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Sample records for hollow cathode plasma

  1. Sheet Plasma Produced by Hollow Cathode Discharge

    Institute of Scientific and Technical Information of China (English)

    张龙; 张厚先; 杨宣宗; 冯春华; 乔宾; 王龙

    2003-01-01

    A sheet plasma is produced by a hollow cathode discharge under an axial magnetic field.The plasma is about 40cm in length,4 cm in width and 1cm in thickness.The electron density is about 108cm-3.The hollow cathode is made to be shallow with a large opening,which is different from the ordinary deep hollow cathode.A Langmuir probe is used to detect the plasma.The electron density and the spatial distribution of the plasma change when voltage,pressure and the magnetic field vary.A peak and a data fluctuation at about 200 G-300 G are observed in the variation of electron density(or thickness of the sheet plasma)with the magnetic field.Our work will be helpful in characterizing the sheet plasma and will make the production of dense sheet plasma more controllable.

  2. Hollow-Cathode Source Generates Plasma

    Science.gov (United States)

    Deininger, W. D.; Aston, G.; Pless, L. C.

    1989-01-01

    Device generates argon, krypton, or xenon plasma via thermionic emission and electrical discharge within hollow cathode and ejects plasma into surrounding vacuum. Goes from cold start up to full operation in less than 5 s after initial application of power. Exposed to moist air between operations without significant degradation of starting and running characteristics. Plasma generated by electrical discharge in cathode barrel sustained and aided by thermionic emission from emitter tube. Emitter tube does not depend on rare-earth oxides, making it vulnerable to contamination by exposure to atmosphere. Device modified for use as source of plasma in laboratory experiments or industrial processes.

  3. Characteristics of Plasma Spraying Torch with a Hollow Cathode

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A kind of plasma spraying torch with a hollow cathode is described in this paper.The plasma torch can be used for axial powder injection in plasma spray studies. The arc characteristics of the plasma torch with various gas flowrates, different gas media, are presented. The mathematical modeling and computational method are developed for predicting the temperature and velocity field inside the plasma torch.

  4. Hollow cathode heater development for the Space Station plasma contactor

    Science.gov (United States)

    Soulas, George C.

    1993-01-01

    A hollow cathode-based plasma contactor has been selected for use on the Space Station. During the operation of the plasma contactor, the hollow cathode heater will endure approximately 12000 thermal cycles. Since a hollow cathode heater failure would result in a plasma contactor failure, a hollow cathode heater development program was established to produce a reliable heater design. The development program includes the heater design, process documents for both heater fabrication and assembly, and heater testing. The heater design was a modification of a sheathed ion thruster cathode heater. Three heaters have been tested to date using direct current power supplies. Performance testing was conducted to determine input current and power requirements for achieving activation and ignition temperatures, single unit operational repeatability, and unit-to-unit operational repeatability. Comparisons of performance testing data at the ignition input current level for the three heaters show the unit-to-unit repeatability of input power and tube temperature near the cathode tip to be within 3.5 W and 44 degrees C, respectively. Cyclic testing was then conducted to evaluate reliability under thermal cycling. The first heater, although damaged during assembly, completed 5985 ignition cycles before failing. Two additional heaters were subsequently fabricated and have completed 3178 cycles to date in an on-going test.

  5. Modification of W surfaces by exposure to hollow cathode plasmas

    Science.gov (United States)

    Stancu, C.; Stokker-Cheregi, F.; Moldovan, A.; Dinescu, M.; Grisolia, C.; Dinescu, G.

    2017-10-01

    In this work, we assess the surface modifications induced on W samples following exposure to He and He/H2 radiofrequency plasmas in hollow cathode discharge configuration. Our study addresses issues that relate to the use of W in next-generation fusion reactors and, therefore, the investigation of W surface degradation following exposure and heating by plasmas to temperatures above 1000 °C is of practical importance. For these experiments, we used commercially available tungsten samples having areas of 30 × 15 mm and 0.1 mm thickness. The hollow cathode plasma was produced using a radiofrequency (RF) generator (13.56 MHz) between parallel plate electrodes. The W samples were mounted as one of the electrodes. The He and He/H2 plasma discharges had a combined effect of heating and bombardment of the W surfaces. The surface modifications were studied for discharge powers between 200 and 300 W, which resulted in the heating of the samples to temperatures between 950 and 1230 °C, respectively. The samples were weighed prior and after plasma exposure, and loss of mass was measured following plasma exposure times up to 90 min. The analysis of changes in surface morphology was carried out by optical microscopy, scanning electron microscopy and atomic force microscopy. Additionally, optical emission spectra of the respective plasmas were recorded from the region localized inside the hollow cathode gap. We discuss the influence of experimental parameters on the changes in surface morphology.

  6. Life Cycle Tests on a Hollow Cathode Based Plasma Contactor

    Science.gov (United States)

    Vaughn, Jason A.; Schneider, Todd A.; Munafo, Paul (Technical Monitor)

    2001-01-01

    The propulsive Small Expendable Deployer System (ProSEDS) mission is designed to provide an on-orbit demonstration of the electrodynamic propulsion capabilities of tethers in space. The ProSEDS experiment will be a secondary payload on a Delta II unmanned expendable booster with a mission duration of 12 days. A 5-km conductive tether is attached to the Delta II second stage and collects current from the low Earth orbit (LEO) plasma, and a Hollow Cathode Plasma Contactor (HCPC) emits the collected electrons from the Delta II, completing the electrical circuit to the ambient plasma. The HCPC for the ProSEDS mission have made it necessary to turn off the HCPC once a minute throughout the entire mission. Because of the unusual operating requirements by the ProSEDS mission, an engineering development unit of the HCPC was built to demonstrate the HCPC design would start reliably for the life of the ProSEDS mission. During the life test the engineering unit cycled for over 10,000 on/off cycles without missing a single start, and during that same test the HCPC unit demonstrated the capability to emit 0 to 5 A electron emission current. The performance of the HCPC unit during this life test will be discussed.

  7. Status of Hollow Cathode Heater Development for the Space Station Plasma Contactor

    Science.gov (United States)

    Soulas, George C.

    1994-01-01

    A hollow cathode-based plasma contactor has been selected for use on the Space Station. During the operation of the plasma contactor, the hollow cathode heater will endure approximately 12000 thermal cycles. Since a hollow cathode heater failure would result in a plasma contactor failure, a hollow cathode heater development program was established to produce a reliable heater. The development program includes the heater design, process documents for both heater fabrication and assembly, and heater testing. The heater design was a modification of a sheathed ion thruster cathode heater. Heater tests included testing of the heater unit alone and plasma contactor and ion thruster testing. To date, eight heaters have been or are being processed through heater unit testing, two through plasma contactor testing and three through ion thruster testing, all using direct current power supplies. Comparisons of data from heater unit performance tests before cyclic testing, plasma contactor tests, and ion thruster tests at the ignition input current level show the average deviation of input power and tube temperature near the cathode tip to be +/-0.9 W and +/- 21 C, respectively. Heater unit testing included cyclic testing to evaluate reliability under thermal cycling. The first heater, although damaged during assembly, completed 5985 ignition cycles before failing. Four additional heaters successfully completed 6300, 6300, 700, and 700 cycles. Heater unit testing is currently ongoing for three heaters which have to date accumulated greater than 7250, greater than 5500, and greater than 5500 cycles, respectively.

  8. Broadband microwave characteristics of a novel coaxial gridded hollow cathode argon plasma

    Science.gov (United States)

    Gao, Ruilin; Yuan, Chengxun; Li, Hui; Jia, Jieshu; Zhou, Zhong-Xiang; Wang, Ying; Wang, Xiaoou; Wu, Jian

    2016-08-01

    The interaction between microwave and large area plasma is crucially important for space communication. Gas pressure, input power, and plasma volume are critical to both the microwave electromagnetic wave phase shift and electron density. This paper presents a novel type of large coaxial gridded hollow cathode plasma having a 50 cm diameter and a 40 cm thickness. Microwave characteristics are studied using a microwave measurement system that includes two broadband antennae in the range from 2 GHz to 18 GHz. The phase shift under varying gas pressure and input power is shown. In addition, the electron density ne, which varies from 1.2 × 1016 m-3 to 8.7 × 1016 m-3 under different discharge conditions, is diagnosed by the microwave system. The measured results accord well with those acquired by Langmuir Probe measurement and show that the microwave properties in the large volume hollow cathode discharge significantly depend on the input power and gas pressure.

  9. Operational Status of the International Space Station Plasma Contactor Hollow Cathode Assemblies July 2001 to May 2013

    Science.gov (United States)

    Kamhawi, Hani; Yim, John T.; Patterson, Michael J.; Dalton, Penni J.

    2013-01-01

    The International Space Station has onboard two Aerojet Rocketdyne developed plasma contactor units that perform the function of charge control. The plasma contactor units contain NASA Glenn Research Center developed hollow cathode assemblies. NASA Glenn Research Center monitors the on-orbit operation of the flight hollow cathode assemblies. As of May 31, 2013, HCA.001-F has been ignited and operated 123 times and has accumulated 8072 hours of operation, whereas, HCA.003-F has been ignited and operated 112 times and has accumulated 9664 hours of operation. Monitored hollow cathode ignition times and anode voltage magnitudes indicate that they continue to operate nominally.

  10. Operational Status of the International Space Station Plasma Contactor Hollow Cathode Assemblies from July 2011 to May 2013

    Science.gov (United States)

    Kamhawi, Hani; Yim, John T.; Patterson, Michael J.; Dalton, Penni J.

    2014-01-01

    The International Space Station has onboard two Aerojet Rocketdyne developed plasma contactor units that perform the function of charge control. The plasma contactor units contain NASA Glenn Research Center developed hollow cathode assemblies. NASA Glenn Research Center monitors the onorbit operation of the flight hollow cathode assemblies. As of May 31, 2013, HCA.001-F has been ignited and operated 123 times and has accumulated 8072 hours of operation, whereas, HCA.003-F has been ignited and operated 112 times and has accumulated 9664 hours of operation. Monitored hollow cathode ignition times and anode voltage magnitudes indicate that they continue to operate nominally.

  11. Multiple Hollow Cathode Wear Testing for the Space Station Plasma Contactor

    Science.gov (United States)

    Soulas, George C.

    1994-01-01

    A wear test of four hollow cathodes was conducted to resolve issues associated with the Space Station plasma contactor. The objectives of this test were to evaluate unit-to-unit dispersions, verify the transportability of contamination control protocols developed by the project, and to evaluate cathode contamination control and activation procedures to enable simplification of the gas feed system and heater power processor. These objectives were achieved by wear testing four cathodes concurrently to 2000 hours. Test results showed maximum unit-to-unit deviations for discharge voltages and cathode tip temperatures to be +/-3 percent and +/-2 percent, respectively, of the nominal values. Cathodes utilizing contamination control procedures known to increase cathode lifetime showed no trends in their monitored parameters that would indicate a possible failure, demonstrating that contamination control procedures had been successfully transferred. Comparisons of cathodes utilizing and not utilizing a purifier or simplified activation procedure showed similar behavior during wear testing and pre- and post-test performance characterizations. This behavior indicates that use of simplified cathode systems and procedures is consistent with long cathode lifetimes.

  12. Low-Temperature Nitriding of Pure Titanium by using Hollow Cathode RF-DC Plasma

    Science.gov (United States)

    Windajanti, J. M.; S, D. J. Djoko H.; Abdurrouf

    2017-05-01

    Pure titanium is widely used for the structures and mechanical parts due to its high strength, low density, and high corrosion resistance. Unfortunately, titanium products suffer from low hardness and low wear resistance. Titanium’s surface can be modified by nitriding process to overcome such problems, which is commonly conducted at high temperature. Here, we report the low-temperature plasma nitriding process, where pure titanium was utilized by high-density RF-DC plasma combined with hollow cathode device. To this end, a pure titanium plate was set inside a hollow tube placed on the cathode plate. After heating to 450 °C, a pre-sputtering process was conducted for 1 hour to remove the oxide layer and activate the surface for nitriding. Plasma nitriding using N2/H2 gasses was performed in 4 and 8 hours with the RF voltage of 250 V, DC bias of -500 to -600 V, and gas pressure of 75 to 30 Pa. To study the nitriding mechanism as well as the role of hollow cathode, the nitrided specimen was characterized by SEM, EDX, XRD, and micro-hardness equipment. The TiN compound was obtained with the diffusion zone of nitrogen until 5 μm thickness for 4 hours nitriding process, and 8 μm for 8 hours process. The average hardness also increased from 300 HV in the untreated specimen to 624 HV and 792 HV for 4 and 8 hours nitriding, respectively.

  13. Plasma-Surface Interactions in Hollow Cathode Discharges for Electric Propulsion

    Science.gov (United States)

    Capece, Angela Maria

    Electric thrusters generate high exhaust velocities and can achieve specific impulses in excess of 1000 s. The low thrust generation and high specific impulse make electric propulsion ideal for interplanetary missions, spacecraft station keeping, and orbit raising maneuvers. Consequently, these devices have been used on a variety of space missions including Deep Space 1, Dawn, and hundreds of commercial spacecraft in Earth orbit. In order to provide the required total impulses, thruster burn time can often exceed 10,000 hours, making thruster lifetime essential. One of the main life-limiting components on ion engines is the hollow cathode, which serves as the electron source for ionization of the xenon propellant gas. Reactive contaminants such as oxygen can modify the cathode surface morphology and degrade the electron emission properties. Hollow cathodes that operate with reactive impurities in the propellant will experience higher operating temperatures, which increase evaporation of the emission materials and reduce cathode life. A deeper understanding of the mechanisms initiating cathode failure will improve thruster operation, increase lifetime, and ultimately reduce cost. A significant amount of work has been done previously to understand the effects of oxygen poisoning on vacuum cathodes; however, the xenon plasma adds complexity, and its role during cathode poisoning is not completely understood. The work presented here represents the first attempt at understanding how oxygen impurities in the xenon discharge plasma alter the emitter surface and affect operation of a 4:1:1 BaO-CaO-Al2O3 hollow cathode. A combination of experimentation and modeling was used to investigate how oxygen impurities in the discharge plasma alter the emitter surface and reduce the electron emission capability. The experimental effort involved operating a 4:1:1 hollow cathode at various conditions with oxygen impurities in the xenon flow. Since direct measurements of the emitter

  14. Formation of Ti-N graded bioceramic layer by DC hollow-cathode plasma nitriding

    Institute of Scientific and Technical Information of China (English)

    ZHENG Chuan-lin

    2004-01-01

    Ti-N graded ceramic layer was formed on titanium by using DC hollow-cathode plasma nitriding technique. The structure of Ti-N layer was analyzed using X-ray diffractometry(XRD) with Cu Kα radiation, and the microhardness( HV0.1) was measured from the surface to inner along the cross section of Ti-N layer. The results indicate that the Ti-N graded layer is composed of ε-Ti2 N, δ-TiN and α-Ti(N) phases. Mechanism discussion shows that hollow-cathode discharge can intensify gas ionization, increase current density and enhance the nitriding potential, which directly increases the thickness of the diffusion coatings compared with traditional nitriding methods.

  15. Gas-discharge sources with charged particle emission from the plasma of glow discharge with a hollow cathode

    CERN Document Server

    Semenov, A P

    2001-01-01

    One studied properties of a magnetron discharge with a cold hollow and uncooled rod cathodes. One demonstrated the dominant effect of thermoelectron emission of a rod cathode heated in a discharge on characteristics of discharge and on emission properties of a gas-discharge plasma and the possibility pf a smooth transition of glow discharge to diffusion mode of arc discharge combustion. Paper describes sources of ions and electrons with improved physical and generalized design and engineering parameters. One shows the promise of the electrode structure of a hollow cathode magnetron discharge to be used as a source, in particular, of the atomic hydrogen and of atom flow of a working rod cathode

  16. Prediction of the cathodic arc root behaviour in a hollow cathode thermal plasma torch

    Energy Technology Data Exchange (ETDEWEB)

    Freton, Pierre; Gonzalez, Jean-Jacques; Escalier, Gaelle, E-mail: pierre.freton@laplace.univ-tlse.f [Universite de Toulouse, UPS, INPT, LAPLACE (Laboratoire Plasma et Conversion d' Energie), 118 route de Narbonne, F-31062 Toulouse cedex 9 (France)

    2009-10-07

    The upper part of a well type cathode (WTC) plasma torch is modelled for several conditions in an air medium in the presence of an electric arc. The plasma flow created by the electric arc is described and the results compared with the data from the literature. Special attention is paid to the description of arc root attachment and to its movement due to the balance of forces. A fine description of the magnetic field produced by the external solenoid is reported. The model is based on the Fluent software implemented with specific developments to be adapted to the thermal plasma domain. The paper shows the necessity to provide an accurate description of the external magnetic field due to the strong influence of the radial magnetic field component. Overall, we propose an original approach for arc root movement description which contributes to the understanding of the flow behaviour in the WTC torch.

  17. Hollow cathode sustained plasma microjets: Characterization and application to diamond deposition

    Science.gov (United States)

    Sankaran, R. Mohan; Giapis, Konstantinos P.

    2002-09-01

    Extending the principle of operation of hollow cathode microdischarges to a tube geometry has allowed the formation of stable, high-pressure plasma microjets in a variety of gases including Ar, He, and H2. Direct current discharges are ignited between stainless steel capillary tubes (d=178 mum) which are operated as the cathode and a metal grid or plate that serves as the anode. Argon plasma microjets can be sustained in ambient air with plasma voltages as low as 260 V for cathode-anode gaps of 0.5 mm. At larger operating voltage, this gap can be extended up to several millimeters. Using a heated molybdenum substrate as the anode, plasma microjets in CH4/H2 mixtures have been used to deposit diamond crystals and polycrystalline films. Micro-Raman spectroscopy of these films shows mainly sp3 carbon content with slight shifting of the diamond peak due to internal stresses. Optical emission spectroscopy of the discharges used in the diamond growth experiments confirms the presence of atomic hydrogen and CH radicals.

  18. Hollow Cathode With Multiple Radial Orifices

    Science.gov (United States)

    Brophy, John R.

    1992-01-01

    Improved hollow cathode serving as source of electrons has multiple radial orifices instead of single axial orifice. Distributes ion current more smoothly, over larger area. Prototype of high-current cathodes for ion engines in spacecraft. On Earth, cathodes used in large-diameter ion sources for industrial processing of materials. Radial orientation of orifices in new design causes current to be dispersed radially in vicinity of cathode. Advantageous where desireable to produce plasma more nearly uniform over wider region around cathode.

  19. Experimental measurements of the hollow cathode DC glow discharge parameters in Ar and He plasmas

    Science.gov (United States)

    Omrani, M.; Amrollahi, R.; Iraji, D.

    2016-12-01

    In this article, we focus on some of the fundamental parameters of SS316L hollow cathode glow discharge. Four SS316L samples are placed at different locations on the cathode surface and the current passed through them is measured in Ar and He glow discharge plasmas. The wall current densities of Ar and He are in the range of 8-25 µA cm-2 and 8-35 µA cm-2, respectively. Results also show that with decreasing working pressure, the ion flux and current density distribution on the wall surface becomes more uniform. The ion flux of the Ar and He is in the range of 1013 to 1014 ~\\text{ion} \\text{c}{{\\text{m}}-2} . Total energy losses of Ar and He are measured at the pressure range of 1.4-5.5  ×  10-2 torr and 3.2-7.1  ×  10-1, respectively. In both Ar and He, total energy losses decreased with increasing pressure. The secondary electron emission coefficients of Ar and He, which are evaluated for the hallow cathode configuration, are about 0.42 and 0.26, respectively, and are higher in comparison with the plate cathode configuration.

  20. Plasma Treatment of Polyethylene Powder Particles in Hollow Cathode Glow Discharge

    Science.gov (United States)

    Wolter, Matthias; Quitzau, Meike; Bornholdt, Sven; Kersten, Holger

    2008-09-01

    Polyethylen (PE) is widely used in the production of foils, insulators, packaging materials, plastic bottles etc. Untreated PE is hydrophobic due to its unpolar surface. Therefore, it is hard to print or glue PE and the surface has to be modified before converting. In the present experiments a hollow cathode glow discharge is used as plasma source which is mounted in a spiral conveyor in order to ensure a combines transport of PE powder particles. With this set-up a homogeneous surface treatment of the powder is possible while passing the glow discharge. The plasma treatment causes a remarkable enhancement of the hydrophilicity of the PE powder which can be verified by contact angle measurements and X-ray photoelectron spectroscopy.

  1. Surface Charging Controlling of the Chinese Space Station with Hollow Cathode Plasma Contactor

    Science.gov (United States)

    Jiang, Kai; Wang, Xianrong; Qin, Xiaogang; Yang, Shengsheng; Yang, Wei; Zhao, Chengxuan; Chen, Yifeng; Shi, Liang; Tang, Daotan; Xie, Kan

    2016-07-01

    A highly charged manned spacecraft threatens the life of an astronaut and extravehicular activity, which can be effectively reduced by controlling the spacecraft surface charging. In this article, the controlling of surface charging on Chinese Space Station (CSS) is investigated, and a method to reduce the negative potential to the CSS is the emission electron with a hollow cathode plasma contactor. The analysis is obtained that the high voltage (HV) solar array of the CSS collecting electron current can reach 4.5 A, which can be eliminated by emitting an adequate electron current on the CSS. The theoretical analysis and experimental results are addressed, when the minimum xenon flow rate of the hollow cathode is 4.0 sccm, the emission electron current can neutralize the collected electron current, which ensures that the potential of the CSS can be controlled in a range of less than 21 V, satisfied with safety voltage. The results can provide a significant reference value to define a flow rate to the potential controlling programme for CSS.

  2. Broadband microwave measurement of electron temperature of a large coaxial gridded hollow cathode helium plasma

    Science.gov (United States)

    Gao, Ruilin; Yuan, Chengxun; Jia, Jieshu; Zhou, Zhong-Xiang; Wang, Ying; Wang, Xiaoou; Li, Hui; Wu, Jian

    2016-10-01

    This paper reports a new kind of large coaxial gridded hollow cathode discharge at low pressure in a helium atmosphere. A method is presented to determine the electron temperature by measuring the broadband microwave properties; typically, the frequency band extends from 2 to 12 GHz. The method involves positioning the discharge device between the two antenna ports to measure the scattering parameter using a network analyzer. For a weak ionized plasma, this method is stable over the entire frequency range. A microwave signal loss of 0.27-37.83 dB was measured within the frequency range. Based on the measured attenuation of the microwaves, the electron temperature was estimated to range from 1.6-4.6 eV under different conditions, which showed good agreements with the results of Langmuir Probe measurements.

  3. Life Testing of the Hollow Cathode Plasma Contactor for the ProSEDS Mission

    Science.gov (United States)

    Vaughn, Jason A.; Schneider, Todd A.; Finckenor, Miria M.; Munafo, Paul M. (Technical Monitor)

    2001-01-01

    The Propulsive Small Expendable Deployer System (ProSEDS) mission is designed to provide an on-orbit demonstration of the electrodynamic propulsion capabilities of tethers in space. The ProSEDS experiment will be a secondary payload on a Delta 11 unmanned expendable booster. A 5-km conductive tether is attached to the Delta 11 second stage and collects current from the low Earth orbit (LEO) plasma. A hollow cathode plasma contactor emits the collected electrons from the Delta II, completing the electrical circuit with the ambient plasma. The current flowing through the tether generates thrust based on the Lorentz Force Law. The thrust will be generated opposite to the velocity vector, slowing down the spacecraft and causing it to de-orbit in approximately 14 days compared to the normal 6 months. A 10-km non-conductive tether is between the conductive tether and an endmass containing several scientific instruments. The ProSEDS mission lifetime was set at I day because most of the primary objectives can be met in that time. The extended ProSEDS mission will be for as many days as possible, until the Delta 11 second stage burns up or the tether is severed by a micrometeoroid or space debris particle. The Hollow Cathode Plasma Contactor (HCPC) unit has been designed for a 12-day mission. Because of the science requirements to measure the background ambient plasma, the HCPC must operate on a duty cycle. Later in the ProSEDS mission, the HCPC is operated in a manner to allow charging of the secondary battery. Due to the unusual operating requirements by the ProSEDS mission, a development unit of the HCPC was built for thorough testing. This developmental unit was tested for a simulated ProSEDS mission, with measurements of the ability to start and stop during the duty cycle. These tests also provided valuable data for the ProSEDS software requirements. Qualification tests of the HCPC flight hardware are also discussed.

  4. Low pressure arc discharges with hollow cathodes and their using in plasma generators and charged particle sources

    CERN Document Server

    Vintizenko, L G; Koval, N N; Tolkachev, V S; Lopatin, I V; Shchanin, P M

    2001-01-01

    Paper presents the results of investigation into arc discharges with a hollow cathode generating 10 sup 1 sup 0 -10 sup 1 sup 2 concentration gas-discharge plasma in essential (approx 1 m sup 3) volumes at low (10 sup - sup 2 -1 Pa) pressures and up to 200 A discharge currents. One studied design of discharge systems with heated and cold cathodes their peculiar features, presented the parameters of plasma generators and of charged particle sources based on arc discharges and discussed, as well, the problems of more rational application of those systems in the processes for surface modification of solids

  5. Tungsten and Barium Transport in the Internal Plasma of Hollow Cathodes

    Science.gov (United States)

    Polk, James E.; Mikellides, Ioannis G.; Katz, Ira; Capece, Angela M.

    2008-01-01

    The effect of tungsten erosion, transport and redeposition on the operation of dispenser hollow cathodes was investigated in detailed examinations of the discharge cathode inserts from an 8200 hour and a 30,352 hour ion engine wear test. Erosion and subsequent re-deposition of tungsten in the electron emission zone at the downstream end of the insert reduces the porosity of the tungsten matrix, preventing the flow of barium from the interior. This inhibits the interfacial reactions of the barium-calcium-aluminate impregnant with the tungsten in the pores. A numerical model of barium transport in the internal xenon discharge plasma shows that the barium required to reduce the work function in the emission zone can be supplied from upstream through the gas phase. Barium that flows out of the pores of the tungsten insert is rapidly ionized in the xenon discharge and pushedback to the emitter surface by the electric field and drag from the xenon ion flow. Thisbarium ion flux is sufficient to maintain a barium surface coverage at the downstream endgreater than 0.6, even if local barium production at that point is inhibited by tungsten deposits. The model also shows that the neutral barium pressure exceeds the equilibrium vapor pressure of the impregnant decomposition reaction over much of the insert length,so the reactions are suppressed. Only a small region upstream of the zone blocked by tungsten deposits is active and supplies the required barium. These results indicate that hollowcathode failure models based on barium depletion rates in vacuum dispenser cathodes are very conservative.

  6. Compact lanthanum hexaboride hollow cathode.

    Science.gov (United States)

    Goebel, Dan M; Watkins, Ronald M

    2010-08-01

    A compact lanthanum hexaboride hollow cathode has been developed for space applications where size and mass are important and research and industrial applications where access for implementation might be limited. The cathode design features a refractory metal cathode tube that is easily manufactured, mechanically captured orifice and end plates to eliminate expensive e-beam welding, graphite sleeves to provide a diffusion boundary to protect the LaB6 insert from chemical reactions with the refractory metal tube, and several heater designs to provide long life. The compact LaB(6) hollow cathode assembly including emitter, support tube, heater, and keeper electrode is less than 2 cm in diameter and has been fabricated in lengths of 6-15 cm for different applications. The cathode has been operated continuously at discharge currents of 5-60 A in xenon. Slightly larger diameter versions of this design have operated at up to 100 A of discharge current.

  7. A N2 Plasma Light Source Generated in Hollow Cathode Discharge and Its Application in Lithographic Plate Making

    Institute of Scientific and Technical Information of China (English)

    LI Chao-yang; CHEN Qiang; ZHANG Guang-qiu

    2007-01-01

    Computer to conventional plate (CTCP) technology is getting more and more attention in printing industries.In this paper we report a nitrogen plasma light source generated in hollow cathode discharge (HCD),which is used for pre-sensitivity (PS) plate exposure.The N2 molecule emits abundant spectrum ranging from 350 nm to 460 nm.With the voltage of 580 V,current of 1.8 A and pressure of 70 Pa in the discharge an optical power density of 0.46 mW/cm2 is obtained.The optical power density could be further increased with optimizing the lens system.The phototonus efficiency of this source is discussed in detail based upon the chemical principle and the FTIR analysis on the coating material.

  8. The effects of a realistic hollow cathode plasma contactor model on the simulation of bare electrodynamic tether systems

    Science.gov (United States)

    Blash, Derek M.

    The region known as Low-Earth Orbit (LEO) has become populated with artificial satellites and space debris since humanities initial venture into the region. This has turned LEO into a hazardous region. Since LEO is very valuable to many different countries, there has been a push to prevent further buildup and talk of even deorbiting spent satellites and debris already in LEO. One of the more attractive concepts available for deorbiting debris and spent satellites is a Bare Electrodynamic Tether (BET). A BET is a propellantless propulsion technique in which two objects are joined together by a thin conducting material. When these tethered objects are placed in LEO, the tether sweeps across the magnetic field lines of the Earth and induces an electromotive force (emf) along the tether. Current from the space plasma is collected on the bare tether under the action of the induced emf, and this current interacts with the Earth's magnetic field to create a drag force that can be used to deorbit spent satellites and space debris. A Plasma Contactor (PC) is used to close the electrical circuit between the BET and the ionospheric plasma. The PC requires a voltage and, depending on the device, a gas flow to emit electrons through a plasma bridge to the ionospheric plasma. The PC also can require a plasma discharge electrode and a heater to condition the PC for operation. These parameters as well as the PC performance are required to build an accurate simulation of a PC and, therefore, a BET deorbiting system. This thesis focuses on the development, validation, and implementation of a simulation tool to model the effects of a realistic hollow cathode PC system model on a BET deorbit system.

  9. A comparison between micro hollow cathode discharges and atmospheric pressure plasma jets in Ar/O2 gas mixtures

    Science.gov (United States)

    Lazzaroni, C.; Chabert, P.

    2016-12-01

    Using global models, micro hollow cathode discharges (MHCDs) are compared to radiofrequency atmospheric pressure plasma jets (APPJs) in terms of reactive oxygen species (ROS) production. Ar/O2 gas mixtures are investigated, typically with a small percentage of oxygen in argon. The same chemical reaction set, involving 17 species and 128 chemical reactions in the gas phase, is used for both devices, operated in the typical geometries previously published; the APPJ is driven by a radiofrequency voltage across a 1 mm gap, at atmospheric pressure, while the MHCD is driven by a DC voltage source, at 100 Torr and in a 400 μm hole. The MHCD may be operated either in the self-pulsing or in the normal (stationary) regime, depending on the driving voltage. The comparison shows that in both regimes, the MHCD produces larger amounts of \\text{O}2\\ast , while the APPJ produces predominantly reactive oxygen ground state species, \\text{O} and {{\\text{O}}3} . These large differences in ROS composition are mostly due to the higher plasma density produced in the MHCD. The difference in operating pressure is a second order effect.

  10. Modelling of local ion nitriding in a glow discharge with hollow cathode

    Science.gov (United States)

    Budilov, V.; Ramazanov, K.; Khusainov, Yu

    2017-05-01

    The paper presents the results of computer calculations of glow discharge plasma parameters in a hollow cathode zone and modeling of thermal and diffusion processes at local ion nitriding with a hollow cathode. The proposed model of a glow discharge with a hollow cathode with sufficient accuracy allowed to describe the distribution of plasma parameters in a cathode void. Values of plasma parameters in a cathode void formed by a mesh screen and cathode surface were obtained via the probe method. It was found that the use of hollow cathode effect allows to increase the concentration of ions near the treated surface by 1.5 times. The suggested computer model allows to predict the distribution of the temperature field and depth of a diffusion layer at local ion nitriding with a hollow cathode for various configurations and sizes.

  11. Barium depletion in hollow cathode emitters

    Energy Technology Data Exchange (ETDEWEB)

    Polk, James E., E-mail: james.e.polk@jpl.nasa.gov; Mikellides, Ioannis G.; Katz, Ira [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91109 (United States); Capece, Angela M. [Graduate Aerospace Laboratories, California Institute of Technology, Pasadena, California 91125 (United States)

    2016-01-14

    Dispenser hollow cathodes rely on a consumable supply of Ba released by BaO-CaO-Al{sub 2}O{sub 3} source material in the pores of a tungsten matrix to maintain a low work function surface. The examination of cathode emitters from long duration tests shows deposits of tungsten at the downstream end that appear to block the flow of Ba from the interior. In addition, a numerical model of Ba transport in the cathode plasma indicates that the Ba partial pressure in the insert may exceed the equilibrium vapor pressure of the dominant Ba-producing reaction, and it was postulated previously that this would suppress Ba loss in the upstream part of the emitter. New measurements of the Ba depletion depth from a cathode insert operated for 8200 h reveal that Ba loss is confined to a narrow region near the downstream end, confirming this hypothesis. The Ba transport model was modified to predict the depletion depth with time. A comparison of the calculated and measured depletion depths gives excellent qualitative agreement, and quantitative agreement was obtained assuming an insert temperature 70 °C lower than measured beginning-of-life values.

  12. Compact Rare Earth Emitter Hollow Cathode

    Science.gov (United States)

    Watkins, Ronald; Goebel, Dan; Hofer, Richard

    2010-01-01

    A compact, high-current, hollow cathode utilizing a lanthanum hexaboride (LaB6) thermionic electron emitter has been developed for use with high-power Hall thrusters and ion thrusters. LaB6 cathodes are being investigated due to their long life, high current capabilities, and less stringent xenon purity and handling requirements compared to conventional barium oxide (BaO) dispenser cathodes. The new cathode features a much smaller diameter than previously developed versions that permit it to be mounted on axis of a Hall thruster ( internally mounted ), as opposed to the conventional side-mount position external to the outer magnetic circuit ("externally mounted"). The cathode has also been reconfigured to be capable of surviving vibrational loads during launch and is designed to solve the significant heater and materials compatibility problems associated with the use of this emitter material. This has been accomplished in a compact design with the capability of high-emission current (10 to 60 A). The compact, high-current design has a keeper diameter that allows the cathode to be mounted on the centerline of a 6- kW Hall thruster, inside the iron core of the inner electromagnetic coil. Although designed for electric propulsion thrusters in spacecraft station- keeping, orbit transfer, and interplanetary applications, the LaB6 cathodes are applicable to the plasma processing industry in applications such as optical coatings and semiconductor processing where reactive gases are used. Where current electrical propulsion thrusters with BaO emitters have limited life and need extremely clean propellant feed systems at a significant cost, these LaB6 cathodes can run on the crudest-grade xenon propellant available without impact. Moreover, in a laboratory environment, LaB6 cathodes reduce testing costs because they do not require extended conditioning periods under hard vacuum. Alternative rare earth emitters, such as cerium hexaboride (CeB6) can be used in this

  13. Generation of uniform low-temperature plasma in a pulsed non-self-sustained glow discharge with a large-area hollow cathode

    Science.gov (United States)

    Akhmadeev, Yu. H.; Denisov, V. V.; Koval, N. N.; Kovalsky, S. S.; Lopatin, I. V.; Schanin, P. M.; Yakovlev, V. V.

    2017-01-01

    Generation of plasma in a pulsed non-self-sustained glow discharge with a hollow cathode with an area of ≥2 m2 at gas pressures of 0.4-1 Pa was studied experimentally. At an auxiliary arc-discharge current of 100 A and a main discharge voltage of 240 V, a pulse-periodic glow discharge with a current amplitude of 370 A, pulse duration of 340 μs, and repetition rate of 1 kHz was obtained. The possibility of creating a uniform gas-discharge plasma with a density of up to 1012 cm-3 and an electron temperature of 1 eV in a volume of >0.2 m3 was demonstrated. Such plasma can be efficiently used to treat material surfaces and generate pulsed ion beams with a current density of up to 15 mA/cm2.

  14. Cesiated hollow cathodes in the multicusp ion source

    Science.gov (United States)

    Belchenko, Yu. I.; Oka, Y.; Hamabe, M.; Kaneko, O.; Krivenko, A.; Takeiri, Y.; Tsumori, K.; Osakabe, M.; Ikeda, K.; Asano, E.; Kawamoto, T.

    2002-02-01

    A cesiated hydrogen hollow cathode (CHC) was tested for plasma injection in the multicusp negative ion source (MS). The CHC arc with hydrogen feed and cesium seeding through the CHC volume was explored. One cathode unit (40 mm length, 19 mm in diameter, emission opening area 1-3 mm2) with no special cooling provided the MS discharge operation with direct current up to 30 A, and up to 60 A in the long-pulse mode. High efficiency of negative ion production in the MS discharge, driven by a CHC plasma injection was recorded.

  15. Substrate temperature influence on the properties of GaN thin films grown by hollow-cathode plasma-assisted atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Alevli, Mustafa, E-mail: mustafaalevli@marmara.edu.tr; Gungor, Neşe [Department of Physics, Faculty of Arts and Sciences, Marmara University, Goztepe, 34722 Istanbul (Turkey); Haider, Ali; Kizir, Seda; Leghari, Shahid A.; Biyikli, Necmi, E-mail: biyikli@unam.bilkent.edu.tr [Institute of Materials Science and Nanotechnology, Bilkent University, Bilkent, 06800 Ankara, Turkey and National Nanotechnology Research Center (UNAM), Bilkent University, Bilkent, 06800 Ankara (Turkey)

    2016-01-15

    Gallium nitride films were grown by hollow cathode plasma-assisted atomic layer deposition using triethylgallium and N{sub 2}/H{sub 2} plasma. An optimized recipe for GaN film was developed, and the effect of substrate temperature was studied in both self-limiting growth window and thermal decomposition-limited growth region. With increased substrate temperature, film crystallinity improved, and the optical band edge decreased from 3.60 to 3.52 eV. The refractive index and reflectivity in Reststrahlen band increased with the substrate temperature. Compressive strain is observed for both samples, and the surface roughness is observed to increase with the substrate temperature. Despite these temperature dependent material properties, the chemical composition, E{sub 1}(TO), phonon position, and crystalline phases present in the GaN film were relatively independent from growth temperature.

  16. Study of the Discharge Mode in Micro-Hollow Cathode

    Institute of Scientific and Technical Information of China (English)

    HE Feng; HE Shoujie; ZHAO Xiaofei; GUO Bingang; OUYANG Jiting

    2012-01-01

    In this study, micro-hollow cathode discharge (MHCD) is investigated by a fluid model with drift-diffusion approximation. The MHC device is a cathode/dielectric/anode sandwich structure with one hole of a diameter D=200 um. The gas is a Ne/Xe mixture at a pressure p=50-500 Torr. The evolutions of the discharge show that there are two different discharge modes. At larger pD the discharge plasma and high density excited species expand along the cathode surface and, a ringed discharge mode is formed. At smaller pD, the discharge plasma and the excited species expand along the axis of the cathode aperture to form a columnar discharge.

  17. The Hollow Cathode Phase of Pseudospark Operation

    Science.gov (United States)

    1993-06-01

    THE HOLLOW CATHODE PHASE OF PSEUDOSPARK OPERATION L. Pitchford and J. P. Boeuf University Paul Sabatier, France V. Puech University De Paris-Sud...ORGANIZATION NAME(S) AND ADDRESS(ES) University Paul Sabatier, France 8. PERFORMING ORGANIZATION REPORT NUMBER 9. SPONSORING/MONITORING AGENCY NAME...Appl. Phys. 53, 1699 (1988). [9] A. Anders, S. Anders, and M. Gundersen, submitted to Phys. Rev. Lett. [10] J. P. Boeuf and L. Pitchford , IEEE

  18. Hollow cathode modeling: II. Physical analysis and parametric study

    Science.gov (United States)

    Sary, Gaétan; Garrigues, Laurent; Boeuf, Jean-Pierre

    2017-05-01

    A numerical emissive hollow cathode model which couples plasma and thermal aspects of the NASA NSTAR cathode has been presented in a companion paper and simulation results obtained using the plasma model were compared to experimental data. We now compare simulation results with measurements using the full coupled model. Inside the cathode, the simulated plasma density profile agrees with the experimental data up to the ±50% experimental uncertainty while the simulated emitter temperature differs from measurements by at most 5 K. We then proceed to an analysis of the cathode discharge both inside the cathode where electron emission is dominant and outside in the near plume where electron transport instabilities are important. As observed previously in the literature, the total emitted electron current is much larger (34 {{A}}) than the set discharge current collected at the anode (13 {{A}}) while ionization plays a negligible role. Extracted electrons are emitted from a region much shorter than the full emitter (0.9 {{cm}} versus 2.5 {{cm}}). The influence of an applied axial magnetic field in the plume is also assessed and we observe that it leads to a 10-fold increase of the plasma density 1 cm downstream of the orifice entrance while the simulated discharge potential at the anode is increased from 10 {{V}} up to 35.5 {{V}}. Lastly, we perform a parametric study on both the operating point (discharge current, mass flow rate) and design (inner radius) of the cathode. The simulated useful operating envelope is shown to be limited at low discharge current mostly because of the probable ion sputtering of the emitter and at high discharge current because of emitter evaporation, plasma oscillations and sputtering of the keeper electrode. The behavior of the cathode is also analyzed w.r.t. its internal radius and simulation results show that the useful emitter length scales linearly with the cathode radius.

  19. Modeling High Pressure Micro Hollow Cathode Discharges

    Science.gov (United States)

    2007-11-02

    cathode discharge excimer lamps , Phys. Plasmas 7, 286 (2000). [3] RH Stark and KH Schoenbach, Direct high pressure glow discharges, J. Appl. Phys...temperature profiles in argon glow discharges, J. Appl. Phys. 88, 2234 (2000) [8] M. Moselhy, W. Shi, R. Stark, A flat glow discharge excimer radiation...MHCD acts as a plasma cathode for a third electrode (anode). Some experimental results in this geometry are available for argon and for air from the

  20. High-pressure hollow cathode discharges

    Science.gov (United States)

    Schoenbach, Karl H.; El-Habachi, Ahmed; Shi, Wenhui; Ciocca, Marco

    1997-11-01

    Reducing the diameter of the cathode hole in a plane anode - hollow cathode geometry to 0963-0252/6/4/003/img1m has allowed us to generate direct current discharges in argon at atmospheric pressure. Up to pressure times cathode hole diameter (pD) values of approximately 5 Torr cm, and at sub-mA currents, glow discharges (predischarges) are observed with a shape which is determined by the vacuum electric field. In the same pD range, but at higher currents of up to approximately 4 mA, the discharges are of the hollow cathode discharge type. At pD values exceeding 5 Torr cm the predischarges turn into surface discharges along the mica spacer between the electrodes. At currents > 4 mA filamentary, pulsed discharges are observed. Qualitative information on the electron energy distribution in the microdischarges has been obtained by studying the VUV emission from ionized argon atoms and the argon excimer radiation at 130 nm. The results of the spectral measurements indicate the presence of a relatively large concentration of electrons with energies > 15 eV over the entire pressure range. The fact that the current - voltage characteristic of the microdischarges has a positive slope over much of the current range where excimer radiation is emitted indicates the possibility of forming arrays of these discharges and using them in flat panel excimer lamps.

  1. Improved Rare-Earth Emitter Hollow Cathode

    Science.gov (United States)

    Goebel, Dan M.

    2011-01-01

    An improvement has been made to the design of the hollow cathode geometry that was created for the rare-earth electron emitter described in Compact Rare Earth Emitter Hollow Cathode (NPO-44923), NASA Tech Briefs, Vol. 34, No. 3 (March 2010), p. 52. The original interior assembly was made entirely of graphite in order to be compatible with the LaB6 material, which cannot be touched by metals during operation due to boron diffusion causing embrittlement issues in high-temperature refractory materials. Also, the graphite tube was difficult to machine and was subject to vibration-induced fracturing. This innovation replaces the graphite tube with one made out of refractory metal that is relatively easy to manufacture. The cathode support tube is made of molybdenum or molybdenum-rhenium. This material is easily gun-bored to near the tolerances required, and finish machined with steps at each end that capture the orifice plate and the mounting flange. This provides the manufacturability and robustness needed for flight applications, and eliminates the need for expensive e-beam welding used in prior cathodes. The LaB6 insert is protected from direct contact with the refractory metal tube by thin, graphite sleeves in a cup-arrangement around the ends of the insert. The sleeves, insert, and orifice plate are held in place by a ceramic spacer and tungsten spring inserted inside the tube. To heat the cathode, an insulating tube is slipped around the refractory metal hollow tube, which can be made of high-temperature materials like boron nitride or aluminum nitride. A screw-shaped slot, or series of slots, is machined in the outside of the ceramic tube to constrain a refractory metal wire wound inside the slot that is used as the heater. The screw slot can hold a single heater wire that is then connected to the front of the cathode tube by tack-welding to complete the electrical circuit, or it can be a double slot that takes a bifilar wound heater with both leads coming out

  2. Compact High Current Rare-Earth Emitter Hollow Cathode for Hall Effect Thrusters

    Science.gov (United States)

    Hofer, Richard R. (Inventor); Goebel, Dan M. (Inventor); Watkins, Ronnie M. (Inventor)

    2012-01-01

    An apparatus and method for achieving an efficient central cathode in a Hall effect thruster is disclosed. A hollow insert disposed inside the end of a hollow conductive cathode comprises a rare-earth element and energized to emit electrons from an inner surface. The cathode employs an end opening having an area at least as large as the internal cross sectional area of the rare earth insert to enhance throughput from the cathode end. In addition, the cathode employs a high aspect ratio geometry based on the cathode length to width which mitigates heat transfer from the end. A gas flow through the cathode and insert may be impinged by the emitted electrons to yield a plasma. One or more optional auxiliary gas feeds may also be employed between the cathode and keeper wall and external to the keeper near the outlet.

  3. Electrical conduction and dielectric relaxation properties of AlN thin films grown by hollow-cathode plasma-assisted atomic layer deposition

    Science.gov (United States)

    Altuntas, Halit; Bayrak, Turkan; Kizir, Seda; Haider, Ali; Biyikli, Necmi

    2016-07-01

    In this study, aluminum nitride (AlN) thin films were deposited at 200 °C, on p-type silicon substrates utilizing a capacitively coupled hollow-cathode plasma source integrated atomic layer deposition (ALD) reactor. The structural properties of AlN were characterized by grazing incidence x-ray diffraction, by which we confirmed the hexagonal wurtzite single-phase crystalline structure. The films exhibited an optical band edge around ˜5.7 eV. The refractive index and extinction coefficient of the AlN films were measured via a spectroscopic ellipsometer. In addition, to investigate the electrical conduction mechanisms and dielectric properties, Al/AlN/p-Si metal-insulator-semiconductor capacitor structures were fabricated, and current density-voltage and frequency dependent (7 kHz-5 MHz) dielectric constant measurements (within the strong accumulation region) were performed. A peak of dielectric loss was observed at a frequency of 3 MHz and the Cole-Davidson empirical formula was used to determine the relaxation time. It was concluded that the native point defects such as nitrogen vacancies and DX centers formed with the involvement of Si atoms into the AlN layers might have influenced the electrical conduction and dielectric relaxation properties of the plasma-assisted ALD grown AlN films.

  4. [High current microsecond pulsed hollow cathode lamp excited ionic fluorescence spectrometry of alkaline earth elements in inductively coupled plasma with a Fassel-torch].

    Science.gov (United States)

    Zhang, Shao-Yu; Gong, Zhen-Bin; Huang, Ben-Li

    2006-02-01

    High current microsecond pulsed hollow cathode lamp (HCMP-HCL) excited ionic fluorescence spectrometry (IFS) of alkaline earth elements in inductively coupled plasma (ICP) with a Fassel-torch has been investigated. In wide condition ranges only IFS was observed, whilst atomic fluorescence spectrometry (AFS) was not detectable. More intense ionic fluorescence signal was observed at lower observation heights and at lower incident RF powers. Without introduction of any reduction organic gases into the ICP, the limit of detection (LOD, 3sigma) of Ba was improved by 50-fold over that of a conventional pulsed (CP) HCL with the Baird sleeve-extended torch. For Ca and Sr, the LODs by HCMP-HCL-ICP-IFS and CP-HCL-ICP-AFS show no significant difference. Relative standard deviations were 0.6%-1.4% (0.1-0.2 microg x mL(-1), n = 10) for 5 ionic fluorescence lines. Preliminary studies showed that the intensity of ionic fluorescence could be depressed in the presence of K, Al and P.

  5. Experimental investigation of a capacitive blind hollow cathode discharge with central gas injection

    Science.gov (United States)

    Hoffmann, D.; Müller, M.; Petkow, D.; Herdrich, G.; Lein, S.

    2014-12-01

    The operating parameters and resulting plasma properties of a blind hollow cathode (BHC) discharge have been investigated. The hollow cathode was driven capacitively with a pulsed dc signal of 200 kHz in a power range between 50 and 100 W at an ambient pressure of about 10 Pa. The working gas was argon, which was introduced with a ceramic capillary at different positions of the longitudinal axis of the hollow cathode with flow rates of between 30 and 1000 sccm. The current-voltage characteristics were recorded. The pressure at the end of the BHC was measured with a miniaturized pressure transducer with varying volumetric flow rate and axial position of the capillary in the hollow cathode. To characterize the ignition behaviour of the system, the measured breakdown voltages were compared with phenomenological Paschen curves calculated from the pressure data. Optical emission spectroscopy was used to examine the origins of the light emission, comparing the glow mode and hollow cathode mode in particular. A high-speed camera recorded some plasma processes. A mounting with an indium tin oxide coated glass was used to observe the inner volume of the BHC along the longitudinal axis, while the plasma was operated with different parameters. The optical observations revealed an inhomogeneous plasma condition along the axis.

  6. Development of plasma cathode electron guns

    Science.gov (United States)

    Oks, Efim M.; Schanin, Peter M.

    1999-05-01

    The status of experimental research and ongoing development of plasma cathode electron guns in recent years is reviewed, including some novel upgrades and applications to various technological fields. The attractiveness of this kind of e-gun is due to its capability of creating high current, broad or focused beams, both in pulsed and steady-state modes of operation. An important characteristic of the plasma cathode electron gun is the absence of a thermionic cathode, a feature which leads to long lifetime and reliable operation even in the presence of aggressive background gas media and at fore-vacuum gas pressure ranges such as achieved by mechanical pumps. Depending on the required beam parameters, different kinds of plasma discharge systems can be used in plasma cathode electron guns, such as vacuum arcs, constricted gaseous arcs, hollow cathode glows, and two kinds of discharges in crossed E×B fields: Penning and magnetron. At the present time, plasma cathode electron guns provide beams with transverse dimension from fractional millimeter up to about one meter, beam current from microamperes to kiloamperes, beam current density up to about 100 A/cm2, pulse duration from nanoseconds to dc, and electron energy from several keV to hundreds of keV. Applications include electron beam melting and welding, surface treatment, plasma chemistry, radiation technologies, laser pumping, microwave generation, and more.

  7. Transition characteristics from radio-frequency discharge to arc in hollow cathode configuration

    Institute of Scientific and Technical Information of China (English)

    许建平; 巩春志; 吴明忠; 田修波

    2014-01-01

    The technique ofglow discharges in radio frequency configuration was applied to ignite hollow cathode vacuum arc discharge.The effect of discharge parameters on the building up of hollow cathode arc discharge was investigated.The emission spectrum during the vacuum arc ignition process was measured to disclose the discharge dynamics.There exists a threshold radio frequency power (300 W),beyond which hollow cathode is in γmode discharge status while radio frequency discharge changes into the arc discharge.With the increase of the radio frequency power,the plasma temperature and electronic density increase,and the discharge mode transits more rapidly.The ignition time ofhollow cathode vacuum arc discharge is less than 4 s with a radio frequency power of700 W.

  8. Miniaturized cathodic arc plasma source

    Science.gov (United States)

    Anders, Andre; MacGill, Robert A.

    2003-04-15

    A cathodic arc plasma source has an anode formed of a plurality of spaced baffles which extend beyond the active cathode surface of the cathode. With the open baffle structure of the anode, most macroparticles pass through the gaps between the baffles and reflect off the baffles out of the plasma stream that enters a filter. Thus the anode not only has an electrical function but serves as a prefilter. The cathode has a small diameter, e.g. a rod of about 1/4 inch (6.25 mm) diameter. Thus the plasma source output is well localized, even with cathode spot movement which is limited in area, so that it effectively couples into a miniaturized filter. With a small area cathode, the material eroded from the cathode needs to be replaced to maintain plasma production. Therefore, the source includes a cathode advancement or feed mechanism coupled to cathode rod. The cathode also requires a cooling mechanism. The movable cathode rod is housed in a cooled metal shield or tube which serves as both a current conductor, thus reducing ohmic heat produced in the cathode, and as the heat sink for heat generated at or near the cathode. Cooling of the cathode housing tube is done by contact with coolant at a place remote from the active cathode surface. The source is operated in pulsed mode at relatively high currents, about 1 kA. The high arc current can also be used to operate the magnetic filter. A cathodic arc plasma deposition system using this source can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

  9. Comparison of trimethylgallium and triethylgallium as “Ga” source materials for the growth of ultrathin GaN films on Si (100) substrates via hollow-cathode plasma-assisted atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Alevli, Mustafa, E-mail: mustafaalevli@marmara.edu.tr [Department of Physics, Marmara University, Göztepe Kadıköy, 34722 İstanbul (Turkey); Haider, Ali; Kizir, Seda; Leghari, Shahid A.; Biyikli, Necmi, E-mail: biyikli@unam.bilkent.edu.tr [Institute of Materials Science and Nanotechnology, Bilkent University, Bilkent, 06800 Ankara, Turkey and National Nanotechnology Research Center (UNAM), Bilkent University, Bilkent, 06800 Ankara (Turkey)

    2016-01-15

    GaN films grown by hollow cathode plasma-assisted atomic layer deposition using trimethylgallium (TMG) and triethylgallium (TEG) as gallium precursors are compared. Optimized and saturated TMG/TEG pulse widths were used in order to study the effect of group-III precursors. The films were characterized by grazing incidence x-ray diffraction, atomic force microscopy, x-ray photoelectron spectroscopy, and spectroscopic ellipsometry. Refractive index follows the same trend of crystalline quality, mean grain, and crystallite sizes. GaN layers grown using TMG precursor exhibited improved structural and optical properties when compared to GaN films grown with TEG precursor.

  10. Influence of the floating potential on micro-hollow cathode operation

    Energy Technology Data Exchange (ETDEWEB)

    Levko, D. [Department of Aerospace Engineering and Engineering Mechanics, The University of Texas at Austin, Austin, Texas 78712 (United States); Bliokh, Y. P.; Krasik, Ya. E. [Department of Physics, Technion, 32000 Haifa (Israel)

    2015-06-15

    The influence of a keeper electrode with a floating potential on the operation of a micro-hollow cathode is studied using the two-dimensional particle-in-cell Monte Carlo collisions model. The floating potential is determined self-consistently, taking into account the electron and ion charges collected by the keeper and the potential induced by the plasma non-compensated space charge. It is shown that the parameters of the micro-hollow cathode operation vary significantly, according to whether the keeper potential is floating or has a specified constant value.

  11. Effect of the Hollow Cathode Heat Power on the Performance of an Hall-Effect Thruster

    Institute of Scientific and Technical Information of China (English)

    NING Zhongxi; YU Daren; LI Hong; YAN Guojun

    2009-01-01

    Effect of the hollow cathode heat power on the performance of a Hall-effect thruster is investigated. The variations in the Hall-effect thruster's performance (thrust, specific impulse and anode efficiency) with the hollow cathode heat power was obtained from the analysis of the experimental data. Through an analysis on the coupling relationship between the electrons emitted from the hollow cathode and the environmental plasma, it was found that the heat power would affect the electron emission of the emitter and the space potential of the coupling zone, which would lead to a change in the effective discharge voltage. The experimental data agree well with the results of calculation which can be used to explain the experimental phenomena.

  12. Research of Hollow Cathode Remote Plasma Polymerization on Surface of Secondary Battery Separator%电池隔膜表面空心阴极等离子体接枝聚合研究

    Institute of Scientific and Technical Information of China (English)

    温贻芳; 陈新; 芮延年; 王红卫

    2012-01-01

    The surface of non-woven polypropylene secondary battery separator was modified by hollow cathode remote plasma polymerizatioa The polymerization mechanism was analyzed, and the effects of working parameters (such as discharge power, working gas flow rate, sample position etc. ) on the polymerization rate were studied systematically. The IR and SEM were used to analyze the chemical composition and the surface morphology. The results show that the hydrophilic group was imported on the surface of polypropylene after hollow cathode remote plasma modification, so that the wettability of the non-woven polypropylene secondary battery separator was greatly improved.%应用自制的空心阴极等离子体装置,引发丙烯酸在丙纶表面的接枝聚合,研究了等离子体接枝聚合作用机理,分析了等离子体接枝聚合各参数(放电功率、气体流量、丙烯酸蒸气流量、样品位置等)对聚合速率的影响.通过红外光谱、扫描电镜等对丙纶接枝聚合膜表面的化学组成和形态结构等进行了表征分析,证明了亲水基团的引入,改善了丙纶隔膜的亲水性能.

  13. Low-current hollow-cathode discharge in a trigger unit of a cold cathode thyratron

    OpenAIRE

    Landl, N. V.; Korolev, Yuriy Dmitrievich; Frants, O. B.; Geyman, V. G.; Bolotov, A. V.

    2015-01-01

    The paper deals with the investigations of the effect of cathode emissivity on the regimes of low-current hollow-cathode glow discharge. It is shown that an increase in the emissivity due to the so-called high-emissivity tablet allows the essential decrease in the discharge initiation voltage and the discharge burning voltage. The model of current sustaining for the hollow-cathode discharge, which takes into account the external emission current has been developed. On basis of the model, the ...

  14. Low-current hollow-cathode discharge in a trigger unit of a cold cathode thyratron

    Science.gov (United States)

    Landl, N. V.; Korolev, Y. D.; Frants, O. B.; Geyman, V. G.; Bolotov, A. V.

    2015-11-01

    The paper deals with the investigations of the effect of cathode emissivity on the regimes of low-current hollow-cathode glow discharge. It is shown that an increase in the emissivity due to the so-called high-emissivity tablet allows the essential decrease in the discharge initiation voltage and the discharge burning voltage. The model of current sustaining for the hollow-cathode discharge, which takes into account the external emission current has been developed. On basis of the model, the current-voltage characteristics of the discharge have been interpreted.

  15. Optical characteristics of nanocrystalline Al{sub x}Ga{sub 1−x}N thin films deposited by hollow cathode plasma-assisted atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Goldenberg, Eda, E-mail: goldenberg@unam.bilkent.edu.tr [UNAM – National Nanotechnology Research Center, Bilkent University, Ankara 06800 (Turkey); Ozgit-Akgun, Cagla; Biyikli, Necmi [Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey); Kemal Okyay, Ali [Department of Electrical and Electronics Engineering, Bilkent University, Ankara 06800 (Turkey)

    2014-05-15

    Gallium nitride (GaN), aluminum nitride (AlN), and Al{sub x}Ga{sub 1−x}N films have been deposited by hollow cathode plasma-assisted atomic layer deposition at 200 °C on c-plane sapphire and Si substrates. The dependence of film structure, absorption edge, and refractive index on postdeposition annealing were examined by x-ray diffraction, spectrophotometry, and spectroscopic ellipsometry measurements, respectively. Well-adhered, uniform, and polycrystalline wurtzite (hexagonal) GaN, AlN, and Al{sub x}Ga{sub 1−x}N films were prepared at low deposition temperature. As revealed by the x-ray diffraction analyses, crystallite sizes of the films were between 11.7 and 25.2 nm. The crystallite size of as-deposited GaN film increased from 11.7 to 12.1 and 14.4 nm when the annealing duration increased from 30 min to 2 h (800 °C). For all films, the average optical transmission was ∼85% in the visible (VIS) and near infrared spectrum. The refractive indices of AlN and Al{sub x}Ga{sub 1−x}N were lower compared to GaN thin films. The refractive index of as-deposited films decreased from 2.33 to 2.02 (λ = 550 nm) with the increased Al content x (0 ≤ x ≤ 1), while the extinction coefficients (k) were approximately zero in the VIS spectrum (>400 nm). Postdeposition annealing at 900 °C for 2 h considerably lowered the refractive index value of GaN films (2.33–1.92), indicating a significant phase change. The optical bandgap of as-deposited GaN film was found to be 3.95 eV, and it decreased to 3.90 eV for films annealed at 800 °C for 30 min and 2 h. On the other hand, this value increased to 4.1 eV for GaN films annealed at 900 °C for 2 h. This might be caused by Ga{sub 2}O{sub 3} formation and following phase change. The optical bandgap value of as-deposited Al{sub x}Ga{sub 1−x}N films decreased from 5.75 to 5.25 eV when the x values decreased from 1 to 0.68. Furthermore, postdeposition annealing did not

  16. Development and Testing of High Current Hollow Cathodes for High Power Hall Thrusters

    Science.gov (United States)

    Kamhawi, Hani; Van Noord, Jonathan

    2012-01-01

    NASA's Office of the Chief Technologist In-Space Propulsion project is sponsoring the testing and development of high power Hall thrusters for implementation in NASA missions. As part of the project, NASA Glenn Research Center is developing and testing new high current hollow cathode assemblies that can meet and exceed the required discharge current and life-time requirements of high power Hall thrusters. This paper presents test results of three high current hollow cathode configurations. Test results indicated that two novel emitter configurations were able to attain lower peak emitter temperatures compared to state-of-the-art emitter configurations. One hollow cathode configuration attained a cathode orifice plate tip temperature of 1132 degC at a discharge current of 100 A. More specifically, test and analysis results indicated that a novel emitter configuration had minimal temperature gradient along its length. Future work will include cathode wear tests, and internal emitter temperature and plasma properties measurements along with detailed physics based modeling.

  17. Design of triode extraction system for a dual hollow cathode ion source

    Institute of Scientific and Technical Information of China (English)

    WANG Jing-Hui; ZHU Kun; ZHAO Wei-Jiang; LIU Ke-Xin

    2011-01-01

    A triode extraction system is designed for a dual hollow cathode ion source being developed at the Institute of Heavy Ion Physics,Peking University.Basic parameters of the plasma are selected after examining the operation principle of the ion source,then the triode extraction system is designed and optimized by using software PBGUNS (for Particle Beam GUN Simulations).The physical design of the system is given in this paper.

  18. Ion Nitriding of Titanium Alloys with a Hollow Cathode Effect Application

    Directory of Open Access Journals (Sweden)

    V.V. Budilov

    2015-09-01

    Full Text Available The method of ion nitriding the titanium VT6 alloy in glow discharge with the hollow cathode effect (HCE was investigated. Probe measurements of glow discharge plasma under HCE conditions and without it were performed; ion densities near the cathode surface were measured. The effect of HCE on microstructure, microhardness and wear resistance of VT6 alloy was determined. The technology of ion nitriding titanium alloys, based on phase modification of the surface layer in glow discharge with HCE, was developed.

  19. High Pressure Micro-Slot Hollow Cathode Discharge

    Institute of Scientific and Technical Information of China (English)

    Wang Xinbing; Zhou Lina; Yao Xilin

    2005-01-01

    A direct current glow discharge source structure operating at high pressure based on the micro-slot hollow cathode is presented in this article. A 100 μm width slot cathode was fabricated of copper, and a stable DC glow discharge with an area of 0.5 mm2 was produced in noble gases (He, Ne) and air over a wide pressure range (kPa ~ 10 kPa). The current-voltage characteristics and the near UV radiation emission of the discharge were studied.

  20. Design and Manufacturing Processes of Long-Life Hollow Cathode Assemblies

    Science.gov (United States)

    Patterson, Michael J. (Inventor); Verhey, Timothy R. (Inventor); Soulas, George C. (Inventor)

    2002-01-01

    The design and manufacturing processes for Hollow Cathode Assemblies (HCA's) that operate over a broad range of emission currents up to 30 Amperes, at low potentials, with lifetimes in excess of 17,500 hours. The processes include contamination control procedures which cover hollow cathode component cleaning procedures, gas feed system designs and specifications, and hollow cathode activation and operating procedures to thereby produce cathode assemblies that have demonstrated stable and repeatable operating conditions, for both the discharge current and voltage. The HCA of this invention provides lifetimes of greater than 10,000 hours, and expected lifetimes of greater than 17,500 hours, whereas the present state-of-the-art is less than 500 hours at emission currents in excess of 1 Ampere. Stable operation is provided over a large range of operating emission currents, up to a 6:1 ratio, and this HCA can emit electron currents of up to 30 Amperes in magnitude to an external anode that simulates the current drawn to a space plasma at voltages of less than 20 Volts.

  1. Measurement of electric fields in a helium micro-hollow cathode discharge by forbidden transitions

    Science.gov (United States)

    Namba, Shinichi; Maki, Daisuke; Takiyama, Ken

    2013-09-01

    Micro-hollow cathode discharges operated at high pressure has been attracting a great deal of interest for various application, such as, excimer light sources, medical/biological fields and microchemical reactor. In the plasmas, the electric (E) field in the sheath region plays an important role to generate and sustain the plasmas. In order to determine the E field in the He microplasma, the emissions of allowed (He I 2P-4D: 492.19 nm) and forbidden (2P-4F: 492.06 nm) lines were observed. The cathode and anode were both made of brass, and ceramic disks were used to electrically insulate the electrodes. The cathode disk had inner hole diameter of 1.0 mm (length: 2.0 mm). The gas with a flow rate was 1.0 L/min. The discharge was operated at voltages of 250 V, currents of 8 mA and gas pressures up to 100 kPa. The plasmas in the cathode opening were observed using a visible spectrometer. The forbidden line associated with the level mixing of upper levels was observed in the cathode surface, indicating that the high E field was formed. As the intensity ratio of forbidden to the allowed lines is a function of the E field which is calculated by perturtabation theory, we derived the field strength of 18 kV/cm at 1.0 mm cathode surface.

  2. Hollow nanoparticle cathode materials for sodium electrochemical cells and batteries

    Energy Technology Data Exchange (ETDEWEB)

    Shevchenko, Elena; Rajh, Tijana; Johnson, Christopher S.; Koo, Bonil

    2016-07-12

    A cathode comprises, in its discharged state, a layer of hollow .gamma.-Fe.sub.2O.sub.3 nanoparticles disposed between two layers of carbon nanotubes, and preferably including a metallic current collector in contact with one of the layers of carbon nanotubes. Individual particles of the hollow .gamma.-Fe.sub.2O.sub.3 nanoparticles comprise a crystalline shell of .gamma.-Fe.sub.2O.sub.3 including cation vacancies within the crystal structure of the shell (i.e., iron vacancies of anywhere between 3% to 90%, and preferably 44 to 77% of available octahedral iron sites). Sodium ions are intercalated within at least some of the cation vacancies within the crystalline shell of the hollow .gamma.-Fe.sub.2O.sub.3 nanoparticles.

  3. Note: Improved heater design for high-temperature hollow cathodes

    Science.gov (United States)

    McDonald, M. S.; Gallimore, A. D.; Goebel, D. M.

    2017-02-01

    We present an improved heater design for thermionic cathodes using a rhenium filament encased in a boron nitride ceramic sleeve. This heater is relatively simple to fabricate, yet has been successfully used to reliably and repeatably light a lanthanum hexaboride (LaB6) hollow cathode based on a previously published design without noticeable filament degradation over hundreds of hours of operation. The high decomposition temperature of boron nitride (2800 C for inert environments) and melting point for rhenium (3180 C) make this heater especially attractive for use with LaB6, which may require operating temperatures upwards of 1700 C. While boron nitride decomposes in air above 1000 C, the heater was used only at vacuum with an inert gas discharge, and no degradation was observed. Limitations of current state of the art cathode heaters are also discussed and compared with the rhenium-boron nitride combination.

