WorldWideScience

Sample records for hokokusho tansanado ni

  1. Achievement report for fiscal 1997 on the research and development to lead to gas hydrate using technology. Research and development on exploration, research and development on drilling technologies, survey and research on a method to evaluate environmental impact, and survey and research on a utilization system; 1997 nendo gas haidoreto shigenka gijutsu sendo kenkyu kaihatsu seika hokokusho. Tansanado ni kansuru kenkyu kaihatsu, kussaku gijutsu ni kansuru kenkyu kaihatsu, kankyo eikyo hyokaho no chosa kenkyu, riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    The present study is intended to analyze comprehensively geophysical, geological and geochemical data, and establish a technology to estimate distribution of gas hydrate (GH) in sea areas around Japan. It is also intended to develop a high-accuracy resource amount calculating method utilizing the result of excavation of GH planned in the future. In order to achieve these goals, the following activities are performed: (1) study on a method to estimate production environment of GH deposits, (2) development of a method to estimate GH stability areas by using the crust thermal flow measuring method, and (3) study on estimation of GH distribution and wide-area potential. For the study (1), an inorganic element analyzer was introduced, and calibration of devices was performed in fiscal 1997. A survey was carried out on literatures related to distribution of inorganic elements and process of GH deposit production. In the study (2), design and trial fabrication were executed on a high-accuracy crust thermal flow measuring device, capable of long-term continuous observation. In the study (3), re-processing focusing on BSR was implemented by using the latest computer and analysis software on the data in which BSR has been confirmed in the surveys done in the past on sea areas around Japan. (NEDO)

  2. FY 1998 annual report on the preliminary research and development of techniques for developing resources from gas-hydrate. Studies on gas-hydrate exploration, excavation techniques, methods for assessing environmental impacts, and gas hydrate handling systems; 1998 nendo gas hydrate shigenka gijutsu sendoken kaihatsu seika hokokusho. Tansanado ni kansuru kenkyu kaihatsu, kussaku gijutsu nado ni kansuru kenkyu kaihatsu, kankyo eikyo hyokaho no kenkyu kaihatsu, riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This R and D project is for the preliminary studies on development of the following 4 types of techniques for developing resources from gas-hydrates (GH): (1) gas-hydrate exploration, (2) excavation techniques, (3) methods for assessing environmental impacts, and (4) gas hydrate handling systems. The FY 1988 R and D results are described. For gas-hydrate exploration, the methods for analyzing inorganic ions and trace quantities of elements, which are necessary for accurately estimating the offshore GH around Japan, are established; and case studies are conducted for methods of predicting GH deposit forming mechanisms, and stability fields of GH, based on terrestrial heat flow and seismic data. For excavation techniques, GH decomposition rate is analyzed using a laboratory system which reproduces conditions of excavation of GH layers. For methods for assessing environmental impacts, a geo-hazard predicting model is established, to study ground displacement and gas leakage sensing systems and data transmission systems to cope with the hazards. For gas hydrate handling systems, an overall system is studied, and storage and transportation systems are outlined. (NEDO)

  3. Report on the FY 1999 research survey on the development of high ductile chromium alloys; 1999 nendo koensei kuromu gokin no kaihatsu ni kansuru kenkyu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The R and D of chromium alloys had been conducted till about the 1970s, which brought the unfavorable results. That's why chromium alloys are brittle at normal temperature and difficult in processing. However, the technology development in recent years review them. The development is earnestly desired also of the materials exceeding the Ni base super alloys which are heat resistant materials for power generation. Cr is rich as resource and light-weighted, and the oxidation film is stable and self-restorational at high temperature. The alloys are excellent in processability at normal temperature and excellent also in toughness. The nitrogen content is strongly concerned with brittleness and intergranular fracture at normal temperature. Therefore, Cr alloys were trially manufactured by the HIP sintering/hot forging method using electrolytic Cr powder with high-purity (99.99%) and low-nitrogen (10ppm) to study a possibility of improving brittleness at normal temperature, mechanical properties at high temperature, oxidation resistance, high-temperature corrosion resistance, etc. A variety of excellent characteristics of Cr alloys were made clear. However, also made clear were the problems: strength is low at normal temperature/high temperature; screw process is impossible because of high notch sensibility; those are not almighty high-temperature corrosion resistant materials. Further efforts should be exerted for the commercialization. (NEDO)

  4. FY 1998 annual report on the decomposition/removal of harmful compounds in the gaseous phase by porous membrane provided with a catalytic function; 1998 nendo shokubai kinotsuki fuyo takomaku ni yoru kisochu yugai busshitsu no bunkai jokyo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Harmful compounds, e.g., dioxins and nitrogen oxides, released into the air are causing severer environmental problems on a global scale. In order to solve these problems, it is necessary to efficiently remove the released compounds in the vicinity of the living environments, while preventing, as far as possible, their formation at the sources. An attempt has been made to develop porous membranes impregnated with composites of a variety of metallic oxides showing activities as photocatalysts and for dark reactions by the ion engineering method, in order to drastically solve the above problems. Described herein are the FY 1998 results. Thin films of various titanium oxide crystals (anatase, rutile, and their combinations) are formed on Si substrates by the ion engineering method, as the photocatalysts for decomposition of aldehyde and water (for hydrogen production), to validate the optimum crystalline structures for the photocatalysis. Porous bodies of Ni and carbon are also impregnated with anatase TiO{sub 2} for decomposition of harmful gaseous compounds and water, to validate the effects of the porous membranes provided with catalytic functions. (NEDO)

  5. Achievement report for fiscal 1995 on the research and development of comprehensive basic technologies on marine resources (manganese nodule mining system) in industrial and scientific technology research and development project. Trends and forecasts of the supply-demand for metal resources (Ni, Co, Cu, Fe, Mn) that are contained in manganese nodules; 1995 nendo kaiyo shigen sogo kiban gijutsu no kenkyu kaihatsu (mangan dankai saiko system) seika hokokusho. Mangan dankai ni kakawaru kinzoku shigen (Ni, Co, Cu, Fe, Mn) no kyokyu ni kansuru shorai doko no suitei

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-01

    Living standards improving in developing countries especially in China are the most influential factor to determine the demand for Cu. Consumption of Ni will depend on the trends of advanced technologies such as Ni-hydrogen battery, fuel cell, shape memory alloy, hydrogen absorbing alloy, in addition to increase in global population and developing countries' living standards improvement. Co is far more dependent on advanced technologies than Ni is. On the land, Ni ore is increasingly lower in quality and Co is being retrieved from by-products of Cu production, both meeting the problem of unstable supply. Consideration is made to apply new extraction methods to Cu production; there are some potential resources for Fe and Mn. The Mn nodule exists in great quantities and is a attractive source of supply, but a long time will be required before it is exploited. It is necessary to speed up the study to exploit the Mn nodule, but first of all the problem of its competition with land resources in terms of cost has to be solved. It needs to be found out at what stage of production the Mn nodule is competitive with land products. In any case, Japan should undertake the efforts of marine resources exploitation leading other countries of the world. (NEDO)

  6. Fiscal 1999 achievement report on the venture business assisting type regional consortium - Minor business creation base type. Development of environmentally friendly chromium-free plating technology and research on its practical application; 1999 nendo chiiki consortium kenkyu kaihatsu jigyo seika hokokusho. Kankyo ni yasashii kuromu daitai mekki gijutsu kaihatsu to sono jitsuyoka kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    In this research, the seeds provided by Technology Research Institute of Osaka Prefecture and Nomura Plating Co., Ltd., relative to their plating processes using ion exchange membranes and metal anodes are utilized. Efforts are made to prolong the bathing life of the Ni-W alloy plating solution, to put the plating bath in an enclosure, to develop a chromium-free plating technology wherewith bating life is longer, environmental impact is smaller, and resistance to corrosion is higher, and experiments and tests are conducted for industrialization and for the practical application of the developed technologies. At Technology Research Institute of Osaka Prefecture, electrolytic Ni-W alloy plating was taken up. An insoluble anode separated from the plating solution by a cation exchange membrane and plural metal anodes were brought into a new process and, into the same, novel technologies were further introduced, which were a metal ion supply method in which the distribution of current to 3 anodes was regulated and the employment of a sacrificial anode decomposition agent. The new process was investigated for its validity and difficulties. Furthermore, Ni-W-P alloy plating was studied and a mirror-like Ni-W-P alloy plate was developed in a phosphorous acid added bath without detriment to the non-waste solution plating process, and the plate exhibited high corrosion resistance in a CASS (copper-accelerated acetic acid salt spray) test. (NEDO)

  7. Achievement report for 1st phase (fiscal 1974-80) Sunshine Program research and development - Hydrogen energy. Research on transportation of hydrogen in the form of metallic hydride; 1974-1980 nendo kinzoku suisokabutsu ni yoru suiso no yuso gijutsu no kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    This report concerns the transportation and storage of hydrogen using metallic hydrides that perform absorption and desorption of hydrogen. Alloys useable for this purpose have to be capable of reversibly absorbing and desorbing hydrogen within a certain temperature range. In the absence of guidelines to follow in the quest for such alloys, the efforts at discovering them turned out to be a continual series of trials and errors. Researches were conducted into the hydrogenation reaction of Mg and Mg-based alloys and into hydrides of V-based alloys, and into Zr-based alloy hydrides such as the ZrMn{sub 2} hydride, ZrNiMn hydride, Zr(Fe{sub x}Mn{sub 1-x}){sub 2} hydrides, TiZrFe{sub 2} hydride, Zr{sub x}Ti{sub 1-x}(Fe{sub y}Mn{sub 1-y}) hydrides, etc. Also studied were the electronics of hydrogen in metallic hydrides, rates of reaction between Mg-Ni-based alloys and hydrogen systems, endurance tests for hydrides of Mg-Ni-based alloys, effects exerted by absorbed gas molecules during the storage of hydrogen in Mg-Ni-based alloys, effective thermal conductivity in a layer filled with a metallic hydride, metallic hydride-aided hydrogen transportation systems, chemical boosters, etc. (NEDO)

  8. Achievement report on research and development in the Sunshine Project in fiscal 1980. Research on a hydrogen manufacturing technology by using thermo-chemical method. (Research on equipment materials for iodine system cycle); 1980 nendo netsukagakuho ni yoru suiso seizo gijutsu no kenkyu seika hokokusho. Yosokei cycle no sochi zairyo no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    This paper describes research on materials of equipment for the second stage reaction in relation with development on a hydrogen manufacturing technology by using the iodine system cycle in the thermo-chemical method. The second stage reaction produces MgO, I{sub 2} and O{sub 2} by decomposition of Mg(IO{sub 3}){sub 2} at 600 to 650 degrees C. Corrosion tests were carried out by using 25Cr-20Ni steel and Ni-50Cr alloy having shown relatively high corrosion resistance in the researches to date, which were added with trace amount of different alloy elements. The tests were performed in gas mixture of I{sub 2}, O{sub 2} and H{sub 2}O at 600 to 700 degrees C for 48 to 192 hours. The average corrosion rate of 25Cr-20Ni steel was reduced by adding Y(0.2%), Ca (0.2%) or Si+Al (1%Si+1%Al), by which relatively uniform corrosion pattern was shown, and the corrosion resistance was improved remarkably. The average corrosion rate of 25Cr-20Ni steel showed a trend of increasing by adding Si and Nb, and non-uniform corrosion like pitting has occurred, revealing that it is not preferable from the aspect of corrosion resistance. The average corrosion rates of the tested materials tended to become somewhat greater under heat insulated condition than under continuously heating condition. Effect of Mg(IO{sub 3}){sub 2} deposition is very small. (NEDO)

  9. Achievement report on research and development in the Sunshine Project in fiscal 1979. Research on hydrogen manufacturing technologies (Research on equipment materials for iodine system cycle); 1979 nendo netsukagakuho ni yoru suiso seizo gijutsu no kenkyu seika hokokusho. Yosokei cycle no sochi zairyo no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-03-01

    From among researches on hydrogen manufacturing technologies using thermo-chemistry in the Sunshine Project, discussions were given on equipment materials, with the second-stage reaction in the iodine system cycle as the object. This paper describes achievements in fiscal 1979. The reaction produces MgO, I{sub 2} and O{sub 2} from Mg(IO{sub 3}){sub 2}. Corrosion tests were performed by using test pieces made of Ni alloy, iron-Ni-Cr alloy, Ti alloy, Zr alloy, Nb and Ta. These materials are thought to have excellent corrosion resistance in high temperature gaseous phase composed of iodine, oxygen and water. Corrosion tests were carried out also by using sheet formed test pieces of 24 kinds of alloys and six kinds of commercially available non-ferrous metallic materials in different temperatures and atmospheres, mainly the iodine plus oxygen plus H{sub 2}O mixed gas atmosphere at 600 degrees C. The corrosion resistance of the tested materials can be divided into three ranks. Materials having relatively good resistance were Ni-50Cr alloy and Co group alloy. Materials having good corrosion resistance are very little affected by water content. The higher the temperature, the more the metal corrosivity has increased. Preliminary discussions were given on pipe formability in materials having good corrosion resistance as the equipment piping materials. Their mechanical properties were also tested. This paper also describes corrosion resistance tests under heat transferring condition by using pipe-formed test pieces. (NEDO)

  10. Achievement report for 1st phase (fiscal 1974-80) Sunshine Program research and development - Hydrogen energy. Research on hydrogen production technology using thermochemical method (Research on iodine-based cycle etc.); 1974-1980 nendo netsukagakuho ni yoru suiso seizo gijutsu no kenkyu seika hokokusho. Yosokei cycle nado no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    Iodine-alkaline earth metal (Mg, Ca) cycles are discovered, and the one with Mg is found excellent. The reaction consists of four stages, that is, Stage (1) where 1/5Mg(IO{sub 3}){sub 2}+MgI{sub 2}(aq) is obtained from 6/5MgO+6/5I{sub 2}, Stage (2) where 1/5MgO+1/5I{sub 2}+1/2O{sub 2} is obtained from 1/5Mg(IO{sub 3}){sub 2}, Stage (3) where MgO+2HI is obtained from MgI{sub 2}+H{sub 2}O, and Stage (4) where H{sub 2}+I{sub 2} is obtained from 2HI. Since there is much iodine and water at Stage (1), MgO thrice MgI{sub 2} in mol is added for reforming and concentration. At Stage (4), where the decomposition rate is as low as 17-27% with the equilibrium dissociation reaction proceeding at 300-700 degrees C, hydrogen is selectively separated by permeation through a porous diaphragm for the acceleration of the reaction. As for materials for the device, they are narrowed down to high-priced ones, that is, Ta and Nb for Stage (1), Ni-50Cr for Stage (2), and Mo etc. for Stages (3) and (4). Under the circumstances, a study is started for the development of a chemical vapor plating process which is high in corrosion resistance. Other cycles such as sulfur-based cycles and hybrid cycles are also investigated. (NEDO)

  11. Ni hombres ni mujeres providenciales

    OpenAIRE

    Montaño Virreira, Sonia

    2000-01-01

    Debo advertir a la y el lector de este texto que lo que a continuación se presenta no es, ni de lejos, una propuesta realista, si por ella entendemos la traducción, enclave mujer, de las actuales tendencias de liderazgo político vigentes en la región. Por el contrario, intento argumentaren favor de un liderazgo que supere el caudillismo como estilo y se aproxime al máximo hacia el respeto de las formas, entendiendo que sin ellas no es posible construir la democracia. Para hacerlo reviso rápid...

  12. Survey and research on applications of parallel compiler; Heiretsu compiler tekiyorei ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-31

    An urgent proposition is made that an advanced computing software program development and maintenance system be set up, and activities are conducted in search of strategies and guidelines for the establishment of such a system. Out of recognition that it is important to develop software programs such as operation systems for supercomputers, a survey is conducted of software technology development strategies especially involving application software programs. It is proposed that efforts be positively exerted to develop strategic software developing programs for advanced computing for concentratedly enhancing the development now under way of strategic software programs. In concrete terms, named as strategic software programs to be developed are a next-generation semiconductor TCAD (technology computer-aided design) system, protein structure/function analysis system, fatigue simulation system, next-generation fluid analysis system, chemical reaction simulator, grid computing, and a nanodevice surface analysis system. (NEDO)

  13. Report of 'Survey on Asian environmental information networks'; 'Asia kankyo joho network chosa' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    This project is implemented to survey the current statuses and future trends of the Asian district environment-related information networks, for the (research cooperation project for development of environmental condition measuring laser radar systems), being promoted by NEDO. First, current statuses of the network names, managing organizations, user numbers, conditions of use, protocols for use, service conditions, major domestic nodes and internationally connected conditions are surveyed mainly for internet-connected networks, for surveying the current statuses and future trends of the research networks in Asian countries. Second, current statuses in Indonesia of the network names, managing organizations, user numbers, conditions of use, protocols for use, service conditions, domestic node sites and managing organizations, charge systems and institutions, types/reliability/ stability of the circuits, and conditions of restriction of use, if any, for surveying the current statuses and future trends in Indonesia. Third, conditions of and needs for network utilization by researchers for Asian district environments. (NEDO)

  14. Proceedings of RITE international workshop on valuation; Total eko balance ni kansuru kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    The RITE International Workshop on Valuation was held in Tokyo and Osaka in February 1996, and eight papers on total ecobalance were reported. In The Field of Impact Assessment, described were constitution and methodology about impact assessment in a wide sense. In LCA Yesterday, Today and Tomorrow, discussed were the historical development and future outlook of LCA. In Standardization of Product Life Cycle Assessment, a survey of the present situation of LCA international standardization was made. In the Relationship between Product Life Cycle Assessment Methodology, considered was the relationship between the goal definition of the product life cycle assessment and the methodological choices. In Valuation in LCA, the present study of LCA was reviewed. Besides, reviews of the LCA study in Japan were made public.

  15. Report on Asian Environment Information Network; 'Asia kankyo joho network' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The goal is the construction of Asian Environment Information Network (AEInet) in accordance with a contract signed between Indonesia's LIPI (Indonesian Institute of Science) and NEDO under NEDO's Research Cooperation Project Concerning the Development of Environment Measuring Laser Radar (LR). The network is so designed and constituted as to operate on a private line between Indonesia and Japan via IP (Internet protocol) and to enable the exchange on the Internet network of the data collected/analyzed by the Indonesian LR system and of articles of e-mail between scientists of the two countries. The AEInet will be utilized for the collection/analysis of LR-collected data; exchange of observed data and the result of processing; provision of support to environment information scientists in exchanging e-mail and information; and the search of databases for the implementation of the project. In this paper, the outline and functions of the system, network system design, WWW server construction, network operating status, joint researches with Indonesia, etc., are described. (NEDO)

  16. Research report for establishment of NEDO vision; NEDO vision no sakutei ni muketa chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Because of an increase in energy demand due to economic growth and industrial structure change in the Asian area and its effect on global environment, the economic evolution harmonizing with energy and environment (3E) of the Asian area is required. The role of Japan, in particular, NEDO for achieving such 3E was studied from an international viewpoint. The following are thus surveyed: The history of energy demands, economic growth, an increase in energy consumption and their effect on global environment in the Asian area, and the policies, measures and future plans of Asian countries corresponding to the above situations. The role of NEDO is first of all R & D of biomass toward practical use, and development of effective use technology of biomass energy. Positive approach to control of CO2 emission and immobilization of CO2 is also required in industrial and traffic fields. As technology transfer from Japan, promotion of joint researches and establishment of an economic support scheme are expected together with transfer of the basement technology and training. 79 figs., 13 tabs.

  17. Decay of 57Ni

    International Nuclear Information System (INIS)

    Santos Scardino, A.M. dos.

    1987-01-01

    The decay of 57 Ni to 57 Co was studied by gamma ray spectroscopy using both singles and coincidence spectra. The sources were obtained with the 58 Ni (Y,n) 57 Ni reaction. Natural metallic nickel was irradiated in the bremsstrahluhng beam of the linear accelerator of the Instituto de Fisica da Universidade de Sao Paulo with 30 MeV electrons. The singles espectra were taken with 104 cc HPGe detector and the coincidences espectra with 27 and 53cc Ge(Li) and 104 cc. HPGe detectors. The energies of transitions that follow the 57 Ni decay were measured using 56 Co as standard (which was obtained by (Y,np) reaction in 58 Ni) and taking into account the cascade cross-over relations. (author) [pt

  18. Bridging exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi-Montes, Natalia, E-mail: nataliarin@gmail.com [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain); Gorria, Pedro [Departamento de Física & IUTA, EPI, Universidad de Oviedo, E-33203 Gijón (Spain); Martínez-Blanco, David [Servicios Científico-Técnicos, Universidad de Oviedo, E-33006 Oviedo (Spain); Fuertes, Antonio B. [Instituto Nacional del Carbón, CSIC, E-33080 Oviedo (Spain); Fernández Barquín, Luis [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, E-39005 Santander (Spain); Puente-Orench, Inés [Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza and Institut Laue-Langevin, BP 156, F-38042 Grenoble Cedex 9 (France); Blanco, Jesús A. [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain)

    2016-02-15

    Among all bi-magnetic core(transition metal)@shell(transition metal oxide) nanoparticles (NPs), Ni@NiO ones show an onset temperature for the exchange bias (EB) effect far below the Néel temperature of bulk antiferromagnetic NiO. In this framework, the role played by the magnetism of NiO at the nanoscale is investigated by comparing the microstructure and magnetic properties of NiO and Ni@NiO NPs. With the aim of bridging the two systems, the diameter of the NiO NPs (~4 nm) is chosen to be comparable to the shell thickness of Ni@NiO ones (~2 nm). The EB effect in Ni@NiO NPs is attributed to the exchange coupling between the core and the shell, with an interfacial exchange energy of ΔE~0.06 erg cm{sup −2}, thus comparable to previous reports on Ni/NiO interfaces both in thin film and NP morphologies. In contrast, the EB detected in NiO NPs is explained in a picture where uncompensated spins located on a magnetically disordered surface shell are exchange coupled to the antiferromagnetic core. In all the studied NPs, the variation of the EB field as a function of temperature is described according to a negative exponential law with a similar decay constant, yielding a vanishing EB effect around T~40–50 K. In addition, the onset temperature for the EB effect in both NiO and Ni@NiO NPs seems to follow a universal dependence with the NiO crystallite size. - Highlights: • Comparison of the exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles. • Universal temperature dependence of the exchange bias effect. • Suggested similar physical origin of the effect in both systems. • Size and crystallinity of the NiO shell hold the key for exchange bias properties.

  19. OpenNI cookbook

    CERN Document Server

    Falahati, Soroush

    2013-01-01

    This is a Cookbook with plenty of practical recipes enriched with explained code and relevant screenshots to ease your learning curve. If you are a beginner or a professional in NIUI and want to write serious applications or games, then this book is for you. Even OpenNI 1 and OpenNI 1.x programmers who want to move to new versions of OpenNI can use this book as a starting point. This book uses C++ as the primary language but there are some examples in C# and Java too, so you need to have about a basic working knowledge of C or C++ for most cases.

  20. Gd-Ni-Si system

    International Nuclear Information System (INIS)

    Bodak, O.I.; Shvets, A.F.

    1983-01-01

    By X-ray phase analysis method isothermal cross section of phase diagram of the Gd-Ni-Si system at 870 K is studied. The existence of nine previously known compounds (GdNisub(6.72)Sisub(6.28), GdNi 10 Si 2 , GdNi 5 Si 3 , GdNi 4 Si, GdNi 2 Si 2 , GdNiSi 3 , GdNiSi 2 , Gd 3 Ni 6 Si 2 and GdNiSi) is confirmed and three new compounds (GdNisub(0.2)Sisub(1.8), Gdsub(2)Nisub(1-0.8)Sisub(1-1.2), Gd 5 NiSi 4 ) are found. On the base of Gd 2 Si 3 compound up to 0.15 at. Ni fractions, an interstitial solid solution is formed up to 0.25 at Ni fractions dissolution continues of substitution type. The Gd-Ni-Si system is similar to the Y-Ni-Si system

  1. Internal carbonitriding behavior of Ni-V, Ni-Cr, and Ni-3Nb alloys

    International Nuclear Information System (INIS)

    Allen, A.T.; Douglass, D.L.

    1999-01-01

    Ni-2V, Ni-5V, Ni-12V, Ni-10Cr, Ni-20Cr, and Ni-3Nb alloys were carbonitrided in C 3 H 6 and NH 3 gas mixtures (bal H 2 ) over the range 700--1,000 C. Carbonitridation of Ni-12V and Ni-20Cr in C 3 H 6 /NH 3 /H 2 (1.5/1.5/97 v/o) and (1.5/10/88.5 v/o) produced duplex subscales consisting of near-surface nitrides with underlying carbides. Growth of each zone obeyed the parabolic rate law under most conditions. The presence of carbon generally did not effect the depth of the nitride zones compared to nitriding the alloys in NH 3 /H 2 (10/90 v/o). However, at 700 C, the nitride zones were deeper in the carbonitrided Ni-V alloys and Ni-20Cr. The presence of nitrogen generally increased the depth of the carbide zones in Ni-12V and Ni-20Cr compared to carburizing these alloys in C 3 H 6 /H 2 (1.5/98.5 v/o). VN, CrN, and NbN formed in Ni-V, Ni-Cr, and Ni-Nb alloys, respectively, whereas the underlying carbide layers contained V 4 C 3 in Ni-12V, Cr 3 C 2 above a zone of Cr 7 C 3 in Ni-20Cr, and NbC in Ni-3Nb. The solubilities and diffusivities of nitrogen and carbon in nickel were determined. Nitrogen and carbon each exhibited retrograde solubility with temperature in pure Ni in both carbonitriding environments. Nitrogen diffusion in nickel was generally lower in each carbonitriding mixture compared to nitrogen diffusion in a nitriding environment, except at 700 C when nitrogen diffusion was higher. Carbon diffusion in nickel was generally higher in the carbonitriding environments compared to carbon diffusion in a carburizing environment

  2. Nipah Virus (NiV)

    Science.gov (United States)

    ... Form Controls Cancel Submit Search the CDC Nipah Virus (NiV) Note: Javascript is disabled or is not ... gov . Recommend on Facebook Tweet Share Compartir Nipah virus (NiV) is a member of the family Paramyxoviridae , ...

  3. FY 1997 report of survey on the intellectual property in international collaboration research project; 1997 nendo chosa hokokusho (kokusai kyodo kenkyu ni okeru chiteki zaisanken ni tsuite no chosa hokokusho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In promoting international collaboration research project, coordination of the patent system of each country which participants to the project belong to has broad implications in concluding the contract for the project. For example, in Japan, 100% of the patent belongs to the government for contrast or collaboration project with the government. While, in the USA, the patent developed by the private company belongs to the private company even for the contrast project. In Japan, the shared patent can not be transferred to the third party or implemented without agreement with the partner. While, in the USA, the shared patent can be transferred to the third party or implemented without agreement with the partner. Due to such a difference, some projects can not be established by ill coordination of intellectual property even when the meaning of the projects is well understood. In this survey, was investigated the outline of patent systems of major countries to study about what should well balanced treatment of intellectual property in international collaboration research project be in the future. 4 figs., 8 tabs.

  4. Ni República parlamentaria ni presidencialista

    OpenAIRE

    Álvarez Tardío, Manuel

    2004-01-01

    Revista de Estudios Políticos (Nueva Época), Núm. 123. Enero-Marzo 2004 Este trabajo está dedicado al estudio de un aspecto básico del sistema político de la II República española (1931-1936): el modelo de presidencia de la República y de relaciones de la misma con el parlamento y el gobierno. Aquí se sostiene que la Segunda República, de acuerdo con su Constitución, no fue un régimen parlamentario ni presidencial. Combinó de forma extraña y ambigua elementos de ambos modelos. Probablement...

  5. FY 1974 report. Study on hydrogen combustion technology; 1974 nendo suiso nensho gijutsu ni kansuru kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-03-01

    In the use of hydrogen as fuel, there is the problem on NOx emission. The amount of NOx emission is not as much as in the use of coal or oil, but is more than in the use of natural gas or town gas. However, it can be said that hydrogen is an ideal fuel if considered that it does not emit other air pollutants such as CO, HC and soot/dust which are usually associated with hydrocarbon base gas fuels, and also that hydrogen forms a circulation system which is ecologically sound. The flame of hydrogen is non-luminous, but the flame temperature is high. The formation of NOx depends strongly upon the flame temperature, and therefore, in the design of hydrogen burner, it is necessary to well mix it with air and to avoid the production of the local high temperature region. Further, when using hydrogen to large boiler, the combustion technology to control NOx reduction is needed. About the hydrogen flame, the matter to be noticed is an experimental result that NOx reduction was observed by adding trace ammonia to hydrogen gas. If this method can be successful, NOx can be reduced with no increase in fuel consumption. It leads to hydrogen's reaching a position of clean energy. (NEDO)

  6. Report on survey/research on energy-related elementary techniques; Energy kanren yoso gijutsu ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The survey/research project is implemented for establishing environment-compatible energy systems in urban areas by constructing wide-area heat supply networks to exchange energy among cities. This project studies, taking Kanagawa Pref. as the model area, distributions of unutilized energy sources, and possibilities of their utilization for heat supply. There are large quantities of unutilized energy, including waste heat from power plants, general works and cleaning works, and low-temperature waste heat from, e.g., sewage and pumping systems. The district air conditioning promotion areas are selected from those consuming large quantities of heat energy in the prefecture, and their characteristics are grasped. The effects of the networks on total energy consumption of the entire prefecture are estimated for the cases of introducing the district air conditioning systems or wide-area heat supply networks in these selected areas. Introduction of optimum advanced heat utilization systems in stereotyped areas is also considered, in order to predict the effects of introduction of wide-area heat supply networks. (NEDO)

  7. Fiscal 2000 study on technology and marketability concerning phytoremediation; 2000 nendo phytoremediation ni kansuru gijutsu oyobi shijosei no chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    An investigative study was conducted on phytoremediation with the purpose of correcting soil contamination caused by heavy metals and the like. In Japan, in connection with the cadmium pollution along the Jintsugawa River region in Toyama Prefecture, a growth of botanical colony such as Athyrium ykoscense was confirmed having a high capacity in absorbing/accumulating heavy metals, with a possibility suggested that they may be utilized for phytoremediation. In a technological research for restoring the environment sustainingly in a wide area, feasibility has been proven to remove polluting agricultural chemicals in farmlands and toxic substance in old industrial sites by making forest trees like poplars, lawns and herbage function. In a project for the cleanup of oil contaminated soil after Gulf War, a demonstrative test of bioremediation for one hectare was performed and, after 15 month experiment, 80 to 90% of aliphatic compounds and 50 to 60% aromatic compounds were degraded. In EU Framework Program in Europe, phytoremediation projects have been implemented across the member countries. (NEDO)

  8. Trend of advanced technology of micromachines in the USA; Beikoku ni okeru micro machine sentan gijutsu doko chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    In this research, the data of advanced technology of micromachines in the USA have been searched, collected, and arranged from the US patent information, technical journal information, and newspaper and general journal information. According to demand, the main undertaking information was interviewed from well-informed persons. The data were compiled as advanced technology trend of micromachines in the USA. Sensors are remarkably predominant in the elemental technology. There are also important topics in the fields of actuators, motors, lenses, devices, and structures. On the other hand, materials, etchings, packages, motive powers, and softwares are also important elemental technology in spite of their less information. From the viewpoint of usage, detection systems are remarkably predominant. Then, robots, processing systems, optics, analysis systems, motive power systems, medical systems, and acoustic systems are also important. From the viewpoint of industrial sector, the environmental items are predominant. Automobiles, medical treatments, and information communications follow the above. When new relationships to the secondary usage and tertiary usage are not found, it would be rather hard to express such a technology development trend more clearly.

  9. International Workshop on Carbon Cycling and Coral Reef Metabolism; Sangosho no tanso junkan ni kansuru kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-16

    The paper described the International Workshop on Carbon Cycling and Coral Reef Metabolism which was held at Miyako-jima, Okinawa Pref. on October 17-24, 1995. In the workshop, researchers got together which are involved in marine chemistry, marine biology, coral ecology, and environmental science, and discussed the carbon cycling and metabolism of coral reef. Discussions were made on what the coral reef ecosystem is, and what the definition of a sink or a source for CO2 is. Also discussed were scales of how much time and space should be considered to make these issues clear. Further, it was proposed that it was necessary to investigate carbon balance of both the whole system and the components of the system and to keep track of mass transfer among neighboring components of the system. Seventeen presentations were given. The workshop obtained a definite consensus on carbon balance of the coral reef system. 123 refs., 39 figs., 9 tabs.

  10. Fiscal 1993 investigational report on heat pump heat storage technology; 1993 nendo heat pump chikunetsu gijutsu ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    This project is for an investigation into the heat pump (HP) use heat storage technology, with the aim of clarifying the present status of HP heat storage technology, the utilization status, and the developmental trend of technology and of contributing to the spread of heat energy effective use using HP heat storage technology and to the promotion of the technical development. Accordingly, the evaluation of the following was made: sensible heat (SH), latent heat (LH), chemical heat storage technology (CH), and heat storage technology (HS). Investigations were made on the sensible heat use heat storage technology of water, brine, stone, soil, etc. in terms of SH; the phase change sensible heat use heat storage technology of ice, hydrate salt, paraffins, etc. in terms of LH; hydration, hydroxide, 2-propanol pyrolysis, adsorption of silica gel, zeolite and water, and heat storage technology using metal hydride, etc. in terms of CH. In terms of HS, the following were studied and evaluated from the study results of the heat storage system in which HP is applied to the sensible heat and latent heat type heat storage technology: contribution to the power load levelling and the reduction of heat source capacity, heat recovery and the use of unused energy, improvement of the system efficiency by combining HP and heat storage technology. 24 refs., 242 figs., 56 tabs.

  11. Report on Asian Environment Information Network; 'Asia kankyo joho network' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The goal is the construction of Asian Environment Information Network (AEInet) in accordance with a contract signed between Indonesia's LIPI (Indonesian Institute of Science) and NEDO under NEDO's Research Cooperation Project Concerning the Development of Environment Measuring Laser Radar (LR). The network is so designed and constituted as to operate on a private line between Indonesia and Japan via IP (Internet protocol) and to enable the exchange on the Internet network of the data collected/analyzed by the Indonesian LR system and of articles of e-mail between scientists of the two countries. The AEInet will be utilized for the collection/analysis of LR-collected data; exchange of observed data and the result of processing; provision of support to environment information scientists in exchanging e-mail and information; and the search of databases for the implementation of the project. In this paper, the outline and functions of the system, network system design, WWW server construction, network operating status, joint researches with Indonesia, etc., are described. (NEDO)

  12. Report on the actual situations of the commercially applied, industrial robots; Sangyoyo robot ni kansuru kigyo jittai chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-08-01

    Described herein are the actual situations of industrial robots as the FY 1991 questionnaire survey results. The questionnaires were sent to 541 factories, and 74% thereof were recovered. The major machine types fall into categories of manual manipulator, stationary sequence manipulator, remote controlling robot, sequence robot, playback robot, numerically controlling robot and intelligent robot. They are mainly driven by hydraulic, pneumatic, or electrical power. Their mechanism types cover polar coordinate, cylindrical coordinate, rectangular coordinate and articulation types, among others. They are mainly controlled by electronically, electrically (hydraulic or relay), or pneumatically. The major purposes for general works include casting, forging, resin processing, heat treatment, pressing, welding, coating, machining, cutting, assembling, reception/delivery of goods, and testing/inspection. The special works they are in service include those for power/gas/water services, construction works, and research and development. By work step, they are in service, e.g., for loading/unloading goods, palletising/packing goods, supporting, screening, welding, spraying/coating, grinding, clamping, assembling, and riveting. (NEDO)

  13. Fiscal 1995 investigation on biological fixation of carbon dioxide; 1995 nendo seibutsuteki CO2 kotei ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    To cope with the global warming caused by CO2, an investigation was conducted into biological fixation. It is necessary to make a many-sided and comprehensive study on the mechanism of CO2 fixation, the scale (area and carbon holding density), the rate and the environmental impact of the introduction of the technology and the technical problems, and to make a quantitative evaluation of each of the methods in order to make them practical proposals. The global ecosystem is classified into the land biota and ocean biota, and each typical ecosystem was surveyed in terms of the surface area, the carbon holding amount (presently existing amount), the net primary production amount, the required nutrient salt amount, the transpiration rate, etc. Next, a discussion was made on the increasing effect of the carbon fixation amount by changing the present ecosystem from the aspect of scale and rate. At the same time, a study was carried out of energy efficiency, economical efficiency and problems. Last, elementary technology was taken up which seems to be important for implementing measures for the biological carbon fixation. As to the ocean, it is necessary to obtain information, which is not sufficient to utilize marine biota for CO2 fixation, especially on the mechanism of depth-direction transfer of organism and its quantitative grasp. As to the land, one of the measures is conversion of the ecosystem where the amount of carbon fixed is small to the ecosystem where the amount is large. 249 refs., 58 figs., 51 tabs.

  14. Report on an investigation into heat pumps in China in fiscal 1995; 1995 nendo Chugoku ni okeru heat pump system ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The paper surveyed the present status, the status of spread, and the technical development of the technology of heat pumps for residential and industrial uses in China. Main examples of installation of heat pumps are cited below: steam drive absorption type refrigerators in Beijing; sea water heat source turbo heat pumps in Qingdao; hot water drive absorption type refrigerators in Beijing; oil-fueled absorption type water cooling and heating appliances in Beijing; ice latent heat storage airconditioning systems using electrically-driven screw chiller in Beijing; temperature rising systems using electrically-driven heat pump of the solar energy utilization warm water swimming pool in Guangdong Province; cooling water supply using waste heat utilization absorption type refrigerator of the alcohol plant in Shandong Province; timber drying systems using electrically-driven heat pump, and marine product cultivation systems in Quangdong Province; distillation systems using steam turbine heat pump in Jiangxi Province. The demand for heat pumps is expected to be 20 million units under the 9th 5-year plan, and the development of equipment is thought to go toward promotion of energy conservation, low noise, multi-type or multi-functional air conditioning equipment, and computer use. 137 figs., 40 tabs.

  15. Fiscal 1999 survey report. Survey of leading countries' approaches to biomass energy development; 1999 nendo shuyokoku ni okeru biomass energy kaihatsu eno torikumi ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The survey aims to help Japan deliberate its future biomass energy development strategy including the course Japan is to follow in its research and development of biomass energy by clarifying leading countries' approaches to the subject matter and trends of their research and development efforts in this connection. The states of biomass energy development in the U.S. and Europe are reported. In the U.S., President Clinton issued Executive Order 13134 on August 12, 1999, regarding bio-based products and bioenergy development. In this country, bioenergy and bio-based production technologies have developed to reach a stage where business pays, and commercial plants are in service. The U.S. Administration mentions as a strategy the efficient development of the bioenergy industry. In Europe, where resources are versatile and local, it is difficult to assess the economy of scale, and small-scale development efforts are being accumulated. Practical technologies under development mostly involve direct combustion. European measures are similar to U.S. measures in that such political goals as local development and employment promotion are firmly woven into them. (NEDO)

  16. Fiscal 1994 survey report. Survey of recent trends in CFC phaseout measures overseas; 1994 nendo shogaikoku ni okeru freon taisaku saishin doko ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    Technical literature is referred to for the survey of recent trends in CFC (chlorofluorocarbon) phaseout in various countries overseas. The European Union will totally abolish CFC by the end of 1994 while other developed countries will totally abolish the same by the end of 1995 in compliance with the Montreal protocol. Many of the developing countries are actively striving to reduce CFC use with the help of the Multilateral Fund of Montreal. China and India have production facilities in themselves, and have not announced a phaseout program. There is a proposition for accelerating the regulation of HCFCs (hydrochlorofluorocarbons), but reliable substitutes for them are not yet available and their ozone layer restoring capability if used will be slight. It is feared that such will on the contrary retard CFC phaseout in developing countries. Accordingly, any abrupt acceleration of CFC phaseout implementation is inappropriate. Introduced in this report as fluorine-containing greenhouse gas-related information are a summary of the United Nations Framework Convention on Climate Change and the history of Intergovernmental Panel on Climate Change activities. According to an American survey, the aluminum industry emits 30,000 tons of CF{sub 4} and C{sub 2}F{sub 6}, and the semiconductor manufacturing industry 2,000-3,000 tons. As for SF{sub 6}, 5,000-8,000 tons are emitted mainly by the power industry. Measures for inhibiting them are being taken. (NEDO)

  17. Global environmental benefits of industrial heat pumps (fiscal 1993); 1993 nendo koon heat pumping gijutsu ni yoru chikyu ondanka keigen koka ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    An investigational study was conducted aiming at making a quantitative grasp of effects of the spread of industrial heat pumps on energy conservation and greenhouse gas reduction and at promoting the spread. Finally, the following eight countries joined this international joint research: Canada, France, Japan, Holland, Norway, Sweden, the U.K. and the U.S. Each country share the work and expenses for the research with each other. Japan made investigational researches on the application of heat pumps to processes of the chemical industry, oil refining industry, food industry, paper/pulp industry, and dyeing/weaving industry, and on the effects of greenhouse gas reduction. As procedures taken, values up to 2010 were estimated of energy prices in each country, energy supply/demand, rates of the heat source configuration for electric power supply, etc., the heat flow of the above-mentioned process was made clear, and analyses were conducted of annual profits, energy consumption, and depreciation period in the case of adopting heat pumps. Moreover, the energy conservation amount and greenhouse effect gas reduction amount were estimated based on the result of the analyses. 69 figs., 196 tabs.

  18. Report for fiscal 2000 investigations on effects imposed by introducing emission trading system; 2000 nendo haishutsuryo torihiki system donyu ni yoru eikyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With regard to effectiveness of the emission trading targeted to reduce the greenhouse effect gas emission, evaluation has been given from the three viewpoints: economies, environment, and household economy. In the research, simulations were implemented by using the GEC calculation model modified for introduction of domestic emission trading, and utilization of international emission trading. In evaluating the effects on industries and foreign trades, notice was given on the large energy consuming industries to discuss the effects of introducing the emission trading on the quantity of production and export. Regarding the effects on environment, calculations and discussions were given on greenhouse effect gas leakage rates to assess the greenhouse effect gas emission reducing effects from the domestic and international viewpoints. As a result of the discussions, it was found that the economies, environment and household economy are all benefited in regard with the domestic emission trading. Utilization of the international emission trading was also found to have sufficient positive benefit exist for the economies and household economy. (NEDO)

  19. Fiscal 1994 survey report. Survey of environmentally friendly chemical process (Ecochemistry); 1994 nendo kankyo ni yasashii kagaku hanno process (ecochemistry) ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    Processes that contain latent environmental problems are the massive generation of wastes (inorganic salt, acid catalyst, base catalyst, and huge quantities of wastewater), handling of dangerous substances (use of hydrogen fluoride, use of phosgene, and use of substances whose discharge is legally controlled), processes which consume much energy (circulation of quantities of raw materials, use of quantities of solvents, separation of products with difficulties, use of high pressure, and multiple stage reaction), and processes which are expected to use resources now remaining unexploited. As an element technology for the solution of problems, there is the development of a solid redox catalyst for liquid phase oxidation. As compared with a liquid phase homogeneous catalyst, it discharges less inorganic wastes, facilitates the separation, recovery, and treatment of inorganic salts, corrodes structural materials less, and is thermally stable. An alkane partial oxidation catalyst when developed will achieve more energy conservation than an alkene oxidation catalyst. In relation to acid/base reaction, the zeolite catalyst will be improved and ultrastrong acids and ultrastrong bases will be developed, and these will reduce wastes, mitigate corrosion, and facilitate product separation. The development of a process is also expected which will avoid the use of toxic phosgene. (NEDO)

  20. Microstructural development in NiAl/Ni-Si-B/Ni transient liquid phase bonds

    International Nuclear Information System (INIS)

    Gale, W.F.; Orel, S.V.

    1996-01-01

    A transmission electron microscopy (TEM) based investigation of microstructural development during transient liquid phase bonding of near-stoichiometric NiAl to commercial purity nickel is presented in this article. The work described employed Ni-4.5 wt pct Si-3.2 wt pct B (BNi-3) melt-spun interlayers. The precipitation of both Ni-Al based phases and borides within the joint and adjacent substrate regions is discussed. The article considers martensite formation (within the NiAl substrate) and the precipitation of L1 2 type phases (both within the joint and at the interface with the NiAl substrate). The relative roles of the two substrate materials (NiAl and Ni) in the isothermal resolidification process are identified. The preferential formation of Ni 3 B boride phases in the Ni substrate near the original location of the Ni substrate-joint interface is discussed and contrasted with the absence of similar events in the NiAl substrate

  1. Ni landsbyer i Danmark

    DEFF Research Database (Denmark)

    Larsen, Jacob Norvig

    Denne rapport beskriver en evaluering af statsstøttede forsøg med at styrke og udvikle mindre lokalsamfund. Forsøgene er gennemført i ni kommuner. Da der i disse år er stor opmærksomhed om de små byers og samfunds udviklingsmuligheder, har erfaringerne fra forsøgsprojekterne bred interesse. Forsø...

  2. Reduction mechanism of Ni2+ into Ni nanoparticles prepared from ...

    Indian Academy of Sciences (India)

    journal of. March 2009 physics pp. 577–586. Reduction mechanism of Ni2+ into Ni ..... and at high field, no domain wall is available and hence, the system becomes a .... [23] J Ding, T Tsuzuki, P G McCormick and R Street, J. Phys. D: Appl.

  3. Reactive Ni/Ti nanolaminates

    International Nuclear Information System (INIS)

    Adams, D. P.; Bai, M. M.; Rodriguez, M. A.; McDonald, J. P.; Jones, E. Jr.; Brewer, L.; Moore, J. J.

    2009-01-01

    Nickel/titanium nanolaminates fabricated by sputter deposition exhibited rapid, high-temperature synthesis. When heated locally, self-sustained reactions were produced in freestanding Ni/Ti multilayer foils characterized by average propagation speeds between ∼0.1 and 1.4 m/s. The speed of a propagating reaction front was affected by total foil thickness and bilayer thickness (layer periodicity). In contrast to previous work with compacted Ni-Ti powders, no preheating of Ni/Ti foils was required to maintain self-propagating reactions. High-temperature synthesis was also stimulated by rapid global heating demonstrating low ignition temperatures (T ig )∼300-400 deg. C for nanolaminates. Ignition temperature was influenced by bilayer thickness with more coarse laminate designs exhibiting increased T ig . Foils reacted in a vacuum apparatus developed either as single-phase B2 cubic NiTi (austenite) or as a mixed-phase structure that was composed of monoclinic B19 ' NiTi (martensite), hexagonal NiTi 2 , and B2 NiTi. Single-phase, cubic B2 NiTi generally formed when the initial bilayer thickness was made small.

  4. Electroplated Ni on the PN Junction Semiconductor

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Joo; Uhm, Young Rang; Son, Kwang Jae; Kim, Jong Bum; Choi, Sang Moo; Park, Jong Han; Hong, Jintae [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a Ni-63 plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 A were coated with Ni at current density from 10 to 50 mA cm{sup 2}. The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased.

  5. Electroplated Ni on the PN Junction Semiconductor

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Uhm, Young Rang; Son, Kwang Jae; Kim, Jong Bum; Choi, Sang Moo; Park, Jong Han; Hong, Jintae

    2015-01-01

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a Ni-63 plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 A were coated with Ni at current density from 10 to 50 mA cm 2 . The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased

  6. Synthesis and electrochemical behavior of nanostructured cauliflower-shape Co-Ni/Co-Ni oxides composites

    International Nuclear Information System (INIS)

    Gupta, Vinay; Kawaguchi, Toshikazu; Miura, Norio

    2009-01-01

    Nanostructured Co-Ni/Co-Ni oxides were electrochemically deposited onto stainless steel electrode by electrochemical method and characterized for their structural and supercapacitive properties. The SEM images indicated that the obtained Co-Ni/Co-Ni oxides had cauliflower-type nanostructure. The X-ray diffraction pattern showed the formation of Co 3 O 4 , NiO, Co and Ni. The EDX elemental mapping images indicated that Ni, Co and O are distributed uniformly. The deposited Co-Ni/Co-Ni oxides showed good supercapacitive characteristics with a specific capacitance of 331 F/g at 1 mA/cm 2 current density in 1 M KOH electrolyte. A mechanism of the formation of cauliflower-shape Co-Ni/Co-Ni oxides was proposed. A variety of promising applications in the fields such as energy storage devices and sensors can be envisioned from Co-Ni/Co-Ni oxides

  7. Radiochemical method for 63Ni

    International Nuclear Information System (INIS)

    Holm, E.; Nilsson, U.; Hallstadius, L.

    1985-01-01

    A radianalytical method for the determination of 63 Ni content in environmental samples of activated corrosion products is described. After chemical separation and electrodepositing of 63 Ni on silver briquets, the chemical yield is determined by X-ray fluorescence analysis. For the detection of low-energy beta activity, an open gas flow GM-counter with an anticoincidence guard counter is put to use

  8. Electronic structure of Ni/sub 3/Al and Ni/sub 3/Ga alloys

    CERN Document Server

    Pong, W F; Chang, Y K; Tsai, M H; Hsieh, H H; Pieh, J Y; Tseng, P K; Lee, J F; Hsu, L S

    1999-01-01

    This work investigates the charge transfer and Al(Ga) p-Ni d hybridization effects in the intermetallic Ni/sub 3/Al(Ni/sub 3/Ga) alloy using the NiL/sub 3.2/- and K-edge and Al(Ga)K X-ray absorption near edge structure (XANES) measurements. We find that the intensity of white-line features at the NiL/sub 3.2/-edge in the Ni/sub 3/Al(Ni /sub 3/Ga) alloy decreased in comparison with that of pure Ni, which can be attributed to the enhancement of Ni3d states filling and the depletion of the density of Ni 3d unoccupied states in the Ni/sub 3 /Al(Ni/sub 3/Ga) alloy. Two clear features are also observed in the Ni/sub 3/Al(Ni/sub 3/Ga) XANES spectrum at the Al(Ga) K-edge, which can be assigned to the Al(Ga) unoccupied 3p (4p) states and their hybridized states with the Ni 3d/4sp states above the Fermi level in Ni/sub 3/Al(Ni/sub 3/Ga). The threshold at Al K-edge XANES for Ni/sub 3/Al clearly shifts towards higher photon energies relative to that of pure Al, indicating that Al loses charges upon forming Ni/sub 3 /Al. ...

  9. Nitriding behavior of Ni and Ni-based binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Fonovic, Matej

    2015-01-15

    Gaseous nitriding is a prominent thermochemical surface treatment process which can improve various properties of metallic materials such as mechanical, tribological and/or corrosion properties. This process is predominantly performed by applying NH{sub 3}+H{sub 2} containing gas atmospheres serving as the nitrogen donating medium at temperatures between 673 K and 873 K (400 C and 600 C). NH{sub 3} decomposes at the surface of the metallic specimen and nitrogen diffuses into the surface adjacent region of the specimen whereas hydrogen remains in the gas atmosphere. One of the most important parameters characterizing a gaseous nitriding process is the so-called nitriding potential (r{sub N}) which determines the chemical potential of nitrogen provided by the gas phase. The nitriding potential is defined as r{sub N} = p{sub NH{sub 3}}/p{sub H{sub 2}{sup 3/2}} where p{sub NH{sub 3}} and p{sub H{sub 2}} are the partial pressures of the NH{sub 3} and H{sub 2} in the nitriding atmosphere. In contrast with nitriding of α-Fe where the nitriding potential is usually in the range between 0.01 and 1 atm{sup -1/2}, nitriding of Ni and Ni-based alloys requires employing nitriding potentials higher than 100 atm{sup -1/2} and even up to ∞ (nitriding in pure NH{sub 3} atmosphere). This behavior is compatible with decreased thermodynamic stability of the 3d-metal nitrides with increasing atomic number. Depending on the nitriding conditions (temperature, nitriding potential and treatment time), different phases are formed at the surface of the Ni-based alloys. By applying very high nitriding potential, formation of hexagonal Ni{sub 3}N at the surface of the specimen (known as external nitriding) leads to the development of a compound layer, which may improve tribological properties. Underneath the Ni{sub 3}N compound layer, two possibilities exist: (i) alloying element precipitation within the nitrided zone (known as internal nitriding) and/or (ii) development of metastable and

  10. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    International Nuclear Information System (INIS)

    Holec, D.; Bojda, O.; Dlouhy, A.

    2008-01-01

    Non-uniform distributions of Ni 4 Ti 3 precipitate crystallographic variants are investigated in a Ni-rich NiTi shape memory alloy after aging, assisted by external stress. A finite-element method model is presented that considers the elastic anisotropy of the B2 parent phase and also mutual misorientations of grains in a polycrystalline sample. On loading by the external stress, the stress is redistributed in the microstructure and the precipitation of some Ni 4 Ti 3 crystallographic variants becomes distinctly favorable in grain boundary regions since these variant configurations minimize the elastic interaction energy. The volume fraction of the affected grain boundary regions is calculated and the numerical results are compared with the data obtained by differential scanning calorimetry and transmission electron microscopy

  11. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    Czech Academy of Sciences Publication Activity Database

    Holec, David; Bojda, Ondřej; Dlouhý, Antonín

    2008-01-01

    Roč. 481, Sp. Iss. (2008), s. 462-465 ISSN 0921-5093. [ESOMAT 2006. Bochum, 10.09.2006-15.09.2006] R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitates * Multi-step martensitic transformations Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.806, year: 2008

  12. Electronic structure of Ni-- and Ni2--ethylene cluster complexes

    International Nuclear Information System (INIS)

    Basch, H.; Newton, M.D.; Moskowitz, J.W.

    1978-01-01

    The electronic structure of metal cluster--ethylene complexes has been investigated by carrying out ab initio bonding pair-correlated, self-consistent field, and configuration interaction (CI) calculations on the NiC 2 H 4 and Ni 2 C 2 H 4 species. The π-NiC 2 H 4 and π-Ni 2 C 2 H 4 cluster complexes are found to be bound, the former only with CI, while disigma-Ni 2 C 2 H 4 has only a repulsive Ni 2 --C 2 H 4 ground state potential curve. The bonding in the π-type cluster complexes can be described as follows: The metal atom configuration is 3d 9 4s 1 with the 4s hybridized (by the metal 4p) away from the ethylene molecule, thereby allowing the π orbital to form a dative sigma bond with the metal atom. The bonding interaction is promoted by the presence of a second nickel atom behind the first one, leading to a 4s orbital electron deficiency of the bonded nickel atom and thus making this nickel atom a better electron acceptor. Back donation from the occupied metal 3d into the ethylene π* molecular orbital also takes place to some extent, and thus both features of the classical Dewar--Chatt--Duncanson model are observed. The π-Ni 2 C 2 H 4 species is analyzed in terms of the addition of a bare nickel atom to a π-NiC 2 H 4 cluster complex, with concomitant stabilization of the orbitals of the bonded nickel atom. A study of the excited electronic states of π-NiC 2 H 4 shows that low-lying 4s→π* and 3d→π* (M→L) charge transfer transitions are predicted. The former is not observed experimentally, probably due to the diffuse nature of the 4s orbital. The relationship between small cluster--ethylene complex systems and ethylene chemisorption on a nickel metal surface is discussed

  13. Radioactive 63Ni in biological research

    International Nuclear Information System (INIS)

    Kasprzak, K.S.; Sunderman, F.W. Jr.

    1979-01-01

    Applications of 63 Ni in biological research are reviewed, with emphasis upon recent investigations of nickel metabolism and toxicology in experimental animals. The radiochemistry of 63 Ni is summarized, including consideration of the preparation of certain 63 Ni compounds (e.g. 63 Ni(CO) 4 and 63 Ni 3 S 2 ) that are of current interest in toxicology, teratology and cancer research. Practical guidance is given regarding the detection and determination of 63 Ni in biological materials by autoradiography and liquid scintillation spectrometry. (author)

  14. Superstructure of NiAs

    International Nuclear Information System (INIS)

    Nozue, Tatsuhiro; Kobayashi, Hisao; Kamimura, Takashi; Yamaguchi, Yasuo

    2001-01-01

    The structural transition in NiAs was studied by neutron diffraction on the single crystalline sample. The crystal structure of NiAs has been reported to be bottom-centered orthorhombic with Cmc2 1 symmetry (niccolite-type). The measurement of temperature dependence of the powder X-ray diffraction revealed that NiAs undergoes a structural transition to the NiAs-type at T t =335 K. In present neutron diffraction experiment at room temperature, we observed the reflections indexed on the basis of the orthorhombic unit cell. The intensities of these reflections are qualitatively explained in terms of the niccolite-type structure with taking account of three domain structures, except for the weak reflections indexed as (001), (003) and (012). Then, the intensities of (001), (002) and (004) reflections were measured in temperature range of 20 to 420 K. The temperature dependences of (002) and (004) reflections qualitatively agree with those of the calculated intensities using the atomic positions of niccolite-type structure. However, the temperature dependence of (001) reflection shows the anomaly around T t , which suggests the symmetry of crystal structure of NiAs is not the Cmc2 1 symmetry. (author)

  15. Thermal stability and electrical characteristics of NiSi films with electroplated Ni(W) alloy

    International Nuclear Information System (INIS)

    Xin Yuhang; Hu Anmin; Li Ming; Mao Dali

    2011-01-01

    In this study, an electroplating method to deposited Ni, crystalline NiW(c-NiW), amorphous NiW (a-NiW) films on P-type Si(1 0 0) were used to form Ni-silicide (NiSi) films. After annealed at various temperatures, sheet resistance of Ni/Cu, c-NiW/Cu and a-NiW/Cu was measured to observe the performance of those diffusion barrier layers. With W added in the barrier layer, the barrier performance was improved. The results of XRD and resistance measurement of the stacked Si/Ni(W)/Cu films reveal that Cu atom could diffuse through Ni barrier layer at 450 deg. C, could diffuse through c-NiW at 550 deg. C, but could hardly diffuse through a-NiW barrier layer. c-NiW layer has a better barrier performance than Ni layer, meanwhile the resistance is lower than a-NiW layer.

  16. Giant magnetoimpedance effect in sputtered single layered NiFe film and meander NiFe/Cu/NiFe film

    International Nuclear Information System (INIS)

    Chen, L.; Zhou, Y.; Lei, C.; Zhou, Z.M.; Ding, W.

    2010-01-01

    Giant magnetoimpedance (GMI) effect on NiFe thin film is very promising due to its application in developing the magnetic field sensors with highly sensitivity and low cost. In this paper, the single layered NiFe thin film and NiFe/Cu/NiFe thin film with a meander structure are prepared by the MEMS technology. The influences of sputtering parameters, film structure and conductor layer width on GMI effect in NiFe single layer and meander NiFe/Cu/NiFe film are investigated. Maximum of the GMI ratio in single layer and sandwich film is 5% and 64%, respectively. The results obtained are useful for developing the high-performance magnetic sensors based on NiFe thin film.

  17. High Ni in Archean tholeiites

    Science.gov (United States)

    Arndt, Nicholas T.

    1991-03-01

    Archean tholeiites generally have higher Ni, Co. Cr and Fe than most younger tholeiites with similar MgO contents. These characteristics cannot be attributed to high T or P batch melting in the Archean mantle, because, although such melts are enriched in siderophile elements, they have higher MgO than normal tholeiites. As primary melts fractionate to lower MgO, they lose Ni, Co and Cr. Nor can the differences between Archean and younger tholeiites be attributed to secular variation in mantle compositions because Archean komatiites have Ni, Co, Cr contents similar to modern (Gorgona) komatiites. It is suggested that the high siderophile element content of Archean tholeiites results from mixing of either komatiitic with basaltic magmas, as might occur in an ascending, melting mantle plume or column, or of komatiite and more evolved rocks, as may take place when komatiite encounters and assimilates crustal rocks.

  18. FY1998 research report on the basic research on geothermal district heating in Kamchatka, Russia; 1998 nendo Roshia Renpo Kamchatka shu ni okeru chinetsu riyo ni yoru chiiki danbo ni kansuru kiso chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-05-01

    Petropavlovsk-Kamchatky (P-K) city in Kamchatka, Russia is operating hot-water district heating using heavy oil boilers and waste hot water of thermal power plants as heat sources. Feasibility study was made on district heating using natural geothermal hot water and/or geothermal heat pump systems as heat sources of hot water supply for reduction of greenhouse effect gas emission. Among 3 areas including geothermal hot water, use of hot water in K area was impossible because of lower temperature and less spring water. Use of hot water in P and UP areas was impossible as primary hot water because of temperature drop to 64 degrees C during hot water supply toward P-K city. The building heating operation test was carried out using the geothermal heat pump system installed in a newly drilled heat exchange well of 100m deep. As a result, sufficient heat recovery was achieved for heating. If all of 49 boiler houses for heating are replaced with such geothermal heat pump systems, CO{sub 2} reduction was estimated to be 520,000t/y. (NEDO)

  19. Relation between shape of Ni-particles and Ni migration in Ni-YSZ electrodes – a hypothesis

    DEFF Research Database (Denmark)

    Mogensen, Mogens Bjerg; Hauch, Anne; Sun, Xiufu

    2016-01-01

    This is an attempt to explain a phenomenon of total depletion of Ni next to the electrolyte in Ni-YSZ cermet electrodes in solid oxide electrolysis cells during electrolysis at high current density/overpotential. Intuitively, we would think that Ni would always migrate down the steam partial...

