares of an Industrial City in Semi-Arid Area of China

    Science.gov (United States)

    Han, Xiufeng; Lu, Xinwei; Qinggeletu; Wu, Yongfu

    2017-01-01

    The contamination characteristics and health risk of barium (Ba), cobalt (Co), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), lead (Pb), vanadium (V), zinc (Zn), arsenic (As), mercury (Hg), and cadmium (Cd) in samples of dust gathered from squares and parks of Baotou city, an industrial city situated in a semi-arid location of the northwest China were investigated. The contents of Ba, Co, Cr, Cu, Mn, Ni, V, Pb, and Zn in the collected dust samples were determined using X-ray fluorescence spectrometry, while the contents of As and Hg in the dust were investigated by use of the ICP-MS. Further, cadmium was quantified through the atomic absorption spectrometry. Levels of contamination of heavy metals analyzed in the dust samples were evaluated using the Geo-Accumulation index (Igeo) as well as through a Pollution Load Index (PLI). Their health risks to children and adults were evaluated based on the US EPA model of health risk. The findings portrayed that the mean concentrations of Ba, Co Cr, Cu, Pb, V, Cd, and Hg were elevated as compared with their local soil background values. Mean values of Igeo illustrate the order of Co > Cr> Cd > Hg > Pb > Cu > Ba > V > Ni > Mn > Zn > As. It was evident that dusts from the parks and squares were “unpolluted” to “moderately polluted”. Assessment of health risk depicts that ingestion is the foremost route of exposure in regard to the heavy metals, then the dermal adsorption follows. Hg exposure from dust might also set impending health threats to children. Besides, the cancer risks of Co, Cr, Ni, Cd, and As are considered to be within the presently tolerable range. PMID:28783109

  10. Assessment on the occupational exposure of urban public bus drivers to bioaccessible trace metals through resuspended fraction of settled bus dust

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Peng [State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, No. 73 Huanghe Road, Nangang District, Harbin 150090 (China); Stockbridge School of Agriculture, University of Massachusetts, Amherst, MA 01003 (United States); Liu, Sa [Environmental Health Sciences Division, School of Public Health, University of California, Berkeley, CA, 94720-7360 (United States); Ye, Wenyuan [Department of Chemical Engineering, KU Leuven, Willem de Croylaan 46, B-3001 Heverlee (Belgium); Lin, Nan; Meng, Ping [State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, No. 73 Huanghe Road, Nangang District, Harbin 150090 (China); Feng, Yujie, E-mail: yujief@hit.edu.cn [State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, No. 73 Huanghe Road, Nangang District, Harbin 150090 (China); Zhang, Zhaohan; Cui, Fuyi; Lu, Binyu [State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, No. 73 Huanghe Road, Nangang District, Harbin 150090 (China); Xing, Baoshan [Stockbridge School of Agriculture, University of Massachusetts, Amherst, MA 01003 (United States)

    2015-03-01

    Limited information is available on the bioaccessible fraction of trace metals in the resuspended fraction of settled bus dust in order to estimate bus drivers ' occupational exposure. In this study, 45 resuspended fraction of settled dust samples were collected from gasoline and compressed natural gas (CNG) powered buses and analyzed for trace metals and their fraction concentrations using a three-step sequential extraction procedure. Experimental results showed that zinc (Zn) had the greatest bioaccessible fraction, recorded as an average of 608.53 mg/kg, followed in order of decreasing concentration by 129.80 mg/kg lead (Pb), 56.77 mg/kg copper (Cu), 34.03 mg/kg chromium (Cr), 22.05 mg/kg nickel (Ni), 13.17 mg/kg arsenic (As) and 2.77 mg/kg cadmium (Cd). Among the three settled bus dust exposure pathways, ingestion was the main route. Total exposure hazard index (HIt) for non-carcinogenic effect trace metals was lower than the safety level of 1. The incremental lifetime cancer risk (ILCR) for drivers was estimated for trace metal exposure. Pb and Ni presented relatively high potential risks in the non-carcinogenic and potentially carcinogenic health assessment for all drivers. ILCR was in the range of 1.84E − 05 to 7.37E − 05 and 1.74E − 05 to 6.95E − 05 for gasoline and CNG buses, respectively. - Highlights: • As, Cd and Ni had relatively higher bioaccessibility and mobility in the resuspended fraction of settled bus dust. • Bioaccessible metal concentrations were higher in gasoline-fueled buses than those in CNG-fueled buses. • The carcinogenic risk probabilities to drivers were around the acceptable level.

  11. Anthropogenic Enrichment of Heavy Metals in Urban Dust and Possible Corresponding Sources

    Science.gov (United States)

    van Laaten, Neele; Merten, Dirk; Pirrung, Michael

    2017-04-01

    Atmospheric dust (particulate matter, PM) is regarded as a crucial factor for human health and a major environmental problem in densely populated areas. Due to anthropogenic processes like traffic, waste incineration and industry increased amounts of PM can be detected in those areas. To reduce the amounts detailed knowledge on both the composition of PM and the source contribution in a target area is needed. The latter has, to our knowledge, rarely been regarded in central Europe. Within this study, spider webs from various locations in the city of Jena (Germany), that act as natural trappers of PM, were analyzed for the contents of 27 trace elements using aqua regia digestion followed by ICP-OES and ICP-MS determinations. Aerosol-crust enrichment factors were calculated for selected elements and both a cluster analysis and a factor analysis were executed to identify sources of PM. High values for the enrichment factors clearly show an anthropogenic influence. In addition, the cluster analysis leads to a grouping of the sampling points mainly depending on the kind and volume of traffic at the corresponding locations. Five different possible sources of PM can be found by the factor analysis: Soil erosion (41% of variance), abrasion of rails (16%), tyre and break wear (16%), charcoal combustion (8%) and oil combustion (7%).

  12. Microscopic and chemical studies of metal particulates in tree bark and attic dust: evidence for historical atmospheric smelter emissions, Humberside, UK.

    Science.gov (United States)

    Tye, A M; Hodgkinson, E S; Rawlins, B G

    2006-09-01

    Tree barks and attic dusts were examined as historical archives of smelter emissions, with the aim of elucidating the pathways of pollution associated with a plume of Sn and Pb contamination in top soils, found close to the former Capper Pass smelter, Humberside, UK. Samples were collected from three villages within the area of the contamination plume. Scanning electron microscopy (SEM) and bulk chemical analyses were used to assess particle type, number and deposition patterns. SEM analysis of dusts and bark revealed that Sn and Pb particles were present in samples from all three villages along with copper, zinc and iron particles. These were almost entirely dusts demonstrated that concentrations of Sn, Pb, Cu, As, Sb and Cd diminished with increasing distance from the source. Strong positive correlations were found between Sn and Pb, As, Sb and Cd in the attic dusts. Enrichment factors (EF) were calculated for these trace elements based on topsoil element concentrations obtained from the soil survey of the study area. Decreases in these trace element concentrations and EF values with distance away from the smelter are consistent with trends found in the soil survey for Sn and Pb and are typical of deposition patterns around smelter stacks. The study demonstrates that tree bark and attic dusts can be effective archives of metal particulates deposited from large static emission sources.

  13. Experimental Study on Toxic Dust and Gas Control in Blasting at Metal Mines%金属矿山爆破除尘降毒实验研究

    Institute of Scientific and Technical Information of China (English)

    刘桂丽

    2011-01-01

    以爆破过程除尘降毒为目的,分析了金属矿山爆破尘毒来源,根据实验场所情况,选取水封爆破和喷雾除尘结合使用的方案进行实验.实验结果表明,水封爆破和水雾除尘对于降低粉尘和有毒有害气体浓度具有明显的效果.%In order to reduce the concentration of dust and poisonous gas in blasting process at metal mines, the sources of toxic dust in blasting was analyzed.According to the conditions of experimental site, experiment was made on the combined application of water - seal blasting and dust control with water spraying.The result showed that the combined application of water seal blasting and dust control with water spraying can effectively reduced the concentration of dust and poisonous gases.

  14. Evaluation of the pollution and human health risks posed by heavy metals in the atmospheric dust in Ebinur Basin in Northwest China.

    Science.gov (United States)

    Abuduwailil, Jilili; Zhaoyong, Zhang; Fengqing, Jiang

    2015-09-01

    Recently, a large amount of research assessing pollution levels and the related health risks posed by atmosphere dust has been undertaken worldwide. However, little work has been done in the oases of the arid regions of Northwest China. In this paper, we studied the pollution and health risks over a year of seven heavy metals in the atmospheric dust of Ebinur Basin, a typical oasis in Northwest China. The results showed the following: (1) The annual amount of atmospheric deposition in Ebinur Basin was 298.23 g m(-2) and the average monthly atmospheric deposition was 25.06 g m(-2). The average and maximum values of the seven heavy metals measured were all below the National Soil Environmental Quality Standards (2nd). (2) Heavy metals of Cu, Cr, and As in the atmospheric deposition mainly originated from the natural geological background, while Zn came from human activity. This study also showed that among the seven measured heavy metals, the ratios of the no-pollution status of Pb, Cd, and Hg were higher than those of others with moderate degrees of pollution also accounting for a certain ratio. (3) The carcinogenic risks from As, Cd, and Cr were all lower than the corresponding standard limit values, and these metals are considered not harmful to the health of the basin. However, there is a relatively high risk of exposure for children from hand-to-mouth intake, which is worthy of attention. This research showed that both human activity and natural factors, such as wind and altitude, influenced the heavy metal contents in the atmospheric dust of the study area. Furthermore, recent human activity in the study area had the most negative influence on the accumulation of the heavy metals and the corresponding health risks, especially for Hg, Pb, and Cd, which is worthy of attention.

  15. Dust formation and mass loss around intermediate-mass AGB stars with initial metallicity Zini ≤ 10-4 in the early Universe - I. Effect of surface opacity on stellar evolution and the dust-driven wind

    Science.gov (United States)

    Tashibu, Shohei; Yasuda, Yuki; Kozasa, Takashi

    2017-04-01

    Dust formation and the resulting mass loss around asymptotic giant branch (AGB) stars with initial metallicity in the range 0 ≤ Zini ≤ 10-4 and initial mass 2 ≤ Mini/M⊙ ≤ 5 are explored by hydrodynamical calculations of the dust-driven wind (DDW) along the AGB evolutionary tracks. We employ the MESA code to simulate the evolution of stars, assuming an empirical mass-loss rate in the post-main-sequence phase and considering three types of low-temperature opacity (scaled-solar, CO-enhanced and CNO-enhanced opacity) to elucidate the effect on stellar evolution and the DDW. We find that the treatment of low-temperature opacity strongly affects dust formation and the resulting DDW; in the carbon-rich AGB phase, the maximum dot{M} of Mini ≥ 3 M⊙ stars with the CO-enhanced opacity is at least one order of magnitude smaller than that with the CNO-enhanced opacity. A wide range of stellar parameters being covered, the necessary condition for driving efficient DDW with dot{M} ≥ 10^{-6} M⊙ yr-1 is expressed as effective temperature Teff ≲ 3850 K and log (δCL/κRM) ≳ 10.43log Teff - 32.33, with the carbon excess δC defined as εC - εO, the Rosseland mean opacity κR in units of cm2 g-1 in the surface layer and the stellar mass (luminosity) M(L) in solar units. The fitting formulae derived for gas and dust mass-loss rates in terms of input stellar parameters could be useful for investigating the dust yield from AGB stars in the early Universe being consistent with stellar evolution calculations.

  16. Street Dust: Source and Sink of Heavy Metals To Urban Environment

    Directory of Open Access Journals (Sweden)

    Ayrault S.

    2013-04-01

    Full Text Available Air-transferred solid material accumulated for 40 years in different places in an urban area, Grenoble city, France. An appropriate fractionation procedure allowed to separate: 1 a coarse inorganic fraction, 2 a coarse organic fraction, 3 a slowly depositing organo-clay fraction and 4 very fine particles. The composition of each fraction was determined for 20 elements and for isotopic lead signature. The organo-clay fraction was especially rich in Ag, Cd, Co, Cr, Ni and Ti. The sand fraction showed very high concentrations specifically in Cu, Pb and Fe. In contrast, Cd and Zn were mainly accumulated in the coarse organic fraction. The SEM-EDX study of the coarse inorganic fraction showed the presence of red particles associating Pb and Fe, black particles rich in Cu and typical fly ashes originating mostly from iron industry. This sand fraction is suspected to contribute to the contamination of the organo-clay fraction through adsorption. The Pb-Fe contamination likely originates from the neighbouring road surface contaminated by car traffic for several decades. The 206Pb/207Pb ratio showed that these street dust samples may contain up to 50% of lead originated from leaded gasoline additives, twelve years after their prohibition. All these features clearly differ from the composition found for the deposit on tree bark in the same place. These results demonstrate that the deposition over several decades is a very complex phenomenon which requires multi-techniques investigations to be understood thoroughly. They also show that large dense particles which can only be transported on a limited distance by high magnitude events may play a major role in the long-term contamination of urban soils.

  17. Assessment of health risk of trace metal pollution in surface soil and road dust from e-waste recycling area in China.

    Science.gov (United States)

    Yekeen, Taofeek Akangbe; Xu, Xijin; Zhang, Yuling; Wu, Yousheng; Kim, Stephani; Reponen, Tiina; Dietrich, Kim N; Ho, Shuk-Mei; Chen, Aimin; Huo, Xia

    2016-09-01

    Informal recycling of e-waste and the resulting heavy metal pollution has become a serious burden on the ecosystem in Guiyu, China. In this investigation, we evaluated the trace metal concentration of community soil and road dust samples from 11 locations in Guiyu and 5 locations (consisting of residential areas, kindergarten/school, and farm field) in a reference area using graphite furnace atomic absorption spectrophotometer. The study spanned four seasons, 2012-2013, with a view to assess the risk associated with e-waste recycling in the study area. The concentrations of Pb, Cd, Cr, and Mn were 448.73, 0.71, 63.90, and 806.54 mg/kg in Guiyu soil and 589.74, 1.94, 69.71, and 693.74 mg/kg, in the dust, respectively. Pb and Cd values were significantly higher (P ≤ 0.05) than the reference area, and the mixed model analysis with repeated seasonal measurements revealed soil Pb and Cd levels that were 2.32 and 4.34 times, while the ratios for dust sample were 4.10 and 3.18 times higher than the reference area. Contamination factor, degree of contamination, and pollution load index indicated that all sampling points had a high level of metal contamination except farm land and kindergarten compound. The cumulative hazard index of Pb, Cd, Cr, and Mn for children in exposed area was 0.99 and 1.62 for soil and dust, respectively, suggesting non-cancer health risk potential. The significant accumulation of trace metals in the e-waste recycling area predisposes human life, especially children, to a potentially serious health risk.

  18. Human Health Risk Assessment Based on Toxicity Characteristic Leaching Procedure and Simple Bioaccessibility Extraction Test of Toxic Metals in Urban Street Dust of Tianjin, China

    Science.gov (United States)

    Yu, Binbin; Wang, Yu; Zhou, Qixing

    2014-01-01

    The potential ecological and human health risk related with urban street dust from urban areas of Tianjin, China was quantitatively analyzed using the method of toxicity characteristic leaching procedure (TCLP) and simple bioaccessibility extraction test (SBET). In the study, Hakason index, Nemerow index (P), the hazard index (HI) and the cancer risk index (RI) were calculated to assess the potential risk. The sequence of potential ecological risk based on Hakason index was arsenic (As) > cadmium (Cd) > lead (Pb) > copper (Cu) > chromium (Cr), in particular, As and Cd were regarded as high polluted metals. While the results of extraction of TCLP were assessed using P, the sequence was As > Pb > Cd > Cr > Cu, which mean that As and Pb should be low polluted, and Cd, Cr and Cu would barely not polluted. For human health, total carcinogenic risk for children and adults was 2.01×10−3 and 1.05×10−3, respectively. This could be considered to be intolerable in urban street dust exposure. The sequence in the hazard quotient (HQ) of each element was As > Cr > Pb > Cu > Cd. The HI value of these toxic metals in urban street dust for children and adults was 5.88×10−1 and 2.80×10−1, respectively. According to the characters of chemistry, mobility, and bioavailability of metals in urban street dust, we estimated the hazards on the environment and human health, which will help us to get more reasonable information for risk management of metals in urban environment. PMID:24651129

  19. Human health risk assessment based on toxicity characteristic leaching procedure and simple bioaccessibility extraction test of toxic metals in urban street dust of Tianjin, China.

    Directory of Open Access Journals (Sweden)

    Binbin Yu

    Full Text Available The potential ecological and human health risk related with urban street dust from urban areas of Tianjin, China was quantitatively analyzed using the method of toxicity characteristic leaching procedure (TCLP and simple bioaccessibility extraction test (SBET. In the study, Hakason index, Nemerow index (P, the hazard index (HI and the cancer risk index (RI were calculated to assess the potential risk. The sequence of potential ecological risk based on Hakason index was arsenic (As > cadmium (Cd > lead (Pb > copper (Cu > chromium (Cr, in particular, As and Cd were regarded as high polluted metals. While the results of extraction of TCLP were assessed using P, the sequence was As > Pb > Cd > Cr > Cu, which mean that As and Pb should be low polluted, and Cd, Cr and Cu would barely not polluted. For human health, total carcinogenic risk for children and adults was 2.01 × 10(-3 and 1.05 × 10(-3, respectively. This could be considered to be intolerable in urban street dust exposure. The sequence in the hazard quotient (HQ of each element was As > Cr > Pb > Cu > Cd. The HI value of these toxic metals in urban street dust for children and adults was 5.88 × 10(-1 and 2.80 × 10(-1, respectively. According to the characters of chemistry, mobility, and bioavailability of metals in urban street dust, we estimated the hazards on the environment and human health, which will help us to get more reasonable information for risk management of metals in urban environment.

  20. Rural Households

    DEFF Research Database (Denmark)

    2013-01-01

    dependency on state institutions under the Vietnamese transition to a market society. It discusses present poverty definitions and measures by comparing survey data with the formal economic categorization of rural households. Both the overall characteristics of rural society and qualitative data indicate...

  1. Household Savings

    DEFF Research Database (Denmark)

    Browning, Martin; Lusardi, Annamaria

    In this survey, we review the recent theoretical and empirical literature on household saving and consumption. The discussion is structured around a list of motives for saving and how well the standard theory captures these motives. We show that almost all of the motives for saving that have been...

  2. Exploring the Overabundance of ULXs in Metal- and Dust-poor Local Lyman Break Analogs

    CERN Document Server

    Basu-Zych, Antara R; Fragos, Tassos; Hornschemeier, Ann; Yukita, Mihoko; Zezas, Andreas; Ptak, Andy

    2016-01-01

    We have studied high mass X-ray binary (HMXB) populations within two low-metallicity, starburst galaxies, Haro 11 and VV 114. These galaxies serve as analogs to high-redshift (z>2) Lyman break galaxies, and within the larger sample of Lyman break analogs (LBAs) are sufficiently nearby (10^{39}$ erg/s; ultraluminous X-ray sources, ULXs) in these low-metallicity galaxies, based on 8 detected ULXs. Comparing with the star-forming galaxy X-ray luminosity function (XLF) presented by Mineo et al. (2012), Haro 11 and VV 114 host ~4 times more L$_X>10^{40}$ erg/s sources than expected given their SFRs. We simulate the effects of source blending from crowded lower luminosity HMXBs using the star-forming galaxy XLF and then vary the XLF shapes until we reproduce the observed point source luminosity distributions. We find that these LBAs have a shallower bright end slope than the standard XLF. If we conservatively assume that the brightest X-ray source from each galaxy is powered by an AGN rather than a HMXB and elimina...

  3. Exploring the Overabundance of ULXs in Metal- and Dust-poor Local Lyman Break Analogs

    Science.gov (United States)

    Basu-Zych, Antara R.; Lehmer, Bret; Fragos, Tassos; Hornschemeier, Ann; Yukita, Mihoko; Zezas, Andreas; Ptak, Andy

    2016-02-01

    We have studied high-mass X-ray binary (HMXB) populations within two low-metallicity, starburst galaxies, Haro 11 and VV 114. These galaxies serve as analogs to high-redshift (z\\gt 2) Lyman break galaxies and, within the larger sample of Lyman break analogs (LBAs), they are sufficiently nearby (crowded lower-luminosity HMXBs using the star-forming galaxy XLF and then vary the XLF normalizations and bright-end slopes until we reproduce the observed point source luminosity distributions. We find that these LBAs have a shallower bright-end slope ({γ }2=1.90) than the standard XLF ({γ }2=2.73). If we conservatively assume that the brightest X-ray source from each galaxy is powered by an accreting supermassive black hole rather than an HMXB and eliminate these sources from consideration, the luminosity distribution becomes poorly constrained but does appear to be consistent with a standard XLF.

  4. Distributions, sources and pollution status of 17 trace metal/metalloids in the street dust of a heavily industrialized city of central China.

    Science.gov (United States)

    Li, Zhonggen; Feng, Xinbin; Li, Guanghui; Bi, Xiangyang; Zhu, Jianming; Qin, Haibo; Dai, Zhihui; Liu, Jinling; Li, Qiuhua; Sun, Guangyi

    2013-11-01

    A series of representative street dust samples were collected from a heavily industrialized city, Zhuzhou, in central China, with the aim to investigate the spatial distribution and pollution status of 17 trace metal/metalloid elements. Concentrations of twelve elements (Pb, Zn, Cu, Cd, Hg, As, Sb, In, Bi, Tl, Ag and Ga) were distinctly amplified by atmospheric deposition resulting from a large scale Pb/Zn smelter located in the northwest fringe of the city, and followed a declining trend towards the city center. Three metals (W, Mo and Co) were enriched in samples very close to a hard alloy manufacturing plant, while Ni and Cr appeared to derive predominantly from natural sources. Other industries and traffic had neglectable effects on the accumulation of observed elements. Cd, In, Zn, Ag and Pb were the five metal/metalloids with highest pollution levels and the northwestern part of city is especially affected by heavy metal pollution.

  5. The relationship between magnetic parameters and heavy metal contents of indoor dust in e-waste recycling impacted area, Southeast China.

    Science.gov (United States)

    Zhu, Zongmin; Han, Zhixuan; Bi, Xiangyang; Yang, Wenlin

    2012-09-01

    Environmental contamination due to uncontrolled e-waste recycling is an emerging global problem. The aim of this study is to test the applicability of magnetic methods for detecting the metal pollutants emitted from e-waste recycling activities. Dust samples collected from a typical e-waste recycling region in Guiyu, Guangdong Province, China, were investigated using magnetic, geochemical, micro-morphological and mineralogical analysis. The values of mass-specific susceptibility (χ) and saturation isothermal remanent magnetization (SIRM) in dusts from e-waste recycling impacted areas ranged from 101 to 636×10(-8) m(3) kg(-1) and from 10.5 to 85.2×10(-3) Am(2) kg(-1), respectively. There was a significant correlation between SIRM and χ (r(2)=0.747, pdust samples. The values of χ(fd)% varied from 2.6 to 4.6% with a mean of 3.4%, which suggested that magnetic carriers in the dusts are predominately coarse-grained particles. Two shapes of magnetic particles, spherule (10-150 μm) and angular-shaped particles (30-300 μm), were identified by scanning electron microscope (SEM) and energy dispersive X-ray spectrometer (EDX) analyses. κ-T curves, magnetic hysteresis loops and X-ray diffraction (XRD) analysis indicated that these magnetic particles were magnetite and goethite. There were significant correlations between SIRM and heavy metals (especially Cd, Co, Fe, Ni and Zn) as well as the Tomlinson pollution load index (PLI) of the dust, indicating that SIRM can be used as an efficient proxy for metal pollution in the e-waste recycling impacted area.

  6. Valorization of GaN based metal-organic chemical vapor deposition dust a semiconductor power device industry waste through mechanochemical oxidation and leaching: A sustainable green process.

    Science.gov (United States)

    Swain, Basudev; Mishra, Chinmayee; Lee, Chan Gi; Park, Kyung-Soo; Lee, Kun-Jae

    2015-07-01

    Dust generated during metal organic vapor deposition (MOCVD) process of GaN based semiconductor power device industry contains significant amounts of gallium and indium. These semiconductor power device industry wastes contain gallium as GaN and Ga0.97N0.9O0.09 is a concern for the environment which can add value through recycling. In the present study, this waste is recycled through mechanochemical oxidation and leaching. For quantitative recovery of gallium, two different mechanochemical oxidation leaching process flow sheets are proposed. In one process, first the Ga0.97N0.9O0.09 of the MOCVD dust is leached at the optimum condition. Subsequently, the leach residue is mechanochemically treated, followed by oxidative annealing and finally re-leached. In the second process, the MOCVD waste dust is mechanochemically treated, followed by oxidative annealing and finally leached. Both of these treatment processes are competitive with each other, appropriate for gallium leaching and treatment of the waste MOCVD dust. Without mechanochemical oxidation, 40.11 and 1.86 w/w% of gallium and Indium are leached using 4M HCl, 100°C and pulp density of 100 kg/m(3,) respectively. After mechanochemical oxidation, both these processes achieved 90 w/w% of gallium and 1.86 w/w% of indium leaching at their optimum condition.

  7. Investigation of heavy metal concentrations on urban soils, dust and vegetables nearby a former smelter site in Mortagne du Nord, Northern France

    Energy Technology Data Exchange (ETDEWEB)

    Douay, F.; Roussel, H.; Fourrier, H. [Lab. Sols et Environnement, Inst. Superieur d' Agriculture, Lille (France); Heyman, C. [Cellule Inter regionale d' Epidemiologie Nord Picardie, Lille (France); Chateau, G. [Direction Regionale des Affaires Sanitaires et Sociales, Lille (France)

    2007-06-15

    Environmental situations near former industrial sites like Mortagne du Nord (Northern France) in which the soil, dust and homegrown vegetables have been contaminated by heavy metals can represent a sanitary risk to the surrounding population. In order to evaluate the contamination level in different exposition media in this site, 26 urban topsoils, 17 dust and 38 vegetable samples were taken near the former zinc smelter site. All the observed levels on urban soil samples (except one) are over regional agricultural reference values for Cd and Pb. 45% of the vegetable samples are over the European foodstuff limits and one dust sample taken in the school playground outdoor tarmac area exceeds the French limit in dust set up at 1000 {mu}g m-{sup 2} for Pb. The Cd and Pb levels fluctuate depending on the use of the ground (kitchen garden, lawn, courtyard) and its location. The lack of simple correlations between the distance from the former smelter site and the Pb concentrations on sampled soils let us think that human activities contributed in the local urban contamination. In this context, who is now responsible for the soil contamination and the human exposure? (orig.)

  8. ISM Properties in Low-Metallicity Environments III. The Dust Spectral Energy Distributions of II Zw 40, He 2-10 and NGC 1140

    CERN Document Server

    Galliano, F; Jones, A P; Wilson, C D; Bernard, J P

    2005-01-01

    We present new 450 and 850 micron SCUBA data and 1.3 mm MAMBO data of the dwarf galaxies II Zw 40, He 2-10 and NGC 1140. Additional ISOCAM, IRAS as well as ground based data are used to construct the observed mid-infrared to millimeter spectral energy distribution of these galaxies. These spectral energy distributions are modeled in a self-consistent way, as was achieved with NGC 1569 (Galliano et al., 2003), synthesizing both the global stellar radiation field and the dust emission, with further constraints provided by the photoionisation of the gas. Our study shows that low-metallicity galaxies have very different dust properties compared to the Galaxy. Our main results are: (i) a paucity of PAHs which are likely destroyed by the hard penetrating radiation field, (ii) a very small (3-4 nm) average size of grains, consistent with the fragmentation and erosion of dust particles by the numerous shocks, (iii) a significant millimetre excess in the dust spectral energy distribution which can be explained by the ...

  9. 45 Potential Toxins Found in Household Dust

    Science.gov (United States)

    ... The study findings were published Sept. 14 in Environmental Science & Technology . SOURCES: Ami Zota, Sc.D., assistant professor, environmental ... 2016, statement, American Chemistry Council; Sept. 14, 2016, Environmental Science & Technology HealthDay Copyright (c) 2016 HealthDay . All rights reserved. ...

  10. Dust dispersal and Pb enrichment at the rare-metal Orlovka-Spokoinoe mining and ore processing site: insights from REE patterns and elemental ratios.

    Science.gov (United States)

    Dolgopolova, Alla; Weiss, Dominik J; Seltmann, Reimar; Dulski, Peter

    2006-04-30

    Different geological, technogenic and environmental samples from the Orlovka-Spokoinoe Ta-Nb-Sn-W mining site and ore processing complex in Eastern Transbaikalia (Russia), were analysed for Pb, Y, Zr, Hf and rare earth elements (REE) to assess the effect of dust and metal dispersal on the environment within the Orlovka-Spokoinoe mining site. Potential source material analysed included ore-bearing and barren granites, host rocks, tailing pond sediments, and ore concentrates. Lichens and birch leaves were used as receptor samples. The REE enrichment relative to chondrite, the extent of the Eu anomalies, the enrichments of heavy REE (HREE), and Zr/Hf and Yb/Y ratios suggest that tailings, barren granites, and metasedimentary host rocks are the main sources of dust in the studied mining environment. In addition, calculated lead enrichment (relative to host rocks) suggests that the environment is polluted with Pb. Our results clearly demonstrate the potential of REE patterns and elemental ratios as a reliable technique to trace dust and metals sources and dispersal within a confined mining area offering a new tool for environmental assessment studies.

  11. Dust dispersal and Pb enrichment at the rare-metal Orlovka-Spokoinoe mining and ore processing site: Insights from REE patterns and elemental ratios

    Energy Technology Data Exchange (ETDEWEB)

    Dolgopolova, Alla [Centre for Russian and Central EurAsian Mineral Studies (CERCAMS), Department of Mineralogy, Natural History Museum, Cromwell Road, London SW7 5BD (United Kingdom)]. E-mail: allad@nhm.ac.uk; Weiss, Dominik J. [Centre for Russian and Central EurAsian Mineral Studies (CERCAMS), Department of Mineralogy, Natural History Museum, Cromwell Road, London SW7 5BD (United Kingdom); Department of Earth Science and Engineering, Imperial College London, London SW7 2AZ (United Kingdom); Seltmann, Reimar [Centre for Russian and Central EurAsian Mineral Studies (CERCAMS), Department of Mineralogy, Natural History Museum, Cromwell Road, London SW7 5BD (United Kingdom); Dulski, Peter [GFZ Potsdam, Telegrafenberg, D-14473 Potsdam (Germany)

    2006-04-30

    Different geological, technogenic and environmental samples from the Orlovka-Spokoinoe Ta-Nb-Sn-W mining site and ore processing complex in Eastern Transbaikalia (Russia), were analysed for Pb, Y, Zr, Hf and rare earth elements (REE) to assess the effect of dust and metal dispersal on the environment within the Orlovka-Spokoinoe mining site. Potential source material analysed included ore-bearing and barren granites, host rocks, tailing pond sediments, and ore concentrates. Lichens and birch leaves were used as receptor samples. The REE enrichment relative to chondrite, the extent of the Eu anomalies, the enrichments of heavy REE (HREE), and Zr/Hf and Yb/Y ratios suggest that tailings, barren granites, and metasedimentary host rocks are the main sources of dust in the studied mining environment. In addition, calculated lead enrichment (relative to host rocks) suggests that the environment is polluted with Pb. Our results clearly demonstrate the potential of REE patterns and elemental ratios as a reliable technique to trace dust and metals sources and dispersal within a confined mining area offering a new tool for environmental assessment studies.

  12. Trace Metals in Saharan Dust: The Use of in Vitro Bioaccessibility Extractions To Assess Potential Health Risks in a Dustier World: Chapter 3

    Science.gov (United States)

    Morman, Suzette A.; Garrison, Virginia H.; Plumlee, Geoffrey S.

    2013-01-01

    Exposure to fine particulate matter (PM) is acknowledged as a risk factor for human morbidity and mortality. Epidemiology and toxicology studies have focused on anthropogenic sources of PM and few consider contributions produced by natural processes (geogenic), or PM produced from natural sources as a result of human activities (geoanthropogenic PM). The focus of this study was to elucidate relationships between human/ecosystem health and dusts produced by a system transitioning from a dominantly natural to a geoanthropogenic PM source. As part of a larger study investigating the relationship between atmospheric transportation of African dust, human health, and coral reef declines, we examined dust samples sourced in Mali, Africa, collected using high-volume samplers from three sites (Mali, Tobago and U.S. Virgin Islands). Inhalation and ingestion exposure pathways were explored by filter extractions using simulated lung and gastric fluids. Bioaccessibility varied by metal and extraction fluid. Although too few samples were analyzed for robust statistics, concentrations for several metals decreased slightly while bioaccessibility increased at downwind sites.

  13. A METAL-STRONG AND DUST-RICH DAMPED Ly{alpha} ABSORPTION SYSTEM TOWARD THE QUASAR SDSS J115705.52+615521.7

    Energy Technology Data Exchange (ETDEWEB)

    Wang Jianguo [National Astronomical Observatories/Yunnan Observatory, Chinese Academy of Sciences, P.O. Box 110, Kunming, Yunnan 650011 (China); Zhou Hongyan; Jiang Peng; Lu Honglin; Wang Huiyuan; Wang Tinggui [Key Laboratory for Research in Galaxies and Cosmology, Department for Astronomy, University of Sciences and Technology of China, Chinese Academy of Sciences, Hefei, Anhui 230026 (China); Ge Jian; Hamann, Fred [Astronomy Department, University of Florida, 211 Bryant Space Science Center, P.O. Box 112055, Gainesville, FL 32611 (United States); Xavier Prochaska, J. [Department of Astronomy and Astrophysics, UCO/Lick Observatory, University of California, 1156 High Street, Santa Cruz, CA 95064 (United States); Yuan Weimin, E-mail: wangjg@ynao.ac.cn [National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China)

    2012-11-20

    We report the discovery of an unusual, extremely dust-rich and metal-strong damped Ly{alpha} absorption system (DLA) at a redshift z{sub a} = 2.4596 toward the quasar SDSS J115705.52+615521.7 with an emission-line redshift z{sub e} = 2.5125. The quasar spectrum, taken in the Sloan Digital Sky Survey, shows a very red color and a number of metal absorption lines, including C II, Al II, Si II, Fe II, and Zn II, which are confirmed and further characterized by follow-up spectroscopy made with the Multiple Mirror Telescope. Its neutral hydrogen column density N {sub HI} = 10{sup 21.8{+-}0.2} cm{sup -2} is among the highest values measured in quasar DLAs. The measured metal column density is N {sub ZnII} Almost-Equal-To 10{sup 13.8} cm{sup -2}, which is about 1.5 times larger than the largest value in any previously observed quasar DLAs. We derive the extinction curve of the dusty DLA using a new technique, which is an analog of the 'pair method' widely used to measure extinction curves in the Milky Way (MW). The best-fit curve is an MW-like law with a significant broad feature centered around 2175 A in the rest frame of the absorber. The measured extinction A{sub V} Almost-Equal-To 0.92 mag is unprecedentedly high in quasar DLAs. After applying an extinction correction, the i-band absolute magnitude of the quasar is as high as M{sub i} Almost-Equal-To -29.4 mag, placing it as one of the most luminous quasars ever known. The large gas-phase relative abundance of [Zn/Fe] Almost-Equal-To 1.0 indicates that metals are heavily depleted onto dust grains in the absorber. The dust depletion level is between that of the warm and cool clouds in the MW. This discovery is suggestive of the existence of a rare yet important population of dust-rich DLAs with both high metallicities and high column densities, which may have significant impact on the measurement of the cosmic evolution of neutral gas mass density and metallicity.