  4. Influence of the Iron Anisothermal Sintering on the Characteristic of the Hollow Cathode Discharge

    Institute of Scientific and Technical Information of China (English)

    BRUNATTO; Silvio Francisco; MUZART; Joel Louis Rene

    2004-01-01

    This work studies the influence of anisothermal iron sintering process on hollow cathode discharge characteristics. Two independent cathodes form an annular discharge. The pressed cylindrical iron powder sample, acting as central cathode, was placed concentrically in the interior of an external cathode. The external cathode, machined from an AISI 3 l0 steel bar, besides acting to confine the geometry of the plasma, can also acts as a source of alloying elements. The sample heating is a function of the ion bombardment energy and, so, of the discharge electrical parameters: current (or current density) and the effective potential applied to the cathode. Successive anisothermal sintering is performed in a same sample until the reproducibility of the electrical parameters being obtained. The heating experiments up to 1250 ℃, in a gas mixture of 80% Ar + 20% H2, at pressure of 133 Pa, at flow of 2xl0-6 m3s-1, with an inter-cathode radial space of 5.8 mm,were carried out. It was verified the metallurgical evolution of the iron sample sintering process influences the current-ton(time switched-on of the pulse) characteristics of the discharge.

  5. Experimental Study on RF Hollow Cathode Discharge

    Institute of Scientific and Technical Information of China (English)

    甘肇强; 吴雪梅; 姚伟国

    2001-01-01

    By using a longitudinal static magnetic field, we have shown that it is possible to excite an intensive plasma in a simple stainless steel tube which is connected with a RF power supply. Under certain conditions, the very bright Ar Ⅱ lines were excited. The emission intensities of Ar Ⅱ lines were increased with the increase in RF power, magnetic field, and the decrease in argon pressure. As the plasma-sheath boundary oscillating under the RF voltage, the plasma column is periodically compressed by the oscillating boundary.``

  6. Electron and ion kinetics in a micro hollow cathode discharge

    Energy Technology Data Exchange (ETDEWEB)

    Kim, G J; Iza, F; Lee, J K [Electronics and Electrical Engineering Department, Pohang University of Science and Technology, Pohang, 790-784 (Korea, Republic of)

    2006-10-21

    Electron and ion kinetics in a micro hollow cathode discharge are investigated by means of two-dimensional axisymmetric particle-in-cell Monte Carlo collision simulations. Argon discharges at 10 and 300 Torr are studied for various driving currents. Electron and ion energy probability functions (IEPF) are shown at various times and locations to study the spatio-temporal behaviour of the discharge. The electron energy probability function (EEPF) evolves from the Druyvesteyn type in the early stages of the discharge into a two (or three) temperature distribution when steady state is reached. In steady state, secondary electrons accelerated across the cathode fall populate the high energy tail of the EEPF while the low energy region is populated by trapped electrons. The IEPF evolves from a Maxwellian in the negative glow (bulk) to a two temperature distribution on the cathode surface. The overpopulation of low energy ions near the cathode surface is attributed to a larger collision cross section for low energy ions and ionization within the cathode fall.

  7. Role of hydrogen diffusion in temperature-induced transformation of carbon nanostructures deposited on metallic substrates by using a specially designed fused hollow cathode cold atmospheric pressure plasma source

    Science.gov (United States)

    Sharma, Bikash; Kar, R.; Pal, Arup R.; Shilpa, R. K.; Dusane, R. O.; Patil, D. S.; Suryawanshi, S. R.; More, M. A.; Sinha, S.

    2017-04-01

    Carbon nanofibers (CNFs) and carbon nanotubes (CNTs) are grown on inconel substrates under two different experimental conditions using atmospheric pressure glow discharge radio-frequency (RF) PECVD process. A specially designed hollow cathode is used for this plasma generation. The growth is carried out at 610 and 660 °C substrate temperatures on inconel substrates. Our results show that CNFs and CNTs could be synthesized at 610 and 660 °C respectively irrespective of pre-treatment methods in either set. HRTEM results indicate that a temperature-induced transformation of CNFs into CNTs occur when the growth temperature is raised from 610 to 660 °C. With the help of characterization results and a schematic model, it is shown how an increase in hydrogen diffusion (~44% increase) plays a pivotal role in this transformation by providing a sink for hydrogen atoms. Field emission results show that most defective CNFs contribute to the maximum emission current density. This better field emission behavior is explained on the basis that the outer surfaces of CNFs are more defective due to the presence of the open edges of the graphene planes, which results in better field emission from the outer surfaces of the CNFs.

  8. The analysis of high amplitude of potential oscillations near the hollow cathode of ion thruster

    Science.gov (United States)

    Qin, Yu; Xie, Kan; Guo, Ning; Zhang, Zun; Zhang, Cen; Gu, Zengjie; Zhang, Yu; Jiang, Zhaorui; Ouyang, Jiting

    2017-05-01

    The influence of gas flow, current level, and different shapes of anode on the oscillation amplitude and the characteristics of the hollow cathode discharge were investigated. The average plasma potential, temporal measurements of plasma potential, ion density, the electron temperature, as well as waveforms of plasma potential for test conditions were measured. At the same time, the time-resolved images of the plasma plume were also recorded. The results show that the potential oscillations appear at high discharge current or low flow rate. The potential oscillation boundaries, the position of maximum amplitude of plasma potential, and the position where the highest ion density was observed, were found. Both of the positions are affected by different shapes of anode configurations. This high amplitude of potential oscillations is ionization-like instabilities. The xenon ions ionized in space was analyzed for the fast potential rise and spatial dissipation of the space xenon ions was the reason for the gradual potential delay.

  9. Emission characteristics of laser ablation-hollow cathode glow discharge spectral source

    Directory of Open Access Journals (Sweden)

    Karatodorov Stefan

    2014-11-01

    Full Text Available The emission characteristics of a scheme combining laser ablation as sample introduction source and hollow cathode discharge as excitation source are presented. The spatial separation of the sample material introduction by laser ablation and hollow cathode excitation is achieved by optimizing the gas pressure and the sample-cathode gap length. At these conditions the discharge current is maximized to enhance the analytical lines intensity.

  10. Two-dimensional, hybrid model of glow discharge in hollow cathode geometries

    Energy Technology Data Exchange (ETDEWEB)

    Fiala, A.; Pitchford, L.C.; Boeuf, J.P. [Universite Paul Sabatier, Toulouse (France)

    1995-12-31

    Low pressure glow discharges in plane-plane geometries have been studied extensively over the years and most of their features are known from experiments and numerical simulation. If a plane cathode is replaced by a cathode with some hollow structure, then, for a certain range of conditions, the negative glows of opposite (adjacent) cathode walls overlap and the discharge behaviour dramatically changes. The voltage is lower at a constant current and the current is even several orders of magnitude higher for a given voltage than for the plane cathode. At the same time, the intensity of the light emission from the discharge considerably increases. This effect is called the hollow cathode effect. There are several physical phenomena which could be responsible for the big efficiency of the hollow cathode discharges. The recent investigations based on the Monte Carlo simulation of the electron kinetics have shown that the trapping of energetic electrons in the hollow cathode cavity can explain the order of magnitude of the hollow cathode effect. The configuration of the discharge tube presented in fig. 1 is used here to study the behaviour of glow discharges in a hollow cathode means of numerical simulation.

  11. Study of electron current extraction from a radio frequency plasma cathode designed as a neutralizer for ion source applications

    Energy Technology Data Exchange (ETDEWEB)

    Jahanbakhsh, Sina, E-mail: sinajahanbakhsh@gmail.com; Satir, Mert; Celik, Murat [Department of Mechanical Engineering, Bogazici University, Istanbul 34342 (Turkey)

    2016-02-15

    Plasma cathodes are insert free devices that are developed to be employed as electron sources in electric propulsion and ion source applications as practical alternatives to more commonly used hollow cathodes. Inductively coupled plasma cathodes, or Radio Frequency (RF) plasma cathodes, are introduced in recent years. Because of its compact geometry, and simple and efficient plasma generation, RF plasma source is considered to be suitable for plasma cathode applications. In this study, numerous RF plasma cathodes have been designed and manufactured. Experimental measurements have been conducted to study the effects of geometric and operational parameters. Experimental results of this study show that the plasma generation and electron extraction characteristics of the RF plasma cathode device strongly depend on the geometric parameters such as chamber diameter, chamber length, orifice diameter, orifice length, as well as the operational parameters such as RF power and gas mass flow rate.

  12. Laser-plasma-based linear collider using hollow plasma channels

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, C.B., E-mail: CBSchroeder@lbl.gov; Benedetti, C.; Esarey, E.; Leemans, W.P.

    2016-09-01

    A linear electron–positron collider based on laser-plasma accelerators using hollow plasma channels is considered. Laser propagation and energy depletion in the hollow channel is discussed, as well as the overall efficiency of the laser-plasma accelerator. Example parameters are presented for a 1-TeV and 3-TeV center-of-mass collider based on laser-plasma accelerators.

  13. Atlas of uranium emission intensities in a hollow cathode discharge

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, B.A.; Keller, R.A.; Engleman, R. Jr.

    1980-07-01

    The uranium emission spectrum from a hollow cathode discharge is displayed from 11,000 to 26,000 cm/sup -1/. This atlas lists 4928 spectral lines of uranium; 3949 are classified to the neutral spectrum and 431 are classified to the singly ionized spectrum. Listed wavenumbers are accurate to +-0.003 cm/sup -1/ and the listed relative intensities to +-8%. The richness of the spectrum makes this atlas useful for wavenumber calibration of lasers, spectrographs, and monochromators to an accuracy of 1 part in 10/sup 7/. This atlas is also useful as a guide to the uranium spectrum, and relative oscillator strengths (gf values) can be calculated from the intensities to a precision of +-20%.

  14. Coronal and Local Thermodynamic Equilibriums in a Hollow Cathode Discharge

    Institute of Scientific and Technical Information of China (English)

    ZHENG Xu-Tao

    2005-01-01

    @@ A characteristic two-section profile of excited-state populations is observed in a hollow cathode discharge and is explained by coexistence of the coronal equilibrium (CE) and the local thermodynamic equilibrium (LTE).At helium pressure 0.1 Torr and cathode current 200-300 mA, vacuum ultraviolet radiations from He I 1snp 1 P (n = 2-16) and He Ⅱ np2P (n = 2-14) axe resolved with a 2.2-M McPherson spectrometer. Relative populations of these states are deduced from the discrete line intensities and are plotted against energy levels. For both the He Ⅰ and He Ⅱ series, as energy level increases, populations of high-n (n > 10) states are found to decrease much more quickly than low-n (n < 7) populations. While low-n populations are described with the CE dominated by direct electron-impact excitations, high-n populations are fitted with the LTE to calculate the population temperatures of gas atoms and ions. Validities of the CE and LTE in different n-ranges are considered on the competition between radiative decays of the excited states and their collisions with gas atoms.

  15. Plasma distribution of cathodic ARC deposition system

    Energy Technology Data Exchange (ETDEWEB)

    Anders, S.; Raoux, S.; Krishnan, K.; MacGill, R.A.; Brown, I.G. [Lawrence Berkeley National Lab., CA (United States)

    1996-08-01

    The plasma distribution using a cathodic arc plasma source with and without magnetic macroparticle filter has been determined by depositing on a transparent plastic substrate and measuring the film absorption. It was found that the width of the distribution depends on the arc current, and it also depends on the cathode material which leads to a spatial separation of the elements when an alloy cathode is used. By applying a magnetic multicusp field near the exit of the magnetic filter, it was possible to modify the plasma distribution and obtain a flat plasma profile with a constant and homogeneous elemental distribution.

  16. Mercury vapor hollow cathode component studies. [emissive materials for ion thruster requirements

    Science.gov (United States)

    Zuccaro, D. E.

    1973-01-01

    An experimental study of starting and operating characteristics of conventional hollow cathodes and of hollow cathodes without alkaline earth emissive materials demonstrated that the emissive mix is essential to obtain the desired cathode operation. Loss of the emissive mix by evaporation and chemical reaction was measured. New insert designs consisting of emissive mix supported on nickel and of barium impregnated porous tungsten were studied. Cathodes with a modified orifice geometry operated in a low voltage, 'spot' mode over a broad range of discharge current. Thermal degradation tests on cathode heaters showed the flame sprayed SERT II type to be the most durable at high temperatures. Thermal shock was observed to be a significant factor in limiting cathode heater life. A cathode having a barium impregnated porous tungsten tip and a heater which is potted in sintered alumina was found to have favorable operating characteristics.

  17. Mercury vapor hollow cathode component studies. [emissive materials for ion thruster requirements

    Science.gov (United States)

    Zuccaro, D. E.

    1973-01-01

    An experimental study of starting and operating characteristics of conventional hollow cathodes and of hollow cathodes without alkaline earth emissive materials demonstrated that the emissive mix is essential to obtain the desired cathode operation. Loss of the emissive mix by evaporation and chemical reaction was measured. New insert designs consisting of emissive mix supported on nickel and of barium impregnated porous tungsten were studied. Cathodes with a modified orifice geometry operated in a low voltage, 'spot' mode over a broad range of discharge current. Thermal degradation tests on cathode heaters showed the flame sprayed SERT II type to be the most durable at high temperatures. Thermal shock was observed to be a significant factor in limiting cathode heater life. A cathode having a barium impregnated porous tungsten tip and a heater which is potted in sintered alumina was found to have favorable operating characteristics.

  18. Ignition and extinction phenomena in helium micro hollow cathode discharges

    Energy Technology Data Exchange (ETDEWEB)

    Kulsreshath, M. K.; Schwaederle, L.; Dufour, T.; Lefaucheux, P.; Dussart, R. [GREMI, CNRS/Université d' Orléans (UMR7344), Orléans (France); Sadeghi, N. [LIPhy, CNRS and Universite Joseph Fourier (UMR5588), Grenoble (France); Overzet, L. J. [GREMI, CNRS/Université d' Orléans (UMR7344), Orléans (France); PSAL, UTDallas, Richardson, Texas 75080-3021 (United States)

    2013-12-28

    Micro hollow cathode discharges (MHCD) were produced using 250 μm thick dielectric layer of alumina sandwiched between two nickel electrodes of 8 μm thickness. A through cavity at the center of the chip was formed by laser drilling technique. MHCD with a diameter of few hundreds of micrometers allowed us to generate direct current discharges in helium at up to atmospheric pressure. A slowly varying ramped voltage generator was used to study the ignition and the extinction periods of the microdischarges. The analysis was performed by using electrical characterisation of the V-I behaviour and the measurement of He*({sup 3}S{sub 1}) metastable atoms density by tunable diode laser spectroscopy. At the ignition of the microdischarges, 2 μs long current peak as high as 24 mA was observed, sometimes followed by low amplitude damped oscillations. At helium pressure above 400 Torr, an oscillatory behaviour of the discharge current was observed just before the extinction of the microdischarges. The same type of instability in the extinction period at high pressure also appeared on the density of He*({sup 3}S{sub 1}) metastable atoms, but delayed by a few μs relative to the current oscillations. Metastable atoms thus cannot be at the origin of the generation of the observed instabilities.

  19. Ignition and extinction phenomena in helium micro hollow cathode discharges

    CERN Document Server

    Kulsreshath, M K; Schwaederle, L; Dufour, T; Overzet, L J; Lefaucheux, P; Dussart, R

    2016-01-01

    Micro hollow cathode discharges (MHCD) were produced using 250 m thick dielectric layer of alumina sandwiched between two nickel electrodes of 8 m thickness. A through cavity at the center of the chip was formed by laser drilling technique. MHCD with a diameter of few hundreds of micrometers allowed us to generate direct current discharges in helium at up to atmospheric pressure. A slowly varying ramped voltage generator was used to study the ignition and the extinction periods of the microdischarges. The analysis was performed by using electrical characterisation of the V-I behaviour and the measurement of He*(3S1) metastable atoms density by tunable diode laser spectroscopy. At the ignition of the microdischarges, 2 s long current peak as high as 24 mA was observed, sometimes followed by low amplitude damped oscillations. At helium pressure above 400 Torr, an oscillatory behaviour of the discharge current was observed just before the extinction of the microdischarges. The same type of instability in the ext...

  20. Hollow cathode lamp based Faraday anomalous dispersion optical filter.

    Science.gov (United States)

    Pan, Duo; Xue, Xiaobo; Shang, Haosen; Luo, Bin; Chen, Jingbiao; Guo, Hong

    2016-07-15

    The Faraday anomalous dispersion optical filter (FADOF), which has acquired wide applications, is mainly limited to some gaseous elements and low melting-point metals before, for the restriction of the attainable atomic density. In conventional FADOF systems a high atomic density is usually achieved by thermal equilibrium at the saturated vapor pressure, hence for elements with high melting-points a high temperature is required. To avoid this restriction, we propose a scheme of FADOF based on the hollow cathode lamp (HCL), instead of atomic vapor cells. Experimental results in strontium atoms verified this scheme, where a transmission peak corresponding to the (88)Sr (5s(2))(1)S0 - (5s5p)(1)P1 transition (461 nm) is obtained, with a maximum transmittance of 62.5% and a bandwith of 1.19 GHz. The dependence of transmission on magnetic field and HCL discharge current is also studied. Since the state-of-art commercial HCLs cover about 70 elements, this scheme can greatly expand the applications of FADOFs, and the abundant atomic transitions they provide bring the HCL based FADOFs potential applications for frequency stabilization.

  1. Uniqueness theorem for the non-local ionization source in glow discharge and hollow cathode

    CERN Document Server

    Gorin, Vladimir V

    2012-01-01

    The paper is devoted to the proof of the uniqueness theorem for solution of the equation for the non-local ionization source in a glow discharge and a hollow cathode in general 3D geometry. The theorem is applied to wide class of electric field configurations, and to the walls of discharge volume, which have a property of incomplete absorption of the electrons. Cathode is regarded as interior singular source, which is placed arbitrarily close to the wall. The existence of solution is considered also. During the proof of the theorem many of useful structure formulae are obtained. Elements of the proof structure, which have arisen, are found to have physical sense. It makes clear physical construction of non-local electron avalanche, which builds a source of ionization in glow discharge at low pressures. Last has decisive significance to understand the hollow cathode discharge configuration and the hollow cathode effect.

  2. Hollow ballistic pendulum for plasma momentum measurements

    Science.gov (United States)

    Goncharov, S. F.; Pashinin, P. P.; Perov, V. Y.; Serov, R. V.; Yanovsky, V. P.

    1988-05-01

    A novel pendulum design—hollow ballistic pendulum—is suggested for plasma momentum measurements. It has an advantage over the pendula used earlier in laser plasma experiments of being insensitive to a momentum of matter evaporated and scattered by the pendulum wall exposed to the plasma, which usually exceeds plasma momentum to be measured. Simple expressions describing pendulum performance are derived, and requirements of shape and size are established. Using this kind of pendulum in experiments on laser acceleration of thin foils made it possible to measure the momentum of accelerated foil with an accuracy of about 10%.

  3. RF Electron Gun with Driven Plasma Cathode

    CERN Document Server

    Khodak, Igor

    2005-01-01

    It's known that RF guns with plasma cathodes based on solid-state dielectrics are able to generate an intense electron beam. In this paper we describe results of experimental investigation of the single cavity S-band RF gun with driven plasma cathode. The experimental sample of the cathode based on ferroelectric ceramics has been designed. Special design of the cathode permits to separate spatially processes of plasma development and electron acceleration. It has been obtained at RF gun output electron beam with particle energy ~500 keV, pulse current of 4 A and pulse duration of 80 ns. Results of experimental study of beam parameters are referred in. The gun is purposed to be applied as the intense electron beam source for electron linacs.

  4. Diamond-Like Carbon Film Deposition Using DC Ion Source with Cold Hollow Cathode

    Directory of Open Access Journals (Sweden)

    E. F. Shevchenko

    2014-01-01

    Full Text Available Carbon diamond-like thin films on a silicon substrate were deposited by direct reactive ion beam method with an ion source based on Penning direct-current discharge system with cold hollow cathode. Deposition was performed under various conditions. The pressure (12–200 mPa and the plasma-forming gas composition consisting of different organic compounds and hydrogen (C3H8, CH4, Si(CH32Cl2, H2, the voltage of accelerating gap in the range 0.5–5 kV, and the substrate temperature in the range 20–850°C were varied. Synthesized films were researched using nanoindentation, Raman, and FTIR spectroscopy methods. Analysis of the experimental results was made in accordance with a developed model describing processes of growth of the amorphous and crystalline carbon materials.

  5. Towards a reduced chemistry module of a He-Ar-Cu hollow cathode discharge

    Science.gov (United States)

    Mihailova, D.; van Dijk, J.; Grozeva, M.; Degrez, G.; van der Mullen, J. J. A. M.

    2011-05-01

    This study is aimed at finding a reduced chemistry module for a hollow cathode discharge (HCD) excited in a He-Ar-Cu mixture. This enables us to construct lean and reliable models that can be used as a part of the design tool of HCDs. To this end estimative calculations and numerical simulations are performed under optimal conditions for lasing. An analysis of the species behaviour and reactions is made and as a result the model is simplified by means of reducing the number of species and reactions. The consequences of these reductions are justified by comparing the results of the simplified models with those of a more complete one. This study delivers a model that is chemically lean and thus, much less time consuming. It can be used in optimization studies to find the optimum in the plasma control parameter set of HCDs. The technique developed in this study for HCDs can be applied to glow discharges in general.

  6. Self-pulsing in a low-current hollow cathode discharge: From Townsend to glow discharge

    Energy Technology Data Exchange (ETDEWEB)

    Qin, Yu [School of Physics, Beijing Institute of Technology, Beijing 100081 (China); School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081 (China); Xie, Kan, E-mail: xiekan@bit.edu.cn [School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081 (China); Zhang, Yu; Ouyang, Jiting [School of Physics, Beijing Institute of Technology, Beijing 100081 (China)

    2016-02-15

    We investigate the self-pulsing phenomenon of a low current cavity discharge in a cylindrical hollow cathode in pure argon. The waveforms of pulsed current and voltage are measured, and the time-averaged and time-resolved images of hollow cathode discharge are recorded by using high-speed intensified charge coupled device camera. The results show that the self-pulsing is a mode transition between low-current stage of Townsend discharge and high-current stage of glow discharge. During the self-pulsing, the current rising time relates to the dissipation of space charges, and the decay time relates to the reconstruction of the virtual anode by the accumulation of positive ions. Whether or not space charges can form and keep the virtual anode is responsible for the discharge mode and hence plays an important role in the self-pulsing phenomenon in low current hollow cathode discharge.

  7. Cathode heating mechanisms in pseudospark plasma switches

    Science.gov (United States)

    Sommerer, Timothy J.; Pak, Hoyoung; Kushner, Mark J.

    1992-10-01

    Pseudosparks, and the back-lighted thyratron (BLT) in particular, are finding increasing application as pulse power switches. An attractive feature of BLTs is that high current densities (≥ tens of kA cm-2) can be sustained from metal cathodes without auxiliary heating. The source of this current is believed to be electric-field-enhanced thermionic emission resulting from heating of the cathode by ion bombardment during commutation which ultimately melts the surface of the cathode. It is proposed that a photon-driven ionization mechanism in the interelectrode gap of the BLT is responsible for initiating the observed patterns of cathode surface melting and electron emission. A 21/2-dimensional computer model is presented that incorporates a photo-induced ionization mechanism to spread the plasma into the interelectrode gap. It predicts a melting of the cathode in a pattern similar to that which is experimentally observed, and predicts a rate of field-enhanced thermionic electron emission that is sufficient to explain the high BLT conduction current density. In the absence of these mechanisms, the model does not predict the observed large-area melting of the face of the cathode. The cathode heating rate during the BLT switching phase is maximum for operating parameters that are very close to the limit for which the switch will close (that is, the smallest possible pressure-electrode spacing product and smallest possible electrode holes).

  8. Modulation Transfer Spectroscopy of Ytterbium Atoms in a Hollow Cathode Lamp

    Institute of Scientific and Technical Information of China (English)

    WANG Wen-Li; XU Xin-Ye

    2011-01-01

    We present the experimental study of modulation transfer spectroscopy of ytterbium atoms in a hollow cathode lamp.The dependences of its linewidth, slope and magnitude on the various experimental parameters are measured and fitted by the well-known theoretical expressions. The experimental results are in good agreement with the theoretical prediction. We have observed the Dicke narrowing effect by increasing the current of the hollow cathode lamp. It is also found that there are the optimal current and laser power to generate the better modulation transfer spectroscopy signal, which can be employed for locking the laser frequency to the atomic transition.

  9. Characteristics of a toroidal planar hollow cathode and its use for the preparation of Bi nanoparticles

    Science.gov (United States)

    Perez, A.; Luna, A. T.; Muhl, S.

    2013-12-01

    Using ideas from the sputter deposition by gas flow hollow cathode (GFHC) we have designed a new version in the form of a toroidal planar hollow cathode. Here the flow of gas is used to entrain the sputtered atoms and nanoparticles formed by agglomeration in the gas phase, through the cathode central exit aperture towards the substrate. We have studied the characteristics of the deposit as a function of the applied pulsed dc electrical power, the argon gas pressure and flow. By varying the different operating parameters, such as pressure (6.7-267 Pa), power (40-120 W) and gas flow (20-140 sccm), it was possible to control the size of the nanoparticles (10-150 nm) and the deposition rate (0.4-4.0 nm min-1). We demonstrate that the nanoparticles are of crystalline bismuth, even though the cathode is made of graphite with small added pieces of bismuth.

  10. Metrology in arc plasmas - A new cathode

    Science.gov (United States)

    Croche, R.

    1980-02-01

    A new radiating source consisting of an electric arc under argon pressure is described, with power varying between about 0.2 and 1.5 kW, and with the plasma furnishing a continuous spectrum between 115 and 350 nm. The arc functions from 5 to 50 A, with a voltage varying between 30 and 35 V. The cathode of the transfer arc is described in detail, including such advantages as easy igniting of the arc and the possibility of re-sharpening the tip of the cathode. Most important, the new 'knife-shaped' form of the tungsten cathode has improved the stability and reproducibility of the ultraviolet continuum emitted by the plasma of the arc, which is used at the French National Institute of Metrology as a transfer standard of spectral radiance in the vacuum ultraviolet.

  11. Hollow plasma channel for positron plasma wakefield acceleration

    Directory of Open Access Journals (Sweden)

    W. D. Kimura

    2011-04-01

    Full Text Available Plasma wakefield acceleration (PWFA has demonstrated the ability to produce very high gradients to accelerate electrons and positrons. In PWFA, a drive bunch of charged particles passes through a uniform plasma, thereby generating a wakefield that accelerates a witness bunch traveling behind the drive bunch. This process works well for electrons, but much less so for positrons due to the positive charge attracting rather than repealing the plasma electrons, which leads to reduced acceleration gradient, halo formation, and emittance growth. This problem can be alleviated by having the positron beam travel through a hollow plasma channel. Presented are modeling results for producing 10–100 cm long hollow plasma channels suitable for positron PWFA. These channels are created utilizing laser-induced gas breakdown in hydrogen gas. The results show that hollow channels with plasma densities of order 10^{16}  cm^{-3} and inner channel radii of order 20  μm are possible using currently available terawatt-level lasers. At these densities and radii, preliminary positron PWFA modeling indicates that longitudinal electric fields on axis can exceed 3  GV/m.

  12. Modeling of LaB6 hollow cathode performance and lifetime

    Science.gov (United States)

    Pedrini, Daniela; Albertoni, Riccardo; Paganucci, Fabrizio; Andrenucci, Mariano

    2015-01-01

    Thermionic hollow cathodes are currently used as sources of electrons in a variety of space applications, in particular as cathodes/neutralizers of electric thrusters (Hall effect and ion thrusters). Numerical tools are needed to guide the design of new devices before their manufacturing and testing, since multiple geometrical parameters influence the cathode performance. A reduced-order, numerical model was developed to assess the performance of orificed hollow cathodes, with a focus on the operational lifetime. The importance of the lifetime prediction is tied to its impact on the operational lifetime of the thruster to which the cathode is coupled. The cathode architecture consists of a refractory metal tube with an internal electron emitter made of lanthanum hexaboride (LaB6). The choice of LaB6 accounts for the reduced evaporation rate, the low sensitivity to poisoning and the absence of an activation procedure with respect to oxide cathodes. A LaB6 emitter is thus a valuable option for long-lasting cathodes, despite its relatively high work-function and reactivity with many refractory metals at high temperatures. The suggested reduced-order model self-consistently predicts the key parameters of the cathode operation, shedding light on the power deposition processes as well as on the main erosion mechanisms. Preliminary results showed good agreement with both the experimental data collected by Alta and data available from the literature for different operating conditions and power levels. Next developments will include further comparisons between theoretical and experimental data, considering cathodes of various size and operating conditions.

  13. Hollow Carbon Nanofiber-Encapsulated Sulfur Cathodes for High Specific Capacity Rechargeable Lithium Batteries

    KAUST Repository

    Zheng, Guangyuan

    2011-10-12

    Sulfur has a high specific capacity of 1673 mAh/g as lithium battery cathodes, but its rapid capacity fading due to polysulfides dissolution presents a significant challenge for practical applications. Here we report a hollow carbon nanofiber-encapsulated sulfur cathode for effective trapping of polysulfides and demonstrate experimentally high specific capacity and excellent electrochemical cycling of the cells. The hollow carbon nanofiber arrays were fabricated using anodic aluminum oxide (AAO) templates, through thermal carbonization of polystyrene. The AAO template also facilitates sulfur infusion into the hollow fibers and prevents sulfur from coating onto the exterior carbon wall. The high aspect ratio of the carbon nanofibers provides an ideal structure for trapping polysulfides, and the thin carbon wall allows rapid transport of lithium ions. The small dimension of these nanofibers provides a large surface area per unit mass for Li2S deposition during cycling and reduces pulverization of electrode materials due to volumetric expansion. A high specific capacity of about 730 mAh/g was observed at C/5 rate after 150 cycles of charge/discharge. The introduction of LiNO3 additive to the electrolyte was shown to improve the Coulombic efficiency to over 99% at C/5. The results show that the hollow carbon nanofiber-encapsulated sulfur structure could be a promising cathode design for rechargeable Li/S batteries with high specific energy. © 2011 American Chemical Society.

  14. Plasma Cathode for E-Beam Lasers

    Science.gov (United States)

    1975-08-01

    JMJIIJUillWWpi^WiffW^HipaHIP’Pi1’’’ "a" ii.lllVi;lM’iiWMlMBfj!|l|>WiiU|’lUW"L’l’w«|M>l|Wy™.^J"^^y-ff^w», iitM ^^^ The 4 cm x 40 cm plasma cathode e-gun, which is

  15. Cathodic Cage Plasma Nitriding: An Innovative Technique

    OpenAIRE

    Sousa,R.R.M.; de Araújo, F. O.; J. A. P. da Costa; Brandim,A.S.; R. A. de Brito; C. Alves

    2012-01-01

    Cylindrical samples of AISI 1020, AISI 316, and AISI 420 steels, with different heights, were simultaneously treated by a new technique of ionic nitriding, entitled cathodic cage plasma nitriding (CCPN), in order to evaluate the efficiency of this technique to produce nitrided layers with better properties compared with those obtained using conventional ionic nitriding technique. This method is able to eliminate the edge effect in the samples, promoting a better uniformity of temperature, and...

  16. Operating modes of a hydrogen ion source based on a hollow-cathode pulsed Penning discharge

    Energy Technology Data Exchange (ETDEWEB)

    Oks, E. M. [Institute of High Current Electronics, Siberian Branch of Russian Academy of Science, Tomsk (Russian Federation); Tomsk State University of Control System and Radioelectronics, Tomsk (Russian Federation); Shandrikov, M. V., E-mail: shandrikov@opee.hcei.tsc.ru; Vizir, A. V. [Institute of High Current Electronics, Siberian Branch of Russian Academy of Science, Tomsk (Russian Federation)

    2016-02-15

    An ion source based on a hollow-cathode Penning discharge was switched to a high-current pulsed mode (tens of amperes and tens of microseconds) to produce an intense hydrogen ion beam. With molecular hydrogen (H{sub 2}), the ion beam contained three species: H{sup +}, H{sub 2}{sup +}, and H{sub 3}{sup +}. For all experimental conditions, the fraction of H{sub 2}{sup +} ions in the beam was about 10 ÷ 15% of the total ion beam current and varied little with ion source parameters. At the same time, the ratio of H{sup +} and H{sub 3}{sup +} depended strongly on the discharge current, particularly on its distribution in the gap between the hollow and planar cathodes. Increasing the discharge current increased the H{sup +} fraction in ion beam. The maximum fraction of H{sup +} reached 80% of the total ion beam current. Forced redistribution of the discharge current in the cathode gap for increasing the hollow cathode current could greatly increase the H{sub 3}{sup +} fraction in the beam. At optimum parameters, the fraction of H{sub 3}{sup +} ions reached 60% of the total ion beam current.

  17. Preparation of spherical hollow alumina particles by thermal plasma

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Wonkyung [Department of Chemical Engineering, INHA University, 253 Yonghyun-dong, Nam-gu, Incheon 402‐751 (Korea, Republic of); Regional Innovation Center for Environmental Technology of Thermal Plasma (RIC-ETTP), INHA University, 253 Yonghyun-dong, Nam-gu, Incheon 402‐751 (Korea, Republic of); Choi, Sooseok [Center for Advance Research in Fusion Reactor Engineering, Seoul National University, 599 Gwanak-ro, Gwanak-gu, Seoul 151‐742 (Korea, Republic of); Oh, Seung-Min [Daejoo Electronic Materials Co., 1236‐10 Jeongwang-dong, Siheung-si, Kyunggi-do 429‐848 (Korea, Republic of); Park, Dong-Wha, E-mail: dwpark@inha.ac.kr [Department of Chemical Engineering, INHA University, 253 Yonghyun-dong, Nam-gu, Incheon 402‐751 (Korea, Republic of); Regional Innovation Center for Environmental Technology of Thermal Plasma (RIC-ETTP), INHA University, 253 Yonghyun-dong, Nam-gu, Incheon 402‐751 (Korea, Republic of)

    2013-02-01

    Spherical hollow particles were prepared from solid alumina powders using DC arc thermal plasma, and then spray coating was performed with the as-prepared particles. Operating variables for the hollow particle preparation process were additional plasma gas, input power, and carrier gas flow rate. The spherical hollow alumina particles were produced in the case of using additive gas of H{sub 2} or N{sub 2}, while alumina surface was hardly molten in the pure argon thermal plasma. In addition, the hollow particles were well produced in high power and low carrier gas conditions due to high melting point of alumina. Hollow structure was confirmed by focused ion beam-scanning electron microscopy analysis. Morphology and size distribution of the prepared particles that were examined by field emission-scanning electron microscopy and phase composition of the particles was characterized by X-ray diffraction. In the spray coating process, the as-prepared hollow particles showed higher deposition rate. - Highlights: ► Spherical hollow alumina powder was prepared by non-transferred DC arc plasma. ► Diatomic gasses were added in Ar plasma for high power. ► Prepared hollow alumina powder was efficient for the plasma spray coating.

  18. Preparation and photoluminescence of ZnO with nanostructure by hollow-cathode discharge

    Institute of Scientific and Technical Information of China (English)

    Xin-chao BIAN; Chun-qing HUO; Yue-fei ZHANG; Qiang CHEN

    2008-01-01

    Without the use of a metal catalyst in the pro-cess, ZnO with nanostructures was successfully prepared on Si (100) substrate by simple chemical vapor-deposition method. In our work, Ar was used as the plasma forming gas, O2 was the reactive gas and metal zinc powder (99.99% purity) vaporized by cylinder hollow-cathode dis-charge (HCD) acted as the zinc source. The crystal struc-tures of the as-synthesized ZnO nanostructures were characterized by X-ray diffraction (XRD); the ZnO sam-ple growing on the wall of the crucible showed a 'comb-like' nanostructure, while the other one at the bottom of the crucible showed a 'rod-like' structure, which can be attributed to the difference of the oxygen content. The measurement on the photoluminescence (PL) perform-ance of the ZnO nanostructures was carried out at room temperature. The results indicated that the 'comb-shape' ZnO nanomaterial possessed a remarkably strong ultra-violet emission peak centered at 388 nm, while ZnO nanorods, except better ultraviolet emission, also had relatively strong blue-green emission ranging from 470 to 600 nm due to the existence of oxygen vacancies. The growth mechanism of ZnO with nanostructures is also discussed in this paper.

  19. Cathodic Vacuum Arc Plasma of Thallium

    OpenAIRE

    Yushkov, Georgy Yu.; Anders, Andre

    2006-01-01

    Thallium arc plasma was investigated in a vacuum arc ion source. As expected from previous consideration of cathode materials in the Periodic Table of the Elements, thallium plasma shows lead-like behavior. Its mean ion charge state exceeds 2.0 immediately after arc triggering, reaches the predicted 1.60 and 1.45 after about 100 microsec and 150 microsec, respectively. The most likely ion velocity is initially 8000 m/s and decays to 6500 m/s and 6200 m/s after 100 microsec and 150 micros...

  20. Facile Synthesis of V2O5 Hollow Spheres as Advanced Cathodes for High-Performance Lithium-Ion Batteries

    Directory of Open Access Journals (Sweden)

    Xingyuan Zhang

    2017-01-01

    Full Text Available Three-dimensional V2O5 hollow structures have been prepared through a simple synthesis strategy combining solvothermal treatment and a subsequent thermal annealing. The V2O5 materials are composed of microspheres 2–3 μm in diameter and with a distinct hollow interior. The as-synthesized V2O5 hollow microspheres, when evaluated as a cathode material for lithium-ion batteries, can deliver a specific capacity as high as 273 mAh·g−1 at 0.2 C. Benefiting from the hollow structures that afford fast electrolyte transport and volume accommodation, the V2O5 cathode also exhibits a superior rate capability and excellent cycling stability. The good Li-ion storage performance demonstrates the great potential of this unique V2O5 hollow material as a high-performance cathode for lithium-ion batteries.

  1. Facile Synthesis of V₂O₅ Hollow Spheres as Advanced Cathodes for High-Performance Lithium-Ion Batteries.

    Science.gov (United States)

    Zhang, Xingyuan; Wang, Jian-Gan; Liu, Huanyan; Liu, Hongzhen; Wei, Bingqing

    2017-01-18

    Three-dimensional V₂O₅ hollow structures have been prepared through a simple synthesis strategy combining solvothermal treatment and a subsequent thermal annealing. The V₂O₅ materials are composed of microspheres 2-3 μm in diameter and with a distinct hollow interior. The as-synthesized V₂O₅ hollow microspheres, when evaluated as a cathode material for lithium-ion batteries, can deliver a specific capacity as high as 273 mAh·g(-1) at 0.2 C. Benefiting from the hollow structures that afford fast electrolyte transport and volume accommodation, the V₂O₅ cathode also exhibits a superior rate capability and excellent cycling stability. The good Li-ion storage performance demonstrates the great potential of this unique V₂O₅ hollow material as a high-performance cathode for lithium-ion batteries.

  2. Auxiliary glow discharge in the trigger unit of a hollow-cathode thyratron

    Energy Technology Data Exchange (ETDEWEB)

    Korolev, Yu. D.; Landl, N. V., E-mail: landl@lnp.hcei.tsc.ru; Geyman, V. G.; Frants, O. B.; Shemyakin, I. A.; Nekhoroshev, V. O. [Russian Academy of Sciences, Institute of High-Current Electronics, Siberian Branch (Russian Federation)

    2016-08-15

    Results from studies of a low-current glow discharge with a hollow cathode are presented. A specific feature of the discharge conditions was that a highly emissive tablet containing cesium carbonate was placed in the cathode cavity. In the absence of a tablet, the discharge ignition voltage was typically ≥3.5 kV, while the burning voltage was in the range of 500–600 V. The use of the tablet made it possible to decrease the ignition voltage to 280 V and maintain the discharge burning voltage at a level of about 130 V. A model of the current sustainment in a hollow-cathode discharge is proposed. Instead of the conventional secondary emission yield, the model uses a generalized emission yield that takes into account not only ion bombardment of the cathode, but also the emission current from an external source. The model is used to interpret the observed current−voltage characteristics. The results of calculations agree well with the experimental data. It is shown that, in some discharge modes, the external emission current from the cathode can reach 25% of the total discharge current.

  3. Auxiliary glow discharge in the trigger unit of a hollow-cathode thyratron

    Science.gov (United States)

    Korolev, Yu. D.; Landl, N. V.; Geyman, V. G.; Frants, O. B.; Shemyakin, I. A.; Nekhoroshev, V. O.

    2016-08-01

    Results from studies of a low-current glow discharge with a hollow cathode are presented. A specific feature of the discharge conditions was that a highly emissive tablet containing cesium carbonate was placed in the cathode cavity. In the absence of a tablet, the discharge ignition voltage was typically ≥3.5 kV, while the burning voltage was in the range of 500-600 V. The use of the tablet made it possible to decrease the ignition voltage to 280 V and maintain the discharge burning voltage at a level of about 130 V. A model of the current sustainment in a hollow-cathode discharge is proposed. Instead of the conventional secondary emission yield, the model uses a generalized emission yield that takes into account not only ion bombardment of the cathode, but also the emission current from an external source. The model is used to interpret the observed current-voltage characteristics. The results of calculations agree well with the experimental data. It is shown that, in some discharge modes, the external emission current from the cathode can reach 25% of the total discharge current.

  4. Atlas of the Spectrum of a Platinum/Neon Hollow-Cathode Lamp in the Region 1130-4330 Å

    Science.gov (United States)

    SRD 112 Atlas of the Spectrum of a Platinum/Neon Hollow-Cathode Lamp in the Region 1130-4330 Å (Web, free access)   Atlas of the Spectrum of a Platinum/Neon Hollow-Cathode Lamp in the Region 1130-4330 Å contains wavelengths and intensities for about 5600 lines in the region 4330 Å. An atlas plot of the spectrum is given, with the spectral lines marked and their intensities, wavelengths, and classifications listed.

  5. Alkali Absorption Property of Polypropylene Non-woven Fabrics Surface Modified by Hollow Cathode Remote Plasma Polymerization%空心阴极远区等离子体接枝聚合表面改性丙纶无纺布的吸碱性能

    Institute of Scientific and Technical Information of China (English)

    温贻芳; 陈新; 王士喜; 芮延年; 王红卫

    2011-01-01

    利用空心阴极远区等离子体改性技术对丙纶无纺布表面进行了改性处理,研究了等离子体处理参数对丙纶无纺布吸碱性能的影响;采用红外光谱、扫描电镜等对丙纶无纺布表面的化学组成和形态等进行了表征。结果表明:等离子体处理时间、放电功率、气体流量等对丙纶无纺布的吸碱性能有很大的影响,而且试样距丙烯酸喂气管的距离对处理效果的影响也很明显;通过空心阴极远区等离子体接枝聚合表面改性处理,在丙纶无纺布的表面引入了亲水性羧基基团,改善了其浸润性,显著提高了其吸碱率和吸碱速率,达到了国外进1:7电池隔膜的指标。%The surface of polypropylene non-woven fabrics was modified by hollow cathode remote plasma modification technology. The effect of the plasma treatment parameters on the property of polypropylene non-woven fabrics was studied. The FTIR and SEM were used to analyze the chemical composition and morphology. The results show that plasma treatment time, discharge power, gas flow had a great influence on the alkali absorption property, and the effect of the distance between the sample and acrylic acid feeding tube on treatment results was obvious. The invasion property of the polypropylene non-woven fabrics was improved due to the import of hydrophilic group by hollow cathode remote plasma surface modification. The alkali absorption capacity and rate were raised obviously, and the alkali absorption performance reached the level of foreign battery separator.

  6. Assessments of Hollow Cathode Wear in the Xenon Ion Propulsion System (XIPs(c)) by Numerical Analyses and Wear Tests

    Science.gov (United States)

    Mikellides, Ioannis G.; Katz, Ira; Goebel, Dan M.; Polk, James E.

    2008-01-01

    The standard approach presently followed by NASA to qualify electric propulsion for the required mission throughput has been based largely on life tests, which can be costly and time consuming. Revised electric propulsion lifequalification approaches are being formulated that combine analytical and/or computational methods with (shorter-duration) wear tests. As a model case, a wear test is being performed at JPL to assess the lifetime of the discharge hollow cathode in the Xenon Ion Propulsion System (XIPS(c)), a 25-cm ion engine developed by L-3 Communications Electron Technologies, Inc. for commercial applications. Wear and plasma data accumulated throughout this life-assessment program are being used to validate the existing 2-D hollow cathode code OrCa2D. We find that the OrCa2D steady-state solution predicts very well the time-averaged plasma data and the keeper voltage after 5500 hrs of operation in high-power mode. When the wave motion that occurs naturally in these devices is accounted for, based on an estimate of the maximum wave amplitude, the molybdenum-keeper erosion profile observed in the XIPS(c) discharge cathode is also reproduced within a factor of two of the observation. When the same model is applied to predict the erosion of a tantalum keeper we find that erosion is reduced by more than two orders of magnitude compared to the molybdenum keeper due the significantly lower sputtering yield of tantalum. A tantalum keeper would therefore allow keeper lifetimes that greatly exceed the present requirements for deep-space robotic missions considered by NASA. Moreover, such large reduction of the erosion renders the largest uncertainties in the models, which are associated with the wave amplitude estimates and the electron transport model, negligible.

  7. Optogalvanic effect and laser-induced current oscillations in hollow-cathode lamps

    Science.gov (United States)

    Eldakli, Mohsan S. A.; Ivković, Saša S.; Obradović, Bratislav M.

    2017-03-01

    This paper presents a study of two commercial hollow-cathode lamps (HCLs) with the intention of demonstrating different phenomena in gas discharges. The optogalvanic effect in both HCLs is produced by a laser diode radiated at the wavelength that corresponds to neon transition 1s2–2p2 at 659.89 nm. The voltage–current characteristics of the lamps are explained using a classical theory of hollow-cathode discharge, while the optogalvanic signal is treated as a small perturbation of the discharge current. For certain values of voltage self-sustained current oscillations are observed in one of the HCLs. In the same HCL laser-induced optogalvanic dumped oscillations are detected. A phenomenological model that includes the effective circuit parameters of the discharge is used to explain the oscillation characteristics.

  8. Laser optogalvanic wavelength calibration with a commercial hollow cathode iron - neon discharge lamp

    Science.gov (United States)

    Zhu, Xinming; Nur, Abdullahi H.; Misra, Prabhakar

    1994-01-01

    351 optogalvanic transitions have been observed in the 337 - 598 nm wavelength region using an iron - neon hollow cathode discharge lamp and a pulsed tunable dye laser. 223 of these have been identified as transitions associated with neon energy levels. These optogalvanic transitions have allowed, in conjunction with interference fringes recorded concomitantly with an etalon, the calibration of the dye laser wavelength with 0.3/cm accuracy.

  9. Continuous calibration of a vacuum ultraviolet system from 65 to 125 nm by a cascade arc and comparison with the calibrated line radiation of a hollow cathode.

    Science.gov (United States)

    Frost, R M; Awakowicz, P

    1997-03-20

    A high-power stationary helium cascade arc has been developed as a standard source for continuum radiation in the VUV spectral range from 65 to 125 nm. The calibration of the VUV system response was based on the calculated and measured continuum radiation of a 2-mmphi pure He arc. Diagnostics of the arc plasma in partial thermal equilibrium yielded the electron density and the temperature that were inserted in the calculations of the continuous radiation. The results were compared with the helium, argon, and krypton radiation lines of a high-current hollow cathode lamp. This lamp was built according to the construction drawings of a hollow cathode, which was calibrated by means of the electron synchrotron radiation at the Physikalisch Technische Bundesanstalt Berlin.

  10. A hollow cathode ion source for production of primary ions for the BNL electron beam ion source.

    Science.gov (United States)

    Alessi, James; Beebe, Edward; Carlson, Charles; McCafferty, Daniel; Pikin, Alexander; Ritter, John

    2014-02-01

    A hollow cathode ion source, based on one developed at Saclay, has been modified significantly and used for several years to produce all primary 1+ ions injected into the Relativistic Heavy Ion Collider Electron Beam Ion Source (EBIS) at Brookhaven. Currents of tens to hundreds of microamperes have been produced for 1+ ions of He, C, O, Ne, Si, Ar, Ti, Fe, Cu, Kr, Xe, Ta, Au, and U. The source is very simple, relying on a glow discharge using a noble gas, between anode and a solid cathode containing the desired species. Ions of both the working gas and ionized sputtered cathode material are extracted, and then the desired species is selected using an ExB filter before being transported into the EBIS trap for charge breeding. The source operates pulsed with long life and excellent stability for most species. Reliable ignition of the discharge at low gas pressure is facilitated by the use of capacitive coupling from a simple toy plasma globe. The source design, and operating experience for the various species, is presented.

  11. A hollow cathode ion source for production of primary ions for the BNL electron beam ion source

    Energy Technology Data Exchange (ETDEWEB)

    Alessi, James, E-mail: alessi@bnl.gov; Beebe, Edward; Carlson, Charles; McCafferty, Daniel; Pikin, Alexander; Ritter, John [Collider-Accelerator Department, Brookhaven National Laboratory, Upton, New York 11973 (United States)

    2014-02-15

    A hollow cathode ion source, based on one developed at Saclay, has been modified significantly and used for several years to produce all primary 1+ ions injected into the Relativistic Heavy Ion Collider Electron Beam Ion Source (EBIS) at Brookhaven. Currents of tens to hundreds of microamperes have been produced for 1+ ions of He, C, O, Ne, Si, Ar, Ti, Fe, Cu, Kr, Xe, Ta, Au, and U. The source is very simple, relying on a glow discharge using a noble gas, between anode and a solid cathode containing the desired species. Ions of both the working gas and ionized sputtered cathode material are extracted, and then the desired species is selected using an ExB filter before being transported into the EBIS trap for charge breeding. The source operates pulsed with long life and excellent stability for most species. Reliable ignition of the discharge at low gas pressure is facilitated by the use of capacitive coupling from a simple toy plasma globe. The source design, and operating experience for the various species, is presented.

  12. A multiple gap plasma cathode electron gun and its electron beam analysis in self and trigger breakdown modes

    Science.gov (United States)

    Kumar, Niraj; Pal, Dharmendra Kumar; Jadon, Arvind Singh; Pal, Udit Narayan; Rahaman, Hasibur; Prakash, Ram

    2016-03-01

    In the present paper, a pseudospark discharge based multiple gap plasma cathode electron gun is reported which has been operated separately in self and trigger breakdown modes using two different gases, namely, argon and hydrogen. The beam current and beam energy have been analyzed using a concentric ring diagnostic arrangement. Two distinct electron beams are clearly seen with hollow cathode and conductive phases. The hollow cathode phase has been observed for ˜50 ns where the obtained electron beam is having low beam current density and high energy. While in conductive phase it is high current density and low energy electron beam. It is inferred that in the hollow cathode phase the beam energy is more for the self breakdown case whereas the current density is more for the trigger breakdown case. The tailor made operation of the hollow cathode phase electron beam can play an important role in microwave generation. Up to 30% variation in the electron beam energy has been achieved keeping the same gas and by varying the breakdown mode operations. Also, up to 32% variation in the beam current density has been achieved for the trigger breakdown mode at optimized trigger position by varying the gas type.

  13. Two-stage plasma gun based on a gas discharge with a self-heating hollow emitter.

    Science.gov (United States)

    Vizir, A V; Tyunkov, A V; Shandrikov, M V; Oks, E M

    2010-02-01

    The paper presents the results of tests of a new compact two-stage bulk gas plasma gun. The plasma gun is based on a nonself-sustained gas discharge with an electron emitter based on a discharge with a self-heating hollow cathode. The operating characteristics of the plasma gun are investigated. The discharge system makes it possible to produce uniform and stable gas plasma in the dc mode with a plasma density up to 3x10(9) cm(-3) at an operating gas pressure in the vacuum chamber of less than 2x10(-2) Pa. The device features high power efficiency, design simplicity, and compactness.

  14. Electronic Transition Spectra of Thiophenoxy and Phenoxy Radicals in Hollow Cathode Discharges

    Science.gov (United States)

    Araki, Mitsunori; Wako, Hiromichi; Niwayama, Kei; Tsukiyama, Koichi

    2014-06-01

    Diffuse interstellar bands (DIBs) still remain the longest standing unsolved problem in spectroscopy and astrochemistry, although several hundreds of DIBs have been already detected. It is expected that identifications of DIBs can give us crucial information for extraterrestrial organic molecule. One of the best approaches to identify carrier molecules of DIBs is a measurement of DIB candidate molecule produced in the laboratory to compare their absorption spectra with astronomically observed DIB spectra. Radical in a gas phase is a potential DIB candidate molecule. The electronic transitions of polyaromatic hydrocarbon radicals result in optical absorption. However, because radicals are unstable, their electronic transitions are difficult to observe using a laboratory spectrometer system. To solve this difficulty, we have developed a glow-discharge cell using a hollow cathode in which radicals can be effectively produced as a high-density plasma. The radicals produced were measured by using the cavity ringdown (CRD) spectrometer and the discharge emission spectrometer. The CRD spectrometer, which consists of a tunable pulse laser system, an optical cavity and a discharge device, is an apparatus to observe an high-resolution optical absorption spectrum. The electronic transition of the thiophenoxy radical C6H5OS was observed in the discharge emission of thiophenol C6H5OH. The electronic transition frequency of the thiophenoxy radical was measured. A optical discharge emission was examined by using a HORIBA Jobin Yvon iHR320 monochromator. We detected the phenoxy radical C6H5O in the discharge of phenol C6H5OH. The band observed at 6107 Å in the discharge was assigned to the electronic transition of the phenoxy radical on the basis of the sample gas dependences and the reported low resolution spectrum. The electronic transition frequency of the phenoxy radical was measured. Comparison studies of the thiophenoxy and phenoxy radicals were made with known DIB spectra

  15. Heater Validation for the NEXT-C Hollow Cathodes

    Science.gov (United States)

    Verhey, Timothy R.; Soulas, George C.; Mackey, Jonathan Ar.

    2017-01-01

    Swaged cathode heaters whose design was successfully demonstrated under a prior flight project are to be provided by the NASA Glenn Research Center for the NEXT-C ion thruster being fabricated by Aerojet Rocketdyne. Extensive requalification activities were performed to validate process controls that had to be re-established or revised because systemic changes prevented reuse of the past approaches. A development batch of heaters was successfully fabricated based on the new process controls. Acceptance and cyclic life testing of multiple discharge and neutralizer sized heaters extracted from the development batch was initiated in August, 2016, with the last heater completing testing in April, 2017. Cyclic life testing results substantially exceeded the NEXT-C thruster requirement as well as all past experience for GRC fabricated units. The heaters demonstrated ultimate cyclic life capability of 19050 to 33500 cycles. A qualification batch of heaters is now being fabricated using the finalized process controls. A set of six heaters will be acceptance and cyclic tested to verify conformance to the behavior observed with the development heaters. The heaters for flight use will be then be provided to the contractor. This paper summarizes the fabrication process control activities and the acceptance and life testing of the development heater units.

  16. Invited article: physical and chemical analyses of impregnated cathodes operated in a plasma environment.

    Science.gov (United States)

    Sengupta, Anita; Kulleck, James; Hill, Norm; Ohlinger, Wayne

    2008-11-01

    Destructive analyses of impregnated-cathode assemblies from an ion thruster life test were performed to characterize erosion and degradation after 30,472 h of operation. Post-test inspection of each cathode included examination of the emitter (insert), orifice plate, cathode tube, heater, anode assembly, insulator, and propellant isolator. The discharge-cathode assembly experienced significant erosion due to ion sputtering from the discharge plasma. The keeper electrode plate was removed and the heater and orifice plate were heavily eroded at the conclusion of the test. Had the test continued, these processes would likely have led to cathode failure. The discharge cathode insert experienced significant tungsten transport and temperature dependent barium oxide depletion within the matrix. Using barium depletion semiempirical relations developed by Palluel and Shroff, it is estimated that 25,000 h of operation remained in the discharge insert at the conclusion of the test. In contrast, the neutralizer insert exhibited significantly less tungsten transport and barium oxide depletion consistent with its lower current operation. The neutralizer was estimated to have 140,000 h of insert life remaining at the conclusion of the test. Neither insert had evidence of tungstate or oxide layer formation, previously known to have impeded cathode ignition and operation in similar long duration hollow-cathode tests. The neutralizer cathode was in excellent condition at the conclusion of the test with the exception of keeper tube erosion from direct plume-ion impingement, a previously underappreciated life-limiting mechanism. The most critical finding from the test was a power dependent deposition process within the neutralizer-cathode orifice. The process manifested at low-power operation and led to the production of energetic ions in the neutralizer plume, a potential life-limiting process for the neutralizer. Subsequent return of the engine and neutralizer operation to full

  17. Cathodic Cage Plasma Nitriding: An Innovative Technique

    Directory of Open Access Journals (Sweden)

    R. R. M. de Sousa

    2012-01-01

    Full Text Available Cylindrical samples of AISI 1020, AISI 316, and AISI 420 steels, with different heights, were simultaneously treated by a new technique of ionic nitriding, entitled cathodic cage plasma nitriding (CCPN, in order to evaluate the efficiency of this technique to produce nitrided layers with better properties compared with those obtained using conventional ionic nitriding technique. This method is able to eliminate the edge effect in the samples, promoting a better uniformity of temperature, and consequently, a smaller variation of the thickness/height relation can be obtained. The compound layers were characterized by X-ray diffraction, optical microscopy, and microhardness test profile. The results were compared with the properties of samples obtained with the conventional nitriding, for the three steel types. It was verified that samples treated by CCPN process presented, at the same temperature, a better uniformity in the thickness and absence of the edge effect.

  18. Design and Manufacturing Processes of Long-Life Hollow Cathode Assembles

    Science.gov (United States)

    Patterson, Michael J. (Inventor); Verhey, Timothy R. (Inventor); Soulas, George C. (Inventor)

    2004-01-01

    A process for testing an impregnated insert of a Hollow Cathode Assembly (HCA) subsequent to every exposure of the HCA to air, and prior to ignition, using a heater and an oil-free assembly having a base pressure of less than 5.0 x 10(exp -6) torr. The process comprises the steps of: installing the HCA in a vacuum; energizing the heater to a particular current level; de-energizing the heater after one-half hour; again energizing the heater to a particular current level; and de-energizing the heater for at least one-half hour.

  19. Emission of excimer radiation from direct current, high-pressure hollow cathode discharges

    Science.gov (United States)

    El-Habachi, Ahmed; Schoenbach, Karl H.

    1998-01-01

    A novel, nonequilibrium, high-pressure, direct current discharge, the microhollow cathode discharge, has been found to be an intense source of xenon and argon excimer radiation peaking at wavelengths of 170 and 130 nm, respectively. In argon discharges with a 100 μm diam hollow cathode, the intensity of the excimer radiation increased by a factor of 5 over the pressure range from 100 to 800 mbar. In xenon discharges, the intensity at 170 nm increased by two orders of magnitude when the pressure was raised from 250 mbar to 1 bar. Sustaining voltages were 200 V for argon and 400 V for xenon discharges, at current levels on the order of mA. The resistive current-voltage characteristics of the microdischarges indicate the possibility to form arrays for direct current, flat panel excimer lamps.

  20. Characterization of the NEXT Hollow Cathode Inserts After Long-Duration Testing

    Science.gov (United States)

    Mackey, J.; Shastry, R.; Soulas, G.

    2017-01-01

    Hollow dispenser cathode inserts are a critical element of electric propulsion systems, and should therefore be well understood during long term operation to ensure reliable system performance. This work destructively investigated cathode inserts from the NEXT long-duration test which demonstrated 51,184 hours of high-voltage operation, 918 kg of propellant throughput, and 35.5 MN-s of total impulse. The characterization methods used include scanning electron microscopy with energy dispersive spectroscopy and X-ray diffraction. Microscopy analysis has been performed on fractured surfaces, emission surfaces, and metallographically polished cross-sections of post-test inserts and unused inserts. Impregnate distribution, etch region thickness, impregnate chemical content, emission surface topography, and emission surface phase identification are the primary factors investigated.

  1. Cathodic Cage Plasma Nitriding of Ti6Al4V Alloy

    Directory of Open Access Journals (Sweden)

    Maciej OSSOWSKI

    2016-05-01

    Full Text Available Glow discharge nitriding is being used increasingly more often for modifying the properties of titanium and its alloys with the aim to increase their frictional wear resistance, fatigue strength, and, in the case of medical applications, to eliminate the metallosis effect. Unlike PVD methods, ion nitriding ensures the formation of diffusive layers with very good adhesion to the substrate, but which still have some disadvanteges such as the “edge effect” or “hollow cathode effect” which hinders treatment of complex workpieces. The paper compares nitrided layers produced on Ti6Al4V alloy using two different types of nitriding processes. The first process is conventional dc plasma nitriding (DCPN where the samples were placed at the cathode potential, while the second one is a new method of cathodic cage plasma nitriding (CCPN process, where the substrate is insulated from the cathode and anode. The experiments have shown that the treatment conducted in a cathodic cage can be alternative for conventional ion nitriding, especially when used for small parts with complicated shapes used in the space or medical industry. DOI: http://dx.doi.org/10.5755/j01.ms.22.1.7343

  2. Assistant Anode in a Cathodic Arc Plasma Source

    Institute of Scientific and Technical Information of China (English)

    张涛; Paul K. Chu; 张荟星; Ian G. Brown

    2001-01-01

    The performance and characteristics of a cathodic arc plasma source, consisting of a titanium cathode, an anode with and without a tungsten mesh, and a coil producing a focusing magnetic field between the anode and cathode,are investigated. The high transparency and large area of the mesh allow a high plasma flux to penetrate the anode from the cathodic arc. The mesh helps to decrease the arc resistance and the ignition voltage of the cathodic arc in the focusing magnetic field, and to increase the life of the source, which means that the source makes the cathodic arc easily and greatly stabilized during the operation when a focusing magnetic field exists in the source.

  3. Plasma characterization on carbon fiber cathode by spectroscopic diagnostics

    Institute of Scientific and Technical Information of China (English)

    Liu Lie; Li Li-Min; Xu Qi-Fu; Chang Lei; Wen Jian-Chun

    2009-01-01

    This paper mainly investigates plasma characterization on carbon fiber cathodes with and without cesium iodide (CsI) coating powered by a~300 ns,~200 kV accelerating pulse. It was found that the CsI layers can not only improve the diode voltage,but also maintain a stable perveance.This indicates a slowly changed diode gap or a low cathode plasma expansion velocity.By spectroscopic diagnostics,in the vicinity of the cathode surface the average plasma density and temperature were found to be~3×1014 cm-3 and~5 eV,respectively,for an electron current density of~40 A/cm2.Furthermore,there exists a multicomponent plasma expansion toward the anode.The plasma expansion velocity,corresponding to the carbon and hydrogen ions,is estimated to be~1.5 cm/μs.Most notably,Cs spectroscopic line was obtained only at the distance ≤0.5 mm from the cathode surface.Carbon and hydrogen ions are obtained up to the distance of 2.5 mm from the cathode surface.Cs ions almost remain at the vicinity of the cathode surface.These results show that the addition of Cal enables a slow cathode plasma expansion toward the anode,providing a positive prospect for developing long-pulse electron beam sources.

  4. Plasma-induced field emission study of carbon nanotube cathode

    Directory of Open Access Journals (Sweden)

    Yi Shen

    2011-10-01

    Full Text Available An investigation on the plasma-induced field emission (PFE properties of a large area carbon nanotube (CNT cathode on a 2 MeV linear induction accelerator injector is presented. Experimental results show that the cathode is able to emit intense electron beams. Intense electron beams of 14.9–127.8  A/cm^{2} are obtained from the cathode. The CNT cathode desorbs gases from the CNTs during the PFE process. The fast cathode plasma expansion affects the diode perveance. The amount of outgassing is estimated to be 0.06–0.49  Pa·L, and the ratio of outgassing and electron are roughly calculated to be within the range of 170–350 atoms per electron. The effect of the outgassing is analyzed, and the outgassing mass spectrum of the CNT cathode has been studied during the PFE. There is a significant desorption of CO_{2}, N_{2}(CO, and H_{2} gases, which plays an important role during the PFE process. All the experiments demonstrate that the outgassing plays an important role in the formation of the cathode plasma. Moreover, the characteristic turn-on time of the CNT cathode was measured to be 39 ns.

  5. Small-size plasma diode with a transparent internal cathode for neutron generation

    Science.gov (United States)

    Shikanov, A. E.; Vovchenko, E. D.; Kozlovskii, K. I.; Shatokhin, V. L.

    2015-01-01

    A discharge plasma system for neutron generation based on the concept of inertial electrostatic confinement is considered. The system is made in the form of a gas-filled (1-60 Pa) diode with a composite hollow cathode placed at its center symmetrically to an embracing hollow cylindrical anode. Preionization of the discharge gap and an original design of the electrode system with a transparent central part make it possible to initiate a pulse high-voltage (100-150 kV) volume discharge in the ion oscillation mode. Estimates of the neutron emission in such a deuterium-filled diode show the feasibility of generating a pulse with a neutron yield on the order of 105 in the reaction D( d, n)3He, which is confirmed in experiments with an optimized geometry of the electrodes.

  6. Global model of a micro hollow cathode discharge in Ar/N2 used for nitride synthesis

    Science.gov (United States)

    Lazzaroni, Claudia; Kasri, Salima

    2016-09-01

    A global model of a Micro Hollow Cathode Discharge (MHCD) in argon (Ar) with an admixture of nitrogen (N2) , working at several hundreds of Torr, is presented. MHCDs allow high electron densities and therefore high dissociation degree of nitrogen to be reached which is particularly suited for nitride deposition given the high bond energy of molecular nitrogen. The global model is based on the numerical resolution of the particle balance equations and the power balance equation. The model is run until the steady state is reached and we obtain the plasma parameters that are the species densities and the electron temperature. A particular focus is given to the atomic nitrogen density, a key parameter for the deposition and growth of nitride films. A parametric study is done varying the gas pressure and the N2 fraction in Ar. Despite being fed by a DC power supply, MHCDs operate in steady state and in self-pulsed mode, both captured by the model. The effect of the MHCD mode (steady or self-pulsed) on the plasma parameters is also presented.

  7. Hollow spherical carbonized polypyrrole/sulfur composite cathode materials for lithium/sulfur cells with long cycle life

    Science.gov (United States)

    Wang, Zhongbao; Zhang, Shichao; Zhang, Lan; Lin, Ruoxu; Wu, Xiaomeng; Fang, Hua; Ren, Yanbiao

    2014-02-01

    Hollow carbonized polypyrrole (PPy) spheres are synthesized using poly(methyl methacrylate-ethyl acrylate-acrylic acid) latex spheres as sacrificial templates. The hollow spherical carbonized PPy/sulfur composite cathode materials are prepared by heating the mixture of hollow carbonized PPy spheres and element sulfur at 155 °C for 24 h. Scanning electron microscope (SEM) and transmission electron microscope (TEM) observations show the hollow structures of the carbonized PPy spheres and the homogeneous distribution of sulfur on the carbonized PPy shells. The hollow spherical carbonized PPy/sulfur composite with 60.9 wt.% S shows high specific capacity and excellent cycling stability when used as the cathode materials in lithium/sulfur cells, whose initial specific discharge capacity reaches as high as 1320 mA h g-1 and the reversible discharge capacity retains 758 mA h g-1 after 400 cycles at 0.2C. The excellent electrochemical properties benefit from the hollow structures and the flexible shells of the carbonized PPy spheres.

