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Sample records for holen limestones south-central

  1. Bivalves and gastropods from the middle Campanian Anacacho limestone, South Central Texas

    Science.gov (United States)

    Elder, W.P.

    1996-01-01

    The Anacacho Limestone was deposited during the Campanian and represents two depositional intervals, one of early Campanian and one of middle Campanian age. These two intervals correspond to periods of major eustatic sea level rise. This study focuses on the molluscan paleontology of the middle Campanian interval in the eastern part of the Anacacho exposure belt in Medina County, Texas. Molluscan assemblages in this area are indicative of inner to mid-shelf environments. No significant reef components are present. These eastern Anacacho deposits are interpreted to represent more offshore, deeper water environments than those to the southwest, where reef and lagoonal deposits have been reported. Analysis of the macrofossil components from these eastern localities has expanded the number of invertebrate species known from the Anacacho Limestone by nearly three-fold. This increase in diversity, based on a small amount of new work, suggests that many more taxa are yet to be identified, particularly in the western part of the exposure belt in Uvalde and Kinney Counties. This paper documents the bivalve and gastropod fauna, discussing and illustrating 24 bivalve taxa and 11 gastropod species. Two new bivalve species are named, Panopea anacachoensis new species and Spondylus siccus new species, and two potentially new gastropod species are identified but not named herein due to inadequate material. This paper expands the distribution of many eastern Gulf Coast and Atlantic Coast taxa westward into Texas and shows strong ties between the Anacacho fauna and that of the Campanian Tar Heel and Bladen Formations of the Black Creek Group in North Carolina. The taxonomic ties between these two areas probably reflect the thorough documentation of the North Carolina fauna, which is the best documented Campanian bivalve fauna in the Gulf or Atlantic Coast regions.

  2. South-central Alaska forests: inventory highlights.

    Science.gov (United States)

    Sally Campbell; Willem W.S. van Hees; Bert. Mead

    2005-01-01

    This publication presents highlights of a recent south-central Alaska inventory conducted by the Pacific Northwest Research Station Forest Inventory and Analysis Program (USDA Forest Service). South-central Alaska has about 18.5 million acres, of which one-fifth (4 million acres) is forested. Species diversity is greatest in closed and open Sitka spruce forests, spruce...

  3. Limestone Caverns

    Science.gov (United States)

    Powell, Richard L.

    1970-01-01

    Describes the origin of limestone caverns, using Mammoth Cave as an example, with particular reference to the importance of groundwater information of caverns, the present condition of groundwater, and how caverns develop within fluctuating groundwater zones. (BR)

  4. Limestone Paradise

    Institute of Scientific and Technical Information of China (English)

    BRUCE CONNOLLY

    2004-01-01

    <正> In Guangxi there is an area I have frequently referred to as ’Heaven on Earth’. It is the limestone district stretching along the valley of the Li River from the popular tourist city of Guilin to the scenic wonderland of tiny, laid-back, Yangshuo.Produced 300 million years ago when an ancient sea covered this area, the limestone is formed from the compressed fossilised remains of sea creatures. The movements of the continents caused the earth to rise up and the sea disappeared.

  5. Limestone compaction: an enigma

    Science.gov (United States)

    Shinn, Eugene A.; Halley, Robert B.; Hudson, J. Harold; Lidz, Barbara H.

    1977-01-01

    Compression of an undisturbed carbonate sediment core under a pressure of 556 kg/cm2 produced a “rock” with sedimentary structures similar to typical ancient fine-grained limestones. Surprisingly, shells, foraminifera, and other fossils were not noticeably crushed, which indicates that absence of crushed fossils in ancient limestones can no longer be considered evidence that limestones do not compact.

  6. Frequency dependent Lg attenuation in south-central Alaska

    Science.gov (United States)

    McNamara, D.E.

    2000-01-01

    The characteristics of seismic energy attenuation are determined using high frequency Lg waves from 27 crustal earthquakes, in south-central Alaska. Lg time-domain amplitudes are measured in five pass-bands and inverted to determine a frequency-dependent quality factor, Q(f), model for south-central Alaska. The inversion in this study yields the frequency-dependent quality factor, in the form of a power law: Q(f) = Q0fη = 220(±30) f0.66(±0.09) (0.75≤f≤12Hz). The results from this study are remarkably consistent with frequency dependent quality factor estimates, using local S-wave coda, in south-central Alaska. The consistency between S-coda Q(f) and Lg Q(f) enables constraints to be placed on the mechanism of crustal attenuation in south-central Alaska. For the range of frequencies considered in this study both scattering and intrinsic attenuation mechanisms likely play an equal role.

  7. GIS coverages of the Castle Mountain Fault, south central Alaska

    Science.gov (United States)

    Labay, Keith A.; Haeussler, Peter J.

    2001-01-01

    The Castle Mountain fault is one of several major east-northeast-striking faults in southern Alaska, and it is the only fault with had historic seismicity and Holocene surface faulting. This report is a digital compilation of three maps along the Castle Mountain fault in south central Alaska. This compilation consists only of GIS coverages of the location of the fault, line attributes indicating the certainty of the fault location, and information about scarp height, where measured. The files are presented in ARC/INFO export file format and include metadata.

  8. Benchmarking Terrestrial Ecosystem Models in the South Central US

    Science.gov (United States)

    Kc, M.; Winton, K.; Langston, M. A.; Luo, Y.

    2016-12-01

    Ecosystem services and products are the foundation of sustainability for regional and global economy since we are directly or indirectly dependent on the ecosystem services like food, livestock, water, air, wildlife etc. It has been increasingly recognized that for sustainability concerns, the conservation problems need to be addressed in the context of entire ecosystems. This approach is even more vital in the 21st century with formidable increasing human population and rapid changes in global environment. This study was conducted to find the state of the science of ecosystem models in the South-Central region of US. The ecosystem models were benchmarked using ILAMB diagnostic package developed as a result of International Land Model Benchmarking (ILAMB) project on four main categories; viz, Ecosystem and Carbon Cycle, Hydrology Cycle, Radiation and Energy Cycle and Climate forcings. A cumulative assessment was generated with weighted seven different skill assessment metrics for the ecosystem models. This synthesis on the current state of the science of ecosystem modeling in the South-Central region of US will be highly useful towards coupling these models with climate, agronomic, hydrologic, economic or management models to better represent ecosystem dynamics as affected by climate change and human activities; and hence gain more reliable predictions of future ecosystem functions and service in the region. Better understandings of such processes will increase our ability to predict the ecosystem responses and feedbacks to environmental and human induced change in the region so that decision makers can make an informed management decisions of the ecosystem.

  9. Wind energy resource atlas. Volume 7. The south central region

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, R.L.; Graves, L.F.; Sprankle, A.C.; Elliott, D.L.; Barchet, W.R.; George, R.L.

    1981-03-01

    This atlas of the south central region combines seven collections of wind resource data: one for the region, and one for each of the six states (Arkansas, Kansas, Louisiana, Missouri, Oklahoma, and Texas). At the state level, features of the climate, topography, and wind resource are discussed in greater detail than that provided in the regional discussion, and the data locations on which the assessment is based are mapped. Variations, over several time scales, in the wind resource at selected stations in each state are shown on graphs of monthly average and interannual wind speed and power, and hourly average wind speed for each season. Other graphs present speed, direction, and duration frequencies of the wind at these locations.

  10. Natural phenomena hazards, Hanford Site, south central Washington

    Energy Technology Data Exchange (ETDEWEB)

    Tallman, A.M.

    1996-04-16

    This document presents the natural phenomena hazard (NPH) loads for use in implementing DOE Order 5480.28, Natural Phenomena Hazards Mitigation, at the Hanford Site in south-central Washington State. The purpose of this document is twofold: (1) summarize the NPH that are important to the design and evaluation of structures, systems, and components at the Hanford Site; (2) develop the appropriate natural phenomena loads for use in the implementation of DOE Order 5480.28. The supporting standards, DOE-STD-1020-94, Natural Phenomena Hazards Design and Evaluation Criteria for Department of Energy Facilities (DOE 1994a); DOE-STD-1022-94, Natural Phenomena Hazards Site Characteristics Criteria (DOE 1994b); and DOE-STD-1023-95, Natural Phenomena Hazards Assessment Criteria (DOE 1995) are the basis for developing the NPH loads.

  11. Direct Sulfation of Limestone

    DEFF Research Database (Denmark)

    Hu, Guilin; Dam-Johansen, Kim; Wedel, Stig

    2007-01-01

    The direct sulfation of limestone was studied in a laboratory fixed-bed reactor. It is found that the direct sulfation of limestone involves nucleation and crystal grain growth of the solid product (anhydrite). At 823 K and at low-conversions (less than about 0.5 %), the influences of SO2, O-2...... and CO2 on the direct sulfation of limestone corresponds to apparent reaction orders of about 0.2, 0.2 and -0.5, respectively. Water is observed to promote the sulfation reaction and increase the apparent reaction orders of SO2 and O-2. The influence of O-2 at high O-2 concentrations (> about 15...... %) becomes negligible. In the temperature interval from 723 K to 973 K, an apparent activation energy of about 104 kJ/mol is observed for the direct sulfation of limestone. At low temperatures and low conversions, the sulfation process is most likely under mixed control by chemical reaction and solid...

  12. Monitoring the Increase in Seismicity in South-Central Kansas

    Science.gov (United States)

    Nolte, K.; Tsoflias, G. P.; Watney, W. L.

    2016-12-01

    There has been a dramatic increase in seismicity in the Midcontinent over the last five years, which appears to be linked to the injection of large volumes of wastewater from oilfield operations. Injection of fluids into deeper formations causes an increase in pore pressure, which can facilitate slip on existing faults oriented optimally to subsurface stress fields. Very little is known about the stresses within the shallow basement in Southern Kansas which has seen an increase in seismicity. The historical average of 21 M>3 earthquakes a year has increased to 188 M>3 reported earthquakes observed in 2011, in the US midcontinent. Earthquake focal mechanisms were analyzed for western Sumner County, south-central Kansas, from May of 2015 to July of 2016. The Kansas Geological Society (KGS) seismometer array in the Wellington Oil Field and the United States Geological Survey (USGS) portable array in southern Kansas were used to locate the earthquakes. These arrays generated a catalog of events from Mw .4 to Mw 3.5. Analyses of focal mechanisms for nearly 200 earthquakes larger than approximately Mw 2.0 were included in the inversion. Earthquakes of this magnitude were recorded on nearly all stations. The larger magnitude events tend to cluster in Northeast-Southwest and Northwest-Southeast lineations. These local, larger earthquakes provide a better understanding of the stresses that are causing the increased seismicity. The stress tensor was calculated for the region to the west of the city of Wellington, KS, in Sumner County. The primary horizontal stress direction is nearly east. This observation is in agreement with well data that estimates the maximum horizontal stress at approximately 75 degrees.

  13. Relocations of Earthquakes (1899 1917) in South-Central Alaska

    Science.gov (United States)

    Doser, Diane I.

    2006-08-01

    I have relocated 18 earthquakes occurring in the south-central Alaska region between 1899 and 1917 using a bootstrap relocation technique. Locations of events within the Yakutat region suggest that the 1899 sequence began on 4 September with a MS = 7.9 event within the area of the Pamplona fault zone/western Transition fault zone, rupturing the western portion of the North American/Pacific plate interface. A MS = 7.4 event on 10 September appears to have ruptured the offshore portion of the plate interface to the east of the 4 September event. This was followed by a MS = 8.0 event that likely ruptured the onshore and down-dip portion of the plate interface. A MS = 7.0 event in 1908 may have ruptured a small portion of the plate interface between the 4 September and 10 September events. Events occurring between 1911 and 1916 in the Prince William Sound region appear to be slab events occurring in similar locations to more recent seismicity. Within the Kodiak region the 1900 earthquake of MS = 7.7 has a location consistent with the rupture of the Kodiak asperity which also ruptured during the 1964 great Alaska earthquake. Other large magnitude Kodiak events appear to be associated with regions of recent seismicity, including the Karluk Lake area of southwestern Kodiak Island and the Albatross Basin located offshore southeast of Kodiak Island. Space-time seismicity patterns since 1899 indicate that magnitude 6 to7 events have occurred with regularity in the Kodiak Island region; that there has been a lack of magnitude ≥ 6 events in the Prince William Sound region since 1964, and that the Yakutat region has remained notably quiescent at the magnitude ≥ 6 level.

  14. Late Quaternary vegetation history of Rough Canyon, south-central New Mexico, USA

    Science.gov (United States)

    Betancourt, J.L.; Rylander, Kate Aasen; Penalba, C.; McVickar, J.L.

    2001-01-01

    South-central New Mexico, USA, at the junction of the Rocky Mountains, High Plains and Chihuahuan Desert, is one of the better known regions in the late Quaternary of North America. Plant macrofossils and pollen from a packrat midden series in Rough Canyon, New Mexico allows refinement of plant distributions and paleoclimates in this transitional area since full glacial times. From 17 000 to 12 000 14C yr BP, Pinus edulis–Juniperus scopulorum woodlands dominated limestone substrates between 1800 and 1490 m, with Pseudotsugamenziesii and other mixed-conifer species restricted to shady, north-facing slopes. Juniperus deppeana, the dominant juniper today above 2000 m in southern New Mexico, is conspicuously absent from glacial middens and must have been displaced south of the US–Mexico border. The minimum climatic conditions for P. edulis–J. scopulorum woodlands are ca 20% wetter and 3.5–5°C cooler (July mean maximum temperatures) than the modern climate at Rough Canyon. Holocene warming/drying may have started as early as 12 000 14C yr BP with the extirpation of J. scopulorum from Rough Canyon, and was completed by at least 10 54014C yr BP. The record for arrivals of some desert species is confounded by traces of pollen and macrofossils in some of the glacial middens, which could signify either earliest occurrence or temporal mixing (contamination) of assemblages. AMS 14C dating can discriminate between early arrival and contamination in midden macrofossils but not in pollen. AMS dates show that Choisya dumosa, presently near its northern (cold) limits at Rough Canyon, endured late glacial winters, possibly as clonal populations. Some Larrea tridentata leaves and pollen occur in middens dominated by conifers and oaks no longer at the site; an AMS date of 3205 14C yr BP on Larrea leaves from one midden indicates contamination. Evidence for some macrofossil contamination, however, does not rule out the possibility that pollen of desert

  15. The South Central Overland Trail in western Utah, 1850-1900

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The following report is a discussion of the South Central Overland Trail, which goes west from Salt Lake City and skirts the worst of the salt desert, stopping at...

  16. Winter habitat associations of blackbirds and starlings wintering in the south-central United States

    National Research Council Canada - National Science Library

    Matthew Strassburg; Shawn M Crimmins; George M Linz; Patrick C McKann; Wayne E Thogmartin

    2015-01-01

    .... We used the National Audubon Society Christmas Bird Count data from the south-central United States and mixed-effects models to identify habitat factors associated with population trend and abundance for 5 species...

  17. Transience and Glacial Erosion in South Central Alaska

    Science.gov (United States)

    Valentino, J.; Spotila, J. A.; Owen, L. A.; Buscher, J.

    2013-12-01

    It is documented that a glacial presence in active orogenic belts undergoing rapid rock uplift will increase erosion rates often matching rates of rock uplift. Glacial erosion seems to have shaped the mass balance of numerous mountain ranges and tectonic settings, but the Kenai Peninsula and Chugach Mountains of south central Alaska do not conform to this pattern. The Kenai Peninsula is an uplifted forearc forming above the Aleutian subduction zone and the Chugach Mountains are the continuation of the orogenic belt around Prince William Sound. This mountain belt is comprised of accreted Mesozoic island arcs, which were sequentially metamorphosed from the cretaceous through the Tertiary. Geomorphic analysis and past studies, including Buscher et al. (2008) and Arkle et al. (2013), show that the Chugach Mountains and Kenai Peninsula are similar to the Saint Elias Mountains in the Yakutat collision zone with regards to topographic ruggedness. The region is dominated by alpine glaciers, ice fields, and extensive valley glaciers that are actively eroding the topography through headwall erosion and valley glacier down cutting. Despite this, there is a low background long term erosion rate of <0.1-0.2 mm/yr (Buscher et al, 2008). This suggests a transient landscape that has not yet fully adjusted to onset of erosive glacial conditions. Through the use of four dating techniques spanning different timescales, we aim to quantify erosion rates in the Kenai and Chugach Mountains. (U-TH)/He thermochronometry (106-7 yr), He/He thermochronometry (105-6 yr), OSL thermochronometry (105-6 yr), and 10Be and 36CL cosmogenic dating (103-4 yr), are being used in conjunction to test if short-term rates exceed long-term rates, thereby indicating a transient response to late Cenozoic glaciations. This analysis will also address how landscapes respond to the onset of glacial conditions and subsequent climate fluctuations. The history of exhumation and erosion will also characterize the role

  18. Particulate Matter Concentration Levels in South Central Richmond, California (Invited)

    Science.gov (United States)

    Bonner, B.; Byias, C.; Cuff, K. E.; Diaz, J.; Love, K.; Marks-Block, T.; McLane, F.; Mollique, Z.; Montes, E.; Ross, R.; Washington, B.

    2009-12-01

    South Central Richmond, California is the home of one of the nation’s most innovative green workforce training centers, Richmond BUILD - Green Jobs Training facility. A near constant stream of young people engaged in training activities, instructors, invited guests, and journalists of various ages can be seen moving in and out of the facility nearly every day of the week throughout a given year. Additionally, the comings and goings of young children and adults associated with a mid-sized elementary school just north of the facility contributes to the general area’s substantial human traffic. Unfortunately, however, a major highway, Interstate 580, a major thoroughfare, 23rd Street and a railway line operated by Burlington Northern Santa Fe, Union Pacific, and the Richmond Pacific Railroad frame the triangular area within which these two sites are situated. In addition, a major petrochemical complex and several shipping facilities are located less than three kilometers away north and west of this area. As part of a general assessment of air quality in this heavily human traveled area, we conducted a study of particulate matter (PM) concentrations over a five-month period beginning in August of 2009. Measurements were made at a variety of locations, and results were used to map the spatial distribution of PM of various sizes. Regions of high concentration levels were identified, and these particular areas then were monitored over time. Preliminary results of our study indicate that regions with high concentrations are consistent across the range of particle sizes measured, which suggests a common source for PM found in the study area. As these regions are located close to a major thoroughfare and railway line, we believe that diesel-burning vehicles are major contributors to the PM levels found in the study area. Time series results suggest a fairly strong correlation between higher than average PM concentrations and abnormally high wind gusts. On days when wind

  19. Implementation of a Regional Healthcare Information Organization in South Central Texas

    Science.gov (United States)

    2007-12-06

    initiative of GSAHC. The purpose of this paper is to provide a strategic plan to implement a R HIO for this region. The plan will utilize the thinking...the South Central Texas RHIO. The growing influence of F HiOs within the global Regional Healthcare Information Organization 26 healthcare industry...These approaches cannot be counted on for the establishment of the South Central Texas R HIO or for its subsequent sustainability. While seed money

  20. Quaternary tectonic setting of South-Central coastal California

    Science.gov (United States)

    Lettis, William R.; Hanson, Kathryn L.; Unruh, Jeffrey R.; McLaren, Marcia; Savage, William U.; Keller, Margaret A.

    2004-01-01

    Recent geodetic, geologic, and seismologic studies show that the south-central coast of California is a region of active Quaternary deformation. Northeast-directed crustal shortening is occurring in a triangular-shaped region between the Hosgri-San Simeon fault system on the west, the Southern Coast Ranges on the northeast, and the western Transverse Ranges on the south. We informally call this region the Los Osos domain. In this study, we conducted detailed geological, seismological, and geophysical investigations to characterize the nature and rates of deformation in the domain. Locations of active and potentially active faults and folds are compiled at a scale of 1:250,000 for the entire domain based primarily on onshore geologic data and offshore geophysical data. Crustal shortening in the domain is accommodated by a series of prominent northwest-trending reverse faults and localized folding. The reverse faults separate distinct structural blocks that have little or no internal deformation. Hangingwall blocks are being uplifted at rates of up to 0.2 mm/yr. Footwall blocks are either static or slowly subsiding at rates of 0.1 mm/yr or less, except for localized areas of concentrated subsidence directly adjacent to some faults. The cumulative rate of crustal shortening is about 1 to 2 mm/yr across the northern part of the domain based on observed geologic deformation. Cumulative shortening across the central and southern parts of the domain is poorly constrained by geologic data and may approach 2 to 3 mm/yr. Historical and instrumental seismicity generally are spatially associated with the uplifted blocks and bordering reverse faults to depths of about 10 km. Together with near-surface geological data and deeper crustal geophysical imaging that show high-angle faulting, the seismicity data indicate that the reverse faults probably extend to the base of the seismogenic crust. The base of the seismogenic crust may correspond with a mid-crustal detachment or

  1. Neurocysticercosos in South-Central America and the Indian Subcontinent: a comparative evaluation

    Directory of Open Access Journals (Sweden)

    Gagandeep Singh

    1997-09-01

    Full Text Available Neurocysticercosis is an important public health problem in South-Central America and South Asia. A review of the differences in epidemiological and clinical attributes of cysticercosis and taeniasis in South Central America and India, respectively, is undertaken in the present communication. Intestinal taeniasis is hyperendemic in several American countries. In comparison, the prevalence of Taenia solium infestation is lower in India. The clinical manifestations in several American neurocysticercosis series comprise epilepsy, intracranial hypertension and meningeal - racemose cysticercosis, in roughly equal proportions. An overwhelming majority of the Indian subjects present with seizures. The commonest pathological substrate of the disorder in Indian patients is the solitary parenchymal degenerating cyst. The reasons for the predominance of solitary forms in India, and of multilesional forms in South Central America are discussed. The magnitude of Taenia solium infestation and the frequency of pork consumption in a given population appear to influence the quantum of cyst load in affected individuals.

  2. Geology of the State of Morelos and contiguous areas in south-central Mexico

    Science.gov (United States)

    Fries, Carl F.

    1959-01-01

    The area described lies in south-central Mexico and embraces all but the southeastern corner and easternmost border of the State of Moreles, the second smallest State in the Mexican Republic. It includes small contiguous parts of the State of Mexico, in the northeastern corner, and of the State of Guerrero in the southwestern corner. Limiting geographic coordinates are 98 45 to 99 39 west longitude and 18 18 to 19 08 north latitude, the northern boundary being only 35 km south of Mexico City, capital of the Republic. The geological map does not cover the entire rectangle outlined, but is irregular in form and measures roughly 4150 sq. km, three-quarters of it representing two0thirds of the State of Moreles and the rest lying outside the State. The region ranges in altitude from 730 m above sea level at Iguala near the south edge of the map, to a general level of about 3000 m at the north edge, although individual peaks rise to 3900 m and Popocatepetl Volcano, a few kilometers east of the northeastern border of the map, rises to 5452 m above sea level. Annual rainfall ranges from a minimum of about 640 mm in the low country, to 1200 mm and more at altitudes above 2000 m. Most of it falls in summer between June and September. Winter frosts are rare below 1800 m. The climate is of savanna to steppe type; soils are thin and may be classified as belonging to the tachernoses group, with strong development of calcareous evaporates (caliche) at altitudes below 1800 m. The northern border of the area forms the southern half of the late Pliocene to Recent Neo-volcanic Belt of basic volcanism that crosses Mexico in the direction N. 80 W., and thus has constructional topography. The rest of the area belongs to the Balsas Basin physiographic province, which is characterized by maturely dissected terrain tributary to the large Balsas River. All but the southwestern corner of the area drains southward via the Amacuzac River into the Mexcala-Balsas River, and thence westward into

  3. Development of a Geologic Exploration Model foe the Permo-Pennsylvanian Petroleum System in South-Central Montana

    Energy Technology Data Exchange (ETDEWEB)

    David A. Lopez

    2007-06-30

    presented: migration occurred (1) before mid-Jurassic erosion produced a major regional unconformity or (2) about 82 million years ago. Migration pre-Laramide occurred because oil in both the Bighorn Basin and the Powder River Basin are part of the same petroleum system. Geochemical analyses of oils from producing fields across the region show the oils are all similar and have the same source and generation history. No Phosphoria source rocks exist in the project area of south-central Montana, requiring that oil migrated from distant source areas, probably in central and southwestern Wyoming. Oil shows and production in the Tensleep are absent in the northern part of the project area. This appears to be controlled by the merging of the top of the Tensleep Sandstone and the Jurassic unconformity (top of the Triassic Chugwater Formation). There should be potential for the discovery of oil in Tensleep stratigraphic traps or combination traps everywhere south of the Jurassic-Pennsylvanian Isopach zero contour except where the Tensleep has been exposed by uplift and erosion. Known Tensleep fields in south-central Montana are generally small in area, which agrees with outcrop studies that show eolian dune sequences are generally quite small in lateral extent, on the order of 10 to 40 acres. Although existing fields are small in area, they are very productive; individual wells will probably make 300,000 to 500,000 barrels of oil. In the project area, hydrodynamic considerations are important. All the existing Tensleep fields have active water drives. In many cases, the reservoir pressure today is as it was when initially discovered. In areas of high structural complexity, such as the Lodge Grass-Crow Agency fault and the Lake Basin fault zone, significant structural closure may be necessary to trap oil because of the strong hydrodynamic influence exerted by the underlying Madison Formation aquifer.

  4. 21 CFR 184.1409 - Ground limestone.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Ground limestone. 184.1409 Section 184.1409 Food... Specific Substances Affirmed as GRAS § 184.1409 Ground limestone. (a) Ground limestone consists essentially... classifying of naturally occurring limestone. (b) The ingredient meets the specifications of the...

  5. The rediscovery of Astragalus autranii (Fabaceae) on Mt Tomor, south central Albania

    DEFF Research Database (Denmark)

    Tan, Kit; Shuka, Lulezim; Gjeta, Ermelinda

    2015-01-01

    collected by Baldacci in 1892 on Mt Tomor in south central Albania and rediscovered by Markgraf at the locus classicus in June 1928. A complete and amended description of the species is here provided as corolla features were not available in the type material and the flower colour was incorrectly described...

  6. Recreation and tourism in south-central Alaska: patterns and prospects.

    Science.gov (United States)

    Steve Colt; Stephanie Martin; Jenna Mieren; Martha. Tomeo

    2002-01-01

    Based on data from various sources, this report describes the extent and nature of recreation and tourism in south-central Alaska. Current activities, past trends, and prospective developments are presented. Particular attention is given to activities that occur on, or are directly affected by management of, the Chugach National Forest. Recreation and tourism in and...

  7. Vegetation and Terrain Relationships in South-Central New Mexico and Western Texas

    Science.gov (United States)

    1980-11-01

    tea) Ephecotu tutiWrCa Torr. (long-leaf nphedra; Mormon tea) GRAMINEAE (Grasses) Anditwpogon bwrfbiudis, Lag. -Anditopogon zcchww-LdeA, Swartz (Silver...7I E APPENDIX G. (Continued) A Listing of the Flora of the Fort Bliss and Adjacent Areas in South-Central New Mexico Plant Community. GRAMINEAE

  8. Sedimentology and paleogeography of an Upper Cretaceous turbidite basin in the South-Central Pyrenees, Spain

    NARCIS (Netherlands)

    Hoorn, van B.

    1970-01-01

    The present study deals with the primary lithology, sedimentary structures, depositional history and paleogeography of an Upper Cretaceous turbidite basin in the south-central Pyrenees, and presents a brief review of the lithology and depositional environment of surrounding contemporaneous deposits.

  9. Lithostratigraphic subdivision of Post-Hercynian deposits in the South-Central Pyrenees, Spain

    NARCIS (Netherlands)

    Mey, P.H.W.; Nagtegaal, P.J.C.; Roberti, K.J.; Hartevelt, J.J.A.

    1968-01-01

    On the existing geological maps of the South-Central Pyrenees such as those of Dalloni (1910, 1930), Misch (1934), Almela & Rios (1947) and Alastrue, Almela & Rios (1957) the units distinguished and the colours used represent stratigraphie time intervals. Many stage boundaries, however, fall at

  10. Geochemical Investigation of the Arbuckle-Simpson Aquifer, South-Central Oklahoma, 2004-06

    Science.gov (United States)

    Christenson, Scott; Hunt, Andrew G.; Parkhurst, David L.

    2009-01-01

    A geochemical reconnaissance investigation of the Arbuckle-Simpson aquifer in south-central Oklahoma was initiated in 2004 to characterize the ground-water quality at an aquifer scale, to describe the chemical evolution of ground water as it flows from recharge areas to discharge in wells and springs, and to determine the residence time of ground water in the aquifer. Thirty-six water samples were collected from 32 wells and springs distributed across the aquifer for chemical analysis of major ions, trace elements, isotopes of oxygen and hydrogen, dissolved gases, and age-dating tracers. In general, the waters from wells and springs in the Arbuckle-Simpson aquifer are chemically suitable for all regulated uses, such as public supplies. Dissolved solids concentrations are low, with a median of 347 milligrams per liter (mg/L). Two domestic wells produced water with nitrate concentrations that exceeded the U.S. Environmental Protection Agency's nitrate maximum contaminant level (MCL) of 10 mg/L. Samples from two wells in the confined part of the aquifer exceeded the secondary maximum contaminant level (SMCL) for chloride of 250 mg/L and the SMCL of 500 mg/L for dissolved solids. Water samples from these two wells are not representative of water samples from the other wells and springs completed in the unconfined part of the aquifer. No other water samples from the Arbuckle-Simpson geochemical reconnaissance exceeded MCLs or SMCLs, although not every chemical constituent for which the U.S. Environmental Protection Agency has established a MCL or SMCL was analyzed as part of the Arbuckle-Simpson geochemical investigation. The major ion chemistry of 34 of the 36 samples indicates the water is a calcium bicarbonate or calcium magnesium bicarbonate water type. Calcium bicarbonate water type is found in the western part of the aquifer, which is predominantly limestone. Calcium magnesium bicarbonate water is found in the eastern part of the aquifer, which is predominantly a

  11. Genetic Diversity of the Ring-Tailed Lemur (Lemur catta) in South-Central Madagascar.

    Science.gov (United States)

    Clarke, Tara A; Gray, Olivia; Gould, Lisa; Burrell, Andrew S

    2015-01-01

    Madagascar's lemurs, now deemed the most endangered group of mammals, represent the highest primate conservation priority in the world. Due to anthropogenic disturbances, an estimated 10% of Malagasy forest cover remains. The endangered Lemur catta is endemic to the southern regions of Madagascar and now occupies primarily fragmented forest habitats. We examined the influence of habitat fragmentation and isolation on the genetic diversity of L. catta across 3 different forest fragments in south-central Madagascar. Our analysis revealed moderate levels of genetic diversity. Genetic differentiation among the sites ranged from 0.05 to 0.11. These data suggest that the L. catta populations within south-central Madagascar have not yet lost significant genetic variation. However, due to ongoing anthropogenic threats faced by ring-tailed lemurs, continued conservation and research initiatives are imperative for long-term viability of the species. © 2015 S. Karger AG, Basel.

  12. West Nile Virus Antibodies in Permanent Resident and Overwintering Migrant Birds in South-Central Kansas

    OpenAIRE

    Shelite, Thomas R.; Rogers, Christopher M.; Litzner, Brandon R.; Johnson, R. Roy; Schneegurt, Mark A.

    2008-01-01

    We conducted serological studies, using epitope-blocking ELISAs directed at West Nile virus (WNV) and flavivirus antibodies, of wild birds in south-central Kansas, the first for this state, in the winters of 2003–04 through 2005–06. Overwintering migratory species (primarily the American tree sparrow and dark-eyed junco) consistently showed significantly lower seropositivity than permanent residents (primarily the northern cardinal). The cardinal showed annual variation in seropositivity betw...

  13. Salt decay of Morley limestone

    NARCIS (Netherlands)

    Nijland, T.G.; Van Hees, R.P.J.

    2009-01-01

    Salt weathering is one of the main causes of decay of natural stone, and by consequence a major problem to the conservation of cultural heritage. In the present case, the performance of Morley limestone from the Département Meuse, France, as a replacement stone under saltloaded conditions is evaluat

  14. Paleozoic Hydrocarbon-Seep Limestones

    Science.gov (United States)

    Peckmann, J.

    2007-12-01

    To date, five Paleozoic hydrocarbon-seep limestones have been recognized based on carbonate fabrics, associated fauna, and stable carbon isotopes. These are the Middle Devonian Hollard Mound from the Antiatlas of Morocco [1], Late Devonian limestone lenses with the dimerelloid brachiopod Dzieduszyckia from the Western Meseta of Morocco [2], Middle Mississippian limestones with the dimerelloid brachiopod Ibergirhynchia from the Harz Mountains of Germany [3], Early Pennsylvanian limestones from the Tantes Mound in the High Pyrenees of France [4], and Late Pennsylvanian limestone lenses from the Ganigobis Shale Member of southern Namibia [5]. Among these examples, the composition of seepage fluids varied substantially as inferred from delta C-13 values of early diagenetic carbonate phases. Delta C-13 values as low as -50 per mil from the Tantes Mound and -51 per mil from the Ganigobis limestones reveal seepage of biogenic methane, whereas values of -12 per mil from limestones with Dzieduszyckia associated with abundant pyrobitumen agree with oil seepage. Intermediate delta C-13 values of carbonate cements from the Hollard Mound and Ibergirhynchia deposits probably reflect seepage of thermogenic methane. It is presently very difficult to assess the faunal evolution at seeps in the Paleozoic based on the limited number of examples. Two of the known seeps were typified by extremely abundant rhynchonellide brachiopods of the superfamily Dimerelloidea. Bivalve mollusks and tubeworms were abundant at two of the known Paleozoic seep sites; one was dominated by bivalve mollusks (Hollard Mound, Middle Devonian), another was dominated by tubeworms (Ganigobis Shale Member, Late Pennsylvanian). The tubeworms from these two deposits are interpreted to represent vestimentiferan worms, based on studies of the taphonomy of modern vestimentiferans. However, this interpretation is in conflict with the estimated evolutionary age of vestimentiferans based on molecular clock methods

  15. Tribal engagement strategy of the South Central Climate Science Center, 2014

    Science.gov (United States)

    Andrews, William J.; Taylor, April; Winton, Kimberly T.

    2014-01-01

    The South Central Climate Science Center was established by the U.S. Department of the Interior in 2012 to increase understanding of climate change and coordinate an effective response to climate-change effects on Native American tribes and natural and cultural resources that the Department manages. The eight regional Climate Science Centers of the U.S. Department of the Interior work closely with natural-resource management agencies, university researchers, and others such as tribes and private landowners on climate-change issues. The relatively large number of Native Americans in the south central United States and their special knowledge of changing ecosystems make working with tribes and tribal members on climate-change issues particularly important in this part of the Nation. This circular describes priorities of the South Central Climate Science Center and provides information about resources available from Climate Science Centers and partner agencies regarding climate change. The circular also describes how this Climate Science Center, tribes and tribal members, and others can collaborate to minimize potential harmful effects of climate change on human society and our surrounding ecosystems.

  16. Limestone valib eetilisi firmasid / Virge Lahe

    Index Scriptorium Estoniae

    Lahe, Virge

    2008-01-01

    Endised Hansapanga investeerimisfondide analüütikud hakkavad läbi Limestone fondide pakkuma sotsiaalselt vastutustundlikku investeerimist (Socially Responsible Investing). Kommenteerivad Art Lukas ja Silver Vohu. Vt. samas: Limestone Investment Management AS

  17. Engineering Geology of Limestone in Malaysia

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    This paper provides an overview of the engineering geology of limestone. Limestone is of rather wide occurrence in Malaysia. It is interesting in view of the unique landforms and karstic features that are encountered in limestone terrains, e.g. steep, subvertical limestone cliffs rising abruptly and majestically above the ground surface and highly variable and pinnacled subterranean limestone bedrock. The karstic features and associated engineering geological problems of both the limestone hills and the bedrock are discussed in the paper. Rockfalls, sinkholes, cavities, etc. are some of the common engineering geological problems associated with limestone terrains. Some local case studies are provided as illustrations. Finally the rock mechanical properties of limestone is discussed at the end of the paper.``

  18. Limestone valib eetilisi firmasid / Virge Lahe

    Index Scriptorium Estoniae

    Lahe, Virge

    2008-01-01

    Endised Hansapanga investeerimisfondide analüütikud hakkavad läbi Limestone fondide pakkuma sotsiaalselt vastutustundlikku investeerimist (Socially Responsible Investing). Kommenteerivad Art Lukas ja Silver Vohu. Vt. samas: Limestone Investment Management AS

  19. Structural studies in limestone sulfidation

    Energy Technology Data Exchange (ETDEWEB)

    Fenouil, Laurent A. [Univ. of California, Berkeley, CA (United States)

    1993-05-01

    This study investigates the sulfidation of limestone at high temperatures (700--900°C) as the first step in the design of a High-Temperature Coal-Gas Clean-Up system using millimeter-size limestone particles. Several workers have found that the rate of this reaction significantly decreases after an initial 10 to 15% conversion of CaCO3 to CaS. The present work attempts to explain this feature. It is first established that millimeter-size limestone particles do not sinter at temperatures up to the CaCO3 calcination point (899°C at 1.03 bar CO2} partial pressure). It is then shown that CaS sinters rapidly at 750 to 900°C if CO2 is present in the gas phase. Scanning Electron Microscope (SEM) photographs and Electron Dispersive Spectroscopy (EDS) data reveal that the CaS product layer sinters and forms a quasi-impermeable coating around the CaCO3 grains that greatly hinders more H2S from reaching the still unreacted parts of the stone. Moreover, most of the pores initially present within the limestone structure begin to disappear or, at least, are significantly reduced in size. From then on, subsequent conversion is limited by diffusion of H2S through the CaS layer, possibly by S2- ionic diffusion. The kinetics is then adequately described by a shrinking-core model, in which a sharp front of completely converted limestone is assumed to progress toward the center of the pellet. Finally, experimental evidence and computer simulations using simple sintering models suggest that the CaS sintering, responsible for the sharp decrease in the sulfidation rate, is surface-diffusion controlled.

  20. CALCIUM CARBONATE DISSOLUTION RATE IN LIMESTONE CONTACTORS

    Science.gov (United States)

    The rate of carbonate mineral dissolution from limestone was studied using a rotating disk apparatus and samples of limestone of varied composition. The purpose of this study was to determine the effect of limestone composition on the kinetics of carbonate mineral dissolution. Th...

  1. Simulation of canal and control-pond operation at the Quivira National Wildlife Refuge, south-central Kansas

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Efficient water management of the Quivira National Wildlife Refuge, located in the Rattlesnake Creek Basin of south-central Kansas, is a complicated task. In a...

  2. Ground-water quality in quaternary deposits of the central high plains aquifer, south-central Kansas, 1999

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Water samples from 20 randomly selected domestic water-supply wells completed in the Quaternary deposits of south-central Kansas were collected as part of the High...

  3. Reclaiming our Past: A Critical Race History of Chicana/o Education In South Central Los Angeles, 1930-1949

    OpenAIRE

    Alonso, LLuliana

    2015-01-01

    This dissertation explores the educational experiences of Chicana/os in the first half of the twentieth century using one of the most ethnically diverse communities in the state of California—South Central Los Angeles—as a case study. Driven by the following questions, my research explored: 1) What were the social and economic conditions of the Mexican community of South Central Los Angeles during 1930-1949? 2) What were the dominant discourses about this population during the period understu...

  4. Organic pollutant burden of the giant mussels Choromytilus chorus from the south-central Chilean coast.

    Science.gov (United States)

    Toro, Beatriz; Palma-Fleming, Hernán; Navarro, Jorge M

    2004-04-01

    A comparative quantitative analysis was made on the contents of organochlorines (OCh) and polycyclic aromatic hydrocarbons (PAH) in tissues of the giant mussel Choromytilus chorus from three bays in south-central Chile exposed to various degrees of pollutant input. Mussels from the three bays contained levels of OCh near the detection limits of method, with a tendency to be slightly higher in the polluted bay (San Vicente) than in the other bays (Corral and Yaldad). PAH levels and types in Corral and Yaldad were well below of carcinogenicity permitted in mussels for human consumption.

  5. Impacts of land use and climate change on carbon dynamics in south-central Senegal

    Science.gov (United States)

    Liu, Shu-Guang; Kaire, M.; Wood, Eric C.; Diallo, O.; Tieszen, Larry L.

    2004-01-01

    Total carbon stock in vegetation and soils was reduced 37% in south-central Senegal from 1900 to 2000. The decreasing trend will continue during the 21st century unless forest clearing is stopped, selective logging dramatically reduced, and climate change, if any, relatively small. Developing a sustainable fuelwood and charcoal production system could be the most feasible and significant carbon sequestration project in the region. If future climate changes dramatically as some models have predicted, cropland productivity will drop more than 65% around 2100, posing a serious threat to food security and the efficiency of carbon sequestration projects.

  6. Reconnaissance geologic map of the Sangre de Cristo Wilderness Study Area, south-central Colorado

    Science.gov (United States)

    Johnson, Bruce R.; Lindsey, David A.; Bruce, R.M.; Soulliere, Sandra J.

    1987-01-01

    The Wilderness Act (Public Law 88-577, September 3, 1964) and related acts require the U.S. Geological Survey and the U.S. Bureau of Mines to survey certain areas on Federal lands to determine the mineral values, if any, that may be present. Results must be made available to the public and to be submitted to the President and Congress. This report presents the results of geologic studies in the Sangre de Cristo Wilderness Study Area in the Rio Grande and San Isabel National Forests, south-central Colorado. The area was designated as a wilderness study area under Public Lay 96-560 in 1980. 

  7. A 600-year-long stratigraphic record of tsunamis in south-central Chile

    Science.gov (United States)

    Hong, Isabel; Dura, Tina; Ely, Lisa L.; Horton, Benajamin P.; Nelson, Alan R.; Cisternas, Marco; Nikitina, Daria; Wesson, Robert L.

    2017-01-01

    The stratigraphy within coastal river valleys in south-central Chile clarifies and extends the region’s history of large, earthquakes and accompanying tsunamis. Our site at Quidico (38.1°S, 73.3°W) is located in an overlap zone between ruptures of magnitude 8–9 earthquakes in 1960 and 2010, and, therefore, records tsunamis originating from subduction-zone ruptures north and south of the city of Concepción. Hand-dug pits and cores in a 3-m-thick sequence of freshwater peat in an abandoned meander (a little-examined depositional environment for tsunami deposits) and exposures along the Quidico River show five sand beds that extend as much as 1.2 km inland. Evidence for deposition of the beds by tsunamis includes tabular sand beds that are laterally extensive (>100 m), well sorted, fine upward, have sharp lower contacts, and contain diatom assemblages dominated by brackish and marine taxa. Using eyewitness accounts of tsunami inundation, 137Cs analyses, and 14C dating, we matched the upper four sand beds with historical tsunamis in 2010, 1960, 1835, and 1751. The oldest prehistoric bed dates to 1445–1490 CE and correlates with lacustrine and coastal records of similar-aged earthquakes and tsunamis in south-central Chile.

  8. Lead in drinking water: sampling in primary schools and preschools in south central Kansas.

    Science.gov (United States)

    Massey, Anne R; Steele, Janet E

    2012-03-01

    Studies in Philadelphia, New York City, Houston, Washington, DC, and Greenville, North Carolina, have revealed high lead levels in drinking water. Unlike urban areas, lead levels in drinking water in suburban and rural areas have not been adequately studied. In the study described in this article, drinking water in primary schools and preschools in five suburban and rural south central Kansas towns was sampled to determine if any exceeded the U.S. Environmental Protection Agency (U.S. EPA) guidance level for schools and child care facilities of 20 parts per billion (ppb). The results showed a total of 32.1% of the samples had detectable lead levels and 3.6% exceeded the U.S. EPA guidance level for schools and child care providers of 20 ppb. These results indicate that about one-third of the drinking water consumed by children age six and under in the five suburban and rural south central Kansas towns studied has some lead contamination, exposing these children to both short-term and long-term health risks. The authors suggest a need for increased surveillance of children's drinking water in these facilities.

  9. U.S. Department of the Interior South Central Climate Science Center

    Science.gov (United States)

    Shipp, Allison A.

    2012-01-01

    On September 14, 2009, the Secretary of the Interior signed a Secretarial Order (No. 3289) entitled, "Addressing the Impacts of Climate Change on America's Water, Land, and Other Natural and Cultural Resources." The Order effectively established the U.S. Department of the Interior (DOI) Climate Science Centers (CSCs) for the purpose of integrating DOI science and management expertise with similar contributions from our partners to provide information to support strategic adaptation and mitigation efforts on public and private lands across the United States and internationally. The South Central Climate Science Center (SC CSC) is supported by a consortium of partners that include The University of Oklahoma, Texas Tech University, Louisiana State University, The Chickasaw Nation, The Choctaw Nation of Oklahoma, Oklahoma State University, and the National Oceanic and Atmospheric Administration's Geophysical Fluid Dynamics Laboratory. Additionally, the SC CSC will collaborate with a number of other universities, State and federal agencies, and nongovernmental organizations (NGOs) with interests and expertise in climate science. The primary partners of the SC CSC are the Landscape Conservation Cooperatives (LCCs), which include the Desert, Eastern Tallgrass Prairie and Big Rivers, Great Plains, Gulf Coast Prairie, Gulf Coastal Plains and Ozarks, and Southern Rockies. CSC collaborations are focused on common science priorities that address priority partner needs, eliminate redundancies in science, share scientific information and findings, and expand understanding of climate change impacts in the south-central United States and Mexico.

  10. Three-dimensional electrical resistivity image of the South-Central Chilean subduction zone

    Science.gov (United States)

    Kapinos, Gerhard; Montahaei, Mansoureh; Meqbel, Naser; Brasse, Heinrich

    2016-01-01

    Based on isotropic 3-D inversion, we re-interpret long-period magnetotelluric data collected across the geotectonic structures of the South-Central Chilean continental margin at latitudes 38°-41°S and summarize results of long-period magnetotelluric (MT) investigations performed between 2000 and 2005. The new 3-D conductivity image of the South-Central Chilean subduction zone basically confirms former 2-D inversion models along three profiles and complete the previous results. The models show good electrical conductors in the tip of the continental crustal beneath the Pacific Ocean, the frequently observed forearc conductor at mid-crustal levels, a highly-conductive zone at similar levels slightly offset from the volcanic arc and a - not well-resolved - conductor in the Argentinian backarc. The subducted Nazca Plate generally appears as a resistive but discontinuous feature. Unlike before, we are now able to resolve upper crustal conductors (interpreted as magma reservoirs) beneath active Lonquimay, Villarrica, and Llaima volcanoes which were obscured in 2-D inversion. Data fit is rather satisfactory but not perfect; we attribute this to large-scale crustal anisotropy particularly beneath the Coastal Cordillera, which we cannot include into our solution for the time being.

  11. Early development of the south Central American margin: mechanisms and tectonic implications

    Science.gov (United States)

    Buchs, D. M.; Baumgartner, P. O.; Arculus, R.; Montes, C.; Bayona, G.; Cardona, A.

    2012-04-01

    The south Central American margin forms the SW border of the Caribbean Plate on top of the subducting Cocos and Nazca Plates between Nicaragua and Colombia. New and previous tectonostratigraphic, age and geochemical results show that the forearc basement between south Costa Rica and east Panama is composed of autochthonous and accreted sequences that provide important constraints on the development of the south Central American margin, the evolution of the Caribbean Plate and the formation of an inter-American land bridge. Autochtonous sequences in the forearc include three tectonostratigraphic units that occur at a regional scale: (1) a Late Cretaceous oceanic plateau considered to represent an extension of the Caribbean Large Igneous Province (CLIP) at the base of the arc; (2) Late Campanian to Maastrichtian protoarc sequences that cover or intrude the oceanic plateau; and (3) Maastrichtian to Eocene sequences of a more mature volcanic arc that overlies or intrude preceding units. These units clearly indicate that subduction initiation along the margin and, thus, the birth of the Caribbean Plate occurred in the Campanian. Incipient subduction was possibly triggered or facilitated by contrasted lithospheric strength across the edge of the CLIP and collision between the CLIP and South America during westward migration of South America. Accreted sequences in the forearc include mostly Late Cretaceous to Eocene seamount fragments between south Costa Rica and west Panama, with additional Eocene to Miocene olistostromal and hemipelagic sediments in south Costa Rica. The age and tectonostratigraphic relationships of accreted sequences, autochtonous sequences, and overlying forearc slope sediment suggest that subduction erosion, punctuated by local seamount or sediment accretion was the dominant process controlling the evolution of the outer margin at least until the Miocene. A major tectonic event affected the margin in the Middle Eocene, which is indicated by a

  12. The Record of Giant Earthquakes in the Sediments of Lago Villarrica (South-Central Chile)

    Science.gov (United States)

    Moernaut, J.; de Batist, M.; Pino, M.; Brümmer, R.

    2008-05-01

    South-Central Chile is located where the oceanic Nazca plate actively subducts underneath the continental South American plate. This subduction zone has ruptured in great destructive earthquakes with variable magnitude during historical times, with as tragic highlight the 1960 Valdivia earthquake, which accounts for the largest instrumentally recorded earthquake worldwide (Moment Magnitude: 9.5). Damage from severe ground-shaking was reported from up to 1000 km south of the 1960 earthquake epicenter and a devastating tsunami ravaged across the Pacific. The historical earthquake records in South-Central Chile only cover ~500 yrs, so "natural" archives -in which paleo-earthquake activity has been recorded and preserved- need to be explored to reveal a statistically significant earthquake recurrence. In this study, a high-resolution seismic survey on Lago Villarrica has been executed to study its sedimentary infill for fingerprints of severe shaking. The seismic profiles acquired in our study show a succession of voluminous underwater landslide deposits and their related failure scars. Multiple slope failures occurred simultaneously in calm depositional environments, which points toward a strong, instantaneous basin-wide trigger of slope instability. Evaluation of all possible slope failure processes led us to infer that very strong earthquakes are the most likely triggers of these landslide events. Our seismic profiles also show a distinct stratigraphic level of sediment disturbance, locally overlain by a field of sediment volcanoes, which have dimensions up to 70 m wide and 2 m thick. These structures are interpreted as a result of sudden compaction in a buried landslide deposit and subsequent vertical flow of overpressured pore water and entrained sediments which have been expelled at the paleo-lake bottom. We postulate that this process of subsurface sediment mobilization has been triggered by seismic ground-shaking, as such sediment volcanoes have been commonly

  13. Streamflow characteristics and trends at selected streamgages in southwest and south-central Kansas

    Science.gov (United States)

    Juracek, Kyle E.

    2016-01-11

    Historical data for nine selected streamgages in southwest and south-central Kansas were used in an assessment of streamflow characteristics and trends. This information is required by the U.S. Fish and Wildlife Service and the Kansas Department of Wildlife, Parks and Tourism to assist with the effective management of Etheostoma cragini (Arkansas darter) habitats and populations in the State. Changing streamflow conditions, such as a reduction or elimination of streamflow, may adversely affect the Arkansas darter. Priority basins for the Arkansas darter represented by the selected streamgages include the Cimarron River, Rattlesnake Creek, the North Fork Ninnescah River, the South Fork Ninnescah River, the Medicine Lodge River, and the Chikaskia River.

  14. Streamflow characteristics and trends at selected streamgages in southwest and south-central Kansas

    Science.gov (United States)

    Juracek, Kyle E.

    2016-01-11

    Historical data for nine selected streamgages in southwest and south-central Kansas were used in an assessment of streamflow characteristics and trends. This information is required by the U.S. Fish and Wildlife Service and the Kansas Department of Wildlife, Parks and Tourism to assist with the effective management of Etheostoma cragini (Arkansas darter) habitats and populations in the State. Changing streamflow conditions, such as a reduction or elimination of streamflow, may adversely affect the Arkansas darter. Priority basins for the Arkansas darter represented by the selected streamgages include the Cimarron River, Rattlesnake Creek, the North Fork Ninnescah River, the South Fork Ninnescah River, the Medicine Lodge River, and the Chikaskia River.

  15. Land surface and atmospheric conditions associated with heat waves in the South Central United States

    Science.gov (United States)

    Lee, Eungul; Bieda, Rahama; Shanmugasundaram, Jothiganesh; Richter, Heather

    2017-04-01

    Exposure to extreme heat was reconstructed based on regional land-atmosphere processes from 1979 to 2010 in the South Central U.S. The study region surrounds the Chickasaw Nation (CN), a predominantly Native American population with a highly prevalent burden of climate-sensitive chronic diseases. Land surface and atmospheric conditions for summer heat waves were analyzed during spring (March-April-May, MAM) and summer (June-July-August, JJA) based on the Climate and Ocean: Variability, Predictability, and Change maximum temperature definition for heat wave frequency (HWF). The spatial-temporal pattern of HWF was determined using empirical orthogonal function (EOF) analysis and the corresponding principle component time series of the first EOF of HWF. Statistically significant analyses of observed conditions indicated that sensible heat increased and latent heat fluxes decreased with high HWF in the South Central U.S. The largest positive correlations of sensible heat flux to HWF and the largest negative correlations of latent heat flux to HWF were specifically observed over the CN. This is a significantly different energy transfer regime due to less available soil moisture during the antecedent MAM and JJA. The higher sensible heat from dry soil could cause significant warming from the near surface (> 2.0°C) to the lower troposphere (> 1.5°C), and accumulated boundary layer heat could induce the significant patterns of higher geopotential height and enhance anticyclonic circulations (negative vorticity anomaly) at the midtroposphere. Results suggested a positive land-atmosphere feedback associated with heat waves and called attention to the need for region-specific climate adaptation planning.

  16. Tuberculosis among HIV-positive patients at Butajira Hospital, South-Central Ethiopia

    Directory of Open Access Journals (Sweden)

    Seada Mohammed

    2015-12-01

    Full Text Available Background: Tuberculosis (TB is the leading cause of morbidity and mortality among people living with Human Immunodeficiency Virus (HIV. This study was carried out to determine the prevalence of tuberculosis and its associated factors among HIV-positive patients at Butajira Hospital, South-Central Ethiopia. Methods: A retrospective review of standardized 222 HIV-positive patient records between July 2011 and June 2012 was conducted. A data sheet was used to collect relevant variables. Data were entered, organized and analysed using SPSS Version 16.0 Software. A p-value 15 years (18.95%. Among 45 TB/HIV cases, 26.7% had smear-positive pulmonary TB; 62.2% had smear-negative pulmonary TB; and 11.1% had extra-pulmonary TB. Malnutrition (OR= 45.7, CD4+ T-cell count <200/μl (OR= 5.4 and WHO clinical stage III or IV (OR= 4.12 were associated with tuberculosis in HIV-positive patients. Conclusion: In conclusion, the prevalence of TB/HIV co-infection at Butajira Zonal Hospital, South-Central Ethiopia was high. The co-infection was associated with malnutrition, low CD4 + T-cell count and WHO clinical stage III or IV. Therefore, compulsory TB screening among HIV-positive patients is mandatory. Besides, public awareness, community mobilization should be encouraged. Moreover, large scale studies on the trends in TB/HIV co-infection and associated factors should also be implemented across the country.

  17. Mio-Pliocene aridity in the south-central Andes associated with Southern Hemisphere cold periods.

    Science.gov (United States)

    Amidon, William H; Fisher, G Burch; Burbank, Douglas W; Ciccioli, Patricia L; Alonso, Ricardo N; Gorin, Andrew L; Silverhart, Perri H; Kylander-Clark, Andrew R C; Christoffersen, Michael S

    2017-06-20

    Although Earth's climate history is best known through marine records, the corresponding continental climatic conditions drive the evolution of terrestrial life. Continental conditions during the latest Miocene are of particular interest because global faunal turnover is roughly synchronous with a period of global glaciation from ∼6.2-5.5 Ma and with the Messinian Salinity Crisis from ∼6.0-5.3 Ma. Despite the climatic and ecological significance of this period, the continental climatic conditions associated with it remain unclear. We address this question using erosion rates of ancient watersheds to constrain Mio-Pliocene climatic conditions in the south-central Andes near 30° S. Our results show two slowdowns in erosion rate, one from ∼6.1-5.2 Ma and another from 3.6 to 3.3 Ma, which we attribute to periods of continental aridity. This view is supported by synchrony with other regional proxies for aridity and with the timing of glacial ‟cold" periods as recorded by marine proxies, such as the M2 isotope excursion. We thus conclude that aridity in the south-central Andes is associated with cold periods at high southern latitudes, perhaps due to a northward migration of the Southern Hemisphere westerlies, which disrupted the South American Low Level Jet that delivers moisture to southeastern South America. Colder glacial periods, and possibly associated reductions in atmospheric CO2, thus seem to be an important driver of Mio-Pliocene ecological transitions in the central Andes. Finally, this study demonstrates that paleo-erosion rates can be a powerful proxy for ancient continental climates that lie beyond the reach of most lacustrine and glacial archives.

  18. Climate variability and spruce beetle (Dendroctonus rufipennis) outbreaks in south-central and southwest Alaska.

    Science.gov (United States)

    Sherriff, Rosemary L; Berg, Edward E; Miller, Amy E

    2011-07-01

    We used tree ring data (AD 1601-2007) to examine the occurrence of and climatic influences on spruce beetle (Dendroctonus rufipennis) outbreaks in south-central and southwest Alaska and found evidence of regional-scale outbreaks dating from the mid-1700s, related to climate variability at multiple temporal scales. Over interannual time scales (approximately 1-3 years), El Niño years, combined with severe late-summer drought, appeared to contribute significantly to spruce beetle outbreaks in the study area. Over multidecadal time scales (up to approximately 40 years), cool-phase Pacific Decadal Oscillation (PDO) conditions tended to precede beetle outbreaks, regardless of the phase of El Niño-Southern Oscillation (ENSO). All sites showed low-severity disturbances attributed to spruce beetle damage, most notably during the 1810s. During other major periods of disturbance (i.e., 1870s, 1910s, 1970s), the effects of spruce beetle outbreaks were of moderate or higher severity. The highly synchronized timing of spruce beetle outbreaks at interannual to multidecadal scales, and particularly the association between cool-phase PDO conditions and beetle disturbance, suggests that climate (i.e., temperature, precipitation) is a primary driver of outbreaks in the study area. Our disturbance chronologies (mid-1700s to present) suggest that recent irruptions (1990s to present) in south-central and southwest Alaska are within the historical geographic range, but that outbreaks since the 1990s show greater spatiotemporal synchrony (i.e., more sites record high-severity infestations) than at any other time in the past approximatly 250 years.

  19. Watershed Governance in South-Central Texas: Working from the Bottom up

    Science.gov (United States)

    Lopes, V. L.

    2014-12-01

    The purpose of this presentation is to introduce a set of key concepts that can guide the development of ecological governance systems and briefly describe a watershed ecological governance project in south-central Texas. Ecological governance is a form of governance embedding ecological principles and values in all levels of decision making and action, from the personal to the global. The model of ecological governance discussed here incorporates ideas and approaches that are already being put into practice in many watershed governance projects in the US and abroad; it is based on the premise that contemporary governance systems will continue to evolve in this direction, incorporating more and more of the features of ecological governance. The watershed governance project described here was devised to ensure that the long-term ecological integrity of a small urbanazing waterhed in south-central Texas is preserved and that the water quality standards are maintained for present and future generations. The ecological integrity of small spring-fed watersheds in Texas are under serious threat due to rapid urban development dependent on groundwater supplies, continued drilling of personal wells that are exempt from pumping regulation, and lack of adequate legal jurisdiction for managing development in rural and semi-rural areas. The watershed governance project was motivated by a firm belief of local stakeholders that watershed protection is an individual as well as a community responsibility, and the recognition that a balance between growth and protection is essential to maintain watershed integrity. It is concluded that whereas emergent systems of ecological governance struggle to succeed in an institutional context oriented towards the pursuit of self-interest and competition, their acceptance will happen more readily as ecological principles and values diffuses throughout modern society.

  20. The use of limestone powder as an alternative cement replacement ...

    African Journals Online (AJOL)

    The use of limestone powder as an alternative cement replacement material: An ... The laboratory test results revealed that up to 15% replacement of clinker by fine ... Early strength, Limestone filler, Loss on ignition, Portland limestone cement ...

  1. Sedimentology, paleoclimatology, and diagenesis of Post-Hercynian continental deposits in the South-Central Pyrenees, Spain

    NARCIS (Netherlands)

    Nagtegaal, Peter J.C.

    1969-01-01

    The first chapter of the post-Hercynian geologic history of the South-Central Pyrenees is recorded in a sequence of fluvial and volcanic deposits which reach a total of added maximum thicknesses of more than 2300 m and date from the Westphalian D up to and including the Lower Triassic. The present s

  2. Depositional history and clay minerals of the Upper Cretaceous basin in the South-Central Pyrenees, Spain

    NARCIS (Netherlands)

    Nagtegaal, P.J.C.

    1972-01-01

    An ordered sequence of well-defined sedimentary environments reflects the deepening and shallowing stages in the depositional history of the Upper Cretaceous basin in the South-Central Pyrenees, Spain. The sequence, which has a Santonian age at its base, starts with a calcarenite barrier system on w

  3. The Wallula fault and tectonic framework of south-central Washington, as interpreted from magnetic and gravity anomalies

    Energy Technology Data Exchange (ETDEWEB)

    Blakely, Richard J. [U.S. Geological Survey, Menlo Park, CA (United States); Sherrod, Brian [U.S. Geological Survey, Seattle, WA (United States); Weaver, Craig [U.S. Geological Survey, Seattle, WA (United States); Wells, Ray E. [U.S. Geological Survey, Menlo Park, CA (United States); Rohay, Alan C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2013-11-13

    Magnetic and gravity data, collected in south-central Washington near the Yakima Fold and Thrust Belt (YFTB) are used to model upper crustal structure, the extent of the late Columbia River Basalt flow named the Ice Harbor member, the vertical conduits (dikes) that the Ice Harbor erupted from, and whether the dikes are offset or affected by faulting on the Wallula Fault zone.

  4. Depositional history and clay minerals of the Upper Cretaceous basin in the South-Central Pyrenees, Spain

    NARCIS (Netherlands)

    Nagtegaal, P.J.C.

    1972-01-01

    An ordered sequence of well-defined sedimentary environments reflects the deepening and shallowing stages in the depositional history of the Upper Cretaceous basin in the South-Central Pyrenees, Spain. The sequence, which has a Santonian age at its base, starts with a calcarenite barrier system on w

  5. Biomarker evidence for increasing aridity in south-central India over the Holocene

    Science.gov (United States)

    Sarkar, S.; Wilkes, H.; Prasad, S.; Brauer, A.; Basavaiah, N.; Strecker, M. R.; Sachse, D.

    2012-12-01

    Summer monsoonal rainfall has played an important role in the development and sustenance of the largely agro-based economy in the Indian subcontinent in the recent past. A better understanding of past variations in monsoonal rainfall can therefore lead to an assessment of its potential impact on early human societies. However, our knowledge of spatiotemporal patterns of past monsoon strength, as inferred from proxy records, is limited due to the lack of high-resolution paleo-hydrological records from continental archives. Here, we reconstruct centennial-scale hydrological variability associated with changes in the intensity of the Indian Summer Monsoon based on a record of lipid biomarker abundances and compound-specific stable isotopic composition of a 10-m-long sediment core from saline-alkaline Lonar Lake, situated in the core 'monsoon zone' of south-central India. We identified three periods of distinct hydrology over the Holocene in south-central India. The period between 10.4 and 6.5 ka BP was characterized by a relatively high abundance of land-plant biomarkers, such as long-chain n-alkanes. The composition of these leaf-wax n-alkanes (weighted average of concentration of different chain-length n-alkanes, expressed as the ACL index) and their negative δ13C (-30‰ to -33 ‰) indicate the dominance of woody C3 vegetation in the catchment, and negative δD (-170‰ to -175‰) values argue for a wet period due to an intensified monsoon. Rapid fluctuations in abundance of both terrestrial and aquatic biomarkers between 6.5 and 4 ka BP indicate an unstable lake ecosystem, culminating in a transition to arid conditions. Higher ACL values and a pronounced shift to more positive δ13C values (up to -22‰) of leaf-wax n-alkanes over this period indicate a change of dominant vegetation to C4 grasses. Along with a 40‰ increase in leaf wax n-alkane δD values, which likely resulted from less rainfall and/or higher plant evapotranspiration, we interpret this period

  6. Mobile LiDAR Measurement for Aerosol Investigation in South-Central Hebei, China

    Science.gov (United States)

    qin, kai; Wu, Lixin; Zheng, Yunhui; Wong Man, Sing; Wang, Runfeng; Hu, Mingyu; Lang, Hongmei; Wang, Luyao; Bai, Yang; Rao, Lanlan

    2016-04-01

    With the rapid industrialization and urbanization in China during the last decades, the increasing anthropogenic pollutant emissions have significantly caused serious air pollution problems which are adversely influencing public health. Hebei is one of the most air polluted provinces in China. In January 2013, an extremely severe and persistent haze episode with record-breaking PM2.5 outbreak affecting hundreds of millions of people occurred over eastern and northern China. During that haze episode, 7 of the top 10 most polluted cities in China were located in the Hebei Province according to the report of China's Ministry of Environmental Protection. To investigate and the spatial difference and to characterize the vertical distribution of aerosol in different regions of south-central Hebei, mobile measurements were carried out using a mini micro pulse LiDAR system (model: MiniMPL) in March 2014. The mobile LiDAR kit consisting of a MiniMPL, a vibration reduction mount, a power inverter, a Windows surface tablet and a GPS receiver were mounted in a car watching though the sunroof opening. For comparison, a fixed measurement using a traditional micro pulse LiDAR system (model: MPL-4B) was conducted simultaneously in Shijiazhuang, the capital of Hebei Province. The equipped car was driven from downtown Shijiazhuang by way of suburban and rural area to downtown Cangzhou, Handan, and Baoding respectively at almost stable speed around 100Km per hour along different routes which counted in total more than 1000Km. The results can be summarized as: 1) the spatial distribution of total aerosol optical depth along the measurement routes in south-central Hebei was controlled by local terrain and population in general, with high values in downtown and suburban in the plain areas, and low values in rural areas along Taihang mountain to the west and Yan mountain to the north; 2) obviously high AODs were obtained at roads crossing points, inside densely populated area and nearby

  7. Paleoseismic potential of sublacustrine landslide records in a high-seismicity setting (south-central Alaska)

    Science.gov (United States)

    Praet, Nore; Moernaut, Jasper; Van Daele, Maarten; Boes, Evelien; Haeussler, Peter J.; Strupler, Michael; Schmidt, Sabine; Loso, Michael G.; De Batist, Marc

    2017-01-01

    Sublacustrine landslide stratigraphy is considered useful for quantitative paleoseismology in low-seismicity settings. However, as the recharging of underwater slopes with sediments is one of the factors that governs the recurrence of slope failures, it is not clear if landslide deposits can provide continuous paleoseismic records in settings of frequent strong shaking. To test this, we selected three lakes in south-central Alaska that experienced a strong historical megathrust earthquake (the 1964 Mw9.2 Great Alaska Earthquake) and exhibit high sedimentation rates in their main basins (0.2 cm yr-1 -1.0 cm yr-1). We present high-resolution reflection seismic data (3.5 kHz) and radionuclide data from sediment cores in order to investigate factors that control the establishment of a reliable landslide record. Seismic stratigraphy analysis reveals the presence of several landslide deposits in the lacustrine sedimentary infill. Most of these landslide deposits can be attributed to specific landslide events, as multiple landslide deposits sourced from different lacustrine slopes occur on a single stratigraphic horizon. We identify numerous events in the lakes: Eklutna Lake proximal basin (14 events), Eklutna Lake distal basin (8 events), Skilak Lake (7 events) and Kenai Lake (7 events). The most recent event in each basin corresponds to the historic 1964 megathrust earthquake. All events are characterized by multiple landslide deposits, which hints at a regional trigger mechanism, such as an earthquake (the synchronicity criterion). This means that the landslide record in each basin represents a record of past seismic events. Based on extrapolation of sedimentation rates derived from radionuclide dating, we roughly estimate a mean recurrence interval in the Eklutna Lake proximal basin, Eklutna Lake distal basin, Skilak Lake and Kenai Lake, at ~ 250 yrs, ~ 450 yrs, ~ 900 yrs and ~ 450 yrs, respectively. This distinct difference in recording can be explained by variations

  8. Presence of rapidly degrading permafrost plateaus in south-central Alaska

    Science.gov (United States)

    Jones, Benjamin M.; Baughman, Carson A.; Romanovsky, Vladimir E.; Parsekian, Andrew D.; Babcock, Esther L.; Stephani, Eva; Jones, Miriam C.; Grosse, Guido; Berg, Edward E.

    2016-11-01

    Permafrost presence is determined by a complex interaction of climatic, topographic, and ecological conditions operating over long time scales. In particular, vegetation and organic layer characteristics may act to protect permafrost in regions with a mean annual air temperature (MAAT) above 0 °C. In this study, we document the presence of residual permafrost plateaus in the western Kenai Peninsula lowlands of south-central Alaska, a region with a MAAT of 1.5 ± 1 °C (1981-2010). Continuous ground temperature measurements between 16 September 2012 and 15 September 2015, using calibrated thermistor strings, documented the presence of warm permafrost (-0.04 to -0.08 °C). Field measurements (probing) on several plateau features during the fall of 2015 showed that the depth to the permafrost table averaged 1.48 m but at some locations was as shallow as 0.53 m. Late winter surveys (augering, coring, and GPR) in 2016 showed that the average seasonally frozen ground thickness was 0.45 m, overlying a talik above the permafrost table. Measured permafrost thickness ranged from 0.33 to > 6.90 m. Manual interpretation of historic aerial photography acquired in 1950 indicates that residual permafrost plateaus covered 920 ha as mapped across portions of four wetland complexes encompassing 4810 ha. However, between 1950 and ca. 2010, permafrost plateau extent decreased by 60.0 %, with lateral feature degradation accounting for 85.0 % of the reduction in area. Permafrost loss on the Kenai Peninsula is likely associated with a warming climate, wildfires that remove the protective forest and organic layer cover, groundwater flow at depth, and lateral heat transfer from wetland surface waters in the summer. Better understanding the resilience and vulnerability of ecosystem-protected permafrost is critical for mapping and predicting future permafrost extent and degradation across all permafrost regions that are currently warming. Further work should focus on reconstructing

  9. Comparison of two adult mosquito sampling methods with human landing catches in south-central Ethiopia.

    Science.gov (United States)

    Kenea, Oljira; Balkew, Meshesha; Tekie, Habte; Gebre-Michael, Teshome; Deressa, Wakgari; Loha, Eskindir; Lindtjørn, Bernt; Overgaard, Hans J

    2017-01-13

    The human landing catch (HLC) is the standard reference method for measuring human exposure to mosquito bites. However, HLC is labour-intensive, exposes collectors to infectious mosquito bites and is subjected to collector bias. These necessitate local calibration and application of alternative methods. This study was undertaken to determine the relative sampling efficiency (RSE) of light traps with or without yeast-produced carbon dioxide bait vs. HLC in south-central Ethiopia. The experiment was conducted for 39 nights in a 3 × 3 Latin square randomized design with Anopheles arabiensis as the target species in the period between July and November 2014 in Edo Kontola village, south-central Ethiopia. Center for Disease Control and Prevention light trap catches (LTC) and yeast-generated carbon dioxide-baited light trap catches (CB-LTC) were each evaluated against HLC. The total nightly mosquito catches for each Anopheles species in either method was compared with HLC by Pearson correlation and simple linear regression analysis on log-transformed [log10(x + 1)] values. To test if the RSE of each alternative method was affected by mosquito density, the ratio of the number of mosquitoes in each method to the number of mosquitoes in HLC was plotted against the average mosquito abundance. Overall, 7606 Anopheles females were collected by the three sampling methods. Among these 5228 (68.7%) were Anopheles ziemanni, 1153 (15.2%) An. arabiensis, 883 (11.6%) Anopheles funestus s.l., and 342 (4.5%) Anopheles pharoensis. HLC yielded 3392 (44.6%), CB-LTC 2150 (28.3%), and LTC 2064 (27.1%) Anopheles females. The RSEs of LTC and HLC for An. arabiensis were significantly correlated (p method for sampling An. arabiensis. LTC can be used for large-scale indoor An. arabiensis surveillance and monitoring when it is difficult to use HLC. CB-LTC does not substantially improve sampling of this major vector compared to LTC in this setting. Trial registration PACTR201411000882128

  10. Depth to top of the Minnekahta Limestone

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set is a polygon coverage created in ARC/INFO that represents the depth to the top of the Minnekahta Limestone below the land surface, Black Hills, South...

  11. Depth to top of the Madison Limestone

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set is a polygon coverage created in ARC/INFO that represents the depth to the top of the Madison Limestone below the land surface, Black Hills, South...

  12. The behavior limestone under explosive load

    Science.gov (United States)

    Orlov, M. Yu; Orlova, Yu N.; Bogomolov, G. N.

    2016-11-01

    Limestone behavior under explosive loading was investigated. The behavior of the limestone by the action of the three types of explosives, including granular, ammonite and emulsion explosives was studied in detail. The shape and diameter of the explosion craters were obtained. The observed fragments after the blast have been classified as large, medium and small fragments. Three full-scale experiments were carried out. The research results can be used as a qualitative test for the approbation of numerical methods.

  13. [Limestone and pyrite-limestone constructed wetlands for treating river water].

    Science.gov (United States)

    Zhang, Jing; Li, Rui-hua; Li, Jie; Hu, Jun-song; Sun, Qian-qian

    2013-09-01

    Polluted river water was treated with limestone and pyrite-limestone subsurface horizontal constructed wetlands. The aims were to know the performance of two wetlands on removal of common pollutants, especially nitrogen and phosphorus, and analyze the actions of these minerals. The relationship between hydraulic retention time and purification performance of two constructed wetlands was studied. The optimal hydraulic retention time for pollutant removal was about 3 d, The average removal efficiency of COD, TN and TP were 51%, 70% and 95%, respectively. With same influent and hydraulic loading, the average removal efficiency of COD, NH4+ -N, TN and TP were 53.93%, 82.13%, 66%, 50.9%, and 51.66%, 77.43%, 72.06%, 97.35% for limestone and pyrite-limestone constructed wetlands, respectively. There were few differences between limestone and pyrite-limestone wetlands on COD removal, but the nitrogen and phosphorus removal of pyrite-limestone constructed wetland was higher than that of limestone constructed wetland. The phosphorus removal of pyrite-limestone wetland was more efficiency and stable, not affected by temperature.

  14. Late Quaternary Tephrostratigraphy of South-Central Chile (~ 38 - 40 °S)

    Science.gov (United States)

    Fontijn, K.; Rawson, H. L.; Van Daele, M. E.; Moernaut, J.; Abarzúa, A. M.; Pyle, D. M.; Mather, T. A.; De Batist, M. A. O.; Moreno-Roa, H.; Naranjo, J. A.

    2014-12-01

    The volcanoes of the Siete Lagos region ("Lake District") in South-Central Chile form part of the Southern Volcanic Zone of the Andes and include some of the most active volcanoes in South America, i.e. Villarrica and Llaima. The Late Quaternary (~ last 15 ka) regional tephrostratigraphic record for this region is however still poorly developed. We combine detailed stratigraphic logging of terrestrial sections in the vicinity of Llaima, Sollipulli, Villarrica, Quetrupillan, Mocho-Choshuenco and Puyehue-Cordón Caulle volcanoes with petrological, whole-rock and glass geochemical data, and 14C dating on charcoal entrained in volcanic deposits, and correlate the on-land sequences with tephra layers in existing 14C-dated lacustrine records of Laguna Las Ranas and Lagos Villarrica, Calafquén and Riñihue. The combined record includes previously described major eruptions, e.g. Llaima Pumice (Llaima) and Alpehue Pumice (Sollipulli), which help to constrain the relative timing of events. These correlations suggest that several widespread volcanic units are several hundreds to thousands of years older than previously thought. The record also includes newly described pumice-producing events, e.g. for the poorly studied Quetrupillan volcano, and provides new insights into the post-glacial eruptive frequency in the Southern Volcanic Zone. The newly updated stratigraphy with high-quality geochemical data also contributes to the regional tephrochronological framework which helps to significantly improve age models for lacustrine palaeoseismological and palaeoenvironmental archives.

  15. Modeling water quality, temperature, and flow in Link River, south-central Oregon

    Science.gov (United States)

    Sullivan, Annett B.; Rounds, Stewart A.