  20. Ni-NiO core-shell inverse opal electrodes for supercapacitors.

    Science.gov (United States)

    Kim, Jae-Hun; Kang, Soon Hyung; Zhu, Kai; Kim, Jin Young; Neale, Nathan R; Frank, Arthur J

    2011-05-14

    A general template-assisted electrochemical approach was used to synthesize three-dimensional ordered Ni core-NiO shell inverse opals (IOs) as electrodes for supercapacitors. The Ni-NiO IO electrodes displayed pseudo-capacitor behavior, good rate capability and cycling performance. © The Royal Society of Chemistry 2011

  1. CONFIGURATION-INTERACTION IN NI METAL AND NI-ALLOYS AND HIGH-ENERGY SPECTROSCOPY

    NARCIS (Netherlands)

    TANAKA, A; JO, T; SAWATZKY, GA

    We discuss the electronic state of Ni atoms in Ni metal and of Ni impurity in Cu and Au metals from the viewpoint of 3d configuration interaction (CI) using the Anderson impurity model including atomic multiplets. On the basis of the discussion, we give an interpretation for the Ni 2p-core X-ray

  2. Iodine capture by Hofmann-type clathrate Ni(II)(pz)[Ni(II)(CN)_4

    International Nuclear Information System (INIS)

    Massasso, Giovanni; Long, Jerome; Haines, Julien; Devautour-Vinot, Sabine; Maurin, Guillaume; Larionova, Joulia; Guerin, Christian; Guari, Yannick; Grandjean, Agnes; Onida, Barbara; Donnadieu, Bruno

    2014-01-01

    The thermally stable Hofmann-type clathrate framework Ni(II)(pz)[Ni(II)(CN)_4] (pz = pyrazine) was investigated for the efficient and reversible sorption of iodine (I_2) in the gaseous phase and in solution with a maximum adsorption capacity of 1 mol of I_2 per 1 mol of Ni(II)pz)[Ni(II)(CN)_4] in solution. (authors)

  3. Density functional theory study of the interfacial properties of Ni/Ni3Si eutectic alloy

    International Nuclear Information System (INIS)

    Zhao, Yuhong; Wen, Zhiqin; Hou, Hua; Guo, Wei; Han, Peide

    2014-01-01

    In order to clarify the heterogeneous nucleation potential of α-Ni grains on Ni 3 Si particles in Ni-Ni 3 Si eutectic alloy, the work of adhesion (W ad ), fracture toughness (G), interfacial energy (γ i ), and electronic structure of the index (0 0 1), (1 1 0) and (1 1 1) Ni/Ni 3 Si interfaces with two different cohesive manners are investigated using first-principles method based on density functional theory. Results indicate that the center site stacking sequence (OM) is preferable to continue the natural stacking sequence of bulk Ni and Ni 3 Si. Since OM stacking interfaces have larger W ad , G and γ i than that of the top site stacking (OT) interfaces. The Ni/Ni 3 Si (1 1 0) interface with OM stacking has the best mechanical properties. Therefore, the formation of this interface can improve the stability, ductility and fracture toughness of Ni-Ni 3 Si eutectic alloy. The calculated interfacial energy of Ni/Ni 3 Si (0 0 1), (1 1 0) and (1 1 1) interfaces with OM stacking proves the excellent nucleation potency of Ni 3 Si particles for α-Ni phase from thermodynamic considerations. Besides, the electronic structure and chemical bonding of (1 1 0) interface with OM stacking are also discussed.

  4. Density of Liquid Ni-Cr Alloy

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The density of liquid Ni-Cr alloy was measured by a modified sessile drop method. The density of liquid Ni-Cr alloywas found to decrease with increasing temperature and Cr concentration in the alloy. The molar volume of liquidNi-Cr alloy increases with increasing the Cr concentration in the alloy. The molar volume of Ni-Cr alloy determinedin the present work shows a positive deviation from the linear molar volume.

  5. Laser alloyed Al-Ni-Fe coatings

    CSIR Research Space (South Africa)

    Pityana, SL

    2008-10-01

    Full Text Available The aim of this work was to produce crack-free thin surface layers consisting of binary (Al-Ni, Al-Fe) and ternary (Al-Ni-Fe) intermetallic phases by means of a high power laser beam. The laser surface alloying was carried out by melting Fe and Ni...

  6. Fiscal 1998 research report. Research on the possibility of promoting CDM project through technology transfer with plant exports; 1998 nendo chosa hokokusho. Plant yushutsugata gijutsu iten wo tsujita CDM project suishin kanosei ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Study was made on promotion of CDM (clean development mechanism) project through technology transfer with plant exports. Although CDM system was provided in COP3 on climate change held in Kyoto in 1997, its detailed rules including project approval are yet undecided, and only the schedule to provide the detailed rules until COP6 in 2000 was decided in COP4 in 1998. The common recognition that the CDM project with plant exports produces various merits for both Japan and the partner country is increasing. However, from the viewpoint of forming concrete CDM projects, most Japanese enterprises are passive in approach to the CDM project because of no detailed design of CDM, uncertain profitability and procedures, and avoidance of additional burdens. Plant export is also difficult because of the fact that assessment of a new project is difficult. Enterprises' deeper recognition on the CDM project, and a governmental integrated support system are desirable. (NEDO)

  7. Research report of fiscal 1997. Study on total energy and material control (feasibility study on circulating society); 1997 nendo chosa hokokusho. Total energy and material control ni kansuru chosa (junkangata shakai kochiku kanosei chosa) chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In order to construct real sustainable global environment and human society in the 21st century called the century of environment, not only the innovation of manufacturing processes technically supporting such the construction but also the conception including the innovation of the whole society from a wide viewpoint are essential. As a total energy and material control system (TEMCOS) concept, the view of an energy-saving circulating society is attempted which minimizes a total energy and material flow in Japan, and the role and issue of manufacturing industry, in particular, material industry are extracted. As one of the targets of such a concept, the conception of an eco-town is also described. Paying attention on some important material industries including a mass material flow and consuming a large amount of energy such as metal, plastics and automobile industries, the study result on a material flow for every industry is arranged, and some effective issues contributing to minimize a material flow and control energy consumption and CO2 emission are extracted. 80 refs., 67 figs., 30 tabs.

  8. Fiscal 1997 survey report on the trend of global warming protection measures of substituting freons; 1997 nendo chosa hokokusho (daitai freon no chikyu ondanka taisaku doko ni kansuru chosa hokokusho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The trend survey was conducted of global warming protection measures by participation in international conferences, scientific society meetings and lecture meetings, and by literature surveys. We participated in the international conference on ozonosphere protection measures. In the 9th meeting of the nations which concluded the Montreal Protocol, the strengthening of restrictions on methyl bromide was decided on. In the UNEP solvent technology selection conference and the OORG conference of the World Bank, reports were made on substituting solvents in Japan, activities supporting developing countries, and the developmental trend of urethane use foaming agent. In the international conference on ozonosphere protection measures, introduced were the present status of Japan`s ODA for developing countries and examples of success of the substitution in the solvent field. The paper included nine reports on CFC destruction technology related literature made public in the past one year. The paper also introduced a comparative study of de-HCFC substituting technology at U.S. Oak Ridge National Laboratory, U.S. EPA`s prediction of emission of fluorine 3 gas, the predicted value of HFC emission and trial calculation of contributing rate in all greenhouse gases by IIR, Green Peace and Elf Atochem, and NOAA`s measured data on SF6 in the atmosphere. 49 refs., 46 figs., 26 tabs.

  9. Fiscal 1998 research report on information structuring technology for advanced use of NEDO research reports; 1998 nendo NEDO seika hokokusho nado no kodo riyo ni hitsuyona joho kozoka gijutsu no chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Research was made on electronic NEDO research reports corresponding to the recent extending trend of Internet. The logical structure and electronic format of NEDO research reports as document were first studied considering document disclosure and reuse of technical information. HTML as electronic format for Internet is unfortunately insufficient to describe the logical structure of NEDO research reports because of HTML's restricted description. Thus, XML which is being watched because of its possible definition of original tags was studied in place of HTML. As a result, because at present preparation of standards on XML and a compatibility for implementation of standards are insufficient, it was concluded that construction of the electronic document system for NEDO research reports is still too early. However, since adoption of XML as document format is important from the viewpoint of a property succession on Internet, preparation of the XML format file of NEDO research reports is essential. (NEDO)

  10. FY 2000 report on the survey of technological strategy for the creation of the robot society in the 21st century; 2000 nendo chosa hokokusho. 21 seiki ni okeru robot shakai sozo no tameno gijutsu senryaku chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-05-01

    For the purpose of constructing the future-oriented robot technology system and clarifying the robot technology strategy viewed from the necessity, contribution and marketability in the society, investigational study was made by the special committee for technology strategy survey. In the section meeting for the needs, the following 5 working groups had a grasp of the needs: reinforcement of production technology; bio-industry; medical act support; how to cope with disasters; life support. Based on the results of the analysis of factors of the successful manufacture of industrial robots during the 1980s - 1990s, the quantitative estimate of the market was made as much as possible. Further, in the section meeting for the seeds, the 6 working groups were set up, and they conducted the trend survey/analysis of the development of element technology of robot in Japan and abroad, the extraction of developmental subjects, etc. As a result, the following were specified as the seeds to be emphasized: construction of the remotely distributed system using network; nano-handling technology; sensitivity interface/human behavior comprehension technology/simulation technology, robot vision, moving technology, advanced manipulation technology. (NEDO)

  11. Nanostructure analysis of friction welded Pd-Ni-P/Pd-Cu-Ni-P metallic glass interface

    International Nuclear Information System (INIS)

    Ohkubo, T.; Shoji, S.; Kawamura, Y.; Hono, K.

    2005-01-01

    Friction welded Pd 40 Ni 40 P 20 /Pd 40 Cu 30 Ni 10 P 20 metallic glass interface has been characterized by energy filtering transmission electron microscopy. The interface is fully amorphous with a gradual compositional change of Cu and Ni in the range of 30 nm. By annealing above T g , the interdiffusion of Cu and Ni progressed in the supercooled liquid region, and the crystallization occurred from the Pd 40 Ni 40 P 20 glass

  12. Study of dipole interaction in micron-width NiFe/Cu/NiFe/NiO wire using exchange anisotropy

    International Nuclear Information System (INIS)

    Kimura, Takashi; Itagaki, Yoshio; Wakaya, Fujio; Gamo, Kenji

    2001-01-01

    The dipole interaction between a NiFe layer pinned by a NiO and a free NiFe layer in a micron-wide NiFe/Cu/NiFe/NiO wire was studied by changing the direction of the exchange bias from the NiO layer. The effect of the dipole interaction when the exchange bias was perpendicular to the wire axis was larger than that when the exchange bias was parallel to the wire axis, and was consistently explained by the stray field caused by the magnetic charges of the pinned layer. It was demonstrated that this method, using exchange anisotropy, is useful for investigating the dipole interaction between ferromagnetic materials separated by a nonmagnetic material in small-scale magnetic multilayers. [copyright] 2001 American Institute of Physics

  13. Effects of Ni particle morphology on cell performance of Na/NiCl2 battery

    Science.gov (United States)

    Kim, Mangi; Ahn, Cheol-Woo; Hahn, Byung-Dong; Jung, Keeyoung; Park, Yoon-Cheol; Cho, Nam-ung; Lee, Heesoo; Choi, Joon-Hwan

    2017-11-01

    Electrochemical reaction of Ni particle, one of active cathode materials in the Na/NiCl2 battery, occurs on the particle surface. The NiCl2 layer formed on the Ni particle surface during charging can disconnect the electron conduction path through Ni particles because the NiCl2 layer has very low conductivity. The morphology and size of Ni particles, therefore, need to be controlled to obtain high charge capacity and excellent cyclic retention. Effects of the Ni particle size on the cell performance were investigated using spherical Ni particles with diameters of 0.5 μm, 6 μm, and 50 μm. The charge capacities of the cells with spherical Ni particles increased when the Ni particle size becomes smaller because of their higher surface area but their charge capacities were significantly decreased with increasing cyclic tests owing to the disconnection of electron conduction path. The inferior cyclic retention of charge capacity was improved using reticular Ni particles which maintained the reliable connection for the electron conduction in the Na/NiCl2 battery. The charge capacity of the cell with the reticular Ni particles was higher than the cell with the small-sized spherical Ni particles approximately by 26% at 30th cycle.

  14. One dimensional motion of interstitial clusters and void growth in Ni and Ni alloys

    Science.gov (United States)

    Yoshiie, T.; Ishizaki, T.; Xu, Q.; Satoh, Y.; Kiritani, M.

    2002-12-01

    One dimensional (1-D) motion of interstitial clusters is important for the microstructural evolution in metals. In this paper, the effect of 2 at.% alloying with elements Si (volume size factor to Ni: -5.81%), Cu (7.18%), Ge (14.76%) and Sn (74.08%) in Ni on 1-D motion of interstitial clusters and void growth was studied. In neutron irradiated pure Ni, Ni-Cu and Ni-Ge, well developed dislocation networks and voids in the matrix, and no defects near grain boundaries were observed at 573 K to a dose of 0.4 dpa by transmission electron microscopy. No voids were formed and only interstitial type dislocation loops were observed near grain boundaries in Ni-Si and Ni-Sn. The reaction kinetics analysis which included the point defect flow into planar sink revealed the existence of 1-D motion of interstitial clusters in Ni, Ni-Cu and Ni-Ge, and lack of such motion in Ni-Si and Ni-Sn. In Ni-Sn and Ni-Si, the alloying elements will trap interstitial clusters and thereby reduce the cluster mobility, which lead to the reduction in void growth.

  15. First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    International Nuclear Information System (INIS)

    Yun-Jiang, Wang; Chong-Yu, Wang

    2009-01-01

    A model system consisting of Ni[001](100)/Ni 3 Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni 3 Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni 3 Al multilayer can be well predicted by the Voigt–Reuss–Hill rule of mixtures. (classical areas of phenomenology)

  16. Flowsheet for 63Ni production

    International Nuclear Information System (INIS)

    Williams, D.F.; Knauer, J.B.; O'Kelley, G.D.; Wiggins, J.T.; Porter, C.E.

    1992-01-01

    The production of large quantities of high specific activity 63 Ni (>10Ci/g) requires both a highly enriched 62 Ni target and a long irradiation period at high neutron flux. Trace impurities in the nickel and associated target materials are also activated and account for a significant fraction of the discharged activity and essentially all of the gamma activity. While most of these undesirable activation products (mainly transition metals) can be easily removed as chloride complexes during anion exchange, chromium, present as 51 Cr, and manganese, present as 54 Mn, are exceptions and require solvent extraction of the in-cell product to achieve the desired purity. In addition to summarizing the current development and production experience, optimized flowsheets are discussed

  17. Microstructural investigations of Ni and Ni2Al3 coatings exposed in biomass power plants

    DEFF Research Database (Denmark)

    Wu, D. L.; Dahl, K. V.; Christiansen, T. L.

    2018-01-01

    The present work investigates the corrosion resistance of Ni and Ni2Al3 coated austenitic stainless steel (TP347H) tubes, which were exposed in a biomass-fired boiler with an outlet steam temperature of 540 °C for 6757 h. The Ni2Al3 coating was produced by electroplating Ni followed by low...... temperature pack cementation. After exposure, microstructural investigations were performed by light optical and electron microscopy (SEM-EDS). Electroplated Ni coatings were not protective in straw firing power plants and exhibited similar corrosion morphology as uncoated tubes. For Ni2Al3 coatings...

  18. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Gagorowska, B; Dus-Sitek, M [Institute of Physics, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Czestochowa (Poland)

    2007-08-15

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d{sub Cu} = 2 nm) and the thickness of Ni layer - variable (1 nm {<=} d{sub Ni} {<=} 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent.

  19. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    International Nuclear Information System (INIS)

    Gagorowska, B; Dus-Sitek, M

    2007-01-01

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d Cu = 2 nm) and the thickness of Ni layer - variable (1 nm ≤ d Ni ≤ 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent

  20. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition; Etude exclusive des collisions centrales Ni+Ni et Ni+Au: coexistence de phase et decomposition spinodale

    Energy Technology Data Exchange (ETDEWEB)

    Guiot, B

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  1. niños preescolares

    Directory of Open Access Journals (Sweden)

    Claudia Rosario Portilla Ramírez

    2007-01-01

    Full Text Available Este estudio explora la relación entre la escritura y la comprensión de la referencia a través de una tarea de sinonimia en niños entre 5 y 6 años de edad, de origen latinoamericano, escolarizados en Barcelona (España. Las variables relacionadas con la tarea de sinonimia fueron (a la comprensión de la entidad lingüística nombre y (b el nivel de conceptualización de la escritura de los niños y la presencia de etiquetas escritas durante la tarea. Para la tarea de sinonimia se utilizaron pares de sinónimos dialectales del español (de Latinoamérica y de la Península Ibérica. Los resultados mostraron una diferenciación en el razonamiento de los niños, la cual dependía de la comparación entre lenguaje oral y lenguaje escrito en el desarrollo de la tarea, evidenciando una mayor aceptación de la sinonimia en la modalidad de lenguaje oral que en la modalidad de lenguaje escrito.

  2. Reinvestigation of 56Ni decay

    International Nuclear Information System (INIS)

    Sur, B.; Norman, E.B.; Lesko, K.T.; Browne, E.; Larimer, R.

    1990-01-01

    In a series of experiments, we have reinvestigated the decay of the doubly magic nucleus 56 Ni, which is believed to be copiously produced in supernovae. We have confirmed its previously known decay scheme and half-life, and have searched for several rare decay modes. We establish an upper limit of 5.8x10 -7 for the branching ratio of the second forbidden unique β + decay to the 158-keV level in 56 Co, leading to a lower limit of 2.9x10 4 yr for the half-life of fully ionized 56 Ni nuclei in cosmic rays. We also establish an upper limit of 5.0x10 -3 for the branching ratio of the isospin forbidden Fermi electron capture transition to the 1451-keV level in 56 Co, which in turn leads to an upper limit of 124 keV for the isospin mixing Coulomb matrix element of the 56 Ni ground state

  3. On the nature of Ni···Ni interaction in a model dimeric Ni complex.

    Science.gov (United States)

    Kamiński, Radosław; Herbaczyńska, Beata; Srebro, Monika; Pietrzykowski, Antoni; Michalak, Artur; Jerzykiewicz, Lucjan B; Woźniak, Krzysztof

    2011-06-07

    A new dinuclear complex (NiC(5)H(4)SiMe(2)CHCH(2))(2) (2) was prepared by reacting nickelocene derivative [(C(5)H(4)SiMe(2)CH=CH(2))(2)Ni] (1) with methyllithium (MeLi). Good quality crystals were subjected to a high-resolution X-ray measurement. Subsequent multipole refinement yielded accurate description of electron density distribution. Detailed inspection of experimental electron density in Ni···Ni contact revealed that the nickel atoms are bonded and significant deformation of the metal valence shell is related to different populations of the d-orbitals. The existence of the Ni···Ni bond path explains the lack of unpaired electrons in the complex due to a possible exchange channel.

  4. Synthesis of Ni core NiO shell nanostructure and magnetic investigation for shell thickness determination

    International Nuclear Information System (INIS)

    Arabi, H.; Bruck, E.; Tichelaar, F.D.

    2007-01-01

    Full text: Nickel oxide has received a considerable amount of attention in recent years for its catalytic, electronic and magnetic properties. Ni nanoparticles with an average size of 8 nm were prepared by dc - arc discharge in argon atmosphere. A current of 130 A and 300 milli bar pressure of argon have been applied. The produced Ni nanoparticles were annealed for oxidizing in air at 350 for six hours to produce antiferromagnetic NiO particles. The structure of Ni and NiO nanoparticles and size estimation of them studied by means of X-ray diffraction. The size and morphology of the particles were also characterized by high resolution transmission microscopy (TEM). The Ni core NiO shell structure, resulting from the oxidation process, were studied by magnetic properties measurements. A quantum design squid magnetometer, model MPMS5S was used for measuring saturation magnetization of both nanoparticles of Ni with and without NiO layer. By knowing the density of Ni and NiO, we were able to deduce the thickness of the Ni core and NiO outer layer. They are around 3 and 5 nanometers respectively. (authors)

  5. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition

    International Nuclear Information System (INIS)

    Guiot, B.

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  6. Atomistic calculations of hydrogen interactions with Ni3Al grain boundaries and Ni/Ni3Al interfaces

    International Nuclear Information System (INIS)

    Baskes, M.I.; Angelo, J.E.; Moody, N.R.

    1995-01-01

    Embedded Atom Method (EAM) potentials have been developed for the Ni/Al/H system. The potentials have been fit to numerous properties of this system. For example, these potentials represent the structural and elastic properties of bulk Ni, Al, Ni 3 Al, and NiAl quite well. In addition the potentials describe the solution and migration behavior of hydrogen in both nickel and aluminum. A number of calculations using these potentials have been performed. It is found that hydrogen strongly prefers sites in Ni 3 Al that are surrounded by 6 Ni atoms. Calculations of the trapping of hydrogen to a number of grain boundaries in Ni 3 Al have been performed as a function of hydrogen chemical potential at room temperature. The failure of these bicrystals under tensile stress has been examined and will be compared to the failure of pure Ni 3 Al boundaries. Boundaries containing a preponderance of nickel are severely weakened by hydrogen. In order to investigate the potential embrittlement of γ/γ' alloys, trapping of hydrogen to a spherical Ni 3 Al precipate in nickel as a function of chemical potential at room temperature has been calculated. It appears that the boundary is not a strong trap for hydrogen, hence embrittlement in these alloys is not primarily due to interactions of hydrogen with the γ/γ interface

  7. Structural features in Ni-Al alloys

    International Nuclear Information System (INIS)

    Abylkalykova, R.B.; Kveglis, L.I.; Rakhimova, U.A.; Nasokhova, Sh.B.; Tazhibaeva, G.B.

    2007-01-01

    Purpose of the work is study of structural transformations under diverse memory effect in Ni-Al alloys. Examination were conducted in following composition samples: Ni -75 at.% and Al - 25 at.%. The work is devoted to clarification reasons both formation atom-ordered structures in inter-grain boundaries of bulk samples under temperature action and static load. Revealed inter-grain inter-boundary layers in Ni-Al alloy both bulk and surface state have complicated structure

  8. Compositional and structural characterisation of Ni-phyllosilicates in hydrous silicate type Ni-laterite deposits

    OpenAIRE

    Villanova de Benavent, Cristina

    2015-01-01

    Ni-bearing Mg-phyllosilicates (commonly known as garnierites) are significant ore minerals in many Ni-laterite deposits worldwide. However, the characterisation of these mineral phases is complex, as well as their classification and nomenclature, due to their fine-grained nature, low crystallinity and frequent occurrence as mixtures. The aim of this study is to shed some light to the nature of the Ni-bearing Mg-phyllosilicates occurring at the Falcondo Ni-laterite. In this deposit, these ...

  9. Thermal capture cross section for 58Ni (n,γ)59 Ni reaction

    International Nuclear Information System (INIS)

    Carbonari, A.W.; Pecequilo, B.R.S.

    1989-01-01

    The 58 Ni total thermal capture cross section was determined by suming the partial cross sections calculated for the primary transitions of the reaction 58 Ni (n,γ) 59 Ni. The primary transitions energies and intensities were determined from the 58 Ni thermal neutrons prompt gamma capture gamma rays spectrum in the 3.7 to 9.3 MeV region. The obtained value for the total cross section was 4.52 + 0.10b. (author) [pt

  10. Formation enthalpy of NiBe and Ni5Be21

    International Nuclear Information System (INIS)

    Ivanov, M.I.; Karpova, T.F.; Dalago, N.Yu.

    1981-01-01

    The method of dissolution calorimetry is used to determine standard enthalpies of NiBe and Ni 5 Be 21 formation, which are 84.8+-2.2 and (-669+-37)kJ/mol. The enthalpy values of NiBe and Ni 5 Be 21 at 331 K are shown to coincide (within the limits of errors of these values) with the values at the standard temperature of 298.15 K [ru

  11. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    KAUST Repository

    Wu, Shaohua; Wu, Xiaozhi; Wang, Rui; Liu, Qing; Gan, Liyong

    2014-01-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  12. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    KAUST Repository

    Wu, Shaohua

    2014-12-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  13. Creep and shrinkage of Mo(Ni)

    International Nuclear Information System (INIS)

    Kaysser, W.A.; Hofmann-Amtenbrink, M.; Petzow, G.

    1984-01-01

    To avoid some of the errors inherent in a quantitative interpretation of shrinkage of powder compacts as Mo-Ni, other experiments were looked for, where the influence of Ni on the material transport properties of Mo could be measured semi-quantitatively during heating up to temperature and subsequent isothermal annealing. The bending of thin Mo foils under small loads was found to be an experimental arrangement, where variations in stress, in Ni-concentration and in intrinsic material properties could be realized. The results of these creep experiments will be compared in a qualitative sense with sintering experiments in Mo-Ni done under similar conditions as the creep experiments

  14. Structure-activity relations for Ni-containing zeolites during NO reduction. II. Role of the chemical state of Ni

    NARCIS (Netherlands)

    Mosqueda Jimenez, B.I.; Jentys, A.; Seshan, Kulathuiyer; Lercher, J.A.

    2003-01-01

    The influence of the metal in Ni-containing zeolites used as catalysts for the reduction of NO with propane and propene was studied. In the fresh catalysts, Ni is located in ion exchange positions for Ni/MOR, Ni/ZSM-5, and Ni/MCM-22. The formation of carbonaceous deposits, the removal of Al from

  15. Ni-P/Zn-Ni compositionally modulated multilayer coatings - Part 2: Corrosion and protection mechanisms

    Science.gov (United States)

    Bahadormanesh, Behrouz; Ghorbani, Mohammad

    2018-06-01

    The Ni-P/Zn-Ni compositionally modulated multilayer coatings CMMCs were electrodeposited from a single bath by switching the deposition current density. The corrosion resistance of the deposits was studied and compared with that of monolayers of Ni-P and Zn-Ni alloys via Tafel polarization, EIS and salt spray tests. Characterization of corrosion products by means of EDS and XRD revealed more details from the corrosion mechanism of the monolayers and multilayers. The corrosion current density of Ni-P/Zn-Ni CMMCs were around one tenth of Zn-Ni monolayer. The CMMC with incomplete layers performed lower polarization resistance and higher corrosion current density compared to the CMMC with complete layers. The electrical circuit that was proposed for modeling the corrosion process based on the EIS spectrum, proved that layering reduces the porosity and consequently improves the barrier properties. Although, layering of Zn-Ni layers with Ni-P deposits increased the time to red rust in salt spray test, the time for white rust formation decreased. The corrosion mechanism of both Zn-Ni and Ni-P (containing small amount of Zn) was preferential dissolution of Zn and the corrosion products were comprised of mainly Zn hydroxychloride and Zn hydroxycarbonate. Also, Ni and P did not take part in the corrosion products. Based on the electrochemical character of the layers and the morphology of the corroded surface, the corrosion mechanism of multilayers was discussed.

  16. Joining of Ni-TiC FGM and Ni-Al Intermetallics by Centrifugal Combustion Synthesis

    International Nuclear Information System (INIS)

    Ohmi, Tatsuya; Matsuura, Kiyotaka; Iguchi, Manabu; Mizuma, Kiminori

    2008-01-01

    A centrifugal combustion synthesis (CCS) process has been investigated to join a Ni-Al intermetallic compound and a Ni-TiC cermet. The cermet, a tubular graphite mold, and a green compact of reactants consisting of Al, Ni and NiO were set in a centrifugal caster. When the combustion synthesis reaction was induced in the centrifugal force field, a synthesized molten Ni-Al alloy flowed into the graphite mold and joined to the cermet. The soundness of the joint interface depended on the volume percentage of TiC phase in the cermet. A lot of defects were formed near the interface between the Ni-TiC cermet and the cast Ni-Al alloy when the volume percentage of TiC was 50% or higher. For this kind of cermet system, using a functionally graded cermet such as Ni-10 vol.%TiC/Ni-25 vol.%TiC/Ni-50 vol.%TiC overcame this difficulty. The four-point bending strength of the joined specimen consisting of the three-layered FGM cermet and cast Ni-29 mol%Al alloy was 1010 MPa which is close to the result for a Ni-29 mol%Al alloy specimen

  17. Dynamic recovery in nanocrystalline Ni

    International Nuclear Information System (INIS)

    Sun, Z.; Van Petegem, S.; Cervellino, A.; Durst, K.; Blum, W.; Van Swygenhoven, H.

    2015-01-01

    The constant flow stress reached during uniaxial deformation of electrodeposited nanocrystalline Ni reflects a quasi-stationary balance between dislocation slip and grain boundary (GB) accommodation mechanisms. Stress reduction tests allow to suppress dislocation slip and bring recovery mechanisms into the foreground. When combined with in situ X-ray diffraction it can be shown that grain boundary recovery mechanisms play an important role in producing plastic strain while hardening the microstructure. This result has a significant consequence for the parameters of thermally activated glide of dislocations, such as athermal stress and activation volume, which are traditionally derived from stress/strain rate change tests

  18. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    International Nuclear Information System (INIS)

    Chopra, Nitin; Claypoole, Leslie; Bachas, Leonidas G.

    2010-01-01

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  19. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, Nitin [University of Alabama, Department of Metallurgical and Materials Engineering, Center for Materials for Information Technology (MINT) (United States); Claypoole, Leslie [Fairmont State University (United States); Bachas, Leonidas G., E-mail: bachas@uky.ed [University of Kentucky, Department of Chemistry (United States)

    2010-10-15

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  20. Report on results of research. Basic studies on characteristics of coal char gasification under pressure; Sekitan char no kaatsuka ni okeru gas ka tokuseino kiso kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-03-01

    This paper explains basic studies on characteristics of coal char gasification under pressure. Hydro-gasification of coal needs as a gasifying agent a large amount of hydrogen, which is effectively produced by the water gasification of exhaust unreacted residual char. In fiscal 1975, gasification was tested on Taiheiyo coal carbonized char by an atmospheric fluidized gasifier of 28 mm bore. In fiscal 1976, experiment was conducted under pressure by fully improving the auxiliary safety equipment. The char and gas yield increased with higher pressure in pressurized carbonization by an autoclave. In fiscal 1977, clinker was successfully prevented by using quartz sand for a fluidized medium. In fiscal 1978, two-stage continuous gasification was examined. In fiscal 1979, correlation was determined between operation factors such as gasification pressure, temperature, etc., and clinker formation/char reactivity. An experiment was conducted for particle pop-out using a pressurized fluidized bed of 100 mm inner diameter, with the pop-out quantity found to be proportional to the 0.38th power of a pressure. A high pressure fluidized gasifier was built having a char processing capacity of 1 t/day, 20 atmospheric pressure, and an inner diameter of 100 mm. In fiscal 1980, this device was continuously operated, elucidating problems for the practicability. (NEDO)

  1. Evaluation report on the research and development of automatic sewing systems; 'Jido hosei system' no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    A comprehensive evaluation is made upon completion of the automatic sewing system research and development project. The project aims to achieve a 50% increase in productivity through effective use of a multiple-product/small-amount production scheme in small and medium sewing industries. The intelligent cloth inspecting machine (prior to sewing) in a laser-aided cutting system is as competent as the currently used sewing mill inspection system, and the resultant data are effectively utilized in the cutting process. As for the cutter, it is demonstrated that it is more than two times higher in cutting speed than a currently used laser cutting system; that it is sufficiently accurate in avoiding parts with flaws and in pattern matching; and that it is reliable in complying with process information provided. As for the flexible sewing system, it is acknowledged that it correctly recognizes information attached to cut parts and that it joins them with flexibility in response to changes in the material, pattern, or size. As for the high-technology assembling system, satisfaction is found in its automated 3-dimensional sewing of parts received from the previous stage and in its flow of production. As for the 3-dimensional flexible press, the quality after finish is found satisfying. The said systems are integratedly operated, and it is found that the goal of the research and development has been achieved. (NEDO)

  2. Fiscal 2000 survey report. Survey of DSM status in Europe centering about thermal storage; 2000 nendo Oshu ni okeru chikunetsu wo chushin to shita DSM jokyo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    In search of measures for popularizing thermal storage technology in Japan, investigations were conducted into the conditions of electric power and the state of DSM (demand side management) in Italy, Spain, Portugal, and Greece whose climate is similar to Japan's. The results of the effort were edited and classified into six items, which are (1) power conditions, (2) DSM status, (3) popularity of thermal storage, (4) merits of thermal storage, (5) measures for thermal storage popularization, and (6) propositions to Japan. In all the countries, the power demand peak has shifted to the summer season or the difference in demand for power between summer and winter has decreased and, except in the case of Greece, the load factor has increased, these due to the increase in demand for power for cooling equipment. In Greece, the load factor has decreased since the peak shifted to summer. In every country, the rate schedule based on season of the year and time of the day is treated as a basic incentive for DSM. Except in Greece, there is no summer demand suppression type DSM menu and efforts are being exerted rather to have loads built in off-peak time zones. As for thermal storage systems in use, they are mostly of the ice-aided type. Those in the residential/commercial sector are on the increase, and it is estimated that 50% of ice thermal storage systems will be found in this sector in 2000. (NEDO)

  3. Wind power development field test project at Okkobe-cho. Close survey on wind conditions; Okkobecho ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    A survey was made on regional wind conditions on the assumption that a wind power generator was installed around Okkobe Rakuno-no-oka, Okkobe-cho, Monbetsu-gun, Hokkaido. The survey period was one year from Oct., 1998 to Sept., 1999. The observations were carried out on the average wind velocity, average wind direction, standard deviation of velocity, and the maximum instantaneous wind velocity. With a fixed point observation at 20 m above ground, and with the minimum observation time unit of 10 minutes, an average value during the 10 minutes was determined as the measurement of each category. However, the maximum instantaneous wind velocity was determined on the measurement with the minimum observation time unit of 2 seconds. The average wind velocity was 4.8 m/s, the maximum wind velocity during the period was 29.9 m/s, the prevailing wind direction was WSW (17.1%), the wind axis was WSW-ENE, and the total occurrence rate of wind direction was 51.1%. The intensity of turbulence was 0.19 at a wind velocity of 2.0 m/s or above and was 0.16 at 4.0 m/s or above. An estimated annual operation rate of a windmill was 59-77% using the rated value of a 150 kW, 300 kW and 750 kW class windmills. (NEDO)

  4. Wind power development field test project at Hirashima, Sakito-cho. Detailed wind characteristics survey; Sakitocho Hirashima ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    A detailed wind characteristics survey was conducted at Hirashima, Sakito-cho, Nishisonogi-gun, Nagasaki Prefecture, on the assumption that a wind power generation system would be constructed. The survey was a 1-year project from October 1998 through September 1999, and wind characteristics such as the average wind speed, average wind direction, standard deviation of wind velocity, and the maximum instantaneous wind speed were observed. The observation point was fixed at 20m above ground, the minimum time unit for observation was 10 minutes, and the 10-minute average value was defined as the measured value. For the maximum instantaneous wind speed, the minimum time unit for observation was set to be 2 seconds. The yearly average wind speed was 7.1m/s and the maximum wind speed in the period was 37m/s. Winds came prevalently from N (13.9%), and then from NNE (13.3%), NW (12.2%), and NE (10.7%). The total wind direction occurrence rate involving the 4 directions was 50.1%. Turbulence intensity was 0.14 at wind speed 2.0m/s or more and 0.12 at wind speed 4.0m/s or more. Estimated wind turbine yearly operating factors of 77-87% were obtained using rated values of a 150kW, 300kW, and 750kW-class wind turbines. (NEDO)

  5. Wind power development field test project at Maruyama-machi. Close survey on wind conditions; Maruyamamachi ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    A survey was made on wind conditions in Maruyama-machi, Awa-gun, Chiba prefecture, on the assumption that a wind power generation system was installed therein. The survey period was one year from Oct., 1998 to Sept., 1999. The observations were carried out on the average wind velocity, average wind direction, standard deviation of velocity, and the maximum instantaneous wind velocity. With a fixed point observation at 20 m above ground, and with the minimum observation time unit of 10 minutes, an average value during the 10 minutes was determined as the measurement of each category. However, the maximum instantaneous wind velocity was determined on the measurement with the minimum observation time unit of 2 seconds. The average annual wind velocity was 3.5 m/s, the maximum wind velocity during the period was 27 m/s, and the wind axis was WSW-ENE, with the total occurrence rate of the wind direction 44.1%. The intensity of turbulence was 0.23 at a wind velocity of 2.0 m/s or above and was 0.22 at 4.0 m/s or above. An estimated annual operation rate of a windmill was 40-60% using the rated value of a 150 kW, 300 kW and 750 kW class windmills. (NEDO)

  6. Wind power development field test project at Ashibe-cho. Detailed wind characteristics survey; Ashibecho ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    A detailed wind characteristics survey was conducted at Ashibe-cho, Iki-gun, Nagasaki Prefecture, on the assumption that a wind power generation system would be constructed. The survey was a 1-year project from October 1998 through September 1999, and wind characteristics such as the average wind speed, average wind direction, standard deviation of wind velocity, and the maximum instantaneous wind speed were observed. The observation point was fixed at 20m above ground, the minimum time unit for observation was 10 minutes, and the 10-minute average value was defined as the measured value. For the maximum instantaneous wind speed, the minimum time unit for observation was set to be 2 seconds. The yearly average wind speed was 5.8m/s and the maximum wind speed in the period was 35m/s. Winds came from the prevailing direction of NE (21.3%), and then from NNE (14.7%) and ENE (7.9%). The wind axis was in the NE-SW direction, and the total wind direction occurrence rate from the 6 directions was 60.2%. Turbulence intensity was 0.19 at wind speed 2.0m/s or more and 0.17 at wind speed 4.0m/s or more. Estimated wind turbine yearly operating factors of 66-84% were obtained using rated values of a 150kW, 300kW, and 750kW-class wind turbines. (NEDO)

  7. Research report of fiscal 1997. Basic research on the commercialization of innovative energy technologies; 1997 nendo chosa hokokusho. Kakushinteki energy gijutsu no jitsuyoka ni kansuru kiso chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper summarizes the research result in fiscal 1997 from the basic research results on the commercialization of innovative energy technologies. The target of a photovoltaic power generation market includes isolated power sources (several kWp) for distant places or developing countries, and those (several tens kWp) for personal residences or public facilities. Although the former is mainly promoted in the West, while the latter over the world, their profitability is unsolved. Power plants over several hundreds kWp are in demonstration test. Solar heat power generation of several tens to hundreds MWp is most profitable, however, small-scale one is poor in feasibility. Australia takes an interest in distributed photovoltaic power generation directly connected with actual lives of residents, and has a dominant opinion that desert is useless as large-scale site. This country lays emphasis on protection and maintenance rather than positive use of desert based on a basic cognition that desert is easily changed and broken. The Australian government announced power company`s obligation to use renewable energy by 2%, and a strong organization is scheduled to be newly established. 59 figs., 57 tabs.

  8. Report on achievements in fiscal 1998. Survey on environmental effects from photovoltaic power generation systems; 1998 nendo daikibo taiyoko hatsuden system no kankyo eikyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Different environmental effects may be assumed when large-size photovoltaic power generation systems are installed in vast unutilized lands including deserts. Knowledge having been acquired to date has been put into order on the following subjects as the pre-survey thereon: (1) environmental characteristics of desert areas, (2) discussions on environmental effects from (a) environmental assessment viewpoints, (b) contents of the environmental assessment, and (c) environmental assessment institutions, and (3) the survey policy. In discussing the environmental characteristics, it is revealed that desert areas are neither sterile nor unused, but pasturage and agriculture have been carried out in historical and traditional ways. In discussing the environmental effects, it was recognized that surveys on primary and secondary effects on the environmental are indispensable. With regard to the institutions, there are countries who have and have not the institutions even among the OECD member states. In addition, it was known that environments in the desert areas vary greatly according to the particular areas, whereas there are possibilities of installing the facilities because the effects of the facility locations on the environment are various. Therefore, it was decided to start from the case studies in locations of different types. (NEDO)

  9. Report on the FY 1999 R and D survey on ultra-high sensitive photoelectric converter; 1999 nendo chokokando koden henkan soshi ni kansuru kenkyu kaihatsu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    By the ICB method which is one of the ion engineering methods, photomultipliers were formed using organic dye thin films. By changing the energy to bond traps on thin film/metal electrode interface and electric charges by change of acceleration energy of ion beams, a technology was developed for adjusting the optimum operating temperature between -20 degrees C and +100 degrees C. The wide range of operating temperature and favorable SN ratio can be realized. It was made clear that the dark current of the photomultiplier is composed of two components of contribution by the residual charge stored on the interface at photomultiplying and of contribution by charge injection from the Schottky barrier. Based on this, the residual electric charge removal method by heating and applied pulse voltage was developed. The development for practical use was studied of ultra-high sensitive photoelectric converters. As an intelligent photo sensor, a biomimetic visual photosensor was proposed which uses amplification/memory/arithmetic functions and film formation/processability of organic thin films. The paper also described the image sensor. (NEDO)

  10. Research report for fiscal 1998. Research into the recycling of plastic wastes into resources; 1998 nendo hai plastic no saishigenka ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The actualities in Japan are investigated of the types and quantities of plastic wastes, collection and recovery systems, and recycling technologies. Plastic wastes exceeded 9-million tons in 1996, of which 39% was effectively utilized while 61% was merely incinerated or used for reclamation. The 61% of the plastic wastes which are equivalent to oil resources in terms of the energy they contain is found dealt with in such ways, for which additional energy has to be consumed. Some problems are mentioned that occur in the CO2 gas reduction effort in the process of plastic waste recycling for each of its stages of production, distribution, assortment, recovery, and reuse. The problems involve the required reform into production designs and systems with the greatest importance attached to recyclability; share of the expenses between the producing and distributing parties and financial support to assortment/recovery systems; reform of consciousness of both people at large and the administrative organizations, mutual collaboration between them, and reasonable share of expenses between them; construction of a unified assortment/recovery system; expansion of the scope of use of recycled products and the building of environments that encourage their use; diversification of recycling methods and establishment of technologies therefor; and limits on the use of materials and products that generate heavy impacts on environments during their life cycles. (NEDO)

  11. Research report for fiscal 1998. Study of utilization of biomass including foods in energy industry; 1998 nendo shokubutsu nado no biomass no energy riyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Rice being produced as food is taken up out of various types of biomass, and a feasibility study from the viewpoints of technology and economy is conducted as to its use in the energy industry. The production of ethanol from rice, though it has no past record worth discussion, is similar to the production of ethanol from other biomass resources in terms of technology and economy. The problem is that the production cost of rice is far higher than those of other materials. It is expected, however, that there will a large-scale production cost reduction and an increase in the yield when novel cultivation techniques are introduced in the future. It is also expected that alcohol from rice will be sufficiently competitive with alcohol from molasses or the like when the exploitation of cellulose-family by-products such as husks becomes feasible. The study on this occasion deals solely with the effective use of farmland and the surplus rice. A confrontation between rice as a biomass resource and rice as a food has to be avoided as much as possible in the long term because it may cause a price rise and compromise the security of food supply. That is, in discussing this matter, it is mandatory to draw a very definite line between rice as a food and rice as an alcohol production material. (NEDO)

  12. Fiscal 1992 report. Overseas surveys out of surveys for coal hydrogasification technology development; 1992 nendo sekitan suiten gaska gijutsu kaihatsu chosa ni okeru kaigai chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-12-01

    As part of the coal hydrogasification technology development survey project, overseas surveys were carried out as in the preceding fiscal year. With an emphasis placed on the process materials and resources, and on product utilization technologies, surveys and studies were conducted about the trends of development of coal and natural gas resources, and information was collected on energy-related matters in Indonesia and Australia. The need of hydrogasification technology was investigated from the viewpoint of natural resources. Moreover, Japanese engineers were dispatched to APEC (Asia-Pacific Economic Cooperation Conference) New Energy Seminar, Indonesia. Visits were made for information on the natural gas resources at an LNG base in East Kalimantan, Indonesia; coal gasification, energy, and others at CSIRO (Commonwealth Scientific and Industrial Research Organization), Australia; coal bed and methane resources at Warren Center, University of Sydney, Australia; coal bed and methane resources at the Brisbane office, Mitsubishi Gas Chemical Company, Inc.; and coal resources at coal mines of Idemitsu South Queensland Coal Pty Ltd. (NEDO)

  13. FY 1997 survey report on information sharing product life-cycle systems. 2; 1997 nendo joho kyoyugata product life cycle system ni kansuru chosa hokokusho. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Highly value-added products considering a total life-cycle of products by integrating both production and consumption activities are much in demand, and each information corresponding to each product should be realized by concept integrating both information and product as common element. Survey was made on what a social system integrating production and consumption should be, a product information model, and technology integrating both information and product for raw material, industrial machine and household appliance as examples. An information model shared by the whole production and consumption activities was first prepared. Based on this model, data storage, update, retrieval and dispatch technologies were surveyed and developed for life-cycle systems. Degradation and life sensing technology was surveyed for maintenance, repair and disposal activities using proper unstable information of each product. A support system for use of shared information was developed to promote a new highly value-added function. Total evaluation was made on information sharing product life-cycle systems. 10 refs., 23 figs., 7 tabs.

  14. Report on field test project for wind power development at Nagashima-cho. Detailed wind characteristics survey; Nagashimacho ni okeru furyoku field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    A detailed wind characteristics survey was conducted to study the feasibility of a wind power generation system for Nagashima-cho, Izumi-gun, Kagoshima Prefecture. Observation instruments were installed at the top of a hill approximately 80m above the sea level situated to the northwest of the Nagashima-cho town hall and, in the period October 1998 through September 1999, data were collected at a point 20m above ground, such as the average wind speed and direction, wind velocity standard deviation, and the maximum instantaneous wind velocity. The data were analyzed, and findings were obtained, as mentioned below. The annual average wind speed was 5.0m, strong in winter and weak in summer. The annual wind direction occurrence rate was 61.8%, turbulence intensity was 0.17 at wind speeds of 4m/s and more, these not presenting any particular problem. Wind energy density was 148W/m{sup 2}. Both wind speed conditions and energy density were slightly lower than the reference levels indicated for evaluation. Studies were made on the assumption that three classes of wind turbines (150, 300, and 750kW) would be introduced, and then it was found that both operating factors and facility availability rates exceeded the required levels. Since there were no detrimental factors in the surrounding conditions, it was concluded that possibilities were high that wind power generation at the site would be practical. (NEDO)

  15. Report of 'Survey on Asian environmental information networks'; 'Asia kankyo joho network chosa' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    This project is implemented to survey the current statuses and future trends of the Asian district environment-related information networks, for the (research cooperation project for development of environmental condition measuring laser radar systems), being promoted by NEDO. First, current statuses of the network names, managing organizations, user numbers, conditions of use, protocols for use, service conditions, major domestic nodes and internationally connected conditions are surveyed mainly for internet-connected networks, for surveying the current statuses and future trends of the research networks in Asian countries. Second, current statuses in Indonesia of the network names, managing organizations, user numbers, conditions of use, protocols for use, service conditions, domestic node sites and managing organizations, charge systems and institutions, types/reliability/ stability of the circuits, and conditions of restriction of use, if any, for surveying the current statuses and future trends in Indonesia. Third, conditions of and needs for network utilization by researchers for Asian district environments. (NEDO)

  16. Report on survey in fiscal 2000 on the feasibility study on structuring research aiding net; 2000 nendo kenkyu shien net no kochiku ni kansuru kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    A study has been performed on the possibility of efficient utilization of research resources by summarizing the resource information for research and development by the industrial, governmental and academic areas and by providing research organizations with the information through the Internet. As a result of the survey on research aiding cases that apply the network used by the public organizations and corporations inside and outside the country, it was found that Japan often utilizes research facilities and holds seminars having selected regional research organizations, while the U.S. provides large-size aids in wide area, such as technological information service, patent service, and human resource service. A questionnaire survey was conducted on interests toward the necessity of research aids, specific needs for aids, and provided services. As a result, it was revealed that interest toward the research aiding net is considerably high, and strong demands are present in structuring database for the research human resource information, needs information, and information on researchers in different fields. Discussions were given on structuring the research aiding net, wherein the system contents, structuring expense, and the development schedule were presented. (NEDO)

  17. Fiscal 2000 survey report. Basic research on hot molding of amorphous ceramics; 2000 nendo amorphous netsukan ceramics seikeiho ni kansuru kiso kenkyu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Experiments were conducted on the plasticity processing of heat resistant ceramics making use of the viscous deformation of amorphous ceramics in the supercooled liquid temperature domain. Concerning the preparation of powder of amorphous ceramics, the plasma rotating electrode method of Institute for Materials Research, Tohoku University, was employed, and a bamboo leaf shaped amorphous flake was successfully fabricated by increasing the arc discharge current. In a search of texture easy to turn amorphous, it was observed that Al{sub 2}O{sub 3}-La{sub 2}O{sub 3} had a supercooled liquid domain of as large as 70K, and this enabled a conclusion that it was a promising candidate for hot molding in a supercooled liquid domain. In an experiment of molding in a supercooled liquid domain, Al{sub 2}O{sub 3}-Gd{sub 2}O{sub 3} was used in a press molding process. As the result, a compact bulk mold was obtained in a temperature domain far lower than in the case of conventional sintering. Crystallization had already advanced in all the molds experimentally fabricated by press molding, and this disabled a study of characteristics to be exhibited by an amorphous mold, but it was found that they had a compressive strength of approximately 1,800MPa. (NEDO)

  18. Fiscal 2000 survey report on the survey and research on green technology industry; 2000 nendo green technology industry ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The approaches of the Government and local autonomies to green technologies are surveyed toward the construction of a green technology industry. The present activities and future outlook of environmental industries interested in green technologies are surveyed and examined, the green technologies here including (1) energy conservation measures and development of non-fossil fuels, (2) energy-related and environmental measures for countering global warming, (3) waste treatment measures for countering dioxins and endocrine disrupters. A survey is conducted of the outlines and future trends of green technology related important studies now under way at laboratories and research institutes of universities, the Government, and private-sector corporations. Based on the results of the surveys, important subjects of technical development in green technologies are extracted and studied for the possibility and outlook of their practical application. Tasks to discharge and problems to occur before they are introduced to the market are also evaluated and confirmed. Based on the results of the research and development of green technologies, actualities of environmental industries are taken up, and the problems and tasks to be settled before environmental technologies are introduced to the market are investigated and studied. (NEDO)

  19. Fiscal 1998 survey report. Survey on method of environmental-impact assessment in wind power development; 1998 nendo furyoku kaihatsu ni okeru kankyo eikyo hyoka shuho chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    With the purpose of preparing the main points of 'environmental-impact assessment guidelines for wind power developments (draft)', examples of environmental-impact assessments, related laws and regulations in Japan and abroad were collected, and rearranged in respect to requirements in environmental-assessments, concrete procedures, survey/projection/assessment method, summarisation of results, etc. It was clarified, for example; in a large-scale wind power development, it can be dealt with by choosing items and contents on the assumption that a land area is developed; in a small-scale development, there is basically no need of considering the possible effect of the construction work; and, as far as noise, vibration and the ecosystem (plants/animals) are concerned, however, the characteristics of the site be taken into consideration. Objects for general assessment are noise, low-frequency air vibration, radio wave interference, the ecosystem (plants and animals) and the landscape. The guideline draft is constituted of (1) basic items, (2) overview of the area, (3) determination of items for environmental-impact assessment and (4) research, prediction, assessment, conservation measures and follow-up research; in the basic items, importance of preliminary consideration was emphasized, as were priority/simplification, implementation of environmental conservation measures, and implementation of follow-up research. (NEDO)

  20. FY 1996 annual report of investigation on biological fixation of carbon dioxide. 2; 1996 nendo seibutsuteki CO2 kotei ni kansuru chosa hokokusho. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Various kinds of biological fixation processes of CO2 were evaluated from the various viewpoints. Afforestation of tropical and temperate areas, greening of desert, biomass energy production in these areas by energy plantation, coastal mangrove plantation, fertilization with nitrogen and phosphate to outer ocean and coastal, upwelling zone fertilization with iron, and coral reef expansion combined with OTEC (ocean thermal energy conversion) were comparatively investigated as the selected measures. As a result, the cost of CO2 fixation by cultivation of sea weed and plankton was much higher than that of afforestation. The iron fertilization method which was considered to be one of the high CO2 reduction potentials might be economical. However, its effect could not be quantitatively evaluated. The afforestation of tropical and temperate areas seemed to be most feasible in a short term from the viewpoints of economy and environment. It was suggested that the establishment of a systematic water management technology could make greening and afforestation of desert. 76 refs., 27 figs., 28 tabs.

  1. Research report on the trend of preventive measures against global warming by substituting CFCs; Daitai freon no chiku ondanka taisaku doko ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This paper reports the research results on the present state and future trend of protective measures for the ozone layer, and the trend of preventive measures against global warming by substituting CFCs such as HFC, through international conferences, meetings and lecture meetings, and literature survey. In the 8th meeting of the parties to the Montreal Protocol, it was presented that refrigerator producers in Thailand phased out CFCs from their products earlier than the schedule in cooperation with Japan. The final draft including the approval of essential use from 1997 to 2002 was reviewed, and reported to the technology/economy assessment panel. Reduction of ozone depleting substances was guided in Thailand, Indonesia and Philippines. The latest trend of substituting technologies of HCFC was surveyed, and the control trend of F-containing greenhouse effect gas emission was also surveyed through the conference of the parties of climate change in fiscal 1996. Based on the IPCC report in 1995, the emission amount of greenhouse gases of nearly 10% in contribution such as CO2, methane and fluorocarbon was arranged. R and D on destruction of CFCs was also surveyed. 35 refs., 54 figs., 32 tabs.

  2. Report on surveys in fiscal 2000 on the survey on promotion of freer flow of researchers; 2000 nendo kenkyu jinzai no ryudoka sokushin ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    In order to help discuss the system and environment improvement to promote freer flow of Japanese researchers, surveys and discussions were given on the actual status in America and European countries. In the U.S., results as independent researchers are demanded from the very early time under the severely competitive environment, wherein the fair evaluation of the results allows the researchers to step-up the positions and research environment to which the researchers are oriented. In Germany, a function to promote researcher mobility is available as a system, such as promotion of exchange with other sectors during researcher education course (the internship system at the fourth grade in a university, and power training and performance record building at the Max-Planck Institut during the long term of post-doctoral period before attaining a professor position), or prohibition of inviting university professors into the same faculty. The actual status of Japan not having high mobility of researchers has been caused by the system based on the lifetime employment, whose shortcomings include stiffness in personnel affairs, and reduction in activities of researchers due to aging. (NEDO)

  3. Reports on 1974 result of Sunshine Project. Research on tar sand and oil shale; 1974 nendo tar sand oyobi oil shale ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-04-04

    The purpose of this research is to grasp the policy of the oil sand resource countries, the properties and existing conditions of the resources, effects of the oil sand resources on a long term energy supply/demand, etc., and to clarify the meaning and position of the researches on the development of oil sand resources in the future energy policy of Japan. The quantities of oil sand resources are mostly in the process of investigation except Alberta province of Canada and are estimated to be two trillion barrels. The quantity for which strip mining is possible is about 90 billion barrels, which are mostly located in the Athabasca region. The oil sand holding countries take a policy of positively developing oil sand. No barriers are particularly provided against the introduction of foreign technology and capital. Where the prospects are possible for the development of oil sand are Canada and Venezuela. R and D should be emphasized on the refining of bitumen and the extraction method within the oil reservoir. The investment per b/d is about 15-20 thousand dollars, which is likely to be more than twice as much as for the North Sea oilfields. The properties and quality of the synthetic crude oil are superior while the risk of exploitation is small; therefore, oil sand will be competitive with crude oil in the future. (NEDO)

  4. Fiscal 1994 technological survey report. Research study on polymer materials by precision polymerization; 1994 nendo seimitsu jugo kobunshi zairyo ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    In the paradigm that propelled polymer chemistry, there are involved the establishment of polymer concept, engineering plastics, regulation of higher ordered structure, and precision polymerization. The first two produced the polymer chemistry era in the 20th century. The regulation of higher ordered structure and the precision polymerization are the fundamental technologies supporting the polymer chemistry of the 21st century. The precision polymerization is a technology for regulating the stereospecificity, sequential structure, and molecular weight of polymers by regulating atoms and molecules and is referred to the following important techniques to be concrete. In the precision addition polymerization, stereospecific regulation and purification of active site to give living polymers are required while, in the precision condensation polymerization, regulation of condensation probability process to be secondary Marcov chain is necessary, as is the establishment of non-defect condensation condition avoiding high temperature deterioration and the like. In the biomimetic precision polymerization, key issues are the method of incorporating molecular recognition control and sequential structure control by living organs into an industrial process. If the higher ordered structure can be regulated by the precision polymerization, it is possible to obtain numerous high performance/high functional materials such as superconductors. (NEDO)

  5. Report on the field test project for wind power development at Kamiyaku Town (wind characteristics investigation); Kamiyakucho ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    Wind characteristics are observed for a year at the above town located at the northern end of the Yakushima island, Kagoshima Prefecture. The exponential index of the wind speed distribution in the vertical direction is 6.06 with all the directions averaged, and is so high as 8.4/13.6 in the wind directions (W/E). Prudence should be exercised, when to estimate the wind speed at the wind turbine hub altitude, against disjunction from the simple exponential law due to geographical peculiarities of the observation location. Turbulence intensity is low and is 0.15 when the wind speed is 2m/s or more, not exerting an ill effect on wind power development. As for the total wind direction occurrence rate on the prevalent wind axis, 78.2% is recorded, which is much higher than the reference value (60%). The average wind speed on this wind axis is high, and this shows that the location is quite suitable for wind power development. The annual average wind speed of 6.3m/s is much higher than the reference value, this again promising a success. The wind energy density of 478W/m{sup 2} is sufficiently high, as compared with the reference value (215W/m{sup 2}). Since there are possibilities of a maximum instantaneous wind speed of over 60m/s, caution is to be used in determining wind endurance for the wind turbine design. The annual capacity ratios for the 150/300/750kW wind turbine models are 33.8/36.5/36.9%, respectively, higher than the NEDO-provided reference value (17% or higher) and predicting sufficient power generation. (NEDO)

  6. Fiscal 1998 research report. Feasibility study on international cooperation for technology transfer; 1998 nendo chosa hokokusho. Gijutsu iten ni kakawaru kokusai kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    CTI (Climate Technology Initiative) is a framework for use by developed countries in international cooperation and voluntary promotion of the development and diffusion of technologies contributory to reduction of greenhouse gas emissions. The CTI's activity goal is to accelerate the transfer and diffusion of technologies for climate change control. As the first step toward personnel development programs relating to energy efficiency, CTI organized its workshop on that theme. The results of the workshop have been examined, and its achievements were reported at COP4 meeting, while responses by participatory countries were studied to evaluate the potential of international cooperation with regard to personnel development for reducing greenhouse gas emissions. In fiscal 1998, the CTI workshop 'Energy Efficiency' was held. The participants from developing countries understood the necessity and importance of energy saving enough through discussions in the workshop, and announced their message toward the world at COP4 meeting. (NEDO)

  7. International symposium on environmental impacts of advanced alternative to CFC; CFC shinki daitai busshitsu no kankyo eikyo ni kansuru kokusai symposium hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-07

    The international symposium on environmental effects of new CFC substitutes was held in Tsukuba City, Ibaraki Pref. on February 7-9, 1996, and 19 papers were made public. In Session 1 (Plenary lecture), reports were made on Global warming and climate change: a review of recent studies; Stratospheric ozone, CFCs, and CFC-substitutes: an update, etc. In Session 2, Measurements of OH rate constants for advanced refrigerants as well as HCFCs and HFCs; The reaction rate of CFC alternatives with OH radical; Experimental and estimated rate constants: reactions of hydroxyl radicals with several halocarbons, etc. In Session 3, Measurement of uptake coefficients of some acetyl halides and fluorinated ethers into water; Mass transfer at the air/water interface: removal processes of halocarbonyl compounds; Heterogeneous reactions of fluorinated ethers on allophane or titanium dioxide, etc. In Session 4, papers were reported on model calculations relating to the global warming.