  8. Characterization of plasma chemistry and ion energy in cathodic arc plasma from Ti-Si cathodes of different compositions

    Energy Technology Data Exchange (ETDEWEB)

    Eriksson, A. O.; Zhirkov, I.; Dahlqvist, M.; Jensen, J.; Hultman, L.; Rosen, J. [Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linkoeping University, SE-581 83 Linkoeping (Sweden)

    2013-04-28

    Arc plasma from Ti-Si compound cathodes with up to 25 at. % Si was characterized in a DC arc system with respect to chemistry and charge-state-resolved ion energy. The plasma ion composition showed a lower Si content, diverging up to 12 at. % compared to the cathode composition, yet concurrently deposited films were in accordance with the cathode stoichiometry. Significant contribution to film growth from neutrals is inferred besides ions, since the contribution from macroparticles, estimated by scanning electron microscopy, cannot alone account for the compositional difference between cathode, plasma, and film. The average ion charge states for Ti and Si were higher than reference data for elemental cathodes. This result is likely related to TiSi{sub x} phases of higher cohesive energies in the compound cathodes and higher effective electron temperature in plasma formation. The ion energy distributions extended up to {approx}200 and {approx}130 eV for Ti and Si, respectively, with corresponding average energies of {approx}60 and {approx}30 eV. These averages were, however, not dependent on Si content in the cathode, except for 25 at. % Si where the average energies were increased up to 72 eV for Ti and 47 eV for Si.

  9. C3 as the dominant carbon cluster in high pressure discharges in graphite hollow cathodes

    Science.gov (United States)

    Janjua, Sohail Ahmad; Ahmad, Mashkoor; Khan, Sabih-ud-Din; Khalid, Rahila; Aleem, Abid; Ahmad, Shoaib

    2007-03-01

    Results are presented that have been obtained while operating the graphite hollow cathode duoplasmatron ion source in dual mode under constant discharge current. This dual mode operation enabled us to obtain the mass and emission spectra simultaneously. In mass spectra C3 is the main feature but C4 and C5 are also prominent, whereas in emission spectra C2 is also there and its presence shows that it is in an excited state rather than in an ionic state. These facts provide evidence that C3 is produced due to the regeneration of a soot forming sequence and leave it in ionic state. C3 is a stable molecule and the only dominant species among the carbon clusters that survives in a regenerative sooting environment at high-pressure discharges.

  10. Modelling of low-current self-generated oscillations in a hollow cathode discharge

    CERN Document Server

    Donko, Z

    1999-01-01

    Low-current self-generated oscillations in a rectangular hollow cathode discharge in helium gas were investigated experimentally and by means of a two-dimensional self-consistent hybrid model. The model combines Monte Carlo simulation of the motion of fast electrons and a fluid description of slow electrons and positive ions. The low-frequency (<=20 kHz) oscillations were found to arise as an effect of the interaction of the gas discharge and the external electric circuit - consisting of a stable voltage source, a series resistor and a capacitor formed by the discharge electrodes. Good agreement was found between the experimentally observed and calculated oscillation frequency and current wave forms. Beside these characteristics the modelling also made it possible to calculate the time dependence of numerous other discharge characteristics (e.g. electron multiplication, ion density, potential distribution) and provided detailed insight into the mechanism of oscillations. The advantage of the present model ...

  11. Spectroscopic determination of highly nonequilibrium velocity spectra of hydrogen atoms in H{sub 2} + Ne, Ar, Kr hollow-cathode discharges

    Energy Technology Data Exchange (ETDEWEB)

    Lavrov, B.P.; Mel`nikov, A.S. [St. Petersburg State Univ., Peterhof (Russian Federation)

    1995-12-01

    Energy distribution functions of excited (into the state with principal quantum number n = 3) and normal hydrogen atoms in plasma of a hollow-cathode discharge in an H{sub 2} + Ar mixture are determined in the range of 0-120 eV from Doppler profiles of spectral lines of the Balmer series. The distribution functions are found to be substantially nonequilibrium. The analysis of spectral profiles of H{sub {alpha}}lines in plasma of a high-volt-age hollow-cathode discharge in pure hydrogen shows that a part of the high-velocity excited hydrogen atoms is formed through charge exchange of negative H{sup {minus}} ions. Estimates show that the concentration of high-velocity H{sup {minus}} ions does not exceed several percent of the concentration of positive ions and increases with hydrogen pressure. Estimates of relative cross sections for excitation of hydrogen atoms to levels with n = 3, 4, and 5 in collisions of H atorns with H{sub 2} molecules are made. 18 refs., 3 figs., 1 tab.

  12. Non-Monotonicity of Excited State Populations Observed in a Cu-He Hollow Cathode Discharge

    Institute of Scientific and Technical Information of China (English)

    ZHENG Xu-Tao

    2005-01-01

    @@ An interesting non-monotonic structure in the distribution of excited state populations is observed in a Cu-He hollow cathode discharge, and this is explained by l-changing collisions of the excited states with background gas atoms. At helium pressure of 0.1 Torr and cathode current of 200-300mA, relative populations of He I 1snp 1p (n = 2-16) states are measured with the corresponding VUV radiation intensities, and are plotted against excitation energies. As energy levels increase, populations of high-n (n > 10) states are found to decrease much more quickly than low-n (n < 7) populations. For intermediate states (n = 7-10), the declining tendency is interfered by population transfers from 1sns 1 S states due to l-changing collisions, and an obvious non-monotonic structure is formed at relatively low electric current. Measurements have also been carried out for He Ⅱ np 2 p (n = 2-14) series, in which the l-changing collisions are overwhelmed by Stark quenching of the n2S states and thus population interference does not occur.

  13. Ultra short electron beam bunches from a laser plasma cathode

    Energy Technology Data Exchange (ETDEWEB)

    Maekawa, Akira [Nuclear Professional School, University of Tokyo, 2-22 Shirakata-Shirane, Tokai, Naka, Ibaraki 319-1188 (Japan)]. E-mail: maekawa@nuclear.jp; Tsujii, Ryosuke [Nuclear Professional School, University of Tokyo, 2-22 Shirakata-Shirane, Tokai, Naka, Ibaraki 319-1188 (Japan); Kinoshita, Kennichi [Nuclear Professional School, University of Tokyo, 2-22 Shirakata-Shirane, Tokai, Naka, Ibaraki 319-1188 (Japan); Atsushi, Yamazaki [Nuclear Professional School, University of Tokyo, 2-22 Shirakata-Shirane, Tokai, Naka, Ibaraki 319-1188 (Japan); Kobayashi, Kazuyuki [Nuclear Professional School, University of Tokyo, 2-22 Shirakata-Shirane, Tokai, Naka, Ibaraki 319-1188 (Japan); Uesaka, Mitsuru [Nuclear Professional School, University of Tokyo, 2-22 Shirakata-Shirane, Tokai, Naka, Ibaraki 319-1188 (Japan); Shibata, Yukio [Nuclear Professional School, University of Tokyo, 2-22 Shirakata-Shirane, Tokai, Naka, Ibaraki 319-1188 (Japan); Kondo, Yasuhiro [Nuclear Professional School, University of Tokyo, 2-22 Shirakata-Shirane, Tokai, Naka, Ibaraki 319-1188 (Japan); Ohkubo, Takeru [Takasaki Advanced Radiation Research Institute, Japan Atomic Energy Agency, 1233 Watanuki-machi, Takasaki, Gunma (Japan); Hosokai, Tomonao [Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo (Japan); Zhidkov, Alexei [Central Research Institute of Electric Power Industry, 2-6-1 Nagasaka, Yokosuka, Kanagawa (Japan); Takahashi, Toshiharu [Kyoto University Research Reactor Institute, Asahiro-nishi2, Kumatori, Sennan, Osaka (Japan)

    2007-08-15

    The fluctuation of the electron bunch duration due to energy spectrum instability in a laser plasma cathode has been examined. Previous experiments clearly proved that a laser plasma cathode can generate ultrashort electron bunches with a bunch duration of 130 fs (FWHM) and a geometrical emittance 0.07{pi} mm mrad. The effect of temporal elongation of electron bunches due to their energy spread is estimated and the results are in good agreement with previous experiments. It is also clarified that the instability of the energy spectrum not only leads to a fluctuation of the bunch shape but also to a time-of-flight jitter, affecting possible future applications of a laser plasma cathode.

  14. The effect of atomic oxygen for the hollow-cathode in a 20 mN class ion thruster

    OpenAIRE

    長野, 寛; 早川, 幸男; 稲永, 康隆; 尾崎, 敏之; 首藤, 和雄; NAGANO, Hiroshi; Hayakawa, Yukio; Inanaga, Yasutaka; Ozaki, Toshiyuki; Shuto, Kazuo

    2014-01-01

    The super-low earth orbits under the altitude of 250 km are very attractive for earth and atmospheric observation. JAXA plans to launch the first test satellite in super-low altitude called SLATS. Such satellites use ion thrusters to compensate for air drag and keep their altitude. However, there are a lot of atomic oxygen in super-low earth orbit. The dispenser cathodes generally show degradation by oxidation. Therefore, the effect of atomic oxygen for the hollow-cathode was evaluated here. ...

  15. NEW CATHODE MATERIALS FOR INERT AND OXIDIZING ATMOSPHERE PLASMA APPLICATION

    OpenAIRE

    1990-01-01

    This study has been carried out to develop new cathode materials for two types of thermionic cathode. First is concerning to the tungsten electrodes for the plasma furnace and welding torches. The second one is the electrodes for air plasma cutting torch. Tungsten electrodes activated with a single and combined additives of rare earth metal oxides, such as La2O3, Y2O3 and CeO2, are produced and pared with pure and thoriated tungsten electrode conventionally used, from the point of view of ele...

  16. 离子发动机空心阴极寿命预测%Lifetime forecast of hollow cathode for ion engine

    Institute of Scientific and Technical Information of China (English)

    郭宁; 江豪成; 顾佐

    2009-01-01

    To verify the lifetime of the hollow cathode for ion enging,a mathematic model was developed according to the characteristics of evaperation loss of the LaBs emitter in hollow cathode to forecast the lifetime of the hollow cathode.The results showed that the lifetime of the hollow cathode developed by the Lanzhou Institute of Physics (LIP) can over 40000hr with the rated thermionic current (5.00A).After a 3500hr lifetime test for the hollow cathode,of which the results were analyzed,the mathematic model for forecasting the lifetime of the hollow cathode was verified basically correct.%为验证空心阴极的寿命,本文根据空心阴极LaB6发射体的损耗特点,采用数学建模方法对空心阴极的寿命进行了预测.预测结果表明兰州物理研究所研制的空心阴极工作在额定状态下(发射电流5.00 A),其寿命可达到40000 h以上.3500 h寿命试验后空心阴极解剖分析结果初步验证了预测模型的正确性.

  17. Process for thermal imaging scanning of a swaged heater for an anode subassembly of a hollow cathode assembly

    Science.gov (United States)

    Patterson, Michael J. (Inventor); Verhey, Timothy R. R. (Inventor); Soulas, George C. (Inventor)

    2004-01-01

    A process for thermal imaging scanning of a swaged heater of an anode subassembly of a hollow cathode assembly, comprising scanning a swaged heater with a thermal imaging radiometer to measure a temperature distribution of the heater; raising the current in a power supply to increase the temperature of the swaged heater; and measuring the swaged heater temperature using the radiometer, whereupon the temperature distribution along the length of the heater shall be less than plus or minus 5 degrees C.

  18. On the role of secondary electrons in beam plasma generation inside a dielectric flask by fore-vacuum plasma-cathode electron source

    Science.gov (United States)

    Zolotukhin, D. B.; Burdovitsin, V. A.; Oks, E. M.

    2017-09-01

    The paper presents the results of experimental research and numerical simulation, demonstrating a considerable influence of secondary electrons on parameters of the beam-produced plasma generated at a pressure range of 1-13 Pa by injection of a continuous (with current of tens mA) electron beam into a dielectric (quartz) flask. An electron beam was formed by a fore-vacuum plasma-cathode electron source based on a hollow cathode discharge. The secondary electrons were emitted as a result of high-energy (3-8 keV) electron beam bombardment mainly a bottom end of the flask. These electrons provide an additional contribution to the ionization of the gas and also affect on the longitudinal distribution of the plasma density along the flask.

  19. Plasma gun with coaxial powder feed and adjustable cathode

    Science.gov (United States)

    Zaplatynsky, Isidor (Inventor)

    1991-01-01

    An improved plasma gun coaxially injects particles of ceramic materials having high melting temperatures into the central portion of a plasma jet. This results in a more uniform and higher temperature and velocity distribution of the sprayed particles. The position of the cathode is adjustable to facilitate optimization of the performance of the gun wherein grains of the ceramic material are melted at lower power input levels.

  20. Multicapillary cathode controlled by a ferroelectric plasma source

    Science.gov (United States)

    Gleizer, J. Z.; Hadas, Y.; Krasik, Ya. E.

    2008-06-01

    We present results of high-current microsecond and sub-microsecond duration electron beam generation in a ~200 kV diode with a multicapillary dielectric cathode (MCDC) assisted by a ferroelectric plasma source (FPS). Electron beam current densities are achieved up to 40 A/cm2. It was shown that the operation of the MCDC is determined by the parameters of the plasma flow generated by the FPS. Also, it was found that the high resistivity of the plasma produced inside the capillaries allows effective de-coupling of individual capillary plasma discharges which results in uniform electron beam generation.

  1. Ion energy distributions for the identification of active species and processes in low pressure hollow cathode discharges

    Energy Technology Data Exchange (ETDEWEB)

    Tanarro, I; Herrero, V J [Instituto de Estructura de la Materia, CSIC, Serrano 123, 28006 Madrid (Spain)], E-mail: itanarro@iem.cfmac.csic.es

    2009-08-15

    Energy distributions of ions generated in hollow cathode low pressures dc discharges of different gases and gas mixtures containing Ar, H{sub 2}, N{sub 2}, O{sub 2} or CH{sub 4} are studied by quadrupole mass spectrometry. The ions are sampled through a small diaphragm in the grounded cathode. The measured distributions are mostly determined by the acceleration of ions in the sheath region between the negative glow and the cathode, displaying in general a narrow peak centred at energies close to the anode potential, but with specific features for the distinct ions. It is shown that information about ion production and sheath collision processes can be derived from the shapes of the different energy distributions. In some cases these distributions are used for the estimation of the relative abundance of ions with the same mass/charge ratio but different compositions in complex gas mixtures.

  2. First results on Ge resonant laser photoionization in hollow cathode lamp

    Energy Technology Data Exchange (ETDEWEB)

    Scarpa, Daniele, E-mail: daniele.scarpa@lnl.infn.it; Andrighetto, Alberto [INFN-LNL, Viale Universita’ 2, Legnaro, 35020 Padova (Italy); Barzakh, Anatoly; Fedorov, Dmitry [Petersburg Nuclear Physics Institute (PNPI), NRC Kurchatov Institute, Gatchina 188300 (Russian Federation); Mariotti, Emilio [CNISM, University of Siena DSFTA, 53100 Siena (Italy); Nicolosi, Piergiorgio [Department Information Engineering, University of Padova, IFN-CNR UOF Padova, 35122 Padova (Italy); Tomaselli, Alessandra [Department of Electrical, Computer, and Biomedical Engineering, University of Pavia, 27100 Pavia (Italy)

    2016-02-15

    In the framework of the research and development activities of the SPES project regarding the optimization of the radioactive beam production, a dedicated experimental study has been recently started in order to investigate the possibility of in-source ionization of germanium using a set of tunable dye lasers. Germanium is one of the beams to be accelerated by the SPES ISOL facility, which is under construction at Legnaro INFN Laboratories. The three-step, two color ionization schemes have been tested using a Ge hollow cathode lamp. The slow and the fast optogalvanic signals were detected and averaged by an oscilloscope as a proof of the laser ionization inside the lamp. As a result, several wavelength scans across the resonances of ionization schemes were collected with the fast optogalvanic signal. Some comparisons of ionization efficiency for different ionization schemes were made. Furthermore, saturation curves of the first excitation transitions have been obtained. This investigation method and the setup built in the laser laboratory of the SPES project can be applied for the photo-ionization scheme studies also for the other possible radioactive elements.

  3. [Determination of soil available nutrient contents using multi-element hollow cathode lamp].

    Science.gov (United States)

    Lu, Shao-kun; He, Dong-xian; Hu, Juan-xiu; Wang, Yu-chang

    2011-07-01

    The soil available nutrient determination based on atomic absorption spectrometry using multi-element hollow cathode lamp (HCL) is improved from the instrument using single-element HCLs via modifying the software and hardware. As a test, available Cu, Fe, Zn, Mg and Ca contents of 30 fluvo-aquic soil samples measured by atomic absorption spectrometry using a multi-element HCL were compared with that measured by using single-element HCLs for 3 replications. A significant linear relationship with the slope close to 1 was found in soil available Cu, Fe, Zn and Ca contents measured by using multi-element HCL and single-element HCLs. The linear correlation coefficient of 0.86 and the slope of 0.85 were found in soil available Mg content. No significant difference was revealed from the above comparison data via analysis of variance. Therefore, the soil available nutrient determination based on atomic absorption spectrometry using multi-element HCL has the same measurement accuracy and is 50%-60% time-saving compared to that by using single-element HCLs.

  4. Three-dimensional interconnected cobalt oxide-carbon hollow spheres arrays as cathode materials for hybrid batteries

    Institute of Scientific and Technical Information of China (English)

    Jiye Zhan; Xinhui Xia n; Yu Zhong; Xiuli Wang; Jiangping Tu n

    2016-01-01

    Hierarchical porous metal oxides arrays is critical for development of advanced energy storage devices. Herein, we report a facile template-assisted electro-deposition plus glucose decomposition method for synthesis of multilayer CoO/C hollow spheres arrays. The CoO/C arrays consist of multilayer inter-connected hollow composite spheres with diameters of ∼350 nm as well as thin walls of ∼20 nm. Hierarchical hollow spheres architecture with 3D porous networks are achieved. As cathode of high-rate hybrid batteries, the multilayer CoO/C hollow sphere arrays exhibit impressive enhanced performances with a high capacity (73.5 mAh g?1 at 2 A g?1), and stable high-rate cycling life (70 mAh g?1 after 12,500 cycles at 2 A g?1). The improved electrochemical performance is owing to the composite hollow-sphere architecture with high contact area between the active materials and electrolyte as well as fast ion/electron transportation path.

  5. High-Frequency-Induced Cathodic Breakdown during Plasma Electrolytic Oxidation

    Science.gov (United States)

    Nominé, A.; Nominé, A. V.; Braithwaite, N. St. J.; Belmonte, T.; Henrion, G.

    2017-09-01

    The present communication shows the possibility of observing microdischarges under cathodic polarization during plasma electrolytic oxidation at high frequency. Cathodic microdischarges can ignite beyond a threshold frequency found close to 2 kHz. The presence (respectively, absence) of an electrical double layer is put forward to explain how the applied voltage can be screened, which therefore prevents (respectively, promotes) the ignition of a discharge. Interestingly, in the conditions of the present study, the electrical double layer requires between 175 and 260 μ s to form. This situates the expected threshold frequency between 1.92 and 2.86 kHz, which is in good agreement with the value obtained experimentally.

  6. Demonstration of the hollow channel plasma wakefield accelerator

    Energy Technology Data Exchange (ETDEWEB)

    Gessner, Spencer J.

    2016-09-17

    A plasma wakefield accelerator is a device that converts the energy of a relativistic particle beam into a large-amplitude wave in a plasma. The plasma wave, or wakefield, supports an enormous electricfield that is used to accelerate a trailing particle beam. The plasma wakefield accelerator can therefore be used as a transformer, transferring energy from a high-charge, low-energy particle beam into a high-energy, low-charge particle beam. This technique may lead to a new generation of ultra-compact, high-energy particle accelerators. The past decade has seen enormous progress in the field of plasma wakefield acceleration with experimental demonstrations of the acceleration of electron beams by several gigaelectron-volts. The acceleration of positron beams in plasma is more challenging, but also necessary for the creation of a high-energy electron-positron collider. Part of the challenge is that the plasma responds asymmetrically to electrons and positrons, leading to increased disruption of the positron beam. One solution to this problem, first proposed over twenty years ago, is to use a hollow channel plasma which symmetrizes the response of the plasma to beams of positive and negative charge, making it possible to accelerate positrons in plasma without disruption. In this thesis, we describe the theory relevant to our experiment and derive new results when needed. We discuss the development and implementation of special optical devices used to create long plasma channels. We demonstrate for the first time the generation of meter-scale plasma channels and the acceleration of positron beams therein.

  7. Plasma Cathode Electron Sources Physics, Technology, Applications

    CERN Document Server

    Oks, Efim

    2006-01-01

    This book fills the gap for a textbook describing this kind of electron beam source in a systematic and thorough manner: from physical processes of electron emission to examples of real plasma electron sources and their applications.

  8. Erosion behaviour of composite Al-Cr cathodes in cathodic arc plasmas in inert and reactive atmospheres

    CERN Document Server

    Franz, Robert; Hawranek, Gerhard; Polcik, Peter

    2015-01-01

    Al$_{x}$Cr$_{1-x}$ composite cathodes with Al contents of x = 0.75, 0.5 and 0.25 were exposed to cathodic arc plasmas in Ar, N$_2$ and O$_2$ atmospheres and their erosion behaviour was studied. Cross-sectional analysis of the elemental distribution of the near-surface zone in the cathodes by scanning electron microscopy revealed the formation of a modified layer for all cathodes and atmospheres. Due to intermixing of Al and Cr in the heat-affected zone, intermetallic Al-Cr phases formed as evidenced by X-ray diffraction analysis. Cathode poisoning effects in the reactive N$_2$ and O$_2$ atmospheres were non-uniform as a result of the applied magnetic field configuration. With the exception of oxide islands on Al-rich cathodes, reactive layers were absent in the circular erosion zone, while nitrides and oxides formed in the less eroded centre region of the cathodes.

  9. Investigation of cold cathodes of plasma sources generating of hydrogen ion beams

    CERN Document Server

    Veresov, L P; Dzkuya, M I; Zhukov, Y N; Kuznetsov, G V; Tsekvava, I A

    2001-01-01

    Designs of a hollow cellular cathode (HCC) and of an inverse cylindrical multichamber magnetronic cathode (ICMMC), used as cold cathodes in duoplasmatron for hydrogen ion beam generation, are described. Their service characteristics are compared. It is ascertained that emission ability of both HCC and ICMMC is approximately the same. However, duoplasmatron with ICMMC features a three times higher gas effectiveness compared with HCC. Service life of duoplasmatron with both types of cathodes amounts to several thousand hours. On the basis of test results the choice is made in favour of ICMMC

  10. A simplified 461-nm laser system using blue laser diodes and a hollow cathode lamp for laser cooling of Sr

    CERN Document Server

    Shimada, Yosuke; Ohtsubo, Nozomi; Aoki, Takatoshi; Torii, Yoshio

    2013-01-01

    We develop a simplified light source at 461 nm for laser cooling of Sr without frequency-doubling crystals but with blue laser diodes. An anti-reflection coated blue laser diode in an external cavity (Littrow) configuration provides an output power of 40 mW at 461 nm. Another blue laser diode is used to amplify the laser power up to 110 mW by injection locking. For frequency stabilization, we demonstrate modulation-free polarization spectroscopy of Sr in a hollow cathode lamp. The simplification of the laser system achieved in this work is of great importance for the construction of transportable optical lattice clocks.

  11. A simplified 461-nm laser system using blue laser diodes and a hollow cathode lamp for laser cooling of Sr.

    Science.gov (United States)

    Shimada, Yosuke; Chida, Yuko; Ohtsubo, Nozomi; Aoki, Takatoshi; Takeuchi, Makoto; Kuga, Takahiro; Torii, Yoshio

    2013-06-01

    We develop a simplified light source at 461 nm for laser cooling of Sr without frequency-doubling crystals but with blue laser diodes. An anti-reflection coated blue laser diode in an external cavity (Littrow) configuration provides an output power of 40 mW at 461 nm. Another blue laser diode is used to amplify the laser power up to 110 mW by injection locking. For frequency stabilization, we demonstrate modulation-free polarization spectroscopy of Sr in a hollow cathode lamp. The simplification of the laser system achieved in this work is of great importance for the construction of transportable optical lattice clocks.

  12. Reduction in plasma potential by applying negative DC cathode bias in RF magnetron sputtering

    Science.gov (United States)

    Isomura, Masao; Yamada, Toshinori; Osuga, Kosuke; Shindo, Haruo

    2016-11-01

    We applied a negative DC bias voltage to the cathode of an RF magnetron sputtering system and successfully reduced the plasma potential in both argon plasma and hydrogen-diluted argon plasma. The crystallinity of the deposited Ge films is improved by increasing the negative DC bias voltage. It is indicated that the reduction in plasma potential is effective for reducing the plasma damage on deposited materials, caused by the electric potential between the plasma and substrates. In addition, the deposition rate is increased by the increased electric potential between the plasma and the cathode owing to the negative DC bias voltage. The present method successfully gives us higher speed and lower damage sputtering deposition. The increased electric potential between the plasma and the cathode suppresses the evacuation of electrons from the plasma and also enhances the generation of secondary electrons on the cathode. These probably suppress the electron loss from the plasma and result in the reduction in plasma potential.

  13. Cold-cathode, pulsed-power plasma discharge switch

    Science.gov (United States)

    Goebel, Dan M.

    1996-09-01

    CROSSATRONTMmodulator switches are cold-cathode, grid-controlled, plasma-discharge devices that are used for thyratron and hard-tube replacement in high-voltage, pulsed-power applications. CROSSATRON modulator switches have been used to produce square pulses of up to 100 kV and 1000 A, and CROSSATRON laser-discharge switches have switched peak discharge currents of up to 10 kA at 40 kV. The major advantage that CROSSATRON switches offer over other plasma switches is a rapid deionization time that permits high pulse-repetition frequencies (103 to 106 pulses per second depending on the application), and a long life associated with the cold-cathode plasma production mechanism. Compared to hard tubes, CROSSATRON switches have a relatively low forward voltage drop (500 V), the ability to close and open up to 1 kA of peak current, and lower grid-drive power requirements. In this article, we describe the physical mechanisms for how the switch works based on simple models and experimental data. The design of CROSSATRON switches is explained, and characteristic performance in closing and opening applications is described and explained.

  14. Hollow-spherical Co/N-C nanoparticle as an efficient electrocatalyst used in air cathode microbial fuel cell.

    Science.gov (United States)

    Yang, Tingting; Li, Kexun; Pu, Liangtao; Liu, Ziqi; Ge, Baochao; Pan, Yajun; Liu, Ying

    2016-12-15

    The hollow-spherical Co/N-C nanoparticle, which is synthesized via a simple hydrothermal reaction followed by heat treatment, is firstly used as electrocatalyst for oxygen reduction reaction (ORR) in air-cathode microbial fuel cell (MFC). The maximum power density of MFC with 10% Co/N-C air-cathode is as high as 2514±59mWm(-2), which is almost 174% higher than the control. The exchange current density (i0) of cathode equipped with 10% Co/N-C is 238% higher than that of untreated AC. While the total resistance of treated samples decreases from 13.017 to 10.255Ω. The intensity ratio of Raman D to G band (ID/IG) decreases from 0.93 (N-C) to 0.73 (Co/N-C), indicating the catalyst forms graphite structure. Both XRD and XPS testify that Co is bonded to N within graphitic sheets and serves as the active sites in ORR. The four-electron pathway of the Co/N-C also plays a crucial role in electrochemical catalytic activity. As a result, it can be expected that the as-synthesized Co/N-C, with extraordinary electro-catalytic performance towards ORR, will be a promising alternative to the state-of-the-art non-precious metal ORR electro-catalysts for electrochemical energy applications.

  15. Biochemistry-directed hollow porous microspheres: bottom-up self-assembled polyanion-based cathodes for sodium ion batteries.

    Science.gov (United States)

    Lin, Bo; Li, Qiufeng; Liu, Baodong; Zhang, Sen; Deng, Chao

    2016-04-21

    Biochemistry-directed synthesis of functional nanomaterials has attracted great interest in energy storage, catalysis and other applications. The unique ability of biological systems to guide molecule self-assembling facilitates the construction of distinctive architectures with desirable physicochemical characteristics. Herein, we report a biochemistry-directed "bottom-up" approach to construct hollow porous microspheres of polyanion materials for sodium ion batteries. Two kinds of polyanions, i.e. Na3V2(PO4)3 and Na3.12Fe2.44(P2O7)2, are employed as cases in this study. The microalgae cell realizes the formation of a spherical "bottom" bio-precursor. Its tiny core is subjected to destruction and its tough shell tends to carbonize upon calcination, resulting in the hollow porous microspheres for the "top" product. The nanoscale crystals of the polyanion materials are tightly enwrapped by the highly-conductive framework in the hollow microsphere, resulting in the hierarchical nano-microstructure. The whole formation process is disclosed as a "bottom-up" mechanism. Moreover, the biochemistry-directed self-assembly process is confirmed to play a crucial role in the construction of the final architecture. Taking advantage of the well-defined hollow-microsphere architecture, the abundant interior voids and the highly-conductive framework, polyanion materials show favourable sodium-intercalation kinetics. Both materials are capable of high-rate long-term cycling. After five hundred cycles at 20 C and 10 C, Na3V2(PO4)3 and Na(3.12)Fe2.44(P2O7)2 retain 96.2% and 93.1% of the initial capacity, respectively. Therefore, the biochemistry-directed technique provides a low-cost, highly-efficient and widely applicable strategy to produce high-performance polyanion-based cathodes for sodium ion batteries.

  16. Scalable synthesis of Na3V2(PO4)(3)/C porous hollow spheres as a cathode for Na-ion batteries

    Energy Technology Data Exchange (ETDEWEB)

    Mao, JF; Luo, C; Gao, T; Fan, XL; Wang, CS

    2015-01-01

    Na3V2(PO4)(3) (NVP) has been considered as a very promising cathode material for sodium-ion batteries (SIBs) due to its typical NASICON structure, which provides an open and three dimensional (3D) framework for Na+ migration. However, the low electronic conductivity of NVP limits its rate capability and cycling ability. In this study, carbon coated hollow structured NVP/C composites are synthesized via a template-free and scalable ultrasonic spray pyrolysis process, where the carbon coated NVP particles are uniformly decorated on the inner and outer surfaces of the porous hollow carbon spheres. When evaluated as a cathode material for SIBs, the unique NVP/C porous hollow sphere cathode delivers an initial discharge capacity of 99.2 mA h g(-1) and retains 89.3 mA h g(-1) after 300 charge/discharge cycles with a very low degradation rate of 0.035% per cycle. For comparison, the NVP/C composite, prepared by the traditional sol-gel method, delivers a lower initial discharge capacity of 97.4 mA h g(-1) and decreases significantly to 71.5 mA h g(-1) after 300 cycles. The superior electrochemical performance of NVP/C porous hollow spheres is attributed to their unique porous, hollow and spherical structures, as well as the carbon-coating layer, which provides a high contact area between electrode/electrolyte, high electronic conductivity, and high mechanical strength.

  17. Single-Crystal MgO Hollow Nanospheres Formed in RF Impulse Discharge Plasmas

    Directory of Open Access Journals (Sweden)

    Satoru Iizuka

    2012-01-01

    Full Text Available Spherical MgO nanoparticles with a hollow inside, that is, MgO hollow nanospheres, were created in Ar/O2 plasma produced by radio frequency (RF impulse discharge using a Mg rod electrode. The hollow nanospheres were found on the SiO2 plates placed near the powered Mg electrode. The electron refraction pattern showed that each nanosphere was made of a single crystal of MgO. Since the shape was spherical, these nanoparticles seemed to be created during the levitation in the plasma without touching any walls. The formation mechanism with a quasiliquid cooling model was also discussed.

  18. Characteristics of Single Cathode Cascaded Bias Voltage Arc Plasma

    Science.gov (United States)

    Ou, Wei; Deng, Baiquan; Zeng, Xianjun; Gou, Fujun; Xue, Xiaoyan; Zhang, Weiwei; Cao, Xiaogang; Yang, Dangxiao; Cao, Zhi

    2016-06-01

    A single cathode with a cascaded bias voltage arc plasma source has been developed with a new quartz cathode chamber, instead of the previous copper chambers, to provide better diagnostic observation and access to the plasma optical emission. The cathode chamber cooling scheme is also modified to be naturally cooled only by light emission without cooling water to improve the optical thin performance in the optical path. A single-parameter physical model has been developed to describe the power dissipated in the cascaded bias voltage arc discharge argon plasmas, which have been investigated by utilizing optical emission spectroscopy (OES) and Langmuir probe. In the experiments, discharge currents from 50 A to 100 A, argon flow rates from 800 sccm to 2000 sccm and magnetic fields of 0.1 T and 0.2 T were chosen. The results show: (a) the relationship between the averaged resistivity and the averaged current density exhibits an empirical scaling law as \\barη \\propto \\bar {j}-0.63369 and the power dissipated in the arc has a strong relation with the filling factor; (b) through the quartz, the argon ions optical emission lines have been easily observed and are dominating with wavelengths between 340 nm and 520 nm, which are the emissions of Ar+-434.81 nm and Ar+-442.60 nm line, and the intensities are increasing with the arc current and decreasing with the inlet argon flow rate; and (c) the electron density and temperature can reach 2.0 × 1019 m-3 and 0.48 eV, respectively, under the conditions of an arc current of 90 A and a magnetic field of 0.2 T. The half-width of the ne radial profile is approximatively equal to a few Larmor radii of electrons and can be regarded as the diameter of the plasma jet in the experiments. supported by the International Thermonuclear Experimental Reactor (ITER) Program Special of Ministry of Science and Technology (No. 2013GB114003), and National Natural Science Foundation of China (Nos. 11275135, 11475122)

  19. Hollow-cathode electrode for high-power, high-pressure discharge devices

    Science.gov (United States)

    Chang, J.J.; Alger, T.W.

    1995-08-22

    Several different cold cathode configurations are disclosed for a gas discharge device each having a plurality of grooves of selected spacing, depth and width to improve the emission of electrons in a gas discharge device. Each of the cold cathode configurations can be machined from a single piece of a selected material. Several of the configurations can be assembled with individual elements which is easily seen from the various figures. 8 figs.

  20. C{sub 3} as the dominant carbon cluster in high pressure discharges in graphite hollow cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Janjua, Sohail Ahmad; Ahmad, Mashkoor; Khan, Sabih-ud-Din; Khalid, Rahila; Aleem, Abid; Ahmad, Shoaib [Carbon Based Nanotechnology and Accelerator Laboratory, PINSTECH, PO Box Nilore, Islamabad (Pakistan)

    2007-03-07

    Results are presented that have been obtained while operating the graphite hollow cathode duoplasmatron ion source in dual mode under constant discharge current. This dual mode operation enabled us to obtain the mass and emission spectra simultaneously. In mass spectra C{sub 3} is the main feature but C{sub 4} and C{sub 5} are also prominent, whereas in emission spectra C{sub 2} is also there and its presence shows that it is in an excited state rather than in an ionic state. These facts provide evidence that C{sub 3} is produced due to the regeneration of a soot forming sequence and leave it in ionic state. C{sub 3} is a stable molecule and the only dominant species among the carbon clusters that survives in a regenerative sooting environment at high-pressure discharges.

  1. Erosion behavior of composite Al-Cr cathodes in cathodic arc plasmas in inert and reactive atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Franz, Robert, E-mail: robert.franz@unileoben.ac.at; Mendez Martin, Francisca; Hawranek, Gerhard [Montanuniversität Leoben, Franz-Josef-Strasse 18, 8700 Leoben (Austria); Polcik, Peter [Plansee Composite Materials GmbH, Siebenbürgerstrasse 23, 86983 Lechbruck am See (Germany)

    2016-03-15

    Al{sub x}Cr{sub 1−x} composite cathodes with Al contents of x = 0.75, 0.5, and 0.25 were exposed to cathodic arc plasmas in Ar, N{sub 2}, and O{sub 2} atmospheres and their erosion behavior was studied. Cross-sectional analysis of the elemental distribution of the near-surface zone in the cathodes by scanning electron microscopy revealed the formation of a modified layer for all cathodes and atmospheres. Due to intermixing of Al and Cr in the heat-affected zone, intermetallic Al-Cr phases formed as evidenced by x-ray diffraction analysis. Cathode poisoning effects in the reactive N{sub 2} and O{sub 2} atmospheres were nonuniform as a result of the applied magnetic field configuration. With the exception of oxide islands on Al-rich cathodes, reactive layers were absent in the circular erosion zone, while nitrides and oxides formed in the less eroded center region of the cathodes.

  2. Characterization of a radio frequency hollow electrode discharge at low gas pressures

    Science.gov (United States)

    Ahadi, Amir Mohammad; Trottenberg, Thomas; Rehders, Stefan; Strunskus, Thomas; Kersten, Holger; Faupel, Franz

    2015-08-01

    A radio frequency (RF) hollow discharge configuration is presented, which makes use of a combination of RF plasma generation and the hollow cathode effect. The system was especially designed for the treatment of nanoparticles, plasma polymerization, and nanocomposite fabrication. The process gas streams through the plasma in the inner of the cylindrical electrode system. In the here presented measurements, pure argon and argon with oxygen admixtures are exemplarily used. The discharge is characterized by probe measurements in the effluent, electrical measurements of the discharge parameters, and visual observations of the plasma glow. It is found that the RF fluctuations of the plasma potential are weak. The plasma potential resembles the one of a DC hollow cathode discharge, the RF hollow electrode acts as a cathode due to the self-bias, and a high voltage sheath forms in its inner cylinder.

  3. Biochemistry-directed hollow porous microspheres: bottom-up self-assembled polyanion-based cathodes for sodium ion batteries

    Science.gov (United States)

    Lin, Bo; Li, Qiufeng; Liu, Baodong; Zhang, Sen; Deng, Chao

    2016-04-01

    Biochemistry-directed synthesis of functional nanomaterials has attracted great interest in energy storage, catalysis and other applications. The unique ability of biological systems to guide molecule self-assembling facilitates the construction of distinctive architectures with desirable physicochemical characteristics. Herein, we report a biochemistry-directed ``bottom-up'' approach to construct hollow porous microspheres of polyanion materials for sodium ion batteries. Two kinds of polyanions, i.e. Na3V2(PO4)3 and Na3.12Fe2.44(P2O7)2, are employed as cases in this study. The microalgae cell realizes the formation of a spherical ``bottom'' bio-precursor. Its tiny core is subjected to destruction and its tough shell tends to carbonize upon calcination, resulting in the hollow porous microspheres for the ``top'' product. The nanoscale crystals of the polyanion materials are tightly enwrapped by the highly-conductive framework in the hollow microsphere, resulting in the hierarchical nano-microstructure. The whole formation process is disclosed as a ``bottom-up'' mechanism. Moreover, the biochemistry-directed self-assembly process is confirmed to play a crucial role in the construction of the final architecture. Taking advantage of the well-defined hollow-microsphere architecture, the abundant interior voids and the highly-conductive framework, polyanion materials show favourable sodium-intercalation kinetics. Both materials are capable of high-rate long-term cycling. After five hundred cycles at 20 C and 10 C, Na3V2(PO4)3 and Na3.12Fe2.44(P2O7)2 retain 96.2% and 93.1% of the initial capacity, respectively. Therefore, the biochemistry-directed technique provides a low-cost, highly-efficient and widely applicable strategy to produce high-performance polyanion-based cathodes for sodium ion batteries.Biochemistry-directed synthesis of functional nanomaterials has attracted great interest in energy storage, catalysis and other applications. The unique ability of

  4. Development of realtime monitoring technology for laser photoreaction product - Study on spectroscopy of rare earth elements by using diode laser and hollow cathode glow discharge

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Sang Chun [Kyungnam University, Masan (Korea); Lee, Gea Ho [Chungnam National University, Taejon (Korea); Lee, Yong Il [Changwon National University, Changwon (Korea); Kim, Hyo Jin [Dongduk Women' s University, Seoul (Korea); Huh, Yong Dck [Dankook University, Seoul (Korea)

    1998-05-01

    Currently, fast and precise analysis of rare earth and actinide elements are much concerned and required for the safe treatments and storage of nuclear wastes generated by nuclear power plants. However, current technology is still far from the requirements for accurate realtime monitoring and measurement of radioactive elements. This project is of development of new technology of realtime monitoring and analysis of rare earth elements by using glow discharge and diode laser spectroscopy, and the study of spectroscopic characteristics of rare earth elements in glow discharge plasma. And, saturated absorption spectroscopy of rare earth elements was investigated with diode lasers. A see-through hollow cathode glow discharge (st-HCGD) cell was developed for the purpose of a portable atomizer and and its characteristics were investigated. High resolution spectroscopy was achieved with diode laser assisted saturated absorption spectroscopy. it is considered for major improvement of radioactive isotope detection technology. We expect a portable high resolution spectrometry with a see-through HCGD atomizer and diode lasers in near future. (Author). 63 refs., 39 figs., 7 tabs.

  5. Thermal and electrical influences from bulk plasma in cathode heating modeling

    Science.gov (United States)

    Chen, Tang; Wang, Cheng; Zhang, Xiao-Ning; Zhang, Hao; Xia, Wei-Dong

    2017-02-01

    In this paper, a numerical calculation is performed for the purpose of estimating the thermal and electrical influences from bulk plasma in cathode heating modeling, in other words researching the necessity of a coupling bulk plasma in near-cathode layer modeling. The proposed model applied in the present work is an improved one from previous work. In this model, the near-cathode region is divided into two parts: the sheath and the ionization layer. The Schottky effect at the cathode surface is considered based on the analytic solution of a 1D sheath model. It is noted that the arc column is calculated simultaneously in the near-cathode region and the cathode bulk. An application is presented for an atmospheric free burning argon arc with arc currents of 50 A-600 A. The modeling results show three interesting points: (1) at the cathode surface, energy transport due to heat conduction of heavy particles and electrons is comparable to total heating flux, no matter whether the arc discharge is performed in a high (400 A) or low current (50 A) situation; (2) the electrical influence from bulk plasma on the cathode heating modeling becomes obvious in a high current situation (>400 A) for the spot mode; (3) the near-cathode layer voltage drop ({{U}\\text{tot}} ) is larger in the diffuse mode than in the spot mode for the same current, which is just the opposite to that for decoupled modeling.

  6. Sulfur/graphitic hollow carbon sphere nano-composite as a cathode material for high-power lithium-sulfur battery.

    Science.gov (United States)

    Shin, Eon Sung; Kim, Min-Seop; Cho, Won Il; Oh, Si Hyoung

    2013-08-03

    The intrinsic low conductivity of sulfur which leads to a low performance at a high current rate is one of the most limiting factors for the commercialization of lithium-sulfur battery. Here, we present an easy and convenient method to synthesize a mono-dispersed hollow carbon sphere with a thin graphitic wall which can be utilized as a support with a good electrical conductivity for the preparation of sulfur/carbon nano-composite cathode. The hollow carbon sphere was prepared from the pyrolysis of the homogenous mixture of the mono-dispersed spherical silica and Fe-phthalocyanine powder in elevated temperature. The composite cathode was manufactured by infiltrating sulfur melt into the inner side of the graphitic wall. The electrochemical cycling shows a capacity of 425 mAh g-1 at 3 C current rate which is more than five times larger than that for the sulfur/carbon black nano-composite prepared by simple ball milling.

  7. Cathodic Cage Plasma Nitriding of Ti6Al4V Alloy

    OpenAIRE

    Ossowski, Maciej (OPI); Borowski, Tomasz; Michal TARNOWSKI; Tadeusz WIERZCHON

    2016-01-01

    Glow discharge nitriding is being used increasingly more often for modifying the properties of titanium and its alloys with the aim to increase their frictional wear resistance, fatigue strength, and, in the case of medical applications, to eliminate the metallosis effect. Unlike PVD methods, ion nitriding ensures the formation of diffusive layers with very good adhesion to the substrate, but which still have some disadvanteges such as the “edge effect” or “hollow cathode effect” which hinder...

  8. Synthesis and Electrochemical Property of LiMn2O4 Porous Hollow Nanofiber as Cathode for Lithium-Ion Batteries

    Science.gov (United States)

    Duan, Lianfeng; Zhang, Xueyu; Yue, Kaiqiang; Wu, Yue; Zhuang, Jian; Lü, Wei

    2017-02-01

    The LiMn2O4 hollow nanofibers with a porous structure have been synthesized by modified electrospinning techniques and subsequent thermal treatment. The precursors were electrospun directly onto the fluorine-doped tin oxide (FTO) glass. The heating rate and FTO as substrate play key roles on preparing porous hollow nanofiber. As cathode materials for lithium-ion batteries (LIBs), LiMn2O4 hollow nanofibers showed the high specific capacity of 125.9 mAh/g at 0.1 C and a stable cycling performance, 105.2 mAh/g after 400 cycles. This unique structure could relieve the structure expansion effectively and provide more reaction sites as well as shorten the diffusion path for Li+ for improving electrochemical performance for LIBs.

  9. Synthesis and Electrochemical Property of LiMn2O4 Porous Hollow Nanofiber as Cathode for Lithium-Ion Batteries.

    Science.gov (United States)

    Duan, Lianfeng; Zhang, Xueyu; Yue, Kaiqiang; Wu, Yue; Zhuang, Jian; Lü, Wei

    2017-12-01

    The LiMn2O4 hollow nanofibers with a porous structure have been synthesized by modified electrospinning techniques and subsequent thermal treatment. The precursors were electrospun directly onto the fluorine-doped tin oxide (FTO) glass. The heating rate and FTO as substrate play key roles on preparing porous hollow nanofiber. As cathode materials for lithium-ion batteries (LIBs), LiMn2O4 hollow nanofibers showed the high specific capacity of 125.9 mAh/g at 0.1 C and a stable cycling performance, 105.2 mAh/g after 400 cycles. This unique structure could relieve the structure expansion effectively and provide more reaction sites as well as shorten the diffusion path for Li(+) for improving electrochemical performance for LIBs.

  10. Preparation of Hollow Spherical and Core/shell Structured Powders by Plasma Processing

    Institute of Scientific and Technical Information of China (English)

    ZHANG; Xiaofeng; ZHOU; Kesong; DENG; Changguang; SONG; Jinbing; ZHANG; Jifu; DONG; Shujuan

    2015-01-01

    Four types of hollow spherical micro- and nano-szied powders of ZrO2-7wt.%Y2O3(7YSZ), ZrO2-7wt.%Y2O3, Al2O3-13 wt.% TiO2(AT) and WC as well as one type of core/shell structured powder of ZrB2-30 wt.%Mo Si2 were prepared via plasma processing. In addition, the formation mechanisms of hollow spherical and core/shell structured powders prepared via plasma processing were also proposed.

  11. Development and Experimental Operation of a Flashboard Plasma Cathode Test Stand

    Science.gov (United States)

    2012-06-01

    Bixier, M. Krishnan, and D. Huet, “Density measurements in flash board plasmas for a magnetically confined plasma opening switch ,” in Pulsed Power...of HPMWs ........................................................ 3  C.  BACKGROUND OF CATHODES AND THEIR LIMITATIONS ............ 6  1.  Thermionic ...HPM system ...... 4  Figure 2.  Illustration of a thermionic cathode in an electron gun (From [11]) ....... 6  Figure 3.  Photoelectric emission from

  12. Demonstration of a positron beam-driven hollow channel plasma wakefield accelerator.

    Science.gov (United States)

    Gessner, Spencer; Adli, Erik; Allen, James M; An, Weiming; Clarke, Christine I; Clayton, Chris E; Corde, Sebastien; Delahaye, J P; Frederico, Joel; Green, Selina Z; Hast, Carsten; Hogan, Mark J; Joshi, Chan; Lindstrøm, Carl A; Lipkowitz, Nate; Litos, Michael; Lu, Wei; Marsh, Kenneth A; Mori, Warren B; O'Shea, Brendan; Vafaei-Najafabadi, Navid; Walz, Dieter; Yakimenko, Vitaly; Yocky, Gerald

    2016-06-02

    Plasma wakefield accelerators have been used to accelerate electron and positron particle beams with gradients that are orders of magnitude larger than those achieved in conventional accelerators. In addition to being accelerated by the plasma wakefield, the beam particles also experience strong transverse forces that may disrupt the beam quality. Hollow plasma channels have been proposed as a technique for generating accelerating fields without transverse forces. Here we demonstrate a method for creating an extended hollow plasma channel and measure the wakefields created by an ultrarelativistic positron beam as it propagates through the channel. The plasma channel is created by directing a high-intensity laser pulse with a spatially modulated profile into lithium vapour, which results in an annular region of ionization. A peak decelerating field of 230 MeV m(-1) is inferred from changes in the beam energy spectrum, in good agreement with theory and particle-in-cell simulations.

  13. Demonstration of a positron beam-driven hollow channel plasma wakefield accelerator

    Science.gov (United States)

    Gessner, Spencer; Adli, Erik; Allen, James M.; An, Weiming; Clarke, Christine I.; Clayton, Chris E.; Corde, Sebastien; Delahaye, J. P.; Frederico, Joel; Green, Selina Z.; Hast, Carsten; Hogan, Mark J.; Joshi, Chan; Lindstrøm, Carl A.; Lipkowitz, Nate; Litos, Michael; Lu, Wei; Marsh, Kenneth A.; Mori, Warren B.; O'Shea, Brendan; Vafaei-Najafabadi, Navid; Walz, Dieter; Yakimenko, Vitaly; Yocky, Gerald

    2016-06-01

    Plasma wakefield accelerators have been used to accelerate electron and positron particle beams with gradients that are orders of magnitude larger than those achieved in conventional accelerators. In addition to being accelerated by the plasma wakefield, the beam particles also experience strong transverse forces that may disrupt the beam quality. Hollow plasma channels have been proposed as a technique for generating accelerating fields without transverse forces. Here we demonstrate a method for creating an extended hollow plasma channel and measure the wakefields created by an ultrarelativistic positron beam as it propagates through the channel. The plasma channel is created by directing a high-intensity laser pulse with a spatially modulated profile into lithium vapour, which results in an annular region of ionization. A peak decelerating field of 230 MeV m-1 is inferred from changes in the beam energy spectrum, in good agreement with theory and particle-in-cell simulations.

  14. Positron acceleration by plasma wake fields driven by a hollow electron beam

    CERN Document Server

    Jain, Neeraj; Palastro, J P

    2014-01-01

    A scheme of wake field generation for positron acceleration using hollow or donut shaped electron driver beams is studied. An annular shaped, electron free region forms around a hollow driver beam creating a favorable region (longitudinal field is accelerating and transverse field is focusing and radially linear) for positron acceleration. Accelerating gradients of the order of 10 GV/m are produced by a hollow electron beam driver with FACET like parameters. The peak accelerating field increases linearly with the total charge in the beam driver while the axial size of the favorable region ($\\sim$ one plasma wavelength) remains approximately fixed. The radial size drops with the total charge but remains large enough for the placement of a witness positron beam. We simulate an efficient acceleration of a 23 GeV positron beam to 35.4 GeV with a maximum energy spread of 0.4\\% and very small emittance over a plasma length of 140 cm.

  15. Morphology, Structure and Biodegradability of Hollow HA Microspheres Obtained by Plasma Spraying

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    The spraying-dried HA (ASD) was employed. ASD was plasma-sprayed onto ice to obtain hollow HA microspheres. The particle size of the sample was determined with a particle size analyzer. The morphology and structure of the samples were measured by scanning electron microscope and X-ray powder diffraction.The in vitro biodegradability of samples was evaluated by immersion tests in Ringer' s solution (RS) and simulated body fluid ( SBF). The samples were immersed respectively in RS and SBF for a period. The Ca2+ ion concentration in the solutions was determined by Atomic Adsorption Spectrum. By plasma spraying hollow HA microspheres were obtained. The hollow microspheres consisted mainly of low crystalline and amorphous HA, and had better biodegradability.

  16. Suspension Plasma Spray Fabrication of Nanocrystalline Titania Hollow Microspheres for Photocatalytic Applications

    Science.gov (United States)

    Ren, Kun; Liu, Yi; He, Xiaoyan; Li, Hua

    2015-10-01

    Hollow inorganic microspheres with controlled internal pores in close-cell configuration are usually constructed by submicron-sized particles. Fast and efficient large-scale production of the microspheres with tunable sizes yet remains challenging. Here, we report a suspension plasma spray route for making hollow microspheres from nano titania particles. The processing permits most nano particles to retain their physiochemical properties in the as-sprayed microspheres. The microspheres have controllable interior cavities and mesoporous shell of 1-3 μm in thickness. Spray parameters and organic content in the starting suspension play the key role in regulating the efficiency of accomplishing the hollow sphere structure. For the ease of collecting the spheres for recycling use, ferriferous oxide particles were used as additives to make Fe3O4-TiO2 hollow magnetic microspheres. The spheres can be easily recycled through external magnetic field collection after each time use. Photocatalytic anti-bacterial activities of the hollow spheres were assessed by examining their capability of degrading methylene blue and sterilizing Escherichia coli bacteria. Excellent photocatalytic performances were revealed for the hollow spheres, giving insight into their potential versatile applications.

  17. Plasma environment during hot cathode direct current discharge plasma chemical vapor deposition of diamond films

    Institute of Scientific and Technical Information of China (English)

    朱晓东; 詹如娟; 周海洋; 胡敏; 温晓辉; 周贵恩; 李凡庆

    1999-01-01

    The plasma characteristics have been investigated in situ by using optical emission spectroscopy (OES) and the Langmuir probe during hot cathode direct current discharge plasma chemical vapor deposition of diamond films. The changes of atomic H and CH radical in the ground state have been calculated quantitatively according to the results of OES and the Langmuir probe measurement as discharge current density varied. It is shown that atomic H and CH radicals both in the ground state and in the excited state increase with the enhancement of the discharge current density in the plasma. The electron density and CH emission intensity increase linearly with the enhancement of discharge current densities. The generation of different carbon-containing radicals is related to the elevation of electron temperature. Combining the growth process of diamond films and the diagnostic results, it is shown that atomic H in the excited state may improve the diamond growth efficiently, and the increase of electron temperat

  18. Seeding the m = 0 instability in dense plasma focus Z-pinches with a hollow anode

    CERN Document Server

    Liu, J X; McMahon, M; Tummel, K; Cooper, C; Higginson, D; Shaw, B; Povilus, A; Link, A; Schmidt, A

    2016-01-01

    The dense plasma focus (DPF) is a classic Z-pinch plasma device that has been studied for decades as a radiation source. The formation of the m = 0 plasma instability during the compression phase is linked to the generation of high-energy charged particle beams, which, when operated in deuterium, lead to beam-target fusion reactions and the generation of neutron yield. In this paper, we present a technique of seeding the m = 0 instability by employing a hollow in the anode. As the plasma sheath moves along the anode's hollow structure, a low density perturbation is formed and this creates a non-uniform plasma column which is highly unstable. Dynamics of the low density perturbation and preferential seeding of the m = 0 instability were studied in detail with fully kinetic plasma simulations performed in the Large Scale Plasma particle-in-cell code as well as with a simple snowplow model. The simulations showed that by employing an anode geometry with appropriate inner hollow radius, the neutron yield of the D...

  19. Diamond-like a-C:H coatings deposited in a non-self-sustained discharge with plasma cathode

    Science.gov (United States)

    Gavrilov, N. V.; Mamaev, A. S.; Kaĭigorodov, A. S.

    2009-01-01

    Hydrogenated amorphous carbon (a-C:H) coatings have been obtained by means of acetylene decomposition in a non-self-sustained periodic pulse discharge (2A, 50 kHz, 10 μs) with hollow cathode. The discharge operation was maintained by plasma cathode emission with grid stabilization based on dc glow discharge. Using the proposed method, it is possible to control the deposition conditions (total pressure of the Ar + C2H2 mixture, partial pressure of C2H2, ion current density, carbon ion energy) within broad limits, to apply a-C:H coatings onto large-area articles, and to perform deposition in one technological cycle with ion etching and ion implantation treatments aimed at improving the adhesion of coatings to substrates (Ti, Al, stainless steel, VK8 hard alloy) at temperatures below 150°C. Results of determining the deposition rate (1-8 μm), the nanohardness of coatings (up to 70 GPa), and the fraction of sp 3 bonds (25-70%) in the diamond-like coating material are presented.

  20. Integration issues of a plasma contactor Power Electronics Unit

    Science.gov (United States)

    Pinero, Luis R.; York, Kenneth W.; Bowers, Glen E.

    1995-06-01

    A hollow cathode-based plasma contactor is baselined on International Space Station Alpha (ISSA) for spacecraft charge control. The plasma contactor system consists of a hollow cathode assembly (HCA), a power electronics unit (PEU), and an expellant management unit (EMU). The plasma contactor has recently been required to operate in a cyclic mode to conserve xenon expellant and extend system life. Originally, a DC cathode heater converter was baselined for a continuous operation mode because only a few ignitions of the hollow cathode were expected. However, for cyclic operation, a DC heater supply can potentially result in hollow cathode heater component failure due to the DC electrostatic field. This can prevent the heater from attaining the proper cathode tip temperature for reliable ignition of the hollow cathode. To mitigate this problem, an AC cathode heater supply was therefore designed, fabricated, and installed into a modified PEU. The PEU was tested using resistive loads and then integrated with an engineering model hollow cathode to demonstrate stable steady-state operation. Integration issues such as the effect of line and load impedance on the output of the AC cathode heater supply and the characterization of the temperature profile of the heater under AC excitation were investigated.

  1. Integration issues of a plasma contactor Power Electronics Unit

    Science.gov (United States)

    Pinero, Luis R.; York, Kenneth W.; Bowers, Glen E.

    1995-01-01

    A hollow cathode-based plasma contactor is baselined on International Space Station Alpha (ISSA) for spacecraft charge control. The plasma contactor system consists of a hollow cathode assembly (HCA), a power electronics unit (PEU), and an expellant management unit (EMU). The plasma contactor has recently been required to operate in a cyclic mode to conserve xenon expellant and extend system life. Originally, a DC cathode heater converter was baselined for a continuous operation mode because only a few ignitions of the hollow cathode were expected. However, for cyclic operation, a DC heater supply can potentially result in hollow cathode heater component failure due to the DC electrostatic field. This can prevent the heater from attaining the proper cathode tip temperature for reliable ignition of the hollow cathode. To mitigate this problem, an AC cathode heater supply was therefore designed, fabricated, and installed into a modified PEU. The PEU was tested using resistive loads and then integrated with an engineering model hollow cathode to demonstrate stable steady-state operation. Integration issues such as the effect of line and load impedance on the output of the AC cathode heater supply and the characterization of the temperature profile of the heater under AC excitation were investigated.

  2. INFLUENCE OF VACUUM ARC PLASMA EVAPORATOR CATHODE GEOMETRY OF ON VALUE OF ADMISSIBLE ARC DISCHARGE CURRENT

    Directory of Open Access Journals (Sweden)

    I. A. Ivanou

    2015-01-01

    Full Text Available An analysis of main design parameters that determine a level of droplet formation intensity at the generating stage of plasma flow has been given in the paper. The paper considers the most widely used designs of water cooled consumable cathodes. Ti or Ti–Si and Fe–Cr alloys have been taken as a material for cathodes. The following calculated data: average ionic charge Zi for titanium plasma +1.6; for «titanium–silicon plasma» +1.2, an electronic discharge 1.6022 ⋅ 10–19 C, an ion velocity vi = 2 ⋅ 104 m/s, an effective volt energy equivalent of heat flow diverted in the cathode Uк = 12 V, temperature of erosion cathode surface Тп = 550 К; temperature of the cooled cathode surface То = 350 К have been accepted in order to determine dependence of a maximum admissible arc discharge current on cathode height. The calculations have been carried out for various values of the cathode heights hк (from 0.02 to 0.05 m. Diameter of a target cathode is equal to 0.08 m for a majority of technological plasma devices, therefore, the area of the erosion surface is S = 0.005 m2.A thickness selection for a consumable target cathode part in the vacuum arc plasma source has been justified in the paper. The thickness ensures formation of minimum drop phase in the plasma flow during arc cathode material evaporation. It has been shown that a maximum admissible current of an arc discharge is practically equal to the minimum current of stable arcing when thickness of the consumable cathode part is equal to 0.05 m. The admissible discharge current can be rather significant and ensure high productivity during coating process with formation of relatively low amount of droplet phase in the coating at small values of hк.

  3. Optimal positron-beam excited plasma wakefields in Hollow and Ion-Wake channels

    CERN Document Server

    Sahai, Aakash A

    2015-01-01

    A positron-beam interacting with the plasma electrons drives radial suck-in, in contrast to an electron-beam driven blow-out in the over-dense regime, $n_b>n_0$. In a homogeneous plasma, the electrons are radially sucked-in from all the different radii. The electrons collapsing from different radii do not simultaneously compress on-axis driving weak fields. A hollow-channel allows electrons from its channel-radius to collapse simultaneously exciting coherent fields. We analyze the optimal channel radius. Additionally, the low ion density in the hollow allows a larger region with focusing phase which we show is linearly focusing. We have shown the formation of an ion-wake channel behind a blow-out electron bubble-wake. Here we explore positron acceleration in the over-dense regime comparing an optimal hollow-plasma channel to the ion-wake channel. The condition for optimal hollow-channel radius is also compared. We also address the effects of a non-ideal ion-wake channel on positron-beam excited fields.

  4. [The comparative assessment of the wound-healing effects of the treatment with the use of Bioptron, Minitag, Orion+ apparatuses and hollow cathode lamps (experimental study)].

    Science.gov (United States)

    Sharipova, M M; Voronova, S N; Rukin, E M; Vasilenko, A M

    2011-01-01

    The objective of the present experimental study was the comparative assessment of the wound-healing effects of radiation emitted from Bioptron, Minitag, Orion+ apparatuses and hollow cathode lamps (HCL). The emitters of any type were shown to be equally efficacious in that they accelerated wound epithelization by 30% on the average compared with control. Based on the difference between spectral and power characteristics of different sources of radiation and dynamics of their wound-healing efficacy (including that of two types of HCL), the authors arrived at the conclusion that the further development of the proposed approach to wound healing is a promising line of research in the field of spectral phototherapy.

  5. The evolution of ion charge states in cathodic vacuum arc plasmas: a review

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre

    2011-12-18

    Cathodic vacuum arc plasmas are known to contain multiply charged ions. 20 years after “Pressure Ionization: its role in metal vapour vacuum arc plasmas and ion sources” appeared in vol. 1 of Plasma Sources Science and Technology, it is a great opportunity to re-visit the issue of pressure ionization, a non-ideal plasma effect, and put it in perspective to the many other factors that influence observable charge state distributions, such as the role of the cathode material, the path in the density-temperature phase diagram, the “noise” in vacuum arc plasma as described by a fractal model approach, the effects of external magnetic fields and charge exchange collisions with neutrals. A much more complex image of the vacuum arc plasma emerges putting decades of experimentation and modeling in perspective.

  6. Estimation of dynamic properties of attractors observed in hollow copper electrode atmospheric pressure arc plasma system

    Indian Academy of Sciences (India)

    S Ghorul; S N Sahasrabudhe; P S S Murthy; A K Das; N Venkatramani

    2002-07-01

    Understanding of the basic nature of arc root fluctuation is still one of the unsolved problems in thermal arc plasma physics. It has direct impact on myriads of thermal plasma applications being implemented at present. Recently, chaotic nature of arc root behavior has been reported through the analysis of voltages, acoustic and optical signals which are generated from a hollow copper electrode arc plasma torch. In this paper we present details of computations involved in the estimation process of various dynamic properties and show how they reflect chaotic behavior of arc root in the system.

  7. Modeling a short cold cathode DC discharge device with controllable plasma parameters

    Science.gov (United States)

    Kudryavtsev, Anatoly; Adams, Steven; Demidov, Vladimir; Bogdanov, Yevgeny

    2009-11-01

    A short (without positive column) DC gas-discharge device with a cold cathode has been modeled. The device consists of the plane disk-shaped cathode and anode while the inter-electrode gap is bounded by a cylindrical wall. The cathode and anode are each 2.5 cm in diameter, and the inter-electrode gap is 12 mm. The wall is made of conducting parts divided by an insulator. The modeling has been performed for argon plasma at 1 Torr pressure. It is demonstrated in the model that spatial distributions of electron density and temperature and argon metastable atom density depend on the DC voltage applied to different conducting parts of the wall. Applied voltage can trap within the device volume energetic electrons arising from atomic and molecular processes in the plasma. This leads to a modification in the heating of slow electrons by energetic electrons and as a result modifies the controlling plasma parameters.

  8. High quality electron beam generation in a proton-driven hollow plasma wakefield accelerator

    CERN Document Server

    Li, Yangmei; Lotov, Konstantin V; Sosedkin, Alexander P; Hanahoe, Kieran; Mete-Apsimon, Oznur

    2016-01-01

    Proton-driven plasma wakefield accelerators have numerically demonstrated substantially higher accelerating gradients compared to conventional accelerators and the viability of accelerating electrons to energy frontier in a single plasma stage. However, due to the intrinsic strong and radially varying transverse fields, the beam quality is still far from suitable for practical application in future colliders. Here we propose a new accelerating region which is free from both plasma electrons and ions in the proton-driven hollow plasma channel. The high quality electron beam is therefore generated with this scheme without transverse plasma fields. The results show that a 1 TeV proton driver can propagate and accelerate an electron beam to 0.62 TeV with correlated energy spread of 4.6% and well-preserved normalized emittance below 2.4 mm mrad in a single hollow plasma channel of 700 m. More importantly, the beam loading tolerance is significantly improved compared to the uniform plasma case. This high quality an...

  9. Efficient small molecular organic light emitting diode with graphene cathode covered by a Sm layer with nano-hollows and n-doped by Bphen:Cs2CO3 in the hollows.

    Science.gov (United States)

    Yao, Li; Li, Lei; Qin, Laixiang; Ma, Yaoguang; Wang, Wei; Meng, Hu; Jin, Weifeng; Wang, Yilun; Xu, Wanjin; Ran, Guangzhao; You, Liping; Qin, Guogang

    2017-03-10

    Graphene is a favorable candidate for electrodes of organic light emitting diodes (OLEDs). Graphene has quite a high work function of ∼4.5 eV, and has been extensively studied when used as anodes of OLEDs. In order to use graphene as a cathode, the electron injection barrier between the graphene cathode and the electron transport layer has to be low enough. Using 4,7-diphenyl-1,10-phenanthroline (Bphen):Cs2CO3 to n-dope graphene is a very good method, but the electron injection barrier between the n-doped graphene and Bphen:Cs2CO3 is still too high to be ∼1.0 eV. In this work, in order to further reduce the electron injection barrier, a novel method is suggested. On the graphene cathode, a Sm layer with a lot of nano-hollows, and subsequently a layer of Bphen:Cs2CO3, are deposited. The Bphen:Cs2CO3 can n-dope graphene in the nano-hollows, and the Fermi level of the graphene rises. The nano Sm layer is very easily oxidized. Oxygen adsorbed on the surface of graphene may react with Sm to form an O(-)-Sm(+) dipole layer. On the areas of the Sm oxide dipole layer without nano-hollows, the electron injection barrier can be further lowered by the dipole layer. Electrons tend to mainly inject through the lower electron barrier where the dipole layer exists. Based on this idea, an effective inverted small molecular OLED with the structure of graphene/1 nm Sm layer with a lot of nano-hollows/Bphen:Cs2CO3/Alq3:C545T/NPB/MoO3/Al is presented. The maximum current efficiency and maximum power efficiency of the OLED with a 1 nm Sm layer are about two and three times of those of the reference OLED without any Sm layer, respectively.