    2016-09-09

    The 2.1-km (1.3-mi) Link River connects Upper Klamath Lake to the Klamath River in south-central Oregon. A CE-QUAL-W2 flow and water-quality model of Link River was developed to provide a connection between an existing model of the upper Klamath River and any existing or future models of Upper Klamath Lake. Water-quality sampling at six locations in Link River was done during 2013–15 to support model development and to provide a better understanding of instream biogeochemical processes. The short reach and high velocities in Link River resulted in fast travel times and limited water-quality transformations, except for dissolved oxygen. Reaeration through the reach, especially at the falls in Link River, was particularly important in moderating dissolved oxygen concentrations that at times entered the reach at Link River Dam with marked supersaturation or subsaturation. This reaeration resulted in concentrations closer to saturation downstream at the mouth of Link River.

  16. Paleozoogeography of the Wine Mouse (Akodon oenos & Late Holocene Paleoenvironments in South-Central Mendoza, Argentina

    Directory of Open Access Journals (Sweden)

    Fernando Julián Fernández

    2011-02-01

    Full Text Available Cranial remains of the wine mouse (Akodon oenos are documented from an archaeological site in south-central Mendoza, Argentina (Agua de La Mula, 35º22' S, 68º15' W, which dates to the end of the late Holocene (1610 ± 60; 1260 ± 60; 1000 ± 50 C14 yr B.P.. The taxonomic status of this small rodent is currently being assessed, but these remains represent the first fossil record for the morphotaxon A. oenos. The species’ present distribution is restricted to a few records from Mendoza province. Analysis of the remains supports paleoenvironmental reconstruction using the small mammal assemblage recovered from this site. From the late Holocene into modernity temperature decreased and winter precipitation increased, resulting in advance of Patagonian steppe grading with altitude into Monte desert. Holocene climatic conditions may explain the relatively late human occupation of ecologically marginal environments in this region, which probably favored effective human occupation of the Payunia region at sites such as Agua de La Mula between 1600 and 1000 years B.P.

  17. Reservoir assessment of the Nubian sandstone reservoir in South Central Gulf of Suez, Egypt

    Science.gov (United States)

    El-Gendy, Nader; Barakat, Moataz; Abdallah, Hamed

    2017-05-01

    The Gulf of Suez is considered as one of the most important petroleum provinces in Egypt and contains the Saqqara and Edfu oil fields located in the South Central portion of the Gulf of Suez. The Nubian sandstone reservoir in the Gulf of Suez basin is well known for its great capability to store and produce large volumes of hydrocarbons. The Nubian sandstone overlies basement rocks throughout most of the Gulf of Suez region. It consists of a sequence of sandstones and shales of Paleozoic to Cretaceous age. The Nubian sandstone intersected in most wells has excellent reservoir characteristics. Its porosity is controlled by sedimentation style and diagenesis. The cementation materials are mainly kaolinite and quartz overgrowths. The permeability of the Nubian sandstone is mainly controlled by grain size, sorting, porosity and clay content especially kaolinite and decreases with increase of kaolinite. The permeability of the Nubian Sandstone is evaluated using the Nuclear Magnetic Resonance (NMR technology) and formation pressure data in addition to the conventional logs and the results were calibrated using core data. In this work, the Nubian sandstone was investigated and evaluated using complete suites of conventional and advanced logging techniques to understand its reservoir characteristics which have impact on economics of oil recovery. The Nubian reservoir has a complicated wettability nature which affects the petrophysical evaluation and reservoir productivity. So, understanding the reservoir wettability is very important for managing well performance, productivity and oil recovery.

  18. Cave-dwelling bats (Mammalia: Chiroptera and conservation concerns in South central Mindanao, Philippines

    Directory of Open Access Journals (Sweden)

    Krizler C. Tanalgo

    2015-12-01

    Full Text Available The stable microclimate in caves provides a relatively constant habitat for many bat species in the Philippines, but human encroachment continues to disrupt this habitat and imperil many of the species roosting in the caves.  In South central Mindanao, the diversity and conservation status of cave bats remain undocumented and unexplored.  We employed mist-netting to capture bats from five different caves within the town of Kabacan, northern Cotabato, Philippines.  A total of 14 bat species were identified including the Philippine endemics Hipposideros pygmaeus and Ptenochirus jagori and the threatened Megaerops wetmorei. However, despite the declining conservation status of the bats, local disturbance such as bat hunting for bush meat and unregulated tourism are currently taking place in the caves.  Large species such as Eonycteris spelaea and Rousettus amplexicaudatus are killed almost every day for food and trade.  Therefore, the high species richness, and the presence of endemic and threatened species coupled with the occurrence of anthropogenic disturbances in caves suggests the need for an urgent and effective conservation intervention involving the local government and public community. 

  19. [Regional differences of inputs of organic matter and chemical fertilizer in South Central China].

    Science.gov (United States)

    Liu, Huan-yao; Wu, Jin-shui; Zhou, Jiao-gen; Xiao, He-ai; Zhou, Ping

    2015-09-01

    This article analyzed the inputs of organic matter and chemical fertilizer in the cropland of South Central China, i.e., Hunan, Hubei, Guangdong and Guangxi, and then calculated the budgets of nitrogen (N), phosphorus (P) and potassium (K), based on the data from field investigations and peasant household surveys in the four provinces. The results showed that total amounts of organic matter inputs in the four provinces was ranked as follow: 8993 kg · hm(-2) in Guangxi, 6390 kg · hm(-2) in Hunan, 5012 kg · hm(-2) in Hubei, 4630 kg · hm(-2) in Guangdong, and average NPK inputs in the four provinces were ranked as follow: 777.5 kg · hm(-2) in Guangxi, 501.6 kg · hm(-2) in Hunan, 486.4 kg · hm(-2) in Hubei, 340.4 kg · hm(-2) in Guangdong. The N and P input surpluses were greatest in Guangxi (67.2% and 99.0% as for N and P, respectively) , followed by Hunan (33.2% and 50.8%), Hubei (11.8% and 11.0%), and Guangdong (7.8% and 30.0%). However, K input was deficient in Hunan, Hubei, and Guangdong (6.6%, 18.7% and 12.4%), but surplus in Guangxi (19.5%).

  20. Mid-Holocene Sector Collapse at Mount Spurr Volcano, South-Central Alaska

    Science.gov (United States)

    Waythomas, Christopher F.

    2007-01-01

    Radiocarbon-dated volcanic mass-flow deposits on the southeast flank of Mount Spurr in south-central Alaska provide strong evidence for the timing of large-scale destruction of the south flank of the volcano by sector collapse at 4,769^ndash;4,610 yr B.P. The sector collapse created an avalanche caldera and produced an ~1-km3-volume clay-rich debris avalanche that flowed into the glacially scoured Chakachatna River valley, where it transformed into a lahar that extended an unknown distance beyond the debris avalanche. Hydrothermal alteration, an unbuttressed south flank of the volcano, and local structure have been identified as plausible factors contributing to the instability of the edifice. The sector collapse at Mount Spurr is one of the later known large-volume (>1 km,sup>3) flank failures recognized in the Aleutian Arc and one of the few known Alaskan examples of transformation of a debris avalanche into a lahar.

  1. Geologic map of the Alamosa 30’ × 60’ quadrangle, south-central Colorado

    Science.gov (United States)

    Thompson, Ren A.; Shroba, Ralph R.; Michael N. Machette,; Fridrich, Christopher J.; Brandt, Theodore R.; Cosca, Michael A.

    2015-10-15

    The Alamosa 30'× 60' quadrangle is located in the central San Luis Basin of southern Colorado and is bisected by the Rio Grande. The Rio Grande has headwaters in the San Juan Mountains of Colorado and ultimately discharges into the Gulf of Mexico 3,000 kilometers (km) downstream. Alluvial floodplains and associated deposits of the Rio Grande and east-draining tributaries, La Jara Creek and Conejos River, occupy the north-central and northwestern part of the map area. Alluvial deposits of west-draining Rio Grande tributaries, Culebra and Costilla Creeks, bound the Costilla Plain in the south-central part of the map area. The San Luis Hills, a northeast-trending series of flat-topped mesas and hills, dominate the landscape in the central and southwestern part of the map and preserve fault-bound Neogene basin surfaces and deposits. The Precambrian-cored Sangre de Cristo Mountains rise to an elevation of nearly 4,300 meters (m), almost 2,000 m above the valley floor, in the eastern part of the map area. In total, the map area contains deposits that record surficial, tectonic, sedimentary, volcanic, magmatic, and metamorphic processes over the past 1.7 billion years.

  2. Breeding ecology of Wandering Tattlers Tringa incana: a study from south-central Alaska

    Science.gov (United States)

    Gill, Robert; Tomkovich, Pavel S.; Dementyev, Maksim N.

    2015-01-01

    Montane-nesting shorebirds are arguably the least studied of the Charadriiformes, owing in part to the remoteness of their breeding areas, low nesting densities, and specialized behaviors. We studied a marked population of the Wandering Tattler Tringa incana, during a three-year period (1997–1999) on nesting grounds in south-central Alaska. Two aspects of our results stand out. First is the previously undescribed preference for tattlers to nest several kilometers removed from pre-nesting feeding areas, mostly in association with both small (kettle) lakes and running water (near small distributaries of major drainages). Second is the apparent use of the study area by cohorts of birds of different breeding status, including (1) local breeders, which defended pre-breeding foraging areas, (2) local non-breeding birds, which remained on the area but were not territorial, and (3) transients that were captured later in the season, but not seen again on the area during the season of capture. We also found that (1) birds tended to nest in clusters despite what appeared to be the ample availability of nesting habitat, (2) they employed an inconspicuous’ nesting strategy whereby neither member of a pair betrayed its presence on the nesting area, and (3) females departed the area during early chick-rearing, leaving males to tend broods.

  3. Validity of Drought Indices as Drought Predictors in the South-Central United States

    Science.gov (United States)

    Rohli, R. V.; Bushra, N.; Lam, N.; Zou, L.; Mihunov, V.; Reams, M.; Argote, J.

    2015-12-01

    Drought is among the most insidious types of natural disasters and can have tremendous economic and human health impacts. This research analyzes the relationship between two readily-accessible drought indices - the Palmer Drought Severity Index (PDSI) and Palmer Hydrologic Drought Index (PHDI) - and the damage incurred by such droughts in terms of monetary loss, over the 1975-2010 time period on monthly basis, for five states in the south-central U.S.A. Because drought damage in the Spatial Hazards Events and Losses Database for the United States (SHELDUSTM) is reported at the county level, statistical downscaling techniques were used to estimate the county-level PDSI and PHDI. Correlation analysis using the downscaled indices suggests that although relatively few months contain drought damage reports, in general drought indices can be useful predictors of drought damage at the monthly temporal scale extended to 12 months and at the county-wide spatial scale. The varying time lags between occurrence of drought and reporting of damage, perhaps due to varying resilience to drought intensity and duration by crop types across space, irrigation methods, and adaptation measures of the community to drought varies over space and time, are thought to contribute to weakened correlations. These results present a reminder of the complexities of anticipating the effects of drought but they contribute to the effort to improve our ability to mitigate the effects of incipient drought.

  4. Little Ice Age glacial geomorphology and sedimentology of Portage Glacier, South-Central Alaska

    Directory of Open Access Journals (Sweden)

    Carlos Córdova

    2009-06-01

    Full Text Available The study of glacial landforms and deposits is important, as it isdifficult to observe processes under modern glaciers and ice-sheets. Thus landscapes and sediments that are the product of present glaciation can give insight into processes that occurred during Pleistocene times. This study investigates the genesis of little ice age glacial landforms present in Portage Glacier, South-Central Alaska. The present day moraine morphology and sedimentology in Portage Glacier valley reveals the presence of two types of till and moraines. The clast-rich sandy diamicton present on the 1852 moraine is interpreted to be a basal till indicating this feature is a pushmoraine representing an advance or a standstill position of Portage Glacier in 1852. The moderately sorted gray sandy boulder gravel present on the 1900 and 1922 moraines is interpreted to be an ice-marginal deposit (ablation till with a mixture of supraglacial and glaciofluvial sediments deposited by slumping and stream sortingprocesses. All of these features are interpreted to be ablation moraines representing glacier retreat and moraine building in 1900 and1922.

  5. Wisconsinan and Sangamonian climate interpreted from fossil ostracodes and vegetation in south-central Illinois

    Energy Technology Data Exchange (ETDEWEB)

    Curry, B.B. (Illinois State Geological Survey, Champaign, IL (United States)); Forester, R.M. (Geological Survey, Denver, CO (United States)); Zhu, Hong; Baker, R.G. (Univ. of Iowa, Iowa City, IA (United States). Dept. of Geology)

    1992-01-01

    The interpretation of paleoclimate during the late Illinoian, Sangamonian, and Wisconsinan Ages in the region of present south-central Illinois has been based on plant macrofossil, pollen, and vertebrate records. The ostracode records identify periods of flow across the basins and perhaps characteristics of groundwater discharge or recharge. Basins with the largest lake-to-catchment-area ratio were most sensitive to changes in effective moisture and hydrochemistry. The Sangamonian included three intervals during which the winters were warmer than those of historical record. These intervals are represented by sediment containing relatively abundant arboreal pollen, notably bald cypress and sweet gum, and the ostracode Heterocypris punctata, which lives in subtropical to tropical lakes and estuaries. H. punctata occurs with other ostracodes that require low salinity; their association indicates that precipitation typically exceeded evaporation and that the basin was affected by throughflow. The Sangamonian ended with two warm, wet episodes that sandwich an interval implying prairie lake conditions. Warmth-loving species are abundantly represented in upper Sangamonian sediments. Such warm, wet episodes are not known to have occurred in the Midcontinent during the Holocene. The top of the Sangamonian in all except the Pittsburgh Basin is capped by a layer of reworked sediment containing fluvial ostracodes and exotic mixtures of pollen, including both spruce and sweet gum but dominated by chenopods. The reworked layer is overlain by Wisconsinan sediment containing abundant pollen of boreal taxa and ostracodes that indicate basin throughflow.

  6. Greenhouse gas fluxes of a shallow lake in south-central North Dakota, USA

    Science.gov (United States)

    Tangen, Brian; Finocchiaro, Raymond; Gleason, Robert A.; Dahl, Charles F.

    2016-01-01

    Greenhouse gas (GHG) fluxes of aquatic ecosystems in the northern Great Plains of the U.S. represent a significant data gap. Consequently, a 3-year study was conducted in south-central North Dakota, USA, to provide an initial estimate of GHG fluxes from a large, shallow lake. Mean GHG fluxes were 0.02 g carbon dioxide (CO2) m−2 h−1, 0.0009 g methane (CH4) m−2 h−1, and 0.0005 mg nitrous oxide (N2O) m−2 h−1. Fluxes of CO2 and CH4 displayed temporal and spatial variability which is characteristic of aquatic ecosystems, while fluxes of N2O were consistently low throughout the study. Comparisons between results of this study and published values suggest that mean daily fluxes of CO2, CH4, and N2O fromLong Lakewere low, particularly when compared to the well-studied prairie pothole wetlands of the region. Similarly, cumulative seasonal CH4 fluxes, which ranged from 2.68–7.58 g CH4 m−2, were relatively low compared to other wetland systems of North America. The observed variability among aquatic ecosystems underscores the need for further research.

  7. Adapting natural resource management to climate change: The South Central Oregon and Northern Rockies Adaptation Partnerships

    Science.gov (United States)

    Halofsky, J.; Peterson, D. L.

    2015-12-01

    Concrete ways to adapt to climate change are needed to help natural resource managers take the first steps to incorporate climate change into management and take advantage of opportunities to balance the negative effects of climate change. We recently initiated two science-management climate change adaptation partnerships, one with three national forests and one national park in south central Oregon, and the other with 16 national forests, three national parks and other stakeholders in the northern Rockies region. Goals of both partnerships were to: (1) synthesize published information and data to assess the exposure, sensitivity, and adaptive capacity of key resource areas, including water use, infrastructure, fisheries, and vegetation and disturbance; (2) develop science-based adaptation strategies and tactics that will help to mitigate the negative effects of climate change and assist the transition of biological systems and management to a warmer climate; (3) ensure adaptation strategies and tactics are incorporated into relevant planning documents; and (4) foster an enduring partnership to facilitate ongoing dialogue and activities related to climate change in the partnerships regions. After an initial vulnerability assessment by agency and university scientists and local resource specialists, adaptation strategies and tactics were developed in a series of scientist-manager workshops. The final vulnerability assessments and adaptation actions are incorporated in technical reports. The partnerships produced concrete adaptation options for national forest and other natural resource managers and illustrated the utility of place-based vulnerability assessments and scientist-manager workshops in adapting to climate change.

  8. Concentrations of Selected Pharmaceuticals and Antibiotics in South-Central Pennsylvania Waters, March through September 2006

    Science.gov (United States)

    Loper, Connie A.; Crawford, J. Kent; Otto, Kim L.; Manning, Rhonda L.; Meyer, Michael T.; Furlong, Edward T.

    2007-01-01

    This report presents environmental and quality-control data from analyses of 15 pharmaceutical and 31 antibiotic compounds in water samples from streams and wells in south-central Pennsylvania. The analyses are part of a study by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP) to define concentrations of selected emerging contaminants in streams and well water in Pennsylvania. Sampling was conducted at 11 stream sites and at 6 wells in 9 counties of south-central Pennsylvania. Five of the streams received municipal wastewater and 6 of the streams received runoff from agricultural areas dominated by animal-feeding operations. For all 11 streams, samples were collected at locations upstream and downstream of the municipal effluents or animal-feeding operations. All six wells were in agricultural settings. A total of 120 environmental samples and 21 quality-control samples were analyzed for the study. Samples were collected at each site in March/April, May, July, and September 2006 to obtain information on changes in concentration that could be related to seasonal use of compounds. For streams, 13 pharmaceuticals and 11 antibiotics were detected at least 1 time. Detections included analytical results that were estimated or above the minimum reporting limits. Seventy-eight percent of all detections were analyzed in samples collected downstream from municipal-wastewater effluents. For streams receiving wastewater effluents, the pharmaceuticals caffeine and para-xanthine (a degradation product of caffeine) had the greatest concentrations, 4.75 ug/L (micrograms per liter) and 0.853 ug/L, respectively. Other pharmaceuticals and their respective maximum concentrations were carbamazepine (0.516 ug/L) and ibuprofen (0.277 ug/L). For streams receiving wastewater effluents, the antibiotic azithromycin had the greatest concentration (1.65 ug/L), followed by sulfamethoxazole (1.34 ug/L), ofloxacin (0.329 ug

  9. Well log and 2D seismic data character of the Wilcox Group in south-central Louisiana

    Science.gov (United States)

    Enomoto, Catherine B.

    2014-01-01

    Well logs and 2D seismic data were used to interpret the depth and morphology of potential Paleocene and lower Eocene Wilcox Group slope and basin-floor reservoirs in south-central Louisiana. These may occur in a poorly explored area previously estimated by the U.S. Geological Survey to contain a mean undiscovered conventional resource potential of 26,398 billion cubic feet of gas and 423 million barrels of natural gas liquids.

  10. Dental caries among children visiting a mobile dental clinic in South Central Kentucky: a pooled cross-sectional study

    OpenAIRE

    2013-01-01

    Background Dental caries is one of the most common chronic childhood diseases affecting a large portion of children in the United States. The prevalence of childhood dental caries in Kentucky is among the highest in the nation. The purposes of this study are to (1) compare sociodemographic differences between caries and no caries groups and (2) investigate factors associated with untreated dental caries among children who visited a mobile dental clinic in South Central Kentucky. Methods Study...

  11. Assessment of undiscovered oil and gas resources of the Cook Inlet region, south-central Alaska, 2011

    Science.gov (United States)

    Stanley, Richard G.; Charpentier, Ronald R.; Cook, Troy A.; Houseknecht, David W.; Klett, Timothy R.; Lewis, Kristen A.; Lillis, Paul G.; Nelson, Philip H.; Phillips, Jeffrey D.; Pollastro, Richard M.; Potter, Christopher J.; Rouse, William A.; Saltus, Richard W.; Schenk, Christopher J.; Shah, Anjana K.; Valin, Zenon C.

    2011-01-01

    The U.S. Geological Survey (USGS) recently completed a new assessment of undiscovered, technically recoverable oil and gas resources in the Cook Inlet region of south-central Alaska. Using a geology-based assessment methodology, the USGS estimates that mean undiscovered volumes of nearly 600 million barrels of oil, about 19 trillion cubic feet of natural gas, and 46 million barrels of natural gas liquids remain to be found in this area.

  12. Drought-induced sulphate release from a wetland in south-central Ontario.

    Science.gov (United States)

    Eimers, M Catherine; Watmough, Shaun A; Buttle, James M; Dillon, Peter J

    2007-04-01

    Increased sulphate (SO(4)) export from wetlands following summer droughts in central Ontario, Canada has been associated with the delayed chemical recovery of downstream surface waters following decreased sulphur (S) emissions. Prolonged summer droughts result in a decrease or cessation of stream flow, declines in wetland water table level and oxidation of reduced S compounds to SO(4), which is subsequently flushed into drainage streams when stream flow resumes. Sulphate input-output budget calculations (1983-1995 and 1999-2001) at a conifer Sphagnum swamp in the Plastic Lake catchment, indicate that SO(4) is retained in most years but is exported on a net basis following particularly severe summer droughts that result in the cessation of stream flow for more than 54 days (95% CI: 41-72 days). Hindcast calculations using long-term (1916-2000) stream discharge records from a nearby station indicate that while droughts occurred frequently in south-central Ontario over the past 85 years, sufficiently dry conditions to cause net SO(4) export occurred in only 18 of the past 85 years, and indicate a cumulative positive SO(4) balance for the swamp (i.e. net SO(4) retention). Furthermore, the S pool at the Plastic Lake swamp has been estimated to be approximately 1500 kg S/ha in the upper 40 cm peat layer, which is large compared to the amount of net SO(4) export that occurs even in years with particularly dry summers (e.g. -43 kg S/ha in 1987/88). Together, these data suggest that the wetland S pool at Plastic Lake has not been depleted by previous droughts and will continue to sustain episodic drought-related SO(4) export for the foreseeable future.

  13. Risk across disciplines: An interdisciplinary examination of water and drought risk in South-Central Oklahoma

    Science.gov (United States)

    Lazrus, H.; Paimazumder, D.; Towler, E.; McPherson, R. A.

    2013-12-01

    Drought is a challenge faced by communities across the United States, exacerbated by growing demands on water resources and climate variability and change. The Arbuckle-Simpson Aquifer (ASA) in south-central Oklahoma, situated in the heart of the Chickasaw Nation, is the state's only sole-source groundwater basin and sustains the Blue River, the state's only free-flowing river. The recent comprehensive hydrological studies of the aquifer indicate the need for sustainable management of the amount of water extracted. However, the question of how to deal with that management in the face of increasing drought vulnerability, diverse demands, and climate variability and change remains. Water management carries a further imperative to be inclusive of tribal and non-tribal interests. To examine this question, we are conducting an investigation of drought risk from multiple disciplines. Anthropological data comes from stakeholder interviews that were designed to investigate conflict over water management by understanding how people perceive risk differently based on different opinions about the structure of the resource, varying levels of trust in authorities, and unequal access to resources. . The Cultural Theory of Risk is used to explain how people view risks as part of their worldviews and why people who hold different worldviews disagree about risks associated with water availability. Meteorological analyses of longitudinal data indicate periods of drought that are noted in stakeholder interviews. Analysis of stream gauge data investigates the influence of climate variability on local hydrologic impacts, such as changing groundwater levels and streamflows, that are relevant to planning and management decisions in the ASA. Quantitative assessment of future drought risk and associated uncertainty and their effect on type and scale of future economic and social impacts are achieved by combining elements of statistical and dynamical downscaling to improve predictions of

  14. Micro and Macroscale Drivers of Nutrient Concentrations in Urban Streams in South, Central and North America

    Science.gov (United States)

    Loiselle, Steven A.; Gasparini Fernandes Cunha, Davi; Shupe, Scott; Valiente, Elsa; Rocha, Luciana; Heasley, Eleanore; Belmont, Patricia Pérez; Baruch, Avinoam

    2016-01-01

    Global metrics of land cover and land use provide a fundamental basis to examine the spatial variability of human-induced impacts on freshwater ecosystems. However, microscale processes and site specific conditions related to bank vegetation, pollution sources, adjacent land use and water uses can have important influences on ecosystem conditions, in particular in smaller tributary rivers. Compared to larger order rivers, these low-order streams and rivers are more numerous, yet often under-monitored. The present study explored the relationship of nutrient concentrations in 150 streams in 57 hydrological basins in South, Central and North America (Buenos Aires, Curitiba, São Paulo, Rio de Janeiro, Mexico City and Vancouver) with macroscale information available from global datasets and microscale data acquired by trained citizen scientists. Average sub-basin phosphate (P-PO4) concentrations were found to be well correlated with sub-basin attributes on both macro and microscales, while the relationships between sub-basin attributes and nitrate (N-NO3) concentrations were limited. A phosphate threshold for eutrophic conditions (>0.1 mg L-1 P-PO4) was exceeded in basins where microscale point source discharge points (eg. residential, industrial, urban/road) were identified in more than 86% of stream reaches monitored by citizen scientists. The presence of bankside vegetation covaried (rho = –0.53) with lower phosphate concentrations in the ecosystems studied. Macroscale information on nutrient loading allowed for a strong separation between basins with and without eutrophic conditions. Most importantly, the combination of macroscale and microscale information acquired increased our ability to explain sub-basin variability of P-PO4 concentrations. The identification of microscale point sources and bank vegetation conditions by citizen scientists provided important information that local authorities could use to improve their management of lower order river

  15. Moisture concentration variation of silages produced on commercial farms in the South-central USA.

    Science.gov (United States)

    Han, K J; Pitman, W D; Chapple, A

    2014-10-01

    Preservation of forage crops as silage offers opportunity to avoid the high risk of rain-damaged hay in the humid south-central USA. Recent developments with baled silage or baleage make silage a less expensive option than typical chopped silage. Silage has been important in the region primarily for dairy production, but baleage has become an option for the more extensive beef cattle industry in the region. Silage samples submitted to the Louisiana State University Agricultural Center Forage Quality Lab from 2006 through 2013 were assessed for dry matter (DM) and forage nutritive characteristics of chopped silage and baleage of the different forage types from commercial farms primarily in Louisiana and Mississippi. Of the 1,308 silage samples submitted, 1,065 were annual ryegrass (AR) with small grains (SG), the warm-season annual (WA) grasses, sorghums and pearl millet, and the warm-season perennial (WP) grasses, bermudagrass and bahiagrass, providing the remaining samples. Concentration of DM was used to indicate an effective ensiling opportunity, and AR silage was more frequently within the target DM range than was the WA forage group. The AR samples also indicated a high-quality forage with average crude protein (CP) of 130 g/kg and total digestible nutrient (TDN) near 600 g/kg. The cooler winter weather at harvest apparently complicated harvest of SG silage with chopped SG silage lower in both CP and TDN (104 and 553 g/kg, respectively) than either AR silage or baleage of SG (137 and 624 g/kg for CP and TDN, respectively). The hot, humid summer weather along with large stems and large forage quantities of the WA grasses and the inherently higher fiber concentration of WP grasses at harvest stage indicate that preservation of these forage types as silage will be challenging, although successful commercial silage samples of each forage type and preservation approach were included among samples of silages produced in the region.

  16. Bias correction of daily precipitation in south-central Chile using NCEP CFSv2

    Science.gov (United States)

    Maass, T.; castro Heredia, L. M.; Suarez, F. I.; Fernandez, B.

    2015-12-01

    Hydroelectric power plant operations are heavily influenced by the streamflow forecasts on their basins. In Chile, these forecasts are based on historical observations. However, this approach has reached its limit of quality and reliability, being difficult to adapt to current weather conditions (climate change), to extreme weather conditions, and to ungauged basins. In this work, we evaluated the bias correction of NCEP-CSv2 daily precipitation with the aim of incorporating this forecast into a real-time hydrological forecasting system. Bias correction was performed using two approaches of the Quantile Mapping (QM) method: a) a polynomial fit (APo) applied to the differences between the forecasted and observed cumulative distribution functions (CDFs) for the training period; and b) using a Gamma probability distribution (APb) to fit the forecasted and observed CDFs. The bias correction was applied at two locations in south-central Chile: over the valley and in the Andes mountains. To estimate the CDFs and the QM fitting models in the training period, historical records and data from the CFSv2 Reforecast model (between 1995 and 2009) were used. The bias correction evaluation was done between 2011 and 2014 with the forecast of the CFSv2 model. The uncorrected CFSv2 results show that the mid-term forecasts (six months) have a high correlation (r>0.5) for the first days of the forecast (2 weeks), but an important underestimation in the observed data from both the valley and the mountain. After applying the bias correction (APo or APb), the errors of the corrected forecasts decrease in relation to the uncorrected CFSv2 forecasts, with a noticeable improvement for the first forecasted days (being the APo errors lower than those of the APb). In the long term, and as might be expected, the errors increase: the peak precipitation is underestimated and the null rainfall is overestimated.

  17. Shrubline but not treeline advance matches climate velocity in montane ecosystems of south-central Alaska.

    Science.gov (United States)

    Dial, Roman J; Smeltz, T Scott; Sullivan, Patrick F; Rinas, Christina L; Timm, Katriina; Geck, Jason E; Tobin, S Carl; Golden, Trevor S; Berg, Edward C

    2016-05-01

    Tall shrubs and trees are advancing into many tundra and wetland ecosystems but at a rate that often falls short of that predicted due to climate change. For forest, tall shrub, and tundra ecosystems in two pristine mountain ranges of Alaska, we apply a Bayesian, error-propagated calculation of expected elevational rise (climate velocity), observed rise (biotic velocity), and their difference (biotic inertia). We show a sensitive dependence of climate velocity on lapse rate and derive biotic velocity as a rigid elevational shift. Ecosystem presence identified from recent and historic orthophotos ~50 years apart was regressed on elevation. Biotic velocity was estimated as the difference between critical point elevations of recent and historic logistic fits divided by time between imagery. For both mountain ranges, the 95% highest posterior density of climate velocity enclosed the posterior distributions of all biotic velocities. In the Kenai Mountains, mean tall shrub and climate velocities were both 2.8 m y(-1). In the better sampled Chugach Mountains, mean tundra retreat was 1.2 m y(-1) and climate velocity 1.3 m y(-1). In each mountain range, the posterior mode of tall woody vegetation velocity (the complement of tundra) matched climate velocity better than either forest or tall shrub alone, suggesting competitive compensation can be important. Forest velocity was consistently low at 0.1-1.1 m y(-1), indicating treeline is advancing slowly. We hypothesize that the high biotic inertia of forest ecosystems in south-central Alaska may be due to competition with tall shrubs and/or more complex climate controls on the elevational limits of trees than tall shrubs. Among tall shrubs, those that disperse farthest had lowest inertia. Finally, the rapid upward advance of woody vegetation may be contributing to regional declines in Dall's sheep (Ovis dalli), a poorly dispersing alpine specialist herbivore with substantial biotic inertia due to dispersal reluctance.

  18. Anaemia among children in a drought affected community in south-central Ethiopia.

    Science.gov (United States)

    Gari, Taye; Loha, Eskindir; Deressa, Wakgari; Solomon, Tarekegn; Atsbeha, Hanibale; Assegid, Meselech; Hailu, Alemayehu; Lindtjørn, Bernt

    2017-01-01

    As part of a field trial (PACTR201411000882128) to provide evidence on the combined use of long-lasting insecticidal nets and indoor residual spray for malaria prevention, we measured haemoglobin values among children aged 6 to 59 months. The aim of this study was to estimate the prevalence of anaemia, and to determine the risk factors of anaemia and change in haemoglobin value in Adami Tullu district in south-central Ethiopia. Repeated cross-sectional surveys among 2984 children in 2014 and 3128 children in 2015; and a cohort study (malaria as exposure and anaemia as outcome variable) were conducted. The study area faced severe drought and food shortages in 2015. Anaemia was diagnosed using HemoCue Hb 301, and children with haemoglobin anaemia. The prevalence of anaemia was 28.2% [95% Confidence Interval (CI), 26.6-29.8] in 2014 and increased to 36.8% (95% CI, 35.1-38.5) in 2015 (Panaemia was 30; (95% CI, 28-32) cases per 100 children years of observation. The risk of anaemia was high (adjusted Hazard Ratio = 10) among children with malaria. Children from poor families [Adjusted Odds Ratio (AOR); 1.3; 95% CI, 1.1-1.6)], stunted children (AOR 1.5; 95% CI; 1.2-1.8), and children aged less than 36 months (AOR; 2.0; 95% CI, 1.6-2.4) were at risk of anaemia compared to their counterparts. There was no significant difference in risk of anaemia among the trial arms. Young age, stunting, malaria and poverty were the main predictors of anaemia. An increase in the prevalence of anaemia was observed over a year, despite malaria prevention effort, which could be related to the drought and food shortage. Therefore, conducting trials in settings prone to drought and famine may bring unexpected challenges.

  19. Spring-migration ecology of Northern Pintails in south-central Nebraska

    Science.gov (United States)

    Pearse, Aaron T.; Krapu, Gary L.; Cox, Robert R.; Davis, Bruce E.

    2011-01-01

    Spring-migration ecology of staging Northern Pintails, Anas acuta, was investigated in south-central Nebraska, USA. Habitat associations, local movements, settling patterns, arrival dates, residency times and survival were estimated from 71 radiomarked pintails during spring 2001, 2003 and 2004, and diet determined from 130 females collected during spring 1998 and 1999. Seventy-two percent of pintail diurnal locations were in palustrine wetlands, 7% in riverine wetlands, 3% in lacustrine wetlands, 6% in municipal sewage lagoons and irrigation reuse pits and 10.5% in croplands. Emergent wetlands with hemi-marsh conditions were used diurnally more often than wetlands with either open or closed vegetation structures. Evening foraging flights averaged 4.3 km (SE = 0.6) and 72% were to cornfields. In accord with these findings, 87% of 93 pintails collected during spring 1998 and 1999 returning to evening roosts consumed corn, which represented 84% dry mass of all foods. Pintails collected on non-cropped wetlands ingested invertebrates and seeds from wetland plants more frequently than birds returning to roost. Radiomarked pintails arrived in Nebraska on 7 March 2003 and 18 February 2004; average arrival date was six days earlier during 2004 compared to 2003. Residency time for individuals varied greatly (1–40 days) yet yearly means were similar and averaged 9.5 days within the region. No mortality was detected for 71 birds monitored over 829 exposure days. Conservation planners linking population dynamics and habitat conditions at spring-staging areas need to focus on pintail body condition during spring and its connection with reproductive success and survival during the breeding season.

  20. Coastal lake sediments reveal 5500 years of tsunami history in south central Chile

    Science.gov (United States)

    Kempf, Philipp; Moernaut, Jasper; Van Daele, Maarten; Vandoorne, Willem; Pino, Mario; Urrutia, Roberto; De Batist, Marc

    2017-04-01

    We present an exceptionally long and continuous coastal lacustrine record of ∼5500 years from Lake Huelde on the west coast of Chiloé Island in south central Chile. The study area is located within the rupture zone of the giant 1960 CE Great Chilean Earthquake (MW 9.5). The subsequent earthquake-induced tsunami inundated Lake Huelde and deposited mud rip-up clasts, massive sand and a mud cap in the lake. Long sediment cores from 8 core sites within Lake Huelde reveal 16 additional sandy layers in the 5500 year long record. The sandy layers share sedimentological similarities with the deposit of the 1960 CE tsunami and other coastal lake tsunami deposits elsewhere. On the basis of general and site-specific criteria we interpret the sandy layers as tsunami deposits. Age-control is provided by four different methods, 1) 210Pb-dating, 2) the identification of the 137Cs-peak, 3) an infrared stimulated luminescence (IRSL) date and 4) 22 radiocarbon dates. The ages of each tsunami deposit are modelled using the Bayesian statistic tools of OxCal and Bacon. The record from Lake Huelde matches the 8 regionally known tsunami deposits from documented history and geological evidence from the last ∼2000 years without over- or underrepresentation. We extend the existing tsunami history by 9 tsunami deposits. We discuss the advantages and disadvantages of various sedimentary environments for tsunami deposition and preservation, e.g. we find that Lake Huelde is 2-3 times less sensitive to relative sea-level change in comparison to coastal marshes in the same region.

  1. Prevalence of malaria infection in Butajira area, south-central Ethiopia

    Directory of Open Access Journals (Sweden)

    Woyessa Adugna

    2012-03-01

    Full Text Available Abstract Background In 2005, the Ethiopian government launched a massive expansion of the malaria prevention and control programme. The programme was aimed mainly at the reduction of malaria in populations living below 2,000 m above sea level. Global warming has been implicated in the increase in the prevalence of malaria in the highlands. However, there is still a paucity of information on the occurrence of malaria at higher altitudes. The objective of this study was to estimate malaria prevalence in highland areas of south-central Ethiopia, designated as the Butajira area. Methods Using a multi-stage sampling technique, 750 households were selected. All consenting family members were examined for malaria parasites in thick and thin blood smears. The assessment was repeated six times for two years (October 2008 to June 2010. Results In total, 19,207 persons were examined in the six surveys. From those tested, 178 slides were positive for malaria, of which 154 (86.5% were positive for Plasmodium vivax and 22 (12.4% for Plasmodium falciparum; the remaining two (1.1% showed mixed infections of Plasmodium falciparum and Plasmodium vivax. The incidence of malaria was higher after the main rainy season, both in lower lying and in highland areas. The incidence in the highlands was low and similar for all age groups, whereas in the lowlands, malaria occurred mostly in those of one to nine years of age. Conclusion This study documented a low prevalence of malaria that varied with season and altitudinal zone in a highland-fringe area of Ethiopia. Most of the malaria infections were attributable to Plasmodium vivax.

  2. Interseismic strain accumulation in seismic gap of south central Chile from GPS measurements

    Science.gov (United States)

    Rudloff, A.; Vigny, C.; Ruegg, J. C.; Campos, J.

    2003-04-01

    Three campaigns of Global Positioning System (GPS) measurements were carried out in the Concepcion-Constitucion seismic gap in South Central Chile in 1996, 1999, and 2002. We observed a network of about 40 sites, made of 2 east-west transects roughly perpendicular to the trench ranging from the coastal area to the Argentina border and 1 north-south profile along the coast. Data sets were processed with MIT's GAMIT/GLOBK package. Horizontal velocities have formal uncertainties around 1 to 2 mm/yr in average. Vertical velocities are also determined and have uncertainties around 2 to 5 mm/yr. We find that the convergence between Nazca and South-America plates better matches the pole previously estimated by (Larson et al, 1997) than the Nuvel-1A estimate. Our estimate predicts a convergence of 72 mm/yr at N70 to be compared with Nuvel-1A 80 mm/yr at N79. With respect to stable South America, horizontal velocities decrease from 35 mm/yr on the coast to 14 mm/yr in the Cordillera. Vertical velocities help constraint lithospheric flecture. Partionning of the slightly oblique convergence will be investigated. The gradient of convergent parallel velocities reflects aseismic elastic loading on a zone of about 400 km width. Interestingly enough, this gradient exhibit a linear pattern, marginally compatible with the expected arctangent shape. 70 mm/yr of motion accumulated since the last big event in this area (1835 Earthquake described by Darwin) represent more than 10 m of displacement. Therefore, this area is probably mature for a next large earthquake, the magnitude of which could reach 8.5.

  3. Storm deposits (tempestites) in Ordovician cratonic carbonates (Arbuckle Group, south-central Oklahoma)

    Energy Technology Data Exchange (ETDEWEB)

    Goldhammer, R.K.; Elmore, R.D.

    1983-03-01

    The Early Ordovician Kindblade Formation (Arbuckle Group), exposed in the Arbuckle Mountains of south-central Oklahoma, is a shallow marine epicontinental carbonate sequence that contains numerous storm deposits. The storm deposits (tempestites) are of two types, proximal and distal; the latter dominates in terms of both number and aggregate thickness. Distal tempestites consist of a fining upward sequence, 5 to 50 cm (2 to 20 in.) thick, that overlies an eroded hardground or firmground. The sequence consists of a lag lithoclastic grainstone that grades up into a laminated peloidal grainstone and then into mudstone. Primary sedimentary features such as laminations, burrows, and allochems are truncated at the surfaces, and borings are filled with unsorted lithoclasts. The lithoclasts at the base of the sequence are bored, generally well rounded, discoid in shape, and consist of mudstone, peloidal packstone, and oolitic grainstone. The overlying mudstone is sparsely fossiliferous and bioturbated with burrows either selectively dolomitized or infilled with lithoclastric grainstone. Proximal tempestites consist of coarse lithoclastic flat pebble conglomerate beds approximately 1 m (3.25 ft) thick that are interbedded with ooid grainstone and overlie mudstone. The contact between the units is sharp and erosional. The lithoclasts are of variable composition and may be up to 20 cm (7.75 in.) in diameter. The two types of tempestites occur in crude cycles, which consist of distal deposits overlain by proximal tempestites and ooid grainstones. The abundance of the storm deposits in the section, approximately one every 20 cm (7.75 in.), indicates that hundreds of storm-induced events are recorded in the Kindblade Formation.

  4. Laser Removal of Protective Treatments on Limestone

    Science.gov (United States)

    Gómez-Heras, M.; Rebollar, E.; Alvarez de Buergo, M.; Oujja, M.; Fort, R.; Castillejo, M.

    This work presents an investigation of the laser removal of polymeric materials acting as consolidants and water-repellents on limestone used on buildings of architectural and artistic value. The removal of the consolidant Paraloid B-72 and the water-repellent product Tegosivin HL-100, applied on samples of Colmenarand Bateig limestone, was studied as a function of the laser wavelength, by using the four harmonics of a Q-switched Nd:YAG laser (1064, 532, 355 and 266 nm). Elimination of the coatings and subsequent surface modifications were monitored through colorimetry, roughness measurements and scanning electron microscopy (SEM). The fundamental laser radiation was effective in removing the treatments, although thermal alteration processes were induced on the calcite crystals of the limestone. The best results were obtained by irradiation in the near UV at 355 nm.

  5. Controls on dryland mountain landscape development along the NW Saharan desert margin: Insights from Quaternary river terrace sequences (Dadès River, south-central High Atlas, Morocco)

    Science.gov (United States)

    Stokes, M.; Mather, A. E.; Belfoul, M.; Faik, F.; Bouzid, S.; Geach, M. R.; Cunha, P. P.; Boulton, S. J.; Thiel, C.

    2017-06-01

    This study documents river terraces from upstream reaches of the Dadès River, a major fluvial system draining the south-central High Atlas Mountains. Terraces occur as straths with bedrock bases positioned at 10 m altitudinal intervals up to 40 m (T1-T5) above the valley floor, becoming less common between 50 and 140 m. The rock strength, stratigraphy and structure of the mountain belt influences terrace distribution. Terraces are absent in river gorges of structurally thickened limestone; whilst well-developed, laterally continuous terraces (T1-T4) form along wide valleys occupying syncline structures dominated by weaker interbedded limestone-mudstone. Terrace staircases develop in confined canyons associated with weaker lithologies and influence from structural dip and stratigraphic configuration. Terraces comprise a bedrock erosion surface overlain by fluvial conglomerates, rare overbank sands and colluvium. This sequence with some OSL/IRSL age control, suggests terrace formation over a 100 ka climate cycle with valley floor aggradation during full glacials and incision during glacial-interglacial transitions. This integrates with other archives (e.g. lakes, glaciers, dunes), appearing typical of landscape development along the NW Saharan margin south of the High Atlas, and similar to patterns in the western-southern Mediterranean. The 100 ka climate cycle relationship suggests that the terrace sequence documents Late-Middle Pleistocene landscape development. Consistent altitudinal spacing of terraces and their distribution throughout the orogen suggests sustained base-level lowering linked to uplift-exhumation of the High Atlas. Low incision rates (<0.2 mm a-1) and general absence of terrace deformation suggests dominance of isostatically driven base-level lowering with relief generation being Early Pleistocene or older.

  6. Potential degradation mechanisms of stylolitic limestones

    Science.gov (United States)

    Aly, Nevin; Török, Ákos; Aguilar Sanchez, Asel Maria; Wangler, Timothy

    2017-04-01

    Stylolites are irregular rough surfaces formed due to the pressure-solution process and commonly developed in carbonate stones. Stylolite formation is usually accompanied by the accumulation of insoluble residues i.e. organic matter, oxides and clays on the stylolitic surfaces. The amount and the type of these clays may play a significant role in the deterioration of the host stone. This study presents the characterization of various stylolitic limestones containing different amounts of clays and used extensively as building cladding and decorative stones in Israel and in Hungary. The first case study focuses on two lithotypes from Israel, both of them are biocalcirudite-calcarenite with high amount of bioclasts. Abundance of open stylolites filled partially with organic matter and minor amounts of clays exist in the first lithotype with cream colour. The second lithotype has grey colour and contains organic matter and pyrite dispersed throughout the stone and more concentrated within the stylolites along with clay and dolomite crystal. Both lithotypes exhibit signs of decay just after a few years of exposure. The first studied Hungarian limestone is a red Jurassic carbonate (ammonitico rosso type) that was formed in pelagic marine environment. This wackestone contains abundant pelagic microfossils. The limestone has been used from Roman period in Central Europe in Hungary, Romania and Poland. The stylolites are seen as darker bedding parallel seams containing minor amounts of clay and hematite. Small amount of clay is also found in isolated nodules. The second Hungarian lithotype is also a Jurassic limestone which contains less clay than the previous one. This yellowish-white limestone is strongly cemented and contains red intersecting stylolites that do not follow the bedding planes or stratification. The main aim of this study is to understand and evaluate the damage mechanism of different stylolitic limestones. Samples were exposed to multiple thermal and wet

  7. Effect of Limestone Fillers the Physic-Mechanical Properties of Limestone Concrete

    Science.gov (United States)

    bederina, Madani; makhloufi, Zoubir; bouziani, Tayeb

    This work focuses on the exploitation of local industrial wastes and their use in the formulation of new concretes which can be used in local constructions. The valorised materials are limestone crushing sand (0/5 mm) and limestone fillers (80 μm). The two materials are extracted from local aggregate crushing wastes. Thus, and since the used gravels are also of limestone nature, the formulated composite is a limestone concrete. So this study constitutes an experimental work that aims at the study of the effect of the addition of limestone fillers on the physico-mechanical behaviour of limestone concrete. To carry out this study, different proportions of fillers ranging from 0 to 40% were considered. Very important results have been achieved on the workability and strength. By increasing the amount of limestone filler in concrete, the first one improves, but the second one increases then decreases passing by an optimal content of fillers which gives a maximum mechanical strength. Finally, and concerning the dimensional variations, it is noteworthy that they decrease at the beginning till an optimal value of fillers content, but beyond this optimum, they start increasing without exceeding recommended values.

  8. Potential role of environmental contaminants in the pathology of beak deformities among Black-capped chickadees in South-central Alaska

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — More than 1,400 individual Black-capped Chickadees (Poecile atricapillus) with beak deformities were recorded in south-central Alaska between 1991 and 2005. Over 200...

  9. Characterization of surface-water quality based on real-time monitoring and regression analysis, Quivira National Wildlife Refuge, south-central Kansas, December 1998 through June 2001

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Because of the considerable wildlife benefits offered by the Quivira National Wildlife Refuge in south-central Kansas, there is a desire to ensure suitable water...

  10. The Research Process on Converter Steelmaking Process by Using Limestone

    Science.gov (United States)

    Tang, Biao; Li, Xing-yi; Cheng, Han-chi; Wang, Jing; Zhang, Yun-long

    2017-08-01

    Compared with traditional converter steelmaking process, steelmaking process with limestone uses limestone to replace lime partly. A lot of researchers have studied about the new steelmaking process. There are much related research about material balance calculation, the behaviour of limestone in the slag, limestone powder injection in converter and application of limestone in iron and steel enterprises. The results show that the surplus heat of converter can meet the need of the limestone calcination, and the new process can reduce the steelmaking process energy loss in the whole steelmaking process, reduce carbon dioxide emissions, and improve the quality of the gas.

  11. Environmental Factors Affecting the Whale Shark Aggregation site in the South Central Red Sea

    KAUST Repository

    Hozumi, Aya

    2015-12-01

    Motivation behind the spring whale shark (Rhincodon typus) aggregation in Al-Lith, on the Saudi Arabian coast of the South Central Red Sea, is uncertain. A plausible hypothesis is that whale sharks gather to feed on high prey density, leading to questions about the cause of the prey density. A bottom-up process fueled by nutrient input or accumulation from physical advection could create a peak in prey biomass. Wastewater discharged from an aquaculture facility could affect productivity or provide a chemosensory cue for whale sharks. Yet, basic physico-biological oceanography of this region is unresolved. Monthly profiles, long-term moorings, and spatial surveys were used to describe the temporal variability of potential prey biomass and water masses in this region for the first time. Plankton abundance of individuals larger than ~0.7 cm did not peak during whale shark season. Rather, a decrease coinciding the trailing end of whale shark detections was observed. Sites 180 m apart had differences in acoustic backscatter, suggesting small-scale biomass patchiness, supporting the small-scale variability in whale shark habitat selectivity. Red Sea Deep Water, a nutrient-rich water mass formed in the northern Red Sea, appeared in July at the same time the Tokar wind jet from the Sudanese mountain gap is the highest. Gulf of Aden Water, a nutrient-rich water mass from the Indian Ocean, arrived as episodes from May to September, contrary to previous expectations that the water arrives continuously. It is unlikely that these natural nutrient sources are directly responsible for the high prey density attracting the whale sharks. The aquaculture plume, observed at the aggregation site, had a distinct seasonality from the ambient waters. The plume’s highest salinity (>48) approached the extreme limits of coral tolerances. Nutrient concentrations (nitrate, nitrite, phosphate, silica), suspended particulate matter, phytoplankton biomass, bacteria and cyanobacteria cell counts

  12. Seismic Attribute Analysis of the Mississippian Chert at the Wellington Field, south-central Kansas

    Science.gov (United States)

    Sirazhiev, Ayrat

    Mississippian chert reservoirs, important hydrocarbon resources in North America, are highly heterogeneous, typically below seismic resolution and, therefore, present a challenging task for predicting reservoir properties from seismic data. In this study, I conducted a seismic attribute analysis of the Mississippian chert reservoir at the Wellington Field, south-central Kansas using well and 3D PSTM seismic data. The microporous cherty dolomite reservoir exhibits a characteristic vertical gradational porosity reduction and associated increase in acoustic velocity, known as a ramp-transition velocity function. I investigated possible relationships of the Mississippian reservoir thickness and porosity with post-stack seismic attributes, including inverted acoustic impedance. The analysis of well-log and seismic data revealed that fault #1 divides the Wellington Field diagonally from the southwestern corner to the northeastern corner. The reservoir in the southeastern part of the field is characterized by a vertical gradational porosity decrease (from 25-30 to 4-6%), variable thickness (6-20 m), lower seismic amplitude and frequency content, locally developed double reflector, and high correlation between seismic amplitude and reservoir thickness conformable with the theoretical amplitude response of a ramp-transition velocity function. Amplitude envelope was used to predict the reservoir thickness in this part of the field. The Mississippian reservoir in the northwestern part of the field has more heterogeneous porosity distribution within the reservoir interval, thins in the north-north-west direction, while no clear relationship was found between reservoir thickness and instantaneous seismic attributes. The model-based inversion and porosity model predicted from inverted impedance supported the well-log and seismic attribute interpretation. The reliability of the predicted porosity model is tested by cross-validation. Resolution limits were determined using wedge

  13. Abundance and dynamics of anopheline larvae in a highland malarious area of south-central Ethiopia.

    Science.gov (United States)

    Animut, Abebe; Gebre-Michael, Teshome; Balkew, Meshesha; Lindtjørn, Bernt

    2012-06-13

    Malaria is a public health problem in Ethiopia, and increasingly so in highland areas, possibly because of global warming. This study describes the distribution, breeding habitat and monthly dynamics of anopheline larvae in Butajira, a highland area in south-central Ethiopia. A study of the abundance and dynamics of Anopheles larvae was undertaken at different sites and altitudes in Butajira from July 2008 to June 2010. The sites included Hobe (1817 m.a.s.l), Dirama (1995m.a.s.l.) and Wurib (2196m.a.s.l.). Potential anopheline larval habitats were surveyed once per month in each village. The recorded characteristics of the habitats included habitat type, pH, surface debris, emergent plants, algae, substrate, turbidity, temperature, length, width, depth, distance to the nearest house and anophelines. The Spearman correlation coefficient and Mann-Whitney U test were used to calculate the degree of association between the density of anopheline species and key environmental factors. Among the different types of habitat surveyed, the Odamo, Akamuja and Assas streams and Beko swamp were positive for anopheline larvae. A total of 3,957 third and fourth instar larvae were collected from the three localities, and they represented ten species of anophelines. These were: Anopheles cinereus (32.5%), An. arabiensis (31.4%), An. chrysti (23%), An. demeilloni (12.2%), An. pretoriensis (0.6%), An. azaniae (0.1%), An. rufipes(0.1%), An. sergentii (0.06%), An. garnhami (0.06%) and An. pharoensis (0.03%). The density of anopheline larvae was highest during the dry months. An. arabiensis was widely distributed, and its density decreased from the lowest elevation in Hobe to the highest in Wurib. The density of An. arabiensis larvae was correlated positively with larval habitat temperature (r = 0.33, p < 0.05) and negatively with depth of larval habitat (r = -0.56, p < 0.05). Ten species of anophelines were identified, including two known vectors of malaria (An

  14. Aeromagnetic interpretation in the south-central Zimbabwe Craton: (reappraisal of) crustal structure and tectonic implications

    Science.gov (United States)

    Ranganai, Rubeni T.; Whaler, Kathryn A.; Ebinger, Cynthia J.

    2016-11-01

    Regional aeromagnetic data from the south-central Zimbabwe Craton have been digitally processed and enhanced for geological and structural mapping and tectonic interpretation integrated with gravity data, to constrain previous interpretations based on tentative geologic maps and provide new information to link these structural features to known tectonic events. The derived maps show excellent correlation between magnetic anomalies and the known geology, and extend lithological and structural mapping to the shallow/near subsurface. In particular, they reveal the presence of discrete crustal domains and several previously unrecognised dykes, faults, and ultramafic intrusions, as well as extensions to others. Five regional structural directions (ENE, NNE, NNW, NW, and WNW) are identified and associated with trends of geological units and cross-cutting structures. The magnetic lineament patterns cut across the >2.7 Ga greenstone belts, which are shown by gravity data to be restricted to the uppermost 10 km of the crust. Therefore, the greenstone belts were an integral part of the lithosphere before much of the upper crustal (brittle) deformation occurred. Significantly, the observed magnetic trends have representatives craton-wide, implying that our interpretation and inferences can be applied to the rest of the craton with confidence. Geological-tectonic correlation suggests that the interpreted regional trends are mainly 2.5 Ga (Great Dyke age) and younger, and relate to tectonic events including the reactivation of the Limpopo Belt at 2.0 Ga and the major regional igneous/dyking events at 1.8-2.0 Ga (Mashonaland), 1.1 Ga (Umkondo), and 180 Ma (Karoo). Thus, their origin is here inferred to be inter- and intra-cratonic collisions and block movements involving the Zimbabwe and Kaapvaal Cratons and the Limpopo Belt, and later lithospheric heating and extension associated with the break-up of Gondwana. The movements produced structures, or reactivated older fractures

  15. Quantifying sediment dynamics on alluvial fans, Iglesia basin, south Central Argentine Andes

    Science.gov (United States)

    Harries, Rebekah; Kirstein, Linda; Whittaker, Alex; Attal, Mikael; Peralta, Silvio

    2017-04-01

    Qualitative interpretations of environmental change drawn from alluvial fan stratigraphy typically tie the deposition of greater volumes of coarser sediment to wetter climatic periods. For example, step changes in sediment flux and discharge associated with glacial-interglacial cycles are often linked to the progradation and back stepping of a fan's toe (Harvey et al, 2002). Indeed, more recent quantitative stratigraphic models demonstrate changes in the volume and calibre of sediment fluxed from an uplifted catchment can produce predictable shifts in the rate at which fluvial deposits fine downstream (Duller et al. 2010, Armitage et al. 2011). These interpretations, however, make three important assumptions: 1) the volume and calibre of the sediment transferred from an eroding mountain belt to a depositional basin is directly related to climate through some value of time-averaged discharge or catchment wetness; 2) lateral sources of sediment, such as tributaries, do not significantly influence the pattern of deposition in a basin and, similarly, 3) the reworking of older fan surfaces is minimal and does not impact the depositional pattern of younger deposits. Here we demonstrate each of these assumptions underestimates the importance of variance in transportable grain sizes in influencing the local and basin-wide deposited grain size trends. Using the Iglesia basin in the Argentine south Central Andes as a natural laboratory, we compare three large, adjacent, alluvial fan systems whose catchments experience the same background tectonic and climatic forcing. We find regional climate forcing is not expressed uniformly in the downstream grain size fining rates of their modern systems. Furthermore, we observe the variance in transportable grain sizes supplied from each primary catchment and the variance of material introduced by tributaries and fan surfaces downstream can act as first order controls on the rate of downstream fining. We also raise the importance of

  16. Stream and aquifer biology of south-central Texas; a literature review, 1973-97

    Science.gov (United States)

    Ourso, R.T.; Hornig, C.E.

    1999-01-01

    This report summarizes in table format 32 aquatic vertebrate (primarily fish), 54 aquatic invertebrate, and 13 aquatic plant studies available for the area of the South-Central Texas study unit of the U.S. Geological Survey National Water-Quality Assessment. The studies, published mostly during 1973?97, pertain to the Guadalupe, San Antonio, and Nueces River Basins, the San Antonio-Nueces and Nueces-Rio Grande Coastal Basins, and the Edwards aquifer where it underlies the upper parts of the three river basins. The biology of the study-unit streams is determined mostly by the characteristics of the ecoregions they transect?the Edwards Plateau, Texas Blackland Prairies, East Central Texas Plains, Western Gulf Coastal Plain, and Southern Texas Plains. About 20 percent of the previous fish and invertebrate studies and about 75 percent of the aquatic plant surveys have centered on Comal Springs in Comal County and San Marcos Springs in Hays County. Although several important studies are available for the San Antonio region, documentation of aquatic biology for the remainder of the study unit is relatively sparse. The streams in the study unit, particularly in the Edwards Plateau, support three dominant biological groups?fish, aquatic invertebrates, and plants. Potential threats to these organisms include impoundments and flood-control projects, siltation from erosion, ground-water pumping, recreational activities, wastewater discharge, and introduction of non-native species. More than 30 non-native fish, invertebrate, and plant species have been introduced into the region. Of the 19 aquatic species Federally listed as endangered or threatened in Texas, 8 are associated with springs and spring runs in the study unit. All of the endangered species in the study unit are associated with springs and spring runs. A large number of endemic species in the study unit are associated with subterranean aquatic ecosystems, most likely a consequence of the unique proximity of the

  17. GREYBULL SANDSTONE PETROLEUM POTENTIAL ON THE CROW INDIAN RESERVATION, SOUTH-CENTRAL MONTANA

    Energy Technology Data Exchange (ETDEWEB)

    David A. Lopez

    2000-12-14

    Evaluation of the Lower Cretaceous Greybull Sandstone on the Crow Indian Reservation for potential stratigraphic traps in the valley-fill sandstone was the focus of this project. The Crow Reservation area, located in south-central Montana, is part of the Rocky Mountain Foreland structural province, which is characterized by Laramide uplifts and intervening structural basins. The Pryor and Bighorn mountains, like other foreland uplifts, are characterized by asymmetrical folds associated with basement-involved reverse faults. The reservation area east of the mountains is on the northwestern flank of the Powder River Basin. Therefore, regional dips are eastward and southeastward; however, several prominent structural features interrupt these regional dips. The nearly 4,000 mi{sup 2} reservation is under explored but has strong potential for increased oil and gas development. Oil and gas production is well established in the Powder River Basin of Wyoming to the south as well as in the areas north and west of the reservation. However, only limited petroleum production has been established within the reservation. Geologic relations and trends indicate strong potential for oil and gas accumulations, but drilling has been insufficient for their discovery. The Greybull Sandstone, which is part of the transgressive systems tract that includes the overlying Fall River Sandstone, was deposited on a major regional unconformity. The erosional surface at the base of the Greybull Sandstone is the +100 Ma, late Aptian-Early Albian regional unconformity of Weimer (1984). This lowstand erosional surface was controlled by a basin-wide drop in sea level. In areas where incised Greybull channels are absent, the lowstand erosional unconformity is at the base of the Fall River Sandstone and equivalent formations. During the pre-Greybull lowstand, sediment bypassed this region. In the subsequent marine transgression, streams began to aggrade and deposit sand of the lower Greybull Sandstone

  18. Hydrological processes and chemical characteristics of low-alpine patterned wetlands, south-central New Zealand

    Science.gov (United States)

    Chagué-Goff, Catherine; Mark, Alan F.; Dickinson, Katharine J. M.

    2010-05-01

    SummaryPatterned wetlands in New Zealand are not only rare, but they are distinguished from their Northern Hemisphere counterparts by their vegetation and the supply of rainfall which is relatively free of pollution. Hydrological processes in two low-alpine patterned wetlands (5 and 220 ha) on block-faulted uplands in south-central South Island, New Zealand were investigated using hydraulic head gradients, and chemical and isotope data. There was no significant spatial variability in chemical parameters within either wetland, although the larger wetland is characterised by a lower trophic status than the smaller one. Ca 2+ concentrations and pH of surface water of both wetlands are within the range of that of Northern Hemisphere ombrotrophic/mesotrophic bogs and poor fens. Pool water chemistry only partially overlaps with the lower end of the Ca 2+ distribution for the Northern Hemisphere wetlands, likely to be caused by the low level of Ca 2+ in aeolian dust. The pH in the pools of the small wetland was generally higher, probably as a result of differing organic acid production by the Sphagnum and sedge species, both of which were common and dominant or sub-dominant in the wetlands. Some temporal variability was observed, possibly due to seasonal variations in plant uptake and/or rainfall. A steady increase in Na + concentrations in the pools over 4 years was tentatively attributed to an excess of supply from rainfall and/or groundwater. Cation and stable isotope data indicate strong evaporation in pools and surface water, despite the high ambient relative humidity, and mixing within the top of the wetland sequence. Stratigraphy indicates that peat formation has been interrupted by flooding or runoff, bringing mineral matter into the wetlands, particularly in the earlier development stages of the larger wetland. The peat sequence is thicker in the smaller wetland, reaching up to 2.8 m, with limited mineral input during wetland development. The relatively low p

  19. Recharge of an Unconfined Pumice Aquifer: Winter Rainfall Versus Snow Pack, South-central Oregon

    Science.gov (United States)

    Cummings, M. L.; Weatherford, J. M.; Eibert, D.

    2015-12-01

    Walker Rim study area, an uplifted fault block east of the Cascade Range, south-central Oregon, exceeds 1580 m elevation and includes Round Meadow-Sellers Marsh closed basin, and headwaters of Upper Klamath Basin, Deschutes Basin, and Christmas Lake Valley in the Great Basin. The water-bearing unit is 2.8 to 3.0 m thick Plinian pumice fall from the Holocene eruption of Mount Mazama, Cascade Range. The perched pumice aquifer is underlain by low permeability regolith and bedrock. Disruption of the internal continuity of the Plinian pumice fall by fluvial and lacustrine processes resulted in hydrogeologic environments that include fens, wet meadows, and areas of shallow water table. Slopes are low and surface and groundwater pathways follow patterns inherited from the pre-eruption landscape. Discharge for streams and springs and depth to water table measured in open-ended piezometers slotted in the pumice aquifer have been measured between March and October, WY 2011 through WY2015. Yearly occupation on same date has been conducted for middle April, June 1st, and end of October. WY2011 and WY2012 received more precipitation than the 30 year average while WY2014 was the third driest year in 30 years of record. WY2014 and WY2015 provide an interesting contrast. Drought conditions dominated WY2014 while WY2015 was distinct in that the normal cold-season snow pack was replaced by rainfall. Cumulative precipitation exceeded the 30-year average between October and March. The pumice aquifer of wet meadows and areas of shallow water table experienced little recharge in WY2015. Persistence of widespread diffuse discharge from fens declined by middle summer as potentiometric surfaces lowered into confining peat layers or in some settings into the pumice aquifer. Recharge of the perched pumice aquifer in rain-dominated WY2015 was similar to or less than in the snow-dominated drought of WY2014. Rain falling on frozen ground drove runoff rather than aquifer recharge.

  20. Multi-scale characterization of monument limestones

    CERN Document Server

    Beck, K; Al-Mukhtar, M; Rozenbaum, Olivier

    2003-01-01

    Among the parameters influencing stone deterioration, moisture and water movements through the pore network are essential. This communication presents differents methods to characterize stones and to determinate the water transfer properties. Results are analysed for two limestones having similar total porosity, but characterized by different pore networks. These different porous systems govern dissimilar water properties.

  1. The Limestone Glades And Barrens Of West Virginia

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Cedar glade, limestone barren, and glade woodland communities are reported from limestone terranes in the Ridge and Valley of northeastern West Virginia. The cedar...

  2. U.S. Department of the Interior South Central Climate Science Center strategic science plan, 2013--18

    Science.gov (United States)

    Winton, Kim T.; Dalton, Melinda S.; Shipp, Allison A.

    2013-01-01

    The Department of the Interior (DOI) recognizes and embraces the unprecedented challenges of maintaining our Nation’s rich natural and cultural resources in the 21st century. The magnitude of these challenges demands that the conservation community work together to develop integrated adaptation and mitigation strategies that collectively address the impacts of climate change and other landscape-scale stressors. On September 14, 2009, DOI Secretary Ken Salazar signed Secretarial Order 3289 (amended February 22, 2010) entitled, “Addressing the Impacts of Climate Change on America’s Water, Land, and Other Natural and Cultural Resources.” The Order establishes the foundation for two partner-based conservation science entities to address these unprecedented challenges: Climate Science Centers (CSCs and Landscape Conservation Cooperatives (LCCs). CSCs and LCCs are the Department-wide approach for applying scientific tools to increase understanding of climate change and to coordinate an effective response to its impacts on tribes and the land, water, ocean, fish and wildlife, and cultural-heritage resources that DOI manages. Eight CSCs have been established and are managed through the U.S. Geological Survey (USGS) National Climate Change and Wildlife Science Center (NCCWSC); each CSC works in close collaboration with their neighboring CSCs, as well as those across the Nation, to ensure the best and most efficient science is produced. The South Central CSC was established in 2012 through a cooperative agreement with the University of Oklahoma, Texas Tech University, Louisiana State University, the Chickasaw Nation, the Choctaw Nation of Oklahoma, Oklahoma State University, and NOAA’s Geophysical Fluid Dynamics Lab; hereafter termed the ”Consortium” of the South Central CSC. The Consortium has a broad expertise in the physical, biological, natural, and social sciences to address impacts of climate change on land, water, fish and wildlife, ocean, coastal, and

  3. Water resources in the Big Lost River Basin, south-central Idaho

    Science.gov (United States)

    Crosthwaite, E.G.; Thomas, C.A.; Dyer, K.L.

    1970-01-01

    The Big Lost River basin occupies about 1,400 square miles in south-central Idaho and drains to the Snake River Plain. The economy in the area is based on irrigation agriculture and stockraising. The basin is underlain by a diverse-assemblage of rocks which range, in age from Precambrian to Holocene. The assemblage is divided into five groups on the basis of their hydrologic characteristics. Carbonate rocks, noncarbonate rocks, cemented alluvial deposits, unconsolidated alluvial deposits, and basalt. The principal aquifer is unconsolidated alluvial fill that is several thousand feet thick in the main valley. The carbonate rocks are the major bedrock aquifer. They absorb a significant amount of precipitation and, in places, are very permeable as evidenced by large springs discharging from or near exposures of carbonate rocks. Only the alluvium, carbonate rock and locally the basalt yield significant amounts of water. A total of about 67,000 acres is irrigated with water diverted from the Big Lost River. The annual flow of the river is highly variable and water-supply deficiencies are common. About 1 out of every 2 years is considered a drought year. In the period 1955-68, about 175 irrigation wells were drilled to provide a supplemental water supply to land irrigated from the canal system and to irrigate an additional 8,500 acres of new land. Average. annual precipitation ranged from 8 inches on the valley floor to about 50 inches at some higher elevations during the base period 1944-68. The estimated water yield of the Big Lost River basin averaged 650 cfs (cubic feet per second) for the base period. Of this amount, 150 cfs was transpired by crops, 75 cfs left the basin as streamflow, and 425 cfs left as ground-water flow. A map of precipitation and estimated values of evapotranspiration were used to construct a water-yield map. A distinctive feature of the Big Lost River basin, is the large interchange of water from surface streams into the ground and from the

  4. Geochemical Changes to Arc Magmatism in South Central Tibet During the India-Asia Collision

    Science.gov (United States)

    Waldrip, W. R.; Ducea, M. N.; Kapp, P. A.

    2013-12-01

    To study the changes in arc magmatism of the India-Asia collision, we focused on three geologic units in southern Tibet which span the transition from subduction to collision: (a) The Linzizong Formation, a 3-5 km thick volcanic-bearing succession (69 -40 Ma) within the Gangdese arc, (b) detrital zircons from the Kailas Formation, an alluvial fan-lacustrine unit (20-24 Ma) that was primarily sourced from the Linzizong Formation and the Gangdese plutonic arc and (c) the Lamuka Formation, a potassic calc-alkaline volcanic unit (11-12 Ma), which unconformably overlies the Linzizong Formation. Two sampling transects in the Sangsang area of south central Tibet were systematically described and sampled to produce a chemical, isotopic and chronostratigraphic section that examine the changing arc chemistry over time. New isotopic data from these transects show that the Cenozoic volcanic rocks of southern Tibet can be divided into three trends based on isotopic data. The first trend is from 70 to 55 Ma. 87Sr/86Sri ratios increase from 0.705 to 0.728 and the ɛHf(t) of individual zircons decreases from 6.1 to -6.0 during this period. The ɛNdo value of -6.0 is relatively constant during this the period. From 55 to 50 Ma, 87Sr/86Sri ratios decrease to 0.708 and ɛHf(t) increase to 13.9 at 50 Ma.ɛNdo values increase to -2.8. The third period includes samples <50 Ma. ɛHf(t) values from detrital zircons immediately decrease to ɛHf(t) 2.4 at 47 Ma and continue to decrease down to ɛHf(t) -7.6 at 45 Ma and ɛHf(t) -12.4 at 11 Ma. Lamuka Formation rocks have 87Sr/86Sri ratios as low as 0.7239 and ɛNdo of -14.3, in agreement with the Hf isotopic data from detrital zircons during this period. There is a consensus between Sr, Nd and Hf isotopic systems that there was an increased contribution of juvenile material to the melt from 55 to 50 Ma followed by a increase in crustal contributions to the melt by 48 Ma and that the crustal contributions increase through the through the

  5. Detrital Zircon Geochronology of Cretaceous and Paleogene Strata Across the South-Central Alaskan Convergent Margin

    Science.gov (United States)

    Bradley, Dwight; Haeussler, Peter; O'Sullivan, Paul; Friedman, Rich; Till, Alison; Bradley, Dan; Trop, Jeff

    2009-01-01

    Ages of detrital zircons are reported from ten samples of Lower Cretaceous to Paleogene metasandstones and sandstones from the Chugach Mountains, Talkeetna Mountains, and western Alaska Range of south-central Alaska. Zircon ages are also reported from three igneous clasts from two conglomerates. The results bear on the regional geology, stratigraphy, tectonics, and mineral resource potential of the southern Alaska convergent margin. Chugach Mountains - The first detrital zircon data are reported here from the two main components of the Chugach accretionary complex - the inboard McHugh Complex and the outboard Valdez Group. Detrital zircons from sandstone and two conglomerate clasts of diorite were dated from the McHugh Complex near Anchorage. This now stands as the youngest known part of the McHugh Complex, with an inferred Turonian (Late Cretaceous) depositional age no older than 91-93 Ma. The zircon population has probability density peaks at 93 and 104 Ma and a smattering of Early Cretaceous and Jurassic grains, with nothing older than 191 Ma. The two diorite clasts yielded Jurassic U-Pb zircon ages of 179 and 181 Ma. Together, these findings suggest a Mesozoic arc as primary zircon source, the closest and most likely candidate being the Wrangellia composite terrane. The detrital zircon sample from the Valdez Group contains zircons as young as 69 and 77 Ma, consistent with the previously assigned Maastrichtian to Campanian (Late Cretaceous) depositional age. The zircon population has peaks at 78, 91, 148, and 163 Ma, minor peaks at 129, 177, 330, and 352 Ma, and no concordant zircons older than Devonian. A granite clast from a Valdez Group conglomerate yielded a Triassic U-Pb zircon age of 221 Ma. Like the McHugh Complex, the Valdez Group appears to have been derived almost entirely from Mesozoic arc sources, but a few Precambrian zircons are also present. Talkeetna Mountains - Detrital zircons ages were obtained from southernmost metasedimentary rocks of the

  6. Late Pleistocene to Holocene tephrostratigraphy of the Lonquimay Volcano, South Central Chile

    Science.gov (United States)

    Gilbert, D.; Freundt, A.; Kutterolf, S.; Burkert, C.

    2010-12-01

    The Lonquimay Volcanic Complex (LVC) in South Central Chile (38.38°S, 71.58°W) is part of the Southern Volcanic Zone of the Andes, which formed in response to the subduction of the Nazca Plate beneath the South American Plate. During the course of its magmatic evolution, the LVC produced explosive eruptions documented in the succession of widespread tephra deposits, as well as large lava flows that originated from the main edifice and several adjacent minor eruptive centers. The last eruptive phase in Lonquimays volcanic evolution occurred from 1988-1990. It led to the formation of the Navidad cinder cone with its associated 10.2 km long lava flow, and a widely distributed tephra blanket of andesitic composition (Moreno and Gardeweg, 1989). During recent field work we reinvestigated and complemented the LVC tephrostratigraphy as originally established by Polanco (1998)by detailed logging of 22 outcrops and collecting 126 stratigraphically controlled samples that were analyzed for their matrix glass, mineral and bulk rock compositions. This data set allows us to verify and extend the field-based correlations, and to establish a tephrostratigraphy for the LVC that comprises 15 stratigraphic units (LQA-LQO) and provides a framework for ongoing investigations of the petrogenetic evolution of the LVC. The stratigraphic record identifies at least 13 explosive eruptions of VEI > 3 that occurred since the last glaciation period (17150 a BP, McCulloch et al. 2000). Magmatic compositions of the tephra deposits range from basaltic scoriae (51wt% SiO2) to evolved dacitic pumice lapilli layers (67wt% SiO2), and thus have a wider compositional range than the chemically distinct andesitic lavas (57-63wt%) of the LVC. The vertical succession of tephra compositions reflects four periods of progressive magmatic differentiation, each successively tapped by several eruptions. The maximum degree of fractionation reached during these periods increases to younger ages. The

  7. Limnology of Big Lake, south-central Alaska, 1983-84

    Science.gov (United States)

    Woods, Paul F.

    1992-01-01

    The limnological characteristics and trophic state of Big Lake in south-central Alaska were determined from the results of an intensive study during 1983-84. The study was begun in response to concern over the potential for eutrophication of Big Lake, which has experienced substantial residential development and recreational use because of its proximity to Anchorage. The east and west basins of the 1,213 square-hectometer lake were each visited 36 times during the 2-year study to obtain a wide variety of physical, chemical, and biological data. During 1984, an estimate was made of the lake's annual primary production. Big Lake was classified as oligotrophic on the basis of its annual mean values for total phosphorus (9.5 micrograms per liter), total nitrogen (209 micrograms per liter), chlorophyll-a (2.5 micrograms per liter), secchi-disc transparency (6.3 meters), and its mean daily integral primary production of 81.1 milligrams of carbon fixed per square meter. The lake was, however, uncharacteristic of oligotrophic lakes in that a severe dissolved-oxygen deficit developed within the hypolimnion during summer stratification and under winter ice cover. The summer dissolved-oxygen deficit resulted from the combination of strong and persistent thermal stratification, which developed within 1 week of the melting of the lake's ice cover in May, and the failure of the spring circulation to fully reaerate the hypolimnion. The autumn circulation did reaerate the entire water column, but the ensuing 6 months of ice and snow cover prevented atmospheric reaeration of the water column and led to development of the winter dissolved-oxygen deficit. The anoxic conditions that eventually developed near the lake bottom allowed the release of nutrients from the bottom sediments and facilitated ammonification reactions. These processes yielded hypolimnetic concentrations of nitrogen and phosphorus compounds, which were much larger than the oligotrophic concentrations measured

  8. Limestone reaction in calcium aluminate cement–calcium sulfate systems

    Energy Technology Data Exchange (ETDEWEB)

    Bizzozero, Julien, E-mail: julien.bizzozero@gmail.com; Scrivener, Karen L.