  8. Report on evaluation concerning R and D of magneto hydrodynamic (MHD) generation. Introduction; Denji ryutai (MHD) hatsuden no kenkyu kaihatsu ni kansuru hyoka hokokusho. Soron

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1984-03-01

    Evaluation was conducted concerning R and D on magneto hydrodynamic (MHD) generation, with proposals made for the future R and D. As a result of the experimental operation and studies of the Mark 7 machine for MHD generation, a cold wall type generation channel was found promising in the long-term durability under MHD generation conditions. In addition, R and D was conducted on the exhaust gas control system that fulfilled an environmental standard, seed recovery method, grasp of seed coagulation state, etc. The R and D on element technologies were carried out along with the R and D of the Mark 7 and played a role in the backup of its experiment. MHD generation presents a large number of attractive characteristics, with its development expected in the future. However, it seems too early to immediately move on to the next step. Examinations should be made on such matters as comparisons with various kinds of new power generation systems using coal, trends in foreign countries particularly the U-500 project of the Soviet Union, the ideal system for more efficient development, and possibility of international cooperation. (NEDO)

  9. Fiscal 1999 survey report. Survey of feasibility of international cooperation in the transfer of technology; 1999 nendo gijutsu iten ni kakawaru kokusai kyoryoku kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Among the activity goals of CTI (climate technology initiative), which is a framework designed to encourage international cooperation of leading nations in the voluntary development and diffusion of technologies supposed to contribute to the reduction of greenhouse gas emissions, there is the promotion of the transfer and diffusion of climate change preventing technologies. To achieve the goal, energy efficiency oriented workshops will be held as part of the training for the raising of people skilled in energy saving, the results will be examined, the achievements attained at such events will be introduced at COP5 (Conference of the Parties at Bonn), and the responses of the respective countries will be reviewed, all these for the investigation of the feasibility of international cooperation for raising people dedicated to the reduction of greenhouse gas emission. In this fiscal year, aiming to make clear the possibility of contribution to the transfer of software-related technologies through cooperation of multiple nations, lecturers from leading countries and participants from developing nations met, held a workshop over energy efficiency technologies, and the results were compiled. (NEDO)

  10. Evaluation report on research and development of 'seawater purification and byproduct utilization'; 'Kaisui Tansuika to fukusanbutsu riyo' no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1978-03-01

    Research, development, and evaluation were made on seawater purification for the purpose of supplying inexpensive city water stably in the future. In the research of the high flow rate long-tube type multi-stage flash process, basic characteristics were identified by studying fluidity, heat transfer, deaeration, and decarburization by using a test plant with a capacity of 3,000 m{sup 3}/d. A number of findings were derived in carrying out demonstration studies by using a test module with a capacity of 100,000 m{sup 3}/d. Research on heat transfer pipe materials covered a wide area including copper alloys, titanium and aluminum alloys, and ferrous materials, where a prospect was obtained on materials which may be practically usable in the future as transfer pipes in large seawater purifying equipment. Research on a concrete evaporator body proved that it is more economical than steel evaporators, and has sufficient corrosion resistance even against high-temperature brine. Other activities included researches on effects of contaminated seawater, brine diffusion, byproduct utilization, and total systems. Social and economic evaluations were also performed. (NEDO)

  11. Report for fiscal 2001 investigations on energy saving assistance institutions in different countries; 2001 nendo kakkoku no sho energy shien seido ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Taking up China, India, Indonesia and Thailand as the object, investigations were performed on political financing measures that can be used for installing energy saving facilities, and on applicable preferential taxation systems that are applied in each country. Indonesia has no aid measures such as subsidies and political financing directly purposed for energy conservation. Import duty exemption is applied for the purpose of promoting investments. Three kinds of funds are available through IFCT to implement fund aid to protect the environment. Energy saving fund has been established as an energy saving policy to provide subsidies. Energy saving machineries recognized by the investment committee are exempted from the import duties. India has no political financing measures directly purposed for energy conservation. Its preferential taxation system for energy conservation includes the 100% accelerated amortization system for energy saving machineries and facilities, and the preferential import duty system. In China, the financing from the China National Development Bank is considered utilizable in installing energy saving facilities. The country has no aid measures in the taxation system, but fund aid and subsidy by supplementing interest are provided. (NEDO)

  12. Report on investigations and studies on chemical conversion of photo-energy; Hikari energy no kagakuteki henkan ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1984-03-01

    This paper summarizes problems in utilization of solar energy, their solutions, features, the currently achieved results, and prospects. With regard to water decomposition using semiconductors, simultaneous generation of hydrogen and oxygen has already been achieved, and there is high possibility of raising the efficiency by improving catalysts. Water decomposition using metal complexes has acceleration of charge isolation as the largest problem, whose prospect of solution is not necessarily bright at the present time. Photo-catalytic reaction is a field to be discussed as one means of developing a new synthesizing method from the viewpoint of organic synthetic chemistry. Conversion into electric energy that uses a photovoltaic process has high efficiency, and is a field to be noted. In photo-energy conversion by means of photo-synthesis, living organisms performing hydrogen production at high efficiency have been discovered. Important studies include the studies in terms of chemical engineering using these living organisms, improvement of breeds by gene manipulations, and studies that utilize living organisms or part of the constituting components. (NEDO)

  13. Report on the field test project for wind power development at Soyo Town (wind characteristics investigation); Soyomachi ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    Wind characteristics are observed for a year at Soyo Town, Aso-gun, Kumamoto Prefecture. The annual average wind speed is 5.9m/s and 5.6m/s at 20m and 10m above ground, respectively, satisfying the reference values of 5.6m/s and 5.0m/s. The prevalent wind direction is WNW (occurrence rate: 32.8%). The wind from the directions with WNW at their middle occupies 75%, stable and satisfying the reference value of 60%. Strong winds come frequently from the direction of high occurrence, which is advantageous in arranging plural wind turbine systems. The exponential index in the wind speed vertical distribution is 13.3, but wind distribution is not simple at a mountain top site like the observation station in this report. Wind characteristics are similar to those at places with mild inundations, and the maximum instantaneous wind speed of 40.8m/s will not pose a problem. The wind energy density is 205W/m{sup 2}, satisfying the reference value of 150. Wind power systems of 150kW, 300kW, and 750kW are assumed. When the exponential index is 13.3, their annual operation rates will be 70%, 71%, and 82%; and their capacity ratios are 22.6%, 23.9%, and 22.9%, all satisfying the reference values. They will collect 297MWh, 629MWh, and 1507MWh of wind energy per year. It is concluded that Soyo Town is fully qualified as a site for wind power development. (NEDO)

  14. Investigational report on international joint research in medical/walfare appliances in fiscal 1993; 1993 nendo iryo fukushi kiki kokusai kyodo kenkyu ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The field of concrete cooperation, method of R and D, and business, environment to support the project, and system to promote the project were studied for the research under international cooperation through investigating the trend and organization of R and D of the medical/welfare appliances at home and abroad. Projects were then proposed. In the project for collecting/analyzing the trace quantity of blood, the anomaly is inspected at a molecular level from the collected trace quantity of blood to make the biochemical inspection painless for the patients suffering from infectious symptom or disease of adults. In the project for the high-accuracy and high-function measurement without invading the diseased part of living body, the configuration and metabolic function are measured by nuclear magnetic resonance to early detect the symptom of Alzheimer and other different obstinate diseases. In the operation support system project with three-dimensional images of living body, the three-dimensional information is obtained, by X-ray CT or MRI, about the diseased part of living tissue. Upon the exact determination of its location, the disease is cured. Besides, the monitoring systemproject was proposed for the old people`s safety against dementia. The human care robot project was also done. 56 refs., 11 figs., 15 tabs.

  15. Fiscal 1999 survey report. Survey and research concerning development of next-generation chemical process technologies; 1999 nendo jisedai kagaku process gijutsu kaihatsu ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    To further enhance resource/energy conservation and environmental impact reduction, it is necessary to develop innovative chemical reaction process technologies. It is for this reason that 'development of next-generation chemical reaction process technologies' is being carried out under the New Sunshine Program. The survey and research, for the fulfilment of the above goal, aim to select important technologies and put in a easy-to-study order the problems contained in associated technologies for picking out tasks for future studies for the purpose of suggesting some subjects to be taken up for future development. In addition, studies are made about how a comprehensive technology assessment system should be. In this fiscal year, propositions are compiled for research and development projects on five subjects. Studies of subjects other than these five will also continue to eventually build concrete propositions on them. The said five subjects involve 1) the development and application of nonaqueous biotechnologies, 2) biotechnology-aided polymeric material creation processes, 3) construction of high-efficiency energy conservation processes using innovative grain handling technologies in the high-temperature reaction field, 4) manufacture of high-performance polymeric materials for batteries and development of battery fabrication processes, and 5) the development of an energy conservation process maximally utilizing environmentally-friendly polyolefin. (NEDO)

  16. FY1998 report on the surveys and studies on developing next generation chemical process technologies; 1998 nendo jisedai kagaku process gijutsu kaihatsu ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For further resource and energy conservation and environmental load reduction, development is necessary on innovative chemical reaction technologies. This paper describes surveys on next generation chemical processes. As non-halogen processes subject to development of new catalysts, new processes were investigated and searching experiments and discussions were given on isocyanate, propylene oxide, and phenol. Technological progress in the C1 chemistry was investigated. Problems in hydrocarbon compound oxidation, hydroxylation, and decomposition by utilizing microorganisms were put into order as application of environmentally friendly technologies. Marine biotechnical possibilities were surveyed. The surveys were given on new processes utilizing the phase transfer catalyst forming a third phase, manufacture of biodegradable plastics, and a novel reaction system combined with self-separation process using molecular assembly. Possibilities were searched on designing a truly simple production system of highly energy saving type. Such fundamental common technologies as structure analysis, property control and reaction engineering were investigated for methods to manufacture functional micro-powder chemical materials. Development was discussed on a system for technology assessment over whole product life cycle to structure a technology assessment basis. (NEDO)

  17. Fiscal 1990 report. Overseas surveys out of surveys for coal hydrogasification technology development; 1990 nendo sekitan suiten gaska gijutsu kaihatsu chosa ni okeru kaigai chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-12-01

    For the selection and evaluation of coal gasification processes suitable for substitute natural gas (SNG) production, visits were made to overseas business corporations, research institutes, etc., engaged in the development of coal gasification technology, surveys were conducted of the status of development abroad, and information was collected. Visited were Westfield Development Center, British Gas plc; Midlands Research Station, British Gas plc; IEA Coal Research; IFP (Institut Francais de Petrole); and DMT-FP (DMT-Gesellschaft fur Forschung und Prufung mbH). The Westfield Development Center uses coal from near-by open cut mines and supplies town gas to the Scottish region. The slagging Lurgi process, etc., were investigated. At Midlands Research Station, where a coal hydrogasification process is under development, the history of development and the cold model test were summarized, a test plan using a 5 tons/day pilot plant and the modification of test facilities were explained, and the 5 tons/day pilot plant was visited for study. (NEDO)

  18. Evaluation report on research and development of a subsea petroleum production system; Kaitei sekiyu seisan system no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1985-03-01

    In order to assure stable supply of oil and natural gas resources, and achieve enhancement in ocean development technologies in general, development has been made on the subsea petroleum production system (SBPPS), which is effective in ocean floor petroleum production from oil fields at great depths (300 m or deeper), and can be applicable to continental shelves and continental slopes around Japan. The SBPPS consists of four sub-systems of shafts, pipelines, manifolds, and riser and oil storage, whose basic development targets were established for the total system. The system was given a conceptual design for the total system, and the above four sub-systems were designed according to the conceptual design. The experimenting devices of each system were fabricated on a trial basis while fundamental studies are being made on component technologies, and experiments were performed to verify basic functions of the sub-systems. Developments were made on such operation technologies as the system operation technology, production control technology, safety control technology, and maintenance and repair technology required to operate the SBPPS. On-shore and general off-shore experiments were carried out to verify the functions of the experimenting devices of each system, the comprehensive functions and the operation technology. Comprehensive evaluation was given on the above achievements from the technical, economic and social viewpoints. (NEDO)

  19. Report on evaluation of research and development of resources recycling/reutilization systems. Phase 2; Shigen saisei riyo gijutsu system no kenkyu kaihatsu (dainiki) ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1983-08-01

    Described herein are the final evaluation results obtained by the 7-year R and D project, beginning in the FY 1976, established by the national project system for developing the techniques for treating urban solid wastes. This project has developed a semi-wet type selective crushing/sorting unit for sorting the wastes, and established the elementary techniques for recycling the wastes into various products, e.g., compost, pulp, combustible gases, aggregates, methane gas, or fuel oil. Two types of total treating systems, in which these elementary techniques are integrated, have been developed; one is to recover materials and the other energy. They can comprehensively, efficiently treat the wastes, adapting themselves to various situations. Pyrolysis which discharges reduced quantities of flue gases is adopted. Waste water is treated, mainly by biological treatment which is supported by the conventional methods, e.g., coagulation and adsorption. The cost estimation results indicate that the total system developed by this project can compare favorably with the conventional incineration system under general conditions, at a capacity of 300 t/d or more, when taking into consideration the secondary effects brought by the recycling/reutilization. This system is commercially feasible, when it meets with local characteristics, e.g., garbage collecting systems, market values of recycled resources, treatment/disposal conditions, and natural and social environments. This project has sufficiently achieved the original objectives. (NEDO)

  20. Fiscal 2000 report. Feasibility study on international cooperation concerning technology transfer; 2000 nendo gijutsu iten ni kakawaru kokusai kyoryoku kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    A workshop was held concerning technology transfer in the software of environmental technologies, for the purpose of contributing to CTI (Climate Technology Initiative), an international framework for dealing with technological problems in preventing climate change, with the results of the workshop compiled. The workshop was held for a period from September 10 to September 23, 2000; the contents were, for example, an outline on energy conservation, introduction to cleaner production, lectures on related technologies, seminars on actual cases including case studies, factory tours, etc., and discussion session by all participants; and, in general, the workshop was conducted so as to promote understanding on cleaner production and energy conservation. Four lecturers were invited to this workshop from an international organization, U.S. and Japan. In addition, two staff members and two technical consultants from ICETT (the International Center for Environmental Technology Transfer) gave lectures and advice as technology advisers. Three environmental specialists were invited from each of the five countries, China, Indonesia, Thailand, Philippines, and Vietnam. (NEDO)

  1. FY 1998 annual summary report on shared product life-cycle total information system. 3; 1998 nendo joho kyoyugata product lifecycle system ni kansuru chosa hokokusho. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Recycling resources is gaining importance increasingly to correspond to global environmental problems. In urban areas, in particular, it is important to efficiently recover and recycle used large-size consumer products, e.g., home electric appliances and automobiles, which are discharged in large quantities. This study proposes a shared product life-cycle total information system, based on recognition that material recycling systems, encompassing stock materials, product production, consumption, and disposal and recycling of wastes, are essential. This system corresponds a material to information, in an attempt to realize more efficient recycling of products. The study for this fiscal year was focused on use of information modules attached to products and their members, product recycling systems using these modules, necessity for and problems involved in thermal recycle systems, problems involved in recycling home electric appliances and extraction of the data for their recycling, and material recycling process systems for home electric appliances and automobiles. (NEDO)

  2. Achievement report on research and development of optics-aided measurement/control system; Hikari oyo keisoku seigyo system no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1986-03-01

    The project aims to establish technologies for putting the above-named system to practical use. Such a system will measure, transmit, and control, with safety and stability by use of optical technologies, industrial process related information to be generated in certain areas such as industrial complexes and very large plants, the information including images, temperatures, flow rates, constituents, etc. Total system evaluation was performed in demonstration tests for appropriateness conducted for 32 systems in fiscal 1980 and 10 systems in fiscal 1981. Studied in the development of element technologies are opto-electronic integrated circuits (OEIC), semiconductor laser devices, light-intercepting devices, optical transmission paths, dielectric light switches, and optical sensors. For OEIC, in particular, since it is believed to be the nucleus of an optical application system, an optical technology joint research office is established, where efforts center on the substrate crystal growth technology, process technology, and crystal/process evaluation technology. (NEDO)

  3. FY 2000 Study report on the study on trends of the technologies related to climate change; 2000 nendo kiko hendo ni kansuru gijutsu doko chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This project is aimed at construction of the system which can provide information after searching in realtime key words in a vast volume of reports by Intergovernment Panel on climate Change (IPCC) and answers to Policy Relevant Questions (PRQ). The technical terms appearing in scientific documents use few synonyms to avoid ambiguity, and analysis of frequency of keywords is expected to be an index which provides important information. The chapters in the IPCC reports are not independent but coordinated with each other. It is therefore considered that analysis of the inter-chapter structures based on the keyword frequency analysis provides the meaningful viewpoints for, e.g., understanding Third Accessment Report (TAR) and extraction of the future research themes. For analysis of the logical structures of the sentences containing the keywords, special attention is focused on the term (sustainability) as the most important keyword in TARs, and its logical structures are analyzed. It is decided that the answers to PRQ are extracted from TOD. (NEDO)

  4. Fiscal 2000 survey report. Survey of DSM status in Europe centering about thermal storage; 2000 nendo Oshu ni okeru chikunetsu wo chushin to shita DSM jokyo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    In search of measures for popularizing thermal storage technology in Japan, investigations were conducted into the conditions of electric power and the state of DSM (demand side management) in Italy, Spain, Portugal, and Greece whose climate is similar to Japan's. The results of the effort were edited and classified into six items, which are (1) power conditions, (2) DSM status, (3) popularity of thermal storage, (4) merits of thermal storage, (5) measures for thermal storage popularization, and (6) propositions to Japan. In all the countries, the power demand peak has shifted to the summer season or the difference in demand for power between summer and winter has decreased and, except in the case of Greece, the load factor has increased, these due to the increase in demand for power for cooling equipment. In Greece, the load factor has decreased since the peak shifted to summer. In every country, the rate schedule based on season of the year and time of the day is treated as a basic incentive for DSM. Except in Greece, there is no summer demand suppression type DSM menu and efforts are being exerted rather to have loads built in off-peak time zones. As for thermal storage systems in use, they are mostly of the ice-aided type. Those in the residential/commercial sector are on the increase, and it is estimated that 50% of ice thermal storage systems will be found in this sector in 2000. (NEDO)

  5. Survey report on an environmental harmony type production system of chemical products; Kankyo chowagata kagaku seihin seizo system ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    As part of establishing an environmental harmony type production system of chemical products, study and survey were made on PET bottles. Using the life cycle analysis method (LCA), a study was made for proposing a material recycle (MR) method which is environmentally and economically excellent in the stage of recycling waste PET bottles. The total cost of recycling can be reduced by 34% supported by a decrease in equipment cost and improvement in yield if there is no mixture of foreign substances such as aluminum caps and PVC bottles. However, the ratio of the amount obtained from the reduction to the total production cost is small, and it is necessary to take measures from a viewpoint of the cost in a total production process and environmental loads. In a survey in Kawaguchi city, PET bottles discharged from the business sector occupied 41% of all the discharge amount. In a survey in Yokohama city, very important data were obtained on PET bottles appointed as the second type under the recycle law. The quality of PET bottles to be brought to the recycling plant is important for effectively processing PET bottles in MR method. For achievement of MR which is low in cost and small in environmental load, needed were cooperation by citizens, the shipping management system in autonomous government, and changes in design and material quality to be made by the industrial circle. 8 refs., 64 figs., 68 tabs.

  6. Fiscal 1998 research report. Research on energy conversion technology using biomass resources; 1998 nendo chosa hokokusho. Biomass shigen wo genryo to suru energy henkan gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Feasibility study was made on construction of the new energy production system by thermochemical conversion or combination of thermochemical and biological conversions of agricultural, fishery and organic waste system biomass resources. This report first outlines types and characteristics of biomass over the world, proposes the classification method of biomass from the viewpoint of biomass energy use, and shows the introduction scenario of biomass energy. The energy potential is calculated of agricultural waste, forestry waste and animal waste as the most promising biomass energy resources, and the biomass energy potential of energy plantation is estimated. The present and future of biochemical energy conversion technologies are viewed. The present and future of thermochemical energy conversion technologies are also viewed. Through evaluation of every conversion technology, the difference in feature between each conversion technology was clarified, and the major issues for further R and D were showed. (NEDO)

  7. Evaluation report on research and development of 'the comprehensive water recycling and utilization systems'; 'Mizu sogo saisei riyo system' no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-08-01

    This research and development project is aimed at treatment of sewage, industrial waste water and the like at lower cost for reutilization, while efficiently producing methane or the like by the systems annexed to the water treatment systems with high-concentration bio-reactor systems incorporating separation membranes. The waste water types studied to be treated by these systems include sewage discharged in large quantities and waste water containing oil/fat and protein (low-concentration waste water), and starch-, alcohol and paper/pulp-containing waste water, and excrements (medium-concentration waste water). The project has found the optimum systems, by adequately configuring the separation membrane modules, and combining dissolution of suspended solid with methane fermentation reactors for selective treatment of organic substances; improved efficiencies of removing organic substances and producing methane by fermentation, and realized reduction in quantities of discharged sludge; and thereby established the bases for the new waste water treatment techniques. The reactor systems developed for water treatment are those based on biological removal of nitrogen. They greatly reduce treatment time to produce treated water of high quality. For treatment of sludge, the techniques have been developed to convert sludge into oil. These results are well applicable to various areas, e.g., sewage treatment, and food and pulp industries. (NEDO)

  8. Fiscal 2000 survey report. Research on creation of microspheric photonic material; 2000 nendo bishokyu photonics zairyo no sosei ni kansuru kenkyu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Experiments were conducted under microgravity for findings on the creation of microspheric photonic materials which are high in sphericity. The experiments were carried out at the fall type microgravity facility of Japan Microgravity Center (JAMIC). In the experiments on the ground surface and under microgravity, glass specimens of 3BaO-97B{sub 2}O{sub 3} mol%, 4BaO-96B{sub 2}O{sub 3} mol%, and 2SrO-98B{sub 2}O{sub 3} mol% were tested. They were heated, melted, and cooled for the on-site observation of phase splitting in them. It was found as the result that, in the case of specimen 3BaO-97B{sub 2}O{sub 3}, the phase splitting start under microgravity was similar to that on the ground surface while the nucleation velocity was lower under microgravity. Specimen 2SrO-98B{sub 2}O{sub 3} mol% exhibited an approximately 0.5-second delay in its phase splitting start under microgravity as compared with its ground surface behavior. As for the nucleation velocity under microgravity, the value was same as that on the ground surface in the first half but, in the second half, it was lower than that on the ground surface. The said approximately 0.5-second delay in the phase splitting start was, when the cooling rate was taken into consideration, attributed to an approximately 6.5 degrees C fall in the phase splitting start temperature, and this suggested that phase splitting was suppressed under microgravity. (NEDO)

  9. FY 2000 report on the results of the research study of environmental information network; 2000 nendo kankyo joho network ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the FY 2000 results of the research study on environmental information network formation. The Internet is experiencing an explosive increase in volume of information distributed therethrough. This is accompanied by increased problems related to information searches, information exchange security and information-reliability guarantees. First in demand are excellent portal sites, and second are sites that can be relied on to responsibly provide information. Cooperation with the real world off the Net is of particular importance, because the operating organizations, e.g., sites, will lose their raison deter, unless they clarify their unique abilities and characteristics under the tendencies towards broadened bands and ubiquity. The public sector, on the other hand, is highly reliable, accumulates a large volume of information, and has high network capacity. It has various functions, e.g., supporting the activities pertaining to ISO standards, and promoting the activities, e.g., those for educational programs, interdisciplinary exchanges by researchers, and matching of various organizations. The international cooperation for environmental information needs construction and operation of the networks, and construction of the infrastructures in the developing countries. If information becomes more ubiquitous, a chaotic sea of information will result. NEDO is strongly obliged to serve as the beacon, because it has established a huge volume of environment-related technologies, information, and networks. (NEDO)

  10. Report on surveys and researches to excavate international joint researches related to industrial technologies; Sangyo gijutsu ni kansuru kokusai kyodo kenkyu hakkutsu no tame no chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Five themes were taken up for a project of the 'surveys and researches to excavate international joint researches related to industrial technologies'. Investigation groups were organized and dispatched for each theme toperform domestic and overseas surveys. Discussions were given on eachtheme for the possibilities of structuring international joint researches. The five themes are as follows: 'wearable information network related technologies', wherein technologies to micronize information devices have been advanced rapidly, and the technologies are entering the age from personalizing and mobilizing the information into the wearable computing; this theme is intended to develop systems to unify these technologies by means of international joint researches: 'surveys on using unutilized animal oils and fats as chemical raw materials', which are intended to make clear possibilities and problems in utilizing animal oils and fats as raw materials for the chemical industry that can substitute fossil resources: 'international joint researches on new glasses' and 'processes to manufacture semiconductors using glassy carbon' to develop glassy carbon having excellent chemical resistance substituting quartz: and 'international joint researches on the Russian project which places environment and energy in its center'. (NEDO)

  11. Report of 'Survey on Asian environmental information networks'; 'Asia kankyo joho network chosa' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    Information systems, mainly aided by computers, are becoming increasingly important, contributing to development of wide areas of societies and economics, to begin with. However, few developing countries have established sufficient information systems, in spite of their strong desires to do so, which will further widen the gap between them and advanced countries, where these systems are acceleratedly advancing. Given these situations, Center of International Cooperation for Computerization (CICC) has been implementing various projects for providing assistance to and cooperation with oversea countries which are trying to develop information systems. This report summarizes the project, which CICC has been commissioned by Optoelectronic Industry and Technology Development Association as part of the cooperation programs, for establishing the Asian environmental information networks. It outlines the research cooperation project for the environmental networks, results of the 4 on-the-spot surveys, 2 occasions for inviting researchers to Japan, and construction of the internet and Asian environmental information network systems. (NEDO)

  12. Wind power development field test project at Kodomari-mura 'Marinetopia'. Close survey on wind conditions; Kodomarimura Marinetopia ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    A survey was made on wind conditions in Imabetsu-machi, Higashi Tsugaru-gun, Aomori prefecture, on the assumption that a wind power generation system was installed therein. The survey period was one year from Oct., 1998 to Sept., 1999. The observations were carried out on the average wind velocity, average wind direction, standard deviation of velocity, and the maximum instantaneous wind velocity. With a fixed point observation at 20 m above ground, and with the minimum observation time unit of 10 minutes, an average value during the 10 minutes was determined as the measurement of each category. However, the maximum instantaneous wind velocity was determined on the measurement with the minimum observation time unit of 2 seconds. The annual average wind velocity was 4.8 m/s, the maximum wind velocity during the period was 35 m/s, the prevailing wind direction was NW-WNW and ESE-SEW, and the occurrence rate of wind direction at the wind axis of NW-SE was 88.1%. The intensity of turbulence was 0.24 at a wind velocity of 2.0 m/s or above and was 0.20 at 4.0 m/s or above. An estimated annual operation rate of a windmill was 46-64% using the rated value of a 150 kW, 300 kW and 750 kW class windmills. (NEDO)

  13. Report on a feasibility survey of the cold accumulated heat use energy system in Hokkaido; Hokkaido ni okeru reichikunetsu riyo energy system no kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A survey was conducted of various systems which use in summer cold heat from the snow stored in winter. A model of the cold accumulated heat system of the type which has a high possibility of the introduction was built to study a possibility of the realization. Types of the model system were selected assuming the utilization of cold heat energy of snow in Sapporo, a typical large city in the cold heavy-snow area. Studies were made on each model of urban type commercial facilities, urban type offices, suburban type shopping center, and suburban type hospitals. For each model, more than one systems were studied according to types and forms of the storage tank, and heat recovery methods. As a result, it was found that cold heat energy of snow can be utilized almost effectively by making an appropriate study of the energy balance like the possible supply of cold heat exceeded the demand in two models of an urban type office building and an suburban type hospital. Further, operating expenses of typical models were roughly calculated. 51 figs., 20 figs.

  14. Report on the field test project for wind power development at Yugawara Town (wind characteristics investigation); Yugawaramachi ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    Wind characteristics are observed in the period November 1997 through October 1998 at Yugawara Town, Kanagawa Prefecture. The average wind speed is 5.1m/s and 5.0m/s at 20m and 10m above ground, respectively, suggesting that the difference in altitude causes but a very small difference in wind speed and that a large wind speed component exists in the vertical direction. Under the 16 compass point system, the wind direction occurrence rate is the highest in the NE direction and the second highest in the W direction. The two directions are prevalent, and their occurrence rates on the wind axes total 62.6%. The occurrence rate of wind speeds of not less than 5m/s is 40%. Turbulence intensity is 0.23 and 0.17 for the average wind speed of not less than 2m/s and for the average wind speed of not less than 4m/s, respectively, suggesting but a little impact of air current turbulence. The amounts of energy to be acquired by wind turbine systems of 150kW, 300kW, and 750kW are estimated at 301,363kWh, 651,593kWh, and 1,668,825kWh, respectively. Their annual capacity ratios are 22.9%, 24.8%, and 25.4%, respectively. Since difference in wind speed due to difference in altitude is small, it is supposed that the wind speed at the hub altitude is not so high. It is inferred consequently that service operation will be quite difficult to realize. Difficulties will be also encountered in relation to the route of turbine system transportation, power distribution line, and the distance to a transformation station. (NEDO)

  15. 1998 Annual Study Report. Standardization of image processing for digital home equipment; 1998 nendo seika hokokusho. Kateiyo digital denshi kiki ni okeru digital gazo shori no hyojunka

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The electronic industry should invariably correspond to MPEG-4, when considering the essential conditions for home information equipment of the next generation to be used massively. This project is aimed at formulation of the standard platform for MPEG-4, and identification of the necessary examples and corresponding the necessary tools/functions thereto, to give an impetus for the future development, and to positively provide the additional aids to the tools which strengthen MPEG-4 in the arena of promoting the international standardization. The efforts in this year began with investigations on the assumption of the concrete application examples, considered from the standards' structures, and were concentrated on investigations on characteristic problems involved in each of the system, server and client blocks which constitute the system, and then on identification of the products application, based on the analysis of the MPEG-4 profiles and levels. These have led to selection of an MPEG-4 receiver as the case study item for extracting problems possibly involved in assembling works. (NEDO)

  16. Report on surveys in fiscal 2000 on the surveys and researches in relation to nano-technology; 2000 nendo nano technology ni kakawaru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    In order to view over the situation surrounding the nano-technology as a whole, surveys and discussions were given by means of questionnaire and open discussion meetings. In the questionnaire, the answer that the products utilizing nano-scale structure have already been, or scheduled to be put on sale has exceeded half of the total answers. Experts view that the nano-technology is infiltrating steadily into the actual society. In view of the applicable fields, and in the opening discussion meetings, drastic innovation was expected in the industrial technologies in the future not too far away as a dream world, by using the 'nano-technology' that utilizes a principle completely different from the principles that have been practically used. In order to achieve that goal, a recognition was made clear that the braeakthrough in other fields is important, and the field crossing fusion such as coordination with academia, and exchanges between different businesses and different fields is important. In the comparison of competitive edges of Japan, America and Europe, Japan was recognized to possess sufficient competitive power, but the sense of crisis is felt toward the latent technological power of America of the future. (NEDO)

  17. FY 1998 annual report on the research and development of superhigh-sensitivity photocurrent conversion devices; 1998 nendo chokokando koden henkan soshi ni kansuru kenkyu kaihatsu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Described herein are research and development of superhigh-sensitivity photocurrent conversion devices. The huge photocurrent multiplication effect exhibited by a thin film of organic pigment semiconductor is expected to be applicable to various new devices, e.g., superhigh-sensitivity, intelligent optical sensor families and photocurrent devices. Photocurrent multiplier thin films of perylene is prepared by an ionized cluster beam method, to evaluate their structures and photocurrent characteristics as the basic knowledge for controlling their characteristics by the ion engineering procedures. Photocurrent multiplier thin films of new, two-layer structure are developed, and improvement and stabilization of their characteristics are studied. Increasing sensing sensitivity by, e.g., introduction of p-n junction and reducing dark current resulting from the light memory effect are found to be effective to improve the S/N ratio. An organic EL light-emitting layer capable of positive/negative feedback, as one of the elementary techniques for realizing intelligent devices, is made on a trial basis and evaluated for its characteristics, and studied for its application to photocurrent multiplier thin films. Functional devices in which the arithmetic and controlling functions of the thin films are utilized are also studied. (NEDO)

  18. Evaluation report on research and development of an ultra-advanced processing system. 3; Chosentan kako system no kenkyu kaihatsu ni kansuru hyoka hokokusho. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-08-01

    This paper describes comprehensive evaluation on the following technologies as the ultra-advanced processing system: (1) large output excimer laser, (2) high-density ion beam, (3) an ultra-precision machining device, (4) ultra-advanced processing, (5) measurement and evaluation, and (6) comprehensive test. In the item (1), research and development was performed on such technologies as output increasing, output stabilization and beam formation, having achieved the targets. In the item (2), research and development was performed on such technologies as beam convergence, plasma control, ion transportation, high-frequency quadruple pole acceleration, and large-capacity class ion beam, having achieved the targets. In the item (3), research and development was performed on form creation and ultra-precision machining, having achieved the targets. In the item (4), research and development was performed on formation of high function thin films to apply the laser abrasion process to large area, ion surface modification, wide band area optics, high reflectance optics, ion injection, dynamic mixing, and modification of ultra high-grade metal surface, having achieved the targets. In the item (5), research and development was performed on high-accuracy roughness measurement, shape measurement, optical property evaluation, a wavelength meter, ultra advanced processing standard measurement, and environment correction technology, having achieved the targets. In the item (6), comprehensive demonstration was carried out on the component technologies. (NEDO)

  19. FY 1993 annual report. Survey and study on establishment of databases for body functions; 1993 nendo shintai kino database no kochiku ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    As part of the health/welfare-related information collection, analysis and information service project, establishment of the databases is surveyed and studied for human life technology and body functions of the aged in the aging society. The survey/study on establishment of the human life technology for the aged covers concept of human life technology, systems of the databases for human life technology, and techniques for the database systems. The case study on the human life technology databases for the aged takes up everyday life behaviors of the aged as the models, and analyzes human and life characteristics in everyday life, to clarify the human characteristic, human performance and human life technology design data to be stored in the databases. The validity of the method developed by this project is tested for their behaviors, such as bathing and outgoing. For establishment of the databases for body functions of the aged, literature surveys and interviews are conducted for the technological trends. (NEDO)

  20. Report on the research achievements in the Sunshine Project in fiscal 1992. Studies on a direct gasification catalyst; 1992 nendo chokusetsu ekika shokubai ni kansuru kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-10-01

    This paper describes the research achievements in the Sunshine Project in fiscal 1992 in studies on a direct gasification catalyst. The paper summarizes the points where the catalyst research has reached to date. The catalyst surface effective for hydrogenation is the metal surface that can dissociate hydrogen. However, metals having large adsorption heat against hydrogen do not show the activity greatly because these metals are difficult of desorbing hydrogen having high dissociating activity. The coal liquefaction system has the surface oxidized by water content, wherein hydrogen dissociation cannot be expected, and sulfides are suitable. When a sulfide catalyst contacts hydrogen, the catalyst itself is desulfurized, producing H{sub 2}S and becomes a low-order sulfide. When atmospheric H{sub 2}S contacts this sulfide, it dissociates into HS and H, and this H behaves as active hydrogen. However, the liquefaction activity can be recognized even in a sulfuric acid type catalyst containing no sulfide whatsoever, wherein the H{sub 2}S partial pressure in the reaction system becomes extremely low. This fact means that the active hydrogen is not necessarily generated by the dissociation of H{sub 2}S. There is no other way but to think that hydrogen is dissociated directly without going through H{sub 2}S. If this is true, it provides a new guideline in developing and designing the future catalysts. (NEDO)

  1. Fiscal 1999 technical survey report. Survey of energy conservation technologies in Japan; 1999 nendo kokunai no sho energy gijutsu ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    NEDO (New Energy and Industrial Technology Development Organization), in its effort to implement a joint project with importing countries, endeavors to popularize energy conservation technologies by introducing them into plants in the importing countries and by demonstrating their validity on real systems. Energy conservation technologies in use in Japan's steelmaking, cement making, chemical, and oil refining industries were reassessed in view of their usefulness in the above-said project. During the reassessment, they were analyzed also for cost effectiveness for the scales on which they would possibly be introduced. Ninety-four technologies were reassessed, which involved the top pressure recovery facilities, continuous casting facilities, high frequency melting furnace, and high efficiency sintering furnace ignition device, these for the steelmaking industry; the materials crushing vertical roller mill, NSP (new suspension preheater) type cement calcination kiln, finishing process preliminary crusher, urban wastes conversion into materials for cement making or into fuel, these for the cement making industry; the multi-effect evaporator for an ammonia manufacturing process and the device for collecting waste heat at the outlet of a synthetic gas compressor, these for the chemical industry; and reduction in the amount of injection steam by use of vacuum distillation tower top steam recycling, etc., these in relation with oil refining facilities. (NEDO)

  2. Report on evaluation of research and development of superhigh-function electronic computers; Chokoseino denshi keisanki no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1973-02-20

    Described herein is development of superhigh-function electronic computers.This project was implemented on a 6-year joint project, beginning in FY 1966, by the government, industrial and academic circles, with the objective to develop standard, large-size computers comparable with those of the world's highest functions by the beginning of the 70's. The computers developed by this project met almost all of the specifications of the world's representative, large-size commercial computers, partly surpassing the world's machine. In particular, integration of the virtual memory, buffer memory and multi-processor functions, which were considered to be the central technical features of the computers of the next generation, into one system was a Japan's unique concept, not seen in other countries. The other developments considered to have great ripple effects are seen in LSI's, and techniques for utilizing and mounting them and for improving their reliability. Development of magnetic discs is another notable result for the peripheral devices. Development of the input/output devices was started to correspond to inputting, outputting and reading Chinese characters, which are characteristics of Japan. The software developed has sufficient functions for common use and is considered to be the world's leading, large-size operating system, although evaluation thereof largely awaits the actual specification results. (NEDO)

  3. Evaluation report on the research and development of automatic sewing systems; 'Jido hosei system' no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-03-01

    A comprehensive evaluation is made upon completion of the automatic sewing system research and development project. The project aims to achieve a 50% increase in productivity through effective use of a multiple-product/small-amount production scheme in small and medium sewing industries. The intelligent cloth inspecting machine (prior to sewing) in a laser-aided cutting system is as competent as the currently used sewing mill inspection system, and the resultant data are effectively utilized in the cutting process. As for the cutter, it is demonstrated that it is more than two times higher in cutting speed than a currently used laser cutting system; that it is sufficiently accurate in avoiding parts with flaws and in pattern matching; and that it is reliable in complying with process information provided. As for the flexible sewing system, it is acknowledged that it correctly recognizes information attached to cut parts and that it joins them with flexibility in response to changes in the material, pattern, or size. As for the high-technology assembling system, satisfaction is found in its automated 3-dimensional sewing of parts received from the previous stage and in its flow of production. As for the 3-dimensional flexible press, the quality after finish is found satisfying. The said systems are integratedly operated, and it is found that the goal of the research and development has been achieved. (NEDO)

  4. FY 1998 annual report on power generation by waste heat from cement production in China; Chugoku ni okeru cement hainetsu hatsuden 1998 nendo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This project is to implement a feasibility study for applying waste heat power generation, which have been already commercialized in Japan and producing remarkable results, to China's cement plants producing 3,500 t/d or more of clinker, and thereby to try to establish a link with the Japan's clean development mechanism. It is expected that introduction of these systems improves energy use efficiency and environments in China. The study results indicate that the project for a Tongling Conch plant could generate power of 15,000 kW, reducing CO2 emissions by 89,178 t/y and cumulatively 1,783,560 tons in the 20-year period. The results also indicate that the project will be highly profitable, with an estimated internal return rate of as high as 33.78%. The project for a Huaxin plant could generate power of 8,400 kW, reducing CO2 emissions by 48,412 t/y and cumulatively 968,240 tons in the 20-year period, annually saving power charges by 325 million yen and bringing an internal return rate of 10.72%. (NEDO)

  5. Fiscal 1998 survey report. Survey on method of environmental-impact assessment in wind power development; 1998 nendo furyoku kaihatsu ni okeru kankyo eikyo hyoka shuho chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    With the purpose of preparing the main points of 'environmental-impact assessment guidelines for wind power developments (draft)', examples of environmental-impact assessments, related laws and regulations in Japan and abroad were collected, and rearranged in respect to requirements in environmental-assessments, concrete procedures, survey/projection/assessment method, summarisation of results, etc. It was clarified, for example; in a large-scale wind power development, it can be dealt with by choosing items and contents on the assumption that a land area is developed; in a small-scale development, there is basically no need of considering the possible effect of the construction work; and, as far as noise, vibration and the ecosystem (plants/animals) are concerned, however, the characteristics of the site be taken into consideration. Objects for general assessment are noise, low-frequency air vibration, radio wave interference, the ecosystem (plants and animals) and the landscape. The guideline draft is constituted of (1) basic items, (2) overview of the area, (3) determination of items for environmental-impact assessment and (4) research, prediction, assessment, conservation measures and follow-up research; in the basic items, importance of preliminary consideration was emphasized, as were priority/simplification, implementation of environmental conservation measures, and implementation of follow-up research. (NEDO)

  6. Report on a survey in fiscal 1999. Survey on movements in technologies related to climate change; 1999 nendo kiko hendo ni kansuru gijutsu doko chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Working group 3 of the Intergovernmental Panel on Climate Change (IPCC) is now conducting technological and socio-economical assessments of climate change mitigation measures. The objectives of this research are, in conjunction with the IPCC activities, to perform investigation on the draft of the Third Assessment Report and the related literatures, and survey and study movements in technologies for climate change mitigation measures by performing investigations and researches by using models as required. Chapter 1 generalizes the activities of IPCC since 1988, and describes the preparation schedule for the third assessment report being worked on, as well as the summary movements thereof and the features of the third assessment report. Chapter 2 states the history of the activities. Chapter 3 describes that the third assessment report (draft) being prepared by the Working Group 3 is composed as a whole of the options of implementation, the theoretical background of the implementation, the international institutions, and the evaluation on the implementation. It generalizes the first order draft (FOD). Chapter 4 states the results of investigations on the points of issue which were regarded as the problems in the process of preparing the FOD. Chapter 5 describes the investigations of the FOD, making various important keywords as the axis of the investigations. (NEDO)

  7. FY 1999 report on investigation on establishment of body function database; 1999 nendo shintai kino database no kochiku ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The investigation is made to provide the data which widely cover various characteristics of aged persons for the general designers who design equipment and environments for aged persons. It is found, by the tests for measuring sight and hearing sensations of the aged, that they generally need higher sound to hear; frequency of alarming sound is preferably lowered from 3,000 to 4,000Hz now used for the equipment to 1,000 to 2,000Hz, and the level at which sound can be heard is significantly different from that at which the announcement can be understood. For evacuation order or the like, for example, it is necessary to announce the disaster site and evacuation routes, which the aged hear for the first time, especially slowly and distinctively. The database of body functions of the aged are improved by correcting the problems associated with depth of strata and poor prospects, frequently pointed out by those who look up the data from the daily actions, in such a way that the system can be easily looked at from notices for each function position of the product and also from the related human characteristics. (NEDO)

  8. Report on a survey in fiscal 1999. Survey on movements in technologies related to phytoremediation; 1999 nendo phytoremediation ni kansuru gijutsu doko chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This survey is intended to discuss the status quo in movements of technologies related to phytoremediation (PM) that utilizes metabolic functions of plants, the overseas situation thereof where the PM application has advanced, and the future technological problems. The PM can be divided largely into the following four categories according to the actions of plants: 1) phyto-extraction - absorbs substances dissolved in water directly or through actions of leguminous bacteria to purify the water or soil; 2) phyto-transformation - action to absorb polluting substances into plant bodies and decompose them; 3) phyto-stimulation - rhizospheric microorganisms are activated by enzymes secreted from roots to decompose chemical substances; and 4) phyto-stabilization - actions to fix or stabilize polluting chemical substances by actions of substances secreted from plants and/or leguminous bacteria in soil and interactions with soil particles. Japan's independent researches have derived such researches as a research to utilize street lining trees to purify polluted air, a research to realize purification of hard-to-degrade substances by introducing degradable genes of microorganisms, and a research intended to create plants that accumulate in them heavy metals densely. (NEDO)

  9. Fiscal 1998 research report. Feasibility survey on offshore wind power generation in Japan; 1998 nendo chosa hokokusho. Nippon ni okeru yojo furyoku hatsuden no donyu kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This survey studied the feasibility of large-scale offshore wind power generation in Japan. Attempt was also made on preparation of outline maps of offshore wind around Japan. The cost of future offshore wind power generation systems is roughly dependent on technical issues and environmental issues. As technical issues, 'installation site,' 'foundation,' 'system interconnection' and 'maintenance/management' were summarized based on applications in Europe. As a result, it was clarified that technical issues can be solved with existing technologies to a certain extent, however, those relate to economical problems closely. The previous environment impact assessments say that wind power generation has no problems on the environmental issues. As relatively strong wind coastal areas, the outline maps of offshore wind point out Western Hokkaido area, Japan Sea area of Tohoku district, Pacific ocean area of the central part of Honshu, Genkai Nada area, Western Kyushu area and Southwest islands area, and suggest that these areas are promising for offshore wind power generation. (NEDO)

  10. Survey report for fiscal 1999. Project of diffusing gas driven cooling systems in Oman; 1999 nendo Oman koku ni okeru gas reibo fukyu jigyo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    With the clean development mechanism (CDM) borne in mind, a study is made about the diffusion of gas driven cooling systems in Oman. The project under study aims to replace the motor driven turbo cooling systems, now in use at the Royal Hospital and other buildings in various areas, with gas driven cooling systems. It is then found that, when the Royal Hotel is equipped with such systems, energy will be saved by 1,855 tons/year in terms of oil, and greenhouse gas reduced by 5,129 tons/year in terms of CO2. When the Royal Hospital and other large buildings with heavy cooling loads, situated at or near the center of Muscat City and in the vicinity of the existing natural gas pipelines, are taken into account, energy will be saved by 13,049 tons/year in terms of oil and greenhouse gas will be reduced by 31,636 tons/year in terms of CO2, thanks to the presence of universities, hotels, and a sector occupied by government offices. As for the time necessary for investment recovery, it will be 4.7-5.3 years in case the investment does not cover a gas decompression station construction cost and 6.2-6.8 years in case it covers such. The new system will cost 7% less than the existing system. When a comparison is made in terms of electricity charges, the new system will be 30% lower than the existing system. The Omani Government is critical of a plan for allowing Japan to establish there an energy supply company (financed by Japan). (NEDO)

  11. Report on the surveys in fiscal 1999. Surveys on practical application of the research achievements; 1999 nendo kenkyu seika no jitsuyoka ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    A number of technological hurdles exist in the process of practically applying the fundamental researches, wherein risks for private business entities to promote the technological development are not at all small. The present surveys are intended to elucidate the actual status as to how a practical application process for technologies is positioned in the series of research and technological development activity floats by private corporations, and what kinds of problems are present, to serve for discussing the way the future supportive environment improvement should be. The 'practical application processes' in private corporations were put into order and analyzed, using as the base the existing study results relative to technological innovation mechanisms. Investigations ere performed on the existing Japanese research and technological development supporting institutions for the practical application processes employed by the private corporations. The result was used for reference of discussing the problems therein. Furthermore, it is indicated that, in the R and D strategies in the U.S.A., profitability is placed as the largest target by means of strengthening the linkage between research and commercialization. This has resulted in decline in the fundamental researches, for which discussions are developed currently. This paper reports investigations on the actual status of business enterprises in the practical application processes. (NEDO)

  12. Report on a survey in fiscal 1999. Survey on movements in technologies related to phytoremediation; 1999 nendo phytoremediation ni kansuru gijutsu doko chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This survey is intended to discuss the status quo in movements of technologies related to phytoremediation (PM) that utilizes metabolic functions of plants, the overseas situation thereof where the PM application has advanced, and the future technological problems. The PM can be divided largely into the following four categories according to the actions of plants: 1) phyto-extraction - absorbs substances dissolved in water directly or through actions of leguminous bacteria to purify the water or soil; 2) phyto-transformation - action to absorb polluting substances into plant bodies and decompose them; 3) phyto-stimulation - rhizospheric microorganisms are activated by enzymes secreted from roots to decompose chemical substances; and 4) phyto-stabilization - actions to fix or stabilize polluting chemical substances by actions of substances secreted from plants and/or leguminous bacteria in soil and interactions with soil particles. Japan's independent researches have derived such researches as a research to utilize street lining trees to purify polluted air, a research to realize purification of hard-to-degrade substances by introducing degradable genes of microorganisms, and a research intended to create plants that accumulate in them heavy metals densely. (NEDO)

  13. Fiscal 1991 report. Overseas surveys out of surveys for coal hydrogasification technology development; 1991 nendo sekitan suiten gaska gijutsu kaihatsu chosa ni okeru kaigai chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-11-01

    For the selection and evaluation of coal gasification processes suitable for substitute natural gas (SNG) production, visits were made to business corporations, research institutes, etc., engaged in the development of coal gasification technology abroad, and surveys were conducted of the development status overseas and information was collected. Visits were made and information was collected on the Lurgi process, a commercial SNG plant, and others at Dakota Gasification Company, U.S.; U-gas process and others at Institute of Gas Technology; energy-related matters at U.S. Department of Energy; coal hydrogasification process and others at Midlands Station, British Gas plc; Shell coal gasification process and others at Amsterdam Research Institute, Royal Dutch Shell; coal gasification, high-temperature desulfurization, and others at KEMA, Holland; and IGCC (integrated gasification combined cycle) verification plant with the Shell coal gasification process incorporated thereinto, now under construction at Demkolec. (NEDO)

  14. Report on construction of thermal power plants for industrial use in China in FY 1997; 1997 nendo chosa hokokusho (Chugoku ni okeru kogyoyo karyoku hatsuden setsubi secchi)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Steam supply and power generating plants in China can be classified into systems for district heating and power generation and systems for steam supply and power generation for industrial use. Steam supply and power generating plants for district heating in winter season are diffused due to the introduction of Russian technology. There are steam supply and power generating plants for supplying steam to manufacturing equipment in works and generating power for industrial use. Both of these are called heat and power stations. This survey was conducted for the latter thermal power generation plants for industrial use. China has heat and power stations with a total capacity of 22,000 MW, and a half of them are used for district heating. Although the thermal efficiency of usual thermal power generation plants is between 30 and 40%, that of heat and power stations is between 60 and 70%. Latent demand of such power generation plants for industrial use is large. Problems for the diffusion were extracted. It was considered that steam supply and combined power generating plants using natural gas are effective when constructed in large cities, in the vicinity of large cities, or in technological universities. 22 figs., 15 tabs.

  15. Report on achievements in fiscal 1975 in Sunshine Project. Studies on a technology to measure inside of wells; 1975 nendo koseinai sokutei gijutsu ni kansuru kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-03-01

    In order to identify the actual status of geothermal reservoirs, development is made on a technology to detect cracks in a geothermal reservoir. This fiscal year has launched development of a PS sonic logging device of well wall compression type, which is considered most effective in crack detection. This device has a number of new development elements such as a mechanism to have a transmitter and a receiver compressed on a geologic stratum to send sonic energy directly into the stratum, simultaneous use of S-wave having excellent characteristics in evaluating crack faces quantitatively and calculating porosities, and a cooling mechanism for electronics installed in the wells. Combining this with a micro seismogram log scheduled to be fabricated in fiscal 1976 will form the mainstream of crack face detection. A continual flow meter measures behavior of steam and hot water to identify flow-out or flow-in patterns and depths of fluid in wells under flowing condition. Adding this meter to temperature and pressure elements scheduled to be developed in fiscal 1976 will provide data to give an important guideline in underground heat production. This meter was attempted with enhancement in heat and pressure resistant characteristics and stabilization of operation for design and fabrication, which were carried out using the spinner flow meter as the base. (NEDO)

  16. Fiscal 2000 survey report. Survey and study of constellation satellites technology; 2000 nendo chosa hokokusho. Konsutereshon eisei gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Demands for constellation satellites were surveyed and satellite systems were studied for extracting basic technical tasks relative to constellation satellite systems and for drafting space verification plans. For a constellation satellite system to accomplish its missions, two or more satellites have to be simultaneously navigated. It is assumed that its field of application will cover earth observation, information communication, risk management, disaster prevention, and the like. With such applications taken into consideration, surveys and studies were conducted about the need and marketability of constellation satellites, need of state-level involvement, and requests for missions to be imposed on a constellation system. For plural satellites to satisfy mission requests by coordinating with each other, it will be necessary to develop basic technologies, such as navigational guidance, communications control, system autonomous management, and operation on the ground. Functions and performance that a constellation satellite system are requested to have and basic technologies to be studied and developed were extracted, and space verification plans were drafted. (NEDO)

  17. Evaluation report on research and development of an ultra-advanced processing system. Summary edition; Chosentan kako system no kenkyu kaihatsu ni kansuru hyoka hokokusho. Gaiyohen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-08-01

    Research, development and evaluation were performed with an objective of establishing the basic processing technology and ultra-precision machining device technology utilizing large output excimer laser and high density ion beams. With regard to the large output excimer laser technology, the short wavelength excimer laser life extension technology has demonstrated ong-life operation of 1.02 times 10{sup 9} shots exceeding the final target at the initial laser output of 105 mJ/pulse. With respect to the high-density ion beam technology, the gas phase converged ion beam technology has achieved an ionic current density of 2.5 {mu}A/sr. and a beam current of 25 pA. Regarding the ultra-precision machining device technology, a large ultra-precision grinding machine of five shaft control type was developed as a final target demonstrating machine, which exhibited the shape accuracy of 0.7 {mu}m and surface roughness of 3.45nm. The surface roughness satisfied the final target. Other activities include studies on the ultra-advanced processing technology, measurement and evaluation technology, comprehensive tests, and practical application of the technologies, having derived respective achievements. (NEDO)

  18. Report on the cooperative study of technology to collect valuable resources in brine; Kansuichu no yuka shigen kaishu gijutsu ni kansuru kenkyu kyoryoku hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The paper reported on the research, design, and evaluation on a system to recover by sedimentation magnesium from the brine in the salt manufacture by solar evaporation in Mexico, and a system to recover by adsorbent lithium, boron, etc. from the brine of the solar pond salt field in China. In the case of Mexico, an overall recovery system was developed, but in the evaluation of economy of the system, it cannot be said that the system is feasible even if assuming that the required fresh water can be secured. It was found out that the economical efficiency largely depends upon the cost of hydrated lime and the selling price of magnesia clinker. In the case of China, a plant for production of 500 tons/year of lithium carbonate was conceptually designed to evaluate the economical efficiency. As a result, the internal profitability of the plant is not so high, approximately 6%, though continuously profitable during the operation of 15 years. It was indicated that the project was not economically very efficient. 164 figs., 44 tabs.

  19. Fiscal 1998 research report. Feasibility study on international cooperation for technology transfer; 1998 nendo chosa hokokusho. Gijutsu iten ni kakawaru kokusai kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    CTI (Climate Technology Initiative) is a framework for use by developed countries in international cooperation and voluntary promotion of the development and diffusion of technologies contributory to reduction of greenhouse gas emissions. The CTI's activity goal is to accelerate the transfer and diffusion of technologies for climate change control. As the first step toward personnel development programs relating to energy efficiency, CTI organized its workshop on that theme. The results of the workshop have been examined, and its achievements were reported at COP4 meeting, while responses by participatory countries were studied to evaluate the potential of international cooperation with regard to personnel development for reducing greenhouse gas emissions. In fiscal 1998, the CTI workshop 'Energy Efficiency' was held. The participants from developing countries understood the necessity and importance of energy saving enough through discussions in the workshop, and announced their message toward the world at COP4 meeting. (NEDO)

  20. Report on `Survey of commercialization of intellectual ownership such as patent rights`; `Tokkyoken nado chiteki shoyuken no jitsuyoka ni kansuru chosa` hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    A survey was conducted on research results in industrial circles, universities, etc. in the U.S., Europe and Japan, especially the state of how intellectual ownership such as patent rights is handled and the present situation of the commercialization of intellectual ownership, proposing problems and measures to be taken for promotion of practical use of excellent research results in Japan. The most important thing obtained from the survey is that study jointly by industrial circles and universities in the U.S. and Europe is much more advancing than that in Japan and is firmly established not only in industrial circles, universities and national research institutes, but in the whole society, actually producing a lot of favorable results. For Japan to catch up with the U.S. and Europe, needed is not only accumulation of the ideas in the past, but drastic measures to be taken from a new point of view. Concretely, it was proposed that by belonging intellectual properties such as patent rights to universities/research institutes and transferring their disposal rights to them, royalties of licenses are given back to inventors as incentives, and that as a body promoting the transfer to the industrial circle, `management organization` to which private vitality is introduced is established in universities/research institutes in order to promote interconnection between the industrial circle and universities. 15 refs., 35 figs., 36 tabs.

  1. Report on the field test project for wind power development at Yaku Town (wind characteristics investigation); Yakumachi ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    Wind characteristics are observed for a year at Yakushima Young Travellers' Village of the above-named town, Kagoshima Prefecture. The exponential index of the wind speed distribution in the vertical direction is between 1.6 and 4.7, or 3.5 on the average, relatively small due probably to the peculiar terrain and causing no trouble in the development. Turbulence intensity is 0.16 at when the wind speed is 2m/s or more, low enough to meet the reference value (0.30 or less). The total occurrence rate on the prevalent wind axis (SSE-NNW) is 48%, falling short of the reference value (60% or more). The average wind speed in the prevalent wind direction is high and the wind energy density concentrates on the prevalent wind axis, this showing that the site is good for wind power development. The annual average wind speed is 5.6m/s, slightly lower than the reference value (5.8m/s or more). Since there are possibilities of a maximum instantaneous wind speed of over 60m/s, caution is to be used in determining the wind endurance level for the wind turbine design. The annual wind energy density is 325W/m{sup 2}, fully meeting the reference value (215W/m{sup 2} or more). The annual operation rates of the 150/300/750kW wind turbine models are 61/65/80%, and these meet the reference value (45% or more). Their annual capacity ratios are 24.5/26.6/27.7%, and these again meet the reference value (17% or more). (NEDO)

  2. Report on surveys in fiscal 2000 on the surveys and researches in relation to nano-technology; 2000 nendo nano technology ni kakawaru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    In order to view over the situation surrounding the nano-technology as a whole, surveys and discussions were given by means of questionnaire and open discussion meetings. In the questionnaire, the answer that the products utilizing nano-scale structure have already been, or scheduled to be put on sale has exceeded half of the total answers. Experts view that the nano-technology is infiltrating steadily into the actual society. In view of the applicable fields, and in the opening discussion meetings, drastic innovation was expected in the industrial technologies in the future not too far away as a dream world, by using the 'nano-technology' that utilizes a principle completely different from the principles that have been practically used. In order to achieve that goal, a recognition was made clear that the braeakthrough in other fields is important, and the field crossing fusion such as coordination with academia, and exchanges between different businesses and different fields is important. In the comparison of competitive edges of Japan, America and Europe, Japan was recognized to possess sufficient competitive power, but the sense of crisis is felt toward the latent technological power of America of the future. (NEDO)

  3. Survey on the life cycle system of a product with shared information; Joho kyoyugata product life cycle system ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This report provides and proposes new concept and optimization technology on the life cycle system of product for emission minimum. For the proposed life cycle system of product with shared information, the global emission minimum is realized by considering the final emission, the information is given to the product and shared in all the life cycle system, the information sending function is considered from the product, and the information necessary for material processing are actively used. For this life cycle system of product, development of the information model for the system, development of the technology of data saving, renewing, searching and sending, development of sensing and re-using technologies of the product for life cycle, development of the technology attaching information in the product for emission minimum, design of the guidelines of material composition, and research and development of materials for emission minimum are extracted and provided as tasks. 26 refs., 69 figs., 8 tabs.

  4. Report on survey of promotion of activities implemented jointly in China in FY 1997; 1997 nendo chosa hokokusho (Chugoku ni okeru kyodo jisshi katsudo no suishin chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Rapid economy growth has been observed in Asia including Japan. On the other hand, problems of population and environment grew even worse with the economic growth. Especially, China is the second CO2 emission country in the world. Large energy demand is still forecasted with its economic growth in the future. It is well-known that the energy consumption per unit GDP is very large. Therefore, it is very significant to promote the activities implemented jointly with China for mitigating the emission of greenhouse gases including CO2, which provides a significant meaning for solving global environmental issues as well as for improving regional environmental issues. It is necessary for the above to recognize the appropriate current situations and to promote the activities implemented jointly suitable for the country. Based on the discussions and information exchanges about environmental issues with staffs concerning environmental policies and scientists as well as the field surveys, methods for the activities implemented jointly were investigated to provide some proposals. 4 figs., 8 tabs.

  5. Fiscal 1997 survey report. Survey on the innovative well drilling technology; 1997 nendo chosa hokokusho. Kakushinteki kosei kussaku gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In the geothermal drilling, reduction of the cost of well drilling is an important subject for technical development. The geothermal resource development tends to be made at higher temperatures and at deeper wells. In the present drilling technology, the cost is rising with the exponentially increasing depth and temperature, and there is also occurring the technical limit. Accordingly, the survey clarified the limit of the present drilling technology/cost to point out the research trend of the drilling technology as substitute for the present one, possibilities of the introduction, and the R and D target and subjects. As to latest drilling systems abroad and in Japan, the following were surveyed to study and extract promising technologies and systems: improvement/application of drilling equipment/materials (enhancement of heat resistance of the main drilling equipment, etc., cooling effects of top drive, heat resistance verification of MWD tools, PDM, tricone bits, multi-stage cementing tools, etc.), heightening of drilling rates, trend surveys of slim hole drilling, control drilling, well maintenance/workover, and well design technology. 68 refs., 73 figs., 40 tabs.

  6. Evaluation report on research and development of high-speed computation system for technological use; Kagaku gijutsuyo kosoku keisan system no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-08-01

    The above-named project is an effort implemented under the large-scale industrial technology research and development system through the cooperation of industrial, academic, and governmental circles in the nine-year-long period beginning in fiscal 1981. The project aims to establish technologies required for putting to practical use a high-speed computation system capable of speedily dealing with huge technological problems which the computers available at the commencement of the project failed to solve. The goals set for new devices and comprehensive systems were sufficiently challenging in view of the technological level of those days, and are still at the highest level in the world. It is judged that the goals were set with reason and appropriateness. The liaison council for the implementation of the project is constituted of people of experience or academic standing, entrusted research and development activities, Ministry of International Trade and Industry bureaus concerned, and the Electrotechnical Laboratory of the same ministry. Discussion, coordination, and communication on concrete matters are under way between the constituent members, contributing to the enhancement of research and development. The liaison council activities are evaluated to be appropriate and effective. (NEDO)

  7. Fiscal 1999 survey report. Survey and research concerning development of next-generation chemical process technologies; 1999 nendo jisedai kagaku process gijutsu kaihatsu ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    To further enhance resource/energy conservation and environmental impact reduction, it is necessary to develop innovative chemical reaction process technologies. It is for this reason that 'development of next-generation chemical reaction process technologies' is being carried out under the New Sunshine Program. The survey and research, for the fulfilment of the above goal, aim to select important technologies and put in a easy-to-study order the problems contained in associated technologies for picking out tasks for future studies for the purpose of suggesting some subjects to be taken up for future development. In addition, studies are made about how a comprehensive technology assessment system should be. In this fiscal year, propositions are compiled for research and development projects on five subjects. Studies of subjects other than these five will also continue to eventually build concrete propositions on them. The said five subjects involve 1) the development and application of nonaqueous biotechnologies, 2) biotechnology-aided polymeric material creation processes, 3) construction of high-efficiency energy conservation processes using innovative grain handling technologies in the high-temperature reaction field, 4) manufacture of high-performance polymeric materials for batteries and development of battery fabrication processes, and 5) the development of an energy conservation process maximally utilizing environmentally-friendly polyolefin. (NEDO)

  8. Fiscal 1998 research report. Feasibility survey on offshore wind power generation in Japan; 1998 nendo chosa hokokusho. Nippon ni okeru yojo furyoku hatsuden no donyu kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This survey studied the feasibility of large-scale offshore wind power generation in Japan. Attempt was also made on preparation of outline maps of offshore wind around Japan. The cost of future offshore wind power generation systems is roughly dependent on technical issues and environmental issues. As technical issues, 'installation site,' 'foundation,' 'system interconnection' and 'maintenance/management' were summarized based on applications in Europe. As a result, it was clarified that technical issues can be solved with existing technologies to a certain extent, however, those relate to economical problems closely. The previous environment impact assessments say that wind power generation has no problems on the environmental issues. As relatively strong wind coastal areas, the outline maps of offshore wind point out Western Hokkaido area, Japan Sea area of Tohoku district, Pacific ocean area of the central part of Honshu, Genkai Nada area, Western Kyushu area and Southwest islands area, and suggest that these areas are promising for offshore wind power generation. (NEDO)

  9. FY 1998 survey report. Examinational research on the construction of body function database; 1998 nendo chosa hokokusho. Shintai kino database no kochiku ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The body function database is aimed at supplying and supporting products and environment friendly to aged people by supplying the data on body function of aged people in case of planning, designing and production when companies supply the products and environment. As a method for survey, group measuring was made for measurement of visual characteristics. For the measurement of action characteristics, the moving action including posture change was studied, the experimental plan was carried out, and items of group measurement and measuring methods were finally proposed. The database structure was made public at the end of this fiscal year, through the pre-publication/evaluation after the trial evaluation conducted using pilot database. In the study of the measurement of action characteristics, the verification test was conducted for a small-size group. By this, the measurement of action characteristics was finally proposed. In the body function database system, subjects on operation were extracted/bettered by trially evaluating pilot database, and also adjustment of right relations toward publication and preparation of management methods were made. An evaluation version was made supposing its publication. (NEDO)

  10. Continuum mechanics simulations of NiO/Ni-YSZ composites during reduction and re-oxidation

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Frandsen, Henrik Lund; Kaiser, Andreas

    2010-01-01

    for the dimensional change arises from the volumetric change related to the phase change NiO ↔ Ni. The measurable change in bulk length is given by the ceramic YSZ backbone as a response to the stress created by the chemical strain. The different subprocesses described in the model for YSZ were elastic and anelastic...... expansion, diffusional creep, grain boundary sliding (GBS) and microcracking due to excessive stress. In the Ni/NiO phase, nonelastic strains in terms of diffusional and power law creep were implemented, and additionally for NiO deformation due to microcracking and/or pseudoplasticity. Semi...