  10. Efficient small molecular organic light emitting diode with graphene cathode covered by a Sm layer with nano-hollows and n-doped by Bphen:Cs2CO3 in the hollows

    Science.gov (United States)

    Yao, Li; Li, Lei; Qin, Laixiang; Ma, Yaoguang; Wang, Wei; Meng, Hu; Jin, Weifeng; Wang, Yilun; Xu, Wanjin; Ran, Guangzhao; You, Liping; Qin, Guogang

    2017-03-01

    Graphene is a favorable candidate for electrodes of organic light emitting diodes (OLEDs). Graphene has quite a high work function of ∼4.5 eV, and has been extensively studied when used as anodes of OLEDs. In order to use graphene as a cathode, the electron injection barrier between the graphene cathode and the electron transport layer has to be low enough. Using 4,7-diphenyl-1,10-phenanthroline (Bphen):Cs2CO3 to n-dope graphene is a very good method, but the electron injection barrier between the n-doped graphene and Bphen:Cs2CO3 is still too high to be ∼1.0 eV. In this work, in order to further reduce the electron injection barrier, a novel method is suggested. On the graphene cathode, a Sm layer with a lot of nano-hollows, and subsequently a layer of Bphen:Cs2CO3, are deposited. The Bphen:Cs2CO3 can n-dope graphene in the nano-hollows, and the Fermi level of the graphene rises. The nano Sm layer is very easily oxidized. Oxygen adsorbed on the surface of graphene may react with Sm to form an O‑–Sm+ dipole layer. On the areas of the Sm oxide dipole layer without nano-hollows, the electron injection barrier can be further lowered by the dipole layer. Electrons tend to mainly inject through the lower electron barrier where the dipole layer exists. Based on this idea, an effective inverted small molecular OLED with the structure of graphene/1 nm Sm layer with a lot of nano-hollows/Bphen:Cs2CO3/Alq3:C545T/NPB/MoO3/Al is presented. The maximum current efficiency and maximum power efficiency of the OLED with a 1 nm Sm layer are about two and three times of those of the reference OLED without any Sm layer, respectively.

  11. Hollow silicon carbide nanoparticles from a non-thermal plasma process

    Science.gov (United States)

    Coleman, Devin; Lopez, Thomas; Yasar-Inceoglu, Ozgul; Mangolini, Lorenzo

    2015-05-01

    We demonstrate the synthesis of hollow silicon carbide nanoparticles via a two-step process involving the non-thermal plasma synthesis of silicon nanoparticles, followed by their in-flight carbonization, also initiated by a non-thermal plasma. Simple geometric considerations associated with the expansion of the silicon lattice upon carbonization, in combination of the spherical geometry of the system, explain the formation of hollow nanostructures. This is in contrast with previous reports that justify the formation of hollow particles by means of out-diffusion of the core element, i.e., by the Kirkendall nanoscale effect. A theoretical analysis of the diffusion kinetics indicates that interaction with the ionized gas induces significant nanoparticle heating, allowing for the fast transport of carbon into the silicon particle and for the subsequent nucleation of the beta-silicon carbide phase. This work confirms the potential of non-thermal plasma processes for the synthesis of nanostructures composed of high-melting point materials, and suggests that such processes can be tuned to achieve morphological control.

  12. Performance of the FOS and GHRS Pt/(Cr)-Ne Hollow-cathode Lamps after their Return from Space and Comparison with Archival Data

    Science.gov (United States)

    Kerber, Florian; Lindler, Don; Bristow, Paul; Lembke, Dominik; Nave, Gillian; Reader, Joseph; Sansonetti, Craig J.; Heap, Sara R.; Rosa, Michael R.; Wood, H. John

    2006-01-01

    The Space Telescope European Coordinating Facility (ST-ECF) and National Institute of Standards and Technology (NIST) are collaborating to study hollow cathode calibration lamps as used onboard the Hubble Space Telescope (HST). As part of the STIS Calibration Enhancement (STIS-CE) Project we are trying to improve our understanding of the performance of hollow cathode lamps and the physical processes involved in their long term operation. The original flight lamps from the Faint Object Spectrograph (FOS) and the Goddard High Resolution Spectrograph (GHRS) are the only lamps that have ever been returned to Earth after extended operation in space. We have taken spectra of all four lamps using NIST s 10.7-m normal-incidence spectrograph and Fourier transform spectrometer (FTS) optimized for use in the ultraviolet (UV). These spectra, together with spectra archived from six years of on-orbit operations and pre-launch spectra, provide a unique data set - covering a period of about 20 years - for studying aging effects in these lamps. Our findings represent important lessons for the choice and design of calibration sources and their operation in future UV and optical spectrographs in space.

  13. Solvothermal synthesis of monodisperse LiFePO4 micro hollow spheres as high performance cathode material for lithium ion batteries.

    Science.gov (United States)

    Yang, Shiliu; Hu, Mingjun; Xi, Liujiang; Ma, Ruguang; Dong, Yucheng; Chung, C Y

    2013-09-25

    A microspherical, hollow LiFePO4 (LFP) cathode material with polycrystal structure was simply synthesized by a solvothermal method using spherical Li3PO4 as the self-sacrificed template and FeCl2·4H2O as the Fe(2+) source. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) show that the LFP micro hollow spheres have a quite uniform size of ~1 μm consisting of aggregated nanoparticles. The influences of solvent and Fe(2+) source on the phase and morphology of the final product were chiefly investigated, and a direct ion exchange reaction between spherical Li3PO4 templates and Fe(2+) ions was firstly proposed on the basis of the X-ray powder diffraction (XRD) transformation of the products. The LFP nanoparticles in the micro hollow spheres could finely coat a uniform carbon layer ~3.5 nm by a glucose solution impregnating-drying-sintering process. The electrochemical measurements show that the carbon coated LFP materials could exhibit high charge-discharge capacities of 158, 144, 125, 101, and even 72 mAh g(-1) at 0.1, 1, 5, 20, and 50 C, respectively. It could also maintain 80% of the initial discharge capacity after cycling for 2000 times at 20 C.

  14. Soliton-plasma nonlinear dynamics in mid-IR gas-filled hollow-core fibers

    DEFF Research Database (Denmark)

    Habib, Selim; Markos, Christos; Bang, Ole

    2017-01-01

    We investigate numerically soliton-plasma interaction in a noble-gas-filled silica hollow-core anti-resonant fiber pumped in the mid-IR at 3.0 mu m. We observe multiple soliton self-compression stages due to distinct stages where either the self-focusing or the self-defocusing nonlinearity...... dominates. Specifically, the parameters may be tuned so the competing plasma self-defocusing nonlinearity only dominates over the Kerr self-focusing nonlinearity around the soliton self-compression stage, where the increasing peak intensity on the leading pulse edge initiates a competing self...

  15. Microwave-driven plasmas in Hollow-Core Photonic Crystal Fibres

    Science.gov (United States)

    Alves, L. L.; Leroy, O.; Boisse-Laporte, C.; Leprince, P.; Debord, B.; Gerome, F.; Jamier, R.; Benabid, F.

    2013-09-01

    This paper reports on a novel solution to ignite and maintain micro-plasmas in gas-filled Hollow-Core Photonic Crystal Fibres (HC-PCFs), using CW microwave excitation (2.45 GHz). The original concept is based on a surfatron, generating argon micro-plasmas of few centimetres in length within a 100 μm core-diameter Kagome HC-PCF, at ~1 mbar on-gap gas-pressure using low powers (core diameter, pressure and electron density). Work supported by ANR and DGA (ASTRID-2011-UVfactor) and by FCT (Pest-OE/SADG/LA0010/2011).

  16. Cathode configuration influence on low-inductance vacuum spark plasma dynamics

    Science.gov (United States)

    Sarantsev, S. A.; Dvoeglazov, Ya M.; Dodulad, E. I.; Raevsky, I. F.; Savjolov, A. S.

    2016-09-01

    The results of studies of cathode configuration influence on high current low- inductance vacuum spark (HLVS) plasma dynamics are presented in this work. The research was carried out on “PION” installation using shadowgraphy method. Molecular nitrogen laser (λ = 337 nm) was used as a radiation source. It was determined that the HLVS behavior changes with the increase of number of discharges. In a fresh electrode system (less than 200 discharges) the dependence of constriction position on the discharge trigger position is observed during HLVS development. Also, high gradients of plasma density and secondary constrictions are observed. In a previously exploited electrode system (more than 300 discharges) HLVS behavior changes: plasma density gradients become less expressed, secondary constrictions disappear. In electrode systems with highly developed cathode surface plasma density gradient distribution pattern only slightly changes from discharge to discharge, e.g. the discharge becomes more stable.

  17. Application of electron beam equipment based on a plasma cathode gun in additive technology

    Science.gov (United States)

    Galchenko, N. K.; Kolesnikova, K. A.; Semenov, G. V.; Rau, A. G.; Raskoshniy, S. Y.; Bezzubko, A. V.; Dampilon, B. V.; Sorokova, S. N.

    2016-11-01

    The paper discusses the application of electron beam equipment based on a plasma cathode gun for three-dimensional surface modification of metals and alloys. The effect of substrate surface preparation on the adhesion strength of gas thermal coatings has been investigated.

  18. Observation of Quartz Cathode-Luminescence in a Low Pressure Plasma Discharge

    Science.gov (United States)

    Foster, John E.

    2004-01-01

    Intense, steady-state cathode-luminescence has been observed from exposure of quartz powder to a low pressure rf-excited argon plasma discharge. The emission spectra (400 to 850 nm) associated with the powder luminescence were documented as a function of bias voltage using a spectrometer. The emission was broad-band, essentially washing out the line spectra features of the argon plasma discharge.

  19. A simple sample preparation method for measuring amoxicillin in human plasma by hollow fiber centrifugal ultrafiltration.

    Science.gov (United States)

    Dong, Wei-Chong; Hou, Zi-Li; Jiang, Xin-Hui; Jiang, Ye

    2013-02-01

    A simple sample preparation method has been developed for the determination of amoxicillin in human plasma by hollow fiber centrifugal ultrafiltration (HF-CF-UF). A 400-μL plasma sample was placed directly into the HF-CF-UF device, which consisited of a slim glass tube and a U-shaped hollow fiber. After centrifugation at 1.25 × 10(3) g for 10 min, the filtrate was withdrawn from the hollow fiber and 20 µL was directly injected into the high-performance liquid chromatography (HPLC) for analysis. The calibration curve was linear over the range of 0.1-20 µg/mL (r = 0.9996) and the limit of detection was as low as 0.025 µg/mL. The average recovery and absolute recovery were 99.9% and 84.5%, respectively. Both the intra-day and inter-day precisions (relative standard deviation) were less than 3.1% for three concentrations (0.25, 2.5 and 10 µg/mL). The sample preparation process was simplified. Only after a single centrifugal ultrafiltration can the filtrate be injected directly into HPLC. The present method is simple, sensitive and accurate. It could be effective for the analysis of biological samples with high protein contents, especially for the biopharmaceutical analysis of drugs that use traditional isolation techniques for sample preparation such as the protein precipitation method.

  20. Vacuum arc with a distributed cathode spot as a plasma source for plasma separation of spent nuclear fuel and radioactive waste

    Energy Technology Data Exchange (ETDEWEB)

    Amirov, R. Kh., E-mail: ravus46@yandex.ru; Vorona, N. A.; Gavrikov, A. V.; Lizyakin, G. D.; Polishchuk, V. P.; Samoilov, I. S.; Smirnov, V. P.; Usmanov, R. A.; Yartsev, I. M. [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation)

    2015-10-15

    Results from experimental studies of a vacuum arc with a distributed cathode spot on the heated cathode are presented. Such an arc can be used as a plasma source for plasma separation of spent nuclear fuel and radioactive waste. The experiments were performed with a gadolinium cathode, the properties of which are similar to those of an uranium arc cathode. The heat flux from the plasma to the cathode (and its volt equivalent) at discharge voltages of 4-15 V and discharge currents of 44-81 A, the radial distribution of the emission intensity of gadolinium atoms and singly charged ions in the arc channel at a voltage of 4.3 V, and the plasma electron temperature behind the anode were measured. The average charge of plasma ions at arc voltages of 3.5-8 V and a discharge current of 52 A and the average rate of gadolinium evaporation in the discharge were also determined.

  1. La2NiO4+δ Infiltration of Plasma-Sprayed LSCF Coating for Cathode Performance Improvement

    Science.gov (United States)

    Li, Ying; Zhang, Shan-Lin; Li, Cheng-Xin; Wei, Tao; Yang, Guan-Jun; Li, Chang-Jiu; Liu, Meilin

    2016-01-01

    Perovskite-structured (La0.6Sr0.4Co0.2Fe0.8O3) LSCF has been widely studied as a cathode material for intermediate-temperature solid oxide fuel cells. However, the application of LSCF cathode is likely to be limited by its sluggish surface catalytic properties and long-term stability issues. Oxygen hyper-stoichiometric La2NiO4+δ with K2NiF4 structure exhibits higher catalytic properties, ionic conductivity, and stability in comparison with LSCF cathode. Due to the good chemical compatibility of these two cathode materials, it is possible to prepare a composite cathode by the infiltration of La2NiO4+δ in the porous LSCF. This composite structure fully utilizes the advantages of the two cathodes and enhances the LSCF cathode performance. In this study, the LSCF cathode was deposited by using an atmospheric plasma spray technique, and the porous LSCF cathode was then infiltrated by La2NiO4+δ. The atmospheric plasma spray technique was used to reduce the SOFC manufacturing cost. The microstructure of coatings was characterized by SEM and EDS. The cathode polarization resistance was found to decrease by ~40% after the La2NiO4+δ infiltration. Also, the activation energy decreased from 1.53 to 1.40 eV.

  2. The evidence of cathodic micro-discharges during plasma electrolytic oxidation process

    Energy Technology Data Exchange (ETDEWEB)

    Nominé, A., E-mail: alexandre.nomine@univ-lorraine.fr [Institut Jean Lamour, UMR 7198 CNRS, Université de Lorraine, Parc de Saurupt, 54011 Nancy (France); National Institute of Science and Technology “MISiS,” 4, Leninskij Prospekt, Moscow 119049 (Russian Federation); Martin, J.; Noël, C.; Henrion, G.; Belmonte, T. [Institut Jean Lamour, UMR 7198 CNRS, Université de Lorraine, Parc de Saurupt, 54011 Nancy (France); Bardin, I. V.; Kovalev, V. L.; Rakoch, A. G. [National Institute of Science and Technology “MISiS,” 4, Leninskij Prospekt, Moscow 119049 (Russian Federation)

    2014-02-24

    Plasma electrolytic oxidation (PEO) processing of EV31 magnesium alloy has been carried out in fluoride containing electrolyte under bipolar pulse current regime. Unusual PEO cathodic micro-discharges have been observed and investigated. It is shown that the cathodic micro-discharges exhibit a collective intermittent behavior, which is discussed in terms of charge accumulations at the layer/electrolyte and layer/metal interfaces. Optical emission spectroscopy is used to determine the electron density (typ. 10{sup 15} cm{sup −3}) and the electron temperature (typ. 7500 K) while the role of F{sup −} anions on the appearance of cathodic micro-discharges is pointed out.

  3. Linear to non linear analysis for positron acceleration in plasma hollow channel wakefields

    Science.gov (United States)

    Amorim, Ligia Diana; An, Weiming; Mori, Warren B.; Vieira, Jorge

    2016-10-01

    Plasma wakefield accelerators are promising candidates for future generation compact accelerators. The standard regime of operation, non-linear or blowout regime, is reached when a particle bunch space charge or laser pulse ponderomotive force radially expels plasma electrons forming a bucket of ions that defocus positron bunches, thus preventing their acceleration. To avoid defocusing, hollow plasma channels have been considered. The corresponding wakefields have been examined in the linear and non-linear excitation regimes for electrons. It is therefore important to extend the theory for positron acceleration, particularly in the nonlinear regime where the wakefields strongly differ. In this work we explore the wakefield structure, examine the differences between the electron and positron beam cases, and explore positron acceleration in nonlinear regimes. We support our findings with multi-dimensional particle-in-cell simulations performed with OSIRIS and quasi-3D and QuickPIC.

  4. Crunch-in regime - Non-linearly driven hollow-channel plasma

    CERN Document Server

    Sahai, Aakash A

    2016-01-01

    Plasma wakefields driven inside a hollow-channel plasma are significantly different from those driven in a homogeneous plasma. This work investigates the scaling laws of the accelerating and focusing fields in the "crunch-in" regime. This regime is excited due to the collapse of the electron-rings from the channel walls onto the propagation axis of the energy-source, in its wake. This regime is thus the non-linearly driven hollow channel, since the electron-ring displacement is of the order of the channel radius. We present the properties of the coherent structures in the "crunch-in" regime where the channel radius is matched to the beam properties such that channel-edge to on-axis collapse time has a direct correspondence to the energy source intensity. We also investigate the physical mechanisms that underlie the "crunch-in" wakefields by tuning the channel radius. Using a theoretical framework and results from PIC simulations the possible applications of the "crunch-in" regime for acceleration of positron ...

  5. Fluid and gyrokinetic modelling of particle transport in plasmas with hollow density profiles

    Science.gov (United States)

    Tegnered, D.; Oberparleiter, M.; Nordman, H.; Strand, P.

    2016-11-01

    Hollow density profiles occur in connection with pellet fuelling and L to H transitions. A positive density gradient could potentially stabilize the turbulence or change the relation between convective and diffusive fluxes, thereby reducing the turbulent transport of particles towards the center, making the fuelling scheme inefficient. In the present work, the particle transport driven by ITG/TE mode turbulence in regions of hollow density profiles is studied by fluid as well as gyrokinetic simulations. The fluid model used, an extended version of the Weiland transport model, Extended Drift Wave Model (EDWM), incorporates an arbitrary number of ion species in a multi-fluid description, and an extended wavelength spectrum. The fluid model, which is fast and hence suitable for use in predictive simulations, is compared to gyrokinetic simulations using the code GENE. Typical tokamak parameters are used based on the Cyclone Base Case. Parameter scans in key plasma parameters like plasma β, R/LT , and magnetic shear are investigated. It is found that β in particular has a stabilizing effect in the negative R/Ln region, both nonlinear GENE and EDWM show a decrease in inward flux for negative R/Ln and a change of direction from inward to outward for positive R/Ln . This might have serious consequences for pellet fuelling of high β plasmas.

  6. Hollow screw-like drill in plasma using an intense Laguerre-Gaussian laser

    Science.gov (United States)

    Wang, Wenpeng; Shen, Baifei; Zhang, Xiaomei; Zhang, Lingang; Shi, Yin; Xu, Zhizhan

    2015-02-01

    With the development of ultra-intense laser technology, MeV ions can be obtained from laser-foil interactions in the laboratory. These energetic ion beams can be applied in fast ignition for inertial confinement fusion, medical therapy, and proton imaging. However, these ions are mainly accelerated in the laser propagation direction. Ion acceleration in an azimuthal orientation was scarcely studied. In this research, a doughnut Laguerre-Gaussian (LG) laser is used for the first time to examine laser-plasma interaction in the relativistic intensity regime in three-dimensional particle-in-cell simulations. Studies have shown that a novel rotation of the plasma is produced from the hollow screw-like drill of an mode laser. The angular momentum of particles in the longitudinal direction produced by the LG laser is enhanced compared with that produced by the usual laser pulses, such as linearly and circularly polarized Gaussian pulses. Moreover, the particles (including electrons and ions) can be trapped and uniformly compressed in the dark central minimum of the doughnut LG pulse. The hollow-structured LG laser has potential applications in the generation of x-rays with orbital angular momentum, plasma accelerators, fast ignition for inertial confinement fusion, and pulsars in the astrophysical environment.

  7. Hollow screw-like drill in plasma using an intense Laguerre–Gaussian laser

    Science.gov (United States)

    Wang, Wenpeng; Shen, Baifei; Zhang, Xiaomei; Zhang, Lingang; Shi, Yin; Xu, Zhizhan

    2015-01-01

    With the development of ultra-intense laser technology, MeV ions can be obtained from laser–foil interactions in the laboratory. These energetic ion beams can be applied in fast ignition for inertial confinement fusion, medical therapy, and proton imaging. However, these ions are mainly accelerated in the laser propagation direction. Ion acceleration in an azimuthal orientation was scarcely studied. In this research, a doughnut Laguerre–Gaussian (LG) laser is used for the first time to examine laser–plasma interaction in the relativistic intensity regime in three-dimensional particle-in-cell simulations. Studies have shown that a novel rotation of the plasma is produced from the hollow screw-like drill of an mode laser. The angular momentum of particles in the longitudinal direction produced by the LG laser is enhanced compared with that produced by the usual laser pulses, such as linearly and circularly polarized Gaussian pulses. Moreover, the particles (including electrons and ions) can be trapped and uniformly compressed in the dark central minimum of the doughnut LG pulse. The hollow-structured LG laser has potential applications in the generation of x-rays with orbital angular momentum, plasma accelerators, fast ignition for inertial confinement fusion, and pulsars in the astrophysical environment. PMID:25651780

  8. Non-self-sustained discharge with hollow anode for plasma-based surface treatment

    Directory of Open Access Journals (Sweden)

    Misiruk Ivan O.

    2016-06-01

    Full Text Available The paper discusses plasma methods for surface modification using the non-self-sustained glow discharge with a hollow anode. This discharge is characterised by low voltage and high values of electron and ion currents. It can be easily excited in vacuum-arc installations that are widely used for coatings deposition. It is shown that such type of discharge may be effectively used for ion pumping, film deposition, ion etching, diffusion saturation of metallic materials, fusion and brazing of metals, and for combined application of above mentioned technologies in a single vacuum cycle.

  9. Existence of a virtual cathode close to a strongly electron emissive wall in low density plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Tierno, S. P., E-mail: sp.tierno@upm.es; Donoso, J. M.; Domenech-Garret, J. L.; Conde, L. [Department of Applied Physics, E.T.S.I. Aeronáutica y del Espacio. Universidad Politécnica de Madrid, 28040 Madrid (Spain)

    2016-01-15

    The interaction between an electron emissive wall, electrically biased in a plasma, is revisited through a simple fluid model. We search for realistic conditions of the existence of a non-monotonic plasma potential profile with a virtual cathode as it is observed in several experiments. We mainly focus our attention on thermionic emission related to the operation of emissive probes for plasma diagnostics, although most conclusions also apply to other electron emission processes. An extended Bohm criterion is derived involving the ratio between the two different electron densities at the potential minimum and at the background plasma. The model allows a phase-diagram analysis, which confirms the existence of the non-monotonic potential profiles with a virtual cathode. This analysis shows that the formation of the potential well critically depends on the emitted electron current and on the velocity at the sheath edge of cold ions flowing from the bulk plasma. As a consequence, a threshold value of the governing parameter is required, in accordance to the physical nature of the electron emission process. The latter is a threshold wall temperature in the case of thermionic electrons. Experimental evidence supports our numerical calculations of this threshold temperature. Besides this, the potential well becomes deeper with increasing electron emission, retaining a fraction of the released current which limits the extent of the bulk plasma perturbation. This noninvasive property would explain the reliable measurements of plasma potential by using the floating potential method of emissive probes operating in the so-called strong emission regime.

  10. Research on the effect of cathode plasma expansion on x-band relativistic backward wave oscillator using moving-boundary conformal PIC method

    Science.gov (United States)

    Chen, Zaigao; Wang, Jianguo; Wang, Yue

    2016-09-01

    The cathode plasma expansion has been widely investigated and is recognized as impedance collapse in a relativistic backward wave oscillator (RBWO). However, the process of formation and expansion of cathode plasma is very complicated, and the thickness of plasma is only several millimeters, so the simulation of cathode plasma requires high temporal and spatial resolutions. Only the scaled-down diode model and the thin gas layer model are considered in the previous hybrid simulation, and there are few numerical studies on the effect of cathode plasma expansion on the RBWO. In this paper, the moving-boundary conformal particle-in-cell method is proposed; the cathode plasma front is treated in this novel method as the actual cathode surface, and the explosive electron emission boundary moves as the expansion of cathode plasma. Moreover, in order to accurately simulate the electromagnetic field near the cathode surface, the conformal finite-difference time-domain method based on the enlarged cell technique is adopted. The numerical simulation indicates that the diode voltage decreases and the beam current increases as cathode plasma expands; when the cathode plasma velocity is 10 cm/μs, the pulse duration of the generated microwave decreases from 30 ns to 10 ns, the working frequency decreases from 9.83 GHz to 9.64 GHz, and the output power decreases 30% in the course of cathode plasma expansion.

  11. Cathodic arcs

    OpenAIRE

    Anders, Andre

    2003-01-01

    Cathodic arc plasma deposition has become the technology of choice for hard, wear and corrosion resistant coatings for a variety of applications. The history, basic physics of cathodic arc operation, the infamous macroparticle problem and common filter solutions, and emerging high-tech applications are briefly reviewed. Cathodic arc plasmas stand out due to their high degree of ionization, with important consequences for film nucleation, growth, and efficient utilization of substrate bia...

  12. Experimental investigation of a 1 kA/cm² sheet beam plasma cathode electron gun.

    Science.gov (United States)

    Kumar, Niraj; Pal, Udit Narayan; Pal, Dharmendra Kumar; Prajesh, Rahul; Prakash, Ram

    2015-01-01

    In this paper, a cold cathode based sheet-beam plasma cathode electron gun is reported with achieved sheet-beam current density ∼1 kA/cm(2) from pseudospark based argon plasma for pulse length of ∼200 ns in a single shot experiment. For the qualitative assessment of the sheet-beam, an arrangement of three isolated metallic-sheets is proposed. The actual shape and size of the sheet-electron-beam are obtained through a non-conventional method by proposing a dielectric charging technique and scanning electron microscope based imaging. As distinct from the earlier developed sheet beam sources, the generated sheet-beam has been propagated more than 190 mm distance in a drift space region maintaining sheet structure without assistance of any external magnetic field.

  13. Development of Polysulfone Hollow Fiber Porous Supports for High Flux Composite Membranes: Air Plasma and Piranha Etching

    OpenAIRE

    Ilya Borisov; Anna Ovcharova; Danila Bakhtin; Stepan Bazhenov; Alexey Volkov; Rustem Ibragimov; Rustem Gallyamov; Galina Bondarenko; Rais Mozhchil; Alexandr Bildyukevich; Vladimir Volkov

    2017-01-01

    For the development of high efficiency porous supports for composite membrane preparation, polysulfone (PSf) hollow fiber membranes (outer diameter 1.57 mm, inner diameter 1.12 mm) were modified by air plasma using the low temperature plasma treatment pilot plant which is easily scalable to industrial level and the Piranha etch (H2O2 + H2SO4). Chemical and plasma modification affected only surface layers and did not cause PSf chemical structure change. The modifications led to surface roughne...

  14. Graphene-coated hollow fiber membrane as the cathode in anaerobic electrochemical membrane bioreactors – Effect of configuration and applied voltage on performance and membrane fouling

    KAUST Repository

    Werner, Craig M.

    2015-12-22

    Electrically conductive, graphene-coated hollow-fiber porous membranes were used as cathodes in anaerobic electrochemical membrane bioreactors (AnEMBRs) operated at different applied voltages (0.7 V and 0.9 V) using a new rectangular reactor configuration, compared to a previous tubular design (0.7 V). The onset of biofouling was delayed and minimized in rectangular reactors operated at 0.9 V, compared to those at 0.7 V due to higher rates of hydrogen production. Maximum transmembrane pressures for the rectangular reactor were only 0.10 bar (0.7 V) or 0.05 bar (0.9 V) after 56 days of operation, compared to 0.46 bar (0.7 V) for the tubular reactor after 52 days. The thickness of the membrane biofouling layer was approximately 0.4 µm for rectangular reactors and 4 µm for the tubular reactor. Higher permeate quality (TSS = 0.05 mg/L) was achieved in the rectangular AnEMBR than the tubular AnEMBR (TSS = 17 mg/L), likely due to higher current densities that minimized the accumulation of cells in suspension. These results show that the new rectangular reactor design, which had increased rates of hydrogen production, successfully delayed the onset of cathode biofouling and improved reactor performance.

  15. Investigation on the Plasma-Induced Emission Properties of Large Area Carbon Nanotube Array Cathodes with Different Morphologies

    OpenAIRE

    Liu Liang; Liao Qingliang; Qin Zi; Zhang Zheng; Qi Junjie; Zhang Yue; Huang Yunhua

    2011-01-01

    Abstract Large area well-aligned carbon nanotube (CNT) arrays with different morphologies were synthesized by using a chemical vapor deposition. The plasma-induced emission properties of CNT array cathodes with different morphologies were investigated. The ratio of CNT height to CNT-to-CNT distance has considerable effects on their plasma-induced emission properties. As the ratio increases, emission currents of CNT array cathodes decrease due to screening effects. Under the pulse electric fie...

  16. Effect of process parameters on coating composition of cathodic-plasma-electrolysis-treated copper

    Indian Academy of Sciences (India)

    ASIYEH HABIBI; S MOHAMMAD MOUSAVI KHOIE; FARZAD MAHBOUBI; MUSTAFA URGEN

    2017-04-01

    Cathodic plasma electrolysis is a novel technique to form nanostructured layers on metallic surfaces by application of high voltage in a suitable aqueous electrolyte. In the present study, copper is treated by plasma electrolysisin 50 vol% ethanol electrolyte and coatings comprising carbon nanostructure and copper oxide are formed on the copper. The effect of some process parameters such as electrical conductivity, volume and temperature of electrolyte and ratio of anode to cathode surface area on current–voltage behaviour and subsequently coating compositions are investigated at 150V deposition voltage. The composition and morphology of these coatings are characterized by X-ray diffraction, Raman spectroscopy and scanning electron microscopy. Different current–voltage behaviours, temperatures of substrate and the contents and energies of radicals and ions around the substrate by changes in the mentioned parameters cause different compositions from 100 vol% copper oxide to different ratios of copper oxide to carbon, the structure changing from amorphous to graphitic structure in carbon and amorphous to cubic morphology in copper oxide on the substrate. Therefore, the understanding of cathodic plasma electrolysiscan be developed.

  17. Surface nitridation of silicon nano-particles using double multi-hollow discharge plasma CVD

    Energy Technology Data Exchange (ETDEWEB)

    Uchida, Giichiro; Yamamoto, Kosuke; Kawashima, Yuki; Sato, Muneharu; Nakahara, Kenta; Itagaki, Naho; Koga, Kazunori; Shiratani, Masaharu [Graduate School of Information Science and Electrical Engineering, Kyushu University, Fukuoka (Japan); Kamataki, Kunihiro [Center for Reserch and Advancement in Higher Education, Kyushu University, Fukuoka (Japan); Kondo, Michio [National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki (Japan)

    2011-10-15

    We present production of silicon nano-particles and their surface nitridation for efficient multiple-exciton generation. Nitridated silicon nano-particles were produced using double multi-hollow discharge plasma CVD, where generation of silicon particles and their nitridation were independently performed using SiH{sub 4}/H{sub 2} and N{sub 2} multi-hollow discharge plasmas. We succeeded in controlling nitrogen content in a silicon nano-particle by varying a number density of N radicals irradiated to the Si particle. We also observed strong photoluminescence (PL) emission around 300-500 nm from silicon nano-particles, where the PL peak energy is about 2.5 and 3.1 eV for pure Si nano-particles, and 2.5, 3.1, and 4.1 eV for nitridated Si nano-particles. The additional UV-peak of 4.1 eV from nitridated Si particles is closely related to the nitridation surface layer on Si nano-particles (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  18. High-energy lithium-ion hybrid supercapacitors composed of hierarchical urchin-like WO3/C anodes and MOF-derived polyhedral hollow carbon cathodes.

    Science.gov (United States)

    Xu, Juan; Li, Yuanyuan; Wang, Lei; Cai, Qifa; Li, Qingwei; Gao, Biao; Zhang, Xuming; Huo, Kaifu; Chu, Paul K

    2016-09-22

    A lithium-ion hybrid supercapacitor (Li-HSC) comprising a Li-ion battery type anode and an electrochemical double layer capacitance (EDLC) type cathode has attracted much interest because it accomplishes a large energy density without compromising the power density. In this work, hierarchical carbon coated WO3 (WO3/C) with a unique mesoporous structure and metal-organic framework derived nitrogen-doped carbon hollow polyhedra (MOF-NC) are prepared and adopted as the anode and the cathode for Li-HSCs. The hierarchical mesoporous WO3/C microspheres assembled by radially oriented WO3/C nanorods along the (001) plane enable effective Li(+) insertion, thus exhibit high capacity, excellent rate performance and a long cycling life due to their high Li(+) conductivity, electronic conductivity and structural robustness. The WO3/C structure shows a reversible specific capacity of 508 mA h g(-1) at a 0.1 C rate (1 C = 696 mA h g(-1)) after 160 discharging-charging cycles with excellent rate capability. The MOF-NC achieved the specific capacity of 269.9 F g(-1) at a current density of 0.2 A g(-1). At a high current density of 6 A g(-1), 92.4% of the initial capacity could be retained after 2000 discharging-charging cycles, suggesting excellent cycle stability. The Li-HSC comprising a WO3/C anode and a MOF-NC cathode boasts a large energy density of 159.97 W h kg(-1) at a power density of 173.6 W kg(-1) and 88.3% of the capacity is retained at a current density of 5 A g(-1) after 3000 charging-discharging cycles, which are better than those previously reported for Li-HSCs. The high energy and power densities of the Li-HSCs of WO3/C//MOF-NC render large potential in energy storage.

  19. Enhanced propagation for relativistic laser pulses in inhomogeneous plasmas using hollow channels.

    Science.gov (United States)

    Fuchs, J; d'Humières, E; Sentoku, Y; Antici, P; Atzeni, S; Bandulet, H; Depierreux, S; Labaune, C; Schiavi, A

    2010-11-26

    The influence of long (several millimeters) and hollow channels, bored in inhomogeneous ionized plasma by using a long pulse laser beam, on the propagation of short, ultraintense laser pulses has been studied. Compared to the case without a channel, propagation in channels significantly improves beam transmission and maintains a beam quality close to propagation in vacuum. In addition, the growth of the forward-Raman instability is strongly reduced. These results are beneficial for the direct scheme of the fast ignitor concept of inertial confinement fusion as we demonstrate, in fast-ignition-relevant conditions, that with such channels laser energy can be carried through increasingly dense plasmas close to the fuel core with minimal losses.

  20. Hollow screw like drill in plasma using an intense Laguerre Gaussian laser

    CERN Document Server

    Wang, Wenpeng; Zhang, Xiaomei; Zhang, Lingang; Shi, Yin; Xu, Zhizhan

    2014-01-01

    With the development of ultra intense laser technology, MeV ions from the laser foil interaction have been obtained by different mechanisms, such as target normal sheath acceleration, radiation pressure acceleration, collisionless shock acceleration, breakout afterburner, and a combination of different mechanisms. These energetic ion beams can be applied in fast ignition for inertial confinement fusion, medical therapy, and proton imaging. However, these ions are mainly accelerated in the laser propagation direction, and the ion acceleration in an azimuthal orientation is scarcely mentioned. Here, a doughnut Laguerre Gaussian LG laser is used for the first time to study the laser plasma interaction in the relativistic intensity regime in three dimensional particle in cell simulations. Studies have shown that a novel rotation of the plasma is produced from the hollow screw like drill of a LG mode laser. The angular momentum of the protons in the longitudinal direction produced by the LG laser is remarkably enh...

  1. Charge-state and element-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres

    CERN Document Server

    Franz, Robert; Anders, André

    2014-01-01

    The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al$^{+}$ regardless of the background gas species, whereas Cr$^{2+}$ ions were dominating in Ar and N$_2$ and Cr$^{+}$ in O$_2$ atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ions that were subjected to collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were mainly thermalised. In addition to the positively charged metal and gas ions, negatively charged oxygen an...

  2. Dynamics of cathode spots in low-pressure arc plasma removing oxide layer on steel surfaces

    Science.gov (United States)

    Tang, Z. L.; Yang, K.; Liu, H. X.; Zhang, Y. C.; Li, H.; Zhu, X. D.

    2016-03-01

    The dynamics of cathode spots has been investigated in low-pressure arc plasma for removing oxide layer on low carbon steel surfaces. The motion of cathode spots was observed with a high speed camera, and the arc voltage was analyzed by fast Fourier transform. The spots move on clean steel surface as a random walk, and the low-frequency components dominated the voltage waveform. However, the spots on steel surfaces with oxide layer tend to burn on the rim of the eroded area formed in the previous arcing, and the low-frequency components decrease correspondingly. The "color" of the colored random noise for arc voltage varies from the approximate brown noise for clean steel surface to pink noise for thick oxide layer, where the edge effect of boundary is considered to play a significant role.

  3. Fine-tunable plasma nano-machining for fabrication of 3D hollow nanostructures: SERS application

    Science.gov (United States)

    Mehrvar, L.; Hajihoseini, H.; Mahmoodi, H.; Tavassoli, S. H.; Fathipour, M.; Mohseni, S. M.

    2017-08-01

    Novel processing sequences for the fabrication of artificial nanostructures are in high demand for various applications. In this paper, we report on a fine-tunable nano-machining technique for the fabrication of 3D hollow nanostructures. This technique originates from redeposition effects occurring during Ar dry etching of nano-patterns. Different geometries of honeycomb, double ring, nanotube, cone and crescent arrays have been successfully fabricated from various metals such as Au, Ag, Pt and Ti. The geometrical parameters of the 3D hollow nanostructures can be straightforwardly controlled by tuning the discharge plasma pressure and power. The structure and morphology of nanostructures are probed using atomic force microscopy (AFM), scanning electron microscopy (SEM), optical emission spectroscopy (OES) and energy dispersive x-ray spectroscopy (EDS). Finally, a Ag nanotube array was assayed for application in surface enhanced Raman spectroscopy (SERS), resulting in an enhancement factor (EF) of 5.5 × 105, as an experimental validity proof consistent with the presented simulation framework. Furthermore, it was found that the theoretical EF value for the honeycomb array is in the order of 107, a hundred times greater than that found in nanotube array.

  4. The determination of micro-arc plasma composition and properties of nanoparticles formed during cathodic plasma electrolysis of 304 stainless steel

    Science.gov (United States)

    Jovović, Jovica; Stojadinović, Stevan; Vasilić, Rastko; Tadić, Nenad; Šišović, Nikola M.

    2017-05-01

    This paper presents the research focused on the determination of micro-arc plasma composition during cathodic plasma electrolysis of AISI304 stainless steel in water solution of sodium hydroxide. The complex line shape of several Fe I spectral lines was observed and, by means of a dedicated fitting procedure based on the spectral line broadening theory and H2O thermal decomposition data, the mole fraction of micro-arc plasma constituents (H2, Fe, O, H, H2O, and OH) was determined. Subsequent characterization of the cathodic plasma electrolysis product formed during the process revealed that it consists of Fe-nanoparticles with median diameter of approximately 60 nm.

  5. Real-time imaging, spectroscopy, and structural investigation of cathodic plasma electrolytic oxidation of molybdenum

    Energy Technology Data Exchange (ETDEWEB)

    Stojadinović, Stevan, E-mail: sstevan@ff.bg.ac.rs; Tadić, Nenad; Šišović, Nikola M.; Vasilić, Rastko [Faculty of Physics, University of Belgrade, Studentski trg 12-16, 11000 Belgrade (Serbia)

    2015-06-21

    In this paper, the results of the investigation of cathodic plasma electrolytic oxidation (CPEO) of molybdenum at 160 V in a mixed solution of borax, water, and ethylene glycol are presented. Real-time imaging and optical emission spectroscopy were used for the characterization of the CPEO. During the process, vapor envelope is formed around the cathode and strong electric field within the envelope caused the generation of plasma discharges. The spectral line shape analysis of hydrogen Balmer line H{sub β} (486.13 nm) shows that plasma discharges are characterized by the electron number density of about 1.4 × 10{sup 21 }m{sup −3}. The electron temperature of 15 000 K was estimated by measuring molybdenum atomic lines intensity. Surface morphology, chemical, and phase composition of coatings formed by CPEO were characterized by scanning electron microscopy with energy dispersive x-ray spectroscopy and x-ray diffraction. The elemental components of CPEO coatings are Mo and O and the predominant crystalline form is MoO{sub 3}.

  6. Surface monofunctionalized polymethyl pentene hollow fiber membranes by plasma treatment and hemocompatibility modification for membrane oxygenators

    Science.gov (United States)

    Huang, Xin; Wang, Weiping; Zheng, Zhi; Fan, Wenling; Mao, Chun; Shi, Jialiang; Li, Lei

    2016-01-01

    The hemocompatibility of polymethyl pentene (PMP) hollow fiber membranes (HFMs) was improved through surface modification for membrane oxygenator applications. The modification was performed stepwise with the following: (1) oxygen plasma treatment, (2) functionalization of monosort hydroxyl groups through NaBH4 reduction, and (3) grafting 2-methacryloyloxyethyl phosphorylcholine (MPC) or heparin. SEM, ATR-FTIR, and XPS analyses were conducted to confirm successful grafting during the modification. The hemocompatibility of PMP HFMs was analyzed and compared through protein adsorption, platelet adhesion, and coagulation tests. Pure CO2 and O2 permeation rates, as well as in vitro gas exchange rates, were determined to evaluate the mass transfer properties of PMP HFMs. SEM results showed that different nanofibril topographies were introduced on the HFM surface. ATR-FTIR and XPS spectra indicated the presence of functionalization of monosort hydroxyl group and the grafting of MPC and heparin. Hemocompatibility evaluation results showed that the modified PMP HFMs presented optimal hemocompatibility compared with pristine HFMs. Gas permeation results revealed that gas permeation flux increased in the modified HFMs because of dense surface etching during the plasma treatment. The results of in vitro gas exchange rates showed that all modified PMP HFMs presented decreased gas exchange rates because of potential surface fluid wetting. The proposed strategy exhibits a potential for fabricating membrane oxygenators for biomedical applications to prevent coagulation formation and alter plasma-induced surface topology and composition.

  7. Cell adhesion property of cathodic arc plasma deposited CrN thin film

    Science.gov (United States)

    Kim, Sun Kyu; Pham, Vuong Hung

    2009-09-01

    The interaction between human osteoblast cells and CrN thin film was studied in vitro. CrN thin films were produced by cathodic arc plasma deposition. The surface was characterized by atomic force microscopy. Cell adhesion on the coatings was assessed by MTT assay and visualization. Cell cytoskeleton organization was studied by analyzing microtubule and actin cytoskeleton organization. Focal contact adhesion was monitored by analyzing vinculin density. The study found that the CrN thin film is a potential candidate as a protective coating on implantable devices that require minimal cellular adhesion.

  8. Synthesis of thick diamond films by direct current hot-cathode plasma chemical vapour deposition

    CERN Document Server

    Jin Zeng Sun; Bai Yi Zhen; Lu Xian Yi

    2002-01-01

    The method of direct current hot-cathode plasma chemical vapour deposition has been established. A long-time stable glow discharge at large discharge current and high gas pressure has been achieved by using a hot cathode in the temperature range from 1100 degree C to 1500 degree C and non-symmetrical configuration of the poles, in which the diameter of the cathode is larger than that of anode. High-quality thick diamond films, with a diameter of 40-50 mm and thickness of 0.5-4.2 mm, have been synthesized by this method. Transparent thick diamond films were grown over a range of growth rates between 5-10 mu m/h. Most of the thick diamond films have thermal conductivities of 10-12 W/K centre dot cm. The thick diamond films with high thermal conductivity can be used as a heat sink of semiconducting laser diode array and as a heat spreading and isolation substrate of multichip modules. The performance can be obviously improved

  9. Scheme for proton-driven plasma-wakefield acceleration of positively charged particles in a hollow plasma channel

    Directory of Open Access Journals (Sweden)

    Longqing Yi (易龙卿

    2013-07-01

    Full Text Available A new scheme for accelerating positively charged particles in a plasma-wakefield accelerator is proposed. If the proton drive beam propagates in a hollow plasma channel, and the beam radius is of order of the channel width, the space charge force of the driver causes charge separation at the channel wall, which helps to focus the positively charged witness bunch propagating along the beam axis. In the channel, the acceleration buckets for positively charged particles are much larger than in the blowout regime of the uniform plasma, and stable acceleration over long distances is possible. In addition, phasing of the witness with respect to the wave can be tuned by changing the radius of the channel to ensure the acceleration is optimal. Two-dimensional simulations suggest that, for proton drivers likely available in future, positively charged particles can be stably accelerated over 1 km with the average acceleration gradient of 1.3  GeV/m.

  10. Interfacial Reaction Dependent Performance of Hollow Carbon NanoSphere – Sulfur composite as a cathode for Li-S battery

    Directory of Open Access Journals (Sweden)

    Jianming eZheng

    2015-05-01

    Full Text Available Lithium-sulfur (Li-S battery is a promising energy storage system due to its high energy density, cost effectiveness and environmental friendliness of sulfur. However, there are still a number of technical challenges, such as low Coulombic efficiency and poor long-term cycle life, impeding the commercialization of Li-S battery. The electrochemical performance of Li-S battery is closely related with the interfacial reactions occurring between hosting substrate and active sulfur species which are poorly conducting at fully oxidized and reduced states. Here, we correlate the relationship between the performance and interfacial reactions in the Li-S battery system, using a hollow carbon nanosphere (HCNS with highly graphitic character as hosting substrate for sulfur. With an appropriate amount of sulfur loading, HCNS/S composite exhibits excellent electrochemical performance because of the fast interfacial reactions between HCNS and the polysulfides. However, further increase of sulfur loading leads to increased formation of highly resistive insoluble reaction products (Li2S2/Li2S which limits the reversibility of the interfacial reactions and results in poor electrochemical performances. These findings demonstrate the importance of the interfacial reaction reversibility in the whole electrode system on achieving high capacity and long cycle life of sulfur cathode for Li-S batteries.

  11. The Infrared Spectrum of Uranium Hollow Cathode Lamps from 850 nm to 4000 nm: Wavenumbers and Line Identifications from Fourier Transform Spectra

    CERN Document Server

    Redman, Stephen L; Nave, Gillian; Ramsey, Lawrence W; Mahadevan, Suvrath

    2011-01-01

    We provide new measurements of wavenumbers and line identifications of 10 100 UI and UII near-infrared (NIR) emission lines between 2500 cm-1 and 12 000 cm-1 (4000 nm to 850 nm) using archival FTS spectra from the National Solar Observatory (NSO). This line list includes isolated uranium lines in the Y, J, H, K, and L bands (0.9 {\\mu}m to 1.1 {\\mu}m, 1.2 {\\mu}m to 1.35 {\\mu}m, 1.5 {\\mu}m to 1.65 {\\mu}m, 2.0 {\\mu}m to 2.4 {\\mu}m, and 3.0 {\\mu}m to 4.0 {\\mu}m, respectively), and provides six times as many calibration lines as thorium in the NIR spectral range. The line lists we provide enable inexpensive, commercially-available uranium hollow-cathode lamps to be used for high-precision wavelength calibration of existing and future high-resolution NIR spectrographs.

  12. Cathodic arcs

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre

    2003-10-29

    Cathodic arc plasma deposition has become the technology of choice for hard, wear and corrosion resistant coatings for a variety of applications. The history, basic physics of cathodic arc operation, the infamous macroparticle problem and common filter solutions, and emerging high-tech applications are briefly reviewed. Cathodic arc plasmas standout due to their high degree of ionization, with important consequences for film nucleation, growth, and efficient utilization of substrate bias. Industrial processes often use cathodic arc plasma in reactive mode. In contrast, the science of arcs has focused on the case of vacuum arcs. Future research directions include closing the knowledge gap for reactive mode, large area coating, linear sources and filters, metal plasma immersion process, with application in high-tech and biomedical fields.

  13. One-step preparation of hydrogenated ZrO2 microspheres by cathode plasma electrolysis

    Science.gov (United States)

    Liu, Chenxu; Xiang, Qingyun; Yang, Mu; Wang, Shengdian; Wang, Linxiu; Zhang, Jin; He, Yedong

    2017-07-01

    Hydrogenated ZrO2 microspheres were directly prepared by cathode plasma electrolysis (CPE) in an aqueous solution of Zr(NO3)4•5H2O. Owing to the energy of plasma and the cathodic hydrogen evolution reactions, the CPE method combined the preparation of ZrO2 ceramic and the hydrogen treatment into only one step. The results showed regular microspheres consisting of tetragonal-ZrO2 and monoclinic-ZrO2 with 1-10 µm in diameter were formed at relatively high concentration of Zr(NO3)3•5H2O. These ZrO2 microspheres contained about 52.54 µg g-1 hydrogen which caused a narrow band gap (3.10 eV). Thus, the microspheres showed good photocatalytic activity under simulated sunlight, and the degradation of RhB dye reached nearly 58% for 3 h of irradiation, much better than the ZrO2 microspheres after dehydrogenation treatment.

  14. Advanced plasma flow simulations of cathodic-arc and ferroelectric plasma sources for neutralized drift compression experiments

    Directory of Open Access Journals (Sweden)

    Adam B. Sefkow

    2008-07-01

    Full Text Available Large-space-scale and long-time-scale plasma flow simulations are executed in order to study the spatial and temporal evolution of plasma parameters for two types of plasma sources used in the neutralized drift compression experiment (NDCX. The results help assess the charge neutralization conditions for ion beam compression experiments and can be employed in more sophisticated simulations, which previously neglected the dynamical evolution of the plasma. Three-dimensional simulations of a filtered cathodic-arc plasma source show the coupling efficiency of the plasma flow from the source to the drift region depends on geometrical factors. The nonuniform magnetic topology complicates the well-known general analytical considerations for evaluating guiding-center drifts, and particle-in-cell simulations provide a self-consistent evaluation of the physics in an otherwise challenging scenario. Plasma flow profiles of a ferroelectric plasma source demonstrate that the densities required for longitudinal compression experiments involving ion beams are provided over the drift length, and are in good agreement with measurements. Simulations involving azimuthally asymmetric plasma creation conditions show that symmetric profiles are nevertheless achieved at the time of peak on-axis plasma density. Also, the ferroelectric plasma expands upstream on the thermal expansion time scale, and therefore avoids the possibility of penetration into the acceleration gap and transport sections, where partial neutralization would increase the beam emittance. Future experiments on NDCX will investigate the transverse focusing of an axially compressing intense charge bunch to a sub-mm spot size with coincident focal planes using a strong final-focus solenoid. In order to fill a multi-tesla solenoid with the necessary high-density plasma for beam charge neutralization, the simulations predict that supersonically injected plasma from the low-field region will penetrate and

  15. Investigation on the Plasma-Induced Emission Properties of Large Area Carbon Nanotube Array Cathodes with Different Morphologies.

    Science.gov (United States)

    Liao, Qingliang; Qin, Zi; Zhang, Zheng; Qi, Junjie; Zhang, Yue; Huang, Yunhua; Liu, Liang

    2011-12-01

    Large area well-aligned carbon nanotube (CNT) arrays with different morphologies were synthesized by using a chemical vapor deposition. The plasma-induced emission properties of CNT array cathodes with different morphologies were investigated. The ratio of CNT height to CNT-to-CNT distance has considerable effects on their plasma-induced emission properties. As the ratio increases, emission currents of CNT array cathodes decrease due to screening effects. Under the pulse electric field of about 6 V/μm, high-intensity electron beams of 170-180 A/cm(2) were emitted from the surface plasma. The production mechanism of the high-intensity electron beams emitted from the CNT arrays was plasma-induced emission. Moreover, the distribution of the electron beams was in situ characterized by the light emission from the surface plasma.

  16. Investigation on the Plasma-Induced Emission Properties of Large Area Carbon Nanotube Array Cathodes with Different Morphologies

    Directory of Open Access Journals (Sweden)

    Liu Liang

    2011-01-01

    Full Text Available Abstract Large area well-aligned carbon nanotube (CNT arrays with different morphologies were synthesized by using a chemical vapor deposition. The plasma-induced emission properties of CNT array cathodes with different morphologies were investigated. The ratio of CNT height to CNT-to-CNT distance has considerable effects on their plasma-induced emission properties. As the ratio increases, emission currents of CNT array cathodes decrease due to screening effects. Under the pulse electric field of about 6 V/μm, high-intensity electron beams of 170–180 A/cm2 were emitted from the surface plasma. The production mechanism of the high-intensity electron beams emitted from the CNT arrays was plasma-induced emission. Moreover, the distribution of the electron beams was in situ characterized by the light emission from the surface plasma.

  17. Reservoir Cathode for Electric Space Propulsion Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose a hollow reservoir cathode to improve performance in ion and Hall thrusters. We will adapt our existing reservoir cathode technology to this purpose....

  18. An Optical Streak Diagnostic for Observing Anode-Cathode Plasmas for Radiographic Source Development

    Energy Technology Data Exchange (ETDEWEB)

    Droemer, Darryl W. [National Security Technologies, LLC; Crain, Marlon D.; Lare, Gregory A. [National Security Technologies, LLC; Bennett, Nichelle L. [National Security Technologies, LLC; Johnston, Mark D. [Sandia National Laboratories

    2013-06-13

    National Security Technologies, LLC, and Sandia National Laboratories are collaborating in the development of pulsed power–driven flash x-ray radiographic sources that utilize high-intensity electron beam diodes. The RITS 6 (Radiographic Integrated Test Stand) accelerator at Sandia is used to drive a self magnetic pinch diode to produce a Bremsstrahlung x-ray source. The high electric fields and current densities associated with these short A-K gap pinch beam diodes present many challenges in diode development. Plasmas generated at both the anode and cathode affect the diode performance, which is manifested in varying spot (source) sizes, total dose output, and impedance profiles. Understanding the nature of these plasmas including closure rates and densities is important in modeling their behavior and providing insight into their mitigation. In this paper we describe a streak camera–based optical diagnostic that is capable of observing and measuring plasma evolution within the A-K gap. By imaging a region of interest onto the input slit of a streak camera, we are able to produce a time-resolved one-dimensional image of the evolving plasma. Typical data are presented.

  19. Study of the use of an electric discharge for hollow cathodes used as optical excitation sources in the spectrographic measurement of fluorine in thorium, uranium and plutonium; Etude de l'utilisation de la decharge electrique en cathode creuse comme source d'excitation optique pour le dosage spectrographique du fluor dans le thorium, l'uranium et le plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Bufpereau, M.; Crehange, G.; Poublan, J. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    Previous works and phenomena concerned with a hollow cathode excitation are reviewed. Experiments aimed specially on the determination of the best conditions for an analysis of fluorine in oxides-metals and solutions. In that purpose, several factors have been pointed out. One started some researches about others elements that fluorine. Carrying fluorine into discharge and excitation have been more specially studied. A quantitative analysis method is given. The analysis limit is 45 ppm about but the detection limit is 5 ppm about. As a conclusion, various ways for optical excitation of fluorine are reviewed as other analytical possibilities a hollow cathode discharge offers. (authors) [French] On rappelle les travaux effectues jusqu'alors ainsi que les phenomenes mis en jeu dans l'excitation cathode creuse. Les experiences effectuees ont eu pour but essentiel la determination des conditions optima du dosage du fluor dans les oxydes, metaux et solutions. Pour cela de nombreux facteurs ont ete mis en evidence. Certaines etudes concernant d'autres elements que le fluor ont ete amorcees. Le passage du fluor dans la decharge et son excitation ont ete plus particulierement etudies. Une methode d'analyse quantitative est degagee, la limite de dosage est de l'ordre de 45 ppm, la limite de detection de 5 ppm. En conclusion, on passe en revue les differentes methodes d'excitation optique du fluor ainsi que les autres possibilites analytiques que peut offrir la cathode creuse. (auteurs)

  20. Effects of cathodic voltages on structure and wear resistance of plasma electrolytic oxidation coatings formed on aluminium alloy

    Energy Technology Data Exchange (ETDEWEB)

    Li, Qingbiao [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); School of Science, Lanzhou University of Technology, Lanzhou 730050 (China); Liang, Jun, E-mail: jliang@licp.cas.cn [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Liu, Baixing; Peng, Zhenjun [State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); Wang, Qing [School of Science, Lanzhou University of Technology, Lanzhou 730050 (China)

    2014-04-01

    Highlights: • The PEO coating growth rate increased with the cathodic voltage increasing. • Higher cathodic voltage resulted in more compact coating structure. • The compact structure led to low surface roughness and high wear resistance. - Abstract: Plasma electrolytic oxidation (PEO) coatings were prepared on aluminium alloy using pulsed bipolar power supply at constant anodic voltage and different cathodic voltages. The samples were prepared to attain the same coating thickness by adjusting the processing time. The scanning electron microscope (SEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD) and tribometer were employed to investigate the microstructure, element content, phase composition and wear resistance of the coatings respectively. It was found that the coating growth rate enhanced obviously and the coatings exhibited a more compact structure with thicker inner layer and lower surface roughness when the cathodic voltage increased. The coatings were mainly composed of crystalline γ-Al{sub 2}O{sub 3} and amorphous silicate oxides and their relative content changed with the cathodic voltage. The wear resistance of the coatings improved significantly with the increase of cathodic voltage.

  1. Current evolution and plasma density space distribution in the reflex discharge with ring cathodes

    Science.gov (United States)

    Samokhin, A. A.; Liziakin, G. D.; Gavrikov, A. V.; Usmanov, R. A.; Smirnov, V. P.

    2016-11-01

    In this paper the numerical model of direct current gas discharge in drift-diffusion approximation is considered. For two-component plasma the processes of the gas discharge development in the reflex geometry with ring cathodes at a helium pressure of 35 mTorr are studied. We investigate the influence of: (a) the boundary conditions on the dielectric, (b) the electron temperature and (c) the coefficient of the secondary ion-electron emission on the I-U curve of the discharge. In a magnetic field of 50 Gauss the impact of the discharge voltage U = 300-700 V on the evolutionary process of the discharge is examined. The effect of diffusion on maintaining steady state discharge is researched. The parameters of the existence of a high-current (tens of μA) and low voltage (tens of mA) discharge modes are defined.

  2. Performance evaluation of self-breakdown-based single-gap plasma cathode electron gun

    Indian Academy of Sciences (India)

    Niraj Kumar; Nalini Pareek; Udit Narayan Pal; Deepak Kumar Verma; Jitendra Prajapati; Mahesh Kumar; Bharat Lal Meena; Ram Prakash

    2014-06-01

    This paper presents the experimental studies on self-breakdown-based single-gap plasma cathode electron (PCE) gun (5–20 kV/50–160 A) in argon, gas atmosphere and its performance evaluation based on particle-in-cell (PIC) simulation code `OOPIC-Pro’.The PCE-Gun works in conducting phase (low energy, high current) of pseudospark discharge. It produces an intense electron beam, which can propagate more than 200 mm in the drift space region without external magnetic field. The profile of this beam in the drift space region at different breakdown conditions (i.e., gas pressures and applied voltages) has been studied and the experimental results are compared with simulated values. It is demonstrated that ∼30% beam current is lost during the propagation possibly due to space charge neutralization and collisions with neutral particles and walls.

  3. Synthesis and characterization hollow spherical La0.7Sr0.2Ca0.1Co0.9Fe0.1O3–δ (LSCCT for cathode of solid oxide fuel cell (SOFC

    Directory of Open Access Journals (Sweden)

    H. H. Yu

    2016-10-01

    Full Text Available Hollow spheres structures of La0.7Sr0.2Ca0.1Co0.9Fe0.1O3–δ (LSCCT have been synthesized via hydrothermal method using carbon spheres as template. The structure and electrical conductivity of obtained samples are characterized by X-ray diffraction (XRD, scanning electron microscope (SEM, transmission electron microscope (TEM and direct current (DC four-probe method respectively. The results show that hollow spheres structures of LSCCT with the mean particle size of 0,9 - 1,2 μm is single perovskite. The electrical conductivity of the samples is higher than 100 S/cm from 600 to 800 ℃ and can meet the demand of the electrical properties for the cathode materials.

  4. Development of Polysulfone Hollow Fiber Porous Supports for High Flux Composite Membranes: Air Plasma and Piranha Etching

    Directory of Open Access Journals (Sweden)

    Ilya Borisov

    2017-02-01

    Full Text Available For the development of high efficiency porous supports for composite membrane preparation, polysulfone (PSf hollow fiber membranes (outer diameter 1.57 mm, inner diameter 1.12 mm were modified by air plasma using the low temperature plasma treatment pilot plant which is easily scalable to industrial level and the Piranha etch (H2O2 + H2SO4. Chemical and plasma modification affected only surface layers and did not cause PSf chemical structure change. The modifications led to surface roughness decrease, which is of great importance for further thin film composite (TFC membranes fabrication by dense selective layer coating, and also reduced water and ethylene glycol contact angle values for modified hollow fibers surface. Furthermore, the membranes surface energy increased two-fold. The Piranha mixture chemical modification did not change the membranes average pore size and gas permeance values, while air plasma treatment increased pore size 1.5-fold and also 2 order enhanced membranes surface porosity. Since membranes surface porosity increased due to air plasma treatment the modified membranes were used as efficient supports for preparation of high permeance TFC membranes by using poly[1-(trimethylsilyl-1-propyne] as an example for selective layer fabrication.

  5. Detailed analysis of hollow ions spectra from dense matter pumped by X-ray emission of relativistic laser plasma

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, S. B., E-mail: sbhanse@sandia.gov, E-mail: anatolyf@hotmail.com [Sandia National Laboratories, Albuquerque, New Mexico 87123 (United States); Colgan, J.; Abdallah, J. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Faenov, A. Ya., E-mail: sbhanse@sandia.gov, E-mail: anatolyf@hotmail.com [Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow 125412 (Russian Federation); Quantum Beam Science Directorate, Japan Atomic Energy Agency, Kyoto 619-0215 (Japan); Pikuz, S. A.; Skobelev, I. Yu. [Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow 125412 (Russian Federation); Wagenaars, E.; Culfa, O.; Dance, R. J.; Tallents, G. J.; Rossall, A. K.; Woolsey, N. C. [York Plasma Institute, Department of Physics, University of York, York YO10 5DD (United Kingdom); Booth, N.; Lancaster, K. L. [Central Laser Facility, STFC Rutherford Appleton Laboratory, Didcot OX11 0QX (United Kingdom); Evans, R. G. [Department of Physics, Imperial College, London SW7 2AZ (United Kingdom); Gray, R. J.; McKenna, P. [SUPA, Department of Physics, University of Strathclyde, Glasgow G4 ONG (United Kingdom); Kaempfer, T.; Schulze, K. S. [Helmholtzinstitut Jena, Jena D-07743 (Germany); Uschmann, I. [Helmholtzinstitut Jena, Jena D-07743 (Germany); Institut für Optik und Quantenelektronic, Friedrich-Schiller-Universität Jena, Max-Wien Platz 1, Jena, D-07743 (Germany); and others

    2014-03-15

    X-ray emission from hollow ions offers new diagnostic opportunities for dense, strongly coupled plasma. We present extended modeling of the x-ray emission spectrum reported by Colgan et al. [Phys. Rev. Lett. 110, 125001 (2013)] based on two collisional-radiative codes: the hybrid-structure Spectroscopic Collisional-Radiative Atomic Model (SCRAM) and the mixed-unresolved transition arrays (MUTA) ATOMIC model. We show that both accuracy and completeness in the modeled energy level structure are critical for reliable diagnostics, investigate how emission changes with different treatments of ionization potential depression, and discuss two approaches to handling the extensive structure required for hollow-ion models with many multiply excited configurations.

  6. La2Zr2O7 TBCs toughened by Pt particles prepared by cathode plasma electrolytic deposition

    Science.gov (United States)

    Deng, Shun-jie; Wang, Peng; He, Ye-dong; Zhang, Jin

    2016-06-01

    La2Zr2O7 thermal barrier coatings (TBCs) with dispersed Pt particles were prepared by cathode plasma electrolytic deposition (CPED) with ceramic balls added to the cathode region. Compared with the conventional CPED, when ceramic balls are used in the cathode region, the plasma discharge ignition current density decreases approximately 62-fold and the stable plasma discharges occur at the whole cathode surface. Such TBCs with a thickness of 100 μm exhibit a crack-free surface and are composed of pyrochlore-structured La2Zr2O7. Cyclic oxidation, scratching, and thermal insulation capability tests show that such TBCs not only exhibit high resistance to oxidation and spallation but also provide good thermal insulation. These beneficial effects are attributed to the excellent properties of TBCs, such as good thermal insulation because of low thermal conductivity, high-temperature oxidation resistance because of low-oxygen diffusion rate, and good mechanical properties because of the toughening effect of Pt particles.

  7. Low voltage drop plasma switch for inverter and modulator applications

    Science.gov (United States)

    Goebel, D. M.; Poeschel, R. L.; Schumacher, R. W.

    1993-08-01

    A low forward voltage drop plasma switch has been developed for high-efficiency inverter and modulator applications. The switch, called the HOLLOTRON, is based on a grid-controlled, thermionic hollow-cathode discharge. A low forward voltage drop (10-20 V) is achieved by operating the hollow-cathode discharge in a static gas pressure of xenon. The dense plasma generated in the Ba-oxide dispenser hollow cathode is spread over a relatively large control grid area by a diverging magnetic field superimposed on the discharge. Interruption of the discharge current at high current densities (≳4 A/cm2) over the grid area is achieved by biasing the control grid sufficiently negative with respect to the plasma. The HOLLOTRON switch has demonstrated voltage stand-off of up to 20 kV, switching times of ≤0.3 μs, and pulse repetition frequencies of 20 kHz at 50% duty.

  8. Study of the feasibility of distributed cathodic arc as a plasma source for development of the technology for plasma separation of SNF and radioactive wastes

    Energy Technology Data Exchange (ETDEWEB)

    Amirov, R. Kh.; Vorona, N. A.; Gavrikov, A. V.; Liziakin, G. D.; Polistchook, V. P.; Samoylov, I. S.; Smirnov, V. P.; Usmanov, R. A., E-mail: ravus46@yandex.ru; Yartsev, I. M. [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation)

    2015-12-15

    One of the key problems in the development of plasma separation technology is designing a plasma source which uses condensed spent nuclear fuel (SNF) or nuclear wastes as a raw material. This paper covers the experimental study of the evaporation and ionization of model materials (gadolinium, niobium oxide, and titanium oxide). For these purposes, a vacuum arc with a heated cathode on the studied material was initiated and its parameters in different regimes were studied. During the experiment, the cathode temperature, arc current, arc voltage, and plasma radiation spectra were measured, and also probe measurements were carried out. It was found that the increase in the cathode heating power leads to the decrease in the arc voltage (to 3 V). This fact makes it possible to reduce the electron energy and achieve singly ionized plasma with a high degree of ionization to fulfill one of the requirements for plasma separation of SNF. This finding is supported by the analysis of the plasma radiation spectrum and the results of the probe diagnostics.

  9. Pretreatment of plasma samples by a novel hollow fiber centrifugal ultrafiltrate device for the determination of cefaclor concentrations in human plasma.

    Science.gov (United States)

    Li, Jun-Mei; Li, Cen; Jiang, Ye; Ren, Shu-Meng

    2010-10-29

    A simple sample preparation method was developed by using a centrifugal ultrafiltration (CF-UF) device with hollow fiber (HF) for the determination of cefaclor in plasma by HPLC. Samples were placed into a homemade device, which was consisted of a glass tube and a U-shaped hollow fiber. The filtrate was withdrawn from the hollow fiber into a syringe after centrifugation and 20 μL was directly injected into the HPLC for analysis. The HPLC method had a linear calibration curve in the concentration range of 6.00×10(-2)-30.7 μg mL(-1)(r=0.9996). The limit of detection (LOD) and limit of quantitation (LOQ) were 0.02 and 0.06 μg mL(-1), respectively. The intra and inter-day precisions (RSD) were 1.7%, 1.2%, 1.0% and 3.6%, 2.5%, 1.9%, respectively, for three concentrations. Assay accuracy was higher than 99.2% and the absolute recovery was 86.8-92.5%. It is feasible to use this novel and low cost device for sample pretreatment for the analysis of cefaclor in plasma.