    2015-10-15

    This paper reports a study of ternary blends composed of calcium aluminate cement, calcium sulfate hemihydrate and limestone. Compressive strength tests and hydration kinetics were studied as a function of limestone and calcium sulfate content. The phase evolution and the total porosity were followed and compared to thermodynamic simulation to understand the reactions involved and the effect of limestone on these binders. The reaction of limestone leads to the formation of hemicarboaluminate and monocarboaluminate. Increasing the ratio between sulfate and aluminate decreases the extent of limestone reaction.

  9. White-tailed deer harvest from the chronic wasting disease eradication zone in south-central Wisconsin

    Science.gov (United States)

    Blanchong, Julie A.; Joly, D.O.; Samuel, M.D.; Langenberg, J.A.; Rolley, R.E.; Sausen, J.F.

    2006-01-01

    Chronic wasting disease (CWD) was discovered in free-ranging white-tailed deer (Odocoileus virginianus) in south-central Wisconsin in 2002. The current control method for CWD in the state is the harvest of deer from affected areas to reduce population density and lower CWD transmission. We used spatial regression methods to identify factors associated with deer harvest across south-central Wisconsin. Harvest of deer by hunters was positively related to deer density (slope=0.003, 95% CI=0.0001-0.006), the number of landowners that requested harvest permits (slope=0.071, 95% CI=0.037-0.105), and proximity to the area of highest CWD infection (slope=-0.041, 95% CI=-0.056- -0.027). Concomitantly, harvest was not impacted in areas where landowners signed a petition protesting intensive deer reduction (slope=-0.00006, 95% CI=-0.0005-0.0003). Our results suggest that the success of programs designed to reduce deer populations for disease control or to reduce overabundance in Wisconsin are dependent on landowner and hunter participation. We recommend that programs or actions implemented to eradicate or mitigate the spread of CWD should monitor and assess deer population reduction and evaluate factors affecting program success to improve methods to meet management goals.

  10. Preliminary description of hydrologic characteristics and contaminant transport potential of rocks in the Pasco Basin, south-central Washington

    Energy Technology Data Exchange (ETDEWEB)

    Deju, R.A.; Fecht, K.R.

    1979-03-01

    This report aims at consolidating existing data useful in defining the hydrologic characteristics of the Pasco Basin within south-central Washington. It also aims at compiling the properties required to evaluate contaminant transport potential within individual subsurface strata in this basin. The Pasco Basin itself is a tract of semi-arid land covering about 2,000 square miles in south-central Washington. The regional geology of this basin is dominated by tholeiitic flood basalts of the Columbia Plateau. The surface hydrology of the basin is dominated by the Yakima, Snake, and Columbia rivers. Short-lived ephemeral streams may flow for a short period of time after a heavy rainfall or snowmelt. The subsurface hydrology of the Pasco Basin is characterized by an unconfined aquifer carrying the bulk of the water discharged within the basin. This aquifer overlies a series of confined aquifers carrying progressively smaller amounts of groundwater as a function of depth. The hydraulic properties of the various aquifers and non-water-bearing strata are characterized and reported. A summary of the basic properties is tabulated. The hydrochemical data obtained are summarized. The contaminant transport properties of the rocks in the Pasco Basin are analyzed with emphasis on the dispersion and sorption coefficients and the characteristics of the potential reactions between emplaced waste and the surrounding medium. Some basic modeling considerations of the hydrogeologic systems in the basin with a brief discussion of model input requirements and their relationship to available data are presented.

  11. Relict nebkhas (pimple mounds) record prolonged late Holocene drought in the forested region of south-central United States

    Science.gov (United States)

    Seifert, Christopher L.; Cox, Randel Tom; Forman, Steven L.; Foti, Tom L.; Wasklewicz, Thad A.; McColgan, Andrew T.

    2009-05-01

    The origin and significance of pimple mounds (low, elliptical to circular dune-like features found across much of the south-central United States) have been debated for nearly two centuries. We cored pimple mounds at four sites spanning the Ozark Plateau, Arkansas River Valley, and Gulf of Mexico Coastal Plain and found that these mounds have a regionally consistent textural asymmetry such that there is a significant excess of coarse-grained sediment within their northwest flanks. We interpret this asymmetry as evidence of an eolian depositional origin of these mounds and conclude they are relict nebkhas (coppice dunes) deposited during protracted middle to late Holocene droughts. These four mounds yield optically stimulated luminescence ages between 2400 and 700 yr that correlate with well-documented periods of eolian activity and droughts on the southern Great Plains, including the Medieval Climate Anomaly. We conclude vegetation loss during extended droughts led to local eolian deflation and pimple mound deposition. These mounds reflect landscape response to multi-decadal droughts for the south-central U.S. The spatial extent of pimple mounds across this region further underscores the severity and duration of late Holocene droughts, which were significantly greater than historic droughts.

  12. Ecosystem Modeling in the South Central US: A Synthesis of Current Models toward the Development of Coupled Models

    Science.gov (United States)

    Kc, M.

    2015-12-01

    Ecosystem services and products are the foundation of sustainability for regional and global economy since we are directly or indirectly dependent on the ecosystem services like food, livestock, water, air, wildlife etc. It has been increasingly recognized that for sustainability concerns, the conservation problems need to be addressed in the context of entire ecosystems. This approach known as the ecosystem approach is fundamental to managing earth's finite resources since it addresses the interactions that link biotic systems, of which human, flora and fauna are integral parts, with the physical systems on which they depend. This approach is even more vital in the 21st century with formidable increasing human population and rapid changes in global environment. This study is being conducted to find the state of the science of ecosystem models in the South-Central region of US. The propose of the project is to conduct a systematic review and synthesize relevant information on the current state of the science of ecosystem modeling in the South-Central region of US toward coupling these models with climate, agronomic, hydrologic, economic or management models to better represent ecosystem dynamics as affected by climate change and human activities; and hence gain more reliable predictions of future ecosystem functions and service in the region. Better understandings of such processes will increase our ability to predict the ecosystem responses and feedbacks to environmental and human induced change in the region so that decision makers can make an informed management decisions of the ecosystem.

  13. Beneficiation of a low grade limestone sample

    Institute of Scientific and Technical Information of China (English)

    Rao Danda Srinivas; Vijayakumar Tadiparthi Venkata; Subba Rao Sripada; Bhaskar Raju Guntamadugu; Prabhakar Swarna

    2011-01-01

    Pilot scale column flotation studies were conducted on a low grade siliceous limestone ore.Silica content was reduced to less than 1% in the concentrate so that it became satisfactory for use in the paper or rubber industries.The limestone sample was crystalline and constituted primarily of calcite that contained quartz,feldspar,pyroxene,and biotite as gangue minerals.Quartz is the major silicate gangue whereas feldspar,pyroxene,and biotite exist in minor to trace quantities.Traces of pyrite were also observed within the sample.A reverse flotation process was adopted where the silicate gangue minerals were floated using two different commercial cationic collectors:Chem-750 F or Floatamine-D.The studies clearly suggest it is possible to produce a limestone concentrate assaying around 96-97% CaCO3 containing less than 1 % SiO2.The effect of feed flow rate,percent solids,froth depth,and wash water on the grade and recovery of the CaCO3 concentrate is discussed.

  14. Hydrogeologic framework of the Wood River Valley aquifer system, south-central Idaho

    Science.gov (United States)

    Bartolino, James R.; Adkins, Candice B.

    2012-01-01

    metamorphosed to some degree, thus rock types and their relationships vary over distance. Quaternary-age sediment and basalt compose the primary source of groundwater in the Wood River Valley aquifer system. These Quaternary deposits can be divided into three units: a coarse-grained sand and gravel unit, a fine-grained silt and clay unit, and a single basalt unit. The fine- and coarse-grained units were primarily deposited as alluvium derived from glaciation in the surrounding mountains and upper reaches of tributary canyons. The basalt unit is found in the southeastern Bellevue fan area and is composed of two flows of different ages. Most of the groundwater produced from the Wood River Valley aquifer system is from the coarse-grained deposits. The altitude of the pre-Quaternary bedrock surface in the Wood River Valley was compiled from about 1,000 well-driller reports for boreholes drilled to bedrock and about 70 Horizontal-to-Vertical Spectral Ratio (HVSR) ambient-noise measurements. The bedrock surface generally mimics the land surface by decreasing down tributary canyons and the main valley from north to south; it ranges from more than 6,700 feet in Baker Creek to less than 4,600 feet in the central Bellevue fan. Most of the south-central portion of the Bellevue fan is underlain by an apparent topographically closed area on the bedrock surface that appears to drain to the southwest towards Stanton Crossing. Quaternary sediment thickness ranges from less than a foot on main and tributary valley margins to about 350 feet in the central Bellevue fan. Hydraulic conductivity for 81 wells in the study area was estimated from well-performance tests reported on well-driller reports. Estimated hydraulic conductivity for 79 wells completed in alluvium ranges from 1,900 feet per day (ft/d) along Warm Springs Creek to less than 1 ft/d in upper Croy Canyon. A well completed in bedrock had an estimated hydraulic conductivity value of 10 ft/d, one well completed in basalt had a value of

  15. Elemental analysis of limestone samples from Obajana and Mfamosing limestone deposits, Nigeria, using nuclear techniques

    Energy Technology Data Exchange (ETDEWEB)

    Akpan, I.O. [Department of Physics, University of Calabar, Calabar, Cross River State (Nigeria); Amodu, A.E. [Science Laboratory Technology Department, Federal Polytechnic, Idah, Kogi State (Nigeria); Akpan, A.E., E-mail: anthonyakpan@yahoo.com [Department of Physics, University of Calabar, Calabar, Cross River State (Nigeria)

    2011-10-15

    Six limestone samples were picked from three different points at the Obajana and Mfamosing limestone deposits. The limestone samples were subjected to elemental analysis by Proton-Induced X-Ray Emission (PIXE) analysis. The samples were irradiated by a 4 mm diameter beam of protons with energy of 2.5 MeV and beam current of 0.2 nA for 0.9 ms. The analysis was carried out with the 1.7 MV Tandem accelerator at the Centre for Energy Research and Development (CERD), Ile-Ife, Osun State, Nigeria. The NIST geology standard NIST 278 was analysed for quality assurance. The elemental composition and concentration of 14 elements were determined in the two locations. Ten elements were found at the Obajana deposit while 13 elements were found at the Mfamosing deposits. The elements: Mg, Al, Ca and Mn do not differ much at both deposits while others differ. The major elements (Ca, Fe, Al, Si and K) present in the limestones were also found in airborne particulate matter studied by earlier researchers. These observations suggest that all particulate emissions and wastes from the Limestone deposit should be closely monitored to reduce their cumulative effects on both health and the environment

  16. Elemental analysis of limestone samples from Obajana and Mfamosing limestone deposits, Nigeria, using nuclear techniques.

    Science.gov (United States)

    Akpan, I O; Amodu, A E; Akpan, A E

    2011-10-01

    Six limestone samples were picked from three different points at the Obajana and Mfamosing limestone deposits. The limestone samples were subjected to elemental analysis by Proton-Induced X-Ray Emission (PIXE) analysis. The samples were irradiated by a 4mm diameter beam of protons with energy of 2.5 MeV and beam current of 0.2nA for 0.9 ms. The analysis was carried out with the 1.7MV Tandem accelerator at the Centre for Energy Research and Development (CERD), Ile-Ife, Osun State, Nigeria. The NIST geology standard NIST 278 was analysed for quality assurance. The elemental composition and concentration of 14 elements were determined in the two locations. Ten elements were found at the Obajana deposit while 13 elements were found at the Mfamosing deposits. The elements: Mg, Al, Ca and Mn do not differ much at both deposits while others differ. The major elements (Ca, Fe, Al, Si and K) present in the limestones were also found in airborne particulate matter studied by earlier researchers. These observations suggest that all particulate emissions and wastes from the Limestone deposit should be closely monitored to reduce their cumulative effects on both health and the environment.

  17. Status and trends of land change in the Midwest–South Central United States—1973 to 2000

    Science.gov (United States)

    Auch, Roger F.; Karstensen, Krista A.; Auch, Roger F.; Karstensen, Krista A.

    2015-12-10

    U.S. Geological Survey (USGS) Professional Paper 1794–C is the third in a four-volume series on the status and trends of the Nation’s land use and land cover, providing an assessment of the rates and causes of land-use and land-cover change in the Midwest–South Central United States between 1973 and 2000. Volumes A, B, and D provide similar analyses for the Western United States, the Great Plains of the United States, and the Eastern United States, respectively. The assessments of land-use and land-cover trends are conducted on an ecoregion-by-ecoregion basis, and each ecoregion assessment is guided by a nationally consistent study design that includes mapping, statistical methods, field studies, and analysis. Individual assessments provide a picture of the characteristics of land change occurring in a given ecoregion; in combination, they provide a framework for understanding the complex national mosaic of change and also the causes and consequences of change. Thus, each volume in this series provides a regional assessment of how (and how fast) land use and land cover are changing, and why. The four volumes together form the first comprehensive picture of land change across the Nation.Geographic understanding of land-use and land-cover change is directly relevant to a wide variety of stakeholders, including land and resource managers, policymakers, and scientists. The chapters in this volume present brief summaries of the patterns and rates of land change observed in each ecoregion in the Midwest–South Central United States, together with field photographs, statistics, and comparisons with other assessments. In addition, a synthesis chapter summarizes the scope of land change observed across the entire Midwest–South Central United States. The studies provide a way of integrating information across the landscape, and they form a critical component in the efforts to understand how land use and land cover affect important issues such as the provision of

  18. Optimizing Fracture Treatments in a Mississippian "Chat" Reservoir, South-Central Kansas

    Energy Technology Data Exchange (ETDEWEB)

    K. David Newell; Saibal Bhattacharya; Alan Byrnes; W. Lynn Watney; Willard Guy

    2005-10-01

    This project is a collaboration of Woolsey Petroleum Corporation (a small independent operator) and the Kansas Geological Survey. The project will investigate geologic and engineering factors critical for designing hydraulic fracture treatments in Mississippian ''chat'' reservoirs. Mississippian reservoirs, including the chat, account for 159 million m3 (1 billion barrels) of the cumulative oil produced in Kansas. Mississippian reservoirs presently represent {approx}40% of the state's 5.6*106m3 (35 million barrels) annual production. Although geographically widespread, the ''chat'' is a heterogeneous reservoir composed of chert, cherty dolomite, and argillaceous limestone. Fractured chert with micro-moldic porosity is the best reservoir in this 18- to 30-m-thick (60- to 100-ft) unit. The chat will be cored in an infill well in the Medicine Lodge North field (417,638 m3 [2,626,858 bbls] oil; 217,811,000 m3 [7,692,010 mcf] gas cumulative production; discovered 1954). The core and modern wireline logs will provide geological and petrophysical data for designing a fracture treatment. Optimum hydraulic fracturing design is poorly defined in the chat, with poor correlation of treatment size to production increase. To establish new geologic and petrophysical guidelines for these treatments, data from core petrophysics, wireline logs, and oil-field maps will be input to a fracture-treatment simulation program. Parameters will be established for optimal size of the treatment and geologic characteristics of the predicted fracturing. The fracturing will be performed and subsequent wellsite tests will ascertain the results for comparison to predictions. A reservoir simulation program will then predict the rate and volumetric increase in production. Comparison of the predicted increase in production with that of reality, and the hypothetical fracturing behavior of the reservoir with that of its actual behavior, will serve as tests of

  19. Diversity and effective population size of four horse breeds from microsatellite DNA markers in South-Central Mexico

    Directory of Open Access Journals (Sweden)

    J. F. Vázquez-Armijo

    2017-06-01

    Full Text Available The South-Central region of Mexico has experienced a sizeable introduction of purebred horses for recreational aims. A study was designed to assess effective population sizes and genetic diversity and to verify the genetic integrity of four horse breeds. Using a 12-microsatellite panel, Quarter Horse, Azteca, Thoroughbred and Creole (CRL horses were sampled and analysed for diversity and genetic structure. Genetic diversity parameters showed high numbers of heterozygous horses but small effective population sizes in all breeds. Population structure results suggested some degree of admixture of CRL with the other reference breeds. The highly informative microsatellite panel allowed the verification of diversity in introduced horse populations and the confirmation of small effective population sizes, which suggests a risk for future breed integrity.

  20. Selected hydrologic data, Yampa River basin and parts of the White River basin, northwestern Colorado and south-central Wyoming

    Science.gov (United States)

    Giles, T.F.; Brogden, Robert E.

    1978-01-01

    Selected hydrologic data are presented from four energy-related projects conducted by the U.S. Geological Survey in the Yampa River basin and parts of the White River basin in northwestern Colorado and south-central Wyoming. Water-quality data during 1974 and 1975 and parts of 1976 for 129 ground-water sites and 119 surface-water sites are tabulated. For most samples, major cations, anions, and trace metals were analyzed. For the same time period, field measurements of specific conductance, temperature, and pH were made on 252 springs and wells. These samplings sites, as well as the locations of 20 climatological stations, 18 snow-course sites, and 43 surface-water gaging stations, are shown on maps. Geologic units that contain coal deposits or supply much of the water used for stock and domestic purposes in the area also are shown on a map. (Woodard-USGS)

  1. Land surface and atmospheric conditions associated with heat waves over the Chickasaw Nation in the South Central United States

    Science.gov (United States)

    Lee, Eungul; Bieda, Rahama; Shanmugasundaram, Jothiganesh; Basara Richter, Heather

    2016-06-01

    Exposure to extreme heat was reconstructed based on regional land-atmosphere processes from 1979 to 2010 in the South Central U.S. The study region surrounds the Chickasaw Nation (CN), a predominantly Native American population with a highly prevalent burden of climate-sensitive chronic diseases. Land surface and atmospheric conditions for summer heat waves were analyzed during spring (March-April-May, MAM) and summer (June-July-August, JJA) based on the Climate and Ocean: Variability, Predictability, and Change maximum temperature definition for heat wave frequency (HWF). The spatial-temporal pattern of HWF was determined using empirical orthogonal function (EOF) analysis and the corresponding principle component time series of the first EOF of HWF. Statistically significant analyses of observed conditions indicated that sensible heat increased and latent heat fluxes decreased with high HWF in the South Central U.S. The largest positive correlations of sensible heat flux to HWF and the largest negative correlations of latent heat flux to HWF were specifically observed over the CN. This is a significantly different energy transfer regime due to less available soil moisture during the antecedent MAM and JJA. The higher sensible heat from dry soil could cause significant warming from the near surface (>2.0°C) to the lower troposphere (>1.5°C), and accumulated boundary layer heat could induce the significant patterns of higher geopotential height and enhance anticyclonic circulations (negative vorticity anomaly) at the midtroposphere. Results suggested a positive land-atmosphere feedback associated with heat waves and called attention to the need for region-specific climate adaptation planning.

  2. Bird Diversity and Structure in Different Land-use Types in Lowland South-Central Mindanao, Philippines.

    Science.gov (United States)

    Tanalgo, Krizler Cejuela; Pineda, John Arislyn Fuentes; Agravante, Maricel Estolloso; Amerol, Zabide Mamalo

    2015-12-01

    Birds are crucial to maintaining the balance of many ecosystems by providing various ecological services. The diversity of birds and their feeding guilds in different land-use types were investigated in south-central Mindanao to elucidate the effect of disturbance and habitat modification on bird communities. Point count method was employed to identify birds in three habitat types: i) agroforests; ii) ricefields; iii) roads and heavily disturbed areas. A total of 1114 bird sightings were recorded that included 33 species of 24 families; of these, 3 were Philippine endemics, and 5 were migrant species. Among all of the habitat types, the highest species diversity was found in agroforests (1/D = 16.148), and the lowest was recorded from roads and heavily disturbed habitats. The species composition of agroforests was more similar to ricefields than to areas with high levels of disturbance, such as roads. The characteristic of the vegetation and the availability of food resources may be vital to the diversity of birds in every habitat as evidenced by the high species richness of frugivores and insectivores in agroforests and ricefields, respectively, where food source is largely available. The observation of Streptopelia tranquebarica was a new record for Mindanao, and it was particularly sighted in ricefields. Therefore, this study indicates that land-use change and modification may alter bird diversity structure, and the maintenance of the vegetation in land-use types as food and resource, and as habitat is essential to the conservation of the native and ecologically-important bird species in south-central Mindanao.

  3. Dental caries among children visiting a mobile dental clinic in South Central Kentucky: a pooled cross-sectional study

    Science.gov (United States)

    2013-01-01

    Background Dental caries is one of the most common chronic childhood diseases affecting a large portion of children in the United States. The prevalence of childhood dental caries in Kentucky is among the highest in the nation. The purposes of this study are to (1) compare sociodemographic differences between caries and no caries groups and (2) investigate factors associated with untreated dental caries among children who visited a mobile dental clinic in South Central Kentucky. Methods Study subjects were children aged 6 to 15 years who participated in the school-based dental sealant program through the mobile dental clinic operated by the Institute for Rural Health at Western Kentucky University between September 2006 and May 2011 (n = 2,453). Descriptive statistics were calculated for sociodemographic factors (age, gender, race/ethnicity, insurance status, and urban versus rural residential location) and caries status. We used chi-square tests to compare sociodemographic differences of children stratified by caries and no caries status as well as three levels of caries severity. We developed a logistic regression model to investigate factors associated with untreated dental caries while controlling for sociodemographic characteristics. Results The proportion of children having untreated dental caries was 49.7% and the mean number of untreated dental caries was 2.0. The proportion of untreated dental caries was higher in older children, children with no insurance and living in rural residential locations, and caries severity was also higher in these groups. Odds ratio indicated that older ages, not having private insurance (having only public, government-sponsored insurance or no insurance at all) and rural residential location were associated with having untreated dental caries after controlling for sociodemographic characteristics of children. Conclusions Untreated dental caries was more likely to be present in older children living in rural areas without

  4. The use of mosquito nets and the prevalence of Plasmodium falciparum infection in rural South Central Somalia.

    Directory of Open Access Journals (Sweden)

    Abdisalan M Noor

    Full Text Available BACKGROUND: There have been resurgent efforts in Africa to estimate the public health impact of malaria control interventions such as insecticide treated nets (ITNs following substantial investments in scaling-up coverage in the last five years. Little is known, however, on the effectiveness of ITN in areas of Africa that support low transmission. This hinders the accurate estimation of impact of ITN use on disease burden and its cost-effectiveness in low transmission settings. METHODS AND PRINCIPAL FINDINGS: Using a stratified two-stage cluster sample design, four cross-sectional studies were undertaken between March-June 2007 across three livelihood groups in an area of low intensity malaria transmission in South Central Somalia. Information on bed net use; age; and sex of all participants were recorded. A finger prick blood sample was taken from participants to examine for parasitaemia. Mantel-Haenzel methods were used to measure the effect of net use on parasitaemia adjusting for livelihood; age; and sex. A total of 10,587 individuals of all ages were seen of which 10,359 provided full information. Overall net use and parasite prevalence were 12.4% and 15.7% respectively. Age-specific protective effectiveness (PE of bed net ranged from 39% among <5 years to 72% among 5-14 years old. Overall PE of bed nets was 54% (95% confidence interval 44%-63% after adjusting for livelihood; sex; and age. CONCLUSIONS AND SIGNIFICANCE: Bed nets confer high protection against parasite infection in South Central Somalia. In such areas where baseline transmission is low, however, the absolute reductions in parasitaemia due to wide-scale net use will be relatively small raising questions on the cost-effectiveness of covering millions of people living in such settings in Africa with nets. Further understanding of the progress of disease upon infection against the cost of averting its consequent burden in low transmission areas of Africa is therefore required.

  5. Dental caries among children visiting a mobile dental clinic in South Central Kentucky: a pooled cross-sectional study.

    Science.gov (United States)

    Dawkins, Erika; Michimi, Akihiko; Ellis-Griffith, Gregory; Peterson, Tina; Carter, Daniel; English, Gary

    2013-05-02

    Dental caries is one of the most common chronic childhood diseases affecting a large portion of children in the United States. The prevalence of childhood dental caries in Kentucky is among the highest in the nation. The purposes of this study are to (1) compare sociodemographic differences between caries and no caries groups and (2) investigate factors associated with untreated dental caries among children who visited a mobile dental clinic in South Central Kentucky. Study subjects were children aged 6 to 15 years who participated in the school-based dental sealant program through the mobile dental clinic operated by the Institute for Rural Health at Western Kentucky University between September 2006 and May 2011 (n = 2,453). Descriptive statistics were calculated for sociodemographic factors (age, gender, race/ethnicity, insurance status, and urban versus rural residential location) and caries status. We used chi-square tests to compare sociodemographic differences of children stratified by caries and no caries status as well as three levels of caries severity. We developed a logistic regression model to investigate factors associated with untreated dental caries while controlling for sociodemographic characteristics. The proportion of children having untreated dental caries was 49.7% and the mean number of untreated dental caries was 2.0. The proportion of untreated dental caries was higher in older children, children with no insurance and living in rural residential locations, and caries severity was also higher in these groups. Odds ratio indicated that older ages, not having private insurance (having only public, government-sponsored insurance or no insurance at all) and rural residential location were associated with having untreated dental caries after controlling for sociodemographic characteristics of children. Untreated dental caries was more likely to be present in older children living in rural areas without insurance. Health interventionists may use

  6. Prevalence and risk factors for Leptospira spp. in cattle herds in the south central region of Paraná state

    Directory of Open Access Journals (Sweden)

    Vanessa Y Hashimoto

    2012-02-01

    Full Text Available The aim of this study was to determine the prevalence of anti-Leptospira spp. antibodies and the risk factors for Leptospira spp. infection in breeding cattle herds in the south central region of Paraná state. It was based on the statistic delineation/serological samples and information regarding the selected farms employed in the study of bovine brucellosis for Paraná state in the context of National Program for Control and Eradication of Brucellosis and Tuberculosis. A total of 1.880 females aged >24 months from 274 non vaccinated herds were studied. Serum samples were tested for antibodies against Leptospira spp. using microscopic agglutination test (MAT with 22 Leptospira serovars. The epidemiological questionnaire was applied on all the selected farms and aimed to obtain epidemiological data. Hundred eighty one of 274 herds were positive for Leptospira spp./presenting prevalence of positive herds of 66.06% (IC95%=60.12-71,65%. Presence of >43 cattle (OR=3.120; IC=1.418-6.867/animal purchase (OR=2.010; IC=1.154-3.500/rent of pastures (OR=2.925; IC=1.060-8.068 and presence of maternity paddock (OR=1.981; IC=1,068-3,676 were identified as risk factors for leptospirosis due to any serovar in the multivariate logistic regression. Risk factors for leptospirosis due to serovar Hardjo were presence of >43 cattle (OR=3.622; IC=1.512-8,677/animal purchase (OR=3.143; IC=1.557-6.342/rent of pastures (OR=4.070; IC=1.370-12.087 and presence of horses (OR=2.981; IC=1.321-6.726. These results indicate that Leptospira spp. infection is widespread in the south central region of Paraná state and that factors related to the herd characteristic and management are associated with the infection.

  7. Hydrogen Chloride Reaction with Lime and Limestone

    DEFF Research Database (Denmark)

    Erik Weinell, Claus; Jensen, Peter I.; Dam-Johansen, Kim

    1992-01-01

    The capacity of solid slaked lime and limestone for binding HCl from a gas phase has been investigated in the temperature range 60-1000 °C. The binding capacity is largest in the range 500-600 °C. However, for slaked lime in the presence of water, a large binding capacity is observed also below 150...... °C. This is ascribed to the formation of a partially liquid product phase. At temperatures exceeding 500 °C the binding capacity is limited by chemical equilibrium between gas and solid. For the range of properties studied the binding capacity is independent of particle size and only depends slightly...

  8. Using of Local Limestone as Aggregate in Concrete Mixture

    Directory of Open Access Journals (Sweden)

    Dr.Muyasser M. Jomaa'h

    2012-03-01

    Full Text Available This research deals with the field investigations and construction properties for using limestone as a lightweight course aggregate in concrete mixture in stead of normal coarse aggregate. Concrete cubes samples have been prepared with dimensions of 150*150*150 mm according to ASTM. For these samples the normal coarse aggregate was replaced by 100% coarse crushed limestone. Three types of limestone which were used (Al-Sinea, Makhool and Himreen, it was found that the Al-Sinea type of limestone gave a good combination (fcu =32.11MPa without admixtures. The obtained results showed a suitable reduction in dead loads of structural elements and cost. Accordingly, the usage of limestone will improve the structural applications and concrete mix properties to attain economic viability. These above results make limestone as a good alternative of normal coarse aggregate

  9. Elemental analysis of limestone samples from Ewekoro limestone deposit in southwest Nigeria

    Science.gov (United States)

    Obiajunwa, E. I.; Nwachukwu, J. I.

    2000-10-01

    Limestone samples of different colours from Ewekoro limestone deposit in Ogun State, Nigeria were subjected to elemental analysis by proton-induced X-ray emission (PIXE) and proton-induced gamma-ray emission (PIGME) techniques. The irradiation was by 2.5 MeV proton beams from the ion beam analysis (IBA) facility of the 3 MV Van de Graaff accelerator at the Australian Nuclear Science and Technology Organisation (ANSTO), Lucas Heights. Elemental composition and concentrations of 22 major, minor and trace elements were determined. The NIST geological standard, NBS278, was analysed for quality assurance. The concentrations of the major elements (Ca, Fe, K and Al) are similar in the samples while the other major elements differed. Calcium accounts for about 38%, giving 86.8% CaCO 3 content in the limestones. The major elements (Al, Ca, Fe, Si, S and K), present in the limestones, were also found to be enriched in airborne particulate matter studied by earlier workers, thus confirming cement dust as the major contributor to the particulate matter within and around cement factories.

  10. Rock mass characterization for tunnels in the Copenhagen limestone

    DEFF Research Database (Denmark)

    Foged, Niels Nielsen; Jakobsen, Lisa; Jackson, Peter

    2007-01-01

    Tunnels in Copenhagen are drilled through highly anisotropic limestone comprising alternating strongly lithified and less lithified parts. The mass quality of the limestone is usually defined from fracture spacing registered in core samples. The deposit is, however, affected destructively by dril...... by drilling activity yielding a low Rock Quality Designation RQD. In-situ observations of the limestone in excavations or televiewer logs reveal only few natural discontinuities compared to core logging, indicating a very good suitability for tunneling....

  11. Limestone types used from the classic Karst region in Slovenia

    Science.gov (United States)

    Kramar, Sabina; Mirtič, Breda; Mladenović, Ana; Rožič, Boštjan; Bedjanič, Mojca; Kortnik, Jože; Šmuc, Andrej

    2014-05-01

    The paper presents a variety of limestones from the Karst Region that is one of the most interesting areas containing reserves of natural stones in Slovenia. The region is mainly composed of Cretaceous shallow-water limestone, with the most common type currently excavated being the rudist limestone of the Lipica Formation, which dates to the Santonian to Campanian. Limestones of this formation are mainly represented by a light grey, thick-bedded to massive Lipica limestone rich in (largely fragmented) rudists. Rudist shells can be either relatively well preserved (such as in Lipica Fiorito quarried limestone) or almost completely disintegrated and intensively endolitised (Lipica Unito quarried limestone). Beside the Lipica Formation, natural stone types have been excavated from two other formations or members in the Karst region: the Repen Formation (Repen and Kopriva limestones), and the Tomaj Limestone (dark, laminated limestone within the Lipica Formation). As documented, the region has been associated with the quarrying and processing of stone at least for over two thousand years, i.e. since the Roman period. Although a large number of quarries in all mentioned formations are documented in the Karst region, many are inactive nowadays. Some of the quarries are declared as geological monuments of national importance or officially protected as a natural monument. Karst limestones are considered the highest quality calcareous natural stones in Slovenia. They are characterised by high density, low water absorption and low open porosity; consequently they also exhibit high frost and salt resistance as well as high compressive and flexural strength. Besides in the Karst region and other parts of Slovenia, the Karst limestones were used in the construction of several important buildings and monuments in many other European Countries, and worldwide. Nowadays, they are most commonly used in the construction of façade cladding, pavements, window sills, staircases, indoor

  12. Rock mass characterization for tunnels in the Copenhagen limestone

    DEFF Research Database (Denmark)

    Foged, Niels Nielsen; Jakobsen, Lisa; Jackson, Peter;

    2007-01-01

    Tunnels in Copenhagen are drilled through highly anisotropic limestone comprising alternating strongly lithified and less lithified parts. The mass quality of the limestone is usually defined from fracture spacing registered in core samples. The deposit is, however, affected destructively by dril...... by drilling activity yielding a low Rock Quality Designation RQD. In-situ observations of the limestone in excavations or televiewer logs reveal only few natural discontinuities compared to core logging, indicating a very good suitability for tunneling....

  13. Breschini and Haversat, eds.: Analysis of South-Central California Shell Artifacts: Studies from Santa Cruz, Monterey, San Luis Obispo, and Santa Barbara Counties

    OpenAIRE

    Hughes, Richard E.

    1989-01-01

    Analysis of South-Central Californian Shell Artifacts: Studies from Santa Cruz, Monterey, San Luis Obispo, and Santa Barbara Counties. Gary S. Breschmi and Trudy Haversat, eds. Salinas: Coyote Press Archives of California Prehistory No. 23, 1988, xiv + 105 pp., 21 figs., 28 tables, $8.70, (paper).

  14. Reduction of Risk in Exploration and Prospect Generation through a Multidisciplinary Basin-Analysis Program in the South-Central Mid-Continent Region

    Energy Technology Data Exchange (ETDEWEB)

    Banerjee, S.; Barker, C.; Fite, J.; George, S.; Guo, Genliang; Johnson, W.; Jordan, J., Szpakiewicz, M.; Person, M.; Reeves, T.K.; Safley, E.; Swenson, J.B.; Volk, L.; and Erickson, R.

    1999-04-02

    This report will discuss a series of regional studies that were undertaken within the South-Central Mid-Continent region of the U.S. Coverage is also provided about a series of innovative techniques that were used for this assessment.

  15. The Portuguese Lioz, a Monumental Limestone

    Science.gov (United States)

    Silva, Zenaide

    2017-04-01

    Lioz is a microcrystalline limestone which occurs in Portugal and outcrops in the Lisbon area and its neighboring counties Oeiras, Pero Pinheiro, Lameiras. The rock is whitish to light and dark pink and contains 120 million years old rudists fossils. This fossiliferous content imprints a decorative aspect to the rock contributing to its very wide use as construction material and its favorite use in churches and official monuments making it the Royal Stone in Portugal along the XVII and XVIII centuries. Lisbon has the best exposition of Lioz as a fundamental stone in several monuments, the best examples being the Jeronimos Monastery, the Belém Tower, the Cultural Center in Belém and many old churches spread in Lisbon area. Among the latter the Jesuit Church of São Roque is a special example. The fact that the rock stratigraphic sequence allows the different rock colors as white, light and dark pink and a yellow facies variety in a local occurrence (Negrais yellow) makes it a special source for decorative patterns that can be found in a few churches in Lisbon, Évora, Mafra exhibiting "embutidos" technique, of indian origin and inspired on contemporaneous Italian churches. Mafra is the place where a monumental architectural set, composed by three integrated constructions, was built in the XVIII century by king D.João V using Lioz limestone as the main rock material, in all available colors. Along the XVII and XVIII centuries, the rock was transported to some portuguese colonies, mainly as ballast to improve the navigability of the boats, and used at the destinations as construction material for monuments, official buildings and churches. Brazil and especially Salvador, in Bahia, is the best example of that, where Lioz is beautifully exposed in monuments and as true art in many churches where the Portuguese or Italian influences are very strong. All these facts make the Portuguese Lioz Limestone as very representative of the Heritage present in Portugal and its

  16. STEAM INJECTION INTO FRACTURED LIMESTONE AT LORING AIR FORCE BASE

    Science.gov (United States)

    A research project on steam injection for the remediation of spent chlorinated solvents from fractured limestone was recently undertaken at the former Loring AFB in Limestone, ME. Participants in the project include the Maine Department of Environmental Protection, EPA Region I,...

  17. Exploration for limestone deposit at Onigbedu, South-Western Nigeria

    Science.gov (United States)

    Oyedele, Kayode F.; Oladele, Sunday; Emakpor, Charles A.

    2016-09-01

    The Onigbedu limestone deposit was investigated using the aeromagnetic data, resistivity soundings and borings with the aim of characterizing the limestone deposit and estimating its reserves. The subsurface structural features and depth to basement were identified with the analysis of aeromagnetic data. Twenty nine boreholes were drilled for subsurface appraisal and correlation of the limestone deposit. Eighty nine Vertical Electrical Sounding (VES) were acquired using the Schlumberger array. The results showed NE-SW trending lineaments that segmented the limestone. Depth to basement varied from 144.2 m to 1090 m. The VES results showed four to six layers indicating the topsoil (7-315 Ωm), clay (2-25 Ωm), shale (6-31 Ωm), limestone (20-223 Ωm), sandstone (>200 Ωm) and sandy materials. The VES results correlated well with the lithological unit delineated from the borehole. The overburden thickness ranged from 3.3 m to 28 m, while the limestone thickness varies between 18.1 m and 48.3 m. The limestone reserve was estimated at 1.9 × 109 t. This study concluded that the study area had vast occurrence of the limestone deposits, which would be of economic importance, if exploited.

  18. Mathematical Modeling on Open Limestone Channel

    CERN Document Server

    Bandstra, Joel; Wu, Naiyi

    2014-01-01

    Acid mine drainage (AMD) is the outflow of acidic water from metal mines or coal mines. When exposed to air and water, metal sulfides from the deposits of the mines are oxidized and produce acid, metal ions and sulfate, which lower the pH value of the water. An open limestone channel (OLC) is a passive and low cost way to neutralize AMD. The dissolution of calcium into the water increases the pH value of the solution. A differential equation model is numerically solved to predict the variation of concentration of each species in the OLC solution. The diffusion of Calcium due to iron precipitates is modeled by a linear equation. The results give the variation of pH value and the concentration of Calcium.

  19. Face logging in Copenhagen Limestone, Denmark

    DEFF Research Database (Denmark)

    Jakobsen, Lisa; Foged, Niels Nielsen; Erichsen, Lars;

    2015-01-01

    The requirement for excavation support can be assessed from face logging. Face logs can also improve our knowledge of lithological and structural conditions within bedrock and supplement information from boreholes and geophysical logs. During the construction of 8 km metro tunnel and 4 km heating...... tunnel in Copenhagen more than 2.5 km face logs were made in 467 locations at underground stations, shafts, caverns and along bored tunnels. Over 160 geotechnical boreholes, many with geophysical logging were executed prior to construction works. The bedrock consists of Paleogene "Copenhagen limestone......" and face logs show a sub-horizontally layered structure, with alternate extremely weak to extremely strong beds of variable thickness. The rhythmicity is thought to be climatically controlled. Stronger beds represent reduced sedimentation rate related to climatic deterioration while weaker beds result from...

  20. Modeling contaminant plumes in fractured limestone aquifers

    DEFF Research Database (Denmark)

    Mosthaf, Klaus; Brauns, Bentje; Fjordbøge, Annika Sidelmann

    the established approaches of the equivalent porous medium, discrete fracture and dual continuum models. However, these modeling concepts are not well tested for contaminant plume migration in limestone geologies. Our goal was to develop and evaluate approaches for modeling the transport of dissolved contaminant...... in the planning of field tests and to update the conceptual model in an iterative process. Field data includes information on spill history, distribution of the contaminant (multilevel sampling), geology and hydrogeology. To describe the geology and fracture system, data from borehole logs, packer tests, optical...... distribution in the aquifer. Different models were used for the planning and interpretation of the pump and tracer test. The models were evaluated by examining their ability to describe collected field data. The comparison with data showed that the models have substantially different representations...

  1. The invasive species Ulex europaeus (Fabaceae) shows high dynamism in a fragmented landscape of south-central Chile.

    Science.gov (United States)

    Altamirano, Adison; Cely, Jenny Paola; Etter, Andrés; Miranda, Alejandro; Fuentes-Ramirez, Andres; Acevedo, Patricio; Salas, Christian; Vargas, Rodrigo

    2016-08-01

    Ulex europaeus (gorse) is an invasive shrub deemed as one of the most invasive species in the world. U. europaeus is widely distributed in the south-central area of Chile, which is considered a world hotspot for biodiversity conservation. In addition to its negative effects on the biodiversity of natural ecosystems, U. europaeus is one of the most severe pests for agriculture and forestry. Despite its importance as an invasive species, U. europaeus has been little studied. Although information exists on the potential distribution of the species, the interaction of the invasion process with the spatial dynamic of the landscape and the landscape-scale factors that control the presence or absence of the species is still lacking. We studied the spatial and temporal dynamics of the landscape and how these relate to U. europaeus invasion in south-central Chile. We used supervised classification of satellite images to determine the spatial distribution of the species and other land covers for the years 1986 and 2003, analysing the transitions between the different land covers. We used logistic regression for modelling the increase, decrease and permanence of U. europaeus invasion considering landscape variables. Results showed that the species covers only around 1 % of the study area and showed a 42 % reduction in area for the studied period. However, U. europaeus was the cover type which presented the greatest dynamism in the landscape. We found a strong relationship between changes in land cover and the invasion process, especially connected with forest plantations of exotic species, which promotes the displacement of U. europaeus. The model of gorse cover increase presented the best performance, and the most important predictors were distance to seed source and landscape complexity index. Our model predicted high spread potential of U. europaeus in areas of high conservation value. We conclude that proper management for this invasive species must take into account

  2. Multiproxy approach revealing climate and cultural changes during the last 26kyrs in south-central Chile

    Science.gov (United States)

    Abarzua, Ana M.; Jarpa, Leonora; Martel, Alejandra; Vega, Rodrigo; Pino, Mario

    2010-05-01

    Multiproxy approach from Purén Lumaco Valley (38°S) describes the paleonvironmental history during the Last Maximum Glacial (LGM) in south-central Chile. Three sediment cores and severals AMS 14C dates were used to perform a complete pollen, diatoms, chironomids, and sedimentological records demonstrating the existence of a large and non profundal paleolake, between 25 and 20kyr BP. Some of these evidence are laminated silty-clay sediments (lacustrine rhythmites), associated with the presence of siderite mineral (FeCO3), besides biological proxies like Fragilaria construens and Stauroforma inermes (planctonic diatoms), and Dicrotendipes sp. and Tanytarsini tribe (littoral chironomids). The pollen ensemble reveals the first glacial refuge of Araucaria araucana forests in the low lands during the LGM. The lake was drained abruptly into a swamp/bog at 12kyr BP and colonized by Myrtaceae wet forest. This evidence suggest the dry/warm climate period of early Holocene in south-central Chile. Later, the sediments indicate variable lacustrine levels, and increase of charcoal particles, associated to current climatic conditions. The pollen spectrum dominated by Myrtaceae and Nothofagus contrasts with a strongly disturb current landscape. Actually, Purén-Lumaco valley constitutes a complex peat-bog system dominated by exotic grasses and forest species (Tritricum aestivum, Pinus radiata and Eucalyptus spp.). Some archaeological antecedents in the area document the human development at ca. 7yrs BP. The greatest archaeological characteristic present in the valley is the kuel, a Mapuche earth accumulation. The presence and extension of almost 300 kuel in the valley reflect the social/economic development, and partly explains why the region was the major resistance area for Spanish colonizer during XVI-XVII centuries. Also the archaeological findings reveal the presence of maize pollen (Zea mays) within their food consumption. The influence of climate and human impact in

  3. Microfacies and diagenesis of the reefal limestone, Callovian Tuwaiq Mountain Limestone Formation, central Saudi Arabia

    Science.gov (United States)

    EL-Sorogy, Abdelbaset S.; Almadani, Sattam A.; Al-Dabbagh, Mohammad E.

    2016-03-01

    In order to document the microfacies and diagenesis of the reefal limestone in the uppermost part of the Callovian Tuwaiq Mountain Limestone Formation at Khashm Al-Qaddiyah area, central Saudi Arabia, scleractinian corals and rock samples were collected and thin sections were prepared. Coral framestone, coral floatstone, pelloidal packstone, bioclastic packstone, bioclastic wacke/packstone, algal wackestone and bioclastic foraminiferal wacke/packstone were the recorded microfacies types. Cementation, recrystallization, silicification and dolomitization are the main diagenetic alterations affected the aragonitic skeletons of scleractinian corals. All coral skeletons were recrystallized, while some ones were dolomitized and silicified. Microfacies types, as well as the fossil content of sclearctinian corals, bivalves, gastropods, brachiopods and foraminifera indicated a deposition in environments ranging from shelf lagoon with open circulation in quiet water below wave base to shallow reef flank and organic build up for the uppermost reefal part of the Tuwaiq Formation in the study area.

  4. Three-dimensional facies architecture of the Salem Limestone (middle Mississippian), Eastern Margin of Illinois basin

    Energy Technology Data Exchange (ETDEWEB)

    Nadeem, A.; Keith, B.D.; Thompson, T.A. [Indiana Univ., Bloomington, IN (United States)

    1995-09-01

    Mapping of sedimentary surfaces in the Middle Mississippian Salem Limestone exposed on sawed quarry walls in south-central Indiana has revealed a hierarchy of depositional units representative of the extremely dynamic hydrographic regime of the upper shoreface zone. The depositional units on the scale of microform and mesoform are represented by the microfacies and the facies respectively. Based on their hierarchy, genetically related depositional units and associated bounding surfaces were grouped together to construct four architectural packages (APs) of the scale of mesoforms. AP-I is dominantly an echinoderm- and bryozoan-rich grainstone and consists of bedforms ranging from small ripples bounded by first-order surfaces to two- and three- dimensional megaripples bounded by the second-order surfaces. It formed as part of a giant ramp (asymmetric wavefield) within the intrashoal channel setting. AP-II, also a skeletal grainstone, is a complex of giant sandwaves that moved into the area under the infulence of a storm and partly filled the basal channel form of AP-I. Large avalanche foresets with tangential toesets prevail. AP-III is a dark-gray spatially discontinuous skeletal grainstone to packstone that laterally grades into a skeletal packstone to wackestone. It locally developed overhangs, rips-ups, and hardground on its upper surface. AP-IV is a skeletal and oolitic grainstone formed of tabular two-dimensional megaripples (planar cross-beds) and three-dimensional oscillatory megaripples (trough cross-beds). These architectural packages based on the bedform architecture and micro-and mesoscale compositional changes can be used to characterize micro-, meso, and macroscale heterogeneities. Models of facies architecture from this and similar outcrop studies can be applied to the subsurface Salem reservoirs in the Illinois Basin using cores.

  5. Field trial of a pulsed limestone diversion well

    Science.gov (United States)

    Sibrell, Philip L.; Denholm, C.; Dunn, Margaret

    2013-01-01

    The use of limestone diversion wells to treat acid mine drainage (AMD) is well-known, but in many cases, acid neutralization is not as complete as would be desired. Reasons for this include channeling of the water through the limestone bed, and the slow reaction rate of the limestone gravel. A new approach to improve the performance of the diversion well was tested in the field at the Jennings Environmental Education Center, near Slippery Rock, PA. In this approach, a finer size distribution of limestone was used so as to allow fluidization of the limestone bed, thus eliminating channeling and increasing particle surface area for faster reaction rates. Also, water flow was regulated through the use of a dosing siphon, so that consistent fluidization of the limestone sand could be achieved. Testing began late in the summer of 2010, and continued through November of 2011. Initial system performance during the 2010 field season was good, with the production of net alkaline water, but hydraulic problems involving air release and limestone sand retention were observed. In the summer of 2011, a finer size of limestone sand was procured for use in the system. This material fluidized more readily, but acid neutralization tapered off after several days. Subsequent observations indicated that the hydraulics of the system was compromised by the formation of iron oxides in the pipe leading to the limestone bed, which affected water distribution and flow through the bed. Although results from the field trial were mixed, it is believed that without the formation of iron oxides and plugging of the pipe, better acid neutralization and treatment would have occurred. Further tests are being considered using a different hydraulic configuration for the limestone sand fluidized bed.

  6. Range overlap and individual movements during breeding season influence genetic relationships of caribou herds in south-central Alaska

    Science.gov (United States)

    Roffler, Gretchen H.; Adams, Layne G.; Talbot, Sandra L.; Sage, George K.; Dale, Bruce W.

    2012-01-01

    North American caribou (Rangifer tarandus) herds commonly exhibit little nuclear genetic differentiation among adjacent herds, although available evidence supports strong demographic separation, even for herds with seasonal range overlap. During 1997–2003, we studied the Mentasta and Nelchina caribou herds in south-central Alaska using radiotelemetry to determine individual movements and range overlap during the breeding season, and nuclear and mitochondrial DNA (mtDNA) markers to assess levels of genetic differentiation. Although the herds were considered discrete because females calved in separate regions, individual movements and breeding-range overlap in some years provided opportunity for male-mediated gene flow, even without demographic interchange. Telemetry results revealed strong female philopatry, and little evidence of female emigration despite overlapping seasonal distributions. Analyses of 13 microsatellites indicated the Mentasta and Nelchina herds were not significantly differentiated using both traditional population-based analyses and individual-based Bayesian clustering analyses. However, we observed mtDNA differentiation between the 2 herds (FSTM = 0.041, P

  7. Random and systematic spatial variability of 137Cs inventories at reference sites in South-Central Brazil

    Directory of Open Access Journals (Sweden)

    Correchel Vladia

    2005-01-01

    Full Text Available The precision of the 137Cs fallout redistribution technique for the evaluation of soil erosion rates is strongly dependent on the quality of an average inventory taken at a representative reference site. The knowledge of the sources and of the degree of variation of the 137Cs fallout spatial distribution plays an important role on its use. Four reference sites were selected in the South-Central region of Brazil which were characterized in terms of soil chemical, physical and mineralogical aspects as well as the spatial variability of 137Cs inventories. Some important differences in the patterns of 137Cs depth distribution in the soil profiles of the different sites were found. They are probably associated to chemical, physical, mineralogical and biological differences of the soils but many questions still remain open for future investigation, mainly those regarding the adsorption and dynamics of the 137Cs ions in soil profiles under tropical conditions. The random spatial variability (inside each reference site was higher than the systematic spatial variability (between reference sites but their causes were not clearly identified as possible consequences of chemical, physical, mineralogical variability, and/or precipitation.

  8. Clay mineralogical evidence of a bioclimatically-affected soil, Rouge River basin, South-Central Ontario, Canada

    Science.gov (United States)

    Mahaney, W. C.

    2015-01-01

    Holocene soils in drainage basins of South-Central Ontario, Canada, are generally Fluvisols (Entisols) in floodplains transitioning to Brunisols (Inceptisols), Luvisols (Alfisols) and Podzols (Spodosols) in older terraces and in the glaciated tableland. A single landslide sourced from the highest fluvial terrace in the Rouge basin, with a rubble drop of ~ 12 m emplaced a lobe-shaped mass of reworked stream gravel, glaciolacustrine sediment and till, emplaced approximately 6 m above mean water level at a height roughly equivalent to previously dated mid-Holocene terraces and soils. Clay mineralogy of the soil formed in this transported regolith produced the usual semi-detrital/pedogenic distribution of 1:1 (Si:Al = 1:1), 2:1 and 2:1:1 clay minerals as well as primary minerals consisting of plagioclase feldspar, quartz, mica and calcite. Unexpectedly, the presence of moderate amounts of Ca-smectite in the Bk and Ck horizons, relative to a clay-mineral depleted parent material (Cuk), argues for a soil hydrological change affecting the wetting depth in the deposit. The presence of the uncommon 'maidenhair fern' (Adiantum pedantum) in the mass wasted deposit, a plant capable of high evapotranspiration, is interpreted as producing a bioclimatic disruption limiting soil water penetration to near root depth (wetting depth), thus producing a clay mineral anomaly.

  9. Recent mantle degassing recorded by carbonic spring deposits along sinistral strike-slip faults, south-central Australia

    Science.gov (United States)

    Ring, Uwe; Tonguç Uysal, I.; Yüce, Galip; Ünal-İmer, Ezgi; Italiano, Francesco; İmer, Ali; Zhao, Jian-xin

    2016-11-01

    The interior of the Australian continent shows evidence for late Quaternary to Recent fault-controlled mantle 3He and CO2 degassing. A series of interconnected NW-striking sinistral faults, the Norwest fault zone (NFZ), in south-central Australia are associated with travertine mounds, the latter show a regular spacing of 50-70 km. U-series ages on 26 samples range from 354 ± 7 to 1.19 ± 0.02ka (2σ errors) and suggest a clustering every ∼3-4 ka since ∼26 ka. Geochemical data demonstrate a remarkable mantle-to-groundwater connection. Isotopic data indicate that the groundwater is circulating to depths >3 km and interacting with Neoproterozoic/Cambrian basement and mantle volatiles. 3He/4He isotope ratios show that the He comes in part from the mantle. This demonstrates that the NFZ cuts through the entire crust and provides pathways for mantle degassing. Scaling relationships suggest that the series of sinistral faults that make up the NFZ are interconnected at depths and have a significant strike length of 60-70 km or more. The NFZ occurs where a major compositional boundary and a significant heat flow anomaly occurs, and a major step in lithospheric thickness has been mapped. We discuss a tectonic model in which recent stress field, heat flow and lithospheric structure in central Australia reactivated a set of steeply dipping Neoproterozoic faults, which may now be growing into a crustal/lithospheric-scale structure.

  10. Regional Climate Enterprises in the South Central U.S.: Crossover Relationships to Maximize User Engagement Effectiveness

    Science.gov (United States)

    Langston, M. A.; Shafer, M.; Bartush, B.; Brown, D. P.

    2016-12-01

    Several Federal agencies have recently established regional enterprises that provide climate science and services. These include DOI's Climate Science Centers (CSCs), USDA's Regional Climate Hubs (Hubs), DOI's Landscape Conservation Cooperatives (LCCs), and NOAA's Regional Integrated Sciences and Assessments Programs (RISAs), all of which have missions that include translating climate information for various constituencies and user groups. Each of these organizations makes a unique contribution to the regional climate services landscape; however, the potential for duplication of effort is also present. To ensure that appropriate levels of programmatic coordination are taking place, these entities have developed roles and relationships that crossover between organizations. These efforts have typically not been formally codified or prescribed; rather, they have developed organically and effectively in a fashion appropriate for the regional context. In this presentation, both advantages and disadvantages of this approach are addressed via examples from the South Central U.S. Advantages include flexibility and the development of extensive, multi-disciplinary networks; disadvantages include the lack of a holistic approach to oversight and planning. Best practices and opportunities to continue strengthening cross-organizational regional efficiencies are also highlighted.

  11. Sources and Delivery of Nutrients to the Northwestern Gulf of Mexico from Streams in the South-Central United States

    Science.gov (United States)

    Rebich, R.A.; Houston, N.A.; Mize, S.V.; Pearson, D.K.; Ging, P.B.; Evan, Hornig C.

    2011-01-01

    SPAtially Referenced Regressions On Watershed attributes (SPARROW) models were developed to estimate nutrient inputs [total nitrogen (TN) and total phosphorus (TP)] to the northwestern part of the Gulf of Mexico from streams in the South-Central United States (U.S.). This area included drainages of the Lower Mississippi, Arkansas-White-Red, and Texas-Gulf hydrologic regions. The models were standardized to reflect nutrient sources and stream conditions during 2002. Model predictions of nutrient loads (mass per time) and yields (mass per area per time) generally were greatest in streams in the eastern part of the region and along reaches near the Texas and Louisiana shoreline. The Mississippi River and Atchafalaya River watersheds, which drain nearly two-thirds of the conterminous U.S., delivered the largest nutrient loads to the Gulf of Mexico, as expected. However, the three largest delivered TN yields were from the Trinity River/Galveston Bay, Calcasieu River, and Aransas River watersheds, while the three largest delivered TP yields were from the Calcasieu River, Mermentau River, and Trinity River/Galveston Bay watersheds. Model output indicated that the three largest sources of nitrogen from the region were atmospheric deposition (42%), commercial fertilizer (20%), and livestock manure (unconfined, 17%). The three largest sources of phosphorus were commercial fertilizer (28%), urban runoff (23%), and livestock manure (confined and unconfined, 23%). ?? 2011 American Water Resources Association. This article is a U.S. Government work and is in the public domain in the USA.

  12. Sources and Delivery of Nutrients to the Northwestern Gulf of Mexico from Streams in the South-Central United States.

    Science.gov (United States)

    Rebich, Richard A; Houston, Natalie A; Mize, Scott V; Pearson, Daniel K; Ging, Patricia B; Evan Hornig, C

    2011-10-01

    SPAtially Referenced Regressions On Watershed attributes (SPARROW) models were developed to estimate nutrient inputs [total nitrogen (TN) and total phosphorus (TP)] to the northwestern part of the Gulf of Mexico from streams in the South-Central United States (U.S.). This area included drainages of the Lower Mississippi, Arkansas-White-Red, and Texas-Gulf hydrologic regions. The models were standardized to reflect nutrient sources and stream conditions during 2002. Model predictions of nutrient loads (mass per time) and yields (mass per area per time) generally were greatest in streams in the eastern part of the region and along reaches near the Texas and Louisiana shoreline. The Mississippi River and Atchafalaya River watersheds, which drain nearly two-thirds of the conterminous U.S., delivered the largest nutrient loads to the Gulf of Mexico, as expected. However, the three largest delivered TN yields were from the Trinity River/Galveston Bay, Calcasieu River, and Aransas River watersheds, while the three largest delivered TP yields were from the Calcasieu River, Mermentau River, and Trinity River/Galveston Bay watersheds. Model output indicated that the three largest sources of nitrogen from the region were atmospheric deposition (42%), commercial fertilizer (20%), and livestock manure (unconfined, 17%). The three largest sources of phosphorus were commercial fertilizer (28%), urban runoff (23%), and livestock manure (confined and unconfined, 23%).

  13. Molecular characterisation of Cryptosporidium spp. in lambs in the South Central region of the State of São Paulo

    Directory of Open Access Journals (Sweden)

    A.S. Zucatto

    2015-04-01

    Full Text Available Considering the proximity of sheep farmers to animals that are possibly diseased or releasing fecal oocysts into the environment and the marked pathogenicity in lambs, the aim of this study was to determine the occurrence and to molecularly characterize the infection by Cryptosporidium spp. in lambs in the South Central region of the state of São Paulo, Brazil. A total of 193 fecal samples were collected from sheep of several breeds, males and females, aged up to one year. Polymerase chain reaction (nested-PCR was used to amplify DNA fragments from the subunit 18S rRNA gene and indicated 15% positivity; sequencing of amplified fragments was possible for 19 samples. Analysis of the obtained sequences showed that the identified species were Cryptosporidium xiaoi for 15 samples, constituting thus the first molecular characterization study of this Cryptosporidium species in Brazil. Cryptosporidium ubiquitum was identified for three samples and Cryptosporidium meleagridis for one sample; the latter two are considered zoonotic species.

  14. Rock-Eval pyrolysis and vitrinite reflectance results from the Sheep Creek 1 well, Susitna basin, south-central Alaska

    Science.gov (United States)

    Stanley, Richard G.; Lillis, Paul G.; Pawlewicz, Mark J.; Haeussler, Peter J.

    2014-01-01

    We used Rock-Eval pyrolysis and vitrinite reflectance to examine the petroleum source potential of rock samples from the Sheep Creek 1 well in the Susitna basin of south-central Alaska. The results show that Miocene nonmarine coal, carbonaceous shale, and mudstone are potential sources of hydrocarbons and are thermally immature with respect to the oil window. In the samples that we studied, coals are more organic-rich and more oil-prone than carbonaceous shales and silty mudstones, which appear to be potential sources of natural gas. Lithologically similar rocks may be present in the deeper parts of the subsurface Susitna basin located west of the Sheep Creek 1 well, where they may have been buried deeply enough to generate oil and (or) gas. The Susitna basin is sparsely drilled and mostly unexplored, and no commercial production of hydrocarbons has been obtained. However, the existence of potential source rocks of oil and gas, as shown by our Rock-Eval results, suggests that undiscovered petroleum accumulations may be present in the Susitna basin.

  15. Patterns of fish community composition along a river affected by agricultural and urban disturbance in south-central Chile

    Energy Technology Data Exchange (ETDEWEB)

    Orrego, Rodrigo [University of Ontario Institute of Technology, Oshawa, Ontario; Barra, Ricardo [University of Concepcion, Eula, Chile; Chiang, Gustavo [University of Concepcion, Eula, Chile; Adams, Marshall [ORNL; Gavilan, Juan F. [University of Concepcion, Eula, Chile

    2008-03-01

    Patterns of fish community composition in a south-central Chile river were investigated along the altitudinal-spatial and environmental gradient and as a function of anthropogenic factors. The spatial pattern of fish communities in different biocoenotic zones of the Chillan River is influenced by both natural factors such a hydrologic features, habitat, and feeding types, and also by water quality variables which can reduce the diversity and abundance of sensitive species. A principal component analysis incorporating both water quality parameters and biomarker responses of representative fish species was used to evaluate the status of fish communities along the spatial gradient of the stream. The abundance and diversity of the fish community changed from a low in the upper reaches where the low pollution-tolerant species such as salmonid dominated, to a reduced diversity in the lower reaches of the river where tolerant browser species such as cypriniformes dominated. Even though the spatial pattern of fish community structure is similar to that found for the Chilean Rivers, the structure of these communities is highly influenced by human disturbance, particularly along the lower reaches of the river.

  16. Depositional environments and sequence stratigraphy of the Bahram Formation (middleelate Devonian) in north of Kerman, south-central Iran

    Institute of Scientific and Technical Information of China (English)

    Afshin Hashmie; Ali Rostamnejad; Fariba Nikbakht; Mansour Ghorbanie; Peyman Rezaie; Hossien Gholamalian

    2016-01-01

    This study is focused on sedimentary environments, facies distribution, and sequence stratigraphy. The facies and sequence stratigraphic analyses of the Bahram Formation (middleelate Devonian) in south-central Iran are based on two measured stratigraphic sections in the southern Tabas block. The Bah-ram Formation overlies red sandstones Padeha Formation in sections Hutk and Sardar and is overlain by Carboniferous carbonate deposits of Hutk Formation paraconformably, with a thickness of 354 and 386 m respectively. Mixed siliciclastic and carbonate sediments are present in this succession. The field observations and laboratory studies were used to identify 14 micro/petrofacies, which can be grouped into 5 depositional environments: shore, tidal flat, lagoon, shoal and shallow open marine. A mixed carbonate-detrital shallow shelf is suggested for the depositional environment of the Bahram Formation which deepens to the east (Sardar section) and thins in southern locations (Hutk section). Three 3rd-order cyclic siliciclastic and carbonate sequences in the Bahram Formation and one sequence shared with the overlying joint with Hutk Formation are identified, on the basis of shallowing upward patterns in the micro/pertofacies.

  17. Late Holocene spatial patterns of coseismic land level changes and earthquake rupture areas, south-central Alaska

    Science.gov (United States)

    Shennan, I.; Barlow, N.; Watcham, E.

    2010-12-01

    Previous investigations of multiple late Holocene earthquake events in Cook Inlet suggest different spatial patterns of co-seismic subsidence for the 1964, ~900 BP and ~1500 BP great earthquakes . One hypothesis to explain these differences is that they record variations in the location, extent or depth of the rupture zone. Testing this hypothesis is important if we are to reduce uncertainties regarding the nature of future earthquake hazard in south central Alaska and improve our understanding of the nature of past earthquake ruptures in this region. Here we study sites beyond Cook Inlet to address the issue of spatial variability; Copper River Delta and Cape Suckling record coseismic uplift, Middle Bay and Anton Larson Bay, Kodiak Island, record coseismic subsidence. The 1964 rupture involved two segments (Kodiak and Prince William Sound) of the Aleutian Megathrust. We aim to quantify coseismic deformation for three Late Holocene earthquakes: ~500BP, a single segment rupture of the Kodiak segment; and ~900 and ~1500BP earthquakes that we consider involved simultaneous rupturing of three segments. These are the Kodiak and Prince William Sound segments and the adjacent segment extending to the Pamplona - Malaspina thrust front in the east. In this scenario, the Yakataga seismic gap ruptures in conjunction with the Aleutian megathrust.

  18. Use of Potential Fields Data to Identify Petrological Controls on Seismicity within South-Central and Southeastern Alaska

    Science.gov (United States)

    Doser, D. I.; Veilleux, A. M.; Rodriguez, H.; de La Pena, A.; Mankhemthong, N.

    2010-12-01

    We have used data from regional gravity and aeromagnetic surveys to determine how variations in petrological properties of the upper plate(s) and subducting lower plate(s) influence the concentration of background seismicity in south-central and southeastern Alaska, as well as possible controls on asperities that ruptured during great earthquakes along the plate margin. In the Prince William Sound region it appears that seismicity concentrates at the edges of mafic and ultramafic bodies within the upper (North American) plate, while within Cook Inlet upper plate seismicity concentrates at the edges of a large serpentinite body. Rupture segmentation during the 1958 Fairweather earthquake in southeastern Alaska is associated with gravity highs along the Fairweather fault, while segmentation of the Queen Charlotte fault system appears related to changes in the structure of the Pacific plate. Although gravity coverage within the St. Elias region is sparse, background seismicity at depths of 10 to 20 km, including aftershocks of the 1979 Mw=7.4 St. Elias event, wraps around the edge of a gravity high located at the intersection of the Pamplona and Chugach-St. Elias fault systems. These results emphasize how additional gravity and magnetic data collection should be included as part of the upcoming Earthscope initiative in Alaska.

  19. Variations Of Surface Deformation And Lateral Extent Of Ruptures In Sequential Earthquake Deformation Cycles, South Central Alaska

    Science.gov (United States)

    Shennan, I.; Barlow, N.; Bruhn, R. L.

    2009-12-01

    Multidisciplinary studies in south central Alaska provide evidence of at least 7 great earthquakes during the past 4000 yr, including the Mw = 9.2 earthquake of March 27th 1964. Using new data collected in 2009 we demonstrate variations in coseismic deformation by using stratigraphic and microfossil data to reconstruct relative sea-level changes in coastal sediment sequences through earthquake cycles. The key theme that arises over timescales of the last few millennia is one of temporal and spatial variability of surface deformation. Quantitative data show both temporal and spatial similarities and differences for different earthquake cycles. We find there is no fixed recurrence interval between great earthquakes. The shortest interval is between ~180 and 720 years. The longest interval is ~790 - 920 years, which is between the penultimate, ~900 BP, and the 1964 earthquakes. The 1964 rupture involved two segments (Kodiak and Prince William Sound) of the Aleutian Megathrust. Using data from sites in upper Cook Inlet, recording coseismic subsidence in 1964, between Copper River Delta and Cape Suckling, coseismic uplift in 1964, and the Yakataga coast to Icy Bay, no uplift in 1964, we have evidence to suggest simultaneous rupturing ~900BP and ~1500BP of three segments of the megathrust. These are two that formed the 1964 rupture zone and the adjacent segment extending to the Pamplona - Malaspina thrust front in the east. In this scenario the Yakataga seismic gap ruptures in conjunction with the Aleutian megathrust.

  20. Geology, thermal maturation, and source rock geochemistry in a volcanic covered basin: San Juan sag, south-central Colorado

    Energy Technology Data Exchange (ETDEWEB)

    Gries, R.R. [Priority Oil & Gas, Denver, CO (United States); Clayton, J.L. [Geological Survey, Denver, CO (United States); Leonard, C. [Platte River Associates, Denver, CO (United States)

    1997-07-01

    The San Juan sag, concealed by the vast San Juan volcanic field of south-central Colorado, has only recently benefited from oil and gas wildcat drilling and evaluations. Sound geochemical analyses and maturation modeling are essential elements for successful exploration and development. Oil has been produced in minor quantities from an Oligocene sill in the Mancos Shale within the sag, and major oil and gas production occurs from stratigraphically equivalent rocks in the San Juan basin to the southwest and in the Denver basin to the northeast. The objectives of this study were to identify potential source rocks, assess thermal maturity, and determine hydrocarbon-source bed relationships. Source rocks are present in the San Juan sag in the upper and lower Mancos Shale (including the Niobrara Member), which consists of about 666 m (2184 ft) of marine shale with from 0.5 to 3.1 wt. % organic carbon. Pyrolysis yields (S{sub 1} + S{sub 2} = 2000-6000 ppm) and solvent extraction yields (1000-4000 ppm) indicate that some intervals within the Mancos Shale are good potential source rocks for oil, containing type II organic matter, according to Rock-Eval pyrolysis assay.

  1. Effects of mercury deposition and coniferous forests on the mercury contamination of fish in the South Central United States.

    Science.gov (United States)

    Drenner, Ray W; Chumchal, Matthew M; Jones, Christina M; Lehmann, Christopher M B; Gay, David A; Donato, David I

    2013-02-05

    Mercury (Hg) is a toxic metal that is found in aquatic food webs and is hazardous to human and wildlife health. We examined the relationship between Hg deposition, land coverage by coniferous and deciduous forests, and average Hg concentrations in largemouth bass (Micropterus salmoides)-equivalent fish (LMBE) in 14 ecoregions located within all or part of six states in the South Central U.S. In 11 ecoregions, the average Hg concentrations in 35.6-cm total length LMBE were above 300 ng/g, the threshold concentration of Hg recommended by the U.S. Environmental Protection Agency for the issuance of fish consumption advisories. Percent land coverage by coniferous forests within ecoregions had a significant linear relationship with average Hg concentrations in LMBE while percent land coverage by deciduous forests did not. Eighty percent of the variance in average Hg concentrations in LMBE between ecoregions could be accounted for by estimated Hg deposition after adjusting for the effects of coniferous forests. Here we show for the first time that fish from ecoregions with high atmospheric Hg pollution and coniferous forest coverage pose a significant hazard to human health. Our study suggests that models that use Hg deposition to predict Hg concentrations in fish could be improved by including the effects of coniferous forests on Hg deposition.

  2. Can We Mitigate Climate Extremes using Managed Aquifer Recharge: Case Studies California Central Valley and South-Central Arizona, USA

    Science.gov (United States)

    Scanlon, B. R.; Reedy, R. C.; Faunt, C. C.; Pool, D. R.; Uhlman, K.

    2015-12-01

    Frequent long-term droughts interspersed with intense floods in the southwestern U.S. underscore the need to store more water to manage these climate extremes. Here we show how managed aquifer recharge can enhance drought resilience in the southwestern U.S. with ~ 70% of California under extreme drought and 75% of Arizona under moderate drought. Data on water sources, transportation, and users were compiled for managed aquifer recharge systems in the Central Valley and south-central Arizona. Groundwater depletion of 115 to 145 km3 in the 1900s created large subsurface reservoirs in thick alluvial basins in these regions. Large canals and aqueducts up to several 100 km long allow water to be imported from reservoirs, mostly in more humid regions. Imported water is either used instead of groundwater or is applied in surface spreading basins primarily during wet periods (≤1.3 km3/yr Central Valley, ≤0.7 km3/yr Arizona) and is extracted during droughts. The dominant water users include irrigators and municipalities both within and outside the managed aquifer recharge systems. Groundwater modeling indicates that recharge basins significantly increase groundwater storage in the Central Valley. Managed aquifer recharge systems significantly enhance drought resilience and increase sustainability of water resources in semiarid regions, complementing surface water reservoirs and conjunctive surface water/groundwater use by providing longer term storage.

  3. United Arab Emirates limestones: impact of petrography on thermal behavior

    Science.gov (United States)

    Alaabed, Sulaiman; Soltan, Abdel Monem; Abdelghany, Osman; Amin, Bahaa Eldin Mahmoud; El Tokhi, Mohamed; Khaleel, Abbas; Musalim, Abdullah

    2014-12-01

    The thermal behavior of selected limestones from representative localities of the United Arab Emirates is investigated for their suitability for soft-burnt lime production. The limestone samples were collected from the Ghalilah, Musandam, Shauiba, Muthaymimah, Dammam and Asmari formations. The samples were characterized for petrography, mineral and chemical composition, together with physico-mechanical characteristics. Investigative methods included transmitted light microscopy (TLM), cathodoluminescence (CLM) and scanning electron microscopy (SEM), as well as X-ray micro-tomography (μ-CT), XRD, XRF and Archimedes method. The limestone samples were fired in an electrical muffle furnace for 0.25, 0.5, 1 and 2 hours at 800, 900, 1,000 and 1,100 °C. After firing the lime grains were tested to determine their hydration rate and microfabric. The Ghalilah and Musandam limes show the lowest and highest maximum hydration rates, respectively, due mainly to the impure nature of the former, and the smaller lime crystallites and dominance of post-calcination micro-cracks of the latter. The Dammam and Asmari limes preserve a "ghost" microfabric of the original limestone. Higher allochem contents impose lower activation energy requirements for calcination, which implies earlier calcination of the allochems. The Musandam, Shauiba and Muthaymimah limestones may be useful for the production of reactive soft-burnt lime under the applied firing conditions, however, the Dammam and Asmari limestones need more advanced calcination conditions than the applied ones. The Ghalilah limestone was found to be unsuitable for the production of lime.

  4. Limestone quarry becomes a wind farm

    Energy Technology Data Exchange (ETDEWEB)

    Wizelius, T. [Vindform (Sweden)

    2000-06-01

    A former limestone quarry on the coast at Smoejen in eastern Gotland, Sweden, has been converted into a wind farm delivering 10 MW of electricity to the grid. Two Enercon turbines were installed at the site in 1995 and a further eight Vestas turbines in 1999; the latter cost 80 million SEK (US$9.6 million), including 11 million SEK for grid connection. The wind farm's expansion in 1999 involved construction of new access roads and extensive foundations on which to mount the four 660 kW and four 1.65 MW turbines. Grid connection is a significant issue as the wind farm is expected to generate some 27 GWh/year. The eight new turbines have internal transformers connected underground to interlocking plants. One of the reasons for using different sizes of turbines is to alleviate environmental concerns; the larger turbines are located within the quarry, thus reducing the number of trees felled and improving the wind farm's visual appearance.

  5. Residual CO2 trapping in Indiana limestone.

    Science.gov (United States)

    El-Maghraby, Rehab M; Blunt, Martin J

    2013-01-01

    We performed core flooding experiments on Indiana limestone using the porous plate method to measure the amount of trapped CO(2) at a temperature of 50 °C and two pressures: 4.2 and 9 MPa. Brine was mixed with CO(2) for equilibration, then the mixture was circulated through a sacrificial core. Porosity and permeability tests conducted before and after 884 h of continuous core flooding confirmed negligible dissolution. A trapping curve for supercritical (sc)CO(2) in Indiana showing the relationship between the initial and residual CO(2) saturations was measured and compared with that of gaseous CO(2). The results were also compared with scCO(2) trapping in Berea sandstone at the same conditions. A scCO(2) residual trapping end point of 23.7% was observed, indicating slightly less trapping of scCO(2) in Indiana carbonates than in Berea sandstone. There is less trapping for gaseous CO(2) (end point of 18.8%). The system appears to be more water-wet under scCO(2) conditions, which is different from the trend observed in Berea; we hypothesize that this is due to the greater concentration of Ca(2+) in brine at higher pressure. Our work indicates that capillary trapping could contribute to the immobilization of CO(2) in carbonate aquifers.

  6. Trends analyses of 30 years of ambient 8 hour ozone and precursor monitoring data in the South Central U.S.: progress and challenges.

    Science.gov (United States)

    Sather, Mark E; Cavender, Kevin

    2016-07-13

    In the last 30 years ambient ozone concentrations have notably decreased in the South Central U.S. Yet, current ambient ozone concentrations measured over the past three years 2013-2015 in this area of the U.S. are not meeting the U.S. 2015 8 hour ozone standard of 70 parts per billion (ppb). This paper provides an update on long-term trends analyses of ambient 8 hour ozone and ozone precursor monitoring data collected over the past 30 years (1986-2015) in four South Central U.S. cities, following up on two previously published reviews of 20 and 25 year trends for these cities. All four cities have benefitted from national ozone precursor controls put in place during the 1990s and 2000s involving cleaner vehicles (vehicle fleet turnover/replacement over time), cleaner fuels, cleaner gasoline and diesel engines, and improved inspection/maintenance programs for existing vehicles. Additional ozone precursor emission controls specific to each city are detailed in this paper. The controls have resulted in impressive ambient ozone and ambient ozone precursor concentration reductions in the four South Central U.S. cities over the past 30 years, including 31-70% ambient nitrogen oxides (NOx) concentration declines from historical peaks to the present, 43-72% volatile organic compound (VOC) concentration declines from historical peaks to the present, a related 45-76% VOC reactivity decline for a subset of VOC species from historical peaks to the present, and an 18-38 ppb reduction in city 8 hour ozone design value concentrations. A new challenge for each of the four South Central U.S. cities will be meeting the U.S. 2015 8 hour ozone standard of 70 ppb.