  11. Niños y niñas como cuidadores familiares

    OpenAIRE

    María Rosa Estupiñán Aponte

    2015-01-01

    En el contexto familiar, el cuidado de otra persona por parte de niños y niñas constituye un terreno inexplorado tanto en su significado como en las implicaciones que podrían darse en el proceso. Aunque históricamente se ha asignado el cuidado familiar a las mujeres generando condiciones de inequidad, incrementada con los cambios sociales de los últimos tiempos, es necesario reconocer que en muchos hogares niños y niñas se han visto obligados a desempeñar esta labor sin la preparación ni las ...

  12. .';.:NI~

    African Journals Online (AJOL)

    al wat ons werd was. Na middagete op 29 Junie, is ek per kar suid om die grand te gaan besigtig en om te sien hoe my stellings, van die vyandelike oogpunt, daaruit .... van Gatt se optrede moes die. Nieu-Seelanders, in 'n briljante nagaanval, met gevelde bajonette, 'n weg baan deur die vyand am daardie nag te ontvlug.

  13. Water dissociation on Ni(100) and Ni(111): Effect of surface temperature on reactivity

    International Nuclear Information System (INIS)

    Seenivasan, H.; Tiwari, Ashwani K.

    2013-01-01

    Water adsorption and dissociation on Ni(100) and Ni(111) surfaces are studied using density functional theory calculations. Water adsorbs on top site on both the surfaces, while H and OH adsorb on four fold hollow and three fold hollow (fcc) sites on Ni(100) and Ni(111), respectively. Transition states (TS) on both surfaces are identified using climbing image-nudged elastic band method. It is found that the barrier to dissociation on Ni(100) surface is slightly lower than that on Ni(111) surface. Dissociation on both the surfaces is exothermic, while the exothermicity on Ni(100) is large. To study the effect of lattice motion on the energy barrier, TS calculations are performed for various values of Q (lattice atom coordinate along the surface normal) and the change in the barrier height and position is determined. Calculations show that the energy barrier to reaction decreases with increasing Q and increases with decreasing Q on both the surfaces. Dissociation probability values at different surface temperatures are computed using semi-classical approximation. Results show that the influence of surface temperature on dissociation probability on the Ni(100) is significantly larger compared to that of Ni(111). Moreover, on Ni(100), a dramatic shift in energy barrier to lower incident energy values is observed with increasing surface temperature, while the shift is smaller in the case of Ni(111)

  14. Creatividad en niños superdotados

    OpenAIRE

    González Román, María del Pilar

    1992-01-01

    Se ha realizado un estudio sobre la creatividad en los niños superdotados. Analizándose los diferentes modelos de creatividad y superdotacion avalados por un estudio empírico, en el cual se han valorado las diferencial que existen entre los niños superdotados y contraste a nivel verbal y grafico-espacial.

  15. Preparation of one-step NiO/Ni-CGO composites using factorial design

    International Nuclear Information System (INIS)

    Araujo, A.J.M. de; Sousa, A R.O. de; Camposa, L.F.A.; Macedo, D.A.; Loureiro, F. J.A.; Fagg, D.P.

    2016-01-01

    This work deals with the synthesis, processing and characterization of NiO/Ni- CGO composite materials as potential solid oxide fuel cell (SOFC) anodes. The particulate materials were obtained by a one-step synthesis method and characterized by thermal analysis (prior to calcination) and X-ray diffraction (calcined powder). The ceramic processing of samples containing from 30 to 70 wt.% NiO was carried out by factorial design. Besides the NiO content controlled during the chemical synthesis, the impacts of the pore-former content (citric acid, used in proportions of 0, 7.5 and 15 wt.%) and the sintering temperature (1300, 1350 and 1400 °C) were also investigated. The open porosity of NiO-CGO composites and reduced Ni-CGO cermets was modeled as a function of factors (NiO content, citric acid content and sintering temperature) and interaction of factors. (author)

  16. Nanoscale structural heterogeneity in Ni-rich half-Heusler TiNiSn

    International Nuclear Information System (INIS)

    Douglas, Jason E.; Pollock, Tresa M.; Chater, Philip A.; Brown, Craig M.; Seshadri, Ram

    2014-01-01

    The structural implications of excess Ni in the TiNiSn half-Heusler compound are examined through a combination of synchrotron x-ray and neutron scattering studies, in conjunction with first principles density functional theory calculations on supercells. Despite the phase diagram suggesting that TiNiSn is a line compound with no solid solution, for small x in TiNi 1+x Sn there is indeed an appearance—from careful analysis of the scattering—of some solubility, with the excess Ni occupying the interstitial tetrahedral site in the half-Heusler structure. The analysis performed here would point to the excess Ni not being statistically distributed, but rather occurring as coherent nanoclusters. First principles calculations of energetics, carried out using supercells, support a scenario of Ni interstitials clustering, rather than a statistical distribution.

  17. Microstructural evolution of Ni40Zr60 alloy during early stage of mechanical alloying of intermetallic compounds NiZr2 and Ni11Zr9

    International Nuclear Information System (INIS)

    Lee Peeyew; Koch, C.C.

    1994-01-01

    The microstructural change of Ni 40 Zr 60 alloy during mechanical alloying of mixtures of the intermetallic compounds NiZr 2 and Ni 11 Zr 9 has been studied by transmission electron microscopy. A specific ''cauliflower'' phase was formed during early stage of mechanical alloying process. It is suggested that the solid state reaction between intermetallic compounds NiZr 2 and Ni 11 Zr 9 is not the only origin for the formation of the ''cauliflower'' phase. ((orig.))

  18. Microstructure and tribological properties of NiMo/Mo2Ni3Si intermetallic 'in-situ' composites

    International Nuclear Information System (INIS)

    Gui Yongliang; Song Chunyan; Yang Li; Qin Xiaoling

    2011-01-01

    Research highlights: → Wear resistant NiMo/Mo 2 Ni 3 Si intermetallic 'in-situ' composites was fabricated successfully with Mo-Ni-Si powder blends as the starting materials. Microstructure of the NiMo/Mo 2 Ni 3 Si composites consists of Mo 2 Ni 3 Si primary dendrites, binary intermetallic phase NiMo and small amount of Ni/NiMo eutectics structure. The NiMo/Mo 2 Ni 3 Si composites exhibited high hardness and outstanding tribological properties under room-temperature dry-sliding wear test conditions which were attributed to the covalent-dominant strong atomic bonds and excellent combination of strength and ductility and toughness. - Abstract: Wear resistant NiMo/Mo 2 Ni 3 Si intermetallic 'in-situ' composites with a microstructure of ternary metal silicide Mo 2 Ni 3 Si primary dendritic, the long strip-like NiMo intermetallic phase, and a small amount of Ni/NiMo eutectics structure were designed and fabricated using molybdenum, nickel and silicon elemental powders. Friction and wear properties of NiMo/Mo 2 Ni 3 Si composites were evaluated under different contact load at room-temperature dry-sliding wear test conditions. Microstructure, worn surface morphologies and subsurface microstructure were characterized by OM, XRD, SEM and EDS. Results indicate that NiMo/Mo 2 Ni 3 Si composites have low fiction coefficient, excellent wear resistance and sluggish wear-load dependence. The dominant wear mechanisms of NiMo/Mo 2 Ni 3 Si composites are soft abrasion and slightly superficial oxidative wear.

  19. Nonenzymatic Glucose Sensor Based on In Situ Reduction of Ni/NiO-Graphene Nanocomposite

    Directory of Open Access Journals (Sweden)

    Xiaohui Zhang

    2016-10-01

    Full Text Available Ni/NiO nanoflower modified reduced graphene oxide (rGO nanocomposite (Ni/NiO-rGO was introduced to screen printed electrode (SPE for the construction of a nonenzymatic electrochemical glucose biosensor. The Ni/NiO-rGO nanocomposite was synthesized by an in situ reduction process. Graphene oxide (GO hybrid Nafion sheets first chemical adsorbed Ni ions and assembled on the SPE. Subsequently, GO and Ni ions were reduced by hydrazine hydrate. The electrochemical properties of such a Ni/NiO-rGO modified SPE were carefully investigated. It showed a high activity for electrocatalytic oxidation of glucose in alkaline medium. The proposed nonenzymatic sensor can be utilized for quantification of glucose with a wide linear range from 29.9 μM to 6.44 mM (R = 0.9937 with a low detection limit of 1.8 μM (S/N = 3 and a high sensitivity of 1997 μA/mM∙cm−2. It also exhibited good reproducibility as well as high selectivity.

  20. Enthalpy of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys

    International Nuclear Information System (INIS)

    Witusiewicz, V.T.; Sommer, F.

    2000-01-01

    Since the Al-Cu-Ni-Zr system is a basis for the production of bulk amorphous materials by rapid solidification techniques from the liquid state, it is of great scientific interest to determine the partial and the integral thermodynamic functions of liquid and undercooled liquid alloys. Such data, as was pointed out previously, are important in order to understand their extremely good glass-forming ability in multicomponent metallic systems as well as for processing improvements. In order to measure the thermodynamic properties of the Al-Cu-Ni-Zr quaternary, it is necessary to have reliable thermochemical data for its constituent canaries and ternaries first. In a series of articles, the authors have reported in detail the thermodynamic properties of liquid Al-Cu, Al-Ni, Cu-Ni, Cu-Zr, Al-Zr, Al-Cu-Ni, and Al-Cu-Zr alloys. This article deals with the direct calorimetric measurements of the partial and the integral enthalpies of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys and the heat capacity of liquid Ni 26 Zr 74 . In a subsequent article, the authors will present similar data for the liquid ternary Al-Ni-Zr and for the liquid quaternary Al-Cu-Ni-Zr alloys

  1. The Ni-YSZ interface

    DEFF Research Database (Denmark)

    Jensen, Karin Vels

    The anode/electrolyte interface in solid oxide fuel cells (SOFC) is known to cause electrical losses. Geometrically simple Ni/yttria-stabilised zirconia (YSZ) interfaces were examined to gain information on the structural and chemical changes occurring during experiments at 1000°C in an atmosphere...... of 97% H2/3% H2O. Electrochemical impedance spectroscopy at open circuit voltage (OCV) and at anodic and cathodic polarisations (100 mV) was performed. A correlation of the electrical data with the structure development and the chemical composition was attempted. Nickel wires with different impurity...... between polarised and non-polarised samples. With pure nickel wires, however, the microstructures depended on the polarisation/non-polarisation conditions. At non-polarised conditions a hill and valley type structure was found. Anodic polarisation produced an up to 1 μm thick interface layer consisting...

  2. Study of the central collisions in the reactions Ni + Al and Ni + Ni at 28 A.MeV; Etude des collisions centrales dans les reactions Ni + Al et Ni + Ni a 28 A.MeV

    Energy Technology Data Exchange (ETDEWEB)

    Lebreton, L.

    1995-12-01

    The work is in characterisation of mechanisms in the energy range of onset of multifragmentation (excitation energy of composed nucleus around 4 - 5 AMeV). This work focused on an experiment performed at the SARA facility, in Grenoble, using the AMPHORA multi detection array. I have been particularly interested in central collisions in the Ni + Al and Ni + Ni systems. The possibility to detect complete events for Ni + Al, and quasi-complete events for the Ni + Ni case, is the reason of this choice. Furthermore Ni + Ni presents the interest of a symmetrical system, for which the excitation energy per nucleon is maximum. The study of these reactions has been focused on the quasi-complete events (events for which at least 80 % of the total charge has been detected). Heavy ions produced in peripheral collisions are very likely emitted along the beam line or stopped in the plastic detectors, energy thresholds are too high for the quasi-target products detection, consequently by requiring complete or quasi-complete measurement of the total charge, we are able to detect mostly central events. The knowledge of informations like charge, energy or detection angles allows to isolate the source(s) and to reconstruct the size and the excitation energy of the source(s). Comparisons with simulations like sequential emission (GEMINI code), very deep inelastic collision or instantaneous emission (Berliner code) allows to characterise the first stage of the collision (binary collisions or central collisions) and the type of deexcitation of the source(s). Some calculations was also performed with the statistical model code MODGAN. Indeed azimuthal correlations seem to be a good tool in getting more information about involved reaction mechanisms. Comparisons with MODGAN provide information about angular momentum of the source and time delay between emissions of the two particles (separation between sequential or instantaneous process). (author). 69 refs.

  3. Electrochemical preparation and characteristics of Ni-Co-LaNi{sub 5} composite coatings as electrode materials for hydrogen evolution

    Energy Technology Data Exchange (ETDEWEB)

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-02-15

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi{sub 5} composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi{sub 5} particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi{sub 5} coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol{sup -1} for the Ni-Co-LaNi{sub 5}, Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi{sub 5} proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi{sub 5} is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface.

  4. Electrochemical preparation and characteristics of Ni-Co-LaNi5 composite coatings as electrode materials for hydrogen evolution

    International Nuclear Information System (INIS)

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-01-01

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi 5 composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi 5 particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi 5 coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol -1 for the Ni-Co-LaNi 5 , Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi 5 proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi 5 is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface

  5. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong; Anjum, Dalaver H.; Zhou, Lu; Laveille, Paco; Basset, Jean-Marie

    2015-01-01

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles

  6. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong

    2015-06-25

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles, and the like.

  7. Growth of single-crystal W whiskers during humid H2/N2 reduction of Ni, Fe-Ni, and Co-Ni doped tungsten oxide

    International Nuclear Information System (INIS)

    Wang Shiliang; He Yuehui; Zou Jou; Wang Yong; Huang Han

    2009-01-01

    Numbers of W whiskers were obtained by reducing Ni, Ni-Fe, and Ni-Co doped tungsten oxide in a mixed atmosphere of humid H 2 and N 2 . The phases and morphologies of the reduction products were characterized by XRD and SEM. Intensive TEM and EDS analyses showed that the obtained whiskers were W single crystals which typical have alloyed particles (Ni-W, Fe-Ni, or Co-Ni-W) at the growth tips. The formed W whiskers were presumed to be induced by the alloyed particles. Our experimental results revealed that, during the reduction process of tungsten oxide, the pre-reduced Ni, Fe-Ni, or Co-Ni particles not only served as nucleation aids for the initial growth of W phase from W oxide but also played the roles of catalysts during the reductive decomposition of gaseous WO 2 (OH) 2 .

  8. Exchange bias variations of the seed and top NiFe layers in NiFe/FeMn/NiFe trilayer as a function of seed layer thickness

    International Nuclear Information System (INIS)

    Sankaranarayanan, V.K.; Yoon, S.M.; Kim, C.G.; Kim, C.O.

    2005-01-01

    Development of exchange bias at the seed and top NiFe layers in the NiFe (t nm)/FeMn(10 nm)/NiFe(5 nm) trilayer structure is investigated as a function of seed layer thickness, in the range of 2-20 nm. The seed NiFe layer shows maximum exchange bias at 4 nm seed layer thickness. The bias shows inverse thickness dependence with increasing thickness. The top NiFe layer on the other hand shows only half the bias of the seed layer which is retained even after the sharp fall in seed layer bias. The much smaller bias for the top NiFe layer is related to the difference in crystalline texture and spin orientations at the top FeMn/NiFe interface, in comparison to the bottom NiFe/FeMn interface which grows on a saturated NiFe layer with (1 1 1) orientation

  9. An Ultrastable and High-Performance Flexible Fiber-Shaped Ni-Zn Battery based on a Ni-NiO Heterostructured Nanosheet Cathode.

    Science.gov (United States)

    Zeng, Yinxiang; Meng, Yue; Lai, Zhengzhe; Zhang, Xiyue; Yu, Minghao; Fang, Pingping; Wu, Mingmei; Tong, Yexiang; Lu, Xihong

    2017-11-01

    Currently, the main bottleneck for the widespread application of Ni-Zn batteries is their poor cycling stability as a result of the irreversibility of the Ni-based cathode and dendrite formation of the Zn anode during the charging-discharging processes. Herein, a highly rechargeable, flexible, fiber-shaped Ni-Zn battery with impressive electrochemical performance is rationally demonstrated by employing Ni-NiO heterostructured nanosheets as the cathode. Benefiting from the improved conductivity and enhanced electroactivity of the Ni-NiO heterojunction nanosheet cathode, the as-fabricated fiber-shaped Ni-NiO//Zn battery displays high capacity and admirable rate capability. More importantly, this Ni-NiO//Zn battery shows unprecedented cyclic durability both in aqueous (96.6% capacity retention after 10 000 cycles) and polymer (almost no capacity attenuation after 10 000 cycles at 22.2 A g -1 ) electrolytes. Moreover, a peak energy density of 6.6 µWh cm -2 , together with a remarkable power density of 20.2 mW cm -2 , is achieved by the flexible quasi-solid-state fiber-shaped Ni-NiO//Zn battery, outperforming most reported fiber-shaped energy-storage devices. Such a novel concept of a fiber-shaped Ni-Zn battery with impressive stability will greatly enrich the flexible energy-storage technologies for future portable/wearable electronic applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Synthesis of a novel Au nanoparticles decorated Ni-MOF/Ni/NiO nanocomposite and electrocatalytic performance for the detection of glucose in human serum.

    Science.gov (United States)

    Chen, Jingyuan; Xu, Qin; Shu, Yun; Hu, Xiaoya

    2018-07-01

    A nonenzymatic glucose electrochemical sensor was constructed based on Au nanoparticles (AuNPs) decorated Ni metal-organic-framework (MOF)/Ni/NiO nanocomposite. Ni-MOF/Ni/NiO nanocomposite was synthesized by one-step calcination of Ni-MOF. Then AuNPs were loaded onto the Ni-based nanocomposites' surface through electrostatic adsorption. Through characterization by transmission electron microscopy (TEM), high resolution TEM (HRTEM) and energy disperse spectroscopy (EDS) mapping, it is found that the AuNPs were well distributed on the surface of Ni-based nanocomposite. Cyclic voltammetric (CV) study showed the electrocatalytic activity of Au-Ni nanocomposite was highly improved after loading AuNPs onto it. Amperometric study demonstrated that the Au-Ni nanocomposites modified glassy carbon electrode (GCE) exhibited a high sensitivity of 2133.5 mA M -1 cm -2 and a wide linear range (0.4-900 μM) toward the oxidation of glucose with a detection limit as low as 0.1 μM. Moreover, the reproducibility, selectivity and stability of the sensor all exhibited outstanding performance. We applied the as-fabricated high performance sensor to measure the glucose levels in human serum and obtained satisfactory results. It is believed that AuNPs decorated Ni MOF/Ni/NiO nanocomposite provides a new platform for developing highly performance electrochemical sensors in practical applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  11. Ni antagelser om Situationel Dialektisk Videnskabsteori

    DEFF Research Database (Denmark)

    Dakwar, Julia Rytter; Lorentzen, Anne-Christine Rosfeldt; Smedegaard, Flemming

    2017-01-01

    I artiklen præsenteres et præliminært bud på en Situationel Dialektisk Videnskabsteori (SDV) i form af ni antagelser. Situationel, fordi antagelserne ikke er statiske, men alle overvejelser og valg under de enkelte antagelser er afhængige af situationen. Dialektisk, fordi alle ni antagelser...... opererer med dialektiske modsætninger, og alle videnskabsteoretiske valg ses som valg på kontinua. De ni antagelser, som bliver præsenteret og diskuteret i artiklen, er: Antagelse 1: Teori og praksis fordrer hinanden Antagelse 2: Del og helhed hænger sammen Antagelse 3: Forbundne sagsforhold påvirker...

  12. New developments in Ni/Ti multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, I; Hoghoj, P [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1997-04-01

    It is now 20 years since super-mirrors were first used as a neutron optical element. Since then the field of multilayer neutron-optics has matured with multilayers finding their way to application in many neutron scattering instruments. However, there is still room for progress in terms of multilayer quality, performance and application. Along with work on multilayers for neutron polarisation Ni/Ti super-mirrors have been optimised. The state-of-the-art Ni/Ti super-mirror performance and the results obtained in two neutron-optics applications of Ni/Ti multilayers are presented. (author).

  13. Site occupancy of Fe in ternary Ni 75-x

    Indian Academy of Sciences (India)

    The results of a detailed structural and magnetic study clearly indicate that regardless of the thermal history of the samples, Fe has a strong preference for the Ni sites in Ni-poor (non-stoichiometric) Ni75Al25 alloys. Fe substitution has a profound effect on the nature of magnetism in Ni75Al25.

  14. Reduction of a Ni/Spinel Catalyst for Methane Reforming

    DEFF Research Database (Denmark)

    Kehres, Jan; Andreasen, Jens Wenzel; Fløystad, Jostein Bø

    2015-01-01

    microscopy (HRTEM) was performed on the fresh catalyst sample. The Ni particles in the fresh catalyst sample were observed to exhibit a Ni/NiO core/shell structure. A decrease of the Ni lattice parameter is observed during the reduction in a temperature interval from 413 – 453 K, which can be related...

  15. Influence of Ni Solute segregation on the intrinsic growth stresses in Cu(Ni) thin films

    International Nuclear Information System (INIS)

    Kaub, T.M.; Felfer, P.; Cairney, J.M.; Thompson, G.B.

    2016-01-01

    Using intrinsic solute segregation in alloys, the compressive stress in a series of Cu(Ni) thin films has been studied. The highest compressive stress was noted in the 5 at.% Ni alloy, with increasing Ni concentration resulting in a subsequent reduction of stress. Atom probe tomography quantified Ni's Gibbsian interfacial excess in the grain boundaries and confirmed that once grain boundary saturation is achieved, the compressive stress was reduced. This letter provides experimental support in elucidating how interfacial segregation of excess adatoms contributes to the post-coalescence compressive stress generation mechanism in thin films. - Graphical abstract: Cu(Ni) film stress relationship with Ni additions. Atom probe characterization confirms solute enrichment in the boundaries, which was linked to stress response.

  16. NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

    International Nuclear Information System (INIS)

    Zhou, M. H.; Wang, Y. G.; Bi, K.; Fan, H. P.; Zhao, Z. S.

    2015-01-01

    The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α E,31 = 2.8 V ⋅ cm −1 ⋅ Oe −1 is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors

  17. NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, M. H.; Wang, Y. G.; Bi, K., E-mail: bike@bupt.edu.cn [State Key Laboratory of Information Photonics and Optical Communications and School of Science, Beijing University of Posts and Telecommunications, Beijing 100876 (China); Fan, H. P. [School of Mechanical and Electrical Engineering, Qingdao Technological University Qindao College, Qingdao 266106 (China); Zhao, Z. S. [Shandong Engineering Consulting Institute, Jinan 250013 (China)

    2015-04-15

    The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α{sub E,31} = 2.8 V ⋅ cm{sup −1} ⋅ Oe{sup −1} is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors.

  18. Fe-solubility of Ni7S6 and Ni9S8: Thermodynamic analysis

    International Nuclear Information System (INIS)

    Waldner, P.

    2011-01-01

    Experimental data on phase equilibria have been used for thermodynamic analysis of the iron solubility of the nickel sulfides Ni 7 S 6 and Ni 9 S 8 . For both compounds, a two-sublattice approach within the framework of the compound energy formalism has been applied to perform Gibbs free energy modelling at 0.1 MPa total pressure consistently embedded in recent thermodynamic assessment studies of other iron-nickel-sulfides. The predicted maxima of iron solubility around 3 at% of Ni 7 S 6 and 5.5 at% of Ni 9 S 8 are confirmed by experimental data. The calculations of complex ternary phase relations with Fe-bearing Ni 7 S 6 and Ni 9 S 8 gain further improvement. The first internally consistent description of all thermodynamically stable phases known in the literature for the iron-nickel-sulfur system is completed.

  19. Phase stability and magnetism in NiPt and NiPd alloys

    International Nuclear Information System (INIS)

    Paudyal, Durga; Mookerjee, Abhijit

    2004-01-01

    We show that the differences in stability of 3d-5d NiPt and 3d-4d NiPd alloys arise mainly due to relativistic corrections. The magnetic properties of disordered NiPd and NiPt alloys also differ due to these corrections, which lead to increase in the separation between the s-d bands of 5d elements in these alloys. For the magnetic case we also analyse the results in terms of splitting of majority and minority spin d band centres of the 3d elements. We further examine the effect of relativistic corrections to the pair energies and order-disorder transition temperatures in these alloys. The magnetic moments and Curie temperatures have also been studied along with the short range ordering/segregation effects in NiPt/NiPd alloys

  20. Precipitation of Ni4Ti3-variants in a polycrystalline Ni-rich NiTi shape memory alloy

    Czech Academy of Sciences Publication Activity Database

    Bojda, Ondřej; Eggeler, G.; Dlouhý, Antonín

    2005-01-01

    Roč. 53, č. 1 (2005), s. 99-104 ISSN 1359-6462 R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitation * Transmission electron microscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.228, year: 2005

  1. Ni-Ni ion pair excitation transfer in D sub(3h) symmetry

    International Nuclear Information System (INIS)

    Terrile, M.C.

    1990-01-01

    The mechanisms contributing to excitation transfer are examined for Ni-Ni ion pairs in order to explain the delocalized character of electronic excitations observed in CsNiF sub(3). Using both first-and second-order perturbation theory and from symmetry arguments, the kind of interactions giving matrix elements between states connecting different sites for the position of the excitation are discussed. (author)

  2. Electronic structure of graphene on Ni surfaces with different orientation

    International Nuclear Information System (INIS)

    Pudikov, D.A.; Zhizhin, E.V.; Rybkin, A.G.; Rybkina, A.A.; Zhukov, Y.M.; Vilkov, O. Yu.; Shikin, A.M.

    2016-01-01

    An experimental study of the graphene, synthesized by propylene cracking on Ni surfaces with different orientation: (100) and (111), using angle-resolved photoemission, has been performed. It has been shown that graphene on Ni(111) had a perfect lateral structure due to consistency of their lattices, whereas graphene/Ni(100) consisted of a lot of domains. For both systems electronic structure was quite similar and demonstrated a strong bonding of graphene to the underlying Ni surface. After Au intercalation the electronic structure of graphene in both systems was shifted to the Fermi level and became linear in the vicinity of the K point of the Brillouin zone. - Highlights: • Graphene on Ni(111) is well-ordered, whereas on Ni(100) – multi-domain. • Graphene on Ni(111) and Ni(100) is strongly bonded with substrate. • Intercalation of Au atoms restores the linearity in dispersion and makes graphene quasi-free on both Ni(100) and Ni(111).

  3. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    Kabir, L.; Mandal, A.R. [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India); Mandal, S.K., E-mail: sk_mandal@hotmail.co [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India)

    2010-04-15

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni{sup 2+} clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni{sup 2+} clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  4. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Science.gov (United States)

    Kabir, L.; Mandal, A. R.; Mandal, S. K.

    2010-04-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  5. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    International Nuclear Information System (INIS)

    Kabir, L.; Mandal, A.R.; Mandal, S.K.

    2010-01-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  6. Modeling and simulation of NiO dissolution and Ni deposition in molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Suk Woo; Choi, Hyung-Joon; Lim, Tae Hoon [Korea Institute of Science & Technology, Seoul (Korea, Republic of)] [and others

    1996-12-31

    Dissolution of NiO cathode into the electrolyte matrix is an important phenomena limiting the lifetime of molten carbonate fuel cell (MCFC). The dissolved nickel diffuses into the matrix and is reduced by dissolved hydrogen leading to the formation of metallic nickel films in the pores of the matrix. The growth of Ni films in the electrolyte matrix during the continuous cell operation results eventually in shorting between cathode and anode. Various mathematical and empirical models have been developed to describe the NiO dissolution and Ni deposition processes, and these models have some success in estimating the lifetime of MCFC by correlating the amount of Ni deposited in the matrix with shorting time. Since the exact mechanism of Ni deposition was not well understood, deposition reaction was assumed to be very fast in most of the models and the Ni deposition region was limited around a point in the matrix. In fact, formation of Ni films takes place in a rather broad region in the matrix, the location and thickness of the film depending on operating conditions as well as matrix properties. In this study, we assumed simple reaction kinetics for Ni deposition and developed a mathematical model to get the distribution of nickel in the matrix.

  7. Layering and temperature-dependent magnetization and anisotropy of naturally produced Ni/NiO multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Pappas, S. D.; Trachylis, D.; Velgakis, M. J. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Kapaklis, V.; Joensson, P. E.; Papaioannou, E. Th. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process Engineering Research Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Poulopoulos, P. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Materials Science Department, University of Patras, 26504 Patras (Greece); Fumagalli, P. [Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Politis, C. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Materials Science and Engineering, University of Texas at Arlington, Arlington, Texas 76019 (United States)

    2012-09-01

    Ni/NiO multilayers were grown by magnetron sputtering at room temperature, with the aid of the natural oxidation procedure. That is, at the end of the deposition of each single Ni layer, air is let to flow into the vacuum chamber through a leak valve. Then, a very thin NiO layer ({approx}1.2 nm) is formed. Simulated x-ray reflectivity patterns reveal that layering is excellent for individual Ni-layer thickness larger than 2.5 nm, which is attributed to the intercalation of amorphous NiO between the polycrystalline Ni layers. The magnetization of the films, measured at temperatures 5-300 K, has almost bulk-like value, whereas the films exhibit a trend to perpendicular magnetic anisotropy (PMA) with an unusual significant positive interface anisotropy contribution, which presents a weak temperature dependence. The power-law behavior of the multilayers indicates a non-negligible contribution of higher order anisotropies in the uniaxial anisotropy. Bloch-law fittings for the temperature dependence of the magnetization in the spin-wave regime show that the magnetization in the multilayers decreases faster as a function of temperature than the one of bulk Ni. Finally, when the individual Ni-layer thickness decreases below 2 nm, the multilayer stacking vanishes, resulting in a dramatic decrease of the interface magnetic anisotropy and consequently in a decrease of the perpendicular magnetic anisotropy.

  8. XRD studies on solid state amorphisation in electroless Ni/P and Ni/B deposits

    International Nuclear Information System (INIS)

    Sampath Kumar, P.; Kesavan Nair, P.

    1996-01-01

    The decomposition of electroless Ni-P and Ni-B deposits on annealing at various temperature is studied using x-ray diffraction techniques employing profile deconvolution and line profile analysis. It appears that solid state amorphisation takes place in the Ni-B deposits in a narrow temperature range just prior to the onset of crystallization of amorphous phase. In the case of Ni-P deposits no evidence for solid state amorphisation could be obtained. Thermodynamic and kinetic considerations also support such a conclusion

  9. Ni adsorption and Ni-Al LDH precipitation in a sandy aquifer: An experimental and mechanistic modeling study

    NARCIS (Netherlands)

    Regelink, I.C.; Temminghoff, E.J.M.

    2011-01-01

    Mining activities and industries have created nickel (Ni) contaminations in many parts of the world. The objective of this study is to increase our understanding of Ni adsorption and Nickel-Aluminium Layered Double Hydroxide (Ni-Al LDH) precipitation to reduce Ni mobility in a sandy soil aquifer. At

  10. Core/shell AgNi/PtAgNi nanoparticles as methanol-tolerant oxygen reduction electrocatalysts

    International Nuclear Information System (INIS)

    Wu, Dengfeng; Cheng, Daojian

    2015-01-01

    A core/shell AgNi/PtAgNi nanoparticle (NP) was synthesized via a new seed-mediated growth method in organic solvent medium. The as-synthesized AgNi/PtAgNiNP exhibits an AgNi core coated with PtAgNi shell, which was confirmed by transmission electron microscopy (TEM), ultraviolet–visible absorption spectroscopy and X-ray Photoelectron Spectroscopy (XPS). The AgNi/PtAgNiNPs/C catalyst possesses higher oxygen reduction reaction (ORR) activity and better durability compared with the commercial Pt/C catalyst. It is found that the ORR polarization curve of the AgNi/PtAgNiNPs/C catalyst shows an onset potential of 0.91 V vs. RHE, which is superior to the commercial Pt/C (0.88 V vs. RHE). In addition, the AgNi/PtAgNiNPs/C catalyst shows much better durability than the commercial Pt/C catalyst. More interestingly, the AgNi/PtAgNiNPs/C catalyst displays much higher methanol tolerance than the commercial Pt/C catalyst in 0.1 M KOH solution in the presence of 0.5 M methanol. Our results show that core/shell AgNi/PtAgNiNPs possess selective activity for ORR even in the presence of methanol, showing potential application as methanol-tolerant cathode catalysts in direct methanol fuel cells.

  11. Grain boundaries in Ni3Al. 2

    International Nuclear Information System (INIS)

    Kung, H.; Sass, S.L.

    1992-01-01

    This paper discusses the dislocation structure of small angle tilt and twist boundaries in ordered Ni 3 Al, with and without boron, investigated using transmission electron microscopy. Dislocation with Burgers vectors that correspond to anti-phase boundary (APB)-coupled superpartials were found in small angle twist boundaries in both boron-free and boron-doped Ni 3 Al, and a small angle tilt boundary in boron-doped Ni 3 Al. The boundary structures are in agreement with theoretical models proposed by Marcinkowski and co-workers. The APB energy determined from the dissociation of the grain boundary dislocations was lower than values reported for isolated APBs in Ni 3 Al. For small angle twist boundaries the presence of boron reduced the APB energy at the interface until it approached zero. This is consistent with the structure of these boundaries containing small regions of increased compositional disorder in the first atomic plane next to the interface

  12. Ni-ZrB2 electrocomposites

    International Nuclear Information System (INIS)

    Pushpavanam, M.; Natarajan, S.R.

    1992-01-01

    New generation materials require high temperature oxidation resistance besides many other tribological properties. Ni-ZrB 2 composites and their properties are dealt with in this paper. (author). 7 refs., 3 figs., 4 tabs

  13. Not in Traffic Surveillance (NiTS)

    Data.gov (United States)

    Department of Transportation — The Not-in-Traffic Surveillance (NiTS) system is a virtual data collection system designed to provide counts and details regarding fatalities and injuries that occur...

  14. Niños y Violencia

    OpenAIRE

    International Child Development Centre

    1997-01-01

    Este Innocenti Digest explora la violencia de los niños y hacia los niños, usando el marco de la Convención de los Derechos del Niño de las Naciones Unidas. Se centra en la violencia interpersonal, tanto intrafamiliar como extrafamiliar. Se incluye el abuso sexual y la explotación ya que a pesar de no implicar obligatoriamente violencia o coerción, la mayor parte de la evidencia demuestra su efectos dañinos tanto físicos como psicológicos. También se discute la implicación de los niños en los...

  15. Collision strengths for transitions in Ni XIX

    Indian Academy of Sciences (India)

    4l configurations of Ni XIX, for which flexible atomic code. (FAC) has been ... atomic data (namely energy levels, radiative rates, collision strengths, excitation rates, etc.) ... Zhang and Sampson, who adopted the Coulomb–Born-exchange.

  16. Root morphology of Ni-treated plants

    International Nuclear Information System (INIS)

    Leskova, A.; Fargasova, A.; Giehl, R. F. H.; Wiren, N. von

    2015-01-01

    Plant roots are very important organs in terms of nutrient and water acquisition but they also serve as anchorages for the aboveground parts of the plants. The roots display extraordinary plasticity towards stress conditions as a result of integration of environmental cues into the developmental processes of the roots. Our aim was to investigate the root morphology of Arabidopsis thaliana plants exposed to a particular stress condition, excess Ni supply. We aimed to find out which cellular processes - cell division, elongation and differentiation are affected by Ni, thereby explaining the seen root phenotype. Our results reveal that a distinct sensitivity exists between roots of different order and interference with various cellular processes is responsible for the effects of Ni on roots. We also show that Ni-treated roots have several auxin-related phenotypes. (authors)

  17. Density and Structure Analysis of Molten Ni-W Alloys

    Institute of Scientific and Technical Information of China (English)

    Feng XIAO; Liang FANG

    2004-01-01

    Density of molten Ni and Ni-W alloys was measured in the temperature range of 1773~1873 K with a sessile drop method.The density of molten Ni and Ni-W alloys trends to decrease with increasing temperature. The density and molar volume of the alloys trend to increase with increasing W concentration in the alloys. The calculation result shows an ideal mixing of Ni-W alloys.

  18. Fe-Cr-Ni system alloys

    International Nuclear Information System (INIS)

    Levin, F.L.

    1986-01-01

    Phase diagram of Fe-Cr-Ni system, which is the basic one for production of corrosion resistant alloys, is considered. Data on corrosion resistance of such alloys are correlated depending on a number of factors: quality and composition of modifying elements, corrosion medium, temperature, alloy structure, mechanical and thermal treatment. Grades of Fe-Ni-Cr alloys are presented, and fields of their application are pointed out

  19. Synthesis of Ni3Ta, Ni2Ta and NiTa by high-energy ball milling and subsequent heat treatment

    International Nuclear Information System (INIS)

    Benites, H.S.N.; Silva, B.P da; Ramos, A.S.; Silva, A.A.A.P.; Coelho, G.C.; Lima, B.B. de

    2014-01-01

    The tantalum has relevance for the development of multicomponent Ni-based superalloys which are hardened by solid solution and precipitation mechanisms. Master alloys are normally used in the production step in order to produce refractory metals and alloys. The present work reports on the synthesis of Ni_3Ta, Ni_2Ta and NiTa by high-energy ball milling and subsequent heat treatment. The elemental Ni-25Ta, Ni-33Ta and Ni-50Ta (at.-%) powder mixtures were ball milled under Ar atmosphere using stainless steel balls and vials, 300 rpm and a ball-to-powder weight ratio of 10:1. Following, the as-milled samples were uniaxially compacted and heat-treated at 1100 deg C for 4h under Ar atmosphere. The characterization of as-milled and heat-treated samples was conducted by means of X-ray diffraction, scanning electron microscopy, and energy dispersive spectrometry. A large amount of Ni_3Ta, Ni_2Ta and NiTa was formed in the mechanically alloyed heat-treated Ni-25Ta, Ni-33Ta and Ni-50Ta alloys. (author)

  20. Structural Investigation of Fe-Ni-S and Fe-Ni-Si Melts by High-temperature Fluorescence XAFS Measurements

    International Nuclear Information System (INIS)

    Manghnani, Murli H.; Balogh, John; Hong Xinguo; Newville, Matthew; Amulele, G.

    2007-01-01

    Iron-nickel (Fe-Ni) alloy is regarded as the most abundant constituent of Earth's core, with an amount of 5.5 wt% Ni in the core based on geochemical and cosmochemical models. The structural role of nickel in liquid Fe-Ni alloys with light elements such as S or Si is poorly understood, largely because of the experimental difficulties of high-temperature melts. Recently, we have succeeded in acquiring Ni K-edge fluorescence x-ray absorption fine structure (XAFS) spectra of Fe-Ni-S and Fe-Ni-Si melts and alloys. Different structural environment of Ni atoms in Fe-Ni-S and Fe-Ni-Si melts is observed, supporting the effect of light elements in Fe-Ni melts

  1. Generalized report on the research cooperation promoting project. Research cooperation related to the mine waste water treatment technology utilizing biotechnology; Kenkyu kyoryoku suishin jigyo sokatsu hokokusho. Bio riyo ni yoru kohaisui shori gijutsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This paper is a generalized report in relation with the mine waste water treatment technology utilizing biotechnology, from among the promotion projects for research cooperation with China. Ferric iron (Fe{sup 3+}), which precipitates at low pH, is produced by utilizing bacteria which derives energy from oxidizing ferrous iron (Fe{sup 2+}) in the waste water, and the iron is precipitated and removed by using low-cost calcium carbonate as a neutralizing agent. Joint researches and developments have been carried out on selection of optimal kinds of bacteria, cultivation of bacteria oxidizing iron at high efficiency, optimal removal system of heavy metals in mine waste water, and recovery of useful resources. Japanese engineers were sent to sites in China, Chinese researchers were received in Japan, and pilot plants were operated and studied. For the purpose of proliferating and enlightening the result of the project, a seminar was held in Beijing in February 1998. In order for the achievements derived up to fiscal 1998 to be used in diverse fields, fiscal 1999 will carry out follow-ups, including assistance, for the voluntary researches performed by China. The follow-ups will also include confirmation on the state of testing the iron oxidizing bacteria technology, technical guidance, and analyses and discussions on the data. (NEDO)

  2. Report on 'manufacturing technology supported by advanced and integrated information system through international cooperation'. Domestic surveys; 'Kan'i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Kokunai chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    The committee of manufacturing technology supported by advanced and integrated information system through international cooperation (MATIC) has been established as the organization to promote necessary surveys, deliberate the research and development guidelines and themes, and thereby support the joint R and D projects with Asian countries to improve information systems for their manufacturing industries by MATIC. The R and D skeletons are set in FY 1994 for the works in and after FY 1995. The relationships between affiliates of Japanese enterprises and local enterprises, actual conditions of the manufacturing industries and so on are surveyed, in order to extract problems related to the information systems for the promising manufacturing industries in the Asian countries. Each industry has its own characteristics with respect to, e.g., numbers f parts and process steps, product life cycle, extent of automation, skill of workers, and spread of the related industries. Therefore, 3 industrial areas are picked up as those considered to be adequate for the case studies, and surveyed for the system functions, performance, elementary techniques and so on which are required to establish the information systems for their production systems. (NEDO)

  3. FY 1994 report on the cooperative research on the biological use mine wastewater treatment technology; 1994 nendo bio riyo ni yoru kohaisui shori gijutsu ni kansuru kenkyu kyoryoku hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    In this project, a pilot plant for mine wastewater treatment facilities using Thiobacillus ferrooxidans was installed at the Wushan mine in China to study the operation using the bacteria habitable in this mine. The project aims at establishing the mine wastewater treatment technology using the method of Thiobacillus ferrooxidans in China. The field survey and study in Japan were carried out. In the field survey, the technical guidance was given for incubation method, neutralization experiment method and analysis method of Thiobacillus ferrooxidans. In the study in Japan, one kind of bacteria to be used was selected in the 'selection test for the optimum kind of bacteria,' and a study was made which was titled 'Study of mine wastewater treatment using the method of Thiobacillus ferrooxidans which is suitable for the mine site.' In 'Study of the optimum removal of heavy metal in mine wastewater,' a table test of sulfide precipitation method was conducted on copper removal/recovery to make formation conditions of copper sulfide clear. The conditions obtained were reflected in 'Study of mine wastewater treatment by the method of Thiobacillus ferrooxidans which is suitable for the mine site,' and various conditions for bacteria oxidation process were studied. The paper surveyed characteristics of heavy metal and temperature of Chinese strains. Further, the basic data were acquired which contribute to the production of inorganic flocculants. (NEDO)

  4. FY 2000 report on the survey on global warming prevention measures in main E.U. countries; 2000 nendo EU shuyokoku ni okeru ondanka boshi taisaku no gaiyo ni tsuite hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This report dealt with the background of energy policies in E.U. countries and energy plans. At COP3, E.U. countries internationally gave a pledge that they will reduce the emission of greenhouse effect gas 8% from that as of 1990 during 2008-2012, which is stricter than those given by Japan and the U.S. Actually, the European Commission made public 'Toward the European Climate Change Programme' and 'Green Paper on Emissions Trading in the E.U.' These are correspondent to E.U.' global warming preventive strategy which is called the twin track approach by the European Commission. The former is a frame for coordinating individual reduction measures taken under the responsibility of member countries as the whole E.U. As to the latter, for the specified sectors from energy supply sectors to large energy consumption industries, it was planned to be started in 2005. And, the basic policy on the trade and concrete subjects/problems on the trading system were arranged. (NEDO)

  5. Fiscal 1998 research report. Research cooperation on car energy and environmental technology based on ITS technology in China; 1998 nendo seika hokokusho. Chugoku ni okeru ITS gijutsu wo mochiita jidosha energy kankyo gijutsu ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This research aims at preparation of the car energy/environmental vision based on ITS (intelligent transport system) technology in China, enhancement of the transport planning ability of Qinghua University, and promotion of effective energy use in China. The following activities were carried out concretely: Survey on the actual traffic situation by Qinghua University, analysis of environment deterioration factors based on the survey result, estimation of a traffic environment improvement effect, study on traffic flow simulation technique based on traffic engineering, and study on traffic planning technique. As the diffusion strategy of ITS along Chinese circumstances, standardization and improvement of a multi- modal traffic system, navigation and its application system, and ETC (electronic toll collection) system are promising. Expectation for Japan and Japanese roles are as follows: Improvement of signal control, provision of information systems such as navigation, discussion on ITS technology such as ETC with Chinese specialists, and feasibility study on introduction of ITS technology for every Chinese district. (NEDO)

  6. FY 2000 report on the survey on global warming prevention measures in main E.U. countries; 2000 nendo EU shuyokoku ni okeru ondanka boshi taisaku no gaiyo ni tsuite hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This report dealt with the background of energy policies in E.U. countries and energy plans. At COP3, E.U. countries internationally gave a pledge that they will reduce the emission of greenhouse effect gas 8% from that as of 1990 during 2008-2012, which is stricter than those given by Japan and the U.S. Actually, the European Commission made public 'Toward the European Climate Change Programme' and 'Green Paper on Emissions Trading in the E.U.' These are correspondent to E.U.' global warming preventive strategy which is called the twin track approach by the European Commission. The former is a frame for coordinating individual reduction measures taken under the responsibility of member countries as the whole E.U. As to the latter, for the specified sectors from energy supply sectors to large energy consumption industries, it was planned to be started in 2005. And, the basic policy on the trade and concrete subjects/problems on the trading system were arranged. (NEDO)

  7. Report on the research cooperation promoting project in fiscal 1998. Research cooperation related to the mine waste water treatment technology utilizing biomass; 1998 nendo kenkyu kyoryoku suishin jigyo hokokusho. Bio riyo ni yoru kohaisui shori gijutsu ni kansuru kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This paper describes the achievement in relation with the mine waste water treatment technology utilizing biomass, from among the promotion projects for research cooperation with China. Waste water is converted into ferric iron (Fe{sup 3+}), which precipitates at low pH, by utilizing iron oxidizing bacteria which use ferrous iron (Fe{sup 2+}) in the waste water as the energy source, and is precipitated and removed by using low-cost calcium carbonate as a neutralizing agent. Fiscal 1998 has performed eight site surveys with 47 persons in total. The main survey items are the study and guidance of pilot plant operation and the survey on measures to prevent occurrence of contamination by heavy metals in Wushan Mine. Additional site surveys were made at Dexing Mine and Yinshan Lead/Zinc Mine. Continued from fiscal 1997, consumables required for the pilot plant were purchased, and items of the bench-scale testing equipment used by Japan for domestic researches (an oxidation and neutralization testing equipment and a copper recovering and testing equipment) were transported to China. The operation research data of the pilot plant were put in order and analyzed. This paper summarizes the concept design of the shaft waste water treatment facilities for the north mine in Wushan Mine, and the surveys on measures for heavy metal contamination sources. (NEDO)

  8. Research and survey report of FY 1997 on the CO2 balance for high-temperature CO2 fixation and utilization technology; 1997 nendo chosa hokokusho (nisanka tanso koon bunri gijutsu ni okeru CO2 balance ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The purpose of this research is to clarify the application condition and effectiveness of high-temperature CO2 fixation and utilization technology. To evaluate the present process, it was compared with others, such as separation using a polymer membrane, physico-chemical absorption process, adsorption process, hydrogen contact reduction process, and biological fixation. The development trends of absorption, membrane, adsorption, and cryogenic separation were investigated. The questionnaire was carried out about the separation technologies which are in the stage of performance test using actual gas, to arrange and compare the data and information. The current trends of chemical and biological CO2 fixation and utilization technology were also investigated for arranging the subjects. High-temperature CO2 disposal by the carbonation in concrete waste has been studied, to clarify its application conditions and effectiveness. In order to compare the separation technologies, treatment processes of CO2 in the exhaust gas from boilers of LNG power generation and coal fired power generation were simulated. These processes were simulated by ASPEN PLUS for the modeling. Trends of application of ASPEN PLUS and collection of information were surveyed by participating in the ASPEN WORLD. 103 refs., 51 figs., 55 tabs.

  9. Achievement report for fiscal 1984 on Sunshine Program. Research on liquefaction characteristics different between coal types and on technical physical properties; 1984 nendo tanshu ni yoru ekika tokusei to kogakuteki busseichi ni kansuru kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1985-03-01

    Liquefaction characteristics of coal specimens, collected from many locations across the world, are determined so as to make clear the correlations between coal type and liquefaction reactivity. Conducted for this purpose are the analysis of chemical structures of the specimens, liquefaction tests in an autoclave using various catalysts and medium oils, liquefaction tests in a 0.1t/d bench plant, investigation of the constituents of the generated oil and their separation, and the secondary stabilization treatment for the commercialization of the product. The reaction tower is kept under constant conditions, the state of the liquid mixture in the reaction tower is evaluated by tracking the flow of coal out of the reaction tower after switchover from anthracene oil to coal paste, the gas flow in the reaction tower is estimated by tracking time-wise changes in the concentration level of inert gas at the reaction tower outlet port, the inert gas having been injected in pulses into the reaction system operating under the reaction conditions. For the implementation of the above-mentioned steps, a system is designed and constructed for directly collecting samples from the vapor phase section in the reaction tower operating under given reaction conditions (temperature: 400-450 degrees C, pressure 150-300kg/cm{sup 2}), and experiments are conducted to collect gas/liquid equilibrium data in the reaction tower under the given reaction conditions. (NEDO)

  10. FY 1974 Report on results of Sunshine Project. Study on physicochemical properties of rocks in geothermal districts; 1974 nendo chinetsu chitai ni okeru ganseki no butsuri kagakuteki tokusei ni kansuru kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-03-01

    The geothermal district is characterized by distributions of high temperature and hot water. The beds and rocks in these areas are characteristically altered by these conditions. It is an object of this research and development project to clarify how properties of the beds and rocks in these areas, exposed to the characteristic physicochemical conditions, differ from properties of those in other areas. There are may rock properties. In this project, the studied properties are centered by those used for physical exploitation (or geophysical methods), e.g., electrical properties (electrical exploitation), magnetic properties (magnetic exploitation), and thermal conductivity (measurement of heat flow rates and geothermal gradients). The FY 1974 project covers pigeonholing the basic data, establishment of the experimental procedures, and measurement of water quality characteristics and temperature distributions (geothermal temperature gradients) at the test site. This paper reports the results categorized by (I) measurement of rock resistivity and effects on moisture content on this property, (II) properties of water in the geothermal district (Yahata-daira District), and (III) relationships between rock thermal conductivity and other properties. (NEDO)

  11. FY 1999 report on the results of the R and D on high performance industrial furnace, etc.; 1999 nendo koseino kogyoro no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    In the development of high performance industrial furnace, initial targets were achieved such as energy saving of 30%, downsizing of 20%, and a remarkable NOx reduction. To verify the achievement, the test field project is being worked on by NEDO. In FY 1998, 23 heating furnaces, 29 heat treat furnaces and 6 melting furnaces were under the project at energy saving effect of 52,000 kl converted to crude oil. In FY 1999, 18 heating furnaces, 26 heat treat furnaces and 7 melting furnaces are now under the project at energy saving effect of 57,000 kl. The project was awarded 'The 9th Nikkei Global Environmental Technology Prize.' The themes for the R and D are as follows: high efficiency exhaust heat utilization system, self-completion type high temperature/high radiation heating technology, technology to make heat transfer in steel heating suitable under non-stationary state, high efficiency heat transfer technology, technology to optimize the shape of heating furnace, high performance atmosphere heat treat furnace, high efficiency heat transfer technology by high temperature jet flame heating, technology of high efficiency aluminum melting furnace, technology to improve soaking degree in steel heating, high performance tubular heating furnace in oil refining, optimum combustion control technology of regenerative burner furnace, and laser measuring method inside industrial furnace. (NEDO)

  12. Report on the FY 1999 investigational survey on the activation of oxygen electrode by ion implantation; 1999 nendo ion chunyuho ni yoru sanso denkyoku no kasseika ni kansuru kenkyu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The oxygen electrode is important as the base electrode for water electrolysis and fuel cell, but to move it, overvoltage (activated energy) in addition to equilibrium voltage is necessary, which leads to the lowering of energy efficiency. By forming the active spot by ion implantation, the lowering of overvoltage was studied. The implantation of Ru{sup +} ion in Ruthenium dioxide thin film electrode reduced the oxygen generating overvoltage by 15-20mV. Even in the oxygen reduction, activity was also increased. The chemical composition of thin film does not change by ion implantation. The increase in activity is based on a physical change which is called the surface defect formation. The layer of ion implantation is composed of microcrystals, which is thought to contribute to the formation of any active spot. Ions were implanted in Pt electrode as a practical use material, and even in the oxygen reduction of Pt, a possibility of heightening activity by ion implantation was admitted even in the oxygen reduction of Pt. The generation of high activity oxygen by ion plantation and development of oxygen reduction electrode were established as one method as a rule. (NEDO)

  13. Fiscal 1999 research report. Survey on development trends of natural gas conversion technologies into liquefied fuel in Russia; 1999 nendo Roshia ni okeru tennen gas no ekitai nenryoka gijutsu no kaihtsu doko nado ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Russia having world-largest natural gas resources is promoting the forefront basic research on liquefaction technology of natural gas, in particular, Fischer-Tropsch (FT) synthetic process positively. For 3 years from fiscal 1998, this project surveys the trend of R and D on catalytic technology for liquefaction of natural gas in Russia, and fabricates the prototype FT catalyst effective for liquefaction of natural gas at a Russian research institute to evaluate its practical applicability experimentally. In fiscal 1999, based on the research result in fiscal 1998, the project carried out continuous survey on the research activity of research institutes in Russia, the research trend of liquefaction technology and the concrete results of contract researches on catalyst, and summarized the evaluation result of research results. In addition, continuous world-wide document survey on FT synthetic process was made to confirm R and D trends based on the trend of liquefaction research projects in the world, and to collect basic information on catalytic reactors for FT synthetic process by document survey. (NEDO)

  14. Fiscal 1993 investigational study of a model of international cooperation for an environmentally harmony type green technosystem; 1993 nendo Oshu ni okeru haikibutsu shori oyobi recycle no doko ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    For the natural environment preservation, effective utilization of resources, and maintenance of the ecosystem, an international cooperation model was proposed for the environmental harmony type green technosystem. A comprehensive evaluating analysis of a green forest resource, etc. as the global resource, and an intensive extraction of subjects and needs was made. The analysis was conducted of technical possibility and abstract business development effects toward the industrialization with high values added which is in harmony with the environment. As a case study, the Papua New Guinea area, Malaysia was selected and re-evaluated. For this typical tropical forest area, a new technical system was studied based on the natural environment, industry/economy, social/cultural assessment, etc., and a model for industrializing new international cooperation was proposed. For the model making for industrialization, various steps to be taken and conditions to be prepared were studied and arranged for the realization. Upon going ahead with the international technical cooperation, Japan, a large lumber consuming country, needs to always consider the fostering and effective use of lumber resource in particular. 27 refs., 28 figs., 30 tabs.

  15. Achievement report for fiscal 1976 on Sunshine Program. Research on safety technology in hydrogen energy system; 1976 nendo suiso energy system ni okeru hoan gijutsu ni kansuru kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-03-01

    Material is collected relative to the safety of hydrogen inside Japan and outside and, on the basis of the collected data, generalization is made of a draft of general standards for the safety of hydrogen and a draft of technological standards for the safety of gaseous hydrogen and liquid hydrogen. In the draft of general standards for the safety of hydrogen, the physical properties of hydrogen and basic matters about the handling of hydrogen are put together, and the possible ignition sources are classified and measures against ignition are shown, and general matters about fire prevention and fighting are explained. Hydrogen attack and embrittlement are taken into consideration, and the caution to exercise when selecting, treating, and processing materials for use with hydrogen is described. Attention is paid to the handling of hydrogen, referring to the dangers of aerohypoxia, frostbite and cold death, and burns. Furthermore, a proposition is newly suggested this fiscal year, which emphasizes the need of disaster preventing facilities such as explosion-proofed electrical equipment and explosion-proofed wiring and explains where to install them and how to maintain them. Also taken up in the research are the need of measures, such as the delivery of safety education and training to workers, to cope with dangers peculiar to hydrogen, and the methods of implementing such programs. (NEDO)

  16. FY 1974 report on the results of the Sunshine Project. Investigational research on safety technology in the hydrogen energy system; 1974 nendo suiso erergy system ni okeru hoan gijutsu ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-05-01

    In this study, samples were surveyed and collected of the present regulations and standard, disaster accident, basic literature, etc. concerning the safety of hydrogen in Japan and abroad. Further, according to the necessity, these collected data were translated. The data to be examined/collected are those in and after 1950, and the data except the above-mentioned are collected if those are thought to be important. As to the condition of hydrogen to be examined/surveyed, those under all conditions from gas (normal pressure) to liquid and solidified hydrogen. The data for survey were classified into law/standard, corporate standard, samples of disaster accident, and general literature. The general literature was classified into general physical property, material relation, fire/explosion, and harmfulness/environment. The number of the disasters collected is 81, from which 3 in relation to suffocation and handicap were excluded. The rest is related to fire/explosion and burst. Most accidents occurred at plant or on corporate side, however, it is worthy of note that accidents occurred during the charge of buttery and with advertising balloon or balloon. (NEDO)

  17. Fiscal 1975 Sunshine Project research report. Research on safety technology for hydrogen energy systems; 1975 nendo suiso energy system ni okeru hoan gijutsu ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-05-01

    Important notices and problems on the safety for hydrogen gas were analyzed. Analysis was made on hydrogen gas property, flammability, explosivility, bio-toxicity, equipment, storage, transport, leakage, fire, technology and education for safety management, and quality and analysis of products. Study was also made on the relation between the above items and every domestic or overseas standard. Important notices and problems on the safety for liquid hydrogen were analyzed. Analysis was made on liquid hydrogen property, liquefaction and refining equipment, transport, storage, materials concerned, bio-toxicity, leakage, fire fighting technique, and safety management. Among them, such problems are pointed out from the viewpoint of accident prevention, as O-P conversion, refining of hydrogen gas for liquefaction, selection of structural materials, hydrogen embrittlement, layout of various equipment and devices, explosion-proof electric devices, and leakage detection. Research on effective fire fighting and fire preventive measures against hydrogen leakage and diffusion from tanks or piping are also in demand. (NEDO)

  18. Report on evaluation of research and development of direct steel-making using high-temperature reducing gas. Phase 1. Draft; Koon kangen gas riyo ni yoru chokusetsu seitetsu no kenkyu kaihatsu (daiikki) ni kansuru hyoka hokokusho (an)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-01-01

    Described herein is development of direct steel-making using high-temperature reducing gas. A light hydrocarbon fraction (boiling point: 230 degrees C or lower), produced by steam cracking of vacuum residua, is reformed into a reducing gas in the presence of steam, using heat to be supplied by a nuclear plant which produces high-temperature gases for various purposes. This reducing gas is then supplied to a plant for producing reduced iron. This project has established basic techniques for designing, constructing and operating a direct steel-making pilot plant, to be connected to a 50 MWt high-temperature gas test furnace. The closed iron-making system and greatly reduced SOx emissions to several fractions of the current level are some of the expected effects. The environmental impacts of the high-temperature gas furnace will be on a level with those associated with a light-water reactor. Cracking and gasification of vacuum residua, which has found limited purposes so far, should expand its applicable areas and reduce dependence on fossil resources, leading to diversification of energy sources. The overall thermal efficiency of the high-temperature gas furnace is expected to increase to at least 60%, because its high-temperature gases of around 1,000 degrees C can be used for heating processes, and the waste heat can be further used for generation of steam for power production. (NEDO)

  19. Fiscal 1997 survey report. 2. Survey on the preparation of technical information in the APEC region (downstream field); 1997 nendo chosa hokokusho. 2. APEC ikinai ni okeru gijutsu joho seibi ni kakawaru (karyu bun`ya)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The Japanese government is conducting the training on the CCT downstream field for the persons concerned in the CCT utilization field in the APEC region, especially in nations as new comer into the CCT utilization field where the coal consumption is expected to rapidly increase (China, Indonesia, Thailand, and the Philippines). The demand for CCT diffusion/education to the persons concerned in coal utilization in the APEC region is increasing from each country, and the CCT diffusion/education is becoming a more and more important issue. Accordingly, for the purpose of increasing the understanding of CCT and improving the ability of the persons concerned in APEC countries, the paper surveyed and arranged the environmental protection technology out of the CCT technical information of Japan, and inputted the results into CD-ROM. The results are planned to be used for the understanding of Japan`s advanced CCT and ability improvement in the CCT training course to be planned for managers and engineers from APEC countries. The CD-ROM includes the coal combustion flue gas related technologies such as desulfurization technology, denitrification technology and dust collecting technology which are the environmental protection technology out of the coal utilization technologies in Japan

  20. Report on the Sunshine Project in fiscal 1990. Studies on liquefaction characteristics by coal types and on engineering properties; 1990 nendo tanshu ni yoru ekika tokusei to kogakuteki busseichi ni kansuru kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-07-01

    This paper describes the achievements at the Government Industrial Development Laboratory, Hokkaido in the Sunshine Project in fiscal 1990. Surveys were carried on different catalytic activities for co-liquefaction of various types of coals. The Ru system was found preferable in acquiring fatty family products of low boiling points. Reactions of co-liquefaction constituents do not progress independently, but have positive interaction. Adding Ru is effective in accelerating hydrogenation of condensed aromatic rings and hydrogenation of cleaving nucleus, but in view of the hydrogenating decomposition capability, the Mo-system may be better. In a liquefaction plant test, diesel oil was manufactured by reforming and improving the Yallourn coal light oil. However, the oxygen content was too high, aggravating the temperature distribution control in catalyst bed, and not having achieved the intended denitrification rate. Discussions were given on co-liquefaction of the depressurization residues of Cold Lake (CLVB[vacuum bottom])/Athabasca (ATVB) and Battle River coal. The CLCVB and ATVB were turned into lower molecules easily through hydrogenation treatment. The reaction characteristics reflected the characteristics of medium oil. Depolymerization of coal has progressed faster in ATVB. In the study on the engineering property values, discussions were given on behavior of solid particles in a bubble column, and gas hold-up of slurry. (NEDO)

  1. Report on simple operation type CAD/CAM system development through international cooperation. Current statuses of Asian countries; 'Kan'i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Asia shokoku no jokyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    Information systems, mainly aided by computers, are becoming increasingly important, contributing to development of wide areas of societies and economics, to begin with. However, few developing countries have established sufficient information systems, in spite of their strong desires to do so, which will further widen the gap between them and advanced countries, where these systems are acceleratedly advancing. Given these situations, Center of International Cooperation for Computerization (CICC) has been implementing various projects for providing assistance to and cooperation with oversea countries which are trying to develop information systems. This report summarizes the project, which CICC has been commissioned by NEDO as part of the cooperation programs, for manufacturing technology supported by advanced and integrated information system through international cooperation. It outlines the research cooperation memoranda NEDO has concluded with Indonesia, Malaysia, Singapore and Thailand, and the authorities of China, Indonesia, Malaysia, Singapore and Thailand. (NEDO)

  2. Research report of fiscal 1997. Survey on creation of high-efficiency renewable resources, and bioconversion technology; 1997 nendo chosa hokokusho. Kokoritsu saisei kano shigen no sosei narabi ni bioconversion gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Survey was made on material production technology using creation technology of high-efficiency renewable resources (photosynthesis reaction of plants). Industrially usable plant resources in overseas countries and Japan were arranged, and plant resources unused for food were also surveyed. The present state of genetic engineering necessary for metabolic engineering of higher plants such as fit and high-expression technology of genes, plant cell cultivation, and control technology of plant cell multiplication is described, and elementary technologies required for future gene-recombined plants are predicted. Survey was also made on the trend of creation technology of industrial plants for fat and oil, biodegradable polyester, amino acid, cellulose, fiber (cotton) and forest wood. A patent list on plant biotechnology was prepared, and study on bioconversion of plant resources was also surveyed. Overseas R & D trends on conversion and effective use technologies of renewable bio- resources are reported, and process design and its profitability were evaluated through a case study. 414 refs., 87 figs., 55 tabs.