  10. Near Discharge Cathode Assembly Plasma Potential Measurements in a 30-cm NSTAR Type Ion Engine During Beam Extraction

    Science.gov (United States)

    Herman, Daniel A.; Gallimore, Alec D.

    2006-01-01

    Floating emissive probe plasma potential data are presented over a two-dimensional array of locations in the near Discharge Cathode Assembly (DCA) region of a 30-cm diameter ring-cusp ion thruster. Discharge plasma data are presented with beam extraction at throttling conditions comparable to the NASA TH Levels 8, 12, and 15. The operating conditions of the Extended Life Test (ELT) of the Deep Space One (DS1) flight spare ion engine, where anomalous discharge keeper erosion occurred, were TH 8 and TH 12 consequently they are of specific interest in investigating discharge keeper erosion phenomena. The data do not validate the presence of a potential hill plasma structure downstream of the DCA, which has been proposed as a possible erosion mechanism. The data are comparable in magnitude to data taken by other researchers in ring-cusp electron-bombardment ion thrusters. The plasma potential structures are insensitive to thruster throttling level with a minimum as low as 14 V measured at the DCA exit plane and increasing gradually in the axial direction. A sharp increase in plasma potential to the bulk discharge value of 26 to 28 volts, roughly 10 mm radially from DCA centerline, was observed. Plasma potential measurements indicate a low-potential plume structure that is roughly 20 mm in diameter emanating from the discharge cathode that may be attributed to a free-standing plasma double layer.

  11. Numerical simulation of discharge plasma generation and nitriding the metals and alloys

    Science.gov (United States)

    Koval, T. V.; Manakov, R. A.; Nguyen Bao, Hung; Tran My, Kim An

    2017-01-01

    This research provides the numerical simulation of the plasma generation in a hollow cathode as well as the diffusion of nitrogen atoms into the metal in the low-pressure glow discharge plasma. The characteristics of the gas discharge were obtained and the relation of the basic technological parameters and the structural and phase state of the nitrided material were defined. Authors provided the comparison of calculations with the experimental results of titanium nitriding by low-pressure glow discharge plasma in a hollow cathode.

  12. Numerical Study of Injection Mechanisms for Generation of Mono-Energetic Femtosecond Electron Bunch from the Plasma Cathode

    CERN Document Server

    Ohkubo, Takeru; Zhidkov, Alexei

    2005-01-01

    Acceleration gradients of up to the order of 100GV/m and mono-energetic electron bunch up to 200MeV have recently been observed in several plasma cathode experiments. However, mechanisms of self-injection in plasma are not sufficiently clarified, presently. In this study, we carried out 2D PIC simulation to reveal the mechanisms of mono-energetic femtosecond electron bunch generation. We found two remarkable conditions for the generation: electron density gradient at vacuum-plasma interface and channel formation in plasma. Steep electron density gradient (~ plasma wave length) causes rapid injection and produces an electron bunch with rather high charge and less than 100fs duration. The channel formation guides an injected laser pulse and decreases the threshold of laser self-focusing, which leads to high electric field necessary for wave-breaking injection.

  13. High-current-density, high brightness cathodes for free electron laser applications

    Energy Technology Data Exchange (ETDEWEB)

    Green, M.C. (Varian Associates, Palo Alto, CA (USA). Palo Alto Microwave Tube Div.)

    1987-06-01

    This report discusses the following topics: brightness and emittance of electron beams and cathodes; general requirements for cathodes in high brightness electron guns; candidate cathode types; plasma and field emission cathodes; true field emission cathodes; oxide cathodes; lanthanum hexaborides cathodes; laser driven thermionic cathodes; laser driven photocathodes; impregnated porous tungsten dispenser cathodes; and choice of best performing cathode types.

  14. Enhanced human bone marrow mesenchymal stem cell functions on cathodic arc plasma-treated titanium.

    Science.gov (United States)

    Zhu, Wei; Teel, George; O'Brien, Christopher M; Zhuang, Taisen; Keidar, Michael; Zhang, Lijie Grace

    2015-01-01

    Surface modification of titanium for use in orthopedics has been explored for years; however, an ideal method of integrating titanium with native bone is still required to this day. Since human bone cells directly interact with nanostructured extracellular matrices, one of the most promising methods of improving titanium's osseointegration involves inducing bio-mimetic nanotopography to enhance cell-implant interaction. In this regard, we explored an approach to functionalize the surface of titanium by depositing a thin film of textured titanium nanoparticles via a cathodic arc discharge plasma. The aim is to improve human bone marrow mesenchymal stem cell (MSC) attachment and differentiation and to reduce deleterious effects of more complex surface modification methods. Surface functionalization was analyzed by scanning electron microscopy, atomic force microscopy, contact angle testing, and specific protein adsorption. Scanning electron microscopy and atomic force microscopy examination demonstrate the deposition of titanium nanoparticles and the surface roughness change after coating. The specific fibronectin adsorption was enhanced on the modified titanium surface that associates with the improved hydrophilicity. MSC adhesion and proliferation were significantly promoted on the nanocoated surface. More importantly, compared to bare titanium, greater production of total protein, deposition of calcium mineral, and synthesis of alkaline phosphatase were observed from MSCs on nanocoated titanium after 21 days. The method described herein presents a promising alternative method for inducing more cell favorable nanosurface for improved orthopedic applications.

  15. Electrochemical Properties of Boron-Doped Diamond Electrodes Prepared by Hot Cathode Direct Current Plasma CVD

    Directory of Open Access Journals (Sweden)

    Hong Yan PENG

    2016-05-01

    Full Text Available A series of boron-doped diamond (BDD films were deposited by using a hot cathode direct current plasma chemical vapor deposition(HCDC-PCVD system with different ratios of CH4/H2/B(OCH33 (trimethylborate gas mixture. The morphology, structure and quality of BDD films were controled by SEM, XRD and Raman measurements. The electrochemical properties of the BDD films were investigated by electrochemical methods. Cyclic voltammetric performances of the BDD films indicated that the main determinant in the electrochemical characteristics of BDD films was the boron doping amount. The threshold potential for oxygen evolution increased from 1 V to 2.5 V. Meanwhile, the electrochemical potential window of BDD films was enlarged from 2.2 V to 4.5 V when the B content was increased from 1.75 × 1019cm-3 to 2.4 × 1021 cm−3. The cyclic voltammograms of BDD films in K4Fe(CN6 and K3Fe(CN6 mixed solution indicated that the behavior of Fe(CN6-3/-4 redox couple could be regarded as semi-reversible.DOI: http://dx.doi.org/10.5755/j01.ms.22.2.12926

  16. Enhanced human bone marrow mesenchymal stem cell functions on cathodic arc plasma-treated titanium

    Directory of Open Access Journals (Sweden)

    Zhu W

    2015-12-01

    Full Text Available Wei Zhu,1 George Teel,1 Christopher M O’Brien,1 Taisen Zhuang,1 Michael Keidar,1 Lijie Grace Zhang1–3 1Department of Mechanical and Aerospace Engineering, 2Department of Biomedical Engineering, 3Department of Medicine, The George Washington University, Washington, DC, USA Abstract: Surface modification of titanium for use in orthopedics has been explored for years; however, an ideal method of integrating titanium with native bone is still required to this day. Since human bone cells directly interact with nanostructured extracellular matrices, one of the most promising methods of improving titanium’s osseointegration involves inducing biomimetic nanotopography to enhance cell–implant interaction. In this regard, we explored an approach to functionalize the surface of titanium by depositing a thin film of textured titanium nanoparticles via a cathodic arc discharge plasma. The aim is to improve human bone marrow mesenchymal stem cell (MSC attachment and differentiation and to reduce deleterious effects of more complex surface modification methods. Surface functionalization was analyzed by scanning electron microscopy, atomic force microscopy, contact angle testing, and specific protein adsorption. Scanning electron microscopy and atomic force microscopy examination demonstrate the deposition of titanium nanoparticles and the surface roughness change after coating. The specific fibronectin adsorption was enhanced on the modified titanium surface that associates with the improved hydrophilicity. MSC adhesion and proliferation were significantly promoted on the nanocoated surface. More importantly, compared to bare titanium, greater production of total protein, deposition of calcium mineral, and synthesis of alkaline phosphatase were observed from MSCs on nanocoated titanium after 21 days. The method described herein presents a promising alternative method for inducing more cell favorable nanosurface for improved orthopedic applications

  17. Cathodoluminescence of Cr-doped diamond-like carbon film by filtered cathodic vacuum arc plasma

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Meng-Wen; Jao, Jui-Yun [Department of Materials Science and Engineering, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 402, Taiwan (China); Lin, Chun-Chun; Hsieh, Wei-Jen; Yang, Yu-Hsiang [Department of Materials Science and Engineering, National Tsing Hua University, 101, Sec. 2, Kuang-Fu Road, Hsinchu 300, Taiwan (China); Cheng, Li-Shin; Shieu, F.S. [Department of Materials Science and Engineering, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 402, Taiwan (China); Shih, Han C., E-mail: hcshih@mx.nthu.edu.tw [Department of Materials Science and Engineering, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 402, Taiwan (China); Department of Materials Science and Engineering, National Tsing Hua University, 101, Sec. 2, Kuang-Fu Road, Hsinchu 300, Taiwan (China); Institute of Materials Science and Nanotechnology, Chinese Culture University, 55 Hwa Kang Road, Yang Ming Shan, Taipei 111, Taiwan (China)

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer The formation of the DLC:Cr films dependent on the flow rates of C{sub 2}H{sub 2}/Ar have been achieved in our FCVA plasma. Black-Right-Pointing-Pointer The amorphous DLC:Cr have high sp{sup 2} content can be completely converted to nanocrystalline Cr{sub 3}C{sub 2}. Black-Right-Pointing-Pointer The effect of doping with Cr is apparently to change the band structure of the DLC and its consequent cathodoluminescence property. - Abstract: Cr doped diamond-like carbon (DLC:Cr) film was synthesized in various flow rates of C{sub 2}H{sub 2}/Ar under a substrate voltage of -50 V at 500 Degree-Sign C by a filtered cathodic vacuum arc plasma. This work has found that the structure of the films was correlated to the flow rate of C{sub 2}H{sub 2}/Ar but the luminescence properties are similar. The cathodoluminescence spectra of DLC:Cr films obtained at 1.9-2.4 eV verifies that the luminescence from the films is in the visible region. The incorporation of Cr into the carbon network results in red emission shifted to 1.99 eV and the orange emission (2.03 eV) also appeared due to the transitions between chromium-related electron levels and {sigma}* states. The peak at 2.10 eV may result from the defects of the structures in DLC:Cr films.

  18. Pulsed plasma electron sourcesa)

    Science.gov (United States)

    Krasik, Ya. E.; Yarmolich, D.; Gleizer, J. Z.; Vekselman, V.; Hadas, Y.; Gurovich, V. Tz.; Felsteiner, J.

    2009-05-01

    There is a continuous interest in research of electron sources which can be used for generation of uniform electron beams produced at E ≤105 V/cm and duration ≤10-5 s. In this review, several types of plasma electron sources will be considered, namely, passive (metal ceramic, velvet and carbon fiber with and without CsI coating, and multicapillary and multislot cathodes) and active (ferroelectric and hollow anodes) plasma sources. The operation of passive sources is governed by the formation of flashover plasma whose parameters depend on the amplitude and rise time of the accelerating electric field. In the case of ferroelectric and hollow-anode plasma sources the plasma parameters are controlled by the driving pulse and discharge current, respectively. Using different time- and space-resolved electrical, optical, spectroscopical, Thomson scattering and x-ray diagnostics, the parameters of the plasma and generated electron beam were characterized.

  19. Design and initial results from a kilojoule level dense plasma focus with hollow anode and cylindrically symmetric gas puff

    Science.gov (United States)

    Ellsworth, J. L.; Falabella, S.; Tang, V.; Schmidt, A.; Guethlein, G.; Hawkins, S.; Rusnak, B.

    2014-01-01

    We have designed and built a Dense Plasma Focus (DPF) Z-pinch device using a kJ-level capacitor bank and a hollow anode, and fueled by a cylindrically symmetric gas puff. Using this device, we have measured peak deuteron beam energies of up to 400 keV at 0.8 kJ capacitor bank energy and pinch lengths of ˜6 mm, indicating accelerating fields greater than 50 MV/m. Neutron yields of on the order of 107 per shot were measured during deuterium operation. The cylindrical gas puff system permitted simultaneous operation of DPF with a radiofrequency quadrupole accelerator for beam-into-plasma experiments. This paper describes the machine design, the diagnostic systems, and our first results.

  20. Investiagtion of Nanoscale Carbon Nitride Thin Films Grown Using DC HCD Hollow Cathode Discharge%用直流中空阴极放电方法(DC HCD)生长的纳米级碳的氮化物薄膜研究

    Institute of Scientific and Technical Information of China (English)

    YAN Y.H.; SHI Y.C.; YANG P.; TANG X.L.; FENG P.X.

    2005-01-01

    There is growing interest in the underlying physical processes in optoelectronic devices based on thin-film multilayer structures. Recently, many investigators have made great efforts on synthesizing the ultra - hard nanoscale carbon nitride thin films. Considering low cost and simple configuration, we used DC hollow cathode discharge (HCD) for deposition of nanoscale carbon nitride thin films.

  1. Mixed matrix hollow fiber membranes for removal of protein-bound toxins from human plasma

    NARCIS (Netherlands)

    Tijink, M.S.L.; Wester, M.; Glorieux, G.; Gerritsen, K; Sun, J.; Swart, P.C.; Borneman, Z.; Wessling, M.; Vanholder, R.; Joles, J.A.; Stamatialis, D.

    2013-01-01

    In end stage renal disease (ESRD) waste solutes accumulate in body fluid. Removal of protein bound solutes using conventional renal replacement therapies is currently very poor while their accumulation is associated with adverse outcomes in ESRD. Here we investigate the application of a hollow fiber

  2. Simulation of the atomic and ionic densities in the ionization layer of a plasma arc with a binary cathode

    Energy Technology Data Exchange (ETDEWEB)

    Ortega, D; Marin, J A Sillero; Munoz-Serrano, E; Casado, E, E-mail: f92orhed@uco.e [Departamento de Fisica, Universidad de Cordoba, 14071 Cordoba (Spain)

    2009-04-21

    A physical model was developed to study the behaviour of the cathode material evaporated from a thoriated tungsten cathode of an atmospheric-pressure argon plasma arc. The densities of tungsten and thorium atoms and ions in the ionization layer were obtained, and the influence of the different physical processes on the evaporated cathode material was established. It was found that almost all of the neutral atoms evaporated from the cathode are ionized near the beginning of the ionization layer, i.e. near the boundary between the sheath and the ionization layer. Thorium ions are concentrated in a 4 {mu}m region near the beginning of this layer, while tungsten ions are found in a region of 9 {mu}m. The contribution of the electric force to the velocity of ions is the dominant contribution only near the beginning of the ionization layer. At a distance from the interface between the sheath and the ionization layer greater than 3.8 {mu}m in the case of thorium ions, and greater than 5 {mu}m in the case of tungsten ions, the contributions of the density gradient forces and the frictional forces are more important than the electric force contribution.

  3. Influence of argon fraction on plasma parameters in H2-N2 mixture discharge with cathodic cage

    Science.gov (United States)

    Naeem, Muhammad; Zaka-ul-Islam, Mujahid; Khattak, Zahid Iqbal; Shafiq, Muhammad; Zakaullah, Muhammad

    2017-01-01

    Low-pressure H2-N2 mixture pulsed DC plasmas with a cathodic cage (active screen) are widely used for plasma nitriding applications. In this study, the low-pressure H2-N2 mixture plasma with a cathodic cage generated by 50 Hz pulsed DC source is investigated with triple Langmuir probe and optical emission spectroscopy. The electron temperature (TeLP T e LP ) and electron number density (ne) are measured using a triple Langmuir probe (TLP). The excitation temperature (TexcOES T e xc OES ) is calculated spectroscopically using Boltzmann plot method whereas nitrogen dissociation fraction is estimated using actinometry as well as the intensity ratio method (IN (746.83 nm)/IN2(337.1 nm)). The results show that the electron and excitation temperatures, electron density and nitrogen atomic species density [N] all increase with the argon admixture, however, the important molecular ionized species density [N2+ N 2 + ] significantly decreases beyond 30% addition. This study provides useful information about the influence of the argon addition on plasma parameters and active species generation. As a result it helps to optimize the plasma nitriding system as a function of argon admixture to avoid random trials in the processing.

  4. Development of hollow anode penning ion source for laboratory application

    Science.gov (United States)

    Das, B. K.; Shyam, A.; Das, R.; Rao, A. D. P.

    2012-03-01

    The research work presented here focuses for the development of miniature penning type ion source. One hollow anode penning type ion source was developed in our laboratory. The size of the ion source is 38 mm diameter and 55 mm length. The ion source consists of two cathodes, a hollow anode and one piece of rare earth permanent magnet. The plasma was created in the plasma region between cathodes and the hollow anode. The J × B force in the region helps for efficient ionization of the gas even in the high vacuum region˜1×10 -5 Torr. The ions were extracted in the axial direction with help of the potential difference between the electrodes and the geometry of the extraction angle. The effect of the extraction electrode geometry for efficient extraction of the ions from the plasma region was examined. This ion source is a self extracted ion source. The self extracted phenomena reduce the cost and the size of the ion source. The extracted ion current was measured by a graphite probe. An ion current of more than 200 μA was observed at the probe placed 70 mm apart from the extraction electrode. In this paper, the structure of the ion source, effect of operating pressure, potential difference and the magnetic field on the extracted ion current is reported.

  5. Phenomenology of plasma engine cathodes at high current rates and low pressures

    Science.gov (United States)

    Huegel, H.; Kruelle, G.

    1984-01-01

    The effects of low surrounding pressures on cathodes of arc jet engines with electromagnetic acceleration are investigated for pressure and current energies of 20 to 100 Torr. and 400 to 1000 A. Experiments with 50 mm long and 8 mm diameter tungsten-thorium cathode in a coaxial gas flow show that pre-heating of the cathode reduces the duration of the instable arc discharge and thus material loss. The use of lighter gases also reduces instability effects, as well as the use of increased pressures and a massive gas influx.

  6. Direct fabrication of metal-free hollow graphene balls with a self-supporting structure as efficient cathode catalysts of fuel cell

    Science.gov (United States)

    Lu, Yanqi; Liu, Mingda; Nie, Huagui; Gu, Cancan; Liu, Ming; Yang, Zhi; Yang, Keqin; Chen, Xi'an; Huang, Shaoming

    2016-06-01

    Despite the good progress in developing carbon catalysts for oxygen reduction reaction (ORR), the current metal-free carbon catalysts are still far from satisfactory for large-scale applications of fuel cell. Developing hollow graphene balls with a self-supporting structure is considered to be an ideal method to inhibit graphene stacking and improve their catalytic performance. Herein, we fabricated metal-free hollow graphene balls with a self-supporting structure, through using a new strategy that involves direct metal-free catalytic growth from assembly of SiO2 spheres. To our knowledge, although much researches involving the synthesis of graphene balls have been reported, investigations into the direct metal-free catalytic growth of hollow graphene balls are rare. Furthermore, the electrocatalytic performance shows that the resulting hollow graphene balls have significantly high catalytic activity. More importantly, such catalysts also possess much improved stability and better methanol tolerance in alkaline media during the ORR compared with commercial Pt/C catalysts. The outstanding performances coupled with an easy and inexpensive preparing method indicated the great potential of the hollow graphene balls with a self-supporting structure in large-scale applications of fuel cell.

  7. Ion angular distribution in plasma of vacuum arc ion source with composite cathode and elevated gas pressure.

    Science.gov (United States)

    Nikolaev, A G; Savkin, K P; Yushkov, G Yu; Oks, E M

    2014-02-01

    The Metal Vapor Vacuum Arc (MEVVA) ion sources are capable of generating ion beams of almost all metals of the periodic table. For this kind of ion source, a combination of gas feeding with magnetic field allows the simultaneous generation of both metal and gaseous ions. That makes the MEVVA ion source an excellent instrument for science and application. This work presents results of investigation for ion angular distributions in vacuum arc plasma of Mevva-V.Ru ion source for composite cathodes and for elevated gas pressure. It was shown that for all the cathode materials, singly charged ions have wider angular distribution than multiply charged ions. Increasing the working gas pressure leads to a significant change in the angular distribution of gaseous ions, while with the distribution of metal ions gas remains practically unchanged. The reasons for such different influences are discussed.

  8. Influence of gas pressure on electron beam emission current of pulsed cathodic-arc-based forevacuum plasma electron source

    Science.gov (United States)

    Burdovitsin, Victor A.; Kazakov, Andrey V.; Medovnik, Alexander V.; Oks, Efim M.

    2017-09-01

    We describe our experimental investigation of the effect of background gas pressure on the emission parameters of a pulsed cathodic-arc-based forevacuum-pressure plasma-cathode electron source. We find that increased gas pressure over the range 4-16 Pa significantly reduces the beam current rise-time and significantly increases the emission current amplitude. For example, at a discharge current of 20 A, increasing the working gas pressure from 4 Pa to 16 Pa increases the emission current from 8 A to 18 A and shortens the beam rise-time from 50 μs to 20 μs. This influence of gas pressure on the electron beam parameters can be explained by the effect of arc discharge current switching from the anode to emission. In our case, the current switching effect is caused by increased working gas pressure. In the forevacuum pressure range, the increase of the electron emission current with the growth of gas pressure is due to a rise in the emission plasma potential which is caused by ion back-streaming from the plasma formed in the electron beam transport region. A model describing the influence of gas pressure on the electron emission from the plasma is presented.

  9. Energetic Ion Mitigation Methodology for High Power Plasma Thruster Cathodes Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The presence of energetic ions, that appear under high cathode current operation, stand as a showstopper to the realization of high power electric propulsion....

  10. Microhollow cathode discharges

    Science.gov (United States)

    Schoenbach, K. H.; Moselhy, M.; Shi, W.; Bentley, R.

    2003-07-01

    By reducing the dimensions of hollow cathodes into the hundred micrometer range, stable, direct current, high (atmospheric) pressure glow discharges in rare gases, rare gas-halide mixtures and in air could be generated. The electron energy distribution in these microdischarges is non-Maxwellian, with a pronounced high-energy tail. The high electron energy together with the high gas density, which favors three-body collisions, is the reason for an efficient excimer generation in these microplasmas. Excimer efficiencies from 1% to 9% have been measured for argon, xenon, argon fluoride, and xenon chloride direct current excimer emitters, with a radiant excimer emittance of up to 2 W/cm2 for xenon. Adding small amounts of oxygen to argon has allowed us to generate vacuum ultraviolet line radiation at 130.5 nm with an efficiency approaching 1%. Pulsing xenon discharges with nanosecond electrical pulses has led to an increase in intensity to 15 W/cm2 and to a simultaneous increase in efficiency to more than 20%. Operating the discharges in an abnormal glow mode has allowed us to generate microdischarge arrays without individual ballast. Applications of these plasma arrays are excimer lamps and plasma reactors.

  11. Investigations of the cathode region of an argon arc plasma by degenerate four-wave mixing laser spectroscopy and optical emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Dzierzega, K [Marian Smoluchowski Institute of Physics, Jagiellonian University, ul. Reymonta 4, 30-059 Cracow (Poland); Pokrzywka, B [Mt. Suhora Observatory, Cracow Pedagogical University, ul. Podchorazych 2, 30-083 Cracow (Poland); Pellerin, S [LASEP, Universite d' Orleans-Centre Universitaire de Bourges, Rue Gaston Berger BP 4043, 18028 Bourges (France)

    2004-07-07

    Degenerate four-wave mixing (DFWM) laser spectroscopy was used in local studies of atmospheric pressure argon plasma generated in a free-burning arc. The results of plasma diagnostics using the DFWM method were compared to the results obtained with optical emission measurements. In the cathode region of the arc the maxima of both the DFWM signal and the emission coefficient for the 696.5 nm Ar I line depend on the distance from the cathode tip. This effect proves the departure of the plasma state from local thermal equilibrium (LTE) as it has been reported by many authors. On the other hand the Stark shifts of the 696.5 nm Ar I line determined by the DFWM method in relation to plasma diagnostic results show no deviations from LTE on the arc axis down to 1.0 mm from the cathode tip.

  12. Ion sources with arc-discharge plasma box driven by directly heated LaB(6) electron emitter or cold cathode.

    Science.gov (United States)

    Ivanov, Alexander A; Davydenko, Vladimir I; Deichuli, Petr P; Shulzhenko, Grigori I; Stupishin, Nikolay V

    2008-02-01

    In the Budker Institute, Novosibirsk, an ion source with arc-discharge plasma box has been developed in the recent years for application in thermonuclear devices for plasma diagnostics. Several modifications of the ion source were provided with extracted current ranging from 1 to 7 A and pulse duration of up to 4 s. Initially, the arc-discharge plasma box with cold cathode was used, with which pulse duration is limited to 2 s by the cathode overheating and sputtering in local arc spots. Recently, a directly heated LaB(6) electron emitter was employed instead, which has extended lifetime compared to the cold cathode. In the paper, characteristics of the beam produced with both arrangements of the plasma box are presented.

  13. A Microfiltration Polymer-Based Hollow-Fiber Cathode as a Promising Advanced Material for Simultaneous Recovery of Energy and Water

    KAUST Repository

    Katuri, Krishna

    2016-09-12

    A novel electrocatalytic and microfiltration polymeric hollow fiber is fabricated for simultaneous recovery of energy (H2) and clean fresh water from wastewater, hence addressing two grand challenges facing society in the current century (i.e., providing adequate supplies of clean fresh water and energy as the world\\'s population increases).

  14. Hierarchical LiMn2O4 Hollow Cubes with Exposed {111} Planes as High-Power Cathodes for Lithium-Ion Batteries.

    Science.gov (United States)

    Wu, Yu; Cao, Chuanbao; Zhang, Junting; Wang, Lin; Ma, Xilan; Xu, Xingyan

    2016-08-01

    Hierarchical LiMn2O4 hollow cubes with exposed {111} planes have been synthesized using cube-shaped MnCO3 precursors, which are fabricated through a facile co-precipitation reaction. Without surface modification, the as-prepared LiMn2O4 exhibits excellent cyclability and superior rate capability. Surprisingly, even over 70% of primal discharge capacity can be maintained for up to 1000 cycles at 50 C, and with only about 72 s of discharge time the as-prepared materials can deliver initial discharge capacity of 96.5 mA h g(-1). What is more, the materials have 98.4% and 90.7% capacity retentions for up to 100 cycles at 5 C under the temperatures of 25 and 60 °C, respectively. The superior electrochemical performance can be attributed to the unique hierarchical and interior hollow structure, exposed {111} planes, and high-quality crystallinity.

  15. Cauliflower-like SnO2 hollow microspheres as anode and carbon fiber as cathode for high performance quantum dot and dye-sensitized solar cells

    Science.gov (United States)

    Ganapathy, Veerappan; Kong, Eui-Hyun; Park, Yoon-Cheol; Jang, Hyun Myung; Rhee, Shi-Woo

    2014-02-01

    Cauliflower-like tin oxide (SnO2) hollow microspheres (HMS) sensitized with multilayer quantum dots (QDs) as photoanode and alternative stable, low-cost counter electrode are employed for the first time in QD-sensitized solar cells (QDSCs). Cauliflower-like SnO2 hollow spheres mainly consist of 50 nm-sized agglomerated nanoparticles; they possess a high internal surface area and light scattering in between the microspheres and shell layers. This makes them promising photoanode material for both QDSCs and dye-sensitized solar cells (DSCs). Successive ionic layer adsorption and reaction (SILAR) method and chemical bath deposition (CBD) are used for QD-sensitizing the SnO2 microspheres. Additionally, carbon-nanofiber (CNF) with a unique structure is used as an alternative counter electrode (CE) and compared with the standard platinum (Pt) CE. Their electrocatalytic properties are measured using electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and Tafel-polarization. Under 1 sun illumination, solar cells made with hollow SnO2 photoanode sandwiched with the stable CNF CE showed a power conversion efficiency of 2.5% in QDSCs and 3.0% for DSCs, which is quite promising with the standard Pt CE (QDSCs: 2.1%, and DSCs: 3.6%).Cauliflower-like tin oxide (SnO2) hollow microspheres (HMS) sensitized with multilayer quantum dots (QDs) as photoanode and alternative stable, low-cost counter electrode are employed for the first time in QD-sensitized solar cells (QDSCs). Cauliflower-like SnO2 hollow spheres mainly consist of 50 nm-sized agglomerated nanoparticles; they possess a high internal surface area and light scattering in between the microspheres and shell layers. This makes them promising photoanode material for both QDSCs and dye-sensitized solar cells (DSCs). Successive ionic layer adsorption and reaction (SILAR) method and chemical bath deposition (CBD) are used for QD-sensitizing the SnO2 microspheres. Additionally, carbon-nanofiber (CNF) with a

  16. Enhancing the plasma illumination behaviour of microplasma devices using microcrystalline/ultra-nanocrystalline hybrid diamond materials as cathodes.

    Science.gov (United States)

    Chang, Tinghsun; Lou, Shiucheng; Chen, Huangchin; Chen, Chulung; Lee, Chiyoung; Tai, Nyanhwa; Lin, Inan

    2013-08-21

    The properties of capacity-type microplasma devices were significantly enhanced due to the utilisation of hybrid diamond films as cathodes. The performance of the microplasma devices was closely correlated with the electron field emission (EFE) properties of the diamond cathode materials. The nanoemitters, which were prepared by growing duplex-structured diamond films [microcrystalline diamond (MCD)/ultra-nanocrystalline diamond (UNCD)] on Si-pyramid templates via a two-step microwave plasma enhanced chemical vapour deposition (MPE-CVD) process, exhibited improved EFE properties (E0 = 5.99 V μm(-1), J(e) = 1.10 mA cm(-2) at 8.50 V μm(-1) applied field), resulting in superior microplasma device performance (with a lower threshold field of 200 V mm(-1) and a higher plasma current density of 7.80 mA cm(-2)) in comparison with UNCD film devices prepared using a single-step MPE-CVD process. The superior EFE properties of the duplex-structured MCD-UNCD films relative to those of the UNCD films can be attributed to the unique granular structure of the diamond films. High-resolution transmission electron microscopy reveals that the MCD-UNCD films consisted of abundant graphitic phases located at the periphery of large diamond aggregates and at the boundaries between the ultra-small diamond grains. The presence of the graphite phase is presumed to be the prime factor that renders these films more conductive and causes these films to exhibit higher EFE properties, thus resulting in the improved plasma illumination properties of the microplasma devices.

  17. Effect of particle size on the polycrystalline CeB6 cathode prepared by spark plasma sintering

    Institute of Scientific and Technical Information of China (English)

    BAO Lihong; ZHANG Jiuxing; ZHOU Shenlin

    2011-01-01

    The full densification polycrystalline cerium hexaboride (CeB6) cathode material was prepared by using the spark plasma sintering (SPS) method in an oxygen free system. The starting precursor nanopowders with an average grain size of 50 nm were prepared by high-energy ball milling. The ball-milled nanopowder was fully densified at 1550 ℃ under 50 MPa, which was about 350 ℃ lower than the conventional hot-pressing method and it was also lower than that of coarse powder under the same sintering condition. The mechanical properties of nanopowder sintered samples were significantly better than that of coarse powder, e.g., the flexural strength and Vickers hardness were 211% and 51% higher than that of coarse powder, respectively. The electron backscattered diffraction (EBSD) result showed that the (100) fiber texture could be fabricated by the ball-milled nanopowder sintered at 1550 ℃ and the thermionic emission current density was measured to be 16.04 A/cm2 at a cathode temperature of 1873 K.

  18. Materials characterization of impregnated W and W–Ir cathodes after oxygen poisoning

    Energy Technology Data Exchange (ETDEWEB)

    Polk, James E., E-mail: james.e.polk@jpl.nasa.gov [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Dr., Pasadena, CA 91109 (United States); Capece, Angela M. [California Institute of Technology, 1200 E. California Blvd., Pasadena, CA 91125 (United States)

    2015-05-30

    Highlights: • Impregnated W and W–Ir cathodes were operated with 100 ppm of oxygen in Xe gas. • High concentrations of oxygen accelerated the formation of tungstate layers. • The W–Ir emitter exhibited less erosion and redeposition at the upstream end. • Tungsten was preferentially transported in the insert plasma of the W–Ir cathode. - Abstract: Electric thrusters use hollow cathodes as the electron source for generating the plasma discharge and for beam neutralization. These cathodes contain porous tungsten emitters impregnated with BaO material to achieve a lower surface work function and are operated with xenon propellant. Oxygen contaminants in the xenon plasma can poison the emitter surface, resulting in a higher work function and increased operating temperature. This could lead directly to cathode failure by preventing discharge ignition or could accelerate evaporation of the BaO material. Exposures over hundreds of hours to very high levels of oxygen can result in increased temperatures, oxidation of the tungsten substrate, and the formation of surface layers of barium tungstates. In this work, we present results of a cathode test in which impregnated tungsten and tungsten–iridium emitters were operated with 100 ppm of oxygen in the xenon plasma for several hundred hours. The chemical and morphological changes were studied using scanning electron microscopy, energy dispersive spectroscopy, and laser profilometry. The results provide strong evidence that high concentrations of oxygen accelerate the formation of tungstate layers in both types of emitters, a phenomenon not inherent to normal cathode operation. Deposits of pure tungsten were observed on the W–Ir emitter, indicating that tungsten is preferentially removed from the surface and transported in the insert plasma. A W–Ir cathode surface will therefore evolve to a pure W composition, eliminating the work function benefit of W–Ir. However, the W–Ir emitter exhibited less erosion

  19. Cathodic cage plasma deposition of TiN and TiO{sub 2} thin films on silicon substrates

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, Romulo R. M. de [Department of Mechanics, Federal Institute of Education, Science, and Technology of Piaui, Praça da Liberdade, 1597, CEP 64000-040 Teresina, Piaui, Brazil and Department of Mechanical Engineering, Federal University of Piaui, Campus Min. Petronio Portela, Ininga, CEP 64049-550 Teresina, Piaui (Brazil); Sato, Patricia S.; Nascente, Pedro A. P., E-mail: nascente@ufscar.br [Department of Materials Engineering, Federal University of Sao Carlos, Via Washington Luis km 235, CEP 13565-905 Sao Carlos, Sao Paulo (Brazil); Viana, Bartolomeu C. [Department of Physics, Federal University of Piaui, Campus Min. Petronio Portela, Ininga, CEP 64049-550 Teresina, Piaui (Brazil); Alves, Clodomiro [Department of Exact and Natural Sciences, Federal Rural University of Semi Arido, Avenida Francisco Mota, 572, CEP 59625-900 Mossoro, Rio Grande do Norte (Brazil); Nishimoto, Akio [Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, 3-3-35 Yamate-cho, Suita, Osaka 564-8680 (Japan)

    2015-07-15

    Cathodic cage plasma deposition (CCPD) was used for growing titanium nitride (TiN) and titanium dioxide (TiO{sub 2}) thin films on silicon substrates. The main advantages of the CCPD technique are the uniformity, tridimensionality, and high rate of the film deposition that occurs at higher pressures, lower temperatures, and lower treatment times than those used in conventional nitriding treatments. In this work, the influence of the temperature and gas atmosphere upon the characteristics of the deposited films was investigated. The TiN and TiO{sub 2} thin films were characterized by x-ray diffraction, scanning electron microscopy, and Raman spectroscopy to analyze their chemical, structural, and morphological characteristics, and the combination of these results indicates that the low-cost CCPD technique can be used to produce even and highly crystalline TiN and TiO{sub 2} films.

  20. Porous-Al2O3 thermal barrier coatings with dispersed Pt particles prepared by cathode plasma electrolytic deposition

    Institute of Scientific and Technical Information of China (English)

    Jin Zhang

    2016-01-01

    Porousa-Al2O3 thermal barrier coatings (TBCs) containing dispersed Pt particles were prepared by cathode plasma electrolytic deposition (CPED). The influence of the Pt particles on the microstructure of the coatings and the CPED process were studied. The prepared coatings were mainly composed ofα-Al2O3. The average thickness of the coatings was approximately 100μm. Such single-layer TBCs ex-hibited not only excellent high-temperature cyclic oxidation and spallation resistance, but also good thermal insulation properties. Porousa-Al2O3 TBCs inhibit further oxidation of alloy substrates because of their extremely low oxygen diffusion rate, provide good thermal insu-lation because of their porous structure, and exhibit excellent mechanical properties because of the toughening effect of the Pt particles and because of stress relaxation induced by deformation of the porous structure.

  1. Electron beam treatment of non-conducting materials by a fore-pump-pressure plasma-cathode electron beam source

    Energy Technology Data Exchange (ETDEWEB)

    Burdovitsin, V A; Klimov, A S; Medovnik, A V; Oks, E M, E-mail: burdov@fet.tusur.r [Tomsk State University of Control Systems and Radioelectronics, 634050, 40 Lenin Ave., Tomsk (Russian Federation)

    2010-10-15

    In the irradiation of an insulated target by an electron beam produced by a plasma-cathode electron beam source operating in the fore-vacuum pressure range (5-15 Pa), the target potential is much lower than the electron beam energy, offering the possibility of direct electron treatment of insulating materials. It is found that in the electron beam irradiation of a non-conducting target in a moderately high pressure range, the electron charge on the target surface is neutralized mainly by ions from a volume discharge established between the negatively charged target surface and the grounded walls of the vacuum chamber. This allows the possibility of direct electron beam treatment (heating, melting, welding) of ceramics and other non-conducting and semiconductor materials.

  2. Formation and stability of a hollow electron beam in the presence of a plasma wake field driven by an ultra-short electron bunch

    Energy Technology Data Exchange (ETDEWEB)

    Tanjia, F., E-mail: tanjia.fatema@gmail.com [Dipartimento di Fisica, Universià di Napoli “Federico II” (Italy); INFN Sezione di Napoli (Italy); Fedele, R. [Dipartimento di Fisica, Universià di Napoli “Federico II” (Italy); INFN Sezione di Napoli (Italy); De Nicola, S. [Dipartimento di Fisica, Universià di Napoli “Federico II” (Italy); INFN Sezione di Napoli (Italy); CNR-SPIN, Complesso Universitario di Monte S' Angelo, Napoli (Italy); Akhter, T. [Dipartimento di Fisica, Universià di Napoli “Federico II” (Italy); INFN Sezione di Napoli (Italy); Jovanović, D. [Institute of Physics, University of Belgrade, Belgrade (Serbia)

    2016-09-01

    A numerical investigation on the spatiotemporal evolution of an electron beam, externally injected in a plasma in the presence of a plasma wake field, is carried out. The latter is driven by an ultra-short relativistic axially-symmetric femtosecond electron bunch. We first derive a novel Poisson-like equation for the wake potential where the driving term is the ultra-short bunch density, taking suitably into account the interplay between the sharpness and high energy of the bunch. Then, we show that a channel is formed longitudinally, through the externally injected beam while experiencing the effects of the bunch-driven plasma wake field, within the context of thermal wave model. The formation of the channel seems to be a final stage of the 3D evolution of the beam. This involves the appearance of small filaments and bubbles around the longitudinal axis. The bubbles coalesce forming a relatively stable axially-symmetric hollow beam structure. - Highlights: • A novel Poisson-like equation for the wake potential driven by the ultra-short bunch density is derived in the context of PWF theory. • The spatiotemporal evolution of another externally injected electron beam in the presence plasma wake field is numerically investigated. • A channel is formed longitudinally, through the externally injected beam while experiencing the effects of the bunch-driven plasma wake field. • A relatively stable axially symmetric hollow beam structure is formed through the evolution.

  3. Green hydrophilic modification of PE hollow fiber membranes in a module scale via long-distance and dynamic low-temperature H2O plasma flow

    Science.gov (United States)

    Li, Mei-Sheng; Zhao, Zhi-Ping; Wang, Ming-Xing

    2016-11-01

    A green chemistry process, long-distance and dynamic low-temperature (LDDLT) H2O plasma, was developed to modify PE hollow fiber membranes in a module scale using our modified LDDLT plasma setup. The modification degree of LDDLT-H2O plasma was 2 times greater than that of Ar plasma, but the effective treatment distance achieved by LDDLT-Ar plasma was about two times of that obtained by LDDLT-H2O plasma (22 cm). Under the suitable conditions, the effective treatment distance can reach over 54 cm after LDDLT-H2O plasma treatment from the double inlets, closed to some industrial module sizes. The improvement in surface hydrophilicity was because of the introduction of numerous oxygen-containing groups. High concentrations of OH radicals in H2O plasma played a major role in the membrane surface hydroxylation. This directly resulted in a great enhancement in the pure water flux. It increased from about 6 L m-2 h-1 to 45 L m-2 h-1 after treatment. Also, the H2O plasma-treated membrane module exhibited good hydrophilic stability during 285 days storage.

  4. Accuracy assessment on the analysis of unbound drug in plasma by comparing traditional centrifugal ultrafiltration with hollow fiber centrifugal ultrafiltration and application in pharmacokinetic study.

    Science.gov (United States)

    Zhang, Lin; Zhang, Zhi-Qing; Dong, Wei-Chong; Jing, Shao-Jun; Zhang, Jin-Feng; Jiang, Ye

    2013-11-29

    In present study, accuracy assessment on the analysis of unbound drug in plasma was made by comparing traditional centrifugal ultrafiltration (CF-UF) with hollow fiber centrifugal ultrafiltration (HFCF-UF). We used metformin (MET) as a model drug and studied the influence of centrifugal time, plasma condition and freeze-thaw circle times on the ultrafiltrate volume and related effect on the measurement of MET. Our results demonstrated that ultrafiltrate volume was a crucial factor which influenced measurement accuracy of unbound drug in plasma. For traditional CF-UF, the ultrafiltrate volume cannot be well-controlled due to a series of factors. Compared with traditional CF-UF, the ultrafiltrate volume by HFCF-UF can be easily controlled by the inner capacity of the U-shaped hollow fiber inserted into the sample under enough centrifugal force and centrifugal time, which contributes to a more accurate measurement. Moreover, the developed HFCF-UF method achieved a successful application in real plasma samples and exhibited several advantages including high precision, extremely low detection limit and perfect recovery. The HFCF-UF method offers the advantage of highly satisfactory performance in addition to being simple and fast in pretreatment, with these characteristics being consistent with the practicability requirements in current scientific research.

  5. Investigation of micro-structure and micro-hardness properties of 304L stainless steel treated in a hot cathode arc discharge plasma

    Energy Technology Data Exchange (ETDEWEB)

    Malik, Hitendra K., E-mail: hkmalik@physics.iitd.ac.in [Department of Physics, Indian Institute of Technology Delhi, New Delhi – 110016 (India); Singh, Omveer [Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi – 110016 (India); Dahiya, Raj P. [Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi – 110016 (India); Deenbandhu Chhotu Ram University of Science and Technology, Murthal–131039 (India)

    2015-08-28

    We have established a hot cathode arc discharge plasma system, where different stainless steel samples can be treated by monitoring the plasma parameters and nitriding parameters independently. In the present work, a mixture of 70% N{sub 2} and 30% H{sub 2} gases was fed into the plasma chamber and the treatment time and substrate temperature were optimized for treating 304L Stainless Steel samples. Various physical techniques such as x-ray diffraction, energy dispersive x-ray spectroscopy and micro-vickers hardness tester were employed to determine the structural, surface composition and surface hardness of the treated samples.

  6. Investigation of micro-structure and micro-hardness properties of 304L stainless steel treated in a hot cathode arc discharge plasma

    Science.gov (United States)

    Malik, Hitendra K.; Singh, Omveer; Dahiya, Raj P.

    2015-08-01

    We have established a hot cathode arc discharge plasma system, where different stainless steel samples can be treated by monitoring the plasma parameters and nitriding parameters independently. In the present work, a mixture of 70% N2 and 30% H2 gases was fed into the plasma chamber and the treatment time and substrate temperature were optimized for treating 304L Stainless Steel samples. Various physical techniques such as x-ray diffraction, energy dispersive x-ray spectroscopy and micro-vickers hardness tester were employed to determine the structural, surface composition and surface hardness of the treated samples.

  7. Beam loading in the bubble regime in plasmas with hollow channels

    Science.gov (United States)

    Golovanov, A. A.; Kostyukov, I. Yu.; Thomas, J.; Pukhov, A.

    2016-09-01

    Based on the already existing analytical theory of the strong nonlinear wakefield (which is called "bubble") in transversely inhomogeneous plasmas, we study the particular behavior of non-loaded (empty) bubbles and bubbles with accelerated bunches. We obtain an analytical expression for the shape of a non-loaded bubble in a general case and verify it with particle-in-cell (PIC) simulations. We derive a method of calculating the acceleration efficiency for arbitrary accelerated bunches. The influence of flat-top electron bunches on the shape of a bubble is studied. It is also shown that it is possible to achieve the acceleration in a homogeneous longitudinal electric field by the adjustment of the longitudinal density profile of the accelerated electron bunch. The predictions of the model are verified by 3D PIC simulations and are in a good agreement with them.

  8. Beam loading in the bubble regime in plasmas with hollow channels

    CERN Document Server

    Golovanov, A A; Thomas, J; Pukhov, A

    2016-01-01

    Based on the already existing analytical theory of the strongly-nonlinear wakefield (which is called "bubble") in transversely inhomogeneous plasmas, we study particular behavior of non-loaded (empty) bubbles and bubbles with accelerated bunches. We obtain an analytical expression for the shape of a non-loaded bubble in a general case and verify it with particle-in-cell (PIC) simulations. We derive a method of calculation of the acceleration efficiency for arbitrary accelerated bunches. The influence of flat-top electron bunches on the shape of a bubble is studied. It is also shown that it is possible to achieve acceleration in a homogeneous longitudinal electric field by the adjustment of the longitudinal density profile of the accelerated electron bunch. The predictions of the model are verified by 3D PIC simulations and are in a good agreement with them.

  9. Interaction of DC Microhollow Cathode Discharge Plasma Micro Jet with Liquid Media

    Science.gov (United States)

    Zhu, Weidong; Lopez, Jose; Becker, Kurt

    2008-10-01

    There have been different approaches in studying the interaction between plasma and liquid, such as sustained plasmas in contact with liquids and pulsed electric discharge in liquids. Recently, we have discovered that stable plasma can be sustained within a gas cavity maintained inside liquid media. A prototype device with key dimensions in sub-millimeter range were operated successfully in de-ionized water and turbo molecular pump oil with ambient air, pure nitrogen or pure oxygen used as the operating gas. Hydrogen Peroxide production in de-ionized water with ambient air as the working gas is estimated to be about 80 mg/L after 15 minutes plasma jet-water interaction while energy consumption is only about 8-10 W. With the radicals readily generated and directly introduced into the liquid media, it could lead to applications such as in-liquid bio-waste treatment, bio-rich liquid modification, in-situ monitoring/sensing, and filtration of by-products from VOC treatment by plasma.

  10. Highly Durable Supportless Pt Hollow Spheres Designed for Enhanced Oxygen Transport in Cathode Catalyst Layers of Proton Exchange Membrane Fuel Cells.

    Science.gov (United States)

    Dogan, Didem C; Cho, Seonghun; Hwang, Sun-Mi; Kim, Young-Min; Guim, Hwanuk; Yang, Tae-Hyun; Park, Seok-Hee; Park, Gu-Gon; Yim, Sung-Dae

    2016-10-10

    Supportless Pt catalysts have several advantages over conventional carbon-supported Pt catalysts in that they are not susceptible to carbon corrosion. However, the need for high Pt loadings in membrane electrode assemblies (MEAs) to achieve state-of-the-art fuel cell performance has limited their application in proton exchange membrane fuel cells. Herein, we report a new approach to the design of a supportless Pt catalyst in terms of catalyst layer architecture, which is crucial for fuel cell performance as it affects water management and oxygen transport in the catalyst layers. Large Pt hollow spheres (PtHSs) 100 nm in size were designed and prepared using a carbon template method. Despite their large size, the unique structure of the PtHSs, which are composed of a thin-layered shell of Pt nanoparticles (ca. 7 nm thick), exhibited a high surface area comparable to that of commercial Pt black (PtB). The PtHS structure also exhibited twice the durability of PtB after 2000 potential cycles (0-1.3 V, 50 mV/s). A MEA fabricated with PtHSs showed significant improvement in fuel cell performance compared to PtB-based MEAs at high current densities (>800 mA/cm(2)). This was mainly due to the 2.7 times lower mass transport resistance in the PtHS-based catalyst layers compared to that in PtB, owing to the formation of macropores between the PtHSs and high porosity (90%) in the PtHS catalyst layers. The present study demonstrates a successful example of catalyst design in terms of catalyst layer architecture, which may be applied to a real fuel cell system.

  11. Polarographic behaviour of loratadine and its direct determination in pharmaceutical formulation and human plasma by cathodic adsorptive stripping voltammetry.

    Science.gov (United States)

    Ghoneim, M M; Mabrouk, M M; Hassanein, A M; Tawfik, A

    2001-07-01

    The polarographic behaviour of the antihistaminic drug loratadine has been investigated in B.R. buffer solution of different pH values. Contradictory to that mentioned before in a previously published work, loratadine is electro-active at the mercury electrode. In B.R. buffer solution of pH values > or =6 it is reduced via a single 2-electrons irreversible wave corresponding to saturation of carbon-nitrogen double bond of the pyridine ring. The electrode reaction pathway was proposed and discussed. A sensitive differential pulse stripping voltammetric method based on controlled adsorptive accumulation of loratadine on a hanging mercury drop electrode has been developed for its direct determination at nanomolar concentrations without nitration of the drug. The optimized conditions for the direct cathodic adsorptive stripping voltammetric determination of the drug are: 0.1 M sodium hydroxide solution as a supporting electrolyte, accumulation potential, -1.2 V; accumulation time, 30 s; scan rate, 2-5 mV x s(-1) and pulse amplitude 100 mV. The proposed procedure was applied for the assay of loratadine in pharmaceutical formulation and human plasma. The average recoveries were 99.32-99.44 and 100.33-102.99% with the RSD 0.27-0.42 and 0.39-0.90% in pharmaceutical formulation and human plasma, respectively. The limits of detection of 1.60x10(-7) and 1.25x10(-7) M loratadine were found in pharmaceutical formulation and human plasma, respectively.

  12. Inorganic-solid-state electrolyte layer deposited by cathodic arc plasma for rapidly switching electrochromic device

    Science.gov (United States)

    Chen, Po-Wen; Chang, Chen-Te; Wu, Jin-Yu; Jan, Der-Jun; Li, Yu-Chen; Hsieh, Cheng-Chang; Tsai, Wen-Fa

    2017-08-01

    This work focuses on fabricating a solid electrolyte Ta2O5 thin film deposited by cathodic arc plasm (CAP) deposition through three different ratio of oxygen and argon. In our experiments, refractive index of Ta2O5 films are taken as 2.25, 1.96, 1.9 with various O2/Ar= 1.5, O2/Ar= 2, O2/Ar= 2.4, respectively. Our results show that the refractive index mostly decreased as we increase the oxygen flow rate, in which the minimum is found at 240 sccm. It provides good conduction pathways for ions through smaller thin-film's refractive index that exhibits more porosity voids. This property enhances ion's mobility for electrochromic device causing rapid coloring/bleaching phenomenon. Ta2O5 thin film is suitable as a solid electrolyte layer in center of electrochromic device (ECD) using CAP deposition. As a result, rapid response times were observed in fabricated device with an area of 5 cm×5 cm, exhibiting transmittance optical modulation ΔT = 61.5% (@550 nm) with the bleaching time τ = 8 s and transmittance optical modulation ΔT = 50% (@550 nm) with the coloring time τ = 10 s.

  13. Generation of low-temperature plasma by low-pressure arcs for synthesis of nitride coatings

    Science.gov (United States)

    Krysina, O. V.; Koval, N. N.; Lopatin, I. V.; Shugurov, V. V.; Kovalsky, S. S.

    2016-01-01

    Experiments were performed to study gas, metal, and mixed metal-gas plasmas. The plasmas were generated with the use of an arc evaporator and a gas-plasma source with a hot filament and hollow cathode that were operated independently or simultaneously. It has been revealed that the arc current of gas-plasma source affects the parameters of the metal-gas plasma and the element concentrations in the coatings. It has been demonstrated that the characteristics of the nitride coatings produced by plasma-assisted vacuum-arc deposition can be controlled by varying the parameters of the arc in the gas-plasma source.

  14. Formation and stability of a hollow electron beam in the presence of a plasma wake field driven by an ultra-short electron bunch

    CERN Document Server

    Tanjia, F; De Nicola, S; Akhter, T; Jovanovic, D

    2015-01-01

    A numerical investigation on the spatiotemporal evolution of an electron beam, externally injected in a plasma in the presence of a plasma wake field, is carried out. The latter is driven by an ultra-short relativistic axially-symmetric femtosecond electron bunch. We first derive a novel Poisson-like equation for the wake potential where the driving term is the ultra-short bunch density, taking suitably into account the interplay between the sharpness and high energy of the bunch. Then, we show that a channel is formed longitudinally, through the externally injected beam while experiencing the effects of the bunch-driven plasma wake field, within the context of thermal wave model. The formation of the channel seems to be a final stage of the 3D evolution of the beam. This involves the appearance of small filaments and bubbles around the longitudinal axis. The bubbles coalesce forming a relatively stable axially-symmetric hollow beam structure.

  15. Unified model to the Tungsten inert Gas welding process including the cathode, the plasma and the anode; Modele couple cathode-plasma-piece en vue de la simulation du procede de soudage a l'arc TIG

    Energy Technology Data Exchange (ETDEWEB)

    Brochard, M.

    2009-06-15

    During this work, a 2D axially symmetric model of a TIG arc welding process had been developed in order to predict for given welding parameters, the needed variables for a designer of welded assembly: the heat input on the work piece, the weld pool geometry,... The developed model, using the Cast3M finite elements software, deals with the physical phenomena acting in each part of the process: the cathode, the plasma, the work piece with a weld pool, and the interfaces between these parts. To solve this model, the thermohydraulics equations are coupled with the electromagnetic equations that are calculated in part using the least squares finite element method. The beginning of the model validation consisted in comparing the results obtained with the ones available in the scientific literature. Thus, this step points out the action of each force in the weld pool, the contribution of each heat flux in the energy balance. Finally, to validate the model predictiveness, experimental and numerical sensitivity analyses were conducted using a design of experiments approach. The effects of the process current, the arc gap and the electrode tip angle on the weld pool geometry and the energy transferred to the work piece and the arc efficiency were studied. The good agreement obtained by the developed model for these outputs shows the good reproduction of the process physics. (author)

  16. High heat flux plasma generator for new divertor plasma simulator in Nagoya University

    Energy Technology Data Exchange (ETDEWEB)

    Narita, S.; Ezumi, N.; Ohno, N.; Uesugi, Y.; Takamura, S. [Nagoya Univ. (Japan)

    1997-12-31

    A new divertor simulator called NAGDIS-II has been constructed in order to investigate edge plasma physics in fusion devices. Improved TP-D type plasma source, which consists of LaB{sub 6} cathode with a Mo hollow shield and external heating system, water-cooled intermediate electrode and anode was employed to make a high density plasma in the NAGDIS-II. The performance and reliability of the discharge system was confirmed by quantitatively measuring neutral pressure, heating efficiency and plasma parameters. (author)

  17. Morphology and Structure Properties of Boron-doped Diamond Films Prepared by Hot Cathode Direct Current Plasma Chemical Vapor Deposition

    Directory of Open Access Journals (Sweden)

    Mengmei PAN

    2016-05-01

    Full Text Available Boron-doped diamond (BDD films were deposited by hot cathode direct current plasma chemical vapor deposition (HCDC-PCVD according to various mixture ratios of CH4/H2/B(OCH33 gas. The Raman performances and surface morphologies of the BDD films were then characterized by Raman spectroscopy and scanning electron microscopy (SEM. Results indicated that the flow rate of B(OCH33 had marked effects on the growth characteristics of the produced boron-doped diamond films. The presence and concentration of the doped boron atoms significantly altered both the surface morphologies and structures of the diamond films. With increasing flow rate of B(OCH33, the crystal grain surfaces became smooth as visible under SEM. The B-doping levels in these films increased from 1.75×1019cm-3 to a maximum of 2.4×1021cm-3, estimated from the Raman spectra. DOI: http://dx.doi.org/10.5755/j01.ms.22.2.12923

  18. Vanadium Pentoxide-Based Composite Synthesized Using Microwave Water Plasma for Cathode Material in Rechargeable Magnesium Batteries

    Directory of Open Access Journals (Sweden)

    Tatsuhiko Yajima

    2013-10-01

    Full Text Available Multivalent cation rechargeable batteries are expected to perform well as high-capacity storage devices. Rechargeable magnesium batteries have an advantage in terms of resource utilization and safety. Here, we report on sulfur-doped vanadium pentoxide (S-V2O5 as a potential material for the cathodes of such a battery; S-V2O5 showed a specific capacity of 300 mAh·g−1. S-V2O5 was prepared by a method using a low-temperature plasma generated by carbon felt and a 2.45 GHz microwave generator. This study investigates the ability of S-V2O5 to achieve high capacity when added to metal oxide. The highest recorded capacity (420 mAh·g−1 was reached with MnO2 added to composite SMn-V2O5, which has a higher proportion of included sulfur than found in S-V2O5. Results from transmission electron microscopy, energy-dispersive X-ray spectroscopy, Micro-Raman spectroscopy, and X-ray photoelectron spectroscopy show that the bulk of the SMn-V2O5 was the orthorhombic V2O5 structure; the surface was a xerogel-like V2O5 and a solid solution of MnO2 and sulfur.

  19. Direct determination of praziquantel in pharmaceutical formulations and human plasma by cathodic adsorptive stripping differential-pulse voltammetry.

    Science.gov (United States)

    Ghoneim, M M; Mabrouk, M M; Tawfik, A

    2002-11-07

    The polarographic and cyclic voltammetric behaviour of praziquantel was studied in B.R. buffers of different pH values. Contradictory to that mentioned in a previously published work, praziquantel is an electro-active compound. Its polarogram exhibited a single 2-electron irreversible reduction wave in B.R. buffer of pH 5, the wave height decreased on the increase of pH till it disappeared in solution of pH >7. This wave was attributed to the reduction of the Cz.dbnd6;O double bond. The quantitative trace determination of bulk praziquantel was studied at a hanging mercury drop electrode by cathodic adsorptive stripping differential-pulse voltammetry. A fully validated sensitive procedure based on controlled adsorptive accumulation of the drug onto a HMDE was developed for its direct determination without derivatization. Accumulation of praziquantel was found to be optimized in 0.1 M Na(2)SO(4) solution as supporting electrolyte under the following conditions: accumulation potential, -1.2 V (vs. Ag/AgCl/KCl(s)); accumulation time, 30 s; scan rate, 10 mV/s and pulse height 100 mV. The proposed procedure was applied successfully for determination of praziquantel in its pharmaceutical formulations and human plasma. The mean recoveries of the drug were 98.85-99.42% and 99.12-100.47% with RSD of 0.49-0.95% and 0.45-0.52% in pharmaceutical formulations and human plasma, respectively. Limits of detection and quantitation of 1.14x10(-9) and 3.80x10(-9) M praziquantel, respectively, were achieved.

  20. Chaotic-to-ordered state transition of cathode-sheath instabilities in DC glow discharge plasmas

    Indian Academy of Sciences (India)

    Md Nurujjaman; A N Sekar Iyengar

    2006-08-01

    Transition from chaotic to ordered state has been observed during the initial stage of a discharge in a cylindrical DC glow discharge plasma. Initially it shows a chaotic behavior but increasing the discharge voltage changes the characteristics of the discharge glow and shows a period subtraction of order 7 period → 5 period → 3 period → 1 period, i.e. the system goes to single mode through odd cycle subtraction. On further increasing the discharge voltage, the system goes through period doubling, like 1 period → 2 period → 4 period. On further increasing the voltage, the system goes to stable state through two period subtraction, like 4 period → 2 period → stable.

  1. A High Performance Cathode Heater for Hall Thrusters Project

    Data.gov (United States)

    National Aeronautics and Space Administration — High current hollow cathodes are the baseline electron source for next generation high power Hall thrusters. Currently for electron sources providing current levels...

  2. Relationship Between Designed Three-Dimensional YSZ Electrolyte Surface Area and Performance of Solution-Precursor Plasma-Sprayed La0.8Sr0.2MnO3- δ Cathodes

    Science.gov (United States)

    Zhang, Shan-Lin; Huang, Jiang-Yuan; Li, Cheng-Xin; Yang, Guan-Jun; Li, Chang-Jiu

    2016-12-01

    Active three-phase boundaries (TPBs) significantly influence cathode performance in solid oxide fuel cells, but obtaining long TPBs and understanding the mechanism underlying the improved cathode performance when the electrolyte is prepared with a smooth surface by a high-temperature sintering process remain essential challenges. In this work, we used flame spraying to deposit single-layer semimolten particles on a smooth electrolyte to build a three-dimensional surface with enlarged active surface area and thus increased TPBs. Meanwhile, La0.8Sr0.2MnO3- δ (LSM) cathodes with fine microstructure were deposited by solution-precursor plasma spraying (SPPS) on the designed electrolyte to establish a three-dimensional cathode-electrolyte interface. The deposition behavior of the semimolten particles on the smooth electrolyte and LSM cathodes on the three-dimensional electrolyte surface was studied. The effects of the area enlargement factor ( α area) on the polarization resistance of the SPPS LSM cathodes were investigated, using three-dimensional electrolytes with α area from 1.29 to 2.48. The results indicated that convex particles with different molten states bonded well with the electrolytes. SPPS LSM cathodes also showed good interfacial bonding with convex particles. Finally, the cathode polarization ( R p) decreased linearly with increase of α area. At 800 °C, R p decreased from 0.98 to 0.32 Ω cm2 when α area was increased from 1.29 to 2.48.

  3. Microhollow cathode discharge excimer lamps

    Science.gov (United States)

    Schoenbach, Karl H.; El-Habachi, Ahmed; Moselhy, Mohamed M.; Shi, Wenhui; Stark, Robert H.

    2000-05-01

    Microhollow cathode discharges are high-pressure, nonequilibrium gas discharges between a hollow cathode and a planar or hollow anode with electrode dimensions in the 100 μm range. The large concentration of high-energy electrons, in combination with the high-gas density favors excimer formation. Excimer emission was observed in xenon and argon, at wavelengths of 128 and 172 nm, respectively, and in argon fluoride and xenon chloride, at 193 and 308 nm. The radiant emittance of the excimer radiation was found to increase monotonically with pressure. However, due to the decrease in source size with pressure, the efficiency (ratio of excimer radiant power to input electrical power), has for xenon and argon fluoride a maximum at ˜400 Torr. The maximum efficiency is between 6% and 9% for xenon, and ˜2% for argon fluoride.

  4. Supercontinuum generation in the vacuum ultraviolet through dispersive-wave and soliton-plasma interaction in a noble-gas-filled hollow-core photonic crystal fiber

    Science.gov (United States)

    Ermolov, A.; Mak, K. F.; Frosz, M. H.; Travers, J. C.; Russell, P. St. J.

    2015-09-01

    We report on the generation of a three-octave-wide supercontinuum extending from the vacuum ultraviolet (VUV) to the near infrared, spanning at least 113-1000 nm (i.e., 11 -1.2 eV ), in He-filled hollow-core kagome-style photonic crystal fiber. Numerical simulations confirm that the main mechanism is an interaction between dispersive-wave emission and plasma-induced blue-shifted soliton recompression around the fiber zero dispersion frequency. The VUV part of the supercontinuum, the modeling of which proves to be coherent and possesses a simple phase structure, has sufficient bandwidth to support single-cycle pulses of 500 asec duration. We also demonstrate, in the same system, the generation of narrower-band VUV pulses through dispersive-wave emission, tunable from 120 to 200 nm with efficiencies exceeding 1 % and VUV pulse energies in excess of 50 nJ.

  5. Effects of cathodic component of current on porosity and hardness characteristics of micro plasma oxidation(MPO) coatings on aluminum alloy

    Institute of Scientific and Technical Information of China (English)

    Samir Hamid Awad; QIAN Han-cheng

    2005-01-01

    Micro plasma oxidation(MPO) has recently been investigated as a novel,rapid and effective means to provide modified surfaces with improved properties of load bearing and wear resistance on light alloys particularly aluminum alloys.MPO is a multifactor-controlled process,these factors must be controlled to produce high quality coatings.The main research emphasis in MPO coating development over the past years seems to be the attainment of higher hardness levels and thick coatings.The porosity of MPO coating is the most complex phenomenon affecting the distribution,levels and the measurements of the hardness;and it is controlled by suitable selection of important parameters such as the electrical conditions.Ceramics coatings were synthesized on Al substrate by MPO to examine the effects of adding a cathodic phase alternated with anodic-cathodic current on the porosity and hardness characteristics of coatings by X-ray diffraction(XRD),scanning electron microscopy(SEM),and microhardness tester.The coatings produced by the combined mode are more dense and less porous than that by the anodic-cathodic mode.Microhardness test shows that the coatings produced by the combined mode exhibit both the highest hardness,and less reduction percentage in hardness with increasing the coatings thickness.These improvements become more significant for the polished and thicker coatings.

  6. Physical processes associated with current collection by plasma contactors

    Science.gov (United States)

    Katz, Ira; Davis, Victoria A.

    1990-01-01

    Recent flight data confirms laboratory observations that the release of neutral gas increases plasma sheath currents. Plasma contactors are devices which release a partially ionized gas in order to enhance the current flow between a spacecraft and the space plasma. Ionization of the expellant gas and the formation of a double layer between the anode plasma and the space plasma are the dominant physical processes. A theory is presented of the interaction between the contactor plasma and the background plasma. The conditions for formation of a double layer between the two plasmas are derived. Double layer formation is shown to be a consequence of the nonlinear response of the plasmas to changes in potential. Numerical calculations based upon this model are compared with laboratory measurements of current collection by hollow cathode-based plasma contactors.

  7. Innovation in the development of plasma propulsion devices in Israel

    Science.gov (United States)

    Lev, Dan R.

    2017-04-01

    In this paper we review plasma propulsion development approach which focuses on innovation. We then bring the example of the state of Israel in general, and Rafael in particular, and show how it has adopted an innovative approach to develop a low power Hall thruster and a low current cathode. To present one special test-case of innovation we elaborate upon the development process of a heaterless hollow cathode that was developed at Rafael. In particular, by presenting the cathode characterization and wear test results we demonstrate that the heaterless cathode developed has a sufficiently wide operational range and may operate continuously for 1,500 hours without any measurable degradation in performance.

  8. Quartz antenna with hollow conductor

    Science.gov (United States)

    Leung, Ka-Ngo; Benabou, Elie

    2002-01-01

    A radio frequency (RF) antenna for plasma ion sources is formed of a hollow metal conductor tube disposed within a glass tube. The hollow metal tubular conductor has an internal flow channel so that there will be no coolant leakage if the outer glass tube of the antenna breaks. A portion of the RF antenna is formed into a coil; the antenna is used for inductively coupling RF power to a plasma in an ion source chamber. The antenna is made by first inserting the metal tube inside the glass tube, and then forming the glass/metal composite tube into the desired coil shape.