  7. Remarks on Echinodermata from the South Central Mediterranean Sea based upon collections made during the MARCOS cruise (10 to 20th April, 2007)

    OpenAIRE

    2009-01-01

    The MARCOS cruise, which took place in the South Central Mediterranean Sea on board the RV ‘Urania’, resulted in the collection of 27 species of Echinodermata from shallow to bathyal depths, many from around Malta (the Fisheries Management Zone). The fauna is represented by common to rare taxa already reported from the Mediterranean with the exception of the amphi-Atlantic ophiuroid Ophiotreta valenciennesi rufescens (Koehler, 1896), recorded from the Mediterranean Basin for the first time. O...

  8. Northward extension of Carolina slate belt stratigraphy and structure, South-Central Virginia: Results from geologic mapping

    Science.gov (United States)

    Hackley, P.C.; Peper, J.D.; Burton, W.C.; Horton, J.W.

    2007-01-01

    Geologic mapping in south-central Virginia demonstrates that the stratigraphy and structure of the Carolina slate belt extend northward across a steep thermal gradient into upper amphibolite-facies correlative gneiss and schist. The Neoproterozoic greenschist-facies Hyco, Aaron, and Virgilina Formations were traced northward from their type localities near Virgilina, Virginia, along a simple, upright, northeast-trending isoclinal syncline. This syncline is called the Dryburg syncline and is a northern extension of the more complex Virgilina synclinorium. Progressively higher-grade equivalents of the Hyco and Aaron Formations were mapped northward along the axial trace of the refolded and westwardly-overturned Dryburg syncline through the Keysville and Green Bay 7.5-minute quadrangles, and across the northern end of the Carolina slate belt as interpreted on previous geologic maps. Hyco rocks, including felsic metatuff, metawacke, and amphibolite, become gneisses upgrade with areas of local anatexis and the segregation of granitic melt into leucosomes with biotite selvages. Phyllite of the Aaron Formation becomes garnet-bearing mica schist. Aaron Formation rocks disconformably overlie the primarily felsic volcanic and volcaniclastic rocks of the Hyco Formation as evidenced by repeated truncation of internal contacts within the Hyco on both limbs of the Dryburg syncline at the Aaron-Hyco contact. East-northeast-trending isograds, defined successively by the first appearance of garnet, then kyanite ?? staurolite in sufficiently aluminous rocks, are superposed on the stratigraphic units and synclinal structure at moderate to high angles to strike. The textural distinction between gneisses and identifiable sedimentary structures occurs near the kyanite ?? staurolite-in isograd. Development of the steep thermal gradient and regional penetrative fabric is interpreted to result from emplacement of the Goochland terrane adjacent to the northern end of the slate belt during

  9. Chemical and isotope characteristics of a tufa-precipitating stream in Karwów (south-central Poland)

    Science.gov (United States)

    Duliński, Marek; Gradziński, Michał; Motyka, Jacek; Czop, Mariusz

    2016-04-01

    Chemical and isotope composition of a tufa-precipitating spring located in Karwów (south-central Poland) is described with the emphasis on the CO2-H2O-CaCO3 system. Carbonate solution is formed with participation of biogenic carbon dioxide and appears at the surface close to saturation state with respect to calcite. At the outflow of the spring the water is characterized by long-term stability of physical and chemical parameters. Along the course of the spring the tufa bed is formed as a result of CO2 outgassing. The carbon and oxygen isotope investigations were performed both on water solutions and the tufa calcite precipitated on CaCO3 plates exposed in water for different periods of time. In general, results of the 13C analyses and numerical modeling using NETPATH code suggest that calcite is precipitated close to carbon isotope equilibrium conditions except for the situations when the extreme outgassing of CO2 takes place. Several measured precipitate samples have shown distinctly lower δ18O values than expected for tufa formation under equilibrium conditions. This cannot be explained by kinetic effects known from karstic caves or lake studies as they lead to higher δ18O values of precipitated carbonates than at isotope equilibrium. Also, short-term fluctuations of water temperature cannot be responsible for the observed deviations in oxygen isotope composition of measured tufa samples from equilibrium values. Further work is needed to better understand the factors controlling 18O isotope composition of tufa deposits.

  10. Estimation of streamflow gains and losses in the lower San Antonio River watershed, south-central Texas, 2006-10

    Science.gov (United States)

    Lizarraga, Joy S.; Wehmeyer, Loren L.

    2012-01-01

    The U.S. Geological Survey (USGS), in cooperation with the San Antonio River Authority, the Evergreen Underground Water Conservation District, and the Goliad County Groundwater Conservation District, investigated streamflow gains and losses during 2006-10 in the lower San Antonio River watershed in south-central Texas. Streamflow gains and losses were estimated using 2006-10 continuous streamflow records from 11 continuous streamflow-gaging stations, and discrete streamflow measurements made at as many as 20 locations on the San Antonio River and selected tributaries during four synoptic surveys during 2006-7. From the continuous streamflow records, the greatest streamflow gain on the lower San Antonio River occurred in the reach from Falls City, Tex., to Goliad, Tex. The greatest streamflow gain on Cibolo Creek during 2006-10 occurred in the reach from near Saint Hedwig, Tex., to Sutherland Springs, Tex. The San Antonio River between Floresville, Tex., and Falls City was the only reach that had an estimated streamflow loss during 2006-10. During all four synoptic streamflow measurement surveys, the only substantially flowing tributary reach to the main stem of the lower San Antonio River was Cibolo Creek. Along the main stem of the lower San Antonio River, verifiable gains larger than the potential measurement error were estimated in two of the four synoptic streamflow measurement surveys. These gaining reaches occurred in the two most downstream reaches of the San Antonio River between Goliad and Farm Road (FM) 2506 near Fannin, Tex., and between FM 2506 near Fannin to near McFaddin. There were verifiable gains in streamflow in Cibolo Creek, between La Vernia, Tex., and the town of Sutherland Springs during all four surveys, estimated at between 4.8 and 14 ft3/s.

  11. Streamflow gain and loss and water quality in the upper Nueces River Basin, south-central Texas, 2008-10

    Science.gov (United States)

    Banta, J. Ryan; Lambert, Rebecca B.; Slattery, Richard N.; Ockerman, Darwin J.

    2012-01-01

    The U.S. Geological Survey-in cooperation with the U.S. Army Corps of Engineers, The Nature Conservancy, the Real Edwards Conservation and Reclamation District, and the Texas Parks and Wildlife Department-investigated streamflow gain and loss and water quality in the upper Nueces River Basin, south-central Texas, specifically in the watersheds of the West Nueces, Nueces, Dry Frio, Frio, and Sabinal Rivers upstream from the Edwards aquifer outcrop. Streamflow in these rivers is sustained by groundwater contributions (for example, from springs) and storm runoff from rainfall events. To date (2012), there are few data available that describe streamflow and water-quality conditions of the rivers within the upper Nueces River Basin. This report describes streamflow gain-loss characteristics from three reconnaissance-level synoptic measurement surveys (hereinafter referred to as "surveys") during 2008-10 in the upper Nueces River Basin. To help characterize the hydrology, groundwater-level measurements were made, and water-quality samples were collected from both surface-water and groundwater sites in the study area from two surveys during 2009-10. The hydrologic (streamflow, springflow, and groundwater) measurements were made during three reconnaissance-level synoptic measurement surveys occurring in July 21-23, 2008; August 8-18, 2009; and March 22-24, 2010. These survey periods were selected to represent different hydrologic conditions. Streamflow gains and losses were based on streamflow and springflow measurements made at 74 sites in the study area, although not all sites were measured during each survey. Possible water chemistry relations among sample types (streamflow, springflow, or groundwater), between surveys, and among watersheds were examined using water-quality samples collected from as many as 20 sites in the study area.

  12. Compositional data supports decentralized model of production and circulation of artifacts in the pre-Columbian south-central Andes.

    Science.gov (United States)

    Lazzari, Marisa; Pereyra Domingorena, Lucas; Stoner, Wesley D; Scattolin, María Cristina; Korstanje, María Alejandra; Glascock, Michael D

    2017-05-16

    The circulation and exchange of goods and resources at various scales have long been considered central to the understanding of complex societies, and the Andes have provided a fertile ground for investigating this process. However, long-standing archaeological emphasis on typological analysis, although helpful to hypothesize the direction of contacts, has left important aspects of ancient exchange open to speculation. To improve understanding of ancient exchange practices and their potential role in structuring alliances, we examine material exchanges in northwest Argentina (part of the south-central Andes) during 400 BC to AD 1000 (part of the regional Formative Period), with a multianalytical approach (petrography, instrumental neutron activation analysis, laser ablation inductively coupled plasma mass spectrometry) to artifacts previously studied separately. We assess the standard centralized model of interaction vs. a decentralized model through the largest provenance database available to date in the region. The results show: (i) intervalley heterogeneity of clays and fabrics for ordinary wares; (ii) intervalley homogeneity of clays and fabrics for a wide range of decorated wares (e.g., painted Ciénaga); (iii) selective circulation of two distinct polychrome wares (Vaquerías and Condorhuasi); (iv) generalized access to obsidian from one major source and various minor sources; and (v) selective circulation of volcanic rock tools from a single source. These trends reflect the multiple and conflicting demands experienced by people in small-scale societies, which may be difficult to capitalize by aspiring elites. The study undermines centralized narratives of exchange for this period, offering a new platform for understanding ancient exchange based on actual material transfers, both in the Andes and beyond.

  13. Summary statistics and graphical comparisons of historical hydrologic and water-quality data, Seco Creek Watershed, South-Central Texas

    Science.gov (United States)

    Brown, David W.; Slattery, Richard N.; Gilhousen, Jon R.

    1998-01-01

    The U.S. Geological Survey collected hydrologic (rainfall, streamflow, and reservoir content) and water-quality data in the Seco Creek watershed, south-central Texas. Most of the data from 15 sites were collected as part of a study in cooperation with the U.S. Department of Agriculture and the Texas State Soil and Water Conservation Board to evaluate the effects of agricultural best-management practices on surface- and ground-water quantity and quality in the 255-square-mile watershed. Nearly 400 best-management practices at 58 sites were implemented by landowners in the watershed during March 1990-September 1995. Most of the data are from the early 1990s, the period during and after implementation of best-management practices. Data from five sites include water quality and are summarized in tables and graphics in the text; and data from all 15 sites are summarized on a diskette. Maximum annual rainfall among the sites for which data are presented in the text (excluding one site) for the during-and-after-implementation period (March 1990-September 1995) was 53.27 inches in water year 1992. Maximum annual total streamflow among the sites for the period was 63,400 acre-feet, also in water year 1992. At the one site with water-quality data (under base-flow conditions) for both the before-implementation period and the during-and-after implementation period of best-management practices, percentiles (5, 25, 50, 75, 95) for specific conductance, nitrate concentration, and fecal coliform density were less for the during-and-after-implementation period than for the before-implementation period.

  14. Tree-ring isotopes reveal drought sensitivity in trees killed by spruce beetle outbreaks in south-central Alaska.

    Science.gov (United States)

    Csank, Adam Z; Miller, Amy E; Sherriff, Rosemary L; Berg, Edward E; Welker, Jeffrey M

    2016-10-01

    Increasing temperatures have resulted in reduced growth and increased tree mortality across large areas of western North American forests. We use tree-ring isotope chronologies (δ(13) C and δ(18) O) from live and dead trees from four locations in south-central Alaska, USA, to test whether white spruce trees killed by recent spruce beetle (Dendroctonus rufipennis Kirby) outbreaks showed evidence of drought stress prior to death. Trees that were killed were more sensitive to spring/summer temperature and/or precipitation than trees that survived. At two of our sites, we found greater correlations between the δ(13) C and δ(18) O chronologies and spring/summer temperatures in dead trees than in live trees, suggesting that trees that are more sensitive to temperature-induced drought stress are more likely to be killed. At one site, the difference between δ(13) C in live and dead trees was related to winter/spring precipitation, with dead trees showing stronger correlations between δ(13) C and precipitation, again suggesting increased water stress in dead trees. At all sites where δ(18) O was measured, δ(18) O chronologies showed the greatest difference in climate response between live and dead groups, with δ(18) O in live trees correlating more strongly with late winter precipitation than dead trees. Our results indicate that sites where trees are already sensitive to warm or dry early growing-season conditions experienced the most beetle-kill, which has important implications for forecasting future mortality events in Alaska.

  15. Structured decision making for conservation of bull trout (Salvelinus confluentus) in Long Creek, Klamath River Basin, south-central Oregon

    Science.gov (United States)

    Benjamin, Joseph R.; McDonnell, Kevin; Dunham, Jason B.; Brignon, William R.; Peterson, James T.

    2017-06-21

    With the decline of bull trout (Salvelinus confluentus), managers face multiple, and sometimes contradictory, management alternatives for species recovery. Moreover, effective decision-making involves all stakeholders influenced by the decisions (such as Tribal, State, Federal, private, and non-governmental organizations) because they represent diverse objectives, jurisdictions, policy mandates, and opinions of the best management strategy. The process of structured decision making is explicitly designed to address these elements of the decision making process. Here we report on an application of structured decision making to a population of bull trout believed threatened by high densities of nonnative brook trout (S. fontinalis) and habitat fragmentation in Long Creek, a tributary to the Sycan River in the Klamath River Basin, south-central Oregon. This involved engaging stakeholders to identify (1) their fundamental objectives for the conservation of bull trout, (2) feasible management alternatives to achieve their objectives, and (3) biological information and assumptions to incorporate in a decision model. Model simulations suggested an overarching theme among the top decision alternatives, which was a need to simultaneously control brook trout and ensure that the migratory tactic of bull trout can be expressed. More specifically, the optimal management decision, based on the estimated adult abundance at year 10, was to combine the eradication of brook trout from Long Creek with improvement of downstream conditions (for example, connectivity or habitat conditions). Other top decisions included these actions independently, as well as electrofishing removal of brook trout. In contrast, translocating bull trout to a different stream or installing a barrier to prevent upstream spread of brook trout had minimal or negative effects on the bull trout population. Moreover, sensitivity analyses suggested that these actions were consistently identified as optimal across

  16. Stratigraphic and geochemical evolution of an oceanic arc upper crustal section: The Jurassic Talkeetna Volcanic Formation, south-central Alaska

    Science.gov (United States)

    Clift, P.D.; Draut, A.E.; Kelemen, P.B.; Blusztajn, J.; Greene, A.

    2005-01-01

    The Early Jurassic Talkeetna Volcanic Formation forms the upper stratigraphic level of an oceanic volcanic arc complex within the Peninsular Terrane of south-central Alaska. The section comprises a series of lavas, tuffs, and volcaniclastic debris-How and flow turbidite deposits, showing significant lateral facies variability. There is a general trend toward more volcaniclastic sediment at the top of the section and more lavas and tuff breccias toward the base. Evidence for dominant submarine, mostly mid-bathyal or deeper (>500 m) emplacement is seen throughout the section, which totals ???7 km in thickness, similar to modern western Pacific arcs, and far more than any other known exposed section. Subaerial sedimentation was rare but occurred over short intervals in the middle of the section. The Talkeetna Volcanic Formation is dominantly calc-alkatine and shows no clear trend to increasing SiO2 up-section. An oceanic subduction petrogenesis is shown by trace element and Nd isotope data. Rocks at the base of the section show no relative enrichment of light rare earth elements (LREEs) versus heavy rare earth elements (REES) or in melt-incompatible versus compatible high field strength elements (HFSEs). Relative enrichment of LREEs and HFSEs increases slightly up-section. The Talkeetna Volcanic Formation is typically more REE depleted than average continental crust, although small volumes of light REE-enriched and heavy REE-depleted mafic lavas are recognized low in the stratigraphy. The Talkeetna Volcanic Formation was formed in an intraoceanic arc above a north-dipping subduction zone and contains no preserved record of its subsequent collisions with Wrangellia or North America. ?? 2005 Geological Society of America.

  17. Dublin South Central (DSC)

    LENUS (Irish Health Repository)

    O'Gorman, Clodagh S M

    2010-12-01

    Children who appear healthy, even if they have one or more recognized cardiovascular risk factors, do not generally have outcomes of cardiovascular or other vascular disease during childhood. Historically, pediatric medicine has not aggressively screened for or treated cardiovascular risk factors in otherwise healthy children. However, studies such as the P-Day Study (Pathobiological Determinants of Atherosclerosis in Youth), and the Bogalusa Heart Study, indicate that healthy children at remarkably young ages can have evidence of significant atherosclerosis. With the increasing prevalence of pediatric obesity, can we expect more health problems related to the consequences of pediatric dyslipidemia, hypertriglyceridemia, and atherosclerosis in the future? For many years, medications have been available and used in adult populations to treat dyslipidemia. In recent years, reports of short-term safety of some of these medications in children have been published. However, none of these studies have detailed long-term follow-up, and therefore none have described potential late side-effects of early cholesterol-lowering therapy, or potential benefits in terms of reduction of or delay in cardiovascular or other vascular end-points. In 2007, the American Heart Association published a scientific statement on the use of cholesterol-lowering therapy in pediatric patients. In this review paper, we discuss some of the current literature on cholesterol-lowering therapy in children, including the statins that are currently available for use in children, and some of the cautions with using these and other cholesterol-lowering medications. A central tenet of this review is that medications are not a substitute for dietary and lifestyle interventions, and that even in children on cholesterol-lowering medications, physicians should take every opportunity to encourage children and their parents to make healthy diet and lifestyle choices.

  18. Early Holocene fauna from a new subfossil site: A first assessment from Christmas River, south central Madagascar

    Directory of Open Access Journals (Sweden)

    Patricia C. Wright

    2012-06-01

    Full Text Available We report on faunal remains recovered during recent explo­rations at ‘Christmas River’, the only subfossil locality known from Madagascar’s south central plateau. Recovered remains of several extinct taxa date to approximately 10,000 14C years before present (BP, including crocodiles, tortoises, the elephant bird Aepyornis, the carnivoran Cryptoprocta spelea, the lemurs Archaeolemur majori, Pachylemur insignis, and Megaladapis edwardsi, and abundant remains of the dwarf hippopotamus, Hippopotamus lemerlei. The presence of southern – limited, forest – dependent species at Christmas River supports the hypothesis that forest once extended, perhaps discontinu­ously, across the central highlands towards the west. One theory is that sites in the north central highlands, which are higher in elevation, maintained more mesic conditions during Plio–Quaternary climate shifts than those of the lower elevation sites of the south central highlands. Thus, elevation above sea level may have acted as a filter that limited species dispersal across the island in the past. Such a scenario would explain the distinction between more humid, higher elevation, northern highland subfossil communities versus more arid, lower eleva­tion, southern subfossil communities. Continued exploration at Christmas River thus provides a remarkable opportunity for deciphering ecological changes that have taken place in south central Madagascar during the Holocene. RÉSUMÉMadagascar est reconnue comme l’une des régions les plus sensibles du monde en ce qui concerne les menaces pesant sur sa biodiversité, et cela à cause de niveaux d’endémisme inégalés, d’une diversité variée et d’un impact humain important sur l’environnement. Suite à la colonisation par l’Homme il y a plus de 2000 ans, des extinctions de masse de la faune et un important recul forestier ont eu lieu en laissant des marques sur les écosystèmes modernes qui sont dans un état de

  19. Lutetian limestones in the Paris region: Petrographic and compositional examination

    Energy Technology Data Exchange (ETDEWEB)

    Blanc, A. [Lab. de Recherche des Monuments Historiques, Champs-sur-Marne (France); Holmes, L.L.; Harbottle, G. [Brookhaven National Lab., Upton, NY (United States). Chemistry Dept.

    1998-12-31

    Stone for building and decorating monuments in the Paris Basin from antiquity to the present came from numerous quarries in the Lutetian limestone formations of the region. To identify specific stone sources used for masonry and sculptures in these monuments, a team of geologists and archaeologists have investigated 300 quarries and collected 2,300 limestone samples for study in a collaborative effort by geologists and chemists. Petrographic and paleontologic examinations of thin sections enable geologists to distinguish the Tertiary Lutetian limestones from similar stone in Jurassic and Cretaceous strata. The methods of the geologist have been supplemented by those of the chemistry whose compositional studies by neutron activation analysis can differentiate among the fine-grained upper Lutetian limestones extracted from specific ancient quarries.

  20. LUTETIAN LIMESTONES IN THE PARIS REGION: PETROGRAPHIC AND COMPOSITIONAL EXAMINATION

    Energy Technology Data Exchange (ETDEWEB)

    BLANC,A.; HOLMES,L.L.; HARBOTTLE,G.

    1998-06-11

    Stone for building and decorating monuments in the Paris Basin from antiquity to the present came from numerous quarries in the Lutetian limestone formations of the region. To identify specific-stone sources used for masonry and sculptures in these monuments, a team of geologists and archaeologists has investigated 300 quarries and collected 2,300 limestone samples for study in a collaborative effort by geologists and chemists. Petrographic and paleontologic examinations of thin sections enable geologists to distinguish the Tertiary Lutetian limestones from similar stone in Jurassic and Cretaceous strata. The methods of the geologist have been supplemented by those of the chemist whose compositional studies by neutron activation analysis can differentiate among the fine-grained upper Lutetian limestones extracted from specific ancient quarries.

  1. Parcels and Land Ownership, Published in 2011, Limestone County Government.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Parcels and Land Ownership dataset as of 2011. The extent of these data is generally Limestone County, AL. This metadata was auto-generated through the Ramona...

  2. Egyptian limestone for gamma dosimetry: an electron paramagnetic resonance study

    Science.gov (United States)

    Salama, E.

    2014-04-01

    The electron paramagnetic resonance (EPR) properties of limestone from a certain Egyptian site were investigated in order to propose an efficient and low-cost gamma dosimeter. Radiation-induced free radicals were of one type which was produced in the limestone samples at g=2.0066 after exposure to gamma radiation (60Co). EPR spectrum was recorded and analyzed. The microwave power saturation curve and the effect of changing modulation amplitude on peak-to- peak signal height were investigated. The response of limestone to different radiation doses (0.5-20 kGy) was studied. Except for the decrease in signal intensities during the first five hours following irradiation, over the period of two months fair stabilities of signal intensities were noticed. From the current results, it is possible to conclude that natural limestone may be a suitable material for radiation dosimetry in the range of irradiation processing.

  3. Kinetic Study of Calcination of Jakura Limestone Using Power Rate ...

    African Journals Online (AJOL)

    National Research Institute for Chemical Technology, P.M. B 1052, Zaria, Kaduna State, Nigeria. [*Author ... calcination of Jakura limestone was also found to be first order reaction with respect to CaCO3 ..... Kinetics and Reactor Design, Gulp.

  4. the use of limestone powder as an alternative cement replacement ...

    African Journals Online (AJOL)

    user

    properties of cement paste and hardened mortar in two ranges of blain fineness .... shrinkage as compared to siliceous additives. It is ... 100LSF (Lime. Saturation Factor) ..... production of Portland limestone cement were free from impurities or ...

  5. Facies patterns and depositional environments of Palaeozoic cephalopod limestones

    Science.gov (United States)

    Wendt, J.; Aigner, T.

    1985-07-01

    In the eastern Anti-Atlas (Morocco) a platform and basin topography was established during the late Devonian, probably as a result of early Variscan tensional tectonics. Cephalopod limestones were deposited on shallow pelagic platforms, platform slopes and shallow, slowly subsiding basins. On the platform a transition from land areas into nearshore quartzose brachiopod coquinas, crinoidal limestones, condensed cephalopod limestones and finally into nodular limestones is observed. The latter often become disintegrated into incipient debris flows which pass into nodular limestone/marl alternations of a shallow basin. Deeper basins with shale sedimentation lack cephalopod limestones. Similar facies types also occur in the late Devonian of the Montagne Noire (France), Rheinisches Schiefergebirge (West Germany), Moravian Karst (Czechoslovakia), Holy Cross Mountains (Poland) and in the early Carboniferous of the Cantabrian Mountains (Spain). Due to strong late Variscan compressional tectonics and limited outcrops, detailed facies patterns could not be mapped in these regions, but the same facies types as in the eastern Anti-Atlas suggest similar coast/platform, slope and shallow basin topographies. During cephalopod limestone deposition water depth on the platforms was in the order of several tens to about one hundred metres, as is inferred from repeated subaerial exposures and distinctive depositional and faunal/floral features. Water depth in the adjacent shallow basins might have reached several hundreds of metres. Cephalopod limestones represent a typical stage in the evolution of geosynclines, characterized by extremely low sedimentation rates (1-5 m m.y. -1). This stage is preceded by deposition of thick neritic clastics and/or carbonates and is succeeded by deposition of deep-water clastics or flysch.

  6. A Metagenomic Survey of Limestone Hill in Taiwan

    Science.gov (United States)

    Hsu, Y. W.; Li, K. Y.; Chen, Y. W.; Huang, T. Y.; Chen, W. J.; Shih, Y. J.; Chen, J. S.; Fan, C. W.; Hsu, B. M.

    2016-12-01

    The limestone of Narro-Sky in Tainliao, Taiwan is of Pleistocene reef limestones interbedded in clastic layers that covered the Takangshan anticlines. Understanding how microbial relative abundance was changed in response to changes of environmental factors may contribute to better comprehension of roles that microorganisms play in altering the landscape structures. In this study, microorganisms growing on the wall of limestone, in the water dripping from the limestone wall and of soil underneath the wall were collected from different locations where the environmental factors such as daytime illumination, humidity, or pH are different. Next generation sequencing (NGS) was carried out to examine the compositions and richness of microbial community. The metagenomics were clustered into operational taxonomic units (OTUs) to analyze relative abundance, diversities and principal coordinates analysis (PCoA). Our results showed the soil sample has the highest alpha diversity while water sample has the lowest. Four major phyla, which are Proteobacteria, Acidobacteria, Actinobacteria, and Cyanobacteria, account for 80 % of total microbial biomass in all groups. Cyanobacteria were found most abundantly in limestone wall instead of water or soil of weathering limestone. The PCoA dimensional patterns of each phylum showed a trace of microbial community dynamic changes, which might be affected by environmental factors. This study provides the insights to understand how environmental factors worked together with microbial community to shape landscape structures.

  7. Converting SDAP into gypsum in a wet limestone scrubber

    Energy Technology Data Exchange (ETDEWEB)

    Fogh, F. [Faelleskemikerne, Elsamprojekt A/S, Fredericia (Denmark)

    1996-12-01

    The ELSAM power pool has an installed electrical capacity of approx. 5 GW{sub e}, mainly firing import coal. The major base load units are equipped with desulphurization units and three different desulphurization technologies are used: the wet limestone gypsum process, the spray dry absorption process and a sulphuric acid process. Gypsum and sulphuric acid are commercialized, whereas it has been difficult to utilize the spray dry absorption product (SDAP). The main constituents of SDAP are calcium sulphide, calcium chloride, hydrated lime and impurities mainly originating from fly ash. Sulphide can be oxidized into sulphate in acidic solution - the reaction is utilized in the wet limestone gypsum process - and the possibility of using any spare capacity in the wet limestone gypsum units to oxidize the sulphide content of SDAP into sulphate and produce usable gypsum has been investigated in the laboratory and in a 400 MW{sub e} equivalent wet limestone unit. The limestone inhibition effect of the addition of SDAP is currently being studied in the laboratory in order to determine the effect of different SDAP types (plant/coal sources) on limestone reactivity before further long-term full-scale tests are performed and permanent use of the process planned. (EG)

  8. Modeling the influence of limestone addition on cement hydration

    Directory of Open Access Journals (Sweden)

    Ashraf Ragab Mohamed

    2015-03-01

    Full Text Available This paper addresses the influence of using Portland limestone cement “PLC” on cement hydration by characterization of its microstructure development. The European Standard EN 197-1:2011 and Egyptian specification ESS 4756-1/2009 permit the cement to contain up to 20% ground limestone. The computational tools assist in better understanding the influence of limestone additions on cement hydration and microstructure development to facilitate the acceptance of these more economical and ecological materials. μic model has been developed to enable the modeling of microstructural evolution of cementitious materials. In this research μic model is used to simulate both the influence of limestone as fine filler, providing additional surfaces for the nucleation and growth of hydration products. Limestone powder also reacts relatively slow with hydrating cement to form monocarboaluminate (AFmc phase, similar to the mono-sulfoaluminate (AFm phase formed in ordinary Portland cement. The model results reveal that limestone cement has accelerated cement hydration rate, previous experimental results and computer model “cemhyd3d” are used to validate this model.

  9. Petrogenesis of incipient charnockite in the Ikalamavony sub-domain, south-central Madagascar: New insights from phase equilibrium modeling

    Science.gov (United States)

    Endo, Takahiro; Tsunogae, Toshiaki; Santosh, M.; Shaji, E.; Rambeloson, Roger A.

    2017-06-01

    Incipient charnockites representing granulite formation on a mesoscopic scale occur in the Ambodin Ifandana area of Ikalamavony sub-domain in south-central Madagascar. Here we report new petrological data from these rocks, and discuss the process of granulite formation on the basis of petrography, mineral equilibrium modeling, and fluid inclusion studies. The incipient charnockites occur as brownish patches, lenses, and layers characterized by an assemblage of biotite + orthopyroxene + K-feldspar + plagioclase + quartz + magnetite + ilmenite within host orthopyroxene-free biotite gneiss with an assemblage of biotite + K-feldspar + plagioclase + quartz + magnetite + ilmenite. Lenses and layers of calc-silicate rock (clinopyroxene + garnet + plagioclase + quartz + titanite + calcite) are typically associated with the charnockite. Coarse-grained charnockite occurs along the contact between the layered charnockite and calc-silicate rock. The application of mineral equilibrium modeling on the mineral assemblages in charnockite and biotite gneiss employing the NCKFMASHTO system as well as fluid inclusion study on coarse-grained charnockite defines a P-T range of 8.5-10.5 kbar and 880-900 °C, which is nearly consistent with the inferred P-T condition of the Ikalamavony sub-domain (8.0-10.5 kbar and 820-880 °C). The result of T versus H2O activity (a(H2O)) modeling demonstrates that orthopyroxene-bearing assemblage in charnockite is stable under relatively low a(H2O) condition of 0.42-0.43, which is consistent with the popular models of incipient-charnockite formation related to the lowering of water activity and stabilization of orthopyroxene through dehydration of biotite. The occurrence of calc-silicate rocks adjacent to the charnockite suggests that the CO2-bearing fluid that caused dehydration and incipient-charnockite formation might have been derived through decarbonation of calc-silicate rocks during the initial stage of decompression slightly after the peak

  10. Possible impacts of climate change on freezing rain in south-central Canada using downscaled future climate scenarios

    Directory of Open Access Journals (Sweden)

    C. S. Cheng

    2007-01-01

    Full Text Available Freezing rain is a major atmospheric hazard in mid-latitude nations of the globe. Among all Canadian hydrometeorological hazards, freezing rain is associated with the highest damage costs per event. Using synoptic weather typing to identify the occurrence of freezing rain events, this study estimates changes in future freezing rain events under future climate scenarios for south-central Canada. Synoptic weather typing consists of principal components analysis, an average linkage clustering procedure (i.e., a hierarchical agglomerative cluster method, and discriminant function analysis (a nonhierarchical method. Meteorological data used in the analysis included hourly surface observations from 15 selected weather stations and six atmospheric levels of six-hourly National Centers for Environmental Prediction (NCEP upper-air reanalysis weather variables for the winter months (November–April of 1958/59–2000/01. A statistical downscaling method was used to downscale four general circulation model (GCM scenarios to the selected weather stations. Using downscaled scenarios, discriminant function analysis was used to project the occurrence of future weather types. The within-type frequency of future freezing rain events is assumed to be directly proportional to the change in frequency of future freezing rain-related weather types The results showed that with warming temperatures in a future climate, percentage increases in the occurrence of freezing rain events in the north of the study area are likely to be greater than those in the south. By the 2050s, freezing rain events for the three colder months (December–February could increase by about 85% (95% confidence interval – CI: ±13%, 60% (95% CI: ±9%, and 40% (95% CI: ±6% in northern Ontario, eastern Ontario (including Montreal, Quebec, and southern Ontario, respectively. The increase by the 2080s could be even greater: about 135% (95% CI: ±20%, 95% (95% CI: ±13%, and 45% (95% CI: ±9

  11. Short-term response of the solid Earth to cryosphere fluctuations and the earthquake cycle in south-central Alaska

    Science.gov (United States)

    Sauber, J. M.; Freymueller, J. T.; Han, S. C.; Davis, J. L.; Ruppert, N. A.

    2016-12-01

    In southern Alaska surface deformation and gravimetric change are associated with the seismic cycle as well as a strong seasonal cycle of snow accumulation and melt and a variable rate of glacier mass wastage. Numerical modeling of the solid Earth response to cryosphere change on a variety of temporal and spatial scales plays a critical role in supporting the interpretation of time-variable gravity and other geodetic data. In this study we calculate the surface displacements and stresses associated with variable spatial and temporal cryospheric loading and unloading in south-central coastal Alaska. A challenging aspect of estimating the response of the solid Earth to short-term (months to 102 years) regional cryospheric fluctuations is choosing the rock mechanics constitutive laws appropriate to this region. Here we report calculated differences in the predicted surface displacements and stresses during the GRACE time period (2002 to present). Broad-scale, GRACE-derived estimates of cryospheric mass change, along with independent snow melt onset/refreeze timing, snow depth and annual glacier wastage estimates from a variety of methods, were used to approximate the magnitude and timing of cryospheric load changes. We used the CIG finite element code PyLith to enable input of spatially complex surface loads. An as example of our evaluation of the influence of variable short-term surface loads, we calculated and contrasted the predicted surface displacements and stresses for a cooler than average and higher precipitation water year (WY12) versus a warmer than average year (WY05). Our calculation of these comparative stresses is motivated by our earlier empirical evaluation of the influence of short-term cryospheric fluctuations on the background seismic rate between 1988-2006 (Sauber and Ruppert, 2008). During the warmer than average years between 2002-2006 we found a stronger seasonal dependency in the frequency of small tectonic events in the Icy Bay region relative

  12. Quality of groundwater and surface water, Wood River Valley, south-central Idaho, July and August 2012

    Science.gov (United States)

    Hopkins, Candice B.; Bartolino, James R.

    2013-01-01

    Residents and resource managers of the Wood River Valley of south-central Idaho are concerned about the effects that population growth might have on the quality of groundwater and surface water. As part of a multi-phase assessment of the groundwater resources in the study area, the U.S. Geological Survey evaluated the quality of water at 45 groundwater and 5 surface-water sites throughout the Wood River Valley during July and August 2012. Water samples were analyzed for field parameters (temperature, pH, specific conductance, dissolved oxygen, and alkalinity), major ions, boron, iron, manganese, nutrients, and Escherichia coli (E.coli) and total coliform bacteria. This study was conducted to determine baseline water quality throughout the Wood River Valley, with special emphasis on nutrient concentrations. Water quality in most samples collected did not exceed U.S. Environmental Protection Agency standards for drinking water. E. coli bacteria, used as indicators of water quality, were detected in all five surface-water samples and in two groundwater samples collected. Some analytes have aesthetic-based recommended drinking water standards; one groundwater sample exceeded recommended iron concentrations. Nitrate plus nitrite concentrations varied, but tended to be higher near population centers and in agricultural areas than in tributaries and less populated areas. These higher nitrate plus nitrite concentrations were not correlated with boron concentrations or the presence of bacteria, common indicators of sources of nutrients to water. None of the samples collected exceeded drinking-water standards for nitrate or nitrite. The concentration of total dissolved solids varied considerably in the waters sampled; however a calcium-magnesium-bicarbonate water type was dominant (43 out of 50 samples) in both the groundwater and surface water. Three constituents that may be influenced by anthropogenic activity (chloride, boron, and nitrate plus nitrite) deviate from this

  13. Microanalysis of the aerosol collected over south-central New Mexico during the alive field experiment, May-December 1989

    Science.gov (United States)

    Sheridan, Patrick J.; Schnell, Russel C.; Kahl, Jonathan D.; Boatman, Joe F.; Garvey, Dennis M.

    Thirty-eight size-segregated aerosol samples were collected in the lower troposphere over the high desert of south-central New Mexico, using cascade impactors mounted onboard two research aircraft. Four of these samples were collected in early May, sixteen in mid-July, and the remaining ones in December 1989, during three segments of the ALIVE field initiative. Analytical electron microscope analyses of aerosol deposits and individual particles from these samples were performed to physically and chemically characterize the major particulate species present in the aerosol. Air-mass trajectories arriving at the sampling area in the May program were quite different from those calculated for the July period. In general, the May trajectories showed strong westerly winds, while the July winds were weaker and southerly, consistently passing over or very near the border cities of El Paso, Texas, and Ciudad Juarez, Mexico. Aerosol samples collected during the May period were predominantly fine (0.1-0.5 μm dia.), liquid H 2SO 4 droplets. Samples from the July experiment were comprised mostly of fine, solid (NH 4) 2SO 4 or mostly neutralized sulfate particles. In both sampling periods, numerous other particle classes were observed, including many types with probable terrestrial or anthropogenic sources. The numbers of these particles, however, were small when compared with the sulfates. Composite particle types, including sulfate/crustal and sulfate/carbonaceous, were also found to be present. The major differences in aerosol composition between the May and July samples (i.e. the extensive neutralization of sulfates in the July samples) can be explained by considering the different aerosol transport pathways and the proximity of the July aerosol to the El Paso/Juarez urban plume. Winds during the December experiment were quite variable, and may have contributed to the widely varying aerosol compositions observed in these samples. When the aircraft sampled the El Paso

  14. Human Settlements in the South-Central U.S., Viewed at Night from the International Space Station

    Science.gov (United States)

    Dawson, Melissa; Evans, Cynthia; Stefanov, William; Wilkinson, M. Justin; Willis, Kimberly; Runco, Susan

    2012-01-01

    A recent innovation of astronauts observing Earth from the International Space Station (ISS) is documenting human footprints by photographing city lights at night time. One of the earliest night-time images from the ISS was the US-Mexico border at El Paso-Ciudad Juarez. The colors, patterns and density of city lights document the differences in the cultural settlement patterns across the border region, as well as within the urban areas themselves. City lights help outline the most populated areas in settlements around the world, and can be used to explore relative population densities, changing patterns of urban/suburban development, transportation networks, spatial relationship to geographic features, and more. The data also provides insight into parameters such as surface roughness for input into local and regional climate modeling and studies of light pollution. The ground resolution of night-time astronaut photography from the ISS is typically an order of magnitude greater than current Defense Meteorological Satellite Program (DMSP) data, and therefore can serve as a "zoom lens" for selected urban areas. Current handheld digital cameras in use on the ISS, optimized for greater light sensitivity, provide opportunities to obtain new detailed imagery of atmospheric phenomena such as airglow, aurora, and noctilucent clouds in addition to documenting urban patterns. ISS astronauts have taken advantage of increasingly sensitive digital cameras to document the world at night in unprecedented detail. In addition, the capability to obtain time-lapse imagery from fixed cameras has been exploited to produce dynamic videos of both changing surface patterns around the world and atmospheric phenomena. We will profile some spectacular images of human settlements over the South-Central U.S., and contrast with other images from around the world. More data can be viewed at http://eol.jsc.nasa.gov/Videos/CrewEarthObservationsVideos/. US-Mexico border is obvious by the different

  15. Geology and stratigraphy of the Challis Volcanic Group and related rocks, Little Wood River area, south-central Idaho

    Science.gov (United States)

    Sandford, Richard F.; Snee, Lawrence W.

    2005-01-01

    The southwestern part of the Challis volcanic field occupies the valley of the Little Wood River and its tributaries in the Hailey and Idaho Falls 1??2? quadrangles of south-central Idaho. The Little Wood River area is a structurally controlled topographic basin that is partly filled by Eocene Challis Volcanic Group and younger rocks. Rock types in the Challis Volcanic Group of the Little Wood River area include, in order of decreasing abundance, andesite lava flows and tuff breccia, dacite lava flows and flow breccia, volcaniclastic sedimentary rocks, lithic tuff, nonvolcanic conglomerate, and rhyolite dikes. A basal nonvolcanic conglomerate, that locally rests on upper Paleozoic sedimentary rocks at a regional unconformity, was deposited prior to eruption of volcanic rocks. Andesite was the first volcanic rock erupted and is a voluminous sequence as thick as 3,000 ft (1,000 m). Locally thick volcaniclastic sedimentary rocks accumulated in topographic lows. A sharp transition marks the beginning of dacite eruption from fissures and flow-dome complexes. Dacite flows and breccias are as thick as 2,000 ft (600 m). An upper volcaniclastic unit was deposited in paleotopographic lows following emplacement of the main dacite unit. Next, a widespread, distinctive, lithic rich ash flow tuff, correlated with the tuff of Stoddard Gulch, was deposited over much of the area. Deposition of the tuff was followed by eruption of thin andesite and dacite lava flows and deposition of conglomeratic sedimentary rocks. The entire sequence was then intruded by a dacite flow-dome complex composed of at least three separate intrusions. The Challis Volcanic Group in the study area is calcalkaline. Andesitic rocks are typically high potassium basaltic andesite, high potassium andesite, shoshonite, and banakite (latite). Dacitic rocks are high potassium dacite and trachyte. Tuffs and vitrophyres range in composition from basaltic andesite to trachyte. The paleotopographic basin in which the

  16. Assessment of nonpoint-source contamination of the High Plains Aquifer in south-central Kansas, 1987

    Science.gov (United States)

    Helgesen, John O.; Stullken, Lloyd E.; Rutledge, A.T.

    1994-01-01

    Ground-water quality was assessed in a 5,000-square-mile area of the High Plains aquifer in south-central Kansas that is susceptible to nonpoint-source contamination from agricultural and petroleum-production activities. Of particular interest was the presence of agricultural chemicals and petroleum-derived hydrocarbons that might have been associated with brines that formerly were disposed into unlined ponds. Random sampling of ground water was done within a framework of discrete land-use areas (irrigated cropland, petroleum-production land containing former brine-disposal ponds, and undeveloped rangeland) of 3-10 square miles. Although true baseline water-quality conditions probably are rare, in this region they are represented most closely by ground water in areas of undeveloped rangeland. The sampling design enabled statistical hypothesis testing, using nonparametric procedures, of the effects of land use, unsaturated-zone lithology, and type of well sampled. Results indicate that regional ground-water quality has been affected by prevailing land-use activities, as shown by increased concentrations of several inorganic constituents. Ground water beneath irrigated cropland was characterized by significantly larger concentrations of hardness, alkalinity, calcium, magnesium, potassium, fluofide, and nitrite plus nitrate than was water beneath undeveloped rangeland. Few nondegraded pesticides were detected in the aquifer, probably because of degradation and sorption. Atrazine was the most common, but only in small concentrations. round water beneath petroleum-production land was characterized by significantly larger concentrations of hardness, alkalinity, dissolved solids, sodium, and chloride than was water beneath undeveloped rangeland. Nonpoint-source contamination by oil-derived hydrocarbons was not discernible. The occurrences of trace organic compounds were similar between petroleum-production land and undeveloped rangeland, which indicates a natural origin

  17. GPS and Satellite InSAR Observations of Landslide Activity at the Sinking Canyon in South Central Idaho

    Science.gov (United States)

    Aly, M. H.; Glenn, N. F.; Thackray, G. D.

    2014-12-01

    Multiple rotational, transitional, and lateral spread landslides have occurred in south central Idaho where basalt lava flows overly unconsolidated lake and fluvial sediments at the Sinking Canyon. The canyon is about 0.1 km deep and 0.25-1 km wide along a 4-km segment of the Salmon Falls Creek (SFC). Local topography and hydrological conditions are most likely the major triggering factors that have initiated landslides by increasing the gravitational stresses and weakening the canyon wall materials. Landslide activity has created natural dams of SFC, which in turn has resulted in forming large lakes with a potential flooding hazard to life and property downstream. In this study, we use campaign Global Positioning System (GPS) measurements of 2003-2004 and Synthetic Aperture Radar Interferometric (InSAR) data acquired during 1992-2007 by the European radar satellites (ERS-1 and ERS-2) to identify, monitor, and analyze recent landslide activity at SFC. Results show that three main landslides have been active during the period of observation: the Salmon Falls landslide (SFL) that has been first reported in 1999, the historical 1937 landslide, and a third unnamed landslide to the north of the 1937 slide. InSAR measurements indicate that the SFL has been active during the period of our earliest interferogram (1992-1993) whereas the slide head has detached and has moved away from the eastern canyon wall about 3 cm. Over the years, the SFL body and toe have been pushed westward repetitively at rates of about 3-7 cm/yr. The toe is confined by the western canyon wall and thus is pushed upward in some years causing slight uplift (2-3 cm). Our field observations reveal many transverse and radial cracks associated with the deformation pattern caused by recurring motions. The historic 1937 slide is the largest mass wasting and is the least active landslide in the study area. The unnamed slide shows episodic activity with varying rates (0-4 cm/yr) of line-of-sight motions. This

  18. Thermal basin modelling of the Arauco forearc basin, south central Chile — Heat flow and active margin tectonics

    Science.gov (United States)

    Kuhn, Philipp P.; Echtler, Helmut; Littke, Ralf; Alfaro, Guillermo

    2010-11-01

    The Arauco basin is part of the coastal forearc domain in South-Central Chile. During its evolution since the Late Cretaceous it was subject to multiple deposition cycles and the erosion of lower bathyal to beach and lagoon sediments. These different environments were established in alternating accretional and erosive subduction tectonic settings along the South Andean active margin. Whereas the general development is well understood, inconsistencies arise regarding the origin of the high thermal maturity of Eocene coals and the estimates of vertical movements of the whole area during the Cenozoic. Thermal modelling of this forearc basin provides new insights regarding its thermal evolution and evaluation of the magnitudes of subsidence and inversion. Results are based on the analysis of coal samples from surface outcrops, mines and drill cores of ten onshore wells from ENAP/Sipetrol. Newly derived vitrinite reflectance (VR r) measurements indicated a temperature in the range of 135-150 °C for the oldest sediment unit of the Arauco basin, which was reached in post Eocene times. Furthermore, 1D basin modelling techniques indicate scenarios that could explain the coalification values in the basin's sediments. The models were calibrated against VR r data from drill core samples supplied by ENAP/Sipetrol. A Miocene and an Oligocene subsidence/inversion scenario were considered, while neither could be securely discarded based on the modelling results. Furthermore, it can be shown that the current thermal maturity was not reached by an increased heat flow (HF) or a deep subsidence only. Consequently, a structural inversion accompanied by the erosion of ~ 3.0 ± 0.4 km depending on the locality in combination with a high HF of ~ 64 ± 4 mW/m 2 is the best explanation of the available data. The HF, which is high for a forearc setting, can be attributed to the increased temperature of the relatively young subducted Nazca Plate and an additional influence of ascending hot

  19. The belt of metagabbros of La Pampa: Lower Paleozoic back-arc magmatism in south-central Argentina

    Science.gov (United States)

    Chernicoff, Carlos J.; Zappettini, Eduardo O.; Villar, Luisa M.; Chemale, Farid, Jr.; Hernández, Laura

    2009-12-01

    Combined geological, geochronological, geochemical and geophysical studies have led to identification of a large (˜300 km long, ˜5 km wide) N-S trending belt of metagabbros in the province of La Pampa, south-central Argentina. This belt, though only poorly exposed in the localities of Valle Daza and Sierra de Lonco Vaca, stands out in the geophysical data (aeromagnetics and gravity). Modeling of the aeromagnetic data permits estimation of the geometry of the belt of metagabbros and surrounding rocks. The main rock type exposed is metagabbros with relict magmatic nucleii where layering is preserved. A counterclockwise P-T evolution affected these rocks, i.e., during the Middle Ordovician the protolith reached an initial granulite facies of metamorphism (M1), evolving to amphibolite facies (M2). During the Upper Devonian, a retrograde, greenschist facies metamorphism (M3) partially affected the metagabbros. The whole-rock Sm-Nd data suggest a juvenile source from a depleted mantle, with model ages ranging from 552 to 574 Ma, and positive Epsilon values of 6.51-6.82. A crystallization age of 480 Ma is based on geological considerations, i.e. geochronological data of the host rocks as well as comparisons with the Las Aguilas mafic-ultramafic belt of Sierra de San Luis (central Argentina). The geochemical studies indicate an enriched MORB and back-arc signature. The La Pampa metagabbros are interpreted to be originated as a result of the extension that took place in a back-arc setting coevally with the Famatinian magmatic arc (very poorly exposed in the western part of the study area). The extensional event was 'aborted' by the collision of the Cuyania terrane with Pampia-Gondwana in the Middle Ordovician, causing deformation and metamorphism throughout the arc-back-arc region. The similarities between the La Pampa metagabbros and the mafic-ultramafic Las Aguilas belt of the Sierra de San Luis are very conspicuous, for example, the age (Lower Paleozoic), geochemical

  20. Morphological description and ecology of some rare macroalgae in south-central Spanish rivers (Castilla-La Mancha Region

    Directory of Open Access Journals (Sweden)

    Moreno Alcaraz, Jose Luis

    2013-06-01

    Full Text Available The Castilla-La Mancha Region (south-central Spain is scarcely studied in terms of freshwater algae. However, both the implementation of the Water Framework Directive (2000/60/CE and the evaluation of the ecological state of European aquatic ecosystems have increased the intensity and frequency of water body monitoring, including the rivers, lakes and wetlands of this region. Thus, our knowledge on algal biodiversity and the geographical distribution of many species is rapidly increasing. In this study we describe the occurrence, ecological conditions and morphological characteristics of five algal species which are rare at the European level: Nostochopsis lobata Wood ex Bornet & Flahault, Batrachospermum atrum (Hudson Harvey, Chroothece richteriana Hansg., Oocardium stratum Nägeli and Tetrasporidium javanicum Möbius. In addition, we include Hydrurus foetidus (Vill. Trev., a more common alga in Spain, since this is the first record for the region. Finally, we compare morphological and ecological characteristics of the studied populations with other European records.El conocimiento sobre la biodiversidad algal de la región de Castilla-La Mancha, situada en la zona centro-sur de España, es escaso en comparación con el de otras regiones peninsulares. Sin embargo, la aplicación de la Directiva Marco del Agua (2000/60/CE, y la evaluación del estado ecológico de los ecosistemas acuáticos europeos, ha traído consigo un aumento en la frecuencia e intensidad en el muestreo de ríos, lagos y humedales. De esta forma, durante los últimos años se han producido nuevos hallazgos en la región que han permitido ampliar el conocimiento de la biodiversidad de algas así como de la distribución geográfica de muchas de sus especies. En este trabajo se describen las condiciones ecológicas y las características morfológicas de cinco especies que pueden considerarse raras a nivel europeo: Nostochopsis lobata Wood & Bornet & Flahault, Batrachospermum

  1. Style and rate of quaternary deformation of the Hosgri Fault Zone, offshore south-central coastal California

    Science.gov (United States)

    Hanson, Kathryn L.; Lettis, William R.; McLaren, Marcia; Savage, William U.; Hall, N. Timothy; Keller, Mararget A.

    2004-01-01

    The Hosgri Fault Zone is the southernmost component of a complex system of right-slip faults in south-central coastal California that includes the San Gregorio, Sur, and San Simeon Faults. We have characterized the contemporary style of faulting along the zone on the basis of an integrated analysis of a broad spectrum of data, including shallow high-resolution and deep penetration seismic reflection data; geologic and geomorphic data along the Hosgri and San Simeon Fault Zones and the intervening San Simeon/Hosgri pull-apart basin; the distribution and nature of near-coast seismicity; regional tectonic kinematics; and comparison of the Hosgri Fault Zone with worldwide strike-slip, oblique-slip, and reverse-slip fault zones. These data show that the modern Hosgri Fault Zone is a convergent right-slip (transpressional) fault having a late Quaternary slip rate of 1 to 3 mm/yr. Evidence supporting predominantly strike-slip deformation includes (1) a long, narrow, linear zone of faulting and associated deformation; (2) the presence of asymmetric flower structures; (3) kinematically consistent localized extensional and compressional deformation at releasing and restraining bends or steps, respectively, in the fault zone; (4) changes in the sense and magnitude of vertical separation both along trend of the fault zone and vertically within the fault zone; (5) strike-slip focal mechanisms along the fault trace; (6) a distribution of seismicity that delineates a high-angle fault extending through the seismogenic crust; (7) high ratios of lateral to vertical slip along the fault zone; and (8) the separation by the fault of two tectonic domains (offshore Santa Maria Basin, onshore Los Osos domain) that are undergoing contrasting styles of deformation and orientations of crustal shortening. The convergent component of slip is evidenced by the deformation of the early-late Pliocene unconformity. In characterizing the style of faulting along the Hosgri Fault Zone, we assessed

  2. Streamlined subglacial bedforms on the Närke plain, south-central Sweden - Areal distribution, morphometrics, internal architecture and formation

    Science.gov (United States)

    Möller, Per; Dowling, Thomas P. F.

    2016-08-01

    A flow set of close to 1000 drumlins has been mapped by means of LiDAR-derived digital elevation models and investigated by trenching. The area is situated on the SW part of the Närke plain and its surrounding uplands in south-central Sweden, which was deglaciated in the early Preboreal in a glacioaquatic setting. We find that there is considerable morphological difference in drumlin distribution patterns over crystalline basement areas compared to streamlined terrain over Palaeozoic sedimentary rock basement. The former area is characterized by thin Quaternary drift and the drumlins are all of the rock-cored type, built due to active deposition of sediment around obstacles to glacier flow. The latter area is characterized by deep Quaternary drift and the drumlins are more elongate and also larger in all dimensions, as compared to rock-cored drumlins. Irrespective of these geomorphological differences on local landscape scale we find that drumlin morphometric values remain part of a morphological continuum at the regional scale. Based on the internal sediment architecture as revealed in two cross-drumlin sections we find that the soft-cored drumlins were formed by compressional constructive deformation, along with excavational deformation along the flanks of the emerging drumlins, which shaped the separating troughs. Intermediate-type drumlins are those that demonstrate a coupling between underlying Palaeozoic sediment strata in areas of shallow drift sheet. These are the result of differing rheological response between incorporated sedimentary rock and a deforming bed below the ice-bed interface. An overall conclusion is that we find geomorphic and architectural compositional differences between the drumlins and the flowset they form. We can closely relate these differences to contextual geological variations with respect to basement type and drift depth. We argue that drumlin formation is better explained not by one single 'unifying' process but rather a set of

  3. Characterization of limestone reacted with acid-mine drainage in a pulsed limestone bed treatment system at the Friendship Hill National Historical Site, Pennsylvania, USA

    Energy Technology Data Exchange (ETDEWEB)

    Hammarstrom, J.M.; Sibrell, P.L.; Belkin, H.E. [US Geological Survey, Reston, VA (United States)

    2003-11-01

    Armoring of limestone is a common cause of failure in limestone-based acid-mine drainage (AMD) treatment systems. Limestone is the least expensive material available for acid neutralization, but is not typically recommended for highly acidic, Fe-rich waters due to armoring with Fe(III) oxyhydroxide coatings. A new AMD treatment technology that uses CO{sub 2} in a pulsed limestone bed reactor minimizes armor formation and enhances limestone reaction with AMD. Limestone was characterized before and after treatment with constant flow and with the new pulsed limestone bed process using AMD from an inactive coal mine in Pennsylvania (pH = 2.9, Fe = 150 mg/l, acidity 1000 mg/l CaCO{sub 3}). In constant flow experiments, limestone is completely armored with reddish-colored ochre within 48 h of contact in a fluidized bed reactor. Effluent pH initially increased from the inflow pH of 2.9 to over 7, but then decreased to {lt}4 during the 48 h of contact. Limestone grains developed a rind of gypsum encapsulated by a 10- to 30-mum thick, Fe-Al hydroxysulfate coating. Armoring slowed the reaction and prevented the limestone from generating any additional alkalinity in the system. With the pulsed flow limestone bed process, armor formation is largely suppressed and most limestone grains completely dissolve resulting in an effluent pH of {gt}6 during operation. Limestone removed from a pulsed bed pilot plant is a mixture of unarmored, rounded and etched limestone grains and partially armored limestone and refractory mineral grains (dolomite, pyrite). Aluminium-rich zones developed in the interior parts of armor rims in both the constant flow and pulsed limestone bed experiments in response to pH changes at the solid/solution interface.

  4. Integrated geophysical and geological studies of selected major tectonic features in south-central U.S

    Science.gov (United States)

    Alrefaee, Hamed

    The current dissertation includes three separate chapters, each utilizing the power of the integration of different geophysical datasets with geology to investigate tectonic and structural processes responsible for the geological evolution of selected major tectonic features in south-central U. S. These tectonic features are; the Arkoma basin of Oklahoma and Arkansas, the Llano uplift of central Texas, and the Meers fault of the southwestern Oklahoma. The Arkoma basin is an arcuate structural feature that extends from the Gulf coastal plain in central Arkansas westward 400 km to the Arbuckle Mountains in south-central Oklahoma. The interpretation of the 3-D seismic data reveals an E-W zone of crustal weakness in the northern part of the study area, which could be a Late Paleozoic tectonic inversion of the extension faulting that developed during Cambrian rifting and later foreland basin development. The seismic interpretation reveals a compressive deformation of the Late Paleozoic strata related to the Ouachita orogeny. Magnetic boundaries such as faults andor body edges extending E-W, NE-SW and NW-SE have been delineated using magnetic edge detector techniques in the northern, southeastern, and western parts of the study area, respectively. The Euler magnetic depth estimation method delineated the same faults determined using magnetic edge detector techniques. The maximum depth to faults dominating the basement and/or the intrabasement features determined by the Euler's method is about 3850 m. The fault trends delineated by the seismic interpretation and those determined by the Euler's method and the edge detector techniques show a very clear correlation. The Llano Uplift is a broad structural dome in central Texas with 2 to 3 km of structural relief relative to the subsurface Fort Worth and Kerr basins to the northeast and southwest. The initial uplift due to an arc-continent collision was followed by a continent-continent collision between the Laurentia and a

  5. Modifying the properties of finely ground limestone by tumbling granulation

    Science.gov (United States)

    Macho, Oliver; Eckert, Maroš; Tomášová, Barbora; Peciar, Peter; Ščasný, Martin; Fekete, Roman; Peciar, Marián

    2016-06-01

    Calcium carbonate in the form of finely ground limestone is a material that has found its application in a wide range of industries, in the chemical, rubber, agricultural, and paper industries, is used for desulfurization of boilers and other. In civil engineering, ground limestone is used for the production of building materials, plaster and mortar mixtures, as a filler in concrete mixtures, in road construction, and as an essential component of mastic asphalt. This paper deals with examining the modification of the properties of finely ground limestone by the tumbling agglomeration method. It has been shown that the components of concrete with a round grain have a positive effect on the pumping of concrete in comparison with an elongated grain or the rough surface of crushed stone. The experiments will be carried out on a granulation plate using a variety of granulation liquid. The agglomerates and their properties were compared with untreated finely ground limestone, with a focus on detecting changes in compressibility, density and particle size. The output of this paper is a description and graphical representation of the changes in the properties of ground limestone before and after the agglomeration process.

  6. Modifying the properties of finely ground limestone by tumbling granulation

    Directory of Open Access Journals (Sweden)

    Macho Oliver

    2016-06-01

    Full Text Available Calcium carbonate in the form of finely ground limestone is a material that has found its application in a wide range of industries, in the chemical, rubber, agricultural, and paper industries, is used for desulfurization of boilers and other. In civil engineering, ground limestone is used for the production of building materials, plaster and mortar mixtures, as a filler in concrete mixtures, in road construction, and as an essential component of mastic asphalt. This paper deals with examining the modification of the properties of finely ground limestone by the tumbling agglomeration method. It has been shown that the components of concrete with a round grain have a positive effect on the pumping of concrete in comparison with an elongated grain or the rough surface of crushed stone. The experiments will be carried out on a granulation plate using a variety of granulation liquid. The agglomerates and their properties were compared with untreated finely ground limestone, with a focus on detecting changes in compressibility, density and particle size. The output of this paper is a description and graphical representation of the changes in the properties of ground limestone before and after the agglomeration process.

  7. The evolutionary dynamics of highly pathogenic avian influenza H5N1 in south-central Vietnam reveals multiple clades evolving from Chinese and Cambodian viruses.

    Science.gov (United States)

    Nguyen, Tinh Huu; Than, Van Thai; Thanh, Hien Dang; Nguyen, Van Quang; Nguyen, Kim Hue; Nguyen, Duc Tan; Park, Jong-Hwa; Chung, In Sik; Jeong, Dae Gwin; Chang, Kyu-Tae; Oh, Tae Kwang; Kim, Wonyong

    2015-10-01

    In Vietnam, highly pathogenic avian influenza (HPAI), such as that caused by H5N1 viruses, is the most highly contagious infectious disease that has been affecting domestic poultry in recent years. Vietnam might be an evolutionary hotspot and a potential source of globally pandemic strains. However, few studies have reported viruses circulating in the south-central region of Vietnam. In the present study, 47 H5N1-positive samples were collected from both vaccinated and unvaccinated poultry farms in the South Central Coast region of Vietnam during 2013-2014, and their genetic diversity was analyzed. A common sequence motif for HPAI virus was identified at HA-cleavage sites in all samples: either RERRRKR/G (clades 2.3.2.1c and 2.3.2.1a) or REGRRKKR/G (clade 1.1.2). Phylogenetic analysis of HA genes identified three clades of HPAI H5N1: 1.1.2 (n=1), 2.3.2.1a (n=1), and 2.3.2.1c (n=45). The phylogenetic analysis indicated that these Vietnamese clades may have evolved from Chinese and Cambodian virus clades isolated in 2012-2013 but are less closely related to the clades detected from the Tyva Republic, Bulgaria, Mongolia, Japan, and Korea in 2009-2011. Detection of the coexistence of virus clades 2.3.2.1 and the very virulent 1.1.2 in the south-central regions suggests their local importance and highlights concerns regarding their spread, both northwards and southwards, as well as the potential for reassortment. The obtained data highlight the importance of regular identification of viral evolution and the development and use of region-specific vaccines.

  8. A Pediatric Application of the STRAC Regional Hospital Trauma Registry Database: Pediatric Trauma Deaths in South Central Texas During 2004-2013.

    Science.gov (United States)

    Buehner, Michelle; Aden, Jay; Borgman, Mathew; Love, Preston; Wright, Brandi; Edwards, Mary

    2017-01-01

    The purpose of this study was to define the demographics of pediatric traumatic injuries and to understand the predictive value of injury type, prehospital, and emergency department (ED) data regarding the mortality of pediatric trauma patients (<14 years of age) in South Central Texas. We report a retrospective review of pediatric trauma patients presenting to Trauma Service Area P in South Central Texas during 2004-2013. The primary outcome was mortality; secondary outcomes were ventilator days, hospital days, and intensive care unit stay. Demographics, Abbreviated Injury Score (AIS) codes, ICD-9 codes, transport times, Emergency Medical Services (EMS) vital signs en route and on arrival to the emergency department (ED), and outcomes were evaluated. A total of 8004 traumatically injured children presented to EDs in South Central Texas during the study period; 4109 of these presented via EMS. Most patients were Hispanic and male. Distribution was even across age groups. Overall mortality was 2%, and the mortality of those arriving by EMS was 3.7%. Abnormal vital signs and Glasgow Coma Score upon presentation to both EMS and the ED were strongly associated with mortality. Increased Injury Severity Score, the need for transfusion in the ED, and increased maximal AIS were also strongly associated with mortality. African American race was associated with increased mortality, although transport time and age were not. Most injuries overall were caused by motor vehicle collisions; however, burns and falls were most common in infants. The most lethal injuries were caused by firearms (mostly seen in preteens) and assaults (mostly seen in infants). This analysis of injured children in Southwest Texas offers insight into areas of needed quality improvement in the trauma system and potential areas to focus prevention efforts.

  9. Remarks on Echinodermata from the South Central Mediterranean Sea based upon collections made during the MARCOS cruise (10 to 20th April, 2007

    Directory of Open Access Journals (Sweden)

    C. MIFSUD

    2012-12-01

    Full Text Available The MARCOS cruise, which took place in the South Central Mediterranean Sea on board the RV ‘Urania’, resulted in the collection of 27 species of Echinodermata from shallow to bathyal depths, many from around Malta (the Fisheries Management Zone. The fauna is represented by common to rare taxa already reported from the Mediterranean with the exception of the amphi-Atlantic ophiuroid Ophiotreta valenciennesi rufescens (Koehler, 1896, recorded from the Mediterranean Basin for the first time. Odontaster mediterraneus (von Marenzeller, 1893 and Luidia sarsi Lutken, 1858 are also first records for the Maltese Islands.

  10. Assessing and mapping drought hazard in Africa and South-Central America with a Meteorological Drought Severity Index

    Science.gov (United States)

    Carrao, Hugo; Barbosa, Paulo; Vogt, Jürgen

    2015-04-01

    the intra-annual variability of precipitation in estimating the severity of events that can impact on seasonal activities. The MDSI is standardized in space and time, and considers the relative monthly precipitation deficits and the seasonal influence of precipitation regimes in the meteorological drought severity computation. In this study, the calculation of the MDSI is performed with monthly precipitation totals from the Full Data Reanalysis Monthly Product Version 6.0 of the Global Precipitation Climatology Centre (GPCC). This dataset provides a global analysis at 0.5 dd latitude/longitude grid spacing of monthly precipitation over land from operational in situ rain gauges collected between January 1901 and December 2010. Using the MDSI, we estimated the severity of drought events that occurred in the past 100 years in Africa and South-Central America, and produced drought hazard maps based on the probability of exceedance the median historical severity. Overall, results indicate that drought hazard is high for semiarid areas, such as Northeastern and Southern South America, as well as Eastern and Southwestern Africa. Since available water resources in semiarid areas are already insufficient to permanently meet the demands of human activities, the outcomes highlight the aggravated risk for food security and confirm the need for the implementation of disaster mitigation measures in those regions.

  11. Surficial Geologic Map of the Worcester North-Oxford- Wrentham-Attleboro Nine-Quadrangle Area in South- Central Massachusetts

    Science.gov (United States)

    Stone, Byron D.; Stone, Janet R.; DiGiacomo-Cohen, Mary L.

    2008-01-01

    The surficial geologic map layer shows the distribution of nonlithified earth materials at land surface in an area of nine 7.5-minute quadrangles (417 mi2 total) in south-central Massachusetts (fig. 1). Across Massachusetts, these materials range from a few feet to more than 500 ft in thickness. They overlie bedrock, which crops out in upland hills and in resistant ledges in valley areas. The geologic map differentiates surficial materials of Quaternary age on the basis of their lithologic characteristics (such as grain size and sedimentary structures), constructional geomorphic features, stratigraphic relationships, and age. Surficial materials also are known in engineering classifications as unconsolidated soils, which include coarse-grained soils, fine-grained soils, or organic fine-grained soils. Surficial materials underlie and are the parent materials of modern pedogenic soils, which have developed in them at the land surface. Surficial earth materials significantly affect human use of the land, and an accurate description of their distribution is particularly important for water resources, construction aggregate resources, earth-surface hazards assessments, and land-use decisions. The mapped distribution of surficial materials that lie between the land surface and the bedrock surface is based on detailed geologic mapping of 7.5-minute topographic quadrangles, produced as part of an earlier (1938-1982) cooperative statewide mapping program between the U.S. Geological Survey and the Massachusetts Department of Public Works (now Massachusetts Highway Department) (Page, 1967; Stone, 1982). Each published geologic map presents a detailed description of local geologic map units, the genesis of the deposits, and age correlations among units. Previously unpublished field compilation maps exist on paper or mylar sheets and these have been digitally rendered for the present map compilation. Regional summaries based on the Massachusetts surficial geologic mapping

  12. Sediment Quality and Comparison to Historical Water Quality, Little Arkansas River Basin, South-Central Kansas, 2007

    Science.gov (United States)

    Juracek, Kyle E.; Rasmussen, Patrick P.

    2008-01-01

    The spatial and temporal variability in streambed-sediment quality and its relation to historical water quality was assessed to provide guidance for the development of total maximum daily loads and the implementation of best-management practices in the Little Arkansas River Basin, south-central Kansas. Streambed-sediment samples were collected at 26 sites in 2007, sieved to isolate the less than 63-micron fraction (that is, the silt and clay), and analyzed for selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 25 trace elements, and the radionuclides beryllium-7, cesium-137, lead-210, and radium-226. At eight sites, streambed-sediment samples also were collected and analyzed for bacteria. Particulate nitrogen, phosphorus, and organic carbon concentrations in the streambed sediment varied substantially spatially and temporally, and positive correlations among the three constituents were statistically significant. Along the main-stem Little Arkansas River, streambed-sediment concentrations of particulate nitrogen and phosphorus generally were larger at and downstream from Alta Mills, Kansas. The largest particulate nitrogen concentrations were measured in samples collected in the Emma Creek subbasin and may be related to livestock and poultry production. The largest particulate phosphorus concentrations in the basin were measured in samples collected along the main-stem Little Arkansas River downstream from Alta Mills, Kansas. Particulate nitrogen, phosphorus, and organic carbon content in the water and streambed-sediment samples typically decreased as streamflow increased. This inverse relation may be caused by an increased contribution of sediment from channel-bank sources during high flows and (or) increased particle sizes transported by the high flows. Trace element concentrations in the streambed sediment varied from site to site and typically were less than threshold-effects guidelines for possible adverse biological effects

  13. Structural and geochronological record of India-Asia suturing in the Lopu Kangri Range, south-central Tibet

    Science.gov (United States)

    Laskowski, A. K.; Kapp, P. A.

    2013-12-01

    Better constraining the geological evolution of the India-Asia suture zone is vital to our comprehension of the Himalayan-Tibetan orogen. This study presents new mapping, igneous U-Pb geochronology, and detrital zircon geochronology from suture zone rocks exposed in the Lopu Kangri Range. Located ~50 km NW of Saga in south-central Tibet, this range exposes a >1.5 km thick panel of suture zone architecture that was exhumed by late Cenozoic orogen-parallel extension across two N-S, moderate-angle normal faults. The Lopu Kangri Range and its surroundings expose all of the major suture-zone assemblages. In the north, Cretaceous--Eocene Gangdese arc granitoids are unconformably overlain by nonmarine, conglomerate-bearing strata of the Eocene (?)--Miocene Kailas Fm. Metaconglomerate exposed in the same structural position within the Range contains garnet porphyroblasts. Gangdese arc and metaconglomerate rocks are confined to the footwall of the north-directed Great Counter Thrust system, which carried Cretaceous-Early Eocene Xigaze forearc, suture zone mélange, and Indian passive margin (Tethyan) strata northwards across three major NE-SW fault strands during the Miocene. Tethyan strata in the Range consist of locally garnet- and sillimanite-bearing calc-gneiss and schist that display N-S stretching lineations and top-N s-c fabrics. These rocks are exposed in the southern half of the range beneath suture zone mélange in the footwall of a moderately N-dipping, normal-sense shear zone. Six detrital zircon samples from the Xigaze forearc, metaconglomerate and meta-Tethyan strata were analyzed to confirm our lithologic correlations and provenance interpretations made in the field. 12 igneous U-Pb samples were analyzed to characterize granitoids that intrude the Range. They reveal a suite of 50-40 Ma granitoids that display a general younging trend from north to south across the suture. Five samples of 35-10 Ma leucogranites contain inherited zircon cores whose age spectra

  14. Crustal deformation in the south-central Andes backarc terranes as viewed from regional broad-band seismic waveform modelling

    Science.gov (United States)

    Alvarado, Patricia; Beck, Susan; Zandt, George; Araujo, Mario; Triep, Enrique

    2005-11-01

    The convergence between the Nazca and South America tectonic plates generates a seismically active backarc region near 31°S. Earthquake locations define the subhorizontal subducted oceanic Nazca plate at depths of 90-120 km. Another seismic region is located within the continental upper plate with events at depths Sierras Pampeanas and is responsible for the large earthquakes that have caused major human and economic losses in Argentina. South of 33°S, the intense shallow continental seismicity is more restricted to the main cordillera over a region where the subducted Nazca plate starts to incline more steeply, and there is an active volcanic arc. We operated a portable broad-band seismic network as part of the Chile-Argentina Geophysical Experiment (CHARGE) from 2000 December to 2002 May. We have studied crustal earthquakes that occurred in the back arc and under the main cordillera in the south-central Andes (29°S-36°S) recorded by the CHARGE network. We obtained the focal mechanisms and source depths for 27 (3.5 Sierras Pampeanas, over the flat-slab segment is dominated by reverse and thrust fault-plane solutions located at an average source depth of 20 km. One moderate-sized earthquake (event 02-117) is very likely related to the northern part of the Precordillera and the Sierras Pampeanas terrane boundary. Another event located near Mendoza at a greater depth (~26 km) (event 02-005) could also be associated with the same ancient suture. We found strike-slip focal mechanisms in the eastern Sierras Pampeanas and under the main cordillera with shallower focal depths of ~5-7 km. Overall, the western part of the entire region is more seismically active than the eastern part. We postulate that this is related to the presence of different pre-Andean geological terranes. We also find evidence for different average crustal models for those terranes. Better-fitting synthetic seismograms result using a higher P-wave velocity, a smaller average S-wave velocity and a

  15. Ground-water quality in Quaternary deposits of the central High Plains aquifer, south-central Kansas, 1999

    Science.gov (United States)

    Pope, Larry M.; Bruce, Breton W.; Hansen, Cristi V.

    2001-01-01

    Water samples from 20 randomly selected domestic water-supply wells completed in the Quaternary deposits of south-central Kansas were collected as part of the High Plains Regional Ground-Water Study conducted by the U.S. Geological Survey's National Water-Quality Assessment Program. The samples were analyzed for about 170 water-quality constituents that included physical properties, dissolved solids and major ions, nutrients and dissolved organic carbon, trace elements, pesticides, volatile organic compounds, and radon. The purpose of this study was to provide a broad overview of ground-water quality in a major geologic subunit of the High Plains aquifer. Water from five wells (25 percent) exceeded the 500-milligrams-per-liter of dissolved solids Secondary Maximum Contaminant Level for drinking water. The Secondary Maximum Contaminant Levels of 250 milligrams per liter for chloride and sulfate were exceeded in water from one well each. The source of these dissolved solids was probably natural processes. Concentrations of most nutrients in water from the sampled wells were small, with the exception of nitrate. Water from 15 percent of the sampled wells had concentrations of nitrate greater than the 10-milligram-per-liter Maximum Contaminant Level for drinking water. Water from 80 percent of the sampled wells showed nitrate enrichment (concentrations greater than 2.0 milligrams per liter), which is more than what might be expected for natural background concentrations. This enrichment may be the result of synthetic fertilizer applications, the addition of soil amendment (manure) on cropland, or livestock production. Most trace elements in water from the sampled wells were detected only in small concentrations, and few exceeded respective water-quality standards. Only arsenic was detected in one well sample at a concentration (240 micrograms per liter) that exceeded its proposed Maximum Contaminant Level (5.0 micrograms per liter). Additionally, one concentration of

  16. Novel Hydroxyapatite Coatings for the Conservation of Marble and Limestone

    Science.gov (United States)

    Naidu, Sonia

    Marble and limestone are calcite-based materials used in the construction of various structures, many of which have significant artistic and architectural value. Unfortunately, due to calcite's high dissolution rate, these stones are susceptible to chemically-induced weathering in nature. Limestone, due to its inherent porosity, also faces other environmental weathering processes that cause weakening from disintegration at grain boundaries. The treatments presently available are all deficient in one way or another. The aim of this work is to examine the feasibility of using hydroxyapatite (HAP) as a novel protective coating for marble and limestone, with two goals: i) to reduce acid corrosion of marble and ii) to consolidate physically weathered limestone. The motivation for using HAP is its low dissolution rate and structural compatibility with calcite. Mild, wet chemical synthesis routes, in which inorganic phosphate-based solutions were reacted with marble and limestone, alone and with other precursors, were used to produce HAP films. Film nucleation, growth and phase evolution were studied on marble to understand film formation and determine the optimal synthesis route. An acid resistance test was developed to investigate the attack mechanism on marble and quantify the efficacy of HAP-based coatings. Film nucleation and growth were dependent on substrate surface roughness and increased with calcium and carbonate salt additions during synthesis. Acid attack on marble occurred via simultaneous dissolution at grain boundaries, twin boundaries and grain surfaces. HAP provided intermediate protection against acid attack, when compared to two conventional treatments. Its ability to protect the stone from acid was not as significant as predicted from dissolution kinetics and this was attributed to incomplete coverage and residual porosity within the film, arising from its flake-like crystal growth habit, which enabled acid to access the underlying substrate. The

  17. Experimental study on exhaust gas after treatment using limestone

    Directory of Open Access Journals (Sweden)

    Sakhrieh Ahmad

    2013-01-01

    Full Text Available In this study a simple low-cost exhaust gas after-treatment filter using limestone was developed and tested on a four cylinder DI diesel engine coupled with dynamometer under variable engine running conditions. Limestone was placed in cast iron housing through which exhaust gases passes. The concentration of both carbon dioxide and nitrogen oxides were measured with and without the filter in place. It was found that both pollutants were decreased significantly when the filter is in place, with no increase in the fuel consumption rate.