  3. Report on a survey in fiscal 1999. Survey on industrial utilization of microorganism reaction mechanisms under anaerobic condition; 1999 nendo kenki jokenka ni okeru biseibutsu hanno kiko no kogyoteki riyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Industrial utilization of reaction mechanisms of microorganisms under anaerobic condition permits structuring energy saving type production processes. The present survey has investigated features of new microorganisms under anaerobic condition and the status of researches thereon inside and outside the country, and discussed their future applications. Chapter 1 compares anaerobic microorganisms and functions of microorganism under anaerobic condition with those aerobic to describe their general features, and describes the purpose of this survey and the summary of the investigations. Chapter 2 surveys the current status of technologies to utilize microorganisms under anaerobic condition. Chapter 3 outlines metabolic characteristics of the anaerobic microorganisms, and extracts functions effective for material production by different anaerobic microorganisms to describe their applicability. Chapter 4 evaluates the system classification for the anaerobic microorganisms utilizing the basic arrangement of 16S rRNA genes, and extracts technical problems therein. Chapter 5 proposes structuring a total methane fermentation system including a raw material collecting process, and enhancing alcohol productivity of Zymomonas bacteria. (NEDO)

  4. Research report for fiscal 1998. Survey on the researchers and research institutes for the effects of global warming and its countermeasures; 1998 nendo onshitsu koka gas ni yoru kankyo eikyo nado ni kansuru kenkyusha kenkyu kikan chosa chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Researchers and research institutes across the world (except those in Japan), engaged in the study of global warming and measures to deal with the phenomenon, are extracted in compliance with certain specified standards, and the latest information on them is appropriately arranged and listed. It is further developed into an electronic database for the convenience of users. The collected information includes more than 230 research institutes and more than 1,000 researchers. The endeavor is exerted by extracting essays and institutes mainly out of the on-line databases. More than 1,000 essays and 130 institutes are covered. Visits are made to five institutes in the U.S. and four in Europe who are most actively engaged in the study of global warming, and detailed researches are conducted and information is exchanged. The Argonne National Institute copes with all energy problems related to global warming. Descriptions are given about environmental impact surveys and CO2 isolation in the ocean at the Center for Global Science of the Massachusetts Institute of Technology. At the Oak Ridge National Laboratory, the visitors heard explanations of technologies related to renewable energies and so forth. Researches are made into ecosystems at the University of California, and into natural energies at the University of Hawaii. Also visited are research institutes in Australia, Germany, Netherlands, and Britain. (NEDO)

  5. Report on research cooperation for bio-aided treatment of waste water from pits, conducted in FY1997; 1997 nendo bio riyo ni yoru kohaisui shori gijutsu ni kansuru kenkyu kyoryoku hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This research cooperation promotion project was implemented to develop techniques for preventing water pollution by waste water from pits in mines in China and thereby contributing to environmental preservation by studying to select optimum bacteria, culture the bacteria for high-efficient oxidation of iron, efficiently remove heavy metals from waste water, develop waste water treatment techniques with the aid of the iron-oxidizing bacteria, suitable for the mines in China, and develop techniques for recovering useful resources. The bio-aided waste water treatment process is a suitable method for treating waste water discharged from mining pits, in which ferrous iron present in waste water is oxidized with the aid of iron-oxidizing bacteria growing with ferrous ion as the energy source into ferric iron, which is precipitated at a low pH and removed in the presence of inexpensive calcium carbonate as the neutralizer. The pilot plant has been operating smoothly in a mode to treat waste water discharged from mining pits in Wushan Mine, almost satisfying the targets of treated water properties, i.e., pH: 0.5 or less, Cu: less than 0.5, Zn: less than 2.0, Pb: less than 1.0, Cd: less than 0.1, As: less than 0.5, Mn: less than 2.0, and SS: less than 70, all in mg/L except for pH. (NEDO)

  6. Report on a survey in fiscal 1999. Survey on the actual state of utilizing unified evaluation models for global warming; 1999 nendo chikyu ondanka ni kansuru togo hyoka model no katsuyo jittai ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The present survey is intended to compare and analyze major unified global warming evaluation models available inside and outside the country, and analyze the directionality on supports for the future model developments that will be performed by the Ministry of International Trade and Industry. The report describes in Section 1 how the summaries of the global warming evaluation models may be put into order. A unified evaluation model may be positioned basically as a platform to unify the processes of recognizing scientific problems and the processes of determining the policies. Section 2 describes how the summaries of the major global warming evaluation models may be put into order. The models include the followings: DNE21 (Dynamic New Earth 21), GRAPE model, AIM model, MESSAGE (IIASA) model, IMAGE2 (RIVM), and GREEN (Gene Ral Equilibrium Environment)(OECD). Section 3 summarizes the purposes, general situation of development, scope of the objects, and technological features as the features of each model. Section 4 describes the analysis of the actual state of utilizing unified evaluation models for global warming. The results of the analysis were put into order in a map form to make clear the positioning of the major models that have been put into order. (NEDO)

  7. FY1998 report on a survey related to joint utilization of welfare device development data using an international network; 1998 nendo kokusai network ni yoru fukushi kiki kaihatsu data no kyodo riyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A survey was made in relation with joint utilization of welfare device development data using an international network. Developing welfare devices requires data from ergonomic and medical systems, while the cope of the objects is wide, and the kinds are various. For proliferation of welfare devices, system compatibility evaluation including that on using environment is important, including living environments that are different by countries. The present survey has identified how data for aged, handicapped and help-needing persons are accumulated and utilized in research organizations in America and Europe for both of the ergonomic and medical areas. The survey also investigated major academic societies in overseas countries, and collected database and academic network information that support the advanced research and development. At the same time, investigations were also made on organizations and corporations who are moving forward the efficient data utilization. Welfare device and service information providing systems in Japan were investigated to compare them with the trends in other countries. Conceptions and methods were compiled to utilize data internationally and jointly. Database models for device development were considered, and a proposal was made on structuring a research and development supporting database, and the operation method thereof. (NEDO)

  8. FY 2000 report on the survey on the global warming prevention measures in the U.S.; 2000 nendo Beikoku ni okeru ondanka boshi taisaku no gaiyo ni tsuite hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The results of the overseas survey were summed up mostly of global warming prevention measures taken by the U.S. government and those by private companies. At COP3 in 1997, the U.S. gave a pledge internationally that they would reduce greenhouse effect gas emissions during 2008-2012 7% below from that in 1990. But the U.S. government seems hesitating to take concrete measures in regions. Hesitating, however, they are publicly making it a target to find how to eliminate a risk of global warming which is now a global problem in cooperation with other countries and international organizations. Concretely, programs are as follows: ranking of the energy consumption amount of household electric appliances, housing loan programs taking energy efficiency into account, preferential taxing system, incentive money system in case of using the substituting energy transportation program, waste management program, commendation of men of achievements and prize-winning, etc. (NEDO)

  9. Achievement report for fiscal 1998 on Simple Operation Type CAD/CAM System Development through International Cooperation; 1998 nendo 'kan'i sosagata denshi sekkei seian shien system no kaihatsu ni kansru kenkyu kyoryoku' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The subject project is implemented in the fields of automobiles and their parts, electrical home appliances and their parts, and textile and apparel. In the field of automobiles and their parts, a prototype is developed of an integrated information management system which is to serve between corporation head offices and assembling businesses overseas, and another prototype is developed of an inter-business technical data serving system which is to serve between overseas assembling businesses and supporting businesses, both involving Japan, Indonesia, and Thailand. In the field of electrical home appliances and their parts, a prototype is developed of an electronic catalog system in a joint endeavor with research institutes of Indonesia, Malaysia, Singapore, and Thailand, and a demonstration test is conducted. A design concurrent engineering system is developed by Japan and Malaysian research institutes. In the field of textile and apparel, prototypes are developed, by Japanese, Chinese, and Indonesian apparel manufactures, of an apparel manufacturing specification system, international EDI (electronic data interchange) system, translation system, and a CAD (computer-aided design)/CAM (computer-aided manufacturing) data interchange system. (NEDO)

  10. Report for fiscal 1997 on simple operation type CAD/CAM system development through international cooperation. Research achievements; 1997 nendo 'kan'i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Kenkyu seika

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper reports the achievements in fiscal 1995 in the research and development project for an electronics design and production aid system of simple operation type (MATIC). The project is intended to support works of Asian countries on the information society, and enhance levels of the manufacturing industries and supportive industries by utilizing the information technologies. The working group (WG)I, related to automobiles and components thereof, improved functions of the primary system and continued demonstration tests. The group launched for the secondary system a system development that makes timely information transmission and receipt possible among research and development enterprises, local assembly enterprises and facility and parts suppliers. The WGII (household appliances and their parts) designed and developed an electronic catalog system based on pre-prototypes developed independently by different countries, and performed demonstration tests. The WGIII (textiles and apparels) carried out with China demonstration tests on the international EDI system, translation system and CAD/CAM system. It also developed a sewing technology standards system. It installed equipment and devices in Indonesia for preparation of the demonstration tests. (NEDO)

  11. FY 2000 Report on the survey results. Survey on international cooperation for development of a system for supporting low-invasion surgical operations; 2000 nendo teishinshu shujutsu shien system kaihatsu ni kakawaru kokusai kyoryoku ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The international Medical Treatment Symposium and Exhibition were held from July 20 to the end of August, 2000 in Hannover in Germany, in which the Japan's system for supporting low-invasion surgical operations was presented and information was exchanged for the system. A total of 50 to 100 neurosurgeons visited the exhibition, held as part of the symposium, every day from July 21 to 24. The system for supporting low-invasion surgical operations is rated as the most advanced one in the world. It attracted much attention, because a number of attendees applied for operating manipulator. The research trends seen in the symposium point to early diagnosis of diseases, finer surgical operations, low-invasion type operations, use of high-function diagnosis devices for improving operations, real-time imaging, and application of DNA diagnosis to pathological diagnosis, among others. Japan is leading the world in the technological areas of micromachines, robotics, high-vision and diagnosis. The bold researches, e.g., those on artificial visual and hearing systems to be embedded in the head, are pursued more extensively in the overseas countries. (NEDO)

  12. Fiscal 1999 research result report. Research on improvement of boiling heat transfer characteristics by photocatalyst wall; 1999 nendo hikari shokubai hekimen ni yoru futto netsu dentatsu tokusei kaizen ni kansuru kenkyu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Research was made on improvement of the wettability and boiling heat transfer characteristics of a photocatalyst wall. Measurement experiment of the wettability was made for anatase type titan oxide-coated Al, SUS and Pb plates, rutil type titan oxide-flame coated SUS plate, raw plate, and oxide-plasma coated titan plate. In the ground experiment, the contact angles of distilled water and oil on specimen surfaces were measured. In the microgravity experiment, falling droplet images were recorded by using the facility of Japan Microgravity Center (JAMIC). For obtaining the effect of radioactive emission, UV irradiation, {gamma} ray and neutron beam irradiation by nuclear reactor, and {gamma} ray irradiation by Co-60 were carried out. As the experiment result, the rutil type titan oxide-flame coated SUS plate, nonconductor-coated titan plate, and zircaloy plate showed large improvement of the wettability by {gamma} ray irradiation with Co-60. It was also confirmed that in particular, titan shows the large effect of radioactive emission, and the wettability deteriorates rapidly after {gamma} ray irradiation. (NEDO)

  13. Fiscal 1998 research report on the development trends of natural gas conversion technologies into liquefied fuel in Russia; 1998 nendo Roshia ni okeru tennen gas no ekitai nenryoka gijutsu no kaihatsu doko nado ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Russia having natural gas resources largest in the world is actively promoting the basic research on liquefaction technology of natural gas such as Fischer-Tropsch (FT) synthetic catalyst, and its research potential is extremely high. This 3-year research project surveys the R and D trends of catalyst technology for liquefaction of natural gas, and fabricates the prototype FT synthetic catalyst based on the idea of Russian researchers to evaluate its feasibility experimentally. This report summarizes the following to clarify the research background: (1) The technology system for liquefaction of natural gas, and its future R and D trend, (2) The R and D trends of liquefaction technology of natural gas in the world, (3) The R and D trends of liquefaction technology of natural gas in Russia, (4) The research system of catalyses in Russia, (5) The activities of Russian catalysis research institutes, (6) The fuel liquefaction technologies of Russian major research institutes, and (7) The proposals from Russian research institutes. (NEDO)

  14. Fiscal 1998 research report on development of the advanced industrial furnace (R and D on the advanced industrial furnace). Volume 3; 1998 nendo koseino kogyoro no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This report summarizes the research results of the chapter 4 and 5 (experimental database) from the research report on development of the advanced industrial furnace. The chapter 4 summarizes functions of the temperature performance evaluation simulator of the advanced continuous heating furnace for the database system, and various research results obtained by the simulator. This chapter also summarizes the research result on the applicability of high-temperature air combustion to other industries, the patent research result on heat storage combustion technology, the basic technology research result, and the reaction analysis result by FLUENT. The chapter 5 summarizes the combustion experiment data collection by developing self-completion high-temperature high-radiation heating technology. As for R and D on technology optimizing the profile of heating furnaces, the following data are summarized: measurement data of heat transfer in furnaces and heat flux data at right overhead furnace temperature under cold air and preheated air combustion in conventional furnaces, and heat storage combustion. (NEDO)

  15. Fiscal 1997 survey report on the project on energy conservation by effectively using building energy in Indonesia; 1997 nendo chosa hokokusho (Indonesia ni okeru biru energy yuko riyo ni yoru sho energy ka project chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    As an energy conservation method for a model building, the following eight methods were selected and trially calculated of the effects. 1) adoption of high efficient illumination apparatus, 2) introduction of an illuminance control system, 3) cooling water secondary pump with invertor, 4) ventilation control for parking lots, 5) heightening of the established temperature, 6) improvement of the 24-hour run chiller, 7) elevator with invertor, and 8) introduction of the photovoltaic power generation. As a result, it was found out that energy was totally reduced by about 3,837.4 MWh/yr or 25.6%. If viewed from the amount of reduction in greenhouse gas, the amount of CO2 emitted from office buildings, approximately 0.22 million t-C/yr, decreases to approximately 0.16 million t-C/yr. Further, approximately 0.93 million t-C/yr, the amount of CO2 emitted from commercial use facilities such as office buildings, department stores and hotels is reduced to about 0.69 million t-C/yr, thanks to the effect of the project on energy saving buildings, which made a CO2 reduction by approximately 0.24 million t-C/yr possible. Validity of the project on energy conservation in Indonesia was confirmed. 2 refs., 55 figs., 38 tabs.

  16. Fiscal 1999 survey report. Survey of leading countries' approaches to biomass energy development; 1999 nendo shuyokoku ni okeru biomass energy kaihatsu eno torikumi ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The survey aims to help Japan deliberate its future biomass energy development strategy including the course Japan is to follow in its research and development of biomass energy by clarifying leading countries' approaches to the subject matter and trends of their research and development efforts in this connection. The states of biomass energy development in the U.S. and Europe are reported. In the U.S., President Clinton issued Executive Order 13134 on August 12, 1999, regarding bio-based products and bioenergy development. In this country, bioenergy and bio-based production technologies have developed to reach a stage where business pays, and commercial plants are in service. The U.S. Administration mentions as a strategy the efficient development of the bioenergy industry. In Europe, where resources are versatile and local, it is difficult to assess the economy of scale, and small-scale development efforts are being accumulated. Practical technologies under development mostly involve direct combustion. European measures are similar to U.S. measures in that such political goals as local development and employment promotion are firmly woven into them. (NEDO)

  17. Reports on 1981 result of Sunshine Project. Research on conditioning required for industrialization of new energy technology; 1981 nendo shin energy gijutsu kigyoka ni hitsuyona joken seibi ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    This research was intended to establish foundation for the coming new energy era, by clarifying all interfering elements and taking counter measures, in further spreading and promoting the new phase of new energy technology development under the Sunshine Project. With the public section as the main body, studies were made in the technological aspect as well as the legal/institutional aspects, and also an investigation was conducted of the cases of introducing new energy from overseas. In the subject research, with 1990 set as the target year, the following examinations were carried out for the purpose of concretely estimating the situation of introducing new energy into the society in Japan at such point in time. The examinations were to study the feasibility of substitution with new energy in fiscal 1990 on the present level of oil consumption; to extract problems on the basis of the results and examining a policy of introducing and promoting new energy; and, to investigate on the spot, as a case study in building a coal liquefaction plant in a coal production area overseas, a relation with the energy policy of the producing country in implementing the overseas operation and importation of liquefied oil so produced, etc. (NEDO)

  18. Achievement report on research and development (1st phase) of direct iron making by use of high-temperature; Koon kangen gas riyo ni yoru chokusetsu seitetsu no kenkyu kaihatsu (daiikki) ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1981-02-01

    Efforts are put into the study of direct iron making for use in a closed system where heat energy from a multi-purpose high-temperature gas furnace expected to be developed in the near future will be utilized for iron making. The researches, carried out for the establishment of technologies necessary for designing, building, and operating a pilot plant dimensionally suitable for connection to a 50MWt multi-purpose high-temperature gas furnace, cover the plant total system, a high-temperature heat exchanger, ultrahigh-temperature alloys, high-temperature insulating materials, a reduced gas generating unit, and a reduced iron making unit. When the effort is evaluated as a whole, it is found that the newly developed system is effective in preventing pollution, emitting but 0.1Nm{sup 3} of SOx per 1 ton of crude iron against the 0.4-0.9Nm{sup 3} emitted by a blast furnace/converter iron making mill. It is also found effective in reducing fossil fuel dependence and in enhancing energy source diversification. When it comes to energy conversion efficiency, furthermore, it is shown that the new system achieves a rate of 60% or more while only approximately 30% is attained by light water reactor power generation and approximately 40% by a high-temperature gas furnace. (NEDO)

  19. FY 1997 report on the research study for preparation of NEDO`s vision. Biomass energy; 1997 nendo chosa hokokusho (NEDO vision sakutei ni muketa chosa kenkyu). Biomass energy ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Research study was made on the current usage, technological development and future subjects of biomass energy. The current use of biomass energy over the world estimated to be nearly a billion t/y oil equivalent. This value is estimated to be only a part of a pure primary biomass yield of 73 billion t/y oil equivalent showing a large supply potential. The evaluation result of a biomass energy potential in the world by GLUE (Global Land Use and Energy Model) considering worldwide biomass flow and competition of land use showed that no change of land use form in advanced areas is predicted, and no production of new biomass energy from forests in advancing areas is also expected. Production of biomass energy from farm products is promising in advanced areas, while the potential of biomass residue is high in advancing areas showing the possibility of energy development. Development of new biotechnologies such as molecular control of bio-production functions is expected to increase biomass resources. 76 refs., 26 figs., 30 tabs.

  20. Reports on 1976 result of Sunshine Project. Investigation on development policy and position of various coal liquefaction processes in Japan; 1976 nendo Nippon ni okeru kakushu sekitan ekika process no kaihatsu hoshin to ichizuke ni kansuru chosa seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1977-03-01

    This report is the summary of the 'investigation results concerning development policy and position of various coal liquefaction processes in Japan'. The purpose of this investigative research is primarily to clarify the position of coal energy in the future energy supply, technologies of converting coal to clean fuel as the form of coal energy utilization most suitable for Japan, and the position of coal liquefaction in such converting technologies, and also to decide on the policy of R and D on coal liquefaction process in Japan at present. Accordingly, this paper investigates the status quo of various liquefaction processes including the coal liquefaction technologies for which R and D are conducted under the Sunshine Project; making analysis/assessment from such viewpoint as clean process as environmental safeguard and a precondition for coal energy utilization, technical problems concerning coal import and transportation, and suitability for the present energy consumption structure centering on oil; and further, examining the position of coal liquefaction in the general effective utilization of coal as organic carbonaceous resources in the distant future. (NEDO)

  1. Report on surveys in fiscal 2000 on the survey on preparing list of names of well-informed persons in industrial technological fields; 2000 nendo sangyo gijutsu bun'ya ni okeru yushikisha meibo sakutei ni kakawaru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    In order to identify, in establishing plans for industrial technological fields, the well-informed persons from whom useful knowledge and comments can be obtained, a well-informed person survey was conducted by surveying and hearing the roles and selection processes of the well-informed persons inside and outside the country. For the organizations in Japan, the survey was made on Japan Society for the Promotion of Science, and Japan Science Technology Organization. For the organizations outside the country, surveys were made on two organizations in the U.S., one organization in Germany, and one organization in U.K. All of them are the research aiding organizations established to allocate the national budget to the research investments. As compared to Japan, the organizations in foreign countries are characterized as follows: technological fields that are given priority are declared clearly by the organizations; in selecting the publicly advertised projects, the guidelines on the research scope are strict, but flexibility is given in fund allocation; the first screening process is carried out by researchers and scholars in the same technological field, and the second screening is performed by the authorization committee. Extraction of well-informed persons and preparation of a name list were performed for some of the technological fields in Japan by means of the hearing survey. (NEDO)

  2. FY 1997 report on the modification of dental materials with Ag for improvement of antibacterial activity; 1997 nendo chosa hokokusho (gin ion ni yoru shikayo zairyo no kokinsei fuyo ni kansuru kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Improvement of an antibacterial activity is one of the issues in modification of artificial teeth for an aged society. Study was made on improvement technique of an antibacterial activity with Ag ion as secondary corrosion measures. Partial gaps of dental materials themselves and gaps between materials and peripheral tissues causes bad breath or bad teeth through propagation of disease germs. Ag ion is harmless and has an antibacterial activity for bio-tissues from a macro-viewpoint, however, only corrosion germ causing bad teeth in mouths should be sterilized by controlling an elution rate of Ag properly. The antibacterial activity was controlled by controlling Ag ion implantation depth and rate, and Ag elution rate for dental materials. Experiment was made on an IMZ twinplus specimen implanted with Ag ion and an Ag thin film-coated specimen using beagle dog in comparison with an unmodified specimen. As a result, the very favorable antibacterial activity was obtained. Ag ion is effective for prevention of endogenous infectious disease due to mouth germs in dental surgery. 3 refs., 47 figs., 10 tabs.

  3. Report on research results of the development of high efficient boilers in fiscal 1996. Research development of high efficient industrial furnaces, etc; Koseino boiler no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Out of the developments of high efficient boilers which have been continued since fiscal 1993, the paper reported the result of the development conducted in fiscal 1996. The oxygen combustion (the oxygen enrichment combustion including 100% oxygen combustion) decreases the amount of flue gas and reduces heat loss of the flue gas, and is also effective as NOx reduction measures. The experiment was conducted using testing furnace. The boiler efficiency rapidly increased with the increasing concentration of oxygen enrichment. In the pure oxygen combustion, the overall boiler efficiency of a 106% level (low heating value standard) is expected. Since the boiler wet flue gas is decreased, the NOx emission is reduced. The boiler can raise the combustion temperature with no fear of NOx and can be reduced in size. CO2 decreases in proportion to the energy saving effect. The development of a condensation flue gas heat exchanger is aimed at recovering heat down to the low temperature. Prediction of heat transfer in the steam condensation region becomes possible, and the size reduction can be expected. Dew point corrosion resistant materials were also selected. As to the high speed combustion control, a simple type using micro-processor was developed. Obtained were high speed, compactness, electric power saving, and high controllability. 14 refs., 306 figs., 88 tabs.

  4. Report for fiscal 1995 on simple operation type CAD/CAM system development through international cooperation. Research results; 1995 nendo 'kan'i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Kenkyu seika

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    This 5-year project beginning in FY 1994 is aimed at joint researches with various Asian countries for development of simply operable electronic designs and manufacturing support systems, which supports development of supporting industries (SI) for manufacturing industries in these countries. The project is being implemented in a total of 5 countries, China, Indonesia, Malaysia, Singapore and Thailand, in cooperation with the research institutes with which NEDO has concluded the basic contracts. The following three working groups are established to study construction of the model systems and design these systems for promotion of the joint project in each country; (1) automobiles and their parts, (2) home electric/electronic appliances, and their parts, and (3) textiles and apparels. The FY 1995 project results are described. The working group (1) covers definitions of the business models and conditions for systematizing these models for the demonstration tests. The working group (2) covers development of the electronic catalogues, electronic yellow pages/preproto types, and concurrent engineering. The working group (3) covers the SGML sewing technique specification systems, surveys and utilization tests for network infrastructures, international EDI systems for the textile industry, and translation systems for technical terms of the textile industry. (NEDO)

  5. Survey report for fiscal 1998. Evaluation by industrial circles of the COP3 outcome and their future response (America); 1998 nendo chosa hokokusho. COP3 no kekka ni taisuru sangyokai no hyoka oyobi kongo no taio ni tsuite (Beikoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Response in America to COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change) is investigated. Office of Energy Efficiency and Renewable Energy (EE) of America's Department of Energy conducts activities designed to protect environments and supports America's economic competitiveness. The scope of EE activities is quite wide, covering efforts at energy efficiency improvement and renewal energy utilization for all energy consuming sectors involving construction work and equipment for buildings, various industries and public utility works, and transportation. EE also supports and promotes the development of advanced industrial materials, electric vehicles, hybrid vehicles, fuel cells, etc. In the field of renewable energy, it deals with the exploitation of sunlight, biomass, wind force, water power, geothermal energy, etc. It also supports efficiency improvement efforts being undertaken through studies of advanced power transmission and distribution, high-temperature superconduction, energy storage, etc. The said supports are provided not only by Federal Government but also by state governments, and include financial aids. A number of programs are under way, worked out and promoted by the respective bureaus and departments. They are evaluated, protected, and implemented through the partnership of official and civilian organizations. (NEDO)

  6. Outline of investigation on restraint of carbon dioxide generation by green chemistry. 1999.1-1999.3; 1998 nendo green chemistry ni yoru CO2 hassei yokusei ni kakawaru chosa kenkyu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Investigations were conducted into the above in some leading OECD (Organization for Economic Cooperation and Development) member states. Green chemistry is a new concept in which clean technology, environment-friendly chemistry, and the like are combined, and is a chemical solution for reducing or stopping the use or generation of materials, products, by-products, solvents, reagents, etc., which are dangerous to health and environments, throughout the whole life cycle of chemicals covering the processes of their designing, manufacturing, dumping, and recycling. In this fiscal year, the actual state of the generation of biomass, regarded as representative of reproducible materials, and its feasibility as chemical resources were investigated. In an effort at finding out chemical reactions safer to health and causing less environmental impact, investigations were also conducted into the recent trends of catalysts, novel reactions for organic syntheses, use of supercritical fluids, photocatalysts, biomimetic processes, etc. The development of substitutes for plastic additives was also studied. Since acceptance by the citizenry is quite important for green chemistry to take effect, educating and enlightening activities in the U.S., Britain, France, and Germany were inquired into. (NEDO)

  7. Fiscal 1997 report on the survey of the actual state of various coal related industrial furnaces in China; 1997 nendo chosa hokokusho (Chugoku ni okeru sekitan ni kakawaru kakushu kogyoro no jittai chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    It is thought that environmental prevention technologies related to boilers which are the largest coal use field in China have been almost all made model projects till now. Further, coal or coke is used in various industrial furnaces except boilers in every industrial sector in China. The amount of coal use there is large next to that in boilers, which is a cause of the country`s serious air pollution. Accordingly, an investigation was commenced in fiscal 1997 aiming at grasping the actual state of environmental pollution caused by various coal related industrial furnaces in China and studying the environmental improvement. This time, various industrial furnaces were examined in chemical and iron/steel industries. It could be inferred that both industries made efforts to enhance and rationalize production activities and then give consideration also to the environmental prevention. Generally, however, most plants still have old-fashioned production facilities, while the facilities are being modernized little by little. It was found that in China productivity was lower than Japan and the environmental pollution was in a serious condition. 16 refs., 28 figs., 69 tabs.

  8. Achievement report for fiscal 1997 on research under New Sunshine Program. Research on heavy oil hydrogenation and heavy oil/coal coprocessing; 1997 nendo jushitsuyu no suisoka shori narabi ni jushitsuyu/sekitan no coprocessing ni kansuru kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-02-01

    The achievements of the Hokkaido National Industrial Research Institute relating to the titled research are reported. In the study relating to the structural properties of heavy oils, the structures of products of Green River shale oil carbonization is analyzed, heterofunctional groups contained in the oil are subjected to FT-IR (Fourier transform infrared) spectroscopic analysis, and their forms of existence are investigated. In the study relating to the hydrogenation process of heavy oils, findings obtained from experiments are reported, which involve the processing of shale oil by hydrogenation and changes brought about in its chemical structure, hydrogenation of oil sand bitumen, kinetics of hydrocracking of bitumen at a high conversion rate, and a lumping model for bitumen hydrocracking reaction. In the study relating to the coprocessing of heavy oil/coal, coprocessing is experimented for coal and shale oil, coal and oil sand bitumen, and other combinations, and the results are reported. Also, a review is made of the transfer of hydrogen in coprocessing. (NEDO)

  9. Report on achievements in fiscal 1975 in Sunshine Project. Studies on physical and chemical properties of rocks in geothermal areas; 1975 nendo chinetsu chitai ni okeru ganseki no butsuri kagakuteki tokusei ni kansuru kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-03-01

    This paper reports the achievements of (A) studies on change in rock specific resistance due to temperature and water content, and (B) petrological, mineralogical and chemical studies on thermally transformed rocks. In the study (A), it was discovered that use of high-pressure capsules allow to obtain test samples in a condition of containing hot water as a result of studies on temperature change in rock specific resistance due to hot water content. In the measurements of geothermal gradient and heat conductivity of test drilled rock cores, the experiments revealed that there are different patterns of temperature restoration due to geological conditions and finish of wells, and properties of mud water used. The studies on thermal structures and underground structures decided shapes of measurement test samples of test drilled cores. In the measurements of heat conductivity and heat flow rate of test drilled rock cores, considerations were given on the relationship among sectional temperature increasing rate, heat conductivity and heat flow rate. The measurements of residual magnetism and magnetization in rocks described interpretation on the result of test drilled core measurement. In the study (B), aluminous sphere in the Hachimantai Onuma geothermal area is first described. Then, a description is given on the relationship between chemical constituents and electric conductivity of natural water in Mt. Akita Yakeyama and its vicinity. (NEDO)

  10. FY 1999 achievement report on the development of high performance boilers. R and D on high performance industrial furnaces, etc.; 1999 nendo koseino boiler no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This project started in FY 1993 to survey the actual state of industrial use boilers. Based on the results of the survey, in fiscal 1995, 1996 and 1997, no improvement of the present technology which has limits, but the development was made of the oxygen combustion and element technology which are factors for heightening boiler performance with a new idea first in the world. In fiscal 1998, a target for the overall thermal efficiency of 105% was settled by testing a pilot plant where the element technology was integrated into the small once-through boiler, flue/smoke tube boiler, water tube boiler, etc. In fiscal 1999, the target of the overall thermal efficiency of boiler was reached by a pilot plant test to clarify combustion characteristics, heat transfer characteristics, environmental characteristics, etc. Further, effects of energy saving were increased by the adoption method of oxygen supply equipment. Concretely, an overall boiler efficiency of 105.73% exceeding the targeted value of 105% was achieved at a pilot plant of actual scale, by concentrating the results of each of the element technologies such as 'oxygen combustion,' 'condensation type flue gas heat exchanger,' 'high performance combustion control device,' and 'rapid rotating auxiliary machine.' (NEDO)

  11. The complex transfer reaction (14C, 15O) on Ni, Zn and Ge targets: existence and mass of 69Ni

    International Nuclear Information System (INIS)

    Dessagne, P.; Bernas, M.; Langevin, M.; Pougheon, F.; Roussel, P.; Morrison, G.C.

    1984-01-01

    The ( 14 C, 15 O) complex transfer reaction has been studied at 72 MeV incident energy on 58 Ni, 60 Ni, 62 Ni, 64 Ni, 68 Zn, 70 Zn and 74 Ge, 76 Ge targets. Spectra and differential cross sections have been measured in a 5 0 angular range centred around a laboratory angle of 6 0 . The nucleus 69 Ni has been observed and its mass determined for the first time

  12. Electroless Ni-P/Ni-B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance

    International Nuclear Information System (INIS)

    Narayanan, T.S.N. Sankara; Krishnaveni, K.; Seshadri, S.K.

    2003-01-01

    The present work deals with the formation of Ni-P/Ni-B duplex coatings by electroless plating process and evaluation of their hardness, wear resistance and corrosion resistance. The Ni-P/Ni-B duplex coatings were prepared using dual baths (acidic hypophosphite- and alkaline borohydride-reduced electroless nickel baths) with both Ni-P and Ni-B as inner layers and with varying single layer thickness. Scanning electron microscopy (SEM) was used to assess the duplex interface. The microhardness, wear resistance and corrosion resistance of electroless nickel duplex coatings were compared with electroless Ni-P and Ni-B coatings of similar thickness. The study reveals that the Ni-P and Ni-B coatings are amorphous in their as-plated condition and upon heat-treatment at 450 deg. C for 1 h, both Ni-P and Ni-B coatings crystallize and produce nickel, nickel phosphide and nickel borides in the respective coatings. All the three phases are formed when Ni-P/Ni-B and Ni-B/Ni-P duplex coatings are heat-treated at 450 deg. C for 1 h. The duplex coatings are uniform and the compatibility between the layers is good. The microhardness, wear resistance and corrosion resistance of the duplex coating is higher than Ni-P and Ni-B coatings of similar thickness. Among the two types of duplex coatings studied, hardness and wear resistance is higher for coatings having Ni-B coating as the outer layer whereas better corrosion resistance is offered by coatings having Ni-P coating as the outer layer

  13. Heavy metal environmental impact. Nickel (Ni); Impatto ambientale da metalli pesanti. Il Nichel (Ni)

    Energy Technology Data Exchange (ETDEWEB)

    Bressa, G. [Padua Univ. Padua (Italy). Dipt. di Farmacologia, Lab. di Tossicologia

    2001-02-01

    Nickel (Ni) is a heavy metal in over 3.000 different alloys used to produce kitchen utensils, batteries, coins, etc.. Human extractive and industrial activities are therefore a cause for environmental dispersion of this metal into the biosphere. This shows how in urban areas car traffic and house-heating are the main sources of nickel pollution. Nickel is relatively non-toxic, such as iron, cobalt, copper and zinc; nevertheless prolonged inhalation of dust containing such compounds as Ni O or NiCl{sub 2} concurs in the outbreak of respiratory pathologies. The carcinogenic effect of such compounds as Ni S, Ni O and Ni(CO){sub 4} has been confirmed by experiments on laboratory animals. Ni potentially toxic concentrations, and as a consequence of potential environmental impact, are to be mainly found in populated areas where the main sources are represented by industries and landfills. [Italian] Il nichel (Ni) e' un metallo presente in oltre 3.000 differenti leghe che vengono utilizzate per la produzione di utensili da cucina, batterie, monete, ecc.. Le attivita' estrattive ed industriali dell'uomo sono quindi causa di una dispersione del metallo nella biosfera. Sono stati riscontrati elevati tassi di Ni nell'atmosfera di aree urbane. Cio' sta a dimostrare che nelle aree urbane il traffico automobilistico e il riscaldamento domestico sono le fonti principali di inquinamento da tale metallo. Il nichel e' relativamente atossico, analogamente a ferro, cobalto, rame e zinco, tuttavia l'inalazione protratta di polveri contenenti composti come il NiO o il NiCl{sub 2} contribuisce al manifestarsi di patologie dell'apparato respiratorio. E' stato confermato sperimentalmente su animali da laboratorio l'effetto cancerogeno di alcuni composti quali NiS, NiO e Ni(CO){sub 4}. Concentrazioni potenzialmente tossiche di Ni, e quindi di probabile impatto ambientale, sono maggiormente da ricercare nelle zone antropizzate dove le fonti

  14. Ultrathin NiO/NiFe2O4 Nanoplates Decorated Graphene Nanosheets with Enhanced Lithium Storage Properties

    International Nuclear Information System (INIS)

    Du, Dejian; Yue, Wenbo; Fan, Xialu; Tang, Kun; Yang, Xiaojing

    2016-01-01

    Highlights: • Ultrathin NiO/NiFe 2 O 4 nanoplates derived from NiFe layered double hydroxides are fabricated on the graphene. • NiO/NiFe 2 O 4 nanoplates on the graphene show superior electrochemical performance compared to pure NiO/NiFe 2 O 4 aggregates. • The effects of the content and the particle size/component of NiO/NiFe 2 O 4 on the electrochemical performances are studied. • Graphene-encapsulated NiO/NiFe 2 O 4 is prepared and shows slightly decreased performance compared to graphene-based composite. - Abstract: As anode materials for lithium-ion batteries, bicomponent metal oxide composites show high reversible capacities; but the morphology and particle size of the composites are hardly controllable, which may reduce their electrochemical properties. In this work, ultrathin NiO/NiFe 2 O 4 nanoplates with a diameter of 5 ∼ 7 nm and a thickness of ∼2 nm are controllably fabricated on the graphene derived from NiFe layered double hydroxides (NiFe-LDHs), and exhibit superior electrochemical performance compared to pure NiO/NiFe 2 O 4 aggregates without graphene. The nanosized NiO and NiFe 2 O 4 plates are separated from each other and the graphene substrate can prevent the aggregation of NiO/NiFe 2 O 4 as well as enhance the electronic conductivity of the composite, which is beneficial to improving the electrochemical performance. Moreover, the effects of the content and the particle size/component of NiO/NiFe 2 O 4 on the electrochemical performances are also studied in order to achieve optimal performance. Ultrathin NiO/NiFe 2 O 4 nanoplates are further encapsulated by graphene nanosheets and show slightly decreased performance compared to those supported by graphene nanosheets. The different electrochemical behaviors of graphene-containing composites may be attributed to the different interactions between graphene nanosheets and NiO/NiFe 2 O 4 nanoplates.

  15. Investigation into the MgF2-NiF2, CaF2-NiF2, SrF2-NiF2 systems

    International Nuclear Information System (INIS)

    Ikrami, D.D.; Petrov, S.V.; Fedorov, P.P.; Ol'khovaya, L.A.; Luginina, A.A.; AN SSSR, Moscow. Inst. Fizicheskikh Problem; AN SSSR, Moscow. Inst. Kristallografii)

    1984-01-01

    Using the methods of differential thermal and X-ray phase analyses the systems MgF 2 -NiF 2 , CaF 2 -NiF 2 , SrF 2 -NiF 2 have been studied. In the system SrF 2 -NiF 2 the only orthorhombic compounds SrNiF 4 (a=14.43; b=3.93; c=5.66 (+-0.01 A)) is formed. SrNiF 4 density constitutes: dsub(X-ray)=4.60+-0.01 g/cm 3 , dsub(exp.)=4.60+-0.03 g/cm 3 . Refraction indices are as follows SrNiF 4 :Ng=1.500; Nsub(m)=1.497; Nsub(p)=1.479. SrNiF 4 magnetic ordering temperature Tsub(N) approximately 100 K

  16. Microstructure and mechanical properties of sputter deposited Ni/Ni{sub 3}Al multilayer films at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Chao [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Feng, Kai, E-mail: fengkai@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Li, Zhuguo, E-mail: lizg@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Lu, Fenggui; Huang, Jian; Wu, Yixiong [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China)

    2016-08-15

    Highlights: • Ni/Ni{sub 3}Al multilayers are prepared by magnetron sputtering. • Both grain size and phase constitution of annealed Ni/Ni{sub 3}Al multilayers are dependent on individual layer thickness. • The hardness of annealed Ni/Ni{sub 3}Al multilayers varies with individual layer thickness and annealing temperature. • 40 nm Ni/Ni{sub 3}Al multilayer exhibits excellent hardness at elevated temperature. - Abstract: Nano-structured Ni/Ni{sub 3}Al multilayer was prepared by magnetron sputtering, with individual layer thicknesses h varying from 10 to 160 nm. The microstructure and hardness of Ni/Ni{sub 3}Al multilayer were investigated by X-ray diffraction, transmission electron microscopy and nanoindentation. The results show that the hardness increases with decreasing h for as-deposited and 500 °C annealed multilayers. When annealed at 700 °C, the hardness approach a peak value at h = 40 nm with followed by softening at smaller h. The influence of individual layer thickness, grain size as well as formation of ordered Ni{sub 3}Al on strengthening mechanisms of Ni/Ni{sub 3}Al multilayers at elevated temperature are discussed.

  17. Enhanced Electrocatalytic Activity for Water Splitting on NiO/Ni/Carbon Fiber Paper

    Directory of Open Access Journals (Sweden)

    Ruoyu Zhang

    2016-12-01

    Full Text Available Large-scale growth of low-cost, efficient, and durable non-noble metal-based electrocatalysts for water splitting is crucial for future renewable energy systems. Atomic layer deposition (ALD provides a promising route for depositing uniform thin coatings of electrocatalysts, which are useful in many technologies, including the splitting of water. In this communication, we report the growth of a NiO/Ni catalyst directly on carbon fiber paper by atomic layer deposition and report subsequent reduction and oxidation annealing treatments. The 10–20 nm NiO/Ni nanoparticle catalysts can reach a current density of 10 mA·cm−2 at an overpotential of 189 mV for hydrogen evolution reactions and 257 mV for oxygen evolution reactions with high stability. We further successfully achieved a water splitting current density of 10 mA·cm−2 at 1.78 V using a typical NiO/Ni coated carbon fiber paper two-electrode setup. The results suggest that nanoparticulate NiO/Ni is an active, stable, and noble-metal-free electrocatalyst, which facilitates a method for future water splitting applications.

  18. Ni(salen): a system that forms many solvates with interacting Ni atoms

    NARCIS (Netherlands)

    Siegler, M.A.M.; Lutz, M.

    2009-01-01

    Recrystallization of [N,N’-Ethylene-bis(salicylideneiminato)]-nickel(II) [Ni(salen)] has been carried out from a large selection of solvents. Crystals can be either solvent free or solvates. This study is based on X-ray crystal structure determinations, which include the redetermination of Ni(salen)

  19. Thermal stability of electrodeposited Ni and Ni-Co layers; an EBSD-study

    DEFF Research Database (Denmark)

    Rasmussen, Anette Alsted; Gholinia, A.; Trimby, P.W.

    2004-01-01

    The influence of heat treatment on the microstructure and the microtexture of electrodeposited Ni and Ni-Co layers was investigated with Electron Backscatter Diffraction (EBSD) with high resolution. Samples were annealed for 1 hour at 523 K and 673 K, the temperature region wherein...

  20. The role of Ni in sulfided carbon-supported Ni-Mo hydrodesulfurization catalysts

    NARCIS (Netherlands)

    Bouwens, S.M.A.M.; Barthe-Zahir, N.; Beer, de V.H.J.; Prins, R.

    1991-01-01

    The thiophene hydrodesulfurization activities of Ni and Ni---Mo sulfide catalysts supported on activated carbon were measured at atmospheric pressure and the catalyst structures were studied by means of X-ray photoelectron spectroscopy, dynamic oxygen chemisorption, and chemical sulfur analysis. The

  1. Mechanical properties of NiO/Ni-YSZ composites depending on temperature, porosity and redox cycling

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Kaiser, Andreas; Mogensen, Mogens Bjerg

    2009-01-01

    The Impulse Excitation Technique (IET) was used to determine the elastic modulus and specific damping of different Ni/NiO-YSZ composites suitable for use in solid oxide fuel cells (SOFC). The porosity of the as-sintered samples varied from 9 to 38% and that of the reduced ones from 31 to 52%. For...

  2. Climate Prediction Center - El Niño/La Niña Home

    Science.gov (United States)

    Weather Service NWS logo - Click to go to the NWS home page Climate Prediction Center Site Map News Information CPC Web Team HOME > El Niño/La Niña Forecasts Current U.S. Climate Outlook SST Forecasts Temperature and Anomalies NOAA/ National Weather Service National Centers for Environmental Prediction Climate

  3. Synthesis and magnetic properties of multilayer Ni/Cu and NiFe/Cu ...

    Indian Academy of Sciences (India)

    The diameter of wires can be easily varied by pore size of alumina, ranging ... saturated HgCl2 solution to remove the remaining Al, and then dipped in 5 wt% ... for NiFe alloy it is 1.3 V, that is higher than for Ni/Cu nanowires to diminish Cu.

  4. Effect of solute atoms on swelling in Ni alloys and pure Ni under He + ion irradiation

    Science.gov (United States)

    Wakai, E.; Ezawa, T.; Imamura, J.; Takenaka, T.; Tanabe, T.; Oshima, R.

    2002-12-01

    The effects of solute atoms on microstructural evolutions have been investigated using Ni alloys under 25 keV He + irradiation at 500 °C. The specimens used were pure Ni, Ni-Si, Ni-Co, Ni-Cu, Ni-Mn and Ni-Pd alloys with different volume size factors. The high number densities of dislocation loops about 1.5×10 22 m -3 were formed in the specimens irradiated to 1×10 19 ions/m 2, and they were approximately equivalent, except for Ni-Si. The mean size of loops tended to increase with the volume size factor of solute atoms. In a dose of 4×10 20 ions/m 2, the swelling was changed from 0.2% to 4.5%, depending on the volume size factors. The number densities of bubbles tended to increase with the absolute values of the volume size factor, and the swelling increased with the volume size factors. This suggests that the mobility of helium and vacancy atoms may be influenced by the interaction of solute atoms with them.

  5. Bonding Strength of Ni/Ni3Al Interface with Different Lattice Misfit

    Institute of Scientific and Technical Information of China (English)

    Ping PENG; Caixing ZHENG; Shaochang HAN; Zhaohui JIN; Rui YANG; Zhuangqi HU

    2003-01-01

    The interfacial binding covalent bond density (CBD) and the local environmental total bond order (LTBO) of the Ni/Ni3Alinterface with different lattice misfits (δ) were calculated by using first-principles discrete variation Xα method. It was foundthat

  6. Electrochemical Behaviour of Ni and Ni-PVC Electrodes for the Electroxidation of Ethanol

    International Nuclear Information System (INIS)

    Mohd Syafiq Hamdan; Norazzizi Nordin; Siti Fathrita Mohd Amir; Riyanto; Mohamed Rozali Othman

    2011-01-01

    In this study, two nickel based electrodes were prepared; nickel foil and nickel-polyvinylchloride (Ni-PVC), in order to study their electrochemical behavior using cyclic voltammetry, CV and chronocoulometry, CC. Ni electrode was prepared from Ni metal foil while Ni-PVC electrode was prepared by mixing a weighed portion of Ni powder and PVC in THF solvent, swirled until the suspension was homogeneous and drying the suspension in an oven at 50 degree Celsius for 3 h. The dry sample was then placed in a 1 cm diameter stainless steel mould and pressed at 10 ton/ cm 2 . From CV data, Ni-PVC electrode showed a better electrochemical behavior compared to Ni metal foil electrode. The use of Ni-PVC electrode at higher concentration of supporting electrolyte (1.0 M KOH) was better than at lower concentration of the same supporting electrolyte in electroxidation of ethanol. In addition to acetic acid, the oxidation of ethanol also produced ethyl acetate and acetaldehyde. (author)

  7. Room-temperature ferromagnetism in Dy films doped with Ni

    Energy Technology Data Exchange (ETDEWEB)

    Edelman, I. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation)], E-mail: ise@iph.krasn.ru; Ovchinnikov, S. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation); Siberian Federal University, Av. Svobodnyi 71, Krasnoyarsk 660074 (Russian Federation); Markov, V.; Kosyrev, N.; Seredkin, V.; Khudjakov, A.; Bondarenko, G. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation); Kesler, V. [Institute of Semiconductor Physics, Siberian Division, Russian Academy of Sciences, Av. Akademika Lavrent' eva 13, Novosibirsk 630090 (Russian Federation)

    2008-09-01

    Temperature, magnetic field and spectral dependences of magneto-optical effects (MOEs) in bi-layer films Dy{sub (1-x)}Ni{sub x}-Ni and Dy{sub (1-x)}(NiFe){sub x}-NiFe were investigated, x changes from 0 to 0.06. Peculiar behavior of the MOEs was revealed at temperatures essentially exceeding the Curie temperature of bulk Dy which is explained by the magnetic ordering of the Dy layer containing Ni under the action of two factors: Ni impurities distributed homogeneously over the whole Dy layer and atomic contact of this layer with continues Ni layer. The mechanism of the magnetic ordering is suggested to be associated with the change of the density of states of the alloy Dy{sub (1-x)}Ni{sub x} owing to hybridization with narrow peaks near the Fermi level character for Ni.

  8. Room-temperature ferromagnetism in Dy films doped with Ni

    International Nuclear Information System (INIS)

    Edelman, I.; Ovchinnikov, S.; Markov, V.; Kosyrev, N.; Seredkin, V.; Khudjakov, A.; Bondarenko, G.; Kesler, V.

    2008-01-01

    Temperature, magnetic field and spectral dependences of magneto-optical effects (MOEs) in bi-layer films Dy (1-x) Ni x -Ni and Dy (1-x) (NiFe) x -NiFe were investigated, x changes from 0 to 0.06. Peculiar behavior of the MOEs was revealed at temperatures essentially exceeding the Curie temperature of bulk Dy which is explained by the magnetic ordering of the Dy layer containing Ni under the action of two factors: Ni impurities distributed homogeneously over the whole Dy layer and atomic contact of this layer with continues Ni layer. The mechanism of the magnetic ordering is suggested to be associated with the change of the density of states of the alloy Dy (1-x) Ni x owing to hybridization with narrow peaks near the Fermi level character for Ni

  9. Elementary martensitic transformation processes in Ni-rich NiTi single crystals with Ni4Ti3 precipitates

    International Nuclear Information System (INIS)

    Michutta, J.; Somsen, Ch.; Yawny, A.; Dlouhy, A.; Eggeler, G.

    2006-01-01

    The present study shows that multiple-step martensitic transformations can be observed in aged Ni-rich NiTi single crystals. Ageing of solution-annealed and water-quenched Ni-rich NiTi single crystals results in a homogeneous precipitation of coherent Ni 4 Ti 3 particles. When the interparticle spacing reaches a critical value (order of magnitude: 200 nm), three distinct transformation processes are observed on cooling from the high-temperature phase using differential scanning calorimetry and in situ transmission electron microscopy. The transformation sequence begins with the formation of R-phase starting from all precipitate/matrix interfaces (first step). The transformation continues with the formation of B19' and its subsequent growth along all precipitate/matrix interfaces (second step). Finally, the matrix in between the precipitates transforms to B19' (third step). Elementary transformation mechanisms which account for two- and three-step transformations in a system with small-scale microstructural heterogeneities were identified

  10. Probing the semi-magicity of $^{68}$Ni via the $^{3}$H($^{66}$Ni,$^{68}$Ni)p two-neutron transfer reaction in inverse kinematics

    CERN Multimedia

    Reiter, P; Blazhev, A A; Kruecken, R; Franchoo, S; Mertzimekis, T; Darby, I G; Van de walle, J; Raabe, R; Elseviers, J; Gernhaeuser, R A; Sorlin, O H; Georgiev, G P; Bree, N C F; Habs, D; Chapman, R; Gaudefroy, L; Diriken, J V J; Jenkins, D G; Kroell, T; Axiotis, M; Huyse, M L; Patronis, N

    We propose to perform the two-neutron transfer reaction $^{3}$H($^{66}$Ni, $^{68}$Ni)$p$ using the ISOLDE radioactive ion beam at 2.7 $A$ MeV and the MINIBALL + T-REX setup to characterize the 0$^{+}$ and 2$^{+}$ states in $^{68}$Ni.

  11. Mechanical alloying of the FeNi-Ag system

    International Nuclear Information System (INIS)

    Gonzalez, G.; Ibarra, D.; Ochoa, J.; Villalba, R.; Sagarzazu, A.

    2007-01-01

    The Fe-Ni-Ag system is of particular interest for its potential applications as soft magnetic granular material with small magnetic grains embedded in a non-magnetic metal matrix. Under equilibrium conditions: Fe-Ag and Ni-Ag are immiscible and Fe-Ni shows complete solubility. These materials are particularly important for magnetoresistivity properties. The properties of these alloys are closely related to their microstructure; therefore, a detailed study of the transformations occurring during milling was undertaken using pre-alloyed Fe x Ni 100-x (x = 30, 50 and 70) further milled with different Ag content to give the following alloys compositions (Fe x -Ni 100-x ) 100-y Ag y (y = 5, 20, 60). Consolidation of the mechanically alloyed powders by sintering at 950 o C was performed. Morphological and structural characterization of the sintered powders was carried out by scanning and transmission electron microscopy and X-ray diffraction. Fe 30 Ni 70 and Fe 50 Ni 50 formed ordered FeNi 3 compound. Fe 70 Ni 30 showed the formation of a mixture of γ-(Fe,Ni) and α-Fe(Ni) solid solutions. The mixture of these systems with Ag showed the metal solid solutions surrounded by Ag islands of Fe x Ni y -Ag, There was also evidence of Ag diffusing into the γ-(Fe,Ni). High Ag content (60%) shows formation of islands of FeNi surrounded by Ag. Sintering is always improved with the Ag content

  12. Effect of amount of glycine as fuel in obtaining nanocomposite Ni/NiO

    International Nuclear Information System (INIS)

    Simoes, A.N.; Simoes, V.N.; Neiva, L.S.; Quirino, M.R.; Vieira, D.A.; Gama, L.

    2010-01-01

    This paper proposes to investigate the effect of the amount of glycine in obtaining nanocomposite Ni/NiO synthesized by combustion reaction technique. The amount of glycine used was calculated on the stoichiometric composition of 50% and 100%. Characterizations by X-ray diffraction (XRD), N2 adsorption by the BET method and scanning electron microscopy (SEM) were performed with powder of Ni/NiO result. The analysis of X-ray diffraction showed the presence of crystalline NiO phase in the presence of nickel as a secondary phase, whose amount increased with the amount of glycine. Increasing the concentration of glycine also caused an increase in surface area, which ranged from 1.1 to 1.4 m 2 /g. The micrographs revealed the formation of soft agglomerates with porous appearance and easy dispersions. It can be concluded that the synthesis is effective to obtain nanosized powders. (author)

  13. Neutron enrichment at midrapidity in 58Ni + 58Ni at 52 MeV/u

    International Nuclear Information System (INIS)

    Theriault, D.; Vallee, A.; Gingras, L.; Larochelle, Y.; Roy, R.; April, A.; Beaulieu, L.; Grenier, F.; Lemieux, F.; Moisan, J.; Samri, M.; Saint-Pierre, C.; Turbide, S.; Yennello, S.J.; Martin, E.; Winchester, E.

    2003-01-01

    By combining data from a charged particle 58 Ni + 58 Ni experiment at 52 MeV/u with an 36 Ar + 58 Ni experiment at 50 MeV/u for which free neutrons have been detected, an increase in the neutron to proton ratio of the whole nuclear material at midrapidity has been experimentally observed in the reaction 58 Ni + 58 Ni at 52 MeV/u. The neutron to proton ratio is measured above the initial neutron to proton ratio of the system. Neutron to proton ratio of the quasi-projectile emission is analysed for the same reactions and is seen to decrease below the ratio of the initial system. (authors)

  14. Improvement of thermoelectric properties for half-Heusler TiNiSn by interstitial Ni defects

    International Nuclear Information System (INIS)

    Hazama, Hirofumi; Matsubara, Masato; Asahi, Ryoji; Takeuchi, Tsunehiro

    2011-01-01

    We have synthesized off-stoichiometric Ti-Ni-Sn half-Heusler thermoelectrics in order to investigate the relation between randomly distributed defects and thermoelectric properties. A small change in the composition of Ti-Ni-Sn causes a remarkable change in the thermal conductivity. An excess content of Ni realizes a low thermal conductivity of 2.93 W/mK at room temperature while keeping a high power factor. The low thermal conductivity originates in the defects generated by an excess content of Ni. To investigate the detailed defect structure, we have performed first-principles calculations and compared with x ray photoemission spectroscopy measurement. Based on these analyses, we conclude that the excess Ni atoms randomly occupy the vacant sites in the half-Heusler structure, which play as phonon scattering centers, resulting in significant improvement of the figure of merit without any substitutions of expensive heavy elements, such as Zr and Hf.

  15. Magnetoresistance of nanogranular Ni/NiO controlled by exchange anisotropy

    International Nuclear Information System (INIS)

    Del Bianco, L.; Spizzo, F.; Tamisari, M.; Allia, P.