  14. Determination of Geo-Environmental Factors and Source of Heavy Metals in Street Dust, Masjed-e- Soleiman City, Khouzestan Province

    Directory of Open Access Journals (Sweden)

    Z Javidaneh

    2016-09-01

    Full Text Available Background and Objectives: Street dust reflects one of the most important indicators of pollution in the urban environment. Most studies carried out in the world on heavy metal pollution are related to cities and metropolitans, while less attention has been paid to towns. Masjed-e- Soleiman, the most oil-rich town is located in the north eastern part of Khuzestan Province in Iran. This town contains geogenic pollutants such as gas and oil sources, oil and gas activities, oil and gas combustion, industries, and heavy traffic, which make it important from the viewpoint of environmental impact assessment. Materials and Methods: For monitoring and management of pollution, 11 samples of street dust were collected and prepared from different stations within the town during the dry season (June 2013. Each sample was analyzed using ICP-OES instrument. Results: Possible sources of the heavy metals were identified by multivariate analyses such as Principal Component Analysis (PCA and Cluster Analysis (CA. In addition, factors such as the Index of Geo-accumulation (Igeo, Pollution Index (PI, Integration Pollution Index (IPI, and Enrichment Factor (EF were assessed to determine the degree of heavy metals pollution in street dust of the Masjed-e- Soleiman Town. The results of PCA and CA indicated that the region is mostly affected by oil pollution (both natural and combustion of fossil fuels, traffic, and industrial activities (PI revealed high levels of Pb, Cd, Cu, and Zn pollution in samples and the average level of Ni, As, and V pollution in other samples. Igeo indicated the moderate to severe pollution of some samples to Pb, Cd, Cu, and Zn while no to moderate pollution against Ni, As, and V in other samples. EF for Pb, Cd, Cu, and Zn showed a significant pollution in some samples and other samples represented the least pollution against Ni, As, and V. Conclusion: Results showed that the concentrations of heavy metals in dust samples were higher than

  15. Determination of heavy metals and their speciation in street dusts by inductively coupled plasma-optical emission spectrometry after a Community Bureau of Reference sequential extraction procedure.

    Science.gov (United States)

    Altundag, Huseyin; Imamoglu, Mustafa; Doganci, Secil; Baysal, Erkan; Albayrak, Sinem; Tuzen, Mustafa

    2013-01-01

    Sequential selective extraction techniques are commonly used to fractionate the solid-phase forms of metals in soils. This procedure provides measurements of extractable metals from media, such as acetic acid (0.11 M), hydroxyl ammonium chloride (0.1 M), hydrogen peroxide (8.8 M) plus ammonium acetate (1 M), and aqua regia stages of the sequential extraction procedure. In this work, the extractable Pb, Cu, Mn, Sr, Ni, V, Fe, Zn, and Cr were evaluated in street dust samples from Sakarya, Turkey, between May and October 2009 using the three-step sequential extraction procedure described by the Community Bureau of Reference (BCR, now the Standards, Measurements, and Testing Programme) of the European Union. The sampling sites were divided into 10 categories; a total of 50 street dusts were analyzed. The determination of multielements in the samples was performed by inductively coupled plasma-optical emission spectrometry. Validation of the proposed method was performed using BCR 701 certified reference material. The results showed good agreement between the obtained and the certified values for the metals analyzed.

  16. Source apportionment and spatial-temporal variations in the metal content of surface dust collected from an industrial area adjoining Delhi, India.

    Science.gov (United States)

    Pathak, Aditya Kumar; Yadav, Sudesh; Kumar, Pawan; Kumar, Rakesh

    2013-01-15

    Surface dust collected during three different seasons from Faridabad industrial area adjoining Delhi is studied for different metals, their spatial and temporal variations, and sources. Al, Fe, Mn, Ti, Ca and Mg show limited variations and lower abundances compared to Upper Continental Crust (UCC); Fe shows enrichment and seasonal changes. Cd, V, Co, Ba, Ti, Ni, Cu, Cr and Zn show significant spatial and temporal variations, and enrichments compared to UCC indicate their anthropogenic sources. Seasonal variability could be due to: 1) different types of industries, 2) variations in the emissions, 3) very frequent shifting of small scale industry within the region, and 4) changes in the land use pattern. The sampling sites, according to the geo-accumulation index, are: 1) least polluted for Ca, Mg, Al and Ti except for Ti in winter, 2) least to moderately polluted for Ba, Co and V but season specific, and 3) moderately to extremely polluted for other metals. Average pollution load index of 2.67-2.87 indicates consistently high level of pollution at all sites in all sampling seasons. The sites located in the residential areas near small to medium scale unorganized industry are more polluted compared to sites near large industries suggesting that the small scale unorganized industries causes more pollution. Three dominant sources of metals were identified: 1) mixed industrial, 2) crustal, and 3) vehicular, oil and battery related burnings. The third component related to Ba, Pb, Cd, Zn and Cr, further splits into two components in the pre-monsoon and winter samples. Surface dust, enriched in metals, is likely to cause serious danger to public health. There is an urgent need to make a shift from unorganized to formally organized industry to reduce the metal pollution and protect human health and environment as a whole.

  17. Research Progress on the Pollution Characteristics of Heavy Metal in Urban Dust%城市积尘重金属污染特征研究进展∗

    Institute of Scientific and Technical Information of China (English)

    孟久灵; 周飞; 陈棉彪; 房平; 张丽娟; 黄楚珊; 王小娇; 胡国成

    2016-01-01

    Urban dust is more than the sink of emissions of urban areas pollutants, and the secondary pollution lead to atmosphere, water and sediment of urban areas and its surrounding, so the dust is closely related to human health and the environmental quality. An overview of research progress on the pollution characteristics of heavy metal in urban dust in domestic and abroad was generalized, mainly including sources and analysis methods of heavy metals in urban dust, the damage of heavy metals in urban dust to the environment, exposure characteristics of heavy metals in urban dust. Finally it was proposed to unify chemical speciation analysis method of heavy metals in urban dust, formulate the method of ecological risk assessment of urban dust heavy metal pollution, combine the research of urban dust with other environmental media, analyze quantitatively of the source of heavy metal of urban dust, etc.%城市积尘是城市地区多个污染源排放的污染物聚集的汇,又是引起城市地区及周边大气、水体和沉积物的二次污染源,因此积尘与人类健康、环境质量密切相关。综述了国内外关于城市积尘中重金属污染特征的研究进展,内容主要包括城市积尘重金属来源及分析;城市积尘重金属的环境危害;城市积尘重金属的暴露特征。最后提出了要统一积尘重金属化学形态分析法、制定适合评价城市积尘重金属污染生态风险的方法、将城市积尘的研究与其他环境介质相结合起来、定量分析积尘重金属的来源等的展望。

  18. Characterization of heavy metals and brominated flame retardants in the indoor and outdoor dust of e-waste workshops: implication for on-site human exposure.

    Science.gov (United States)

    Xu, Feng; Liu, Yangcheng; Wang, Junxia; Zhang, Gang; Zhang, Wei; Liu, Lili; Wang, Jinfu; Pan, Bishu; Lin, Kuangfei

    2015-04-01

    Forty-four indoor and outdoor dust samples were collected from e-waste workshops and were analyzed to characterize the heavy metals and brominated flame retardants (BFRs) as well as on-site human exposure. The results showed that the most abundant Polybrominated diphenyl ethers (PBDE) congener from three sites was deca-BDE, and it was penta-BDE for the other site. A significant and positive association was found between BDE-209 and decabromodiphenyl ethane (DBDPE). The high percentage of nona-BDE indicated the debromination of deca-BDE during e-waste recycling. The ratio comparison of BDE-47 to (BDE-100 + BDE-99) indicated that the outdoor dust went through more physiochemical processes. The enrichment factors for Cu and Pb were high in both the indoor and outdoor samples. Cd significantly exceeded the Chinese soil guideline grade III. The PCA results combined with the enrichment factor (EF) values suggested common sources and behaviours of Cu, Pb and Sb in the indoor dust. Co, Cr, Ni, Zn and Mn in the outdoor samples were more likely affected by crust. Strong correlations were found only for Pb and Sb with polybrominated diphenyl ethers (PBDEs). The hazard index for on-site human exposure to Pb was at a chronic risk. Despite the low deleterious risk of BFRs, concern should be given to DBDPE; the chronic toxicity of which is not known.

  19. Metal Exposure and Associated Health Risk to Human Beings by Street Dust in a Heavily Industrialized City of Hunan Province, Central China

    Directory of Open Access Journals (Sweden)

    Guangyi Sun

    2017-03-01

    Full Text Available Fifty-five urban street dust samples were collected from Zhuzhou, an industrial city in central China and analyzed for a range of toxic elements. Potential carcinogenic and non-carcinogenic health effects on children and adults due to exposure to street dust were assessed. Concerning the two subgroups, the child cohort is confronted with considerably greater health risks than adults. According to the Hazard Quotient (HQ method, ingestion of dust particles poses primary risk to children and adults, followed by dermal contact and inhalation for all of the metals investigated except Hg, for which inhalation of its elemental vapor constitute a slightly higher risk than ingestion. For children, Pb, As, Cd, Cr, Hg and Sb exposure were deemed as the highest contributors to non-cancer health risks, while As and Cr represent an enhanced cancer risk for children. For adults, risk indicator values for both cancer and non-cancer effects obtained were within the safety threshold. In a comparison with other locations within and outside mainland China, exposure to arsenic is prominent for the population of Zhuzhou, indicating more attention and preventive actions should been taken.

  20. Investigating relationships between biomarkers of exposure and environmental copper and manganese levels in house dusts from a Portuguese industrial city.

    Science.gov (United States)

    Reis, A P; Costa, S; Santos, I; Patinha, C; Noack, Y; Wragg, J; Cave, M; Sousa, A J

    2015-08-01

    This study reports on data obtained from a pilot survey focusing on house dust and toenail metal(loids) concentrations in residents living in the industrial city of Estarreja. The study design hereby described aims at investigating relationships between human toenails and both copper and manganese levels in settled house dusts. A total of 21 households and 30 individuals were recruited for the pilot study: 19 households corresponding to 27 residents living near the industrial complex, forming the exposed group, plus 2 households and 3 residents from residential areas with no anticipated environmental contaminants that were used for comparison. Factorial analysis was used for source identification purposes. Investigation on the potential influence of environmental factors over copper and manganese levels in the toenails was carried out via questionnaire data and multiple correspondence analysis. The results show that copper concentrations are more elevated in the indoor dusts, while manganese concentrations are more elevated in the outdoor dust samples. The geometrical relationships in the datasets suggest that the backyard soil is a probable source of manganese to the indoor dust. Copper and manganese contents in the toenail clippings are more elevated in children than in adults, but the difference between the two age groups is not statistically significant (p > 0.05). Investigation of environmental factors influencing the exposure-biomarker association indicates a probable relationship between manganese contents in indoor dust and manganese levels in toenail clippings, a result that is partially supported by the bioaccessibility estimates. However, for copper, no relationship was found between indoor dusts and the biomarkers of exposure.

  1. Organic compounds in the urban dusts in Celje area

    OpenAIRE

    Gorazd Žibret

    2013-01-01

    This paper presents the results of the analysis of organic chemicals in different urban dusts. The aim of the researchis preliminary evaluation of the presence of organic contaminants in household dust, attic dust and streetsediment. Celje area has been chosen as a pilot study site due to availability of sampling materials from previoussampling campaigns. Samples have been tested to the presence of 120 organic compounds. Attic dust contains 98different organic compounds or 82 % of all measure...

  2. Polycyclic Aromatic Hydrocarbons in Residential Dust: Sources of Variability

    OpenAIRE

    Whitehead, Todd P; Metayer, Catherine; Petreas, Myrto; Does, Monique; Buffler, Patricia A.; Rappaport, Stephen M.

    2013-01-01

    Background: There is interest in using residential dust to estimate human exposure to environmental contaminants. Objectives: We aimed to characterize the sources of variability for polycyclic aromatic hydrocarbons (PAHs) in residential dust and provide guidance for investigators who plan to use residential dust to assess exposure to PAHs. Methods: We collected repeat dust samples from 293 households in the Northern California Childhood Leukemia Study during two sampling rounds (from 2001 thr...

  3. 浙江省城市灰尘重金属分布%Distribution of Heavy Metals Within Znejiang Province for Urban Dust

    Institute of Scientific and Technical Information of China (English)

    陈莉; 李凤全; 叶玮; 王天阳; 朱丽东

    2012-01-01

    根据浙江省11个地级市城市灰尘数据,分析灰尘重金属Pb,Cu,Zn,Ni,Cr,Co在省域尺度上的分布规律。结果显示,浙江省灰尘重金属含量整体表现为西北低、东南高,西南低、东北高,由内地向沿海市区升高。各地市均表现出明显不同的变化特征和累积量,舟山市具有较强的灰尘重金属累积和较低的空间变异;杭州市灰尘重金属的累积和变异程度都较高;温州、嘉兴、宁波等沿海市区灰尘重金属富集明显,但空间变异性低;金华市灰尘重金属变异程度相当,但Pb,Zn,Cu累积明显;台州、绍兴的Ni,Cr累积量低,但变异程度高;衢州Cu,Zn的累积和Cr,Co的变异高;湖州、丽水灰尘重金属的累积和变异程度都较低。灰尘重金属在省域上累积程度是Cu〉Zn〉Pb〉Cr〉Co〉Ni,变异较强的是Pb、Zn、Cu,较弱的是Co、Cr,而Ni的累积程度和空间变异都较低。研究发现人类活动是浙江省灰尘重金属输入的绝对重要影响因素,地形特征、地表径流和盛行风对城市灰尘重金属的迁移、扩散和稀释也具有重要作用。%According to the dust date coming from 11 cities in Zhejiang,Pb,Cu,Zn,Ni,Cr,Co distribution and characteristic on provincial scale were analyzed.The results showed that: For heavy metal content,the southeast and northeast were high,northwest and southwest were low,meanwhile the content increased from the mainland to the coastal cities gradually.Cities reflected different variations and accumulation.Zhoushan had a high heavy metal accumulation and low spatial variability.The accumulation and spatial variability of heavy metals in Hangzhou were high.Coastal cities for Wenzhou,Jiaxing and Ningbo expressed strong accumulation and weak variability.Jinhua was in the position of moderate variation,but Pb,Zn,Cu accumulation were significantly.Ni,Cr in Taizhou and Shaoxing showed a low accumulation and a high spatial variability.Quzhou had high accumulation of

  4. Assessment of mobility and bio-availability of heavy metals in dry depositions of Asian dust and implications for environmental risk.

    Science.gov (United States)

    Lee, Pyeong-Koo; Choi, Byoung-Young; Kang, Min-Ju

    2015-01-01

    We assess the potential mobility and bio-availability of selected metals (As, Cd, Co, Cr, Cu, Ni, Mo, Pb, S, Zn, and Zr) in the dry depositions of Asian and non-Asian dust from the city of Daejeon, Korea. For this study, we applied Pb isotopes, total extraction and chemical sequential extraction methods to the dry depositions. In addition, microscopic analysis was performed using X-ray diffraction (XRD) and focused ion beam (FIB)-scanning electron microscopy (SEM-EDS). FIB-SEM cross-section observations and Pb isotope data showed a black carbon is an important carrier of associated heavy metals originating from China. A five-step sequential extraction performed on the dry depositions showed that S and Cd are the most abundant elements in the water-soluble and cation-exchangeable fraction. In addition, Zn and Pb appeared predominantly in the carbonate and reducible fractions. On the other hand, Cu, Mo and, to a lesser degree, As were significantly associated with the organic fraction, while Co, Ni, Cr and Zr were bound to the residual fraction. These results showed that S, Cd, Zn and Pb, which were highly concentrated in potentially mobile fractions, have potential environmental risk because potential changes in redox state and pH may remobilize these metals. In addition, the estimated remobilization concentrations of these metals were significant. Thus, this study shows that frequent and careful monitoring of S, Cd, Z, Pb and, to a lesser degree, Cu, Mo and As is very important for assessing environmental risk in Korea. Copyright © 2014 Elsevier Ltd. All rights reserved.

  5. Dust Versus Cosmic Acceleration

    CERN Document Server

    Aguirre, A N

    1999-01-01

    Two groups have recently discovered a statistically significant deviation in the fluxes of high-redshift type Ia supernovae from the predictions of a Friedmann model with zero cosmological constant. This letter argues that bright, dusty, starburst galaxies would preferentially eject a dust component with a shallower opacity curve (hence less reddening) and a higher opacity/mass than the observed galactic dust which is left behind. Such dust could cause the falloff in flux at high-z without violating constraints on reddening or metallicity. The specific model presented is of needle-like dust, which is expected from the theory of crystal growth and has been detected in samples of interstellar dust. Carbon needles with conservative properties can supply the necessary opacity, and would very likely be ejected from galaxies as required. The model is not subject to the arguments given in the literature against grey dust, but may be constrained by future data from supernova searches done at higher redshift, in clust...

  6. Dust, Climate, and Human Health

    Science.gov (United States)

    Maynard, N. G.

    2003-12-01

    Air pollution from both natural and anthropogenic causes is considered to be one of the most serious world-wide environment-related health problems, and is expected to become worse with changes in the global climate. Dust storms from the atmospheric transport of desert soil dust that has been lifted and carried by the winds - often over significant distances - have become an increasingly important emerging air quality issue for many populations. Recent studies have shown that the dust storms can cause significant health impacts from the dust itself as well as the accompanying pollutants, pesticides, metals, salt, plant debris, and other inorganic and organic materials, including viable microorganisms (bacteria, viruses and fungi). For example, thousands of tons of Asian desert sediments, some containing pesticides and herbicides from farming regions, are commonly transported into the Arctic during dust storm events. These chemicals have been identified in animal and human tissues among Arctic indigenous populations. Millions of tons of airborne desert dust are being tracked by satellite imagery, which clearly shows the magnitude as well as the temporal and spatial variability of dust storms across the "dust belt" regions of North Africa, the Middle East, and China. This paper summarizes the most recent findings on the effects of airborne desert dust on human health as well as potential climate influences on dust and health

  7. Inorganic analysis of dust fall and office dust in an industrial area of Jordan.

    Science.gov (United States)

    Jaradat, Qasem M; Momani, Kamal A; Jbarah, Abdel-Aziz Q; Massadeh, Adnan

    2004-10-01

    This article deals with the determination and comparison of heavy metals and water-soluble anions and cations in indoor dust and outdoor dust fall in the petroleum refinery area in Jordan. Three sampling sites were considered in the Jordanian petroleum refinery complex for the collection of dust fall and office dust samples. These samples were analyzed for water-soluble anions (F-, Cl-, Br-, NO3-, C2O4(2-), and SO4(2-)) and cations (Li+, Na+, K+, Mg2+, and Ca2+) using auto-suppressed ion chromatography. Heavy metals (Pb, Cd, Cu, Zn, Cr, Fe, and Al) were determined using flame or graphite-furnace atomic absorption. No correlations were found between heavy metal concentrations in dust fall and office dust samples, indicating different sources. High enrichment factors for heavy metals were found in dust-fall samples, except for Fe and Cr. Zinc showed the highest and cadmium the lowest flux rates.

  8. Polycyclic Aromatic Hydrocarbons in Residential Dust: Sources of Variability

    Science.gov (United States)

    Metayer, Catherine; Petreas, Myrto; Does, Monique; Buffler, Patricia A.; Rappaport, Stephen M.

    2013-01-01

    Background: There is interest in using residential dust to estimate human exposure to environmental contaminants. Objectives: We aimed to characterize the sources of variability for polycyclic aromatic hydrocarbons (PAHs) in residential dust and provide guidance for investigators who plan to use residential dust to assess exposure to PAHs. Methods: We collected repeat dust samples from 293 households in the Northern California Childhood Leukemia Study during two sampling rounds (from 2001 through 2007 and during 2010) using household vacuum cleaners, and measured 12 PAHs using gas chromatography–mass spectrometry. We used a random- and a mixed-effects model for each PAH to apportion observed variance into four components and to identify sources of variability. Results: Median concentrations for individual PAHs ranged from 10 to 190 ng/g of dust. For each PAH, total variance was apportioned into regional variability (1–9%), intraregional between-household variability (24–48%), within-household variability over time (41–57%), and within-sample analytical variability (2–33%). Regional differences in PAH dust levels were associated with estimated ambient air concentrations of PAH. Intraregional differences between households were associated with the residential construction date and the smoking habits of residents. For some PAHs, a decreasing time trend explained a modest fraction of the within-household variability; however, most of the within-household variability was unaccounted for by our mixed-effects models. Within-household differences between sampling rounds were largest when the interval between dust sample collections was at least 6 years in duration. Conclusions: Our findings indicate that it may be feasible to use residential dust for retrospective assessment of PAH exposures in studies of health effects. PMID:23461863

  9. Could Aerosol Dust Plume-derived Trace Metals and Inorganic Nutrient be Fueling the Recent Growth and Proliferation of Noctiluca scintillans Blooms in the Arabian Sea?

    Science.gov (United States)

    Tan, Y. S.; Ang, A.; Gomes, H. R.; Goes, J. I.

    2016-12-01

    Noctiluca scintillans, a species of mixotrophic dinoflagellate, has been proliferating in the Arabian Sea for the past 20 years in winter when convective mixing brings up nutrient-rich waters from deeper depths. It is believed that the unique mixotrophic nature of this organism, where it is able to feed on other phytoplankton, as well as photosynthesize by hosting a large endosymbiotic population of Pedinomonas noctilucae, gives it a greater competitive advantage over other phytoplankton. It is believed that this physiological plasticity of Noctiluca is responsible for the species shift from a diatom dominated ecosystem of the past in the Arabian sea, to the current widespread blooms of Noctiluca. Here we have attempted to examine how Noctiluca are able to sustain themselves over an extended period when nutrients from winter convective mixing are completely exhausted in the euphotic zone. In this study we test the hypotheses, that new inputs of nutrients from anthropogenic sources such as sewage and land-based nutrient runoff as well as from thick aeolian dust storms from the nearby regions such as Oman and Iran allow Noctiluca to survive and grow from winter into the spring inter-monsoon season. A recently cultured strain of Arabian Sea green Noctiluca grown in media amended with dust collected from Oman and Iran, different trace metals (Iron, Selenium and Cobalt) as well as nutrients (Nitrate, Ammonium and Urea) has been used to test our hypotheses. This is the first time such experiments have been conducted in the laboratory as previously no Noctiluca culture survived beyond 6 months. Growth of Noctiluca was measured in terms of cell count and the photosynthetic efficiency of cells using the fluorescence induction and relaxation technique which deduces the quantum efficiency of photochemistry in PSII. Moreover, we also measured the ammonia content in the cells which has long been suspected to provide buoyancy to cells and/or serve as a nitrogenous nutrient to

  10. Multi-elemental characterization of tunnel and road dusts in Houston, Texas using dynamic reaction cell-quadrupole-inductively coupled plasma-mass spectrometry: Evidence for the release of platinum group and anthropogenic metals from motor vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Spada, Nicholas; Bozlaker, Ayse [Department of Civil and Environmental Engineering, University of Houston, Houston, TX 77204-4003 (United States); Chellam, Shankararaman, E-mail: chellam@uh.edu [Department of Civil and Environmental Engineering, University of Houston, Houston, TX 77204-4003 (United States); Department of Chemical and Biomolecular Engineering, University of Houston, Houston, TX 77204-4004 (United States)

    2012-07-20

    Highlights: Black-Right-Pointing-Pointer Analytical method for PGEs, main group, transition and rare earth metals developed. Black-Right-Pointing-Pointer Comprehensive characterization of road and tunnel dust samples was accomplished. Black-Right-Pointing-Pointer PGEs in dusts arise from autocatalyst attrition. Black-Right-Pointing-Pointer Mobile sources also contributed to Cu, Zn, Ga, As, Mo, Cd, Sn, Sb, Ba, W and Pb. Black-Right-Pointing-Pointer All other elements, including rare earths arose from crustal sources. - Abstract: Platinum group elements (PGEs) including Rh, Pd, and Pt are important tracers for vehicular emissions, though their measurement is often challenging and difficult to replicate in environmental campaigns. These challenges arise from sample preparation steps required for PGE quantitation, which often cause severe isobaric interferences and spectral overlaps from polyatomic species of other anthropogenically emitted metals. Consequently, most previous road dust studies have either only quantified PGEs or included a small number of anthropogenic elements. Therefore a novel analytical method was developed to simultaneously measure PGEs, lanthanoids, transition and main group elements to comprehensively characterize the elemental composition of urban road and tunnel dusts. Dust samples collected from the vicinity of high-traffic roadways and a busy underwater tunnel restricted to single-axle (predominantly gasoline-driven) vehicles in Houston, TX were analyzed for 45 metals with the newly developed method using dynamic reaction cell-quadrupole-inductively coupled plasma-mass spectrometry (DRC-q-ICP-MS). Average Rh, Pd and Pt concentrations were 152 {+-} 52, 770 {+-} 208 and 529 {+-} 130 ng g{sup -1} respectively in tunnel dusts while they varied between 6 and 8 ng g{sup -1}, 10 and 88 ng g{sup -1} and 35 and 131 ng g{sup -1} in surface road dusts. Elemental ratios and enrichment factors demonstrated that PGEs in dusts originated from autocatalyst

  11. The advances in research on heavy metals of the surface dust in urban areas%城市地表灰尘重金属研究进展及展望

    Institute of Scientific and Technical Information of China (English)

    王济; 张一修; 高翔

    2012-01-01

    城市地表灰尘是城市环境科学研究的对象之一,在对国内外有关城市灰尘概念界定研究成果进行总结的基础上,对城市地表灰尘提出新的概念和新的认识。城市地表灰尘是城市生态环境中具有环境指示作用的地表颗粒物,是含有重金属、多环芳烃等多种污染物的源与汇。对国内外地表灰尘重金属的含量水平、时空分布特征、迁移循环、赋存形态及生物有效性等方面的研究成果进行比较系统的阐述;灰尘中重金属的来源识别的方法主要有GIS空间分析,元素示踪技术,统计学方法等。并提出在今后的研究中应进一步完善城市地表灰尘中重金属的时间变化规律、地表灰尘在环境中的滞留时间、粒径的划分以及区域人体健康影响及风险评估模型优化四个方面的研究。%Surface dust in urban areas is one of the important topics in urban environmental science.A review was given in this paper on the conceptual definition of surface dust in urban areas.The new concept and new understandings about surface dust in urban areas were put forward.Surface dust was sources and sinks of many pollutants as heavy metals and PAHs have environmental indicative function in urban areas.A review was given on the advances in the research on heavy metals of surface dust in urban areas in various aspects in this paper,such as content level,space-time distribution,transference and cycle,forms and bioavailability.The concentrations of heavy metals of surface dust in surface dust in urban areas were obviously higher than environmental background values in soil.The research on methods of spatial distribution of heavy metals were line type and face type.The concentrations of pollutants have changed over times.The main transporting medium of surface dust is atmosphere.The heavy metals in surface dust has exchangeable,carbonate combination,iron and manganese oxide combination,organic sulfide combination

  12. Reducing aluminum dust explosion hazards: case study of dust inerting in an aluminum buffing operation.

    Science.gov (United States)

    Myers, Timothy J

    2008-11-15

    Metal powders or dusts can represent significant dust explosion hazards in industry, due to their relatively low ignition energy and high explosivity. The hazard is well known in industries that produce or use aluminum powders, but is sometimes not recognized by facilities that produce aluminum dust as a byproduct of bulk aluminum processing. As demonstrated by the 2003 dust explosion at aluminum wheel manufacturer Hayes Lemmerz, facilities that process bulk metals are at risk due to dust generated during machining and finishing operations [U.S. Chemical Safety and Hazard Investigation Board, Investigation Report, Aluminum Dust Explosion Hayes Lemmerz International, Inc., Huntington, Indiana, Report No. 2004-01-I-IN, September 2005]. Previous studies have shown that aluminum dust explosions are more difficult to suppress with flame retardants or inerting agents than dust explosions fueled by other materials such as coal [A.G. Dastidar, P.R. Amyotte, J. Going, K. Chatrathi, Flammability limits of dust-minimum inerting concentrations, Proc. Saf. Progr., 18-1 (1999) 56-63]. In this paper, an inerting method is discussed to reduce the dust explosion hazard of residue created in an aluminum buffing operation as the residue is generated. This technique reduces the dust explosion hazard throughout the buffing process and within the dust collector systems making the process inherently safer. Dust explosion testing results are presented for process dusts produced during trials with varying amounts of flame retardant additives.

  13. METALLICITIES, DUST, AND MOLECULAR CONTENT OF A QSO-DAMPED Ly{alpha} SYSTEM REACHING log N(H I) = 22: AN ANALOG TO GRB-DLAs

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, R. [Programa de Modelagem Computacional-SENAI-Cimatec, 41650-010 Salvador, Bahia (Brazil); Noterdaeme, P.; Petitjean, P. [UPMC-CNRS, UMR7095, Institut d' Astrophysique de Paris, 98bis Blvd. Arago, F-75014 Paris (France); Ledoux, C. [European Southern Observatory, Alonso de Cordova 3107, Casilla 19001, Vitacura, Santiago 19 (Chile); Srianand, R.; Rahmani, H. [Inter-University Centre for Astronomy and Astrophysics, Post Bag 4, Ganeshkhind, Pune 411007 (India); Lopez, S., E-mail: rguimara@eso.org [Departamento de Astronomia, Universidad de Chile, Casilla 36-D, Santiago (Chile)

    2012-06-15

    We present the elemental abundance and H{sub 2} content measurements of a damped Ly{alpha} (DLA) system with an extremely large H I column density, log N(H I) (cm{sup -2}) = 22.0 {+-} 0.10, at z{sub abs} = 3.287 toward the QSO SDSS J081634+144612. We measure column densities of H{sub 2}, C I, C I*, Zn II, Fe II, Cr II, Ni II, and Si II from a high signal-to-noise and high spectral resolution VLT-UVES spectrum. The overall metallicity of the system is [Zn/H] = -1.10 {+-} 0.10 relative to solar. Two molecular hydrogen absorption components are seen at z = 3.28667 and 3.28742 (a velocity separation of Almost-Equal-To 52 km s{sup -1}) in rotational levels up to J = 3. We derive a total H{sub 2} column density of log N(H{sub 2}) (cm{sup -2}) = 18.66 and a mean molecular fraction of f = 2N(H{sub 2})/[2N(H{sub 2}) + N(H I)] = 10{sup -3.04{+-}0.37}, typical of known H{sub 2}-bearing DLA systems. From the observed abundance ratios we conclude that dust is present in the interstellar medium of this galaxy, with an enhanced abundance in the H{sub 2}-bearing clouds. However, the total amount of dust along the line of sight is not large and does not produce any significant reddening of the background QSO. The physical conditions in the H{sub 2}-bearing clouds are constrained directly from the column densities of H{sub 2} in different rotational levels, C I and C I*. The kinetic temperature is found to be T Almost-Equal-To 75 K and the particle density lies in the range n{sub H} = 50-80 cm{sup -3}. The neutral hydrogen column density of this DLA is similar to the mean H I column density of DLAs observed at the redshift of {gamma}-ray bursts (GRBs). We explore the relationship between GRB-DLAs and the high column density end of QSO-DLAs finding that the properties (metallicity and depletion) of DLAs with log N(H I) > 21.5 in the two populations do not appear to be significantly different.

  14. Magnetic susceptibility of dust-loaded leaves as a proxy of traffic-related heavy metal pollution in Kathmandu city, Nepal

    Science.gov (United States)

    Gautam, Pitambar; Blaha, Ulrich; Appel, Erwin

    Dust-loaded tree leaves from Kathmandu have been analyzed for magnetic susceptibility ( χ) and heavy metal (HM) contents. For 221 samples of leaves of cypress (mainly Cupressus corneyana), silky oak ( Grevillea robusta) and bottlebrush ( Callistemon lanceolatus), χ has a range of (0.01-54)×10 -8 m 3 kg -1 with a median of about 10.0×10 -8 m 3 kg -1. Trees situated close to the busy road intersections, near the main bus station and sectors of roads with steep slope yield elevated susceptibility. Chemical analysis of 20 samples of varying susceptibility by atomic absorption spectrometry yields the following maximum HM contents: Fe (1.3 wt%), Mn (281.9 ppm), Zn (195.2 ppm), Cu (41.5 ppm), Pb (38.4 ppm), Ni (8.1 ppm), Cr (6.4 ppm), Co (4.1 ppm) and Cd (1.2 ppm). The logarithmic susceptibility on dry mass basis ( χ) shows significant linear relationship with HM contents: Pearson's correlation coefficient r>0.8 with Zn, Fe, Cr; r>0.7 with Mn, Cu; r>0.6 with Pb, Ni. Magnetic phases are of soft (magnetite/maghemite) and hard (hematite) coercivities. Microscopy of magnetic extracts reveals spherules (mostly of 2-20 μm diameter) originated from vehicle exhausts through the combustion process as well as crystalline grains of lithogenic origin. The dust accumulation in leaves took place mainly after monsoon (beginning of October 2001) till the sampling period (first half of February 2002). Despite the dependence of susceptibility and HM contents on a variety of spatial and temporal factors (amount of particulate matter (PM), efficiency of deposition/removal of PM by wind, precipitation, birds etc.), a significant correlation of susceptibility to HM implies that the former serves as an effective proxy of metallic pollution. Hence, susceptibility-based bio-monitoring technique is recommended as an economic and rapid tool for assessment of environmental pollution in urban areas like Kathmandu.

  15. Exploring the overabundance of ultraluminous X-ray sources in metal- and dust-poor local Lyman break analogs

    Science.gov (United States)

    Basu-Zych, Antara; Lehmer, Bret; Fragos, Tassos; Hornschemeier, Ann E.; Zezas, Andreas; Yukita, Mihoko; Ptak, Andrew

    2016-01-01

    We have studied high mass X-ray binary (HMXB) populations within two low-metallicity, starburst galaxies, Haro 11 and VV 114. These galaxies serve as analogs to high-redshift (z > 2) Lyman break galaxies, and within the larger sample of Lyman break analogs (LBAs) are sufficiently nearby (1039 erg s-1 ultraluminous X-ray sources, ULXs) in these low-metallicity galaxies, based on 8 detected ULXs. Comparing with the star-forming galaxy X-ray luminosity function (XLF), Haro 11 and VV 114 host ~4 times more LX>1040 erg s-1 sources than expected given their SFRs. We simulate the effects of source blending from crowded lower luminosity HMXBs using the star-forming galaxy XLF and then vary the XLF normalizations and bright-end slopes until we reproduce the observed point source luminosity distributions. Based on this analysis, we find that these LBAs have a shallower bright end slope than the standard XLF.

  16. Allergies, asthma, and dust

    Science.gov (United States)

    Reactive airway disease - dust; Bronchial asthma - dust; Triggers - dust ... Things that make allergies or asthma worse are called triggers. Dust is a common trigger. When your asthma or allergies become worse due to dust, you are ...

  17. Bioaccessibility of Fipronil Sorbed to Soil and House Dust

    Science.gov (United States)

    Fipronil is a phenylpyrazole insecticide with uses ranging from soil treatment, to the control of household pests and ectoparasites on pets. Soils and house dusts readily sorb fipronil and when these soils and dusts are ingested, the fipronil may become bioaccessible for uptake ...

  18. Bioaccessibility of Fipronil Sorbed to Soil and House Dust

    Science.gov (United States)

    Fipronil is a phenylpyrazole insecticide with uses ranging from soil treatment, to the control of household pests and ectoparasites on pets. Soils and house dusts readily sorb fipronil and when these soils and dusts are ingested, the fipronil may become bioaccessible for uptake ...

  19. Seasonal concentrations, contamination levels, and health risk assessment of arsenic and heavy metals in the suspended particulate matter from an urban household environment in a metropolitan city, Beijing, China.

    Science.gov (United States)

    Yang, Y Y; Liu, L Y; Guo, L L; Lv, Y L; Zhang, G M; Lei, J; Liu, W T; Xiong, Y Y; Wen, H M

    2015-07-01

    The levels and health risks of arsenic and heavy metals (As, Ba, Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn) in the suspended particulate matter (SPM) collected from an urban household environment in Beijing of China for 12 months were investigated. The mean concentrations of the studied toxic elements were higher and lower than crustal abundance and PM2.5 in the urban outdoors of Beijing. The concentrations of the studied elements displayed significant seasonality. The highest concentrations of the total elements occurred in winter, followed by autumn, while the lowest concentrations were recorded in summer. Based on the calculated values of enrichment factor (EF) and geoaccumulation index (Igeo), the levels for As and Cu were heavily contaminated, while those for Cd, Pb, and Zn were extremely contaminated. As and Pb might pose risks to children and adults via ingestion exposure. The accumulative risks of multi-elements resulted from dermal contact and inhalation exposures were not negligible. More attention should be paid to reducing the non-carcinogenic and carcinogenic health risks posed by the toxic elements bound to urban household SPM particles via ingestion, inhalation, and dermal contact exposure.