  18. Effect of SO2 Dry Deposition on Porous Dolomitic Limestones

    Science.gov (United States)

    Olaru, Mihaela; Aflori, Magdalena; Simionescu, Bogdana; Doroftei, Florica; Stratulat, Lacramioara

    2010-01-01

    The present study is concerned with the assessment of the relative resistance of a monumental dolomitic limestone (Laspra – Spain) used as building material in stone monuments and submitted to artificial ageing by SO2 dry deposition in the presence of humidity. To investigate the protection efficiency of different polymeric coatings, three commercially available siloxane-based oligomers (Lotexan-N, Silres BS 290 and Tegosivin HL 100) and a newly synthesized hybrid nanocomposite with silsesquioxane units (TMSPMA) were used. A comparative assessment of the data obtained in this study underlines that a better limestone protection was obtained when treated with the hybrid nanocomposite with silsesquioxane units.

  19. Effect of SO2 Dry Deposition on Porous Dolomitic Limestones

    Directory of Open Access Journals (Sweden)

    Florica Doroftei

    2010-01-01

    Full Text Available The present study is concerned with the assessment of the relative resistance of a monumental dolomitic limestone (Laspra – Spain used as building material in stone monuments and submitted to artificial ageing by SO2 dry deposition in the presence of humidity. To investigate the protection efficiency of different polymeric coatings, three commercially available siloxane-based oligomers (Lotexan-N, Silres BS 290 and Tegosivin HL 100 and a newly synthesized hybrid nanocomposite with silsesquioxane units (TMSPMA were used. A comparative assessment of the data obtained in this study underlines that a better limestone protection was obtained when treated with the hybrid nanocomposite with silsesquioxane units.

  20. Initial kinetics of the direct sulfation of limestone

    DEFF Research Database (Denmark)

    Hu, Guilin; Shang, Lei; Dam-Johansen, Kim;

    2008-01-01

    The initial kinetics of direct sulfation of Faxe Bryozo, a porous bryozoan limestone was studied in the temperature interval from 873 to 973 K in a pilot entrained flow reactor with very short reaction times (between 0.1 and 0.6 s). The initial conversion rate of the limestone - for conversions...... ions in calcite grains is established. The validity of the model is limited to the initial sulfation period, in which nucleation of the solid product calcium sulphate is not started. This theoretical reaction-diffusion model gives a good simulation of the initial kinetics of the direct sulfation...

  1. Sulfate-water isotope geothermometry and lead isotope data for the regional geothermal system in the Twin Falls area, south-central Idaho

    Science.gov (United States)

    Mariner, R.H.; Young, H.W.; Bullen, T.D.; Janik, C.J.; ,

    1997-01-01

    Sulfate-water isotope geothermometry for the geothermal system at Twin Falls, Idaho indicates aquifer-temperatures of 90?? to 106 ??C; most sites are between 90?? and 93 ??C. 206Pb/204pb and 280Pb/204Pb of individual thermal waters are principally a function of how much lead has been dissolved from the carbonate and silicate fractions of the Paleozoic limestone collected west of Grand View Peak. Although most thermal waters are recovered from Tertiary rhyolite, very little of the dissolved lead is from the rhyolite. Recharge to this system occurs in northern Nevada and the fluid moves northward in the Paleozoic limestones. The occurrence of thermal fluid in the Idavada Volcanics near and south of Twin Falls, Idaho is the result of upward movement of this fluid from the Paleozoic limestone.

  2. Oxic limestone drains for treatment of dilute, acidic mine drainage

    Science.gov (United States)

    Cravotta, Charles A.

    1998-01-01

    Limestone treatment systems can be effective for remediation of acidic mine drainage (AMD) that contains moderate concentrations of dissolved O2 , Fe3+ , or A13+ (1‐5 mg‐L‐1 ). Samples of water and limestone were collected periodically for 1 year at inflow, outflow, and intermediate points within underground, oxic limestone drains (OLDs) in Pennsylvania to evaluate the transport of dissolved metals and the effect of pH and Fe‐ and Al‐hydrolysis products on the rate of limestone dissolution. The influent was acidic and relatively dilute (pH 1 mg‐L‐1 ) but was near neutral (pH = 6.2‐7.0); Fe and Al decreased to less than 5% of influent concentrations. As pH increased near the inflow, hydrous Fe and Al oxides precipitated in the OLDs. The hydrous oxides, nominally Fe(OH)3 and AI(OH)3, were visible as loosely bound, orange‐yellow coatings on limestone near the inflow. As time elapsed, Fe(OH)3 and AI(OH)3 particles were transported downflow. During the first 6 months of the experiment, Mn 2+ was transported conservatively through the OLDs; however, during the second 6 months, concentrations of Mn in effluent decreased by about 50% relative to influent. The accumulation of hydrous oxides and elevated pH (>5) in the downflow part of the OLDs promoted sorption and coprecipitation of Mn as indicated by its enrichment relative to Fe in hydrous‐oxide particles and coatings on limestone. Despite thick (~1 mm) hydrous‐oxide coatings on limestone near the inflow, CaCO3 dissolution was more rapid near the inflow than at downflow points within the OLD where the limestone was not coated. The rate of limestone dissolution decreased with increased residence time, pH, and concentrations of Ca2+ and HCO3‐ and decreased PCO2. The following overall reaction shows alkalinity as an ultimate product of the iron hydrolysis reaction in an OLD:Fe2+ + 0.25 O2 +CaCO3 + 2.5 H2O --> Fe(OH)3 + 2 Ca2+ + 2 HCO3-where 2 moles of CaCO3 dissolve for each mole of Fe(OH)3 produced

  3. Triatominae survey (Hemiptera: Reduviidae: Triatominae) in the south-central region of the state of Bahia, Brazil between 2008 and 2013.

    Science.gov (United States)

    Mendonça, Vagner José; de Oliveira, Jader; Rimoldi, Aline; Filho, Júlio C R Ferreira; de Araújo, Renato Freitas; da Rosa, João Aristeu

    2015-05-01

    Triatomine surveillance in rural areas, artificial ecotypes, and natural ecotopes of the cities of Caturama, Ibipitanga, Macaúbas, and Seabra in the south-central region of the Brazilian state of Bahia was carried out between 2008 and 2013. Natural infection by Trypanosoma cruzi was evaluated in the specimens collected to monitor vectors of Chagas disease. A total of 1,357 specimens were collected, and four species were identified: Triatoma sordida (83%), Triatoma lenti (16.4%), Triatoma pseudomaculata (0.5%), and Panstrongylus geniculatus (0.1%). Triatoma sordida was found in four cities, only 0.7% in intradomiciliary environments. Triatoma lenti was found only in Macaúbas; 8.5% were found in intradomiciliary environments, 88.3% in peridomiciliary environments, and 3.1% in sylvatic environments. Natural infection by T. cruzi was 0.5% for T. sordida and 3.1% T. lenti. All of these cases were found in peridomiciliary environments of Macaúbas. As the results show, triatomines were found in intradomiciliary environments in three cities that were surveyed in the south-central region of the state of Bahia. Thus, an epidemiologic survey should be performed to avoid the risk of transmission to the population.

  4. 中南地区的“新三反”运动%On the"New Movement against Three Evils"in South Central China

    Institute of Scientific and Technical Information of China (English)

    谌玉梅

    2013-01-01

    At the beginning of 1953, the Central Committee of the Communist Party of China started the"New Movement against Three Evils". Its content is fighting against bureaucracy, commandism, and violations of laws and disciplines. South Central China is an important area. In all, the movement was carried out in order. This paper summerizes South Central China's "New Movement against Three Evils"from the aspects of arrangements, progress and problems.%1953年初,中共中央发动了一场以反对官僚主义、命令主义和违法乱纪为主要内容的“新三反”运动,中南地区的“新三反”运动是其重要组成部分。总的来说,中南地区的“新三反”运动基本上是按照中央精神有序开展起来的。本文拟从运动的部署、开展情况及暴露出来的问题等方面,对中南地区“新三反”运动作一简要概述。

  5. Amphibian, reptilian, and avian remains from the Fox Hills Formation (Maastrichtian): Shoreline and estuarine deposits of the Pierre Sea in south-central North Dakota

    Science.gov (United States)

    Hoganson, J.W.; Erickson, J.M.; Holland, F.D.

    2007-01-01

    Although vertebrate fossils, except for fish, are not common in the Maastrichtian Fox Hills Formation, amphibian, reptilian, and avian remains have been recovered at several localities in south-central North Dakota from shoreline facies of the retreating Pierre-Fox Hills seaway. This mixed fauna of aquatic, terrestrial, and marine taxa provides insight into the composition of coastal communities and habitats at the interface between the Hell Creek delta and the Western Interior Seaway. The delta-platform aquatic paleocommunity is represented by the efficient swimming salamanders Opistho- trition kayi and Lisserpeton bairdi, the carnivorous soft-shelled turtle "Aspideretes" sensu lato, the underwater piscivorous predator Champsosaurus laramiensis, and the large, predatory crocodile IBorealosuchus. Terrestrial areas were inhabited by the tortoise-like Basilemys and the predatory dinosaurs Tyrannosaurus and cf. Saurornit- holestes. Birds occupied niches in the warm-temperate to subtropical, forested delta platform and shoreline areas. These nonmarine taxa in the Fox Hills Formation indicate that the geographic range of these animals extended to shoreline areas of the Western Interior Seaway. The toxochelyid turtle Lophochelys and the ambush predators Mosasaurus dekayi and IPlioplatecarpus resided in the shallow marine and estuarine habitats. These taxa and marine fish taxa reported earlier indicate that normal marine conditions in south- central North Dakota persisted into the latest Late Cretaceous in comparison with coeval Hell Creek Formation sites more distal from the Western Interior Seaway. ?? 2007 The Geological Society of America. All rights reserved.

  6. Mantle Branch Structure in the South-Central Segment of the Da Hinggan Mts., Inner Mongolia and Its Ore-controlling Role

    Institute of Scientific and Technical Information of China (English)

    NIU Shuyin; SUN Aiqun; WANG Baode; NIE Fengjun; JIANG Sihong; SHAO Jian; GUO Lijun; LIU Jianming

    2009-01-01

    Mantle branch structure is the third tectonic unit of multiple evolution of a mantle branch. It is not only the main mechanism of intercontinental orogeny, but also an important ore-forming and ore-control structure. Studies on geotectonic evolution, regional geological characteristics and ore-forming and ore-control structures have shown that since the Mesozoic the Da Hinggan Mts. region has entered a typical intercontinental orogenic stage, and it is closely related to mantle branch activities. The south-central segment of the Da Hinggan Mts. is a typical mantle branch structure and possesses obvious magmatic-metamorphic complexes in the core, detachment slip beds in the periphery and overlapped fault depression basins. Moreover, all of these are the principal factors leading to ore formation and ore control in the region. This paper also further explores the mechanism of mineralization in the south-central segment of the Da Hinggan, summaries the rules of mineralization, puts forward the models of mineralization and points out future ore-exploring orientation.

  7. The Kinetics of Calcination of High Calcium Limestone

    Directory of Open Access Journals (Sweden)

    P. C. Okonkwo

    2012-02-01

    Full Text Available The kinetics of calcination of a high calcium type of limestone was studied. Ukpilla limestone found in the central region of Nigeria was studied. The limestone composition shows that the limestone has 51.29% calcium oxide and 41.53% loss on ignition and magnesium oxide content of 2.23%. The following parameters were determined; diffusion coefficient of lime layer, and mass transfer coefficient, conductivity of lime layer and beat transfer coefficient, convective parameter and diffusive parameter for temperatures 9000C, 10000C, 10600C and 10800C. The reaction was found to be limited by mass and heat transfers across the tune layer of the calcining article, theoptimal temperature of calcination was found to be 10600C. Diffusivity and mass transfer coefficient decreases with increase in calcination temperature. The thermal conductivity increases with increase in temperature. The diffusive and convective parameter decreases with increase in temperature. The reactivity of lime calcined at different temperatures were determined. The reactivity of the lime increases with decrease in calcination temperature.

  8. Shear creep characteristics and constitutive model of limestone

    Institute of Scientific and Technical Information of China (English)

    Yu Mei; Mao Xianbiao; Hu Xinyu

    2016-01-01

    The characters of limestone in weak interlayer of a high rocky slope in Xuzhou, China, are studied by shear static test and shear creep test. The results show that limestone specimens have attenuation creep properties and constant rate creep properties, almost have no accelerated creep properties. The exponen-tial type empirical formula is selected to fit creep grading curves by polynomial regression analysis method, and the square sums of the fitting results residual are in the order of 10-7. Then grade creep curves at every shear loads are set up. Combining creep rate-time curve, the creep properties of limestone are analyzed. As the physical meaning of component model is clearer, the Poytin–Thomson model is set up. Through the least square method, the optimal parameters of Poytin–Thomson model are obtained, and the sums of squared residuals belong to 10-3 order of magnitude, which can meet the accuracy requirements of engineering calculation. So the Poytin–Thomson model can reflect the shear creep char-acteristics of limestone very well.

  9. Catalytic and Gas-Solid Reactions Involving HCN over Limestone

    DEFF Research Database (Denmark)

    Jensen, Anker; Johnsson, Jan Erik; Dam-Johansen, Kim

    1997-01-01

    In coal-fired combustion systems solid calcium species may be present as ash components or limestone added to the combustion chamber. In this study heterogeneous reactions involving HCN over seven different limestones were investigated in a laboratory fixed-bed quartz reactor at 873-1,173 K....... Calcined limestone is an effective catalyst for oxidation of HCN. Under conditions with complete conversion of HCN at O-2 concentrations above about 5,000 ppmv the selectivity for formation of NO and N2O is 50-70% and below 5%, respectively. Nitric oxide can be reduced by HCN to N-2 in the absence of O-2...... and to N-2 and N2O in the presence of O-2. At low O-2 concentrations or low temperatures. HCN may react with CaO, forming calcium cyanamide, CaCN2. The selectivities for formation of NO and N2O from oxidation of CaCN2 is 20-25% for both species. The catalytic activity of limestone for oxidation of HCN...

  10. The Solnhofen Limestone: A stony heritage of many uses

    Science.gov (United States)

    Kölbl-Ebert, Martina; Kramar, Sabina; Cooper, Barry J.

    2016-04-01

    High above the valley of the River Altmühl (Bavaria, Germany), between Solnhofen to the west and Kelheim to the east, numerous quarries give access to thinly plated limestone from the Upper Jurassic, some 150 million years before the present. The main quarry areas lie around the town of Eichstätt and between the villages of Solnhofen, Langenaltheim and Mörnsheim. Here limestone slabs have been quarried for several hundred years, some even in Roman times. Solnhofen Limestone is famous worldwide; not only because it is a beautiful building stone of high quality, but also because of the exceptionally well-preserved fossils it contains -among them the early bird Archaeopteryx. The quarry industry between Solnhofen and Eichstätt has shaped a cultural landscape, with old and new quarries sunk into the plain and numerous spoil heaps rising above it, for the rock is not all economically useful. But many of the spoil heaps and the old quarries are environmentally protected as they provide a habitat for some rare plants and animals. It is not necessary to cut the Solnhofen Limestone with a saw: it is split by hand into thin and even slabs or sheets which are used for flagstones and wall covers, which since centuries are sold world-wide. Locally it also serves as roof tiles for traditional houses. Thick slabs of especially fine quality may be found near Solnhofen and Mörnsheim and are used for lithography printing.

  11. Fine-scale species associations in alvar limestone grasslands

    NARCIS (Netherlands)

    Diekmann, M; Dupre, C; van der Maarel, E

    2004-01-01

    To examine the importance of positive or negative interactions of plant species on a micro-scale, species associations were studied in 38 1 m(2) - plots in alvar limestone grasslands on Oland, Sweden. Each plot was assumed to be homogeneous as to its environmental conditions and spatial distribution

  12. Field guide to the Mesozoic accretionary complex along Turnagain Arm and Kachemak Bay, south-central Alaska

    Science.gov (United States)

    Bradley, Dwight C.; Kusky, Timothy M.; Karl, Susan M.; Haeussler, Peter J.

    1997-01-01

    Turnagain Arm, just east of Anchorage, provides a readily accessible, world-class cross section through a Mesozoic accretionary wedge. Nearly continuous exposures along the Seward Highway, the Alaska Railroad, and the shoreline of Turnagain Arm display the two main constituent units of the Chugach terrane: the McHugh Complex and Valdez Group. In this paper we describe seven bedrock geology stops along Turnagain Arm, and two others in the Chugach Mountains just to the north (Stops 1-7 and 9), which will be visited as part of the May, 1997 field trip of the Alaska Geological Society. Outcrops along Turnagain Arm have already been described in two excellent guidebook articles (Clark, 1981; Winkler and others 1984), both of which remain as useful and valid today as when first published. Since the early 1980's, studies along Turnagain Arm have addressed radiolarian ages of chert and conodont ages of limestone in the McHugh Complex (Nelson and others, 1986, 1987); geochemistry of basalt in the McHugh Complex (Nelson and Blome, 1991); post-accretion brittle faulting (Bradley and Kusky, 1990; Kusky and others, 1997); and the age and tectonic setting of gold mineralization (Haeussler and others, 1995). Highlights of these newer findings will described both in the text below, and in the stop descriptions.Superb exposures along the southeastern shore of Kachemak Bay show several other features of the McHugh Complex that are either absent or less convincing along Turnagain Arm. While none of these outcrops can be reached via the main road network, they are still reasonably accessible - all are within an hour by motorboat from Homer, seas permitting. Here, we describe seven outcrops along the shore of Kachemak Bay that we studied between 1989 and 1993 during geologic mapping of the Seldovia 1:250,000- scale quadrangle. These outcrops (Stops 61-67) will not be part of the 1997 itinerary, but are included here tor the benefit of those who may wish to visit them later.

  13. Aquatic biological communities and associated habitats at selected sites in the Big Wood River Watershed, south-central Idaho, 2014

    Science.gov (United States)

    MacCoy, Dorene E.; Short, Terry M.

    2016-09-28

    Assessments of streamflow (discharge) parameters, water quality, physical habitat, and biological communities were completed between May and September 2014 as part of a monitoring program in the Big Wood River watershed of south-central Idaho. The sampling was conducted by the U.S. Geological Survey in cooperation with Blaine County, Trout Unlimited, the Nature Conservancy, and the Wood River Land Trust to help identify the status of aquatic resources at selected locations in the watershed. Information in this report provides a basis with which to evaluate and monitor the long-term health of the Big Wood River and its major tributaries. Sampling sites were co-located with existing U.S. Geological Survey streamgaging stations: three on the main stem Big Wood River and four on the North Fork Big Wood River (North Fork), Warm Springs Creek (Warm Sp), Trail Creek (Trail Ck), and East Fork Big Wood River (East Fork) tributaries.The analytical results and quality-assurance information for water quality, physical habitat, and biological community samples collected at study sites during 2 weeks in September 2014 are summarized. Water-quality data include concentrations of major nutrients, suspended sediment, dissolved oxygen, and fecal-coliform bacteria. To assess the potential effects of nutrient enrichment on algal growth, concentrations of periphyton biomass (chlorophyll-a and ash free dry weight) in riffle habitats were determined at each site. Physical habitat parameters include stream channel morphology, habitat volume, instream structure, substrate composition, and riparian vegetative cover. Biological data include taxa richness, abundance, and stream-health indicator metrics for macroinvertebrate and fish communities. Statistical summaries of the water-quality, habitat, and biological data are provided along with discussion of how these findings relate to the health of aquatic resources in the Big Wood River watershed.Seasonal discharge patterns using statistical

  14. Aquatic biological communities and associated habitats at selected sites in the Big Wood River Watershed, south-central Idaho, 2014

    Science.gov (United States)

    MacCoy, Dorene E.; Short, Terry M.

    2016-09-28

    Assessments of streamflow (discharge) parameters, water quality, physical habitat, and biological communities were completed between May and September 2014 as part of a monitoring program in the Big Wood River watershed of south-central Idaho. The sampling was conducted by the U.S. Geological Survey in cooperation with Blaine County, Trout Unlimited, the Nature Conservancy, and the Wood River Land Trust to help identify the status of aquatic resources at selected locations in the watershed. Information in this report provides a basis with which to evaluate and monitor the long-term health of the Big Wood River and its major tributaries. Sampling sites were co-located with existing U.S. Geological Survey streamgaging stations: three on the main stem Big Wood River and four on the North Fork Big Wood River (North Fork), Warm Springs Creek (Warm Sp), Trail Creek (Trail Ck), and East Fork Big Wood River (East Fork) tributaries.The analytical results and quality-assurance information for water quality, physical habitat, and biological community samples collected at study sites during 2 weeks in September 2014 are summarized. Water-quality data include concentrations of major nutrients, suspended sediment, dissolved oxygen, and fecal-coliform bacteria. To assess the potential effects of nutrient enrichment on algal growth, concentrations of periphyton biomass (chlorophyll-a and ash free dry weight) in riffle habitats were determined at each site. Physical habitat parameters include stream channel morphology, habitat volume, instream structure, substrate composition, and riparian vegetative cover. Biological data include taxa richness, abundance, and stream-health indicator metrics for macroinvertebrate and fish communities. Statistical summaries of the water-quality, habitat, and biological data are provided along with discussion of how these findings relate to the health of aquatic resources in the Big Wood River watershed.Seasonal discharge patterns using statistical

  15. Holocene limestones of part of the western continental shelf of India

    Digital Repository Service at National Institute of Oceanography (India)

    Nair, R.R.; Hashimi, N.H.; Guptha, M.V.S.

    Dredging on the western continental shelf of India has shown that the most common rock types outcropping on the irregular topography of the outer shelf (70-90 m) are algal limestones and shelly limestones containing superficial ooids and pelletoids...

  16. Overlying surficial deposits and absent areas for the Madison Limestone, Black Hills area, South Dakota.

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set describes areas where the Madison Limestone is directly overlain by surficial deposits, as well as those areas where the Madison Limestone is absent...

  17. Overlying surficial deposits and absent areas for Minnekahta Limestone in the Black Hills area, South Dakota

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set describes areas where the Minnekahta Limestone is directly overlain by surficial deposits, as well as those areas where the Minnekahta Limestone is...

  18. Carbon and Oxygen Isotope Ratios in Rona Limestone, Romania

    Directory of Open Access Journals (Sweden)

    Stela Cuna

    2001-04-01

    Full Text Available The carbon and oxygen isotopic compositions of limestones provide criteria for the evaluation of the depositional environment. For Jurassic and younger samples, the best discrimination between marine and fresh-water limestones is given by Z parameter, calculated as a linear correlation between δ13C and δ18O (‰ PDB. Rona Limestone (Upper Paleocene - Lower Eocene, outcropping on a small area in NW Transylvania (Meseş area is a local lacustrine facies. There, it divides Jibou Formation into the Lower Red Member and the Upper Variegated Member, respectively. Recently, a sequence containing a marine nannoplankton assemblage was identified in the base of Rona deposits. The main goal of our study was to characterize, based on the isotopic record, the primary environment of formation of the deposit, as well as that in which some diagenetic processes (the formation of dolomite and of green clay around the siliceous chert nodules took place. Ten samples representing limestones, dolomitic limestone, marls and the green carbonate-rich clay were studied from petrographical and mineralogical points of view, and the carbon and oxygen isotopic ratios from the carbonate (calcite component were measured. In conclusion, it was found that the procedure of extraction of CO2 we used enabled the discrimination between the isotopic prints of calcite vs. dolomite. This pleads for considering our results as a primary isotopic pattern in the bulk rock. The oxygen and carbon isotope data indicate a fresh-water depositional environment with Z<120. The δ13C mean value (-4.96 ‰ PDB is, generally, representative for fresh-water carbonates of the Tertiary period. The same environment characterized also the formation of carbonates within the green clay.

  19. 76 FR 60815 - Final Legislative Environmental Impact Statement (LEIS) for the Limestone Hills Training Area...

    Science.gov (United States)

    2011-09-30

    ... Department of the Army Final Legislative Environmental Impact Statement (LEIS) for the Limestone Hills... land within the Limestone Hills Training Area (LHTA) from BLM administration. The LEIS proposes that..., mining, recreation, transportation, utility right-of-ways, and wildlife management. A limestone mine...

  20. Quarry Quest. A Field Trip Guide to the Indiana Limestone District, Monroe and Lawrence Counties, Indiana.

    Science.gov (United States)

    Shewmaker, Sherman N.

    This guide provides information for planning a field trip to the Indiana Limestone District. This district, located in Monroe and Lawrence Counties, Indiana, is responsible for material that has dominated the building-limestone market in the United States for nearly a century. A few of the many well-known buildings using Indiana limestone are the…

  1. Genetic characterization of Kenai brown bears (Ursus arctos): Microsatellite and mitochondrial DNA control region variation in brown bears of the Kenai Peninsula, south central Alaska

    Science.gov (United States)

    Jackson, J.V.; Talbot, S.L.; Farley, S.

    2008-01-01

    We collected data from 20 biparentally inherited microsatellite loci, and nucleotide sequence from the maternally inherited mitochondrial DNA (mtDNA) control region, to determine levels of genetic variation of the brown bears (Ursus arctos L., 1758) of the Kenai Peninsula, south central Alaska. Nuclear genetic variation was similar to that observed in other Alaskan peninsular populations. We detected no significant inbreeding and found no evidence of population substructuring on the Kenai Peninsula. We observed a genetic signature of a bottleneck under the infinite alleles model (IAM), but not under the stepwise mutation model (SMM) or the two-phase model (TPM) of microsatellite mutation. Kenai brown bears have lower levels of mtDNA haplotypic diversity relative to most other brown bear populations in Alaska. ?? 2008 NRC.

  2. Examination of the Reelfoot Rift Petroleum System, south-central United States, and the elements that remain for potential exploration and development

    Science.gov (United States)

    Coleman, James; Pratt, Thomas L.

    2016-01-01

    The Reelfoot rift is one segment of a late Proterozoic(?) to early Paleozoic intracontinental rift complex in the south-central United States. The rift complex is situated beneath Mesozoic to Cenozoic strata of the Mississippi embayment of southeastern Missouri, northeastern Arkansas, and western Tennessee and Kentucky. The rift portion of the stratigraphic section consists primarily of synrift Cambrian and Ordovician strata, capped by a postrift sag succession of Late Ordovician to Cenozoic age. Potential synrift source rocks have been identified in the Cambrian Elvins Shale. Thermal maturity of Paleozoic strata within the rift ranges from the oil window to the dry gas window. Petroleum generation in Elvins source rocks likely occurred during the middle to late Paleozoic. Upper Cretaceous sedimentary rocks unconformably overlie various Paleozoic units and define the likely upper boundary of the petroleum system.

  3. Simulation of streamflow and the effects of brush management on water yields in the upper Guadalupe River watershed, south-central Texas, 1995-2010

    Science.gov (United States)

    Bumgarner, Johnathan R.; Thompson, Florence E.

    2012-01-01

    The U.S. Geological Survey, in cooperation with the Texas State Soil and Water Conservation Board and the Upper Guadalupe River Authority, developed and calibrated a Soil and Water Assessment Tool watershed model of the upper Guadalupe River watershed in south-central Texas to simulate streamflow and the effects of brush management on water yields in the watershed and to Canyon Lake for 1995–2010. Model simulations were done to quantify the possible change in water yield of individual subbasins in the upper Guadalupe River watershed as a result of the replacement of ashe juniper (Juniperus ashei) with grasslands. The simulation results will serve as a tool for resource managers to guide their brush-management efforts.

  4. Prevalence of hepatitis C virus genotypes in south-central Sicily, Italy: a comparative study between 2000/2001 and 2010/2014

    Directory of Open Access Journals (Sweden)

    Liborio Bellomo

    2016-06-01

    Full Text Available The aim of this study is to evaluate the prevalence of various genotypes in the population of south-central Sicily (Italy and to compare recent data with those of 2000/2001. In 2000, the patients tested were 202, all hepatitis C virus (HCV-RNA and anti-HCV positive. From 2010 to 2014 the patients examined are in total 535, all anti-HCV positive, but 111 with genotype negative and therefore likely HCV-RNA negative. The study showed a clear predominance of genotype 1b for both men and women, however, with a much greater prevalence in the older cohort. In both groups, then, the 3a genotype follows for men, while the 2a/2c follows for women. 1a genotype prevalence rate falls in the most recent group of women. The cases of co-infection of more genotypes remain very content in 2014 as it happened in 2000.

  5. Performance of portland limestone cements: Cements designed to be more sustainable that include up to 15% limestone addition

    Science.gov (United States)

    Barrett, Timothy J.

    In 2009, ASTM and AASHTO permitted the use of up to 5% interground limestone in ordinary portland cement (OPC) as a part of a change to ASTM C150/AASHTO M85. When this work was initiated a new proposal was being discussed that would enable up to 15% interground limestone cement to be considered in ASTM C595/AASHTO M234. This work served to provide rapid feedback to the state department of transportation and concrete industry for use in discussions regarding these specifications. Since the time this work was initiated, ASTM C595/AASHTO M234 was passed (2012c) and PLCs are now able to be specified, however they are still not widely used. The proposal for increasing the volume of limestone that would be permitted to be interground in cement is designed to enable more sustainable construction, which may significantly reduce the CO2 that is embodied in the built infrastructure while also extending the life of cement quarries. Research regarding the performance of cements with interground limestone has been conducted by the cement industry since these cements became widely used in Europe over three decades ago, however this work focuses on North American Portland Limestone Cements (PLCs) which are specifically designed to achieve similar performance as the OPCs they replace.This thesis presents a two-phase study in which the potential for application of cements containing limestone was assessed. The first phase of this study utilized a fundamental approach to determine whether cement with up to 15% of interground or blended limestone can be used as a direct substitute to ordinary portland cement. The second phase of the study assessed the concern of early age shrinkage and cracking potential when using PLCs, as these cements are typically ground finer than their OPC counterparts. For the first phase of the study, three commercially produced PLCs were obtained and compared to three commercially produced OPCs made from the same clinker. An additional cement was tested

  6. Contribution of Oil and Gas Production to Atmospheric CH4 in the South-Central United States: Reconciling Bottom-up and Top-down Estimates

    Science.gov (United States)

    Liu, Z.; Pinto, J. P.; Turner, A. J.; Bruhwiler, L.; Henze, D. K.; Brioude, J. F.; Bousserez, N.; Sargsyan, K.; Safta, C.; Najm, H. N.; LaFranchi, B. W.; Bambha, R.; Michelsen, H. A.

    2014-12-01

    Estimates of anthropogenic CH4 emissions in the United States have been largely inconsistent, particularly for oil and gas production (OGP) in the South-Central United States. We have quantified the contribution of OGP to the South-Central US (TX/OK/KS) CH4 budget through atmospheric regional transport modeling with the Community Multi-scale Air Quality (CMAQ). This model is driven by a new process-based, spatially resolved OGP CH4 emissions inventory. We employed Bayesian inference to calibrate CMAQ emissions inputs using continuous CH4 measurements at the DOE Southern Great Plains (SGP) central facility and evaluated model predictions against a subset of aircraft and surface flask measurements that are assimilated by NOAA's CarbonTracker-CH4. Our results suggest that OGP emissions are the largest source of CH4 observed at the DOE SGP site and the largest source of CH4 in TX/OK/KS, constituting ~45% of total CH4 emission in the region. The next largest source in the region is livestock, with other sources being relatively less important. We estimate OGP emissions in TX/OK/KS contribute about one half of national total OGP emissions. Using continuous CH4 measurements, we found evidence of rapid nocturnal transport by the Great Plains low-level jet (LLJ) and sporadic oil and gas emissions. Our study demonstrates the importance of improved knowledge of the spatial and temporal features of oil and gas emissions in reconciling CH4 budgets derived using bottom-up and top-down approaches at regional and national scales.

  7. Observed and CMIP5 modeled influence of large-scale circulation on summer precipitation and drought in the South-Central United States

    Science.gov (United States)

    Ryu, Jung-Hee; Hayhoe, Katharine

    2017-02-01

    Annual precipitation in the largely agricultural South-Central United States is characterized by a primary wet season in May and June, a mid-summer dry period in July and August, and a second precipitation peak in September and October. Of the 22 CMIP5 global climate models with sufficient output available, 16 are able to reproduce this bimodal distribution (we refer to these as "BM" models), while 6 have trouble simulating the mid-summer dry period, instead producing an extended wet season ("EW" models). In BM models, the timing and amplitude of the mid-summer westward extension of the North Atlantic Subtropical High (NASH) are realistic, while the magnitude of the Great Plains Lower Level Jet (GPLLJ) tends to be overestimated, particularly in July. In EW models, temporal variations and geophysical locations of the NASH and GPLLJ appear reasonable compared to reanalysis but their magnitudes are too weak to suppress mid-summer precipitation. During warm-season droughts, however, both groups of models reproduce the observed tendency towards a stronger NASH that remains over the region through September, and an intensification and northward extension of the GPLLJ. Similarly, future simulations from both model groups under a +1 to +3 °C transient increase in global mean temperature show decreases in summer precipitation concurrent with an enhanced NASH and an intensified GPLLJ, though models differ regarding the months in which these decreases are projected to occur: early summer in the BM models, and late summer in the EW models. Overall, these results suggest that projected future decreases in summer precipitation over the South-Central region appear to be closely related to anomalous patterns of large-scale circulation already observed and modeled during historical dry years, patterns that are consistently reproduced by CMIP5 models.

  8. The Influence of Grain Size on Decomposition Reaction of Limestone in Dispersing State

    Institute of Scientific and Technical Information of China (English)

    XU De-long; WEI Hon-gen; LUO Yong-qin

    2004-01-01

    The thermal behavior and kinetic parameters of decomposition reaction of limestone in a temperature-programmed mode were investigated by means of TG. The experimental results show that the kinetic model functions in different forms for the thermal decomposition reactions of different limestone grain sizes in dispersing state under the atmosphere of static air are 4(1-α)3/4 for small size limestone and (1-α) for large size limestone. Information was obtained on the relationship among the decomposition temperature, decomposition time, decomposition fraction, decomposition reaction rate constant and grain size of limestone.

  9. Effective stress law for the permeability of a limestone

    CERN Document Server

    Ghabezloo, Siavash; Guédon, Sylvine; Martineau, François

    2008-01-01

    The effective stress law for the permeability of a limestone is studied experimentally by performing constant head permeability tests in a triaxial cell with different conditions of confining pressure and pore pressure. Test results have shown that a pore pressure increase and a confining pressure decrease both result in an increase of the permeability, and that the effect of the pore pressure change on the variation of the permeability is more important than the effect of a change of the confining pressure. A power law is proposed for the variation of the permeability with the effective stress. The permeability effective stress coefficient increases linearly with the differential pressure and is greater than one as soon the differential pressure exceeds few bars. The test results are well reproduced using the proposed permeability-effective stress law. A conceptual pore-shell model based on a detailed observation of the microstructure of the studied limestone is proposed. This model is able to explain the ex...

  10. Experimental study on rheological deformation and stress properties of limestone

    Institute of Scientific and Technical Information of China (English)

    唐明明; 王芝银

    2008-01-01

    The systematic experiment regarding the general uniaxial compression test and the creep deformations of the typical limestones from the surrounding rock of the highway tunnels were made.The relationship between the axial stress and the delayed deformation steady value was obtained from the creep tests under low loading stresses.By the least square method,the parameters of Nishihara creep model were calculated from the creep curves.The results indicate that the strain change always lags behind the increase of stress,and the long-term strength of the limestone is about 80.6% of the stress at the volumetric strain reversal which is obtained from the conventional uniaxial compression test.

  11. Modified dry limestone process for control of sulfur dioxide emissions

    Science.gov (United States)

    Shale, Correll C.; Cross, William G.

    1976-08-24

    A method and apparatus for removing sulfur oxides from flue gas comprise cooling and conditioning the hot flue gas to increase the degree of water vapor saturation prior to passage through a bed of substantially dry carbonate chips or lumps, e.g., crushed limestone. The reaction products form as a thick layer of sulfites and sulfates on the surface of the chips which is easily removed by agitation to restore the reactive surface of the chips.

  12. Influence of pore system characteristics on limestone vulnerability: a laboratory study

    Science.gov (United States)

    Cultrone, G.; Russo, L. G.; Calabrò, C.; Uroševič, M.; Pezzino, A.

    2008-05-01

    Hyblean limestone of Oligo-Miocene age was widely used as a construction material in the architectural heritage of Eastern Sicily (Italy). Among them, the so-called Pietra Bianca di Melilli (Melilli limestone) and Calcare di Siracusa (Syracuse limestone) were prized for their attractive appearance, ease of quarrying, and workability. Syracuse limestone shows general weathering, whereas Melilli limestone is better preserved, and only differential erosion or superficial exfoliation can be detected in monuments. The cause of the different behavior of these two limestones was investigated from the petrographic and petrophysical points of view. The saturation coefficient is higher in Melilli limestone, and ultrasound measurements indicate that it is less compact than Syracuse limestone, so that Melilli limestone could deteriorate more easily than Syracuse limestone. However, pore interconnections and the size of very small pores play the main role in the durability of both materials. The “irregularity” of the Syracuse pore system and its greater number of micropores hinder water flow through the exterior, promote stress in pore structure, and favor the development of scaling, as confirmed by salt crystallization tests. In Melilli limestone, the low concentration of micropores and fast water evaporation allow solutions to reach the surface more easily, resulting in less damaging efflorescence.

  13. Microfacies of Hallstatt Limestones near Silická Brezová

    Directory of Open Access Journals (Sweden)

    Katarína Kronome

    2009-01-01

    Full Text Available This work is focused on microfacies analysis of the Upper Triassic Hallstatt limestones occurring at the locality "Trench" – a section of the Silicic Unit near the Silická Brezová village. Classical methods of limestones study are amended by statistical methods. The section studied is built of Tuvalian to Sevatian sediments, i.e. upper parts of the Tisovec (Waxeneck Limestone, Hallstatt and Dachstein Limestones (the paper is focused mainly to the Hallstatt Limestone. They are developed in facies of bedded bioclastic limestones of greyish-pink and brick-red colour with signs of nodularity. These limestones sedimented mainly in open shelf environment communicating with deep water environment during the sedimentation.

  14. Guri limestone, a new hydrocargon reservoir in south Iran

    Energy Technology Data Exchange (ETDEWEB)

    Kashfi, M.S.

    1982-10-01

    The Guri Limestone Member of the Mishan Formation of Early to Middle Miocene age produces gas in the SE portion of the Zagros geosyncline. The Mishan Formation, which is predominantly marl in its type section near Khuzestan Province, becomes more agrillaceous with an increase in organic content towards the SE where the sequence thickens. In the SE portion of the Azgros geosyncline, the lower part of the Mishan changes to a highly-resistant, fossiliferous limestone which is called the Guri Limestone. This is of Late-Early Miocene age in most of the SE Zagros and rises in stratigraphic postion towards the NW, becoming of Middle Miocene age in Khuzestan Province. The Guri thickens considerably with massive reefal-type deposits towards the eastern end of the Fars Province near the Oman high. Lithological and geochemical studies support the hypothesis that the Mishan Formation could serve as a source rock for the hydrocarbons which have been found within the Guri. However, subsidence has failed to place the Mishan Formation within the thermal zone thought to be necessary for liquid hydrocarbon formation, and it is more likely that the deposits will produce gas.

  15. Structural characterization of a karstified limestone formation using GPR

    Science.gov (United States)

    Rousset, D.; Sénéchal, G.; Gaffet, S.

    2009-12-01

    The Laboratoire Souterrain à Bas Bruit (LSBB) at Rustrel - Pays d'Apt, France, is an Inter-disciplinary Underground Science and Technology Laboratory buried in a karstified limestone formation. A multidisciplinary program focused on water circulation monitoring is presently performed inside the tunnels. This program comprises the investigation of faults, fractures, karstification and stratigraphy ofthe limestone massif using GPR. We present the main results obtained from these data. The tunnel has been dug in lower cretaceous limestone which is characterized by a low clay content, high electrical resistivity which results in generally very low attenuation of electro-magnetic waves. 90% of the tunnels floor are made of concrete whereas other are made of bare limestone. This experimental site offers a unique opportunity of perfoming measurements within an unweathered limestone massif. The whole 3km long tunnel has been investigated using single offset shielded 250 MHz antennas in May 2009. Processing includes : DC and very low frequency removal, amplitude compensation preserving lateral variations, migration and time to depth conversion. When necessary predictive deconvolution has been applied to remove ringing effects. These data sets are characterized by good signal to noise ratio and a signal penetration down to 18 meters. These data allow us to accurately map the stratigraphy of the surrounding rocks across the concrete walls of the tunnel. Some 20 m deep vertical wells have been drilled inside the tunnel through observed reflectors. This is a strong validation of the GPR images. The estimated resolution is centimetric to decimetric and matches the required geologic accuracy. The GPR data set allows to extend previous geological results in depth, particularly in the concrete coated parts of the tunnel where conventional geological surveying is impossible. Thanks to the processing which preserves lateral amplitude variations, GPR sections exhibit prominent

  16. Thermo-poroelastic response of an argillaceous limestone

    Science.gov (United States)

    Selvadurai, Patrick; Najari, Meysam

    2016-04-01

    Argillaceous limestones are now being considered by many countries that intend to develop deep geologic storage facilities for siting both high-level and intermediate- to low-level nuclear fuel wastes. In deep geologic settings for high level nuclear wastes, the heating due to radioactive decay is transmitted through an engineered barrier, which consists of the waste container and an engineered geologic barrier, which consists of an encapsulating compacted bentonite. The heat transfer process therefore leads to heating of the rock mass where the temperature of the rock is substantially lower than the surface temperature of the waste container. This permits the use of mathematical theories of poroelastic media where phase transformations, involving conversion of water to a vapour form are absent. While the thermo-poroelastic responses of geologic media such as granite and porous tuff have been investigated in the literature, the investigation of thermo-poroelastic responses of argillaceous limestones is relatively new. Argillaceous limestones are considered to be suitable candidates for siting deep geologic repositories owing to the ability to accommodate stress states with generation of severe defects that can influence their transmissivity characteristics. Also the clay fraction in such rocks can contribute to long term healing type phenomena, which is a considerable advantage. This research presents the results of a laboratory investigation and computational modelling of the same that examines the applicability of the theory of thermo-poroelasticity, which extend Biot's classical theory of poroelasticity to include uncoupled heat conduction. The experimental configuration involves the boundary heating of a cylinder of the Cobourg Limestone from southern Ontario, Canada. The cylinder measuring 150 mm in diameter and 278 mm in length contains an axisymmetric fluid-filled cylindrical cavity measuring 26 mm in diameter and 139 mm in length. Thermo-poroelastic effects

  17. High Resolution Airborne InSAR DEM of Bagley Ice Valley, South-central Alaska: Geodetic Validation with Airborne Laser Altimeter Data

    Science.gov (United States)

    Muskett, R. R.; Lingle, C. S.; Echelmeyer, K. A.; Valentine, V. B.; Elsberg, D.

    2001-12-01

    Bagley Ice Valley, in the St. Elias and Chugach Mountains of south-central Alaska, is an integral part of the largest connected glacierized terrain on the North American continent. From the flow divide between Mt. Logan and Mt. St. Elias, Bagley Ice Valley flows west-northwest for some 90 km down a slope of less than 1o, at widths up to 15 km, to a saddle-gap where it turns south-west to become Bering Glacier. During 4-13 September 2000, an airborne survey of Bagley Ice Valley was performed by Intermap Technologies, Inc., using their Star-3i X-band SAR interferometer. The resulting digital elevation model (DEM) covers an area of 3243 km2. The DEM elevations are orthometric heights, in meters above the EGM96 geoid. The horizontal locations of the 10-m postings are with respect to the WGS84 ellipsoid. On 26 August 2000, 9 to 18 days prior to the Intermap Star-3i survey, a small-aircraft laser altimeter profile was acquired along the central flow line for validation. The laser altimeter data consists of elevations above the WGS84 ellipsoid and orthometric heights above GEOID99-Alaska. Assessment of the accuracy of the Intermap Star-3i DEM was made by comparison of both the DEM orthometric heights and elevations above the WGS84 ellipsoid with the laser altimeter data. Comparison of the orthometric heights showed an average difference of 5.4 +/- 1.0 m (DEM surface higher). Comparison of elevations above the WGS84 ellipsoid showed an average difference of -0.77 +/- 0.93 m (DEM surface lower). This indicates that the X-band Star-3i interferometer was penetrating the glacier surface by an expected small amount. The WGS84 comparison is well within the 3 m RMS accuracy quoted for GT-3 DEM products. Snow accumulation may have occurred, however, on Bagley Ice Valley between 26 August and 4-13 September 2000. This will be estimated using a mass balance model and used to correct the altimeter-derived surface heights. The new DEM of Bagley Ice Valley will provide a reference

  18. Scope and Limits of an anamnestic questionnaire in a control-induced low-endemicity helminthiasis setting in south-central Cote d'Ivoire.

    Directory of Open Access Journals (Sweden)

    Thomas Fürst

    Full Text Available BACKGROUND: Schistosomiasis and soil-transmitted helminthiasis are two high-burden neglected tropical diseases. In highly endemic areas, control efforts emphasize preventive chemotherapy. However, as morbidity, infection, and transmission begin to decrease, more targeted treatment is likely to become more cost-effective, provided that comparatively cheap diagnostic methods with reasonable accuracy are available. METHODOLOGY: Adults were administered an anamnestic questionnaire in mid-2010 during a cross-sectional epidemiological survey in the Taabo health demographic surveillance system in south-central Côte d'Ivoire. Questions pertaining to risk factors and signs and symptoms for schistosomiasis and soil-transmitted helminthiasis were included. The individuals' helminth infection status and their belonging to three different anthelmintic treatment groups were compared with the questionnaire results (i to inform the local health authorities about the epidemiological and clinical footprint of locally prevailing helminthiases, and (ii to explore the scope and limits of an anamnestic questionnaire as monitoring tool, which eventually could help guiding the control of neglected tropical diseases in control-induced low-endemicity settings. PRINCIPAL FINDINGS: Our study sample consisted of 195 adults (101 males, 94 females. We found prevalences of hookworm, Trichuris trichiura, Schistosoma haematobium, and Schistosoma mansoni of 39.0%, 2.7%, 2.1%, and 2.1%, respectively. No Ascaris lumbricoides infection was found. Helminth infection intensities were generally very low. Seven, 74 and 79 participants belonged to three different treatment groups. Multivariable logistic regression models revealed statistically significant (p<0.05 associations between some risk factors, signs, and symptoms, and the different helminth infections and treatment groups. However, the risk factors, signs, and symptoms showed weak diagnostic properties. CONCLUSIONS

  19. Sulphur dioxide removal using South African limestone/siliceous materials

    Energy Technology Data Exchange (ETDEWEB)

    D.O. Ogenga; M.M. Mbarawa; K.T. Lee; A.R. Mohamed; I. Dahlan [Tshwane University of Technology, Pretoria (South Africa)

    2010-09-15

    This study presents an investigation into the desulfurization effect of sorbent derived from South African calcined limestone conditioned with fly ash. The main aim was to examine the effect of chemical composition and structural properties of the sorbent with regard to SO{sub 2} removal in dry-type flue gas desulfurization (FGD) process. South African fly ash and CaO obtained from calcination of limestone in a laboratory kiln at a temperature of 900{sup o}C were used to synthesize CaO/ash sorbent by atmospheric hydration process. The sorbent was prepared under different hydration conditions: CaO/fly ash weight ratio, hydration temperature (55-75{sup o}C) and hydration period (4-10 h). Desulfurization experiments were done in the fixed bed reactor at 87{sup o}C and relative humidity of 50%. The chemical composition of both the fly ash and calcined limestone had relatively high Fe{sub 2}O{sub 3} and oxides of other transitional elements which provided catalytic ability during the sorbent sorption process. Generally the sorbents had higher SO{sub 2} absorption capacity in terms of mol of SO{sub 2} per mol of sorbent (0.1403-0.3336) compared to hydrated lime alone (maximum 0.1823). The sorbents were also found to consist of mesoporous structure with larger pore volume and BET specific surface area than both CaO and fly ash. X-ray diffraction (XRD) analysis showed the presence of complex compounds containing calcium silicate hydrate in the sorbents. 19 refs., 6 figs., 3 tabs.

  20. Physical Deterioration of Egyptian Limestone Affected by Saline Water

    Directory of Open Access Journals (Sweden)

    Mohammed EL-GOHARY

    2013-12-01

    Full Text Available This study is the second in a series of experiments that describe the chemical, physical and thermal properties of archaeological limestone affected by salt and saline water in Egypt. This research aims to study the aggressive physical effects of different types of salts dominated in saline water and their different mechanisms on the acceleration of weathering processes that affect Egyptian limestone. It presents a multidisciplinary approach to characterize, at both micro/macro scales, the behavior of a limestone widely used as a construction material in most of Egyptian monuments when interacting with some types of salt solutions of various concentrations. A systematic optical, morphological, physical and mechanical analysis of the fresh and weathered stone samples were used to evaluate different characteristics through using scientific some techniques such as optical microscope (OP and scanning electron microscope (SEM. In addition to the using of some special computer programs that were used to define different physical and mechanical properties such as weight changes, bulk density, total porosity, water uptake, water content, thermal dilatation and abrasion resistant. The results proved that all investigated samples were gradually affected by the types of salinity paths and salt concentrations. These results will serve as a database for the future comparison of long term behavior of stones before and after the planned conservation of the entire area. So, it is pertinent to device some scientific methods and interventions to reduce all factors of salt effects and removing their harmful aspects from historic fabric of the archaeological buildings through some scientific recommendations

  1. Investigations of the properties of dredged limestone fill

    DEFF Research Database (Denmark)

    Foged, Niels; Gordon, Anne

    1999-01-01

    limestone fill that is pumped ito ponds of the reclamation site. The work utilised a number of geophysical and geotechnical investigation techniques in the field, supplemented with laboratory testing.The study of in-situ electrical resistivities revealed larger variations in the ground conditions than were...... expected on the basis of information available from borehole logs.Ground deformation moduli were evaluated within an area planned for a maintenance centre by DSBmateriel using the continuous surface wave method, in conjunction with retrospective forward modelling. deformation properties calculated from...

  2. Absorption spectra of crystalline limestones experimentally deformed or tectonised

    Science.gov (United States)

    Cervelle, B.; ChayéD'Albissin, M.; Gouet, G.; Visocekas, R.

    1982-11-01

    Diffuse-reflectance spectra have been measured for a series of samples of Carrara marble experimentally deformed under different cylindrical stress ( P = 0, 100, 250, 500, 980 bars). The creation of point defects that results has been shown up classically by irradiation with β rays (40 krads), thus producing a typical blue coloration linked with the formation of colour centres. The diffuse-reflectance spectra, measured on powders with a microscope-spectrometer in the visible range (400-800 nm), allow the determination of the absorption spectra by means of the Kubelka-Munk function. These absorption spectra have been measured for each of the deformed samples, as well as for different fractions of a very deformed specimen subsequently heated at temperatures between 100 and 500° C for a fixed time. In the same way, tectonised crystalline limestones, of various origins, were studied without any other treatment than the irradiation with β rays. From this study the following preliminary conclusions have been drawn: (1) The absorption spectrum of an undeformed but merely irradiated specimen of crystalline limestone is practically monotonous, but in the deformed specimens a broad band of absorption appears, having a maximum at 620 nm with several shoulders, the chief of which is at 520 nm. (2) This absorption band shows the existence of colour centres, the density of which can be estimated relatively by means of the chromaticity coordinates x and y of the C.I.E. obtained from the diffuse-reflectance spectra (C.I.E. = Commission Internationale de l'Éclairage). (3) An overgrinding of calcite generates defects that have the same spectra as those produced during the experimental deformation. Consequently, in obtaining the powders of grain size 50-80 μm needed for the diffuse spectrometry, great care must be exercised. (4) For a given confining pressure, the defect density is proportional to the deformation rate. (5) One can calibrate the effect of the annealing of

  3. Site investigations on cavernous limestone for the Remouchamps Viaduct, Belgium

    OpenAIRE

    Waltham, Antony; Vandenven, Georges; Ek, Camille

    1986-01-01

    POOR GROUND CONDITIONS on cavernous limestone created severe difficulties at the sites of four piers of the Remouchamps Viaduct. The discovery, during excavations for foundations, of large open cavities prompted a major re-appraisal of site investigation procedure, and also some redesign of the viaduct structure. La situation défavorable des fondations de quatre des piliers du viaduc autoroutier de Remouchamps posa des problèmes de construction. La présence de cavités karstiques largement ...

  4. Water transport in limestone by X-ray CAT scanning

    Science.gov (United States)

    Mossoti, Victor G.; Castanier, Louis M.

    1989-01-01

    The transport of water through the interior of Salem limestone test briquettes can be dynamically monitored by computer aided tomography (commonly called CAT scanning in medical diagnostics). Most significantly, unless evaporation from a particular face of the briquette is accelerated by forced air flow (wind simulation), the distribution of water in the interior of the briquette remains more or less uniform throughout the complete drying cycle. Moreover, simulated solar illumination of the test briquette does not result in the production of significant water gradients in the briquette under steady-state drying conditions.

  5. OPTIMALIZATION OF BLASTING IN »LAKOVIĆI« LIMESTONE QUARRY

    Directory of Open Access Journals (Sweden)

    Branko Božić

    1992-12-01

    Full Text Available The optimalization of exploitation in »Lakovići« limestone quarry is described. Based on determined discontinuities in the rock mass and their densities, the best possible working site have been located in order to obtain the best possible sizes of blasted rocks and work slope stability. Optimal lowest resistance line size for the quarry has been counted and proved experimentally. New blasting parameters have resulted in considerable saving of drilling and explosive (the paper is published in Croatian.

  6. Electrokinetically Enhanced Delivery for ERD Remediation of Chlorinated Ethenes in a Fractured Limestone Aquifer

    DEFF Research Database (Denmark)

    Broholm, Mette Martina; Hansen, Bente H.; With Nedergaard, Lærke;

    Leakage of the chlorinated solvents PCE and TCE into limestone aquifers from contaminated overburden and the long-lasting back diffusion from the secondary source in the limestone matrix pose a severe risk for contamination of drinking water resources. Dechlorination of PCE and TCE in limestone...... often accumulates cis-DCE due to incomplete dechlorination in the limestone aquifers, as observed downgradient of a PCE and TCE DNAPL source area at Naverland in Denmark. A microcosm study with limestone core material and groundwater from the Naverland site source area spiked with PCE showed...... that enhanced reductive dechlorination (ERD) by the addition of donor and specific degraders (KB1® culture) can lead to complete dechlorination of PCE and TCE in the limestone aquifer, provided sufficient contact between specific degraders, donor and specific degraders, is obtained. Advection-based delivery...

  7. Kinetic Hydration Heat Modeling for High-Performance Concrete Containing Limestone Powder

    Directory of Open Access Journals (Sweden)

    Xiao-Yong Wang

    2017-01-01

    Full Text Available Limestone powder is increasingly used in producing high-performance concrete in the modern concrete industry. Limestone powder blended concrete has many advantages, such as increasing the early-age strength, reducing the setting time, improving the workability, and reducing the heat of hydration. This study presents a kinetic model for modeling the hydration heat of limestone blended concrete. First, an improved hydration model is proposed which considers the dilution effect and nucleation effect due to limestone powder addition. A degree of hydration is calculated using this improved hydration model. Second, hydration heat is calculated using the degree of hydration. The effects of water to binder ratio and limestone replacement ratio on hydration heat are clarified. Third, the temperature history and temperature distribution of hardening limestone blended concrete are calculated by combining hydration model with finite element method. The analysis results generally agree with experimental results of high-performance concrete with various mixing proportions.

  8. Effects of projected climate (2011–50) on karst hydrology and species vulnerability—Edwards aquifer, south-central Texas, and Madison aquifer, western South Dakota

    Science.gov (United States)

    Mahler, Barbara J.; Stamm, John F.; Poteet, Mary F.; Symstad, Amy J.; Musgrove, MaryLynn; Long, Andrew J.; Norton, Parker A.

    2015-12-22

    Karst aquifers—formed by the dissolution of soluble rocks such as limestone—are critical groundwater resources in North America, and karst springs, caves, and streams provide habitat for unique flora and fauna. Springflow and groundwater levels in karst terrane can change greatly over short time scales, and therefore are likely to respond rapidly to climate change. How might the biological communities and ecosystems associated with karst respond to climate change and accompanying changes in groundwater levels and springflow? Sites in two central U.S. regions—the Balcones Escarpment of south-central Texas and the Black Hills of western South Dakota (fig. 1)—were selected to study climate change and its potential effects on the local karst hydrology and ecosystem. The ecosystems associated with the Edwards aquifer (Balcones Escarpment region) and Madison aquifer (Black Hills region) support federally listed endangered and threatened species and numerous State-listed species of concern, including amphibians, birds, insects, and plants. Full results are provided in Stamm and others (2014), and are summarized in this fact sheet.

  9. Disparity between state fish consumption advisory systems for methylmercury and US Environmental Protection Agency recommendations: A case study of the south central United States.

    Science.gov (United States)

    Adams, Kimberly J; Drenner, Ray W; Chumchal, Matthew M; Donato, David I

    2016-01-01

    Fish consumption advisories are used to inform citizens in the United States about noncommercial game fish with hazardous levels of methylmercury (MeHg). The US Environmental Protection Agency (USEPA) suggests issuing a fish consumption advisory when concentrations of MeHg in fish exceed a human health screening value of 300 ng/g. However, states have authority to develop their own systems for issuing fish consumption advisories for MeHg. Five states in the south central United States (Arkansas, Louisiana, Mississippi, Oklahoma, and Texas) issue advisories for the general human population when concentrations of MeHg exceed 700 ng/g to 1000 ng/g. The objective of the present study was to estimate the increase in fish consumption advisories that would occur if these states followed USEPA recommendations. The authors used the National Descriptive Model of Mercury in Fish to estimate the mercury concentrations in 5 size categories of largemouth bass-equivalent fish at 766 lentic and lotic sites within the 5 states. The authors found that states in this region have not issued site-specific fish consumption advisories for most of the water bodies that would have such advisories if USEPA recommendations were followed. One outcome of the present study may be to stimulate discussion between scientists and policy makers at the federal and state levels about appropriate screening values to protect the public from the health hazards of consuming MeHg-contaminated game fish.

  10. Quantity and location of groundwater recharge in the Sacramento Mountains, south-central New Mexico (USA), and their relation to the adjacent Roswell Artesian Basin

    Science.gov (United States)

    Rawling, Geoffrey C.; Newton, B. Talon

    2016-06-01

    The Sacramento Mountains and the adjacent Roswell Artesian Basin, in south-central New Mexico (USA), comprise a regional hydrologic system, wherein recharge in the mountains ultimately supplies water to the confined basin aquifer. Geologic, hydrologic, geochemical, and climatologic data were used to delineate the area of recharge in the southern Sacramento Mountains. The water-table fluctuation and chloride mass-balance methods were used to quantify recharge over a range of spatial and temporal scales. Extrapolation of the quantitative recharge estimates to the entire Sacramento Mountains region allowed comparison with previous recharge estimates for the northern Sacramento Mountains and the Roswell Artesian Basin. Recharge in the Sacramento Mountains is estimated to range from 159.86 × 106 to 209.42 × 106 m3/year. Both the location of recharge and range in estimates is consistent with previous work that suggests that ~75 % of the recharge to the confined aquifer in the Roswell Artesian Basin has moved downgradient through the Yeso Formation from distal recharge areas in the Sacramento Mountains. A smaller recharge component is derived from infiltration of streamflow beneath the major drainages that cross the Pecos Slope, but in the southern Sacramento Mountains much of this water is ultimately derived from spring discharge. Direct recharge across the Pecos Slope between the mountains and the confined basin aquifer is much smaller than either of the other two components.

  11. Nocturnal arboreality in snakes in the swamplands of the Atchafalaya Basin of south-central Louisiana and Big Thicket National Preserve of Southeast Texas

    Science.gov (United States)

    Glorioso, Brad M.; Waddle, Hardin

    2017-01-01

    The southeastern United States is home to a diverse assemblage of snakes, but only one species, the Rough Greensnake (Opheodrys aestivus), is considered specialized for a predominantly arboreal lifestyle. Other species, such as Ratsnakes (genus Pantherophis) and Ribbonsnakes/Gartersnakes (genus Thamnophis), are widely known to climb into vegetation and trees. Some explanations given for snake climbing behavior are foraging, thermoregulation, predator avoidance, and response to flood. Reports of arboreality in snake species typically not associated with life in the trees (such as terrestrial, aquatic, and even fossorial species) usually come from single observations, with no knowledge of prevalence of the behavior. Here, we report on arboreality of snake species detected during 8 years of night surveys in the Atchafalaya Basin of south-central Louisiana and 5+ years of night surveys in Big Thicket National Preserve in southeast Texas. We recorded a total of 1,088 detections of 19 snake species between the two study areas, with 348 detections above ground level (32%). The Rough Greensnake and Western Ribbonsnake (Thamnophis proximus) accounted for nearly 75% of total arboreal detections among the two study areas. However, with one exception, all snake species detected more than once between both study areas had at least one arboreal detection. These observations demonstrate that snakes with widely varying natural histories may be found in the trees at night, and for some species, this behavior may be more common than previously believed.

  12. Risk factors associated with the prevalence of tuberculosis-like lesions in fenced wild boar and red deer in south central Spain.

    Science.gov (United States)

    Vicente, Joaquín; Höfle, Ursula; Garrido, Joseba M; Fernández-de-Mera, Isabel G; Acevedo, Pelayo; Juste, Ramón; Barral, Marta; Gortazar, Christian

    2007-01-01

    In recent decades the management of large game mammals has become increasingly intensive in south central Spain (SCS), resulting in complex epidemiological scenarios for disease maintenance, and has probably impeded schemes to eradicate tuberculosis (TB) in domestic livestock. We conducted an analysis of risk factors which investigated associations between the pattern of tuberculosis-like lesions (TBL) in wild boar (Sus scrofa) and red deer (Cervus elaphus) across 19 hunting estates from SCS and an extensive set of variables related to game management, land use and habitat structure. The aggregation of wild boar at artificial watering sites was significantly associated with an increasing risk of detecting TBL in both species, which probably relates to enhanced opportunities for transmission. Aggregation of wild boar at feeding sites was also associated with increased risks of TBL in red deer. Hardwood Quercus spp. forest availability was marginally associated with an increased risk of TB in both species, whereas scrubland cover was associated with a reduced individual risk of TBL in the wild boar. It is concluded that management practices that encourage the aggregation of hosts, and some characteristics of Mediterranean habitats could increase the frequency and probability of both direct and indirect transmission of TB. These findings are of concern for both veterinary and public health authorities, and reveal tuberculosis itself as a potential limiting factor for the development and sustainability of such intensive game management systems in Spanish Mediterranean habitats.

  13. Historical and projected climate (1901–2050) and hydrologic response of karst aquifers, and species vulnerability in south-central Texas and western South Dakota

    Science.gov (United States)

    Stamm, John F.; Poteet, Mary F.; Symstad, Amy J.; Musgrove, MaryLynn; Long, Andrew J.; Mahler, Barbara J.; Norton, Parker A.

    2015-12-18

    Two karst aquifers, the Edwards aquifer in the Balcones Escarpment region of south-central Texas and the Madison aquifer in the Black Hills of western South Dakota, were evaluated for hydrologic response to projected climate change through 2050. Edwards aquifer sites include Barton Springs, the Bexar County Index Well, and Comal Springs. Madison aquifer sites include Spearfish Creek and Rhoads Fork Spring. Climate projections at sites were based on output from the Community Climate System Model of global climate, linked to the Weather Research and Forecasting (WRF) model of regional climate. The WRF model output was bias adjusted to match means for 1981–2010 from records at weather stations near Madison and Edwards aquifer sites, including Boerne, Texas, and Custer and Lead, South Dakota. Hydrologic response at spring and well sites was based on the Rainfall-Response Aquifer and Watershed Flow (RRAWFLOW) model. The WRF model climate projections for 2011–50 indicate a significant upward trend in annual air temperature for all three weather stations and a significant downward trend in annual precipitation for the Boerne weather station. Annual springflow simulated by the RRAWFLOW model had a significant downward trend for Edwards aquifer sites and no trend for Madison aquifer sites.

  14. Regional Climate Zone Modeling of a Commercial Absorption Heat Pump Hot Water Heater Part 1: Southern and South Central Climate Zones

    Energy Technology Data Exchange (ETDEWEB)

    Geoghegan, Patrick J [ORNL; Shen, Bo [ORNL; Keinath, Christopher M. [Stone Mountain Technologies, Inc., Johnson City; Garrabrant, Michael A. [Stone Mountain Technologies, Inc., Johnson City

    2016-01-01

    Commercial hot water heating accounts for approximately 0.78 Quads of primary energy use with 0.44 Quads of this amount from natural gas fired heaters. An ammonia-water based commercial absorption system, if fully deployed, could achieve a high level of savings, much higher than would be possible by conversion to the high efficiency nonheat-pump gas fired alternatives. In comparison with air source electric heat pumps, the absorption system is able to maintain higher coefficients of performance in colder climates. The ammonia-water system also has the advantage of zero Ozone Depletion Potential and low Global Warming Potential. A thermodynamic model of a single effect ammonia-water absorption system for commercial space and water heating was developed, and its performance was investigated for a range of ambient and return water temperatures. This allowed for the development of a performance map which was then used in a building energy modeling software. Modeling of two commercial water heating systems was performed; one using an absorption heat pump and another using a condensing gas storage system. The energy and financial savings were investigated for a range of locations and climate zones in the southern and south central United States. A follow up paper will analyze northern and north/central regions. Results showed that the system using an absorption heat pump offers significant savings.

  15. Impact of Forage Fertilization with Urea and Composted Cattle Manure on Soil Fertility in Sandy Soils of South-Central Vietnam

    Directory of Open Access Journals (Sweden)

    Keenan C. McRoberts

    2016-01-01

    Full Text Available Increased production in smallholder beef systems requires improved forage management. Our objective was to evaluate the effects of composted cattle manure and mineral nitrogen (urea application on soil fertility and partial nutrient balances in plots established to Brachiaria cv. Mulato II in south-central coastal Vietnam from 2010 to 2013. A randomized complete block design was implemented on six farms (blocks, with five rates of composted cattle manure (0, 4, 8, 12, and 24 Mg DM/ha per yr and three urea rates (0, 60, and 120 kg N/ha per yr in a factorial design. Soil was analyzed before and after the experiment. Compost increased soil pH, organic matter, Ca, Mg, and Mn. The effect of compost and urea applications on postexperiment soil fertility depended on preexperiment soil fertility for K, P, S, Mg, Zn, Mn, Cu, and organic matter, suggesting that the ability to maintain soil fertility depends on the interaction between soil organic and inorganic amendments and existing soil fertility. Highest farm yields were also achieved on farms with higher preexperiment soil fertility levels. Negative partial nutrient balances for N, P, and K suggest that yields will not be sustainable over time even for the highest fertilization inputs used in this experiment.

  16. Hf isotope study of Palaeozoic metaigneous rocks of La pampa province and implications for the occurrence of juvenile early Neoproterozoic (Tonian) magmatism in south-central Argentina

    Science.gov (United States)

    Chernicoff, C. J.; Zappettini, E. O.; Santos, J. O. S.; Belousova, E.; McNaughton, N. J.

    2011-12-01

    On a global scale, juvenile Tonian (Early Neoproterozoic) magmatic rocks are associated with the extensional events that lead to the breakup of the Rodinia supercontinent. In Argentina, no geological record is available for this time interval, lasting from 1000 to 850 Ma. We present indirect evidence for the existence of Tonian extension in Argentina, as supported by Hf and Nd isotope determinations on Phanerozoic magmatic and sedimentary rocks. We mainly focus on our own Hf isotope determinations carried out on U-Pb SHRIMP dated zircons from Palaeozoic metaigneous rocks of La Pampa province, south-central Argentina, i.e. metagabbros of Valle Daza, dioritic orthogneiss of Estancia Lote 8, and metadiorite of Estancia El Carancho, having found that these rocks were derived from sources of ca. 920 to ca 880 Ma, with ɛHf values between +6.83 and + 9.59. Inherited zircons of this age and character identified in these rocks also point to the same source. We also compile additional Hf and Nd studies from previous work on Phanerozoic magmatic and sedimentary rocks. We preliminarily compare the age of the juvenile Tonian sources referred to in our work with that of two extensional events identified in the São Francisco craton, Brazil.

  17. Vegetative Propagation Trial of Prosopis africana (Guill. et Perr. Taub. by Air Layering under Sudano-Sahelian Climate in the South-Central Niger

    Directory of Open Access Journals (Sweden)

    Laouali Abdou

    2015-01-01

    Full Text Available Prosopis africana is a species of great socioeconomic importance but threatened with extinction in Niger because of overuse and regeneration problem. This study, conducted in the Maradi (Niger area, precisely at El Gueza in the south of Gazaoua department, aims to evaluate the vegetative propagation capacity of P. africana by air layering under the Sudano-Sahelian climate of the south-central Niger. A ring of bark was taken on each selected branch and the wound was covered with a black plastic filled with a damp mixture of soil and wood debris. The chosen parameters are the diameter class and the position on the branch. In all, 60 branches were treated and followed for 130 days: 28.33% produced shoots and there was no significant difference between the diameter classes and between the positions. These results show that propagating trees of the species by air layering is possible and this technique can be used to multiply and keep this species, which will reduce the regeneration problem linked to a low seed germination rate.

  18. [Relationships between vegetation characteristics and soil properties at different restoration stages on slope land with purple soils in Hengyang of Hunan Province, South-central China].

    Science.gov (United States)

    Yang, Ning; Zou, Dong-Sheng; Yang, Man-Yuan; Hu, Li-Zhen; Zou, Fang-Ping; Song, Guang-Tao; Lin, Zhong-Gui

    2013-01-01

    By using space series to replace time series, this paper studied the relationships between the vegetation characteristics and soil properties at different restoration stages on the slope land with purple soils in Hengyang of Hunnan Province South-central China. There existed obvious differences in the soil physical and chemical properties at different restoration stages. From grassplot, grass-shrub, shrub to shrub-arbor, the soil organic matter, total and available N, and moisture contents increased markedly, soil bulk density had an obvious decrease, soil total and available P contents changed little, and soil pH decreased gradually, but no significant differences were observed among different restoration stages. At different restoration stages, the biomass of plant community had effects on the quantity and composition of soil microbes. The quantities of soil bacteria and fungi had significant positive correlations with the aboveground biomass of plant community, but the quantity of soil actinomycetes had less correlation with plant community's aboveground biomass. At different restoration stages, the activities of soil urease, protease, alkaline phosphatase, invertase, cellulase, catalase, and polyphenol oxidase decreased with increasing soil layer, and had significant positive correlations with plant community's richness and aboveground biomass.

  19. Water quality and relation to taste-and-odor compounds in North Fork Ninnescah River and Cheney Reservoir, south-central Kansas, 1997-2003

    Science.gov (United States)

    Christensen, Victoria G.; Graham, Jennifer L.; Milligan, Chad R.; Pope, Larry M.; Ziegler, Andrew C.

    2006-01-01

    Cheney Reservoir, the primary water supply for the city of Wichita in south-central Kansas, and its main source of inflow, the North Fork Ninnescah River, were sampled between 1997 and 2003 for sediment, nutrients, and the taste-and-odor-causing compounds geosmin and 2-methylisoborneol (MIB). It is believed that objectionable tastes and odors in Cheney Reservoir result from cyanobacteria (blue-green algae), and there is concern with proliferation of algal growth. Both nutrients and suspended solids affect algal growth and may be a concern for taste-and-odor issues. The transport of nutrients and suspended solids from the North Fork Ninnescah River to Cheney Reservoir was monitored as part of an effort to understand and thereby mitigate algal proliferation. The regression-estimated concentrations of total phosphorus in water entering the reservoir from the North Fork Ninnescah River during 2001–03 exceeded the base-flow, runoff, and long-term goals established by the Cheney Reservoir Task Force. Total suspended-solids concentrations in water from the North Fork Ninnescah River during 2001–03 generally exceeded long-term goals only during periods of runoff.

  20. PAH concentrations in the moss species Hylocomium splendens (Hedw.) B.S.G. and Pleurozium schreberi (Brid.) Mitt. from the Kielce area (south-central Poland).

    Science.gov (United States)

    Dołęgowska, Sabina; Migaszewski, Zdzisław M

    2011-09-01

    Forty eight samples of mosses Hylocomium splendens and Pleurozium schreberi from the Kielce area (south-central Poland) were analyzed for seventeen polycyclic aromatic hydrocarbons. The PAH concentrations varied from 558.00 μg/kg (ppb) to 4457.00 μg/kg in H. splendens and from 643.00 to 3086.00 μg/kg in P. schreberi. In both moss species phenanthrene (75.00-732.00 μg/kg), fluoranthene (101.00-577.00 μg/kg) and pyrene (68.00-568.00 μg/kg) predominated, but H. splendens accumulated more PAHs than P. schreberi at eighteen different sites. The highest PAH concentrations were noted at sites located close to the housing estates (sites 1-10) and potential emission sources (e.g. heat and power generating plant "Kielce S.A.") (sites 19-21). The moss samples displayed the diverse ring sequence, but the most prevalent was four>five>three>six. The diagnostic ratios (three+four ring/total PAHs, Flu/Py, Phen/Ant, Phen/Phen+Ant, Flu/Flu+Py, IndPy/IndPy+BghiPe and BaA/BaA+Chr) indicated that coal and petroleum combustion was a principal PAH source in the study area.

  1. Differentiating simple and composite tectonic landscapes using numerical fault slip modeling with an example from the south central Alborz Mountains, Iran

    KAUST Repository

    Landgraf, A.

    2013-09-01

    The tectonically driven growth of mountains reflects the characteristics of the underlying fault systems and the applied tectonic forces. Over time, fault networks might be relatively static, but stress conditions could change and result in variations in fault slip orientation. Such a tectonic landscape would transition from a “simple” to a “composite” state: the topography of simple landscapes is correlated with a single set of tectonic boundary conditions, while composite landscapes contain inherited topography due to earlier deformation under different boundary conditions. We use fault interaction modeling to compare vertical displacement fields with topographic metrics to differentiate the two types of landscapes. By successively rotating the axis of maximum horizontal stress, we produce a suite of vertical displacement fields for comparison with real landscapes. We apply this model to a transpressional duplex in the south central Alborz Mountains of Iran, where NW oriented compression was superseded by neotectonic NE compression. The consistency between the modeled displacement field and real landforms indicates that the duplex topography is mostly compatible with the modern boundary conditions, but might include a small remnant from the earlier deformation phase. Our approach is applicable for various tectonic settings and represents an approach to identify the changing boundary conditions that produce composite landscapes. It may be particularly useful for identifying changes that occurred in regions where river profiles may no longer record a signal of the change or where the spatial pattern of uplift is complex.

  2. Optimisation of a wet FGD pilot plant using fine limestone and organic acids

    DEFF Research Database (Denmark)

    Frandsen, Jan; Kiil, Søren; Johnsson, Jan Erik

    2001-01-01

    The effects of adding an organic acid or using a limestone with a fine particle size distribution (PSD) have been examined in a wet flue gas desulphurisation (FGD) pilot plant. Optimisation of the plant with respect to the degree of desulphurisation and the residual limestone content of the gypsum......, but the residual limestone content in the gypsum increased to somewhere between 19 and 30 wt%, making this pH range unsuitable for use in a full-scale plant. The investigations have shown that both the addition of organic acids and the use of a limestone with a fine PSD can be used to optimise wet FGD plants. (C...