    2013-01-01

    A link between exchange anisotropy and magnetoresistance has been found to occur in a Ni/NiO sample consisting of Ni nanocrystallites (mean size ∼13 nm, Ni content ∼33 vol%) dispersed in a NiO matrix. This material shows metallic-type electric conduction and isotropic spin-dependent magnetoresistance as well as exchange bias effect. The latter is the outcome of an exchange anisotropy arising from the contact interaction between the Ni phase and the NiO matrix. Combined analysis of magnetization M(H) and magnetoresistance MR(H) loops measured in the 5–250 K temperature range after zero-field-cooling (ZFC) and after field-cooling (FC) from 300 K reveals that the magnetoresistance is influenced by exchange anisotropy, which is triggered by the FC process and can be modified in strength by varying the temperature. Compared to the ZFC case, the exchange anisotropy produces a horizontal shift of the FC MR(H) loop along with a reduction of the MR response associated to the reorientation of the Ni moments. A strict connection between magnetoresistance and remanent magnetization of FC loops on one side and the exchange field on the other, ruled by exchange anisotropy, is indicated. - Highlights: • Nanogranular Ni/NiO with giant magnetoresistance (MR) and exchange bias effect. • Exchange anisotropy produces a shift of the field-cooled MR(H) loop and reduces MR. • MR, remanence of field-cooled loops and exchange field are three correlated quantities. • It is possible to control MR of nanogranular systems through the exchange anisotropy

  16. Ferromagnetic resonance study of sputtered NiFe/V/NiFe heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Alayo, W., E-mail: willian.rodriguez@ufpel.edu.br [Departamento de Física – IFM, Universidade Federal de Pelotas, 96010-900 Rio Grande do Sul (Brazil); Pelegrini, F. [Instituto de Física, Universidade Federal de Goiás, Goiânia, 74001-970 (Brazil); Baggio-Saitovitch, E. [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro, RJ, 22290-180 (Brazil)

    2015-03-01

    The Ni{sub 81}Fe{sub 19}/V/Ni{sub 81}Fe{sub 19} heterostructures has been produced by magnetron sputtering and analyzed by ferromagnetic resonance. Two systems were investigated: the non symmetrical NiFe(50 Å)/V(t)/NiFe(30 Å) trilayers and the symmetrical NiFe(80 Å)/V(t)/NiFe(80 Å) trilayers, with variable ultrathin V thickness t. Ferromagnetic exchange coupling was evidenced for t below 10 Å by the excitation of the optic mode, in the case of the non symmetrical samples, and by the observation of a single resonance mode for the symmetrical trilayers. For larger V thickness, all samples exhibited two modes, which were attributed to the resonance of the individual NiFe layers with different effective magnetizations. The analysis with the equilibrium and resonance conditions provided the exchange coupling constants and effective magnetizations. - Highlights: • We present a study of symmetrical and non symmetrical NiFe/V/NiFe trilayers deposited on Si single crystals by ferromagnetic resonance (FMR) at room temperature. • For the non symmetrical trilayers, the FMR spectra show the optic and acoustic modes for samples with very thin V layer thicknesses, evidencing ferromagnetic exchange coupling, whereas, for larger V thickness, the spectra exhibited two well resolved modes associated to each independent NiFe layer. For the symmetrical trilayers, strong ferromagnetic exchange coupling is evidenced by the observation of a single resonance mode. • The analysis with the equilibrium condition and dispersion relation provides the exchange coupling constants and effective magnetizations.

  17. Hydrogen absorption kinetics and structural properties of Mg85Ni10Ca5 and Mg90Ni10

    International Nuclear Information System (INIS)

    Aoki, Masakazu; Saito, Katsushi; Towata, Shin-ichi

    2005-01-01

    Mg 85 Ni 10 Ca 5 and Mg 90 Ni 10 were prepared by melting mixtures of the elements in mild steel crucibles and pouring them into copper molds. Hydrogen absorption kinetics and structural properties of the alloys were characterized by the volumetric method using a Sievert's apparatus, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The crystallite size of Mg in Mg 85 Ni 10 Ca 5 , which is evaluated by XRD peak broadening, is about 50% smaller than that in Mg 90 Ni 10 . In addition, the nanometer-scale structure composed of Mg, Mg 2 Ni, Mg 2 Ca was observed in Mg 85 Ni 10 Ca 5 . Mg 85 Ni 10 Ca 5 shows better hydrogen absorption kinetics than Mg 90 Ni 10 in the temperature range of room temperature to 573 K. The better absorption kinetics of Mg 85 Ni 10 Ca 5 is mainly attributed to the nanometer-scale structure

  18. Sputtering Yields of Si and Ni from the Ni1-xSix System Studied by Rutherford Backscattering Spectrometry

    Science.gov (United States)

    Kim, Su Chol; Yamaguchi, Satoru; Kataoka, Yoshihide; Iwami, Motohiro; Hiraki, Akio; Satou, Mamoru; Fujimoto, Fuminori

    1982-01-01

    Sputtering yields of Si and Ni from thin layer films of Ni-Si compounds (Ni1-xSix), including the pure materials (Ni and Si), caused by 5 keV Ar+ ion bombardment were investigated using backscattering spectrometry. The sputtering yield for Si from Ni1-xSix increased with increasing Si concentration. However, there is an abrupt decrease in the yield for Si concentrations above NiSi2 to pure Si. This is in clear contrast to the sputtering yield of Ni from Ni1-xSix which increased with increasing Ni concentration monotonously. These results are discussed on the basis of both the difference in the atomic density and the electronic state of the alloy.

  19. Phase Equilibria of the Sn-Ni-Si Ternary System and Interfacial Reactions in Sn-(Cu)/Ni-Si Couples

    Science.gov (United States)

    Fang, Gu; Chen, Chih-chi

    2015-07-01

    Interfacial reactions in Sn/Ni-4.5 wt.%Si and Sn-Cu/Ni-4.5 wt.%Si couples at 250°C, and Sn-Ni-Si ternary phase equilibria at 250°C were investigated in this study. Ni-Si alloys, which are nonmagnetic, can be regarded as a diffusion barrier layer material in flip chip packaging. Solder/Ni-4.5 wt.%Si interfacial reactions are crucial to the reliability of soldered joints. Phase equilibria information is essential for development of solder/Ni-Si materials. No ternary compound is present in the Sn-Ni-Si ternary system at 250°C. Extended solubility of Si in the phases Ni3Sn2 and Ni3Sn is 3.8 and 6.1 at.%, respectively. As more Si dissolves in these phases their lattice constants decrease. No noticeable ternary solubility is observed for the other intermetallics. Interfacial reactions in solder/Ni-4.5 wt.%Si are similar to those for solder/Ni. Si does not alter the reaction phases. No Si solubility in the reaction phases was detected, although rates of growth of the reaction phases were reduced. Because the alloy Ni-4.5 wt.%Si reacts more slowly with solders than pure Ni, the Ni-4.5 wt.%Si alloy could be a potential new diffusion barrier layer material for flip chip packaging.

  20. Report for fiscal 1998 on Simple Operation Type CAD/CAM System Development through International Cooperation. Report on the achievements of counterparts overseas; 1998 nendo 'kan'i sosagata denshi sekkei seian shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Kaigai counter part seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Concerning the subject matter, achievements of China, Indonesia, Malaysia, Singapore, and Thailand are reported. In China, a technical data transfer process is under development, designed to serve between CAD (computer-aided design)/CAM (computer-aided manufacturing) packages of different file formats. In Indonesia, WG1 activities are being conducted with the assistance of Toyota Motor Corporation, and WG3 activities with the assistance of Wacoal Corporation, Japan. In Malaysia, designing, development, and tests are under way for prototype systems of an electronic catalog, direct link to CAD/CAM, transfer and sharing of electronic manufacturing data, etc., all to be completed by March 1999. In Singapore, an electronic parts library is compiled, and a verification test is conducted involving response time, download time, etc. In Thailand, development is under way of an engineering browser, automobile industry-oriented WEB-based information center, etc. (NEDO)

  1. Report for fiscal 1998 on Simple Operation Type CAD/CAM System Development through International Cooperation. Report on the achievements of counterparts overseas; 1998 nendo 'kan'i sosagata denshi sekkei seian shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Kaigai counter part seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Concerning the subject matter, achievements of China, Indonesia, Malaysia, Singapore, and Thailand are reported. In China, a technical data transfer process is under development, designed to serve between CAD (computer-aided design)/CAM (computer-aided manufacturing) packages of different file formats. In Indonesia, WG1 activities are being conducted with the assistance of Toyota Motor Corporation, and WG3 activities with the assistance of Wacoal Corporation, Japan. In Malaysia, designing, development, and tests are under way for prototype systems of an electronic catalog, direct link to CAD/CAM, transfer and sharing of electronic manufacturing data, etc., all to be completed by March 1999. In Singapore, an electronic parts library is compiled, and a verification test is conducted involving response time, download time, etc. In Thailand, development is under way of an engineering browser, automobile industry-oriented WEB-based information center, etc. (NEDO)

  2. Fiscal 1997 report on the results of the research on the development of high-performance industrial furnaces. R and D of high-performance industrial furnaces, etc; 1997 nendo seika hokokusho (koseino kogyoro no kaihatsu ni kansuru kenkyu seika hokokusho). Koseino kogyoro nado ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    A R and D was conducted for the purpose of developing remarkable energy conservation/CO2 reduction technologies. In fiscal 1997, the five working groups about the following were formed to have animated discussions: the basic research, heating furnace, heat treatment furnace, melting furnace, and tubular heating furnace. The research subjects are the pursuit/deepening of the base study on flame structures in high temperature air combustion, critical heat recovery of the system in high temperature air combustion, examination of the basic common technology on the ultimate optimization of the material heat transfer, construction of general-purpose experimental database, setting-up of design standards for general-purpose high-performance industrial furnaces, presentation of examples of the actual trial design based on the design standards and feasibility study of the practical application, preparatory support of the field test project on high-performance industrial furnaces for commercialization/diffusion/spread, etc. Further, how to arrange the developmental results was studied to make the results of the project useful for study of the prompt commercialization. 442 refs., 1444 figs., 311 tabs.

  3. Ni/boride interfaces and environmental embrittlement in Ni-based superalloys: A first-principles study

    International Nuclear Information System (INIS)

    Sanyal, Suchismita; Waghmare, Umesh V.; Hanlon, Timothy; Hall, Ernest L.

    2011-01-01

    Highlights: ► Fracture strengths of Ni/boride interfaces through first-principles calculations. ► Fracture strengths of Ni/boride interfaces are higher than Ni/Ni 3 Al and NiΣ5 grain boundaries. ► Ni/boride interfaces have higher resistance to O-embrittlement than Ni/Ni 3 Al and NiΣ5 grain boundaries. ► CrMo-borides are more effective than Cr-borides in resisting O-embrittlement. ► Electronegativity differences between alloying elements correlate with fracture strengths. - Abstract: Motivated by the vital role played by boride precipitates in Ni-based superalloys in improving mechanical properties such as creep rupture strength, fatigue crack growth rates and improved resistance towards environmental embrittlement , we estimate fracture strength of Ni/boride interfaces through determination of their work of separation using first-principles simulations. We find that the fracture strength of Ni/boride interfaces is higher than that of other commonly occurring interfaces in Ni-alloys, such as Ni Σ-5 grain boundaries and coherent Ni/Ni 3 Al interfaces, and is less susceptible to oxygen-induced embrittlement. Our calculations show how the presence of Mo in Ni/M 5 B 3 (M = Cr, Mo) interfaces leads to additional reduction in oxygen-induced embrittlement. Through Electron-Localization-Function based analyses, we identify the electronic origins of effects of alloying elements on fracture strengths of these interfaces and observe that chemical interactions stemming from electronegativity differences between different atomic species are responsible for the trends in calculated strengths. Our findings should be useful towards designing Ni-based alloys with higher interfacial strengths and reduced oxygen-induced embrittlement.

  4. Nickel distribution and isotopic fractionation in a Brazilian lateritic regolith: Coupling Ni isotopes and Ni K-edge XANES

    Science.gov (United States)

    Ratié, G.; Garnier, J.; Calmels, D.; Vantelon, D.; Guimarães, E.; Monvoisin, G.; Nouet, J.; Ponzevera, E.; Quantin, C.

    2018-06-01

    Ultramafic (UM) rocks are known to be nickel (Ni) rich and to weather quickly, which makes them a good candidate to look at the Ni isotope systematics during weathering processes at the Earth's surface. The present study aims at identifying the Ni solid speciation and discussing the weathering processes that produce Ni isotope fractionation in two deep laterite profiles under tropical conditions (Barro Alto, Goiás State, Brazil). While phyllosilicates and to a lower extent goethite are the main Ni-bearing phases in the saprolitic part of the profile, iron (Fe) oxides dominate the Ni budget in the lateritic unit. Nickel isotopic composition (δ60Ni values) has been measured in each unit of the regolith, i.e., rock, saprock, saprolite and laterite (n = 52). δ60Ni varies widely within the two laterite profiles, from -0.10 ± 0.05‰ to 1.43 ± 0.05‰, showing that significant Ni isotope fractionation occurs during the weathering of UM rocks. Overall, our results show that during weathering, the solid phase is depleted in heavy Ni isotopes due to the preferential sorption and incorporation of light Ni isotopes into Fe oxides; the same mechanisms likely apply to the incorporation of Ni into phyllosilicates (type 2:1). However, an isotopically heavy Ni pool is observed in the solid phase at the bottom of the saprolitic unit. This feature can be explained by two hypotheses that are not mutually exclusive: (i) a depletion in light Ni isotopes during the first stage of weathering due to the preferential dissolution of light Ni-containing minerals, and (ii) the sorption or incorporation of isotopically heavy Ni carried by percolating waters (groundwater samples have δ60Ni of 2.20 and 2.27‰), that were enriched in heavy Ni isotopes due to successive weathering processes in the overlying soil and laterite units.

  5. The acceleration intermediate phase (NiS and Ni3S2) evolution by nanocrystallization in Li/NiS2 thermal batteries with high specific capacity

    Science.gov (United States)

    Jin, Chuanyu; Zhou, Lingping; Fu, Licai; Zhu, Jiajun; Li, Deyi; Yang, Wulin

    2017-06-01

    The intermediate phase of NiS2 is thought to be a bottleneck currently to improve the overall performance of Li/NiS2 thermal batteries because of its low conductivity and close formation enthalpy between NiS2 and the intermediate phase (NiS, Ni3S2, etc). For improving the discharge performances of Li/NiS2 thermal batteries, the nano NiS2 with an average size of 85 ± 5 nm is designated as a cathode material. The electrochemical measurements show that the specific capacity of nano NiS2 cathode is higher than micro NiS2. The nano NiS2 cathode exhibits excellent electrochemical performances with high specific capacities of 794 and 654 mAh g-1 at current density of 0.1 and 0.5 A cm-2 under a cut-off voltage of 0.5 V, respectively. These results show that the rapid intermediate phase evolution from the nanocrystallization can obviously enhance use efficiency of NiS2 and improve discharge performances of thermal batteries.

  6. Room temperature isotherms for Mo and Ni

    International Nuclear Information System (INIS)

    Masse, J.L.

    1986-11-01

    Isotherms at room temperature for Mo and Ni are proposed. They are of three types: BIRCH, KEANE and BORN-MIE. The adjustable constants appearing in these isotherms have been determined from experimental quantities at zero pressure. An evaluation of the limit of (δB T /δP) T as P #-> # ∞, where B T is the isothermal bulk modulus, has been also used. These three isotherms obtained for Mo and Ni are compared with isotherms derived from shock-wave data according to the PRIETO's model. There is a good agreement between these and these derived from shock-wave data. The three isotherms proposed for Mo and Ni can be considered as valid until pressures of several B To , where B To is the bulk modulus B T at P = o [fr

  7. Advances in developing TiNi nanoparticles

    International Nuclear Information System (INIS)

    Castro, A. Torres; Cuellar, E. Lopez; Mendez, U. Ortiz; Yacaman, M. Jose

    2006-01-01

    The elaboration of nanoparticles has become a field of great interest for many scientists. Nanoparticles possess different properties than those ones shown in bulk materials. Shape memory alloys have the exceptional ability to recuperate its original shape by simple heating after being 'plastically' deformed. When this process is originated, important changes in properties, as mechanical and electrical, are developed in bulk material. If there is possible to obtain nanoparticles with shape memory effects, these nanoparticles could be used in the elaboration of nanofluids with the ability to change their electrical and thermal conductivity with temperature changes, i.e., smart nanofluids. In this work, some recent results and discussion of TiNi nanoparticles obtained by ion beam milling directly from a TiNi wire with shape memory are presented. The nanoparticles obtained by this process are about 2 nm of diameter with a composition of Ti-41.0 at.% Ni. Synthesized nanoparticles elaborated by this method have an ordered structure

  8. Cutting NiTi with Femtosecond Laser

    Directory of Open Access Journals (Sweden)

    L. Quintino

    2013-01-01

    Full Text Available Superelastic shape memory alloys are difficult to machine by thermal processes due to the facility for Ti oxidation and by mechanical processes due to their superelastic behavior. In this study, femtosecond lasers were tested to analyze the potential for machining NiTi since femtosecond lasers allow nonthermal processing of materials by ablation. The effect of processing parameters on machining depth was studied, and material removal rates were computed. Surfaces produced were analyzed under SEM which shows a resolidified thin layer with minimal heat affected zones. However, for high cutting speeds, that is, for short interaction times, this layer was not observed. A depletion of Ni was seen which may be beneficial in biomedical applications since Ni is known to produce human tissue reactions in biophysical environments.

  9. La niña proletaria

    Directory of Open Access Journals (Sweden)

    Cartabia, Sabrina A.

    2011-12-01

    Full Text Available El presente trabajo se propone trazar un paralelo entre el cuento de Osvaldo Lamborghini “El niño proletario”, el cual, según la autora del ensayo, introduce al lector en la lucha de clases y el sometimiento de los/as proletarios/as, que sufren las mujeres, en particular a través de la violencia sexual. De esa forma la autora se pregunta si el poder que ciertas clases detentan sobre otras no influye también sobre el sometimiento de la mujer. El ensayo analiza además cómo la violencia sexual es una herramienta que constituye la base de la desigualdad, el sometimiento y la degradación de la mujer, al igual que constituye una herramienta de opresión de otros grupos vulnerables como los niños y niñas.

  10. Effects of phase transformation and interdiffusion on the exchange bias of NiFe/NiMn

    International Nuclear Information System (INIS)

    Lai, Chih-Huang; Lien, W. C.; Chen, F. R.; Kai, J. J.; Mao, S.

    2001-01-01

    The correlation between the exchange field of NiFe/NiMn and the phase transformation of NiMn was investigated. Transmission electron microscopy (TEM) dark-field images, contributed by the order phase of NiMn, were used to identify the location and volume fraction of the order phase. TEM selected area diffraction patterns showed the (110) superlattice diffraction rings of NiMn, verifying the existence of the order phase in the annealed samples. The order volume fraction can be calculated by the dark field image contributed by the (110) diffraction. The exchange field increased almost linearly with increasing order volume fraction. Energy dispersive x-ray spectroscopy attached to TEM indicated that Mn diffused into NiFe for annealing at 280 degreeC, leading to a larger coercivity and small coercivity squareness. Part of the NiMn still maintains the paramagnetic phase even after annealing at 280 degreeC. [copyright] 2001 American Institute of Physics

  11. Ni3Si2 nanowires grown in situ on Ni foam for high-performance supercapacitors

    Science.gov (United States)

    Jiang, Yizhe; Li, Zhihui; Li, Beibei; Zhang, Jinying; Niu, Chunming

    2016-07-01

    Ni3Si2 nanowires and nanoawls have grown in situ on the surface of Ni foams by a controlled low pressure chemical vapor deposition process. Structural characterization shows that the individual Ni3Si2 nanowire is single crystal covered with a thin layer (1-2 nm) of SiO2 with a diameter of ∼20-30 nm and length of ten's micrometers. Individual nanoawl with a circular cone shape is polycrystalline. Both Ni3Si2 nanowire and nanoawl samples are evaluated as potential electrode materials for supercapacitors. The nanowire electrode delivers a very high specific capacitance and excellent rate capability. A specific capacitance of 760 F g-1 is measured at current density of 0.5 A g-1, which decreases to 518 F g-1 when the current density increases to 10 A g-1. The capacitance is dominated by pseudocapacitance with a mechanism similar to that of NiO or Ni(OH)2 widely studied in the literature. An asymmetric supercapacitor fabricated by pairing Ni3Si2 nanowire electrode with an activated carbon electrode exhibits energy densities of 17.5 Wh kg-1 and 8.8 Wh kg-1 at power densites of 301 W kg-1 and 3000 W kg-1.

  12. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    Energy Technology Data Exchange (ETDEWEB)

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace, E-mail: jglin@ntu.edu.tw

    2017-02-15

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  13. Radiation damage buildup and dislocation evolution in Ni and equiatomic multicomponent Ni-based alloys

    Energy Technology Data Exchange (ETDEWEB)

    Levo, E. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Granberg, F., E-mail: fredric.granberg@helsinki.fi [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Fridlund, C.; Nordlund, K. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Djurabekova, F. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Helsinki Institute of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland)

    2017-07-15

    Single-phase multicomponent alloys of equal atomic concentrations (“equiatomic”) have proven to exhibit promising mechanical and corrosion resistance properties, that are sought after in materials intended for use in hazardous environments like next-generation nuclear reactors. In this article, we investigate the damage production and dislocation mobility by simulating irradiation of elemental Ni and the alloys NiCo, NiCoCr, NiCoFe and NiFe, to assess the effect of elemental composition. We compare the defect production and the evolution of dislocation networks in the simulation cells of two different sizes, for all five studied materials. We find that the trends in defect evolution are in good agreement between the different cell sizes. The damage is generally reduced with increased alloy complexity, and the dislocation evolution is specific to each material, depending on its complexity. We show that increasing complexity of the alloys does not always lead to decreased susceptibility to damage accumulation under irradiation. We show that, for instance, the NiCo alloy behaves very similarly to Ni, while presence of Fe or Cr in the alloy even as a third component reduces the saturated level of damage substantially. Moreover, we linked the defect evolution with the dislocation transformations in the alloys. Sudden drops in defect number and large defect fluctuations from the continuous irradiation can be explained from the dislocation activity.

  14. Corrosion Resistance Of Electroless Ni-P/Cu/Ni-P Multilayer Coatings

    Directory of Open Access Journals (Sweden)

    Zhao G.L.

    2015-06-01

    Full Text Available Ni-P/Cu/Ni-P multilayer coatings were prepared by deposition of Cu layer between two Ni–P layers. The Cu layer was deposited by metal displacement reaction between Cu2+ and Fe atoms. Corrosion behavior of single-layer Ni-P coatings, double-layer Ni-P/Cu coatings, and three-layer Ni-P/Cu/Ni-P coatings were investigated by electrochemical tests in 3.5% NaCl solution. The three-layer coatings exhibited more positive Ecorr and decreased Icorr compared with conventional single-layer Ni-P coatings, which indicated an improved corrosion resistance. The polarization curves of the three-layer coatings were characterized by two passive regions. The improved corrosion resistance was not only attributed to the function of the blocked pores of Cu. The Cu interlayer also acted as a sacrificial layer instead of a barrier in the coatings, which altered the corrosion mechanism and further improved the corrosion resistance of the coatings.

  15. PRECIPITATION HARDENING IN B2-ORDERED NiAl BY Ni2AlTiCOMPOUND

    Institute of Scientific and Technical Information of China (English)

    W.H. Tian; K. Ohishi; M. Nemoto

    2001-01-01

    Microstructural variations and correlated hardness changes in B2-ordered NiAl containing fine precipitation of Ni2AlTi have been investigated by means of transmission electron microscopy (TEM) and hardness tests. The amount of age hardening is not large as compared to the large microstructural variations during aging. TEM observations have revealed that the L21-type Ni2AlTi precipitates keep a lattice coherency with the NiAl matrix at the beginning of aging. By longer periods of aging Ni2AlTi precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. The temperature dependence of the yield strength of precipitate-containing B2-ordered NiAl was investigated by compression tests over the temperature range of 873-1273K. The fine precipitation of Ni2AlTi was found to enhance greatly the yield strength and the high-temperature strength is comparison with that of superalloy Mar-M200.``

  16. Development of small-scale electroplating system for Ni-63 electroplating onto Ni foil

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Choi, Sang Mu; Son, Kwang Jae; Hong, Jintae

    2016-01-01

    Betavoltaic battery is a device that converts the decay energy of beta-emitting radioisotopes into electric energy. Ni-63 is pure betaemitter with a low energy spectrum and significantly long half-life of 100.1 years and thus is widely used as the power source of betavoltaic battery. There are several methods for the formation of a Ni deposit onto a semiconductor such as electroplating, electroless plating, and chemical vapor deposition. In this study, small-scale radioisotope electroplating system was designed and fabricated to perform electroplating with a small amount of plating buffer and minimum exposure of radioactive materials. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery. In this study, an electroplating system for small-scale Ni electroplating was designed and manufactured. The process for the fabrication of a Ni-63 foil as the energy source of a betavoltaic battery was developed using the minimum concentration of Ni. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery

  17. Development of small-scale electroplating system for Ni-63 electroplating onto Ni foil

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Joo; Choi, Sang Mu; Son, Kwang Jae; Hong, Jintae [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    Betavoltaic battery is a device that converts the decay energy of beta-emitting radioisotopes into electric energy. Ni-63 is pure betaemitter with a low energy spectrum and significantly long half-life of 100.1 years and thus is widely used as the power source of betavoltaic battery. There are several methods for the formation of a Ni deposit onto a semiconductor such as electroplating, electroless plating, and chemical vapor deposition. In this study, small-scale radioisotope electroplating system was designed and fabricated to perform electroplating with a small amount of plating buffer and minimum exposure of radioactive materials. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery. In this study, an electroplating system for small-scale Ni electroplating was designed and manufactured. The process for the fabrication of a Ni-63 foil as the energy source of a betavoltaic battery was developed using the minimum concentration of Ni. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery.

  18. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    International Nuclear Information System (INIS)

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace

    2017-01-01

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  19. Tipos especiales de niños

    Directory of Open Access Journals (Sweden)

    Mercedes Rodrigo Bellido

    1946-09-01

    Full Text Available En las tres últimas lecciones han sido expuestas algunas consideraciones referentes a niños y adolescentes desde el nacimiento hasta el dintel de la juventud. En todas ellas hemos procurado poner de relieve la necesidad de individualizar el conocimiento de cada niño para obtener mejores resultados en su adaptación a su futura vida de adultos, En todas ellas  nos hemos referido al llamado niño normal. Nos corresponde en la lección de hoy ocuparnos can la superficialidad característica de estas charlas tipo-muestrario, de otras categorías de niños muy dignos de interés.. quienes unas por exceso, otros por defecto, otros por dificultades de adaptación por diferentes causas, se desvían de la línea media de la normalidad. Consideramos que no está fuera del lugar, aquí, el tema de los niños excepcionales y por el contrario que es necesario intensificar el estudio de los trastornos de la vida mental y emocional de los niños en la preparación de los estudiantes de Medicina. Y no es nuestra solo esta opinión; no hace mucho tiempo en la Medical School de Ia Universidad de Minnessota hemos sabido que se ha hecho un intento de considerar y evaluar factores emocionales ambientales sobre las mismas bases que los descubrimientos fisiológicos.

  20. Ni Foam-Ni3 S2 @Ni(OH)2 -Graphene Sandwich Structure Electrode Materials: Facile Synthesis and High Supercapacitor Performance.

    Science.gov (United States)

    Wang, Xiaobing; Hu, Jiangjiang; Su, Yichang; Hao, Jin; Liu, Fanggang; Han, Shuang; An, Jian; Lian, Jianshe

    2017-03-23

    A novel Ni foam-Ni 3 S 2 @Ni(OH) 2 -graphene sandwich-structured electrode (NF-NN-G) with high areal mass loading (8.33 mg cm -2 ) has been developed by sulfidation and hydrolysis reactions. The conductivity of Ni 3 S 2 and Ni(OH) 2 were both improved. The upper layer of Ni(OH) 2 , covered with a thin graphene film, is formed in situ from the surface of the lower layer of Ni 3 S 2 , whereas the Ni 3 S 2 grown on Ni foam substrate mainly acts as a rough support bridging the Ni(OH) 2 and Ni foam. The graphene stabilized the Ni(OH) 2 and the electrochemical properties were effectively enhanced. The as-synthesized NF-NN-G-5mg electrode shows a high specific capacitance (2258 F g -1 at 1 A g -1 or 18.81 F cm -2 at 8.33 mA cm -2 ) and an outstanding rate property (1010 F g -1 at 20 Ag -1 or 8.413 F cm -2 at 166.6 mA cm -2 ). This result is around double the capacitance achieved in previous research on Ni 3 S 2 @Ni(OH) 2 /3DGN composites (3DGN=three-dimensional graphene network). In addition, the as-fabricated NF-NN-G-5mg composite electrode has an excellent cycle life with no capacitance loss after 3000 cycles, indicating a potential application as an efficient electrode. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Salud mental del niño

    OpenAIRE

    Ospina de González, Bernarda

    1987-01-01

    Es ya reconocida por todos las importancia de los primeros años de vida en la estructutración de la personalidad y, por consiguiente, en la salud mental del niño. En este artículo se hace una síntesis de los diferentes aspectos del desarrollo de la personalidad infanltil que seben ser conocidos por el personal de salud para estar en condiciones de brindar una atención integral a la madre y al niño. Con igual propósito se señalan algunos patrones de tipo psicosocial que influyen en la estabili...

  2. Magnetic anisotropy of Ni/Cr multilayers

    International Nuclear Information System (INIS)

    Kang, S.; Xia, H.

    1997-01-01

    The magnetic anisotropy of Ni/Cr multilayers has been investigated by using vibrating sample magnetometer (VSM) and ferromagnetic resonance techniques (FMR). The FMR spectra are obtained as a function of the orientation of the applied magnetic field from in-plane to out-of-plane. The results are fitted theoretically to determine the magnetic anisotropy. From VSM and FMR, a positive value for Ni/Cr interface anisotropy is obtained, which favours a perpendicular easy axis. The possible mechanism for the perpendicular anisotropy has been discussed and it may be attributed to the magnetostriction, caused by intrinsic stress due to lattice mismatch. (orig.). With 005 figs., 001 tabs

  3. Ionizing Radiation Effects in Ni Nanotubes

    Science.gov (United States)

    Shlimas, D.; Kozlovsky, A.; Shumskaya, A.; Kaniukov, E.; Ibragimova, M.; Zdorovets, M.; Kadyrzhanov, K.

    2017-01-01

    Polycrystalline nickel nanotubes with diameter of 380 nm and wall thickness 95 nm were synthesized by electrochemical method using PET track-etched membranes with thickness of 12 μm. A comprehensive study of the structural, morphological and electrical characteristics of Ni nanotubes irradiated with C+13 ions with energy 1.75 MeV/nucleon and fluence ranging from 109 to 5 × 1011 cm-2 was carried out. The ability of modification of structural parameters such as lattice parameter and the average size of crystallites and conductivity of Ni nanotubes by irradiation was shown.

  4. Optimization of process parameters for synthesis of silica–Ni ...

    Indian Academy of Sciences (India)

    Optimization of process parameters for synthesis of silica–Ni nanocomposite by design of experiment ... Sol–gel; Ni; design of experiments; nanocomposites. ... Kolkata 700 032, India; Rustech Products Pvt. Ltd., Kolkata 700 045, India ...

  5. Ni hollow spheres as catalysts for methanol and ethanol electrooxidation

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Changwei [Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 (China); School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Hu, Yonghong; Rong, Jianhua; Liu, Yingliang [Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 (China); Jiang, San Ping [School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore)

    2007-08-15

    In this paper, we successfully synthesized Ni hollow spheres consisting of needle-like nickel particles by using silica spheres as template with gold nanoparticles seeding method. The Ni hollow spheres are applied to methanol and ethanol electrooxidation in alkaline media. The results show that the Ni hollow spheres give a very high activity for alcohol electrooxidation at a very low nickel loading of 0.10 mg cm{sup -2}. The current on Ni hollow spheres is much higher than that on Ni particles. The onset potential and peak potential on Ni hollow spheres are more negative than that on Ni particles for methanol and ethanol electrooxidation. The Ni hollow spheres may be of great potential in alcohol sensor and direct alcohol fuel cells. (author)

  6. Separation and preparation of "6"2Ni isotope

    International Nuclear Information System (INIS)

    Ren Xiuyan; Mi Yajing; Zeng Ziqiang; Li Gongliang; Tu Rui

    2014-01-01

    Micro nuclear battery is the perfect power of space craft equipment. "6"3Ni is the core operation material of the "6"3Ni battery. It can produce radioisotope "6"3Ni while high abundance "6"2Ni is irradiated in the reactor. In order to meet the requirements of the abundance and the purity, research of the separation for "6"2Ni isotope was developed. The magnetic field and beam transmission status were simulated. The improvement designs of the ion source and the collector pocket were carried out. The process flow of high abundance "6"2Ni using electromagnetic separation method was established. The experiment of "6"2Ni isotope was developed by using electromagnetism isotope separator. The results show that the enrichment of "6"2Ni isotope is more than 90%. (authors)

  7. X-ray fluorescence analysis of Fe - Ni - Mo systems

    International Nuclear Information System (INIS)

    Belyaev, E.E.; Ershov, A.V.; Mashin, A.I.; Mashin, N.I.; Rudnevskij, N.K.

    1998-01-01

    Procedures for the X-ray fluorescence determination of the composition and thickness of Fe - Ni - Mo thin films and the concentration of elements in thick films of the Fe - Ni - Mo alloy are developed [ru

  8. Structure characterization of Ni/NiO and Ti/TiO2 interfaces

    International Nuclear Information System (INIS)

    Lamine, Brahim

    1983-01-01

    This research thesis reports the structure characterization of Ni-NiO and Ti-TiO 2 interfaces through an in-situ investigation of thin blade oxidation, of oxide germination and growth, and through a determination of mutual metal/oxide orientation relationships. Thin films of TiO 2 have also been characterized and the study of the influence of vacuum annealing on TiO 2 layer structure and morphology has been attempted. The examination of metal-oxide interface reveals a duplex structure of NiO and TiO 2 layers, and a preferential grain boundary oxidation of the underlying metal [fr

  9. Structure of Ni-rich Ni--Cr--B--Si coating alloys

    International Nuclear Information System (INIS)

    Knotek, O.; Lugscheider, E.; Reimann, H.

    1975-01-01

    The structures of quaternary, nickel-rich Ni--Cr--B--Si alloys were analyzed at a constant boron content of 10 at. percent and a temperature of 850 0 C. The composition range for silicide formation was determined. In these quaternary alloys, known binary nickel silicides, nickel and chromium borides, and the ternary silico-boride Ni 6 Si 2 B were confirmed. A new composition for the W 5 Si 3 -type phase in the Ni--B--Si system was proposed. (U.S.)

  10. The study of quasi-projectiles produced in Ni+Ni and Ni+Au collisions: excitation energy and spin

    International Nuclear Information System (INIS)

    Buta, A.

    2003-02-01

    During the collision between the projectile and the target nuclei in the intermediate energy regime (E < 100 MeV/nucleon) two excited nuclei are mainly observed in the exit channel, the quasi projectile (QP) and the quasi target. They disintegrate by particle emission. However, this binary picture is perturbed by the emission of particles and light fragments with velocities intermediate between the projectile velocity and the target one, all along the interaction (midrapidity component). This work aim to determine the excitation energy and the intrinsic angular momentum (or spin) of quasi-projectiles produced in the Ni+Ni and Ni+Au collisions at 52 and 90 MeV/nucleon. The excitation energy is deduced from the kinematical characteristics of particles emitted by the quasi-projectile. They have to be separated from midrapidity particles. Three different scenarios have been used for this purpose. The spin of the quasi-projectile has been extracted from the experimental data by mean of proton and alpha particles multiplicities emitted by the QP in the Ni+Au at 52 MeV/nucleon reaction. The results have been compared to the predictions of a theoretical model based on nucleon transfers. Their evolution is qualitatively reproduced as a function of the violence of the collision. (author)

  11. Low temperature gaseous nitriding of Ni based superalloys

    DEFF Research Database (Denmark)

    Eliasen, K. M.; Christiansen, Thomas Lundin; Somers, Marcel A. J.

    2010-01-01

    In the present work the nitriding response of selected Ni based superalloys at low temperatures is addressed. The alloys investigated are nimonic series nos. 80, 90, 95 and 100 and nichrome (Ni/Cr......In the present work the nitriding response of selected Ni based superalloys at low temperatures is addressed. The alloys investigated are nimonic series nos. 80, 90, 95 and 100 and nichrome (Ni/Cr...

  12. Giant magnetocaloric effect in isostructural MnNiGe-CoNiGe system by establishing a Curie-temperature window

    KAUST Repository

    Liu, E. K.; Zhang, H. G.; Xu, G. Z.; Zhang, X. M.; Ma, R. S.; Wang, W. H.; Chen, J. L.; Zhang, H. W.; Wu, G. H.; Feng, L.; Zhang, Xixiang

    2013-01-01

    An effective scheme of isostructural alloying was applied to establish a Curie-temperature window in isostructural MnNiGe-CoNiGe system. With the simultaneous accomplishment of decreasing structural-transition temperature and converting

  13. The large magnetoelectric effect in Ni-lead zirconium titanate-Ni trilayers derived by electroless deposition

    International Nuclear Information System (INIS)

    Bi, K; Wang, Y G; Wu, W; Pan, D A

    2010-01-01

    Magnetoelectric (ME) Ni-lead zirconium titanate-Ni trilayers with neither electrodes nor bonding layers have been derived by electroless deposition. The structure and magnetic properties of the electroless deposited Ni layers with different pH values are characterized by x-ray diffraction and vibrating sample magnetometer. The influence of the bias magnetic field and the magnetic field frequency (f) on ME coupling is discussed. It is seen that α E,31 depends strongly on H dc and f. The value of the ME coefficient increases as the thickness of the Ni layer and the pH of the bath increase. A maximum of the ME voltage coefficient α E,31 = 5.77 V cm -1 Oe -1 at resonance frequency with a deposited Ni layer thickness t Ni = 302 μm is obtained. The large ME coefficient makes these Ni-PZT-Ni trilayers suitable for applications in sensors, actuators and transducers. (fast track communication)

  14. Development of the dentistry alloy Ni-Cr-Nb; Desenvolvimento de ligas odontologicas Ni-Cr-Nb

    Energy Technology Data Exchange (ETDEWEB)

    Souza, M.A.; Ramos, A.S.; Hashimoto, T.M., E-mail: mari_sou@hotmail.co [UNESP/FEG, Guaratingueta, SP (Brazil). Fac. de Engenharia. Dept. de Materiais e Tecnologia

    2010-07-01

    This work reports on the structural characterization of Ni-Cr-Mo and Ni-Cr-Nb alloys produced by arc melting. Samples were characterized by means of optical microscopy, X-ray diffraction, scanning electron microscopy, and EDS analysis. Results indicated that the arc melting process was efficient to produce homogeneous structures in Ni-Cr-Mo and Ni-Cr-Nb alloys. The nickel dissolved large amounts of Cr, Mo and Nb, which was detected by EDS analysis and X-ray diffraction. The alloy containing molybdenum indicated the presence of structure based on Ni{sub SS}, while that the alloys containing niobium presented primary grains of Ni{sub SS} and precipitates formed by the simultaneous transformation of the Ni and Ni{sub 3}Nb phases. (author)

  15. Microstructure and electrochemical characterization of laser melt-deposited Ti2Ni3Si/NiTi intermetallic alloys

    International Nuclear Information System (INIS)

    Dong Lixin; Wang Huaming

    2008-01-01

    Corrosion and wear resistant Ti 2 Ni 3 Si/NiTi intermetallic alloys with Ti 2 Ni 3 Si as the reinforcing phase and the ductile NiTi as the toughening phase were designed and fabricated by the laser melt-deposition manufacturing process. Electrochemical behavior of the alloys was investigated using potentiodynamic polarization testing and electrochemical impedance spectroscopy in an NaOH solution. The results showed that the alloys have outstanding corrosion resistance due to the formation of a protective passive surface film of Ni(OH) 2 as well as the high chemical stability and strong inter-atomic bonds inherent to Ti 2 Ni 3 Si and NiTi intermetallics. The Ti 2 Ni 3 Si content has a significant influence on the microstructure of the alloys but only a slight effect on electrochemical corrosion properties

  16. Homotopic mapping solution of an oscillator for the El Niño/La Niña-southern oscillation

    International Nuclear Information System (INIS)

    Xian-Chun, Zhou; Yi-Hua, Lin; Wan-Tao, Lin; Jia-Qi, Mo

    2009-01-01

    This paper considers a class of oscillator for the El Niño/La Niña-southern oscillation (ENSO) model. By using the homotopic mapping method, it obtains approximations of the solution for the ENSO model. (general)

  17. Electrochemical reduction of NiO in a composite electrode

    DEFF Research Database (Denmark)

    Hu, Qiang; Jacobsen, Torben; Hansen, Karin Vels

    2013-01-01

    a lower overpotential. Microstructures of NiO with different reduction degrees are shown. Electrochemical impedance spectroscopy is carried out during the reduction process. Electrochemical reduction of NiO may need an induction period. When NiO is reduced at a constant voltage the current initially...

  18. Morphological and compositional engineering of Ni/carbon ...

    Indian Academy of Sciences (India)

    Ni/multi-walled carbon nanotubes (MWCNTs) composite films were deposited on the glassy carbon electrode (GCE) by a Ni plating bath containing homogeneously dispersed MWCNTs using polyvinylpyrrolidone (PVP) as dispersion additive. Incorporation of MWCNTs into Ni matrix was greatly enhanced by the application ...

  19. CLASSICAL AREAS OF PHENOMENOLOGY: First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    Science.gov (United States)

    Wang, Yun-Jiang; Wang, Chong-Yu

    2009-10-01

    A model system consisting of Ni[001](100)/Ni3Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni3Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni3Al multilayer can be well predicted by the Voigt-Reuss-Hill rule of mixtures.

  20. Low-field spin dynamics of Cr7Ni and Cr7Ni-Cu -Cr 7Ni molecular rings as detected by μ SR

    Science.gov (United States)

    Sanna, S.; Arosio, P.; Bordonali, L.; Adelnia, F.; Mariani, M.; Garlatti, E.; Baines, C.; Amato, A.; Sabareesh, K. P. V.; Timco, G.; Winpenny, R. E. P.; Blundell, S. J.; Lascialfari, A.

    2017-11-01

    Muon spin rotation measurements were used to investigate the spin dynamics of heterometallic Cr7Ni and Cr7Ni -Cu-Cr7Ni molecular clusters. In Cr7Ni the magnetic ions are arranged in a quasiplanar ring and interact via an antiferromagnetic exchange coupling constant J , while Cr7Ni -Cu-Cr7Ni is composed of two Cr7Ni linked by a bridging moiety containing one Cu ion, that induces an inter-ring ferromagnetic interaction J'≪J . The longitudinal muon relaxation rate λ collected at low magnetic fields μ0H BPP)-like heuristic fitting model that takes into account of a distribution of electronic spin characteristic times for T >5 K, while the shoulder presented by Cr7Ni can be reproduced by a BPP function that incorporates a single electronic characteristic time theoretically predicted to dominate for T <5 K. The flattening of λ (T ) in Cr7Ni -Cu-Cr7Ni occurring at very low temperature can be tentatively attributed to field-dependent quantum effects and/or to an inelastic term in the spectral density of the electronic spin fluctuations.

  1. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al nanoparticles as a high microwave absorption material

    International Nuclear Information System (INIS)

    Pang, Yu; Xie, Xiubo; Li, Da; Chou, Wusheng; Liu, Tong

    2017-01-01

    The Al_3Ni_2@Al nanoparticles (NPs) were prepared from Ni_4_5Al_5_5 master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m"2/g and big pore volume of 0.507 cc/g. The saturation magnetization (M_S) and coercivity (H_C) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m"2/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  2. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al nanoparticles as a high microwave absorption material

    Energy Technology Data Exchange (ETDEWEB)

    Pang, Yu; Xie, Xiubo; Li, Da [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China); Chou, Wusheng [School of Mechanical Engineering and Automation, Beihang University, Beijing 100191 (China); Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China)

    2017-03-15

    The Al{sub 3}Ni{sub 2}@Al nanoparticles (NPs) were prepared from Ni{sub 45}Al{sub 55} master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m{sup 2}/g and big pore volume of 0.507 cc/g. The saturation magnetization (M{sub S}) and coercivity (H{sub C}) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m{sup 2}/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  3. Tracer diffusion of 60Co and 63Ni in amorphous NiZr alloy

    International Nuclear Information System (INIS)

    Hoshino, K.; Averback, R.S.; Hahn, H.; Rothman, S.J.

    1987-01-01

    Tracer diffusion of 60 Co and 63 Ni in equiatomic amorphous NiZr alloy in the temperature range between 486 and 641 0 K can be described by: D/sub Co/sup */ = 3.7 x 10 -7 exp[-(135 +- 14) kJ mole -1 /RT] m 2 /sec and D/sub Ni//sup */ = 1.7 x 10 -7 exp[-(140 +- 9) kJ mole -1 /RT] m 2 /sec. The values of D/sub Ni//sup */ are in reasonable agreement with those measured by the Rutherford backscattering technique. The measured diffusivities were independent of time, indicating that no relaxation took place during diffusion. 27 refs., 2 tabs

  4. Precipitation-induced of partial annealing of Ni-rich NiTi shape memory alloy

    Science.gov (United States)

    Nashrudin, Muhammad Naqib; Mahmud, Abdus Samad; Mohamad, Hishamiakim

    2018-05-01

    NiTi shape memory alloy behavior is very sensitive to alloy composition and heat treatment processes. Thermomechanical behavior of near-equiatomic alloy is normally enhanced by partial anneal of a cold-worked specimen. The shape memory behavior of Ni-rich alloy can be enhanced by ageing precipitation. This work studied the effect of simultaneous partial annealing and ageing precipitation of a Ni-rich cold drawn Ti-50.9at%Ni wire towards martensite phase transformation behavior. Ageing treatment of a non-cold worked specimen was also done for comparison. It was found that the increase of heat treatment temperature caused the forward transformation stress to decrease for the cold worked and non-cold worked specimens. Strain recovery on the reverse transformation of the cold worked wire improved compared to the non-cold worked wire as the temperature increased.

  5. Corrosion behaviour of electrodeposited nanocrystalline Ni-W and Ni-Fe-W alloys

    International Nuclear Information System (INIS)

    Sriraman, K.R.; Ganesh Sundara Raman, S.; Seshadri, S.K.

    2007-01-01

    The present work deals with evaluation of corrosion behaviour of electrodeposited nanocrystalline Ni-W and Ni-Fe-W alloys. Corrosion behaviour of the coatings deposited on steel substrates was studied using polarization and electrochemical impedance spectroscopy techniques in 3.5% NaCl solution while their passivation behaviour was studied in 1N sulphuric acid solution. The corrosion resistance of Ni-W alloys increased with tungsten content up to 7.54 at.% and then decreased. In case of Ni-Fe-W alloys it increased with tungsten content up to 9.20 at.% and then decreased. The ternary alloy coatings exhibited poor corrosion resistance compared to binary alloy coatings due to preferential dissolution of iron from the matrix. Regardless of composition all the alloys exhibited passivation behaviour over a wide range of potentials due to the formation of tungsten rich film on the surface

  6. Evolution of collectivity in the 78Ni region: Coulomb excitation of 74Ni at intermediate energies.

    Directory of Open Access Journals (Sweden)

    Marchi T.

    2014-03-01

    Full Text Available The study of the collective properties of nuclear excitations far from stability provides information about the shell structure at extreme conditions. Spectroscopic observables such as the energy or the transition probabilities of the lowest states, in nuclei with large neutron excess, allow to probe the density and isospin dependence of the effective interaction. Indeed, it was recently shown that tensor and three-body forces play an important role in breaking and creating magic numbers. Emblematic is the case of the evolution of the Ni isotopic chain where several features showed up moving from the most neutron rich stable isotope (64Ni towards the 78Ni nucleus where the large neutron excess coincides with a double shell closure. In this framework, we have recently performed an experiment with the goal to extract the B(E2; 0+ → 2+ value for the 74Ni nucleus in an intermediate-energy Coulomb excitation experiment: preliminary results are discussed.

  7. Rate of hydrogen motion in Ni-substituted LaNi5Hx from NMR

    International Nuclear Information System (INIS)

    Mendenhall, Michael P.; Bowman, Robert C.; Ivancic, Timothy M.; Conradi, Mark S.

    2007-01-01

    Partial substitution of Sn, Ge, or Si for Ni in LaNi 5 H x greatly enhances the stability under repeated hydrogen-cycling. Proton NMR relaxation measurements are reported here to determine the rates of H hopping in the substituted metals LaNi 4.6 M 0.4 H x with M = Sn, Ge, and Si, for comparison to bare LaNi 5 H x . The relaxation times T 2 * (FID), T 2 (Hahn echo), T 2 -CPMG, T 1 , and T 1ρ were determined from 130 to 375 K. The three substituents result in only small increases in the average rate of motion at a given temperature but with a broader distribution of rates over the many inequivalent H sites and hopping paths. Evidently, the average energy barriers along the paths for H motion are only little affected by these substituents. Changes of H content x produce only minor changes in the relaxation times

  8. Moessbauer effect measurements on the intermetallic compounds Ni3Al and Ni3Ge

    International Nuclear Information System (INIS)

    Drijver, J.W.; Woude, F. van der

    1975-01-01

    Moessbauer parameters obtained from room temperature emission and absorption spectra of Ni 3 Al and Ni 3 Ga processed by a computer assuming a singlet and a doublet are given. The doublet is due to iron or cobalt atoms at the nickel site. Quadrupole splitting at 57 Fe nuclei in Ni 3 Ga is larger than in Ni 3 Al, viz. 0.52 and 0.37 mm/sec, respectively. Isomer shift at the Al/Ga position is very close to -0.02 mm/sec found in metallic nickel. Also given are the hyperfine magnetic fields at 4.2 K. Considering the preference of 57 Co and 57 Fe atoms in the lattice, the field intensities at the nickel and aluminium sites are found to be 227 +- 1 and 238 +- 1 kOe, respectively. (Z.S.)

  9. Low energy structure of even-even Ni isotopes close to 78Ni

    International Nuclear Information System (INIS)

    Rykaczewski, Krzysztof Piotr; Mazzocchi, C.; Grzywacz, Robert Kazimierz; Batchelder, J.C.; Bingham, Carrol R.; Fong, D.; Hamilton, J.H.; Hwang, J.K.; Karny, M.; Krolas, W.; Liddick, S.N.; Lisetskiy, A. F.; Morton, N.H.; Mantica, P.F.; Mueller, W.F.; Steiner, M.; Stolz, A.; Winger, J.A.

    2005-01-01

    The structure of magic neutron-rich nickel isotopes produced in the fragmentation of a 140 A MeV 86 Kr beam was investigated. For the first time four gamma transitions were assigned to the decay of the I π =8 + , T 1/2 = 590 +180 -110 isomer, thus establishing the 0 + -2 + -4 + -6 + -8 + ground-state band in 76 Ni. The previously unknown 2 + and 4 + levels belonging to the ground-state band in 74 Ni were identified in the β decay of 74 Co (T 1/2 =30(3) ms). The decay properties of 72 Co → 72 Ni were verified and confirmed on the basis of γ-γ coincidence data. The relevance of the measured level properties for the magicity of 78 Ni is analyzed with the help of advanced shell-model predictions

  10. The process of Ni-63 production and measurement of beta radiation of irradiated Ni-63

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Uhma, Young Rang; Kim, Jong Bum; Choi, Sang Mu; Son, Kwang Jae; Hong, Jin Tae; Park, Jong Han

    2016-01-01

    It has the following characteristics: long service lifetime, high energy density, easy small-scale fabrication, and minimum maintenance. For this reasons, betavoltaic batteries are widely used in many low-power applications such as medical applications and power sources for micro electro-mechanical system (MEMS) because they can operate effectively at extreme environments. Proper selection of radioisotope is a critical factor in the design of a betavoltaic battery. The important factors affecting the performance of a betavoltaic battery are specific activity, half-life, and toxicity. In this study, a target for irradiation was produced using 99% Ni-62 metal power concentrate. Ni-62 target of 1 g was irradiated in MARIA reactor operated in Poland for 470 hours, and estimated production of Ni- 63 was calculated. Irradiated Ni-63 pellets were dissolved in HCl solution, and its beta radiation was measured by Liquid Scintillation Counter (LSC).

  11. Synthetic Ni3S2/Ni hybrid architectures as potential contrast agents in MRI

    International Nuclear Information System (INIS)

    Ma, J; Chen, K

    2016-01-01

    Traditional magnetic resonance imaging (MRI) contrast agents mainly include superparamagnetic (SPM) iron oxide nanoparticle as T 2 contrast agent for liver and paramagnetic Gd (III)-chelate as T 1 contrast agent for all organs. In this work, weak ferromagnetic kale-like and SPM cabbage-like Ni 3 S 2 @Ni hybrid architectures were synthesized and evaluated as potential T 1 MRI contrast agents. Their relatively small r 2 /r 1 ratios of 2.59 and 2.38, and high r 1 values of 11.27 and 4.89 mmol −1 L s −1 (for the kale-like and cabbage-like Ni 3 S 2 @Ni, respectively) will shed some light on the development of new-type MRI contrast agents. (paper)

  12. Hierarchical NiCo2 O4 nanosheets grown on Ni nanofoam as high-performance electrodes for supercapacitors.

    Science.gov (United States)

    Gao, Guoxin; Wu, Hao Bin; Ding, Shujiang; Liu, Li-Min; Lou, Xiong Wen David

    2015-02-18

    A high-performance electrode for supercapacitors is designed and synthesized by growing electroactive NiCo2 O4 nanosheets on conductive Ni nanofoam. Because of the structural advantages, the as-prepared Ni@NiCo2 O4 hybrid nanostructure exhibits significantly improved electrochemical performance with high capacitance, excellent rate capability, and good cycling stability. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Ni(II) complexes of dithiophosphonic acids

    Indian Academy of Sciences (India)

    aDepartment of Chemistry, Science and Research Branch, Islamic Azad ... The compounds were characterized by 1H, 13C and 31P NMR, IR spectroscopy and elemental analysis. The ... design and synthesize Ni(II) complexes with new ..... Yield: 86%. ..... 28 65. 18. Greenwood D 1989 Antimicrobial chemotherapy (New.

  14. Ni MINERALIZATION AND PGE CHARACTERIZATION IN THE ...

    African Journals Online (AJOL)

    Mgina

    fractionation, (2) the IPGEs are often associated with chromites as alloys or sulfides in ... Key words: Tanzania, Kabanga, Luhuma, PGE, Ni-Cu sulfides .... massive sulfide based on size of ore zone ... to ≤ 0.1 wt% and Fe2O3T = 80- ≈ 87 wt%.

  15. Modelling of rechargeable NiMH batteries

    NARCIS (Netherlands)

    Ledovskikh, A.; Verbitskiy, E.; Ayeb, A.; Notten, P.H.L.

    2003-01-01

    A new mathematical model has been developed for rechargeable NiMH batteries, which is based on the occurring physical–chemical processes inside. This model enables one to simultaneously simulate the battery voltage, internal gas pressures (both PO2 and PH2) and temperature during battery operation.

  16. Characterisation of a Zn / Ni Plating Bath

    Science.gov (United States)

    2009-09-03

    accelerated corrosion in the first stages which is then slowed down by its own product of corrosion, Zn(OH)212. Zinc hydroxide dehydrates in time to form ZnO ... Electrochemistry , 1991, 21, 642 [5] – Alfantasi, A.M., A study on the synthesis, characterization ans properties of pulse-plated ultrafine- grained Zn-Ni alloy

  17. Evidence for an isomer in 76Ni

    International Nuclear Information System (INIS)

    Sawicka, M.; Pfuetzner, M.; Grzywacz, R.; Daugas, J.M.; Belier, G.; Sauvestre, J.E.; Matea, I.; Lewitowicz, M.; Georgiev, G.; Grawe, H.; Mayet, P.; Becker, F.; Bingham, C.; Borcea, R.; Hammache, F.; Ibrahim, F.; Bouchez, E.; Buta, A.; Dragulescu, E.; Giovinazzo, J.; Meot, V.; Negoita, F.; De Oliveira Santos, F.; Perru, O.; Roig, O.; Rykaczewski, K.P.; Saint-Laurent, M.G.; Sorlin, O.; Stanoiu, M.; Stefan, I.; Stodel, C.; Theisen, C.; Verney, D.

    2004-01-01

    In the experiment performed at the LISE2000 spectrometer at GANIL neutron-rich nickel isotopes were studied by microsecond isomer spectroscopy. Evidence for an isomer in 76 Ni is found, consistently with the shell model prediction of an 8 + state of ν(g 9/2 ) 2 structure. (orig.)

  18. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    Energy Technology Data Exchange (ETDEWEB)

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju [KAERI, Daejeon (Korea, Republic of)

    2012-10-15

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  19. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    International Nuclear Information System (INIS)

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju

    2012-01-01

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  20. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties

    International Nuclear Information System (INIS)

    Liu, Tong; Pang, Yu; Xie, Xiubo; Qi, Wen; Wu, Ying; Kobayashi, Satoru; Zheng, Jie; Li, Xingguo

    2016-01-01

    The fabrication of microporous metal materials with many potential applications is challenging due to their high chemical activities and the difficulty in controlling the pore size. By adjusting the reaction condition and the composition of the Ni–Al nanoparticle precursor, we have successfully produced the microporous Ni nanoparticles (NPs) of 22 nm by chemical dealloying method. During the passivation process, the microporous Ni NPs covered with NiO shell are generated as the result of surface oxidation. The micropores range from 0.6 to 1.2 nm in diameter with a large surface area of 68.9 m"2/g. Due to the elimination of Al atoms during dealloying process, the crystalline size of the microporous Ni NPs is sharply decreased to 2–5 nm. The specific architecture offers the microporous Ni/NiO NPs a small microwave reflection coefficient (RC) and a wide absorption bandwidth (RC ≤ −10 dB) of −49.1 dB and 5.8 GHz, much better than the nonporous counterpart of −24.1 dB and 3.7 GHz. The enhanced microwave absorption performance has been interpreted in terms of the micropore structure, core/shell structure and nanostructure effects. - Highlights: • Microporous Ni/NiO nanoparticles are prepared by chemical dealloying method. • They possess micropores of 0.6–1.2 nm with a surface area of 68.9 m"2/g. • They show minimum microwave reflection coefficient of −49.1 dB and bandwidth of 5.8 GHz. • Microwave absorption mechanism is explained by micropore and core/shell structures.

  1. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing, 100191 (China); Pang, Yu; Xie, Xiubo [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing, 100191 (China); Qi, Wen; Wu, Ying [China Iron & Steel Research Institute Group, Advanced Technology & Materials Co., Ltd, No.76 Xueyuannanlu, Haidian District, Beijing, 100081 (China); Kobayashi, Satoru [Faculty of Engineering, Iwate University, Ueda, Morioka, 020-8551 (Japan); Zheng, Jie; Li, Xingguo [Beijing National Laboratory for Molecular Sciences (BNLMS), The State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 (China)

    2016-05-15

    The fabrication of microporous metal materials with many potential applications is challenging due to their high chemical activities and the difficulty in controlling the pore size. By adjusting the reaction condition and the composition of the Ni–Al nanoparticle precursor, we have successfully produced the microporous Ni nanoparticles (NPs) of 22 nm by chemical dealloying method. During the passivation process, the microporous Ni NPs covered with NiO shell are generated as the result of surface oxidation. The micropores range from 0.6 to 1.2 nm in diameter with a large surface area of 68.9 m{sup 2}/g. Due to the elimination of Al atoms during dealloying process, the crystalline size of the microporous Ni NPs is sharply decreased to 2–5 nm. The specific architecture offers the microporous Ni/NiO NPs a small microwave reflection coefficient (RC) and a wide absorption bandwidth (RC ≤ −10 dB) of −49.1 dB and 5.8 GHz, much better than the nonporous counterpart of −24.1 dB and 3.7 GHz. The enhanced microwave absorption performance has been interpreted in terms of the micropore structure, core/shell structure and nanostructure effects. - Highlights: • Microporous Ni/NiO nanoparticles are prepared by chemical dealloying method. • They possess micropores of 0.6–1.2 nm with a surface area of 68.9 m{sup 2}/g. • They show minimum microwave reflection coefficient of −49.1 dB and bandwidth of 5.8 GHz. • Microwave absorption mechanism is explained by micropore and core/shell structures.

  2. Geometric structures of thin film: Pt on Pd(110) and NiO on Ni(100)

    Energy Technology Data Exchange (ETDEWEB)

    Warren, Oden L. [Iowa State Univ., Ames, IA (United States)

    1993-07-01

    This thesis is divided into 3 papers: dynamical low-energy electron- diffraction investigation of lateral displacements in topmost layer of Pd(110); determination of (1x1) and (1x2) structures of Pt thin films on Pd(110) by dynamical low-energy electron-diffraction analysis; and structural determination of a NiO(111) film on Ni(100) by dynamical low-energy electron-diffraction analysis.

  3. Fabrication and tensile properties of rapidly solidified Cu-10wt. %Ni alloy. [Cu-10Ni

    Energy Technology Data Exchange (ETDEWEB)

    Baril, D; Angers, R; Baril, J [Dept. of Mining and Metallurgy, Laval Univ., Ste-Foy, Quebec (Canada)

    1992-10-15

    Cu-10wt.%Ni ribbons were produced by melt spinning and cut into small particles with a blade cutter mill. The powders were then hot consolidated to full density by hot pressing followed by hot extrusion. Tensile properties of the resulting pieces were measured. Cu-10wt.%Ni cast ingots were also hot extruded and mechanically tested to compare with the rapidly solidified alloy and to evaluate the possible benefits brought by the rapid solidification process.

  4. 59Ni and 63Ni separation from boric acid concentrates produced at NPP

    International Nuclear Information System (INIS)

    Fisera, O.

    2010-01-01

    Procedure for direct separation of radionickel from boric acid concentrate was developed. Quantitative separation from 100 mL of real concentrate on the column filled with 3 mL of PAN-DMG composite material was achieved. PAN-DMG material (dimethylglyoxime in porous beads of polyacrylonitrile) was compared with Ni Resin and DMG-PAN material exhibited higher sorption capacity for nickel than Ni Resin. (author)

  5. Valence electronic structure of Ni in Ni Si alloys from relative K X-ray intensity studies

    Science.gov (United States)

    Kalayci, Y.; Aydinuraz, A.; Tugluoglu, B.; Mutlu, R. H.

    2007-02-01

    The Kβ-to-Kα X-ray intensity ratio of Ni in Ni 3Si, Ni 2Si and NiSi has been determined by energy dispersive X-ray fluorescence technique. It is found that the intensity ratio of Ni decreases from pure Ni to Ni 2Si and then increases from Ni 2Si to NiSi, in good agreement with the electronic structure calculations cited in the literature. We have also performed band structure calculations for pure Ni in various atomic configurations by means of linear muffin-tin orbital method and used this data with the normalized theoretical intensity ratios cited in the literature to estimate the 3d-occupation numbers of Ni in Ni-Si alloys. It is emphasized that investigation of alloying effect in terms of X-ray intensity ratios should be carried out for the stoichiometric alloys in order to make reliable and quantitative comparisons between theory and experiment in transition metal alloys.