  20. Factors affecting lead and cadmium levels in house dust in industrial areas of eastern Germany.

    Science.gov (United States)

    Meyer, I; Heinrich, J; Lippold, U

    1999-08-30

    The indoor exposure of 381 women (52-59 years old) to lead and cadmium was assessed by measuring the levels of the contaminants in sedimented house dust. The study was conducted in the areas surrounding the towns of Hettstedt, a region of mining and smelting of non-ferrous ores, of Bitterfeld, a centre of chemical production and coal mining, and of Zerbst, a primarily agricultural area. Factors that were significantly associated with lead and cadmium surface loading rates included the city area of residence, urban environment of dwelling, ventilation behaviour, type of heating, year of construction of building and crowding in the sampling room. In metal-contaminated areas, the transport of heavy metals into the home from external sources and their subsequent resuspension into the air due to normal household activities are significant factors in the exposure to heavy metals, whereas in unpolluted areas indoor sources play the major role.

  1. Metallicities, dust and molecular content of a QSO-Damped Lyman-{\\alpha} system reaching log N (H i) = 22: An analog to GRB-DLAs

    CERN Document Server

    Guimarães, R; Petitjean, P; Ledoux, C; Srianand, R; Lopez, S; Rahmani, H

    2012-01-01

    We present the elemental abundance and H2 content measurements of a Damped Lyman-{\\alpha} (DLA) system with an extremely large H i column density, log N(H i) (cm-2) = 22.0+/-0.10, at zabs = 3.287 towards the QSO SDSS J 081634+144612. We measure column densities of H2, C i, C i^*, Zn ii, Fe ii, Cr ii, Ni ii and Si ii from a high signal-to-noise and high spectral resolution VLT-UVES spectrum. The overall metallicity of the system is [Zn/H] = -1.10 +/- 0.10 relative to solar. Two molecular hydrogen absorption components are seen at z = 3.28667 and 3.28742 (a velocity separation of \\approx 52 km s-1) in rotational levels up to J = 3. We derive a total H2 column density of log N(H2) (cm-2) = 18.66 and a mean molecular fraction of f = 2N(H2)/[2N(H2) + N(H i)] = 10-3.04+/-0.37, typical of known H2-bearing DLA systems. From the observed abundance ratios we conclude that dust is present in the Interstellar Medium (ISM) of this galaxy, with a enhanced abundance in the H2-bearing clouds. However, the total amount of dus...

  2. 金属丝棉结构在电焊烟尘处理中的过滤性能研究%Research on Filtering Properties of Metal Cotton Structure in Treatment of Welding Smoke and Dust

    Institute of Scientific and Technical Information of China (English)

    杨利芳; 范怀良

    2011-01-01

    The wedding smoke and dust is extremely harmful to human, it must be treated before letting out into the environment.However the amount of welding smoke and dust is very large and makes the filter efficiency much lower, which causes much restriction to the small mobile dust leaner.For making a better use of the mobile dust cleaner, researching high efficient filtering material becomes very necessary.By studying the relationship among collection efficiency, pressure loss, remnant pressure drop and other factors, the filter properties of metal cotton were obtained, and a special filtering structure of metal cotton was designed.The application of the metal cotton filtering structure in welding smoke and dust cleaner shows that the desired dust-removal result can be obtained and many disadvantages of the existing welding dust cleaner can be overcome.%电焊烟尘对人危害极大,必须加以净化才能排放到空气中.然而电焊作业烟尘量极大,由于过滤效率低,导致小型移动式电焊除尘器应用受到限制.为了更好地利用移动式除尘器净化电焊烟尘,研究高效过滤材料变得非常重要.通过数值模拟金属丝绵的除尘效率、过滤压力损失及残余压降等影响过滤性能的因素,将金属丝绵应用于移动式除尘器.为了更好地发挥金属丝绵的过滤性能,设计特殊的过滤结构,并在电焊烟尘除尘器中应用以提高除尘器的过滤效率.结果表明,金属丝绵应用于电焊除尘器可以获得理想的除尘效果,并且可以克服很多现有电焊除尘器的缺点.

  3. Indoor metallic pollution and children exposure in a mining city

    Energy Technology Data Exchange (ETDEWEB)

    Barbieri, Enio, E-mail: enniobg@gmail.com [IRD (Institut de Recherche pour le Développement), La Paz (Bolivia, Plurinational State of); Fontúrbel, Francisco E. [Departamento de Ciencias Ecológicas, Facultad de Ciencias, Universidad de Chile, Santiago de Chile (Chile); Herbas, Cristian [Instituto IGEMA, Universidad Mayor de San Andrés, La Paz (Bolivia, Plurinational State of); Barbieri, Flavia L. [IRD (Institut de Recherche pour le Développement), La Paz (Bolivia, Plurinational State of); Universidad Mayor de San Andrés, SELADIS (Instituto de Servicios de Laboratorio para el Diagnóstico e Investigación en Salud), La Paz (Bolivia, Plurinational State of); Berlin School of Public Health, Charité Universitätsmedizin, Berlin (Germany); Gardon, Jacques [IRD (Institut de Recherche pour le Développement), La Paz (Bolivia, Plurinational State of); Universidad Mayor de San Andrés, SELADIS (Instituto de Servicios de Laboratorio para el Diagnóstico e Investigación en Salud), La Paz (Bolivia, Plurinational State of); IRD, HSM, Montpellier (France)

    2014-07-01

    Mining industries are known for causing strong environmental contamination. In most developing countries, the management of mining wastes is not adequate, usually contaminating soil, water and air. This situation is a source of concern for human settlements located near mining centers, especially for vulnerable populations such as children. The aim of this study was to assess the correlations of the metallic concentrations between household dust and children hair, comparing these associations in two different contamination contexts: a mining district and a suburban non-mining area. We collected 113 hair samples from children between 7 and 12 years of age in elementary schools in the mining city of Oruro, Bolivia. We collected 97 indoor dust samples from their households, as well as information about the children's behavior. Analyses of hair and dust samples were conducted to measure As, Cd, Pb, Sb, Sn, Cu and Zn contents. In the mining district, there were significant correlations between non-essential metallic elements (As, Cd, Pb, Sb and Sn) in dust and hair, but not for essential elements (Cu and Zn), which remained after adjusting for children habits. Children who played with dirt had higher dust-hair correlations for Pb, Sb, and Cu (P = 0.006; 0.022 and 0.001 respectively) and children who put hands or toys in their mouths had higher dust-hair correlations of Cd (P = 0.011). On the contrary, in the suburban area, no significant correlations were found between metallic elements in dust and children hair and neither children behavior nor gender modified this lack of associations. Our results suggest that, in a context of high metallic contamination, indoor dust becomes an important exposure pathway for children, modulated by their playing behavior. - Highlights: • Mining activities are an important source of environmental pollution. • Mining pollution contaminated also indoor homes, creating a risk to population. • Indoor dust and hair concentrations

  4. Household food waste

    NARCIS (Netherlands)

    Wahlen, S.; Winkel, Thomas

    2017-01-01

    Food waste is debated not only in the light of sustainable consumption in research and policy, but also in the broader public. This article focuses on food waste in household contexts, what is widely believed the end of the food chain. However, household food waste is far more complex and intricate

  5. Household financial behavior

    NARCIS (Netherlands)

    Brounen, Dirk; Koedijk, Kees; Pownall, Rachel

    2016-01-01

    Greater personal responsibility toward financial decision-making is being advocated on a global basis. Individuals and households are encouraged to take a more active approach to personal finance. In this paper, we examine behavioral factors, which lead households toward savings and financial planni

  6. Household financial behavior

    NARCIS (Netherlands)

    Brounen, Dirk; Koedijk, Kees; Pownall, Rachel

    2016-01-01

    Greater personal responsibility toward financial decision-making is being advocated on a global basis. Individuals and households are encouraged to take a more active approach to personal finance. In this paper, we examine behavioral factors, which lead households toward savings and financial

  7. Households' portfolio choices

    NARCIS (Netherlands)

    Hochgürtel, S.

    1998-01-01

    This thesis presents four topics on households' portfolio choices. Empirically, households do not hold well-diversified wealth portfolios. In particular, they refrain from putting their savings into risky assets. We explore several ways that might help explaining this observation. Using Dutch

  8. Essays in household finance

    NARCIS (Netherlands)

    Djordjevic, Ljubica

    2015-01-01

    Household finance is a young and vibrant research field that continuously attracts public attention. There may be very few matters that people care so much about as their personal finance. Recent rise of academic interest in household finance is to a great extent due to households’ more active role

  9. Household electricity demand profiles

    DEFF Research Database (Denmark)

    Marszal, Anna Joanna; Heiselberg, Per Kvols; Larsen, Olena Kalyanova

    2016-01-01

    Highlights •A 1-min resolution household electricity load model is presented. •Model adapts a bottom-up approach with single appliance as the main building block. •Load profiles are used to analyse the flexibility potential of household appliances. •Load profiles can be applied in other domains, e...

  10. Pollution and potential ecological risk of heavy metals in surface dust on urban kindergartens%某城市幼儿园地表灰尘重金属污染及潜在生态风险

    Institute of Scientific and Technical Information of China (English)

    马建华; 王晓云; 侯千; 段海静

    2011-01-01

    选取河南省某市31个幼儿园采集地表灰尘样品,用火焰原子吸收分光光度法测定其Zn、Pb、Cr、Cu和Ni含量,应用地积累指数法和潜在生态风险指数法探讨了灰尘重金属的污染特征和潜在生态风险.结果表明:城区幼儿园灰尘Zn、Pb、Cr、Cu和Ni的平均含量分别是郊区对照幼儿园的1.93、2.13、5.45、1.90和0.98倍;Pb、Zn、Cr和Cu属于人为源重金属,Ni属于混合源重金属.灰尘Pb污染比较严重,Ni和Zn多为轻污染或偏中污染,Cu和Cr污染较轻.所有幼儿园的灰尘重金属潜在生态总风险均在强烈风险以上,Pb对生态总风险的平均贡献率达70.34%,是最主要的风险因子.潜在生态总风险指数(RJ)的分级标准必须根据所研究的污染物数目及其毒性响应系数大小进行调整.%Many studies have been undertaken on heavy metal pollution of surface dust or street dust in many cities, but very few studies have been done on the pollution and potential ecological risk of kindergarten dust. Thirty-one surface dust samples were collected from kindergartens in one of cities located in the east of Henan Province, China. Concentrations of Ph, Zn, Cr, Cu and Ni in the samples were determined using F-AAS (flame atomic absorption spectrophotometry). Pollution and potential ecological risk of heavy metals in the samples were discussed with geoaccmulation index (Igo) and potential ecological risk index (RI) respectively. The results show that average concentrations of Zn, Pb, Cr, Cu and Ni in kindergarten dust in urban area of the city are 311.84, 256.15, 89.17, 52.47 and 40. 79 mg/kg respectively, and 1.93, 2. 13, 5.45, 1.90 and 0.98 times of the control samples respectively. The heavy metals can be classified into two groups: anthropogenic source metals and mixed source metals. The first group of metals, Pb, Zn, Cr and Cu, is mainly derived from urban industries, traffic, domestic wastes, religion activities etc; while the second group, Ni

  11. Hazardous household waste management in Vinnytsia region

    OpenAIRE

    Ishchenko, Vitalii; Petruk, Roman; Kozak, Yana

    2016-01-01

    The article analyzes hazardous household waste, including detergents, paints, adhesives, expired medicines, luminescent lamps, pesticides, fertilizers, batteries and accumulators, electrical and electronic waste, mercury-containing materials. Research shows that they contain a large quantity of dangerous and toxic substances (compounds of heavy metals, chlorinated polymers, aromatic hydrocarbons, surfactants, etc.), which pose a significant risk to the environment and ...

  12. Migration and Transformation of Heavy Metals in Street Dusts with Different Particle Sizes During Urban Runoff%不同粒径地表街尘中重金属在径流冲刷中的迁移转化

    Institute of Scientific and Technical Information of China (English)

    何小艳; 赵洪涛; 李叙勇; 连宾; 王小梅

    2012-01-01

    在我国快速城市化进程中,街尘及其径流冲刷引起的重金属污染日显突出.通过对北京市城乡道路街尘及其人工降雨模拟径流冲刷过程中不同粒径街尘中重金属的分析,探讨街尘与径流冲刷过程中的粒径效应及不同重金属赋存形态的动态变化规律.结果表明,同一粒径颗粒物从"静态"街尘到"动态"径流中的颗粒物,重金属浓度呈下降趋势.街尘中重金属在径流冲刷过程中,存在溶解与解析现象,颗粒物粒径越小,减少比率越大,5种重金属(Cr、Cu、Ni、Pb、Zn)的减少比率分别为24.3%、56.8%、34.3%、22.8%、27.3%.街尘中的弱酸可提取态比例要略大于径流颗粒物中弱酸可提取态比例,部分以水溶态进入水体中.在径流冲刷过程中,水相溶解态重金属变化不大,水相颗粒态重金属含量随降雨时间径流过程迅速降低.固相颗粒物的重金属浓度随降雨时间总体上呈下降趋势.粒径越小,冲刷率越大,最大为62.1%,最小为4.6%.地表街尘在径流冲刷过程中,小粒径颗粒物具有较强的迁移能力,较容易进入水体造成污染.%The heavy metal pollution in runoff caused by street dust washoff has been an increasingly prominent problem in the context of rapid urbanization in China.Based on measurement of heavy metal contents in street dusts with different particle sizes and an experiment of street dust washoff using simulated rainfall,we analyzed the role of particle size of street dust in heavy metal pollution,and the variation in geometrical forms of heavy metals during street dust washoff.Our results showed that the heavy metal concentration decreased from "static" street dust to "dynamic" runoff particulate in the same diameter particles.Heavy metals in street dust were dissolved and extracted during washoff.The average loss proportion of the five metals(Cr,Cu,Ni,Pb,Zn) were 24.3%,56.8%,34.3%,22.8%,27.3%,respectively.The loss

  13. Radon in indoor concentrations and indoor concentrations of metal dust particles in museums and other public buildings.

    Science.gov (United States)

    Carneiro, G L; Braz, D; de Jesus, E F; Santos, S M; Cardoso, K; Hecht, A A; Dias da Cunha, Moore K

    2013-06-01

    The aim of this study was to evaluate the public and occupational exposure to radon and metal-bearing particles in museums and public buildings located in the city of Rio de Janeiro, Brazil. For this study, four buildings were selected: two historic buildings, which currently house an art gallery and an art museum; and two modern buildings, a chapel and a club. Integrated radon concentration measurements were performed using passive radon detectors with solid state nuclear track detector-type Lexan used as nuclear track detector. Air samplers with a cyclone were used to collect the airborne particle samples that were analyzed by the particle-induced X-ray emission technique. The average unattached-radon concentrations in indoor air in the buildings were above 40 Bq/m(3), with the exception of Building D as measured in 2009. The average radon concentrations in indoor air in the four buildings in 2009 were below the recommended reference level by World Health Organization (100 Bq/m(3)); however, in 2011, the average concentrations of radon in Buildings A and C were above this level, though lower than 300 Bq/m(3). The average concentrations of unattached radon were lower than 148 Bq/m(3) (4pCi/L), the USEPA level recommended to take action to reduce the concentrations of radon in indoor air. The unattached-radon average concentrations were also lower than the value recommended by the European Union for new houses. As the unattached-radon concentrations were below the international level recommended to take action to reduce the radon concentration in air, it was concluded that during the period of sampling, there was low risk to human health due to the inhalation of unattached radon in these four buildings.

  14. A lunar dust simulant: CLDS-i

    Science.gov (United States)

    Tang, Hong; Li, Xiongyao; Zhang, Sensen; Wang, Shijie; Liu, Jianzhong; Li, Shijie; Li, Yang; Wu, Yanxue

    2017-02-01

    Lunar dust can make serious damage to the spacecrafts, space suits, and health of astronauts, which is one of the most important problems faced in lunar exploration. In the case of rare lunar dust sample, CLDS-i with high similarity to the real lunar dust is an important objective for studying dust protection and dust toxicity. The CLDS-i developed by the Institute of Geochemistry Chinese Academy Sciences contains ∼75 vol% glass and a little nanophase metal iron (np-Fe0), and with a median particle size about 500 nm. The CLDS-i particles also have complicated shape and sharp edges. These properties are similar to those of lunar dust, and make the CLDS-i can be applied to many fields such as the scientific researches, the treatment technology and toxicological study of lunar dust.

  15. Seasonal Provincial Characteristics of Vertical Distribution of Dust Loadings and Heavy Metals near Surface in City%城市区域近地表灰尘及重金属沉降垂向季节变化

    Institute of Scientific and Technical Information of China (English)

    李晓燕; 张舒婷

    2015-01-01

    With the emergence of urban high-rise building, the vertical space of human daily life gradually extended upward. Seasonal characteristics of vertical distribution of dust loadings and heavy metals near surface are remarkable. In this study, we collected dust deposited on the windowsill at different space height (1th- 8th floor) from three buildings in Guiyang city during spring, summer, autumn and winter, and analyzed the deposition fluxes of dust and elements including Ca, Fe, Cd, Cr, Cu, Ni, Pb and Zn. The results showed that: the total changing trend of vertical distribution of dust loadings was that the deposition fluxes of dust in winter were the highest, followed by those in spring, and the deposition fluxes of dust in summer were the lowest. The degree of variation on dust loadings dependent on the change of elevation was the highest in winter, followed by that in summer, and was relatively lower in spring and autumn. The effect on dust loadings by seasonal changing was relatively heavier on windowsill on the lower level than on the higher level. The levels of elements were the highest in spring dust, while those in autumn were relatively lower. Among the 8 elements, the variability of Zn in dust related to space time variation was the most obvious, and that of Ca was weaker. The atmospheric inversion condition might be one of the reasons that improved the deposition fluxes of dust and the contents of Pb and Zn in dust during winter and spring.%随着城市高层建筑的出现,人类日常生活的垂向空间范围逐渐向上延伸,近地表灰尘及重金属沉降垂向分布的季节特征值得关注.本研究分别在春、夏、秋、冬四季采集贵阳市某生活-文教区近地表不同空间高度平台上的灰尘样品,分析灰尘沉降通量及灰尘中 Ca、 Fe、 Cd、 Cr、 Cu、 Ni、 Pb 和 Zn 含量,探讨灰尘沉降通量及元素含量随空间高度的变化,揭示区域近地表灰尘及重金属沉降垂向分布的季节变

  16. Dust Formation in Milky Way-like Galaxies

    CERN Document Server

    McKinnon, Ryan; Vogelsberger, Mark

    2015-01-01

    We introduce a dust model for cosmological simulations implemented in the moving-mesh code AREPO and present a suite of cosmological hydrodynamical zoom-in simulations to study dust formation within galactic haloes. Our model accounts for the stellar production of dust, accretion of gas-phase metals onto existing grains, destruction of dust through local supernova activity, and dust driven by winds from star-forming regions. We find that accurate stellar and active galactic nuclei feedback is needed to reproduce the observed dust-metallicity relation and that dust growth largely dominates dust destruction. Our simulations predict a dust content of the interstellar medium which is consistent with observed scaling relations at $z = 0$, including scalings between dust-to-gas ratio and metallicity, dust mass and gas mass, dust-to-gas ratio and stellar mass, and dust-to-stellar mass ratio and gas fraction. We find that roughly two-thirds of dust at $z = 0$ originated from Type II supernovae, with the contribution ...

  17. HD/H2 as a Probe of the Roles of Gas, Dust, Light, Metallicity, and Cosmic Rays in Promoting the Growth of Molecular Hydrogen in the Diffuse Interstellar Medium

    Science.gov (United States)

    Liszt, H. S.

    2015-01-01

    We modeled recent observations of UV absorption of HD and {H_2} in the Milky Way and toward damped/subdamped Lyα systems at z = 0.18 and z >1.7. N(HD)/N({H_2}) ratios reflect the separate self-shieldings of HD and {H_2} and the coupling introduced by deuteration chemistry. Locally, observations are explained by diffuse molecular gas with 16 cm-3 1.7, N(HD) is comparable to the Galaxy but with 10 times smaller N({H_2}) and somewhat smaller N({H_2})/N(H I). Comparison of our Galaxy with the Magellanic Clouds shows that smaller {H_2}/H is expected at subsolar metallicity, and we show by modeling that HD/{H_2} increases with density at low metallicity, opposite to the Milky Way. Observations of HD would be explained with higher n(H) at low metallicity, but high-z systems have high HD/{H_2} at metallicity 0.04 shielding effects. The abrupt {H_2} transition to {H_2}/H ≈ 1%-10% occurs mostly from self-shielding, although it is assisted by extinction for n(H) <~ 16 cm-3. Interior {H_2} fractions are substantially increased by dust extinction below <~ 32 cm-3. At smaller n(H), ζ H , small increases in {H_2} triggered by dust extinction can trigger abrupt increases in N(HD).

  18. Dicarboxylic acids, metals and isotopic compositions of C and N in atmospheric aerosols from inland China: implications for dust and coal burning emission and secondary aerosol formation

    Science.gov (United States)

    Wang, G.; Xie, M.; Hu, S.; Gao, S.; Tachibana, E.; Kawamura, K.

    2010-07-01

    Dicarboxylic acids (C2-C10), metals, elemental carbon (EC), organic carbon (OC), and stable isotopic compositions of total carbon (TC) and total nitrogen (TN) were determined for PM10 samples collected at three urban and one suburban sites of Baoji, an inland city of China, during winter and spring 2008. Oxalic acid (C2) was the dominant diacid, followed by succinic (C4) and malonic (C3) acids. Total diacids in the urban and suburban areas were 1546±203 and 1728±495 ng m-3 during winter and 1236±335 and 1028±193 ng m-3 during spring. EC in the urban and the suburban atmospheres were 17±3.8 and 8.0±2.1 μg m-3 during winter and 20±5.9 and 7.1±2.7 μg m-3 during spring, while OC at the urban and suburban sites were 74±14 and 51±7.9 μg m-3 in winter and 51±20 and 23±6.1 μg m-3 in spring. Secondary organic carbon (SOC) accounted for 38±16% of OC in winter and 28±18% of OC in spring, suggesting an enhanced photochemical production of secondary organic aerosols in winter under an inversion layer development. Total metal elements in winter and spring were 34±10 and 61±27 μg m-3 in the urban air and 18±7 and 32±23 μg m-3 in the suburban air. A linear correlation (r2>0.8 in winter and r2>0.6 in spring) was found between primary organic carbon (POC) and Ca2+/Fe, together with a strong dependence of pH value of sample extracts on water-soluble inorganic carbon, suggesting fugitive dust as an important source of the airborne particles. Polycyclic aromatic hydrocarbons (PAHs), sulfate, and Pb in the samples well correlated each other (r2>0.6) in winter, indicating an importance of emissions from coal burning for house heating. Stable carbon isotope compositions of TC (δ13C) became higher with an increase in the concentration ratios of C2/OC due to aerosol aging. In contrast, nitrogen isotope compositions of TN (δ15N) became lower with an increases in the mass ratios of NH4+/PM10 and NO3-/PM10, which is possibly caused by an enhanced adsorption and

  19. Dust Mite Allergy

    Science.gov (United States)

    Dust mite allergy Overview By Mayo Clinic Staff Dust mite allergy is an allergic reaction to tiny bugs that commonly live in house dust. Signs of dust mite allergy include those common to hay fever, such as ...

  20. Andromeda's dust

    Energy Technology Data Exchange (ETDEWEB)

    Draine, B. T.; Aniano, G. [Princeton University Observatory, Peyton Hall, Princeton, NJ 08544-1001 (United States); Krause, Oliver; Groves, Brent; Sandstrom, Karin; Klaas, Ulrich; Linz, Hendrik; Rix, Hans-Walter; Schinnerer, Eva; Schmiedeke, Anika; Walter, Fabian [Max-Planck-Institut fur Astronomie, Konigstuhl 17, D-69117 Heidelberg (Germany); Braun, Robert [CSIRO—Astronomy and Space Science, P.O. Box 76, Epping, NWS 1710 (Australia); Leroy, Adam, E-mail: draine@astro.princeton.edu, E-mail: ganiano@ias.u-psud.fr [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22903 (United States)

    2014-01-10

    Spitzer Space Telescope and Herschel Space Observatory imaging of M31 is used, with a physical dust model, to construct maps of dust surface density, dust-to-gas ratio, starlight heating intensity, and polycyclic aromatic hydrocarbon (PAH) abundance, out to R ≈ 25 kpc. The global dust mass is M {sub d} = 5.4 × 10{sup 7} M {sub ☉}, the global dust/H mass ratio is M {sub d}/M {sub H} = 0.0081, and the global PAH abundance is (q {sub PAH}) = 0.039. The dust surface density has an inner ring at R = 5.6 kpc, a maximum at R = 11.2 kpc, and an outer ring at R ≈ 15.1 kpc. The dust/gas ratio varies from M {sub d}/M {sub H} ≈ 0.026 at the center to ∼0.0027 at R ≈ 25 kpc. From the dust/gas ratio, we estimate the interstellar medium metallicity to vary by a factor ∼10, from Z/Z {sub ☉} ≈ 3 at R = 0 to ∼0.3 at R = 25 kpc. The dust heating rate parameter (U) peaks at the center, with (U) ≈ 35, declining to (U) ≈ 0.25 at R = 20 kpc. Within the central kiloparsec, the starlight heating intensity inferred from the dust modeling is close to what is estimated from the stars in the bulge. The PAH abundance reaches a peak q {sub PAH} ≈ 0.045 at R ≈ 11.2 kpc. When allowance is made for the different spectrum of the bulge stars, q {sub PAH} for the dust in the central kiloparsec is similar to the overall value of q {sub PAH} in the disk. The silicate-graphite-PAH dust model used here is generally able to reproduce the observed dust spectral energy distribution across M31, but overpredicts 500 μm emission at R ≈ 2-6 kpc, suggesting that at R = 2-6 kpc, the dust opacity varies more steeply with frequency (with β ≈ 2.3 between 200 and 600 μm) than in the model.

  1. 30 CFR 56.9315 - Dust control.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Dust control. 56.9315 Section 56.9315 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR METAL AND NONMETAL MINE SAFETY AND... control. Dust shall be controlled at muck piles, material transfer points, crushers, and on haulage...

  2. Essays in Household Finance

    DEFF Research Database (Denmark)

    Hanspal, Tobin

    This Ph.D. thesis, entitled Essays in Household Finance, analyzes the determinants and implications of investment biases, personal experiences in financial markets, and financing disruptions on households, individual investors, and entrepreneurs and small business owners. The first essay...... on risk taking is the potential bias resulting from inertia and inattention, which has been shown to be endemic in household finance. If individuals are inert or inattentive, it is difficult to establish whether changes in risk taking are caused by personal experiences or whether the change in risk taking...

  3. Essays in Household Finance

    DEFF Research Database (Denmark)

    Hanspal, Tobin

    This Ph.D. thesis, entitled Essays in Household Finance, analyzes the determinants and implications of investment biases, personal experiences in financial markets, and financing disruptions on households, individual investors, and entrepreneurs and small business owners. The first essay...... on risk taking is the potential bias resulting from inertia and inattention, which has been shown to be endemic in household finance. If individuals are inert or inattentive, it is difficult to establish whether changes in risk taking are caused by personal experiences or whether the change in risk taking...

  4. Heavy Metal Pollution and the Ecological Risk Assessment of Urban Street Dust in Kunming%昆明市街道灰尘重金属污染及潜在生态风险评价

    Institute of Scientific and Technical Information of China (English)

    梁涛; 史正涛; 吴枫; 谷晓梅

    2011-01-01

    The concentrations of Cu, Zn, Pb, As, Cr and Ni in urban street dust collected from Kunming were analyzed by using X-Ray fluorescence spectrometry. Spatial technique was applied to study the content level and the spatial distribution characteristics of heavy metal pollution in street dust of Kunming. The ecological risks of heavy metals in street dust were assessed with the potential ecological risk index method. The results show that the average concentrations of Cu, Zn, Pb, As, Cr and Ni in the street dust in Kunming were 166.6, 316.53, 97.49, 20.56, 79.41 and 21.45mg·kg-1, respectively, much higher than the background concentrations in soil in China, in which Cu, Zn, Pb and As contributed to pollution largely, whose concentrations had reached a relative enrichment level. Accumulation of heavy metals in dry season was significantly higher than that in rainy season .The highest content of heavy metals existed in the industrial areas, and the second in traffic areas. Heavy metals mainly came from traffic pollution in urban street dust and from industrial pollution in suburbs .The potential ecological risk of heavy metals in the street dust of Kunming had reached a higher level. The order of potential ecological risk indexes of heavy metals was Cu > Zn > As > Pb > Cr >Ni, in which Cu was the most important ecological risk factor.%利用X-Ray荧光光谱仪对昆明市街道灰尘的Cu、Zn、Ph、As、Cr和Ni等元素进行了分析,讨论了街道灰尘中重金属含量的水平和空间分布特征;采用潜在生态危害指数法对灰尘中重金属的潜在生态风险进行了评价.结果表明:昆明市街道灰尘中重金属Cu、Zn、Pb、As、Cr和Ni的平均含量分别为166.6、316.53、97.49、20.56、79.41和21.45 mg/kg,与全国土壤背景值相比有较大积累,其中cu、zn、Pb和As都达到相对富集类,污染程度较重;重金属元素在旱季有明显积累趋势,雨季相对降低;重金属在工业区含量最高,其次为

  5. Carpet-dust chemicals as measures of exposure: Implications of variability

    Directory of Open Access Journals (Sweden)

    Whitehead Todd P

    2012-03-01

    Full Text Available Abstract Background There is increasing interest in using chemicals measured in carpet dust as indicators of chemical exposures. However, investigators have rarely sampled dust repeatedly from the same households and therefore little is known about the variability of chemical levels that exist within and between households in dust samples. Results We analyzed 9 polycyclic aromatic hydrocarbons, 6 polychlorinated biphenyls, and nicotine in 68 carpet-dust samples from 21 households in agricultural communities of Fresno County, California collected from 2003-2005. Chemical concentrations (ng per g dust ranged from Conclusions Our findings suggest that attenuation bias should be relatively modest when using these semi-volatile carpet-dust chemicals as exposure surrogates in epidemiologic studies.

  6. Indoor Allergen Levels and Household Distributions in Nine Cities Across China

    Institute of Scientific and Technical Information of China (English)

    ZHENG Yi Wu; NORBACK Dan; GJESING Birgitte; ZHONG Nan Shan; SPANGFORT DMichael; LAI Xu Xin; ZHAO De Yu; ZHANG Chun Qing; CHEN Jian Jun; ZHANG Luo; WEI Qing Yu; CHEN Shi; LIU En Mei

    2015-01-01

    Objective Chinese allergic subjects have high levels of sensitization to house dust mite (HDM) and other indoor allergens. This study quantifies common indoor allergen levels in Chinese households. Methods Dust samples were collected from nine cities. Major allergens Der p 1 and Der f 1 from Dermatophagoides pteronyssinus and D. farinae, and specific antigens of Blomia tropicalis, Tyrophagus putrescentiae, Acarus siro, and cockroach species Blattella germanica and Periplaneta americana were measured by ELISA. Results HDM allergens were found in dust samples from bedding in 95% of the Chinese households. The median levels varied from Conclusion HDM allergens are present in bedding dust samples from most Chinese households. Cities in southern and central China have relatively high levels of HDM major allergens compared to cities in northern and western China. Antigens of storage mites and cockroaches are not as common as HDM allergens.

  7. Antibacterials in Household Products

    Science.gov (United States)

    ... residue-producing ). Common examples of this group are triclosan, triclocarban, and benzalkonium chloride. Did you know that over 1000 commercial products contain triclosan or other biocide agents? Antibacterials in household products ...

  8. Polybrominated Diphenyl Ethers in Residential Dust: Sources of Variability

    Science.gov (United States)

    Whitehead, Todd P.; Brown, F. Reber; Metayer, Catherine; Park, June-Soo; Does, Monique; Petreas, Myrto X.; Buffler, Patricia A.; Rappaport, Stephen M.

    2013-01-01

    We characterized the sources of variability for polybrominated diphenyl ethers (PBDEs) in residential dust and provided guidance for investigators who plan to use residential dust to assess exposure to PBDEs. We collected repeat dust samples from 292 households in the Northern California Childhood Leukemia Study during two sampling rounds (from 2001–2007 and during 2010) using household vacuum cleaners and measured 22 PBDEs using high resolution gas chromatography-high resolution mass spectrometry. Median concentrations for individual PBDEs ranged from <0.1–2,500 ng per g of dust. For each of eight representative PBDEs, we used a random-effects model to apportion total variance into regional variability (0–11%), intra-regional between-household variability (17–50%), within-household variability over time (38–74%), and within-sample variability (0–23%) and we used a mixed-effects model to identify determinants of PBDE levels. Regional differences in PBDE dust levels were associated with residential characteristics that differed by region, including the presence of furniture with exposed or crumbling foam and the recent installation of carpets in the residence. Intra-regional differences between households were associated with neighborhood urban density, racial and ethnic characteristics, and to a lesser extent, income. For some PBDEs, a decreasing time trend explained a modest fraction of the within-household variability; however, most of the within-household variability was unaccounted for by our mixed-effects models. Our findings indicate that it may be feasible to use residential dust for retrospective assessment of PBDE exposures in studies of children’s health (e.g., the Northern California Childhood Leukemia Study). PMID:23628589

  9. Indoor metallic pollution related to mining activity in the Bolivian Altiplano

    Energy Technology Data Exchange (ETDEWEB)

    Fonturbel, Francisco E., E-mail: fonturbel@ug.uchile.cl [Departamento de Ciencias Ecologicas, Facultad de Ciencias, Universidad de Chile, Santiago (Chile); Barbieri, Enio [IRD-HSM (Institut de Recherche pour le Developpement), La Paz (Bolivia, Plurinational State of); Herbas, Cristian [Universidad Mayor de San Andres, IGEMA Institute (Instituto de Investigaciones Geologicas y del Medio Ambiente), La Paz (Bolivia, Plurinational State of); Barbieri, Flavia L.; Gardon, Jacques [IRD-HSM (Institut de Recherche pour le Developpement), La Paz (Bolivia, Plurinational State of); Universidad Mayor de San Andres, SELADIS Institute (Instituto de Servicios de Laboratorio para el Diagnostico e Investigacion en Salud), La Paz (Bolivia, Plurinational State of)

    2011-10-15

    The environmental pollution associated with mining and metallurgical activities reaches its greatest extent in several Andean cities and villages. Many locations in this area have accumulated through centuries a large amount of mining wastes, often disregarding the magnitude of this situation. However, in these naturally mineralized regions, there is little information available stating the exact role of mining and metallurgical industries in urban pollution. In this study, we demonstrated that the various metallic elements present in indoor dust (As, Cd, Cu, Pb, Sb, Sn, Zn) had a common origin and this contamination was increased by the proximity to the mines. Lead dust concentration was found at concerning levels for public health. In addition, wrong behaviors such as carrying mining workwear home contributed to this indoor dust pollution. Consequently, the constant exposure of the population could represent a potential health hazard for vulnerable groups, especially children. - Highlights: > We measured polymetallic pollution in household indoor dust from a mining town. > Toxic elements (Pb, As, Cd, Sb) in dust are correlated, suggesting a common origin. > The most polluted houses are within a 1 km radius around the mining center. > Carrying mining workwear home increases indoor pollution. > Lead concentrations in dust represent a serious concern for Public Health (600 {mu}g/g). - In a typical Andean mining city, the urban indoor pollution with toxic metallic elements is directly related to the closeness of the mining activities.

  10. Concentrations and particle size effect of heavy metals in the street dust of Xuchang City%许昌市街道灰尘重金属含量及其粒径效应

    Institute of Scientific and Technical Information of China (English)

    闫慧; 肖军; 张俊丽

    2016-01-01

    Background aim and scope Street dust is an important pathway for pollution material in the urban environment. Street dust often becomes a sink for both industrial and residential pollutants, including waste incineration residues, vehicle exhaust emissions, and products of tire wear, metallic fragments, fossil fuel combustion emissions and garden soil. Among the pollutants in street dust, heavy metals are often more severe than others. Heavy metal elements are often not decomposed by microorganisms and may become enriched through the food chain, affecting human health, especially that of children and elderly people. Moreover, heavy metals have more affinity to establish metallic bonds with ferrous material, which leads to enhancement of the magnetic susceptibility of street dust. Many studies have reported excellent relationships between magnetic susceptibility and the levels of some heavy metals in street dust or industrial/urban soils, this relationship forms the basis for the use of magnetic methods in pollution studies. Therefore, magnetic susceptibility characteristics of street dust can be used to relfect a city’s heavy metal pollution. Furthermore, heavy metal enrichment regularity in street dust research has important signiifcance. Along with the remarkably fast development of the economy and urbanization of China, environmental pollution is becoming a more serious problem in many cities. Xuchang City is one core city of the Central Megalopolis of China;industrial pollution and vehicle exhaust emissions have aggravated the city’s pollution in recent years, especially the particulate matter pollution. At present particle size effect of heavy metal of Xuchang City street dust has not been reported. This present research studied the Xuchang City street dust particle size and heavy metals concentration. Our main aims are to analyze the particle size and heavy metal concentration and to identify the relationships between them. The results may provide useful

  11. Radiative transfer modelling of dust in IRAS 18333-2357: the only planetary nebula in the metal-poor globular cluster M22

    Science.gov (United States)

    Muthumariappan, C.; Parthasarathy, M.; Ita, Y.