  9. Pretreatment of plasma samples by a novel hollow fiber centrifugal ultrafiltration technique for the determination of plasma protein binding of three coumarins using acetone as protein binding releasing agent.

    Science.gov (United States)

    Li, Junmei; Shi, Qingwen; Jiang, Ye; Liu, Yan

    2015-09-15

    A novel and practical sample pretreatment method based on hollow fiber centrifugal ultrafiltration (HFCF-UF) was developed to determine plasma protein binding by using HPLC. The samples for analyzing unbound and total concentrations could be prepared in parallel simultaneously by the same device. It only required centrifugation for a short time and the filtrate could be injected directly for HPLC analysis without further treatment. Coumarins were selected as the model drugs. Acetone was chosen as the releasing agent to free the binding drug from the drug-protein complex for the total drug concentration determination. Non-specific bindings (NSBs) between the analytes and hollow fiber membrane materials were investigated. The type and volume of protein binding releaser were optimized. Additionally, centrifugal speed and centrifugal time were considered. Under the optimized conditions, the absolute recovery rates of the unbound and total concentrations were in the range of 97.5-100.9% for the three analytes. The limits of detection were in the range of 0.0135-0.0667μgmL(-1). In vitro plasma protein binding of the three coumarins was determined at three concentrations using the validated method and the relative standard deviations (RSDs) were less than 3.4%. Compared with traditional method, the HFCF-UF method is simple to run, no specialized equipment requirement and is a more accurate plasma pretreatment procedure with almost excellent drug-protein binding equilibrium. Therefore, this method can be applied to determine the plasma protein binding in clinical practice. It also provides a reliable alternative for accurate monitoring of unbound or total drug concentration in therapeutic drug monitoring (TDM).

  10. Characteristics of a multi-keV monochromatic point x-ray source based on vacuum diode with laser-produced plasma as cathode

    Indian Academy of Sciences (India)

    A Moorti; A Raghuramaiah; P A Naik; P D Gupta

    2004-11-01

    Temporal, spatial and spectral characteristics of a multi-keV monochromatic point x-ray source based on vacuum diode with laser-produced plasma as cathode are presented. Electrons from a laser-produced aluminium plasma were accelerated towards a conical point tip titanium anode to generate K-shell x-ray radiation. Approximately 1010 photons/pulse were generated in x-ray pulses of ∼ 18 to ∼ 28 ns duration from a source of ∼ 300 m diameter, at ℎ = 4.51 keV ( emission of titanium), with a brightness of ∼ 1020 photons/cm2 /s/sr. This was sufficient to record single-shot x-ray radiographs of physical objects on a DEF-5 x-ray film kept at a distance of up to ∼ 10 cm.

  11. Early results of microwave transmission experiments through an overly dense rectangular plasma sheet with microparticle injection

    Science.gov (United States)

    Gillman, Eric D.; Amatucci, W. E.

    2014-06-01

    These experiments utilize a linear hollow cathode to create a dense, rectangular plasma sheet to simulate the plasma layer surrounding vehicles traveling at hypersonic velocities within the Earth's atmosphere. Injection of fine dielectric microparticles significantly reduces the electron density and therefore lowers the electron plasma frequency by binding a significant portion of the bulk free electrons to the relatively massive microparticles. Measurements show that microwave transmission through this previously overly dense, impenetrable plasma layer increases with the injection of alumina microparticles approximately 60 μm in diameter. This method of electron depletion is a potential means of mitigating the radio communications blackout experienced by hypersonic vehicles.

  12. Enhancing Micro-Cathode Arc Thruster (muCAT) Plasma Generation to Analyze Magnetic Field Angle Effects on Sheath Formation in Hall Thrusters

    Science.gov (United States)

    Lukas, Joseph Nicholas

    Using a Delta IV or Atlas V launch vehicle to send a payload into Low Earth Orbit can cost between 13,000 and 14,000 per kilogram. With payloads that utilize a propulsion system, maximizing the efficiency of that propulsion system would not only be financially beneficial, but could also increase the range of possible missions and allow for a longer mission lifetime. This dissertation looks into efficiency increases in the Micro-Cathode Arc Thruster (muCAT) and Hall Thruster. The muCAT is an electric propulsion device that ablates solid cathode material, through an electrical arc discharge, to create plasma and ultimately produce thrust. About 90% of the arc discharge current is conducted by electrons, which go toward heating the anode and contribute very little to thrust, with only the remaining 10% going toward thrust in the form of ion current. I will discuss the results of an experiment in which electron heating on a low melting point anode was shown to increase ion current, which theoretically should increase thrust levels at low frequencies. Another feature of the muCAT is the use of an external magnetic solenoid which increases thrust, ion current, and causes uniform cathode erosion. An experiment has shown that efficiency can also be increased by removing the external magnetic field power supply and, instead, utilizing the residual arc current to power the magnetic solenoid. A Hall Thruster is a type of electric propulsion device that accelerates ions across an electric potential between an anode and magnetically trapped electrons. The limiting factor in Hall Thruster operation is the lifetime of the wall material. During operation, a positively charged layer forms over the surface of the walls, known as a plasma sheath, which contributes to wall erosion. Therefore, by reducing or eliminating the sheath layer, Hall Thruster operational lifetime can increase. Computational modeling has shown that large magnetic field angles and large perpendicular electric

  13. A pulsed cathodic arc spacecraft propulsion system

    Energy Technology Data Exchange (ETDEWEB)

    Neumann, P R C; Bilek, M M M; Tarrant, R N; McKenzie, D R [School of Physics, University of Sydney, NSW 2006 Australia (Australia)

    2009-11-15

    We investigate the use of a centre-triggered cathodic arc as a spacecraft propulsion system that uses an inert solid as a source of plasma. The cathodic vacuum arc produces almost fully ionized plasma with a high exhaust velocity (>10{sup 4} m s{sup -1}), giving a specific impulse competitive with other plasma or ion thrusters. A centre trigger design is employed that enables efficient use of cathode material and a high pulse-to-pulse repeatability. We compare three anode geometries, two pulse current profiles and two pulse durations for their effects on impulse generation, energy and cathode material usage efficiency. Impulse measurement is achieved through the use of a free-swinging pendulum target constructed from a polymer material. Measurements show that impulse is accurately controlled by varying cathode current. The cylindrical anode gave the highest energy efficiency. Cathode usage is optimized by choosing a sawtooth current profile. There is no requirement for an exhaust charge neutralization system.

  14. Determination of picomolar levels of platinum in estuarine waters: a comparison of cathodic stripping voltammetry and isotope dilution-inductively coupled plasma mass spectrometry.

    Science.gov (United States)

    Obata, Hajime; Yoshida, Tetsuaki; Ogawa, Hiroshi

    2006-10-27

    A comparative study to determine picomolar concentrations of platinum in natural waters was performed using two different analytical techniques. Results obtained by cathodic stripping voltammetry (CSV) were compared with those obtained by isotope dilution-inductively coupled plasma mass spectrometry (ID-ICPMS) combined with anion exchange resin column extraction method. Using successive UV irradiations with low-pressure mercury (L-Hg) lamp for 4h prior to CSV analysis, the results of both methods were comparable. Without adequate photolytic decomposition, the results obtained using CSV were generally lower than those obtained using ID-ICPMS in the estuarine waters around Tokyo Bay. This difference implies the presence of organically complexed Pt species in the estuarine waters. The Pt enrichment in the middle of the Tokyo Bay estuaries probably reflects the anthropogenic release of Pt from highly populated areas in Tokyo.

  15. Analysis of cathode geometry to minimize cathode erosion in direct current microplasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Causa, Federica [Dipartimento di Scienze dell' Ambiente, della Sicurezza, del Territorio, degli Alimenti e della Salute, Universita degli studi di Messina, 98122 Messina (Italy); Ghezzi, Francesco; Caniello, Roberto; Grosso, Giovanni [Istituto di Fisica del Plasma, Consiglio Nazionale delle Ricerche, EURATOM-ENEA-CNR Association, Via R. Cozzi 53, 20125 Milano (Italy); Dellasega, David [Istituto di Fisica del Plasma, Consiglio Nazionale delle Ricerche, EURATOM-ENEA-CNR Association, Via R. Cozzi 53, 20125 Milano (Italy); Dipartimento di Energia, Politecnico di Milano, Via Ponzio 34/3, 20133 Milano (Italy)

    2012-12-15

    Microplasma jets are now widely used for deposition, etching, and materials processing. The present study focuses on the investigation of the influence of cathode geometry on deposition quality, for microplasma jet deposition systems in low vacuum. The interest here is understanding the influence of hydrogen on sputtering and/or evaporation of the electrodes. Samples obtained with two cathode geometries with tapered and rectangular cross-sections have been investigated experimentally by scanning electron microscopy and energy dispersion X-ray spectroscopy. Samples obtained with a tapered-geometry cathode present heavy contamination, demonstrating cathode erosion, while samples obtained with a rectangular-cross-section cathode are free from contamination. These experimental characteristics were explained by modelling results showing a larger radial component of the electric field at the cathode inner wall of the tapered cathode. As a result, ion acceleration is larger, explaining the observed cathode erosion in this case. Results from the present investigation also show that the ratio of radial to axial field components is larger for the rectangular geometry case, thus, qualitatively explaining the presence of micro-hollow cathode discharge over a wide range of currents observed in this case. In the light of the above findings, the rectangular cathode geometry is considered to be more effective to achieve cleaner deposition.

  16. The use of electrostatic probes to characterize the discharge plasma structure and identify discharge cathode erosion mechanisms in ring-cusp ion thrusters

    Science.gov (United States)

    Herman, Daniel Andrew

    The erosion of the discharge cathode assembly (DCA) is currently one of the lifetime limiting factors of ion thruster operation and will play an even more important role for more ambitious, future ion thruster applications requiring more throughput at higher-power. Erosion of the DCA has been observed throughout the ground-based wear testing of the 30-cm NSTAR ion thruster. Energetic ions have been detected near the DCA, from Laser-Induced Fluorescence (LIF) measurements, that appear to be the cause of the DCA erosion, though a mechanism by which ions gain sufficient energy to sputter erode the DCA material has not been determined. This dissertation presents research aimed at characterizing the discharge chamber plasma near the DCA to determine the mechanism by which energetic ions are created and erode the DCA inside ring-cusp ion engines. A diagnostic technique is developed to interrogate the near-DCA regions of two ion thrusters: the 30-cm FMT2 NSTAR and 40-cm LM4 NEXT engines. Both engines contain similar plasma structures. Number densities are highest along cathode centerline as the axial magnetic field near the DCA effectively confines electrons to a narrow plume. Plasma potential mappings rule out the existence of a potential-hill that has been proposed as the cause of the DCA erosion. A free standing potential gradient structure is found to form the transition between the low-potential cathode plume and the high-potential bulk discharge plasma, termed a double layer. The field-aligned double layer accelerates ions from the bulk discharge plasma towards the DCA centerline. Measured plasma parameters and LIF velocimetry data are used to calculate an erosion rate utilizing near-threshold sputtering yield formulae. Singly-ionized xenon cannot solely account for the observed NSTAR erosion rates. Incorporation of double-ionized xenon from measured double-to-single current measurements in the plume of the 30-cm and 40-cm thrusters significantly increases the

  17. The Use of an Electron Microchannel as a Self-Extracting and Focusing Plasma Cathode Electron Gun

    Science.gov (United States)

    Cornish, S.; Khachan, J.

    2016-02-01

    A new and simple type of electron gun is presented. Unlike conventional electron guns, which require a heated filament or extractor, accelerator and focusing electrodes, this gun uses the collimated electron microchannels of an inertial electrostatic confinement (IEC) discharge to achieve the same outcome. A cylindrical cathode is placed coaxially within a cylindrical anode to create the discharge. Collimated beams of electrons and fast neutrals emerge along the axis of the cylindrical cathode. This geometry isolates one of the microchannels that emerge in a negatively biased IEC grid. The internal operating pressure range of the gun is 35-190 mTorr. A small aperture separates the gun from the main vacuum chamber in order to achieve a pressure differential. The chamber was operated at pressures of 4-12 mTorr. The measured current produced by the gun was 0.1-3 mA (0.2-14 mA corrected measurement) for discharge currents of 1-45 mA and discharge voltages of 0.5-12 kV. The collimated electron beam emerges from the aperture into the vacuum chamber. The performance of the gun is unaffected by the pressure differential between the vacuum chamber and the gun. This allows the aperture to be removed and the chamber pressure to be equal to the gun pressure if required.

  18. Hall-effect thruster--Cathode coupling: The effect of cathode position and magnetic field topology

    Science.gov (United States)

    Sommerville, Jason D.

    2009-12-01

    Hall-effect thruster (HET) cathodes are responsible for the generation of the free electrons necessary to initiate and sustain the main plasma discharge and to neutralize the ion beam. The position of the cathode relative to the thruster strongly affects the efficiency of thrust generation. However, the mechanisms by which the position affects the efficiency are not well understood. This dissertation explores the effect of cathode position on HET efficiency. Magnetic field topology is shown to play an important role in the coupling between the cathode plasma and the main discharge plasma. The position of the cathode within the magnetic field affects the ion beam and the plasma properties of the near-field plume, which explains the changes in efficiency of the thruster. Several experiments were conducted which explored the changes of efficiency arising from changes in cathode coupling. In each experiment, the thrust, discharge current, and cathode coupling voltage were monitored while changes in the independent variables of cathode position, cathode mass flow and magnetic field topology were made. From the telemetry data, the efficiency of the HET thrust generation was calculated. Furthermore, several ion beam and plasma properties were measured including ion energy distribution, beam current density profile, near-field plasma potential, electron temperature, and electron density. The ion beam data show how the independent variables affected the quality of ion beam and therefore the efficiency of thrust generation. The measurements of near-field plasma properties partially explain how the changes in ion beam quality arise. The results of the experiments show that cathode position, mass flow, and field topology affect several aspects of the HET operation, especially beam divergence and voltage utilization efficiencies. Furthermore, the experiments show that magnetic field topology is important in the cathode coupling process. In particular, the magnetic field

  19. Dense Metal Plasma in a Solenoid for Ion Beam Neutralization

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre; Kauffeldt, Marina; Oks, Efim M.; Roy, Prabir K.

    2010-10-30

    Space-charge neutralization is required to compress and focus a pulsed, high-current ion beam on a target for warm dense matter physics or heavy ion fusion experiments. We described approaches to produce dense plasma in and near the final focusing solenoid through which the ion beam travels, thereby providing an opportunity for the beam to acquire the necessary space-charge compensating electrons. Among the options are plasma injection from pulsed vacuum arc sources located outside the solenoid, and using a high current (> 4 kA) pulsed vacuum arc plasma from a ring cathode near the edge of the solenoid. The plasma distribution is characterized by photographic means, by an array of movable Langmuir probes, by a small single probe, and by evaluating Stark broadening of the Balmer H beta spectral line. In the main approach described here, the plasma is produced at several cathode spots distributed azimuthally on the ring cathode. It is shown that the plasma is essentially hollow, as determined by the structure of the magnetic field, though the plasma density exceeds 1014 cm-3 in practically all zones of the solenoid volume if the ring electrode is placed a few centimeters off the center of the solenoid. The plasma is non-uniform and fluctuating, however, since its density exceeds the ion beam density it is believed that this approach could provide a practical solution to the space charge neutralization challenge.

  20. Characteristics of RF Cold Plasma at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    QIU Liang; MENG Yuedong; SHU Xingsheng

    2007-01-01

    The characteristics of a stable discharge at atmospheric pressure is investigated.The plasma source consisted of two closely spaced parallel-plated perforated electrodes,driven by a radio frequency power to generate a uniform cold plasma in Helium at atmospheric pressure.Both alpha and gamma modes were clearly observed.The hollow cathode effects were found in the discharge.The influence of the dielectric barrier on the discharge was also investigated by utilizing a surface-anodized aluminium electrode as the anode.

  1. Experimental study of miniature hollow cathode plasma electron gun%小型空心阴极等离子体电子枪实验

    Institute of Scientific and Technical Information of China (English)

    李文旭; 鄢扬; 傅文杰; 黎晓云; 吴坚强

    2010-01-01

    基于空心阴极效应和低压辉光放电原理,设计了一种小型空心阴极等离子体电子枪并进行了实验研究,在低气压下获得了稳定的空心阴极辉光放电,测量电子枪放电结果表明:在空心阴极中加入灯丝热子可明显降低放电气压;电子束电流的大小随放电电压增大而增大,受气体气压影响较小;在气压2 Pa,放电电压10 kV,脉宽4 μs脉冲下放电,可得到脉宽为2 μs,电流为600 mA的电子束.

  2. Study of the hollow cathode plasma electron-gun%空心阴极等离子体电子枪研究

    Institute of Scientific and Technical Information of China (English)

    张永辉; 江金生; 常安碧

    2003-01-01

    对空心阴极等离子体电子枪的理论与机理做了较详细的分析,介绍了空心阴极放电特性,论述了激励电极和调制电极在空心阴极内等离子体形成过程中的作用,分析了等离子体中电子和离子的运动及主要参数,推导出空心阴极内电场与电流密度的表达式,研究了形成稳定电子束流的基本条件.利用泊松方程、电流连续性方程和运动方程对其进行了数值模拟计算,并给出了优化结果. 在此基础上设计出了输出束流脉宽为1μs、幅值达2kA的空心阴极等离子体电子枪.

  3. Microhollow Cathode Discharge Excimer Lamps

    Science.gov (United States)

    Schoenbach, K. H.

    1999-11-01

    character. Reducing the diameter of the cathode hole in a hollow cathode discharge geometry to values on the order of 100 μm has allowed us to extend the pressure range of stable, direct current hollow cathode gas discharges up to atmospheric pressure. The large concentration of high-energy electrons generated in the cathode fall, in combination with the high neutral gas density favors three-body processes such as excimer formation. Excimer emission in xenon discharges peaking at 172 nm, was observed with efficiencies between 6% and 9% at pressures of several hundred Torr. Typical forward voltages are 200 V at dc currents up to 8 mA. Pulsed operation allowed us to extend the current range to 80 mA with corresponding linear increase in optical power. Spatially resolved measurements showed that the source of the excimer radiation at atmospheric pressure and currents of less than 8 mA is confined to the cathode opening. The radiative emittance at 8 mA and atmospheric pressure is approximately 20 W/cm^2. With reduced pressure and increased current, respectively, the excimer source extends into the area outside the cathode hole. Besides in xenon, excimer emission in argon at a peak wavelength of 128 nm has been recorded. In addition to operating the discharge in rare gases, we have also explored its use as rare gas-halide excimer source. In a gas mixture containing 1% ArF we were able to generate stable dc discharges in flowing gas at pressures ranging from 100 Torr to atmospheric pressure. The spectra of the high-pressure ArF discharges are dominated by excimer radiation peaking at 193 nm. The excimer emission of a single ArF discharge at 700 Torr was measured as 150 mW at an efficiency of 3%. Parallel operation of these discharges by means of a resistive anode, which has recently been demonstrated for argon discharges, offers the possibility to use microhollow cathode discharge arrays as dc-excimer lamps, with estimated power densities exceeding 10 W/cm^2. abstract

  4. Collaborative Research: Understanding Ion Losses to Plasma Boundaries Sheaths and Presheaths

    Energy Technology Data Exchange (ETDEWEB)

    Hershkowitz, Noah [Univ. of Wisconsin, Madison, WI (United States)

    2015-10-01

    Sheaths are common to all bounded steady-state plasmas. This includes laboratory, industrial, fusion, and in some cases even space plasmas. They form in general to balance particle loss and maintain quasi-neutrality in plasmas. Electrons are lighter than the ions by 2000 times or more (depending on the gas), and in most plasmas ion temperatures are rarely higher than the electron temperature and generally much lower. Thus in most cases, negative potential sheaths occur to confine electrons and allow ions to be freely lost. We have investigated how a plasma locally response to a positive bias on a small electrode, and have established area criteria which plasma reacts differently to the positive bias – first a pure electron sheath, and a global non-ambipolar regime where all electrons are lost to the electrode, and a double layer structure identified as a virtual cathode forms to limiting electron loss and maintain quasi-neutrality, and finally a anode spot regime where a secondary discharge occurs in front of the electrode, turning it into the major loss area of the entire plasma. Electrode area and plasma parameters criteria for these regimes were established, and the effect of the virtual cathode on the electrode’s I-V characteristics was investigated. We have also developed a global non-ambipolar electron source to replace hollow cathodes in a number of plasma applications. This eliminates the lifetime limitation and maintenance cost of hollow cathodes as they easily wear out easily and cannot be replaced in space applications.

  5. A new atmospheric RF cold plasma source with microhollow cathode structure%一种新型微空阴极结构的大气压射频冷等离子体源

    Institute of Scientific and Technical Information of China (English)

    裘亮; 孟月东; 任兆杏; 钟少锋

    2006-01-01

    介绍微空阴极的结构和物理机理,着重介绍一种新型大气压下射频激励的大面积冷等离子体源--融合空心阴极(fused hollow cathodes,FHC).结合应用和与之有关的研究,简单介绍空心阴极的放电特性,以及影响其放电特性的因素,如阴极材料、气体种类、频率、气体流速、气压、阴极内径等.另外提到了其他两种相关的微空阴极系统.

  6. High-rate and low-temperature growth of ZnO:Ga thin films by steered cathodic arc plasma evaporation

    Energy Technology Data Exchange (ETDEWEB)

    Liang, Chih-Hao [Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan (China); Wang, Wei-Lin [Nano Materials Center, ITRI South, Industrial Technology Research Institute, Tainan, Taiwan (China); Hwang, Weng-Sing, E-mail: wshwang@mail.ncku.edu.tw [Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan (China)

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer ZnO:Ga (GZO) films are deposited on glass by steered cathodic arc plasma evaporation. Black-Right-Pointing-Pointer GZO films are grown at a high growth rate (220 nm/min) and low temperature (120 Degree-Sign C). Black-Right-Pointing-Pointer Films with low strain show low resistivity and high transparency. Black-Right-Pointing-Pointer Droplet size is reduced when a high-melting-point GZO ceramic target is adopted. Black-Right-Pointing-Pointer Metal-like conductivity indicates GZO films became degenerated semiconductors. - Abstract: Ga-doped ZnO (GZO) thin films with various thicknesses (120-520 nm) are deposited on the glass substrate at a high growth rate of 220 nm/min and a low temperature of 120 Degree-Sign C by a steered cathodic arc plasma evaporation (steered CAPE). The growth mechanism, microstructure, residual stress, surface morphology, electrical and optical properties, chemical states, electron transport behaviors and thickness effect of the GZO films are investigated. The film stress is gradually relaxed from -0.516 GPa to -0.090 GPa with thickness increasing. Transmission electron microscopy (TEM) images show that the GZO microstructure consists of c-axis textured columnar grains accompanied by some embedded nanodroplets. The droplet size is significantly reduced when a high-melting-point (1975 Degree-Sign C) GZO ceramic target is adopted. High-resolution TEM image shows the GZO crystallites nucleated directly onto the amorphous substrate. The electrical properties improve with increasing thickness. The lowest resistivity (4.72 Multiplication-Sign 10{sup -4} {Omega} cm) is achieved at the thickness of 520 nm, with a corresponding transmittance of 89% in the visible region. Temperature-dependent resistivity measurements show that metal-semiconductor transition temperature increases from 136 K to 225 K when decreasing the thickness, which is due to the increasing the localized states caused by the defects and

  7. Characterization of multicapillary dielectric cathodes

    Science.gov (United States)

    Gleizer, J. Z.; Hadas, Y.; Yarmolich, D.; Felsteiner, J.; Krasik, Ya. E.

    2007-04-01

    Parameters of the plasma and electron beam produced by a multicapillary cathode in a diode powered by a ˜200kV, ˜300ns pulse are presented. It was found that the source of electrons is the plasma ejected from the capillaries. Inside the capillaries this plasma obtains electron density and temperature of ˜8×1015cm-3 and ˜5eV, respectively. In the vicinity of the cathode, the density and temperature of the plasma electrons were found to be 2×1014cm-3 and 4.5eV, respectively, for electron current density of ˜40A/cm2. It was shown that the plasma expansion velocity is in the range of (1-2)×106cm/s for current density of >12A/cm2.

  8. Determination of trace Cd, Cu, Fe, Pb and Zn in diesel and gasoline by inductively coupled plasma mass spectrometry after sample clean up with hollow fiber solid phase microextraction system

    Energy Technology Data Exchange (ETDEWEB)

    Nomngongo, Philiswa N.; Ngila, J. Catherine, E-mail: jcngila@uj.ac.za

    2014-08-01

    This study reports a simple and efficient method for the determination of trace Cd, Cu, Fe, Pb and Zn in diesel and gasoline samples by inductively coupled plasma mass spectrometry after matrix removal and analyte pre-concentration using hollow fiber-solid phase microextraction (HF–SPME). The optimization of HF-SPME procedure was carried out using two-level full factorial and central composite designs. Four factors (variables), that are, sample solution pH, acceptor phase amount, extraction time and eluent concentration were optimized. Under the optimized experimental conditions, the precision was ≤ 3% (C = 10 μg L{sup −1}, n = 15), limits of detection and quantification ranged from 0.1 to 0.3 μg L{sup −1} and 0.3–0.9 μg L{sup −1}, respectively, and the maximum preconcentration factor was 30. The HF-SPME method was applied for the determination of trace metals in real gasoline and diesel samples. - Highlights: • Hollow fiber solid phase microextraction of metal ions in diesel and gasoline • Use of hollow fiber-supported sol–gel combined with cation exchange resin • Optimization of HF-SPME using multivariate techniques • Determination of Cd, Cu, Fe, Pb and Zn using ICP–MS • Relatively low LOD and LOQ.

  9. The study of micro-arc discharges during cathodic plasma electrolysis of refractory metals using the spectral line shape of Na I lines

    Science.gov (United States)

    Jovović, Jovica; Stojadinović, Stevan; Tadić, Nenad; Vasilić, Rastko; Šišović, Nikola M.

    2016-03-01

    The micro-arc discharges during cathodic plasma electrolysis of refractory metals (Zr, Ti, Ta) are studied by means of optical emission spectroscopy. The fitting procedure based on three mutually shifted profiles is developed to analyze the complex line shape of Na I 568.64 nm and 615.86 nm doublets. Each profile includes effects of instrumental, Doppler, Stark, van der Waals and resonance broadening. The results show the existence of three discharge zones with electron number density values Ne1=7× 1014 \\text{cm}-3 , Ne2=(0.5\\text{--}1)× 1016 \\text{cm}-3 and Ne3= (1.5\\text{--}2.8)× 1016 \\text{cm}-3 while those of sodium ground-state atoms are Ng1=1.4×1017 \\text{cm}-3 , Ng2=3.6×1017 \\text{cm}-3 and Ng3=(1.7\\text{--}3.7)×1018 \\text{cm}-3 .

  10. Fabrication of AlN/BN bishell hollow nanofibers by electrospinning and atomic layer deposition

    Directory of Open Access Journals (Sweden)

    Ali Haider

    2014-09-01

    Full Text Available Aluminum nitride (AlN/boron nitride (BN bishell hollow nanofibers (HNFs have been fabricated by successive atomic layer deposition (ALD of AlN and sequential chemical vapor deposition (CVD of BN on electrospun polymeric nanofibrous template. A four-step fabrication process was utilized: (i fabrication of polymeric (nylon 6,6 nanofibers via electrospinning, (ii hollow cathode plasma-assisted ALD of AlN at 100 °C onto electrospun polymeric nanofibers, (iii calcination at 500 °C for 2 h in order to remove the polymeric template, and (iv sequential CVD growth of BN at 450 °C. AlN/BN HNFs have been characterized for their chemical composition, surface morphology, crystal structure, and internal nanostructure using X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, and selected area electron diffraction. Measurements confirmed the presence of crystalline hexagonal BN and AlN within the three dimensional (3D network of bishell HNFs with relatively low impurity content. In contrast to the smooth surface of the inner AlN layer, outer BN coating showed a highly rough 3D morphology in the form of BN nano-needle crystallites. It is shown that the combination of electrospinning and plasma-assisted low-temperature ALD/CVD can produce highly controlled multi-layered bishell nitride ceramic hollow nanostructures. While electrospinning enables easy fabrication of nanofibrous template, self-limiting reactions of plasma-assisted ALD and sequential CVD provide control over the wall thicknesses of AlN and BN layers with sub-nanometer accuracy.

  11. Hollow microporous organic capsules

    National Research Council Canada - National Science Library

    Li, Buyi; Yang, Xinjia; Xia, Lingling; Majeed, Muhammad Irfan; Tan, Bien

    2013-01-01

    Fabrication of hollow microporous organic capsules (HMOCs) could be very useful because of their hollow and porous morphology, which combines the advantages of both microporous organic polymers and non-porous nanocapsules...

  12. Propagation characteristics of atmospheric-pressure He+O2 plasmas inside a simulated endoscope channel

    Science.gov (United States)

    Wang, S.; Chen, Z. Y.; Wang, X. H.; Li, D.; Yang, A. J.; Liu, D. X.; Rong, M. Z.; Chen, H. L.; Kong, M. G.

    2015-11-01

    Cold atmospheric-pressure plasmas have potential to be used for endoscope sterilization. In this study, a long quartz tube was used as the simulated endoscope channel, and an array of electrodes was warped one by one along the tube. Plasmas were generated in the inner channel of the tube, and their propagation characteristics in He+O2 feedstock gases were studied as a function of the oxygen concentration. It is found that each of the plasmas originates at the edge of an instantaneous cathode, and then it propagates bidirectionally. Interestingly, a plasma head with bright spots is formed in the hollow instantaneous cathode and moves towards its center part, and a plasma tail expands through the electrode gap and then forms a swallow tail in the instantaneous anode. The plasmas are in good axisymmetry when [O2] ≤ 0.3%, but not for [O2] ≥ 1%, and even behave in a stochastic manner when [O2] = 3%. The antibacterial agents are charged species and reactive oxygen species, so their wall fluxes represent the "plasma dosage" for the sterilization. Such fluxes mainly act on the inner wall in the hollow electrode rather than that in the electrode gap, and they get to the maximum efficiency when the oxygen concentration is around 0.3%. It is estimated that one can reduce the electrode gap and enlarge the electrode width to achieve more homogenous and efficient antibacterial effect, which have benefits for sterilization applications.

  13. Origin of microplasma instabilities during DC operation of silicon based microhollow cathode devices

    Science.gov (United States)

    Felix, Valentin; Lefaucheux, Philippe; Aubry, Olivier; Golda, Judith; Schulz-von der Gathen, Volker; Overzet, Lawrence J.; Dussart, Rémi

    2016-04-01

    The failure mechanisms of micro hollow cathode discharges (MHCD) in silicon have been investigated using their I-V characteristics, high speed photography and scanning electron microscopy. Experiments were carried out in helium. We observed I-V instabilities in the form of rapid voltage decreases associated with current spikes. The current spikes can reach values more than 100 times greater than the average MHCD current. (The peaks can be more than 1 Ampere for a few 10’s of nanoseconds.) These current spikes are correlated in time with 3-10 μm diameter optical flashes that occur inside the cavities. The SEM characterizations indicated that blister-like structures form on the Si surface during plasma operation. Thin Si layers detach from the surface in localized regions. We theorize that shallow helium implantation occurs and forms the ‘blisters’ whenever the Si is biased as the cathode. These blisters ‘explode’ when the helium pressure inside them becomes too large leading to the transient micro-arcs seen in both the optical emission and the I-V characteristics. We noted that blisters were never found on the metal counter electrode, even when it was biased as the cathode (and the Si as the anode). This observation led to a few suggestions for delaying the failure of Si MHCDs. One may coat the Si cathode (cavities) with blister resistant material; design the MHCD array to operate with the Si as the anode rather than as the cathode; or use a gas additive to prevent surface damage. Regarding the latter, tests using SF6 as the gas additive successfully prevented blister formation through rapid etching. The result was an enhanced MHCD lifetime.

  14. Hollow dimension of modules

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    In this paper, we are interested in the following general question: Given a module Mwhich has finite hollow dimension and which has a finite collection of submodules Ki (1≤i≤n) such that M=K1+... +Kn, can we find an expression for the hollow dimension of Min terms of hollow dimensions of modules built up in some way from K1 Kn? We prove the following theorem:Let Mbe an amply supplemented module having finite hollow dimension and let Ki (1≤i≤n) be a finite collection of submodules of Msuch that M=K1+...+Kn. Then the hollow dimension h(M) of Mis the sum of the hollow dimensions of Ki (1≤i≤n) ifand only if Ki is a supplement of K1+...+Ki-1+Ki+1+...+Kn in Mfor each 1≤i≤n.

  15. Research of the Effects of Electron Focused Electric Field upon an Enhanced Glow Discharge Plasma Ion Implantation

    Institute of Scientific and Technical Information of China (English)

    LI Liu-he; WU Yong-qin; ZHANG Yan-hua; CAI Xun; CHU Paul K

    2004-01-01

    A new Enhanced Glow Discharge Plasma Ion Implantation methods are introduced, in which the plasma are produced by the self glow discharge excitated by high negative voltage bias. The electric field is designed to a electron focusing mode by using a small area hollow anode and a large area sample holder cathode. The pattern of equipotentials of the electric field are calculated through finite-element method. By using the special electron-focusing field, the self glow discharge are enhanced and provide denser ions to implanted into the substrate.

  16. Theory and Numerical Simulation of Plasma-wall Interactions in Electric Propulsion

    Science.gov (United States)

    Mikellides, Ioannis

    2016-10-01

    Electric propulsion (EP) can be an enabling technology for many science missions considered by NASA because it can produce high exhaust velocities, which allow for less propellant mass compared to typical chemical systems. Over the last decade two EP technologies have emerged as primary candidates for several proposed science missions, mainly due to their superior performance and proven record in space flight: the Ion and Hall thrusters. As NASA looks ahead to increasingly ambitious science goals, missions demand higher endurance from the propulsion system. So, by contrast to the early years of development of these thrusters, when the focus was on performance, considerable focus today is shifting towards extending their service life. Considering all potentially life-limiting mechanisms in Ion and Hall thrusters two are of primary concern: (a) the erosion of the acceleration channel in Hall thrusters and (b) the erosion of the hollow cathode. The plasma physics leading to material wear in these devices are uniquely challenging. For example, soon after the propellant is introduced into the hollow cathode it becomes partially ionized as it traverses a region of electron emission. Electron emission involves highly non-linear boundary conditions. Also, the sheath size is typically many times smaller than the characteristic physical scale of the device, yet energy gained by ions through the sheath must be accounted for in the erosion calculations. The plasma-material interactions in Hall thruster channels pose similar challenges that are further exacerbated by the presence of a strong applied magnetic field. In this presentation several complexities associated with plasma-wall interactions in EP will be discussed and numerical simulation results of key plasma properties in two examples, Hall thrusters and hollow cathodes, will be presented.

  17. Two-dimensional model of stationary plasma thruster

    Energy Technology Data Exchange (ETDEWEB)

    Pitchford, L.C.; Boeuf, J.P. [Universite Paul Sabatier, Toulouse (France)

    1995-12-31

    A stationary plasma thruster, SPT, (also called closed-drift thrusters or Hall thrusters) is an electromagnetic propulseur design which has been developed over the past thirty years in the former USSR. SPT`s are small devices with a thrust greater than 1000 s{sup -1}, and a lifetime of several 1000 hours or more. These properties make the SPT of interest for applications such as satellite station-keeping or orbit transfer. The geometry of the SPT is shown; it consists of a hollow, cylindrical dielectric (typically of several centimeters length and diameter) with a central dielectric rod. A voltage on the order of several 100`s of V is applied at the anode (at one end of the cylinder). The cathode is an externally powered hollow cathode or a hot filament positioned slightly past the exit of the dielectric cylinder. Gas, typically xenon, flows in from around the anode and is ionized by the electrons which are emitted from the cathode. A magnetic field is applied which is mainly in the radial direction. The magnetic strength is such that the electrons tend to be trapped along the magnetic field lines, but the ion trajectories are not significantly influenced by the magnetic field. For these conditions, the current at the anode is several amps. At the exit plane, the xenon is almost fully ionized. The ion flux at the exhaust provides the thrust.

  18. Filtered cathodic arc deposition apparatus and method

    Science.gov (United States)

    Krauss, Alan R.

    1999-01-01

    A filtered cathodic arc deposition method and apparatus for the production of highly dense, wear resistant coatings which are free from macro particles. The filtered cathodic arc deposition apparatus includes a cross shaped vacuum chamber which houses a cathode target having an evaporable surface comprised of the coating material, means for generating a stream of plasma, means for generating a transverse magnetic field, and a macro particle deflector. The transverse magnetic field bends the generated stream of plasma in the direction of a substrate. Macro particles are effectively filtered from the stream of plasma by traveling, unaffected by the transverse magnetic field, along the initial path of the plasma stream to a macro particle deflector. The macro particle deflector has a preformed surface which deflects macro particles away from the substrate.

  19. Development of a power electronics unit for the Space Station plasma contactor

    Science.gov (United States)

    Hamley, John A.; Hill, Gerald M.; Patterson, Michael J.; Saggio, Joseph, Jr.; Terdan, Fred; Mansell, Justin D.

    1994-02-01

    A hollow cathode plasma contactor has been baselined as a charge control device for the Space Station (SS) to prevent deleterious interactions of coated structural components with the ambient plasma. NASA LeRC Work Package 4 initiated the development of a plasma contactor system comprised of a Power Electronics Unit (PEU), an Expellant Management Unit (EMU), a command and data interface, and a Plasma Contactor Unit (PCU). A breadboard PEU was designed and fabricated. The breadboard PEU contains a cathode heater and discharge power supply, which were required to operate the PCU, a control and auxiliary power converter, an EMU interface, a command and telemetry interface, and a controller. The cathode heater and discharge supplies utilized a push-pull topology with a switching frequency of 20 kHz and pulse-width-modulated (PWM) control. A pulse ignition circuit derived from that used in arcjet power processors was incorporated in the discharge supply for discharge ignition. An 8088 based microcontroller was utilized in the breadboard model to provide a flexible platform for controller development with a simple command/data interface incorporating a direct connection to SS Mulitplexer/Demultiplexer (MDM) analog and digital I/O cards. Incorporating this in the flight model would eliminate the hardware and software overhead associated with a 1553 serial interface. The PEU autonomously operated the plasma contactor based on command inputs and was successfully integrated with a prototype plasma contactor unit demonstrating reliable ignition of the discharge and steady-state operation.

  20. Development of a Power Electronics Unit for the Space Station Plasma Contactor

    Science.gov (United States)

    Hamley, John A.; Hill, Gerald M.; Patterson, Michael J.; Saggio, Joseph, Jr.; Terdan, Fred; Mansell, Justin D.

    1994-01-01

    A hollow cathode plasma contactor has been baselined as a charge control device for the Space Station (SS) to prevent deleterious interactions of coated structural components with the ambient plasma. NASA LeRC Work Package 4 initiated the development of a plasma contactor system comprised of a Power Electronics Unit (PEU), an Expellant Management Unit (EMU), a command and data interface, and a Plasma Contactor Unit (PCU). A breadboard PEU was designed and fabricated. The breadboard PEU contains a cathode heater and discharge power supply, which were required to operate the PCU, a control and auxiliary power converter, an EMU interface, a command and telemetry interface, and a controller. The cathode heater and discharge supplies utilized a push-pull topology with a switching frequency of 20 kHz and pulse-width-modulated (PWM) control. A pulse ignition circuit derived from that used in arcjet power processors was incorporated in the discharge supply for discharge ignition. An 8088 based microcontroller was utilized in the breadboard model to provide a flexible platform for controller development with a simple command/data interface incorporating a direct connection to SS Mulitplexer/Demultiplexer (MDM) analog and digital I/O cards. Incorporating this in the flight model would eliminate the hardware and software overhead associated with a 1553 serial interface. The PEU autonomously operated the plasma contactor based on command inputs and was successfully integrated with a prototype plasma contactor unit demonstrating reliable ignition of the discharge and steady-state operation.

  1. Nanotube cathodes.

    Energy Technology Data Exchange (ETDEWEB)

    Overmyer, Donald L.; Lockner, Thomas Ramsbeck; Siegal, Michael P.; Miller, Paul Albert

    2006-11-01

    Carbon nanotubes have shown promise for applications in many diverse areas of technology. In this report we describe our efforts to develop high-current cathodes from a variety of nanotubes deposited under a variety of conditions. Our goal was to develop a one-inch-diameter cathode capable of emitting 10 amperes of electron current for one second with an applied potential of 50 kV. This combination of current and pulse duration significantly exceeds previously reported nanotube-cathode performance. This project was planned for two years duration. In the first year, we tested the electron-emission characteristics of nanotube arrays fabricated under a variety of conditions. In the second year, we planned to select the best processing conditions, to fabricate larger cathode samples, and to test them on a high-power relativistic electron beam generator. In the first year, much effort was made to control nanotube arrays in terms of nanotube diameter and average spacing apart. When the project began, we believed that nanotubes approximately 10 nm in diameter would yield sufficient electron emission properties, based on the work of others in the field. Therefore, much of our focus was placed on measured field emission from such nanotubes grown on a variety of metallized surfaces and with varying average spacing between individual nanotubes. We easily reproduced the field emission properties typically measured by others from multi-wall carbon nanotube arrays. Interestingly, we did this without having the helpful vertical alignment to enhance emission; our nanotubes were randomly oriented. The good emission was most likely possible due to the improved crystallinity, and therefore, electrical conductivity, of our nanotubes compared to those in the literature. However, toward the end of the project, we learned that while these 10-nm-diameter CNTs had superior crystalline structure to the work of others studying field emission from multi-wall CNT arrays, these nanotubes still

  2. [Investigation on the electron density of a micro-plasma jet operated at atmospheric pressure].

    Science.gov (United States)

    Li, Xue-chen; Zhao, Na; Liu, Wei-yuan; Liu, Zhi-qiang

    2010-07-01

    In the present paper, a micro-hollow cathode discharge setup was used to generate micro-plasma jet in flowing mixture of Ar and N2 at atmospheric pressure. The characteristics of the micro-plasma jet were investigated by means of optical method and electrical one. It has been found that breakdown occurs in the gas between the two electrodes when the input power of electric source is increased to a certain value. Plasma appears along the gas flow direction when the mixed gas flows from the aperture of the micro-hollow cathode, and the length of plasma reaches 4 mm. The discharge current is quasi-continuous, and the duration of discharge pulse is about 0.1 micros. Electron density was studied by using Einstein equation and Stark broadening of spectral lines from the emission spectrum respectively. It was found that the results of electron density calculated by the two methods are consistent with the order of 10(15) x cm(-3). It was also found that the electron density is almost independent of power. A qualitative explanation to the phenomenon is given based on the gas discharge theory.

  3. Verification of high efficient broad beam cold cathode ion source

    Science.gov (United States)

    Abdel Reheem, A. M.; Ahmed, M. M.; Abdelhamid, M. M.; Ashour, A. H.

    2016-08-01

    An improved form of cold cathode ion source has been designed and constructed. It consists of stainless steel hollow cylinder anode and stainless steel cathode disc, which are separated by a Teflon flange. The electrical discharge and output characteristics have been measured at different pressures using argon, nitrogen, and oxygen gases. The ion exit aperture shape and optimum distance between ion collector plate and cathode disc are studied. The stable discharge current and maximum output ion beam current have been obtained using grid exit aperture. It was found that the optimum distance between ion collector plate and ion exit aperture is equal to 6.25 cm. The cold cathode ion source is used to deposit aluminum coating layer on AZ31 magnesium alloy using argon ion beam current which equals 600 μA. Scanning electron microscope and X-ray diffraction techniques used for characterizing samples before and after aluminum deposition.

  4. Comparison of Numerical and Experimental Time-Resolved Near-Field Hall Thruster Plasma Properties

    Science.gov (United States)

    2014-03-06

    RESOLVED NEAR-FIELD HALL THRUSTER PLASMA PROPERTIES 807 TABLE I BHT -600 HALL THRUSTER AT NOMINAL XENON OPERATING CONDITIONS AND PERFORMANCE [21] 1.2-m...is a 600 W BHT -600 with a 3.2-mm hollow cathode manufactured by the Busek Company (Natick, MA). This thruster has been studied previously using both...electrostatic probes and various opti- cal diagnostics [17]–[20]. The BHT -600 has an acceleration channel outer radius of 32 mm, inner radius of 24 mm

  5. Electrospray ionization-ion mobility spectrometry as a detection system for three-phase hollow fiber microextraction technique and simultaneous determination of trimipramine and desipramine in urine and plasma samples.

    Science.gov (United States)

    Jafari, M T; Saraji, M; Sherafatmand, H

    2011-04-01

    A novel method based on three-phase hollow fiber microextraction technique (HF-LPME) coupled with electrospray ionization-ion mobility spectrometry (ESI-IMS) was developed for the simultaneous determination of two antidepressant drugs (trimipramine and desipramine) in urine and plasma samples. The effects of various parameters such as type of organic solvent, composition of donor and acceptor phase, stirring rate, salt addition, extraction time, and temperature were investigated. Under the optimized conditions, the relative standard deviation was in the range of 5-6%, and the method quantitation limit (MQL) of utilizing HF-LPME/ESI-IMS was 5 μg/L for both drugs. The relative recoveries obtained by the proposed method from urine and plasma samples were in the range 94% to 97% for trimipramine and 92% to 96% for desipramine. Finally, the feasibility of the proposed method was successfully confirmed by extraction and determination of trace amounts of trimipramine and desipramine in biological samples without any significant matrix effect.

  6. Engineering Stable Hollow Capsules

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    @@ Scientists at the CAS Institute of Chemistry have been succeeded in fabricating stable hollow capsules by extending covalent layer-by-layer self-assembly(CSA)technique from 2-dimensional to 3-dimensional systems.

  7. Hollow-Fiber Clinostat

    Science.gov (United States)

    Rhodes, Percy H.; Miller, Teresa Y.; Snyder, Robert S.

    1990-01-01

    Hollow-fiber clinostat, is bioreactor used to study growth and other behavior of cells in simulated microgravity. Cells under study contained in porous hollow fiber immersed in culture medium inside vessel. Bores in hollow fiber allow exchange of gases, nutrients, and metabolic waste products between living cells and external culture media. Hollow fiber lies on axis of vessel, rotated by motor equipped with torque and speed controls. Desired temperature maintained by operating clinostat in standard tissue-culture incubator. Axis of rotation made horizontal or vertical. Designed for use with conventional methods of sterilization and sanitation to prevent contamination of specimen. Also designed for asepsis in assembly, injection of specimen, and exchange of medium.

  8. Microwave Plasma Chemical Vapor Deposition of Carbon Coatings on LiNi1/3Co1/3Mn1/3O2 for Li-Ion Battery Composite Cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Doeff, M.M.; Kostecki, R.; Marcinek, M.; Wilcoc, J.D.

    2008-12-10

    In this paper, we report results of a novel synthesis method of thin film conductive carbon coatings on LiNi{sub 1/3}Co{sub 1/3}Mn{sub 1/3}O{sub 2} cathode active material powders for lithium-ion batteries. Thin layers of graphitic carbon were produced from a solid organic precursor, anthracene, by a one-step microwave plasma chemical vapor deposition (MPCVD) method. The structure and morphology of the carbon coatings were examined using SEM, TEM, and Raman spectroscopy. The composite LiNi{sub 1/3}Co{sub 1/3}Mn{sub 1/3}O{sub 2} electrodes were electrochemically tested in lithium half coin cells. The composite cathodes made of the carbon-coated LiNi{sub 1/3}Co{sub 1/3}Mn{sub 1/3}O{sub 2} powder showed superior electrochemical performance and increased capacity compared to standard composite LiNi{sub 1/3}Co{sub 1/3}Mn{sub 1/3}O{sub 2} electrodes.

  9. A miniature origami biofuel cell based on a consumed cathode.

    Science.gov (United States)

    Yu, You; Han, Yujie; Lou, Baohua; Zhang, Lingling; Han, Lei; Dong, Shaojun

    2016-11-10

    Considerable interest has been focused on miniature biofuel cells (BFCs) because of their portability and possibility to be implantable. Origami devices with hollow channels will provide novel insight into the assembly methods of miniature BFCs. Herein a miniature origami BFC has been fabricated from a MnO2-graphite flake consumed solid-state cathode. For further practical applications, miniature origami BFCs can directly generate energy from soft drinks.

  10. Liquid plasma sprayed nano-network La0.4Sr0.6Co0.2Fe0.8O3/Ce0.8Gd0.2O2 composite as a high-performance cathode for intermediate-temperature solid oxide fuel cells

    Science.gov (United States)

    Zhang, Shan-Lin; Li, Chang-Jiu; Li, Cheng-Xin; Yang, Guan-Jun; Huang, Kevin; Liu, Meilin

    2016-09-01

    Here, we investigate the feasibility of using a liquid plasma spray process as a novel method for the cost-effective fabrication of a nanonetwork of La0.4Sr0.6Co0.2Fe0.8O3-δ (LSCF) and Ce0.8Gd0.2O2-δ (GDC) composite as a high-performance cathode for intermediate-temperature solid oxide fuel cells. A suspension containing well-dispersed nanosized GDC particles in an LSCF precursor solution is designed as the feedstock. The effects of GDC concentration in the suspension on the phase composition, microstructure, and electrochemical performance of the resulting cathode are studied. When the GDC concentration increases to 15 g L-1, the nanosized GDC particles distribute uniformly and continuously on the LSCF backbone to form a porous network structure. The electrochemical studies further indicate that the cathode polarization decreased with the increase in GDC concentration from 0 g L-1 to 15 g L-1, whereas a further increase in the GDC concentration increases the cathode polarization instead. At 600 and 750 °C, the cathode prepared using 15 g L-1 GDC concentration exhibits an impressive area-specific polarization resistance (Rp) of 0.1 Ω cm2 and 0.009 Ω cm2, respectively. Finally, the Rp of the optimal cathode almost does not change after the isothermal dwelling at 650 °C for 350 h.

  11. Charge state, angular distribution, and kinetic energy of ions from multicomponent-cathodes in vacuum arc devices

    Energy Technology Data Exchange (ETDEWEB)

    Nikolaev, A. G., E-mail: nik@opee.hcei.tsc.ru; Savkin, K. P.; Yushkov, G. Yu.; Frolova, V. P. [Institute of High Current Electronics SB RAS, 2/3 Akademichesky Ave., Tomsk 634055 (Russian Federation); Oks, E. M. [Institute of High Current Electronics SB RAS, 2/3 Akademichesky Ave., Tomsk 634055 (Russian Federation); Tomsk State University of Control Systems and Radioelectronics, 40 Lenin Ave., Tomsk 634050 (Russian Federation); Barengolts, S. A. [Prokhorov General Physics Institute RAS, 38 Vavilov St., Moscow 119991 (Russian Federation)

    2014-12-07

    We present research results on vacuum arc plasma produced with multicomponent cathode made of several different elements. The ion mass-to-charge-state spectra of the plasmas were studied by time-of-flight spectrometry. The angular distributions of different ion species were measured, and the kinetic energy of their directed (streaming) motion was determined. It is shown that the fractional composition of ions of different cathode components in the plasma flow from the cathode spot closely matches the fractional content of these components in the composite cathode. The charge states of ions of the various cathode components are determined by the average electron temperature in the cathode spot plasma. The angular distribution of lower mass ions in the plasma from a multicomponent cathode is less isotropic and broader than for the plasma from a single-component cathode of the same light element. The directed kinetic energies of the ions of the different components for plasma from a multicomponent cathode are lower for lighter elements and greater for heavier elements compared to the ion directed energy for plasmas from single-component cathodes made of the same materials. The physical processes responsible for these changes in the ion charge states in multicomponent-cathode vacuum arc plasma are discussed.

  12. ZnO Nanowire Formation by Two-Step Deposition Method Using Energy-Controlled Hollow-Type Magnetron RF Plasma

    Directory of Open Access Journals (Sweden)

    Hideki Ono

    2011-01-01

    Full Text Available ZnO nanowire was produced in RF (radio frequency discharge plasma. We employed here a two-step deposition technique. In the 1st step, zinc atoms were sputtered from a zinc target to create zinc nuclei on a substrate before the growth of ZnO nanostructure. Here, we used pure argon plasma for physical sputtering. In the 2nd step, we employed an oxygen discharge mixed with argon, where oxygen radicals reacted with zinc nuclei to form ZnO nanostructures. Experimental parameters such as gas flow ratio and target bias voltage were controlled in O2/Ar plasma. Properties of the depositions were analysed by SEM and Raman spectroscopy. We found that many folded and bundled nanowires formed in the 2nd step. The diameter of wires was typically 10–100 nm. We also discussed a growth mechanism of ZnO nanowires.

  13. Planar-Focusing Cathodes

    CERN Document Server

    Lewellen, J W

    2005-01-01

    Conventional pi-mode rf photoinjectors typically use magnetic solenoids for emittance compensation. This provides independent focusing strength, but can complicate rf power feed placement, introduce asymmetries (due to coil crossovers), and greatly increase the cost of the photoinjector. Cathode-region focusing can also provide for a form of emittance compensation. Typically this method strongly couples focusing strength to the field gradient on the cathode, however, and also requires altering the longitudinal position of the cathode to change the focusing. We propose a new method for achieving cathode-region variable-strength focusing for emittance compensation. The new method reduces the coupling to the gradient on the cathode, and does not require a change in the longitudinal position of the cathode. Expected performance for an S-band system is similar to conventional solenoid-based designs. This paper presents the results of rf cavity and beam dynamics simulations of the new design.

  14. Parallel Operation of Microhollow Cathode Discharges

    Science.gov (United States)

    Stark, Robert H.; Shi, Wenhui; Schoenbach, Karl H.

    1998-10-01

    The dc current-voltage characteristics of microhollow cathode discharges has, in certain ranges of the discharge current, a positive slope [1]. In these current ranges it should be possible to operate multiple discharges in parallel without individual ballast, and be used as flat panel excimer lamps [2] or large area plasma cathodes. In order to verify this hypothesis we have studied the parallel operation of two microhollow cathode discharges of 100 micrometer hole diameter in argon at pressures from 100 Torr to 800 Torr. Stable dc operation of the two discharges, without individual ballast, was obtained if the voltage-current characteristics of the individual discharges had a positive slope greater than 10 V/mA over a voltage range of more than 5 to obtain parallel operation over the entire current range of the microhollow cathode discharges, which includes regions of negative differential conductivity, we have replaced the metal anode by a semi-insulating semiconductor, which serves as distributed resistive ballast. With this method, we were able to ignite and sustain an array of dc microhollow cathode discharges over a wide range of pressure and discharge current. [1] K.H.Schoenbach et al. Appl. Phys. Lett. 68, 13 (1996). [2] A.El-Habachi and K.H.Schoenbach, APL. 72, 1 (1998). This work was funded by the Department of Energy, Advanced Energy Division, and by the Air Force Office of Scientific Research (AFOSR) in cooperation with the DDR&E Air Plasma Ramparts MURI Program.

  15. Cathodic Protection Model Facility

    Data.gov (United States)

    Federal Laboratory Consortium — FUNCTION: Performs Navy design and engineering of ship and submarine impressed current cathodic protection (ICCP) systems for underwater hull corrosion control and...

  16. Effect of cathode model on arc attachment for short high-intensity arc on a refractory cathode

    Science.gov (United States)

    Javidi Shirvan, Alireza; Choquet, Isabelle; Nilsson, Håkan

    2016-12-01

    Various models coupling the refractory cathode, the cathode sheath and the arc at atmospheric pressure exist. They assume a homogeneous cathode with a uniform physical state, and differ by the cathode layer and the plasma arc model. However even the most advanced of these models still fail in predicting the extent of the arc attachment when applied to short high-intensity arcs such as gas tungsten arcs. Cathodes operating in these conditions present a non-uniform physical state. A model taking into account the first level of this non-homogeneity is proposed based on physical criteria. Calculations are done for 5 mm argon arcs with a thoriated tungsten cathode. The results obtained show that radiative heating and cooling of the cathode surface are of the same order. They also show that cathode inhomogeneity has a significant effect on the arc attachment, the arc temperature and pressure. When changing the arc current (100 A, 200 A) the proposed model allows predicting trends observed experimentally that cannot be captured by the homogeneous cathode model unless restricting a priori the size of the arc attachment. The cathode physics is thus an important element to include to obtain a comprehensive and predictive arc model.

  17. Plasma and Ion Sources in Large Area Coatings: A Review

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre

    2005-02-28

    Efficient deposition of high-quality coatings often requires controlled application of excited or ionized particles. These particles are either condensing (film-forming) or assisting by providing energy and momentum to the film growth process, resulting in densification, sputtering/etching, modification of stress, roughness, texture, etc. In this review, the technical means are surveyed enabling large area application of ions and plasmas, with ion energies ranging from a few eV to a few keV. Both semiconductortype large area (single wafer or batch processing with {approx} 1000 cm{sup 2}) and in-line web and glass-coating-type large area (> 10{sup 7} m{sup 2} annually) are considered. Characteristics and differences between plasma and ion sources are explained. The latter include gridded and gridless sources. Many examples are given, including sources based on DC, RF, and microwave discharges, some with special geometries like hollow cathodes and E x B configurations.

  18. Hollow-Core Fiber Lamp

    Science.gov (United States)

    Yi, Lin (Inventor); Tjoelker, Robert L. (Inventor); Burt, Eric A. (Inventor); Huang, Shouhua (Inventor)

    2016-01-01

    Hollow-core capillary discharge lamps on the millimeter or sub-millimeter scale are provided. The hollow-core capillary discharge lamps achieve an increased light intensity ratio between 194 millimeters (useful) and 254 millimeters (useless) light than conventional lamps. The capillary discharge lamps may include a cone to increase light output. Hollow-core photonic crystal fiber (HCPCF) may also be used.

  19. Joule heat generation in thermionic cathodes of high-pressure arc discharges

    Energy Technology Data Exchange (ETDEWEB)

    Benilov, M. S.; Cunha, M. D. [Departamento de Fisica, CCCEE, Universidade da Madeira, Largo do Municipio, 9000 Funchal (Portugal)

    2013-02-14

    The nonlinear surface heating model of plasma-cathode interaction in high-pressure arcs is extended to take into account the Joule effect inside the cathode body. Calculation results are given for different modes of current transfer to tungsten cathodes of different configurations in argon plasmas of atmospheric or higher pressures. Special attention is paid to analysis of energy balances of the cathode and the near-cathode plasma layer. In all the cases, the variation of potential inside the cathode is much smaller than the near-cathode voltage drop. However, this variation can be comparable to the volt equivalent of the energy flux from the plasma to the cathode and then the Joule effect is essential. Such is the case of the diffuse and mixed modes on rod cathodes at high currents, where the Joule heating causes a dramatic change of thermal and electrical regimes of the cathode. The Joule heating has virtually no effect over characteristics of spots on rod and infinite planar cathodes.

  20. Spectral and electrical diagnosis of complex space-charge structures excited by a spherical grid cathode with orifice

    Science.gov (United States)

    Schrittwieser, R. W.; Ionita, C.; Teodorescu-Soare, C. T.; Vasilovici, O.; Gurlui, S.; Irimiciuc, S. A.; Dimitriu, D. G.

    2017-04-01

    Optical emission spectroscopy and Langmuir probes were used to diagnose complex space-charge structures that appear inside and around a spherical grid with orifice applying a negative voltage below a critical value to it. Measurements (through the orifice) delivered the axial profiles of plasma potential, electron temperature and density, and of the densities of excited atoms and ions. Thereby the formation of a double layer was found in the region near the orifice with a potential drop close to the ionisation potential of the applied gas, confirming the presence of a fireball in that region (also evidenced by visual observation), i.e. of a quasi-spherical bright plasma region consisting of a positive core (an ion-rich plasma) confined by a double layer. Spectral investigations confirmed the presence of high ion density inside the spherical grid (due to the hollow cathode effect), while outside the grid a transition region with a strong rate of ionisation and excitation processes appears. Information on the nonlinear dynamics of this space-charge structure was obtained from the analysis of the oscillations of the discharge current, as well as of the floating potential inside and outside the spherical grid. Dedicated to Hans Pécseli at the occasion of his 70th birthday, an extraordinary plasma physicist and a wonderful, noble and warm-hearted friend for more than 40 years.

  1. The double sheath on cathodes of discharges burning in cathode vapour

    Energy Technology Data Exchange (ETDEWEB)

    Benilov, M S; Benilova, L G [Departamento de Fisica, Universidade da Madeira, Largo do MunicIpio, 9000 Funchal (Portugal)

    2010-09-01

    The model of a collisionless near-cathode space-charge sheath with ionization of atoms emitted by the cathode surface is considered. Numerical calculations showed that the mathematical problem is solvable and its solution is unique. In the framework of this model, the sheath represents a double layer with a potential maximum, with the ions which are produced before the maximum returning to the cathode surface and those produced after the maximum escaping into the plasma. Numerical results are given in a form to be readily applicable in analysis of discharges burning in cathode vapour, such as vacuum arcs. In particular, the results indicate that the ion backflow coefficient in such discharges exceeds 0.5, in agreement with values extracted from the experiment.

  2. High-current carbon-epoxy capillary cathode

    Science.gov (United States)

    Gleizer, J. Z.; Queller, T.; Bliokh, Yu.; Yatom, S.; Vekselman, V.; Krasik, Ya. E.; Bernshtam, V.

    2012-07-01

    The results of experiments on the reproducible generation of an electron beam having a high current density of up to 300 A/cm2 and a satisfactorily uniform cross-sectional distribution of current density in a ˜200 kV, ˜450 ns vacuum diode with a carbon-epoxy capillary cathode are presented. It was found that the source of the electrons is the plasma formed as a result of flashover inside the capillaries. It is shown that the plasma formation occurs at an electric field ≤15 kV/cm and that the cathode sustains thousands of pulses without degradation in its emission properties. Time- and space-resolved visible light observation and spectroscopy analyses were used to determine the cathode plasma's density, temperature, and expansion velocity. It was found that the density of the cathode plasma decreases rapidly in relation to the distance from the cathode. In addition, it was found that the main reason for the short-circuiting of the accelerating gap is the formation and expansion of the anode plasma. Finally, it was shown that when an external guiding magnetic field is present, the injection of the electron beam into the drift space with a current amplitude exceeding its critical value changes the radial distribution of the current density of the electron beam because the inner electrons are reflected from the virtual cathode.

  3. Platelet-rich plasma combined with closed reduction and hollow screw internal fixation for femoral neck fracture%PRP联合闭合复位空心螺钉内固定治疗股骨颈骨折

    Institute of Scientific and Technical Information of China (English)

    陈志军; 杨彪; 张大华

    2016-01-01

    目的:分析自体富血小板血浆( PRP)联合闭合复位空心螺钉内固定治疗股骨颈骨折的临床效果。方法回顾性分析2010年5月至2014年8月在我院治疗的200例股骨颈骨折患者的临床资料,分为PRP组和对照组,各100例。 PRP组采用PRP联合闭合复位空心螺钉内固定治疗,对照组单纯采用闭合复位空心螺钉内固定治疗,记录2组患者住院时间、骨折愈合时间、切口愈合情况、术后并发症、Harris评分及髋关节功能恢复情况。结果 PRP组住院时间、骨折愈合时间明显短于对照组,切口甲级愈合率高于对照组,术后合并股骨头坏死及骨折不愈合率明显低于对照组,差异均具有统计学意义(P<0.05)。 PRP组患者术后6个月、12个月Harris评分分别为87.35、90.82分,均高于对照组的81.37、84.32分,术后6个月、12个月髋关节功能优良率分别为86%、90%,高于对照组的67%和76%,差异均具有统计学意义(P<0.05)。结论 PRP联合闭合复位空心螺钉内固定治疗股骨颈骨折能明显缩短骨折愈合时间,减少术后并发症,提高患者髋关节功能及术后生活质量,安全性和有效性较高。%Objective To explore the clinical effect of autologous platelet-rich plasma ( PRP) combined with closed reduction and hol-low screw internal fixation for femoral neck fracture .Methods Totally 200 cases of femoral neck fracture were collected from May 2010 to August 2014 in our hospital .Randomly divided them into two groups , namely the PRP group and the control group , with 100 patients in each group.The PRP group were given autologous platelet-rich plasma ( PRP) combined with closed reduction and hollow screw internal fixation , while the control group were given closed reduction and hollow screw internal fixation merely .The length of stay , time of fracture healing , wound healing state , postoperative complications rate

  4. Research and Development of a New Field Enhanced Low Temperature Thermionic Cathode that Enables Fluorescent Dimming and Loan Shedding without Auxiliary Cathode Heating

    Energy Technology Data Exchange (ETDEWEB)

    Feng Jin

    2009-01-07

    This is the final report for project entitled 'Research and development of a new field enhanced low temperature thermionic cathode that enables fluorescent dimming and load shedding without auxiliary cathode heating', under Agreement Number: DE-FC26-04NT-42329. Under this project, a highly efficient CNT based thermionic cathode was demonstrated. This cathode is capable of emitting electron at a current density two order of magnitude stronger then a typical fluorescent cathode at same temperatures, or capable of emitting at same current density but at temperature about 300 C lower than that of a fluorescent cathode. Detailed fabrication techniques were developed including CVD growth of CNTs and sputter deposition of oxide thin films on CNTs. These are mature technologies that have been widely used in industry for large scale materials processing and device fabrications, thus, with further development work, the techniques developed in this project can be scaled-up in manufacturing environment. The prototype cathodes developed in this project were tested in lighting plasma discharge environment. In many cases, they not only lit and sustain the plasma, but also out perform the fluorescent cathodes in key parameters such like cathode fall voltages. More work will be needed to further evaluate more detailed and longer term performance of the prototype cathode in lighting plasma.

  5. Comparative study of structural and electro-optical properties of ZnO:Ga films grown by steered cathodic arc plasma evaporation and sputtering on plastic and their application on polymer-based organic solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Liang, Chih-Hao, E-mail: dataman888@hotmail.com [R& D Division, Walsin Technology Corporation, Kaohsiung, Taiwan (China); Hsiao, Yu-Jen [National Nano Device Laboratories, National Applied Research Laboratories, Tainan, Taiwan (China); Hwang, Weng-Sing [Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan (China)

    2016-08-01

    Ga-doped ZnO (GZO) films with various thicknesses (105–490 nm) were deposited on PET substrates at a low temperature of 90 °C by a steered cathodic arc plasma evaporation (steered CAPE), and a GZO film with a thickness of 400 nm was deposited at 90 °C by a magnetron sputtering (MS) for comparison. The comparative analysis of the microstructure, residual stress, surface morphology, electrical and optical properties, chemical states, and doping efficiency of the films produced by the steered CAPE and MS processes was performed, and the effect of thickness on the CAPE-grown GZO films was investigated in detail. The results showed that the GZO films grown by steered CAPE exhibited higher crystallinity and lower internal stress than those deposited by MS. The transmittance and electrical properties were also enhanced for the steered CAPE-grown films. The figure of merit (Φ = T{sup 10}/R{sub s}, where T is the transmittance and R{sub s} is the sheet resistance in Ω/□). was used to evaluate the performance of the electro-optical properties. The GZO films with a thickness of 400 nm deposited by CAPE had the highest Φ value, 1.94 × 10{sup −2} Ω{sup −1}, a corresponding average visible transmittance of 88.8% and resistivity of 6.29 × 10{sup −4} Ω·cm. In contrast, the Φ value of MS-deposited GZO film with a thickness of 400 nm is only 1.1 × 10{sup −3} Ω{sup −1}. This can be attributed to the increase in crystalline size, [0001] preferred orientation, decrease in stacking faults density and Ar contamination in steered CAPE-grown films, leading to increases in the Hall mobility and carrier density. In addition, the power conversion efficiency (PCE) of organic solar cells was significantly improved by using the CAPE-grown GZO electrode, and the PCE values were 1.2% and 1.7% for the devices with MS-grown and CAPE-grown GZO electrodes, respectively. - Highlights: • ZnO:Ga (GZO) films were grown on PET by steered cathodic arc plasma evaporation (CAPE

  6. An improved reservoir oxide cathode

    Science.gov (United States)

    Wang, Xiaoxia; Liao, Xianheng; Luo, Jirun; Zhao, Qinglan

    2005-09-01

    A new type of reservoir oxide cathode has been developed in IECAS. The emission characteristics of the cathode are tested. The results show the new cathode has higher emission current density and better resistance to poisoning at same operating condition compared with those of conventional reservoir oxide cathode.