  6. La Niña, El Niño, and Atlantic Hurricane Damages in the United States

    Science.gov (United States)

    data discussed below), this definition results in 22 El Niño years, 29 neutral years, and 22 La Niña accounting for the most significant societal changes. To normalize past impacts data to 1997 values, losses , 169 and 186. Trenberth, K. E., 1997: The definition of El Niño. Bull. Amer. Meteor. Soc., 78, 2771

  7. Observations of defect structure evolution in proton and Ni ion irradiated Ni-Cr binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Briggs, Samuel A., E-mail: sabriggs2@wisc.edu [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Barr, Christopher M. [Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Pakarinen, Janne [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); SKC-CEN Belgian Nuclear Research Centre, Boeretang 200, B-2400 Mol (Belgium); Mamivand, Mahmood [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Hattar, Khalid [Sandia National Laboratories, PO Box 5800, Albuquerque, NM 87185 (United States); Morgan, Dane D. [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Taheri, Mitra [Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Sridharan, Kumar [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States)

    2016-10-15

    Two binary Ni-Cr model alloys with 5 wt% Cr and 18 wt% Cr were irradiated using 2 MeV protons at 400 and 500 °C and 20 MeV Ni{sup 4+} ions at 500 °C to investigate microstructural evolution as a function of composition, irradiation temperature, and irradiating ion species. Transmission electron microscopy (TEM) was applied to study irradiation-induced void and faulted Frank loops microstructures. Irradiations at 500 °C were shown to generate decreased densities of larger defects, likely due to increased barriers to defect nucleation as compared to 400 °C irradiations. Heavy ion irradiation resulted in a larger density of smaller voids when compared to proton irradiations, indicating in-cascade clustering of point defects. Cluster dynamics simulations were in good agreement with the experimental findings, suggesting that increases in Cr content lead to an increase in interstitial binding energy, leading to higher densities of smaller dislocation loops in the Ni-18Cr alloy as compared to the Ni-5Cr alloy. - Highlights: • Binary Ni-Cr alloys were irradiated with protons or Ni ions at 400 and 500 °C. • Higher irradiation temperatures yield increased size, decreased density of defects. • Hypothesize that varying Cr content affects interstitial binding energy. • Fitting CD models for loop nucleation to data supports this hypothesis.

  8. Study of the magnetic anisotropy in Ni/Cu and Ni/glass thin films

    Energy Technology Data Exchange (ETDEWEB)

    Cherif, S.-M. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse, 93340 (France); Layadi, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria)]. E-mail: a_layadi@yahoo.fr; Ben Youssef, J. [Laboratoire de Magnetisme de Bretagne, U.B.O., Brest 29238 (France); Nacereddine, C. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Roussigne, Y. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse, 93340 (France)

    2007-01-01

    The magnetic properties of evaporated Ni/Cu and Ni/glass thin films have been investigated by means of the vibrating sample magnetometer (VSM), the Brillouin light scattering (BLS) and magnetic force microscopy (MFM). The Ni thickness, t, ranges from 31 to 165 nm. The second- and fourth-order magnetic anisotropy constants, K {sub 1} and K {sub 2}, have been included; for the Ni/Cu series, K {sub 1} was found to decrease from 1.0x10{sup 6} to 0.18x10{sup 6} erg/cm{sup 3} as t increases from 31 to 165 nm, while K {sub 2} increased from 0.24x10{sup 6} to 0.8x10{sup 6} erg/cm{sup 3}. Over all the thickness range, the magnetization easy axis is in plane. For thinner films, there is a good agreement between anisotropy constant values inferred from VSM and BLS. Stripe domains were observed for t{>=}165 nm in Ni/glass and t{>=}90 nm in Ni/Cu.

  9. Study of the magnetic anisotropy in Ni/Cu and Ni/glass thin films

    International Nuclear Information System (INIS)

    Cherif, S.-M.; Layadi, A.; Ben Youssef, J.; Nacereddine, C.; Roussigne, Y.

    2007-01-01

    The magnetic properties of evaporated Ni/Cu and Ni/glass thin films have been investigated by means of the vibrating sample magnetometer (VSM), the Brillouin light scattering (BLS) and magnetic force microscopy (MFM). The Ni thickness, t, ranges from 31 to 165 nm. The second- and fourth-order magnetic anisotropy constants, K 1 and K 2 , have been included; for the Ni/Cu series, K 1 was found to decrease from 1.0x10 6 to 0.18x10 6 erg/cm 3 as t increases from 31 to 165 nm, while K 2 increased from 0.24x10 6 to 0.8x10 6 erg/cm 3 . Over all the thickness range, the magnetization easy axis is in plane. For thinner films, there is a good agreement between anisotropy constant values inferred from VSM and BLS. Stripe domains were observed for t≥165 nm in Ni/glass and t≥90 nm in Ni/Cu

  10. Effect of Ni4Ti3 precipitation on martensitic transformation in Ti-Ni

    International Nuclear Information System (INIS)

    Zhou, N.; Shen, C.; Wagner, M.F.-X.; Eggeler, G.; Mills, M.J.; Wang, Y.

    2010-01-01

    Precipitation of Ni 4 Ti 3 plays a critical role in determining the martensitic transformation path and temperature in Ni-Ti shape memory alloys. In this study, the equilibrium shape of a coherent Ni 4 Ti 3 precipitate and the concentration and stress fields around it are determined quantitatively using the phase field method. Most recent experimental data on lattice parameters, elastic constants, precipitate-matrix orientation relationship and thermodynamic database are used as model inputs. The effects of the concentration and stress fields on subsequent martensitic transformations are analyzed through interaction energy between a nucleating martensitic particle and the existing microstructure. Results indicate that R-phase formation prior to B19' phase could be attributed to both direct elastic interaction and stress-induced spatial variation in concentration near Ni 4 Ti 3 precipitates. The preferred nucleation sites for the R-phase are close to the broad side of the lenticular-shaped Ni 4 Ti 3 precipitates, where tension normal to the habit plane is highest, and Ni concentration is lowest.

  11. Fabrication of metallic alloy powder (Ni{sub 3}Fe) from Fe–77Ni scrap

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Inseok [ES Materials Research Center, Research Institute of Industrial Science and Technology, Incheon 406-840 (Korea, Republic of); Shin, Shun-Myung [Extractive Metallurgy Department, Korea Institute of Geoscience and Mineral Resources, Deajeon 305-350 (Korea, Republic of); Ha, Sang-An [Department of Environmental Engineering, Silla University, Busan 46958 (Korea, Republic of); Wang, Jei-Pil, E-mail: jpwang@pknu.ac.kr [Department of Metallurgical Engineering, Pukyong National University, Busan 608-739 (Korea, Republic of)

    2016-06-15

    The oxidation behavior of Fe–77Ni alloy scrap was investigated at an oxygen partial pressure of 0.2 atm and temperatures ranging from 400 °C to 900 °C. The corresponding oxidation rate increased with increasing temperature and obeyed the parabolic rate law, as evidenced by its linear proportionality to the temperature. In addition, surface morphologies, cross-sectional views, compositions, structural properties were examined by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Diffusion through either the spinel structure or the NiO layer, which were both present in the alloy during oxidation at elevated temperatures, was deemed the rate-limiting step of the reaction. The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap was obtained using ball-milling and sieving processes. In fact, 15 h of milling yielded a recovery ratio of 97%. Using hydrogen gas, the oxide powder was successfully reduced to an alloy powder of Ni{sub 3}Fe and reduction rates of ∼97% were achieved after 3 h at 1000 °C. - Highlights: • The oxidation behavior of Fe–77Ni alloy scrap was investigated. • The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap. • Using hydrogen gas, the oxide powder was successfully reclaimed. • Reduction rates of ∼97% were achieved after 3 h at 1000 °C.

  12. Positron annihilation studies in CeNiIn and LaNiIn

    International Nuclear Information System (INIS)

    Ray, R.; Giri, S.; Sen, M.; Nambissan, P.M.G.; Ghoshray, K.; Ghoshray, A.; Sen, P.

    1997-01-01

    Doppler broadened positron annihilation spectral lineshape (DBPAS) and positron lifetime measurements in the temperature range 18-280 K have been performed in CeNiIn and LaNiIn systems. The nature of the temperature variations of the lifetime in both systems is almost similar in the whole temperature range studied, whereas the nature of the temperature variation of the S parameter in CeNiIn is similar to that in LaNiIn except in the temperature region 18-40 K. For the former system there is a dip around 20 K in the S parameter versus temperature curve. The lifetime versus T curve in both systems could be explained by the thermal expansion of the lattice. The S parameter versus T curve in LaNiIn could also be attributed to the thermal expansion of the lattice, whereas in CeNiIn the above mentioned dip seems an extra feature of the thermal expansion of the lattice. To understand this low temperature behaviour other results on the same system have been discussed. (orig.)

  13. Interfacial reaction of Ni{sub 3}Sn{sub 4} intermetallic compound in Ni/SnAg solder/Ni system under thermomigration

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yi-Shan; Yang, Chia-Jung; Ouyang, Fan-Yi, E-mail: fyouyang@ess.nthu.edu.tw

    2016-07-25

    The growth of Ni{sub 3}Sn{sub 4} intermetallic compound (IMC) between liquid–solid interface in micro-scale Ni/SnAg/Ni system was investigated under a temperature gradient of 160 °C/cm at 260 °C on a hot plate. In contrast to a symmetrical growth of Ni{sub 3}Sn{sub 4} on both interfaces under isothermally annealed at 260 °C, the interfacial Ni{sub 3}Sn{sub 4} IMC exhibited asymmetric growth under a temperature gradient; the growth of Ni{sub 3}Sn{sub 4} at cold interface was faster than that at hot side because of temperature gradient induced mass migration of Ni atoms from the hot end toward the cold end. It was found that two-stage growth behavior of Ni{sub 3}Sn{sub 4} IMC under a temperature gradient. A growth model was established and growth kinetic analysis suggested that the chemical potential gradient controlled the growth of Ni{sub 3}Sn{sub 4} at stage I (0–120 min) whereas the dynamic equilibrium between chemical potential gradient and temperature gradient forces was attained at the hot end at stage II (120–210 min). When dynamic equilibrium was achieved at 260 °C, the critical length-temperature gradient product at the hot end was experimentally estimated to be 489.18 μm × °C/cm and the moving velocity of Ni{sub 3}Sn{sub 4} interface due to Ni consumption was calculated to be 0.134 μm/h. The molar heat of transport (Q*) of Ni atoms in molten SnAg solder was calculated to be +0.76 kJ/mol. - Highlights: • Interfacial reaction in Ni/SnAg solder/Ni system under thermal gradient. • Growth rate of Ni{sub 3}Sn{sub 4} at cold end is faster than that at hot end. • Critical length-temperature gradient product at hot end is 489.2 μm°C/cm at 260 °C. • Velocity of Ni{sub 3}Sn{sub 4} moving interface is 0.134 μm/h during dynamic equilibrium. • Molar heat of transport (Q*) of Ni in molten SnAg was +0.76 kJ/mol.

  14. Evaluation of the Antitumor Activity by Ni Nanoparticles with Verbascoside

    Directory of Open Access Journals (Sweden)

    Mingyue Chen

    2013-01-01

    Full Text Available Verbascoside (VB has attracted a great deal of attention due to ITS pharmacological properties. In our study, we synthesized a multifunctional verbascoside coated Ni nanoparticles (VB-Ni. Transmission electron microscopy (TEM and high performance liquid chromatography (HPLC display the characteristics of VB-Ni nanoparticles. Compared with VB, VB-Ni has been proven to induce apoptosis and resist the growth of doxorubicin-resistant K562 cells in vitro and in vivo. Thus, VB-Ni nanoparticles can be thought of as an ideal mode of cancer treatment.

  15. A Study on Production of Carbon Nanotubes by CH4 Decomposition over LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Carbon nanotubes (CNTs) of narrow size distribution can be abundantly produced in the catalytic decomposition of CH4 over pre-reduced LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4.The CNTs obtained were characterized by means of transmission electron microscopy (TEM).Thermal oxidation of CNTs in air was monitored thermogravimetrically (TG). The resultsrevealed that a lower La/Ni ratio of the catalysts would lead to a wider diameter distribution and a higher degree of graphitic nature.

  16. Thin NiTi Films Deposited on Graphene Substrates

    Science.gov (United States)

    Hahn, S.; Schulze, A.; Böhme, M.; Hahn, T.; Wagner, M. F.-X.

    2017-03-01

    We present experimental results on the deposition of Nickel Titanium (NiTi) films on graphene substrates using a PVD magnetron sputter process. Characterization of the 2-4 micron thick NiTi films by electron microscopy, electron backscatter diffraction, and transmission electron microscopy shows that grain size and orientation of the thin NiTi films strongly depend on the type of combination of graphene and copper layers below. Our experimental findings are supported by density functional theory calculations: a theoretical estimation of the binding energies of different NiTi-graphene interfaces is in line with the experimentally determined microstructural features of the functional NiTi top layer.

  17. Achievement report for fiscal 1999. Research on mesh-based estimation of natural energy for Southeast Asia as represented by Myanmar (Assessment of wind power and solar energy using numerical weather model); 1999 nendo Myanmar koku wo rei ni shita Tonan Asia ni okeru shizen energy no mesh suitei ni kansuru kenkyu seika hokokusho. Suchi kisho model ni yoru furyoku taiyo energy hyoka

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    As the first step for the introduction of wind power systems and photovoltaic power systems into developing countries in Southeast Asia etc. and for their diffusion in them for the exploitation of natural energy, a numerical weather model useable in Southeast Asia is developed to make up for the insufficiency of weather data in the region. A technique is developed, to explain which the case of Myanmar is cited, for estimating with accuracy such natural conditions as wind direction, wind velocity, and solar radiation in the past one-year period for the assessment of power to be generated using wind turbines and solar panels. The results of the observation of wind conditions indicate that wind directions are mainly northerly or westerly and that wind speeds are as week as 1-3m/s on the average. As for total solar radiation per diem in December through March, it is found that there is 17-23MJ/m{sup 2}/day, which is twice the level to be measured in Tokyo. A comparison is made between the weather observation results and a model calculation, and it is found that the latter sufficiently reproduces the actual weather conditions. Based on the values of wind conditions and solar radiation estimated in Myanmar, the amount of power to be obtained from an assumed arrangement of wind power systems and solar panels is assessed. (NEDO)

  18. Properties of mechanically alloyed Mg-Ni-Ti ternary hydrogen storage alloys for Ni-MH batteries

    Science.gov (United States)

    Ruggeri, Stéphane; Roué, Lionel; Huot, Jacques; Schulz, Robert; Aymard, Luc; Tarascon, Jean-Marie

    MgNiTi x, Mg 1- xTi xNi and MgNi 1- xTi x (with x varying from 0 to 0.5) alloys have been prepared by high energy ball milling and tested as hydrogen storage electrodes. The initial discharge capacities of the Mg-Ni-Ti ternary alloys are inferior to the MgNi electrode capacity. However, an exception is observed with MgNi 0.95Ti 0.05, which has an initial discharge capacity of 575 mAh/g compared to 522 mAh/g for the MgNi electrode. The Mg-Ni-Ti ternary alloys show improved cycle life compared to Mg-Ni binary alloys with the same Mg/Ni atomic ratio. The best cycle life is observed with Mg 0.5Ti 0.5Ni electrode which retains 75% of initial capacity after 10 cycles in comparison to 39% for MgNi electrodes, in addition to improved high-rate dischargeability (HRD). According to the XPS analysis, the cycle life improvement of the Mg 0.5Ti 0.5Ni electrode can be related to the formation of TiO 2 which limits Mg(OH) 2 formation. The anodic polarization curve of Mg 0.5Ti 0.5Ni electrode shows that the current related to the active/passive transition is much less important and that the passive region is more extended than for the MgNi electrode but the corrosion of the electrode is still significant. This suggests that the cycle life improvement would be also associated with a decrease of the particle pulverization upon cycling.

  19. Densities of molten Ni-(Cr, Co, W) superalloys

    Institute of Scientific and Technical Information of China (English)

    XIAO Feng; YANG Ren-hui; FANG Liang; LIU Lan-xiao; ZHAO Hong-kai

    2008-01-01

    In order to obtain more accurate density for molten Ni-(Cr, Co, W) binary alloy, the densities of molten pure Ni and Ni-Cr, Ni-Co, Ni-W alloys were measured with a sessile drop method. It is found that the measured densities of molten pure Ni and Ni-Cr, Ni-Co, Ni-W alloys decrease with increasing temperature in the experimental temperature range. The density of alloys increases with increasing W and Co concentrations while it decreases with increasing Cr concentration in the alloy at 1 773-1 873 K. The molar volume of Ni-based alloys increases with increasing W concentration while it decreases with increasing Co concentration. The effect of Cr concentration on the molar volume of the alloy is little in the studied concentration range. The accommodation among atomic species was analyzed. The deviation of molar volume from ideal mixing shows an ideal mixing of Ni-(Cr, Co, W) binary alloys.

  20. Spectroscopic investigation of Ni speciation in hardened cement paste.

    Science.gov (United States)

    Vespa, M; Dähn, R; Grolimund, D; Wieland, E; Scheidegger, A M

    2006-04-01

    Cement-based materials play an important role in multi-barrier concepts developed worldwide for the safe disposal of hazardous and radioactive wastes. Cement is used to condition and stabilize the waste materials and to construct the engineered barrier systems (container, backfill, and liner materials) of repositories for radioactive waste. In this study, Ni uptake by hardened cement paste has been investigated with the aim of improving our understanding of the immobilization process of heavy metals in cement on the molecular level. X-ray absorption spectroscopy (XAS) coupled with diffuse reflectance spectroscopy (DRS) techniques were used to determine the local environment of Ni in cement systems. The Ni-doped samples were prepared at two different water/cement ratios (0.4, 1.3) and different hydration times (1 hour to 1 year) using a sulfate-resisting Portland cement. The metal loadings and the metal salts added to the system were varied (50 up to 5000 mg/kg; NO3(-), SO4(2-), Cl-). The XAS study showed that for all investigated systems Ni(ll) is predominantly immobilized in a layered double hydroxide (LDH) phase, which was corroborated by DRS measurements. Only a minor extent of Ni(ll) precipitates as Ni-hydroxides (alpha-Ni(OH)2 and beta-Ni(OH)2). This finding suggests that Ni-Al LDH, rather than Ni-hydroxides, is the solubility-limiting phase in the Ni-doped cement system.

  1. Design and fabrication of Ni nanowires having periodically hollow nanostructures.

    Science.gov (United States)

    Sada, Takao; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2014-10-07

    We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag 'barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 ± 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni(2+) for the interior surfaces of AAO. The Ni shell layer allows the Ni segments to remain even after dissolution of the Ag segments. Because the electroplating conditions can be easily controlled, we could carefully adjust the size and pitch of the periodically hollow nanospaces. We also describe a method for the fabrication of Ni nanorods by forming an Ag shell instead of a Ni shell on the Ni-Ag barcode nanowire, in which the interior of the AAO surfaces was modified with a compound bearing a thiol group prior to electroplating.

  2. Ductility of Ni3Al doped with substitutional elements

    International Nuclear Information System (INIS)

    Hanada, S.; Chiba, A.; Guo, H.Z.; Watanabe, S.

    1993-01-01

    This paper reports on ductility of B-free Ni 3 Al alloys. Recrystallized Ni 3 Al binary alloys with Ni-rich compositions show appreciable ductility when an environmental effect is eliminated, while the alloys with stoichiometric and Al-rich compositions remain brittle. The ductility in the Ni-rich Ni 3 Al alloys is associated with low ordering energy. The additions of ternary elements, which are classified as γ formers, ductilize ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Pd, Pt, Cu and Co), whereas the additions of γ' formers embrittle ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Ta, Mo, Nb, Zr, Hf, V, Ti and Si). The additions of small amounts (less than 1 at%) of γ' formers such as Zr and Hf also ductilize as-cast ternary Ni 3 Al alloys. Ductility of Ni 3 Al alloys doped with substitutional elements is discussed in terms of ordering energy and microstructure

  3. CO2 activation on bimetallic CuNi nanoparticles

    Directory of Open Access Journals (Sweden)

    Natalie Austin

    2016-10-01

    Full Text Available Density functional theory calculations have been performed to investigate the structural, electronic, and CO2 adsorption properties of 55-atom bimetallic CuNi nanoparticles (NPs in core-shell and decorated architectures, as well as of their monometallic counterparts. Our results revealed that with respect to the monometallic Cu55 and Ni55 parents, the formation of decorated Cu12Ni43 and core-shell Cu42Ni13 are energetically favorable. We found that CO2 chemisorbs on monometallic Ni55, core-shell Cu13Ni42, and decorated Cu12Ni43 and Cu43Ni12, whereas, it physisorbs on monometallic Cu55 and core-shell Cu42Ni13. The presence of surface Ni on the NPs is key in strongly adsorbing and activating the CO2 molecule (linear to bent transition and elongation of C˭O bonds. This activation occurs through a charge transfer from the NPs to the CO2 molecule, where the local metal d-orbital density localization on surface Ni plays a pivotal role. This work identifies insightful structure-property relationships for CO2 activation and highlights the importance of keeping a balance between NP stability and CO2 adsorption behavior in designing catalytic bimetallic NPs that activate CO2.

  4. NiCo2S4 nanosheet-decorated 3D, porous Ni film@Ni wire electrode materials for all solid-state asymmetric supercapacitor applications.

    Science.gov (United States)

    Saravanakumar, Balasubramaniam; Jayaseelan, Santhana Sivabalan; Seo, Min-Kang; Kim, Hak-Yong; Kim, Byoung-Suhk

    2017-12-07

    Wire type supercapacitors with high energy and power densities have generated considerable interest in wearable applications. Herein, we report a novel NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode for high performance supercapacitor application. In this work, a facile method is introduced to fabricate a 3D, porous Ni film deposited on a Ni wire as a flexible electrode, followed by decoration with NiCo 2 S 4 as an electroactive material. The fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode displays a superior performance with an areal and volumetric capacitance of 1.228 F cm -2 and 199.74 F cm -3 , respectively, at a current density of 0.2 mA cm -1 with a maximum volumetric energy and power density (E V : 6.935 mW h cm -3 ; P V : 1.019 W cm -3 ). Finally, the solid state asymmetric wire type supercapacitor is fabricated using the fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire as a positive electrode and N-doped reduced graphene oxide (N-rGO) as a negative electrode and this exhibits good areal and volumetric capacitances of C A : 0.12 F cm -2 and C V : 19.57 F cm -2 with a higher rate capability (92%). This asymmetric wire type supercapacitor demonstrates a low leakage current and self-discharge with a maximum volumetric energy (E V : 5.33 mW h cm -3 ) and power (P V : 855.69 mW cm -3 ) density.

  5. Surface morphology and electronic structure of Ni/Ag(100)

    International Nuclear Information System (INIS)

    Hite, D. A.; Kizilkaya, O.; Sprunger, P. T.; Howard, M. M.; Ventrice, C. A. Jr.; Geisler, H.; Zehner, D. M.

    2000-01-01

    The growth morphology and electronic structure of Ni on Ag(100) has been studied with scanning tunneling microscopy (STM) and synchrotron based angle resolved photoemission spectroscopy. At deposition temperatures at or below 300 K, STM reveals Ni cluster growth on the surface along with some subsurface growth. Upon annealing to 420 K, virtually all Ni segregates into the subsurface region forming embedded nanoclusters. The electronic structure of Ni d bands in the unannealed surface shows dispersion only perpendicular to the surface whereas the annealed surface has Ni d bands that exhibit a three-dimensional-like structure. This is a result of the increased Ni d-Ag sp hybridization bonding and increased coordination of the embedded Ni nanoclusters. (c) 2000 American Vacuum Society

  6. Measurement and analyses of molten Ni-Co alloy density

    Institute of Scientific and Technical Information of China (English)

    XIAO Feng; K. MUKAI; FANG Liang; FU Ya; YANG Ren-hui

    2006-01-01

    With the advent of powerful mathematical modeling techniques for material phenomena, there is renewed interest in reliable data for the density of the Ni-based superalloys. Up to now, there has been few report on the density of molten Ni-Co alloy.In order to obtain more accurate density data for molten Ni-Co alloy, the density of molten Ni-Co alloy was measured with a modified sessile drop method, and the accommodation of different atoms in molten Ni-Co alloy was analyzed. The density of alloy is found to decrease with increasing temperature and Co concentration in the alloy. The molar volume of molten Ni-Co alloy increases with increasing Co concentration. The molar volume of Ni-Co alloy determined shows a positive deviation from the linear molar volume, and the deviation of molar volume from ideal mixing increases with increasing Co concentration over the experimental concentration range.

  7. In situ NiTi/Nb(Ti) composite

    International Nuclear Information System (INIS)

    Jiang, Daqiang; Cui, Lishan; Jiang, Jiang; Zheng, Yanjun

    2013-01-01

    Graphical abstract: - Highlights: • In situ NiTi/Nb(Ti) composites were fabricated. • The transformation temperature was affected by the mixing Ti:Ni atomic ratios. • The NiTi component became micron-scale lamella after forging and rolling. • The composite exhibited high strength and high damping capacity. - Abstract: This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTi–Nb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength

  8. Ni3d-Gd4f correlation effects on the magnetic behaviour of GdNi

    Energy Technology Data Exchange (ETDEWEB)

    Paulose, P L [Tata Inst. of Fundamental Research, Bombay (India); Patil, Sujata [Tata Inst. of Fundamental Research, Bombay (India); Mallik, R [Tata Inst. of Fundamental Research, Bombay (India); Sampathkumaran, E V [Tata Inst. of Fundamental Research, Bombay (India); Nagarajan, V [Tata Inst. of Fundamental Research, Bombay (India)

    1996-07-01

    The results of magnetization and heat-capacity measurements on the alloys, Gd{sub 1-x}Y{sub x}Ni (x=0.0, 0.25, 0.5, 0.75 and 0.9) are reported. The data suggest that there is a Gd induced magnetic moment on Ni, which may in turn enhance Gd-Gd exchange interaction strength in GdNi. The induced moment (on Ni) apparently exhibits itinerant ferromagnetism in the magnetically ordered state of GdNi. (orig.).

  9. Effects of Bond Coating on NiCrBSi-Mo Composite Functional Coating Properties in Plasma Spraying NiCrBSi-Mo/Ni Coating

    OpenAIRE

    DU Ji-yu; LI Fang-yi; LU Hai-yang; SHANG Jian-tong; LI Zhen

    2017-01-01

    Nickel-based bond coating and composite functional coating were sprayed on leaf blade steel material FV520B successively by using air plasma spraying system. NiCrBSi-Mo powder deposition rate, coating porosity, bonding strength and surface hardness were tested. The results indicate that, for the NiCrBSi-Mo/Ni coating, bond coating with 180-220μm thickness can improve NiCrBSi-Mo powder deposition rate while the surface coating with lower porosity, higher bonding strength and high hardness is p...

  10. Thermodynamic characterization of Ni3TeO6, Ni2Te3O8 and NiTe2O5

    Science.gov (United States)

    Dawar, Rimpi; Babu, R.; Ananthasivan, K.; Anthonysamy, S.

    2017-09-01

    Measurement of vapour pressure of TeO2(g) over the biphasic mixture Ni3TeO6 (s) + NiO(s) in the temperature range 1143-1272 K was carried out using transpiration-thermogravimetric technique (TTG). Gibbs energy of formation of Ni3TeO6 was obtained from the temperature dependence of vapour pressure of TeO2 (g) generated by the incongruent vapourisation reaction, Ni3TeO6 (s) → NiO(s) + TeO2 (g) + 1/2 O2 in the temperature range 1143-1272 K. An isoperibol type drop calorimeter was used to measure the enthalpy increments of Ni3TeO6, Ni2Te3O8 and NiTe2O5. Thermodynamic functions viz., heat capacity, entropy and Gibbs energy functions of these compounds were derived from the experimentally measured enthalpy increment values. Third-law analysis was carried out to ascertain absence of temperature dependent systematic errors in the measurement of vapour pressure of TeO2 (g). A value of -1265.1 ± 1.5 kJ mol-1 was obtained for Δ Hf,298K o (Ni3TeO6) using third-law analysis.

  11. Structural and magnetic properties of Ni-Zn and Ni-Zn-Co ferrites

    Energy Technology Data Exchange (ETDEWEB)

    Knyazev, A.V., E-mail: knyazevav@gmail.com [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Zakharchuk, I.; Lähderanta, E. [Lappeenranta University of Technology, P.O. Box 20, FI-53851 Lappeenranta (Finland); Baidakov, K.V.; Knyazeva, S.S. [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Ladenkov, I.V. [Joint-stock Company “Research and Production Company “Salut”, Nizhni Novgorod (Russian Federation)

    2017-08-01

    Highlights: • Ni-Zn and Ni-Zn-Co ferrite powders were prepared by the solid-state reaction at 1073 K. • The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. • The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. • The temperature dependences of magnetization exhibit large spin frustration and spin-glass-like behavior. - Abstract: Ni-Zn and Ni-Zn-Co ferrite powders with nominal compositions Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} were prepared by the solid-state reaction synthesis with periodic regrinding during the calcination at 1073 K. The structure of Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} was refined assuming space group F d-3m. Scanning electron microscopy revealed the average sizes of the crystalline ferrite particles are 130–630 nm for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 140–350 nm for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. The Curie temperature tends to increase upon Zn substitution by Co, as well. The temperature dependences of magnetization measured using zero-field cooled and field cooled protocols exhibit large spin frustration and spin-glass-like behavior.

  12. Anti-corrosive and anti-microbial properties of nanocrystalline Ni-Ag coatings

    Energy Technology Data Exchange (ETDEWEB)

    Raghupathy, Y.; Natarajan, K.A.; Srivastava, Chandan, E-mail: csrivastava@materials.iisc.ernet.in

    2016-04-15

    Graphical abstract: - Highlights: • Electrodeposition yielded phase-segregated, nanocrystalline Ni-Ag coatings. • Ni-Ag alloys exhibited smaller Ni crystals compared to pure Ni. • Ultra fine Ni grains of size 12–14 nm favoured Ni-Ag solid solution. • Nanocrystalline Ag resisted bio-fouling by Sulphate Reducing bacteria. • Ni-Ag outperformed pure Ni in corrosion and bio-corrosion tests. - Abstract: Anti-corrosive and anti-bacterial properties of electrodeposited nanocrystalline Ni-Ag coatings are illustrated. Pure Ni, Ni-7 at.% Ag, & Ni-14 at.% Ag coatings were electrodeposited on Cu substrate. Coating consisted of Ni-rich and Ag-rich solid solution phases. With increase in the Ag content, the corrosion resistance of the Ni-Ag coating initially increased and then decreased. The initial increase was due to the Ni-Ag solid solution. The subsequent decrease was due to the increased galvanic coupling between the Ag-rich and Ni-rich phases. For all Ag contents, the corrosion resistance of the Ni-Ag coating was higher than the pure Ni coating. Exposure to Sulphate Reducing Bacteria (SRB) revealed that the extent of bio-fouling decreased with increase in the Ag content. After 2 month exposure to SRB, the Ni-Ag coatings demonstrated less loss in corrosion resistance (58% for Ni-7 at.% Ag and 20% for Ni-14 at.% Ag) when compared pure Ni coating (115%).

  13. Niños y niñas como cuidadores familiares

    Directory of Open Access Journals (Sweden)

    María Rosa Estupiñán Aponte

    2015-01-01

    Full Text Available En el contexto familiar, el cuidado de otra persona por parte de niños y niñas constituye un terreno inexplorado tanto en su significado como en las implicaciones que podrían darse en el proceso. Aunque históricamente se ha asignado el cuidado familiar a las mujeres generando condiciones de inequidad, incrementada con los cambios sociales de los últimos tiempos, es necesario reconocer que en muchos hogares niños y niñas se han visto obligados a desempeñar esta labor sin la preparación ni las destrezas necesarias. Desde una perspectiva de género, el artículo busca evidenciar esta situación mediante la revisión de los abordajes que sobre el tema se han hecho en países de Europa y Norteamérica, así como el análisis de información obtenida a partir de las Encuestas de Hogares y Uso del Tiempo (EUT en algunos países de Latinoamérica. Se establece la forma como las problemáticas sociales inciden en las dinámicas, tipo de tareas y responsabilidades que deben asumir niños y niñas en los hogares, mostrando delgados límites entre la colaboración al interior de las familias, la transmisión cultural de roles y funciones y las actividades que podrían incidir negativamente en su crecimiento y el ejercicio de sus derechos.

  14. Estilos de vida saludables de niños, niñas y adolescentes

    Directory of Open Access Journals (Sweden)

    Lilia Campo-Ternera

    2017-01-01

    Full Text Available Objetivo: Describir los estilos de vida saludables de niños, niñas y adolescentes de Barranquilla. Materiales y métodos: Estudio descriptivo de corte transversal en 991 niños, niñas y ado - lescentes. Se evaluó la actividad física mediante los cuestionarios de Actividad Física para Adolescentes y para niños escolares; se aplicó una encuesta que midió los conocimientos y prácticas de los escolares sobre salud bucal, lavado de manos, consumo de frutas y verduras y cuidado postural; la Lista de Chequeo “Mi Vida en la Escuela”, la cual evalúa los índices de “bullying” y agresión; y la inteligencia emocional a través dela escala TMMS -24. Resultados: El 65,4 % se categoriza como inactivos físicamente. Solo el 14,7% de los estudiantes reconoce que el peso máximo del bolso es el 10 % de su peso corporal; el 34,1 % cambia el cepillo de dientes cada 3 meses, como lo recomiendan los expertos, y 48,4 % se cepilla los dientes entre 2 y 3 veces al día. El 16,6 % no se lava las manos antes y después de ir al baño y 9,4 % no lo hace antes y después de las comidas; el 17,5 % no tiene un buen consumo de verduras y frutas; y se encontró un Índice de “bullying” en el 55,6 % de los participantes. Conclusión: Los anteriores resultados obligan a plantear intervenciones que incrementen las prácticas saludables en niños, niñas y adolescentes.

  15. Electrochemical properties of the ball-milled LaMg10NiMn alloy with Ni powders

    International Nuclear Information System (INIS)

    Wang Yi; Wang Xin; Gao Xueping; Shen Panwen

    2008-01-01

    The electrochemical characteristics of the ball-milled LaMg 10 NiMn alloys with Ni powders were investigated. It was found that the ball-milled LaMg 10 NiMn + 150 wt.% Ni composite exhibited higher first discharge capacity and better cycle performance. By means of the analysis of electrochemical impedance spectra (EIS), it was shown that the existence of manganese in LaMg 10 NiMn alloy increased the electrocatalytic activity due to its catalytic effect, and destabilized metal hydrides, and so reduced the hydrogen diffusion resistance. These contributed to the higher discharge capacity of the ball-milled LaMg 10 NiMn-Ni composite. According to the analytical results of X-ray diffraction (XRD), EIS and steady-state polarization (SSP) experiments, the inhibition of metal corrosion is not the main reason for the better cycle performance. The main reason is that the electrochemical reaction resistance of the ball-milled LaMg 10 NiMn-Ni composite is always lower than that of the ball-milled LaMg 10 Ni 2 -Ni composite because the former one contains manganese, which is a catalyst for the electrode reaction

  16. High-frequency permeability of electroplated CoNiFe and CoNiFe-C alloys

    International Nuclear Information System (INIS)

    Rhen, Fernando M.F.; McCloskey, Paul; O'Donnell, Terence; Roy, Saibal

    2008-01-01

    We have investigated CoNiFe and CoNiFe-C electrodeposited by pulse reverse plating (PRP) and direct current (DC) techniques. CoNiFe(PRP) films with composition Co 59.4 Fe 27.7 Ni 12.8 show coercivity of 95 A m -1 (1.2 Oe) and magnetization saturation flux (μ 0 M s ) of 1.8 T. Resistivity of CoNiFe (PRP) is about 24 μΩ cm and permeability remains almost constant μ r ' ∼475 up to 30 MHz with a quality factor (Q) larger than 10. Additionally, the permeability spectra analysis shows that CoNiFe exhibits a classical eddy current loss at zero bias field and ferromagnetic resonance (FMR) when biased with 0.05 T. Furthermore, a crossover between eddy current and FMR loss is observed for CoNiFe-PRP when baised with 0.05 T. DC and PRP plated CoNiFe-C, which have resistivity and permeability of 85, 38 μΩ cm, μ r '=165 and 35 with Q>10 up to 320 MHz, respectively, showed only ferromagnetic resonance losses. The ferromagnetic resonance peaks in CoNiFe and CoNiFe-C are broad and resembles a Gaussian distribution of FMR frequencies. The incorporation of C to CoNiFe reduces eddy current loss, but also reduces the FMR frequency

  17. Corrosive sliding wear behavior of laser clad Mo2Ni3Si/NiSi intermetallic coating

    International Nuclear Information System (INIS)

    Lu, X.D.; Wang, H.M.

    2005-01-01

    Many ternary metal silicides such as W 2 Ni 3 Si, Ti 2 Ni 3 Si and Mo 2 Ni 3 Si with the topologically closed-packed (TCP) hP12 MgZn 2 type Laves phase crystal structure are expected to have outstanding wear and corrosion resistance due to their inherent high hardness and sluggish temperature dependence and strong atomic bonds. In this paper, Mo 2 Ni 3 Si/NiSi intermetallic coating was fabricated on substrate of an austenitic stainless steel AISI321 by laser cladding using Ni-Mo-Si elemental alloy powders. Microstructure of the coating was characterized by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive X-ray analysis (EDS). Wear resistance of the coating is evaluated under corrosive sliding wear test condition. Influence of corrosion solutions on the wear resistance of the coating was studied and the wear mechanism was discussed based on observations of worn surface morphology. Results showed that the laser clad Mo 2 Ni 3 Si/NiSi composite coating have a fine microstructure of Mo 2 Ni 3 Si primary dendrites and the interdendritic Mo 2 Ni 3 Si/NiSi eutectics. The coating has excellent corrosive wear resistance compared with austenitic stainless steel AISI321 under acid, alkaline and saline corrosive environments

  18. Magnetic properties of two new compounds: Pr2Ni3Si5 and Ho2Ni3Si5

    International Nuclear Information System (INIS)

    Mazumdar, C.; Padalia, B.D.; Godart, C.

    1994-01-01

    Formation of two more new materials, Pr 2 Ni 3 Si 5 and Ho 2 Ni 3 Si 5 , of the series, R 2 Ni 3 Si 5 (R = rare earth and Y) and their magnetic properties are reported here. These materials crystallize in the orthorhombic U 2 Co 3 Si 5 -type structure (space group Ibam). Magnetic susceptibility measurement in the temperature range 5 K--300 K show that the compound Pr 2 Ni 3 Si 5 order antiferromagnetically at T N ∼ 8.5 K and Ho 2 Ni 3 Si 5 at ∼ 6 K. Considering T N (Gd 2 Ni 3 Si 5 ) ∼ 15 K, T N (Pr 2 Ni 3 Si 5 ) ∼ 8.5 K is rather high. The magnetic susceptibility of both of the materials, in the paramagnetic state, follows a Curie-Weiss law with effective moment close to that of the corresponding free trivalent rare earth ion

  19. Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

    Directory of Open Access Journals (Sweden)

    Vladimir Linkov

    2013-07-01

    Full Text Available Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C, were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM, X-ray diffraction (XRD and X-ray photoelectron spectroscopy (XPS, and methanol oxidation activity compared using CV and chronoamperometry (CA. While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells.

  20. Hard X-ray MCD in GdNi/sub 5/ and TbNi/sub 5/ single crystals

    CERN Document Server

    Galera, R M

    1999-01-01

    XMCD experiments have been performed at the R L/sub 2,3/ and Ni K- edges on magnetically saturated single crystals of GdNi/sub 5/ and Tb Ni/sub 5/ ferromagnetic compounds. The spectra present huge and well structured dichroic $9 signals at both the R L/sub 2,3/ and the Ni K- edges. Structures from the quadrupolar (2p to 4f) transitions are clearly observed at the R L/sub 2,3/-edges. Though Ni is not magnetic, large intensities, up to 0.4, are measured at the $9 Ni K- edge. The Ni K-edge XMCD shows a three-peak structure which intensities dependent on the rare earth. (7 refs).

  1. Electrochemically induced transformation of NiS nanoparticles into Ni(OH)2 in KOH aqueous solution toward electrochemical capacitors

    International Nuclear Information System (INIS)

    Hou Linrui; Yuan Changzhou; Li Diankai; Yang Long; Shen Laifa; Zhang Fang; Zhang Xiaogang

    2011-01-01

    Highlights: → NiS is synthesized by means of the H 2 O/CS 2 interface under hydrothermal treatment. → NiS itself owns poor electrochemical capacitance in 2 M KOH solution. → NiS is electrochemically induced and transformed into electroactive Ni(OH) 2 . → Ni(OH) 2 is responsible for good energy storage of the NiS in the KOH solution. → The new formed Ni(OH) 2 delivers large energy density at high rates. - Abstract: Nickel sulfide nanoparticles (NPs) are first synthesized by virtue of a unique H 2 O/CS 2 interface under mild hydrothermal treatment. Electrochemical data reveals that the as-synthesized NiS NPs themselves own poor supercapacitive behavior at initial cyclic voltammetry (CV) cycles in 2 M KOH solution, while a specific capacitance of 893 F g -1 can be surprisingly obtained at a current density of 5 A g -1 just after continuous 320 CV cycles. X-ray diffraction and Fourier transform infrared techniques demonstrate that what is really responsible for the good electrochemical capacitance in the KOH aqueous solution is the new electrochemically formed Ni(OH) 2 phase, rather than NiS NPs themselves. The Ni(OH) 2 is slowly formed during the continuous CV cycling process, in which the electrochemically induced phase transformation from NiS to Ni(OH) 2 phase takes place. Furthermore, the new Ni(OH) 2 phase demonstrates the great ability of delivering large specific capacitance at high rates.

  2. Fe-Ni-bearing serpentines from the saprolite horizon of Caribbean Ni-laterite deposits: new insights from thermodynamic calculations

    Science.gov (United States)

    Villanova-de-Benavent, Cristina; Domènech, Cristina; Tauler, Esperança; Galí, Salvador; Tassara, Santiago; Proenza, Joaquín A.

    2017-10-01

    Fe-Ni-bearing serpentine from the saprolite horizon is the main Ni ores in hydrous silicate-type Ni laterites and formed by chemical weathering of partially serpentinized ultramafic rocks under tropical conditions. During lateritization, Mg, Si, and Ni are leached from the surface and transported downwards. Fe2+ is oxidized to Fe3+ and fixed as insoluble Fe-oxyhydroxides (mostly goethite) that incorporate Ni. This Ni is later leached from goethite and incorporated in secondary serpentine and garnierite. As a result, a serpentine-dominated saprolite horizon forms over the ultramafic protolith, overlapped by a Fe-oxyhydroxide-dominated limonite horizon. The serpentine from the protolith (serpentine I) is of hydrothermal origin and yields similar Ni (0.10-0.62 wt.% NiO) and lower Fe (mostly 1.37-5.81 wt.% FeO) concentrations than the primary olivine. In contrast, Fe-Ni-bearing serpentine from the saprolite (serpentine II) shows significantly higher and variable Fe and Ni contents, typically ranging from 2.23 to 15.59 wt.% Fe2O3 and from 1.30 to 7.67 wt.% NiO, suggesting that serpentine get enriched in Fe and Ni under supergene conditions. This study presents detailed mineralogical, textural, and chemical data on this serpentine II, as well as new insights by thermodynamic calculations assuming ideal solution between Fe-, Ni- and Mg-pure serpentines. The aim is to assess if at atmospheric pressure and temperature Fe-Ni-bearing serpentine can be formed by precipitation. Results indicate that the formation of serpentine II under atmospheric pressure and temperature is thermodynamically supported, and pH, Eh, and the equilibrium constant of the reaction are the parameters that affect the results more significantly.

  3. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Santella, M.L.; Alexander, D.J. [Oak Ridge National Laboratory, TN (United States)] [and others

    1995-05-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for (1)high-strength castable composition for turbochargers, furnace furniture, and hot-die applications; (2) castability (fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) hot fabricability of cast ingots. All of the issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes work completed to address some of these issues during the fourth quarter of FY 1994.

  4. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Viswanathan, S.; Santella, M.L. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, wire, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for: (1) high-strength castable composition for many applications that have been identified; (2) castability (mold type, fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) workability of cast or powder metallurgy product to sheet, bar, and wire. The four issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes the work completed to address some of these issues during FY 1996.

  5. Internal chlorination of Ni-Cr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Berztiss, D.; Hennesen, K.; Grabke, H.J. [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    1998-12-31

    In contrast to internal oxidation, sulfidation and carburization, very little information is available regarding internal chlorination, especially diffusion of chlorine in metallic alloys. This paper describes results of experiments on Ni-Cr alloys (<10 wt% Cr) exposed in an atmosphere containing radioactive HCl. The diffusion of chlorine in the alloy can be determined by measurement of residual {beta}-activity from the sample surface. Successively thin layers (0.5-10 {mu}m) of the alloy were removed by lapping and the surface activity was measured to obtain a depth profile. Both single and polycrystalline materials were tested. Through this work it should be determined if there is in fact solubility and diffusion of chlorine in Ni-based alloys as some authors have proposed or if the ingress of chlorine is mainly a grain boundary phenomenon. (orig.)

  6. Resonant Ni and Fe KLL Auger spectra photoexcited from NiFe alloys

    International Nuclear Information System (INIS)

    Koever, L.; Cserny, I.; Berenyi, Z.; Egri, S.; Novak, M.

    2005-01-01

    Complete text of publication follows. KLL Auger spectra of 3d transition metal atoms in solid environment, measured using high energy resolution, give an insight into the details of the local electronic structure surrounding the particular atoms emitting the signal Auger electrons. Fine tuning the energy of the exciting monochromatic photons across the K-absorption edge, features characteristic to resonant phenomena can be identified in the spectra. The shapes of the resonantly photoexcited KLL Auger spectra induced from 3d transition metals and alloys are well interpreted by the single step model of the Auger process, based on the resonant scattering theory. The peak shapes are strongly influenced by the 4p partial density of unoccupied electronic states around the excited atom. High energy resolution studies of KLL Auger spectra of 3d transition metals using laboratory X-ray sources, however, request very demanding experiments and yield spectra of limited statistical quality making the evaluation of the fine details in the spectra difficult. The Tunable High Energy XPS (THE- XPS) instrument at BW2 offers optimum photon x and energy resolution for spectroscopy of deep core Auger transitions. For the present measurements high purity polycrystalline Ni and Fe sheets as well as NiFe alloy samples of different compositions (Ni 80 Fe 20 , Ni 50 Fe 50 , Ni 20 Fe 80 ) were used. The surfaces of the samples were cleaned by in-situ argon ion sputtering. The measurements of the Ni and Fe KL 23 L 23 Auger spectra of the metal and alloy samples were performed with the THE-XPS instrument using high electron energy resolution (0.2 eV). In Fig.1, the measured Fe KL 23 L 23 spectrum, photoexcited at the Fe K absorption edge from Fe metal, is compared with the respective spectrum excited from a Ni 50 Fe 50 alloy. A significant broadening of the 1 D 2 peak and an enhancement of the spectral intensity at the low energy loss part of this peak observed in the alloy sample, while the

  7. Phase transitions in alloys of the Ni-Mo system

    International Nuclear Information System (INIS)

    Ustinovshikov, Y.; Shabanova, I.

    2011-01-01

    Graphical abstract: The structure of Ni-20 at.% Mo and Ni-25 at.% Mo alloys was studied by methods of TEM and XPS. It is shown that at high temperatures the tendency toward phase separation takes place in the alloys and crystalline bcc Mo particles precipitate in the liquid solution. At 900 deg. C and below, the tendency toward ordering leads to the dissolution of Mo particles and precipitation of the particles of Ni 3 Mo, Ni 2 Mo or Ni 4 Mo chemical compounds. Highlights: → 'Chemical' phase transition 'ordering-phase separation' is first discovered in alloys of the Ni-Mo system. → It is first shown that the phase separation in the alloys studied begins at temperatures above the liquidus one. → The formation of Ni 3 Mo from A1 has gone through the intervening stage of the Ni 4 Mo and Ni 2 Mo coexistence. - Abstract: The structure of Ni-20 at.% Mo and Ni-25 at.% Mo alloys heat treated at different temperatures was studied by the method of transmission electron microscopy. X-ray photoelectron spectroscopy was used to detect the sign of the chemical interaction between Ni and Mo atoms at different temperatures. It is shown that at high temperatures the tendency toward phase separation takes place. The system of additional reflections at positions {1 1/2 0} on the electron diffraction patterns testifies that the precipitation of crystalline bcc Mo particles begins in the liquid solution. At 900 deg. C and below, the tendency toward ordering leads to the precipitation of the particles of the chemical compounds. A body-centered tetragonal phase Ni 4 Mo (D1 a ) is formed in the Ni-20 at.% Mo alloy. In the Ni-25 at.% Mo alloy, the formation of the Ni 3 Mo (D0 22 ) chemical compound from the A1 solid solution has gone through the intervening stage of the Ni 4 Mo (D1 a ) and Ni 2 Mo (Pt 2 Mo) formation.

  8. Combining Ru, Ni and Ni(OH){sub 2} active sites for improving catalytic performance in benzene hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Lihua, E-mail: lihuazhu@stu.xmu.edu.cn [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Sun, Hanlei; Zheng, Jinbao [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Yu, Changlin, E-mail: yuchanglinjx@163.com [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Zhang, Nuowei [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Shu, Qing [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Chen, Bing H., E-mail: chenbh@xmu.edu.cn [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)

    2017-05-01

    In this study, the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were successfully prepared by the simple methods of hydrazine-reduction and galvanic replacement, where 0.04/0.96 and T represented the Ru/Ni atomic ratio and reducing temperature of the catalyst in N{sub 2}+10%H{sub 2}, respectively. The nanostructures of the Ru{sub 0.04}Ni{sub 0.96} nanoparticles in the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were controlled by modulating their annealing temperature in N{sub 2}+10%H{sub 2} and characterized by an array of techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), scanning transmission electron microscopy energy dispersive X-ray spectroscopy (STEM-EDS) mapping and high-sensitivity low-energy ion scattering (HS-LEIS). The Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, which was composed of Ru clusters or single atoms supported on Ni/Ni(OH){sub 2} nanoparticles, exhibited much better catalytic performance for benzene hydrogenation than the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts reduced at above 30 °C, such as Ru{sub 0.04}Ni{sub 0.96}/C(160) with the nanostructure of partial Ru{sub 0.04}Ni{sub 0.9} alloy and Ru{sub 0.04}Ni{sub 0.96}/C(280) with the nanostructure of complete Ru{sub 0.04}Ni{sub 0.9} alloy. The reason was that the synergistic effect of multiple active sites – Ru, Ni and Ni(OH){sub 2} sites was present in the Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, where hydrogen was preferentially activated at Ru sites, benzene was probably activated at Ni(OH){sub 2} surface and Ni acted as a “bridge” for transferring activated H{sup ∗} species to activated benzene by hydrogen spillover effect, hydrogenating and forming product – cyclohexane. This study also provided a typical example to illustrate that the synergy effect of multiple active sites can largely improve the catalytic hydrogenation performance. - Highlights: • The Ru

  9. Imaging magnetic domains in Ni nanostructures

    International Nuclear Information System (INIS)

    Asenjo, A.; Jaafar, M.; Gonzalez, E.M.; Martin, J.I.; Vazquez, M.; Vicent, J.L.

    2007-01-01

    The study of nanomagnets is the subject of increasing scientific effort. The size, the thickness and the geometric shape of the elements determine the magnetic properties and then the domain configuration. In this work, we fabricated by electron-beam lithography the three different arrays of Ni nanostructures keeping the size, the thickness and also the distance constant between the elements but varying the geometry: square, triangular and circular. The domain structure of the nanomagnets is studied by magnetic force microscopy

  10. Determination of 59Ni in radioactive waste

    International Nuclear Information System (INIS)

    Fisera, O.; Sebesta, F.

    2010-01-01

    Composite material PAN-DMG, containing chelating agent dimethylglyoxime (DMG) immobilized in porous matrix of binding polymer polyacrylonitrile (PAN), was used for nickel separation and concentration. Method for preparation of 59 Ni source for low energy photon spectrometry was developed using homogeneous precipitation of nickel with DMG. The proposed method was tested with two types of real radioactive waste (boric acid concentrate from nuclear power plant (NPP) evaporator and spent ion exchanger from NPP). (author)

  11. Structural, electrical and magnetic properties of evaporated Ni/Cu and Ni/glass thin films

    Energy Technology Data Exchange (ETDEWEB)

    Nacereddine, C. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Layadi, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria)]. E-mail: A_Layadi@yahoo.fr; Guittoum, A. [Centre de Recherche Nucleaire d' Alger (CRNA), Alger 16000 (Algeria); Cherif, S.-M. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Chauveau, T. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Billet, D. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Youssef, J. Ben [Laboratoire de Magnetisme de Bretagne, U.B.O., Brest 29238 (France); Bourzami, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Bourahli, M.-H. [Departement d' O. M. P., Universite Ferhat Abbas, Setif 19000 (Algeria)

    2007-01-25

    The structural, electrical and magnetic properties of Ni thin films evaporated onto glass and polycrystalline Cu substrates have been investigated. The Ni thickness ranges from 31 to 165 nm. X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM) have been used to study the structure and morphology of these systems. The Ni/Cu and Ni/glass thin films are found to be polycrystalline with a (1 1 1) texture. There is an overall increase of the grain size with increasing thickness. A negative strain was noted indicating that all the samples are under a compressive stress. Diffusion at the grain boundaries seems to be a major contribution to the electrical resistivity in this thickness range. Study of the hysteresis curves, obtained by vibrating sample magnetometer (VSM), indicates that all samples are characterized by an in-plane magnetization easy axis. Higher in-plane coercive fields seem to be associated with higher grain size, indicating that coercivity may be due to nucleation of reverse domains rather than pinning of domain walls. The saturation field and the squareness have been studied as a function of the Ni thickness.

  12. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-10-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  13. HDO of Methyl Palmitate over Silica-Supported Ni Phosphides: Insight into Ni/P Effect

    Directory of Open Access Journals (Sweden)

    Irina V. Deliy

    2017-10-01

    Full Text Available Two sets of silica-supported nickel phosphide catalysts with a nickel content of about 2.5 and 10 wt % and Ni/P molar ratio 2/1, 1/1 and 1/2 in each set, were prepared by way of a temperature-programmed reduction method using (Ni(CH3COO2 and ((NH42HPO4 as a precursor. The NixPy/SiO2 catalysts were characterized using chemical analysis N2 physisorption, XRD, TEM, 31P MAS NMR. Methyl palmitate hydrodeoxygenation (HDO was performed in a trickle-bed reactor at 3 MPa and 290 °C with LHSV ranging from 0.3 to 16 h−1. The Ni/P ratio was found to affect the nickel phosphide phase composition, POx groups content and catalytic properties in methyl palmitate HDO with the TOF increased along with a decline of Ni/P ratio and a growth of POx groups’ content. Taking into account the possible routes of methyl palmitate conversion (metal-catalyzed hydrogenolysis or acid-catalyzed hydrolysis, we proposed that the enhancement of acid POx groups’ content with the Ni/P ratio decrease provides an enhancement of the rate of methyl palmitate conversion through the acceleration of acid-catalyzed hydrolysis.

  14. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-01-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  15. Tungsten inert gas (TIG) welding of Ni-rich NiTi plates: functional behavior

    Science.gov (United States)

    Oliveira, J. P.; Barbosa, D.; Braz Fernandes, F. M.; Miranda, R. M.

    2016-03-01

    It is often reported that, to successfully join NiTi shape memory alloys, fusion-based processes with reduced thermal affected regions (as in laser welding) are required. This paper describes an experimental study performed on the tungsten inert gas (TIG) welding of 1.5 mm thick plates of Ni-rich NiTi. The functional behavior of the joints was assessed. The superelasticity was analyzed by cycling tests at maximum imposed strains of 4, 8 and 12% and for a total of 600 cycles, without rupture. The superelastic plateau was observed, in the stress-strain curves, 30 MPa below that of the base material. Shape-memory effect was evidenced by bending tests with full recovery of the initial shape of the welded joints. In parallel, uniaxial tensile tests of the joints showed a tensile strength of 700 MPa and an elongation to rupture of 20%. The elongation is the highest reported for fusion-welding of NiTi, including laser welding. These results can be of great interest for the wide-spread inclusion of NiTi in complex shaped components requiring welding, since TIG is not an expensive process and is simple to operate and implement in industrial environments.

  16. High resolution TEM study of Ni4Ti3 precipitates in austenitic Ni51Ti49

    International Nuclear Information System (INIS)

    Tirry, Wim; Schryvers, Dominique

    2003-01-01

    Binary NiTi with a composition of 51 at.% Ni was heat treated to form lens-shaped Ni 4 Ti 3 precipitates that are coherent or semi-coherent with the B2 matrix. High resolution transmission electron microscopy (HRTEM) was used to study the internal structure of the precipitates, precipitate-precipitate and matrix-precipitate interfaces and the deformation of the B2 matrix near a precipitate. Observations were made in the B2 and B2 zones and compared with computer simulated high resolution images. The B2 observations made it possible to study the [0 0 1] H zone orientation of Ni 4 Ti 3 (direction defined according to the hexagonal unit cell of Ni 4 Ti 3 ) which corresponds to the normal of the central plane of the discs. In these images the superperiodicity of the 4:3 ordering is clearly visible confirming the known atomic structure. Close to the precipitate the B2 matrix is deformed, as determined by measuring the interplanar spacing from the HRTEM images. The observed deformations are compared with theoretical models for the stress field

  17. Breakdown of antiferromagnet order in polycrystalline NiFe/NiO bilayers probed with acoustic emission

    Science.gov (United States)

    Lebyodkin, M. A.; Lebedkina, T. A.; Shashkov, I. V.; Gornakov, V. S.

    2017-07-01

    Magnetization reversal of polycrystalline NiFe/NiO bilayers was investigated using magneto-optical indicator film imaging and acoustic emission techniques. Sporadic acoustic signals were detected in a constant magnetic field after the magnetization reversal. It is suggested that they are related to elastic waves excited by sharp shocks in the NiO layer with strong magnetostriction. Their probability depends on the history and number of repetitions of the field cycling, thus testifying the thermal-activation nature of the long-time relaxation of an antiferromagnetic order. These results provide evidence of spontaneous thermally activated switching of the antiferromagnetic order in NiO grains during magnetization reversal in ferromagnet/antiferromagnet (FM/AFM) heterostructures. The respective deformation modes are discussed in terms of the thermal fluctuation aftereffect in the Fulcomer and Charap model which predicts that irreversible breakdown of the original spin orientation can take place in some antiferromagnetic grains with disordered anisotropy axes during magnetization reversal of exchange-coupled FM/AFM structures. The spin reorientation in the saturated state may induce abrupt distortion of isolated metastable grains because of the NiO magnetostriction, leading to excitation of shock waves and formation of plate (or Lamb) waves.

  18. Electric Monopole Transition Strengths in 62Ni

    Directory of Open Access Journals (Sweden)

    Evitts L. J.

    2016-01-01

    Full Text Available Excited states in 62Ni were populated with a (p, p’ reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0, were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77−34+23 × 10−3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0 value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0 values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0 value for the 22+ to 21+ transition.

  19. Electric Monopole Transition Strengths in 62Ni

    Science.gov (United States)

    Evitts, L. J.; Garnsworthy, A. B.; Kibédi, T.; Moukaddam, M.; Alshahrani, B.; Eriksen, T. K.; Holt, J. D.; Hota, S. S.; Lane, G. J.; Lee, B. Q.; McCormick, B. P.; Palalani, N.; Reed, M. W.; Stroberg, S. R.; Stuchbery, A. E.

    2016-09-01

    Excited states in 62Ni were populated with a (p, p') reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0), were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77-34+23 × 10-3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0) value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0) values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0) value for the 22+ to 21+ transition.

  20. Length-dependent corrosion behavior, Ni2+ release, cytocompatibility, and antibacterial ability of Ni-Ti-O nanopores anodically grown on biomedical NiTi alloy.