  3. Coralgal facies of the Upper Eocene-Lower Oligocene limestones in Letca-Rastoci area

    Directory of Open Access Journals (Sweden)

    Ioana Prica

    2001-09-01

    Full Text Available In this paper are described the coralgal facies identified in the Upper Eocene-Lower Oligocene limestone succession (Cozla Formation outcropping in two quarries at Letca and Rastoci (Sălaj district, Romania. In the studied profiles the coral and algae limestones are interlayered with bioclastic limestones with foraminifera. On the top of relatively deep water deposits, coral and algae crusts and dendritic corals coated by algae were deposited. The environment registered a gradual deepening, the deposits being completely immersed, while bioclastic limestones with foraminifera were recurrently formed. This cycle is repeated, the whole succession being caracterized by several such “parasequences”.

  4. Limestone particle size and artificial light for laying hens in the second laying cycle

    Directory of Open Access Journals (Sweden)

    Alexsandro Nunes de Oliveira

    2013-07-01

    Full Text Available The experiment was conducted to evaluate the effects of limestone particle size and the use of artificial light for laying hens in the second laying cycle. We used 240 Hisex White laying hens at 82 weeks of age in a completely randomized design in a 5 × 2 factorial arrangement, resulting in 10 treatments with 4 replicates of 6 birds. The variables were the five particle sizes obtained by increasing the proportion of thick limestone (0, 25, 50, 75 and 100% compared with thin limestone and two lighting programs: with and without artificial light. Limestone particle size and light did not affect performance or egg quality. However, there were changes in bird feeding schedule throughout the day as a response to the lighting program. Bone quality, density and mineral content of the tibia were not affected by the treatments, but limestone particle size had a quadratic effect of on bone deformity and strength, obtaining maximum inclusion points with 63% and 59% of thick limestone, respectively. The use of large particles of limestone in the diet and the use of a lighting program does not influence the performance and quality of the eggs of laying hens in the second production cycle, but the use of a proportion of 63.3 g of average particle size (0.60 mm replacing the fine limestone (0.23 mm per 100 g of total limestone added to the diet improves bone quality in these birds.

  5. The effect of water on the sulphation of limestone

    Energy Technology Data Exchange (ETDEWEB)

    Chunbo Wang; Lufei Jia; Yewen Tan; E.J. Anthony [North China Electric Power University, Baoding City (China). School of Energy and Power Engineering

    2010-09-15

    A series of tests was conducted in a thermogravimetric analyzer (TGA) to study the sulphation behaviour of limestone in the presence of water over the temperature range of 800-850{sup o}C. Four different Canadian limestones, all with a particle size range of 75-425 {mu}m, were sulphated using a synthetic flue gas with a composition of 15% CO{sub 2}, 3% O{sub 2}, 0% or 10% H{sub 2}O, 1750 ppm SO{sub 2} and the balance N{sub 2}. Water was shown to have a significant promotional effect on sulphation, especially in the diffusion-controlled stage. However, the effect of water during the kinetic-controlled stage appeared to be much less pronounced. Based on these results, it is proposed that the presence of water leads to the transient formation of Ca(OH){sub 2} as an intermediate, which in turn reacts with SO{sub 2} at a faster rate than CaO does. Alternatively stated, it appears that H{sub 2}O acts as catalyst for the sulphation reaction of CaO. 30 refs., 8 figs., 3 tabs.

  6. Characteristics of acric luvisol on Magleš limestones

    Directory of Open Access Journals (Sweden)

    Knežević Milan

    2006-01-01

    Full Text Available Very deep soils with clearly differentiated two-layered profile physiography were studied on the limestones of the mountain Magleš. The very marked morphological differentiation of the profile is followed by significant textural differences and the variation of chemical characteristics of the soils. The profiles are 80-140 cm deep. The topsoil part of the solum, yellow-brown in colour, is 30-90 cm deep. Its textural class is silty-clay loam. Its chemical characteristics are very acid reaction and very low degree of base saturation. The relic (B horizon is reddish brown in colour, and it is characterized by a very high percentage of the colloidal clay, it is highly plastic and it has a compact structure. Its reaction is mostly weak acid to neutral, and the degree of base saturation is very high. The study results confirm the hypothesis of a very high impact of the Aeolian process on the formation of deep two-layered profiles on Magleš limestones.

  7. Laser removal of water repellent treatments on limestone

    Science.gov (United States)

    Gómez-Heras, Miguel; Alvarez de Buergo, Mónica; Rebollar, Esther; Oujja, Mohamed; Castillejo, Marta; Fort, Rafael

    2003-12-01

    Protective and water repellent treatments are applied on stone materials used on buildings or sculptures of artistic value to reduce water intrusion without limiting the natural permeability to water vapour of the material. The effect of the wavelength associated with the laser removal of two water repellent treatments applied on limestone, Paraloid B-72, a copolymer of methyl acrylate and ethyl methacrylate, and Tegosivin HL-100, a modified polysiloxane resin, was investigated by using the four harmonics of a Q-switched Nd:YAG laser (1064, 532, 355 and 266 nm). The modifications induced on the surface of limestone samples by laser irradiation were studied using colorimetry, roughness measurements and scanning electron microscopy (SEM). The removal of the treatments was found to be dependent on the laser irradiation conditions and on the characteristics of the coatings. The fundamental laser radiation was effective in removing both treatments, but thermal alteration processes were induced on the constituent calcite crystals. The best results were obtained by irradiation in the near UV at 355 nm.

  8. Laser removal of water repellent treatments on limestone

    Energy Technology Data Exchange (ETDEWEB)

    Gomez-Heras, Miguel; Alvarez de Buergo, Monica; Rebollar, Esther; Oujja, Mohamed; Castillejo, Marta; Fort, Rafael

    2003-12-15

    Protective and water repellent treatments are applied on stone materials used on buildings or sculptures of artistic value to reduce water intrusion without limiting the natural permeability to water vapour of the material. The effect of the wavelength associated with the laser removal of two water repellent treatments applied on limestone, Paraloid B-72, a copolymer of methyl acrylate and ethyl methacrylate, and Tegosivin HL-100, a modified polysiloxane resin, was investigated by using the four harmonics of a Q-switched Nd:YAG laser (1064, 532, 355 and 266 nm). The modifications induced on the surface of limestone samples by laser irradiation were studied using colorimetry, roughness measurements and scanning electron microscopy (SEM). The removal of the treatments was found to be dependent on the laser irradiation conditions and on the characteristics of the coatings. The fundamental laser radiation was effective in removing both treatments, but thermal alteration processes were induced on the constituent calcite crystals. The best results were obtained by irradiation in the near UV at 355 nm.

  9. Characterizing and modelling 'ghost-rock' weathered limestones

    Science.gov (United States)

    Dubois, Caroline; Goderniaux, Pascal; Deceuster, John; Poulain, Angélique; Kaufmann, Olivier

    2016-04-01

    'Ghost-rock' karst aquifer has recently been highlighted. In this particular type of aquifer, the karst is not expressed as open conduits but consists in zones where the limestone is weathered. The in-situ weathering of limestone leaves a soft porous material called 'alterite'. The hydro-mechanical properties of this material differs significantly from those of the host rock: the weathering enhances the storage capacity and the conductivity of the rock. This type of weathered karst aquifer has never been studied from a hydrogeological point of view. In this study, we present the hydraulic characterization of such weathered zones. We also present a modelling approach derived from the common Equivalent Porous Medium (EPM) approach, but including the spatial distribution of hydrogeological properties through the weathered features, from the hard rock to the alterite, according to a weathering index. Unlike the Discrete Fracture Network (DFN) approaches, which enable to take into account a limited number of fractures, this new approach allows creating models including thousands of weathered features. As the properties of the alterite have to be considered at a centimeter scale, it is necessary to upscale these properties to carry out simulations over large areas. Therefore, an upscaling method was developed, taking into account the anisotropy of the weathered features. Synthetic models are built, upscaled and different hydrogeological simulations are run to validate the method. This methodology is finally tested on a real case study: the modelling of the dewatering drainage flow of an exploited quarry in a weathered karst aquifer in Belgium.

  10. Hydrogeology of the gray limestone aquifer in southern Florida

    Science.gov (United States)

    Reese, Ronald S.; Cunningham, Kevin J.

    2000-01-01

    Results from 35 new test coreholes and aquifer-test, water-level, and water-quality data were combined with existing hydrogeologic data to define the extent, thickness, hydraulic properties, and degree of confinement of the gray limestone aquifer in southern Florida. This aquifer, previously known to be present only in southeastern Florida (Miami-Dade, Broward, and Palm Beach Counties) below, and to the west of, the Biscayne aquifer, extends over most of central-south Florida, including eastern and central Collier County and southern Hendry County; it is the same as the lower Tamiami aquifer to the north, and it becomes the water-table aquifer and the upper limestone part of the lower Tamiami aquifer to the west. The aquifer generally is composed of gray, shelly, lightly to moderately cemented limestone with abundant shell fragments or carbonate sand, abundant skeletal moldic porosity, and minor quartz sand. The gray limestone aquifer comprises the Ochopee Limestone of the Tamiami Formation, and, in some areas, the uppermost permeable part of an unnamed formation principally composed of quartz sand. Underlying the unnamed formation is the Peace River Formation of the upper Hawthorn Group, the top of which is the base of the surficial aquifer system. Overlying the aquifer and providing confinement in much of the area is the Pinecrest Sand Member of the Tamiami Formation. The thickness of the aquifer is comparatively uniform, generally ranging from 30 to 100 feet. The unnamed formation part of the aquifer is up to 20 feet thick. The Ochopee Limestone accumulated in a carbonate ramp depositional system and contains a heterozoan carbonate-particle association. The principal rock types of the aquifer are pelecypod lime rudstones and floatstones and permeable quartz sands and sandstones. The pore types are mainly intergrain and separate vug (skeletal-moldic) pore spaces. The rock fabric and associated primary and secondary pore spaces combine to form a dual diffuse

  11. Stress-Induced Permeability Alterations in an Argillaceous Limestone

    Science.gov (United States)

    Selvadurai, A. P. S.; Głowacki, A.

    2017-05-01

    The paper presents the results of experiments that were conducted to determine the influence of a triaxial stress state on the evolution of the permeability of an argillaceous limestone. The limestone rock is found in the Ordovician rock formations above the Precambrian basement located in southern Ontario, Canada, which is being considered as a potential host rock for the construction of a deep ground repository for storing low- and intermediate-level nuclear waste. The paper presents the results of an extensive series of hydraulic pulse tests and steady-state tests that were conducted to determine the permeability alterations in zones that can experience levels of damage that can be present in vicinity of an excavated underground opening. A "state-space" relationship is developed to describe permeability evolution with the triaxial stress in the pre-failure regime. The permeability evolution in extensively damaged post-failure states of the rock is also investigated. It is shown that permeability alterations were four orders of magnitude higher as a result of significant damage to the material, which is an important consideration in establishing the efficiency of the host rock formation as a barrier for the long-term containment of radionuclide migration.

  12. Colmenar limestone as a resource for built heritage

    Science.gov (United States)

    Fort, Rafael; Álvarez de Buergo, Mónica; Varas-Muriel, MªJosé; Mercedes Pérez-Monserrat, Elena

    2013-04-01

    The Colmenar stone (or Colmenar limestone) has been used in the construction of significant builidings of the Central area of Spain, such as the Royal Palace of Aranjuez (16th -18th centuries) or the Royal Palace of Madrid (18th century). Nowadays this building stone is still widely used, both for new construction and restoration works, as well as for the indoor ornamentation of emblematic buildings such as the Royal Theater of Madrid (20th century). There are many quarries from where this stone was exploited, being the most prestigious ones those located in Colmenar de Oreja, at 50 km Southeast the city of Madrid. The high quality of the stone in these quarries, its whiteness and pureness, made this locality the most relevant in these stonés extractive activities, concentrating the most relevant exploitations and providing the stone the denomination of the municipality (Colmenar). It was an underground mining extraction until the 20th century in order to reach the highest quality level of the mine, the so called "Banco Gordo" (Thick Bank). Generically known as moorland limestone, this rock belongs to the fluvial-lacustrine carbonates of the Upper Miocene Unit of the Tertiary Madrid's Basin. Its tonality mainly ranges from white to cream and even light grey. Under a petrographic point of view, this limestone is constituted by 40% of bioclasts (characea, ostracods and gasteropods), 20-30% of micritic matrix and 30-40% of sparitic cement. Therefore, it can be classified as a biomicrite/biosparite limestone or as a bioclastic packstone. Some particularities of these limestones regarding their appearance are related to some karstic processes they underwent linked to some dissolution phenomena during the Pliocene. All of this resulted on an abundance of cavities with terra rossa fillings, a non-soluble clayey residue, iron enriched, which is the responsible for the reddish and pinkish color that the Colmenar stone sometimes shows. These petrographic characteristics

  13. Crystallographic transformation of limestone during calcination under CO2.

    Science.gov (United States)

    Valverde, Jose Manuel; Medina, Santiago

    2015-09-14

    The calcination reaction of limestone (CaCO3) to yield lime (CaO) is at the heart of many industrial applications as well as natural processes. In the recently emerged calcium-looping technology, CO2 capture is accomplished by the carbonation of CaO in a gas-solid reactor (carbonator). CaO is derived by the calcination of limestone in a calciner reactor under necessarily high CO2 partial pressure and high temperature. In situ X-ray diffraction (XRD) has been employed in this work to gain further insight into the crystallographic transformation that takes place during the calcination of limestone under CO2, at partial pressures (P) close to the equilibrium pressure (Peq) and at high temperature. Calcination under these conditions becomes extremely slow. The in situ XRD analysis presented here suggests the presence of an intermediate metastable CaO* phase stemming from the parent CaCO3 structure. According to the reaction mechanism proposed elsewhere, the exothermicity of the CaO* → CaO transformation and high values of P/Peq inhibit the nucleation of CaO at high temperatures. The wt% of CaO* remains at a relatively high level during slow calcination. Two diverse stages have been identified in the evolution of CaO crystallite size, L. Initially, L increases with CaCO3 conversion, following a logarithmic law. Slow calcination allows the crystallite size to grow up from a few nanometers at nucleation up to around 100 nm near the end of conversion. Otherwise, quick calcination at relatively lower CO2 concentrations limits CaO crystallite growth. Once calcination reaches an advanced state, the presence of CaO* drops to zero and the rate of increase of the CaO crystallite size is significantly hindered. Arguably, the first stage in CaO crystallite growth is driven by aggregation of the metastable CaO* nanocrystals, due to surface attractive forces, whereas the second one is consistent with sintering of the aggregated CaO crystals, and persists with time after full

  14. Occurrence of methane in groundwater of south-central New York State, 2012-systematic evaluation of a glaciated region by hydrogeologic setting

    Science.gov (United States)

    Heisig, Paul M.; Scott, Tia-Marie

    2013-01-01

    A survey of methane in groundwater was undertaken to document methane occurrence on the basis hydrogeologic setting within a glaciated 1,810-square-mile area of south-central New York along the Pennsylvania border. Sixty-six wells were sampled during the summer of 2012. All wells were at least 1 mile from any known gas well (active, exploratory, or abandoned). Results indicate strong positive and negative associations between hydrogeologic settings and methane occurrence. The hydrogeologic setting classes are based on topographic position (valley and upland), confinement or non-confinement of groundwater by glacial deposits, well completion in fractured bedrock or sand and gravel, and hydrogeologic subcategories. Only domestic wells and similar purposed supply wells with well-construction and log information were selected for classification. Field water-quality characteristics (pH, specific conductance, dissolved oxygen, and temperature) were measured at each well, and samples were collected and analyzed for dissolved gases, including methane and short-chain hydrocarbons. Carbon and hydrogen isotopic ratios of methane were measured in 21 samples that had at least 0.3 milligram per liter (mg/L) of methane. Results of sampling indicate that occurrence of methane in groundwater of the region is common—greater than or equal to 0.001 mg/L in 78 percent of the groundwater samples. Concentrations of methane ranged over five orders of magnitude. Methane concentrations at which monitoring or mitigation are indicated (greater than or equal to 10 mg/L) were measured in 15 percent of the samples. Methane concentrations greater than 0.1 mg/L were associated with specific hydrogeologic settings. Wells completed in bedrock within valleys and under confined groundwater conditions were most closely associated with the highest methane concentrations. Fifty-seven percent of valley wells had greater than or equal to 0.1 mg/L of methane, whereas only 10 percent of upland wells

  15. Quaternary Tectonic Tilting Governed by Rupture Segments Controls Surface Morphology and Drainage Evolution along the South-Central Coast of Chile

    Science.gov (United States)

    Echtler, H. P.; Bookhagen, B.; Melnick, D.; Strecker, M.

    2004-12-01

    The Chilean coast represents one of the most active convergent margins in the Pacific rim, where major earthquakes (M>8) have repeatedly ruptured the surface, involving vertical offsets of several meters. Deformation along this coast takes place in large-scale, semi-independent seismotectonic segments with partially overlapping transient boundaries. They are possibly related to reactivated inherited crustal anisotropies; internal seismogenic deformation may be accommodated by structures that have developed during accretionary wedge evolution. Seismotectonic segmentation and the identification of large-scale rupture zones, however, are based on limited seismologic und geodetic observations over short timespans. In order to better define the long-term behavior and deformation rates of these segments and to survey the tectonic impact on the landscape on various temporal and spatial scales, we investigated the south-central coast of Chile (37-38S). There, two highly active, competing seismotectonic compartments influence the coastal and fluvial morphology. A rigorous analysis of the geomorphic features is a key for an assessment of the tectonic evolution during the Quaternary and beyond. We studied the N-S oriented Santa María Island (SMI), 20 km off the coast and only ~70km off the trench, in the transition between the two major Valdivia (46-37S) and Concepción (38-35S) rupture segments. The SMI has been tectonically deformed throughout the Quaternary and comprises two tilt domains with two topographic highs in the north and south that are being tilted eastward. The low-lying and flat eastern part of the island is characterized by a set of emergent Holocene strandlines related to coseismic uplift. We measured detailed surface morphology of these strandlines and E-W traversing ephemeral stream channels with a laser-total station and used these data to calibrate and validate high-resolution, digital imagery. In addition, crucial geomorphic markers were dated by the

  16. New data concerning the age of Mesozoic limestone from Scarisoara (Bihor Mountains

    Directory of Open Access Journals (Sweden)

    Ioan I. Bucur

    2000-09-01

    Full Text Available Microfacies and micropalaeontologic studies on some limestone samples collected within the Scărişoara Glacier Cave are presented. The investigation pointed out that the age of the limestone around Scărişoara Cave is of Upper Jurassic (Kimmeridgian age and not Triassic as it was considered in most of the studies.

  17. Carbonate petrology of algal limestones (Lois-Ciguera Formation, Upper Carboniferous, León, Spain)

    NARCIS (Netherlands)

    Meijer, de J.J.

    1971-01-01

    The Lois-Ciguera Formation is a unit of alternating limestones and terrigenous sediments of Lower to Upper Moscovian age in the Cantabrian Mountains of northern Spain. The proportion of limestones is fairly high, 30 to 50% of the total thickness. In the eastern part of the Lois-Ciguera Synclinorium,

  18. GEOPHYSICAL AND LABORATORY STUDIES OF THE SPREAD AND QUALITY OF THE ODUKPANI LIMESTONE DEPOSIT

    Directory of Open Access Journals (Sweden)

    A. E. Akpan

    2014-01-01

    Full Text Available The Odukpani limestone deposit has been investigated using geophysical and laboratory techniques with the aim of generating information on its spread and quality. Information generated from the analyses of twenty-six Vertical Electrical Soundings (VES and core drilling data were used in the study. The VES data were acquired in both grid and random patterns in the immediate area of the limestone mineralisation and the adjoining areas using the Schlumberger array was adopted in acquiring the VES data in both grid and random patterns in the limestone mineralized and the adjoining areas. Cored limestone samples were analysed using the Proton Induced X-ray Emission (PIXE method in order to determine their elemental composition and consequently quality. Both manual and computer modeling techniques were used in modeling the VES. Results show that the limestones have limited spread and have high concentration of Ca ((11,200% and K (302,400%. Mean electrical resistivity of the limestone horizon is 405 Ωm which is suggestive of a limestone deposit that is not pure but contaminated with Fe (8,620%, shaly and other contaminants. The limestone deposit is limited in both vertical and lateral extents. Thus the deposit will not favor any large scale mining operation and equipment deployed for its exploitation must be corrosion resistant type.

  19. Development of engineered cementitious composites with limestone powder and blast furnace slag

    NARCIS (Netherlands)

    Zhou, J.; Qian, S.; Sierra Beltran, M.G.; Ye, G.; Van Breugel, K.; Li, V.C.

    2009-01-01

    Nowadays limestone powder and blast furnace slag (BFS) are widely used in concrete as blended materials in cement. The replacement of Portland cement by limestone powder and BFS can lower the cost and enhance the greenness of concrete, since the production of these two materials needs less energy an

  20. Oriented nucleation and growth of anhydrite during direct sulfation of limestone

    DEFF Research Database (Denmark)

    Hu, Guilin; Dam-Johansen, Kim; Wedel, Stig

    2008-01-01

    The direct sulfation of limestone (Iceland Spar) was studied at 973 K in a fixed-bed reactor. Scanning electron microscopy examinations of the sulfated limestone particles show that the sulfation process involves oriented nucleation and growth of the solid product, anhydrite. The reason...

  1. Assessment of the state of conservation of a Middle Neolithic flint mine in Maastricht limestone

    NARCIS (Netherlands)

    Van Hees, R.P.J.; Nijland, T.G.

    2009-01-01

    Upper Cretaceous Maastricht limestone ("mergel") outcrops in the provinces of Dutch and Belgian Limburg. The Upper Cretaceous in the Netherlands consists of the geological Maastricht Formation and the upper part of the Gulpen Formation. Limestones from the Maastricht Formation represent one of the f

  2. Assessment of the state of conservation of a Middle Neolithic flint mine in Maastricht limestone

    NARCIS (Netherlands)

    Hees, R.P.J. van; Nijland, T.G.

    2009-01-01

    Upper Cretaceous Maastricht limestone (‘mergel’) outcrops in the provinces of Dutch and Belgian Limburg. The Upper Cretaceous in the Netherlands consists of the geological Maastricht Formation and the upper part of the Gulpen Formation. Limestones from the Maastricht Formation represent one of the f

  3. STEAM ENHANCED REMEDIATION RESEARCH FOR DNAPL IN FRACTURED ROCK, LORING AIR FORCE BASE, LIMESTONE, MAINE

    Science.gov (United States)

    This report details a research project on Steam Enhanced Remediation (SER) for the recovery of volatile organic compounds from fractured limestone that was carried out at the Quarry at the former Loring Air Force Base in Limestone, Maine. This project was carried out by USEPA, Ma...

  4. Adsorption and desorption of phosphate on limestone in experiments simulating seawater intrusion

    Science.gov (United States)

    The absorption and desorption of phosphorus on a large block of limestone was investigated using deionized water (DIW) and seawater. The limestone had a high affinity to adsorb phosphorus in DIW. Phosphate adsorption was significantly less in seawater, and more phosphorus was desorbed in the seawate...

  5. LATEST TOURNAISIAN (EARLY CARBONIFEROUS CONODONTS FROM THE TABAI LIMESTONE, TIRAH, NORTHWESTERN PAKISTAN

    Directory of Open Access Journals (Sweden)

    FAZL-I-RABBI KHAN

    2004-11-01

    Full Text Available A new stratigraphic unit, the Tabai Limestone of the poorly known Tirah area of northwest Pakistan, is one of several Early Carboniferous carbonate units distributed along the North Gondwana margin, some connected with transgressive interludes. The Tabai Limestone has produced latest Tournaisian (Early Carboniferous conodonts indicative of the middle of the anchoralis-latus Zone.

  6. Specialized consultant in radiological safety to the south central hospital of high speciality, PEMEX. V. - November of 2001; Asesoria especializada en seguridad radiologica al hospital central sur de alta especialidad, PEMEX. V.- Noviembre de 2001

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Vizuet G, J.; Benitez S, J. A.; Garcia A, J.; Rodriguez A, F

    2002-01-15

    The south central hospital of high speciality, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray equipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the hospital can conserve its respective sanitary license.(Autho000.

  7. Specialized consultant in radiological safety to the south central hospital of high speciality, PEMEX. III.- September of 2001; Asesoria especializada en seguridad radiologica al hospital central sur de alta especialidad, PEMEX III.- Septiembre de 2001

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Vizuet G, J.; Benitez S, J. A.; Rodriguez A, F.; Garcia A, J

    2001-12-15

    The south central hospital of high speciality, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray equipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the hospital can conserve its respective sanitary license.(Author)

  8. Specialized consultant in radiological safety to the south central hospital of high speciality, PEMEX. IV. - October of 2001; Asesoria especializada en seguridad radiologica a la clinica al hospital central sur de alta especialidad, PEMEX. IV.- Octubre de 2001

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Vizuet G, J.; Benitez S, J. A.; Garcia A, J.; Rodriguez A, F

    2002-01-15

    The south central hospital of high speciality, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray equipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the hospital can conserve its respective sanitary license.(Author)

  9. Specialized consultant in radiological safety to the south central hospital of high speciality, PEMEX. I. - July of 2001; Asesoria especializada en seguridad radiologica al hospital central sur de alta especialidad, PEMEX I.- Julio de 2001

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Vizuet G, J

    2001-09-15

    The south central hospital of high speciality, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray equipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the hospital can conserve its respective sanitary license.(Author)

  10. Specialized consultant in radiological safety to the south central hospital of high speciality, PEMEX. II.- August of 2001; Asesoria especializada en seguridad radiologica al hospital central sur de alta especialidad, PEMEX II.- Agosto de 2001

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Vizuet G, J.; Benitez S, J. A.; Rodriguez A, F.; Garcia A, J

    2001-12-15

    The south central hospital of high speciality, dependent of PEMEX, It request consultant of the ININ to be able to maintain their sanitary license for the use of X-ray equipment for the radiologic diagnostic.The proposal of the ININ was to be a program of technical attendance, schedule monthly to be able to solve the observations that are presented in the use of those equipment, and that the hospital can conserve its respective sanitary license.(Author)

  11. Sierra Elvira limestone: petrophysical characteristics of an Andalusian heritage stone

    Directory of Open Access Journals (Sweden)

    Valverde, I.

    2008-06-01

    Full Text Available “Sierra Elvira stone” is one of the ornamental building stones most widely used in the historical monuments of eastern Andalusia. A Liassic age limestone, it appears in the central section of the Baetic Mountains and more specifically in the Middle Subbaetic domain. While the most common variety is a crinoid limestone, a micritic limestone of the same age has also been quarried, albeit in much smaller quantities. These stones form very thick beds, up to nearly 5 m deep, that run in consistently parallel lines and have a dip angle that facilitates quarrying.With petrographic, physical and mechanical properties that ensure stone strength and durability, it is a high quality building material suitable for both structural and ornamental purposes. These properties can be attributed to the minimal open porosity and concomitant excellent water resistance that characterize the stone, as well as to its high mechanical strength and low textural anisotropy, both elastic and mechanical. With such attributes, the stone can be successfully used for any number of purposes, including decorative stonework (portals, fountains, plinths, structural members (column shafts and bases or urban curbing and paving. Intervention on Sierra de Elvira limestone structures should be limited to cleaning or repair, for consolidating or protective materials are scantly effective.La “Piedra de Sierra Elvira” constituye una de las piedras ornamentales más significativas del Patrimonio Arquitectónico de Andalucía Oriental. Es una roca caliza del Lias que aflora en el Subbético Medio del sector central de las Cordilleras Béticas. El litotipo más explotado es una caliza con crinoides, en bastante menor importancia se ha extraído también otra caliza micrítica de la misma edad. Los bancos son muy potentes, en algunos casos de más de 5 m, con un paralelismo constante y un buzamiento que favorece su explotación en los frentes de cantera.Sus caracter

  12. Limestone fragmentation and attrition during fluidized bed oxyfiring

    Energy Technology Data Exchange (ETDEWEB)

    Fabrizio Scala; Piero Salatino [Istituto di Ricerche sulla Combustione - CNR, Napoli (Italy)

    2010-04-15

    Attrition/fragmentation of limestone under simulated fluidized bed oxyfiring conditions was investigated by means of an experimental protocol that had been previously developed for characterization of attrition/fragmentation of sorbents in air-blown atmospheric fluidized bed combustors. The protocol was based on the use of different and mutually complementary techniques. The extent and pattern of attrition by surface wear in the dense phase of a fluidized bed were assessed in experiments carried out with a bench scale fluidized bed combustor under simulated oxyfiring conditions. Sorbent samples generated during simulated oxyfiring tests were further characterized from the standpoint of fragmentation upon high velocity impact by means of a purposely designed particle impactor. Results showed that under calcination-hindered conditions attrition and fragmentation patterns are much different from those occurring under air-blown atmospheric combustion conditions. Noteworthy, attrition/fragmentation enhanced particle sulfation by continuously regenerating the exposed particle surface. 13 refs., 8 figs.

  13. Innovative Field Investigations in Limestone using a FACT-FLUTe

    DEFF Research Database (Denmark)

    Mosthaf, Klaus; Barrett Sørensen, Mie; Broholm, Mette Martina

    2015-01-01

    concentration and aqueous concentration can be established. This allows the FACT-FLUTe technology to be employed for the characterization of contaminant distribution in limestone aquifers. A comparison between the aqueous (pore water) concentrations calculated with the model from the FACT-FLUTE data...... activated carbon technique) is an innovative monitoring technique, which allows determining the distribution of a contaminant in the surrounding of a borehole with a higher resolution than conventional monitoring methods. The FACT technique proved to be a helpful tool for characterization of contaminant...... between measured sorbed concentration (mg/g AC) and the aqueous pore water concentration (mg/L). The objective of the research presented was to develop a tool for the interpretation of FACT measurements and apply it to the Naverland dataset for comparison with concentrations in groundwater samples sampled...

  14. Identification of Calcium Sulphoaluminate Formation between Alunite and Limestone

    Directory of Open Access Journals (Sweden)

    Hee-Chan Cho

    2009-06-01

    Full Text Available This study was carried out to identify the conditions of formation of calcium sulphoaluminate (3CaO·3Al2O3·CaSO4 by the sintering of a limestone (CaCO3 and alunite [K2SO4·Al2(SO43·4Al(OH3] mixture with the following reagents: K2SO4, CaCO3, Al(OH3, CaSO4·2H2O, and SiO2. When K2SO4, CaCO3, Al(OH3, CaSO4·2H2O were mixed in molar ratios of 1:3:6:3 and sintered at 1,200~1,300 °C, only 3CaO·3Al2O3·CaSO4 and calcium langbeinite (2CaSO4·K2SO4 were generated. With an amount of CaO that is less than the stoichiometric molar ratio, 3CaO·3Al2O3·CaSO4 was formed and anhydrite (CaSO4 did not react and remained behind. With the amount of CaSO4 that is less than the stoichiometric molar ratio, the amounts of 3CaO·3Al2O3·CaSO4 and 2CaSO4·K2SO4 decreased, and that of CaO·Al2O3 increased. In the K2SO4-CaO-Al2O3-CaSO4-SiO2 system, to stabilize the formation of 3CaO·3Al2O3·CaSO4, 2CaSO4·K2SO4, and β-2CaO·SiO2, the molar ratios of CaO: Al2O3: CaSO4 must be kept at 3:3:1 and that of CaO/SiO2, over 2.0; otherwise, the generated amount of 3CaO·3Al2O3·CaSO4 decreased and that of gehlenite (2CaO·Al2O3·SiO2 with no hydration increased quantitatively. Therefore, if all SO3(g generated by the thermal decomposition of alunite reacts with CaCO3 (or CaO, the thermal decomposition product of limestone to form CaSO4 in an alunite- limestone system, 1 mol of pure alunite reacts with 6 mol of limestone to form 1 mol of 3CaO·3Al2O3·CaSO4 and 1 mol of 2CaSO4·K2SO4.

  15. Identification of Calcium Sulphoaluminate Formation between Alunite and Limestone.

    Science.gov (United States)

    Kim, Hyung-Seok; Han, Gi-Chun; Ahn, Ji-Whan; Cho, Kye-Hong; Cho, Hee-Chan

    2009-01-01

    This study was carried out to identify the conditions of formation of calcium sulphoaluminate (3CaO·3Al(2)O(3)·CaSO(4)) by the sintering of a limestone (CaCO(3)) and alunite [K(2)SO(4)·Al(2)(SO(4))(3)·4Al(OH)(3)] mixture with the following reagents: K(2)SO(4), CaCO(3), Al(OH)(3), CaSO(4)·2H(2)O, and SiO(2). When K(2)SO(4), CaCO(3), Al(OH)(3), CaSO(4)·2H(2)O were mixed in molar ratios of 1:3:6:3 and sintered at 1,200∼1,300 °C, only 3CaO·3Al(2)O(3)·CaSO(4) and calcium langbeinite (2CaSO(4)·K(2)SO(4)) were generated. With an amount of CaO that is less than the stoichiometric molar ratio, 3CaO·3Al(2)O(3)·CaSO(4) was formed and anhydrite (CaSO(4)) did not react and remained behind. With the amount of CaSO(4) that is less than the stoichiometric molar ratio, the amounts of 3CaO·3Al(2)O(3)·CaSO(4) and 2CaSO(4)·K(2)SO(4) decreased, and that of CaO·Al(2)O(3) increased. In the K(2)SO(4)-CaO-Al(2)O(3)-CaSO(4)-SiO(2) system, to stabilize the formation of 3CaO·3Al(2)O(3)·CaSO(4), 2CaSO(4)·K(2)SO(4), and β-2CaO·SiO(2), the molar ratios of CaO: Al(2)O(3): CaSO(4) must be kept at 3:3:1 and that of CaO/SiO(2), over 2.0; otherwise, the generated amount of 3CaO·3Al(2)O(3)·CaSO(4) decreased and that of gehlenite (2CaO·Al(2)O(3)·SiO(2)) with no hydration increased quantitatively. Therefore, if all SO(3)(g) generated by the thermal decomposition of alunite reacts with CaCO(3) (or CaO, the thermal decomposition product of limestone) to form CaSO(4) in an alunite- limestone system, 1 mol of pure alunite reacts with 6 mol of limestone to form 1 mol of 3CaO·3Al(2)O(3)·CaSO(4) and 1 mol of 2CaSO(4)·K(2)SO(4).

  16. The Influence of Combustion-derived pollutants on limestone deterioration

    DEFF Research Database (Denmark)

    Johnson, J.B.; Montgomery, Melanie; Thompson, G.E.

    1996-01-01

    -ionized water at pH 5.5, for clean-rain base-line data, the relative effects of the Cl-, SO42- and NO3- components (5.2, 8.6 and 3.0 mg 1(-1) respectively) of an artificial acid-rain solution were studied. Using spray run-off solution rates of 0.2 mi cm(-2), day(-1) and pH values of 5.5 and 3.8, the work...... and Monks Park limestones, respectively. At pH 3.8 the individual anion recession rates were increased to 11.1 +/- 0.5 and 13.9 +/- 0.5 mu m yr(-1) respectively, similar to the rates of 12.5 +/- 1.6 and 13.8 +/- 2.2 mu m yr(-1) for the mixed anion artificial acid rain solution on Portland and Monks Park...

  17. Long-term responses of sandy beach crustaceans to the effects of coastal armouring after the 2010 Maule earthquake in South Central Chile

    Science.gov (United States)

    Rodil, Iván F.; Jaramillo, Eduardo; Acuña, Emilio; Manzano, Mario; Velasquez, Carlos

    2016-02-01

    Earthquakes and tsunamis are large physical disturbances frequently striking the coast of Chile with dramatic effects on intertidal habitats. Armouring structures built as societal responses to beach erosion and shoreline retreat are also responsible of coastal squeeze and habitat loss. The ecological implications of interactions between coastal armouring and earthquakes have recently started to be studied for beach ecosystems. How long interactive impacts persist is still unclear because monitoring after disturbance generally extends for a few months. During five years after the Maule earthquake (South Central Chile, February 27th 2010) we monitored the variability in population abundances of the most common crustacean inhabitants of different beach zones (i.e. upper, medium, and lower intertidal) at two armoured (one concrete seawall and one rocky revetment) and one unarmoured sites along the sandy beach of Llico. Beach morphology changed after the earthquake-mediated uplift, restoring upper- and mid-shore armoured levels that were rapidly colonized by typical crustacean species. However, post-earthquake increasing human activities affected the colonization process of sandy beach crustaceans in front of the seawall. Lower-shore crab Emerita analoga was the less affected by armouring structures, and it was the only crustacean species present at the three sites before and after the earthquake. This study shows that field sampling carried out promptly after major disturbances, and monitoring of the affected sites long after the disturbance is gone are effective approaches to increase the knowledge on the interactive effects of large-scale natural phenomena and artificial defences on beach ecology.

  18. Traditional Homegardens and Domestic Biomass Fuel Consumption Pattern in the Developing World: The Case of a South-Central Rural Village of Bangladesh

    Energy Technology Data Exchange (ETDEWEB)

    Mukul, S.A. (Dept. of Forestry and Environmental Science, School of Agriculture and Mineral sciences, Shahjalal Univ. of Science and Technology, Sylhet 3114 (Bangladesh)). E-mail: sharif_a_mukul@yahoo.com

    2008-10-15

    Peoples living in most developing countries meet majority of their biomass fuel requirements from the forest. However, this usual practice becomes difficult to maintain as the forest of this region decreases in an alarming rate. In such context, homegardens will have to play the key role in near future where in many forest poor regions it's already playing the vital role. An exploratory study was conducted in a south-central rural village of Bangladesh to realize this potential contribution of homegardens to households domestic biomass fuel supplies, which is as well a virtually forest poor region of the country. Households were grouped into three different land holding categories and a total of thirty respondents, 10 from each category were selected randomly to understand their domestic biomass fuel consumption pattern as well as the role of homegardens to meet this fuel supply. Study suggested that, majority (87%) of the households of the area rely extensively on their homegardens to meet their domestic cooking energy requirements. During the study 47 homestead species were identified having fuel value of which 12 were identified as the most preferred species in the area. The contribution of wood fuel in households domestic energy sharing was reported as 56% followed by dried leaves (21%), dung cake/sticks (14%), crop residues (6%) and others (3%). Study finally concluded for a rich homegarden system in forest near regions to conserve country's remaining forest by providing an alternative source of biomass fuel. A participatory management of governments' fallow and khas lands, public places including road, railway and canal banks for tree farming to benefit rural land-less and marginal people were also recommended

  19. A deglacial and Holocene record of climate variability in south-central Alaska from stable oxygen isotopes and plant macrofossils in peat

    Science.gov (United States)

    Jones, Miriam C.; Wooller, Matthew J.; Peteet, Dorothy M.

    2014-01-01

    We used stable oxygen isotopes derived from bulk peat (δ18OTOM), in conjunction with plant macrofossils and previously published carbon accumulation records, in a ∼14,500 cal yr BP peat core (HT Fen) from the Kenai lowlands in south-central Alaska to reconstruct the climate history of the area. We find that patterns are broadly consistent with those from lacustrine records across the region, and agree with the interpretation that major shifts in δ18OTOM values indicate changes in strength and position of the Aleutian Low (AL), a semi-permanent low-pressure cell that delivers winter moisture to the region. We find decreased strength or a more westerly position of the AL (relatively higher δ18OTOM values) during the Bølling-Allerød, Holocene Thermal Maximum (HTM), and late Holocene, which also correspond to warmer climate regimes. These intervals coincide with greater peat preservation and enhanced carbon (C) accumulation rates at the HT Fen and with peatland expansion across Alaska. The HTM in particular may have experienced greater summer precipitation as a result of an enhanced Pacific subtropical high, a pattern consistent with modern δ18O values for summer precipitation. The combined warm summer temperatures and greater summer precipitation helped promote the observed rapid peat accumulation. A strengthened AL (relatively lower δ18OTOM values) is most evident during the Younger Dryas, Neoglaciation, and the Little Ice Age, consistent with lower peat preservation and C accumulation at the HT Fen, suggesting less precipitation reaches the leeward side of the Kenai Mountains during periods of enhanced AL strength. The peatlands on the Kenai Peninsula thrive when the AL is weak and the contribution of summer precipitation is higher, highlighting the importance of precipitation seasonality in promoting peat accumulation. This study demonstrates that δ18OTOM values in peat can be applied toward understand large-scale shifts in atmospheric circulation

  20. Interactions and potential implications of Plasmodium falciparum-hookworm coinfection in different age groups in south-central Cote d'Ivoire.

    Directory of Open Access Journals (Sweden)

    Aurélie A Righetti

    Full Text Available BACKGROUND: Given the widespread distribution of Plasmodium and helminth infections, and similarities of ecological requirements for disease transmission, coinfection is a common phenomenon in sub-Saharan Africa and elsewhere in the tropics. Interactions of Plasmodium falciparum and soil-transmitted helminths, including immunological responses and clinical outcomes of the host, need further scientific inquiry. Understanding the complex interactions between these parasitic infections is of public health relevance considering that control measures targeting malaria and helminthiases are going to scale. METHODOLOGY: A cross-sectional survey was carried out in April 2010 in infants, young school-aged children, and young non-pregnant women in south-central Côte d'Ivoire. Stool, urine, and blood samples were collected and subjected to standardized, quality-controlled methods. Soil-transmitted helminth infections were identified and quantified in stool. Finger-prick blood samples were used to determine Plasmodium spp. infection, parasitemia, and hemoglobin concentrations. Iron, vitamin A, riboflavin, and inflammation status were measured in venous blood samples. PRINCIPAL FINDINGS: Multivariate regression analysis revealed specific association between infection and demographic, socioeconomic, host inflammatory and nutritional factors. Non-pregnant women infected with P. falciparum had significantly lower odds of hookworm infection, whilst a significant positive association was found between both parasitic infections in 6- to 8-year-old children. Coinfected children had lower odds of anemia and iron deficiency than their counterparts infected with P. falciparum alone. CONCLUSIONS/SIGNIFICANCE: Our findings suggest that interaction between P. falciparum and light-intensity hookworm infections vary with age and, in school-aged children, may benefit the host through preventing iron deficiency anemia. This observation warrants additional investigation to

  1. Rapid movement of frozen debris-lobes: implications for permafrost degradation and slope instability in the south-central Brooks Range, Alaska

    Science.gov (United States)

    Daanen, R.P.; Grosse, G.; Darrow, M.M.; Hamilton, T.D.; Jones, Benjamin M.

    2012-01-01

    We present the results of a reconnaissance investigation of unusual debris mass-movement features on permafrost slopes that pose a potential infrastructure hazard in the south-central Brooks Range, Alaska. For the purpose of this paper, we describe these features as frozen debris-lobes. We focus on the characterisation of frozen debris-lobes as indicators of various movement processes using ground-based surveys, remote sensing, field and laboratory measurements, and time-lapse observations of frozen debris-lobe systems along the Dalton Highway. Currently, some frozen debris-lobes exceed 100 m in width, 20 m in height and 1000 m in length. Our results indicate that frozen debris-lobes have responded to climate change by becoming increasingly active during the last decades, resulting in rapid downslope movement. Movement indicators observed in the field include toppling trees, slumps and scarps, detachment slides, striation marks on frozen sediment slabs, recently buried trees and other vegetation, mudflows, and large cracks in the lobe surface. The type and diversity of observed indicators suggest that the lobes likely consist of a frozen debris core, are subject to creep, and seasonally unfrozen surface sediment is transported in warm seasons by creep, slumping, viscous flow, blockfall and leaching of fines, and in cold seasons by creep and sliding of frozen sediment slabs. Ground-based measurements on one frozen debris-lobe over three years (2008–2010) revealed average movement rates of approximately 1 cm day−1, which is substantially larger than rates measured in historic aerial photography from the 1950s to 1980s. We discuss how climate change may further influence frozen debris-lobe dynamics, potentially accelerating their movement. We highlight the potential direct hazard that one of the studied frozen debris-lobes may pose in the coming years and decades to the nearby Trans Alaska Pipeline System and the Dalton Highway, the main artery for transportation

  2. Reconstruction of the late Holocene climate in the Minusink Hollow, south-central Siberia, and its potential influence on settled farming versus nomadic cattle herding

    Science.gov (United States)

    Tchebakova, N. M.; Blyakharchuk, T.; Parfenova, E. I.; Soja, A. J.

    2013-12-01

    Introduction. Prehistoric and early historic human cultures are known to be closely connected to and dependent on their natural environments. Gumilev (2000) developed a theory relating the rise, development and fall of human cultures (ethnos) to the changing environment. This theory improved our understanding of human history as the natural interactions the biosphere and sociosphere. We test the hypothesis that climate change altered the means of subsistence of ancient tribes and forced them to choose agricultural or cattle herding economic strategies. Our study area is the Khakass-Minusinsk Hollow located at the foothills of the Sayan Mountains, south-central Siberia, which was, for a few millennia, a buffer zone for human migrations across the Great Eurasian Steppe. Methods. Three different methods (the Montane Bioclimatic Model; the biomization method; and the actualizm method) were employed to reconstruct vegetation from the fossil pollen of sediment cores of two mountain lakes in the study area at eleven time slices relating to successive human cultures back to the midHolocene. Our bioclimatic model was used inversely to convert site paleovegetation into site paleoclimates. Climate-based regression models were developed and applied to reconstructed climates to evaluate possible pasture and grain crops for these time slices. Results. Our pollen-based reconstructions of the climate fluctuations uncovered several dry periods with steppe and forest-steppe lands dominating up to 85% of the area and four wetter periods with forests dominating up to 60% of the area since 6000 BP. Grasslands increased one order of magnitude during the dry periods and provided extensive open space likely suitable for pastoralism; however, both grain and pasture yields dropped during these dry periods. During wetter climates, both grain and pasture yields could increase twofold and support more fixed human settlements centered around farming and herding cattle. Thus, the dry periods

  3. Potential influence of the late Holocene climate on settled farming versus nomadic cattle herding in the Minusinsk Hollow, south-central Siberia

    Science.gov (United States)

    Blyakharchuk, T. A.; Tchebakova, N. M.; Parfenova, E. I.; Soja, A. J.

    2014-05-01

    Prehistoric and early historic human cultures are known to be closely connected to and dependent on their natural environments. We test the hypothesis that climate change influenced the means of subsistence of ancient tribes and favored agricultural or cattle herding economic strategies. Our study area is the Khakass-Minusinsk Hollow, located in the foothills of the Sayan Mountains, south-central Siberia, which was, for a few millennia, a buffer zone for human migrations across the Great Eurasian Steppe. Three different methods (the Montane BioClimatic Model, MontBCliM; the biomization method; and the actualizm method) are employed to reconstruct vegetation taken from the fossil pollen of sediment cores in two mountain lakes at eleven time slices related to successive human cultures back to the mid-Holocene. MontBCliM model is used inversely to convert site paleo-vegetation into site paleo-climates. Climate-based regression models are developed and applied to reconstructed climates to evaluate possible pasture and grain crops for these time slices. Pollen-based reconstructions of the climate fluctuations uncovered several dry periods with steppe and forest-steppe and wetter periods with forests since 6000 BP. Grasslands increased by an order of magnitude during the dry periods and provided extensive open space suitable for pastoralism; however, both grain and pasture yields decreased during these dry periods. During wetter climates, both grain and pasture yields increased twofold and supported more fixed human settlements centered around farming and cattle herding. Thus, the dry periods favored pastoralist rather than farming activities. Conversely, tribes that practiced agriculture had some advantage in the wet periods.

  4. A credibility-based chance-constrained optimization model for integrated agricultural and water resources management: A case study in South Central China

    Science.gov (United States)

    Lu, Hongwei; Du, Peng; Chen, Yizhong; He, Li

    2016-06-01

    This study presents a credibility-based chance-constrained optimization model for integrated agricultural irrigation and water resources management. The model not only deals with parameter uncertainty represented as fuzzy sets, but also provides a credibility level which indicates the confidence level of the generated optimal management strategies. The model is used on a real-world case study in South Central China. Results from the case study reveal that: (1) a reduction in credibility level would result in an increasing planting area of watermelon, but impaired the planting acreage of high-quality rice and silk; (2) groundwater allocation would be prioritized for reducing surface water utilization cost; (3) the actual phosphorus and nitrogen emissions reached their limit values in most of the zones over the planning horizon (i.e., phosphorus and nitrogen emissions reaching 969 tonnes and 3814 tonnes under λ = 1.00, respectively; phosphorus and nitrogen emissions reaching 972 tonnes and 3891 tonnes under λ = 0.70, respectively). When the credibility level reduces from 1.00 to 0.70, system benefit would rise by 32.60% and groundwater consumption would be reduced by 79.51%. However, the pollutant discharge would not increase as expected, which would be reduced by 40.14% on the contrary. If system benefit is not of major concern, an aggressive strategy is suggested by selecting a rather low credibility level (say, 0.70). This strategy is suggested for guaranteeing protection of local groundwater resources and mitigation of local environmental deterioration by sacrificing part of system benefit.

  5. Colour changes by laser irradiation of reddish building limestones

    Energy Technology Data Exchange (ETDEWEB)

    Grossi, C.M., E-mail: c.grossi-sampedro@uea.ac.uk [School of Health Sciences, University of East Anglia, Norwich NR4 7TJ (United Kingdom); Benavente, D. [Department of Earth and Environment Sciences, University of Alicante. 03690 Alicante (Spain)

    2016-10-30

    Highlights: • This is the first time that XPS is used to determine the cause of colour change in coloured stones when cleaned with laser at 1064 nm. • We demonstrate that the colour change in red limestones is due to a reduction in the state of oxidation of iron, in this case present as hematite. • XPS could be routinely used to analyse causes of colour changes during laser cleaning in other types of coloured building stones. - Abstract: We have used X-ray photoelectron spectroscopy (XPS) as a novel method to investigate the causes of colour changes in a reddish limestone under irradiation by a Q-switched Nd:YAG 1064 nm laser. We irradiated clean dry and wet surfaces of Pidramuelle Roja, a building stone frequently used in the Asturian heritage, at fluences ranging from 0.12 to 1.47 J cm{sup −2}. We measured the colour coordinates and undertook XPS analysis of the state of oxidation of iron both before and after irradiation. Visible colour changes and potential aesthetic damage occurred on dry surfaces from a fluence of 0.31 J cm{sup −2}, with the stone showing a greening effect and very intense darkening. The colour change on dry surfaces was considerably higher than on wet surfaces, which at the highest fluence (1.47 J cm{sup −2}) was also above the human visual detection threshold. The use of XPS demonstrated that the change in colour (chroma and hue) is associated with a reduction in the iron oxidation state on dry surfaces during laser irradiation. This points out to a potential routinary use of XPS to analyse causes of colour changes during laser cleaning in other types of coloured building stones.

  6. Geochemistry, environmental and provenance study of the Middle Miocene Leitha limestones (Central Paratethys

    Directory of Open Access Journals (Sweden)

    Ali Ahmed

    2017-06-01

    Full Text Available Mineralogical, major, minor, REE and trace element analyses of rock samples were performed on Middle Miocene limestones (Leitha limestones, Badenian collected from four localities from Austria (Mannersdorf, Wöllersdorf, Kummer and Rosenberg quarries and the Fertőrákos quarry in Hungary. Impure to pure limestones (i.e. limited by Al2O3 contents above or below 0.43 wt. % were tested to evaluate the applicability of various geochemical proxies and indices in regard to provenance and palaeoenvironmental interpretations. Pure and impure limestones from Mannersdorf and Wöllersdorf (southern Vienna Basin show signs of detrital input (REEs = 27.6 ± 9.8 ppm, Ce anomaly = 0.95 ± 0.1 and the presence of quartz, muscovite and clay minerals in impure limestones and diagenetic influence (low contents of, e.g., Sr = 221 ± 49 ppm, Na is not detected, Ba = 15.6 ± 8.8 ppm in pure limestones. Thus, in both limestones the reconstruction of original sedimentary palaeoenvironments by geochemistry is hampered. The Kummer and Fertőrákos (Eisenstadt–Sopron Basin comprise pure limestones (e.g., averages Sr = 571 ± 139 ppm, Na = 213 ± 56 ppm, Ba = 21 ± 4 ppm, REEs = 16 ± 3 ppm and Ce anomaly = 0.62 ± 0.05 and composed predominantly of calcite exhibiting negligible diagenesis. Deposition under a shallow-water, well oxygenated to intermittent dysoxic marine environment can be reconstructed. Pure to impure limestones at Rosenberg–Retznei (Styrian Basin are affected to some extent by detrital input and volcano-siliciclastic admixture. The Leitha limestones at Rosenberg have the least diagenetic influence among the studied localities (i.e. averages Sr = 1271 ± 261 ppm, Na = 315 ± 195 ppm, Ba = 32 ± 15 ppm, REEs = 9.8 ± 4.2 ppm and Ce anomaly = 0.77 ± 0.1 and consist of calcite, minor dolomite and quartz. The siliciclastic sources are characterized by immobile elemental ratios (i.e. La/Sc and Th/Co which apply not only for the siliciclastics, but also

  7. Selected wells and test holes used in structure-contour maps of the Inyan Kara Group, Minnekahta Limestone, Minnelusa Formation, Madison Limestone, and Deadwood Formation in the Black Hills Area, South Dakota

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This dataset describes wells and test holes completed in the Madison Limestone that were used to create the structure-contours for the top of the Madison Limestone,...

  8. Hydration of Blended Portland Cements Containing Calcium-Aluminosilicate Glass Powder and Limestone

    DEFF Research Database (Denmark)

    Moesgaard, Mette; Poulsen, S.L.; Herfort, D.

    2012-01-01

    in an accelerated hydration for alite (Ca3SiO5), the main constituent of Portland cement. A higher degree of limestone reaction has been observed in the blend containing both limestone and NCAS glass as compared to the limestone – Portland mixture. This reflects that limestone reacts with a part of the alumina......This work investigates the hydration of blended Portland cement containing 30 wt.% Na2O-CaO-Al2O3-SiO2 (NCAS) glass particles either as the only supplementary cementitious material (SCM) or in combination with limestone, using 29Si MAS NMR, powder XRD, and thermal analyses. The NCAS glass...... represents a potential alternative to traditional SCMs, used for reduction of the CO2 emission associated with cement production. It is found that the NCAS glass takes part in the hydration reactions after about two weeks of hydration and a degree of reaction of approx. 50 % is observed after 90 days...

  9. Properties of failure mode and thermal damage for limestone at high temperature

    Institute of Scientific and Technical Information of China (English)

    MAO Xian-biao; ZHANG Lian-ying; LI Tian-zhen; LIU Hai-shun

    2009-01-01

    The mechanical properties of limestone such as the stress-strain curve, the variable characteristics of peak strength and the modulus of elasticity of limestone were studied under the action of temperatures ranging from room temperature to 800℃. Our results show that: 1) the temperature has not clear effect on the mechanical properties of limestone from room temperature to 600 ℃. However, the mechanical properties of limestone deteriorate rapidly when the temperature is above 600 ℃. In this case, the peak stress and modulus of elasticity decrease rapidly. When the temperature reaches 800 ℃, the entire process, showing the stress-strain curve is displayed indicating an obvious state of plastic-deformation; 2) the failure mode of limestone shows the breakdown of tensile strength from room temperature to 600 ℃, as well as the compress shearing damage over 600 ℃; 3) combining our test results with the concept of thermal damage, a thermal damage equation was derived.

  10. Utilization of solar energy. Solar thermal heating systems; Die Waerme vom Himmel holen. Solarthermische Systeme

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2012-07-01

    Solar thermal power plants collect solar heat by means of collectors. Thus, solar thermal power plants support the heating and supply warm water for the showers. The implementation of solar thermal power plants is interesting especially for the exchange of the heating system as well as in the new house.

  11. Landing and Oviposition Responses of Rhagoletis indifferens (Dipt., Tephritidae) on Sweet Cherry Treated with Kaolin- and Limestone-Based Products

    Science.gov (United States)

    Kaolin- and limestone-based products were compared for their effects on landing and oviposition on sweet cherry by Rhagoletis indifferens Curran (Dipt., Tephritidae). Surround (95% calcined kaolin), Cocoon (100% hydrous kaolin), Eclipse (>97% limestone), and Purshade (62.5% limestone) were studied....

  12. 77 FR 60458 - Public Land Order No. 7803; Withdrawal of Public Lands for the Limestone Hills Training Area; MT

    Science.gov (United States)

    2012-10-03

    ... Bureau of Land Management Public Land Order No. 7803; Withdrawal of Public Lands for the Limestone Hills... laws, for a period of 5 years. This withdrawal will protect the Limestone Hills Training Area in... hours. SUPPLEMENTARY INFORMATION: The Limestone Hills Training Area withdrawal will maintain the...

  13. Modeling of Hydration, Compressive Strength, and Carbonation of Portland-Limestone Cement (PLC) Concrete.

    Science.gov (United States)

    Wang, Xiao-Yong

    2017-01-26

    Limestone is widely used in the construction industry to produce Portland limestone cement (PLC) concrete. Systematic evaluations of hydration kinetics, compressive strength development, and carbonation resistance are crucial for the rational use of limestone. This study presents a hydration-based model for evaluating the influences of limestone on the strength and carbonation of concrete. First, the hydration model analyzes the dilution effect and the nucleation effect of limestone during the hydration of cement. The degree of cement hydration is calculated by considering concrete mixing proportions, binder properties, and curing conditions. Second, by using the gel-space ratio, the compressive strength of PLC concrete is evaluated. The interactions among water-to-binder ratio, limestone replacement ratio, and strength development are highlighted. Third, the carbonate material contents and porosity are calculated from the hydration model and are used as input parameters for the carbonation model. By considering concrete microstructures and environmental conditions, the carbon dioxide diffusivity and carbonation depth of PLC concrete are evaluated. The proposed model has been determined to be valid for concrete with various water-to-binder ratios, limestone contents, and curing periods.

  14. Stratigraphy and sedimentology of the Upper Cretaceous (Campanian) Anacacho Limestone, Texas, USA

    Science.gov (United States)

    Swezey, C.S.; Sullivan, E.C.

    2004-01-01

    The Upper Cretaceous Anacacho Limestone is exposed in outcrops between the cities of San Antonio and Del Rio, Texas. A detailed study of four outcrops (Blanco Creek section, Sabinal River section, Seco Creek section, Hondo Creek section) shows that the Anacacho Limestone rests on the Upson Clay (which contains fauna of early Campanian age) and is overlain by the Corsicana Marl (which contains fauna of early Maastrichtian age). An unconformity within the Anacacho Limestone is used herein to separate the limestone into a lower member and an upper member. The lower Anacacho member contains fauna of early Campanian age, whereas the upper Anacacho member contains fauna of middle Campanian age. The lower Anacacho member consists predominantly of wackestones to packstones, which are overlain by packstones to grainstones capped by the unconformity. This unconformity is interpreted as a marine flooding surface, delineating a transition from carbonate grainstones deposited in shallow water (<30 m depth) to a chalk deposited in deeper water. Above the unconformity, the upper Anacacho member is characterized by a chalk, overlain by wackestones and packstones. The uppermost section of the Anacacho Limestone consists of packstones and grainstones with abundant and diverse fossils. Most of the Anacacho Limestone developed in relatively shallow water (<50 m depth) leeward of a large carbonate build-up (possibly a rudistid reef) that now comprises the Anacacho Mountains. The environment, however, was open to marine water throughout deposition of the Anacacho Limestone. ?? 2004 Elsevier Ltd. All rights reserved.

  15. Preliminary microfacies analysis and cyclicity of the Wahoo Limestone, Lisburne Field, North Slope, Alaska

    Energy Technology Data Exchange (ETDEWEB)

    Morgan, S.K.; Watts, K.F.

    1995-05-01

    A well from the Lisburne field near Prudhoe Bay was examined in core, thin section, and on well logs for comparison with Wahoo Limestone in the Arctic National Wildlife Refuge (ANWR). Carbonate cycles (parasequences) are well developed in both areas but the greater abundance of terrigenous sediment and associated carbonate facies indicate that the study well is located in a more landward position on the Wahoo carbonate ramp, closer to a source of terrigenous sediment. This report presents the preliminary results of microfacies analyses that have been conducted on 424 of a total 1,115 thin sections from the study well. The stratigraphic nomenclature extended from ANWR (the type locality of the Wahoo Limestone) is different that the terminology previously used for the subsurface Lisburne Group near Prudhoe Bay. We distinguish informal lower and upper members within the Mississippian to Pennsylvanian Wahoo Limestone which overlies the Mississippian Alapah Limestone. Our upper Alapah corresponds to the middle Alapah of previous workers. Our lower Wahoo Limestone member corresponds to the upper Alapah of previous workers. Our upper Wahoo Limestone member corresponds to the previous Wahoo Limestone and is the major hydrocarbon reservoir at the Lisburne field, which is characterized by well-developed carbonate cycles (parasequences).

  16. Modeling of Hydration, Compressive Strength, and Carbonation of Portland-Limestone Cement (PLC Concrete

    Directory of Open Access Journals (Sweden)

    Xiao-Yong Wang

    2017-01-01

    Full Text Available Limestone is widely used in the construction industry to produce Portland limestone cement (PLC concrete. Systematic evaluations of hydration kinetics, compressive strength development, and carbonation resistance are crucial for the rational use of limestone. This study presents a hydration-based model for evaluating the influences of limestone on the strength and carbonation of concrete. First, the hydration model analyzes the dilution effect and the nucleation effect of limestone during the hydration of cement. The degree of cement hydration is calculated by considering concrete mixing proportions, binder properties, and curing conditions. Second, by using the gel–space ratio, the compressive strength of PLC concrete is evaluated. The interactions among water-to-binder ratio, limestone replacement ratio, and strength development are highlighted. Third, the carbonate material contents and porosity are calculated from the hydration model and are used as input parameters for the carbonation model. By considering concrete microstructures and environmental conditions, the carbon dioxide diffusivity and carbonation depth of PLC concrete are evaluated. The proposed model has been determined to be valid for concrete with various water-to-binder ratios, limestone contents, and curing periods.

  17. The influence of temperature on failure modes for Solnhofen limestone

    Science.gov (United States)

    Zhu, W.; Xiao, X.; Evans, B.

    2003-04-01

    The initiation and growth of shear localization is of fundamental importance in understanding the mechanics of earthquake and faulting. Because dilatancy is generally observed as a precursor to brittle faulting, early laboratory and theoretical studies tended to focus on dilatant materials. However, recent laboratory studies demonstrated that investigating the complex interplay between dilatancy and compaction is crucial in understanding this brittle failure phenomenon in many porous rocks. In this study, we deformed Solnhofen limestone with initial porosity of 4.5% at temperatures of 473, 523, 573 and 673 K, at confining pressures (argon) of 70 to 300 MPa, and a constant pore pressure (distilled water or argon) of 50 MPa. In situ measurements of dilatancy, permeability and storage capacity were performed with Argon gas as pore fluid. To elucidate the mechanisms that control the failure modes in Solnhofen limestone, both SEM and TEM studies are conducted on the deformed samples. Our experimental results indicate that the deformation mechanisms and failure modes are sensitive to both pressure and temperature conditions. At low pressures and temperatures, significant amount of strain softening and an abrupt stress drop were observed during localization. However, at higher pressure and temperature, the localization process became rather progressive, with strain softening and dilatancy accumulating over large amount of axial strain. Our experimental results also demonstrate that shear-enhanced compaction can evolve to dilatant cataclasis at elevated temperature, which is consistent with previous low temperature experimental data (Baud et al., 2000). This implies that stress-induced compaction and dilation should not be viewed as mutually exclusive processes. Testing existing theoretical models using well-constraint laboratory studies is the critical first step towards a better understanding of the physics of deformation processes. Following the localization model

  18. ARD remediation with limestone in a CO2 pressurized reactor

    Science.gov (United States)

    Sibrell, Philip L.; Watten, Barnaby J.; Friedrich, Andrew E.; Vinci, Brian J.

    2000-01-01

    We evaluated a new process for remediation of acid rock drainage (ARD). The process treats ARD with intermittently fluidized beds of granular limestone maintained within a continuous flow reactor pressurized with CO2. Tests were performed over a thirty day period at the Toby Creek mine drainage treatment plant, Elk County, Pennsylvania in cooperation with the Pennsylvania Department of Environmental Protection. Equipment performance was established at operating pressures of 0, 34, 82, and 117 kPa using an ARD flow of 227 L/min. The ARD had the following characteristics: pH, 3.1; temperature, 10 °C; dissolved oxygen, 6.4 mg/L; acidity, 260 mg/L; total iron, 21 mg/L; aluminum, 22 mg/L; manganese, 7.5 mg/L; and conductivity, 1400 μS/cm. In all cases tested, processed ARD was net alkaline with mean pH and alkalinities of 6.7 and 59 mg/L at a CO2 pressure of 0 kPa, 6.6 and 158 mg/L at 34 kPa, 7.4 and 240 mg/L at 82 kPa, and 7.4 and 290 mg/L at 117 kPa. Processed ARD alkalinities were correlated to the settled bed depth (pIron, aluminum, and manganese removal efficiencies of 96%, 99%, and 5%, respectively, were achieved with filtration following treatment. No indications of metal hydroxide precipitation or armoring of the limestone were observed. The surplus alkalinity established at 82 kPa was successful in treating an equivalent of 1136 L/min (five-fold dilution) of the combined three ARD streams entering the Toby Creek Plant. This side-stream capability provides savings in treatment unit scale as well as flexibility in treatment effect. The capability of the system to handle higher influent acidity was tested by elevating the acidity to 5000 mg/L with sulfuric acid. Net alkaline effluent was produced, indicating applicability of the process to highly acidic ARD.

  19. Rehabilitation of lands mined for limestone in the Indian desert

    Science.gov (United States)

    Sharma, K.D.; Kumar, S.; Gough, L.P.

    2000-01-01

    In the Indian desert, the economics of mining is second only to agriculture in importance. However, research on the rehabilitation of land disturbed by mining has only recently received serious attention. An attempt has been made to determine both the qualitative and quantitative success of rehabilitation plans used to revegetate limestone mine spoils in an area near Barna, northwest arid India. Rehabilitation success was achieved using a combination of rainwater harvesting techniques, soil amendment application approaches, plant establishment methods and the selection of appropriate germplasm material (trees, shrubs and grasses). It is expected that the resulting vegetative cover will be capable of self-perpetuation under natural conditions while at the same time meeting the land-use needs of the local people. The minespoils have adequate levels of the major nutrients (except P, Mo and Se) for proper plant and grazing animal health. Levels of organic matter are low whereas total B concentrations are exceptionally high. Also, the population of soil fungi, Azotobactor, and nitrifying bacteria is negligible. Enhanced plant growth was achieved in treated plots, compared to control plots, where spoil moisture storage was improved by 5-45 per cent. Due to the decomposition of farmyard manure and nitrogen fixation by planted leguminous plant species, the electrical conductance of treated mine spoils increased threefold, CaCO3 content decreased from 20??0 to 5??2 per cent, and organic carbon, P, K, and biological activity increased significantly. The rehabilitation protocol used at the site appears to have been successful because plant self-regeneration is occurring. The increased diversity of woody perennials resulted in 'dominance' being better shared among species and 'evenness' being increased within the plant community elements. The early to mid-successional trends are continuing for six years following initial rehabilitation. This study developed methods for the

  20. Possible Evidence for Enhanced Seasonality During the Little Ice Age Indicated by Multiple Isotopes from Kepler Lake, South-Central Alaska

    Science.gov (United States)

    Gonyo, A.; Yu, Z.; Bebout, G.

    2008-12-01

    We present multiple-proxy data from two short cores (85 cm and 101 cm) from Kepler Lake, an evaporation- insensitive, groundwater-fed marl lake in South-Central Alaska to reconstruct climate and environmental changes in the recent centuries. The proxies used include calcite C and O isotopes, organic matter (OM) C and N isotopes, and loss on ignition (LOI) analysis. Two cores can be visually correlated based upon LOI results. A 600 year chronology was established based on 3 calibrated AMS 14C dates of terrestrial macrofossils and 210Pb analysis. δ18OVPDB values of inorganic calcite range from - 17.0‰ to -15.7‰, with the highest values between 1470 and 1840 AD during the Little Ice Age (LIA). The relatively high δ18O values during the cold LIA contrast with the conventional temperature interpretation of O isotopes. Therefore, the isotopic shifts around the LIA were likely caused by a shift in atmospheric circulation. A weakening of the wintertime Aleutian Low pressure system residing over the Gulf of Alaska would result in enriched 18O in precipitation as well as a colder winter climate in SC Alaska. During the LIA period CaCO3 contents were elevated by ~15% to >80%. Calcite precipitation in freshwater lakes is primarily a function of summer temperature; we propose that the LIA in SC Alaska represents a period of colder winters and warmer summers. This interpretation is also supported by C isotopes, reflecting aquatic productivity. Both δ13C OM and δ13Ccalcite (relative to VPDB) exhibit relatively high values at 1600 to 1840 AD, after which δ13COM remains constant throughout the rest of the record and δ13Ccalcite declines after the LIA. The delayed increase in δ13C of OM and calcites at 1600 AD may reflect the differential responses of calcite precipitation and aquatic productivity. The negative shift of ~1‰ in δ18O in the 1840s has also been documented in ice cores from Mt. Logan and in marl lake sediments from the southern Yukon, suggesting a broad

  1. Chemical and isotopic variations in the Wiśniówka Mała mine pit water, Holy Cross Mountains (south-central Poland)

    Science.gov (United States)

    Migaszewski, Zdzisław M.; Gałuszka, Agnieszka; Hałas, Stanisław; Dąbek, Józef; Dołęgowska, Sabina; Budzyk, Irena; Starnawska, Ewa; Michalik, Artur

    2009-03-01

    In 2005 and 2006, hydrogeochemical study was carried out in the bipartite Wiśniówka Mała pit lake of the Holy Cross Mountains (south-central Poland). This is the largest acidic water body in Poland. This report presents the element concentrations in the water and sediment, stable sulfur and oxygen isotope ratios in the soluble sulfates, and stable oxygen isotope ratio in the water. The scope of the investigation also encompassed mineralogical examinations (scanning electron microscope, X-ray diffraction) of the sediment. The results of this study show that there is a spatial and temporal variability in concentrations of most elements and sulfur isotope ratios in the examined pit lake. The water of the western pond displayed a lower pH with a mean of 3.73 and higher conductivity (390 μS cm-1) as well as higher concentrations of sulfates (156 mg L-1) and most of the cations and anions. The concentrations of Fe2+ and Fe3+ averaged 0.8 and 0.4 mg·L-1. In contrast, the eastern pond water revealed a higher pH (mean of 4.36), lower conductivity (293 μS cm-1) and lower sulfate (90 mg L-1) and trace metal levels. Similar variations were recorded in the stable sulfur isotope ratios. The δ34SV-CDT(SO4 2-) values in the water of the western pit pond were in the range of -6.7 to -4.6‰ (mean of -5.6‰), whereas that in the eastern pit pond ranged from -2.2 to -0.9‰ (-1.6‰). The alkalinity of the entire lake water was below 0.1 mg·L-1 CaCO3. No distinct difference in the δ18OV-SMOW(SO4 2-) was noted between the western and eastern pit ponds. Compared to the Purple Pond in the Sudetes (Poland) and similar sites throughout the world, the examined pit lake is highlighted by distinctly low concentrations of sulfates, iron and other trace metals. Based on this and other studies performed in the Holy Cross Mountains, a conclusion can be drawn that the SO4 2- in the Wiśniówka Mała pit lake water is a mixture of SO4 2- derived from the following sources: (1) pyrite

  2. Farm-level risk factors for the occurrence, new infection or persistence of tuberculosis in cattle herds from South-Central Spain.

    Science.gov (United States)

    Martínez-López, B; Barasona, J A; Gortázar, C; Rodríguez-Prieto, V; Sánchez-Vizcaíno, J M; Vicente, J

    2014-10-01

    Eradication of tuberculosis (TB) in cattle is a priority in the EU. However, and despite the resources invested, TB eradication is still a goal yet to be accomplished. As a consequence, the identification of risk factors contributing to TB transmission and persistence is key to a better understand and, ultimately, more cost-effectively control and eradicate this complex zoonotic disease worldwide. This study aimed to identify the factors contributing to the TB occurrence, new infection, and persistence in one of the most TB-prevalent regions in the South-Central part of Spain (SCS), Ciudad Real (CR), and for which high quality and detailed information on cattle and wild ungulate demographics, management, and sanitary status was available for up to 5 years (2007-2011). Multilevel logistic modeling was used for this purpose. Results of this study revealed that the risk for TB (occurrence, new infection, and/or persistence) in cattle herds from CR is related to TB-persistence on farm in previous years, extensive production systems (beef and bullfighting being more risky that dairy) and large farm in terms of cattle number. Also, the presence and proximity of fenced hunting estates (which are usually intensively managed) significantly contributed to the risk of TB occurrence and persistence in CR. This association suggests that wild ungulates may play a role as TB-reservoirs and transmit TB to cattle in the CR, a region where TB is endemic and is associated with extensive farming of beef cattle. To the best of author's knowledge this is the first study to (i) evaluate the wild ungulate-domestic interface at a farm level using detailed information over an extensive region and period of time (2007-2011) and (ii) to identify a direct association between TB in cattle and the proximity and management practices of wild ungulates. Methods and results presented here may support policies to better prevent and control TB in the SCS and in other regions/countries with similar

  3. Time variations of gaseous and reactive mercury in the industrial area of Puertollano (south-central Spain). Temporal cycles with marked variations

    Science.gov (United States)

    Martínez-Coronado, Alba; Esbrí, Jose Maria; Higueras, Pablo

    2016-06-01

    Puertollano (48,086 inhabitants) is the largest industrial city in the Castilla-La Mancha region (South-Central Spain). The city is located some 250 km South of Madrid; it was an important coal mining site during the last century and today it is the location of one of the most important Spanish oil refineries and the only refinery located away from the coast. Nowadays the area (which mainly includes the Ojailen valley) has a large open pit coal mine (Encasur), two power plants (Eon and Elcogas) and a petrochemical complex (Repsol) located S and SE from the town. These industries give rise to a complex scenario in terms of mercury emissions to the atmosphere: Repsol, Elcogas and Eon act as discrete sources, while coal mine and dumps acts as a general, diffuse source. The mercury contents in Puertollano town and the related industrial area were characterized during 2010 and 2011 by acquiring stationary data of Gaseous Elemental Mercury (GEM), Reactive Gaseous Mercury (RGM), meteorological parameters and other atmospheric contaminants (NO, NO2, SO2, benzene, toluene, xylene, ozone and PM10). In addition, several Total Gaseous Mercury (TGM) mobile surveys were carried out covering the Ojailen valley. Total Gaseous Mercury (TGM) in the whole valley was in the range 0-24 ng m-3 in all surveys, while higher levels were found near to the coal mine and in the vicinity of a coal power plant that employs clean technology (Elcogas). Tekran data showed low GEM levels during 2010-2011 (1.81 ng m-3 on average), while lower GEM levels were measured during autumn and summer, and maximum levels in spring (7.32 ng m-3 on average). RGM measurements were 0.0088 ng m-3, i.e., significantly lower than background levels in the USA and Europe (0.04 ng m-3). Concentrations of these mercury species' were higher during summer (0.0117 ng m-3). Multiple regression analysis was carried out and good relationships between GEM levels, meteorological parameters and other pollutants were identified

  4. Occurrence of dissolved solids, nutrients, atrazine, and fecal coliform bacteria during low flow in the Cheney Reservoir watershed, south-central Kansas, 1996

    Science.gov (United States)

    Christensen, V.G.; Pope, L.M.