  7. Propagation characteristics of atmospheric-pressure He+O{sub 2} plasmas inside a simulated endoscope channel

    Energy Technology Data Exchange (ETDEWEB)

    Wang, S.; Chen, Z. Y.; Wang, X. H., E-mail: xhw@mail.xjtu.edu.cn; Li, D.; Yang, A. J.; Liu, D. X.; Rong, M. Z. [State Key Laboratory of Electrical Insulation and Power Equipment, Centre for Plasma Biomedicine, Xi' an Jiaotong University, Xi' an 710049 (China); Chen, H. L. [Frank Reidy Center for Bioelectrics, Old Dominion University, Norfolk, Virginia 23508 (United States); Kong, M. G. [State Key Laboratory of Electrical Insulation and Power Equipment, Centre for Plasma Biomedicine, Xi' an Jiaotong University, Xi' an 710049 (China); Frank Reidy Center for Bioelectrics, Old Dominion University, Norfolk, Virginia 23508 (United States); Department of Electrical and Computer Engineering, Old Dominion University, Norfolk, Virginia 23529 (United States)

    2015-11-28

    Cold atmospheric-pressure plasmas have potential to be used for endoscope sterilization. In this study, a long quartz tube was used as the simulated endoscope channel, and an array of electrodes was warped one by one along the tube. Plasmas were generated in the inner channel of the tube, and their propagation characteristics in He+O{sub 2} feedstock gases were studied as a function of the oxygen concentration. It is found that each of the plasmas originates at the edge of an instantaneous cathode, and then it propagates bidirectionally. Interestingly, a plasma head with bright spots is formed in the hollow instantaneous cathode and moves towards its center part, and a plasma tail expands through the electrode gap and then forms a swallow tail in the instantaneous anode. The plasmas are in good axisymmetry when [O{sub 2}] ≤ 0.3%, but not for [O{sub 2}] ≥ 1%, and even behave in a stochastic manner when [O{sub 2}] = 3%. The antibacterial agents are charged species and reactive oxygen species, so their wall fluxes represent the “plasma dosage” for the sterilization. Such fluxes mainly act on the inner wall in the hollow electrode rather than that in the electrode gap, and they get to the maximum efficiency when the oxygen concentration is around 0.3%. It is estimated that one can reduce the electrode gap and enlarge the electrode width to achieve more homogenous and efficient antibacterial effect, which have benefits for sterilization applications.

  8. have a hollow leg

    Institute of Scientific and Technical Information of China (English)

    周立

    2003-01-01

    英语对话 A:We must prevent our family members from getting involved with drugs, really. B:That’s a sure thing.We must make sure that they never involve them- selves with that. A:By the way,does your husband drink a lot? B:Yeah.That’s the only thing that keeps worrying me.And he often boasts that he has a hollow leg and nobody can drink him under the ta- ble.

  9. Nanostructured sulfur cathodes

    KAUST Repository

    Yang, Yuan

    2013-01-01

    Rechargeable Li/S batteries have attracted significant attention lately due to their high specific energy and low cost. They are promising candidates for applications, including portable electronics, electric vehicles and grid-level energy storage. However, poor cycle life and low power capability are major technical obstacles. Various nanostructured sulfur cathodes have been developed to address these issues, as they provide greater resistance to pulverization, faster reaction kinetics and better trapping of soluble polysulfides. In this review, recent developments on nanostructured sulfur cathodes and mechanisms behind their operation are presented and discussed. Moreover, progress on novel characterization of sulfur cathodes is also summarized, as it has deepened the understanding of sulfur cathodes and will guide further rational design of sulfur electrodes. © 2013 The Royal Society of Chemistry.

  10. Cathodic hydrodimerization of nitroolefins

    OpenAIRE

    Michael Weßling; Hans J. Schäfer

    2015-01-01

    Nitroalkenes are easily accessible in high variety by condensation of aldehydes with aliphatic nitroalkanes. They belong to the group of activated alkenes that can be hydrodimerized by cathodic reduction. There are many olefins with different electron withdrawing groups used for cathodic hydrodimerization, but not much is known about the behaviour of the nitro group. Synthetic applications of this group could profit from the easy access to nitroolefins in large variety, the C–C bond formation...

  11. Electron waves and resonances in bounded plasmas

    CERN Document Server

    Vandenplas, Paul E

    1968-01-01

    General theoretical methods and experimental techniques ; the uniform plasma slab-condenser system ; the hollow cylindrical plasma ; scattering of a plane electromagnetic wave by a plasma column in steady magnetic fields (cold plasma approximation) ; hot non-uniform plasma column ; metallic and dielectric resonance probes, plasma-dielectric coated antenna, general considerations.

  12. Arc Plasma Gun With Coaxial Powder Feed

    Science.gov (United States)

    Zaplatynsky, Isidor

    1988-01-01

    Redesigned plasma gun provides improved metallic and ceramic coatings. Particles injected directly through coaxial bore in cathode into central region of plasma jet. Introduced into hotter and faster region of plasma jet.

  13. Hollow metal target magnetron sputter type radio frequency ion source

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, N., E-mail: mwada@mail.doshisha.ac.jp; Kasuya, T.; Wada, M. [Graduate School of Science and Engineering, Doshisha University, Kyoto 610–0321 (Japan); Tsubouchi, N. [Kansai Institute, Advanced Industrial Science and Technology, Osaka 563–8577 (Japan)

    2014-02-15

    A 70 mm diameter 70 mm long compact ion source equipped with a hollow sputtering target has been designed and tested. The hollow sputtering target serves as the radio frequency (RF) plasma excitation electrode at 13.56 MHz. A stable beam of Cu{sup +} has been extracted when Ar was used as the discharge support gas. In the extracted beam, Cu{sup +} had occupied more than 85% of the total ion current. Further increase in Cu{sup +} ions in the beam is anticipated by increasing the RF power and Ar pressure.

  14. Cathode materials review

    Energy Technology Data Exchange (ETDEWEB)

    Daniel, Claus, E-mail: danielc@ornl.gov; Mohanty, Debasish, E-mail: danielc@ornl.gov; Li, Jianlin, E-mail: danielc@ornl.gov; Wood, David L., E-mail: danielc@ornl.gov [Oak Ridge National Laboratory, 1 Bethel Valley Road, MS6472 Oak Ridge, TN 37831-6472 (United States)

    2014-06-16

    The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403-431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead-acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide-hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J. Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783-789) demonstrated a high-energy and high-power LiCoO{sub 2} cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

  15. Cathode materials review

    Science.gov (United States)

    Daniel, Claus; Mohanty, Debasish; Li, Jianlin; Wood, David L.

    2014-06-01

    The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403-431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead-acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide-hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J. Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783-789) demonstrated a high-energy and high-power LiCoO2 cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

  16. Plasma-based accelerator structures

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, Carl B. [Univ. of California, Berkeley, CA (United States)

    1999-12-01

    Plasma-based accelerators have the ability to sustain extremely large accelerating gradients, with possible high-energy physics applications. This dissertation further develops the theory of plasma-based accelerators by addressing three topics: the performance of a hollow plasma channel as an accelerating structure, the generation of ultrashort electron bunches, and the propagation of laser pulses is underdense plasmas.

  17. Mercury - the hollow planet

    Science.gov (United States)

    Rothery, D. A.

    2012-04-01

    Mercury is turning out to be a planet characterized by various kinds of endogenous hole (discounting impact craters), which are compared here. These include volcanic vents and collapse features on horizontal scales of tens of km, and smaller scale depressions ('hollows') associated with bright crater-floor deposits (BCFD). The BCFD hollows are tens of metres deep and kilometres or less across and are characteristically flat-floored, with steep, scalloped walls. Their form suggests that they most likely result from removal of surface material by some kind of mass-wasting process, probably associated with volume-loss caused by removal (via sublimation?) of a volatile component. These do not appear to be primarily a result of undermining. Determining the composition of the high-albedo bluish surface coating in BCFDs will be a key goal for BepiColombo instruments such as MIXS (Mercury Imaging Xray Spectrometer). In contrast, collapse features are non-circular rimless pits, typically on crater floors (pit-floor craters), whose morphology suggests collapse into void spaces left by magma withdrawal. This could be by drainage of either erupted lava (or impact melt) or of shallowly-intruded magma. Unlike the much smaller-scale BCFD hollows, these 'collapse pit' features tend to lack extensive flat floors and instead tend to be close to triangular in cross-section with inward slopes near to the critical angle of repose. The different scale and morphology of BCFD hollows and collapse pits argues for quite different modes of origin. However, BCFD hollows adjacent to and within the collapse pit inside Scarlatti crater suggest that the volatile material whose loss was responsible for the growth of the hollows may have been emplaced in association with the magma whose drainage caused the main collapse. Another kind of volcanic collapse can be seen within a 25 km-wide volcanic vent outside the southern rim of the Caloris basin (22.5° N, 146.1° E), on a 28 m/pixel MDIS NAC image

  18. Hollow Polyimide Microspheres

    Science.gov (United States)

    Weiser, Erik S. (Inventor); St.Clair, Terry L. (Inventor); Echigo, Yoshiaki (Inventor); Kaneshiro, Hisayasu (Inventor)

    2001-01-01

    A shaped article composed of an aromatic polyimide has a hollow, essentially spherical structure and a particle size of about 100 to about 1500 micrometers, a density of about 1 to about 6 pounds/cubic foot and a volume change of 1 to about 20% by a pressure treatment of 30 psi for 10 minutes at room temperature. A syntactic foam, made of a multiplicity of the shaped articles which are bonded together by a matrix resin to form an integral composite structure, has a density of about 3 to about 30 pounds/cubic feet and a compression strength of about 100 to about 1400 pounds/sq inch.

  19. Birefringent hollow core fibers

    DEFF Research Database (Denmark)

    Roberts, John

    2007-01-01

    Hollow core photonic crystal fiber (HC-PCF), fabricated according to a nominally non-birefringent design, shows a degree of un-controlled birefringence or polarization mode dispersion far in excess of conventional non polarization maintaining fibers. This can degrade the output pulse in many...... and an increased overlap between the polarization modes at the glass interfaces. The interplay between these effects leads to a wavelength for optimum polarization maintenance, lambda(PM), which is detuned from the wavelength of highest birefringence. By a suitable fiber design involving antiresonance of the core...

  20. Birefringent hollow core fibers

    DEFF Research Database (Denmark)

    Roberts, John

    2007-01-01

    Hollow core photonic crystal fiber (HC-PCF), fabricated according to a nominally non-birefringent design, shows a degree of un-controlled birefringence or polarization mode dispersion far in excess of conventional non polarization maintaining fibers. This can degrade the output pulse in many...... and an increased overlap between the polarization modes at the glass interfaces. The interplay between these effects leads to a wavelength for optimum polarization maintenance, lambda(PM), which is detuned from the wavelength of highest birefringence. By a suitable fiber design involving antiresonance of the core...

  1. Ignition Features of Plasma-Beam Discharge in Gas-Discharge Electron Gun Operation

    Directory of Open Access Journals (Sweden)

    Valery A. Tutyk

    2013-01-01

    Full Text Available The current paper presents the results of experimental researches to determine the mode features of plasma-beam discharge (PBD generation by an electron beam injected by a low-vacuum gasdischarge electron gun (LGEG with the cold cathode and hollow anode on the basis of the high-voltage glow discharge and in the range of helium pressure of P ? 10 ÷ 130 Pa. The PBD boundaries and their dependences on parameters of an electron beam are found. The influence of PBD on parameters of low-vacuum gas-discharge electron gun is revealed. It causes an avalanche increase of electron beam current and burning of plasma-beam discharge in the whole space of the vacuum chamber volume and generation of electromagnetic radiation is revealed. Achieved results will be used for implementation of various vacuum technologies in the medium of reaction gas and generated electromagnetic radiation.

  2. Anodization of aluminum and silicon in plasma of a non-self-sustained glow discharge

    Energy Technology Data Exchange (ETDEWEB)

    Burachevsky, Yu. A., E-mail: office@tusur.ru; Burdovitsin, V. A.; Oks, E. M. [Tomsk State University of Control Systems and Radioelectronics (Russian Federation)

    2011-12-15

    The results of anodization of aluminum and silicon in an oxygen plasma are presented. The plasma was generated by a non-self-sustained glow discharge with a hollow cathode excited by an electron beam at the oxygen pressure of 20 Pa. The density of the current flowing through the anodized specimen did not exceed 1.5 mA/cm{sup 2}, and its temperature was 200-250 Degree-Sign C. Continuous Al{sub 2}O{sub 3} and SiO{sub 2} films were formed on the aluminum and silicon surfaces. The growth rate of the oxide layers was 150-200 nm/h for Al{sub 2}O{sub 3} and 400-800 nm/h for SiO{sub 2}.

  3. Development of potassium ion conducting hollow glass fibers. [potassium sulfur battery

    Science.gov (United States)

    Tsang, F. Y.

    1974-01-01

    Potassium ion conducting glasses, chemically resistant to potassium, potassium sulfide and sulfur, were made and their possible utility as the membrane material for a potassium/sulfur battery was evaluated. At least one satisfactory candidate was found. It possesses an electrical resistance which makes it usable as a membrane in the form of a fine hollow fiber. It's chemical and electrochemical resistances are excellent. The other aspects of the possible potassium sulfur battery utilizing such fine hollow fibers, including the header (or tube sheet) and a cathode current collector were studied. Several cathode materials were found to be satisfactory. None of the tube sheet materials studied possessed all the desired properties. Multi-fiber cells had very limited life-time due to physical failure of fibers at the fiber/tube sheet junctions.

  4. Filtered cathodic arc source

    Science.gov (United States)

    Falabella, Steven; Sanders, David M.

    1994-01-01

    A continuous, cathodic arc ion source coupled to a macro-particle filter capable of separation or elimination of macro-particles from the ion flux produced by cathodic arc discharge. The ion source employs an axial magnetic field on a cathode (target) having tapered sides to confine the arc, thereby providing high target material utilization. A bent magnetic field is used to guide the metal ions from the target to the part to be coated. The macro-particle filter consists of two straight solenoids, end to end, but placed at 45.degree. to one another, which prevents line-of-sight from the arc spot on the target to the parts to be coated, yet provides a path for ions and electrons to flow, and includes a series of baffles for trapping the macro-particles.

  5. Study of electrodepositing Au on hollow polystyrene microspheres

    Energy Technology Data Exchange (ETDEWEB)

    Jin Rong [Research Center of Laser Fusion, China Academy of Engineering Physics, P.O. Box 919-987, Mianyang 621900 (China); School of Material Science and Engineering, Xihua University, Chengdu 610039 (China); Zhang Yunwang [Research Center of Laser Fusion, China Academy of Engineering Physics, P.O. Box 919-987, Mianyang 621900 (China); Zhang Lin, E-mail: zhlmy@sina.com [Research Center of Laser Fusion, China Academy of Engineering Physics, P.O. Box 919-987, Mianyang 621900 (China); Wei Chengfu, E-mail: wcf@mail.xhu.edu.cn [School of Material Science and Engineering, Xihua University, Chengdu 610039 (China); Guo Jianjun [School of Material Science and Engineering, Xihua University, Chengdu 610039 (China)

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer The gold is electrodeposited on hollow polystyrene microspheres by self-designed setup in this paper. Black-Right-Pointing-Pointer The Au electrodeposit is finer and more uniform on account of the microspheres freely move on the cathode. Black-Right-Pointing-Pointer The morphology, thickness and roughness of Au electrodeposits were analyzed using Scanning Electron Microscopy, X-ray diffraction and Atomic Force Microscope, respectively. - Abstract: The electrodeposited Au film on hollow polystyrene microspheres is successfully prepared by a set of self-designed device. The film is more compact and uniform on account of the microspheres freely moving on the cathode. These experiments mainly focus on the analysis of spherical symmetry, thickness and roughness of electrodeposited Au film. Under conditions of current density 1.5-3 mA cm{sup -2}, the temperature 25 Degree-Sign C, and the stirring rate 150 rpm, the electrodeposited microsphere is coated with a considerably orbicular film. The morphology, thickness and roughness of Au electrodeposits are studied by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and Atomic Force Microscope (AFM), respectively.

  6. Excimer Emission from Direct Current Microhollow Cathode Discharges

    Science.gov (United States)

    Stark, R. H.; El-Habachi, A.; Shi, W.; Schoenbach, K. H.

    1997-10-01

    Reducing the dimensions of the cathode hole to less than 200 micrometer has allowed us to operate argon discharges in a hollow cathode discharge mode, dc, up to pressures of one atmosphere. Spectral measurements in the VUV have shown that the microdischarges are strong sources of argon excimer radiation at 128 nm. This points to a nonthermal electron energy distribution where a considerable part of the electrons have energies exceeding the ionization potential of argon. Whereas the discharges in argon were dc up to atmospheric pressure, discharges in xenon became unstable at pressures exceeding 300 Torr, and current spikes were observed. The xenon excimer emission at 172 nm, however, was found to increase, independent of the mode, dc or pulsed, when the pressure was increased to one atmosphere. The microdischarges have resistive current-voltage characteristics. This has allowed us to generate simple arrays of these discharges, with possible applications as flat panel excimer lamps.

  7. High-current long-duration uniform electron beam generation in a diode with multicapillary carbon-epoxy cathode

    Energy Technology Data Exchange (ETDEWEB)

    Queller, T.; Gleizer, J. Z.; Krasik, Ya. E. [Physics Department, Technion, Haifa 32000 (Israel)

    2013-09-28

    The results of reproducibly generating an electron beam with a current density of up to 5 kA/cm{sup 2}, without the cathode-anode gap being shorted by the plasma formed inside the cathode carbon-epoxy capillaries, in a ∼350 kV, ∼600 ns diode, with and without an external guiding magnetic field, are presented. The cathode sustained hundreds of pulses without degradation of its emission properties. Time- and space-resolved emissions of the plasma and spectroscopy analyses were used to determine the cathode plasma's density, temperature, and expansion velocity.

  8. High-current long-duration uniform electron beam generation in a diode with multicapillary carbon-epoxy cathode

    Science.gov (United States)

    Queller, T.; Gleizer, J. Z.; Krasik, Ya. E.

    2013-09-01

    The results of reproducibly generating an electron beam with a current density of up to 5 kA/cm2, without the cathode-anode gap being shorted by the plasma formed inside the cathode carbon-epoxy capillaries, in a ˜350 kV, ˜600 ns diode, with and without an external guiding magnetic field, are presented. The cathode sustained hundreds of pulses without degradation of its emission properties. Time- and space-resolved emissions of the plasma and spectroscopy analyses were used to determine the cathode plasma's density, temperature, and expansion velocity.

  9. Advanced Cathode Electrolyzer (ACE) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed innovation is a static, cathode-fed, 2000 psi, balanced-pressure Advanced Cathode Electrolyzer (ACE) based on PEM electrolysis technology. It...

  10. Advanced Cathode Electrolyzer (ACE) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed innovation is a static, cathode-fed, 2000 psi, balanced-pressure Advanced Cathode Electrolyzer (ACE) based on PEM electrolysis technology. It...

  11. Highly Efficient Micro Cathode Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Busek Company, Inc. proposes to develop a micro thermionic cathode that requires extremely low power and provides long lifetime. The basis for the cathode is a...

  12. Efficient plasma-enhanced method for layered LiNi1/3Co1/3Mn1/3O2 cathodes with sulfur atom-scale modification for superior-performance Li-ion batteries.

    Science.gov (United States)

    Jiang, Qianqian; Chen, Ning; Liu, Dongdong; Wang, Shuangyin; Zhang, Han

    2016-06-01

    In order to improve the electrochemical performance of LiNi1/3Co1/3Mn1/3O2 as a lithium insertion positive electrode material, atom-scale modification was realized to obtain the layered oxysulfide LiNi1/3Co1/3Mn1/3O2-xSx using a novel plasma-enhanced doping strategy. The structure and electrochemical performance of LiNi1/3Co1/3Mn1/3O2-xSx are investigated systematically, which confirms that the S doping can make the structure stable and benefit the electrochemical performance. The phys-chemical characterizations indicate that oxygen atoms in the initial LiNi1/3Co1/3Mn1/3O2 have been partially replaced by S atoms. It should be pointed out that the atom-scale modification does not significantly alter the intrinsic structure of the cathode. Compared to the pristine material, the LiNi1/3Co1/3Mn1/3O2-xSx shows a superior performance with a higher capacity (200.4 mA h g(-1)) and a significantly improved cycling stability (maintaining 94.46% of its initial discharge capacity after 100 cycles). Moreover, it has an excellent rate performance especially at elevated performance, which is probably due to the faster Li(+) transportation after S doping into the layered structure. All the results show that the atom-scale modification with sulfur atoms on LiNi1/3Co1/3Mn1/3O2, which significantly improved the electrochemical performance, offers a novel anionic doping strategy to realize the atom-scale modification of electrode materials to improve their electrochemical performance.

  13. Cathode material for lithium batteries

    Science.gov (United States)

    Park, Sang-Ho; Amine, Khalil

    2013-07-23

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  14. Electrochemical cells and cathode materials

    Energy Technology Data Exchange (ETDEWEB)

    Skarstad, P.M.; Untereker, D.F.; Meritt, D.R.

    1988-08-02

    This patent describes an electrochemical cell comprising anode and cathode means in operative relationship. The cathode means comprising a cathode material comprised of, at least in part: a halogen component selected from the group consisting of iodine, bromine, iodine bromide and mixtures thereof, and poly(ethylene oxide), at least in part.

  15. SOFC Cathode Mechanisms

    DEFF Research Database (Denmark)

    Jacobsen, Torben; Zachau-Christiansen, Birgit; Bay, Lasse

    1996-01-01

    The transient response of SOFC oxygen cathodes shows a characteristic inductive hysteresis and correspondingly the impedance diagram combines one or two capacitive arcs with a low frequency inductive arc. These features are discussed on the basis of a three step reaction sequence taken from...

  16. Smart cathodic protection systems

    NARCIS (Netherlands)

    Polder, R.B.; Leggedoor, J.; Schuten, G.; Sajna, S.; Kranjc, A.

    2010-01-01

    Cathodic protection delivers corrosion protection in concrete structures exposed to aggressive environments, e.g. in de-icing salt and marine climates. Working lives of a large number of CP systems are at least more than 13 years and probably more than 25 years, provided a minimum level of maintenan

  17. Effects of Gas Flow Rate on the Discharge Characteristics of a DC Excited Plasma Jet

    Science.gov (United States)

    Li, Xuechen; Jia, Pengying; Di, Cong; Bao, Wenting; Zhang, Chunyan

    2015-09-01

    A direct current (DC) source excited plasma jet consisting of a hollow needle anode and a plate cathode has been developed to form a diffuse discharge plume in ambient air with flowing argon as the working gas. Using optical and electrical methods, the discharge characteristics are investigated for the diffuse plasma plume. Results indicate that the discharge has a pulse characteristic, under the excitation of a DC voltage. The discharge pulse corresponds to the propagation process of a plasma bullet travelling from the anode to the cathode. It is found that, with an increment of the gas flow rate, both the discharge plume length and the current peak value of the pulsed discharge decrease in the laminar flow mode, reach their minima at about 1.5 L/min, and then slightly increase in the turbulent mode. However, the frequency of the pulsed discharge increases in the laminar mode with increasing the argon flow rate until the argon flow rate equals to about 1.5 L/min, and then slightly decreases in the turbulent mode. supported by National Natural Science Foundation of China (Nos. 10805013, 11375051), Funds for Distinguished Young Scientists of Hebei Province, China (No. A2012201045), Department of Education for Outstanding Youth Project of China (No. Y2011120), and Youth Project of Hebei University of China (No. 2011Q14)

  18. Bone tissue response to plasma-nitrided titanium implant surfaces

    Directory of Open Access Journals (Sweden)

    Emanuela Prado FERRAZ

    2015-02-01

    Full Text Available A current goal of dental implant research is the development of titanium (Ti surfaces to improve osseointegration. Plasma nitriding treatments generate surfaces that favor osteoblast differentiation, a key event to the process of osteogenesis. Based on this, it is possible to hypothesize that plasma-nitrided Ti implants may positively impact osseointegration. Objective The aim of this study was to evaluate the in vivo bone response to Ti surfaces modified by plasma-nitriding treatments. Material and Methods Surface treatments consisted of 20% N2 and 80% H2, 450°C and 1.5 mbar during 1 h for planar and 3 h for hollow cathode. Untreated surface was used as control. Ten implants of each surface were placed into rabbit tibiae and 6 weeks post-implantation they were harvested for histological and histomorphometric analyses. Results Bone formation was observed in contact with all implants without statistically significant differences among the evaluated surfaces in terms of bone-to-implant contact, bone area between threads, and bone area within the mirror area. Conclusion Our results indicate that plasma nitriding treatments generate Ti implants that induce similar bone response to the untreated ones. Thus, as these treatments improve the physico-chemical properties of Ti without affecting its biocompatibility, they could be combined with modifications that favor bone formation in order to develop new implant surfaces.

  19. Bone tissue response to plasma-nitrided titanium implant surfaces.

    Science.gov (United States)

    Ferraz, Emanuela Prado; Sverzut, Alexander Tadeu; Freitas, Gileade Pereira; Sá, Juliana Carvalho; Alves, Clodomiro; Beloti, Marcio Mateus; Rosa, Adalberto Luiz

    2015-01-01

    A current goal of dental implant research is the development of titanium (Ti) surfaces to improve osseointegration. Plasma nitriding treatments generate surfaces that favor osteoblast differentiation, a key event to the process of osteogenesis. Based on this, it is possible to hypothesize that plasma-nitrided Ti implants may positively impact osseointegration. Objective The aim of this study was to evaluate the in vivo bone response to Ti surfaces modified by plasma-nitriding treatments. Material and Methods Surface treatments consisted of 20% N2 and 80% H2, 450°C and 1.5 mbar during 1 h for planar and 3 h for hollow cathode. Untreated surface was used as control. Ten implants of each surface were placed into rabbit tibiae and 6 weeks post-implantation they were harvested for histological and histomorphometric analyses. Results Bone formation was observed in contact with all implants without statistically significant differences among the evaluated surfaces in terms of bone-to-implant contact, bone area between threads, and bone area within the mirror area. Conclusion Our results indicate that plasma nitriding treatments generate Ti implants that induce similar bone response to the untreated ones. Thus, as these treatments improve the physico-chemical properties of Ti without affecting its biocompatibility, they could be combined with modifications that favor bone formation in order to develop new implant surfaces.

  20. Understanding the role of different conductive polymers in improving the nanostructured sulfur cathode performance.

    Science.gov (United States)

    Li, Weiyang; Zhang, Qianfan; Zheng, Guangyuan; Seh, Zhi Wei; Yao, Hongbin; Cui, Yi

    2013-01-01

    Lithium sulfur batteries have brought significant advancement to the current state-of-art battery technologies because of their high theoretical specific energy, but their wide-scale implementation has been impeded by a series of challenges, especially the dissolution of intermediate polysulfides species into the electrolyte. Conductive polymers in combination with nanostructured sulfur have attracted great interest as promising matrices for the confinement of lithium polysulfides. However, the roles of different conductive polymers on the electrochemical performances of sulfur electrode remain elusive and poorly understood due to the vastly different structural configurations of conductive polymer-sulfur composites employed in previous studies. In this work, we systematically investigate the influence of different conductive polymers on the sulfur cathode based on conductive polymer-coated hollow sulfur nanospheres with high uniformity. Three of the most well-known conductive polymers, polyaniline (PANI), polypyrrole (PPY), and poly(3,4-ethylenedioxythiophene) (PEDOT), were coated, respectively, onto monodisperse hollow sulfur nanopsheres through a facile, versatile, and scalable polymerization process. The sulfur cathodes made from these well-defined sulfur nanoparticles act as ideal platforms to study and compare how coating thickness, chemical bonding, and the conductivity of the polymers affected the sulfur cathode performances from both experimental observations and theoretical simulations. We found that the capability of these three polymers in improving long-term cycling stability and high-rate performance of the sulfur cathode decreased in the order of PEDOT > PPY > PANI. High specific capacities and excellent cycle life were demonstrated for sulfur cathodes made from these conductive polymer-coated hollow sulfur nanospheres.

  1. Cathodic Arcs From Fractal Spots to Energetic Condensation

    CERN Document Server

    Anders, Andre

    2009-01-01

    Emphasizes the fractal character of cathode spots, and describes strongly fluctuating plasma properties such as the presence of multiply charged ions that move with supersonic velocity. This book also deals with issues, such as arc source construction, and macroparticle removal. It is intended for scientists, practitioners, and students alike

  2. Magnetic field penetration of erosion switch plasmas

    Science.gov (United States)

    Mason, Rodney J.; Jones, Michael E.; Grossmann, John M.; Ottinger, Paul F.

    1988-10-01

    Computer simulations demonstrate that the entrainment (or advection) of magnetic field with the flow of cathode-emitted electrons can constitute a dominant mechanism for the magnetic field penetration of erosion switch plasmas. Cross-field drift in the accelerating electric field near the cathode starts the penetration process. Plasma erosion propagates the point for emission and magnetic field injection along the cathode toward the load-for the possibility of rapid switch opening.

  3. Excimer emission from cathode boundary layer discharges

    Science.gov (United States)

    Moselhy, Mohamed; Schoenbach, Karl H.

    2004-02-01

    The excimer emission from direct current glow discharges between a planar cathode and a ring-shaped anode of 0.75 and 1.5 mm diameter, respectively, separated by a gap of 250 μm, was studied in xenon and argon in a pressure range from 75 to 760 Torr. The thickness of the "cathode boundary layer" plasma, in the 100 μm range, and a discharge sustaining voltage of approximately 200 V, indicates that the discharge is restricted to the cathode fall and the negative glow. The radiant excimer emittance at 172 nm increases with pressure and reaches a value of 4 W/cm2 for atmospheric pressure operation in xenon. The maximum internal efficiency, however, decreases with pressure having highest values of 5% for 75 Torr operation. When the discharge current is reduced below a critical value, the discharge in xenon changes from an abnormal glow into a mode showing self-organization of the plasma. Also, the excimer spectrum changes from one with about equal contributions from the first and second continuum to one that is dominated by the second continuum emission. The xenon excimer emission intensity peaks at this discharge mode transition. In the case of argon, self-organization of the plasma was not seen, but the emission of the excimer radiation (128 nm) again shows a maximum at the transition from abnormal to normal glow. As was observed with xenon, the radiant emittance of argon increases with pressure, and the efficiency decreases. The maximum radiant emittance is 1.6 W/cm2 for argon at 600 Torr. The maximum internal efficiency is 2.5% at 200 Torr. The positive slope of the current-voltage characteristics at maximum excimer emission in both cases indicates the possibility of generating intense, large area, flat excimer lamps.

  4. Magnetized plasma jets in experiment and simulation

    Science.gov (United States)

    Schrafel, Peter; Greenly, John; Gourdain, Pierre; Seyler, Charles; Blesener, Kate; Kusse, Bruce

    2013-10-01

    This research focuses on the initial ablation phase of a thing (20 micron) Al foil driven on the 1 MA-in-100 ns COBRA through a 5 mm diameter cathode in a radial configuration. In these experiments, ablated surface plasma (ASP) on the top of the foil and a strongly collimated axial plasma jet can be observed developing midway through current-rise. Our goal is to establish the relationship between the ASP and the jet. These jets are of interest for their potential relevance to astrophysical phenomena. An independently pulsed 200 μF capacitor bank with a Helmholtz coil pair allows for the imposition of a slow (150 μs) and strong (~1 T) axial magnetic field on the experiment. Application of this field eliminates significant azimuthal asymmetry in extreme ultraviolet emission of the ASP. This asymmetry is likely a current filamentation instability. Laser-backlit shadowgraphy and interferometry confirm that the jet-hollowing is correlated with the application of the axial magnetic field. Visible spectroscopic measurements show a doppler shift consistent with an azimuthal velocity in the ASP caused by the applied B-field. Computational simulations with the XMHD code PERSEUS qualitatively agree with the experimental results.

  5. Hydrogen atom kinetics in capacitively coupled plasmas

    Science.gov (United States)

    Nunomura, Shota; Katayama, Hirotaka; Yoshida, Isao

    2017-05-01

    Hydrogen (H) atom kinetics has been investigated in capacitively coupled very high frequency (VHF) discharges at powers of 16-780 mW cm-2 and H2 gas pressures of 0.1-2 Torr. The H atom density has been measured using vacuum ultra violet absorption spectroscopy (VUVAS) with a micro-discharge hollow cathode lamp as a VUV light source. The measurements have been performed in two different electrode configurations of discharges: conventional parallel-plate diode and triode with an intermediate mesh electrode. We find that in the triode configuration, the H atom density is strongly reduced across the mesh electrode. The H atom density varies from ˜1012 cm-3 to ˜1010 cm-3 by crossing the mesh with 0.2 mm in thickness and 36% in aperture ratio. The fluid model simulations for VHF discharge plasmas have been performed to study the H atom generation, diffusion and recombination kinetics. The simulations suggest that H atoms are generated in the bulk plasma, by the electron impact dissociation (e + H2 \\to e + 2H) and the ion-molecule reaction (H2 + + H2 \\to {{{H}}}3+ + H). The diffusion of H atoms is strongly limited by a mesh electrode, and thus the mesh geometry influences the spatial distribution of the H atoms. The loss of H atoms is dominated by the surface recombination.

  6. Cathode-less gridded ion thrusters for small satellites

    Science.gov (United States)

    Aanesland, Ane

    2016-10-01

    Electric space propulsion is now a mature technology for commercial satellites and space missions that requires thrust in the order of hundreds of mN, and with available electric power in the order of kW. Developing electric propulsion for SmallSats (1 to 500 kg satellites) are challenging due to the small space and limited available electric power (in the worst case close to 10 W). One of the challenges in downscaling ion and Hall thrusters is the need to neutralize the positive ion beam to prevent beam stalling. This neutralization is achieved by feeding electrons into the downstream space. In most cases hollow cathodes are used for this purpose, but they are fragile and difficult to implement, and in particular for small systems they are difficult to downscale, both in size and electron current. We describe here a new alternative ion thruster that can provide thrust and specific impulse suitable for mission control of satellites as small as 3 kg. The originality of our thruster lies in the acceleration principles and propellant handling. Continuous ion acceleration is achieved by biasing a set of grids with Radio Frequency voltages (RF) via a blocking capacitor. Due to the different mobility of ions and electrons, the blocking capacitor charges up and rectifies the RF voltage. Thus, the ions are accelerated by the self-bias DC voltage. Moreover, due to the RF oscillations, the electrons escape the thruster across the grids during brief instants in the RF period ensuring a full space charge neutralization of the positive ion beam. Due to the RF nature of this system, the space charge limited current increases by almost a factor of 2 compared to classical DC biased grids, which translates into a specific thrust two times higher than for a similar DC system. This new thruster is called Neptune and operates with only one RF power supply for plasma generation, ion acceleration and electron neutralization. We will present the downscaling of this thruster to a 3cm

  7. Cathode erosion in high-current high-pressure arc

    CERN Document Server

    Nemchinsky, V A

    2003-01-01

    Cathode erosion rate was experimentally investigated for two types of arcs: one with tungsten cathode in nitrogen atmosphere and one with hafnium cathode in oxygen atmosphere. Conditions were typical for plasma arc cutting systems: gas pressure from 2 to 5 atm, arc current from 200 to 400 A, gas flow rate from 50 to 130 litre min sup - sup 1. It was found that the actual cathode evaporation rate G is much lower than G sub 0 , the evaporation rate that follows from the Hertz-Knudsen formula: G = nu G sub 0. The difference is because some of the evaporated particles return back to the cathode. For conditions of our experiments, the factor nu could be as low as 0.01. It was shown experimentally that nu depends strongly on the gas flow pattern close to the cathode. In particular, swirling the gas increases nu many times. To explain the influence of gas swirling, model calculations of gas flows were performed. These calculations revealed difference between swirling and non-swirling flows: swirling the gas enhances...

  8. Self-pulsing of a micro thin cathode discharge

    CERN Document Server

    Gebhardt, Markus; Hemke, Torben; Brinkmann, Ralf Peter; Mussenbrock, Thomas

    2011-01-01

    Microplasmas operated at atmospheric pressure show a number of peculiar dynamic phenomena. One of these phenomena is self-pulsing, which is characterized by intrinsic pulsing behavior of a DC driven plasma discharge. This work focuses on the numerical simulation of self-pulsing in a micro thin cathode discharge operated in atmospheric pressure argon. By means of a hybrid plasma model we show self-pulsing of the discharge in the expected MHz frequency range and described its actual origin.

  9. Microstructure and Properties of Plasma Source Nitrided AISI 316 Austenitic Stainless Steel

    Science.gov (United States)

    Li, G. Y.; Lei, M. K.

    2016-11-01

    Plasma source nitriding is a relatively new nitriding technology which can overcome those inherent shortcomings associated with conventional direct current plasma nitriding technology such as the arcing surface damage, the edging effect and the hollow cathode effect. There is considerable study on the properties of nitrided samples for laboratorial scale plasma source nitriding system; however, little information has been reported on the industrial-scale plasma source nitriding system. In this work, AISI 316 austenitic stainless steel samples were nitrided by an industrial-scale plasma source nitriding system at various nitriding temperatures (350, 400, 450 and 500 °C) with a floating potential. A high-nitrogen face-centered-cubic phase (γN) formed on the surface of nitrided sample surface. As the nitriding temperature was increased, the γN phase layer thickness increased, varying from 1.5 μm for the lowest nitriding temperature of 350 °C, to 30 μm for the highest nitriding temperature of 500 °C. The maximum Vickers microhardness of the γN phase layer with a peak nitrogen concentration of 20 at.% is about HV 0.1 N 15.1 GPa at the nitriding temperature of 450 °C. The wear and corrosion experimental results demonstrated that the γN phase was formed on the surface of AISI 316 austenitic stainless steel by plasma source nitriding, which exhibits not only high wear resistance, but also good pitting corrosion resistance.

  10. Switching a Nanocluster Core from Hollow to Non-hollow

    KAUST Repository

    Bootharaju, Megalamane Siddaramappa

    2016-03-24

    Modulating the structure-property relationship in atomically precise nanoclusters (NCs) is vital for developing novel NC materials and advancing their applications. While promising biphasic ligand-exchange (LE) strategies have been developed primarily to attain novel NCs, understanding the mechanistic aspects involved in tuning the core and the ligand-shell of NCs in such biphasic processes is challenging. Here, we design a single phase LE process that enabled us to elucidate the mechanism of how a hollow NC (e.g., [Ag44(SR)30]4-, -SR: thiolate) converts into a non-hollow NC (e.g., [Ag25(SR)18]-), and vice versa. Our study reveals that the complete LE of the hollow [Ag44(SPhF)30]4- NCs (–SPhF: 4-fluorobenzenethiolate) with incoming 2,4-dimethylbenzenethiol (HSPhMe2) induced distortions in the Ag44 structure forming the non-hollow [Ag25(SPhMe2)18]- by a disproportionation mechanism. While the reverse reaction of [Ag25(SPhMe2)18]- with HSPhF prompted an unusual dimerization of Ag25, followed by a rearrangement step that reproduces the original [Ag44(SPhF)30]4-. Remarkably, both the forward and the backward reactions proceed through similar size intermediates that seem to be governed by the boundary conditions set by the thermodynamic and electronic stability of the hollow and non-hollow metal cores. Furthermore, the resizing of NCs highlights the surprisingly long-range effect of the ligands which are felt by atoms far deep in the metal core, thus opening a new path for controlling the structural evolution of nanoparticles.

  11. High-current electron beam generation in a diode with a multicapillary dielectric cathode

    Science.gov (United States)

    Gleizer, J. Z.; Hadas, Y.; Gurovich, V. Tz.; Felsteiner, J.; Krasik, Ya. E.

    2008-02-01

    Results of high-current electron beam generation in an ˜200kV, ˜250ns diode with a multicapillary dielectric cathode (MCDC) assisted by either velvet-type or ferroelectric plasma sources (FPSs) are presented. Multicapillary cathodes made of cordierite, glass, and quartz glass samples were studied. It was found that the source of electrons is the plasma ejected from capillaries. The plasma parameters inside capillary channels and in the vicinity of the cathode surface were determined during the accelerating pulse using visible range spectroscopy. It was shown that glass multicapillary cathodes are characterized by less surface erosion than the cordierite cathodes. Also, it was found that multicapillary cathodes assisted by a FPS showed longer lifetime and better vacuum compatibility than multicapillary cathodes assisted by a velvet-type igniter. Finally, it was found that quartz glass MCDC assisted by FPS is characterized by almost simultaneous formation of the plasma in a cross-sectional area of the dielectric sample with respect to the beginning of the accelerating pulse. The latter is explained by intense UV radiation which synchronized formation of parallel discharges due to induced secondary electron emission.

  12. High-Current Cold Cathode Employing Diamond and Related Materials

    Energy Technology Data Exchange (ETDEWEB)

    Hirshfield, Jay L. [Omega-P, Inc., New Haven, CT (United States)

    2014-10-22

    The essence of this project was for diamond films to be deposited on cold cathodes to improve their emission properties. Films with varying morphology, composition, and size of the crystals were deposited and the emission properties of the cathodes that utilize such films were studied. The prototype cathodes fabricated by the methods developed during Phase I were tested and evaluated in an actual high-power RF device during Phase II. These high-power tests used the novel active RF pulse compression system and the X-band magnicon test facility at US Naval Research Laboratory. In earlier tests, plasma switches were employed, while tests under this project utilized electron-beam switching. The intense electron beams required in the switches were supplied from cold cathodes embodying diamond films with varying morphology, including uncoated molybdenum cathodes in the preliminary tests. Tests with uncoated molybdenum cathodes produced compressed X-band RF pulses with a peak power of 91 MW, and a maximum power gain of 16.5:1. Tests were also carried out with switches employing diamond coated cathodes. The pulse compressor was based on use of switches employing electron beam triggering to effect mode conversion. In experimental tests, the compressor produced 165 MW in a ~ 20 ns pulse at ~18× power gain and ~ 140 MW at ~ 16× power gain in a 16 ns pulse with a ~ 7 ns flat-top. In these tests, molybdenum blade cathodes with thin diamond coatings demonstrated good reproducible emission uniformity with a 100 kV, 100 ns high voltage pulse. The new compressor does not have the limitations of earlier types of active pulse compressors and can operate at significantly higher electric fields without breakdown.

  13. Hollow waveguide for urology treatment

    Science.gov (United States)

    Jelínková, H.; Němec, M.; Koranda, P.; Pokorný, J.; Kőhler, O.; Drlík, P.; Miyagi, M.; Iwai, K.; Matsuura, Y.

    2010-02-01

    The aim of our work was the application of the special sealed hollow waveguide system for the urology treatment - In our experimental study we have compared the effects of Ho:YAG (wavelength 2100 nm) and Er:YAG (wavelength 2940 nm) laser radiation both on human urinary stones (or compressed plaster samples which serve as a model) fragmentation and soft ureter tissue incision in vitro. Cyclic Olefin Polymer - coated silver (COP/Ag) hollow glass waveguides with inner and outer diameters 700 and 850 μm, respectively, were used for the experiment. To prevent any liquid to diminish and stop the transmission, the waveguide termination was utilized.

  14. Controlled synthesis of double-wall a-FePO4 nanotubes and their LIB cathode properties.

    Science.gov (United States)

    Cai, Ren; Liu, Hai; Zhang, Wenyu; Tan, Huiteng; Yang, Dan; Huang, Yizhong; Hng, Huey Hoon; Lim, Tuti Mariana; Yan, Qingyu

    2013-04-08

    Double-wall amorphous FePO4 nanotubes are prepared by an oil-phase chemical route. The inward diffusion of vacancies and outward diffusion of ions through passivation layers result in double-wall nanotubes with thin walls. Such a process can be extended to prepare hollow polydedral nanocrystals and hollow ellipsoids. The double-wall FePO4 nanotubes show interesting cathode performance in Li ion batteries. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Nanostructured lanthanum manganate composite cathode

    DEFF Research Database (Denmark)

    Wang, Wei Guo; Liu, Yi-Lin; Barfod, Rasmus

    2005-01-01

    that the (La1-xSrx)(y)MnO3 +/-delta (LSM) composite cathodes consist of a network of homogenously distributed LSM, yttria-stabilized zirconia (YSZ), and pores. The individual grain size of LSM or YSZ is approximately 100 nm. The degree of contact between cathode and electrolyte is 39% on average. (c) 2005...

  16. Cathodic hydrodimerization of nitroolefins

    Directory of Open Access Journals (Sweden)

    Michael Weßling

    2015-07-01

    Full Text Available Nitroalkenes are easily accessible in high variety by condensation of aldehydes with aliphatic nitroalkanes. They belong to the group of activated alkenes that can be hydrodimerized by cathodic reduction. There are many olefins with different electron withdrawing groups used for cathodic hydrodimerization, but not much is known about the behaviour of the nitro group. Synthetic applications of this group could profit from the easy access to nitroolefins in large variety, the C–C bond formation with the introduction of two nitro groups in a 1,4-distance and the conversions of the nitro group by reduction to oximes and amines, the conversion into aldehydes and ketones via the Nef reaction and base catalyzed condensations at the acidic CH bond. Eight 1-aryl-2-nitro-1-propenes have been electrolyzed in an undivided electrolysis cell to afford 2,5-dinitro-3,4-diaryl hexanes in high yield. The 4-methoxy-, 4-trifluoromethyl-, 2-chloro- and 2,6-difluorophenyl group and furthermore the 2-furyl and 2-pyrrolyl group have been applied. The reaction is chemoselective as only the double bond but not the nitro group undergoes reaction, is regioselective as a ß,ß-coupling with regard to the nitro group and forms preferentially two out of six possible diastereomers as major products.

  17. Cathodic hydrodimerization of nitroolefins.

    Science.gov (United States)

    Weßling, Michael; Schäfer, Hans J

    2015-01-01

    Nitroalkenes are easily accessible in high variety by condensation of aldehydes with aliphatic nitroalkanes. They belong to the group of activated alkenes that can be hydrodimerized by cathodic reduction. There are many olefins with different electron withdrawing groups used for cathodic hydrodimerization, but not much is known about the behaviour of the nitro group. Synthetic applications of this group could profit from the easy access to nitroolefins in large variety, the C-C bond formation with the introduction of two nitro groups in a 1,4-distance and the conversions of the nitro group by reduction to oximes and amines, the conversion into aldehydes and ketones via the Nef reaction and base catalyzed condensations at the acidic CH bond. Eight 1-aryl-2-nitro-1-propenes have been electrolyzed in an undivided electrolysis cell to afford 2,5-dinitro-3,4-diaryl hexanes in high yield. The 4-methoxy-, 4-trifluoromethyl-, 2-chloro- and 2,6-difluorophenyl group and furthermore the 2-furyl and 2-pyrrolyl group have been applied. The reaction is chemoselective as only the double bond but not the nitro group undergoes reaction, is regioselective as a ß,ß-coupling with regard to the nitro group and forms preferentially two out of six possible diastereomers as major products.

  18. Hollow Porous Hierarchical-Structured 0.5Li2MnO3·0.5LiMn0.4Co0.3Ni0.3O2 as a High-Performance Cathode Material for Lithium-Ion Batteries.

    Science.gov (United States)

    Fu, Fang; Tang, Jiayu; Yao, Yuze; Shao, Minhua

    2016-10-05

    We report a novel hollow porous hierarchical-architectured 0.5Li2MnO3·0.5LiMn0.4Co0.3Ni0.3O2 (LLO) for lithium-ion batteries (LIBs). The obtained lithium-rich layered oxides possess a large inner cavity, a permeable porous shell, and excellent structural robustness. In LIBs, such unique features are favorable for fast Li(+) transportation and can provide sufficient contact between active materials and electrolytes, accommodate more Li(+), and improve the kinetics of the electrochemical reaction. The as-prepared LLO displays an extremely high initial discharge capacity (296.5 mAh g(-1) at 0.2 C), high rate capability (162.6 mAh g(-1) at 10 C), and excellent cycling stability (237.6 mAh g(-1) after 100 cycles at 0.5 C and 153.8 mAh g(-1) after 200 cycles at 10 C). These values are superior to most literature data.

  19. Preparation and electrochemical properties of carbon-coated LiFePO4 hollow nanofibers

    Science.gov (United States)

    Wei, Bin-bin; Wu, Yan-bo; Yu, Fang-yuan; Zhou, Ya-nan

    2016-04-01

    Carbon-coated LiFePO4 hollow nanofibers as cathode materials for Li-ion batteries were obtained by coaxial electrospinning. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Brunauer-Emmett-Teller specific surface area analysis, galvanostatic charge-discharge, and electrochemical impedance spectroscopy (EIS) were employed to investigate the crystalline structure, morphology, and electrochemical performance of the as-prepared hollow nanofibers. The results indicate that the carbon-coated LiFePO4 hollow nanofibers have good long-term cycling performance and good rate capability: at a current density of 0.2C (1.0C = 170 mA·g-1) in the voltage range of 2.5-4.2 V, the cathode materials achieve an initial discharge specific capacity of 153.16 mAh·g-1 with a first charge-discharge coulombic efficiency of more than 97%, as well as a high capacity retention of 99% after 10 cycles; moreover, the materials can retain a specific capacity of 135.68 mAh·g-1, even at 2C.

  20. Preparation and electrochemical properties of carbon-coated LiFePO4 hollow nanofibers

    Institute of Scientific and Technical Information of China (English)

    Bin-bin Wei; Yan-bo Wu; Fang-yuan Yu; Ya-nan Zhou

    2016-01-01

    Carbon-coated LiFePO4 hollow nanofibers as cathode materials for Li-ion batteries were obtained by coaxial electrospinning. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Brunauer–Emmett–Teller specific surface area analysis, galvanostatic charge–discharge, and electrochemical impedance spectroscopy (EIS) were employed to investigate the crystalline structure, morphology, and electrochemical performance of the as-prepared hollow nanofibers. The results indicate that the carbon-coated LiFePO4 hollow nanofibers have good long-term cycling performance and good rate capability:at a current density of 0.2C (1.0C=170 mA·g−1) in the voltage range of 2.5–4.2 V, the cathode materials achieve an initial discharge specific capacity of 153.16 mAh·g−1 with a first charge–discharge coulombic efficiency of more than 97%, as well as a high capacity retention of 99%after 10 cycles;moreover, the materi-als can retain a specific capacity of 135.68 mAh·g−1, even at 2C.

  1. Hollow waveguide cavity ringdown spectroscopy

    Science.gov (United States)

    Dreyer, Chris (Inventor); Mungas, Greg S. (Inventor)

    2012-01-01

    Laser light is confined in a hollow waveguide between two highly reflective mirrors. This waveguide cavity is used to conduct Cavity Ringdown Absorption Spectroscopy of loss mechanisms in the cavity including absorption or scattering by gases, liquid, solids, and/or optical elements.

  2. PIC-DSMC simulation of a triggered vacuum switch with a copper/beryllium cathode

    Science.gov (United States)

    Fierro, Andrew; Moore, Chris; Moore, Stan; Biedermann, Laura; Hopkins, Matthew

    2016-09-01

    Typical vacuum discharge simulations rely on the injection of neutral or ionized metal vapor from the cathode into an electrically stressed anode-cathode gap. Simultaneous electron emission, also from the cathode, allows for electron-impact ionization of the emitted metal vapor allowing for plasma formation and subsequent closing mechanism to begin. This work looks to analyze the effect of photoemission from the cathode and/or photoionization of metal vapor on the switch closing process through kinetic simulation techniques. A 500 micron anode-cathode gap is chosen with a variable voltage applied to the anode and a grounded half copper, half beryllium cathode. Injection of the metal vapor for both cathode materials is modeled as a linearly ramped flux with a temperature of 1500 K and a bulk velocity (13.2 km/s for Cu and 22 km/s for Be) away from the cathode. Electron-impact excitation of the emitted metal vapor allows for subsequent spontaneous emission of photons which can then photoionize the metal vapor or cause photoemission from the cathode. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. DOE's NNSA under contract DE-AC04-94AL85000.

  3. Erythrocyte-like hollow carbon capsules and their application in proton exchange membrane fuel cells.

    Science.gov (United States)

    Kim, Jung Ho; Yu, Jong-Sung

    2010-12-14

    Hierarchical nanostructured erythrocyte-like hollow carbon (EHC) with a hollow hemispherical macroporous core of ca. 230 nm in diameter and 30-40 nm thick mesoporous shell was synthesized and explored as a cathode catalyst support in a proton exchange membrane fuel cell (PEMFC). The morphology control of EHC was successfully achieved using solid core/mesoporous shell (SCMS) silica template and different styrene/furfuryl alcohol mixture compositions by a nanocasting method. The EHC-supported Pt (20 wt%) cathodes prepared have demonstrated markedly enhanced catalytic activity towards oxygen reduction reactions (ORRs) and greatly improved PEMFC polarization performance compared to carbon black Vulcan XC-72 (VC)-supported ones, probably due to the superb structural characteristics of the EHC such as uniform size, well-developed porosity, large specific surface area and pore volume. In particular, Pt/EHC cathodes exhibited ca. 30-60% higher ORR activity than a commercial Johnson Matthey Pt catalyst at a low catalyst loading of 0.2 mg Pt cm(-2).

  4. Hollow melon-seed-shaped lithium iron phosphate micro- and sub-micrometer plates for lithium-ion batteries.

    Science.gov (United States)

    Yang, Xian-Feng; Yang, Jin-Hua; Zhong, Yu Lin; Gariepy, Vincent; Trudeau, Michel L; Zaghib, Karim; Ying, Jackie Y

    2014-06-01

    Melon-seed-shaped LiFePO4 hollow micro- and sub-micrometer plates have been synthesized via a polyol-assisted hydrothermal method. The as-prepared LiFePO4 hollow materials were new with regard to their single-crystalline shells with large ac surfaces. Based on the detailed analysis of time-dependent studies, a possible growth mechanism was proposed involving nucleation, anisotropic growth, selective etching, and reversed recrystallization. The effects of polyol concentration, reaction temperature, and feeding sequence of precursors on the growth of LiFePO4 materials were investigated. The electrochemical properties of as-prepared LiFePO4 hollow materials were examined as cathode materials.

  5. The effect of plasma-nitrided titanium surfaces on osteoblastic cell adhesion, proliferation, and differentiation.

    Science.gov (United States)

    Ferraz, Emanuela P; Sa, Juliana C; de Oliveira, Paulo T; Alves, Clodomiro; Beloti, Marcio M; Rosa, Adalberto L

    2014-04-01

    In this study, we evaluated the effect of new plasma-nitrided Ti surfaces on the progression of osteoblast cultures, including cell adhesion, proliferation and differentiation. Ti surfaces were treated using two plasma-nitriding protocols, hollow cathode for 3 h (HC 3 h) and 1 h (HC 1 h) and planar for 1 h. Untreated Ti surfaces were used as control. Cells derived from human alveolar and rat calvarial bones were cultured on Ti surfaces for periods of up to 14 days and the following parameters were evaluated: cell morphology, adhesion, spreading and proliferation, alkaline phosphatase (ALP) activity, extracellular matrix mineralization, and gene expression of key osteoblast markers. Plasma-nitriding treatments resulted in Ti surfaces with distinct physicochemical characteristics. The cell adhesion and ALP activity were higher on plasma-nitrided Ti surfaces compared with untreated one, whereas cell proliferation and extracellular matrix mineralization were not affected by the treatments. In addition, the plasma-nitrided Ti surfaces increased the ALP, reduced the osteocalcin and did not affect the Runx2 gene expression. We have shown that HC 3 h and planar Ti surfaces slightly favored the osteoblast differentiation process, and then these surfaces should be considered for further investigation using preclinical models. Copyright © 2013 Wiley Periodicals, Inc.

  6. Dynamics of the formation and loss of boron atoms in a H2/B2H6 microwave plasma

    Science.gov (United States)

    Duluard, C. Y.; Aubert, X.; Sadeghi, N.; Gicquel, A.

    2016-09-01

    For further improvements in doped-diamond deposition technology, an understanding of the complex chemistry in H2/CH4/B2H6 plasmas is of general importance. In this context, a H2/B2H6 plasma ignited by microwave power in a near resonant cavity at high pressure (100-200 mbar) is studied to measure the B-atom density in the ground state. The discharge is ignited in the gas mixture (0-135 ppm B2H6 in H2) by a 2.45 GHz microwave generator, leading to the formation of a hemispheric plasma core, surrounded by a faint discharge halo filling the remaining reactor volume. Measurements with both laser induced fluorescence and resonant absoption with a boron hollow cathode lamp indicate that the B-atom density is higher in the halo than in the plasma core. When the absorption line-of-sight is positioned in the halo, the absorption is so strong that the upper detection limit is reached. To understand the mechanisms of creation and loss of boron atoms, time-resolved absorption measurements have been carried out in a pulsed plasma regime (10 Hz, duty cycle 50%). The study focuses on the influence of the total pressure, the partial pressure of B2H6, as well as the source power, on the growth and decay rates of boron atoms when the plasma is turned off.

  7. Cathodic contact glow discharge electrolysis: its origin and non-faradaic chemical effects

    Science.gov (United States)

    Gupta, Susanta K. Sen; Singh, Rajshree

    2017-01-01

    Normal electrolysis (NE), at sufficiently high voltages, breaks down and undergoes a transition to a phenomenon called contact glow discharge electrolysis (CGDE) in which a sheath of glow discharge plasma encapsulates one of the electrodes, the anode or the cathode. The chemical effects of CGDE are highly non-faradaic e.g. a mixture of H2 and H2O2 plus O2 each in excess of the Faraday law value is liberated at the glow discharge plasma electrode from an aqueous electrolyte solution. Studies of cathodic CGDE, particularly its origin and chemical effects, in comparison to those of anodic CGDE have received significantly less attention and have not been studied in detail. The present paper is an attempt towards elucidation of the mechanisms of the growth of cathodic CGDE during NE and its non-faradaic chemical effects. The findings of the study have led to the inference that emission of secondary electrons from the metal cathode with sufficient kinetic energies, vaporization of the electrolyte solvent in the vicinity of the cathode surface induced by Joule heating and the onset of hydrodynamic instabilities in local vaporization contribute to the generation of the plasma at the cathode during NE. The findings have further shown that non-faradaic yields of CGDE at the cathode originate from energy transfer processes in two reaction zones: a plasma phase reaction zone around the cathode which accounts for ~75% of the yields, and a liquid phase reaction zone near the plasma-catholyte solution interface accounting for the remaining ~25% of the yields.

  8. Hollow waveguides with low intrinsic photoluminescence fabricated with Ta2O5 and SiO2 films

    OpenAIRE

    Zhao, Y.; Jenkins, M; Measor, P.; Leake, K.; Liu, S.; Schmidt, H.; Hawkins, A R

    2011-01-01

    A type of integrated hollow core waveguide with low intrinsic photoluminescence fabricated with Ta2O5 and SiO2 films is demonstrated. Hollow core waveguides made with a combination of plasma-enhanced chemical vapor deposition SiO2 and sputtered Ta2O5 provide a nearly optimal structure for optofluidic biofluorescence measurements with low optical loss, high fabrication yield, and low background photoluminescence. Compared to earlier structures made using Si3N4, the photoluminescence background...

  9. Efficient Overall Water-Splitting Electrocatalysis Using Lepidocrocite VOOH Hollow Nanospheres

    KAUST Repository

    Shi, Huanhuan

    2016-11-29

    Herein we report the control synthesis of lepidocrocite VOOH hollow nanospheres and further their applications in electrocatalytic water splitting for the first time. By tuning the surface area of the nanospheres, the optimal performance can be achieved with low overpotentials of 270 mV for the oxygen evolution reaction (OER) and 164 mV for the hydrogen evolution reaction (HER) at 10 mA cm-2 in 1 m KOH, respectively. Furthermore, when used as both the anode and cathode for overall water splitting, a low cell voltage of 1.62 V is required to reach the current density of 10 mA cm-2 , making the VOOH hollow nanospheres an efficient alternative to water splitting.

  10. Electrochemically Active Polymeric Hollow Fibers based on Poly(ether- b -amide)/Carbon Nanotubes

    KAUST Repository

    Cuevas, Carolina

    2017-09-18

    A simple and effective method to incorporate catalytic activity to a hollow fiber membrane is reported. Polyetherimide hollow fiber membranes were coated with a solution containing carboxyl-functionalized multi-walled carbon nanotubes and poly(ether-b-amide). Electron microscopy images confirmed the presence of a layer of percolating carbon nanotubes on the surface of the membranes. Cyclic voltammetry and linear swept voltammetry experiments showed that these membranes are able to drive the reactions of hydrogen evolution, and oxygen reduction, making them a cheaper, and greener substitute for platinum based cathodes in microbial bioelectrochemical systems. Water flux and molecular weight cut off experiments indicated that the electrochemically active coating layer does not affect the ultrafiltration performance of the membrane.

  11. Sacrificial Template Synthesis and Properties of 3D Hollow-Silicon Nano- and Microstructures.

    Science.gov (United States)

    Hölken, Iris; Neubüser, Gero; Postica, Vasile; Bumke, Lars; Lupan, Oleg; Baum, Martina; Mishra, Yogendra Kumar; Kienle, Lorenz; Adelung, Rainer

    2016-08-10

    Novel three-dimensional (3D) hollow aero-silicon nano- and microstructures, namely, Si-tetrapods (Si-T) and Si-spheres (Si-S) were synthesized by a sacrificial template approach for the first time. The new Si-T and Si-S architectures were found as most temperature-stable hollow nanomaterials, up to 1000 °C, ever reported. The synthesized aero-silicon or aerogel was integrated into sensor structures based on 3D networks. A single microstructure Si-T was employed to investigate electrical and gas sensing properties. The elaborated hollow microstructures open new possibilities and a wide area of perspectives in the field of nano- and microstructure synthesis by sacrificial template approaches. The enormous flexibility and variety of the hollow Si structures are provided by the special geometry of the sacrificial template material, ZnO-tetrapods (ZnO-T). A Si layer was deposited onto the surface of ZnO-T networks by plasma-enhanced chemical vapor deposition. All samples demonstrated p-type conductivity; hence, the resistance of the sensor structure increased after introducing the reducing gases in the test chamber. These hollow structures and their unique and superior properties can be advantageous in different fields, such as NEMS/MEMS, batteries, dye-sensitized solar cells, gas sensing in harsh environment, and biomedical applications. This method can be extended for synthesis of other types of hollow nanostructures.

  12. Synthesis, characterization and X-ray spectral investigation of hollow graphitic carbon nanospheres

    Energy Technology Data Exchange (ETDEWEB)

    Ilkiv, Bogdan [Frantsevich Institute for Problems of Materials Science, 3 Krzhyzhanivsky Str., Kyiv 03680 (Ukraine); Petrovska, Svitlana, E-mail: sw.piotrowska@gmail.com [Frantsevich Institute for Problems of Materials Science, 3 Krzhyzhanivsky Str., Kyiv 03680 (Ukraine); Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Sendai 980-8577 (Japan); Sergiienko, Ruslan [Physico-Technological Institute of Metals and Alloys NAS of Ukraine, 34/1 Vernadsky Ave., Kyiv 142 03680 (Ukraine); Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Sendai 980-8577 (Japan); Foya, Oleksandr [Frantsevich Institute for Problems of Materials Science, 3 Krzhyzhanivsky Str., Kyiv 03680 (Ukraine); Ilkiv, Oleksandra [National Technical University of Ukraine “Kyiv Polytechnic Institute”, Engineering-Physical Faculty, 35 Polytekchnichna Str., Kyiv 03056 (Ukraine); Shibata, Etsuro; Nakamura, Takashi [Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Sendai 980-8577 (Japan); Zaulychnyy, Yaroslav [Frantsevich Institute for Problems of Materials Science, 3 Krzhyzhanivsky Str., Kyiv 03680 (Ukraine); National Technical University of Ukraine “Kyiv Polytechnic Institute”, Engineering-Physical Faculty, 35 Polytekchnichna Str., Kyiv 03056 (Ukraine)

    2014-12-25

    Highlights: • We synthesized hollow graphitic carbon nanospheres. • We investigated the electronic structure of hollow graphitic carbon nanospheres. • Additional mixed π + σ overlapping occurred in the hollow graphitic carbon nanospheres. • Some residual iron atoms form sp hybrid bonds with carbon. - Abstract: Hollow graphitic carbon nanospheres (HGCNSs) obtained by treatment of iron carbide-filled carbon nanocapsules were investigated using the ultra-soft X-ray emission spectroscopy method. Carbon nanocapsules were synthesized by the plasma discharge method in an ultrasonic cavitation field of liquid hexane. It was revealed that additional mixed π + σ-overlapping occurred in the hollow graphitic carbon nanospheres as a result of the bending of the graphene sheets. Some iron atoms remained after washing in acid. It was found that in the hollow graphitic carbon nanospheres, sp-hybrid bonds formed between the carbon and residual iron atoms when high-energy 3d + 4s-states overlapped with sp{sup n}-hybrid orbitals (2 < n < 3). Scanning and transmission electron microscopy methods were used to study the spatial morphology and structure of the fabricated HGCNSs. The electronic structures of the HGCNSs were compared with those of reference synthetic graphite powder, carbon onions, and graphene nanosheets.

  13. 78 FR 60271 - Hollow Dam Power Company; Ampersand Hollow Dam Hydro, LLC; Notice of Application for Transfer of...

    Science.gov (United States)

    2013-10-01

    ... Federal Energy Regulatory Commission Hollow Dam Power Company; Ampersand Hollow Dam Hydro, LLC; Notice of..., Hollow Dam Power Company (transferor) and Ampersand Hollow Dam Hydro, LLC (transferee) filed an application for transfer of license for the Hollow Dam Project, FERC No. 6972, located on the West Branch...

  14. Characteristics of Cu implantation into Si by PBII using UBMS cathode

    Institute of Scientific and Technical Information of China (English)

    于伟东; 夏立芳; 孙跃

    2001-01-01

    The implantation of Cu into Si substrate was carried out by plasma-based ion implantation (PBII) using unbalanced magnetron sputtering (UBMS) cathode as the metal plasma source. The different pulse bias (Up) and the distance between the cathode and the samples (ds-t) were chosen to research the characteristics of this method. The results show that the implantation of metal ions can be realized by the metal plasma source of UBMS cathode. The physical process such as the metal ion pure implantation, the gas ion implantation, the recoil implantation of the metal atoms, the deposition of the metal particles and the re-sputtering of the metal film depend on the energy, dose and deposition rate of the ions (Cu+, Ar+). The metal plasma based ion implantation of Cu into Si substrate is favored by selecting higher Up (60  kV) and larger ds-t (200  mm).