    2013-10-01

    We report results from our 1D radiative transfer modelling of dust in the hydrogen-deficient planetary nebula IRAS 18333-2357 located in the globular cluster M22. A spectral energy distribution was constructed from archival UV, optical and IR data including Akari photometry at its 18, 65, 90, 140 and 160 μm bands. An archival Spitzer spectrum shows several aromatic infrared bands indicating a carbon-rich dust shell. The spectral energy distribution is well fitted by a model which considers a modified Mathis-Rumpl-Nordsieck grain size distribution and a radial density function which includes compression of the nebula by its interaction with the Galactic halo gas. The model indicates that a significant amount of cold dust, down to a temperature of 50 K, is present at the outer edge of the nebula. At the inner edge, the dust temperature is 97 K. The dust shell has a size of 26 ± 6.3 arcsec. We find a large amount of excess emission, over the emission from thermal equilibrium dust, in the mid-IR region. This excess emission may have originated from the thermally fluctuating dust grains with size ˜12 Å in the UV field of the hot central star. These grains, however, come from the same population and conditions as the thermal equilibrium grains. The dust mass of this grain population is (1.2 ± 0.73) × 10-3 M⊙ and for the thermal equilibrium grains it is (1.4 ± 0.60) × 10-4 M⊙, leading to a total dust mass of (1.3 ± 0.91) × 10-3 M⊙. The derived dust-to-gas mass ratio is 0.3 ± 0.21. For a derived bolometric luminosity of (1700 ± 1230) L⊙ and an assumed central star mass of (0.55 ± 0.02) M⊙, the surface gravity is derived to be log g = 4.6 ± 0.24. We propose that the progenitor of IRAS 18333-2357 had possibly evolved from an early stellar merger case and the hydrogen-deficient nebula results from a late thermal pulse. The hydrogen-rich nebula, which was ejected by the progenitor during its normal asymptotic giant branch evolution, might have been

  12. Household batteries: Evaluation of collection methods

    Energy Technology Data Exchange (ETDEWEB)

    Seeberger, D.A.

    1992-01-01

    While it is difficult to prove that a specific material is causing contamination in a landfill, tests have been conducted at waste-to-energy facilities that indicate that household batteries contribute significant amounts of heavy metals to both air emissions and ash residue. Hennepin County, MN, used a dual approach for developing and implementing a special household battery collection. Alternative collection methods were examined; test collections were conducted. The second phase examined operating and disposal policy issues. This report describes the results of the grant project, moving from a broad examination of the construction and content of batteries, to a description of the pilot collection programs, and ending with a discussion of variables affecting the cost and operation of a comprehensive battery collection program. Three out-of-state companies (PA, NY) were found that accept spent batteries; difficulties in reclaiming household batteries are discussed.

  13. Household batteries: Evaluation of collection methods

    Energy Technology Data Exchange (ETDEWEB)

    Seeberger, D.A.

    1992-12-31

    While it is difficult to prove that a specific material is causing contamination in a landfill, tests have been conducted at waste-to-energy facilities that indicate that household batteries contribute significant amounts of heavy metals to both air emissions and ash residue. Hennepin County, MN, used a dual approach for developing and implementing a special household battery collection. Alternative collection methods were examined; test collections were conducted. The second phase examined operating and disposal policy issues. This report describes the results of the grant project, moving from a broad examination of the construction and content of batteries, to a description of the pilot collection programs, and ending with a discussion of variables affecting the cost and operation of a comprehensive battery collection program. Three out-of-state companies (PA, NY) were found that accept spent batteries; difficulties in reclaiming household batteries are discussed.

  14. Accumulation and health risk assessment of heavy metals in kindergarten surface dust in the city of Kaifeng%开封市幼儿园地表灰尘重金属积累及健康风险

    Institute of Scientific and Technical Information of China (English)

    王晓云; 马建华; 侯千; 段海静

    2011-01-01

    Samples of surface dust were collected from thirty-one kindergartens in Kaifeng. The concentrations of Pb, Zn, Cr, Cu and Ni in different sizefractionated ( <0.15, 0. 15 ~0.25 and >0.25 mm in diameter) samples and in the mixed samples with all size fractions were determined by flame atomic absorption spectrophotometry (F-AAS). The accumulations of heavy metals in dust were analyzed using Enrichment Factor ( EF), and health risks of heavy metals to young children were assessed using Health Index (HI). The results show that the average concentrations of Pb, Zn, Ni, Cu and Cr in the samples are 242.99, 297.32, 52.57, 38.92 and 82.13 mg· kg - 1 respectively, which all exceed the background values in the fluvo-aquic soils of China. The metals Pb, Zn and Cr, mainly from human activities and enriched in dust significantly, are anthropogenic source metals; Ni, mainly from natural factors, is a natural source metals, while Cu, both from human activities and natural factors, is a mixed source metals. The samples from the old downtown area, industrial area and near major roads are polluted with heavy metals much more heavily than those in other areas of the city. It was also found that Pb is mainly enriched in the coarse fraction ( >0.25 mm) of dust, Zn in the fine fraction ( <0.15 mm), and Cu, Cr and Ni in all size fractions of dust without significant differences. The particle compositions of dust are fine 55% , coarse 28% and medium 17% , while the average mass percents of all heavy metals in the different size fractions are 50.03% in fine dust, 29.55% in coarse and 18.43% in medium. The main exposure pathway of heavy metals to young children is hand-to-mouth ingestion. The HIJ indicate that heavy metals have different levels of health risk to young children ( Pb > Cr > Ni > Zn > Cu), in eight ( 25.8% ) kindergartens HIpb > 1, and one ( 3.2 % ) Hlcr > 1. A health risk from Pb and Cr exists in some kindergartens; but generally, there

  15. Lead in Chinese villager house dust

    Science.gov (United States)

    Bi, Xiangyang; Liu, Jinling; Han, Zhixuan

    2016-04-01

    House dust has been recognized as an important contributor to children's blood Pb. Here we conducted a comprehensive study to investigate geographical variation of Pb in Chinese villager house dust. The concentrations of Pb in 477 house dust samples collected from twenty eight areas throughout China varied from 12 to 2510 mg/kg, with geometric mean and median concentration of 54 mg/kg and 42 mg/kg, respectively. The median Pb concentrations in different geographical areas ranged from 16 (Zhangjiakou, Hebei) to 195 mg/kg (Loudi, Hunan). The influences of outdoor soil Pb concentrations, dates of construction, house decorative materials, heating types, and site specific pollution on Pb concentrations in house dust were evaluated. No correlations were found between the house dust Pb concentrations and the age of houses, as well as house decorative materials. Whereas outdoor soil, coal combustion, and site specific pollution may be potential Pb sources. The results of scanning electron microscopy (SEM) showed that Pb bearing particles appeared as cylindrical, flaky and irregular aggregates with the particle size ranging from about 10 to 800 μm. The energy dispersive X-ray microanalysis (EDX) suggested that Pb in the dust particles may be associated with calcium compounds. But the major fraction of Pb in the household dust samples was found to be strongly bound to Fe-Mn oxide phases (37%) while Pb present in minor fractions individually making up between 14 and 18% was characterized in falling order as residual, carbonate, organic/sulphide and exchangeable fractions by the sequential extraction method applied. Bioaccessible Pb making up an average proportion of 53% in the household dusts was significantly correlated to the Fe-Mn oxide phases of Pb.

  16. 北京市幼儿园地面尘中有毒金属浓度及其健康风险%Concentrations and Health Risks of Toxic Metals in Surface Dust in Kindergartens of Beijing

    Institute of Scientific and Technical Information of China (English)

    段恒轶; 吴亚涛; 王珏; 刘兆荣

    2014-01-01

    灰尘摄入是儿童金属暴露的重要来源.为了解北京市区幼儿园环境中有毒金属污染水平及其对儿童健康的影响,利用自制采样器采集北京市区代表幼儿园地面尘,并分析其中的 Pb、 Cd、 Hg、 As 浓度.结果表明 Cd、 Hg、 Pb 在室内地面尘中具有不同程度的富集且呈现明显的季节变化特征.夏季地面尘中 Pb、 Cd、 Hg、 As 浓度的几何均值分别为63.12、1.67、0.06、0.22μg•g -1;冬季分别为117.40、4.52、0.95、0.88μg•g -1.通过计算地理累积指数发现,北京市区幼儿园受到严重的 Cd、Pb 污染.暴露及健康风险评估结果表明,儿童对地面尘中有毒金属的经口摄入量远大于皮肤摄入量.4种金属对儿童均无显著的致癌和非致癌风险.但相比于其他金属,Pb 的非致癌风险较高,其危险指数达0.12,需要引起重视.%Dust intake is an important source of children's metal exposure. To explore the contamination level and health risk of toxic metals in kindergartens, surface dust samples were collected with self-made sampler in representative kindergartens in urban Beijing and concentrations of Pb, Hg, Cd, As were analyzed. It was found that Cd, Hg, Pb accumulated in indoor dust in different degrees with a significant seasonal variation. The geometric means of Pb, Cd, Hg, As concentrations were 63. 12 μg•g - 1 , 1. 67 μg•g - 1 , 0. 06μg•g - 1 , 0. 22 μg•g - 1 in summer and 117. 40 μg•g - 1 , 4. 52 μg•g - 1 , 0. 95 μg•g - 1 , 0. 88 μg•g - 1 in winter, respectively. Geo-accumulation indexes calculated for each metal showed a severe contamination of Pb and Cd in indoor surface dusts. The results of exposure and health risk assessment of target substances displayed that the oral intake of dust metals was much higher than that of dermal pathways for children. However, no obvious carcinogenic and non-carcinogenic risks were found for all metals. The Pb, against other species, had the highest

  17. Chemical Forms and Pollution Characteristics of Heavy Metals in Urban Street Dust of Xi’an, China%西安市街尘中重金属赋存形态和污染特征分析

    Institute of Scientific and Technical Information of China (English)

    袁宏林; 张恒; 李星星; 李龙

    2015-01-01

    Urban street dust is the dependent carrier of heavy metals and other contaminants, and residents’ frequent contact with contaminants in daily activities make them easily enter the human body, which is of great harm to the health of residents, so street dust pollution control has attracted widespread attention. In order to study the status and distribution of heavy metal contamination of street dust, eight regions with different road surface characteristics were selected as street dust sampling points in winter and spring when street dust gathers abundantly in Xi’an. Tessier sequential extraction was used to extract the heavy metals in the sample, and ICP-MS was used to measure the content of Cu, Zn, Fe, Mn, Pb and Cd in street dust in different forms. The contrast with environmental background values of heavy metals in the soil in Shaanxi Province shows that the content of the six heavy metal elements in the street dust of all eight sampling points significantly exceeds background values, respectively 3.8, 8.1, 2.3, 2.5, 15.7 and 49.6 times, and the gathering of Cd, Pb and Zn in the dust of trunk and secondary streets is severer than branches. According to deviation analysis:the content of cadmium at each point had a greater influence on the environment, iron at each point is relatively balanced, other elements are slightly different at each point. The accumulation of Cd and Cu on the asphalt road surface is higher than concrete road surface, while that of Pb and Zn is lower. According to the occurrence form analysis, Cu in the street dust of Xi'an is mainly in the organic bound form; Fe and Zn is mainly in the ferro-manganese bound form; Mn exists in the ferro-manganese bound form and organic bound form;Pb mainly exists in the exchangeable form and ferro-manganese bound form;Cd mainly exists in the exchangeable form and carbonate bound form. The higher the street grade, the larger the proportion of exchangeable form and carbonate bound form of heavy metals

  18. Dicarboxylic acids, metals and isotopic compositions of C and N in atmospheric aerosols from inland China: implications for dust and coal burning emission and secondary aerosol formation

    Directory of Open Access Journals (Sweden)

    G. Wang

    2010-07-01

    Full Text Available Dicarboxylic acids (C2–C10, metals, elemental carbon (EC, organic carbon (OC, and stable isotopic compositions of total carbon (TC and total nitrogen (TN were determined for PM10 samples collected at three urban and one suburban sites of Baoji, an inland city of China, during winter and spring 2008. Oxalic acid (C2 was the dominant diacid, followed by succinic (C4 and malonic (C3 acids. Total diacids in the urban and suburban areas were 1546±203 and 1728±495 ng m−3 during winter and 1236±335 and 1028±193 ng m−3 during spring. EC in the urban and the suburban atmospheres were 17±3.8 and 8.0±2.1 μg m−3 during winter and 20±5.9 and 7.1±2.7 μg m−3 during spring, while OC at the urban and suburban sites were 74±14 and 51±7.9 μg m−3 in winter and 51±20 and 23±6.1 μg m−3 in spring. Secondary organic carbon (SOC accounted for 38±16% of OC in winter and 28±18% of OC in spring, suggesting an enhanced photochemical production of secondary organic aerosols in winter under an inversion layer development. Total metal elements in winter and spring were 34±10 and 61±27 μg m−3 in the urban air and 18±7 and 32±23 μg m−3 in the suburban air. A linear correlation (r2>0.8 in winter and r2>0.6 in spring was found between primary organic carbon (POC and Ca2+/Fe, together with a strong dependence of pH value of sample extracts on water-soluble inorganic carbon, suggesting fugitive dust as an important source of the airborne particles. Polycyclic aromatic hydrocarbons (PAHs, sulfate, and Pb in the samples well correlated each other (r2>0.6 in winter, indicating an importance of emissions from coal burning for house heating. Stable carbon isotope compositions of TC (δ13C became higher with an increase

  19. Household food security, Ghana.

    Science.gov (United States)

    Tetebo, R

    1997-12-01

    Two major projects incorporating household food security components have been implemented since the ICN. The first is a UNICEF-funded project that addresses community participation in development. The second is a FAO-funded project: "Promoting Household Food Security and Improving Nutrition through Nutrition Education and Training." This project examines the effects of processing and storage procedures on the nutrient quality of traditional and indigenous fruits and vegetables. It is a young project, but much is being learned from it. Other projects aim to minimize food wastage during processing and storage by developing new processing machinery for use by rural households. Women's issues have become central since the ICN and there is increased support from both government and nongovernment sources to help women with food production and processing.

  20. Reconstructing Pompeian Households

    CERN Document Server

    Mimno, David

    2012-01-01

    A database of objects discovered in houses in the Roman city of Pompeii provides a unique view of ordinary life in an ancient city. Experts have used this collection to study the structure of Roman households, exploring the distribution and variability of tasks in architectural spaces, but such approaches are necessarily affected by modern cultural assumptions. In this study we present a data-driven approach to household archeology, treating it as an unsupervised labeling problem. This approach scales to large data sets and provides a more objective complement to human interpretation.

  1. High-volume samplers for the assessment of respirable silica content in metal mine dust via direct-on-filter analysis

    CSIR Research Space (South Africa)

    Cauda, EG

    2014-08-01

    Full Text Available exposure to silica by two main factors: 1) variability of the silica percent in the mining dust and 2) lengthy off-site laboratory analysis of collected samples. The collection of samples for short periods of time during the workers' shift and subsequent on...

  2. Dust and molecules in extra-galactic planetary nebulae

    CERN Document Server

    Garcia-Hernandez, D A

    2015-01-01

    Extra-galactic planetary nebulae (PNe) permit the study of dust and molecules in metallicity environments other than the Galaxy. Their known distances lower the number of free parameters in the observations vs. models comparison, providing strong constraints on the gas-phase and solid-state astrochemistry models. Observations of PNe in the Galaxy and other Local Group galaxies such as the Magellanic Clouds (MC) provide evidence that metallicity affects the production of dust as well as the formation of complex organic molecules and inorganic solid-state compounds in their circumstellar envelopes. In particular, the lower metallicity MC environments seem to be less favorable to dust production and the frequency of carbonaceous dust features and complex fullerene molecules is generally higher with decreasing metallicity. Here, I present an observational review of the dust and molecular content in extra-galactic PNe as compared to their higher metallicity Galactic counterparts. A special attention is given to th...

  3. Promoting household energy conservation

    NARCIS (Netherlands)

    Steg, Linda

    2008-01-01

    It is commonly assumed that households must change their behaviour to reduce the problems caused by increasing levels of fossil energy use. Strategies for behaviour change will be more effective if they target the most important causes of the behaviour in question. Therefore, this paper first discus

  4. GEOCHEMISTRY OF ATMOSPHERIC DUST ON THE TERRITORY OF THE CITY OF YEREVAN

    Directory of Open Access Journals (Sweden)

    Armen Saghatelyan

    2012-06-01

    Full Text Available This research is focused on the level of heavy metal contents in dust of a near-ground layer of atmosphere. The dust load level was evaluated as medial. Indicated was a quality composition of dominating dust pollutants. The level of summary load of metals was low.

  5. 典型材料屋面积尘重金属形态分布与风险评估%Speciation Distribution and Risk Assessment of Heavy Metals in Typical Material Roof Dusts

    Institute of Scientific and Technical Information of China (English)

    李敦柱; 管运涛; 刘安; 李思远

    2015-01-01

    With the modified BCR sequential extraction procedure, the chemical speciation and risk for 10 heavy metals (Ba, Co, Cr, Cu, mn, Ni, Pb, Sb, Sr and Zn) in roof dusts were investigated. The subjects of this study were collected from four typical material paved roofs (i. e. , ceramic tile, concrete, metal and asphalt) in southeast China. The results indicated that the average contents of heavy metals in roof dust significantly exceeded road dust. The analysis of chemical fraction showed that the acid soluble/ exchangeable fraction of Zn was much higher than other elements, the existence of Pb and Cu was mainly in oxidization fraction, while other heavy metals dominated by the residual fraction. The mobility sequence percentages for all roof dust samples decreased in the order of Pb > Zn> Cu》mn > Co》Sr > Sb > Ni > Ba > Cr, and it should be noted that Pb, Zn, Cu, mn and Co all have more than 50% proportion in mobility sequence. Based on environmental risk assessment, the highest values of contamination factors (Cf ) and risk assessment code (RAC) consistently was observed in Zn, which indicated that Zn had relatively high ecological risk. Health risk assessment showed that the non-carcinogenic hazard indexes (HI) of heavy metals decreased in the order of Pb > Cr > Sb > Zn > mn > Cu > Ba > Ni > Co >Sr, the HI of heavy metals for adults were lower than safe value while the HI of Pb for children was higher than safe value, suggesting that they will not harm the adult's health except Pb for children. The carcinogenic risk for Cr, Co and Ni were all below the threshold values, which indicated that there was no carcinogenic risk.%以华南地区4种典型材料屋面(瓷砖、混凝土、金属和沥青)为研究对象,采用改进式 BCR 连续提取法对其屋面积尘中10种重金属(Ba、 Co、 Cr、 Cu、 mn、 Ni、 Pb、 Sb、 Sr 和 Zn)进行形态分析与风险评估。结果表明,屋面积尘重金属平均含量明显高于道路

  6. Household Adjustments to Hurricane Katrina

    National Research Council Canada - National Science Library

    Meri Davlasheridze; Qin Fan

    2017-01-01

    This paper examines household adjustments to Hurricane Katrina by estimating the effects of Katrina-induced damages on changes in household demographics and income distributions in the Orleans Parish...

  7. Physical properties of suspended dust in Iceland

    Science.gov (United States)

    Dagsson Waldhauserova, Pavla; Olafsson, Haraldur; Arnalds, Olafur; Skrabalova, Lenka; Sigurdardottir, Gudmunda; Branis, Martin; Hladil, Jindrich; Chadimova, Leona; Skala, Roman; Navratil, Tomas; Menar, Sibylle von Lowis of; Thorsteinsson, Throstur

    2014-05-01

    Atmospheric Dust Measurements (ADMI 2013) of one of the most active dust sources in Iceland (Mælifellsandur) were conducted during season with high precipitation on August 8th-18th, 2013. We measured mass concentrations (PM2.5 and PM10), particle size distributions in size range 0.3-10μm and number concentrations during rather small dust event. Dust samples of the event were analyzed (morpho-textural observations, optical and scanning-electron microscopy). Two TSI 8520 DustTrak Aerosol Monitors (light-scattering laser photometers that measure aerosol mass concentrations in range 0.001 to 100 mg/m3) and one TSI Optical Particle Sizer (OPS) 3330 (optical scattering from single particle up to 16 different channels - 0.3 to 10 μm - measuring particle size distribution) were used. We measured a dust event which occurred during wet and low wind/windless conditions as result of surface heating in August 2013. Maximum particle number concentration (PM~0.3-10 µm) reached 149954 particles cm-3 min-1 while mass concentration (PM1.5-5 µm in diameter. Close-to-ultrafine particle size distributions showed a significant increase in number with the severity of the dust event. Number concentrations were well correlated with mass concentrations. The mineralogy and geochemical compositions showed that glaciogenic dust contains sharp-tipped shards with bubbles and 80 % of the particulate matter is volcanic glass rich in heavy metals. Wet dust particles were mobilized within < 4 hours. Here we introduced a comprehensive study on physical properties of the Icelandic dust aerosol and the first scientific study of particle size distributions in an Icelandic dust event including findings on initiation of dust suspension.

  8. Efficient Intra-Household Allocations

    DEFF Research Database (Denmark)

    Browning, Martin

    for households which have more than one member. We make minimal assumptions about how the individual members of the household resolve conflicts. All we assume is that however decisions are made, outcomes are efficient. We refer to this as the collective setting. We show that in the collective setting household...

  9. Households, Migration, and Community Context.

    Science.gov (United States)

    Benson, Janet E.

    1990-01-01

    Studies why Vietnamese and Laotian refugee households take the forms they do in a small southwestern Kansas community. Argues that extended family and other nonnuclear family households facilitate refugee adaptation. Economic conditions, labor and housing markets, and refugee legal status all influence household composition, members' roles, and…

  10. House dust in seven Danish offices

    Science.gov (United States)

    Mølhave, L.; Schneider, T.; Kjærgaard, S. K.; Larsen, L.; Norn, S.; Jørgensen, O.

    Floor dust from Danish offices was collected and analyzed. The dust was to be used in an exposure experiment. The dust was analyzed to show the composition of the dust which can be a source of airborne dust indoors. About 11 kg of dust from vacuum cleaner bags from seven Danish office buildings with about 1047 occupants (12 751 m 2) was processed according to a standardized procedure yielding 5.5 kg of processed bulk dust. The bulk dust contained 130.000-160.000 CFU g -1 microorganisms and 71.000-90.000 CFU g -1 microfungi. The content of culturable microfungi was 65-123 CFU 30 g -1 dust. The content of endotoxins ranged from 5.06-7.24 EU g -1 (1.45 ng g -1 to 1.01 ng g -1). Allergens (ng g -1) were from 147-159 (Mite), 395-746 (dog) and 103-330 (cat). The macro molecular organic compounds (the MOD-content) varied from 7.8-9.8 mg g -1. The threshold of release of histamine from basophil leukocytes provoked by the bulk dust was between 0.3 and 1.0 mg ml -1. The water content was 2% (WGT) and the organic fraction 33%. 6.5-5.9% (dry) was water soluble. The fiber content was less than 0.2-1.5% (WGT) and the desorbable VOCs was 176-319 μg g -1. Most of the VOC were aldehydes. However, softeners for plastic (DBP and DEHP) were present. The chemical composition includes human and animal skin fragments, paper fibers, glass wool, wood and textilefibers and inorganic and metal particles. The sizes ranged from 0.001-1 mm and the average specific density was 1.0 g m -3. The bulk dust was resuspended and injected into an exposure chamber. The airborne dust was sampled and analyzed to illustrate the exposures that can result from sedimented dirt and dust. The airborne dust resulting from the bulk dust reached concentrations ranging from 0.26-0.75 mg m -3 in average contained 300-170 CFU m -3. The organic fraction was from 55-70% and the water content about 2.5% (WGT). The content of the dust was compared to the similar results reported in the literature and its toxic potency is

  11. Dust Measurements in Tokamaks

    Energy Technology Data Exchange (ETDEWEB)

    Rudakov, D; Yu, J; Boedo, J; Hollmann, E; Krasheninnikov, S; Moyer, R; Muller, S; Yu, A; Rosenberg, M; Smirnov, R; West, W; Boivin, R; Bray, B; Brooks, N; Hyatt, A; Wong, C; Fenstermacher, M; Groth, M; Lasnier, C; McLean, A; Stangeby, P; Ratynskaia, S; Roquemore, A; Skinner, C; Solomon, W M

    2008-04-23

    Dust production and accumulation impose safety and operational concerns for ITER. Diagnostics to monitor dust levels in the plasma as well as in-vessel dust inventory are currently being tested in a few tokamaks. Dust accumulation in ITER is likely to occur in hidden areas, e.g. between tiles and under divertor baffles. A novel electrostatic dust detector for monitoring dust in these regions has been developed and tested at PPPL. In DIII-D tokamak dust diagnostics include Mie scattering from Nd:YAG lasers, visible imaging, and spectroscopy. Laser scattering resolves size of particles between 0.16-1.6 {micro}m in diameter; the total dust content in the edge plasmas and trends in the dust production rates within this size range have been established. Individual dust particles are observed by visible imaging using fast-framing cameras, detecting dust particles of a few microns in diameter and larger. Dust velocities and trajectories can be determined in 2D with a single camera or 3D using multiple cameras, but determination of particle size is problematic. In order to calibrate diagnostics and benchmark dust dynamics modeling, pre-characterized carbon dust has been injected into the lower divertor of DIII-D. Injected dust is seen by cameras, and spectroscopic diagnostics observe an increase of carbon atomic, C2 dimer, and thermal continuum emissions from the injected dust. The latter observation can be used in the design of novel dust survey diagnostics.

  12. Dust characterization in FTU tokamak

    Energy Technology Data Exchange (ETDEWEB)

    De Angeli, M., E-mail: deangeli@ifp.cnr.it [Istituto di Fisica del Plasma – Consiglio Nazionale delle Ricerche, Milan (Italy); Maddaluno, G. [ENEA Unità Tecnica Fusione, C.R. ENEA Frascati, CP65, 00044 Frascati (Italy); Laguardia, L. [Istituto di Fisica del Plasma – Consiglio Nazionale delle Ricerche, Milan (Italy); Ripamonti, D. [Istituto per l’Energetica e le Interfasi – Consiglio Nazionale delle Ricerche, Milan (Italy); Perelli Cippo, E. [Istituto di Fisica del Plasma – Consiglio Nazionale delle Ricerche, Milan (Italy); Apicella, M.L. [ENEA Unità Tecnica Fusione, C.R. ENEA Frascati, CP65, 00044 Frascati (Italy); Conti, C. [Istituto per la Conservazione e la Valorizzazione dei Beni Culturali – CNR, Milan (Italy); Giacomi, G. [ENEA Unità Tecnica Fusione, C.R. ENEA Frascati, CP65, 00044 Frascati (Italy); Grosso, G. [Istituto di Fisica del Plasma – Consiglio Nazionale delle Ricerche, Milan (Italy)

    2015-08-15

    Dust present in the vessel of FTU has been collected and analysed. Being FTU a device with full metal plasma facing components for the whole life and equipped with a liquid lithium limiter (LLL) make FTU of special interest from a point of view of dust studies. Analyses were conducted by standard dust analysis methods and by dedicated analysis, as X-rays and neutron diffraction, to investigate the presence of lithium compounds due the presence of the LLL in FTU. Dust collected near the LLL presents a different elemental composition, namely Li compounds, compared to the dust collected in the rest of the vessel; in particular LiO{sub 2}, LiOH, and Li{sub 2}CO{sub 3}. On the basis of these results, the formation of Li{sub 2}CO{sub 3} is proposed via a two steps process. Results of fuel retention measured by thermal desorption spectroscopy (TDS) method show that fuel retention should not be an issue for FTU.

  13. Household Characteristics That Influence Simple Household Demand on Electricity

    Directory of Open Access Journals (Sweden)

    Tongam Sihol Nababan

    2015-08-01

    Full Text Available This research aims to analyze the characteristics of households that affect the electric energy consumption of simple households. The second objective is to analyze the probability of each of the factors affecting the electricity energy consumption of small household. The research was conducted in Medan City in the period of March 2014 to November 2014 with samples of 143 small households, the customer of PT. PLN (Persero Medan, which use the power of electricity for TR-1 /450VA. Data were analyzed by using the logistic regression model. The estimation results indicated that (1 the higher the willingnes to pay (WTP of households, the higher the tendency to consume elec trical energy per month. (2 the closer the households residence to the city center, the higher the tendency to consume electrical energy than of the households residence in the suburbs, (3 increasingly unfavourable response to electrical quality, the higher the opportunity to consume a greater electric power monthly.

  14. Some Stars are Totally Metal: A New Mechanism Driving Dust Across Star-Forming Clouds, and Consequences for Planets, Stars, and Galaxies

    CERN Document Server

    Hopkins, Philip F

    2014-01-01

    Dust grains in neutral gas behave as aerodynamic particles, so they can develop large local density fluctuations entirely independent of gas density fluctuations. Specifically, gas turbulence can drive order-of-magnitude 'resonant' fluctuations in the dust density on scales where the gas stopping/drag timescale is comparable to the turbulent eddy turnover time. Here we show that for large grains (size >0.1 micron, containing most grain mass) in sufficiently large molecular clouds (radii >1-10 pc, masses >10^4 solar), this scale becomes longer than the characteristic sizes of pre-stellar cores (the sonic length), so large fluctuations in the dust-to-gas ratio are imprinted on cores. As a result, star clusters and protostellar disks formed in large clouds should exhibit substantial abundance spreads in the elements preferentially found in large grains (C, O, Si). This naturally predicts populations of carbon-enhanced stars, certain highly unusual stellar populations observed in nearby open clusters, and may exp...

  15. Recycling of steelmaking dusts: The Radust concept

    Directory of Open Access Journals (Sweden)

    Jalkanen H.

    2005-01-01

    Full Text Available Recycling of dusts and other wastes of steelmaking is becoming to a necessity of two reasons: due to high contents of iron oxides dusts are valuable raw material for steelmaking and tightening environmental legislation makes the landfill disposal of wastes more expensive. Fine dust fractions from various stages of steelmaking route contain besides iron and carbon heavy metals especially zinc and lead and heavy hydrocarbons that are acceptable neither for landfill disposal nor for recycling back to processes without any spe4cial treatments. Some theoretical and practical aspects concerning high temperature treatments of steelmaking dusts for removal of hazardous components and production of clean high iron raw material for recycling is discussed in this paper. The Radust technology developed at Koverhar steelwork in Finland for treatment of the most problematic fine fractions of blast furnace and oxygen converter dusts is shortly presented and discussed.

  16. The Household Planning Game

    DEFF Research Database (Denmark)

    Koch, Louise; Ramsøy, Thomas Z.; Nyström, Marcus

    2014-01-01

    Two common reasons why people end up in personal financial problems are either because they have not learned to manage a budget, or because they have unrealistic expectations of what they can afford to buy. To assess potential level for risk-seeking behavior in daily life, we created a novel test...... - The Household Planning Game (HPG) - modelled upon the well-known Iowa Gambling Task (IGT). The basic foundations of the HPG were largely the same as the IGT, however illustrations of consumer goods were positioned at the top of the cards, and the participant's task was to select a card as if it was a natural...... on the same schedule as in the IGT. Eighteen university students performed the HPG, which was separated into three conditions containing 100 trials. During the game, participants were asked to; 1) pay a number of fixed monthly costs or save money for various household costs; 2) purchase a number of consumer...

  17. Lumped Thermal Household Model

    DEFF Research Database (Denmark)

    Biegel, Benjamin; Andersen, Palle; Stoustrup, Jakob

    2013-01-01

    a lumped model approach as an alternative to the individual models. In the lumped model, the portfolio is seen as baseline consumption superimposed with an ideal storage of limited power and energy capacity. The benefit of such a lumped model is that the computational effort of flexibility optimization......In this paper we discuss two different approaches to model the flexible power consumption of heat pump heated households: individual household modeling and lumped modeling. We illustrate that a benefit of individual modeling is that we can overview and optimize the complete flexibility of a heat...... pump portfolio. Following, we illustrate two disadvantages of individual models, namely that it requires much computational effort to optimize over a large portfolio, and second that it is difficult to accurately model the houses in certain time periods due to local disturbances. Finally, we propose...

  18. Pollution analysis and evaluation of heavy metals in urban dust in Guiyang%贵阳市区地表灰尘重金属污染分析与评价

    Institute of Scientific and Technical Information of China (English)

    张一修; 王济; 张浩

    2011-01-01

    以贵阳市区为研究地点,采集了贵阳城区工业区、交通区、商业区、居民区、文教区、公园广场、对照区7个类别共80个采样点的地表灰尘,分析了地表灰尘重金属在不同区域的分布特征,并分析其可能来源.最后,应用潜在生态危害指数法对6个功能区(工业区、交通区、商业区、居民区、文教区、公共区)样品中重金属的潜在生态危害进行评价.结果表明:贵阳市地表灰尘重金属的平均质量分数均高于贵州省土壤环境背景值,Cd、As、Cu污染质量分数都超过4倍以上背景值水平,其余重金属污染水平大多处于1~3倍背景值水平.就单个重金属潜在生态危害系数平均值来看,地表灰尘的潜在生态危害最大的是Hg,其次是Cd,生态危害最低的是Cr.6个功能区生态危害水平均属于强生态危害水平,其中工业区和公共区生态危害水平最高.%This study focused on characterization of heavy metals in the dust of the city of Guiyang. 80 surfacial dust samples were collected from 7 land-use types, such as industrial area, traffic area, commercial area, residential area, cultural and educational area,public and square area, as well as contrast area. Distribution characterization and possible sources of heavy metals of Hg, Cd, As, Pb,Cr, Cu, Ni and Zn were analysised. Potential ecological risk index was adopted to estimate the potential ecological risk of 6 land-use types(traffic areas, industrial area, commercial areas, residential area, cultural and educational area, public and square area). The results showed that the average concentration of heavy metals in the dust exceeded the soil background value in Guizhou. Cd, As, Cu were 4 times of the soil background value in Guizhou, the other heavy metals were 1-3 times of the soil background value. Based on the calculation results of heavy metal ecological risk index in street surface dust of Guiyang potential ecological risk of Hg was the

  19. Shotgun pyrosequencing metagenomic analyses of dusts from swine confinement and grain facilities.

    Directory of Open Access Journals (Sweden)

    Robert J Boissy

    Full Text Available Inhalation of agricultural dusts causes inflammatory reactions and symptoms such as headache, fever, and malaise, which can progress to chronic airway inflammation and associated diseases, e.g. asthma, chronic bronchitis, chronic obstructive pulmonary disease, and hypersensitivity pneumonitis. Although in many agricultural environments feed particles are the major constituent of these dusts, the inflammatory responses that they provoke are likely attributable to particle-associated bacteria, archaebacteria, fungi, and viruses. In this study, we performed shotgun pyrosequencing metagenomic analyses of DNA from dusts from swine confinement facilities or grain elevators, with comparisons to dusts from pet-free households. DNA sequence alignment showed that 19% or 62% of shotgun pyrosequencing metagenomic DNA sequence reads from swine facility or household dusts, respectively, were of swine or human origin, respectively. In contrast only 2% of such reads from grain elevator dust were of mammalian origin. These metagenomic shotgun reads of mammalian origin were excluded from our analyses of agricultural dust microbiota. The ten most prevalent bacterial taxa identified in swine facility compared to grain elevator or household dust were comprised of 75%, 16%, and 42% gram-positive organisms, respectively. Four of the top five swine facility dust genera were assignable (Clostridium, Lactobacillus, Ruminococcus, and Eubacterium, ranging from 4% to 19% relative abundance. The relative abundances of these four genera were lower in dust from grain elevators or pet-free households. These analyses also highlighted the predominance in swine facility dust of Firmicutes (70% at the phylum level, Clostridia (44% at the Class level, and Clostridiales at the Order level (41%. In summary, shotgun pyrosequencing metagenomic analyses of agricultural dusts show that they differ qualitatively and quantitatively at the level of microbial taxa present, and that the

  20. Galaxy Simulation with Dust Formation and Destruction

    CERN Document Server

    Aoyama, Shohei; Shimizu, Ikkoh; Hirashita, Hiroyuki; Todoroki, Keita; Choi, Jun-Hwan; Nagamine, Kentaro

    2016-01-01

    We perform smoothed particle hydrodynamics (SPH) simulations of an isolated galaxy with a new treatment for dust formation and destruction. To this aim, we treat dust and metal production self-consistently with star formation and supernova feedback. For dust, we consider a simplified model of grain size distribution by representing the entire range of grain sizes with large and small grains. We include dust production in stellar ejecta, dust destruction by supernova (SN) shocks, grain growth by accretion and coagulation, and grain disruption by shattering. We find that the assumption of fixed dust-to-metal mass ratio becomes no longer valid when the galaxy is older than 0.2 Gyr, at which point the grain growth by accretion starts to contribute to the nonlinear rise of dust-to-gas ratio. As expected in our previous one-zone model, shattering triggers grain growth by accretion since it increases the total surface area of grains. Coagulation becomes significant when the galaxy age is greater than $\\sim$ 1 Gyr: a...