    Science.gov (United States)

    Hang, Ruiqiang; Liu, Yanlian; Bai, Long; Zhang, Xiangyu; Huang, Xiaobo; Jia, Husheng; Tang, Bin

    2018-08-01

    In the present work, nickel-titanium-oxygen nanopores with different length (0.55-114 μm) were anodically grown on nearly equiatomic nickel-titanium (NiTi) alloy. Length-dependent corrosion behavior, nickel ion (Ni 2+ ) release, cytocompatibility, and antibacterial ability were investigated by electrochemical, analytical chemistry, and biological methods. The results show constructing nanoporous structure on the NiTi alloy improve its corrosion resistance. However, the anodized samples release more Ni 2+ than that of the bare NiTi alloy, suggesting chemical dissolution of the nanopores rather than electrochemical corrosion governs the Ni 2+ release. In addition, the Ni 2+ release amount increases with nanopore length. The anodized samples show good cytocompatibility when the nanopore length is covers the one (1-11 μm) that the nanopores showing favorable antibacterial ability. Consequently, the nanopores with length in the range of 1-11 μm are promising as coatings of biomedical NiTi alloy for anti-infection, drug delivery, and other desirable applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  1. Effects of P/Ni ratio and Ni content on performance of γ-Al_2O_3-supported nickel phosphides for deoxygenation of methyl laurate to hydrocarbons

    International Nuclear Information System (INIS)

    Zhang, Zhena; Tang, Mingxiao; Chen, Jixiang

    2016-01-01

    Graphical abstract: - Highlights: • The formation of AlPO_4 was unfavorable for that of nickel phosphides. • The phase compositions of nickel phosphide depended on the amount of reduced P. • Catalytic activity was determined by surface Ni site density and catalyst acidity. • HDO pathway was promoted by increasing P/Ni ratio and Ni content. • Nickel phosphide gave much higher carbon yield and lower H_2 consumption than Ni. - Abstract: γ-Al_2O_3-supported nickel phosphides (mNi-Pn) were prepared by the TPR method and tested for the deoxygenation of methyl laurate to hydrocarbons. The effects of the P/Ni ratio (n = 1.0–2.5) and Ni content (m = 5–15 wt.%) in the precursors on their structure and performance were investigated. Ni/γ-Al_2O_3 was also studied for comparison. It was found that the formation of AlPO_4 in the precursor inhibited the reduction of phosphate and so the formation of nickel phosphides. With increasing the P/Ni ratio and Ni content, the Ni, Ni_3P, Ni_1_2P_5 and Ni_2P phases orderly formed, accompanying with the increases of their particle size and the amount of weak acid sites (mainly due to P-OH group), while the CO uptake and the amount of medium strong acid sites (mainly related to Ni sites) reached maximum on 10%Ni-P1.5. In the deoxygenation reaction, compared with Ni/γ-Al_2O_3, the mNi-Pn catalysts showed much lower activities for decarbonylation, C−C hydrogenolysis and methanation due to the ligand and ensemble effects of P. The conversion and the selectivity to n-C11 and n-C12 hydrocarbons achieved maximum on 10%Ni-P 2.0 for the 10%Ni-Pn catalysts and on 8%Ni-P2.0 for the mNi-P2.0 catalysts, while the turnover frequency (TOF) of methyl laurate mainly increased with the P/Ni ratio and Ni content. We propose that TOF was influenced by the nickel phosphide phases, the catalyst acidity and the particle size as well as the synergetic effect between the Ni site and acid site. Again, the hydrodeoxygenation pathway of methyl

  2. Level structure of 60Ni from the 58Ni(α,2p#betta#) reaction

    International Nuclear Information System (INIS)

    Chan, T.U.; Morand, C.; Azgui, F.

    1982-03-01

    The 60 Ni nucleus has been studied via the 58 Ni (α, 2p#betta#) reaction at Esub(α)=32 MeV using in-beam #betta# spectroscopy techniques. High-spin states up to 10 MeV excitation have been established. Among the 5 branches depopulating the Yrast Jsup(π)=7 - state, has been found an E3 transition down to the 4 + state. Comparison with direct reaction results leads to assign very probably the [#betta#fsub(5/2),#betta#gsub(9/2)] 7 - configuration to the Jsup(π)=7 - Yrast state at 5349 keV. Other high-spin states might be accounted for by the breaking of the 56 Ni core

  3. Atomistic simulation of the pinning of edge dislocations in Ni by Ni3Al precipitates

    International Nuclear Information System (INIS)

    Kohler, Christopher; Kizler, Peter; Schmauder, Siegfried

    2005-01-01

    Classical molecular dynamics simulations of the interaction of edge dislocations in Ni with chains of spherical Ni 3 Al precipitates are performed using EAM potentials. The order hardening is investigated at temperature T=0 -bar K by determining the critical resolved shear stresses (CRSSs) for a superdislocation that is dissociated into four partial dislocations. The CRSS is computed as a function of the radius and the distance of the precipitates. It is found that for precipitates with a diameter smaller than the dissociation width of perfect edge dislocation in Ni, the CRSS of the trailing dislocation of the superdislocation is a fraction of about 0.4 of the CRSS of the leading dislocation

  4. Sorption properties of new composite materials suitable for radioanalytical determination of 59-Ni and 63-Ni

    International Nuclear Information System (INIS)

    Fisera, O.; Sebesta, F.

    2006-01-01

    New composite materials for separation and radioanalytical determination of radionickel ( 59, 63 Ni) were prepared and their sorption properties were examined. Chelating agents dimethylglyoxime (DMG) and diphenylglyoxime (DFG) as active components were immobilized in porous matrix of binding polymer polyacrylonitrile (PAN). Sorption properties of these materials were compared with commercial Ni Resin (Eichrom Technologies, USA). Weight distribution ratios, sorption kinetics and operating capacities were investigated during experiments performed. The highest weight distribution ratios were found for the material DFG-PAN. The sorbent DMG-PAN has the highest operating capacity. The fastest kinetics of nickel sorption was determined for the commercial Ni Resin. Elution of nickel with nitric acid solution allows subsequent and direct determination of radionickel by liquid scintillation counting. (author)

  5. Effect of amorphous Mg50Ni50 on hydriding and dehydriding behavior of Mg2Ni alloy

    International Nuclear Information System (INIS)

    Guzman, D.; Ordonez, S.; Fernandez, J.F.; Sanchez, C.; Serafini, D.; Rojas, P.A.; Aguilar, C.; Tapia, P.

    2011-01-01

    Composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 was prepared by mechanical milling starting with nanocrystalline Mg 2 Ni and amorphous Mg 50 Ni 50 powders, by using a SPEX 8000 D mill. The morphological and microstructural characterization of the powders was performed via scanning electron microscopy and X-ray diffraction. The hydriding characterization of the composite was performed via a solid gas reaction method in a Sievert's-type apparatus at 363 K under an initial hydrogen pressure of 2 MPa. The dehydriding behavior was studied by differential thermogravimetry. On the basis of the results, it is possible to conclude that amorphous Mg 50 Ni 50 improved the hydriding and dehydriding kinetics of Mg 2 Ni alloy upon cycling. A tentative rationalization of experimental observations is proposed. - Research Highlights: → First study of the hydriding behavior of composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 . → Microstructural characterization of composite material using XRD and SEM was obtained. → An improved effect of Mg 50 Ni 50 on the Mg 2 Ni hydriding behavior was verified. → The apparent activation energy for the hydrogen desorption of composite was obtained.

  6. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting.

    Science.gov (United States)

    Wang, Dewen; Li, Qun; Han, Ce; Xing, Zhicai; Yang, Xiurong

    2018-01-24

    The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS 2 nanosheet array on carbon cloth (NiO@Ni/WS 2 /CC) composite. This composite serves as a unique three-dimensional (3D) synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS 2 , but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS 2 . This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO 2 , as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm -2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS 2 . Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  7. Impact of Interstitial Ni on the Thermoelectric Properties of the Half-Heusler TiNiSn

    Directory of Open Access Journals (Sweden)

    Sonia A. Barczak

    2018-03-01

    Full Text Available TiNiSn is an intensively studied half-Heusler alloy that shows great potential for waste heat recovery. Here, we report on the structures and thermoelectric properties of a series of metal-rich TiNi1+ySn compositions prepared via solid-state reactions and hot pressing. A general relation between the amount of interstitial Ni and lattice parameter is determined from neutron powder diffraction. High-resolution synchrotron X-ray powder diffraction reveals the occurrence of strain broadening upon hot pressing, which is attributed to the metastable arrangement of interstitial Ni. Hall measurements confirm that interstitial Ni causes weak n-type doping and a reduction in carrier mobility, which limits the power factor to 2.5–3 mW m−1 K−2 for these samples. The thermal conductivity was modelled within the Callaway approximation and is quantitively linked to the amount of interstitial Ni, resulting in a predicted value of 12.7 W m−1 K−1 at 323 K for stoichiometric TiNiSn. Interstitial Ni leads to a reduction of the thermal band gap and moves the peak ZT = 0.4 to lower temperatures, thus offering the possibility to engineer a broad ZT plateau. This work adds further insight into the impact of small amounts of interstitial Ni on the thermal and electrical transport of TiNiSn.

  8. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    D’Addato, S., E-mail: sergio.daddato@unimore.it [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Spadaro, M.C. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Luches, P. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Grillo, V. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); CNR-IMEM, Parco Area delle Scienze 37/A, 43100 Parma (Italy); Frabboni, S.; Valeri, S. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Ferretti, A.M.; Capetti, E.; Ponti, A. [CNR-ISTM, Laboratorio di Nanotecnologie, via G. Fantoli 16/15, 20138 Milano (Italy)

    2014-07-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  9. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting

    Directory of Open Access Journals (Sweden)

    Dewen Wang

    2017-12-01

    Full Text Available The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER and oxygen evolution reaction (OER is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS2 nanosheet array on carbon cloth (NiO@Ni/WS2/CC composite. This composite serves as a unique three-dimensional (3D synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS2, but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS2. This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO2, as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm–2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS2. Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  10. Enhanced optical and electrical properties of Ni inserted ITO/Ni/AZO tri-layer structure for photoelectric applications

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, M. Melvin David; Kim, Hyunki [Department of Electrical Engineering, Incheon National University, Incheon 406772 (Korea, Republic of); Park, Yun Chang [Measurement and Analysis Division, National Nanofab Center (NNFC), Daejeon 305-806 (Korea, Republic of); Kim, Joondong, E-mail: joonkim@incheon.ac.kr [Department of Electrical Engineering, Incheon National University, Incheon 406772 (Korea, Republic of)

    2015-05-15

    Highlights: • Ni-embedding transparent conductor effectively reduces the resistivity. • Ni insertion improves the carrier mobility and collection efficiencies. • ITO/Ni/AZO is effective to improve photo-responses compared to ITO/AZO. - Abstract: A thin Ni layer of 5 nm thickness was deposited in between indium-tin-oxide (ITO) and aluminum-doped-zinc oxide (AZO) layers of 50 nm thickness each. The Ni inserting tri-layer structure (ITO/Ni/AZO) showed lower resistivity of 5.51 × 10{sup −4} Ωcm which is nearly 20 times lesser than 97.9 × 10{sup −4} Ωcm of bilayer structure (ITO/AZO). A thin Ni layer in between ITO and AZO enhanced the carrier concentration, mobility and photoresponse behaviors so that figure of merit (FOM) value of ITO/Ni/AZO device was greater than that of ITO/AZO device. ITO/Ni/AZO structure showed improved quantum efficiencies over a broad range of wavelengths (∼350–950 nm) compared to that of ITO/AZO bilayer structure, resulting in enhanced photoresponses. These results show that the optical, electrical and photoresponse properties of ITO/AZO structure could be enhanced by inserting Ni layer of 5 nm thickness in between ITO and AZO layers.

  11. On the Ni-Ion release rate from surfaces of binary NiTi shape memory alloys

    Science.gov (United States)

    Ševčíková, Jana; Bártková, Denisa; Goldbergová, Monika; Kuběnová, Monika; Čermák, Jiří; Frenzel, Jan; Weiser, Adam; Dlouhý, Antonín

    2018-01-01

    The study is focused on Ni-ion release rates from NiTi surfaces exposed in the cell culture media and human vascular endothelial cell (HUVEC) culture environments. The NiTi surface layers situated in the depth of 70 μm below a NiTi oxide scale are affected by interactions between the NiTi alloys and the bio-environments. The finding was proved with use of inductively coupled plasma mass spectrometry and electron microscopy experiments. As the exclusive factor controlling the Ni-ion release rates was not only thicknesses of the oxide scale, but also the passivation depth, which was two-fold larger. Our experimental data strongly suggested that some other factors, in addition to the Ni concentration in the oxide scale, admittedly hydrogen soaking deep below the oxide scale, must be taken into account in order to rationalize the concentrations of Ni-ions released into the bio-environments. The suggested role of hydrogen as the surface passivation agent is also in line with the fact that the Ni-ion release rates considerably decrease in NiTi samples that were annealed in controlled hydrogen atmospheres prior to bio-environmental exposures.

  12. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    International Nuclear Information System (INIS)

    D’Addato, S.; Spadaro, M.C.; Luches, P.; Grillo, V.; Frabboni, S.; Valeri, S.; Ferretti, A.M.; Capetti, E.; Ponti, A.

    2014-01-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  13. Distorted-wave calculations of electron impact ionisation in the Ni isonuclear sequence

    Energy Technology Data Exchange (ETDEWEB)

    Griffin, D C; Pindzola, M S

    1988-10-14

    Electron impact ionisation cross sections for Ni/sup +/, Ni/sup 3+/, Ni/sup 5+/, Ni/sup 6+/, Ni/sup 7+/, Ni/sup 8+/, Ni/sup 12+/, Ni/sup 14+/, and Ni/sup 16+/ are calculated in the distorted-wave approximation. These calculations include contributions from direct ionisation and inner-shell excitation followed by autoionisation. For Ni/sup 12+/, Ni/sup 14+/, and Ni/sup 16+/ we report not only on ionisation cross sections from the ground states but also from the metastable states of these ions. Experimental cross section measurements exist for all ions reported here, except Ni/sup 16+/. The agreement between experiment and theory is reasonably good and improves with ionisation stage.

  14. NiTiCu/AlN/NiTiCu shape memory thin film heterostructures for vibration damping in MEMS

    Energy Technology Data Exchange (ETDEWEB)

    Kaur, Navjot; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in

    2014-03-25

    Highlights: • Fabrication of NiTiCu/AlN/NiTiCu heterostructure using dc/rf magnetron sputtering. • Exhibits highest hardness (38 GPa) and elastic modulus (187 GPa). • Enhanced dissipation of mechanical energy (E{sub d} = 5.7 N J). • High damping capacity (0.052) and figure of merit (∼0.62). • Can be applied for vibration damping in MEMS. -- Abstract: Shape memory alloy (NiTiCu) thin films coupled with piezoelectric AlN layer produce an intelligent material for vibration damping. In the present study pure NiTiCu, NiTiCu/AlN and NiTiCu/AlN/NiTiCu heterostructures have been deposited on Si substrate using magnetron sputtering technique. By the use of the interfaces and shape memory effect provided by NiTiCu layers, the damping capacity can be increased along with increase in stiffness and mechanical hardness. The heterostructures were characterized in terms of structural, electrical, morphological and mechanical properties by X-ray diffraction (XRD), four probe resistivity method, atomic force microscopy, field emission scanning electron microscopy, and nanoindentation. The NiTiCu/AlN/NiTiCu heterostructure exhibit enhanced mechanical and damping properties as compared to NiTiCu/AlN and pure NiTiCu. This enhancement in hardness and damping of the heterostructure could be attributed to the shape memory effect of NiTiCu, intrinsic piezoelectricity of AlN and increased number of interfaces in heterostructure that help in dissipation of mechanical vibrations. The findings of this work provide additional impetus for the application of these heterostructures in emerging fields of nanotechnology and microelectro mechanical (MEMS) devices.

  15. NiTiCu/AlN/NiTiCu shape memory thin film heterostructures for vibration damping in MEMS

    International Nuclear Information System (INIS)

    Kaur, Navjot; Kaur, Davinder

    2014-01-01

    Highlights: • Fabrication of NiTiCu/AlN/NiTiCu heterostructure using dc/rf magnetron sputtering. • Exhibits highest hardness (38 GPa) and elastic modulus (187 GPa). • Enhanced dissipation of mechanical energy (E d = 5.7 N J). • High damping capacity (0.052) and figure of merit (∼0.62). • Can be applied for vibration damping in MEMS. -- Abstract: Shape memory alloy (NiTiCu) thin films coupled with piezoelectric AlN layer produce an intelligent material for vibration damping. In the present study pure NiTiCu, NiTiCu/AlN and NiTiCu/AlN/NiTiCu heterostructures have been deposited on Si substrate using magnetron sputtering technique. By the use of the interfaces and shape memory effect provided by NiTiCu layers, the damping capacity can be increased along with increase in stiffness and mechanical hardness. The heterostructures were characterized in terms of structural, electrical, morphological and mechanical properties by X-ray diffraction (XRD), four probe resistivity method, atomic force microscopy, field emission scanning electron microscopy, and nanoindentation. The NiTiCu/AlN/NiTiCu heterostructure exhibit enhanced mechanical and damping properties as compared to NiTiCu/AlN and pure NiTiCu. This enhancement in hardness and damping of the heterostructure could be attributed to the shape memory effect of NiTiCu, intrinsic piezoelectricity of AlN and increased number of interfaces in heterostructure that help in dissipation of mechanical vibrations. The findings of this work provide additional impetus for the application of these heterostructures in emerging fields of nanotechnology and microelectro mechanical (MEMS) devices

  16. Three-dimensional electrode of Ni/Co layered double hydroxides@NiCo2S4@graphene@Ni foam for supercapacitors with outstanding electrochemical performance

    International Nuclear Information System (INIS)

    Tao, Yan; Ruiyi, Li; Lin, Zhou; Chenyang, Ma; Zaijun, Li

    2015-01-01

    We reported a new strategy for fabricating three-dimensiona electrode of Ni/Co layered double hydroxide@NiCo 2 S 4 @graphene@Ni foam for supercapacitors. The resulting 3D electrode offers a jungle-like architecture. The unique structure creates ultra fast electron transfer and electrolyte transport as well as the maximum utilization rate of the space and the surface. The electrode exhibits a prominent advantage of high specific capacitance, high-current capacitive behaviour and cycle stability. - Highlights: • The study developed a new strategy for fabricating 3D electrode of Ni/Co-LDH@NiCo 2 S 4 @G. • The as-prepared 3D electrode offers a jungle-like architecture. • The unique structure creates an efficient conduction network and high mass loading. • The electrode achieves significantly synergetic effect among different materials. • The electrode exhibits an excellent electrochemical performance for supercapacitors. - ABSTRACT: Great challenge for the fabrication of free-standing three-dimensional electrode still remains to simultaneously achieve high specific capacitance, rate performance and cycle stability. The paper reprted a new three-dimensional (3D) electrode of Ni/Co layered double hydroxide@NiCo 2 S 4 @graphene@Ni foam (Ni/Co-LDH@NiCo 2 S 4 @G) for supercapacitors. The as-prepared 3D electrode offers an unique architecture, which create an efficient conduction network and maximum utilization of space and interface. The graphene acts as well-knit and conductive skin coated on the skeleton of Ni foam for growing NiCo 2 S 4 . The conductive NiCo 2 S 4 array serves as bridge between Ni/Co-LDH and graphene, leading to ultrafast electron transfer and electrolyte transport. A slew of splits and holes existing in the NiCo 2 S 4 array play one role as the ion-reservoir to contain host of electrolyte ions. To evaluate the feasibility of 3D electrode’s application in supercapacitors, the electrochemical performance was investigated by using the three

  17. Energetic Mapping of Ni Catalysts by Detailed Kinetic Modeling

    DEFF Research Database (Denmark)

    Bjørgum, Erlend; Chen, De; Bakken, Mari G.

    2005-01-01

    Temperature-programmed desorption (TPD) of CO has been performed on supported and unsupported nickel catalysts. The unsupported Ni catalyst consists of a Ni(14 13 13) single crystal which has been studied under ultrahigh vacuum conditions. The desorption energy for CO at low CO surface coverage...... was found to be 119 kJ/mol, and the binding energy of C to the Ni(111) surface of the crystal was 703 kJ/mol. The supported catalysts consist of nickel supported on hydrotalcite-like compounds with three different Mg2+/Al3+ ratios. The experimental results show that for the supported Ni catalysts TPD of CO...... precursor seems to result in more steplike sites, kinks, and defects for carbon monoxide dissociation. A detailed kinetic modeling of the TPO results based on elementary reaction steps has been conducted to give an energetic map of supported Ni catalysts. Experimental results from the ideal Ni surface fit...

  18. Synthesis of electroplated {sup 63}Ni source and betavoltaic battery

    Energy Technology Data Exchange (ETDEWEB)

    Uhm, Young Rang; Yoo, Kwon Mo; Choi, Sang Mu; Kim, Jin Joo; Son, Kwang Jae [Radioisotope Research Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-12-15

    Radioisotope (Nuclear) battery using {sup 63}Ni was prepared as beta cell. The electroplated {sup 63}Ni on Ni foil is fabricated, and beta cell and photovoltaic hybrid battery was designed to use at both day and night in space project. A Ni-plating solution is prepared by dissolving metal particles including {sup 62}Ni and {sup 63}Ni from neutron irradiation of (n,γ). Electroplating solution of a chloride bath consists on nickel ions in HCl, H{sub 3}BO{sub 3}, and KOH. The deposition was carried out at current density of 10 mA cm{sup -2}. The prepared beta source was attached on a PN junction and measured I-V properties. The power output at activity of 0.07 mCi and 0.45 mCi were 0.55 pW and 2.69 nW, respectively.

  19. Microstructure and martensitic transformation of Ni-Ti-Pr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Chunwang [Inner Mongolia University of Technology, College of Science, Hohhot (China); Shanghai Maritime University, College of Arts and Sciences, Shanghai (China); Zhao, Shilei; Jin, Yongjun; Hou, Qingyu [Inner Mongolia University of Technology, College of Science, Hohhot (China); Guo, Shaoqiang [Beihang University, Key Laboratory of Micro-nano Measurement, Manipulation and Physics (Ministry of Education), Department of Physics, Beijing (China)

    2017-09-15

    The effect of Pr addition on the microstructure and martensitic transformation behavior of Ni{sub 50}Ti{sub 50-x}Pr{sub x} (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9) alloys were investigated experimentally. Results show that the microstructures of Ni-Ti-Pr alloys consist of the NiTi matrix and the NiPr precipitate with the Ti solute. The martensitic transformation start temperature decreases gradually with the increase in Pr fraction. The stress around NiPr precipitates is responsible for the decrease in martensitic transformation temperature with the increase in Pr fraction in Ni-Ti-Pr alloys. (orig.)

  20. Near-surface segregation in irradiated Ni3Si

    International Nuclear Information System (INIS)

    Wagner, W.; Rehn, L.E.; Wiedersich, H.

    1982-01-01

    The radiation-induced growth of Ni 3 Si films on the surfaces of Ni(Si) alloys containing = 3 Si phase has been observed. Post-irradiation depth profiling by Auger electron spectroscopy, as well as in situ analysis by high-resolution Rutherford backscattering spectrometry, reveals Si-enrichment at the surfaces of Ni(Si) alloys in excess of stoichiometric Ni 3 Si during irradiation. Thin, near-surface layers with silicon concentrations of 28 to 30 at.% are observed, and even higher Si enrichment is found in the first few atom layers. Transmission electron microscopy and selected area-electron diffraction were employed to characterize these Si-enriched layers. A complex, multiple-spot diffraction pattern is observed superposed on the diffraction pattern of ordered Ni 3 Si. The d-spacings obtained from the extra spots are consistent with those of the orthohexagonal intermetallic compound Ni 5 Si 2 . (author)

  1. Crystal growth velocity in deeply undercooled Ni-Si alloys

    Science.gov (United States)

    Lü, Y. J.

    2012-02-01

    The crystal growth velocity of Ni95Si5 and Ni90Si10 alloys as a function of undercooling is investigated using molecular dynamics simulations. The modified imbedded atom method potential yields the equilibrium liquidus temperatures T L ≈ 1505 and 1387 K for Ni95Si5 and Ni90Si10 alloys, respectively. From the liquidus temperatures down to the deeply undercooled region, the crystal growth velocities of both the alloys rise to the maximum with increasing undercooling and then drop slowly, whereas the athermal growth process presented in elemental Ni is not observed in Ni-Si alloys. Instead, the undercooling dependence of the growth velocity can be well-described by the diffusion-limited model, furthermore, the activation energy associated with the diffusion from melt to interface increases as the concentration increases from 5 to 10 at.% Si, resulting in the remarkable decrease of growth velocity.

  2. Diffusion studies in amorphous NiZr alloys

    International Nuclear Information System (INIS)

    Hahn, H.; Averback, R.S.; Hoshino, K.; Rothman, S.J.

    1987-06-01

    Tracer impurity and self diffusion measurements have been made on amorphous (a-) NiZr alloys using radioactive tracer, Secondary Ion Mass Spectrometry and Rutherford backscattering techniques. The temperature dependence of diffusion in a-NiZr can be represented in the form D = D 0 exp(-Q/kT), with no structural relaxation effects being observed. The mobility of an atom in a-NiZr increased dramatically with decreasing atomic radius of the diffusing atom and also with decreasing Ni content for Ni concentrations below ≅40 at. %. These diffusion characteristics in a-NiZr are remarkably similar to those in α-Zr and α-Ti. These mechanisms assume that Zr and Ti provide a close packed structure, either crystalline or amorphous, through which small atoms diffuse by an interstitial mechanism and large atoms diffuse by a vacancy mechanism. 12 refs., 2 figs., 2 tabs

  3. Thermal variation of magnetization in Ni/V multilayers

    International Nuclear Information System (INIS)

    Benkirane, K.; Elkabil, R.; Hamdoun, A.; Lassri, M.; Abid, M.; Lassri, H.; Krishnan, R.

    2004-01-01

    The magnetic properties of Ni/V multilayers, prepared by the RF sputtering method, have been systematically studied by magnetic measurements. The magnetization decreases with a decrease in Ni layer thickness tNi and the analysis of the results at 5K indicates the presence of a dead Ni layer about 12A thick. The effective anisotropy Keff of Ni/V multilayers is obtained using a torque magnetometer. The interface contribution to the magnetic anisotropy is practically negligible. A spin-wave theory has been used to explain the temperature dependence of the magnetization and the approximate values for the bulk exchange interaction Jb, surface exchange interaction JS, and the interlayer coupling strength JI for various Ni layer thicknesses have been obtained

  4. Synthesis of electroplated 63Ni source and betavoltaic battery

    International Nuclear Information System (INIS)

    Uhm, Young Rang; Yoo, Kwon Mo; Choi, Sang Mu; Kim, Jin Joo; Son, Kwang Jae

    2015-01-01

    Radioisotope (Nuclear) battery using 63 Ni was prepared as beta cell. The electroplated 63 Ni on Ni foil is fabricated, and beta cell and photovoltaic hybrid battery was designed to use at both day and night in space project. A Ni-plating solution is prepared by dissolving metal particles including 62 Ni and 63 Ni from neutron irradiation of (n,γ). Electroplating solution of a chloride bath consists on nickel ions in HCl, H 3 BO 3 , and KOH. The deposition was carried out at current density of 10 mA cm -2 . The prepared beta source was attached on a PN junction and measured I-V properties. The power output at activity of 0.07 mCi and 0.45 mCi were 0.55 pW and 2.69 nW, respectively

  5. Equilibrium relationships in the system Ni-U-O

    International Nuclear Information System (INIS)

    Mansour, N.A.L.

    1980-01-01

    Phase relationships were established in air and in oxygen. Mixtures of NiO and U 3 O 8 oxidize to NiUO 4 . The results of analysis of NiUO 4 were identical to those previously published for NiU 3 O 10 . The uranate dissociates to NiO and U 3 O 8 at a temperature higher than that of their oxidation back to the uranate on cooling because of the difficulty of oxygen diffusion and uranate nucleation. Accordingly, dissociation temperature was taken to represent equilibrium and was used to calculate roughly ΔH and ΔS for the reaction of dissociation. In presence of NiO, U 3 O 8 melts partially and does not dissociate to the lower oxide. (orig.) [de

  6. Coercivity scaling in antidot lattices in Fe, Ni, and NiFe thin films

    Energy Technology Data Exchange (ETDEWEB)

    Gräfe, Joachim, E-mail: graefe@is.mpg.de; Schütz, Gisela; Goering, Eberhard J., E-mail: goering@is.mpg.de

    2016-12-01

    Antidot lattices can be used to artificially engineer magnetic properties in thin films, however, a conclusive model that describes the coercivity enhancement in this class of magnetic nano-structures has so far not been found. We prepared Fe, Ni, and NiFe thin films and patterned each with 21 square antidot lattices with different geometric parameters and measured their hysteretic behavior. On the basis of this extensive dataset we are able to provide a model that can describe both the coercivity scaling over a wide range of geometric lattice parameters and the influence of different materials.

  7. Sideward flow of K+ in Ru+Ru and Ni+Ni reactions sat SIS energies

    International Nuclear Information System (INIS)

    Crochet, P.; Herrmann, N.; Wisniewski, K.

    2000-01-01

    Experimental data on K + and proton sideward flow measured with the FOPI detector at SIS/GSI in the reactions Ru+Ru at 1.69 A GeV and Ni+Ni at 1.93 A GeV are presented. The K + sideward flow is found to be anti-correlated (correlated) with the one of protons at low (high) transverse momenta. When compared to the predictions of a transport model, the data favour the existence of an in-medium repulsive K + -nucleon potential. (author)

  8. Shape and size effects on layered Ni/PZT/Ni composites magnetoelectric performance

    Energy Technology Data Exchange (ETDEWEB)

    Pan, D A; Zhang, S G; Qiao, L J [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Volinsky, Alex A [Department of Mechanical Engineering, University of South Florida, Tampa FL 33620 (United States)], E-mail: lqiao@ustb.edu.cn

    2008-09-07

    This paper presents the magnetoelectric (ME) effect in trilayered Ni/PZT/Ni composites which is related to their size and shape. The ME composites with the same interfacial areas but different geometrical shapes have different ME voltage coefficients. Longitudinal resonant modes in the rectangular and triangular trilayered ME composites were studied. One should choose optimized size, shape and working frequency of the ME composites in order to gain the maximum ME effect. This study plays a guiding role for trilayered ME composites design for real applications. (fast track communication)

  9. Microstructural evolution of neutron-irradiated Ni-Si and Ni-Al alloys

    Science.gov (United States)

    Takahashi, H.; Garner, F. A.

    1992-10-01

    Additions of silicon and aluminum suppress the neutron-induced swelling of pure nickel but to different degrees. Silicon is much more effective initially when compared to aluminum on a per atom basis but silicon exhibits a nonmonotonic influence on swelling with increasing concentration. Silicon tends to segregate toward grain boundaries while aluminum segregates away from these boundaries. Whereas the formation of the Ni 3Si phase is frequently observed in charged particle irradiation experiments conducted at much higher displacement rates, it did not occur during neutron irradiation in this study. Precipitation also did not occur in Ni-5Al during neutron irradiation, nor has it been reported to occur during ion irradiation.

  10. Strengthening by ordered precipitates in a Ni--Ni4Mo system

    International Nuclear Information System (INIS)

    Goodrum, J.W.; LeFevre, B.G.

    1977-01-01

    The strength characteristics and microstructures of aged Ni-Mo alloys containing ordered (Ni 4 Mo) precipitates were studied as a function of aging time and temperature. It was found that 17 at. percent Mo alloy aged at 750 0 C produced a uniform dispersion of cuboidal β precipitates which coarsened with time producing a gradual increase in flow stress. The flow stress increment was found to vary in qualitative agreement with both order strengthening and coherency strain models. Both these models give over-estimates of the strengthening increment. A negative dependence of flow stress on temperature is attributed to coherency strain contributions

  11. The nature of strong Brønsted acidity of Ni-SMM clay

    NARCIS (Netherlands)

    Yue, C.; Liu, C.; Mezari, B.; Brückner, A.; Pidko, E.A.; Rigutto, M.S.; Hensen, E.J.M.

    2016-01-01

    The origin of the high Brønsted acidity of Ni-SMM (Ni-substituted synthetic mica-montmorillonite; beidellite structure) clays was investigated. Ni-SMM clays with varying F content, SMM with F and Ni-SMM without F in the structure were synthesized under hydrothermal conditions. Ni-SMM clays with

  12. Los niños y los videojuegos

    OpenAIRE

    Orrego Gaviria, Jaime; Fundación Valle de Lili

    2007-01-01

    Los niños y los videojuegos / Efectos perjudiciales de la utilización de los videojuegos por los niños y adolescentes/ Efectos benéficos de la de la utilización de los videojuegos por los niños y adolescentes/ Recomendaciones para favorecer el uso adecuado/ Sistema de clasificación de los videojuegos

  13. Electrochemical Characterization of Ni/(Sc)YSZ Electrodes

    DEFF Research Database (Denmark)

    Ramos, Tania; Thydén, Karl Tor Sune; Mogensen, Mogens Bjerg

    2010-01-01

    Investigations of Ni/(Sc)YSZ cermets for solid oxide cells (SOCs) were performed by electrochemical impedance spectroscopy (EIS), under varying experimental conditions and upon redox cycling, using three different designs of symmetric cells. The deconvolution and fitting of the obtained impedance...... parameters. Initial degradation results for both Ni/ScYSZ and Ni/YSZ based anodes under very high steam content are also reported. ©2010 COPYRIGHT ECS - The Electrochemical Society...

  14. Irradiation-induced precipitation in Ni--Si alloys

    International Nuclear Information System (INIS)

    Barbu, A.; Ardell, A.J.

    1975-07-01

    The microstructures of Ni + ion-irradiated Ni--Si solid-solution alloys, containing 2, 4, 6 and 8 at. percent Si were investigated as a function of dose, dose-rate, and temperature. Results of transmission electron microscopy and other data show the precipitation of γ' (Ni 3 Si) in all samples irradiated at 500 0 C. Characteristics of the precipitates are described and a mechanism for their formation is suggested. (U.S.)

  15. Ni-YSZ graded coatings produced by dipping

    International Nuclear Information System (INIS)

    Ferrari, B.; Moreno, R.

    2004-01-01

    A new colloidal processing route for the shaping of a graded Ni-YSZ composite for applications in SOFC devices is described. A Ni foil is coated by Ni/YSZ layers by dipping in aqueous suspensions with an organic binder. Behind the metal-ceramic layers introduced to improve adhesion, an outer thin layer of nanosized YSZ is formed by electrophoretic deposition. (Abstract Copyright [2004], Wiley Periodicals, Inc.)

  16. Low-field spin dynamics of Cr7Ni and Cr7Ni-Cu-Cr7Ni molecular rings as detected by μsR

    OpenAIRE

    Sanna, S.; Arosio, P.; Bordonali, L.; Adelnia, F.; Mariani, M.; Garlatti, E.; Baines, C.; Amato, A.; Sabareesh, K. P.V.; Timco, G.; Winpenny, R. E.P.; Blundell, S. J.; Lascialfari, A.

    2017-01-01

    Muon spin rotation measurements were used to investigate the spin dynamics of heterometallic Cr7Ni and Cr7Ni-Cu-Cr7Ni molecular clusters. In Cr7Ni the magnetic ions are arranged in a quasiplanar ring and interact via an antiferromagnetic exchange coupling constant J, while Cr7Ni-Cu-Cr7Ni is composed of two Cr7Ni linked by a bridging moiety containing one Cu ion, that induces an inter-ring ferromagnetic interaction J ≪ J. The longitudinal muon relaxation rate λ collected at low magnetic fields...

  17. Comparison of three Ni-Hard I alloys

    Energy Technology Data Exchange (ETDEWEB)

    Dogan, Omer N.; Hawk, Jeffrey A.; Rice, J. (Texaloy Foundry Co., Inc., Floresville, Texas)

    2004-09-01

    This report documents the results of an investigation which was undertaken to reveal the similarities and differences in the mechanical properties and microstructural characteristics of three Ni-Hard I alloys. One alloy (B1) is ASTM A532 class IA Ni-Hard containing 4.2 wt. pct. Ni. The second alloy (B2) is similar to B1 but higher in Cr, Si, and Mo. The third alloy (T1) also falls in the same ASTM specification, but it contains 3.3 wt. pct. Ni. The alloys were evaluated in both as-cast and stress-relieved conditions except for B2, which was evaluated in the stress-relieved condition only. While the matrix of the high Ni alloys is composed of austenite and martensite in both conditions, the matrix of the low Ni alloy consists of a considerable amount of bainite, in addition to the martensite and the retained austenite in as cast condition, and primarily bainite, with some retained austenite, in the stress relieved condition. It was found that the stress relieving treatment does not change the tensile strength of the high Ni alloy. Both the as cast and stress relieved high Ni alloys had a tensile strength of about 350 MPa. On the other hand, the tensile strength of the low Ni alloy increased from 340 MPa to 452 MPa with the stress relieving treatment. There was no significant difference in the wear resistance of these alloys in both as-cast and stressrelieved conditions.

  18. An investigation of the oxidized Ni/InAs interface

    International Nuclear Information System (INIS)

    Venter, A.; Botha, J.R.; Swart, H.C.; Naidoo, S.; Olivier, E.J.

    2009-01-01

    Ni was resistively deposited onto bulk InAs and subsequently oxidized in an O 2 atmosphere. The anneal temperature and time were 450 deg. C and 2.5 h, respectively. X-ray diffraction of the oxidized Ni/InAs sample revealed the formation of In 3 Ni 2 and In 2 O 3 on the front suggesting inter diffusion of In, Ni and O. NiO was not detected by X-ray diffraction. In a preliminary study, using glass as a substrate, NiO readily formed when using these oxidation parameters. Conductivity measurements of the oxidized Ni/InAs surface revealed a conducting front and insulating rear surface while TEM of the Ni/InAs interface revealed an intermediate amorphous diffusion zone between the 'oxidized' Ni layer and the bulk InAs. A closer investigation of the intermediate layer supports the X-ray diffraction results, suggesting compound formation due to diffusion of oxygen and nickel into the substrate, and out-diffusion of In and As from the bulk of the sample. AES was used to further elucidate these results.

  19. An investigation of the oxidized Ni/InAs interface

    Energy Technology Data Exchange (ETDEWEB)

    Venter, A., E-mail: andre.venter@nmmu.ac.z [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Botha, J.R. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Swart, H.C. [Department of Physics, University of the Free State, PO Box 339, Bloemfontein 9300 (South Africa); Naidoo, S.; Olivier, E.J. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa)

    2009-12-01

    Ni was resistively deposited onto bulk InAs and subsequently oxidized in an O{sub 2} atmosphere. The anneal temperature and time were 450 deg. C and 2.5 h, respectively. X-ray diffraction of the oxidized Ni/InAs sample revealed the formation of In{sub 3}Ni{sub 2} and In{sub 2}O{sub 3} on the front suggesting inter diffusion of In, Ni and O. NiO was not detected by X-ray diffraction. In a preliminary study, using glass as a substrate, NiO readily formed when using these oxidation parameters. Conductivity measurements of the oxidized Ni/InAs surface revealed a conducting front and insulating rear surface while TEM of the Ni/InAs interface revealed an intermediate amorphous diffusion zone between the 'oxidized' Ni layer and the bulk InAs. A closer investigation of the intermediate layer supports the X-ray diffraction results, suggesting compound formation due to diffusion of oxygen and nickel into the substrate, and out-diffusion of In and As from the bulk of the sample. AES was used to further elucidate these results.

  20. Oxidation of hydrogen peroxide by [Ni III (cyclam)

    Indian Academy of Sciences (India)

    The kinetics of oxidation of H2O2 by [NiIII(cyclam)]3+, [NiIIIL1], was studied in aqueous acidic media at 25°C and I = 0.5M (NaClO4). The [NiIIIL1] to [NiIIL1] reduction was found to be fast in the presence of Cu(II) ion than the oxidation of the cyclam ligand by ·OH. The rate constant showed an inverse acid dependence on H+ ...

  1. Level density of radioactive doubly-magic nucleus 56Ni

    International Nuclear Information System (INIS)

    Santhosh Kumar, S.; Rengaiyan, R.; Victor Babu, A.; Preetha, P.

    2012-01-01

    In this work the single particle energies are obtained by diagonalising the Nilsson Hamiltonian in the cylindrical basis and are generated up to N =11 shells for the isotopes of Ni from A = 48-70, emphasizing the three magic nuclei viz, 48 Ni, 56 Ni and 68 Ni. The statistical quantities like excitation energy, level density parameter and nuclear level density which play the important roles in the nuclear structure and nuclear reactions can be calculated theoretically by means of the Statistical or Partition function method. Hence the statistical model approach is followed to probe the dynamical properties of the nucleus in the microscopic level

  2. CVD Graphene/Ni Interface Evolution in Sulfuric Electrolyte

    DEFF Research Database (Denmark)

    Yivlialin, Rossella; Bussetti, Gianlorenzo; Duò, Lamberto

    2018-01-01

    Systems comprising single and multilayer graphene deposited on metals and immersed in acid environments have been investigated, with the aim of elucidating the mechanisms involved, for instance, in hydrogen production or metal protection from corrosion. In this work, a relevant system, namely...... chemical vapor deposited (CVD) multilayer graphene/Ni (MLGr/Ni), is studied when immersed in a diluted sulfuric electrolyte. The MLGr/Ni electrochemical and morphological properties are studied in situ and interpreted in light of the highly oriented pyrolytic graphite (HOPG) electrode behavior, when...... immersed in the same electrolyte. Following this interpretative framework, the dominant role of the Ni substrate in hydrogen production is clarified....

  3. Design and fabrication of Ni nanowires having periodically hollow nanostructures

    Science.gov (United States)

    Sada, Takao; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2014-09-01

    We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag `barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 +/- 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni2+ for the interior surfaces of AAO. The Ni shell layer allows the Ni segments to remain even after dissolution of the Ag segments. Because the electroplating conditions can be easily controlled, we could carefully adjust the size and pitch of the periodically hollow nanospaces. We also describe a method for the fabrication of Ni nanorods by forming an Ag shell instead of a Ni shell on the Ni-Ag barcode nanowire, in which the interior of the AAO surfaces was modified with a compound bearing a thiol group prior to electroplating.We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag `barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 +/- 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni2+ for the

  4. Comparative study of NiW, NiMo and MoW prepared by mechanical alloying

    International Nuclear Information System (INIS)

    Gonzalez, G.; Sagarzazu, A.; Villalba, R.; Ochoa, J.

    2007-01-01

    The present work concern the amorphisation process induced by mechanical alloying in the NiW, NiMo and MoW systems. The alloys chosen combine a group of transition elements varying from very similar atomic radius and electronic valences (MoW) to different ones (NiW and NiMo). The three systems achieved an amorphous state after 50 h of milling. The mechanism of amorphisation proposed for NiW and NiMo was the combined effect of an excess concentration of the solute atoms entering into the structure of one of the elements and a critical concentration of defects. Continuous formation of an amorphous phase at the interface of the crystalline phase was observed during the process. MoW seems to amorphize by continuous reduction of grain size down to a critical value where the amorphisation takes place

  5. The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy under Xe26+ ion irradiation

    Science.gov (United States)

    Chen, Huaican; Hai, Yang; Liu, Renduo; Jiang, Li; Ye, Xiang-xi; Li, Jianjian; Xue, Wandong; Wang, Wanxia; Tang, Ming; Yan, Long; Yin, Wen; Zhou, Xingtai

    2018-04-01

    The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy was investigated. 7 MeV Xe26+ ion irradiation was performed at room temperature and 650 °C with peak damage dose from 0.05 to 10 dpa. With the increase of damage dose, the hardness of Ni-Mo-Cr and Ni-W-Cr alloy increases, and reaches saturation at damage dose ≥1 dpa. Moreover, the damage dose dependence of hardness in both alloys can be described by the Makin and Minter's equation, where the effective critical volume of obstacles can be used to represent irradiation hardening resistance of the alloys. Our results also show that Ni-W-Cr alloy has better irradiation hardening resistance than Ni-Mo-Cr alloy. This is ascribed to the fact that the W, instead of Mo in the alloy, can suppress the formation of defects under ion irradiation.

  6. Flexible bottom-emitting white organic light-emitting diodes with semitransparent Ni/Ag/Ni anode.

    Science.gov (United States)

    Koo, Ja-Ryong; Lee, Seok Jae; Lee, Ho Won; Lee, Dong Hyung; Yang, Hyung Jin; Kim, Woo Young; Kim, Young Kwan

    2013-05-06

    We fabricated a flexible bottom-emitting white organic light-emitting diode (BEWOLED) with a structure of PET/Ni/Ag/Ni (3/6/3 nm)/ NPB (50 nm)/mCP (10 nm)/7% FIrpic:mCP (10 nm)/3% Ir(pq)(2) acac:TPBi (5 nm)/7% FIrpic:TPBi (5 nm)/TPBi (10 nm)/Liq (2 nm)/ Al (100 nm). To improve the performance of the BEWOLED, a multilayered metal stack anode of Ni/Ag/Ni treated with oxygen plasma for 60 sec was introduced into the OLED devices. The Ni/Ag/Ni anode effectively enhanced the probability of hole-electron recombination due to an efficient hole injection into and charge balance in an emitting layer. By comparing with a reference WOLED using ITO on glass, it is verified that the flexible BEWOLED showed a similar or better electroluminescence (EL) performance.

  7. Hydride Reactivity of Ni-II-X-Ni-II Entities : Mixed-Valent Hydrido Complexes and Reversible Metal Reduction

    NARCIS (Netherlands)

    Gehring, Henrike; Metzinger, Ramona; Herwig, Christian; Intemann, Julia; Harder, Sjoerd; Limberg, Christian

    After the lithiation of PYR-H2 (PYR2-=[{NC(Me)C(H)C(Me)NC6H3(iPr)2}2(C5H3N)]2-), which is the precursor of an expanded beta-diketiminato ligand system with two binding pockets, its reaction with [NiBr2(dme)] led to a dinuclear nickel(II)bromide complex, [(PYR)Ni(mu-Br)NiBr] (1). The bridging bromide

  8. Studies on the valence electronic structure of Fe and Ni in FexNi1−x ...

    Indian Academy of Sciences (India)

    structure of Fe and Ni in various Fex Ni1−x alloys. Since Kβ-to-Kα X-ray intensity ratio has been reported [2–7] to be a sensitive physical parameter to investigate the changes in the valence electronic structure of 3d-transition metals [2], we have undertaken the study of the valence electronic structure of Fe and Ni in the Fex ...

  9. Effects of Ni content on nanocrystalline Fe–Co–Ni ternary alloys synthesized by a chemical reduction method

    Energy Technology Data Exchange (ETDEWEB)

    Chokprasombat, Komkrich, E-mail: komkrich28@gmail.com [Department of Physics, Faculty of Science, Thaksin University, Phatthalung 93210 Thailand (Thailand); Pinitsoontorn, Supree [Integrated Nanotechnology Research Center, Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 Thailand (Thailand); Maensiri, Santi [School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000 Thailand (Thailand)

    2016-05-01

    Magnetic properties of Fe–Co–Ni ternary alloys could be altered by changing of the particle size, elemental compositions, and crystalline structures. In this work, Fe{sub 50}Co{sub 50−x}Ni{sub x} nanoparticles (x=10, 20, 40, and 50) were prepared by the novel chemical reduction process. Hydrazine monohydrate was used as a reducing agent under the concentrated basic condition with the presence of poly(vinylpyrrolidone). We found that the nanoparticles were composed of Fe, Co and Ni with compositions according to the molar ratio of the metal sources. Interestingly, the particles were well-crystalline at the as-prepared state without post-annealing at high temperature. Increasing Ni content resulted in phase transformation from body centered cubic (bcc) to face centered cubic (fcc). For the fcc phase, the average particle size decreased when increased the Ni content; the Fe{sub 50}Ni{sub 50} nanoparticles had the smallest average size with the narrowest size distribution. In additions, the particles exhibited ferromagnetic properties at room temperature with the coercivities higher than 300 Oe, and the saturation magnetiation decreased with increasing Ni content. These results suggest that the structural and magnetic properties of Fe–Co–Ni alloys could be adjusted by varying the Ni content. - Highlights: • We prepared nanocrystalline Fe–Co–Ni alloys by a novel chemical reduction process. • Elemental compositions could be well controlled by the molar ratio of metal sources. • Particle size and magnetic properties clearly depended on the Ni contents. • Fe{sub 50}Co{sub 10}Ni{sub 40} exhibited high saturation magnetization of 126.3 emu/g.

  10. Effect of Ni content on the morphological evolution of Ni-YSZ solid oxide fuel cell electrodes

    Science.gov (United States)

    Chen-Wiegart, Yu-chen Karen; Kennouche, David; Scott Cronin, J.; Barnett, Scott A.; Wang, Jun

    2016-02-01

    The coarsening of Ni in Ni-yttria-stabilized zirconia (YSZ) anodes is a potential cause of long term solid oxide fuel cells (SOFC) performance degradation. The specifics of the Ni-YSZ structure—including Ni/YSZ ratio, porosity, and particle size distributions—are normally selected to minimize anode polarization resistance, but they also impact long-term stability. A better understanding of how these factors influence long-term stability is important for designing more durable anodes. The effect of structural details, e.g., Ni-YSZ ratio, on Ni coarsening has not been quantified. Furthermore, prior measurements have been done by comparing evolved structures with control samples, such that sample-to-sample variations introduce errors. Here, we report a four dimensional (three spatial dimensions and time) study of Ni coarsening in Ni-YSZ anode functional layers with different Ni/YSZ ratios, using synchrotron x-ray nano-tomography. The continuous structural evolution was observed and analyzed at sub-100 nm resolution. It is shown quantitatively that increasing the Ni/YSZ ratio increases the Ni coarsening rate. This is due to both increased pore volume and a decrease in the YSZ volume fraction, such that there is more free volume and a less obtrusive YSZ network, both of which allow greater Ni coarsening. The results are shown to be in good agreement with a power-law coarsening model. The finding is critical for informing the design of SOFC electrode microstructures that limit coarsening and performance degradation.

  11. Formation of nickel germanides from Ni layers with thickness below 10 nm

    Energy Technology Data Exchange (ETDEWEB)

    Jablonka, Lukas; Kubart, Tomas; Primetzhofer, Daniel; Abedin, Ahmad; Hellström, Per-Erik; Östling, Mikael; Jordan-Sweet, Jean; Lavoie, Christian; Zhang, Shi-Li; Zhang, Zhen

    2017-03-01

    The authors have studied the reaction between a Ge (100) substrate and thin layers of Ni ranging from 2 to 10 nm in thickness. The formation of metal-rich Ni5Ge3Ni5Ge3 was found to precede that of the monogermanide NiGe by means of real-time in situ x-ray diffraction during ramp-annealing and ex situ x-ray pole figure analyses for phase identification. The observed sequential growth of Ni5Ge3Ni5Ge3 and NiGe with such thin Ni layers is different from the previously reported simultaneous growth with thicker Ni layers. The phase transformation from Ni5Ge3Ni5Ge3 to NiGe was found to be nucleation-controlled for Ni thicknesses <5 nm<5 nm, which is well supported by thermodynamic considerations. Specifically, the temperature for the NiGe formation increased with decreasing Ni (rather Ni5Ge3Ni5Ge3) thickness below 5 nm. In combination with sheet resistance measurement and microscopic surface inspection of samples annealed with a standard rapid thermal processing, the temperature range for achieving morphologically stable NiGe layers was identified for this standard annealing process. As expected, it was found to be strongly dependent on the initial Ni thickness

  12. The Ni-rich Part of the Ni-P-Sn System: Isothermal Sections

    Czech Academy of Sciences Publication Activity Database

    Schmetterer, C.; Vízdal, J.; Kroupa, Aleš; Kodentsov, A.; Ipser, H.

    2009-01-01

    Roč. 38, č. 11 (2009), s. 2275-2300 ISSN 0361-5235 R&D Projects: GA MŠk(CZ) OC08053 Institutional research plan: CEZ:AV0Z20410507 Keywords : lead free solder * phase diagram * Ni-P-Sn Subject RIV: BJ - Thermodynamics Impact factor: 1.428, year: 2009

  13. Fabrication of TiNi/CFRP smart composite using cold drawn TiNi wires

    Science.gov (United States)

    Xu, Ya; Otsuka, Kazuhiro; Toyama, Nobuyuki; Yoshida, Hitoshi; Jang, Byung-Koog; Nagai, Hideki; Oishi, Ryutaro; Kishi, Teruo

    2002-07-01

    In recent years, pre-strained TiNi shape memory alloys (SMA) have been used for fabricating smart structure with carbon fibers reinforced plastics (CFRP) in order to suppress microscopic mechanical damages. However, since the cure temperature of CFRP is higher than the reverse transformation temperatures of TiNi SMA, special fixture jigs have to be used for keeping the pre-strain during fabrication, which restricted its practical application. In order to overcome this difficulty, we developed a new method to fabricate SMA/CFRP smart composites without using special fixture jigs by controlling the transformation temperatures of SMA during fabrication. This method consists of using heavily cold-worked wires to increase the reverse transformation temperatures, and of using flash electrical heating of the wires after fabrication in order to decrease the reverse transformation temperatures to a lower temperature range again without damaging the epoxy resin around SMA wires. By choosing proper cold-working rate and composition of TiNi alloys, the reverse transformation temperatures were well controlled, and the TiNi/CFRP hybrid smart composite was fabricated without using special fixture jigs. The damage suppressing effect of cold drawn wires embedded in CFRP was confirmed.

  14. Transformation dynamics of Ni clusters into NiO rings under electron beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Knez, Daniel, E-mail: daniel.knez@felmi-zfe.at [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria); Thaler, Philipp; Volk, Alexander [Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, 8010 Graz (Austria); Kothleitner, Gerald [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria); Ernst, Wolfgang E. [Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, 8010 Graz (Austria); Hofer, Ferdinand [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria)

    2017-05-15

    We report the transformation of nickel clusters into NiO rings by an electron beam induced nanoscale Kirkendall effect. High-purity nickel clusters consisting of a few thousand atoms have been used as precursors and were synthesized with the superfluid helium droplet technique. Aberration-corrected, analytical scanning transmission electron microscopy was applied to oxidise and simultaneously analyse the nanostructures. The transient dynamics of the oxidation could be documented by time lapse series using high-angle annular dark-field imaging and electron energy-loss spectroscopy. A two-step Cabrera-Mott oxidation mechanism was identified. It was found that water adsorbed adjacent to the clusters acts as oxygen source for the electron beam induced oxidation. The size-dependent oxidation rate was estimated by quantitative EELS measurements combined with molecular dynamics simulations. Our findings could serve to better control sample changes during examination in an electron microscope, and might provide a methodology to generate other metal oxide nanostructures. - Highlights: • Beam induced conversion of Ni clusters into crystalline NiO rings has been observed. • Ni clusters were grown with the superfluid He-droplet technique. • oxidizeSTEM was utilized to investigate and simultaneously oxidize these clusters. • Oxidation dynamics was captured in real-time. • Cluster sizes and the oxidation rate were estimated via EELS and molecular dynamics.

  15. Structural conditions of achieving maximum ductility of two-phase Ni-NiO alloys

    International Nuclear Information System (INIS)

    Grabin, V.V.; Dabizha, E.V.; Movchan, B.A.

    1984-01-01

    A study was made on possibility of increasing ductility of two-phase Ni-NiO alloys, proJuced by traditional technology: ingot smelting, rolling and corresponding annealing for production of grain with certain size. The correlation of mechanical properties of Ni-NiO alloys and pure nickel shows that completion of the structural conJition D--lambda (where D - the average grain diameter, lambda - the value of free path between particles) in two-phase alloys enables: to increase the ultimate strength 1.5 times and preserve the basic level of pure nickel plasticity - at 20 deg C; to increase plasticity 1.4-1.5 times with preserved basic level of pure nickel plasticity - at 800 deg C. The conclusions testify to possibility of controlling mechanical properties of two-phase alloys using structural D and lambda parameters It is proposed that creation of structures with more unifor m particle distribution with respect to sizes will the accompanied by further increase of plasticity under D=lambda condition

  16. Experimental study of the $^{66}$Ni$(d,p)^{67}$Ni one-neutron transfer reaction

    CERN Document Server

    Diriken, J.; Andreyev, A.N.; Antalic, S.; Bildstein, V.; Blazhev, A.; Darby, I.G.; De Witte, H.; Eberth, J.; Elseviers, J.; Fedosseev, V.N.; Flavigny, F.; Fransen, Ch.; Georgiev, G.; Gernhauser, R.; Hess, H.; Huyse, M.; Jolie, J.; Kröll, Th.; Krücken, R.; Lutter, R.; Marsh, B.A.; Mertzimekis, T.; Muecher, D.; Orlandi, R.; Pakou, A.; Raabe, R.; Randisi, G.; Reiter, P.; Roger, T.; Seidlitz, M.; Seliverstov, M.; Sotty, C.; Tornqvist, H.; Van De Walle, J.; Van Duppen, P.; Voulot, D.; Warr, N.; Wenander, F.; Wimmer, K.

    2015-01-01

    The quasi-SU(3) sequence of the positive parity $νg_{9/2}, d_{5/2}, s_{1/2}$ orbitals above the N=40 shell gap are assumed to induce strong quadrupole collectivity in the neutron-rich Fe (Z=26) and Cr (Z=24) isotopes below the nickel region. In this paper the position and strength of these single-particle orbitals are characterized in the neighborhood of $^{68}$Ni (Z=28,N=40) through the $^{66}$Ni($d,p$)$^{67}$Ni one-neutron transfer reaction at 2.95 MeV/nucleon in inverse kinematics, performed at the REX-ISOLDE facility in CERN. A combination of the Miniball $\\gamma$-array and T-REX particle-detection setup was used and a delayed coincidence technique was employed to investigate the 13.3-$\\mu$s isomer at 1007 keV in $^{67}$Ni. Excited states up to an excitation energy of 5.8 MeV have been populated. Feeding of the $νg_{9/2}$ (1007 keV) and $νd_{5/2}$ (2207 keV and 3277 keV) positive-parity neutron states and negative parity ($νpf$) states have been observed at low excitation energy. The extracted relativ...

  17. Energies of Electronic States of Ni (II) Ion in NiO-Al2O3 Catalyst Prepared by Impregnation

    International Nuclear Information System (INIS)

    Obadovic, D. Z.; Kiurski, J.; Marinkovic-Neducin, R. P.

    2007-01-01

    The behavior of NiO-Al2O3 catalysts is strongly dependent on the preparation method, as well as on pretreatment conditions. In the present work we investigated the influences of Ni(II) ion on NiO-Al2O3 catalysts properties due to the preparation by impregnation method. Based on experimental diffuse reflectance spectroscopy (DRS) data of electronic d-d transitions of Ni (II) promoter ion the energies of electronic states in spinel-like structure were calculated, and the most probable scheme of molecular orbital have been proposed

  18. Interacción familiar y desarrollo emocional en niños y niñas

    Directory of Open Access Journals (Sweden)

    Gloria Cecilia Henao López

    2009-01-01

    Full Text Available En la presente investigación se tuvo como objetivo principal abordar los estilos de interacción de padres y madres de niños y niñas preescolares y su relación con el desarrollo emocional de sus hijos e hijas (235 niños y 169 niñas entre cinco y seis años de edad. Las dimensiones que se consideraron para evaluar el nivel emocional de los niños y niñas fueron: autorregulación, comprensión emocional, y empatía. Como primer aspecto describimos los tipos de interacción con sus hijos e hijas y el desarrollo emocional de los niños y niñas evaluados. Un segundo aspecto que se abordó, es el de explorar las asociaciones entre el estilo de interacción familiar y el desarrollo emocional infantil. El instrumento utilizado dirigido a los padres y madres fue la Escala de Identificación de Prácticas Educativas Familiares (PEF, versión española realizada por Alonso y Román; a los niños y niñas les aplicamos la evaluación del desempeño emocional (EDEI, que se construye como parte de esta investigación. Se trabajó con una muestra de 404 niños y niñas, y sus respectivos padres y madres. Los resultados obtenidos en esta investigación resaltan el estilo equilibrado como generador de conductas adecuadas y adaptativas en el niño o niña, al igual que rescata este estilo como el que más posibilita el nivel de comprensión emocional en los niños y niñas de nuestro estudio.

  19. Enhanced photocatalytic efficiency in zirconia buffered n-NiO/p-NiO single crystalline heterostructures by nanosecond laser treatment

    Energy Technology Data Exchange (ETDEWEB)

    Molaei, R.; Bayati, M. R.; Alipour, H. M.; Nori, S.; Narayan, J. [Department of Materials Science and Engineering, NC State University, EB-1, Raleigh, North Carolina 27695-7907 (United States)

    2013-06-21

    We report the formation of NiO based single crystalline p-n junctions with enhanced photocatalytic activity induced by pulsed laser irradiation. The NiO epilayers were grown on Si(001) substrates buffered with cubic yttria-stabilized zirconia (c-YSZ) by using pulsed laser deposition. The NiO/c-YSZ/Si heterostructures were subsequently laser treated by 5 pulses of KrF excimer laser (pulse duration = 25 Multiplication-Sign 10{sup -9} s) at lower energies. Microstructural studies, conducted by X-ray diffraction ({theta}-2{theta} and {phi} techniques) and high resolution transmission electron microscope, showed a cube-on-cube epitaxial relationship at the c-YSZ/Si interface; the epitaxial relationship across the NiO/c-YSZ interface was established as NiO<111 > Double-Vertical-Line Double-Vertical-Line c-YSZ<001> and in-plane NiO<110> Double-Vertical-Line Double-Vertical-Line c-YSZ<100>. Electron microscopy studies showed that the interface between the laser annealed and the pristine region as well as the NiO/c-YSZ interface was atomically sharp and crystallographically continuous. The formation of point defects, namely oxygen vacancies and NiO, due to the coupling of the laser photons with the NiO epilayers was confirmed by XPS. The p-type electrical characteristics of the pristine NiO epilayers turned to an n-type behavior and the electrical conductivity was increased by one order of magnitude after laser treatment. Photocatalytic activity of the pristine (p-NiO/c-YSZ/Si) and the laser-annealed (n-NiO/p-NiO/c-YSZ/Si) heterostructures were assessed by measuring the decomposition rate of 4-chlorophenol under UV light. The photocatalytic reaction rate constants were determined to be 0.0059 and 0.0092 min{sup -1} for the as-deposited and the laser-treated samples, respectively. The enhanced photocatalytic efficiency was attributed to the suppressed charge carrier recombination in the NiO based p-n junctions and higher electrical conductivity. Besides, the oxygen vacancies

  20. Tritium-tracer study of catalytic hydrogenation reaction of ethylene on Ni, Pt and Ni-Pt

    International Nuclear Information System (INIS)

    Matsuyama, M.; Yasuda, Y.; Takeuchi, T.

    1978-01-01

    The influence of the pressure of tritiated hydrogen on the rate of the formation of tritiated ethylene, X, and that of tritiated ethane, Z, in the hydrogenation reaction of ethylene on Ni, Pt and Ni-Pt (1:1) alloy catalysts was investigated. The ratio of the rate of the exchange to that of the hydrogenation, selectivity X/Z, decreased markedly with the increase in the pressure of the tritiated hydrogen and the order of X/Z was Ni>Ni-Pt>Pt. These results were interpreted in terms of the difference in the amount of chemisorbed tritium on each metal catalyst. (orig.) [de