  15. Hollow chain-like beams

    CERN Document Server

    Cherepko, Dmitriy; Popkov, Ivan

    2012-01-01

    To generate hollow chain-like beams the diffraction of the first order Bessel beam by zone plate with two odd open Fresnel zone has been investigated. It has been shown that the capsules size is influenced by the number of the second odd open Fresnel zone and by the zone plate focal length. A hollow chain-like beam has been experimentally generated as a result of the first order Bessel beam diffraction by zone plate with the first and the ninth open Fresnel zones. The orbital angular momentum presence has been proved experimentally. The main features of the beam have been investigated. Sufficiently good agreement between experimental and numerically calculated results has been demonstrated.

  16. Fabrication of Metallic Hollow Nanoparticles

    Science.gov (United States)

    Kim, Jae-Woo (Inventor); Choi, Sr., Sang H. (Inventor); Lillehei, Peter T. (Inventor); Chu, Sang-Hyon (Inventor); Park, Yeonjoon (Inventor); King, Glen C. (Inventor); Elliott, James R. (Inventor)

    2016-01-01

    Metal and semiconductor nanoshells, particularly transition metal nanoshells, are fabricated using dendrimer molecules. Metallic colloids, metallic ions or semiconductors are attached to amine groups on the dendrimer surface in stabilized solution for the surface seeding method and the surface seedless method, respectively. Subsequently, the process is repeated with additional metallic ions or semiconductor, a stabilizer, and NaBH.sub.4 to increase the wall thickness of the metallic or semiconductor lining on the dendrimer surface. Metallic or semiconductor ions are automatically reduced on the metallic or semiconductor nanoparticles causing the formation of hollow metallic or semiconductor nanoparticles. The void size of the formed hollow nanoparticles depends on the dendrimer generation. The thickness of the metallic or semiconductor thin film around the dendrimer depends on the repetition times and the size of initial metallic or semiconductor seeds.

  17. Purification of nanoparticles by hollow fiber diafiltration

    Science.gov (United States)

    Veeken, J.

    2012-09-01

    Hollow Fiber Diafiltration (Hollow Fiber Tangential Flow Filtration) is an efficient and rapid alternative to traditional methods of nanoparticle purification such as ultracentrifugation, stirred cell filtration, dialysis or chromatography. Hollow Fiber Diafiltration can be used to purify a wide range of nanoparticles including liposomes, colloids, magnetic particles and nanotubes. Hollow Fiber Diafiltration is a membrane based method where pore size determines the retention or transmission of solution components. It is a flow process where the sample is gently circulated through a tubular membrane. With controlled replacement of the permeate or (dialysate), pure nanoparticles can be attained. Hollow Fiber Diafiltration can be directly scaled up from R&D volumes to production. By adding more membrane fibers and maintaining the operating parameters, large volumes can be processed in the same time with the same pressure, and flow dynamics as bench-scale volumes. Keywords: hollow fiber, Diafiltration, filtration, purification, tangential flow filtration.

  18. Hollow-core grating fiber

    Science.gov (United States)

    Barillé, R.; Tajalli, P.; Roy, P.; Ahmadi-kandjani, S.; Kucharski, S.; Ortyl, E.

    2012-02-01

    We propose a new type of hollow-core fiber where the propagation is ensured by a photoinduced self-pattern acting as a surface relief grating (SRG). The SRG is written by launching a suitable laser beam with proper polarization in a capillary glass fiber with the inner surface previously coated with an azopolymer thin film. Such a grating acts as a wavelength/angle dependant reflective mirror and enhances the confinement and the propagation of the light.

  19. Cyclodextrin purification with hollow fibers

    Energy Technology Data Exchange (ETDEWEB)

    Berthod, A. (Univ. de Lyon 1, Villeubranne Cedex (France)); Jin, Heng Liang,; Armstrong, D.W. (Univ. of Missouri, Rolla (USA))

    1991-01-01

    Cyclodextrins are cyclic 1-4 linked oligomers of {alpha}-D-glucopyranose prepared from starch hydrolysis through enzymatic reactions. Mixtures of the three main cyclodextrins (CD), {alpha}-, {beta}-, and {gamma}-CDs, are always produced. A possible facile purification process is proposed. Permeation through hollow fibers made of a perfluorinated ionomer membrane. Nafion type, is shown to be an effective way to separate {alpha}-CD from {beta}- and {gamma}-CD. {Alpha}-CD with 95% purity was obtained after permeation through a Nafion hollow fiber of an equimolar 0.02 M solution of the three CDs. The fiber had a 56 cm{sup 2}/cm{sup 3} surface area per volume ratio. Kinetic studies and continuous extraction experiments with a 2-m coiled fiber showed that it is possible to obtain a 11.5 g {alpha}-CD solution with 92.4% purity or a 0.6 g {alpha}-CD solution with 97.2% purity, depending on the flow rate. The transport of CDs through the membrane could be due to moving water pools inside the ionomer. The small {alpha}-CD fits easily in such pools when the large {beta}- and {gamma}-CDs are excluded by steric hindrance. Temperature raises increased the permeation rates while decreasing the selectivity. The process could be scaled-up associating hollow fibers in bundle.

  20. Space Charge Mitigation With Longitudinally Hollow Bunches

    CERN Multimedia

    Oeftiger, Adrian; Rumolo, Giovanni

    2016-01-01

    Hollow longitudinal phase space distributions have a flat profile and hence reduce the impact of transverse space charge. Dipolar parametric excitation with the phase loop feedback systems provides such hollow distributions under reproducible conditions. We present a procedure to create hollow bunches during the acceleration ramp of CERN’s PS Booster machine with minimal changes to the operational cycle. The improvements during the injection plateau of the downstream Proton Synchrotron are assessed in comparison to standard parabolic bunches.

  1. Space Charge Mitigation With Longitudinally Hollow Bunches

    CERN Document Server

    Oeftiger, Adrian; Rumolo, Giovanni; CERN. Geneva. ATS Department

    2016-01-01

    Suitably, hollow longitudinal phase space distributions have a flat profile and hence reduce the impact of transverse space charge. Dipolar parametric excitation with the phase loop feedback systems provides such hollow distributions under reproducible conditions. We present a procedure to create hollow bunches during the acceleration ramp of CERN’s PS Booster machine with minimal changes to the operational cycle. The improvements during the injection plateau of the downstream Proton Synchrotron are assessed in comparison to standard parabolic bunches.

  2. Influence of Jet Angle and Ion Density of Cathode Side on Low Current Vacuum Arc Characteristics

    Institute of Scientific and Technical Information of China (English)

    WANG Lijun; JIA Shenli; SHI Zongqian

    2008-01-01

    In this study, the influence of the initial jet angles (IJAs) and ion number densities (INDs) at the cathode side on the low current vacuum arc (LCVA) characteristics is simulated and analysed. The results show that the ion temperature, electron temperature, ion number density, axial current density and plasma pressure all decrease with the increase of the cathode IJAs. It is also shown that LCVA can cause a current constriction for lower cathode IND, and the anode sheath potential is more nonuniform, which is mainly related to the nonuniform distribution of the axial current density at the anode side.

  3. Liquid cathode primary batteries

    Science.gov (United States)

    Schlaikjer, Carl R.

    1985-03-01

    Lithium/liquid cathode/carbon primary batteries offer from 3 to 6 times the volumetric energy density of zinc/alkaline manganese cells, improved stability during elevated temperature storage, satisfactory operation at temperatures from -40 to +150 °C, and efficient discharge at moderate rates. he lithium/sulfur dioxide cell is the most efficient system at temperatures below 0 °C. Although chemical reactions leading to electrolyte degradation and lithium corrosion are known, the rates of these reactions are slow. While the normal temperature cell reaction produces lithium dithionite, discharge at 60 °C leads to a reduction in capacity due to side reactions involving sulfur dioxide and discharge intermediates. Lithium/thionyl chloride and lithium/sulfuryl chloride cells have the highest practical gravimetric and volumetric energy densities when compared with aqueous and most other nonaqueous systems. For thionyl chloride, discharge proceeds through a series of intermediates to sulfur, sulfur dioxide and lithium chloride. Catalysis, leading to improved rate capability and capacity, has been achieved. The causes of rapid reactions leading to thermal runaway are thought to be chemical in nature. Lithium/sulfuryl chloride cells, which produce sulfur dioxide and lithium chloride on discharge, experience more extensive anode corrosion. An inorganic cosolvent and suitable salt are capable of alleviating this corrosion. Calcium/oxyhalide cells have been studied because of their promise of increased safety without substantial sacrifice of energy density relative to lithium cells. Anode corrosion, particularly during discharge, has delayed practical development.

  4. Liquid cathode primary batteries

    Energy Technology Data Exchange (ETDEWEB)

    Schlaikjer, C.R.

    1985-01-15

    Lithium/liquid cathode/carbon primary batteries offer from 3 to 6 times the volumetric energy density of zinc/alkaline manganese cells, improved stability during elevated temperature storage, satisfactory operation at temperatures from -40 to +150/sup 0/C, and efficient discharge at moderate rates. The lithium/sulfur dioxide cell is the most efficient system at temperatures below 0/sup 0/C. Although chemical reactions leading to electrolyte degradation and lithium corrosion are known, the rates of these reactions are slow. While the normal temperature cell reaction produces lithium dithionite, discharge at 60/sup 0/C leads to a reduction in capacity due to side reactions involving sulfur dioxide and discharge intermediates. Lithium/thionyl chloride and lithium/sulfuryl chloride cells have the highest practical gravimetric and volumetric energy densities when compared with aqueous and most other nonaqueous systems. For thionyl chloride, discharge proceeds through a series of intermediates to sulfur, sulfur dioxide and lithium chloride. Catalysis, leading to improved rate capability and capacity, has been achieved. The causes of rapid reactions leading to thermal runaway are thought to be chemical in nature. Lithium/sulfuryl chloride cells, which produce sulfur dioxide and lithium chloride on discharge, experience more extensive anode corrosion. An inorganic cosolvent and suitable salt are capable of alleviating this corrosion. Calcium/oxyhalide cells have been studied because of their promise of increased safety without substantial sacrifice of energy density relative to lithium cells. Anode corrosion, particularly during discharge, has delayed practical development.

  5. Hollow fibers for compact infrared gas sensors

    Science.gov (United States)

    Lambrecht, A.; Hartwig, S.; Herbst, J.; Wöllenstein, J.

    2008-02-01

    Hollow fibers can be used for compact infrared gas sensors. The guided light is absorbed by the gas introduced into the hollow core. High sensitivity and a very small sampling volume can be achieved depending on fiber parameters i.e. attenuation, flexibility, and gas exchange rates. Different types of infrared hollow fibers including photonic bandgap fibers were characterized using quantum cascade lasers and thermal radiation sources. Obtained data are compared with available product specifications. Measurements with a compact fiber based ethanol sensor are compared with a system simulation. First results on the detection of trace amounts of the explosive material TATP using hollow fibers and QCL will be shown.

  6. Fast plasma discharge capillary design as a high power throughput soft x-ray emission source.

    Science.gov (United States)

    Wyndham, E S; Favre, M; Valdivia, M P; Valenzuela, J C; Chuaqui, H; Bhuyan, H

    2010-09-01

    We present the experimental details and results from a low energy but high repetition rate compact plasma capillary source for extreme ultraviolet and soft x-ray research and applications. Two lengths of capillary are mounted in two versions of a closely related design. The discharge operates in 1.6 and 3.2 mm inner diameter alumina capillaries of lengths 21 and 36 mm. The use of water both as dielectric and as coolant simplifies the compact low inductance design with nanosecond discharge periods. The stored electrical energy of the discharge is approximately 0.5 J and is provided by directly charging the capacitor plates from an inexpensive insulated-gate bipolar transistor in 1 μs or less. We present characteristic argon spectra from plasma between 30 and 300 Å as well as temporally resolved x-ray energy fluence in discrete bands on axis. The spectra also allow the level of ablated wall material to be gauged and associated with useful capillary lifetime according to the chosen configuration and energy storage. The connection between the electron beams associated with the transient hollow cathode mechanism, soft x-ray output, capillary geometry, and capillary lifetime is reported. The role of these e-beams and the plasma as measured on-axis is discussed. The relation of the electron temperature and the ionization stages observed is discussed in the context of some model results of ionization in a non-Maxwellian plasma.

  7. Deactivating bacteria with RF Driven Hollow Slot Microplasmas in Open Air at Atmospheric Pressure

    Science.gov (United States)

    Yu, Zengqi; Pruden, Amy; Sharma, Ashish; Collins, George

    2003-10-01

    A hollow slot discharge operating in open air at atmospheric pressure has demonstrated its ability to deactivate bacterial growth on nearby surfaces exposed to the RF driven plasma. The cold plasma exits from a hollow slot with a width of 0.2 mm and variable length of 1-35 cm. An internal electrode was powered by 13.56 MHz radio-frequency power at a voltage below 200 V. External electrically grounded slots face the work piece. The plasma plume extends millimeters to centimeter beyond the hollow slot toward the work piece to be irradiated. Argon-Oxygen gas mixtures, at 33 liters per minute flow, were passed through the electrodes and the downstream plasma was employed for the process, with treatment exposure time varied from 0.06 to 0.18 seconds. Bacterial cultures were fixed to 0.22 micron cellulose filter membranes and passed under the plasma at a controlled rate at a distance of about 5-10 millimeters from the grounded slot electrode. Preliminary studies on the effectiveness of the plasma for sterilization were carried out on E. coli. Cultures were grown overnight on the membranes after exposure and the resulting colony forming units (cfu) were determined in treated and untreated groups. In the plasma treated group, a 98.2% kill rate was observed with the lowest exposure time, and increased to 99.8% when the exposure time was tripled. These studies clearly demonstrate the ability of the RF-driven hollow slot atmospheric plasma to inhibit bacterial growth on surfaces.

  8. Accelerating Solitons in Gas-Filled Hollow-Core Photonic Crystal Fibers

    CERN Document Server

    Facao, M; Almeida, P

    2013-01-01

    We found the self-similar solitary solutions of a recently proposed model for propagation of pulses in gas filled hollow-core photonic crystal fibers that includes a plasma induced nonlinearity. As anticipated for a simpler model and using a perturbation analysis, there are indeed stationary solitary waves that accelerate and self-shift to higher frequencies. However, if the plasma nonlinearity strength is large or the pulse amplitudes are small, the solutions have distinguished long tails and decay as they propagate.

  9. Experimental investigations of the nonlinear dynamics of a complex space-charge configuration inside and around a grid cathode with hole

    Science.gov (United States)

    Teodorescu-Soare, C. T.; Dimitriu, D. G.; Ionita, C.; Schrittwieser, R. W.

    2016-03-01

    By negatively biasing a metallic grid with a small hole, down to a critical value of the applied potential a complex space-charge structure appears inside and around the grid cathode. The static current-voltage characteristic of the discharge shows one or two current jumps (the number of current jumps depending on the working gas pressure), one of them being of hysteretic type. Electrical probe measurements show a positive potential inside the grid cathode with respect to the potential applied on it. This is interpreted as being due to the hollow cathode effect. Thus, the inner fireball appears around the virtual anode inside the grid cathode. For more negative potentials, the electrons inside the cathode reach sufficient energy to penetrate the inner sheath near the cathode, passing through the hole and giving rise to a second fireball-like structure located outside the cathode. This second structure interacts with the negative glow of the discharge. The recorded time series of the discharge current oscillations reveal strongly nonlinear dynamics of the complex space-charge structure: by changing the negative potential applied on the grid cathode, the structure passes through different dynamic states involving chaos, quasi-periodicity, intermittency and period-doubling bifurcations, appearing like a competition of different routes to chaos.

  10. Optical and electrical investigations into cathode ignition and diode closure

    Energy Technology Data Exchange (ETDEWEB)

    Coogan, J.J.; Rose, E.A.; Shurter, R.P.

    1991-01-01

    The temporal behavior of high-power diodes is closely related to the impedance collapse caused by the movement of the cathode and/or anode plasmas. This impedance collapse can be especially problematic when a constant power electron beam is required. This is the case for the very large area (square meters) diodes used to pump the amplifiers within the Aurora KrF laser system. The electron beam technology development program at Los Alamos utilizes the Electron Beam Test Facility (EGTF) to study diode physics in an attempt to better understand the basic phenomenology of ignition and closure. A combination of optical and electric diagnostics has been fielded on the Electron Beam Test Facility to study ignition and closure in large area electron beam diodes. A four-channel framing camera is used to observe the formation of microplasmas on the surface of the cathode and the subsequent movement of these plasmas toward the anode. Additionally, a perveance model is used to extract information about this plasma from voltage and current profiles. Results from the two diagnostics are compared. Closure velocity measurements are presented showing little dependence on applied magnetic field for both velvet and carbon felt emitters. We also report the first observation of the screening effect in large area cold cathode diodes. 13 refs., 11 figs.

  11. Optical and electrical investigations into cathode ignition and diode closure

    Science.gov (United States)

    Coogan, J. J.; Rose, E. A.; Shurter, R. P.

    The temporal behavior of high-power diodes is closely related to the impedance collapse caused by the movement of the cathode and/or anode plasmas. This impedance collapse can be especially problematic when a constant power electron beam is required. This is the case for the very large area (square meters) diodes used to pump the amplifiers within the Aurora KrF laser system. The electron beam technology development program at Los Alamos utilizes the Electron Beam Test Facility (EGTF) to study diode physics in an attempt to better understand the basic phenomenology of ignition and closure. A combination of optical and electric diagnostics has been fielded on the Electron Beam Test Facility to study ignition and closure in large area electron beam diodes. A four-channel framing camera is used to observe the formation of microplasmas on the surface of the cathode and the subsequent movement of these plasmas toward the anode. Additionally, a perveance model is used to extract information about this plasma from voltage and current profiles. Results from the two diagnostics are compared. Closure velocity measurements are presented showing little dependence on applied magnetic field for both velvet and carbon felt emitters. We also report the first observation of the screening effect in large area cold cathode diodes.

  12. Hollow system with fin. Transient Green function method combination for two hollow cylinders

    Directory of Open Access Journals (Sweden)

    Buikis Andris

    2017-01-01

    Full Text Available In this paper we develop mathematical model for three dimensional heat equation for the system with hollow wall and fin and construct its analytical solution for two hollow cylindrical sample. The method of solution is based on Green function method for one hollow cylinder. On the conjugation conditions between both hollow cylinders we construct solution for system wall with fin. As result we come to integral equation on the surface between both hollow cylinders. Solution is obtained in the form of second kind Fredholm integral equation. The generalizing of Green function method allows us to use Green function method for regular non-canonical domains.

  13. Traumatic and nontraumatic perforation of hollow viscera.

    Science.gov (United States)

    Espinoza, R; Rodríguez, A

    1997-12-01

    Hollow viscus injuries are usually managed with few complications. However, if their diagnosis is delayed, or if reparative suture closure should fail, the patient is placed at risk of multiple organ failure. This article presents diagnostic approaches, emphasizing imaging modalities, and therapeutic strategies for three clinical scenarios of hollow viscus perforation: 1) acute appendicitis, 2) gastroduodenal peptic ulcer disease, and 3) trauma.

  14. Adsorption characteristics of activated carbon hollow fibers

    OpenAIRE

    2009-01-01

    Carbon hollow fibers were prepared with regenerated cellulose or polysulfone hollow fibers by chemical activation using sodium phosphate dibasic followed by the carbonization process. The activation process increases the adsorption properties of fibers which is more prominent for active carbone fibers obtained from the cellulose precursor. Chemical activation with sodium phosphate dibasic produces an active carbon material with both mesopores and micropores.

  15. Positron Beam Propagation in a Meter Long Plasma Channel

    Energy Technology Data Exchange (ETDEWEB)

    Marsh, K.A.; Blue, B.E.; Clayton, C.E.; Joshi, C.; Mori, W.B.; /UCLA; Decker, F.-J.; Hogan, M.J.; Iverson, R.; O' Connell, C.; Raimondi, P.; Siemann, Robert H.; Walz, D.; /SLAC; Katsouleas, T.C.; Muggli, P.; /Southern California U.

    2008-03-17

    Recent experiments and simulations have shown that positron beams propagating in plasmas can be focused and also create wakes with large accelerating gradients. For similar parameters, the wakes driven by positron beams are somewhat smaller compared to the case of an electron beam. Simulations have shown that the wake amplitude can be increased if the positron beam is propagated in a hollow plasma channel (Ref. 1). This paper, compares experimentally, the propagation and beam dynamics of a positron beam in a meter scale homogeneous plasma, to a positron beam hollow channel plasma. The results show that positron beams in hollow channels are less prone to distortions and deflections. Hollow channels were observed to guide the positron beam onto the channel axis. Beam energy loss was also observed implying the formation of a large wake amplitude. The experiments were carried out as part of the E-162 plasma wakefield experiments at SLAC.

  16. Current self-limitation in a transverse nanosecond discharge with a slotted cathode

    Science.gov (United States)

    N, A. ASHURBEKOV; K, O. IMINOV; O, A. POPOV; G, S. SHAKHSINOV

    2017-03-01

    A high-voltage transverse pulsed nanosecond discharge with a slotted hollow cathode was found to be a source of high-energy (few kV) ribbon electron beams. Conditions for the formation and extinction of electron beams were experimentally studied in discharges in helium at pressures of 1–100 Torr. It was found that interaction of fast electrons with a non-uniform electric field near the slotted cathode led to limitation of the magnitude of the discharge current. A physical model was developed to describe the discharge current self-limitation that was in satisfactory agreement with the experimental results. Some technical solutions that are expected to increase the upper current limits in transverse nanosecond discharge are discussed.

  17. Reservoir Cathode for Electric Space Propulsion Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose a reservoir cathode to improve performance in both ion and Hall-effect thrusters. We propose to adapt our existing reservoir cathode technology to this...

  18. Mechanistic Enhancement of SOFC Cathode Durability

    Energy Technology Data Exchange (ETDEWEB)

    Wachsman, Eric [Univ. of Maryland, College Park, MD (United States)

    2016-02-01

    Durability of solid oxide fuel cells (SOFC) under “real world” conditions is an issue for commercial deployment. In particular cathode exposure to moisture, CO2, Cr vapor (from interconnects and BOP), and particulates results in long-term performance degradation issues. Here, we have conducted a multi-faceted fundamental investigation of the effect of these contaminants on cathode performance degradation mechanisms in order to establish cathode composition/structures and operational conditions to enhance cathode durability.

  19. Fabrication of functional hollow carbon spheres with large hollow interior as active colloidal catalysts

    Institute of Scientific and Technical Information of China (English)

    Qiang Sun; Guanghui Wang; Wencui Li; Xiangqian Zhang; Anhui Lu

    2012-01-01

    In this study,we have established a facile method to synthesize functional hollow carbon spheres with large hollow interior,which can act as active colloidal catalysts.The method includes the following steps:first,hollow polymer spheres with large hollow interior were prepared using sodium oleate as the hollow core generator,and 2,4-dihydroxybenzoic acid and hexamethylene tetramine (HMT) as the polymer precursors under hydrothermal conditions; Fe3+ or Ag+ cations were then introduced into the as-prepared hollow polymer spheres through the carboxyl groups; finally,the hollow polymer spheres can be pseudomorphically converted to hollow carbon spheres during pyrolysis process,meanwhile iron or silver nanoparticles can also be formed in the carbon shell simultaneously.The structures of the obtained functional hollow carbon spheres were characterized by TEM,XRD,and TG.As an example,Ag-doped hollow carbon spheres were used as colloid catalysts which showed high catalytic activity in 4-nitrophenol reduction reaction.

  20. 用中空纤维液相微萃取-HPLC法测定人血浆中酒石酸美托洛尔的浓度%Determination of the concentration of metoprolol tartrate in human plasma by HPLC coupled with hollow fiber liquid phase microextraction method

    Institute of Scientific and Technical Information of China (English)

    宫雪菲; 马海英; 易丽昕; 刘亚非

    2012-01-01

    Objective: To establish a HPLC coupled with hollow fiber liquid phase microextraction(HF-LPME) method for determination of the concentration of metoprolol tartrate in human plasma. Methods: The concentrations of donor phase and receptive phase,time, temperature and rotary speed of extraction,and concentration of NaCl in HF-LPME were optimized. The hollow fiber was placed in plasma sample solution to perform microextraction, and then the extract was analyzed by HPLC method with fluorescence detection on Agilent Zorbax XDB-C13 column. The mobile phase consisted of methanol-0. 1% phosphoric acid(40 ! 60) with a flow rate of 1 ml/min. The excitation wavelength was 227 nm and the emission wavelength was 305 nm. The column temperature was 30 C. Results: Metoprolol tartrate was in good linearity within the range of 2-125 ng/ml. The intra-day and inter-day RSD of low, middle and high concentrations ( 5, 20, 100 ng/ml) were all less than 10%, and recoveries were (87. 1±7. 3) % , (92. 6±5. 8) % and (89. 1±2. 5) % .respectively. Conclusion: HPLC coupled with HF-LPME method is suitable for analysis of concentration of metoprolol tartrate in human plasma.%目的:建立中空纤维液相微萃取-HPLC法测定人血浆中酒石酸美托洛尔的浓度.方法:优化酒石酸美托洛尔液相微萃取法供给相和接受相的浓度、萃取时间、萃取温度、萃取转速和离子强度,血浆样品经中空纤维液相微萃取法萃取后,用HPLC法测定酒石酸美托洛尔的浓度.色谱柱:Agilent Zorbax Eclipse XDB-C18柱,流动相:甲醇-0.1%磷酸(40∶60),流速:1 ml/min,激发波长:227 nm,发射波长:305 nm,柱温:30℃.结果:酒石酸美托洛尔在2~ 125 ng/ml线性关系良好,低、中、高三种浓度(5、20、100 ng/ml)的日内、日间精密度均<10%,回收率分别为(87.1±7.3)%、(92.6±5.8)%和(89.1±2.5)%.结论:中空纤维液相微萃取-HPLC法适用于测定血浆样品中酒石酸美托洛尔的浓度.

  1. Novel Cathodes Prepared by Impregnation Procedures

    Energy Technology Data Exchange (ETDEWEB)

    Eduardo Paz

    2006-09-30

    (1) We showed that similar results were obtained when using various LSM precursors to produce LSM-YSZ cathodes. (2) We showed that enhanced performance could be achieved by adding LSCo to LSMYSZ cathodes. (3) We have preliminary results showing that there is a slow deactivation with LSFYSZ cathodes.

  2. POROUS WALL, HOLLOW GLASS MICROSPHERES

    Energy Technology Data Exchange (ETDEWEB)

    Sexton, W.

    2012-06-30

    Hollow Glass Microspheres (HGM) is not a new technology. All one has to do is go to the internet and Google{trademark} HGM. Anyone can buy HGM and they have a wide variety of uses. HGM are usually between 1 to 100 microns in diameter, although their size can range from 100 nanometers to 5 millimeters in diameter. HGM are used as lightweight filler in composite materials such as syntactic foam and lightweight concrete. In 1968 a patent was issued to W. Beck of the 3M{trademark} Company for 'Glass Bubbles Prepared by Reheating Solid Glass Particles'. In 1983 P. Howell was issued a patent for 'Glass Bubbles of Increased Collapse Strength' and in 1988 H. Marshall was issued a patent for 'Glass Microbubbles'. Now Google{trademark}, Porous Wall, Hollow Glass Microspheres (PW-HGMs), the key words here are Porous Wall. Almost every article has its beginning with the research done at the Savannah River National Laboratory (SRNL). The Savannah River Site (SRS) where SRNL is located has a long and successful history of working with hydrogen and its isotopes for national security, energy, waste management and environmental remediation applications. This includes more than 30 years of experience developing, processing, and implementing special ceramics, including glasses for a variety of Department of Energy (DOE) missions. In the case of glasses, SRS and SRNL have been involved in both the science and engineering of vitreous or glass based systems. As a part of this glass experience and expertise, SRNL has developed a number of niches in the glass arena, one of which is the development of porous glass systems for a variety of applications. These porous glass systems include sol gel glasses, which include both xerogels and aerogels, as well as phase separated glass compositions, that can be subsequently treated to produce another unique type of porosity within the glass forms. The porous glasses can increase the surface area compared to &apos

  3. Filtered cathodic arc deposition with ion-species-selectivebias

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre; Pasaja, Nitisak; Sansongsiri, Sakon; Lim, SunnieH.N.

    2006-10-05

    A dual-cathode arc plasma source was combined with acomputer-controlled bias amplifier such as to synchronize substrate biaswith the pulsed production of plasma. In this way, bias can be applied ina material-selective way. The principle has been applied to the synthesismetal-doped diamond-like carbon films, where the bias was applied andadjusted when the carbon plasma was condensing, and the substrate was atground when the metal was incorporated. In doing so, excessive sputteringby too-energetic metal ions can be avoided while the sp3/sp2 ratio can beadjusted. It is shown that the resistivity of the film can be tuned bythis species-selective bias. The principle can be extended tomultiple-material plasma sources and complex materials

  4. A centre-triggered magnesium fuelled cathodic arc thruster uses sublimation to deliver a record high specific impulse

    Science.gov (United States)

    Neumann, Patrick R. C.; Bilek, Marcela; McKenzie, David R.

    2016-08-01

    The cathodic arc is a high current, low voltage discharge that operates in vacuum and provides a stream of highly ionised plasma from a solid conducting cathode. The high ion velocities, together with the high ionisation fraction and the quasineutrality of the exhaust stream, make the cathodic arc an attractive plasma source for spacecraft propulsion applications. The specific impulse of the cathodic arc thruster is substantially increased when the emission of neutral species is reduced. Here, we demonstrate a reduction of neutral emission by exploiting sublimation in cathode spots and enhanced ionisation of the plasma in short, high-current pulses. This, combined with the enhanced directionality due to the efficient erosion profiles created by centre-triggering, substantially increases the specific impulse. We present experimentally measured specific impulses and jet power efficiencies for titanium and magnesium fuels. Our Mg fuelled source provides the highest reported specific impulse for a gridless ion thruster and is competitive with all flight rated ion thrusters. We present a model based on cathode sublimation and melting at the cathodic arc spot explaining the outstanding performance of the Mg fuelled source. A further significant advantage of an Mg-fuelled thruster is the abundance of Mg in asteroidal material and in space junk, providing an opportunity for utilising these resources in space.

  5. Hollow Micro-/Nanostructures: Synthesis and Applications

    KAUST Repository

    Lou, Xiong Wen (David)

    2008-11-03

    Hollow micro-nanostructures are of great interest in many current and emerging areas of technology. Perhaps the best-known example of the former is the use of fly-ash hollow particles generated from coal power plants as partial replacement for Portland cement, to produce concrete with enhanced strength and durability. This review is devoted to the progress made in the last decade in synthesis and applications of hollow micro-nanostructures. We present a comprehensive overview of synthetic strategies for hollow structures. These strategies are broadly categorized into four themes, which include well-established approaches, such as conventional hard-templating and soft-templating methods, as well as newly emerging methods based on sacrificial templating and template-free synthesis. Success in each has inspired multiple variations that continue to drive the rapid evolution of the field. The Review therefore focuses on the fundamentals of each process, pointing out advantages and disadvantages where appropriate. Strategies for generating more complex hollow structures, such as rattle-type and nonspherical hollow structures, are also discussed. Applications of hollow structures in lithium batteries, catalysis and sensing, and biomedical applications are reviewed. © 2008 WILEY-VCH Verlag GmbH & Co. KGaA,.

  6. Catheterized plasma X-ray source

    Energy Technology Data Exchange (ETDEWEB)

    Derzon, Mark S.; Robinson, Alex; Galambos, Paul C.

    2017-06-20

    A radiation generator useful for medical applications, among others, is provided. The radiation generator includes a catheter; a plasma discharge chamber situated within a terminal portion of the catheter, a cathode and an anode positioned within the plasma discharge chamber and separated by a gap, and a high-voltage transmission line extensive through the interior of the catheter and terminating on the cathode and anode so as to deliver, in operation, one or more voltage pulses across the gap.

  7. Designing hollow nano gold golf balls.

    Science.gov (United States)

    Landon, Preston B; Mo, Alexander H; Zhang, Chen; Emerson, Chris D; Printz, Adam D; Gomez, Alan F; DeLaTorre, Christopher J; Colburn, David A M; Anzenberg, Paula; Eliceiri, Matthew; O'Connell, Connor; Lal, Ratnesh

    2014-07-09

    Hollow/porous nanoparticles, including nanocarriers, nanoshells, and mesoporous materials have applications in catalysis, photonics, biosensing, and delivery of theranostic agents. Using a hierarchical template synthesis scheme, we have synthesized a nanocarrier mimicking a golf ball, consisting of (i) solid silica core with a pitted gold surface and (ii) a hollow/porous gold shell without silica. The template consisted of 100 nm polystyrene beads attached to a larger silica core. Selective gold plating of the core followed by removal of the polystyrene beads produced a golf ball-like nanostructure with 100 nm pits. Dissolution of the silica core produced a hollow/porous golf ball-like nanostructure.

  8. Hollow Core, Whispering Gallery Resonator Sensors

    CERN Document Server

    Ward, Jonathan M; Chormaic, Síle Nic

    2014-01-01

    A review of hollow core whispering gallery resonators (WGRs)is given. After a short introduction to the topic of whispering gallery resonators we provide a description of whispering gallery modes in hollow or liquid core WGRs. Next, whispering gallery mode (WGM) sensing mechanisms are outlined and some fabrication methods for microbubbles, microcapillaries and other tubular WGM devices are discussed. We then focus on the most common applications of hollow core WGRs, namely refractive index and temperature sensing, gas sensing, force sensing, biosensing, and lasing. The review highlights some of the key papers in this field and gives the reader a general overview of the current state-of-the-art.

  9. Pulsed microhollow cathode discharge excimer sources

    Science.gov (United States)

    Moselhy, Mohamed; Shi, Wenhui; Strak, Robert H.; Schoenbach, Karl H.

    2001-10-01

    Microhollow cathode discharges (MHCDs) are non-equilibrium, high-pressure gas discharges between perforated electrodes separated by a dielectric layer. Typical dimensions for the electrode foil thickness and hole diameter are 100 μm. Direct current experiments in xenon, argon, neon, helium, argon fluoride, and xenon chloride [1,2] have been performed. The excimer efficiency varies between 1 % and 9 %. Pulsed operation allowed us to increase the current from 8 mA (dc) to approximately 80 mA (pulsed with a pulse width of 700 μs), limited by the onset of instabilities. The total excimer power was found to increase linearly with current, however, the radiant emittance and efficiency stayed constant. Reducing the pulse duration into the nanosecond range allowed us to increase the current into the ampere range. The maximum measured excimer power was 2.75 W per microdischarge. The maximum radiant emittance was 15 W/cm^2 and the efficiency reached values of 20 %. This effect is assumed to be due to non-equilibrium electron heating in the high-pressure plasma [3]. This work was supported by the National Science Foundation under grant # CTS0078618. 1. Karl H. Schoenbach, Ahmed El-Habachi, Mohamed M. Moselhy, Wenhui Shi, and Robert H. Stark, Physics of Plasmas 7, 2186 (2000). 2. P. Kurunczi, J. Lopez, H. Shah, and K. Becker, Int. J. Mass Spectrom. 205, 277 (2001). 3. Robert H. Stark and Karl H. Schoenbach, J. Appl. Phys. 89, 3568 (2001).

  10. Analysis of MESSENGER high-resolution images of Mercury's hollows and implications for hollow formation

    Science.gov (United States)

    Blewett, David T.; Stadermann, Amanda C.; Susorney, Hannah C.; Ernst, Carolyn M.; Xiao, Zhiyong; Chabot, Nancy L.; Denevi, Brett W.; Murchie, Scott L.; McCubbin, Francis M.; Kinczyk, Mallory J.; Gillis-Davis, Jeffrey J.; Solomon, Sean C.

    2016-09-01

    High-resolution images from MESSENGER provide morphological information on the nature and origin of Mercury's hollows, small depressions that likely formed when a volatile constituent was lost from the surface. Because graphite may be a component of the low-reflectance material that hosts hollows, we suggest that loss of carbon by ion sputtering or conversion to methane by proton irradiation could contribute to hollows formation. Measurements of widespread hollows in 565 images with pixel scales <20 m indicate that the average depth of hollows is 24 ± 16 m. We propose that hollows cease to increase in depth when a volatile-depleted lag deposit becomes sufficiently thick to protect the underlying surface. The difficulty of developing a lag on steep topography may account for the common occurrence of hollows on crater central peaks and walls. Disruption of the lag, e.g., by secondary cratering, could restart growth of hollows in a location that had been dormant. Images at extremely high resolution (~3 m/pixel) show that the edges of hollows are straight, as expected if the margins formed by scarp retreat. These highest-resolution images reveal no superposed impact craters, implying that hollows are very young. The width of hollows within rayed crater Balanchine suggests that the maximum time for lateral growth by 1 cm is ~10,000 yr. A process other than entrainment of dust by gases evolved in a steady-state sublimation-like process is likely required to explain the high-reflectance haloes that surround many hollows.

  11. Plasma backflow phenomenon in high-current vacuum arc

    Energy Technology Data Exchange (ETDEWEB)

    Wang Lijun [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Jia Shenli [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Zhang Ling [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Shi Zongqian [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Yang Dingge [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Gentils, Francois [Schneider Electric SAS, 37 quai Paul-Louis Merlin, 38050 Grenoble Cedex 9 (France); Jusselin, BenoIt [Schneider Electric SAS, 37 quai Paul-Louis Merlin, 38050 Grenoble Cedex 9 (France)

    2007-10-07

    Based on the two-temperature magnetohydrodynamic model, a high-current vacuum arc (HCVA) in vacuum interrupters is simulated and analysed. The phenomenon of plasma backflow in arc column is found, which is ultimately ascribed to the strong magnetic pinch effect of HCVA. Due to plasma backflow, the maximal value of ion density at the cathode side is not located at the centre of the cathode side, but at the paraxial region of the cathode side, that is to say, ion density appears to sag at the centre of the cathode side (arc column seems to be divided into two parts). The sag of light intensity is also found by experiments.

  12. Account of near-cathode sheath in numerical models of high-pressure arc discharges

    Science.gov (United States)

    Benilov, M. S.; Almeida, N. A.; Baeva, M.; Cunha, M. D.; Benilova, L. G.; Uhrlandt, D.

    2016-06-01

    Three approaches to describing the separation of charges in near-cathode regions of high-pressure arc discharges are compared. The first approach employs a single set of equations, including the Poisson equation, in the whole interelectrode gap. The second approach employs a fully non-equilibrium description of the quasi-neutral bulk plasma, complemented with a newly developed description of the space-charge sheaths. The third, and the simplest, approach exploits the fact that significant power is deposited by the arc power supply into the near-cathode plasma layer, which allows one to simulate the plasma-cathode interaction to the first approximation independently of processes in the bulk plasma. It is found that results given by the different models are generally in good agreement, and in some cases the agreement is even surprisingly good. It follows that the predicted integral characteristics of the plasma-cathode interaction are not strongly affected by details of the model provided that the basic physics is right.

  13. Fabricating a hollow bulb obturator

    Directory of Open Access Journals (Sweden)

    Fatih Sari

    2012-01-01

    Full Text Available

    Obturators are generally used in the rehabilitation of the maxillectomy defects. Ideally, obturators should be light, properly fit and construction should be made easily. By decreasing the weight of the prosthesis, the retention and stability may be optimized to allow the obturator for function comfortably during mastication, phonation, and deglutition. In this case, a 65-year-old male patient underwent surgical removal of left part of the maxilla due to the squamous cell carcinoma. In this technique fabrication of a hollow bulb obturator prosthesis as a single unit in heat-cured acrylic resin using a single-step flasking procedure was described. The patient’s functional and esthetic expectations were satisfied.

  14. Hollow-core tapered coupler for large inner diameter hollow-core optical fibers

    Institute of Scientific and Technical Information of China (English)

    Guiyao Zhou(周桂耀); Zhiyun Hou(侯峙云); Lantian Hou(侯蓝田); Jigang Liu(刘继刚)

    2003-01-01

    A novel hollow-core tapered coupler has been theoretically designed and fabricated by fiber drawing machine. The coupler's inner wall is coated with a polycrystalline GeO2 film. The coupling loss of hollow-core tapered coupler is about 0.2 dB. Hollow-core tapered coupler reduces the transmission loss of hollow-core optical fiber (HCOF) by 0.5 dB/m, therefore the coupler is suitable for coupling high power CO2 laser in industrial application.

  15. Hollow Alveolus-Like Nanovesicle Assembly with Metal-Encapsulated Hollow Zeolite Nanocrystals.

    Science.gov (United States)

    Dai, Chengyi; Zhang, Anfeng; Liu, Min; Gu, Lin; Guo, Xinwen; Song, Chunshan

    2016-08-23

    Inspired by the vesicular structure of alveolus which has a porous nanovesicle structure facilitating the transport of oxygen and carbon dioxide, we designed a hollow nanovesicle assembly with metal-encapsulated hollow zeolite that would enhance diffusion of reactants/products and inhibit sintering and leaching of active metals. This zeolitic nanovesicle has been successfully synthesized by a strategy which involves a one-pot hydrothermal synthesis of hollow assembly of metal-containing solid zeolite crystals without a structural template and a selective desilication-recrystallization accompanied by leaching-hydrolysis to convert the metal-containing solid crystals into metal-encapsulated hollow crystals. We demonstrate the strategy in synthesizing a hollow nanovesicle assembly of Fe2O3-encapsulated hollow crystals of ZSM-5 zeolite. This material possesses a microporous (0.4-0.6 nm) wall of hollow crystals and a mesoporous (5-17 nm) shell of nanovesicle with macropores (about 350 nm) in the core. This hierarchical structure enables excellent Fe2O3 dispersion (3-4 nm) and resistance to sintering even at 800 °C; facilitates the transport of reactant/products; and exhibits superior activity and resistance to leaching in phenol degradation. Hollow nanovesicle assembly of Fe-Pt bimetal-encapsulated hollow ZSM-5 crystals was also prepared.

  16. Acceleration and evolution of a hollow electron beam in wakefields driven by a Laguerre-Gaussian laser pulse

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Guo-Bo [Key Laboratory for Laser Plasmas (MOE) and Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240 (China); College of Science, National University of Defense Technology, Changsha 410073 (China); Chen, Min, E-mail: minchen@sjtu.edu.cn, E-mail: yanyunma@126.com; Luo, Ji; Zeng, Ming; Yu, Lu-Le; Weng, Su-Ming [Key Laboratory for Laser Plasmas (MOE) and Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240 (China); Schroeder, C. B.; Esarey, E. [Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Li, Fei-Yu [SUPA, Department of Physics, University of Strathclyde, Glasgow G4 0NG (United Kingdom); Ma, Yan-Yun, E-mail: minchen@sjtu.edu.cn, E-mail: yanyunma@126.com; Yu, Tong-Pu [College of Science, National University of Defense Technology, Changsha 410073 (China); Sheng, Zheng-Ming [Key Laboratory for Laser Plasmas (MOE) and Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240 (China); SUPA, Department of Physics, University of Strathclyde, Glasgow G4 0NG (United Kingdom)

    2016-03-15

    We show that a ring-shaped hollow electron beam can be injected and accelerated by using a Laguerre-Gaussian laser pulse and ionization-induced injection in a laser wakefield accelerator. The acceleration and evolution of such a hollow, relativistic electron beam are investigated through three-dimensional particle-in-cell simulations. We find that both the ring size and the beam thickness oscillate during the acceleration. The beam azimuthal shape is angularly dependent and evolves during the acceleration. The beam ellipticity changes resulting from the electron angular momenta obtained from the drive laser pulse and the focusing forces from the wakefield. The dependence of beam ring radius on the laser-plasma parameters (e.g., laser intensity, focal size, and plasma density) is studied. Such a hollow electron beam may have potential applications for accelerating and collimating positively charged particles.

  17. LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES

    Energy Technology Data Exchange (ETDEWEB)

    Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

    2002-03-31

    This project has three main goals: Thin Films Studies, Preparation of Graded Porous Substrates and Basic Electrical Characterization and testing of Planar Single Cells. This period has continued to address the problem of making dense 1/2 to 5 {micro}m thick dense layers on porous substrates (the cathode LSM). Our current status is that we are making structures of 2-5 cm{sup 2} in area, which consist of either dense YSZ or CGO infiltrated into a 2-5 {micro}m thick 50% porous layer made of either nanoncrystalline CGO or YSZ powder. This composite structure coats a macroporous cathode or anode; which serves as the structural element of the bi-layer structure. These structures are being tested as SOFC elements. A number of structures have been evaluated both as symmetrical and as button cell configuration. Results of this testing indicates that the cathodes contribute the most to cell losses for temperatures below 750 C. In this investigation different cathode materials were studied using impedance spectroscopy of symmetric cells and IV characteristics of anode supported fuel cells. Cathode materials studied included La{sub 0.8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (LSCF), La{sub 0.7}Sr{sub 0.2}MnO{sub 3} (LSM), Pr{sub 0.8}Sr{sub 0.2}Fe{sub 0.8}O{sub 3} (PSCF), Sm{sub 0.8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (SSCF), and Yb{sub .8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (SSCF). A new technique for filtering the Fourier transform of impedance data was used to increase the sensitivity of impedance analysis. By creating a filter specifically for impedance spectroscopy the resolution was increased. The filter was tailored to look for specific circuit elements like R//C, Warburg, or constant phase elements. As many as four peaks can be resolved using the filtering technique on symmetric cells. It may be possible to relate the different peaks to material parameters, like the oxygen exchange coefficient. The cathode grouped in order from lowest to highest ASR is

  18. Hollow rhodoliths increase Svalbard's shelf biodiversity

    Science.gov (United States)

    Teichert, Sebastian

    2014-11-01

    Rhodoliths are coralline red algal assemblages that commonly occur in marine habitats from the tropics to polar latitudes. They form rigid structures of high-magnesium calcite and have a good fossil record. Here I show that rhodoliths are ecosystem engineers in a high Arctic environment that increase local biodiversity by providing habitat. Gouged by boring mussels, originally solid rhodoliths become hollow ecospheres intensely colonised by benthic organisms. In the examined shelf areas, biodiversity in rhodolith-bearing habitats is significantly greater than in habitats without rhodoliths and hollow rhodoliths yield a greater biodiversity than solid ones. This biodiversity, however, is threatened because hollow rhodoliths take a long time to form and are susceptible to global change and anthropogenic impacts such as trawl net fisheries that can destroy hollow rhodoliths. Rhodoliths and other forms of coralline red algae play a key role in a plurality of environments and need improved management and protection plans.

  19. optimizing compressive strength characteristics of hollow building ...

    African Journals Online (AJOL)

    eobe

    This paper evaluates the compressive strength of sandcrete hollow building blocks when its sand fraction is partially replaced ... defines sandcrete blocks as composite materials made .... industry as well as the economy of Nigeria, if there is no.

  20. BOX-DEATH HOLLOW ROADLESS AREA, UTAH.

    Science.gov (United States)

    Weir, Gordon W.; Lane, Michael

    1984-01-01

    Geologic mapping, geochemical sampling, and a search for prospects and mineralized rock in the Box-Death Hollow Roadless Area, Utah indicate that there is little promise for the occurrence of mineral or energy resources in the area. Additional exploratory drilling by industry seems warranted if wells elsewhere in the region find oil or gas in strata as yet untested in the Box-Death Hollow Roadless Area.

  1. Mode characteristics of hollow core Bragg fiber

    Institute of Scientific and Technical Information of China (English)

    Minning Ji; Zhidong Shi; Qiang Guo

    2005-01-01

    Analytical expression to calculate propagation constant and mode field of the hollow core Bragg fiber is derived. Numerical results are presented. It is shown that the fundamental mode of the hollow core Bragg fiber is circularly symmetric TE01 mode with no polarization degeneracy, while the higher order mode may be HE11, TM01, or TE02 etc.. This property is different from conventional optical fiber that its fundamental mode is the linearly polarized HE11 mode and is polarization degeneracy.

  2. Preliminary Design Study of the Hollow Electron Lens for LHC

    CERN Document Server

    Perini, Diego; CERN. Geneva. ATS Department

    2017-01-01

    A Hollow Electron Lens (HEL) has been proposed in order to improve performance of halo control and collimation in the Large Hadron Collider in view of its High Luminosity upgrade (HL-LHC). The concept is based on a beam of electrons that travels around the protons for a few meters. The electron beam is produced by a cathode and then guided by a strong magnetic field generated by a set of superconducting solenoids. The first step of the design is the definition of the magnetic fields that drive the electron trajectories. The estimation of such trajectories by means of a dedicated MATLAB® tool is presented. The influence of the main geometrical and electrical parameters are analysed and discussed. Then, the main mechanical design choices for the solenoids, cryostats gun and collector are described. The aim of this paper is to provide an overview of the preliminary design of the Electron Lens for LHC. The methods used in this study also serve as examples for future mechanical and integration designs of similar ...

  3. Optoelectronic and structural properties of InGaN nanostructures grown by plasma-assisted MOCVD

    Science.gov (United States)

    Seidlitz, Daniel; Senevirathna, M. K. I.; Abate, Y.; Hoffmann, A.; Dietz, N.

    2015-09-01

    This paper presents optoelectronic and structural layer properties of InN and InGaN epilayers grown on sapphire templates by Migration-Enhanced Plasma Assisted Metal Organic Chemical Vapor Deposition (MEPA-MOCVD). Real-time characterization techniques have been applied during the growth process to gain insight of the plasma-assisted decomposition of the nitrogen precursor and associated growth surface processes. Analyzed Plasma Emission Spectroscopy (PES) and UV Absorption Spectroscopy (UVAS) provide detection and concentrations of plasma generated active species (N*/NH*/NHx*). Various precursors have been used to assess the nitrogen-active fragments that are directed from the hollow cathode plasma tube to the growth surface. The in-situ diagnostics results are supplemented with ex-situ materials structures investigation results of nanoscale structures using Scanning Near-field Optical Microscopy (SNOM). The structural properties have been analyzed by Raman spectroscopy and Fourier transform infrared (FTIR) reflectance. The Optoelectronic and optical properties were extracted by modeling the FTIR reflectance (e.g. free carrier concentration, high frequency dielectric constant, mobility) and optical absorption spectroscopy. The correlation and comparison between the in-situ metrology results with the ex-situ nano-structural and optoelectronic layer properties provides insides into the growth mechanism on how plasma-activated nitrogen-fragments can be utilized as nitrogen precursor for group III-nitride growth. The here assessed growth process parameter focus on the temporal precursor exposure of the growth surface, the reactor pressure, substrate temperature and their effects of the properties of the InN and InGaN epilayers.

  4. Arc Plasma Torch Modeling

    CERN Document Server

    Trelles, J P; Vardelle, A; Heberlein, J V R

    2013-01-01

    Arc plasma torches are the primary components of various industrial thermal plasma processes involving plasma spraying, metal cutting and welding, thermal plasma CVD, metal melting and remelting, waste treatment and gas production. They are relatively simple devices whose operation implies intricate thermal, chemical, electrical, and fluid dynamics phenomena. Modeling may be used as a means to better understand the physical processes involved in their operation. This paper presents an overview of the main aspects involved in the modeling of DC arc plasma torches: the mathematical models including thermodynamic and chemical non-equilibrium models, turbulent and radiative transport, thermodynamic and transport property calculation, boundary conditions and arc reattachment models. It focuses on the conventional plasma torches used for plasma spraying that include a hot-cathode and a nozzle anode.

  5. Raman spectroscopy system with hollow fiber probes

    Science.gov (United States)

    Liu, Bing-hong; Shi, Yi-Wei

    2012-11-01

    A Raman remote spectroscopy system was realized using flexible hollow optical fiber as laser emittion and signal collection probes. A silver-coated hollow fiber has low-loss property and flat transmission characteristics in the visible wavelength regions. Compared with conventional silica optical fiber, little background fluorescence noise was observed with optical fiber as the probe, which would be of great advantages to the detection in low frequency Raman shift region. The complex filtering and focusing system was thus unnecessary. The Raman spectra of CaCO3 and PE were obtained by using the system and a reasonable signal to noise ratio was attained without any lens. Experiments with probes made of conventional silica optical fibers were also conducted for comparisons. Furthermore, a silver-coated hollow glass waveguide was used as sample cell to detect liquid phase sample. We used a 6 cm-long hollow fiber as the liquid cell and Butt-couplings with emitting and collecting fibers. Experiment results show that the system obtained high signal to noise ratio because of the longer optical length between sample and laser light. We also give the elementary theoretical analysis for the hollow fiber sample cell. The parameters of the fiber which would affect the system were discussed. Hollow fiber has shown to be a potential fiber probe or sample cell for Raman spectroscopy.

  6. Towards higher stability of resonant absorption measurements in pulsed plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Britun, Nikolay, E-mail: nikolay.britun@umons.ac.be [Chimie des Interactions Plasma Surface (ChIPS), CIRMAP, Université de Mons, 23 Place du Parc, B-7000 Mons (Belgium); Michiels, Matthieu [Materia Nova Research Center, Parc Initialis, B-7000 Mons (Belgium); Snyders, Rony [Chimie des Interactions Plasma Surface (ChIPS), CIRMAP, Université de Mons, 23 Place du Parc, B-7000 Mons (Belgium); Materia Nova Research Center, Parc Initialis, B-7000 Mons (Belgium)

    2015-12-15

    Possible ways to increase the reliability of time-resolved particle density measurements in pulsed gaseous discharges using resonant absorption spectroscopy are proposed. A special synchronization, called “dynamic source triggering,” between a gated detector and two pulsed discharges, one representing the discharge of interest and another being used as a reference source, is developed. An internal digital delay generator in the intensified charge coupled device camera, used at the same time as a detector, is utilized for this purpose. According to the proposed scheme, the light pulses from the reference source follow the gates of detector, passing through the discharge of interest only when necessary. This allows for the utilization of short-pulse plasmas as reference sources, which is critical for time-resolved absorption analysis of strongly emitting pulsed discharges. In addition to dynamic source triggering, the reliability of absorption measurements can be further increased using simultaneous detection of spectra relevant for absorption method, which is also demonstrated in this work. The proposed methods are illustrated by the time-resolved measurements of the metal atom density in a high-power impulse magnetron sputtering (HiPIMS) discharge, using either a hollow cathode lamp or another HiPIMS discharge as a pulsed reference source.

  7. A sulfur host based on titanium monoxide@carbon hollow spheres for advanced lithium-sulfur batteries

    Science.gov (United States)

    Li, Zhen; Zhang, Jintao; Guan, Buyuan; Wang, Da; Liu, Li-Min; Lou, Xiong Wen (David)

    2016-10-01

    Lithium-sulfur batteries show advantages for next-generation electrical energy storage due to their high energy density and cost effectiveness. Enhancing the conductivity of the sulfur cathode and moderating the dissolution of lithium polysulfides are two key factors for the success of lithium-sulfur batteries. Here we report a sulfur host that overcomes both obstacles at once. With inherent metallic conductivity and strong adsorption capability for lithium-polysulfides, titanium monoxide@carbon hollow nanospheres can not only generate sufficient electrical contact to the insulating sulfur for high capacity, but also effectively confine lithium-polysulfides for prolonged cycle life. Additionally, the designed composite cathode further maximizes the lithium-polysulfide restriction capability by using the polar shells to prevent their outward diffusion, which avoids the need for chemically bonding all lithium-polysulfides on the surfaces of polar particles.

  8. Ion energy distributions in bipolar pulsed-dc discharges of methane measured at the biased cathode

    Energy Technology Data Exchange (ETDEWEB)

    Corbella, C; Rubio-Roy, M; Bertran, E; Portal, S; Pascual, E; Polo, M C; Andujar, J L, E-mail: corbella@ub.edu [FEMAN Group, IN2UB, Departament de Fisica Aplicada i Optica, Universitat de Barcelona, c/ MartI i Franques 1, 08028 Barcelona (Spain)

    2011-02-15

    The ion fluxes and ion energy distributions (IED) corresponding to discharges in methane (CH{sub 4}) were measured in time-averaged mode with a compact retarding field energy analyser (RFEA). The RFEA was placed on a biased electrode at room temperature, which was powered by either radiofrequency (13.56 MHz) or asymmetric bipolar pulsed-dc (250 kHz) signals. The shape of the resulting IED showed the relevant populations of ions bombarding the cathode at discharge parameters typical in the material processing technology: working pressures ranging from 1 to 10 Pa and cathode bias voltages between 100 and 200 V. High-energy peaks in the IED were detected at low pressures, whereas low-energy populations became progressively dominant at higher pressures. This effect is attributed to the transition from collisionless to collisional regimes of the cathode sheath as the pressure increases. On the other hand, pulsed-dc plasmas showed broader IED than RF discharges. This fact is connected to the different working frequencies and the intense peak voltages (up to 450 V) driven by the pulsed power supply. This work improves our understanding in plasma processes at the cathode level, which are of crucial importance for the growth and processing of materials requiring controlled ion bombardment. Examples of industrial applications with these requirements are plasma cleaning, ion etching processes during fabrication of microelectronic devices and plasma-enhanced chemical vapour deposition of hard coatings (diamond-like carbon, carbides and nitrides).

  9. Analysis of XeC1 Emission in a Hollow Cathode Discharge.

    Science.gov (United States)

    1981-06-01

    excited homopolar molecule, e.g., Xe2 , Hg2 The term exciplex refers to an electronically excited heteropolar complex, e.g., KrF , XeOH , XeCl , which...frequently overlooked and both homopolar and heteropolar systems are commonly referred to as excimers, Excimers are formed by the interaction between two...mode and a non-scanning mode. Scanning is performed using a 1 rpm motor and produces plots of in- tensity versus wavelength. The non-scanning mode is

  10. Computer Simulation of Intense Electron Beam Generation in a Hollow Cathode Diode.

    Science.gov (United States)

    1980-09-05

    Phys. Rev. Lett. 40, 1504 (1978).I ’ 9. Robert K. Parker, Technical Report AFWL-TR-73-92, USAF Weapons Lab., Albuquerque, New Mexico (1973). , 12 .% xv...t C. Bruno (1 copy) J. Barbaro (. copy) Ecole Polytechnique ft Labo, PMI 91128 Palaiseau Cedex France Attn: 11. Doucet (1 copy) J. M. Buzzi (1 copy

  11. Reflective article having a sacrificial cathodic layer

    Energy Technology Data Exchange (ETDEWEB)

    Kabagambe, Benjamin; Buchanan, Michael J.; Scott, Matthew S.; Rearick, Brian K.; Medwick, Paul A.; McCamy, James W.

    2017-09-12

    The present invention relates to reflective articles, such as solar mirrors, that include a sacrificial cathodic layer. The reflective article, more particularly includes a substrate, such as glass, having a multi-layered coating thereon that includes a lead-free sacrificial cathodic layer. The sacrificial cathodic layer includes at least one transition metal, such as a particulate transition metal, which can be in the form of flakes (e.g., zinc flakes). The sacrificial cathodic layer can include an inorganic matrix formed from one or more organo-titanates. Alternatively, the sacrificial cathodic layer can include an organic polymer matrix (e.g., a crosslinked organic polymer matrix formed from an organic polymer and an aminoplast crosslinking agent). The reflective article also includes an outer organic polymer coating, that can be electrodeposited over the sacrificial cathodic layer.

  12. Thermal analysis of the influence of the support in the superficial treatment by plasma of cylindrical samples

    Energy Technology Data Exchange (ETDEWEB)

    Belisio, A.S.; Lima, J.A.; Alves Junior, C. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Programa de Pos-Graduacao em Engenharia Mecanica]. E-mails: abelisio@yahoo.com.br; jalima@dem.ufrn.br; alvesjr@dem.ufrn.br

    2008-07-01

    Different of the conventional processes of heating, that is, transport, convection, and radiation, heat transfer in heating process by plasma also occur also by collisions of particles, in other words, through the transfer heat motion ions for the surface of the sample, the kinetic energy, and potential those particles, as well as the enthalpy of the chemical reactions involved in the surface. In thermal plasmas, that transfer can to be simplified initially through general energy balance between plasma and samples. However, existent models of temperature distribution are in its majority unidimensional and it do not analyze, mainly, support influence on sample in the heating process by r plasma. In that way, with the mark of analyzing the temperature distribution in the samples submitted to polarization voltage of 706 V, 744 V and 790 V, as well as process heating support influence analysis those samples, the present work developed a code computational for a transient (2D-t) two-dimensional model, destined to the simulation of the heat transfer during heating phases and cooling in superficial process of treatment by plasma in cylindrical samples of copper, being considered the configuration of hollow cathode and the presence of a support. The model computational serves as a tool in the predict of the final properties of treated samples, well as in the specification of the parameters of the heating processes by plasma. In the developed model was considered that the physical samples properties were variable, functions of the temperature field. The results obtained through simulation are leaning and validated in experimental and theoretical data available in the literature, as well as, in information of tests accomplished in Lab Plasma/ UFRN. (author)

  13. Carbon nanotube—Based cold cathodes: Field emission angular properties and temporal stability

    Science.gov (United States)

    Iacobucci, S.; Fratini, M.; Rizzo, A.; Zhang, Y.; Cole, M. T.; Milne, W. I.; Lagomarsino, S.; Liscio, A.; Stefani, G.

    2016-10-01

    The field emission (FE) properties of carbon nanotube (CNT)-based cathodes have been investigated on nanostructured surfaces grown by plasma enhanced chemical vapor deposition. The FE angular properties and temporal stability of the emergent electron beam have been determined using a dedicated apparatus for cathodes of various architectures and geometries, characterized by scanning electron microscopy and I-V measurements. The angular electron beam divergence and time instability at the extraction stage, which are crucial parameters in order to obtain high brilliance of FE-based-cathode electron sources, have been measured for electrons emitted by several regular architectures of vertically aligned arrays and critically compared to conventional disordered cathodes. The measured divergences strongly depend on the grid mesh. For regular arrays of individual CNT, divergences from 2° to 5° have been obtained; in this specific case, measurements together with ray-tracing simulations suggest that the maximum emission angle is of the order of ±30° about the tube main axis. Larger divergences have been measured for electron beams emitted from honeycomb-structured cathodes (6°) and significantly broader angle distributions (10°) from disordered CNT surfaces. Emission current instabilities of the order of 1% for temporal stability studies conducted across a medium time scale (hours) have been noted for all cathodes consisting of a high number (104 and larger) of aligned CNTs, with the degree of stability being largely independent of the architecture.

  14. Sun powers Libya cathodic-protection system

    Energy Technology Data Exchange (ETDEWEB)

    Currer, G.W.

    1982-03-22

    Well castings and part of the main 300-mile-long, 32-in diameter pipeline from Sarir to Tobruk are cathodically protected by solar power, which prevents galvanic action by applying an electric direct current of appropriate magnitude and polarity to the steel structures. They then act as cathodes and become the recipients of metallic ions. At each cathodic-protection station, the solar-generaor system consists of solar-panel arrays, electronic controls, and batteries.

  15. Preventing Corrosion by Controlling Cathodic Reaction Kinetics

    Science.gov (United States)

    2016-03-25

    Preventing corrosion by controlling cathodic reaction kinetics Progress Report for Period: 1 SEP 2015-31 MAR 2016 John Keith Department of...25 March 2016 Preventing corrosion by controlling cathodic reaction kinetics Annual Summary Report: FY16 PI: John Keith, 412-624-7016,jakeith...dominate the metal’s cathodic behavior. Within an alkaline environment, we expect the following reduction reactions to be catalyzed on the oxide

  16. Cathodic cage nitriding of AISI 409 ferritic stainless steel with the addition of CH4

    Directory of Open Access Journals (Sweden)

    Rômulo Ribeiro Magalhães de Sousa

    2012-04-01

    Full Text Available AISI 409 ferritic stainless steel samples were nitrided using the cathodic cage plasma nitriding technique (CCPN, with the addition of methane to reduce chromium precipitation, increase hardness and wear resistance and reduce the presence of nitrides when compared to plasma carbonitriding. Microhardness profiles and X-Ray analysis confirm the formation of a very hard layer containing mainly ε-Fe3N and expanded ferrite phases.

  17. Hollow glass for insulating layers

    Science.gov (United States)

    Merticaru, Andreea R.; Moagar-Poladian, Gabriel

    1999-03-01

    Common porous materials, some of which will be considered in the chapters of this book, include concrete, paper, ceramics, clays, porous semiconductors, chromotography materials, and natural materials like coral, bone, sponges, rocks and shells. Porous materials can also be reactive, such as in charcoal gasification, acid rock dissolution, catalyst deactivation and concrete. This study continues the investigations about the properties of, so-called, hollow glass. In this paper is presented a computer simulation approach in which the thermo-mechanical behavior of a 3D microstructure is directly computed. In this paper a computer modeling approach of porous glass is presented. One way to test the accuracy of the reconstructed microstructures is to computed their physical properties and compare to experimental measurement on equivalent systems. In this view, we imagine a new type of porous type of glass designed as buffer layer in multilayered printed boards in ICs. Our glass is a variable material with a variable pore size and surface area. The porosity could be tailored early from the deposition phases that permitting us to keep in a reasonable balance the dielectric constant and thermal conductivity.

  18. Ultrasonic-assisted cathodic electrochemical discharge for graphene synthesis.

    Science.gov (United States)

    Van Thanh, Dang; Oanh, Phung Phi; Huong, Do Tra; Le, Phuoc Huu

    2017-01-01

    We present a novel and highly efficient method for exfoliating of graphite to produce graphene via the synergistic effects of in-situ plasma induced electrochemical exfoliation with ultrasonic energy, called ultrasonic-assisted cathodic electrochemical discharge. This method can work at moderate temperatures without the need of acidic media or expensive ionic electrolyte. The produced graphene exhibited a large lateral dimension of approximately 6μm and a thickness of 2.5nm, corresponding to approximately seven layers of graphene. An exfoliating mechanism of graphite to produce graphene sheets is also proposed in this study.

  19. Stirring Unmagnetized Plasma

    CERN Document Server

    Collins, C; Wallace, J; Jara-Almonte, J; Reese, I; Zweibel, E; Forest, C B; 10.1103/PhysRevLett.108.115001

    2012-01-01

    A new concept for spinning unmagnetized plasma is demonstrated experimentally. Plasma is confined by an axisymmetric multi-cusp magnetic field and biased cathodes are used to drive currents and impart a torque in the magnetized edge. Measurements show that flow viscously couples momentum from the magnetized edge (where the plasma viscosity is small) into the unmagnetized core (where the viscosity is large) and that the core rotates as a solid body. To be effective, collisional viscosity must overcome the ion-neutral drag due to charge exchange collisions.

  20. Modelling effects of current distributions on performance of micro-tubular hollow fibre solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Doraswami, U.; Droushiotis, N. [Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom); Kelsall, G.H., E-mail: g.kelsall@imperial.ac.u [Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom)

    2010-04-15

    A three-dimensional model, considering mass, momentum, energy and charge conservation, was developed and the equations solved to describe the physico-chemical phenomena occurring within a single, micro-tubular hollow fibre solid oxide fuel cell (HF-SOFC). The model was used to investigate the spatial distributions of potential, current and reactants in a 10 mm long HF-SOFC. The predicted effects of location of current collectors, electrode conductivities, cathode thickness and porosity were analysed to minimise the ranges of current density distributions and maximise performance by judicious design. To decrease the computational load, azimuthal symmetry was assumed to model 50 and 100 mm long reactors in 2-D. With connectors at the same end of the HF-SOFC operating at a cell voltage of 0.5 V and a mean 5 kA m{sup -2}, axial potential drops of ca. 0.14 V in the cathode were predicted, comparable to the cathode activation overpotential. Those potential drops caused average current densities to decrease from ca. 6.5 to ca.1 kA m{sup -2} as HF-SOFC length increased from 10 to 100 mm, at which much of the length was inactive. Peak power densities were predicted to vary from 3.8 to <2.5 kW m{sup -2}, depending on the location of the current collectors; performance increased with increasing cathode thickness and decreasing porosity.