  1. HD/H2 as a probe of the roles of gas, dust, light, metallicity and cosmic rays in promoting the growth of molecular hydrogen in the diffuse interstellar medium

    CERN Document Server

    Liszt, H S

    2014-01-01

    We modelled recent observations of UV absorption of HD and \\HH\\ in the Milky Way and toward damped/sub-damped Lyman alpha systems at z=0.18 and z $>$ 1.7. N(HD)/N(\\HH) ratios reflect the separate self-shieldings of HD and \\HH\\ and the coupling introduced by deuteration chemistry. Locally, observations are explained by diffuse molecular gas with $ 16 \\pccc \\la$ n(H) $\\la 128 \\pccc $ if the cosmic-ray ionization rate per H-nucleus \\zetaH $= 2\\times 10^{-16}\\ps$ as inferred from \\H3\\p\\ and OH\\p. The dominant influence on N(HD)/N(\\HH) is the cosmic-ray ionization rate with a much weaker downward dependence on n(H) at Solar metallicity, but dust-extinction can drive N(HD) higher as with N(\\HH). At z $>$ 1.7, N(HD) is comparable to the Galaxy but with 10x smaller N(\\HH) and somewhat smaller N(\\HH)/N(H I). Comparison of our Galaxy and the Magellanic Clouds shows that smaller \\HH/H is expected at sub-Solar metallicity and we show by modelling that HD/\\HH\\ increases with density at low metallicity, opposite to the Mil...

  2. Dust properties of Lyman break galaxies in cosmological simulations

    CERN Document Server

    Yajima, Hidenobu; Thompson, Robert; Choi, Jun-Hwan

    2013-01-01

    Recent observations have indicated the existence of dust in high-redshift galaxies, however, the dust properties in them are still unknown. Here we present theoretical constraints on dust properties in Lyman break galaxies (LBGs) at z=3 by post-processing a cosmological smoothed particle hydrodynamics simulation with radiative transfer calculations. We calculate the dust extinction in 2800 dark matter halos using the metallicity information of individual gas particles in our simulation. We use only bright galaxies with rest-frame UV magnitude M_1700 < -20 mag, and study the dust size, dust-to-metal mass ratio, and dust composition. From the comparison of calculated color excess between B and V-band (i.e., E(B-V)) and the observations, we constrain the typical dust size, and show that the best-fitting dust grain size is ~ 0.05 micron, which is consistent with the results of theoretical dust models for Type-II supernova. Our simulation with the dust extinction effect can naturally reproduce the observed rest...

  3. Households at Pella, Jordan

    DEFF Research Database (Denmark)

    Walmsley, Alan George

    2007-01-01

    The excavation of six courtyard houses at Pella in the Jordan Valley, destroyed in a massive earthquake in the mid-eighth century AD, gives an exceptional opportunity to study a wide range of objectives from daily life within a secure archaeological context. The recovery of detailed information...... about the layout of buildings and the contextual origin of the many domestic objects recovered permit a full reconstruction of life in the household, especially the use of space. Generally, the upstairs area served as the primary living quarters, whereas the ground floor was used to house valuable...

  4. 西安市城区街道灰尘重金属含量水平及风险评价%The content levels and health risk assessment of heavy metals in street dust in Xi′an

    Institute of Scientific and Technical Information of China (English)

    范汇晨; 谭志海; 刘倩

    2016-01-01

    针对重金属污染与人体健康之间的关系,利用原子吸收光谱法测定西安市各功能区主要街道的灰尘中Pb、Cu、Cr、Cd和Zn的含量,并依据美国环保局(US EPA )人体暴露风险评估方法对街道灰尘重金属进行健康风险评估,结果表明,西安市街道灰尘重金属含量总体水平略高,均超过西安市土壤背景值;周内和周末西安市街道灰尘中重金属含量不同,周内重金属含量排序为:商业区>重工业区>旅游区>文教区>轻工业区;周末重金属含量排序为:重工业区>旅游区>商业区>文教区>轻工业区。暴露及风险评估结果表明:手‐口途径是人体摄入重金属最主要的途径,其次为皮肤和呼吸途径;重金属对于人体的非致癌风险表现为:Pb>Cu>Zn ,均小于风险阈值1,不会对人体造成健康危害,且儿童的非致癌风险大于成人;重金属Cd和Cr尚未形成致癌风险。%Street dust in main streets of Xi′an was collected for identifying the relationship be‐tween human health and heavy metal pollution .Pb ,Cu ,Cr ,Cd and Zn in the dust samples were investigated by atomic absorption spectrometry .Health risk assessment of heavy metals in the street dust was carried out using the US EPA health risk assessment model .The results show that the level of heavy metals is higher compared with the background values in Xi′an soil .In the weekdays ,the range of heavy metal contents is as follows :commercial area> heavy indus‐trial area> tourist area> cultural and eductional area> light industrial area ;at the weekends :heavy industry area> tourist area> commercial area> cultural and educational area> light in‐dustry area .The health risk assessment results show that the hand‐mouth way is the major one for human to take in heavy metals ,followed by pathways of skin and respiration .The range of non‐cancer hazard risks is Pb>Cu>Zn ,all less than risk

  5. Pollution Comes Home and Gets Personal: Women's Experience of Household Chemical Exposure

    Science.gov (United States)

    Altman, Rebecca Gasior; Morello-Frosch, Rachel; Brody, Julia Green; Rudel, Ruthann; Brown, Phil; Averick, Mara

    2008-01-01

    We report on interviews conducted with participants in a novel study about environmental chemicals in body fluids and household air and dust. Interviews reveal how personal and collective environmental history influence the interpretation of exposure data, and how participants fashion an emergent understanding of environmental health problems from…

  6. The dust content of galaxies from z = 0 to z = 9

    CERN Document Server

    Popping, Gergö; Galametz, Maud

    2016-01-01

    We study the dust content of galaxies from z $=$ 0 to z $=$ 9 in semi-analytic models of galaxy formation that include new recipes to track the production and destruction of dust. We include condensation of dust in stellar ejecta, the growth of dust in the interstellar medium (ISM), the destruction of dust by supernovae and in the hot halo, and dusty winds and inflows. The rate of dust growth in the ISM depends on the metallicity and density of molecular clouds. Our fiducial model reproduces the relation between dust mass and stellar mass from z $=$ 0 to z $=$ 7, the dust-to-gas ratio of local galaxies as a function of stellar mass, the double power law trend between dust-to- gas ratio and gas-phase metallicity, the number density of galaxies with dust masses less than $10^{8.3} M_\\odot$, and the cosmic density of dust at z $=$ 0. The dominant mode of dust formation is dust growth in the ISM, except for galaxies with $M_* < 10^7 M_\\odot$, where condensation of dust in supernova ejecta dominates. The dust-t...

  7. Household fuel demand analysis

    Energy Technology Data Exchange (ETDEWEB)

    Cohn, S.; Hirst, E.; Jackson, J.

    1976-01-01

    This study develops econometric models of residential demands for electricity, natural gas, and petroleum products. Fuel demands per household are estimated as functions of fuel prices, per capita income, heating degree days, and mean July temperature. Cross-sectional models are developed using a large data base containing observations for each state and year from 1951 through 1974. Long-run own-price elasticities for all three fuels are greater than unity with natural gas showing the greatest sensitivity to own-price changes. Cross-price elasticities are all less than unity except for the elasticity of demand for oil with respect to the price of gas (which is even larger than the own-price elasticity of demand for oil). The models show considerable stabiity with respect to own-price elasticities but much instability with respect to the cross-price and income elasticities.

  8. Cold dust clumps in dynamically hot gas

    CERN Document Server

    Kim, S; Madden, S C; Meixner, M; Hony, S; Panuzzo, P; Sauvage, M; Roman-Duval, J; Gordon, K D; Engelbracht, C; Israel, F P; Misselt, K; Okumura, K; Li, A; Bolatto, A; Skibba, R; Galliano, F; Matsuura, M; Bernard, J -P; Bot, C; Galametz, M; Hughes, A; Kawamura, A; Onishi, T; Paradis, D; Poglitsch, A; Reach, W T; Robitaille, T; Rubio, M; Tielens, A G G M

    2010-01-01

    We present clumps of dust emission from Herschel observations of the Large Magellanic Cloud (LMC) and their physical and statistical properties. We catalog cloud features seen in the dust emission from Herschel observations of the LMC, the Magellanic type irregular galaxy closest to the Milky Way, and compare these features with HI catalogs from the ATCA+Parkes HI survey. Using an automated cloud-finding algorithm, we identify clouds and clumps of dust emission and examine the cumulative mass distribution of the detected dust clouds. The mass of cold dust is determined from physical parameters that we derive by performing spectral energy distribution fits to 250, 350, and 500 micronm emission from SPIRE observations using DUSTY and GRASIL radiative transfer calculation with dust grain size distributions for graphite/silicate in low-metallicity extragalactic environments. The dust cloud mass spectrum follows a power law distribution with an exponent of gamma=-1.8 for clumps larger than 400 solar mass and is si...

  9. Physics of interstellar dust

    CERN Document Server

    Krugel, Endrik

    2002-01-01

    The dielectric permeability; How to evaluate grain cross sections; Very small and very big particles; Case studies of Mie calculus; Particle statistics; The radiative transition probability; Structure and composition of dust; Dust radiation; Dust and its environment; Polarization; Grain alignment; PAHs and spectral features of dust; Radiative transport; Diffuse matter in the Milky Way; Stars and their formation; Emission from young stars. Appendices Mathematical formulae; List of symbols.

  10. Bioavailability of Heavy Metals in Urban Surface Dust and Rainfall-Runoff System%城市地表灰尘-降雨径流系统重金属生物有效性研究

    Institute of Scientific and Technical Information of China (English)

    常静; 刘敏; 李先华; 林啸; 王丽丽; 高磊

    2009-01-01

    以上海中心城区为例,定点采集地表灰尘、径流悬浮物、雨水口和河流沉积物,探讨重金属在地表灰尘一降雨径流系统中的环境行为及其生物有效性变化.研究表明,研究区域地表灰尘重金属浓度高于上海土壤背景值,其中Zn、Pb、Cd和Cu高出5~7倍,Cr和Ni高出2倍,径流非点源污染Pb、Cr和Ni贡献较大,Cd、Cu和Zn污染程度较轻.多介质赋存形态研究表明,重金属生物有效性依次为Zn>Ni>Cd>Cu>Pb>Cr.其中Cr、Zn和Cu在4种介质中分别以残渣态、碳酸盐态和有机态为主;Ni地表灰尘以残渣态为主,其它3种介质以碳酸盐态为主;Cd地表灰尘以有机态为主,径流悬浮物以非稳定形态为主;Ph在迁移过程中主导形态由铁锰结合态变为有机态.非稳定形态(F1+F2)在径流悬浮物组分中占有最高比例,6种重金属迁移比率平均值为1.74,说明从地表灰尘到径流颗粒物,重金属生物有效性明显升高,径流水体毒性和潜在生态效应值得关注;雨水口和河流沉积物残渣态含量较高,成为重金属在城市地表环境迁移的蓄积库.%A sequential digest was used to examine the speciation of particulate-associated heavy metals in multi-media environment of surface dust and rainfall-runoff system. Within the Shanghai central district, different environment medium in four sites were sampled including street dust, runoff suspended particles, gully pot sediment and river sediment during April 2006. The result shows that in the study area, heavy metal concentrations of surface dusts are significantly higher than the Shanghai soil background values and the nonpoint runoff pollution of Pb, Cr and Ni are serious while Cd, Cu and Zn pollution degree relatively light. In the multi-media transport process, the order of heavy metal bioavailability is Zn>Ni>Cd>Cu>Pb>Cr. For Cr, Zn and Cu, the dominated chemical forms of the four different environmental media remain the same phase of

  11. 铜陵市区表土与灰尘重金属污染健康风险评估%Heavy metal contamination and health risk assessment for urban topsoil and dust in Tongling City

    Institute of Scientific and Technical Information of China (English)

    李如忠; 潘成荣; 陈婧; 姜艳敏; 丁贵珍

    2012-01-01

    以典型有色金属矿山城市铜陵市为对象,从工业用地、居住用地、商贸用地、文教用地、交通用地和城市广场等6种主要用地类型中,选择64个采样点位,采集表土和不透水地面灰尘样.在对Pb、Cu、Cr、Zn、Ni、As和Cd含量分析测试的基础上,利用美国国家环保局(US EPA)推荐的健康风险评价模型,就儿童和成人群体在不同功能用地、不同暴露途径下的重金属致癌和非致癌风险进行分析和评估,并对表土与灰尘的健康风险效应进行比较.结果表明:铜陵市表土与灰尘重金属含量显著高于该市土壤背景值,意味着铜陵城区土壤和地表灰尘已遭受较为严重的重金属污染;重金属Cr、Ni、As和Cd的致癌风险均值分别为4.30×10-7、7.18×10-9、4.26×10-4和7.58×l0-8,不同功能用地的致癌风险均显著超过US EPA推荐的可接受风险阈值范围10-6~10-4和国际辐射防护委员会(ICRP)推荐的最大可按受风险值5.0×10-5;表土与灰尘的儿童非致癌风险分别高达5.20和16.58,灰尘对成人的非致癌风险达2.80,都远高于安全阈值1.0,表明铜陵市表土与地表灰尘已对公众身体健康构成危害;主导致癌与非致癌风险效应的主要污染因子是As,主要暴露途径是手-口摄入途径.%This research focused on the potential health risk assessment of heavy metals (including As) pollution in urban topsoil and dust from Tongling, a typical nonferrous metal mining city, China. Samples were collected from sixty four sampling sites covering six land-use types, that is, industrial, residential, commercial, educational and traffic areas, as well as city squares. The heavy metal (Pb, Cu, Cr, Zn, Ni, As and Cd) contents of all samples were analyzed and health risk assessment were conducted for children and adult respectively, using the risk models recommended by the United States Environmental Protection Agency (US EPA). The levels of heavy metal elements in

  12. Household Structure and Living Conditions in Nigeria

    Science.gov (United States)

    Mberu, Blessing Uchenna

    2007-01-01

    Data on 7,632 households from the 1999 Nigeria Demographic and Health Survey are used to examine household structure and living conditions in Nigeria. The study finds significant disadvantage in living conditions of single-adult, female- and single-adult, male-headed households relative to two-parent households. Extended households show no…

  13. Feedback on household electricity consumption

    DEFF Research Database (Denmark)

    Grønhøj, Alice; Thøgersen, John

    2011-01-01

    consumption, we evaluate the effects of giving households detailed feedback about their electricity consumption on a small liquid crystal display (LCD) screen. Twenty Danish households participated in the study over a 5-month period. A new feedback system was developed in a user-involved innovation process...

  14. Dust in the Universe

    Science.gov (United States)

    Hemenway, Mary Kay; Armosky, Brad J.

    2004-01-01

    Space is seeming less and less like empty space as new discoveries and reexaminations fill in the gaps. And, ingenuity and technology, like the Spitzer Space Telescope, is allowing examination of the far reaches of the Milky Way and beyond. Even dust is getting its due, but not the dust everyone is familiar with. People seldom consider the dust in…

  15. Household waste recycling behaviour in South Africa - has there been progress in the last 5 years?

    CSIR Research Space (South Africa)

    Strydom, Wilma F

    2016-10-01

    Full Text Available towns and rural areas lag even further behind in terms of dedicated recycling households, at only 2.6%. Of the four paper and packaging recyclables surveyed (plastic, paper, glass, metal), plastic showed the largest increase in percentage of households...

  16. Dust Combustion Safety Issues for Fusion Applications

    Energy Technology Data Exchange (ETDEWEB)

    L. C. Cadwallader

    2003-05-01

    This report summarizes the results of a safety research task to identify the safety issues and phenomenology of metallic dust fires and explosions that are postulated for fusion experiments. There are a variety of metal dusts that are created by plasma erosion and disruptions within the plasma chamber, as well as normal industrial dusts generated in the more conventional equipment in the balance of plant. For fusion, in-vessel dusts are generally mixtures of several elements; that is, the constituent elements in alloys and the variety of elements used for in-vessel materials. For example, in-vessel dust could be composed of beryllium from a first wall coating, tungsten from a divertor plate, copper from a plasma heating antenna or diagnostic, and perhaps some iron and chromium from the steel vessel wall or titanium and vanadium from the vessel wall. Each of these elements has its own unique combustion characteristics, and mixtures of elements must be evaluated for the mixture’s combustion properties. Issues of particle size, dust temperature, and presence of other combustible materials (i.e., deuterium and tritium) also affect combustion in air. Combustion in other gases has also been investigated to determine if there are safety concerns with “inert” atmospheres, such as nitrogen. Several coolants have also been reviewed to determine if coolant breach into the plasma chamber would enhance the combustion threat; for example, in-vessel steam from a water coolant breach will react with metal dust. The results of this review are presented here.

  17. 贵阳城区垃圾站周边地表灰尘重金属水平及季节分异%The Pollution Status of Dust Heavy Metals around Refuse Transfer Stations in Guiyang City

    Institute of Scientific and Technical Information of China (English)

    胡军; 李晓燕; 曹益金

    2012-01-01

    以贵阳城区垃圾转运站为研究对象,分别于夏季(7月)和冬季(2月)在垃圾站周边采集灰尘样品共26个,研究垃圾转运站地表灰尘重金属水平及冬、夏季节分布规律。结果显示,贵阳市城区垃圾站地表灰尘As、Cd、Cu、Ni、Pb和Zn的几何平均值分别为19.8、0.975、156、43.4、99.1和416mg/kg,与贵州省土壤背景值相比,Cd、Cu和Pb累积较重,As和Ni累积较轻。位于次级街道的垃圾站地表灰尘重金属水平显著高于位于城市主干道的垃圾站,垃圾站周边环境和清洁程度的不同可能是导致地表灰尘重金属空间差异的主要原因。贵阳市城区垃圾站灰尘重金属冬、夏季节分异总体表现不明显,但位于次级街道的垃圾站地表灰尘Cd和Pb含量冬季高于夏季。%A survey was conducted to investigate the content distribution of heavy metals in dusts around garbage stations in Guiyang based on 26 dust samples collected in summer and winter. The results showed that the geometric concentrations of As, Cd, Cu, Ni, Pb and Zn around garbage stations in Guiyang were 19.8, 0. 975, 156, 43.4, 99.1 and 416 mg/kg, respec- tively. Compared to the elemental background values of Guizhou soil, the data showed that Cd, Cu and Zn were relatively heav- ily accumulated while As and Ni were slightly accumulated. The garbage stations located in secondary streets had higher heavy metal concentrations in dust than those located in main thoroughfares, which were mainly conducted by different environments and the cleaning state of these garbage stations. For all garbage stations, there was no significant difference in heavy metal con- centrations in summer and winter, while the garbage stations located in the secondary streets had higher concentrations of Cd and Pb in winter than in summer.

  18. Comparative absorption and bioaccumulation of polybrominated diphenyl ethers following ingestion via dust and oil in male rats

    Science.gov (United States)

    Household dust has been implicated as a major source of polybrominated diphenyl ether (PBDE) exposure in humans. This finding has important implications especially for young children, who tend to ingest more dust than adults and may be more susceptible to some of the putative developmental effects ...

  19. An Intensely Star-Forming Galaxy at z~7 with Low Dust and Metal Content Revealed by Deep ALMA and HST Observations

    CERN Document Server

    Ouchi, Masami; Ono, Yoshiaki; Nakanishi, Kouichiro; Kohno, Kotaro; Momose, Rieko; Kurono, Yasutaka; Ashby, M L N; Shimasaku, Kazuhiro; Willner, S P; Fazio, G G; Tamura, Yoichi; Iono, Daisuke

    2013-01-01

    We report deep ALMA observations complemented with associated HST imaging for a luminous (m_uv=25) galaxy, 'Himiko', at a redshift z=6.595. The galaxy is remarkable for its high star formation rate, 100 Mo/yr, securely estimated from our deep HST and Spitzer photometry, and the absence of any evidence for strong AGN activity or gravitational lensing magnification. Our ALMA observations probe an order of magnitude deeper than previous IRAM observations, yet fail to detect a 1.2mm dust continuum, indicating a flux <52uJy comparable with or weaker than that of local dwarf irregulars with much lower star formation rates. We likewise provide a strong upper limit for the flux of [CII] 158um, L([CII]) < 5.1x10^7 Lo, a diagnostic of the hot interstellar gas often described as a valuable probe for early galaxies. In fact, our observations indicate Himiko lies off the local L([CII]) - star formation rate scaling relation by a factor of more than 30. Both aspects of our ALMA observations suggest Himiko is an uniqu...

  20. Characterisation of atmospheric deposited particles during a dust storm in urban areas of Eastern Australia.

    Science.gov (United States)

    Gunawardena, Janaka; Ziyath, Abdul M; Bostrom, Thor E; Bekessy, Lambert K; Ayoko, Godwin A; Egodawatta, Prasanna; Goonetilleke, Ashantha

    2013-09-01

    The characteristics of dust particles deposited during the 2009 dust storm in the Gold Coast and Brisbane regions of Australia are discussed in this paper. The study outcomes provide important knowledge in relation to the potential impacts of dust storm related pollution on ecosystem health in the context that the frequency of dust storms is predicted to increase due to anthropogenic desert surface modifications and climate change impacts. The investigated dust storm contributed a large fraction of fine particles to the environment with an increased amount of total suspended solids, compared to dry deposition under ambient conditions. Although the dust storm passed over forested areas, the organic carbon content in the dust was relatively low. The primary metals present in the dust storm deposition were aluminium, iron and manganese, which are common soil minerals in Australia. The dust storm deposition did not contain significant loads of nickel, cadmium, copper and lead, which are commonly present in the urban environment. Furthermore, the comparison between the ambient and dust storm chromium and zinc loads suggested that these metals were contributed to the dust storm by local anthropogenic sources. The potential ecosystem health impacts of the 2009 dust storm include, increased fine solids deposition on ground surfaces resulting in an enhanced capacity to adsorb toxic pollutants as well as increased aluminium, iron and manganese loads. In contrast, the ecosystem health impacts related to organic carbon and other metals from dust storm atmospheric deposition are not considered to be significant.

  1. Dust origin in late-type dwarf galaxies: ISM growth vs. type II supernovae

    CERN Document Server

    Zhukovska, Svitlana

    2014-01-01

    We re-evaluate the roles of different dust sources in dust production as a function of metallicity in late-type dwarf galaxies, with the goal of understanding the relation between dust content and metallicity. The dust content ol late-type dwarf galaxies with episodic star formation is studied with a multicomponent model of dust evolution, which includes dust input from AGB stars, type II SNe and dust growth by accretion of atoms in the ISM. Dust growth in the ISM becomes an important dust source in dwarf galaxies, on the timescale of 0.1 - a few Gyrs. It increases the dust-to-gas ratio (DGR) during post-burst evolution, unlike type II SNe, which eject grains to the ISM only during starbursts. Before the dust growth in the ISM overtakes the dust production, AGB stars can be major sources of dust in metal-poor dwarf galaxies. Our models reproduce the relation between the DGR and oxygen abundance, derived from observations of a large sample of dwarf galaxies. The steep decrease in the DGR at low O values is exp...

  2. The chemistry of dust formation in red supergiants

    CERN Document Server

    Cherchneff, Isabelle

    2013-01-01

    Massive stars in their late stages of evolution as Red Supergiants experience mass loss. The resulting winds show various degrees of dynamical and chemical complexity and produce molecules and dust grains. This review summarises our knowledge of the molecular and dust components of the wind of Red Supergiants, including VY CMa and Betelgeuse. We discuss the synthesis of dust as a non-equilibrium process in stellar winds, and present the current knowledge of the chemistry involved in the formation of oxygen-rich dust such as silicates and metal oxides.

  3. Evaluating levels and health risk of heavy metals in exposed workers from surgical instrument manufacturing industries of Sialkot, Pakistan.

    Science.gov (United States)

    Junaid, Muhammad; Hashmi, Muhammad Zaffar; Malik, Riffat Naseem

    2016-09-01

    The study aimed to monitor heavy metal (chromium, Cr; cadmium, Cd; nickel, Ni; copper, Cu; lead, Pb; iron, Fe; manganese, Mn; and zinc, Zn) footprints in biological matrices (urine, whole blood, saliva, and hair), as well as in indoor industrial dust samples, and their toxic effects on oxidative stress and health risks in exposed workers. Overall, blood, urine, and saliva samples exhibited significantly higher concentrations of toxic metals in exposed workers (Cr; blood 16.30 μg/L, urine 58.15 μg/L, saliva 5.28 μg/L) than the control samples (Cr; blood 5.48 μg/L, urine 4.47 μg/L, saliva 2.46 μg/L). Indoor industrial dust samples also reported to have elevated heavy metal concentrations, as an example, Cr quantified with concentration of 299 mg/kg of dust, i.e., more than twice the level of Cr in household dust (136 mg/kg). Superoxide dismutase (SOD) level presented significant positive correlation (p ≤ 0.01) with Cr, Zn, and Cd (Cr > Zn > Cd) which is an indication of heavy metal's associated raised oxidative stress in exposed workers. Elevated average daily intake (ADI) of heavy metals resulted in cumulative hazard quotient (HQ) range of 2.97-18.88 in workers of different surgical units; this is an alarming situation of health risk implications. Principal component analysis-multiple linear regression (PCA-MLR)-based pie charts represent that polishing and cutting sections exhibited highest metal inputs to the biological and environmental matrices than other sources. Heavy metal concentrations in biological matrices and dust samples showed a significant positive correlation between Cr in dust, urine, and saliva samples. Current study will help to generate comprehensive base line data of heavy metal status in biomatrices and dust from scientifically ignored industrial sector. Our findings can play vital role for health departments and industrial environmental management system (EMS) authorities in policy making and implementation.

  4. Toxicity of lunar dust

    CERN Document Server

    Linnarsson, Dag; Fubini, Bice; Gerde, Per; Karlsson, Lars L; Loftus, David J; Prisk, G Kim; Staufer, Urs; Tranfield, Erin M; van Westrenen, Wim

    2012-01-01

    The formation, composition and physical properties of lunar dust are incompletely characterised with regard to human health. While the physical and chemical determinants of dust toxicity for materials such as asbestos, quartz, volcanic ashes and urban particulate matter have been the focus of substantial research efforts, lunar dust properties, and therefore lunar dust toxicity may differ substantially. In this contribution, past and ongoing work on dust toxicity is reviewed, and major knowledge gaps that prevent an accurate assessment of lunar dust toxicity are identified. Finally, a range of studies using ground-based, low-gravity, and in situ measurements is recommended to address the identified knowledge gaps. Because none of the curated lunar samples exist in a pristine state that preserves the surface reactive chemical aspects thought to be present on the lunar surface, studies using this material carry with them considerable uncertainty in terms of fidelity. As a consequence, in situ data on lunar dust...

  5. Household vehicles energy consumption 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-08-01

    Household Vehicles Energy Consumption 1994 reports on the results of the 1994 Residential Transportation Energy Consumption Survey (RTECS). The RTECS is a national sample survey that has been conducted every 3 years since 1985. For the 1994 survey, more than 3,000 households that own or use some 6,000 vehicles provided information to describe vehicle stock, vehicle-miles traveled, energy end-use consumption, and energy expenditures for personal vehicles. The survey results represent the characteristics of the 84.9 million households that used or had access to vehicles in 1994 nationwide. (An additional 12 million households neither owned or had access to vehicles during the survey year.) To be included in then RTECS survey, vehicles must be either owned or used by household members on a regular basis for personal transportation, or owned by a company rather than a household, but kept at home, regularly available for the use of household members. Most vehicles included in the RTECS are classified as {open_quotes}light-duty vehicles{close_quotes} (weighing less than 8,500 pounds). However, the RTECS also includes a very small number of {open_quotes}other{close_quotes} vehicles, such as motor homes and larger trucks that are available for personal use.

  6. How much do South African households in towns & rural areas recycle?

    CSIR Research Space (South Africa)

    Strydom, Wilma

    2016-10-01

    Full Text Available . For individual waste streams, the highest percentage of households recycling some (not “nothing”, i.e. any quantity from “very little” to “everything”) is obtained for plastic (13.7%), followed by glass (12.3%) and paper (10.0%). Nine percent (9.4%) of households... in large urban areas recycle metal and 6.4% WEEE (percentages not shown on graph; sum of percentages of not “nothing”). When considering only those households recycling more than half of their recyclables (“Top 3” i.e. households recycling “everything...

  7. Farm Households Food Production and Households' Food Security ...

    African Journals Online (AJOL)

    food security status based on Dietary Energy Consumed (DEC) per Adult Equivalent (AE) per day, identifies ..... also conducted to supplement information collected through the ...... self-sufficient households to sustain their lives but not to make ...

  8. Solid-waste management practices of households in Manila, Philippines.

    Science.gov (United States)

    Bernardo, Eileen C

    2008-10-01

    The experiences and practices of household waste management of people in a barangay (village) in Manila, Philippines are documented. The data were gathered through an interview with household members using open-ended questions. Interviews were also conducted with garbage collectors as well as scavengers. Results showed that the households generated an average of 3.2 kg of solid waste per day, or 0.50 kg/capita/day. The types of wastes commonly generated are food/kitchen wastes, papers, PET bottles, metals, and cans, boxes/cartons, glass bottles, cellophane/plastics, and yard/garden wastes. The respondents segregate their wastes into PET bottles, glass bottles, and other waste (mixed wastes). No respondents perform composting. It is worth noting, however, that burning of waste is not done by the respondents. The households rely on garbage collection by the government. Collection is done twice daily, except Sundays, and household members bring their garbage when the garbage truck arrives. However, there are those who dump their garbage in nondesignated pick-up points, usually in a corner of the street. The dumped garbage becomes a breeding ground for disease-causing organisms. Some household respondents said that it is possible that the dumping in certain areas caused the dengue fever suffered by some of their family members. Mothers and household helpers are responsible for household waste management. Scavengers generally look for recyclable items in the dumped garbage. All of them said that it is their only source of income, which is generally not enough for their meals. They are also aware that their work affects their health. Most of the respondents said that garbage collection and disposal is the responsibility of the government. The results of the study showed that RA 9003, also known as the Ecological Solid Waste Management Act of 2000, is not fully implemented in Metro Manila.

  9. AN INFRARED CENSUS OF DUST IN NEARBY GALAXIES WITH SPITZER (DUSTINGS). I. OVERVIEW

    Energy Technology Data Exchange (ETDEWEB)

    Boyer, Martha L.; Sonneborn, George [Observational Cosmology Laboratory, Code 665, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); McQuinn, Kristen B. W.; Gehrz, Robert D.; Skillman, Evan [Minnesota Institute for Astrophysics, School of Physics and Astronomy, 116 Church Street SE, University of Minnesota, Minneapolis, MN 55455 (United States); Barmby, Pauline [Department of Physics and Astronomy, University of Western Ontario, London, ON, N6A 3K7 (Canada); Bonanos, Alceste Z. [IAASARS, National Observatory of Athens, GR-15236 Penteli (Greece); Gordon, Karl D.; Meixner, Margaret [STScI, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Groenewegen, M. A. T. [Royal Observatory of Belgium, Ringlaan 3, B-1180 Brussels (Belgium); Lagadec, Eric [Laboratoire Lagrange, UMR7293, Univ. Nice Sophia-Antipolis, CNRS, Observatoire de la Côte d' Azur, F-06300 Nice (France); Lennon, Daniel [ESA—European Space Astronomy Centre, Apdo. de Correo 78, E-28691 Villanueva de la Cañada, Madrid (Spain); Marengo, Massimo [Department of Physics and Astronomy, Iowa State University, Ames, IA 50011 (United States); Sloan, G. C. [Astronomy Department, Cornell University, Ithaca, NY 14853-6801 (United States); Van Loon, Jacco Th. [Astrophysics Group, Lennard-Jones Laboratories, Keele University, Staffordshire ST5 5BG (United Kingdom); Zijlstra, Albert, E-mail: martha.boyer@nasa.gov [Jodrell Bank Centre for Astrophysics, Alan Turing Building, University of Manchester, Manchester M13 9PL (United Kingdom)

    2015-01-01

    Nearby resolved dwarf galaxies provide excellent opportunities for studying the dust-producing late stages of stellar evolution over a wide range of metallicity (–2.7 ≲ [Fe/H] ≲ –1.0). Here, we describe DUSTiNGS (DUST in Nearby Galaxies with Spitzer): a 3.6 and 4.5 μm post-cryogen Spitzer Space Telescope imaging survey of 50 dwarf galaxies within 1.5 Mpc that is designed to identify dust-producing asymptotic giant branch (AGB) stars and massive stars. The survey includes 37 dwarf spheroidal, 8 dwarf irregular, and 5 transition-type galaxies. This near-complete sample allows for the building of statistics on these rare phases of stellar evolution over the full metallicity range. The photometry is >75% complete at the tip of the red giant branch for all targeted galaxies, with the exception of the crowded inner regions of IC 10, NGC 185, and NGC 147. This photometric depth ensures that the majority of the dust-producing stars, including the thermally pulsing AGB stars, are detected in each galaxy. The images map each galaxy to at least twice the half-light radius to ensure that the entire evolved star population is included and to facilitate the statistical subtraction of background and foreground contamination, which is severe at these wavelengths. In this overview, we describe the survey, the data products, and preliminary results. We show evidence for the presence of dust-producing AGB stars in eight of the targeted galaxies, with metallicities as low as [Fe/H] = –1.9, suggesting that dust production occurs even at low metallicity.

  10. Dusts in ITER: diagnostics and removal techniques

    Energy Technology Data Exchange (ETDEWEB)

    Rosanvallon, S.; Grisolia, C.; Worms, J.; Hong, S.H. [Association Euratom-CEA Cadarache (DRFC/SIPP), 13 - Saint-Paul-lez-Durance (France). Dept. de Recherches sur la Fusion Controlee; Delaporte, P. [Universite de la Mediterranee, LP3, UMR 6182 CNRS, 13 - Marseille (France); Onofrie, J.F. [University of Provence, IUSTI-CNRS, 13 - Marseille (France); Counsell, G. [Association Euratom/UKAEA, Culham Science Centre, Abingdon (United Kingdom); Winter, J. [lnstitute of Experimental Physics 2, Bochum (Germany)

    2007-07-01

    Full text of publication follows: Dusts will be present in ITER and will represent an issue in terms of safety. As a matter of facts, dusts will be created by interaction of the plasma with the in-vessel materials and will be thus made of carbon, beryllium and tungsten. They will be activated, tritiated and chemically toxic. Safety limits have been set in order to reduce these dust hazards. The first set of limits is based on a limitation of the radiological impact on environment in case of dust spreading. Tungsten has been used as representative of ITER dust because it is the most radiologically hazardous of the plasma facing materials. Thus the mobilizable dust inside the vacuum vessel has to be limited to few hundreds of kilograms of carbon, beryllium and tungsten. The objective of the second set of limits is to ensure that the dust chemical reactivity is adequately controlled. Indeed this reactivity is greatly enhanced on the hot surfaces of the divertor in case of steam ingress, oxidation of the metals, beryllium in particular, leading to hydrogen production and possible explosion. The dusts on the hot surfaces of the divertor should not exceed few kilograms of carbon, beryllium and tungsten. Some calculations have shown that the dusts limits inside the vacuum vessel could be reached in about 500 plasma pulses, and in any case before the assumed replacement of the divertor for planned maintenance. Thus techniques for dust diagnostics and removal need to be developed for ITER to ensure that the set of safety limits are fulfilled. To minimize the impact on the machine operation time, these techniques have to be elaborated considering the ITER vacuum vessel constraints if entering the machine (magnetic field, radiation, vacuum and temperature) or to be non invasive. This paper will present a strategy that could be developed at different periods of the machine operation (during/between pulses and during short or long maintenance periods) in order to monitor the

  11. Brominated and organophosphate flame retardants in indoor dust of Jeddah, Kingdom of Saudi Arabia: Implications for human exposure.