    1997-01-01

    A network of 34 stream sampling sites was established in the 1,005-square-mile Cheney Reservoir watershed, south-central Kansas, to evaluate spatial variability in concentrations of selected water-quality constituents during low flow. Land use in the Cheney Reservoir watershed is almost entirely agricultural, consisting of pasture and cropland. Cheney Reservoir provides 40 to 60 percent of the water needs for the city of Wichita, Kansas. Sampling sites were selected to determine the relative contribution of point and nonpoint sources of water-quality constituents to streams in the watershed and to identify areas of potential water-quality concern. Water-quality constituents of interest included dissolved solids and major ions, nitrogen and phosphorus nutrients, atrazine, and fecal coliform bacteria. Water from the 34 sampling sites was sampled once in June and once in September 1996 during Phase I of a two-phase study to evaluate water-quality constituent concentrations and loading characteristics in selected subbasins within the watershed and into and out of Cheney Reservoir. Information summarized in this report pertains to Phase I and was used in the selection of six long-term monitoring sites for Phase II of the study. The average low-flow constituent concentrations in water collected during Phase I from all sampling sites was 671 milligrams per liter for dissolved solids, 0.09 milligram per liter for dissolved ammonia as nitrogen, 0.85 milligram per liter for dissolved nitrite plus nitrate as nitrogen, 0.19 milligram per liter for total phosphorus, 0.20 microgram per liter for dissolved atrazine, and 543 colonies per 100 milliliters of water for fecal coliform bacteria. Generally, these constituents were of nonpoint-source origin and, with the exception of dissolved solids, probably were related to agricultural activities. Dissolved solids probably occur naturally as the result of the dissolution of rocks and ancient marine sediments containing large salt

  5. THE LOWER EOCENE RODA SANDSTONE (SOUTH-CENTRAL PYRENEES:AN EXAMPLE OF A FLOOD-DOMINATED RIVER-DELTA SYSTEMIN A TECTONICALLY CONTROLLED BASIN

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    ROBERTO TINTERRI

    2007-07-01

    Full Text Available The lower Eocene Roda Sandstone (Figols Group, south-central Pyrenees mainly consists of mouth bars and delta-front sandstone lobes deposited in a flood-dominated river-delta system. The deposition of these bodies was strongly controlled by an interaction between flood-dominated gravity flows entering seawater, topographic confinement and tidal currents. The Roda Sandstone is made up of six depositional sequences of different hierarchical order each of which is characterized by a basal deltaic sandstone wedge (R1 to R6 that passes upward into a siltstone and mudstone interval. Each basal deltaic sandstone wedge is composed of three types of facies association and respective facies tract (sensu Mutti 1992 that, from proximal to distal zones, are indicated as T1, T2 and T3. These three facies tracts are created by the downcurrent evolution of different types of sediment-laden stream flows entering seawater and related hyperpycnal flows. Their deposits are constituted by three different types of coarse-grained mouth bars and corresponding fine-grained delta-front sandstone lobes. The tidal influence is present in facies tract T3 in the R5 and R6 sandstone units, where the passage between flood-dominated mouth bars and the delta-front sandstone lobes occurs through intermediate facies characterized by different types of sigmoidal-cross stratification whose meaning will be discussed. The basal deltaic sandstone wedges of Roda sandstone are characterized by a progressive forestepping culminating in the R6 unit that erodes the underlying R5 unit and by an overlying backstepping unit indicated as R7. The erosive surface at the base of R6 unit is interpreted as a sequence boundary that divides the Roda Sandstone into two parts: 1 an underlying highstand system tract (HST and falling stage system tract (FSST (units R1 to R5 and 2 an overlying low-stand delta (the R6 unit that passes upward into highstand mudstone through a transgressive system tract

  6. The impact of acid deposition and forest harvesting on lakes and their forested catchments in south central Ontario: a critical loads approach

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    S. A. Watmough

    2002-01-01

    Full Text Available The impact of acid deposition and tree harvesting on three lakes and their representative sub-catchments in the Muskoka-Haliburton region of south-central Ontario was assessed using a critical loads approach. As nitrogen dynamics in forest soils are complex and poorly understood, for simplicity and to allow comparison among lakes and their catchments, CLs (A for both lakes and forest soils were calculated assuming that nitrate leaching from catchments will not change over time (i.e. a best case scenario. In addition, because soils in the region are shallow, base cation weathering rates for the representative sub-catchments were calculated for the entire soil profile and these estimates were also used to calculate critical loads for the lakes. These results were compared with critical loads obtained by the Steady State Water Chemistry (SSWC model. Using the SSWC model, critical loads for lakes were between 7 and 19 meq m-2yr-1 higher than those obtained from soil measurements. Lakes and forests are much more sensitive to acid deposition if forests are harvested, but two acid-sensitive lakes had much lower critical loads than their respective forested sub-catchments implying that acceptable acid deposition levels should be dictated by the most acid-sensitive lakes in the region. Under conditions that assume harvesting, the CL (A is exceeded at two of the three lakes and five of the six sub-catchments assessed in this study. However, sulphate export from catchments greatly exceeds input in bulk deposition and, to prevent lakes from falling below the critical chemical limit, sulphate inputs to lakes must be reduced by between 37% and 92% if forests are harvested. Similarly, sulphate leaching from forested catchments that are harvested must be reduced by between 16 and 79% to prevent the ANC of water draining the rooting zone from falling below 0 μeq l-1. These calculations assume that extremely low calcium leaching losses (9–27 μeq l-1 from

  7. Kittlitz's and Marbled Murrelets in Kenai Fjords National Park, South-Central Alaska: At-Sea Distribution, Abundance, and Foraging Habitat, 2006-08

    Science.gov (United States)

    Arimitsu, M.L.; Piatt, J.F.; Romano, Marc D.; Madison, E.N.; Conaway, J.S.

    2010-01-01

    Kittlitz's murrelets (Brachyramphus brevirostris) and marbled murrelets (B. marmoratus) are small diving seabirds and are of management concern because of population declines in coastal Alaska. In 2006-08, we conducted a study in Kenai Fjords National Park, south-central Alaska, to estimate the recent population size of Brachyramphus murrelets, to evaluate productivity based on juvenile to adult ratios during the fledgling season, and to describe and compare their use of marine habitat. We also attempted a telemetry study to examine Kittlitz's murrelet nesting habitat requirements and at-sea movements. We estimated that the Kittlitz's murrelet population was 671 ? 144 birds, and the marbled murrelet population was 5,855 ? 1,163 birds. Kittlitz's murrelets were limited to the heads of three fjords with tidewater glaciers, whereas marbled murrelets were more widely distributed. Population estimates for both species were lower in 2007 than in 2006 and 2008, possibly because of anomalous oceanographic conditions that may have delayed breeding phenology. During late season surveys, we observed few hatch-year marbled murrelets and only a single hatch-year Kittlitz's murrelet over the course of the study. Using radio telemetry, we found a likely Kittlitz's murrelet breeding site on a mountainside bordering one of the fjords. We never observed radio-tagged Kittlitz's murrelets greater than 10 kilometer from their capture sites, suggesting that their foraging range during breeding is narrow. We observed differences in oceanography between fjords, reflecting differences in sill characteristics and orientation relative to oceanic influence. Acoustic biomass, a proxy for zooplankton and small schooling fish, generally decreased with distance from glaciers in Northwestern Lagoon, but was more variable in Aialik Bay where dense forage fish schools moved into glacial areas late in the summer. Pacific herring (Clupea pallasii), capelin (Mallotus villosus) and Pacific sand lance

  8. Soil-Transmitted Helminths and Associated Factors among Pre-School Children in Butajira Town, South-Central Ethiopia: A Community-Based Cross-Sectional Study.

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    Teha Shumbej

    Full Text Available Soil-transmitted helminths (STH remain a major public health problem, particularly in tropical and sub-tropical regions of the world. Though infections are prevalent among all age groups, the world health organization (WHO considers Pre-school age children (PSAC, school-aged children, and pregnant women as segments of population at high risk of STH morbidities.This study aimed at determining the prevalence and infection intensity of STH and associated factors among PSAC in Butajira Town, south-central Ethiopia.A community-based cross-sectional study was conducted from May to June, 2014 in Butajira Town. The PSAC were selected by systematic sampling technique and invited to participate in the present study. McMaster technique was employed for parasitological analysis of stool samples. Pearson's Chi-square and Fisher's exact tests were performed where appropriate to identify any association between STH infection and independent factors. Multivariate logistic regression model was fitted to identify independent predictors of STH among the PSAC. P-value less than 0.05 was considered statistically significant.A total of 377 (with 96% compliance rate PSAC were able to provide complete data (socio-demographic information and stool sample. The study showed that 23.3% (88/377 PSAC were infected with one or more species of STH. Ascaris lumbricoides was the most prevalent STH (14.9% followed by Trichuris trichiura (6.4%. The overall infection intensity, expressed as geometric mean for A. lumbricoides, T. trichiura, and hookworms were 229, 178, and 154 eggs per gram of stool, respectively. The multivariate logistic regression model estimated that being in the age group of 36-47 months (AOR: 2.5, 95% CI: 1.2-5.3, P = 0.016, untrimmed finger nail (AOR: 3.2, 95% CI: 1.8-5.5, P < 0.001, and not washing hands before a meal (AOR: 3.0, 95% CI: 1.7-5.4, P < 0.001 were independent predictors of STH infections among the children.The present study showed that STH was a

  9. Middle Jurassic Topawa group, Baboquivari Mountains, south-central Arizona: Volcanic and sedimentary record of deep basins within the Jurassic magmatic arc

    Science.gov (United States)

    Haxel, G.B.; Wright, J.E.; Riggs, N.R.; Tosdal, R.M.; May, D.J.

    2005-01-01

    Among supracrustal sequences of the Jurassic magmatic arc of the southwestern Cordillera, the Middle Jurassic Topawa Group, Baboquivari Mountains, south-central Arizona, is remarkable for its lithologic diversity and substantial stratigraphic thickness, ???8 km. The Topawa Group comprises four units (in order of decreasing age): (1) Ali Molina Formation-largely pyroclastic rhyolite with interlayered eolian and fluvial arenite, and overlying conglomerate and sandstone; (2) Pitoikam Formation-conglomerate, sedimentary breccia, and sandstone overlain by interbedded silt- stone and sandstone; (3) Mulberry Wash Formation-rhyolite lava flows, flow breccias, and mass-flow breccias, with intercalated intraformational conglomerate, sedimentary breccia, and sandstone, plus sparse within-plate alkali basalt and comendite in the upper part; and (4) Tinaja Spring Porphyry-intrusive rhyolite. The Mulberry Wash alkali basalt and comendite are genetically unrelated to the dominant calcalkaline rhyolite. U-Pb isotopic analyses of zircon from volcanic and intrusive rocks indicate the Topawa Group, despite its considerable thickness, represents only several million years of Middle Jurassic time, between approximately 170 and 165 Ma. Sedimentary rocks of the Topawa Group record mixing of detritus from a minimum of three sources: a dominant local source of porphyritic silicic volcanic and subvolcanic rocks, identical or similar to those of the Topawa Group itself; Meso- proterozoic or Cambrian conglomerates in central or southeast Arizona, which contributed well-rounded, highly durable, polycyclic quartzite pebbles; and eolian sand fields, related to Middle Jurassic ergs that lay to the north of the magmatic arc and are now preserved on the Colorado Plateau. As the Topawa Group evidently represents only a relatively short interval of time, it does not record long-term evolution of the Jurassic magmatic arc, but rather represents a Middle Jurassic "stratigraphic snapshot" of the arc

  10. STUDIES ON PHYSICAL PROPERTIES OF BUKIT KAMANGS’ LIMESTONE AS MINERAL SOURCE FOR LAYING HENS

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    Khalil

    2011-09-01

    Full Text Available Samples of limestone composites were measured for hardness in 5 difference colors: black, dark blue, blue, light blue and white. Limestone was then ground and particle sizes of meal were measured. The meal were mixed with other locally available materials to produce 5 difference mineral formulas: P1: 100% limestone meal, P2: 50% limestone meal + 50% fresh water oyster shell meal, P3: 35% limestone meal + 30% fresh water oyster shell meal + 35% bone meal, P4: 35% limestone meal + 30% fresh water oyster shell meal + 34.2% bone meal + 0.5% salt + 0.3% micro minerals and P5: 100% fresh water oyster shell meal. The formulas were stored for 12 weeks. Samples were taken weekly for analyzing of moisture content and physical properties. By a feeding trial the five mineral formulas were mixed in the level of 6 % into basal diet and fed to 150 laying hens for 24 weeks. Parameters measured included body weight, feed intake, egg production and FCR. Results showed that the composites of Bukit Kamangs’ limestone had difference hardness. The strongest was found by the black composite of 23.4 HRc-C or 245.0 BHN. The meal products contained large particles (>0.42 mm of 17.8%. Moisture content of mineral formulas increased during storage, but their physical properties were no significant changes. The highest moisture increase was found by the product of 100% limestone, but it could be reduced by mixing with oyster shell meal and bone meal. The best laying performances (P<0.05 were found by the hens fed with diet supplemented with mineral formula containing limestone, fresh water oyster shell and fortified with micro minerals.

  11. Diversity and biogeography of land snails (Mollusca, Gastropoda) in the limestone hills of Perak, Peninsular Malaysia.

    Science.gov (United States)

    Foon, Junn Kitt; Clements, Gopalasamy Reuben; Liew, Thor-Seng

    2017-01-01

    Limestone hills are now gaining global conservation attention as hotspots for short-range endemic species. Levels of land snail endemism can be high at limestone hills, especially at hill clusters that are geographically isolated. In the State of Perak, Peninsular Malaysia, limestone hills have been opportunistically surveyed for land snails in the past, but the majority have yet to be surveyed. To address this knowledge gap, we systematically surveyed the terrestrial malacofauna of 12 limestone hills that, based on our opinion, are a representation of the limestone land snail assemblages within the State. Our inventory yielded high sampling completeness (>85%). We found 122 species of land snails, of which 34 species were unique to one of the surveyed hills. We identified 30 species that are potentially new to science. The number of land snail species recorded at each hill ranged between 39 and 63 species. Four of the sampled limestone hills namely, Prk 01 G. Tempurung, Prk 55 G. Pondok, Prk 47 Kanthan, and Prk 64 Bt Kepala Gajah, have high levels of species richness and unique species, representing 91% of the total species recorded in this study. We identified two clusters of limestone hills in central Perak with distinct differences in land snail species composition - a northern hill cluster on elevated granite bedrock and southern hill cluster in a low-lying valley surrounded by alluvial soils. As limestone hills continue to be quarried to meet the cement demand, the four identified limestone hills, along with other hills from the two clusters, warrant urgent conservation attention in order to maintain high species diversity within Perak's terrestrial malacofauna.

  12. STUDIES ON PHYSICAL PROPERTIES OF BUKIT KAMANGS’ LIMESTONE AS MINERAL SOURCE FOR LAYING HENS

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    K. Khalil

    2014-10-01

    Full Text Available Samples of limestone composites were measured for hardness in 5 difference colors: black, darkblue, blue, light blue and white. Limestone was then ground and particle sizes of meal were measured.The meal were mixed with other locally available materials to produce 5 difference mineral formulas:P1: 100% limestone meal, P2: 50% limestone meal + 50% fresh water oyster shell meal, P3: 35%limestone meal + 30% fresh water oyster shell meal + 35% bone meal, P4: 35% limestone meal + 30%fresh water oyster shell meal + 34.2% bone meal + 0.5% salt + 0.3% micro minerals and P5: 100% freshwater oyster shell meal. The formulas were stored for 12 weeks. Samples were taken weekly foranalyzing of moisture content and physical properties. By a feeding trial the five mineral formulas weremixed in the level of 6 % into basal diet and fed to 150 laying hens for 24 weeks. Parameters measuredincluded body weight, feed intake, egg production and FCR. Results showed that the composites ofBukit Kamangs’ limestone had difference hardness. The strongest was found by the black composite of23.4 HRc-C or 245.0 BHN. The meal products contained large particles (>0.42 mm of 17.8%. Moisturecontent of mineral formulas increased during storage, but their physical properties were no significantchanges. The highest moisture increase was found by the product of 100% limestone, but it could bereduced by mixing with oyster shell meal and bone meal. The best laying performances (P<0.05 werefound by the hens fed with diet supplemented with mineral formula containing limestone, fresh wateroyster shell and fortified with micro minerals.

  13. CARBONIFEROUS CORALS AND CHAETETIDS FROM EXOTIC LIMESTONE BLOCK OF THE CRIMEA

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    VICTOR OGAR

    2015-11-01

    Full Text Available A chaetetid sponge and coral fauna from a Carboniferous exotic limestone block in the Lower Jurassic Esciorda olistostrome on the Bodrak River (Crimean Mountains are described for the first time. The Bodrak exotic block is composed of massive limestone. It contains the chaetetid Chaetetes (Boswellia sp., the tabulate coral Multithecopora sp., and poorly preserved rugose corals, including Dibunophyllum? sp., Cordibia? sp. and gen. et sp. indet. Only the fasciculate colonies of the rugose coral Lytvophyllum askynensis (Kossovaya, 2009 are confidently identified. The studied association of fossils is similar to that of the Donets Basin and the Urals and confirms the Lower Bashkirian age of the Bodrak limestone block. 

  14. Capture of SO2 by limestone in a 71 MWe pressurized fluidized bed boiler

    Directory of Open Access Journals (Sweden)

    Shimizu Tadaaki

    2003-01-01

    Full Text Available A 71 MWe pressurized fluidized bed coal combustor was operated. A wide variety of coals were burnt under fly ash recycle conditions. Limestone was fed to the combustor as bed material as well as sorbent. The emission of SO^ and limestone attrition rate were measured. A simple mathematical model of SO? capture by limestone with intermittent solid attrition was applied to the analysis of the present experimental results. Except for high sulfur fuel, the results of the present model agreed with the experimental results.

  15. Radon in the Creswell Crags Permian limestone caves

    Energy Technology Data Exchange (ETDEWEB)

    Gillmore, G.K. E-mail: g.k.gillmore@bradford.ac.uk; Phillips, P.S.; Denman, A.R.; Gilbertson, D.D

    2002-07-01

    An investigation of radon levels in the caves of Creswell Crags, Derbyshire, an important Site of Special Scientific Interest (SSSI) shows that the Lower Magnesian Limestone (Permian) caves have moderate to raised radon gas levels (27-7800 Bq m{sup -3}) which generally increase with increasing distance into the caves from the entrance regions. This feature is partly explained in terms of cave ventilation and topography. While these levels are generally below the Action Level in the workplace (400 Bq m{sup -3} in the UK), they are above the Action Level for domestic properties (200 Bq m{sup -3}). Creswell Crags has approximately 40,000 visitors per year and therefore a quantification of effective dose is important for both visitors and guides to the Robin Hood show cave. Due to short exposure times the dose received by visitors is low (0.0016 mSv/visit) and regulations concerning exposure are not contravened. Similarly, the dose received by guides is fairly low (0.4 mSv/annum) due in part to current working practice. However, the risk to researchers entering the more inaccessible areas of the cave system is higher (0.06 mSv/visit). This survey also investigated the effect of seasonal variations on recorded radon concentration. From this work summer to winter ratios of between 1.1 and 9.51 were determined for different locations within the largest cave system.

  16. Colour changes by laser irradiation of reddish building limestones

    Science.gov (United States)

    Grossi, C. M.; Benavente, D.

    2016-10-01

    We have used X-ray photoelectron spectroscopy (XPS) as a novel method to investigate the causes of colour changes in a reddish limestone under irradiation by a Q-switched Nd:YAG 1064 nm laser. We irradiated clean dry and wet surfaces of Pidramuelle Roja, a building stone frequently used in the Asturian heritage, at fluences ranging from 0.12 to 1.47 J cm-2. We measured the colour coordinates and undertook XPS analysis of the state of oxidation of iron both before and after irradiation. Visible colour changes and potential aesthetic damage occurred on dry surfaces from a fluence of 0.31 J cm-2, with the stone showing a greening effect and very intense darkening. The colour change on dry surfaces was considerably higher than on wet surfaces, which at the highest fluence (1.47 J cm-2) was also above the human visual detection threshold. The use of XPS demonstrated that the change in colour (chroma and hue) is associated with a reduction in the iron oxidation state on dry surfaces during laser irradiation. This points out to a potential routinary use of XPS to analyse causes of colour changes during laser cleaning in other types of coloured building stones.

  17. Syracuse Limestone: From the Past a Prospect for Contemporary Buildings

    Directory of Open Access Journals (Sweden)

    Enrico Ciliberto

    2013-04-01

    Full Text Available The conservation of the historic stone heritage has great importance when this material characterizes the image of a city, as it happens in Syracuse (Sicily. Its historical buildings are afflicted by a heavy state of deterioration due to the particular microclimate, to pollution and to neglect endured over time. This article reports the investigations made on limestone samples from historic façades of the city and from the neighboring quarries still in operation, in order to understand the petrographic typology, the reaction to the degradation over time, the possible maintenance and recovery interventions, and the correct applications in buildings of new construction. For this aim, bulk and surface analysis have been made both on the quarry materials and on the corresponding aged materials. It is therefore possible to define the types of rock most suitable for the use in contemporary architecture guaranteeing criteria of perfect biocompatibility. In this way a natural material can be employed in traditional and innovative uses and ensure both the sustainability of the interventions and the continuity of a consolidated tradition.

  18. A procedure to evaluate environmental rehabilitation in limestone quarries.

    Science.gov (United States)

    Neri, Ana Claudia; Sánchez, Luis Enrique

    2010-11-01

    A procedure to evaluate mine rehabilitation practices during the operational phase was developed and validated. It is based on a comparison of actually observed or documented practices with internationally recommended best practices (BP). A set of 150 BP statements was derived from international guides in order to establish the benchmark. The statements are arranged in six rehabilitation programs under three categories: (1) planning (2) operational and (3) management, corresponding to the adoption of the plan-do-check-act management systems model to mine rehabilitation. The procedure consists of (i) performing technical inspections guided by a series of field forms containing BP statements; (ii) classifying evidences in five categories; and (iii) calculating conformity indexes and levels. For testing and calibration purposes, the procedure was applied to nine limestone quarries and conformity indexes were calculated for the rehabilitation programs in each quarry. Most quarries featured poor planning practices, operational practices reached high conformity levels in 50% of the cases and management practices scored moderate conformity. Despite all quarries being ISO 14001 certified, their management systems pay low attention to issues pertaining to land rehabilitation and biodiversity. The best results were achieved by a quarry whose expansion was recently submitted to the environmental impact assessment process, suggesting that public scrutiny may play a positive role in enhancing rehabilitation practices. Conformity indexes and levels can be used to chart the evolution of rehabilitation practices at regular intervals, to establish corporate goals and for communication with stakeholders. Copyright 2010 Elsevier Ltd. All rights reserved.

  19. Study on control of rock fragmentation at limestone quarry

    Institute of Scientific and Technical Information of China (English)

    SASAOKA Takashi; SHIMADA Hideki; SASAKI Takayuki; ICHINOSE Masatomo; MATSUI Ki-kuo

    2008-01-01

    The size distribution of a muck pile depends not on only the blasting standardbut also on the mechanical properties, joint system, and crack density of the rock mass.As, the cracks in the rock masses are especially heavily developed at the limestone quar-ries in Japan, they, along with the joints, have a large impact on the effects of blasting,such as the size of the muck pile. Therefore, if the joint system and/or crack density in arock mass can be determined and quantitatively evaluated, the blasting operation can beconducted more effectively, efficiently and safely. However, guidelines for designing ap-propriate blasting standards based on the rock mass conditions have not yet been scien-tifically developed. Therefore, blasting tests were conducted on different mines and faces,under different geological conditions and blasting standards, in order to determine the im-pacts of each factor on the effects of blasting. Summarized the results of a series of blast-ing tests and described the impacts of geological conditions on the size of the muck pileproduced by blast.

  20. The influence of combustion derived pollutants on limestone deterioration

    DEFF Research Database (Denmark)

    Johnson, JB; Montgomery, Melanie; Thompson, GE;

    1996-01-01

    10(-4) mu g cm(-2) s(-1), the pollutants were assessed individually and in various combinations, along with ozone as oxidant, at 84% RH with dry or water-wetted surfaces. The degradation was followed by analysis of exposed stone, for Cl-, SO42- and NO3-, and of run-off solution for Ca2+, in addition...... to the anions. From these data, the total calcium released from limestone to reaction ions and products and the percentages of each pollutant reacted (and so the deposition velocity (V-D)) in each exposure regime were calculated. HCl acted independently of the presence of other pollutants, showed 40 and 100...... rose from 3 to 40% at 84% RH in the presence of SO2 and O-3, with a V-D at 3 mm s(-1), but decreased in the presence of run-off solution. A limited study was performed on smoke-coated and naturally exposed, reaction-product-coated, samples. In addition to obvious factors such as deposited mass...

  1. Radon in the creswell crags Permian limestone caves.

    Science.gov (United States)

    Gillmore, G K; Phillips, P S; Denman, A R; Gilbertson, D D

    2002-01-01

    An investigation of radon levels in the caves of Creswell Crags, Derbyshire, an important Site of Special Scientific Interest (SSSI) shows that the Lower Magnesian Limestone (Permian) caves have moderate to raised radon gas levels (27-7800 Bq m(-3)) which generally increase with increasing distance into the caves from the entrance regions. This feature is partly explained in terms of cave ventilation and topography. While these levels are generally below the Action Level in the workplace (400 Bq m(-3) in the UK), they are above the Action Level for domestic properties (200 Bq m(-3)). Creswell Crags has approximately 40,000 visitors per year and therefore a quantification of effective dose is important for both visitors and guides to the Robin Hood show cave. Due to short exposure times the dose received by visitors is low (0.0016 mSv/visit) and regulations concerning exposure are not contravened. Similarly, the dose received by guides is fairly low (0.4 mSv/annum) due in part to current working practice. However, the risk to researchers entering the more inaccessible areas of the cave system is higher (0.06 mSv/visit). This survey also investigated the effect of seasonal variations on recorded radon concentration. From this work summer to winter ratios of between 1.1 and 9.51 were determined for different locations within the largest cave system.

  2. Regional soil geochemistry in the Ojailen Valley: a realm dominated by the industrial and mining city of Puertollano (South Central Spain)

    Science.gov (United States)

    López-Berdonces, Miguel; Fernandez-Calderón, Sergio; Higueras, Pablo; María Esbrí, Jose; Gonzalez-Corrochano, Beatríz; García-Noguero, Eva Mª; Martínez-Coronado, Alba; García-Noguero, Carolina

    2013-04-01

    Regional soil geochemistry in the Ojailén Valley: a realm dominated by the industrial and mining city of Puertollano (South Central Spain). Authors: Miguel A. López-Berdonces¹; Sergio Fernández Calderón¹; Pablo Higueras¹; José María Esbrí¹; Beatriz González-Corrochano¹; Eva Mª García-Noguero¹; Alba Martínez-Coronado¹; Carolina García Noguero¹ ¹Instituto de Geología Aplicada, Universidad de Castilla La Mancha, Almadén 13400 (Spain). Ojailén Valley is situated in South Central of Spain, an area where livestock, agriculture, mining and industry coexist. This work tries to assess the relationships between these activities and local environmental compartments: water, soils and heavy metal contents, and establish the most appropriate methodology of sample treatment and analytical techniques that can be employed on this kind of studies. For soil geochemistry, 152 samples were taken at two different depths, one at surface layer and another at 20 cm depth, and establish relationships between them and the possible sources. For this purpose, we determine soil parameters (pH, conductivity and organic matter) and total metal contents by Energy Dispersion of X Ray Fluorescence (EDXRF). Samples with higher nickel contents were analyzed with Inductive Coupled Plasma Spectroscopy (ICP-OES) after acid digestion. The study of surface waters includes 18 samples along the river and tributaries near mining and industrial areas. Water analysis was performed by ICP-OES. Soil samples shows pH between 6 and 8.5, highest located near on the east part of the valley, in the vicinity of petrochemical complex. Conductivity values show higher levels (1600 µS cm¯¹) in the vicinity of Puertollano and the industrial sites. Local reference value (LRV) for contaminated soils were determined according to the methodology proposed by Jimenez-Ballesta et al. (2010), using the equation: LRV=GM + 2SD, where LRV: Local Reference Value, GM: Geometric Mean, SD: Standard Deviation

  3. Generalized thickness of the Madison Limestone and Englewood Formation, Black Hills, South Dakota.

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set is a polygon coverage created in ARC/INFO that represents the generalized thickness of the Madison Limestone and Englewood Formation, Black Hills,...

  4. Coated limestone as a filler for the production of PVC-products

    Directory of Open Access Journals (Sweden)

    Mihajlović Slavica

    2005-01-01

    Full Text Available The results of laboratory investigations of the possibility to obtain coated limestone for the production of PVC-products are presented in this paper. Limestone from the "Venčac" deposit (Aranđelovac, Serbia and Montenegro was used as the raw material. The investigations were carried out in two phases: obtaining the coated limestone and determination of the degree of coating. The results of the investigations showed that successful coating of the surface of the limestone particles with Ca-stearate (Ca-stearate content 3% was achieved in a vibro mill with rings and the obtained degree of coating was higher than 95%. The coating degree was determined in transmitted light by a polarization microscope applying the immersion method (water immersion.

  5. Systematic ichnology of microborings from the Cenozoic White Limestone Group, Jamaica, West Indies

    NARCIS (Netherlands)

    Blissett, D.J.; Pickerill, R.K.

    2007-01-01

    The Middle Eocene to Middle Miocene White Limestone Group of Jamaica contains a common and diverse, poorly to well-preserved microboring ichnofauna, namely Centrichnus eccentricus Bromley & Martinell, Curvichnus pediformis isp. nov., Dendrorete balani Tavernier, Campbell & Golubic, Dipatulichnus rot

  6. Reactivation of limestone sorbents in FBC for SO{sub 2} capture

    Energy Technology Data Exchange (ETDEWEB)

    E.J. Anthony; E.M. Bulewicz; L. Jia [CETC-O/NRCan, Ottawa, ON (Canada)

    2007-04-15

    Fluidized bed combustion (FBC) has the considerable advantage of being capable of burning high-sulphur fuels while achieving in situ sulphur capture by means of limestone addition. Unfortunately the efficiency of this process is limited, and limestone utilization in the range of 30-45% is not uncommon. In consequence, improving limestone utilization has long been an aim of FBC research. The principal directions this research has taken are the use of water (as liquid or vapour) to reactivate the spent sorbent, or mixing of chemical additives with the limestone to improve its utilization. Despite research stretching over the entire history of FBC combustion, there are still no working commercial applications of reactivation technology noted in the open literature. The paper presents some of the more important research undertaken in this field and explores the major knowledge gaps that still exist in the area of sorbent reactivation. 131 refs., 6 figs., 6 tabs. 3 apps.

  7. Techniques for Source Zone and Plume Characterization of Tetrachloroethene in Fractured Limestone Aquifers

    DEFF Research Database (Denmark)

    Fjordbøge, Annika Sidelmann; Mosthaf, Klaus; Janniche, Gry S.;

    Characterization of chlorinated solvents in fractured limestone aquifers is essential for proper development of site specific conceptual models and subsequent risk assessment and remediation. High resolution characterization is challenged by the difficulties involved in collection of intact core...... samples as water flushing during drilling often results in extensive core losses, especially from zones with soft limestone in contact with flint beds. Field investigations with alternative characterization techniques have been carried out at two Danish sites with tetrachloroethene (PCE) contaminated...... fractured limestone aquifers. The two sites represent different scales (source and plume) and contaminant levels (DNAPL and dissolved). The scope of the investigations was to evaluate different techniques for characterization of the contaminant distribution in the limestone aquifers and to obtain...

  8. SELECTED CHARACTERISTICS OF LIMESTONE AND DOLOMITE RESERVOIRS IN THE UNITED STATES.

    Science.gov (United States)

    Schmoker, James W.; Krystinik, Katherine B.; Halley, Robert B.

    1985-01-01

    Limestone reservoirs are more numerous in the United States than dolomite reservoirs (by a ratio of about 3 to 1) because limestones are more abundant than dolomite. However, in the eight states that account for over 90% of United States carbonate reservoirs, there is a statistical tendency for carbonate reservoirs to occur preferentially in dolomites. Dolomite reservoirs, on the average, are larger and deeper than those of limestone, yet they often have lower matrix porosities and permeabilities. This line of investigation offers supplemental evidence that dolomitization tends to improve the reservoir properties of a given formation, and that effective fracture systems at reservoir depths are more likely to occur in dolomites than in limestones. Refs.

  9. 76 FR 35396 - Black Hills National Forest, Mystic Ranger District, South Dakota, Section 30 Limestone Mining...

    Science.gov (United States)

    2011-06-17

    ... mitigation for significant cultural and archaeological values by the proposed undertaking. Successful... processing into chemical grade limestone products. Concurrent reclamation is planned. Therefore approximately... planners are aware of issues related to cultural (heritage) resources and scenic quality. Through...

  10. Primulina cardaminifolia (Gesneriaceae), a rare new species from limestone areas in Guangxi, China

    National Research Council Canada - National Science Library

    Xu, Wei-Bin; Liu, Yan; Kono, Yoshiko; Chang, Hsuan; Peng, Ching-I; Chung, Kuo-Fang

    2013-01-01

    Primulina cardaminifolia Yan Liu & W.B. Xu (Gesneriaceae), a distinct new species with imparipinnate leaves, is described and illustrated from a limestone valley in Guangxi Zhuangzu Autonomous Region, China...

  11. Systematic ichnology of microborings from the Cenozoic White Limestone Group, Jamaica, West Indies

    NARCIS (Netherlands)

    Blissett, D.J.; Pickerill, R.K.

    2007-01-01

    The Middle Eocene to Middle Miocene White Limestone Group of Jamaica contains a common and diverse, poorly to well-preserved microboring ichnofauna, namely Centrichnus eccentricus Bromley & Martinell, Curvichnus pediformis isp. nov., Dendrorete balani Tavernier, Campbell & Golubic, Dipatulichnus

  12. Deterioration of limestone aggregate mortars by liquid sodium in fast breeder reactor environment

    Energy Technology Data Exchange (ETDEWEB)

    Mohammed Haneefa, K., E-mail: mhkolakkadan@gmail.com [Department of Civil Engineering, IIT Madras, Chennai (India); Santhanam, Manu [Department of Civil Engineering, IIT Madras, Chennai (India); Parida, F.C. [Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam (India)

    2014-08-15

    Highlights: • Limestone mortars were exposed to liquid sodium exposure at 550 °C. • Micro-analytical techniques were used to characterize the exposed specimens. • The performance of limestone mortar was greatly influenced by w/c. • The fundamental degradation mechanisms of limestone mortars were identified. - Abstract: Hot liquid sodium at 550 °C can interact with concrete in the scenario of an accidental spillage of sodium in liquid metal cooled fast breeder reactors. To protect the structural concrete from thermo-chemical degradation, a sacrificial layer of limestone aggregate concrete is provided over it. This study investigates the fundamental mechanisms of thermo-chemical interaction between the hot liquid sodium and limestone mortars at 550 °C for a duration of 30 min in open air. The investigation involves four different types of cement with variation of water-to-cement ratios (w/c) from 0.4 to 0.6. Comprehensive analysis of experimental results reveals that the degree of damage experienced by limestone mortars displayed an upward trend with increase in w/c ratios for a given type of cement. Performance of fly ash based Portland pozzolana cement was superior to other types of cements for a w/c of 0.55. The fundamental degradation mechanisms of limestone mortars during hot liquid sodium interactions include alterations in cement paste phase, formation of sodium compounds from the interaction between solid phases of cement paste and aggregate, modifications of interfacial transition zone (ITZ), decomposition of CaCO{sub 3}, widening and etching of rhombohedral cleavages, and subsequent breaking through the weakest rhombohedral cleavage planes of calcite, staining, ferric oxidation in grain boundaries and disintegration of impurity minerals in limestone.

  13. Retention and transport of graphene oxide in water-saturated limestone media.

    Science.gov (United States)

    Dong, Shunan; Sun, Yuanyuan; Gao, Bin; Shi, Xiaoqing; Xu, Hongxia; Wu, Jianfeng; Wu, Jichun

    2017-08-01

    In this work, column experiments were conducted to investigate the transport characteristics of graphene oxide (GO) nanoparticles in limestone media under various electrolytes, solution pH, and humic acid (HA) concentration conditions. In the limestone media, GO exhibited relatively low mobility with the mass recovery rate lower than 65.2%, even when solution ionic strength was low. The presence of HA enhanced its mobility. In addition, the presence of S(2-), a divalent anion, also promoted GO transport in limestone media compared to Cl(-) under similar ionic strength conditions through neutralizing more positive charge and thus diminishing the cation bridging. Solution pH showed slight effect on the transport of GO in limestone with the mass recovery range from 40.3% to 51.7%. Over all, decreases in solution pH, HA concentration and increases in solution ionic strength reduced the mobility of GO in the limestone media under the tested conditions. These results indicated both environmental conditions and media characteristics played important roles in controlling GO fate and transport in porous media. The one-site kinetic deposition model was applied to describe the interactions between the GO and limestone media and model simulations fitted the observed experimental data very well. As limestone is an important component of aquiferous media in subsurface, findings from this study elucidated the key factors and processes controlling the fate of GO particles in limestone media, which can inform the prediction and assessment of the risks of GO in groundwater environment. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Comparison of different modeling approaches to simulate contaminant transport in a fractured limestone aquifer

    DEFF Research Database (Denmark)

    Mosthaf, Klaus; Rosenberg, L.; Balbarini, Nicola

    approaches have been developed to describe contaminant transport in fractured media, such as the discrete fracture (with various fracture geometries), equivalent porous media (with and without anisotropy), and dual porosity models. However, these modeling concepts are not well tested for limestone geologies...... of field data is the determination of relevant hydraulic properties and interpretation of aqueous and solid phase contaminant concentration sampling data. Traditional water sampling has a bias towards fracture sampling, however concentrations in the limestone matrix are needed for assessing contaminant...

  15. Evaluation of modeling approaches to simulate contaminant transport in a fractured limestone aquifer

    DEFF Research Database (Denmark)

    Mosthaf, Klaus; Fjordbøge, Annika Sidelmann; Broholm, Mette Martina

    contaminant transport in fractured media, such as discrete fracture, equivalent porous media, and dual continuum models. However, these modeling concepts are not well tested for real limestone geologies. Our goal is therefore to develop, evaluate and compare approaches for modeling transport of contaminants...... data is the determination of relevant hydraulic properties and interpretation of aqueous and solid phase contaminant concentration sampling data. Traditional water sampling has a bias towards fracture sampling; however, concentrations in the limestone matrix are needed for assessing contaminant rebound...

  16. River water quality in weathered limestone: A case study in upper Mahanadi basin, India

    Indian Academy of Sciences (India)

    B K Panigrahy; B C Raymahashay

    2005-10-01

    Stromatolitic limestone and calcareous shale belonging to Chattisgarh Supergroup of Proterozoic age dominate the upper part of the Mahanadi river basin.X-ray diffractogram (XRD)of limestone rocks show presence of a significant amount of calcite,dolomite and ankerite.Shales of various colours contain calcite and dolomite.It is observed that congruent dissolution of carbonate minerals in the Charmuria pure limestone has given rise to a typical karst topography.On the other hand, limestones are also seen to support red and black soil pro files.This indicates that the limestone bedrock undergoes a parallel incongruent weathering,which leaves a residue of decomposed rock. The XRD analyses reveal that the limestone soils thus formed contain an assemblage of quartz,clays and Fe-oxides.It is likely that the silicate component trapped during deposition of the stromatolitic limestone weathers incongruently resulting in diverse soil profiles.Carbonate and silicate mineral weathering schemes have been worked out to explain the soil formation,fixation of Al in clay minerals, and Fe in goethite.The water quality parameters such as Ca, Mg and HCO3 in the river water suggest under saturation with respect to calcite and dolomite.The mineral stability diagrams indicate that kaolinite and Ca-smectite are stable in the river water environment,hence they occur in suspended sediments and soils.The dominant influence of carbonate weathering on the water quality is observed even in the downstream part of the river outside the limestone terrain.

  17. Evaluation of Bryozoan limestone properties based on in-situ abd laboratory element tests

    DEFF Research Database (Denmark)

    Jackson, Peter Graham; Steenfelt, Jørgen S.; Foged, Niels Nielsen

    2004-01-01

    As part of the preparation for the Citytunnel project in Malmö southern Sweden, the Bryozoan limestone formation was investigated, a geological model was defined for this formation and its mass properties were derived for the design of a major cavern. This paper describes the methodology used for...... for making the link between the geological model and the engineering properties of the limestone. It also describes the mentodology used to derive mass strength properties from element and borehole scale testing....

  18. Abrupt environmental and climatic change during the deposition of the Early Permian Haushi limestone, Oman

    OpenAIRE

    Stephenson, Michael; Angiolini, Lucia; Leng, Melanie; Brewer, T. S.; Berra, F.; F. Jadoul; G. Gambacorta; Verna, V.; Al Beloushi, B.

    2008-01-01

    During the late Sakmarian (Early Permian), the Haushi limestone was deposited in a shallow embayment of the Neotethys Ocean covering what is now north Oman and parts of southeast Saudi Arabia. The sea persisted through the late Sakmarian, but by the time of the deposition of the ?Artinskian Middle Gharif Member, limestone deposition had ceased and generally arid fluvial and minor lacustrine palaeonvironments in a low accommodation space setting had become established. Analysis of three subsur...

  19. Human impact on the vegetation of limestone cliffs in the northern Swiss Jura mountains

    OpenAIRE

    Müller, Stefan

    2006-01-01

    Cliffs provide unique habitats for many specialised organisms, including chamaephytes and slowly growing trees. Drought, high temperature amplitude, scarcity of nutrients and high insolation are general characteristics of exposed limestone cliff faces. The vegetation of limestone cliffs in the Swiss Jura mountains consists of plants of arctic-alpine, continental and Mediterranean origin. Several populations exhibit relicts from post- or interglacial warm or cold climatic per...

  20. Interpretation of well hydrographs in the karstic Maynardville Limestone at the Oak Ridge Y-12 Plant

    Energy Technology Data Exchange (ETDEWEB)

    Shevenell, L.A.; McMaster, B.W.

    1996-06-01

    The Maynardville Limestone in Oak Ridge, Tennessee underlies the southern portion of Bear Creek Valley (BCV), and is considered to be the primary pathway for groundwater leaving the Y-12 Plant boundaries. Sixty-seven percent of all wells drilled into the Maynardville Limestone have intersected at least one cavity, suggesting karst features may be encountered throughout the shallow (< 200 ft) portions of the Limestone. Because waste facilities at the Y-12 Plant are located adjacent to the Maynardville Limestone, contaminants could enter the karst aquifer and be transported in the conduit system. As part of an overall hydrologic characterization effort of this karst aquifer, 41 wells in the Maynardville Limestone were instrumented with pressure transducers to monitor water level changes (hydrographs) associated with rain events. Wells at depths between approximately 20 and 750 ft were monitored over the course of at least two storms in order that variations with depth could be identified. The wells selected were not exclusively completed in cavities but were selected to include the broad range of hydrologic conditions present in the Maynardville Limestone. Cavities, fractures and diffuse flow zones were measured at a variety of depths. The water level data from the storms are used to identify areas of quickflow versus slower flowing water zones. The data are also used to estimate specific yields and continuum transmissitives in different portions of the aquifer.

  1. Effects of strain rates on mechanical properties of limestone under high temperature

    Institute of Scientific and Technical Information of China (English)

    Tang Furong; Mao Xianbiao; Zhang Lianying; Yin Huiguang; Li Yan

    2011-01-01

    The experimental tests for limestone specimens at 700 ℃ in uniaxial compression were carried out to investigate the mechanical effects of loading rates on limestone by using a MTS810 rock mechanics servocontrolled testing system considering the loading rate as a variable.The mechanical properties of limestone such as the stress-strain curve,variable characteristics of peak strength and the modulus of elasticity of limestone were studied under the strain rates ranging from 1.1 × 10-s to 1.1 × 10-1 s-1.(1) Sharp decreases were shown for the peak strength and elastic modulus of limestone from 1.1 × 10-5 to 1.1 × 10 4 s-1 at 700 C as well as a downward trend was shown from 1.1 × 10 4 to 1.1 × 10-1 s-1with the rise of the strain rate.(2) The peak strain increased from 1.1 × 10-5 to 1.1 × 10-4 s-1,however,there was no obvious changes shown for the peak strain of limestone from 1.1 × 10-4 to 1.1 × 10-1 s-1.These results can nrovide valuable references for the rock blasting effect and design of mine.

  2. Accelerated weathering of limestone for CO2 mitigation opportunities for the stone and cement industries

    Science.gov (United States)

    Langer, W.H.; Juan, C.A.S.; Rau, G.H.; Caldeira, K.

    2009-01-01

    Large amounts of limestone fines coproduced during the processing of crushed limestone may be useful in the sequestration of carbon dioxide (CO 2). Accelerated weathering of limestone (AWL) is proposed as a low-tech method to capture and sequester CO2 from fossil fuel-fired power plants and other point-sources such as cement manufacturing. AWL reactants are readily available, inexpensive, and environmentally benign. Waste CO 2 is hydrated with water to produce carbonic acid, which then reacts with and is neutralized by limestone fines, thus converting CO2 gas to dissolved calcium bicarbonate. AWL waste products can be disposed of in the ocean. Feasibility requires access to an inexpensive source of limestone and to seawater, thus limiting AWL facilities within about 10 km of the coastline. The majority of U.S. coastal power generating facilities are within economical transport distance of limestone resources. AWL presents opportunities for collaborative efforts among the crushed stone industry, electrical utilities, cement manufactures, and research scientists.

  3. Influence of limestone waste as partial replacement material for sand and marble powder in concrete properties

    Directory of Open Access Journals (Sweden)

    Omar M. Omar

    2012-12-01

    Full Text Available Green concrete are generally composed of recycling materials as hundred or partial percent substitutes for aggregate, cement, and admixture in concrete. Limestone waste is obtained as a by-product during the production of aggregates through the crushing process of rocks in rubble crusher units. Using quarry waste as a substitute of sand in construction materials would resolve the environmental problems caused by the large-scale depletion of the natural sources of river and mining sands. This paper reports the experimental study undertaken to investigate the influence of partial replacement of sand with limestone waste (LSW, with marble powder (M.P as an additive on the concrete properties. The replacement proportion of sand with limestone waste, 25%, 50%, and 75% were practiced in the concrete mixes except in the concrete mix. Besides, proportions of 5%, 10% and 15% marble powder were practiced in the concrete mixes. The effects of limestone waste as fine aggregate on several fresh and hardened properties of the concretes were investigated. The investigation included testing of compressive strength, indirect tensile strength, flexural strength, modulus of elasticity, and permeability. It was found that limestone waste as fine aggregate enhanced the slump test of the fresh concretes. But the unit weight concretes were not affected. However, the good performance was observed when limestone waste as fine aggregate was used in presence of marble powder.

  4. Experimental Study on the Porosity Creep Properties of Broken Limestone

    Directory of Open Access Journals (Sweden)

    Li Shun-cai

    2016-01-01

    Full Text Available In the underground engineering, the long-term stability of the surrounding rocks (especially the broken rocks containing water and the ground settlement resulted from the seepage-creep coupling above goaf have been the important research subjects concerning the deep mining. For the broken rock, its porosity is an important structural parameter determining its creep properties, and the porosity change rate is more superior to describe the creep characteristics compared with the strain change rate at a certain direction. In this paper, MTS815.02 Rock Mechanics Test System is used to carry out the creep experiments on water-saturated broken limestone, and then the time curves of porosity and of the porosity change rate are obtained. By regression, we have got the relation equation between the porosity change rate with the instant porosity and the stress level during the creep. The study indicates that when the stress retains a constant level, the relation between the porosity change rate and the instant porosity can be fitted with a cubical polynomial. The obtained creep relation equation between the porosity change rate and the instant porosity and the instant stress provides a necessary state equation for studying the coupling between the seepage and the creep of the broken rock. Furthermore, the seepage in the broken rock has been verified to satisfy the Forchheimer’s non-Darcy flow according to our previous studies, and its seepage properties, k, β and ca can all be expressed respectively as the polynomial of the porosity, so, by combining with these three state equations we have obtained the four essential state equations for solving the coupling problems of the seepage and the creep for the broken rocks.

  5. Mangrove plantation over a limestone reef - Good for the ecology?

    Science.gov (United States)

    Asaeda, Takashi; Barnuevo, Abner; Sanjaya, Kelum; Fortes, Miguel D.; Kanesaka, Yoshikazu; Wolanski, Eric

    2016-05-01

    There have been efforts to restore degraded tropical and subtropical mangrove forests. While there have been many failures, there have been some successes but these were seldom evaluated to test to what level the created mangrove wetlands reproduce the characteristics of the natural ecosystem and thus what ecosystem services they can deliver. We provide such a detailed assessment for the case of Olango and Banacon Islands in the Philippines where the forest was created over a limestone reef where mangroves did not exist in one island but they covered most of the other island before deforestation in the 1940s and 1950s. The created forest appears to have reached a steady state after 60 years. As is typical of mangrove rehabilitation efforts worldwide, planting was limited to a single Rhizophora species. While a forest has been created, it does not mimic a natural forest. There is a large difference between the natural and planted forests in terms of forest structure and species diversity, and tree density. The high density of planted trees excludes importing other species from nearby natural forests; therefore the planted forest remains mono-specific even after several decades and shows no sign of mimicking the characteristics of a natural forest. The planted forests provided mangrove propagules that invaded nearby natural forests. The planted forest has also changed the substratum from sandy to muddy. The outline of the crown of the planted forest has become smooth and horizontal, contrary to that of a natural forest, and this changes the local landscape. Thus we recommend that future mangrove restoration schemes should modify their methodology in order to plant several species, maintain sufficient space between trees for growth, include the naturally dominant species, and create tidal creeks, in order to reproduce in the rehabilitated areas some of the key ecosystem characteristics of natural mangrove forests.

  6. Combined Sm-Nd and Lu-Hf dating of garnets from the Putomayo foreland basin in south-central Colombia and implications

    Science.gov (United States)

    Bloch, E. M.; Ibanez-mejia, M.; Ganguly, J.

    2013-12-01

    Garnet-whole rock (Grt-WR) ages of metapelites determined by the Lu-Hf decay system are almost always older than those determined by the Sm-Nd system. Unambiguous interpretation of the observed age differences has been hindered by a lack of adequate information about grain size, diffusion data for Hf in garnet, and in many cases about peak metamorphic conditions and cooling rates, all of which affect the closure temperatures of these decay systems. As part of a broader study on basement rocks from the Andean Putomayo foreland basin in south-central Colombia, we have determined the Lu-Hf and Sm-Nd Grt-WR ages of these rocks using painstakingly handpicked garnets of ~50 μm radius, and obtained ages of 1070 × 5.6 and 1007 × 2.9 Ma, respectively. By modeling the retrograde Fe-Mg zoning in garnet adjacent to biotite according to an asymptotic cooling model (1/T = 1/To + ηt) with the diffusion data from [1], an initial cooling rate of ~2-5 °C/Ma is obtained independently of the geochronological data; peak P-T conditions of ~8 kb, 675 °C are imposed by garnet-orthopyroxene thermobarometry. Using the above data in conjunction with the Nd diffusion data from [2] and Hf diffusion data from our recent study, we obtain closure temperatures for the Lu-Hf and Sm-Nd decay systems in garnet of ~545-565 °C and 415-430 °C, respectively. Results from analytical solutions [3, 4] and a more flexible numerical method are found to be in good agreement with one another. The calculated difference of closure temperatures predicts a difference of ~105-40 Ma between the ages determined by the two decay systems, as compared to the observed age difference of 63 × 6 Ma. The predicted peak metamorphic age derived from the measured and calculated resetting ages of the two decay systems is between ~1030 and 1185 Ma, as compared to the Lu-Hf age of 1070 ×1.9 Ma; we are currently working to obtain U-Pb zircon ages to better constrain this peak metamorphic age. In calculating these results

  7. Water Quality in the Equus Beds Aquifer and the Little Arkansas River Before Implementation of Large-Scale Artificial Recharge, South-Central Kansas, 1995-2005

    Science.gov (United States)

    Ziegler, Andrew C.; Hansen, Cristi V.; Finn, Daniel A.

    2010-01-01

    Artificial recharge of the Equus Beds aquifer using runoff from the Little Arkansas River in south-central Kansas was first proposed in 1956 and was one of many options considered by the city of Wichita to preserve its water supply. Declining aquifer water levels of as much as 50 feet exacerbated concerns about future water availability and enhanced migration of saltwater into the aquifer from past oil and gas activities near Burrton and from the Arkansas River. Because Wichita changed water-management strategies and decreased pumping from the Equus Beds aquifer in 1992, water storage in the aquifer recovered by about 50 percent. This recovery is the result of increased reliance on Cheney Reservoir for Wichita water supply, decreased aquifer pumping, and larger than normal precipitation. Accompanying the water-level recovery, the average water-level gradient in the aquifer decreased from about 12 feet per mile in 1992 to about 8 feet per mile in January 2006. An important component of artificial recharge is the water quality of the receiving aquifer and the water being recharged (source water). Water quality within the Little Arkansas River was defined using data from two real-time surface-water-quality sites and discrete samples. Water quality in the Equus Beds aquifer was defined using sample analyses collected at 38 index sites, each with a well completed in the shallow and deep parts of the Equus Beds aquifer. In addition, data were collected at diversion well sites, recharge sites, background wells, and prototype wells for the aquifer storage and recovery project. Samples were analyzed for major ions, nutrients, trace metals, radionuclides, organic compounds, and bacterial and viral indicators. Water-quality constituents of concern for artificial recharge are those constituents that frequently (more than 5 percent of samples) may exceed Federal [U.S. Environmental Protection Agency (USEPA)] and State drinking-water criteria in water samples from the receiving

  8. Simulation of streamflow, evapotranspiration, and groundwater recharge in the lower San Antonio River Watershed, South-Central Texas, 2000-2007

    Science.gov (United States)

    Lizarraga, Joy S.; Ockerman, Darwin J.

    2010-01-01

    The U.S. Geological Survey (USGS), in cooperation with the San Antonio River Authority, the Evergreen Underground Water Conservation District, and the Goliad County Groundwater Conservation District, configured, calibrated, and tested a watershed model for a study area consisting of about 2,150 square miles of the lower San Antonio River watershed in Bexar, Guadalupe, Wilson, Karnes, DeWitt, Goliad, Victoria, and Refugio Counties in south-central Texas. The model simulates streamflow, evapotranspiration (ET), and groundwater recharge using rainfall, potential ET, and upstream discharge data obtained from National Weather Service meteorological stations and USGS streamflow-gaging stations. Additional time-series inputs to the model include wastewater treatment-plant discharges, withdrawals for cropland irrigation, and estimated inflows from springs. Model simulations of streamflow, ET, and groundwater recharge were done for 2000-2007. Because of the complexity of the study area, the lower San Antonio River watershed was divided into four subwatersheds; separate HSPF models were developed for each subwatershed. Simulation of the overall study area involved running simulations of the three upstream models, then running the downstream model. The surficial geology was simplified as nine contiguous water-budget zones to meet model computational limitations and also to define zones for which ET, recharge, and other water-budget information would be output by the model. The model was calibrated and tested using streamflow data from 10 streamflow-gaging stations; additionally, simulated ET was compared with measured ET from a meteorological station west of the study area. The model calibration is considered very good; streamflow volumes were calibrated to within 10 percent of measured streamflow volumes. During 2000-2007, the estimated annual mean rainfall for the water-budget zones ranged from 33.7 to 38.5 inches per year; the estimated annual mean rainfall for the entire

  9. Geophysical Characterization of the Quaternary-Cretaceous Contact Using Surface Resistivity Methods in Franklin and Webster Counties, South-Central Nebraska

    Science.gov (United States)

    Teeple, Andrew P.; Kress, Wade H.; Cannia, James C.; Ball, Lyndsay B.

    2009-01-01

    To help manage and understand the Platte River system in Nebraska, the Platte River Cooperative Hydrology Study (COHYST), a group of state and local governmental agencies, developed a regional ground-water model. The southern boundary of this model lies along the Republican River, where an area with insufficient geologic data immediately north of the Republican River led to problems in the conceptualization of the simulated flow system and to potential problems with calibration of the simulation. Geologic descriptions from a group of test holes drilled in south-central Nebraska during 2001 and 2002 indicated a possible hydrologic disconnection between the Quaternary-age alluvial deposits in the uplands and those in the Republican River lowland. This disconnection was observed near a topographic high in the Cretaceous-age Niobrara Formation, which is the local bedrock. In 2003, the U.S. Geological Survey, in cooperation with the COHYST, collected surface geophysical data near these test holes to better define this discontinuity. Two-dimensional imaging methods for direct-current resistivity and capacitively coupled resistivity were used to define the subsurface distribution of resistivity along several county roads near Riverton and Inavale, Nebraska. The relation between the subsurface distribution of resistivity and geology was defined by comparing existing geologic descriptions of test holes to surface-geophysical resistivity data along two profiles and using the information gained from these comparisons to interpret the remaining four profiles. In all of the resistivity profile sections, there was generally a three-layer subsurface interpretation, with a resistor located between two conductors. Further comparison of geologic data with the geophysical data and with surficial features was used to identify a topographic high in the Niobrara Formation near the Franklin Canal which was coincident with a resistivity high. Electrical properties of the Niobrara

  10. Postwildfire debris-flow hazard assessment of the area burned by the 2012 Little Bear Fire, south-central New Mexico

    Science.gov (United States)

    Tillery, Anne C.; Matherne, Anne Marie

    2013-01-01

    A preliminary hazard assessment was developed of the debris-flow potential from 56 drainage basins burned by the Little Bear Fire in south-central New Mexico in June 2012. The Little Bear Fire burned approximately 179 square kilometers (km2) (44,330 acres), including about 143 km2 (35,300 acres) of National Forest System lands of the Lincoln National Forest. Within the Lincoln National Forest, about 72 km2 (17,664 acres) of the White Mountain Wilderness were burned. The burn area also included about 34 km2 (8,500 acres) of private lands. Burn severity was high or moderate on 53 percent of the burn area. The area burned is at risk of substantial postwildfire erosion, such as that caused by debris flows and flash floods. A postwildfire debris-flow hazard assessment of the area burned by the Little Bear Fire was performed by the U.S. Geological Survey in cooperation with the U.S. Department of Agriculture Forest Service, Lincoln National Forest. A set of two empirical hazard-assessment models developed by using data from recently burned drainage basins throughout the intermountain Western United States was used to estimate the probability of debris-flow occurrence and volume of debris flows along the burn area drainage network and for selected drainage basins within the burn area. The models incorporate measures of areal burn extent and severity, topography, soils, and storm rainfall intensity to estimate the probability and volume of debris flows following the fire. Relative hazard rankings of postwildfire debris flows were produced by summing the estimated probability and volume ranking to illustrate those areas with the highest potential occurrence of debris flows with the largest volumes. The probability that a drainage basin could produce debris flows and the volume of a possible debris flow at the basin outlet were estimated for three design storms: (1) a 2-year-recurrence, 30-minute-duration rainfall of 27 millimeters (mm) (a 50 percent chance of occurrence in

  11. Collision-induced basalt eruptions at Pleiku and Buôn Mê Thuột, south-central Viet Nam

    Science.gov (United States)

    Hoàng, Nguyễn; Flower, Martin F. J.; Chí, Cung Thu'ọ'ng; Xuân, Phạm Tích; Quý, Hoàng Văn; Sơn, Trần Thanh

    2013-09-01

    Neogene-Quaternary basalts occur as dispersed volcanic clusters in the vicinity of the Tethyan tectonic belt, possibly representing 'far-field' effects of the Early Tertiary collisions of Gondwana fragments with the southern margin of Eurasia. In Indochina, such a 'Diffuse Igneous Province' post-dates the 45-42 Ma 'hard' India-Asia collision and southeastward, collision induced (c. 30-17 Ma.), extrusion of Indochina. Extrusion was accommodated by left-lateral strike-slip shearing on the Ailao Shan-Red River Fault, coeval with seafloor spreading in the East Viet Nam (South China) Sea. The Indochina basalts mostly comprise shield-building tholeiites capped by small-volume undersaturated types, the latter often bearing mantle xenoliths and 'exotic' xenocrysts such as sapphire, zircon. They appeared at c. 17 Ma, more-or-less coinciding with the cessation of both continental extrusion and seafloor spreading. At this point extensional stress appears to have shifted westwards to continental Indochina, with magmatic activity appearing, characteristically, at 'pull-apart' basins. However, the relationship of mantle melting beneath this region to its geodynamic setting is controversial, being variously attributed to mantle plumes, extreme lithospheric stretching, and lateral asthenospheric displacement. There is little or no definitive evidence for regional mantle upwelling while lithosphere stretching alone appears to be insufficient to allow for melting, Here, we present geochemical and Sr, Nd, and Pb isotopic (and paleomagnetic data), for cored sections from the Pleiku and Buon Mê Thuột plateaus in south-central Viet Nam, representative in most respects of the Indochina province as a whole. In the Pleiku shield olivine tholeiite flows are intercalated with quartz tholeiites while, in contrast, alkali basalts predominate over olivine tholeiite in the Buon Mê Thuột (BMT) shield. The first of these features (in Pleiku) probably reflects crustal wall-rock reaction while

  12. Trends In Nutrient and Sediment Concentrations and Loads In Major River Basins of the South-Central United States, 1993-2004

    Science.gov (United States)

    Rebich, Richard A.; Demcheck, Dennis K.

    2008-01-01

    Nutrient and sediment data collected at 115 sites by Federal and State agencies from 1993 to 2004 were analyzed by the U.S. Geological Survey to determine trends in concentrations and loads for selected rivers and streams that drain into the northwestern Gulf of Mexico from the south-central United States, specifically from the Lower Mississippi, Arkansas-White-Red, and Texas-Gulf Basins. Trends observed in the study area were compared to determine potential regional patterns and to determine cause-effect relations with trends in hydrologic and human-induced factors such as nutrient sources, streamflow, and implementation of best management practices. Secondary objectives included calculation of loads and yields for the study period as a basis for comparing the delivery of nutrients and sediment to the northwestern Gulf of Mexico from the various rivers within the study area. In addition, loads were assessed at seven selected sites for the period 1980-2004 to give hydrologic perspective to trends in loads observed during 1993-2004. Most study sites (about 64 percent) either had no trends or decreasing trends in streamflow during the study period. The regional pattern of decreasing trends in streamflow during the study period appeared to correspond to moist conditions at the beginning of the study period and the influence of three drought periods during the study period, of which the most extreme was in 2000. Trend tests were completed for ammonia at 49 sites, for nitrite plus nitrate at 69 sites, and for total nitrogen at 41 sites. For all nitrogen constituents analyzed, no trends were observed at half or more of the sites. No regional trend patterns could be confirmed because there was poor spatial representation of the trend sites. Decreasing trends in flow-adjusted concentrations of ammonia were observed at 25 sites. No increasing trends in concentrations of ammonia were noted at any sites. Flow-adjusted concentrations of nitrite plus nitrate decreased at 7

  13. Modeling CO2 Sequestration in Saline Aquifer and Depleted Oil Reservoirs to Evaluate Regional CO2 Sequestration Potential of Ozark Plateau Aquifer System, South-Central Kansas

    Science.gov (United States)

    Watney, W. L.; Rush, J.

    2011-12-01

    The Paleozoic-age Ozark Plateau Aquifer System (OPAS) in southern Kansas consists of a thick (>450 m) and deeply buried (>1 km) succession of Cambro-Ordovician Arbuckle Group strata (dolomite) overlain by Lower Ordovician to Lower Carboniferous-age carbonate, chert, and shale. The Arbuckle Group is a thick widespread saline aquifer in southern Kansas. A 500 meter core of the OPAS interval and immediate overlying Pennsylvanian shale caprock were cored in early 2011 in the BEREXCO Wellington KGS #1-32 well in Wellington Field, a nearly depleted oil field in Sumner County, in south-central Kansas. An exhaustive set of modern logs were run in the KGS #1-32 well including chemical, microresistivity imaging, dipole sonic, nuclear magnetic resonance, and standard porosity and resistivity wireline logs. In addition, routine and special core analyses provide vital means to calibrate these logs. Core also provide vital chemical analyses and rock samples to run flow experiments, including in situ conditions, to establish reaction kinetics of rock and connate brines with CO2. Core and logs also provide the means to calibrate a 26 km2 multicomponent 3D seismic survey that was acquired in Wellington Field in 2010. Studies of four oil fields, also part of this project, are underway in southwestern Kansas to provide additional calibration points for the western part of the regional study that covers 65,000 km2 where CO2 sequestration capacity will be measured. Several hundred deep wells have been identified to serve as type wells in the regional study area. Well logs and sample descriptions are being digitized, correlated, and mapped to define distribution of aquifers, oil reservoirs, and caprocks. Drill stem test data have been analyzed for deep wells to establish that the Arbuckle is an open aquifer connected to surface exposures 100s of km to east in central Missouri. Over 500 km2 of 3D seismic have been donated by industrial partners to aid in understanding fault and fracture

  14. Estimating Monthly Solar Radiation in South-Central Chile Estimación de Radiación Solar Mensual en la Zona Centro Sur de Chile

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    José Álvarez

    2011-12-01

    Full Text Available Solar radiation is a key component in process-based models. The amount of this energy depends on the location, time of the year, and atmospheric conditions. Several equations and models have been developed for different conditions using historical data from weather station networks or satellite measurements. However, solar radiation estimates are too local since they rely on weather stations or have a resolution that is too coarse when working with satellites. In this study, we estimated monthly global solar radiation for the south-central region of Chile using the r.sun model and validated it with observations from automatic weather stations. We analyzed the performance of global radiation results with the Hargreaves-Samani (HS and Bristow-Campbell (BC models. Estimates from a calibrated rsun model accounted for 89% of the variance (r² = 0.89 in monthly mean values for 15 locations in the research area. The model performed very well for a wide area and conditions in Chile when we compared it with the HS and BC models. Our estimates of global solar radiation using the rsun model could be improved through calibration of ground measurements and more precise cloudiness estimates as they become available. With additional procedures, the rsun model could be used to provide spatial estimates of daily, weekly, monthly, and yearly solar radiation.La radiación solar es un componente clave en los modelos basados en procesos. La cantidad de esta energía depende de la ubicación, época del año, y también de las condiciones atmosféricas. Varias ecuaciones y modelos han sido desarrollados para diferentes condiciones, utilizando datos históricos de las redes de estaciones meteorológicas o de las mediciones por satélite. Sin embargo, las estimaciones de la radiación solar son demasiado locales con estaciones meteorológicas, o con una resolución muy gruesa cuando se trabaja con satélites. En el presente estudio se estimó radiación solar global

  15. Experimental study and mechanism analysis of modified limestone by red mud for improving desulfurization

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hongtao; Han, Kuihua; Niu, Shengli; Lu, Chunmei; Liu, Mengqi; Li, Hui [Shandong Univ., Jinan (China). School of Energy and Power Engineering

    2013-07-01

    Red mud is a type of solid waste generated during alumina production from bauxite, and how to dispose and utilize red mud in a large scale is yet a question with no satisfied answer. This paper attempts to use red mud as a kind of additive to modify the limestone. The enhancement of the sulfation reaction of limestone by red mud (two kinds of Bayer process red mud and one kind of sintering process red mud) are studied by a tube furnace reactor. The calcination and sulfation process and kinetics are investigated in a thermogravimetric (TG) analyzer. The results show that red mud can effectively improve the desulfurization performance of limestone in the whole temperature range (1,073-1,373K). Sulfur capacity of limestone (means quality of SO{sub 2} which can be retained by 100mg of limestone) can be increased by 25.73, 7.17 and 15.31% while the utilization of calcium can be increased from 39.68 to 64.13%, 60.61 and 61.16% after modified by three kinds of red mud under calcium/metallic element (metallic element described here means all metallic elements which can play a catalytic effect on the sulfation process, including the Na, K, Fe, Ti) ratio being 15, at the temperature of 1,173K. The structure of limestone modified by red mud is interlaced and tridimensional which is conducive to the sulfation reaction. The phase composition analysis measured by XRD of modified limestone sulfated at high temperature shows that there are correspondingly more sulphates for silicate and aluminate complexes of calcium existing in the products. Temperature, calcium/metallic element ratio and particle diameter are important factors as for the sulfation reaction. The optimum results can be obtained as calcium/metallic element ratio being 15. Calcination characteristic of limestone modified by red mud shows a migration to lower temperature direction. The enhancement of sulfation by doping red mud is more pronounced once the product layer has been formed and consequently the promoting

  16. Comparative study of porous limestones used in heritage structures in Cyprus and in Hungary

    Science.gov (United States)

    Theodoridou, Magdalini; Ioannou, Ioannis; Rozgonyi-Boissinot, Nikoletta; Török, Ákos

    2015-04-01

    Porous limestone is widely used as construction material in the monuments of Cyprus and Hungary. The present study compares the physical properties of a bioclastic limestone from Cyprus and an oolitic limestone from Hungary. Petra Gerolakkou is a Pliocene limestone from Cyprus that originates from the district of Nicosia, the island's capital. It has been extensively used throughout the years in construction and restoration projects, particularly in the Nicosia area. Distinctive examples of its use can be found in the majority of the most important historic monuments in Nicosia, such as the Venetian walls and fortifications, churches (e.g. the Agia Sofia Cathedral), the archbishop and presidential palaces and a high number of other traditional buildings. The studied Miocene limestone from Hungary was exploited from Sóskút quarry (15-20 km W-SW to Budapest). The quarry provided stone for emblematic monuments of the capital of Hungary such as the Parliament building, Mathias Church, the Opera House and Citadella. In this study, mechanical parameters for both aforementioned stones, such as uniaxial compressive and tensile strengths, were tested under laboratory conditions. Their density, porosity and water absorption were also compared. The studied limestone from Cyprus exhibits porosity values within the range of 48-51%, apparent density between 1340 and 1400 kg/m3 and strength values under uniaxial compressive load between 1.2 and 2.8 MPa. This lithotype is also considered susceptible to salt decay, since an approximate mass loss of 12.5% is noted after 15 salt crystallization artificial weathering cycles. The porosity of the Hungarian limestone is in the order of 16-35%, the bulk density is 1600-1950 kg/m3, while the compressive strength is 2.5-15 MPa. Durability tests indicate that even after 10 freeze-thaw cycles the loss in strength is dramatic. Test results indicate that use of porous limestone in both countries is common and fabric strongly controls the

  17. Nomination of the Globigerina Limestone of the Maltese Islands as a "Global Heritage Stone Resource"

    Science.gov (United States)

    Cassar, JoAnn

    2016-04-01

    The Maltese Islands consist of two main islands, Malta and Gozo, as well as a small number of islets, and lie in the central Mediterranean Sea approximately 90 km south of Sicily. Although only 316 square kilometres in size, the Islands contain a rich concentration of archaeological sites and historic buildings, as well as vernacular architecture and modern buildings, for the most part built of the local Globigerina Limestone, which is one of the few natural resources of the Islands. This stone can be described as a typical "soft limestone", very easy to carve and shape. It forms part of the large family of Oligo-Miocene "soft limestones" widely diffused in the Mediterranean Basin. The Maltese Globigerina Limestone Formation is one of five main Formations, and varies in thickness from 20 to over 200 m. The material used for building is located stratigraphically in the lower part of the Globigerina Limestone Formation, called the Lower Globigerina Limestone. This Formation is stratified into thick beds at outcrop. Sections where bioturbation is concentrated often also occur. This limestone is fine-grained, yellow to pale grey in colour, almost wholly composed of the tests of globigerinid planktonic foraminifera. Petrographically, Globigerina Limestone can be described as a bioclastic packstone, with bioclastic wackestones also occurring. This limestone has always been used as the predominant building material in the Islands. The Maltese prehistoric Temples, which were constructed approximately 6000 years ago, bear testimony to this. Between 1530 and 1798 the Order of the Knights of St John built kilometres of fortifications in this same material to protect the Island from the expanding Ottoman Empire. Fortifications, impressive churches, auberges and palaces were built of this stone during this period. The capital city of Valletta, a rich and dense manifestation of Baroque architecture in Globigerina Limestone, is included on the UNESCO World Heritage List, as are

  18. Studies on the preparation of value-added products for limestone

    Energy Technology Data Exchange (ETDEWEB)

    Chae, Young Bae; Jeong, Soo Bok; Ko, Won Sik; Park, Je Shin; Oh, Jung Whan [Korea Institute of Geology Mining and Materials, Taejon (Korea, Republic of)

    1997-12-01

    Most of limestone in our country was consumed by the cement and iron/steel making industries and the amount of that was up to 72 million ton in 1996. Recently, importation of high grade limestone that have properties of high whiteness and grade are increased with diversification of chemical products and powder as various qualified filler, because high grade limestone are limited and of few deposit in our country. Therefore, the purpose of this study has investigated to raise to high grade by economical processes with low grade of domestic limestone. In this year, first of all, we investigated the status of application utilize and related industries with the domestic limestone, and then being consideration with condition selected the adequate sample from Andong, Jungsun and Kumsan area. Magnetic materials were involved in impurities of sample, so magnetic separation method was applied in elimination of the ferro-magnetic materials and para-magnetic materials, such as chlorite, muscovite, quartz, dolomite, magnetite, feldspar and so on. The limestone sample has many kinds of impurity. Investigation of flotation was undertaken to eliminate impurities from limestone crude ore and the tests were performed to get a optimum condition adding oleic acid as a promoter, sodium silicate and sodium carbonate as a conditioning agents and MIBC as a frother, while to float the sulfide minerals added amyl xanthate as a promoter, and sulfuric acid as a pH regulator. And most of the impurities involving in flotation sink contained such as quartz, chlorite, muscovite, feldspar, dolomite and so on. Selective crushing and classification methods were performed to eliminate impurities depends on the mineral properties and should be the selective crushing methods are very useful at the manufacturing factory of heavy calcium carbonate with the dry milling system. (author). 36 refs., 46 tabs., 33 figs.

  19. Crushed Limestone Dust Valorization for Eco Friendly non Fired Wall Tiles

    Directory of Open Access Journals (Sweden)

    Wangrakdiskul Ubolrat

    2016-01-01

    Full Text Available Utilizing crushed limestone dust; the by-product of crushing limestone plant for producing non-fired wall tiles is the objective of this research. The main raw materials of non-fired wall tiles consist of laterite soil, fluvial sand and Portland cement. The crushed limestone dust has been used as the substitute material of non-fired wall tiles for enhancing their bending strength. In this experiment, four groups of formulas have been constructed. Firstly, crushed limestone dust has been mixed into the basic formula for substitution of laterite soil. Secondly, crushed limestone dust has been used for substitution to river soil of the basic formula. Thirdly, it has been substituted to Portland cement in the basic formula. Finally, the best formulas of the first three groups has been selected and mixed up to make the new formulas. After mixing the raw materials of selected formula, forming specimens by uni-axial pressing at 100 bar has been performed. Then, they have been aged for 1 week at the room temperature. After that, testing the specimens’ properties has been carried out. They are bending strength and water absorption which comparing with Thailand Industrial Standard (TIS 614-2529. The experimental results show that adding the crushed limestone dust to the basic composition has an effect on the bending strength and water absorption. The compositions of the best formula are laterite soil 55%, fluvial sand 7.5%, Portland cement 22.5%, and crushed limestone dust 15%. It gives the bending strength by 2.32 MPa, water absorption 3.20%. The water absorption property can pass the TIS standard, but bending strength could not pass. The estimated cost of raw materials is 0.09065 THB/100 g.

  20. Effects of aquifer storage and recovery activities on water quality in the Little Arkansas River and Equus Beds Aquifer, south-central Kansas, 2011-14

    Science.gov (United States)

    Stone, Mandy L.; Garrett, Jessica D.; Poulton, Barry C.; Ziegler, Andrew C.