    Science.gov (United States)

    Ali, Nadeem; Eqani, Syed Ali Musstjab Akber Shah; Ismail, Iqbal Mohammad Ibrahim; Malarvannan, Govindan; Kadi, Mohammad W; Albar, Hussain Mohammed Salem; Rehan, Mohammad; Covaci, Adrian

    2016-11-01

    Different flame retardants (FRs) namely polybrominated diphenyl ethers (PBDEs), emerging brominated/chlorinated flame retardants (Br/Cl FRs), and organophosphate FRs (OPFRs) were analyzed in cars, air conditioner (AC) filters and floor dust of different households from Jeddah, Kingdom of Saudi Arabia (KSA). To the best of our knowledge, this is first study in literature reporting emerging Br/Cl FRs and OPFRs in AC filter dust and also first to report on their occurrence in dust from KSA. Chlorinated alkyl phosphate, penta-BDEs, BDE-209, and decabromodiphenylethane (DBDPE) were the major chemicals in dust samples from all microenvironments. ΣOPFRs occurred at median concentrations (ng/g dust) of 15,400, 10,500, and 3750 in AC filter, car and house floor dust, respectively. For all analyzed chemicals, relatively lower levels were observed in floor dust than car and AC filter dust. The profiles of FRs in car dust were different from AC filter and floor dust, which reflected their wider application as FR and plasticizer in variety of household and commercial products. For toddlers, assuming high dust intake and 95th percentile concentrations, the computed exposure estimation for BDE-99 was higher than RfD values.

  12. Household vehicles energy consumption 1991

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-09

    The purpose of this report is to provide information on the use of energy in residential vehicles in the 50 States and the District of Columbia. Included are data about: the number and type of vehicles in the residential sector, the characteristics of those vehicles, the total annual Vehicle Miles Traveled (VMT), the per household and per vehicle VMT, the vehicle fuel consumption and expenditures, and vehicle fuel efficiencies. The data for this report are based on the household telephone interviews from the 1991 RTECS, conducted during 1991 and early 1992. The 1991 RTECS represents 94.6 million households, of which 84.6 million own or have access to 151.2 million household motor vehicles in the 50 States and the District of Columbia.

  13. Household composition and psychological health

    DEFF Research Database (Denmark)

    Joensen, Lene Eide; Willaing, Ingrid; Holt, Richard I G

    2017-01-01

    in the association between household composition and psychological health. METHODS: The study is part of the DAWN2 study conducted in 17 countries. The population comprised 8596 people with diabetes (PWD). Multiple regression models (linear and binary) were applied. RESULTS: People living with 'other adult......AIMS: 1) To explore the effect of household composition on the psychological health of adults with diabetes by comparing those living with other adult(s) including a partner with those living with neither partner nor other adult(s); 2) to examine potential mediation of social support...... to the other household composition groups. The association between household composition and psychological health was not mediated by diabetes-specific social support. CONCLUSIONS: The study indicates the psychological vulnerability of respondents living without a partner but with other adult(s). Appropriate...

  14. Dust grains from the heart of supernovae

    Science.gov (United States)

    Bocchio, M.; Marassi, S.; Schneider, R.; Bianchi, S.; Limongi, M.; Chieffi, A.

    2016-03-01

    Dust grains are classically thought to form in the winds of asymptotic giant branch (AGB) stars. However, there is increasing evidence today for dust formation in supernovae (SNe). To establish the relative importance of these two classes of stellar sources of dust, it is important to know the fraction of freshly formed dust in SN ejecta that is able to survive the passage of the reverse shock and be injected in the interstellar medium. With this aim, we have developed a new code, GRASH_Rev, that allows following the dynamics of dust grains in the shocked SN ejecta and computing the time evolution of the mass, composition, and size distribution of the grains. We considered four well-studied SNe in the Milky Way and Large Magellanic Cloud: SN 1987A, CasA, the Crab nebula, and N49. These sources have been observed with both Spitzer and Herschel, and the multiwavelength data allow a better assessment the mass of warm and cold dust associated with the ejecta. For each SN, we first identified the best explosion model, using the mass and metallicity of the progenitor star, the mass of 56Ni, the explosion energy, and the circumstellar medium density inferred from the data. We then ran a recently developed dust formation model to compute the properties of freshly formed dust. Starting from these input models, GRASH_Rev self-consistently follows the dynamics of the grains, considering the effects of the forward and reverse shock, and allows predicting the time evolution of the dust mass, composition, and size distribution in the shocked and unshocked regions of the ejecta. All the simulated models aagree well with observations. Our study suggests that SN 1987A is too young for the reverse shock to have affected the dust mass. Hence the observed dust mass of 0.7-0.9 M⊙ in this source can be safely considered as indicative of the mass of freshly formed dust in SN ejecta. Conversely, in the other three SNe, the reverse shock has already destroyed between 10-40% of the

  15. Polybrominated diphenyl ethers (PBDEs) in house dust in Beijing, China.

    Science.gov (United States)

    Li, K; Fu, S

    2013-10-01

    Eleven house dust samples were collected in Beijing to quantify 42 different polybrominated diphenyl ethers (PBDEs). Total PBDEs concentrations ranged from 140 to 1,300 ng g(-1). The dominant PBDEs congener identified was BDE 209, which made up more than 70% of all PBDEs congeners. Concentrations of PBDEs in Chinese house dust were lower than in other countries. The most polluted areas were electronics shops and households. It is likely that PBDEs exposure is a potential threat for Beijing residents, particularly toddlers.

  16. Formation of hexachlorobenzene from dusts of an electric arc furnace used in steelmaking: effect of temperature and dust composition.

    Science.gov (United States)

    Murakami, Taichi; Shimura, Mizuki; Kasai, Eiki

    2008-10-01

    A certain amount of hexachlorobenzene (HCB), designated a persistent organic pollutant (POP) by the Stockholm Convention, is emitted from an electric arc furnace (EAF) used in the steelmaking process. To understand the formation and decomposition behaviors of HCB during the treatment of waste gases from an EAF, characterization of dust samples from EAFs in different plants was conducted. Dusts 1 and 2 were bag filter dusts collected from a common steel plant and a special steel plant, respectively. The initial concentrations of HCB in dusts 1 and 2 were 62 and < 0.1 ng/g of dust, respectively. Then a series of heating experiments was carried out with these dust samples under various conditions. The formation of HCB from both dusts was not significant under an Ar atmosphere, although the amount of formation from dust 1 slightly increased with an increase in the holding temperature. Under an Ar--20% O2 atmosphere, however, a remarkable amount of HCB formed from dust 1 above 573 K. A certain amount of HCB was also formed from dust 2, even though the initial concentration of HCB was very low. Moreover, the coexistence of metallic compounds such as CuCl2 had a significant accelerating effect on the formation of HCB.

  17. Operational Dust Prediction

    Science.gov (United States)

    Benedetti, Angela; Baldasano, Jose M.; Basart, Sara; Benincasa, Francesco; Boucher, Olivier; Brooks, Malcolm E.; Chen, Jen-Ping; Colarco, Peter R.; Gong, Sunlin; Huneeus, Nicolas; Jones, Luke; Lu, Sarah; Menut, Laurent; Morcrette, Jean-Jacques; Mulcahy, Jane; Nickovic, Slobodan; Garcia-Pando, Carlos P.; Reid, Jeffrey S.; Sekiyama, Thomas T.; Tanaka, Taichu Y.; Terradellas, Enric; Westphal, Douglas L.; Zhang, Xiao-Ye; Zhou, Chun-Hong

    2014-01-01

    Over the last few years, numerical prediction of dust aerosol concentration has become prominent at several research and operational weather centres due to growing interest from diverse stakeholders, such as solar energy plant managers, health professionals, aviation and military authorities and policymakers. Dust prediction in numerical weather prediction-type models faces a number of challenges owing to the complexity of the system. At the centre of the problem is the vast range of scales required to fully account for all of the physical processes related to dust. Another limiting factor is the paucity of suitable dust observations available for model, evaluation and assimilation. This chapter discusses in detail numerical prediction of dust with examples from systems that are currently providing dust forecasts in near real-time or are part of international efforts to establish daily provision of dust forecasts based on multi-model ensembles. The various models are introduced and described along with an overview on the importance of dust prediction activities and a historical perspective. Assimilation and evaluation aspects in dust prediction are also discussed.

  18. 合肥市城区地表灰尘重金属分布特征及环境健康风险评价%Distribution of Metals in Urban Dusts of Hefei and Health Risk Assessment

    Institute of Scientific and Technical Information of China (English)

    李如忠; 周爱佳; 童芳; 吴亚东; 张萍; 喻佳

    2011-01-01

    This study focused on the characterization and the health risk assessment of heavy metals in the dust of Hefei City,China.Samples were collected from fifty two sampling points covering six land-use types.Most of the sites were impervious ground such as residential,commercial,industrial,educational and traffic areas,as well as public landscapes and city squares.Concentrations of Zn,Pb,Cu,Cd and Cr were measured to investigate their distribution and evaluate their risk to human health.The US EPA Health Risk Assessment Model was employed to evaluate the carcinogenic and non-carcinogenic risks of heavy metals to child and adult,respectively.The results showed that concentrations of Cd and Zn were 46 and 37 times higher than soil background values,respectively.The concentrations of Cu and Pb were 3-5 times,and Cr concentration was 1.5 times higher than the soil background values of Anhui Province.The carcinogenic risk indexes of Cr and Cd were 3.22×10-7 and 2.26×10-9,respectively,which were lower than the soil management standard of the US EPA,i.e.1.0×10-6.The total non-carcinogenic hazard index of the five metals for adults was only 0.212,but for children it reached to 1.259 and exceeded the safety threshold value(1.0),suggesting that the adverse health impact on children exposure to metals in urban dusts were relatively serious in Hefei.The ingestion of dust particles was the major exposure pathway for health risk.The orders of non-carcinogenic hazard indexes of land-use types and heavy metals were industrial areapublic landscapes and city squarescommercial areaeducational arearesidential areatraffic area,and PbCrZnCdCu,respectively.%以安徽省合肥市城区为研究区域,采集居住区、商业区、工业区、文教区、交通区和公园绿地等6种功能用地共52个点位的地表灰尘,探析重金属Zn、Pb、Cu、Cd和Cr在不同功能区的分布特征,并以美国环保署(US EPA)推荐的健康风险评价模型,分别就儿童和成人2

  19. Chemical composition of material fractions in Danish household waste

    DEFF Research Database (Denmark)

    Riber, Christian; Petersen, Claus; Christensen, Thomas Højlund

    2009-01-01

    The chemical composition of Danish household waste was determined by two approaches: a direct method where the chemical composition (61 substances) of 48 material fractions was determined after hand sorting of about 20 tonnes of waste collected from 2200 households; and an indirect method where...... batches of 80-1200 tonnes of unsorted household waste was incinerated and the content of the waste determined from the content of the outputs from the incinerator. The indirect method is believed to better represent the small but highly contaminated material fractions (e,g., batteries) than the direct...... method, because of the larger quantities included and the more homogenous material to sample from. Differences between the direct and the direct methods led to corrections in the of heavy metal concentration of a few fractions. The majority of the energy content of the waste originates from organic waste...

  20. Occurrence and levels of polybrominated diphenyl ethers (PBDEs) in house dust and hair samples from Northern Poland; an assessment of human exposure.

    Science.gov (United States)

    Król, Sylwia; Namieśnik, Jacek; Zabiegała, Bożena

    2014-09-01

    Polybrominated diphenyl ethers (PBDEs) are among most ubiquitous compounds to be found in indoor environment and ingestion of household dust is considered an important route of exposure to PBDEs, especially in toddlers and young children. The present work reported concentration levels of PBDE congeners (PBDE-28, -47, -99, -100, -153, -154, -183 and -209) in hair and dust samples from selected households from Northern Poland. The concentrations of PBDEs in dust ranged from PBDEs via ingestion of household dust varied from 21 to 92ngd(-1) in toddlers and from 3.7 to 20ngd(-1) in adults. By comparison of correlation between the concentrations of PBDEs in paired hair and dust samples the present work also investigated the possibility of use of hair for reflecting the actual exposure to PBDEs in humans. Finally the possible uncertainties associated with exposure assessment were investigated in the present study.

  1. Stone dusting process advance

    Energy Technology Data Exchange (ETDEWEB)

    Matt Ryan; David Humphreys [Mining Attachments (Qld.) Pty Ltd. (Australia)

    2009-01-15

    The coal mining industry has, for many years, used dry stone dust or calcium carbonate (CaCO{sub 3}) in the prevention of the propagation of coal dust explosions throughout their underground mines in Australia. In the last decade wet stone dusting has been introduced. This is where stone dust and water are mixed together to form a paste like slurry. This mixture is pumped and sprayed on to the underground roadway surfaces. This method solved the contamination of the intake airways but brought with it a new problem known as 'caking'. Caking is the hardened layer that is formed as the stone dust slurry dries. It was proven that this hardened layer compromises the dispersal characteristics of the stone dust and therefore its ability to suppress a coal dust explosion. This project set out to prove a specially formulated, non toxic slurry additive and process that could overcome the caking effect. The slurry additive process combines dry stone dust with water to form a slurry. The slurry is then treated with the additive and compressed air to create a highly vesicular foam like stone dusted surface. The initial testing on a range of additives and the effectiveness in minimising the caking effect of wet dusting were performed at Applied Chemical's research laboratory in Melbourne, Victoria and independently tested at the SGS laboratory in Paget, Queensland. The results from these tests provided the platform to conduct full scale spraying trials at the Queensland Mines Rescue Station and Caledon Coal's Cook Colliery, Blackwater. The project moved into the final stage of completion with the collection of data. The intent was to compare the slurry additive process to dry stone dusting in full-scale methane explosions at the CSIR Kloppersbos explosion facility in Kloppersbos, South Africa.

  2. Distribution of polybrominated diphenyl ethers and dust particle size fractions adherent to skin in indoor dust, Pretoria, South Africa.

    Science.gov (United States)

    Kefeni, Kebede Keterew; Okonkwo, Jonathan O

    2014-03-01

    In order to determine human exposure to the indoor toxicant, selection of dust fraction and understanding dust particle size distribution in settled indoor dust are very important. This study examined the influence of dust particle size on the concentration of polybrominated diphenyl ethers (PBDEs) congeners, assessed the distribution of dust particle size and characterized the main indoor emission sources of PBDEs. Accordingly, the concentrations of PBDE congeners determined in different indoor dust fractions were found to be relatively higher in the order of dust particle size: 45-106 μm>(106-150 μm. The finding shows arbitrary selection of dust fractions for exposure determination may result in wrong conclusions. Statistically significant moderate correlation between the concentration of Σ9PBDEs and organic matter content calculated with respect to the total dust mass was also observed (r=0.55, p=0.001). On average, of total dust particle size <250 μm, 93.4 % (m/m%) of dust fractions was associated with less than 150 μm. Furthermore, of skin adherent dust fractions considered (<150 μm), 86 % (v/v%) is in the range of particle size 9.25-104.7 μm. Electronic materials treated with PBDEs were found the main emission sources of PBDE congeners in indoor environment. Based on concentrations of PBDEs determined and mass of indoor dust observed, 150 μm metallic sieve is adequate for human exposure risk assessment. However, research in this area is very limited and more research is required to generalize the fact.

  3. Ceiling (attic) dust: a "museum" of contamination and potential hazard.

    Science.gov (United States)

    Davis, Jeffrey J; Gulson, Brian L

    2005-10-01

    Ceiling or attic dusts provide an indirect measure of air pollution integrated over varying time periods. We undertook an investigation into the particle-size distributions and sources and exposure pathways of metals in ceiling dusts from 38 houses in the city of Sydney, Australia. The houses ranged in age from 4 to 106 years and were grouped into three settings: industrial, semi-industrial, and non-industrial. The main roof types were terracotta tile (n=23), cement tile (n=8), and corrugated iron (n=4), with two slate and one asbestos. Soils and rocks from the Sydney area were also analyzed to provide "background" values and allow the estimation of enrichment factors. The bulk of the dusts contained particles derived from soil of crustal origin and organic plant material, with an anthropogenic component estimated at up to 25%. Particle sizes from selected dust samples showed a bimodal distribution, and the volumes of fine dusts were 50% terracotta tile, cement, and iron, median regression analyses showed that there were no significant effects with respect to age. Median regression analyses for terracotta tile, cement tile, and corrugated iron roofs showed a "roof" effect for Cu and V. Significant correlations (P0.03) were observed between most of the metals As-Cd-Cu-Pb-Sb-Zn, especially from the industrial settings. Pathways of dust exposure in this study are classified as being passive or active based upon the probable route of dust infiltration. Ceiling dusts pose a probable health hazard if the dust is disturbed and allowed to plume within the living areas of a dwelling, thereby exposing the occupants, especially children, to elevated levels of metals and fine particulates. Modeling shows that exposure to the elevated levels of Pb in dust could give rise to blood lead concentrations exceeding current guidelines for the industrial and semi-industrial areas.

  4. Household food wastage in Britain.

    Science.gov (United States)

    Wenlock, R W; Buss, D H; Derry, B J

    1980-01-01

    1. The total food and drink available for human consumption in the United Kingdom would provide approximately 13 MJ (3100 kcal)/person per d, while the energy intake recommended for the population is approximately 9.6 MJ (2300 kcal)/person per d. A proportion of this substantial difference must be due to wastage in the home as well as in catering establishments and during the storage, distribution and processing of food. 2. As part of a general investigation of this problem, a representative sample of 100 British households was asked to collect all the potentially-edible food wasted in their homes during 1 week, and to keep a record of the food, other than commercial pet food, which they gave to pets and wild birds. A total of 672 households co-operated fully, 338 in summer and 334 in winter. Each food sample received was weighed, and its energy content was determined calorimetrically. 3. Significantly more waste food was collected in summer than in winter, equivalent to 9.3 MJ (2220 kcal)/household per week and 7.1 MJ (1700 kcal)/household per week respectively. In terms of energy, cereals, fat and meat wastage predominated, while in terms of weight, milk was more important and fat less so. 4. Considerable quantities of otherwise edible food were also given to pets and birds, accounting on average for a further 2.4 MJ (570 kcal) and 3.0 MJ (710 kcal)/household per week in summer and winter respectively. The energy content of all food wasted in the home therefore averaged 11.7 MJ (2790 kcal)/household per week in summer and 10.1 MJ (2410 kcal)/households per week in winter, equivalent to 0.6 MJ (150 kcal) and 0.5 MJ (130 kcal)/person per d respectively. This is less than one-quarter of the gap between food supplies and the amount of food thought to be eaten in the UK. 5. Food wastage was significantly influenced by the composition of the family, with adults wasting more in absolute terms than children, and larger households wasting less per person than smaller

  5. Respirable dust measured downwind during rock dust application.

    Science.gov (United States)

    Harris, M L; Organiscak, J; Klima, S; Perera, I E

    2017-05-01

    The Pittsburgh Mining Research Division of the U.S. National Institute for Occupational Safety and Health (NIOSH) conducted underground evaluations in an attempt to quantify respirable rock dust generation when using untreated rock dust and rock dust treated with an anticaking additive. Using personal dust monitors, these evaluations measured respirable rock dust levels arising from a flinger-type application of rock dust on rib and roof surfaces. Rock dust with a majority of the respirable component removed was also applied in NIOSH's Bruceton Experimental Mine using a bantam duster. The respirable dust measurements obtained downwind from both of these tests are presented and discussed. This testing did not measure miners' exposure to respirable coal mine dust under acceptable mining practices, but indicates the need for effective continuous administrative controls to be exercised when rock dusting to minimize the measured amount of rock dust in the sampling device.

  6. Dust escape from Io

    Science.gov (United States)

    Flandes, Alberto

    2004-08-01

    The Dust ballerina skirt is a set of well defined streams composed of nanometric sized dust particles that escape from the Jovian system and may be accelerated up to >=200 km/s. The source of this dust is Jupiter's moon Io, the most volcanically active body in the Solar system. The escape of dust grains from Jupiter requires first the escape of these grains from Io. This work is basically devoted to explain this escape given that the driving of dust particles to great heights and later injection into the ionosphere of Io may give the particles an equilibrium potential that allow the magnetic field to accelerate them away from Io. The grain sizes obtained through this study match very well to the values required for the particles to escape from the Jovian system.

  7. Galactic dust properties

    Science.gov (United States)

    Paradis, D.

    2011-12-01

    Recent studies have shown evidence for variations in the dust emissivity law with temperature and wavelength. A recent dust emission model, called TLS model (for two-level systems), based on the description of the disordered internal structure of the amorphous dust grains has been developped to interpret observations in the far-infrared/submillimeter (FIR/submm) domain. A recent work focusing on the comparison between data of the diffuse interstellar medium seen by FIRAS-WMAP, as well as Archeops compact sources, with the TLS model allowed us to constrain the model parameters characterizing the general Galactic dust properties. Using the newly available Herschel/Hi-GAL data of the inner Galactic plane, we report a 500 μm emissivity excess in the peripheral parts of the Galactic plane, that can reach up to 20% of the emissivity. Results of the TLS modeling indicate significant changes in the dust properties from the central to peripheral parts of the Galactic plane.

  8. Connecting The Interstellar Gas And Dust Properties Of Distant Galaxies

    Science.gov (United States)

    Kulkarni, Varsha

    The properties of interstellar gas and dust in distant galaxies are fundamental parameters in constraining galaxy evolution models. Quasar absorption systems (QASs), which trace intervening galaxies along the sightlines to luminous background quasars, provide invaluable tools to directly study gas and dust in distant normal galaxies. Recent studies of QASs have found interesting trends in both gas and dust properties, such as correlations in metallicity with redshift and dust depletions. Our Spitzer spectroscopic studies also indicate that silicate dust grains are present in QASs, and in fact, at a level higher than expected for diffuse gas in the Milky Way. Moreover, the silicate dust grains in these distant galaxies may be substantially more crystalline than those in the Milky Way interstellar medium. We now propose a comprehensive study of the gas and dust properties of all QASs with strong Ly-alpha and/or metal absorption lines that have adequate archival IR data to probe the study of dust. Our analysis will include data primarily from the NASA-supported Spitzer, Herschel, HST, and Keck Observatory archives, along with a small amount of VLT/SDSS archival data. Our specific goals are as follows: (1) We will measure a large range of metal absorption lines in high-resolution quasar spectra from Keck, HST, and VLT archives to uniformly determine the metallicity, dust depletions, ionization, and star formation rates in the foreground QASs. In particular, we will study the variations in these quantities with gas velocity, using Voigt profile fitting techniques to determine the velocity structure. This analysis will also allow us to quantify the kinematics of the absorbing gas. (2) We will use archival Spitzer IRS quasar spectra to search for and measure the strengths of the 10 and 18 micron silicate dust absorption features for a much larger sample of QASs than previously studied. (3) We will fit the observed silicate absorption features in the Spitzer archival

  9. Peach leaf responses to soil and cement dust pollution.

    Science.gov (United States)

    Maletsika, Persefoni A; Nanos, George D; Stavroulakis, George G

    2015-10-01

    Dust pollution can negatively affect plant productivity in hot, dry and with high irradiance areas during summer. Soil or cement dust were applied on peach trees growing in a Mediterranean area with the above climatic characteristics. Soil and cement dust accumulation onto the leaves decreased the photosynthetically active radiation (PAR) available to the leaves without causing any shade effect. Soil and mainly cement dust deposition onto the leaves decreased stomatal conductance, photosynthetic and transpiration rates, and water use efficiency due possibly to stomatal blockage and other leaf cellular effects. In early autumn, rain events removed soil dust and leaf functions partly recovered, while cement dust created a crust partially remaining onto the leaves and causing more permanent stress. Leaf characteristics were differentially affected by the two dusts studied due to their different hydraulic properties. Leaf total chlorophyll decreased and total phenol content increased with dust accumulation late in the summer compared to control leaves due to intense oxidative stress. The two dusts did not cause serious metal imbalances to the leaves, except of lower leaf K content.

  10. Ambiental dust speciation and metal content variation in TSP, PM 10 and PM 2.5 in urban atmospheric air of Harare (Zimbabwe).

    Science.gov (United States)

    Kuvarega, A T; Taru, P

    2008-09-01

    Levels of TSP, PM(10) and PM(2.5) as well as levels of Pb, Co, Ni and Cd in TSP, PM(10) and PM(2.5) have been determined in atmospheric particulates collected at Loius Mountbatten School (Harare). The samples were collected for a period of 6 months from July to December 2002. The average levels of TSP, PM(10) and PM(2.5) measured at the site are 106.11, 59.70 and 40.55 mg m(-3) respectively. The average level of TSP at Loius Mountbatten School is 106.11 mg m(-3), which is higher than the annual WHO guideline limit of 90 mg m(-3). The average level of PM(10) measured at Loius Mountbatten School is 59.70 mg m(-3), and is higher than the US-EPA and UK-EU guideline limit of 50 mg m(-3). The average level of PM(2.5) measured at the site are also higher than the WHO and US-EPA annual guideline limit of 15 mg m(-3). The analysis of metal concentrations in TSP, PM(10) and PM(2.5) was done using Graphite Furnace Atomic Absorption Spectrometry (GFAAS). The analysis showed the following average elemental concentrations: 0.157 mg Pb m(-3) in TSP, 0.166 mg Pb m(-3) in PM(10), 0.185 mg Pb m(-3) in PM(2.5), 0.009 mg Co m(-3) in TSP, 0.007 mg Co m(-3) in PM(10), 0.011 mg Co m(-3) in PM(2.5), 0.223 mg Ni m(-3) in TSP, 0.166 mg Ni m(-3) in PM(10), 0.180 mg Ni m(-3) in PM(2.5) and 0.005 mg Cd m(-3) in TSP, 0.006 mg Cd m(-3) in PM(10), 0.005 mg Cd m(-3) in PM(2.5). The levels of Pb and Ni were generally higher than those of Co and Cd and this could have been due to high traffic volumes and various industrial activities in the Workington Industrial Area.

  11. 青岛城市公园灰尘重金属的形态分布及健康风险评价%Chemical Speciation of Heavy Metals and Health Risk Assessment in Dust of Qingdao Urban Parks

    Institute of Scientific and Technical Information of China (English)

    钱翌; 刘峥延

    2011-01-01

    The total amount of heavy metals and their distributions of chemical speciation were analysed in the dust samples from different parks of the four districts in Qingdao, including Shinan, Shibei, Sifang and Licang Districts, and the health risk of heavy me%对青岛市南、市北、四方和李沧四区的公园灰尘样品的重金属全量和形态分布进行分析,并对公园灰尘重金属的污染状况进行了健康风险评价。结果表明:青岛城市公园土壤和灰尘均在不同程度上受到Cu、Zn、Pb、cd的污染,李沧区4种重金属含量均在四区最高。市南区公园灰尘中的Cu、Pb、cd的含量最低,市北区的Zn含量最低;Cu主要以有机结合态为主,Zn主要以碳酸盐结合态和铁锰氧化态为主,Pb主要以铁锰氧化态为主,cd主要以铁锰氧化态和残渣态为主;健康风险评价的结果表明4种重金属非致癌风险由大到小为Pb〉Cu〉Cd〉Zn,

  12. Determinants of Soviet Household Income

    Directory of Open Access Journals (Sweden)

    by Kenneth Smith

    2007-06-01

    Full Text Available World Values Survey data are used to examine household income in the Soviet Union. The data, gathered Summer/Fall 1990, provide a rare opportunity to empirically examine microeconomic factors influencing a Soviet household’s position in the regional/national income distribution. The survey contains data - collected regionally - from the three Baltic republics, Belarus, and the Moscow region. The data indicate certain patterns that existed and determined Soviet household income though there are often considerable regional variations. Further, there are marked differences between income distribution determinants in the Soviet Union and the U.S. and West Germany though similarities exist as well

  13. Molecular mechanisms of dust-induced toxicity in human corneal epithelial cells: Water and organic extract of office and house dust.

    Science.gov (United States)

    Xiang, Ping; Liu, Rong-Yan; Sun, Hong-Jie; Han, Yong-He; He, Rui-Wen; Cui, Xin-Yi; Ma, Lena Q

    2016-01-01

    Human corneal epithelial (HCE) cells are continually exposed to dust in the air, which may cause corneal epithelium damage. Both water and organic soluble contaminants in dust may contribute to cytotoxicity in HCE cells, however, the associated toxicity mechanisms are not fully elucidated. In this study, indoor dust from residential houses and commercial offices in Nanjing, China was collected and the effects of organic and water soluble fraction of dust on primary HCE cells were examined. The concentrations of heavy metals in the dust and dust extracts were determined by ICP-MS and PAHs by GC-MS, with office dust having greater concentrations of heavy metals and PAHs than house dust. Based on LC50, organic extract was more toxic than water extract, and office dust was more toxic than house dust. Accordingly, the organic extracts induced more ROS, malondialdehyde, and 8-Hydroxydeoxyguanosine and higher expression of inflammatory mediators (IL-1β, IL-6, and IL-8), and AhR inducible genes (CYP1A1, and CYP1B1) than water extracts (pdust presented greater suppression of superoxide dismutase and catalase activity than those of house dust. In addition, exposure to dust extracts activated NF-κB signal pathway except water extract of house dust. The results suggested that both water and organic soluble fractions of dust caused cytotoxicity, oxidative damage, inflammatory response, and activation of AhR inducible genes, with organic extracts having higher potential to induce adverse effects on primary HCE cells. The results based on primary HCE cells demonstrated the importance of reducing contaminants in indoor dust to reduce their adverse impacts on human eyes.

  14. AN ECO-FRIENDLY MANAGEMENT OF HOUSEHOLD ORGANIC WASTE

    Directory of Open Access Journals (Sweden)

    Puneeta Dandotiya

    2015-06-01

    Full Text Available The household organic wastes commonly include dust, food and kitchen waste, garden waste, paper waste etc. that is generated everyday from every house. This highly nutritive organic waste is the house of infectious bacteria, vector and insect. A study was conducted to explore the possibility of vermicomposting of household organic waste at home level. For this study household waste (HW and garden (leaves with soil-dust waste (GW were selected. They were mixed with dried dung powder (DDP and vermicompost (VC in different ratios. The mixture (20 Kg was subjected for pre-decomposting for a period of 15-20 days, followed by release of 50 earthworms (E. eugeniae. Regular sprinkling of water was made in the culture media to maintain moisture content to 50-60% and temperature in the range of 20-28̊C up to 80 days. At end of the experiment observations were made in terms of number and weight of earthworms, juveniles and cocoons. Analysis of vermicompost was also done for values of pH, nitrogen, phosphorus and potassium. The best results of earthworm as well as vermicompost parameters were obtained in the mixture containing equal quantity of KW+DDP+GW+VC with a maximum increase in worm population and worm biomass. Maximum fertilizer values of nitrogen, potassium and phosphorus content were observed in this mixture. It can be concluded that organic waste generated from home and garden can easily be converted into high quality valuable compost at home level with fruitful outcome.

  15. Dust Destruction Rates and Lifetimes in the Magellanic Clouds

    Science.gov (United States)

    Temim, Tea; Dwek, Eli; Tchernyshyov, Kirill; Boyer, Martha L.; Meixner, Margaret; Gall, Christa; Roman-Duval, Julia

    2015-01-01

    The nature, composition, abundance, and size distribution of dust in galaxies is determined by the rate at which it is created in the different stellar sources and destroyed by interstellar shocks. Because of their extensive wavelength coverage, proximity, and nearly face-on geometry, the Magellanic Clouds (MCs) provide a unique opportunity to study these processes in great detail. In this paper we use the complete sample of supernova remnants (SNRs) in the MCs to calculate the lifetime and destruction efficiencies of silicate and carbon dust in these galaxies. We find dust lifetimes of 22+/-13 Myr (30+/-17 Myr) for silicate (carbon) grains in the LMC, and 54 +/- 32 Myr (72 +/- 43 Myr) for silicate (carbon) grains in the SMC. The significantly shorter lifetimes in the MCs, as compared to the Milky Way, are explained as the combined effect of their lower total dust mass, and the fact that the dust-destroying isolated SNe in the MCs seem to be preferentially occurring in regions with higher than average dust-to-gas (D2G) mass ratios. We also calculate the supernova rate and the current star formation rate in the MCs, and use them to derive maximum dust injection rates by asymptotic giant branch (AGB) stars and core collapse supernovae (CCSNe). We find that the injection rates are an order of magnitude lower than the dust destruction rates by the SNRs. This supports the conclusion that, unless the dust destruction rates have been considerably overestimated, most of the dust must be reconstituted from surviving grains in dense molecular clouds. More generally, we also discuss the dependence of the dust destruction rate on the local D2G mass ratio and the ambient gas density and metallicity, as well as the application of our results to other galaxies and dust evolution models.

  16. DUST DESTRUCTION RATES AND LIFETIMES IN THE MAGELLANIC CLOUDS

    Energy Technology Data Exchange (ETDEWEB)

    Temim, Tea; Dwek, Eli; Boyer, Martha L. [Observational Cosmology Lab, Code 665, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Tchernyshyov, Kirill; Meixner, Margaret [Department of Physics and Astronomy, The Johns Hopkins University, 366 Bloomberg Center, 3400 North Charles Street, Baltimore, MD 21218 (United States); Gall, Christa [Department of Physics and Astronomy, Aarhus University, Ny Munkegade 120, DK-8000 Aarhus C (Denmark); Roman-Duval, Julia, E-mail: tea.temim@nasa.gov [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States)

    2015-02-01

    The dust budget in galaxies depends on the rate at which dust grains are created in different stellar sources and destroyed by interstellar shocks. Because of their extensive wavelength coverage, proximity, and nearly face-on geometry, the Magellanic Clouds (MCs) provide a unique opportunity to study these processes in great detail. In this paper, we use the complete sample of supernova remnants (SNRs) in the MCs to calculate the lifetimes and destruction efficiencies of silicate and carbon dust. We find dust lifetimes of 22 ± 13 Myr (30 ± 17 Myr) for silicate (carbon) grains in the LMC, and 54 ± 32 Myr (72 ± 43 Myr) for silicate (carbon) grains in the SMC. The corresponding dust destruction rates are 2.3 × 10{sup –2} M {sub ☉} yr{sup –1} (5.9 × 10{sup –3} M {sub ☉} yr{sup –1}) and 3.0 × 10{sup –3} M {sub ☉} yr{sup –1} (5.6 × 10{sup –4} M {sub ☉} yr{sup –1}) for silicate (carbon) grains in the LMC and SMC, respectively. The significantly shorter lifetimes in the MCs, as compared to the Milky Way, are explained as the combined effect of their lower total dust mass and preferentially higher dust-to-gas (D2G) mass ratios in the vicinity of the SNRs. We find that the maximum dust injection rates by asymptotic giant branch stars and core collapse supernovae are an order of magnitude lower than the dust destruction rates by the SNRs, suggesting that most of the dust may be reconstituted in dense molecular clouds. We also discuss the dependence of the dust destruction rate on the local D2G mass ratio, ambient gas density, and metallicity, as well as the application of our results to other galaxies and dust evolution models.