    2016-07-18

    The Equus Beds aquifer in south-central Kansas is aprimary water source for the city of Wichita. The Equus Beds aquifer storage and recovery (ASR) project was developed to help the city of Wichita meet increasing current (2016) and future water demands. The Equus Beds ASR project pumps water out of the Little Arkansas River during above-base flow conditions, treats it using drinking-water quality standards as a guideline, and recharges it into the Equus Beds aquifer for later use. Phase II of the Equus Beds ASR project currently (2016) includes a river intake facility and a surface-water treatment facility with a 30 million gallon per day capacity. Water diverted from the Little Arkansas River is delivered to an adjacent presedimentation basin for solids removal. Subsequently, waste from the surface-water treatment facility and the presedimentation basin is returned to the Little Arkansas River through a residuals return line. The U.S. Geological Survey, in cooperation with the city of Wichita, developed and implemented a hydrobiological monitoring program as part of the ASR project to characterize and quantify the effects of aquifer storage and recovery activities on the Little Arkansas River and Equus Beds aquifer water quality.Data were collected from 2 surface-water sites (one upstream and one downstream from the residuals return line), 1 residuals return line site, and 2 groundwater well sites (each having a shallow and deep part): the Little Arkansas River upstream from the ASR facility near Sedgwick, Kansas (upstream surface-water site 375350097262800), about 0.03 mile (mi) upstream from the residuals return line site; the Little Arkansas River near Sedgwick, Kans. (downstream surface-water site 07144100), about 1.68 mi downstream from the residuals return line site; discharge from the Little Arkansas River ASR facility near Sedgwick, Kansas (residuals return line site 375348097262800); 25S 01 W 07BCCC01 SMW–S11 near CW36 (MW–7 shallow groundwater well

  1. Drenov Grič black limestone as a heritage stone from Slovenia

    Science.gov (United States)

    Kramar, Sabina; Rožič, Boštjan; Žbona, Nina; Bedjanič, Mojca; Mladenović, Ana

    2016-04-01

    The limestone known as Drenov Grič black limestone is considered one of the most beautiful Slovenian natural stones due to its homogenous black colour interwoven with white veins. Over the centuries it has been exploited from three major quarries west of Ljubljana, with the main quarry at Drenov Grič playing the primary role in supplying building material for the central parts of Slovenia. All the quarries are currently not active. In the area of Drenov grič, one locality of black limestone is protected - Kuclerjev kamnolom quarry. It has the status of 'valuable natural feature of national importance' and is protected as a natural monument. This well-stratified micritic limestone of Triassic (Carnian) age occurs in 10-80 cm thick beds, with thin marl interlayers. The stone contains abundant fossil bivalves and ostracods. Apart from calcite as the main component, dolomite, quartz, illite/muscovite and pyrite are also present. The limestone is relatively rich in carbonaceous and bituminous organic matter, which is responsible for the black colour of the stone. This component does not have any adverse effect on mechanical and physical characteristics. As the lime¬stone is dense, thus facilitating a good polish, it has been commercially considered as marble. The stone has been widely used in Slovenian monuments, not only in Ljubljana but also in other regions of Slovenia. Many inner and outdoor architectural elements were made of this limestone, particularly in the baroque period, which was known for the extensive use of black limestones also in other European countries. The most significant use of this limestone has been recorded in sculptured portals and altars. Some of the important buildings decorated utilising this stone, are the Ljubljana Cathedral, the St. James's Parish Church, and the Franciscan Church of the Annunciation, all of which are located in Ljubljana, some of them having been declared as cultural monuments of local or national importance. When

  2. Actinobacterial diversity in limestone deposit sites in Hundung, Manipur (India and their antimicrobial activities

    Directory of Open Access Journals (Sweden)

    Salam eNimaichand

    2015-05-01

    Full Text Available Studies on actinobacterial diversity in limestone habitats are scarce. This paper reports profiling of actinobacteria isolated from Hundung limestone samples in Manipur, India using ARDRA as the molecular tool for preliminary classification. A total of 137 actinobacteria were clustered into 31 phylotypic groups based on the ARDRA pattern generated and representative of each group was subjected to 16S rRNA gene sequencing. Generic diversity of the limestone isolates consisted of Streptomyces (15 phylotypic groups, Micromonospora (4, Amycolatopsis (3, Arthrobacter (3, Kitasatospora (2, Janibacter (1, Nocardia (1, Pseudonocardia (1 and Rhodococcus (1. Considering the antimicrobial potential of these actinobacteria, 19 showed antimicrobial activities against at least one of the bacterial and candidal test pathogens, while 45 exhibit biocontrol activities against at least one of the rice fungal pathogens. Out of the 137 actinobacterial isolates, 118 were found to have at least one of the three biosynthetic gene clusters (PKS-I, PKS-II, NRPS. The results indicate that 86% of the strains isolated from Hundung limestone deposit sites possessed biosynthetic gene clusters of which 40% exhibited antimicrobial activities. It can, therefore, be concluded that limestone habitat is a promising source for search of novel secondary metabolites.

  3. Petrography and geochemistry of Paleocene-Eocene limestones in the Ching-dar syncline, eastern Iran

    Institute of Scientific and Technical Information of China (English)

    S. Halimeh Hashemi Azizi; Gholamreza Mirab Shabestari; Ahmadreza Khazaei

    2014-01-01

    The Ching-dar syncline is located to the west of the city of Birjand, in the east of Iran. The ca. 500 m thick studied section at the eastern flank of the syncline contains a sequence of almost continuous shallow-marine limestones that exhibit no major sedimentary breaks or evidence for volcanic activity. Skeletal grains consist of large benthic foraminifera and green algae whereas non-skeletal grains are mostly peloids and intraclasts. They were deposited on a shallow-marine carbonate ramp. The limestones have undergone extensive diagenetic processes with varying intensities, the most important of which are micritization, cementation, compaction (chemical and mechanical), internal filling and stylolitization. Chemical analysis of the limestone samples revealed high calcium and low magnesium content. Major and minor element values were used to determine the original carbonate mineralogy of these lime-stones. Petrographic evidence and elemental values indicate that calcite was the original carbonate mineral in the limestones of the Ching-dar syncline. The elemental composition of the Ching-dar car-bonates also demonstrates that they have stabilized in a meteoric phreatic environment. Variation of Sr/Ca vs. Mn values suggests that diagenetic alteration occurred in an open geochemical system.

  4. Actinobacterial diversity in limestone deposit sites in Hundung, Manipur (India) and their antimicrobial activities.

    Science.gov (United States)

    Nimaichand, Salam; Devi, Asem Mipeshwaree; Tamreihao, K; Ningthoujam, Debananda S; Li, Wen-Jun

    2015-01-01

    Studies on actinobacterial diversity in limestone habitats are scarce. This paper reports profiling of actinobacteria isolated from Hundung limestone samples in Manipur, India using ARDRA as the molecular tool for preliminary classification. A total of 137 actinobacteria were clustered into 31 phylotypic groups based on the ARDRA pattern generated and representative of each group was subjected to 16S rRNA gene sequencing. Generic diversity of the limestone isolates consisted of Streptomyces (15 phylotypic groups), Micromonospora (4), Amycolatopsis (3), Arthrobacter (3), Kitasatospora (2), Janibacter (1), Nocardia (1), Pseudonocardia (1) and Rhodococcus (1). Considering the antimicrobial potential of these actinobacteria, 19 showed antimicrobial activities against at least one of the bacterial and candidal test pathogens, while 45 exhibit biocontrol activities against at least one of the rice fungal pathogens. Out of the 137 actinobacterial isolates, 118 were found to have at least one of the three biosynthetic gene clusters (PKS-I, PKS-II, NRPS). The results indicate that 86% of the strains isolated from Hundung limestone deposit sites possessed biosynthetic gene clusters of which 40% exhibited antimicrobial activities. It can, therefore, be concluded that limestone habitat is a promising source for search of novel secondary metabolites.

  5. Influence of clay swelling on the mechanical behaviour of Egyptian Helwan limestone

    Science.gov (United States)

    Aly, Nevin

    2016-04-01

    Clay minerals exist naturally in the majority of different Egyptian limestones types. Changes in the dimensions of clays during swelling / shrinking process induced by changes in the environmental conditions can result in acceleration the deterioration of the hosting stone. Petrographic investigation by scanning - electron microscope (SEM) of Helwan limestone (biomicritic limestone) revealed distribution of a typical smectite morphology (curled - leaf shape) beside abundance of glauconite pellets within the stone material. The clay frication extracted from Helwan reached 10% and oriented aggregates samples were analyzed by X- ray diffraction (XRD) and confirmed the identification of smectite as the main mineral in the clay frication. To study the effect of the clay content on the mechanical behavior of Helwan limestone, hygric swelling test was performed at first by using displacement sensor and then the effect of multiple wetting/ drying cycles on the stone strength was determined using unconfined compressive strength (UCS). Results revealed that there was a significant correlation between degree of swelling of the clay and strength of the limestone.

  6. High efficiency of heavy metal removal in mine water by limestone

    Institute of Scientific and Technical Information of China (English)

    YAO Zhigang; ZHOU Lifa; BAO Zhengyu; GAO Pu; SUN Xingwang

    2009-01-01

    The removal of Cd, Cu, Ni and Zn from dilute mine water by using several geological materials including pure limestone, sand, carbonaceous limestone and brecciated limestone was performed on a laboratory scale. The results showed that to add geological materials in combination with sodium carbonate injection would notably enhance the efficiency of heavy metal removal to varying degrees. Pure limestone was found the best one among the four materials mentioned above for removing heavy metals from mine water. The removal efficiencies of pure limestone when it is ground as fine as 30-60 meshes are 58.6% for Cd, 100% for Cu, 47.8% for Ni, and 36.8% for Zn at 20℃. The optimum pH is about 8.9 to 9.1. The mechanism of higher effective removal, perhaps, is primarily due to co-precipitation under the control of calcite-related pH value. According to this research, Na2CO3 injection manners, including slug dosing and drip-wise, seemed to have little impact on the efficiency of heavy metal removal.

  7. Impacts of Limestone Multi-particle Size on Production Performance, Egg Shell Quality, and Egg Quality in Laying Hens

    Directory of Open Access Journals (Sweden)

    X. Y. Guo

    2012-06-01

    Full Text Available This experiment was conducted to evaluate the effects of single or multi-particle size limestone on the egg shell quality, egg production, egg quality and feed intake in laying hens. A total of 280 laying hens (ISA brown were used in this 10-wk trial. Laying hens were randomly assigned to 4 treatments with 14 replications per treatment and 5 adjacent cages as a replication (hens were caged individually. The experimental treatments were: i L, basal diet+10% large particle limestone; ii LS1, basal diet+8% large particle limestone+2% small particle limestone; iii LS2, basal diet+6% large particle limestone+4% small particle limestone; iv S, basal diet+10% small particle limestone. The egg production was unaffected by dietary treatments. The egg weight in S treatment was lighter than other treatments (p<0.05. The egg specific gravity in S treatment was lower than other treatments (p<0.05. The eggshell strength and eggshell thickness in S treatment were decreased when compared with other dietary treatments (p<0.05. The laying hens in LS1 and LS2 treatment had a higher average feed intake than the other two treatments (p<0.05. Collectively, the dietary multi-particle size limestone supplementation could be as efficient as large particle size limestone.

  8. Influence of limestone fillers on combustion characteristics of asphalt mortar for pavements

    DEFF Research Database (Denmark)

    Ke, Wu; Kai, Zhu; Wu, Hao;

    2014-01-01

    Asphalt materials will be ignited and release significant toxic fumes within tunnel fires. Thus, combustion characteristics of asphalt materials used in road tunnel should be studied in order to limit such an adverse effect. In the present work we study the influence of limestone fillers...... on combustion characteristics of asphalt mortar by thermogravimetric and kinetic analysis. It is shown that the combustion of asphalt mortar is not just a linear superposition of asphalt and limestone. The limestone will increase the ignition point and the activation energy of the primary volatile release......, and will catalyze the char formation from the primary volatile release. Kinetic analysis shows that the primary volatile release stage of asphalt mortar combustion can be explained by a three-dimensional diffusion model, the secondary volatile release and char combustion stage can be explained by a model under...

  9. BRACHIOPODS FROM THE UPPER TRIASSIC REEF HABITATS OF THE NORTHERN CALCAREOUS ALPS (DACHSTEIN LIMESTONE, HOCHSCHWAB, AUSTRIA

    Directory of Open Access Journals (Sweden)

    MILOS SIBLÍK

    2005-11-01

    Full Text Available Upper Triassic brachiopods from 2 localities in the reef Dachstein Limestone of the SE Hochschwab massif in Styria, Austria are systematically described and illustrated. About 900 variably preserved specimens belong to 28 species, representing thus the most diverse brachiopod fauna known from the North Alpine Dachstein Limestone. This indicates that brachiopods were common inhabitants of reef habitats during the Alpine Norian. Oxycolpella, Sinucosta and Aulacothyropsis are dominant. Seven brachiopod species are known from the Kössen Formation (Rhaetian. Adygella biplicata (Dagys and Ladinian Hungarispira loretzi (Bittner are the newcomers in the Nordalpine Dachstein Limestone. In addition to brachiopods, only some fragments of bivalves were found. Conodonts of the species Epigondolella triangularis (Budurov 1972 indicate the Early Norian age.

  10. Reduction of soil pollution by usingwaste of the limestone in the cement industry

    Science.gov (United States)

    Muñoz, M. Cecilia Soto; Robles Castillo, Marcelo; Blanco Fernandez, David; Diaz Gonzalez, Marcos; Naranjo Lamilla, Pedro; Moore Undurraga, Fernando; Pardo Fabregat, Francisco; Vidal, Manuel Miguel Jordan; Bech, Jaume; Roca, Nuria

    2016-04-01

    In the cement manufacturing process (wet) a residue is generated in the flotation process. This builds up causing contamination of soil, groundwater and agricultural land unusable type. In this study to reduce soil and water pollution 10% of the dose of cement was replaced by waste of origin limestone. Concretes were produced with 3 doses of cement and mechanical strengths of each type of concrete to 7, 28 and 90 days were determined. the results indicate that the characteristics of calcareous residue can replace up to 10% of the dose of cement without significant decreases in strength occurs. It is noted that use of the residue reduces the initial resistance, so that the dose of cement should not be less than 200 kg of cement per m3. The results allow recommends the use of limestone waste since it has been observed decrease in soil and water contamination without prejudice construction material Keywords: Soil contamination; Limestone residue; Adding concrete

  11. Modelling of Limestone Dissolution in Wet FGD Systems: The Importance of an Accurate Particle Size Distribution

    DEFF Research Database (Denmark)

    Kiil, Søren; Johnsson, Jan Erik; Dam-Johansen, Kim

    1999-01-01

    In wet flue gas desulphurisation (FGD) plants, the most common sorbent is limestone. Over the past 25 years, many attempts to model the transient dissolution of limestone particles in aqueous solutions have been performed, due to the importance for the development of reliable FGD simu-lation tools...... suspended in a liquid solution. The measured PSDs were sensitive to the addition of a dispersing agent, the dispersion time, and the presence of ultrasound. It was found that the different PSDs influenced the simulated rate of dis-solution significantly (i.e. from below to above the measured dissolution...... rate). The results of this work show that a representative PSD is essential in order to model the rate of dissolution of lime-stone particles accurately....

  12. High Resolution Hydraulic Profiling and Groundwater Sampling using FLUTe™ System in a Fractured Limestone Setting

    DEFF Research Database (Denmark)

    Janniche, Gry Sander; Christensen, Anders G.; Grosen, Bernt;

    innovative investi-gation methods for characterization of the source zone hydrogeology and contamination, including FLUTe system hydraulic profiling and Water-FLUTe multilevel groundwater sampling, in fractured bryo-zoan limestone bedrock. High resolution hydraulic profiling was conducted in three cored......Characterization of the contaminant source zone architecture and the hydraulics is essential to develop accurate site specific conceptual models, delineate and quantify contaminant mass, perform risk as-sessment, and select and design remediation alternatives. This characterization is particularly...... challeng-ing in deposit types as fractured limestone. The activities of a bulk distribution facility for perchloroe-thene (PCE) and trichloroethene (TCE) at the Naverland site near Copenhagen, Denmark, has resulted in PCE and TCE DNAPL impacts to a fractured clay till and an underlying fractured limestone...

  13. Soil-gas diffusivity fingerprints of the dual porosity system in fractured limestone

    DEFF Research Database (Denmark)

    Claes, Niels; Chamindu, D.T.K.K.; Jensen, Jacob Birk;

    2010-01-01

    The presence of fractured vadose zones (e.g., limestone or clay tills) may potentially pose significant environmental concerns due to the rapid, preferential migration of gaseous plumes through interconnected pore networks. However, recent modelling studies related to fractured vadose zone...... processes are mostly limited to hydrogeological (water and solute) transport studies with very poor attention to the gaseous phase transport studies (Kristensen et al. 2010). This study characterizes fractured limestone soils for gas diffusion based on three different gas diffusivity fingerprints. The first...... fingerprint is a two-parameter exponential model, which mainly describes the gas diffusivity in the limestone matrix while taking both fracture connectivity and matrix pore connectivity into account. With the second fingerprint, we make a close observation of the tortuous matrix pore network by means...

  14. Microfacies and diagenesis of Gua Bama limestone, Pahang Darul Makmur, Malaysia

    Science.gov (United States)

    Joeharry, Nelisa Ameera Mohamed; Ali, Che Aziz; Leman, Mohd Shafeea; Mohamed, Kamal Roslan

    2016-11-01

    Gua Bama limestone hill in Lipis District, Pahang State is a well-known site for the hunt of Malaysian Permo-Triassic Boundary. This paper details the microfacies and diagenesis of limestone succession at Gua Bama outcrop as an early effort to constrain the desired Permo-Triassic Boundary. Six microfacies have been identified: mudstone, peloidal wackestone, bioclastic wackestone, radiolarian wackestone, intraclastic packstone, and peloidal packstone. The appearance of highly diverse benthic fauna in fragmented forms and the dominance of mudstone-wackestone microfacies prove that carbonates of Gua Bama were deposited in low-energy shallow marine environment. Gua Bama have been subjected to multiple diagenetic processes, namely cementation, compaction, neomorphism, and micritization. Based on diagenetic textures observed, it can be interpreted that Gua Bama limestone had undergone diagenesis within marine water phreatic zone and deep burial realms.

  15. Impacts of Limestone Particle Size on the Performance of Flexible Wood Fiber Composite Floor

    Directory of Open Access Journals (Sweden)

    Hongcheng He

    2015-01-01

    Full Text Available Sustainable wood floor (WFF, produced from natural plants, is a sort of novel green and ecofriendly composite floor, which has been attracting more and more attention in the world. WFF also gives a solution of utilizations of agricultural wastes, such as bamboo mats and hemp hurd. The additive limestone powder plays key role in the performance of flexible bamboo composite floor, so, in this paper, the effects of limestone size and size distributions were investigated. The best particle size distributions of limestone are 25 wt% of 48 μm, 25 wt% of 106 μm, and 50 wt% of 160 μm. The as-obtained WFF has good elasticity, good affinity, and strong comfortableness as well as free formaldehyde release.

  16. A NEW DAONELLA FROM THE LADINIAN PLATFORM OF THE ESINO LIMESTONE (SOUTHERN ALPS, ITALY

    Directory of Open Access Journals (Sweden)

    CRISTIANO LARGHI

    2006-03-01

    Full Text Available The bivalve Daonella Mojsisovics, 1874 is very common in the Middle Triassic pelagic facies, whereas the record of this genus from shallow water limestones is rare. In the present paper a new species of Daonella, named D. pseudograbensis, is described from the Esino Limestone, a Ladinian (Middle Triassic carbonate platform in the central Southern Alps. The species is described from Brembana Valley, where the Esino Limestone is rather rich in bioclastic lenses yielding faunas with bivalves, cephalopods, gastropods, brachiopods, corals and calcareous algae. Daonella pseudograbensis n. sp. is based on very well preserved specimens, which are often articulated and closed, all coming from the same locality. The new species shows a narrow range of intraspecific and ontogenetic morphologic variations. It is easy distinguishable from the other species of the genus for the outline and ornamentation; it therefore differs from D. grabensis Kittl, 1912, the most similar species, for the longer anterior dorsal margin.Pdf

  17. Numerical modelling of the effect of weathering on the progressive failure of underground limestone mines

    CERN Document Server

    Ghabezloo, Siavash

    2008-01-01

    The observations show that the collapse of underground limestone mines results from a progressive failure due to gradual weathering of the rockmass. The following stages can be considered for the limestone weathering and degradation process in underground mines: condensation of the water on the roof of the gallery, infiltration of water in the porous rock, migration of the air CO2 molecules in the rock pore water by convection and molecular diffusion, dissolution of limestone by CO2 rich water and consequently, reduction of the strength properties of rock. Considering this process, a set of equations governing different hydrochemo-mechanical aspects of the weathering phenomenon and progressive failure occurring in these mines is presented. Then the feasibility of numerical modelling of this process is studied and a simple example of application is presented.

  18. Mensuration of microstructure multi-fractal spectra of calcined limestone particle surfaces

    Institute of Scientific and Technical Information of China (English)

    Jianyu Shang; Songling Wang; Chunbo Wang; Chunchang Song

    2010-01-01

    The microstructure of the surface of a calcined limestone particle is multi-fractal.We develop an analytic method that surveys the boundary curve multi-fractal dimensions with SEM,gets a three-dimensional surface structure α-f(α)curve via zero-sets,and finally calculates the multi-fractal spectrum values of the particle surface's microstructural topography.After analyzing two spectra from limestone particles calcined at 850 ℃ and 900 ℃,it was shown that the microstructural topographies of the surfaces of calcined limestone multi-particle system have some degree of self-similarity.This mensuration method is proposed to describe the multi-fractal characteristics of a micro-scale particle's surface topography.

  19. Geological investigations of the sites of lithothamnian limestone in the area between Brezno and Savinja

    Directory of Open Access Journals (Sweden)

    Ivan Strgar

    2003-12-01

    Full Text Available In the area between Brezno and Savinja, detailed geological investigations and geological prospecting of ten lithothamnian limestone deposits were carried out according to the program of investigations in 1991 and 1992. Those sites were:• In the north, partly in the extraction area of former Laško colliery, with deposits Brezno – Bezoviški hrib, west of Gornje Brezno, between Gornje Brezno and Govce, Govškihrib, Trnov hrib, between Liša shaft and Barbara level, between Barbara level and Konjušnica, Brdo and Podšmihel. Western sites lie in the area belonging to the Hrastnik Municipality, but mostly in the area belonging to the La{ko Municipality• In the south the area of Turski les, which belongs to the Hrastnik MunicipalityThe objective of the investigations was to establish reserves and resources of lithothamnian limestone for the purposes of construction industry. The limestone should be extracted according to a special program of substitutional activities after the Laško minewill be closed. In the area Brezno – Brezoviški hrib detailed geological investigations were made, while in other nine areas only geological prospecting and assessment of the resources of lithothamnian limestone were carried out.Each of the investigated areas was assessed from the point of view of natural and economic indicators, such as: quantity of reserves and resources of lithothamnian limestone with preliminary evaluation of quality, usability, access and urban parts, possible impactson narrow and wide surroundings, environment and usability of rock and aggregate.The results of the investigations pointed out three deposits as potentially interesting and perspective: between the Barbara shaft and Konju{nica, Brdo and Turski les. Other deposits were classified either as deposits with limited reserves and resources of lithothamnian limestone, or as non-perspective due to different limitations.

  20. Modelling of catalytic oxidation of NH3 and reduction of NO on limestone during sulphur capture

    DEFF Research Database (Denmark)

    Kiil, Søren; Bhatia, Suresh K.; Dam-Johansen, Kim

    1996-01-01

    for the catalytic chemistry of NH3 during simultaneous sulphur capture on a Stevns Chalk particle. The reduction of NO by NH3 over CaSO4 (which is the product of the reaction between SO2, O2 and limestone) was found to be important because this reaction could explain the change in selectivity with increased solid...... conversion observed experimentally. Simulations also suggested that it may be advantageous with respect to the emission of NO to use smallinstead of big limestone particles for desulphurisation in fluidised bed combustors due to the ways different sized particles capture SO2....

  1. Accelerated weathering of limestone for CO2 mitigation: Opportunities for the stone and cement industries

    Science.gov (United States)

    Langer, William H.; San, Juan A.; Rau, Greg H.; Caldeira, Ken

    2009-01-01

    Accelerated weathering of limestone appears to provide a low-tech, inexpensive, high-capacity, environmentally friendly CO2 mitigation method that could be applied to about 200 fossil fuel fired power plants and about eight cement plants located in coastal areas in the conterminous U.S. This approach could also help solve the problem of disposal of limestone waste fines in the crushed stone industry. Research and implementation of this technology will require new collaborative efforts among the crushed stone and cement industries, electric utilities, and the science and engineering communities.

  2. Discrimination of moist oil shale and limestone using laser induced breakdown spectroscopy

    Science.gov (United States)

    Paris, P.; Piip, K.; Lepp, A.; Lissovski, A.; Aints, M.; Laan, M.

    2015-05-01

    Laser-induced plasma emission spectra of Estonian oil shale and associated limestone with varying moisture content were studied. Time gated spectra excited by 1064 nm laser radiation were recorded. Spectral lines for determination of plasma parameters were selected. Moisture causes the reduction of the intensity of the total emission, and increases the intensity of the Hα line. It was found that the effect of the moisture content on the plasma temperature and electron concentration was inconsiderable. Using the ratio of intensities of Hα and Mg spectral lines, it was possible to distinguish reliably between limestone and oil shale independently of their moisture content.

  3. Hydration of Blended Portland Cements Containing Calcium-Aluminosilicate Glass Powder and Limestone

    DEFF Research Database (Denmark)

    Moesgaard, M; Poulsen, Søren Lundsted; Herfort, D;

    2012-01-01

    M. MOESGAARD, S.L. POULSEN, D. HERFORT, M. STEENBERG, L.F. KIRKEGAARD, J. SKIBSTED, Y. YUE, Hydration of Blended Portland Cements Containing Calcium-Aluminosilicate Glass Powder and Limestone, Journal of the American Ceramic Society 95, 403 – 409 (2012).......M. MOESGAARD, S.L. POULSEN, D. HERFORT, M. STEENBERG, L.F. KIRKEGAARD, J. SKIBSTED, Y. YUE, Hydration of Blended Portland Cements Containing Calcium-Aluminosilicate Glass Powder and Limestone, Journal of the American Ceramic Society 95, 403 – 409 (2012)....

  4. Modelling of Limestone Dissolution in Wet FGD Systems: The Importance of an Accurate Particle Size Distribution

    DEFF Research Database (Denmark)

    Kiil, Søren; Johnsson, Jan Erik; Dam-Johansen, Kim

    1999-01-01

    In wet flue gas desulphurisation (FGD) plants, the most common sorbent is limestone. Over the past 25 years, many attempts to model the transient dissolution of limestone particles in aqueous solutions have been performed, due to the importance for the development of reliable FGD simu-lation tools....... In this work, a critical examination of the models was conducted. The survey revealed that the models rely on the use of adjustable parameters in order to match experimental data. To investigate this, a simple particle model was set up. Model predictions were compared to experi-mental data for three different...

  5. Investigations of a Cretaceous limestone with spectral induced polarization and scanning electron microscopy

    DEFF Research Database (Denmark)

    Johansson, Sara; Sparrembom, Charlotte; Fiandaca, Gianluca

    2017-01-01

    in early time ranges for bedrock characterization. The inverted sections showed variations within the limestone that could be caused by variations in texture and composition. Samples from a deep drilling in the Kristianstad basin were investigated with scanning electron microscopy and energy dispersive X...... in the texture of the limestone at different levels, governed by fossil shapes and composition, proportions of calcareous cement and matrix as well as amount of silicate grains. Textural variations may have implications on the variation in Cole–Cole relaxation time and frequency factor. However, more research...

  6. THE NUSPLINGEN LITHOGRAPHIC LIMESTONE - A "FOSSIL LAGERSTAETTE" OF LATE KIMMERIDGIAN AGE FROM THE SWABIAN ALB (GERMANY

    Directory of Open Access Journals (Sweden)

    GERD DIETL

    2004-03-01

    Full Text Available A short overview is given on the actual excavations within a fossiliferous lithographic limestone site near Nusplingen (western Swabian Alb, SW Germany. In contrast to the better known Early Tithonian Solnhofen Lithographic Limestone, it is much richer in fossils and 0.5 my older (Late Kimmeridgian, Beckeri Zone, Ulmense Subzone. Many of the fossils exhibit an excellent preservation, sometimes even of the organic matter. More than 7.000 specimens have been recorded belonging to almost 300 taxa (plants, microfossils, invertebrates, ichnofossils, and vertebrates.

  7. Basalt-Limestone and Andesite-Limestone Interaction in the Arc Crust - Implications for Volcanic Degassing of CO2

    Science.gov (United States)

    Carter, L. B.; Dasgupta, R.

    2014-12-01

    Volcanically emitted CO2 is generally mantle-derived, but high degassing rates at some arcs (e.g. Merapi [1] and Colli Albani Volcanic District [2]) are thought to be affected by magma-carbonate interaction in the upper plate. However, the effects of depth, temperature, and composition on this process are poorly known. We experimentally simulated magma (50%)-limestone (50%) wallrock interactions at 0.5-1.0 GPa, 1100-1200 °C using pure calcite and a hydrous (~3-5 wt.% H2O) melt (basalt, andesite, or dacite). At 1.0 GPa, 1200 °C starting melts are superliquidus, whereas in the presence of calcite, Ca-rich cpx ± Ca-scapolite are produced. With increasing T, basalt-calcite interaction causes the melt, on a volatile-free basis, to become silica-poor and Ca-rich with alumina decreasing as cpx becomes more CaTs-rich. The same trend is seen with all starting melt compositions as P decreases at a constant T (1200 °C), producing melts similar to ultracalcic (CaO/Al2O3>>1) melt inclusions found in arc settings. Shifting from basalt to andesite has little effect on SiO2 and CaO of the reacted melt (e.g. 37 wt.% SiO2, 42 wt.% CaO at 0.5 GPa, 1200 °C), whereas Al2O3 of andesite-derived reacted melt is lower, likely a result of lower alumina in the starting andesite. Wall-rock calcite consumption is observed to increase with increasing T, decreasing P, and increasing melt XSiO2. At 0.5 GPa between 1100 and 1200 °C, our basalt experiments yield carbonate assimilation from 22 to 48 wt.%. This decreases to 20 wt.% at 1.0 GPa, 1200 °C, whereas an andesitic composition assimilates 59 to 52 wt.% from 0.5 to 1.0 GPa at 1200 °C. The higher assimilation in andesite-added runs at high-T is because of lower silicate liquidus as evidenced by lower modal proportion or absence of cpx ± scapolite. Using a magma flux rate estimated for Mt. Vesuvius [3], we obtain a CO2 outflux for a single such volcano experiencing arc magma-calcite reaction [4] of at least 2-4% of the present

  8. Borehole geophysical, fluid, and hydraulic properties within and surrounding the freshwater/saline-water transition zone, San Antonio segment of the Edwards aquifer, south-central Texas, 2010-11

    Science.gov (United States)

    Thomas, Jonathan V.; Stanton, Gregory P.; Lambert, Rebecca B.

    2012-01-01

    The freshwater zone of the San Antonio segment of the Edwards aquifer is used by residents of San Antonio and numerous other rapidly growing communities in south-central Texas as their primary water supply source. This freshwater zone is bounded to the south and southeast by a saline-water zone with an intermediate zone transitioning from freshwater to saline water, the transition zone. As demands on this water supply increase, there is concern that the transition zone could potentially move, resulting in more saline water in current supply wells. Since 1985, the U.S. Geological Survey (USGS), San Antonio Water System (SAWS), and other Federal and State agencies have conducted studies to better understand the transition zone.

  9. Specialized consulting in radiological safety to the south central hospital of high specialty, PEMEX. VI. December of 2001; Asesoria especializada en seguridad radiologica al hospital central sur de alta especialidad. PEMEX. VI. Diciembre de 2001

    Energy Technology Data Exchange (ETDEWEB)

    Angeles C, A.; Vizuet G, J.; Benitez S, J.A.; Garcia A, J.; Rodriguez A, F. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2002-01-15

    It is a report of a specialized consulting in radiological safety that to be carried the ININ to PEMEX for the South Central Hospital of High Specialty, to maintain the sanitary license for the use of X-ray equipment of medical diagnostic, and guarantee these services with a program of quality assurance. To give fulfilment to that requests it is programmed a technical assistance monthly, with reports of results during the development of the service. In this document it is carried a report of the advances and results in the month of december of the 2001, where the following documents are analyzed: Manual of radiological safety, program of quality assurance, operation procedures, procedure of maintenance team, procedure of medical radiological control of the specialized personnel; also are annotate the obtained results and their observations. (Author)

  10. Effects of aquifer storage and recovery activities on water quality in the Little Arkansas River and Equus Beds Aquifer, south-central Kansas, 2011–14

    Science.gov (United States)

    Stone, Mandy L.; Garrett, Jessica D.; Poulton, Barry C.; Ziegler, Andrew C.

    2016-07-18

    The Equus Beds aquifer in south-central Kansas is aprimary water source for the city of Wichita. The Equus Beds aquifer storage and recovery (ASR) project was developed to help the city of Wichita meet increasing current (2016) and future water demands. The Equus Beds ASR project pumps water out of the Little Arkansas River during above-base flow conditions, treats it using drinking-water quality standards as a guideline, and recharges it into the Equus Beds aquifer for later use. Phase II of the Equus Beds ASR project currently (2016) includes a river intake facility and a surface-water treatment facility with a 30 million gallon per day capacity. Water diverted from the Little Arkansas River is delivered to an adjacent presedimentation basin for solids removal. Subsequently, waste from the surface-water treatment facility and the presedimentation basin is returned to the Little Arkansas River through a residuals return line. The U.S. Geological Survey, in cooperation with the city of Wichita, developed and implemented a hydrobiological monitoring program as part of the ASR project to characterize and quantify the effects of aquifer storage and recovery activities on the Little Arkansas River and Equus Beds aquifer water quality.Data were collected from 2 surface-water sites (one upstream and one downstream from the residuals return line), 1 residuals return line site, and 2 groundwater well sites (each having a shallow and deep part): the Little Arkansas River upstream from the ASR facility near Sedgwick, Kansas (upstream surface-water site 375350097262800), about 0.03 mile (mi) upstream from the residuals return line site; the Little Arkansas River near Sedgwick, Kans. (downstream surface-water site 07144100), about 1.68 mi downstream from the residuals return line site; discharge from the Little Arkansas River ASR facility near Sedgwick, Kansas (residuals return line site 375348097262800); 25S 01 W 07BCCC01 SMW–S11 near CW36 (MW–7 shallow groundwater well

  11. Lithofacies and Petrophysical Properties of Portland Base Bed and Portland Whit Bed Limestone as Related to Durability

    NARCIS (Netherlands)

    Dubelaar, C.W.; Engering, S.; Van Hees, R.P.J.; Koch, R.; Lorenz, H.G.

    2003-01-01

    This study focuses on the differences in lithofacies and petrophysical properties of Base Bed and Whit Bed Portland limestone and the presumed relationships between these characteristics and the durability of this building stone. As Portland limestone probably will be used as a stone for several res

  12. Lithofacies and petrophysical properties of Portland Base Bed and Portland Whit Bed limestone as related to durability

    NARCIS (Netherlands)

    Dubelaar, C.W.; Engering, S.; Hees, R.P.J. van; Koch, R.; Lorenz, H.G.

    2003-01-01

    This study focuses on the differences in lithofacies and petrophysical properties of Base Bed and Whit Bed Portland limestone and the presumed relationships between these characteristics and the durability of this building stone. As Portland limestone probably will be used as a stone for several res

  13. Kinetics of the direct sulfation of limestone at the initial stage of crystal growth of the solid product

    DEFF Research Database (Denmark)

    Hu, Guilin; Dam-Johansen, Kim; Wedel, Stig

    2011-01-01

    The direct sulfation of limestone was studied in a quartz bench scale fixed‐bed reactor with the technique of data deconvolution. The obtained results show that the direct sulfation of limestone has a two‐period kinetic behavior: a short initial sulfation period with high but fast decreasing...

  14. Lightweight concrete with Algerian limestone dust. Part II: study on 50% and 100% replacement to normal aggregate at timely age

    Directory of Open Access Journals (Sweden)

    S. Kitouni

    2015-12-01

    Full Text Available Abstract A control lightweight concrete (LWC mixture made with 50% and 100% of limestone as a replacement of coarse aggregates in weight was prepared. Limestone is used for economical and environmental concern. The concrete samples were cured at 65% relative humidity at 20 ºC. The compressive and flexural tensile strengths, elastic modulus and Poisson's ratio of hardened concrete were measured. Laboratory compressive and tensile strength tests results showed that LWC can be produced by the use of limestone. The aim of this study is twofold: one is to design a lightweight concrete with the use of limestone that will provide an advantage of reduction in dead weight of a structure; and second is to obtain a more economical LWC mixture with the use of limestone.

  15. Studies of the possibility of hydrogen sulfide absorption by limestones during the gasification of liquid and solid fuels

    Energy Technology Data Exchange (ETDEWEB)

    Hrncir, J.; Biba, V.

    1980-01-01

    When solid or liquid fuels such as coal or oil are gasified with air, the fuel gases produced can contain substantial amounts of sulfur. One possible way to remove this sulfur and thus purify the gas is to use limestone in a fluidized bed to absorb the sulfur as hydrogen sulfide. A study of the feasibility of such a process examined the kinetics of the CaO-H/sub 2/S reaction in a differential kinetic reactor in the 1290/sup 0/-1650/sup 0/F temperature range. The investigation (1) tested the reactivity of four natural limestones, (2) evaluated the experimental data via the M. Pell model, (3) examined the effects of the structural parameters of the limestones and the limestone calcinates upon the reaction with hydrogen sulfide, and (4) for one type of limestone, determined the dependence of its reactivity on a specific surface and described this dependence by a mathematical model.

  16. Biological iron(II) oxidation as pre-treatment to limestone neutralisation of acid water

    CSIR Research Space (South Africa)

    Maree, JP

    1998-01-01

    Full Text Available Iron (II) should be oxidised to iron (III) before the neutralisation of acid water with limestone, otherwise the oxidation will occur downstream of the neutralisation plant with the formation of acid (reactions 1 and 2). This study aimed...

  17. Hydrology of the cavernous limestones of the Mammoth Cave area, Kentucky

    Science.gov (United States)

    Brown, Richmond F.

    1966-01-01

    The Mammoth Cave National Park in central Kentucky offers a unique opportunity to study the occurrence of ground water in limestone under natural conditions. Ground water occurs as perched and semiperched bodies in alternate sandstone, shale, and limestone formations and under water-table conditions at the approximate level of the Green River in thick soluble limestone. Three continuous recorders that operated for 5 years indicate that precipitation on the Mammoth Cave plateau recharges the underlying sandstone rapidly. Ground water from the sandstone discharges horizontally to the edges of the plateau and vertically to underlying formations. Some of the precipitation recharges underlying formations almost immediately through overland flow to sinkholes and free fall through open shafts to pools at the water table. Much of the precipitation on the Pennyroyal plain flows overland into sinkholes and then through solution openings to the Green River. Water from the Green River flows into limestone solution channels under Mammoth Cave plateau at some stages, and this water discharges again to the Green River downstream. The presence of salt water, high in chloride in the Green River, makes it possible to trace the movement of the river water through the underground streams. Graphs show relationships of chloride concentration, stage of the Green River, time, precipitation, ground-water levels, and stratigraphy.

  18. Attrition of limestones by impact loading in fluidized beds: The influence of reaction conditions

    Energy Technology Data Exchange (ETDEWEB)

    Scala, Fabrizio [Istituto di Ricerche sulla Combustione, Consiglio Nazionale delle Ricerche, Napoli (Italy); Salatino, Piero [Istituto di Ricerche sulla Combustione, Consiglio Nazionale delle Ricerche, Napoli (Italy); Dipartimento di Ingegneria Chimica, Universita degli Studi di Napoli Federico II, Napoli (Italy)

    2010-09-15

    The extent of attrition associated with impact loading was studied for five different limestones pre-processed in fluidized bed under different reaction conditions. The experimental procedure was based on the measurement of the amount and the particle size distribution of the debris generated upon impact of sorbent samples against a target at velocities between 10 and 45 m/s. The effect of calcination, sulfation and calcination/re-carbonation on impact damage was assessed. Fragmentation by impact loading of the limestones was significant and increased with the impact velocity. Lime samples displayed the largest propensity to undergo impact damage, followed by sulfated, re-carbonated and raw limestones. Fragmentation of the sulfated samples followed a pattern typical of the failure of brittle materials. On the other hand, the behaviour of lime samples better conformed to a disintegration failure mode, with extensive generation of very fine fragments. Raw limestone and re-carbonated lime samples followed either of the two patterns depending on the sorbent nature. The extent of particle fragmentation increased after multiple impacts, but the incremental amount of fragments generated upon one impact decreased with the number of successive impacts. (author)

  19. Soft-sediment ichnotaxa from the Cenozoic White Limestone Group, Jamaica, West Indies

    NARCIS (Netherlands)

    Blissett, D.J.; Pickerill, R.K.

    2004-01-01

    Jamaica, the third largest of the Greater Antillean islands, exposes various lithological units that are dominated by Cenozoic carbonate rocks including those of the mid-Cenozoic White Limestone Group. This Group is comprised of six formations, the Troy, Swanswick, Somerset, Moneague, Montpelier and

  20. Decomposition and reduction of N2O over Limestone under FBC Conditions

    DEFF Research Database (Denmark)

    Johnsson, Jan Erik; Jensen, Anker; Vaaben, Rikke;

    1997-01-01

    The addition of limestone for sulfur retention in FBC has in many cases been observed to influence the emission of N2O. The catalytic activity of N2O over calcined Stevns Chalk for decomposition of N2O in a laboratory fixed bed quartz reactor was measured. It was found that calcined Stevns Chalk ...

  1. Decomposition and Reduction of N2O over Limestone under FBC Conditions

    DEFF Research Database (Denmark)

    Johnsson, Jan Erik; Jensen, Anker; Vaaben, Rikke;

    1997-01-01

    The addition of limestone for sulfur retention in fluidized bed combustion (FBC) has in many cases been observed to influence the emission of N2O. The catalytic activity of N2O over calcined Stevns Chalk for decomposition of N2O in a laboratory fixed bed quartz reactor was measured. It was found...

  2. Anisotropic Variation Law of Rock Permeability with the Burial Depth of Limestone

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Permeability tensors of both macrofracture and microfracture systems were measured progressively along the depth of limestone formations at severed sites. It was found that the principal permeability values Kx, Ky and Kz in these permeability tensors all decrease simultaneously and logarithmically with depth. However, the limestone aquifers are composed of an upper region where the larger permeability ellipsoid is upright or prolate and characterized by Kz>Kx and Kz>Ky, a transitional zone, and a lower zone whose smaller permeability ellipsoid is horizontal or oblate and characterized by Kz<Kx and Kz<Ky. The inversion of the permeability ellipsoids in direction indicates that the anisotropy of rock permeability with the depth of limestone formations has evidently changed. The anisotropic variation law of permeability tensors in a macrofracture system displays a similar pattern with that in a microfracture system. It is next to impossible to examine the rock permeability tensor of the aquifer just by measuring the hydraulic parameters of macrofracture system directly, unless the limestone aquifer is exposed on or near the earth's surface. Therefore, the permeability tensors of a macrofracture system at any depth may be indirectly and roughly determined from the gaugeable permeability tensors of the microfracture system by conversion. This anisotropic variation law of rock permeability with depth is of great significance in the study of three-dimensional fracture water flow the huge carbonate formations and in the research on the conditions of karst development and karst distribution.

  3. Modification of water transfer properties on historical limestones induced by bio-calcification treatment

    OpenAIRE

    Rozenbaum, Olivier; Rouet, Jean-Louis

    2013-01-01

    The effects of a bio-treatment on limestone (here tuffeau) is measured over a large number of dryingimbibition cycles. A model based on a space-dependent permeability coefficient is proposed. It leads to a non-linear diffusion model which accounts for the deviation from the standard Washburn model.

  4. Performance Monitoring: Evaluating an Organic Carbon-Limestone PRB for Treatment of Heavy Metals and Acidity

    Science.gov (United States)

    Since 2004, researchers from the U.S. EPA National Risk Management Research Laboratory (NRMRL) have annually evaluated performance of an organic carbon-limestone permeable reactive barrier (PRB) system installed in 2003 by EPA Region 6 at the Delatte Metals Superfund site in Ponc...

  5. Study on Dynamic Mechanical Properties of Limestone under Uniaxial Impact Compressive Loads

    Directory of Open Access Journals (Sweden)

    Fei Zou

    2016-01-01

    Full Text Available The dynamic mechanical properties of limestone are studied with 5 types of impact pressure acting on limestone samples in axial direction in this paper. The rubber shaper with a diameter of 5 mm and thickness of 2 mm is adopted. Besides the conical punch of split pressure bar of Hopkinson with a diameter of 50 mm is also used. The half-sinusoid pulse is obtained by using the pulse shaper method and special punch method; the constant strain rate deformation of the sample is realized. Dynamic compressive properties and failure modes of limestone under different impact pressure are investigated. In addition, energy dissipation is studied in the process of experiment. The results show that the dynamic compressive strength of limestone has an exponent relation to strain rate. The failure strain, degree of fragmentation, incident energy, and absorption energy increase, while the energy absorbency decreases with the increasing of strain rate. However, the initial elastic modulus is not sensitive to the strain rate. The research method and conclusions have reference value for the dynamic mechanical properties of other brittle materials.

  6. Facies development and paleoenvironment of the Hajajah Limestone Member, Aruma Formation, central Saudi Arabia

    Science.gov (United States)

    El-Sorogy, Abdelbaset S.; Ismail, Abdelmoneim; Youssef, Mohamed; Nour, Hamdy

    2016-12-01

    The Campanian Hajajah Limestone Member of the Aruma Formation was formed during two regressive episodes. Each of them formed of three depositional facies, from base to top: 1) intra-shelf basin facies, made up of fossiliferous green shale and mudstone with ostracods and badly preserved foraminifers. 2) fore-reef facies, consists of hard, massive, marly coralline limestone. The upper part is rich with low divers, badly to moderate preserved, solitary and colonial corals, and, 3) back reef and near-shore facies, consists of fossiliferous sandy dolomitized, bioturbated limestone with abundant reworked corals, bivalves, gastropods, and aggregate grains. On the basis of field observations, micro-and macrofossils and microfacies analysis, the Hajajah Limestone Member was deposited in distal marine settings below storm wave base in a low-energy environment changed upward to fore-reef framework in an open marine environment with moderate to high energy conditions and terminated with shallow marine facies with accumulation of skeletal grains by storms during regression.

  7. Electrochemical desalination of salt infected limestone masonry of a historic warehouse

    DEFF Research Database (Denmark)

    Ottosen, Lisbeth M.; Christensen, Iben Vernegren; Rörig-Dalgaard, Inge

    2012-01-01

    plant for electrochemical desalination, a method where the driving force is an applied electrical potential. The test plant covered about 25 m2 surface of a limestone wall of a historic warehouse. It consisted of 72 electrode units which were placed in two rows; the one above the other and the mutual...

  8. Primulina beiliuensis var. fimbribracteata (Gesneriaceae, a New Variety in A Limestone Cave from Northern Guangdong, China

    Directory of Open Access Journals (Sweden)

    Bi-Dan Lai

    2015-03-01

    Full Text Available Primulina beiliuensis var. fimbribracteata F. Wen & B.D. Lai, a new variety of Gesneriaceae from a limestone cave in Shaoguan, Guangdong, China, is described and illustrated in this report. This new species is similar to P. beiliuensis B. Pan & S.X. Huang var. beiliuensis, but easily differs from the type variety in several morphological characters, both vegetative and reproductive.

  9. Effects of limestone petrography and calcite microstructure on OPC clinker raw meals burnability

    Science.gov (United States)

    Galimberti, Matteo; Marinoni, Nicoletta; Della Porta, Giovanna; Marchi, Maurizio; Dapiaggi, Monica

    2016-12-01

    Limestone represents the main raw material for ordinary Portland cement clinker production. In this study eight natural limestones from different geological environments were chosen to prepare raw meals for clinker manufacturing, aiming to define a parameter controlling the burnability. First, limestones were characterized by X-Ray Fluorescence, X-Ray Powder Diffraction and Optical Microscopy to assess their suitability for clinker production and their petrographic features. The average domains size and the microstrain of calcite were also determined by X-Ray Powder Diffraction line profile analysis. Then, each limestone was admixed with clay minerals to achieve the adequate chemical composition for clinker production. Raw meals were thermally threated at seven different temperatures, from 1000 to 1450 °C, to evaluate their behaviour on heating by ex situ X-Ray Powder Diffraction and to observe the final clinker morphology by Scanning Electron Microscopy. Results indicate the calcite microstrain is a reliable parameter to predict the burnability of the raw meals, in terms of calcium silicates growth and lime consumption. In particular, mixtures prepared starting from high-strained calcite exhibit a better burnability. Later, when the melt appears this correlation vanishes; however differences in the early burnability still reflect on the final clinker composition and texture.

  10. Treatment Of Metal-Mine Effluents By Limestone Neutralization And Calcite Co-Precipitation

    Science.gov (United States)

    The U.S. Geological Survey - Leetown Science Center and the Colorado School of Mines have developed a remediation process for the treatment of metals in circumneutral mining influenced waters. The process involves treatment with a pulsed limestone bed (PLB) system, followed by c...

  11. Treatment Of Metal-Mine Effluents By Limestone Neutralization And Calcite Co-Precipitation (Presentation)

    Science.gov (United States)

    The U.S. Geological Survey - Leetown Science Center and the Colorado School of Mines have developed a remediation process for the treatment of metals in circumneutral mining influenced waters. The process involves treatment with a pulsed limestone bed (PLB) system, followed by c...

  12. Discrimination of moist oil shale and limestone using laser induced breakdown spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Paris, P., E-mail: peeter.paris@ut.ee; Piip, K.; Lepp, A.; Lissovski, A.; Aints, M.; Laan, M.

    2015-05-01

    Laser-induced plasma emission spectra of Estonian oil shale and associated limestone with varying moisture content were studied. Time gated spectra excited by 1064 nm laser radiation were recorded. Spectral lines for determination of plasma parameters were selected. Moisture causes the reduction of the intensity of the total emission, and increases the intensity of the H{sub α} line. It was found that the effect of the moisture content on the plasma temperature and electron concentration was inconsiderable. Using the ratio of intensities of H{sub α} and Mg spectral lines, it was possible to distinguish reliably between limestone and oil shale independently of their moisture content. - Highlights: • Laser induced plasma emission spectra of both; Estonian oil shale and limestone with varying moisture content were studied. • The temporal change of the laser induced plasma plume temperature T{sub e} and electron density n{sub e} were evaluated. • Plasma temperature and electron concentration changed with the moisture content inconsiderably. • Limestone and oil shale are distinguished independently of their moisture content by the intensity ratio of H{sub α} and Mg lines.

  13. Primulina beiliuensis var. fimbribracteata (Gesneriaceae), a New Variety in A Limestone Cave from Northern Guangdong, China

    OpenAIRE

    Bi-Dan Lai; Fang Wen

    2015-01-01

    Primulina beiliuensis var. fimbribracteata F. Wen & B.D. Lai, a new variety of Gesneriaceae from a limestone cave in Shaoguan, Guangdong, China, is described and illustrated in this report. This new species is similar to P. beiliuensis B. Pan & S.X. Huang var. beiliuensis, but easily differs from the type variety in several morphological characters, both vegetative and reproductive.

  14. Goat Urine and Limestone Affect Nitrogen and Cation Distributions in an Acidic Grassland

    Science.gov (United States)

    Use of goats (Capra aegagrus hircus L.) to clear overgrown pastures and woodlots of unwanted vegetation may result in high rates of urine deposition where goats congregate. Surface application of limestone to dystrophic acid soils before clearing is known to augment ammonia gas volatilization from ...

  15. The mechanics of intersecting echelon veins and pressure solution seams in limestone

    Science.gov (United States)

    Seyum, Solomon; Pollard, David D.

    2016-08-01

    Many studies that describe the formation of echelon vein arrays relate the causative stresses implicitly to the deformation, reliant on simple shear kinematics, such that the vein-to-array angle and the array width are the primary physical quantities. In contrast, we identify twelve physical quantities to describe echelon veins in two dimensions, including coeval, vein-intersecting, pressure solution seams. A finite element method is used to reproduce vein shapes in linear elastic and elastic-perfectly plastic model limestone. Model vein geometries are designed using values within the range of geometries measured from echelon veins at Raplee Anticline and Comb Monocline, Utah. Four physical quantities are significant for describing echelon vein shapes: vein spacing, vein-array angle, limestone elastic stiffness, and closing of orthogonal pressure solution seams. Pressure solution seam closing influences the mechanical interaction between adjacent veins, and for a range of conditions, causes a nearly linear vein opening distribution (triangular shapes) and encourages straight vein propagation, both of which approximate field measurements. Model results show that small spacing of veins with seams and large vein-array angles promote straight vein traces in limestone with stiffness typical of laboratory measurements, given the physical geologic conditions inferred from the burial history of the limestone strata.

  16. Adsorption/desorption of phosphorus on limestone from the Biscayne Aquifer under freshwater and seawater conditions.

    Science.gov (United States)

    Areas of seawater intrusion are known geochemically active regions particularly in limestone aquifers, where carbonate mineral dissolution and ion exchange reactions are important. Both of these processes can lead to a release of phosphorus from the aquifer matrix to the groundwater as seawater int...

  17. Optimization of nanolime solvent for the consolidation of coarse porous limestone

    Science.gov (United States)

    Borsoi, Giovanni; Lubelli, Barbara; van Hees, Rob; Veiga, Rosário; Silva, António Santos

    2016-09-01

    The potentialities of nanomaterials for application in the field of conservation have been widely investigated in the last two decades. Among nanomaterials, nanolimes, i.e., dispersions of lime nanoparticles in alcohols are promising consolidating products for calcareous materials. Nanolimes are effective in recovering the very superficial loss of cohesion of decayed materials, but they do not always provide sufficient mass consolidation. This limitation is mainly related to the deposition of the nanoparticles nearby the surface of the material. Experimental research has been set up with the aim of improving the in-depth deposition of lime nanoparticles. Previous research by the authors has shown that nanolime deposition within a substrate can be controlled by adapting the nanolimes properties (kinetic stability and evaporation rate) to the moisture transport behavior of the substrate. Nanolime properties can be modified by the use of different solvents. In this research, nanolime dispersions have been further optimized for application on Maastricht limestone, a coarse porous limestone. Firstly, nanolimes were synthesized and dispersed in ethanol and/or water, both pure and mixed in different percentages. Subsequently, based on the kinetic stability of the nanolime dispersions, the most promising solvent mixtures were selected and applied on the limestone. The deposition of lime nanoparticles within the limestone was studied by phenolphthalein test, optical microscopy and scanning electron microscopy. The results confirm that nanolime dispersed in a mixture of ethanol (95 %) and water (5 %) can guarantee a better nanoparticles in-depth deposition within coarse porous substrates, when compared to dispersions in pure ethanol.

  18. Limestone characterization to model damage from acidic precipitation: Effect of pore structure on mass transfer

    Science.gov (United States)

    Leith, S.D.; Reddy, M.M.; Irez, W.F.; Heymans, M.J.

    1996-01-01

    The pore structure of Salem limestone is investigated, and conclusions regarding the effect of the pore geometry on modeling moisture and contaminant transport are discussed based on thin section petrography, scanning electron microscopy, mercury intrusion porosimetry, and nitrogen adsorption analyses. These investigations are compared to and shown to compliment permeability and capillary pressure measurements for this common building stone. Salem limestone exhibits a bimodal pore size distribution in which the larger pores provide routes for convective mass transfer of contaminants into the material and the smaller pores lead to high surface area adsorption and reaction sites. Relative permeability and capillary pressure measurements of the air/water system indicate that Salem limestone exhibits high capillarity end low effective permeability to water. Based on stone characterization, aqueous diffusion and convection are believed to be the primary transport mechanisms for pollutants in this stone. The extent of contaminant accumulation in the stone depends on the mechanism of partitioning between the aqueous and solid phases. The described characterization techniques and modeling approach can be applied to many systems of interest such as acidic damage to limestone, mass transfer of contaminants in concrete and other porous building materials, and modeling pollutant transport in subsurface moisture zones.

  19. Piedramuelle Limestone in the building heritage of Oviedo, Spain, and adjacent towns.

    Science.gov (United States)

    Cardenes Van den Eynde, Victor; Mateos, Felix Javier; Valdeon, Luis; Rojo, Araceli

    2017-04-01

    The Piedramuelle limestone has a very important representation in the building heritage of Oviedo, historical capital of Asturias (Spain) and surrounding towns. This argillaceous limestone has been quarried since the High Middle Ages until the beginning of the XX century. The main mineralogical components are carbonates (mainly calcite and sometimes ankerite, 70-90%), quartz (5-15%), terrigenous minerals (6-15%) and iron oxides (weathering than the coarse-grained one, and it is used in the building heritage mainly for ornamental details, while the coarse-grained one is found in the bigger blocks and ashlars of the buildings. Some of the buildings constructed with Piedramuelle limestone are the Cathedral, the Old University and the Palaces from the XVII and XVIII centuries. The ambiance and historical architecture of Oviedo and adjacent towns is closely linked with the textures and colors of this stone. Nowadays, the Piedramuelle limestone is not exploited anymore, being the quarries exhausted. This represents an issue from a conservation point of view, since there is not a suitable stone for replacement. In order to preserve and maintain the building heritage of these towns, it is very important to prospect and protect the remaining outcrops still able to supply this characteristic stone.

  20. Integrated iron(II) oxidation and limestone neutralisation of acid mine water

    CSIR Research Space (South Africa)

    Maree, JP

    1999-01-01

    Full Text Available Volumetric iron (II) oxidation rates exceeding 100 g/(l.d) were achieved by dosing powdered limestone to a bio-reactor treating artificial acid mine water. Neutralisation and partial sulphate removal were achieved as well. The rate is highly...

  1. Limestone neutralisation of arsenic-rich effluent from a gold mine

    CSIR Research Space (South Africa)

    De Beer, Morris

    2008-03-01

    Full Text Available of limestone treatment is 45.8% less than that of lime. The acidity can be removed from 33.5 to 0.06 g/L (as CaCO3). The study also showed no significant differences in the TCLP characteristics of the resultant sludge when water is treated with lime...

  2. Low temperature production of wollastonite from limestone and silica sand through solid-state reaction

    Directory of Open Access Journals (Sweden)

    Rashita Abd Rashid

    2014-03-01

    Full Text Available Wollastonite was produced using solid-state reaction from limestone and silica sand. Limestone containing a high percentage of CaO (55.10% and silica sand with 99% SiO2 were used as starting materials. The ratios of limestone/sand used were 1:1, 2:1 and 3:1 with various firing temperatures, namely 1100, 1200, 1300, 1400 and 1450 °C. The raw materials and fired products were characterised for mineral phases, chemical composition of content such as CaO, SiO2 and loss on ignition (LOI, density and microstructure. CaSiO3 with an α-phase was detected at firing temperatures as low as 1300 °C, together with olivine and quartz phases, obtained from a 1:1 ratio. No α-CaSiO3 was detected for 2:1 and 3:1 ratios; only olivine and larnite phases were present. The density of the product was 2.93 g cm−3, which is close to the theoretical value, with a specific surface area of 3.23 m2 g−1. This study shows that the Malaysian limestone and silica sand can produce good properties of wollastonite materials.

  3. Analytical Modeling and Contradictions in Limestone Reservoirs: Breccias, Vugs, and Fractures

    Directory of Open Access Journals (Sweden)

    Nelson Barros-Galvis

    2015-01-01

    Full Text Available Modeling of limestone reservoirs is traditionally developed applying tectonic fractures concepts or planar discontinuities and has been simulated dynamically without considering nonplanar discontinuities as sedimentary breccias, vugs, fault breccias, and impact breccias, assuming that all these nonplanar discontinuities are tectonic fractures, causing confusion and contradictions in reservoirs characterization. The differences in geometry and connectivity in each discontinuity affect fluid flow, generating the challenge to develop specific analytical models that describe quantitatively hydrodynamic behavior in breccias, vugs, and fractures, focusing on oil flow in limestone reservoirs. This paper demonstrates the differences between types of discontinuities that affect limestone reservoirs and recommends that all discontinuities should be included in simulation and static-dynamic characterization, because they impact fluid flow. To demonstrate these differences, different analytic models are developed. Findings of this work are based on observations of cores, outcrops, and tomography and are validated with field data. The explanations and mathematical modeling developed here could be used as diagnostic tools to predict fluid velocity and fluid flow in limestone reservoirs, improving the complex reservoirs static-dynamic characterization.

  4. Fluoride removal from groundwater by limestone treatment in presence of phosphoric acid.

    Science.gov (United States)

    Gogoi, Sweety; Nath, Suresh K; Bordoloi, Shreemoyee; Dutta, Robin K

    2015-04-01

    Fluoride removal from groundwater has been studied by addition of dilute phosphoric acid (PA) to the influent water before limestone treatment through laboratory plug-flow column experiments and bench-scale plug-flow pilot tests. In this PA-enhanced limestone defluoridation (PAELD) technique, fluoride is removed from 0.526 mM to 0.50-52.60 μM in 3 h with near neutral final pH. The presence of PA increases the fluoride removal capacity of limestone to 1.10 mg/g compared to 0.39 mg/g reported in its absence. The changes in fluoride removal with variation in initial PA concentration, initial fluoride concentration and the final pH have been found to be statistically significant with p fluoride by calcium phosphates produced in situ in the reactor is the dominant mechanism of fluoride removal in the PAELD. Precipitation of CaF2 and sorption of fluoride by the limestone also contribute to the fluoride removal. High efficiency, capacity, safety, environment-friendliness, low cost and simplicity of operation make the PAELD a potential technique for rural application. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Limestone and Zeolite as Alternative Media in Horizontal Subsurface Flow Constructed Wetlands: Laboratory-Scale Studies

    Science.gov (United States)

    Lizama, K.; Jaque, I.; Ayala, J.

    2016-12-01

    Arsenic is well known for its chronic toxicity. Millions of people around the world are currently at risk, drinking water with As concentrations above 10 ppb, the WHO drinking water guideline. Although different treatment options exist, they are often limited by elevated costs and maintenance requirements. Constructed wetlands are a natural water treatment system, capable to remove metals and metalloids -including As- via different physical, chemical and biological processes. The use of alternative supporting media to enhance As removal in subsurface flow wetlands has been recommended, but not sufficiently studied. Limestone and zeolite have been identified as effective supporting media in subsurface flow wetlands aiming As removal. However, there are still key aspects to be addressed, such as the implications of using these media, the speciation in the solid phase, the role of vegetation, etc. This study investigated the performance of limestone and zeolite in three types of experiments: batch, column and as main supporting media in a bench scale horizontal subsurface flow wetland system. Synthetic water resembling a contaminated river in Chile (As concentration=3 mg/L, Fe concentration= 100 mg/L, pH=2) was used in all experiments. In the batch experiments, the As concentration, the mass of media and the contact time were varied. The column system consisted of three limestone columns and three zeolite columns, operated under a hydraulic loading of 20 mm/d. The wetland system consisted of twelve PVC cells: six filled with zeolite and six with limestone. Phragmites australis were planted in three cells of each media type, as control cells. From the batch experiments, maximum As sorption capacities as indicated by Langmuir model were 1.3 mg/g for limestone and 0.17 mg/g for zeolite, at 18 h contact time and 6.3 g/L medium concentration. EDS and XPS analyses revealed that As and Fe were retained in zeolite at the end of the batch experiments. Zeolite and limestone

  6. Investigations of a Cretaceous limestone with spectral induced polarization and scanning electron microscopy

    Science.gov (United States)

    Johansson, Sara; Sparrenbom, Charlotte; Fiandaca, Gianluca; Lindskog, Anders; Olsson, Per-Ivar; Dahlin, Torleif; Rosqvist, Håkan

    2017-02-01

    Characterization of varying bedrock properties is a common need in various contexts, ranging from large infrastructure pre-investigations to environmental protection. A direct current resistivity and time domain induced polarization (IP) survey aiming to characterize properties of a Cretaceous limestone was carried out in the Kristianstad basin, Sweden. The time domain IP data was processed with a recently developed method in order to suppress noise from the challenging urban setting in the survey area. The processing also enabled extraction of early decay times resulting in broader spectra of the time decays and inversion for Cole-Cole parameters. The aims of this study is to investigate if large-scale geoelectrical variations as well as small-scale structural and compositional variations exist within the Kristianstad limestone, and to evaluate the usefulness of Cole-Cole inverted IP data in early time ranges for bedrock characterization. The inverted sections showed variations within the limestone that could be caused by variations in texture and composition. Samples from a deep drilling in the Kristianstad basin were investigated with scanning electron microscopy and energy dispersive X-ray spectroscopy, and the results showed that varying amounts of pyrite, glauconite and clay matrix were present at different levels in the limestone. The local high IP anomalies in the limestone could be caused by these minerals otherwise the IP responses were generally weak. There were also differences in the texture of the limestone at different levels, governed by fossil shapes and composition, proportions of calcareous cement and matrix as well as amount of silicate grains. Textural variations may have implications on the variation in Cole-Cole relaxation time and frequency factor. However, more research is needed in order to directly connect microgeometrical properties in limestone to spectral IP responses. The results from this study show that it is possible to recover

  7. The Öland limestone - A Swedish stone used for more than one thousand years

    Science.gov (United States)

    Schouenborg, Björn; Wickström, Linda; Mikaelsson, Jan

    2016-04-01

    The second largest island in Sweden is the home of the "Öland limestone", a condensed and bedded limestone whose origin dates back to Lower Ordovician, i.e. about 480 M years ago. Öland is a part of the palaeocontinent Baltica that, at the time, was situated at low latitudes with deposition of the calcareous sediments in a cool water environment. The limestone on Öland represents a proximal ramp tectonic setting, with the oldest sediments deposited in the west and younger sediments deposited towards east and southeast. Fluctuating sea-levels have created erosional hard grounds such as the Flowery sheet. These hardgrounds are recognised by their vivid colours and trace fossils, and can be traced all over Baltica, but is maybe best represented on Öland. Ordovician limestones are present in many places in Sweden, but it is the occurrence on Öland that is the most renowned in a building stone perspective. One reason for this is the favourable trading location, an island off the Swedish East coast in middle of the trading routes between the Baltic countries and the continent. Other reasons are the pleasant aesthetical values with numerous orthoceratites and other fossils. The limestones on Öland differ in colour. From the red varieties (with oxidized iron) to brownish and grey. The bedding is mostly in the cm-scale which easily enables very exploitable thickness of slabs. Every mm limestone represents about 1000 years of deposition. The limestone has most likely been used in a very crude way for many thousand years, but archaeological evidence of a more industrialized usage is just a little more than 1000 years. It is known from the literature that the first official Swedish king, Gustav Vasa (16th century), desired this stone. At the time it was called "Öland marble", and the king "imported" specialists to process it further at the Royal Stone workshop on northern Öland. Remnants of tools and working sites still remain in an outdoor museum. Export of the

  8. Quantifying and timing of long-term carbonate mobilisation in a limestone aquifer

    Science.gov (United States)

    Kirstein, J.; Gaupp, R.

    2012-04-01

    Carbonate dissolution during weathering, its intermediate storage by reprecipitation, and/or final export to the sea are major components in the global carbon cycle. The Thuringian Basin in the central part of Germany exposes deposits of the German Triassic Muschelkalk sequence consisting of limestone and dolostone beds. Partial dissolution, oxidation and iron redistribution is obvious in limestones along the slopes of the middle Saale river valley. These features are most prominent close to a Mid Quaternary valley floor (Elster terrace). They decrease down-section following fractures in homogeneous micritic limestones of the Lower Muschelkalk (Jena Formation), and reach a minimum close to the present groundwater table. It implies a discontinuous vertical migration of the groundwater table close to the valley slopes, spanning >700 ka of valley incision, and a coeval increase of oxidative weathering of sulfides and organic matter in the micritic carbonate. The recharging groundwater carries dissolved and particulate organic matter from the soil into fractures and pores. Microbial community oxidizes the organic material by using O2 that diffuses in from atmosphere. Due to the dissolved CO2 the water is undersaturated concerning carbonate minerals. The fissures enlarge by the water dissolving the limestones. The working hypothesis suggests the maximum of carbonate dissolution and descendant export within the vadose zone. Material export is supposed to occur dependant on climatic variations with microbial mediation in both dissolution and transient reprecipitation. Furthermore, the study area has the important advantage that the timing of the 100 m migration of the ground water table has a good age control due to topographic dating of terrace formation. Key aspects of this study are the quantification of long-term telodiagenetic transformations of the limestones, the timing of the involved processes and the analysis of current carbon fluxes both surface and subsurface

  9. Evolution and extinction of Permian fusulinid fauna in the Khao Tham Yai Limestone in NE Thailand

    Science.gov (United States)

    Hada, Shigeki; Khosithanont, Somboon; Goto, Hiroya; Fontaine, Henri; Salyapongse, Sirot

    2015-05-01

    The first detailed biostratigraphic investigation of a single limestone unit within the Khao Tham Yai Limestone shows it was deposited continuously in a shelf setting without any intercalation of clastic beds. It ranges from the Wordian (middle Middle Permian) up to the Wuchiapingian (lower Upper Permian). The limestone unit is divided in ascending order into three fusulinid zones, i.e. Colania, Lepidolina and Codonofusiella zones. The middle zone is characterized by an abundance of large-tested fusulinids characteristic of the Lepidolina Zone. Shell sizes of the fusulinid species in this zone display continuous rapid morphological change along a one-way evolutionary path from small, primitive species with simple structure to large, highly evolved species having a complicated wall structure. Fusulinid biostratigraphy in a single limestone unit elucidates evolution and extinction patterns of Permian fusulinids of the shallow-water Tethyan shelf area in the Indochina Block. Our study reveals that the boundary between the Guadalupian (Middle Permian) and Lopingian (Upper Permian) in the Khao Tham Yai Limestone is clearly defined as an abrupt change in the fusulinid assemblages from the elimination of large-tested Verbeekinids and Schwagerinids to the domination of small-shelled Schubertellids. The Schubertellids underwent slower evolutionary morphological change than earlier fusulinids and were decreasingly dominant through the Permian. A similar pattern of fusulinid evolution and extinction at the Guadalupian-Lopingian boundary occurs in shallow-water Tethyan shelf areas and mid-oceanic shallow-water environments in mid-Panthalassa. Eventually, even smaller fusulinids abruptly become extinct. Clastic deposits finally replace previous carbonate formations characterized by algae-foraminifera biota. It starts in the upper Middle Permian in the southern parts and spreads throughout the whole area in the lower Upper Permian in NE Thailand. These observations suggest

  10. Calcium levels and limestone particle size in the diet of commercial layers at the end of the first production cycle

    Directory of Open Access Journals (Sweden)

    K Pelicia

    2009-06-01

    Full Text Available This study evaluated the effect of dietary calcium levels and limestone particle size distribution on first-cycle layer performance and egg quality. A completely randomized experimental design in 4x3 factorial arrangement (four Ca levels - 3.0, 3.5, 4.0, 4.5%; and three limestone particle size distributions - 100% fine, 50% fine and 50% coarse, 30% fine and 70% coarse was applied, totaling 12 treatments with six replicates of eight birds each. The treatments did not influence the most of evaluated performance and internal and external egg quality parameters. However, limestone particle size distribution quadratically affected with percentage of defective eggs, with the lowest percentage obtained with the distribution 61.75% fine limestone and 38.25% coarse limestone. Increasing dietary Ca levels significantly increased eggshell weight per surface area and the percentage of Ca excreted in the feces. It was concluded that the combination of the highest dietary Ca level (4.5% with 50% replacement of fine-particle limestone by coarse limestone results in better eggshell and increases the number of marketable eggs.

  11. Studies on the preparation of value-added products for limestone

    Energy Technology Data Exchange (ETDEWEB)

    Chae, Young Bae; Jeong, Soo Bok; Ko, Won Sik; Chang, Byung Pyo [Korea Institute of Geology Mining and Materials, Taejon (Korea)

    1998-12-01

    Imports of high grade limestone and calcium carbonate powder that have properties of high whiteness and grade are increased with diversification of chemical products and powder as various qualified filler, because high grade limestone are limited or few deposited in our country. There are three kinds in the importation calcium carbonate powder that have properties of high whiteness over 95 deg., high purity and hydrophobic with fatty acid coating at the powder surface. This study is to develop the process of grade up by economical processes with low and/or middle grade of domestic limestone and of powder coating by dry base. We investigated the status of application utilize and related industries with the domestic limestone, and then being consideration with condition selected the adequate sample from Taeback, Uljin, Andong, Jungsun and Kumsan area. The limestone sample has many kinds of impurity. So, the method of preparation used in this experiment is Magnetic separation, Flotation, Selective crushing and Precision Classifying according the mineral properties. Magnetic separation method was applied in elimination of the ferro-magnetic materials and para-magnetic materials, such as chlorite, muscovite, quartz dolomite, magnetite, feldspar and so on. Flotation process was undertaken to eliminate of the small size impurities form limestone crude ore and the tests were performed to get a optimum condition adding oleic acid as a promoter, sodium silicate and sodium carbonate as a conditioning agents and MIBC as a frother and sulfuric acid as a pH regulator. Selective crushing and classification methods were performed for eliminated impurities depends on the mineral properties and should be the selective crushing methods on the mineral properties and should be the selective crushing methods are very useful at the manufacturing process of heavy calcium carbonate with the dry milling system. In the heavy calcium carbonate powder coating experiments, A contact angle of

  12. Cretaceous planktic foraminiferal biostratigraphy of the Calera Limestone, Northern California, USA

    Science.gov (United States)

    Sliter, W.V.

    1999-01-01

    The Calera Limestone is the largest, most stratigraphically extensive limestone unit of oceanic character included in the Franciscan Complex of northern California. The aim of this paper is to place the Calera Limestone at its type locality (Rockaway Beach, Pacifica) in a high-resolution biostratigraphy utilizing planktic foraminifers studied in thin section. A section, about 110 m-thick, was measured from the middle thrust slice exposed by quarrying on the southwest side of Calera Hill at Pacifica Quarry. Lithologically, the section is divided in two units; a lower unit with 73 m of black to dark-grey limestone, black chert and tuff, and an upper unit with 36.8 m of light-grey limestone and medium-grey chert. Two prominent black-shale layers rich in organic carbon occur 11 m below the top of the lower black unit and at the boundary with overlying light-grey unit, yielding a total organic content (TOC) of 4.7% and 1.8% t.w., respectively. The fossiliferous Calera Limestone section measured at Pacifica Quarry, from the lower black shale, contains eleven zones and three subzones that span approximately 26 m.y. from the early Aptian to the late Cenomanian. The zones indentified range from the Globigerinelloides blowi Zone to the Dicarinella algeriana Subzone of the Rotalipora cushmani Zone. Within this biostratigraphic interval, the Ticinella bejaouaensis and Hedbergella planispira Zones at the Aptian/Albian boundary are missing as are the Rotalipora subticinensis Subzone of the Biticinella breggiensis Zone and the overlying Rotalipora ticinensis Zone in the late Albian owing both to low-angle thrust faulting and to unconformities. The abundance and preservation of planktic foraminifers are poor in the lower part and improve only within the upper G. algerianus Zone. The faunal relationship indicate that the lower black shale occurs in the upper part of the G. blowi Zone and correlates with the Selli Event recognized at global scale in the early Aptian. The upper black

  13. Effects of Thaumasite Formation on the Performance of Portland-limestone Concrete Stored in Magnesium Sulfate Solution

    Institute of Scientific and Technical Information of China (English)

    GAO Lixiong; YAO Yan; WANG Ling

    2005-01-01

    The influence of thaumasite formation on the performance of Portland- limestone cement concrete stored in magnesium sulfate solution was studied. The experimental results show that the deterioration of Portlandlimestone cement concrete is higher than that of Portland cement concrete. The more the content of limestone, the more serious the deterioration of concrete, and also the lower the temperature, the earlier the deterioration of concrete. Thaumasite was detected to form in the Portland-limestone pastes when stored in 10wt% MgSO4 solution at 3- 10 ℃ and it was easy to form at lower temperatures.

  14. Effects of the earthquake of March 27, 1964, on air and water transport, communications, and utilities systems in south-central Alaska: Chapter B in The Alaska earthquake, March 27, 1964: effects on transportation, communications, and utilities

    Science.gov (United States)

    Eckel, Edwin B.

    1967-01-01

    The earthquake of March 27, 1964, wrecked or severely hampered all forms of transportation, all utilities, and all communications systems over a very large part of south-central Alaska. Effects on air transportation were minor as compared to those on the water, highway, and railroad transport systems. A few planes were damaged or wrecked by seismic vibration or by flooding. Numerous airport facilities were damaged by vibration or by secondary effects of the earthquake, notably seismic sea and landslide-generated waves, tectonic subsidence, and compaction. Nearly all air facilities were partly or wholly operational within a few hours after the earthquake. The earthquake inflicted enormous damage on the shipping industry, which is indispensable to a State that imports fully 90 percent of its requirements—mostly by water—and whose largest single industry is fishing. Except for those of Anchorage, all port facilities in the earthquake-affected area were destroyed or made inoperable by submarine slides, waves, tectonic uplift, and fire. No large vessels were lost, but more than 200 smaller ones (mostly crab or salmon boats) were lost or severely damaged. Navigation aids were destroyed, and hitherto well-known waterways were greatly altered by uplift or subsidence. All these effects wrought far-reaching changes in the shipping economy of Alaska, many of them to its betterment. Virtually all utilities and communications in south-central Alaska were damaged or wrecked by the earthquake, but temporary repairs were effected in remarkably short times. Communications systems were silenced almost everywhere by loss of power or by downed lines; their place was quickly taken by a patchwork of self-powered radio transmitters. A complex power-generating system that served much of the stricken area from steam, diesel, and hydrogenerating plants was disrupted in many places by vibration damage to equipment and by broken transmission lines. Landslides in Anchorage broke gas