  17. Organic compounds in the urban dusts in Celje area

    Directory of Open Access Journals (Sweden)

    Gorazd Žibret

    2013-06-01

    Full Text Available This paper presents the results of the analysis of organic chemicals in different urban dusts. The aim of the researchis preliminary evaluation of the presence of organic contaminants in household dust, attic dust and streetsediment. Celje area has been chosen as a pilot study site due to availability of sampling materials from previoussampling campaigns. Samples have been tested to the presence of 120 organic compounds. Attic dust contains 98different organic compounds or 82 % of all measured. Terpenoids, alkylbenzenes and different Polycyclic AromaticHydrocarbons (PAH’s, as well as plasticizers, halogenated compounds (among them also PCB’s and pesticides(DDT and degradation products can be found there. It also contains all of the in this study analysed US-EPA prioritypollutants. Street dust contained 70 different organic chemicals (58 %, among them 14 priority pollutants. Tracesof aliphatic organic compounds, PAH’s, aldehydes and ketones, esters, and plasticizers are found there. House dustcontains lowest number of organic compounds. Among 45 detected (38 % of total measured, 8 are priority pollutants.Aliphatic compounds, alkylbenzenes, aldehides, ketones, acids and PAH’s can be found there. Current numberof analysed samples, as well as only qualitative evaluations were made does not allow making any solid interpretationof obtained results in regarding to the potential sources of chemicals or potential environmental hazards. Thisstudy can thus be used only as a guideline for future studies of organic chemicals in urban dusts.

  18. Seasonal and occupational trends of five organophosphate pesticides in house dust.

    Science.gov (United States)

    Smith, Marissa N; Workman, Tomomi; McDonald, Katie M; Vredevoogd, Melinda A; Vigoren, Eric M; Griffith, William C; Thompson, Beti; Coronado, Gloria D; Barr, Dana; Faustman, Elaine M

    2016-08-24

    Since 1998, the University of Washington's Center for Child Environmental Health Risks Research has followed a community-based participatory research strategy in the Lower Yakima Valley of Washington State to assess pesticide exposure among families of Hispanic farmworkers. As a part of this longitudinal study, house dust samples were collected from both farmworker and non-farmworker households, across three agricultural seasons (thinning, harvest and non-spray). The household dust samples were analyzed for five organophosphate pesticides: azinphos-methyl, phosmet, malathion, diazinon, and chlorpyrifos. Organophosphate pesticide levels in house dust were generally reflective of annual use rates and varied by occupational status and agricultural season. Overall, organophosphate pesticide concentrations were higher in the thinning and harvest seasons than in the non-spray season. Azinphos-methyl was found in the highest concentrations across all seasons and occupations. Farmworker house dust had between 5- and 9-fold higher concentrations of azinphos-methyl than non-farmworker house dust. Phosmet was found in 5-7-fold higher concentrations in farmworker house dust relative to non-farmworker house dust. Malathion and chlorpyriphos concentrations in farmworker house dust ranged between 1.8- and 9.8-fold higher than non-farmworker house dust. Diazinon showed a defined seasonal pattern that peaked in the harvest season and did not significantly differ between farmworker and non-farmworker house dust. The observed occupational differences in four out of five of the pesticide residues measured provides evidence supporting an occupational take home pathway, in which workers may bring pesticides home on their skin or clothing. Further, these results demonstrate the ability of dust samples to inform the episodic nature of organophosphate pesticide exposures and the need to collect multiple samples for complete characterization of exposure potential.Journal of Exposure Science

  19. Effects of dust grains on early galaxy evolution

    CERN Document Server

    Hirashita, H

    2002-01-01

    Stars form out of molecular gas and supply dust grains during their last evolutionary stages; in turn hydrogen molecules (H2) are produced more efficiently on dust grains. Therefore, dust can drastically accelerate H2 formation, leading to an enhancement of star formation activity. In order to examine the first formation of stars and dust in galaxies, we model the evolution of galaxies in the redshift range of 55) galaxies in sub-millimetre and near-infrared bands. We find that: i) ALMA can detect dust emission from several thousands of galaxies per square degree, and ii) NGST can detect the stellar emission from 10^6 galaxies per square degree. Further observational checks of our predictions include the integrated flux of metal (oxygen and carbon) lines. We finally discuss possible color selection strategies for high-redshift galaxy searches.

  20. 城市植物叶面尘粒径和几种重金属(Cu、Zn、Cr、Cd、Pb、Ni)的分布特征%Distribution features of particle size and heavy metal elements in foliage-captured dust

    Institute of Scientific and Technical Information of China (English)

    王会霞; 石辉; 李秧秧; 张雅静; 杜红霞; 杜衡

    2012-01-01

    This paper takes as its target to reveal the distribution features of particle size and heavy metal elements (Cu, Zn, Cr, Cd, Pb, Ni) in foliage-captured dust, by using the foliar dust samples of ligustrum lucidum and liguslrum quihoui collected from different areas of Xi' an, including its industrial area (IA), commercial and service area (CSA), heavy-traffic area (HTA), residential and edupa-tional area ( REA) and comparatively pollution-free area ( CPFA). Size distribution of the collected samples was determined with a laser particle size analyzer, while the concentrations of heavy metals in the samples were measured with an atomic absorption spectrophotometer. We have also discussed the likely sources of the heavy metals in the dust. The paniculate size of the foliar dust proves to be less than SO fim, and PM10( participate matter with aerodynamic diameter less than 10 fun) makes up between 13.8% and 63.1% of the particles. There exist two peak values of the foliar dust for Ligustrum lucidum, with its mean and peak values of the dust size being highest in CPFA, and followed by 1A, RE A, HTA and CSA. For ligustrum quihoui, however, the size distribution of the foliar dust proves to be normal, with its mean and peak value in the increasing order of CPFA, CSA, HTA, REA, IA. Heavy metals are significantly enriched in foliar dust, with its mean concentrations being (32S.S ± 72.6) mg/kg for Cu, (3 965.6 ±1 112.9) mg/kg for Zn, (349.2 ± 149.3) mg/kg for Cr, (35.3 ±6.8) mg/kg for Cd, (1 182.0 ±355.1) mg/kg for Pb, (324.1 ± 129.5) mg/kg for Ni. Significant differences are found in heavy metals among different urban areas. By contrast, Cu, Zn, Cr, Cd, Pb and Ni concentrations in foliar dust prove no significant difference between Ligustrum lucidum and Ligustrum quihoui. The results of our investigation suggest that the contents of Zn, Pb, Ni and Cr in the foliar dust are the highest in IA with the greatest values observed in HTA for Cu and Cd. However, the

  1. Household Portfolios in the Netherlands

    NARCIS (Netherlands)

    Alessie, R.J.M.; Hochgürtel, S.; van Soest, A.H.O.

    2000-01-01

    We describe and analyse the portfolio structure of Dutch households using micro panel data from the CentER Savings Survey, 1993-1998.The data allows for a distinction between many types of assets.Moreover, we have information on mortgage debt, consumer debt, etc.We analyse the composition of househo

  2. Changing Age and Household Patterns

    DEFF Research Database (Denmark)

    Højbjerg Jacobsen, Rasmus; Hougaard Jensen, Svend E.

    2014-01-01

    This paper studies the effects on tax revenues and welfare expenditures in Denmark caused by changes in age and household structures over the years 1982-2007. During that period, there has been a minor fall in the old-age dependency ratio, and a major increase in the number of people living alone...

  3. Making Psychology a Household Word

    Science.gov (United States)

    Levant, Ronald F.

    2006-01-01

    This article addresses Ronald F. Levant's four APA presidential initiatives for 2005. "Making Psychology a Household Word" was both the general theme for his presidency as well as an initiative in its own right. The other three initiatives were "Promoting Health Care for the Whole Person," "Enhancing Diversity Within APA," and "Developing an APA…

  4. Financial planning for young households

    DEFF Research Database (Denmark)

    Pedersen, Anne Marie Boiden; Weissensteiner, Alex; Poulsen, Rolf

    2013-01-01

    We analyze the financial planning problems of young households whose main decisions are how to finance the purchase of a house (liabilities) and how to allocate investments in pension savings schemes (assets). The problems are solved using a multi-stage stochastic programming model where...

  5. Response of the Eastern Mediterranean microbial ecosystem to dust and dust affected by acid processing in the atmosphere

    Directory of Open Access Journals (Sweden)

    Michael David Krom

    2016-08-01

    Full Text Available Acid processes in the atmosphere, particularly those caused by anthropogenic acid gases, increase the amount of bioavailable P in dust and hence are predicted to increase microbial biomass and primary productivity when supplied to oceanic surface waters. This is likely to be particularly important in the Eastern Mediterranean Sea (EMS, which is P limited during the winter bloom and N&P co-limited for phytoplankton in summer. However, it is not clear how the acid processes acting on Saharan dust will affect the microbial biomass and primary productivity in the EMS. Here, we carried out bioassay manipulations on EMS surface water on which Saharan dust was added as dust (Z, acid treated dust (ZA, dust plus excess N (ZN and acid treated dust with excess N (ZNA during springtime (May 2012 and measured bacterioplankton biomass, metabolic and other relevant chemical and biological parameters. We show that acid treatment of Saharan dust increased the amount of bioavailable P supplied by a factor of ~40 compared to non-acidified dust (18.4 nmoles P mg-1 dust vs. 0.45 nmoles P mg-1 dust, respectively. The increase in chlorophyll, primary and bacterial productivity for treatments Z and ZA were controlled by the amount of N added with the dust while those for treatments ZN and ZNA (in which excessive N was added were controlled by the amount of P added. These results confirm that the surface waters were N&P co-limited for phytoplankton during springtime. However, total chlorophyll and primary productivity in the acid treated dust additions (ZA and ZNA were less than predicted from that calculated from the amount of the potentially limiting nutrient added. This biological inhibition was interpreted as being due to labile trace metals being added with the acidified dust. A probable cause for this biological inhibition was the addition of dissolved Al, which forms potentially toxic Al nanoparticles when added to seawater. Thus, the effect of anthropogenic acid

  6. An Infrared Census of DUST in Nearby Galaxies with Spitzer (DUSTiNGS), I. Overview

    CERN Document Server

    Boyer, Martha L; Barmby, Pauline; Bonanos, Alceste Z; Gehrz, Robert D; Gordon, Karl D; Groenewegen, M A T; Lagadec, Eric; Lennon, Daniel; Marengo, Massimo; Meixner, Margaret; Skillman, Evan; Sloan, G C; Sonneborn, George; van Loon, Jacco Th; Zijlstra, Albert

    2014-01-01

    Nearby resolved dwarf galaxies provide excellent opportunities for studying the dust-producing late stages of stellar evolution over a wide range of metallicity (-2.7 75% complete at the tip of the Red Giant Branch for all targeted galaxies, with the exception of the crowded inner regions of IC 10, NGC 185, and NGC 147. This photometric depth ensures that the majority of the dust-producing stars, including the thermally-pulsing AGB stars, are detected in each galaxy. The images map each galaxy to at least twice the half-light radius to ensure that the entire evolved star population is included and to facilitate the statistical subtraction of background and foreground contamination, which is severe at these wavelengths. In this overview, we describe the survey, the data products, and preliminary results. We show evidence for the presence of dust-producing AGB stars in 8 of the targeted galaxies, with metallicities as low as [Fe/H] = -1.9, suggesting that dust production occurs even at low metallicity.

  7. Corrosion inhibition of a hygroscopic inorganic dust-depressor

    Institute of Scientific and Technical Information of China (English)

    Longzhe Jin; Lu Wang; Dongke Chen

    2006-01-01

    Metallic corrosion is a serious problem in the application of a hygroscopic inorganic dust-depressor. The basic characteristics of a hygroscopic inorganic dust-depressor and its corrosivity, corrosion mechanism, as well as the principle of corrosion inhibition were analyzed. The static mass-loss test was carried out to investigate the corrosion behavior and the effect of the dustdepressor. The static corrosion rates of steel specimens were measured in six different corrosion inhibitor solutions of the dustdepressor, and the suitable corrosion inhibitors for the dust-depressor to reduce the corrosivity were found out.

  8. Combined glassification of EAF dust and incinerator fly ash.

    Science.gov (United States)

    Cheng, T W

    2003-01-01

    Stainless steelmaking dust contains large amount of heavy metals, such as Cr and Ni. If these hazardous materials are not treated properly, they will cause detrimental secondary contamination. Preliminary study on recycling stainless steelmaking dust employed the thermal molten technology. Glass-ceramics were formed by combination stainless steel dust and incinerator fly ash with the ratio of 1:9. The major phases were Augite, Akermanite, and Donathite. It was found that the glass-ceramics shows the best characteristic at 900 degrees C after 5 h of heat treatment. This product can be used as building materials or refractory materials.

  9. Composite circumstellar dust grains

    Science.gov (United States)

    Gupta, Ranjan; Vaidya, Dipak B.; Dutta, Rajeshwari

    2016-10-01

    We calculate the absorption efficiencies of composite silicate grains with inclusions of graphite and silicon carbide in the spectral range 5-25 μm. We study the variation in absorption profiles with volume fractions of inclusions. In particular we study the variation in the wavelength of peak absorption at 10 and 18 μm. We also study the variation of the absorption of porous silicate grains. We use the absorption efficiencies to calculate the infrared flux at various dust temperatures and compare with the observed infrared emission flux from the circumstellar dust around some M-type and asymptotic giant branch stars obtained from IRAS and a few stars from Spitzer satellite. We interpret the observed data in terms of the circumstellar dust grain sizes, shape, composition and dust temperature.

  10. Composite Circumstellar Dust Grains

    CERN Document Server

    Gupta, Ranjan; Dutta, Rajeshwari

    2016-01-01

    We calculate the absorption efficiencies of composite silicate grains with inclusions of graphite and silicon carbide in the spectral range 5--25$\\rm \\mu m$. We study the variation in absorption profiles with volume fractions of inclusions. In particular we study the variation in the wavelength of peak absorption at 10 and 18$\\rm \\mu m$. We also study the variation of the absorption of porous silicate grains. We use the absorption efficiencies to calculate the infrared flux at various dust temperatures and compare with the observed infrared emission flux from the circumstellar dust around some M-Type \\& AGB stars obtained from IRAS and a few stars from Spitzer satellite. We interpret the observed data in terms of the circumstellar dust grain sizes; shape; composition and dust temperature.

  11. Nano Dust Analyzer Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop a new highly sensitive instrument to confirm the existence of the so-called nano-dust particles, characterize their impact parameters, and...

  12. A Picture of Subsidized Households 2009

    Data.gov (United States)

    Department of Housing and Urban Development — Picture of Subsidized Households describes the nearly 5 million households living in HUD-subsidized housing in the United States for the year 2009. Picture 2009...

  13. Characterization of household food waste in Denmark

    DEFF Research Database (Denmark)

    Edjabou, Vincent Maklawe Essonanawe; Petersen, C.; Scheutz, Charlotte

    This paper presents a methodology and the results of compositional analysis of food waste from Danish families living in single-family houses. Residual household waste was sampled and manually sorted from 211 single-family houses in the suburb of Copenhagen. The main fractions contributing...... to the household food waste were avoidable vegetable food waste and non-avoidable vegetable food waste. Statistical analysis found a positive linear relationship between household size and the amount of the household food waste....

  14. Characterization of household food waste in Denmark

    DEFF Research Database (Denmark)

    Edjabou, Vincent Maklawe Essonanawe; Petersen, C.; Scheutz, Charlotte

    This paper presents a methodology and the results of compositional analysis of food waste from Danish families living in single-family houses. Residual household waste was sampled and manually sorted from 211 single-family houses in the suburb of Copenhagen. The main fractions contributing...... to the household food waste were avoidable vegetable food waste and non-avoidable vegetable food waste. Statistical analysis found a positive linear relationship between household size and the amount of the household food waste....

  15. Evolution of dust extinction curves in galaxy simulation

    Science.gov (United States)

    Hou, Kuan-Chou; Hirashita, Hiroyuki; Nagamine, Kentaro; Aoyama, Shohei; Shimizu, Ikkoh

    2017-07-01

    To understand the evolution of extinction curve, we calculate the dust evolution in a galaxy using smoothed particle hydrodynamic simulations incorporating stellar dust production, dust destruction in supernova shocks, grain growth by accretion and coagulation, and grain disruption by shattering. The dust species are separated into carbonaceous dust and silicate. The evolution of grain size distribution is considered by dividing grain population into large and small grains, which allows us to estimate extinction curves. We examine the dependence of extinction curves on the position, gas density and metallicity in the galaxy, and find that extinction curves are flat at t ≲ 0.3 Gyr because stellar dust production dominates the total dust abundance. The 2175 Å bump and far-ultraviolet (FUV) rise become prominent after dust growth by accretion. At t ≳ 3 Gyr, shattering works efficiently in the outer disc and low-density regions, so extinction curves show a very strong 2175 Å bump and steep FUV rise. The extinction curves at t ≳ 3 Gyr are consistent with the Milky Way extinction curve, which implies that we successfully included the necessary dust processes in the model. The outer disc component caused by stellar feedback has an extinction curve with a weaker 2175 Å bump and flatter FUV slope. The strong contribution of carbonaceous dust tends to underproduce the FUV rise in the Small Magellanic Cloud extinction curve, which supports selective loss of small carbonaceous dust in the galaxy. The snapshot at young ages also explains the extinction curves in high-redshift quasars.

  16. Dust evolution processes in normal galaxies at z > 6 detected by ALMA

    Science.gov (United States)

    Wang, Wei-Chen; Hirashita, Hiroyuki; Hou, Kuan-Chou

    2017-03-01

    Recent Atacama Large Millimetre/submillimetre Array (ALMA) observations of high-redshift normal galaxies have been providing a great opportunity to clarify the general origin of dust in the Universe, not biased to very bright special objects even at z > 6. To clarify what constraint we can get for the dust enrichment in normal galaxies detected by ALMA, we use a theoretical model that includes major processes driving dust evolution in a galaxy; that is, dust condensation in stellar ejecta, dust growth by the accretion of gas-phase metals and supernova destruction. Using the dust emission fluxes detected in two normal galaxies at z > 6 by ALMA as a constraint, we can get the range of the time-scales (or efficiencies) of the above mentioned processes. We find that if we assume extremely high-condensation efficiency in stellar ejecta (fin ≳ 0.5), rapid dust enrichment by stellar sources in the early phase may be enough to explain the observed ALMA flux, unless dust destruction by supernovae in those galaxies is stronger than that in nearby galaxies. If we assume a condensation efficiency expected from theoretical calculations (fin ≲ 0.1), strong dust growth (even stronger than assumed for nearby galaxies if they are metal-poor galaxies) is required. These results indicate that the normal galaxies detected by ALMA at z > 6 are biased to objects (i) with high dust condensation efficiency in stellar ejecta, (ii) with strong dust growth in very dense molecular clouds or (iii) with efficient dust growth because of fast metal enrichment up to solar metallicity. A measurement of metallicity is crucial to distinguish among these possibilities.

  17. Dust and Stellar Emission of the Magellanic Clouds

    CERN Document Server

    Skibba, Ramin A; Aniano, Gonzalo; Babler, Brian; Bernard, Jean-Philippe; Bot, Caroline; Carlson, Lynn Redding; Galametz, Maud; Galliano, Frederic; Gordon, Karl; Hony, Sacha; Israel, Frank; Lebouteiller, Vianney; Li, Aigen; Madden, Suzanne; Meixner, Margaret; Misselt, Karl; Montiel, Edward; Okumura, Koryo; Panuzzo, Pasquale; Paradis, Deborah; Roman-Duval, Julia; Rubio, Monica; Sauvage, Marc; Seale, Jonathan; Srinivasan, Sundar; van Loon, Jacco Th

    2012-01-01

    We study the emission by dust and stars in the Large and Small Magellanic Clouds, a pair of low-metallicity nearby galaxies, as traced by their spatially resolved spectral energy distributions (SEDs). This project combines Herschel Space Observatory PACS and SPIRE far-infrared photometry with other data at infrared and optical wavelengths. We build maps of dust and stellar luminosity and mass of both Magellanic Clouds, and analyze the spatial distribution of dust/stellar luminosity and mass ratios. These ratios vary considerably throughout the galaxies, generally between the range $0.01\\leq L_{\\rm dust}/L_\\ast\\leq 0.6$ and $10^{-4}\\leq M_{\\rm dust}/M_\\ast\\leq 4\\times10^{-3}$. We observe that the dust/stellar ratios depend on the interstellar medium (ISM) environment, such as the distance from currently or previously star-forming regions, and on the intensity of the interstellar radiation field (ISRF). In addition, we construct star formation rate (SFR) maps, and find that the SFR is correlated with the dust/s...

  18. Newton to Einstein — dust to dust

    Energy Technology Data Exchange (ETDEWEB)

    Kopp, Michael; Uhlemann, Cora; Haugg, Thomas, E-mail: michael.kopp@physik.lmu.de, E-mail: cora.uhlemann@physik.lmu.de, E-mail: thomas.haugg@physik.lmu.de [Arnold Sommerfeld Center for Theoretical Physics, Ludwig-Maximilian University Munich, Theresienstr. 37, Munich, 80333 (Germany)

    2014-03-01

    We investigate the relation between the standard Newtonian equations for a pressureless fluid (dust) and the Einstein equations in a double expansion in small scales and small metric perturbations. We find that parts of the Einstein equations can be rewritten as a closed system of two coupled differential equations for the scalar and transverse vector metric perturbations in Poisson gauge. It is then shown that this system is equivalent to the Newtonian system of continuity and Euler equations. Brustein and Riotto (2011) conjectured the equivalence of these systems in the special case where vector perturbations were neglected. We show that this approach does not lead to the Euler equation but to a physically different one with large deviations already in the 1-loop power spectrum. We show that it is also possible to consistently set to zero the vector perturbations which strongly constrains the allowed initial conditions, in particular excluding Gaussian ones such that inclusion of vector perturbations is inevitable in the cosmological context. In addition we derive nonlinear equations for the gravitational slip and tensor perturbations, thereby extending Newtonian gravity of a dust fluid to account for nonlinear light propagation effects and dust-induced gravitational waves.

  19. Household Consumption, Investment and Life Insurance

    DEFF Research Database (Denmark)

    Bruhn, Kenneth; Steffensen, Mogens

    2011-01-01

    This paper develops a continuous-time Markov model for utility optimization of households. The household optimizes expected future utility from consumption by controlling consumption, investments and purchase of lifeinsurance for each person in the household. The optimal controls are investigated...

  20. Division of household tasks and financial management

    NARCIS (Netherlands)

    Antonides, G.

    2011-01-01

    Both the standard economic model and bargaining theory make predictions about financial management and the division of household labor between household partners. Using a large Internet survey, we have tested several predictions about task divisions reported by Dutch household partners. The division

  1. Spending time and money within the household

    DEFF Research Database (Denmark)

    Browning, Martin; Gørtz, Mette

    We consider theoretically and empirically the allocation of time and money within the household. The novelty of our empirical work is that we have a survey which provides information on both time use and the allocation of some goods within the household, for the same households. We can consider w...

  2. Spending time and money within the household

    DEFF Research Database (Denmark)

    Browning, Martin; Gørtz, Mette

    We consider theoretically and empirically the allocation of time and money within the household. The novelty of our empirical work is that we have a survey which provides information on both time use and the allocation of some goods within the household, for the same households. We can consider...

  3. Dust Attenuation in Hydrodynamic Simulations of Spiral Galaxies

    CERN Document Server

    Rocha, M; Primack, J R; Cox, T J; Rocha, Miguel; Jonsson, Patrik; Primack, Joel R.

    2007-01-01

    We study the effects of dust in hydrodynamic simulations of spiral galaxies when different radial metallicity gradients are assumed. SUNRISE, a Monte-Carlo radiative-transfer code, is used to make detailed calculations of the internal extinction of disk galaxies caused by their dust content. SUNRISE is used on eight different Smooth Particle Hydrodynamics (SPH) simulations of isolated spiral galaxies. These galaxies vary mainly in mass and hence luminosity, spanning a range in luminosities from -16 to -22 magnitudes in the B band. We focus on the attenuation in different wavelength bands as a function of the disk inclination and the luminosity of the models, and compare this to observations. Observations suggest different metallicity gradients for galaxies of different luminosities. These metallicity gradients were explored in our different models, finding that the resulting dust attenuation matches observations for edge-on galaxies, but do not show a linear behaviour in log axis ratio as some observations ha...

  4. Applicability of coatings to control metal dusting

    NARCIS (Netherlands)

    Hermse, C.G.M.; Wortel, J.C. van

    2009-01-01

    We have performed a long term comparative study between five wrought and three centricast materials, both as-is, and in coated condition. Two commercially available coatings were applied to each different alloy. One coating was aluminum based with a chromium rich intermediate layer. The other coatin

  5. Aspects of Household Cooling Technology

    OpenAIRE

    Mrzyglod, Matthias; Holzer, Stefan

    2014-01-01

    Actually available household cooling appliances in the highest efficiency class may consume less then 10W average electrical power. To achieve such power consumptions special challenges for the cooling system had to overcome. The related cooling system design has to consider several effects, which arise from the corresponding low cooling capacity demand, start/stop cycles and additional power consumptions by control accessories. The lecture provides symptomatic aspects of cooling technology, ...

  6. Characterization of steel mill electric-arc furnace dust.

    Science.gov (United States)

    Sofilić, Tahir; Rastovcan-Mioc, Alenka; Cerjan-Stefanović, Stefica; Novosel-Radović, Vjera; Jenko, Monika

    2004-06-18

    In order to make a complete characterization of electric-arc furnace (EAF) dust, as hazardous industrial waste, and to solve its permanent disposal and/or recovery, bearing in mind both the volumes formed in the Croatian steel industry and experiences of developed industrial countries, a study of its properties was undertaken. For this purpose, samples of EAF dust, taken from the regular production process in the Zeljezara Sisak Steel Mill between December 2000 and December 2001, were subjected to a series of tests. The chemical composition of EAF dust samples was investigated by means of a several different analytical methods. The results from the chemical analysis show that the approximate order of abundance of major elements in EAF dusts is as follows: Fe, Zn, Mn, Ca, Mg, Si, Pb, S, Cr, Cu, Al, C, Ni, Cd, As and Hg. Granular-metric composition of single samples was determined by applying sieve separation. Scanning electron micro-structural examination of EAF dust microstructure was performed and results indicated that all twelve EAF dusts were composed of solid spherical agglomerates with Fe, Zn, Pb, O, Si and Ca as the principal element. The investigation of grain morphology and the mineralogical composition of EAF dust were taken by combination of high resolution Auger electron spectroscopy (HR AES), X-ray photoelectron spectroscopy (XPS) and X-ray powder diffraction analysis. The analysis of XPS-spectra determined the presence of zinc in the form of ZnO phase and the presence of lead in the form of PbO phase, i.e. PbSO3/PbSO4 forms. The results of the X-ray diffraction phase analysis show that the basis of the examined EAF dust samples is made of a mixture of metal oxides, silicates and sulphates. The metal concentration, anions, pH value and conductivity in water eluates was determined in order to define the influence of EAF dust on the environment.

  7. A BIOPHYSIOCHEMICAL ANALYSIS OF SETTLED LIVESTOCK AND POULTRY HOUSING DUSTS

    Directory of Open Access Journals (Sweden)

    Carresse Gerald

    2014-01-01

    Full Text Available The levels and composition of agricultural dusts are influenced by animal species, production strategy, housing type and ventilation efficiency. Agricultural dust within animal houses is complex and consists of feed particles, microbes and their products, dander, fecal matter, gases, metals and other organic and inorganic components. Livestock and poultry production facilities may be categorized as confinement, semi-confinement or pasture-based. Characterization of animal husbandry building dust will provide insight into understanding exposures experienced by animals, workers and farm visitors. The goal was to characterize biophysiochemical features of livestock dusts from swine, small ruminant, equine, poultry and cattle husbandry units. Settled dust samples were collected from livestock and poultry housing units at the University Farm and other livestock farms across the state. Morphological features were determined by electron microscopy and gravimetry. Biochemical evaluation consisted of pH determination and trace metal detection via mass spectrometry. Biological assessment centered on bacterial characterization via selective media, DNA analysis and endotoxin quantitation. Morphological analyses revealed higher levels of respirable and thoracic particles in poultry, swine, small ruminant and equine units compared to the dairy unit (p<0.01. Dusts were slightly acidic with the exception of the NCAT small ruminant unit (p<0.05. Dust endotoxin levels were consistent and bacterial species detected include Listeria and Escherichia coli. These findings suggest animal husbandry buildings harbor higher levels of smaller respirable and thoracic dust particles compared to inhalable particles. This information may be helpful in understanding dust exposures experienced by animals, farmers and agricultural workers.

  8. Physico-chemical characterisation of material fractions in residual and source-segregated household waste in Denmark.

    Science.gov (United States)

    Götze, R; Pivnenko, K; Boldrin, A; Scheutz, C; Astrup, T Fruergaard

    2016-08-01

    Physico-chemical waste composition data are paramount for the assessment and planning of waste management systems. However, the applicability of data is limited by the regional, temporal and technical scope of waste characterisation studies. As Danish and European legislation aims for higher recycling rates evaluation of source-segregation and recycling chains gain importance. This paper provides a consistent up-to-date dataset for 74 physico-chemical parameters in 49 material fractions from residual and 24 material fractions from source-segregated Danish household waste. Significant differences in the physico-chemical properties of residual and source-segregated waste fractions were found for many parameters related to organic matter, but also for elements of environmental concern. Considerable differences in potentially toxic metal concentrations between the individual recyclable fractions within one material type were observed. This indicates that careful planning and performance evaluation of recycling schemes are important to ensure a high quality of collected recyclables. Rare earth elements (REE) were quantified in all waste fractions analysed, with the highest concentrations of REE found in fractions with high content of mineral raw materials, soil materials and dust. The observed REE concentrations represent the background concentration level in non-hazardous waste materials that may serve as a reference point for future investigations related to hazardous waste management. The detailed dataset provided here can be used for assessments of waste management solutions in Denmark and for the evaluation of the quality of recyclable materials in waste.

  9. The anthropogenic magnetic particles contain in indoor dust as markers of pollution emitted by different outside sources.

    Science.gov (United States)

    Szczepaniak, Iga; Górka-Kostrubiec, Beata

    2015-04-01

    The aim of the study was to explain the impact of magnetic particles originated from different external sources of pollution on the air quality inside apartments. We used the indoor dust as an indicator of air pollution inside apartments. For the study, a small town was chosen, in which dominated the local sources of pollution: (1) vehicle traffic (in the city center), (2) local heating plant, (3) individual households (in the suburbs) and (4) re-emission of soil particles from the contaminated post-industrial area. In each of four areas were selected several private apartments as a sampling points. Dust samples were collected by the owners of apartments from the floor surface using vacuum cleaners in the same time period (September 2014). The concentration-dependent magnetic parameters (magnetic susceptibility - and magnetization MS) were used to determine the level of the magnetic pollution of the indoor dust. The properties of magnetic particles (mineralogy, domain structure and grain size), and their chemical composition were used to describe and identify the source of air pollution inside the apartments. Generally, the results showed that in each of studied areas were observed flats with both: very high and low values of parameters depending on the concentration of magnetic particles. The biggest differences between the areas were visible in mineralogy of magnetic fraction of pollution. The research of apartments exposed to pollution generated by vehicle traffic (located in the city center) show a wide range of values χ (75-1021 -10-8 m3kg-1) and MS (35-656 -10-3 Am2kg-1). These differences were due to the high contribution of pure iron to magnetic fraction of pollution. Detailed analysis of the M (T) curves revealed two magnetic transitions: first at a temperature Tc = 585oC for magnetite and the second at Tc = 760oC for pure iron. For the dust samples from the city center the high values of χ and MS well correlated with high level of anthropogenic elements

  10. Household hazardous waste in municipal landfills: contaminants in leachate.

    Science.gov (United States)

    Slack, R J; Gronow, J R; Voulvoulis, N

    2005-01-20

    Household hazardous waste (HHW) includes waste from a number of household products such as paint, garden pesticides, pharmaceuticals, photographic chemicals, certain detergents, personal care products, fluorescent tubes, waste oil, heavy metal-containing batteries, wood treated with dangerous substances, waste electronic and electrical equipment and discarded CFC-containing equipment. Data on the amounts of HHW discarded are very limited and are hampered by insufficient definitions of what constitutes HHW. Consequently, the risks associated with the disposal of HHW to landfill have not been fully elucidated. This work has focused on the assessment of data concerning the presence of hazardous chemicals in leachates as evidence of the disposal of HHW in municipal landfills. Evidence is sought from a number of sources on the occurrence in landfill leachates of hazardous components (heavy metals and xenobiotic organic compounds [XOC]) from household products and the possible disposal-to-emissions pathways occurring within landfills. This review demonstrates that a broad range of xenobiotic compounds occurring in leachate can be linked to HHW but further work is required to assess whether such compounds pose a risk to the environment and human health as a result of leakage/seepage or through treatment and discharge.

  11. Oblique dust density waves

    Science.gov (United States)

    Piel, Alexander; Arp, Oliver; Menzel, Kristoffer; Klindworth, Markus

    2007-11-01

    We report on experimental observations of dust density waves in a complex (dusty) plasma under microgravity. The plasma is produced in a radio-frequency parallel-plate discharge (argon, p=15Pa, U=65Vpp). Different sizes of dust particles were used (3.4 μm and 6.4μm diameter). The low-frequency (f 11Hz) dust density waves are naturally unstable modes, which are driven by the ion flow in the plasma. Surprisingly, the wave propagation direction is aligned with the ion flow direction in the bulk plasma but becomes oblique at the boundary of the dust cloud with an inclination of 60^o with respect to the plasma boundary. The experimental results are compared with a kinetic model in the electrostatic approximation [1] and a fluid model [2]. Moreover, the role of dust surface waves is discussed. [1] M. Rosenberg, J. Vac. Sci. Technol. A 14, 631 (1996) [2] A. Piel et al, Phys. Rev. Lett. 97, 205009 (2006)

  12. The Dust-to-Gas Ratio in the Small Magellanic Cloud Tail

    CERN Document Server

    Gordon, K D; Müller, E; Misselt, K A; Bolatto, A; Bernard, J -P; Reach, W; Engelbracht, C W; Babler, B; Bracker, S; Block, M; Clayton, G C; Hora, J; Indebetouw, R; Israel, F P; Li, A; Madden, S; Meade, M; Meixner, M; Sewilo, M; Shiao, B; Smith, L J; van Loon, J Th; Whitney, B A

    2008-01-01

    The Tail region of the Small Magellanic Cloud (SMC) was imaged using the MIPS instrument on the Spitzer Space Telescope as part of the SAGE-SMC Spitzer Legacy. Diffuse infrared emission from dust was detected in all the MIPS bands. The Tail gas-to-dust ratio was measured to be 1200 +/- 350 using the MIPS observations combined with existing IRAS and HI observations. This gas-to-dust ratio is higher than the expected 500-800 from the known Tail metallicity indicating possible destruction of dust grains. Two cluster regions in the Tail were resolved into multiple sources in the MIPS observations and local gas-to-dust ratios were measured to be ~440 and ~250 suggests dust formation and/or significant amounts of ionized gas in these regions. These results support the interpretation that the SMC Tail is a tidal tail recently stripped from the SMC that includes gas, dust, and young stars.

  13. Simulation of windblown dust transport from a mine tailings impoundment using a computational fluid dynamics model

    OpenAIRE

    Stovern, Michael; Felix, Omar; Csavina, Janae; Kyle P. Rine; Russell, MacKenzie R.; Jones, Robert M; King, Matt; Betterton, Eric A.; Sáez, A. Eduardo

    2014-01-01

    Mining operations are potential sources of airborne particulate metal and metalloid contaminants through both direct smelter emissions and wind erosion of mine tailings. The warmer, drier conditions predicted for the Southwestern US by climate models may make contaminated atmospheric dust and aerosols increasingly important, due to potential deleterious effects on human health and ecology. Dust emissions and dispersion of dust and aerosol from the Iron King Mine tailings in Dewey-Humboldt, Ar...

  14. Planar dust-acoustic waves in electron-positron-ion-dust plasmas with dust size distribution

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hong-Yan; Zhang, Kai-Biao [Sichuan University of Science and Engineering, Zigong (China)

    2014-06-15

    Nonlinear dust-acoustic solitary waves which are described with a Kortweg-de vries (KdV) equation by using the reductive perturbation method, are investigated in a planar unmagnetized dusty plasma consisting of electrons, positrons, ions and negatively-charged dust particles of different sizes and masses. The effects of the power-law distribution of dust and other plasma parameters on the dust-acoustic solitary waves are studied. Numerical results show that the dust size distribution has a significant influence on the propagation properties of dust-acoustic solitons. The amplitudes of solitary waves in the case of a power-law distribution is observed to be smaller, but the soliton velocity and width are observed to be larger, than those of mono-sized dust grains with an average dust size. Our results indicate that only compressed solitary waves exist in dusty plasma with different dust species. The relevance of the present investigation to interstellar clouds is discussed.

  15. Radial distribution of stars, gas and dust in SINGS galaxies. II. Derived dust properties

    CERN Document Server

    Muñoz-Mateos, J C; Boissier, S; Zamorano, J; Dale, D A; Pérez-González, P G; Gallego, J; Madore, B F; Bendo, G; Thornley, M D; Draine, B T; Boselli, A; Buat, V; Calzetti, D; Moustakas, J; Kennicutt, R C; 10.1088/0004-637X/701/2/1965

    2009-01-01

    We present a detailed analysis of the radial distribution of dust properties in the SINGS sample, performed on a set of UV, IR and HI surface brightness profiles, combined with published molecular gas profiles and metallicity gradients. The internal extinction, derived from the TIR-to-FUV luminosity ratio, decreases with radius, and is larger in Sb-Sbc galaxies. The TIR-to-FUV ratio correlates with the UV spectral slope beta, following a sequence shifted to redder UV colors with respect to that of starbursts. The star formation history (SFH) is identified as the main driver of this departure. We have also derived radial profiles of the total dust mass surface density, the fraction of the dust mass contributed by PAHs, the fraction of the dust mass heated by very intense starlight and the intensity of the radiation field heating the grains. The dust profiles are exponential, their radial scale-length being constant from Sb to Sd galaxies (only ~10% larger than the stellar scale-length). Many S0/a-Sab galaxies ...

  16. Canadian House Dust Study: Population-based concentrations, loads and loading rates of arsenic, cadmium, chromium, copper, nickel, lead, and zinc inside urban homes

    Energy Technology Data Exchange (ETDEWEB)

    Rasmussen, Pat E. [Exposure and Biomonitoring Division, Healthy Environments and Consumer Safety Branch, Health Canada, 50 Colombine Driveway, Ottawa, ON, Canada K1A 0K9 (Canada); Department of Earth Sciences, University of Ottawa, 140 Louis Pasteur, Ottawa, ON, Canada K1N 6N5 (Canada); Levesque, Christine [Exposure and Biomonitoring Division, Healthy Environments and Consumer Safety Branch, Health Canada, 50 Colombine Driveway, Ottawa, ON, Canada K1A 0K9 (Canada); Chénier, Marc; Gardner, H. David [Exposure and Biomonitoring Division, Healthy Environments and Consumer Safety Branch, Health Canada, 50 Colombine Driveway, Ottawa, ON, Canada K1A 0K9 (Canada); Department of Earth Sciences, University of Ottawa, 140 Louis Pasteur, Ottawa, ON, Canada K1N 6N5 (Canada); Jones-Otazo, Heather [Regions and Programs Branch, Health Canada, 180 Queen Street West, Toronto, ON, Canada M5V 3L7 (Canada); Petrovic, Sanya [Contaminated Sites Division, Healthy Environments and Consumer Safety Branch, Health Canada, 269 Laurier Ave West, Ottawa, ON, Canada K1A 0K9 (Canada)

    2013-01-15

    The Canadian House Dust Study was designed to obtain nationally representative urban house dust metal concentrations (μg g{sup −1}) and metal loadings (μg m{sup −2}) for arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn). Consistent sampling of active dust of known age and provenance (area sampled) also permitted the calculation of indoor loading rates (mg m{sup −2} day{sup −1} for dust and μg m{sup −2} day{sup −1} for metals) for the winter season (from 2007 to 2010) when houses are most tightly sealed. Geomean/median indoor dust loading rates in homes located more than 2 km away from industry of any kind (9.6/9.1 mg m{sup −2} day{sup −1}; n = 580) were significantly lower (p < .001) than geomean (median) dust loading rates in homes located within 2 km of industry (13.5/13.4 mg m{sup −2} day{sup −1}; n = 421). Proximity to industry was characterized by higher indoor metal loading rates (p < .003), but no difference in dust metal concentrations (.29 ≥ p ≤ .97). Comparisons of non-smokers' and smokers' homes in non-industrial zones showed higher metal loading rates (.005 ≥ p ≤ .038) in smokers' homes, but no difference in dust metal concentrations (.15 ≥ p ≤ .97). Relationships between house age and dust metal concentrations were significant for Pb, Cd and Zn (p < .001) but not for the other four metals (.14 ≥ p ≤ .87). All seven metals, however, displayed a significant increase in metal loading rates with house age (p < .001) due to the influence of higher dust loading rates in older homes (p < .001). Relationships between three measures of metals in house dust – concentration, load, and loading rate – in the context of house age, smoking behavior and urban setting consistently show that concentration data is a useful indicator of the presence of metal sources in the home, whereas dust mass is the overriding influence on metal loadings and loading rates

  17. Analysis of Inhalable Dust Produced in Manufacturing of Wooden Furniture

    Directory of Open Access Journals (Sweden)

    Naxin Yuan

    2014-10-01

    Full Text Available To provide an in-depth understanding of preventing occupational diseases and improving working conditions, characteristics of inhalable dust were studied. The results showed that total dust concentration (TDC from mechanical sanding, portable planning and sanding, putty sanding, and painting sanding with inadequate exhaust ventilation were higher than occupational exposure limits (OELs. The more the furniture material was sanded and the worse the dust exhaust apparatus, the higher the TDC was. The TDC from portable planer sanding and dry sanding and putty sanding was in the range from 8.4 mg/m3 to 8.7 mg/m3 and from 5.3 mg/m3 to 8.4 mg/m3, respectively. The TDC from mechanical sanding and painting sanding was in the range from 4.4 to 6.4 mg/m3 and from 3.4 mg/m3 to 4.9 mg/m3, respectively. More than 90% suspended particulate matter in their TDC had a PM10 in all aforementioned results. The sanding procedure produced 6.7% to 8.2% free silica in the total particulate matter, in addition to wood dust, putty dust, or painting dust. Heavy metals in dust from putty sanding and painting exceeding the OELs were lead (Pb; > 0.3 mg/m3 and cadmium (Cd; > 0.01 mg/m3. There was a large amount of granular grinding material, cluster putty, planar painting dust, and a small amount fibroid wood dust in the dust from putty sanding and painting sanding.

  18. Dust exposure in Finnish foundries.

    Science.gov (United States)

    Siltanen, E; Koponen, M; Kokko, A; Engström, B; Reponen, J

    1976-01-01

    Dust measurements were made in 51 iron, 9 steel, and 8 nonferrous foundries, at which 4,316 foundrymen were working. The sampling lasted at least two entire shifts or work days continuously during various operations in each foundry. The dust samples were collected at fixed sites or in the breathing zones of the workers. The mass concentration was determined by weighing and the respirable dust fraction was separated by liquid sedimentation. The free silica content was determined by X-ray diffraction. In the study a total of 3,188 samples were collected in the foundries and 6,505 determinations were made in the laboratory. The results indicated a definite difference in the dust exposure during various operations. The highest dust exposures were found during furnace, cupola, and pouring ladle repair. During cleaning work, sand mixing, and shake-out operations excessive silica dust concentrations were also measured. The lowest dust concentrations were measured during melting and pouring operations. Moderate dust concentrations were measured during coremaking and molding operations. The results obtained during the same operations of iron and steel foundries were similar. The distribution of the workers into various exposure categories, the content of respirable dust and quartz, the correlation between respirable dust and total dust, and the correlation between respirable silica and total dust concentrations are discussed. Observations concerning dust suppression and control methods are briefly considered.

  19. Analytical Study of Nonlinear Dust Acoustic Waves in Two-Dimensional Dust Plasma with Dust Charge Variation

    Institute of Scientific and Technical Information of China (English)

    LIN Chang; ZHANG Xiu-Lian

    2005-01-01

    The nonlinear dust acoustic waves in two-dimensional dust plasma with dust charge variation is analytically investigated by using the formally variable separation approach. New analytical solutions for the governing equation of this system have been obtained for dust acoustic waves in a dust plasma for the first time. We derive exact analytical expressions for the general case of the nonlinear dust acoustic waves in two-dimensional dust plasma with dust charge variation.

  20. Genesis and evolution of dust in the early Universe

    Science.gov (United States)

    Gall, Christa

    2010-10-01

    depends on the assumed IMF. AGB stars dominate the dust production if SNe produce " 3 × 10-3 M⊙ of dust whereas SNe dominate if they are more efficient. The mass ranges of 8-12M⊙ and 12-20 M⊙ for SNe are equally important and dominate the overall SN contribution regardless of the IMF. A main part of the thesis is devoted to the development of a numerical galactic chemical evolution model. The model is constructed such that the effect of a wide range of parameters can be investigated. We ascertain the temporal progression of the xv dustmass, the dust-to-gas and dust-to-metalmass ratios aswell as other physical properties of a galaxy and study their dependence on the mass of the galaxy, the IMF, dust production efficiencies and the degree of dust destruction in the interstellar medium (ISM). From this study we find that the amount of dust and the physical properties of a galaxy strongly depend on the initial gas mass available. Overall, while the total amount of dust produced increases with galaxy mass, the detailed outcome depends on the SN dust production efficiency, the IMF and the strength of dust destruction in the ISM. Dust production with a dominant contribution by AGB stars is found to be insufficient to account for the dust masses in excess of 108 M⊙ within 400 Myr after starburst. Furthermore, we investigate the influence of the star formation rate (SFR) of the starburst on the evolution of various quantities such as the amount of dust and gas, stellar masses, SFRs and the metallicity. We aim to determine the earliest epochs at which an agreement with observationally derived physical properties of QSOs at z ! 6 can be achieved. We apply the obtained results to individual QSOs at z ! 6. We find that large quantities of dust can be generated rapidly as early as 30 Myr after the onset of the starburstwhen the SFR of the starburst is ˜ 103 M⊙ yr-1. The amount of dust and several physical quantities of individual QSOs at z ! 6 are satisfactorily reproduced

  1. Interstellar Silicate Dust Grain Properties in Distant Galaxies Probed by Quasar Absorption Systems

    Science.gov (United States)

    Aller, Monique C.; Kulkarni, Varsha P.; York, Donald G.; Welty, Daniel E.; Vladilo, Giovanni; Som, Debopam

    2015-01-01

    Dust grains are a fundamental component of the interstellar medium, and significantly impact many of the physical processes driving galaxy evolution, including star formation, and the heating, cooling and ionization of interstellar material. Using the absorption features produced by dust in the spectra of luminous background quasars, it is possible to study the properties of extragalactic interstellar dust grains. We will present results from an ongoing program utilizing existing Spitzer Space Telescope infrared quasar spectra to probe silicate dust grain properties in z<1.4 quasar absorption systems. In combination with complementary ground-based data on associated gas-phase metal absorption lines, we explore connections between the interstellar dust and gas in the quasar absorption systems. Our project yields clear detections of the 10 micron silicate dust absorption feature in the studied systems, as well as detections of the 18 micron silicate dust absorption feature in sources with adequate spectral coverage. Based on measured variations in the breath, peak wavelength, and substructure of the 10 micron absorption features, there appear to be differences in the silicate dust grain properties from system-to-system. We also show indications of trends between the gas-phase metal properties, such as metallicity and gas velocity spread, with the silicate dust grain absorption properties. Support for this work is provided by NASA through an award issued by JPL/Caltech and through NASA grant NNX14AG74G, and from National Science Foundation grants AST-0908890 and AST-1108830 to the University of South Carolina.

  2. Dust reddening in star-forming galaxies

    CERN Document Server

    Xiao, Ting; Wang, Huiyuan; Zhou, Hongyan; Lu, HongLin; Dong, Xiaobo

    2011-01-01

    We present empirical relations between the global dust reddening and other physical galaxy properties including the Halpha luminosity, Halpha surface brightness, metallicity and axial ratio for star-forming disc galaxies. The study is based on a large sample of ~22 000 well-defined star-forming galaxies selected from the Sloan Digital Sky Survey (SDSS). The reddening parameterized by color excess E(B-V) is derived from the Balmer decrement. Besides the dependency of reddening on Halpha luminosity / surface brightness and gas phase metallicity, it is also correlated with the galaxy inclination, in the sense that edge-on galaxies are more attenuated than face-on galaxies at a give intrinsic luminosity. In light of these correlations, we present the empirical formulae of E(B-V) as a function of these galaxy properties, with a scatter of only 0.07 mag. The empirical relation can be reproduced if most dust attenuation to the HII region is due to diffuse background dust distributing in a disc thicker than that of H...

  3. Dust Devil Days

    Science.gov (United States)

    2004-01-01

    [figure removed for brevity, see original site] Released 6 July 2004 The atmosphere of Mars is a dynamic system. Water-ice clouds, fog, and hazes can make imaging the surface from space difficult. Dust storms can grow from local disturbances to global sizes, through which imaging is impossible. Seasonal temperature changes are the usual drivers in cloud and dust storm development and growth. Eons of atmospheric dust storm activity has left its mark on the surface of Mars. Dust carried aloft by the wind has settled out on every available surface; sand dunes have been created and moved by centuries of wind; and the effect of continual sand-blasting has modified many regions of Mars, creating yardangs and other unusual surface forms. Dust devils, small cyclonic wind storms, are common in the American Southwest and on Mars. As the dust devil moves across the surface it picks up the loose dust, leaving behind a dark track to mark its passage. These dust devil tracks are in the Argyre Basin. Image information: VIS instrument. Latitude -46.6, Longitude 317.5 East (42.5 West). 19 meter/pixel resolution. Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time. NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the

  4. Dust Devil Tracks

    Science.gov (United States)

    Reiss, Dennis; Fenton, Lori; Neakrase, Lynn; Zimmerman, Michael; Statella, Thiago; Whelley, Patrick; Rossi, Angelo Pio; Balme, Matthew

    2016-11-01

    Dust devils that leave dark- or light-toned tracks are common on Mars and they can also be found on the Earth's surface. Dust devil tracks (hereinafter DDTs) are ephemeral surface features with mostly sub-annual lifetimes. Regarding their size, DDT widths can range between ˜1 m and ˜1 km, depending on the diameter of dust devil that created the track, and DDT lengths range from a few tens of meters to several kilometers, limited by the duration and horizontal ground speed of dust devils. DDTs can be classified into three main types based on their morphology and albedo in contrast to their surroundings; all are found on both planets: (a) dark continuous DDTs, (b) dark cycloidal DDTs, and (c) bright DDTs. Dark continuous DDTs are the most common type on Mars. They are characterized by their relatively homogenous and continuous low albedo surface tracks. Based on terrestrial and martian in situ studies, these DDTs most likely form when surficial dust layers are removed to expose larger-grained substrate material (coarse sands of ≥500 μm in diameter). The exposure of larger-grained materials changes the photometric properties of the surface; hence leading to lower albedo tracks because grain size is photometrically inversely proportional to the surface reflectance. However, although not observed so far, compositional differences (i.e., color differences) might also lead to albedo contrasts when dust is removed to expose substrate materials with mineralogical differences. For dark continuous DDTs, albedo drop measurements are around 2.5 % in the wavelength range of 550-850 nm on Mars and around 0.5 % in the wavelength range from 300-1100 nm on Earth. The removal of an equivalent layer thickness around 1 μm is sufficient for the formation of visible dark continuous DDTs on Mars and Earth. The next type of DDTs, dark cycloidal DDTs, are characterized by their low albedo pattern of overlapping scallops. Terrestrial in situ studies imply that they are formed when sand

  5. Dust during the Reionization

    CERN Document Server

    Elfgren, E; Elfgren, Erik

    2003-01-01

    The possibility that population III stars have reionized the Universe at redshifts greater than 6 has recently gained momentum with WMAP polarization results. Here we analyse the role of early dust produced by these stars and ejected into the intergalactic medium. We show that this dust, heated by the radiation from the same population III stars, produces a submillimetre excess. The electromagnetic spectrum of this excess is compatible with the FIRAS (Far Infrared Absolute Spectrophotometer) cosmic far infrared background. This spectrum, a Doppler spectrum times the $\

  6. Status of metal levels and their potential sources of contamination in Southeast Asian rivers.

    Science.gov (United States)

    Chanpiwat, Penradee; Sthiannopkao, Suthipong

    2014-01-01

    To assess the concentration and status of metal contaminants in four major Southeast Asian river systems, water were collected from the Tonle Sap-Bassac Rivers (Cambodia), Citarum River (Indonesia), lower Chao Phraya River (Thailand), and Saigon River (Vietnam) in both dry and wet seasons. The target elements were Be, Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Mo, Ag, Cd, Ba, Tl, and Pb and the concentrations exceeded the background metal concentrations by 1- to 88-fold. This distinctly indicates enrichment by human urban area activities. The results of a normalization technique used to distinguish natural from enriched metal concentrations confirmed contamination by Al, Cd, Co, Mn, Ni, Pb, and Zn. Cluster analysis revealed the probable source of metals contamination in most sampling sites on all rivers studied to be anthropogenic, including industrial, commercial, and residential activities. Stable lead isotopes analyses applied to track the sources and pathways of anthropogenic lead furthermore confirmed that anthropogenic sources of metal contaminated these rivers. Discharges of wastewater from both industrial and household activities were major contributors of Pb into the rivers. Non-point sources, especially road runoff and street dust, also contributed contamination from Pb and other metals.

  7. Transition rates of selected metals determined in various types of teas (Camellia sinensis L. Kuntze) and herbal/fruit infusions.

    Science.gov (United States)

    Schulzki, Grit; Nüßlein, Birgit; Sievers, Hartwig

    2017-01-15

    Teas and raw materials used as ingredients of herbal and fruit infusions (HFI) were analysed by means of ICP-MS for their content of aluminium, arsenic, cadmium, copper, lead and mercury in the dry product and in the infusion. Samples of tea (Camellia sinensis L. Kuntze) were selected to include different origins, types (black, green), leaf grades (whole leaf, broken, fannings, dust) and manufacturing techniques (orthodox, "crush, tear, curl"). The selected HFI raw materials (chamomile, elderberries, fennel, hibiscus, mate, peppermint, rooibos and rose hip) cover the most important matrices (flower, fruit, seed, herb, leaf) and reflect the economic significance of these HFI materials in trade. Infusions were prepared under standardised conditions representing typical household brewing. Transition rates for the investigated metals vary significantly but are mostly well below 100%. We propose default transition rates for metals to avoid overestimation of exposure levels from tea/HFI consumption.

  8. Electrostatic Characterization of Lunar Dust

    Science.gov (United States)

    2008-01-01

    To ensure the safety and success of future lunar exploration missions, it is important to measure the toxicity of the lunar dust and its electrostatic properties. The electrostatic properties of lunar dust govern its behavior, from how the dust is deposited in an astronaut s lungs to how it contaminates equipment surfaces. NASA has identified the threat caused by lunar dust as one of the top two problems that need to be solved before returning to the Moon. To understand the electrostatic nature of lunar dust, NASA must answer the following questions: (1) how much charge can accumulate on the dust? (2) how long will the charge remain? and (3) can the dust be removed? These questions can be answered by measuring the electrostatic properties of the dust: its volume resistivity, charge decay, charge-to-mass ratio or chargeability, and dielectric properties.

  9. [Silicosis hazard of silica dusts in diamond mining industry (experimental study)].

    Science.gov (United States)

    Mironova, G E; Bezrukavnikova, L M; Kuz'mina, L P

    2001-01-01

    Slow progressing experimental coniosis was induced by exposure to two samples of silica dust that was obtained from diamond openwork in "Mir" quarry of Yakutia. Moderate fibrogenicity of the dusts studied results from relatively low portions of silica and from metals oxides admixtures.

  10. Households in the smart grid

    DEFF Research Database (Denmark)

    Christensen, Toke Haunstrup; Friis, Freja; Gram-Hanssen, Kirsten

    It is a widespread assumption within the energy sector that the “smart grid” will be a crucial element of a future low-carbon energy system, and households are assigned an important role in this (particularly in relation to balancing consumption and production). However, this raises questions about...... the integration of consumers’ everyday life practices in this system. This paper introduces the ideas of the smart grid and review relevant demonstration projects. Special focus is on the role of consumers and electric vehicles. The paper ends with introducing major research questions and presents a new research...

  11. Car use within the household

    DEFF Research Database (Denmark)

    de Borger, Bruno; Mulalic, Ismir; Rouwendal, Jan

    2013-01-01

    , respectively. When we do take into account the substitution effect, these figures reduce to, respectively, -0.32 and -0.45. We further estimate an alternative version of the model to test the hypothesis that substitution in response to higher fuel prices will be predominantly from the least to the most fuel...... efficient car, finding partial support for the underlying hypothesis. More importantly, the results of this extended model emphasize the importance of behavioural differences related to the position of the most fuel efficient car in the household, suggesting that households’ fuel efficiency choices...

  12. Households in the smart grid

    DEFF Research Database (Denmark)

    Christensen, Toke Haunstrup; Friis, Freja; Gram-Hanssen, Kirsten

    It is a widespread assumption within the energy sector that the “smart grid” will be a crucial element of a future low-carbon energy system, and households are assigned an important role in this (particularly in relation to balancing consumption and production). However, this raises questions about...... the integration of consumers’ everyday life practices in this system. This paper introduces the ideas of the smart grid and review relevant demonstration projects. Special focus is on the role of consumers and electric vehicles. The paper ends with introducing major research questions and presents a new research...

  13. Estrogenic effects from household stoves.

    Science.gov (United States)

    Wu, W Z; Chen, J; Rehmann, K; Schramm, K W; Kettrup

    2002-09-01

    With the application of a genetically modified yeast, estrogen receptor-activating compounds were detected in the soot and emission gas of a wood-burning household stove. The EC50 value of 17beta-estradiol was divided by the EC50 value of soot, and the obtained relative estrogenic value for raw soot was 2.37E-5, indicating that soot was about 100,000 times less estrogenic than 17beta-estradiol. Chemical analysis revealed that alkyl phenol, benzonic acid, and PAHs represented the major constituents in the most potent fractions of the soot. Along with PAHs, other constituents might also contribute to the estrogenicity of soot.

  14. Dust fallout in Kuwait city: deposition and characterization.

    Science.gov (United States)

    Al-Awadhi, Jasem M; Alshuaibi, Arafat A

    2013-09-01

    Dust fallouts in Kuwait city was monitored on monthly basis during the period from March 2011 to February 2012 at 10 locations. The results of this study reveal that: (1) monthly dust deposition rates ranged from 0.002 to 0.32 kg/m(2) with average deposition rate of 0.053 kg/m(2) and annual average deposition rate of 0.59 kg/m(2), ranking the first out of 56 dust deposition rates observed throughout the world; (2) on average, about 55.9% of the settled dust have fine to very fine sand fraction sizes, while silt and clay comprise an average of 37.4 and 1.4% of the total sample, respectively; (3) the concentrations for Zn and Mo out of 15 other elements analyzed from the dust were up to 11 times higher than their soil background values in Kuwait, while Pb and Ni were about seven times higher; (4) Mo, Ni, Pb and Zn show maximum enrichment relative to the upper continental crustal component (Mn); (5) Sr, Zr and Zn show highest concretions among all collected samples; and (6) quartz and calcite were the dominant minerals in the dust samples. The distribution of the heavy metals in dust seems to be controlled mainly by the land uses and the volume of traffic emissions.

  15. Evolution of dust and molecular hydrogen in the Magellanic System

    CERN Document Server

    Yozin, Cameron

    2014-01-01

    We investigate the evolution of the interstellar medium (ISM) in self-consistent, chemodynamical simulations of the Magellanic Clouds (MCs) during their recent (z<0.3) past. An explicit modelling of dust and molecular hydrogen lifecycles enables the comparison of our models against the observed properties of the ISM, including elemental depletion from the gas-phase. Combining this model with a tidal-dominated paradigm for the formation for the Magellanic Stream and Bridge, we reproduce the age-metallicity relations, long gas depletion timescales, and presently observed dust and molecular hydrogen masses of the MCs to within their respective uncertainties. We find that these models' enrichment depends sensitively on the processing of dust within the ISM and the dynamical influence of external tides/stellar bars. The ratio of characteristic dust destruction timescales in our SMC and LMC models, a governing parameter of our models' evolution, is consistent with estimates based on observed supernova (SN) rates...

  16. NEW ULTRAVIOLET EXTINCTION CURVES FOR INTERSTELLAR DUST IN M31

    Energy Technology Data Exchange (ETDEWEB)

    Clayton, Geoffrey C. [Department of Physics and Astronomy, Louisiana State University, Baton Rouge, LA 70803 (United States); Gordon, Karl D.; Bohlin, R. C. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Bianchi, Luciana C. [Department of Physics and Astronomy, The Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218 (United States); Massa, Derck L.; Wolff, Michael J. [Space Science Institute, 4750 Walnut Street, Suite 205, Boulder, CO 80301 (United States); Fitzpatrick, Edward L., E-mail: gclayton@fenway.phys.lsu.edu, E-mail: bohlin@stsci.edu, E-mail: kgordon@stsci.edu, E-mail: bianchi@jhu.edu, E-mail: mjwolff@spacescience.org, E-mail: edward.fitzpatrick@villanova.edu [Department of Astronomy and Astrophysics, Villanova University, 800 Lancaster Avenue, Villanova, PA 19085 (United States)

    2015-12-10

    New low-resolution UV spectra of a sample of reddened OB stars in M31 were obtained with the Hubble Space Telescope/STIS to study the wavelength dependence of interstellar extinction and the nature of the underlying dust grain populations. Extinction curves were constructed for four reddened sightlines in M31 paired with closely matching stellar atmosphere models. The new curves have a much higher signal-to-noise ratio than previous studies. Direct measurements of N(H i) were made using the Lyα absorption lines enabling gas-to-dust ratios to be calculated. The sightlines have a range in galactocentric distance of 5–14 kpc and represent dust from regions of different metallicities and gas-to-dust ratios. The metallicities sampled range from solar to 1.5 solar. The measured curves show similarity to those seen in the Milky Way and the Large Magellanic Cloud. The Maximum Entropy Method was used to investigate the dust composition and size distribution for the sightlines observed in this program, finding that the extinction curves can be produced with the available carbon and silicon abundances if the metallicity is super-solar.

  17. Identification of the exploatation dust in road dust

    Directory of Open Access Journals (Sweden)

    B. Gajdzik

    2012-01-01

    Full Text Available The aim of this publication is to determine models of explore dust from vehicle brake systems and the presentationof measurement results of the exploitation dust, which is separate from road dust. The following methods and measuring devices were used: T-01M device, screen analysis, analysis of chemical composition with the use of a scanning microscope with Energy Dispersive x-ray Spectroscopy (EDS analyser. The measurements for identifying this type of dust were conducted on marked sections of roads: motorway, city road and mountain road. The explored dust was distinguished in the following car systems: brakes, clutch plates, tyres and catalytic converters.

  18. Contamination assessment and spatial distribution of heavy metals in dust surrounding the Changqing town lead-zinc smelting plant in Baoji%宝鸡长青镇铅锌冶炼厂周围灰尘中重金属的空间分布及污染评价

    Institute of Scientific and Technical Information of China (English)

    任春辉; 卢新卫; 陈灿灿; 杨林娜; 杨光

    2012-01-01

    The concentrations of heavy metals in dust samples surrounding the Changqing town lead-zinc smelting plant in Baoji city were measured by X- Ray fluorescence spectrometry. The contamination levels of heavy metals in dust were assessed based on the geo-accumulation index and the enrichment factor. The results show that the average concentrations of Cu, Pb, Zn, Cr, Ni and V in dust were 123.1, 1449.1, 2082.1, 1085.0, 40.8 and 81.8 mg. kg -~ , respectively, which were higher than the corresponding background values of Shaanxi topsoil. The average concentrations of Cu, Pb, Zn, Cr, ~Ni and V in dust were respectively 5.8, 67.7, 30.0, 17.4, 1.4 and 1.2 times the corresponding background values of Shaanxi topsoil. The content of Cu, Pb, Zn, Cr and Ni in dust was the highest within 500 m of lead-zinc smelting plant. The assessment results showed that Cu, Pb, Zn and Cr had different contamination levels in dust around the lead-zinc smelting plant and the contaminated areas were mainly distributed in the northwest and southwest and southeast of lead-zlnc smelting plant. The dust surrounding the Changqing lead-zinc smelting plant were not polluted by Ni and V.%利用X-Ray荧光光谱仪对宝鸡市长青镇铅锌冶炼厂周围灰尘中重金属含量进行了分析,并采用地积累指数和富集因子评价方法评价了灰尘中重金属的污染状况.结果表明,该铅锌厂周围灰尘中Cu、Pb、Zn、Cr、Ni和V的几何平均含量分别为123.1、1449.1、2082.1、1085.0、840.和81.8mg·kg-1,均明显高于陕西省表层土壤背景值,分别为陕西省表层土壤背景值的5.8、67.7、30.0、17.4、1.4和1.2倍.距离铅锌厂500m范围的灰尘中Cu、Pb、Zn、Cr、Ni的含量最高.污染评价结果表明,长青镇铅锌厂周围灰尘中Cu、Pb、Zn、Cr都存在着不同程度的污染,污染区域主要集中在铅锌厂的西北、西南和东南方向,而Ni和V则基本无污染.

  19. Cylindrically symmetric dust spacetime

    CERN Document Server

    Senovilla, J M M; Senovilla, Jose M. M.; Vera, Raul

    2000-01-01

    We present an explicit exact solution of Einstein's equations for an inhomogeneous dust universe with cylindrical symmetry. The spacetime is extremely simple but nonetheless it has new surprising features. The universe is ``closed'' in the sense that the dust expands from a big-bang singularity but recollapses to a big-crunch singularity. In fact, both singularities are connected so that the whole spacetime is ``enclosed'' within a single singularity of general character. The big-bang is not simultaneous for the dust, and in fact the age of the universe as measured by the dust particles depends on the spatial position, an effect due to the inhomogeneity, and their total lifetime has no non-zero lower limit. Part of the big-crunch singularity is naked. The metric depends on a parameter and contains flat spacetime as a non-singular particular case. For appropriate values of the parameter the spacetime is a small perturbation of Minkowski spacetime. This seems to indicate that flat spacetime may be unstable agai...

  20. Cylindrically symmetric dust spacetime

    Science.gov (United States)

    Senovilla, José M. M.

    2000-07-01

    We present an explicit exact solution of Einstein's equations for an inhomogeneous dust universe with cylindrical symmetry. The spacetime is extremely simple but nonetheless it has surprising new features. The universe is `closed' in the sense that the dust expands from a big-bang singularity but recollapses to a big-crunch singularity. In fact, both singularities are connected so that the whole spacetime is `enclosed' within a single singularity of general character. The big-bang is not simultaneous for the dust, and in fact the age of the universe as measured by the dust particles depends on the spatial position, an effect due to the inhomogeneity, and their total lifetime has no non-zero lower limit. Part of the big-crunch singularity is naked. The metric depends on a parameter and contains flat spacetime as a non-singular particular case. For appropriate values of the parameter the spacetime is a small perturbation of Minkowski spacetime. This seems to indicate that flat spacetime may be unstable against some global non-vacuum perturbations.

  1. Left in the Dust

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    NASA's Stardust spacecraft ended its seven-year voyage January 15 after a safe landing on earth, bringing back a capsule of comet particles and samples of interstellar dust that exceeded the loftiest of expectations of mission scientists. The ensuing studies of the cosmic treasure are expected to shed light on the origins of the solar system and earth itself.

  2. Dust devil dynamics

    Science.gov (United States)

    Horton, W.; Miura, H.; Onishchenko, O.; Couedel, L.; Arnas, C.; Escarguel, A.; Benkadda, S.; Fedun, V.

    2016-06-01

    A self-consistent hydrodynamic model for the solar heating-driven onset of a dust devil vortex is derived and analyzed. The toroidal flows and vertical velocity fields are driven by an instability that arises from the inversion of the mass density stratification produced by solar heating of the sandy surface soil. The nonlinear dynamics in the primary temperature gradient-driven vertical airflows drives a secondary toroidal vortex flow through a parametric interaction in the nonlinear structures. While an external tangential shear flow may initiate energy transfer to the toroidal vortex flow, the nonlinear interactions dominate the transfer of vertical-radial flows into a fast toroidal flow. This secondary flow has a vertical vorticity, while the primary thermal gradient-driven flow produces the toroidal vorticity. Simulations for the complex nonlinear structure are carried out with the passive convection of sand as test particles. Triboelectric charging modeling of the dust is used to estimate the charging of the sand particles. Parameters for a Dust Devil laboratory experiment are proposed considering various working gases and dust particle parameters. The nonlinear dynamics of the toroidal flow driven by the temperature gradient is of generic interest for both neutral gases and plasmas.

  3. Fuel choices in urban Indian households

    Energy Technology Data Exchange (ETDEWEB)

    Farsi, Mehdi; Filippini, Massimo [Centre for Energy Policy and Economics, Department of Management, Technology and Economics, ETH Zurich, Switzerland and Department of Economics, University of Lugano, (Switzerland); Pachauri, Shonali [International Institute for Applied Systems Analysis, Schlossplatz 1, A-2361, Laxenburg, (Austria)

    2007-12-15

    This paper applies an ordered discrete choice framework to model fuel choices and patterns of cooking fuel use in urban Indian households. The choices considered are for three main cooking fuels: firewood, kerosene, and LPG (liquid petroleum gas). The models, estimated using a large microeconomic dataset, show a reasonably good performance in the prediction of households' primary and secondary fuel choices. This suggests that ordered models can be used to analyze multiple fuel use patterns in the Indian context. The results show that lack of sufficient income is one of the main factors that retard households from using cleaner fuels, which usually also require the purchase of relatively expensive equipment. The results also indicate that households are sensitive to LPG prices. In addition to income and price, several socio-demographic factors such as education and sex of the head of the household are also found to be important in determining household fuel choice. (Author).

  4. Modeling Dust and Starlight in Galaxies Observed by Spitzer and Herschel: NGC 628 and NGC 6946

    CERN Document Server

    Aniano, G; Calzetti, D; Dale, D A; Engelbracht, C W; Gordon, K D; Hunt, L K; Kennicutt, R C; Krause, O; Leroy, A K; Rix, H-W; Roussel, H; Sandstrom, K; Sauvage, M; Walter, F; Armus, L; Bolatto, A D; Crocker, A; Meyer, J Donovan; Galametz, M; Helou, G; Hinz, J; Johnson, B D; Koda, J; Montiel, E; Murphy, E J; Skibba, R; Smith, J -D T; Wolfire, M G

    2012-01-01

    We characterize the dust in NGC628 and NGC6946, two nearby spiral galaxies in the KINGFISH sample. With data from 3.6um to 500um, dust models are strongly constrained. Using the Draine & Li (2007) dust model, (amorphous silicate and carbonaceous grains), for each pixel in each galaxy we estimate (1) dust mass surface density, (2) dust mass fraction contributed by polycyclic aromatic hydrocarbons (PAH)s, (3) distribution of starlight intensities heating the dust, (4) total infrared (IR) luminosity emitted by the dust, and (5) IR luminosity originating in regions with high starlight intensity. We obtain maps for the dust properties, which trace the spiral structure of the galaxies. The dust models successfully reproduce the observed global and resolved spectral energy distributions (SEDs). The overall dust/H mass ratio is estimated to be 0.0082+/-0.0017 for NGC628, and 0.0063+/-0.0009 for NGC6946, consistent with what is expected for galaxies of near-solar metallicity. Our derived dust masses are larger (by...

  5. Financial Satisfaction from Intra-Household Perspectives

    OpenAIRE

    Namkee Ahn; Victoria Ateca; Arantza Ugidos

    2007-01-01

    We address individuals’ financial satisfaction from the intra-household perspective. Our purpose is twofold. First, we want to contrast the hypothesis of relative income within the household. Does the income level of one individual relative to that of other members of the same household matter in his/her income satisfaction? Second, we want to test procedural utility hypothesis in that different sources of income may contribute differentially to individuals’ income satisfaction. In particular...

  6. Household Air Pollution: Sources and Exposure Levels to Fine Particulate Matter in Nairobi Slums

    Directory of Open Access Journals (Sweden)

    Kanyiva Muindi

    2016-07-01

    Full Text Available With 2.8 billion biomass users globally, household air pollution remains a public health threat in many low- and middle-income countries. However, little evidence on pollution levels and health effects exists in low-income settings, especially slums. This study assesses the levels and sources of household air pollution in the urban slums of Nairobi. This cross-sectional study was embedded in a prospective cohort of pregnant women living in two slum areas—Korogocho and Viwandani